This monograph addresses a narrow aspect of cold regions engineering, namely the effects of cold weather on the traditional civil engineering disciplines of hydrology and hydraulics. Hydrologic and hydraulic considerations in the design, construction, and operation of civil works are very important. Many of the problems encountered in the design and construction of buildings, transportation systems, water supply facilities, wastetreatment facilities, and hazardous waste disposal facilities, for example are closely tied to the characteristics of the site hydrology.
The paper presents the progress of the Radioactive Waste Management Plan which accompanies the Decommissioning Plan for research reactor WWR-S located in Magurele, Ilfov, near Bucharest, Romania. The new variant of the Decommissioning Plan was elaborated taking into account the IAEA recommendation concerning radioactive waste management. A new feasibility study for WWR-S decommissioning was also developed. The preferred safe management strategy for radioactive wastes produced by reactor decommissioning is outlined. The strategy must account for reactor decommissioning, as well as rehabilitation of the existing Radioactive WasteTreatment Plant and the upgrade of the Radioactive Waste Disposal Facility at Baita-Bihor. Furthermore, the final rehabilitation of the laboratories and reusing of cleaned reactor building is envisaged. An inventory ...
Papers are presented under 38 symposia. Subjects included reinforced concrete, protective coatings and linings, cathodic/anodic protection, chemical cleaning of boilers, managing corrosion with plastics, water treatment, HRSG boiler tube failure analysis, corrosion in oil and gas production, corrosion in petroleum refining and gas, processing, pipelines and tanks, high temperature materials, chemical process industry, aerospace equipment, materials technology developments for incinerators and waste fuel-fired processors, materials and corrosion in fossil-fuels conversion and combustion, corrosion in nuclear systems, marine corrosion, building systems, corrosion mechanisms, corrosion inhibitors and corrosion monitoring and measurement.
This program deals with solid waste disposal with topics/services covering: Reusable Building Materials and Large Household Items Exchange, Beneficial Use Determination, Biosolids, Certification, Compost Facil...
A brief article considers the possible result of the enquiry into Nirex`s plan to build an underground rock laboratory at Sellafield in relation to radioactive waste disposal in the UK. (UK).
This inspection plan is written to meet the requirements of WAC 173-303 for operations of a TSD facility. Owners/operators of TSD facilities are required to inspection their facility and active waste management units to prevent and/or detect malfunctions, discharges and other conditions potentially hazardous to human health and the environment. A written plan detailing these inspection efforts must be maintained at the facility in accordance with Washington Administrative Code (WAC), Chapter 173-303, ``Dangerous Waste Regulations`` (WAC 173-303), a written inspection plan is required for the operation of a treatment, storage and disposal (TSD) facility and individual TSD units. B Plant is a permitted TSD facility currently operating under interim status with an approved Part A Permit. Various operational systems and locations within or under the control of B Plant have been permitted for waste ...
WASAG DECON developed a concept for the biological in situ remediation of an TNT-contaminated former seepage pond. This pond is located on the site of an ammunition factory in Lower Saxony. Unit 1982 all the waste water from the production buildings was directed into this pond, including TNT-contaminated water from the flushing of shells. Due to this practice, the sediment of the pond, the underlying soil and the groundwater became contaminated with TNT. The area of the soil contamination adds to abut 2.000 m{sup 2}. The remediation concept includes three steps: 1. Excavation of the most highly contaminated soil with TNT-concentrations above 1000 mg/kg. 2. Reduction of the remaining contamination by a biological in situ treatment using organic and inorganic amendments and mechanical tillage. After about to years of treatment, remediation goals of 50 mg/kg are expected to be reached on most of the area. ...
This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for wastetreatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the ...
This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU wastetreatment technologies.
Most important radionuclides naturally appearing in minerals used to form building materials are described. The frequently met ranges of concentrations of these radionuclides in the building materials composed from natural products as well as from power-plant wastes and metallurgic plant wastes are discussed and propositions concerning the limitation of presence of radioactive nuclides in the building materials are given, with special concern paid to materials for dwelling and public utility buildings. The elaborated technique of measuring potassium 40, radium 226 and thorium 228 concentrations is presented. Data on the organization of controlling-and-measuring laboratories in this field are given. (author).
This article describes the processes for the treatment of plastic waste: sampling, sorting, comminution. The requirements for the different processes for wastetreatment (as recycling, utilization as raw material, energy recovery, combustion) are listed. (SR)
In front of the risks linked with the increase of the greenhouse gas emissions in the atmosphere, the decision makers must take into consideration first, the scientific advice of climatic change experts, and second, the considerable inertia of the climatic system. Thus, any action implemented so far will have an impact all along the 21. century and later whatever the future human activities. The aim of this memento is to sensibilize the decision makers about the possible consequences of their choice in terms of volume of greenhouse gases and of medium- and long-term evolution: 1 - stakes, role of local decision-makers (greenhouse effect and climatic change, France's international commitment, stakes, liabilities of local decision makers, decentralization laws, local plans of fight against greenhouse effect, public information and dialogue); 2 - urbanism and transports (urban displacements, alternatives to individual cars, collective transportation systems, parking, inter-region ...
This report consists of a broad overview of activities at Los Alamos National Laboratory (LANL). The following topics are discussed: The growth of the waste management group; what we do today; the mission of the waste management group; the liquid wastetreatment section; the radioactive liquid waste project office; the chemical waste section; the radioactive waste section; and the technical support section.
The applicability of the electro-slag melting method for treating plutonium contaminated metallic waste was studied. A 100kg test furnace was built and simulated metallic waste was melted and solidified in this furnace. Waste volume was reduced to 1/25 with a decontamination factor of 25 and the slag and the copper mold are repeatedly usable. The process is expected to be employed in the project of PWTF (Plutonium contaminated WasteTreatment Facilities).
During its jubilee, the French building technical and scientific centre (CSTB) has organized a colloquium about the future tendencies of buildings evolution in the 20 forthcoming years: autonomy in energy production and wastes or effluents management, reduction of water consumption and management of water, hot water production and space heating, bio-sensors for the management of indoor air-quality, control of noise environment using active acoustic systems etc.. (J.S.)
Some comments are given on the recycling of waste, mainly plastics, as evaluated from the viewpoint of energy environment. Discussed about the waste in general are the definition and classification, generation and resource recovery rates, current state of recycling, problems about recycling, related legislation, and current conditions overseas. Discussed about the treatment and recycling of plastics waste are the characters and use of plastic product, current state of waste plastics treatment, current state of waste plastics recycling (material recycling, thermal recycling), energy recovery by thermal recycling, quantity recyclable from waste plastics, energy consumption and cost for waste plastics recycling, effect and impact of increase in waste plastics in case material ...
The purpose of this study is to develop the radioisotope tracer technology, which can be used in solving industrial and environmental problems and to build a strong tracer group to support the local industries. In relation to the tracer technology in 1999, experiments to estimate the efficiencies of a sludge digester of a waste water treatment plant and a submerged biological reactor of a dye industry were conducted. As a result, the tracer technology for optimization of facilities related to wastewater treatment has been developed and is believed to contribute to improve their operation efficiency. The quantification of the experimental result was attempted to improve the confidence of tracer technology by ECRIN program which basically uses the MCNP simulation principle. Using thin layer activation technique, wear of tappet shim was estimated. Thin layer surface of a tappet shim was irradiated by ...
ObjectivesObjectives Not AvailableDescriptionA collaborative study of the anaerobic treatment of wastes containing recalcitrant and inhibitory compounds using the SERC Anaerobic facility, in particular biomass structure, monitoring and control, catabolism and toxicity, pre-acidification and microbial growth and mesophilic and thermophilic lignocellulose degradation.~%~
This report estimates the economic and financial effects of compliance with the proposed effluent limitations guidelines and standards for the Centralized WasteTreatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts...
This analysis, submitted in support of proposed effluent limitations guidelines and standards for the centralized wastetreatment (CWT) industry, investigates the cost-effectiveness of 24 regulatory options, representing all possible combinations of nine ...
The Waste Management Project manages and integrates (non-TWRS) waste management activities at the site. Activities include management of Hanford wastes as well as waste transferred to Hanford from other DOE, Department of Defense, or other facilities. This work includes handling, treatment, storage, and disposal of radioactive, nonradioactive, hazardous, and mixed solid and liquid wastes. Major Waste Management Projects are the Solid Waste Project, Liquid Effluents Project, and Analytical Services. Existing facilities (e.g., grout vaults and canyons) shall be evaluated for reuse for these purposes to the maximum extent possible.
This study examined the atmospheric pollution created by some wastetreatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for wastetreatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as ...
Since 1976 the Austrian Research Centre Seibersdorf has the task to collect, treat and store radioactive waste (Radwaste) arising in Austria. Within the Department of Waste Management a variety of appropriate treatment systems are installed. For storing unconditioned and conditioned waste proper storage-halls are available. The collection of Radwaste is carried out using 100 l drums, for the conditioned waste the 200 l drum concept is used. The interim storage of conditioned waste is done at Seibersdorf until a final repository is built. The present plan foresees one to be in operation at the year 2012. (author).
The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)
This document presents the details of the implementation of the Site Treatment Plan developed by Ames Laboratory in compliance with the Federal Facilities Compliance Act. Topics discussed in this document include: implementation of the plan; milestones; annual updates to the plan; inclusion of new waste streams; modifications of the plan; funding considerations; low-level mixed wastetreatment plan and schedules; and TRU mixed waste streams.
Two of the US Department of Energy's (DOE) nuclear waste management-related goals are to ensure that waste management is not an obstacle to the further development of light-water reactors and the closure of the nuclear fuel cycle and to fulfill its institutional responsibility for providing safe storage and disposal of existing and future nuclear wastes. As part of its approach to achieving these goals, the Office of Remedial Action and Waste Technology of DOE established what is now called the Nuclear WasteTreatment Program (NWTP) at the Pacific Northwest Laboratory during the second half of FY 1982. To support DOE's attainment of its goals, the NWTP is to provide technology necessary for the design and operation of nuclear wastetreatment facilities by commercial enterprises as part of a licensed ...
The ANDRA, the French national agency of radioactive wastes, is organizing today the information needs of tomorrow. The aim is to allow the future generations to have access to the knowledge of the existence of subsurface radioactive waste facilities and to understand the context and technologies of such facilities. The storage of this information is made on 'permanent paper', a high resistant paper with a lifetime of 600 to 1000 years. An updating of these data is made every 5 years for each waste disposal center. Another project, still in progress, concerns the memory management of deep geologic waste disposal facilities for which the time scale to be considered is of the order of millennia. (J.S.)
Building 922 houses all of SNL/California`s ES and H Departments: Health Protection, Environmental Protection, Safety, and Environmental Operations. It covers approximately 10,000 square feet and houses about 80 people. The office personnel generate nonhazardous solid office wastes in their daily activities. To determine the types and amounts of waste generated, a special PPOA sorting team sorted all of the trash collected from the building for a period of one-week (including paper and aluminum cans in the recycling bins). The team sorted the trash into major categories: paper, plastic, metals, glass, wet garbage, rest room waste, and miscellaneous materials. They then sorted it into subcategories within each major category. Rest room waste was collected but not sorted. The waste in each category was weighed separately. The total amount of ...
The fundamental points to be considered in a wastetreatment system for a country like Japan, where the final disposal method has not been decided and the wastes have to be stored in the power plants, are volume reduction of the wastes, safe storage of the wastes in the plant, and flexibility regarding the final disposal. A system has been developed that consists of a thin film evaporator for the direct solidification of the liquid waste, a pelletizer for producing hard pellets from the powdered wastes, a pellet storage unit, and a solidification unit for the final disposal. A pilot plant with wastetreatment capacity of 200 kg/h was built in 1976 and has proved the system feasibility. This paper reports on pilot plant tests of the thin film evaporator and other components, tests on pellet ...
The fundamental points to be considered in a wastetreatment system for a country like Japan, where the final disposal method has not been decided and the wastes have to be stored in the power plants, are volume reduction of the wastes, safe storage of the wastes in the plant, and flexibility regarding the final disposal. A system has been developed that consists of a thin film evaporator for the direct solidification of the liquid waste, a pelletizer for producing hard pellets from the powdered wastes, a pellet storage unit, and a solidification unit for the final disposal. A pilot plant with wastetreatment capacity of 200 kg/h was built in 1976 and has proved the system feasibility. This paper reports on pilot plant tests of the thin film evaporator and other components, tests on pellet ...
In a treatment system of radioactive waste solution including sodium sulfate generated from a boiling water type nuclear reactor, waste solution is fed into a thin film evaporator where the waste solution is evaporated and made into powder while precipitating in a peripheral surface of the evaporator vessel. The surface of the precipitated solid is wiped by rotating wiper blades and removed off as radioactive solid powder. The rotational speed of a rotor to which the wiper blades are secured is controlled at a minimum and necessary rotational speed which contributes to make the waste solution into the powder so that the rate of worn out of the wiper blade is decreased.
Hospital wastes comprises approximately 80% domestic waste components, also known as non-risk waste and 20% hazardous or risk waste. The 20% of the hospital waste stream or the risk waste (also known as infectious, medical, clinical wastes) comprises components which could be potentially contaminated with infections, chemical or radioactive agents. Therefore, it should be handled and disposed of in such a manner as to minimize potential human exposure and cross-contamination. Hospital risk waste and be subdivided into seven general categories as follows: infections, anatomical/pathological, chemical, pharmaceutical, radioactive waste, sharps and pressurised containers. These waste categories are generated by many types of health care establishments, including hospitals, clinics, ...
A nation-wide survey of natural radioactivity in building materials was conducted during 1982-1984. Samples including industrial wastes, by-products and common building materials were collected from main building material manufactories in 29 provinces except Taiwan. The results of exposure rates, specific activities and release rate for "2"2"2Rn are presented. The specific activities of common materials are listed in declining order as follows: clay bricks > common concrete and sandstones > limes and ordinary cement. The highest level was found in breeze bricks made of stone coal, phosphogypsum and red mud with high intrinsic radioactivity. Therefore, these raw materials should be strictly controlled in manufacturing building materials. The measurement results also showed that the typical specific activities of common building materials in our country were ...
More important than waste generation numbers, the pollution prevention and waste minimization successes achieved at Hanford in 1993 have reduced waste and improved operations at the Site. Just a few of these projects are: A small research nuclear reactor, unused and destined for disposal as low level radioactive waste, was provided to a Texas University for their nuclear research program, avoiding 25 cubic meters of waste and saving $116,000. By changing the slope on a asphalt lot in front of a waste storage pad, run-off rainwater was prevented from becoming mixed low level waste water, preventing 40 cubic meters of waste and saving $750,000. Through more efficient electrostatic paint spraying equipment and a solvent recovery system, a paint shop reduced hazardous waste by 3,500 kilograms, saving ...
An examination of chemical and radiological characteristics of RI organic liquid waste, wet oxidation by Fenton reaction and decomposition liquid wastetreatment process were studied. These items will be applied to develop the equipment of wet oxidation and decomposition liquid wastetreatment mixed processes for the safe treatment of RI organic liquid waste which is consisted of organic solvents such as toluene, alcohol and acetone. Two types of toluene solutions were selected as a candidate decomposition material. As for the first type, the concentration of toluene was above 20 vol percent. As for the second type, the solubility of toluene was considered. The decomposition ration by Fenton reaction was above 95 percent for both of them. From the adsorption equilibrium tests, a -Na{sup +} substituted/acid treated activated carbon and ...
The bibliography contains citations concerning wastetreatment and disposal in the food processing industry. Methods, equipment, and technology are considered. References discuss waste heat recovery and examine treatment of wastes resulting from meat and seafood processing, dairy and beverage production, and fruit and vegetable processing. The citations explore conversion of the treated waste to fertilizer and for use in animal feeds, combustion for energy production, biogas production, and composting. The recovery and recycling of usable chemicals from the food waste are also covered. Food packaging recycling is considered in a related bibliography. (Contains 250 citations and includes a subject term index and title list.)
Liquid radioactive wastetreatment method of using evaporator was widely used from Kori 1 to Uljin 3 and 4, but a liquid radioactive wastetreatment equipment that uses an ion exchange method instead of an evaporator was adopted aiming to minimize amount of radioactive waste and radiation exposure. However, the same equipment was introduced and applied for the first time in Korea and had experienced difficulties in securing credibility for the equipment and handling of liquid radioactive waste with inadequate data about performance and experience in operation and maintenance. In this study, examination, application and effect analysis was performed on the optimization measure for handling liquid radioactive waste of Yonggwang Nuclear Power Unit 5 and 6(YGN 5 and 6) that applies an ion exchange method
The work of this association is cut according to 6 axes. Three publications: radiological quality of marine and continental waters of the Normandy coast (synthesis 1997 and 1998); preliminary study of the iodine 129 distribution in the environment of the reprocessing plant of La Hague with terrestrial moss (Homalotecium sericeum); radiological surveillance of the aquatic environment of the nuclear facilities on the area of La Hague (1997 and 1998). The second axis concerns the radiation protection with a campaign of radon measures in a school of the Vire rural district (june 1999). The third part is devoted to the radioecology with the surveillance of radioactivity in the aquatic continental environment of nuclear facilities and the radioecological surveillance (1999) of the building site of Cogema la Hague in the area of tidal range of the Moulinets cove. The fourth part concerns the radioactive waste and environment, with the study of the ...
By presenting some case studies, this paper analyzes China`s situation with regard to hazardous waste: its environmental trade, treatment, and management. The paper describes China`s experiences with the environmental trade of hazardous waste in both the internal and international market. Regulations for managing the import of waste are discussed, as are China`s major approaches to the trading of hazardous waste both at home and overseas. The major reasons for setting up the Asian-Pacific Regional Training Center for Technology Transfer and Environmental Sound Management of Wastes in China and the activities involved in this effort are also described. 1 tab.
A self contained continuous power generation system as described at INTELEC 1979, was successfully commissioned and put into service in a major communications centre at Cardiff in Wales. The objective was to provide all telecommunications equipment and electrical building engineering services from a dual fuel enginegenerating plant, and to recover waste heat energy to heat or cool the building. The plant, which is fully automatic, comprises five 1300kW engines using natural gas or diesel oil, and associated waste heat boiler and chiller systems. This paper reviews the functioning of the plant during its first three years of operation.
Concentrations of 226Ra, 232Th, and 40K measured in bauxite waste, local building materials, and soils are presented and used in model equations to estimate the effective gamma dose-equivalent increments over background in the center of a standard-sized room in a prototype house. Calculated and measured values compare reasonably well.
This report contains preconceptual designs and planning level life-cycle cost estimates for managing hazardous waste. The report`s information on treatment, storage, and disposal modules can be integrated to develop total life-cycle costs for various waste management options. A procedure to guide the US Department of Energy and its contractor personnel in the use of cost estimation data is also summarized in this report.
The present report is final report from a study on characterisation of radioactive waters in the Nordic countries. The study has mainly been focused on long-lived low and intermediate level radioactive waste. Methods to measure or estimate the activity content and the general composition are discussed. Recommendations are given regarding characterisation of waste under treatment and characterisation of already produced waste packages. (au).
The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970's, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in ...
The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970`s, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in ...
The Mixed Waste Management Facility, or MWMF, has been proposed as a national testbed facility for the demonstration and evaluation of technologies that are alternatives to incineration for the treatment of mixed low-level waste. The facility design will enable evaluation of technologies at pilot scale, including all aspects of the processes, from receiving and feed preparation to the preparation of final forms for disposal. The MWMF will reduce the risk of deploying such technologies by addressing the following: (1) Engineering development and scale-up. (2) Process integration and activation of the treatment systems. (3) Permitting and stakeholder issues. In light of the severe financial constraints imposed on the DOE and federal programs, DOE/HQ requested a study to assess the cost benefit for the MWMF given other potential alternatives to meet wastetreatment ...
The basic principle of the green building philosophy is to design buildings that consider environmental performance. Residential and commercial buildings in Canada consume about 30 per cent of the total secondary energy use and are responsible for approximately 29 per cent of carbon dioxide equivalent greenhouse gas emissions and many other wastes. An optimization model was developed which minimizes life cycle cost and life cycle environmental impact. The model distinguishes different energy sources and incorporates their impacts, such as resource depletion, global warming and acidification. The model also considers design variables such as window type, orientation, building orientation, window-to-wall ratio, wall type and roof type. The model can be used to identify optimum green building designs for given conditions. The model uses expanded cumulative exergy ...
The U.S. Department of Energy (DOE) Headquarters and associated contractors have developed an IBM PC-based software package that estimates costs, schedules, and public and occupational health risks for a range of mixed-waste management options. A key application of the software package is the comparison of various waste-treatment options documented in the draft Site Treatment Plans prepared in accordance with the requirements of the Federal Facility Compliance Act of 1992. This automated Systems Analysis Methodology consists of a user interface for configuring complexwide or site-specific waste-management options; calculational algorithms for cost, schedule and risk; and user-selected graphical or tabular output of results. The mixed-waste management activities modeled in the automated Systems Analysis Methodology include waste storage, characterization, ...
This paper described the basic design of Alpha Aqueous WasteTreatment Process in NUCEF. Since various experiments using the TRU (transuranium) elements are carried out in NUCEF, wastes containing TRU elements arise. The liquid wastes in NUCEF are categorized into three types. Decontamination and volume reduction of the liquid waste mainly of recovery water from acid recovery process which has lowest radioactive concentration is the most important task, because the arising rate of the waste is large. The major function of the Alpha Aqueous WasteTreatment Process is to decontaminate the radioactive concentration below the level which is allowed to discharge into sea. Prior the process design of this facility, the followings are evaluated:property and arising rate of the liquid waste, room space to ...
The need for efficient management of industrial chemical wastes, especially those considered hazardous or radioactive, is receiving increased attention in the United States. During the past five years, several federal laws have addressed the establishment of stronger programs for the control of hazardous and residual wastes. At a facility such as Oak Ridge National Laboratory (ORNL), an efficient waste management program is an absolute necessity to ensure protection of human health and compliance with regulatory requirements addressing the treatment and disposal of hazardous, nonhazardous, and radioactive wastes. This report highlights the major regulatory requirements under which the Laboratory must operate and their impact on ORNL facilities. Individual waste streams, estimates of quantities of waste, and current waste ...
Different types of radioactive liquid waste are being generated at Advanced Fuel Fabrication Facility (AFFF), Tarapur during the quality control analysis of the mixed oxide (MOX) fuel pellets. A laboratory scale study was performed for treatment of such waste. Some of the waste streams originating from U and Pu analysis contain components like sulphate and phosphate which interfere during chemical precipitation of alpha activity from the waste. Various chemical co-precipitation experiments were conducted based on alkaline precipitation. Reductive precipitation using sodium sulphite and Fe(II) was found to be promising and the same was suggested for plant scale treatment. (author)
This report estimates the economic and financial effects and the benefits of compliance with the proposed effluent limitations guidelines and standards for the Centralized WasteTreatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts in terms of changes in the profitability of wastetreatment operations at CWT facilities, changes in market prices to CWT services, and changes in the quantities of waste management at CWT facilities in six geographic regions. EPA has also examined the impacts on companies owning CWT facilities (including impacts on small entities), on communities in which CWT facilities are located, and on environmental justice. EPA examined the benefits to society of the CWT effluent limitations guidelines and standards by examining cancer and non-cancer health effects of the regulation, recreational benefits, and cost savings to ...
Information about current and projected waste generation as well as available treatment, storage, and disposal (TSD) capabilities and needs is crucial for effective, efficient, and safe waste management. This is especially true for large corporations that are responsible for multisite operations involving diverse and complex industrial processes. Such information is necessary not only for day-to-day operations, but also for strategic planning to ensure safe future performance. This paper reports on some methods developed and successfully applied to obtain requisite information and to assist waste management planning at the corporate level in a nationwide system of laboratories and industries. Waste generation and TSD capabilities at selected US Department of Energy (DOE) sites were studied. 1 ref., 2 tabs.
After the publication of the 2nd progress report of geological disposal of TRU waste in Japan, policy and general scheme of future study for the waste disposal in Japan was published by ANRE and JAEA. This annual report summarized aim and progress of individual problem, which was assigned into JAEA in the published policy and general scheme. The problems are as follows; characteristics of TRU waste and its geologic disposal, treatment and waste production, quality control and inspection methodology for waste, mechanical analysis of near-field, data acquisition and preparation on radionuclides migration, cementitious material transition, bentonite and rock alteration in alkaline solution, nitrate effect, performance assessment of the disposal system and decomposition of nitrate as an alternative technology. (author)
In recent years, there has been increasing demand for resource-recycling of waste plastic, especially due to the introduction of legislation on recycling of materials used for packages of household goods. Methods of recycling waste plastic from household goods are currently still under development, and appropriate techniques to deal with such waste are required. Toshiba has developed a technique to dehydrochlorinate plastic containing polyvinyl chloride (PVC). This paper introduces our petrolization and dehydrochlorination system for waste plastic containing PVC. (author)
There is a model on the Oak Ridge Reservation which provides requirements for determining capacities and capabilities related to low-level, hazardous, and mixed wastes. In FY 1987, the model will be sufficiently advanced to provide various waste management scenarios. These scenarios will be compared technically, operationally, and financially by use of waste characterization data and process simulators that are currently under development. The results of the process simulations will be used to help identify wastetreatment, storage, and disposal technologies that need to be demonstrated prior to full-scale development for DOE use. The information derived from this effort will be made available to all DOE facilities.
This document establishes the minimum training requirements for the Plutonium Finishing Plant (PFP) personnel who are responsible for management of dangerous waste. The training plan outlines training requirements for handling of solid dangerous waste during generator accumulation and liquid dangerous waste during treatment and storage operations. The implementation of this training plan will ensure the PFP facility compliance with the training plan requirements of Dangerous Waste Regulation. Chapter 173-303-330. Washington Administrative Code (WAC). The requirements for such compliance is described in Section 11.0 of WHC-CM-7-5 Environmental Compliance Manual.
Describes the wastes produced and the waste disposal methods used at BEWAG power plants. Wastes covered include fly ash, fluidized bed ash, gypsum from flue gas desulfurization and evaporation residues. Disposal methods include using ashes and gypsum to make building materials. Despite many years of experience in the utilization and disposal of residues from coal-fired power stations BEWAG have not encountered any disposal problems. 5 tabs.
What technical, economic and institutional factors make radioactive and/or hazardous waste management technologies publicly acceptable? The goal of this paper is to initiate an identification of factors likely to render radioactive and hazardous waste management technologies publicly acceptable and to provide guidance on how technological R&D might be revised to enhance the acceptability of alternative waste management technologies. Technology development must attend to the full range of technology characteristics (technical, engineering, physical, economic, health, environmental, and socio-institutional) relevant to diverse stakeholders. ORNL`s efforts in recent years illustrate some attempts to accomplish these objectives or, at least, to build bridges toward the integrated design of waste management technologies.
Within the framework of efforts to optimize state-of-the-art waste disposal methods, this research project makes a theoretical analysis of the propagation behaviour of pollutants from landfills and waste incineration plants into the immediate vicinity of such plants. In order to judge the propagation of pollutants near the above-mentioned waste disposal facilities, a calculation program was developed within the framework of this research project which permits simulation of the propagation of such emissions in a three-dimensional space by application of an Eulerian grid model. It is capable of realistically representing fluid flow conditions and pollutant concentrations for certain points of times within the complex building patterns of such plants, for randomly chosen atmospheric conditions. (orig.)
Logistics modeling is a powerful analytical technique for effective planning of waste storage, treatment, and disposal activities. Logistics modeling facilitates analyses of alternate scenarios for future waste flows, facility schedules, and processing or handling capacities. These analyses provide an increased understanding of the specific needs for waste storage, treatment, and disposal while adequate time remains to plan accordingly. They also help to determine the sensitivity of these needs to various system parameters. This paper discusses a logistics modeling system developed by the Pacific Northwest Laboratory (PNL) to aid in solid waste planning for a large industrial complex managing many different types and classifications of waste. The basic needs for such a system are outlined, and the approach adopted in developing the system is ...
This final report for the Swiss Federal Office of Energy (SFOE) is one of a series of reports concerning municipal development in various cities in Switzerland. The four city districts involved include Basel (Gundeldinger Feld), Lausanne (Bellevaux), Lucerne (Basel-/Bernstrasse) and Zurich (Werdwies). This paper takes a look at aspects of building ecology. In the four areas, the following building types and projects were examined with respect to their ecology: Basel: conversion of commercial premises to a community centre, Lausanne and Lucerne: Enhancement of residential areas, Zurich: a new residential building. Criteria examined include general building ecology, building materials, raw materials, toxic substances, recycling, maintenance and deconstruction, energy for heating and hot water, grey energy, electricity, ground usage, water, wastes and public ...
The Oak Ridge National Laboratory (ORNL) is developing a treatment process for remote-handled (RH) liquid transuranic mixed waste governed by the concept of minimizing the volume of waste requiring disposal. This task is to be accomplished by decontaminating the bulk components so the process effluent can be disposed with less risk and expense. Practical processes have been demonstrated on the laboratory scale for removing cesium 137 and strontium 90 isotopes from the waste, generating a concentrated waste volume, and rendering the bulk of the waste nearly radiation free for downstream processing. The process is projected to give decontamination factors of 10{sup 4} for cesium and 10{sup 3} for strontium. Because of the extent of decontamination, downstream processing will be contact handled. The transuranic, radioactive fraction of the mixed ...
Atomic Energy of Canada Limited (AECL) operates the WasteTreatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of ...
Atomic Energy of Canada Limited (AECL) operates the WasteTreatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of ...
As waste disposal methods and long-term precautionary care of the environment are closely related, disposal of non-avoidable and intractable residual products is to be viewed primarily from a safety angle. Also, thermal processes airm mainly at treatment, not utilization. 'Safety' in this context addresses both the environmental compatibility of the products and the process itself. In other words, only mature techniques (i.e., safe, proven ones) are employed. (orig.)
This report assesses the water quality related benefits that would be expected if the US Environmental Protection Agency (EPA) adopts the proposed effluent limitations, guidelines and pretreatment standards for the Centralized WasteTreatment (CWT) Industry. EPA estimates that under baseline conditions 205 CWT facilities discharge approximately 5.22 million lbs/year of metal and organic pollutants.
The objective of the ''Waste Handling Building Conceptual Study'' is to develop proposed design requirements for the repository Waste Handling System in sufficient detail to allow the surface facility design to proceed to the License Application effort if the proposed requirements are approved by DOE. Proposed requirements were developed to further refine waste handling facility performance characteristics and design constraints with an emphasis on supporting modular construction, minimizing fuel inventory, and optimizing facility maintainability and dry handling operations. To meet this objective, this study attempts to provide an alternative design to the Site Recommendation design that is flexible, simple, reliable, and can be constructed in phases. The design concept will be input to the ''Modular Design/Construction and Operation Options ...
Radioactive wastes are generally classified into 3 type depending on their physical property: liquid, solid and gaseous type. State-of -the art concerning liquid wastetreatment has already been published; KAERI/TR-1315/99. Solid wastes classification package and treatment method will be studied to effectively manage them during the practical decommissioning work. All of the spent fuel produced during the operation of the TRIGA Mark-2 and 3 have been transported to the US last year, 1998, according to the spent fuel management strategy set-up by the US government for the non-proliferation of nuclear energy. Solid wastes are mainly all equipment existing inside of the reactors, activated concrete among the bio-shielded concrete, pipes, pimps, resin filter and it's housings, heat-exchangers, liquid waste storage tanks, to radioactive ...
Research at the Savannah River Technology Center aided development of a technical design basis for a WasteTreatment Plant (WTP) to pre-treat and vitrify Hanford tank waste as part of the River Protection Project (RPP). The research addresses safety concerns, process optimization, and waste form compliance. This program will provide technical data to ensure that the process functions as it was designed and minimizes costs.
The Transuranic Waste Form Characterization and Data Base (Volume 1) provides a wide range of information from which a comprehensive data base can be established and from which standards and criteria can be developed for the present NRC waste management program. Supplementary information on each of the areas discussed in Volume 1 is presented in Appendices A through K (Volumes 2 and 3). The structure of the study (Volume 1) is outlined and appendices of Volumes 2 and 3 correlate with each main section of the report. The Executive Summary reviews the sources, quantities, characteristics and treatment of transuranic wastes in the United States. Due to the variety of potential treatment processes for transuranic wastes, the end products for long-term storage may have corresponding variations in quantities and characteristics.
Zirconium phosphate was one of the earliest inorganic ion-exchange suggested for removing strontium and cesium from aqueous nuclear waste. This paper studied ionic exchange to remove Cs-137 and Sr-90 by using different cationic of zirconium phosphate. In this case the parameters studied were the effect of temperature and ion concentration to percent up take and distribution coefficients. It is also conducted the study on column experiments to determine the breakthrough curves for Cs-137 and Sr-90. The result showed the potential of use of zirconium phosphate in radioactive wastetreatment. (author)
Reverse osmosis is a simple process and has relatively high decontamination factor compared to other processes used for the treatment of radioactive liquid waste. Furthermore the quantity of secondary waste of this process is small. In this study, test solution containing nine elements such as cesium, strontium, cobalt etc. in chloride forms are treated by reverse osmosis. Permeate rate decreases as the increase of osmotic pressure of feed solution and is expressed by linear equation. Decontamination factor of cations of univalency is more than ten, and about one tenth of that of bivalency. Decontamination factors of all the elements used in this experiment are approximately estimated using the solution-diffusion model.
Reverse osmosis is a simple process and has relatively high decontamination factor comparing to other processes used for the treatment of radioactive liquid waste. Furthermore the quantity of secondary waste of this process is small. In this study, test solution containing nine elements such as cesium, strontium, cobalt etc. in chloride forms are treated by reverse osmosis. Permeate rate decreases as the increase of osmotic pressure of feed solution and is expressed by linear equation. Decontamination factor of cations of univalency is more than ten, and about one tenth of that of bivalency. Decontamination factors of all the elements used in this experiment are approximately estimated using the solution-diffusion model. (author).
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches `A' and `B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards f...
;Table of Contents: Legal authority; Summary of proposed regulations; Industry definition and waste streams; Industry description; Data and information gathering; Selection of pollutant parameters; Drilling wastes-characterization, control, and treatment technologies; Produced water-characterization, control, and treatment technologies; Miscellaneous waste-characterization, control, and treatment technologies; Cost and pollutant loading determination of drilling fluids and drill cuttings; Compliance cost and pollutant load determination of produced water; Compliance cost and pollutant load determination of well treatment, workover, and completion fluids; Cost and pollutant loading determination of deck drainage; Options selection-rationale and total costs; Pretreatment standards; Non-water quality environmental impacts and other factors; ...
The reduction of emission from power plants of the public power industry inevitably leads to more and more residual products being obtained which require utilization. Traditionally, the building and building materials industry as well as, for a number of years, the gypsum industry have been the main customers processing these residual materials. To avoid having to tip them at landfills that are in short supply already, further uses are sought; so, for instance, in farming to ameliorate soil and fertilize plants. Relative to this subject, proposals are already available which are presented as lectures at the conference and discussed, together with practical knowledge and new investigation results. (BBR).
A testing program has been conducted by the Westinghouse Hanford Company to confirm the baseline waste form selection for use in Waste Receiving and Processing (WRAP) Module 2A. WRAP Module 2A will provide treatment required to properly dispose of containerized contact-handled, mixed low-level waste at the US Department of Energy Hanford Site in south-central Washington State. Solidification/stabilization has been chosen as the appropriate treatment for this waste. This work is intended to test cement-based, thermosetting polymer, and thermoplastic polymer solidification media to substantiate the technology approach for WRAP Module 2A. Screening tests were performed using the major chemical constituent of each waste type to measure the gross compatibility with the immobilization media and to determine formulations for more detailed testing. ...
US Department of Energy (DOE) Order 5820.2A was promulgated in final form on September 26, 1988. The order requires heads of field organizations to prepare and to submit updates on the waste management plans for all operations under their purview according to the format in Chap. 6, {open_quotes}Waste Management Plan Outline.{close_quotes} These plans are to be submitted by the DOE Oak Ridge Operations Office (DOE-ORO) in December of each year and distributed to the DP-12, ES&H-1, and other appropriate DOE Headquarters (DOE-HQ) organizations for review and comment. This document was prepared in response to this requirement for fiscal year (FY) 1994. The Oak Ridge National Laboratory (ORNL) waste management mission is reduction, collection, storage, treatment, and disposal of DOE wastes, generated primarily in pursuit of ORNL missions, in order to protect human health and safety ...
This paper describes the unique challenges involved in achieving compliance with the Resource Conservation and Recovery Act (Public Law 94-580) Land Disposal Restrictions (LDR) treatment standards for four types of mixed wastes generated throughout the U.S. Department of Energy (DOE) complex: (1) radioactively contaminated lead acid batteries; (2) radioactively contaminated cadmium-, mercury-, and silver-containing batteries; (3) mercury-bearing mixed wastes; and (4) radioactive lead solids. For each of these mixed waste types, the paper identifies the strategy pursued by DOE's Office of Pollution Prevention and Resource Conservation Policy and Guidance (EH-43) in coordination with other DOE elements and the U.S. Environmental Protection Agency (EPA) to meet the compliance challenge. Specifically, a regulatory interpretation was obtained from EPA agreeing that the LDR treatment ...
The purpose of this study is to extend the knowledge base for wetland treatment to include processes and substances of particular importance to small, on-site systems receiving oil and gas well waste water. Collection of data on the sorption of heavy metals and the degradation of toxic organics is one of the key tasks. The toxic organics phenolics and anthracene, and chromium and copper have been selected as target adsorbates. An information search was performed on oil refinery wastetreatment wetland systems.
Three samples of dusts generated by the non ferrous metallurgical industries are treated between 200 and 800 degree centigree in controlled oxidizing and reducing atmospheres. The objective of this study is to recover the valuable metals from these wastes. The treatments of these solids under oxidizing conditions at 700 degree centigree are well adapted for two samples. The totality of valuable elements are concentrated in the treatments residues. The use of hydrogen at 600 degree centigree, permits the removal of up to 100 % of valuable metals contained in the treated industrial wastes. The recovery rate of valuable metals (Pb, Zn, Cu) as well as the Global Decontamination Factor are reported. (Author) 9 refs.
The Department of Energy (DOE) currently operates four thermal treatment facilities that are permitted under regulations for hazardous waste combustors. As regulations become more stringent and public stakeholders become more influential, permitting these facilities is increasingly difficult. As they become more available, continuous emission monitors (CEMs) may offer the potential to assure regulators and the public of the safe operation of treatment facilities. The Mixed Waste Focus Area (MWFA) has participated in the development and testing of a variety of CEMs that could have application to DOE facilities.
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
This guidebook concerns the design of air-conditioning and air-treatment installations in recent and old buildings. The design of indoor atmosphere treatment systems is based on a rigorous and safe methodology. The following aspects are reviewed: situation of ambient air treatment, different aspects of a project, humid-air technique, principles of air treatment, basic conditions for a successful project, determination of enthalpy and hydric loads of rooms, design of ambient treatment systems, cold water production using a thermodynamical system, aeraulics, hydraulics, acoustics, logics of operation, forecasting of energy consumptions, global management of air-conditioning installations, ambient air-treatment systems. (J.S.)
The Army Reactor Area (ARA) II was constructed in the late 1950s as a test site for the Stationary Low Power Reactor No. 1 (SL-1). The SL-1 was a prototype power and heat source developed for use at remote military bases using a direct cycle, boiling water, natural circulation reactor designed to operate at a thermal power of 3,000 kW. The ARA II compound encompassed 3 acres and was comprised of (a) the SL-1 Reactor Building, (b) eight support facilities, (c) 50,000-gallon raw water storage tank, (d) electrical substation, (e) aboveground 1,400-gallon heating oil tank, (f) underground 1,000-gallon hazardous waste storage tank, and (g) belowground power, sewer, and water systems. The reactor building was a cylindrical, aboveground facility, 39 ft in diameter and 48 ft high. The lower portion of the building contained the reactor pressure vessel surrounded by gravel shielding. Above the pressure vessel, ...
In this report, research and development results on the bituminization of radioactive wastes are closely reviewed, especially those regarding wastetreatment technologies, waste solidifying procedures and the characteristics of asphalt and solidified forms. A new concept of the bituminization method is suggested in this report which can improve the characteristics of solidified forms. Stable solid forms with high leach resistance, high thermal resistance and good compression strength were produced by the suggested bituminization method, in which spent polyethylene from agricultural farms was added. This report can help further research and development of improved bituminized forms of radioactive wastes that will maintain long term stabilities in disposal sites. (author). 59 refs., 19 tabs., 18 figs
The Soviet Union does not currently have an overall radioactive waste management program or national laws that define objectives, procedures, and standards, although such a law is being developed, according to the Soviets. Occupational health and safety does not appear to receive major attention as it does in Western nations. In addition, construction practices that would be considered marginal in Western facilities show up in Soviet nuclear power and waste management operations. The issues involved with radioactive waste management and environmental restoration are being investigated at several large Soviet institutes; however, there is little apparent interdisciplinary integration between them, or interaction with the USSR Academy of Sciences. It is expected that a consensus on technical solutions will be achieved, but it may be slow in coming, especially for final disposal of high-level radioactive ...
The Soviet Union does not currently have an overall radioactive waste management program or national laws that define objectives, procedures, and standards, although such a law is being developed, according to the Soviets. Occupational health and safety does not appear to receive major attention as it does in Western nations. In addition, construction practices that would be considered marginal in Western facilities show up in Soviet nuclear power and waste management operations. The issues involved with radioactive waste management and environmental restoration are being investigated at several large Soviet institutes; however, there is little apparent interdisciplinary integration between them, or interaction with the USSR Academy of Sciences. It is expected that a consensus on technical solutions will be achieved, but it may be slow in coming, especially for final disposal of high-level radioactive ...
A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.
A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.
In the spring of 1991, the Environmental Protection Agency, Region 10 (EPA), launched an investigation into tanker waste disposal practices for vessels discharging ballast water at the Alyeska Pipeline Services Company's Ballast Water Treatment (BWT) facility and marine terminal in Valdez, Alaska. It had been alleged that the Exxon Shipping Company was transferring 'toxic wastes originating in California' to Valdez. In response, EPA decided to examine all waste streams generated on board and determine what the fate of these wastes were in addition to investigating the Exxon specific charges. An extensive Information Request was generated and sent to the shipping companies that operate vessels transporting Alaska North Slope Crude. Findings included information on cargo and fuel tank washings, cleaning agents, and engine room waste.
The aim of this study is to compare, from an environmental point of view, different alternatives for the management of municipal solid waste generated in the town of Castellon de la Plana (Spain). This town currently produces 207ton of waste per day and the waste management system employed today involves the collection of paper/cardboard, glass and light packaging from materials banks and of rest waste at street-side containers. The proposed alternative scenarios were based on a combination of the following elements: selective collection targets to be accomplished by the year 2015 as specified in the Spanish National Waste Plan (assuming they are reached to an extent of 50% and 100%), different collection models implemented nationally, and diverse treatments of both the separated biodegrad...
In the past years I have been dealing with the following aspects of waste planning: a) waste reduction (regarding particularly home composting); b) transformation and reorganisation of waste collection systems; c) experimental introduction of a new way to pay for waste collection and treatment services, from ''tax'' to ''tariff''. In these years, I have been a consultant for municipalities in the planning of these three points. In the city (Venice) and in the Region I come from (''Veneto'') there are some of the most important Italian experiences about them. (orig).
Measurements are presented of indoor radon levels made in a prototype house constructed partly of bauxite waste (red mud) and partly of conventional materials. The mud used contains higher than the average amounts of {sup 226}Ra and {sup 232}Th found in local building materials. The rates of exhalation of radon from the material used in the construction of the house are measured and employed with measured air change rates to make estimates of the average contribution of the various materials to the measured radon levels indoors. There is fairly good agreement between the two. The increment of radon related dose equivalents above background are also estimated and these are combined with previously determined gamma dose equivalents and used as a basis for assessing the acceptability of the practice of using red mud as a building material. (author)
Measurements are presented of indoor radon levels made in a prototype house constructed partly of bauxite waste (red mud) and partly of conventional materials. The mud used contains higher than the average amounts of "2"2"6Ra and "2"3"2Th found in local building materials. The rates of exhalation of radon from the material used in the construction of the house are measured and employed with measured air change rates to make estimates of the average contribution of the various materials to the measured radon levels indoors. There is fairly good agreement between the two. The increment of radon related dose equivalents above background are also estimated and these are combined with previously determined gamma dose equivalents and used as a basis for assessing the acceptability of the practice of using red mud as a building material. (author)
This article comments on the fact that there are only 17 energy-from-waste installations in operation in the U.S. and in this respect it lags behind other industrialized nations. Explanations for this gap include the relatively inexpensive garbage disposal as landfill, operating difficulties of some early plants and the high cost of building such facilities. There has been a recent push to build resource-recovery plants and it is believed that chemical companies will probably buy energy products from such plants. Hooker Chemical Co's new energy-from-waste plant at Niagra Falls, N.Y. is described, other companies involved in resource-recovery projects are mentioned, and it is hoped that more companies will invest in such plants.
Several U.S. Department of Energy organizations and the U.S. Bureau of Mines have been collaboratively conducting mixed wastetreatment process demonstration testing on the near full-scale graphite electrode submerged arc melter system at the Bureau`s Albany (Oregon) Research Center. An initial test series successfully demonstrated arc melter capability for treating surrogate incinerator ash of buried mixed wastes with soil. The conceptual treatment process for that test series assumed that buried waste would be retrieved and incinerated, and that the incinerator ash would be vitrified in an arc melter. This report presents results from a recently completed second series of tests, undertaken to determine the ability of the arc melter system to stably process a wide range of {open_quotes}as-received{close_quotes} heterogeneous solid mixed wastes containing high ...
A review of the various solidification agents and techniques that are currently available or potentially applicable for the solidification of low-level radioactive wastes is presented. An overview of the types and quantities of low-level wastes produced is presented. Descriptions of waste form matrix materials, the wastes types for which they have been or may be applied and available information concerning relevant waste form properties and characteristics follow. Also included are descriptions of the processing techniques themselves with an emphasis on those operating parameters which impact upon waste form properties. The solidification agents considered in this survey include: hydraulic cements, thermoplastic materials, thermosetting polymers, glasses, synthetic minerals and composite materials. This survey is part of a program supported by the United States ...
According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing ...
The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive wastetreatment. A non-radioactive simulated SBW was used based on the ...
The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive wastetreatment. A non-radioactive simulated SBW ...
The cold effluents (sanitary waste and decontaminated radioactive water) are flocculated with sodium phosphate and pumped through a trickling filter. The average decontamination obtained is about 86% for alpha emittera and 76% for beta emitters. The cool effluents (activity < 10/sup -3/ mu c/ml) can be treated by several methods. Provisions have been made for two successive chemical flocculations eventually followed by an adsorptlon. The warm wastetreatment (activity between 10/sup -3/ and 1 mu c/ml) is still in the experimental stage. The following methods are used: evaporation for some chemically contaminated wastes, browncoal filtration for reactor effluents, and a combination of chemical treatment and browncoal adsorption in other cases. (auth)
Twenty years after its building, the tertiary sector of La Defense district near Paris has been rehabilitated. The main reason is not only the age and wear of materials but the heating costs, the fire protection regulations, the search for a better air quality and air renewing with less dusts, smells and noise and a controlled moisture. This paper describes first the original installation of the Monge CB 6 office building and then the renovated installation: the central hot and cold air-treatment plant, the variable flow ventilation system, the air extraction and supply system threw the roofs and the pressure and thermal regulation of the installation. (J.S.)
... Carbon capture and storage Waste Prevention and Recycling EU clean air strategy Environmental liability: Applying the 'polluter pays' principle What goes around ...comes around: Recycling and climate change Behind closed doors: Air quality in buildings Keeping cool with refrigerants: The F-gas review Regions fighting climate ...
...six months Organising local tours of the area for up to 1000 affected families in the Izu Penninsula area around Mount Fuji Mobile food stalls that wlll serve up to 10,000 bottles of water and 10,000 servings of food Mobile human waste disposal units Building northern Japan support committees Browser does not support script. Browser does not support script. For further information, please contact: Garry Campbell, PR & ...
The manual enhances and simplifies the work of those architects and engineers whose practice includes the analysis and modification of existing buildings to reduce both fuel consumption and operating costs. A review of the principles of energy use and conservation is given. The manual also provides a step-by-step methodology for assessing and improving the year-round energy performance of buildings, as well as a series of forms, charts, and nomographs designed to serve as day-to-day tools in the energy professional's toolbox. After a cost-benefit analysis is prepared for each conservation opportunity, the owner will be able to implement decisions based on projected energy savings and calculate investment costs, operational changes, and payback periods. Each of these considerations is accorded a detailed treatment.
In order to produce a quality grout from LLW using hydraulic cements, proper conditioning of the waste is essential for complete cement curing. Several technologies were investigated as options for conditions. Since the LLW is dilute, removal of all, or most, of the water will significantly reduce the final waste volume. Neutralization of the LLW is also desirable since acidic liquids to not allow cement to cure properly. The nitrate compounds are very soluble and easily leached from solid waste forms; therefore, denitration is desirable. Thermal and chemical denitration technologies have the advantages of water removal, neutralization, and denitration. The inclusion of additives during thermal treatment were investigated as a method of forming insoluable waste conditions.
This final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project that involves the building of a joint biogas plant serving 60 farmers and industrial companies with an annual processing capacity of 45,000 tons. The plant is to produce biogas to be fed into the gas mains and will not only reduce nutrient loading in a region with an extensive livestock industry but also reduce carbon dioxide emissions by using the gas as a motor fuel. The importance of the project with respect to both the environment and energy policy-making is discussed and the costs involved are examined. Details are presented on the technology used and on the material flows involved. Figures are quoted on energy production. The various biogenic substrates used, such as food wastes, waste oils, cereal wastes and used mushroom substrates, are discussed, as is the use of the solid and liquid outputs of the ...
Applications using microwave energy in the chemical processing industry have increased within the last ten years. Recently, interest in wastetreatment applications process development, especially solidification, has grown. Microwave waste processing offers many advantages over conventional wastetreatment technologies. These advantages include a high density, leach resistant, robust waste form, volume and toxicity reduction, favorable economics, in-container treatment, good public acceptance, isolated equipment, and instantaneous energy control. The results from the {open_quotes}cold{close_quotes} demonstration scale testing at the Rocky Flats nuclear weapons facility are described. Preliminary results for a transuranic (TRU) precipitation sludge indicate that volume reductions of over 80% are achievable over the current immobilization ...
It is an object of the claimed invention to combine chemical treatment with microfiltration process to treat groundwater, leachate from contaminated soil washing, surface and run-off waters contaminated with toxic metals, radionuclides and trace amounts of organics from variety of sources. The process can also be used to treat effluents from industrial processes such as discharges associated with smelting, mining and refining operations. Influent contaminants amenable to treatment are from a few mg/L to hundreds of mg/L. By selecting appropriate precipitation, ion exchange and adsorption agents and conditions, efficiencies greater than 99.9 percent can be achieved for removal of contaminants. The filtered water for discharge can be targeted with either an order of magnitude greater or lower than contaminant levels for drinking water.
This paper describes an innovative use of post-consumer waste HDPE plastic in concrete as a soft filler. A reference concrete was proportioned to have the 28-day compressive strength of 5000 psi (35 MPa). A high-density plastic was shredded into small particles for use in the concrete. These particles were subjected to three chemical treatments (water, bleach, bleach + NaOH) to improve their bonding with the cementitious matrix. The plastic particles were added to the concrete in the range of 0--5% of total mixture by weight. Compressive strengths were measured for each test mixture. The results showed that chemical treatment has a significant effect on performance of the plastic filler in concrete. Of the three treatments used on the plastic, the best performance was observed with the alkaline bleach treatment (bleach + NaOH) with respect to compressive strength of concrete.
This document includes the following topics: Background; Data Collection; Scope/Applicability of the Proposed Regulation; Description of the Industry; Industry Subcategorization; Pollutants of Concern for the Centralized WasteTreatment Industry; Pollutants Selected for Regulation; Wastewater Treatment Technologies; Regulatory Options Considered and Selected for Basis of Regulation; Long-Term Averages, Variability Factors, and Limitations and Standards; Cost of Treatment Technologies; Pollutant Loading and Removal Estimates; Non-Water Quality Impacts; Implementation; Analytical Methods and Baseline Values; List of Definitions; List of Acronyms; Appendix A--Pollutant Groups; Appendix B--Listing of Characerization Data From Non-Hazardous Oils Facilities; Appendix C--Listing of Daily Influent and Effluent Measuements; Appendix D--Facility-Specific Compliance Costs; Appendix E--Attachements to Chapter 10; ...
Described and discussed in this paper are radiation processes and their advantages over the conventional techniques. Radiation sterilization of medical products, food irradiation, wood plastic composites, and radiation treatment of sewage and waste waters are presented. The Philippine experience in using these technologies, its problems and barriers are also given. (ELC).
More than 100 old mine dumps active mine tailing ponds and granite quarries were investigated in South-West Germany to evaluate their potential impact on the environment caused by natural radioactive materials and by toxic metals. Five mine sites were monitored for a longer period according to their radon impact on the environment. They showed seasonal variations greater than a factor of 5 at some places. The annual mean radon concentration over granitic soil was found to be about 44 Bq.m/sup -3/ while very near the dumps more than 370 Bq.m/sup -3/ were usual. Radium concentrations up to 185 Bq.kg/sup -1/ were found in certain types of abandoned mine dumps. Some of the waste rock piles investigated are in the immediate neighbourhood of buildings and some old mine establishments are now used as homes. In these dwellings passive time integrating radon dosemeters have been exposed for up to a three month period. The average radon concentrations in ...
An economic analysis of the potential advantages of alternatives for recycling and reusing equipment now stored in Building 865 at the Rocky Flats Plant (RFP) in Colorado has been conducted. The inventory considered in this analysis consists primarily of metallurgical and process equipment used before January 1992, during development and production of nuclear weapons components at the site. The economic analysis consists of a thorough building inventory and cost comparisons for four equipment dispositions alternatives. The first is a baseline option of disposal at a Low Level Waste (LLW) landfill. The three alternatives investigated are metal recycling, reuse with the government sector, and release for unrestricted use. This report provides item-by-item estimates of value, disposal cost, and decontamination cost. The economic evaluation methods documented here, the simple cost comparisons presented, and the data provided as ...
In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it ...
In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it ...
The technology developed here will exploit the ability of microorganisms to remove dissolved metals from aqueous solutions. Microbial sorbents for uranium will be immobilized biosorbents will be deployed ex situ within flow-through reactors for the continuous or semicontinuous treatment of recovered wastewaters. The proposed technology will primarily be applied within a pump-and-treat process using immobilized biosorbents for the large-scale, long-term remediation of uranium-laden surface water or groundwater impoundments (environmental restoration). The technology may be equally useful as an ``end-of-pipe`` treatment of process effluents (waste management). Successful operation of this process will achieve immobilization of the targeted waste and accompanying volume reduction.
In the well-known devices for increasing the decontamination factor in the treatment of radioactive waste water by evaporation, which consist of narrowing devices with evaporator sump and condenser, droplets of liquid and solid particles are carried over from the breeder space, which are radioactive and therefore make the decontamination factor worse. Better results are obtained if one places a fibre bed filter between the evaporator sump and the condenser, preferably in a horizontal connecting pipe between the evaporator sump and the condenser.
Abstract Elevated temperatures resulting from climate change pose a clear threat to reef-building corals; however, the traits that might influence corals- survival and dispersal during climate change remain poorly understood. Global gene expression profiling is a powerful hypothesis-forming tool that can help elucidate these traits. Here, we applied a novel RNA-Seq protocol to study molecular responses to heat and settlement inducers in aposymbiotic larvae of the reef-building coral Acropora millepora. This analysis of a single full-sibling family revealed contrasting responses between short- (4-h) and long-term (5-day) exposures to elevated temperatures. Heat shock proteins were up-regulated only in the short-term treatment, while the long-term treatment induced the down-regulation of rib...
In addition to the goal of ensuring waste disposal, thermal wastetreatment has always been aimed at the energy-efficient utilisation of wastes. Developments in waste management have led to an increase in high-calorific waste arisings. This is attributable to the use of mechanical-biological wastetreatment as well as to segregated waste collection systems. High-calorific wastes are equivalent to fossil fuels in terms of their calorific content. Furthermore, they fulfil the legal requirements for conversion to energy. Another source of high-calorific wastes suitable for conversion to energy can be made available through the segregated disposal of industrial wastes, in many cases at low cost. These high-calorific fractions of varying ...
The industrial application of anaerobic digestion is a relatively new, yet proven wastetreatment technology. Anaerobic digestion reduces and upgrades organic waste, and is a good way to control air pollution as it reduces methane and nitrous gas emissions. For environmental and energy considerations, anaerobic digestion is a nearly perfect wastetreatment process. However, its economic viability is still in question. A number of parameters - type of waste (solid or liquid), digester system, facility size, product quality and end use, environmental requirements, cost of alternative treatments (including labor), and interest rates - define the investment and operating costs of an anaerobic digestion facility. Therefore, identical facilities that treat the same amount and type of waste may, depending on location, ...
The system which is performed the transportation and measurement of drum automatically to measure the surface dose-rate of radioactive waste drum and can inspect place of contaminated sources and precise dose-rate within a drum according to measuring many places equally at the same time has been developed. It is expected that the system be used to minimized radiation exposure of workers and manage the drum effectively according to established at the production facilities as well as the radioactive wastetreatment facilities. (author). 7 refs., 9 tabs., 16 figs.
The generation of industrial solid wastes containing leachable species of environmental concern is a problem for developing and developed nations alike. These materials arise from direct processing of mineral ores, from production of metals and minerals, from manufacturing operations, and from air and water pollution treatment processes. The general characteristics that make these wastes intractable is that their content of hazardous species is not easily liberated from the waste yet is not bound so tightly that they are safe for landfill disposal or industrial use. The approach taken in this work is a thermal treatment that separates the inorganic contaminants from the wastes. The objective is to provide recovery and reuse of both the residual solids and liberated contaminants. The results from operating this technique using two very different types of ...
Los Alamos National Laboratory (LANL) is currently evaluating hazardous wastetreatment and environmental remediation technologies in existence and under development to determine applicability to remediation needs of the DOE facilities under the Albuquerque Operations Office and to determine areas of research need. To assist LANL is this effort, Science Applications International Corporation (SAIC) conducted an assessment of technologies and monitoring methods that have been demonstrated or are under development. The focus of this assessment is to: (1) identify existing technologies for hazardous wastetreatment and environmental remediation of old waste sites; (2) identify technologies under development and the status of the technology; (3) assess new technologies that need development to provide adequate hazardous wastetreatment and ...
A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the wastetreatment lagoons of the Los Alamos Meson Physic...
The bibliography contains citations from a worldwide literature survey pertaining to the uses of activated charcoal in industry as well as in the laboratory, including its use in air pollution, chemical adsorption, radioactive waste adsorption, electrochemistry, industrial wastetreatment, and the mining industry. (This updated bibliography contains 92 citations, 12 of which are new entries to the previous edition.)
At Los Alamos National Laboratory (LANL), a recent effort in waste minimization has focused on scrap metal from radiological controlled areas (RCAs). In particular, scrap metal from RCAs needs to be dispositioned in a reasonable and cost effective manner. Recycling of DOE scrap metals from RCAs is currently under a self-imposed moratorium. Since recycling is not available and reuse is difficult, often metal waste from RCAs, which could otherwise be recycled, is disposed of as low-level waste. Estimates at LANL put the cost of low-level waste disposal at $550 to $4000 per cubic meter, depending on the type of waste and the disposal site. If the waste is mixed, the cost for treatment and disposal can be as high as $50,000 per cubic meter. Disposal of scrap metal as low-level waste uses up valuable space in the low-level ...
This report documents the Mixed Waste Focus Area (MWFA)-sponsored Alternative Technology Workshop held in Salt Lake City, Utah, from January 24--27, 1995. The primary workshop goal was identifying potential applications for emerging technologies within the Options Analysis Team (OAT) ''wise'' configuration. Consistent with the scope of the OAT analysis, the review was limited to the Mixed Low-Level Waste (MLLW) fraction of DOE's mixed waste inventory. The Los Alamos team prepared workshop materials (databases and compilations) to be used as bases for participant review and recommendations. These materials derived from the Mixed Waste Inventory Report (MWIR) data base (May 1994), the Draft Site Treatment Plan (DSTP) data base, and the OAT treatment facility configuration of December 7, 1994. In reviewing workshop results, the reader should note several caveats ...
Radiation exposure of members of the public can be increased appreciably by the use of building materials containing above-normal levels of natural radioactivity. This phenomenon has attracted attention in recent years, and in this review, an attempt is made to the quantify exposures incurred under various circumstances. The second section of the review is a general survey of those building materials, mostly industrial wastes, that have aroused interest in Member countries. The probability that environmental pressures may cause such wastes to be used more and more by building industries may lead to similar situations in the future. Other review material of a relevant nature is described in the third section. Primordial radionuclides only are considered here. They are: potassium-40 (K-40); radium-226 (Ra-226) and its decay products; the series headed by thorium-232 (Th-232). The ...
Radioactive waste is generally classified on the basis of how much radiation and the type of radiation it emits as well as the length of time over which it will continue to emit radiation. Many activities dealing with radioactive materials produce nuclear wastes, including civilian nuclear power programs (nuclear Power plant operations and nuclear fuel-cycle activities), defense nuclear programs (nuclear weapons production, naval nuclear reactor programs, and related R and D), and industrial and institutional activities (scientific research, medical operations, and other industrial uses of Radioisotopic sources or Radio chemicals). To minimize the potential adverse health and environment impacts to people and other systems including of animals, plant and etc, during the entire lifetime of the radionuclides involved, nuclear waste must be carefully and properly managed. The scope of nuclear - waste ...
author.The existing management of hospital waste in Lebanon currently poses both an environmental hazard as well as a public health risk. This is due mainly to lack of legislation, information and modern treatment and disposal facilities designed for this purpose. A nation-wide questionnaire survey was conducted to asses the status of hospital waste management. The study started from October 1997 till August 1998. We found that 75% of the surveyed hospitals completely ignore their total waste quantity: 73% of hospitals surveyed practice segregation at source of infectious, pathological, sharps and pharmaceuticals; more than 40% dispose of their hospital risk wastes through the municipality waste disposal, 24% by burning in open fires, 14% by on-site hospital incinerators, 11% in on-site dumping, 8% handled by a private contractor and 1% in uncontrolled landfill. ...
The Tank Waste Remediation System (TWRS) Program mission is to store, treat, and immobilize highly radioactive Hanford Site waste (current and future tank waste and the strontium/cesium capsules) in an environmentally sound, safe, and cost-effective manner. The scope of the TWRS Waste Pretreatment Program is to treat tank waste and separate that waste into HLW and LLW fractions and provide additional treatment as required to feed LLW and HLW immobilization facilities. Enhanced sludge washing was chosen as the baseline process for separating Hanford tank waste sludge. Section 1.0 briefly discusses the purpose of the evaluation plan and provides the background that led to the choice of enhanced sludge washing as the baseline process. Section 2.0 provides a brief summary of the evaluation plan details. Section 3.0 ...
The Kemp's Ridley sea turtle, Lepidochelys kempi, is an endangered species. The National Marine Fisheries Service's Head Start program is part of an international operation to save the turtles from extinction. Under the Head Start program, eggs from the Ridley's only known wild nesting beach at Rancho Nuevo in Mexico are transported to Padre Island on the Texas coast to be hatched. The head start enables the turtles to develop a survival advantage. The principal objective was to develop baseline waste-characterization data required to design a waste-water treatment scheme for the Galveston Head Start facility. As a secondary objective, preliminary testing of some filtration components was undertaken to determine which units were most appropriate for inclusion in a wastewater treatment scheme.
Most waste water treatment plants have processes to remove nutrients in order to avoid eutrophication in water receiving bodies. Regarding phosphorus removal. the most common option is chemical precipitation with ferric or aluminical precipitation with ferric or aluminium salts. We show here the successful experience carried out by the WWTP of Blanes and the company Safloc. A method ato remove phosphorus from waste water was developed by adding sodium aluminate. The use of this compound has turned out to be a sustainable way for this purpose in terms of costs, reliability and minimization of sludge production. (Author)
For the treatment of dam waste water containing micro quantities of uranium, the so-called chemical precipitation method is conventionally used, that is, acidic sodium phosphate is added to it and so the uranium (UO_2"2"+) is removed in coprecipitation with the then occurring calcium phosphate (solid). The method, however, has several problems, such as the large space required and large quantities of sludge. For the pupose of eliminating such difficulties and removal and recovery of the uranium, development of the new uranium adsorption method was started. Of the many uranium adsorbents available, excellent ones were selected and then the continuous treatment test was made with small apparatus. Subsequently, the dam waste water uranium recovery facility was completed in 1983. (Mori, K.).
From 1991 to 1996, key studies on the reutilization, treatment, and disposal technology of hazardous wastes have been incorporated into the national plan for environmental protection science and technology. At present, the research achievements have been accomplished, have passed national approval, and have been accepted. The author of this paper, as leader of the national group for this research work, expounds the newest achievements of the studies involving four parts: (1) the reutilization technology of electroplating sludge, including the ion-exchange process for recovering the sludge and waste liquor for producing chromium tanning agent and extracting chromium and colloidal protein from tanning waste residue; on the recovery of heavy metals from the electroplating waste liquor with microbic purification; on the demonstration project of producing modified plastics from the ...
This paper, firstly, introduces the background in developing a high quality water supply system, in which the drinking water system is isolated inside a building. Results of questionnaire on the high quality service water are illustrated. The results of questionnaire have revealed that the high quality service water is extremely interested. Then, are described the target quality of high quality water, the constitution of high quality water supply system, the treatment process, the measures to secure safety and sanitary, and the method of maintenance. The high quality water is produced through the activated charcoal absorption treatment, membrane treatment, ozonation, cooling, mineral addition, and disinfection of city water. Furthermore, application examples of this system adopted to a department store and a bachelor apartment house are introduced. For the high quality water supply system in the ...
Full text.This study focuses on the management of municipal solid waste (MSW) in Lebanon. It addresses the current status of MSW management in Lebanon in terms of collection, transport and disposal, infers the associated impacts of such practices and discusses mitigation measures and finally proposes basic guidelines for a national strategy for solid waste management in the country. The study is based on available previous investigations and on a field survey of 113 villages in four different countries. The study revealed the absence of an effective environmental policy and poor collection and disposal methods throughout the country, except for the Greater Beirut Area (G A), where better solid waste management practices are employed. Although collection of MSW outside GBA was found to be acceptable by local authorities, resources (labor and equipment) were not used efficiently. Furthermore, treatment of ...
This Waste Management Plant (WMP) for the Bear Creek Valley Treatability Study addresses waste management requirements for the Oak Ridge Y-12 Plant. The study is intended to produce treatment performance data required to design a treatment system for contaminated groundwater. The treatability study will consist of an evaluation of various treatment media including: continuous column tests, with up to six columns being employed to evaluate the performance of different media in the treatment of groundwater; an evaluation of the denitrifying capacity and metal uptake capacity of a wetland system; and the long-term denitrifying capacity and metal uptake capacity of algal mats. The Sampling and Analysis Plan (SAP) covers the project description, technical objectives, procedures, and planned work activities in greater detail. The Health and Safety Plan (HASP) ...
To use such sites very effectively, pile foundations will be used for soil stabilization and for important structures for the prevention of subsidence. Negative friction that may ensue from the differential settlement of the soil has to be prevented. Measures against gas will include gas collecting and exhausting facilities in the lower parts of structures, natural and forced exhaust systems, and gas detection/warning units. For revegetation, plants strong against bad soil should be selected, they should be protected from generated gas with protecting sheets or the like, and a thick layer of vegetation-capable soil needs to be laid. Replacement, compaction, and solidification are the fundamentals of soil improvement at wastes final treatment locations and of soil-related pollution prevention in the vicinity of the newly produced sites. Across the country, the service life expectancy is approximately 7-8 years for general ...
Neutron radiography (NR) is a useful non-destructive method for determination of hydrogen content in various building and technical materials. Monitoring of transport processes of moisture and hydrogenous liquids in porous building materials is enabled by fast, quasi-real-time NR methods based on novel imaging plate neutron detectors (IP-NDs). Hydrogen content in the samples is determined by quantitative analysis of measured profiles of neutron attenuation in the samples. Detailed description of quantitative NR method is presented by the authors in another accompanying contribution at this conference. Deterioration of building materials is originated by different processes that all require presence of water therefore it is essential to limit or prevent the transport of water through the porous material. In this presentation, results of a study of clay brick impregnation by silicone based hydrophobic agents will be ...
The Ministere des Ressources naturelles du Quebec (Quebec Natural Resources Department) implemented a remedial program to treat the waste rock pile at Wood Cadillac, located near Cadillac, in Abitibi, Quebec. The solutions proposed by INRS-Georessources and ENVIROCONSEIL are aimed at eliminating erosion and stabilizing the geochemical processes. Part of the proposed solution also included the use of a reducing trickling filter for the treatment of acid leachates, which also contain arsenic when exiting the waste rock pile. The trickling filter is composed of forest tailings in which the bacteria reduce the sulphates and stimulate the precipitation of arsenic into arsenic sulphates. This is a new treatment that was developed following laboratory experiments which demonstrated the feasibility of the process and quantified the parameters. A demonstration unit was constructed by ENVIROCONSEIL and installed ...
The report addresses the application of reverse osmosis to the treatment of radioactive liquid waste, focusing on the effects of non-radioactive cations and anions, existing in radioactive waste, on the removal of radioactive nuclides. The bivalent cations are generally about ten times as high in decontamination factor as monovalent ones. In the case of anions, the factor of SO{sub 4}{sup 2-} is about ten times that of Cl{sup -} while that of NO{sub 3}{sup -} is somewhat smaller than that of Cl{sup -}. During permeation through membrane, anions tend to accompany cations, and the decontamination factor of accompanying ions is found to increase with that of the paring ions. These results indicate that if one can select components that will remain in the liquid waste, one should consider their effects on the efficiency of its treatment. Furthermore, the interaction between two anions ...
The report addresses the application of reverse osmosis to the treatment of radioactive liquid waste, focusing on the effects of non-radioactive cations and anions, existing in radioactive waste, on the removal of radioactive nuclides. The bivalent cations are generally about ten times as high in decontamination factor as monovalent ones. In the case of anions, the factor of SO_4"2"- is about ten times that of Cl"- while that of NO_3"- is somewhat smaller than that of Cl"-. During permeation through membrane, anions tend to accompany cations, and the decontamination factor of accompanying ions is found to increase with that of the paring ions. These results indicate that if one can select components that will remain in the liquid waste, one should consider their effects on the efficiency of its treatment. Furthermore, the interaction between two anions or between two cations can be ...
Rehabilitation of open-cut coal mining spoils at Collie, Western Australia, requires amelioration before adequate survival and growth of rehabilitation species can occur. Lolium ridgidum was used in a greenhouse pot experiment to assess the ability of lime (CaCO/sub 3/) and two waste-products of regional industry, bauxite processing caustic waste (red mud) and timber milling refuse (sawdust), to render the low pH spoils suitable for plant growth. CaCO/sub 3/ at 1% and red mud at 18% were both effective in reducing acidity and levels of available Al in the overburden. Red-mud treatment produced 10-fold increases in plant dry matter accumulation over the CaCO/sub 3/ treatment when no fertilizer was used. This is due to the presence of significant amounts of phosphorus in the red mud. With additions of a balanced NPK fertilizer at 0.077%, CaCO/sub 3/ treatment produced the best plant ...
Molten salt oxidation (MSO) is a good alternative to incineration for the treatment of a variety of organic wastes such as explosives, low-level mixed waste streams, PCB contaminated oils, spent resins and carbon. Since mid-1990s, the U.S. Army Defense Ammunition Center (DAC) and the Department of Energy (DOE) have jointly invested in MSO development at the Lawrence Livermore National Laboratory (LLNL). LLNL first demonstrated the MSO process for the effective destruction of explosives, explosives-contaminated materials, and other wastes on a 1.5-kg/hr bench-scale unit, and then in an integrated MSO facility capable of treating 8 kg/hr of low-level radioactive mixed wastes. Several MSO systems have been built with sizes up to 10 ft in height and 16 inches in diameter. LLNL in 2001 completed a MSO plant for DAC for the destruction of explosives-contaminated sludge and ...
The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics ...
The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the ...
Full text.Increased environmental concerns and the emphasis on material and energy recovery are gradually changing the orientation of municipal solid waste (MSW) management and planning. In this context, the application of optimization techniques have been introduced to design the least cost solid waste management systems, considering the variety of management processes (recycling, composting, anaerobic digestion, incineration and land filling) and the existence of uncertainties associated with the number of system components and their interrelations. This study presents a model that was developed and applied to serve as a solid socio-economic and environmental considerations. The model accounts for solid waste generation rates, composition, collection, treatment, disposal as well as potential environmental impacts of various MSW management techniques. The model follows a linear programming formulation ...
Industrial solid wastes (fly ash and red mud, a by-product of the aluminium industry) have been employed as supports for preparation of Ru-based catalysts. Physical and chemical treatments on red mud were conducted and these modified supports were also used for preparation of Ru-based catalysts. Those Ru catalysts were characterized by various techniques such as N2 adsorption, H{sub 2} adsorption, XRD, XPS, and temperature-programmed reduction (TPR), and were then tested for catalytic ammonia decomposition to hydrogen. It was found that red-mud-supported Ru catalyst exhibits higher ammonia conversion and hydrogen production than fly-ash-supported catalyst. Heat and chemical treatments of the red mud greatly improve the catalytic activity. Moreover, a combination of acid and heat treatments produces the highest catalytic conversion of ammonia. 35 refs., 4 figs., 4 tabs.
A process for separation of actinides and technetium from reprocessing high level liquid waste has been developed, the CTH-process. The main parts are three consecutive solvent extraction cycles followed by an optional step for sorption on inorganic ion exchangers. The first extraction cycle removes and recovers uranium, neptunium, and plutonium by extraction with HDEHP. The second extraction cycle separates technetium and nitric acid from the waste using TBP. In the third extraction cycle Am and Cm are separated from the waste using HDEHP. The actinide free waste is then passed through inorganic ion exchangers to remove most of remaining radionuclides. The process has been tested on an authenic HLLW solution. A decontamination factor > 10/sup 5/ for alpha emitters was measured for the solvent extraction process and the sorption on inorganic ion exchangers gave a decontamination factor > 3x10/sup ...
Natural minerals and some industrial wastes are used as low cost sorbents for removal of metal ions from effluent streams. Apatite as natural mineral and red mud as an industrial waste have been tested for their sorption properties with respect to two important fission products "1"3"7Cs and "9"0Sr. Their ion exchanging capacity was tested after every 4 hours till 24 hours. The material gets saturated after 4-8 hours. Hence these materials can be considered for treating in treating LLW before discharge, industrial wastetreatment and as backfill or admixture material for shallow land repository. (author)
These Appendices describe various technologies that may be applicable to the Mixed WasteTreatment Plant (MWTP) Chemical/Physical Treatment System (CPTS). These technologies were identified by the CPTS Technical Support Group (TSG) as potentially applicable to a variety of separation, volume reduction, and decontamination requirements. The purpose was to identify all available and developing technologies, and their characteristics, for subsequent evaluation for specific requirements identified for the CPTS. However, the technologies described herein are not necessarily all inclusive, nor are they necessarily all applicable.
Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.
Rotex Inc. has designed and manufactured industrial sifting equipment since 1844. This site (an existing industrial facility) encompasses approximately 140,000 ft[sup 2] (13,006 m[sup 2]) of offices, R D shops, assembly and storage areas, as well as a large welding shop that was the main focus of this project. This facility consists of three separate buildings that are all connected and open to one another. The original building dates from 1908. The newest addition (32,400 ft[sup 2]; 3,010 m[sup 2]) was added in 1977, and is referred to as the 77 Building. This building was initially equipped with oil fired heating equipment due to the moratorium on new gas sales that was in effect at that time. This project was driven by the client's need to remove underground oil storage tanks to comply with environmental standards. This article describes the 77 Building conversion from ...
In the Savannah River Site's (SRS') Solid Waste Management Program, a key to success is the Public Involvement Program. The Solid Waste Division at SRS manages the site's transuranic, low-level, mixed, and hazardous wastes. All decisions associated with management of this waste are of interest to the public and successful program implementation would be impossible without a vigorous public involvement program. The SRS Solid Waste Division (SWD) and its Department of Energy (DOE) customer developed, implemented, and maintain a comprehensive public participation and communications program. It is staffed by public participation and technical specialists to ensure information is presented in a manner that is technically accurate while being tailored for understanding by people without a technical background. The program provides the public with accurate, ...
This plan establishes a Department-wide goal to reduce total releases of toxic chemicals to the environment and off-site transfers of such toxic chemicals by 50 percent by December 31, 1999, in compliance with Executive Order 12856. Each site that meets the threshold quantities of toxic chemicals established in the Emergency Planning and Community Right-to-Know Act (EPCRA) will participate in this goal. In addition, each DOE site will establish site-specific goals to reduce generation of hazardous, radioactive, radioactive mixed, and sanitary wastes and pollutants, as applicable. Implementation of this plan will represent a major step toward the environmental risks and costs associated with DOE operations and increasing the Department's use of preventive environmental management practices. Investing in Waste Minimization Pollution Prevention (WMin/PP) steadily reduce hazardous and radioactive waste generation and will ...
Aqueous solutions (mixed waste) generated from various LLNL operations, such as debris washing, sample preparation and analysis, and equipment maintenance and cleanout, were combined for storage in the B695 tank farm. Prior to combination the individual waste streams had different codes depending on the particular generating process and waste characteristics. The largest streams were CWC 132, 791, 134, 792. Several smaller waste streams were also included. This combined waste stream was treated at LLNL's wastetreatment facility using a vacuum filtration and cool vapor evaporation process in preparation for discharge to sanitary sewer. Prior to discharge, the treated waste stream was sampled and the results were reviewed by LLNL's water monitoring specialists. The treated solution was discharged ...
The slow or stagnant rate of nuclear power generation development in many developed countries over the last two decades has resulted in a significant shortage in the population of mid-career nuclear industry professionals. This shortage is even more pronounced in some specific areas of expertise such as radiological protection, waste management and decommissioning. This situation has occurred at a time when the renaissance of nuclear power and the globalization of the nuclear industry are steadily gaining momentum and when the industry's involvement in international and national debates in these three fields of expertise (and the industry's impact on these debates) is of vital importance. This paper presents the World Nuclear Association (WNA) approach to building and enhancing worldwide industry cooperation in radiological protection, waste management and decommissioning, which is manifested through the activities of the ...
Pilot-scale pyrolysis units have been in operation since 1980 to test the efficiency of thermal treatment of transuranic (TRU) solid waste to retrieve the TRUs and to reduce the volume of wastes such as spent solvent, spent resin, and others. These wastes are generated by reprocessing, fuel production, and utilities. NUKEM has developed a criticality-safe, ring-slab reactor to decompose solid TRU waste. The plant processes 25 kg/h with a polyvinyl chloride content up to 70%. The overall throughput (inactive) up to the spring of 1982 was 2000 kg. The decontamination factor for the reactor itself is 1000. The liquid wastes, mainly spent solvent, are cracked under nitrogen at 400 to 700/sup 0/C in a reactor that is filled by a packed bed kept in motion by a specially designed agitator. This unit was built for 15 kg/h water equivalent evaporation. Up to 1982 the ...
Pilot-scale pyrolysis units have been in operation since 1980 to test the efficiency of thermal treatment of transuranic (TRU) solid waste to retrieve the TRUs and to reduce the volume of wastes such as spent solvent, spent resin, and others. These wastes are generated by reprocessing, fuel production, and utilities. NUKEM has developed a criticality-safe, ring-slab reactor to decompose solid TRU waste. The plant processes 25 kg/h with a polyvinyl chloride content up to 70%. The overall throughput (inactive) up to the spring of 1982 was 2000 kg. The decontamination factor for the reactor itself is 1000. The liquid wastes, mainly spent solvent, are cracked under nitrogen at 400 to 700"0C in a reactor that is filled by a packed bed kept in motion by a specially designed agitator. This unit was built for 15 kg/h water equivalent evaporation. Up to 1982 the unit ...
During the phases of separation, treatment, conditioning and storage of radioactive waste, destructive and nondestructive methods for their characterization are needed. In order to satisfy this necessity, in the frame of the National Program of Research and Development, the 'Laboratory for characterization of spent nuclear fuel and high/medium level radioactive waste- LABORAD' was created. The purpose of the project was to accredit the analysis methods available in the laboratory, and also to develop new methods for the characterization of the radioactive waste. A special attention was paid to the high-level radioactive waste and spent nuclear fuel characterization that require special facilities for handling. These facilities (e.g. hot cells, remote handlers, transport container) are already available in our institute. Experimental results and performances obtained during ...
A schematic diagram shows the various processing steps to be performed during feed preparation in the Hanford Waste Vitrification Plant (HWVP). The pretreated NCAW is transferred to the slurry receipt adjustment tank (SRAT) in the HWVP for concentration. Water removed during boildown is collected in the slurry mix evaporator condensate tank (SMECT). After wastetreatment the water is returned to the storage tanks for eventual disposal. The pretreated Neutralized Current Acid Waste (NCAW) is concentrated in the SRAT to approximately 125 g waste oxides/ liter. Formic acid is then added at a controlled rate to improve rheological properties and achieve a required reduction/oxidation state. Reflux boiling is initiated and continued for several hours. The concentrated slurry is cooled and pumped to the slurry mix evaporator (SME). In the SME, glass frit is added, and the slurry is ...
A glovebox was designed, fabricated, and mocked-up for the WIPP Gas Generation Experiments (GGE) being conducted at ANL-W. GGE will determine the gas generation rates from materials in contact handled transuranic waste at likely long term repository temperature and pressure conditions. Since the customer`s schedule did not permit time for performing R&D of the support systems, designing the glovebox, and fabricating the glovebox in a serial fashion, a parallel approach was undertaken. As R&D of the sampling system and other support systems was initiated, a specification was written concurrently for contracting a manufacturer to design and build the glovebox and support equipment. The contractor understood that the R&D being performed at ANL-W would add additional functional requirements to the glovebox design. Initially, the contractor had sufficient information to design the glovebox shell. Once the shell design was approved, ANL-W ...
At the 1996 Conference in North Carolina, The Green Institute began to share its story. Their presentation this year will cover where they are in the design process and their plans for using solar and wind technologies in the development of an Eco-Industrial Park and Business Incubator. Located in a Federal Enterprise Community in Minneapolis, this project borrows sustainable and green building principles using the Rocky Mountain Institute and Solar Living Center as models. Using a change in the paradigm regarding how industry does business, The Green Institute is joining with developments across the country that are putting together Eco-Industrial Parks which use closed loop production systems to reduce waste and emissions generated from manufacturing processes. Using renewable energy, both solar and wind, presents challenges both in the integration of systems on this small site and the educational opportunities with a large potential audience ...
JRR-3 is a research reactor of 10 MWt output, which attained the criticality in 1962. All the design, manufacture, installation and others of this reactor were carried out by Japanese technologies, except the fuel and heavy water as the moderator and coolant, therefore it is nicknamed Home-made No.1 Reactor. Recently, due to the change in the state of utilizing research reactors and the rise of quality in the utilization, JRR-3 has become to be unable to meet sufficiently the needs of users. The plan of reconstructing the JRR-3 was considered under such situation, and in order to reuse the reactor building, the reactor proper is removed, and an entirely new, high performance, versatile reactor is to be constructed. In this paper, as to the removal works of the JRR-3 reactor proper, the method of execution, design, the execution of works and so on are outlined. The removal works of the reactor facilities were started in February, 1986. The removal of the accessory ...
The basic relationships of the convolution/superposition dose calculation technique are reviewed, and a modelling technique that can be used for obtaining a satisfactory beam model for a commercially available convolution/superposition-based treatment planning system is described. A fluence energy spectrum for a Co-60 treatment machine obtained from a Monte Carlo simulation was used for modelling the fluence spectrum for a Rokus M machine. In order to achieve this model we measured the depth dose distribution and the dose profiles with a Wellhofer dosimetry system. The primary fluence was iteratively modelled by comparing the computed depth dose curves and beam profiles with the depth dose curves and crossbeam profiles measured in a water phantom. The objective of beam modelling is to build a model of the primary fluence that the patient is exposed to, which can then be used for the calculation of the dose deposited in the ...
This paper builds on earlier work to give a consistent treatment of the positive column of discharges in electronegative gases covering the transition from collisionless to collisional. In particular it seeks to elucidate the conditions under which there is an ion-ion plasma core surrounded by an electron-ion plasma, and when there is not. The parameters which describe the processes of ionization, attachment, detachment and recombination are related to the central negative ion density relative to the electron density and, where appropriate, the size of the core. The use, by earlier workers, of the Boltzmann approximation to describe the negative ion distribution and to obtain ambipolar diffusion coefficients at higher pressures is shown not to be justified. This leads to the clarification of an inconsistency in the literature. Where possible, the work is related to other recent treatments of the same problem in order to ...
This paper presents a decision approach, and associated computer software tools, for prioritizing and selecting among technology development activities. The approach elicits and then summarizes technology development preferences from stakeholders, and then integrates preferences into a set of funding recommendations. By formalizing the technology review process, the decision approach builds consensus and clarifies the basis for final budget decisions. The software development was conducted jointly by Pacific Northwest Laboratory and Decisions Science Associates, Incorporated. The Underground Storage Tank Integrated Demonstration funded the task; however, the approach should also be valuable to the US Department of Energy Office of Technology Development, the Office of Waste Management, and the Office of Environmental Restoration.
This conference provided a forum to discuss advances in the application of bioengineering principles and practices dealing with biological systems for the production of food, bioproducts and energy. The topics of discussion ranged from engineering practices in agriculture, forestry, bioresources, biochemistry and biosystems. The sessions of the conference were entitled: renewable energy; waste management; soil and water; machinery systems; building and storage systems; and bioproducts and food. The conference also featured a workshop on integrated biomass supply and logistics. In addition to 20 posters, the conference featured 67 presentations, of which 3 have been catalogued separately for inclusion in this database. refs., tabs., figs.
Actinides other than the main uranium or plutonium isotopes take a growing part in the different stages of the nuclear cycle. For the French nuclear power program based on the development of light water reactors and fast breeders, many evaluations of the secondary actinides build up are made for the both reactor types using mainly the existing reactor codes. The comparison of these foreseen compositions with experimental results allows to perform some adjustments of the neutronic data. The secondary actinide compositions are given for some typical fuels and their consequences on the nuclear cycle are discussed. An hypothetical burning of these wastes in fast reactors has been studied and the main conclusions are reported.
The purpose of this report is to provide the reader with a basic understanding of Argonne National Laboratory`s current general refuse disposal and material recycling programs, how they were developed, and where they are going. In order to better understand the current situation, a brief description of the facilities past practices is explained. ANL is a multi-program research and development center owned by DOE and operated by the University of Chicago. Argonne`s primary facilities are on a 1,700 acre site, 27 miles southwest of Chicago. Fifty-seven major buildings house approximately 4,500 employees at the site.
The purpose of this report is to provide the reader with a basic understanding of Argonne National Laboratory`s current general refuse disposal and material recycling programs, how they were developed, and where they are going. In order to better understand the current situation, a brief description of the facilities past practices is explained. ANL is a multi-program research and development center owned by the U.S. Department of Energy (DOE) and operated by the University of Chicago. Argonne`s primary facilities are on a 1,700 acre site, 27 miles southwest of Chicago. Fifty-seven major buildings house approximately 4,500 employees at the site.
The strategy for management of the Oak Ridge National Laboratory`s (ORNL) radioactively contaminated liquid waste was reviewed in 1991. The latest information available through the end of 1990 on waste characterization, regulations, US Department of Energy (DOE) budget guidance, and research and development programs was evaluated to determine how the strategy should be revised. Few changes are needed to update the strategy to reflect new waste characterization, research, and regulatory information. However, recent budget guidance from DOE indicates that minimum funding will not be sufficient to accomplish original objectives to upgrade the liquid low-level waste (LLLW) system to comply with the Federal Facilities Agreement, provide long-term LLLW treatment capability, and minimize environmental, safety, and health risks. Options are presented that might allow the ORNL LLLW system to ...
The strategy for management of the Oak Ridge National Laboratory`s (ORNL`s) radioactively contaminated liquid waste was reviewed. The latest information on waste characterization, regulations, US Department of Energy (DOE) budget guidance, and research and development programs was evaluated to determine how the strategy should be revised. Few changes are needed to update the strategy to reflect new waste characterization, research, and regulatory information. However, recent budget guidance from DOE indicates that minimum funding will not be sufficient to accomplish original objectives to upgrade the liquid low-level waste (LLLW) system to be in compliance with the Federal Facilities Agreement compliance, provide long-term LLLW treatment capability, and minimize Environmental Safety & Health risks. Options are presented that might allow the ORNL LLLW system to continue ...
Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), and into radiochemical and radioactive laundry waste. Although the evaporation process has a high decontamination ability, it has several problems such as corrosion, foam, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED), instead of the current evaporation process, has been introduced into the Yonggwang NPP No 5 and 6. These two methods have been compared to understand the differences in this study. Aspects compared here were the released radioactivity amount of the liquid radioactive wastes, the dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. The IED system is designed to discharge higher radioactivity about 20% than the evaporating system, ...
In the early 1980s, AECL built a WasteTreatment Centre (WTC) for managing low-level solid and aqueous liquid wastes for converting CANDU wastes. At present, two liquid waste streams are being treated at the WTC. The liquid waste streams are volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis (TRO) membrane technologies. The concentrate produced from the TRO system and the volume-reduced MF backwash solutions are evaporated while simultaneously adding bitumen in a thin-film evaporator. A water-free product of chemical and radiochemical salts and bitumen is removed in 200-L galvanized steel drums for storage. The radiation field of product drums on contact typically has a value of 0.5 to 3 R/h depending upon the feed concentration of radioactivity to the evaporator. The ...
A method for assessing management systems for low-level radioactive waste is being developed for US Department of Energy. The method is based on benefit-cost-risk analysis. Waste management is broken down into its component steps, which are generation, treatment, packaging, storage, transportation, and disposal. Several different alternatives available for each waste management step are described. A particular waste management system consists of a feasible combination of alternatives for each step. Selecting an optimal waste management system would generally proceed as follows: (1) qualitative considerations are used to narrow down the choice of waste management system alternatives to a manageable number; (2) the costs and risks for each of these system alternatives are evaluated; (3) the number of alternatives is further reduced by ...
Molten salt oxidation (MSO) is proposed as a {sup 238}Pu wastetreatment technology that should be developed for volume reduction and recovery of {sup 238}Pu and as an alternative to the transport and permanent disposal of {sup 238}Pu waste to the WIPP repository. In MSO technology, molten sodium carbonate salt at 800--900 C in a reaction vessel acts as a reaction media for wastes. The waste material is destroyed when injected into the molten salt, creating harmless carbon dioxide and steam and a small amount of ash in the spent salt. The spent salt can be treated using aqueous separation methods to reuse the salt and to recover 99.9% of the precious {sup 238}Pu that was in the waste. Tests of MSO technology have shown that the volume of combustible TRU waste can be reduced by a factor of at least twenty. Using this factor the present ...
Waste tank W-12 is a tank in the ORNL Low-Level Liquid Waste (LLLW) system that collected waste from Building 3525. Because of a leaking flange in the discharge line from W-12 to the evaporator service tank (W-22) and continual inleakage into the tank from an unknown source, W-12 was removed from service to comply with the Federal Facilities Agreement requirement. The initial response was to decontaminate the valve pit between tank W-12 and the evaporator service tank (W-22) to determine if personnel could enter the pit to attempt repair of the leaking flange. Preventing the spread of radioactive contamination from the pit to the environment and to other waste systems was of concern during the decontamination. The drain in the pit goes to the process waste system; therefore, if high-level liquid waste were generated during decontamination ...
Los Alamos National Laboratory (LANL) was established during World War II with a single mission -- to design and build an atomic bomb. In the 65 years since, nuclear weapons physics, design and engineering have been the Laboratory's primary and sustaining mission. Experimental and process operations -- and associated cleanout and upgrade activities -- have generated a significant inventory of transuranic (TRU) waste that is stored at LANL's Technical Area 54, Material Disposal Area G (MDA G). When the Waste Isolation Pilot Plant (WIPP) opened its doors in 1999, LANL's TRU inventory totaled about 10,200 m{sup 3}, with a plutonium 239-equivalent curie (PE Ci) content of approximately 250,000 curies. By December 2008, a total of about 2,300 m3 (61,000 PE Ci) had been shipped to WIPP from LANL. This has resulted in a net reduction of about 1,000 m{sup 3} of TRU inventory over that time frame. This ...
TOXCHEM is a microcomputer based modelling system for predicting the fate of toxic contaminants in wastewater treatment plants. The package evaluates concentrations of toxics in final effluent and waste sludge, and mass air emissions from municipal or industrial activated sludge wastewater treatment plants. Maximum allowable influent concentrations of toxics required to meet effluent discharge or air emission limits can also be estimated. The package contains a read-only database with treatability parameters for over 100 contaminants, including organic compounds and metals. If effluent or sludge quality limits have been specified, treatment plant owners and operators can use the package to estimate the permissable discharge limits for dischargers to their collection system. A hypothetical example is provided of application of the software to a planning problem involving the start up of a new operation ...
Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of ...
Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of ...
The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), ...
Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.
The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the wastetreatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of ...
The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the wastetreatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of radioactivity in ...
Full text: There are following general tendencies linking to SNF and radioactive waste management (RWM) in the Russian nuclear industry now. The intention to use the closed nuclear fuel cycle based on power water reactors and fast reactor. The intensification of measures aimed at the solution of 'nuclear legacy' from defenses programs of USSR. The intention to improve the existing national RW management infrastructure in the near years by means of the creation of a centralized national system (including managing corporation responsible for operation of long-storage and disposal facilities of conditioned RW). The main aims radioactive waste management (RWM) in nuclear power plants (NPP) for the next 10-15 years are to equip all NPPs with the necessary set of facilities for conditioning of the stored and currently generated RW with packaging the end-product into containers, to build regional NPPs RW repositories and to ...
This ACDR was performed following completed of the Conceptual Design Report in July 1992; the work encompassed August 1992 to January 1994. Mission of the WRAP Module 2A facility is to receive, process, package, certify, and ship for permanent burial at the Hanford site disposal facilities the Category 1 and 3 contact handled low-level radioactive mixed wastes that are currently in retrievable storage at Hanford and are forecast to be generated over the next 30 years by Hanford, and waste to be shipped to Hanford from about DOE sites. This volume provides an introduction to the ACDR process and the scope of the task along with a project summary of the facility, treatment technologies, cost, and schedule. Major areas of departure from the CDR are highlighted. Descriptions of the facility layout and operations are included.
A formulation to pelletize simulated high-level ICPP alumina waste calcine was developed. The pellets are formed on a 41-cm-diameter disc pelletizer using 5% bentonite, 2% metakaolin, and 5 wt % calcium hydroxide as a solid binder and a solution of 7M phosphoric acid and 4M nitric acid as a liquid binder. After drying and heat treatment at 800/sup 0/C for 2 hours, the average crush strength of the pellets is 3.9 MPa and the pellets have a leach resistance of 10/sup -3/ g/cm/sup 2//day, based on Soxhlet leaching for 48 h at 95/sup 0/C with distilled water.
A carrier coprecipitation procedures has been developed for the removal of radioactive strontium from caustic liquid low-level waste (LLLW) generated at Oak Ridge National Laboratory. The two-step treatment process involves the addition of normal Sr (as SrCl{sub 2}) to the waste matrix, which is composed primarily of 0.3 M NaOH and 0.6 M Na{sub 2}CO{sub 3}. The active Sr equilibrates with the normal Sr carrier and coprecipitates as SrCO{sub 3} at pH 13. A liquid/solid separation is made before the pH of the supernate is reduced to pH 8 with sulfuric acid. During the neutralization step, the aluminum is the waste precipitates as Al(OH){sub 3}. Further Sr decontamination is achieved as traces of active Sr sorb to the Al(OH){sub 3} that precipitates during the neutralization step. A final liquid/solid separation is made at pH 8 to remove the sorbed active Sr. Maximum Sr decontamination of the LLLW is ...
The EPA has designated vitrification as the best developed available technology for immobilization of High-Level Nuclear Waste. In a recent federal facilities compliance agreement between the EPA, the State of Washington, and the DOE, the DOE agreed to vitrify all of the Low Level Radioactive Waste resulting from processing of High Level Radioactive Waste stored at the Hanford Site. This is expected to result in the requirement of 100 ton per day Low Level Radioactive Waste melters. Thus, there is increased need for the rapid adaptation of commercial melter equipment to DOE`s needs. DOE has needed a facility where commercial pilot scale equipment could be operated on surrogate (non-radioactive) simulations of typical DOE waste streams. The DOE/Industry Center for Vitrification Research (Center) was established in 1992 at the Clemson University Department of Environmental Systems ...
This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1993. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process, (2) treatment schemes for liquid wastes stored or being generated at Argonne, (3) a process based on sorbing modified TRUEX solvent on magnetic beads to be used for separation of ...
In response to the need for a comprehensive and consistent approach to the complex issue of mixed waste management, a generalized methodology for remediation of a mixed waste site has been developed. The methodology is based on requirements set forth in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the Resource Conservation and Recovery Act (RCRA) and incorporates ``lessons learned`` from process design, remediation methodologies, and remediation projects. The methodology is applied to the treatment of 32,000 drums of mixed waste sludge at the Oak Ridge K-25 Site. Process technology options are developed and evaluated, first with regard to meeting system requirements and then with regard to CERCLA performance criteria. The following process technology options are investigated: (1) no action, (2) separation of hazardous and radioactive species, (3) dewatering, (4) ...
This paper evaluates the two well-known final waste disposal methods, incineration and landfilling. In particular we compare the social cost of two best-available technologies using a point estimate based on private and environmental cost data for the Netherlands. Not only does our comparison allow for Waste-to-Energy incineration plants but for landfills as well. The data provide support for the widespread policy preference for incineration over landfilling only if the analysis is restricted to environmental costs alone and includes savings of both energy and material recovery. Gross private costs, however, are so much higher for incineration, that landfilling is the social cost minimizing option at the margin even in a densely populated country such as the Netherlands. Furthermore, we show that our result generalizes to other European countries and probably to the USA. Implications for waste policy are discussed as well. ...
The U.S. Department of Energy (DOE) has developed comparatively detailed quality assurance requirements for the high-level radioactive waste disposal systems. Quality assurance is recognized as a key issue for confidence building and smooth implementation of the HLW program in Japan, and Japan is at an initial phase of repository development. Then the quality assurance requirements at site research and site selection, site characterization, and site suitability analysis used in the Yucca Mountain project were examined in detail and comprehensive descriptions were developed using flow charts. Additionally, the applicability to the Japan high-level radioactive waste disposal project was studied. The examination and study were performed for the following QA requirements: The requirements that have the relative importance at site research and site selection, site characterization, and site suitability analysis (such as planning ...
subsequent to its in-reactor dwell time, spent fuel still contains large amounts of materials that are recoverable, for value-added energy purposes (uranium, plutonium), together with fission products, and minor actinides, making up the residues from nuclear reactions. The treatment and recycling of spent nuclear fuel, as implemented in France, entail that such materials be chemically partitioned. The development of the process involved, and its deployment on an industrial scale stand as a high achievement of French science, and technology. Treatment and recycling allow both a satisfactory management of nuclear waste to be implemented, and substantial savings, in terms of fissile material. Bolstered of late as it has been, due to spectacularly skyrocketing uranium prices, this strategy is bound to become indispensable, with the advent of the next generation of fast reactors. This Monograph surveys the chemical process used ...
The U.S. Department of Energy`s (DOE) Environmental Management Office of Science and Technology (EM-50) authorized studies on alternative systems for treating contact-handled DOE mixed low-level radioactive waste (MLLW). The on-going Integrated Thermal Treatment Systems` (ITTS) and the Integrated Nonthermal Treatment Systems` (INTS) studies satisfy this request. EM-50 further authorized supporting studies including this technology and subsystem cost sensitivity analysis. This analysis identifies areas where technology development could have the greatest impact on total life cycle system costs. These areas are determined by evaluating the sensitivity of system life cycle costs relative to changes in life cycle component or phase costs, subsystem costs, contingency allowance, facility capacity, operating life, and disposal costs. For all treatment systems, the most cost sensitive life cycle phase is the ...
The primary function of the Waste Handling Shaft (WHS) at the Waste Isolation Pilot Plant (WIPP) is to permit the transfer of radioactive waste from the surface waste handling building to the underground storage area. It also serves as an intake shaft for small volumes of air during normal storage operations and as an emergency escape route. Part of the construction was the placement of a concrete liner and steel reinforced key in 1984. During a routine shaft inspection in May 1990, some degradation of the WHS concrete liner was observed between the depths of 800 and 900 feet below the ground surface. Detailed investigations of the liner had been carried out by Sandia National Laboratories and by Westinghouse Electric Corporation Waste Isolation Division (WID) through Lankard Materials Laboratory. Observations, reports, and data support the conclusion that the ...
This document reports the results of testing of spent ion exchange media pretreatment technologies. Emphasis of the testing activities has been on screening pretreatment technologies, such as drying and emulsification, which are compatible with vitrification, cementation, and incineration. Ion exchange media tested for cementation and incineration pretreatment technologies were typical organic ion exchange resins and inorganic zeolites. The ion exchange medium tested for vitrification pretreatment technologies was inorganic zeolite. The results of testing activities are discussed in detail in this report.
The use of finely powdered ion exchange resins improve loading of specific ion exchange materials with better performance but as such these materials are not suitable for column operation. However, by proper selection of ion exchange support medium, it is possible to get better product. The radioactive solution can be treated by suspending this material, stirring and allowing to settle. The present method gives DF in the range of 70 - 80 even after repeated use as compared to DF in the range of 5 to 10 by single conventional chemical treatment process. (author)
The first biogas plant using the Plauen method has been operated without failures in the Saxon Vogtland since May 1987. This large scale anaerob treatment plant which is the first one in Germany handles besides agricultural recidual substance both municipal and industrial organic residues. The results show clearly that fermentation is a real alternative to composting, combusting and deponing. (orig.)
Waste management has gone through a history of shifting problems, demands, and strategies over the years. In contrast to the long prevailing view that the problem could be solved by hiding or moving it, waste is now viewed as a problem ranging from local to global concern, and as being an integral part of several sectors in society. Decisive for this view has been society's increasing complexity and thus the increasing complexity of waste, together with a general development of environmental consciousness, moving from local focus on point emission sources, to regional and global issues of more complex nature. This thesis is about the development and application ORWARE; a model for computer aided environmental systems analysis of municipal waste management. Its origin is the hypothesis that widened perspectives are needed in waste management decision-making to avoid severe ...
The treatment of chronic pain conditions continue to present a challenge to the medical field. Physical therapy treatment needs to approach the management of chronic pain differently than the approach used to resolve acute pain. Patients with chronic pain often have many factors that have perpetuated the pain condition. These factors, as well as pain itself, influence their ability to reactivate and perform functional daily activities. Physical therapists can begin to address some of the factors, including fear and deconditioning, by building confidence and body awareness in a self-care model including a slow graduated reactivation program. There is evidence that patients with chronic pain conditions have altered motor control that may be influencing reoccurrences and possible flares of pa...
This document presents a conceptual design for a contingency interim measure (IM) for treatment of the public water supply system at Barnes, Kansas, should this become necessary. The aquifer that serves the public water supply system at Barnes has been affected by trace to low concentrations of carbon tetrachloride and its degradation product, chloroform. Investigations conducted on behalf of the CCC/USDA by Argonne National Laboratory (Argonne 2008a) have demonstrated that groundwater at the Barnes site is contaminated with carbon tetrachloride at concentrations exceeding the Kansas Tier 2 risk-based screening level (RBSL) and the EPA maximum contaminant level (MCL) of 5.0 {micro}g/L for this compound. The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) formerly operated a grain storage facility in Barnes, approximately 800 ft east-southeast of the public water supply wells. Carbon tetrachloride was used in the ...
The French radioactive waste management act of December 30, 1991, included two key provisions. It initiated a major research program with three areas of investigation concerning high-level long-lived radioactive waste management routes, and called for the Government to submit a legislative proposal to Parliament within 15 years (by 2006) specifying the policy guidelines adopted. Considering the sensitive nature of the subject, the questions surrounding the issue of radioactive waste, and the social, economic and environmental concerns for present and future generations, the Government has inaugurated, in 2005, a nationwide public debate on these issues between the submittal of the research reports and the parliamentary discussion of the proposed law. In this context, the CEA has decided to concentrate at Marcoule the expertise and experience acquired in the area of radioactive waste management and to ...
The Safety Analysis Report for the TRUPACT-II Shipping Package [Transuranic Package Transporter-II (TRUPACT-II) SARP] set limits for gas generation rates, wattage limits, and flammable volatile organic compound (VOC) concentrations in transuranic (TRU) waste containers that would be shipped to the Waste Isolation Pilot Plant (WIPP). Based on existing headspace gas data for drums stored at the Idaho National Engineering Laboratory (INEL) and the Rocky Flats Environmental Technology Site (RFETS), over 30 percent of the contact-handled TRU waste drums contain flammable VOC concentrations greater than the limit. Additional requirements may be imposed for emplacement of waste in the WIPP facility. The conditional no-migration determination (NMD) for the test phase of the facility required that flame tests be performed if significant levels of flammable VOCs were present in TRU waste ...
Reported on here are studies of various methods for liquefying coal. Hydropyrolysis as an alternative method for producing liquid hydrocarbons and a carbon enriched char is discussed. Other methods described involve supercritical gas extraction of coal and use of natural gas as a hydrogenating agent. Relevant waste water treatments are discussed as well. 65 refs., 9 figs.
This document describes the proposed strategy for disposal of spent and failed melters from the tank wastetreatment plant to be built by the Office of River Protection at the Hanford site in Washington. It describes program management activities, disposal and transportation systems, leachate management, permitting, and safety authorization basis approvals needed to execute the strategy.
This bibliography contains citations concerning theoretical aspects and industrial applications of activated charcoal. Topics include absorption capacity and mechanism studies, kinetic and thermodynamic aspects, and properties descriptions and evaluations. Applications include utilzation in water analyses and wastetreatment, air pollution control and measurement, and in nuclear facilities. (This updated bibliography contains 160 citations, 14 of which are new entries to the previous edition.)
This bibliography contains citations concerning theoretical aspects and industrial applications of activated charcoal. Topics include absorption capacity and mechanism studies, kinetic and thermodynamic aspects, and properties descriptions and evaluations. Applications include utilization in water analyses and wastetreatment, air pollution control and measurement, and in nuclear facilities. (This updated bibliography contains 150 citations, 14 of which are new entries to the previous edition.)
Decomposition of organic compounds contained in the spent ion exchange resins is considered effective in reducing the waste volume. A system using the wet-oxidation process has been studied for the treatment of the spent resins stored at Trino Nuclear Power Plant owned by SOGIN. Compared with various processes for treating sludge and resin, the wet-oxidation system is rather simple and the process conditions are mild. Not contaminated ion exchange resin samples similar to those ones used in Trino NPP were processed by wet-oxidation and appropriate decomposition of the organic compounds was verified. After decomposition the residue can be solidified with cement for final disposal. When compared with direct solidification without decomposition, the number of waste packages can be significantly reduced. Additional measures for conditioning secondary waste products have also been studied, and their ...
The `Hanford Facility Dangerous Waste Permit Application` is considered to be a single application organized into a General Information Portion (this document, DOE/RL-91-28) and a Unit- Specific Portion. The scope of the General Information Portion includes information that could be used to discuss operating units, units undergoing closure, or units being dispositioned through other options. Documentation included in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units. A checklist indicating where information is contained in the General Information Portion, in relation to the Washington State Department of Ecology guidance documentation, is located in the Contents Section. The intent of the General Information Portion is: (1) to provide an overview of the Hanford Facility; and (2) to assist in streamlining efforts associated with treatment, storage, ...
Reclamation of copper mine tailings in a cost effective, successful, and sustainable manner is an ongoing area of evaluation in the arid southwest. A study was initiated in September, 1996 near Hayden, Arizona to evaluate the use of municipal biosolids for reclaiming acidic copper mine tailings (pH of 2.5 to 4.0). The main objectives of the study were to (1) define an appropriate level of biosolids application for optimum plant growth, and (2) evaluate the effects of green waste and lime amendments. The experiment was a randomized complete block design with four biosolid rates of 20, 70, 100 and 135 dry tons/acre, three amendment treatments (none, green waste, and green waste plus lime); with three replications. Non-replicated controls (no treatment, green waste only and lime only) were included for comparison. Shortly after biosolids incorporation to a depth of ...
BIBRA "t"r"a"d"e"m"a"r"k, is the new bio-technological method developed in Gundremmingen for treating radioactive waste water, using bacteria in a process analogous to the long-established principle of communal sewage treatment plants. The method exploits the behaviour of the micro-organisms found there, to establish optimum adaptation of their population for decomposing the typical pollutants found in this washing water. This procedure is particularly suitable for nuclear engineering plants, because in such plants the waste water composition changes little so that the bacteria can achieve optimum adaptation to this waste water. The organic ingredients of the washing media are decomposed by introducing air. The advantage of the procedure is not only the significant reduction of the amount of waste material, but also enhanced efficiency of the cleaning process. The decontamination ...
The Pacific Northwest National Laboratory (PNNL) operates a number of research and development (R and D) facilities for the Department of Energy on the Hanford Site. According to DOE Order 5400.1, a Facility Effluent Monitoring Plan is required for each site, facility, or process that uses, generates, releases, or manages significant pollutants or hazardous materials. Three of the R and D facilities: the 325, 331, and 3720 Buildings, are considered major emission points for radionuclide air sampling and thus individual Facility Effluent Monitoring Plans (FEMPs) have been developed for them. Because no definition of ''significant'' is provided in DOE Order 5400.1 or the accompanying regulatory guide DOE/EH-0173T, this FEMP was developed to describe monitoring requirements in the DOE-owned, PNNL-operated facilities that do not have individual FEMPs. The remainder of the DOE-owned, PNNL-operated facilities are referred to as ...
In the United States today, governments at all levels and the citizenry are paying increasing attention to the effects, both real and hypothetical, of industrial activity on the environment. Responsible modem industries, reflecting this heightened public and regulatory awareness, are either substituting benign materials for hazardous ones, or using hazardous materials only under carefully controlled conditions. In addition, present-day environmental consciousness dictates that we deal responsibly with legacy wastes. The decontamination and decommissioning (D&D) of facilities at which mercury was used or processed presents a variety of challenges. Elemental mercury is a liquid at room temperature and readily evaporates in air. In large mercury-laden buildings, droplets may evaporate from one area only to recondense in other cooler areas. The rate of evaporation is a function of humidity and temperature; consequently, different parts of a ...
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches 'A' and 'B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards for the protection against ionizing radiation and for the safety of radiation sources. ...
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches 'A' and 'B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards for the protection against ionizing radiation and for the ...
Conventional methods for removing metals from aqueous solutions include chemical precipitation, chemical oxidation or reduction, ion exchange, reverse osmosis, electrochemical treatment and evaporation. The removal of radionuclides from aqueous waste streams has largely relied on ion exchange methods which can be prohibitively costly given increasingly stringent regulatory effluent limits. The use of microbial cells as biosorbants for heavy metals offers a potential alternative to existing methods for decontamination or recovery of heavy metals from a variety of industrial waste streams and contaminated ground waters. The toxicity and the extreme and variable conditions present in many radionuclide containing waste streams may preclude the use of living microorganisms and favor the use of non-living biomass for the removal of actinides from these waste streams. In the work presented ...
An evaporator using a hydrophobic membrane made from a polytetrafluoroethylene (PTFE) was developed to improve DF (Decontamination Factor) and to reduce evaporator size. The membrane distillation, provided by the evaporator, is a new technique for liquid purification. Fundamental experiments were carried out to develop the membrane filter (tube type, outer diameter, 8 mm; membrane thickness, 500 {mu}m) for radioactive liquid treatment. The continuous operation test using actual liquid waste was also made during about 3,000 h. (This is almost equal to the operation time of an actual evaporator per year.) The evaporation rate decreased with increase an operation time due to contamination of waste impurity. But the rate was recovered by washing the membrane with hot water and then drying it. DF was over 10{sup 4} which is ten times larger than that for a conventional system. A pilot plant (capacity, 200 kg-liquid ...
Hydrothermal oxidation (HTO) is a promising technology for the treatment of aqueous-fluid hazardous and mixed waste streams. Waste streams identified as likely candidates for treatment by this technology are primarily aqueous fluids containing hazardous organic compounds, and often containing inorganic compounds including radioisotopes (mixed wastes). These wastes are difficult and expensive to treat by conventional technologies (e.g. incineration) due to their high water content; in addition, incineration can lead to concerns related to stack releases. An especially attractive potential advantage of HTO over conventional treatment methods is the total containment of all reaction products within the overall system. The potential application of hydrothermal oxidation (HTO) technology for the treatment of DOE hazardous or ...
A container experiment was conducted to test the hypothesis that uncomposted wool wastes could be used as nutrient source and growth medium constituent for container-grown plants. The treatments were: (1) rate of wool-waste application (0 or unamended control, 20, 40, 80, and 120 g of wool per 8-in. pot), (2) growth medium constituents [(2.1) wool plus perlite, (2.2) wool plus peat, and (2.3) wool plus peat plus perlite], and (3) plant species (basil and Swiss chard). A single addition of 20, 40, 80, or 120 g of wool-waste to Swiss chard (Beta vulgaris L.) and basil (Ocimum basilicum L.) in pots with growth medium provided four harvests of Swiss chard and five harvests of basil. Total basil yield from the five harvests was 1.6-5 times greater than the total yield from the unamended control, while total Swiss chard yield from the four harvests was 2-5 times greater relative to the respective unamended ...
This report is a compilation of the groundwater sampling results from three monitoring wells located near the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS), Nye County, Nevada, for calendar year 2007. The NTS is an approximately 3,561 square kilometer (1,375 square mile) restricted-access federal installation located approximately 105 kilometers (65 miles) northwest of Las Vegas, Nevada (Figure 1). Pilot wells UE5PW-1, UE5PW-2, and UE5PW-3 are used to monitor the groundwater at the Area 5 RWMS (Figure 2). In addition to groundwater monitoring results, this report includes information regarding site hydrogeology, well construction, sample collection, and meteorological data measured at the Area 5 RWMS. The disposal of low-level radioactive waste and mixed low-level radioactive waste at the Area 5 RWMS is regulated by U.S. Department of Energy (DOE) Order 435.1, 'Radioactive ...
Environmental radon monitoring activities at the DOE Fernald Environmental Management Project (FEMP) have been conducted extensively since the early 1980`s. Monitoring has been conducted at ambient concentration levels (< 1 pCi/L Rn-222), inside buildings, and at significantly elevated levels (hundreds of thousands pCi/L Rn-222) within the K-65 silo that store concentrated radium bearing wastes. The purpose of this paper/presentation is to present and discuss some of the difficulties encountered/solutions (e.g. reliability, detection limits, affects of environmental factors, data transfer, etc.) that have been discovered while taking measurements using both alpha track-etch passive integrating detectors and alpha scintillation real-time detectors. A short summary and conclusion section is provided following each topic presented.
The design, construction and operation of a pilot plant are often important stages in the development of a project for the production of uranium concentrates. Since building and operating a pilot plant is very costly and may not always be required, it is important that such a plant be built only after several prerequisites have been met. The main purpose of this guidebook is to discuss the objectives of a pilot plant and its proper role in the overall project. Given the wide range of conditions under which a pilot plant may be designed and operated, it is not possible to provide specific details. Instead, this book discusses the rationale for a pilot plant and provides guidelines with suggested solutions for a variety of problems that may be encountered. This guidebook is part of a series of Technical Reports on uranium ore processing being prepared by the IAEA's Division of Nuclear Fuel Cycle and Waste Management. 42 refs, 7 figs, 3 tabs.
This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period October 1, 2004 through December 31, 2004. The following tasks have been completed. First, the renovation of the new Combustion Laboratory and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building have proceeded well. Second, the detailed design of supporting and hanging structures for the CFBC was completed. Third, the laboratory-scale simulated fluidized-bed facility was modified after completing a series of pretests. The two problems identified during the pretest were solved. Fourth, the carbonization of chicken waste and coal was investigated in a tube furnace and a Thermogravimetric Analyzer (TGA). The experimental results from this study are presented in this report. Finally, ...
This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2004 through September 30, 2004. The following tasks have been completed. First, renovation of the new Combustion Laboratory and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building have started. Second, the design if the component parts of the CFBC system have been reviewed and finalized so that the drawings may be released to the manufacturers during the next quarter. Third, the experiments for solid waste (chicken litter) incineration have been conducted using a Thermogravimetric Analyzer (TGA). This is in preparation for testing in the simulated fluidized-bed combustor. The experimental results from this study are presented in this report. Finally, the proposed work for ...
The Baird and McGuire site is a former chemical manufacturing facility in northwest Holbrook, Massachusetts, approximately 14 miles south of Boston. From 1912 to 1983 the company operated a chemical manufacturing and batching facility on the property. Manufactured products included herbicides, pesticides, disinfectants, soaps, floor waxes and solvents. Waste disposal methods at the site included direct discharge into the soil, nearby brook and wetlands, and a former gravel pit (now covered) in the eastern portion of the site. EPA conducted a removal action at the site in 1983 after a waste lagoon overflowed spreading contaminants into the Cochato River. The company ceased operating shortly thereafter. A second removal action was conducted in 1985, following the discovery of dioxin in site soils. EPA also conducted an Initial Remedial Measure at the site from 1985 through 1987 which involved constructing a new water main to direct water away ...
This paper summarizes the progress to date by CH2M HILL and the UKAEA in development of a parametric modelling capability for estimating the costs of large nuclear decommissioning projects in the United Kingdom (UK) and Europe. The ability to successfully apply parametric cost estimating techniques will be a key factor to commercial success in the UK and European multi-billion dollar waste management, decommissioning and environmental restoration markets. The most useful parametric models will be those that incorporate individual components representing major elements of work: reactor decommissioning, fuel cycle facility decommissioning, waste management facility decommissioning and environmental restoration. Models must be sufficiently robust to estimate indirect costs and overheads, permit pricing analysis and adjustment, and accommodate the intricacies of international monetary exchange, currency fluctuations and contingency. The development ...
This paper summarizes the progress to date by CH2M HILL and the UKAEA in development of a parametric modelling capability for estimating the costs of large nuclear decommissioning projects in the United Kingdom (UK) and Europe. The ability to successfully apply parametric cost estimating techniques will be a key factor to commercial success in the UK and European multi-billion dollar waste management, decommissioning and environmental restoration markets. The most useful parametric models will be those that incorporate individual components representing major elements of work: reactor decommissioning, fuel cycle facility decommissioning, waste management facility decommissioning and environmental restoration. Models must be sufficiently robust to estimate indirect costs and overheads, permit pricing analysis and adjustment, and accommodate the intricacies of international monetary exchange, currency fluctuations and contingency. The development ...
The electrometallurgical treatment process described in this paper builds on our experience in treating spent fuel from the Experimental Breeder Reactor (EBR-II). The work is also to some degree, a spin-off from applying electrometallurgical treatment to spent fuel from the Hanford single pass reactors (SPRs) and fuel and flush salt from the Molten Salt Reactor Experiment (MSRE) in treating EBR-II fuel, we recover the actinides from a uranium-zirconium fuel by electrorefining the uranium out of the chopped fuel. With SPR fuel, uranium is electrorefined out of the aluminum cladding. Both of these processes are conducted in a LiCl-KCl molten-salt electrolyte. In the case of the MSRE, which used a fluoride salt-based fuel, uranium in this salt is recovered through a series of electrochemical reductions. Recovering high-purity uranium from an aluminum-matrix fuel is more challenging than treating SPR or EBR-II fuel because the ...
... of waste food generated at McMurdo Station. Some of the difficulties of disposing of waste food ... change waste generation or management at the site? Yes. This will be a temporary waste management ...
The methods introduced for the field of cleaning waste water can be classified under various processes. Chemical oxidation is done with ozone, hydrogen peroxide and ultraviolet irradiation with subsequent biological decomposition. Another method is ultra-filtration with recovery of valuable materials or waste water ponds with algae biomass to decompose ammonium compounds, nitrates and phosphates. (EF) [Deutsch] Die auf dem Gebiet der Abwasserreinigung vorgestellten Methoden kann man in verschiedene Verfahren einordnen. Die chemische Oxidation erfolgt mit Ozon, Wasserstoff-Peroxid, UV Bestrahlung und anschliessenden biologischen Abbau. Eine andere Methode ist die Ultrafiltration mit Rueckgewinnung von Wertstoffen oder Abwasserteiche mit Algenbiomasse zum Abbau von Ammoniumverbindungen, Nitraten und Phosphaten. (EF)
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two sha...
Actinide recycling by partitioning and transmutation is considered as one of the most promising strategies to reduce the inventory of radioactive waste, thus contributing to make nuclear energy sustainable. To make advances beyond the current state of the art in pyrochemical separations processes, the Domain 2 (DM2) of ACSEPT has been built on considering a process approach based on system studied. Four work packages that represent the main steps of a process block diagram have been identified: head-end steps, core process development, and salt treatment for recycling and waste conditioning. The results obtained in this domain will be integrated in DM 3 (Process) in order to orientate the R and D studies of DM2 and to propose and validate flowsheets at the end of the project. The state of the art on pyrochemical separation within the European Community and the working program of ACSEPT in pyrometallurgy are presented in ...
The present contribution focuses on the input side of individual process techniques. It shows on the basis of example calculations how two parameters describing the incinerable (residual) waste that are of particular importance for unconventional thermal treatment methods, namely ``pollutant load`` and ``calorific value``, can be influenced by a recycling stage and then further by mechanical-biological pretreatment. [Deutsch] Im folgenden soll das Hauptaugenmerk auf die Inputseite zu den einzelnen thermischen Verfahren gelegt werden und anhand einer Beispielrechnung aufgezeigt werden, wie sich die fuer einen Einsatz in nichtkonventionellen thermischen Verfahren besonders wichtigen Parameter des aufbereiteten (Rest)Abfalls `Schadstoffbelastung` und `Heizwert` zunaechst durch eine Verwertung und weiter durch eine mechanisch-biologische Vorbehandlung veraendern. (orig./SR)
An incinerator for the treatment of low-level radioactive solid wastes was installed in Tokai Research Establishment, JAERI, 1966. The incinerator was equipped with a scrubber, cyclone, electrostatic precipitator and HEPA filter. The retention factor (R.F.) of the furnace as well as the decontamination factors (D.F.) of each dust collector were measured using "3"2P as a tracer under various conditions. It was found that the overall D.F. of the incinerator was improved by the increase of the temperature in the furnace, decrease of the off gas flowrate, increase of the charged voltage of the electrostatic precipitator and by the increase of the liquid gas ratio of the scrubber. The overall D.F. of the incinerator (including the R.F. in the furnace) on the standard operating conditions was 9.1x10"6. (auth.).
Normal butylamine compounds are studied as salt-free wash reagents for degraded solvent used in PUREX process in spent fuel reprocessing. The solvent wash tests were carried out with two types of butylamine compounds, n-butylamine oxalate and n-butylamine bicarbonate, by counter-current mode using a small size mixer-settler composed of two 4-stage wash steps. Di-n-butyl phosphoric acid (HDBP), the main degradation product from TBP, was removed from real degraded solvent with decontamination factor of 2.5 {approx} 7.9. The study on electrolytic decomposition of butylamine compounds was also conducted for wastetreatment.
EPA has proposed effluent limitations guidelines and standards for the centralized wastetreatment (CWT) industry. This report investigates the cost-effectiveness of all possible combinations of proposed control options for the three subcategories of CWT operations. EPA considered three control options for metals, two for oils and two for organics, with 12 possible combinations of these options. The report measures cost-effectiveness through a comparison of compliance costs to the quantity of pollutants removed under each combination of control options. The effectiveness of the regulations is measured in terms of reductions in the pounds of pollutants discharged to surface waters, weighted to account for the pollutants` toxicity. Some pollutants removed are specifically addressed by the regulation, while others and not directly regulated but are removed incidentally as a result of controlling for other pollutants.
The suitability of calcium silicate bricks (CSBs) for the retrospective measurement of gamma dose using luminescence techniques has been investigated. Bricks of this type are distinguished from fired clay bricks by containing negligible clay and requiring comparatively low temperature treatment during manufacture. They have been used widely in the construction f buildings in the Former Soviet Union since the 1970s but hitherto have not been used for retrospective dosimetry measurements. A procedure based on the se of the 210 deg. C thermoluminescence (TL) peak of quartz was tested with granular quartz extracted from three types of CSB, one of which had been taken from a settlement downwind of Chernobyl. The degree to which the residual geological TL signal within the temperature range of the 210 deg. C L peak had been reduced during manufacture varied with brick type; the levels of residual TL corresponded, in the samples tested, to absorbed ...
Animal carcasses from slaughterhouses are usually composted on farms, but the composting process is not optimized and a large volumes of carbonaceous residues are needed. This type of composting takes place over a period of 6 to 9 months in a nonaerated static pile. Quebec's industrial research centre (CRIQ) developed an organic biodrying process (BIOSECO) adapted to large-scale operations in order to optimize the treatment of slaughterhouse residues. Biodrying is a form of composting, in which the thermophilic phase is optimized, making it possible to evaporate large amounts of water. Biodrying is done inside a building and reduces the amount of carbonaceous residues considerably. The process is optimized by the sequence in which the slaughterhouse residues are added, the choice of input and the aeration flow. Slaughterhouse residues can be treated non-stop throughout the entire year. Since the odours are nearly completed limited to ...
The use of entire plant communities of native species is gaining interest in the green roof industry. Plant communities must be matched with environmental conditions that mimic conditions in their original habitats. Urban built environments do not differ significantly from the rocky outcrops with poor, shallow soil that many plants colonize. This paper provided details of an experiment investigating the impact of plant community structure and species diversity on living roof performance. The aim of the experiment was to determine the impact of species diversity on precipitation interception, nutrient retention, temporal biomass constancy and roof temperature constancy. The diversity treatment included separate monocultures of 8 species in the community, randomly determined mixtures of 4 species, and a mixture of all 8. Functional groups included mosses, liverworts, colonial algae and a mycorrhizal inoculum. In a second experiment, between 1 and 4 of the functional ...
The purpose of this paper is to evaluate a complete set of environmental pathways for disposal options and conditions that the Nuclear Regulatory Commission (NRC) may analyze for a low-level radioactive waste (LLW) license application. The regulations pertaining In the past, shallow-land burial has been used for the disposal of low-level radioactive waste. However, with the advent of the State Compact system of LLW disposal, many alternative technologies may be used. The alternative LLW disposal facilities include below- ground vault, tumulus, above-ground vault, shaft, and mine disposal This paper will form the foundation of an update of the previously developed Sandia National Laboratories (SNL)/NRC LLW performance assessment methodology. Based on the pathway assessment for alternative disposal methods, a determination will be made about whether the current methodology can satisfactorily analyze the pathways and phenomena likely to be ...
Full text: During JET operations, tritium contaminated waste is generated principally but not exclusively from 'intervention' work and from removing or replacing redundant items. It is essential for JET and for any future fusion plant to have available a route for managing each waste stream however large or small, both during operation and decommissioning of the plant. The long term outcome is to have for each tritiated waste stream from JET a route for its management leading to its eventual disposal or recycling (and thus to be available for similar waste streams which will be produced by ITER operations). Since several years SCK#centre dot#CEN has been developing techniques for the treatment of tritiated waste. Amongst them, technologies for water detritiation, for the treatment of tritiated organic liquids and for the decontamination of ...
This report provides a chronological history of policies and practices relating to the management of radioactive waste for which the US Atomic Energy Commission and its successor agencies, the Energy Research and Development Administration and the Department of Energy, have been responsible since the enactment of the Atomic Energy Act in 1946. The defense programs and capabilities that the Commission inherited in 1947 are briefly described. The Commission undertook a dramatic expansion nationwide of its physical facilities and program capabilities over the five years beginning in 1947. While the nuclear defense activities continued to be a major portion of the Atomic Energy Commission`s program, there was added in 1955 the Atoms for Peace program that spawned a multiplicity of peaceful use applications for nuclear energy, e.g., the civilian nuclear power program and its associated nuclear fuel cycle; a variety of industrial applications; and medical research, ...
Red mud is a waste and tail material from primary aluminum production, and is named for its color, coming from its iron oxide content. The quantity of red mud is almost equal to the primary aluminum production and leads to a considerable environmental issue. Red mud of the ETI Seydisehir Aluminum Plant is considered as detrimental waste for storage due to its content of various metal oxides, elements and caustics. This detrimental effect is classified into two groups: first, environmental health and second, the cost of storage. In order to minimize the negative effect of red mud, there have been or are presently many investigations carried out on usage of red mud in building materials. However, no effective way of utilizing red mud has yet been found. In this study domestic red mud was investigated and chemical analyses were performed by EDAX and XRF techniques. Radioactivity of the samples was also measured with gamma ...
Embracing the notion of going green, an affluent school district in Pennsylvania spent $83 million as part of the high school's renovation and expansion project. The three-level addition is now equipped with self-dimming lights, energy-efficient windows, a rooftop solar water heater, and a geothermal cooling and heating system. As a bonus for going green, the school district received a $250,000 grant from the Pennsylvania Department of Environmental Protection. The district used that money to create an information center in the lobby of the building where a touch-screen computer provides students, staff, and visitors with data related to the operation of the school's energy-efficient water and electrical systems. The system will graphically depict utility use over the course of a year. The monitoring system and touch-screen computer can turn this school into a living lab, with science, math, and economics teachers using the data as teaching tools within classrooms. ...
Contents: Introduction; Design Criteria for a Green Building; Comparison of Energy Efficiency Measures; Whole House Energy Efficiency; Built Examples of Energy Efficient Houses; and Product Energy of Building Elements.
In situ treatment has been proposed as a remediation alternative for surface water and groundwater contaminated with uranium and nitrate as a result of former waste disposal practices in the S-3 Ponds. Interceptor trenches containing reactive media have been proposed to treat groundwater, and constructed wetlands and/or algal mats are potential alternatives for treating surface water. This report presents the results from testing of ten different reactive media, and combinations of media, that are candidates for use in the proposed interceptor trenches to remove uranium and nitrate from groundwater. It also presents the results of testing and evaluation of algal mats and wetlands for removing uranium and nitrate from surface water.
This paper introduces the solid radwaste management system, treatment methods and its continuous improvement during the past 9 years in Guangdong Daya Bay Nuclear Power Station (GNPS). GNPS has paid great attention and made a lot of efforts to implement the principle of waste minimization with source control, improvement of treatment process and strict management, so the output of solid radwastes has annually decreased since 1994. In 2002, the output of solid radwastes in GNPS was 63.5 m"3, only 50% of 1995 (127 m"3), reached the advanced level as the same type NPPs in France. During the period 1994-2002, the accumulated production of solid radwaste Packages in GNPS is 1563.51 m"3 only 18% of the design value; all the packages meet the standard and requirement for safe disposal. Besides, this paper analyzes some new technical processes and presents some proposals for further decreasing the solid radwaste production
Increasingly, governments enact more stringent regulations governing nitrogen and phosphorus in the discharge effluent of wastewater treatment plants. Scientists know that nitrogen and phosphorus accelerates the eutrophication of lakes and reservoirs and stimulates algal growth. Ammonia has proven to be toxic to aquatic life forms, including fish. Engineers favour Biological Nutrient Removal (BNR) over chemical addition to wastewater treatment. Sequencing Batch Reactors (SBRs), a type of bioreactor requiring less land, provide the anaerobic, anoxic, and aerobic zones necessary for BNR. Methanol was used as an effective external source of carbon for denitrification but lacked research. The authors remedied this situation and some of the results were available. They indicated that the addition of methanol in the SBR increased solids production in the SBR, leading to increased sludge wasting to the aerobic digester. All ...
The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had virtually zero impact on both foaming and the dissolution of silica particles. Over 100 sites in the United ...
The Conference on Building Design and Architecture organized by Swedish Council for Building Research Contents included articles on building physics, thermal-climate technology, and building location and planning.
A research report presents the basic data required when designing a building with minimal environmental impacts. Topics covered include the energy consumption of building elements during their lifetime, the environmental implications linked to the extraction and processing of building material and the energy consumed in buildings by the occupants. (UK)
The Waste Sampling and Characterization Facility (WSCF) complex consists of the main structure (WSCF) and four support structures located in the 600 Area of the Hanford site east of the 200 West area and south of the Hanford Meterology Station. WSCF is to be used for low level sample analysis, less than 2 mRem. The Laboratory features state-of-the-art analytical and low level radiological counting equipment for gaseous, soil, and liquid sample analysis. In particular, this facility is to be used to perform Resource Conservation and Recovery Act (RCRA) of 1976 and Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 sample analysis in accordance with U.S. Environmental Protection Agency Protocols, room air and stack monitoring sample analysis, waste water treatment process support, and contractor laboratory quality assurance checks. The samples to be analyzed contain very low concentrations ...
The Raywell Process Plants unit, which reclaims a wide range of organic solvents, including chlorinated hydrocarbons, is based on thin film evaporation and distillation rather than steam distillation, thus reducing the risk of contamination by water. Henry Balfour and Co.'s Pfaudler Solvent Recovery System gives 96% or better solvent recovery and produces a near-solid waste suitable for landfill disposal; like the Raywell system, it uses a mechanically wiped thin-film evaporator. Midland Oil Refineries uses sa Raywell thin-film evaporator for recovery of waste lubricating oils rather than the conventional sulfuric acid/clay treatment, thus avoiding formation of sulfuric acid sludge waste. The Henry Balfour Bioenergy anaerobic digestion system gives yields of fuel gas with 65-75% methane as high as 0.8 cu m/kg BOD; it achieves 95-98% BOD removal with no pH control or nutrient addition because it ...
The evolution of the technology of waste combustion, energy recovery and flue gas treatment allows to redefine the role of the incineration plant as a basic component of integrated waste management systems. Starting with an overview of the evaluation of emission limits and of the new Best Available Techniques (BAT) approach, strongly recommended by the European Union, the paper reports an overview of the stack emission concentrations measured in recent plants in Italy compared to older ones, with special attention to the dioxin issue. Concerning this topic, it is demonstrated that BAT-equipped plants can act as actual dioxin destroyer rather than producers, even when all the fluxes released in the environment (gaseous, solid and liquid residues) are taken into account. The second part of the paper deals with the evolution of the flue gas control technologies of the last 20 years, pointing out the major trends and the future ...
Anaerobic treatment of olive oil mill wastewaters (COD up to 220 kg/cubic m) is feasible, and the most promising results were obtained on UASB reactors, both at laboratory and pilot scale (tank capacity 15 litres and 5 cubic m), fed on diluted waste (COD = 13-18 kg/cubic m). Volumetric loading rates ranging from 16-21.5 kg COD/cubic m/day and 70% removal efficiencies were obtained with these digesters. Start-up of UASB reactors fed on olive oil mill waste is a delicate step which still has to be fully controlled and optimized. The best results were obtained by starting with very diluted waste (COD = 5 kg/cubic m). Granulation of the sludge, as achieved in Dutch UASB digesters fed on sugar beet wastewaters, was not obtained, but, even so, the settleability of the sludge was very good. 22 references.
In this study based on the mass transfer theory, experiments for the evaporation rates depending on various conditions were carried out through the operation of the existing Natural Evaporation Facility in KAERI. Evaporation media were made of the cotton and polyester. Air circulation in the facility was forced by exhausting fans. The evaporation rate and the decontamination factor were calculated by the result of experiment. The evaporation rate increased as the flow rate of air supply, the feed rate of liquid waste, and the temperature of supplied air increased. As for the humility of supplied air, the evaporation rate was getting higher as the humidity was getting lower. As the result of this study, operation conditions of the Natural Evaporation Facility are optimized as follows; The air temperature above 8C .deg., the air humidity below 70%, the air flow rate 1.14-1.47 m/sec, and the liquid waste feed rate 4.6l/hr.m"2. The decontamination ...
By treatment with beta or gamma rays, PTFE waste is converted to high-grade PTFE fine powder. High-molecular weight PTFE is degraded to low-molecular weight PTFE. Due to this the density, the degree of crystallinity, and the melt flow index are increased, which enhances the brittleness of the material. Irradiation of PTFE thus facilitates milling and makes the material pourable and free-flowing. Milled PTFE fine powder, lie PTFE plastic, combines temperature resistance, weather fastness, and chemical stability with good slip behaviour and antiadhesive properties. Areas of application for fine powder include additives for plastics, printing inks, nonstick coatings, and antifriction lacquers. (orig.).
During a high temperature treatment of the radioactive wastes that contain ruthenium, some ruthenium is volatilized and released to the off gas system. The volatilized ruthenium is removed with a scrubber and an adsorber. It was expected that the scrubber was one of the most effective equipments to remove ruthenium and the decontamination factor of the scrubber was studied. The experimental apparatus was simulated as part of an actual perforated plate column scrubber. The non-radioactive ruthenium which simulated the radioactive ruthenium was volatilized and fed into the scrubber. The decontamination factor of the scrubber was determined by the ratio of the ruthenium concentration at the inlet and outlet of the scrubber off gas stream. The results showed that the scrubber removed the volatile ruthenium effectively as expected.
The report presents a summary of the work of the Department of Nuclear Safety Research and Nuclear Facilities in 1995. The department`s research and development activities are organized in three research programmes: Radiation Protection, Reactor Safety, and Radioanalytical Chemistry. The nuclear facilities operated by the department include the Research Reactor DR3, the Isotope Laboratory, the WasteTreatment Plant, and the Educational Reactor DR1. Lists of staff and publications are included together with a summary of the staff`s participation in national and international committees. (au) 5 tabs., 21 ills.
As an application of ART2 neural networks, computer aided monitoring of pump efficiency is successfully examined for an industrial waste-liquid treatment process with measured data of valve openness and liquid flow rates. By running the neural networks in parallel, we confirm that accuracy to detect system changes is good, and the adjustment of classifier parameters is relatively easy. Investigating the resulting classes carefully, frequency of each class is correlated with pump efficiency. The relative amount of variables are also related to the classes. (author)
Recycling of used battery for recovering lead done by either small household/small scale industries has been identified as a source of air pollution, especially by heavy metal (Pb). This condition give an adverse impact toward workers and societies. Technological aspect is one of the causal. The process apply an open system. Therefore, a lot of energy, as well as dust wasted to the air without prior treatment. For overcoming this condition, closed system by utilizing Cupola furnace will be offered as one of the alternatives clean technology application and to increase the recovering performance in order to set an effective and efficient result. (author)
Selected samples of waste microbial biomass originating from various industrial fermentation processes and biological treatment plants have been screened for biosorbent properties in conjunction with uranium and thorium in aqueous solutions. Biosorption isotherms have been used for the evaluation of biosorptive uptake capacity of the biomass which was also compared to an activated carbon and the ion exchange resin currently used in uranium production processes. Determined uranium and thorium biosorption isotherms were independent of the initial U or Th solution concentration. Solution pH affected the exhibited uptake. 24 refs.
The exergy method is used to compare different production processes and various methods for emission abatement with respect to their overall environmental impact. Some ammonium nitrate production processes are studied as examples, because the pollutants (ammonia and ammonium nitrate), emitted from these processes into the air and/or into the water, are really a feedstock and a product from the production process. Therefore, the essential result of the waste flows treatment is the recycling of the pollutants (ammonia and ammonium nitrate) back into the production process, decreasing simultaneously the exergy input and cumulative exergy consumption. (author)
A successful boron neutron capture treatment (BNCT) of a patient with multiple liver metastases has been first given in Italy, by placing the removed organ into the thermal neutron column of the Triga research reactor of the University of Pavia. In Finland, FiR 1 Triga reactor with an epithermal neutron beam well suited for BNCT has been extensively used to irradiate patients with brain tumors such as glioblastoma and recently also head and neck tumors. In this work we have studied by MCNP Monte Carlo simulations, whether it would be beneficial to treat an isolated liver with epithermal neutrons instead of thermal ones. The results show, that the epithermal field penetrates deeper into the liver and creates a build-up distribution of the boron dose. Our results strongly encourage further studying of irradiation arrangement of an isolated liver with epithermal neutron fields.
Despite the current global economic crisis, the Cleantech industry has excellent growth prospects. Especially technologies for water treatment, energy efficiency in buildings and combined heat and power will face high demand and high growth rates in the coming years, just like the suppliers for the wind and solar industry. Today German companies are market leaders in these segments. However, there is a threat that they will lose this competitive position as international competition increases. Besides attractive incentive schemes and regulatory framework, access to venture capital and the fast expansion to international markets is an important factor to secure the leading market position of German Cleantech companies. (orig.)
Various kinds of decontaminations are carried out in atomic power plant. Here current decontamination technologies such as chemical decontamination with chemical solution or blast decontamination have a problem of reduction of secondary radioactive waste generated in the decontamination process. On the other hand, a low pressure arc plasma can remove metal oxide film on the metal substrate without heavy damage on the metal substrate when the object to be treated was set as a cathode. Dry surface decontamination technology with using low-pressure arc plasma can decrease secondary radioactive waste because low-pressure arc plasma does not need any chemical solution. In addition, the time required for treatment can be shorter, so it is possible for the low-pressure arc plasma decontamination technology to interpolate the current decontamination technologies such as spot decontamination technology etc. Therefore we have been ...
The primary objective of this task was to perform a variability study of the high activity waste (HAW) acidic feed to determine the impact of feed variability on the quality of the final grout and on the mixability of the salt solution into the dry powders. The HAW acidic feeds were processed through the neutralization/pH process, targeting a final pH of 12. These fluids were then blended with the dry materials to make the final waste forms. A secondary objective was to determine if elemental substitution for cost prohibitive or toxic elements in the simulant affects the mixing response, thus providing a more economical simulant for use in full scale tests. Though not an objective, the HAW simulant used in the full scale tests was also tested and compared to the results from this task. A statistically designed test matrix was developed based on the maximum molarity inputs used to make the acidic solutions. The maximum molarity inputs were: 7.39 ...
It is possible to slow down the progression of Alzheimer's disease with pharmacological treatment. When this treatment is given to people with types of dementia that affect the frontal and temporal lobes (Frontotemporal Dementia) the results are discouraging. It is observed that the patients show pronounced restlessness and mania. In this article we describe a nonpharmacological psychosocial approach, music therapy, and how it is possible to work with this method when constitutional, regulative, dialogical, and integrative aspects are included. The focus is on therapeutic singing where well-known songs are applied in order to build up structure and stability and/or as means of arousal regulation. Songs with personal meaning make it possible to acknowledge the person's emotions, breaking the social isolation, and meeting the music therapy participant's psychosocial needs. The clinical approach is an integration of a ...
A measurement of environmental radioactivity in Tokyo was started from 1974. We have been executing fixed time and fixed point observation since 1983 in Tokyo continuously. Measurement item is rain water, airborne dust, activated sludge at sewage treatment plants and external dose rate. Measurement data from 1983 to 1995 is reported in this paper. Moreover, we have been carried out the measurement of radon concentration in air from 1988 to 1991 in different types of residental buildings. The measurement results of rain water, airborne dust, external dose rate were approximately a background level respectively except for the Chernobyl nuclear power plant accident. Radionuclides used as radiopharmaceuticals were detected in the activated sludge at every sewage treatment plant but its concentration was lower than concentration limit in Japan. From a result of radon concentration measurements, there were no place which exceeds ...
A method is described for immobilizing or solidifying waste material, which includes blending the waste material with powdered metal and subjecting the mixture of waste material and powdered metal to high pressure. (author).
Recently, in various production engineering of inorganic chemistry system, a large quantity of acids such as nitric acid and hydrocholoric acid have been used, the examples that acid and slats with high concentration are included in the sewer, treatment technique of acid-effluent in the sewer has been known as the diffusion-dialysis, acid-retardation using anion exchange resin. In this report, treatment and properties of acid-effluent recovery and effect of a coexisting slat by the diffusion-dialysis and acid retardation were compared. In the acid retardation, the concentration beyond the solution system can be recovered when the flow interval between waste acid and water was selected appropriately. In the diffusion-dialysis, it has a tendency that rate of recovery was low in the week acid. However, even in the case of which metal irons form complex anion, it is possible that acid and slat were separated well. 7 refs., 11 ...
As part of their corporate policy on environmental protection, Chevron, has taken an approach to work collaboratively with other industry members, universities and government agencies in phytoremediation research. The petroleum industry is interested in the integration of phytoremediation with the many biotechnology treatment technologies currently being used by the industry. Phytoremediation is a complex technology that does not just transfer wastes to another site, but offers in-situ final use and disposal treatment at sites anywhere in the world. Sites for potential remediation range from abandoned large refineries, chemical plants, or small urban gas stations. Research has focused on the cleanup of metals and hydrocarbons in diverse types of soil, water and groundwater conditions. This includes research into remediation of petroleum contaminants such as total petroleum hydrocarbon (TPH), polynuclear aromatic ...
...Species - see CITES Trade of Dangerous Chemicals Transport and Environment U Urban Environment Use of natural resources V Volatile Organic Compounds W Waste Landfills Waste electrical and electronic equipment - see WEEE Waste incineration Waste legislation - reporting Waste management planning Waste oils Waste shipments Waste water - see Urban waste water Water Bathing Water Drinking water Floods Marine environment Urban waste water Water Framework Directive WEEE - Waste Electric and Electronic Equipment Wildlife ...
The Conference on Building Design and Architecture organized by Swedish Council for Building Research Contents included articles on building physics, thermal-climate technology, indoor-air-quality technology, construction materials, quality assurance, and building policy and regulation.
Untreated landfill leachates and wastes from metal plating and mining operations are sources of environmental contamination by heavy metals. Because of their toxicity and potential for accumulation, the discharge of heavy metals must be controlled. Standard physical and chemical treatments used to remove metals from wastes such as concentration by electro-precipitation, ion exchange, solvent extraction, evaporative recovery, and conventional precipitation, are usually expensive and produce high quantities of sludge. Biosorption is the removal of metals from aqueous solutions by microorganisms. It is called biosorption rather than bioadsorption or bioaccumulation because the mechanisms of removal are not restricted to adsorption or metabolic uptake and so the more general term is preferable and has come to be accepted. In this thesis the focus is one two microorganisms and two metals. However, the possible combinations of ...
The nation's wetlands are a valuable resource serving many important natural, industrial, commercial and recreational functions. Wetlands protect shore areas from waves and storms; act as storage areas for flood waters; remove waste from water by trapping soils or silt which settle to the bottom; improve water quality and reduce pollution; are a commercial breeding ground for fish and other foods; and provide space for recreation and habitat for wildlife. They also are located in prime industrial development areas. Recent wetlands losses have caused much public outcry, politicking and regulatory efforts to prevent this trend. During the '90s, the public will see efforts to strike a proper balance regarding wetlands use. Today, wetlands protection is a permitting issue for nearly every major industrial or commercial development and expansion project. Wetlands permit requirements affect a range of business entities. Any project that involves ...
France has committed herself to keep in 2010 the same levels of greenhouse gas emissions as those of 1990, i.e. 144 millions of tons of carbon equivalent (MtCe). However, taking into account the existing pollution abatement measures and the measurements performed so far, the greenhouse gases level should reach 160 MtCe in 2010. Therefore, the inter-ministry commission on greenhouse effect decided on November 27, 1998 to elaborate a new national plan of fight against greenhouse effect. The elaboration of the new plan has fallen under the responsibility of the inter-ministry mission of greenhouse effect (MIES). The new plan was presented by the prime minister, L. Jospin, on January 19, 2000. This document summarises the content of the new plan: architecture (modalities of elaboration, content), measures for the reduction of greenhouse gas emissions (industry, transportation sector, buildings, agriculture-forestry, wastes valorization, development ...
Concerning the gamma emitters, the only analysis on soils put in evidence the presence of cesium-137 ({sup 137}Cs), that does not come from the cyclotron functioning but from past man action as the Chernobylsk accident and the nuclear weapon tests in atmosphere. Independently of the functioning of the installation, we observe an increase of the ambient gamma radiation only near radioactive waste storage. It results of the storage of the former cyclotron elements. The induced increase is moderated because at 5 meters the values do not exceed the background noise. In relation with the functioning of the installation an increase of the ambient gamma radiation is noticed. Two causes are to considered: the release of radionuclides in atmosphere with gaseous effluents and the radiance of radiation sources inside the building. After the stopping of the installation (48 h at least), no increase of gamma radiation is observed. About the neutrons ...
In the framework of the feasibility study of radioactive waste disposal in deep geologic formations, a clay formation (named 'argilite de l'Est') has been selected in the Meuse-Haute Marne region (France) for the construction of an underground laboratory. The percolation of alkaline solutions through the argilite has been studied using column experiments with short residence times (30 min). These experiments simulate the leaching of a cement which could be used in the building materials of the laboratory. The alkaline solutions used are mono-cationic solutions of calcium, sodium and strontium. The behaviour of calcium is differentiated from the other cations. For all alkaline solutions (NaOH, Ca(OH){sub 2} or Sr(OH){sub 2}) chemical reactions consuming both hydroxide ions and their associated cations have been evidenced. These reactions are heterogenous reactions of surface adsorption by site ionization. The calcium ...
Clay-based materials can be cold-stabilized using binder and formed by extrusion. This paper deals with the properties of such materials under the influence of silico-aluminous flying ashes addition. Flying ashes are solid industrial wastes produced by coal combustion. Characteristics of ashes bearing clay-based products, such as dimensional stability, water and mechanical resistance, accelerated aging, are considerably improved with respect to simple clay-binder mixtures. This is principally due to a better hydration of the binder in ashes-bearing mixtures because of: a higher free-water availability as a consequence of the smaller specific surface of ash grains, the filler effect of ash grains which do not participate to the reactions, the specific property of silico-aluminous ashes that can fix the lime in presence of water to produce hydrated compounds. These ashes-bearing clay based materials can have the same qualities as classical ...
This purpose of this report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period April 1, 2005 through June 30, 2005. The following tasks have been completed. First, the new Combustion Laboratory was occupied on June 15, 2005, and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building is in the final painting stage. Second, the fabrication and manufacturing contract for the CFBC Facility was awarded to Sterling Boiler & Mechanical, Inc. of Evansville, Indiana. Sterling is manufacturing the assembly and component parts of the CFBC system. The erection of the CFBC system is expected to start September 1, 2005. Third, mercury emissions from the cofiring of coal and chicken waste was studied experimentally in the laboratory-scale simulated ...
This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period January 1, 2005 through March 31, 2005. The following tasks have been completed. First, the renovation of the new Combustion Laboratory is nearly complete, and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building is in the final stages. Second, the fabrication and manufacture of the CFBC Facility is being discussed with a potential contractor. Discussions with potential contactor regarding the availability of materials and current machining capabilities have resulted in the modification of the original designs. The selection of the fabrication contractor for the CFBC Facility is expected during the next quarter. Third, co-firing experiments conducted with coal and chicken waste ...
In order to effectively recover uranium, rotation speed of solid cathode was examined, and effect of uranium concentration and current density on electrodeposition were confirmed. And the potentiostatic and galvanostatic electrorefining experiments were conducted. Element used in the experiments were Zr, Nd, La chlorides. The reduction potentials of chlorides metals on liquid Cd cathode were measured by cyclic voltammetry experiments. The electrowinning experiments were performed in order to recover small amounts of uranium in salt. Experimental set-up for the batch type reductive extraction experiments were developed and installed. On the base of experimental results of batch type, multi-stage extraction equipment was set-up, and optimum number of stage and recover yield were measured. In the oxidative extraction study is examine selective separation behavior of the rare earth metals from alloy composed of actinide and lanthanide metals to determine the effective separation condition. ...
9 9 simulated Purex waste oxides was investigated as a function of Na/sub 2/O, CaO and P/sub 2/O/sub 5/ content. All compositions lost some sulfate at 50 to 100 deg C above the softening point. In generai the volatility decreased with increase of either Na/ sub 2/O or CaO relative to P/sub 2/O/sub 5/, but no simple correlation Was indicated. Softening temperatures were lowered by inc ease in Na/sub 2/O vs CaO. Ceramic solids were obtained but no true glasses. Attempts to produce glasses by addition of varying combinations of Al/sub 2/O/sub 3/, PbO, BaO, and B/sub 2/O/ sub 3/ to simulated Pure x waste plus phosphite were unsuccessful. The use of 0.005 M Na/sub 2/C/O/sub 3/ to precipitate calcium from wastes containing up to 3 ppm of phosphate was demonstrated in four pilot plant runs and produced a decrease in the hardness of the waste leaving the clarifier. An inadvertent ...
For purposes of assessing the dumpability of wastes, Article 1 - Ordinance on the Environmentally Responsible Landfilling of Household Wastes (AbfAblV) - of the Ordinance on the Environmentally Responsible Landfilling of Household Wastes and Biological WasteTreatment Plants defines classificaton criteria for biologically and mechanically treated wastes destined for landfilling. The practical experiences that have been gathered with these classification criteria and values were evaluated in a questionnaire-based survey. This was done in particular for the purpose of verifying and validating proposals on the methodology of respiration and fermentation tests. A general finding has been that the application and implementation of the regulations of the AbfAblV is fraught with difficulties. This is evident for one thing in the frequency of analyses and for another in ...
Red mud is a solid waste produced in the process of alumina extraction from bauxite. In this paper, recovery iron from Bayer red mud was studied with direct reduction roasting process followed by magnetic separation, and then building materials were prepared from alumosilicate residues. After analysis of chemical composition and crystalline phase, the effects of different parameters on recovery efficiency of iron were carried out. The optimum reaction parameters were proposed as the following: ratio of carbon powder: red mud at 18:100, ratio of additives: red mud at 6:100, roasting at 1300 deg. C for 110 min. With these optimum parameters, total content of iron in concentrated materials was 88.77%, metallization ratio of 97.69% and recovery ratio of 81.40%. Then brick specimens were prepared with alumosilicate residues and hydrated lime. Mean compressive strength of specimens was 24.10 MPa. It was indicated that main mineral phase transformed ...
Except nuclear industry, diverse structures (hospitals, of research or manufacturers) can have appeal to the use of radioisotopes conditioned under unsealed shape. Such practices lead to tolerate releases in environment in the respect of a statutory device. So the collective network can contain radioisotopes the future of which is going to depend partially on the cleaning applied to waste water. This study through the analysis of a concrete case, has for objective to inform about the future of gamma radioelements present in waste water treated by a wastewater treatment plant. The contamination of the network is essentially due to Tc{sup 99} and I{sup 131}, radioelements present whatever the working day and the hour considered. The total estimated in-load for a day is important, of the order of 4000 MBq for Tc{sup 99} and 15 to 300 MBq for I{sup 131}. The assessment of cleaning of the station shows that this one plays a role ...
In a case study of the River Lahn, Hessen, Germany, the ecological impact of effluents from sewage treatment plants was investigated. These emissions have a significant impact on the receiving water quality with ammonia, nitrite, phosphorus and the eutrophication as most important factors. Current legislation standards seem to be sufficent for the sanitation of the nitrogen load. The potential of phosphorus removal in sewage treatment plants however may not reach the demand for eutrophication abatement. Therefore, integrated and immission oriented strategies are required including in site measures of river restoration. (orig.) [Deutsch] An der hessischen Lahn wurde in einem mehrjaehrigen Forschungsvorhabens die Bedeutung von Abwasserereinleitungen aus Klaeranlagen hinsichtlich ihrer gewaesseroekologischen Relevanz untersucht. Wesentliche Belastungen beziehen sich auf die Parameter Ammonium, Nitrit und Phosphor sowie eutrophierungsbedingte ...
Recycling and disposal of spent sodium-sulfur (Na/S) batteries are important issues that must be addressed as part of the commercialization process of Na/S battery-powered electric vehicles. The use of Na/S batteries in electric vehicles will result in significant environmental benefits, and the disposal of spent batteries should not detract from those benefits. In the United States, waste disposal is regulated under the Resource Conservation and Recovery Act (RCRA). Understanding these regulations will help in selecting recycling and disposal processes for Na/S batteries that are environmentally acceptable and cost effective. Treatment processes for spent Na/S battery wastes are in the beginning stages of development, so a final evaluation of the impact of RCRA regulations on these treatment processes is not possible. The objectives of tills report on battery recycling and disposal are as follows: ...
A survey is given on the results in hand on the natural radioactivity of building materials. It is shown that only a small percentage of building materials has an increased content of radioactive materials. The results are compared with approximate values given in a Russian publication. (orig./AK).
;Contents: Energy Use; Building Fabric Performance; Ventilation and Infiltration; Passive Solar Design; Heating Systems and Controls; Hot and Cold Water Provision; and Lighting and Electrical Appliances.
The development of comfort in buildings throughout the centuries was influenced by the demand for progress, wealth and innovation in various respects. At present, it seems that progress may only be possible by taking into account the environment and creat...
Contents: Energy Use; Building Fabric Performance; Ventilation and Infiltration; Passive Solar Design; Heating Systems and Controls; Hot and Cold Water Provision; and Lighting and Electrical Appliances.
Batch and dynamic flow biosorption studies were carried out using the waste biomass entrapped in silica-gel matrix for the removal of nickel(II) ions from synthetic solutions and real wastewater. Batch biosorption conditions were examined with respect to initial pH, S/L ratio, contact time, and initial nickel ion concentration. Zeta potential measurements showed that immobilized biosorbent was negatively charged in the pH range of 3.0-8.0. The immobilized biomass was found to possess relatively high biosorption capacity (98.01 mg g{sup -1}), and biosorption equilibrium was established in a short time of operation (5 min). The equilibrium data were followed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Scanning electron microscope analysis was used to screen the changes on the surface structure of the waste biomass after immobilization and nickel(II) biosorption. Sorbent-sorbate interactions were confirmed by Fourier ...
Canada's environmental performance is compared to the 28 other nations in the Organization for Economic Cooperation and Development (OECD). Twenty-five environmental indicators in ten categories are examined. These are: air, water, energy, biodiversity, waste, climate change, ozone depletion, agriculture, transportation and miscellaneous. Results show Canada with the poorest environmental record of all OECD countries, except the United States. The statistical information, compiled from data verified and published by the OECD, shows Canada among the worst three countries on nine indicators (per capita GHG emissions, CO and VOCs emissions, water consumption, energy consumption, energy efficiency, volume of timber logged, generation of nuclear waste, and the highest amount of energy consumed per unit of GDP). Tracking Canada's energy performance over the past two decades reveals that the situation is worsening in terms of water and energy ...
This Process Waste Assessment was conducted to evaluate the two largest hazardous waste streams generated on-site at Sandia National Laboratory (SNL)/California -- ``Other Inorganic Solid Waste`` and ``Empty Containers <30 Gallons.``
1 to the operator of a waste collective system by an agreement or contract. The conditions for the ...Fees of the waste collective system are subject to the supervision of the authority responsible for market surveillance. ...The operator of waste collection system collects wastes from producers and holder and transports these to a collection
This book contains the results of an architectural evaluation of building examples with integrated photovoltaic. Danish Building and Urban Research and Danish Technological Institute conducted the work within the framework of Solar Energy Centre Denmark. Seven examples are selected to inspire Danish architects and building owners to use PV in the building environment. The examples come from Denmark and countries (the Netherlands and Germany) with similar building traditions, climate and solar conditions. All the examples demonstrate architectural concepts that integrate photovoltaic as a natural part of the building envelope. (BA)
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO{sub 2}, PrO{sub 2}), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements to their molten salt-insoluble ...
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements to their molten salt-insoluble precipitates were ...
The Department of Energy selected caustic-side solvent extraction (CSSX) as the preferred cesium-removal technology for SRS high-level waste. In the pretreatment step of the CSSX flowsheet, the incoming salt solution, which contains entrained sludge, is contacted with MST to adsorb strontium and selected actinides. An alternative approach replaces MST with the addition of sodium permanganate, strontium nitrate, and hydrogen peroxide. The pretreatment operation then filters the resulting slurry to remove the sludge and MST or manganese oxide and strontium carbonate solids. The filtrate receives further treatment in the solvent extraction system. SRTC personnel coordinated tests using a SpinTek rotary microfilter at the vendor location in FY01. These tests demonstrated a significant improvement - 2.5 to 6 times increase - in performance relative to the conventional cross-flow filter units. Rotary microfilter testing used a filter disk with ...
A detailed assessment of the consumption of mercury, divided into use areas, was carried out. Disposal and emissions to the environment were also qualified. The assessment is mainly based on data from 1992 - 1993. The most important source of emission of mercury to air is solid waste incineration which is assessed in particular to be due to the supply of mercury in batteries (most likely mercury oxide batteries from photo equipment) and to dental fillings. The second most important source of mercury emission to air is coal-fired power plants which are estimated to account for 200-500 kg of mercury emission p.a. Other mercury emissions are mainly related to wastetreatment and disposal. The consumption of mercury is generally decreasing. During the period from 1982/83 - 1992-93, the total consumption of mercury in Denmark was about halved. This development is related to the fact that consumption with regard to several ...
To raise the efficiency of the redox method and decrease the amount of radioactive wastes, a possibility of improving the decontamination process for NPP heat exchanger tubes made of stainless steel is studied. In the home practice the redox method of equipment decontamination is carried out as a multi-cycle process. In each cycle the surface is treated first with a permanganate alkaline solution ther with an oxalic acid solution, with a condensate washing-at between the treatments. Using samples cut out of the steam generator pipelines of the first and third power units of the Novovoronezh NPP the effect of the oXalic acid concentration, as well as washout time and conditions on the decontamination factor are studied. On the basis of analysis of the obtained data a conclusion is drawn that using oxalic acid of low concentrations and increasing its concentrations from cycle to cycle maximum decontamination factor values can be obtained at a ...
A pretreatment flowsheet was tested for separating key radionuclide components from the sludge stored in one of the high level waste tanks (B-110) at the Hanford Site; this sludge resulted primarily from the bismuth phosphate process, which was one of the three major plutonium separation processes used at Handford. This test involved (1) washing with water, (2) caustic leaching, (3) acid dissolution, (4) separation of transuranic elements (TRUs) by extraction with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO), (5) separation of Sr by extraction with di-t-butylcyclohexano-18-crown-6, (6) separation of Cs from the acid-dissolved sludge solution by treatment with ammonium molybdophosphate (AMP), and (7) separation of Cs from the sludge wash and caustic leach solutions by ion exchange using a phenol-formaldehyde resin (CS-100). The results of the radionuclide separation steps indicated that the proposed flowsheet is a viable ...
This report is a compilation of worksheets from the waste management units of Savannah River Plant. Information is presented on the following: Solid Waste Management Units having received hazardous waste or hazardous constituents with a known release to the environment; Solid Waste Management Units having received hazardous waste or hazardous constituents with no known release to the environment; Solid Waste Management Units having received no hazardous waste or hazardous constituents; Waste Management Units having received source; and special nuclear, or byproduct material only.
Research highlights: #-># The building occupancy affecting the cooling load prediction is studied. #-># PENN model is adopted in this study for predicting the building cooling load. #-># Statistical approach is adopted to result a less prejudice prediction performance. #-># Results show that occupancy data can significantly improve the prediction. -- Abstract: Building cooling load prediction is one of the key factors in the success of energy-saving measures. Many computational models available in the industry today have been developed from either forward or inverse modeling approaches. However, most of these models require extensive computer resources and involve lengthy computation. This paper discusses the use of data-driven intelligent approaches, a probabilistic entropy-based neural (PENN) model to predict the cooling load of a building. Although it is common knowledge that the presence ...
as manufacturing plants and laboratories, including the Chemical Laboratory at the House of David in Benton Harbor, Michigan. Built in America: Historic BuildingBuildings Survey/...
The photovoltaic (PV) industry is rapidly beginning to recognize the market potential of the buildings sector. New PV-for-buildings products have recently become commercially available, and numerous products that are under development will be introduced within the next 5 years. To ensure that these new products will be adopted and used in common building practices, the PV industry should recognize and address important buildings industry issues. These issues include building codes and standards, after-market servicing, education, and warranties and insurance policies. Photovoltaic systems are also still very expensive. The simplest method for increasing their value for a building is to decrease the building's electrical loads through energy efficiency and conservation. Meeting these goals can only be accomplished through ...
Following a referendum in Italy in 1987, the four Nuclear Power Plants (NPPs) owned and operated by the state utility ENEL were closed. After closing the NPPs, ENEL selected a ''safestore'' decommissioning strategy; anticipating a safestore period of some 40-50 years. This approach was consistent with the funds collected during plant operation, and was reinforced by the lack of both a waste repository and a set of national free release limits for contaminated materials in Italy. During 1999, twin decisions were made to privatize ENEL and to transform the nuclear division into a separate subsidiary of the ENEL group. This group was renamed Sogin and during the following year, ownership of the company was transferred to the Italian Treasury. On formation, Sogin was asked by the Italian government to review the national decommissioning strategy. The objective of the review was to move from a safestore strategy to a prompt ...
This paper describes the use of numerical analysis for studying natural convection cooling systems for long term storage of heat producing radioactive materials, including special nuclear materials and nuclear waste. The paper explains the major design philosophy, and shares the experiences of numerical modeling. The strategy of storing radioactive material is to immobilize nuclear high-level waste by a vitrification process, convertion it into borosilicate glass, and cast the glass into stainless steel canisters. These canisters are seal welded, decontaminated, inspected, and temporarily stored in an underground vault until they can be sent to a geologic repository for permanent storage. These canisters generate heat by nuclear decay of radioactive isotopes. The function of the storage facility ventilation system is to ensure that the glass centerline temperature does not exceed the glass transition temperature during storage and the vault ...
The Savannah River Site (SRS) is a 310-square-mile United States Department of Energy nuclear facility located along the Savannah River (SRS) near Aiken, South Carolina. Nuclear weapons material production began in the early 1950s, utilizing five production reactors. In the early 1990s all SRS production reactor operations were terminated. The first reactor closure end state declaration was recently institutionalized in a Comprehensive Environmental Response and Compensation and Liability Act (CERCLA) Early Action Record of Decision. The decision for the final closure of the 318,000 square foot 105-P Reactor was determined to be in situ decommissioning (ISD). ISD is an acceptable and cost effective alternative to off-site disposal for the reactor building, which will allow for consolidation of remedial action wastes generated from other cleanup activities within the P Area. ISD is considered protective by the regulators, U. S. Environmental ...
Tanzania has recently developed a comprehensive environmental policy which has put high priority on several specific environmental issues. One of the issues is the quality of waste water. A special priority is given to the pollution from the sisal industry. The East-African agro-industries generate very large quantities of organic residues from production and processing of different crops. These residues form a major contribution to the pollution of air, soil and waterways, but, at the same time they constitute a large potential for production of bioenergy through anaerobic digestion as well as potential substrate for other biological fermentation processes. Generally, these residues are regarded as having no or very little value and the different disposal methods are mainly a matter of getting rid of the waste. The generation of residues are very often concentrated on few large units, which makes the exploitation of these resources feasible in ...
Power Fluidic systems for the control of liquids and gaseous flows have been adopted for use in radioactive processing plants in the UK. These devices are intrinsically reliable with no mechanical moving parts because they are able to make use of the hydrodynamics of the fluids being controlled. This reliability feature leads to a zero cell maintenance concept and the elimination of mechanical drive/control systems in cell. The first phase of the development work led to their use in the Fast Reactor Reprocessing Plant at Dounreay and the Highly Active Liquor Storage facility at Sellafield. The success of these early developments has led to an extensive development programme for an extended range of applications in the Thermal Oxide Reprocessing Plant and its associated wastetreatment facilities at Sellafield. The technology has now been fully demonstrated and adopted for these plants with considerable benefit over a wide range of applications.
An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements.
An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements
A series of modifications which increased the capacity of Canadian Electrolytic Zinc's Valleyfield plant from 220,000 MT/year to 260,000 MT/year during the last decade is discussed, combined with an an overview of the plant's operations. The modifications included modernisation of the waste disposal methods and facilities, such as a new high-density sludge wastewater treatment process, a new process to remove selenium from weak acid solutions and the jarofix process. Roasting capacity also has been improved by recent investments in new cooling coils, rebricking, oxygen enrichment and process automation. In addition to increases in refining capacity, the improvements also enabled the company to minimize its impact on the environment and the community.
This paper reports on current dual fuel engines utilizing standard mechanical (Bosch type) fuel injection systems set to 5--6 percent pilot delivery that do not appear capable of reducing NO{sub x} emissions much below the current minimum of 4 g/bhp-h without incurring substantial penalties in efficiency and operability. A prototype Electronic Pilot Fuel Injector (EPFI) was designed that overcomes the shortcomings of the mechanical injection system, consistently delivering 3 percent or less pilot at pressures as high as 20,000 psi. The EPFI was installed and tested in one cylinder of a standard production dual fuel engine operating at a waste water treatment facility.
Korea Atomic Energy Research Institute (KAERI) has many R and D facilities in operation, including HANARO research reactor, radioactive wastetreatment facility (RWTF), post-irradiation examination facility (PIEF) and irradiated material test facility (IMEF). Recently, nation-wide interest is focused on the safety and security of major industrial facilities. Safe operation of nuclear facilities is imperative because of the consequence of public disaster by radiological release/ contamination, in case of an accident. Recently, Ministry of Science and Technology (MOST) of the Korean government announced amendments of Atomic Energy laws to enforce requirements of the physical protection and radiological emergency. In this paper, the context of amended Atomic Energy laws were reviewed to confirm quality assurance measures and identify additional QA activities, if any, that is required by the amendment
Photodestruction has received much attention in recent years. In particular, titanium dioxide (TiO{sub 2}) and ozonolysis have attained a position of prominence. These technologies hold promise for the destruction of trace amounts of aqueous high explosives that are generated by load and pack operations, as well as demilitarization activities. Currently this water is treated by passing through a bed of activated carbon. The carbon is then steam regenerated and reused, thus creating a second waste stream which must be disposed of, or the carbon is burned directly. Recent trends in environmental regulation have shown that this may not be a viable option for process water remediation in the future. This talk will discuss efforts to employ alternate aqueous treatment techniques that not only remove the explosives compounds but are able to transform the parent compound into carbon dioxide and water. Titanium dioxide photocatalysis as well as ...
This report reviews coal conversion processes which may be introduced in Canada within the next decade if interest in alternate energy technologies continues. A detailed review was conducted on coal liquefaction and gasification projects worldwide including information on individual proprietors, process technologies used, their present status and available environmental data. Further assessment of emissions and wastes emanating from commercial-scale plants was used to determine significant or potentially significant wastestreams connected to the various technologies, particularly wastewater discharges. Emphasis was placed on those technologies that are close to commercialization in Canada, i.e. SASOL II-type liquefaction facility at Hat Creek. Available information on wastewater treatment/reuse is also included in this report.
Radioactively contaminated acidic aqueous wastes and organic liquids were discharged to the soil column at three disposal sites within the 200 West Area of the Hanford Site, Washington. As a result, a portion of the underlying groundwater is contaminated with carbon tetrachloride several orders of magnitude above the maximum contaminant level accepted for a drinking water supply. Treatability testing and cleanup actions have been initiated to remove the contamination from both the unsaturated soils to minimize further groundwater contamination and the groundwater itself. To expedite cleanup, innovative technologies for (1) drilling, (2) site characterization, (3) monitoring, (4) well field development, and (5) contaminant treatment are being demonstrated and subsequently used where possible to improve the rates and cost savings associated with the removal of carbon tetrachloride from the soils and groundwater.
Red mud is a by-product of bauxite processing through Bayer process. The amount of red mud generated depends largely on the type of ore used and the processing. Use of red mud as a catalyst can be a good alternative to the existing commercial catalysts. Its properties such as iron content in form of ferric oxide (Fe{sub 2}O{sub 3}), high surface area, sintering resistance, resistance to poisoning and low cost make it an attractive potential catalyst for many reactions. Besides red mud, ferric ion sludge from wastewater treatment plant has also been studied for its catalytic properties, mainly due to its ferric oxide constituent. This paper reviews the studies on red mud as a catalyst. The catalyst characteristics, reaction mechanisms involved and performance are examined and compared with iron oxide catalyst and commercial catalysts. (author)
Nuclear power plants of 20 units of in Korea are generating about 700 MTU of spent fuels annually. The inventory of spent fuels in Korea were estimated about 10,087.07 MTU at end of 2008, and the storage space of spent fuels won't be available any more at 2016 due to the saturation of the spent fuel pools in the plants. In addition, in order to reduce carbon emission and correspond to the enormous electricity demand in Korea, 8 units of nuclear power plants are under construction and several more plants are under planning. The 100,000 MTU of spent fuel inventory are expected by the year of 2095 in Korea. Therefore, short term and long term of spent fuel management plans are under discussion and implementation in Korea. As a short term of spent fuel management strategy for the target year of 2016, central or local spent fuel dry interim storage options are mostly under discussion. As a long term of management plan, fast reactor and advanced fuel cycle R and D plan were approved by 255th ...
Preliminary results are presented from a field study to evaluate the relative hydrologic performance of various landfill capping technologies installed by the Los Alamos National Laboratory at Hill Air Force Base, Utah. Four cover designs (two Los Alamos capillary barrier designs, one modified EPA RCRA design, and one conventional design) were installed in large lysimeters instrumented to monitor the fate of natural precipitation between 01 January 1990 and 20 September 1993. After 45 months of study, results showed that the cover designs containing barrier layers were effective in reducing deep percolation as compared to a simple soil cap design. The RCRA cover, incorporating a clay hydraulic barrier, was the most effective of all cover designs in controlling percolation but was not 100% effective. Over 90% of all percolation and barrier lateral flow occurred during the months of February through May of each year, primarily as a result of snow melt, early spring rains and low ...
In the first part of the symposium, experts reviewed the state of the art of decentralized waste water treatment in Europe. In the second part, exemplary solutions in Poland and the Czech Republic were presented. The final part was dedicated to future concepts and strategies. [German] Im Herbst letzten Jahres hat die Kommunale Umwelt-AktioN U.A.N. in einer Abfolge von drei Abwasserfachsymposien Expertenrunden zum Austausch ueber den aktuellen Stand des Wissens zum Thema dezentrale Abwasserbehandlung veranstaltet. Mit dem Internationalen Symposium 'Konzepte zur Abwasserbehandlung im laendlichen Raum Europas' in Celle hat das Projekt der U.A.N. seinen Abschluss gefunden. Der Konzeption des Projektes entsprechend haben im 1. Teil des Symposiums Experten ueber den Stand der Entwicklung auf dem Sektor der dezentralen Abwasserbehandlung in Deutschland berichtet. Im 2. Teil unserer Fachtagung wurden europaeische Beispiele fuer ...
A new filtration process using acrylic fiber has been developed which has wide applications in water works, sewage water treatment and waste water treatment facilities. Instead of sand, the common filter media in conventional systems, this new system uses long, fine acrylic fibers. Compared with a conventional system, the filtration speed and suspended solids (SS) retention of the new system have been increased 500% from 120--200 m/d to 400--1,200 m/d and from 2--3 kg/m{sup 2} to 5--20 kg/m{sup 2}, respectively. In addition, the backwash time has been decreased 60%, from 20--30 min to 10 min. As SS retention increase, the empty space between the fibers (fiber void) decreases and pressure drops due to the high filtration rate. Thus the pressure decreases rapidly after a certain period of filtration because of the increased SS retention cause fiber compression. This system is primarily based on solution clarification, but ...
Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (both radioactive and hazardous according to the Resource Conservation and Recovery Act) wastes. Depending on regulatory requirements, the mercury in the off-gas must be controlled with sometimes very high efficiencies. Compliance to the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Several test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include: (a) The depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests, (b) MERSORB(reg_sign) carbon can sorb Hg up to 19 wt% of ...
The paper deals with the disposal of radioactive waste and the plans for dealing with solid wastes of intermediate and low levels of activity, which are the responsibility of NIREX. NIREX is an executive body which co-ordinates the waste-disposal plans of the main radioactive waste producers. The disposal routes for the active wastes are described including the deep disposal of wastes containing material that will remain active for thousands of years. Requirements for deep burial are outlined with reference to the geology and hydrogeology of the site. Monitoring, maintenance and surveillance are mentioned for the protection of the public.
This work come along of the necessity to utilize an unique High-Energy Electron Linear Accelerator (10 MV) for radiant treatments which require higher doses in the surface levels of tissue. It is analyzed the interposition of acrylic degraders (spoilers) in the beam, especially for opposed and parallel fields in the cases of head and neck. It was analyzed the possible combinations of the following parameters: 1) Field sizes defined at isocenter (100 cm) 6 x 6 cm"2, 8 x 8 cm"2 and 10 x 10 cm"2 ; 2) Surface-spoiler distance (DSS) of 4, 7 and 10 cm; 3) Spoilers with different thickness 1.1 and 1.5 cm. It was observed a displacement of the maximum dose toward the surface, and an increase in the percentile doses in the build-up zone when the spoiler is nearing and/or increasing its thickness. It is verified that the use of spoilers, support the symmetry and plane of the beam inside of the clinically acceptable margins. When the results obtained are ...
Petroleum is the unchallenged energy market leader in West Germany,having a share of 42%; natural gas accounts for 16-17%. West Germany imports 29% of its natural gas from the Soviet Union, 28% from the Netherlands, 14% from Norway, and 1% from Denmark. In West Germany many-branched natural gas distribution system is operated, equipped with a.o. 21 installations for underground storage which results in a great flexibility of the system. Because of the preferential treatment given to the use of coal as fuel for power plants the share of natural gas has decreased to the present 6% in the last ten years. In the indutrial sector the share is 18%. Strict air pollution abatement measures ('TA-Luft') favour the use of natural gas. However, duty has been levied on the use of natural gas per January 1st, 1989. For space heating of houses and commercial buildings the share of natural gas is 27%. 7 figs., 9 ills.
In searching modulators of immunity and hematopoiesis among natural products, being used as foods, six herbs exhibited lymphocyte proliferation in vitro, and six exhibited augmentation of hematopoietic cell growth. The combined treatments showed synergistic effects of lymphocyte proliferation and of hematopoietic cell growth. On the other hand, we found four effective oriental medicinal prescriptions, used as energy tonic or blood-building decoctions, for survival and regeneration of hematopoietic cells and for protection of stem cells of intestinal crypt in irradiated mice. On the basis of these results, extracts from combinations of herbs were made in expectation of higher effects in the three respects. In immuno modulation activity by the two combinations of herbs was confirmed in mice. In culture of bone narrow cells, growth improvement of non-adherent precursor and induction of cytokine expression by herb mixture extracts were observed. In ...
Acrylonitrile electropolymerization (in an aprotic and anhydrous medium) has been used as a way to build thin, homogeneous and covering polyacrylonitrile layers grafted on the surface of usual metals and specially on copper-based shape memory alloy: Cu-Zn-Al. The results of the study first confirm the possibility of grafting thin and covering polyacrylonitrile layers on Cu-Zn-Al surface. The morphology of the films however is influenced by the geometry of the polycristalline structure of the alloy and its superficial defects. Samples obtained after grafting polyacrylonitrile films were submitted to corrosion tests based on Electrochemical Impedance Spectroscopy (EIS) measurements in a NaCl/H{sub 2}O medium. Results show that some post-treatments of the grafted films are necessary to improve their protective role, while preserving the strong interfacial bondings. Actually, thermal and mechanical cycling of the shape memory alloy covered by ...
The Outstanding Achievement Award in Water Pollution Control' is intended to recognize the water pollution control program that best demonstrates achieving significant, lasting, and measurable excellence in water-quality improvement in preventing water-quality degradation in a region, basin, or water body. This article is about the 1991 Award. This year, WPCF honored Los Angeles Hyperion Treatment Plant with a citation of outstanding achievement. To qualify for this honor, Hyperion has remarkably improved the quality of wastewater discharged to Santa Monica Bay since 1985. Capital programs developed by Los Angeles to achieve this rapid improvement, coined the Hyperion Improvement Program (HIP), reflect the city's commitment to protect the valuable resource of Santa Monica Bay. The HIP was conceived in 1986 to cease sludge ocean disposal by the end of 1987 and expedite effluent quality improvement before 1991, when the full secondary expansion is ...
This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes of Virginia that are potential biomass energy sources.
This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes and industrial wastes in Florida that are potential biomass energy sources.
This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes and industrial wastes of Alabama that are potential biomass energy sources.
Waste Technology and Innovation Study Final Report ...Waste Technology and Innovation Study Final Report 21/18569/150554 ...Survey of waste and resource recovery related technology and innovation, including products and product uses
This is the third of a series of research reports which builds on the previous contents which dealt with energy efficiency techniques and minimizing the environmental effects of building materials. It presents some specifications for house types and gives built examples of energy efficient homes in Europe. (UK)
A research report describes the energy efficiency techniques to be employed in designing a building which is ``green``. Topics covered include building fabric performance, ventilation and infiltration, passive solar design, heating systems and controls, hot and cold water provision, lighting and electrical appliances. (UK)
The development of comfort in buildings throughout the centuries was influenced by the demand for progress, wealth and innovation in various respects. At present, it seems that progress may only be possible by taking into account the environment and creating methods of reducing further damage to the environment. The innovative feature of future progress my be reducing the impact on the environment from human and building activities by using appropriate technology. As it is impossible to build without any impact on the environment and this is likely to be so in the future, the objective is and will be to find solutions for buildings which are more compatible with the environment. The objective is to demonstrate that it is viable to design buildings with minimized impact on the environment, while still maintaining appropriate comfort levels.
This report summarizes the major activities conducted in the Chemical and Energy Research Section of the Chemical Technology Division at Oak Ridge National Laboratory (ORNL) during the period October--December 1997. The section conducts basic and applied research and development in chemical engineering, applied chemistry, and bioprocessing, with an emphasis on energy-driven technologies and advanced chemical separations for nuclear and waste applications. The report describes the various tasks performed within six major areas of research: Hot Cell Operations, Process Chemistry and Thermodynamics, Separations and Materials Synthesis, Fluid Structure and Properties, Biotechnology Research, and Molecular Studies. The name of a technical contact is included with each task described, and readers are encouraged to contact these individuals if they need additional information. Activities conducted within the area of Hot Cell Operations included efforts to optimize the ...
The performance of PAN-based composite absorbers was evaluated in dynamic experiments at flow rates ranging from 25--100 bed volumes (BV) per hour. Composite absorbers with active components of ammonium molybdophosphate (AMP) PAN and K-Co ferrocyanide (KCoFC) PAN were used for separating Cs from a 1 M HNO{sub 3} + 1 M NaNO{sub 3} + 2 {times} 10{sup {minus}5} M CsCl acidic simulant solution. KCoFC-PAN and two other FC-based composite absorbers were tested for separating Cs from alkaline simulant solutions containing 0.01 M to 1 M NaOH and 1 M NaNO{sub 3} + x {times} 10{sup {minus}4} M CsCl. The efficiency of the Cs sorption on the AMP-PAN absorber from acidic simulant solutions was negatively influenced by the dissolution of the AMP active component. At flow rates of 50 BV/hr, the decontamination factor of about 10{sup 3} could be maintained for treatment of 380 BV of the feed. With the KCoFC-PAN absorber, the decontamination factor of about 10{sup 3} could be ...
The paper introduces the disposal procedures of the old reactor pressure vessel head. Reactor pressure vessel (RPV) heads were replaced successfully in Daya Bay Nuclear Power Plant. The on-site treatment and disposal of replaced heads was thereafter implemented. This is the first time in China for large size radioactive article disposal. To guarantee the safety of old head treatment, issues of radiation protection have to be taken into account. Dose rate distribution of the old head surface and radioactivity were initially calculated according to the operation history and the neutron flux rate of the reactor. Shielding calculation and package design was thereafter worked out based on the data obtained from the old head, e.g. neutron flux, sorts of nuclides, radioactivity and dose rates. Shielding package was afterwards manufactured in special factories and transported to Daya Bay NPP site by truck and ship. The shielding package was designed ...
This bibliography contains citations concerning the control and mitigation of radon pollution in homes and commercial buildings. Citations cover radon transport studies in buildings and soils, remedial action proposals on contaminated buildings, soil venting, building ventilation, sealants, filtration systems, water degassing, reduction of radon sources in building materials, and evaluation of existing radon mitigation programs including their cost effectiveness. Analysis and detection of radon and radon toxicity are covered in separate published bibliographies. (Contains 129 citations fully indexed and including a title list.).
The US Department of Energy Office of Building Technology, State and Community Programs sponsored EcoTecture Solutions, Inc. (dba Sustainable Living Alliance {trademark}) in producing two home tours showcasing energy- and resource-efficient buildings in Austin, Texas, held on October 16, 1999, and Albuquerque, New Mexico, held on May 20, 2000. Lists are given of the notable building technologies, passive solar design features, and energy- and water-efficient technologies and design employed in the houses. There were over 1200 visitors to the 22 residential and 3 commercial buildings included in the tour.
In the construction work for the Unit No.5 Turbine Building at Hamaoka Nuclear Power Station, the collaboration work for the planning and the coordination of the building construction and the machinery installation was carried out utilizing three-dimensional computer aided design (3D CAD) information. It was the first time in Japan for a building constructor and a plant manufacturer to work together, exchanging 3D CAD data of the whole building and adjusting the construction schedule. It was made possible to confirm the correspondence concerning the planning of both companies from the primary stage of the project by the total process simulation and to adjust on-going work precisely by the partial process simulation.
In the construction work for the Unit No.5 Turbine Building at Hamaoka Nuclear Power Station, the collaboration work for the planning and the coordination of the building construction and the machinery installation was carried out utilizing three-dimensional computer aided design (3D CAD) information. It was the first time in Japan for a building constructor and a plant manufacturer to work together, exchanging 3D CAD data of the whole building and adjusting the construction schedule. It was made possible to confirm the correspondence concerning the planning of both companies from the primary stage of the project by the total process simulation and to adjust on-going work precisely by the partial process simulation.
Purpose of this assessment for this town in the Slovak Republic is to develop information on the building sector energy efficiency and improvement potential for use by town management to support decisions on providing energy services to Handlova citizens. Objectives were to characterize baseline space and water heat energy use and efficiency improvement potential in the residential and nonresidential building sectors. Intention was to identify major areas of efficiency improvement potential and cost-effectiveness. Four levels of energy and fuel prices were used. A significant efficiency resource exists in the space and water heating end uses in these building sectors; it amounts to 42% of the total building sector space and water heat energy consumption.
An independent investigation of pipe welding leaks from the Low-Level Waste 2 (LLW2) Skid-B System for the possibilities of improper welding (IW), microbiologically influenced corrosion (MIC), sensitization, chloride pitting corrosion (CPC), and intergranular stress corrosion cracking (IGSCC) was conducted. The results show the prevailing mechanisms that caused the leaks are identified as IW, CPC, and the improper selection of weld filler material for the base metals in an environment of the North Plateau underground water. These is no evidence of MIC, sensitization, or IGSCC. The chloride pitting corrosion mechanism that took place at all the welds are also described. All the pipelines were replaced with polyvinyl chloride (PVC) for cost saving and the LLW2 Skid B System has been successfully operating since 1999. This report summarizes the findings and recommendations associated with preventive measures for future operations. The LLW2 Facility is a replacement ...
Changes in physical and chemical characteristics of aquatic habitats made to reduce or eliminate ecological risks can sometimes have unforeseen consequences. Environmental management activities on the U.S. Dept. of Energy reservation in Oak Ridge, Tennessee,have succeeded in improving water quality in streams impacted by discharges fi-om industrial facilities and waste disposal sites. The diversity and abundance of pollution-sensitive components of the benthic macroinvertebrate communities of three streams improved after new wastetreatment systems or remedial actions reduced inputs of various toxic chemicals. Two of the streams were known to be mercury-contaminated from historical spills and waste disposal practices. Waterborne mercury concentrations in the third were typical of uncontaminated systems. In each case, concentrations of mercury in fish, or the apparent biological availability of mercury ...
A preliminary investigation was conducted on ion specific membranes. This investigation concentrated on testing candidate organic compounds for transporting cesium ions through a membrane composed of the organic compound supported on a substrate. Solid PVC membranes were initially tried, but were found to be too slow. Thereafter, only liquid membranes were tested. These were faster and cesium concentration factors up to 2.96 were achieved in a single membrane cell. A cell with two membranes achieved a cesium concentration factor of 4.19. Cesium precipitation with sodium tetraphenyl borate in high sodium concentrations was explored. No interference from sodium was found until the sodium nitrite concentration reached 4.5 moles. Concurrently, cesium concentrations as high as 5.4 g/L were precipitated. Potassium tetraphenyl borate is being investigated for use in exchange columns for the removal of cesium from solutions. Initial investigations show that cesium removal is affected by (K/sup ...
A preliminary investigation was conducted on ion specific membranes. This investigation concentrated on testing candidate organic compounds for transporting cesium ions through a membrane composed of the organic compound supported on a substrate. Solid PVC membranes were initially tried, but were found to be too slow. Thereafter, only liquid membranes were tested. These were faster and cesium concentration factors up to 2.96 were achieved in a single membrane cell. A cell with two membranes achieved a cesium concentration factor of 4.19. Cesium precipitation with sodium tetraphenyl borate in high sodium concentrations was explored. No interference from sodium was found until the sodium nitrite concentration reached 4.5 moles. Concurrently, cesium concentrations as high as 5.4 g/L were precipitated. Potassium tetraphenyl borate is being investigated for use in exchange columns for the removal of cesium from solutions. Initial investigations show that cesium removal is affected by [K"+] ...
In this study based on the mass transfer theory, experiments for the evaporation rates depending on various conditions were carried out through the operation of the existing Natural Evaporation Facility in KAERI. Evaporation media were made of the cotton and polyester. Air circulation in the facility was forced by exhausting fans. The evaporation rate and the decontamination factor were calculated by the result of experiment. The evaporation rate increased as the flow rate of air supply, the feed rate of liquid waste, and the temperature of supplied air increased. As for the humility of supplied air, the evaporation rate was getting higher as the humidity was getting lower. As the result of this study, operation conditions of the Natural Evaporation Facility are optimized as follows; The air temperature above 8C .deg., the air humidity below 70%, the air flow rate 1.14-1.47 m/sec, and the liquid waste feed rate 4.6l/hr.m{sup 2}. The ...
This revision of the APT Waste Management Plan details the waste management requirements and issues specific to the APT plant for design considerations, construction, and operation. The APT Waste Management Plan is by its nature a living document and will be reviewed at least annually and revised as required.
The scope of our problems with nuclear waste management is outlined. Present and future inventories of nuclear wastes are assessed for risk. A discussion of what is presently being done to solve waste management problems and what might be done in the future are presented. (DC)
Electronic waste or e-waste is one of the rapidly growing problems of the world. E-waste comprises of a multitude of components, some containing toxic substances that can have an adverse impact on human...Full Text Available
The purpose of the Hanford Waste Management Plan (HWMP) is to provide an integrated plan for the safe storage, interim management, and disposal of existing waste sites and current and future waste streams at the Hanford Site. The emphasis of this plan is, however, on the disposal of Hanford Site waste. The plans presented in the HWMP are consistent with the preferred alternative which is based on consideration of comments received from the public and agencies on the draft Hanford Defense Waste Environmental Impact Statement (HDW-EIS). Low-level waste was not included in the draft HDW-EIS whereas it is included in this plan. The preferred alternative includes disposal of double-shell tank waste, retrievably stored and newly generated TRU waste, one pre-1970 TRU solid waste site near the Columbia River ...
From out of the numerous technical alternatives the manual develops a waste management concept with emphasis on methods which can be coordinated for maximum ecological use and minimum economic costs. A clear-cut analysis of the present state of waste utilization and waste disposal in the Federal Republic of Germany (chapter 1) is followed by a detailed description of conventional and modern state-of-the-art waste utilization methods based on ecological evaluation criteria (chapter 3). An optimum waste utilization concept for defined quantities of wastes is derived from the ecological and economic comparison of waste utilization techniques given in chapter 3. Chapter 4 points out different variants of waste utilization and waste disposal methods and shows how to determine the optimum variant of the ...
A Lawrence Livermore National Laboratory (LLNL) Management Pre-Start Review (MPR) Team was formed to independently verify the operational readiness of Building 368 (B368) Biosafety Level III (BSL-3) Facility to conduct research with biological pathogens and toxins including those considered Select Agents. Review objectives and criteria were developed from the DOE/NNSA and LLNL requirements. These were provided in the Implementation Plan for the Biosafety Level III (BSL-3) Facility Management Pre-Start Review (BSL-3 MPR) at Lawrence Livermore National Laboratory that was reviewed and approved by DOE/NNSA-LSO. The formal part of the LLNL MPR for the BSL-3 Facility was begun in August of 2005 but work on the MPR was stopped in October of 2005 due to the need for LLNL to reassess organizational and operational controls and respond to Centers for Disease Control and Prevention inquiries related to a shipping incident involving select agents. The MPR was restarted in ...
Drastic changes in waste management procedures are expected from the German Municipal Waste Disposal Regulations which became effective on June 1, 1993. Waste disposal will be subject to certain restrictions which, e.g. demand that wastes must be pretreated and inerted before they are stored. These regulations favor thermal waste disposal methods such as the carbonization/combustion method which is planned for a commercial-scale plant in the city of Fuerth. (orig./BBR)
Sep 2, 2008 ... Abstract: This tutorial is intended to serve as a guide towards proper hazardous waste management. Knowing the regulations, different ...
China operates 10 nuclear power reactors and has 5 more under construction. A large extension of nuclear power is expected by 2020. Nuclear generated electricity accounts for 2% of the total electric power generation. The Chinese policy is to have spent fuel reprocessed in China. So, final disposal include vitrified waste and some CANDU spent fuel for direct disposal. There is a legal framework in place in China to manage HLW. The China Atomic Energy Authority (CAEA) has the responsibility for setting policy on HLW disposal and implementing the disposal programme, while the National Nuclear Safety Administration (NNSA) and the State Environment Protection Agency (SEPA) are the regulatory bodies, which are responsible for licensing and reviewing of environment impact assessment report. The China National Nuclear Corporation (CNNC) is considered to be the actual implementer, conducting the major activities for HLW management. In the 1980's, China started generic ...
This request is submitted to seek interim approval to operate a Toxic Substances Control Act (TSCA) of 1976 chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) waste. Operation of a chemical waste landfill for disposal of PCB waste ...
This Radioactive and Mixed Waste Management Plan for the Hazardous Waste Handling Facility at Lawrence Berkeley Laboratory is written to meet the requirements for an annual report of radioactive and mixed waste management activities outlined in DOE Order 5820.2A. Radioactive and mixed waste management activities during FY 1994 listed here include principal regulatory and environmental issues and the degree to which planned activities were accomplished.
Considering the fact that more than 40% of all household wastes are organic wastes composting could be an excellent relief and complement to other waste disposal methods (e.g. combustion or direct landfills). Provided the right conditions household wastes could be composted together with sewage sludges and manures. The paper discusses the legal aspects, quantitative evaluations, conveying systems, as well as the compost utilization and marketing aspects valid for the Federal Republic of Germany.
Implementation of a plan to charge waste management costs to the facility that generates such waste requires a long-term commitment and consistent administration. The benefit is that generators are provided the incentive to optimize waste management practices if the charges are appropriately applied. This paper summarizes (1) a plan to charge waste generators, (2) the administrative structure of the plan, (3) a comparison between the rate structure and changes in waste disposal operations, and (4) issues that have surfaced as the plan is implemented. 2 refs., 1 fig., 1 tab.
Following the executive summary, this document contains the following: (1) waste management facilities design objectives; (2) AVLIS production plant wastes; (3) waste management design criteria; (4) waste management plan description; and (5) waste management plan implementation. 17 figures, 18 tables.
This official IEA report is a deliverable of IEA SHC Task 21/IEA BCS Annex 29: Daylight in Buildings. The Task focuses on daylighting systems and strategies which can be applied in new and existing buildings with a high potential electricity saving potential such as offices, schools, commercial, and institutional buildings. The daylighting performance of these strategies and systems is tested in laboratory facilities, through modeling, and in real case study buildings. This paper provides methods and procedures to evaluate the daylighting performance of real buildings. Annex 29 case studies located in Europe, North America, and Australia. It is a deliverable of Subtask D research projects. The main objective of Subtask D, as stated in the Implementing Agreement of Task 21/Annex 29, is `to demonstrate the viability of daylighting buildings in various world ...
The high-purity-oxygen activated sludge process will be used to expand secondary treatment capacity and improve water quality in Santa Monica Bay. The facility is operated by the city of Los Angeles Department of Public Works` Bureau of Sanitation. The overall Hyperion Full Secondary Project is 30% complete, including a new headworks, a new primary clarifier battery, an electrical switch yard, and additional support facilities. The upgrading of secondary facilities is 50% complete, and construction of the digester facilities, the waste-activated sludge thickening facility, and the second phase of the three-phase modification to existing primary clarifier batteries has just begun. The expansion program will provide a maximum monthly design capacity of 19,723 L/s(450 mgd). Hyperion`s expansion program uses industrial treatment techniques rarely attempted in a municipal facility, particularly on such a large scale, including: ...
The biodegradation of one of the most commonly used commercially available dispersants in the treatment of hydrocarbon out-flow was studied. The culture mediums employed were sea water, sterile sea water, and medium M19 (Merck). The latter two were inoculated with two kinds of microorganisms of the Pseudomona genus isolated from sludge from a wastetreatment plant. The dispersants used is a commercial product made of anionic sulphated dispersants (1.710% by weight); anionic sulphonated dispersants (0.144%) and non-ionic dispersants (8.146%), both accompained by hidrocarbonated solvent (90%). The degradation processes occurred at differents temperatures (20, 30 and 37). The greatest degradation was obtained at 30 degree centigree. The degradation percentages obtained with the miscroorganisms were 40% of the anionic total and 70% of the non-ionic total after 56 hours for the 5:2 strain and 40% of the anionic total and 9.3% of ...
At the 7th Healthy Buildings Conference, which was held in Singapore, 7-11 December 2003, more than 500 articles to improve public health and productivity of workers in buildings and the performance of installations. Special attention is paid to indoor air quality and thermal comfort in relation to energy efficiency. [Dutch] Op de laatste Healthy Buildings conferentie, december 2003 in Singapore, werden meer dan 500 artikelen gepresenteerd over het creeren van gezonde, productiviteit verhogende gebouwen en installaties. Deze keer lag de nadruk op binnenluchtkwaliteit en thermisch binnenklimaat, onder andere op het aspect energiezuinigheid. Opvallend was ook de aandacht die de problemen met binnenluchtkwaliteit in ontwikkelingslanden kreeg.
A number of buildings dating from the 1950s and 1960s were retrofitted with thermal insulation in order to cut energy consumption. This took place within the building competition 'Therma' nitrated by the Federal Ministry of Regional Planning, Building and Town Planning in 1974. Result at that time were so encouraging that now, 15 years later the results were checked again with special attention to the long-term performance of the thermal insulation measures. Laboratory tests prove that the building materials are still in good condition and that humidity has not increased with age. Cracks in the surface plaster of the compound insulation systems occurred at different frequencies and intensities and usually caused by thermal tensions. (BWI).
In accordance with federal legislation, the U.S. Department of Energy (DOE) has conducted a project to demonstrate use of its Energy Conservation Voluntary Performance Standards for Commercial and Multi-Family High-Rise Residential Buildings; Mandatory for New Federal Buildings; Interim Rule (referred to in this report as DOE-1993). A key requisite of the legislation requires DOE to develop commercial building energy standards that are cost effective. During the demonstration project, DOE specifically addressed this issue by assessing the impacts of the standards on (1) construction costs, (2) builders (and especially small builders) of multi-family, high-rise buildings, and (3) the ability of low-to moderate-income persons to purchase or rent units in such buildings. This document reports on this project.
A survey was conducted to determine the sources of buildings energy conservation case studies and educational aids available in Canada. In total 785 consultants, educational institutions, building developers, manufacturers and government agencies were contacted. The results of this survey provide an indication of those agencies in Canada most actively involved with energy conservation in buildings, a listing of those agencies in Canada having case study information and/or educational aids materials available related to energy conservation in buildings, and a broad description of the subject area of the case studies and educational aids listed. The results of this study are intended to provide a source listing of energy conservation case studies and educational aids to the Buildings Energy Technology Transfer Program lead agencies and others conducting similar studies in the ...
This work concerns the development of nuclear energy and nuclear waste management in particular. Two parts of this study can be distinguished. In the first part (theoretical), a thorium-plutonium fuel based on MOX and dedicated for PWR was investigated in order to transmute plutonium in a potentially low waste fuel cycle. It was shown that this type of fuel is not regenerative but could be used for a transition to the industrial thorium fuel cycle without building new reactors. Thanks to moderated neutron spectra and high loaded actinide mass in the core, U-233 is quickly created ({approx}300 kg/y) for a loss of about {approx}1200 kg of fissile plutonium. In the second part (experimental), we have developed and built a new reaction chamber to measure neutron cross sections of actinides by alpha-gamma spectroscopy. This experimental device (in principle transportable) was commissioned in the high flux reactor of ILL ...
The Hanford Waste Vitrification Plant Project has been established to convert the high-level radioactive waste associated with nuclear defense production at the Hanford Site into a waste form suitable for disposal in a deep geologic repository. The Hanford Waste Vitrification Plant will mix processed radioactive waste with borosilicate material, then heat the mixture to its melting point (vitrification) to forin a glass-like substance that traps the radionuclides in the glass matrix upon cooling. The Hanford Waste Vitrification Plant Quality Assurance Program has been established to support the mission of the Hanford Waste Vitrification Plant. This Quality Assurance Program Description has been written to document the Hanford Waste Vitrification Plant Quality Assurance Program.
An average of 9 million gallons per day of oil-contaminated ballast water off loaded from tankers are treated at the Alyeska Pipeline Service Company Ballast Water Treatment Facility at the terminus of the Trans-Alaska Pipeline in Port Valdez, Alaska. This paper focuses on the results of 2 Prince William Sound Regional Citizens' Advisory Council monitoring programs which detail changes in the chemical composition of treated ballast water as it moves from tankers through the facility and subsequently traces the effluent hydrocarbons into the receiving environment of Port Valdez. The treatment facility involves gravity separation tanks, dissolved air flotation cells and biological treatment tanks. Effluent containing traces of volatile aromatics, including benzene, toluene, ethylbenzene and xylenes, low levels of oil, saturated hydrocarbons and polycyclic aromatic hydrocarbons is being continuously discharged to Port ...
The turbulent history of legislature concerned with the waste-management industry and the amount of material on this subject as well as the significance of the material in its own right led to the decision to publish all legal regulations on waste in one volume. It includes above all the Waste Law, Regulations on Determination of Waste, Regulations on Determination of Residual Products, Technical Instructions for Waste, Regulations for Monitoring Waste and Residual Products, Regulations on Probition from the Use of Chlorofluorohydrocarbons and Halon, Regulations on Packaging and Regulations on Sewage Sludge. The introduction explains the development and the role of the Waste Law and its applicability, goals and principles: The concept of waste, avoidance of waste, avoidance of ...
Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental ...
In response to US Department of Energy directives, Argonne National Laboratory (ANL) has developed a waste minimization plan aimed at reducing the amount of wastes at this national research and development laboratory. Activities at ANL are primarily research- oriented and as such affect the amount and type of source reduction that can be achieved at this facility. The objective of ANL's waste minimization program is to cost-effectively reduce all types of wastes, including hazardous, mixed, radioactive, and nonhazardous wastes. The ANL Waste Minimization Plan uses a waste minimization audit as a systematic procedure to determine opportunities to reduce or eliminate waste. To facilitate these audits, a computerized bar-coding procedure is being implemented at ANL to track hazardous wastes ...
The potential hazard of landfill wastes was previously evaluated by examining the extraction procedures for individual waste, although various wastes were co-disposed of in actual landfills. This paper investigates the reduction of extraction-procedure toxicity by co-disposing various combinations of two wastes. When two wastes are mixed homogeneously, the extraction of heavy metals from the waste mixture is critically affected by the extract pH. Thus, co-disposal wastes will have a resultant pH between the pH values of its constituent. The lower the resultant pH, the lower the concentrations of heavy metals in the extract. When these wastes are extracted sequentially, the latter extracted waste has a stronger influence on the final concentration of heavy metals in the extract. Small-scale lysimeter ...
Results of a survey conducted by Concawe on 75 oil refineries in Europe show that the total quantity of waste requiring disposal in 1986 was 0.5 million metric tons. This quantity of waste is but 0.13% of the total refinery throughput of 387 million metric tons during 1986. The survey revealed a wide range of disposal costs, depending on the particular properties of the waste and local conditions. A summary of total waste generation and how the waste is disposed of is shown. Details on the types of waste disposed, the disposal methods used, and the costs of disposal are detailed in this excerpt from the Concawe survey.
The primary purpose of the Waste Management Program Plan is to provide an annual report of how Waste Management's operations are conducted, what facilities are being used to manage wastes, what forces are acting to change current waste management systems, and what plans are in store for the coming fiscal year. In addition, this document projects activities for several years beyond the coming fiscal year in order to adequately plan for safe handling, storage, and disposal of radioactive wastes generated at the Savannah River Site and for developing technology for improved management of wastes. In this document, work descriptions and milestone schedules are current as of December 1991.
This Waste Management Plan functions as a management and planning tool for managing waste streams generated as a result of operations at the Idaho CERCLA Disposal Facility (ICDF) Complex. The waste management activities described in this plan support the selected remedy presented in the Waste Area Group 3, Operable Unit 3-13 Final Record of Decision for the operation of the Idaho CERCLA Disposal Facility Complex. This plan identifies the types of waste that are anticipated during operations at the Idaho CERCLA Disposal Facility Complex. In addition, this plan presents management strategies and disposition for these anticipated waste streams.
This document presents a detailed schedule for the implementation of the strategy for managing defense remote-handled (RH) transuranic (TRU) waste. The baseline management strategy was defined in the Defense Remote-Handled Transuranic Waste Cost/Schedule Optimization Study and is summarized in this document. Also included are revised RH TRU waste inventory projections, current site management plans, a list of key decision points and milestones, and a discussion of uncertainties associated with management of RH TRU waste. The plans are summarized in a detailed schedule diagram and in an RH TRU waste work off diagram. 9 refs., 5 figs., 4 tabs.
Researches and production of radio-isotopes, radio-pharmaceuticals and cold kits are carried out in the Radio-isotope Production Facility (RIPF). Four concrete hot cells in Bank-1 are to produce the Ir-192 source for NDT. Eleven lead hot cells in Bank-2 are to produce Ho-166, Cr-51, P-32/33, Tc-99m, Lu-177, Sr-90/Y-90 and W-188/Re-188 for research purpose. Six lead hot cells in Bank-3 are used for the production of I-131 for diagnosis and therapy of cancer in the hospital. A hot cell in Bank-3 is also utilized for the research of I-125 and Br-82. Four lead hot cells in Bank-4 are utilized for the production of Mo-99/Tc-99m generators since 2005. The major systems including the Heat and Ventilated Air Conditioning (HVAC) system and the air cleaning system such as charcoal and HEPA filter trains to filter the radioactive contaminants are in operation. So are the systems such as power supply and distribution system, UPS, fire protection system, liquid radioactive ...
The Monsanto Chemical Company operates a plastics and resins plant located in Addyston, Ohio. The process equipment requires routine rinsing with technical grade acetone between batches. Due to the volumes of spent acetone generated and the associated RCRA hazardous waste regulations, the plant sought to recycle and reuse the acetone to reduce the purchase cost of virgin acetone and the cost of spent acetone disposal. One of the first options explored was package unit distillation units. The cost of these units was in the $20--$30,000 range in 1989 dollars. Even though the cost of a package unit was not deemed unreasonable, there were additional costs and concerns that led to elimination of this option. The unit would have required additional manpower to operate and maintain, i.e., at least a fraction of an operator and mechanic. For plant safety reasons, it was desired to operate this package unit outside the production building, thus ...
Roller compacted concretes (RCC) were developed for the Norwegian Skjerka hydropower project. RCCs were developed to have a high-volume fly ash content to address environmental issues, including the reduction of carbon dioxide emissions associated with dam construction. They also makes good use of waste product and conserve natural resources. This study examined a series of mixtures to determine the appropriateness of using RCC as a competing alternative to the traditional rock fill dam proposed for the Skjerka hydropower project. The main advantage of RCC is speed, allowing a relatively large dam to be constructed in just one summer season, saving financial costs and providing early return on the investment. In addition, fly ash can be used in the structure, using clean and renewable energy. Several procedures to proportion RCC mixtures were proposed, including the optimal paste volume method which is based on the assumption that an optimal RCC should have just ...
Petropavlovsk-Kamchatky (P-K) city in Kamchatka, Russia is operating hot-water district heating using heavy oil boilers and waste hot water of thermal power plants as heat sources. Feasibility study was made on district heating using natural geothermal hot water and/or geothermal heat pump systems as heat sources of hot water supply for reduction of greenhouse effect gas emission. Among 3 areas including geothermal hot water, use of hot water in K area was impossible because of lower temperature and less spring water. Use of hot water in P and UP areas was impossible as primary hot water because of temperature drop to 64 degrees C during hot water supply toward P-K city. The building heating operation test was carried out using the geothermal heat pump system installed in a newly drilled heat exchange well of 100m deep. As a result, sufficient heat recovery was achieved for heating. If all of 49 boiler houses for heating are replaced with such ...
Only within the past decade has the potential of metal biosorption by biomass materials been well established. For economic reasons, of particular interest are abundant biomass types generated as a waste byproduct of large-scale industrial fermentations or certain metal-binding algae found in large quantities in the sea. These biomass types serve as a basis for newly developed metal biosorption processes foreseen particularly as a very competitive means for the detoxification of metal-bearing industrial effluents. The assessment of the metal-building capacity of some new biosorbents is discussed. Lead and cadmium, for instance, have been effectively removed from very dilute solutions by the dried biomass of some ubiquitous species of brown marine algae such as Ascophyllum and Sargassum, which accumulate more than 30% of biomass dry weight in the metal. Mycelia of the industrial steroid-transforming fungi Rhizopus and Absidia are excellent ...
The dwelling is equipped with solar collectors which heat the air circulating in the cavity walls and the space beneath the floors. The thermal aspects of such a building are described. Heat balance, losses, heating by the sun in different seasons are described. Different measures taken to reduce the energy losses are described.
The following subjects are dealt with: physics of indoor air flow, flow in individual rooms, exchange of air and pollution between individual building zones and with the outside world, thermal coupling with the building shell, thermal comfort and air quality, evaluation of the ventilation. figs., tabs., refs.
Based on a generalized theory of perturbations and on non-linear programming an approach to the quantitative determination of necessary accuracies for nuclear data is described. It is used to calculate transactinide isotope build-up in reactors.
First, attention is paid to the development and use of new construction techniques, including the use of new building materials, e.g. synthetic materials and the so-called steel frame method. Next, the reduction of the energy consumption during the service life of a house is discussed. The reduction can be realized by means of passive methods, e.g. improved windows, thermal insulation and design, or by means of active methods, e.g. electric load monitoring. The information in this article mainly concerns the housing construction in the USA and Canada. The purpose of this article to contribute to the discussion in the Netherlands on innovation in the building technology, e.g. formulated in the report `Bouwvisie 2010` (Vision on Buildings for the year 2010) of the Dutch Advisory Board Technology Policy for the Building Industry (ARTB, abbreviated in Dutch) and the building technology ...
situ by isolating portions of the building envelope and performing tests .MAXIMUM ALLOWED LOAD ...and shall identify commissioning team members who will perform testing and prepare documentation.The commissioning agent may be
The follow-up system for wastes (JAeSTI), developed at the end of the 1990s, forms a basis for today's followup activities in Finland. JAeSTI relies on an environmental protection database, the compliance monitoring system VAHTI operated by the environmental authorities. Waste followup and waste statistics depend very much on the annual waste quantities recorded in the VAHTI system. In the KYJ-project the coverage and reliability of the data in the VAHTI system was evaluated as for the streams of solid municipal waste. The project also included the compiling of national statistics on municipal waste for the year 2000. The project used other information sources, too, such as statistics compiled when the National Waste Plan and regional waste plans were revised in 2002. In addition, the extent and quantity of ...
An intemted approach to building a networking infrastructure is an absolute necessiry for meeting the multidisciplinary science networking requirements of ...
The risk analysis was carried out in consideration of conditions prevailing at the Kalkar site analogous to the investigations in phase A of DRS (German Reactor Study). Earthquake design loads include the probabilities of upper deviations of the site intensities to be expected. The calculations of dynamic loads for select buildings are made using models and computational methods. Component analyses were performed analogous to DRS for the supports of large components, supports of the roof construction of the reactor building taking into account support reserves due to plastic work capacity, wall disks in steam generator buildings and switchboard plant buildings. (DG).
The operation of buildings can be temporarily modified to use much less electricity. These actions may be necessary during regional electricity shortages lasting anywhere from days to months. The electricity conservation measures typically involve a combination of technical modifications, temporary changes in occupant behavior, and greatly increased vigilance. At the same time, attempts to drastically reduce a building's electricity use may have unexpected consequences affecting energy use, the indoor environment, and the performance of building materials and equipment. Electricity shortfalls such as those described in this paper may occur more often as a result of climate change and liberalized electricity markets. (author)
Ontologies ? a form of structured and logically related knowledge or classification hierarchy embedded in a computer system ? are regarded by many scientists as having enormous promise for the consistent use and re-use of data. To realise this promise, however, is not straightforward. In this paper, based on ethnographic observation, we argue that the challenges for ontology building are ?social? as much as they are technical. By this we mean the routine work undertaken in the building process and the problems and difficulties entailed can be understood in terms of the practices of knowledge workers and the practical nature of ?sorting things out?. Getting a better sense of how, in practise, this work gets done gives a sense of the main challenges of building successful ontologies and how ...
Many non-domestic buildings, built recently in the UK, use natural means to provide ventilation for indoor air quality and thermal comfort. This paper presents monitoring results obtained from such a purpose built naturally ventilated educational building. Its performance during the summer is discussed based on monitored results. Using thermal and ventilation modelling, the paper also discusses the optimisation of the building's summer performance. Recommendations on the selection of appropriate ventilation strategies in relation to the prevailing external conditions are derived and the appropriateness of the control methods is discussed. (author)
There is increasing pressure to operate laboratory facilities in environmentally and financially sustainable ways. A key factor in achieving this goal is careful consideration of how energy is used by the buildings' ventilation system, both for conditioning air supplied to the laboratories and the energy used moving air through the building. Traditionally, laboratory energy use is treated as an engineering concern within the scope of the building's overall design and operation. However, this approach limits the involvement of key stakeholders in many important decisions and can lead to unexpected safety concerns for the laboratory's users. We believe that a broad view of the parties affected by a laboratory building's operations is necessary to avoid having the various stakeholders working...
The objective of this report is to review the different technologies for trapping the gaseous wastes containing Cs, Ru, Tc, {sup 14}C, Kr, Xe, I and {sup 3}H from a voloxidation process. Based on literature reviews and KAERI's experimental results on the gaseous fission products trapping, appropriate trapping method for each fission product has been selected considering process reliability, simplicity, decontamination factor, availability, and disposal. Specifically, the most promising trapping method for each fission product has been proposed for the development of the INL off-gas trapping system. A fly ash filter is proposed as a trapping media for a cesium trapping unit. In addition, a calcium filter is proposed as a trapping media for ruthenium, technetium, and {sup 14}C trapping unit. In case of I trapping unit, AgX is proposed. For Kr and Xe, adsorption on solid is proposed. SDBC (Styrene Divinyl Benzene Copolymer) is also proposed as a conversion ...
This study presents three-dimensional simulation results of multispecies and multi-reaction electrorefining for spent nuclear wastetreatment. Fluid-dynamic behavior of electrorefining is analyzed by commercial computational fluid-dynamics code. The results of local fluid dynamics are coupled with one-dimensional electrochemical reaction analysis code in order to predict local current density distribution. The new approach shows current distribution patterns over the cathode surface in LiCl-KCl molten-salt electrolyte. The current density distribution patterns are analyzed for various electrode rotational speeds and diverse applied currents and the results show a good agreement with general principle of mass transfer observations. Spatially periodic and vertically striped pattern of current density is predicted at the cathode side due to mass transfer depression at separation points. These slow mass transfer regions are vulnerable to be ...
Myostatin is a member of the transforming growth factor-{beta} (TGF-{beta}) family and a strong negative regulator of muscle growth. Here, we present the crystal structure of myostatin in complex with the antagonist follistatin 288 (Fst288). We find that the prehelix region of myostatin very closely resembles that of TGF-{beta} class members and that this region alone can be swapped into activin A to confer signalling through the non-canonical type I receptor Alk5. Furthermore, the N-terminal domain of Fst288 undergoes conformational rearrangements to bind myostatin and likely acts as a site of specificity for the antagonist. In addition, a unique continuous electropositive surface is created when myostatin binds Fst288, which significantly increases the affinity for heparin. This translates into stronger interactions with the cell surface and enhanced myostatin degradation in the presence of either Fst288 or Fst315. Overall, we have identified several characteristics unique to ...
Investigations were made on the biodegradability and bacterial toxicity of chemicals. The intention was to obtain data necessary for estimating and judging the behaviour of these chemicals during aerobic biological waste water treatment. The course of biodegradation and toxicity with time and concentration could be measured, quantified and described. As test procedure, the respirometric dilution method was used. This method is based on a die away test with continuous measuring of the oxygen used for biochemical oxidation processes. The course of the oxygen demand with time and concentration shows the biodegradation and toxicity patterns of the tested chemical. A variety of household and industrial chemicals were investigated. One group of substances were microbiocides, some of which showed toxic effects at concentrations less than 20 mg/l while others were biodegradable even at concentrations of 200 mg/l. Another group of test chemicals were ...
Phosphorus sorption capacities of several different materials including Merribrook soil (a loamy sand) and some industrial solid wastes (red mud neutralized with gypsum, fly ash, bottom ash and black oxide) were determined in sorption isotherms by Langmuir and Freundlich equations. The materials were characterized by bulk density, particle density, total porosity and particle size distributions. Red mud gypsum possessed the best sorption capacity based on the Langmuir maxima. Alkaline fly ash and Merribrook soil had lower sorption maxima compared to the red mud gypsum. Bottom ash and acidic fly ash had very low sorption capacity at low concentrations. Merribrook soil had the highest hydraulic conductivity. The results suggested that alkaline fly ash may be a promising amendment for coarse sand bed to enhance phosphorus removal. Merribrook soil appears to be suitable for on-site wastewater treatment.
The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental ...
The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental ...
Decommissioning of radiological and nuclear installations is for this century the new challenge. One of the performance criteria is the reduction of total quantities of radioactive materials (liquid or solid) arising from dismantling and decontamination of radiological and nuclear installations. In this work we present a new application of the water soluble polymers used as: - flocculation agents in treatment and conditioning process within the management of radioactive liquid materials; - strippable coatings on solid materials based on the water soluble polymers. The parameters of water soluble polymers made in our Institute by radiation processing have been analysed, namely the molecular average weight, composition, and efficiency of utilization of these polymeric materials as well as the content of ash, additives, decontamination factor, consumption per surfaces/liter, corrosion aspects, compatibility with various surfaces (of metal, concrete, plastics, etc). ...
The Water Frame work Directive (December 2000) proposes integrated water management in regard to both quality and quality. A mathematical model has therefore been produced at the CEIT and EPTISA research centre, in collaboration with the Ebro Hydrographic. Confederation (CHE), to predict water quality and thus begin integrated management of it in the river basins. A description is given of the characteristics of the simulation tool. The hydraulic model is based on the numerical (weighted, four-point implicit) resolution of the complete Saint Venant equations. The quality model is based on the IWA River Water Quality Model Number 1 which has clear advantages (consistency, mass balance and easy integration with the biological models of the waste water treatment plants and the collector networks compared to traditional models. The experimental validation, which includes calibration in wintertime of the hydraulic and quality models most ...
This paper reported on a study in which hydrogen was produced by fermentation of biomass. A continuous process using a non-sterile substrate with a readily available mixed microflora was used on heat treated digested sewage sludge from a wastewater treatment plant. Hydrogen was produced from waste sugar at a pH of 5.2 and a temperature of 37 degrees C. An experimental setup of three 5.5 L working volume continuously stirred tank reactors (CSTR) in different stirring speeds were constructed and operated at 7 different hydraulic retention times (HRTs) and different organic loading rates (OLR). Dissolved organic carbon was examined. The results showed that the stirring speed of 135 rpm had a beneficial effect on hydrogen fermentation. The best performance was obtained in 135 rpm and 8 h of HRT. The amount of gas varied with different OLRs, but could be stabilized on a high level. Methane was not detected when the HRT was less than 16 h. The study ...
The pilot area of the Vyngapour oil field allotted for MIOR tests contains three injection and three producing wells. These wells were treated in summer 1993 and 1994. Before, during, and after MIOR treatments on the pilot area the chemical compounds of injected and formation waters were studied, as well as the amount and species of microorganisms entering the stratum with the injected water and indigenous bacteria presented in bottomhole zones of the wells. The results of monitoring showed that the bottomhole zone of the injection well already had biocenosis of heterotrophic, hydrocarbon-oxidizing, methanogenic, and sulfate-reducing bacteria, which were besides permanently introduced into the reservoir during the usual waterflooding. The nutritious composition activated vital functions of all bacterial species presented in the bottomhole zone of the injection well. The formation waters from producing wells showed the increase of the content of nitrate, sulfate, ...
The results from a hot test, using authentic HLLW solution, of the CTH actinide separation process are reported. The process consists of three solvent extraction cycles for separation of actinides and technetium from reprocessing high level liquid waste, utilizing HDEHP, TBP, and HDEHP in sequence, and an optional step for sorption on inorganic ion exchangers of the fission product content in the process raffinate. In general the process worked according to predictions but a malfunctioning feed pump gave a 10% loss of Pu to one stream. The hot test indicating that U and Pu can be recovered with losses below 0.1% and Am, Cm with a loss below 0.2%. Np and Tc were difficult to follow because of the low activity of /sup 237/Np and because /sup 99/Tc is a pure beta emitter, but the results indicate that also these elements behaved according to predictions, i.e., that recoveries >= 99.8% for Np and >= 97% for Tc can be achieved. For the HLLW stream the solvent ...
The merits of single stage absorption heat pumps coupled to simple distillation for effluent treatment are discussed. An experimental integrated absorption heat pump effluent purification system (IAHPEPS) was built and operated with water-lithium bromide as a working mixture. This unit has been used to raise the temperature and hence, the vapour pressure of the impure water contained in one vessel, to the point where pure water vapour will distil from impure effluent solution (tap water or brine) and condense in a second vessel used to collect pure water. Pure effluent production rates of between 0.5 and 4.3 kg h{sup -1} were obtained. The actual coefficient of performance (COP{sub A}) and the heat pump effectiveness varied from 1.1 to 1.4 and 0.58 to 0.72, respectively. The results from the small scale systems indicate the likely results from industrial scale units which could be operated with low quality heat such as waste heat, solar or ...
A residue of the sugar industry can be used in revegetation programs on metal contaminated sites. - Phytostabilisation of bare heavily contaminated substrate, such as abandoned mine sites, is considered a very appropriate technology in order to diminish erosion and dispersion of contaminants into the surroundings. In this short-term pot study, application of industrial sugar residue (ISR), a waste product of the sugar industry, proved to ameliorate spoils conditions for plant performance by elevating pH and immobilising several metals. Although arsenate concentrations were positively correlated to spoil pH and spoil treatment with ISR mobilised As, growth of both Phaseolus vulgaris and Holcus lanatus improved significantly after applications of 3.75 g ISR kg{sup -1} dry spoil. Nutrient uptake from the substrate, with the exception of potassium, was elevated by ISR. As a remediation technique ISR application could be effective although in ...
Experiments on aqueous TiO{sup 2} photocatalytic reaction characteristics of 4 nitrogen-containing and 12 aromatic organic compounds were carried out. Based on the values calculated for the distribution of ionic species and atomic charge, the characteristics of their photocatalytic decomposition were estimated. It was shown that the dependence of decomposition of the N-containing compounds were linearly proportional to their nitrogen atomic charge values, while that of the aromatic compounds were inversely proportional. The effects of aqueous pH, oxygen content and concentration on the TiO{sup 2} photocatalytic characteristics of EDTA-Cu(II) and EDTA-Fe(III) were experimentally investigated. All EDTA systems were decomposed better in the pH range of 2.5{approx}3.0 and with more dissolved oxygen. These results could be applied to a unit process for removal of organic impurities dissolved in a source water of the system water, and for treatment of EDTA-containing ...
The Process WasteTreatment Plant (PWTP) at the Oak Ridge National Laboratory is designed to remove radioactive contaminants, principally {sup 90}Sr, from process wastewater. Planned upgrades to the PWTP will use chabazite zeolite columns. Pilot-scale studies have shown that mass transfer zone lengths increase from 10 to about 30 cm as the superficial velocity increases from 5.5 to 22 cm/min. Calculations with a multicomponent equilibrium model showed that the distribution coefficient for strontium remains essentially constant over the process conditions, suggesting that a simple kinetic model (the Rosen long-bed solution) should adequately represent breakthrough behavior. Using a distribution coefficient of 4.87 L/g predicted by the equilibrium model, good agreement was found between experimental breakthrough curves and those calculated with the Rosen solution. This model allows prediction of bed depths and cycle times necessary to achieve the ...
ObjectivesThis programme aims; To rethink how waste is thought about in social science; To provide a global analysis of waste; To examine how rethinking waste impinges on core social science concerns, notably: economies, researching globalisation, hazards and risk, and materiality. Social science understandings of waste position waste as the end-point of production and consumption, and see waste as a question of disposal.DescriptionThe Waste of the World is a five year research programme funded under ESRC's Large Grant Scheme. It brings together researchers in geography, anthropology and materials science from the University of Sheffield, Durham University, University College London and Goldsmiths College London, and connects the UK with South Asia (particularly India and Bangladesh), as well as the US, Europe and Kazakhstan. The ...
This Waste Management Plan describes waste management and waste minimization activities for Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory. The waste management activities described in this plan support the selected response action presented in the Final Record of Decision for Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13. This plan identifies the waste streams that will be generated during implementation of the remedial action and presents plans for waste minimization, waste management strategies, and waste disposition.
In the discussion of environmental architecture, we are conjoining two disciplines, the subject of architecture and that of ecology. At their best, green buildings are examples of applied ecology, where designers understand the constitution, organization, and structure of ecosystems, and the impacts of architecture are considered from an environmental perspective. By utilizing the concepts, methods, and language of ecology, designers can create architecture that intentionally engages the natural systems of a site. The establishment of assessment criteria implies the definition of building design criteria. If we establish criteria that are based on our best scientific understanding of environmental capacity, we will begin to develop a building stock that is sustainable. To do this we must quantify the link between the resulting environmental impacts and their cause in building production and use. This is ...
The preliminary results of a feasibility study of nighttime and/or daytime accelerated ventilation for reducing or even avoiding air conditioning energy consumption in commercial buildings, is presented. The first part of the study is based on computerized simulations and in-situ experimentations which are described. The second part is aimed at determining technological limitations to the various components and optimizing building environmental quality in terms of energy conservation, acoustics and air quality
In this study, a probabilistic seismic risk analysis of the Wolsung NPP containment building was performed by a seismic hazard analysis and a seismic fragility analysis based on the nonlinear dynamic time-history analyses. The conventional seismic fragility analysis of the safety related structures in a NPP have been performed by using the linear elastic analysis results. The probabilistic seismic risk of the containment building was 5.19e-8.
In this study, a probabilistic seismic risk analysis of the Wolsung NPP containment building was performed by a seismic hazard analysis and a seismic fragility analysis based on the nonlinear dynamic time-history analyses. The conventional seismic fragility analysis of the safety related structures in a NPP have been performed by using the linear elastic analysis results. The probabilistic seismic risk of the containment building was 5.19e-8.
This report provides a detailed description of, and the baseline assumptions and simulation results for, the building prototype simulations conducted for the building types designated in the Work Plan for Demand-side Management Assessment of Hawaii`s Demand-Side Resources (HES-4, Phase 2). This report represents the second revision to the initial building prototype description report provided to DBEDT early in the project. Modifications and revisions to the prototypes, based on further calibration efforts and on comments received from DBEDT Staff have been incorporated into this final version. These baseline prototypes form the basis upon which the DSM measure impact estimates and the DSM measure data base were developed for this project. This report presents detailed information for each of the 17 different building prototypes developed for use with the DOE-21E program (23 ...
This request is submitted to seek interim approval to operate a chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) wastes. This request covers only the disposal of small quantities of solid PCB wastes contained in decommissioned su...
The Waste Acceptance Preliminary Specifications (WAPS) require that the DWPF estimate the inventory of long-lived radionuclides present in the waste glass, and report the values in the Waste Form Qualification Report. In this report, conservative (biased high) estimates of the radionuclide inventory of glass produced from waste currently in the Tank Farm are provided. In most cases, these calculated values compare favorably with actual data. In those cases where the agreement is not good, the values reported here are conservative.
This paper very briefly outlines hazardous waste management issues, including regulations, in Mongolia. Air, water, and soil pollutants are identified and placed in context with climatic, social, and economic circumstances. The primary need identified is technology for the collection and disposal of solid wastes. Municipal waste problems include rapid urbanization and lack of sanitary landfills. Industrial wastes of concern are identified from the mining and leather industries. 4 refs., 2 tabs.
A supplementary report to the plan for waste disposal in the Copenhagen area, Denmark. It presents a mapping of wastes and waste flow in invidual areas, a description of recycling methods and waste collection systems. In addition legislative demands and potentials are dealth with. (CLS).
On 21 October 1994, three brothers entered a waste repository at Tammiku, Estonia, without authorization and removed a metal container enclosing a caesium-137 source. During the removal the source was dislodged and fell to the ground. One of the men picked up the source, placed it in his pocket and took it to his home in the nearby village of Kiisa. Very soon after entry into the repository he began to feel ill, and few hours later he began to vomit. The man was subsequently admitted to hospital with severe injuries to his leg and hip and died on 2 November 1994. The injury and subsequent death were not attributed to radiation exposure, and the source remained in the man's house with his wife and stepson and the boy's great-grandmother. The boy was hospitalized on 17 November with severe burns on his hands, and these were identified by a doctor as radiation induced. The authorities were alerted, and the Estonian Rescue Board recovered the source from the house. The ...