WorldWideScience
1

Production and remediation of low sludge simulated Purex waste glasses, 2: Effects of sludge oxide additions on glass durability  

Energy Technology Data Exchange (ETDEWEB)

Glass produced during the Purex 4 campaigns of the Integrated DWPF Melter System (IDMS) and the 774 Research Melter contained a lower fraction of sludge components than targeted by the Product Composition Control System (PCCS). Purex 4 glass was more durable than the benchmark (EA) glass, but was less durable than most other simulated SRS high-level waste glasses. Further, the measured durability of Purex 4 glass was not as well correlated with the durability predicted from the DWPF process control algorithm, probably because the algorithm was developed to predict the durability of SRS high-level waste glasses with higher sludge content than Purex 4. A melter run, designated Purex 4 Remediation, was performed using the 774 Research Melter to determine if the initial PCCS target composition determined for Purex 4 would ...

1993-10-01

2

Production and remediation of low-sludge, simulated Purex waste glasses, 1: Effects of sludge oxide additions on melter operation  

Energy Technology Data Exchange (ETDEWEB)

Glass produced during the Purex 4 campaigns of the Integrated Defense Waste Processing Facility (DWPF) Melter System (IDMS) and the 774 Research Melter contained a lower fraction of sludge components than targeted by the Product Composition Control System (PCCS). Purex 4 glass was more durable than the benchmark (EA) glass, but less durable than most simulated SRS high-level waste glasses. Also, Purex 4 glass was considerably less durable than predicted by the algorithm which will be used to control production of DWPF glass. A melter run was performed using the 774 Research Melter to determine if the initial PCCS target composition determined for Purex 4 would produce acceptable glass whose durability could be accurately modeled by Hydration Thermodynamics. Reagent grade oxides and carbonates were ...

1993-07-15

3

Surface Crystallization and Composition of Spinel and Acmite in High-Level Waste Glass  

Science.gov (United States)

Surface crystallization and surface-to-bulk ratio in high-level waste glasses.

2000-07-10

4

EFFECTS OF QUARTZ PARTICLE SIZE AND SUCROSE ADDITION ON MELTING BEHAVIOR OF A MELTER FEED FOR HIGH-LEVEL GLASS  

Energy Technology Data Exchange (ETDEWEB)

The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had virtually zero impact on both foaming and the ...

2010-07-28

7

Environmentally conscious sintered glass-ceramics  

Energy Technology Data Exchange (ETDEWEB)

Sintered glass-ceramics have been produced using municipal incinerator solid residues and glass cullet or an inert waste, from feldspars processing, as sintering aids. The capability of three different mixtures, either previously vitrified or not, to be sintered was investigated by means of linear shrinkage, water absorption and bulk density measurements, and by X-ray diffraction analysis and scanning electron microscopy observations. Particular attention has been addressed to the study of particle size effect on the sintering process. The conclusions that can be drawn from the experimental study are that the preliminary vitrification step is essential in order to obtain a dense sintered glass-ceramic product in the 850-1050 C temperature range developing silicate crystalline phases. The optimal powder particle size that confers a good densification degree was found to be < ...

2002-07-01

8

The influence of the binder on the properties of sintered glass-ceramics produced from industrial wastes  

Energy Technology Data Exchange (ETDEWEB)

Sintered glass-ceramics were produced from coal fly ashes, red mud from aluminum production and silica fume. The capabilities of Tuncbilek fly ash and a mixture of Orhaneli fly ash, red mud and silica fume to be vitrified and devitrified by sintering process were investigated by means of scanning electron microscopy and X-ray diffraction analysis. To determine the effect of binder in the sintering technique, glass powders were pressed without or with the addition of polyvinyl alcohol. Owing to microstructural observations, density and hardness measurements, it can be said that physical properties and the hardness of the produced samples strongly depended on the crystallization degree of the samples. Toxicity characteristic leaching procedure test results showed that glass-ceramic samples produced by using sintering technique could be considered as nonhazardous materials. Chemical durability of the ...

2009-09-15

9

Projected radionuclide inventories of DWPF glass from current waste at time of production  

Energy Technology Data Exchange (ETDEWEB)

The Waste Acceptance Preliminary Specifications (WAPS) require that the DWPF estimate the inventory of long-lived radionuclides present in the waste glass, and report the values in the Waste Form Qualification Report. In this report, conservative (biased high) estimates of the radionuclide inventory of glass produced from waste currently in the Tank Farm are provided. In most cases, these calculated values compare favorably with actual data. In those cases where the agreement is not good, the values reported here are conservative.

1993-02-04

10

Fixation of high-level wastes in glasses  

Energy Technology Data Exchange (ETDEWEB)

A plant for the fixation of high-level wastes in borosilicate glass has been operating in France since 1978. A large plant is under construction in the U.S. for the fixation of defence high-level waste and plans for other glass fixation plants are well advanced at several sites around the world. Among the reasons for the selection of borosilicate glass as a fixation medium are the relative ease of processing wastes of variable composition by means of well established technology, and the long-term radiation and thermal stability of the glass. Well formulated glass also has sufficient resistance to the action of groundwater so that it can serve as an important barrier against the spread of radionuclides via groundwater in any forseeable situation. Research is continuing to quantify the reactions of ...

1986-07-30

11

Magnetic properties of glasses from geothite industrial wastes recycling (FeOOH)  

International Nuclear Information System (INIS)

It has been carried out the magnetic properties determination for high iron oxide content glasses series obtained from a geothite red mud waste from the zinc hydrometallurgy and dolomite and glass cullet as main raw materials. It has been determined the magnetic susceptibility and magnetization values for the glasses here investigated. The results suggest that the magnetic behaviour are depending on the glass chemical composition, so that glasses can be differently classified like ferrimagnetic, ferromagnetic, superparamagnetic and paramagnetic. (Author) 6 refs.

12

Transmission electron microscopy of simulated DWPF high level nuclear waste glasses following gamma irradiation  

International Nuclear Information System (INIS)

Thermal analysis testing revealed slight weight changes, which were a function of gamma irradiation, in a highly reduced Defense Waste Processing Facility (DWPF) simulated waste glass. Transmission electron microscopy (TEM) was performed on this glass to determine if the weight change corresponded to microstructural variations. TEM analyses showed that no microstructural changes were attributable to gamma irradiation. Exposure of the samples to the electron beam in the TEM did cause changes in the glass microstructures in some cases. These changes were likely due to localized heating of the glass due to interactions with the transmitted electrons.

1994-04-25

13

Community Geothermal Technology Program: Hawaii glass project. Final report  

Energy Technology Data Exchange (ETDEWEB)

Objective was to develop a glass utilizing the silica waste material from geothermal energy production, and to supply local artists with this glass to make artistic objects. A glass composed of 93% indigenous Hawaiian materials was developed; 24 artists made 110 objects from this glass. A market was found for art objects made from this material.

1988-01-20

14

Characterization of projected DWPF glasses heat treated to simulate canister centerline cooling  

Energy Technology Data Exchange (ETDEWEB)

Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. The glass will be produced and poured into stainless steel canisters in the Defense Waste Processing Facility (DWPF). Eventually these canistered waste forms will be sent to a geologic repository for final disposal. In order to assure acceptability by the repository, the Department of Energy has defined requirements which DWPF canistered waste forms must meet. These requirements are the Waste Acceptance Preliminary Specifications (WAPS). The WAPS require DWPF to identify the crystalline phases expected to be present in the final glass product. Knowledge of the thermal history of the borosilicate glass during filling and cooldown of the canister is necessary to determine the ...

1992-05-01

16

SUCCESSES AND EMERGING ISSUES IN SIMULATING THE MIXING BEHAVIOR OF LIQUID-PARTICLE NUCLEAR WASTE SLURRIES AT THE SAVANNAH RIVER SITE - 211B  

Energy Technology Data Exchange (ETDEWEB)

Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent ...

2009-09-02

17

INTRINSIC DOSIMETRY: A POTENTIAL NEW TOOL FOR NUCLEAR FORENSICS INVESTIGATIONS  

International Nuclear Information System (INIS)

Thermoluminescence (TL) dosimetry was used to measure dose effects on the raw stock material of borosilicate container glass from different geographical locations. Effects were studied at times up to 60 days post-irradiation at doses from 0.15 to 20 Gy. The minimum detectable dose using this technique was estimated to be 0.15 Gy which is roughly equivalent to a 24 hr irradiation 1 cm from a 50 ng source of 60Co. Two peaks were identified in the TL glow curve, a relatively unstable peak around 125 C and a more stable peak around 225 C. Differences in TL glow curve shape and intensity were also observed for the glasses from different geographical origins. We investigate radiation induced defects in glass to further develop the technique of intrinsic dosimetry - the measurement of the total absorbed dose received by the walls of a container holding radioactive material. Intrinsic ...

2010-07-11

18

Vitrification of waste  

Energy Technology Data Exchange (ETDEWEB)

A method for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300{degrees}C to 800{degrees}C to incinerate organic materials, then heated further to a temperature in the range of approximately 1100{degrees}C to 1400{degrees}C at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.

1992-12-31

19

Projected radionuclide inventories of DWPF glass from current waste at time of production. Revision 1  

Energy Technology Data Exchange (ETDEWEB)

The Waste Acceptance Preliminary Specifications (WAPS) require that the DWPF estimate the inventory of long-lived radionuclides present in the waste glass, and report the values in the Waste Form Qualification Report. In this report, conservative (biased high) estimates of the radionuclide inventory of glass produced from waste currently in the Tank Farm are provided. In most cases, these calculated values compare favorably with actual data. In those cases where the agreement is not good, the values reported here are conservative.

1993-02-04

20

Polymeric radioactive waste disposal containers: an investigation into the application of polymers vice metals to house low and intermediate level radioactive waste  

Energy Technology Data Exchange (ETDEWEB)

The research carried out in Canada in the design of containers for the disposal of radioactive waste has focussed on spent nuclear fuel, even though the quantities of other currently stored radioactive wastes are substantially greater. Research carried out at the Royal Military College of Canada on the effects of mixed fields of radiation on high polymer adhesives and composite materials has shown that some polymers are quite resistant to radiation and could well serve in the fabrication of radioactive waste disposal containers. The purpose of this research was to determine if thermoplastic polymers could be used as superior materials to replace metals in the application of low and intermediate level radioactive waste disposal containers. Polymers have the advantage that they do not corrode like metals. The experimental methods, used in this research, focused on the ...

2001-07-01

21

Design and performance of a 100-kg/h, direct calcine-fed electric-melter system for nuclear-waste vitrification  

Energy Technology Data Exchange (ETDEWEB)

This report describes the physical characteristics of a ceramic-lined, joule-heated glass melter that is directly connected to the discharge of a spray calciner and is currently being used to study the vitrification of simulated nuclear-waste slurries. Melter performance characteristics and subsequent design improvements are described. The melter contains 0.24 m/sup 3/ of glass with a glass surface area of 0.76 m/sup 2/, and is heated by the flow of an alternating current (ranging from 600 to 1200 amps) between two Inconel-690 slab-type electrodes immersed in the glass at either end of the melter tank. The melter was maintained at operating temperature (900 to 1260/sup 0/C) for 15 months, and produced 62,000 kg of glass. The maximum sustained operating period was 122 h, during which glass was produced at the rate of 70 kg/h.

1980-11-01

22

Hanford Waste Vitrification Plant Quality Assurance Program description for high-level waste form development and qualification  

International Nuclear Information System (INIS)

The Hanford Waste Vitrification Plant Project has been established to convert the high-level radioactive waste associated with nuclear defense production at the Hanford Site into a waste form suitable for disposal in a deep geologic repository. The Hanford Waste Vitrification Plant will mix processed radioactive waste with borosilicate material, then heat the mixture to its melting point (vitrification) to forin a glass-like substance that traps the radionuclides in the glass matrix upon cooling. The Hanford Waste Vitrification Plant Quality Assurance Program has been established to support the mission of the Hanford Waste Vitrification Plant. This Quality Assurance Program Description has been written to document the Hanford Waste Vitrification Plant Quality Assurance Program.

1993-05-06

23

Numerical analysis of a natural convection cooling system for radioactive canisters storage  

International Nuclear Information System (INIS)

This paper describes the use of numerical analysis for studying natural convection cooling systems for long term storage of heat producing radioactive materials, including special nuclear materials and nuclear waste. The paper explains the major design philosophy, and shares the experiences of numerical modeling. The strategy of storing radioactive material is to immobilize nuclear high-level waste by a vitrification process, convertion it into borosilicate glass, and cast the glass into stainless steel canisters. These canisters are seal welded, decontaminated, inspected, and temporarily stored in an underground vault until they can be sent to a geologic repository for permanent storage. These canisters generate heat by nuclear decay of radioactive isotopes. The function of the storage facility ventilation system is to ensure that the glass centerline temperature does not exceed ...

1995-02-01

24

Review of high-level waste form properties. [146 bibliographies  

Energy Technology Data Exchange (ETDEWEB)

This report is a review of waste form options for the immobilization of high-level-liquid wastes from the nuclear fuel cycle. This review covers the status of international research and development on waste forms as of May 1979. Although the emphasis in this report is on waste form properties, process parameters are discussed where they may affect final waste form properties. A summary table is provided listing properties of various nuclear waste form options. It is concluded that proposed waste forms have properties falling within a relatively narrow range. In regard to crystalline versus glass waste forms, the conclusion is that either glass of crystalline materials can be shown to have some advantage when a single property is considered; however, at this date no single ...

1980-12-01

25

Long-term hygrothermal effects on damage tolerance of hybrid composite sandwich panels  

Science.gov (United States)

A sandwich construction, composed of hybrid carbon-glass fiber-reinforced plastic skins and a

1995-01-01

26

Durability of Defense Waste Processing Facility glasses within the Purex range of compositions  

Energy Technology Data Exchange (ETDEWEB)

Processing in the Defense Waste Processing Facility (DWPF) is controlled by constraints on predicted properties of the product glass. One of these properties is chemical durability, which is measured as the response of various glass constituents to the seven-day Product Consistency Test (PCT) [1]. As currently implemented into the DWPF`s Product Composition Control System (PCCS) the response of boron is taken as representative of all of the constituent responses, and control is in terms of the boron response. This response, in normalized units and in log scale, is taken to be a linear function of the glass`s free energy of hydration, {Delta}G. {Delta}G is a parameter which represents the sum of influences on durability of the various glass oxide components. A generalized relationship between these two variables is documented in [2]. This relationship appears to underpredict releases ...

1995-05-01

27

In situ Raman spectroscopy investigation of bioactive glass reactivity: Simulated body fluid solution vs TRIS-buffered solution  

British Library Electronic Table of Contents (United Kingdom)

In the present contribution, the innovative in situ Raman micro-spectroscopy was applied to investigate the in vitro reactivity of various bioactive glasses. All the investigated glasses belonged to the Na2O\\K2O-CaO-P2O5-SiO2 system, but contained sensibly different percentages of network modifiers. The glasses were immersed for increasing times, up to 96h, in simulated body fluid (SBF) and in tris-buffered (TRIS) solution. In this way, two fundamental items were addressed, i.e. the effect of the glass composition and the nature of the soaking fluid on the overall reactivity. As regards the SBF, all the glasses were able to promote the formation of a hydroxyl-carbonate apatite (HCA) surface layer in very short times. The reaction rate was particularly quick for the 45S5 Bioglass and for it...

2011-01-01

28

Evaluation of Phase II glass formulations for vitrification of Hanford Site low-level waste  

Energy Technology Data Exchange (ETDEWEB)

A vendor glass formulation study was carried out at Pacific Northwest Laboratory (PNL), supporting the Phase I and Phase II melter vendor testing activities for Westinghouse Hanford Company. This study is built upon the LLW glass optimization effort that will be described in a separate report. For Phase I vendor melter testing, six glass formulations were developed at PNL and additional were developed by Phase I vendors. All the doses were characterized in terms of viscosity and chemical durability by the 7-day Product Consistency Test. Twelve Phase II glass formulations (see Tables 3.5 and 3.6) were developed to accommodate 2.5 wt% P{sub 2}O{sub 5} and 1.0 wt% S0{sub 3} without significant processing problems. These levels of P{sub 2}O{sub 5} and SO{sub 3} are expected to be the highest possible concentrations from Hanford Site LLW streams at 25 wt% waste loading in ...

1996-03-01

29

De-entrainment of boron by evaporation  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this research was to investigate the de-entrainment of boron for evaporators used in nuclear power plants. The forced circulation and semi-continuous type evaporator was used in the experiment. Cyclone and glass-wool packed column which is supposed to provide good decontamination factor as well as easy maintenance, were selected as de-entrainment device to be used in the evaporation of radioactive liquid wastes. The de-entrainment device combined with cyclone and glass-wool column has shown overall DF more than 1000 for boron.

1986-12-01

30

Modeling jet penetration in glass  

Energy Technology Data Exchange (ETDEWEB)

It is well known that composite armors, consisting of glass elements confined with metallic tampers, are extraordinarily effective against shaped charge attack. Early experiments showed that jets fired against glass targets appeared to be bombarded by tiny fragments that destroyed alignment and reduced residual jet penetration. This result was attributed to an elastic rebound effect in which the outward radial motion of the target around the jet periphery was supposed to be arrested by tensile hoop stresses which developed behind the divergent shock front. Glass fragments were then accelerated radially inward and these destabilized the jet. To sustain the large tensile hoop stresses required, the glass must not have been fractured by the initial shock, behind which the stress state is typically well above the Hugoniot elastic limit. Modeling the penetration of a ...

1990-04-05

31

Obsidians and tektites: Natural analogues for water diffusion in nuclear waste glasses  

Energy Technology Data Exchange (ETDEWEB)

Projected scenarios for the proposed Yucca Mountain repository include significant periods of time when high relative humidity atmospheres will be present, thus the reaction processes of interest will include those known to occur under these conditions. The ideal natural analog for the proposed Yucca Mountain repository would consist of natural borosilicate glasses exposed to expected repository conditions for thousands of years; however, the prospects for identifying such an analog are remote, but an important caveat for using natural analog studies is to relate the reaction processes in the analog to those in the system of interest, rather than a strict comparison of the glass compositions. In lieu of this, identifying natural glasses that have reacted via reaction processes expected in the repository is the most attractive option. The goal of this study is to quantify molecular water diffusion in the natural analogs ...

1991-11-01

32

Heavy ion induced changes in nuclear waste glasses: a micro Raman investigation  

International Nuclear Information System (INIS)

Borosilicate based glass formulations have been found suitable for fixing the HLW (high level radioactive liquid waste) generated after reprocessing of the spent nuclear fuel. As the glass experiences continuous irradiation by #alpha#, #beta#a, and #gamma# radiations from the radioactive components of HLW, alteration in the glass structure may occur. Understanding of these structural evolutions of the nuclear waste glasses under irradiation is crucial to secure long term disposal and predict their behavior. In the present work, alkali based barium borosilicate glasses, having composition similar to that of Trombay Research Reactor waste glass were irradiated with high energy "1"2C beam and the radiation induced changes were monitored by micro Raman experiment. Since a "1"2C atom can be considered as ...

2010-12-01

33

WASTE TREATMENT AND DISPOSAL PROGRESS REPORT FOR JUNE AND JULY 1962  

Science.gov (United States)

9 9 simulated Purex waste oxides was investigated as a function of Na/sub 2/O, CaO and P/sub 2/O/sub 5/ content. All compositions lost some sulfate at 50 to 100 deg C above the softening point. In generai the volatility decreased with increase of either Na/ sub 2/O or CaO relative to P/sub 2/O/sub 5/, but no simple correlation Was indicated. Softening temperatures were lowered by inc ease in Na/sub 2/O vs CaO. Ceramic solids were obtained but no true glasses. Attempts to produce glasses by addition of varying combinations of Al/sub 2/O/sub 3/, PbO, BaO, and B/sub 2/O/ sub 3/ to simulated Pure x waste plus phosphite were unsuccessful. The use of 0.005 M Na/sub 2/C/O/sub 3/ to precipitate calcium from wastes containing up to 3 ppm of phosphate was demonstrated in four pilot plant runs and produced a decrease in the hardness of the ...

1962-12-19

34

Standardisation of techniques for evaluation of solidified high level waste product: A status report  

Science.gov (United States)

The results of studies on: (1) development of suitable glass compositions for solidification and vitrification of high level radioactive wastes, and (2) the characteristics of these compositions, namely, leaching, mechanical properties, thermal conductivity, viscosity and homogeneity evaluation are reported. Inactive simulated purex waste was used for compositions reported herein. The data generated on leaching and other product characteristics of the selected vitrified waste products was used to evaluate the performance of corresponding experimental units and techniques with respect to their reproducibility and reliability.

1981-01-01

35

The off-gas cleaning system for gases formed during the vitrification of high-activity wastes from the nuclear power plant A 1  

International Nuclear Information System (INIS)

A multielement apparatus for the removal of aerosols formed in the vitrification of simulated high-activity accident wastes from the decommissioned nuclear power plant A-1 has been designed, manufactured and tested. The apparatus consists of two cooling and condensing steps connected in series, and of five filtration steps also connected in series. The five filtration steps allowed to achieve a decontamination factor of 1x10"5 in the case of removal of a NaCl("2"4Na) testing model aerosol. The decontamination factor for removal of the cesium aerosol by the whole apparatus was 3.3x10"6. In the first filtration step the aerosols are removed by the cartridge with a filtration fabric made of polyethylene fibers, in the second step by the cartridge with a granulated natural material, in the third step by the cartridge with glass-fiber filtration paper, in the fourth and fifth steps by the cartridge with high-efficiency filtration paper made of ...

36

Environmental assessment of alternative municipal solid waste management strategies. A Spanish case study  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study is to compare, from an environmental point of view, different alternatives for the management of municipal solid waste generated in the town of Castellon de la Plana (Spain). This town currently produces 207ton of waste per day and the waste management system employed today involves the collection of paper/cardboard, glass and light packaging from materials banks and of rest waste at street-side containers. The proposed alternative scenarios were based on a combination of the following elements: selective collection targets to be accomplished by the year 2015 as specified in the Spanish National Waste Plan (assuming they are reached to an extent of 50% and 100%), different collection models implemented nationally, and diverse treatments of both the separated biodegrad...

2010-01-01

37

White luminescence of Tm-Dy ions co-doped aluminoborosilicate glasses under UV light excitation  

International Nuclear Information System (INIS)

Tm3+ and Dy3+ ions co-doped aluminoborosilicate glasses were prepared in this study. The luminescence properties of the glasses were analyzed. A combination of blue, green, yellow, and red emission bands was shown for these glasses, and white light emission could be observed under UV light excitation. White light luminescence color could be changed by varying the excitation wavelength. Concentration quenching effect was investigated in this paper. Furthermore, the dependence of luminescence properties on glass compositions was studied. Results showed that the luminescence intensity changed with different network modifier oxides, while the white color luminescence was not affected significantly. - Graphical abstract: Tm3+ and Dy3+ ions co-doped aluminoborosilicate glasses, which emit white light under UV light excitation, were prepared. The dependence of ...

2008-10-01

38

Control of the reduction/oxidation potential of Hanford Waste Vitrification Plant feeds  

International Nuclear Information System (INIS)

A schematic diagram shows the various processing steps to be performed during feed preparation in the Hanford Waste Vitrification Plant (HWVP). The pretreated NCAW is transferred to the slurry receipt adjustment tank (SRAT) in the HWVP for concentration. Water removed during boildown is collected in the slurry mix evaporator condensate tank (SMECT). After waste treatment the water is returned to the storage tanks for eventual disposal. The pretreated Neutralized Current Acid Waste (NCAW) is concentrated in the SRAT to approximately 125 g waste oxides/ liter. Formic acid is then added at a controlled rate to improve rheological properties and achieve a required reduction/oxidation state. Reflux boiling is initiated and continued for several hours. The concentrated slurry is cooled and pumped to the slurry mix evaporator (SME). In the SME, glass frit is added, and the slurry is ...

1988-09-11

39

DWPF waste form compliance plan (Draft Revision)  

Energy Technology Data Exchange (ETDEWEB)

The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970's, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in ...

1991-01-01

40

DWPF waste form compliance plan (Draft Revision)  

Energy Technology Data Exchange (ETDEWEB)

The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970`s, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in ...

1991-12-31

41

Survey of agents and techniques applicable to the solidification of low-level radioactive wastes  

Energy Technology Data Exchange (ETDEWEB)

A review of the various solidification agents and techniques that are currently available or potentially applicable for the solidification of low-level radioactive wastes is presented. An overview of the types and quantities of low-level wastes produced is presented. Descriptions of waste form matrix materials, the wastes types for which they have been or may be applied and available information concerning relevant waste form properties and characteristics follow. Also included are descriptions of the processing techniques themselves with an emphasis on those operating parameters which impact upon waste form properties. The solidification agents considered in this survey include: hydraulic cements, thermoplastic materials, thermosetting polymers, glasses, synthetic minerals and composite materials. This survey is part of a program supported ...

1981-12-01

42

Nuclear waste form risk assessment for US defense waste at Savannah River Plant. Annual report fiscal year 1980  

Energy Technology Data Exchange (ETDEWEB)

Waste form dissolution studies and preliminary performance analyses were carried out to contribute a part of the data needed for the selection of a waste form for the disposal of Savannah River Plant defense waste in a deep geologic repository. The first portion of this work provides descriptions of the chemical interactions between the waste form and the geologic environment. We reviewed critically the dissolution/leaching data for borosilicate glass and SYNROC. Both chemical kinetic and thermodynamic models were developed to describe the dissolution process of these candidate waste forms so as to establish a fundamental basis for interpretation of experimental data and to provide directions for future experiments. The complementary second portion of this work is an assessment of the impacts of alternate waste forms upon the consequences of ...

1981-07-01

43

Sampling and Analysis at the Vortec Vitrification Facility in Paducah, Kentucky. Semiannual report, November 1, 1996--March 31, 1997  

Science.gov (United States)

The Vortec Cyclone Melting System (CMS) facility; to be located at the U.S. Department of Energy (DOE) Paducah Gaseous Diffusion Plant, is designed to treat soil contaminated with low levels of heavy metals and radioactive elements, as well as organic waste. The primary components of Vortec`s CMS are a counter rotating vortex (CRV) reactor and cyclone melter. In the CMS process, granular glass forming ingredients and other feedstocks are introduced into the CRV reactor where the intense CRV mixing allows the mixture to achieve a stable reaction and rapid heating of the feedstock materials. Organic contaminants in the feedstock are effectively oxidized, and the inert inorganic solids are melted. The University of North Dakota Energy {ampersand} Environmental Research Center (EERC) has been contacted to help in the development of sampling plans and to conduct the sampling at the facility. This document is written in a format ...

1997-12-31

44

Review of the Vortec soil remediation demonstration program  

Energy Technology Data Exchange (ETDEWEB)

The principal objective of the METC/Vortec program is to develop and demonstrate the effectiveness of the Vortec CMS in remediating soils contaminated with hazardous materials and/or low levels of radionuclides. To convincingly demonstrate the CMS`s capability, a Demonstration Plant will be constructed and operated at a DOE site that has a need for the remediation of contamination soil. The following objectives will be met during the program: (1) establish the glass chemistry requirements to achieve vitrification of contaminated soils found at the selected DOE site; (2) complete the design of a fully integrated soil vitrification demonstration plant with a capacity to process 25 TPD of soil; (3) establish the cost of a fully integrated soil demonstration plant with a capacity to process 25 TPD of soil; (4) construct and operate a fully integrated demonstration plant; (5) analyze all influent and effluent streams to establish the partitioning of ...

1994-12-31

45

Lithium ion conductive glass?ceramics with Li3Fe2(PO4)3 and YAG laser-induced local crystallization in lithium iron phosphate glasses  

British Library Electronic Table of Contents (United Kingdom)

The glasses with the composition of 37.5Li2O?(25?x)Fe2O3?xNb2O5?37.5P2O5 (mol%) (x=5,10,15) are prepared, and it is found that the addition of Nb2O5 is effective for the glass formation in the lithium iron phosphate system. The glass?ceramics consisting of Nasicon-type Li3Fe2(PO4)3 crystals with an orthorhombic structure are developed through conventional crystallization in an electric furnace, showing electrical conductivities of 3?10?6?Scm?1 at room temperature and the activation energies of 0.48?eV (x=5) and 0.51?eV (x=10) for Li+ ion conduction in the temperature range of 30?200??C. A continuous wave Nd:YAG laser (wavelength: 1064?nm) with powers of 0.14?0.30?W and a scanning speed of 10??m/s is irradiated onto the surface of the glasses, and the formation of Li3Fe2(PO4)3 crystals is c...

2008-01-01

46

Effect of intergranular glass on phase relation of Nd-#alpha#-sialon  

International Nuclear Information System (INIS)

Quantitative analytical electron microscopy study of dopant distribution in the microstructure of selected Nd-#alpha#-sialon samples revealed the presence of relatively large amounts of glassy phase at quadruple pockets, which exhibited a common composition similar to a melilite solution. Al segregants were depleted from adjacent grain boundaries to satisfy the 'stoichiometry' of such glass. Existence of this glass results in significant deviation of the Nd-#alpha#-sialon composition from the expected values, which shifts the #alpha#-#beta#-sialon phase boundary. Only extra Nd_2O_3 additives enable a monolithic #alpha#-sialon microstructure. The absence of similar glass in Yb-#alpha#-sialon materials keeps the phase relations from such deviations.

2006-04-01

47

Intrinsic Dosimetry Of Glass Containers Used To Transport Nuclear Materials: Potential Implications to the Field of Nuclear Forensics  

International Nuclear Information System (INIS)

Thermoluminescence (TL) and Electron Paramagnetic Resonance (EPR) dosimetry were used to measure dose effects in borosilicate glass with time, from 10 minutes to #approx#60 days following exposure to a dose of up to 10,000 Rad. TL and EPR results were consistent and performed similarly, with both techniques capable of achieving an estimated limit of detection of between 50-100 Rad. Three peaks were identified in the TL glow curve at roughly 110 C, 205 C, and 225 C. The intensity of the 205 C peak was the dominant peak over the time period of this study. The stability of all of the peaks with time since irradiation increased with their corresponding temperature and little or no variation was observed in the glow curve response to a specified total dose attained at different dose rates. The intensity of the 205 C peak decreased logarithmically with time regardless of total dose. Based upon a conservative limit of detection of 330 Rad, a 10,000 ...

48

Peculiarities of Swift Proton Transmission through Tapered Glass Capillaries  

International Nuclear Information System (INIS)

A study of the 150-300 keV proton beam transmission through glass (borosilicate) tapered capillaries with different diameters of the input and output of the capillary was performed. The focusing effect was observed. The areal density of the transmitted beam is enhanced by approximately 20 times. It was shown that changing a taper angle from 0.5 deg to 1.7 deg evidences the increase of the transmission coefficient more than by 300 times keeping the initial energy spectrum of ions. (author)

2011-07-01

49

Behaviour of silicon released during alteration of nuclear waste glass in compacted clay  

Energy Technology Data Exchange (ETDEWEB)

Long term integrated in situ experiments are performed in the HADES underground research facility (Mol, Belgium) in order to study the coupled reactivity between the different components of an underground repository for vitrified high level radioactive waste (HLW): glass, compacted clay, and stainless steel containers, at 90 degrees C and under gamma irradiation. Studies pertaining to the behaviour of silicon, a major element released during glass alteration, are presented here. Data collected from the integrated experiment, from simplified tests, and from modelling are put together, giving complementary information. The integrated experiment is used to investigate overall reactivity, whereas diffusion experiments coupled with modelling focused on the precipitation of silica in clay media. In the integrated in situ experiment, a bentonite clay (FoCa7) mixed with 5 wt.% of powdered glass frit was put in ...

2007-02-15

50

Thermal waste disposal and utilization; Waste management in accordance with the German Municipal Waste Disposal Regulations. Abfaelle thermisch entsorgen und verwerten; Die Verwaltungsvorschrift TA Siedlungsabfall praegt gesamte Abfallbehandlung  

Energy Technology Data Exchange (ETDEWEB)

Drastic changes in waste management procedures are expected from the German Municipal Waste Disposal Regulations which became effective on June 1, 1993. Waste disposal will be subject to certain restrictions which, e.g. demand that wastes must be pretreated and inerted before they are stored. These regulations favor thermal waste disposal methods such as the carbonization/combustion method which is planned for a commercial-scale plant in the city of Fuerth. (orig./BBR)

1993-09-01

51

Melter system technology testing for Hanford Site low-level tankwaste vitrification  

Energy Technology Data Exchange (ETDEWEB)

Following revisions to the Tri-Party Agreement for Hanford Site cleanup, which specified vitrification for Complete melter feasibility and system operability immobilization of the low-level waste (LLW) tests, select reference melter(s), and establish reference derived from retrieval and pretreatment of the radioactive LLW glass formulation that meets complete systems defense wastes stored in 177 underground tanks, commercial requirements (June 1996). Available melter technologies were tested during 1994 to 1995 as part of a multiphase program to select reference Submit conceptual design and initiate definitive design technologies for the new LLW vitrification mission.

1996-05-03

52

A pilot plant demonstration of the vitrification of radioactive solutions using microwave power  

Energy Technology Data Exchange (ETDEWEB)

A process has been developed that exploits the characteristics of microwave heating for the vitrification of high-level radioactive liquid waste. This process, microwave vitrification, has been successfully operated at pilot plant scale in an active cell using simulated liquid waste containing several curies of radioactivity. Excellent decontamination factors have been achieved for both volatiles and nonvolatiles with an average ruthenium decontamination factor of 490 and a gross alpha emitter decontamination factor of 100,000. Almost all the radioactivity is incorporated in a glass block.

1986-01-01

53

A pilot plant demonstration of the vitrification of radioactive solutions using microwave power  

International Nuclear Information System (INIS)

A process has been developed that exploits the characteristics of microwave heating for the vitrification of high-level radioactive liquid waste. This process, microwave vitrification, has been successfully operated at pilot plant scale in an active cell using simulated liquid waste containing several curies of radioactivity. Excellent decontamination factors have been achieved for both volatiles and nonvolatiles with an average ruthenium decontamination factor of 490 and a gross alpha emitter decontamination factor of 100,000. Almost all the radioactivity is incorporated in a glass block.

54

THE RECYCLING OF MIXTURES OF HEAVY METALS FROM WASTE USING ELECTRO- DEPOSITION  

Environmental Research Database

ObjectivesObjectives Not AvailableDescriptionWe will study the electrodeposition of metals from solutions containing a~%~ mixture of metal cations, in order to discover the conditions which lead to the separation of the metals. Measurements will be made both using small glass cells and using a more realistic size (10 cm x 10 cm electrodes) of electrodeposition cell.~%~

1996-01-31

55

Pyrochemical Processing for Low-Level Waste Production in PEACER  

Science.gov (United States)

A pyrochemical partitioning process has been conceptually designed so that the transmutation of spent LWR fuels in PEACER can produce mainly low-level waste (Class C waste) for near-surface burial. Chloride salt technology developed for IFR has been employed as the baseline. Electrorefining, reductive extraction and salt recycling steps are used to construct overall flowsheet in order to support PEACER operation. The decontamination factor for transuranic elements was estimated based on both thermodynamic models and reported experimental data. It is expected that overall decontamination factor can be as high as 10{sup 5} for transuranic elements. Final wastes from pyrochemical processing for PEACER are noble metals, alkaline earth metal, and lanthanides. The final wastes are stabilized by mixing with zeolite and glass-frits such that concentration limit for class C ...

2002-07-01

56

Pyrochemical Processing for Low-Level Waste Production in PEACER  

International Nuclear Information System (INIS)

A pyrochemical partitioning process has been conceptually designed so that the transmutation of spent LWR fuels in PEACER can produce mainly low-level waste (Class C waste) for near-surface burial. Chloride salt technology developed for IFR has been employed as the baseline. Electrorefining, reductive extraction and salt recycling steps are used to construct overall flowsheet in order to support PEACER operation. The decontamination factor for transuranic elements was estimated based on both thermodynamic models and reported experimental data. It is expected that overall decontamination factor can be as high as 10"5 for transuranic elements. Final wastes from pyrochemical processing for PEACER are noble metals, alkaline earth metal, and lanthanides. The final wastes are stabilized by mixing with zeolite and glass-frits such that concentration limit for class C ...

2002-06-09

57

Pollution prevention opportunity assessment for Building 922 solid office waste  

Energy Technology Data Exchange (ETDEWEB)

Building 922 houses all of SNL/California`s ES and H Departments: Health Protection, Environmental Protection, Safety, and Environmental Operations. It covers approximately 10,000 square feet and houses about 80 people. The office personnel generate nonhazardous solid office wastes in their daily activities. To determine the types and amounts of waste generated, a special PPOA sorting team sorted all of the trash collected from the building for a period of one-week (including paper and aluminum cans in the recycling bins). The team sorted the trash into major categories: paper, plastic, metals, glass, wet garbage, rest room waste, and miscellaneous materials. They then sorted it into subcategories within each major category. Rest room waste was collected but not sorted. The waste in each category was weighed separately. The total amount of trash collected during ...

1995-01-01

58

Study of the outgassing behavior of SnO_2:F films on glass in vacuum under external energy excitation  

International Nuclear Information System (INIS)

Vacuum glazing consists of an evacuated space between two sheets of glass. Vacuum glazing has a large effect on energy savings in houses and buildings. Vacuum glazing can achieve higher insulating performance than conventional insulated glazing. Nippon Sheet Glass has successfully developed conventional vacuum glazing. In this study we investigated an advanced form of vacuum glazing. Its thermal insulation ability is equivalent to 100 mm thick glass wool thermal insulation. This vacuum glazing contained a SnO_2:F low emissivity surface. The influence of the residual gas in a vacuum space on heat flow is important to performance. For long-term thermal stability, it is very important to maintain vacuum stability. To understand this better, we studied the behavior of outgassing from the inside glass surfaces exposed to an external energy source. We have studied the behavior of ...

2005-06-15

59

Effects of Manufacturing Defects and Scaling on Glass Fiber Composite Sandwich Panels in General Aviation Aircraft Structures.  

Science.gov (United States)

This report documents the collaborative effort between the United States and Canada to investigate the impact of process-induced defects on strength and stiffness under static and fatigue loading and for low-cost composite aircraft structures, in particul...

2009-01-01

60

Waste recycling as evaluated from the viewpoint of energy environment, mainly about plastics; Haikibutsu recycle no energy kankyomen kara no hyoka. Plastic wo chushin to shite  

Energy Technology Data Exchange (ETDEWEB)

Some comments are given on the recycling of waste, mainly plastics, as evaluated from the viewpoint of energy environment. Discussed about the waste in general are the definition and classification, generation and resource recovery rates, current state of recycling, problems about recycling, related legislation, and current conditions overseas. Discussed about the treatment and recycling of plastics waste are the characters and use of plastic product, current state of waste plastics treatment, current state of waste plastics recycling (material recycling, thermal recycling), energy recovery by thermal recycling, quantity recyclable from waste plastics, energy consumption and cost for waste plastics recycling, effect and impact of increase in waste plastics in case material recycling is forwarded, and ...

1996-05-01

61

Cumulative releases of radionuclides from uncontained waste packages  

Energy Technology Data Exchange (ETDEWEB)

This report describes mathematical predictions for the migration of radionuclides from an emplaced radioactive waste container. The model assumes a spherical-equivalent waste solid surrounded by backfill but neglects the effect of decay heat. 7 refs., 2 tabs. (TEM)

1986-07-01

62

Direct conversion of surplus fissile materials, spent nuclear fuel, and other materials to high-level-waste glass  

Energy Technology Data Exchange (ETDEWEB)

With the end of the cold war the United States, Russia, and other countries have excess plutonium and other materials from the reductions in inventories of nuclear weapons. The United States Academy of Sciences (NAS) has recommended that these surplus fissile materials (SFMs) be processed so they are no more accessible than plutonium in spent nuclear fuel (SNF). This spent fuel standard, if adopted worldwide, would prevent rapid recovery of SFMs for the manufacture of nuclear weapons. The NAS recommended investigation of three sets of options for disposition of SFMs while meeting the spent fuel standard: (1) incorporate SFMs with highly radioactive materials and dispose of as waste, (2) partly burn the SFMs in reactors with conversion of the SFMs to SNF for disposal, and (3) dispose of the SFMs in deep boreholes. The US Government is investigating these options for SFM disposition. A new method for the disposition of SFMs is described herein: the simultaneous ...

1995-01-31

63

Operating experience with solidification of radioactive waste by a thin-film evaporator  

Energy Technology Data Exchange (ETDEWEB)

In the nuclear power stations of GDR the rough radioactive waste includes borat-containing evaporator bottoms and spent ion exchanger resins. For its final disposal in deep geological formations (rock salt mines) this waste has to be solidified. The experience of one year lasting operation of a steam heated thin-film evaporator (heating surface 2 m{sup 3}) for evaporator bottoms to be solidified with a solid content of 200-250 g/l are reported on. In short time such amount of water is abstracted from the rough waste that due to the borate content a hot high-viscous product passes from evaporator to waste drum and there solidifies like glass to monolith. The product quality depends on the adjustment of the flow-equilibrium in the evaporator. Boric acid is used as matrix for the radioactive residues. The residual water content of the solidified waste product was ...

1990-01-01

64

Operating experience with solidification of radioactive waste by a thin-film evaporator  

International Nuclear Information System (INIS)

In the nuclear power stations of GDR the rough radioactive waste includes borat-containing evaporator bottoms and spent ion exchanger resins. For its final disposal in deep geological formations (rock salt mines) this waste has to be solidified. The experience of one year lasting operation of a steam heated thin-film evaporator (heating surface 2 m"3) for evaporator bottoms to be solidified with a solid content of 200-250 g/l are reported on. In short time such amount of water is abstracted from the rough waste that due to the borate content a hot high-viscous product passes from evaporator to waste drum and there solidifies like glass to monolith. The product quality depends on the adjustment of the flow-equilibrium in the evaporator. Boric acid is used as matrix for the radioactive residues. The residual water content of the solidified waste product was about ...

1990-06-01

65

Development and pilot demonstration program of a waste minimization plan at Argonne National Laboratory  

Energy Technology Data Exchange (ETDEWEB)

In response to US Department of Energy directives, Argonne National Laboratory (ANL) has developed a waste minimization plan aimed at reducing the amount of wastes at this national research and development laboratory. Activities at ANL are primarily research- oriented and as such affect the amount and type of source reduction that can be achieved at this facility. The objective of ANL's waste minimization program is to cost-effectively reduce all types of wastes, including hazardous, mixed, radioactive, and nonhazardous wastes. The ANL Waste Minimization Plan uses a waste minimization audit as a systematic procedure to determine opportunities to reduce or eliminate waste. To facilitate these audits, a computerized bar-coding procedure is being implemented at ANL to track hazardous ...

1991-01-01

66

Interaction studies between Crofer-22APU alloy and P2O5 containing barium calcium alumino-borosilicate (BCABS) sealant glass-ceramics  

International Nuclear Information System (INIS)

We present the effect of P2O5 addition on barium calcium aluminum borosilicate BCABS glasses of composition (mol %) 35BaO-15CaO-5Al2O3-(37-x)SiO2-8B2O3-xP2O5 (0?x?5). The incorporation of P2O5 increased network polymerization and crystallization tendency. However, addition of P2O5 leads to the formation of Cr2O3 at the interface, saturating it in the ions of the metal. This improves glass-to-metal bonding. (author)

2010-09-01

67

Engineering and manufacture of oblong-shaped metallic melters for enhancing vitrification throughputs  

International Nuclear Information System (INIS)

Most countries have taken the vitrification route for managing High Level Waste (HLW). Depending on composition of site-specific HLW, suitable glass forming oxides are added to it in a melting furnace designed for converting the mixture to a matrix of borosilicate glass. After thorough homogenization, the product is poured into stainless steel canisters as an inert solidified form. Canisters are seal welded and 2-3 such containers are then packed and sealed in another bigger container for providing an additional engineered barrier. This product form is considered safe for long-term storage. The concurrent vitrification technologies employ either induction-heated metallic melters or joule-heated direct resistance-heated ceramic melters. In India, both technologies have been adopted. While older facilities in Trombay and Tarapur employ metallic melters, a retrofitted facility at Tarapur and the new plant at Kalpakkam are ...

68

Management of industrial solid wastes in Alexandria, Egypt  

Science.gov (United States)

This paper presents a summary of the first phase of the EPA project, which encompasses surveys of residues from industrial sources in Alexandria. Studies to date indicate that wastes from various industries can be recovered economically. Wastes such as tin cans, glass, wastepaper, and food residues from processing of fruits, starch, and beer are examples of reusable industrial wastes in Egypt. The results of experimental studies for reuse of residues from oil refining, starch and yeast processing, and steel pickling are presented. Spent clay from edible oil refining is currently discarded, causing both handling and disposal problems. This clay contains as much as 40% oil; 90% can be recovered by extraction. The recovered oil can be successfully used in soap production, and the spent clay can be reused in oil bleaching. Other examples include starch and yeast wastes, which can be ...

1983-03-01

69

Investigation of corrosion experienced in a spray calciner/ceramic melter vitrification system  

Energy Technology Data Exchange (ETDEWEB)

After periodic testing of a large-scale spray calciner/ceramic melter vitrification system over a 2-yr period, sufficient corrosion was noted on various parts of the vitrification system to warrant its disassembly and inspection. A majority of the 316 SS sintered metal filters on the spray calciner were damaged by chemical corrosion and/or high temperature oxidation. Inconel-601 portions of the melter lid were attacked by chlorides and sulfates which volatilized from the molten glass. The refractory blocks, making up the walls of the melter, were attacked by the waste glass. This attack was occurring when operating temperatures were >1200/sup 0/C. The melter floor was protected by a sludge layer and showed no corrosion. Corrosion to the Inconel-690 electrodes was minimal, and no corrosion was noted in the offgas treatment system downstream of the sintered metal filters. It is believed that most of the melter corrosion ...

1980-08-01

70

Exposure to nitroaromatic explosives and health effects during disposal of military waste  

UK PubMed Central (United Kingdom)

Aims: To investigate the exposure to dinitrotoluene (DNT) and trinitrotoluene (TNT) and the resulting effects in workers which occur during the disposal of military waste. Methods:...Full Text Available

2003-07-01

71

Cost-Effectiveness Analysis of Proposed Effluent Limitations Guidelines and Standards for the Centralized Waste Treatment Industry.  

Science.gov (United States)

This analysis, submitted in support of proposed effluent limitations guidelines and standards for the centralized waste treatment (CWT) industry, investigates the cost-effectiveness of 24 regulatory options, representing all possible combinations of nine ...

1995-01-01

72

Preliminary experience with the new Harwell inactive vitrification pilot plant  

International Nuclear Information System (INIS)

The decision of the United Kingdom to adopt a policy of solidification of high level waste had led to renewed interest in vitrification. The HARVEST process chosen is an adaptation of the FINGAL concept developed at Harwell 15 years ago. Because of certain changes in engineering design and differences in the composition of the waste, additional chemical engineering data are required for HARVEST. The new inactive pilot plant has been built to provide this information. Its size is virtually full-scale and batches of glass up to 1 tonne can be manufactured in vessels of diameter up to 750mm. Five glass-making runs have been carried out. Attention has concentrated on the performance of the off-gas system which employs wet methods. Carry-over of solids occurs, primarily as a result of physical entrainment. The carry-over of synthetic fission products is improved from 2.5 to 0.1% by directing the feed down ...

73

Model analysis of an inter-industrial and inter-regional waste recycling system in Japan  

Energy Technology Data Exchange (ETDEWEB)

In this study, we investigate an inter-industrial and inter-regional recycling system for industrial waste by the cement industry in Japan. We develop a linear programming model that represents cement production processes and waste transportation of all cement factories in Japan. We simulate cost and CO{sub 2}-minimizing systems. The result implies that making waste transportation more efficient in cost is an effective means for CO{sub 2} reduction. (author)

2007-04-15

74

ICPES analyses using full image spectra and astronomical data fitting algorithms to provide diagnostic and result information  

Energy Technology Data Exchange (ETDEWEB)

ICP emission analyses are prone to errors due to changes in power level, nebulization rate, plasma temperature, and sample matrix. As a result, accurate analyses of complex samples often require frequent bracketing with matrix matched standards. Information needed to track and correct the matrix errors is contained in the emission spectrum. But most commercial software packages use only the analyte line emission to determine concentrations. Changes in plasma temperature and the nebulization rate are reflected by changes in the hydrogen line widths, the oxygen emission, and neutral ion line ratios. Argon and off-line emissions provide a measure to correct the power level and the background scattering occurring in the polychromator. The authors` studies indicated that changes in the intensity of the Ar 404.4 nm line readily flag most matrix and plasma condition modifications. Carbon lines can be used to monitor the impact of organics on the analyses and calcium and argon lines can be ...

1997-10-01

75

Aqueous radioactive waste bituminization  

International Nuclear Information System (INIS)

The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container.

5049-01-01

76

Influence of the micro-addition of Mo on glass forming ability and corrosion resistance of Cu-based bulk metallic glasses  

International Nuclear Information System (INIS)

(Cu_4_7Zr_1_1Ti_3_4Ni_8)_1_0_0_-_xMo _x bulk metallic glasses (BMGs) with x = 0, 1 and 2 at.% and a bulk metallic glass matrix composite with x = 5 at.% were successfully prepared by water-cooled copper mold casting. The effect of the addition of a small amount of Mo on the glass forming ability (GFA), thermal properties of the base alloy (i.e. x = 0) were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and differential thermal analyzer (DTA). It is found that the addition of appropriate amount of Mo can enhance the GFA of the Cu-based BMG, as indicated by the increase in the reduced glass transition temperature T _r_g (=T _g/T _l) and the parameter #gamma# (=T _x/(T _g + T _l)) with the increase of Mo. On the other hand, the corrosion resistance of the Cu-based BMGs with different Mo contents was examined by electrochemical polarization and weight ...

2006-05-05

77

Preparation and evaluation of a novel glass-ionomer cement with antibacterial functions  

British Library Electronic Table of Contents (United Kingdom)

Objective.The objective of this study was to use the newly synthesized poly(quaternary ammonium salt) (PQAS)-containing polyacid to formulate the light-curable glass-ionomer cements and study the effect of the PQAS on the compressive strength and antibacterial activity of the formed cements.Materials and methods.The functional QAS and their constructed PQAS were synthesized, characterized and formulated into the experimental high-strength cements. Compressive strength (CS) and Streptococcus mutans viability were used to evaluate the mechanical strength and antibacterial activity of the cements. Fuji II LC cement was used as control. The specimens were conditioned in distilled water at 37 degrees C for 24 h prior to testing. The effects of the substitute chain length, loading as well as gra...

2011-01-01

78

Monitoring potential neurotoxic effects of hazardous waste disposal  

UK PubMed Central (United Kingdom)

This report reviews neurotoxicological principles relevant to situations of hazardous waste disposal. Some of the diagnostic techniques currently used for field assessment of nervous system dysfunction...Full Text Available

1983-02-01

79

Economic Impact Analysis of Proposed Effluent Limitations Guidelines and Standards for the Centralized Waste Treatment Industry.  

Science.gov (United States)

This report estimates the economic and financial effects of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts...

1995-01-01

80

EXECUTIVE SUMMARY  

Wastenet

disposal through HC, and the effects of kerbside collection (KC) of recyclable materials, by measuring ...waste equivalent to 12 % could be attributed to HC and KC.Comparisons between the residual weight data for ...Control showed that the contributions of HC and KC to the overall reduction in residual waste were

81

Dynamic stability and vibration monitoring for No. 9 mine, M-1 dump  

Energy Technology Data Exchange (ETDEWEB)

This study examines the effects of blasting on waste dumps at open pit mining operations. Of specific concern were mining operations at the base of a five hundred foot high waste dump such as the operation at the South Pit of the Smoky-River Coal Ltd. property near Grande Cache, Alberta. An assessment of waste dump stability including factors such as quasi-static deformation behaviour, historical dump deformation behaviours and potential blasting effects was undertaken. It is concluded that safe blasting may be carried out in proximity to waste dumps, but monitoring of dump behaviour is recommended to ensure operational safety. 22 refs., 4 apps.

1988-11-01

84

Estimation of animal and olive solid wastes in Jordan and their potential as a supplementary energy source: An overview  

Energy Technology Data Exchange (ETDEWEB)

Biomass is a potential source of energy that can reduce our dependency on oil as the main source of energy. In addition to municipal solid waste, animal and olive wastes are the main sources of organic waste in Jordan. In 2005, there were more than 2.4 million heads of sheep, about 72 thousand cows, and 40 million hens being raised in farms distributed in all governorates of Jordan. These animals produce 5.3 million tons (as exerted) of solid waste per year. If these quantities can be effectively collected they may constitute a valuable source of energy. This paper is aiming to estimate the amounts of animal and solid wastes generated in Jordan and their energy potential. The total amount of BOD from animal waste is estimated at 200,000 tons per year. Significant quantities of organic waste can also be collected from ...

2010-10-15

85

Low-Level waste phase 1 melter testing off gas and mass balance evaluation  

Energy Technology Data Exchange (ETDEWEB)

Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of Hanford Site tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor ...

1996-06-28

86

Turning the Moon into a Solar Photovoltaic Paradise  

Science.gov (United States)

Lunar resource utilization has focused principally on the extraction of oxygen from the lunar regolith. A number of schemes have been proposed for oxygen extraction from Ilmenite and Anorthite. Serendipitously, these schemes have as their by-products (or more directly as their "waste products"), materials needed for the fabrication of thin film silicon solar cells. Thus lunar surface possesses both the elemental components needed for the fabrication of silicon solar cells and a vacuum environment that allows for vacuum deposition of thin film solar cells directly on the surface of the Moon without the need for vacuum chambers. In support of the US space exploration initiative a new architecture for the production of thin film solar cells on directly on the lunar surface is proposed. The paper discusses experimental data on the fabrication and properties of lunar glass substrates, evaporated lunar regolith thin films (anti-reflect coatings and ...

2006-01-01

87

Kaiser ANIP Participation, 1954-1962  

Science.gov (United States)

... joined together by a thin ribbon of glass that is bent into a frame shape in a prior operacion. The three glass pieces are ...

1963-03-31

88

Use plan for demonstration radioactive-waste incinerator  

Energy Technology Data Exchange (ETDEWEB)

The University of Maryland at Baltimore was awarded a grant from the Department of Energy to test a specially modified incinerator to burn biomedical radioactive waste. In preparation for the incinerator, the Radiation Safety Office devised a comprehensive plan for its safe and effective use. The incinerator plan includes a discussion of regulations regarding on-site incineration of radioactive waste, plans for optimum use in burning four principal waste forms, controlled air incineration technology, and standard health physics safety practices; a use plan, including waste categorization and segregation, processing, and ash disposition; safety procedures, including personnel and area monitoring; and methods to evaluate the incinerator's effectiveness by estimating its volume reduction factors, mass and activity balances, and by determining the cost ...

1982-04-01

89

Heat and fluid flow during the formation of metallic glasses by splat cooling  

Science.gov (United States)

A model is presented for heat and fluid flow during hammer and anvil splat cooling. Predictions are made for the effects of superheat and hammer speed on splat thickness, cooling rate, and subsequent glass formation. The regime of Newtonian heat flow is extended well beyond the previously accepted limiting value of Nusselt number. Measurements of the structure, stability, and thickness of Fe{sub 80}B{sub 20} and Pd{sub 80}Si{sub 20} hammer and anvil splats qualitatively confirm the model prediction. Variations of superheat in shock tube splats produced similar trends to those observed in the hammer and anvil device. In an attempt to vary the equivalent of hammer speed in a shock tube device, an orifice producing a supersonic shock wave was utilized. Significant splat flake thickness reductions resulted as compared to subsonic orifices.

90

Growth and characterisation of electrodeposited ZnO thin films  

Energy Technology Data Exchange (ETDEWEB)

The electrochemical method has been used to deposit zinc oxide (ZnO) thin films from aqueous zinc nitrate solution at 80 deg. C onto fluorine doped tin oxide (FTO) coated glass substrates. ZnO thin films were grown between - 0.900 and - 1.025 V vs Ag/AgCl as established by voltammogram. Characterisation of ZnO films was carried out for both as-deposited and annealed films in order to study the effect of annealing. Structural analysis of the ZnO films was performed using X-ray diffraction, which showed polycrystalline films of hexagonal phase with (002) preferential orientation. Atomic force microscopy was used to study the surface morphology. Optical studies identified the bandgap to be {approx} 3.20 eV and refractive index to 2.35. The photoelectrochemical cell signal indicated that the films had n-type electrical conductivity and current-voltage measurements showed the glass/FTO/ZnO/Au devices exhibit rectifying ...

2008-04-30

91

Development of a high performance air heater through use of an evacuated tube cover design  

Science.gov (United States)

Development of a high performance air heater through use of an evacuated tube cover design is described. The cover design utilizes evacuated fluorescent light tubes laid parallel in a close packed array to form an inner transparent glazing over a conventional metal absorber plate with flow behind the plate. A tempered flat glass plate was used as an outer glazing. Both clear and infrared reflective (IR) tubes were investigated. Solar transmittance tests indicate that the clear tube array has a higher transmittance than two flat sheets of low-iron glass. The IR coating produced substantial transmittance loss. Thermal conductance tests indicate that the tubes behave similar to two flat glass sheets with a vacuum in between. The IR reflective coating was only marginally effective at reducing heat conductance. Final prototype designs are presented along with collector performance estimates.

1980-01-01

92

Nucleation and crystal growth of Li{sub 2}O{center_dot}2SiO{sub 2} in a microwave field  

Energy Technology Data Exchange (ETDEWEB)

A comparison of nucleation and crystallization of Li{sub 2}O{sm_bullet}2SiO{sub 2} between microwave and conventional heating was investigated. Standard stereological techniques were used to evaluate the results. Nucleation and crystallization behaviors during microwave heating appeared different from conventional heating. Work is in progress to better understand the effects of microwaves on nucleation and crystallization in glass.

1995-12-31

93

Influence of relaxation phenomena in liquid phase on magnetic anisotropy of metallic glasses  

International Nuclear Information System (INIS)

It if first shown, that the effective field of uniaxial magnetic anisotropy of Fe-Cr-P-C and Fe-Ni-B-Si system amorphous alloys is reduced with an increase of the source melt isothermal exposure time. The behaviour noted is conditioned by microcoherence and relaxation processes in the nonequilibrium liquid phase after crystal-liquid phase transition.

1996-12-01

94

Features of laser damage to elastic polymers  

Energy Technology Data Exchange (ETDEWEB)

Threshold pump intensity values leading to irreversible damage to colored laser elements based on elastic polymers were measured. The damage to colored elastomers is connected with absorbing microinclusions but is independent of molecular absorption. It is shown that damage to the elastomers has a pronounced threshold character in contrast to the microdamage accumulation effect in glassy polymers. The damage threshold for elastomers is 1.5 times higher, which is connected with the absence of microstresses (characteristics for organic glasses) in the specimens. 13 references.

1988-03-01

95

CRC handbook of laser science and technology. Volume 3. Optical materials, Part 1 - Nonlinear optical properties/radiation damage  

Energy Technology Data Exchange (ETDEWEB)

This book examines the nonlinear optical properties of laser materials. The physical radiation effects on laser materials are also considered. Topics considered include: nonlinear optical properties; nonlinear and harmonic generation materials; two-photon absorption; nonlinear refractive index; stimulated Raman scattering; radiation damage; crystals; and glasses.

1986-01-01

97

Strategic planning for waste management: Characterization of chemically and radioactively hazardous waste and treatment, storage, and disposal capabilities for diverse and varied multisite operations  

Energy Technology Data Exchange (ETDEWEB)

Information about current and projected waste generation as well as available treatment, storage, and disposal (TSD) capabilities and needs is crucial for effective, efficient, and safe waste management. This is especially true for large corporations that are responsible for multisite operations involving diverse and complex industrial processes. Such information is necessary not only for day-to-day operations, but also for strategic planning to ensure safe future performance. This paper reports on some methods developed and successfully applied to obtain requisite information and to assist waste management planning at the corporate level in a nationwide system of laboratories and industries. Waste generation and TSD capabilities at selected US Department of Energy (DOE) sites were studied. 1 ref., 2 tabs.

1988-01-01

98

Research and development for treatment and disposal technologies of TRU waste  

International Nuclear Information System (INIS)

After the publication of the 2nd progress report of geological disposal of TRU waste in Japan, policy and general scheme of future study for the waste disposal in Japan was published by ANRE and JAEA. This annual report summarized aim and progress of individual problem, which was assigned into JAEA in the published policy and general scheme. The problems are as follows; characteristics of TRU waste and its geologic disposal, treatment and waste production, quality control and inspection methodology for waste, mechanical analysis of near-field, data acquisition and preparation on radionuclides migration, cementitious material transition, bentonite and rock alteration in alkaline solution, nitrate effect, performance assessment of the disposal system and decomposition of nitrate as an alternative technology. (author)

2007-04-22

99

Improvement on Liquid Radioactive Waste Treatment System of Nuclear Power Plant By Applying Ion Exchange Method  

International Nuclear Information System (INIS)

Liquid radioactive waste treatment method of using evaporator was widely used from Kori 1 to Uljin 3 and 4, but a liquid radioactive waste treatment equipment that uses an ion exchange method instead of an evaporator was adopted aiming to minimize amount of radioactive waste and radiation exposure. However, the same equipment was introduced and applied for the first time in Korea and had experienced difficulties in securing credibility for the equipment and handling of liquid radioactive waste with inadequate data about performance and experience in operation and maintenance. In this study, examination, application and effect analysis was performed on the optimization measure for handling liquid radioactive waste of Yonggwang Nuclear Power Unit 5 and 6(YGN 5 and 6) that applies an ion exchange method

2010-10-01

100

Deployment Scenarios for Nuclear Waste Management  

International Nuclear Information System (INIS)

A major objective of the DOE Advanced Fuel Cycle Initiative, AFCI, is to explore technologies that may reduce the long-term environmental burden of nuclear energy through more efficient disposal of waste materials. In this work, the potential impact of the AFCI technology and its beneficial effects on waste management and its ability to meet waste management objectives are demonstrated. In addition, practical scenarios to improve permanent disposal utilization and/or reduce the temporary spent nuclear fuel (SNF) storage inventory by closing the fuel cycle through transition to fast reactor (FR) converters are also discussed. (authors)

101

Applications of polymeric smart materials to environmental problems.  

UK PubMed Central (United Kingdom)

New methods for the reduction and remediation of hazardous wastes like carcinogenic organic solvents, toxic materials, and nuclear contamination are vital to environmental health. Procedures for effective...Full Text Available

1997-02-01

102

Methodology for assessing performance of waste management systems  

Energy Technology Data Exchange (ETDEWEB)

The purpose of the methodology provided in this report is to select the optimal way to manage particular sets of waste streams from generation to disposal in a safe and cost-effective manner. The methodology described is designed to review the entire waste management system, assess its performance, ensure that the performance objectives are met, compare different LLW management alternatives, and select the optimal alternative. The methodology is based on decision analysis approach, in which costs and risk are considered for various LLW management alternatives, a comparison of costs, risks, and benefits is made, and an optimal system is selected which minimizes costs and risks and maximizes benefits. A ''zoom-lens'' approach is suggested, i.e., one begins by looking at gross features and gradually proceeds to more and more detail. Performance assessment requires certain information about ...

1988-01-01

103

Logistics modeling of future solid waste storage, treatment, and disposal  

Energy Technology Data Exchange (ETDEWEB)

Logistics modeling is a powerful analytical technique for effective planning of waste storage, treatment, and disposal activities. Logistics modeling facilitates analyses of alternate scenarios for future waste flows, facility schedules, and processing or handling capacities. These analyses provide an increased understanding of the specific needs for waste storage, treatment, and disposal while adequate time remains to plan accordingly. They also help to determine the sensitivity of these needs to various system parameters. This paper discusses a logistics modeling system developed by the Pacific Northwest Laboratory (PNL) to aid in solid waste planning for a large industrial complex managing many different types and classifications of waste. The basic needs for such a system are outlined, and the approach adopted in developing the system is described. A key ...

1993-11-01

104
105

Municipal solid waste management in Lebanon: the need for an integrated approach  

International Nuclear Information System (INIS)

Full text.This study focuses on the management of municipal solid waste (MSW) in Lebanon. It addresses the current status of MSW management in Lebanon in terms of collection, transport and disposal, infers the associated impacts of such practices and discusses mitigation measures and finally proposes basic guidelines for a national strategy for solid waste management in the country. The study is based on available previous investigations and on a field survey of 113 villages in four different countries. The study revealed the absence of an effective environmental policy and poor collection and disposal methods throughout the country, except for the Greater Beirut Area (G A), where better solid waste management practices are employed. Although collection of MSW outside GBA was found to be acceptable by local authorities, resources (labor and equipment) were not used efficiently. Furthermore, treatment of ...

2000-11-23

106

A survey of monitoring and assay systems for release of metals from radiation controlled areas at LANL.  

Energy Technology Data Exchange (ETDEWEB)

At Los Alamos National Laboratory (LANL), a recent effort in waste minimization has focused on scrap metal from radiological controlled areas (RCAs). In particular, scrap metal from RCAs needs to be dispositioned in a reasonable and cost effective manner. Recycling of DOE scrap metals from RCAs is currently under a self-imposed moratorium. Since recycling is not available and reuse is difficult, often metal waste from RCAs, which could otherwise be recycled, is disposed of as low-level waste. Estimates at LANL put the cost of low-level waste disposal at $550 to $4000 per cubic meter, depending on the type of waste and the disposal site. If the waste is mixed, the cost for treatment and disposal can be as high as $50,000 per cubic meter. Disposal of scrap metal as low-level waste uses up valuable space in the low-level ...

2002-01-01

107

Hanford low-level waste process chemistry testing data package  

Science.gov (United States)

Recently, the Tri-Party Agreement (TPA) among the State of Washington Department of Ecology, U.S. Department of Energy (DOE) and the US Environmental Protection Agency (EPA) for the cleanup of the Hanford Site was renegotiated. The revised agreement specifies vitrification as the encapsulation technology for low level waste (LLW). A demonstration, testing, and evaluation program underway at Westinghouse Hanford Company to identify the best overall melter-system technology available for vitrification of Hanford Site LLW to meet the TPA milestones. Phase I is a {open_quotes}proof of principle{close_quotes} test to demonstrate that a melter system can process a simulated highly alkaline, high nitrate/nitrite content aqueous LLW feed into a glass product of consistent quality. Seven melter vendors were selected for the Phase I evaluation: joule-heated melters from GTS Duratek, Incorporated (GDI); Envitco, Incorporated (EVI); Penberthy Electomelt, ...

1996-03-01

108

Effect of chloride concentration and pH on pitting corrosion of waste package container materials  

Energy Technology Data Exchange (ETDEWEB)

Electrochemical cyclic potentiodynamic polarization experiments were performed on several candidate waste package container materials to evaluate their susceptibility to pitting corrosion at 90 degrees C in aqueous environments relevant to the potential underground high-level nuclear waste repository. Results indicate that of all the materials tested, Alloy C-22 and Ti Grade-12 exhibited the maximum corrosion resistance, showing no pitting or observable corrosion in any environment tested. Efforts were also made to study the effect of chloride ion concentration and pH on the measured corrosion potential (Ecorr), critical pitting and protection potential values.

1996-12-01

109

Eulerian approach for multiphase flow simulation in a glass melter  

Energy Technology Data Exchange (ETDEWEB)

A glass furnace, consisting of a combustion space and a glass melter, uses combustion heat to melt sand and cullet into liquid glass to make products. Glass quality is mainly dependent on the temperature, glass composition, and the level of impurities in a glass melter, which include solid batch/cullet particles, liquid glass, and gas bubbles. A comprehensive computational model using an Eulerian approach has been developed to simulate multiphase flows in a glass melter. It includes all the phases, divides solid particles or gas bubbles into various size groups, and treats each group as a continuum. The derived mass, momentum, and energy conservation equations of the flow are solved for local properties for each phase. The simulation considers the heating and melting of the batch (mainly from the radiative heat from ...

2005-12-01

110

Eulerian approach for multiphase flow simulation in a glass melter  

International Nuclear Information System (INIS)

A glass furnace, consisting of a combustion space and a glass melter, uses combustion heat to melt sand and cullet into liquid glass to make products. Glass quality is mainly dependent on the temperature, glass composition, and the level of impurities in a glass melter, which include solid batch/cullet particles, liquid glass, and gas bubbles. A comprehensive computational model using an Eulerian approach has been developed to simulate multiphase flows in a glass melter. It includes all the phases, divides solid particles or gas bubbles into various size groups, and treats each group as a continuum. The derived mass, momentum, and energy conservation equations of the flow are solved for local properties for each phase. The simulation considers the heating and melting of the batch (mainly from the radiative heat from ...

2005-12-01

111

Survey of systems safety analysis methods and their application to nuclear waste management systems  

Energy Technology Data Exchange (ETDEWEB)

This report reviews system safety analysis methods and examines their application to nuclear waste management systems. The safety analysis methods examined include expert opinion, maximum credible accident approach, design basis accidents approach, hazard indices, preliminary hazards analysis, failure modes and effects analysis, fault trees, event trees, cause-consequence diagrams, G0 methodology, Markov modeling, and a general category of consequence analysis models. Previous and ongoing studies on the safety of waste management systems are discussed along with their limitations and potential improvements. The major safety methods and waste management safety related studies are surveyed. This survey provides information on what safety methods are available, what waste management safety areas have been analyzed, and what are potential areas for future study.

1981-11-01

112

Off-gas behavior in the Harvest pot vitrification process  

Energy Technology Data Exchange (ETDEWEB)

The conversion of highly radioactive waste liquor into glass by the pot vitrification process has been studied at Harwell using a full-scale inactive pilot plant. A summary of the off-gas behavior and its interpretation is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) processes involving the volatile species. Entrainment was ...

1983-06-01

113

CHEMICAL TECHNOLOGY DIVISION, UNIT OPERATIONS SECTION MONTHLY PROGRESS REPORT, JULY 1960  

Science.gov (United States)

A critical review of the literature revealed no experiments on uranyl ion transfer from an aqueous to a tributyl phosphate phase which positively measured the kinetics of the chemical reaction at the interphase. Drawing isorhythmic lines on a three component diagram gives a complex correlation for the compaction of three sizes of glass beads. Neither the use of thoria sols nor high feed solution concentrations of thorium nitrate gave any significant increase in mean particle diameters over those obtained from nitrate solutions of lower concentrations in flame denitration. A hydraulic film resistance has been detected in the anion exchange of uranyl sulfate into Dowex 2lK, and chloride elution was found to give a higher apparent uranium diffusion coefficient than nitrate elution. The rate of dissolution of mixed thorium-uranium oxides was determined as a function of the per cent of mixed oxides dissolved. Mixing in tanks packed with ...

1960-10-27

114

Isotopic effects on solubility-limited mass transfer  

Energy Technology Data Exchange (ETDEWEB)

In our previous theoretical analyses, solubility-limited mass transfer from waste solids applies if a species is at a constant elemental concentration in liquid at the waste surface. For an element with isotopes that decay appreciably during the time of interest, a solubility boundary condition results in a time-dependent boundary concentration of each isotope. Here we present mass-transfer equations that include the effects of isotopic decay boundary conditions. 9 refs., 1 fig.

1989-06-01

115

Effect of environmental variables on localized corrosion of high-performance container materials  

Energy Technology Data Exchange (ETDEWEB)

Electrochemical cyclic potentiodynamic polarization (CPP) experiments were performed on several candidate high-performance waste package container materials to evaluate their susceptibility to localized corrosion in aqueous environments relevant to the potential underground high-level nuclear waste repository. This paper presents the results of this study showing the effects of chloride ion (Cl) concentrations, pH, temperature, and electrochemical potential scan rate on the pitting corrosion behavior of these materials.

1997-01-01

116

Treatment for dismantled radioactive solid waste from the TRIGA Mark-2 and 3  

Energy Technology Data Exchange (ETDEWEB)

Radioactive wastes are generally classified into 3 type depending on their physical property: liquid, solid and gaseous type. State-of -the art concerning liquid waste treatment has already been published; KAERI/TR-1315/99. Solid wastes classification package and treatment method will be studied to effectively manage them during the practical decommissioning work. All of the spent fuel produced during the operation of the TRIGA Mark-2 and 3 have been transported to the US last year, 1998, according to the spent fuel management strategy set-up by the US government for the non-proliferation of nuclear energy. Solid wastes are mainly all equipment existing inside of the reactors, activated concrete among the bio-shielded concrete, pipes, pimps, resin filter and it's housings, heat-exchangers, liquid waste storage tanks, to radioactive ...

1999-06-01

117

Effect of Length of Time before Incorporation on Survival of Pathogenic Bacteria Present in Livestock Wastes Applied to Agricultural Soil  

UK PubMed Central (United Kingdom)

In response to reports that the contamination of food can occur during the on-farm primary phase of food production, we report data that describes a possible cost-effective intervention measure. The...Full Text Available

2004-09-01

118

Plastic wastes, lube oils and carbochemical products as secondary feedstocks for blast-furnace coke production  

British Library Electronic Table of Contents (United Kingdom)

Two plastic wastes (polyolefin-enriched and multicomponent), two lube oils (paraffinic and synthetic) and one coal-tar were assessed as individual and combined additives to coal blends for the production of blast furnace coke. The effects of adding 2wt.% of these additives or their mixtures (50:50 w/w) on the coking capacity of coal, coking pressure and coke quality parameters were investigated. It was found that the two plastic wastes reduce fluidity, whereas the addition of oils and tar helps to partially restore the fluidity of the coal-plastic blend. From the co-carbonization of the coking blend with the different wastes in a movable wall oven of over 15kg capacity, it was deduced that polyolefins have a detrimental effect on coking pressure. The addition of oils and tar to the coal-pl...

2011-01-01

119

Economic analysis of effluent limitation guidelines and standards for the centralized waste treatment industry  

Science.gov (United States)

This report estimates the economic and financial effects and the benefits of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts in terms of changes in the profitability of waste treatment operations at CWT facilities, changes in market prices to CWT services, and changes in the quantities of waste management at CWT facilities in six geographic regions. EPA has also examined the impacts on companies owning CWT facilities (including impacts on small entities), on communities in which CWT facilities are located, and on environmental justice. EPA examined the benefits to society of the CWT effluent limitations guidelines and standards by examining cancer and non-cancer health effects of the regulation, recreational benefits, and cost savings to ...

1998-12-01

120

The review of radioactive waste management in the world  

International Nuclear Information System (INIS)

Radioactive waste is generally classified on the basis of how much radiation and the type of radiation it emits as well as the length of time over which it will continue to emit radiation. Many activities dealing with radioactive materials produce nuclear wastes, including civilian nuclear power programs (nuclear Power plant operations and nuclear fuel-cycle activities), defense nuclear programs (nuclear weapons production, naval nuclear reactor programs, and related R and D), and industrial and institutional activities (scientific research, medical operations, and other industrial uses of Radioisotopic sources or Radio chemicals). To minimize the potential adverse health and environment impacts to people and other systems including of animals, plant and etc, during the entire lifetime of the radionuclides involved, nuclear waste must be carefully and properly managed. The scope of nuclear - waste ...

121

Enhanced sludge washing evaluation plan  

Energy Technology Data Exchange (ETDEWEB)

The Tank Waste Remediation System (TWRS) Program mission is to store, treat, and immobilize highly radioactive Hanford Site waste (current and future tank waste and the strontium/cesium capsules) in an environmentally sound, safe, and cost-effective manner. The scope of the TWRS Waste Pretreatment Program is to treat tank waste and separate that waste into HLW and LLW fractions and provide additional treatment as required to feed LLW and HLW immobilization facilities. Enhanced sludge washing was chosen as the baseline process for separating Hanford tank waste sludge. Section 1.0 briefly discusses the purpose of the evaluation plan and provides the background that led to the choice of enhanced sludge washing as the baseline process. Section 2.0 provides a brief summary of the evaluation plan details. Section 3.0 ...

1994-09-01

122

Mo microalloying effect on the glass-forming ability, magnetic, mechanical and corrosion properties of (Fe0.76Si0.096B0.084P0.06)100-xMox bulk glassy alloys  

British Library Electronic Table of Contents (United Kingdom)

The effect of Mo addition on the glass-forming ability (GFA), magnetic properties, mechanical properties and corrosion resistance of (Fe0.76Si0.096B0.084P0.06)100-xMox (x=0, 2, 4 and 6at.%) bulk glassy alloys (BGAs) with high Fe contents was investigated. The 2at.% Mo addition makes the alloy composition approach towards a eutectic point, which could result in an increase in the GFA. The BGA rod with diameters up to 3.5mm was produced by copper mold casting. These BGAs exhibit a rather high saturation magnetization of 0.98-1.51T and lower coercive force of 1.7-2.1A/m. A significant improvement in corrosion resistance was observed with microalloying Mo element in 1N H2SO4 solution. Furthermore, these Fe-based BGAs show super-high strength of ~3.3GPa and Young's modulus of 200GPa.

2011-01-01

123

Immobilization of chloride-rich radioactive wastes produced by pyrochemical operations  

Energy Technology Data Exchange (ETDEWEB)

A a result of its former role as a producer of nuclear weapons components, the Rocky Flats Environmental Technology Site (RFETS), Golden, Colorado accumulated a variety of plutonium-contaminated materials. When the level of contamination exceeded a predetermined level (the economic discard limit), the materials were classified as residues rather than waste and were stored for later recovery of the plutonium. Although large quantities of residues were processed, others, primarily those more difficult to process, remain in storage at the site. It is planned for the residues with lower concentrations of plutonium to be disposed of as wastes at an appropriate disposal facility, probably the Waste Isolation Pilot Plant (WIPP). Because the plutonium concentration is too high or because the physical or chemical form would be difficult to get into a form acceptable to WIPP, it may not be possible to dispose of a portion of the ...

1997-08-01

124

Properties and morphology of PMMA/ABN blends obtained via MMA in situ polymerisation through {gamma}-rays  

Energy Technology Data Exchange (ETDEWEB)

Methylmethacrylate polymerisation in the presence of 4 wt% butadiene-acrylonitrile rubber was carried out at fixed dose-rate and temperature. The effect of irradiation was investigated with respect to the mechanical and dynamic-mechanical properties in the solid state. A general increase of the 'compatibilisation' on irradiation is obtained. In fact both rubber and polymethylmethacrylate glass transition temperatures, determined through dynamic-mechanical analysis, reveal the presence of strong interactions between the components. Furthermore an improvement of the mechanical tensile properties of the blends is observed when irradiation is continued after polymerisation, at least until a certain absorbed dose.

2001-12-01

125

Long-term monitoring of microleakage of dental cements by radiochemical diffusion  

International Nuclear Information System (INIS)

Radioactive "1"4C sucrose was found to be an ideal marker for microleakage because it did not penetrate tooth tissue, dental cement, or mounting resin. The main finding is that the adhesive cements--the glass-ionomer and polycarboxylate--are significantly more effective at preventing microleakage than are the traditional phosphate cements--silicate and zinc phosphate. The differences can be as high as two orders of magnitude. The adhesive cements provide almost perfect and reliable seals. By contrast, the nonadhesive cements are erratic sealants with most of the restorations leaking.

126

Brittle fracture problem in composite insulators  

Energy Technology Data Exchange (ETDEWEB)

The report traces the documented incidences of brittle fracture in composite suspension insulators for use on high voltage transmission lines, and presents the subsequent investigations. It describes the part played by electrical activity, stress corrosion and humidity, and compares similar failures that have taken place in electric traction insulators. It then goes on to review related work on the humidity effects, stress corrosion, fatigue and partial discharges in glass fiber reinforced plastics in general. The final section summarizes the present understanding of the problem and the various measures taken by different manufactures to avoid it in the future. The need for acceptance criteria in this respect is outlined.

1984-04-01

127

Unrestricted disposal of minimal activity levels of radioactive wastes: exposure and risk calculations  

Energy Technology Data Exchange (ETDEWEB)

The US Nuclear Regulatory Commission is currently considering revision of rule 10 CFR Part 20, which covers disposal of solid wastes containing minimal radioactivity. In support of these revised rules, we have evaluated the consequences of disposing of four waste streams at four types of disposal areas located in three different geographic regions. Consequences are expressed in terms of human exposures and associated health effects. Each geographic region has its own climate and geology. Example waste streams, waste disposal methods, and geographic regions chosen for this study are clearly specified. Monetary consequences of minimal activity waste disposal are briefly discussed. The PRESTO methodology was used to evaluate radionuclide transport and health effects. This methodology was developed to assess radiological impacts to a static ...

1984-08-01

128

Stickiness to Glass  

UK PubMed Central (United Kingdom)

Conditions were found in which Chlamydomonas reinhardi exhibits a circadian alteration of its cell surface, measured as ability to stick to glass. Under these same conditions the cells...Full Text Available

1979-06-01

129

Ergonomics: The Study of Work  

Science.gov (United States)

... Problem: At a glass ceramic cooktop plant, workers manually lift uncut plates of glass onto a waist-high conveyor belt, where it is then stacked ...

2011-05-13

130

2007 SB14 Source Reduction Plan/Report  

Energy Technology Data Exchange (ETDEWEB)

Aqueous solutions (mixed waste) generated from various LLNL operations, such as debris washing, sample preparation and analysis, and equipment maintenance and cleanout, were combined for storage in the B695 tank farm. Prior to combination the individual waste streams had different codes depending on the particular generating process and waste characteristics. The largest streams were CWC 132, 791, 134, 792. Several smaller waste streams were also included. This combined waste stream was treated at LLNL's waste treatment facility using a vacuum filtration and cool vapor evaporation process in preparation for discharge to sanitary sewer. Prior to discharge, the treated waste stream was sampled and the results were reviewed by LLNL's water monitoring specialists. The treated solution was discharged following confirmation that ...

2007-07-24

131

The Waste Isolation Pilot Plant: A Success Story with International Cooperation  

Energy Technology Data Exchange (ETDEWEB)

The U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) administers and operates the Waste Isolation Pilot Plant (WIPP) site, which hosts a deep geologic repository for safe disposal of U.S. defense-related TRU waste and is located 42 kilometers (km) east of Carlsbad, New Mexico. CBFO also manages the National Transuranic Waste Program (NTP), which oversees TRU waste management from generation to disposal. The WIPP began receiving waste in March 1999. In some areas of broad international interest, the CBFO has developed a leading expertise through its 25-year WIPP repository and TRU waste characterization activities. In addition to participating in relevant and beneficial experiments, the CBFO will provide the international community convenient access to this information by sponsoring and hosting symposia and workshops on relevant topics and by ...

2002-02-26

132

Corrosion studies of carbon steel under impinging jets of simulated slurries of neutralized current acid waste (NCAW) and neutralized cladding removal waste (NCRW)  

Energy Technology Data Exchange (ETDEWEB)

Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank's structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries ...

1992-01-01

133

Corrosion studies of carbon steel under impinging jets of simulated slurries of neutralized current acid waste (NCAW) and neutralized cladding removal waste (NCRW)  

Energy Technology Data Exchange (ETDEWEB)

Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank`s structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the ...

1992-01-01

134

The development of automatic surface dose-rate measuring and recording system for radioactive waste drum  

International Nuclear Information System (INIS)

The system which is performed the transportation and measurement of drum automatically to measure the surface dose-rate of radioactive waste drum and can inspect place of contaminated sources and precise dose-rate within a drum according to measuring many places equally at the same time has been developed. It is expected that the system be used to minimized radiation exposure of workers and manage the drum effectively according to established at the production facilities as well as the radioactive waste treatment facilities. (author). 7 refs., 9 tabs., 16 figs.

135

Study on the use of zirconium phosphate for radioactive waste treatment  

International Nuclear Information System (INIS)

Zirconium phosphate was one of the earliest inorganic ion-exchange suggested for removing strontium and cesium from aqueous nuclear waste. This paper studied ionic exchange to remove Cs-137 and Sr-90 by using different cationic of zirconium phosphate. In this case the parameters studied were the effect of temperature and ion concentration to percent up take and distribution coefficients. It is also conducted the study on column experiments to determine the breakthrough curves for Cs-137 and Sr-90. The result showed the potential of use of zirconium phosphate in radioactive waste treatment. (author)

1998-12-01

136

Physical aspects of FGD by-products  

Energy Technology Data Exchange (ETDEWEB)

Air pollution constraints continue to intensify, resulting in solid waste volume increases. An example of this is coal burning power plant flue gas desulfurization by scrubbing. The aqueous suspensions of calcium sulfate hemihydrate or calcium sulfate dihydrate will exceed 200 million tons annually by the year 2000. Disposal of these wastes can have massive environmental effects, due to physical instability and leaching to groundwater. One alternate disposal technique is sulfopozzolanic fixation, converting the FGD waste by addition of fine coal ash and an alkaline earth additive, into a monolithic mass. 6 refs., 17 figs., 3 tabs.

1992-01-01

137

Partitioning and transmutation of nuclear waste: the Dutch RAS programme and its relation to international studies  

Energy Technology Data Exchange (ETDEWEB)

In the present paper a review of the Dutch RAS programme is presented. The objectives and achievements of the programme are described. Special attention is given to a recent assessment of the international status of P and T that has been made for the Dutch authorities. The major conclusion of this assessment is that P and T is an important instrument in the management of nuclear waste to achieve the technical limits (ALARA) with respect to radiotoxicity of the waste inventory as well as radiological effects of the disposal. The technology for P and T is, however, only partially available at present and recommendations for the directions of the RAS programme are given. (orig.).

1996-08-01

138

PRESTO-PREP: a data preprocessor for the PRESTO-II code  

Energy Technology Data Exchange (ETDEWEB)

PRESTO-II is a computer code developed to evaluate possible health effects from shallow land disposal of low level radioactive wastes. PRESTO-PREP is a data preprocessor that has been developed to expedite the formation of input data sets for PRESTO-II. PRESTO-PREP utilizes a library of nuclide and risk-specific data. Given an initial waste inventory, the code creates the radionuclide portion of the associated input data set for PRESTO-II. 2 references.

1984-07-01

139

Economic analysis of cogeneration. January 1976-December 1980 (citations from the Energy Data Base). Report for January 1976-December 1980  

Energy Technology Data Exchange (ETDEWEB)

This retrospective bibliography contains citations concerning economic analysis of the techniques and technology for cogeneration and the effects of government policies and industrial attitudes toward cogeneration. Combined energy systems and combined manufacturing/energy systems which utilize waste heat and waste products as well as traditional fuels are included. (Contains 71 citations, fully indexed and including a table of contents.)

1980-12-01

140

EFFECTIVE CONTROL OF SECONDARY WATER POLLUTION FROM FLUE GAS DESULFURIZATION SYSTEMS  

Science.gov (United States)

The report describes tests to demonstrate the feasibility of using a vertical-tube, falling-film, vapor-compression evaporator to concentrate waste water from a flue gas desulfurization (FGD) process. Tests showed that waste water from the Chiyoda FGD process can be concentrated ...

141

Cold regions hydrology and hydraulics  

Energy Technology Data Exchange (ETDEWEB)

This monograph addresses a narrow aspect of cold regions engineering, namely the effects of cold weather on the traditional civil engineering disciplines of hydrology and hydraulics. Hydrologic and hydraulic considerations in the design, construction, and operation of civil works are very important. Many of the problems encountered in the design and construction of buildings, transportation systems, water supply facilities, waste treatment facilities, and hazardous waste disposal facilities, for example are closely tied to the characteristics of the site hydrology.

1990-01-01

142

An initial survey of nuclear material safeguards requirements applicable to the civilian waste management program  

Science.gov (United States)

This report provides an initial survey of the domestic and international safeguards requirements and provides a general framework on which future studies may be based. Additional studies are needed to evaluate the activities required to implement effective safeguards within the civilian waste management system and to ensure compliance with all safeguards requirements. 16 refs.

143

CuBr blue light emitting electroluminescent thin film devices  

British Library Electronic Table of Contents (United Kingdom)

Abstract Visible blue cathodoluminescence (CL), photoluminescence (PL), x-ray excited optical luminescence (XEOL) and electroluminescence (EL) via Zf free excitonic emission have been obtained from CuBr thin films deposited on glass, Cr coated glass, GaAs and Si substrates. In addition to the Zf emission several peaks corresponding to Cu+ emissions via 3d94s - d10 transitions were observed on the AC EL spectrum at 2.10, 2.7, 3.03, 3.07 and 3.80 eV. X-ray diffraction (XRD) measurements confirmed that the vacuum evaporated CuBr thin films grow preferentially with a (111) orientation irrespective of the substrate. While the AC voltage source was found to have no detrimental effects on CuBr thin films, cathodic deposition of Cu metal via electrolytic decomposition was observed under steady sta...

2011-01-01

144

A water calorimeter for high energy x-rays and electrons  

CERN Document Server

The current primary standards at NPL for the measurement of absorbed dose to water in high energy photon and electron beams are graphite calorimeters. However, the quantity of interest in radiation dosimetry is absorbed dose to water. Therefore, a new absorbed dose to water standard based on water calorimetry has been developed for use in high energy photon and electron beams. The calorimeter operates at 4 deg C, with temperature control being provided by liquid cooling. The sealed glass inner vessel of the calorimeter was designed to minimise the effect of non-water materials on the measurement of absorbed dose. The temperature sensing thermistor probes were designed and constructed so that glass is the only material in contact with high purity water inside the vessel. Initial measurements of absorbed dose to water made in 6, 10, and 19 MV photons, and 16 MeV electrons agreed, within the measurement uncertainties of ...

2000-01-01

145

Evaluation of a novel radiopacifiying agent on the physical properties of surgical spineplex.  

Science.gov (United States)

Polymethlylmethacrylate (PMMA) is the most frequently used cement for percutaneous vertebroplasty and kyphoplasty. To aid visualisation during surgery cements are doped with radiopacifying agents such as Barium sulphate (Ba(2)SO(4)) or Zirconium Dioxide (ZiO(2)). Mounting research suggests that these agents may impair the biocompatibility of the cements. However, incorporating an alternative radiopacifier agent with excellent biocompatibility would be a significant step forward. Bioactive radiopaque glasses incorporating elements such as strontium (Sr) and zinc (Zn), known to have beneficial and therapeutic effects on bone, are of great interest in this respect. In this study, the Ba(2)SO(4) of the commercially available Spineplex was incrementally replaced with a radiopaque therapeutic glass composition. The resulting effects on cement setting time, peak isotherm, ultimate compressive strength, Young's ...

2009-08-18

146

Waste minimization in a non-production oriented metal finishing operation  

Energy Technology Data Exchange (ETDEWEB)

This paper provides information on activities undertaken in a non- production oriented metal finishing operation to minimize waste and conserve resources. The facility is a 6000 sq foot shop that typically only deals with prototype parts. Utilizing a plan that includes employee awareness, common sense and existing technology, a noticeable reduction in waste volume has been obtained. Initiatives that are covered include: segregation of cyanide plating solutions, elimination of copper cyanide plating, elimination of hexavalent chromium plating, elimination of vapor degreasing, changing of rinsing practices, and changing a process for cleaning of aluminum parts. Some discussion is also presented on the effectiveness of combining the technologies of physical vapor deposition and electrodeposition to help minimize waste. Plans for additional initiatives including water recycling, elimination of cyanide ...

1991-11-01

147

Using value engineering to facilitate PWAs  

Energy Technology Data Exchange (ETDEWEB)

Value Engineering (VE) is a problem solving methodology that has been used in manufacturing and construction industries for fifty years to improve products, systems and projects while reducing unnecessary cost. A Process Waste Assessment (PWA) is a newly developed methodology designed to characterize waste streams and identify opportunities to reduce or eliminate waste generation. The VE and PWA methodologies are compared to show their general similarities and specific differences, and to suggest how VE can be woven into the PWA methodology. Further, the roles of the VE and PWA team leaders and their training are compared; suggestions are made to help enable the PWA team leader to more effectively lead a group-centered creative process. Examples of how VE has been used in hazardous and radioactive waste minimization and pollution prevention projects are presented, also.

1993-03-19

148

Requirement of decontamination factor for near-surface disposal of PEACER wastes  

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, TRU DF and LLFP removal efficiency have to be achieved more than 1.0E+04 - 1.0E+05 and 96%, respectively. (author)

2005-10-09

149

Inhibiting pitting corrosion in carbon steel exposed to dilute radioactive waste slurries  

Energy Technology Data Exchange (ETDEWEB)

Dilute caustic high-level radioactive waste slurries can induce pitting corrosion in carbon steel. Cyclic potentiodynamic polarization tests were conducted in simulated and actual waste solutions to determine minimum concentrations of sodium nitrate which inhibit pitting in ASTM A537 class 1 steel exposed to these solutions. Susceptibility to pitting was assessed through microscopic inspection of specimens and inspection of polarization scans. Long-term coupon immersion tests were conducted to verify the nitrite concentrations established by the cyclic potentiodynamic polarization tests. The minimum effective nitrite concentration is expressed as a function of the waste nitrate concentration and temperature.

1991-01-01

150

Damage process and luminescent characteristics in silica glasses under ion irradiation  

International Nuclear Information System (INIS)

Full text of publication follows: Understanding the dynamic irradiation effects on silica glasses is important for developing the diagnostic systems used in fusion and fission environments. While fundamental defects having an un-pared electron such as the E' center have been extensively studied, the neutral oxygen deficiency defects have been insufficiently clarified for lack of the detection methods. The ion induced luminescence is one of the probes that can be used to detect non-paramagnetic defects, and to observe creation and annihilation behavior dynamically. In the present study, we examined the characteristics of the ion induced luminescence such as energy, fluence flux and temperature dependence of the luminescence efficiency to analyze damage process quantitatively. Samples of SiO2 glasses were commercially available fused and synthesized silica glasses, produced by Toshiba Ceramics, Co. Ltd.. ...

2007-12-10

151

Low-activity waste envelope definitions for the TWRS Privatization Phase I Request For Proposal  

Energy Technology Data Exchange (ETDEWEB)

Radioactive waste has been stored in large underground storage tanks at the Hanford Site since 1944. Approximately 212 million liters of waste containing approximately 240,000 metric tons of processed chemicals and 177 mega-curies of radionuclides are now stored in 177 tanks. These caustic wastes are in the form of liquids, slurries, saltcakes, and sludge. In 1991, the Tank Waste Remediation System (TWRS) Program was established to manage, retrieve, treat, immobilize, and dispose of these wastes in a safe, environmentally sound, and cost-effective manner. The Department of Energy (DOE) has believes that it is feasible to privatize portions of the TWRS Program. Under the privatization strategy embodied in the Request for Proposal (RFP), DOE will purchase services from a contractor-owned, contractor-operated facility under a fixed-price contract. Phase I of the ...

1996-11-01

152

The Principles of Radioactive Waste Management  

CERN Document Server

The Principles of Radioactive Waste Management

1995-01-01

153

Establishing a nationalsystem for radioactive waste management  

CERN Document Server

Establishing a nationalsystem for radioactive waste management

1995-01-01

154

Annual report on monitoring of the unsaturated zone and recharge areas at INEL to the state of Idaho INEL Oversight Committee  

Energy Technology Data Exchange (ETDEWEB)

During the early years of the INEL, the USGS conducted extensive studies (sitewide drilling program) of the geology and hydrology of the area collecting varied data over the years. The unsaturated zone has not received much attention until recently. The studies that have been done are a result of problems or concerns arising from liquid radioactive waste disposal. The TRA facility has the most information published about its waste disposal activities. The ICPP has less data about the unsaturated zone due to the fact that most waste water disposal has been to a well. Little is known about the effect of waste water disposal at the NRF on the unsaturated zone. Essentially no information was found about waste disposal activities at other facilities, primarily because there does not appear to be any reported problems associated with waste water ...

1992-01-01

155

Annual report on monitoring of the unsaturated zone and recharge areas at INEL to the state of Idaho INEL Oversight Committee  

Energy Technology Data Exchange (ETDEWEB)

During the early years of the INEL, the USGS conducted extensive studies (sitewide drilling program) of the geology and hydrology of the area collecting varied data over the years. The unsaturated zone has not received much attention until recently. The studies that have been done are a result of problems or concerns arising from liquid radioactive waste disposal. The TRA facility has the most information published about its waste disposal activities. The ICPP has less data about the unsaturated zone due to the fact that most waste water disposal has been to a well. Little is known about the effect of waste water disposal at the NRF on the unsaturated zone. Essentially no information was found about waste disposal activities at other facilities, primarily because there does not appear to be any reported problems associated with waste water ...

1992-12-31

156

Advanced organic analysis and analytical methods development: FY 1995 progress report. Waste Tank Organic Safety Program  

Energy Technology Data Exchange (ETDEWEB)

This report describes the work performed during FY 1995 by Pacific Northwest Laboratory in developing and optimizing analysis techniques for identifying organics present in Hanford waste tanks. The main focus was to provide a means for rapidly obtaining the most useful information concerning the organics present in tank waste, with minimal sample handling and with minimal waste generation. One major focus has been to optimize analytical methods for organic speciation. Select methods, such as atmospheric pressure chemical ionization mass spectrometry and matrix-assisted laser desorption/ionization mass spectrometry, were developed to increase the speciation capabilities, while minimizing sample handling. A capillary electrophoresis method was developed to improve separation capabilities while minimizing additional waste generation. In addition, considerable emphasis has been placed on developing a rapid ...

1995-09-01

159

Shedding Synchrotron Light on a Puzzle of Glasses  

ScienceCinema

...introduced english ...the range of simple english ...the range of simple english ...

165

Waste to energy technologies.  

Science.gov (United States)

No abstract prepared.

2010-04-01

166

Thermal Modeling and Performance Analysis of Interim Dry Storage and Geologic Disposal Facilities for Spent Nuclear Fuel  

Science.gov (United States)

Thermal models are constructed and analyses are performed of aluminum-based spent nuclear fuel (Al-SNF) in interim dry storage and geologic disposal configurations. Two models are developed, referred to as the interim storage model and the codisposal waste package (WP) model. Time-dependent source terms of Al-SNF forms and the defense high-level waste (DHLW) canisters are also developed for thermal performance analysis of the geologic codisposal WP.The interim storage model is a three-dimensional conduction-convection conjugate model to investigate the natural convection cooling of a sealed dry storage canister with vertical orientation in a dry storage vault. The analysis is made for various decay heat sources (equivalent to 25 to 35 kW/m{sup 3}) using various boundary conditions around the canister wall and with backfilled nitrogen or helium gas. Based on the data obtained from the Savannah River Site experimental work and available from the ...

2000-07-15

167

Survey of degradation modes of candidate materials for high-level radioactive-waste disposal containers  

International Nuclear Information System (INIS)

Three copper-based alloys, CDA 102 (oxygen-free, high-purity copper), CDA 613 (aluminum bronze), and CDA 715 (Cu-30Ni), are candidates for the fabrication of high-level radioactive-waste disposal containers. Waste will include spent fuel assemblies from reactors as well as borosilicate glass, and will be sent to the prospective repository site at Yucca Mountain in Nye County, Nevada. The decay of radionuclides will result in the generation of substantial heat and in fluxes of gamma radiation outside the containers. In this environment, container materials might degrade by atmospheric oxidation, general aqueous phase corrosion, localized corrosion (LC), and stress corrosion cracking (SCC). This volume is a critical survey of available data on pitting and crevice corrosion of the copper-based candidates. Pitting and crevice corrosion are two of the most common forms of LC of these materials. Data on the SCC of these alloys is ...

1991-07-01

168

Use of thin glass reflectors for solar concentrators  

Science.gov (United States)

Elastically deforming thin glass (thickness = 0.13 to 0.80 mm) provides an alternate method of forming a curved glass reflector which can eliminate some of the disadvantages of thicker glass. A concept is described where silvered thin glass is bonded to a steel backing to form a laminate with a reflectance greater than 93%. Subsequent bending of the flat reflector laminate to a concentrating profile produces compressive stresses throughout the glass if the laminate is properly designed. These compressive stresses enhance fracture resistance and the lamination provides protection for the silver. The design of the laminate is outlined for 0.25 and 0.51 mm thickness glass and fabrication procedures are discussed. Thermal/humidity cycling, hail impact, bond strength measurements and reflectance results are presented which demonstrate the performance capabilities of ...

1980-01-01

169

Functional domain analysis of glass, a zinc-finger-containing transcription factor in Drosophila.  

Science.gov (United States)

The glass gene is required for proper photo-receptor differentiation during development of the Drosophila eye glass codes for a DNA-binding protein containing five zinc fingers that we show is a transcriptional activator. A comparison of the sequences of the glass genes from two species of Drosophila and a detailed functional domain analysis of the Drosophila melanogaster glass gene reveal that both the DNA-binding domain and the transcriptional-activation domain are highly conserved between the two species. Analysis of the DNA-binding domain of glass indicates that the three carboxyl-terminal zinc fingers alone are necessary and sufficient for DNA binding. We also show that a deletion mutant of glass containing only the DNA-binding domain can behave in a dominant-negative manner both in vivo and in a cell culture assay that measures transcriptional activation. ...

1995-07-01

170

Atomic mechanism of glass-to-liquid transition in simple monatomic glasses  

British Library Electronic Table of Contents (United Kingdom)

The atomic mechanism of a glass-to-liquid transition in a monatomic Lennard-Jones (LJ) glass was studied using the molecular dynamics (MD) method. Glassy models were heated up from low temperature at two different heating rates and a glass-to-liquid transition found to occur at the higher heating rate. The temperature dependence of the potential energy, mean-squared-displacements (MSD) of the atoms and the self-intermediate scattering function indicate clearly that a glass transition occurs in the system. The atomic mechanism of the glass-to-liquid transition was investigated by analyzing the spatio-temporal arrangement of liquid-like atoms in the system upon heating. Liquid-like atoms were detected using the Lindemann-melting-like criterion. Upon heating, liquid-like atoms occur at temper...

2011-01-01

171

All the Spent Nuclear Wastes to Low and Intermediate Level Wastes: PyroGreen  

International Nuclear Information System (INIS)

Spent nuclear wastes are inevitable issues to use nuclear power as a sustainable energy. Therefore, every country has their fuel cycles which are best for their environmental and/or political circumstances for the use of nuclear energy. These days agreements are made that spent nuclear fuels should be recycled to minimize waste volume and its toxicity all around the world. Republic of Korea also has a plan to recycle the spent nuclear fuels by using Gen-IV concept burner reactors and pyro-process plants. Not many options of national nuclear strategies are exist because Korea has too many people for its limited land space. KAERI already has been proposing a national fuel cycle concept called 'KIEP-21' that encompasses all the requirements of the advanced nuclear fuel cycle such as reduction of volume, toxicity, HLW heat load and so on. Authors suggest non-national fuel cycle concept called 'PyroGreen' for the sustainable nuclear energy system. ...

2009-06-01

172

Solid waste research and development: A perspective from Pacific Northwest Laboratory  

Energy Technology Data Exchange (ETDEWEB)

The need for research and development (R&D) of technologies and approaches for sound, effective solid waste management is unquestionable. While many advances have been made by the government and private sectors, still more are needed. Resources for conducting R&D, even at the federal level, are limited however, and thus it is critical that resources be distributed as wisely as possible. The US Department of Energy has a vested interest in developing technologies and approaches for managing solid waste because solid waste management is strongly linked to energy use and environmental impacts. This federal role is needed to address the national and international impacts that can result from the cumulative effects of decisions being made at local, county, state, and regional levels. At Pacific Northwest Laboratory (PNL), one of DOE`s R&D laboratories, we are developing an ...

1992-11-01

173

Determination of vapor-liquid equilibrium data and decontamination factors needed for the development of evaporator technology for use in volume reduction of radioactive waste streams  

Energy Technology Data Exchange (ETDEWEB)

A program is currently in progress at Argonne National Laboratory to evaluate and develop evaporator technology for concentrating radioactive waste streams. By concentrating radioactive waste streams, disposal costs can be significantly reduced. To effectively reduce the volume of waste, the evaporator must achieve high decontamination factors so that the distillate is sufficiently free of radioactive material. One technology that shows a great deal of potential for this application is being developed by LICON, Inc. In this program, Argonne plans to apply LICON`s evaporator designs to the processing of radioactive solutions. Concepts that need to be incorporated into the design of the evaporator include, criticality safety, remote operation and maintenance, and materials of construction. To design an effective process for concentrating waste streams, both ...

1993-10-01

174

The numerical simulation on low-level radioactive waste water, low-temperature cooling water drained effect of implement from the Daya Bay Nuclear Power Plant  

International Nuclear Information System (INIS)

In this paper, we calculated the radioactive concentration distribution of radioactive waste water, the temperature distribution of drained cooling water and the effect of implement from the Daya Bay Nuclear Power Plant on nearby waters range, discussed and analysed some problems of computational results and computation with Alternating Direction Implicit Method (ADI). The contents of the article included: the establishment of two-dimension tidal current equation, radioactive waste water pollutant dispersion equation and cooling water heat convection diffusion equation, the numerical difference calculation model of tidal current field, concentration field as well as temperature field, effect impingement with ADI method, numerical calculation results. The result of research showed that: when the Daya Bay Nuclear Power Plant is on normal operation and after the low level radioactive ...

175

Effects of Cynodon dactylon on Stress-Induced Infertility in Male Rats  

UK PubMed Central (United Kingdom)

Cynodon dactylon (Family: Poaceae) is known to be a tackler in Indian mythology and is offered to Lord Ganesha. It is found everywhere, even on waste land, road side, dry places, and...Full Text Available

2011-01-01

176

LiF enhanced nucleation of the low temperature microcrystalline silicon prepared by plasma enhanced chemical vapour deposition  

Energy Technology Data Exchange (ETDEWEB)

A 15-nm lithium fluoride (LiF) thin film evaporated on glass substrate is shown to enhance the nucleation of microcrystalline Si grown by plasma enhanced chemical vapour deposition at the amorphous/microcrystalline boundary conditions. The effect is more pronounced at low substrate temperatures, nucleation density being 10 times higher at {approx} 80 {sup o}C. The effect is ascribed to the ionic chemical nature of LiF, the low work function material used in organic electronic devices, and we propose its use for micro patterning crystalline Si regions in otherwise amorphous Si film.

2009-10-30

177

Ion processing element with composite media  

Energy Technology Data Exchange (ETDEWEB)

An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to effectively process a high volume flows.

2009-03-24

178

Investigation on the effect of cellulosic nanoparticles' morphology on the properties of natural rubber based nanocomposites  

British Library Electronic Table of Contents (United Kingdom)

Cellulose whiskers and microfibrillated cellulose (MFC) were extracted from the rachis of date palm tree and characterized. These cellulosic nanoparticles were used as reinforcing phase to prepare nanocomposite films using latex of natural rubber as matrix. These films were obtained by the casting/evaporation method. The properties of the ensuing nanocomposite films were investigated using differential scanning calorimetry, toluene and water uptake experiments, dynamic mechanical analysis and tensile tests. The stiffness of the natural rubber was significantly increased above its glass-rubber transition temperature upon nanoparticles addition. The reinforcing effect was shown to be higher for nanocomposites with MFC compared to whiskers. It was ascribed to the higher aspect ratio and possi...

2010-01-01

179

Chemical isomeric effects on propanol glassy structures  

Energy Technology Data Exchange (ETDEWEB)

We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)

2002-07-01

180

Chemical isomeric effects on propanol glassy structures  

International Nuclear Information System (INIS)

We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)

181

Chemical and physical change of packaging materials for food by gamma-ray irradiation  

International Nuclear Information System (INIS)

Recently, foods are often exposed to radiation under packed states with various wrapping materials. In this study, the effects of #gamma#-ray radiation were investigated on the additives in wrapping materials on the market. 10 - 50 kGy #gamma# radiation was irradiated to samples under sealed condition in a glass-ware. Polyethylene bag and wrapping film, polypropylene wrapping film, cup and sheet, and polystyrene cup were used as samples. And the additives in these materials were analyzed by GC/MS to evaluate the radiation effects on them. The irradiation was found to induce rapid degradation of antioxidants, especially, Irgafos 168. Some fatty acid amides used as a lubricant and a plasticizer, DBP were also reduced, but not aliphatic hydrocarbons. However, all polystyrene products used in this study included no additives. The contents of styrene dimer and trimer in those wrapping materials were not changed by ...

1999-02-01

182

Luminescence and laser transition studies of Dy3+:K-Mg-Al fluorophosphate glasses  

International Nuclear Information System (INIS)

Dysprosium ion doped fluorophosphate glasses with compositions of PKMAFDy: (56-x/2) P2O5+17K2O+8Al2O3+(15-x/2)MgO+4AlF3+xDy2O3 (x=0.01, 0.05, 0.1, 1.0 and 2.0 mol%) have been prepared by melt quenching technique and are characterized by optical absorption, emission spectra and fluorescence lifetime measurements. The observed bands in the absorption spectrum are analysed by using free-ion Hamiltonian (HFI) model. The Judd-Ofelt (JO) analysis has been performed and the intensity parameters (??, ?=2, 4, 6) have been evaluated that are used to predict radiative properties. From emission spectra, the effective bandwidth (??eff) and the stimulated emission cross-section (?(?p)) were evaluated. The fluorescence decay from the 4F9/2 level of Dy3+ ions have been measured by monitoring the intense 4F9/2#->#6H13/2 transition (573 nm). The lifetimes (?) are found to decrease with increasing concentration due to concentration quenching. The decay curves ...

2009-02-28

183

NAME=\\  

Wastenet

...Sadri, Ahmad; Barlaz, Morton A.; Hater, Gary R. Sadri, Ahmad Effect of biosolids on refuse decomposition and phosphorus cycling Sadri et al., 10.1177/0734242X09343597 Waste Management & Research SAGE Website Help Contact Us Home Advanced ... Article Effect of biosolids on refuse decomposition and phosphorus cycling Ahmad Sadri1*, Morton A. Barlaz2, and Gary R. Hater3 1 Department of Environmental Services, City and County of Honolulu 2 North Carolina State University 3 Waste Management Inc., *...

184

Geotechnical treatment of generated soil and wastes, and their effective use. Burial of wastes and use of thus-formed sites; Hasseido oyobi haikibutsu no jiban kogakuteki shori to yuko riyo. Haikibutsu no umetate to atochi riyo  

Energy Technology Data Exchange (ETDEWEB)

To use such sites very effectively, pile foundations will be used for soil stabilization and for important structures for the prevention of subsidence. Negative friction that may ensue from the differential settlement of the soil has to be prevented. Measures against gas will include gas collecting and exhausting facilities in the lower parts of structures, natural and forced exhaust systems, and gas detection/warning units. For revegetation, plants strong against bad soil should be selected, they should be protected from generated gas with protecting sheets or the like, and a thick layer of vegetation-capable soil needs to be laid. Replacement, compaction, and solidification are the fundamentals of soil improvement at wastes final treatment locations and of soil-related pollution prevention in the vicinity of the newly produced sites. Across the country, the service life expectancy is approximately 7-8 years for general ...

1997-09-01

185

Strontium removal from caustic carbonate waste solutions using carrier coprecipitation  

Energy Technology Data Exchange (ETDEWEB)

A carrier coprecipitation procedures has been developed for the removal of radioactive strontium from caustic liquid low-level waste (LLLW) generated at Oak Ridge National Laboratory. The two-step treatment process involves the addition of normal Sr (as SrCl{sub 2}) to the waste matrix, which is composed primarily of 0.3 M NaOH and 0.6 M Na{sub 2}CO{sub 3}. The active Sr equilibrates with the normal Sr carrier and coprecipitates as SrCO{sub 3} at pH 13. A liquid/solid separation is made before the pH of the supernate is reduced to pH 8 with sulfuric acid. During the neutralization step, the aluminum is the waste precipitates as Al(OH){sub 3}. Further Sr decontamination is achieved as traces of active Sr sorb to the Al(OH){sub 3} that precipitates during the neutralization step. A final liquid/solid separation is made at pH 8 to remove the sorbed active Sr. Maximum Sr decontamination of the LLLW is obtained when at least 50 ...

1994-12-31

186

SRS Public Involvement in Waste Management Has Resulted in Effective Decisions Supported by the Public Including Disposal Changes and Top-to-Bottom Review Initiative Consensus  

Science.gov (United States)

In the Savannah River Site's (SRS') Solid Waste Management Program, a key to success is the Public Involvement Program. The Solid Waste Division at SRS manages the site's transuranic, low-level, mixed, and hazardous wastes. All decisions associated with management of this waste are of interest to the public and successful program implementation would be impossible without a vigorous public involvement program. The SRS Solid Waste Division (SWD) and its Department of Energy (DOE) customer developed, implemented, and maintain a comprehensive public participation and communications program. It is staffed by public participation and technical specialists to ensure information is presented in a manner that is technically accurate while being tailored for understanding by people without a technical background. The program provides the public with accurate, ...

2003-02-27

187

Improving cost-effectiveness for the furnace in a full-scale refinery plant with reuse of waste tail gas fuel  

Energy Technology Data Exchange (ETDEWEB)

The waste tail gas fuel emitted from refinery plant in Taiwan e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement fuel. In this study, it was slowly added to the fuel stream of a heater furnace to replace natural gas for powering a full-scale distillation process. The waste tail gas fuel contained on average 60 mol% of hydrogen. On-site experimental results show that both the flame length and orange-yellowish brightness decrease with increasing proportion of waste gas fuel in the original natural gas fuel. Moreover, the adiabatic flame temperature increases as the content of waste gas fuel is increased in the fuel mixture since waste gas fuel has a higher adiabatic flame temperature than that of natural gas. The complete replacement of natural gas by waste gas fuel for a heater ...

2010-02-15

188

Waste Food Storage at Fortress Rocks  

Science.gov (United States)

... of waste food generated at McMurdo Station. Some of the difficulties of disposing of waste food ... change waste generation or management at the site? Yes. This will be a temporary waste management ...

189

High conductivity glass electrolytes for sodium/sulfur batteries  

International Nuclear Information System (INIS)

Sodium-ion-conducting glasses are considered a promising alternative to the ceramic electrolytes. The glass upon which the most development work has been done is a sodium borate glass, which has an ionic resistivity of about 2 x 10/sup 4/ #OMEGA#-cm at 300"0C. Because of its high resistivity, cells using this borate glass require thousands of hollow glass fibers, each about 80 micrometers outer diameter (15 micrometer wall). In spite of its greater complexity, the cell with the glass electrolyte is of interest because of its potential for lower cost and higher power than the cell with ceramic electrolyte. Recently, silicate glasses of lower resistivity have been proposed for this application. These include: a soda-alumina-silica glass (900 #OMEGA#-cm at 300"0C), a soda-zirconia-magnesia-silica glass ...

1986-06-01

190

Volatile Organic Compound Formation in Waste Composting Processes  

Environmental Research Database

Objectives~%~ To quantify the volatile organic compound (VOC) emissions arising from the composting of a range of municipal and~%~ industrial wastes.~%~~%~ To relate the VOC emissions to the material being processed and the process conditions.~%~~%~ To confirm the findings of the above activites by monitoring full-scale composting operations.~%~~%~ To develop predictive models of VOC emissions in relation to waste feedstock and process conditions.~%~~%~ To produce guidance for plant designers, operators a [continued...]DescriptionA recent study of three composting plants undertaken for the Environment Agency has confirmed earlier work suggesting that waste composting can be a source of volatile organic compound (VOC) emissions. However, these experiments were restricted to garden and kitchen waste composting schemes and it was not ...

2005-01-30

191

Treatment of Difficult Wastes with Molten Salt Oxidation  

Energy Technology Data Exchange (ETDEWEB)

Molten salt oxidation (MSO) is a good alternative to incineration for the treatment of a variety of organic wastes such as explosives, low-level mixed waste streams, PCB contaminated oils, spent resins and carbon. Since mid-1990s, the U.S. Army Defense Ammunition Center (DAC) and the Department of Energy (DOE) have jointly invested in MSO development at the Lawrence Livermore National Laboratory (LLNL). LLNL first demonstrated the MSO process for the effective destruction of explosives, explosives-contaminated materials, and other wastes on a 1.5-kg/hr bench-scale unit, and then in an integrated MSO facility capable of treating 8 kg/hr of low-level radioactive mixed wastes. Several MSO systems have been built with sizes up to 10 ft in height and 16 inches in diameter. LLNL in 2001 completed a MSO plant for DAC for the destruction of explosives-contaminated sludge and ...

2003-02-21

192

Quality assurance requirements and description for the Civilian Radioactive Waste Management Program  

International Nuclear Information System (INIS)

The Quality Assurance Requirements and Description (QARD) is the principal quality assurance document for the Civilian Radioactive Waste Management Program (Program). It establishes the minimum requirements for the Quality Assurance Program. The QARD contains regulatory requirements and program commitments necessary for the development of an effective quality assurance program. Quality assurance implementing documents must be based on, and consistent with, QARD requirements. The QARD applies to the following: (1) acceptance of spent nuclear fuel and high-level radioactive waste; (2) transport of spent nuclear fuel and high-level radioactive waste; (3) the Monitored Retrievable Storage (MRS) facility through application for an operating license; (4) Mined Geologic Disposal System (MGDS), including the site characterization activities (exploratory studies facility (ESF) and surface based testing), through ...

193

Composites from recycled wood and plastics. Report for May 1990-July 1993  

Energy Technology Data Exchange (ETDEWEB)

The ultimate goal of this research was to develop technology to convert recycled wood fiber and plastics into durable products that are recyclable and otherwise environmentally friendly. Two processing technologies were used to prepare wood-plastic composites: air-laying and melt-blending. Research was conducted in (1) developing laboratory methods for converting waste wood, wastepaper, and waste plastics into forms suitable for processing into composites; (2) optimizing laboratory methods for making composite panels from the waste materials; (3) establishing a database on the effects of formulation and bonding agent on physical and mechanical properties of composites; (4) establishing the extent to which the composites can be recycled without unacceptable loss in properties; and (5) reaching out to industry to provide education, to develop applications, and to extend the database. Overall, the program ...

1995-01-01

194

Assay of the uranium and plutonium content in process residues and wastes using the correction for sample self attenuation in segmented gamma scanning system  

International Nuclear Information System (INIS)

A method of the correction for sample self attenuation used in segmented gamma scanner (SGS) is described. The method of calibration for assaying the uranium and plutonium contents of each category of heterogeneous process residues and wastes in nuclear facilities is studied. The effect of variable measurement parameter on measurement results is also studied. The measurement results of SGS assay is compared with that of the destructive assay (DA), which is aimed at evaluating SGS method for assaying uranium and plutonium content in process residues and wastes. The deviation of two assay results is 3.6%. The SGS assay results and DA assay results both are coincided well in error limits. Four category of heterogeneous process residues and wastes in nuclear facilities have assayed successfully in physical inventory. The uncertainty of measurement results for uranium and plutonium content in process ...

1998-09-01

195

An engineering approach to solid waste collection system: Ibadan North as case study  

International Nuclear Information System (INIS)

This research centered on finding and perfecting methods of collection and disposal of refuse in Ibadan North Local Government Areas. The methodology used included questionnaire administration, personal interviews, field reconnaissance, and biochemical tests of water samples, all aimed at providing useful data for the design of effective methods of collecting and disposing refuse. The local government area was divided into three classes based on resident income: a high-income area (Bodija Avenue, etc.), a medium-income area (Sanngo, Oluyole, etc.), and a low-income area (Beere, Adeoyo, etc.). The research outcomes revealed that the waste generation rate for the local government ranged from 0.2 to 0.33 kg/cap/day and waste density ranged from 172.41 to 217.61 kg/m"3. Water analyses showed that the chloride, manganese, lead, and cadmium levels in water from low-income areas were above the WHO standard. The refuse generated in ...

196

Cost effectiveness analysis of effluent limitations guidelines and standards for the centralized waste treament industry  

Science.gov (United States)

EPA has proposed effluent limitations guidelines and standards for the centralized waste treatment (CWT) industry. This report investigates the cost-effectiveness of all possible combinations of proposed control options for the three subcategories of CWT operations. EPA considered three control options for metals, two for oils and two for organics, with 12 possible combinations of these options. The report measures cost-effectiveness through a comparison of compliance costs to the quantity of pollutants removed under each combination of control options. The effectiveness of the regulations is measured in terms of reductions in the pounds of pollutants discharged to surface waters, weighted to account for the pollutants` toxicity. Some pollutants removed are specifically addressed by the regulation, while others and not directly regulated but are removed incidentally as a result of controlling for other ...

1998-12-01

197

Glass-heat-pipe evacuated-tube solar collector  

Science.gov (United States)

A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

1981-08-06

198

Visiatome: The French Discovery and Information Center on Radioactive Waste Management  

International Nuclear Information System (INIS)

The French radioactive waste management act of December 30, 1991, included two key provisions. It initiated a major research program with three areas of investigation concerning high-level long-lived radioactive waste management routes, and called for the Government to submit a legislative proposal to Parliament within 15 years (by 2006) specifying the policy guidelines adopted. Considering the sensitive nature of the subject, the questions surrounding the issue of radioactive waste, and the social, economic and environmental concerns for present and future generations, the Government has inaugurated, in 2005, a nationwide public debate on these issues between the submittal of the research reports and the parliamentary discussion of the proposed law. In this context, the CEA has decided to concentrate at Marcoule the expertise and experience acquired in the area of radioactive waste management and to ...

199

Removal of NO and SO2 in Corona Discharge Plasma Reactor with Water Film  

Science.gov (United States)

In this paper, a novel type of a corona discharge plasma reactor was designed, which consists of needle-plate-combined electrodes, in which a series of needle electrodes are placed in a glass container filled with flue gas, and a plate electrode is immersed in the water. Based on this model, the removal of NO and SO2 was tested experimentally. In addition, the effect of streamer polarity on the reduction of SO2 and NO was investigated in detail. The experimental results show that the corona wind formed between the high-voltage needle electrode and the water by corona discharge enhances the cleaning efficiency of the flue gas because of the presence of water, and the cleaning efficiency will increase with the increase of applied dc voltage within a definite range. The removal efficiency of SO2 up to 98%, and about 85% of NOx removal under suitable conditions is obtained in our experiments.

2004-04-01

200

Radiation treatment of medical devices and packaging materials. Pt. 1  

International Nuclear Information System (INIS)

The first part of the study contains a literature compilation of more than 50 original publications reporting the radiation induced effects in 17 different high polymer materials and glass which are relevant in the manufacturing of medical devices or packing materials. The results collected demonstrate that high energy radiation, i.e. gamma- or X-rays, causes various physical and chemical alterations in high polymer materials. A detailed summary and discussion of the results of the original publications is not included in the present report, it will be presented in the second part of the study. Furthermore, the second part of the study will refer to the aspect of wholesomeness of irradiated medical devices or packing materials in a more general manner of representation. (orig.).

201

Photoconductive ultraviolet detectors based on ZnO films  

British Library Electronic Table of Contents (United Kingdom)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8mA, and a slow photoresponse with a rise time of 5min and a decay time of 7min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the d...

2006-01-01

202

High temperature properties of ceramics in the SiAlON system  

International Nuclear Information System (INIS)

A series of SiAlON materials with a cordierite-based matrix were annealed for different lengths of time to cause crystallization of the glass phase. Their fracture toughness, hardness, and elastic modulus were measured from room temperature up to 1100"0C. The fracture toughness generally decreased with temperature. Short time annealing raised toughness at lower temperatures, while further annealing lowered it back to the value for as-hot pressed materials. At higher test temperatures annealing had no effect on toughness. This annealing behavior is significantly different from that previously reported in the system SaAlON-YAG. Hardness decreased monotonically with temperature for all samples. Both hardness and the elastic modulus were not affected by the annealing treatment. At elevated temperatures appreciable scatter of modulus results allowed only a rough trend of decrease with temperature to be observed.

203

Dielectric properties of sols of silver nanoparticles capped by alkyl carboxylate ligands  

British Library Electronic Table of Contents (United Kingdom)

Sols of silver nanoparticles in toluene were studied by broadband dielectric spectroscopy (10?3?105 Hz). The frequency dependences of the specific alternating current (ac) conductivity and the complex electric modulus were used to estimate the temperature/frequency intervals of long- and short-range charge transfer occurs, respectively. A considerable increase (by more than 30 ?C) in the Vogel temperature T 0 and the glass transition temperature T g in sols compared with the pure solvent was found. It can be hypothesized that these cooperative effects reflect the initial stage of the superlattice formation. Although the dielectric characteristics of sols are generally controlled by the conductivity relaxation, the dielectric response was observed in the high-frequency range (1?103 Hz) at l...

2011-01-01

204

Algebraic Topology Foundations of Supersymmetry and Symmetry Breaking in Quantum Field Theory and Quantum Gravity: A Review  

CERN Document Server

A novel algebraic topology approach to supersymmetry (SUSY) and symmetry breaking in quantum field and quantum gravity theories is presented with a view to developing a wide range of physical applications. These include: controlled nuclear fusion and other nuclear reaction studies in quantum chromodynamics, nonlinear physics at high energy densities, dynamic Jahn-Teller effects, superfluidity, high temperature superconductors, multiple scattering by molecular systems, molecular or atomic paracrystal structures, nanomaterials, ferromagnetism in glassy materials, spin glasses, quantum phase transitions and supergravity. This approach requires a unified conceptual framework that utilizes extended symmetries and quantum groupoid, algebroid and functorial representations of non-Abelian higher dimensional structures pertinent to quantized spacetime topology and state space geometry of quantum operator algebras. Fourier transforms, generalized ...

2009-01-01

205

Treatment of radioactive liquid waste by reverse osmosis; Influence of co-existing ions on the change of decontamination factor  

Energy Technology Data Exchange (ETDEWEB)

The report addresses the application of reverse osmosis to the treatment of radioactive liquid waste, focusing on the effects of non-radioactive cations and anions, existing in radioactive waste, on the removal of radioactive nuclides. The bivalent cations are generally about ten times as high in decontamination factor as monovalent ones. In the case of anions, the factor of SO{sub 4}{sup 2-} is about ten times that of Cl{sup -} while that of NO{sub 3}{sup -} is somewhat smaller than that of Cl{sup -}. During permeation through membrane, anions tend to accompany cations, and the decontamination factor of accompanying ions is found to increase with that of the paring ions. These results indicate that if one can select components that will remain in the liquid waste, one should consider their effects on the efficiency of its treatment. Furthermore, the interaction between two anions ...

1991-01-01

206

Treatment of radioactive liquid waste by reverse osmosis  

International Nuclear Information System (INIS)

The report addresses the application of reverse osmosis to the treatment of radioactive liquid waste, focusing on the effects of non-radioactive cations and anions, existing in radioactive waste, on the removal of radioactive nuclides. The bivalent cations are generally about ten times as high in decontamination factor as monovalent ones. In the case of anions, the factor of SO_4"2"- is about ten times that of Cl"- while that of NO_3"- is somewhat smaller than that of Cl"-. During permeation through membrane, anions tend to accompany cations, and the decontamination factor of accompanying ions is found to increase with that of the paring ions. These results indicate that if one can select components that will remain in the liquid waste, one should consider their effects on the efficiency of its treatment. Furthermore, the interaction between two anions or between two cations can be ...

207

Calcination of Fluorinel-sodium waste blends using sugar as a feed additive (formerly WINCO-11879)  

Energy Technology Data Exchange (ETDEWEB)

Methods were studied for using sugar as a feed additive for converting the sodium-bearing wastes stored at the Idaho Chemical Processing Plant into granular, free flowing solids by fluidized-bed calcination at 500{degrees}C. All methods studied blended sodium-bearing wastes with Fluorinel wastes but differed in the types of sugar (sucrose or dextrose) that were added to the blend. The most promising sugar additive was determined to be sucrose, since it is converted more completely to inorganic carbon than is dextrose. The effect of the feed aluminum-to-alkali metal mole ratio on calcination of these blends with sugar was also investigated. Increasing the aluminum-to-alkali metal ratio from 0.6 to 1.0 decreased the calcine product-to-fines ratio from 3.0 to 1.0 and the attrition index from 80 to 15%. Further increasing the ratio to 1.25 had no effect.

1992-06-01

208

Goal-based waste management strategy to reduce persistence of contaminants in leachate at municipal solid waste landfills  

British Library Electronic Table of Contents (United Kingdom)

The required minimum 30-year post-closure care period for municipal solid waste (MSW) landfills can be shortened by reducing or eliminating of MSW components with long-terms effect in gas and leachate. The objectives of this study were to evaluate the relative persistence of landfill gas, leachate quantity, and selected leachate parameters using post-closure monitoring data from a case study landfill in south Florida. The relative persistence of selected decomposition byproducts in leachate were evaluated by both zero order and first order models based on monitoring data from the case study landfill. The analyses show that although gas and leachate production rates diminish very quickly, some contaminants remain in leachate as the decomposition process continues at a slower rate. For the c...

2011-01-01

209

Effects of thermically-dry sewage sludge and municipal waste compost amendment on microbial biomass, dehydrogenase activity and CO_2 fluxes in a degraded agricultural soil  

International Nuclear Information System (INIS)

Understanding the dynamic of soil C is a key to managing soil organic matter to enhance soil fertility and ecosystem functioning and reduce trace gas emission from soils. Our objective was to determine the influence of thermically-dry sewage sludge (TSL) and municipal waste compost and the application management on soil (mixed or on soil surface) applied at sludge (TSL) and municipal waste compost and the application management on soil (mixed or on soil surface) applied at two rates of 30 t ha"-1 and 60 t ha"-1, on CO_2 fluxes, microbial biomass C (MBC) and dehydrogenase activity (DH), during an incubation study. (Author)

210

Coal liquefaction catalysis by industrial metallic wastes  

Energy Technology Data Exchange (ETDEWEB)

Catalytic activity of industrial metallic wastes in coal liquefaction was examined in a 100lb/day continuous coal processing development unit. Red mud, a waste material from the aluminium industry, and an electric furnace flue dust containing Ni, Mo, Co and Fe showed a pronounced effect on the conversion of a Kentucky bituminous coal. Coal conversion and oil production increased significantly with the addition of red mud and flue dust. Comparison of the catalytic activity of pyrite, red mud, and flue dust, based on selectivity analysis, showed that red mud was the most desirable disposable catalyst. However, if the primary goal of coal liquefaction is high oil production, irrespective of hydrogen consumption, pyrite is the most active catalyst among those discussed in the paper.

1985-01-01

211

Experimental investigation of dose calibrator response for "1"2"5I brachytherapy solutions contained in 5 mL plastic syringes and 2 mL conical glass v-vials as a function of filling mass  

International Nuclear Information System (INIS)

The effect of measurement geometry on the determination of the activity of solutions containing "1"2"5I for use in brachytherapy applications has been investigated for 5 mL plastic syringes and 2 mL conical glass dose vials as a function of filling mass. New dial settings for the syringes over a filling mass range of 1 to 3 g have been determined to be 497#+-#8 and 469#+-#8 (expanded, k=2, uncertainties) for the NIST Capintec CRC-12 and Capintec CRC-35R, respectively, with any effect due to the filling mass lying within the uncertainty in the activity calibration. A filling mass effect was observed in the dose vials, causing a 10.5% reduction in the chamber response from a 2 g filling mass to 1 g. Dial settings at 2 g were experimentally found to be 143#+-#2 and 135#+-#2 (expanded uncertainties) for the NIST Capintec CRC-12 and Capintec CRC-35R, respectively. The appropriate dial settings for the same ...

2002-07-01

212

Ballistic performance of polyurea-coated armor grade ceramic tiles  

Science.gov (United States)

The use of ceramics as energy absorbents has been studied by many researchers and some improvements in the ballistic performance of ceramic tiles have been made by coating them with different classes of materials (e.g. E-glass/epoxy, carbon-fiber/epoxy, etc.). Using ceramics for energy absorbing applications leads to a significant weight reduction of the system. Therefore, any modification to the ceramic configuration in the system which leads to more energy absorption with the same or less areal density is significant. On the other hand, polyurea has been proved to be an excellent energy dissipating agent in many applications. Inspired by this, we are studying the effect of coating ceramics with polyurea and other materials, on the energy absorption and ballistic performance of the resulting ceramic-based composites. In this study, we investigate the effect of polyurea on ballistic efficiency of ceramic tiles. To this end, ...

2010-03-01

213

Waste Sampling and Characterization Facility (WSCF). Maintenance Implementation Plan  

Energy Technology Data Exchange (ETDEWEB)

This Maintenance Implementation Plan has been developed for maintenance functions associated with the Waste Sampling and Characterization Facility (WSCF). This plan is developed from the guidelines presented by Department of Energy (DOE) Order 4330.4A, Maintenance Management Program (DOE 1990), Chapter II. The objective of this plan is to provide baseline information for establishing and identifying WHC conformance programs and policies applicable to implementation of DOE order 4330.4A guidelines. In addition, this maintenance plan identifies the actions necessary to develop a cost-effective and efficient maintenance program at WSCF.

1993-07-01

214

Stability of model recycled mixed plastic waste compatibilised with a cooperative compatibilisation system  

British Library Electronic Table of Contents (United Kingdom)

The effect of the degree of degradation of the components of a model municipal plastic waste (a mixture of low-density polyethylene, high-density polyethylene, polypropylene and high-impact polystyrene) on the toughness and stability of recyclates compatibilised with a cooperative compatibilisation system (a mixture of ethylene-propylene statistical and styrene-butadiene block copolymers with a secondary amine-based stabiliser) was studied. It was shown that good impact strength was achieved for recyclates having components with a low or medium degree of degradation. Mechanical properties of recyclates having the components with a high degree of degradation are deteriorated. The addition of the cooperative compatibilisation system leads to a higher thermo-oxidative stability of recyclates ...

2011-01-01

215

Review of the Vortec soil remediation demonstration program  

Energy Technology Data Exchange (ETDEWEB)

The DOE`s clean-up of its nuclear complex require the development of innovative technologies to convert soils contaminated by hazardous and/or radioactive wastes to forms which can be readily disposed in accordance with current waste disposal methods. The unique features of Votec CMS technology should make it particularly cost-effective process for the vitrification of soils, sediments, sludges, and mill tailings containing organic metallic and/or radioactive contaminants. This article describes the technology (Votec`s combustion and melting system), the results of testing, the demonstration plant system, and summarizes the future schedule and the equipment needed. 3 figs., 3 tabs.

1994-11-01

216

New aspects for the evaluation of radioactive waste disposal methods  

International Nuclear Information System (INIS)

For the performance assessment of radioactive and hazardous waste disposal sites, risk assessments are usually performed for the long term, i.e., over an interval in space and time for which one can predict movement and behavior of toxic agents in the environment. This approach is based on at least three implicit assumptions: One, that the engineering layout will take care of the immediate endangerment of potential receptors; two, that one has carefully evaluated just how far out in space and time the models can be extrapolated, and three, that one can evaluate potential health effects for very low exposures. A few of these aspects will be discussed here in the framework of the scientific method.

1996-08-18

217

Cost-time management: A powerful tool in a new application - cleaning up the weapons complex  

International Nuclear Information System (INIS)

Westinghouse Electric Corporation is aggressively applying cost-time management to bolster timely, cost-effective cleanup and waste management activities at sites it manages for the U.S. Department of Energy (DOE). Cost-time management is a diagnostic technique which is applicable to virtually any process. It identifies opportunities to reduce cycle-times and costs. When applied to cleanup and waste management at DOE facilities, cost-time profile analysis helps identify actions to improve productivity and quality. Moreover, by reducing cycle-times and costs, it achieves significant savings to taxpayers. (author)

1992-03-01

218

Ultrafast laser fabrication of submicrometer pores in borosilicate glass  

UK PubMed Central (United Kingdom)

We demonstrate rapid fabrication of submicrometer-diameter pores in borosilicate glass using femtosecond laser machining and subsequent wet-etch techniques. This approach allows direct and repeatable...Full Text Available

2008-05-15

219

Light-induced Adhesion of Spirogyra Cells to Glass 1  

UK PubMed Central (United Kingdom)

Adhesion of Spirogyra (tentatively, Spirogyra fluviatilis) cells to glass is described. The cells of an algal filament can adhere to a substrate only when they are...Full Text Available

1977-04-01

220

Interfacial reactions between PbO-rich glasses and aluminium composites  

CERN Document Server

565 deg C occurs when dissolution rate exceeds oxidation rate, exposing the fresh Al anode to the glass melt. Under inert atmosphere (at 583 deg C), air oxidation is not possible and galvanic cell redox reactions generate an excessive copper interlayer as the system attempts to sustain the oxide layer at the anode. Similar behaviour is observed in those coatings formed on the alloy using glass C (containing Al sub 2 O sub 3 and Na sub 2 O). In this case, the interfacial reactions involve the PbO of the glass and Pb-rich spherical precipitates are formed in the interfacial region, along side sodium aluminosilicate phases, precipitated from the PbO-depleted glass. The behaviour in both systems indicates that oxygen diffuses through the edge of the glass drop, from the atmosphere, to the substrate/glass interface. Coatings formed on the MMCs in air exhibited a ...

2000-01-01

221

Consolidated silica glass from nanoparticles  

International Nuclear Information System (INIS)

A dense silica glass was prepared by consolidating a highly dispersed silicic acid powder (particle size 1H magic-angle spinning (MAS) NMR confirmed an increase in hydroxyl groups in the sample prepared by SPS relative to that of the conventional SiO2 reference glass. Aside from the comparably high water content, we conclude from the similarity of the IR-reflectance and the 29Si MAS NMR spectra of the SPS sample and the corresponding spectra of the conventionally prepared silica glass, that the short- and medium-range order is virtually the same in both materials. Raman spectroscopy, however, suggests that the number of three- and four-membered rings is significantly smaller in the SPS sample compared to the conventionally prepared sample. Based on these results we conclude that it is possible to prepare glasses by compacting amorphous powders by the SPS process. The SPS process may therefore enable the ...

2008-09-01

222

Reclamation of acidic copper mine tailings using municipal biosolids  

Energy Technology Data Exchange (ETDEWEB)

Reclamation of copper mine tailings in a cost effective, successful, and sustainable manner is an ongoing area of evaluation in the arid southwest. A study was initiated in September, 1996 near Hayden, Arizona to evaluate the use of municipal biosolids for reclaiming acidic copper mine tailings (pH of 2.5 to 4.0). The main objectives of the study were to (1) define an appropriate level of biosolids application for optimum plant growth, and (2) evaluate the effects of green waste and lime amendments. The experiment was a randomized complete block design with four biosolid rates of 20, 70, 100 and 135 dry tons/acre, three amendment treatments (none, green waste, and green waste plus lime); with three replications. Non-replicated controls (no treatment, green waste only and lime only) were included for comparison. Shortly after biosolids incorporation to a depth of ...

1998-12-31

223

Modeling and optimization of a propeller-type tribocharger for granular materials  

British Library Electronic Table of Contents (United Kingdom)

Electrostatic separation has already proved to be an effective means for the recycling of granular plastics from industrial wastes. The aim of the present work was to optimize the operation of a novel device that could ensure effective triboelectric charging of such materials prior to their selective sorting in a high-intensity electric field. The experiments were performed on two sorts of mm-size granular materials Acrylonitrile Butadiene Styrene and High Impact Polystyrene, originating from the processing of waste electric and electronic equipment. The samples were introduced in a Polyvinyl Chloride cylinder, where a co-axial propeller entrained the plastic granules into a helical motion that favored their triboelectric charging by combining the mechanical and aerodynamical effects. The ...

2011-01-01

224

Luminescence of terbium(III) chloride in porous glass  

International Nuclear Information System (INIS)

Capsulation of terbium(III) chloride in porous glass in the amount of 1.5-150 #mu#mole g"-"1 was carried out by impregnation of the glass substrate with variable concentrations of the salt aqueous solutions. Maximum luminosity of terbium(III) chloride in porous glass is found at its concentration of 120 #mu#mole g"-"1, that is close to the corresponding monolayer surface filling. Concentration dependences of terbium(III) luminescence and its quenching by adsorbed water are in agreement with the ideas of molecular fragmentation and uniform distribution of capsulated salt on the substrate surface

2007-03-01

225

Hollow Glass Filament Reinforced Plastics for Deep ...  

Science.gov (United States)

... Problems investigated in various basic hollowness ratios include ultimate compressive strength, fatigue properties, buckling characteristics, and ...

1966-02-08

226

Glass Fragment Hazard from Windows Broken by Airblast  

Science.gov (United States)

... MATHEMATICAL PREDICTION, BODIES, SKIN(ANATOMY), SONIC BOOM, BIOPHYSICS, WOUND BALLISTICS, BONE FRACTURES, SKULL. ...

1980-05-30

227

Consolidation behavior of Cu- and Ni-based bulk metallic glass composites  

Energy Technology Data Exchange (ETDEWEB)

The Cu- and Ni-based bulk metallic glass matrix composites were fabricated by spark plasma sintering of a mixture of gas-atomized metallic glass powders and ductile brass powders. The brass powders added for the enhancement of plasticity are well distributed in the matrix after consolidation. The matrix of the composite materials remains as a fully amorphous phase after consolidation process. With increasing the brass content, the level of plasticity strain increased, although the level of strength decreased. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering.

2007-05-31

228

Comparative radial distribution analysis of the short range order in metallic glass Al_0_._9_1La_0_._0_9 and crystalline Al_1_1La_3  

International Nuclear Information System (INIS)

XAFS data of metallic glass Al_0_._9_1La_0_._0_9 and a crystalline phase Al_1_1La_3 formed by annealing of the glass were measured at the La L_3 edge at T=12 K and analyzed using the radial distribution function method. The shortest La-Al distance appeared to be distinctively smaller within the glass than in the crystal. This difference decreases the disparity in size of La and Al in the alloy, allowing their mixing in the glassy state. ((orig.)).

1994-09-02

229

Ceramic Materials : Physics 130 : Properties of Matter  

Science.gov (United States)

Lecture notes (pdf) on Ceramics is part of a physics course on the properties of matter from the University of Auckland, Department of Chemical and Materials Engineering. The following topics are covered: types of chemical bonding, degree of ionic character, structure of ceramics and crystallography, interstitial sites in different crystal structures, silicate structures, glasses, glass transition temperature, glass viscosity, thermal and mechanical properties of ceramics and glasses, fracture properties of ceramics and processing of ceramic materials. Keywords: ionic bonds; covalent bonds; coordination numbers; thermal shock; grain growth; sintering; green body

2007-02-01

230

Carbon Fiber Reinforced Glass Matrix Composites for Satellite ...  

Science.gov (United States)

... The ultimate compressive strength (UCS) for the HMU/BSG composite is essentially equivalent to the tensile strength exhibited by this system. ...

1992-06-01

231

Microbial degradation of low-level radioactive waste. Volume 2, Annual report for FY 1994  

Science.gov (United States)

The Nuclear Regulatory Commission stipulates in 10 CFR 61 that disposed low-level radioactive waste (LLW) be stabilized. To provide guidance to disposal vendors and nuclear station waste generators for implementing those requirements, the NRC developed the Technical Position on Waste Form, Revision 1. That document details a specified set of recommended testing procedures and criteria, including several tests for determining the biodegradation properties of waste forms. Cement has been widely used to solidify LLW; however, the resulting waste forms are sometimes susceptible to failure due to the actions of waste constituents, stress, and environment. The purpose of this research program is to develop modified microbial degradation test procedures that will be more appropriate than the existing procedures for evaluating the effects of ...

1995-08-01

232

Microbial degradation of low-level radioactive waste. Final report  

Energy Technology Data Exchange (ETDEWEB)

The Nuclear Regulatory Commission stipulates in 10 CFR 61 that disposed low-level radioactive waste (LLW) be stabilized. To provide guidance to disposal vendors and nuclear station waste generators for implementing those requirements, the NRC developed the Technical Position on Waste Form, Revision 1. That document details a specified set of recommended testing procedures and criteria, including several tests for determining the biodegradation properties of waste forms. Information has been presented by a number of researchers, which indicated that those tests may be inappropriate for examining microbial degradation of cement-solidified LLW. Cement has been widely used to solidify LLW; however, the resulting waste forms are sometimes susceptible to failure due to the actions of waste constituents, stress, and environment. The purpose of this research program was ...

1996-06-01

233

Numerical heat transfer studies of PCMs used in a box-type solar cooker  

Energy Technology Data Exchange (ETDEWEB)

Theoretical investigations on the phase change materials (PCMs) used as the heat storage media for box-type solar cookers have been conducted in this study. The selected PCMs are magnesium nitrate hexahydrate, stearic acid, acetamide, acetanilide and erythritol. For a two-dimensional simulation model based on the enthalpy approach, calculations have been made for the melt fraction with conduction only. Different materials such as glass, stainless steel, tin, aluminum mixed, aluminum and copper are used as the heat exchanger container materials in the numerical calculations. The large value of thermal conductivity of heat exchanger container material did not make a significant contribution on the melt fraction except for at very low thermal conductivities. Based on the theoretical results, stearic acid and acetamide are found to be good compatibility with latent heat storage system. It is also found that the initial temperature of PCM does not have very important ...

2008-05-15

234

Fully transparent thin-film transistor devices based on SnO2 nanowires.  

Science.gov (United States)

We report on studies of field-effect transistor (FET) and transparent thin-film transistor (TFT) devices based on lightly Ta-doped SnO2 nano-wires. The nanowire-based devices exhibit uniform characteristics with average field-effect mobilities exceeding 100 cm2/V x s. Prototype nano-wire-based TFT (NW-TFT) devices on glass substrates showed excellent optical transparency and transistor performance in terms of transconductance, bias voltage range, and on/off ratio. High on-currents and field-effect mobilities were obtained from the NW-TFT devices even at low nanowire coverage. The SnO2 nanowire-based TFT approach offers a number of desirable properties such as low growth cost, high electron mobility, and optical transparency and low operation voltage, and may lead to large-scale applications of transparent electronics on diverse substrates. PMID:17595151

2007-06-27

235

Effects of microwaves on cell survival at elevated temperatures  

Energy Technology Data Exchange (ETDEWEB)

Since microwaves are used in human cancer therapy, information on specific biological effects of microwaves at elevated temperatures is important. To help supply this information, we exposed mammalian cells (CHO) and bacteria (Serratia marcescens) to hyperthermal temperatures (43, 44, and 45/sup o/C for CHO and 48, 49, and 50/sup o/C for the bacteria) with and without microwave irradiation. Temperature control was maintained by a refrigeration-reheat system and high-velocity water recirculation. The 2450-MHz microwave source was operated in a pulsed mode with power density up to 500 mW/cm/sup 2/. As expected, the survival curve slopes for both cell types increased rapidly with temperature, doubling for each degree Celsius. Microwave irradiation produced no significant change in extrapolation number for either cell type. However, survival curves of CHO cells which received microwaves were steeper by a factor of 1.25 than their sham-irradiated controls. No ...

1981-12-01

236

Immobilization of waste material  

International Nuclear Information System (INIS)

A method is described for immobilizing or solidifying waste material, which includes blending the waste material with powdered metal and subjecting the mixture of waste material and powdered metal to high pressure. (author).

237

DISPOSING DEVICE FOR WASTE  

J-STORE (Japan)

Full Text Available

2005-12-19

238

Co-combustion of recycled waste materials with peat and coal in a 15 kw fluidized bed reactor  

Energy Technology Data Exchange (ETDEWEB)

Co-combustion tests for recycled fuels and peat were made at a 15 kW fluidized bed reactor at VTT Energy in Jyvaeskylae. Peat was used as reference fuel. 25 tests in total were performed during 1994 - 1996. A part of the peat energy was substituted by coal in five tests, in order to change the sulphur/chlorine ratio of the fuel mixture. Fuel mixtures (25% recycled fuel and 75% peat, at energy ratio) were pelletized in order to get homogeneous fuel mixtures. The tests in the year 1994 were air staging experiments (with and without tertiary air). All test were performed with air staging in the years 1995 and 1996. The aim of the research was to determine whether the co-combustion of waste materials will cause additional emission problems, as compared to combustible emissions from conventional air-staged fluidized bed combustion. Further, the aim was to study which large-volume components can be burned safely. One aim was to study the influence of fuel properties and ...

1998-12-31

239

The carbon balance and greenhouse effects of the Finnish forest sector at present, in the past and future  

Energy Technology Data Exchange (ETDEWEB)

In this study the greenhouse impact of the total Finnish forest sector was considered, which means that the estimated emissions and sink effects from exported forest products were also included. The forest biomass is and seems to be in the next decades the most important factor in the carbon balance of the total forest sector. The development alternatives of forest industries and waste management practices has still a remarkable influence on the greenhouse impact of the Finnish forest sector. The waste management practices in the future has an important influence on the emissions but the exact net greenhouse impact of the landfills is still uncertain. However, the methane emissions from existing landfills can be reduced essentially by gas recovery. Increased incineration and energy recovery of wood waste (and replacing fossil fuel use by it) is also a future alternative for reducing the greenhouse ...

1996-12-31

240

New dimensions in our understanding of the human health effects of environmental pollutants  

Energy Technology Data Exchange (ETDEWEB)

The term {open_quotes}hazardous{close_quotes} waste is used primarily in reference to potential hazards to human health and, to a lesser decree, hazards to wildlife and the ecosystem. Many of the chemicals associated with hazardous waste sites are also widely distributed throughout the environment; therefore, the health hazards associated with hazardous waste sites are not different from those associated with general environmental contamination. Until recently, it was generally assumed that cancer was the human disease of greatest concern associated with toxic chemicals. In fact, most governmental regulations related to exposure are designed on the basis of presumed cancer risks. Since the evidence that hazardous chemicals can cause cancer is strong, it is appropriate to be concerned about cancer risk. Recent evidence, however, has triggered a reevaluation of the assumption that only cancer is of concern. New evidence ...

1996-12-31

241

Underground coal waste disposal: Can it be cost effective. [Considers 10 different methods of transporting the wastes  

Energy Technology Data Exchange (ETDEWEB)

This paper examines the feasibility of returning coal mine wastes to the mined-out areas, as encouraged by PL 95-87, the ''Surface Mining Control and Reclamation Act of 1977'' (SMCRA). Reviews a National Academy of Sciences report which identified alternative backfilling methods. Presents diagram of mechanical backfilling with gravity and mechanical transport, and tables of existing underground mine waste disposal methods and a summary of technical feasibility of alternative disposal systems. Evaluated systems include gravity disposal with mechanical surface transport; gravity disposal with mechanical in-mine transport; complete mechanical disposal; mechanical disposal with gravity surface to underground transport; direct hydraulic disposal; hydraulic disposal with natural head; hydraulic disposal with artificial head; pneumatic disposal with mechanical surface transport; pneumatic disposal with mechanical ...

1983-01-01

242

Test of electron beam technology on Savannah River Laboratory low-activity aqueous waste for destruction of benzene, benzene derivatives, and bacteria  

Energy Technology Data Exchange (ETDEWEB)

High energy radiation was studied as a means for destroying hazardous organic chemical wastes. Tests were conducted at bench scale with a {sup 60}Co source, and at full scale (387 l/min) with a 1.5 MV electron beam source. Bench scale tests for both benzene and phenol included 32 permutations of water quality factors. For some water qualities, as much as 99.99% of benzene or 90% of phenol were removed by 775 krads of {sup 60}Co irradiation. Full scale testing for destruction of benzene in a simulated waste-water mix showed loss of 97% of benzene following an 800 krad dose and 88% following a 500 krad dose. At these loss rates, approximately 5 Mrad of electron beam irradiation is required to reduce concentrations from 100 g/l to drinking water quality (5 {mu}g/l). Since many waste streams are also inhabited by bacterial populations which may affect filtering operations, the effect of irradiation on those ...

1993-08-01

243

Radionuclide release rates from spent fuel for performance assessment modeling  

Energy Technology Data Exchange (ETDEWEB)

In a scenario of aqueous transport from a high-level radioactive waste repository, the concentration of radionuclides in water in contact with the waste constitutes the source term for transport models, and as such represents a fundamental component of all performance assessment models. Many laboratory experiments have been done to characterize release rates and understand processes influencing radionuclide release rates from irradiated nuclear fuel. Natural analogues of these waste forms have been studied to obtain information regarding the long-term stability of potential waste forms in complex natural systems. This information from diverse sources must be brought together to develop and defend methods used to define source terms for performance assessment models. In this manuscript examples of measures of radionuclide release rates from spent nuclear fuel or analogues of nuclear fuel are presented. ...

1994-11-01

244

Pore size distribution, strength, and microstructure of portland cement paste containing metal hydroxide waste  

Energy Technology Data Exchange (ETDEWEB)

Stabilization/solidification of hazardous wastes is used to convert hazardous metal hydroxide waste sludge into a solid mass with better handling properties. This study investigated the pore size development of ordinary portland cement pastes containing metal hydroxide waste sludge and rice husk ash using mercury intrusion porosimetry. The effects of acre and the addition of rice husk ash on pore size development and strength were studied. It was found that the pore structures of mixes changed significantly with curing acre. The pore size shifted from 1,204 to 324 {angstrom} for 3-day old cement paste, and from 956 to 263 {angstrom} for a 7-day old sample. A reduction in pore size distribution for different curing ages was also observed in the other mixtures. From this limited study, no conclusion could be made as to any correlation between strength development and porosity. 10 refs., 6 figs., 3 tabs.

1996-12-31

245

Laboratory studies of gas generation and potential for tank wall corrosion during blending of high-level wastes at the West Valley Demonstration Project  

Energy Technology Data Exchange (ETDEWEB)

Laboratory experiments were conducted to simulate the transfer of acidic THOREX waste from Tank 8D-4 into the alkaline PUREX waste in Tank 8D-2 at West Valley. The purpose of the experiments was to explore means of minimizing the production of nitric oxide (NO) gas during mixing of the two wastes and to assess the potential for the gas to further react in the vapor space possibly leading to enhanced corrosion of the tank walls. Forty one THOREX/PUREX mixing tests were conducted to explore the effects of stirring rate, pH, THOREX addition rate, THOREX or PUREX dilution, and temperature. The two most important criteria for minimizing NO production were to maintain some degree of agitation and the keep the pH in the PUREX high, preferably >12. Steel corrosion tests were performed in the presence of low partial pressures of NO{sub 2} and liquid water or water vapor. The NO{sub 2} (from oxidation of NO in ...

1995-05-01

246

Introduction of microbial nutrients in a nuclear fuel waste disposal vault as a result of excavation and operation activities  

International Nuclear Information System (INIS)

A nuclear fuel waste disposal vault would not likely be a sterile environment. Bacterial activity would be expected in those areas of the vault conducive to bacterial life, i.e., where effects of heat, moisture content, radiation and compaction would not prevent or severely restrict bacterial life and where suitable and sufficient nutrients would be present. An inventory of bacterial nutrients that would be emplaced 'intentionally' with vault materials (fuel waste, waste containers, buffer and backfill materials) has been made previously. This report assesses bacterial nutrients that would be added 'inadvertently' to a vault in the form of residues of materials used to excavate and operate a vault. Measurements of blasting material residues in the various water supplies, excavated broken rock (muck) and in cores drilled in old and new tunnel walls were made at AECL's Underground Research Laboratory. ...

1987-08-27

247

Integration of advanced nuclear materials separation processes  

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the ...

1998-12-31

248

EDF waste packages transport and compliance with regulations: prediction of retention of radionuclides by cementitious materials  

International Nuclear Information System (INIS)

Different concrete waste packages have been designed by Electricite de France (EDF) for the long-term storage of radioactive Low Level Waste (LLW). Their main function is to confine radionuclides from the biosphere for three hundred years in a near-surface disposal. According to the transport regulations, a Type-B package is needed for some waste like water filters. The water filters from EDF nuclear power plants are encapsulated in mortar and placed in a concrete container. Transport regulations for these containers have required the development of a methodology for safety assessment. The reference scenario of container degradation during transport considers a 9 m drop and a 800"oC fire for 30 min. First, the different chemical and physical processes involved in the containment of radionuclides are analysed. In particular, the radionuclide transport mechanisms in cement-based materials have been reviewed. Secondly, the ...

249

Development of pyrometallurgical partitioning of transuranium elements from high-level liquid waste. Improvement to pyrometallurgical partitioning process and process demonstration  

Energy Technology Data Exchange (ETDEWEB)

The partitioning of transuranium elements (TRUs) from high-level liquid waste (HLLW) through the use of pyrometallurgical technology has been underway since 1986, for the purpose of the improving the safety and public acceptance of the disposal of high-level vitrified waste. Prior to the pyrometallurgical partitioning process, the alkali metals can be separated at the denitration process for oxide conversion of HLLW, chlorination in a chloride salt bath can be used to effectively convert oxides to chlorides, and evaporated chlorides can be captured with high efficiency in another adopted chloride salt bath. The higher separation factors between actinides and rare earths are obtained in a LiCl-KCl/Bi system than in a LiCl-KCl/Cd system. Based on the results, we propose a practical process flow for partitioning TRUs from HLLW by pyrometallurgical technology. This process was demonstrated successfully using simulated purex ...

1998-10-01

250

Combustion of biodiesel fuel produced from hazelnut soapstock/waste sunflower oil mixture in a Diesel engine  

International Nuclear Information System (INIS)

Biodiesel is considered as an alternative fuel to Diesel fuel No. 2, which can be generally produced from different kinds of vegetable oils. Since the prices of edible vegetable oils are higher than that of Diesel fuel No. 2, waste vegetable oils and non-edible crude vegetable oils are preferred as potential low priced biodiesel sources. In addition, it is possible to use soapstock, a by-product of edible oil production, for cheap biodiesel production. In this study, a methyl ester biodiesel was produced from a hazelnut soapstock/waste sunflower oil mixture using methanol, sulphuric acid and sodium hydroxide in a two stage process. The effects of the methyl ester addition to Diesel No. 2 on the performance and emissions of a four cycle, four cylinder, turbocharged indirect injection (IDI) Diesel engine were examined at both full and partial loads. Experimental results showed that the hazelnut ...

2005-03-01

251

Amelioration of acidic coal mine overburden from Collie, Western Australia  

Energy Technology Data Exchange (ETDEWEB)

Rehabilitation of open-cut coal mining spoils at Collie, Western Australia, requires amelioration before adequate survival and growth of rehabilitation species can occur. Lolium ridgidum was used in a greenhouse pot experiment to assess the ability of lime (CaCO/sub 3/) and two waste-products of regional industry, bauxite processing caustic waste (red mud) and timber milling refuse (sawdust), to render the low pH spoils suitable for plant growth. CaCO/sub 3/ at 1% and red mud at 18% were both effective in reducing acidity and levels of available Al in the overburden. Red-mud treatment produced 10-fold increases in plant dry matter accumulation over the CaCO/sub 3/ treatment when no fertilizer was used. This is due to the presence of significant amounts of phosphorus in the red mud. With additions of a balanced NPK fertilizer at 0.077%, CaCO/sub 3/ treatment produced the best plant growth in this overburden. The re-use of ...

1983-09-01

252

Acceptable requirement of decontamination factor for LLW disposal of PEACER pyro-processing wastes  

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyro-processing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet below dose constraint ...

2007-09-09

253

Acceptable decontamination factor for near-surface disposal of PEACER wastes  

Energy Technology Data Exchange (ETDEWEB)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet below dose constraint ...

2005-11-15

254

Acceptable decontamination factor for near-surface disposal of PEACER wastes  

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet below dose constraint ...

2005-11-01

255

APEX accelerator cycle for transmutation of long-lived fission wastes  

Energy Technology Data Exchange (ETDEWEB)

Based on preliminary studies, some conclusions can be drawn concerning the Accelerator Fuel Enricher and Fission Product Exterminator (APEX). APEX-1 and APEX-2 systems can destroy TU's, /sup 137/Cs, and /sup 90/Sr at acceptable cost and efficiency. The principal difference between APEX-1 and APEX-2 is the in-reactor and in-circuit inventory of /sup 137/Cs and /sup 90/Sr. Stable and low hazard wastes can be disposed of by burial. Accelerator breeders can effectively sustain a fission reactor economy indefinitely. Military waste can be blended into commercial fuel cycle for transmutation. Accelerator and target technologies appear practical and could be developed in a few years. More detailed studies are needed to better define the technical and economic features of the LAFER and APEX cycles, so that comparative assessments can be made between these cycles, as well as with other transmutation and ...

1980-01-01

256

Synthesis and electrochemical properties of lithium ion conductive glass, Li[sub 3]PO[sub 4]-Li[sub 2]S-SiS[sub 2  

Energy Technology Data Exchange (ETDEWEB)

As a continuation of our previous study, further experiments were performed on Li[sub 3]PO[sub 4]-Li[sub 2]S-SiS[sub 2] lithium ion conductive glass. In the present study, we employed a twin roller for quenching process instead of liquid nitrogen. We found that the glass forming region expands by twin roller technique and conductivity up to 1.5x10[sup -3] S/cm was achieved. Structural analysis on the glass revealed that Li[sub 3]PO[sub 4] doping changes the glass structure of Li[sub 2]S-SiS[sub 2], thereby enhancing the electrical conductivity

1994-02-01

257

Study on the crystallization behaviour and thermal stability of glass-ceramics used as solid oxide fuel cell-sealing materials  

British Library Electronic Table of Contents (United Kingdom)

Glass ceramics are commonly used as sealing materials for planar solid oxide fuel cells (SOFCs). The major requirements of stack and module builders for these materials are the stability of the coefficient of thermal expansion (CTE), excellent bonding (sticking) behaviour and the absence of volatile ingredients, which can lead to changes of the material properties and the sealing ability. SCHOTT Electronic Packaging has developed special glasses and glass-ceramics for various solid oxide fuel cell designs and operating temperatures. The glass compositions are based on the system MgO-Al2O3-BaO-SiO2-B2O3. In this study the evaluation of the developed materials was done by high temperature aging tests for up to 1000h, high temperature XRD-studies and Rietveld calculations, combined with scann...

2011-01-01

258

Molten glass corrosion resistance of immersed combustion-heating tube materials in E-glass  

International Nuclear Information System (INIS)

The corrosion resistance of molybdenum, molybdenum disilicide, and a SiC_(_p_)/Al_2O_3 composite to molten E-glass at 1,550 C was studied. Mo showed no tendency to oxidize as it was immersed in soda-lime silicate glass in a parallel study. MoSi_2 was corroded by soluble molecular oxygen, leaving a Mo_5Si_3 interface behind. The SiC_(_p_)/Al_2O_3 composite was corroded at a more rapid rate wherein the SiC component was oxidized to form amorphous silica and CO bubbles. Based on these results, the activity of soluble molecular oxygen in E-glass was determined to be in the range of 2.4 x 10"-"1"4 to 2.0 x 10 "-"8.

259

Evidence of network demixing in GeS2-Ga2S3 chalcogenide glasses: A phase transformation study  

International Nuclear Information System (INIS)

The information of phase transformation is attained by in situ XRD experiments leading to the knowledge of topological threshold in GeS2-Ga2S3 glasses. The turning point of phase transformation behavior is demonstrated to be glasses containing 14-15 mol% Ga2S3. To interpret it a network demixing model is further improved and proposed for the structure of these ternary or quasi-binary chalcogenide glasses. For the nearest-neighbor coordination environment of glass with a transitional composition of 85.7 mol% (6/7) GeS2.14.3 mol% (1/7) Ga2S3, six-coordinated [S3Ga-X-GaS3] units (X=S or None) are well isolated by the [GeS4] structures, which contributes to the decreasing of precipitation of Ga2S3 crystals in (100-x)GeS2-xGa2S3 (x?14.3) glasses corresponding to the experimental evidence of the phase transformation behavior. This scenario of intermediate-range structural order, firstly, ...

2011-03-01

260

Electrochemical properties for the lithium ion conductive (100-x)(0.6Li{sub 2}S{center{underscore}dot}0.4SiS{sub 2}){center{underscore}dot}xLi{sub 4}SiO{sub 4} oxysulfide glasses  

Energy Technology Data Exchange (ETDEWEB)

Thermal, electrical, and electrochemical properties were investigated for the (100-x)(0.6Li{sub 2}S{center{underscore}dot}0.4SiS{sub 2}){center{underscore}dot}xLi{sub 4}SiO{sub 4} oxysulfide glasses. The glass with x = 5 exhibited high electrical conductivity of about 10{sup {minus}3} S cm{sup {minus}1} at room temperature, high glass stability against crystallization, and good chemical stability in contact with Li metal. Cyclic voltammetry also suggested that this glass has a wide electrochemical window of more than 10 V. On the other hand, further addition of Li{sub 4}SiO{sub 4} up to 20 mol% lowered the conductivity, glass stability against crystallization, and electrochemical stability for the oxysulfide glasses.

1999-09-01

261

BNFL Report Glass Formers Characterization  

Energy Technology Data Exchange (ETDEWEB)

The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten ...

2000-07-27

262

European Commission - Environment  

Wastenet

...Species - see CITES Trade of Dangerous Chemicals Transport and Environment U Urban Environment Use of natural resources V Volatile Organic Compounds W Waste Landfills Waste electrical and electronic equipment - see WEEE Waste incineration Waste legislation - reporting Waste management planning Waste oils Waste shipments Waste water - see Urban waste water Water Bathing Water Drinking water Floods Marine environment Urban waste water Water Framework Directive WEEE - Waste Electric and Electronic Equipment Wildlife ...

263

Bioenergy from waste. Working Group Report; Biohajoavista jaetteistae enemmaen energiaa. Biojaete-energiatyoeryhmaen raportti  

Energy Technology Data Exchange (ETDEWEB)

On 7 May 2009, the Ministry of the Environment set up a working group to evaluate the possible use of biodegradable waste and other biodegradable material flows for energy production and obstacles to promoting their use in the whole production cycle. The deadline for the working group was 31 January 2010. According to its mandate, the working group had to make proposals for the measures needed to promote the energy use of biodegradable waste in order to fulfil the targets of the Government Foresight Report on Long-term Climate and Energy Policy. The working group proposes thirteen measures to be put into operation so that the investments aimed at the energy use of biodegradable waste would grow significantly from the present level. The most important measure is a full ban on depositing biodegradable waste in landfills. The working group sees that the reduction of greenhouse gas emissions from landfills ...

2010-02-15

264

Studies on slag deposit formation in pulverized-coal combustors. 5. Effect of flame temperature, thermal cycling of the steel substrate and time on the adhesion of slag drops to oxidized boiler steels  

Energy Technology Data Exchange (ETDEWEB)

The effect of flame temperature on the Moza-Austin sticking test has been evaluated by increasing the adiabatic flame temperature used to melt the pellet and make it drop. It was found that the variation of apparent contact angle with substrate temperature, for an oxidized steel substrate, was almost independent of flame temperature over the range of 1750-2500 C. However, the strength of adhesion to the substrate increased with higher flame temperature at each substrate temperature. The adhesion force of a drop frozen on the substrate at constant temperature also increased with time up to about one h. This indicated that the adhesion was not caused solely by mechanical anchoring of solidified glass in the pores of the oxide layer. Reduction of the substrate temperature to lower temperatures after attachment of the drop caused lower strength of adhesion, but this was partially restored by raising the temperature. This also suggested a continuing ...

1985-06-01

265

"1"5"1Eu-Moessbauer study of complex magnetism in Eu_2PdSi_3: Effect of Eu"2"+ substitution by Y"3"+ and of high pressure  

International Nuclear Information System (INIS)

With "1"5"1Eu-Moessbauer spectroscopy and other methods the complex magnetic properties of Eu_2PdSi_3, arising from the two crystallographically different lattice sites of the Eu"2"+ ions, have been already studied. Here we study the impact of magnetic dilution of the magnetic Eu"2"+ sites by non-magnetic Y"3"+ ions. A previous specific heat study has found reduced magnetic ordering temperatures with strong indication of disorder effects like in magnetic spin glasses. Here we provide from "1"5"1Eu-Moessbauer spectroscopy detailed information of the impact of Y"3"+ substitution on the magnetic properties of the two lattice sites, well distinguishable in the "1"5"1Eu-spectra. Since the substitution of the larger Eu"2"+ ions by the smaller Y"3"+ ions is connected with a lattice contraction, we also applied high pressure to the Eu_2PdSi_3 sample and observed drastic changes in the magnetic properties originating from a valence transition towards ...

2010-03-01

266

Tritium contamination and decontamination study on materials for ITER remote handling equipment  

Energy Technology Data Exchange (ETDEWEB)

Several materials, lenses, dry bearings and cables were exposed to a tritiated moisture environment to study the behavior of tritium contamination on candidate materials for ITER remote handling equipment. To optimize the tritium removal procedure, decontamination experiments using a gas purge with three different moisture concentrations were also performed. The surface tritium concentrations of CeO{sub 2} containing alkaline barium glass (NB), CeO{sub 2} containing lead glass (LX) and synthetic quartz (Quartz) after the exposure experiments were 7.80, 10.94 and 0.67 Bq/cm{sup 2}, respectively. It was found that the tritium concentration was influenced by the compositions of the materials. The concentrations of tritium on type 831 (solid lubrication material: graphite) and type 237 (solid lubrication material: tungsten disulfate) dry bearings after the exposure experiments were 89.80 and 31.78 Bq/cm{sup 2}, respectively. The tritium ...

2001-09-01

267

Tritium contamination and decontamination study on materials for ITER remote handling equipment  

International Nuclear Information System (INIS)

Several materials, lenses, dry bearings and cables were exposed to a tritiated moisture environment to study the behavior of tritium contamination on candidate materials for ITER remote handling equipment. To optimize the tritium removal procedure, decontamination experiments using a gas purge with three different moisture concentrations were also performed. The surface tritium concentrations of CeO_2 containing alkaline barium glass (NB), CeO_2 containing lead glass (LX) and synthetic quartz (Quartz) after the exposure experiments were 7.80, 10.94 and 0.67 Bq/cm"2, respectively. It was found that the tritium concentration was influenced by the compositions of the materials. The concentrations of tritium on type 831 (solid lubrication material: graphite) and type 237 (solid lubrication material: tungsten disulfate) dry bearings after the exposure experiments were 89.80 and 31.78 Bq/cm"2, respectively. The tritium concentration in an electric ...

2001-09-01

268

Synthesis of c-axis preferred orientation ZnO:Al transparent conductive thin films using a novel solvent method  

International Nuclear Information System (INIS)

Transparent aluminum doped zinc oxide (ZnO:Al, AZO) conducting thin films with a high-preferential c-axis orientation were synthesized using a new sol-gel formula. The films were deposited using a spin-coating route onto borosilicate glass substrates. We used propylene glycol methyl ether (PGME) as the solvent in place of ethylene glycol monomethyl ether (EGME), which is commonly used because it is easier to deposit onto the substrates. PGME is also superior in terms of health and safety. PGME solvent does not need to settle for several days before use and can be spin-coated as soon as the raw material and solvent are mixed. The effects of this novel solvent on the structural, morphological, electrical and optical properties are discussed using XRD, SEM, a four-point probe and UV-VIS spectrophotometry. It was found that the films produced with PGME showed a high-preferential c-axis orientation and compact microstructure in comparison films ...

2010-09-01

269

Processing of exhausted resins for Trino NPP,  

International Nuclear Information System (INIS)

Decomposition of organic compounds contained in the spent ion exchange resins is considered effective in reducing the waste volume. A system using the wet-oxidation process has been studied for the treatment of the spent resins stored at Trino Nuclear Power Plant owned by SOGIN. Compared with various processes for treating sludge and resin, the wet-oxidation system is rather simple and the process conditions are mild. Not contaminated ion exchange resin samples similar to those ones used in Trino NPP were processed by wet-oxidation and appropriate decomposition of the organic compounds was verified. After decomposition the residue can be solidified with cement for final disposal. When compared with direct solidification without decomposition, the number of waste packages can be significantly reduced. Additional measures for conditioning secondary waste products have also been studied, and their ...

2009-10-12

270

Los Alamos second-generation system for passive and active neutron assays of drum-size containers  

International Nuclear Information System (INIS)

We describe in a comprehensive fashion the Los Alamos second-generation system for passive and active neutron assays of drum-size containers. The developmental history of this 7-year project is presented with emphasis on the pulsed active neutron technique (differential dieaway), which has achieved milligram levels of assay sensitivity for both plutonium and uranium wastes. We describe in detail the matrix effects for both passive and active neutron assays. We present in a thorough fashion our novel approach to achieving comprehensive corrections for these matrix effects using measurements made during the assays. We develop a matrix correction formalism based on separate neutron absorption and moderator indices determined from these measurements. These are presented as a series of analytic functions fitted to the data. Absolute calibrations and calibration standards are discussed, as is a practical means (pink drum ...

1972-09-17

271

Assessing plantation biomass for co-firing with coal in northern Indiana: a linear programming approach  

Energy Technology Data Exchange (ETDEWEB)

Tightening environmental regulations and the signing of the Kyoto protocol have prompted electric utilities to consider co-firing biomass with coal to reduce the levels of CO{sub 2}, SO{sub 2} and NOx in stack emissions. This analysis examines the cost competitiveness of plantation produced woody biomass and waste wood with coal in electricity production. A case study of woody biomass production and co-firing in northern Indiana is presented. A linear programming model was developed to examine the optimal co-firing blend of coal and biomass while minimizing variable, cost, including the cost of ash disposal and material procurement costs. This model was used to examine situations where coal is the primary fuel and waste wood, willow trees, or both are available for fuel blending. The results indicate that co-firing woody biomass is cost-effective for the power plant. Sensitivity analysis explored the ...

2000-07-01

272

Subsurface Injection of Liquid Waste  

Science.gov (United States)

... Other Sources Toxics Intranet Subsurface Injection of Liquid Waste -- Florida Surface features of a typical...

274

Radiation protection and the management of radioactive waste in the oil and gas industry  

CERN Document Server

Radiation protection and the management of radioactive waste in the oil and gas industry

2003-01-01

276

On-site burning, remote camp  

Science.gov (United States)

... wood, kitchen wastes, and human faeces. The ash from such waste burning shall be deposited and ...

277

Liquid Radioactive Wastes Processing  

International Science & Technology Center (ISTC)

Methods of Decontamination, Utilization, and Deactivation of Liquid Radioactive Wastes

278

IEE, accelerated waste mgt, McM  

Science.gov (United States)

... in ATCM Recommendation XIV-2. The USAP's materials and waste management efforts are consistent with ...

279

Human Waste Handling-Kooyman  

Science.gov (United States)

... wood, kitchen wastes, and human faeces with the ash from such burning deposited and retained in an ...

280

Dioxins in the Baltic sea  

Wastenet

for municipal waste iron ore sinter plants incinerators for clinical waste facilities of the non-ferrous metal

281

Combustion of Crop Production Wastes  

International Science & Technology Center (ISTC)

Development, Investigation and Improvement of a System of Incinerating Crop Production Wastes in Small Capacity Boilers

283

Ten-year cleanup of U.S. Department of Energy weapon sites: The changing roles for technology development in an era of privatization  

Energy Technology Data Exchange (ETDEWEB)

In its beginning, the U.S. Department of Energy (DOE) Office of Environmental Management (EM) viewed private industry as lacking adequate technology know-how to meet demands of hazardous and radioactive waste problems at the DOE`s laboratories and nuclear weapons production facilities. In November 1989, EM`s Office of Technology Development (recently renamed the Office of Science and Technology) embarked on a bold program of developing and demonstrating {open_quotes}innovative{close_quotes} waste cleanup technologies that would be safer, faster, more effective, and less expensive than the {open_quotes}baseline{close_quotes} commercial methods. This program has engaged DOE sites, national laboratories, and universities to produce preferred solutions to the problems of handling and treating DOE wastes. More recently, much of this work has shifted to joint efforts with private industry partners to ...

1996-12-31

284

Evaluation of the impact of RCRA amendments on waste-to-energy activities by using a system simulation computer code  

Energy Technology Data Exchange (ETDEWEB)

The primary methodology that is used for disposal of municipal solid waste is the use of land fills; 80--85% of the municipal solid waste (MSW) produced in the country currently is land filled. The two other disposal alternatives used are recycling and incineration. Waste-to-energy technology (WTE) which incinerates MSW to produce electricity and/or steam is attractive in other cases since it reduces landfill volume, reduces the consumption of fossil and other fuels, and produces a revenue stream from the sale of the electricity or steam. The gaseous effluents from landfills can also be used to fuel power plants. Recycling and material separation programs can have a substantial impact on the throughput and heating value of MSW collected and thus impact WTE plant economics; the magnitude of the impact will depend upon a number of factors such as what materials and what fraction are separated and recycled, the design of the ...

1994-09-01

285

Acoustic and visual remote sensing of barrels of radioactive waste: Application of civilian and military technology to environmental management of the oceans  

Energy Technology Data Exchange (ETDEWEB)

As part of an ongoing strategic research project to find barrels of radioactive waste off San Francisco, the U.S. Navy (USN), the U.S. Geological Survey (USGS), and the Gulf of the Farallones National Marine Sanctuary (GFNMS) pooled their expertise, resources, and technology to form a partnership to verify new computer enhancement techniques developed for detecting targets the size of 55 gallon barrels on sidescan sonar images. Between 1946 and 1970, approximately 47,800 large barrels and other containers of radioactive waste were dumped in the ocean west of San Francisco; the containers litter an area of the sea floor of at least 1400 km {sup 2} knows as the Farallon Island Radioactive Waste Dump. The exact location of the containers and the potential hazard the containers pose to the environment is unknown. The USGS developed computer techniques and contracted with private industry to enhance sidescan data, collected in ...

1995-04-01

286

Transuranic contaminated waste form characterization and data base  

Energy Technology Data Exchange (ETDEWEB)

This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU waste treatment technologies.

1980-07-01

287

Process Waste Assessment for inorganic solid waste and empty containers <30 gallons  

Energy Technology Data Exchange (ETDEWEB)

This Process Waste Assessment was conducted to evaluate the two largest hazardous waste streams generated on-site at Sandia National Laboratory (SNL)/California -- ``Other Inorganic Solid Waste`` and ``Empty Containers <30 Gallons.``

1993-12-01

288

LAW ON WASTE MANAGEMENT  

Wastenet

1 to the operator of a waste collective system by an agreement or contract. The conditions for the ...Fees of the waste collective system are subject to the supervision of the authority responsible for market surveillance. ...The operator of waste collection system collects wastes from producers and holder and transports these to a collection

289

Spectral analysis of Pr3+-, Sm3+- and Dy3+-doped transparent GeO2-BaO-TiO2 glass ceramics  

British Library Electronic Table of Contents (United Kingdom)

In this paper, we present the photoluminescence properties of Pr3+-, Sm3+- and Dy3+-doped germanate glasses and glass ceramics. From the X-ray diffraction measurement, the host glass structure was determined. These glasses have shown strong absorption bands in the near-infrared (NIR) region. Compared to Pr3+-, Sm3+- and Dy3+-doped glasses, their respective glass ceramics have shown stronger emissions due to the Ba2TiGe2O8 crystalline phase. For Pr3+-doped glass and glass ceramic, emission bands centered at 530nm (3P03H5), 614nm (3P03H6), 647nm (3P03F2) and 686nm (3P03F3) have been observed with 485nm (3H43P0) excitation wavelength. Of them, 647nm (3P03F2) has shown bright red emission. Emission bands of 4G5/26H5/2 (565nm), 4G5/26H7/2 (602nm) and 4G5/26H9/2 (648nm) for the Sm3+:glass and gl...

2009-01-01

290

Uranium and thorium based phosphate matrix: synthesis, characterizations and lixiviation; Matrices a base de phosphate d'uranium et de thorium: syntheses, caracterisations et lixiviation  

Energy Technology Data Exchange (ETDEWEB)

In the framework of the search for a ceramic material usable in the radioactive waste storage, uranium and thorium phosphates have been investigated. Their experimental synthesis conditions have been entirely reviewed, they lead to the preparation of four new compounds: U(UO{sub 2})(PO{sub 4}){sub 2}, U{sub 2}O(PO{sub 4}){sub 2}, UCIPO{sub 4}, 4H{sub 2}O, and Th{sub 4}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}. Experimental evidenced are advanced for non existent compounds such as: U{sub 3}(PO{sub 4}){sub 4}, U{sub 2}O{sub 3}P{sub 2}O{sub 7} and Th{sub 3} (PO{sub 4}){sub 4}. Characterization by several techniques (X-rays and neutron powder diffractions, UV-Visible and Infra-red spectroscopies, XPS,...) were performed. The ab initio structure determination of U(UO{sub 2})(PO{sub 4}){sub 2} has been achieved by X-rays and refined by neutron diffractions. Through its physico-chemical analysis, we found that this compound was a new mixed valence uranium phosphate in which ...

1995-03-01

291

Waste management units - Savannah River Site. Volume 1, Waste management unit worksheets  

Energy Technology Data Exchange (ETDEWEB)

This report is a compilation of worksheets from the waste management units of Savannah River Plant. Information is presented on the following: Solid Waste Management Units having received hazardous waste or hazardous constituents with a known release to the environment; Solid Waste Management Units having received hazardous waste or hazardous constituents with no known release to the environment; Solid Waste Management Units having received no hazardous waste or hazardous constituents; Waste Management Units having received source; and special nuclear, or byproduct material only.

1989-10-01

292

Environmental costs and benefits case study: nuclear power plant. Quantification and economic valuation of selected environmental impacts/effects. Final report  

International Nuclear Information System (INIS)

This case study is an application, to a nuclear power plant, of the methodology for quantifying environmental costs and benefits, contained in the regional energy plan, adopted in April, 1983, by the Northwest Power Planning Council, pursuant to Public Law 96-501.The study is based on plant number 2 of the Washington Public Power Supply System (WNP-2), currently nearing completion on the Hanford Nuclear Reservation in eastern Washington State. This report describes and documents efforts to quantify and estimate monetary values for the following seven areas of environmental effects: radiation/health effects, socioeconomic/infrastructure effects, consumptive use of water, psychological/health effects (fear/stress), waste management, nuclear power plant accidents, and decommissioning costs. 103 references.

293

Off-gas behavior in the HARVEST pot vitrification process  

Energy Technology Data Exchange (ETDEWEB)

A summary of the off-gas behavior in the HARVEST pot vitrification process is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The main volatile elements were Ru, B, Cs. Some volatility was also shown by Na and Li. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) proceses involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The Ru volatility correlated directly with ...

1983-06-01

294

Fabrication of zircon for disposition of weapons plutonium  

International Nuclear Information System (INIS)

This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). In an effort to address the problems of long term storage and nuclear waste minimization, zircon has been proposed as a host medium for plutonium and other actinides recovered from dismantled nuclear weapons. The objective of this work is to investigate the feasibility of large scale fabrication of Pu-bearing zircon. Since PuO_2 is thermodynamically less stable than ZrO_2, it is expected that the process parameters determined for synthesizing ZrSiO_4 (zircon) would be applicable to those for PuSiO_4 (Pu-zircon). Furthermore, since the foremost concern in plutonium processing is the potential for contamination release, this work emphasizes the development of process parameters, using zircon first, to anticipate potential material problems in the containment system for reaction mixtures during processing. Stoichiometric ...

295

Sorption of gold by activated charcoal from cyan-containing solutions of complex salt composition  

Energy Technology Data Exchange (ETDEWEB)

An evaluation was made of the effectiveness of the action of reagents used for cleaning cyan-containing waste water for conditioning of the overflow of copper concentrate thickners of the Belousovskiy enrichment before sorption extraction of gold by activated charcoal. It was established that conditioning of the overflow by iron sulfates (II), copper and zinc diminshes, and by hypochlorite increases the capacitance of the activated charcoal for gold.

1982-01-01

296

Measurements of radioactivity in Jamaican building materials and gamma dose equivalents in a prototype red mud house  

International Nuclear Information System (INIS)

Concentrations of 226Ra, 232Th, and 40K measured in bauxite waste, local building materials, and soils are presented and used in model equations to estimate the effective gamma dose-equivalent increments over background in the center of a standard-sized room in a prototype house. Calculated and measured values compare reasonably well.

297

Experimental verification of caustic-side solvent extraction for removal of cesium from tank waste.  

Energy Technology Data Exchange (ETDEWEB)

The objectives of this report are: to demonstrate complete CSSX process flowsheet (proof of concept)--decontamination factor {ge} 40,000, and concentration factor {approx}15; Scientific and technical issues evaluated--stage efficiency, temperature control, hydraulic performance, long time (multi-day) operation, short-term shutdown, effect of solids, and recovery from Cs moving through strip section.

2001-09-21

298

Effect of calcination and physico-chemical properties of red mud  

Energy Technology Data Exchange (ETDEWEB)

Physico-chemical studies were carried out on a sample of red mud collected from NALCO, Orissa, after calcination up to 1,200 C at an interval of 100 C. The observed change in properties like surface area, particle size, bulk density and mineral phases etc., can be profitably used while finding an appropriate application of this polluting waste from alumina plants.

1996-10-01

299

Effect of areal power density and relative humidity on corrosion resistant container performance  

Energy Technology Data Exchange (ETDEWEB)

The impact of the rewetting process on the performance of waste containers at the Yucca Mountain repository is analyzed. This paper explores the impact of the temperature-humidity relationships on pitting corrosion failure of stainless steel containers for different areal power densities (APDs)in the repository. It compares the likely performance of containers in a repository with a low APD, 55 Kw/acre, and a high APD, 110 kW/acre.

1994-10-01

300

Cost-effectiveness analysis of final effluent limitations guidelines and standards of performance for the offshore oil and gas industry  

International Nuclear Information System (INIS)

The EPA proposed effluent limitations guidelines and standards for the offshore segment of the oil and gas industry on August 26, 1985. On November 26, 1990, and March 13, 1991, the Agency reproposed effluent limitations guidelines and standards for both drilling and production wastes. The report is primarily concerned with the total annualized cost incurred by the offshore oil and gas industry in complying with the regulations.

1993-01-01

301

Application of remote sensing for coal waste embankment monitoring  

Energy Technology Data Exchange (ETDEWEB)

The Bureau of Mines has two projects in the remote sensing field as it pertains to mining. One of these is a completed contract that studied the use of aircraft mounted cameras and the results of photogrammetry. The second project is an ongoing contract to study the effectiveness of using an instrumentation system wired to remote data collection station to record embankment data. 6 refs.

1981-01-01

302

Materials used in new generation vehicles: supplies, shifts, and supporting infrastructure  

Energy Technology Data Exchange (ETDEWEB)

The Partnership for a New Generation of Vehicles (PNGV) program intends to develop new designs for automobiles that will reduce fuel consumption by two thirds but otherwise have price, comfort, safety, and other measures of performance similar to the typical automobile now on the market. PNGV vehicle designs are expected to substitute lightweight materials, such as aluminum, magnesium, carbon-reinforced polymer composites, glass-reinforced polymer composites, and ultra- light steel, for heavier materials such as steel and iron in automobile components. The target mass of a PNGV vehicle is 1,960 pounds, as compared to the average current vehicle that weights 3,240 pounds. Other changes could include the use of different ferrous alloys, engineering changes, or incorporation of advanced ceramic components. Widespread adoption of these vehicle designs would affect materials markets and require concurrent development and adoption of supporting technologies to supply the ...

1997-08-01

303

Enhancement of glass-forming ability and bio-corrosion resistance of Zr-Co-Al bulk metallic glasses by the addition of Ag  

International Nuclear Information System (INIS)

A novel Ni and Cu-free Zr-based bulk metallic glass (BMG) system with enhancement of glass-forming ability (GFA) and bio-corrosion resistance was prepared by copper mold casting by the addition of Ag. It was found that the addition of Ag can considerably enhance the glass-forming ability, as indicated by the increase of the critical glass dimension from 3 mm diameter of the ternary system to over 10 mm in the alloy of Zr_5_3Co_1_8_._5Al_2_3_._5Ag_5. The bio-corrosion behaviors of the Zr-based BMGs in phosphate buffered solution (PBS) were investigated by electrochemical polarization at 310 K. It was found that the addition of appropriate amount of Ag can enhance the corrosion resistance of the BMGs. The X-ray photoelectron spectroscopy (XPS) indicated that the formation of an Al_2O_3-enriched passive film is mainly responsible for the high corrosion resistance of Ag-bearing alloy in phosphate buffered ...

2010-08-01

304

EPR and FT-IR spectroscopic studies of Bi2O3-B2O3-CuO glasses  

International Nuclear Information System (INIS)

EPR and FT-IR absorption measurements have been performed for xCuO.(100-x)[2Bi2O3.B2O3] glass system, with 0?x?50 mol%. The mode in which the addition of the copper ions influences the structure of 2Bi2O3.B2O3 glass matrix was analyzed. The EPR absorption spectra revealed the presence in the glass structure of Cu2+ ions in axially distorted octahedral environments. EPR data pointed out the simultaneous presence of Cu2+ and Cu+ ionic species in the glasses with x?5 mol%. For x>10 mol%, the Cu2+ ions participate in the superexchange magnetic interactions, which increase with CuO content. The FT-IR spectra showed the presence of some bands that are assigned to vibrations of Bi-O bonds from BiO3 pyramidal and BiO6 octahedral units and B-O bonds from BO3 and BO4 units. The data obtained by these measurements reveal the structural changes in the 2Bi2O3.B2O3 glass matrix by controlled ...

2008-10-01

305

Direct observation of radial distribution change during tensile deformation of metallic glass by high energy X-ray diffraction method  

International Nuclear Information System (INIS)

The purpose of this research is to investigate the micro-mechanism of deformation behavior of metallic glasses. We report the results of direct observations of short-range and medium-range structural change during tensile deformation of metallic glasses by high energy X-ray diffraction method. Cu50Zr50 and Ni30Zr70 metallic glass samples in the ribbon shape (1.5 mm width and 25 ?m) were made by using rapid quenching method. Tensile deformation added to the sample was made by using special equipment adopted for measuring the high energy X-ray diffraction. The peaks in pair distribution function g(r) for Cu50Zr50 and N30iZr70 metallic glasses move zigzag into front and into rear during tensile deformation. These results of direct observation on atomic distribution change for Cu50Zr50 and Ni30Zr70 metallic glass ribbons during tensile deformation suggest that the micro-relaxations ...

2009-08-26

306

W1045 environment surf drip shield and waste package outer barrier  

Energy Technology Data Exchange (ETDEWEB)

The environments on the drip shield and waste package outer barrier are controlled by the compositions of the waters that contact these components. the temperature (T) of these components, and the effective relative humidity (RH) at these components. Because the composition of the waters that are expected to enter the emplacement drifts (either by seepage flow or by episodic flow) have not been specified: well J13 water was chosen as the reference water (Harrar 1990). Section 6.2 discusses the accessible RH for the temperatures of interest at the repository horizon. Section 6.3 discusses the adsorption of water on metal alloys in the absence of hygroscopic salts. Because the temperatures of the DSs and the WPOBs are higher than those of the surrounding near-field environment, the relative humidity at the DSs and the WPOBs will be lower than that of the surrounding near-field environment. This difference is a result of the water partial pressure ...

1999-07-14

307

Use of post-consumer waste plastics in cement-based composites  

Energy Technology Data Exchange (ETDEWEB)

This paper describes an innovative use of post-consumer waste HDPE plastic in concrete as a soft filler. A reference concrete was proportioned to have the 28-day compressive strength of 5000 psi (35 MPa). A high-density plastic was shredded into small particles for use in the concrete. These particles were subjected to three chemical treatments (water, bleach, bleach + NaOH) to improve their bonding with the cementitious matrix. The plastic particles were added to the concrete in the range of 0--5% of total mixture by weight. Compressive strengths were measured for each test mixture. The results showed that chemical treatment has a significant effect on performance of the plastic filler in concrete. Of the three treatments used on the plastic, the best performance was observed with the alkaline bleach treatment (bleach + NaOH) with respect to compressive strength of concrete.

1996-10-01

308

Thermo-Hydro Mechanical Characteristics and Processes in the Clay Barrier of a High Level Radioactive Waste Repository. State of the Art Report  

International Nuclear Information System (INIS)

This document is a summary of the available information on the thermo-hydro-mechanical properties of the bentonite barrier of a high-level radioactive waste repository and of the processes taking place in it during the successive repository operation phases. Mainly the thermal properties, the volume change processes (swelling and consolidation), the permeability and the water retention capacity are analysed. A review is made of the existing experimental knowledge on the modification of the these properties by the effect of temperature, water salinity, humidity and density of the bentonite, and their foreseen evolution as a consequence of the processes expected in the repository. The compiled evolution refers mostly to the FEBEX (Spain), the MX-80 (USA) and the FoCa (France) bentonite, considered as reference barrier materials in several European disposal concepts. (Author) 102 refs.

2004-05-01

309

Quality assurance considerations in nuclear waste management  

International Nuclear Information System (INIS)

Proper use of quality assurance will provide the basis for an effective management control system for nuclear waste management programs. Control is essential for achieving successful programs free from costly losses and failures and for assuring the public and regulators that the environment and health and safety are being protected. The essence of quality assurance is the conscientious use of planned and systematic actions, based on selecting and applying appropriate requirements from an established quality assurance standard. Developing a quality assurance program consists of using knowledge of the technical and managerial aspects of a project to identify and evaluate risks of loss and failure and then to select appropriate quality assurance requirements that will minimize the risks. Those requirements are integrated into the project planning documents and are carried out as specific actions during the life of the project.

310

Phase chemistry and radionuclide retention of high level radioactive waste tank sludges  

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate groundwaters with radionuclides and RCRA metals. Experimentation on such sludges is both dangerous and prohibitively expensive so there is a great advantage to developing artificial sludges. The US DOE Environmental Management Science Program (EMSP) has funded a program to investigate the feasibility of developing such materials. The following text reports on the success of this program, and suggests that much of the radioisotope inventory left in a tank will not move out into the surrounding environment. Ultimately, such studies may play a significant role in developing safe and cost effective tank closure strategies.

2000-05-19

311

Leaching characteristics of paraffin waste package with pinhole  

International Nuclear Information System (INIS)

An Effect of pinhole(perforation or pit penetration) that might be formed outside the package on the nuclide leaching from paraffin waste form was investigated. In case of single pinhole, the leached mass and cumulative fraction leached (CFL) increased with the larger diameter of pinhole, but they were not in direct proportion to the size or area of pinhole. If the total area of multiple pinholes was fixed, the leached mass showed a tendency to increase as each size was smaller and the number was more. It was also found that the leached mass was not in direct proportion to the number of pinhole in case of constant size. In order to analyze the test results, the shrinking core model(SCM) was derived from the diffusion-controlled dissolution reaction and compared with previous diffusion model.

2001-05-01

312

Laboratory studies of the diffusive transport of 137Cs and 60Co through potential waste repository soils  

British Library Electronic Table of Contents (United Kingdom)

Tests using reconstituted samples have been performed to assess the diffusive transport of 137Cs and 60Co through natural regolith materials from a region in South Australia being considered for a radioactive waste repository. A double diffusion cell apparatus made of polycarbonate resin was developed to estimate the effective diffusion (De) and sorption coefficients (Kd) that allowed large withdrawals from the source and collector cells and has enabled tests with low concentrations of radioactivity. An alternative to porous stainless steel filter plates has also been used to reduce uncertainty in test interpretation. Analysis of the transient data used a staged method of the Laplace transform to take into consideration the volume of the samples withdrawn from the apparatus during testing....

2010-01-01

313

Influence of gamma irradiation on waste poly(propylene) composites containing talc and high crystallinity poly(propylene)  

British Library Electronic Table of Contents (United Kingdom)

Commercial polyolefin, such as poly(propylene), are widely used because of their easy processing and their excellent mechanical and thermal properties. Although their recycling is well established, the mechanical and thermal properties of the recycled waste poly(propylene)(WPP) are normally lower than those of the virgin material. The introduction of talc can improve the toughness, without compromising the processability and recycling capabilities. However, the thermal properties of these blends should be assessed to limit degradation during recycling. The effect of gamma radiation on the thermal and mechanical properties of WPP/High Crystallinity Poly(propylene)/Talc was studied. TGA, DSC, and electrical conductivity performed the characterization of WPP composites. Mechanical properties ...

2008-01-01

314

Coir pith-a biosorbent for removal of cesium from aqueous solutions  

International Nuclear Information System (INIS)

Coir pith (CP), an abundantly available lignocellulosic agricultural waste from the local coir industry has been found to be an effective biosorbent for removal of metal ions from aqueous solutions. Transition metal hexacyanoferrates, in particular nickel hexacyano ferrate (NiHCF) also referred to as Prussian blue analogue (PBA), is known to be highly selective for removal of cesium from aqueous solutions. A novel method for the synthesis of PBA inside the porous matrix of coir pith and use of this composite material for the sorption of cesium is described in this paper. Equilibrium experiments showed that the sorption capacity of coir pith nearly doubled due to the modification. Owing to its low cost and rapid sorption kinetics, this hybrid material seems to be one of the most promising compounds for the recovery of cesium from liquid nuclear wastes. (author)

2007-01-04

315

Biosorption of reactive dye by waste biomass of Nostoc linckia  

British Library Electronic Table of Contents (United Kingdom)

Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...

2011-01-01

316

UK's Sizewell inquiry; funny how time slips away  

Energy Technology Data Exchange (ETDEWEB)

Comments are made on the Public Inquiry into CEGB's proposal to construct a pressurized water reactor (PWR) at Sizewell, UK. Aspects discussed include: time elapsed and its possible effect on the result; economics of nuclear power plants compared with coal-fired power plants; changes in real sterling/dollar exchange rates; effect of mineworkers' strike; the UK electric power generating system; AGR reactors compared with PWR reactors; extension of Magnox reactor life; radioactive waste management; political decisions.

1985-03-01

317

The use of treated wastewater for chemlali olive tree irrigation: effects on soil properties, growth and oil quality  

Energy Technology Data Exchange (ETDEWEB)

Olive tree (Olea european L.) cultivation, the major tree crops in Mediterranean countries is being extended to irrigated lands. However, the limited water availability, the severe climatic conditions and the increased need for good water quality for urban and industrial sector uses are leading to the urgent use of less water qualities (brackish water and recycled wastewater) for olive tree irrigation. The aim of this work was to asses the effects of long term irrigation with treated waste water (TWW) on the soil chemical properties, on olive tree growth and on oil quality characteristics. (Author)

2009-07-01

318

Experimental study on the volatile ruthenium decontamination factor of the perforated plate column scrubber  

International Nuclear Information System (INIS)

During a high temperature treatment of the radioactive wastes that contain ruthenium, some ruthenium is volatilized and released to the off gas system. The volatilized ruthenium is removed with a scrubber and an adsorber. It was expected that the scrubber was one of the most effective equipments to remove ruthenium and the decontamination factor of the scrubber was studied. The experimental apparatus was simulated as part of an actual perforated plate column scrubber. The non-radioactive ruthenium which simulated the radioactive ruthenium was volatilized and fed into the scrubber. The decontamination factor of the scrubber was determined by the ratio of the ruthenium concentration at the inlet and outlet of the scrubber off gas stream. The results showed that the scrubber removed the volatile ruthenium effectively as expected.

1993-07-01

319

Data needs for locating emergency response units  

International Nuclear Information System (INIS)

It is becoming increasingly evident that a linkage needs to exist between the siting of emergency response units and the routing of high level radioactive waste shipments. It is important to position the response teams so that the most efficient and effective emergency response can be provided. But the data needed to solve the siting problem are fragmented. This paper identifies the weak points in the data already available and suggests ways in which the data can be strengthened in a cost-effective manner. Among the weakest areas are estimates of the time required for various response events to occur, such as notification time, mobilization time, travel time, and containment time.

1992-04-12

320

Thermal expansion model for multiphase electronic packaging materials  

International Nuclear Information System (INIS)

Control of thermal expansion is often necessary in the design and selection of electronic packages. In some instances, it is desirable to have a coefficient of thermal expansion intermediate between values readily attainable with single or two phase materials. The addition of a third phase in the form of fillers, whiskers, or fibers can be used to attain intermediate expansions. To help design the thermal expansion of multiphase materials for specific applications, a closed form model has been developed that accurately predicts the effective elastic properties of isotropic filled materials and transversely isotropic lamina. Properties of filled matrix materials are used as inputs to the lamina model to obtain the composite elastic properties as a function of the volume fraction of each phase. Hybrid composites with two or more fiber types are easily handled with this model. This paper reports that results for glass, quartz, and Kevlar fibers ...

321

The effect of irradiation on packaging materials  

International Nuclear Information System (INIS)

Ionizing radiation, mainly in the form of #gamma#-rays from the radioisotope cobalt 60, is being used increasingly for the inactivation of contaminants in cosmetic and toiletry preparations. The treatment is applied to the product in its final pack, and therefore, it is important to recognize that the properties of the packaging materials could be affected, particularly if high radiation doses are used. The stability of a wide range of materials is discussed. The nature and extent of chemical and physical changes in plastics very much depends on the presence of antioxidants and other additives, and on the environmental conditions during irradiation. Some useful information is available from research into the use of radiation for the preservation of food - many films and laminates have been cleared for use in the United States. The low radiation doses used for the control of contaminants in cosmetic products are quite unlikely to cause changes in packaging materials which will limit the ...

322

Study of structural, thermodynamical and dynamical properties of molecular liquids confined in nano-porous materials  

International Nuclear Information System (INIS)

When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, Tg, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of Tg is observed for small pore sizes and attractive surface while Tg decreases for non attractive surface, ...

2006-01-01

323

Stoichiometry controlled conversion efficiency in nanostructured heterojunction solar cell of CdS/CuInSXSe2-X grown by chemical ion exchange method at room temperature  

British Library Electronic Table of Contents (United Kingdom)

Here in the present paper, we report on growth of stoichiometric and nonstoichiometric nanostructured heterojunction solar cell of CdS/CuInSXSe2-X varying X from 0 to 2 in the interval of 0.5 using cost effective, simple, chemical ion exchange method at room temperature on ITO glass substrate. The as-grown varying composition solar cells annealed at 200degreeC in air and characterized for structural, compositional, optical and illumination studies. The X-ray diffraction pattern obtained from CdS/CuInSXSe2-X solar cell confirms the formation of CuInSe2, CuInS0.5Se1.5, CuInS1Se1, CuInS1.5Se0.5 and CuInS2 phases having tetragonal structure with varying crystallite size from 19, 19.37, 28, 33 and 20nm respectively. The energy dispersive X-ray analysis (EDAX) confirms the expected elemental com...

2011-01-01

324

Photoconductive ultraviolet detectors based on ZnO films  

Energy Technology Data Exchange (ETDEWEB)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360 nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8 mA, and a slow photoresponse with a rise time of 5 min and a decay time of 7 min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the decrease of the barrier height between crystallites. The relaxation time constant {tau} obtained from the curve fitting represents the time accumulation ...

2006-12-15

325

Photoconductive ultraviolet detectors based on ZnO films  

International Nuclear Information System (INIS)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360 nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8 mA, and a slow photoresponse with a rise time of 5 min and a decay time of 7 min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the decrease of the barrier height between crystallites. The relaxation time constant #tau# obtained from the curve fitting represents the time accumulation ...

2006-12-15

326

Oxidation resistance of C/C composites coated by SiC in premixed methane-air combustion; SiC hifuku sareta C/C konpojietto no metan-kuki yokongo nenshojochu ni okeru taisanka tokusei  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the effects of SiC coating on the oxidation resistance of C/C composites in combusting fields, which are expected to be applied to high temperature structural materials at over 1770K. The coating methods employed were CVD and pack cementation. The time changes in weight loss of the specimens were measured at temperatures of 1770K and 1900K under the equivalence ratio of 0.9 generated by methane-air combustion, and the surface of the specimens before and after the experiment was observed by SEM. Although the weight loss of the specimens coated by the CVD method was minimal, the coating layer was easily peeled off from the substrate. On the other hand, the layer of the specimens coated by the pack cementation method was stable and adhered to the substrate, but the substrate was degraded because of penetration of oxygen through the pores in the layer. To cover the pores, the specimens were additionally coated with glass ...

1997-11-01

327

Nanostructured p-CuIn3Se5/n-CdS heterojunction engineered using simple wet chemical approach at room temperature for photovoltaic application  

British Library Electronic Table of Contents (United Kingdom)

Herein, we report engineering of nanostructured p-CuIn3Se5/n-CdS heterojunction thin film on a glass substrate, which is prepared at room temperature using simple wet chemical approach involving ion exchange reactions between CdS and Cu^+, In^3^+ and Se^2^- ions in alkaline medium. The uniform deposition of heterojunction thin films is achieved by optimizing the pH, temperature and molarity of the reactant bath. The as-deposited thin-films were annealed at 200^oC in air for 1h and further characterized for structural, optical and electrical properties using UV-Vis spectrophotometer, X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), Hall effect for type of conductivity, and I-V measurement to investigate the char...

2011-01-01

328

Multi-megajoule Nd: glass fusion laser design  

Energy Technology Data Exchange (ETDEWEB)

New technologies make multi-megajoule glass lasers economically feasible. Laser architectures using harmonic switchout, target plane holographic injection, phase conjugation, continuous apodization and higher amplifier efficiencies have been devised. A plan for a multi-megajoule laser which can be built for an acceptable cost relies on manufacturing economies of scale and the demonstration of the new technologies presented here. These include continuous pour glass production, rapid harmonic crystal growth, switching of large blocks of power using larger capcaitors packed more economically and by using large identical parts counts.

1986-04-04

329

High current implantation of negative copper ions into silica glasses  

Energy Technology Data Exchange (ETDEWEB)

High-current implantation of Cu{sup {minus}} ions into silica glasses has been demonstrated using mA-class negative ion beams at 60 keV. Negative ion implantation has an advantage to alleviate specimen charging for insulating substrates and has attained high dose rates, up to 260 {micro}A/cm{sup 2}. Spherical Cu colloids form in the silica glasses without additional thermal annealing. Optical absorption and reflection of the implanted specimens vary with the current density, even at a fixed dose level. A beam-induced surface plasma may affect the high current implantation.

1997-12-01

330

Waste management at Los Alamos: Protecting our environment  

Energy Technology Data Exchange (ETDEWEB)

This report consists of a broad overview of activities at Los Alamos National Laboratory (LANL). The following topics are discussed: The growth of the waste management group; what we do today; the mission of the waste management group; the liquid waste treatment section; the radioactive liquid waste project office; the chemical waste section; the radioactive waste section; and the technical support section.

1993-11-01

331

Radioactive waste  

Energy Technology Data Exchange (ETDEWEB)

The paper deals with the disposal of radioactive waste and the plans for dealing with solid wastes of intermediate and low levels of activity, which are the responsibility of NIREX. NIREX is an executive body which co-ordinates the waste-disposal plans of the main radioactive waste producers. The disposal routes for the active wastes are described including the deep disposal of wastes containing material that will remain active for thousands of years. Requirements for deep burial are outlined with reference to the geology and hydrogeology of the site. Monitoring, maintenance and surveillance are mentioned for the protection of the public.

1984-02-01

332

WIS decontamination factor demonstration test with radioactive nuclides  

Energy Technology Data Exchange (ETDEWEB)

A radioactive Waste Incineration System (WIS) with suspension combustion is noticed as effective volume reduction technology of low level radiactive wastes that are increasing every year. In order to demonstrate the decontamination efficiency of ceramic filter used on WIS, this test has been carried out with the test facilities as joint research of Central Research Institute of Electric Power Industry (CRIEPI) and Sumitomo Heavy Industries, Ltd. Miscellaneous combustible waste and power resin, to which 5 nuclides (Mn-54, Fe-59, Co-60, Zn-65, Cs-137) were added, were used as samples for incineration. As the result of the test, it was verified that Decontamination Factor (DF) of the single stage ceramic filter was usually kept over 10/sup 5/ for every nuclide, and from the results of above DF, over 10/sup 8/ is expected for real commercial plant as a total system. Therefore, it is realized that the ...

1987-04-01

333

WIS decontamination factor demonstration test with radioactive nuclides  

International Nuclear Information System (INIS)

A radioactive Waste Incineration System (WIS) with suspension combustion is noticed as effective volume reduction technology of low level radiactive wastes that are increasing every year. In order to demonstrate the decontamination efficiency of ceramic filter used on WIS, this test has been carried out with the test facilities as joint research of Central Research Institute of Electric Power Industry (CRIEPI) and Sumitomo Heavy Industries, Ltd. Miscellaneous combustible waste and power resin, to which 5 nuclides (Mn-54, Fe-59, Co-60, Zn-65, Cs-137) were added, were used as samples for incineration. As the result of the test, it was verified that Decontamination Factor (DF) of the single stage ceramic filter was usually kept over 10"5 for every nuclide, and from the results of above DF, over 10"8 is expected for real commercial plant as a total system. Therefore, it is realized that the off-gas clean up ...

334

Thermophilic slurry-phase treatment of petroleum hydrocarbon waste sludges  

Energy Technology Data Exchange (ETDEWEB)

Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of ...

1995-12-31

335

Thermophilic slurry-phase treatment of petroleum hydrocarbon waste sludges  

International Nuclear Information System (INIS)

Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of ...

1995-04-24

336

Integrated risk analysis of a heavy-metal-contaminated site in Taiwan  

Energy Technology Data Exchange (ETDEWEB)

The Love Canal episode began the long battle on hazardous wastes in the United States. Obviously, the potential danger of hazardous wastes is one of the hottest issues among environmental professionals as well as the public. The problems of hazardous wastes in economically booming Taiwan are also alarming. Several farmlands in northern Taiwan were contaminated heavily by industrial effluents containing heavy metals (cadmium and lead) in the early 1980s. Regardless of the many studies that have been conducted about these polluted farmlands, there has not been any remediation - just a passive abandonment of farming activities with minimal compensation. This paper addresses a heavy-metal-contaminated fanning area. A pollution profile across time is delineated using information from the abundance of reports, and the contamination is modeled mathematically. The past, the present, and future exposures are also modeled. The ...

1996-12-31

337

In Situ Remediation Integrated Program: FY 1994 program summary  

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), ...

1995-04-01

338

From waste minimization to ISO 14000: Taiwan`s experience and prospects  

Energy Technology Data Exchange (ETDEWEB)

Taiwan has completed a very successful five-year industrial waste minimization (IWM) demonstration and promotion project sponsored by the government. From 1990 to 1995, the project successfully disseminated the IWM concept of pollution prevention (P2) to industries. It effectively reduced industrial waste while significantly benefitting the economy by assisting industries in implementing in-plant IWM programs. In July 1995, the second stage of the five-year IWM and ISO 14000 promotion project was initiated for further promoting the IWM, P2, and cleaner production and, in particular, coping with the upcoming international environmental management standards (ISO 14000). To assist industries in establishing an environmental management system (EMS) and accumulating related experience, an EMS pilot demonstration project of five model industries and an ISO 14001 EMS demonstration and promotion project for 22 factories in 13 ...

1996-12-31

339

Advanced evaporator technology progress report FY 1992  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the work that was completed in FY 1992 on the program {open_quotes}Technology Development for Concentrating Process Streams.{close_quotes} The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to be incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium ...

1995-01-01

340

Sample manuscript showing specifications and style - NASA ...  

Science.gov (United States)

Figure 7: Horak Cost Estimating Relationship with Statistical Details. For this comparison, we ignore the Material (glass vs metal) and Design (on vs ...

343

Optical properties and up-conversion of Pr"3"+ doped CdS nanoparticles in sol-gel glasses  

International Nuclear Information System (INIS)

Silica glasses containing Pr"3"+ with and without CdS nanoparticles were prepared by sol-gel technique. The influence of CdS nanoparticles on Pr"3"+ doped glass was studied by absorption, photoluminescence and up-conversion. From the measured intensities of various absorption bands of these glasses, the Judd-Ofelt parameters ?_2, ?_4 and ?_6 have been evaluated. The radiative transition probability (A), radiative lifetime (?_R), branching ratio (?_R) and integrated emission cross-section (?_P) were calculated from excited states of "3P_1 and "3P_0 levels. The up-conversion emissions were found in the green, orange and red regions under 800 nm excitation with peaks 559, 612 and 688 nm respectively. On excitation with 370 nm also leads to similar green, orange and red regions.

2010-10-01

346
347
348

Co-operative downconversion luminescence in Tm3+/Yb3+ : SiO2-Al2O3-LiF-GdF3 glasses  

International Nuclear Information System (INIS)

Oxyfluoride aluminosilicate glasses in the composition of 50SiO2-20Al2O3-20LiF-10GdF3-0.5TmF3-xYbF3 (x = 0, 1.0, 2.5, 5, 7.5, 10, 15, 20, 25 and 30 mol%) have been prepared to study their thermal and optical properties. From the differential thermal analysis measurements, glass transition temperatures and onset crystallization temperatures have been evaluated and from them glass stability factors were calculated. Glass stabilities decreased gradually with fluoride content increment in all the studied glasses. The photoluminescence and decay measurements have also been carried out for all these glasses. In these glasses, an efficient near infrared quantum cutting with optimal quantum efficiency approaching 187% has been demonstrated, by exploring the co-operative downconversion mechanism from Tm3+ to Yb3+, with 467 nm (Tm3+ : 3H6 ? 1G4) ...

2008-09-07

349

Calcium phosphate glass-ceramics for bioactive coating on a #beta#-titanium alloy  

International Nuclear Information System (INIS)

The formation of a porous coating is the decisive feature for the bio-compatibility of silica-free calcium phosphate glass ceramics on alloy surfaces like the #beta#-Ti structured Ti-29Nb-13Ta-4.6Zr used in this work. The ceramic composition is highly important: 50CaO-40P_2O_5-7Na_2O-3TiO_2 glass powder produces a pore-free coating unable to bind hydroxyapatite, whereas 60CaO-30P_2O_5-7Na_2O-3TiO_2 glass incorporates pores from which a crystalline hydroxyapatite phase can grow over the surface from simulated body fluid (see Figure). (Abstract Copyright [2003], Wiley Periodicals, Inc.)

2003-07-01

350

Achievement report for fiscal 1998. Research and development on a new manufacturing method for functional thin films suitable for recycling, and their application to colored glasses (the second year); 1998 nendo seika hokokusho. Recycle ni tekishita kinosei usumaku no shinki seizoho to chakushoku glass eno oyo ni kansuru kenkyu kaihatsu (dai 2 nendo)  

Energy Technology Data Exchange (ETDEWEB)

A new thin film manufacturing method is established to add a function to glass material surface, as a new material technology which harmonizes with global environment, and is suitable for resource re-utilization and energy conservation. It is intended to develop a leading technology to promote recycling of colored glasses by applying this technical method to colored glasses. Fiscal 1998 has implemented subsequently to fiscal 1997 the following subjects in the three research items composed of a new manufacturing method of functional thin films, application of the functional thin films to colored glasses, and the comprehensive investigative studies: establishment of an industrial manufacturing method for color coating liquid and evaluation of basic characteristics of the colored functional thin films, optimization of element technology for photo-sensitive gel films by means of chemically modifying ...

1999-03-01

351

U. S. Navy shipboard-generated plastic-waste pilot-recycling program. Research and development report, Apr 90-Jan 91  

Energy Technology Data Exchange (ETDEWEB)

From April 1990 through January 1991, the feasibility of recycling Navy shipboard-generated plastic wastes was explored. Normally, plastic wastes are source separated aboard Navy ships and retained for shoreside disposal in accordance with new fleet requirements implementing MARPOL Annex V that prohibits the discharge of plastics at sea. Over 23,000 pounds of shipboard plastic wastes from USS Lexington (AVT 16) and ships from the Norfolk Naval Base were recycled into park benches, picnic tables and carstops that have been distributed back to the Navy bases for use. Navy shipboard plastics must undergo sorting prior to recycling because Navy plastic waste contains large quantities of composite plastic items (e.g., plastic/paper) that are not easily recyclable. Recycling food-contaminated plastics is not practical due to sanitation problems encountered during handling. However, certain items have good ...

1991-03-01

352

The role of oxygen diffusion in the release of technetium from reducing cementitious waste forms  

Energy Technology Data Exchange (ETDEWEB)

Cementitious materials provide an ideal geochemical environment (e.g., high pH pore fluids and large surface areas for sorption) for immobilizing nuclear waste. The inclusion of reducing agents, such as blast furnace slag (BFS) can immobilize radionuclides by forming of solid sulfide phases. Thermodynamic calculations using the MINTEQ geochemical computer code indicate the elemental sulfur present in BPS reacts with the highly mobile pertechnetate anion (TcO{sub 4}{sup -}) anion to form an insoluble technetium sulfide phase (Tc{sub 2}S{sub 7(s)}). Initially, the waste form very effectively immobilizes technetium. However, as oxygen diffuses into the waste form, an outer zone of oxidized concrete and a shrinking core of reduced intact concrete develops. Oxidation of sulfur in the outer zone results in increased technetium concentrations in the pore fluid because Tc{sub 2}S{sub 7(a)} oxidizes to the ...

1993-12-31

353

The Joint Convention on the Safety of Spent fuel Management and on the safety of Radioactive Waste Management: A UK Regulator's Perspective  

International Nuclear Information System (INIS)

The UK fully supports the objective of the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management to achieve and maintain a high level of safety worldwide in spent fuel and radioactive waste management, through the enhancement of national measures and international co-operation, including where appropriate, safety-related co-operation. The UK's Health and Safety Executive, through its Nuclear Safety Directorate (NSD), has been committed to the Convention since the initial negotiations to set up the Convention and provided the president of the first review meeting in 2003. It would be wrong of any nation to believe that they have all the best solutions to managing spent fuel and radioactive waste. The process of compiling reports for the Convention review meetings provides a structured process through which every contracting party can review its provisions against a common ...

354

The Importance of Building and Enhancing Worldwide Industry Cooperation in the Areas of Radiological Protection, Waste Management and Decommissioning  

International Nuclear Information System (INIS)

The slow or stagnant rate of nuclear power generation development in many developed countries over the last two decades has resulted in a significant shortage in the population of mid-career nuclear industry professionals. This shortage is even more pronounced in some specific areas of expertise such as radiological protection, waste management and decommissioning. This situation has occurred at a time when the renaissance of nuclear power and the globalization of the nuclear industry are steadily gaining momentum and when the industry's involvement in international and national debates in these three fields of expertise (and the industry's impact on these debates) is of vital importance. This paper presents the World Nuclear Association (WNA) approach to building and enhancing worldwide industry cooperation in radiological protection, waste management and decommissioning, which is manifested through the activities of the two WNA working groups ...

355

Resolving issues at the Department of Energy/Oak Ridge Operations Facilities  

Energy Technology Data Exchange (ETDEWEB)

Waste management, like many other issues, has experienced major milestones. In 1971, the Calvert Cliff's decision resulted in an entirely different approach to the consideration of environmental impact analysis in reactor siting. The accidents at Three Mile Island and Chernobyl have had profound effects on nuclear power plant design. The high-level waste repository program has had many similar experiences that have modified the course of events. The management of radioactive, hazardous chemical and mixed waste in all of the facilities of the Oak Ridge Operations (ORO) Office of the Department of Energy (DOE) took on an entirely different meaning in 1984. On April 13, 1984, Federal Judge Robert Taylor said that DOE should proceed 'with all deliberate speed' to bring the Y-12 plant into compliance with the Resource Conservation and Recovery Act and the Clean Water Act. This ...

1988-01-01

356

Developing a holistic strategy for integrated waste management within municipal planning: Challenges, policies, solutions and perspectives for Hellenic municipalities in the zero-waste, low-cost direction  

International Nuclear Information System (INIS)

The present position paper addresses contemporary waste management options, weaknesses and opportunities faced by Hellenic local authorities. It focuses on state-of-the-art, tested as well as innovative, environmental management tools on a municipal scale and identifies a range of different collaboration schemes between local authorities and related service providers. Currently, a policy implementation gap is still experienced among Hellenic local authorities; it appears that administration at the local level is inadequate to manage and implement many of the general policies proposed; identify, collect, monitor and assess relevant data; and safeguard efficient and effective implementation of MSWM practices in the framework of integrated environmental management as well. This shortfall is partly due to the decentralisation of waste management issues to local authorities without a parallel substantial budgetary and capacity ...

2009-05-01

357

Regional assessment of nonforestry related biomass resources: Virginia  

Energy Technology Data Exchange (ETDEWEB)

This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes of Virginia that are potential biomass energy sources.

1988-11-01

358

Regional assessment of nonforestry related biomass resources: Florida  

Energy Technology Data Exchange (ETDEWEB)

This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes and industrial wastes in Florida that are potential biomass energy sources.

1988-11-01

359

Regional assessment of nonforestry related biomass resources: Alabama  

Energy Technology Data Exchange (ETDEWEB)

This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes and industrial wastes of Alabama that are potential biomass energy sources.

1988-11-01

360

Department of the  

Wastenet

Waste Technology and Innovation Study Final Report ...Waste Technology and Innovation Study Final Report 21/18569/150554 ...Survey of waste and resource recovery related technology and innovation, including products and product uses

361

Fundamental Chemistry And Thermodynamics Of Hydrothermal Oxidation Processes  

Science.gov (United States)

Hydrothermal oxidation (HTO) is a promising technology for the treatment of aqueous-fluid hazardous and mixed waste streams. Waste streams identified as likely candidates for treatment by this technology are primarily aqueous fluids containing hazardous organic compounds, and often containing inorganic compounds including radioisotopes (mixed wastes). These wastes are difficult and expensive to treat by conventional technologies (e.g. incineration) due to their high water content; in addition, incineration can lead to concerns related to stack releases. An especially attractive potential advantage of HTO over conventional treatment methods is the total containment of all reaction products within the overall system. The potential application of hydrothermal oxidation (HTO) technology for the treatment of DOE hazardous or mixed wastes has been uncertain due to concerns about safe and ...

2001-12-31

362

Less waste corn, more land in soybeans, and the switch to genetically modified crops: trends with important implications to wildlife management  

Science.gov (United States)

An abundance of waste corn, a key food of many wildlife species, has helped make possible the widespread success of wildlife management in the United States over the past half century. We found waste corn post harvest in Nebraska declined by 47% from 1978 to 1998 due primarily to improvements in combine headers resulting in a marked decline in ear loss. The reduction in waste coincided with major declines in fat storage by sandhill cranes and white-fronted geese during spring migration. Sandhill cranes, northern pintails, white-fronted geese, and lesser snow geese avoided soybeans while staging in spring in the Rainwater Basin Area and Central Platte River Valley. These findings and other literature suggest soybeans are a marginal food for wildlife particularly during periods of high energy requirements. Soybean acreage has increased by 600% in the United States since 1950 and now comprises nearly one-quarter of the ...

2004-01-01

363

Growth of Pinus radiada in soil containing solid waste from the kraft pulp industry  

Energy Technology Data Exchange (ETDEWEB)

The germination and growth of Pinus radials Don. plantlets in solid residues deriving from a Kraft pulp industry was evaluated. Plant conditions were monitored by histological studies of roots and shoot-tips, as well as by plant analyses of several essential and non essential elements. The solids employed consisted of ashes, fly-ashes, dregs, grits, primary sludge, brown stock screening rejects and various mixtures of them. Their addition, in a range of combinations to sandy/metamorphic or marine terrace/clay soils, resulted in effective and sustained growth under greenhouse conditions. Low proportions of wastes favored growth in most cases, indicating that they may act as fertilisers. In some experiments, especially in those where waste was added in proportions ranging from 50% to 60%, germination and/or development were slightly affected. Two-year old field experiments have confirmed that in spite of the high pH values, ...

2000-06-01

364

PROCEEDINGS OF RIKEN BNL RESEARCH CENTER WORKSHOP (VOL. 71)  

Energy Technology Data Exchange (ETDEWEB)

The high energy limit of Quantum Chromodynamics is one of the most fascinating areas in the theory of strong interactions. Over a decade ago the HERA experiment at DESY in Hamburg provided strong evidence for the rise of the proton structure function at small values of the Bjorken variable x. This behavior can be explained as an increase of the gluon density of the proton with energy or correspondingly with smaller values of x. This increase can be attributed on the other hand to the large probability of gluon splitting in QCD. The natural framework for describing the gluon dynamics at small x is the Balitskii-Fadin-Kuraev-Lipatov formalism developed some 30 years ago. It predicts that the gluon density grows very fast with increasing energy, as a power with a large intercept. This increase has to be tamed in order to satisfy the unitarily bound. Over two decades ago, Gribov, Levin and Ryskin proposed the mechanism called the parton saturation, which slows down the fast rise of the ...

2005-03-07

365

Multi-scale modeling of fiber and fabric reinforced cement based composites  

Science.gov (United States)

With an increased use of fiber reinforced concrete in structural applications, proper characterization techniques and development of design guides are needed. This dissertation presents a multi-scale modeling approach for fiber and fabric reinforced cement-based composites. A micromechanics-based model of the yarn pullout mechanism due to the failure of the interfacial zone is presented. The effect of mechanical anchorage of transverse yarns is simulated using nonlinear spring elements. The yarn pullout mechanism was used in a meso-scale modeling approach to simulate the yarn bridging force in the crack evolution process. The tensile stress-strain response of a tension specimen that experiences distributed cracking can be simulated using a generalized finite difference approach. The stiffness degradation, tension stiffening, crack spacing evolution, and crack width characteristics of cement composites can be derived using matrix, interface and fiber properties. The ...

2008-01-01

366

Waste management plan for the APT  

Energy Technology Data Exchange (ETDEWEB)

This revision of the APT Waste Management Plan details the waste management requirements and issues specific to the APT plant for design considerations, construction, and operation. The APT Waste Management Plan is by its nature a living document and will be reviewed at least annually and revised as required.

1997-08-22

369

Nuclear waste management: a perspective  

Energy Technology Data Exchange (ETDEWEB)

The scope of our problems with nuclear waste management is outlined. Present and future inventories of nuclear wastes are assessed for risk. A discussion of what is presently being done to solve waste management problems and what might be done in the future are presented. (DC)

1980-01-01

372

E-waste hazard: The impending challenge  

UK PubMed Central (United Kingdom)

Electronic waste or e-waste is one of the rapidly growing problems of the world. E-waste comprises of a multitude of components, some containing toxic substances that can have an adverse impact on human...Full Text Available

2008-08-01

376

40 CFR 261.2 - Definition of solid waste.  

Science.gov (United States)

...2009-07-01 false Definition of solid waste. 261.2 Section 261.2 Protection...PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.2 Definition...

2009-07-01

377

Hanford Waste Management Plan, 1987  

Energy Technology Data Exchange (ETDEWEB)

The purpose of the Hanford Waste Management Plan (HWMP) is to provide an integrated plan for the safe storage, interim management, and disposal of existing waste sites and current and future waste streams at the Hanford Site. The emphasis of this plan is, however, on the disposal of Hanford Site waste. The plans presented in the HWMP are consistent with the preferred alternative which is based on consideration of comments received from the public and agencies on the draft Hanford Defense Waste Environmental Impact Statement (HDW-EIS). Low-level waste was not included in the draft HDW-EIS whereas it is included in this plan. The preferred alternative includes disposal of double-shell tank waste, retrievably stored and newly generated TRU waste, one pre-1970 TRU solid waste site near the Columbia River ...

1987-01-01

378

Ecological utilization of wastes. A manual for optimum waste management concepts. 3. rev. ed. Oekologische Muellverwertung. Handbuch fuer optimale Abfall-Konzepte  

Energy Technology Data Exchange (ETDEWEB)

From out of the numerous technical alternatives the manual develops a waste management concept with emphasis on methods which can be coordinated for maximum ecological use and minimum economic costs. A clear-cut analysis of the present state of waste utilization and waste disposal in the Federal Republic of Germany (chapter 1) is followed by a detailed description of conventional and modern state-of-the-art waste utilization methods based on ecological evaluation criteria (chapter 3). An optimum waste utilization concept for defined quantities of wastes is derived from the ecological and economic comparison of waste utilization techniques given in chapter 3. Chapter 4 points out different variants of waste utilization and waste disposal methods and shows how to determine the optimum variant of the ...

1991-01-01

379

XRF and PIXE method as trols for the element analysis of metallic glasses  

International Nuclear Information System (INIS)

The radionuclide X-ray fluorescence and particle induced X-ray emission methods were used for rapid and nondestructive analysis of metallic glasses. The methods were compared for accuracy and precision with the atomic absorption method. Some results of the analyses of Fe_xNi_8_0_-_xB_2_0 materials are briefly reviewed. The distribution of elements along the width as well as the length and a qualitative analysis of the composition of material surfaces are considered. (author).

1986-01-01

380

XRF and PIXE analysis of metallic glasses  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence and particle induced X-ray emission methods were used for a rapid and nondestructive analysis of metallic glasses. The methods are compared in accuracy and precision with the atomic absorption method. Some results of analyses of Fe_xNi_8_0_-_xB_2_0 materials are briefly reviewed. The distribution of elements along the width and length, and a qualitative analysis of the composition of material surfaces are considered. (author) 3 refs.

1987-05-01

381

Verification of lithium detector efficiency using DD neutron  

International Nuclear Information System (INIS)

The detection efficiency of a lithium glass detector was calculated using MCNP code, and the calculation was compared with the published results in Pulsed Sphere Plan. A lithium glass detector of our own was made, and its neutron efficiency was calculated. The calculated neutron efficiency was verified with both pulsed and steady DD neutrons. Characteristics of Neutron response of "6Li detector was discussed. (authors)

2005-08-01

382

Quartz ceramics alloying  

International Nuclear Information System (INIS)

The following methods of quartz ceramics alloying were considered: alloying of initial quartz glass; introduction of alloying additive into water slip of quartz glass; porous materials impregnation with salt aqueous solutions and subsequent salt thermal decomposition with formation of stable oxides in pores of ceramics. Oxygen free compounds BN, SiB_4, SiC, Si_3N_4, REM oxides and transition metal oxides were used as alloying additives. Main properties of the materials and compositions obtained are presented.

383

Maintenance of energy systems by means of Internet; Energiesystemen onderhouden met Internet  

Energy Technology Data Exchange (ETDEWEB)

Asean Brown Boveri (ABB) developed Glass (Global access for service and support), a monitoring system for the remote control and management of ABB supplied equipment and other equipment through the Internet. Glass can be applied for many different systems, e.g. automated substations of electric power distribution systems or train equipment

1999-04-01

384

Friction and wear properties of glass fiber reinforced nylons against alumina ceramics in oil; Yuchu ni okeru glass sen`i kyoka nylon no alumina ceramics ni taisuru masatsu mamo tokusei  

Energy Technology Data Exchange (ETDEWEB)

The friction and wear properties of glass fiber reinforced composites of nylons (nylon 6, nylon 66 and nylon 46) with different crystallinities due to their molecular structures were investigated by sliding them with alumina ceramics and using a pin-on-disk friction machine. The friction coefficients of the glass fiber reinforced nylons in oil were lower and more stable than those in air from the initial stage of friction. The transfer of nylon matrix to adhere onto the alumina surface in air was so much greater than in oil that the alumina surface could not be recognized. Consequently, a different between the friction and wear properties in air and in oil was resulted. Reinforcement of nylons with glass fiber remarkably improved their friction properties in oil by its lubricating action, while the wears were rather high contrary to what was expected. This tendency was conspicuous for nylon 46 with high crystallinity. ...

1997-09-01

385

Advanced Ceramic Technology  

Science.gov (United States)

"Precision manufacture of ceramic parts with CNC machining capability for aerospace, lasers, semiconductors and other industries. Materials include alumina, zirconia, glass, ferrites, silicon carbide, silicon nitride, sapphire, cordierite, mullite and others. A.C.T. has seen the number of applications and demand for high-realiability ceramics (aluminum oxide, zirconia, glass, ferrites, silicon carbide, silicon nitride, sapphire, cordierite, mullite, etc...) increase continually within the aerospace, computer and the industrial markets."

2007-02-01

386

Waste Management Project fiscal year 1998 multi-year work plan, WBS 1.2  

Energy Technology Data Exchange (ETDEWEB)

The Waste Management Project manages and integrates (non-TWRS) waste management activities at the site. Activities include management of Hanford wastes as well as waste transferred to Hanford from other DOE, Department of Defense, or other facilities. This work includes handling, treatment, storage, and disposal of radioactive, nonradioactive, hazardous, and mixed solid and liquid wastes. Major Waste Management Projects are the Solid Waste Project, Liquid Effluents Project, and Analytical Services. Existing facilities (e.g., grout vaults and canyons) shall be evaluated for reuse for these purposes to the maximum extent possible.

1997-09-23

387

Safe management of wastes from the mining and milling of Uranium and Thorium ores  

CERN Document Server

Safe management of wastes from the mining and milling of Uranium and Thorium ores

1987-01-01

388

Hazardous Waste Management on the Farm  

Science.gov (United States)

Sep 2, 2008 ... Abstract: This tutorial is intended to serve as a guide towards proper hazardous waste management. Knowing the regulations, different ...

389

Control of Effluent Gases from Solid Waste Processing Using Carbon Nanotubes  

Science.gov (United States)

One of the major problems associated with solid waste processing technologies is the release of

2005-01-01

391

Structural studies of some phospho-borate glasses using ultrasonic pulse-echo technique, DSC and IR spectroscopy  

International Nuclear Information System (INIS)

Glasses in the system (95-x) [0.25 Na2O-0.75 B2O3]-x P2O5-5 Fe2O3 (0?x?15 mol%), have been prepared by the melt quenching technique. Elastic properties and FT-IR spectroscopic studies have been employed to study the role of P2O5 on the structure of the glass system. Elastic properties Poisson's ratio, micro-hardness and Debye temperature have been investigated using sound wave velocity measurements at 4 MHz (both longitudinal and shear) at room temperature. The results showed that the density and the molar volume increase as both sound velocities and the determined glass transition temperatures decrease with increasing the contents of P2O5. Infrared spectra of the glasses reveal that the borate network consists of diborate units and is affected by the increase in the concentration of P2O5 content as a second network former. These results are interpreted in terms of the replacement of the diborate units ...

2009-06-01

392

Spectroscopic properties of Er"3"+ ions in cadmium and alkali cadmium borosulphate glasses  

International Nuclear Information System (INIS)

Spectroscopic properties of Er"3"+ : CBS (CdSO_4 + B_2O_3 and R_2SO_4 + CdSO_4 + B_2O_3, R_2SO_4 = Li_2SO_4.H_2O, Na_2SO_4, K_2SO_4 and Gd_2(SO_4)_3.8H_2O) glasses are reported. The assigned energy level data of Er"3"+(4f"1"1) in these glasses are analysed in terms of a parametrized model Hamiltonian. The standard deviations of the data fits are between 39 and 47 cm"-"1 so that the energy level schemes of the Er"3"+(4f"1"1) ions in borosulphate (CBS) glasses are reasonably well reproduced. Radiative properties for the fluorescent levels of Er"3"+ : CBS glasses are determined by using the Judd-Ofelt theory. The potential laser transitions are identified with the help of predicted radiative properties which are compared and discussed with similar results. (author).

1997-01-01

393

Near infrared to red and yellow to blue upconversion emissions from Pr"3"+: ZrF_4-BaF_2-LaF_3-YF_3-AlF_3-NaF glasses  

International Nuclear Information System (INIS)

This paper describes the development and a detailed analysis carried out on the luminescence characteristics of Pr"3"+ doped ZrF_4-BaF_2-LaF_3-YF_3-AlF_3-NaF glasses. In the present work our objectives are to elucidate the possible mechanisms that are responsible for NIR to red upconversion process and yellow to blue upconversion emission in terms of energy level schemes from the praseodymium containing fibre optical glass composition. We have studied their different physical and optical properties. Besides our investigation on the upconversion emission of these glasses, normal fluorescence studies have also been undertaken in explaining the mechanisms in demonstrating bright red and blue emissions upon excitations at visible and UV wavelengths. Besides these measurements works, a bright blue colour emission was observed under an UV source (202 nm) and upconverted prominent red emissions were observed with a laser diode (LD ...

2004-04-15

394

Metallic glasses as new catalyst systems for energy conversion: Final report  

Energy Technology Data Exchange (ETDEWEB)

Pd-Si metallic glasses have been utilized as catalysts in the Fischer-Tropsch reaction. The glasses are selective of ethane, whereas the in-situ crystallized glasses select a range of hydrocarbons characteristic of conventional Pd catalysts. This shift in selectivity has been observed in other hydrogenation reactions. Surface crystallization caused by the reaction conditions causes variable selectivity. Crystallization in reaction conditions has been monitored by DSC. During the course of the grant we developed the use of (+)- apopinene (6,6-dimethyl-1R,5R-bicyclo(3.1.1)hept-2-ene) as a molecular probe for determining the number and kinds of active sites on metallic glass catalysts. To accomplish this we conducted many experiments for comparison on other types of catalysts. These were foils, powders, and highly dispersed metals on several different supports. The glassy surfaces appear to be three ...

1987-01-01

395

Glass Furnace Combustion and Melting Research Facility.  

Energy Technology Data Exchange (ETDEWEB)

The need for a Combustion and Melting Research Facility focused on the solution of glass manufacturing problems common to all segments of the glass industry was given high priority in the earliest version of the Glass Industry Technology Roadmap (Eisenhauer et al., 1997). Visteon Glass Systems and, later, PPG Industries proposed to meet this requirement, in partnership with the DOE/OIT Glass Program and Sandia National Laboratories, by designing and building a research furnace equipped with state-of-the-art diagnostics in the DOE Combustion Research Facility located at the Sandia site in Livermore, CA. Input on the configuration and objectives of the facility was sought from the entire industry by a variety of routes: (1) through a survey distributed to industry leaders by GMIC, (2) by conducting an open workshop following the OIT Glass Industry Project Review ...

2004-08-01

396

Elastic properties and structural studies on some zinc-borate glasses derived from ultrasonic, FT-IR and X-ray techniques  

International Nuclear Information System (INIS)

Glasses in the system (1 - x) [29Na2O- 4Al2O3- 67B2O3]- xZnO (0 ? x ? 35 mol%), have been prepared by the melt quenching technique. Elastic properties, X-ray and FT-IR spectroscopic studies have been employed to study the role of ZnO on the structure of the investigated glass system. Elastic properties and Debye temperature have been investigated using sound wave velocity measurements at 4 MHz at room temperature. The results showed that the density increases and the molar volume decreases while both sound velocities and the determined glass transition temperatures decrease with increase in x. X-ray and infrared spectra of the glasses reveal that the borate network consists of diborate units and is affected by the increase in the concentration of ZnO content. These results are interpreted in terms of the decrease in the N4 values (fraction of tetrahedral coordinated boron atoms), and substitution of ...

2009-05-05

397

Request for interim approval to operate Trench 94 of the 218-E-12B Burial Ground as a chemical waste landfill for disposal of polychlorinated biphenyl waste in submarine reactor compartments. Revision 2.  

Science.gov (United States)

This request is submitted to seek interim approval to operate a Toxic Substances Control Act (TSCA) of 1976 chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) waste. Operation of a chemical waste landfill for disposal of PCB waste ...

1994-01-01

398

Radioactive and mixed waste management plan for the Lawrence Berkeley Laboratory Hazardous Waste Handling Facility  

Energy Technology Data Exchange (ETDEWEB)

This Radioactive and Mixed Waste Management Plan for the Hazardous Waste Handling Facility at Lawrence Berkeley Laboratory is written to meet the requirements for an annual report of radioactive and mixed waste management activities outlined in DOE Order 5820.2A. Radioactive and mixed waste management activities during FY 1994 listed here include principal regulatory and environmental issues and the degree to which planned activities were accomplished.

1995-01-01

399

Composting - environmentally compatible waste disposal - one of the incredients of waste management  

Energy Technology Data Exchange (ETDEWEB)

Considering the fact that more than 40% of all household wastes are organic wastes composting could be an excellent relief and complement to other waste disposal methods (e.g. combustion or direct landfills). Provided the right conditions household wastes could be composted together with sewage sludges and manures. The paper discusses the legal aspects, quantitative evaluations, conveying systems, as well as the compost utilization and marketing aspects valid for the Federal Republic of Germany.

1988-09-20

400

Charging generators for waste management costs  

Energy Technology Data Exchange (ETDEWEB)

Implementation of a plan to charge waste management costs to the facility that generates such waste requires a long-term commitment and consistent administration. The benefit is that generators are provided the incentive to optimize waste management practices if the charges are appropriately applied. This paper summarizes (1) a plan to charge waste generators, (2) the administrative structure of the plan, (3) a comparison between the rate structure and changes in waste disposal operations, and (4) issues that have surfaced as the plan is implemented. 2 refs., 1 fig., 1 tab.

1988-01-01

401

AVLIS production plant waste management plan  

Energy Technology Data Exchange (ETDEWEB)

Following the executive summary, this document contains the following: (1) waste management facilities design objectives; (2) AVLIS production plant wastes; (3) waste management design criteria; (4) waste management plan description; and (5) waste management plan implementation. 17 figures, 18 tables.

1984-11-15

402

The Polytechnique, UQAT, NSERC chair in environment and tailings management; La Chaire Polytechnique, UQAT, CRSNG en environnement et gestion des rejets miniers  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this new industrial chair is to ensure the continuation and development of new research activities in the field of environment protection as it relates to the good management of mine tailings. The mining industry plays a vital role in the economy of a number of regions in both Quebec and Canada and also causes environmental problems due to the generation of liquid, solid, and gaseous wastes. Mine tailings can cause acid mine drainage. This acid mine drainage (AMD) can have detrimental effects on the ecosystems adjoining tailings or waste rock piles. We must remain aware that some of the remedial measures instituted to contain AMD might cause problems due to their possible instability. Despite the fact that instability is a rare occurrence, it can have disastrous effects on the environment as demonstrated in Spain, Guyana, and the Philippines during the last few years. The creation of this ...

2000-07-01

403

Primary productivity C-14 and algal assay in the study of water pollution effects in the Citarum River and Jatiluhur Reservoir  

International Nuclear Information System (INIS)

Water quality of the Citarum River and the Jatiluhur Reservoir in Indonesia was evaluated using C-14 radioisotope. A close relationship between the abiotic (physical and chemical) and the biotic (algal growth potential, primary productivity, chlorophylla and diversity index of planktonic and benthic macroinvertebrate) parameters was obtained. Algal growth potential to abiotic parameters relationship has the highest correlation coefficient and can be used as a pollution indicator. The other biotic parameters do not show clear relationship with the abiotic parameters. The Citarum water quality is the lowest in those locations which receive human and industrial waste from Bandung and its environment. This water cannot be used for drinking purposes and fishery. The water quality in other locations of the river, however, meets the criteria for agriculture. Agricultural waste does not show any drastic effect on the water quality ...

1983-03-01

404

Phase Chemistry of Tank Sludge Residual Components  

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank sludges can be difficult, dangerous and prohibitively ...

2002-04-02

405

Impact of oil and related chemicals on the marine environment  

International Nuclear Information System (INIS)

This review updates a previous review entitled ''Impact of Oil on the Marine Environment''. It covers oil and individual hydrocarbons, used lubricating oils, chemical control agents for oil spills, and wastes from offshore petroleum operations. It considers all major knowledge generated since the mid-1970s. The review covers its topics comprehensively, from a consideration of the composition, sources and inputs of oil to its ecological and human health effects and its effects on man's use of the sea. The review addresses several key questions on the present levels of contamination, the impact of hydrocarbons and related chemicals on marine biota, the recovery potential of marine ecosystems exposed to these contaminants, the degree of protection required for marine ecosystems known to be vulnerable and sensitive, and recommended research and other actions to fill gaps in knowledge. The review describes the hazards of marine ...

406

Aquatic macroinvertebrates and water quality in Sandia Canyon  

International Nuclear Information System (INIS)

In 1990, field studies of water quality and stream macroinvertebrate communities were initiated in Sandia Canyon at Los Alamos National Laboratory. The studies were designed to establish baseline data and to determine the effects of routine discharges of industrial and sanitary waste. Water quality measurements were taken and aquatic macroinvertebrates sampled at three permanent stations within the canyon. Two of the three sample stations are located where the stream regularly receives industrial and sanitary waste effluents. These stations exhibited a low diversity of macroinvertebrates and slightly degraded water quality. The last sample station, located approximately 0.4 km (0.25 mi) downstream from the nearest wastewater outfall, appears to be in a zone of recovery where water quality parameters more closely resemble those found in natural streams in the Los Alamos area. A large increase in macroinvertebrate diversity ...

2005-09-01

407

Hospital waste management in Lebanon  

International Nuclear Information System (INIS)

Hospital wastes comprises approximately 80% domestic waste components, also known as non-risk waste and 20% hazardous or risk waste. The 20% of the hospital waste stream or the risk waste (also known as infectious, medical, clinical wastes) comprises components which could be potentially contaminated with infections, chemical or radioactive agents. Therefore, it should be handled and disposed of in such a manner as to minimize potential human exposure and cross-contamination. Hospital risk waste and be subdivided into seven general categories as follows: infections, anatomical/pathological, chemical, pharmaceutical, radioactive waste, sharps and pressurised containers. These waste categories are generated by many types of health care establishments, including hospitals, clinics, ...

1999-06-02

408

Water pollution in estuaries and coastal zones. 1978-December 1980 (citations from the NTIS Data Base). Report for 1978-December 1980  

Energy Technology Data Exchange (ETDEWEB)

The bibliography contains selected abstracts of research reports covering studies dealing with water pollution from estuarine and coastal development, the effects of this pollution, and its control. The reports are general in nature so as to be of interest to any coastal area. The topics include pollution as related to urbanization, government actions, coastal planning, natural resource development, and sewage and solid waste disposal. Specific biological and oceanographic studies have been excluded. (This updated bibliography contains 112 citations, 42 of which are new entries to the previous edition.)

1981-01-01

409

Uncertainties of radionuclide migration parameter values obtained from in-situ tracer experiments  

International Nuclear Information System (INIS)

One of the key issues in safety assessment of high-level nuclear waste disposal is evaluating the effects of uncertainty inherent in radionuclide migration parameter values. In this paper, radionuclide transport parameter values and error variances (uncertainties) from in-situ tracer experiments, carried out in a single fracture at the Aespoe Hard Rock Laboratory (HRL) in Sweden, are identified by solving the inverse problem in a framework of the maximum likelihood theory. From the results, it is found that the parameter value uncertainty caused by a conceptual model of radionuclide migration is greater than that caused by a fluctuation in the observed breakthrough curve data. (author)

2005-10-03

410

Site characterization progress report: Yucca Mountain, Nevada, October 1, 1990--March 31, 1991; Number 4  

Energy Technology Data Exchange (ETDEWEB)

In accordance with the requirements of Section 113 (b) (3) of the Nuclear Waste Policy Act of 1982, as amended (NWPA), the US Department of Energy (DOE) has prepared this report on the progress of site characterization activities at Yucca Mountain, Nevada, for the period October 1, 1990, through March 31, 1991. This report is the fourth in a series of reports that are issued at intervals of approximately six months during site characterization. The report covers a number of initiatives to improve the effectiveness of the site characterization program, and covers continued efforts related to preparatory activities, Study Plans, and performance assessment.

1991-10-01

411

Radiation safety in industrial applications  

International Nuclear Information System (INIS)

Oil and gas industry is the largest user of radioactive materials in Nigeria. They make use of radiation generators, sealed and unsealed radioactive sources.Some of these are potentially dangerous to human health and environment if not properly controlled. here is also the need to maintain control over occupational exposures to radiation, as well as to protect the public and the environment through proper management of wastes that may be radiologically hazardous. To minimize these, effective regulatory infrastructure is being put in place.For a smooth take-off of the nuclear power program, the National Nuclear Regulatory Authority and other stake holders in the nuclear industry need to start to put together licensing procedure for these.

2008-03-17

412

Depleted zinc: Properties, application, production  

Energy Technology Data Exchange (ETDEWEB)

The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.

2009-07-15

413

Clean Technology Application : Kupola Model Burner for Increasing the Performance of Spent Accu Recycle  

International Nuclear Information System (INIS)

Recycling of used battery for recovering lead done by either small household/small scale industries has been identified as a source of air pollution, especially by heavy metal (Pb). This condition give an adverse impact toward workers and societies. Technological aspect is one of the causal. The process apply an open system. Therefore, a lot of energy, as well as dust wasted to the air without prior treatment. For overcoming this condition, closed system by utilizing Cupola furnace will be offered as one of the alternatives clean technology application and to increase the recovering performance in order to set an effective and efficient result. (author)

2000-02-01

414

Boring of full scale deposition holes using a novel dry blind boring method  

Energy Technology Data Exchange (ETDEWEB)

As a part of the Finnish radioactive waste disposal research three holes (the size of deposition holes) were bored in the research tunnel at Olkiluoto in Finland. A novel full-face boring technique was used based on rotary crushing of rock and removal of crushed rock by vacuum flushing through the drill string an the purpose of the work was to demonstrate the feasibility of the technique. During the boring test procedures were carried out in order to determine the effect of charges in operating parameters on the performance of the boring machine and the quality of the hole. (refs.).

1996-11-01

415

Autonomic Management of Maintenance Scheduling in Chord  

CERN Document Server

This paper experimentally evaluates the effects of applying autonomic management to the scheduling of maintenance operations in a deployed Chord network, for various membership churn and workload patterns. Two versions of an autonomic management policy were compared with a static configuration. The autonomic policies varied with respect to the aggressiveness with which they responded to peer access error rates and to wasted maintenance operations. In most experiments, significant improvements due to autonomic management were observed in the performance of routing operations and the quantity of data transmitted between network members. Of the autonomic policies, the more aggressive version gave slightly better results.

2010-01-01

416

Drying plant waste; Trocknung von Betriebsabfaellen  

Energy Technology Data Exchange (ETDEWEB)

Under the repository storage conditions of Eram and Konrad, waste packages designed for permanent storage must not contain or release freely mobile liquids, except for the minimum residues attainable by reasonable efforts or unavoidable. In accordance with a directive issued by the German Federal Ministry for the Environment (BMU), waste conditioning must be carried out so as to minimize waste volumes and, if possible, on the site where the waste arises. Liquid waste is conditioned most effectively by drying. At the present time, various different processes for drying liquid waste are employed as reflected by the state of the art: The Robe process; roller drying; the RDA process; Favorit; in-drum drying; and HPA liquid waste drying with make-up feed. The HPA process offers these advantages: Drying under atmospheric ...

1995-11-01

417

The application of computer modeling to health effect research  

Energy Technology Data Exchange (ETDEWEB)

In the United States, estimates show that more than 30,000 hazardous waste disposal sites exist, not including military installations, U.S. Department of Energy nuclear facilities, and hundreds and thousands of underground fuel storage tanks; these sites undoubtedly have their own respective hazardous waste chemical problems. When so many sites contain hazardous chemicals, how does one study the health effects of the chemicals at these sites? There could be many different answers, but none would be perfect. For an area as complex and difficult as the study of chemical mixtures associated with hazardous waste disposal sites, there are no perfect approaches and protocols. Human exposure to chemicals, be it environmental or occupational, is rarely, if ever, limited to a single chemical. Therefore, it is essential that we consider multiple chemical effects and interactions in our risk ...

1996-12-31

418

PROBABILISTIC SAFETY ASSESSMENT OF OPERATIONAL ACCIDENTS AT THE WASTE ISOLATION PILOT PLANT  

Energy Technology Data Exchange (ETDEWEB)

This report presents a probabilistic safety assessment of radioactive doses as consequences from accident scenarios to complement the deterministic assessment presented in the Waste Isolation Pilot Plant (WIPP) Safety Analysis Report (SAR). The International Council of Radiation Protection (ICRP) recommends both assessments be conducted to ensure that ''an adequate level of safety has been achieved and that no major contributors to risk are overlooked'' (ICRP 1993). To that end, the probabilistic assessment for the WIPP accident scenarios addresses the wide range of assumptions, e.g. the range of values representing the radioactive source of an accident, that could possibly have been overlooked by the SAR. Routine releases of radionuclides from the WIPP repository to the environment during the waste emplacement operations are expected to be essentially zero. In contrast, potential accidental releases from ...

2000-09-01

419

Corrosion in waste incineration facilities; Korrosion i avfallsfoerbraenningsanlaeggningar  

Energy Technology Data Exchange (ETDEWEB)

Waste is a heterogeneous fuel, often with high levels of chlorine, alkali and heavy metals. This leads to much more severe corrosion problems than combustion of fossil fuels. The corrosion rates of the materials used can be extremely high. Materials used for heat transferring parts are usually carbon steel or low alloyed steel. These are significantly cheaper than other steels. Austenitic stainless steel is also used, but is often avoided due to its sensitivity to stress corrosion cracking. More advanced materials, such as nickel base alloys, can be used in extremely aggressive environments. Since these materials are expensive and do not always have sufficient mechanical properties, they are often used as coatings on carbon steel tubes or as composite tubes. A new method, which shows good results at the first tests in plants, is electroplating with nickel. Plastic materials can be used in low temperature parts if the temperature does not exceed 150 deg C. A ...

2004-11-01

420

Study on immobilizing radioactive slurry based on alkali-activated slag-clay minerals composite cement  

International Nuclear Information System (INIS)

The feasibility of immobilizing simulated radioactive slurry (SRS) by alkali-activated slag---clay minerals composite cement (AASCM) was studied under the experimental conditions. The results show that the dosage of SRS and water cement ratio (W/C) have significant effect on the flowability of the mixture of AASCM and SRS. The more dosage of SRS, the lower flowability. When cement/sand ratio is 1: 1 and W/C is 0.45, the flowability of the mixture meets the case of solidification engineering and the compressive strength of the waste forms containing 20% SRS meets the needs of GB 14569.1-93. The setting time of the mixture of AASCM and SRS is highly dependent on temperature while sorts of anions have little influence on it. The application of AASCM is suitable below 20 degree C. The leaching resistance of AASCM based waste forms is superior to that of OPC based waste forms. The control of the forms to ...

2006-03-01

421

Evaluation of the suitability of the WIPP site  

Energy Technology Data Exchange (ETDEWEB)

Determination of the suitability of the site for WIPP is only the first major phase in the evaluation of the radiological impact of the repository on the public health and safety. The Environmental Evaluation Group (EEG) will continue to independently review the design of the facility, the operational procedures, the criteria for packaging and shipment of the waste, the plans, procedures and results of the WIPP experiments, emergency preparedness, adherence to EPA and pertinent NRC regulations, and other important features of the project. EEG has concluded from existing evidence that the Los Medanos site for the WIPP project has been characterized in sufficient detail to warrant confidence in the validation of the site for the permanent emplacement of approximately 6 million cubic feet of defense transuranic waste. This conclusion is based on the assumption that the maximum surface dose rate for the unshielded remote-handled transuranic ...

1983-05-01

422

Ammonia recycling and destruction in a CFB gasifier  

Energy Technology Data Exchange (ETDEWEB)

Biomass contains nitrogen that is converted to NOx on combustion. Conversion of biomass into producer gas by thermal gasification offers an opportunity to reduce NOx-emissions by NH3 removal from the producer gas with water. Waste water will have to be treated before it can be drained. Recovered NH3 may have value as base chemical, but usually will have to be disposed off as waste. Recycling within the gasification process is an option to dispose off NH3 waste, provided NH3 is broken down under gasification conditions. We present experimental data on NH3 destruction in a CFB gasifier at temperatures from 780C to 860C, when NH3 is injected into the gasification air. Within that temperature range, the fraction of NH3 that is broken down increases from less than 50% to nearly 100%. Clearly, the presence of O2 at the injection point leads to a much higher rate of NH3 destruction than observed for purely thermal cracking. ...

2004-05-01

423

Achievement report in fiscal 2000. Model project to reduce electric power consumption at cement burning plant; 2000 nendo seika hokoku. Semento shosei plant denryoku shohi sakugen model jigyo  

Energy Technology Data Exchange (ETDEWEB)

In order to serve for efficient energy utilization and environmental improvement in the Republic of Vietnam, a 'Model project to reduce electric power consumption at cement burning plant' has been implemented. This paper summarizes the achievements. This project is intended to add an advanced, matured and reliable electric power generation facility using cement waste heat to the existing cement plant in Vietnam to produce steam and generate power by utilizing the waste heat generated from the preheating process in the burning plant. The present project has performed the detailed designing on the piping, electric facilities and instrumentation based on the basic agreement on the project. Fabrication of the piping has been executed by the Vietnam side. Valves and electric devices were procured and transported, including those fabricated in the previous fiscal year. Technology guiding personnel were sent for unpacking inspection, ...

2002-03-01

424

Waste laws. Waste Classification Ordinance. Residual Material Classification Ordinance. The Waste Technical Code. Ordinance on the Monitoring of Wastes and Residual Material. Ordinance on the Ban on CFCs and Halogenated Hydrocarbons. Packaging Ordinance. Sewage Ordinance. Text edition with index and an introduction by Dr. Clemens Weidemann. As of May 15, 1992. Abfallgesetz. AbfallbestimmungsV. ReststoffbestimmungsV. TA Abfall. Abfall- und ReststoffueberwachungsV. FCKW-Halon-VerbotsV. VerpackungsV. KlaerschlammV. Textausgabe mit Sachverzeichnis und einer Einfuehrung von Rechtsanwalt Dr. Clemens Weidemann. Stand: 15. Mai 1992  

Energy Technology Data Exchange (ETDEWEB)

The turbulent history of legislature concerned with the waste-management industry and the amount of material on this subject as well as the significance of the material in its own right led to the decision to publish all legal regulations on waste in one volume. It includes above all the Waste Law, Regulations on Determination of Waste, Regulations on Determination of Residual Products, Technical Instructions for Waste, Regulations for Monitoring Waste and Residual Products, Regulations on Probition from the Use of Chlorofluorohydrocarbons and Halon, Regulations on Packaging and Regulations on Sewage Sludge. The introduction explains the development and the role of the Waste Law and its applicability, goals and principles: The concept of waste, avoidance of waste, avoidance of ...

1992-01-01

425

Framework for managing wastes from oil and gas exploration and production (E&P) sites.  

Energy Technology Data Exchange (ETDEWEB)

Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental ...

2007-09-15

426

Attenuation of heavy metal leaching from hazardous wastes by co-disposal of wastes  

Energy Technology Data Exchange (ETDEWEB)

The potential hazard of landfill wastes was previously evaluated by examining the extraction procedures for individual waste, although various wastes were co-disposed of in actual landfills. This paper investigates the reduction of extraction-procedure toxicity by co-disposing various combinations of two wastes. When two wastes are mixed homogeneously, the extraction of heavy metals from the waste mixture is critically affected by the extract pH. Thus, co-disposal wastes will have a resultant pH between the pH values of its constituent. The lower the resultant pH, the lower the concentrations of heavy metals in the extract. When these wastes are extracted sequentially, the latter extracted waste has a stronger influence on the final concentration of heavy metals in the extract. Small-scale lysimeter ...

1996-12-31

427

Intercomparison of Retrospective Radon Detectors  

Energy Technology Data Exchange (ETDEWEB)

We performed both a laboratory and field intercomparison of two novel glass-based retrospective radon detectors previously used in major radon case-control studies performed in Missouri and Iowa. The new detectors estimate retrospective residential radon exposure from the accumulation of a long-lived radon decay product, Pb-210, in glass. The detectors use track registration material in direct contact with glass surfaces to measure the alpha emission of a Pb-210 decay product, Po-210. The detector's track density generation rate (tracks cm{sup -2} hr{sup -1}) is proportional to the surface alpha activity. In the absence of other strong sources of alpha emission in the glass, the implanted surface alpha activity should be proportional to the accumulated Po-210 and hence, the cumulative radon gas exposure. The goals of the intercomparison were to: (1) perform collocated measurements using two ...

1998-11-01

428

Survey reveals Europe's refinery-waste disposal methods, amounts, and costs  

Energy Technology Data Exchange (ETDEWEB)

Results of a survey conducted by Concawe on 75 oil refineries in Europe show that the total quantity of waste requiring disposal in 1986 was 0.5 million metric tons. This quantity of waste is but 0.13% of the total refinery throughput of 387 million metric tons during 1986. The survey revealed a wide range of disposal costs, depending on the particular properties of the waste and local conditions. A summary of total waste generation and how the waste is disposed of is shown. Details on the types of waste disposed, the disposal methods used, and the costs of disposal are detailed in this excerpt from the Concawe survey.

1989-08-28

429

Savannah River Site Interim Waste Management Program Plan FY 1991--1992  

Energy Technology Data Exchange (ETDEWEB)

The primary purpose of the Waste Management Program Plan is to provide an annual report of how Waste Management's operations are conducted, what facilities are being used to manage wastes, what forces are acting to change current waste management systems, and what plans are in store for the coming fiscal year. In addition, this document projects activities for several years beyond the coming fiscal year in order to adequately plan for safe handling, storage, and disposal of radioactive wastes generated at the Savannah River Site and for developing technology for improved management of wastes. In this document, work descriptions and milestone schedules are current as of December 1991.

1992-05-01

430

ICDF Complex Operations Waste Management Plan  

Science.gov (United States)

This Waste Management Plan functions as a management and planning tool for managing waste streams generated as a result of operations at the Idaho CERCLA Disposal Facility (ICDF) Complex. The waste management activities described in this plan support the selected remedy presented in the Waste Area Group 3, Operable Unit 3-13 Final Record of Decision for the operation of the Idaho CERCLA Disposal Facility Complex. This plan identifies the types of waste that are anticipated during operations at the Idaho CERCLA Disposal Facility Complex. In addition, this plan presents management strategies and disposition for these anticipated waste streams.

2006-12-01

431

Defense remote-handled transuranic waste implementation plan: Transuranic Waste Program System Integration Office  

Energy Technology Data Exchange (ETDEWEB)

This document presents a detailed schedule for the implementation of the strategy for managing defense remote-handled (RH) transuranic (TRU) waste. The baseline management strategy was defined in the Defense Remote-Handled Transuranic Waste Cost/Schedule Optimization Study and is summarized in this document. Also included are revised RH TRU waste inventory projections, current site management plans, a list of key decision points and milestones, and a discussion of uncertainties associated with management of RH TRU waste. The plans are summarized in a detailed schedule diagram and in an RH TRU waste work off diagram. 9 refs., 5 figs., 4 tabs.

1988-01-01

432

Proceedings of the phytoremediation technical seminar  

International Nuclear Information System (INIS)

The research and development efforts regarding phytoremediation technologies were the main focus of this conference. Phytoremediation is the term for any applied process that uses green plants and their associated microorganisms for remediating contaminated soils and groundwater. The 12 papers presented at this conference provided guidance on recommended requirements for the successful implementation of specific phytoremediation technologies. The mechanisms of phytoremediation for petroleum hydrocarbons were also described. Phytoremediation technologies are divided into two major classes including contaminant removal and contaminant stabilization. Several studies have shown that phytoremediation is effective in degrading, containing and transferring petroleum hydrocarbons in soil and groundwater. Phytoremediation has shown to hold promise for the effective and inexpensive cleanup of various hazardous wastes. refs., tabs., ...

433

Problem of microelements in the combustion, gasification and hydrogenation of coals  

Energy Technology Data Exchange (ETDEWEB)

Role of microelements in coal in connection with their combustion in power stations, gasification and hydrogenation is discussed from the standpoint of environmental pollution and effects on technological parameters. In the wastes from fossil-fuel power stations there are biogenic and toxic elements (Be, B, Pb, etc.) present, which eventually go into the soil. Analyses showed that coal from the Kuznetsk, Donetsk, Ehkibastuz and Kansk-Achinsk basins which are used for power, have a relatively low level of biogenic and toxic microelements, e.g. Ba, B, Mn, Pb, Co, Ni, V, Cu, Y. Coal reactivity in gasification and hydrogenation is discussed. The catalytic effect of several microelements in coal gasification and hydrogenation is established. A geochemical multiplicative indicator is presented which makes quantitative evaluation of the suitability of coals for hydrogenation possible. 17 references.

1984-11-01

434

IAEA RESEARCH CONTRACTS FIRST ANNUAL REPORT. Technical reports Series No. 4  

Science.gov (United States)

Summaries are included of research contracts which expired prior to Dec. 31, 1960. The contracts were concerned with investigations of: electrophysiological responses of biological systems in nerve cells to irradiation with small doses of ionizing radiations; the mode of the protective action of certain sulfhydryl compounds against radiation effects on the synthesis of deoxyribonucleic acid, using tritium-labeled thymidine; development of a bubble chamber method of monitoring and dosimetry for Low fast neutron fluxes; effects of incorporated radioisotopes on the stability of genetic materials; interrelation of root and leaf absorption of radioisotopes in herbaceous plants; uptake of radioactive wastes by lowland rice from soils contaminated by irrigation water, and decontamination of the rice; and comparison between mutation rates induced by acute and chronic gamma irradiations. (B.O.G.)

1961-01-01

435

Cleaning of flue gases from cupola and electric steel melting furnaces in ''Ural'' rotoclones  

Energy Technology Data Exchange (ETDEWEB)

A highly effective and economical apparatus was developed by the All-Union Scientific Research Institute for Energy and Nonferrous Metallurgy for cleaning waste gases from cupola and electric arc steel melting furnaces --- the ''Ural'' rotoclone, which has been successfully introduced in many enterprises. Research results are presented for the efficiency of operation of these aggregates on equipping them on cupola and electric furnaces. With a 2 kPa aerodynamic resistance of the rotoclone the flue gas of the cupola furnace is cleaned to the sanitary standard. Highly effective collection of sublimates and aerosols from the electric arc furnace takes place with a ''Ural'' rotoclone aerodynamic resistance

1981-01-01

436

Streams of solid municipal wastes. Evaluation of data on the basis of waste follow-up system; Kiinteaen yhdyskuntajaetteen virrat: aineistotarkastelua jaetealan seurantajaerjestelmaen avulla  

Energy Technology Data Exchange (ETDEWEB)

The follow-up system for wastes (JAeSTI), developed at the end of the 1990s, forms a basis for today's followup activities in Finland. JAeSTI relies on an environmental protection database, the compliance monitoring system VAHTI operated by the environmental authorities. Waste followup and waste statistics depend very much on the annual waste quantities recorded in the VAHTI system. In the KYJ-project the coverage and reliability of the data in the VAHTI system was evaluated as for the streams of solid municipal waste. The project also included the compiling of national statistics on municipal waste for the year 2000. The project used other information sources, too, such as statistics compiled when the National Waste Plan and regional waste plans were revised in 2002. In addition, the extent and quantity of ...

2004-07-01

437

Three-phase flow in heterogeneous wettability porous media; Deplacements triphasiques en milieux poreux de mouillabilite heterogene  

Energy Technology Data Exchange (ETDEWEB)

Better understanding and modelling of three-phase flow through porous media is of great interest, especially for improved oil recovery methods such as gas injection processes. Early theoretical and experimental studies have already demonstrated that the wettability characteristics of the solid surface and the spreading characteristics of the fluid system hold the key roles. This observation is confirmed by our theoretical results using DLP theory on the stability and the thickness of static oil films. In most of the works related to three-phase flow processes, homogeneous wettability is assumed. There exist only a few studies demonstrating the tremendous impact of the wettability heterogeneities on gas injection. The objective of the present work is twofold: to demonstrate the effect of small scale wettability heterogeneities on gas injection efficiency, and to develop a tool to predict this impact for various patterns and spatial distributions. To this end an ...

1998-11-26

438

Study of ytterbium doping effects on structural, mechanical and opto-thermal properties of sprayed ZnO thin films using the Boubaker Polynomials Expansion Scheme (BPES)  

Energy Technology Data Exchange (ETDEWEB)

In this work, ZnO thin films have been grown on glass substrates by using a solution of propanol (C{sub 3}H{sub 8}O), water (H{sub 2}O) and zinc acetate (Z{sub n}(CH{sub 3}CO{sub 2}){sub 2}) in acidified medium (pH 5). The obtained films were n doped with ytterbium (Yb) at the rates of 100, 200 and 300 ppm. The structural features of the doped films were investigated using XRD, atomic force microscopy and scanning electronic microscopy techniques. XRD analysis shows a strong (0 0 2) X-ray diffraction line for increasing Yb-doping amounts. This c-axis preferential orientation of ZnO crystallites is naturally required to use this oxide as transparent conductor in optoelectronic applications. Atomic force microscopy (AFM) analysis shows an enhancement in the surface roughness of the doped ZnO:Yb thin films. Optical measurements were performed in 300-1800 nm domain via transmittance T(lambda) and reflectance R(lambda) spectra. Conjoint optical and thermal properties ...

2009-10-19

439

Study of ytterbium doping effects on structural, mechanical and opto-thermal properties of sprayed ZnO thin films using the Boubaker Polynomials Expansion Scheme (BPES)  

International Nuclear Information System (INIS)

In this work, ZnO thin films have been grown on glass substrates by using a solution of propanol (C3H8O), water (H2O) and zinc acetate (Zn(CH3CO2)2) in acidified medium (pH 5). The obtained films were n doped with ytterbium (Yb) at the rates of 100, 200 and 300 ppm. The structural features of the doped films were investigated using XRD, atomic force microscopy and scanning electronic microscopy techniques. XRD analysis shows a strong (0 0 2) X-ray diffraction line for increasing Yb-doping amounts. This c-axis preferential orientation of ZnO crystallites is naturally required to use this oxide as transparent conductor in optoelectronic applications. Atomic force microscopy (AFM) analysis shows an enhancement in the surface roughness of the doped ZnO:Yb thin films. Optical measurements were performed in 300-1800 nm domain via transmittance T(?) and reflectance R(?) spectra. Conjoint optical and thermal properties were deduced from the optical measurements in ...

2009-10-19

440

Effects of matrix resin and fiber content on behavior of fatigue crack propagation in continuous-fiber-mat reinforced CP-resin composites; Renzoku sen`i mat kyoka CP resin fukugozai no hiro kiretsu denpa tokusei ni oyobosu bozai oyobi sen`i gan`yuritsu no eikyo  

Energy Technology Data Exchange (ETDEWEB)

The purpose of the present work is to investigate the effects of matrix resin and fiber content on the behavior of fatigue crack propagation in continuous-glass-fiber-mat reinforced CP-resin composites. For this purpose, ductile matrix resin and brittle one are used. These two kinds of resins have the characteristic that the elastic modulus and tensile strength are nearly the same with each other while the elongation is different. The composite specimens are made of these resins and continuous grass fiber mat of 20 wt.% and 60 wt% fiber contents. The fatigue crack propagation test was conducted by using the tapered DCB specimens to control the stress intensity factor range, {delta}K, during the test. The results obtained are as follows; (1) The relation between the crack propagation rate, da/dN, and {delta}K for all the present materials is shown by a straight line in logarithmic representation. (2) For the composites of 20 wt.% fiber content, ...

1996-05-15

441

Neutron cross-sections on minor actinides for next generation reactors: new data from n_TOF (CERN)  

International Nuclear Information System (INIS)

Full text: Climatic problems associated to the greenhouse effect have recently stimulated a renewed interest in nuclear energy production, and triggered new studies aimed at developing future generation systems that would address current major safety, proliferation and waste concerns. In particular a possible solution to the waste problem could come from transmutation of the highly radiotoxic nuclear waste in Accelerator Driven Systems or in Generation-IV fast nuclear reactors. The design and operation of the new systems require accurate cross-section data on a large number of isotopes, in particular plutonium, minor actinides, long-lived fission fragments and structural materials. An important contribution to the field is being provided since a few years by a new time of-flight facility operative at CERN, n_TOF. The main features of the neutron beam, in particular the wide energy spectrum, ranging from ...

2008-06-01

442

Some features of the atomic radial-distribution functions of metal glasses  

Energy Technology Data Exchange (ETDEWEB)

This paper attempts to explain the peculiarities of the radial-distribution function of metal glasses without involving ideas of the amorphous structure. On a computer, the radial atomic density for a spherical eutectic single crystal of the composition Fe/sub 84/C/sub 16/ of radius 15 A formed by alternating small crystals of e-Fe and Fe/sub 3/C of cubic form with the edge of the cube ca 10 A. For the sake of clarity, the diagram of such a quasisingle crystal is shown and has been given a cubic boundary. The change in the relationship between the heights of the subpeaks of the second maximum of the radial distribution function of atoms in the Fe-B glasses with a change in the concentration of boron can be explained by the change in the space group of the Fe/sub 3/B metastable boride which is formed in this system.

1986-09-01

443

Memory of multiple aging stages above the freezing temperature in the Relaxor ferroelectric PLZT.  

Science.gov (United States)

The dynamic dielectric susceptibility and the elastic compliance of the relaxor ferroelectric lanthanum lead zirconate titanate (PLZT) 9/65/35 have been measured under different cooling and heating protocols in order to study aging and memory. The memory of multiple aging stages at different temperatures has been found (several dips in the susceptibility curves on heating), as in spin glass systems below the glass transition. Remarkably, in PLZT the memory of several aging stages is retained also above the freezing temperature deduced from the dynamic susceptibilities. The results are discussed in light of the existing models of aging and memory in spin and dipolar glasses. PMID:15447139

2004-08-24

444

Mechanical properties of SiAlON glass surface after swift heavy-ion bombardment  

International Nuclear Information System (INIS)

A Y-Mg-Si-Al-O-N glass was submitted to swift heavy-ion bombardment at GANIL (Caen, France) and the influence of irradiation on the mechanical properties was studied. The mechanical properties of the glass were characterized both before and after irradiation. Changes in hardness, elastic modulus and fracture toughness of the near-surface irradiated layer were determined using indentation techniques. SRIM calculations allowed to estimate the ions penetration range and the energy deposition relative to electronic and nuclear interactions, which can be correlated to the experimental damaged depth. Meyer's hardness and Young's modulus decrease by about 30 %, while fracture toughness is increased by more than 40 %. (authors)

445

Fluoride release from an orthodontic glass ionomer adhesive in vitro and enamel fluoride uptake in vivo  

British Library Electronic Table of Contents (United Kingdom)

Introduction The objective of this study was to investigate the in-vitro fluoride release from a glass ionomer orthodontic bonding system (Fuji I, GC Corporation, Tokyo, Japan) over a 2-month period and the in-vivo enamel fluoride uptake after 6 months. Methods Ten metal brackets were bonded with either glass ionomer or composite resin (Transbond XT, 3M Unitek, Monrovia, Calif; Light Cure), which served as controls, to recently extracted molars. The bonded teeth, cut at the level of their roots, were stored in distilled water that was renewed after every fluoride measurement at 1, 3, 7, 30, and 60 days. The in-vitro fluoride release was measured by using a fluoride ion-selective electrode, connected to an ion analyzer. Fifteen pairs of premolars were bonded with metal brackets with either ...

2010-01-01

446

Effect of secondary fuels and combustor temperature on mercury speciation in pulverized fuel co-combustion: part 1  

Energy Technology Data Exchange (ETDEWEB)

The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel ...

2007-08-15

447

Assessment of Distribution and Decontamination Factor during Melt Decontamination of Scrap Metal Contaminated with Natural Uranium  

International Nuclear Information System (INIS)

Metal waste generated from domestic nuclear operation for defense and commercial application has led to a growing stockpile of radioactively contaminated scrap metal, much of which is stainless steel. A significant fraction of this material cannot be efficiently surface decontaminated. The burial of this material would be wasteful and expensive, since long term monitoring would be necessary in order to minimize environmental risk. Much of this waste consists of bulky equipment. In many case, this equipment contains valuable material that may be recycled. The piece of equipment considered frequently also has complex geometries, making extremely difficult, time-consuming and expensive to determine the exact location and level of radioactivity on the internal surfaces. After melting, however, the radioactivity may be precisely determined from samples of each ingot. Moreover, an ingot may be released for restricted or ...

2007-05-10

448

Application of 'waste' wood-shaving bottom ash for adsorption of azo reactive dye.  

Science.gov (United States)

The utilization of wood-shaving bottom ash (WBA) for the removal of Red Reactive 141 (RR141), an azo reactive dye, was investigated. WBA/H(2)O and WBA/H(2)SO(4) were made by treating WBA with water and 0.1M H(2)SO(4), respectively, to increase adsorption capacity. Adsorption of RR141 from reactive dye solution (RDS) and reactive dye wastewater (RDW) by WBA/H(2)O and WBA/H(2)SO(4) involved the BET surface area and pore size diameter. Properties of adsorbents, effect of contact time, initial pH of solution, dissolved metals and elution studies indicated that the decolorisation mechanism involved both chemical adsorption and precipitation with calcium ions. In addition, the WBA/H(2)SO(4) surface might contain sulphate-cation complexes that were specific to enhancing dye adsorption from RDW. The adsorption isotherm had a best fit by the Freundlich model. Freundlich parameters showed that WBA/H(2)O used more heterogeneous surface than WBA/H(2)SO(4) and activated carbon ...

2008-04-23

449

Rare-earth doped (#alpha#'/#beta#')-sialon ceramics  

International Nuclear Information System (INIS)

The objectives of this research were to investigate the possibility of controlling the #alpha#'/#beta#' phase ratio and morphology in Sialon ceramics. These objectives have been sought by the control of the starting composition, and by post sintering heat treatment. The main emphasis has been on the production of a series of #alpha#' and (#alpha#'+#beta#') Sialon ceramics with a minimum amount of the glass phase by the pressureless sintering technique and using ytterbium (Yb) as an #alpha#' stabilising element. The Yb additions were made via the oxide or the alumino- silicate presynthesised glass; the latter was found to improve the density. The XRD analysis of the as sintered materials revealed #alpha#' to be the dominant phase with minor contributions from #beta#' sialon and/ or 12H A1N polytype. Additions of SiO_2 or #beta#-Si_3N_4 were made to various materials to assess potential mechanisms for obtaining control over the microstructural ...

450

The Waste of the World  

Environmental Research Database

ObjectivesThis programme aims; To rethink how waste is thought about in social science; To provide a global analysis of waste; To examine how rethinking waste impinges on core social science concerns, notably: economies, researching globalisation, hazards and risk, and materiality. Social science understandings of waste position waste as the end-point of production and consumption, and see waste as a question of disposal.DescriptionThe Waste of the World is a five year research programme funded under ESRC's Large Grant Scheme. It brings together researchers in geography, anthropology and materials science from the University of Sheffield, Durham University, University College London and Goldsmiths College London, and connects the UK with South Asia (particularly India and Bangladesh), as well as the US, Europe and Kazakhstan. The ...

2011-01-30

451

Operable Unit 3-13, Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) Waste Management Plan  

Energy Technology Data Exchange (ETDEWEB)

This Waste Management Plan describes waste management and waste minimization activities for Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory. The waste management activities described in this plan support the selected response action presented in the Final Record of Decision for Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13. This plan identifies the waste streams that will be generated during implementation of the remedial action and presents plans for waste minimization, waste management strategies, and waste disposition.

2006-07-01

452

Waste sampling and characterization facility (WSCF) maintenance implementation plan  

Energy Technology Data Exchange (ETDEWEB)

This Maintenance Implementation Plan (MIP) is written to satisfy the requirements of the US Department of Energy (DOE) Order 4330.4B, Maintenance Management Program that specifies the general policy and objectives for the establishment of the DOE controlled maintenance programs. These programs provide for the management and performance of cost effective maintenance and repair of the DOE property, which includes facilities. This document outlines maintenance activities associated with the facilities operated by Waste Management Hanford, Inc. (WMH). The objective of this MIP is to provide baseline information for the control and execution of WMH Facility Maintenance activities relative to the requirements of Order 4330.4B, assessment of the WMH maintenance programs, and actions necessary to maintain compliance with the Order. Section 2.0 summarizes the history, mission and description of the WMH facilities. Section 3.0 describes maintenance scope ...

1997-08-13

453

Study on separation of CO2 gas by TSS (thermal swing sublimation) method. Part 2; TSS ho (Thermal Swing Sublimation: ondo swing shokaho) ni yoru tansan gas bunri no kenkyu. 2  

Energy Technology Data Exchange (ETDEWEB)

TSS (thermal swing sublimation) method was studied which uses vaporization heat and sensible heat of LNG for solidification and separation of CO2 gas in waste gases of LNG-fired combined cycle power generation system. In experiment, the mixed gas composed of CO2, H2O and N2 was used for simulating waste gas of LNG-fired combined cycle power generation systems, and the growth behavior of ice and dry ice was studied for developing dry ice making technology under low-temperature condition. As the experimental result, the following were clarified: various crystal structures depending on cooling temperature, the effect of gas flow rate on peeling of surface precipitated solids, and solidification characteristics of H2O/CO2 mixed gas. The growth rate of precipitated solid film thickness decreased with an increase in gas flow rate, while increased with CO2 concentration. The shape of a dry ice sublimator similar to that of a ...

1997-03-21

454

Study on a recovery of rare earth oxides from a LiCl-KCl-RECl3 system  

British Library Electronic Table of Contents (United Kingdom)

Radioactive rare earth chlorides in waste LiCl-KCl molten salts have to be separated as a stable form to minimize waste volume and to achieve stable solidification. In this work, thermal behavior of rare earth chlorides (CeCl3, GdCl3, NdCl3, PrCl3) was investigated in an oxygen condition to recover rare earth oxides from a LiCl-KCl-RECl3 system. The rare earth chlorides in the LiCl-KCl molten salts were smoothly converted to an oxychloride form at a higher temperature than 650degreeC, except for CeCl3. CeCl3 was totally converted to an oxide from at a higher temperature than 450degreeC. The rare earth oxychlorides (GdOCl, NdOCl, PrOCl) were effectively converted to oxide forms at a higher temperature than 1100degreeC. It was confirmed that rare earth oxides can be recovered from a LiCl-KCl...

2011-01-01

455

Second mission of North-Cotentin radio-ecology group. The uncertainty calculation; Deuxieme mission du Groupe Radio-ecologie Nord-Cotentin. Le calcul d'incertitude  

Energy Technology Data Exchange (ETDEWEB)

The present study treats only the collective risk of ex-utero leukaemia associated with the routine releases of the nuclear industrial installations of the North Cotentin (0.0009 cases over the considered period) the uncertainty on the contribution to the collective risk of the incidents and the accidents of the nuclear installations (notably the drilling of the pipe of release in sea arisen in 1979-1980 and the fire of the waste silo on January 6. 1981, for the reprocessing plant of La Hague has not been considered. Only 45% of the risk are taken into account by the study. Every calculated value remains very inferior to the number of leukemia cases observed (4 cases observed for two expected cases) and to the risk of radioinduced leukemia any merged exposure sources, that is to say 0.84 cases. It appears thus not very probable that the nuclear installations of the North - Cotentin can explain the tendency to the excess of observed leukaemia. The limits of the ...

2003-03-15

456

Safety assessment for clearance of radioactive metal wastes from nuclear facility  

Energy Technology Data Exchange (ETDEWEB)

Safety assessments for clearance of H-beam and valves, main radioactive metal wastes in Kori nuclear power plants, were carried out to derivate a decontamination factor for satisfying the dose limits of clearance level (Maximum individual dose: 10 {mu}Sv/y, collective dose: 1 man{center_dot}Sv/y) in Korea. Maximum individual dose and collective dose were evaluated by internal dose conversion factor which based on the concept of effective dose in ICRP publication 60. The results of maximum individual dose and collective dose is 139 {mu}Sv per year and 0.166 man{center_dot}Sv per year about H-beam, and 158 {mu}Sv per year and 0.468 man{center_dot}Sv per year about valves respectively. Demand decontamination factor satisfied with, which is respectively more than 13.9 and 15.8 for satisfying clearance level.

2003-10-01

457

Safety assessment for clearance of radioactive metal wastes from nuclear facility  

International Nuclear Information System (INIS)

Safety assessments for clearance of H-beam and valves, main radioactive metal wastes in Kori nuclear power plants, were carried out to derivate a decontamination factor for satisfying the dose limits of clearance level (Maximum individual dose: 10 #mu#Sv/y, collective dose: 1 man#centre dot#Sv/y) in Korea. Maximum individual dose and collective dose were evaluated by internal dose conversion factor which based on the concept of effective dose in ICRP publication 60. The results of maximum individual dose and collective dose is 139 #mu#Sv per year and 0.166 man#centre dot#Sv per year about H-beam, and 158 #mu#Sv per year and 0.468 man#centre dot#Sv per year about valves respectively. Demand decontamination factor satisfied with, which is respectively more than 13.9 and 15.8 for satisfying clearance level.

2003-10-01

458

Positron emission tomography for modelling of geochemical transport processes in clay  

Energy Technology Data Exchange (ETDEWEB)

Geological clay formations are investigated for use as final underground deposit for heat producing nuclear waste. Special kinds of clay (e.g. bentonite) can also be used for the construction of geotechnical barriers. For the long time safety prognosis of the nuclear waste repositories the development of geochemical transport models is indispensable. The transport of aqueous solutions in clay is a complex process. The three-layer-minerals bentonite and illite swell by the adsorption of water, if the volume is restricted a high swelling pressure develops. The excellent barrier effect of natural clay formations and geotechnical clay barriers is based on the high swelling pressure and the high adsorption capacity for radionuclides and other pollutants. The two-layer-mineral kaolinite has no swelling capacity. In contrast to sandy layers a special geochemical transport potential exists in clay besides the well known matrix ...

2004-07-01

459

Performance evaluation of corrosion probes in simulated WVNS tank 8D-2 waste: WVNS tank farm process support  

Energy Technology Data Exchange (ETDEWEB)

Five corrosion probes were received from West Valley Nuclear Services for evaluation in simulated tank 8D-2 3rd-stage sludge wash slurry. The same waste slurry simulated was also used in a series of ongoing corrosion studies assessing the effects of in-tank sludge washing on the integrity of tank 8D-2. Two of the corrosion probes were installed in the coupon corrosion test vessels operating at {approximately}150{degrees}F to compare performance of the probes with that observed by coupon tests conducted in the same vessels. Corrosion rate data calculated from electrical resistance measurements of the corrosion probes were evaluated for this study using two slightly different approaches. One approach uses the total length of exposure of the probe to give a ``time-averaged`` value of the corrosion rate. The other approach uses a shorter period of time (relative to the length of the test) in the calculation of corrosion rate, and is referred to as ...

1994-07-01

460

Parametric Cost Estimates for an International Competitive Edge  

Science.gov (United States)

This paper summarizes the progress to date by CH2M HILL and the UKAEA in development of a parametric modelling capability for estimating the costs of large nuclear decommissioning projects in the United Kingdom (UK) and Europe. The ability to successfully apply parametric cost estimating techniques will be a key factor to commercial success in the UK and European multi-billion dollar waste management, decommissioning and environmental restoration markets. The most useful parametric models will be those that incorporate individual components representing major elements of work: reactor decommissioning, fuel cycle facility decommissioning, waste management facility decommissioning and environmental restoration. Models must be sufficiently robust to estimate indirect costs and overheads, permit pricing analysis and adjustment, and accommodate the intricacies of international monetary exchange, currency fluctuations and contingency. The development ...

2006-07-01

461

Parametric Cost Estimates for an International Competitive Edge  

International Nuclear Information System (INIS)

This paper summarizes the progress to date by CH2M HILL and the UKAEA in development of a parametric modelling capability for estimating the costs of large nuclear decommissioning projects in the United Kingdom (UK) and Europe. The ability to successfully apply parametric cost estimating techniques will be a key factor to commercial success in the UK and European multi-billion dollar waste management, decommissioning and environmental restoration markets. The most useful parametric models will be those that incorporate individual components representing major elements of work: reactor decommissioning, fuel cycle facility decommissioning, waste management facility decommissioning and environmental restoration. Models must be sufficiently robust to estimate indirect costs and overheads, permit pricing analysis and adjustment, and accommodate the intricacies of international monetary exchange, currency fluctuations and contingency. The development ...

462

Nuclear power and sustainable development  

International Nuclear Information System (INIS)

In Romania, the nuclear power is an element of sustainable development, being competitive, efficient and viable in the market economy. Fuel supply is ensured as nuclear fuel is manufactured in the country out of local uranium resources available in Romania. As for the environmental protection, it is known that, unlike the thermal power plants, the nuclear power plants do not release sulfur and nitrogen oxides, carbon dioxide and do not generate slag and ashes. The operation of nuclear power units does not release pollutants and, accordingly, these stations can contribute to the limitation and the abatement of environmental pollution. After seven years of Cernavoda NPP Unit 1 operation, a facility for storing low and medium level nuclear fuel wastes was built at the plant site as well as an intermediate dry storage for spent nuclear fuel whose first modules were commissioned in July 2003. They shall provide safe storage conditions for nuclear fuel ...

2003-07-01

463

NICE3: Dyebath reuse in carpet manufacturing  

Energy Technology Data Exchange (ETDEWEB)

Fact sheet on an analysis system for dyebath processes in the carpet manufacturing industry written for the NICE3 Program. The Georgia Institute of Technology (G.I.T.) has developed an effective automated dyebath analysis and reuse system that improves the energy, environmental, and economic performance of dyehouse batch operations. The new system enables dyeing solutions to be accurately monitored and adjusted for reuse. According to industry estimates, 160 pounds of water are used to produce each pound of textile product. The current wasteful batch dyeing process requires all water and residual chemicals, as well as the energy required to heat the mixture for dyeing, to be dumped after one application. Spent dyebaths can only be reused after they are sampled, analyzed, and reconstituted, a process requiring labor and expertise that are unavailable in the dyehouses. Therefore, successful commercial reuse depends on an automated analysis system ...

1999-09-29

464

Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel(II) from aqueous solution  

British Library Electronic Table of Contents (United Kingdom)

The removal of Ni(II) from aqueous solution by magnetic nanoparticles prepared and impregnated onto tea waste (Fe3O4-TW) from agriculture biomass was investigated. Magnetic nanoparticles (Fe3O4) were prepared by chemical precipitation of a Fe^2^+ and Fe^3^+ salts from aqueous solution by ammonia solution. These magnetic nanoparticles of the adsorbent Fe3O4 were characterized by surface area (BET), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). The effects of various parameters, such as contact time, pH, concentration, adsorbent dosage and temperature were studied. The kinetics followed is first order in nature, and the value of rate constant was found to be 1.90x10^-^2min^-^1 at 100mgL^-^1 and 303K. Removal ef...

2011-01-01

465

Local government`s pollution prevention program  

Energy Technology Data Exchange (ETDEWEB)

The pollution prevention program operated by the Health Department of Boulder County is called Business Partners for a Clean Environment (Business Partners). It is a cooperative effort among local businesses, the City of Boulder, Boulder County, and the Boulder Chamber of Commerce. This nonregulatory, incentive-based program provides industry with pollution prevention information and technical assistance necessary to reduce and/or eliminate environmental waste. This paper provides an overview of the program development, creation of partnerships and trust, and some of the results from implementation of the program. Following the first 18 months of the program, 35 businesses were recognized as Business Partners. The Business Partners program has also received an achievement award from the National Association of Counties for promoting {open_quotes}responsible, responsive, and effective government{close_quotes} and two governor`s awards from the ...

1996-12-31

466

Integrated thermal and nonthermal treatment technology and subsystem cost sensitivity analysis  

Energy Technology Data Exchange (ETDEWEB)

The U.S. Department of Energy`s (DOE) Environmental Management Office of Science and Technology (EM-50) authorized studies on alternative systems for treating contact-handled DOE mixed low-level radioactive waste (MLLW). The on-going Integrated Thermal Treatment Systems` (ITTS) and the Integrated Nonthermal Treatment Systems` (INTS) studies satisfy this request. EM-50 further authorized supporting studies including this technology and subsystem cost sensitivity analysis. This analysis identifies areas where technology development could have the greatest impact on total life cycle system costs. These areas are determined by evaluating the sensitivity of system life cycle costs relative to changes in life cycle component or phase costs, subsystem costs, contingency allowance, facility capacity, operating life, and disposal costs. For all treatment systems, the most cost sensitive life cycle phase is the operations and maintenance phase and the most cost sensitive ...

1997-02-01

467

Federal Facility Agreement plans and schedules for liquid low-level radioactive waste tank systems at Oak Ridge National Laboratory, Oak Ridge, Tennessee  

Energy Technology Data Exchange (ETDEWEB)

Although the Federal Facility Agreement (FFA) addresses the entire Oak Ridge Reservation, specific requirements are set forth for the liquid low-level radioactive waste (LLLW) storage tanks and their associated piping and equipment, tank systems, at ORNL. The stated objected of the FFA as it relates to these tank systems is to ensure that structural integrity, containment and detection of releases, and source control are maintained pending final remedial action at the site. The FFA requires that leaking LLLW tank systems be immediately removed from service. It also requires the LLLW tank systems that do not meet the design and performance requirements established for secondary containment and leak detection be either upgraded or replaced. The FFA establishes a procedural framework for implementing the environmental laws. For the LLLW tank systems, this framework requires the specified plans and schedules be submitted to EPA and TDEC for approval within 60 days, or ...

1992-03-01

468

Factors determining the stainless steel decontamination efficiency for the steam generator heat exchanger tubes at NPPs with the WWERs  

International Nuclear Information System (INIS)

To raise the efficiency of the redox method and decrease the amount of radioactive wastes, a possibility of improving the decontamination process for NPP heat exchanger tubes made of stainless steel is studied. In the home practice the redox method of equipment decontamination is carried out as a multi-cycle process. In each cycle the surface is treated first with a permanganate alkaline solution ther with an oxalic acid solution, with a condensate washing-at between the treatments. Using samples cut out of the steam generator pipelines of the first and third power units of the Novovoronezh NPP the effect of the oXalic acid concentration, as well as washout time and conditions on the decontamination factor are studied. On the basis of analysis of the obtained data a conclusion is drawn that using oxalic acid of low concentrations and increasing its concentrations from cycle to cycle maximum decontamination factor values can be obtained at a ...

469

Development program for magnetically assisted chemical separation: Evaluation of cesium removal from Hanford tank supernatant  

International Nuclear Information System (INIS)

Magnetic particles (MAG*SEP"S"M) coated with various absorbents were evaluated for the separation and recovery of low concentrations of cesium from nuclear waste solutions. The MAG*SEP"S"M particles were coated with (1) clinoptilolite, (2) transylvanian volcanic tuff, (3) resorcinol formaldehyde, and (4) crystalline silico-titanate, and then were contacted with a Hanford supernatant simulant. Particles coated with the crystalline silico-titanate were identified by Bradtec as having the highest capacity for cesium removal under the conditions tested (variation of pH, ionic strength, cesium concentration, and absorbent/solution ratio). The MAG*SEP"S"M particles coated with resorcinol formaldehyde had high distribution ratios values and could also be used to remove cesium from Hanford supernant simulant. Gamma irradiation studies were performed on the MAG*SEP"S"M particles with a gamma dose equivalent to 100 cycles of use. This irradiation decreased the loading ...

1994-05-09

470

Determination of pressure distribution in an aerated bed in a controlled pilot-scale compost reactor  

Energy Technology Data Exchange (ETDEWEB)

This study investigated the effectiveness of dealing with biological waste by composting. In particular, it examined the feasibility of recovering excess thermal energy produced in the process of composting biological waste in terms of mass and energy transport parameters required in the aerated compost bed. An experiment was performed in which a 100 dm{sup 3} adiabatic, leak-tight reactor equipped with a controlled aeration system was constructed to study the temperature and pressure distribution in the bed. Sensors were used to determine the amount and humidity of emitted gases under variable external physical conditions. The perforated bottom of the reactor allowed for bed aeration. As such, the humidity and heat were transported upwards, forced by the air pumped in and by natural convection. In terms of pressure distribution inside the composted and aerated bed, the study results showed that there were considerable ...

2010-07-01

471

Changes in aerobic digester performance with the use of methanol for biological nutrient removal in a full-scale sequencing batch reactor  

Energy Technology Data Exchange (ETDEWEB)

Increasingly, governments enact more stringent regulations governing nitrogen and phosphorus in the discharge effluent of wastewater treatment plants. Scientists know that nitrogen and phosphorus accelerates the eutrophication of lakes and reservoirs and stimulates algal growth. Ammonia has proven to be toxic to aquatic life forms, including fish. Engineers favour Biological Nutrient Removal (BNR) over chemical addition to wastewater treatment. Sequencing Batch Reactors (SBRs), a type of bioreactor requiring less land, provide the anaerobic, anoxic, and aerobic zones necessary for BNR. Methanol was used as an effective external source of carbon for denitrification but lacked research. The authors remedied this situation and some of the results were available. They indicated that the addition of methanol in the SBR increased solids production in the SBR, leading to increased sludge wasting to the aerobic digester. All aspects of the sludge ...

2000-07-01

472

Biological in situ remediation of a former pond for trickling waste water containing explosives  

Energy Technology Data Exchange (ETDEWEB)

WASAG DECON developed a concept for the biological in situ remediation of an TNT-contaminated former seepage pond. This pond is located on the site of an ammunition factory in Lower Saxony. Unit 1982 all the waste water from the production buildings was directed into this pond, including TNT-contaminated water from the flushing of shells. Due to this practice, the sediment of the pond, the underlying soil and the groundwater became contaminated with TNT. The area of the soil contamination adds to abut 2.000 m{sup 2}. The remediation concept includes three steps: 1. Excavation of the most highly contaminated soil with TNT-concentrations above 1000 mg/kg. 2. Reduction of the remaining contamination by a biological in situ treatment using organic and inorganic amendments and mechanical tillage. After about to years of treatment, remediation goals of 50 mg/kg are expected to be reached on most of the area. 3. Contaminations eventually remaining in deeper soil layers ...

2003-07-01

473

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment  

Science.gov (United States)

The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct ...

2001-08-31

474

A space crystal diffraction telescope for the energy range of nuclear transitions  

Energy Technology Data Exchange (ETDEWEB)

This paper contains literature from American Power Conference Air Toxics Being Measured Accurately, Controlled Effectively NO{sub x} and SO{sub 2} Emissions Reduced; Surface Condensers Improve Heat Rate; Usable Fuel from Municipal Solid Waste; Cofiring Technology Reduces Gas Turbine Emissions; Trainable, Rugged Microsensor Identifies of Gases; High-Tc Superconductors Fabricated; High-Temperature Superconducting Current Leads; Vitrification of Low-Level Radioactive and Mixed Wastes; Characterization, Demolition, and Disposal of Contaminated Structures; On-Line Plant Diagnostics and Management; Sulfide Ceramic Materials for Improved Batteries; Flywheel Provides Efficient Energy Storage; Battery Systems for Electric Vehicles; Polymer-Electrolyte Fuel Cells for Transportation; Solid-Oxide Fuel Cells for Transportation; Surface Acoustic Wave Sensor Monitors Emissions in Real-Time; Advance Alternative-Fueled Automotive ...

1995-04-01

475

Treatment of radioactive metallic waste by the electro-slag melting method  

Energy Technology Data Exchange (ETDEWEB)

The applicability of the electro-slag melting method for treating plutonium contaminated metallic waste was studied. A 100kg test furnace was built and simulated metallic waste was melted and solidified in this furnace. Waste volume was reduced to 1/25 with a decontamination factor of 25 and the slag and the copper mold are repeatedly usable. The process is expected to be employed in the project of PWTF (Plutonium contaminated Waste Treatment Facilities).

1983-01-01

476

Request for interim approval to operate 218-E-12B Trench 94 as a chemical waste landfill for disposal of polychlorinated biphenyl wastes in submarine reactor compartments.  

Science.gov (United States)

This request is submitted to seek interim approval to operate a chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) wastes. This request covers only the disposal of small quantities of solid PCB wastes contained in decommissioned su...

1990-01-01

477

Industrial waste and pollution in Mongolia  

Energy Technology Data Exchange (ETDEWEB)

This paper very briefly outlines hazardous waste management issues, including regulations, in Mongolia. Air, water, and soil pollutants are identified and placed in context with climatic, social, and economic circumstances. The primary need identified is technology for the collection and disposal of solid wastes. Municipal waste problems include rapid urbanization and lack of sanitary landfills. Industrial wastes of concern are identified from the mining and leather industries. 4 refs., 2 tabs.

1996-12-31

478

Finally authorized supplementary report to the review on waste disposal in the Copenhagen area 1988. [Denmark]. Endelig godkendt bilagsrapport til affaldsredegoerelse for hovedstadsregionen 1988; Bilagsrapport nr. 1  

Energy Technology Data Exchange (ETDEWEB)

A supplementary report to the plan for waste disposal in the Copenhagen area, Denmark. It presents a mapping of wastes and waste flow in invidual areas, a description of recycling methods and waste collection systems. In addition legislative demands and potentials are dealth with. (CLS).

1988-07-01

479

The use of quartz patch pipettes for low noise single channel recording.  

UK PubMed Central (United Kingdom)

Quartz has a dissipation factor of approximately 10(-4), which is an order of magnitude less than that of the best glasses previously used to fabricate patch pipettes; it's dielectric constant of 3.8...Full Text Available

1993-10-01

480

Structural Change Accompanying Crystallization in the Lithium Ion Conductive Li{sub 2}S-SiS{sub 2}-Li{sub 3}PO{sub 4} Oxysulfide Glasses  

Energy Technology Data Exchange (ETDEWEB)

The structural change of the (100-x)(0.6Li{sub 2}S{center_dot}0.4SiS{sub 2})centre dotxLi{sub 3}PO{sub 4} oxysulfide glassesduring crystallization was analyzed by means of solid-state nuclear magnetic resonance (NMR) and X-ray photoelectron spectroscopy (XPS). The unique tetrahedral units of SiO{sub n}S{sub 4-n} (n=1,2,3) and PO{sub n}S{sub 4-n} (n=1,2,3) present in the glass samples vanished and the SiS{sub 4}, PS{sub 4}, SiO{sub 4} units increased with proceeding of the crystallization process. Nonbridging sulfur and oxygen atoms decreased while bridging oxygens and S{sup 2-} increased with proceeding of the crystallization process. Large structural difference between the glass and the corresponding crystallized sample explained the high stability against crystallization found in the oxysulfide glass with the composition of X=5. (author)

1999-02-01

481

Structural Change Accompanying Crystallization in the Lithium Ion Conductive Li[sub 2]S-SiS[sub 2]-Li[sub 3]PO[sub 4] Oxysulfide Glasses  

Energy Technology Data Exchange (ETDEWEB)

The structural change of the (100-x)(0.6Li[sub 2]S[center dot]0.4SiS[sub 2])centre dotxLi[sub 3]PO[sub 4] oxysulfide glassesduring crystallization was analyzed by means of solid-state nuclear magnetic resonance (NMR) and X-ray photoelectron spectroscopy (XPS). The unique tetrahedral units of SiO[sub n]S[sub 4-n] (n=1,2,3) and PO[sub n]S[sub 4-n] (n=1,2,3) present in the glass samples vanished and the SiS[sub 4], PS[sub 4], SiO[sub 4] units increased with proceeding of the crystallization process. Nonbridging sulfur and oxygen atoms decreased while bridging oxygens and S[sup 2-] increased with proceeding of the crystallization process. Large structural difference between the glass and the corresponding crystallized sample explained the high stability against crystallization found in the oxysulfide glass with the composition of X=5. (author)

1999-02-01

482

Phytochrome Control of Another Phytochrome-mediated Process 1  

UK PubMed Central (United Kingdom)

The phytochrome-mediated attachment of root tips of mung bean (Phaseolus aureus) and barley (Hordeum vulgare) to glass is affected by the prior exposure of hydrated...Full Text Available

1972-04-01

483

Indoleacetic Acid and Abscisic Acid Antagonism  

UK PubMed Central (United Kingdom)

The phytochrome-mediated attachment of mung bean (Phaseolus vulgaris L., var. Oklahoma 612) root tips on glass is quickly affected by indoleactic acid and abscisic acid at concentrations...Full Text Available

1973-01-01

484

INVESTIGATION OF GLASS-METAL COMPOSITE ...  

Science.gov (United States)

... having high fluidity. The SC-51A alloy contains 4.5 to 5.5% silicon, 1 to 1.5% coppers .4 to .6% magnesium, o35% sine, .8% iron, .5% manganes*, ...

1957-09-01

485

Glass-cordierite-mullite ceramics of low dielectric constant; Tworzywa szklano-kordierytowo-mulitowe o malej przenikalnosci elektrycznej  

Energy Technology Data Exchange (ETDEWEB)

Glass-ceramic materials containing 0-60% glass, 0-40% cordierite and 0-40% mullite were developed with dielectric constant lower than of Al{sub 2}O{sub 3} (5.2-6.7). The following glasses were used: SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}, CaO-ZnO-B{sub 2}O{sub 3}, CaO-ZnO-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}, BaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2} and BaO-ZnO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}. The influence of the content of the particular components on the value of dielectric constant of the ceramics was investigated. (author). 9 refs, 3 tabs.

1997-12-31

486

Glass Transition Behaviors of Ethylene Glycol-Water Solutions Confined within Nano-Pores of Silica Gel  

Science.gov (United States)

Enthalpy relaxation properties of the ethylene glycol (EG) aqueous solutions confined within silica-gel void spaces of 1.1 nm in the average void thickness and 6, 12 and 52 nm in their average diameters were examined by an adiabatic calorimetry to understand the glass transition behavior of the solutions and the rearrangement processes of the molecules. The glass transition temperature Tg of EG was found to decrease with adding the water molecules which are mobile under the condition lacking in the full hydrogen-bond network. Meanwhile, the Tg in the water-rich region showed a rise towards pure water; after a phase separation in a 25 mol% (x = 0.25) EG solution, the Tg was 160 K which was higher than that derived by extrapolating the composition dependence to pure water. The Tg = 160 K is the same as observed in the pure water confined within 1.1 nm voids; this indicates the validity of the interpretation that the glass ...

2008-02-01

487

Fiscal Year 1996 Career Program Awards (by state/university)  

Science.gov (United States)

... of Viscous Liquids, Glasses, and Crystalline Materials Under Extremes of Pressure and Temperature ... Materials 9624724 ENG AZ U of Arizona Gervay Jacquelyn Synthesis of Novel Materials Utilizing Sialic ...

488

Evaluation of materials for use in coal preparation plants. Part 2  

Energy Technology Data Exchange (ETDEWEB)

In the second part of this paper the author concludes his examination of the application of thermoplastic materials and also considers alumina ceramics, cast basalt and glass, rubbers, resins and wear-resistant steels

1982-06-01

489

Comparison of Soil Surface Temperature Measurements by Means of Standard Soil Mercury Thermometers and a Barnes Prt-5 Infrared Thermometer.  

Science.gov (United States)

A short account is given of the difficulties encountered in temperature measurement of boundary layers and a comparison of two types of thermometers, an infrared radiometer and mercury in glass thermometer. (Author)

1972-01-01

490

Capture of genomic DNA on glass microscope slides  

UK PubMed Central (United Kingdom)

It is well known that DNA strands bind to silica surfaces in the presence of high concentrations of chaotropic salts. We developed simple methods to evaluate binding and recovery of DNA on flat...Full Text Available

2007-06-15

491

Bacterial Fouling in a Model Core System  

UK PubMed Central (United Kingdom)

We have used a sintered glass bead core to simulate the spaces and surfaces of reservoir rock in studies of the bacterial plugging phenomenon that affects waterflood oil recovery operations. The passage...Full Text Available

1985-03-01