International Nuclear Information System (INIS)

In this report, research and development results on the bituminization of radioactive wastes are closely reviewed, especially those regarding waste treatment technologies, waste solidifying procedures and the characteristics of asphalt and solidified forms. A new concept of the bituminization method is suggested in this report which can improve the characteristics of solidified forms. Stable solid forms with high leach resistance, high thermal resistance and good compression strength were produced by the suggested bituminization method, in which spent polyethylene from agricultural farms was added. This report can help further research and development of improved bituminized forms of radioactive wastes that will maintain long term stabilities in disposal sites. (author). 59 refs., 19 tabs., 18 figs

International Nuclear Information System (INIS)

The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container.

Energy Technology Data Exchange (ETDEWEB)

Acid Rock Drainage (ARD) is the product formed by the atmospheric oxidation of the relatively common pyrite and pyrrhotite. Waste rock dumps and tailings containing sulfide mineral have been reported at toxic materials producing ARD. Mining in sulphide bearing rock is one of activity which may lead to generation and release of ARD. ARD has had some major detrimental affects on mining areas. The purpose of this study was carried out to develop disposal method for preventing contamination of water and soil environment by waste rocks dump and tailings, which could discharge the acid drainage with high level of metals. Scope of this study was as following: environmental impacts by mine wastes, geochemical characteristics such as metal speciation, acid potential and paste pH of mine wastes, interpretation of occurrence of ARD underneath tailings impoundment, analysis of slope ...

Energy Technology Data Exchange (ETDEWEB)

Thermoplastic encapsulation has been extensively studied at Brookhaven National Laboratory`s (BNL) Environmental and Waste Technology Center (EWTC) as a waste encapsulation technology applicable to a wide range of waste types including radioactive, hazardous and mixed wastes. Encapsulation involves processing thermoplastic and waste materials into a waste form product by heating and mixing both materials into a homogeneous molten mixture. Cooling of the melt results in a solid monolithic waste form in which contaminants have been completely surrounded by a polymer matrix. Heating and mixing requirements for successful waste encapsulation can be met using proven technologies available in various types of commercial equipment. Processing techniques for thermoplastic materials, such ...

Energy Technology Data Exchange (ETDEWEB)

In a scenario of aqueous transport from a high-level radioactive waste repository, the concentration of radionuclides in water in contact with the waste constitutes the source term for transport models, and as such represents a fundamental component of all performance assessment models. Many laboratory experiments have been done to characterize release rates and understand processes influencing radionuclide release rates from irradiated nuclear fuel. Natural analogues of these waste forms have been studied to obtain information regarding the long-term stability of potential waste forms in complex natural systems. This information from diverse sources must be brought together to develop and defend methods used to define source terms for performance assessment models. In this manuscript examples of measures of radionuclide release rates from ...

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The Nuclear Regulatory Commission stipulates in 10 CFR 61 that disposed low-level radioactive waste (LLW) be stabilized. To provide guidance to disposal vendors and nuclear station waste generators for implementing those requirements, the NRC developed the Technical Position on Waste Form, Revision 1. That document details a specified set of recommended testing procedures and criteria, including several tests for determining the biodegradation properties of waste forms. Information has been presented by a number of researchers, which indicated that those tests may be inappropriate for examining microbial degradation of cement-solidified LLW. Cement has been widely used to solidify LLW; however, the resulting waste forms are sometimes susceptible to failure due to the actions of ...

Energy Technology Data Exchange (ETDEWEB)

This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU waste treatment technologies.

Energy Technology Data Exchange (ETDEWEB)

Clay-based materials can be cold-stabilized using binder and formed by extrusion. This paper deals with the properties of such materials under the influence of silico-aluminous flying ashes addition. Flying ashes are solid industrial wastes produced by coal combustion. Characteristics of ashes bearing clay-based products, such as dimensional stability, water and mechanical resistance, accelerated aging, are considerably improved with respect to simple clay-binder mixtures. This is principally due to a better hydration of the binder in ashes-bearing mixtures because of: a higher free-water availability as a consequence of the smaller specific surface of ash grains, the filler effect of ash grains which do not participate to the reactions, the specific property of silico-aluminous ashes that can fix the lime in presence of water to produce hydrated compounds. These ashes-bearing clay based materials can ...

Energy Technology Data Exchange (ETDEWEB)

Published in summary form only.

Energy Technology Data Exchange (ETDEWEB)

This study examines the effects of blasting on waste dumps at open pit mining operations. Of specific concern were mining operations at the base of a five hundred foot high waste dump such as the operation at the South Pit of the Smoky-River Coal Ltd. property near Grande Cache, Alberta. An assessment of waste dump stability including factors such as quasi-static deformation behaviour, historical dump deformation behaviours and potential blasting effects was undertaken. It is concluded that safe blasting may be carried out in proximity to waste dumps, but monitoring of dump behaviour is recommended to ensure operational safety. 22 refs., 4 apps.

Energy Technology Data Exchange (ETDEWEB)

A a result of its former role as a producer of nuclear weapons components, the Rocky Flats Environmental Technology Site (RFETS), Golden, Colorado accumulated a variety of plutonium-contaminated materials. When the level of contamination exceeded a predetermined level (the economic discard limit), the materials were classified as residues rather than waste and were stored for later recovery of the plutonium. Although large quantities of residues were processed, others, primarily those more difficult to process, remain in storage at the site. It is planned for the residues with lower concentrations of plutonium to be disposed of as wastes at an appropriate disposal facility, probably the Waste Isolation Pilot Plant (WIPP). Because the plutonium concentration is too high or because the physical or chemical form would be difficult to get into a form acceptable to WIPP, it may not be ...

Energy Technology Data Exchange (ETDEWEB)

The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970`s, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and ...

Energy Technology Data Exchange (ETDEWEB)

Conversion of Idaho National Engineering and Environmental Laboratory radioactive sodium-bearing waste into a single solid waste form by evaporation was demonstrated in both flask-scale and pilot-scale agitated thin film evaporator tests. A sodium-bearing waste simulant was adjusted to represent an evaporator feed in which the acid from the distillate is concentrated, neutralized, and recycled back through the evaporator. The advantage to this flowsheet is that a single remote-handled transuranic waste form is produced in the evaporator bottoms without the generation of any low-level mixed secondary waste. However, use of a recycle flowsheet in sodium-bearing waste evaporation results in a 50% increase in remote-handled transuranic volume in comparison to a non-recycle flowsheet.

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Two criteria, geologic stability and barrier effectiveness, form the basis of the Subseabed Disposal Program's site qualification plan to evaluate the ocean basins and identify those regions having characteristics most favorable for containment of radioactive waste. Stability criteria are used to define those regions least likely to be disturbed by tectonic forces or oceanographic changes during the lifetime of a waste repository. Barrier criteria define those lithologies most likely to form an effective barrier to the release of radionuclides. Two north Pacific regions and three north Atlantic regions (PAC I and II and ATL I, II, and III, respectively) have thus far been selected for further investigation based on the site qualification plan. The PAC I region, centered on the Shatsky Rise in the northwest Pacific, has been subdivided into areas and ...

Energy Technology Data Exchange (ETDEWEB)

This report describes initial work on the development of solidification systems for sodium nitrate waste and compacted waste. Sodium nitrate waste has been solidified in three types of materials: polyethylene, polyester-styrene (PES), and latex cement. Evaluations of the properties of the waste form, such as the ANS 16.1 leaching test, water immersion test and compressive strength measurements were performed on the waste forms containing various amounts of sodium nitrate. 9 refs., 9 figs., 7 tabs.

British Library Electronic Table of Contents (United Kingdom)

The effect of the degree of degradation of the components of a model municipal plastic waste (a mixture of low-density polyethylene, high-density polyethylene, polypropylene and high-impact polystyrene) on the toughness and stability of recyclates compatibilised with a cooperative compatibilisation system (a mixture of ethylene-propylene statistical and styrene-butadiene block copolymers with a secondary amine-based stabiliser) was studied. It was shown that good impact strength was achieved for recyclates having components with a low or medium degree of degradation. Mechanical properties of recyclates having the components with a high degree of degradation are deteriorated. The addition of the cooperative compatibilisation system leads to a higher thermo-oxidative stability of recyclates ...

Energy Technology Data Exchange (ETDEWEB)

The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final ...

Energy Technology Data Exchange (ETDEWEB)

Sodium nitrate waste has been successfully solidified in two types of polymeric materials: polyethylene, a thermoplastic material, and polyester styrene (PES), a thermosetting material. Waste form property evaluation tests such as ANS 16.1 leaching test and compressive strength measurements were performed on the waste forms containing various amounts of sodium nitrate. A single-screw extruder was employed for incorporating dry waste into polyethylene at its melt temperature of 120/sup 0/C to produce a homogenous mixture. Results of the leaching test for polyethylene waste forms containing 30, 50, 60 and 70 wt% sodium nitrate are presented as cumulative fraction leached and leaching indices ranging from 11 to 7.8. Two PES systems are discussed. The first is for solidification of dry salt wastes and ...

Energy Technology Data Exchange (ETDEWEB)

This report will be revised upon completion of current testing investigating the radiolytic stability of additional energetic materials and the analysis of tank farm samples for volatile and semi-volatile organic compounds.

Energy Technology Data Exchange (ETDEWEB)

The follow-up system for wastes (JAeSTI), developed at the end of the 1990s, forms a basis for today's followup activities in Finland. JAeSTI relies on an environmental protection database, the compliance monitoring system VAHTI operated by the environmental authorities. Waste followup and waste statistics depend very much on the annual waste quantities recorded in the VAHTI system. In the KYJ-project the coverage and reliability of the data in the VAHTI system was evaluated as for the streams of solid municipal waste. The project also included the compiling of national statistics on municipal waste for the year 2000. The project used other information sources, too, such as statistics compiled when the National Waste Plan and regional waste plans were revised in 2002. In addition, the extent ...

Energy Technology Data Exchange (ETDEWEB)

A review of the various solidification agents and techniques that are currently available or potentially applicable for the solidification of low-level radioactive wastes is presented. An overview of the types and quantities of low-level wastes produced is presented. Descriptions of waste form matrix materials, the wastes types for which they have been or may be applied and available information concerning relevant waste form properties and characteristics follow. Also included are descriptions of the processing techniques themselves with an emphasis on those operating parameters which impact upon waste form properties. The solidification agents considered in this survey include: hydraulic cements, thermoplastic materials, thermosetting polymers, glasses, synthetic minerals and composite materials. ...

International Nuclear Information System (INIS)

In this program, contemporary solidification agents are being investigated relative to their applications to major fuel cycle and non-fuel cycle low-level waste (LLW) streams. Work is being conducted to determine the range of conditions under which these solidification agents can be applied to specific LLW streams. These studies are directed primarily towards defining operating parameters for both improved solidification of problem wastes and solidification of new LLW streams generated from advanced volume reduction technologies. Work is being conducted to measure relevant waste form properties. These data will be compiled and evaluated to demonstrate compliance with waste form performance and shallow land burial acceptance criteria and transportation requirements (both as they exist and as they are modified with time). 6 tables.

Energy Technology Data Exchange (ETDEWEB)

In October 1992, the US Department of Energy, Richland Field Office (RL) requested that Westinghouse Hanford Company (WHC) respond to a letter from EM-331 asking for completion of a survey of items in storage but not categorized as waste (Roberts 1992). The letter contained an attachment with instructions on how to fill out the attached form and what to exclude from the survey (Appendix A). This report is a summary of the information from the response issued to RL. This report primarily is for use in estimating future waste volumes that may have been overlooked because of the nature of their classification as material not categorized as waste (MNCAW) (i.e., not yet declared Waste).

Energy Technology Data Exchange (ETDEWEB)

This engineering report compiles information on types and quantities of liquid waste discharged from B-Plant directly to cribs, ditches, reverse wells, etc., that are associated with B-Plant. Waste discharges to these cribs via overflow form 241-B, 241-BX, and 241-BY tank farms, and waste discharged to these cribs from sources other than B-Plant are discussed.Discharges from B-Plant to other cribs, unplanned releases, or waste remaining in tanks are not included in the report. Waste stream composition information is used to predict quantities of individual chemicals sent to cribs. This provides an accurate mass balance of waste streams from B-Plant to these cribs. These predictions are compared with known crib inventories as a verification of the process.

Energy Technology Data Exchange (ETDEWEB)

The Transuranic Waste Form Characterization and Data Base (Volume 1) provides a wide range of information from which a comprehensive data base can be established and from which standards and criteria can be developed for the present NRC waste management program. Supplementary information on each of the areas discussed in Volume 1 is presented in Appendices A through K (Volumes 2 and 3). The structure of the study (Volume 1) is outlined and appendices of Volumes 2 and 3 correlate with each main section of the report. The Executive Summary reviews the sources, quantities, characteristics and treatment of transuranic wastes in the United States. Due to the variety of potential treatment processes for transuranic wastes, the end products for long-term storage may have corresponding variations in quantities and characteristics.

International Nuclear Information System (INIS)

In the radiochemical reprocessing of spent fuel from nuclear reactors, a considerable amount of liquid, solid, and gaseous waste is formed; this waste is potentially dangerous to humans and requires the development of special and complex technological techniques for its localization and reliable long-term storage. The most hazardous are liquid wastes of high specific activity - water-tailings solutions obtained in the first cycle of extraction after the removal of uranium and plutonium. These solutions contain more than 99.9% of all the other transuranic elements - isotopes of neptunium, americium, and curium. Where necessary, some fission products and actinides may be removed from wastes of high specific activity for subsequent use. The quantity, composition, and activity of these wastes varies within broad limits, depending on the type and power of the ...

Energy Technology Data Exchange (ETDEWEB)

Two of the US Department of Energy's (DOE) nuclear waste management-related goals are to ensure that waste management is not an obstacle to the further development of light-water reactors and the closure of the nuclear fuel cycle and to fulfill its institutional responsibility for providing safe storage and disposal of existing and future nuclear wastes. As part of its approach to achieving these goals, the Office of Remedial Action and Waste Technology of DOE established what is now called the Nuclear Waste Treatment Program (NWTP) at the Pacific Northwest Laboratory during the second half of FY 1982. To support DOE's attainment of its goals, the NWTP is to provide technology necessary for the design and operation of nuclear waste treatment facilities by commercial enterprises as part of a licensed waste management system ...

Energy Technology Data Exchange (ETDEWEB)

WIPP, intended for underground permanent disposal of defense transuranic waste, is located 40 km east of Carlsbad at a depth of 655 m in the salt beds of the 600-m thick Permian Salado Formation. It will consist of 56 ``rooms`` each 91.5 m long, 10 m wide, and 4 m high, grouped in 8 ``panels`` of 7 rooms each. About 7.5 km of access drifts will also be provided. Excavation began in 1982 and surface/access/test facilities and one panel were completed by 1988, many years before it could be used. Current plans are to start emplacing waste in WIPP in 1998 and continue for 35 years. The north- south drift E140 is the widest (25 ft) of the four main north-south drifts and is the main north-south passage. Plans to conduct experiments with waste in 1993 were abandoned, and the plan now is to use panel 1 for permanent disposal of waste starting in 1998. The stability evaluation resulted in ...

Energy Technology Data Exchange (ETDEWEB)

The complex formation of zirconium with biphenyl mono- and biscatecholyazo derivatives has been studied spectrophotometrically. The composition of the complexes, form and charge of complex-forming zirconium ions have been established. A procedure is suggested for calculation of molar absorptivities and stability constants for each of the complexes formed simultaneously in the system. Possible complex formation schemes have been studied. The data obtained were used to develop a spectrophotometric method of determining zirconium in the presence of large amounts of copper.

Science.gov (United States)

A pyrochemical partitioning process has been conceptually designed so that the transmutation of spent LWR fuels in PEACER can produce mainly low-level waste (Class C waste) for near-surface burial. Chloride salt technology developed for IFR has been employed as the baseline. Electrorefining, reductive extraction and salt recycling steps are used to construct overall flowsheet in order to support PEACER operation. The decontamination factor for transuranic elements was estimated based on both thermodynamic models and reported experimental data. It is expected that overall decontamination factor can be as high as 10{sup 5} for transuranic elements. Final wastes from pyrochemical processing for PEACER are noble metals, alkaline earth metal, and lanthanides. The final wastes are stabilized by mixing with zeolite and glass-frits such that concentration limit for class C ...

International Nuclear Information System (INIS)

The formation of astatide-mercury complexes was investigated in aqueous solutions.The obtained complexes were examined by paper electrophoresis. It was found that Hg(OH)At and Hg(OH)I complexes were formed in neutral solution. The stability constants of the obtained complexes were determined by ion-exchange. The preliminary results indicate that the complex of mercury with astatide is much more stable than similar complexes with iodide. (author)

Energy Technology Data Exchange (ETDEWEB)

According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing ...

International Nuclear Information System (INIS)

This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10"-"3 to 7.3 x 10"-"1 and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure ...

International Nuclear Information System (INIS)

In the geological disposal facility of the high-level radioactive waste, a group of galleries is designed in parallel at the depth of more than 300 m below surface. This is an unprecedented structure in the field of conventional engineering, and it is necessary to take this characteristic into consideration in the design of the galleries. In the geological disposal facility, as well as ensuring the dynamic stability of the gallery during construction and operational periods, it is necessary to evaluate the EDZ adequately for long-term stability after the closure. In this study, analysis of the 'multi tunnels model' which represents the whole gallery group was performed and the results about the outbreak behavior of EDZ were summarized. (author)

Energy Technology Data Exchange (ETDEWEB)

The specific objectives of the work were defined by the Environmental Evaluation Group (EEG) as follows: (1) assess the stability of panel 1 during the proposed operation of waste emplacement; (2) estimate the amount of time before room closure would be expected to transfer rock loads to the waste packages. The work consisted of (1) an analysis of geotechnical data and a review of the Department of Energy`s (DOE) plans for waste emplacement in panel 1, (2) an evaluation of ground conditions based on data analysis and observations of changes in ground conditions since the first evaluation in 1993 (USBM 1993), and (3) preparation of a report and presentation of the results to EEG staff. Excluded from this study are radiological safety issues and policies. The study is based on data provided by DOE and Westinghouse Electric Corporation (operator of the site) and conversations with DOE and Westinghouse ...

Energy Technology Data Exchange (ETDEWEB)

The aims of the present work were to investigate possible compatibility between sodium zirconium phosphate (NZP) and Synroc titanate phases, to prepare NZP-based waste forms by hot-pressing rather than sintering, and to investigate the incorporation in NZP of (a) Cs/Sr as simulated heat-generating nuclides; (b) simulated actinides; and (c) simulated Purex waste. The NZP samples were prepared by methods similar to those used for Synroc. The precursor NZP phase was formed from tetrabutyl zirconate Zr(OC{sub 4}H{sub 9}){sub 4}, sodium nitrate, and 85% orthophosphoric acid. Simulated waste nitrate solutions were then mixed with the liquid precursor. After stir drying of the precursor, calcination was carried out at 700{degree}C to remove nitrates and organics.

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This report addresses remote monitoring of coal waste impoundments for stability. Existing automated geotechnical monitoring systems are described and reviewed along with details of instruments suitable for such systems. An impoundment in West Virginia, which was in the construction stage, was instrumented and monitored between July 1979 and May 1981. Sensors that measure surface and subsurface parameters including settlement, horizontal deflection, surface tilt, pore water pressure, seepage, pond level, and meteorlogical parameters were installed. Recommendations for improving and expanding the capabilities of the monitoring system are given.

Energy Technology Data Exchange (ETDEWEB)

The University of Maryland at Baltimore was awarded a grant from the Department of Energy to test a specially modified incinerator to burn biomedical radioactive waste. In preparation for the incinerator, the Radiation Safety Office devised a comprehensive plan for its safe and effective use. The incinerator plan includes a discussion of regulations regarding on-site incineration of radioactive waste, plans for optimum use in burning four principal waste forms, controlled air incineration technology, and standard health physics safety practices; a use plan, including waste categorization and segregation, processing, and ash disposition; safety procedures, including personnel and area monitoring; and methods to evaluate the incinerator's effectiveness by estimating its volume reduction factors, mass and activity balances, and by determining the cost effectiveness of ...

International Nuclear Information System (INIS)

In the early 1980s, AECL built a Waste Treatment Centre (WTC) for managing low-level solid and aqueous liquid wastes for converting CANDU wastes. At present, two liquid waste streams are being treated at the WTC. The liquid waste streams are volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis (TRO) membrane technologies. The concentrate produced from the TRO system and the volume-reduced MF backwash solutions are evaporated while simultaneously adding bitumen in a thin-film evaporator. A water-free product of chemical and radiochemical salts and bitumen is removed in 200-L galvanized steel drums for storage. The radiation field of product drums on contact typically has a value of 0.5 to 3 R/h depending upon the feed concentration of radioactivity to the evaporator. The total solids content in ...

Energy Technology Data Exchange (ETDEWEB)

The present invention relates to a method of recycling polymeric waste products into monomers and high value forms of carbon by pyrolytic conversion using an induction coupled RF plasma heated reactor.

Energy Technology Data Exchange (ETDEWEB)

Reverse osmosis is a simple process and has relatively high decontamination factor compared to other processes used for the treatment of radioactive liquid waste. Furthermore the quantity of secondary waste of this process is small. In this study, test solution containing nine elements such as cesium, strontium, cobalt etc. in chloride forms are treated by reverse osmosis. Permeate rate decreases as the increase of osmotic pressure of feed solution and is expressed by linear equation. Decontamination factor of cations of univalency is more than ten, and about one tenth of that of bivalency. Decontamination factors of all the elements used in this experiment are approximately estimated using the solution-diffusion model.

Energy Technology Data Exchange (ETDEWEB)

A database has been developed to contain the disposal limits for the E-Area Low Level Waste Facility (ELLWF). This database originates in the form of an EXCEL{copyright} workbook. The pertinent sheets are translated to PDF format using Adobe ACROBAT{copyright}. The PDF version of the database is accessible from the Solid Waste Division web page on SHRINE. In addition to containing the various disposal unit limits, the database also contains hyperlinks to the original references for all limits. It is anticipated that database will be revised each time there is an addition, deletion or revision of any of the ELLWF radionuclide disposal limits.

International Nuclear Information System (INIS)

The formation constants of species formed in the system H"+"+alanine and VO_"2"+alanine have be determined in aqueous solution for 1.0formed complexes and their stability constants were determined ny curve fitting method and it was shown that di oxovanadium(V) forms two mononuclear 1:1 and 1:2 species with alanine of the type VO_2L and VO_2L_2 The protonation constant of the amino group of alanine has been determined using a computer program which employ a least-squares method. The defence of the protonation of alanine and the stability constant of the species on ionic strength are described by a Debby-huckel type equation.

CERN Document Server

Radioactive Waste

Energy Technology Data Exchange (ETDEWEB)

Long-term disposal and management of low and intermediate-level radioactive waste is a major project of the nuclear power industry. Therefore, the selection of an underground waste repository has to be a geologically and seismologically stable storage. Easy transportation and emplacement is essential. The Wolsung nuclear power plant (NPP) of unit no. 1/2/ 3/ 4, which is responsible for the future of the energy industry, has already been constructed at the Wolsung site and a New NPP has recently been created at the Sinwolsung site. Radioactive waste used in the plant facilities, has piled up increasingly every year, but it should be taken to be managed at long-term underground storage disposal facilities. The Wolsung site for radioactivity waste repository was known to be relatively stable through various geological surveys, earthquakes, groundwater, engineering testing and analysis, but still more ...

International Nuclear Information System (INIS)

The Mixed Waste Management Facility, or MWMF, has been proposed as a national testbed facility for the demonstration and evaluation of technologies that are alternatives to incineration for the treatment of mixed low-level waste. The facility design will enable evaluation of technologies at pilot scale, including all aspects of the processes, from receiving and feed preparation to the preparation of final forms for disposal. The MWMF will reduce the risk of deploying such technologies by addressing the following: (1) Engineering development and scale-up. (2) Process integration and activation of the treatment systems. (3) Permitting and stakeholder issues. In light of the severe financial constraints imposed on the DOE and federal programs, DOE/HQ requested a study to assess the cost benefit for the MWMF given other potential alternatives to meet waste treatment needs. The MVVMF Project was asked to ...

Energy Technology Data Exchange (ETDEWEB)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the ...

International Nuclear Information System (INIS)

To dispose the radioactive waste drums, the waste form's integrity and the nuclides inventories must be assured according to the national and site waste acceptance criteria. Because they might be would gravely affected the performance objectives of disposal site. Our national regulation for the waste inventory related to 'Radioactive Waste Acceptance Criteria' requires that the activities of 13 nuclides and gross #alpha# must be measured and the 95 % of nuclides incorporated in the drum must be identified. It is very difficult to measure the radioactivity with accuracy from the regulated waste drum(200L), and have a large error in the analysis results. In present, there are two system, SGS (Segmented Gamma Scanning System) and TGS (Tomographic Gamma Scanning System) for the analysis of radionuclides from the waste drums. ...

Energy Technology Data Exchange (ETDEWEB)

A thin film microoxidation test utilizing the concept of the Lubricant Stability Map has been used to study the effect of temperature on deposit formation by lubricants on upper piston locations of low heat rejection engines. The stability maps were established for two formulated lubricants in this study. These two lubricants were also evaluated in a series of engine tests with various piston temperatures. The deposition phenomena observed in the engine tests have been adequately simulated and described by the stability maps. It is concluded that lubricants at upper piston locations are under a thin film condition similar to that achieved by the thin film microoxidation test. The deposit formation trend is determined by the volatility, thermal stability, and oxidative stability of the base stock. Additives have little effect on deposit formation at very high temperatures. A combined ...

Science.gov (United States)

The thermodynamics of protonation and europium(III) complex formation with substituted methane diphosphonic acids have been reported recently. These ligands form strong complexes with europium in moderately acidic solutions ((H{sup +}) {ge} 0.1 M), conditions not conducive to complexation by most carboxylate and aminopolycarboxylate ligands. A correlation of log {beta} vs pK{sub a} values for phosphonate and carboxylate ligands is used to explore the effect of ligand structure on complex stability. 5 refs., 1 fig.

Energy Technology Data Exchange (ETDEWEB)

In this paper we describe a modelling project to improve a nuclear waste management program in charge of the creation of a new system for the permanent disposal of nuclear waste. SADT (Structural Analysis and Design Technique) is used in order to provide a work-flow description of the functions to be performed by the waste management program. This description is then translated into a number of Coloured Petri Nets (CPN or CP-nets) corresponding to different program functions where additional behavioural inscriptions provide basis for simulation. Each of these CP-nets is simulated to produce timed event charts that are useful for understanding the behaviour of the program functions under different scenarios. Then all the CPN models are linked together to form a single stand-alone application that is useful for validating the interaction and cooperation between the different program functions. A technique ...

Energy Technology Data Exchange (ETDEWEB)

The incorporation of (a) Cs/Sr as simulated heat-generating isotopes contained in Purex reprocessing waste, (b) simulated actinides, and (c) simulated Purex waste in sodium zirconium phosphate (NZP) has been studied. The samples were prepared by sintering, by hot pressing and by hot isostatic pressing in metal bellows containers. The short-term chemical durability of the phosphate-based material containing Purex waste was within an order of magnitude of that for Synroc-C, as measured by 7-day MCC-1 tests at 90{degrees}C. The dissolution behavior showed evidence of re-precipitation phenomena, even after times as short as 28 days. Potential for improvement of NZP-based ceramics for HLW management is discussed. 19 refs., 4 figs., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. The glass will be produced and poured into stainless steel canisters in the Defense Waste Processing Facility (DWPF). Eventually these canistered waste forms will be sent to a geologic repository for final disposal. In order to assure acceptability by the repository, the Department of Energy has defined requirements which DWPF canistered waste forms must meet. These requirements are the Waste Acceptance Preliminary Specifications (WAPS). The WAPS require DWPF to identify the crystalline phases expected to be present in the final glass product. Knowledge of the thermal history of the borosilicate glass during filling and cooldown of the canister is necessary to determine the amount and type of crystalline phases present ...

Energy Technology Data Exchange (ETDEWEB)

Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank`s structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the ...

International Nuclear Information System (INIS)

The possibility of having properly designed multinational fuel cycle agreements which would contribute to public acceptance of nuclear energy are explored. The advantages of existing international cooperation in the field of uranium enrichment and nuclear waste disposal and reprocessing are discussed. The possible forms of multinational co-operation under an international organisation, committed the non-proliferation and operating under international law and covering storage facilities, security of raw materials and the nuclear fuel cycle are summarised in model form. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

Cementitious materials provide an ideal geochemical environment (e.g., high pH pore fluids and large surface areas for sorption) for immobilizing nuclear waste. The inclusion of reducing agents, such as blast furnace slag (BFS) can immobilize radionuclides by forming of solid sulfide phases. Thermodynamic calculations using the MINTEQ geochemical computer code indicate the elemental sulfur present in BPS reacts with the highly mobile pertechnetate anion (TcO{sub 4}{sup -}) anion to form an insoluble technetium sulfide phase (Tc{sub 2}S{sub 7(s)}). Initially, the waste form very effectively immobilizes technetium. However, as oxygen diffuses into the waste form, an outer zone of oxidized concrete and a shrinking core of reduced intact concrete develops. Oxidation of sulfur in the outer zone results in increased technetium concentrations in ...

Energy Technology Data Exchange (ETDEWEB)

The Ministere des Ressources naturelles du Quebec (Quebec Natural Resources Department) implemented a remedial program to treat the waste rock pile at Wood Cadillac, located near Cadillac, in Abitibi, Quebec. The solutions proposed by INRS-Georessources and ENVIROCONSEIL are aimed at eliminating erosion and stabilizing the geochemical processes. Part of the proposed solution also included the use of a reducing trickling filter for the treatment of acid leachates, which also contain arsenic when exiting the waste rock pile. The trickling filter is composed of forest tailings in which the bacteria reduce the sulphates and stimulate the precipitation of arsenic into arsenic sulphates. This is a new treatment that was developed following laboratory experiments which demonstrated the feasibility of the process and quantified the parameters. A demonstration unit was constructed by ENVIROCONSEIL and installed at the Wood Cadillac ...

Energy Technology Data Exchange (ETDEWEB)

Over the past 25 years there have been a large number of long runout flowslides from Rocky Mountain coal mine waste dumps. The waste dumps are constructed as end-dumped fills with an angle of repose of 38{degrees}. Dump heights range between 100 and 400 m. The dumps are normally founded on mountain slopes that are covered with a thin veneer of granular colluvial and dense stony fill materials. Conventional stability analyses carried out for these dumps using friction angles equal to the angle of repose for the waste rock and typical values ranging from 30 to 32{degree} for the foundation materials indicate that many should be stable. The flowslides occur rapidly and display surprisingly long runouts of up to 2 km in some cases. Detailed studies of three of these events indicate that static collapse of saturated or nearly saturated sandy gravel layers within the dumps may be responsible for the initial ...

Energy Technology Data Exchange (ETDEWEB)

Radioactive waste has been stored in large underground storage tanks at the Hanford Site since 1944. Approximately 212 million liters of waste containing approximately 240,000 metric tons of processed chemicals and 177 mega-curies of radionuclides are now stored in 177 tanks. These caustic wastes are in the form of liquids, slurries, saltcakes, and sludge. In 1991, the Tank Waste Remediation System (TWRS) Program was established to manage, retrieve, treat, immobilize, and dispose of these wastes in a safe, environmentally sound, and cost-effective manner. The Department of Energy (DOE) has believes that it is feasible to privatize portions of the TWRS Program. Under the privatization strategy embodied in the Request for Proposal (RFP), DOE will purchase services from a contractor-owned, contractor-operated facility under a fixed-price contract. Phase I of the ...

Energy Technology Data Exchange (ETDEWEB)

The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had virtually zero impact on both foaming and the dissolution of silica ...

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass ...

Energy Technology Data Exchange (ETDEWEB)

For the purpose of solving the limitations such as shape and dimension for magnetic compact fabricated by conventional anisotropic forming under magnetic orienting field, the feasibility of a new magnetic forming process was studied. Ferrite powder mixed with UV resin was compacted in the die mold and followed by alignment under the magnetic field. Effects of viscosity of UV resin and forming condition on magnetic characteristics of the compact was investigated. Maximum degree of alignment for the ferrite powder reached to 0.826. It was predicted that the proposed method had make it possible to fabricate a high performance magnet having the anisotropic alignment of the magnetic powder. The UV resin is desirable to have low viscosity, good properties such as formability and configuration stability for the compact and also parting- ability between the metal mold and the compact. (author)

Energy Technology Data Exchange (ETDEWEB)

Surveillance and maintenance (S M) of 75 sites were conductd by the Remedial Action Section for the Environmental Restoration Program for surplus facilities and sites contaminated with radioactive materials and/or hazardous chemicals. S M activities on these sites were conducted from the end of their operating life until final facility disposal or site stabilization. The objectives of the Waste Area Grouping S M Program are met by maintaining a program of routine S M as well as by implementing interim corrective maintenance when deemed necessary as a result of site surveillance. This report briefly presents this program's activities and includes tables indicating tank levels and dry well data for FY 1991.

International Nuclear Information System (INIS)

The formation and stability constants of the [sup(99m)Tc]PM tetracycline have been investigated by the potentiometric method. The pK value of the complex formed was measured as pK = 5.49 +- 0.19. The spectrophotometric study has been performed on the formation of a complex of Sn(II) and TcO"4"- in the presence of PM Tetracycline. This study shows that Sn(II) forms with PMT a complex at a mole ratio of 1:1. The molar extinction coefficients of the Sn-PMT and [_9_9Tc]PMT complexes have been measured. (author).

International Nuclear Information System (INIS)

By treatment with beta or gamma rays, PTFE waste is converted to high-grade PTFE fine powder. High-molecular weight PTFE is degraded to low-molecular weight PTFE. Due to this the density, the degree of crystallinity, and the melt flow index are increased, which enhances the brittleness of the material. Irradiation of PTFE thus facilitates milling and makes the material pourable and free-flowing. Milled PTFE fine powder, lie PTFE plastic, combines temperature resistance, weather fastness, and chemical stability with good slip behaviour and antiadhesive properties. Areas of application for fine powder include additives for plastics, printing inks, nonstick coatings, and antifriction lacquers. (orig.).

Science.gov (United States)

Molecular dynamics simulations have been used to study the differences between two DNA and RNA 14-mer quadruplexes of analogous sequences. Their structures present a completely different fold: DNA forms a bimolecular quadruplex containing antiparallel strands and diagonal loops; RNA forms an intrastrand parallel quadruplex containing a G-tetrad and an hexad, which dimerizes by hexad stacking. We used a multiscale computational approach combining classical Molecular dynamics simulations and density functional theory calculations to elucidate the difference in stability of the 2-folds and their ability in coordinating cations. The presence of 2'-OH groups in the RNA promotes the formation of a large number of intramolecular hydrogen bonds that account for the difference in fold and stability of the two 14-mers. We observe that the adenines in the RNA quadruplex play a key role in conserving the geometry ...

Energy Technology Data Exchange (ETDEWEB)

The DOE`s clean-up of its nuclear complex require the development of innovative technologies to convert soils contaminated by hazardous and/or radioactive wastes to forms which can be readily disposed in accordance with current waste disposal methods. The unique features of Votec CMS technology should make it particularly cost-effective process for the vitrification of soils, sediments, sludges, and mill tailings containing organic metallic and/or radioactive contaminants. This article describes the technology (Votec`s combustion and melting system), the results of testing, the demonstration plant system, and summarizes the future schedule and the equipment needed. 3 figs., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

Long-Range Alpha Detector (LRAD) systems are designed to monitor alpha contamination by measuring the number of ions in the air. Alpha particles are a form of ionizing radiation and a typical 5-MeV alpha particle will create about 150,000 ion pairs in air. Field tests at various DOE sites have shown that LRAD Surface Soil Monitors (SSM), Sample Monitors, and Object Monitors are faster and more sensitive than traditional alpha detectors for measuring alpha contamination. This paper discusses the various applications of LRAD technology to low-level radioactive waste management.

International Nuclear Information System (INIS)

The structure of the layers formed on a silver electrode by the adsorption of pyridine, Cl"-, CN"- and SO_4"2"- is discussed. A comparison of the amount of the species adsorbed with their Raman spectra shows that there is no simple relation between the species concentration and the enhancement of the Raman intensity. Furthermore, the inhomogeneity of the layers is shown by Raman microscopy observations. These results lead the authors to propose the formation of a new species stabilized in the colloidal silver layer. The Raman enhancement could be explained by the existence of a resonance effect. (Auth.).

Science.gov (United States)

This paper presents a numerical investigation of laminar flows and heat transfer in a horizontal rectangular channel whose top and bottom plates have been punched out in the form of a delta wing. The flow structure with respect to the generation, transport, and stability of vortices in laminar horizontal channel flows with combined forced and free convection are reported. To include free convection, Boussinesq approximation of the buoyancy is used and the flow medium is treated as incompressible.

Energy Technology Data Exchange (ETDEWEB)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the ...

International Nuclear Information System (INIS)

The Quality Assurance Requirements and Description (QARD) is the principal quality assurance document for the Civilian Radioactive Waste Management Program (Program). It establishes the minimum requirements for the Quality Assurance Program. The QARD contains regulatory requirements and program commitments necessary for the development of an effective quality assurance program. Quality assurance implementing documents must be based on, and consistent with, QARD requirements. The QARD applies to the following: (1) acceptance of spent nuclear fuel and high-level radioactive waste; (2) transport of spent nuclear fuel and high-level radioactive waste; (3) the Monitored Retrievable Storage (MRS) facility through application for an operating license; (4) Mined Geologic Disposal System (MGDS), including the site characterization activities (exploratory studies facility (ESF) and surface based testing), through application for an ...

Energy Technology Data Exchange (ETDEWEB)

The ultimate goal of this research was to develop technology to convert recycled wood fiber and plastics into durable products that are recyclable and otherwise environmentally friendly. Two processing technologies were used to prepare wood-plastic composites: air-laying and melt-blending. Research was conducted in (1) developing laboratory methods for converting waste wood, wastepaper, and waste plastics into forms suitable for processing into composites; (2) optimizing laboratory methods for making composite panels from the waste materials; (3) establishing a database on the effects of formulation and bonding agent on physical and mechanical properties of composites; (4) establishing the extent to which the composites can be recycled without unacceptable loss in properties; and (5) reaching out to industry to provide education, to develop applications, and to extend the database. Overall, the program ...

International Nuclear Information System (INIS)

An Effect of pinhole(perforation or pit penetration) that might be formed outside the package on the nuclide leaching from paraffin waste form was investigated. In case of single pinhole, the leached mass and cumulative fraction leached (CFL) increased with the larger diameter of pinhole, but they were not in direct proportion to the size or area of pinhole. If the total area of multiple pinholes was fixed, the leached mass showed a tendency to increase as each size was smaller and the number was more. It was also found that the leached mass was not in direct proportion to the number of pinhole in case of constant size. In order to analyze the test results, the shrinking core model(SCM) was derived from the diffusion-controlled dissolution reaction and compared with previous diffusion model.

Energy Technology Data Exchange (ETDEWEB)

Commercial development of oil shale resources will produce vast quantities of processed shale waste. The presence of potentially toxic trace elements, inorganic salts, and potentially toxic residual organic constitutents make the disposal of vast quantities of processed shale a potential environmental problem. To be environmentally acceptable, processed shale disposal must: result in a physically stable structure, prevent or minimize release of potentially toxic compounds, and provide an economically acceptable post-land use. Water is the common element underlying all factors important to the environmental stability of disposed solid waste. The leaching and transport of solubles by water in processed shale embankments may result in degradation of local surface and groundwater quality. The major purpose of this research is to physically model, study, and describe the redistribution and movement of water and percolates in ...

International Nuclear Information System (INIS)

In this work passive films formed in AISI 304 stainless steel were envisaged as semiconductors and studied by means of photoelectrochemistry and Mott-Schottky plots. The passive films were potentiostatically formed at different potentials (0.2-0.8V) in a basic borate/boric acid solution without and with addition of NaCl (0.5 and 1g/l) and at various temperatures in the range 8-60"oC. The influence of these parameters on the photocurrent, quantum efficiency, bandgap energy and density of charge carriers was determined. The results show that the experimental conditions at which the films are formed influence the semiconductive properties of the film, which seem to be related to the higher or lower stability of the film. An Arrhenius type of relationship was also found between the density of charge carriers and temperature, leading to the determination of an activation energy. (author) 13 refs., 7 figs.

CERN Document Server

The Principles of Radioactive Waste Management

Science.gov (United States)

No abstract prepared.

British Library Electronic Table of Contents (United Kingdom)

Lithium phosphorous oxynitride(Lipon) thin films as a lithium ion conductive electrolyte were prepared by radio frequency reactive sputtering in N2 plasma. The properties of the amorphous Lipon solid electrolyte were investigated as a function of N2 pressure during reactive sputtering. The ionic conductivity and the electrochemical stability of Lipon thin films improved drastically as the N2 pressure decreased. The ionic conductivity closed to 10?6 S cm?1 and obtained a stability window of 1.0?5.0 V with an N2 pressure of 5 mTorr, where the number of nitrogen bonds between the phosphate groups were more than those formed at higher pressure. It was possible to fabricate the Li//LiCoO2 complete thin film battery using this Lipon solid electrolyte, which exhibited excellent discharge characte...

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Spectrophotometric methods were used to investigate the properties of neptunium(VII), (VI), and (V) in silicate solution. The transition of cationic neptunium(VII) to anionic species in non-complexing environments proceeds in the range of ?? 5.5 to 7.5. In the presence of carbonate, this transition occurs at ?? 10.0 to 11.5 and in silicate solutions at ?? 10.5-12.0. These findings show that cationic neptunium(VII) forms complexes with both carbonate and silicate and that the silicate complex is stronger than that of the carbonate. The competition of complex formation reactions for neptunium(VI) with carbonate and silicate and on the known complex stability constant of NpO2(CO3)34- allowed the NpO2SiO3 complex stability constant, log ? = 16.5, to be estimated. Determination of the formation constant of Np(V) complexes with SiO32- was not possible using similar methods.

International Nuclear Information System (INIS)

This paper discusses the storage of spent nuclear fuel by countries around the world. At the present time, all countries are storing it. A small number of countries are reprocessing it for recycling. Essentially all countries are preparing for eventual disposal of end waste form. There is much uncertainty and controversy over what should and will happen.

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows: Large-scale problems such as nuclear waste disposal are increasingly recognized to be interconnected to small scale-mechanisms. Thus, synchrotron-based high-resolution analytical X-ray probes become important tools for exploring the micro-scale chemical reactivity of heterogeneous barrier materials used in nuclear waste repositories. In this study the layout of the micro-XAS beamline at the Swiss Light Source (SLS) will be presented. The beamline is optimized towards micro beam experiments ({approx}1 x 1 {mu}m{sup 2}) in the hard-X-ray regime (4 - {approx}22 keV) and allows to combine micro X-ray fluorescence (micro-XRF), micro X-ray absorption spectroscopy (micro- XAS), and micro X-ray diffraction (micro-XRD) investigations with radioactive samples. Furthermore, the potential of micro-XRF/XAS/XRD for acquiring spatially resolved molecular level information on the speciation and structural coordination ...

International Nuclear Information System (INIS)

A nuclear fuel waste disposal vault would not likely be a sterile environment. Bacterial activity would be expected in those areas of the vault conducive to bacterial life, i.e., where effects of heat, moisture content, radiation and compaction would not prevent or severely restrict bacterial life and where suitable and sufficient nutrients would be present. An inventory of bacterial nutrients that would be emplaced 'intentionally' with vault materials (fuel waste, waste containers, buffer and backfill materials) has been made previously. This report assesses bacterial nutrients that would be added 'inadvertently' to a vault in the form of residues of materials used to excavate and operate a vault. Measurements of blasting material residues in the various water supplies, excavated broken rock (muck) and in cores drilled in old and new tunnel walls were made at AECL's Underground Research Laboratory. ...

Energy Technology Data Exchange (ETDEWEB)

Type 440C stainless steel is a high-C, high-Cr martensitic steel used in applications requiring high hardness and wear resistance in combination with moderate corrosion resistance. Typical applications include precision aerospace bearings and critical components in computer disk drives. The properties of passive films formed on 440C steel were investigated using advanced electrochemical techniques with a view to establishing a method to measure film stability directly in the passivation baths. Electrochemical measurements were sensitive to the passive film properties and were able to quantify the effect of cooling rate on passive film stability. The techniques used included linear polarization, AC impedance, small amplitude cyclic voltammetry, and coulostatic transient measurements. These provided results that exhibited excellent agreement with the AC impedance technique providing the most information about the interfacial ...

Science.gov (United States)

... of waste food generated at McMurdo Station. Some of the difficulties of disposing of waste food ... change waste generation or management at the site? Yes. This will be a temporary waste management ...

International Nuclear Information System (INIS)

The disposal of municipal solid waste in an environmentally sound manner is a major problem worldwide. The composting of the organic fraction of refuse transforms it into soil amendment that can be recycled on agricultural lands. In order to promote the use of compost among farmers, agronomic investigations have to evaluate the impact of its use on soil properties and plant growth. In a greenhouse experiment, a sample of locally produced compost was applied to a sandy clay soil at rates equivalent to 0, 25, 50, 100, and 200 t/ha with supplemental addition of NH_4 NO_3 at levels equivalent to 0, 25, 50 and 100 Kg N/ha. Barley (Hordium vulgare L.) and corn (Zea mays L. indentata) were grown as indicator crops and soil properties were determined over a period of 150 days. Plant growth was affected by N starvation until the compost was stabilized in the soil. Nitrogen starvation persisted for a longer period with increasing applications of compost. ...

Science.gov (United States)

Using low-temperature adsorbed dihydrogen and carbon monoxide as molecular probes, the dehydroxylation of the hydrogen forms of the zeolites Y, and ZSM-5 has been studied. The high stability of the high-silica zeolites to dealumination and their difference from faujasites has been established as being due not only to the strength of their Broensted acid sites but also to the nature of their Lewis acid sites. The chemical properties of the Lewis acid sites and their possible role in catalytic reactions are discussed.

British Library Electronic Table of Contents (United Kingdom)

In this work, effects of coolant chemistry, including concentrations of chloride ions and ethylene glycol and addition of various ions, on corrosion of 3003 Al alloy were investigated by electrochemical impedance spectroscopy measurements and scanning electron microscopy characterization. In chloride-free, ethylene glycol-water solution, a layer of Al-alcohol film is proposed to form on the electrode surface. With the increase of ethylene glycol concentration, more Al-alcohol film is formed, resulting in the increase in film resistance and charge-transfer resistance. In the presence of Cl- ions, they would be involved in the film formation, decreasing the stability of the film. In 50% ethylene glycol-water solution, the threshold value of Cl- concentration for pitting initiation is within ...

Science.gov (United States)

Summaries are included of research contracts which expired prior to Dec. 31, 1960. The contracts were concerned with investigations of: electrophysiological responses of biological systems in nerve cells to irradiation with small doses of ionizing radiations; the mode of the protective action of certain sulfhydryl compounds against radiation effects on the synthesis of deoxyribonucleic acid, using tritium-labeled thymidine; development of a bubble chamber method of monitoring and dosimetry for Low fast neutron fluxes; effects of incorporated radioisotopes on the stability of genetic materials; interrelation of root and leaf absorption of radioisotopes in herbaceous plants; uptake of radioactive wastes by lowland rice from soils contaminated by irrigation water, and decontamination of the rice; and comparison between mutation rates induced by acute and chronic gamma irradiations. (B.O.G.)

Energy Technology Data Exchange (ETDEWEB)

Papers presented at the workshop include: the longterm viability of mined land in Queensland; the determination and achievement of rehabilitation objectives: a state government objective; monitoring native vegetation in regenerated bauxite mines at Weipa: a belt transect method; rehabilitation strategies at the Collinsville open cut coal mine; the alteration of the environment by the construction and operation of the coal export facility at Abbot Point; some aspects of the premining environment at Collinsville; the prospects for long term revegetation of acid coal mine spoil and reject materials; recovery and stability in disturbed and artificially revegetated plant communities: a theoretical viewpoint; revegetation in the arid tropics: Mount Isa Mines' experience; Nabralek and its rehabilitation; rehabilitation and management strategies for acid mine wastes; the purpose and design of water quality monitoring networks at mine sites; ...

Energy Technology Data Exchange (ETDEWEB)

Petrographic research for the Nevada Nuclear Waste Storage Investigations focused on xenolithic variability in the Topopah Spring Member and on variations of clinoptilolite composition at Yucca Mountain. Zeolite and smectite occurrences were considered in terms of their relation to a disturbed zone beneath the potential repository, and mineral stability experiments have produced a new clinoptilolite structure as a result of prolonged heating at low temperature. Limitations were defined on the abundance of erionite and of sulfur. X-ray diffraction studies lead to improved analytical methods. Progress was made in the comparative study of mineralogy in sand ramps and in faults. Geological modeling considered the differences of the diffusion of nonsorbing tracers in vertically and in horizontally fractured rock. Modeling also treated the diffusion of a nonsorbing tracer in devitrified and in zeolitized rock. The results of these experiments in all ...

Energy Technology Data Exchange (ETDEWEB)

As the first step for development of the corrosion resistant superheater tube materials of 500 C, 100 ata used in high efficient waste-to-energy plants, field corrosion tests of six conventional alloys were carried out at metal temperatures of 450 C and 550 C for 700 and 3,000 hours in four typical Japanese waste incineration plants. The test results indicate that austenitic alloys containing approximately 80 wt% [Cr+Ni] show excellent corrosion resistance. When the corrosive environment is severe, intergranular corrosion of 40{approximately}200 {micro}m depth occurs in stainless steel and high alloyed materials. It is confirmed quantitatively that corrosion behavior is influenced by environmental corrosion factors such as Cl concentration and thickness of deposits on tube surface, metal temperature, and flue gas temperature. The excellent corrosion resistance of high [Cr+Ni+Mo] alloys such as Alloy 625 is explained by the ...

British Library Electronic Table of Contents (United Kingdom)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two sha...

International Nuclear Information System (INIS)

The primary function of the Waste Handling Shaft (WHS) at the Waste Isolation Pilot Plant (WIPP) is to permit the transfer of radioactive waste from the surface waste handling building to the underground storage area. It also serves as an intake shaft for small volumes of air during normal storage operations and as an emergency escape route. Part of the construction was the placement of a concrete liner and steel reinforced key in 1984. During a routine shaft inspection in May 1990, some degradation of the WHS concrete liner was observed between the depths of 800 and 900 feet below the ground surface. Detailed investigations of the liner had been carried out by Sandia National Laboratories and by Westinghouse Electric Corporation Waste Isolation Division (WID) through Lankard Materials Laboratory. Observations, reports, and data support the conclusion that the concrete degradation, ...

Energy Technology Data Exchange (ETDEWEB)

As part of an ongoing strategic research project to find barrels of radioactive waste off San Francisco, the U.S. Navy (USN), the U.S. Geological Survey (USGS), and the Gulf of the Farallones National Marine Sanctuary (GFNMS) pooled their expertise, resources, and technology to form a partnership to verify new computer enhancement techniques developed for detecting targets the size of 55 gallon barrels on sidescan sonar images. Between 1946 and 1970, approximately 47,800 large barrels and other containers of radioactive waste were dumped in the ocean west of San Francisco; the containers litter an area of the sea floor of at least 1400 km {sup 2} knows as the Farallon Island Radioactive Waste Dump. The exact location of the containers and the potential hazard the containers pose to the environment is unknown. The USGS developed computer techniques and contracted with private industry to enhance sidescan ...

International Nuclear Information System (INIS)

A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of "1"3"7Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). ...

International Nuclear Information System (INIS)

Liquid radioactive raffinates from nuclear fuel reprocessing at the Idaho National Engineering and Environmental Laboratory were solidified, or calcines, in a fluidized bed reactor at approximately 500 C to form a dry granular material. This calcine has been provisionally stored near-surface in concrete-encased stainless steel bins at the Idaho Nuclear Technology Engineering Center. Research addressing the permanent immobilization of radioactive waste has been ongoing. One option is to separate the radioactive constituents from the calcine, thereby reducing the radioactive waste volume to be ultimately stored at a national nuclear waste repository. Nitric acid dissolution of the calcine is a key front-end unit operation in the separations option. In order to design calcine dissolution equipment, quantification of dissolution reaction rate parameters is required. A pilot-plant-produced, non-radioactive ...

Energy Technology Data Exchange (ETDEWEB)

A numerical model of multiphase air-water flow and contaminant transport in the unsaturated zone is presented. The multiphase flow equations are solved using the two-pressure, mixed form of the equations with a modified Picard linearization of the equations and a finite element spatial approximation. A volatile contaminant is assumed to be transported in either phase, or in both phases simultaneously. The contaminant partitions between phases with an equilibrium distribution given by Henry`s Law or via kinetic mass transfer. The transport equations are solved using a Galerkin finite element method with reduced integration to lump the resultant matrices. The numerical model is applied to published experimental studies to examine the behavior of the air phase and associated contaminant movement under water infiltration. The model is also used to evaluate a hypothetical design for a low-level radioactive waste disposal facility. The model has been ...

Energy Technology Data Exchange (ETDEWEB)

Grout has been evaluated as a means of containing low-level radioactive waste for long-term disposal. Concerns about hydrogen and reactive gas generation in the Hanford Site grout disposal facility lead to the development of the G3 model, which has predicted buildup of radiolytically formed gases in the grout region and their migration to air-filled regions. The G3 model is a one-dimensional code that couples models of gas diffusion with two-phase gas and liquid flow. It was coupled to a compartment diffusion model and these models predicted the concentrations of hydrogen I nitrous oxide, and other gases in air-filled regions of the grout disposal facility. The results have served as the technical basis for safety studies. A unique finding of the G3 model was that a liquid return, or expulsion of unbound liquid from the grout region, could occur. This liquid return is driven by displacement caused by gas bubbles that form ...

Energy Technology Data Exchange (ETDEWEB)

A study to determine how much energy can be recovered from a Florida citrus processing plant was conducted. The production of ethyl alcohol in particular was examined as it is thought to represent the greatest potential for immediate energy recovery. Three-fourths of the energy expended to produce, harvest, process and market a box of fruit was recoverable using existing technology, i.e. 78,500 Btu/ box of fruit recoverable from a total energy expenditure of 107,800 Btu/ box of fruit. Aside from the actual cost benefits of recovering energy in the form of ethanol, the food processor is also helping to reduce the foreign-oil imports by the blending of ethyl alcohol with unleaded gasoline to form gasohol.

International Nuclear Information System (INIS)

A method is described for immobilizing or solidifying waste material, which includes blending the waste material with powdered metal and subjecting the mixture of waste material and powdered metal to high pressure. (author).

Wastenet

...Publications Consultations Application forms Vacancies Contact us About us Air Climate change Flooding Live flood warnings Flood map How to use it About the ...map View the map FAQs Contact us & Feedback Flooding: who does what? Flood warning - what we do Floodline Warnings Direct Flood ...risk Being prepared FAQs Floodline kids Flooding publications External links Business & Flood Risk Seminar Contact us Land Planning Radioactive substances Waste Water ... You are here: Home Page Flooding Flood map View the map View the map: terms and conditions Important information about ...

International Nuclear Information System (INIS)

Full text of publication follows: As SiCf/SiC composites are very low activation materials, their use as structural material for the reactor blanket and first wall components appears essential to demonstrate the potential of D-T fusion power reactor. Positive features of SiCf/SiC are their high performances at elevated operating temperature and the ability to produce a specific component. Critical issues of SiCf/SiC are the mechanical properties, radiation stability and, with regard to technological issues, their hermeticity and joining processes. Improvement of joining processes for SiC/SiC components is also needed. Recently, several blanket designs have been studied: the TAURO blanket concept in the European Union, the ARIESAT concept in the US and the DREAM concept in Japan. In those reactors, hermetic SiCf/SiC or self-sealing coatings are mandatory. The basic idea of self sealing concept is to manufacture a coating with specific requirements (CTE and ...

International Nuclear Information System (INIS)

Cyclic voltammograms of SUS 304 stainless steel in various neutral solutions such as Na_2SO_4 at high temperature were measured, as a successive study to previous report in which effects of temperature and pH on polarization behavior of stainless steel were studied. In this measurement Ag/AgCl reference electrode and platinum counter electrode were used in a static autoclave lined with inconel. Passive films formed in various conditions were analysed by electron diffraction and Auger spectroscopy. Results obtained were compared with anodic behavior of iron, chromium and nickel and with thermodynamical stabilities of their compounds. The main results are summarized as follows. (1) Stainless steel shows such electrochemical behavior as active dissolution, passivation and transpassivation in a deaerated neutral solution at 250"0C after fully reductive treatment of the specimen. In air-saturated solution, the peak of active dissolution is not ...

Energy Technology Data Exchange (ETDEWEB)

The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel ...

International Nuclear Information System (INIS)

Naturally occurring radionuclides are present in most material. The most common naturally occurring radionuclides in material are those of the uranium and thorium series and potassium-40. This material is commonly referred to as Naturally Occurring Radioactive Material (NORM). In some material the levels of naturally occurring radionuclides are significantly higher, to the extent that regulatory control may be required for radiation protection purposes. Regulation of NORM presents a range of new challenges for both regulators and operators. Unlike more traditional industries dealing with radionuclides, NORM industries have generally not had any radiological oversight and, for example, are not equipped for radiological monitoring. Some consumer goods containing NORM, which have not traditionally been considered as a radiological problem (such as some fertilizers), may require regulation and this may have social and economic consequences. The transport and disposal of NORM are also a ...

CERN Document Server

We present new semi-analytical models for the formation of disk galaxies with the purpose of investigating the origin of the near-infrared Tully-Fisher (TF) relation. The models assume that disks are formed by cooling of the baryons inside dark halos with realistic density profiles, and that the baryons conserve their specific angular momentum. Only gas with densities above the critical density given by Toomre's stability criterion is considered eligible for star formation, and a simple recipe for supernovae feedback is included. We emphasize the importance of extracting the proper luminosity and velocity measures from the models, something that has often been ignored in the past. The observed K-band TF relation has a slope that is steeper than simple predictions based on dynamical arguments suggest. Taking the stability related star formation threshold densities into account steepens the TF relation, decreases its scatter, ...

International Nuclear Information System (INIS)

ZrO_2/O'-sialon composites were obtained via reaction sintering of ZrSiO_4 and Si_3N_4 powders at about 1700 deg C. Y_2O_3 was effective in both stabilizing of zirconia and densifying the composites. However, it is not easy to select an optimum value of the single additive to balance these two requirements simultaneously. With low Y_2O_3 addition, some tetragonal zirconia grains in the sintered samples are transformable during mechanical grinding but the full densification of the material is then sacrificed. On the other hand, addition more Y_2O_3 to achieve complete densification results in the zirconia being stabilized into undesirable t' or cubic forms. Therefore no improved toughening effects have been achieved in the composites. Heat-treatment of the materials at 1400 deg C. results in the diffusion of yttria from the grain boundary phase to zirconia and the formation of the O'-cubic zirconia composite may still ...

International Nuclear Information System (INIS)

A study has been made of the precipitation and growth processes which occur during cooling from solution treatment and under isothermal hold conditions in a magnesia-partially-stabilized zirconia alloy. Three types of precipitate have been identified which develop during cooling or during isothermal hold treatments just above and below the eutectoid temperature. These precipitate forms are termed (i) primary, (ii) large random, and (iii) secondary. Further precipitation, slow growth of existing precipitates, and subeutectoid decomposition result when an additional 1100"0C aging treatment is given to the previously cooled material. It is shown that type (iii) secondary precipitates from rapidly within the temperature range of 1300"0 to 1375"0C. The secondary precipitates are largely responsible for the improved room-temperature strength properties of the heat-treated samples. The formation and effects on mechanical properties of each type of ...

Energy Technology Data Exchange (ETDEWEB)

Power system operating conditions vary with system configurations and loading conditions. Coefficients in nominal system model change in a complex manner with different operating point and so does system dynamic behavior. With the aid of unstructured and structured uncertainty descriptions, the worst system variations can be estimated and formulated into two different uncertainty models in frequency domain; multiplicative unstructured uncertainty in the form of transfer function and structured uncertainty with the parametric uncertainty description. The uncertainty descriptions are then incorporated into system nominal model to perform H{sub {infinity}} and {mu} based robust power system stabilizer (PSS) design. Both approaches to the PSS design enable the power system to remain stable over a wide range of system operating conditions but the different performance can be observed due to the inheritance of the ways to handle the system ...

Wastenet

...Species - see CITES Trade of Dangerous Chemicals Transport and Environment U Urban Environment Use of natural resources V Volatile Organic Compounds W Waste Landfills Waste electrical and electronic equipment - see WEEE Waste incineration Waste legislation - reporting Waste management planning Waste oils Waste shipments Waste water - see Urban waste water Water Bathing Water Drinking water Floods Marine environment Urban waste water Water Framework Directive WEEE - Waste Electric and Electronic Equipment Wildlife ...

Czech Academy of Sciences Repository

Full Text Available

Science.gov (United States)

No abstract available.

Energy Technology Data Exchange (ETDEWEB)

Measurements of temperature and NO concentration in laminar, partially premixed methane-air flames stabilized on a ceramic burner in coflow are reported. The NO concentration and temperature were determined by laser-induced fluorescence (LIF) and coherent anti-Stokes Raman scattering (CARS), respectively. Upstream heat loss to the burner was varied by changing the exit velocity of the fuel-air mixture at a constant equivalence ratio of 1,3; this alters the structure of the flame from an axisymmetric Bunsen-type to a strongly stabilized flat flame. To facilitate analysis of the results, a method is derived for separating the effects of dilution from those of chemical reaction based on the relation between the measured temperature and the local mixture fraction, including the effects of upstream heat loss. Using this method, the amount of NO formed during burnout of the hot, fuel-rich combustion products can be ascertained. ...

CERN Document Server

Regulatory Control of Radioactive Waste Management

KoreaScience (Korea)

Full Text Available

International Science & Technology Center (ISTC)

Methods of Decontamination, Utilization, and Deactivation of Liquid Radioactive Wastes

Science.gov (United States)

... wood, kitchen wastes, and human faeces with the ash from such burning deposited and retained in an ...

International Science & Technology Center (ISTC)

Development, Investigation and Improvement of a System of Incinerating Crop Production Wastes in Small Capacity Boilers

Science.gov (United States)

This study examined the effect of sulfur-containing compounds on the storage stability of Jet A

Wastenet

1 to the operator of a waste collective system by an agreement or contract. The conditions for the ...Fees of the waste collective system are subject to the supervision of the authority responsible for market surveillance. ...The operator of waste collection system collects wastes from producers and holder and transports these to a collection

Science.gov (United States)

Hydrothermal oxidation (HTO) is a promising technology for the treatment of aqueous-fluid hazardous and mixed waste streams. Waste streams identified as likely candidates for treatment by this technology are primarily aqueous fluids containing hazardous organic compounds, and often containing inorganic compounds including radioisotopes (mixed wastes). These wastes are difficult and expensive to treat by conventional technologies (e.g. incineration) due to their high water content; in addition, incineration can lead to concerns related to stack releases. An especially attractive potential advantage of HTO over conventional treatment methods is the total containment of all reaction products within the overall system. The potential application of hydrothermal oxidation (HTO) technology for the treatment of DOE hazardous or mixed wastes has been uncertain due to concerns about safe and ...

International Nuclear Information System (INIS)

The critical superconducting paramters of A-15 compounds are reviewed, and the trends analysed in order to predict maximum values. Experimental data on critical temperature is summarized and compared with theory. The ability to form the stoichiometric, well-ordered materials required for maximum Tsub(c) is discussed in terms of the thermodynamic stability of the A-15 phase. It is concluded that critical temperatures in excess of 25 K, in the A-15 structure, are unlikely. The upper critical field data show that, whereas the vanadium-based compounds are paramagnetically limited, the niobium-based compounds are not. The relation between critical current and microstructure is explored. Best data on critical current densities and ac losses is presented. Finally an account is given of the various methods by which actual conductors, both tapes and multifilamentary wires, are made. (author).

British Library Electronic Table of Contents (United Kingdom)

Metal iodates with a lone-pair containing I(V) that is in an asymmetric coordination geometry can form a diversity of unusual structures and many of them are promising new second homonic generation (SHG) materials. They exhibit wide transparency wavelength regions, large SHG coefficients and high optical-damage thresholds as well as moderately high thermal stability. In this paper, the structures and properties of the metal iodates are reviewed. The combination of d0 transition-metal cations with the iodate groups afforded a large number of metal iodates, with cations covering alkali metal, alkaline earth and lanthanide elements. Many of them are noncentrosymmetric (NCS) and display excellent SHG properties due to the additive effects of polarizations from both types of the asymmetric unit...

British Library Electronic Table of Contents (United Kingdom)

The X-ray storage phosphor CsBr:Eu2+ in form of needle image plates is believed to be a promising alternative to the granular BaFBr:Eu2+ with regard to PSL yield and spatial resolution. Unfortunately, CsBr:Eu2+ exhibits poor radiation hardness, which is caused by a migration of europium ions initiated by naturally existing defect centers like (Eu2+-VCs)-centers and X-ray generated MEu-centers. It will be shown that the formation of (Eu2+-O2?)-dipoles at the expense of (Eu2+-VCs)-dipoles, incorporated by thermal annealing in O2-containing and humid atmosphere, does not improve the radiation stability. There is, however, a strong improvement in the radiation hardness by codoping of CsBr:Eu2+ with lithium ions, which is accompanied by a complete suppression of the previously observed MEu-cent...

International Nuclear Information System (INIS)

Scandium reacts with 4-(2-pyridylazo)resorcinol in the presence of monocarboxylic acids (X) to form mixed-ligand complexes with a Sc:PAR:x ratio of 1:2:2. The chemical nature of this interaction has been established, and the extraction of these mixed-ligand complexes has also been investigated; stability constants and molar extinction coefficients have been calculated. The values of the latter decrease in the order CH_3COOH > CH_2ClCOOH > CCl_3COOH. The formation and extraction of mixed-ligand complexes in Sc-PAR-HX systems make it possible to increase the sensitivity and selectivity of scandium determination in comparison with the use of the Sc-PAR mono-ligand complex.

British Library Electronic Table of Contents (United Kingdom)

Vaccine-mediated prevention of primary HIV-1 infection at the heterosexual mucosal portal of entry may be facilitated by highly optimised formulations or drug delivery devices for intravaginal (i.vag) immunization. Previously we described hydroxyethylcellulose (HEC)-based rheologically structured gel vehicles (RSVs) for vaginal immunization of an HIV-1 vaccine candidate, a soluble recombinant trimeric HIV-1 clade-C envelope glycoprotein designated CN54gp140. Here we investigated the efficacy of lyophilized solid dosage formulations (LSDFs) for prolonging antigen stability and as i.vag delivery modalities. LSDFs were designed and developed that upon i.vag administration they would reconstitute with the imbibing of vaginal fluid to mucoadhesive, site-retentive semi-solids. Mice were immunize...

British Library Electronic Table of Contents (United Kingdom)

Chitosan (a?-(1-4)-amino-2-deoxy-b?-D-glucan) is a deacetylated form of chitin, a polysaccharide from crustacean shells. Its unique characteristics, such as positive charge, biodegradability, biocompatibility, nontoxicity, and rigid structure, make this macromolecule ideal for an oral vaccine delivery system. We prepared reverse-phase evaporation vesicles (REVs) sandwiched by chitosan (Chi) and polyvinylic alcohol (PVA). However, in this method, there are still some problems to be circumvented related to protein stabilization. During the inverted micelle phase of protein nanoencapsulation, hydrophobic interfaces are expanded, leading to interfacial adsorption, followed by protein unfolding and aggregation. Here, spectroscopic and immunological techniques were used to ascertain the effects ...

International Nuclear Information System (INIS)

The corrosion behavior of the sputter-deposited amorphous or nanocrystalline W-Nb alloys is studied in 10% NaCl, 0.1 and 1 M NaOH solutions at 24 deg. C, open to air using immersion tests and electrochemical measurements. Niobium metal acts synergistically with tungsten in enhancing the corrosion resistance of the W-Nb alloys so as to show lower corrosion rates than the corrosion rates of the alloy-constituting elements in almost all examined solutions. Corrosion rates of W-Nb alloys are about more than one order of magnitude less than that of the sputter-deposited tungsten and even lower than that of sputter-deposited niobium. The stability of the anodic passive films formed on the W-Nb alloys increase with niobium content.

Energy Technology Data Exchange (ETDEWEB)

Estimation of mixed Weibull distribution by maximum likelihood estimation and other methods is frequently difficult due to unstable estimates arising from limited data. Bayesian techniques can stabilize these estimates through the priors, but there is no closed-form conjugate family for the Weibull distribution. This paper reduces the number of numeric integrations required for using Bayesian estimation on mixed Weibull situations from five to two, thus making it a more feasible approach to the typical user. It also examines the robustness of the Bayesian estimates under a variety of different prior distributions. It is found that Bayesian estimation can improve accuracy over the MLE for situations with low mixture ratios so long as the prior on the weak subpopulation's characteristic life has an expected value less than or equal to the true characteristic life.

Energy Technology Data Exchange (ETDEWEB)

This report is a compilation of worksheets from the waste management units of Savannah River Plant. Information is presented on the following: Solid Waste Management Units having received hazardous waste or hazardous constituents with a known release to the environment; Solid Waste Management Units having received hazardous waste or hazardous constituents with no known release to the environment; Solid Waste Management Units having received no hazardous waste or hazardous constituents; Waste Management Units having received source; and special nuclear, or byproduct material only.

Energy Technology Data Exchange (ETDEWEB)

The goal of this research project by the Energy & Environmental Research Center (EERC) was to determine the potential for coal ash to serve as a {open_quote}functional filler{close_quotes} in plastics and other composite materials, with special emphasis on recycled plastics. The term functional filler is intended to indicate that the material added to the plastic does more than take up space and extend the use of the polymer. Determining the functional filler potential of ash was not the only intent of this project, since another prime objective was to find a use for materials currently considered waste. The term functional filler also opened a door to the use of cenospheres, which are currently marketed and for which there is sufficient market demand that they do not fit the category of a waste even though they are a product of coal combustion. Cenospheres, hollow spherical ash particles, were selected because of their unique properties. ...

Energy Technology Data Exchange (ETDEWEB)

In this study, silver nanoparticles were formed on a natural macroporous matrix, the stem of rice-paper plant, by reducing Ag{sup +} in aqueous solution through in situ processing without using any other stabilizers. The pores of the matrix, with their size of about 100 {mu}m, were thought to act as reaction compartments for the nucleation and growth of silver nanoparticles, and the control of nucleation of silver crystal during the reduction reaction was found to be important to the successful formation of nanosized silver particles onto the matrix. The diameter and amount of resultant silver particles can be controlled by changing the reaction conditions. Under optimized conditions, the content of silver particles in the matrix can reach as high as 1.8 wt% with the particle diameters being kept below 100 nm. The anti-microbial activities in terms of minimum inhibitory concentration (MIC) for the silver nanoparticle composites against ...

Science.gov (United States)

A method is disclosed of producing blast furnace coke by (1) compacting a finely divided coal wherein at least about 60% by weight of the coal has a diameter of less than about 1/8 inch to form a coal compact, which compact immediately after removal from the compacting means comprises at least about 20% by weight of particles having a particle size of less than 1/4 inch in diameter; (2) breaking the thus formed compact such that the bulk density is sufficiently increased to be capable of conversion into coke suitable for use in large blast furnaces upon carbonization thereof; and (3) carbonizing the broken compact to thereby produce blast furnace coke having a minimum hardness of about 68 and a minimum stability of about 55. The compacting is preferably performed at a pressure equivalent to that achieved by passing the finely divided coal between rolls at a pressure applied to the coal of between about 20 and about 60 ...

Energy Technology Data Exchange (ETDEWEB)

The ultrafine fibers based on the composites of polyethylene terephthalate (PET) and a series of fatty acids, lauric acid (LA), myristic acid (MA), palmitic acid (PA), and stearic acid (SA), were prepared successfully via electrospinning as form-stable phase change materials (PCMs). The morphology and thermal properties of the composite fibers were studied by field emission scanning electron microscopy (FE-SEM) and differential scanning calorimetry (DSC), respectively. It was found that the average fiber diameter increased generally with the content of fatty acid (LA) in the LA/PET composite fibers. The fibers with the low mass ratio maintained cylindrical shape with smooth surface while the quality became worse when the mass ratio is too high (more than 100/100). Moreover, the latent heat of the composite fibers increased with the increase of LA content and the phase transition temperature of the fibers have no obvious variations compared with LA. In contrast, ...

International Nuclear Information System (INIS)

A flame retardant tarpaulin is used for protecting equipments upon periodical repairing in places for handling radioactive materials such as a nuclear power plant. It is formed by coating a woven fabric, a knitted fabric or a non-woven fabric with from 100 to 1000% by weight of a composition formed by blending from 3 to 10 parts by weight of red phosphorus and from 7 to 25 parts by weight of melamine sulfate to 100 parts by weight of an ethylene-vinyl acetate copolymer having a vinyl acetate content of from 8 to 28% by weight. Further, it comprises metal hydroxides such as Mg hydroxide and Al hydroxide. Aids such as plasticizers, stabilizers, lubricants and colorants can optionally be blended so long as they do not inhibit the flame retardant effect. It has an excellent flame retardancy, and does not produce poisonous gases or a great amount of ashes when burnt and discarded. It can be processed with satisfactory ...

Energy Technology Data Exchange (ETDEWEB)

The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain contaminant plumes and new or alternative ...

Energy Technology Data Exchange (ETDEWEB)

This paper reported on a study in which hydrogen was produced by fermentation of biomass. A continuous process using a non-sterile substrate with a readily available mixed microflora was used on heat treated digested sewage sludge from a wastewater treatment plant. Hydrogen was produced from waste sugar at a pH of 5.2 and a temperature of 37 degrees C. An experimental setup of three 5.5 L working volume continuously stirred tank reactors (CSTR) in different stirring speeds were constructed and operated at 7 different hydraulic retention times (HRTs) and different organic loading rates (OLR). Dissolved organic carbon was examined. The results showed that the stirring speed of 135 rpm had a beneficial effect on hydrogen fermentation. The best performance was obtained in 135 rpm and 8 h of HRT. The amount of gas varied with different OLRs, but could be stabilized on a high level. Methane was not detected when the HRT was less than 16 h. The study ...

Energy Technology Data Exchange (ETDEWEB)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO{sub 2}, PrO{sub 2}), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements to their molten ...

Energy Technology Data Exchange (ETDEWEB)

The performance of a geologic repository for high-level nuclear waste will be influenced to a large degree by thermohydrologic phenomena created by the emplacement of heat-generating radioactive waste. The importance of these phenomena is manifest in that they can greatly affect the movement of moisture and the resulting transport of radionuclides from the repository. Thus, these phenomena must be well understood prior to a definitive assessment of a potential repository site. An investigation has been undertaken along three separate avenues of analysis: (i) laboratory experiments, (ii) mathematical models, and (iii) similitude analysis. A summary of accomplishments to date is as follows. (1) A review of the literature on the theory of heat and mass transfer in partially saturated porous medium. (2) A development of the governing conservation and constitutive equations. (3) A development of a dimensionless form of the ...

Energy Technology Data Exchange (ETDEWEB)

Increasingly, governments enact more stringent regulations governing nitrogen and phosphorus in the discharge effluent of wastewater treatment plants. Scientists know that nitrogen and phosphorus accelerates the eutrophication of lakes and reservoirs and stimulates algal growth. Ammonia has proven to be toxic to aquatic life forms, including fish. Engineers favour Biological Nutrient Removal (BNR) over chemical addition to wastewater treatment. Sequencing Batch Reactors (SBRs), a type of bioreactor requiring less land, provide the anaerobic, anoxic, and aerobic zones necessary for BNR. Methanol was used as an effective external source of carbon for denitrification but lacked research. The authors remedied this situation and some of the results were available. They indicated that the addition of methanol in the SBR increased solids production in the SBR, leading to increased sludge wasting to the aerobic digester. All aspects of the sludge ...

Energy Technology Data Exchange (ETDEWEB)

The paper deals with the disposal of radioactive waste and the plans for dealing with solid wastes of intermediate and low levels of activity, which are the responsibility of NIREX. NIREX is an executive body which co-ordinates the waste-disposal plans of the main radioactive waste producers. The disposal routes for the active wastes are described including the deep disposal of wastes containing material that will remain active for thousands of years. Requirements for deep burial are outlined with reference to the geology and hydrogeology of the site. Monitoring, maintenance and surveillance are mentioned for the protection of the public.

International Nuclear Information System (INIS)

Epitaxial cobalt disilicide (CoSi_2) layers are grown on n-Si_0_._8_3Ge_0_._1_7/n-Si(001) using a sacrificial Si capping layer at the growth temperature T_s=650 deg. C by reactive chemical vapor deposition using cyclopentadienyl dicarbonyl cobalt (Co(#eta#"5-C_5H_5)(CO)_2). Structural and electrical properties of epi-CoSi_2/Si_0_._8_3Ge_0_._1_7/Si(001) were measured by transmission electron microscopy, X-ray diffraction, Auger electron spectroscopy and sheet resistance measurement as a function of annealing temperature. The combined results showed that the epitaxial CoSi_2 phase by the reaction of Co with the Si capping layer was formed in the as-grown layers. Rapid thermal anneals for the investigation of thermal stability of the as-grown layers showed good thermal stability of the epitaxial CoSi_2 layers with the low sheet resistance value as low as congruent with 4.4 #OMEGA#/cm up to the annealing temperature as high as ...

Science.gov (United States)

Two branches of research are conducted in this thesis. The first deals with nonlinear combustion response as a mechanism for triggering combustion instabilities in solid rocket motors. A nonlinear wave equation is developed to study a wide class of combustion response functions to second-order in fluctuation amplitude. Conditions for triggering are derived from analysis of limit cycles, and regions of triggering are found in parametric space. Introduction of linear cross-coupling and quadratic self-coupling among the acoustic modes appears to be how the nonlinear combustion response produces triggering to a stable limit cycle. Regions of initial conditions corresponding to stable pulses were found, suggesting that stability depends on initial phase angle and harmonic content, as well as the composite amplitude, of the pulse. Also, dependence of nonlinear stability upon system parameters is considered. The second part of this thesis presents ...

Energy Technology Data Exchange (ETDEWEB)

This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes and industrial wastes in Florida that are potential biomass energy sources.

Wastenet

Waste Technology and Innovation Study Final Report ...Waste Technology and Innovation Study Final Report 21/18569/150554 ...Survey of waste and resource recovery related technology and innovation, including products and product uses

Energy Technology Data Exchange (ETDEWEB)

In this paper the concept of a composite power system stabilizer is investigated. This stabilizer comprises a properly designed, robust, conventional power system stabilizer (CPSS) and an auxiliary stabilizer (AS) which can be either a self-tuning stabilizer (ASTS) or a fixed-parameter stabilizer (AFPS). For small disturbances, the CPSS performs satisfactorily over a wide range of operating conditions. When large disturbances occur the auxiliary stabilizer augments the performance of the CPSS. It has been demonstrated that the composite power system stabilizer can significantly improve the dynamic performance of the system when there is a major disturbance such as a short circuit in the system. Because in the case of a single-machine system the parameters of the ASTS do not vary appreciably, it can also be implemented as ...

Energy Technology Data Exchange (ETDEWEB)

A negative public reaction is expected to oppose plans of the British energy industry to take valuable sites for industrial and commercial projects on the ground that government demand forecasts are too high and that they downplay conservation. The United Kingdom (UK) Department of Energy points out that public inquiry always accompanies energy installations and defends the projections made by producers even though each study emphasizes the demand for its own form of energy. At issue are plans to open 150 opencast coal mines a year to compensate for diminishing oil and gas supplies, onshore drilling by oil and gas exploration teams on nearly 50,000 km/sup 2/, and sites required for onshore pipelines, synthetic natural gas facilities, pumped storage plants, and nuclear power stations and waste management. The sites under discussion raise aesthetic and ecological concerns. (DCK)

Energy Technology Data Exchange (ETDEWEB)

Red mud is a by-product of bauxite processing through Bayer process. The amount of red mud generated depends largely on the type of ore used and the processing. Use of red mud as a catalyst can be a good alternative to the existing commercial catalysts. Its properties such as iron content in form of ferric oxide (Fe{sub 2}O{sub 3}), high surface area, sintering resistance, resistance to poisoning and low cost make it an attractive potential catalyst for many reactions. Besides red mud, ferric ion sludge from wastewater treatment plant has also been studied for its catalytic properties, mainly due to its ferric oxide constituent. This paper reviews the studies on red mud as a catalyst. The catalyst characteristics, reaction mechanisms involved and performance are examined and compared with iron oxide catalyst and commercial catalysts. (author)

International Nuclear Information System (INIS)

Fe_5_0Pt_5_0 nanodots dispersed in a SiO_2 film (Fe_5_0Pt_5_0 nanodot film) were formed by a self-assembled nanodot deposition (SAND) method in which Fe_5_0Pt_5_0 and SiO_2 are cosputtered in a high vacuum rf magnetron sputtering equipment. Fe_5_0Pt_5_0 pellets are laid on a SiO_2 target in a sputtering chamber to form the Fe_5_0Pt_5_0 nanodot film in the SAND method. The size and density of Fe_5_0Pt_5_0 nanodot were controlled by changing the ratio of the total area of Fe_5_0Pt_5_0 pellets to that of SiO_2 target. The Fe_5_0Pt_5_0 nanodot size decreases and its density increases when the ratio decreases. As-deposited Fe_5_0Pt_5_0 nanodots self-assembled to a face-centered-cubic phase of single-crystal structure. The Fe_5_0Pt_5_0 nanodot films were annealed to evaluate the nanodot size controllability, the magnetic anisotropy, and the thermal stability. Fully ordered L1_0 face-centered-tetragonal Fe_5_0Pt_5_0 nanodots with ...

Energy Technology Data Exchange (ETDEWEB)

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, is conducting a study to determine the natural geochemistry of the Snake River Plain aquifer system at the Idaho National Engineering Laboratory (INEL), Idaho. As part of this study, a group of geochemical reactions that partially control the natural chemistry of ground water at the INEL were identified. Mineralogy of the aquifer matrix was determined using X-ray diffraction and thin-section analysis and theoretical stabilities of the minerals were used to identify potential solid-phase reactants and products of the reactions. The reactants and products that have an important contribution to the natural geochemistry include labradorite, olivine, pyroxene, smectite, calcite, ferric oxyhydroxide, and several silica phases. To further identify the reactions, analyses of 22 representative water samples from sites tapping the Snake River Plain aquifer system were used to determine the ...

Energy Technology Data Exchange (ETDEWEB)

Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid ...

Science.gov (United States)

The Savannah River Site (SRS) is a 310-square-mile United States Department of Energy nuclear facility located along the Savannah River (SRS) near Aiken, South Carolina. Nuclear weapons material production began in the early 1950s, utilizing five production reactors. In the early 1990s all SRS production reactor operations were terminated. The first reactor closure end state declaration was recently institutionalized in a Comprehensive Environmental Response and Compensation and Liability Act (CERCLA) Early Action Record of Decision. The decision for the final closure of the 318,000 square foot 105-P Reactor was determined to be in situ decommissioning (ISD). ISD is an acceptable and cost effective alternative to off-site disposal for the reactor building, which will allow for consolidation of remedial action wastes generated from other cleanup activities within the P Area. ISD is considered protective by the regulators, U. S. Environmental Protection Agency (US ...

International Nuclear Information System (INIS)

Immobilization of a model liquid organic pollutant, i.e. the 2-chloroaniline (2-CA), into a cement matrix using organoclays as pre-sorbent agents was investigated. Five cement-clay pastes were prepared with different nominal water-to-cement ratios (w/c=0.40, 0.25 and 0.15 wt/wt) and various amounts of waste (waste-to-cement o/c=0.20, 0.60 and 1.00 wt/wt); for comparison, a neat cement paste was also prepared. Dynamic leach tests were performed on solidified monoliths in order to assess the successful immobilization of the 2-CA. In monoliths at constant w/c ratio (0.40) the total amount of pollutant released increases with its initial content, and ranges from 15 to 35% with respect to it. By lowering w/c from 0.40 to 0.15 at constant o/c, the performances improved (<25% released). The microstructure of the hardened cement-clay pastes was characterized by quantitative X-ray diffraction (QXRD) and electronic microscopy (SEM-EDS) techniques; ...

International Nuclear Information System (INIS)

In the utilization of the thermal energy by ocean temperature difference and factory waste heat, the high performance heating surfaces in pipes from which scale can be removed are required. As the method of removing scale, the method using sponge balls seems most suitable, but for applying this method, as the form of the protrusions attached to the inner surfaces of pipes, smooth circular are form is desirable. The promotion of heat transfer with the rows of circular arc protrusions like this is strongly related to the mode of flow and such structure as separation, recirculation flow, readhesion and turbulent energy generation. In this study, as the basic research to optimize the heating surface with the rows of smooth protrusions, the flow characteristics and the heat transfer characteristics including the turbulent structure of the wake of protrusions were experimentally determined, and the essence of the heat transfer ...

Energy Technology Data Exchange (ETDEWEB)

This revision of the APT Waste Management Plan details the waste management requirements and issues specific to the APT plant for design considerations, construction, and operation. The APT Waste Management Plan is by its nature a living document and will be reviewed at least annually and revised as required.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

UK PubMed Central (United Kingdom)

Electronic waste or e-waste is one of the rapidly growing problems of the world. E-waste comprises of a multitude of components, some containing toxic substances that can have an adverse impact on human...Full Text Available

Science.gov (United States)

PMID:21769853

Science.gov (United States)

...2009-07-01 false Definition of solid waste. 261.2 Section 261.2 Protection...PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.2 Definition...

Wastenet

Date: Cost: Allocation:

Energy Technology Data Exchange (ETDEWEB)

From out of the numerous technical alternatives the manual develops a waste management concept with emphasis on methods which can be coordinated for maximum ecological use and minimum economic costs. A clear-cut analysis of the present state of waste utilization and waste disposal in the Federal Republic of Germany (chapter 1) is followed by a detailed description of conventional and modern state-of-the-art waste utilization methods based on ecological evaluation criteria (chapter 3). An optimum waste utilization concept for defined quantities of wastes is derived from the ecological and economic comparison of waste utilization techniques given in chapter 3. Chapter 4 points out different variants of waste utilization and waste disposal methods and shows how to determine the optimum variant of the ...

Energy Technology Data Exchange (ETDEWEB)

Drastic changes in waste management procedures are expected from the German Municipal Waste Disposal Regulations which became effective on June 1, 1993. Waste disposal will be subject to certain restrictions which, e.g. demand that wastes must be pretreated and inerted before they are stored. These regulations favor thermal waste disposal methods such as the carbonization/combustion method which is planned for a commercial-scale plant in the city of Fuerth. (orig./BBR)

CERN Document Server

Safe management of wastes from the mining and milling of Uranium and Thorium ores

Science.gov (United States)

One of the major problems associated with solid waste processing technologies is the release of

Energy Technology Data Exchange (ETDEWEB)

This paper addresses one source of degradation in OPV devices: the metal/organic interface. The basic approach was to study the completed device stability vs. the stability of the organic film itself as shown in subsequent devices fabricated from the films.

Energy Technology Data Exchange (ETDEWEB)

After that power fluctuations had occurred at Borssele nuclear power station it was decided to install a power system stabilizer. This stabilizer shall reduce the unwanted power fluctuations. The preliminary research and the results of measurements carried out during commissioning are described. (J.C.R.)

Energy Technology Data Exchange (ETDEWEB)

This Radioactive and Mixed Waste Management Plan for the Hazardous Waste Handling Facility at Lawrence Berkeley Laboratory is written to meet the requirements for an annual report of radioactive and mixed waste management activities outlined in DOE Order 5820.2A. Radioactive and mixed waste management activities during FY 1994 listed here include principal regulatory and environmental issues and the degree to which planned activities were accomplished.

Energy Technology Data Exchange (ETDEWEB)

Implementation of a plan to charge waste management costs to the facility that generates such waste requires a long-term commitment and consistent administration. The benefit is that generators are provided the incentive to optimize waste management practices if the charges are appropriately applied. This paper summarizes (1) a plan to charge waste generators, (2) the administrative structure of the plan, (3) a comparison between the rate structure and changes in waste disposal operations, and (4) issues that have surfaced as the plan is implemented. 2 refs., 1 fig., 1 tab.

Science.gov (United States)

Thermal models are constructed and analyses are performed of aluminum-based spent nuclear fuel (Al-SNF) in interim dry storage and geologic disposal configurations. Two models are developed, referred to as the interim storage model and the codisposal waste package (WP) model. Time-dependent source terms of Al-SNF forms and the defense high-level waste (DHLW) canisters are also developed for thermal performance analysis of the geologic codisposal WP.The interim storage model is a three-dimensional conduction-convection conjugate model to investigate the natural convection cooling of a sealed dry storage canister with vertical orientation in a dry storage vault. The analysis is made for various decay heat sources (equivalent to 25 to 35 kW/m{sup 3}) using various boundary conditions around the canister wall and with backfilled nitrogen or helium gas. Based on the data obtained from the Savannah River Site experimental work ...

International Nuclear Information System (INIS)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level #alpha# solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends ...

Energy Technology Data Exchange (ETDEWEB)

Municipal solid waste incineration (MSWI) bottom ash contains economically significant levels of silver and gold. Bottom ashes from incinerators at Amsterdam and Ludwigshafen were sampled, processed, and analyzed to determine the composition, size, and mass distribution of the precious metals. In order to establish accurate statistics of the gold particles, a sample of heavy non-ferrous metals produced from 15 tons of wet processed Amsterdam ash was analyzed by a new technology called magnetic density separation (MDS). Amsterdam's bottom ash contains approximately 10 ppm of silver and 0.4 ppm of gold, which was found in particulate form in all size fractions below 20 mm. The sample from Ludwigshafen was too small to give accurate values on the gold content, but the silver content was found to be identical to the value measured for the Amsterdam ash. Precious metal value in particles smaller than 2 mm seems to derive mainly from ...

International Nuclear Information System (INIS)

Hospital wastes comprises approximately 80% domestic waste components, also known as non-risk waste and 20% hazardous or risk waste. The 20% of the hospital waste stream or the risk waste (also known as infectious, medical, clinical wastes) comprises components which could be potentially contaminated with infections, chemical or radioactive agents. Therefore, it should be handled and disposed of in such a manner as to minimize potential human exposure and cross-contamination. Hospital risk waste and be subdivided into seven general categories as follows: infections, anatomical/pathological, chemical, pharmaceutical, radioactive waste, sharps and pressurised containers. These waste categories are generated by many types of health care establishments, including hospitals, clinics, ...

UK PubMed Central (United Kingdom)

We describe the stabilization by pressure of enzymes, including a hydrogenase from Methanococcus jannaschii, an extremely thermophilic deep-sea methanogen. This is the first published...Full Text Available