Energy Technology Data Exchange (ETDEWEB)

Oil shale occurrences have been historically reported in the Cape Breton Island, northern mainland and southern mainland areas of Nova Scotia. Twelve of these occurrences were investigated for this study. Rocks from three of the areas gave oil yields of less than 25 litres per tonne (below oil shale grade) while the remainder gave oil yields greater than 25 litres per tonne (above oil shale grade). The rock types of oil shale grade include silicate-rich shale, carbonaceous shale locally transitional to coal, limy shale and petroliferous limestone associated with coal, silicate-rich shale and cannel shale associated with coal and silicate-rich shale, cannel shale and boghead ...

Energy Technology Data Exchange (ETDEWEB)

Ammonium nitrate shale oil explosives are provided which are effective, powerful, inexpensive, and safe. The explosives contain about 2% to 10% by weight shale oil and about 90% to 98% by weight ammonium nitrate. The shale oil can be whole shale oil or heavy shale oil containing from 0.1% to 65% by weight oil shale dust. The ammonium nitrate is preferably in the form of explosive grade ammonium nitrate prills.

Energy Technology Data Exchange (ETDEWEB)

An evaluation of eastern shale oil (ESO) residue as an asphalt additive to reduce oxidative age hardening and moisture susceptibility was conducted by Western Research Institute (WRI). The ESO residue, have a viscosity of 23.9 Pa{lg_bullet}s at 60{degree}C (140{degree}F), was blended with three different petroleum-derived asphalts, ASD-1, AAK-1, and AAM-1, which are known to be very susceptible to oxidative aging. Rheological and infrared analyses of the unaged and aged asphalts and the blends were then conducted to evaluate oxidative age hardening. In addition, the petroleum-derived asphalts and the blends were coated onto three different aggregates, Lithonia granite (RA), a low-absorption limestone (RD), and a siliceous Gulf Coast gravel (RL), and compacted into briquettes. Successive freeze-thaw cycling was then conducted to evaluate the moisture susceptibility of the prepared briquettes. The rheological analyses of the unaged ...

Energy Technology Data Exchange (ETDEWEB)

China is continuing to extract oil from kerogen shale despite having a crude production capacity of 100 Mt a year. Among the reasons for this policy are the country's rich oil shale resources, comparatively mature extraction techniques, and a comprehensive utilization of the shale that has proved to be economically profitable. China has oil shale deposits of 340 Gt, equivalent to 24.5 Gt of shale oil, to rank fourth in the world after the U.S., Brazil, and the Soviet Union.

Energy Technology Data Exchange (ETDEWEB)

In China, the conventional utilization of oil shale is concentrated mainly on retorting oil shale to produce shale oil and fuel gas, and burning oil shale to generate electricity. The growth of petroleum price, and the development in heavy industry, make these conventional utilization facilities become unavailable on the energy market. In this paper, a new comprehensive utilization system is recommended for the future use of Huadian oil shale, based on the current status of energy and the characteristics of oil shale. The system involves three subsystems: retort subsystem, where coarse oil shale (8-80 mm) is retorted to shale oil, hydrocarbon gases and oil shale semicoke; combustion subsystem, where the mixture fuel of oil-shale semicoke and fine oil shale ...

Energy Technology Data Exchange (ETDEWEB)

Spectrophotometric methods were used to investigate the properties of neptunium(VII), (VI), and (V) in silicate solution. The transition of cationic neptunium(VII) to anionic species in non-complexing environments proceeds in the range of ?? 5.5 to 7.5. In the presence of carbonate, this transition occurs at ?? 10.0 to 11.5 and in silicate solutions at ?? 10.5-12.0. These findings show that cationic neptunium(VII) forms complexes with both carbonate and silicate and that the silicate complex is stronger than that of the carbonate. The competition of complex formation reactions for neptunium(VI) with carbonate and silicate and on the known complex stability constant of NpO2(CO3)34- allowed the NpO2SiO3 complex stability constant, log ? = 16.5, to be estimated. Determination of the formation constant of Np(V) complexes with SiO32- was not possible using similar methods.

Energy Technology Data Exchange (ETDEWEB)

The technology being evaluated is the Modified In-Situ (MIS) retorting process for raw shale oil production, combined with a Circulating Fluidized Bed Combustor (CFBC), for the recovery of energy from the mined shale. (VC)

International Nuclear Information System (INIS)

Short Communication.

Energy Technology Data Exchange (ETDEWEB)

A geochemical survey to assess and evaluate the Devonian oil shale resources of north Alabama, northwest Georgia, and south-central Tennessee has been performed. Information is provided on the location and extent of the more favorable kerogen-bearing Devonian shale, oil and uranium content of the shale, trace metal and standard rock analyses for shale, data on the physical properties of the shale rock, mineralogy of the shale, chemical properties of the oil, and other pertinent data deemed necessary for resource development. The results indicate that the oil yield from areas underlain by Chattanooga Shale can be divided into areas having greater than 7 g/t and areas having less than 7 g/t. In general, the oil yield by Fischer assay of samples from the folded Appalachian Valley and Ridge and the Appalachian Plateaus provinces is poor, all ...

Energy Technology Data Exchange (ETDEWEB)

The Western Research Institute plan for addressing oil shale plant siting methodology calls for identifying the available resources such as oil shale, water, topography and transportation, and human resources. Restrictions on development are addressed: land ownership, land use, water rights, environment, socioeconomics, culture, health and safety, and other institutional restrictions. Descriptions of the technologies for development of oil shale resources are included. The impacts of oil shale development on the environment, socioeconomic structure, water availability, and other conditions are discussed. Finally, the Western Research Institute plan proposes to integrate these topics to develop a flow chart for oil shale plant siting. Western Research Institute has (1) identified relative topics for shale oil plant siting, (2) surveyed both published and ...

Energy Technology Data Exchange (ETDEWEB)

In order to assess whether an oil shale test facility would be of significant use to private sector oil shale developers, the US DOE has studied the past history of oil shale development and its potential for replacing petroleum supplies. A generic test facility's primary function would be to test concepts of mining, retorting, upgrading, and environmental aspects at the engineering scale. This paper summarizes the US oil shale resources, gives a technology analysis, and discusses the potential for a test facility.

Energy Technology Data Exchange (ETDEWEB)

Assessment of the oil shale resources in Kentucky has continued with 75 NX cores available where the oil shale crops out or is overlain by relatively thin cover in the area from Estill County westward to Bullitt County. In this 14 county area, the total black shale section thins across the crest of the Cincinnati arch and changes stratigraphically from that characteristic of the Ohio Shale in Estill County to that of the New Albany Shale in Bullitt County. Despite this stratigraphic transition the two high-carbon zones (greater than 8.0% carbon) can be traced across the arch. As the traverse is followed from the east, the intervening low-carbon zones thin such that at the crest of the arch, there are areas where the entire section of black shale contains more than 8% carbon. Then upon leaving the crest the two high-carbon zones separate again with one remaining ...

Energy Technology Data Exchange (ETDEWEB)

A study is reported of the use of three types of fly ash as a raw material in the production of a potassium silicate fertilizer. The results of high-temperature X-ray diffraction, calcination tests and chemical analyses indicate that a potassium silicate fertilizer conforming with fertilizer specifications can be produced by appropriate regulation of calcining temperature and the amounts of Fe/sub 2/0/sub 3/, Al/sub 2/O/sub 3/, MgO and CaO added. The results of tests of fertilizers incorporating red mud are also reported.

Energy Technology Data Exchange (ETDEWEB)

While no mine in Queensland has yet extracted shale oil economically, large resources of oil shale are known to occur throughout the State. These resources have been reported to the Queensland Department of Resource Industries (formerly the Department of Mines) according to a number of different parameters, using numerous methods of calculation and in some instances, detailed and comprehensive supporting information has not been provided. This paper outlines present methods of calculation and reporting of oil shale resources. A more uniform system of reporting resources of Queensland oil shale is desirable to enable an accountable and reliable estimate of resources to be made. It is intended that a code for the reporting of identified oil shale resources based on the present Australian codes for the reporting of identified mineral and coal resources be prepared, and that the ...

Energy Technology Data Exchange (ETDEWEB)

In October, 1986, the US Bureau of Land Management, White River Resource Area, issued the Final Environmental Impact Statement concerning Rio Blanco Oil Shale Company's request to lease an offtract site for disposal of overburden and spent shale from Tract C-a. A major issue which pitted Rio Blanco Oil Shale Company against many other members of the oil shale community was the covering up of oil shale resources on 84 Mesa. The oil shale resource under 84 Mesa may contain as much oil in place as Tract C-a itself. Some of the significant points concerning this issue are discussed. A summary of environmental consequences is given. 5 figures.

Energy Technology Data Exchange (ETDEWEB)

The objective of this investigation was to perform a preliminary evaluation of the utility of residual materials prepared from Green River Formation (western) and New Albany Shale (eastern) shale oils as recycling agents for aged asphalt pavement. Four petroleum asphalts were first aged by a thin-film accelerated-aging test, which simulates long service life of asphalt in pavement. The aged asphalts were mixed (recycled) with Green River Formation shale oil distillation residua to restore the original viscosities. Separately, for comparison, a commercial recycling agent was used to recycle the aged asphalts under the same circumstances. The recycled asphalts were reaged and the properties of both binder and asphalt-aggregate mixtures studied. Originally, the same study was intended for an eastern shale residua. However, the eastern shale oil distillation residua with the required ...

Energy Technology Data Exchange (ETDEWEB)

Morocco is among the world's leading countries in terms of total indigenous oil shale resources. Following the 1973 oil crisis, Morocco has been determined to develop its oil shale energy resources. In the subsequent years following the crisis, a tremendous number and variety of studies and research efforts have resulted in an enormous amount of data, covering geological, hydrogeological, mining, physical and chemical aspects of the two main deposits, Timahdit and Tarfaya. This article represents a tentative analysis of oil shale development in Morocco and offers a few ideas on where it might be heading. 1 fig., 2 photos.

Science.gov (United States)

... unlimited. It may be released to the Clearinghouse. DePartment of Comereforsae o te enga Page 2. EDITED TRANSLATION A ...

Energy Technology Data Exchange (ETDEWEB)

Exploration for oil shale in Queensland between June 1986 and July 1987 continued over 12 deposits ranging in age from Permian to Tertiary. The total estimated resource of shale oil contained within these deposits is 4479 GL (28.2 billion barrels). 4 refs., 1 fig., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

Shale oil as a fuel source would need to compete with crude oil. The prospects for shale oil therefore depend upon the market outlook and likely prices for crude oil and its products. These are examined for both the world and Australia. For Australia, market prospects for shale oil are assessed in terms of maintaining a degree of self-sufficiency in petroleum fuels. Shale oil might also need to compete with other synthetic liquid fuels. The prospects for producing these in Australia are discussed. Some factors which might influence the pattern of development of a synthetic fuels industry in Australia are described and a role suggested for the federal government to ensure optimum development for national economic growth. 6 refs., 1 fig.

Energy Technology Data Exchange (ETDEWEB)

An Oil Shale Mining Economic Model (OSMEM) was developed and executed for mining scenarios representative of commercially feasible mining operations. Mining systems were evaluated for candidate sites in the Piceance Creek Basin. Mining methods selected included: (1) room-and-pillar; (2) chamber-and-pillar, with spent shale backfilling; (3) sublevel stopping; and (4) sublevel stopping, with spent shale backfilling. Mines were designed to extract oil shale resources to support a 50,000 barrels-per-day surface processing facility. Costs developed for each mining scenario included all capital and operating expenses associated with the underground mining methods. Parametric and sensitivity analyses were performed to determine the sensitivity of mining cost to changes in capital cost, operating cost, return on investment, and cost escalation.

Energy Technology Data Exchange (ETDEWEB)

It has been shown that not only there are abundant oil, gas, coal, coal-bed gas, groundwater and giant uranium deposits but also there are abundant oil shale resources in Ordos basin. It has been shown also that the thickness of oil shale is, usually, 4-36m, oil-bearing 1.5%-13.7%, caloric value 1.66-20.98MJ/kg. The resource amount of oil shale with burial depth less than 2000 m is over 2000x108t (334). Within it, confirmed reserve is about 1x108t (121). Not only huge economic benefit but also precious experience in developing oil shale may be obtained in Ordos basin.

Energy Technology Data Exchange (ETDEWEB)

The Oil Shale Program is directed toward the development of advanced technologies for extracting shale oil from large, currently unrecoverable oil shale resources. The overall goal of the Oil Shale Program is to foster development by the private sector of an economically competitive and environmentally acceptable oil shale industry whose products can compete with natural petroleum liquids in the marketplace by the year 2000. For the achievement of this goal, a series of interrelated technology development steps must take place, some sponsored by DOE, some by other government agencies, and some by other governments and/or the private sector. These include basic and applied research and development, proof-of-concept activities, first-of-a-kind field tests, and associated commercial scale activity. Activities associated with the Oil Shale Program are designed to ...

Energy Technology Data Exchange (ETDEWEB)

For many decades, the oil shale resources of the western United States have been considered possible contributors to the Nation's liquid fuel supply. This volume reviews several paths to development of these resources and the likely consequences of following these paths. A chapter providing background information about the nature of oil shale is followed by an evaluation of technologies for recovery of shale oil. The economics and finances of establishing an industry of various sizes are analyzed. The fact that much of the best shale is located on Federal land is examined in light of the desire to increase use of the resources. The consequences of shale development in terms of impact on the physical and social environments, and a discussion of the availability of water complete the report. Policy options addressing barriers that could hinder the establishment of the ...

Energy Technology Data Exchange (ETDEWEB)

A definition is given for the basic national economic task of developing the recovery of hydrocarbons from bitumen-containing rock and oil shales, and a description is given of the status of the mineral-raw material base. General concepts are given on bitumens and oil shale. Their elemental and group compositions are cited in detail, and a determination is made of the position they occupy in the total system of fossil fuels. An examination is made of data on the distribution and state of bitumen and oil shale resources, and a description is given of their principal deposits. An evaluation is made of gained experience and the potential of existing methods of working bituminous rock and oil shale deposits that include the use of available and utilized method of land-based, underground, and instrastratal extraction of petroleum from those deposits. A presentation is made of the technical-economic aspects ...

International Nuclear Information System (INIS)

Sialons are phases in the Si-Al-O-N and M-Si-Al-O-N systems where M includes Li, Mg, Ca, Sc, Y and the rare earth elements. They are comparable in variety with the mineral silicates and are built up of one-, two-, and three-dimensional arrangements of (Si,Al)(O,N)/sub 4/ tetrahedra in the same way that the structural units of the silicates are SiO/sub 4/ tetrahedra. These new materials include N-containing ceramics, glasses and glass-ceramics that are being explored for their thermal, chemical and physical properties.

Energy Technology Data Exchange (ETDEWEB)

This was a project to investigate the crystal chemistry of OH and H{sub 2}O substitution in silicate minerals by use of X-ray and neutron diffraction methods combined with IR spectroscopy and to interpret and generalize the results using an electrostatic model for these mineral structures. Using these data together with published H position data electrostatic parameters for H sites were calculated from a simple electrostatic model. The data were then used to refine the model for incorporation of H into the wadsleyite structure. This has led to recent work on the synthesis and characterization of hydrous wadsleyites.

Energy Technology Data Exchange (ETDEWEB)

Significant development of an oil shale industry has been projected over the next few decades. The nation's largest oil shale reserves exist in the Wyoming Basin and Colorado Plateau physiographic provinces. This study presents a brief description of the environmental setting and land-use pattern of the region, with a review of the major environmental issues associated with each proposed technology for extracting shale oil. Serious effects may be expected from the modification of very large land surfaces through open-pit mining and spent-shale disposal. The impacts include habitat destruction, potential species loss, and deterioration of surface and groundwater quality. In situ retorting of shale may result in major alterations of groundwater quantity, quality, and flow regimes. Mine dewatering from in situ retorting requires the disposal of large volumes of highly saline ...

Energy Technology Data Exchange (ETDEWEB)

This proceedings includes the papers presented at the US Department of Energy's Second Annual Oil Shale Contractors Meeting. The meeting was sponsored and hosted by the US Department of Energy's Morgantown Energy Technology Center and was held August 12-13, 1986, at the Ramada Inn in Morgantown, West Virginia. This year's meeting was attended by some 100 individuals from private industry, academia, research institutes, national laboratories, state and Federal Government agencies, and other domestic and foreign businesses. The purposes of this meeting were (1) to review and evaluate the current research in the Oil Shale Program, (2) to establish a forum for interchange of information and ideas related to oil shale, and (3) to assist the Department in planning future work. Utilization of the United States oil shale resources will not occur without the investment, involvement, ...

Energy Technology Data Exchange (ETDEWEB)

The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application ...

Energy Technology Data Exchange (ETDEWEB)

The oil shales of the Eastern United States represent a very large energy resource that also lies close to the marketplace. Although estimates vary, one estimate shows that more than 400 billion barrels of oil are recoverable from surface-mineable Devonian oil shales in the states of Alabama, Indiana, Kentucky, Michigan, Ohio, and Tennessee. Conventional thermal retorting of Eastern and Western oil shales with comparable organic carbon contents results in a much lower oil yield for the Eastern shales. This discouraged research and development of this energy resource, until about ten years ago, when the Institute of Gas Technology discovered that retorting Eastern oil shales in a hydrogen-rich atmosphere at elevated pressures gives oil yields that are 2.5 times those possible by thermal retorting. Over the last ten years many research, development, and feasibility programs, both ...

Energy Technology Data Exchange (ETDEWEB)

Trying to achieve the optimal utilization of oil shale resources, and the production of a more environmentally acceptable fuel, as well as a solid waste with a low a sulphur content, thereby reducing acidic leachates, has led to this investigation. In this article, the influences of the bed temperature and the choice of fluidizing gas on the quality and quantity of the produced fuel gas, using a continuous feed fluidized bed reactor, were investigated. The composition and calorific value of the generated gas were determined. There was a nearly linear increase in the amount of fuel gas produced as a function of temperature, reaching {approx}350 kg per 10{sup 3} kg of dry raw shale and the gross calorific value ranged from 15 to 23 MJ-kg{sup -1} with CO and H{sub 2} being the major constituents. Subsequent experiments were carried out, employing a thermogravimetric analyser under similar conditions as applied to the fluidized bed reactor. ...

Energy Technology Data Exchange (ETDEWEB)

Oil shale resource data are provided for a 1300-square mile area around Farson, Wyoming. The data were derived from analyses of samples from 14 core holes drilled by the US Bureau of Mines and the Department of Energy, plus 4 core holes drilled by private companies. Fischer assay oil yield data for nine stratigraphic resource units are tabulated, correlated, and contoured to provide an assessment of shale oil potential in the area. Oil shale resources in the northeastern part of the Green River Basin occur in the Laney Member and the upper part of the Wilkins Peak Member of the Eocene Green River Formation. A total in-place shale oil resource of 137 billion barrels was calculated for the area. Four stratigraphic resource units have average oil yields of 12 to 20+ gallons per ton within the area of investigation, and in some parts a section up to 275 feet thick averages as much as 15.9 gallons per ton. ...

Energy Technology Data Exchange (ETDEWEB)

This article presents the comparative bench testing results of a naturally aspirated, four stroke, four cylinder, water cooled, direct injection Diesel engine when running on diesel fuel and shale oil that is produced in Estonia from local oil shale. The purpose of this research is to investigate the possibility of practical usage of the shale oil as the alternative fuel for a high speed Diesel engine as well as to evaluate the combustion efficiency, brake specific fuel consumption, emission composition changes and the smoke opacity of the exhausts. Test results show that when fuelling a fully loaded engine with shale oil, the brake specific fuel consumption at the maximum torque and rated power is correspondingly higher by 12.3% and 20.4%. However, the brake thermal efficiencies do not differ widely and their maximum values remain equal to 0.36-0.37 for Diesel fuel and 0.32-0.33 for ...

International Nuclear Information System (INIS)

Sodium silicate is vacuum impregnated in bauxite waste (red mud) at room temperature to develop ceramics of mechanical properties comparable to the sintered ceramics. For a concentration up to 10% the fracture toughness increases from 0.12 MNm"-"3"/"2 to 0.9 MNm"-"3"/"2, and the compressive strength from 7 MNm"-"2 to 30 MNm"-"2. The mechanical properties do not deteriorate, when soaked in water for an entire week. The viscosity and the concentration of the silicate solution are crucial, both for the success of the fabrication and the economics of the process. Similar successful results have been obtained for bauxite and lime stone, even though the latter has poor weathering properties. With scanning electron microscopy and energy dispersive analysis, an attempt is made to identify the crystals formed in the composite, which are responsible for the strength. The process is an economic alternative to the sintered ceramics in the construction ...

Energy Technology Data Exchange (ETDEWEB)

Oil shales of the US represent a tremendous store of potential oil. Most of the deposits are relatively unknown and warrant additional investigation. The summary presented cannot hope to cover all of the deposits. Information about them is usually available only locally. However, the 3 best known deposits - the Green River formation, the Devonian black shales, and the retort member of the Phosphoria formation - represent well over 2 trillion bbl (300 x 10/sup 12/ ton) of potential oil in place. This is an oil resource large enough to supplement quite adequately the US petroleum supply, to extend the time available for realigning our energy supply mixes, and to help reach a satisfactory solution to our current energy dilemma. The concentrated resource in the Green River formation is obviously the next most feasible source of oil. If it cannot be developed, all the other deposits will have to wait until it can be. 100 references.

Energy Technology Data Exchange (ETDEWEB)

The steps in assembling the computational tools needed to simulate the explosive fracture of oil shale have been described. The resulting code, with its input data, then was used to simulate 3 explosive field experiments. The results of the calculations are in good agreement with what actually occurred in the field. Further detailed comparisons are in progress for these experiments and the others that have been conducted. The development of computer codes as tools to predict rock breakage makes a variety of studies possible. The properties of the explosive can be changed to see how the extent of rubbling is affected. Studies of spacing and delays for decked charges also are possible. The codes can be applied in situations, such as confined-volume blasting, at the frontiers of blasting technology. These areas are vital to the effective utilization of oil shale resources, especially with in situ techniques. 13 references.

International Nuclear Information System (INIS)

Some results and experimental procedures of laboratory are reported in the frame of researches conducted for the development of new nanostructured composite materials. These new materials, which are constituted by an organic phase: the polymer and an inorganic phase: the silicate, are being strongly investigated nowadays so it is expected that they could provide, among other, better electrical insulation properties and flame-delay in electrical and electronic applications. The laboratory experimental work has been developed from two families of polymers, thermoplastics and thermosets and clays silicates providing lamellar type. There are now some preliminary results, such as obtaining thin films of these nanocomposite materials, their complete characterization by X-ray diffraction, scanning microscopy and thermogravimetric analysis, they do well to wait for future research activities. (author)

International Nuclear Information System (INIS)

Titanium stabilized austenitic steel is sensitive to SCC in the secondary water under the horizontal steam generator operating conditions. SCC was observed under crevice conditions both at the primary collector flanges and the heat exchange tubes. In the crevice environment sulfates and chlorides as aggressive species and silicates and alumino-silicates as ''non-aggressive'' species are present in significant amounts. Local water chemistry parameters were evaluated using the MULTEQ Code. SCC experiments were carried out by rising displacement tests ar 275 deg C in an environment simulating the crevice conditions. Crack growth rate and K_I_S8C_C were determined for the environment where contents of some species were from 10"2 to 10"4 times higher than in blowdowns. (authors)

Energy Technology Data Exchange (ETDEWEB)

This article reviews briefly a range of the latest monitoring and controlling equipment for use in coal mines. This includes pressure transmitters, shale/coal discriminator, nucleonic bunker level indicator, automatic steering and monitoring system, oscilloscope/multimeter, and microprocessor based digital display controllers. 1 fig.

Energy Technology Data Exchange (ETDEWEB)

A magnetic tape consisting of oil-shale Fischer assay data for selected well cores in the Piceance Creek Basin was prepared as a supplement to NTIS tape PB-230 607/AS. Both tapes serve as a data base for calculating oil-shale resources (Pitman, 1981). The tape is in standard IBM format and has the following specifications: EBCDIC (IBM standard), card-image, blocksize 1720 (blocked 20 to 1), record length 86, odd parity, 1,600 bpi, 9-track, no label tape. Each data file on the tape consists of records containing oil-shale analyses for one well core. The first record in a data file consists of a well-core identifier which is a three-digit number preceded by the character 'C'. The second record contains the well name and location, and the remaining records contain Fischer assay data.

Energy Technology Data Exchange (ETDEWEB)

Atmospheric transport represents one of the critically important pathways for the distribution of pollutants from any oil shale operation. Our experience in studying eastern and western shale resources and operation suggest many common features regarding the atmospheric domain, but also many significant differences. Any issue of atmospheric transport and dispersion can be broken down into major elements: source factors which include the spatial and temporal distribution of pollutant sources as well as their chemical and physical characteristics, boundary conditions which include the character of the underlying surface as a lower boundary and the large scale meteorological circulations as an ''upper'' boundary; and meteorological structure is the resulting wind, temperature, moisture, and turbulence environment in the volume of air occupied by emitted material in an atmosphere subjected to the boundary ...

Energy Technology Data Exchange (ETDEWEB)

Over the past few years, the development of domestic oil shale resources has regained significant attention. High oil prices, emerging recovery technologies, increasing world demand for liquid hydrocarbons, and the continued decline in United States conventional oil production has contributed to this interest. Several initiatives have been undertaken by the United States federal government and the private sector to encourage the development of a domestic oil shale industry. The United States has nearly 2.0 trillion barrels of oil shale resources across the eastern and western states. However, the development of this massive resource is constrained by a number of key factors, such as resource access, technology, economics, infrastructure and environmental and regulatory issues. In order to review emerging oil shale technologies from 23 companies and identify options to accelerate the development of this ...

Science.gov (United States)

An evaluation of eastern shale oil as an asphalt additive to reduce oxidative age hardening and moisture susceptibility is being conducted. An eastern shale oil residue having a viscosity of 1.30 Pa`s at 60{degrees}C (140{degrees}F) was blended with three different petroleum-derived asphalts that are known to be very susceptible to oxidative aging. In addition, blends of the eastern shale oil residue and the petroleum-derived asphalts are being coated onto three different aggregates that are known to be susceptible to water stripping. The oxidative age hardening portion of this study is not complete at this time. To date, information has been obtained on the unaged samples and two of the aged petroleum-derived asphalts (AAD-1 and AAK-1). When complete, this data will include rheological data on the unaged, RTFO-aged, and the RTFO/PAV-aged samples and infrared data on the unaged and RTFO/PAV-aged samples. With respect to the ...

Energy Technology Data Exchange (ETDEWEB)

Late plagiogranite bodies in the Semail ophiolite have been previously suggested to represent late stage fractionates within an episodic spreading center magma chamber or the roots of seamount chains. Field and lab observations suggest that these late silicic magma chambers represent zones of repeated injection by dikes of intermediate to mafic composition. Multiple generations of intrusion, partial resorption and reintrusion are preserved in the plagiogranite as 1) relict phantom xenoliths, 2) angular xenoliths with quartz-rich margins, 3) deformed fine-grained dikes with distinct chilled margins, and 4) planes of rectangular blocks with cuspate margins or ellipsoids of similar fine grained mafic materials. The blocks and ellipsoids are actually dismembered mafic dikes that chilled by intruding a cooler silicic liquid and were either thermally fractured or pinched out. All of the dikes are hydrothermally altered to assemblages including amph., ...

Energy Technology Data Exchange (ETDEWEB)

This paper investigates the spectral characteristics of three-dimensionally porous carbon dioxide indicators based on a porous silicate glass and phenolphthalein. The absorption spectra of the original solutions of phenolphthalein in alkaline and acid solutions are shown. The solutions were acidified by bubbling CO/sub 2/ through an alkaline phenolphthalein solution. The authors have succeeded in producing a reversible colorimetric adsorption indicator for carbon dioxide which after proper calibration enables the CO/sub 2/ content of an atmosphere to be estimated quantitatively.

Energy Technology Data Exchange (ETDEWEB)

The article presents the comparative bench testing results of a naturally aspirated four stroke, four cylinder, water cooled, direct injection Diesel engine when running on shale oil that has been treated with multi-functional fuel additives. The purpose of the research is to evaluate the effectiveness of the fuel additives Marisol FT (Sweden) and SO-2E (Estonia) as well as to verify their ability to increase energy conversion and reduce brake specific fuel consumption, contamination and smoke opacity of the exhausts when fuelling the Diesel engine with shale oil. Test results show that application of these additives could be a very efficient means to improve diesel engine performance on shale oil, especially when operating at the light load range. The brake specific fuel consumption at light loads and speeds of 1400-2000 min{sup -1} reduces by 18.3-11.0% due to the application of the Marisol FT. The additive SO-2E proves ...

Energy Technology Data Exchange (ETDEWEB)

Timing and geometry of Maastrichtian third-order sequences and systems tracts of south-central Wyoming were mostly controlled by rapid basin subsidence resulting from thrust loading of foreland basin crust. The basement of the Red Desert/Washakie basin was affected by thrusting in the Sevier belt to the west and by thrusting along the edge of the Wind River Mountains and Granite Mountains. A transgressive systems tract consists of the youngest Ericson Formation above a regional unconformity, backstepping Almond Formation nearshore and nonmarine facies, and shelfal mudstones of the lower Lewis Shale. Regionally, the onset of transgression is younger from east to west, beginning at 71.5 Ma in eastern Wyoming and at 70.5-71 Ma in south-central Wyoming. The transgression culminated in a condensed shale section evident on gamma-ray logs that occurs throughout the basin. Above the gamma-ray zone, the highstand systems tract of the middle and upper ...

Energy Technology Data Exchange (ETDEWEB)

The major problem plaguing the synfuels industry is the financing of large capital requirements in a technologically unproven field. This is exemplified by the 2 to 3 billion dollar investment required by oil shale development. Despite an unquestionable resource which is well characterized and a wealth of information from processes which have undergone extensive pilot development work, financing of a project is difficult because of the risk. In recent studies on a worldwide basis as a background for evaluating the Cottonwood Wash project in the Uinta Basin, Utah, the concept of small scale or modular development of this type of resource can lead to acceptable economics with a substantially higher probability of actual completion. This study discusses Uinta Basin oil shale resources and current developments and evaluates the economics of small scale or modular development for the Cottonwood Wash project processes. This evaluation shows the ...

Energy Technology Data Exchange (ETDEWEB)

Factors important in choosing between process concepts were mechanical complexity and amenability to scale-up studies. The culmination of this work was a process concept known as Staged Turbulent Bed Retorting Process (STB), which has now been tested in pilot plants. Operating conditions are described. The environment in the retort section can be described as a staged, moving bed of particles, in which a portion of the particles are fluidized at gas velocities well below minimum fluidization velocity of many of the particles. Research and engineering evaluations have established that the STB provides prospects for the responsible development of oil shale resources on a commercial scale. A 320 ton/d semiworks unit, the next technological step, will be commissioned shortly. This unit will be large enough to provide scale-up data for design of modules and to demonstrate the entire process, generating data needed to optimize, design, and construct commercial oil ...

Energy Technology Data Exchange (ETDEWEB)

Many countries which do not produce oil are rich with other sources of energy that are not fully utilised, such as tar sand, oil shale and olive cake. Limited previous work was done on producing carbonaceous matter and separating volatile matter from combinations of tar sand, oil shale and olive cake. In this study, a process is designed and tested to produce carbonaceous matter from combinations of three materials mentioned above. Results indicate that the process is successful in producing carbonaceous matter. The minimum temperatures to achieve complete carbonisation was found to be 500degC for a minimum heating time of 1.5h. Carbonised materials were tested for their calorific values, which indicated a successful carbonisation process. The proposed process can be scaled up and automated, and is expected to be economically feasible. Moreover, the process allows for control of unwanted exiting polluting gases and volatile matter and therefore ...

International Nuclear Information System (INIS)

Hydrolysis kinetics of the lead silicate glass (LSG) with 40 mol% PbO in 0.5 N HNO_3 aqueous acid solution was investigated. The surface morphology and the gel layer thickness were studied by scanning electron microscopy (SEM) micrographs. Energy dispersive X-ray spectroscopy (EDS) and inductively coupled plasma spectroscopy (ICP) were used to determine the composition of the gel layer and the aqueous solution, respectively. The silicon content of the dissolution products was determined by using weight-loss data and compositions of the gel layer and the solution. The kinetic parameters were determined using the shrinking-core-model (SCM) for rate controlling step. The activation energy obtained for hydrolysis reaction was Q_c_h_e = 56.07 kJ/mole. The diffusion coefficient of the Pb ions from the gel layer was determined by using its concentration in solution and in LSG. The shrinkage of the sample and the gel layer thickness during dissolution process were ...

CERN Document Server

Laboratory characterization of Interplanetary Dust Particles (IDPs) collected in the lower stratosphere represents a concrete analysis of cosmic dust properties which played a fundamental role in the origin and evolution of Solar System. The IDPs were characterized by Field Emission Scanning Electron Microscope (FESEM) analyses and by InfraRed (IR) micro-spectroscopy. We present the FESEM images of six IDPs: three smooth grains, two porous and one a compact sphere. We also show the results of micro-IR transmission measurements on four IDPs that allowed us to identify their spectral class according to the criteria defined by Sandford and Walker. Only three of the analyzed particles show IR transmission spectra with a dominant "silicate absorption feature" so that they could be assigned to the three IR spectral classes: one has been classified as "amorphous olivine", one appears to be a mixture of "olivines" and "pyroxenes" and one belongs to the "layer-lattice ...

Energy Technology Data Exchange (ETDEWEB)

Reinforced (heterogel) silicate materials containing an amorphous and a crystalline phase are being used more and more industry. Such systems are energetically unsaturated and therefore promising for use in catalysts. The authors used two reinforced materials as supports: an aluminosilicate containing a zeolite (the cracking catalyst, tseokar) and asbestos-containing aluminosilicate. The active component was introduced by impregnation, and this was followed by heat treatment during which the chemical composition and porous structure were formed. The impregnating mixture consisted of solutions of potassium sulfate and vanadate of the required concentrations. The testing shows that reinforced heterogel systems are promising as support materials for sulfuric acid catalysts.

International Nuclear Information System (INIS)

The aim of this study is to prepare some polymeric moulds using Natural rubber latex (NRL)- portland cement composites based on a delayed-action mechanism. Factors affecting the preparation process such as concentration, mixing percentage, additives and their effects on what is regarded as a delayed-action coacervant combination was studied. The effect of Gamma-radiation on the mechanical properties of these moulds was investigated. The effect of natural aging on the prepared moulds was investigated to determine the possibility of using the prepared product in the construction field as expansion joints and cracks filling materials ...etc. The results may be summarized as follows: 1) Composites of natural rubber latex (NRL)-portland cement mould were prepared as two separate parts. The stabilized natural rubber latex (NRL) with hydroxy ethyl cellulose (HEC) as stabilizer and a delayed-action coacervant (sodium meta silicate) present in the rubber mixture was ...

Science.gov (United States)

Lecture notes (pdf) on Ceramics is part of a physics course on the properties of matter from the University of Auckland, Department of Chemical and Materials Engineering. The following topics are covered: types of chemical bonding, degree of ionic character, structure of ceramics and crystallography, interstitial sites in different crystal structures, silicate structures, glasses, glass transition temperature, glass viscosity, thermal and mechanical properties of ceramics and glasses, fracture properties of ceramics and processing of ceramic materials. Keywords: ionic bonds; covalent bonds; coordination numbers; thermal shock; grain growth; sintering; green body

Energy Technology Data Exchange (ETDEWEB)

The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. Along with the major activity of assembling the components of the 50-lb/hr retort, work was also completed in other areas this quarter. Basic studies of the cracking and coking kinetics of model compounds in a fixed bed reactor were continued. Additionally, as part of the effort to investigate niche market applications for KENTORT II-derived products, a study of the synthesis of carbon fibers from the heavy fraction of KENTORT II shale oil was initiated.

Energy Technology Data Exchange (ETDEWEB)

The effect of open pit mine motor transport with ICE on the air basin is examined using the example of shale mines and open pits of the production association ''Estonslanets''. Efficient areas of use of different types of open pit mine motor transport, diesel-trolley tracks and electric cars are determined based on technical-economic and ecologic feasibility.

Energy Technology Data Exchange (ETDEWEB)

This document contains the outline and viewgraphs used in the speech. Topics covered are: conventional oil and gas recovery; unconventional oil and gas sources; oil shale resources; conventional coal combustion; advanced fossil power systems; fluidized bed combustion; coal/oil or coal/water mixtures; and gaseous and liquid fuels from coal. (DMC)

Energy Technology Data Exchange (ETDEWEB)

This report attempts to bring together available information on the coal deposits of Antarctica and discuss factors that would be involved if these deposits were to be explored and mined. Most of the reported principal coal deposits in Antarctica lie generally within the Transantarctic Mountains: the majority are of Permian age and are present in the Victoria Group of the Beacon Supergroup. Several other deposits have been recorded in East Antarctica and in the Antarctic Peninsula, including minor occurrences of Mesozoic and Tertiary coal and carbonaceous shale.

Energy Technology Data Exchange (ETDEWEB)

The increasing scarcity of conventional crude oil resources, as well as the sharply higher prices of crude oil, will generate increased interest in heavy oil, tar sands, and oil shale as potential substitutes. For all of these unconventional oil resources, extraction will be much more difficult, time consuming, and costly than for conventional crude oil. Although the inplace resources are vast and exist in many areas including the United States, the USSR, western Europe, Canada, and Latin America, probably only a small fraction of the inplace resources will prove to be economically extractable. These unconventional oil resources are now being developed in several locations around the world, and depending upon the exact definition probably account for less than 1 percent of current world oil supplies. The major current developments include: Canadian tar sands. Heavy oil production at Yarega in the Komi Autonomous Republic in the Soviet Union. The USSR also burns ...

Energy Technology Data Exchange (ETDEWEB)

The western area of the United Stated contains three young silicic calderas, all of which contain attractive targets for scientific drilling. Of the three, the Yellowstone caldera complex is the largest, has the most intense geothermal anomalies, and is the most seismically active. On the basis of scientific objectives alone. it is easily the first choice for investigating active hydrothermal processes. This report briefly reviews what is known about the geology of Yellowstone National Park and highlights unique information that could be acquired by research drilling only in Yellowstone. However, it is not the purpose of this report to recommend specific drill sites or to put forth a specific drilling proposal. 175 refs., 9 figs., 2 tabs.

British Library Electronic Table of Contents (United Kingdom)

The pore structure of volcanic clasts is examined using measurements of porosity, permeability, and electrical properties. Permeability varies by several orders of magnitude among volcanic clasts and does not depend solely upon porosity. Electrical property measurements of saturated volcanic samples illustrate the influence of pathway tortuosity and pore shape on permeability. For equivalent eruption conditions, silicic samples show higher tortuosities, smaller vesicle sizes, and lower permeabilities than mafic samples. These differences are largely due to variations in vesiculation and crystallization history. Differences between explosive and effusive samples reflect the relative ability of bubbles to form and maintain connected pathways during bubble expansion and collapse. Isotropic sa...

Energy Technology Data Exchange (ETDEWEB)

As to all sinter variations the microradiographic analysis showed that about 86 to 90 % of the implant surface were enclosed split-free with newly formed bone 16 weeks post operation. A silicate salt addition of the test variation Ap/sub 40/KS/sub 15/ and Ap/sub 40/KS/sub 30/ did not cause a negative influence on bone regeneration. On the surface of all test implants a double layer was revealed radiologically, consisting of a 30 - 40 ..mu..m thick bone near X-ray impermeable area and an X-ray permeable area of maximum 120 ..mu..m thickness directed to the nucleus of the implant.

Energy Technology Data Exchange (ETDEWEB)

Sintered glass-ceramics have been produced using municipal incinerator solid residues and glass cullet or an inert waste, from feldspars processing, as sintering aids. The capability of three different mixtures, either previously vitrified or not, to be sintered was investigated by means of linear shrinkage, water absorption and bulk density measurements, and by X-ray diffraction analysis and scanning electron microscopy observations. Particular attention has been addressed to the study of particle size effect on the sintering process. The conclusions that can be drawn from the experimental study are that the preliminary vitrification step is essential in order to obtain a dense sintered glass-ceramic product in the 850-1050 C temperature range developing silicate crystalline phases. The optimal powder particle size that confers a good densification degree was found to be < 45 {mu}m. (orig.)

British Library Electronic Table of Contents (United Kingdom)

This study investigated the optimum polyphenol extraction conditions for two Nigerian green leafy vegetables, Vernonia amygdalina (VA) and Gongronema latifolium (GL) that are widely used for food and medicinal purposes. Seven different solvents were used to extract the total phenolic contents of the leaves; 100% acetone, 80% acetone, 50% acetone, 100% ethanol, 70% ethanol, 100% methanol and 70% methanol and their total phenolic contents were determined. The results showed that the 80% acetone was significantly (p<0.05) the most effective for polyphenol extraction from the leaves and generally the acetone-containing solvents were more effective than alcohol-containing solvents. The 80% acetone extract was fractionated on a silicic acid-packed column to give two main fractions: acetone elute...

International Nuclear Information System (INIS)

L'invention concerne un procede de triage de cristaux irradies. Ce procede non destructeur comporte l'irradiation des cristaux par un rayonnement ionisant pendant une duree et avec une intensite telles qu'il se forme des centres colores distinctifs dans les matieres contenant des ions aluminium. Les cristaux colores qui correspondent en teinte et en profondeur de couleur a des teneurs en aluminium en dehors de la teneur desiree peuvent etre separes. On peut isoler ainsi des matieres de quartz, de verre, de silicates exemptes d'aluminium dans un melange, ou bien on peut choisir des fractions de ces matieres, chacune contenant une teneur uniforme en aluminium.

Energy Technology Data Exchange (ETDEWEB)

This study reviews past assessments of world oil, natural gas, and oil-shale resources. It identifies the methods used in making these assessments (historical statistics, geological analogy, engineering, and probabilistic), the geographical coverage, the time horizons, and the major assumptions about such factors as discovery rates, and recovery factor. The period covered extends from the end of World War II to the end of 1980. Conclusions are presented on the current state of knowledge and understanding concerning each of these three hydrocarbon resources. Regarding world oil resources, an assumed consensus on 2000 billion barrels ultimately recoverable is, in fact, only weakly supported. Close examination of its component parts reveals widespread disagreement. World natural gas resources are even less well understood. And it is premature to venture a meaningful assessment of world oil-shale resources. Thus, our knowledge and scientific ...

Energy Technology Data Exchange (ETDEWEB)

The geology and resources of the lower Yellow Creek area, an area at the northwestern margin of the Piceance Creek basin comprising of four 7.5-minute quadrangles, are described. Subsurface face rocks penetrated by drill holes range in age from Pennsylvania to Cretaceous. Measured sections show the Mancos Shale and the Castlegate Sandstone, Iles Formation, and Williams Fork Formation of the Mesaverde Group of Late Cretaceous age and the Fort Union, Wasatch, Green River, and Uinta formations of Tertiary age. Surficial deposits of Quaternary age include terrace gravels, alluvium, and landslides. Fold axes and faults in the area trend northwesterly. The southern part of the area contains major oil-shale resources. Coal-bearing zones in the Williams Fork and Iles formations contain considerable coal. The coal-resources potential is limited, however, by nonpersistence of the thicker coal beds. Small amounts of gas have been produced from shallow, ...

Energy Technology Data Exchange (ETDEWEB)

An evaluation of eastern shale oil (ESO) residue as an asphalt additive to reduce oxidative age-hardening and moisture susceptibility was conducted. The ESO residue, having a viscosity of 23.9 Pa{sm_bullet}s at 60{degrees}C (140{degrees}F), was blended with three different petroleum-derived asphalts, AAD-1, AAK-1, and AAM-1, that are known to be very susceptible to oxidative aging. Rheological and infrared analyses of the unaged and aged asphalts and the blends were then conducted to evaluate oxidative age-hardening. In addition, the petroleum-derived asphalts and the blends were coated onto three different aggregates, Lithonia granite (RA), a low-absorption limestone (RD), and a silicious Gulf Coast gravel (RL), and compacted into briquets. Successive freeze-thaw cycling was then conducted to evaluate the moisture susceptibility of the prepared briquets. The abbreviations used above for the asphalts and the aggregates are part of the Strategic Highway Research ...

Energy Technology Data Exchange (ETDEWEB)

Petrographic and geochemical characteristics of the Pipe Creek Jr. paragenesis record the stratigraphic and burial evolution of the cratonic Silurian platform of Indiana during Late Silurian to Pennsylvanian. A variety of several diagenetic fluids acting over geological time affected the reef. The paragenetic sequence is as follows: (1) precipitation of turbid, fibrous, blotchy cathodoluminescent (CL) cement; (2) dolomitization of mud-rich facies; (3) precipitation of clear, zoned CL equant calcite cements; (4) fracturing and karst formation, partially filled by geopetal silt and sandstone; (5) precipitation of clear, dull CL, ferroan to nonferroan equant calcite cement, ferroan dolomite overgrowth and equant dolomite cement in moldic porosity, caves and fractures; (6) microdissolution and hydrocarbon emplacement; and (7) stylolitization. The New Albany Shale was both the hydrocarbon source and top seal to the fossil Pipe Creek Jr. oil field with original oil in ...

Energy Technology Data Exchange (ETDEWEB)

This document provides information and presents data on the energy situation in many regions of Canada. The first part deals with the petroleum and the bitumen shales of Alberta (reserves, exploitation and production, environmental impacts), the second part discusses with the hydroelectricity choice of Quebec and the 2004 crisis. The nuclear situation of Ontario is presented in the third part (nuclear park, programs, uranium reserves, research and development on Candu reactors), while the fourth part deals with the renewable energies (wind power and biomass). The canadian situation facing the Kyoto protocol is discussed in the last part. (A.L.B.)

Energy Technology Data Exchange (ETDEWEB)

The Coalspur Formation is a continental succession of interbedded mudstone, siltstone and fine grained sandstone with subordinate coarser grained sandstone layers and channel lag deposits. Chert-pebble conglomerate (the Entrance conglomerate) occurs at the base of the formation, and coal beds interbedded with coaly shale and numerous thin bentonites occur in the upper part of the formation. An economically significant amount of high-quality thermal coal occurs within the upper, Paleocene part of the formation named the Coalspur coal zone. Coal from this zone, also known as the Coal Valley coal zone is being exploited in the Coal Valley Mine. 17 refs., 4 figs.

Energy Technology Data Exchange (ETDEWEB)

This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance ...

Science.gov (United States)

Synthetic fuels differ in the nature and order of magnitude of the environmental impacts associated with their production. Some types pose much more intractable problems, with oil shale leading the list. Perceptions of the difficulty of these environmental problems will continue to shift over time as more research and experimentation is done. It is critical that the development of synthetic fuels move slowly and deliberately so as not to get ahead of researched solutions nor to create environmental burdens that outweigh the social benefits of increased energy production. The Synthetic Fuels Corporation is taking the opposite approach in dispensing funds to all takers. 65 references.

British Library Electronic Table of Contents (United Kingdom)

Uranium has varying degrees of oxidation (+4 and +6) and is responsive to changes in the redox potential of the environment. It is deposited at the reduction barrier with the participation of biota and at the sorption barrier under oxidative conditions. Iron (hydr)oxides are the strongest sorbents of uranium. Uranium, being an element of medium biological absorption, can accumulate (relative to thorium) in the humus horizons of some soils. The high content of uranium in uncontaminated soils is most frequently inherited from the parent rocks in the regions of positive U anomalies: in the soils developed on oil shales and in the marginal zone of bogs at the reduction barrier. The development of nuclear and coal-fired power engineering resulted in the environmental contamination with uranium....

Energy Technology Data Exchange (ETDEWEB)

Geologic sequestration represents a promising strategy for isolating CO{sub 2} waste streams from the atmosphere. Successful implementation of this approach hinges on our ability to predict the relative effectiveness of subsurface CO{sub 2} migration and sequestration as a function of key target-formation and cap-rock properties, which will enable us to identify optimal sites and evaluate their long-term isolation performance. Quantifying this functional relationship requires a modeling capability that explicitly couples multiphase flow and kinetically controlled geochemical processes. We have developed a unique computational package that meets these criteria, and used it to model CO{sub 2} injection at Statoil's North-Sea Sleipner facility, the world's first saline-aquifer storage site. The package integrates a state-of-the-art reactive transport simulator (NUFT) with supporting geochemical software and databases (SUPCRT92). In our Sleipner study, we have ...

International Nuclear Information System (INIS)

The principal types of uranium deposits in Ontario are carbonatites and fenites, alkalic volcanic rocks, pegiatites, calc-silicate rocks, pyritic quartz-pebble conglomerates, polymictic conglomerates and some pelitic rocks, and various 'pitchblende' deposits including late Precambrian unconformities, possibly late Precambrian diabase dikes, and other unconformities: carbonates, sandstones, lignites, and semi-pelitic rocks of middle and upper Precambrian age. Only red unzoned pegmatite and the pyritic quartz-pebble conglomerate have supported production. Ontario reasonably assured and estimated resources in the economic and subeconomic categories in 1977 amounted to 553 000 tonnes U, and 1977 production was 4000 tonnes U. Measured, indicated, and inferred resources in the Elliot Lake - Agnew Lake area are at least 400 000 tonnes U. The latter deposits are also a significant thorium resource. Geological features reflecting major changes in physics and chemistry are ...

International Nuclear Information System (INIS)

Hybrid organic-inorganic coatings with phosphonate functionalities have been synthesized and evaluated as prospective surface treatments for magnesium materials. These coatings have been processed via a sol-gel route by hydrolysis and condensation of a mixture of diethylphosphonatoethyltriethoxy-silane and tetraethoxy-silane with variable molar ratios. The coatings morphology and the surface chemistry at the coating/substrate interface have been characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, "3"1P nuclear magnetic resonance spectroscopy, and time-of-flight secondary ion mass spectrometry. The corrosion protection performance of the coatings deposited on magnesium alloy AZ31B has been examined by a group of electrochemical techniques including potentiodynamic polarization and electrochemical impedance spectroscopy. In addition, a scanning Kelvin probe technique has been used to investigate interfacial properties of the coatings. The improved ...

Energy Technology Data Exchange (ETDEWEB)

The present investigation deals with the fabrication of liquid petroleum gas (LPG) sensor based on semiconducting oxide SnO{sub 2}. The gas sensor elements have been prepared by conventional solid state route. Addition of noble metal sensitizer, palladium and grain growth inhibitor, aluminum silicate to the base material SnO{sub 2}, not only improved the sensitivity towards LPG but also the selectivity in the presence of CO and CH{sub 4} gases. Out of various sensor compositions, SnO{sub 2}:Al{sub 2}Si{sub 2}O{sub 7} (35 wt.%):Pd (1.5 wt.%) sintered at 800 C for 5 h has shown high sensitivity (0.97) towards LPG at an operating temperature of 350 C. Different characterization techniques have been employed, such as differential thermal analysis (DTA), surface area analyzer, X-ray diffraction (XRD), to study the formation of SnO{sub 2}, surface area and crystallite size, respectively. The results suggested the possibility of utilizing the sensor element for the ...

CERN Document Server

This paper presents diffraction-limited 1-18 micron images of the young quadruple star system HD 98800 obtained with the W. M. Keck 10-m telescopes using speckle and adaptive optics imaging at near-IR wavelengths and direct imaging at mid-IR wavelengths. The two components of the visual binary, A and B, both themselves spectroscopic binaries, were separable at all wavelengths, allowing us to determine their stellar and circumstellar properties. Combining these observations with spectroscopic data from the literature, we derive an age of 10 Myr, masses of 0.93 and 0.64 M_sun and an inclination angle of 58 deg for the spectroscopic components of HD 98800 B, and an age of 10 Myr and a mass of 1.1 M_sun for HD 98800 Aa. Our data confirm that the large mid-IR excess is entirely associated with HD 98800 B. This excess exhibits a black body temperature of 150 K and a strong 10 micron silicate emission feature. The theoretical equilibrium radius of large, perfectly ...

Energy Technology Data Exchange (ETDEWEB)

For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is oxidized preferentially, and a portion with low reactivity remains finally. Minerals in coal are known to accelerate the gasification. However, their catalytic effect is related with chemical ...

Energy Technology Data Exchange (ETDEWEB)

The finest particle size fractions ({le} 25 {mu}m) in four fly ash samples from fluidised bed combustion of three biomass based fuels and a municipal solid waste fuel were size separated using a centrifugal SPLITT fractionation cell. The ashes were separated into different size fractions and the cadmium concentration, partition and speciation in each separated fraction were then investigated in relation to their possible leaching. The fractionation was evaluated by environmental scanning electron microscopy, which also provided indications of the associations between Cd and other main elements on the particles through the use of X-ray fluorescence mapping. The total concentration of Cd in each fraction was determined by AAS analysis which showed different dependence on the ash particle size in the case of biomass or waste fuels. In addition, the speciation of Cd in each fraction, investigated by sequential chemical extractions and X-ray powder diffraction analysis, showed Cd to be ...

Science.gov (United States)

Feasibility of depositing continuous films of nano-porous alumino-silicates, primarily zeolites and MCM-41, on metallic and non-metallic substrates was examined with an aim to develop membranes for separation of gaseous mixtures and also for application as hydrogen storage material. Mesoporous silica was deposited in-side the pores of these nano-porous disks with an aim to develop membranes for selective separations. Our study involves supported zeolite film growth on substrates using in-situ hydrothermal synthesis. Faujasite, Silicalite and Mesoporous silica have been grown on various metallic and non-metallic supports. Metallic substrates used for film growth included anodized titanium, sodium hydroxide treated Titanium, Anodized aluminum, and sintered copper. A non-metallic substrate used was nano-porous aluminum oxide. Zeolite film growth was characterized using Scanning Electron Microscope (AMRAY 1820) and High Resolution Transmission electron microscope. ...

Energy Technology Data Exchange (ETDEWEB)

In the early 1980s, a program was begun to evaluate the oil shale resources of the Albert Formation by undertaking a geological lithofacies study of the Albert strata in the Moncton Subbasin of southeastern New Brunswick. Most rock exposures of the Albert were examined from 1982-84 and additional field work was carried out in the summers of 1989 and 1990. In January 1989, 1,900 km of Vibroseis seismic reflection profiles shot from 1981-84 by Chevron Canada Resources Ltd. in the Moncton and Sackville subbasins became publicly available. This report gives the results of the geological investigations on the Albert Formation in the southeastern Moncton Subbasin and the integration of interpreted seismic reflection profiles to help resolve some of the geological problems encountered.

International Nuclear Information System (INIS)

This report summarizes the results of a research programme which involves the development of a laboratory experimental facility for the simulation and study of hydro-thermo-mechanical processes in saturated geomaterials with low permeability. The experimentation involves a synthetic cement based porous material made of cement grout which possesses permeabilities in the range of dense unfractured sandstones or shale. Specially manufactured pore-pressure transducers were installed within the cylindrical block at locations adjacent to a plane free boundary. The block was saturated with the periodic application of a vacuum. In its saturated state the plane boundary of the block was subjected to heating via a circular heater the temperature of which was maintained constant. The resulting pore pressure generation along with temperature at these locations was monitored continuously. The results of a series of experiments are documented and further extensions to the ...

Energy Technology Data Exchange (ETDEWEB)

The Oligocene Kishenehn Formation of northwest Montana and southeast British Columbia consists of fluvial and lacustrine sediments (marlstones, lignites and oil shales) deposited in an elongate, intermontane half-graben. The petroleum source rock potential and steroidal hydrocarbon distribution of selected shales of the Kishenehn Formation were examined. Several steroidal hydrocarbon series were documented, including 4-desmethylsteranes, 4-methylsteranes, sterenes, diasterenes, spirosterenes, C-ring monoaromatic steroids and B-ring monoaromatic anthrasteroids. Non-steroid hydrocarbons present include hopenes, ..beta beta..-hopanes, moretanes, perylene, botryococcane, a series of alkylcyclohexanes, and a fused-ring aromatic tentatively identified as a tetrahydrochrysene. Source rock analysis indicates that the Kishenehn Formation possesses excellent petroleum source potential. Conventional thermal maturity parameters, as well as maturity ...

Energy Technology Data Exchange (ETDEWEB)

Recent work on the St. Louis Limestone in southwestern Kansas has demonstrated that these units contain a significant eolian facies component (up to 80-90% of total unit thickness). Reservoir intervals within the St. Louis are confined to relatively thin subtidal grainstones that, in turn, are capped by a muddy carbonate and shale facies. Critical to exploration and development of these grain-shoal reservoirs is an understanding of their spatial and stratigraphic distribution. Core through the St. Louis and St. Genevieve limestones has been examined and features have been recognized at the top of the eolianites. These surfaces are interpreted as long-term exposure surfaces. The contact between the subtidal grainstone shoals and the overlying muddy carbonate and shale facies is relatively sharp and is interpreted as representing a flooding surface separating shoal from muddy-open shelf facies. In the St. Louis Limestone, the subtidal carbonate ...

Energy Technology Data Exchange (ETDEWEB)

The aim of the thesis is to validate concepts used in hydrocarbon generation and migration models; the model considered is the Temispack model developed by IFP, and the validation is based on the investigation of the thermal and hydraulic evolution in various sedimentary basins. It is shown that, in general, the thermal history of sediments is influenced by external processes (sedimentation rates, lithology, climate changes, regional-scale groundwater circulations) which frequently overprint internal processes (variations of crustal/mantle heat flow). It is found that external processes can frequently explain past thermal events that were erroneously attributed to internal causes (tectonic-thermal events). The origin of over-pressures in young basins with high sedimentation rates is shown to be generally related to compaction disequilibrium. Shale permeability values calibrated against overpressure profiles are consistent with experimental constraints. Compaction ...

Energy Technology Data Exchange (ETDEWEB)

Estonia is rich in such renewable energy sources like wood, peat and wind. Wind energy potential is very high (up to 7 TWh) due to its geographical location. Wind potential could be efficiently used particularly on the western coast and on islands. Wider use of renewable energy sources would allow significant cutting of GHG emissions. Wind energy yield reaches up to 9000 MWh in West-Estonian Archipelago, 4000-8000 MWh in other coastal regions and up to 4000 MWh in inland areas per 2 MW wind turbine. In Estonian coastal regions (20 km wide zone along the 3800 km long coastline) there is 114 000 ha (7.9% of total area) open fields that are fully suitable for harnessing wind energy. Use of wind energy has been hindered so far mainly by a systematic under-capacity operation of two large oil shale power plants in Narva and weak power network system in coastal regions (orig.)

Energy Technology Data Exchange (ETDEWEB)

The article reports the reserves of fossil resources. The world's total coal reserves and recoverable coal reserves the estimated at 8,400 billion tons and 728 billion tons, respectively. For oil, the verified reserves and reserve production ratio in the Middle East are 420.9 billion bbl and about 100 years, respectively. They are 141 billion bbl and about 20 years for North and South America, 81 billion bbl and about 18 years for the Soviet Union, 10.8 billion bbl and 34 years for China, 9.8 billion bbl and 26 years for Western Europe and 38.7 billion bbl and 42 years for Africa. The total reserves of natural gas in the world were shown to be 3,981.6 x 10/sup 12/ cf at the World Petroleum Congress in 1987. The amount of recoverable primitive oil sand resources in the world is 436 billion bbl, of which as much as about 70 percent is in Canada. The amount of ultimate primitive oil shale resources is 3,281 billion bbl, of which 2,002.4 billion bbl is in ...

International Nuclear Information System (INIS)

The Lander Quadrangle, Wyoming, was evaluated to a depth of 1500 m to identify environments and delineate areas that exhibit characteristics favorable for the the occurrence of uranium deposits. The evaluation used criteria established for the National Uranium Resources Evaluation program. The methods of surface investigations included evaluation of aerial radiometric and hydrogeochemical stream-sediment reconnaissance data, verification of some reported uranium occurrences, and general field geology with rock, water, and sediment sampling. The subsurface evaluation was accomplished through the use of 230 various oil-well logs. The results of this investigation identified three environments favorable for sandstone uranium deposits in Eocene fluvial sediments. These environments are within the Battle Spring and upper Fort Union Formations of the northern Great Divide Basin and within the Wind River and the Wagon Bed Formations of the southwest Wind River Basin. Eight other formations ...

British Library Electronic Table of Contents (United Kingdom)

The second and third member of the Qingshankou Formation recovered by CCSD-SK-Is borehole (China Cretaceous Continental Scientific Drilling-SongkeI-the south borehole) is 415.61 m long and 100% of cores recovery. The age of the member corresponds approximately to the Coniacian. The sequence and process of lithology-lithofacies and cyclic stratigraphy were revealed by a detailed core description. 12 rock types and 2 kinds of sedimentary subfacies including semi-deep lake and shallow lake were recognized from the drilling core of the second and third member of the Qingshankou Formation. 10 sedimentary microfacies are present, including dolomite, marl, limestone, oil shale, semi-deep lake turbidite, volcanic ash, seismite, semi-deep lake mudstone, shallow lake mudstone, and shallow lake turbi...

Energy Technology Data Exchange (ETDEWEB)

This document describes research performed at the Morgantown Energy Technology Center in the areas of oil and gas, advanced systems application, environmental technologies, applied energy science and remediation. The following subtasks are described: CROW{sup TM} Process Modeling, Development of a Portable Data Acquisition System and Coalbed Methane Simulator, Tank Bottom Waste Processing using the TaBoRR{sup TM} Process, Process Support and Development, Eastern Shale Oil Residue as an Asphalt Additive, Solid Waste Management, Remediation of Contaminated Soils, The Syn-Ag{sup TM} Process: Coal Combustion Ash Management Option, the Maxi-Acid{sup TM} Process: In- sit Amelioration of Acid Mine Drainage, Spill Test Facility Database, Heavy Oil/Plastics Co-Processing, Fossil Fuel and Hydrocarbon Conversion Using Hydrogen-Rich Plasmas, and North Site Remediation.

International Nuclear Information System (INIS)

Environmental factors, phytoplankton biomass (Chl a) and primary production of two water areas in Daya Bay (Dapeng'ao Bay and Aotou Bay) were investigated during the transition period from spring to summer. Chl a ranged from 3.20 to 13.62 and 13.43 to 26.49 mg m"-"3 in Dapeng'ao Bay and Aotou Bay respectively, if data obtained during red tides are excluded. Primary production varied between 239.7 and 1001.4 mgC m"-"2 d"-"1 in Dapeng'ao Bay. The regional distribution of Chl a and primary production were mostly consistent from spring to summer in both bays. Seasonal transition characters have been found in Daya Bay from spring to summer, including high values of DO, nitrate and silicate. Size structures of phytoplankton and its primary production do not change very much from spring to summer, with micro-phytoplankton dominating and contributing about 50% of the whole. In Daya Bay, phytoplankton is limited by nitrogen in spring, and by phosphate in summer. Artificial ...

Energy Technology Data Exchange (ETDEWEB)

A decade ago, Lovelock and Whitfield raised the question of how much longer the biosphere can survive on Earth. They pointed out that, despite the current fossil-fuel induced increase in the atmospheric CO[sub 2] concentration, the long-term trend should be in the opposite direction: as increased solar luminosity warms the Earth, silicate rocks should weather more readily, causing atmospheric CO[sub 2] to decrease. In their model, atmospheric CO[sub 2] falls below the critical level for C3 photosynthesis, 150 parts per million (p.p.m.), in only 100 Myr, and this is assumed to mark the demise of the biosphere as a whole. Here, this problem is re-examined using a more elaborate model that includes a more accurate treatment of the greenhouse effect of CO[sub 2] a biologically mediated weathering parameterization, and the realization that C4 photosynthesis can persist to much lower concentrations of atmospheric CO[sub 2] ([lt]10 p.p.m.). It was found that a ...

Energy Technology Data Exchange (ETDEWEB)

An outcrop-based study combining detailed lithofacies analysis with high-resolution sequence stratigraphy in the Paradox Basin, southwestern United States. has shown that complex lateral and vertical facies variations occur in relatively consistent and predictable patterns. Large-scale facies shifts of several kilometers occur across major sequence boundaries whereas small-scale lateral and vertical variations develop from stacking of individual cycles. Understanding of vertical stacking patterns and lateral distribution of facies in outcrop can be directly applied to both three-dimensional distribution of reservoir facies in the subsurface as well as the evaluation of heterogeneity within individual reservoirs. The Desert Creek and Ismay intervals of the Paradox Formation (Pennsylvanian) exposed along the San Juan River in southeastern Utah are characterized by high-frequency cyclic repetition of carbonate and siliciclastic facies controlled primarily by 4th and 5th-order changes in ...

Energy Technology Data Exchange (ETDEWEB)

This presentation outlined the energy policy in the United States and its impact on frontier development in Alaska, deepwater offshore fields and in the western oil shale resources. The energy strategy focuses on technologies that increase domestic production from existing resources as well as technologies that create new sources of energy. In addition to emphasizing the cooperation between Canada and the United States in ensuring energy supply security and stability, this paper discussed the importance of overall bilateral trade between the 2 countries. It was noted that Canada is the United State's most secure and reliable energy partner and is the number 1 supplier of imported oil, natural gas, electricity and uranium. The Bush administration's energy policy is based on the mandate to supply stable, reliable, secure, affordable and environmentally sound energy for the country's growing economy. The energy strategy focuses on increasing ...

Energy Technology Data Exchange (ETDEWEB)

As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBRS) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the Clean Air Act Amendment (CAAA) of 1995. Solids motion is also the key to ...

International Nuclear Information System (INIS)

A preliminary geologic investigation was conducted to determine if Triassic sedimentary rocks of the Sanford basin and Colon cross structure in North Carolina are favorable hosts for uranium deposits. Rocks of adjacent Carolina slate belt were also examined as a potential source of uranium. On the basis of favorability criteria for sandstone-type uranium deposits, and geologic and geophysical investigations of the study area, the most favorable sites for further investigation are (1) at the contacts between the Pekin and Cumnock and between the Pekin and Sanford Formations near the Colon cross structure and (2) at the base of the Jonesboro fault, which lies below the Sanford Formation, northwest of Sanford. The highly weathered granites southeast of the Jonesboro fault were a source of the detritus deposited on the cross structure and may have been a primary source of uranium. Uranium leached from the coarse sediment (Pekin Formation) of the cross structure may have been transported ...

Energy Technology Data Exchange (ETDEWEB)

The 66 fields discovered since the 1960s in the northern West Siberian basin contain at least 22 trillion m/sup 3/ (777 tcf) of proved gas, almost one-third of the world's reserves. Half of these fields are giants (> 85 billion m/sup 3/ or 3000 bcf of reserves). These include the largest and second-largest gas fields in the world-Urengoy (8.099 trillion m/sup 3/ or 286 tcf of gas) and Yamburg (4.81 trillion m/sup 3/ or 170 tcf of gas)-as well as most of the other ten largest gas fields in the world. The West Siberian basin occupies a 3.4-million km/sup 2/ (1.31-million mi/sup 2/) arctic lowland immediately east of the Ural Mountains, extending north under the Kara Sea. It is a composite basin, with Mesozoic-Cenozoic basin fill on top of a Paleozoic basin that overlies a crystalline Archean-Proterozoic framework. The productive zones in the northern basin are principally in the Neocomian section (at an average depth of 2800m or 9200 ft) and the Cenomanian section (at an ...

Energy Technology Data Exchange (ETDEWEB)

Outcrops of Tertiary coal-bearing units in sea cliffs of the Kenai Peninsula provide an excellent study area for volcanic ash partings in coals. Twenty mid-to late-Miocene, 50-cm to 3-m thick coal seams exposed in the sea cliffs about 10 km west of Homer contain an average of 10 volcanic ash or lapilli tuff partings each. The bedding relationships of the coal with any one parting cannot be predicted, and the contacts of the partings with the coal range from very sharp to predominantly gradational. These bedding relationships provide clues about the surface on which the ashes fell and on which the coal was accumulating. For example, some ashes fell in standing water, others on irregular subaerial surfaces. The partings are in various stages of alteration to kaolinite and bentonite, and vary in thickness from a few millimeters to about 10 cm. The consistency and texture of the partings depend on the degree of alteration; the less altered partings display visible pumice fragments and ...

Energy Technology Data Exchange (ETDEWEB)

The main objective of the pilot Coal Compilation Project is to provide coal resource maps to stimulate and support industry exploration programs, and assist government in matters of resource management. An essential feature of the program is the use of cost effective Geoscience Information System (GSIS) technology that allows the database and various thematic maps to be analyzed, updated, and displayed with complete flexibility at any scale. This report describes the main features (geology, exploration history, coal occurrences, coal quality etc.) of the study area, map sheet NTS 83F/5 (Entrance), and includes a copy of the 1:50,000 scale map produced. The study area is located in west-central Alberta and contains coal measures deposited within thick successions of sandstones, siltstones, shales and conglomerates. These coal-bearing sequences are part of the Lower Cretaceous Luscar Group, Upper Cretaceous Brazeau Formation and Paleocene Coalspur Formation. The ...

Energy Technology Data Exchange (ETDEWEB)

The Early Palaeozoic Warburton Basin underlies the gas and oil producing Cooper and Eromanga Basins. Postdepositional tectonism created high potential fracture porosities, complicating the stratigraphy and making reservoir prediction difficult. Sequence stratigraphy integrating core, cuttings, well-log, seismic and biostratigraphic data has recognized a carbonate-dominated to mixed carbonate/siliciclastic supersequence comprising several depositional sequences. Biostratigraphy based on trilobites and conodonts ensures reliable well and seismic correlations across structurally complex areas. Lithofacies interpretation indicates sedimentary environments ranging from carbonate inner shelf, peritidal, shelf edge, deep outer shelf and slope to basin. Log facies show gradually upward shallowing trends or abrupt changes indicating possible sequence boundaries. With essential depositional models and sequence analysis from well data, seismic facies suggest general reflection configurations ...

International Nuclear Information System (INIS)

The objectives of this research were to investigate the possibility of controlling the #alpha#'/#beta#' phase ratio and morphology in Sialon ceramics. These objectives have been sought by the control of the starting composition, and by post sintering heat treatment. The main emphasis has been on the production of a series of #alpha#' and (#alpha#'+#beta#') Sialon ceramics with a minimum amount of the glass phase by the pressureless sintering technique and using ytterbium (Yb) as an #alpha#' stabilising element. The Yb additions were made via the oxide or the alumino- silicate presynthesised glass; the latter was found to improve the density. The XRD analysis of the as sintered materials revealed #alpha#' to be the dominant phase with minor contributions from #beta#' sialon and/ or 12H A1N polytype. Additions of SiO_2 or #beta#-Si_3N_4 were made to various materials to assess potential mechanisms for obtaining control over the microstructural development of ...