International Nuclear Information System (INIS)

Atmospheric pressure plasma enhanced chemical vapour deposition system is built. The electrical and optical characteristics of the APPECVD system is given. The system is used to deposit conductive polymers and nano composites onto glass and metal surfaces. The morphological, optical, chemical and electrical characteristics of deposited surfaces are investigated using SEM, AFM four probe deposition purposes. The photovoltaic applications of plasma deposited polymers and nonconsumption are compared with deposited with electrochemical methods show different results. The electrical, chemical and morphological structures of the samples will be given.

International Nuclear Information System (INIS)

Iron oxide films have been deposited on Si(100) substrates by chemical vapour deposition (CVD) of iron(III) tert-butoxide ([Fe(O "tBu)_3]_2) in the temperature range 350-450 deg. C. The precursor flux and substrate temperature were varied to control the phase composition, average grain size and film thickness. The nature of substrate and deposition temperature markedly influence the morphology and iron-oxygen stoichiometry in the CVD deposits. Phase transformations in iron oxide films were achieved through precise local and periodic heating of the films by interfering laser beams. The interaction of iron oxide films with short laser pulses (Nd:YAG, 355 nm) induced partial transformation of hematite (#alpha#-Fe_2O_3) to magnetite (Fe_3O_4) or magnetite to wuestite (Fe_1_-_xO), respectively. The phase characterization and morphology of the hematite and magnetite films were ...

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Polycrystalline silicon films have been grown from Si{sub 2}H{sub 6} by low-pressure chemical vapour deposition at 800 K and in situ laser annealing (LA) on amorphous silicon seed layers deposited on a metallic Ti/Pd/Ag multilayer. The crystalline volume fraction in the seed layer was controlled by thermal annealing. According to the metal-induced crystallization effect, the presence of the metal induces a lower-temperature crystallization of silicon in the seed layers. X-ray diffraction and scanning electron microscopy data show that the formation of palladium silicides in the seed layer drives the growth of wire-like columns which are found to change morphology depending on the seed layer microstructure and LA parameters. It is suggested that superficial palladium was found to affect also the growth rate by enhancing the Si{sub 2}H{sub 6} dissociation.

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Plasma nitriding as a diffusion process is the oldest plasma-assisted process for the surface treatment of metals. Although the use of this process in industry is already well developed and established there are still several scientific questions in the basic understanding of the process and consequently some problems and limits concerning its upscaling for industrial use. Therefore it is necessary to get reproducible results for different geometries of workpieces and for different workload sizes. Correlations between different plasma and treatment parameters, especially in big plants, have to be considered. To understand the process handling using some simple but impressive models the difficulties of treating single parts or mixed workloads are explained. For profitable applications of plasma nitriding plants, some guidelines for the use and selection of a suitable process and a device are given. By the use of a pulsed d.c. power supply for plasma generation most of the industrial ...

International Nuclear Information System (INIS)

A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.)).

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Significant ion irradiation during film growth is required for the formation of cubic boron nitride (cBN) films. Meanwhile, a huge level of intrinsic stress possibly induced by the ion bombardment has been frequently reported to result in cracking and/or lack of adhesion of deposited cBN films. The present work has been performed to investigate the interfacial and/or the buffer layer structures with better matching to the cBN film by relaxation of the film stress using ion-beam-assisted deposition (IBAD). Boron nitride films have been synthesized on Si(100) wafer and tungsten carbide (WC) substrates by depositing boron vapor under simultaneous bombardment with nitrogen ions and nitrogen-argon mixture ions in the energy range of 0.5-10 keV. Cubic BN films with enhanced tribological properties have been explored by inserting a BN layer with various B/N compositions as a controlled ...

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Deposition of hard coatings may influence the mechanical properties of the bulk material and its corrosion resistance. In this work we study the hardness of the coated and the back side of 100Cr6 steel plates. Electrochemical corrosion tests were performed in O{sub 2}-saturated acetate buffer of pH 5.6 at 25degC. Chromium nitride and titanium nitride coatings prepared by different physical vapour deposition processes, such as arc, thermionic arc evaporation, magnetron sputtering and ion-beam-assisted deposition (IBAD) were compared. The results show that, for sufficient corrosion protection, chromium nitride layers have to be thicker than 500 nm. An increased nitrogen partial pressure in the evaporation chamber of the IBAD process improves the corrosion resistance significantly. The hardness of the substrates was reduced in the case of thermoionic arc evaporation only, indicating a ...

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Chromium containing amorphous hydrogenated carbon films (a-C : H/Cr) have been prepared by simultaneous rf plasma activated chemical vapour deposition of methane and magnetron sputtering of a chromium target. During deposition the substrates were heated (up to 300C) and DC biased (-200 and -600 V) in order to obtain films with high chemical stability. Constant temperature tests were performed at 250C in air with coatings deposited on silicon substrates. The degradation of the coatings was monitored by Raman spectroscopy and reflectance and transmission measurements. The main degradation mechanisms are discussed and the relevant parameters which improve the durability of the coatings are presented. Furthermore, the durability of solar selective, multilayered coatings which were deposited on copper sheets was investigated. Based on accelerated aging tests at different temperature ...

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Strains in multivalley semiconductors can destroy the strict equivalence of the valleys that is demanded by cubic symmetry. Significant changes in the properties of a semiconductor may result. A proposed implementation of quantum computing with donor atoms in silicon would suffer from alterations of the donor wave functions caused by strains that are produced by fabrication processes. Deliberately straining the silicon to an extent that removed all but one valley from participation in the lowest donor state, would prevent further changes in the wave function by strain. The strain required can be achieved with established technology for depositing silicon on SiGe alloys. (author)

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Means of intensifying heat transfer with nucleate boiling, based on boiling under constrained conditions (in slots, on a capillary-porous surface) are the most promising since a high intensity of heat transfer is ensured. In the present work we attempt to evolve the main assumptions for the physical model of the process of vapour formation under constrained conditions and to extend them to the boiling of cryogenic liquids on surfaces with a capillary-porous deposit; also, the results are given of experimental investigations of heat transfer with the boiling of nitrogen, oxygen and hydrogen at atmospheric perssures and below on capillary-porous surfaces of various metals of different structure produced by an electric arc method of gasothermal spray coating.

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The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces which are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.

British Library Electronic Table of Contents (United Kingdom)

A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500degreeC. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12wt.% Li and only 0.264wt.% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.

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International Nuclear Information System (INIS)

In this work we present the electrical characterization of non self-aligned p-channel thin film transistors fabricated by using laser doping technique for source/drain contact formation and gate oxide deposited at room temperature by Electron Cyclotron Resonance Plasma Enhanced Chemical Vapour Deposition. These techniques are suitable for a very low temperature process for TFT fabrication. The output characteristics show a current increase at high drain voltage ('kink' effect) rather moderate, if compared to self aligned polysilicon TFTs, probably due to the gradual doping profile induced by laser doping process. After bias stress at low gate voltage and high drain voltage condition a strong reduction of kink current has been observed in the output characteristics at high drain voltage, whereas minor changes has been observed in the transfer characteristics. This behaviour is similar to what observed in n-channel Gate ...

International Nuclear Information System (INIS)

The authors show that dramatically different in-plane crystallographic textures can be produced in body centered cubic (bcc) metal thin films deposited under different conditions. The orientation distribution of polycrystalline bcc thin films on amorphous substrates often has a strong (110) fiber texture, and an in-plane texture may develop when deposition takes place with an off-normal incidence flux of energetic ions or atoms. Three orientations in Nb films have been observed in which the energetic particle flux coincides with crystal channeling directions. In-plane orientations in Mo films have also been obtained in magnetron sputtering systems. The selected orientations are reviewed, and examples are given in which the in-plane orientation of Mo deposited in two similar magnetron system differs by a 90 deg C rotation. The origins of in-plane texture in rectangular magnetron sputtering systems are ...

International Nuclear Information System (INIS)

High-resolution electron microscope observations confirm the presence of small crystallites in thin TbFeCo films protected by Si_3N_4 overcoats. Selected area electron diffraction patterns in top-view projection indicate that the crystals have a face-centered-cubic structure. Microscope analysis reveals grain growth following annealing of these protected thin films at 200 degree C in vacuum, and Kerr measurements yield large reductions in coercivity relative to the room-temperature value. The typical grain size visible in top-view observations increases from about 3 nm in the as-deposited samples to about 30 nm after annealing at 200 degree C for 36 h while the static coercivity, H_c, drops by about 40%. The fcc structure of the crystals is retained after annealing.

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This work analyzes the unoptimized prototype triode-sputtered, 150 microns thick tantalum coatings deposited with a 2.5 microns niobium underlayer on the bore of a large-diameter A723 steel cylinder. The coating was deposited for wear and erosion protection by Pacific Northwest National Laboratory. The phase determination was based on X ray diffraction analysis, wavelength dispersive X ray fluorescence analysis, energy dispersive X ray analysis, and hardness and electrical resistivity measurements. Both X ray diffraction and radius-of- curvature methods were used to determine residual stresses. A locally developed high-resolution pole figure technique was used to perform texture analysis. The post-firing, debonded coating showed alpha-tantalum, preferred 110 orientation, high surface stresses, tantalum oxides, entrapped krypton sputtering gas, interstitial oxygen, and other impurities. The surface and subsurface pole figures revealed broadened ...

International Nuclear Information System (INIS)

The removal of tritiated water vapour was tested by use of a small burning apparatus and a clinoptilolite filter. It was found that decontamination factor of about 10"4 could be obtained by a clinoptilolite filter. The adsorption of HTO in the clinoptilolite is caused by the diffusion, so it is necessary that filtration velocity is maintained below 0.01 m/sec. Decontamination factor was not influence by the moisture content of a clinoptilolite and tritiated water vapour once adsorbed on a filter was hardly removed. (auth.).

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Photoelectrochemical oxidation is a potentially interesting method for destroying toxic organic materials. We have studied the photoelectrocatalytic activity of TiO{sub 2} films made by thermal oxidation of titanium, low pressure chemical vapour deposition (LPCVD), and anodisation of titanium. Two model organic compounds have been investigated for photooxidation: methyl phosphonic acid (MPA) which is a nerve gas analogue and 4-chlorophenol (4-CP) which is a chlorinated aromatic compound considered a standard for the evaluation of the TiO{sub 2} / UV processes. In addition to photoelectrochemical characterisation the films have been characterised by profilometry, XRD, AFM, photocurrent spectroscopy and Raman microscopy. Correlations have been made between the physical properties of the thin films and their catalytic activities. The most catalytic sample of thermally oxidised titanium was prepared at 400 deg C, and the presence of anatase was ...

International Nuclear Information System (INIS)

Fe_5_0Pt_5_0 nanodots dispersed in a SiO_2 film (Fe_5_0Pt_5_0 nanodot film) were formed by a self-assembled nanodot deposition (SAND) method in which Fe_5_0Pt_5_0 and SiO_2 are cosputtered in a high vacuum rf magnetron sputtering equipment. Fe_5_0Pt_5_0 pellets are laid on a SiO_2 target in a sputtering chamber to form the Fe_5_0Pt_5_0 nanodot film in the SAND method. The size and density of Fe_5_0Pt_5_0 nanodot were controlled by changing the ratio of the total area of Fe_5_0Pt_5_0 pellets to that of SiO_2 target. The Fe_5_0Pt_5_0 nanodot size decreases and its density increases when the ratio decreases. As-deposited Fe_5_0Pt_5_0 nanodots self-assembled to a face-centered-cubic phase of single-crystal structure. The Fe_5_0Pt_5_0 nanodot films were annealed to evaluate the nanodot size controllability, the magnetic anisotropy, and the thermal stability. Fully ordered L1_0 face-centered-tetragonal Fe_5_0Pt_5_0 nanodots with ...

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The aim of this work is to combine the MCFC cathode Li{sub x}Ni{sub 1-x}O properties to those of the protective coatings of LiCoO{sub 2}, Li{sub 2}TiO{sub 3} or of CeO{sub 2}, less soluble in the molten carbonates. In the cases of LiCoO{sub 2}, have been carried out by controlled potential coulometry in aqueous solution, a deposition of Co{sub 3}O{sub 4} on dense Ni. The cobalt oxide reacts rapidly in the Li{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3} medium at 650 C to give LiCoO{sub 2}, a spinel cubic phase revealed by Raman spectroscopy. (O.M.)

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In this study samples of AISI 4140 steel were pretreated by plasma nitriding and coated with two different physical vapour deposited coatings (TiN and TiAlN). A hardened AISI 4140 sample and a coated sample were also included in the investigation. To examine the influence of the nitrided zone on the performance of the coating-substrate composite, two different nitriding conditions - a conventional 25% N{sub 2} and an N{sub 2}-poor gas mixture - were used. The specimens were investigated with respect to their microhardness, surface roughness, scratch adhesion and dry sliding wear resistance. Wear tests in which the duplex-treated pins were mated to hardened ball bearing steel discs were performed in a pin-on-disc machine under dry sliding conditions. Metallography, scanning electron microscopy and profilometry were used to analyse the worn surfaces in order to determine the dominant friction and wear characteristics of the samples investigated. ...

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Si nanocrystal floating gate MOS capacitors were formed on p-Si (100) wafers by thermal plasma jet (TPJ) annealing of SiO{sub 2}/SiO{sub x} /SiO{sub 2}/Si(100) stacked structure. The chemical composition of SiO{sub x} layer was controlled by changing the SiH{sub 4}, He, and O{sub 2} gas flow ratio during plasma enhanced chemical vapour deposition. The MOS capacitors showed clear hysteresis in capacitance-voltage (CV) characteristics after TPJ annealing. The hysteresis width shows maximum value when initial composition x =1.7, which shows the maximum photoluminescence (PL) intensity. The maximum hysteresis width of 6.8 V was observed with gate voltage swept between 20 and -20 V in x = 1.7 sample. The result means 7.4 x 10{sup 12} cm{sup -2} carriers are injected to or emitted from Si nanocrystals. The duration of 1 V shift in flatband voltage was {proportional_to}0.1 ms with 20 V pulse, and charged carriers were stably maintained for ...

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Desiccants have been used in many applications to provide dehumidification. This paper describes an application of desiccants which provide both dehumidification and sensible cooling, with little or no use of conventional vapour-compression refrigeration plant. Through a parametric study, the energy consumption and costs of a desiccant cooling system are compared with those of a conventional vapour-compression refrigeration-based air-conditioning system. (author)

International Nuclear Information System (INIS)

Use of high plutonia MOX as fuel is contemplated from the point of view of rapid disposition of plutonium and economic power generation. The fuel pellets are subjected to steep thermal gradients #approx# 1700 K drop across a radius of #approx# 2.5mm. This leads to evaporation-condensation of the fuel constituents to cooler regions. Vaporization depends on fuel compositions such as Pu fraction, Oxygen-to-Metal (O/M) ratio and local temperature. Knowledge of vapour chemistry is essential in understanding the fuel behavior. The vaporization behaviour of MOX was analyzed in this work using thermochemical methods. The vapour phase consisted of nine species; O, O_2, Pu, PuO, PuO_2, U, UO, UO_2 and UO_3. Oxygen formed part of the vapour phase along with other species and oxygen potential was not controlled independently. The vapour pressures were estimated at 2000 K as a function of (O/M) for several ...

International Nuclear Information System (INIS)

Reliable and consistent characterization of the stable isotope composition of atmospheric water vapour and its temporal variability are important prerequisites to the wider application of isotope mass balance methods in atmospheric and water balance studies. A new approach is proposed which utilizes standard class-A evaporation pans, which have sufficient volume to buffer short-term transient variations in atmospheric conditions, justifying the assumption of constant kinetic isotopic fractionation effects in concert with precisely measured temperature and relative humidity to derive vapour isotopic composition. The results of the studies suggest that isotopic sampling of existing, conventionally operated class-A evaporation pans could offer a straightforward and cost-effective solution to the problem of documenting the shifting isotopic distribution in atmospheric moisture

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The possibility of studying the adsorption of acetic acid vapour on coal by the method of multiple attenuated total internal reflection by two proposed procedures has been shown.

International Nuclear Information System (INIS)

Complete text of publication follows. According to the new European regulations (Restrictions of Hazardous Substance Directive), there is an emerging demand for environmental friendly metal treatments instead on formerly used chromate conversion coating technique. The aim of the present investigations was to characterise and compare silicon containing protective thin layers on roughened galvanized steel surfaces (with average roughness of 0.7 microns), using FTIR microscopy and imaging techniques. The silicon containing coatings were produced either by Chemical Vapour Deposition (CVD) or by wet chemical treatment using liquid silane. FTIR techniques offer new possibilities in the characterisations and chemical mapping of differently coated thin films, besides SEM+EDS, AFM, nanoindentation, XPS measurements (P. Nemeth et al., Materials Science Forum, 589 (2008) 433-438). All measurements were carried out by a Varian FTS-7000 spectrometer with a ...

International Nuclear Information System (INIS)

Plasma-deposited thin films prepared at room temperature, ranging from 46 to 250 A of PdAu on #approx#45-50 A Si-oxide and Si-oxynitride films grown on Si wafers were studied. Grazing incidence X-ray diffraction, X-ray reflectivity, and XPS depth profile techniques were used to characterize the thin films. A reactive interface involving Pd- and Au-silicides is formed, linking the thin film to the Si-oxide and Si-oxynitride films: a small fraction of Pd and Au atoms from PdAu migrate into the Si substrate, first penetrating the oxide layer, and the small fraction of Si atoms from the oxide layer migrate into the PdAu film and form a silicide interlayer consisting of a reactive interface made up of mixtures of Au- and Pd-silicides interspersed within the matrix of PdAu and substrate. The concentration profiles of these silicides have a maximum at the interface with decay on both sides. The density and the face-centered cubic (fcc) lattice ...

Science.gov (United States)

... by the boron doping in most of the alloys except for Al66Mn9Zr25 + 50 ppm B alloy; permanent deformation at ultimate compressive strength is not ...

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Anaerobic treatment of olive oil mill wastewaters (COD up to 220 kg/cubic m) is feasible, and the most promising results were obtained on UASB reactors, both at laboratory and pilot scale (tank capacity 15 litres and 5 cubic m), fed on diluted waste (COD = 13-18 kg/cubic m). Volumetric loading rates ranging from 16-21.5 kg COD/cubic m/day and 70% removal efficiencies were obtained with these digesters. Start-up of UASB reactors fed on olive oil mill waste is a delicate step which still has to be fully controlled and optimized. The best results were obtained by starting with very diluted waste (COD = 5 kg/cubic m). Granulation of the sludge, as achieved in Dutch UASB digesters fed on sugar beet wastewaters, was not obtained, but, even so, the settleability of the sludge was very good. 22 references.

British Library Electronic Table of Contents (United Kingdom)

Herein, we fabricated MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers by electrospinning and dip coating method. The amount of MWCNT-OH adsorbed to the pure electrospun nylon 6,6 nanofibers was 0.056wt%. The electrical conductivity of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers was 5.24x10^-^3Scm^-^1. We also investigated the sensing properties of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers by measuring its response upon exposure to low molecular weight alcohol vapours such as methanol, ethanol, 1-propanol, and 1-butanol. The changes of the electrical resistance of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers were demonstrated on the basis of hydrogen bonds among the alcohol vapours and hydroxyl groups (-OH) on MWCNT-OH, and amide groups (-NHCO-) in nylon 6,6. The fa...

International Nuclear Information System (INIS)

The production of ozone in a negative corona discharge fed by carbon dioxide with embedded traces of oxygen and water has been studied. The presence of traces of oxygen in both pure and dry CO_2 leads to an increase in nascent ozone concentrations. In contrast, traces of water vapour (0-800 ppm) are shown to rapidly suppress ozone concentrations with the largest decreases being observed at lowest gas pressures in the discharge (300 Torr). The presence of water vapour did not considerably affect the electrical properties of negative dc corona suggesting that a chemical process is responsible for the ozone loss. We have shown that the addition of water up to a concentration of 1500 ppm has only a marginal effect on the processes of ozone formation but the catalytic cycle of ozone destruction involving OH radicals can be the reason for observed decrease in the total ozone concentration with increasing water concentration.

Science.gov (United States)

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Science.gov (United States)

... Accession Number : ADD257320. Title : Sputter Deposition of Yttrium-Oxides. Descriptive Note : Journal article,. Corporate ...

International Nuclear Information System (INIS)

Up to now, P diffusion in Ge is modeled with an effective diffusivity involving at most a quadratic dependence with the free electron concentration (n). However, recent theoretical studies suggest the existence of a triply negatively charged state for the free vacancy in germanium and experimental data indicate that the E center (PV pair) in Ge has a double acceptor state. These two facts would be consistent with a diffusivity model involving a cubic dependence with n. In this paper the validity of this approach is checked for both pure thermal diffusion (intrinsic and extrinsic) and implanted phosphorus, using either our own experiments or other data available from the literature. Although some discrepancies still exist in some cases for the redistribution of implanted P, it is shown that the introduction of this cubic dependence significantly improves the overall agreement as compared with the usual model.

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The article deals with the effects of various hazardous materials in the working environment. Some of these may be detrimental to the safety and health of the worker. The absorption of hazardous substances by the human body is discussed, as well as the effects of toxic substances. The hazardous substances are classified into the following categories: irritants, asphyxiants, anaesthetics and narcotics, carcinogens, mutagens, teratogens, systemic poisons, hazardous particulate matter and the biotransformation of toxic substances. Examples of hazardous substances include: industrial solvents, fumes and vapours, lead, mercury and uranium.

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The effective half-life based on urine bioassay results of Wolsung NPP's worker was calculated. The effective half-life for tritiated water vapour obtained was 5 {approx} 9 days. In comparison to 10 days reported for ICRP-30, it is lower than the corresponding half-life for Reference Man. Also, the half-life was calculated based on intake amount of daily water. According to this result, the metabolism was reviewed.

International Nuclear Information System (INIS)

The parameters including knot numbers, knot positions and the weights associated with the systematic errors in the cubic spline curve fitting method were discussed. The conditions of using fitting criterion were given as well.

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Some diagnostics at the National Ignition Facility (NIF), including the Gamma Reaction History (GRH) diagnostic, require multiple channels of data to achieve the required dynamic range. These channels need to be stitched together into a single time series, and they may have non-uniform and redundant time samples. We chose to apply the popular cubic smoothing spline technique to our stitching problem because we needed a general non-parametric method. We adapted one of the algorithms in the literature, by Hutchinson and deHoog, to our needs. The modified algorithm and the resulting code perform a cubic smoothing spline fit to multiple data channels with redundant time samples and missing data points. The data channels can have different, time-varying, zero-mean white noise characteristics. The method we employ automatically determines an optimal smoothing level by minimizing the Generalized Cross Validation (GCV) score. In order to automatically ...

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We investigate the formation of nanostructures in 2D strained alloys on face centered cubic (111) surfaces by means of equilibrium Monte Carlo simulations. In the framework of an off-lattice model, we consider one monolayer of two bulk-immiscible adsorbates A and B with negative and positive misfit relative to the substrate, respectively. Simulations show that the adsorbates partly self-organize into island or stripe-like patterns. We show how these structures depend on the relative misfits, interaction, and concentration of components. The morphology is quite different for phase separation and intermixing regimes.

International Nuclear Information System (INIS)

Additional measurements have been made of deposition and retention of inhaled radioactively labeled iron oxide aerosols generated by a spinning top aerosol generator.

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The partial pressures of the components (ThCl/sub 4/, MCl and MThCl/sub 5/) in the saturated vapours of ThCl/sub 4/ solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl/sub 4/ concentration (2 to 50 mol% ThCl/sub 4/) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl.

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The merits of single stage absorption heat pumps coupled to simple distillation for effluent treatment are discussed. An experimental integrated absorption heat pump effluent purification system (IAHPEPS) was built and operated with water-lithium bromide as a working mixture. This unit has been used to raise the temperature and hence, the vapour pressure of the impure water contained in one vessel, to the point where pure water vapour will distil from impure effluent solution (tap water or brine) and condense in a second vessel used to collect pure water. Pure effluent production rates of between 0.5 and 4.3 kg h{sup -1} were obtained. The actual coefficient of performance (COP{sub A}) and the heat pump effectiveness varied from 1.1 to 1.4 and 0.58 to 0.72, respectively. The results from the small scale systems indicate the likely results from industrial scale units which could be operated with low quality heat such as waste heat, solar or ...

International Nuclear Information System (INIS)

Microbial population and moisture content of traditional herbal medicines contaminated with 3 kinds of aerobic microbes, packed in 5 kinds of plastic packaging materials, followed by irradiation at minimum dose of 5 kGy and stored for 6 months were investigated. The highest reduction of microbial counts during storage was observed on samples packed in polyethylene bags. All of packaging materials used were found to be impermeable to microbes and water vapour. Radiation and packaging materials used acted synergistically to inactivate microbes durind storage. The microbial counts decreased as much as 2 to 4 log cycles during storage. (author).

International Nuclear Information System (INIS)

The foils of various materials were irradiated with "6"0Co with an activity of 11,538 TBq. The minimum radiation dose was 25 kGy. Changes in chemico-physical properties were evaluated by infrared spectroscopy and were not detected after irradiation with 25 kGy. Packing foils were subjected to the following tests: mechanical tests, tests of weld strength, tests of impact resistance, free fall tests, permeability tests for water vapour and microbiological tests. The results of all tests were tabulated. The tests showed that the foils are impermeable for microorganisms and provided the welds are airtight the packed products remain sterile. (J.P.).

International Nuclear Information System (INIS)

Tritium is produced in large quantities at heavy water nuclear power reactors via the neutron activation reaction "2H(n,#gamma#)"3H. At Wolsung nuclear power plant which has a CANDU reactor, the tritium concentrations in coolant and in moderator systems are 1.5 Ci/Kg-D_2O and 35 Ci/kg-D_2O, respectively, after 12 years of operation. The airborne tritium concentration in main access area is normally less than 5 MPCa except short-term peaks. The average tritium concentrations in main access controlled areas are normally less than 100 MPCa. Tritium is mainly present in the air of workplace of CANDU reactors as a tritiated water vapour. Airborne tritiated water vapour enters the workers body via inhalation and absorption through skin and can result in a significant dose. The occupational doses from tritium at Wolsung NPP have been maintained below 1 man-Sv per year so far. The tritium contribution to the total plant man-Sv changes between 30 ...

International Nuclear Information System (INIS)

Low pressure silane plasmas are known for their ability to synthesize silicon nanoparticles via gas phase nucleation. While in the past this particle formation has often been considered from the viewpoint of a contamination problem in semiconductor processing, we here describe a silane low pressure plasma that enables the synthesis of highly oriented, cubic-shaped silicon nanocrystals with a rather monodisperse size distribution. These silicon nanocubes have successfully been used in the manufacture of single nanoparticle vertical transistors. We discuss the advantages of this new paradigm of building nanoelectronic devices. The plasma synthesis process is characterized in more detail than in prior work. The particle nucleation, growth and shape evolution are studied. Results indicate that the process provides two spatially distinct zones: a diffuse plasma for particle growth and a constricted plasma zone for particle annealing. Measurements of the plasma ion ...

International Nuclear Information System (INIS)

A magnetic rhombohedral PrCo_2C_x (x = 0.05 #approx#0.25) phase (space group Rbar 3m), which is heavily twinned along the #left brace#110#right brace# and #left brace#211#right brace# planes, was identified. The twinning mechanism was explored by analyzing the reduction of crystal symmetry due to the cubic-rhombohedral phase transformation. The origin of the twinning and the formation of four twin variants were attributed to the insertion of carbon interstitials into Co_4 tetrahedrons along the bar 3 axis in the rhombohedral lattice, which corresponds to one of the four equivalent axes of its parent PrCo_2 cubic-lattice.

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Off-shell interactions for localized closed-string tachyons in C/Z{sub N} superstring backgrounds are analyzed and a conjecture for the effective height of the tachyon potential is elaborated. At large N, some of the relevant tachyons are nearly massless and their interactions can be deduced from the S-matrix. The cubic interactions between these tachyons and the massless fields are computed in a closed form using orbifold CFT techniques. The cubic interaction between nearly-massless tachyons with different charges is shown to vanish and thus condensation of one tachyon does not source the others. It is shown that to leading order in N, the quartic contact interaction vanishes and the massless exchanges completely account for the four point scattering amplitude. This indicates that it is necessary to go beyond quartic interactions or to include other fields to test the conjecture for the height of the tachyon potential. (author)

British Library Electronic Table of Contents (United Kingdom)

Spherical nano-sized YSZ (yttria stabilized ZrO2) powders were successfully synthesized via a reverse microemulsion system. The water droplets in the microemulsion system of yclohexane/water/span85/Triton X-100/hexyl alcohol can act as the nano-reactors which solubilize zirconium oxychloride and ammonia water separately. The minute original reactors are favor to the formation of nano-sized spherical YSZ powders and the dispersibility of the powders can be controlled effectually by adjusting the weight ratio of the LiNO3 molten salt to the precursor. The phase transformation from cubic to monoclinic starts at and 500??C and finally monoclinic and cubic phase with increased crytallinity coexist at 800??C. The effect of LiNO3 molten salt in the formation of YSZ powders was also discussed.

International Nuclear Information System (INIS)

This paper describes stable strontium as composed of four stable isotopes ( Sr 88, Sr 87, Sr 86, and Sr 84), of which Sr 88 contributes more than 82% to its composition. Strontium exists in three crystalline, plymorphic forms; face-centered cubic alpha form, hexagonal beta form and body-centered cubic gamma form. Strontium occupies in many physicochemical aspects an intermediate position between calcium and barium, as does the solubility of strontium salts. As a result of its oxidation potential, strontium readily forms oxides, halides, and sulfide. The author proposes that the slight discrimination against strontium incorporation into bony tissues may be due to the difference in ionic potential (14%) between strontium and calcium. Ionic potential is an indicator of the strength of ionic bonds: strontium has a smaller ratio of ionic charge to ionic radius when compared with calcium.

Energy Technology Data Exchange (ETDEWEB)

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KoreaScience (Korea)

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Science.gov (United States)

... wood, kitchen wastes, and human faeces with the ash from such burning deposited and retained in an ...

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This report attempts to bring together available information on the coal deposits of Antarctica and discuss factors that would be involved if these deposits were to be explored and mined. Most of the reported principal coal deposits in Antarctica lie generally within the Transantarctic Mountains: the majority are of Permian age and are present in the Victoria Group of the Beacon Supergroup. Several other deposits have been recorded in East Antarctica and in the Antarctic Peninsula, including minor occurrences of Mesozoic and Tertiary coal and carbonaceous shale.

International Nuclear Information System (INIS)

The possibilities to grow isolated structures of complex oxides by pulsed laser deposition through stencils were investigated. A stencil consisting of a SiN membrane with apertures of several hundred nanometers embedded in a Si chip is placed in front of a heated substrate (up to 750 degrees Celsius). Deposition through these apertures results in resistless, direct patterning by local deposition of complex oxides like ferroelectric Lead Zirconate Titanate. The created isolated structures were analyzed by AFM imaging. Under-deposition, in this work called broadening, is inevitable during stencil deposition and is depending on deposition parameters, especially pressure. Different causes of broadening are mapped and discussed.

International Nuclear Information System (INIS)

YBa_2Cu_3O_7_-_x thick films have been deposited on silver sheets and MgO single crystals by spray pyrolysis. Film texture is related to film thickness and sintering temperature. The X-ray intensity ratio of the 005 peak to the 110 peak is higher for thin films deposited at the higher temperatures. However, elevated temperatures promote copper diffusion and second-phase formation in films deposited on silver. Films deposited on MgO can have larger grain sizes and are more oriented than those deposited on silver.

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A new magnetic macroparticle filter design consisting of two 90{sup o} filters forming an S-shape is described. Transport properties of this S-filter are investigated using Langmuir and deposition probes. It is shown that filter efficiency is product of the efficiencies of two 90{sup o} filters and the deposition rate is still acceptably high to perform thin film deposition. Films of amorphous hard carbon have been deposited using a 90{sup o} filter and the S-filter, and macroparticle content of the films are compared.

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The understanding of fission product deposition in realistic steam generator conditions is needed for release estimates in PSA studies, and for the design of efficient accident management procedures. This is considered very important because primary-to-secondary leakages risk dominant sequences in many plants. Furthermore, the decay heat of the fission product deposits adds to the thermal load to the steam generator tubes also in other sequences, especially in case of cold leg leakages. This brings out the concern of induced steam generator tube ruptures in cases, where the steam generators are initially intact. The experimental data showed that the highest deposited fraction within the tubes were found in cases with lowest flow velocities. The minimum value of the deposited fraction was observed at intermediate flow velocities. With these relatively low Reynolds numbers, the results calculated with ...

Energy Technology Data Exchange (ETDEWEB)

The electronic structure of the C15, or cubic-Laves-phase material, UAl/sub 2/ has been calculated using the linearized relativistic augmented-plane-wave method. The anomalous behavior of the electrical resistivity, specific heat, and magnetic susceptibility can be explained by the fine structure of the density of states near the Fermi energy alone, without the necessity of the introduction of drastic spin fluctuations or many-body effects.

Energy Technology Data Exchange (ETDEWEB)

An automatic data-smoothing algorithm for data from digital oscilloscopes is described. The algorithm adjusts the bandwidth of the filtering as a function of time to provide minimum mean squared error at each time. It produces an estimate of the root-mean-square error as a function of time and does so without any statistical assumptions about the unknown signal. The algorithm is based on least-squares fitting to the data of cubic spline functions.

Science.gov (United States)

Nuclear magnetic resonance results are presented for a number of NaCl-type compounds and cubic Laves-phase type compounds of uranium, neptunium, and plutonium. Special emphasis is placed on the Knight shift and spin-lattice relaxation time measurements and their interpretation in terms of localized or itinerant pictures of the 5Line integral electrons.

International Nuclear Information System (INIS)

It is shown that the section of the energy surface corresponding to the longitudinal mode by the principal xy-plane for the A-15 compounds will degenerate into four points at the corners of a square at very low temperatures in the cubic phase. When the quasi-shear mode propagating along the (110) direction becomes soft, simultaneously the longitudinal mode will exhibit unusually high phonon focussing. (author).

Energy Technology Data Exchange (ETDEWEB)

Theoretical and experimental results of investigating a cylindrical heat receiver with secondary reflectors are presented. One important element of solar thermal power plants (STPP) is the heat receiver. Several forms of heat receiver exist; the main form is the heat receiver of cavity form (including cylindrical, rectangular, and cubic heat receivers with a noncircular aperture). The linear dimension of such heat receivers is equal to, or larger than, the theoretical diameter of the concentrator focal spot.

Energy Technology Data Exchange (ETDEWEB)

Supercritical CO2 is used as a new solvent for immersion deposition, a galvanic displacement process traditionally carried out in aqueous HF solutions containing metal ions, to selectively develop metal films on featured or non-featured silicon substrates. Components of supercritical fluid immersion deposition (SFID) solutions for fabricating Cu and Pd films on silicon substrates are described along with the corresponding experimental setup and procedure. Only silicon substrates exposed and reactive to SFID solutions can be coated. The highly pressurized and gas-like supercritical CO2, combined with the galvanic displacement property of immersion deposition, enables the SFID technique to selectively deposit metal films in small features. SFID may also provide a new method to fabricate palladium silicide in small features or to metallize porous silicon.

British Library Electronic Table of Contents (United Kingdom)

In this paper we demonstrate the electrodeposition of nickel, a common ferromagnetic material, in various magnetically desirable shapes including nanowires, nanoparticles and highly faceted shells. In order to obtain three dimensional mesostructures, the electrochemical deposition of nickel was performed on highly oriented pyrolytic graphite (HOPG) under different electrolyte composition and deposition potential conditions. Under potentiostatic deposition at one distinct potential negative with respect to the reversible potential of nickel, three stages of nucleation and growth take place leading to a complex morphology of deposits. However, dual-pulse potential deposition and electrodeposition in low pH solutions causing hydrogen evolution, lead to nickel deposits in the form of nanowires...

British Library Electronic Table of Contents (United Kingdom)

In this work an experimental study is carried out to determine the thermo-hydraulic performance of an intercooler (IC) with flat tubes provided with triangular plain internal fins and louvered external fins when it is used on a car equipped with a low pressure EGR. The main unknowns to be answered are the thermo-hydraulic characteristics of the IC working under humid conditions induced by EGR, the conditions under which the water content in the mixture of air and exhaust gases begins to condense and the conditions under which the condensed water will be retained inside the IC. The exhaust gases are here replaced by a mixture of dry air and water vapour which are mixed upstream of the IC. The IC is submitted at the following testing conditions: on the ambient air side, the air temperature i...

British Library Electronic Table of Contents (United Kingdom)

Nanomaterials are increasingly being used to modify adhesives used in aerospace and materials applications. Improvements in thermal and mechanical properties have been found by incorporation of small amounts of nanosize materials in to such adhesives. However, the introduction of nanomaterials to adhesives used in civil engineering applications is still a new approach which needs to be explored, especially in retrofitting of structures. This paper presents part of an ongoing research to address the effect of adding nanomaterials to modify a thermosetting adhesive used for bonding carbon fibre reinforced polymer (CFRP) composites to concrete members. Vapour grown carbon fiber (VGCF) was chosen to modify the adhesive. Different concentrations of carbon nanofibres PR-24 XT-LHT were adopted fo...

International Nuclear Information System (INIS)

Autoionizing and Auger transitions in atomic manganese and samarium have been experimentally investigated by observation of the ejected electrons in the energy region 0 to 40 eV following electron impact excitation with incident beams in the energy range 15-500 eV. Seventy-four spectral features are tabulated for manganese and a number of new assignments have been made based on pseudo-relativistic Hartree-Fock calculations and quantum defect analysis. A similar study of samarium reveals only a number of broad features in the ejected-electron energy range 8-10 eV. Three features have been observed consistently in the ejected-electron spectrum of samarium and assigned by comparison with previous work. (author).

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Solar cells and organic electronic devices require an encapsulation to ensure sufficient lifetime. Key parameters of the encapsulation are permeation barrier, UV stability, temperature stability, optical transmission spectra and mechanical stability. The requirements depend very much on the specific application. Many work groups suggest multilayer stacks to meet the permeation requirements. In this paper the permeation barrier properties of the different constituents of such a multilayer stack are characterized. Different layer materials are compared regarding their water vapour and oxygen permeability as well as the influence of process parameters is examined. Finally temperature dependent permeation measurements are used to characterize the permeation mechanisms in the different constituents of the multilayer barrier.

British Library Electronic Table of Contents (United Kingdom)

A galactose-specific seed lectin was purified from the legume Spatholobus parviflorus and crystallized using the hanging-drop vapour-diffusion technique. Thecrystals belonged to space group P1, with unit-cell parameters a = 60.998, b=60.792, c = 78.179-, = 101.32, = 91.38, = 104.32. X-ray diffraction data were collected under cryoconditions (100-K) to a resolution of 2.04- using a MAR image-plate detector system mounted on a rotating-anode X-ray (Cu-K) generator. Molecular replacement using legume-lectin coordinates as a search model gave a tetrameric structure.

International Nuclear Information System (INIS)

Ultraveiolet spectroscopy of molecules in vapour phase gives valuable information about electronic structure of free molecules. But in many cases vaipour phase investigations are not possible and in order to isolate molecules within solid lattice, we used cryogenic temperature and high vacuum technology to study absorption spectrum within the spectral range (230-270)nm of an isolated benzene molecule in Argon, Krpton, Nitrogen, Carbon and methane matrices. The spectra shifts were measured and calculated in the matrix environment for the electronnic transition (B 24--A 19) in benzene molecule using the matrices mentioned above. Molar extinction coefficients and oscillator strength were measured too. (7 tabs., 32 figs., 50 refs.).

British Library Electronic Table of Contents (United Kingdom)

Analytical relations are obtained for estimating how the distributions of temperature and heat flux vary along a steam-generating tube and how the steam-generator power output reduces due to formation and accumulation of deposits.

International Nuclear Information System (INIS)

The reactive evaporation process was successfully used to deposit films of the A-15 Nb_3Ge phase. This is the first report, to the best of our knowledge, illustrating the use of such processes for the deposition of A-15 compounds. In this process, niobium vapors from an electron-beam-heated evaporation source react with germane gas introduced into the vacuum chamber at low partial pressures (approximately 10"-"4 Torr) to produce Nb_3Ge deposits. The process variables studied were the deposition temperature, the niobium-to-germanium impingement ratio on the substrate and the plasma-enhanced deposition, in this case the activated reactive evaporation process. At low deposition temperatures (below 450"0C) the deposit is amorphous (or microcrystalline) and can be crystallized to the Nb_3Ge phase by heat treatment, e.g. at 850"0C for 1 h in ...

Science.gov (United States)

This report results from a contract tasking Eindhoven University of Technology as follows: The contractor will investigate the plasma treatment of surfaces and plasma enhanced deposition using EUT's cascade arc source as the basis for this effort.

International Nuclear Information System (INIS)

... 194 p. auger electron spectroscopy decomposition deposition interfaces oxygen

International Nuclear Information System (INIS)

Adult and newborn rats were exposed to "2"3"9PuO_2 aerosols of four different size distributions. Rats of both ages were killed at intervals between 1 hr and 60 days postexposure. There were marked age- and particle-related size differences in deposition, although retention was similar throughout. The differences in deposition are attributable to relatively greater deposition of larger particles in the upper respiratory tracts of newborns.

Energy Technology Data Exchange (ETDEWEB)

A compact cesium deposition system was used for direct deposition of cesium atoms and ions onto the inner surface of the 1/3 scale Hydrogen Negative Ion Source for the LHD-NBI system. A small, well defined amount of cesium deposition in the range of 3-200 mg was tested. Negative ion extraction and acceleration were carried out both in the pure hydrogen operation mode and in the cesium mode. Single Cs deposition of 3-30 mg to the plasma chamber have produced temporary 2-5 times increases of H-yield, but the yield was decreased within several discharge pulses to the previous steady-state value. Two consecutive 30 mg depositions done within a 3-5 hours/60 shot interval, produced a similar temporary increase of H-beam, but reached a larger H-yield steady-state value. Deposition of larger 0.1-0.2 g Cs portions with a 20-120 hours/150-270 shot interval improved the ...

Energy Technology Data Exchange (ETDEWEB)

The question about expanding the boundaries of the open pit mining method is examined. The use of methods which consider the advantages of open and underground mining operations with their joint use in horizontal and evenly dipping deposits will make it possible to objectively select the mining method, to expand the range of use of open pit mining operations in the deposits of the Far North and provide an improvement in the technical and economic indicators of mineral extraction.

Energy Technology Data Exchange (ETDEWEB)

This report measured the rate of isothermal deposition of sub-micron particles of magnetite onto the surface of Alloy 800 at pH of 4.2-9.3 at Re=10,000 and a fluid temperature of 25C. Deposition is modelled as a two-step process, the transport of particles to the surface region followed by attachment to the surface.

International Nuclear Information System (INIS)

Between December 2001 and May 2004, a ventilation experiment (VE) was performed in the Mont Terri Underground Research Laboratory (URL) and co-financed by the Commission of the European Communities. The objective was to investigate the desaturation of consolidated clay formations in consequence of the ventilation of underground openings of a repository in such a formation. The results of the geoelectric measurements performed in the second phase of the Mont Terri ventilation test can be summarized as follows: Geoelectric tomography has been found suitable for monitoring ventilation-induced saturation changes in the Opalinus clay. During ventilation with dry air a desaturation down to below 50% could be detected in both desaturation cycles. The desaturated zone extends less than 0.5 m into the rock around the microtunnel. During the second resaturation phase, ventilation with humid air led to quick resaturation at the tunnel surface, while resaturation of the rock mass took months. The ...

Energy Technology Data Exchange (ETDEWEB)

The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain ...

Energy Technology Data Exchange (ETDEWEB)

The Co-doped BaTiO{sub 3} nanosized powders and ceramics were prepared via the sol-gel process. The powders and ceramics were characterized by methods of XRD, SEM and TEM. The dielectric properties of the ceramics were also determined by these methods. The influence of sintering temperature, sintering time and Co concentration on the microstructure and dielectric properties was discussed. The results revealed that the powders were in nanometer scale (30-50 nm) and were mainly composed of cubic BaTiO{sub 3} phase and small amount of BaCO{sub 3}. After sintering, both the cubic BaTiO{sub 3} and BaCO{sub 3} were transformed into tetrahedron BaTiO{sub 3}. The sintering temperatures of the Co-doped BaTiO{sub 3} ceramics decreased (about 100 deg. C) and the Curie temperatures of the ceramics were then moved to lower temperature. In addition, the dielectric constant of the ceramics doping with Co was higher than that of the pure BaTiO{sub 3} ceramics. ...

International Nuclear Information System (INIS)

Single crystal cubic boron nitride (cBN) was heteroepitaxially grown on a seed crystal of diamond under static high pressure and high temperature at 5.5GPa and 1,600--1,700 C, respectively, for 10--100 hour. A temperature gradient method was employed for the crystal growth by using lithium boron nitride as a solvent. Initial growth feature of cBN crystal was found on the diamond seed surface after the growing time of 10 minutes. The nucleation sites of the crystals seem to be near the etch pits on the diamond surface which were introduced by the surface dissolution by the solvent for cBN growth. Two types of growth features, island and step growth were typically shown on the surface. It can be seen that grown crystal appearing as a (111) nitrogen face was exhibited with the step growth feature, while the (11n) face exhibited the island growth feature. Considering the growth process under constant P-T growing condition, growth rate of cBN crystal was significantly ...

International Nuclear Information System (INIS)

4.82 wt% AIN and 2.98 wt% Y_2O_3 were added to Si_3N_4 as sintering agents in order to have #alpha#_Sialon composition of x=0.15 and monoclinic ZrO_2 between 0 to 10 wt% was admixed with Si_3N_4 based ceramics were fabricated by hot-pressing at 1,750 deg C for 90 min under 30 MPa in argon and nitrogen atmospheres effects of sintering atmospheres and addition of ZrO_2 on mechanical properties of Si_3N_4 based ceramics were investigated. As ZrO_2 content increased, the fraction of #alpha#-Sialon tended to decrease and the amount of cubic ZrO_2 increased because Y_2O_3 acted as the stabilizer of ZrO_2. The sintering atmospheres didn't affect on the sintering behavior and the product phases in hot-pressing of Si_3N_4. Bending strength increased when ZrO_2 content. ZrO_2 didn't contribute to the increase of fracture toughness because stabilized cubic ZrO_2 was produced by the added Y_2O_3. (Author).

International Nuclear Information System (INIS)

Understanding the erosion and deposition rates in a small watershed is important for designing soil and water conservation measures. The objective of this study is to estimate the net soil loss and gain at points with various land use types and landform positions in a small watershed in the Sichuan Hilly Basin of China by the 137Cs tracing technique. Among various land use types, the order of erosion rate was bare rock > sloping cultivated land > forest land. The paddy field and Caotu (a kind of cultivated land located at the foot of hills) were depositional areas. The erosion rate under different landform was in this order: hillside > saddle > hilltop. The footslope and the valley were depositional areas. The 137Cs technique was shown to provide an effective means of documenting the spatial distribution of soil erosion and deposition within the small watershed.

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Anti-reflective coatings made with Teflon AF2400 had the highest damage thresholds recorded for physical vapor deposited coatings at the Lawrence Livermore National Laboratory damage facility. Physical vapor deposited layers of Teflon AF2400, a perfluorinated amorphous polymer, maintained the bulk optical properties of a high transmittance from 200 nm to 1600 nm, and a low refractive index. In addition, the refractive index can be intentionally reduced by control of two common deposition parameters, deposition rate and substrate temperature. Scanning electron microscopy and nuclear magnetic resonance observations indicated that morphological changes caused the variations in the refractive index rather than compositional changes. The coatings adhered to fused silica and silicon wafers under normal laboratory handling conditions.

Science.gov (United States)

The properties of the mixing layer in dynamic systems were studied by the example of a mathematical model of the cubic image type. Its role in the generation of information and the evolution of its significance was shown. At the moment of generation, information is of zero significance, and this significance then increases. A criterion of efficiency was proposed, and the optimum moment of making a decision in creative work was determined. It was shown that the increase in the variability of the parameters of a living system upon entry into the mixing layer and its decrease upon exit can serve as objective indicators of the transition of the system from one dynamic regime (attractor) to another. PMID:12723364

Energy Technology Data Exchange (ETDEWEB)

There are several equivalent descriptions for constant B-field background of open string. The background can be interpreted as constant B-field as well as constant gauge field strength or infinitely many D-branes with non-commuting Chan-Paton matrices. In this article, the equivalence of these open string theories is studied in Witten's cubic open string field theory. Through the map between these equivalent descriptions, both algebra of non-commutative coordinates as well as Chan-Paton matrix algebra are identified with subalgebras of open string field algebra. (author)

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This paper reports the presence of face centered cubic cobalt precipitates inside tungsten carbide in nanocomposite of WC-Co synthesized by spray conversion processing. EDS was used to identify the presence and micro-diffraction was employed to determine the nature of the precipitates. There is entrapment of cobalt in tungsten carbide during the spray conversion process used to form WC/Co powder. During consolidation, at high temperatures, the cobalt attains enough mobility to precipitate inside WC. A vanadium containing compound was seen at the interfaces in samples which incorporated VC as a grain growth inhibitor. (orig.)

Energy Technology Data Exchange (ETDEWEB)

In this project we developed photonic crystal modeling capability and fabrication technology that is scaleable to large area. An intelligent optimization code was developed to find the optimal structure for the desired spectral response. In terms of fabrication, an exhaustive survey of fabrication techniques that would meet the large area requirement was reduced to Deep X-ray Lithography (DXRL) and nano-imprint. Using DXRL, we fabricated a gold logpile photonic crystal in the <100> plane. For the nano-imprint technique, we fabricated a cubic array of gold squares. These two examples also represent two classes of metallic photonic crystal topologies, the connected network and cermet arrangement.

CERN Document Server

The existence of a global attractor for the solution semiflow of the extended Brusselator system in the $L^2$ phase space is proved, which is a cubic-autocatalytic and partially reversible reaction-diffusion system with linear coupling between two compartments. The method of grouping and re-scaling estimation is developed to deal with the challenge in proving the absorbing property and the asymptotic compactness of this typical multi-component reaction-diffusion systems. It is also proved that the global attractor is an $(H, E)$ global attractor with the $L^\\infty$ regularity and that the Hausdorff dimension and the fractal dimension of the global attractor are finite. The results and methodology can find many applications and further extensions in complex biological and biochemical dynamical systems.

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On September 25, 1986, an elderly Virginia couple had their home fumigated by a local pest extermination company for the control of wood-boring insects. Two hundred and fifty pounds of sulfurylfluoride (SF), a colorless, odorless fumigant gas commonly used for this purpose, was applied in the approximately 80,000-cubic-foot home that date. Within 1 week, both husband and wife were dead. Because both deaths occurred within a short period of time and the wife's illness was compatible with toxic gas inhalation, these deaths were then thought to be related to the home fumigation.

British Library Electronic Table of Contents (United Kingdom)

A one parameter family of iterative methods for the simultaneous approximation of simple complex zeros of a polynomial, based on a cubically convergent Hansen-Patricks family, is studied. We show that the convergence of the basic family of the fourth order can be increased to five and six using Newtons and Halleys corrections, respectively. Since these corrections use the already calculated values, the computational efficiency of the accelerated methods is significantly increased. Further acceleration is achieved by applying the Gauss-Seidel approach (single-step mode). One of the most important problems in solving nonlinear equations, the construction of initial conditions which provide both the guaranteed and fast convergence, is considered for the proposed accelerated family. These cond...

International Nuclear Information System (INIS)

Non-anisotropic free energy is considered which under minimization yields two magnetic phases: a conical spin density wave and a low temperature conical cycloid. Using equations of motion, the excitation spectrum is studied. Knowing the nature of these excitations, the dielectric function as well as the fluctuation specific heat is computed and compared with the experimental spectrum. Due to the electromagnon going soft, the dielectric function (imaginary part) as well as the specific heat capacity show peaks at the temperature where ferroelectricity appears in the system.

CERN Document Server

Based on Friedberg and Lee's geometric picture by which the tribimaximal PMNS leptonic mixing matrix is constructed, namely corresponding mixing angles correspond to the geometric angles among the sides of a cube. We suggest that the three realistic mixing angles which slightly deviate from the values determined for the cube, are due to a viable deformation from the perfectly cubic shape. Taking the best fitted results of $\\theta_{12}$ and $\\theta_{23}$ as inputs, we determine the central value of $\\sin^22\\theta_{13}$ should be 0.0238 with a relatively large error tolerance, this value lies in the range of measurement precision of the Daya Bay experiment.

International Nuclear Information System (INIS)

Ion bombardment during deposition can significantly modify the film properties. In the partially ionized beam deposition, ions derived from the depositing material, i.e., the self-ions, are used during deposition. Cu films were deposited on SiO_2 substrates at room temperature using 1% Cu self-ions with an energy ranging between 0--4 keV. We studied the microstructures of the Cu films using x-ray diffraction and transmission electron microscopy, measured the impurity level inside the films using secondary ion mass spectrometry, and performed the resistivity measurements using a four point probe. The results indicate that there is an optimum ion energy around 2 keV at which, the integrated x-ray intensity ratio I(111)/I(200) reaches its maximum value indicating a strong left-angle 111 right-angle texture, while the impurity concentration and resisitivity are minimum. The correlation ...

Science.gov (United States)

Ion bombardment during deposition can significantly modify the film properties. In the partially ionized beam deposition, ions derived from the depositing material, i.e., the self-ions, are used during deposition. Cu films were deposited on SiO{sub 2} substrates at room temperature using 1% Cu self-ions with an energy ranging between 0--4 keV. We studied the microstructures of the Cu films using x-ray diffraction and transmission electron microscopy, measured the impurity level inside the films using secondary ion mass spectrometry, and performed the resistivity measurements using a four point probe. The results indicate that there is an optimum ion energy around 2 keV at which, the integrated x-ray intensity ratio {ital I}(111)/{ital I}(200) reaches its maximum value indicating a strong {l angle}111{r angle} texture, while the impurity concentration and resisitivity are minimum. ...

Energy Technology Data Exchange (ETDEWEB)

At Los Alamos National Laboratory (LANL), a recent effort in waste minimization has focused on scrap metal from radiological controlled areas (RCAs). In particular, scrap metal from RCAs needs to be dispositioned in a reasonable and cost effective manner. Recycling of DOE scrap metals from RCAs is currently under a self-imposed moratorium. Since recycling is not available and reuse is difficult, often metal waste from RCAs, which could otherwise be recycled, is disposed of as low-level waste. Estimates at LANL put the cost of low-level waste disposal at $550 to $4000 per cubic meter, depending on the type of waste and the disposal site. If the waste is mixed, the cost for treatment and disposal can be as high as $50,000 per cubic meter. Disposal of scrap metal as low-level waste uses up valuable space in the low-level waste disposal areas and requires transportation to the disposal site under Department of Transportation (DOT) regulations for ...

Energy Technology Data Exchange (ETDEWEB)

The dry deposition of pollutants can be calculated from the concentration of pollutants in the atmosphere and deposition velocity. To calculate deposition velocity, turbulence parameters such as friction velocity and Monin-Obukhov length are used. However, due to the difficulties in observation of turbulence parameters, usually mean values of wind speed and temperature observed using conventional meteorological instruments are used to estimate the dry deposition. The dry deposition velocity is the function of aerodynamic resistance (R{sub a}), sublayer resistance (R{sub b}), surface resistance (R{sub c}). R{sub a} and R{sub b} are calculated from turbulence parameters and R{sub c} is related to surface characteristics. The purpose of the present study is to compare the dry deposition obtained using the data sets of mean values and turbulence parameters measured ...

Science.gov (United States)

A "hemispheres-in-cell" geometry is provided for prediction of colloid retention during transport in porous media. This new geometry preserves the utilities provided in the Happel sphere-in-cell geometry; namely, the ability to predict deposition for a range of porosities, and representation of the influence of neighboring collectors on the fluid flow field. The new geometry, which includes grain to grain contact, is justified by the eventual goal of predicting colloid deposition in the presence of energy barriers, which has been shown in previous literature to involve deposition within grain to grain contacts for colloid:collector ratios greater than approximately 0.005. In order to serve as a platform for predicting deposition in the presence of energy barriers, the model must be shown capable of quantitatively predicting deposition in the absence of energy barriers, which is a ...

Energy Technology Data Exchange (ETDEWEB)

A thin film microoxidation test utilizing the concept of the Lubricant Stability Map has been used to study the effect of temperature on deposit formation by lubricants on upper piston locations of low heat rejection engines. The stability maps were established for two formulated lubricants in this study. These two lubricants were also evaluated in a series of engine tests with various piston temperatures. The deposition phenomena observed in the engine tests have been adequately simulated and described by the stability maps. It is concluded that lubricants at upper piston locations are under a thin film condition similar to that achieved by the thin film microoxidation test. The deposit formation trend is determined by the volatility, thermal stability, and oxidative stability of the base stock. Additives have little effect on deposit formation at very high temperatures. A combined consideration of all ...

International Nuclear Information System (INIS)

Applying the theory of depositional system, the depositional facies and depositional systems of the Zhiluo Formation in Dongsheng area are systematically analysed, and the authors proposed that sediments of the Zhiluo Formation are of fluvial facies, and streams of the Zhiluo time experienced three evolution stages, namely: the early braided stream, the middle low sinuosity meandering stream and the late high sinuosity meandering stream. Based on features of paleoclimatic evolution, the Zhiluo Formation is divided into two lithological members. The lower lithological member consists of sediments of braided and low sinuosity meandering streams under humid-ward paleoclimatic conditions forming grey sedimentary formation. The upper member is composed of sediments of meandering streams under arid-hot paleoclimatic conditions representing complex-colored (mainly red) sedimentary formation. It is suggested that uranium ...

International Nuclear Information System (INIS)

High power and particle deposition on target materials are encountered in many applications including magnetic and inertial fusion devices, nuclear and high energy physics applications, and laser and discharge produced plasma devices. Surface and structural damage to plasma-facing components due to the frequent loss of plasma confinement remains a serious problem for the Tokamak reactor concept. The deposited plasma energy causes significant surface erosion, possible structural failure, and frequent plasma contamination.

International Nuclear Information System (INIS)

Energy conservation and local energy deposition are investigated in the context of coupled-particle (i.e., neutrons, gamma rays, and charged particles) transport analysis. For charged particles, the concept of group splitting the 1 = 0 transfer matrix to ensure both particle and energy conservation is introduced. Although these procedures are more complex than those found in the usual neutron or coupled-neutron gamma-ray problem, they yield a consistent approach for the calculation of local energy deposition.

Energy Technology Data Exchange (ETDEWEB)

The addition of carbon to samples, during imaging, presents a barrier to accurate TEM analysis, the controlled deposition of hydrocarbons by a focused electron beam can be a useful technique for local nanometer-scale sculpting of material. Here we use hydrocarbon deposition to form nanopores from larger focused ion beam (FIB) holes in silicon nitride membranes. Using this method, we close 100-200nm diameter holes to diameters of 10nm and below, with deposition rates of 0.6nm per minute. I-V characteristics of electrolytic flow through these nanopores agree quantitatively with a one dimensional model at all examined salt concentrations.

Energy Technology Data Exchange (ETDEWEB)

There is increasing demand to functionalize meso- and nano-porous materials by coating and make the porous substrate biocompatible or environment friendly. However, coating on a meso-porous substrate poses great challenges, especially if the pore aspect ratio is high. In the current work the pulsed laser deposition (PLD) method is used for coating Ni{sub 3}Al-based meso-porous membranes with diamond-like carbon (DLC) layers of high thickness homogeneity and adhesion. (orig.)

British Library Electronic Table of Contents (United Kingdom)

ABSTRACT Shallow-lacustrine delta deposits of the Upper Triassic Yanchang Formation form the most important petroleum reservoir sandstone units in the Ordos Basin, China. Recent hydrocarbon exploration and outcrop studies demonstrated that shallow-lacustrine sand-rich deltas developed extensively along the gentle flanks and central part of the basin. The vertical succession of facies indicates that the Yanchang Formation records the entire lacustrine life cycle of the Late Triassic Ordos Basin. Four third-order transgressive-regressive cycles and two larger shallow-lacustrine deltaic cycles have been recognized. A process-based depositional model, derived in part from the modern Ganjiang delta in Poyang Lake, China, is used to infer the origins of the sand-rich lacustrine delta deposits. S...

Science.gov (United States)

... The insu- lation between gate and nanowire is the high-k dielectric HfO2, deposited by atomic layer depo- sition (ALD). ...

Energy Technology Data Exchange (ETDEWEB)

Oil shales of the US represent a tremendous store of potential oil. Most of the deposits are relatively unknown and warrant additional investigation. The summary presented cannot hope to cover all of the deposits. Information about them is usually available only locally. However, the 3 best known deposits - the Green River formation, the Devonian black shales, and the retort member of the Phosphoria formation - represent well over 2 trillion bbl (300 x 10/sup 12/ ton) of potential oil in place. This is an oil resource large enough to supplement quite adequately the US petroleum supply, to extend the time available for realigning our energy supply mixes, and to help reach a satisfactory solution to our current energy dilemma. The concentrated resource in the Green River formation is obviously the next most feasible source of oil. If it cannot be developed, all the other deposits will have to wait until ...

Science.gov (United States)

... ge aircraft engines (geae) has taken to development an induction plasma deposition (ipd) processing method for the fabrication of ti6242/sic mmc ...

Energy Technology Data Exchange (ETDEWEB)

The distribution of Lipiodol in the liver and lungs following arterial or portal injection was studied in normal (n=55) and cirrhotic rats (n=20). Using magnified xeroradiography and radioisotope labeled tracers, it was found that Lipiodol was deposited mainly in the liver and lung after either arterial or portal administration. In control rats after arterial injection, deposits in the lung peaked after 2 hours and gradually declined over 48 hours; whereas after portal injection, the deposit steadily increased for 48 hours. Twenty-five percent of cirrhotic rats demonstrated a Lipiodol-induced miliary pattern in the lung. An increased number of portosystemic shunts in cirrhotic rats was also noted. These results suggest that cirrhosis of the liver may be a potential risk factor for developing pulmonary complications after Lipiodol administration. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Focused Ion Beam (FIB) repairs and modifications to integrated circuits have been somewhat limited in the past due to the physical limitations imposed by the nodes of interest being buried under metal layers, the need for multiple layers of FIB generated interconnects, and the like. With the advent of FIB deposited INSULATOR materials, integrated circuit modifications can now be much more complex. The two primary goals of this project were (1) to determine the appropriateness of FIB insulator deposition for aiding FIB connections to metal nodes buried under power busses, and (2) development of a technique to do this. The work presented in this paper includes the development and characterization phases of adding INSULATION DEPOSITION to a FEI 611 FIB system, the problems encountered, their work around, and the aforementioned application of this technology.

British Library Electronic Table of Contents (United Kingdom)

Indium sulfide thin films were deposited onto indium-tin-oxide coated glass substrate by electrochemical deposition from an aqueous solution containing In2 (SO4) 3 and Na2S2O3. The deposition conditions were optimized on the basis of data obtained by scanning electron microscope, Auger electron spectroscopy and optical transmission measurements. Furthermore, the photosensitivity of the films was observed by means of photoelectrochemical measurements, which confirmed that the indium sulfide showed n-type conduction. The X-ray diffraction and Raman studies revealed that the as-grown films were amorphous or nanocrystalline in nature and became polycrystalline In2S3 after annealing.

International Nuclear Information System (INIS)

The corrosion behavior of the sputter-deposited amorphous or nanocrystalline W-Nb alloys is studied in 10% NaCl, 0.1 and 1 M NaOH solutions at 24 deg. C, open to air using immersion tests and electrochemical measurements. Niobium metal acts synergistically with tungsten in enhancing the corrosion resistance of the W-Nb alloys so as to show lower corrosion rates than the corrosion rates of the alloy-constituting elements in almost all examined solutions. Corrosion rates of W-Nb alloys are about more than one order of magnitude less than that of the sputter-deposited tungsten and even lower than that of sputter-deposited niobium. The stability of the anodic passive films formed on the W-Nb alloys increase with niobium content.

UK PubMed Central (United Kingdom)

The density of corn pollen on leaves of milkweed plants inside and outside of cornfields was measured in several studies from different localities. The purpose was to obtain a representative picture...Full Text Available

International Nuclear Information System (INIS)

This paper reports on a series of experiments performed to examine the ability of ion beam assisted thermal deposition to produce good adhesion of Au metallization on GaAs left-angle 100 right-angle substrates. A study of the influence of Ar ion-assisted thermal deposition of the Au films as well as in situ pre-sputtering of the GaAs surface with low-energy Ar ions prior to thermal deposition, shows that strong adhesion can be achieved without resorting to chemical cleaning. The substrate temperature and the relative flux of Ar ions to incident Au atoms were varied in order to correlate these parameters with film adhesion. The interfaces of films processed under these various conditions were examined by XTEM, RBS and XPS. Orientation texture was studied by x-ray diffraction (XRD).

Energy Technology Data Exchange (ETDEWEB)

Effects of ions of Group IA, IIA, IIIB, and VIIB elements on the cathodic deposition of a molybdenum were investigated in a KCl-LiCl (eutectic)-MoCl/sub 3/ molten salt at 773 K (500/degree/C). The results can be summarized as follows: The addition of potassium, rubidium, cesium, and barium cations and fluorine anions to the KCl-LiCl (eutectic)-MoCl/sub 3/ molten salt is effective in depressing the cathodic deposition of the molybdenum subchloride, which hinders the smooth, flat electrodeposition of molybdenum. The addition of lithium, sodium, magnesium, calcium, strontium, and aluminum cations and bromine and iodine anions promotes the undesirable cathodic deposition of the molybdenum subchloride.

International Nuclear Information System (INIS)

Conditions for radiation induced grafting with butyl acrylate dispersed in water emulsion onto chrome-tanned pig skins have been worked out for #gamma#-rays and electron beam irradiations. The highest yield of grafting was observed at monomer concentration approximately 25% (w/w), dose equal to 25 kGy and dose rate not exceeding 10 MGy/h. At these conditions the yield of grafting attained a value approximately 25% and content of homopolymer in the leather amounted to 6%. The efficiency of monomer to polymer conversion decreases when the concentration of monomer in emulsion and dose rate increases. Yield of homopolymer is independent of the dose rate. An explanation of the observed relations has been proposed. The physical and used properties of grafted leathers were tested. Radiation processed leathers were found superior to samples finished by traditional methods. One has to point to better tolerance against chemical cleaning and reduced water take-up without loss of high permeability ...

Energy Technology Data Exchange (ETDEWEB)

Liquid pipeline codes generally stipulate placement of block valves along liquid transmission pipelines such as on each side of major river crossings where environmental hazards could cause or are foreseen to potentially cause serious consequences. Codes, however, do not stipulate any requirement for block valve spacing for low vapour pressure petroleum transportation, nor for remote pipeline valve operations to reduce spills. A review of pipeline codes for valve requirement and spill limitation in high consequence areas is thus presented along with a criteria for an acceptable spill volume that could be caused by pipeline leak/full rupture. A technique for deciding economically and technically effective pipeline block valve automation for remote operation to reduce oil spilled and control of hazards is also provided. In this review, industry practice is highlighted and application of the criteria for maximum permissible oil spill and the technique for deciding ...

Energy Technology Data Exchange (ETDEWEB)

The first equipment installed at KfK-HDB was a system with a thin-film evaporator. This was later replaced by two vapor compression evaporating units with forced circulation, for evaporation of liquid LAW, and a steam-heated natural circulation evaporator, for evaporation of liquid MAW. Nuclear activities of the Karlsruhe Nuclear Research Center phasing out, the liquid radwaste quantities to be treated have been shrinking accordingly, so that the current system is planned to be replaced by a smaller system with a thin-film evaporator. (orig./HP) [Deutsch] Im Laufe der Jahre wurde die Anlage mit Duennschichtverdampfer durch zwei Bruedenkompressionsverdampfer mit Zwangsumwaelzung fuer die Eindampfung leicht aktiver waessriger Abfaelle und einem dampfbeheizten Naturumlaufverdampfer fuer die Eindampfung mittelaktiver waessriger Abfaelle ersetzt. Mittlerweile sinkt der Abwasseranfall seit Jahren stetig aufgrund der sinkenden Aktivitaeten des Zentrums auf dem Gebiet der Kerntechnik. Die ...

International Nuclear Information System (INIS)

Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min"-"1), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production was obtained using high voltage pulses of approximately 150 ns duration in Ar/O_2 mixtures with the maximum efficiency (energy yield) of 23 g kW ...

Energy Technology Data Exchange (ETDEWEB)

Several inexpensive and non-toxic solvents with low vapour pressures were investigated for their suitability as alternative solvents for the absorption of carbon dioxide from flue gas. The solvents include poly(ethylene glycol)s, poly(ethylene glycol) ethers, poly(ethylenimine) and glycerol-based substances. Solvent properties such as thermal stability, solubility of carbon dioxide and selectivity over nitrogen were investigated in a systematic study using a thermogravimetric analyser. Absorption results are reported for pure carbon dioxide and nitrogen as well as a mixture of both gases. Desorption and long-term sorption behaviour are also discussed. Glycerol and poly(ethylene glycol)s show a high solubility of carbon dioxide. Due to the high viscosity of the solvent, carbon dioxide absorption in poly(ethylenimine) is very slow in spite of the presence of favourable amine groups. PEG 300 was found to be the best solvent in this study and shows a high carbon ...

Energy Technology Data Exchange (ETDEWEB)

In 1990, 176 million tonnes (mt) of air-traffic fuel was burned, which produced about 550 mt CO{sub 2}, 220 mt water, 3.5 mt NO{sub x} amd 0.18 mt SO{sub 2}. NO{sub x} emissions from air traffic may, by increasing ozone concentrations, be responsible for about 8% of global greenhouse warming. In the stratosphere NO{sub x} from aircraft is partly responsible for ozone depletion. With present technology 500 aircraft in the stratosphere would cause global ozone losses of 20%. Water vapour added by aircraft also contributes to global warming. In the form of ice crystals between 8 to 13 km above sea level, it acts as cirrus clouds. Probably the least damaging cruising altitude for aircraft is 9 km above sea level. Fuel consumption by aircraft is increasing. Air pollution abatement measures include substituting hydrogen fuel for kerosene, developing engines that emit less NO{sub x} and the introduction of internationally negotiated taxes on kerosene. 30 refs.

Energy Technology Data Exchange (ETDEWEB)

The aim was to gain experience on how to produce Alkali Metal Thermo-Electric-Converter (AMTEC) cells, for the demonstration of their principles and potentials, as a basis for future commercialization. These cells should be able to present an efficient and direct conversion of thermal energy to electric energy. The system is based on an electro-chemical concentration cell built around a {beta}`` aluminium oxide membrane that separates the two chambers. This material is a good conductor of sodium and a bad conductor of electrons, and it is this property which is taken advantage of. In the two chambers of the cell is found saturated sodium vapour at two temperatures. The motive power is the expansion over the membrane where the sodium ions are transported through it whilst the electrons are forced through the outer cycle. This concept is described in detail in addition to the choice of materials, performance testing and results. It was found possible to produce AMTEC ...

Energy Technology Data Exchange (ETDEWEB)

This feasibility study of the uve Institut fuer Technische Chemie und Umweltschutz GmbH discusses the scientific and technical fundamentals of a catalytic process for complete removal of organic pollutants (PAH, H-HC, PCB, phenols, nitro-aromatics and organometallic compounds, e.g. from polluted soil and groundwater) by thermal-catalytic cracking and conversion into simple gases. The process is based on the catalytic reaction of the hydrocarbon compounds with water vapour in the temperature range of 700-900 degrees centigrade. The resulting gas mixtures consist mainly of hydrogen, carbon monoxide, carbon dioxide and methane which can be used as fuels, e.g. for heating or in gas engines. The process is an alterntive to combustion. It is therefore well suited whenever the pollutant to be removed is already mixed with water or water vapour and wherever in-situ removal would be too great a hazard. [Deutsch] Die vorliegende Machbarkeitsstudie aus ...

International Nuclear Information System (INIS)

The energy-versus-volume curve of the spin-density wave (SDW) in body-centred-cubic Cr is calculated with the density functional theory/full-potential linearized augmented plane wave (DFT/FLAPW) method using the generalized gradient approximation (GGA). The predicted ground state is not the SDW, in contrast to an earlier FLAPW calculation. A conjecture is formulated that the widely varying results of the local density approximation (LDA) and GGA - and of different solution methods - can be scaled by the size of the calculated moment. As a consequence, experimentally relevant properties of the SDW can be calculated by tuning the moment. The implications of these results for the ability of DFT to describe Cr are discussed. (author)

International Nuclear Information System (INIS)

Results of three-dimensional laminar and standard K-#epsilon# turbulent numerical simulations of natural convection cooling of ten cubic aluminum blocks mounted on an insulated plate, facing a shrouding wall, are presented. This geometry is chosen so that comparison with experimental results is possible. The considered problem is of great practical importance because it simulates the case of heated electronic chips, mounted on printed board assemblies, which are frequently encountered in electronic industry applications. The problem is mathematically modeled by the three-dimensional conservation differential equations of mass, momentum, energy and turbulent kinetic energy and dissipation (for the turbulent flow model). IN this paper, these equations are numerically solved by a finite volume method and the laminar and turbulent results are compared to the experimental results obtained with similar parameters.

British Library Electronic Table of Contents (United Kingdom)

The thermal stability of nanoscale grains in cryomilled aluminum powders containing 1% diamantane was investigated. Diamantane is a diamondoid molecule consisting of 14 carbon atoms in a diamond cubic structure that is terminated by hydrogen atoms. The nanostructures of the resulting cryomilled powders were characterized using both transmission electron microscopy (TEM) and X-ray diffraction (XRD) techniques. The average grain size was found to be on the order of 22?nm, a value similar to that obtained for cryomilled Al without diamantane. To determine thermal stability, the powders were heated in an inert gas atmosphere at constant temperatures between 423 and 773?K (0.51T m to 0.83T m) for exposure times of up to 10?h. The average grain size for all powders containing diamantane was obse...

International Nuclear Information System (INIS)

The energy bands and the nature of the conduction electrons have been studied for three intermetallic compounds of dysprosium. e.g., DyZn, DyCu and DyRh, following the augmented plane wave method. Density of states results are given and have implications for the stability of the structure of the intermetallic compounds of dysprosium. The charge densities and the number of conduction electrons inside and outside the APW spheres in each of these compounds are calculated; it is shown that the character of conduction electrons within the Dy APW sphere is principally of d type for all the compounds. The consequence of the predominance of d electron in the conduction bands on the various physical parameters is discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

Progress in the worldwide capability of predicting the convective energy loss from solar central receivers is reviewed. The significant advances in the past three years have been in experimental areas. Baseline measurements of the convective heat transfer from large high-temperature surfaces, e.g., a flat plate and a cubical cavity, have been completed and empirical correlations have been obtained. Theoretical modeling activities have not kept pace with the experimental advances, however. Currently, the primary theoretical emphasis is the development and testing of turbulence models suitable for buoyant flows. Three major needs have been identified: the measurement of convective energy losses from operating solar central receivers; the continued development of theoretical models in spite of the relatively slow progress to date; and the quantification of the effects of atmospheric turbulence.

International Nuclear Information System (INIS)

The thermal transformation of Al-base icosahedral phases was studied in-situ by real time neutron powder diffraction. Different compositions have been selected in order to vary the initial phase morphology and change the neutron scattering contrast between species. Alloys with low silicon and large aluminium contents produce first the orthorhombic O-Al_6Mn modification. In alloys with larger silicon content, the #alpha#-AlMnSi cubic phase appears soon after the beginning of the transformation but is still preceeded by O-Al_6Mn. Depending on compositions, the crystallization of the icosahedral phase is controlled either by the diffusion of Al through its interface with the residual fcc aluminium or that of Si within the bulk. The results are discussed in the light of current structural models. (author) 40 refs., 14 figs., 3 tabs.

International Nuclear Information System (INIS)

Transmission electron microscopy and x-ray diffraction data show that rapid thermal anneals of SrS:Ce thin films enhance grain size and reduce crystalline defects. Electron paramagnetic resonance results suggest that these anneals lead to less variance in the crystal field environments at the nearly cubic Ce"3"+ sites along with the formation of another type of Ce"3"+ site believed to involve a nearby Sr vacancy. We suggest that the association of Ce"3"+ sites with V_S_r shifts the electroluminescence towards larger wavelengths as the symmetry of the activator site is lowered. copyright 1997 American Institute of Physics.

International Nuclear Information System (INIS)

Transmission electron microscopy studies on solution-annealed Alloy 800 revealed small (100-200 nm), spherical-shaped titanium carbide (face centered cubic structure) and large (200 nm-5 #mu#m), faceted titanium nitride (hexagonal structure) particles randomly distributed in the austenite matrix. The volume fraction of former particles was found to be greater than that of the latter. Corrosion studies of the alloy in acidic, chlorides and acidic chloride environments at room temperature indicated that the passivity of Alloy 800 was adversely affected by the addition Cl"- ions. X-ray photoelectron spectroscopy revealed that the surface film formed on the alloy at the onset of passivity consisted of Cr"3"+ (as Cr_2O_3), without any Fe"3"+/Fe"2"+ or Ni"2"+. Scanning electron microscopy studies indicated initiation of pitting at large, faceted particles, not at small, spherical-shaped ones.

Energy Technology Data Exchange (ETDEWEB)

The magnetic pyrochlore Er{sub 2}Ru{sub 2}O{sub 7} has been studied with neutron scattering and susceptibility measurements down to a base temperature of 270 mK. For the low temperature phase in which the Er sublattice orders, new magnetic Bragg peaks are reported which can be indexed with integer (hkl) for a face centered cubic cell. Inelastic measurements reveal a wealth of crystal field levels of the Er ion and a copious amount of magnetic scattering below 15 meV. The three lowest groups of crystal field levels are at 6.7, 9.1 and 18.5 meV.

CERN Document Server

We report on the magnetic hyperthermia properties of chemically synthesized ferromagnetic 11 and 16 nm Fe(0) nanoparticles of cubic shape displaying the saturation magnetization of bulk iron. The specific absorption rate measured on 16 nm nanocubes is 1690+-160 W/g at 300 kHz and 66 mT. This corresponds to specific losses-per-cycle of 5.6 mJ/g, largely exceeding the ones reported in other systems. A way to quantify the degree of optimization of any system with respect to hyperthermia applications is proposed. Applied here, this method shows that our nanoparticles are not fully optimized, probably due to the strong influence of magnetic interactions on their magnetic response. Once protected from oxidation and further optimized, such nano-objects could constitute efficient magnetic cores for biomedical applications requiring very large heating power.

British Library Electronic Table of Contents (United Kingdom)

Herein, we demonstrate the structure of the PS colloidal crystals which were fabricated on the hydrophilic/hydrophobic Si wafers by a spin-coating technique. Monodisperse PS colloids are spin-coated onto self-assembled monolayers of 3-(aminopropyl)triethoxysilane and propyltrimethoxysilane coated Si wafers. PS spheres organized as ordered close-packed face-centered cubic structure with (111) planes on the hydrophilic surface while they gathered without the crystal structure on the hydrophobic surface. This paper also reports a simple and rapid method to fabricate the close-packed structure of hollow TiO2 spheres. The colloidal crystal of TiO2 hollow spheres was prepared using the PS sphere template on the hydrophobic surface. The mechanism for the growing multilayers of self-assembled PS p...

International Nuclear Information System (INIS)

Electron charge distributions are presented for Nb_3Ge, Nb_3Al, and two other hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near E/sub F/ suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb_3Ge is also investigated.

Science.gov (United States)

Electron charge distributions are presented for Nb/sub 3/Ge, Nb/sub 3/Al, and two other hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near E/sub F/ suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb/sub 3/Ge is also investigated.

British Library Electronic Table of Contents (United Kingdom)

We carried out theoretical analyses based on ab initio calculations that incorporate free energy of the vapor phase in order to determine the initial growth process of cubic GaN on GaN (001)-(4x1). The results suggest that a N-adsorbed structure appears at the initial growth stage and then Ga adsorbs on the N-adsorbed GaN (001)-(4x1) surface. Considering this process, we performed Monte Carlo simulations. The results suggest that the maximum point of Ga coverage after supplying a Formula Not Shown monolayer of atoms shifted toward a Ga-rich condition from V/III=1.0.

International Nuclear Information System (INIS)

The effect of atmospheric radioactive emissions from United Kingdom nuclear installations on acid deposition is assessed. Nitrogen oxide and ozone production resulting from and associated with discharges of airborne radioactivity, comparison with conventional emissions, and the direct effects of radioactive emissions on trees, are all discussed. (UK).

Energy Technology Data Exchange (ETDEWEB)

Exploration for oil shale in Queensland between June 1986 and July 1987 continued over 12 deposits ranging in age from Permian to Tertiary. The total estimated resource of shale oil contained within these deposits is 4479 GL (28.2 billion barrels). 4 refs., 1 fig., 1 tab.

International Nuclear Information System (INIS)

The mobilization and distribution of previously deposited "2"3"9Pu was compared in pregnant rats (15 and 20 days of gestation) and nonpregnant controls. Pregnancy had little effect on "2"3"9Pu tissue burdens and only minimal activity appeared in the fetoplacental unit. Marked differences were observed in tracer "4"5Ca deposition patterns between the experimental groups.

Energy Technology Data Exchange (ETDEWEB)

In accordance with the comprehensive plan in the eleventh five-year period the main content of prospecting and exploration on land in Axerbaidzhan by the Axneft' association will be done in the central and Western regions of the republic, where Paleogene-Mesozoic deposits will be inspected. Discussed in detail are the directions and volumes of prospecting and exploration in individual regions of Azerbaidzhan. They are determined with consideration of the degree of exploration of the earth's interior, the prospects for the deposits comprising them, and the development of the resources of oil.

Energy Technology Data Exchange (ETDEWEB)

The Buntsandstein facies outcrops along a 12 km long, 150 m thick cuesta near Ayllon (Central Spain). The outcrop study is based on vertical sedimentological sections and continuous photo paneling, and demonstrates the presence of two depositional systems: an alluvial fan system in the lower half of the outcrop, and a straight and braided river system in the upper part of the outcrop. This overall evolution is probably related to base-level fall to base-level rise cycle, in which the reservoir architecture is linked to genetic units stacking pattern: during the base-level fall, the alluvial fan is prograding over sand flat and sandy alluvial plain deposits. Coarse and pebbly proximal sandsheets are interbedded with finer reddish distal deposits. Reservoirs units are laterally continuous, but silty alluvial plain deposits constitute vertical permeability barriers, during base-level stillstand, erosive ...

British Library Electronic Table of Contents (United Kingdom)

Deposition of CN-based films by a novel version of active screen plasma nitriding, aiming at surface modification of polymers, is reported. The approach relies on the use of pure graphite as the grid material, which was found to act both as an active screen and as a dry source of carbon atoms for the synthesis of thin films consisting mainly of a stoichiometric CN layer with columnar-type structure and dome-like nanostructured morphology.

Energy Technology Data Exchange (ETDEWEB)

This paper examines the correlation between mechanical properties and the density, phase, and hydrogen content of deposited alumina layers, and compares them to those of sapphire and amorphous alumina synthesized through ion-beam irradiation of sapphire. Alumina films were deposited using electron beam evaporation of aluminum and co-bombardment with O{sub 2}{sup +} ions (30-230 eV) from an electron cyclotron resonance (ECR) plasma. The H content and phase were controlled by varying the deposition temperature and the ion energy. Sapphire was amorphized at 84 K by irradiation with Al and O ions (in stoichiometric ratio) to a defect level of 4 dpa in order to form an amorphous layer 370 nm thick. Nanoindentation was performed to determine the elastic modulus, yield strength and hardness of all materials. Sapphire and amorphized sapphire have a higher density and exhibit superior mechanical properties in comparison to the ...

International Nuclear Information System (INIS)

Highly conductive biaxially textured RuO_2 thin films were deposited on technically important SiO_2/Si substrates by pulsed laser deposition, where yttria-stabilized zirconia (YSZ) produced by ion-beam-assisted-deposition (IBAD) was used as a template to enhance the biaxial texture of RuO_2 on SiO_2/Si. The biaxially oriented RuO_2 had a room-temperature resistivity of 37 #mu##OMEGA#-cm and residual resistivity ratio above 2. We then deposited Ba_0_._5Sr_0_._5TiO_3 thin films on RuO_2/IBAD-YSZ/SiO_2/Si. The Ba_0_._5Sr_0_._5TiO_3 had a pure (111) orientation normal to the substrate surface and a dielectric constant above 360 at 100 kHz. copyright 1998 Materials Research Society.

International Nuclear Information System (INIS)

The microstructure, microhardness, corrosion, and wear resistance of d.c.-plated Ni electrodeposits prepared from different types of electrolysing Watts-type baths, without or with organic compounds, ceramic powder - SiC and polymer - polytetrafluoroethylene (PTFE), on Cu substrate, which was subsequently removed from the deposits, were investigated. With the change of the type of bath, the deposit grain size was found to decrease markedly, e.g. deposits with an average grain size of about 50 nm could be produced from the bath containing 45 g/dm"3 Ni"2"+ ions, 5 g/dm"3 SiC, and 20 g/dm"3 PTFE. The surface morphology on the bath side of the electrode-posited Ni or Ni-SiC-PTFE foils was characteristic of the type of bath, and its roughness correlated well with the observed grain size. Microhardness and wear resistance increased with decreasing grain size, as expected. On discussing the factors controlling ...

CERN Document Server

An in-plane uniaxial magnetic anisotropy has been observed in thin Co films normally deposited onto obliquely sputtered Ta and Pt underlayers. Associated with this anisotropy is an augmented easy axis coercivity. The in-plane easy axis is, in most cases, perpendicular to the incident deposition plane. Microstructural results indicate that grains are well connected along the magnetic easy axis but are separated by long continuous voids along the hard axis, which is ascribed to a geometric shadowing effect due to the oblique incidence deposition of the underlayer. Hence, the magnetic anisotropy mimics the film growth anisotropy. It is therefore believed that the observed magnetic properties are due to magnetostatic shape anisotropy effects. In-plane coercivity and anisotropy field are shown to increase with underlayer deposition angle, underlayer thickness and magnetic layer thickness. The choice of ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this project were to investigate the dynamic behavior of peat and to evaluate the influence of that behavior on the dynamic response of peat deposits. During the course of the research, the objectives were expanded to explore the effects of strong earthquake shaking on pile foundations embedded in peat deposits. An experimental investigation was undertaken using samples of a peat deposit typical of many large peat deposits in western Washington. A series of ground response analyses was performed to investigate the seismic response of peat deposits. Three vertical profiles through Mercer Slough were analyzed using both equivalent linear and nonlinear ground response analyses. The analyses showed that the soft nature of the Mercer Slough peat would produce amplification of the long-period components of an earthquake ground motion. Comparison of the equivalent linear ...

Energy Technology Data Exchange (ETDEWEB)

In this work we present an ultra-low temperature method for the oxidation of an amorphous silicon-carbide-nitride (SiCN) material. The SiCN is deposited on silicon substrates by plasma enhanced chemical vapor deposition using CH{sub 4}, SiH{sub 4}, and N{sub 2} chemistry. The physical and chemical properties are characterized for the as-deposited SiCN and post-oxidized films are discussed. The SiCN film is exposed to oxygen plasma, where it undergoes a chemical transformation into a binary SiO{sub 2} material system. A 1.7 nm/min oxidation rate is typical for this process and compares favorably to oxidation methods utilizing much higher temperatures. The substrate temperature remains extremely low throughout the oxidation process, T{sub s} < 200 deg. C. Changes in film stress, optical constants, film thickness, surface roughness, and film density are measured. Chemical analysis by X-ray photoelectron spectroscopy is ...

Energy Technology Data Exchange (ETDEWEB)

Ordos Basin, the second largest sedimentary basin in China, contains enormous natural gas resources. Each of the four giant gas fields discovered so far in this basin (i.e., Sulige, Yulin, Wushenqi and Jingbian) has over 100 billion cubic meters (bcm) or 3.53 trillion cubic feet (tcf) of proven gas reserves. This study examines the stable carbon isotope data of 125 gas samples collected from the four giant gas fields in the Ordos Basin. Source rocks in the Upper Paleozoic coal measures are suggested by the generally high {delta}{sup 13}C values of C{sub 2}-C{sub 4} gaseous hydrocarbons in the gases from the Sulige, Yulin and Wushenqi gas fields. The {delta}{sup 13}C values of methane, benzene and toluene in gases from the Lower Paleozoic reservoirs of the Jingbian field indicate a significant contribution from humic source rocks, as they are similar to those in the Upper Paleozoic reservoirs of the Sulige, Yulin and Wushenqi gas fields. ...

Energy Technology Data Exchange (ETDEWEB)

The Maybell uranium mill tailings site is 25 miles (mi) (40 kilometers [km]) west of the town of Craig, Colorado, in Moffat County, in the northwestern part of the state. The unincorporated town of Maybell is 5 road mi (8 km) southwest of the site. The designated site covers approximately 110 acres (ac) (45 hectares [ha]) and consists of a concave-shaped tailings pile and rubble from the demolition of the mill buildings buried in the former mill area. Contaminated materials at the Maybell processing site include the tailings pile, which has an average depth of 20 feet (ft) (6 meters [m]) and contains 2.8 million cubic yards (yd{sup 3}) (2.1 million cubic meters [m{sup 3}]) of tailings. The former mill processing area is on the north side of the site and contains 20,000 yd{sup 3} (15,000 m{sup 3}) of contaminated demolition debris. Off-pile contamination is present and includes areas adjacent to the tailings pile, as well as contamination ...

International Nuclear Information System (INIS)

We succeeded in synthesizing a new cubic intermetallic compound PrCu_4Ag in a fcc structure. Measurements of X-ray diffraction, magnetic susceptibility, magnetization, specific heat, electrical resistivity, thermal expansion, and elastic constants have been performed on single crystals of PrCu_4Ag. A maximum value of #chi#(T) with a corresponding peak in C(T) suggests that an antiferromagnetic phase transition occurs at T_N=2.4 K, where a sudden decrease in #rho#_4_f(T) and a sharp peak in the thermal expansion coefficient #alpha#(T) were observed. Characteristic Curie-type softening was observed in the temperature dependence of the transverse mode for (C_1_1 - C_1_2)/2 and C_4_4 from 70 K down to T_N, which implies that the crystalline electric field (CEF) ground state is the magnetic triplet #GAMMA#_5. The anisotropic properties in M(T,H) and C(T,H) are studied when the external magnetic field is applied in the <100>, <110>, and <111> ...

International Nuclear Information System (INIS)

Half-Heusler phases XYZ (Pearson symbol cF12) are chemically versatile and rich in physical properties. The half-Heusler phase in the Fe-Zn-Sb ternary system was reported in the year 2000. In this work, two new ternary phases are identified in the vicinity of the equiatomic composition FeZnSb in the same system: Fe1-xZnSb (tetragonal, space group P4/nmm, Pearson symbol tP6-?, Z=2: a=4.1113(6) A, c=6.0127(12) A for x=0.08 (1), and a=4.1274(6) A, c=6.0068(12) A for x=0.12 (2)); and Fe7.87Zn6.72Sb8 (Fe0.98Zn0.84Sb) (3) (cubic, space group Fm-3m, Pearson symbol cF96-?, Z=4, a=11.690(13) A). 1 and 2 crystallize in the PbFCl-type structure, and 3 adopts a unique 2x2x2 supercell of a normal half-Heusler structure. The structures of both the tetragonal and cubic phases can be described as assemblies of half-Heusler structure related subunits. Electrical resistivity measurement on the pure sample of 2 shows it has metallic-like behavior, and its thermal ...

Energy Technology Data Exchange (ETDEWEB)

Three blocks of non-welded tuff, one nominally one cubic foot (trial block) and the other two, nominally one cubic metre (1 m{sup 3}), were excavated from the Busted Butte Test Facility on the Nevada Test Site and transported to the Atomic Energy of Canada Limited Whiteshell Laboratories in Pinawa, Manitoba. The trial block and one of the 1-m{sup 3} blocks were used for unsaturated flow experiments. The remaining 1-m{sup 3} block is being used for saturated flow experiments and will be reported on separately. After a vertical flow of synthetic transport solution was set up under unsaturated conditions, a suite of conservative and chemically reactive radionuclide tracers was injected at volumetric flow rates of 20 mL/hr in the trial block, and 10 mL/hr in the 1-m{sup 3} block. The duration of the migration experiment in the trial block was 87 days, while the migration experiment in the 1-m{sup 3} block was continuing after 600 days. Results ...

Energy Technology Data Exchange (ETDEWEB)

The growth of stoichiometric and non-stoichiometric silicon nitride films was studied experimentally on 100 mm silicon wafers by batch depositions from the dichlorosilane (SiH{sub 2}Cl{sub 2})-ammonia (NH{sub 3}) system in a hot-wall horizontal low pressure chemical vapor deposition (LPCVD) reactor. The growth kinetics were discussed in terms of the Langmuir adsorption isotherm. The kinetic parameters were determined by comparing the experimental data with a one-dimensional simulation model. The decomposition of NH{sub 3} at high temperatures was included in the simulation procedure. When the SiH{sub 2}Cl{sub 2}:NH{sub 3} ratios were greater than 1.5, a quantity higher than the thermodynamic critical values above which Si-rich nitride films begin to deposit, various SiN{sub x} films with x < 4/3 were obtained. The composition of the SiN{sub x} films was found to vary along the LPCVD reactor. The film stoichiometry was ...

International Nuclear Information System (INIS)

Crystalline and non-crystalline iron oxide (#alpha#-Fe_2O_3) thin films were obtained by spray pyrolysis onto glass substrate at different temperatures. The results of X-ray diffraction showed that with increasing the deposition time, the film structure changed from non-crystalline to crystalline at the same substrate temperature. At different substrate temperatures and low deposition times (5 min), iron oxide appears almost in non-crystalline form. With rising the substrate temperature and deposition time, the crystallinity was improved. The effect of substrate temperature as well as deposition time on the optical features (absorption coefficient and bandgap) and optical constants of these films has been investigated. Optical constants of the films were determined from spectrophotometric measurement of reflectance and transmittance. Analysis of the results showed that, for non-crystalline iron oxide ...

Energy Technology Data Exchange (ETDEWEB)

Over one-third of Canada's coal resources occurs in the southern Canadian Rocky Mountains, with major deposits in the Front Ranges, Inner Foothills and Outer Foothills. In the Front Ranges, deposits of metallurgical and thermal, high-volatile bituminous to semi-anthracite coal occur in the Late Jurassic-Early Cretaceous Mist Mountain Formation. In the Inner Foothills of northeastern British Columbia and west-central Alberta, resources of metallurgical and thermal medium- and low-volatile bituminous coal occur in Early Cretaceous strata of the Gething and Gates Formations. In the Outer Foothills resources of thermal, high-volatile bituminous coal occur in Late Cretaceous and Paleocene strata of the Belly River Coalspur and Paskapoo Formations. The major deposits of the Front Ranges and Inner Foothills accumulated within the coastal plains of the Fernie and Moosebar-Clearwater seas. Shorelines prograded to the north ...

British Library Electronic Table of Contents (United Kingdom)

Nanocrystalline chromium oxynitride films were deposited by reactive RF magnetron sputtering of metallic chromium target in argon and helium atmospheres. The paper deals with consequence of increase in oxygen partial pressure on structural, hydrophobic and optical properties of chromium oxynitride films. The film stoichiometry changes from CrN and Cr2O3 to only Cr2O3 with increase in oxygen partial pressure as evident from X-Ray Diffraction analysis in both cases. The average crystallite size decreases with increase in oxygen partial pressure for both gas atmospheres. The thickness calculated from transmission data and surface profilometer are in good harmony with each other. The deposited films are hydrophobic by nature and the contact angle of the films varies as a function of surface ro...

British Library Electronic Table of Contents (United Kingdom)

The performance of Ag-promoted Pd/Al2O3 catalysts, which were prepared by the selective deposition of Ag onto Pd using a surface redox (SR) method, during acetylene hydrogenation was compared with that of catalysts prepared by impregnation. The Pd surface was more effectively modified with Ag added by SR, even when small amounts of Ag were added. The catalyst prepared by SR showed a higher ethylene selectivity than the one prepared by impregnation, because SR allowed both the preferential deposition of Ag on the low-coordination sites of Pd and a greater electronic modification of Pd by Ag.

International Nuclear Information System (INIS)

Yttria stabilized zirconia (YSZ) with 8 mol% Y was deposited by reactive magnetron sputtering onto oxidized (100) silicon substrates. It was possible to switch film texture from (111) to (200) by applying a strong RF substrate bias. Transmission electron microscopy showed that the film deposited under bias is porous and exhibits nanoscaled grains, whereas the film deposited without bias is dense and columnar. The ionic conductivity as a function of temperature revealed an activation energy of 1.04 eV. The mechanical stress could be tuned to low values by thermal post-annealing. Using the dense (111) film as electrolyte layer, and the porous (200) film as an interlayer to a porous Pt anode, an open circuit voltage of 0.85 V was obtained in a micro machined fuel cell structure.

International Nuclear Information System (INIS)

The in-depth distribution of phases in c-BN films deposited by Ion Beam Assisted Deposition (IBAD) at two different ion energy values (300 and 600 eV) was investigated using the quantitative IR transmission measurements and the HREM technique. Whatever the value of the studied ion energies, the characteristic layered morphology of c-BN film is observed including the interfacial sp"2 zone between the substrate and the c-BN volume. In the case of 600 eV ion energy, this interfacial zone is less well-defined in comparison with 300 eV ion energy and the corresponding thickness is more important. Furthermore, the h-BN phase is more diluted within the c-BN film volume showing that the purest phase concentration of c-BN is found for the lowest ion energy, i.e., 300 eV.

Energy Technology Data Exchange (ETDEWEB)

The Model of Acidification of Groundwaters in Catchments (MAGIC) was used to simulate the impact of acidifying deposition and future recovery at the Gaardsjoen Covered Catchment Experiment, at a number of hypothetical stations defined by statistical variation of the Gaardsjoen data and at 20 forest monitoring sites in Southern Sweden. For the future predictions a decrease of sulphur deposition of more than 70% was assumed. This assumption is based on a full implementation of the agreements made under the second sulphur protocol from 1994. The modelled impact of reduced deposition on the soils and on the runoff waters was discussed. To complement the discussion on long-term trends in future run-off chemistry, data from Gaardsjoen has been used to asses the risk for short-term acid runoff episodes 26 refs, 23 figs, 7 tabs

Energy Technology Data Exchange (ETDEWEB)

Microcrystalline silicon carbide ({mu}c-SiC) was prepared at low substrate temperatures using Hot Wire chemical vapor deposition (HWCVD). High crystalline volume fractions were achieved at high hydrogen dilution and high deposition pressure. Without intentional doping, such material shows high dark conductivity and high optical absorption below the band gap. The material prepared at low deposition pressure or low hydrogen dilution, on the other hand, shows much lower conductivity and sub-gap absorption, but high spin densities up to 5 x 10{sup 19} cm{sup -3}. This high absorption can be attributed to free carriers, different to {mu}c-Si:H where a correlation between the sub-gap absorption and the spin density is observed.

British Library Electronic Table of Contents (United Kingdom)

Palladium deposition on Pt(110) electrodes was studied. Differently from Pt(111) and Pt(100), first and further layers cannot be distinguished in this case only through the voltammetric behavior of hydrogen and anion adsorption. The potential of zero total charge (pztc) was determined as a function of the amount of deposited Pd using CO charge displacement experiments and voltammetric curves. The variation of the voltammetric charge due to hydrogen and anion adsorption has been followed during Pd deposition. The voltammetric charge between 0.06 and 0.4V first decreases to a minimum, then increases and finally becomes stable, suggesting that the surface is finally covered with a Pd multilayer. The pztc and CO oxidation charge show similar behavior. CO oxidation, NO reduction and Cu UPD were...

Energy Technology Data Exchange (ETDEWEB)

TiB{sub 2} appears to be a promising material for the wear protection in various tribological systems, e.g. the diecasting of Al. This study focuses on the development of titanium boride coatings deposited by PACVD, a deposition method which is most suitable for the coating of substrates with complex shapes. All layers analysed are very smooth and exhibit a quasi-amorphous fracture surface. XRD and TEM analysis indicate a nanocrystalline structure with grain sizes in the order of 2 nm. The diffraction patterns can well be correlated to titanium diboride. WDS reveals an over stoichiometric B/Ti ratio. The layer hardness reaches the value of 33 GPa and the critical load in scratch tests rises to 35 N. Neither 100Cr6 nor Al as a counterpart in pin-on-disk tests leads to wear of the coating. (orig.)

Energy Technology Data Exchange (ETDEWEB)

A calorimetric sensor with several novel design features has been developed. These sensors will provide an accurate sampling of thermal power density and energy deposition from proton beams incident on target components of accelerator-based systems, such as the Accelerator Production of Tritium Project (APT) and the Spallation Neutron Source (SNS). A small, solid slug (volume = 0.347 cc) of target material is suspended by kevlar fibers and surrounded by an adiabatic enclosure in an insulating vacuum canister of stainless steel construction. The slug is in thermal contact with a low-mass, calibrated, 100-k{Omega} thermistor. Power deposition caused by the passage of radiation through the slug is calculated from the rate of temperature rise of the slug. The authors have chosen slugs composed of Pb, Al, and LiAl.

Energy Technology Data Exchange (ETDEWEB)

Carbon dioxide is receiving renewed interest as an efficient and environmentally safe refrigerant in a number of applications, including mobile air conditioning and heat pump systems, and hot water heat pumps. Compact heat exchangers for CO{sub 2} systems are designed with small-diameter tubing. The purpose of this study is therefore to provide a better basis for understanding and predicting heat transfer and pressure drop during flow vaporization of CO{sub 2} in microchannels. The ''unusual'' properties of carbon dioxide give heat transfer and two-phase flow characteristics that are very different from those of conventional refrigerants. Examples of these differences are the much higher pressure, the resulting high vapour density, a very low surface tension, and a low liquid viscosity. High pressure and low surface tension has a major effect on nucleate boiling characteristics, and earlier test data have shown a clear dominance ...

UK PubMed Central (United Kingdom)

Background and objectives: The pathogenesis of acquired nephrogenic systemic fibrosis recently described for patients with renal insufficiency and a history of exposition to gadolinium-based magnetic...Full Text Available

UK PubMed Central (United Kingdom)

Storage proteins are deposited into protein storage vacuoles (PSVs) during plant seed development and maturation and stably accumulate to high levels; subsequently, during germination the storage...Full Text Available

International Nuclear Information System (INIS)

The variation in the superconducting properties of various binary alloys of transition metal-germanium systems was surveyed by studying sputter deposited samples prepared under various conditions. The primary interest has been to study the formation of the stoichiometric A-15 compounds T_3Ge.

UK PubMed Central (United Kingdom)

If bone strength was the only requirement of skeleton, it could be achieved with bulk, but bone must also be light. During growth, bone modelling and remodelling optimize strength, by depositing bone...Full Text Available

Science.gov (United States)

Critical power at boiling transition is an important factor in a boiling water reactor (BWR) fuel bundle design. Boiling transition under high quality accounts for dryout as the result of the complete disappearance of film flow on a fuel rod. This liquid film vanishing process can be calculated by the liquid film model, which takes into account the evaporation due to heat from the rod surface, liquid film entrainment by steam flow, and liquid droplet deposition. It is known that spacers affect liquid film entrainment and liquid droplet deposition, so the detailed study of spacer effects on hydrodynamic characteristics is necessary for critical power prediction based on the film flow model. Many studies have been conducted to examine spacer effects on liquid film flow. However, most of them are restricted to simple test sections such as a rectangular conduit. There are a few reports on fuel bundle geometry; however the bundle studied was only a ...

Science.gov (United States)

Operating PWR units in the USA have experienced very severe corrosion of the tube support plate at the crevice between the tube and the support. This results in distortion of the plate and crushing of the tube (denting). The first task of this project required that currently available computational methods to estimate the pH attained by concentrating boiler water under various fault conditions such as condenser leakage of river waters and faulty operation of condensate polishing plant. Particular attention has been paid to systems in which sulfate predominates. In the second task, the mechanisms are discussed by which solutions become concentrated in porous deposits on a boiling heat transfer surface. It is concluded that more experimental data are needed to test the validity of existing models. High solution concentrations in the deposit may occur at a heat flux close to the critical value for drying out the base of the ...

International Nuclear Information System (INIS)

Iron oxide thin films have been obtained by spray pyrolysis using 100% methanolic and ethanolic solutions of iron tri-chloride. The films were deposited onto ITO-coated glass substrates. The preparative conditions have been optimized to obtain compact, pin-hole-free and smooth thin films which are adherent to the substrate. The structural, morphological and compositional characterizations have been carried out by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. The films deposited using ethanolic solution results into pure hematite; #alpha#-Fe_2O_3 thin films, however, films deposited using methanolic solution consists of hematite and maghemite-c phases of iron oxide. The films are nanocrystalline with particle size of 30-40 nm. The optical absorbance of the film was of the order of 10"5 cm"-"1. The optical band gap of films was found to be 2.26 and 2.20 eV for the films ...

UK PubMed Central (United Kingdom)

Platelet-derived growth factor (PDGF) is a potent moderator of soft tissue repair through induction of the inflammatory phase of repair and subsequent enhanced collagen deposition. We examined the effect...Full Text Available

International Nuclear Information System (INIS)

The electromagnetic field due to an air explosion is here studied: neutron and the gamma-rays, generated by neutronic reactions, deposit energy which ionizes atmosphere; recoil electrons are also created by gamma collisions. This data set allows to solve the Maxwell equations which manage the electromagnetic field. The TRIPOLI-2 code studies the coupled neutron-gamma transport in 3D- geometries by the Monte Carlo method. The code has been modified to calculate the photon energy deposited in matter and the recoil electron current created by Compton effect. The method is tested wiht a simple case; then neutron and gamma transport is studied in air kerma, deposited photon energy, electron current are calculated as functions of space and time and the contributions of the different neutronic reactions are separately evaluated. The calculations presented here are only part of studies about this subject. Developments will relate ...

Science.gov (United States)

A novel reactor combining a flame-deposited nanostructured titanium dioxide film and a set of embedded ceramic electrodes was designed, developed and tested for degradation of methyl tert-butyl ether (MTBE) in water. On applying a voltage to the ceramic electrodes, a surface coro...

International Science & Technology Center (ISTC)

Investigation of Interaction of Laser Radiation with Radioactive Deposits on the metal Surface and Creation of Experimental Stand for Development of Laser Technology for Remote Treatment of Materials Contaminated with Radioactive Substances at the Atomic Power Plants

UK PubMed Central (United Kingdom)

Intravascular coagulation, thrombosis, and fibrin deposition often produce tissue damage in allogeneic inflammatory reactions such as allograft rejection. The mechanisms which initiate blood clotting...Full Text Available

UK PubMed Central (United Kingdom)

Linking biological samples found at a crime scene with the actual crime event represents the most important aspect of forensic investigation, together with the identification of the sample donor. While...Full Text Available

UK PubMed Central (United Kingdom)

Geometric (HOMA) and magnetic (NICS) indices of aromaticity were estimated for aromatic rings of amino acids and nucleobases. Cartesian coordinates were taken directly either from PDB files deposited...Full Text Available

UK PubMed Central (United Kingdom)

A pure culture of an Agrobacterium sp. (deposited as ATCC 55002) that mineralizes the ferric chelate of EDTA (ferric-EDTA) was isolated by selective enrichment from a treatment facility...Full Text Available

UK PubMed Central (United Kingdom)

Molecular chaperones protect cells from the deleterious effects of protein misfolding and aggregation. Neurotoxicity of amyloid-beta (Aβ) aggregates and their deposition in senile plaques are...Full Text Available

Science.gov (United States)

Methods of acidizing a subterranean well formation, acidizing compositions, and sequestering additives for preventing the precipitation of metal compounds in the formation are described. Use of the methods and chemicals described should lead to improved formation permeability as compared to use of previous methods and chemicals. 12 claims.

British Library Electronic Table of Contents (United Kingdom)

Methods of X-ray diffraction and transmission electron microscopy were used to study the microstructure of dispersion-strengthened Cu-Al2O3 nanocomposites obtained by the method of simultaneous deposition of Cu and Al2O3 from the vapor phase. The effect of the size of particles of the oxide (Al2O3) and of their content on the electrical resistance of the composite has been considered. The results obtained make it possible to suppose that the main structural factor that determines the electrical resistance of the composite are nanodispersed particles of Al2O3 with a size of less than 20 nm.