WorldWideScience
2

Daytime Raman lidar measurements of water vapor during the ARM 1997 water vapor intensive observation period  

Energy Technology Data Exchange (ETDEWEB)

Because of the importance of water vapor, the ARM program initiated a series of three intensive operating periods (IOPs) at its CART (Cloud And Radiation Testbed) site. The goal of these IOPs is to improve and validate the state-of-the-art capabilities in measuring water vapor. To date, two of the planned three IOPs have occurred: the first was in September of 1996, with an emphasis on the lowest kilometer, while the second was conducted from September--October 1997 with a focus on both the upper troposphere and lowest kilometer. These IOPs provided an excellent opportunity to compare measurements from other systems with those made by the CART Raman lidar. This paper addresses primarily the daytime water vapor measurements made by the lidar system during the second of these IOPs.

1998-04-01

3

Turn-key Raman lidar for profiling atmospheric water vapor, clouds, and aerosols at the US Southern Great Plains Climate Study Site  

Energy Technology Data Exchange (ETDEWEB)

There are clearly identified scientific requirements for continuous profiling of atmospheric water vapor at the Department of Energy, Atmospheric Radiation Measurement program, Southern Great Plains CART (Cloud and Radiation Testbed) site in northern Oklahoma. Research conducted at several laboratories has demonstrated the suitability of Raman lidar for providing measurements that are an excellent match to those requirements. We have developed and installed a ruggedized Raman lidar system that resides permanently at the CART site, and that is computer automated to eliminate the requirements for operator interaction. In addition to the design goal of profiling water vapor through most of the troposphere during nighttime and through the boundary layer during daytime, the lidar provides quantitative characterizations of aerosols and clouds, including depolarization measurements for particle phase studies.

1997-12-31

4

Raman and SERS recognition of ?-carotene and haemoglobin fingerprints in human whole blood.  

Science.gov (United States)

The present work reports on Raman and Surface Enhanced Raman Scattering (SERS) vibrational fingerprints of ?-carotene and haemoglobin in fresh whole blood (i.e. right after blood test) with different laser excitations, i.e. visible (514 nm) and near-infrared (NIR, 785 nm). The use of colloidal silver nanoparticles significantly increases the Raman signal, thus providing a clear SERS spectrum of blood. The collected spectra have been examined and marker bands of ?-carotene and of the haem prosthetic group of haemoglobin have been found. In particular, the fundamental features of ?-carotene (514 nm excitation), blood proteins and haem molecules (785 nm excitation) were recognized and assigned. Moreover haemoglobin SERS signals can be identified and related with its oxygenation state (oxy-haemoglobin). The data reported show the prospects of Raman and SERS ...

2011-03-26

5

Buried-heterostructure semiconductor Raman laser with threshold pump power less than 1 W  

Energy Technology Data Exchange (ETDEWEB)

The low-power operation of a semiconductor buried-heterostructure Raman laser is reported. We are developing these devices for very wide-band optical communication in the terahertz frequency region. It has a structure with a GaP active layer and Al{sub {ital x}}Ga{sub 1{minus}{ital x}}P cladding layers, which are grown by the temperature-difference method under controlled vapor pressure. By making the stripe width 30--40 {mu}m, we have obtained a threshold pump power of 500 mW. A low-threshold semiconductor Raman laser can be pumped by semiconductor injection lasers. We have measured the optical loss of the waveguide and detected the contribution from scattering and leakage at heterointerfaces.

1989-12-01

6

Interpolating atmospheric water vapor delay by incorporating terrain elevation information  

British Library Electronic Table of Contents (United Kingdom)

In radio signal-based observing systems, such as Global Positioning System (GPS) and Interferometric Synthetic Aperture Radar (InSAR), the water vapor in the atmosphere will cause delays during the signal transmission. Such delays vary significantly with terrain elevation. In the case when atmospheric delays are to be eliminated from the measured raw signals, spatial interpolators may be needed. By taking advantage of available terrain elevation information during spatial interpolation process, the accuracy of the atmospheric delay mapping can be considerably improved. This paper first reviews three elevation-dependent water vapor interpolation models, i.e., the Best Linear Unbiased Estimator in combination with the water vapor Height Scaling Model (BLUE?+?HSM), the Best Linear Unbiased Es...

2011-01-01

7

Device for controlling water supply to nuclear reactor  

International Nuclear Information System (INIS)

Object: To smoothly control automatic water supply for realizing stable operation of a nuclear reactor by providing a flow rate limiting signal selection circuit and a preferential circuit in a water supply control device for a nuclear reactor wherein the speed of a recirculation pump may be changed in two-steps. Structure: Opening angle signals for a water supply regulating valve are controlled by a nuclear reactor water level signal, a vapor flow rate signal and a supplied water flow rate signal through an adder and an adjuster in response to a predetermined water level setting signal. When the water in the reactor is maintained at a predetermined level, a selection circuit receives a water pump condition signal for selecting one of the signals from a supplied water rate limiting ...

8

Atomic force microscopy and surface-enhanced Raman scattering detection of DNA based on DNA-nanoparticle complexes  

Energy Technology Data Exchange (ETDEWEB)

We report a simple method for the label-free detection of double-stranded DNA using surface-enhanced Raman scattering (SERS). We prepared cetyltrimethylammonium bromide (CTAB)-capped silver nanoparticles and a DNA-nanoparticle complex by adding silver nanoparticles to {lambda}-DNA solutions. In the present study, the utilization of CTAB-capped silver nanoparticles facilitates the electrostatic interaction between DNA molecules and silver nanoparticles; at the same time, the introduction of DNA avoids adding aggregating agent for the formation of nanoparticle aggregates to obtain large enhancement of DNA, because the DNA acts as both the probe molecules and aggregating agent of Ag nanoparticles. Atomic force microscopy (AFM) studies show that the morphology of DNA-Ag nanoparticle complexes seems to be determined by the concentrations of the DNA and the nanoparticles. Surface-enhanced Raman scattering (SERS) studies show that the morphology of ...

2009-03-25

9

PROBING NEAR-SURFACE ATMOSPHERIC TURBULENCE WITH LIDAR MEASUREMENTS AND HIGH-RESOLUTION HYDRODYNAMIC MODELS  

Energy Technology Data Exchange (ETDEWEB)

As lidar technology is able to provide fast data collection at a resolution of meters in an atmospheric volume, it is imperative to promote a modeling counterpart of the lidar capability. This paper describes an integrated capability based on data from a scanning water vapor lidar and a high-resolution hydrodynamic model (HIGRAD) equipped with a visualization routine (VIEWER) that simulates the lidar scanning. The purpose is to better understand the spatial and temporal representativeness of the lidar measurements and, in turn, to extend their utility in studying turbulence fields in the atmospheric boundary layer. Raman lidar water vapor data collected over the Pacific warm pool and the simulations with the HIGRAD code are used for identifying the underlying physics and potential aliasing effects of spatially resolved lidar measurements. This capability also helps improve the trade-off between spatial-temporal resolution ...

2000-11-01

10

Demonstration of a Tunable-Bandwidth White Light Interferometer using Anomalous Dispersion in Atomic Vapor  

CERN Document Server

The concept of the 'white-light cavity' has recently generated considerable research interest in the context of gravitational wave detection. Cavity designs are proposed using negative (or anomalous) dispersion in an intracavity medium to make the cavity resonate over a large range of frequencies and still maintain a high cavity build-up. This paper presents the first experimental attempt and demonstration of white-light effect in a meter long ring cavity using an intracavity atomic medium. The medium's negative dispersion is caused by bi-frequency Raman gain in an atomic vapor cell. Although the white light condition was not perfectly achieved and improvements in experimental control are still desirable, significantly broad cavity response over bandwidth greater than 20 MHz has been observed. These devices will have potential applications in new generation laser interferometer gravitational wave detectors.

2006-01-01

11

One-step synthesis of reduced graphite oxide-silver nanocomposite  

British Library Electronic Table of Contents (United Kingdom)

Here, a general approach for the preparation of reduced graphite oxide (rGO)-silver nanocomposite has been investigated. Graphite oxide (GO) sheets are used as the nanoscale substrates for the formation of rGO-silver composite. GO sheets and Ag ions can be reduced at the same time, under a mild condition using l-ascorbic acid (l-AA) as reducing agent. This simple approach should find practical applications in the production of rGO-silver nanocomposite. The SEM analysis indicates that the silver particles are dispersed on graphene sheets. Raman signals of rGO in the composite are increased by the attached silver nanoparticles, displaying surface-enhanced Raman scattering activity. The degree of enhancement can be adjusted by varying the quantity of silver nanoparticles in the composite. In ...

2011-01-01

12

Adding channels with PSBT format at 40Gbit/s in an existing 10Gbit/s optical network  

British Library Electronic Table of Contents (United Kingdom)

Until recently, the wavelength-division-multiplexed (WDM) transmission system has reached record capacities and distances due to innovations such as FEC (Forward Error Correction), distributed Raman amplification, new transmission fiber and advanced optical format. Optical-communication systems exclusively employed conventional On-Off Keying signals in either Non-Return-To-Zero (NRZ) or Return-To-Zero (RZ) format. Recently a number of advanced modulation formats have attracted attention. Some of these formats carry information through On-Off-Keying but also modulate the optical phase in order to enhance the robustness of signal to chromatic dispersion, optical filtering and non-linearities. Through extensive sets of simulation results, we showed that it is possible to replace a channel wit...

2011-01-01

13

Crystal growth of epitaxial CVD diamond using [sup 13]C isotope and characterization of dislocations by Raman spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

[sup 13]C epitaxial diamond films have been grown on [sup 12]C-type IIb diamond substrates doped with boron, using electron assisted chemical vapor deposition. The relation between etch pits to dislocations in [sup 13]C diamond film and the broadening of the first-order Raman peak was examined. The reactant gas was [sup 13]CH[sub 4] of > 99% purity. The substrate temperature was varied from 943 to 1300 C. The uneven surface morphology was confirmed by atomic force microscopy (AFM) and laser microscopy. From 943 to 1030 C, etch pit rows along left angle 100 right angle were observed. At 991 C, the etch pit density on a row was 3300 to 5000 pits/cm. The Ar[sup +] laser beam was focused on a transparent area near the row of etch pits, where the boron impurity of the substrate is less than several 10 ppm. The first-order Raman line of [sup 13]C epitaxial diamond film was broadened to 3.6-4.0 cm[sup -1]. The line broadening ...

1993-03-01

14

Organometallic vapor phase epitaxial growth of (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P and its heterostructures  

International Nuclear Information System (INIS)

The (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P material system, lattice matched to GaAs substrates, is useful for visible laser diodes. Here, low pressure organometallic vapor phase epitaxial growth of Ga/sub 0.5/In/sub 0.5/P and (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P is examined. Epitaxial layers of bulk materials are characterized using photoluminescence, electroreflectance, Raman scattering spectroscopy, and surface morphology studies to determine lattice match and optimum growth conditions. Lattice matching at the growth temperature produces featureless growth surfaces, while lattice matching at room temperatures results in minimum photoluminescence linewidth but cracked surface due to tensile strain during growth. Raman scattering spectra of the quaternary reveal a three-mode structure, with spectral peaks due to GaP-like, in P-like, and AIP-like LO phonons. Additionally, (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub ...

15

Organometallic vapor phase epitaxial growth of (Al/sub x/Ga/sub 1-x/)/sub 0. 5/In/sub 0. 5/P and its heterostructures  

Science.gov (United States)

The (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P material system, lattice matched to GaAs substrates, is useful for visible laser diodes. Here, low pressure organometallic vapor phase epitaxial growth of Ga/sub 0.5/In/sub 0.5/P and (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P is examined. Epitaxial layers of bulk materials are characterized using photoluminescence, electroreflectance, Raman scattering spectroscopy, and surface morphology studies to determine lattice match and optimum growth conditions. Lattice matching at the growth temperature produces featureless growth surfaces, while lattice matching at room temperatures results in minimum photoluminescence linewidth but cracked surface due to tensile strain during growth. Raman scattering spectra of the quaternary reveal a three-mode structure, with spectral peaks due to GaP-like, in P-like, and AIP-like LO phonons. Additionally, (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub ...

1988-09-01

16

Radiochemical and Raman spectroscopy study of the nature of adsorbed layers on a silver electrode  

International Nuclear Information System (INIS)

The structure of the layers formed on a silver electrode by the adsorption of pyridine, Cl"-, CN"- and SO_4"2"- is discussed. A comparison of the amount of the species adsorbed with their Raman spectra shows that there is no simple relation between the species concentration and the enhancement of the Raman intensity. Furthermore, the inhomogeneity of the layers is shown by Raman microscopy observations. These results lead the authors to propose the formation of a new species stabilized in the colloidal silver layer. The Raman enhancement could be explained by the existence of a resonance effect. (Auth.).

17

Experimental investigation of wall static pressure fluctuations in parallel boiling flow  

International Nuclear Information System (INIS)

Measurements of the statistical characteristics of channel wall static pressure fluctuations in parallel one-component boiling flow are reported. The measurements span a wide range of local subcooling and vapor volume fraction, and correspond to flow regimes ranging from highly subcooled bubbly to saturated slug-annular. Vapor volume fraction measurements at the pressure measurement station are also reported in conjunction with visual observation of the flow structure. Variation of static pressure fluctuation intensity and spectral content with local thermal-hydraulic condition is demonstrated. Finally, it is suggested that diagnosis of local two-phase flow regime on the basis of (i) statistical characteristics of the pressure data, and (ii) time trace of pressure signal, may be possible. 15 refs.

1980-01-01

18

Hybridization and Modification of the Ni/C{sub 60} Composites  

Science.gov (United States)

Hybridization and thermal evolution of the Ni+C{sub 60} composites, deposited on Si(001) at room temperature, were studied using Scanning Electron Microscopy, {mu}-Raman spectroscopy and Rutherford Backscattering. As-deposited, the hybrid films exhibited a granular nano-structure with Ni nano-particles encapsulated in C{sub 60} polymerized rinds. The Ni and C (C{sub 60}) distributions in a top layer were found homogeneous with a stable Ni/C (C{sub 60}) ratio; in the larger depth the distributions were inhomogeneous and their ratio dramatically varied. At elevated temperatures, all structural parameters were changed. In the subsurface layer Ni- and C (C{sub 60})-rich zones were formed (due to the induced phase separation), C{sub 60}-molecules decayed and their fragments were transformed into amorphous carbon (a-C). The free volume distribution of the stressed hybrid matter was analyzed by the Hg marker that (in a form of vapors) in-diffused in ...

2009-03-10

19

Water in polymer membranes. 4. Raman scattering from cellulose acetate films  

Energy Technology Data Exchange (ETDEWEB)

Raman scattering was observed from thin film optical waveguides of cellulose acetate exposed to water vapor from 0% to 100% relative humidity (RH), and from dilute solutions of water in methyl acetate. Spectra of cellulose acetate (CA398, 39.8% acetyl) at low RH and cellulose triacetate (CTA) at low and high RH are consistent with the presence of water monomers that are weakly hydrogen bonded to acetyl C=O groups. Differences between the spectra of water in CA398 and CTA at low RH are attributed to sequential hydrogen bonding involving OH groups in CA398. At high RH, CA398 and CTA (to a lesser extent) show bands attributed to water/water interactions that are similar to those found in sequentially hydrogen-bonded hydrates. CA398 films that are annealed at high temperatures exhibit decreased water/water interactions at high RH. Exposure of CA398 films to D/sub 2/O converts > 90% of all polymer OH groups to OD groups. This indicates that water ...

1985-01-17

20

PHYSICAL VAPOR DEPOSITION APPARATUS  

J-STORE (Japan)

Full Text Available

2007-09-14

21

Observation of multiorder coherent Raman sidebands in solid hydrogen film  

Energy Technology Data Exchange (ETDEWEB)

We investigated the Raman coherence characteristics of a solid hydrogen film deposited on a sapphire substrate held at 5.3 K. Using Raman coherence prepared with two single-frequency pulsed lasers, we generated the multiorder coherent Raman sidebands in solid hydrogen film. The highorder Raman sidebands were obtained under strong pumping intensities (>= 230 MW/cm{sup 2}). The generated anti-Stokes(AS)-Raman sidebands extend from the ultraviolet (292 nm for the AS5 band) to the visible (565 nm for the AS1 band) region. The multiorder Raman sideband generation is found to be due to the parametric coupling of pump and coupling lasers. The frequency conversion efficiency from pumping beams to the first AS-Raman sideband shows a maximum (14 %) at a pumping intensity of 360 MW/cm{sup 2}. From an experiment that makes the multimode probe ...

2004-07-15

22

Observation of multiorder coherent Raman sidebands in solid hydrogen film  

International Nuclear Information System (INIS)

We investigated the Raman coherence characteristics of a solid hydrogen film deposited on a sapphire substrate held at 5.3 K. Using Raman coherence prepared with two single-frequency pulsed lasers, we generated the multiorder coherent Raman sidebands in solid hydrogen film. The highorder Raman sidebands were obtained under strong pumping intensities (? 230 MW/cm2). The generated anti-Stokes(AS)-Raman sidebands extend from the ultraviolet (292 nm for the AS5 band) to the visible (565 nm for the AS1 band) region. The multiorder Raman sideband generation is found to be due to the parametric coupling of pump and coupling lasers. The frequency conversion efficiency from pumping beams to the first AS-Raman sideband shows a maximum (14 %) at a pumping intensity of 360 MW/cm2. From an experiment that makes the multimode probe beam beat with the ...

2004-07-01

23

Optimal dynamic detection of explosives  

Energy Technology Data Exchange (ETDEWEB)

The detection of explosives is a notoriously difficult problem, especially at stand-off distances, due to their (generally) low vapor pressure, environmental and matrix interferences, and packaging. We are exploring optimal dynamic detection to exploit the best capabilities of recent advances in laser technology and recent discoveries in optimal shaping of laser pulses for control of molecular processes to significantly enhance the standoff detection of explosives. The core of the ODD-Ex technique is the introduction of optimally shaped laser pulses to simultaneously enhance sensitivity of explosives signatures while reducing the influence of noise and the signals from background interferents in the field (increase selectivity). These goals are being addressed by operating in an optimal nonlinear fashion, typically with a single shaped laser pulse inherently containing within it coherently locked control and probe sub-pulses. With sufficient ...

2009-01-01

24

Resonance Raman enhancement of phenyl ring vibrational modes in phenyl iron complex of myoglobin.  

UK PubMed Central (United Kingdom)

Resonance Raman spectra are reported for the organometallic phenyl-FeIII complexes of horse heart myoglobin. We observed the resonance enhancement of the ring vibrational modes of the bound phenyl group....Full Text Available

1990-04-01

25

Remote sensing of the atmosphere by resonance Raman LIDAR  

Energy Technology Data Exchange (ETDEWEB)

When in resonance, Raman scattering exhibits strong enhancement ranging from four to six orders of magnitude. This physical phenomenon has been applied to remote sensing of the Earth`s atmosphere. With a 16 inch Cassegrain telescope and spectrometer/ CCD-detector system, 70-150 ppm-m of SO{sub 2} in the atmosphere has been detected at a distance of 0.5 kilometer. This system can be used to detect/monitor chemical effluence in the atmosphere by their unique Raman fingerprints. Experimental result together with detailed resonance Raman and atmospheric laser propagation effects will be discussed.

1994-12-01

26

Lateral optical confinement of the heterostructure semiconductor Raman laser  

Science.gov (United States)

This letter describes the first lasing experiment of the heterostructure semiconductor Raman laser with lateral confinement of both the Stokes and pump fields. It has a GaP Raman active layer with thickness of 10 ..mu..m and Al/sub 0.1/Ga/sub 0.9/P cladding layers. The stripe of the active layer has been fabricated by a plasma etching technique. Steps should be taken to realize the semiconductor Raman laser pumped by an injection laser, applicable to wideband optical communication.

1987-11-02

27

Applications of infrared and Raman spectroscopy in industry  

Energy Technology Data Exchange (ETDEWEB)

There have been many recent explosive advances in both IR and Raman spectroscopy which have developed in response to industrial problems of increasing complexity. Probably the biggest factor in these advances has been computerization, which has contributed not only to substantial improvements in data handling but to enormous gains in sensitivities of analyses as well. In this paper numerous examples of Raman and IR applications in industry are given using many of these recent advances, including in-situ techniques, microprobe analyses, unusual combinations of instruments - i.e., hyphenated methods - and new sample handling techniques. The bright future of FT-IR and Raman spectroscopy is also briefly discussed.

1986-07-01

29

Fluid temperature measurement technique by using Raman scattering  

Energy Technology Data Exchange (ETDEWEB)

Temperature measurement technique by using Raman scattering was developed for the liquid water at temperature of 20 - 90 degree C and atmospheric pressure. Strong relationship between Raman scattering characteristics and liquid temperature change was observed. Various kinds of measurement techniques, such as Peak Intensity, Peak Wavelength, FWHM (Full Width at Half Maximum), PMCR ( Polymer Monomer Concentration RAte), TSIR (Temperature Sensitive Intensity Ratio), IDIA (Integral Difference Intensity Area) were tested. TSIR has the highest accuracy in mean error or 0.1 deg C and standard deviation of 0.1248 deg C. This report is one of the results in developing process of Raman temperature measurement technique. Next research step is to develop Raman temperature measurement technique at the high temperature and high pressure conditions in single or two phase flows. (author). 13 refs., 3 tabs., 38 figs.

1999-06-01

30

Uranium isotopic assay instrument  

International Nuclear Information System (INIS)

Full text: The isotopic assay instrument under development at Pacific Northwest National Laboratory (PNNL) is capable of rapid prescreening to detect small and rare particles containing high concentrations of uranium in a heterogeneous sample. The isotopic measurement concept is based on laser vaporization of solid samples followed by sensitive isotope-specific detection using either uranium atomic fluorescence emission or uranium atomic absorbance. Both isotopes are measured concurrently, following a single ablation laser pulse using two external-cavity violet diode lasers. The simultaneous measurement of both isotopes enables the correlation of the fluorescence and absorbance signals on a shot-to-shot basis. This measurement approach demonstrated negligible channel crosstalk between isotopes. Scanning the heterogeneous samples provides high-resolution imagery of sample isotopic fluorescence and absorbance. Isotopically selective excitation of ...

2006-10-16

31

Tunable VUV generation by anti-Stokes stimulated Raman conversion of XeCl laser radiation  

Energy Technology Data Exchange (ETDEWEB)

This paper reports on the results of experiments into efficient higher-order anti-Stokes Raman conversion of tunable short-pulse XeCl laser radiation. The maximum output energy of the pumping laser, in which the radiation of a frequency-doubled dye laser is amplified by two XeCl laser amplifiers, is 55 mJ with a pulse duration of 1 ns FWHM. Using hydrogen gas as a Raman medium, a series of anti-Stokes lines up to the 12th order (121.5 nm) is generated in the vacuum ultraviolet (VUV) region. 16 references.

1987-06-01

32

Phonon damping by and Raman scattering from interband electronic excitations in normal and superconducting A-15 compounds  

International Nuclear Information System (INIS)

Raman scattering measurements of the Esub(g) and Tsub(2g) optical phonons in V"3Si, Nb"3Sn, V"3Ge, Cr"3Si, V"3Pt, and Nb"3Pt are presented and discussed in terms of interaction with interband electronic excitations. Data on superconducting Nb"3Sn is presented and modifications to the phonon spectral function and the spectrum of Raman active interband electronic excitations in the superconducting state are discussed. (orig.).

33

Direct observation of intraionic and interconfigurational excitations in an intermediate-valence compound by Raman spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

Intraionic spin-orbit--split multiplet levels have been observed by electronic Raman scattering in the intermediate-valence compound EuPd/sub 2/Si/sub 2/. From the temperature dependence of the Raman peak positions and widths the interconfigurational excitation energy E/sub x/ and an upper limit of the interconfigurational mixing width T/sub f/, respectively, have been obtained. This is the first spectroscopic support for the underlying assumptions of the ionic interconfigurational fluctuation model that has been proposed to describe intermediate valence.

1985-01-21

34

Direct observation of intraionic and interconfigurational excitations in an intermediate-valence compound by Raman spectroscopy  

International Nuclear Information System (INIS)

Intraionic spin-orbit--split multiplet levels have been observed by electronic Raman scattering in the intermediate-valence compound EuPd_2Si_2. From the temperature dependence of the Raman peak positions and widths the interconfigurational excitation energy E/sub x/ and an upper limit of the interconfigurational mixing width T/sub f/, respectively, have been obtained. This is the first spectroscopic support for the underlying assumptions of the ionic interconfigurational fluctuation model that has been proposed to describe intermediate valence.

35

Raman Under Nitrogen. The High-Resolution Raman Spectroscopy of Crystalline Uranocene, Thorocene, and Ferrocene  

Science.gov (United States)

The utility of recording Raman spectroscopy under liquid nitrogen, a technique we call Raman Under Nitrogen (RUN), is demonstrated for ferrocene, uranocene and thorocene. Using RUN, low temperature (liquid nitrogen cooled) Raman spectra for these compounds exhibit higher resolution than previous studies and new vibrational features are reported. The first Raman spectra of crystalline uranocene at 77 K are reported using excitation from argon (5145 ) and krypton (6764 ) ion lasers. The spectra obtained showed bands corresponding to vibrational transitions at 212, 236, 259, 379, 753, 897, 1500, and 3042 cm-1 , assigned to ring-metal-ring stretching, ring-metal tilting, out-of-plane CCC bending, in-plane CCC bending, ring-breathing, C-H bending, CC stretching and CH stretching, respectively. The assigned vibrational bands are compared to those of uranocene in THF and thorocene. All vibrational frequencies ...

2004-02-08

36

Raman Under Nitrogen. The High-Resolution Raman Spectroscopy of Crystalline Uranocene, Thorocene, and Ferrocene  

International Nuclear Information System (INIS)

The utility of recording Raman spectroscopy under liquid nitrogen, a technique we call Raman Under Nitrogen (RUN), is demonstrated for ferrocene, uranocene and thorocene. Using RUN, low temperature (liquid nitrogen cooled) Raman spectra for these compounds exhibit higher resolution than previous studies and new vibrational features are reported. The first Raman spectra of crystalline uranocene at 77 K are reported using excitation from argon (5145 ) and krypton (6764 ) ion lasers. The spectra obtained showed bands corresponding to vibrational transitions at 212, 236, 259, 379, 753, 897, 1500, and 3042 cm-1 , assigned to ring-metal-ring stretching, ring-metal tilting, out-of-plane CCC bending, in-plane CCC bending, ring-breathing, C-H bending, CC stretching and CH stretching, respectively. The assigned vibrational bands are compared to those of uranocene in THF and thorocene. All vibrational frequencies ...

2004-02-08

37

(Hadamard transform imaging)  

Science.gov (United States)

This report describes the design of, and image reconstruction capacity of a Hadamard Raman Microscopic imager. Microscopy of benzoic acid and graphite electrodes, as well as electrophoretic blotting, are described. (CBS)

1990-01-01

38

Gas sensing behavior of SnO{sub 1.8}:Ag films composed of size-selected nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

Size-selected SnO{sub 1.8}:Ag mixed nanoparticle films have been prepared using a gas phase condensation method. Transmission electron microscopy showed that the applied size-selection technique yields well-defined, monodisperse and spherical SnO{sub 1.8} and Ag nanoparticles, both with a fixed diameter of 20 nm. The technique allows an independent variation of the particle size of both materials as well as the concentration of Ag. It allows to assess the influence of these parameters on the gas-sensing properties of the films, here for ethanol vapor in synthetic air. SnO{sub 1.8}:Ag nanoparticle films show optimal values of the sensor signal and response time at a Ag nanoparticle concentration of 5%. Due to the fact that the Ag nanoparticles are clearly distinct from the SnO{sub 1.8} nanoparticles in the film, the most probable mechanism leading to improved sensor properties is chemical sensitization via a spill-over effect.

2006-12-15

39

Remote measurement of methane in coal mines: a review  

Energy Technology Data Exchange (ETDEWEB)

The authors identify a need for a device which can remotely measure methane in coal mines. Similar techniques which have been used to measure atmospheric pollutants are discussed. These techniques include adsorption, Raman scattering and fluorescence. While differential adsorption and Raman scattering techniques have potential there are a number of problems to be resolved before they could be applied effectively. It is felt that an area which may provide suitable technology sometime in the future is in the field of laser sources. 6 refs., 4 tabs.

1987-02-01

40

Radial distribution functions of amorphous silicon  

Energy Technology Data Exchange (ETDEWEB)

Substantial changes in the radial distribution function of amorphous Si films have been observed in neutron-diffraction studies. The spectra indicate changes in short-range order associated with an approx.11% modification in the bond-angle distribution width. The results allow the first direct comparison of structural and vibrational Raman probes of variations in local order in thin-film amorphous solids. Good agreement is obtained between the measured bond-angle variation and that based on Raman estimates.

1989-03-15

41

Paclitaxel distribution in poly(ethylene glycol) / poly(lactide-co-glycolic acid) blends and its release visualized by coherent anti-Stokes Raman scattering microscopy  

UK PubMed Central (United Kingdom)

Mechanisms underlying the release of paclitaxel (PTX) from poly(ethylene glycol)/poly(lactic-co-glycolic acid) (PEG/PLGA) blends were investigated by coherent anti-Stokes Raman scattering (CARS)...Full Text Available

2007-10-08

42

Nuclear Raman processes and the development of gamma-ray lasers  

International Nuclear Information System (INIS)

This review briefly describes current efforts to develop superradiant sources of coherent radiation for the sub-nanometer range of wavelenghs, using nuclear rather than the atomic or molecular transitions that are stimulated in existing lasers. First the radiative (including Raman) interactions of nuclei with those of atoms and molecules are compared; then the present status of research on the fundamental problems involved in stimulating nuclear gamma radiation is described. (author). 20 refs.; 2 figs.

43

Liquid hydrogen droplet as an ultrahigh-Q optical cavity  

Energy Technology Data Exchange (ETDEWEB)

We describe a liquid hydrogen droplet as an optical cavity via whispering gallery modes. We show that the droplet leads to an ultrahigh-cavity-Q value of 2.5x10{sup 9} in visible region. We show also that the high-Q droplet results in a huge Raman nonlinearity, generating a stimulated Raman comb series covering whole visible region.

2000-07-01

46

Application of low-resolution Raman spectroscopy for the analysis of oxidized olive oil  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to evaluate the potential of low-resolution Raman spectroscopy for monitoring the oxidation status of olive oil. Primary and secondary oxidation parameters such as peroxide value, K"2"3"2 and K"2"7"0 were studied. Low-resolution Raman spectra ranging from 200 to 2700 cm^-^1 in a set of 126 oxidized and virgin olive oil samples were collected directly using a probe. Partial Least Squares was used to calibrate the Raman instrument for the different targeted parameters. The performance of the models was determined by using validation sets, and the best results obtained were: R^2 = 0.91, RMSEP = 2.57 for the peroxide value content; R^2 = 0.88, RMSEP = 0.37 for K"2"3"2; and R^2 = 0.90, RMSEP = 0.08 for K"2"7"0. These results demonstrated that low-resolution Raman spect...

2011-01-01

47

The Effect of Reference Signals in a Visual Vigilance Task.  

Science.gov (United States)

The effect of reference signals on performance in a visual vigilance task was studied under three conditions. Reference signals were presented on the same display as the real signals. In condition 1 (control), no reference signals were displayed. Sugbject...

1969-01-01

48

Raman spectroscopic studies of carbon in extra-terrestrial materials  

International Nuclear Information System (INIS)

The measurements obtained here indicate ways in which micro-Raman spectroscopy can be used to elucidate structural characteristics and distribution of carbon in meteorites and interplanetary dust particles (IDPs). Existing information about structurally significant aspects of Raman measurements of graphite is combined with structurally relevant findings from the present micro-Raman studies of carbons prepared by carbonization of polyvinylidine chloride (PVDC) at various temperatures and natural material, as well as several acid residues from the Allende and Murchison meteorites in order to establish new spectra-structure relationships. Structural features of many of the materials in this study have been measured by x ray analysis and electron microscopy: thus, their structural differences can be directly correlated with differences in the Raman spectra. The spectral parameters consequently affirmed as ...

1990-04-01

49

Temperature profiles from rotational Raman lidar: parameter for the interpretation of PSC composition  

Energy Technology Data Exchange (ETDEWEB)

The depletion of stratospheric ozone is caused by chlorine species formed in heterogeneous processes on the surfaces of polar stratospheric cloud (PSC) particles. For studying local PSC formation processes in the Arctic a temperature lidar receiver was developed that makes use of the rotational Raman method, the only lidar technique for measuring atmospheric temperature profiles not perturbed by the presence of aerosols or cloud particles. The receiver was implemented in the mobile GKSS Raman lidar and transferred to Esrange (67.9 N, 21.1 E) near Kiruna in northern Sweden in winter 1997/98. Temperature data measured between January 22 and February 6, 1998, are presented and compared to model data analyzed by the European centre for medium-range weather forecast. Local temperature profiles are studied in three cases of type-Ib PSCs. This type is characterized by a low depolarization ratio. (orig.)

1999-07-01

50

Laser Raman microscopic studies of passive films formed on type 316LN stainless steels during pitting in chloride solution  

Energy Technology Data Exchange (ETDEWEB)

The surface films formed on type 316LN stainless steels (SS) with different nitrogen contents, during potentiodynamic polarization in acidified 1 M NaCl solution, were characterized by Laser Raman Spectroscopy (LRS). LRS confirmed the presence of oxides and oxychlorides of iron and chromium, hydrated chlorides and nitrates in the film. Raman mapping showed increasing nitrate content in the film with increasing nitrogen content. The film on the uncorroded material showed the presence of chromium and molybdenum oxides. The improvement in pitting corrosion resistance of type 316LN SS with increasing nitrogen content was attributed to increased amount of nitrates in the passive film.

2010-06-15

51

Laser Raman microscopic studies of passive films formed on type 316LN stainless steels during pitting in chloride solution  

International Nuclear Information System (INIS)

The surface films formed on type 316LN stainless steels (SS) with different nitrogen contents, during potentiodynamic polarization in acidified 1 M NaCl solution, were characterized by Laser Raman Spectroscopy (LRS). LRS confirmed the presence of oxides and oxychlorides of iron and chromium, hydrated chlorides and nitrates in the film. Raman mapping showed increasing nitrate content in the film with increasing nitrogen content. The film on the uncorroded material showed the presence of chromium and molybdenum oxides. The improvement in pitting corrosion resistance of type 316LN SS with increasing nitrogen content was attributed to increased amount of nitrates in the passive film.

2010-06-01

52

On Sensitivity of Spectral Radiative Fluxes to Atmospheric Water Vapor in the 940 nm Region (Numerical Simulation)  

Energy Technology Data Exchange (ETDEWEB)

Water vapor is well known to be a critical component in many aspects of atmospheric research, such as radiative transfer and cloud and aerosol processes. This requires both improved measurements of the columnar water vapor and its profiles in the atmosphere in a wide range of conditions, and adjustment of water vapor parameterizations in radiation codes including the perfection of spectroscopic parameters. In this paper we will present the results of comparison of our calculations and downward solar fluxes measured with Rotating Shadowband Spectroradiometer under conditions of horizontally homogeneous clouds. We also will discuss the sensitivity of atmospheric radiation characteristics to variations of water vapor in the band 940 nm: these results may be useful for development of new methods of retrieval of the total column water vapor content (WVC) in the atmosphere from data of ...

2005-03-18

53

Inverse spinel materials. A new class of high voltage cathode materials for Li-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

The influence of Cr on the structure and electrochemical properties of LiCoVO{sub 4} was studied using X-Ray diffraction, scanning electron microscopy, Raman Spectroscopy and cycle tests. Doping levels up to 10 mol% were achieved, which improved the electrochemical stability of the structure of LiCoVO{sub 4}, resulting in a significant increase in the initial charge and discharge capacity. The Raman spectroscopy data for the Cr-doped LiCoVO{sub 4} is similar as for LiCoVO{sub 4}. The replacement of a dopant for the Co-ion in the inverse spinel structure causes several Raman shifts. The X-ray diffraction patterns show no new phases and combined with the Raman spectroscopy data it is concluded that the Cr dopant will be located at the octahedral site (16d) where they create an electronic pathway that enhances the electronic conductivity. However, the capacity dropped significantly after prolonged cycling, ...

2003-07-01

54

Electronic spectra of semiconductor nanocrystals  

Energy Technology Data Exchange (ETDEWEB)

Semiconductor nanocrystals smaller than the bulk exciton show substantial quantum confinement effects. Recent experiments including Stark effect, resonance Raman, valence band photoemission, and near edge X-ray adsorption will be used to put together a picture of the nanocrystal electronic states.

1993-12-31

55

Study on the separation characteristics of tritiated water vapor adsorption.  

Science.gov (United States)

In order to reduce the air concentration of (sup 3)H in the reactor buiIding of Wolsung Heavy Water Reactor, a computer code for estimation of adsorption behavior was programmed based on an equation derived for analysis of water vapor adsorption, and a ba...

1991-01-01

56

Solution-based characterization of surface-enhanced Raman response of single scattering centers  

Energy Technology Data Exchange (ETDEWEB)

We demonstrate the rapid optical characterization of large numbers of individual metal nanoparticles freely diffusing in colloidal solution by confocal laser spectroscopy. We find that hollow gold nanospheres and solid silver nanoparticles linked with a bifunctional ligand, both designed nanostructures, exhibit significantly higher monodispersity in their Rayleigh and Raman scattering response than randomly aggregated gold and silver nanoparticles. We show that measurements of rotational diffusion timescales allow sizing of particles significantly more reliably than can be obtained using translational diffusion timescales.

2008-03-06

57

New materials for SRS lasers  

International Nuclear Information System (INIS)

The problem of search for new materials for spectrally positioned laser sources, which is central for modern photonics, is discussed. The use of the stimulated Raman scattering effect in crystals offers a highly efficient way to the design of such sources. The recent results of investigations into this effect for a large number of various types of crystalline materials are presented. The most promising compounds, as regards the realisation of different laser operation modes, are considered, including calcium, strontium, barium and lead molybdates and tungstates. Several examples of functioning efficient lasers based on novel materials exhibiting the stimulated Raman light scattering effect are given.

2006-10-31

58

Electron combinational light scattering in disordered Ti_x_-_1Fe_x alloys: theory and experiment  

International Nuclear Information System (INIS)

Theoretical description of Raman scattering in disordered alloys of Ti and Zr with transition metals of groups 5-8 of the Mendeleev Periodic System in critical range of concentrations (CRC) is given. Results of Raman scattering experiment in the system Ti_1_-_xF_x at 0.0005

59

Meteorologial Techniques  

Science.gov (United States)

... 2-93 An Atmospheric Particle Emits Electromagnetic ... atmospheric water vapor produces a hydrometeor. ... subject to wind movement (either blowing ...

2003-06-13

60

Characterization of lithium electrode surface in lithium secondary batteries by in situ Raman spectroscopic methods. Final report, 1 September 1989-31 December 1992  

Energy Technology Data Exchange (ETDEWEB)

Surface layers on lithium electrodes formed in several solvents including dimethyl carbonate (DMC), diethyl carbonate (DEC), polyethylene glycol 400 dimethyl ether (PEG400DME), and propylene carbonate (PC) have been studied by Raman spectroscopy. Both DMC and DEC were used singly, and also mixed with either methyl acetate or methyl formate. The Raman spectra showed that passive films formed on the Li surface in different solvents may have different chemical structures, which changed during the charging and discharging processes. A solid film of fullerene C6O, which could be used as a cathode in Li rechargeable batteries, was examined in the PEG400DME solution by both electrochemical and Raman spectroscopy. Cyclic voltammograms (CVs) showed five redox peaks which suggested the formation of C6O(-), C6O(2-), C6O(3-), C6O(4-), and C6O(5-). Raman spectra obtained from thin C6O film indicated that the thin ...

1993-03-24

64

DNA ENCODING MODIFIED SIGNAL PEPTIDE  

J-STORE (Japan)

Full Text Available

2005-01-11

67

Stanford geothermal program. Final report, July 1990--June 1996  

Science.gov (United States)

This report discusses the following: (1) improving models of vapor-dominated geothermal fields: the effects of adsorption; (2) adsorption characteristics of rocks from vapor-dominated geothermal reservoir at the Geysers, CA; (3) optimizing reinjection strategy at Palinpinon, Philippines based on chloride data; (4) optimization of water injection into vapor-dominated geothermal reservoirs; and (5) steam-water relative permeability.

1998-03-01

68

Explosives detection: the problem and prospects  

Energy Technology Data Exchange (ETDEWEB)

The history of explosives vapor detection includes almost every detection strategy known to man. Initial attempts to utilize these techniques were dismal failures. However, with the development of the Electron Capture Detector (ECD), the first promising detection of explosives vapors became possible. The present commercial explosives detectors detect the higher vapor pressure materials but not the whole spectrum. This paper describes the basic properties of explosives molecules and our research to utilize these properties for increased detection sensitivity.

1984-01-01

69

Comparative study of different methodologies for quantitative rock analysis by Laser-Induced Breakdown Spectroscopy in a simulated Martian atmosphere  

Energy Technology Data Exchange (ETDEWEB)

Laser-Induced Breakdown Spectroscopy was selected by NASA as part of the ChemCam instrument package for the Mars Science Laboratory rover to be launched in 2009. ChemCam's Laser-Induced Breakdown Spectroscopy instrument will ablate surface coatings from materials and measure the elemental composition of underlying rocks and soils at distances from 1 up to 10 m. The purpose of our studies is to develop an analytical methodology enabling identification and quantitative analysis of these geological materials in the context of the ChemCam's Laser-Induced Breakdown Spectroscopy instrument performance. The study presented here focuses on several terrestrial rock samples which were analyzed by Laser-Induced Breakdown Spectroscopy at an intermediate stand-off distance (3 m) and in an atmosphere similar to the Martian one (9 mbar CO{sub 2}). The experimental results highlight the matrix effects and the measurement inaccuracies due to the noise accumulated when low ...

2006-03-15

70

Comparative study of different methodologies for quantitative rock analysis by Laser-Induced Breakdown Spectroscopy in a simulated Martian atmosphere  

International Nuclear Information System (INIS)

Laser-Induced Breakdown Spectroscopy was selected by NASA as part of the ChemCam instrument package for the Mars Science Laboratory rover to be launched in 2009. ChemCam's Laser-Induced Breakdown Spectroscopy instrument will ablate surface coatings from materials and measure the elemental composition of underlying rocks and soils at distances from 1 up to 10 m. The purpose of our studies is to develop an analytical methodology enabling identification and quantitative analysis of these geological materials in the context of the ChemCam's Laser-Induced Breakdown Spectroscopy instrument performance. The study presented here focuses on several terrestrial rock samples which were analyzed by Laser-Induced Breakdown Spectroscopy at an intermediate stand-off distance (3 m) and in an atmosphere similar to the Martian one (9 mbar CO2). The experimental results highlight the matrix effects and the measurement inaccuracies due to the noise accumulated when low signals are ...

2006-03-01

71

Power system stabilizer system having improved integrity checking scheme  

Energy Technology Data Exchange (ETDEWEB)

This patent describes improvement in a system for stabilizing the operation of an electrical generator connected to a power distribution network of the type including a power system stabilizer for providing an oscillation signal having a value which normally represents generator oscillations and a modulator circuit responsive to input signals including the oscillation signal to provide a modulated output signal for varying generator excitation, means for checking for operational integrity of the power system stabilizer. It comprises: means for applying, to the power system stabilizer, a test signal of known amplitude and frequency, the test signal simulating generator oscillations and serving to produce a simulated oscillation signal for employment as the oscillation signal, means to store representations of time related ...

1991-03-12

72

Indirect heating of natural gas using vapor chambers; Aquecimento indireto de gas natural com uso de camaras de vapor  

Energy Technology Data Exchange (ETDEWEB)

Operation safety and reliability are major guidelines in the design of city-gate units. Conventional natural gas heaters operate by a indirect mechanism, where liquid water is used to transfer heat by natural convection between the combustion chamber and the natural gas coil. In this work, the concept of vapor chamber is evaluated as an indirect gas heater. In a vapor chamber, liquid water is in contact with the heat source, and vaporizes. The vapor condenses in contact with the heat sink. A reduced scale model was built and tested in order to compare these two heating concepts where the combustion chamber was replaced by electrical cartridge heaters. This engineering model can operate either as a conventional heater or as a vapor chamber. The comparison between the concepts was done by inducing a controlled power to the cartridges and by measuring the resulting temperature ...

2005-07-01

73

A particulate model of solid waste incineration in a fluidized bed combining combustion and heavy metal vaporization  

Energy Technology Data Exchange (ETDEWEB)

This study aims to develop a particulate model combining solid waste particle combustion and heavy metal vaporization from burning particles during MSW incineration in a fluidized bed. The original approach for this model combines an asymptotic combustion model for the carbonaceous solid combustion and a shrinking core model to describe the heavy metal vaporization. A parametric study is presented. The global metal vaporization process is strongly influenced by temperature. Internal mass transfer controls the metal vaporization rate at low temperatures. At high temperatures, the chemical reactions associated with particle combustion control the metal vaporization rate. A comparison between the simulation results and experimental data obtained with a laboratory-scale fluid bed incinerator and Cd-spiked particles shows that the heavy metal vaporization is ...

2009-11-15

74

Negative frequency and complex-carrier modulation and demodulation  

CERN Document Server

Negative frequency has a physical meaning, the complete description of a frequency signal is a rotating complex signal, in complete description, positive frequency signal exp(iwt) and negative frequency signal exp(-iwt) is two distinguishable and independent frequency signals. Because the real-carrier modulation and demodulation do not distinguish positive and negative frequency, so half of the spectrum resources and signal energy are wasted. The complex-carrier modulation uses the distinguishable positive frequency signal exp(iwt) and negative frequency signal exp(-iwt) as the carrier signals, they can carry different information, so the spectrum resources is full used, the complex-carrier demodulation does not lose signal energy, so the spectrum efficiency is improved.

2010-01-01

75

Application of wavelet analysis to signal processing methods for eddy-current test; ueburetto kaiseki no kadenryushinshoho heno tekiyo  

Energy Technology Data Exchange (ETDEWEB)

This study deals with the application of wavelet analysis to detection and characterization of defects from eddy-current and ultrasonic testing signals of a low signal-to-noise ratio. Presented in this paper are the methods for processing eddy-current testing signals of heat exchanger tubes of a steam generator in a nuclear power plant. The results of processing eddy-current testing signals of tube test pieces with artificial flaws show that the flaw signals corrupted by noise and/or non-defect signals can be effectively detected and characterized by using the wavelet methods. (author)

1998-12-15

76

Dynamic response of a liquid-vapor interface during flow film boiling from a sphere  

Energy Technology Data Exchange (ETDEWEB)

Film boiling is the mode if boiling during which the hot surface is separated from the vaporizing liquid by a nearly continuous film vapor. Film boiling is usually considered a very undesirable boiling regime since it is a relatively quiet and inefficient mode of heat transfer, particularly as compared to nucleate boiling. It is customary to analyze the two-phase flow regime of laminar flow film boiling by assuming the two-phase flow regime of laminar flow film boiling by assuming an idealized vapor film flow characterized by a smooth liquid-vapor interface. However, during stable flow film boiling, the wavy nature of the liquid-vapor interface and its role in local heat and mass transport have been largely ignored. The vapor interface is rarely stationary. Interfacial waves may substantially augment the heat transfer rates throughout the layer. The present ...

1987-11-01

77

Piperidine adsorption on two different silver electrodes: A combined surface enhanced Raman spectroscopy and density functional theory study  

Energy Technology Data Exchange (ETDEWEB)

The surface enhanced Raman scattering (SERS) spectra of piperidine in silver colloid solution, on roughened silver electrode and on roughened silver electrode modified with silver nanoparticles were studied, and the high-quality SERS spectra of piperidine on roughened silver electrode modified with silver nanoparticles were obtained for the first time. Surface selection rules derived from the EM enhancement model were employed to deduce piperidine orientations on the different surfaces. On the basis of this, two models of piperidine adsorbed on the surface of the silver nanoparticles were built, and DFT-B3PW91/LanL2dz was applied to calculate the Raman frequencies. It proves that, at higher potential values, the piperidine is perpendicularly standing on the roughened silver electrode surface though its lone-electron pair, but in silver colloid solution and on the silver nanoparticles modified silver electrode the piperidine molecular lies flat ...

2007-10-15

78

On-line analysis of chemical composition using an FT-Raman spectrometer in the near-ir  

Science.gov (United States)

Newly commercialized Fourier transform Raman spectroscopic instrumentation provides a simpler alternative for vibrational spectroscopic analysis. Instrument vendors currently design for laboratory use, but there are many potential process applications of these stable, easy to use instruments. Raman spectroscopy is highly suited to analysis of aqueous samples. Near infrared excitation minimized fluorescence interference and allows for remote operation via fiber optic probes. The Department of Energy has funded research at the Measurement and Control Center to establish the utility of this method for on-line composition analysis in distillation columns. Laboratory evaluation and instrument employs an air-cooled laser and a thermoelectrically cooled detector. The device is mounted on a three by foot cart for convenient location in control rooms. Current fiber optic extension cables allow for analysis in a cell thirty five meters from the ...

1992-01-01

79

Follow up of the functioning of a lithium-polymer battery using confocal Raman micro-spectroscopy; Suivi du fonctionnement d`un accumulateur lithium-polymere par microspectrometrie Raman confocale  

Energy Technology Data Exchange (ETDEWEB)

The confocal Raman micro-spectroscopy has been used for the study of a Lithium/polymer electrolyte-LiTFSI/V{sub 2}O{sub 5} type battery in which the polymer electrolyte thickness is of about 80 {mu}m. The analysis is performed on the side of the battery thanks to a specially designed cell which preserves all the characteristics of the real system. The analysis is performed on 20 points aligned between the anode and the cathode and with a depth of several tenth of {mu}m. The analysis of data obtained during charging/output cycles allows to evaluate the gradients of salt concentration inside the electrolyte, the pollutions of LiOH, Li{sub 2}CO{sub 3}, Li{sub 2}O and Li{sub 3}N -type at the lithium interface, but also the structural modifications of the cathode material. The in-situ study of concentration gradients inside the electrolyte is of prime importance for the understanding of dendrites growth. (J.S.) 11 refs.

1996-12-31

80

Focused ion beam etching of nanometer-size GaN/AlGaN device structures and their optical characterization by micro-photoluminescence/Raman mapping  

Energy Technology Data Exchange (ETDEWEB)

The authors report on the nano-fabrication of GaN/AlGaN device structures using focused ion beam (FIB) etching, illustrated on a GaN/AlGaN heterostructure field effect transistor (HFET). Pillars as small as 20nm to 300nm in diameter were fabricated from the GaN/AlGaN HFET. Micro-photoluminescence and UV micro-Raman maps were recorded from the FIB-etched pattern to assess its material quality. Photoluminescence was detected from 300nm-size GaN/AlGaN HFET pillars, i.e., from the AlGaN as well as the GaN layers in the device structure, despite the induced etch damage. Properties of the GaN and the AlGaN layers in the FIB-etched areas were mapped using UV Micro-Raman spectroscopy. Damage introduced by FIB-etching was assessed. The fabricated nanometer-size GaN/AlGaN structures were found to be of good quality. The results demonstrate the potential of FIB-etching for the nano-fabrication of III-V nitride devices.

2000-07-01

81

First detection of lamella-gyroid-cylinder phase transition of neat polyethylene-poly(ethylene oxide) diblock copolymers on the basis of synchrotron WAXD/SAXS and infrared/Raman spectral measurements  

International Nuclear Information System (INIS)

The phase transition behaviour of polyethylene-b-poly(ethylene oxide) (PE-b-PEO) diblock copolymer with relatively short chain lengths has been studied on the basis of temperature dependent infrared and Raman spectral measurements and synchrotron WAXD/SAXS simultaneous measurements, from which the concrete structural changes were deduced successfully from the various levels of molecular chain conformation, chain packing mode and higher-order structure. The higher-order structure has been found to transform between lamella, perforated lamella, gyroid, cylinder and sphere structures. The inner structural changes occurring in the polyethylene and poly(ethylene oxide) parts have been related with these morphological changes. The morphological transition from lamella to gyroid occurs with keeping the crystalline state of polyethylene parts. This apparently curious transition can be interpreted reasonably by assuming the thermally-activated chain motion in the crystal ...

2009-08-01

82

EPR, optical, infrared and Raman studies of VO"2"+ ions in polyvinylalcohol films  

International Nuclear Information System (INIS)

Electron paramagnetic resonance (EPR), optical, infrared and Raman spectral studies have been carried out on vanadyl ions doped in polyvinylalcohol (PVA) films. The spin-Hamiltonian parameters (g and A) and the molecular orbital coefficients (#beta#_2"*"2 and k) have been evaluated. The values of spin-Hamiltonian parameters confirm that the vanadyl ions are present in PVA films as VO"2"+ molecular ions in an octahedral site with a tetragonal compression (C_4_v). The temperature variation EPR studies reveal that the variation of number of spins with temperature is in accordance with Boltzmann law. It is interesting to observe that the variation of susceptibility with temperature obeys Curie-Weiss law. The FT-IR and FT-Raman spectrum exhibits few bands, which are attributed to O-H, C-H, C-C and C-O groups of stretching and bending vibrations. The optical absorption spectrum exhibits two bands, which are assigned to "2B_2_g->"2B_1_g and ...

2007-01-15

83

Uses of laser optical pumping to produce polarized ion beams  

Energy Technology Data Exchange (ETDEWEB)

Laser optical pumping can be used to produce polarized alkali atom beams or polarized alkali vapor targets. Polarized alkali atom beams can be converted into polarized alkali ion beams, and polarized alkali vapor targets can be used to produce polarized H/sup -/ or /sup 3/He/sup -/ ion beams. In this paper the authors discuss how the polarized alkali atom beams and polarized alkali vapor targets are used to produce polarized ion beams with emphasis on the production of polarized negative ion beams.

1983-04-01

84

Effects of vaporizer and evaporative-condenser size on geofluid effectiveness and cost of electricity for geothermal binary power plants  

Energy Technology Data Exchange (ETDEWEB)

A special study was conducted to investigate the influences of minimum approach temperature differences occurring in supercritical-heater/vaporizer and evaporative-condenser heat rejection systems on geothermal-electric binary power plant performance and cost of electricity. For the systems investigated optimum pinch points for minimizing cost of electricity were estimated to range from 5 to 7/sup 0/F for the heater vaporizer. The minimum approach of condensing temperature to wet-bulb temperature for evaporative condensers was estimated to be about 30/sup 0/F in order to achieve the lowest cost of electricity.

1983-10-01

85

Determination of vapor pressures, enthalpies of sublimation, and enthalpies of fusion of benzenetriols  

Energy Technology Data Exchange (ETDEWEB)

Molar enthalpies of sublimation of 1,2,4-, 1,2,3-, and 1,3,5-tri-hydroxy-benzene, were obtained from the temperature dependence of the vapor pressure measured by the transpiration method. The molar enthalpies of fusion and molar heat capacities of these compounds were measured by DSC. The measured data sets of vaporization, sublimation and fusion enthalpies were checked for internal consistency. Strength of the inter- and intra-molecular hydrogen bonding in di- and tri-hydroxy-benzenes have been assessed.

2004-06-07

86

Pharmaceutical applications of non-linear imaging  

British Library Electronic Table of Contents (United Kingdom)

Non-linear optics encompasses a range of optical phenomena, including two- and three-photon fluorescence, second harmonic generation (SHG), sum frequency generation (SFG), difference frequency generation (DFG), third harmonic generation (THG), coherent anti-Stokes Raman scattering (CARS), and stimulated Raman scattering (SRS). The combined advantages of using these phenomena for imaging complex pharmaceutical systems include chemical and structural specificities, high optical spatial and temporal resolutions, no requirement for labels, and the ability to image in an aqueous environment. These features make such imaging well suited for a wide range of pharmaceutical and biopharmaceutical investigations, including material and dosage form characterisation, dosage form digestion and drug rele...

2011-01-01

87

New High-Pressure Excitations in Parahydrogen  

Energy Technology Data Exchange (ETDEWEB)

Raman and infrared spectroscopy of para-H{sub 2} to pressures in excess of 200GPa and to 8K using new ultrapure synthetic diamond anvils reveals numerous new vibrational excitations in the three high-pressure phases. Highly resolved Raman-active librons indicate differences in orientational ordering between phasesII and III, including evidence for changes within phaseII. The librons in phaseIII are strongly pressure dependent and reflect a substantial increase in ordering with pressure. Multiple vibrons in all three phases (I, II, and III) are observed. The results place new bounds on predicted crystal structures and dynamics of the dense molecular solid. {copyright} {ital 1997} {ital The American Physical Society}

1998-01-01

88

In situ Raman spectroscopy investigation of bioactive glass reactivity: Simulated body fluid solution vs TRIS-buffered solution  

British Library Electronic Table of Contents (United Kingdom)

In the present contribution, the innovative in situ Raman micro-spectroscopy was applied to investigate the in vitro reactivity of various bioactive glasses. All the investigated glasses belonged to the Na2O\\K2O-CaO-P2O5-SiO2 system, but contained sensibly different percentages of network modifiers. The glasses were immersed for increasing times, up to 96h, in simulated body fluid (SBF) and in tris-buffered (TRIS) solution. In this way, two fundamental items were addressed, i.e. the effect of the glass composition and the nature of the soaking fluid on the overall reactivity. As regards the SBF, all the glasses were able to promote the formation of a hydroxyl-carbonate apatite (HCA) surface layer in very short times. The reaction rate was particularly quick for the 45S5 Bioglass and for it...

2011-01-01

89

Finite-duration Seeding Effects in Powerful Backward Raman Amplifiers  

Energy Technology Data Exchange (ETDEWEB)

In the process of backward Raman amplification (BRA), the leading layers of the seed laser pulse can shadow the rear layers, thus weakening the effective seeding power and affecting parameters of output pulses in BRA. We study this effect numerically and also analytically by approximating the pumped pulse by the ''*-pulse'' manifold of self-similar solutions. We determine how the pumped pulse projection moves within the *-pulse manifold, and describe quantitatively the effective seeding power evolution. Our results extend the quantitative theory of BRA to regimes where the effective seeding power varies substantially during the amplification. These results might be of broader interest, since the basic equations, are general equations for resonant 3-wave interactions.

2003-07-14

90

Feasibility of using Gaspils and other methods of remotely measuring methane in coal mines and preparation of a conceptual design for a suitable instrument (UP-M-513) final report  

Energy Technology Data Exchange (ETDEWEB)

The use of differential absorption and Raman scattering techniques for the remote sensing of methane in underground coal mines is examined. An analysis of the differential absorption technique showed that non-range resolved systems were incapable of achieving the desired concentration and range specifications and therefore were unsuitable for use in underground coal mines. The Raman scattering technique proved quite successful and a conceptual design which uses the technique is presented. The availability of suitable UV source is critical to the success of the technique however, and to date there is nothing which meets size and portability requirements for a system of this type. Recommendations for further study are included. 19 refs.

1986-04-01

91

A Single Laser System for Ground State Cooling of 25-Mg+  

CERN Document Server

We present a single solid-state laser system to cool, coherently manipulate and detect $^{25}$Mg$^+$ ions. Coherent manipulation is accomplished by coupling two hyperfine ground state levels using a pair of far-detuned Raman laser beams. Resonant light for Doppler cooling and detection is derived from the same laser source by means of an electro-optic modulator, generating a sideband which is resonant with the atomic transition. We demonstrate ground-state cooling of one of the vibrational modes of the ion in the trap using resolved-sideband cooling. The cooling performance is studied and discussed by observing the temporal evolution of Raman-stimulated sideband transitions. The setup is a major simplification over existing state-of-the-art systems, typically involving up to three separate laser sources.

2010-01-01

92

The bacterial signal indole increases epithelial-cell tight-junction resistance and attenuates indicators of inflammation  

UK PubMed Central (United Kingdom)

Interkingdom signaling is established in the gastrointestinal tract in that human hormones trigger responses in bacteria; here, we show that the corollary is true, that a specific bacterial signal,...Full Text Available

2010-01-05

93

Social competition affects electric signal plasticity and steroid levels in the gymnotiform fish Brachyhypopomus gauderio  

UK PubMed Central (United Kingdom)

Sexually-selected communication signals can be used by competing males to settle contests without incurring the costs of fighting. Steroid regulation of these signals can render them as reliable...Full Text Available

2009-10-01

94

Mutational Analysis of cis-Acting RNA Signals in Segment 7 of Influenza A Virus?  

UK PubMed Central (United Kingdom)

The genomic viral RNA (vRNA) segments of influenza A virus contain specific packaging signals at their termini that overlap the coding regions. To further characterize cis-acting signals...Full Text Available

2008-12-01

95

Colour television, an imitation of the human visual system.  

UK PubMed Central (United Kingdom)

Colour television is examined as an attempt to imitate the human visual system in image formation, spectral sensitivities, adaptation, contrast effects, signal processing, signal modulation, signal...Full Text Available

1975-07-01

96

chapter 5 - NASA's History Office  

Science.gov (United States)

Ever-present water vapor and dust distort or block incoming radiations. ... were among the first scientific sensors to be attached to the earliest space rockets. ...

97

Study on cold startability and mixture formation of high-percentage methanol blends  

Energy Technology Data Exchange (ETDEWEB)

Using gasoline as an example of additives for cold start improvement, fuel vapor composition of methanol-gasoline mixtures, fuel evaporation rate in consideration of temperature drop due to heat of fuel evaporation, air fuel ratio, stoichiometric air fuel ratio and excess air ratio of fuel vapor were calculated. The mixture formation of methanol-gasoline mixtures at low temperature in otto cycle engines was studied. Van Laar's empirical formula was used to estimate the partial pressure of high-percentage methanol blends. It was found that the most part of fuel vapor is occupied by gasoline, even when a small amount of gasoline is added to methanol resulting to an extremely small excess air ratio. It is obvious that this vapor pressure adjustment using gasoline is the dominant factor for improvement in cold startability. (10 figs, 1 tab, 10 refs)

1988-05-31

98

Parametric Modeling of Low-Frequency Water-Vapor-Induced ...  

Science.gov (United States)

indicated for the phase spectral density measurements; how- ever, Ref. 7 provides a very tentative estimate of : ORW ~ 2 ><10"'(RW); Ta = 1000 seconds ...

99

Numerical modeling of scanning laser-induced melting, vaporization and resolidification in metals subjected to step heat flux input  

Energy Technology Data Exchange (ETDEWEB)

We present a 1-D heat transfer, melting, vaporization and resolidification model describing the interaction of a scanning continuous-wave laser with a metal surface wherein the beam power is constant. A physical model based on the Stefan problem is developed with appropriate boundary conditions. The effects of processing parameters on process variables are investigated numerically by varying beam diameters, scan speeds and substrate temperatures for Nickel. Relations are derived for the times to initiate melting, to initiate vaporization, to reach maximum melting depth, for melting-resolidification, and for maximum melting and vaporization depths. Surface temperatures are compared with approximate closed form solutions. (Author)

2004-09-01

100

Nomographs estite floating-roof tank evaporation  

Energy Technology Data Exchange (ETDEWEB)

Nomographs are presented that estimate the evaporation loss from external floating-roof tanks using tank diameter, type of seal, product vapor pressure, and wind velocity.

1986-01-27

101

Instabilities during liquid migration into superheated hydrothermal systems  

Energy Technology Data Exchange (ETDEWEB)

Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into ...

1995-01-26

102

Fuel conversion apparatus and method  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and method are described for the vaporization of liquid fuel oils to produce a gaseous mixture suitable for burning in a burner normally designed for operation utilizing natural gas.

1981-11-24

103

Excitonic transitions in InGaP/InAlGaP strained quantum wells  

Science.gov (United States)

Excitonic transitions in metalorganic vapor phase epitaxially grown In[sub [ital x

1993-08-30

104

Changes of atmospheric water vapor budget in the Pearl River basin and possible implications for hydrological cycle  

British Library Electronic Table of Contents (United Kingdom)

In this study, we thoroughly analyzed abrupt behaviors, trends, and periodicity properties of water vapor flux and moisture budget entering and exiting the four edges of the Pearl River basin based on the NCAR/NCEP reanalysis dataset by using the continuous wavelet transform and the simple two-phase linear regression technique. Possible implications for hydrological cycle and water resource management of these changes are also discussed. The results indicate that: (1) the water vapor propagating through the four edges of the Pearl River basin is decreasing, and it is particularly true for the changes of the water vapor flux exiting from the north edge of the study river basin. The transition point from increase to decrease occurs in the early 1960s; (2) The wavelet transform spectra indica...

2010-01-01

105

Anesthetic stimulation of insect water receptors.  

UK PubMed Central (United Kingdom)

Halothane, chloroform, and carbon tetrachloride, in the vapor and liquid phases, stimulate the water receptor of the blowfly Phormia regina. There are three successive phases of response to long-lasting...Full Text Available

1976-09-01

106

The cross-coupled interferometer for gravitational wave detection  

International Nuclear Information System (INIS)

The cross-coupled interferometer is a new design for interferometric gravitational wave detectors. Similar to the baseline gravitational wave detectors proposed for Advanced LIGO, it uses long-arm cavities in which the signal is generated. The signal fields are then extracted from the arm cavities with an additional cavity behind the long-arm cavities. The tuning of this signal extraction cavity and the parallel tuning of the signal recycling mirror can be used to optimize the peak frequency and the bandwidth of the detector independently. If we replace the signal recycling mirror by a small cavity, it is possible to amplify signals in two different frequency bands.

2002-04-07

107

RATIO COMPUTER  

Science.gov (United States)

An electronic computer circuit is described for producing an output voltage proportional to the product or quotient of tbe voltages of a pair of input signals. ln essence, the disclosed invention provides a computer having two channels adapted to receive separate input signals and each having amplifiers with like fixed amplification factors and like negatlve feedback amplifiers. One of the channels receives a constant signal for comparison purposes, whereby a difference signal is produced to control the amplification factors of the variable feedback amplifiers. The output of the other channel is thereby proportional to the product or quotient of input signals depending upon the relation of input to fixed signals in the first mentioned channel.

1958-11-11

108

Infrared stimulated luminescence in quartz  

Energy Technology Data Exchange (ETDEWEB)

Infrared (IR, 880 nm) stimulated luminescence (IRSL) signal was observed from quartz at room temperature. The characteristics of the signal such as its response to {gamma}-ray irradiation, thermal stability and thermal assistance energy show that the signal originates from different traps than those responsible for the luminescence signal stimulated by green light (GL, 514 nm). The IRSL signal's short lifetime (18 days at 15 deg. C) may have been the reason why it was not detected in previous experiments. The decay of the IR signal after GL illumination was observed. The thermoluminescence at 76 deg. C was enhanced after IR illumination.

2005-02-01

109

Use of Morphological Signal Processing and Computational - NASA  

Science.gov (United States)

Al-Balushi KR, Samanta B. Gear fault diagnosis using energy-based features of acoustic emission signals. Proc. IMechE, Part I: ...

110

Self-Motion and the Shaping of Sensory Signals  

UK PubMed Central (United Kingdom)

Sensory systems must form stable representations of the external environment in the presence of self-induced variations in sensory signals. It is also possible that the variations themselves may provide...Full Text Available

2010-04-01

111

Extracellular Signaling through the Microenvironment: A Hypothesis Relating Carcinogenesis, Bystander Effects, and ...  

Science.gov (United States)

... Extracellular Signaling through the Microenvironment: A Hypothesis Relating Carcinogenesis, Bystander Effects, and Genomic InstabilityMary Helen Barcellos-Hoff1a ... ...

112

Dishonest signalling in a fiddler crab.  

UK PubMed Central (United Kingdom)

Animal communication theory predicts that low-frequency cheating should be common in generally honest signalling systems. However, perhaps because cheats are designed to go undetected, there are few...Full Text Available

2000-04-07

113

Control of Host Cell Phosphorylation by Legionella Pneumophila  

UK PubMed Central (United Kingdom)

Phosphorylation is one of the most frequent modifications in intracellular signaling and is implicated in many processes ranging from transcriptional control to signal transduction in innate immunity....Full Text Available

114

A comprehensive assessment of N-terminal signal peptides prediction methods  

UK PubMed Central (United Kingdom)

BackgroundAmino-terminal signal peptides (SPs) are short regions that guide the targeting of secretory proteins to the correct subcellular compartments in the cell. They are cleaved...Full Text Available

115

Spectroscopic study of some historical arts  

International Nuclear Information System (INIS)

This work presents the spectroscopic results of the investigations of ancient pottery remains excavated in ancient Kremna (BURDUR-TURKEY). The micro-Raman and FT-IR spectroscopic studies of the pottery remains belonging to sixth century allowed us to identify the mineral composition. Some examples are described of the use of this technique in the field of art conservation and diagnostics, with regard to pigments, and some products of metal alteration.

2009-09-24

116

Spectroscopic studies of the Sm_3Ga_5O_1_2 monocrystals  

International Nuclear Information System (INIS)

The fluorescence, absorption, infrared and Raman spectra of Sm_3Ga_5O_1_2 have been investigated. The energy-level schemes in the energy range 3000-16000 cm"-"1 have been determined. The number and symmetries of the Sm_3Ga_5O_1_2 crystal normal mode have been obtained by the molecular site group analysis and their comparison with the experiment has been made.

117

Single-mode 30 MW CO/sub 2/ laser system for 16. mu. m Raman scattering in parahydrogen  

Energy Technology Data Exchange (ETDEWEB)

A CO/sub 2/ laser chain able to supply approx.=30 MW on a single mode TEM/sub 00/ is described. The coupling of a modified Lumonics 101 module with a low-pressure cell constitues the oscillator and two further Lumonics 103 stages two amplifiers. The final pulse achieves the energy of 4.0 J with 90% of this energy in a peak of 100 ns FWHM.

1983-01-11

118

Photoelectrocatalytic degradation of organic pollutants with TiO{sub 2} electrodes  

Energy Technology Data Exchange (ETDEWEB)

Photoelectrochemical oxidation is a potentially interesting method for destroying toxic organic materials. We have studied the photoelectrocatalytic activity of TiO{sub 2} films made by thermal oxidation of titanium, low pressure chemical vapour deposition (LPCVD), and anodisation of titanium. Two model organic compounds have been investigated for photooxidation: methyl phosphonic acid (MPA) which is a nerve gas analogue and 4-chlorophenol (4-CP) which is a chlorinated aromatic compound considered a standard for the evaluation of the TiO{sub 2} / UV processes. In addition to photoelectrochemical characterisation the films have been characterised by profilometry, XRD, AFM, photocurrent spectroscopy and Raman microscopy. Correlations have been made between the physical properties of the thin films and their catalytic activities. The most catalytic sample of thermally oxidised titanium was prepared at 400 deg C, and the presence of anatase was shown by XRD, MPA ...

2001-07-01

119

Observations of time delayed all-optical routing in a slow light regime  

CERN Document Server

We report an observation of a delayed all-optical routing/switching phenomenon based on ultraslow group velocity of light via nondegenerate four-wave mixing processes in a defected solid medium. Unlike previous demonstrations of enhanced four-wave mixing processes using the slow light effects, the present observation demonstrates a direct retrieval of the resonant Raman-pulse excited spin coherence into photon coherence through coherence conversion processes.

2008-01-01

120

ORNL `90  

Energy Technology Data Exchange (ETDEWEB)

This overview of research conducted at ORNL in 1991 presents information on the subjects of biology, physics, and the environment. Specific topics include gene mutations in kidney disease, technology assessments in thermonuclear fusion, submarine hunting technology, ozone-safe refrigerants, optical data storage via surface enhanced raman spectroscopy, and waste mitigating microbes. (GHH)

1990-12-31

121

ORNL '90  

Energy Technology Data Exchange (ETDEWEB)

This overview of research conducted at ORNL in 1991 presents information on the subjects of biology, physics, and the environment. Specific topics include gene mutations in kidney disease, technology assessments in thermonuclear fusion, submarine hunting technology, ozone-safe refrigerants, optical data storage via surface enhanced raman spectroscopy, and waste mitigating microbes. (GHH)

1990-01-01

122

New designs for Ultra High High-Power Single Transverse Mode Cw fibre lasers  

International Nuclear Information System (INIS)

Overcoming the limiting constraints of stimulated Raman scattering (SRS) and stimulated Brilluoin scattering (SBS) poses serious fibre design challenges for increasing the output power of optical amplifiers and lasers. New fibre amplifier designs are proposed to break out of these limitations to reach several kWs CW powers. (Author)

2009-04-01

123

Ionizing radiation target groups of band 3 inserted into egg lecithin liposomes as determined by Raman spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

The purified integral membrane protein, band 3, from human erythrocytes was inserted into egg lecithin liposomes. The insertion of band 3 was determined from thermal transition data from the analysis of the C-H stretching region bands recorded at temperatures from 25 to -22[sup o]C. Raman spectra show that band 3 considerably broadens and lowers the thermal transition of egg lecithin liposomes, suggesting the insertion of band 3. The band 3-inserted liposomes were irradiated with gamma-rays (40 Gy) and the radiation target groups were determined by the analysis of the structural sensitive Raman bands in the 1600-1700 cm[sup -1] (amide I), 1200-1300 cm[sup -1] (amide III) and 550-1030 cm[sup -1] (side chain amino groups) regions. The radiation-sensitive groups as identified from Raman spectra in the region 550-1030 cm[sup -1] are tyrosines and cysteines. The radiation-induced changes in the secondary structure were ...

1993-03-01

124

Ionizing radiation target groups of band 3 inserted into egg lecithin liposomes as determined by Raman spectroscopy  

International Nuclear Information System (INIS)

The purified integral membrane protein, band 3, from human erythrocytes was inserted into egg lecithin liposomes. The insertion of band 3 was determined from thermal transition data from the analysis of the C-H stretching region bands recorded at temperatures from 25 to -22"oC. Raman spectra show that band 3 considerably broadens and lowers the thermal transition of egg lecithin liposomes, suggesting the insertion of band 3. The band 3-inserted liposomes were irradiated with gamma-rays (40 Gy) and the radiation target groups were determined by the analysis of the structural sensitive Raman bands in the 1600-1700 cm"-"1 (amide I), 1200-1300 cm"-"1 (amide III) and 550-1030 cm"-"1 (side chain amino groups) regions. The radiation-sensitive groups as identified from Raman spectra in the region 550-1030 cm"-"1 are tyrosines and cysteines. The radiation-induced changes in the secondary structure were determined from amide I and ...

125

Formation of nano-sized particles of a solid electrolyte by laser ablation  

Energy Technology Data Exchange (ETDEWEB)

Nano-sized particles of a lithium ion conductive solid electrolyte, LiTi{sub 2}(PO{sub 4}){sub 3}, were prepared by laser ablation. The obtained particles were ca. 10nm in diameter. X-ray powder diffraction and Raman spectroscopy showed that they were amorphous with local structure similar to the crystalline counterpart. They were crystallized by the heating at ca. 630{sup o}C. (author)

2005-08-26

126

Fluctuations of the energy of Stokes pulses of resonance coherent SRS  

International Nuclear Information System (INIS)

An analytic solution is obtained for the equations of resonance coherent SRS by neglecting the population of the final level of the Raman transition for the systems with the active-medium length that is smaller than the wavelength of the incident light. For the extended systems, a numerical solution is obtained. The energy distribution of the Stokes pulses is found. The large-scale (about 100%) fluctuations of the Stokes radiation energy were observed in the case of unsaturated amplified spontaneous emission. (nonlinear optical phenomena)

2000-11-30

127

Conductive, spin-cast carbon films from polyacrylonitrile  

Energy Technology Data Exchange (ETDEWEB)

Polyacrylonitrile films have been spin cast and pyrolyzed to produce thin (500--1500 A) carbon films. These films have higher electrical conductivities than films produced by other methods at similar temperatures. The conductivity can be varied by at least four orders of magnitude by changing the pyrolysis temperature. Ultraviolet, infrared, and Raman spectroscopies were used to investigate the chemical structure of the films during different stages of processing.

1987-05-18

128

CRC handbook of laser science and technology. Volume 3. Optical materials, Part 1 - Nonlinear optical properties/radiation damage  

Energy Technology Data Exchange (ETDEWEB)

This book examines the nonlinear optical properties of laser materials. The physical radiation effects on laser materials are also considered. Topics considered include: nonlinear optical properties; nonlinear and harmonic generation materials; two-photon absorption; nonlinear refractive index; stimulated Raman scattering; radiation damage; crystals; and glasses.

1986-01-01

129

Stakeholder acceptance analysis: In-well vapor stripping, in-situ bioremediation, gas membrane separation system (membrane separation)  

Energy Technology Data Exchange (ETDEWEB)

This document provides stakeholder evaluations on innovative technologies to be used in the remediation of volatile organic compounds from soils and ground water. The technologies evaluated are; in-well vapor stripping, in-situ bioremediation, and gas membrane separation.

1995-12-01

130

Second harmonic generation of copper-vapor pulsed laser radiation  

Energy Technology Data Exchange (ETDEWEB)

An experimental study of second harmonic generation in a copper-vapor pulsed laser with an ADP crystal is presented. The ratio of the conversion into the second harmonic is found to depend on the average power of the exciting radiation. The maximum conversion ratio was 8.5%. Thermal self-defocusing is the main obstacle to obtaining high average powers at the double frequency.

1980-08-01

131

Recovery of Water from Boiler Flue Gas  

Energy Technology Data Exchange (ETDEWEB)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat ...

2008-09-30

132

Laser photochemical etching of molybdenum and tungsten thin films by surface halogenation  

Energy Technology Data Exchange (ETDEWEB)

Laser direct-write etching of the refractory metals Mo and W was developed using reactions in chlorine and nitrogen trifluoride vapors. Rate and high spatial resolution are simultaneously optimized using a two-vapor halogenation/development sequence, based on surface modification. Local-area laser chlorination of the metal surface is used to predispose areas to subsequent bulk etching.

1986-12-01

133

Double-electron-capture cross section for I/sup +/ in a magnesium-vapor target  

Energy Technology Data Exchange (ETDEWEB)

Measurements of the double-electron-capture process in which a positive ion of iodine becomes a negative ion in a single collision with a magnesium atom are reported between 20 and 90 keV. The cross section is comparable to that for the rare gases and not as large as might be expected from a two-valence-electron atom. This process is probably insignificant in the production of negative ion beams using a magnesium-vapor target.

1987-06-15

134

Chalk Point Cooling Tower Project. Environmental Systems Corporation's FY77 final report, July 1, 1976--August 31, 1977. Volume II. Cooling Tower Drift Dye Tracer Experiment. [Dye tests of vapor plume dispersion in coastal regions  

Science.gov (United States)

Results are reported from dye tests of the dispersion of the vapor plume from the natural draft cooling tower of a fossil-fuel power plant located in the coastal region of Maryland.

1977-12-01

135

Adsorption of mercury vapor on particles  

Energy Technology Data Exchange (ETDEWEB)

The adsorption of mercury vapor on particles was studied by using soot particles generated by incineration of sewage sludge (EP-ash) and activated carbon particles. Through the experiments, it was found that, at 298 K, the EP-ash has a fairly high adsorption capacity for mercury vapor in the order of 10/sup -6/g/g, which is between that of the ordinary soils and that of activated carbon particles. Furthermore, it was found that physical adsorption of mercury vapor on the studied particles at high temperature is described by Dubinin's equation. On the basis of the equation, it was shown that EP-ash physically adsorbs very little mercury at high temperature, and therefore, most mercury in the EP-ash is chemically adsorbed or contained in a form of mercury compounds. Nevertheless, the total amount of mercury contained in the particles is very little compared to the total mercury in the exhaust gases so that most ...

1986-07-01

144

Fault diagnosis of rolling bearing based on cyclic spectrum density  

International Nuclear Information System (INIS)

The paper considered the vibration signals of rotating equipment as cyclo stationary signals through analyzing the features of this kind of signals. Based on the analytic method of cyclic spectrum density, the paper pointed out that the impact frequency could be extracted effectively with the help of scanning cyclic frequency domain. The validity of the method of cyclic spectrum density is proved by simulating signals and the method is applied to the diagnosis of rolling bearings. (authors)

2009-09-01

146

Climate Change in the 20th and 21st Centuries  

ScienceCinema

...of the and global warming signal so ...

147

The envelope order spectrum based on generalized demodulation time-frequency analysis and its application to gear fault diagnosis  

British Library Electronic Table of Contents (United Kingdom)

The generalized demodulation time-frequency analysis is a novel signal processing method, which is particularly suitable for the processing of multi-component amplitude-modulated and frequency-modulated (AM-FM) signals as it can decompose a multi-component signal into a set of single-component signals whose instantaneous frequencies own physical meaning. While fault occurs in gear, the vibration signals measured from gearbox would exactly display AM-FM characteristics. Therefore, targeting the modulation feature of gear vibration signal in run-ups and run-downs, a fault diagnosis method in which generalized demodulation time-frequency analysis and envelope order spectrum technique are combined is put forward and applied to the transient analysis of gear vibration signal. Firstly the multi-...

2010-01-01

148

Comparison of the green- and infrared-stimulated luminescence of feldspar  

Energy Technology Data Exchange (ETDEWEB)

The differences are highlighted of various aspects of behaviour of the luminescence signal from feldspar when stimulated by green light and when stimulated by infrared radiation. In respect of bleaching, a comparison is made of the influence of white light (daylight) on the two stimulated luminescence signals, as well as a comparison of the influence of infrared exposure on the green-stimulated signal with the influence of green exposure on the infrared-stimulated signal. The influence of preheating on the two stimulated signals is also compared. Light-emitting diode systems were used for both green and infrared stimulation. The observations are considered in relation to the mechanism relevant to green- and infrared-stimulated luminescence from feldspar. (author).

1994-04-01

149

Comparison of the green- and infrared-stimulated luminescence of feldspar  

International Nuclear Information System (INIS)

The differences are highlighted of various aspects of behaviour of the luminescence signal from feldspar when stimulated by green light and when stimulated by infrared radiation. In respect of bleaching, a comparison is made of the influence of white light (daylight) on the two stimulated luminescence signals, as well as a comparison of the influence of infrared exposure on the green-stimulated signal with the influence of green exposure on the infrared-stimulated signal. The influence of preheating on the two stimulated signals is also compared. Light-emitting diode systems were used for both green and infrared stimulation. The observations are considered in relation to the mechanism relevant to green- and infrared-stimulated luminescence from feldspar. (author).

1993-07-01

150

An intracranial aspergilloma with low signal on T2-weighted images corresponding to iron accumulation  

Energy Technology Data Exchange (ETDEWEB)

We present a case of cerebral aspergillosis in an immunocompetent patient. The MRI signal characteristics were compared with the histologic findings. Irregular low-signal zones were demonstrated between the wall of the abscess and the central necrosis on T2-weighted images; the pathology specimen revealed concentrated iron in these transitional zones but no hemosiderin. Iron is an essential element for the growth of fungal hyphae. The low-signal zones may represent the areas where there was active proliferation of aspergillus, and the unique location of the low signal may be a helpful imaging characteristic for the diagnosis of an aspergillus abscess. (orig.)

2001-07-01

151

Formation of organic thin film by hot wall vapor deposition. Hot wall jochakuho ni yoru yuki usumaku no keisei  

Energy Technology Data Exchange (ETDEWEB)

The process operation of the hot wall vapor deposition method, formation of dry organic thin film and the control of molecular arrangement were described. This equipment included a substrate on the upper end of the hot wall tube and the vapor source at the lower end. The remarkable features are the hot wall tube which plays the role to hold vaporizing molecules to the high temperature and to transport molecules, and the flip flop mechanism which gives some idle period for the molecular vaporization by shutter closing. Several experiments were carried out by using stearic acid and by changing the distance S from the upper end of hot wall quartz tube to the substrate, the furnace temperature T{sub f} and the substrate temperature T{sub s}. When T{sub f} is equal to or less than the melting point of stearic acid, molectles are preferentialy made to vertical arrangement. In the case of T{sub f} more than ...

1991-12-01

152

Vapor fraction measurements in a steam-water duct at atmospheric pressure using neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

Real-time neutron radiography has been used to study the dynamic behavior of two-phase flow and measure vapor fractions in a steam-water duct at atmospheric pressure. This unique experimental technique offers one the opportunity to observe and record on videotape now Patterns and transient behavior of two-phase flow inside opaque containers without perturbing the environment. The neutron radiographic technique is non-intrusive and requires no special transparent window region. Data are recorded simultaneously over a large area of interest. Image processing of the video data can be employed to measure bubble velocities and time-averaged and Instantaneous vapor fractions.

1994-11-11

153

Quantitative model of vapor dominated geothermal reservoirs as heat pipes in fractured porous rock  

Science.gov (United States)

We present a numerical model of vapor-dominated reservoirs which is based on the well-known conceptual model of White, Muffler, and Truesdell. Computer simulations show that upon heat recharge at the base, a single phase liquid-dominated geothermal reservoir in fractured rock with low matrix permeability will evolve into a two-phase reservoir with B.P.D. (boiling point-for-depth) pressure and temperature profiles. A rather limited discharge event through cracks in the caprock, involving loss of only a few percent of fluids in place, is sufficient to set the system off to evolve a vapor-dominated state. The attributes of this state are discussed, and some features requiring further clarification are identified. 26 refs., 5 figs.

1985-03-01

154

Preliminary assessment of condensation behavior for hydrocarbon-vapor expansions which cross the saturation line near the critical point  

Energy Technology Data Exchange (ETDEWEB)

Previous analyses of binary cycles for conversion of geothermal energy from moderate temperature resources to electrical energy have shown potential gains in net geofluid effectiveness of on the order of 8%, resulting from selection of turbine-expansion processes whose equilibrium states pass through the two-phase region (assuming major condensation does not occur). If condensation occurs, this gain could be reduced or eliminated by the resulting loss in turbine efficiency. Experience with many fluids, however, indicates that vapor supersaturation (or subcooling) permits metastable pure-vapor states to exist at temperatures considerably below the saturation temperature at a given pressure; thus, by better understanding the condensation process, and properly structuring the cycle, substantial performance gains may be achievable. The present study assessed, qualitatively, the probability for attaining this performance gain.

1982-07-01

155

Health-hazard evaluation report HETA 86-132-1780, Alyeska Pipeline Service Company, Valdez, Alaska  

Energy Technology Data Exchange (ETDEWEB)

A study was made of employee exposure to oil sludge and vapors during oil-sludge removal and maintenance activities at the Alyeska Pipeline Service Company's Ballast Water Treatment Facility, Valdez, Alaska. Total hydrocarbons, except benzene, toluene, and xylene, showed concentrations from 371 to 1228mg/m3. Of eight maintenance workers, five reported headache, dizziness, or nausea when working without a respirator. The authors conclude that workers were potentially exposed to benzene vapors and total hydrocarbon vapors exceeding the evaluation criteria for these substances. The authors recommend the use of respiratory protection measures to reduce exposures during work operations.

1987-02-01

156

Gibbs ensemble Monte Carlo simulations of coexistence properties of a polarizable potential model of water  

Energy Technology Data Exchange (ETDEWEB)

The liquid/vapor coexistence density, the partial vapor pressure, and the heat of vaporization were calculated using Gibbs ensemble Monte Carlo simulation techniques. Long-range interactions such as charge-charge, charge-dipole, and dipole-dipole were evaluated using Ewald summation techniques. A polarizable potential model was used to describe the water-water interactions (Dang and Chang, J. Chem. Phys. 106, 8149, 1997). The model yields good agreement with the corresponding experimental data in the lower temperature region and moderate agreement in the higher temperature region. The critical temperature and density were estimated to be 565 K and 0.28 g/cm3.

2001-12-01

157

Effect of different treatments on acid centers of very high silicon zeolites studied by ir spectroscopy  

Science.gov (United States)

Using the infrared spectroscopy method, we have studied the effect of thermal dehydration (under vacuum and in air) and treatment with water vapor on the acid centers of very high silicon zeolites of the ZSM type. We have shown that dehydration under vacuum and in air completely and irreversibly removes the OH groups at 1120/sup 0/K, while treatment with water vapor removes these groups at 770/sup 0/K. The Lewis acid centers of dehydrated zeolites (represented by two types of centers) are more heat-stable than the Bronsted acid centers, but the vapor treatment at 1020/sup 0/K leads to the disappearance of the Lewis acid centers. In this work, we discuss the reasons for destruction of the acid centers of the zeolites under different treatment conditions.

1986-08-01

158

Dynamic and static error analyses of neutron radiography testing  

Energy Technology Data Exchange (ETDEWEB)

Neutron radiography systems are being used for real-time visualization of the dynamic behavior as well as time-averaged measurements of spatial vapor fraction distributions for two phase fluids. The data in the form of video images are typically recorded on videotape at 30 frames per second. Image analysis of he video pictures is used to extract time-dependent or time-averaged data. The determination of the average vapor fraction requires averaging of the logarithm of time-dependent intensity measurements of the neutron beam (gray scale distribution of the image) that passes through the fluid. This could be significantly different than averaging the intensity of the transmitted beam and then taking the logarithm of that term. This difference is termed the dynamic error (error in the time-averaged vapor fractions due to the inherent time-dependence of the measured data) and is separate from the static error (statistical ...

1999-03-01

159

Characterization of physically vapor deposited AF2400 thin films  

Energy Technology Data Exchange (ETDEWEB)

Anti-reflective coatings made with Teflon AF2400 had the highest damage thresholds recorded for physical vapor deposited coatings at the Lawrence Livermore National Laboratory damage facility. Physical vapor deposited layers of Teflon AF2400, a perfluorinated amorphous polymer, maintained the bulk optical properties of a high transmittance from 200 nm to 1600 nm, and a low refractive index. In addition, the refractive index can be intentionally reduced by control of two common deposition parameters, deposition rate and substrate temperature. Scanning electron microscopy and nuclear magnetic resonance observations indicated that morphological changes caused the variations in the refractive index rather than compositional changes. The coatings adhered to fused silica and silicon wafers under normal laboratory handling conditions.

1993-11-01

160

Analysis of plasma treatment and vapor heat treatment for thin-film transistors by extracting trap densities at front and back interfaces  

International Nuclear Information System (INIS)

Hydrogen (H) plasma treatment, oxygen (O) plasma treatment and water (H_2O)-vapor heat treatment for polycrystalline-silicon (poly-Si) thin-film transistors (TFTs) have been analyzed by separately extracting trap density at a front silicon-oxide interface (D_F) and trap density at a back interface (D_B). It is found that the H plasma treatment is apt to generate D_F and D_B. The O plasma treatment reduces D_F, while the H_2O-vapor heat treatment reduces both D_F and D_B. Improvement of transistor characteristics of poly-Si TFTs depends on understanding these results.

2004-05-17

161

A gear fault diagnosis using Hilbert spectrum based on MODWPT and a comparison with EMD approach  

British Library Electronic Table of Contents (United Kingdom)

When gear fault occurs, the vibration signals always display non-stationary behavior. Therefore time-frequency analysis has become the well-accepted technique for vibration-based gear fault diagnosis. This paper presents the application of a new time-frequency signal processing technique, the Hilbert spectrum based on the maximal overlap discrete wavelet packet transform (MODWPT), to the analysis of simulation signals and gear fault vibration signals measured by the acceleration sensor fixed on the bearing house. As long as the decomposition scale and disjoint dyadic decomposition are chosen suitably, the original signal could be decomposed into a set of monocomponent signals whose instantaneous amplitude and instantaneous frequency own physical meaning. After the instantaneous amplitude a...

2009-01-01

162

Structural and vibrational studies of LiNi{sub 1-y}Co{sub y}VO{sub 4} (0{<=}y{<=}1) cathodes materials for Li-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

The structure and vibrational properties of high voltage cathode materials, namely LiNi{sub 1-y}CO{sub y}VO{sub 4} solid solution with (0{<=}y{<=}1), have been studied using X-ray diffraction, Raman scattering and FTIR measurements. Rietveld refinements show that LiNi{sub 1-y}Co{sub y}VO{sub 4} vanadates belong to the inverse spinel structure with Fd3m(O{sup 7}{sub h}) space group. Analysis of Raman spectra has been carried out in the molecular approximation using a local environment model including VO{sub 4} tetrahedra, (Ni, Co)O{sub 6} and LiO{sub 6} octahedra as vibrational local units. (orig.)

2000-05-15

163

High-pressure Raman study on CeO{sub 2} nanospheres self-assembled by 5 nm CeO{sub 2} nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

CeO{sub 2} undergoes a first-order phase transition from fluorite to {alpha}-PbCl{sub 2}-type structure under high pressure. To evaluate the changes in physical properties of CeO{sub 2} nanomaterials as the particle size decreasing, high-pressure Raman study under quasi-hydrostatic condition has been performed on CeO{sub 2} nanospheres self-assembled by 5 nm CeO{sub 2} nanoparticles at room temperature. Surprisingly, as the pressure elevate to 34 GPa, the CeO{sub 2} nanospheres still retain the cubic fluorite-type structure, indicating the sample is more stable than the bulk counterpart. Whereas, previous high-pressure studies show the phase transition at 22.3/26.5 GPa for 12 nm CeO{sub 2} nanoparticles, which is less stable than the bulk materials. The enhancement of phase stability might be attributed to the increase of surface energy of CeO{sub 2} nanospheres as the size of the building units decrease. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. ...

2011-05-15

164

Consolidated silica glass from nanoparticles  

International Nuclear Information System (INIS)

A dense silica glass was prepared by consolidating a highly dispersed silicic acid powder (particle size 1H magic-angle spinning (MAS) NMR confirmed an increase in hydroxyl groups in the sample prepared by SPS relative to that of the conventional SiO2 reference glass. Aside from the comparably high water content, we conclude from the similarity of the IR-reflectance and the 29Si MAS NMR spectra of the SPS sample and the corresponding spectra of the conventionally prepared silica glass, that the short- and medium-range order is virtually the same in both materials. Raman spectroscopy, however, suggests that the number of three- and four-membered rings is significantly smaller in the SPS sample compared to the conventionally prepared sample. Based on these results we conclude that it is possible to prepare glasses by compacting amorphous powders by the SPS process. The SPS process may therefore enable the preparation of glasses with compositions inaccessible by ...

2008-09-01

165

The envelope order spectrum based on generalized demodulation time-frequency analysis and its application to gear fault diagnosis  

Science.gov (United States)

The generalized demodulation time-frequency analysis is a novel signal processing method, which is particularly suitable for the processing of multi-component amplitude-modulated and frequency-modulated (AM-FM) signals as it can decompose a multi-component signal into a set of single-component signals whose instantaneous frequencies own physical meaning. While fault occurs in gear, the vibration signals measured from gearbox would exactly display AM-FM characteristics. Therefore, targeting the modulation feature of gear vibration signal in run-ups and run-downs, a fault diagnosis method in which generalized demodulation time-frequency analysis and envelope order spectrum technique are combined is put forward and applied to the transient analysis of gear vibration signal. Firstly the multi-component vibration signal of ...

2010-02-01

166

Universal model for water costs of gas exchange by animals and plants  

UK PubMed Central (United Kingdom)

For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for...Full Text Available

2010-05-04

167

Preliminary assessment of condensation behavior for hydrocarbon-vapor expansions which cross the saturation line near the critical point  

Energy Technology Data Exchange (ETDEWEB)

Previous analyses of binary cycles for conversion of geothermal energy from moderate temperature resources to electrical energy have shown potential gains in net geofluid effectiveness on the order of 8%, resulting from selection of turbine-expansion processes whose equilibrium states pass through the two-phase region. If condensation occurs, this gain could be reduced or eliminated by the resulting loss in turbine efficiency. Experience with many fluids, however, indicates that vapor supersaturation permits metastable pure-vapor states to exist at temperatures considerably below the saturation temperature at a given pressure; thus, by better understanding the condensation process, and properly structuring the cycle, substantial performance gains may be possible. The purpose of the present study was to assess the probability for attaining this performance gain by estimating the extent of condensation which might be expected during such an ...

1983-01-01

168

Plasma Treatment within Dielectric Fluids.  

Science.gov (United States)

A dielectric liquid having entrained bubbles of gas or vapor is subjected to an electric field applied between spaced electrodes (112, 116) which generates microdischarges (and thus plasma) within the bubbles, allowing modification of the properties of th...

2003-01-01

169

Oxidation, volatilization, and redistribution of molybdenum from TZM alloy in air  

Energy Technology Data Exchange (ETDEWEB)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, MoO{sub 3}(m), in air and the hydroxide, MoO{sub 2}(OH){sub 2}, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report the authors present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800 C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for ...

2000-01-01

170

Oxidation, Volatilization, and Redistribution of Molybdenum from TZM Alloy in Air  

Energy Technology Data Exchange (ETDEWEB)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, (MoO3)m, in air and the hydroxide, MoO2(OH)2, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report we present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800°C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for vapor ...

2000-01-01

171

Nomographs for soil vapor extraction and off-gas treatment by activated carbon adsorption  

Energy Technology Data Exchange (ETDEWEB)

Soil vapor extraction (SVE) is a widely accepted in-place treatment technology that uses forced air to remove contaminant vapors from zones of permeable vapor flow, thereby enhancing the volatilization of contaminants from the subsurface. The resulting off-gases are contaminated with volatiles and semi-volatiles and have to treated by catalytic or thermal destruction systems, activated carbon adsorbers, or bioreactors. Of these, activated carbon adsorption is the most commonly used technology. From the theoretical foundation of SVE and carbon adsorption, two nomographs were developed for remedial investigation, feasibility studies, planning, operation, and preliminary design purposes. An advantage of such nomographs is that they graphically indicate the sensitivity of the remediation process to different design parameters and critical ranges within a given parameter. In effect, nomographs can help to foster an intuitive ...

1997-12-31

172

New intelligent monitor for CANDU type NPP  

International Nuclear Information System (INIS)

Nuclear energy provides a third of Europe's electricity with nearly no greenhouse-gas emissions. Sustained efforts are now being conducted to harmonize regulations all over Europe through WENRA and to converge on technical nuclear safety practices within the TSO network ETSON (European Technical Safety Organizations Network). In CANDU type NPP the tritiated water occurs by the neutron bombardment of deuterium. The tritiated water vapors imply health hazard (in the critical organs of the body the water presents a 10 day average biological half-life) and the early detection in nuclear plants of tritium emissions is important because the tritiated water vapors have the same characteristics as of atmospheric water vapors. By detecting tritiated vapors, the monitoring system ensures the following objectives: (a) indicates levels of tritium generally due to heavy water leakage, (b) reduces the possibility of ...

2009-10-12

173

Laboratory Investigation of Steam Adsorption in Geothermal Reservoir Rocks.  

Science.gov (United States)

Some vapor-dominated geothermal reservoirs and low-permeability gas reservoirs exhibit anomalous behavior that may be caused by surface adsorption. For example, geothermal reservoirs in the Larderello area of Italy and reservoirs in the Geysers Geothermal...

1988-01-01

174

Explosives detection The problem and prospects  

Energy Technology Data Exchange (ETDEWEB)

Explosives molecules have a number of unique properties. These properties are discussed. They include low vapor pressures, electronegativity, ''stickiness,'' frangibility, and thermal instability. The program for developing an advanced explosives detector is described.

1984-07-01

175

Determination of vapor-liquid equilibrium data and decontamination factors needed for the development of evaporator technology for use in volume reduction of radioactive waste streams  

Energy Technology Data Exchange (ETDEWEB)

A program is currently in progress at Argonne National Laboratory to evaluate and develop evaporator technology for concentrating radioactive waste streams. By concentrating radioactive waste streams, disposal costs can be significantly reduced. To effectively reduce the volume of waste, the evaporator must achieve high decontamination factors so that the distillate is sufficiently free of radioactive material. One technology that shows a great deal of potential for this application is being developed by LICON, Inc. In this program, Argonne plans to apply LICON`s evaporator designs to the processing of radioactive solutions. Concepts that need to be incorporated into the design of the evaporator include, criticality safety, remote operation and maintenance, and materials of construction. To design an effective process for concentrating waste streams, both solubility and vapor-liquid equilibrium data are needed. The key issue, however, is the high decontamination ...

1993-10-01

176

Designing a healthy house - an overview  

Energy Technology Data Exchange (ETDEWEB)

There are certain factors to take into account when determining the suitability of a healthy house site. Power lines, agricultural spraying, vehicle exhaust, and industrial pollution are all potential sources of indoor air contamination. It is recommended that a environmental assessment be done to determine whether there are specific sources of contamination. Good drainage is required. The surrounding landscaping should be open and sunlit, and with low maintenance requirements. Decks and fences made from pressure-treated or chemical treated lumber should be avoided. One of the early decisions in the design process is the choice of the structural system. The key with all foundation types is to control moisture, whether from rain, from the ground, or the condensation of moisture from the air with cooling. The construction frame is sealed away from the occupants by the air/vapor barrier, so only in extreme cases is it essential to use alternatives to softwood lumber ...

1999-11-01

177

Comparison of Indoor Mercury Vapor in Common Areas of Residential Buildings with Outdoor Levels in a Community Where Mercury Is Used for Cultural Purposes  

UK PubMed Central (United Kingdom)

Elemental mercury has been imbued with magical properties for millennia, and various cultures use elemental mercury in a variety of superstitious and cultural practices, raising health concerns for...Full Text Available

2006-01-01

178

Characterization of MJO ... - Microwave Limb Sounder (MLS) - NASA  

Science.gov (United States)

Feb 15, 2008 ... hydrological properties (e.g., hydrometeor budgets, cloud ice/water, transports ... cloud fraction, mass and particle size. In combination, these .... anomaly in the LS is not simply due isentropic movement of water vapor relative ...

179

4 - NASA Technical Reports Server  

Science.gov (United States)

Mar 1, 2011 ... The movement of hydrothermal fluids and/or fumarolic vapors through local rocks prior ... The Solar Energetic Particle Event of December 14, 2006 .... for measurement of non-precipitating cloud hydrometeors and aerosols, ...

180

Vibrational spectroscopy of silica sol-gel components during microwave irradiation  

Energy Technology Data Exchange (ETDEWEB)

In order to study the effects of microwaves on chemical reactions equipment was designed to acquire in-situ vibrational spectra of sol-gel components as they are irradiated with microwaves. Fourier Transform Infrared (FTIR) and Raman spectroscopy were used. A low temperature (10K) FTIR cell was used to trap samples in an argon matrix at 10{sup -7} Torr. For the liquid samples no differences were seen in spectra of irradiated and nonirradiated samples, but the argon matrix isolation technique showed dramatic differences.

1995-12-31

181

Threats to ICF reactor materials: computational simulations of radiation damage induced topological changes in fused silica  

International Nuclear Information System (INIS)

We have performed molecular dynamics simulations of radiation damage in fused silica. In this study, we discuss the role of successive cascade overlap on the saturation and self-healing of oxygen vacancy defects in the amorphous fused silica network. Furthermore, we present findings on the topological changes in fused silica due to repeated energetic recoil atoms. These topological network modifications consistent with experimental Raman spectroscopic observation on neutron and ion irradiated fused silica are indicators of permanent densification that has also been observed experimentally.

2003-04-01

182

Stimulated radiation of high - current relativistic electron beams  

International Nuclear Information System (INIS)

The most propagated mechanisms of stimulated radiation of electron beam such as Cherenkov one-particle and collective effects, ondulator and magnetic bremsshrahlung radiations, Doppler anomalous effect, Thompson and Raman scattering and radiation are discussed. Relation of spontaneous radiation mechanisms of individual electron and stimulated radiation effects in electron beams has been elucidated, grounds of linear electrodynamics of radiative beam instabilities are stated, and main mechanisms of their nonlinear stabilization are elucidated as well. Various simulated processes in electron beams are considered from the unique point of view using a simple mathematical apparatus and such physical laws as conservation and Newton laws.

1987-01-01

183

Spontaneous and stimulated Raman studies of vibrational dephasing in condensed phases  

Energy Technology Data Exchange (ETDEWEB)

Vibrational dephasing in condensed phases is studied from both a theoretical and experimental standpoint. A theory is presented which describes the dynamics of motional or exchange processes in weakly perturbed systems. This general formalism, which has been previously used to describe motional narrowing in magnetic resonance, is applied to vibrational spectroscopy. The model treats the case of a high frequency vibration anharmonically coupled to a low-frequency vibration. Intermolecular exchange of low frequency vibrational quanta results in a temperature dependent broadening and frequency shift of the high frequency vibration. Analysis of experimental data by this model yields both the exchange rates and the anharmonic couplings.

1980-05-01

184

Spectroscopic studies of the Sm/sub 3/Ga/sub 5/O/sub 12/ monocrystals  

Energy Technology Data Exchange (ETDEWEB)

The fluorescence, absorption, infrared and Raman spectra of Sm/sub 3/Ga/sub 5/O/sub 12/ have been investigated. The energy-level schemes in the energy range 3000-16000 cm/sup -1/ have been determined. The number and symmetries of the Sm/sub 3/Ga/sub 5/O/sub 12/ crystal normal mode have been obtained by the molecular site group analysis and their comparison with the experiment has been made.

1984-11-01

185

Solid State Photovoltaic Research Branch  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the progress of the Solid State Photovoltaic Research Branch of the Solar Energy Research Institute (SERI) from October 1, 1988, through September 30,l 1989. Six technical sections of the report cover these main areas of SERIs in-house research: Semiconductor Crystal Growth, Amorphous Silicon Research, Polycrystalline Thin Films, III-V High-Efficiency Photovoltaic Cells, Solid-State Theory, and Laser Raman and Luminescence Spectroscopy. Sections have been indexed separately for inclusion on the data base.

1990-09-01

186

Free electron laser (FEL) annealing of diamond  

International Nuclear Information System (INIS)

Free Electron Laser (FEL) with wide wavelength tunability has been developed and used for various applications. We report the structural-changes in P-ion-implanted diamond when we can achieve resonant excitation of the vibrations of specific bonds in the lattice of target (P-C) by using FEL. The change of property was analyzed by SIMS and Raman spectroscopy. After 5.8 #mu#m-FEL irradiation, we observed the crystallization of amorphous structure which was induced by P-ion-implantation. These results indicated the FEL annealing of diamond at room temperature. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

1998-09-02

187

A hierarchical lattice structure and formation mechanism of ZnO nano-tetrapods  

International Nuclear Information System (INIS)

The existence of characteristic longitudinal optical and transverse optical phonons of cubic ZnO in ZnO nano-tetrapods is determined by Raman spectroscopy and first-principles calculations. Stacking sequence change at the boundary of the core and legs is also identified by high-resolution transmission electron microscopy. Based on this experimental and theoretical evidence, we demonstrate that the lattice structure of ZnO nano-tetrapods is hierarchical with a zinc blende core connecting to four wurtzite legs. Furthermore, we establish the atomic configuration and propose a formation mechanism induced by Laplace pressure in the initial growth stage of ZnO nano-tetrapods.

2009-08-12

188

Water chemistry in the water-vapor circuit at Angra II: evolution of the operational concepts and canceling of the condensed polishing system; Quimica da agua do circuito agua-vapor de Angra II: evolucao do conceito operacional e o cancelamento do sistema de polimento do condensado  

Energy Technology Data Exchange (ETDEWEB)

The chemical operational concept originally established for the water-steam circuit of Angra II nuclear power plant has undergone several modifications throughout the development of the project. This work discusses the two main modifications giving special attention to the costs involved and analyses the main points and the consequences of such modifications 1 ref., 4 figs., 2 tabs.

1995-12-31

189

Uptake of atmospheric tritium by market foods  

Energy Technology Data Exchange (ETDEWEB)

In this paper uptake of tritium by market foods from tritiated water vapor in the air is investigated using cereals and beans purchased in Deep River, Canada. The concentrations of tissue free water tritium (TFWT) and organically bound tritium (OBT) range from 12 to 79% and from 10 to 38% respectively, of that estimated for atmospheric water vapor of the sampling month. The specific activity ratios of OBT to TFWT were constant for cereals, but variable for beans. The elevated OBT was shown to be the result of isotopic exchange of labile hydrogen by the fact that washing the foods with tritium free-water reduced their tritium contents to levels characteristic of their production sites.

1992-03-01

190

Thermodynamic modeling of acidic gas solubility in aqueous solutions of MEA, MDEA and MEA-MDEA blends  

DEFF Research Database (Denmark)

The thermodynamic framework that was developed in a previous work [Vrachnos et al. Ind. Eng. Chem. Res. 2004, 43, 2798] for the description of chemical and vapor-liquid equilibria of carbon dioxide, hydrogen sulfide, and their mixtures in aqueous methyldiethanolamine (MDEA) solutions is revised and extended in this study to the absorption of carbon dioxide into aqueous monoethanolamine (MEA) solutions and aqueous MDEA-MEA blends. The results of the model are compared with experimental data taken from the literature. Very satisfactory predictions of acidic gas vapor-liquid equilibrium over MDEA, MEA, and their blends at various concentrations, acidic gas loadings, and temperatures are obtained.

2006-01-01

191

The natural convection cooling with vaporizing deuterium for the horizontally arranged cold neutron source of the HFR - Grenoble  

International Nuclear Information System (INIS)

Natural convection of vaporizing Deuterium at 25 K transports the heat generated in the moderator cell of the cold neutron source to a He cooled condenser. The thermohydraulics of this thermosiphon were precalculated and the results verified by experiments in a 1:1 model using D_2 as fluid. The experimental results show that the thermosiphon operates stable. The demanded liquid content of the cell as well as wall temperatures below 50 K can be ensured by a proper design of the cell outlet flow geometry. A 7 min. loss of cryogenic power results in transient temperatures of the cell wall of not more than 300 K.

1991-08-01

192

Production of polarized negative ion beams by collisional pumping  

Energy Technology Data Exchange (ETDEWEB)

The production of polarized negative ion beams by collisional pumping is described. Collisional pumping utilizes repeated charge changing collisions in a thick electron-spin-polarized gas or vapor target to form a polarized fast atom beam. The polarized fast atom beam is then partially converted into a polarized negative ion beam in a vapor target. Analysis is presented for a hydrogen beam passing through either a thick polarized H atom target or a thick polarized alkali target. Large polarizations and large currents may be possible.

1983-01-01

193

Production of polarized negative ion beams by ''collisional pumping''  

Energy Technology Data Exchange (ETDEWEB)

The production of polarized negative ion beams by ''collisional pumping'' is described. Collisional pumping utilizes repeated charge changing collisions in a thick electron-spin-polarized gas or vapor target to form a polarized fast atom beam. The polarized fast atom beam is then partially converted into a polarized negative ion beam in a vapor target. Analysis is presented for a hydrogen beam passing through either a thick polarized H atom target or a thick polarized alkali target. Large polarizations and large currents may be possible.

1984-03-01

194

Plasma production and flow in negative ion beams  

Science.gov (United States)

Plasma generated in low-density vapor by a negative ion beam has been studied experimentally and computationally. We show that space charge neutralization of the beam occurs at very low vapor density, and that correspondingly the electron density may be much less than the beam and plasma ion densities. When there is a large local gas density, as in a charge changing cell, the resulting high electron density is also localized to the same region. Therefore, very few electrons will reach a negative ion accelerator even if it is placed one or two beam diameters from such a cell.

1977-09-21

195

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO{sub 2}) in aqueous methyldiethanolamine (MDEA) solutions  

Energy Technology Data Exchange (ETDEWEB)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO{sub 2}) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO{sub 2} were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-15

196

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO_2) in aqueous methyldiethanolamine (MDEA) solutions  

International Nuclear Information System (INIS)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-01

197

Mercury vacuum cleaner operational test and evaluation  

Energy Technology Data Exchange (ETDEWEB)

The Dental Investigation Service, USAFSAM, Brooks AFB, has outlined the need for a vacuum unit to be used in the Air Force dental clinics. The unit must be capable of effectively picking up mercury and at the same time not redistribute mercury vapors throughout the dental clinic during normal operations or mercury-spill situations. The Dental Investigation Service selected the MRS-3, Minuteman Mercury Recovery System, product of American Cleaning Equipment Corporation as the mercury vacuum to be used for T E. The USAF OEHL/ECH was requested by the Dental Investigation Service to perform the T E on the MRS-3 for possible health hazards due to exposures of mercury vapors.

1981-03-01

198

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

Energy Technology Data Exchange (ETDEWEB)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

1992-03-01

199

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

International Nuclear Information System (INIS)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

200

Solid state electrochemistry and spectroelectrochemistry of poly(arylene bisimide-alt-oligoether)s  

International Nuclear Information System (INIS)

Two electroactive polymeric arylene bisimides, namely poly[(4,7,10-trioxatrideca-1,13-diyl)-(1,4,5,8-naphthalenetetracarboxylic bisimide-N,N'-diyl)] and its perylene analogue - poly[(4,7,10-trioxatrideca-1,13-diyl)-(3,4,9,10-perylenetetracarboxylic bisimide-N,N'-diyl)] have been synthesized and studied by cyclic voltammetry, UV-vis-NIR as well as Raman spectroeletrochemistry. Contrary to low molecular weight arylene bisimides, which show a clear two electron, double-step electrochemical reduction (neutral form to radical anion and from radical anion to dianion), in the synthesized polymers multielectron transfers are observed, accompanied with a strong electrochromic effect. However, as probed by cyclic voltammetry, their first reduction step is retarded and covers a wider potential range. We attribute this effect to macromolecular nature of the compounds being reduced and their structural inhomogeneity caused by ?-stacking induced nanoaggregation of bisimide ...

2011-04-01

201

Wnt3a Induces Myofibroblast Differentiation by Upregulating TGF-? Signaling Through SMAD2 in a ?-Catenin-Dependent Manner  

UK PubMed Central (United Kingdom)

Growing evidence suggests the Wnt family of secreted glycoproteins and their associated signaling pathways, linked to development, are recapitulated during wound repair and regeneration events. However,...Full Text Available

202

The discovery of signal transduction by G proteins. A personal account and an overview of the initial findings and contributions that led to our present understanding  

UK PubMed Central (United Kingdom)

The realization that there existed a G-protein coupled signal transduction mechanism developed gradually and was initially the result of an ill fated quest for uncovering the mechanism of action...Full Text Available

2007-04-01

203

The Receptor Tyrosine Kinase FGFR4 Negatively Regulates NF-kappaB Signaling  

UK PubMed Central (United Kingdom)

BackgroundNFκB signaling is of paramount importance in the regulation of apoptosis, proliferation, and inflammatory responses during human development and homeostasis, as...Full Text Available

204

Strange as it may seem: the many links between Wnt signaling, planar cell polarity, and cilia  

UK PubMed Central (United Kingdom)

Cilia are important cellular structures that have been implicated in a variety of signaling cascades. In this review, we discuss the current evidence for and against a link between cilia and both the...Full Text Available

2011-02-01

205

Standardization of clinical decision making for the conduct of credible clinical research in complicated medical environments.  

UK PubMed Central (United Kingdom)

The likelihood that past experience will produce correct guides to current practice depends on the signal-to-noise ratio for the clinical problem of interest. If the signal-to-noise ratio is high, the...Full Text Available

1996-01-01

206

Sodium/Calcium Exchangers Selectively Regulate Calcium Signaling in Mouse Taste Receptor Cells  

UK PubMed Central (United Kingdom)

Taste cells use multiple signaling mechanisms to generate appropriate cellular responses to discrete taste stimuli. Some taste stimuli activate G protein coupled receptors (GPCRs) that cause calcium...Full Text Available

2010-07-01

207

Signal and imaging sciences workshop proceedings  

Energy Technology Data Exchange (ETDEWEB)

Papers are presented in the areas of: Medical Technologies; Non-Destructive Evaluation; Applications of Signal/Image Processing; Laser Guide Star and Adaptive Optics; Computational Electromagnetic, Acoustics and Optics; Micro-Impulse Radar Processing; Optical Applications; TANGO Space Shuttle.

1997-11-01

208

RXR activators molecular signalling: involvement of a PPAR?-dependent pathway in the liver and kidney, evidence for an alternative pathway in the heart  

UK PubMed Central (United Kingdom)

In this study we compared the molecular signalling elicited by rexinoids, selective retinoid X receptor (RXR)-activators, in several organs (i.e. liver, kidney,...Full Text Available

2003-03-01

209

PyEEG: An Open Source Python Module for EEG/MEG Feature Extraction  

UK PubMed Central (United Kingdom)

Computer-aided diagnosis of neural diseases from EEG signals (or other physiological signals that can be treated as time series, e.g., MEG) is an emerging field that has gained much attention in past...Full Text Available

2011-01-01

210

Phosphatidic acid signaling to mTOR: Signals for the survival of human cancer cells  

UK PubMed Central (United Kingdom)

During the past decade elevated phospholipase D (PLD) activity has been reported in virtually all cancers where it has been examined. PLD catalyzes the hydrolysis of phosphatidylcholine to generate...Full Text Available

2009-09-01

211

Monitoring the Simultaneous Presentation of Spatialized Speech Signals in a Virtual Acoustic Environment.  

Science.gov (United States)

The effect of spatial auditory information on a listener's ability to detect, identify, and monitor multiple simultaneous speech signals was evaluated using virtual audio technology. Factorial combinations of three variables - the number of localized spee...

1998-01-01

212

Mapping the Spatiotemporal Dynamics of Calcium Signaling in Cellular Neural Networks Using Optical Flow  

UK PubMed Central (United Kingdom)

An optical flow gradient algorithm was applied to spontaneously forming networks of neurons and glia in culture imaged by fluorescence optical microscopy in order to map functional calcium signaling...Full Text Available

2010-08-01

213

Lnk constrains myeloproliferative diseases in mice  

UK PubMed Central (United Kingdom)

Hematopoietic stem and progenitor cell (HSPC) expansion is regulated by intrinsic signaling pathways activated by cytokines. The intracellular kinase JAK2 plays an essential role in cytokine signaling,...Full Text Available

2010-06-01

214

Listeria monocytogenes Infection Induces Prosurvival Metabolic Signaling in Macrophages?  

UK PubMed Central (United Kingdom)

Host cells use metabolic signaling through the LXRα nuclear receptor to defend against Listeria monocytogenes infection. 25-Hydroxycholesterol is a natural ligand of LXRs that...Full Text Available

2011-04-01

215

Lifespan extension by increased expression of the Drosophila homologue of the IGFBP7 tumour suppressor  

UK PubMed Central (United Kingdom)

Mammals possess multiple insulin-like growth factor (IGF) binding proteins (IGFBPs), and related proteins, that modulate the activity of insulin/IGF signalling (IIS), a conserved neuroendocrine signalling...Full Text Available

2011-02-01

216

JAK/STAT Pathways in Cytokine Signaling and Myeloproliferative Disorders  

UK PubMed Central (United Kingdom)

Hematopoiesis is the cumulative result of intricately regulated signaling pathways that are mediated by cytokines and their receptors. Studies conducted over the past 10 to 15 years have revealed that...Full Text Available

2010-10-01

217

Interictal Functional Connectivity of Human Epileptic Networks Assessed by Intracerebral EEG and BOLD Signal Fluctuations  

UK PubMed Central (United Kingdom)

In this study, we aimed to demonstrate whether spontaneous fluctuations in the blood oxygen level dependent (BOLD) signal derived from resting state functional magnetic resonance imaging (fMRI) reflect...Full Text Available

218

Insulin-Like Growth Factor I Receptor Signaling Is Required for Exercise-Induced Cardiac Hypertrophy  

UK PubMed Central (United Kingdom)

The receptors for IGF-I (IGF-IR) and insulin (IR) have been implicated in physiological cardiac growth, but it is unknown whether IGF-IR or IR signaling are critically required. We generated mice with...Full Text Available

2008-11-01

219

Functional Analysis of the Murine Cytomegalovirus Chemokine Receptor Homologue M33: Ablation of Constitutive Signaling Is Associated with an Attenuated Phenotype In Vivo?  

UK PubMed Central (United Kingdom)

The murine cytomegalovirus (MCMV) M33 gene is conserved among all betaherpesviruses and encodes a homologue of seven-transmembrane receptors (7TMR) with the capacity for constitutive signaling. Previous...Full Text Available

2008-02-01

220

Female Scent Signals Enhance the Resistance of Male Mice to Influenza  

UK PubMed Central (United Kingdom)

BackgroundThe scent from receptive female mice functions as a signal, which stimulates male mice to search for potential mating partners. This searching behavior is coupled with...Full Text Available

221

Differential interleukin-6/Stat3 signaling as a function of cellular context mediates Ras-induced transformation  

UK PubMed Central (United Kingdom)

IntroductionTyrosine phosphorylated signal transducer and activator of transcription 3 (pStat3) is expressed in numerous cancers and is required for mediating tumorigenesis. Autocrine...Full Text Available

2010-01-01

222

Characterization of Cytokinin and Adenine Transport in Arabidopsis Cell Cultures1[OA  

UK PubMed Central (United Kingdom)

Cytokinins are distributed through the vascular system and trigger responses of target cells via receptor-mediated signal transduction. Perception and transduction of the signal can occur at the plasma...Full Text Available

2008-12-01

223

Association Study of Serine Racemase Gene with Methamphetamine Psychosis  

UK PubMed Central (United Kingdom)

Experimental studies have demonstrated that not only dopaminergic signaling but also glutamatergic/NMDA receptor signaling play indispensable roles in the development of methamphetamine psychosis. Our...Full Text Available

2011-03-01

224

Artificial neural network alarm method based on signal time-frequency characteristics  

International Nuclear Information System (INIS)

On the problem of alarm when parts are falling in nuclear power plant, the artificial neural network (ANN) alarm method based on the signal time-frequency characteristics was developed. The method was realized by the improved BP algorithm, and demonstrated with the data from simulation experiments

1998-06-01

225

A Preference for a Sexual Signal Keeps Females Safe  

UK PubMed Central (United Kingdom)

Predation is generally thought to constrain sexual selection by female choice and limit the evolution of conspicuous sexual signals. Under high predation risk, females usually become less choosy, because...Full Text Available

226

49 CFR 236.206 - Battery or power supply with respect to relay; location.  

Science.gov (United States)

...2010-10-01 2010-10-01 false Battery or power supply with respect to relay...Signal Systems Standards § 236.206 Battery or power supply with respect to relay; location. The battery or power supply for each signal...

2010-10-01

231

NEUROPLASTICITY and INNOVATION  

Science.gov (United States)

OF VOCALIZED SPEECH THROUGH. ANALYSIS OF NEURAL SIGNALS. " SYNTHETIC TELEPATHY- WIRELESS. TRANSMISSION OF DECODED. THOUGHTS. " IMPLANTABLE MEMORY-ELIMINATES ...

233

FADC signal reconstruction for the MAGIC telescope  

Energy Technology Data Exchange (ETDEWEB)

Until April 2007 the Major Atmospheric Gamma ray Imaging Cherenkov (MAGIC) telescope used a 300 MSamples/s flash analog-to-digital converter (FADC) system to sample the shaped photomultiplier tube (PMT) signals produced by the captured Cherenkov photons of air showers. Different algorithms to reconstruct the signal from the read-out samples (extractors) have been implemented and are described and compared. Criteria based on the obtained charge and time resolution/bias are defined and used to judge the different extractors, by applying them to calibration, cosmic and pedestal signals. The achievable charge and time resolution have been derived as functions of the number of incident photo-electrons.

2008-09-11

234

Enabling Lightwave Electronics with Nanotechnology ...  

Science.gov (United States)

... Acousto-optic programmable dispersive filters (AOPDF) have been developed for optical signal processing, polarization switching in lasers, and ...

2011-03-29

235

Development and Calibration of Two and Four Wire Water ...  

Science.gov (United States)

... measurement. Power spectral density measurements are made by the dynamic signal analyzer for each channel. A cross power ...

1992-12-01

239

Spectroscopic detection  

Energy Technology Data Exchange (ETDEWEB)

In embodiments, spectroscopic monitor monitors modulated light signals to detect low levels of contaminants and other compounds in the presence of background interference. The monitor uses a spectrometer that includes a transmissive modulator capable of causing different frequency ranges to move onto and off of the detector. The different ranges can include those with the desired signal and those selected to subtract background contributions from those with the desired signal. Embodiments of the system are particularly useful for monitoring metal concentrations in combustion effluent.

2003-01-01

240

Signal processing methods for MFE plasma diagnostics  

Energy Technology Data Exchange (ETDEWEB)

The application of various signal processing methods to extract energy storage information from plasma diamagnetism sensors occurring during physics experiments on the Tandom Mirror Experiment-Upgrade (TMX-U) is discussed. We show how these processing techniques can be used to decrease the uncertainty in the corresponding sensor measurements. The algorithms suggested are implemented using SIG, an interactive signal processing package developed at LLNL.

1985-02-01

241

Optimal Quantum State Estimation by No-Signaling Principle  

CERN Document Server

We obtain a simple derivation of the optimal quantum state estimation of a two-level system using the no-signaling principle. In particular, we show that the no-signaling principle determines the unique form of the guessing probability, independently to a given figure of merit such as the fidelity or the information gain. This proves that optimal measurements for a two-level quantum system is the same for almost all figures of merit.

2010-01-01

242

ATP-gated P2X3 receptors constitute a positive autocrine signal for insulin release in the human pancreatic ? cell  

UK PubMed Central (United Kingdom)

Extracellular ATP has been proposed as a paracrine signal in rodent islets, but it is unclear what role ATP plays in human islets. We now show the presence of an ATP signaling pathway that enhances...Full Text Available

2010-04-06

243

Cyclic Spectral Analysis of Radio Pulsars  

CERN Document Server

Cyclic spectral analysis is a signal processing technique designed to deal with stochastic signals whose statistics vary periodically with time. Pulsar radio emission is a textbook example of this signal class, known as cyclostationary signals. In this paper, we discuss the application of cyclic spectral analysis methods to pulsar data, and compare the results with the traditional filterbank approaches used for almost all pulsar observations to date. In contrast to standard methods, the cyclic spectrum preserves phase information of the radio signal. This feature allows us to determine the impulse response of the interstellar medium and the intrinsic, unscattered pulse profile directly from a single observation. We illustrate these new analysis techniques using real data from an observation of the millisecond pulsar B1937+21.

2011-01-01

244

A Preliminary Investigation of the Reinforcement Function of Signal Detections in Simulated Baggage Screening: Further Support for the Vigilance Reinforcement Hypothesis  

Science.gov (United States)

The vigilance reinforcement hypothesis (VRH) asserts that errors in signal detection tasks are partially explained by operant reinforcement and extinction processes. VRH predictions were tested with a computerized baggage screening task. Our experiment evaluated the effects of signal schedule (extinction vs. variable interval 6 min) and visual field complexity (dial vs. baggage x-ray) on search behavior rates. There was a main effect for signal schedule [F (1, 20) = 14.0, p = 0.001, p[subscript rep] = 0.99], but no effects for field complexity or interaction. The VRH suggests that performance errors in visual screening work may be reduced through operant conditioning of search behaviors by intensive management of artificially planted signals. (Contains 1 table and 3 figures.)

2008-12-01

245

A simple 5-DoF MR-compatible motion signal measurement system.  

Science.gov (United States)

The purpose of this study was to develop a simple motion measurement system with magnetic resonance (MR) compatibility and safety. The motion measurement system proposed here can measure 5-DoF motion signals without deteriorating the MR images, and it has no effect on the intense and homogeneous main magnetic field, the temporal-gradient magnetic field (which varies rapidly with time), the transceiver radio frequency (RF) coil, and the RF pulse during MR data acquisition. A three-axis accelerometer and a two-axis gyroscope were used to measure 5-DoF motion signals, and Velcro was used to attach a sensor module to a finger or wrist. To minimize the interference between the MR imaging system and the motion measurement system, nonmagnetic materials were used for all electric circuit components in an MR shield room. To remove the effect of RF pulse, an amplifier, modulation circuit, and power supply were located in a shielded case, which was made ...

2011-09-01

246

Investigation of the effect of laundering the ground crew chemical defense overgarment on toxic-free-area vapor transfer during shelter entry by initially contaminated personnel. Interim report, Oct 87-Jan 88  

Energy Technology Data Exchange (ETDEWEB)

A study by the U.S. Air Force School of Aerospace Medicine, Brooks AFB, Texas, has compared the shelter processing transfer of chemical warfare agent simulant vapor for subjects wearing unwashed and laundered ground-crew chemical defense overgarments. Twice laundered and four times laundered protective garments were included in the assessment. Test subjects, wearing the unwashed and laundered protective garments were initially sprayed with liquid simulant (methyl salicylate) to a target density of 5 g m-2. They were then sequentially processed into and through the USAFSAM Collective Protection Shelter (SCPS-2B) test facility. Immediately upon entry to the Toxic-Free Area, the subjects were confined in individual off gassing booths for 2 h while offgassed simulant vapor concentration in the booths was recorded. The resulting mean maximum vapor concentrations recorded in the booths for subjects who had worn unwashed and ...

1990-12-01

247

Vapor phase lubrication of a Ni-based superalloy  

Energy Technology Data Exchange (ETDEWEB)

In addition to ceramics, alloys such as tool steel and nickel- and iron-based superalloys are being considered for high temperature applications such as missile bearings and low heat rejection engines. Studies were made to lubricate a nickel-based superalloy at 500{degrees}C, by using a vaporized aryl phosphate ester, at a concentration of 0.1% in air. From deposition and wear studies it was found that it was impossible to form a good polymeric coating on the superalloy surface. Energy dispersive X-ray analyzer (EDXA) analysis showed that this was due to minute quantities of aluminum in the alloy segregating to the surface, upon being heated to 500{degrees}C, forming a passive oxide coating. It was necessary to activate the surface, in order to lubricate the material successfully. A method of activation by electrodepositing the surface with a layer of iron oxide was developed. Once activated, a good lubricous polymer was formed on the superalloy surface. Tests ...

1995-03-01

248

Synopsis of hydrologic data collected by waste management for characterization of unsaturated transport at Area G  

Energy Technology Data Exchange (ETDEWEB)

Data which have been collected by Los Alamos National Laboratory waste management for the hydrologic characterization of the subsurface at the low level radioactive waste disposal facility, Area G, are reported and discussed briefly. The data includes Unsaturated Flow Apparatus measurements of the unsaturated conductivity in samples from borehole G-5. Analysis compares these values to the predictions from van Genuchten estimates, and the implications for transport and data matching are discussed, especially at the location of the Vapor Phase Notch (VPN). There, evaporation drives a significant vapor flux and the liquid flux cannot be measured accurately by the UFA device. Data also include hydrologic characterization of samples from borehole G-5, Area G surface soils, Los Alamos (Cerros de Rio) basalt, Tsankawi and Cerro-Toledo layers, the Vapor Phase Notch (VPN), and additional new samples from the uppermost tuff layer at ...

1998-03-01

249

Studies about the separation of molecular species of hydrogen's isotopes by cryogenic distillation in a plant for heavy water detritiation  

Energy Technology Data Exchange (ETDEWEB)

Cryogenic distillation is the main industrial method for separating hydrogen's isotopes, because it presents the advantage of high separating factors and also the possibility of processing great quantities of gases. In the case of multicomponent mixtures the determination of transport for molecular species between the two phases is very difficult owing to the particularities of physical characteristics of each component from the mixture. The transport of molecular species is also strongly influenced by the hydrodynamics of two phases, in strong connection with the dimension of the interface between the vapor and liquid phase. The characteristics of the interface depend on the type and geometry of the separation area: plates or package. The traditional methods of analysis for exchange processes use the concept 'theoretic plate', a physical entity for which the values of concentrations for vapors and liquid that leaves ...

1998-07-01

250

Performance analysis on a hybrid air-conditioning system of a green building  

Energy Technology Data Exchange (ETDEWEB)

This paper presents the performance analysis on a hybrid air-conditioning system according to the hybrid building energy system of the green building demonstration project in Shanghai, in which a 150 m{sup 2} solar collector is used to power two 10 kW adsorption chillers, a vapor compression heat pump is used to cool air in the evaporating end while the condensing heating at about 80{sup o}C is fully used to regenerate a liquid desiccant dehumidification system. In the hybrid system, the sensible cooling to the air is treated mainly by solar adsorption cooling and vapor compression cooling, whereas the latent heat is treated by the liquid desiccant dehumidification system with regeneration from the condensing heat of the heat pump. The results show that the performance of this system is 44.5% higher than conventional vapor compression system at a latent load of 30% and this improving can be achieved by 73.8% at a 42% latent ...

2006-05-15

251

Laboratory studies of gas generation and potential for tank wall corrosion during blending of high-level wastes at the West Valley Demonstration Project  

Energy Technology Data Exchange (ETDEWEB)

Laboratory experiments were conducted to simulate the transfer of acidic THOREX waste from Tank 8D-4 into the alkaline PUREX waste in Tank 8D-2 at West Valley. The purpose of the experiments was to explore means of minimizing the production of nitric oxide (NO) gas during mixing of the two wastes and to assess the potential for the gas to further react in the vapor space possibly leading to enhanced corrosion of the tank walls. Forty one THOREX/PUREX mixing tests were conducted to explore the effects of stirring rate, pH, THOREX addition rate, THOREX or PUREX dilution, and temperature. The two most important criteria for minimizing NO production were to maintain some degree of agitation and the keep the pH in the PUREX high, preferably >12. Steel corrosion tests were performed in the presence of low partial pressures of NO{sub 2} and liquid water or water vapor. The NO{sub 2} (from oxidation of NO in the vapor space) ...

1995-05-01

252

Investigation of natural circulation two-phase flow behaviour in header manifold using CFD code  

Energy Technology Data Exchange (ETDEWEB)

The three-dimensional (3-D), multiphase, computational fluid dynamic (CFD) code FLUENT is used to simulated two-phase flow behaviour in a CANDU header manifold under low (natural circulation) flow conditions. This behaviour was previously inferred from experimental data. The CFD simulations reported here are being used to support these inferences and to obtain a better understanding of phase distribution in the header manifold. The simulations seem to show that the vapor-water mixture models in the FLUENT code do not capture properly phase separation in the header and proper phase branching at the header-feeder connections that have been observed in experiments at low flows. The simulations using discrete-phase model in FLUENT, which tracks the pathlines of the individual vapor bubbles in the water continuum phase, show interesting, complicated and, in some cases, unexpected bubble trajectories from the point of injection of the bubbles at a ...

2006-07-01

253

Charts give vapor loss from internal floating-roof tanks  

Energy Technology Data Exchange (ETDEWEB)

Nomographs have been constructed to estimate the average evaporation loss from internal floating-roof tanks. Loss determined from the charts can be used to evaluate the economics of seal conversion and to reconcile refinery, petrochemical plant, and storage terminal losses. The losses represent average standing losses only. They do not cover losses associated with the movement of product into or out of the tank. The average standing evaporation loss from an internal floating-roof tank depends on: vapor pressure of the product; type and condition of roof seal; tank diameter; and type of fixed roof support. The nomographs can estimate evaporation loss for product true vapor pressures (TVP) ranging from 1.5 to 14 psia, the most commonly used seals for average and tight fit conditions, tank diameters ranging from 50 to 250 ft, welded and bolted designs, and both self-supporting and column-support fixed roof designs. The charts are purposely limited ...

1987-03-09

254

Water-repellency and antibacterial activities of plasma-treated cleavable silicone surfactants on nylon fabrics  

British Library Electronic Table of Contents (United Kingdom)

In this paper we describe how cleavable surfactants decompose into water-insoluble silanols and two water-soluble products when subjected to vacuum plasma treatment. We used Raman spectroscopic analysis to confirm these structural changes, and we performed contact angle measurements and employed scanning electron microscopy to observe the surface morphologies of these compounds. Our contact angle measurements confirm that the products had degraded on nylon fabrics during argon gas plasma treatment. All of the PEG-silicone polyesters displayed excellent water-repellency; PEG6000-silicone exhibited the largest contact angle (130?) and, hence, the greatest water-repellency. Our results indicate that the silanols that form upon plasma treatment may be useful in coatings applications. We also f...

2006-01-01

255

Time reversible evolution via nonadiabatic coupling in adiabatic dark subspace  

British Library Electronic Table of Contents (United Kingdom)

We propose a method for the creation of arbitrary superposition of N atomic states using generalized stimulated Raman adiabatic passage (STIRAP) techniques with laser fields coupling each one of N lower states to a single upper state in a Formula Not Shown -level atomic system. Formula Not Shown dark states that are composed of N lower states span a dark subspace. In the adiabatic limit, the dark and bright subspaces are decoupled, thus the nonadiabatic interaction within this dark subspace dominates the evolution of the system. Different from general methods to create our required coherent superposition state, in a reverse way, here we consider the required state as the starting point of evolution dynamics, and utilize laser fields to drive it into a single lower state step by step. Time ...

2010-01-01

256

Structure and Optical Properties of Silicon Layers with GaSb Nanocrystals Created by Ion-Beam Synthesis  

International Nuclear Information System (INIS)

We have studied the ion-beam synthesis of GaSb nanocrystals in Si by high-fluence '' hot '' implantation of Sb and Ga ions followed by thermal annealing. The Rutherford backscattering, transmission electron microscopy/transmission electron diffraction, Raman spectroscopy and photoluminescence were used to characterize the implanted layers. It was found that the nanocrystal size increases from 5 to 60 nm in the samples annealed at 900"oC up to 20-90 nm in those annealed at 1100"oC. For the samples annealed at 900"oC a broad band in the region of 0.75-1.05 eV is registered in the photoluminescence spectra. The nature of this photoluminescence band is discussed. (author)

2011-07-01

257

Spectroscopy of gadolinium gallium garnet crystals doped with Y b3+ revisited  

International Nuclear Information System (INIS)

The optical spectroscopy measurements of gadolinium gallium garnet (GGG) crystals doped with Yb show evidence of the presence of non-equivalent optical centers with very similar radiative decay rates. The energy level schemes of those centers have been determined on the basis of optical absorption, luminescence and Raman experiments. Crystal field fitting resulted in two sets of slightly different crystal field parameters for two non-equivalent Yb centers. Both sets of parameters describe perfectly the experimentally detected Y b3+ energy levels. Correlation between systematic trends in the experimental energy level schemes and crystal field parameters is discussed.

2010-06-30

258

Spectral investigation of primary uranyl orthophosphate  

International Nuclear Information System (INIS)

By methods of vibrational (infrared, Raman) and PMR spectroscopy, crystallohydrate forms of monosubstituted uranyl orthophosphate have been examined. The vibrational frequencies of the groupings from the compounds were identified. The existence of non-equivalent H_2PO_4"--groups in the substances under investigation was ascertained. It has been suggested that one of them is a bridged group, and the other is the end group. A fragment of the VO_2(H_2PO_4)_2 hydrate structure is given, its main constituents being uranylphosphate chains. The analysis of water vibrations assumes coordination of one mole of H_2O in VO_2(H_2PO_4)_2:3H_2O to uranium, while two other molecules are only hydrogen-bonded with phosphate anions. Absorption within the region of 2100-2550 cm"-"1 is assigned to vibrations of O...H...O groupings.

259

SRS conversion of XeCl laser radiation into shifted Stokes components  

International Nuclear Information System (INIS)

An experimental study and a theoretical simulation were made of stimulated Raman scattering (SRS) conversion into shifted components. It was found that there were optimal values of the pressure and focal distance for conversion into the first 'blue' satellite of the first Stokes component. A study was made of the spatial and temporal dynamics of SRS conversion, which took into account generation of the shifted components. It was demonstrated theoretically and experimentally that the satellite intensity could be enhanced significantly by additional electron-collision excitation of the vibrational levels in the conversion medium or by the application of pairs of pump pulses. The maximum efficiency of conversion to the first 'blue' satellite of the first Stokes component was 10% and the satellite intensity reached one-third of the intensity of the main Stokes line. (nonlinear optical phenomena and devices)

1998-01-31

260

Resonance Raman and photophysical studies of transition metal complexes in solution and entrapped in zeolites  

Science.gov (United States)

We have obtained convincing evidence for localization of the optical electron on a single-ring fragment of a chelated bipyridine-like'' ligand (ie., pyridylpyrazine or 4-Methyl-bipyridine). In addition we have completed studies of Ru(bipyrazine){sub 3}{sup 2+} in aqueous sulfuric acid (0--98% by weight) and find clear evidence for sequential addition of six-protons to the six peripheral nitrogen atoms. Studies of zeolite-entrapped complexes are continuing and a series of homo- and heteroleptic complexes have been prepared and characterized. Finally, the synthesis of zeolite-entrapped metallophthalocyanines has now been developed and the copper and cobalt analogues synthesized. The characterization of these materials is now in progress.

1992-03-31

261

Polymer-metal complex as gel electrolyte for quasi-solid-state dye-sensitized solar cells  

International Nuclear Information System (INIS)

A kind of polymer-metal complex gel electrolyte is successfully prepared and is used in dye-sensitized solar cells. Raman and X-ray photoelectron spectroscopy confirm the structure of this complex and is found that the metal ion reacts with nitrogen in the polymer. This novel electrolyte shows apparent diffusion coefficient of iodide of 8.37 x 10-7 cm2 s-1 and the energy conversion efficiency of 6.10% when the amount of ZnI2 is 0.04 M. By studying the dissociation active energy of the inorganic salt in electrolytes, we find that the metal salts can dissociate more easily after reacting with polymer and as a result can provide extra free iodide ion. The cell maintains ca. 93% of its initial efficiency after 20 d without further sealing, which shows good long-time stability.

2011-01-01

262

Parametric upconversion of TM and Trivelpiece-Gould (TG) modes to high frequency Free Electron Laser (FEL)  

International Nuclear Information System (INIS)

A backward wave oscillator (BWO) filled with a strongly magnetized plasma supports TM and Trivel-piece-Gould (TG) modes. At large amplitudes these modes may act as wigglers for generating millimeter waves via free electron laser instability. The nonlinear coupling between the wiggler, the beam space charge mode, and the high frequency free electron laser wave is dominated by parallel motions. In the Raman regime the growth rate of instability goes as #approx##omega#_p_b"1"/"2/#gamma#_o"9"/"4, where #omega#_p_b is the beam plasma frequency and #gamma#_o is the relativistic gamma factor.

263

Observation of the microstructural changes in lithium titanate by multi-ion irradiation  

Energy Technology Data Exchange (ETDEWEB)

The irradiation behavior of Li{sub 2}TiO{sub 3} under a fusion reactor environment was simulated by simultaneous irradiation of Li{sub 2}TiO{sub 3} by the triple ion beams and the respective single ion beams of O{sup 2+}, He{sup +} and H{sup +}. The microstructural changes in Li{sub 2}TiO{sub 3} caused by the irradiation were measured by Raman spectroscopy and FT-IR photoacoustic spectroscopy. The results suggest that the formation of TiO{sub 2} due to displacements by irradiation occurs, and the irradiation defects generated by irradiation trap hydrogen and increase the amount of hydroxyl near the surface. Such phenomena are believed to significantly affect the chemical form of the released tritium and the tritium inventory in the breeding materials of a fusion reactor.

2004-08-01

264

Observation of the microstructural changes in lithium titanate by multi-ion irradiation  

International Nuclear Information System (INIS)

The irradiation behavior of Li_2TiO_3 under a fusion reactor environment was simulated by simultaneous irradiation of Li_2TiO_3 by the triple ion beams and the respective single ion beams of O"2"+, He"+ and H"+. The microstructural changes in Li_2TiO_3 caused by the irradiation were measured by Raman spectroscopy and FT-IR photoacoustic spectroscopy. The results suggest that the formation of TiO_2 due to displacements by irradiation occurs, and the irradiation defects generated by irradiation trap hydrogen and increase the amount of hydroxyl near the surface. Such phenomena are believed to significantly affect the chemical form of the released tritium and the tritium inventory in the breeding materials of a fusion reactor.

2004-08-01

265

Nano silicon for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

New results for two types of nano-size silicon, prepared via thermal vapour deposition either with or without a graphite substrate are presented. Their superior reversible charge capacity and cycle life as negative electrode material for lithium-ion batteries have already been shown in previous work. Here the lithiation reaction of the materials is investigated more closely via different electrochemical in situ techniques: Raman spectroscopy, dilatometry and differential electrochemical mass spectrometry (DEMS). The Si/graphite compound material shows relatively high kinetics upon discharge. The moderate relative volume change and low gas evolution of the nano silicon based electrode, both being important points for a possible future use in real batteries, are discussed with respect to a standard graphite electrode. (author)

2006-11-12

266

Ion implantation into concave polymer surface  

Energy Technology Data Exchange (ETDEWEB)

A new technique for ion implantation into concave surface of insulating materials is proposed and experimentally studied. The principle is roughly described by referring to modifying inner surface of a PET (polyethylene terephthalate) bottle. An electrode that is supplied with positive high-voltage pulses is inserted into the bottle. Both plasma formation and ion implantation are simultaneously realized by the same high-voltage pulses. Ion sheath with a certain thickness that depends on plasma parameters is formed just on the inner surface of the bottle. Since the plasma potential is very close to that of the electrode, ions from the plasma are accelerated in the sheath and implanted perpendicularly into the bottle's inner surface. Laser Raman spectroscopy shows that the inner surface of an ion-implanted PET bottle is modified into DLC (diamond-like carbon). Gas permeation measurement shows that gas-barrier property enhances due to the modification.

2006-01-15

267

Investigation of A_1_g phonons in YBa_2Cu_3O_7 by means of linearized-augmented-plane-wave atomic-force calculations  

International Nuclear Information System (INIS)

We report first-principles frozen-phonon calculations for the determination of the force-free geometry and the dynamical matrix of the five Raman-active A_1_g modes in YBa_2Cu_3O_7. To establish the shape of the phonon potentials atomic forces are calculated within the linearized-augmented-plane-wave method. Two different schemes emdash the local-density approximation (LDA) and a generalized gradient approximation (GGA)emdash are employed for the treatment of electronic exchange and correlation effects. We find that in the case of LDA the resulting phonon frequencies show a deviation from experimental values of approximately -10%. Invoking GGA the frequency values are significantly improved and also the eigenvectors are in very good agreement with experimental findings. copyright 1997 The American Physical Society.

268

Free electron laser: general concepts and present state of practical importance  

International Nuclear Information System (INIS)

Since the advent of the first free electron laser (FEL) in 1976 up to now, a series of principles, configurations and operation modes of these FELs have been devised and partially implemented. The principles refer to transverse FEL, longitudinal FEL, combined FEL, and transverse optical klystron FEL. Configurations may be standard or many-stage and the undulators may be magnetostatic, electrostatic or electromagnetic. The operation regimes may be low-gain Compton type, high-gain Compton type, Raman type, with and without space charge. The operation modes may be the amplification of an external coherent EM radiation, a self-amplified spontaneous emission (SASE), or an oscillator. The paper presents in detail these concepts and the limit between classical approach and the quantum approach of FEL. (Author).

1994-09-21

269

Electrochemical performance of flowerlike CaSnO{sub 3} as high capacity anode material for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Nanosized CaSnO{sub 3} is synthesized by a hydrothermal process and characterized by X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM). The SEM observation shows the sample has a porous flowerlike morphology. The electrochemical results exhibit that the stable and reversible capacity of 547 mAh g{sup -1} is obtained after 50 cycles at 60 mA g{sup -1} (0.1 C) and the corresponding charge capacity is determined to be 316 mAh g{sup -1} at the current density of 2.5 C. Cyclic voltammetry and electrochemical impedance spectroscopy data are analyzed to complement the galvanostatic results. The observed excellent performance is attributed to the porous structure and large surface area of flowerlike CaSnO{sub 3}.

2010-04-30

270

Electrochemical deposition of indium sulfide thin films using two-step pulse biasing  

British Library Electronic Table of Contents (United Kingdom)

Indium sulfide thin films were deposited onto indium-tin-oxide coated glass substrate by electrochemical deposition from an aqueous solution containing In2 (SO4) 3 and Na2S2O3. The deposition conditions were optimized on the basis of data obtained by scanning electron microscope, Auger electron spectroscopy and optical transmission measurements. Furthermore, the photosensitivity of the films was observed by means of photoelectrochemical measurements, which confirmed that the indium sulfide showed n-type conduction. The X-ray diffraction and Raman studies revealed that the as-grown films were amorphous or nanocrystalline in nature and became polycrystalline In2S3 after annealing.

2008-01-01

271

Characteristics of diethylenetriamine-crosslinked cotton stalk/wheat stalk and their biosorption capacities for phosphate  

British Library Electronic Table of Contents (United Kingdom)

Two polymeric biosorbents were prepared from cotton stalk (CS) and wheat straw (WS) by the epichlorohydrin-diethylenetriamine-trimethylamine method. Amine-crosslinked cotton stalk (AC-CS) and wheat stalk (AC-WS) were used for the adsorption of phosphate, and their physicochemical properties as well as biosorption properties for phosphate were discussed intensively. Results indicated that the contents of holocellulose in CS and WS corresponded to the distinct phosphate adsorption capacities between AC-CS and AC-WS. Zeta potential and Raman spectra analysis illustrated the electrostatic attraction between phosphate ions and biosorbents. The adsorption of phosphate was not strongly pH dependent when the pH was about 4.0-9.0. The Langmuir isotherm provided the better fit and the maximum adsorp...

2011-01-01

272

Cationic cyclization of purified natural rubber in latex form with a trimethylsilyl triflate as a novel catalyst  

British Library Electronic Table of Contents (United Kingdom)

Cyclization of deproteinized natural rubber (DPNR) or purified natural rubber latex was effectively performed in latex phase by using trimethylsilyl-trifluoromethane sulfonate or trimethylsilyl triflate (TMSOTF) as a novel catalyst, which is still not reported in the case of natural rubber latex. Various cyclization conditions affecting the degree of cyclization were studied, such as dry rubber contents, temperature, TMSOTF concentrations, and time. The cyclized products were characterized by FTIR, Raman, 1H-, and 13C-NMR spectroscopies, as well as DSC and TGA. The degree of cyclization was estimated by 1H-NMR spectrum. It was found that the degree of cyclization in NR was a function of cyclization conditions. The thermal stability of cyclized DPNR increased with the degree of cyclization....

2007-01-01

273

Calibration of Initial Measurements from the Full Aperture Backscatter system on NIF  

Energy Technology Data Exchange (ETDEWEB)

The Full Aperture Backscatter System (FABS) provides a measure of the spectral power, and integrated energy scattered by stimulated Brillouin (348-354 nm) and Raman (400 - 700 nm) scattering into the final focusing lens of the first four beams of the NIF laser. The system was designed to provide measurements at the highest expected fluences with: (1) spectral and temporal resolution, (2) beam aperture averaging, and (3) near-field imaging. This is accomplished with a strongly attenuating diffusive fiber coupler and streaked spectrometer and separate calibrated time integrated spectrometers, and imaging cameras. Measurement of the wavelength dependent sensitivity of the complete system is accomplished with a calibrated Xe lamp. Data from the calibration system is combined with experimental data to produce the power and energy measurements. Examples of measurements will be discussed.

2004-04-01

274

Brown diamonds from an eclogite xenolith from Udachnaya kimberlite, Yakutia, Russia  

British Library Electronic Table of Contents (United Kingdom)

Abstract: We have performed petrographic and spectroscopic studies of brown diamonds from an eclogite xenolith from the Udachnaya pipe (Yakutia, Russia). Brown diamonds are randomly intermixed with colorless ones in the rock and often located at the grain boundaries of clinopyroxene and garnet. Brown diamonds can be characterized by a set of defects (H4, N2D and a line at 490.7nm) which are absent in colorless diamonds. This set of defects is typical for plastically deformed diamonds and indicates that diamonds were likely annealed for a relatively short period after deformation had occurred. Excitation of brown colored zones with a 632.8nm He-Ne laser produced the typical diamond band plus two additional bands at 1730cm^-^1 and 3350cm^-^1. These spectral features are not genuine Raman ban...

2011-01-01

275

A study of the effects of MeV alpha particles in PE and PVDC  

Energy Technology Data Exchange (ETDEWEB)

We have mapped and studied the effects of MeV alpha-particle bombardment in polyvinylidene chloride (PVDC) and polyethylene (PE). We used 3.5 and 5.0 MeV alpha-particle incident beams and stacked polymer films to separate the contributing effects of the electronic ({var_epsilon}{sub e}) and nuclear ({var_epsilon}{sub n}) stopping powers. The electrical conductance and change in the chemical structures were measured by direct resistivity measurement, Raman microprobe, RBS and FTIR. The results indicate significant differences in the ({var_epsilon}{sub e}) and ({var_epsilon}{sub n}) effects at higher alpha-particle bombardment fluences. {copyright} {ital 1997 American Institute of Physics.}

1997-02-01

276

A simple one-step fabrication of micrometer-scale hierarchical TiO2 hollow spheres  

British Library Electronic Table of Contents (United Kingdom)

Hierarchical TiO2 hollow spheres had been prepared based on bubble templates by a simple one-step hydrothermal method. The diameter of hollow spheres was about 700nm and the shell thickness of them was 69nm. They were composed of similar spindle- or needle-like building units. Furthermore, hydrothermal time had an important influence on the morphology and crystallinity of hollow spheres. Moreover, the UV-Vis diffuse reflectance spectra of TiO2 hollow spheres heated at 150^oC for 10h showed the strongest absorption in the UV-Vis region and the Raman spectrum demonstrated the anatase sample. Additionally, a possible formation mechanism of TiO2 hollow spheres was proposed. So this novel and simple method would provide a development direction to fabricate all kinds of inorganic hollow spheres ...

2010-01-01

277

The influence of electromagnetic field irradiated by high-voltage transmission lines on properties of cells.  

Science.gov (United States)

The influence of low-frequency electromagnetic field irradiating by high-voltage transmission lines on signal transduction of cell in spleen cells of the rates have been studied by molecular-biology techniques. The spleen cells are extracted from skilled rates, which are exposed in the electromagnetic field of high-voltage transmission lines with 4000 V/m and 0.09-0.1 G about 400 days. The quantity or level of phosphorylation of signal transducer and activator of transcription (STAT3) in JAK-STAT signal transduction pathway of spleen cells, which are stimulated and unstimulated by IL-2, respectively, are detected by the immunoblotting and immunobiochemistry. The results show that the expression of phospho-STAT3 in spleen cell stimulated by IL-2 differ not from that in the unstimulated cell. The former is significantly large than the latter. This shows that signal transduction of cell is affected by this ...

2005-01-01

278

Signal Processing in Large Systems: a New Paradigm  

CERN Document Server

For a long time, signal processing applications, and most particularly detection and parameter estimation methods, have relied on the limiting behaviour of test statistics and estimators, as the number n of observations of a population grows large comparatively to the population size N, i.e. n>>N. Modern technological and societal advances now demand the study of sometimes extremely large populations, while simultaneously requiring fast signal processing due to accelerated system dynamics; this results in not-so-large practical ratios n/N, sometimes even smaller than one. A disruptive change in classical signal processing methods has therefore been initiated in the past ten years, mostly spurred by the field of large dimensional random matrix theory. The early literature in random matrix theory for signal processing applications is however scarce and highly technical. This tutorial proposes an ...

2011-01-01

279

Negative regulation of {beta}-catenin/Tcf signaling by naringenin in AGS gastric cancer cell  

Science.gov (United States)

Functional activation of {beta}-catenin/Tcf signaling plays an important role in early events in carcinogenesis. We examined the effect of naringenin against {beta}-catenin/Tcf signaling in gastric cancer cells. Reporter gene assay showed that naringenin inhibited {beta}-catenin/Tcf signaling efficiently. In addition, the inhibition of {beta}-catenin/Tcf signaling by naringenin in HEK293 cells transiently transfected with constitutively mutant {beta}-catenin gene, whose product is not phosphorylated by GSK3{beta}, indicates that its inhibitory mechanism was related to {beta}-catenin itself or downstream components. To investigate the precise inhibitory mechanism, we performed immunofluorescence, Western blot, and EMSA. As a result, our data revealed that the {beta}-catenin distribution and the levels of nuclear {beta}-catenin and Tcf-4 proteins were unchanged after naringenin treatment. Moreover, the ...

2005-09-30

280

MRI with pathogenic correlation of small renal cell carcinoma  

Energy Technology Data Exchange (ETDEWEB)

MRI, ultrasonography and angiography were performed on 24 cases with small renal cell carcinoma, and data were compared with pathological architecture type. An average diameter of cancer was 20.8 mm (10-30 mm). Each tumor was pathologically classified into four architecture types: alveolar type (15 cases), papillary type (5 cases), tubular type (3 cases) and cystic type (1 case). In comparison with renal cortex alveolar type renal cell carcinoma showed equal or low signal in T1-weighted images and equal or high signal in T2-weighted images. Papillary and tubular types showed high signal in T1-weighted images, and low signal in T2-weighted images. In alveolar type, many cases showed equal echo in ultrasonography and hypervascularity in angiography, and in papillary and tubular types, many cases showed high echo and hypovascularity. There were many cases with papillary type small cell carcinoma which ...

1999-11-01

281

Effect of Wnt-1 inducible signaling pathway protein-2 (WISP-2/CCN5), a downstream protein of Wnt signaling, on adipocyte differentiation  

British Library Electronic Table of Contents (United Kingdom)

Wnt signaling negatively regulates adipocyte differentiation, and ectopic expression of Wnt-1 in 3T3-L1 cells induces several downstream molecules of Wnt signaling, including Wnt-1 inducible signaling pathway protein (WISP)-2. In this study, we examined the role of WISP-2 in the process of adipocyte differentiation using an in vitro cell culture system. In the differentiation of 3T3-L1 cells, WISP-2 expression was observed in growing cells and declined thereafter. In the mitotic clonal expansion phase of adipocyte differentiation, WISP-2 expression was transiently down-regulated concurrently with up-regulation of CCAAT/enhancer-binding protein d expression. Treatment of 3T3-L1 cells in the differentiation medium with lithium, an activator of Wnt signaling, inhibited the differentiation pro...

2009-01-01

282

Comparative experimental study of dual energy subtraction and conventional digital radiography on chest  

International Nuclear Information System (INIS)

Objective: To compare the efficiency of dual energy subtraction and conventional direct digital radiography in signal detecting ability. Methods: 200 plastic balls which were 4 mm in diameter were taken as signals and were placed on a 10 cm thick plastic board and the right upper thorax of a healthy volunteer. The signals were examined by DES and CDR separately and were estimated by 3 radiologists with 5-value-differentiation method. ROC curve analysis was made by ROC kit software. Results: when signals on plastic board were detected by CDR and DES, ROC curve analysis indicated that there was no significant difference (P=0.4851 > 0.05, two-tailed) between the area under the ROC curves of the two methods (Az=0.9931 for CDR and Az=0.9879 for DES). The difference was significant (P=0.0002 <0.01, two-tailed) between the area under the ROC curves of CDR and DES (Az=0.7276 for CDR and Az=0.8561 for ...

2005-06-01

283

Blind source separation of convolutive mixtures of non circular linearly modulated signals with unknown baud rates  

CERN Document Server

This paper addresses the problem of blind separation of convolutive mixtures of BPSK and circular linearly modulated signals with unknown (and possibly different) baud rates and carrier frequencies. In previous works, we established that the Constant Modulus Algorithm (CMA) is able to extract a source from a convolutive mixture of circular linearly modulated signals. We extend the analysis of the extraction capabilities of the CMA when the mixing also contains BPSK signals. We prove that if the various source signals do not share any non zero cyclic frequency nor any non conjugate cyclic frequencies, the local minima of the constant modulus cost function are separating filters. Unfortunately, the minimization of the Godard cost function generally fails when considering BPSK signals that have the same rates and the same carrier frequencies. This failure is due to the existence of ...

2011-01-01

284

cw operation of an AlGaInP double heterostructure laser diode at 77 K grown by atmospheric metalorganic chemical vapor deposition  

Science.gov (United States)

Continuous wave operation of an Al/sub 0.21/Ga/sub 0.31/In/sub 0.48/P /Ga/sub 0.52/In/sub 0.48/P /Al/sub 0.21/Ga/sub 0.31/In/sub 0.48/P double heterostructure (DH) laser diode was achieved for the first time at 77 K. The device was made from a DH wafer grown by atmospheric metalorganic chemical vapor deposition using triethyl metals and phosphine as source materials. At 77 K, the lasing wavelength was 0.653 ..mu..m and the threshold current was 55 mA for a diode with a nitride-insulated, 8-..mu..m-wide and 250-..mu..m-long stripe geometry.

1984-09-15

285

Waste minimization in a non-production oriented metal finishing operation  

Energy Technology Data Exchange (ETDEWEB)

This paper provides information on activities undertaken in a non- production oriented metal finishing operation to minimize waste and conserve resources. The facility is a 6000 sq foot shop that typically only deals with prototype parts. Utilizing a plan that includes employee awareness, common sense and existing technology, a noticeable reduction in waste volume has been obtained. Initiatives that are covered include: segregation of cyanide plating solutions, elimination of copper cyanide plating, elimination of hexavalent chromium plating, elimination of vapor degreasing, changing of rinsing practices, and changing a process for cleaning of aluminum parts. Some discussion is also presented on the effectiveness of combining the technologies of physical vapor deposition and electrodeposition to help minimize waste. Plans for additional initiatives including water recycling, elimination of cyanide plating and substitution of electrodeposition ...

1991-11-01

286

Thermal gradient humidification-dehumidification desalination system  

Energy Technology Data Exchange (ETDEWEB)

A solar energy desalination process utilizing solar radiation directly for the evaporation of salt water is described. Ambient air takes on water vapor as the air passes through an evaporative medium. It is then directed between a saline water-covered, solar absorbing surface and a solar collecting housing. The resulting heated and moisture-saturated air is cooled in a heat exchange means where condensation of fresh water occurs. Simultaneously, cool salt water is utilized as the cooling water in the heat exchange means, and takes on the heat of condensation given up by the condensing vapor. The heated salt water from the heat exchange means is partially directed over the solar absorbing surface, and at least a portion of it is also directed to wet the evaporative medium. Several optional sub-processes are described for operation of the system during periods of reduced insolation, and an alternative process is described for operation of the ...

1982-12-14

287

Terahertz time-domain spectroscopy of atmospheric water vapor from 0.4 to 2.7 THz.  

Energy Technology Data Exchange (ETDEWEB)

We conducted broadband absorption measurements of atmospheric water vapor in the ground state, X {sup 1}A{sub 1} (000), from 0.4 to 2.7 THz with a pressure broadening-limited resolution of 6.2 GHz using pulsed, terahertz time-domain spectroscopy (THz-TDS). We measured a total of seventy-two absorption lines and forty-nine lines were identified as H{sub 2}{sup 16}O resonances. All the H{sub 2}{sup 16}O lines identified were confirmed by comparing their center frequencies to experimental values available in the literature.

2005-10-01

288

Tank 241-AZ-101 Mixer Pump Test Vapor Sampling and Analysis Plan  

Energy Technology Data Exchange (ETDEWEB)

This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for vapor samples obtained during the operation of mixer pumps in tank 241-AZ-101. The primary purpose of the mixer pump test (MPT) is to demonstrate that the two 300 horsepower mixer pumps installed in tank 241-AZ-101 can mobilize the settled sludge so that it can be retrieved for treatment and vitrification. Sampling will be performed in accordance with Tank 241-AZ-101 Mixer Pump Test Data Quality Objective (Banning 1999) and Data Quality Objectives for Regulatory Requirements for Hazardous and Radioactive Air Emissions Sampling and Analysis (Mulkey 1999). The sampling will verify if current air emission estimates used in the permit application are correct and provide information for future air permit applications.

2000-04-10

289

Separation of magnesium from magnesium chloride and zirconium and/or hafnium subchlorides in the production of zirconium and/or hafnium sponge metal  

International Nuclear Information System (INIS)

This patent describes the producing of a refractory metal wherein a sponge refractory metal is produced as an intermediate product by the use of magnesium with the incidental production of magnesium chloride, and wherein residual magnesium is separated from the magnesium chloride and from refractory metal to a vacuum distillation step which fractionally distills the magnesium, the magnesium chloride, and the metal sub-chlorides; the steps of: recovering fractionally distilled vapors of magnesium chloride and metal sub-chlorides from a sponge refractory metal; separately condensing the vapors as separately recovered; and recycling the separately recovered magnesium at a purity of at least about 96%.

1990-09-21

290

Selective formation of ZnO nanodots on nanopatterned substrates by metalorganic chemical vapor deposition  

International Nuclear Information System (INIS)

Selective formation of ZnO nanodots was accomplished by metalorganic chemical vapor deposition on nanopatterned SiO_2/Si substrates. Self-organized ZnO nanodots were selectively formed in nanopatterned lines of Si created by etching of SiO_2 with focused ion beam (FIB), whereas any nanodots were hardly observed on the SiO_2 surface in the vicinity of the FIB-sputtered Si areas. The mechanism of the selective formation of ZnO nanodots on FIB-nanopatterned lines is mainly attributed to the effective migration of Zn adatoms diffusing on the SiO_2 surface into the Si lines followed by the nucleation at surface atomic steps and kinks created by Ga"+ ion sputtering. Cathodoluminescence measurements confirmed that the emission originated from the selectively grown ZnO nanodots.

2003-10-27

291

Room-temperature continuous-wave operation of a GaInP/AlGaInP multiquantum well laser grown by metalorganic chemical vapor deposition  

Science.gov (United States)

Room-temperature continuous-wave (cw) operation of a GaInP/AlGaInP multiquantum well (MQW) laser was achieved for the first time. The threshold current was 70 mA at 22 /sup 0/C for a device with an 8-..mu..m-wide and a 250-..mu..m-long planar stripe. The emission wavelength was 668 nm. The characteristic temperature T/sub 0/ was 138 K under cw operation. The wafer with the MQW structure composed of 100-A-thick GaInP wells and 40-A-thick AlGaInP barrier layers was grown by atmospheric pressure metalorganic chemical vapor deposition.

1987-04-20

292

Photocatalytic degradation of gaseous pyridine over zeolite-supported titanium dioxide  

Energy Technology Data Exchange (ETDEWEB)

The photocatalyzed degradation of pyridine in the gas phase was investigated using titanium dioxide semiconductor supported on mordenite. The complete mineralization was found to occur over a catalyst containing 75 wt% TiO{sub 2} and 25 wt% mordenite in about 180 min in the presence of saturated water vapor at O{degrees}C (4.6 Torr). Low water vapor pressure of 0.096 Torr was found to be sufficient to achieve a reasonably high percentage and rate of degradation. Diffusion of pyridine within the catalyst adversely affects the activity when the thickness of the catalyst coating exceeds the penetration depth of illumination. The activity of the zeolite-supported catalysts was higher than that of TiO{sub 2}. The photonic efficiency for the complete mineralization of pyridine to CO{sub 2} was determined to be 0.48. 29 refs., 6 refs., 1 tab.

1994-09-01

293

Optoelectronic devices grown by metallo-organic chemical vapor deposition  

International Nuclear Information System (INIS)

The metallo-organic chemical vapor deposition (MOCVD) process has been used with great success to grow AlGaAs-GaAs and InGaAsP-InGaAs-InP heterostructure materials for electronic and optoelectronic applications. Devices fabricated from Al/sub x/Ga/sub 1-x/As-GaAs heterostructures grown by MOCVD include bipolar transistors, field-effect transistors (FETs), high-mobility (or modulation-doped) FETs, large-area high-efficiency solar cells, low-threshold lasers, high-power lasers, quantum-well lasers, and visible lasers. The state of the art for the MOCFD growth of optoelectronic devices is reviewed in this paper, and some comments are made regarding future trends in the growth of these materials by MOCVD.

294

Microgravity two-phase flow regime modeling  

Energy Technology Data Exchange (ETDEWEB)

A flow pattern or flow regime is the characteristics spatial distribution of the phases of fluid in a duct. Since heat transfer and pressure drop are dependent on the characteristic distribution of the phases, it is necessary to describe flow patterns in an appropriate manner so that a hydrodynamic or heat transfer theory applicable to that pattern can be chosen. The objective of the present analysis is to create a flow regime map based on physical modeling of vapor/liquid interaction phenomena in a microgravity environment. In the present work, four basic flow patterns are defined: dispersed flow, stratified flow, slug flow, and annular flow. Fluid properties, liquid and vapor flow rates, and pipe size were chosen as the principal parameters. It is assumed that a transition from one flow pattern to another will occur when there is a change in the dominant force which controls that flow pattern. The forces considered in this modeling are ...

1987-01-01

295

Mechanism of the electric field effect on the intensity of visible continuum emission from the positive column of gas discharge in a cesium vapor-xenon mixture  

British Library Electronic Table of Contents (United Kingdom)

We have studied the nature of continuum emitted in the visible spectral range from a noncontracted positive column of discharge in a cesium vapor-xenon mixture at a pressure of 45 Torr and at a degree of ionization below 3 ? 10?6. The main contribution to the continuous emission under such conditions is due to electron-xenon atom bremsstrahlung. The intensity of emission has been experimentally and theoretically studied as a function of the electric field strength and electron density in the positive column. It is established that an increase in the visible emission intensity with the electric field strength is related to an increase in the number of hot electrons in plasma.

2007-01-01

296

Excess Gibbs free energies and excess volumes of mixtures containing normal alkanes or cyclohexane + thiaalkanes or dithiaalkanes  

Energy Technology Data Exchange (ETDEWEB)

Vapor-liquid equilibria, by head-space gas-chromatographic analysis of the equilibrated vapor phase directly withdrawn from the equilibration apparatus, and molar excess volumes, V[sup E], by means of a vibrating-tube densimeter, of binary mixtures containing thiaalkanes or dithiaalkanes with n-alkanes or cyclohexane, were determined at 298.15 K. The excess molar Gibbs free energies, GE, of the examined mixtures were obtained by a least-squares treatment of the equilibrium data. The GE and V[sup E] values indicate that the steric effect exerted by the alkyl groups adjacent to the S group causes a regular decrease of the G[sup E] (or V[sup E]) with increasing the number of alkyl groups in the thiaalkane. A tentative approach, based on an additivity scheme of surface interactions combined with the scaled particle theory, is presented to estimate the energies of solvation in terms of group contributions.

1993-10-01

297

Elucidating two-phase transport in a polymer electrolyte fuel cell, Part 1: Characterizing flow regimes with a dimensionless group  

British Library Electronic Table of Contents (United Kingdom)

This paper explores the through-/in-plane characteristics of water transport in the cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC). Theoretical analysis is performed on the non-isothermal two-phase flow under flow channels. A dimensionless group Da (Damkohler number for PEFC operation), defined as the ratio of water generation rate to water vapor-phase removal rate, is formulated to characterize the flow regimes in a PEFC. This group, lumping geometrical parameters and physical properties, compares the water vapor-phase removal capability (via water diffusion and holding capacity) with the rate of water production by the oxygen reduction reaction. We find that this dimensionless group can be used to characterize the non-isothermal, two-phase phenomena: when Da&...

2011-01-01

298

A novel accelerated oxidative stability screening method for pharmaceutical solids  

British Library Electronic Table of Contents (United Kingdom)

Abstract Despite the fact that oxidation is the second most frequent degradation pathway for pharmaceuticals, means of evaluating the oxidative stability of pharmaceutical solids, especially effective stress testing, are still lacking. This paper describes a novel experimental method for peroxide-mediated oxidative stress testing on pharmaceutical solids. The method utilizes urea-hydrogen peroxide, a molecular complex that undergoes solid-state decomposition and releases hydrogen peroxide vapor at elevated temperatures (e.g., 30C), as a source of peroxide. The experimental setting for this method is simple, convenient, and can be operated routinely in most laboratories. The fundamental parameter of the system, that is, hydrogen peroxide vapor pressure, was determined using a modified spect...

2011-01-01

299

A mobile remote sensing laboratory for water vapor, trace gas, aerosol, and wind speed measurements  

Energy Technology Data Exchange (ETDEWEB)

The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.

1993-03-19

300

Traffic signal control for a multi-forked road  

British Library Electronic Table of Contents (United Kingdom)

Traffic jams have become very serious at multiforked road intersections, and conventional pre-timed controls are less effective in such situations. In this article, a new traffic signal control system for multi-forked roads is proposed. First, the cellular automaton (CA) model is used to develop a traffic simulator for multi-forked roads. Next, a stochastic model of a traffic jam is built up. In addition, a new traffic signal control algorithm is designed using the optimization technique and a genetic algorithm (GA). Finally, the effectiveness of the proposed method is shown using actual traffic data with a traffic simulator.

2011-01-01

301

Signal simulator for the calibration of eddy current probes  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a signal simulator which is designed to calibrate eddy current probes. By using simultaneously an excitation coil and an electrically conducting plane, the simulator can emulate signals which correspond to spot welds with different flaws. The presence of a conducting plane allows a wide variation of the amplitude and phase of the excitation coil voltage during the calibration of a probe. A mathematical model for the simulator is derived and used to study the variation of the impedance change upon the parameters of the probe. Numerical computation shows that the impedance change depends in an important way on the frequency of the excitation coil current.

1994-01-01

302

Ruling out a 4th generation using limits on hadron collider Higgs signals  

CERN Document Server

We consider the impact of a 4th generation on Higgs to $\\gamma\\gamma$ and $WW,ZZ$ signals and demonstrate that the Tevatron and LHC have essentially eliminated the possibility of a 4th generation if the Higgs is SM-like and has mass below 200 GeV. We also show that the absence of enhanced Higgs signals in current data sets in the $\\gamma\\gamma$ and $WW,ZZ$ final states can strongly constrain (almost eliminate) the possibility of a 4th generation in two-Higgs-doublet models of type II (in the MSSM).

2011-01-01

303

Preparatory Signal Detection for Annex I Countries under the Kyoto Protocol. A Lesson for the Post-Kyoto Policy Process  

Energy Technology Data Exchange (ETDEWEB)

The focus of this study is on the preparatory detection of uncertain net greenhouse gas (GHG) emission changes (also termed emission signals) under the Kyoto Protocol. The crucial question to be addressed is: How well do we need to know net emissions if we want to detect a specified emission signal after a given time? No restrictions exist as to what concerns the net emitter, which may be any GHG source or sink. Annex I countries are chosen as net emitters, simply for reasons of data availability and because of the excellent possibility of comparing net emitters (inter-country comparison). The countries' emissions - in an increasing number of cases even their uncertainties - are available permitting the application of preparatory signal detection techniques, which are suited to address the aforementioned question. We currently discuss four hierarchically-ordered detection concepts to assess emission ...

2004-06-14

304

Phenomenological study of light-induced effects in #alpha#-Al_2O_3:C  

International Nuclear Information System (INIS)

A computerised glow curve deconvolution (CGCD) analysis was applied to the main dosimetric peak of #alpha#-Al_2O_3:C in order to study the effects of light on the glow curve shape. It was shown that both the light-induced signal and the light-induced fading effects tend to shift the main dosimetric peak to higher temperatures and at the same time change its shape. Furthermore it was confirmed that the magnitude of the light-induced signal depends on radiation history and, by increasing the duration of light exposure, the magnitude of the light-induced signal reaches a plateau, thereby implying the saturation of the phototransfer process. (author).

1995-07-10

305

Nutrition and Physical Activity in Aging, Obesity, and Cancer  

British Library Electronic Table of Contents (United Kingdom)

The liver is a primary target of growth hormone (GH). GH signals are mediated by the transcription factor signal transducer and activator of transcription 5 (STAT5). Here, we focus on recent discoveries about the role of GH-STAT5 signaling in hepatic physiology and pathophysiology. We discuss roles of the GH-STAT5 axis in body growth, lipid metabolism, and the cell cycle pertaining to hepatosteatosis, fibrosis, and hepatocellular carcinoma. Finally, we discuss recent discoveries about the role of GH-STAT5 in sex-specific gene expression and bile acid, steroid, and drug metabolism.

2011-01-01

306

Confocal Imaging of Biological Tissues Using Second Harmonic Generation  

Energy Technology Data Exchange (ETDEWEB)

A confocal microscopy imaging system was devised to selectively detect Second harmonic signals generated by biological tissues. Several types of biological tissues were examined using this imaging system, including human teeth, bovine blood vessels, and chicken skin. All these tissues generated strong second harmonic signals. There is considerable evidence that the source of these signals in tissue is collagen. Collagen, the predominant component of most tissues, is known to have second order nonlinear susceptibility. This technique may have diagnostic usefulness in pathophysiological conditions characterized by changes in collagen structure including malignant transformation of nevi, progression of diabetic complications, and abnormalities in wound healing.

2000-03-06

307

Time Integrating Optical Signal Processing  

Science.gov (United States)

... The acousto-optic device have a 30 MHz 1 ... coherent systems including compact non-coherent optical ... a relatively simple phase switching approach. ...

1981-07-01

308

The mass dependence of the signal peak height of a Bragg-curve ionization chamber  

International Nuclear Information System (INIS)

The Bragg-curve detector of the parallel plate ionization chamber type generates a signal that is a distorted replica of the original Bragg-curve. In result of this distortion, the signal peak height is not only a function of the atomic number of the heavy ion, as it is often stated, but also of the particle mass. This mass effect was studied with the aid of computer simulation, and it was found to be dependent on the Frisch grid to anode gap width and on the detector gas. The charge resolution of the detector is affected very significantly by this mass dependence of the signal peak height. Therefore, a careful selection of the detector gas and the grid to anode gap width is necessary, if good charge resolution over a wide range of heavy ions is required. (orig.).

309

The androgen receptor governs the execution, but not programming, of male sexual and territorial behaviors  

UK PubMed Central (United Kingdom)

SUMMARYTestosterone and estrogen are essential for male behaviors in vertebrates. How these two signaling pathways interact to control masculinization of the brain and behavior...Full Text Available

2010-04-29

310

The Natural Statistics of Audiovisual Speech  

UK PubMed Central (United Kingdom)

Humans, like other animals, are exposed to a continuous stream of signals, which are dynamic, multimodal, extended, and time varying in nature. This complex input space must be transduced and sampled...Full Text Available

2009-07-01

311

Telomeres and telomerase in cancer  

UK PubMed Central (United Kingdom)

Myriad genetic and epigenetic alterations are required to drive normal cells toward malignant transformation. These somatic events commandeer many signaling pathways that cooperate to endow aspiring...Full Text Available

2010-01-01

312

Superterrorism and the Military Instrument of Power  

Science.gov (United States)

... Defense. ... 6 Specific restrictions are outlined in US Signals Intelligence Directive (USSID) 18 and DoD Regulation 5240.1-R. 7 House ...

1998-04-01

313

Strings, tachyons and deconfinement  

Energy Technology Data Exchange (ETDEWEB)

We argue that the tachyons which exist in some string models are a signal of deconfinement. We compare the deconfinement temperature obtained from Monte Carlo calculations with some string models. (orig.).

1985-10-17

314

Strings, tachyons and deconfinement  

International Nuclear Information System (INIS)

We argue that the tachyons which exist in some string models are a signal of deconfinement. We compare the deconfinement temperature obtained from Monte Carlo calculations with some string models. (orig.).

315

Retinoids for Treatment of Retinal Diseases  

UK PubMed Central (United Kingdom)

Knowledge about retinal photoreceptor signal transduction and the visual cycle required for normal eyesight has expanded exponentially over the past decade. Substantial progress in human genetics...Full Text Available

2010-06-01

316

R/V Laurence M. Gould LMG0303 - Development of a luminescence - NASA  

Science.gov (United States)

R/V Laurence M. Gould LMG0303 - Development of a luminescence dating capability for Antarctic glaciomarine sediments: Tests of signal zeroing at the ...

317

Polymer Genomics: An Insight into Pharmacology and Toxicology of Nanomedicines 1  

UK PubMed Central (United Kingdom)

Synthetic polymers and nanomaterials display selective phenotypic effects in cells and in the body that affect signal transduction mechanisms involved in inflammation, differentiation, proliferation,...Full Text Available

2006-12-30

318

Photonic Devices and Systems for Optical Signal Processing  

Science.gov (United States)

... lasers, model switched optical memory elements ... Optical RS flip flop, Acousto-optic switches. ... FLOP CIRCUITS, OPTICAL SWITCHING, NOR GATES ...

1993-08-01

319

Performance Evaluation of Several Types of Pulsed Eddy Current Probes for Detecting Wall Thickness Reduction  

Science.gov (United States)

In this paper, four different types of pulsed eddy current (PEC) probe are designed and their performance of detecting wall thickness reduction is compared. By using the backward difference method in time and the finite element method in space, PEC signals from various thickness and materials are numerically calculated and three features of the signal are selected. Since PEC signals and features are obtained by various types and sizes of probe, the comparison is made through the normalized features which reflect the sensitivity of the feature to thickness reduction. The normalized features indicate that the shielded reflection probe provides the best sensitivity to wall thickness reduction for all three signal features. Results show that the best sensitivity to thickness reduction is achieved by the peak value, but also suggest that the time to peak can be a good candidate because of its linear ...

2010-02-01

320

Optical dating: insufficiently bleached sediments  

International Nuclear Information System (INIS)

Although infrared-stimulated luminescence (IRSL) signals in feldspars can be bleached rapidly by sunlight, there could still be a small amount of IRSL signal remaining in sediment grains if they have experienced only relatively short sunlight exposure before deposition. This remaining signal results in a ''remnant dose'' stored in the grain and is important for young samples but negligible for old samples. Several methods have been introduced to detect insufficient bleaching, and some of them can provide information on the extent of the bleaching. Others can only distinguish between samples bleached for a very long time and for a short time. Empirical methods are introduced to evaluate the possible values of equivalent dose accumulated since the grains were deposited. These methods involve the analysis of the equivalent doses and the natural IRSL signals obtained using single-disc dose determination ...

1993-07-01

321

Optical Processing of Microwave Signals - Part B  

Science.gov (United States)

... switching off all the pixels causes all the spectrum lines to disappear (top of Figure 6), next, that switching off one ... Acousto-optic spectrum analyser ...

2003-04-01

322

On the spontaneous emergence of cell polarity  

UK PubMed Central (United Kingdom)

Diverse cell polarity networks require positive feedback for locally amplifying distributions of signalling molecules at the plasma membrane1. Additional...Full Text Available

2008-08-14

323

Neural processing of asynchronous audiovisual speech perception  

UK PubMed Central (United Kingdom)

The temporal synchrony of auditory and visual signals is known to affect the perception of an external event, yet it is unclear what neural mechanisms underlie the influence of temporal synchrony...Full Text Available

2010-02-15

324

N92-22051  

Science.gov (United States)

The KDP crystal was 10 cm long and cut such that the c-axis was 50.3* to the normal of its input face. We selected for study idler and signal beams ...

325

Medium voltage analytical electron microscopy microanalysis versus radiation damage  

Energy Technology Data Exchange (ETDEWEB)

The kinetic energy transferred to some elements by an electron of kinetic energy 100 to 400 kV is discussed. The displacement rates are compared to the signal generation. (DCL)

1985-09-01

327

Mass dependence of the signal peak height of a Bragg-curve ionization chamber  

Energy Technology Data Exchange (ETDEWEB)

The Bragg-curve detector of the parallel plate ionization chamber type generates a signal that is a distorted replica of the original Bragg-curve. In result of this distortion, the signal peak height is not only a function of the atomic number of the heavy ion, as it is often stated, but also of the particle mass. This mass effect was studied with the aid of computer simulation, and it was found to be dependent on the Frisch grid to anode gap width and on the detector gas. The charge resolution of the detector is affected very significantly by this mass dependence of the signal peak height. Therefore, a careful selection of the detector gas and the grid to anode gap width is necessary, if good charge resolution over a wide range of heavy ions is required.

1985-01-01

328

Levels of mesenchymal FGFR2 signaling modulate smooth muscle progenitor cell commitment in the lung  

British Library Electronic Table of Contents (United Kingdom)

Fibroblast growth factor (FGF) signaling has been shown to regulate lung epithelial development but its influence on mesenchymal differentiation has been poorly investigated. To study the role of mesenchymal FGF signaling in the differentiation of the mesenchyme and its impact on epithelial morphogenesis, we took advantage of Fgfr2c+/? mice, which due to a splicing switch express Fgfr2b in mesenchymal tissues and manifest Apert syndrome-like phenotypes. Using a set of in vivo and in vitro studies, we show that an autocrine FGF10?FGFR2b signaling loop is established in the mutant lung mesenchyme, which has several consequences. It prevents the entry of the smooth muscle progenitors into the smooth muscle cell (SMC) lineage and results in reduced fibronectin and elastin deposition. Levels of...

2006-01-01

329

Infrared bleaching of the thermoluminescence of four feldspars  

International Nuclear Information System (INIS)

This paper studies the effect upon the thermoluminescence (TL) signal of four feldspar samples of exposing them to infrared stimulation, as occurs during infrared-stimulated luminescence (IRSL) measurement. Together with pulse annealing measurements these results are used to show which part of the TL signal is removed by exposure to IR and which part is directly related to the IRSL signal that is observed. When the samples are preheated prior to measurement in order to remove any low-temperature (< 200"oC) TL signals, a linear relationship is observed between the amount of TL that is lost and the IRSL light sum that is produced. The IRSL light sum is consistently four times larger than the amount of TL that is lost. Three possible explanations are proposed for this, but no conclusive evidence could be obtained to support any of them. A close similarity is observed in the pulse annealing results and ...

1995-06-01

330

History of the Army Ground Forces. Study Number 13. ...  

Science.gov (United States)

... reconnaissance. Presently the signal ompWa captain rushed up, salutec snappily, anI reported. When the general inquired how. ...

1948-06-30

331

Genomics of human longevity  

UK PubMed Central (United Kingdom)

In animal models, single-gene mutations in genes involved in insulin/IGF and target of rapamycin signalling pathways extend lifespan to a considerable extent. The genetic, genomic and epigenetic influences...Full Text Available

2011-01-12

332

Effect of COX-2 (PGE2) and IL-6 on Prostate Cancer Bone ...  

Science.gov (United States)

... of the AR (25). Dihydrotestosterone increases Wnt signaling activity in preosteoblasts. Functional interactions between ...

2008-02-02

333

ESR dating of fault rocks  

Energy Technology Data Exchange (ETDEWEB)

Past movement on faults can be dated by measurement of the intensity of ESR signals in quartz. These signals are reset by local lattice deformation and local frictional heating on grain contacts at the time of fault movement. The ESR signals then trow back as a result of bombardment by ionizing radiation from surrounding rocks. The age is obtained from the ratio of the equivalent dose, needed to produce the observed signal, to the dose rate. Fine grains are more completely reset during faulting, and a plot of age vs grain size shows a plateau for grains below critical size : these grains are presumed to have been completely zeroed by the last fault activity. We carried out ESR dating of fault rocks collected from the Yangsan fault system. ESR dates from the this fault system range from 870 to 240 ka. Results of this research suggest that long-term cyclic fault activity continued into the pleistocene.

2002-03-15

334

Dysregulation of the mevalonate pathway promotes transformation  

UK PubMed Central (United Kingdom)

The importance of cancer metabolism has been appreciated for many years, but the intricacies of how metabolic pathways interconnect with oncogenic signaling are not fully understood. With a clear understanding...Full Text Available

2010-08-24

335

Digital Hearing Aids: Current "State-of-the-Art"  

Science.gov (United States)

... promise of highly advanced signal processing, ensured that digital hearing aid technology had come of age. So how far have ...

336

Digital Audio Sampling for Film and Video.  

Science.gov (United States)

Digital audio sampling is explained, and some of its implications in digital sound applications are discussed. Digital sound equipment is rapidly replacing analog recording devices as the state-of-the-art in audio technology. The philosophy of digital recording involves doing away with the continuously variable analog waveforms and turning the patterns into numbers. A digital recording device rapidly samples the incoming sounds, quantifying the signal into a series of numerical values (binary codes). Although digital sound eliminates many of the traditional analog problems, digital signal processing presents key problems in sampling rates and synchronization. Careful control is necessary to check signals through each step in the audio chain. The advantages of digital audio processing include increased signal-to-noise ratio, no flutter, transparent generation of copies, and sound manipulation. These ...

1993-03-01

337

Composite vector leptoquarks in [ital e][sup +][ital e[minus  

Energy Technology Data Exchange (ETDEWEB)

We study the signals for composite vector leptoquarks in [ital e][sup +][ital e[minus

1993-02-01

338

Chimpanzees Extract Social Information from Agonistic Screams  

UK PubMed Central (United Kingdom)

Chimpanzee (Pan troglodytes) agonistic screams are graded vocal signals that are produced in a context-specific manner. Screams given by aggressors and victims can be discriminated...Full Text Available

339

Center for Advanced Sensors Year Two Funding (FY2006)  

Science.gov (United States)

... a Networked Embedded Sensing Toolkit (MSR Sense ... edging due to mis-registration than the ... Langrebe, Signal theory in multisensor remote sensing ...

2008-02-26

340

CAAX-box protein, prenylation process and carcinogenesis  

UK PubMed Central (United Kingdom)

CAAX proteins are widely involved in global cellular functions such as proliferation, differentiation, and carcinogenesis. As an important modulator of biological activity, signal transduction via protein...Full Text Available

341

Bacterial chemoreceptors: high-performance signaling in networked arrays  

UK PubMed Central (United Kingdom)

Chemoreceptors are crucial components in the bacterial sensory systems that mediate chemotaxis. Chemotactic responses exhibit exquisite sensitivity, extensive dynamic range and precise adaptation....Full Text Available

2008-01-01

342

Army Communicator. Volume 32, Number 2, Spring 2007  

Science.gov (United States)

... Introduction to the Signal Regiment Cisco Academy 1-4 (CCNA) Engineering Math Basic Electronics/Digital Logic (replaced C Programming ...

2011-05-14

343

An Extended Kalman Filter for Use in a Shared Aperture ...  

Science.gov (United States)

... used to track a point source target ... A one sigma tracking error of .2 ... LOOKING INFRARED SYSTEMS, *KALMAN FILTERING, SIGNAL PROCESSING ...

1978-12-01

344

Advanced readout integrated circuit signal processing  

Science.gov (United States)

Readout integrated circuits (ROICs) for focal plane arrays (FPAs) have become increasingly complex to meet the needs of modern infrared systems. BAE Systems has pioneered a number of advanced signal processing architectures for FPA ROICs. Demonstrated signal processing capabilities of BAE Systems FPAs include analog-to-digital conversion, offset subtraction, individual pixel automatic gain compensation, transient noise suppression, on-FPA defect deselection, reconfigurable pixels, spatial neural network processing and subframe noise averaging. BAE Systems FPA advanced signal processing is not just for demonstrations, but is used in many of their deliverable FPAs, improving real system performance.

2006-06-01

345

A wavelet approach to fault diagnosis of a gearbox under varying load conditions  

British Library Electronic Table of Contents (United Kingdom)

Varying load can cause changes in a measured gearbox vibration signal. However, conventional techniques for fault diagnosis are based on the assumption that changes in vibration signal are only caused by deterioration of the gearbox. There is a need to develop a technique to provide accurate state indicator of gearbox under fluctuating load conditions. This paper presents an approach to gear fault diagnosis based on complex Morlet continuous wavelet transform under this condition. Gear motion residual signal, which represents the departure of time synchronously averaged signal from the average tooth-meshing vibration, is analyzed as source data due to its lower sensitiveness to the alternating load condition. A fault growth parameter based on the amplitude of wavelet transform is proposed ...

2010-01-01

346

A program for passively tracking a target using an array of sensors  

Energy Technology Data Exchange (ETDEWEB)

The problem of passively tracking a moving signal source has importance in a variety of applications such as radar, sonar, seismology, and radio astronomy. In many applications, only limited information is available about the signal source. It will be assumed here that only the signals which are detected by the sensors and the velocity of the source signal are known. The objective of this document is to present a program which passively tracks a target using an array of sensors. This program is available in MATLAB, version 3.5. The algorithm which is implemented consists of three main parts: time delay estimation, passive localization, and data post processing. Each of these parts are discussed, and the mathematical foundation for their solution given. Following, this the organization of the program is presented, and an example of its usage is given.

1993-01-01

348

Sizes, graphitic structures and fractal geometry of light-duty diesel engine particulates.  

Energy Technology Data Exchange (ETDEWEB)

The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and temperature, affected particle sizes ...

2003-01-01

349

Raman spectroscopic studies of liquid phase ordering and dynamics for solutions of ME6N liquid crystal: the approach to simple molecule behavior at high dilutions.  

Science.gov (United States)

We have measured the Raman isotropic profiles of the ?(C?N) band at 2235 cm(-1) for five solutions of ME6N (4-cyanophenyl-4'-hexylbenzoate) liquid crystal dissolved in CCl(4) in the range from x = 0.12 to 0.007 (x, mole fraction of ME6N) and then obtained the corresponding vibrational correlation functions, C(v)(t), by time Fourier transformation. The increase with dilution of the dephasing times ?(v) complies with the behavior of the nonmonotonic concentration dependence predicted by the fluctuation concentration model for this concentration range (x Rothschild, which, being based on the assumption that the environmental modulation is described by a stretched exponential decay e(-(t/?(0))(?)), is more appropriate for the interpretation of the vibrational correlation function arising from a distribution of relaxation processes caused, as in the present case, by the persistence of pseudonematic domains. With dilution the dispersion parameter ? and the average ...

2010-11-11

350

Optical characterization of long-term ordered and nanocrystalline GaP  

International Nuclear Information System (INIS)

The paper generalizes some results of the United States/Moldova program on advanced composite organic and semiconductor light emitters. High density exciton system bound to N impurity superlattice grown by modern technologies and GaP:N, GaP:N:Sm nanocrystals distributed in transparent fluorine-containing polymers will be used as the base elements for new generation of optoelectronic devices. The work seeks to expand further the applications of GaP itself through the formation of nanocomposites. Classic and new methods are applied for preparation of GaP:N nanoparticles with the controlled dimensions developed clear quantum confinement effect. The long-term ordered bulk GaP crystals as well as their nanoparticles have been investigated by TEM, XRD, Raman scattering, and luminescent methods. The evolution of the Raman Light Scattering and luminescence spectra is reported from pure and doped GaP single crystals grown over 40 years ago and evaluated ...

351

Laser Raman scattering measurements of differential molecular diffusion in turbulent nonpremixed jet flames of H{sub 2}/CO{sub 2} fuel  

Science.gov (United States)

This paper explores effects of differential diffusion in nonpremixed turbulent jet flames. Pulsed Raman scattering spectroscopy is used to measure temperature and species concentrations in chemically reacting jets of H{sub 2}/CO{sub 2} into air, over a range of jet Reynolds numbers from 1,000 to 30,000 based on cold jet fluid properties. Results show significant effects of differential diffusion at all jet Reynolds numbers considered. Differential diffusion between H{sub 2} and C0{sub 2} produces differences between the hydrogen element mixture fraction ({xi}{sub H}) and the carbon element mixture fraction ({xi}{sub c}). The greatest effects occur on the rich side of stoichiometric, where {xi}{sub H} is observed to be smaller than {xi}{sub C} at all Reynolds numbers. Differential diffusion between H{sub 2} and H{sub 2}O creates a net flux of hydrogen element toward the stoichiometric contour and causes a local maximum in {xi}H that occurs near the stoichiometric ...

1994-01-01

352

Initiation process of type 1 pitting corrosion on copper water-tubes; Reisui yo dokan ni okeru 1 gata koshoku no hassei  

Energy Technology Data Exchange (ETDEWEB)

Copper tubes have been widely used for water supply and heat exchangers. In such systems copper tubes often suffer from type 1 pitting-corrosion. A mechanism, of the type I pitting-corrosion on copper tubing has been presented, but a initiation mechanism of the pitting corrosion is still unknown. In this paper we aimed to clarify the initiation mechanism of the pitting corrosion. Copper-tube specimens were immersed in a circulating solution. The solution had been used for heat exchangers at a Japanese factory where the water leakage occurred by the pitting corrosion on copper tubes. The solution contained tiny precipitates resulted from corrosion of galvanized steel pipe. During the immersion test changes in the surface state of a copper tube was analyzed by in situ RAMAN (in situ Raman Spectroscopy), SEM (Scanning Electron Microscope), EPMA (Electron Probe Microanalysis), AES (Auger Electron Spectroscopy) and XPS (X-ray Photoelectron ...

1999-07-15

353

Heavy ion induced changes in nuclear waste glasses: a micro Raman investigation  

International Nuclear Information System (INIS)

Borosilicate based glass formulations have been found suitable for fixing the HLW (high level radioactive liquid waste) generated after reprocessing of the spent nuclear fuel. As the glass experiences continuous irradiation by #alpha#, #beta#a, and #gamma# radiations from the radioactive components of HLW, alteration in the glass structure may occur. Understanding of these structural evolutions of the nuclear waste glasses under irradiation is crucial to secure long term disposal and predict their behavior. In the present work, alkali based barium borosilicate glasses, having composition similar to that of Trombay Research Reactor waste glass were irradiated with high energy "1"2C beam and the radiation induced changes were monitored by micro Raman experiment. Since a "1"2C atom can be considered as a cluster of alphas, this beam was chosen to yield linear energy losses (LET) comparable to that in case of a particles. The irradiations were carried out at 30 deg N ...

2010-12-01

354

Formation of silk fibroin nanoparticles in water-miscible organic solvent and their characterization  

Energy Technology Data Exchange (ETDEWEB)

When Silk fibre derived from Bombyx mori, a native biopolymer, was dissolved in highly concentrated neutral salts such as CaCl{sub 2}, the regenerated liquid silk, a gradually degraded peptide mixture of silk fibroin, could be obtained. The silk fibroin nanoparticles were prepared rapidly from the liquid silk by using water-miscible protonic and polar aprotonic organic solvents. The nanoparticles are insoluble but well dispersed and stable in aqueous solution and are globular particles with a range of 35-125 nm in diameter by means of TEM, SEM, AFM and laser sizer. Over one half of the {epsilon}-amino groups exist around the protein nanoparticles by using a trinitrobenzenesulfonic acid (TNBS) method. Raman spectra shows the tyrosine residues on the surface of the globules are more exposed than those on native silk fibers. The crystalline polymorph and conformation transition of the silk nanoparticles from random-coil and {alpha}-helix form (Silk I) into ...

2007-10-15

355

Depth Profiling of N and C in Ion Implanted ZnO and Si Using Deuterium Induced Nuclear Reaction Analysis  

International Nuclear Information System (INIS)

Nuclear Reaction Analysis (NRA) with deuteron ion beams has been used to probe for ion implanted nitrogen and carbon with high sensitivity in zinc oxide and silicon single crystals. The ion implanted N was measured using 1.4 MeV deuteron ion beams and was found to be in agreement with calculated values. The limit of detection for N in ZnO is 8x1014 ions cm-2. Raman measurements of the ion implanted samples showed three additional modes at 275, 504, and 644 cm-1 compared to the un-implanted ZnO crystals. The NRA and Raman results provided information on the N concentration, depth distribution, and structural changes that occur in dependence on the nitrogen ion fluences. The deuterium induced 12C(d,p)13C reaction was used to measure the carbon impurity/dose in ion implanted silicon. It was found that the use of a large cold shield (liquid nitrogen trap) in the ion implanter chamber greatly reduces the amount of carbon impurity on the surface of ...

2008-11-03

356

ul'as , 8L6T 'TE -X@qLuaDaCI 142nOzT,14 SL61 'I AeW -SG4'eC[ lpa ...  

Science.gov (United States)

Superconductivity of A-15 Compounds in the-System Nb-Ge-Sn Synthesized by Chemical Vapor Deposition, -. J. Engelhardt and G. W. Webb, ...

357

U.S. Department of Energy, Nevada Operations Office Environmental Monitoring Program, Summary Data Report, First Calendar Quarter 1996  

Energy Technology Data Exchange (ETDEWEB)

This report discusses environmental surveillance activities conducted on the Nevada Test Site during the first calendar quarter of 1996. Surveillance activities included collection and analysis of air, noble gas, tritiated water vapor, and other water samples. Samples were analyzed for both radiological and non-radiological effluents.

1996-11-01

358

Thermal fatigue failure at the White Cliffs solar thermal power plant  

Energy Technology Data Exchange (ETDEWEB)

The failure of receivers has been one of the main operating problems at the White Cliffs solar thermal power plant. This Technical Note reports the results of an initial investigation that identifies the cause as having been their thermal fatiguing of the tube walls. The fatigue appears to be caused by unstable heat transfer at vapor qualities below the point where critical heat flux is generally exceeded. Methods for avoiding this problem are tested.

1995-02-01

359

Stored light and released fiction  

CERN Document Server

It is shown that the interpretation of the experimental results reported in the publication "Storage of Light in Atomic Vapor" by D.F.Phillips et al., Phys. Rev.Lett. 86, 783 (2001) [quant-ph/0012138] is incorrect. The experimental observation of this paper can be consistently explained in the framework of standard concepts of the physics of optical pumping and has nothing to do with "storage of light", or "dynamic reduction of the group velocity", or "light pulse compression".

2003-01-01

360

Spray Chemical Vapor Deposition of Single-Source Precursors for Chalcopyrite I-III-VI2 Thin-Film Materials  

Science.gov (United States)

Thin-film solar cells on flexible, lightweight, space-qualified substrates provide an attractive approach to fabricating solar arrays with high mass-specific power. A polycrystalline chalcopyrite absorber layer is among the new generation of photovoltaic device technologies for thin film solar cells. At NASA Glenn Research Center we have focused on the development of new single-source precursors (SSPs) for deposition of semiconducting chalcopyrite materials onto lightweight, flexible substrates. We describe the syntheses and thermal modulation of SSPs via molecular engineering. Copper indium disulfide and related thin-film materials were deposited via aerosol-assisted chemical vapor deposition using SSPs. Processing and post-processing parameters were varied in order to modify morphology, stoichiometry, crystallography, electrical properties, and optical properties to optimize device quality. Growth at atmospheric pressure in a horizontal hotwall reactor at 395 C ...

2008-01-01

361

Pyrolysis of dichlorodithiourea cadmium(II)  

Energy Technology Data Exchange (ETDEWEB)

By means of infrared spectroscopy, x-ray diffraction, and differential thermal analysis, the authors investigate the pyrolysis of dichlorodithiourea cadmium, the vapor phase epitaxy of the cadmium sulfide film, and the composition of the solid and gaseous pyrolysis products. Those products are found to include the thiocyanates of guanidine, ammonium, and hydrogen along with cadmium oxides and sulfates and hydrochloric acid.

1987-02-20

362

Performance of a commercial heat pipe under operational conditions  

Energy Technology Data Exchange (ETDEWEB)

The performance of a commercial heat pipe was investigated both experimentally and theoretically. The effect of the temperature difference, the surface area ratio, and the operational conditions on the performance were studied. The heat flow rate and the vapor temperature were estimated on a ready-made commercial heat pipe. Its performance varied considerably with operational conditions. Theoretical consideration of a mathematical model and several nomographs are also presented. This work is applicable to the design and use of heat pipes in the field.

1983-04-01

363

Operational test report integrated system test (ventilation upgrade)  

Energy Technology Data Exchange (ETDEWEB)

Operational Final Test Report for Integrated Systems, Project W-030 (Phase 2 test, RECIRC and HIGH-HEAT Modes). Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks, including upgraded vapor space cooling and filtered venting of tanks AY101, Ay102, AZ101, AZ102.

1999-10-05

364

Nodalization schemes for PGV-440 steam generator model with RELAP5/MOD3  

Energy Technology Data Exchange (ETDEWEB)

Results of calculation of steady thermal-hydraulic characteristics of PVG-440 horizontal steam generator are presented. Steam flows in selected sections are compared to data provided by OKB Gidropress Calculated vapor void fractions are compared to measured ones. (orig.) (3 refs., 3 figs., 8 tabs.).

1993-12-31

365

Nodalization schemes for PGV-440 steam generator model with RELAP5/MOD3  

International Nuclear Information System (INIS)

Results of calculation of steady thermal-hydraulic characteristics of PVG-440 horizontal steam generator are presented. Steam flows in selected sections are compared to data provided by OKB Gidropress Calculated vapor void fractions are compared to measured ones. (orig.) (3 refs., 3 figs., 8 tabs.).

1992-09-29

366

Laser induced fluorescence measurements of the mixing of fuel oil with air  

Energy Technology Data Exchange (ETDEWEB)

We report on measurements of the mixing of fuel oil with air at atmospheric pressure in an industrial premixed gas turbine burner. The concentration of the vaporized fuel oil was measured with laser induced fluorescence. We reason that the fuel oil concentration can be considered with good accuracy as proportional to the fluorescence intensity. (author) 6 fig., 3 refs.

1999-08-01

367

Kinetics of achieving equilibrity at the sorption of radionuclides  

International Nuclear Information System (INIS)

Radionuclide (R) sorption from a solution (vapor) by freshly formed crystals with production of substitution solid solutions under different types of self-disordering is studied. Changes of self-defectiveness and macrodefectiveness with time and effect of radiation defects in the presence of P macroquantities are taken into account. An analysis for monodispersed sorbents is performed. It is shown that the achievement of equilibrium within a reasonable time in impurity-solid phase system depends on defectiveness which ensures a required level of the coefficient of impurity diffusion in sorbent crystals.

368

Heat transfer in boiling liquified gas  

Energy Technology Data Exchange (ETDEWEB)

Means for increasing heat transfer characteristics between the surface of a solid and a boiling liquid are described in which the solid is immersed is comprised of a solid with passages which extend therethrough to the surface for the circulation of liquid through the passages for emergence from the surface to eliminate at least a portion of the unstable vapor film otherwise formed on the surface.

1980-09-23

369

Enhanced Control of Mercury by Wet Flue Gas Desulfurization Systems Site 3 Topical Report.  

Science.gov (United States)

The U.S. Department of Energy and EPRI have co-funded this project to improve the control of mercury emissions from coal-fired power plants equipped with wet flue gas desulfurization (FGD) systems. The project investigated catalytic oxidation of vapor-pha...

2004-01-01

370

Electrophysical properties of supramolecular films of the germanium-oxyethylidenediphosphonic acid complex  

International Nuclear Information System (INIS)

The structure of a fragment of the germanium complex compound (GCC) with oxyethylidenediphosphonic acid and the adsorption properties of GCC films with respect to the vapors of water and some other organic liquids have been studied. The electric conductivity of GCC films has been investigated, and its mechanism has been explained.

2005-04-01

371

EFFECTIVE CONTROL OF SECONDARY WATER POLLUTION FROM FLUE GAS DESULFURIZATION SYSTEMS  

Science.gov (United States)

The report describes tests to demonstrate the feasibility of using a vertical-tube, falling-film, vapor-compression evaporator to concentrate waste water from a flue gas desulfurization (FGD) process. Tests showed that waste water from the Chiyoda FGD process can be concentrated ...

372

Development of High-Efficiency Low-Lift Vapor Compression System - Final Report  

Energy Technology Data Exchange (ETDEWEB)

PNNL, with cofunding from the Bonneville Power Administration (BPA) and Building Technologies Program, conducted a research and development activity targeted at addressing the energy efficiency goals targeted in the BPA roadmap. PNNL investigated an integrated heating, ventilation and air conditioning (HVAC) system option referred to as the low-lift cooling system that potentially offers an increase in HVAC energy performance relative to ASHRAE Standard 90.1-2004.

2010-03-31

373

DOUBLE-SHELL TANK (DST) HYDROXIDE DEPLETION MODEL FOR CARBON DIOXIDE ABSORPTION  

International Nuclear Information System (INIS)

This document generates a supernatant hydroxide ion depletion model based on mechanistic principles. The carbon dioxide absorption mechanistic model is developed in this report. The report also benchmarks the model against historical tank supernatant hydroxide data and vapor space carbon dioxide data. A comparison of the newly generated mechanistic model with previously applied empirical hydroxide depletion equations is also performed.

2009-04-30

374

A review of mesospheric dynamics and chemistry  

Energy Technology Data Exchange (ETDEWEB)

Advances made in understanding the chemistry and dynamics of the atmosphere in the approximate altitude range of 50 to 90 km are addressed. Attention is given to mesospheric structure and seasonal variations, gravity waves and gravity wave saturation, the effects of gravity waves on thermal, momentum and constituent fluxes, and the effect of gravity waves on airglow emissions. A review of research on tides and planetary waves and their effects on the mesosphere are presented as well as discussions on ozone hydroxyl, water vapor, and noctilucent cloud research. 217 refs.

1991-01-01

375

A 3D tomographic EBSD analysis of a CVD diamond thin film  

Energy Technology Data Exchange (ETDEWEB)

We have studied the nucleation and growth processes in a chemical vapor deposition (CVD) diamond film using a tomographic electron backscattering diffraction method (3D EBSD). The approach is based on the combination of a focused ion beam (FIB) unit for serial sectioning in conjunction with high-resolution EBSD. Individual diamond grains were investigated in 3-dimensions particularly with regard to the role of twinning.

2008-09-15

376

Use of signal delay of one of detectors in two-channel radiometric flaw detector  

International Nuclear Information System (INIS)

A possibility is considered or reducing the surface heterogeneity effect of an item being tested on the result of radiation flaw detection by means of signal delay of one of detectors in a two-channel radiometric flaw detector. The exposure of a translationally moving item has been studied as well as an external exposure of a rotating hollow item.

377

Up-Regulation of the RhoA/Rho-Kinase Signaling Pathway in Corpus Cavernosum from Endothelial Nitric-Oxide Synthase (NOS), but Not Neuronal NOS, Null Mice  

UK PubMed Central (United Kingdom)

We tested the hypothesis that the basal release of nitric oxide (NO) from endothelial cells modulates contractile activity in the corpus cavernosum (CC) via inhibition of the RhoA/Rho-kinase signaling...Full Text Available

2010-04-01

378

The analysis of coupled heat and particle transport in Tokamaks by means of Fourier transform  

Energy Technology Data Exchange (ETDEWEB)

A method to deduce the 2 x 2 transport matrix for coupled heat and particle transport in Tokamaks is proposed. The method applies to perturbative experiments, and is based on a Fourier transform of the measured signals of temperature and density. By analyzing different linear combinations of temperature and density, the eigenvectors and eigenvalues of the transport matrix are determined. The method is tested for a number of illustrative cases using simulated data, and the sensitivity to noise on the signals is evaluated. (author).

1992-04-01

379

The Cause of an Eddy Current Signal Noise from a Steam Generator Tube and its Effect on the Detectability of a Crack  

International Nuclear Information System (INIS)

An eddy current inspection has been applied for a pre-service and in-service examination of a steam generator in nuclear power plants. The experience from the inspection of steam generators showed that many plants had an excessive number of tubes with eddy current noise signals over several hundreds, which originated from manufacturing anomalies. The plants in U.S suffered significant downstream inspection costs, history reviews, and diagnostic testing because some signals resembled flaws and others masked a flaw. These lessens learned resulted in issuing the guidelines for steam generator tubing specifications and repair, in order to reduce the number of anomalous signals in the tubes and also to provide the requirement of a signal to noise ratio by applying a field type examination with bobbin coil eddy current probes at a manufacturing process. Besides the noise signals of a ...

2008-05-01

380

Strong WW scattering at photon linear colliders  

Energy Technology Data Exchange (ETDEWEB)

We investigate the possibility of observing strong interactions of longitudinally polarized weak vector bosons in the process {gamma}{gamma}{yields}ZZ at a photon linear collider. We make use of polarization of the photon beams and cuts on the decay products of the Z bosons to enhance the signal relative to the background of transversely polarized ZZ pairs. We find that the background overwhelms the signal unless there are strong resonant effects, as for instance from a technicolor analogue of the hadronic f{sub 2}(1270) meson. ((orig.)).

1995-02-01

381

Strong WW scattering at photon linear colliders  

Energy Technology Data Exchange (ETDEWEB)

We investigate the possibility of observing strong interactions of longitudinally polarized weak vector bosons in the process {gamma}{gamma} {yields} ZZ at a photon linear collider. We make use of polarization of the photon beams and cuts on the decay products of the Z bosons to enhance the signal relative to the background of transversely polarized ZZ pairs. We find that the background overwhelms the signal unless there are strong resonant effects, as for instance from a technicolor analogue of the hadronic f{sub 2}(1270) meson.

1994-06-01

382

Signal transduction pathway controlling synthesis of a class of degradative enzymes in Bacillus subtilis: expression of the regulatory genes and analysis of mutations in degS and degU.  

UK PubMed Central (United Kingdom)

The rates of synthesis of a class of both secreted and intracellular degradative enzymes in Bacillus subtilis are controlled by a signal transduction pathway defined by at least four regulatory genes:...Full Text Available

1990-02-01

383

Roles of the TNF receptor-associated factor (TRAF)2/3 binding site in differential B cell signaling by CD40 and its viral oncogenic mimic, latent membrane protein 1 (LMP1)  

UK PubMed Central (United Kingdom)

The Epstein-Barr virus protein, LMP1, is a functional mimic of the cellular receptor CD40, but signals to B lymphocytes in an amplified and sustained manner compared to CD40. LMP1 contributes...Full Text Available

2009-09-01

384

Real-time monitoring of dosimetry and image quality during digital radiology examinations  

International Nuclear Information System (INIS)

Objective: To explore the feasibility of real-time monitoring exposure dose and image quality by using the data stored in the DICOM image archive of direct digital radiography system. Methods: Model TO. 16 was exposed, the current increased gradually from 0.5 to 125 mAs. The displayed number of model A( diameter 11.1 mm), D (diameter 4.0 mm) and J( diameter 0.7 mm) were recorded, and the detect factors (H_T) was also calculated. Images were sent to workstation before the end of DR examination. An automatic procedure was implemented to extract dose data and exposure parameters from the DICOM header file. Maximum, minimum and 3rd quartile values were preinstalled. Mean values exceeding the threshold trigger alarm signal to guide radiologist to explore the cause. Results: When the current of point A was less than 10 mAs and the current of point D and J were less than 16 mAs, the detect factor (H_T) increased with the rise of current. While point A located within ...

2009-12-01

385

Real time control of micro-machine system using micro-computer based fuzzy logic power system stabilizer  

Energy Technology Data Exchange (ETDEWEB)

A micro-computer based fuzzy logic power system stabilizer is applied to a micro-machine system to investigate its efficiency in real time control. The stabilizing signal is determined by using measured speed or real power signals at every sampling time to damp the system oscillations. The results show the proposed stabilizer improves the system damping effectively subject to various types of disturbances.

1994-12-01

386

Prostaglandin E2 Signals Through PTGER2 to Regulate Sclerostin Expression  

UK PubMed Central (United Kingdom)

The Wnt signaling pathway is a robust regulator of skeletal homeostasis. Gain-of-function mutations promote high bone mass, whereas loss of Lrp5 or Lrp6 co-receptors decrease bone mass. Similarly, mutations...Full Text Available

387

Method of controlling the coolant level in the cooling system of a nuclear power plant  

International Nuclear Information System (INIS)

Object: To prevent a sudden drop in the level of a coolant in a annular pipe encased within a downcomer pipe. Structure: The coolant levels in annular pipes encased within downcomer pipes are simultaneously measured by level gauges which generate signals representative of coolant levels. The signals are fed to a level control system which will actuate valves to regulate the cover gas pressure in order to average the level differences among the annular pipes in different downcomer pipes. (Kamimura, M.).

388

Long-range correlation analysis of earthquake-related geochemical variations recorded in Central Italy  

Energy Technology Data Exchange (ETDEWEB)

The long-range correlation properties in the hourly time variability of geochemical signals measured in a 70 m depth well at Triponzo (Umbria region), are investigated by the detrended fluctuation analysis (DFA). DFA is a data processing method that allows for the detection of scaling behaviors in observational time series even in the presence of non-stationarities. The procedure adopted has allowed for the unambiguous identification of possible correlations among the recorded signals and local earthquakes.

2004-07-01

389

Infrared-stimulated luminescence dating of sediments  

Energy Technology Data Exchange (ETDEWEB)

Luminescence stimulated from feldspars using wavelengths in the infrared region can be applied to the dating of sedimentary grains. Reported stimulation spectra are very similar for a wide range of feldspars, but their emission spectra show greater variation. For accurate dating it is critical that unstable infrared-stimulated luminescence (IRSL) signals are removed from the laboratory-irradiated grains. Several approaches to isolate a thermally stable signal are described. (author).

1994-04-01

390

Implementation and laboratory test results for a fuzzy logic based self-tuned power system stabilizer  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the implementations of a fuzzy logic based self-tuned controller to improve the stability of electric power systems. The stabilizing signal is computed using the standard fuzzy membership function depending on the speed/acceleration state of the generator in the phase plane. The performance of the proposed stabilizer is demonstrated by practical implementation using a digital signal processor mounted on a PC-AT. Results of the experimental tests on a physical model of a power system are presented.

1993-06-01

391

Gas-diesel dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

A gas-diesel dual fuel engine apparatus is described having a diesel engine, a diesel fuel supply system including a diesel fuel injection pump, a gaseous fuel supply system including a gaseous fuel regulating valve, and a governing and controlling device for governing the speed of the engine through the control of fuel supplied to the engine and controlling the switchover of the operation of the engine between a diesel fuel mode and a gaseous fuel mode. The improvement of the governing and controlling device consists of: (a) at least one electronic governor means adapted to compare a speed signal representing the actual operating speed of the diesel engine with a set speed signal representing the set speed thereof; (b) a pair of electric actuator means having respective power amplifier circuits and mechanically connected to the diesel fuel injection pump and the gaseous fuel regulating valve, respectively, for the actuation thereof; (c) mode ...

1986-03-18

392

Feasibility of FIR laser stabilization by injection of a synthesized signal  

Energy Technology Data Exchange (ETDEWEB)

In this paper the feasibility of phase locking a FIR laser by injection of a highly stable synthesized signal is examined. The theory of injection locking is revised in order to take into account the characteristic features of FIR lasers and turns out to be in satisfactory agreement with the experimental data reported. From the results obtained, it is inferred that the state of the art of submillimetric multipliers makes it possible to stabilize FIR laser emissions up to about 1 THz.

1980-12-01

393

Digital signal processing for beam position feedback  

Energy Technology Data Exchange (ETDEWEB)

Stabilization of the particle beam position with respect to the focusing optics in the third generation synchrotron light sources is crucial to achieving low emittance and high brightness. For this purpose, global and local beam orbit correction feedbacks will be implemented in the APS storage ring. In this article, the authors discuss application of digital signal processing to particle/photon beam position feedback using the PID (proportional, integral, and derivative) control algorithm.

1992-04-01

394

Differential regulation of the biosynthesis of glucose transporters by the PI3-K and MAPK pathways of insulin signaling by treatment with novel compounds from Liriope platyphylla.  

Science.gov (United States)

The insulin signaling pathway, involving protein kinase B (PKB) and mitogen-activated protein kinase (MAPK), mediates the biological response to insulin and several growth factors and cytokines. To investigate the correlation between glucose transporter (Glut) biosynthesis and the insulin signaling pathway activated by novel compounds of Liriope platyphylla (LP9M80-H), alterations in Glut and key protein expression in the insulin signaling pathway were analyzed in the liver and brain of ICR mice treated with LP9M80-H. An in vitro assay showed that the highest level of insulin concentration was observed in the LP9M80-H-treated group, followed by the LP-H, LP-M, LP-E, and LP9M80-C-treated groups. Therefore, LP9M80-H was selected for use in studying the detailed mechanism of the insulin signaling pathway in animal systems. In an in vivo experiment, LP9M80-H induced a significant increase in glucose levels ...

2010-12-14

395

Capacity analysis techniques for signalized intersections  

Energy Technology Data Exchange (ETDEWEB)

This book contains nomographs for analysis and design of signalized intersections and thoroughly explains how to use them. The nomographs simplify and reduce the work that otherwise would have to be done by hand. The nomograph method for computing capacity has a significant advantage over computerized methods: it provides insight into the interaction between the various factors in the solution process for design analysis.

1986-01-01

396

Amplified B Lymphocyte CD40 Signaling Drives Regulatory B10 Cell Expansion in Mice  

UK PubMed Central (United Kingdom)

BackgroundAberrant CD40 ligand (CD154) expression occurs on both T cells and B cells in human lupus patients, which is suggested to enhance B cell CD40 signaling and play a role...Full Text Available

397

(-)-Epigallocatechin Gallate Regulates CD3-mediated T Cell Receptor Signaling in Leukemia through the Inhibition of ZAP-70 Kinase*  

UK PubMed Central (United Kingdom)

The ζ chain-associated 70-kDa protein (ZAP-70) of tyrosine kinase plays a critical role in T cell receptor-mediated signal transduction and the immune response. A high level of ZAP-70 expression...Full Text Available

2008-10-17

398

Using support vector machines in the multivariate state estimation technique  

Energy Technology Data Exchange (ETDEWEB)

One approach to validate nuclear power plant (NPP) signals makes use of pattern recognition techniques. This approach often assumes that there is a set of signal prototypes that are continuously compared with the actual sensor signals. These signal prototypes are often computed based on empirical models with little or no knowledge about physical processes. A common problem of all data-based models is their limited ability to make predictions on the basis of available training data. Another problem is related to suboptimal training algorithms. Both of these potential shortcomings with conventional approaches to signal validation and sensor operability validation are successfully resolved by adopting a recently proposed learning paradigm called the support vector machine (SVM). The work presented here is a novel application of SVM for data-based modeling of system state variables in ...

1999-07-01

399

United States Geological Survey (USGS) FM cassette seismic-refraction recording system  

Energy Technology Data Exchange (ETDEWEB)

In this two chapter report, instrumentation used to collect seismic data is described. This data acquisition system has two parts: (1) portable anolog seismic recorders and related ``hand-held-testers`` (HHT) and (2) portable digitizing units. During the anolog recording process, ground motion is sensed by a 2-Hz vertical-component seismometer. The voltage output from the seismometer is split without amplification and sent to three parallel amplifier circuit boards. Each circuit board amplifiers the seismic signal in three stages and then frequency modulates the signal. Amplification at the last two stages can be set by the user. An internal precision clock signal is also frequency modulated. The three data carrier frequencies, the clock carrier frequency, and a tape-speed compensation carrier frequency are summed and recorded on a recorded on a cassette tape. During the digitizing process, the cassette tapes are played ...

1988-12-31

400

Unbiased cut selection for optimal upper limits in neutrino detectors the model rejection potential technique  

CERN Document Server

We present a method for optimising experimental cuts in order to place the strongest constraints (upper limits) on theoretical signal models. The method relies only on signal and background expectations derived from Monte-Carlo simulations, so no bias is introduced by looking at actual data, for instance by setting a limit based on expected signal above the ``last remaining data event.'' After discussing the concept of the ``average upper limit,'' based on the expectation from an ensemble of repeated experiments with no true signal, we show how the best model rejection potential is achieved by optimising the cuts to minimise the ratio of this ``average upper limit'' to the expected signal from the model. As an example, we use this technique to determine the limit sensitivity of kilometre scale neutrino detectors to extra-terrestrial neutrino fluxes from a variety of models, e.g. ...

2003-01-01

401

Ignition timing control apparatus for internal combustion engine  

Energy Technology Data Exchange (ETDEWEB)

An ignition timing control apparatus is described for an internal combustion engine having a reference ignition timing comprising: sensing means for sensing vibrations including knocks of the engine; knock signal deriving means for deriving knock signals from the output of the sensing means; correction magnitude determining means for determining from the knock signals derived by the knock signal deriving means of ignition timing correction magnitude for suppressing the occurrence of knock; displacement magnitude determining means for determining from at least one of an output of the knock signal deriving means and an output of the correction magnitude determining means as a displacement magnitude for the reference ignition timing corresponding to the octane rating of a fuel used in the engine; and ignition timing determining means for setting the reference ignition timing at an ...

1986-06-17

402

Higher order time-frequency analysis as a tool for health monitoring  

Energy Technology Data Exchange (ETDEWEB)

In machine condition monitoring many fault-related vibration signals are highly non-stationary. Time-frequency representations comprise the natural signal-processing tool traditionally used for representing such non-stationary signals. The methods used in this analysis are based on the second order statistics of a signal. This paper discusses the use of higher order time frequency methods in the context of a condition monitoring application. The paper outlines the two classes of higher order representations: the L-Wigner distribution and the sliced Wigner higher order distribution. The use of higher order distributions introduces the possibility of non-oscillating cross-terms, a problem not encountered in conventional bilinear time-frequency methods. Techniques for reducing these cross-terms are presented. The paper compares the performance of bilinear and higher order time-frequency methods using ...

2003-07-01

403

High field ESR of P-doped Si for Quantum Computing Application  

Energy Technology Data Exchange (ETDEWEB)

We measured ESR of phosphorous-doped silicon with a low concentration of P, n, at high magnetic fields and low temperatures to investigate the states of nuclear spin. A sample with n = 6.52 x 10{sup 16} /cm{sup 3} was studied at 2.85 T (80 GHz) from 30 K to 2.3 K by field-modulating cw-ESR for a fixed 0 dB power. As the temperature was lowered, the out-of-phase signal appeared around 18 K, reached at a maximum intensity at 13 K, and disappeared around 6 K. The out-of-phase signal is referred to the field modulation. The in-phase signal started to change from the derivative of absorption spectrum at high temperatures to absorption-like shape around 15 K and asymmetry of intensity for two peaks of hyperfine-separated signals increased as temperatures was lowered. Below 10 K, the saturation of the in-phase signal started to appear. We speculate that the asymmetry is caused by ...

2009-02-01

404

Global interrupt and barrier networks  

Energy Technology Data Exchange (ETDEWEB)

A system and method for generating global asynchronous signals in a computing structure. Particularly, a global interrupt and barrier network is implemented that implements logic for generating global interrupt and barrier signals for controlling global asynchronous operations performed by processing elements at selected processing nodes of a computing structure in accordance with a processing algorithm; and includes the physical interconnecting of the processing nodes for communicating the global interrupt and barrier signals to the elements via low-latency paths. The global asynchronous signals respectively initiate interrupt and barrier operations at the processing nodes at times selected for optimizing performance of the processing algorithms. In one embodiment, the global interrupt and barrier network is implemented in a scalable, massively parallel supercomputing device structure comprising a ...

2008-10-28

405

ESR dating of fault rocks  

Energy Technology Data Exchange (ETDEWEB)

Past movement on faults can be dated by measurement of the intensity of ESR signals in quartz. These signals are reset by local lattice deformation and local frictional heating on grain contacts at the time of fault movement. The ESR signals then grow back as a result of bombardment by ionizing radiation from surrounding rocks. The age is obtained from the ratio of the equivalent dose, needed to produce the observed signal, to the dose rate. Fine grains are more completely reset during faulting, and a plot of age vs. grain size shows a plateau for grains below critical size; these grains are presumed to have been completely zeroed by the last fault activity. We carried out ESR dating of fault rocks collected near the Gori nuclear reactor. Most of the ESR signals of fault rocks collected from the basement are saturated. This indicates that the last movement of the faults had occurred ...

2003-02-15

406

Coded Single-Tone Signaling for Resource Coordination and Interference Management in Femtocell Networks  

CERN Document Server

Resource coordination and interference management is the key to achieving the benefits of femtocell networks. Over-the-air signaling is one of the most effective means for distributed dynamic resource coordination and interference management. However, the design of this type of signal is challenging. In this letter, we address the challenges and propose an effective solution, referred to as coded single-tone signaling (STS). The proposed coded STS scheme possesses certain highly desirable properties, such as no dedicated resource requirement (no overhead), no near-and-far effect, no inter-signal interference (no multi-user interference), low peak-to-average power ratio (deep coverage). In addition, the proposed coded STS can fully exploit frequency diversity and provides a means for high quality wideband channel estimation. The coded STS design is demonstrated through a concrete numerical example. ...

2011-01-01

407

A wavelet approach to fault diagnosis of a gearbox under varying load conditions  

Science.gov (United States)

Varying load can cause changes in a measured gearbox vibration signal. However, conventional techniques for fault diagnosis are based on the assumption that changes in vibration signal are only caused by deterioration of the gearbox. There is a need to develop a technique to provide accurate state indicator of gearbox under fluctuating load conditions. This paper presents an approach to gear fault diagnosis based on complex Morlet continuous wavelet transform under this condition. Gear motion residual signal, which represents the departure of time synchronously averaged signal from the average tooth-meshing vibration, is analyzed as source data due to its lower sensitiveness to the alternating load condition. A fault growth parameter based on the amplitude of wavelet transform is proposed to evaluate gear fault advancement quantitatively. We found that this parameter is insensitive to varying load and ...

2010-04-01

408

A novel small-molecule inhibitor of NF-#kappa#B signaling  

International Nuclear Information System (INIS)

The inducible transcription factor NF-#kappa#B regulates divergent signaling pathways including inflammatory response and cancer development. Selective inhibitors for NF-#kappa#B signaling are potentially useful for treatment of inflammation and cancer. NF-#kappa#B is canonically activated by preferential disposal of its inhibitory protein; I#kappa#B, which suppresses the nuclear translocation of NF-#kappa#B. I#kappa#B#alpha# (a major member of I#kappa#B family proteins) is phosphorylated with an I#kappa#B kinase (IKK) and subsequently polyubiquitylated by SCF"#beta#"T"r"C"P"1 ubiquitin-ligase in the presence of E1 and E2 prior to proteasomal degradation. Here, we describe a novel inhibitor termed GS143, which suppressed I#kappa#B#alpha# ubiquitylation, but not I#kappa#B#alpha# phosphorylation, MDM2-directed p53 ubiquitylation, and proteasome activity in vitro. GS143 markedly suppressed the destruction of I#kappa#B#alpha# stimulated by ...

2008-04-18

409

Experimental study of lipiodol ultra-fluid. On its signal intensity in MR imaging  

Energy Technology Data Exchange (ETDEWEB)

Lipiodol Ultra-Fluid (Lipiodol) is widely applied in the transcatheter arterial embolization (TAE). We studied signal intensity, the T1 relaxation time and the T2 relaxation time of Lipiodol itself using Siemens Magnetom H15-2 T (1.5 Tesla) and Magnetom M10 (1.0 Tesla). Lipiodol showed higher signal intensity than saline solution on the T1-weighted images (short TR, short TE technique in spin echo method). On the T2-weighted images (long TR, long TE technique in spin echo method), Lipiodol showed lower signal intensity than saline solution. The T1 relaxation time of Lipiodol, measured at 1.0 T, was 201 msec and 218 msec at 1.5 T. The T2 relaxation time of Lipiodol, measured at 1.0 T, was 127 msec; and 167 msec at 1.5 T. The signal intensity of Lipiodol at 1.0 T was higher than the intensity at 1.5 T. Shorter T1 relaxation time of Lipiodol at 1.0 T is probably responsible for the higher intensity at 1.0 ...

1988-11-01

410

Equivalent dose estimation using a single aliquot of polymineral fine grains  

International Nuclear Information System (INIS)

We have tested the suitability of a new single-aliquot regenerative-dose protocol for estimating the equivalent dose (D_e) in polymineral fine grains extracted from colluvia from various sites in Germany. First, we report the behaviour of three OSL signals: (i) blue-stimulated, (ii) infrared-stimulated luminescence, and (iii) blue-stimulated luminescence following infrared (IR) stimulation, using a near-UV (290-380 nm) detection window in each case. For these three signals, there is a significant change in sensitivity with regeneration cycle; this change can be compensated for using the response to a fixed test dose after each natural or regenerated measurement. The source of the three luminescence signals is then investigated using pulse-anneal and elevated-temperature experiments. Fading tests on laboratory-induced signals show that although the IR signals fade by up to 23% in 15 ...

2001-02-01

411

Detection of multiple AE signal by triaxial hodogram analysis; Sanjiku hodogram ho ni yoru taju acoustic emission no kenshutsu  

Energy Technology Data Exchange (ETDEWEB)

In order to evaluate dynamic behavior of underground cracks, analysis and detection were attempted on multiple acoustic emission (AE) events. The multiple AE is a phenomenon in which multiple AE signals generated by underground cracks developed in an extremely short time interval are superimposed, and observed as one AE event. The multiple AE signal consists of two AE signals, whereas the second P-wave is supposed to have been inputted before the first S-wave is inputted. The first P-wave is inputted first, where linear three-dimensional particle movements are observed, but the movements are made random due to scattering and sensor characteristics. When the second P-wave is inputted, the linear particle movements are observed again, but are superimposed with the existing input signals and become multiple AE, which creates poor S/N ratio. The multiple AE detection determines it a multiple AE event when ...

1997-05-27

412

Vertical array receptions of the Heard Island transmissions  

Energy Technology Data Exchange (ETDEWEB)

The Heard Island Feasibility Test (HIFT) demonstrated that coded acoustic signals could be detected at ranges up to 18,000 km with currently available source technology. This paper describes one component of the HIFT where a large aperture vertical line array was deployed to record the signals transmitted from Heard Island. We have performed four analysis Of the VLA receptions, of the Heard Island signals. All four suggest the presence of higher order modes. The frequency- vertical wavenumber analysis and the modal beamforming indicate that mode 3 has the highest amplitude while the modal fitting suggests that made 5--6 are largest. It is difficult to resolve the differences since the SNR at the VLA, nearly 18,000 km with a transmission loss of around 145 dB, is quite low. Individual arrivals could not be distinguished because of the long integration time necessitated by the low SNR.

1993-03-23

413

Role of MRI in the diagnostic evaluation of parotid diseases  

International Nuclear Information System (INIS)

MRI findings in 13 patients with monolateral parotid tumor were compared with US, sialographic and CT findings. MRI did not allow an accurate diagnosis in 2 patients with diffuse chronic parotitis. MRI was superior to CT in 1 case in defining the intraglandular site of the lesion, and in 2 patients in showing the extraglandular involvement. MRI proved to be superior to CT thanks to its contrast resolution and to multiplanar imaging. MRI high contrast resolution made it possible to demonstrate neoplastic lesions of 4 mm in diameter. The lesion has low signal intensity on T1-weighted images and high signal intensity on T2-weighted. Parotid tumors cannot be characterized by signal intensity alone: only morphology allows to discriminate between benign and malignant lesions. To conclude, US is a screening method, while MRI is helpful in detecting multifocal lesions and in evaluating the tumor extent.

1988-01-01

414

Particle Swarm Optimization and gravitational wave data analysis: Performance on a binary inspiral testbed  

CERN Document Server

The detection and estimation of gravitational wave (GW) signals belonging to a parameterized family of waveforms requires, in general, the numerical maximization of a data-dependent function of the signal parameters. Due to noise in the data, the function to be maximized is often highly multi-modal with numerous local maxima. Searching for the global maximum then becomes computationally expensive, which in turn can limit the scientific scope of the search. Stochastic optimization is one possible approach to reducing computational costs in such applications. We report results from a first investigation of the Particle Swarm Optimization (PSO) method in this context. The method is applied to a testbed motivated by the problem of detection and estimation of a binary inspiral signal. Our results show that PSO works well in the presence of high multi-modality, making it a viable candidate method for further applications in GW ...

2010-01-01

415

Paroxysmal nocturnal hemoglobinuria: a case report of MR, CT findings  

Energy Technology Data Exchange (ETDEWEB)

Paroxysmal nocturnal hemoglobinuria (PNH) is a rare, acquired disease involving multiple hematopoietic cell lines. Characteristics of PNH are intrinsic hemolytic anemia, iron deficiency anemia and venous thrombosis. We report a case of PNH with characterostoc MR and CT findings. The signal intensity of renal cortex was lower than that of medulla on both T1-and T2-weighted MR imaging. On T2 weighted MR images, the liver showed very low signal intensity but the signal intensity of the spleen was normal. On precontrast CT the attenuation of renal cortex was higher than that of renal medulla and the attenuation of liver was higher than that of the spleen. These findings of MR imaging and CT were the result from the deposition of hemosiderin in the cells of proximal convoluted tubules and transfusional hemosiderosis of liver.

1995-10-15

416

Onset of nucleate boiling and onset of fully developed subcooled boiling using pressure transducers signals spectral analysis  

International Nuclear Information System (INIS)

The experimental technique used for detection of subcooled boiling through analysis of the fluctuation contained in pressure transducer signals is presented. This work was partly conducted at the Institut fuer Kerntechnik und zertoerungsfreie Pruefverfahren von Hannover (IKPH, Germany) in a thermal-hydraulic circuit with one electrically heated rod with annular geometry test section. Piezo resistive pressure sensors are used for onset of nucleate boiling (ONB) and onset of fully developed boiling (OFDB) detection using spectral analysis/ signal correlation techniques. Experimental results are interpreted by phenomenological analysis of these two points and compared with existing correlation. The results allow to conclude that this technique is adequate for the detection and monitoring of the ONB and OFDB. (author)

417

Onset of nucleate boiling and onset of fully developed subcooled boiling using pressure transducers signals spectral analysis  

Energy Technology Data Exchange (ETDEWEB)

The experimental technique used for detection of subcooled boiling through analysis of the fluctuation contained in pressure transducer signals is presented. This work was partly conducted at the Institut fuer Kerntechnik und zertoerungsfreie Pruefverfahren von Hannover (IKPH, Germany) in a thermal-hydraulic circuit with one electrically heated rod with annular geometry test section. Piezo resistive pressure sensors are used for onset of nucleate boiling (ONB) and onset of fully developed boiling (OFDB) detection using spectral analysis/ signal correlation techniques. Experimental results are interpreted by phenomenological analysis of these two points and compared with existing correlation. The results allow to conclude that this technique is adequate for the detection and monitoring of the ONB and OFDB. (author)

2001-12-01

418

Multiscale morphology analysis and its application to fault diagnosis  

Science.gov (United States)

A novel approach to fault diagnosis is proposed using multiscale morphology analysis to extract impulsive features from the signals with strong background noise. Multiscale morphology is applied to one-dimensional signal by defining both the length and height scales of structuring elements (SEs). A local-peak-value based adaptive algorithm is also introduced. The new approach makes the selection of SEs more transparent and is independent of empirical rules. Both simulated impulsive and vibration signals of two defective roller bearings are employed to validate the proposed algorithm. The roller bearing faults presented in the validation include both inner and outer race faults. The test results show that the multiscale morphology analysis is effective and robust to extract morphological features.

2008-04-01

419

Multifractal Fourier detrended cross-correlation analysis of traffic signals  

Science.gov (United States)

Multifractal detrended cross-correlation analysis (MF-DXA) has been developed to detect the long-range power-law cross-correlation of considered signals in the presence of non-stationarity. However, crossovers arising from extrinsic periodic trends make the scaling behavior difficult to analyze. We introduce a Fourier filtering method to eliminate the trend effects and systematically investigate the multifractal cross-correlation of simulated and real traffic signals. The crossover locations are found approximately corresponding to the periods of underlying trend. Traffic velocity on one road and flows on adjacent roads show strong cross-correlation. They also present weak multifractality after periodic trends are removed. The traffic velocity and flow are cross-correlated in opposite directions which is accordant to their actual evolution.

2011-10-01

420

Method and device for identifying different species of honeybees  

Energy Technology Data Exchange (ETDEWEB)

A method and device have been provided for distinguishing Africanized honeybees from European honeybees. The method is based on the discovery of a distinct difference in the acoustical signatures of these two species of honeybees in flight. The European honeybee signature has a fundamental power peak in the 210 to 240 Hz range while the Africanized honeybee signature has a fundamental power peak in the 260 to 290 Hz range. The acoustic signal produced by honeybees is analyzed by means of a detecting device to quickly determine the honeybee species through the detection of the presence of frequencies in one of these distinct ranges. The device includes a microphone for acoustical signal detection which feeds the detected signal into a frequency analyzer which is designed to detect the presence of either of the known fundamental wingbeat frequencies unique to the acoustical signatures of these species as an indication of the ...

1989-01-01

421

Ion beam induced charge imaging of epitaxial GaN detectors  

Energy Technology Data Exchange (ETDEWEB)

We report the use of ion beam induced charge imaging to characterise the charge signal uniformity of epitaxial gallium nitride radiation detectors. The detectors were fabricated from 2 {mu}m thick semi-insulating gallium nitride, grown by MOCVD on a sapphire substrate. A carrier concentration of 1.4x10{sup 15} cm{sup -3} was measured using capacitance-voltage measurements. Ion beam induced charge imaging was carried out with a 2 MeV alpha particle beam focussed to a 3 {mu}m diameter and raster scanned across the device. The resulting ion beam images show excellent charge signal uniformity in this material with no evidence of material defects or polycrystalline structure on the micrometer length scale. No evidence of charge signal trapping was observed in these devices.

2004-09-21

422

Hypoxia decreases sclerostin expression and increases Wnt signaling in osteoblasts  

British Library Electronic Table of Contents (United Kingdom)

Mutations in sclerostin function or expression cause sclerosing bone dysplasias, involving decreased antagonism of Wnt/Lrp5 signaling. Conversely, deletion of the VHL tumor suppressor in osteoblasts, which stabilize HIF-a isoforms and thereby enables HIF-a/b-driven gene transcription, increases bone mineral content and cross-sectional area compared to wild-type controls. We examined the influence of cellular hypoxia (1% oxygen) upon sclerostin expression and canonical Wnt signaling. Osteoblasts and osteocytes cultured under hypoxia revealed decreased sclerostin transcript and protein, and increased expression and nuclear localization of activated b-catenin. Similarly, both hypoxia and the hypoxia mimetic DFO increased b-catenin gene reporter activity. Hypoxia and its mimetics increased exp...

2010-01-01

423

High-vacuum time-resolved laser-induced incandescence of?flame-generated soot  

British Library Electronic Table of Contents (United Kingdom)

We have measured time-resolved laser-induced incandescence of flame-generated soot under high-vacuum conditions (4.1?10?6 mbar) at an excitation wavelength of 532 nm with laser fluences spanning 0.06?0.5 J/cm2. We generated soot in an ethylene/air diffusion flame, introduced it into the vacuum system with an aerodynamic lens, heated it using a pulsed laser with a spatially homogeneous and temporally smooth laser profile, and recorded LII temporal profiles at 685 nm. At low laser fluences LII signal decay rates are slow, and LII signals persist beyond the residence time of the soot particles in the detection region. At these fluences, the temporal maximum of the LII signal increases nearly linearly with increasing laser fluence until reaching a plateau at ?0.18?J/cm2. At higher fluences, th...

2011-01-01

424

Feedwater control device for a reactor  

International Nuclear Information System (INIS)

Purpose: To eliminate the water level deviation due to the recycling flowrate, as well as enable a stable control to a reference value even upon changes in the recycling flowrate caused by the variation in the opening degree of a minimum flow valve. Constitution: Reactor recycling system comprises a feedwater pump, a flowrate control valve, a reactor water level detector, and a minimum flow line and a minimum flow valve for preventing the overheating of the feedwater pump at a low flowrate. A flowrate compensator is further disposed, in which a recycling flowrate signal is subtracted from a pump flow rate signal and the result is fedback as a compensated pump flowrate signal. This enables the control system to operate at a rapid response for suppressing the effect of the recycling flowrate as external disturbance, whereby the water level in the reactor can be controlled stably to the reference level and the possibility ...

1981-11-18

425

Eddy currents signal processing for steam generator inspection in PWR nuclear power plants  

International Nuclear Information System (INIS)

Steam generator tubes in nuclear power plants are periodically checked by means of eddy current probes. The output of a probe is composed of three types of signals: known events (rolling zone, support plates, U-bend part), noise (mainly metallurgical noise) and possible flaws. The latter are random transients, both in arrival time and in shape: they have to be detected and then estimated, before to be fed to the high level stages of a diagnostic system. The objective of the study presented is to develop a semi-automatic system, which could manage and process more than 1 M-bytes of data per tube and provide an operator with reliable diagnostics proposals within a few minutes. This can be achieved only by cooperation of several digital signal processing techniques: detection, segmentation, estimation, noise subtraction, adaptive filtering, modelization, pattern recognition. The paper describes some of these items.

1992-01-01

426

Dynamic control rod worth measurement of Yonggwang Unit 1 cycle 14  

Energy Technology Data Exchange (ETDEWEB)

A dynamic control rod worth measurement was performed for control bank D, C, B, and A of Yonggwang unit 1 cycle 14 during its low power physics test. MASTER was used for three-dimensional core kinetics calculations required to convert excore detector signal into static rod worth, using the same modeling and cross sections as ANC which was used for the core static design. A signal curve fitting method was proposed to solve a low signal problem due to large amount of rod worth, which leads to the distortion of resulting static worth. The static worths measured in this test well agreed with the predicted worth of design within {+-}15% which is a test requirement of rod worth measurement.

2002-05-01

427

Dynamic control rod worth measurement of Yonggwang Unit 1 cycle 14  

International Nuclear Information System (INIS)

A dynamic control rod worth measurement was performed for control bank D, C, B, and A of Yonggwang unit 1 cycle 14 during its low power physics test. MASTER was used for three-dimensional core kinetics calculations required to convert excore detector signal into static rod worth, using the same modeling and cross sections as ANC which was used for the core static design. A signal curve fitting method was proposed to solve a low signal problem due to large amount of rod worth, which leads to the distortion of resulting static worth. The static worths measured in this test well agreed with the predicted worth of design within #+-#15% which is a test requirement of rod worth measurement.

2002-05-01

428

Discriminating between a Stochastic Gravitational Wave Background and Instrument Noise  

CERN Document Server

The detection of a stochastic background of gravitational waves could significantly impact our understanding of the physical processes that shaped the early Universe. The challenge lies in separating the cosmological signal from other stochastic processes such as instrument noise and astrophysical foregrounds. One approach is to build two or more detectors and cross correlate their output, thereby enhancing the common gravitational wave signal relative to the uncorrelated instrument noise. When only one detector is available, as will likely be the case with the Laser Interferometer Space Antenna (LISA), alternative analysis techniques must be developed. Here we show that models of the noise and signal transfer functions can be used to tease apart the gravitational and instrument noise contributions. We discuss the role of gravitational wave insensitive "null channels" formed from particular combinations of the time delay ...

2010-01-01

429

Acute femoral neck fracture  

International Nuclear Information System (INIS)

Ten patients with traumatic femoral neck fracture were studied with MR imaging (0.5 T, Magnetom, Siemens): unenhanced (multiecho, TR/TE = 1,600/30--240 [repetition time/echo time, msec]; gradient echo, TR/TE = 315/14, #theta# = 90 degrees) and Gd-DTPA enhanced (0.1 mM/kg body weight, Magnevist, Schering; gradient echo, TR/TE = 315/14, #theta# = 90 degrees). MR images were compared with clinical-radiographic findings. Digital subtraction angiography of the femoral head (FH) in five patients showed complete interruption of blood supply to the FH in three patients (signal intensity of FH did not increase on postcontrast images) and intact FH arteries in two patients (FH signal increased on postcontrast images, as did the healthy-side signal).

430

A novel wavelet transform aided neural network based transmission line fault analysis method  

Energy Technology Data Exchange (ETDEWEB)

In the present scenario of market driven business, power supply has become more like a commodity. Reliable and quality power need to be ensured to meet customer requirements. In such a situation, it is extremely important that transmission line faults be identified accurately, reliably and in quick time. Advanced signal processing tools such as discrete wavelet transform (DWT) can be used very effectively for parameterisation and characterization of the fault signals. On the other hand, properly configured neural network (NN) can be utilized for classification of the faults based on the DWT signal. The present contribution uses electromagnetic transient program (EMTP) for modeling of a real transmission system and MATLAB for DWT and NN. Various types of faults have been simulated at different locations along the transmission line and an attempt has been made to correctly identify and locate the fault. (author)

2009-06-15

431

A novel wavelet transform aided neural network based transmission line fault analysis method  

British Library Electronic Table of Contents (United Kingdom)

In the present scenario of market driven business, power supply has become more like a commodity. Reliable and quality power need to be ensured to meet customer requirements. In such a situation, it is extremely important that transmission line faults be identified accurately, reliably and in quick time. Advanced signal processing tools such as discrete wavelet transform (DWT) can be used very effectively for parameterisation and characterization of the fault signals. On the other hand, properly configured neural network (NN) can be utilized for classification of the faults based on the DWT signal. The present contribution uses electromagnetic transient program (EMTP) for modeling of a real transmission system and MATLAB for DWT and NN. Various types of faults have been simulated at differ...

2009-01-01

432

A large solid angle, high stopping power Bragg curve spectrometer for coincidence measurements  

Energy Technology Data Exchange (ETDEWEB)

A large acceptance, high stopping power, Bragg curve spectrometer has been developed for use in coincidence experiments with heavy ions. The electron collection fields are radial and position information is obtained from a resistive anode. The detector is 60 cm deep and operates at pressures of up to 2.5 atm of P-10 gas. It is mated to a scattering chamber which allows it to be moved out of plane during coincidence measurements. The detector design was aided by the results of computer simulations of the electron collection process in the detector, and of the signal processing in the electronics. The signals from the Bragg curve spectrometer are recorded in a waveform digitizer and the Bragg peak height, range, position and pileup rejection information are determined from software analysis of the recorded signals. Factors limiting the performance of the detector are discussed, and results obtained with the detector are ...

1991-09-01

433

A large solid angle, high stopping power Bragg curve spectrometer for coincidence measurements  

International Nuclear Information System (INIS)

A large acceptance, high stopping power, Bragg curve spectrometer has been developed for use in coincidence experiments with heavy ions. The electron collection fields are radial and position information is obtained from a resistive anode. The detector is 60 cm deep and operates at pressures of up to 2.5 atm of P-10 gas. It is mated to a scattering chamber which allows it to be moved out of plane during coincidence measurements. The detector design was aided by the results of computer simulations of the electron collection process in the detector, and of the signal processing in the electronics. The signals from the Bragg curve spectrometer are recorded in a waveform digitizer and the Bragg peak height, range, position and pileup rejection information are determined from software analysis of the recorded signals. Factors limiting the performance of the detector are discussed, and results obtained with the detector are ...

434

Tantalum capping on platinum thin heater for selective area heating  

Energy Technology Data Exchange (ETDEWEB)

The thermal radiation which generated from the patterned Ta/Pt/Ta thin heater achieved a high temperature up to 1010 {sup o}C under applied current of 2.4 A. In order to reduce an electromigration at high current of 2 A, a Ta capping layer was placed on the Pt layer instead of conventional capping layer, such as SiNx and CoWP. Under the thermal radiation at the applied current of 2 A in the Ta/Pt/Ta thin heater, the Ta capping layer enhanced the lifetime of the Pt thin heater up to 5 h. A stamping process for the crystallization of a-Si was performed for 40 samples using the Ta/Pt/Ta thin heater. For all samples, a-Si has been selectively crystallized and Raman peaks were located near 519 cm{sup -} {sup 1}. These results indicated that the thermal radiation of the Ta/Pt/Ta thin heater was maintained constantly due to the Ta capping.

2009-05-29

435

Structural properties of Cu(In,Ga)Se2 thin films prepared from chemically processed precursor layers  

International Nuclear Information System (INIS)

We have developed a chemical process for incorporating copper into indium gallium selenide layers with the goal of creating a precursor structure for the formation of copper indium gallium diselenide (CIGS) photovoltaic absorbers. Stylus profilometry, EDX, Raman spectroscopy, XRD and SIMS measurements show that when indium gallium selenide layers are immersed in a hot copper chloride solution, copper is incorporated as copper selenide with no increase in the thickness of the layers. Further measurements show that annealing this precursor structure in the presence of selenium results in the formation of CIGS and that the supply of selenium during the annealing process has a strong effect on the morphology and preferred orientation of these layers. When the supply of Se during annealing begins only once the substrate temperature reaches ? 400 deg. C , the resulting CIGS layers are smoother and have more pronounced preferred orientation than when Se is supplied ...

2009-02-02

436

Structural Characterization and Photoluminescent Properties of (La1-xSmx)2Ti2O7 Solid Solutions Synthesized by a Sol-Gel Route  

British Library Electronic Table of Contents (United Kingdom)

Abstract A series of compounds with the general formula (La1-xSmx)2Ti2O7 (0-- x --1.0) has been synthesized by a sol-gel method and characterized by XRD, Raman spectroscopy, and scanning electron microscopy (SEM). These compounds are structurally isomorphic to perovskite-type La2Ti2O7 until a substitution rate of x = 0.8. Above this substitution rate (x >-0.8), a biphasic mixture is obtained between the substituted perovskite layered phase and the pyrochlore Sm2Ti2O7 phase. The unusual phosphor (La1-xSmx)2Ti2O7 has been elaborated and its luminescent properties were investigated for low rates of substitution. The emission and excitation spectra were used to study the luminescent properties. The (La1.9Sm0.1)2Ti2O7 powders emit bright red-orange lightunder UV excitation. The emission propert...

2011-01-01

437

Strain dependence of Si-Ge interdiffusion in epitaxial Si/Si{sub 1-y}Ge{sub y}/Si heterostructures on relaxed Si{sub 1-x}Ge{sub x} substrates  

Science.gov (United States)

The strain dependence of Si-Ge interdiffusion in epitaxial Si/Si{sub 1-y}Ge{sub y}/Si heterostructures on relaxed Si{sub 1-x}Ge{sub x} substrates has been studied using secondary ion mass spectrometry, Raman spectroscopy, and simulations. At 800 and 880 deg. C, significantly enhanced Si-Ge interdiffusion is observed in Si/Si{sub 1-y}Ge{sub y}/Si heterostructures (y=0.56, 0.45, and 0.3) with Si{sub 1-y}Ge{sub y} layers under compressive strain of -1%, compared to those under no strain. In contrast, tensile strain of 1% in Si{sub 0.70}Ge{sub 0.30} layer has no observable effect on interdiffusion in Si/Si{sub 0.70}Ge{sub 0.30}/Si heterostructures. These results are relevant to the device and process design of high mobility dual channel and heterostructure-on-insulator metal oxide semiconductor field effect transistors.

2006-01-02

438

Stabilization of high-temperature antimony oxide with molybdenum incorporation. Structure of Mo-doped Sb/sub 2/O/sub 4/ by powder neutron diffraction and extended X-ray absorption fine structure spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

It has been discovered that the presence of MoO/sub 3/ lowers the ..cap alpha..-..beta.. transition in Sb/sub 2/O/sub 4/ from 935 to 850/sup 0/C with concurrent dissolution of Mo in the high-temperature (..beta..) form. The structure of Mo-doped ..beta..-Sb/sub 2/O/sub 4/ has been investigated by powder neutron diffraction, extended X-ray absorption fine structure (EXAFS) and Raman spectroscopies, and scanning-electron microscopy (SEM). Cell parameters: a = 12.0571 (12) A, b = 4.8335 (1) A, c = 5.3838 (6) A, ..beta.. = 105.579 (5)/sup 0/, monoclinic, space group C2/c, Z = 4. Combining the results of these techniques leads to the hypothesis that Mo is located interstitially within channels of electron density in the Sb/sub 2/O/sub 4/ structure with concurrent vacancy of two Sb/sup III/ atoms. There is no apparent oxygen deficiency in the resulting structure. 25 references, 6 figures, 3 tables.

1985-10-09

439

Spark plasma sintered tantalum carbide-carbon nanotube composite: Effect of pressure, carbon nanotube length and dispersion technique on microstructure and mechanical properties  

British Library Electronic Table of Contents (United Kingdom)

TaC-4wt.% CNT composites were synthesized using spark plasma sintering. Two kinds of CNTs, having long (10-20mm) and short (1-3mm) length, were dispersed by wet chemistry and spray drying techniques respectively. Spark plasma sintering was carried out at 1850^oC at pressures of 100, 255 and 363MPa. Addition of CNTs leads to an increase in the density of 100MPa sample from 89% to 95%. Short CNTs are more effective in increasing the density of the composites whereas long CNTs are more effective grain growth inhibitors. The longer CNTs are more effective in increasing the fracture toughness and an increase up to 60% was observed for 363MPa sample. Hardness and elastic modulus are found to increase by 22% and 18% respectively for 100MPa samples by addition of long CNTs. Raman spectroscopy, SEM...

2011-01-01

440

Sensitive detection of endocrine disrupters using ionic liquid - Single walled carbon nanotubes modified screen-printed based biosensors.  

Science.gov (United States)

Simple and low cost biosensor based on screen-printed electrode for sensitive detection of some alkylphenols was developed, by entrapment of HRP in a nanocomposite gel based on single-walled carbon nanotubes (SWCNTs) and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF(6)]) ionic liquid. Raman and FTIR spectroscopy, CV and EIS studies demonstrate the interaction between SWCNTs and ionic liquid. The nanocomposite gel, SWCNT-[BMIM][PF(6)] provides to the modified sensor a considerable enhanced electrocatalytic activity toward hydrogen peroxide reduction. The HRP based biosensor exhibits high sensitivity and good stability, allowing a detection of the alkylphenols at an applied potential of -0.2V vs. Ag/AgCl, in linear range from 5.5 to 97.7?M for 4-t-octylphenol and respectively, between 5.5 and 140?M for 4-n-nonylphenol, with a response time of about 5s. The detection limit was 1.1?M for 4-t-octylphenol, and respectively 0.4?M for 4-n-nonylphenol (S/N=3). ...

2011-07-19

441

Selective patterned growth of single-crystal organic nanowires of Ag-TCNQ with chemical raction method  

Energy Technology Data Exchange (ETDEWEB)

Abstract: We report for the selective-area chemical synthesis of semiconductor single-crystal organic nanowires of silver-tetracyanoquinodimethane (Ag-TCNQ). Straight and smooth Ag-TCNQ nanowires can be produced and patterned on micrometer and nanometer scale on silicon substrates covered with a thin layer of Ag film through the reaction of TCNQ and Ag in a simple gas-solid chemical reaction process. Ag-TCNQ nanowires are characterized by UV-vis, IR and Raman spectroscopy, respectively. The Ag-TCNQ nanowires grows preferentially along the [100] direction of strong - stacking of Ag-TCNQ molecules. Nanodevices based on these nanowires are fabricated using focus ion beam (FIB) technique. Electrical properties are characterized and I-V hysteresis is observed, which shows memory effect with electrical switching of three orders on-off ratio. These nanowires could be potential for use in optical storage, ultrahigh-density nanoscale memory and logic devices.

2008-09-01

442

Replacement of leucine-93 by alanine or threonine slows down the decay of the N and O intermediates in the photocycle of bacteriorhodopsin: Implications for proton uptake and 13-cis-retinal----all-trans-retinal reisomerization  

Energy Technology Data Exchange (ETDEWEB)

The authors report that the replacement of Leu-93 in bacteriorhodopsin by Ala (L93A) or Thr (L93T) slows down the photocycle by approximately 100-fold relative to wild-type bacteriorhodopsin. Time-resolved visible absorption spectroscopy and resonance Raman experiments, respectively, show the presence of long-lived O-like and N-like intermediates in the photocycles of the above mutants. We infer the existence of an equilibrium between the N and O intermediates in the photocycles of these mutants. The L93A and L93T mutants exhibit normal proton pumping under continuous illumination, suggesting that the decay of the N and/or O intermediate, and consequently, proton translocation, can be accelerated by the absorption of a second photon. Since the 13-cis----all-trans reisomerization of retinal is completed during the decay of the N and O intermediates, they conclude that the interaction of Leu-93 with retinal is important in this phase of the photocycle. This ...

1991-08-01

443

Nanoparticles and their tailoring with laser light  

Energy Technology Data Exchange (ETDEWEB)

Monodisperse noble metal nanoparticles are of tremendous interest for numerous applications, such as surface-enhanced Raman spectroscopy, catalysis or biosensing. However, preparation of monodisperse metal nanoparticles is still a challenging task, because typical preparation methods yield nanoparticle ensembles with broad shape and/or size distributions. To overcome this drawback, tailoring of metal nanoparticles with laser light has been developed, which is based on the pronounced shape- and size-dependent optical properties of metal nanoparticles. I will demonstrate that nanoparticle tailoring with ns-pulsed laser light is a suitable method to prepare nanoparticle ensembles with a narrow shape and/or size distribution. While irradiation with ns-pulsed laser light during nanoparticle growth permits a precise shape tailoring, post-grown irradiation allows a size tailoring. For example, the initial broad Gaussian size distribution of silver nanoparticles on quartz ...

2009-07-15

444

Investigations of biomimetic light energy harvesting pigments  

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Nature uses chlorophyll and other porphyrinic pigments to capture and transfer light energy as a preliminary step in photosynthesis. The design of synthetic assemblies of light harvesting and energy directing pigments has been explored through synthesis and characterization of porphyrin oligomers. In this project, pigment electronic and vibrational structures have been explored by electrochemistry and dynamic and static optical measurements. Transient absorption data reveal energy transfer between pigments with lifetimes on the order of 20--200 picoseconds, while Raman data reveal that the basic porphyrin core structure is unperturbed relative to the individual monomer units. These two findings, along with an extensive series of experiments on the oxidized oligomers, reveal that coupling between the pigments is ...

1998-12-01

445

Influence of residual K{sup +} on the catalytic performance of CuO-CeO{sub 2} catalysts in preferential oxidation of CO in excess hydrogen  

Energy Technology Data Exchange (ETDEWEB)

Influence of residual K{sup +} on the preferential oxidation of CO in excess hydrogen (PROX) over CuO-CeO{sub 2} catalysts was investigated. CuO-CeO{sub 2} catalysts were characterized by BET, ICP, XRD, UV-Raman and TPR techniques. The results showed that the existence of residual K{sup +} made {alpha} peak in TPR of CuO-CeO{sub 2} catalysts shift to higher temperatures and depressed the PROX in the absence of CO{sub 2} and H{sub 2}O in the feed over CuO-CeO{sub 2} catalysts. However, small amount of residual K{sup +} was beneficial to the catalytic performance of CuO-CeO{sub 2} catalysts in the PROX in the presence of CO{sub 2} and H{sub 2}O in the feed. Consequently, residual K{sup +} with an appropriate content was beneficial to improve the catalytic performance of CuO-CeO{sub 2} catalysts in the presence of CO{sub 2} and H{sub 2}O. (author)

2008-01-15

446

Grain boundary transport in x-ray irradiated polycrystalline diamond  

International Nuclear Information System (INIS)

The transport properties of a 'thin' polycrystalline diamond film are analyzed after the sample exposure to 8.06-keV x-ray radiation. Structure and morphology of the as-grown film have been evaluated by Raman, x-ray diffraction, and scanning electron microscopy techniques. The transport properties have been investigated by measuring dark current-voltage characteristics in the temperature range of 60 to 360 K. Ohmic transport has been evidenced on the as-grown film up to 1.16x10"5 V/cm. After irradiation, nonlinear contributions to the dark current have been evidenced and related to field-assisted thermal ionization of traps. Below 200 K, hopping mechanisms have been observed. Correlations have been found among x-ray irradiation, density of traps involved in the transport processes, and the nonhomogeneous nature of the sample. A simple model of the grain boundary structure is proposed to explain the observations.

2003-05-15

447

Energy-filtered electron microscopy for imaging core-shell nanostructures  

Energy Technology Data Exchange (ETDEWEB)

CuAg core-shell nanoparticles are synthesized by ultra-high vacuum thermal evaporation. We show on this system how the Energy-Filtered Transmission Electron Microscopy (EFTEM) technique allows one to improve the characterization by precisely pointing out the formation of core-shell arrangements in bimetallic nanoparticle assemblies. A criterion to measure the shell thickness from EFTEM images on unique core-shell nanoparticles is defined, that can be used for core-shell nanoparticles of any sizes, with shell thicknesses over 1 nm. It is based on the intensity variation along a line drawn across a core-shell nanoparticle on a EFTEM image. This criterion has been validated by a close comparison of the shell thickness measurements performed in this work and the ones obtained by acoustic micro-Raman spectroscopy. Using this criterion, we report a strong correlation between the size of the Cu cores and the formation of the core-shell arrangements in the nanoparticle ...

2008-08-15

448

Ellipsometry studies on nitrogenated diamond-like carbon (DLC) thin films produced by RF magnetron sputtering  

International Nuclear Information System (INIS)

Nitrogen doped Diamond-like carbon thin films were deposited on n-Si and SiO_2 substrates by rf magnetron sputtering using pure graphite (99.999%) as the target material and mixtures of Ar, N_2 and H_2 for plasma generation. The dependence of structural and optical properties on nitrogen content was investigated using XPS, Raman spectroscopy, FT-IR spectroscopy, and Ellipsometry studies. It was found that as the nitrogen content was increased in the plasma, sp"2 bonding favored. Also it was observed that oxygen contamination increased with nitrogen content. Typical C-H stretching modes connected with diamond-like carbon could be seen in FT-IR spectra. The I_D and I_G bands were well defined and it was observed that as nitrogen content increased I_G band was enhanced. Ellipsometry studies revealed that the optical constants like refractive index (n) and extinction co-efficient (k) increased with increase in nitrogen content as well as substrate temperature. (author)

2003-03-01

449

Effect of substrate temperature on structural properties and corrosion resistance of carbon thin films used as bipolar plates in polymer electrolyte membrane fuel cells  

International Nuclear Information System (INIS)

In this work, the effects of substrate temperature that was changed from 100 to 500 "oC on the structural, chemical and electrical properties of carbon films, prepared by direct current magnetron sputtering technique, on 316L stainless steel as bipolar plate had been investigated. Raman spectroscopy and scanning electron microscopy (SEM) were performed to study the structure and the morphology of the deposited films, respectively. The corrosion resistance and the electrical resistivity were carried out by using corrosion tests and four point-probe technique. The results show that the carbon films change the structure from amorphous to graphite-like by increasing temperatures. At the temperatures higher than 300 "oC, the holes and porosities are formed on the film indicating a decrease of film quality. According to our results, corrosion resistance and electrical properties are depended strongly on the substrate temperature.

2010-07-23

450

Effect of burn-off on physical and chemical properties of coal char; Gas ka shinko ni tomonau sekitan char no tokusei henka  

Energy Technology Data Exchange (ETDEWEB)

For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is oxidized preferentially, and a portion with low reactivity remains finally. Minerals in coal are known to accelerate the gasification. However, their catalytic effect is ...

1996-10-28

451

Composition Dependence of the Photocatalytic Activities of BiOCl1-xBrx Solid Solutions under Visible Light  

British Library Electronic Table of Contents (United Kingdom)

Abstract We prepared BiOCl1-xBrx (x=0-1) solid solutions and characterized their structures, morphologies, and photocatalytic properties by X-ray diffraction, diffuse reflectance spectroscopy, scanning electron microscopy, Raman spectroscopy, photocurrent and photocatalytic activity measurements and also by density functional theory calculations for BiOCl, BiOBr, BiOCl0.5Br0.5. Under visible-light irradiation BiOCl1-xBrx exhibits a stronger photocatalytic activity than do BiOCl and BiOBr, with the activity reaching the maximum at x=0.5 and decreasing gradually as x is increased toward 1 or decreased toward 0. This trend is closely mimicked by the photogenerated current of BiOCl1-xBrx, indicating that the enhanced photocatalytic activity of BiOCl1-xBrx with respect to those of BiOCl and BiO...

2011-01-01

452

Cobalt, titanium or cerium oxide protective coatings for the nickel cathode of the molten carbonate fuel cells; Revetements protecteurs a base d'oxyde de cobalt, de titane ou de cerium pour la cathode de nickel des piles a combustible a carbonates fondus  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to combine the MCFC cathode Li{sub x}Ni{sub 1-x}O properties to those of the protective coatings of LiCoO{sub 2}, Li{sub 2}TiO{sub 3} or of CeO{sub 2}, less soluble in the molten carbonates. In the cases of LiCoO{sub 2}, have been carried out by controlled potential coulometry in aqueous solution, a deposition of Co{sub 3}O{sub 4} on dense Ni. The cobalt oxide reacts rapidly in the Li{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3} medium at 650 C to give LiCoO{sub 2}, a spinel cubic phase revealed by Raman spectroscopy. (O.M.)

2003-10-15

453

Characterisation of passive films on 300 series stainless steels  

Energy Technology Data Exchange (ETDEWEB)

The formation and breakdown of the passive films on stainless steels are mainly controlled by ionic and electronic transport processes. Both these processes are in part controlled by the electronic properties of the oxide film. Consequently, it is vital to gain a detailed perception of the electronic properties of the passive films together with structural and compositional information for a comprehensive understanding of mechanisms behind passivity and localised corrosion. As a step towards this goal the passive films formed on two main austenitic stainless steels AISI 316L and AISI 304L in borate solution were characterised by in situ Raman spectroscopy and photocurrent spectroscopy coupled with electrochemical measurements. This revealed the formation of an Fe-Cr spinel as the dominant constituent in the passive films with more Cr enrichment in the oxide film on 316L than that of 304L. Bandgap readings and semiconductivities of the two stainless steels suggested ...

2006-11-15

454

Characterisation of passive films on 300 series stainless steels  

International Nuclear Information System (INIS)

The formation and breakdown of the passive films on stainless steels are mainly controlled by ionic and electronic transport processes. Both these processes are in part controlled by the electronic properties of the oxide film. Consequently, it is vital to gain a detailed perception of the electronic properties of the passive films together with structural and compositional information for a comprehensive understanding of mechanisms behind passivity and localised corrosion. As a step towards this goal the passive films formed on two main austenitic stainless steels AISI 316L and AISI 304L in borate solution were characterised by in situ Raman spectroscopy and photocurrent spectroscopy coupled with electrochemical measurements. This revealed the formation of an Fe-Cr spinel as the dominant constituent in the passive films with more Cr enrichment in the oxide film on 316L than that of 304L. Bandgap readings and semiconductivities of the two stainless steels suggested ...

2006-11-15

455

Application of titanium containing amorphous hydrogenated carbon films (a-C:H/Ti) as optical selective solar absorber coatings  

Energy Technology Data Exchange (ETDEWEB)

A combined PVD/PECVD process for the vacuum deposition of titanium containing amorphous hydrogenated carbon films is described. Elemental compositions of the deposited films have been determined by in situ core level photoelectron spectroscopy (XPS). The long-term stability of the plasma process has been demonstrated. Target poisoning has not been observed. We have fabricated optical selective surfaces by the deposition of a-C:H/Ti multilayers onto aluminum substrates. Even though we have not optimized layer thicknesses and stoichiometries so far, the experimental results are promising: solar absorptance {alpha}{sub S} of 0.876 and thermal emittance {epsilon}{sub 100C} of 0.061 have been achieved yielding an optical selectivity sis defined as{alpha}{sub S}/{epsilon}{sub 100C} of 14.4. Accelerated aging tests of these coatings have demonstrated their aging stability: the service lifetime is predicted to amount to more than 25 years. Raman spectroscopy has been used ...

2000-01-31

456

Application of spectroscopic techniques for the study of paper documents: A survey  

International Nuclear Information System (INIS)

For many centuries paper was the main material for recording cultural achievements all over the world. Paper is mostly made from cellulose with small amounts of organic and inorganic additives, which allow its identification and characterization and may also contribute to its degradation. Prior to 1850, paper was made entirely from rags, using hemp, flax and cotton fibres. After this period, due to the enormous increase in demand, wood pulp began to be commonly used as raw material, resulting in rapid degradation of paper. Spectroscopic techniques represent one of the most powerful tools to investigate the constituents of paper documents in order to establish its identification and its state of degradation. This review describes the application of selected spectroscopic techniques used for paper characterization and conservation. The spectroscopic techniques that have been used and will be reviewed include: Fourier-Transform Infrared spectroscopy, Raman ...

2009-06-01

457

Advanced organic analysis and analytical methods development: FY 1995 progress report. Waste Tank Organic Safety Program  

Energy Technology Data Exchange (ETDEWEB)

This report describes the work performed during FY 1995 by Pacific Northwest Laboratory in developing and optimizing analysis techniques for identifying organics present in Hanford waste tanks. The main focus was to provide a means for rapidly obtaining the most useful information concerning the organics present in tank waste, with minimal sample handling and with minimal waste generation. One major focus has been to optimize analytical methods for organic speciation. Select methods, such as atmospheric pressure chemical ionization mass spectrometry and matrix-assisted laser desorption/ionization mass spectrometry, were developed to increase the speciation capabilities, while minimizing sample handling. A capillary electrophoresis method was developed to improve separation capabilities while minimizing additional waste generation. In addition, considerable emphasis has been placed on developing a rapid screening tool, based on Raman and infrared spectroscopy, for ...

1995-09-01

458

Accelerated aging tests of chromium containing amorphous hydrogenated carbon coatings for solar collectors  

Energy Technology Data Exchange (ETDEWEB)

Chromium containing amorphous hydrogenated carbon films (a-C : H/Cr) have been prepared by simultaneous rf plasma activated chemical vapour deposition of methane and magnetron sputtering of a chromium target. During deposition the substrates were heated (up to 300C) and DC biased (-200 and -600 V) in order to obtain films with high chemical stability. Constant temperature tests were performed at 250C in air with coatings deposited on silicon substrates. The degradation of the coatings was monitored by Raman spectroscopy and reflectance and transmission measurements. The main degradation mechanisms are discussed and the relevant parameters which improve the durability of the coatings are presented. Furthermore, the durability of solar selective, multilayered coatings which were deposited on copper sheets was investigated. Based on accelerated aging tests at different temperature loads in air (at 220C, 250C and 300C) and in a humid environment (80C sample temperature ...

1998-07-13

459

3-dimensional observations of atmospheric variables during the field campaign COPS  

Energy Technology Data Exchange (ETDEWEB)

The Convective and Orographically-induced Precipitation Study (COPS) has the aim to advance the quality of forecasts of orographically-induced precipitation in complex terrain. COPS is a Research and Development Project of the World Weather Research Program and considered to be one of the largest field campaigns on quantitative precipitation forecasting that has been performed so far. A network of state-of-the-art active and passive remote sensing systems was combined with in total 10 airborne platforms, Meteosat rapid scans and dense networks of standard meteorological instruments during the three months long field phase (June-August, 2007) in south-western Germany/eastern France to observe atmospheric variables in the three spatial dimensions and in time. By the University of Hohenheim, two novel ground-based mobile scanning lidar systems were deployed: a scanning rotational Raman lidar which provides combined measurements of the field of atmospheric temperature ...

2008-05-01

460

Yellow-emitting AlGaInP double heterostructure laser diode at 77 K grown by atmospheric metalorganic chemical vapor deposition  

Energy Technology Data Exchange (ETDEWEB)

Yellow-emitting pulsed laser operation of an Al/sub 0.37/Ga/sub 0.15/In/sub 0.48/P/Al/sub 0.16/Ga/sub 0.36/In/sub 0.48/P/ Al/sub 0.37/Ga/sub 0.15/In/sub 0.48/P double heterostructure laser diode was obtained at 77 K. The emission wavelength was 579 nm. The threshold current density was 5.6 kA/cm/sup 2/ for a diode with a Si/sub 3/N/sub 4/ insulated 8-..mu..m-wide and 250-..mu..m-long stripe geometry. The device was made from a DH wafer grown by conventional metalorganic chemical vapor deposition using triethyl metals and phosphine as source materials.

1984-11-01

461

Water uptake and exchange kinetics of polyelectrolyte films: a neutron reflectometry study  

Energy Technology Data Exchange (ETDEWEB)

The sequential layer-by-layer adsorption of polyanions and polycations to build polyelectrolyte multilayers has triggered enormous interest in their potential uses in a wide range of fields, from photonic to pharmaceutical applications. We show that the conformation of the solvent swollen films - prior to drying - is determined by the initial adsorption conditions, but can be altered ex-situ by exposure to a liquid phase of very high ionic strength. Recently it has been observed that the swelling depends on the charge of the outermost layer. In the PAH/PSS system we saw that assemblies with PSS as the outermost layer swell more than those with PAH outside. A neutron reflectivity study of this effect in addition indicated the existence of two kinds of water, bound with different strength within the films. Beside an unexpected two-step kinetics of swelling, the reflectivity curves of the layers against vacuum before and after re-hydration in D{sub 2}O vapor did not ...

2007-07-01

462

Void fraction estimation within rod bundles based on three-fluid model and comparison with X-ray CT void data  

Energy Technology Data Exchange (ETDEWEB)

An interfacial shear stress equation in the dispersed-annular two-phase flow regime has been developed, which is based on a three-fluid model consisting of a liquid film on a rod, vapor and entrained liquid associated with a vapor flow. It is an extension of J.G.M. Andersen's procedure that provides a two-fluid interfacial shear stress equation using the drift flux parameters C{sub 0} and V{sub gj}. This interfacial shear stress equation can take into account a phase and velocity distribution through an equivalence between the drift flux parameters and the interfacial shear stress. Using the three-fluid subchannel analysis code TEMPO with the three-fluid interfacial shear stress model the capability of a three-fluid calculation using the drift flux parameters C{sub 0} and V{sub gj} that reproduce a measured void fraction is demonstrated. A comparison was made with advanced X-ray computed tomography (CT) void fraction data within a 4x4 ...

1990-06-01

463

Transmission electron microscope characterization of AlGaInP grown by organometallic vapor phase epitaxy  

Energy Technology Data Exchange (ETDEWEB)

AlGaInP epitaxial layers grown at 690 {degree}C by atmospheric pressure organometallic vapor phase epitaxy are investigated by transmission electron microscopy. For the first time, compositionally modulated and ordered structures are simultaneously observed in AlGaInP alloys. The ordering is of the CuPt type with ordering along the {l brace}111{r brace} directions. The ordered regions appear as plate-like microdomains, while the composition modulation takes the form of a fine columnar constrast oriented along the growth direction. In addition, from the results of (001) plan-view diffraction contrast examination, the principal strain direction associated with the modulation structures is found to be perpendicular to the growth direction and lies in the surface plane. Thus, it is concluded that the spinodal decomposition is initiated and developed on the surface during the growth of the AlGaInP epitaxial layers and, finally, forms the columnar structure.

1990-04-09

464

Transmission electron microscope characterization of AlGaInP grown by organometallic vapor phase epitaxy  

International Nuclear Information System (INIS)

AlGaInP epitaxial layers grown at 690 degree C by atmospheric pressure organometallic vapor phase epitaxy are investigated by transmission electron microscopy. For the first time, compositionally modulated and ordered structures are simultaneously observed in AlGaInP alloys. The ordering is of the CuPt type with ordering along the #left brace#111#right brace# directions. The ordered regions appear as plate-like microdomains, while the composition modulation takes the form of a fine columnar constrast oriented along the growth direction. In addition, from the results of (001) plan-view diffraction contrast examination, the principal strain direction associated with the modulation structures is found to be perpendicular to the growth direction and lies in the surface plane. Thus, it is concluded that the spinodal decomposition is initiated and developed on the surface during the growth of the AlGaInP epitaxial layers and, finally, forms the columnar structure.

465

Thin TiO2 grown by metal?organic chemical vapor deposition on (NH4)2S x -treated InP  

British Library Electronic Table of Contents (United Kingdom)

The electrical characteristics of thin TiO2 films prepared by metal?organic chemical vapor deposition grown on a p-type InP substrate were studied. For a TiO2 film of 4.7?nm on InP without and with ammonium sulfide treatment, the leakage currents are 8.8?10?2 and 1.1?10?4?A/cm2 at +2 V bias and 1.6?10?1 and 8.3?10?4?A/cm2 at ?2?V bias. The lower leakage currents of TiO2 with ammonium sulfide treatment arise from the improvement of interface quality. The dielectric constant and effective oxide charge number density are 33 and 2.5?1013?cm2, respectively. The lowest mid-gap interface state density is around 7.6?1011?cm?2?eV?1. The equivalent oxide thickness is 0.52?nm. The breakdown electric field increases with decreasing thickness in the range of 2.5 to 7.6?nm and reaches 9.3?MV/cm at 2.5?n...

2011-01-01

466

Solidification of radioactive waste effluents  

Energy Technology Data Exchange (ETDEWEB)

A process and apparatus for solidifying radioactive waste liquid containing dissolved and/or suspended solids is disclosed. The process includes chemically treating for pH adjustement and precipitation of solids, concentrating solids with a thin-film evaporator to provide liquid concentrate containing about 50% solids, and drying the concentrate with heated mixing apparatus. The heated mixing apparatus includes a heated wall and working means for shearing dried concentrate from internal surfaces and subdividing dry concentrate into dry, powdery particles. The working means includes a rotor and helical means for positively advancing the concentrate and resulting dry particles from inlet to outlet of the mixing apparatus. The dry particles may also be encapsulated in a matrix material. Entrained particles in the vapor stream from the evaporator and mixer are removed in an integral particle separator and the vapor is subsequently condensed and may ...

1983-10-11

467

Separation of the components of the binary mixture ethanol-water by steam flux in solid phase column; Separacao dos componentes da mistura binaria etanol-agua por passagem do vapor em coluna de fase solida  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

1987-12-31

468

Room-temperature cw operation of InGaP/InGaAlP visible light laser diodes on GaAs substrates grown by metalorganic chemical vapor deposition  

Energy Technology Data Exchange (ETDEWEB)

Room-temperature cw operation for InGaP/InGaAlP double heterostructure (DH) laser diodes on GaAs substrates was achieved for the first time. The DH wafers were grown by low-pressure metalorganic chemical vapor deposition using methyl metalorganics. A lasing wavelength of 679 nm and a threshold current of 109 mA at 24C were obtained for an inner stripe structure laser diode with a 250- m-long and 7- m stripe geometry. The laser operated at up to 51C. The characteristic temperature T0 was 87 K at around room temperature. The lowest threshold current density, 5.0 kA/cmS, was obtained with a 20- m stripe width laser diode under room-temperature pulsed operation.

1986-01-20

469

Room-temperature continuous-wave operation of an AlGaInP double heterostructure laser grown by atmospheric pressure metalorganic chemical vapor deposition  

Energy Technology Data Exchange (ETDEWEB)

Continuous-wave (cw) operation at temperatures up to 23 /sup 0/C of an Al/sub 0.26/Ga/sub 0.26/In/sub 0.48/P/Ga/sub 0.52/In/sub 0.48/P/ Al/sub 0.26/Ga/sub 0.26/In/sub 0.48/P double heterostructure (DH) laser has been achieved for the first time. The threshold current was 160 mA at 20 /sup 0/C for a device with a 10-..mu..m-wide and 250-..mu..m-long ion-implanted stripe geometry. The emission wavelength was 671 nm during cw operation at 10 /sup 0/C. To reduce thermal resistance to a heat sink, a dually stacked structure made of a thin (approx.0.3 ..mu..m) p-AlGaInP layer and a p-Al/sub 0.76/Ga/sub 0.24/As layer was used as a cladding layer. The DH wafer was grown by atmospheric pressure metalorganic chemical vapor deposition.

1985-11-15

470

Reduction of exhaust pollutants from a direct-injection diesel engine using oxygenated fuels. Fumigation of oxygenates and addition of oxygenated additives to fuel; Gansanso nenryo ni yoru chokusetsu funshashiki diesel kikan no haiki joka. Gansanso nenryo no kyukikan eno hojo funsha to keiyu eno tenka  

Energy Technology Data Exchange (ETDEWEB)

The effects on engine emissions resulting from the intake manifold fumigation of oxygenated fuel and the addition of oxygenates to the fuel have been investigated using a direct-injection diesel engine. The results show that carefully selected oxygenated fuels effectively work to increase the ignition delay because of their low ignition quality and to decrease the combustion temperature due to the low compression gas temperature produced from their large heat of vaporization, thereby reducing levels of Bosch smoke and nitrogen oxides simultaneously. However, supplementary injection of the oxygenates into the intake air causes a drastic increase in the levels of exhaust total hydrocarbons and CO; thus, it can be said that the addition of oxygenates to the fuel is more practical and effective than fumigation if phase separation of the blended fuel may not be occurred. In the case of addition of the oxygenates to the fuel, it is clarified that smoke is directly ...

1997-03-25

471

Recent Progress in the Growth of Mid-Infrared Emitters by Metal-Organic Chemical Vapor Deposition  

Science.gov (United States)

We report on recent progress and improvements in the metal-organic chemical vapor deposition (MOCVD) growth of mid-infrared lasers and using a high speed rotating disk reactor (RDR). The devices contain AlAsSb active regions. These lasers have multi-stage, type I InAsSb/InAsP quantum well active regions. A semi-metal GaAsSb/InAs layer acts as an internal electron source for the multi-stage injection lasers and AlAsSb is an electron confinement layer. These structures are the first MOCVD multi-stage devices. Growth in an RDR was necessary to avoid the previously observed Al memory effects found in conventional horizontal reactors. A single stage, optically pumped laser yielded improved power (greater than 650 mW/facet) at 80K and 3.8um. A multi-stage 3.8-3.9um laser structure operated up to T=170K. At 80K, peak power greater than 100mW and a high slope- efficiency were observed in gain guided lasers.

1998-01-01

472

Photoluminescence linewidths in metalorganic vapor phase epitaxially grown ordered and disordered InAlGaP alloys  

International Nuclear Information System (INIS)

The dependence of the photoluminescent properties of In_0_._4_8(Al_yGa_1_-_y)_0_._5_2P alloys (0#<=#y#<=#0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ''ordered'' domains and the ''disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a significant optimization of the optical properties of these materials, including the ...

473

Optimization of water injection into vapor-dominated geothermal reservoirs  

Energy Technology Data Exchange (ETDEWEB)

Water injection into a vapor-dominated geothermal reservoir is an effective method of sustaining steam production from the field. Injection puts additional water to the reservoir and raises the prevailing reservoir pressure. This process improves the field`s productivity. However, the increased pressure also increases the water retention capacity of the reservoir rocks through the effects of adsorption and capillary condensation. Due to the significant costs associated with water injection programs, optimizing injection not only involves maximizing the energy yield from the resource but also the present worth of the project. Two crucial parameters that need to be established are: (1) how much to inject; and, (2) when to inject it. This study investigated the optimal design of these parameters. It was found that comparable energy yield can be attained for injection programs that are initiated at various stages of the field`s development. Higher injection rates are ...

1996-12-31

474

OXYGEN-ENRICHED COAL COMBUSTION WITH CARBON DIOXIDE RECYCLE AND RECOVERY: SIMULATION AND EXPERIMENTAL STUDY  

Energy Technology Data Exchange (ETDEWEB)

Two computational problems were worked on for this study. The first chapter examines the option of coal combustion using oxygen feed with carbon dioxide recycle to control the adiabatic flame temperature. Computer simulations using an existing state-of-the-art 3-dimensional computer code for turbulent reacting flows with reacting particles were employed to study the effects of increased carbon dioxide mole fraction on the char burnout, radiant heat transfer, metal partitioning, and NOx formation. The second chapter compares assumptions for the CO/CO{sub 2} ratio at the surface of mineral inclusions made in previous studies to predictions obtained from a pseudo-steady state kinetic model (SKIPPY) for a single porous particle. The detailed kinetic simulations from SKIPPY for varying particle sizes and bulk gas compositions were used to develop algebraic expressions for the CO/CO{sub 2} ratio that can be incorporated into metal vaporization sub-models run as a post ...

2002-02-28

475

Modeling of thermal and hydrodynamic aspects of molten jet/water interactions  

Energy Technology Data Exchange (ETDEWEB)

In order to predict the effect of a fuel-coolant interaction after a hypothetical core-melt-down accident, a phenomenological model has been developed to describe the thermal and hydrodynamic behavior of a high-temperature molten jet when it interacts with saturated or subcooled water in a film boiling regime. The mechanisms of jet-material erosion were analyzed by Kelvin-Helmholtz instabilities on the coherent column and by boundary layer stripping on the leading edge. The heat transfer coefficient, vapor-film thickness, and net steam generation, all of which strongly affect the jet-breakup behavior, were solved analytically. It was found that the jet breakup (or erosion) depends strongly on the steam generation from the jet/water interaction. The jet-breakup length (i.e., penetration distance) was found to be sensitive to the initial jet temperature, water subcooling, and the physical state of the ambient water. The jet-breakup length and leading-edge velocity of ...

1989-01-01

476

Magnetic field amplification and generation in hypervelocity meteoroid impacts with application to lunar paleomagnetism  

International Nuclear Information System (INIS)

A one-dimensional numerical model for the expansion of impact-produced vapor clouds is used to investigate magnetic field generation mechanisms in events such as meteor collisions with the moon. The resulting cloud properties, such as ionization fraction, electrical conductivity, radial expansion velocity, mass density, and energy density are estimated. The model is initiated with the peak shock states and pressure thresholds for incipient and complete vaporization of anorthosite lunar surface materials by iron and GA composition meteorites. The expansion of the spherical gas cloud into a vacuum was traced with a one-dimensional explicit lagrangian hydrodynamic code. The hypervelocity impact plasmas produced are found to be significant in the amplitudes and orientations of the magnetic fields generated. An ambient magnetic field could have been provided by the core dynamo, which would have interacted with the expanding plasmas and formed ...

1984-03-12

477

Load calculation and system evaluation for electric vehicle climate control  

Energy Technology Data Exchange (ETDEWEB)

This paper presents an analysis of the applicability of alternative systems for electric vehicle (EV) heating and air conditioning (HVAC). The paper consists of two parts. The first part is a cooling and heating load calculation for electric vehicles. The second part is an evaluation of several systems that can provide the desired cooling and heating in EVs. These systems are ranked according to their overall weight The overall weight is calculated by adding the system weight and the weight of the battery necessary to provide energy for system operation. The system with the minimum overall weight is considered to be the best, because minimum vehicle weight decreases the energy required for propulsion, and therefore increases the vehicle range. Three systems are considered as the best choices for EV HVAC. These are, vapor compression, ice storage and adsorption systems. These systems are evaluated, including calculations of system weight, system volume, and COP. The ...

1994-09-12

478

Isotope exchange reaction between tritiated water and hydrogen on SiC  

Energy Technology Data Exchange (ETDEWEB)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying the serial reactor model. The ...

2003-11-15

479

Isotope exchange reaction between tritiated water and hydrogen on SiC  

International Nuclear Information System (INIS)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying the serial reactor model. The reaction rate ...

2003-11-15

480

Ionic liquids for post combustion CO{sub 2} absorption  

Energy Technology Data Exchange (ETDEWEB)

The use of ionic liquids for post combustion capture was discussed. Compared to other solvents, ionic liquids can be used in higher concentrations. Other advantages include the large variation in physical and chemical properties and the non measurable vapor pressure. In this study, 78 different ionic liquids were synthesized and the carbon dioxide absorption rate was measured. The most promising ionic liquids were produced and various tests were made to identify the most suitable absorption solvent. The vapor-liquid equilibrium curve was measured between 40 and 110 degrees C. Pilot plant tests with MEA and one selected ionic liquid test with 30 per cent MEA at the pilot plant at the EVNs Duernrohr Power Station in Lower Austria are running successfully with a capture performance of approximately 87 per cent. The experiments will provide a direct comparison of the energy demand and capture performance between the MEA and the ionic liquids.

2009-07-01

481

Horizontal liquid film mist two-phase flow, 2. Droplet deposition and entrainment rates  

Energy Technology Data Exchange (ETDEWEB)

In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow rate distribution of droplets on respective cross sections ...

1984-06-01

482

Horizontal liquid film mist two-phase flow, 2  

International Nuclear Information System (INIS)

In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow rate distribution of droplets on respective cross sections ...

1984-01-01

483

Flux pinning and critical currents in A-15 superconductors  

Science.gov (United States)

The relationship between processing, microstructure, and properties was studied for A-15 compounds in multifilamentary composites produced by solid-state diffusion and in thin-film samples produced by vapor deposition. Grain sizes of A-15 superconducting compounds were measured by transmission electron microscopy of multifilamentary composites reacted at various temperatures. Critical current densities at 4.2 K and fields up to 6 T were found to be similar for niobium-tin, vanadium-gallium, and vanadium-silicon of the same grain size. Study of the Cu-V-Si phase diagram led to the production of improved multifilamentary vanadium-silicon conductors. The effects of various alloying elements on A-15 layers produced by solid-state diffusion were studied. The most promising new observation was that tantalum can be incorporated into niobium-tin reaction layers, leading to an enhancement of critical currents at high fields. The critical temperature of ...

1978-02-01

484

Evaluation of the cleanliness of ultrapure water by the analysis for metal concentration deposited on Si wafer surface using vapor phase decomposition/inductively coupled plasma mass spectrometry  

International Nuclear Information System (INIS)

Along with the shrinkage of LSI geometries, a higher quality of ultrapure water has been continuously required. Analytical technology for ultrapure water has also progressed before ultrapure water production technology improvements. In this study, we performed optimization of the analytical conditions for the direct analysis of acid droplets, and established an analytical technology for measurements of trace amounts of metallic impurities deposited on a wafer surface by means of Vapor Phase Decomposition (VPD)/Inductively Coupled Plasma Mass Spectrometry (ICP-MS). As a result, analytical technology for metallic elements of the 1x10"8 atoms/cm"2 level on wafer surface has been established. By applying analytical technology to the wafer that has been contacted with ultrapure water, a new evaluation technology for ultrapure water quality by means of wafer surface contamination has been established. We confirmed good correlations between metal contamination of the ...

2010-07-01

485

Estimation of vapour pressure over MOX fuel  

International Nuclear Information System (INIS)

Use of high plutonia MOX as fuel is contemplated from the point of view of rapid disposition of plutonium and economic power generation. The fuel pellets are subjected to steep thermal gradients #approx# 1700 K drop across a radius of #approx# 2.5mm. This leads to evaporation-condensation of the fuel constituents to cooler regions. Vaporization depends on fuel compositions such as Pu fraction, Oxygen-to-Metal (O/M) ratio and local temperature. Knowledge of vapour chemistry is essential in understanding the fuel behavior. The vaporization behaviour of MOX was analyzed in this work using thermochemical methods. The vapour phase consisted of nine species; O, O_2, Pu, PuO, PuO_2, U, UO, UO_2 and UO_3. Oxygen formed part of the vapour phase along with other species and oxygen potential was not controlled independently. The vapour pressures were estimated at 2000 K as a function of (O/M) for several Pu-fraction. Results for MOX-28%PuO_2 is shown in ...

2010-12-01

486

Electrical properties of ultra-thin oxynitrided layer using N{sub 2}O plasma in inductively coupled plasma chemical vapor deposition for non-volatile memory on glass  

Energy Technology Data Exchange (ETDEWEB)

In this work, the silicon oxynitride layer was studied as a tunneling layer for non-volatile memory application by fabricating low temperature polysilicon thin film transistors on glass. Silicon wafers were oxynitrided by only nitrous oxide plasma under different radio frequency powers and plasma treatment times. Plasma oxynitridation was performed in RF plasma using inductively coupled plasma chemical vapor deposition. The X-ray energy dispersive spectroscopy was employed to analyze the atomic concentration ratio of nitrogen/oxygen in oxynitride layer. The oxynitrided layer formed under radio frequency power of 150 W and substrate temperature of 623 K was found to contain the atomic concentration ratio of nitrogen/oxygen as high as 1.57. The advantage of high nitrogen concentration in silicon oxide layer formed by using nitrous oxide plasma was investigated by capacitance-voltage measurement. The analysis of capacitance-voltage characteristics demonstrated that ...

2007-06-04

487

Electrical properties of ultra-thin oxynitrided layer using N_2O plasma in inductively coupled plasma chemical vapor deposition for non-volatile memory on glass  

International Nuclear Information System (INIS)

In this work, the silicon oxynitride layer was studied as a tunneling layer for non-volatile memory application by fabricating low temperature polysilicon thin film transistors on glass. Silicon wafers were oxynitrided by only nitrous oxide plasma under different radio frequency powers and plasma treatment times. Plasma oxynitridation was performed in RF plasma using inductively coupled plasma chemical vapor deposition. The X-ray energy dispersive spectroscopy was employed to analyze the atomic concentration ratio of nitrogen/oxygen in oxynitride layer. The oxynitrided layer formed under radio frequency power of 150 W and substrate temperature of 623 K was found to contain the atomic concentration ratio of nitrogen/oxygen as high as 1.57. The advantage of high nitrogen concentration in silicon oxide layer formed by using nitrous oxide plasma was investigated by capacitance-voltage measurement. The analysis of capacitance-voltage characteristics demonstrated that ...

2007-06-04

488

Corrosion behavior of materials at high temperature by environmental oxidants containing sulfur derivatives: effects of aggressive phase composition on experimental alloys. Final report  

Energy Technology Data Exchange (ETDEWEB)

For a better understanding of sulphidation mechanisms, some alloys (alloy 600, alloy 800, Uranus S, iron-chromium-aluminium-alloy) and metals (iron, chromium, nickel, molybdenum, titanium) were tested at 773, 873, 1 073 K in gaseous sulphur dioxide. Total pressure was 760 torrs. Sulphur dioxide pressure was 760, 100 and 10 torrs. Argon, oxygen, water vapor were used, successively, as pressure complement. Oxygen supply, generally speaking cause decay of corrosion resistance in SO/sub 2/ atmospheres especially at 1 073 K with low ratio p/sub O2//P/sub SO/sub 2//. Water vapor supply act similarly. Temperature laws and pressure laws do not give monotonous rise of corrosion values. There are maximas suggesting corrosion products undertaking a volatilization process. According to test conditions, Uranus S, chromium, alloy 800 (and titanium at some extent) showed good corrosion resistance. That results are supporting those obtained by JRC Ispra team, ...

1981-01-01

489

Conversion of a plasma enhanced chemical vapor deposited silicon-carbon-nitride thin film at ultra-low temperature by oxygen plasma  

Energy Technology Data Exchange (ETDEWEB)

In this work we present an ultra-low temperature method for the oxidation of an amorphous silicon-carbide-nitride (SiCN) material. The SiCN is deposited on silicon substrates by plasma enhanced chemical vapor deposition using CH{sub 4}, SiH{sub 4}, and N{sub 2} chemistry. The physical and chemical properties are characterized for the as-deposited SiCN and post-oxidized films are discussed. The SiCN film is exposed to oxygen plasma, where it undergoes a chemical transformation into a binary SiO{sub 2} material system. A 1.7 nm/min oxidation rate is typical for this process and compares favorably to oxidation methods utilizing much higher temperatures. The substrate temperature remains extremely low throughout the oxidation process, T{sub s} < 200 deg. C. Changes in film stress, optical constants, film thickness, surface roughness, and film density are measured. Chemical analysis by X-ray photoelectron spectroscopy is reported for both the as-deposited and ...

2008-01-30

490

Collection of VLE data for acid gas-alkanolamine systems using Fourier transform infrared spectroscopy. Technical report, October 1, 1994--July 31, 1995  

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. The natural gas industry requires vapor-liquid equilibrium (VLE) data to develop more energy efficient amine mixtures. Some energy reductions have been realized in the past decade by applying such amine systems as hindered amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate VLE data impedes the commercial application of these more efficient alkanolamine systems. The first objective of this project is to improve the accuracy of vapor-liquid equilibrium measurements at low hydrogen sulfide concentrations. The second objective is to make VLE measurements for amine mixtures. By improving the accuracy of the VLE data on MDEA and other amines, energy savings can be implemented in the many ...

1995-08-01

491

Collection of VLE data for acid gas-alkanolamine systems using Fourier transform infrared spectroscopy. Phase 1, September 29, 1990--September 30, 1991  

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as ``hindered`` amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA ...

1991-09-01

492

Collection of VLE data for acid gas-alkanolamine systems using Fourier transform infrared spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as hindered'' amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE ...

1991-09-01

493

Carbon dioxide absorption methanol process  

Energy Technology Data Exchange (ETDEWEB)

A process is described for removing carbon dioxide from a feed stream of natural gas, having at least methane, ethane and heavier hydrocarbon, comprising: separating the feed stream in a first separator to form a first stream, having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane, and a second stream, having methane, carbon dioxide and ethane; mixing the second stream with a polar compound to form a third stream; separating the vapor and liquid of the third stream in the bottom portion of an absorber; absorbing carbon dioxide and ethane from the separated vapor of Step C in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane forming a fourth stream; separating the ethane from the polar compound and carbon dioxide in a separator; separating the first stream in a third separator to separate the propane and heavier hydrocarbons from the carbon dioxide and ethane: ...

1987-06-23

494

CO2 Capture by Absorption with Potassium Carbonate  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. In Campaign 3 of the pilot plant, the overall mass transfer coefficient for the stripper with 7 m MEA decreased from 0.06 to 0.01 mol/(m{sup 3}.s.kPa) as the rich loading increased from 0.45 to 0.6 mol CO{sub 2}/mol MEA. Anion chromatography has demonstrated that nitrate and nitrite are major degradation products of MEA and PZ with pure oxygen. In measurements with the high temperature FTIR in 7 m MEA the MEA vapor pressure varied from 2 to 20 Pa at 35 to 70 C. In 2.5 m PZ the PZ vapor pressure varied from 0.2 to 1 Pa from 37 to 70 C.

2005-01-26

495

Advanced evaporator technology progress report FY 1992  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the work that was completed in FY 1992 on the program {open_quotes}Technology Development for Concentrating Process Streams.{close_quotes} The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to be incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium data are needed to ...

1995-01-01

496

626. 2-nm pulsed operation (300 K) of an AlGaInP double heterostructure laser grown by metalorganic chemical vapor deposition  

Energy Technology Data Exchange (ETDEWEB)

Room-temperature pulsed laser operation of (Al/sub 0.55/Ga/sub 0.45/)/sub 0.5/In/sub 0.5/P /(Al/sub 0.17/Ga/sub 0.83/)/sub 0.5/In/sub 0.5/P / (Al/sub 0.55/Ga/sub 0.45/)/sub 0.5/In/sub 0.5/P double heterostructure laser diodes grown by metalorganic chemical vapor deposition has been achieved. The lasing wavelength is 626.2 nm, which is the shortest ever reported for an AlGaInP double heterostructure laser. Threshold current density is 50 kA/cm/sup 2/ for a diode with a 20-..mu..m-wide and 200-..mu..m-long stripe.

1985-01-01

497

Pathway and Surface Mechanism Studies of 1,3-butadiene Selective Oxidation Over Vanadium-Molybdenum-Oxygen Catalysts  

Energy Technology Data Exchange (ETDEWEB)

The partial oxidation of 1,3-butadiene has been investigated over VMoO catalysts synthesized by sol-gel techniques. Surface areas were 9-14 m{sup 2}/g, and compositions were within the solid solution regime, i.e. below 15.0 mol % MoO{sub 3}/(MoO{sub 3} + V{sub 2}O{sub 5}). Laser Raman Spectroscopy and XRD data indicated that solid solutions were formed, and pre- and post-reaction XPS data indicated that catalyst surfaces contained some V{sup +4} and were further reduced in 1,3-butadiene oxidation. A reaction pathway for 1,3-butadiene partial oxidation to maleic anhydride was shown to involve intermediates such as 3,4-epoxy-1-butene, crotonaldehyde, furan, and 2-butene-1,4-dial. The addition of water to the reaction stream substantially increased catalyst activity and improved selectivity to crotonaldehyde and furan at specific reaction temperatures. At higher water addition concentrations, furan selectivity increased from 12% to over 25%. The catalytic effects of ...

2002-05-27

498

Simple method for high-temperature separation of thallium isotopes from a bulk lead target  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for the quantitative isolation of radiothallium in gas form from proton-bombarded lead of mass up to 20 g. The molten lead is kept at about 800 K in hydrofluoric-acid vapor (HF/H/sub 2/O approx. = 1) at a reduced pressure (less than or equal to4 Pa). We used 99.9% lead with the U-240 cyclotron at the Nuclear Research Institute, Academy of Sciences of the Ukrainian SSR, or the phasotron at the Join Nuclear Research Institute, which gave protons at 65 and 680 MeV correspondingly.

1988-03-01

499

Simple method for high-temperature separation of thallium isotopes from a bulk lead target  

International Nuclear Information System (INIS)

A method is proposed for the quantitative isolation of radiothallium in gas form from proton-bombarded lead of mass up to 20 g. The molten lead is kept at about 800 K in hydrofluoric-acid vapor (HF/H_2O #approx =# 1) at a reduced pressure (#<=#4 Pa). We used 99.9% lead with the U-240 cyclotron at the Nuclear Research Institute, Academy of Sciences of the Ukrainian SSR, or the phasotron at the Join Nuclear Research Institute, which gave protons at 65 and 680 MeV correspondingly.

500

Fossil Energy Program. Progress report for April 1978  

Science.gov (United States)

This report--the forty-fifth of a series--is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion process development, materials engineering, alkali metal vapor topping cycles, a coal equipment test program, an AFB coal combustor for cogeneration (CCC), engineering and support studies, process and program assistance, evironmental assessment studies, magnetic beneficiation, and AFBC demonstration plant.

1978-06-01