WorldWideScience
1

Studies about the separation of molecular species of hydrogen's isotopes by cryogenic distillation in a plant for heavy water detritiation  

Energy Technology Data Exchange (ETDEWEB)

Cryogenic distillation is the main industrial method for separating hydrogen's isotopes, because it presents the advantage of high separating factors and also the possibility of processing great quantities of gases. In the case of multicomponent mixtures the determination of transport for molecular species between the two phases is very difficult owing to the particularities of physical characteristics of each component from the mixture. The transport of molecular species is also strongly influenced by the hydrodynamics of two phases, in strong connection with the dimension of the interface between the vapor and liquid phase. The characteristics of the interface depend on the type and geometry of the separation area: plates or package. The traditional methods of analysis for exchange processes use the concept 'theoretic plate', a physical entity for which the values of concentrations for vapors ...

1998-07-01

2

Simple method for high-temperature separation of thallium isotopes from a bulk lead target  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for the quantitative isolation of radiothallium in gas form from proton-bombarded lead of mass up to 20 g. The molten lead is kept at about 800 K in hydrofluoric-acid vapor (HF/H/sub 2/O approx. = 1) at a reduced pressure (less than or equal to4 Pa). We used 99.9% lead with the U-240 cyclotron at the Nuclear Research Institute, Academy of Sciences of the Ukrainian SSR, or the phasotron at the Join Nuclear Research Institute, which gave protons at 65 and 680 MeV correspondingly.

1988-03-01

3

Simple method for high-temperature separation of thallium isotopes from a bulk lead target  

International Nuclear Information System (INIS)

A method is proposed for the quantitative isolation of radiothallium in gas form from proton-bombarded lead of mass up to 20 g. The molten lead is kept at about 800 K in hydrofluoric-acid vapor (HF/H_2O #approx =# 1) at a reduced pressure (#<=#4 Pa). We used 99.9% lead with the U-240 cyclotron at the Nuclear Research Institute, Academy of Sciences of the Ukrainian SSR, or the phasotron at the Join Nuclear Research Institute, which gave protons at 65 and 680 MeV correspondingly.

4

Isotope exchange reaction between tritiated water and hydrogen on SiC  

Energy Technology Data Exchange (ETDEWEB)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method ...

2003-11-15

5

Isotope exchange reaction between tritiated water and hydrogen on SiC  

International Nuclear Information System (INIS)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying ...

2003-11-15

6

Low-pressure degenerate four-wave mixing spectroscopy with flam atomization  

Energy Technology Data Exchange (ETDEWEB)

A combination of degenerate four-wave mixing spectroscopy and a low-pressure sampling technique has been studied for isotopic analysis in an air-acetylene flame. Hyperfine spectra of D lines of sodium and several mixtures of lithium isotopes obtained in this way are presented.

1988-08-01

7

Nomographs estite floating-roof tank evaporation  

Energy Technology Data Exchange (ETDEWEB)

Nomographs are presented that estimate the evaporation loss from external floating-roof tanks using tank diameter, type of seal, product vapor pressure, and wind velocity.

1986-01-27

8

Uranium isotopic assay instrument  

International Nuclear Information System (INIS)

Full text: The isotopic assay instrument under development at Pacific Northwest National Laboratory (PNNL) is capable of rapid prescreening to detect small and rare particles containing high concentrations of uranium in a heterogeneous sample. The isotopic measurement concept is based on laser vaporization of solid samples followed by sensitive isotope-specific detection using either uranium atomic fluorescence emission or uranium atomic absorbance. Both isotopes are measured concurrently, following a single ablation laser pulse using two external-cavity violet diode lasers. The simultaneous measurement of both isotopes enables the correlation of the fluorescence and absorbance signals on a shot-to-shot basis. This measurement approach demonstrated negligible channel crosstalk between isotopes. Scanning the heterogeneous samples provides ...

2006-10-16

9

Explosives detection: the problem and prospects  

Energy Technology Data Exchange (ETDEWEB)

The history of explosives vapor detection includes almost every detection strategy known to man. Initial attempts to utilize these techniques were dismal failures. However, with the development of the Electron Capture Detector (ECD), the first promising detection of explosives vapors became possible. The present commercial explosives detectors detect the higher vapor pressure materials but not the whole spectrum. This paper describes the basic properties of explosives molecules and our research to utilize these properties for increased detection sensitivity.

1984-01-01

10

Determination of vapor pressures, enthalpies of sublimation, and enthalpies of fusion of benzenetriols  

Energy Technology Data Exchange (ETDEWEB)

Molar enthalpies of sublimation of 1,2,4-, 1,2,3-, and 1,3,5-tri-hydroxy-benzene, were obtained from the temperature dependence of the vapor pressure measured by the transpiration method. The molar enthalpies of fusion and molar heat capacities of these compounds were measured by DSC. The measured data sets of vaporization, sublimation and fusion enthalpies were checked for internal consistency. Strength of the inter- and intra-molecular hydrogen bonding in di- and tri-hydroxy-benzenes have been assessed.

2004-06-07

11

Study on cold startability and mixture formation of high-percentage methanol blends  

Energy Technology Data Exchange (ETDEWEB)

Using gasoline as an example of additives for cold start improvement, fuel vapor composition of methanol-gasoline mixtures, fuel evaporation rate in consideration of temperature drop due to heat of fuel evaporation, air fuel ratio, stoichiometric air fuel ratio and excess air ratio of fuel vapor were calculated. The mixture formation of methanol-gasoline mixtures at low temperature in otto cycle engines was studied. Van Laar's empirical formula was used to estimate the partial pressure of high-percentage methanol blends. It was found that the most part of fuel vapor is occupied by gasoline, even when a small amount of gasoline is added to methanol resulting to an extremely small excess air ratio. It is obvious that this vapor pressure adjustment using gasoline is the dominant factor for improvement in cold startability. (10 figs, 1 tab, 10 refs)

1988-05-31

12

Isotopic composition of elements in extra-terrestrial materials 1  

Energy Technology Data Exchange (ETDEWEB)

The present review focuses on the isotropic composition in extra-terrestrial materials. There are many different factors in the variation in isotopic abundance between terrestrial and extra-terrestrial materials. Major factors in unusual isotopic composition are roughly grouped into three categories: factors associated with fractionation of isotopes, nuclear reaction or radioactive disintegration. Fractionation takes place due to differences in mass among various isotopes. There are physical and chemical factors. Physical ones include vaporization and condensation which meteorites may experience during their formation while the chemical ones include chemical reactions and chemical equilibration. There phenomena are mentioned as factors in the variation in isotopic ratio which is associated with nuclear reactions. An important nuclear reaction is the formation of ...

1989-02-01

13

Experimental investigation of wall static pressure fluctuations in parallel boiling flow  

International Nuclear Information System (INIS)

Measurements of the statistical characteristics of channel wall static pressure fluctuations in parallel one-component boiling flow are reported. The measurements span a wide range of local subcooling and vapor volume fraction, and correspond to flow regimes ranging from highly subcooled bubbly to saturated slug-annular. Vapor volume fraction measurements at the pressure measurement station are also reported in conjunction with visual observation of the flow structure. Variation of static pressure fluctuation intensity and spectral content with local thermal-hydraulic condition is demonstrated. Finally, it is suggested that diagnosis of local two-phase flow regime on the basis of (i) statistical characteristics of the pressure data, and (ii) time trace of pressure signal, may be possible. 15 refs.

1980-01-01

14

Effect of resin size on HETP in separation of isotopes by chromatography  

Energy Technology Data Exchange (ETDEWEB)

In this report, the quantitative relation between the height equivalent to a theoretical plate (HETP) and the size of ion exchange resin is studied by enriching lithium isotopes with high pressure ion exchange displacement chromatography. The dependence of HETP on the size of the resin can be expressed as H = C x (anti r)sup( ) in which = 2.4 and it is found that Snyder's equation is suitable for such a system of isotope separation as may be explained by the simple displacement mechanism.

1985-02-01

15

Uptake of atmospheric tritium by market foods  

Energy Technology Data Exchange (ETDEWEB)

In this paper uptake of tritium by market foods from tritiated water vapor in the air is investigated using cereals and beans purchased in Deep River, Canada. The concentrations of tissue free water tritium (TFWT) and organically bound tritium (OBT) range from 12 to 79% and from 10 to 38% respectively, of that estimated for atmospheric water vapor of the sampling month. The specific activity ratios of OBT to TFWT were constant for cereals, but variable for beans. The elevated OBT was shown to be the result of isotopic exchange of labile hydrogen by the fact that washing the foods with tritium free-water reduced their tritium contents to levels characteristic of their production sites.

1992-03-01

16

Explosives detection The problem and prospects  

Energy Technology Data Exchange (ETDEWEB)

Explosives molecules have a number of unique properties. These properties are discussed. They include low vapor pressures, electronegativity, ''stickiness,'' frangibility, and thermal instability. The program for developing an advanced explosives detector is described.

1984-07-01

17

Three-dimensional discrete ordinates radiation transport calculations of neutron fluxes for beginning-of-cycle at several pressure vessel surveillance positions in the high flux isotope reactor  

Energy Technology Data Exchange (ETDEWEB)

The objective of this research was to determine improved thermal, epithermal, and fast fluxes and several responses at mechanical test surveillance location keys 2, 4, 5, and 7 of the pressure vessel of the Oak Ridge National Laboratory High Flux Isotope Reactor (HFIR) for the beginning of the fuel cycle. The purpose of the research was to provide essential flux data in support of radiation embrittlement studies of the pressure vessel shell and beam tubes at some of the important locations.

1993-11-01

18

Vapor fraction measurements in a steam-water duct at atmospheric pressure using neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

Real-time neutron radiography has been used to study the dynamic behavior of two-phase flow and measure vapor fractions in a steam-water duct at atmospheric pressure. This unique experimental technique offers one the opportunity to observe and record on videotape now Patterns and transient behavior of two-phase flow inside opaque containers without perturbing the environment. The neutron radiographic technique is non-intrusive and requires no special transparent window region. Data are recorded simultaneously over a large area of interest. Image processing of the video data can be employed to measure bubble velocities and time-averaged and Instantaneous vapor fractions.

1994-11-11

19

Purification of CH{sub 3}Cl from CH{sub 3}I using cold trap with sealed 2,2,4-trimethylpentane for {delta}{sup 37}Cl measurement  

Energy Technology Data Exchange (ETDEWEB)

A cryogenic separation method of chloromethane (CH{sub 3}Cl) from methyl iodide (CH{sub 3}I) for {delta}{sup 37}Cl measurement with isotope ratio mass spectrometer is described. A cold trap with sealed 2,2,4-trimethylpentane (TMP) as the cryogen is used in this method. CH{sub 3}Cl can be separated from CH{sub 3}I at the TMP melting point (-107 deg. C) based on the difference in the vapor pressure between CH{sub 3}Cl (322.6 Pa) and CH{sub 3}I (lower than 1.3 Pa) at -107 deg. C. After two-step separation processes, the yields of CH{sub 3}Cl purified from CH{sub 3}Cl-CH{sub 3}I mixture are 96-101%, and the difference between the {delta}{sup 37}Cl{sub original} and {delta}{sup 37}Cl{sub Afterseparation} is from -0.06 to +0.06 per mille (0.01 {+-} 0.04 per mille ). These results suggest that CH{sub 3}Cl is completely separated from CH{sub 3}I with no change of {delta}{sup 37}Cl value. This method using the cold trap with sealed ...

2006-01-05

20

Oxidation, volatilization, and redistribution of molybdenum from TZM alloy in air  

Energy Technology Data Exchange (ETDEWEB)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, MoO{sub 3}(m), in air and the hydroxide, MoO{sub 2}(OH){sub 2}, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report the authors present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800 C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for ...

2000-01-01

21

Oxidation, Volatilization, and Redistribution of Molybdenum from TZM Alloy in Air  

Energy Technology Data Exchange (ETDEWEB)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, (MoO3)m, in air and the hydroxide, MoO2(OH)2, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report we present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800°C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for vapor ...

2000-01-01

22

Quantitative model of vapor dominated geothermal reservoirs as heat pipes in fractured porous rock  

Science.gov (United States)

We present a numerical model of vapor-dominated reservoirs which is based on the well-known conceptual model of White, Muffler, and Truesdell. Computer simulations show that upon heat recharge at the base, a single phase liquid-dominated geothermal reservoir in fractured rock with low matrix permeability will evolve into a two-phase reservoir with B.P.D. (boiling point-for-depth) pressure and temperature profiles. A rather limited discharge event through cracks in the caprock, involving loss of only a few percent of fluids in place, is sufficient to set the system off to evolve a vapor-dominated state. The attributes of this state are discussed, and some features requiring further clarification are identified. 26 refs., 5 figs.

1985-03-01

23

Preliminary assessment of condensation behavior for hydrocarbon-vapor expansions which cross the saturation line near the critical point  

Energy Technology Data Exchange (ETDEWEB)

Previous analyses of binary cycles for conversion of geothermal energy from moderate temperature resources to electrical energy have shown potential gains in net geofluid effectiveness of on the order of 8%, resulting from selection of turbine-expansion processes whose equilibrium states pass through the two-phase region (assuming major condensation does not occur). If condensation occurs, this gain could be reduced or eliminated by the resulting loss in turbine efficiency. Experience with many fluids, however, indicates that vapor supersaturation (or subcooling) permits metastable pure-vapor states to exist at temperatures considerably below the saturation temperature at a given pressure; thus, by better understanding the condensation process, and properly structuring the cycle, substantial performance gains may be achievable. The present study assessed, qualitatively, the probability for attaining this performance gain.

1982-07-01

24

Gibbs ensemble Monte Carlo simulations of coexistence properties of a polarizable potential model of water  

Energy Technology Data Exchange (ETDEWEB)

The liquid/vapor coexistence density, the partial vapor pressure, and the heat of vaporization were calculated using Gibbs ensemble Monte Carlo simulation techniques. Long-range interactions such as charge-charge, charge-dipole, and dipole-dipole were evaluated using Ewald summation techniques. A polarizable potential model was used to describe the water-water interactions (Dang and Chang, J. Chem. Phys. 106, 8149, 1997). The model yields good agreement with the corresponding experimental data in the lower temperature region and moderate agreement in the higher temperature region. The critical temperature and density were estimated to be 565 K and 0.28 g/cm3.

2001-12-01

25

Reactive sticking coefficients for silane and disilane on polycrystalline silicon  

Energy Technology Data Exchange (ETDEWEB)

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition-rate measurements using molecular beam scattering and a very low-pressure cold-wall reactor. The RSCs have nonlinear Arrhenius temperature dependencies and decrease with increasing flux at low (710 /sup 0/C) temperatures. Several simple models are proposed to explain these observations. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction and low-pressure chemical vapor deposition-rate measurements.

1988-04-15

26

Molina: a non-linear code to compute the internal hydrodynamics of a gas centrifuge  

Energy Technology Data Exchange (ETDEWEB)

Uranium enrichment by gas centrifugation relies on the pressure diffusion of the isotopes when their gaseous mixture is submitted to the pressure diffusion in the strong radial pressure gradient due to the centrifugal force in a very rapidly rotating cylinder. To compute the isotope separation in a gas centrifuge, the viscous compressible Navier-Stokes equations are solved for the mixture, then the diffusion equations are solved for the isotopes. As far as the separation performance is concerned, the models deal with the steady state of the axi-symmetric gas motion in the rotating cylinder. The numerical tools are briefly presented: first, the MOLINA code which numerically solves the axi-symmetric gas motion in the specific conditions of rapid rotation by use of a change of variables suited to the high density gradient and by use of a Marker And Cell method; ...

2003-07-01

27

Preliminary assessment of condensation behavior for hydrocarbon-vapor expansions which cross the saturation line near the critical point  

Energy Technology Data Exchange (ETDEWEB)

Previous analyses of binary cycles for conversion of geothermal energy from moderate temperature resources to electrical energy have shown potential gains in net geofluid effectiveness on the order of 8%, resulting from selection of turbine-expansion processes whose equilibrium states pass through the two-phase region. If condensation occurs, this gain could be reduced or eliminated by the resulting loss in turbine efficiency. Experience with many fluids, however, indicates that vapor supersaturation permits metastable pure-vapor states to exist at temperatures considerably below the saturation temperature at a given pressure; thus, by better understanding the condensation process, and properly structuring the cycle, substantial performance gains may be possible. The purpose of the present study was to assess the probability for attaining this performance gain by estimating the extent of condensation which might be expected ...

1983-01-01

28

Designing a healthy house - an overview  

Energy Technology Data Exchange (ETDEWEB)

There are certain factors to take into account when determining the suitability of a healthy house site. Power lines, agricultural spraying, vehicle exhaust, and industrial pollution are all potential sources of indoor air contamination. It is recommended that a environmental assessment be done to determine whether there are specific sources of contamination. Good drainage is required. The surrounding landscaping should be open and sunlit, and with low maintenance requirements. Decks and fences made from pressure-treated or chemical treated lumber should be avoided. One of the early decisions in the design process is the choice of the structural system. The key with all foundation types is to control moisture, whether from rain, from the ground, or the condensation of moisture from the air with cooling. The construction frame is sealed away from the occupants by the air/vapor barrier, so only in extreme cases is it essential to use alternatives ...

1999-11-01

29

Isolation condenser passive cooling of a nuclear reactor containment  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a nuclear system comprising a containment airspace in which a nuclear reactor pressure vessel is disposed there being a reactor core within the pressure vessel. It comprises a heat exchanger elevated a distance above the pressure vessel; a pool of water surrounding the heat exchanger; means for venting the pool of water to an environment outside the containment; a heat exchanger entry conduit within the containment, the entry conduit having an open lower end communicating with the containment space, and an upper end connected to the heat exchanger, water-containing heated fluid present in the containment airspace incident a pressure vessel loss of coolant event entering and flowing through the entry conduit into the heat exchanger for cooling the fluid to convert water vapor therein to a condensate and separate non-condensable gasses therefrom; a gravity driven ...

1991-10-22

30

Charts give vapor loss from internal floating-roof tanks  

Energy Technology Data Exchange (ETDEWEB)

Nomographs have been constructed to estimate the average evaporation loss from internal floating-roof tanks. Loss determined from the charts can be used to evaluate the economics of seal conversion and to reconcile refinery, petrochemical plant, and storage terminal losses. The losses represent average standing losses only. They do not cover losses associated with the movement of product into or out of the tank. The average standing evaporation loss from an internal floating-roof tank depends on: vapor pressure of the product; type and condition of roof seal; tank diameter; and type of fixed roof support. The nomographs can estimate evaporation loss for product true vapor pressures (TVP) ranging from 1.5 to 14 psia, the most commonly used seals for average and tight fit conditions, tank diameters ranging from 50 to 250 ft, welded and bolted designs, and both self-supporting and column-support fixed roof ...

1987-03-09

31

Corrosion behavior of materials at high temperature by environmental oxidants containing sulfur derivatives: effects of aggressive phase composition on experimental alloys. Final report  

Energy Technology Data Exchange (ETDEWEB)

For a better understanding of sulphidation mechanisms, some alloys (alloy 600, alloy 800, Uranus S, iron-chromium-aluminium-alloy) and metals (iron, chromium, nickel, molybdenum, titanium) were tested at 773, 873, 1 073 K in gaseous sulphur dioxide. Total pressure was 760 torrs. Sulphur dioxide pressure was 760, 100 and 10 torrs. Argon, oxygen, water vapor were used, successively, as pressure complement. Oxygen supply, generally speaking cause decay of corrosion resistance in SO/sub 2/ atmospheres especially at 1 073 K with low ratio p/sub O2//P/sub SO/sub 2//. Water vapor supply act similarly. Temperature laws and pressure laws do not give monotonous rise of corrosion values. There are maximas suggesting corrosion products undertaking a volatilization process. According to test conditions, Uranus S, chromium, alloy 800 (and titanium at some extent) showed good ...

1981-01-01

32

Isotopic analysis of lithium by hollow cathode excitation  

Energy Technology Data Exchange (ETDEWEB)

A method for quick, high-accuracy measurement of lithium isotopes has become necessary in carrying out research on the separation and concentration of lithium isotopes by ion exchange. The present report focuses on the application of a hollow cathode, as excitation source, to emission spectral analysis for lithium isotope measurement. The grating monochromator used incorporates a pressure scanned etalon. With decreased Doppler broadening and pressure broadening, the hollow cathode, used as excitation source, can give narrow spectral lines, permitting good separation among them. To achieve a high accuracy, the emission intensity of the hollow cathode should be maintained as stable as possible relative to time. In particular, the stability of a light source can be affected significantly by the chemical form of the sample. A study is also made here to identify a condition where lithium ...

1990-04-01

33

Plasma Enhanced Chemical Vapor Deposition (PECVD) Application And Atmospheric Pressure Plasma Characteristics  

International Nuclear Information System (INIS)

Atmospheric pressure plasma enhanced chemical vapour deposition system is built. The electrical and optical characteristics of the APPECVD system is given. The system is used to deposit conductive polymers and nano composites onto glass and metal surfaces. The morphological, optical, chemical and electrical characteristics of deposited surfaces are investigated using SEM, AFM four probe deposition purposes. The photovoltaic applications of plasma deposited polymers and nonconsumption are compared with deposited with electrochemical methods show different results. The electrical, chemical and morphological structures of the samples will be given.

2008-08-25

34

Hermetically sealed aluminum electrolytic capacitor  

Science.gov (United States)

Aluminum electrolytic capacitors are presently not allowed on NASA missions because they outgas water and organic vapors, as well as H2. As a consequence, much larger and heavier packages of tantalum capacitors are used. A hermetically sealed aluminum capacitor has been developed under NASA-MSFC SBIR contracts. This capacitor contains a nongassing electrolyte that was developed for this application so internal pressure would remain low. Capacitors rated at 250 to 540 V have been operated under full load for thousands of hours at 85 and 105 C with good electrical performance and low internal pressure. Electrolyte chemistry and seal engineering concepts will be discussed.

1995-04-01

35

Laser induced fluorescence measurements of the mixing of fuel oil with air  

Energy Technology Data Exchange (ETDEWEB)

We report on measurements of the mixing of fuel oil with air at atmospheric pressure in an industrial premixed gas turbine burner. The concentration of the vaporized fuel oil was measured with laser induced fluorescence. We reason that the fuel oil concentration can be considered with good accuracy as proportional to the fluorescence intensity. (author) 6 fig., 3 refs.

1999-08-01

36

Depleted zinc: Properties, application, production  

Energy Technology Data Exchange (ETDEWEB)

The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.

2009-07-15

37

PHYSICAL VAPOR DEPOSITION APPARATUS  

J-STORE (Japan)

Full Text Available

2007-09-14

38

Terahertz time-domain spectroscopy of atmospheric water vapor from 0.4 to 2.7 THz.  

Energy Technology Data Exchange (ETDEWEB)

We conducted broadband absorption measurements of atmospheric water vapor in the ground state, X {sup 1}A{sub 1} (000), from 0.4 to 2.7 THz with a pressure broadening-limited resolution of 6.2 GHz using pulsed, terahertz time-domain spectroscopy (THz-TDS). We measured a total of seventy-two absorption lines and forty-nine lines were identified as H{sub 2}{sup 16}O resonances. All the H{sub 2}{sup 16}O lines identified were confirmed by comparing their center frequencies to experimental values available in the literature.

2005-10-01

39

Room-temperature continuous-wave operation of a GaInP/AlGaInP multiquantum well laser grown by metalorganic chemical vapor deposition  

Science.gov (United States)

Room-temperature continuous-wave (cw) operation of a GaInP/AlGaInP multiquantum well (MQW) laser was achieved for the first time. The threshold current was 70 mA at 22 /sup 0/C for a device with an 8-..mu..m-wide and a 250-..mu..m-long planar stripe. The emission wavelength was 668 nm. The characteristic temperature T/sub 0/ was 138 K under cw operation. The wafer with the MQW structure composed of 100-A-thick GaInP wells and 40-A-thick AlGaInP barrier layers was grown by atmospheric pressure metalorganic chemical vapor deposition.

1987-04-20

40

Photocatalytic degradation of gaseous pyridine over zeolite-supported titanium dioxide  

Energy Technology Data Exchange (ETDEWEB)

The photocatalyzed degradation of pyridine in the gas phase was investigated using titanium dioxide semiconductor supported on mordenite. The complete mineralization was found to occur over a catalyst containing 75 wt% TiO{sub 2} and 25 wt% mordenite in about 180 min in the presence of saturated water vapor at O{degrees}C (4.6 Torr). Low water vapor pressure of 0.096 Torr was found to be sufficient to achieve a reasonably high percentage and rate of degradation. Diffusion of pyridine within the catalyst adversely affects the activity when the thickness of the catalyst coating exceeds the penetration depth of illumination. The activity of the zeolite-supported catalysts was higher than that of TiO{sub 2}. The photonic efficiency for the complete mineralization of pyridine to CO{sub 2} was determined to be 0.48. 29 refs., 6 refs., 1 tab.

1994-09-01

41

Microgravity two-phase flow regime modeling  

Energy Technology Data Exchange (ETDEWEB)

A flow pattern or flow regime is the characteristics spatial distribution of the phases of fluid in a duct. Since heat transfer and pressure drop are dependent on the characteristic distribution of the phases, it is necessary to describe flow patterns in an appropriate manner so that a hydrodynamic or heat transfer theory applicable to that pattern can be chosen. The objective of the present analysis is to create a flow regime map based on physical modeling of vapor/liquid interaction phenomena in a microgravity environment. In the present work, four basic flow patterns are defined: dispersed flow, stratified flow, slug flow, and annular flow. Fluid properties, liquid and vapor flow rates, and pipe size were chosen as the principal parameters. It is assumed that a transition from one flow pattern to another will occur when there is a change in the dominant force which controls that flow pattern. The forces considered in ...

1987-01-01

42

Mechanism of the electric field effect on the intensity of visible continuum emission from the positive column of gas discharge in a cesium vapor-xenon mixture  

British Library Electronic Table of Contents (United Kingdom)

We have studied the nature of continuum emitted in the visible spectral range from a noncontracted positive column of discharge in a cesium vapor-xenon mixture at a pressure of 45 Torr and at a degree of ionization below 3 ? 10?6. The main contribution to the continuous emission under such conditions is due to electron-xenon atom bremsstrahlung. The intensity of emission has been experimentally and theoretically studied as a function of the electric field strength and electron density in the positive column. It is established that an increase in the visible emission intensity with the electric field strength is related to an increase in the number of hot electrons in plasma.

2007-01-01

43

A novel accelerated oxidative stability screening method for pharmaceutical solids  

British Library Electronic Table of Contents (United Kingdom)

Abstract Despite the fact that oxidation is the second most frequent degradation pathway for pharmaceuticals, means of evaluating the oxidative stability of pharmaceutical solids, especially effective stress testing, are still lacking. This paper describes a novel experimental method for peroxide-mediated oxidative stress testing on pharmaceutical solids. The method utilizes urea-hydrogen peroxide, a molecular complex that undergoes solid-state decomposition and releases hydrogen peroxide vapor at elevated temperatures (e.g., 30C), as a source of peroxide. The experimental setting for this method is simple, convenient, and can be operated routinely in most laboratories. The fundamental parameter of the system, that is, hydrogen peroxide vapor pressure, was determined using a modified spect...

2011-01-01

44

Design and fabrication of a two dimensional valveless micropump  

Energy Technology Data Exchange (ETDEWEB)

The scale-down of a liquid mini-pump (order of 10 mm) to a micrometre scale has been attempted using a novel valveless nozzle-diffuser design and new application of an organic physical vapor-deposited membrane. The micropump employs no moving parts other than the membrane and accomplishes the rectification of fluid flow due to pressure recovery differences in the nozzle and diffuser flow directions. More specifically, liquids flow with less resistance (i.e. conduct more fluid) in the diffuser direction than the nozzle direction, for a given pressure differential. At the micrometre scale, the fabrication of the critical nozzle and diffuser elements was performed by focused ion beam (FIB) microlithography of glass slides. Etched slides were sandwiched to make two-dimensional venturis. Sternme and Sternme noted the importance of a lower Reynolds Number linfit on the desired pressure recovery which ...

1995-12-31

45

Vapor phase lubrication of a Ni-based superalloy  

Energy Technology Data Exchange (ETDEWEB)

In addition to ceramics, alloys such as tool steel and nickel- and iron-based superalloys are being considered for high temperature applications such as missile bearings and low heat rejection engines. Studies were made to lubricate a nickel-based superalloy at 500{degrees}C, by using a vaporized aryl phosphate ester, at a concentration of 0.1% in air. From deposition and wear studies it was found that it was impossible to form a good polymeric coating on the superalloy surface. Energy dispersive X-ray analyzer (EDXA) analysis showed that this was due to minute quantities of aluminum in the alloy segregating to the surface, upon being heated to 500{degrees}C, forming a passive oxide coating. It was necessary to activate the surface, in order to lubricate the material successfully. A method of activation by electrodepositing the surface with a layer of iron oxide was developed. Once activated, a good lubricous polymer was formed on the superalloy surface. Tests ...

1995-03-01

46

Laboratory studies of gas generation and potential for tank wall corrosion during blending of high-level wastes at the West Valley Demonstration Project  

Energy Technology Data Exchange (ETDEWEB)

Laboratory experiments were conducted to simulate the transfer of acidic THOREX waste from Tank 8D-4 into the alkaline PUREX waste in Tank 8D-2 at West Valley. The purpose of the experiments was to explore means of minimizing the production of nitric oxide (NO) gas during mixing of the two wastes and to assess the potential for the gas to further react in the vapor space possibly leading to enhanced corrosion of the tank walls. Forty one THOREX/PUREX mixing tests were conducted to explore the effects of stirring rate, pH, THOREX addition rate, THOREX or PUREX dilution, and temperature. The two most important criteria for minimizing NO production were to maintain some degree of agitation and the keep the pH in the PUREX high, preferably >12. Steel corrosion tests were performed in the presence of low partial pressures of NO{sub 2} and liquid water or water vapor. The NO{sub 2} (from oxidation of NO in the ...

1995-05-01

47

Anomalous carbon isotope fractionation between atmospheric CO/sub 2/ and dissolved inorganic carbon induced by intense photosynthesis  

Energy Technology Data Exchange (ETDEWEB)

A stable isotope mass-balance of dissolved inorganic carbon during a blue-green algae bloom in a softwater lake demonstrates that at low partial pressure of carbon dioxide there must be a large net negative carbon isotope fractionation between atmospheric CO/sub 2/ and the CO/sub 2/ absorbed by lake water at pH = 9.5. Chemical enhancement of CO/sub 2/ invasion at high pH by the reaction CO/sub 2/ + OH/sup -/ ..-->.. HCO/sub 3//sup -/ at large apparent film thicknesses may result in carbon isotope fractionation approaching that for a hydroxide solution. This phenomenon, coupled with a decrease in the photosynthetic fractionation, forced the surface water of a softwater lake to achieve increasingly negative delta /sup 13/C values during an algal bloom, which is in the opposite sense to the trend that results from photosynthesis under less extreme conditions. This and other similar systems must operate ...

1987-04-01

48

Technique for compressing light intensity ranges utilizing a specifically designed liquid crystal notch filter  

Energy Technology Data Exchange (ETDEWEB)

A pin hole camera assembly for use in viewing an object having a relatively large light intensity range, for example a crucible containing molten metal in an atomic vapor laser isotope separation (AVLIS) system is disclosed herein. The assembly includes means for optically compressing the light intensity range appearing at its input sufficient to make it receivable and decipherable by a standard video camera. To accomplish this, the assembly utilizes the combination of interference filter and a liquid crystal notch filter. The latter which preferably includes a cholesteric liquid crystal arrangement is configured to pass light at all wavelengths, except a relatively narrow wavelength band which defines the filter's notch, and includes means for causing the notch to vary to at least a limited extent with the intensity of light at its light incidence surface.

1988-01-01

49

Effect of Atmospheric Conditions on LIBS Spectra  

Energy Technology Data Exchange (ETDEWEB)

Laser-induced breakdown spectroscopy (LIBS) is typically performed at ambient Earth atmospheric conditions. However, interest in LIBS in other atmospheric conditions has increased in recent years, especially for use in space exploration (e.g., Mars and Lunar) or to improve resolution for isotopic signatures. This review focuses on what has been reported about the performance of LIBS in reduced pressure environments as well as in various gases other than air.

2010-05-01

50

Room-temperature continuous-wave operation of an AlGaInP double heterostructure laser grown by atmospheric pressure metalorganic chemical vapor deposition  

Energy Technology Data Exchange (ETDEWEB)

Continuous-wave (cw) operation at temperatures up to 23 /sup 0/C of an Al/sub 0.26/Ga/sub 0.26/In/sub 0.48/P/Ga/sub 0.52/In/sub 0.48/P/ Al/sub 0.26/Ga/sub 0.26/In/sub 0.48/P double heterostructure (DH) laser has been achieved for the first time. The threshold current was 160 mA at 20 /sup 0/C for a device with a 10-..mu..m-wide and 250-..mu..m-long ion-implanted stripe geometry. The emission wavelength was 671 nm during cw operation at 10 /sup 0/C. To reduce thermal resistance to a heat sink, a dually stacked structure made of a thin (approx.0.3 ..mu..m) p-AlGaInP layer and a p-Al/sub 0.76/Ga/sub 0.24/As layer was used as a cladding layer. The DH wafer was grown by atmospheric pressure metalorganic chemical vapor deposition.

1985-11-15

51

Optimization of water injection into vapor-dominated geothermal reservoirs  

Energy Technology Data Exchange (ETDEWEB)

Water injection into a vapor-dominated geothermal reservoir is an effective method of sustaining steam production from the field. Injection puts additional water to the reservoir and raises the prevailing reservoir pressure. This process improves the field`s productivity. However, the increased pressure also increases the water retention capacity of the reservoir rocks through the effects of adsorption and capillary condensation. Due to the significant costs associated with water injection programs, optimizing injection not only involves maximizing the energy yield from the resource but also the present worth of the project. Two crucial parameters that need to be established are: (1) how much to inject; and, (2) when to inject it. This study investigated the optimal design of these parameters. It was found that comparable energy yield can be attained for injection programs that are initiated at various stages of the field`s ...

1996-12-31

52

Estimation of vapour pressure over MOX fuel  

International Nuclear Information System (INIS)

Use of high plutonia MOX as fuel is contemplated from the point of view of rapid disposition of plutonium and economic power generation. The fuel pellets are subjected to steep thermal gradients #approx# 1700 K drop across a radius of #approx# 2.5mm. This leads to evaporation-condensation of the fuel constituents to cooler regions. Vaporization depends on fuel compositions such as Pu fraction, Oxygen-to-Metal (O/M) ratio and local temperature. Knowledge of vapour chemistry is essential in understanding the fuel behavior. The vaporization behaviour of MOX was analyzed in this work using thermochemical methods. The vapour phase consisted of nine species; O, O_2, Pu, PuO, PuO_2, U, UO, UO_2 and UO_3. Oxygen formed part of the vapour phase along with other species and oxygen potential was not controlled independently. The vapour pressures were estimated at 2000 K as a function of (O/M) for several Pu-fraction. Results for ...

2010-12-01

53

CO2 Capture by Absorption with Potassium Carbonate  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. In Campaign 3 of the pilot plant, the overall mass transfer coefficient for the stripper with 7 m MEA decreased from 0.06 to 0.01 mol/(m{sup 3}.s.kPa) as the rich loading increased from 0.45 to 0.6 mol CO{sub 2}/mol MEA. Anion chromatography has demonstrated that nitrate and nitrite are major degradation products of MEA and PZ with pure oxygen. In measurements with the high temperature FTIR in 7 m MEA the MEA vapor pressure varied from 2 to 20 Pa at 35 to 70 C. In 2.5 m PZ the PZ vapor pressure varied from 0.2 to 1 Pa from 37 to 70 C.

2005-01-26

54

CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Progress has been made in this reporting period on three subtasks. A simple thermodynamic model has been developed to represent the CO{sub 2} vapor pressure and speciation of the new solvent. A rate model has been formulated to predict the CO{sub 2} flux with these solutions under absorber conditions. A process and instrumentation diagram and process flow diagram have been prepared for modifications of the existing pilot plant system.

2002-10-01

55

W1045 environment surf drip shield and waste package outer barrier  

Energy Technology Data Exchange (ETDEWEB)

The environments on the drip shield and waste package outer barrier are controlled by the compositions of the waters that contact these components. the temperature (T) of these components, and the effective relative humidity (RH) at these components. Because the composition of the waters that are expected to enter the emplacement drifts (either by seepage flow or by episodic flow) have not been specified: well J13 water was chosen as the reference water (Harrar 1990). Section 6.2 discusses the accessible RH for the temperatures of interest at the repository horizon. Section 6.3 discusses the adsorption of water on metal alloys in the absence of hygroscopic salts. Because the temperatures of the DSs and the WPOBs are higher than those of the surrounding near-field environment, the relative humidity at the DSs and the WPOBs will be lower than that of the surrounding near-field environment. This difference is a result of the water partial pressure in the drift being ...

1999-07-14

56

Thermal- and radiation-induced interactions of water on U02 surfaces.  

Energy Technology Data Exchange (ETDEWEB)

Most plans for the disposition of surplus nuclear materials involve storage in sealed containers where the evolution of gases from reactions of adsorbed water could present both pressure and flammability hazards[l] . Despite efforts such as calcining the material to minimize the water content prior to packaging, both residual moisture and readsorbed water may be present in the final containers . Given the anticipated temperature excursions during transportation and storage, this water may thermally desorb, increasing the pressure, and/or thermally dissociate to produce H2 gas, increasing flammability hazards . In addition, the radiation from the nuclear material may induce radiolysis of the water with the likely products being water vapor, H2, 02 and H2O2. In order to better understand the relative importance of the thermal- and radiationinduced chemistry, we have studied the interactions of water on single crystals of ...

2003-01-01

57

Electronic properties of low temperature microcrystalline silicon carbide prepared by Hot Wire CVD  

Energy Technology Data Exchange (ETDEWEB)

Microcrystalline silicon carbide ({mu}c-SiC) was prepared at low substrate temperatures using Hot Wire chemical vapor deposition (HWCVD). High crystalline volume fractions were achieved at high hydrogen dilution and high deposition pressure. Without intentional doping, such material shows high dark conductivity and high optical absorption below the band gap. The material prepared at low deposition pressure or low hydrogen dilution, on the other hand, shows much lower conductivity and sub-gap absorption, but high spin densities up to 5 x 10{sup 19} cm{sup -3}. This high absorption can be attributed to free carriers, different to {mu}c-Si:H where a correlation between the sub-gap absorption and the spin density is observed.

2008-01-15

60

Spray Chemical Vapor Deposition of Single-Source Precursors for Chalcopyrite I-III-VI2 Thin-Film Materials  

Science.gov (United States)

Thin-film solar cells on flexible, lightweight, space-qualified substrates provide an attractive approach to fabricating solar arrays with high mass-specific power. A polycrystalline chalcopyrite absorber layer is among the new generation of photovoltaic device technologies for thin film solar cells. At NASA Glenn Research Center we have focused on the development of new single-source precursors (SSPs) for deposition of semiconducting chalcopyrite materials onto lightweight, flexible substrates. We describe the syntheses and thermal modulation of SSPs via molecular engineering. Copper indium disulfide and related thin-film materials were deposited via aerosol-assisted chemical vapor deposition using SSPs. Processing and post-processing parameters were varied in order to modify morphology, stoichiometry, crystallography, electrical properties, and optical properties to optimize device quality. Growth at atmospheric pressure in a horizontal ...

2008-01-01

61

Vapor fraction measurements in a steam-water tube at up to 15 bar using neutron radiography techniques  

Energy Technology Data Exchange (ETDEWEB)

Real time neutron radiography has been used to study the dynamic behavior of two phase flow and measure the time averaged vapor fraction in a heated metal tube containing boiling steam water operating at up to 15 bar pressure. The neutron radiographic technique is non-intrusive and requires no special transparent window region. This is the first time this technique has been used in an electrically heated pressurized flow loop. This unique experimental method offers the opportunity to observe and record on videotape, flow patterns and transient behavior of two phase flow inside opaque containers without disturbing the environment. In this study the test sections consisted of stainless steel tubes with a 1.27 cm outer diameter and wall thicknesses of 0.084 cm and 0.124 cm. The experiments were carried out at the Pennsylvania State University 1 megawatt TRIGA reactor facility utilizing a Precise Optics neutron radiography ...

1998-02-01

62

Vapor fraction measurements in a steam-water tube at up to 15 bar using neutron radiography techniques  

International Nuclear Information System (INIS)

Real-time neutron radiography has been used to study the dynamic behavior of two-phase flow and measure the time averaged vapor fraction in a heated metal tube containing boiling steam-water operating at up to 15 bar pressure. The neutron radiographic technique is non-intrusive and requires no special transparent window region. This is the first time this technique has been used in an electrically heated pressurized flow loop. This unique experimental method offers the opportunity to observe and record on videotape, flow patterns and transient behavior of two-phase flow inside opaque containers without disturbing the environment. In this study the test sections consisted of stainless steel tubes with a 1.27 cm outer diameter and wall thicknesses of 0.084 and 0.124 cm. The experiments were carried out at the Pennsylvania State University 1 MW TRIGA reactor facility utilizing a Precise Optics neutron radiography camera. The ...

1999-11-03

63

Vapor fraction measurements in a steam-water tube at up to 15 bar using neutron radiography techniques  

International Nuclear Information System (INIS)

Real time neutron radiography has been used to study the dynamic behavior of two phase flow and measure the time averaged vapor fraction in a heated metal tube containing boiling steam water operating at up to 15 bar pressure. The neutron radiographic technique is non-intrusive and requires no special transparent window region. This is the first time this technique has been used in an electrically heated pressurized flow loop. This unique experimental method offers the opportunity to observe and record on videotape, flow patterns and transient behavior of two phase flow inside opaque containers without disturbing the environment. In this study the test sections consisted of stainless steel tubes with a 1.27 cm outer diameter and wall thicknesses of 0.084 cm and 0.124 cm. The experiments were carried out at the Pennsylvania State University 1 megawatt TRIGA reactor facility utilizing a Precise Optics neutron radiography ...

1998-03-16

64

Influence of phosphorus vapor ambient for InGaAsP growth on GaAs substrate  

Science.gov (United States)

For visible-light-emitting laser diodes, InGaAsP double heterostructures have been grown on GaAs substrates using liquid-phase epitaxy. As the growth temperature is as high as about 780 /sup 0/C, a large amount of phosphorus evaporates from the solutions for the cladding layers during the growth process. The phosphorus vapor disturbs the solution composition for the active layer, so that very thin and uniform active layers cannot be obtained. By using In-P-Sn solution and supplying the phosphorus partial pressure around the graphite boat, the influence of phosphorus vapor ambient for InGaAsP (lambda/sub P//sub L/ = 805 nm) growth is confirmed. When the phosphorus partial pressure increases, the surface of epitaxial layer becomes rough and the substrate is partly etched back. From x-ray diffraction and photoluminescence spectral measurements, the composition of the grown layer is also found to be ...

1986-12-01

65

Measurements of water vapor adsorption on the Geysers rocks  

Energy Technology Data Exchange (ETDEWEB)

The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 °C and at 200 °C as a function of pressure in the range 0.00 ≤ p/p0 ≤ 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were ...

1996-01-24

66

Low-Temperature Neon Isotope Separation  

International Science & Technology Center (ISTC)

Development of a Plant for Neon Isotopes Separation by Low-Temperature Rectification Method

67

Void fraction estimation within rod bundles based on three-fluid model and comparison with X-ray CT void data  

Energy Technology Data Exchange (ETDEWEB)

An interfacial shear stress equation in the dispersed-annular two-phase flow regime has been developed, which is based on a three-fluid model consisting of a liquid film on a rod, vapor and entrained liquid associated with a vapor flow. It is an extension of J.G.M. Andersen's procedure that provides a two-fluid interfacial shear stress equation using the drift flux parameters C{sub 0} and V{sub gj}. This interfacial shear stress equation can take into account a phase and velocity distribution through an equivalence between the drift flux parameters and the interfacial shear stress. Using the three-fluid subchannel analysis code TEMPO with the three-fluid interfacial shear stress model the capability of a three-fluid calculation using the drift flux parameters C{sub 0} and V{sub gj} that reproduce a measured void fraction is demonstrated. A comparison was made with advanced X-ray computed tomography (CT) void fraction data within a 4x4 ...

1990-06-01

68

Transmission electron microscope characterization of AlGaInP grown by organometallic vapor phase epitaxy  

Energy Technology Data Exchange (ETDEWEB)

AlGaInP epitaxial layers grown at 690 {degree}C by atmospheric pressure organometallic vapor phase epitaxy are investigated by transmission electron microscopy. For the first time, compositionally modulated and ordered structures are simultaneously observed in AlGaInP alloys. The ordering is of the CuPt type with ordering along the {l brace}111{r brace} directions. The ordered regions appear as plate-like microdomains, while the composition modulation takes the form of a fine columnar constrast oriented along the growth direction. In addition, from the results of (001) plan-view diffraction contrast examination, the principal strain direction associated with the modulation structures is found to be perpendicular to the growth direction and lies in the surface plane. Thus, it is concluded that the spinodal decomposition is initiated and developed on the surface during the growth of the AlGaInP epitaxial layers and, finally, forms the columnar ...

1990-04-09

69

Transmission electron microscope characterization of AlGaInP grown by organometallic vapor phase epitaxy  

International Nuclear Information System (INIS)

AlGaInP epitaxial layers grown at 690 degree C by atmospheric pressure organometallic vapor phase epitaxy are investigated by transmission electron microscopy. For the first time, compositionally modulated and ordered structures are simultaneously observed in AlGaInP alloys. The ordering is of the CuPt type with ordering along the #left brace#111#right brace# directions. The ordered regions appear as plate-like microdomains, while the composition modulation takes the form of a fine columnar constrast oriented along the growth direction. In addition, from the results of (001) plan-view diffraction contrast examination, the principal strain direction associated with the modulation structures is found to be perpendicular to the growth direction and lies in the surface plane. Thus, it is concluded that the spinodal decomposition is initiated and developed on the surface during the growth of the AlGaInP epitaxial layers and, finally, forms the ...

70

Room-temperature cw operation of InGaP/InGaAlP visible light laser diodes on GaAs substrates grown by metalorganic chemical vapor deposition  

Energy Technology Data Exchange (ETDEWEB)

Room-temperature cw operation for InGaP/InGaAlP double heterostructure (DH) laser diodes on GaAs substrates was achieved for the first time. The DH wafers were grown by low-pressure metalorganic chemical vapor deposition using methyl metalorganics. A lasing wavelength of 679 nm and a threshold current of 109 mA at 24C were obtained for an inner stripe structure laser diode with a 250- m-long and 7- m stripe geometry. The laser operated at up to 51C. The characteristic temperature T0 was 87 K at around room temperature. The lowest threshold current density, 5.0 kA/cmS, was obtained with a 20- m stripe width laser diode under room-temperature pulsed operation.

1986-01-20

71

Photoluminescence linewidths in metalorganic vapor phase epitaxially grown ordered and disordered InAlGaP alloys  

International Nuclear Information System (INIS)

The dependence of the photoluminescent properties of In_0_._4_8(Al_yGa_1_-_y)_0_._5_2P alloys (0#<=#y#<=#0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ''ordered'' domains and the ''disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a significant optimization of the optical properties of these materials, ...

72

Magnetic field amplification and generation in hypervelocity meteoroid impacts with application to lunar paleomagnetism  

International Nuclear Information System (INIS)

A one-dimensional numerical model for the expansion of impact-produced vapor clouds is used to investigate magnetic field generation mechanisms in events such as meteor collisions with the moon. The resulting cloud properties, such as ionization fraction, electrical conductivity, radial expansion velocity, mass density, and energy density are estimated. The model is initiated with the peak shock states and pressure thresholds for incipient and complete vaporization of anorthosite lunar surface materials by iron and GA composition meteorites. The expansion of the spherical gas cloud into a vacuum was traced with a one-dimensional explicit lagrangian hydrodynamic code. The hypervelocity impact plasmas produced are found to be significant in the amplitudes and orientations of the magnetic fields generated. An ambient magnetic field could have been provided by the core dynamo, which would have interacted with the expanding ...

1984-03-12

73

Ionic liquids for post combustion CO{sub 2} absorption  

Energy Technology Data Exchange (ETDEWEB)

The use of ionic liquids for post combustion capture was discussed. Compared to other solvents, ionic liquids can be used in higher concentrations. Other advantages include the large variation in physical and chemical properties and the non measurable vapor pressure. In this study, 78 different ionic liquids were synthesized and the carbon dioxide absorption rate was measured. The most promising ionic liquids were produced and various tests were made to identify the most suitable absorption solvent. The vapor-liquid equilibrium curve was measured between 40 and 110 degrees C. Pilot plant tests with MEA and one selected ionic liquid test with 30 per cent MEA at the pilot plant at the EVNs Duernrohr Power Station in Lower Austria are running successfully with a capture performance of approximately 87 per cent. The experiments will provide a direct comparison of the energy demand and capture performance between the MEA and the ...

2009-07-01

74

Transition armature technology. Progress report No. 2, August 1--September 30, 1991  

Energy Technology Data Exchange (ETDEWEB)

This second report covers the period August 1 to September 30, 1991. During this period we modified our approach to Task 1 (Hybrid Armature study) with the addition of a numerical simulation of the steady state plasma brush length with a 1-D, four-phase equation of state code. A test fixture was designed and fabrication begun on a plasma brush test fixture for hybrid studies. It will be powered by a 140 kJ, 1 MA capacitor bank on loan to the project. Diagnostic data collection with 20 channels of digitizers and data reduction with a microvax were also arranged. Sliding friction of a solid armature was simulated and found to form a vapor layer at velocities below 2 km/s. The simulations indicated that higher interface pressure results in vapor boundary layer formation at lower velocity. If there is also a minimum interface pressure required to commutate high currents, then an optimum interface ...

1991-12-31

75

Tritium Release Behavior from Li_4SiO_4  

International Nuclear Information System (INIS)

This paper proposes a model to explain tritium release behavior of an irradiated Li_4SiO_4 sample made by Forschungszentrum Karlsruhe. The release curves were obtained in a series of experiments carried out using out-pile temperature programmed desorption techniques in the Kyoto University Reactor (KUR). Tritium release curves obtained for different purge gas compositions (N_2, N_2 + H_2, N_2 + H_2O) were compared for selection of suitable conditions to determine the apparent diffusivity of tritium in a crystal grain of Li_4SiO_4.In the model formation, some mass transfer steps in the bulk of the crystal grain and those on the surface of the grain were taken into account, which were diffusion of tritium in the grain, adsorption and desorption of water on the surface of the grain, two types of isotope exchange reactions, and water formation reaction by the addition of hydrogen to the purge gas.Diffusivities of tritium in the crystal grain of Li_4SiO_4 were estimated ...

2004-12-01

76

Three-step photoionization of mercury for application to separation of mercury isomers  

International Nuclear Information System (INIS)

Development of techniques for separating isomeric nuclides is important to the investigation of schemes for gamma-ray lasers. In preparation for an experiment to separate 10_1_4 atoms of the /sub 197m/Hg (299 keV, tau/sub 1/2/ = 24 hours) isomer, we report isotopically selective resonance ionization of mercury atoms. This has been accomplished by three-step excitation via the 6_3P"1 and 8_1S"0 excited states, using three collinear pulsed laser beams of 254, 286, and 532 nm wavelengths from a Nd:YAG and two dye lasers. These beams were passed through a closed mercury-vapor cell containing electrostatic plates to which the ions were drawn. Ion current and fluorescent radiation were measured as a function of laser frequency. Hyperfine structures for the 254- and 286-nm transitions were observed.

77

Growth rate control and solid-gas modeling of TFA-YBa_2Cu_3O_7 thin film processing  

International Nuclear Information System (INIS)

The trifluoroacetate metal-organic decomposition route to YBa_2Cu_3O_7 film growth was investigated in order to bring new insights in the growth mechanism and its dependence on processing conditions and critical current density. Precursor films were processed on LaAlO_3 substrates at different total pressure, oxygen partial pressure, water vapor partial pressure, and volume gas flow rate keeping the growth temperature at 740 "0C. The influence of these various experimental parameters on the film growth rate, which was evaluated by in situ electrical resistance measurements, was studied thoroughly. It was found that the growth rate is nearly independent of the oxygen pressure and proportional to the square root of the water pressure. Additionally, the growth rate increases with a decrease of the total pressure or an increase of the gas flow ...

2010-03-01

78

Thermoelectrically cooled water trap  

Energy Technology Data Exchange (ETDEWEB)

A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

2006-02-21

79

The thermal conductivity jump at crystal-liquid phase transition in CHCl3, C6H6, and CCl4: the action of rotational molecular motions  

International Nuclear Information System (INIS)

The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ? ?p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ? ?p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.

2009-04-01

80

The thermal conductivity jump at crystal-liquid phase transition in CHCl3, C6H6, and CCl4: the action of rotational molecular motion  

Science.gov (United States)

The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ??p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ??p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.

2009-04-01

81

Photoluminescences from Al{sub x}Ga{sub 1{minus}x}P liquid phase epitaxial layers  

Science.gov (United States)

Homogenous Al{sub x}Ga{sub 1{minus}x}P liquid phase epitaxial layers have been obtained with the temperature difference method under controlled vapor pressure (TDM-CVP). Very clear fine structures near band edge in photoluminescence spectra have been observed at 77 K for the first time. Photoluminescence measurement results confirmed that the free exciton recombination without phonon assistance plays an important role in the luminescence at 77 K and becomes dominant at room temperature. It is considered that Zero-phonon assisted free exciton recombination is intensified by some local perturbations to electrical potentials against carriers or excitons introduced by Al atoms in Al{sub x}Ga{sub 1{minus}x}P layers, which can give momentum change necessary for recombination.

1999-10-01

82

Optimal dynamic detection of explosives  

Energy Technology Data Exchange (ETDEWEB)

The detection of explosives is a notoriously difficult problem, especially at stand-off distances, due to their (generally) low vapor pressure, environmental and matrix interferences, and packaging. We are exploring optimal dynamic detection to exploit the best capabilities of recent advances in laser technology and recent discoveries in optimal shaping of laser pulses for control of molecular processes to significantly enhance the standoff detection of explosives. The core of the ODD-Ex technique is the introduction of optimally shaped laser pulses to simultaneously enhance sensitivity of explosives signatures while reducing the influence of noise and the signals from background interferents in the field (increase selectivity). These goals are being addressed by operating in an optimal nonlinear fashion, typically with a single shaped laser pulse inherently containing within it coherently locked control and probe sub-pulses. With sufficient ...

2009-01-01

83

Laser-processed thin-film transistors fabricated from sputtered amorphous-silicon films  

Energy Technology Data Exchange (ETDEWEB)

Low-temperature polysilicon thin-film transistors (TFT's) have been fabricated from sputtered silicon films and characterized as a function of as-deposited hydrogen (H) content and laser crystallization fluence. A general trend is observed where TFT performance improves as the H content is lowered. Devices made from {approximately}0% H sputtered films perform similar to those made from low-pressure chemical-vapor deposition processes (LPCVD), but are fabricated at a much lower process temperature (300 C). The best sputtered TFT's had mobilities of {approximately}200 cm{sup 2}/Vs, and on/off current ratios of more than 10{sup 8}.

2000-01-01

84

Improvements to the RELAP5/MOD3 reflood model and uncertainty quantification of reflood peak clad temperature  

Energy Technology Data Exchange (ETDEWEB)

This research aims to develop reliable, advanced system thermal-hydraulic computer code and to quantify the uncertainties of code to introduce the best estimate methodology of ECCS for LBLOCA. Although the one of best estimate code, RELAP5/MOD3.1 was introduced from USNRC, several deficiencies in its reflood model and some improvements have been made. The improvements consist of modification of reflood wall heat transfer package and adjusting the drop size in dispersed flow regime. The tome smoothing of wall vaporization and level tracking model are also added to eliminate the pressure spike and level oscillation. For the verification of improved model and quantification of associated uncertainty, the FLECHT-SEASET data were used and upper limit of uncertainty at 95% confidence level is evaluated. (Author) 30 refs., 49 figs., 2 tabs.

1994-06-01

85

Experimental Study of Nucleate Pool Boiling of FC-72 on Smooth Surface under Microgravity  

British Library Electronic Table of Contents (United Kingdom)

Experiments of highly subcooled nucleate pool boiling of FC-72 with dissolved air were studied both in short-term microgravity condition utilizing the drop tower Beijing and in normal gravity conditions. The bubble behavior and heat transfer of air-dissolved FC-72 on a small scale silicon chip (10 ? 10 ? 0.5?mm3) were obtained at the bulk liquid subcooling of 41?K and nominal pressure of 102?kPa. The boiling heat transfer performance in low heat flux region in microgravity is similar to that in normal gravity condition, while vapor bubbles increase in size but little coalescence occurs among bubbles, and then forms a large bubble remains attached to the heater surface during the whole microgravity period. Thermocapillary convection may be an important mechanism of boiling heat transfer in ...

2011-01-01

86

Buried-heterostructure semiconductor Raman laser with threshold pump power less than 1 W  

Energy Technology Data Exchange (ETDEWEB)

The low-power operation of a semiconductor buried-heterostructure Raman laser is reported. We are developing these devices for very wide-band optical communication in the terahertz frequency region. It has a structure with a GaP active layer and Al{sub {ital x}}Ga{sub 1{minus}{ital x}}P cladding layers, which are grown by the temperature-difference method under controlled vapor pressure. By making the stripe width 30--40 {mu}m, we have obtained a threshold pump power of 500 mW. A low-threshold semiconductor Raman laser can be pumped by semiconductor injection lasers. We have measured the optical loss of the waveguide and detected the contribution from scattering and leakage at heterointerfaces.

1989-12-01

87

Flow Vaporization of CO{sub 2} in Microchannel Tubes  

Energy Technology Data Exchange (ETDEWEB)

Carbon dioxide is receiving renewed interest as an efficient and environmentally safe refrigerant in a number of applications, including mobile air conditioning and heat pump systems, and hot water heat pumps. Compact heat exchangers for CO{sub 2} systems are designed with small-diameter tubing. The purpose of this study is therefore to provide a better basis for understanding and predicting heat transfer and pressure drop during flow vaporization of CO{sub 2} in microchannels. The ''unusual'' properties of carbon dioxide give heat transfer and two-phase flow characteristics that are very different from those of conventional refrigerants. Examples of these differences are the much higher pressure, the resulting high vapour density, a very low surface tension, and a low liquid viscosity. High pressure and low surface tension has a major effect on nucleate boiling ...

2002-07-01

88

Process feasibility study in support of silicon material, Task I. Quarterly technical progress report (XVIII), December 1, 1979-February 29, 1980  

Energy Technology Data Exchange (ETDEWEB)

Analyses of process system properties were continued for important chemical materials involved in the several processes under consideration for semiconductor and solar cell grade silicon production. Major activities were devoted to physical, thermodynamic and transport property data for silicon. Property data are reported for vapor pressure heat of vaporization, heat of sublimation, liquid heat capacity and solid heat capacity as a function of temperature to permit rapid usage in engineering. Chemical engineering analysis of the HSC process (Hemlock Semiconductor Corporation) for production of silicon was initiated. The process is based on hydrogen reduction of dichlorosilane (DCS) to produce the polysilicon. The chemical vapor deposition reaction for DCS is faster in rate than the conventional process route which utilizes trichlorosilane (TCS) as the silicon raw material. Status and progress are ...

1980-03-01

89

Experimental and theoretical studies on humidification-dehumidification-desalination  

Energy Technology Data Exchange (ETDEWEB)

The shortage of fresh water is increasing at alarming levels, even in temperate zones. Desalination of brackish and seawater is being considered as a solution to growing water demands. Seawater desalination can be accomplished through reverse osmosis, vapor compression, vapor absorption and thermally driven systems. The most suitable process for large-scale desalination plants is successive brine evaporation-condensation with intermediate heat recovery. However, higher process efficiency could be achieved. The use of low temperature heat sources in seawater desalination requires an efficient method of evaporation and condensation at relatively low vapor pressures. This could be achieved in a humidification-dehumidification process using circulated air to enhance evaporation of water. Simulation models, however, neglect either the heat of evaporation or the changes in air and water properties within ...

2006-07-01

90

Adsorption of ethylene on graphitized thermal carbon black and in slit pores: a computer simulation study.  

Science.gov (United States)

In this paper, we studied vapor-liquid equilibria (VLE) and adsorption of ethylene on graphitized thermal carbon black and in slit pores whose walls are composed of graphene layers. Simple models of a one-center Lennard-Jones (LJ) potential and a two-center united atom (UA)-LJ potential are investigated to study the impact of the choice of potential models in the description of VLE and adsorption behavior. Here, we used a Monte Carlo simulation method with grand canonical Monte Carlo (GCMC) and Gibbs ensemble Monte Carlo ensembles. The one-center potential model cannot describe adequately the VLE over the practical range of temperature from the triple point to the critical point. On the other hand, the two-center potential model (Wick et al. J. Phys. Chem. B 2000, 104, 8008-8016) performs well in the description of VLE (saturated vapor and liquid densities and vapor pressure) over the wide range of ...

2004-08-17

91

Development of a method for xenon determination in the microstructure of high burn-up nuclear fuel[Dissertation 17527  

Energy Technology Data Exchange (ETDEWEB)

In nuclear fuel, in approximately one quarter of the fissions, one of the two formed fission products is gaseous. These are mainly the noble gases xenon and krypton with isotopes of xenon contributing up to 90% of the product gases. These noble fission gases do not combine with other species, and have a low solubility in the normally used uranium oxide matrix. They can be dissolved in the fuel matrix or precipitate in nanometer-sized bubbles within the fuel grain, in micrometer-sized bubbles at the grain boundaries, and a fraction also precipitates in fuel pores, coming from fuel fabrication. A fraction of the gas can also be released into the plenum of the fuel rod. With increasing fission, and therefore burn-up, the ceramic fuel material experiences a transformation of its structure in the 'cooler' rim region of the fuel. A subdivision occurs of the original fuel grains of few microns size into thousands of small grains of sub-micron sizes. ...

2008-07-01

92

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia  

Energy Technology Data Exchange (ETDEWEB)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic compositions of the waters ({sup 87}Sr/{sup 86}Sr = 0.7041-0.7172) ...

2005-04-01

93

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia  

International Nuclear Information System (INIS)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic compositions of the waters ("8"7Sr/"8"6Sr = 0.7041-0.7172) are ...

2005-04-01

94

Deuterium isotope effect on molar heat capacities and apparent molar heat capacities in dilute aqueous solutions: A multi-channel heat-flow microcalorimeter study  

International Nuclear Information System (INIS)

The molar heat capacities of chloroform, dichloromethane, methanol, acetonitrile, acetone, dimethyl sulfoxide, benzene, dimethylformamide, toluene, and cyclohexane, as well as their deuterated isotopologues, were measured using a multi-channel heat conduction TAM (Thermal Activity Monitor) III microcalorimeter. In addition, the apparent molar heat capacities of some of the associated dilute aqueous solutions (0.0039 i < 0.0210) were also measured. A temperature drop method from (298.15 to 297.15) K at 0.1 MPa was employed. The corresponding heat capacities were determined from the integration of the measured heat flow. The heat capacity results are shown to be in good to very good agreement with the available literature values. In addition, good correlations were obtained for the effect of isotopic substitution on both molar heat capacity and apparent molar heat capacity in aqueous solutions. These correlations should be useful in the prediction of the molar ...

2008-11-01

95

Opto-acoustic recanilization delivery system  

Energy Technology Data Exchange (ETDEWEB)

Fiber delivered laser pulses emulsify thrombus by mechanical stresses that include a combination of pressure, tension and shear stress. Laser radiation is delivered to the locality of a thrombus and the radiation is absorbed by blood, blood dot, or other present materials. The combination of a leading pressure wave and subsequent vapor bubble cause efficient, emulsification of thrombus. Operating the laser in a low average power mode alleviates potential thermal complications. The laser is operated in a high repetition rate mode to take advantage of ultrasound frequency effects of thrombus dissolution as well as to decrease the total procedure time. Specific parameter ranges for operation are described. The device includes optical fibers surrounding a lumen intended for flow of a cooling agent. The fibers may be arranged concentrically around the lumen to deliver radiation and heat over as large an area as possible. An ...

2002-01-01

96

Experimental study on the flow boiling heat transfer enhancement and pressure drop due to the bubble behavior restricted by a screen sheet; Kanaami ni yoru kiho kyodo seigen ni tomonau futtoryu dennetsu sokushin to ryudo sonshitsu ni kansuru jikkenteki kenkyu  

Energy Technology Data Exchange (ETDEWEB)

A unique method, previously proposed by the author, was applied to the heat transfer augmentation in the flow boiling field. In this method a screen sheet was put on the horizontal heated surface where bubble nucleation occurred. Generated vapor bubbles were trapped between the screen and the wall, became flat and moved along the surface. This restricted bubble behavior caused the heat transfer enhancement. Three types of the screen were tested in the present experiment and the effect of the screen was investigated on the heat transfer and two-phase flow characteristics. In two cases of them, the screen was displaced upward by the bubble nucleation. Compared with the ordinary flow boiling case, heat transfer was enhanced by a factor of 1.2 to 6 within the present experimental range. By using a simple flow model, it was made clear that the effect of the height of the displaced screen was important to evaluate the increase in pressure drop. ...

2000-03-25

97

Semi-empirical calculation of air-broadened half-widths and air pressure-induced frequency shifts of water-vapor absorption lines  

International Nuclear Information System (INIS)

This paper describes a semi-empirical calculation of the air-broadened half-widths and the air pressure-induced frequency shifts for the H_2"1"6O isotopologue. This semi-empirical calculation is based on fits of several recent high-quality measurements and theoretical calculations to the first-order terms in the expansion of the complex Robert-Bonamy (CRB) equations, which yields a second- and first-order polynomial function of the differences in the upper- and lower-state vibrational quantum numbers for the half-width and line shift, respectively. The aim of this work was to obtain a complete set of air-broadened half-widths and air pressure-induced frequency shifts for transitions of H_2"1"6O present in the HITRAN database from microwave to the visible in order to supplement the observed and calculated values. For around 700 sets of rotational quantum numbers (J"'K_a"'K_c"'<-J"''K_a"''K_c"''), semi-empirical coefficients describing the ...

2005-12-01

98

Saddle field fast atom beam source: A new low pressure plasma nitriding method for a alloy Ti-6Al-4V  

Energy Technology Data Exchange (ETDEWEB)

Ti and its alloys (Ti-6Al-4V) have been used in different engineering applications due to their several outstanding properties. Nevertheless, their use in practical applications is limited in many cases due to their poor tribological property. Researches are ongoing on surface modification of Ti based materials by different plasma and ion based techniques to overcome this problem. However, the conventional plasma nitriding techniques have several problems such as formation of an arc, increased possibility of surface contamination due to a comparatively higher operating pressure, production of a very thin nitrided layer after a long processing time, etc. In this present work, the possibility of a new low-pressure plasma nitriding process using a Plasma Enhanced Chemical Vapor Deposition (PECVD) based saddle field fast atom beam source on a Ti-6Al-4V alloy sample is investigated. Plasma nitriding was carried out at 900 deg. C ...

2006-09-25

99

Saddle field fast atom beam source: A new low pressure plasma nitriding method for a alloy Ti-6Al-4V  

International Nuclear Information System (INIS)

Ti and its alloys (Ti-6Al-4V) have been used in different engineering applications due to their several outstanding properties. Nevertheless, their use in practical applications is limited in many cases due to their poor tribological property. Researches are ongoing on surface modification of Ti based materials by different plasma and ion based techniques to overcome this problem. However, the conventional plasma nitriding techniques have several problems such as formation of an arc, increased possibility of surface contamination due to a comparatively higher operating pressure, production of a very thin nitrided layer after a long processing time, etc. In this present work, the possibility of a new low-pressure plasma nitriding process using a Plasma Enhanced Chemical Vapor Deposition (PECVD) based saddle field fast atom beam source on a Ti-6Al-4V alloy sample is investigated. Plasma nitriding was carried out at 900 deg. C ...

2006-09-25

100

Study of the thermal plasma etching at atmospheric pressure on silica rods  

International Nuclear Information System (INIS)

Etching of SiO_2 rods has been obtained with a dc torch with argon as the process gas in an air environment at atmospheric pressure; the high temperature of the plasma jet causes vaporization of the exposed area. The apparatus and torch operative parameters have been set up to obtain a depth etch rate of up to 0.6 mm min"-"1 corresponding to 0.826 g min"-"1. An enthalpy probe has been employed to monitor the plasma conditions before the thermal plasma etching process and from the experimental etch rate a surface rod temperature of T_s_u_r = 2057 K has been derived. Etching has been obtained with uniformity over the entire exposed area with peak to peak differences below 1%. The plasma to rod heat transfer has been simulated using a commercial CFD code Fluent (copyright). The model consists of a non-steady two-dimensional simulation for a compressible turbulent fluid, with an adapted grid calculation. Boundary conditions have been set out using ...

2004-04-21

101

Silicon nitride films deposited from SiH sub 2 Cl sub 2 -NH sub 3 by low pressure chemical vapor deposition: kinetics, thermodynamics, composition and structure  

Energy Technology Data Exchange (ETDEWEB)

The growth of stoichiometric and non-stoichiometric silicon nitride films was studied experimentally on 100 mm silicon wafers by batch depositions from the dichlorosilane (SiH{sub 2}Cl{sub 2})-ammonia (NH{sub 3}) system in a hot-wall horizontal low pressure chemical vapor deposition (LPCVD) reactor. The growth kinetics were discussed in terms of the Langmuir adsorption isotherm. The kinetic parameters were determined by comparing the experimental data with a one-dimensional simulation model. The decomposition of NH{sub 3} at high temperatures was included in the simulation procedure. When the SiH{sub 2}Cl{sub 2}:NH{sub 3} ratios were greater than 1.5, a quantity higher than the thermodynamic critical values above which Si-rich nitride films begin to deposit, various SiN{sub x} films with x < 4/3 were obtained. The composition of the SiN{sub x} films was found to vary along the LPCVD reactor. The film stoichiometry was examined by Rutherford ...

1992-06-15

102

Pressure and impulse scaling methods for wall impact in ICF (inertial confinement fusion)  

Energy Technology Data Exchange (ETDEWEB)

The design of the first structural wall (FSW) in an inertial confinement fusion (ICF) reactor requires some knowledge of the expected wall loading produced by x-ray and neutron deposition; specifically in the High Yield Lithium Injection Fusion Energy (HYLIFE) reactor, wall loading results from two sources -- gas shock and liquid impact. Gas shock is derived from x-ray deposition in the thin layers of exposed blanket material, producing ionized vapor, which will generate gas shock on the FSW. Liquid impact, on the other hand, results from the acceleration of liquid blanket material by two possible forces -- the drag from vapor expansion through the blanket material and the neutron-induced isochoric disassembly process. Both impacts, however, are coupled by the interaction of hot gas expanding through the liquid blanket. This paper discusses scaling methods for estimating pressure and impulse on the HYLIFE FSW from these ...

1990-01-01

103

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn  

CERN Document Server

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn

1987-01-01

106

Cyclotron Production of Radioisotopes  

International Science & Technology Center (ISTC)

Production of Radioactive Isotopes in Republic of Kasakhstan.

108
109

Measurements and evaluations of nuclear data on actinide isotopes  

International Nuclear Information System (INIS)

The measurements of the nuclear decay of actinide isotopes and the evaluation of the radioactive properties of nuclide with the mass 242 is discussed in this paper.

1979-08-01

110

Analysis of advanced direct-injection diesel engine development strategies. Final report, 1 July 1995--9 July 1998  

Energy Technology Data Exchange (ETDEWEB)

The methodology of achieving a high power density (HPD, or brake mean effective pressure) direct-injection Diesel engine has been studied, which is directed to using high fuel/air ratio, high-speed and ceramic engine components. Among the main thrust to achieve these engine changes for an advanced Diesel engine is the design of a high injection pressure (HIP) fuel system. During the course of the present study, two Cummins 903 engines mated with a Rutger-built HIP were employed to investigate the engine response to HIP and in-cylinder processes by using the Rutgers high-speed infrared (IR) spectral digital imaging system. Five separate technical publications were prepared to report results obtained from the study. The main findings include: The HIP system permits engine operation at an air/fuel ratio of as rich as 18 to 1 with smoke emission not worse than with the conventional mechanical (low pressure) injection system; A ...

1998-08-01

111

Natural radiation exposure occurring at handling, storage and disposal of natural radioactive materials; Strahlenbelastung bei Umgang, Lagerung und Abfallhaltung von natuerlicher Radioaktivitaet in Rohstoffen  

Energy Technology Data Exchange (ETDEWEB)

Processing certain raw materials containing natural radioactive isotopes (e.g. U-238, Th-232 or K- 40) into products such as glas, abrasives, grinding materials or electrodes used for gasshielded tungsten-arc welding also leads to certain concentrations of industrial waste containing natural radioactive materials. Such industrial waste does not necessarily contain natural radioactive substances in concentrations exceeding the highest possible levels but nevertheless in significantly measurable quantities. This, however, frequently leads to confusion bordering on irritation by entities processing such substances as well as the general public, since they tend to believe natural radioactive substances in unobjectable concentration to cause similar or identical - health - consequences as man made radioactive substances in detrimental concentration. Radioactive materials may be incorporated intentionally or unintentionally into the product as main or additional ...

2009-07-01

112

Natural radiation exposure occurring at handling, storage and disposal of natural radioactive materials  

International Nuclear Information System (INIS)

Processing certain raw materials containing natural radioactive isotopes (e.g. U-238, Th-232 or K- 40) into products such as glas, abrasives, grinding materials or electrodes used for gasshielded tungsten-arc welding also leads to certain concentrations of industrial waste containing natural radioactive materials. Such industrial waste does not necessarily contain natural radioactive substances in concentrations exceeding the highest possible levels but nevertheless in significantly measurable quantities. This, however, frequently leads to confusion bordering on irritation by entities processing such substances as well as the general public, since they tend to believe natural radioactive substances in unobjectable concentration to cause similar or identical - health - consequences as man made radioactive substances in detrimental concentration. Radioactive materials may be incorporated intentionally or unintentionally into the product as main or additional ...

2009-09-21

113

Modelling of multifrequency IRMPD for laser isotope separation  

International Nuclear Information System (INIS)

The process of infrared multiple photon dissociation (IRMPD) of molecules is of great fundamental importance and has practical significance, such as isotope separation etc. Unfortunately, a clear insight into the process has been hindered by the bewildering array of important variables affecting MPD. The dissociation probability #gamma#(#phi#) i.e. the yield has been found to be a sensitive function of laser fluence #phi# along with numerous other parameters like laser frequency, gas pressure etc. We have shown that in single frequency IRMPD an accurate quantitative characterization of the dissociation probability can be adequately expressed by a 'power law' model with two fitting parameters namely critical fluence, #phi#c and multi photon order, m. This model was exploited in analysing our MPD results on various systems. However, the small isotope shift encountered in heavy elements and the sticking phenomenon observed in ...

2002-12-01

114

Chemistry of transuranium elements and compounds  

International Nuclear Information System (INIS)

Studies are made in this program to enhance our understanding of the role of 5f electrons in chemical bonding. Most of our studies on the macroscopic scale emphasize certain isotopes available from the National Transplutonium Production Program centered at HFIR/TRU -namely, _9_6"2"4"8Cm, _9_7"2"4"9Bk, _9_8"2"4"9Cf, _9_9"2"5"3Es, and _9_9"2"5"4Es. Particular classes of compounds, such as hydrides, chalcogenides, and pnictides are often selected for study on the basis of their utility in bringing out significant chemical differences between the lanthanides and the actinides. High temperature/high pressure experiments on actinide metals and compounds reveal characteristics about the degree of 5f electron localization as a function of atomic number in the series. Magnetic properties of metals and compounds are investigated using ultra-sensitive methods and hydration numbers of ions in solution are investigated by neutron scattering at HFIR. As a ...

1986-05-01

118

Zero-G two phase flow regime modeling in adiabatic flow  

Energy Technology Data Exchange (ETDEWEB)

Two-phase flow, thermal management systems are currently being considered as an alternative to conventional, single phase systems for future space missions because of their potential to reduce overall system mass, size, and pumping power requirements. Knowledge of flow regime transitions, heat transfer characteristics, and pressure drop correlations is necessary to design and develop two-phase systems. This work is concerned with microgravity, two-phase flow regime analysis. The data come from a recent sets of experiments. The experiments were funded by NASA Johnson Space Center (JSC) and conducted by NASA JSC with Texas A M University. The experiment was on loan to NASA JSC from Foster-Miller, Inc., who constructed it with funding from the Air Force Phillips Laboratory. The experiment used R12 as the working fluid. A Foster-Miller two phase pump was used to circulate the two phase mixture and allow separate measurements of the vapor and liquid ...

1993-01-15

119

Zero-G two phase flow regime modeling in adiabatic flow  

International Nuclear Information System (INIS)

Two-phase flow, thermal management systems are currently being considered as an alternative to conventional, single phase systems for future space missions because of their potential to reduce overall system mass, size, and pumping power requirements. Knowledge of flow regime transitions, heat transfer characteristics, and pressure drop correlations is necessary to design and develop two-phase systems. This work is concerned with microgravity, two-phase flow regime analysis. The data come from a recent sets of experiments. The experiments were funded by NASA Johnson Space Center (JSC) and conducted by NASA JSC with Texas A ampersand M University. The experiment was on loan to NASA JSC from Foster-Miller, Inc., who constructed it with funding from the Air Force Phillips Laboratory. The experiment used R12 as the working fluid. A Foster-Miller two phase pump was used to circulate the two phase mixture and allow separate measurements of the vapor ...

1993-01-10

120

Sorption mechanism of solvent vapors to coals; Sekitan eno yobai joki no shuchaku kiko no kaiseki  

Energy Technology Data Exchange (ETDEWEB)

With an objective to clarify the interactions between micropore structure of coal and solvent reagents, a sorption experiment was carried out under solvent saturated vapor pressure. Low-volatile bituminous coal, Pocahontas No. 3 coal, has the aromatic ring structure developed, and makes solvent more difficult to diffuse into coal, hence sorption amount is small. Methanol has permeated since its polarity is high. High-volatile bituminous coal, Illinois No. 6 coal, makes solvent penetrate easily, and the sorption amount was large with both of aromatic and polar solvents. Since brown coal, Beulah Zap coal, contains a large amount of oxygen, and hydrogen bonding is predominant, sorption amount of cyclohexane and benzene having no polarity is small. Methanol diffuses while releasing hydrogen bond due to its polarity, and its sorption amount is large. A double sorption model is available, which expresses the whole sorption amount as a sum of physical ...

1996-10-28

121

Post-CHF Heat Transfer characteristics in one rod bundle geometry  

Energy Technology Data Exchange (ETDEWEB)

In the present paper, experimental study of forced convection boiling were performed to investigate the post-CHF characteristics of a vertical annular channel with one heated rod and four spacer grids for new refrigerant R-134a. The experiments were conducted under outlet pressure of 11.6, 13, 16 and 20 bar, mass fluxes of 100-600 kg/m{sup 2}s, and inlet temperatures of 25-51 .deg. C. The parametric trend of the post-CHF data was well consistent with previous studies. The two phase flow regime in tube flow occurring downstream of the CHF has been called post-CHF, dispersed flow, liquid-deficient flow, mist flow and film boiling. This regime is characterized by a continuous vapor phase with discrete liquid drops and a non-wetted heated surface. This regime has a considerable importance in the areas of light water reactor(LWR) accident analysis and other film boiling applications. The post-CHF region occurs by design in heat exchangers operating ...

2006-07-01

122

Post-CHF Heat Transfer characteristics in one rod bundle geometry  

International Nuclear Information System (INIS)

In the present paper, experimental study of forced convection boiling were performed to investigate the post-CHF characteristics of a vertical annular channel with one heated rod and four spacer grids for new refrigerant R-134a. The experiments were conducted under outlet pressure of 11.6, 13, 16 and 20 bar, mass fluxes of 100-600 kg/m2s, and inlet temperatures of 25-51 .deg. C. The parametric trend of the post-CHF data was well consistent with previous studies. The two phase flow regime in tube flow occurring downstream of the CHF has been called post-CHF, dispersed flow, liquid-deficient flow, mist flow and film boiling. This regime is characterized by a continuous vapor phase with discrete liquid drops and a non-wetted heated surface. This regime has a considerable importance in the areas of light water reactor(LWR) accident analysis and other film boiling applications. The post-CHF region occurs by design in heat exchangers operating in the ...

2006-11-02

123

Photoluminescence linewidths in metalorganic vapor phase epitaxially grown ordered and disordered InAlGaP alloys  

Science.gov (United States)

The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a ...

1992-12-01

124

Photoluminescence linewidths in metalorganic vapor phase epitaxially grown ordered and disordered InAlGaP alloys  

Energy Technology Data Exchange (ETDEWEB)

The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a ...

1992-12-01

125

Organometallic vapor phase epitaxial growth of (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P and its heterostructures  

International Nuclear Information System (INIS)

The (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P material system, lattice matched to GaAs substrates, is useful for visible laser diodes. Here, low pressure organometallic vapor phase epitaxial growth of Ga/sub 0.5/In/sub 0.5/P and (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P is examined. Epitaxial layers of bulk materials are characterized using photoluminescence, electroreflectance, Raman scattering spectroscopy, and surface morphology studies to determine lattice match and optimum growth conditions. Lattice matching at the growth temperature produces featureless growth surfaces, while lattice matching at room temperatures results in minimum photoluminescence linewidth but cracked surface due to tensile strain during growth. Raman scattering spectra of the quaternary reveal a three-mode structure, with spectral peaks due to GaP-like, in P-like, and AIP-like LO phonons. Additionally, (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P/Ga/sub 0.5/In/sub ...

126

Organometallic vapor phase epitaxial growth of (Al/sub x/Ga/sub 1-x/)/sub 0. 5/In/sub 0. 5/P and its heterostructures  

Science.gov (United States)

The (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P material system, lattice matched to GaAs substrates, is useful for visible laser diodes. Here, low pressure organometallic vapor phase epitaxial growth of Ga/sub 0.5/In/sub 0.5/P and (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P is examined. Epitaxial layers of bulk materials are characterized using photoluminescence, electroreflectance, Raman scattering spectroscopy, and surface morphology studies to determine lattice match and optimum growth conditions. Lattice matching at the growth temperature produces featureless growth surfaces, while lattice matching at room temperatures results in minimum photoluminescence linewidth but cracked surface due to tensile strain during growth. Raman scattering spectra of the quaternary reveal a three-mode structure, with spectral peaks due to GaP-like, in P-like, and AIP-like LO phonons. Additionally, (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P/Ga/sub 0.5/In/sub ...

1988-09-01

127

Fractionation of isotopes of alkali metals and alkaline earth metals in ion exchange chromatography  

International Nuclear Information System (INIS)

Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ...

128

A microscopic description of neutron-rich lithium isotopes  

International Nuclear Information System (INIS)

A unified calculation of neutron-rich isotopes in lithium is performed using the hyperspherical basis in which the underlying symmetry of each isotope exhibits a simple structure. The variation of the binding energy as a function of mass number is qualitatively reproduced, and the asymptotic of radial distribution of each isotope decreases exponentially. The form factors of the lithium isotopes are calculated and display diffraction minima. 27 refs., 3 figs., 3 tabs.

129

Quantum molecular dynamics and molecular interactions studied by NMR and INS[Nuclear magnetic resonance; Proton tunnelling; Hydrogen bond  

Energy Technology Data Exchange (ETDEWEB)

The wavefunction of a particle extends into the classically forbidden barrier region of the potential energy surface. The consequence of this partial delocalisation is the phenomenon of quantum tunnelling, an effect which enables a particle to penetrate a potential barrier of magnitude greater than the energy of the particle. The tunnelling probability is an exponential function of the particle mass. The effect is therefore an important contribution to the behaviour of light atoms, in particular the proton. The hydrogen bond has long been appreciated to be an essential component of many biological and chemical systems, and the proton transfer reaction in the hydrogen bond is fundamental to many of these processes. The proton behaviour in the hydrogen bonds of benzoic acid, acetylacetone and calix-4-arene has been studied. A variety of techniques, both experimental and computational, were adopted for the study of the three hydrogen bonded systems. The complementary spectroscopic ...

2002-07-01

130

Theoretical approach to initial growth kinetics of GaN on GaN(001)  

British Library Electronic Table of Contents (United Kingdom)

We carried out theoretical analyses based on ab initio calculations incorporates in which free energy of the vapor phase is incorporated in order to determine the initial growth kinetics of c-GaN on GaN(001)-(4x1). The feasibility of the theoretical approach had been confirmed by calculations of Ga adsorption-desorption transition temperature and transition beam equivalent pressures on the GaAs(001)-(4x2)b2 surface in our previous work [Y. Kangawa, T. Ito, A. Taguchi, K. Shiraishi, T. Ohachi, Surf. Sci. 493 (2001) 178]. The results of calculations suggest that no Ga adsorption occurs on the initial surface under typical growth conditions but that a Ga adsorption site appears after N adsorption on GaN(001)-(4x1). That is, in the initial growth stage of c-GaN on GaN(001)-(4x1), a N-adsorbed ...

2007-01-01

131

Superconducting A-15 Nb_3Ge films produced by reactive evaporation  

International Nuclear Information System (INIS)

The reactive evaporation process was successfully used to deposit films of the A-15 Nb_3Ge phase. This is the first report, to the best of our knowledge, illustrating the use of such processes for the deposition of A-15 compounds. In this process, niobium vapors from an electron-beam-heated evaporation source react with germane gas introduced into the vacuum chamber at low partial pressures (approximately 10"-"4 Torr) to produce Nb_3Ge deposits. The process variables studied were the deposition temperature, the niobium-to-germanium impingement ratio on the substrate and the plasma-enhanced deposition, in this case the activated reactive evaporation process. At low deposition temperatures (below 450"0C) the deposit is amorphous (or microcrystalline) and can be crystallized to the Nb_3Ge phase by heat treatment, e.g. at 850"0C for 1 h in vacuum. The ratio of niobium to germanium in the deposit can be varied by changing the process parameters. The ...

132

Sorption equilibrium and hydration studies of lysozyme: water activity and 360-MHz proton NMR measurement  

International Nuclear Information System (INIS)

An attempt to determine lysozyme hydration by employing a proton nuclear magnetic resonance (NMR) spin-echo technique and to correlated such measurements with the 20 "0C sorption equilibrium data is made. Determinations of specific site hydration for lysozyme, as well as proton NMR transverse relaxation rates for five different types of water populations in the lysozyme-water system, are presented over the whole range of lysozyme concentrations. The proton spin-echo NMR results are consistent with a three-component analysis of the sorption isotherm up to 70% water content, above which two additional water populations are identified by 360-MHz proton NMR spin-echoes. On the basis of the proton NMR results, a major component (III) of the lysozyme sorption isotherm is assigned to the water trapped between lysozyem molecules, whose relaxation rate is increased by diffusion barriers. The trapped water population dominates the relationship between the relative vapor ...

133

Production of negative ions by electron impact. Final report 1 May 81-31 Oct 82  

Science.gov (United States)

Proposed future space-based beam weapons systems will most probably require an intense neutral particle beam for effective operation across geomagnetic field lines. Such neutral beams can most efficiently be obtained by stripping excess electrons from negative ion beams. The objective of this work is to study the process of dissociative attachment of electrons. Specifically, to measure the cross sections for polar dissociation and dissociative attachment for production of H(-). It is suspected that these dissociative attachment cross sections for the production of H(-) from alkali hydrides are large. The insight gained from this study will be extremely helpful in the fabrication of high current density H(-) beam sources for use in the production of intense neutral hydrogen beams. A selection of alkali hydride molecules will be investigated in order to determine the largest cross sections for the production of H(-) by electron impact. The angular distribution of the H(-) ions will be ...

1982-10-01

134

Preliminary assessment of future refining impacts of the Clean Air Act Amendments of 1990  

Energy Technology Data Exchange (ETDEWEB)

A preliminary assessment of the future refining impacts of the Clean Air Act Amendments of 1990 has been performed with the Navy Mobility Fuels Forecasting Systems. The assessment suggests that gasoline reformulation costs in domestic coastal and near-coastal refining regions in the year 2000 could be 3.5 to 5.6 cents per gallon (in terms of 1989 currency). For heating value equivalent to one gallon of conventional gasoline, the regional total added costs (including reformulation costs) for reformulated gasoline could be 5.9 to 8.0 cents. In blending reformulated gasolines, the reduction of butane for lower Reid vapor pressure and the reduction of reformate for lower aromatics are generally compensated by increased percentages of alkylate and/or straight run naphthas. Relatively larger refinery process capacity additions are required for butane isomerization, alkylation, aromatics recovery, and distillate hydrotreating. 21 refs., 3 figs., 18 ...

1991-09-01

135

Numerical studies of an impingement-conditioned small direct-injection diesel engine  

Energy Technology Data Exchange (ETDEWEB)

Numerical studies are performed to identify an optimal range of geometric parameters in connection with the design of an impingement-conditioned small direct-injection diesel engine. The parametric studies were made in a pressure chamber with a circular protrusion on to which sprays are directed to impinge. Computational runs were made for 24 cases carefully chosen to allow examination of the effects on post-impingement spray characteristics of the following parameters: (a) the nozzle-plate distance and (b) the size and geometry pattern of the protrusion. An optimal range of these parameters has been identified through an analysis of the calculated results in terms of vapour concentration, the Sauter mean diameter of the wall spray and the dispersed wall spray volume. The results obtained also reveals that, by just changing the size of the impingement surface and the impingement distance, local fuel vaporization efficiency can be increased as ...

1999-07-01

136

Measures for reliability improvement of on-site power plant at steel works  

Energy Technology Data Exchange (ETDEWEB)

This report describes the arrangement and features of the Ogishima thermal power plant facilities, as well as activities being performed there for operation control, regular inspection and improvement in reliability. The power plant uses about 48 percent of the by-product gas as its fuel to supply about 81 percent of the required power. Operation of the No. 1 unit started in 1976. Currently, the plant has three units, each with an output of 125MW. Each unit consists of a natural circulation boiler with a maximum evaporation capacity of 410 ton/hour and a reheat regenerative condensing turbine with a main vapor pressure of 127 kg/cm/sup 2/G. Techniques used for water properties control and combustion control are also described. In the plant, convetional time management integrity techniques are now being replaced by state management integrity techniques that determines the deterioration tendency in separate sections of the facilities which are ...

1988-04-15

137

Investigation of the evaporation of rare earth chlorides in a LiCl-KCl molten salt  

International Nuclear Information System (INIS)

Uranium dendrites which were deposited at a solid cathode of an electrorefiner contained a certain amount of salts. These salts should be removed for the recovery of pure metal using a cathode processor. In the uranium deposits from the electrorefining process, there are actinide chlorides and rare earth chlorides in addition to uranium chloride in the LiCl-KCl eutectic salt. The evaporation behaviors of the actinides and rare earth chlorides in the salts should be investigated for the removal of salts in the deposits. Experiments on the salt evaporation of rare earth chlorides in a LiCl-KCl eutectic salt were carried out. Though the vapor pressures of the rare earth chlorides were lower than those of the LiCl and KCl, the rare earth chlorides were co-evaporized with the LiCl-KCl eutectic salt. The Hertz-Langmuir relation was applied for this evaporation, and also the evaporation rates of the salt were obtained. The co-evaporation of the rare ...

2011-02-01

138

Influence of high energy electron irradiation on the characteristics of polysilicon thin film transistors  

Energy Technology Data Exchange (ETDEWEB)

The influence of high energy electron (23 MeV) irradiation on the electrical characteristics of p-channel polysilicon thin film transistors (PSTFTs) was studied. The channel 220 nm thick LPCVD (low pressure chemical vapor deposition) deposited polysilicon layer was phosphorus doped by ion implantation. A 45 nm thick, thermally grown, SiO{sub 2} layer served as gate dielectric. A self-alignment technology for boron doping of the source and drain regions was used. 200 nm thick polysilicon film was deposited as a gate electrode. The obtained p-channel PSTFTs were irradiated with different high energy electron doses. Leakage currents through the gate oxide and transfer characteristics of the transistors were measured. A software model describing the field enhancement and the non-uniform current distribution at textured polysilicon/oxide interface was developed. In order to assess the irradiation-stimulated changes of gate oxide parameters the gate ...

2006-08-15

139

Influence of high energy electron irradiation on the characteristics of polysilicon thin film transistors  

International Nuclear Information System (INIS)

The influence of high energy electron (23 MeV) irradiation on the electrical characteristics of p-channel polysilicon thin film transistors (PSTFTs) was studied. The channel 220 nm thick LPCVD (low pressure chemical vapor deposition) deposited polysilicon layer was phosphorus doped by ion implantation. A 45 nm thick, thermally grown, SiO_2 layer served as gate dielectric. A self-alignment technology for boron doping of the source and drain regions was used. 200 nm thick polysilicon film was deposited as a gate electrode. The obtained p-channel PSTFTs were irradiated with different high energy electron doses. Leakage currents through the gate oxide and transfer characteristics of the transistors were measured. A software model describing the field enhancement and the non-uniform current distribution at textured polysilicon/oxide interface was developed. In order to assess the irradiation-stimulated changes of gate oxide parameters the gate oxide ...

2006-08-01

140

Effect of water activity on the lipase catalyzed esterification of geraniol in ionic liquid [bmim]PF6.  

Science.gov (United States)

Enzymatic reactions in non-aqueous media have been shown to be effective in carrying out chemical transformation where the reactants are insoluble in water or water is a byproduct limiting conversion. Ionic liquids, liquid organic salts with infinitesimal vapor pressure, are potentially useful alternatives to organic solvents. It is known that the thermodynamic water activity is an important variable affecting the activity of enzymes in non-aqueous solvents. This study investigated the influence of water activity on the esterification of geraniol with acetic acid in ionic liquid [bmim]PF6 catalyzed by immobilized Candida antarctica lipase B. The conversion of geraniol in [bmim]PF6 was significant although the reaction rate was slower than in organic solvents. The profile of initial reaction rate-water activity was determined experimentally, and differed from the data reported for other non-aqueous solvents. A maximum in the initial reaction ...

2006-02-01

141

Chemical process equipment for Hitachi. ; Featured equipment  

Energy Technology Data Exchange (ETDEWEB)

The present article describes the specialities in various chemical process equipment fabricated by Hitachi. It introduces the thin-film evaporator which heats, vaporizes and concentrates high viscosity fluid and slurry under thin-film conditions, the centrifugal extractor which uses a high speed rotating rotor to separate two kinds of immiscible liquids effectively in counter current contact conditions under a gravitational force ranging from 2,000G to 4,500G, the process gas boiler and heat pipe equipment which recovers exhausted heat effectively from various plants, the furnace and quench systems which are applied to olefin plants, EDC cracking and steam reforming, and the equipment which has been supplied to chemical plants operated under severe conditions, such as high temperature, high pressure and corrosive atmosphere. It was demonstrated that these technologies and know-hows accumulated from Hitachi's extensive experiences in ...

1993-01-01

142

Characteristics of ionic liquid-based electrolytes for chip type aluminum electrolytic capacitors  

Energy Technology Data Exchange (ETDEWEB)

Since ionic liquids (ILs) possess several attractive properties, including chemical and thermal stability, nonflammability, high ionic conductivity, and negligible vapor pressure, a new electrolyte system based on ILs has been proposed for chip type aluminum electrolytic capacitors. Four ILs based on imidazolium/pyrrolidinium cations and maleate/phthalate anions have been synthesized and their thermal stabilities have been examined. The 25wt.% solutions of the four ILs in gamma-butyrolactone (GBL) solvent were prepared as electrolytes of chip type aluminum electrolytic capacitors. The conductivity, sparking voltage and thermal stability of these electrolytes have been systematically investigated. The results revealed that the four IL-based electrolytes exhibited high conductivity. Furthermore, the conductivity of maleate anion-based electrolytes is higher than that of phthalate anion-based electrolytes, whereas the high-temperature durability ...

2006-06-19

143

AlGaInP single quantum well laser diodes  

Energy Technology Data Exchange (ETDEWEB)

The properties and low pressure organometallic vapor phase epitaxy of Ga{sub x}In{sub 1{minus}x}P/(AlGa){sub 0.5}In{sub 0.5}P quantum well (QW) laser diode heterostructures with Al{sub 0.5}In{sub 0.5}P cladding layers, and having wavelength 614 < {lambda} < 690 nm, are described. At longer wavelengths ({lambda} > 660 nm), threshold current densities under 200 A/cm{sup 2} and efficiencies greater than 75% result from a biaxially-compressed GaInP QW active region. Although short wavelength laser performance is diminished by the poor electron confinement afforded by AlGaInP heterostructures, good 630 nm band performance, and extension into the 610 nm band, is achieved with strained, single QW active regions.

1994-12-31

144

Behavior of Aqueous Electrolytes in Steam Cycles - The Final Report on the Solubility and Volatility of copper(I) and Copper(II) Oxides  

Energy Technology Data Exchange (ETDEWEB)

Measurements were completed on the solubility of cupric and cuprous oxides in liquid water and steam at controlled pH conditions from 25 to 400 C (77 to 752 F). The results of this study have been combined with those reported from this laboratory in two previous EPRI reports to provide a complete description of the solubility of these oxides and the speciation of copper dissolved in liquid water and steam as a function of oxidation state, temperature, pH, and in the case of steam, pressure. These constitute the first set of reliable data for cuprous oxide solubility over this range of conditions. For the more intensively studied CuO case, agreement was found between our results and those of previous studies of its solubility in steam, whereas only partial agreement was evident for its solubility in liquid water. For both oxides this disagreement often amounted to orders of magnitude. The solubility of cuprous oxide is somewhat lower than that of CuO at ambient ...

2004-05-01

145

State of the Art Laser Induced Breakdown Spectroscopy  

International Nuclear Information System (INIS)

Methods currently being used or developed for the elemental analysis of materials are chemical analysis, non-destructive inspection and calorimetry. The chemical analysis, which removes high-level radioactive elements through chemical treatments and then performs the quantitative analysis using the ICP-MS(Inductively Coupled Plasma - Mass Spectrometer) or the ID-MS(Isotope Dilution Mass Spectrometer), is recognized the most accurate. However, it requires a long, complex pre-treatment process in which a mass spectrometer could be contaminated. To solve this problem, a new method, which can be performed with high-level radioactivity and at high temperature, was desired. Such a method should also have the same accuracy as the chemical analysis, with a less possibility for instruments to be contaminated. In addition, as interests in the environment and the life quality are increased, a detailed analysis on the environmental impacts is also required. Satisfying all of ...

146

Electron-beam-plasma ion source as source of negative fluorine  

Energy Technology Data Exchange (ETDEWEB)

Radioactive ion beams (RIBs) of short-lived isotopes of fluorine are in demand for investigating astrophysical phenomena related to the hot CNO cycle and rp processes responsible for stellar nucleosynthesis. Since negative ion beams are required for injection into tandem electrostatic accelerators, such as the 25 MV tandem accelerator used for post acceleration of RIBs for the Holifield Radioactive Ion Beam Facility (HRIBF) research program at the Oak Ridge National Laboratory (ORNL), efficient, direct-formation F{sup -} ion sources are highly desirable for RIB applications involving this type of post-accelerator. We have conceived and evaluated a direct extraction F{sup -} source for potential RIB applications which is predicated on the reverse polarity operation of a positive electron-beam-plasma target/ion source (EBPTIS) while simultaneously feeding fluorine rich compounds and Cs vapor into the source. The source is found to operate in two ...

1997-11-01

147

Crystal growth of epitaxial CVD diamond using [sup 13]C isotope and characterization of dislocations by Raman spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

[sup 13]C epitaxial diamond films have been grown on [sup 12]C-type IIb diamond substrates doped with boron, using electron assisted chemical vapor deposition. The relation between etch pits to dislocations in [sup 13]C diamond film and the broadening of the first-order Raman peak was examined. The reactant gas was [sup 13]CH[sub 4] of > 99% purity. The substrate temperature was varied from 943 to 1300 C. The uneven surface morphology was confirmed by atomic force microscopy (AFM) and laser microscopy. From 943 to 1030 C, etch pit rows along left angle 100 right angle were observed. At 991 C, the etch pit density on a row was 3300 to 5000 pits/cm. The Ar[sup +] laser beam was focused on a transparent area near the row of etch pits, where the boron impurity of the substrate is less than several 10 ppm. The first-order Raman line of [sup 13]C epitaxial diamond film was broadened to 3.6-4.0 cm[sup -1]. The line broadening was 50-90% compared with that of the [sup ...

1993-03-01

148

A study of flow boiling phenomena using real time neutron radiography  

International Nuclear Information System (INIS)

The operation and safety of both fossil-fuel and nuclear power stations depend on adequate cooling of the thermal source involved. This is usually accomplished using liquid coolants that are forced through the high temperature regions by a pumping system; this fluid then transports the thermal energy to another section of the power station. However, fluids that undergo boiling during this process create vapor that can be detrimental, and influence safe operation of other system components. The behavior of this vapor, or void, as it is generated and transported through the system is critical in predicting the operational and safety performance. This study uses two advanced penetrating radiation techniques, Real Time Neutron Radiography (RTNR), and High Speed X-Ray Tomography (HS-XCT), to examine void generation and transport behavior in a flow boiling system. The geometries studied were tube side flow boiling in a cylindrical configuration, and ...

1346-01-01

149

Chromatographic separation of lithium isotopes by hydrous manganese(IV) oxide  

Energy Technology Data Exchange (ETDEWEB)

Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. The heavier lithium isotope was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was determined according to the method of Glueckauf from the elution curve and isotopic assays. The separation factor of {sup 6}Li{sup +} -{sup 7}Li{sup +} isotope pair fractionation was 1.018.

2001-06-01

150

On Sensitivity of Spectral Radiative Fluxes to Atmospheric Water Vapor in the 940 nm Region (Numerical Simulation)  

Energy Technology Data Exchange (ETDEWEB)

Water vapor is well known to be a critical component in many aspects of atmospheric research, such as radiative transfer and cloud and aerosol processes. This requires both improved measurements of the columnar water vapor and its profiles in the atmosphere in a wide range of conditions, and adjustment of water vapor parameterizations in radiation codes including the perfection of spectroscopic parameters. In this paper we will present the results of comparison of our calculations and downward solar fluxes measured with Rotating Shadowband Spectroradiometer under conditions of horizontally homogeneous clouds. We also will discuss the sensitivity of atmospheric radiation characteristics to variations of water vapor in the band 940 nm: these results may be useful for development of new methods of retrieval of the total column water vapor content (WVC) in the atmosphere from data of ...

2005-03-18

151

Priorities for human nutrition research using stable isotopes in India  

International Nuclear Information System (INIS)

In this paper, an attempt is made to outline the priority areas for research in human nutrition in India that could be tackled by appropriate application of stable isotope technology. 10 refs.

1989-06-06

153

GAMMA SPECTRA AND PERIODS OF FOUR ODD-A ISOTOPES OF TUNGSTEN AND TANTALUM  

Science.gov (United States)

The gamma spectra and lifetimes of the Ta and W isotopes havimg mass numbers 173, 175, 177, and 179 are determined. (T.F.H.)

1963-06-01

154

A setup for high-resolution isotope shift measurements on unstable lithium isotopes  

Energy Technology Data Exchange (ETDEWEB)

We present a laser spectroscopic approach for measuring the charge radius of the halo nucleus {sup 11}Li and report on recent progress in the development of the experimental apparatus.

2003-05-01

155

Study on the separation characteristics of tritiated water vapor adsorption.  

Science.gov (United States)

In order to reduce the air concentration of (sup 3)H in the reactor buiIding of Wolsung Heavy Water Reactor, a computer code for estimation of adsorption behavior was programmed based on an equation derived for analysis of water vapor adsorption, and a ba...

1991-01-01

156

Meteorologial Techniques  

Science.gov (United States)

... 2-93 An Atmospheric Particle Emits Electromagnetic ... atmospheric water vapor produces a hydrometeor. ... subject to wind movement (either blowing ...

2003-06-13

157

Thermal/hydraulic tests of tube supports in a multi-tube steam generator model  

International Nuclear Information System (INIS)

Tube supports used in the tube bundles of PWR steam generators have consisted of mechanical devices located at intervals along the tube bundle. The presence of tube supports creates regions of restricted flow with altered flow patterns and increased pressure drop. An additional and very important effect is also the possibility of local complete vaporization or dryout occurring in the tube/support flow passage and crevices. The thermal/hydraulic conditions at which dryout occurs are of particular interest because of the possibility of the deposition of dissolved solids with the occurrence of dryout. As long term build-up of solid deposition could have a deleterious effect, knowledge of the conditions at which dryout occurs would possibly provide a means to avoid this build-up. A test program, sponsored by the Steam Generator Project Office of the Electric Power Research Institute, was conducted to determine the thermal/hydraulic conditions at ...

1985-03-01

158

Study of the effect of noncondensable gas on heat transfer phenomena in horizontal steam generator of pactel facility with CATHARE2 V1.5a  

International Nuclear Information System (INIS)

Lappeenranta University of Technology (LTKK) and VTT Energy carried out a series of preliminary tests in 1999 to study the behavior of noncondensable (NC) gases in VVER geometry. The tests aimed at studying the effect of NC gases on system thermal-hydraulics and on heat transfer in a horizontal steam generator (HSG). The system behavior can be affected by hydrogen produced in the core in case of a severe accident, by nitrogen from hydro-accumulators released into the primary circuit in case of a loss-of-coolant accident (LOCA) and more generally by any NC gas in all cases where cooling is ensured by natural circulation. A secondary objective of the tests - the first series of tests ever performed with NC gas with PACTEL - was to find out, if the instrumentation of PACTEL was adequate for this type of tests and if it was functioning properly. This paper presents the measured and calculated (CATHARE code version V15a mod 2.1) results of the test NCg-l. It was carried out in natural ...

2001-03-20

159

Neutron scattering studies of mixed-valence semiconductors  

Energy Technology Data Exchange (ETDEWEB)

Neutron scattering experiments on the mixed-valence (MV) compounds SmB{sub 6} are reported. The inelastic magnetic response of SmB{sub 6} at T = 2 K, measured on a double-isotope single crystal,displays a strongly damped peak at 35 meV corresponding to the inter multiplet transition of Sm{sup 2+}. At lower energies ( h.{omega} {approx_equal} 14 meV), a narrow magnetic excitation is observed, with remarkable scattering-vector and temperature dependences of its intensity. This novel feature is discussed in terms of recent theoretical works describing the formation of an anisotropic local bound state in semiconducting MV materials. If the average samarium valence is decreased by substituting La for Sm, a peak is found to appear at high energies. The elastic magnetic form factor of SmB{sub 6} was determined using polarised neutrons and no significant difference is observed in its Q-dependence with respect to that of pure divalent samarium. This surprising behaviour is ...

1994-12-31

160

Law project adopted by the Senate and authorizing the ratification of the additional protocol to the agreement between France, the European atomic energy community and the international atomic energy agency relative to the application of warranties in France; Projet de loi adopte par le Senat autorisant la ratification du protocole additionnel a l'accord entre la France, la Communaute europeenne de l'energie atomique et l'Agence internationale de l'energie atomique relatif a l'application de garanties en Franc  

Energy Technology Data Exchange (ETDEWEB)

This project of law concerns an additional protocol to the agreement of warranties signed on September 22, 1998 between France, the European atomic energy community and the IAEA. This agreement concerns the declaration of all information relative to the R and D activities linked with the fuel cycle and involving the cooperation with a foreign country non endowed with nuclear weapons. These information include the trade and processing of nuclear and non-nuclear materials and equipments devoted to nuclear reactors (pressure vessels, fuel loading/unloading systems, control rods, force and zirconium tubes, primary coolant pumps, deuterium and heavy water, nuclear-grade graphite), to fuel reprocessing plants, to isotope separation plants (gaseous diffusion, laser enrichment, plasma separation, electromagnetic enrichment), to heavy water and deuterium production plants, and to uranium conversion plants. (J.S.)

2002-10-01

161

Hydrogen trapping by yttrium in low temperature lithium  

Energy Technology Data Exchange (ETDEWEB)

A test to determine the lithium compatibility and impurity gettering capabilities of various materials including yttrium was performed in Beryllium-7 Experimental Lithium (7BELL) at 270/sup 0/C. Yttrium coupons were exposed in liquid lithium for a total of 3,718 hours. X-ray diffraction and bulk chemical analysis data indicated that yttrium absorbs hydrogen from liquid lithium at 270/sup 0/C and transforms to yttrium dihydride (YH/sub 2/). The transformation of yttrium to YH/sub 2/ resulted in embrittlement of the coupons and subsequent fragmentation to small pieces. Additional analysis, based on the equilibrium hydrogen pressures for the transition of yttrium to YH/sub 2/, and Sievert's relationship for hydrogen in equilibrium with hydrogen in lithium, indicates that the temperature of yttrium cannot exceed 280/sup 0/C to control the hydrogen concentration in lithium at below 1 wt ppm. It is concluded in general that yttrium in sponge form is a good ...

1984-05-01

162

Characterization of spent fuel approved testing material: ATM-106  

Energy Technology Data Exchange (ETDEWEB)

The characterization data obtained to date are described for Approved Testing Material (ATM)-106 spent fuel from Assembly BT03 of pressurized-water reactor Calvert Cliffs No. 1. This report is one in a series being prepared by the Materials Characterization Center at Pacific Northwest Laboratory on spent fuel ATMs. The ATMs are receiving extensive examinations to provide a source of well- characterized spent fuel for testing in the US Department of Energy Office of Civilian Radioactive Waste Management (OCWRM) program. ATM-106 consists of 20 full-length irradiated fuel rods with rod-average burnups of about 3700 GJ/kgM (43 MWd/kgM) and expected fission gas release of /approximately/10%. Characterization data include (1) as-fabricated fuel design, irradiation history, and subsequent storage and handling; (2) isotopic gamma scans; (3) fission gas analyses; (4) ceramography of the fuel and metallography of the cladding; (5) calculated nuclide ...

1988-10-01

163

Characterization of spent fuel approved testing material: ATM-103  

Energy Technology Data Exchange (ETDEWEB)

The characterization data obtained to date are described for Approved Testing Material (ATM)-103, which is spent fuel from Assembly D101 of pressurized-water reactor Calvert Cliffs, No. 1. This report is one in a series being written by the Materials Characterization Center (MCC) at Pacific Northwest Laboratory (PNL) on spent fuel ATMs. The ATMs are receiving extensive examinations to provide a source of well-characterized spent fuel for testing in the US nuclear waste repository program. ATM-103 consists of 176 full-length irradiated fuel rods with rod-average burnups of about 2600 GJ/kgM (30 MWd/kgM) and less than 1% fission gas release. Characterization data include 1) as-fabricated fuel design, irradiation history, and subsequent storage and handling; 2) isotopic gamma scans; 3) fission gas analyses; 4) ceramography of the fuel and metallography of the cladding; 5) special fuels studies involving analytical transmission electron microscopy ...

1988-04-01

164

Characterization of spent fuel approved testing material--ATM-104  

Energy Technology Data Exchange (ETDEWEB)

The characterization data obtained to date are described for Approved Testing Material 104 (ATM-104), which is spent fuel from Assembly DO47 of the Calvert Cliffs Nuclear Power Plant (Unit 1), a pressurized-water reactor. This report is one in a series being prepared by the Materials Characterization Center at Pacific Northwest Laboratory (PNL) on spent fuel ATMs. The ATMs are receiving extensive examinations to provide a source of well-characterized spent fuel for testing in the US Department of Energy Office of Civilian Radioactive Waste Management (OCRWM) Program. ATM-104 consists of 128 full-length irradiated fuel rods with rod-average burnups of about 42 MWd/kgM and expected fission gas release of about 1%. A variety of analyses were performed to investigate cladding characteristics, radionuclide inventory, and redistribution of fission products. Characterization data include (1) fabricated fuel design, irradiation history, and subsequent storage and handling ...

1991-12-01

165

Stanford geothermal program. Final report, July 1990--June 1996  

Science.gov (United States)

This report discusses the following: (1) improving models of vapor-dominated geothermal fields: the effects of adsorption; (2) adsorption characteristics of rocks from vapor-dominated geothermal reservoir at the Geysers, CA; (3) optimizing reinjection strategy at Palinpinon, Philippines based on chloride data; (4) optimization of water injection into vapor-dominated geothermal reservoirs; and (5) steam-water relative permeability.

1998-03-01

166

Transition probability in "1"7"7Ta  

International Nuclear Information System (INIS)

... energy levels intermediate mass nuclei isotopes nuclei odd-even nuclei

167

Surprising collectivity in neutron-rich iron isotopes  

International Nuclear Information System (INIS)

... VDPEAZ (Bonn 2010 issue) NUCLEAR PHYSICS AND RADIATION PHYSICS

2010-03-15

168

Radioactive and stable isotope geology  

Energy Technology Data Exchange (ETDEWEB)

Aimed at post-graduate and post-doctoral researchers in geochemistry, this book reflects the rapid changes in the applications of radioactive and stable isotope analysis to a range of geological and geochemical problems. Isotropic chemistry and methods used in mass spectroscopy are discussed initially. The second section deals with radiometric dating methods. The role of isotopes in climate and environmental research is also explored. The book closes with a section on extra-terrestrial matter, geothermometry and the isotopic geochemistry of the Earth`s lithosphere. (UK).

1997-10-01

169

Practical application of a simplified vitamin B_1_2 radioassay  

International Nuclear Information System (INIS)

... blood serum patients radioimmunoassay sampling tracer techniques isotope

170

Physical interpretation of recent isomer investigations  

International Nuclear Information System (INIS)

... lifetime lutetium isotopes lutetium 171 lutetium 173 lutetium 175 lutetium 177

1975-08-01

171

Measurement of the electrical resistivity of the lithium isotopes at low temperatures  

Energy Technology Data Exchange (ETDEWEB)

The electrical resistivity at low temperatures (T = 10 to 90 K) of the lithium isotopes /sup 6/Li and /sup 7/Li and of an isotopic mixture /sup 7 +6/Li has been studied. The specimens contained a small amount of chemical impurities. An appreciable difference was observed in the temperature dependence of the resistivity produced both by deformation of the phonon spectrum, related to the change in isotopic composition, and by the presence of chemical impurities making the nonequilibrium part of the electron distribution function more isotropic.

1982-03-01

172

Isotopic effects on solubility-limited mass transfer  

Energy Technology Data Exchange (ETDEWEB)

In our previous theoretical analyses, solubility-limited mass transfer from waste solids applies if a species is at a constant elemental concentration in liquid at the waste surface. For an element with isotopes that decay appreciably during the time of interest, a solubility boundary condition results in a time-dependent boundary concentration of each isotope. Here we present mass-transfer equations that include the effects of isotopic decay boundary conditions. 9 refs., 1 fig.

1989-06-01

173

Isotopic differences in the lithium transport rate in human erythrocytes during simultaneous incubations with the stable isotopes sup 6 Li and sup 7 Li  

Energy Technology Data Exchange (ETDEWEB)

The membrane transport of the two stable lithium isotopes, {sup 6}Li and {sup 7}Li, by erythrocytes has been studied using a dual channel atomic absorption spectroscopic technique. {sup 6}Li appears to be taken up preferentially to {sup 7}Li, in the ratio of 10 to 40%, depending on the concentration of total lithium and on the lithium isotopic ratio in the external medium.

1992-02-01

174

Interphase mass transfer in the separation of isotopes in countercurrent columns (liquid-solid systems)  

International Nuclear Information System (INIS)

The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.

177

Boron-10 Materials Production  

International Science & Technology Center (ISTC)

Development of Technologies for Boron-10 Isotope Modified Boron-containing Materials Production and their Properties Investigation.

178

A summary of extremes of isotopic variations in extra-terrestrial materials  

International Nuclear Information System (INIS)

In this comprehensive review of current research on isotopic variations of elements in extraterrestrial materials, the variations were classified in terms of the major process involved in the modification of the isotopic composition of the element concerned. Maximum isotopic variations of each element were retrieved from publications which were available in Tokyo up to December 1985, and are presented in tabular form. (author).

179

The evaporation pan technique revisited: Old theory and a new application for time-weighted synoptic tracing of the isotopic composition of atmospheric vapour  

International Nuclear Information System (INIS)

Reliable and consistent characterization of the stable isotope composition of atmospheric water vapour and its temporal variability are important prerequisites to the wider application of isotope mass balance methods in atmospheric and water balance studies. A new approach is proposed which utilizes standard class-A evaporation pans, which have sufficient volume to buffer short-term transient variations in atmospheric conditions, justifying the assumption of constant kinetic isotopic fractionation effects in concert with precisely measured temperature and relative humidity to derive vapour isotopic composition. The results of the studies suggest that isotopic sampling of existing, conventionally operated class-A evaporation pans could offer a straightforward and cost-effective solution to the problem of documenting the shifting isotopic distribution in ...

1999-12-01

180

Stable isotopes of authigenic minerals in variably-saturated fractured tuff  

Energy Technology Data Exchange (ETDEWEB)

Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to ...

1988-11-01

181

Quality and availability of actinide isotopes from the All-Russian Scientific Research Institute of Experimental Physics in Arzamas-16  

International Nuclear Information System (INIS)

This paper describes the problems and capabilities of highly enriched actinide isotopes production by electromagnetic separation in the S-2 mass separator of VNIIEF. Isotope enrichment characteristics for uranium, plutonium, americium and curium isotopes, used in different nuclear physics experiments, and isotope contamination for single and double separations are presented. The capabilities for highly enriched "2"4"4Pu and "2"4"8Cm production for nuclear accelerator experiments and other applications are described, some details of the current and future programmes are given and the transport packaging is described. (orig.).

182

Achievements in testing of the MGA and FRAM isotopic software codes under the DOE/NNSA-IRSN cooperation of gamma-ray isotopic measurement systems  

Energy Technology Data Exchange (ETDEWEB)

DOE/NNSA and IRSN collaborated on a study of gamma-ray instruments and analysis methods used to perform isotopic measurements of special nuclear materials. The two agencies agreed to collaborate on the project in response to inconsistencies that were found in the various versions of software and hardware used to determine the isotopic abundances of uranium and plutonium. IRSN used software developed internally to test the MGA and FRAM isotopic analysis codes for criteria used to stop data acquisition. The stop-criterion test revealed several unusual behaviors in both the MGA and FRAM software codes.

2009-01-01

183

Daytime Raman lidar measurements of water vapor during the ARM 1997 water vapor intensive observation period  

Energy Technology Data Exchange (ETDEWEB)

Because of the importance of water vapor, the ARM program initiated a series of three intensive operating periods (IOPs) at its CART (Cloud And Radiation Testbed) site. The goal of these IOPs is to improve and validate the state-of-the-art capabilities in measuring water vapor. To date, two of the planned three IOPs have occurred: the first was in September of 1996, with an emphasis on the lowest kilometer, while the second was conducted from September--October 1997 with a focus on both the upper troposphere and lowest kilometer. These IOPs provided an excellent opportunity to compare measurements from other systems with those made by the CART Raman lidar. This paper addresses primarily the daytime water vapor measurements made by the lidar system during the second of these IOPs.

1998-04-01

184

Indirect heating of natural gas using vapor chambers; Aquecimento indireto de gas natural com uso de camaras de vapor  

Energy Technology Data Exchange (ETDEWEB)

Operation safety and reliability are major guidelines in the design of city-gate units. Conventional natural gas heaters operate by a indirect mechanism, where liquid water is used to transfer heat by natural convection between the combustion chamber and the natural gas coil. In this work, the concept of vapor chamber is evaluated as an indirect gas heater. In a vapor chamber, liquid water is in contact with the heat source, and vaporizes. The vapor condenses in contact with the heat sink. A reduced scale model was built and tested in order to compare these two heating concepts where the combustion chamber was replaced by electrical cartridge heaters. This engineering model can operate either as a conventional heater or as a vapor chamber. The comparison between the concepts was done by inducing a controlled power to the cartridges and by measuring the resulting temperature ...

2005-07-01

185

A particulate model of solid waste incineration in a fluidized bed combining combustion and heavy metal vaporization  

Energy Technology Data Exchange (ETDEWEB)

This study aims to develop a particulate model combining solid waste particle combustion and heavy metal vaporization from burning particles during MSW incineration in a fluidized bed. The original approach for this model combines an asymptotic combustion model for the carbonaceous solid combustion and a shrinking core model to describe the heavy metal vaporization. A parametric study is presented. The global metal vaporization process is strongly influenced by temperature. Internal mass transfer controls the metal vaporization rate at low temperatures. At high temperatures, the chemical reactions associated with particle combustion control the metal vaporization rate. A comparison between the simulation results and experimental data obtained with a laboratory-scale fluid bed incinerator and Cd-spiked particles shows that the heavy metal vaporization is ...

2009-11-15

186

Use of stable isotopes in mineral nutrition research  

International Nuclear Information System (INIS)

Stable isotopes are valuable tools for research on mineral bioavailability and metabolism. They can be used as tracers with no exposure to radiation and they do not decay over time. Attempts to use stable isotopes of minerals as metabolic tracers were first described only 25 years ago. There were relatively few reports of their use over the next 15 years, but interest in stable isotopes has expanded markedly in the last 10 years. The advantages of stable isotope tracers are so great that scientists have been willing to accept the laborious and costly nature of mineral isotope analysis, and substantial progress has been made in the field. New applications for stable isotopes and new analytical methods have been introduced recently. However, limitations to the approach and methodological problems remain to be resolved. This review describes early work in the field ...

187

On the universality of some Smarandache loops of Bol-Moufang type  

CERN Document Server

A Smarandache quasigroup(loop) is shown to be universal if all its f,g-principal isotopes are Smarandache f,g-principal isotopes. Also, weak Smarandache loops of Bol-Moufang type such as Smarandache: left(right) Bol, Moufang and extra loops are shown to be universal if all their f,g-principal isotopes are Smarandache f,g-principal isotopes. Conversely, it is shown that if these weak Smarandache loops of Bol-Moufang type are universal, then some autotopisms are true in the weak Smarandache sub-loops of the weak Smarandache loops of Bol-Moufang type relative to some Smarandache elements. Futhermore, a Smarandache left(right) inverse property loop in which all its f,g-principal isotopes are Smarandache f,g-principal isotopes is shown to be universal if and only if it is a Smarandache left(right) Bol loop in which all its f,g-principal isotopes ...

2006-01-01

188

Effect of Pressures up to 2.0 GPa on the Mechanical ...  

Science.gov (United States)

... hydrostatic pressures up to 700 MPa. The effect of pressure on the ultimate compressive strength is shown. The effect of size on ...

189

New neutron-rich isotopes in the scandium-to-nickel region, produced by fragmentation of a 500 MeV/u {sup 86}Kr beam  

Energy Technology Data Exchange (ETDEWEB)

We have measured production cross-sections of the new neutron-rich isotopes {sup 58}Ti, {sup 61}V, {sup 63}Cr, {sup 66}Mn, {sup 69}Fe, {sup 71}Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u {sup 86}Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss mesurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parameterization. The resulting prospects for reaching even more neutron-rich isotopes, such as the doubly-magic nuclide {sup 78}Ni, are discussed. (orig.).

1991-10-01

190

New neutron-rich isotopes in the scandium-to-nickel region, produced by fragmentation of a 500 MeV/u sup 86 Kr beam  

Energy Technology Data Exchange (ETDEWEB)

We have measured production cross-sections of the new neutron-rich isotopes {sup 58}Ti, {sup 61}V, {sup 63}Cr, {sup 66}Mn, {sup 69}Fe, {sup 71}Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u {sup 86}Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss measurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parametrization. The resulting prospects for reaching even more neutronrich isotopes, such as the doubly-magic nuclide {sup 78}Ni, are discussed. (orig.).

1992-07-01

191

New neutron-rich isotopes in the scandium-to-nickel region, produced by fragmentation of a 500 MeV/u "8"6Kr beam  

International Nuclear Information System (INIS)

We have measured production cross-sections of the new neutron-rich isotopes "5"8Ti, "6"1V, "6"3Cr, "6"6Mn, "6"9Fe, "7"1Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u "8"6Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss measurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parametrization. The resulting prospects for reaching even more neutronrich isotopes, such as the doubly-magic nuclide "7"8Ni, are discussed. (orig.).

192

Doppler-free optogalvanic spectroscopy of sup(88,86)Sr I and II  

International Nuclear Information System (INIS)

We have measured the isotope shifts of some dipole transitions between excited states of the even strontium isotopes 88 and 86 by applying the technique of Doppler-free intermodulated optogalvanic spectrocopy to a heat-pipe discharge. We were also able to investigate the isotope shift of the Sr II resonance line at 4216.6 A optogalvanically in the mentioned pair of isotopes. Because the 5 snf"1F_3 series appear to have zero level isotope shifts for n>=6, we can give residual level isotope shifts (RLIS) of several odd-parity states of sup(88,86) Sr I. The RLIS of the 5 snp "1P_1 series show pronounced configuration mixing around n=7. (orig.).

193

Dynamic response of a liquid-vapor interface during flow film boiling from a sphere  

Energy Technology Data Exchange (ETDEWEB)

Film boiling is the mode if boiling during which the hot surface is separated from the vaporizing liquid by a nearly continuous film vapor. Film boiling is usually considered a very undesirable boiling regime since it is a relatively quiet and inefficient mode of heat transfer, particularly as compared to nucleate boiling. It is customary to analyze the two-phase flow regime of laminar flow film boiling by assuming the two-phase flow regime of laminar flow film boiling by assuming an idealized vapor film flow characterized by a smooth liquid-vapor interface. However, during stable flow film boiling, the wavy nature of the liquid-vapor interface and its role in local heat and mass transport have been largely ignored. The vapor interface is rarely stationary. Interfacial waves may substantially augment the heat transfer rates throughout the layer. The present ...

1987-11-01

194

Carbon isotope stratigraphy of the upper Kharaib and Shuaiba formations: Implications for the Early Cretaceous evolution of the Arabian Gulf Region  

Energy Technology Data Exchange (ETDEWEB)

The carbon isotope profiles of shallow-marine carbonates from the Barremian-Aptian Kharaib and Shuaiba formations of the Arabian Gulf region range between 0.5 and 7{per_thousand} {delta}{sup 13}C PDB (Peedee belemnite). Systematic variations can be correlated with isotope profiles reported from Tethyan pelagic limestone sequences. The detailed correspondence between the isotopic signature of the relatively well-dated pelagic limestones and the poorly dated shallow-water limestones from the Arabian Gulf region suggests that global marine carbon isotope changes apparently affected deep-sea and shallow-water carbonate sediments similarly and at a similar time resolution. Although oxygen isotopes have been reset during diagenesis, carbon isotopes appear to have maintained their primary marine signature through time. No evidence has been found to connect carbon ...

1996-05-01

195

X-ray ablation measurements and modeling for ICF applications  

Energy Technology Data Exchange (ETDEWEB)

X-ray ablation of material from the first wall and other components of an ICF (Inertial Confinement Fusion) chamber is a major threat to the laser final optics. Material condensing on these optics after a shot may cause damage with subsequent laser shots. To ensure the successful operation of the ICF facility, removal rates must be predicted accurately. The goal for this dissertation is to develop an experimentally validated x-ray response model, with particular application to the National Ignition Facility (NIF). Accurate knowledge of the x-ray and debris emissions from ICF targets is a critical first step in the process of predicting the performance of the target chamber system. A number of 1-D numerical simulations of NIF targets have been run to characterize target output in terms of energy, angular distribution, spectrum, and pulse shape. Scaling of output characteristics with variations of both target yield and hohlraum wall thickness are also described. Experiments have been ...

1996-09-01

196

Visible (657 nm) InGaP/InAlGaP strained quantum well vertical-cavity surface-emitting laser  

Science.gov (United States)

We report the first visible (657 nm) vertical-cavity surface-emitting laser. The photopumped undoped structure was grown using low-pressure metalorganic vapor-phase epitaxy in a single-growth sequence on misoriented GaAs substrates. The optical cavity consists of an In{sub 0.54}Ga{sub 0.46}P/In{sub 0.48}(Al{sub 0.7}Ga{sub 0.3}){sub 0.52} P strained quantum-well active region and a lattice-matched In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52} P (0.7{le}{ital y}{le}1.0) graded spacer region, while the distributed Bragg reflectors are composed of Al{sub 0.5}Ga{sub 0.5}As/AlAs quarter-wave stacks. Room-temperature optically pumped lasing was achieved with a very low-threshold power, clearly demonstrating the viability of this new technology. These results provide the foundation for visible semiconductor laser-diode arrays for a number of applications including laser projection displays, holographic memories, and plastic fiber ...

1992-04-13

197

PFB coal fired combined cycle development program. Annual report, July 1978-June 1979  

Energy Technology Data Exchange (ETDEWEB)

The Coal Fired Combined Cycle (CFCC) is the unique powerplant concept developed under the leadership of the General Electric Company to provide a direct coal-burning gas turbine and steam turbine combined cycle powerplant. On the basis of previous studies and confirming work under this contract, General Electric continues to believe that the CFCC approach offers important advantages over alternate approaches: higher powerplant efficiency in the combustor temperature range of interest; reduced combustor/steam generator corrosion potential, due to low fluid-bed tube temperature (as contrasted to the air in tube cycle); and increased gas turbine bucket life from improved material protection systems. The objective of this program is to evaluate the coal fired combined cycle powerplant conceptual design, and to conduct a supporting development program. The supporting development is required for evaluating the pressurized fluidized bed combustion concept, for developing ...

1980-05-01

198

Methods for evaluating long-term changes in thermal resistance of vacuum insulation panels  

Energy Technology Data Exchange (ETDEWEB)

Vacuum insulation panels (VIP) offer excellent thermal resistance properties that can enhance the energy efficiency of insulating systems, save space and contribute to energy consumption reductions. However, VIPs are not used much in Canada, and new commitments to carbon dioxide reductions has created the need to study the prospect of using VIPs in various components of a building envelope. For that reason, assessment methods for the applicability and sustainability of VIPs for use in building envelope construction were developed. There are practical aspects regarding the long-term performance and application of VIPs in building construction. Air molecules and water molecules can permeate through the foil and seams of the VIPs, causing a reduction in thermal resistance. This paper addresses some of the test methods that may accelerate long term changes in thermal resistance. Results were presented from tests using elevated pressure, relative humidity and ...

2005-07-01

199

Evaluation of 1-site and 5-site models of methane on its adsorption on graphite and in graphitic slit pores.  

Science.gov (United States)

In this paper, we evaluate the performance of the 1- and 5-site models of methane on the description of adsorption on graphite surfaces and in graphitic slit pores. These models have been known to perform well in the description of the fluid-phase behavior and vapor-liquid equilibria. Their performance in adsorption is evaluated in this work for nonporous graphitized thermal carbon black, and simulation results are compared with the experimental data of Avgul and Kiselev (Chemistry and Physics of Carbon; Dekker: New York, 1970; Vol. 6, p 1). On this nonporous surface, it is found that these models perform as well on isotherms at various temperatures as they do on the experimental isosteric heat for adsorption on a graphite surface. They are then tested for their performance in predicting the adsorption isotherms in graphitic slit pores, in which we would like to explore the effect of confinement on the molecule packing. Pore widths of 10 and 20 A are chosen in this ...

2005-10-20

200

A technique for determining the spatial and temporal distributions of surface fluxes of heat and moisture over the Southern Great Plains Cloud and Radiation Testbed  

Energy Technology Data Exchange (ETDEWEB)

Land surface parameterization schemes such as the Simple Biosphere Model (SiB2) have found considerable use in climate simulation models, where they provide lower boundary conditions in the form of surface sensible and latent heat fluxes. A methodology is described to apply models of this type at high resolution, using data from the Department of Energy{close_quote}s Cloud and Radiation Testbed in Oklahoma and Kansas, to determine the spatial variations of heat fluxes over the domain and to determine area-weighted flux averages for use in single-column model studies. Data from a dense array of meteorological instruments are interpolated to provide the wind, temperature, vapor pressure, radiation, and precipitation values needed by SiB2. The state of the vegetation is characterized through the use of the normalized difference vegetation index determined from satellites. The performance of the SiB2 model is evaluated by comparing its predictions ...

1998-03-01

201

A phenomenological model of the thermal hydraulics of convective boiling during the quenching of hot rod bundles  

International Nuclear Information System (INIS)

In this paper, a phenomenological model of the thermal hydraulics of convective boiling in the post-critical-heat-flux (post-CHF) regime is developed and discussed. The model was implemented in the TRAC-PF1/MOD2 computer code (an advanced best-estimate computer program written for the analysis of pressurized water reactor systems). The model was built around the determination of flow regimes downstream of the quench front. The regimes were determined from the flow-regime map suggested by Ishii and his coworkers. Heat transfer in the transition boiling region was formulated as a position-dependent model. The propagation of the CHF point was strongly dependent on the length of the transition boiling region. Wall-to-fluid film boiling heat transfer was considered to consist of two components: first, a wall-to-vapor convective heat-transfer portion and, second, a wall-to-liquid heat transfer representing near-wall effects. Each contribution was ...

1983-10-14

202

Theoretical study of lithium isotope separation by displacement chromatography  

Energy Technology Data Exchange (ETDEWEB)

Lithium isotope separation by displacement chromatography is studied using fundamental principles; the equations are derived assuming theoretical stages in lithium adsorption bands. The concentration profiles in the band are calculated numerically under unsteady state.

1982-01-01

203

Terrestrial and Meteorite Carbon Appear to Have the Same Isotopic Composition  

UK PubMed Central (United Kingdom)

The carbon-isotope ratio recently obtained for the carbon found in the Murchison meteorite, which has been shown (by the racemic nature of twelve component amino acids) to be free of terrestrial contamination,...Full Text Available

1971-02-01

204

Study on the angular. gamma gamma. -correlations for nuclei of Sr even-even isotopes  

Energy Technology Data Exchange (ETDEWEB)

The angular ..gamma gamma..-correlations for nuclei of Sr even-even isotopes with A=82, 84, 86, 88 were measured. Multipole structurs of ..gamma..-transtion series and th coefficients multipole mixing were determined.

1984-05-01

205

Study on the angular #gamma##gamma#-correlations for nuclei of Sr even-even isotopes  

International Nuclear Information System (INIS)

The angular #gamma##gamma#-correlations for nuclei of Sr even-even isotopes with a=8 82, 84, 86, 88 were measured. Multipole structurs of #gamma#-transtion series and th coefficients multipole mixing were determined.

1983-04-01

206

Stable-Carbon-Isotope Composition of Fatty Acids in Hydrothermal Vent Mussels Containing Methanotrophic and Thiotrophic Bacterial Endosymbionts  

UK PubMed Central (United Kingdom)

Fatty acid biomarker analysis coupled with gas chromatography-isotope ratio mass spectrometry was used to confirm the presence of methanotrophic and thiotrophic bacterial endosymbionts in the tissues...Full Text Available

1998-01-01

207

Stable Isotopes (?D, ?13C, ?15N) Reveal Associations Among Geographic Location and Condition of Alaskan Northern ...  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

208

STABLE-ISOTOPE (C, N, H) ANALYSES HELP LOCATE THE WINTER RANGE OF THE COASTAL PLAIN SWAMP SPARROW (MELOSPIZA GEORGIANA ...  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

209

Neutron data requirements for calculating transactinide isotope build-up in reactors  

International Nuclear Information System (INIS)

Based on a generalized theory of perturbations and on non-linear programming an approach to the quantitative determination of necessary accuracies for nuclear data is described. It is used to calculate transactinide isotope build-up in reactors.

1979-08-01

210

ISOTOPIC EVALUATION OF INTERRUPTED MOLT IN NORTHERN BREEDING POPULATIONS OF THE LOGGERHEAD SHRIKEEvaluaci?n Isotopica ...  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

211

Further Evidence for Site Fidelity to Wing Molt Locations by King Eiders: Integrating Stable Isotope Analyses and ...  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

212

Evaluation of 13C isotopic tracers for metabolic flux analysis in mammalian cells  

UK PubMed Central (United Kingdom)

13C metabolic flux analysis (MFA) is the most comprehensive means of characterizing cellular metabolic states. Uniquely labeled isotopic tracers enable more focused analyses to probe...Full Text Available

2009-11-01

213

Uses of laser optical pumping to produce polarized ion beams  

Energy Technology Data Exchange (ETDEWEB)

Laser optical pumping can be used to produce polarized alkali atom beams or polarized alkali vapor targets. Polarized alkali atom beams can be converted into polarized alkali ion beams, and polarized alkali vapor targets can be used to produce polarized H/sup -/ or /sup 3/He/sup -/ ion beams. In this paper the authors discuss how the polarized alkali atom beams and polarized alkali vapor targets are used to produce polarized ion beams with emphasis on the production of polarized negative ion beams.

1983-04-01

214

Effects of vaporizer and evaporative-condenser size on geofluid effectiveness and cost of electricity for geothermal binary power plants  

Energy Technology Data Exchange (ETDEWEB)

A special study was conducted to investigate the influences of minimum approach temperature differences occurring in supercritical-heater/vaporizer and evaporative-condenser heat rejection systems on geothermal-electric binary power plant performance and cost of electricity. For the systems investigated optimum pinch points for minimizing cost of electricity were estimated to range from 5 to 7/sup 0/F for the heater vaporizer. The minimum approach of condensing temperature to wet-bulb temperature for evaporative condensers was estimated to be about 30/sup 0/F in order to achieve the lowest cost of electricity.

1983-10-01

215

The structure of the transitional N=59 nucleus "1"0"1Mo  

International Nuclear Information System (INIS)

... fermions interacting boson model molybdenum 101 neutron-rich isotopes

1987-03-23

216
217

Separation of lithium isotope by NTOE compound  

International Nuclear Information System (INIS)

Separation of lithium isotope by NTOE compound was carried out with 0.01M HCl solution. The ion exchange capacity of NTOE was 0.8 meq/g. The separation factor, #alpha#=("7Li/"6Li)_s_o_l_i_d/("7Li/"6Li)_l_i_q_u_i_d was 1.0242 by the elution chromatography. The lighter isotope, "6Li was concentrated in the liquid phase, while the heavior isotope, "7Li was enriched in the solid phase. (author).

219

Optogalvanic isotope enrichment of Cu ions in Cu-Ne positive column discharges  

Energy Technology Data Exchange (ETDEWEB)

The isotopic enrichment of copper ions in a positive column Cu-Nu discharge using optogalvanic excitation is analyzed with a rate equation model With excitation at 510.6 nm, the fraction of the ions belonging to the 63-amu isotope of copper is enriched relative to the neutral abundance. Enrichment as large as 10% is calculated when the initial abundance of the neutral isotope is small (< or =0.1) and the discharge current density is large (> or =75 mA/cm/sup 2/). The degree of enrichment is examined as a function of the initial abundance, discharge current, the rate of charge exchange, and the diameter of the discharge tube.

1983-07-01

220

Nuclear moments and changes in rms-radii of neutron-deficient silver isotopes  

International Nuclear Information System (INIS)

... nuclear electric moments nuclear magnetic moments nuclear radii quadrupole

1987-03-23

222

Isolation of carrier-free tantalum radioisotopes from proton-irradiated hafnium  

International Nuclear Information System (INIS)

... carrier-free isotopes hafnium compounds irradiation protons solvent extraction

224

Effects of temperature and the use of macroreticular resins in lithium isotope separation by displacement chromatography  

Energy Technology Data Exchange (ETDEWEB)

The effects of temperature and the use of macroreticular resins were studied in lithium isotope separation by an ion-exchange method. The isotope separation factors obtained decreased by increasing the temperature, and the factors for macroreticular resins were identical with those for the usual gel-type resins. However, the performance of isotope separation per unit band length in displacement chromatography was found to be improved by increasing the temperature and using macroreticular resins, because accelerating the interphase mass transfer caused the reduction of HETP (Height Equivalent to a Theoretical Plate).

1983-01-01

225

Decays of "8"8Kr and "8"8Rb  

International Nuclear Information System (INIS)

... isotopes minutes living radioisotopes nuclei odd-odd nuclei particle properties

226

Decay of "1"7"7Ta to levels of "1"7"7Hf  

International Nuclear Information System (INIS)

... intermediate mass nuclei isotopes leptonic decay nuclei odd-even nuclei

1973-10-01

227

Chromosomal damage in human lymphocytes from radio-isotope therapy  

International Nuclear Information System (INIS)

(Dec 1973). United Kingdom Stevenson, AC Medical Research Council, Oxford

229

Annual report, 1979-1980  

Energy Technology Data Exchange (ETDEWEB)

Information is presented concerning reactor research activities; isotope geology; NERC radiocarbon laboratory; teaching activities; and reactor operation.

1980-01-01

231

--No Title--  

Science.gov (United States)

Nitrogens, Sulfurs, Isotopes, and Hydrocarbons Gases Elements Ions and Inorganic Acids Organic Compounds Co-eluting Organics Hopanes, Cholestanes, and Sterols Pesticides,...

2011-08-19

232

chapter 5 - NASA's History Office  

Science.gov (United States)

Ever-present water vapor and dust distort or block incoming radiations. ... were among the first scientific sensors to be attached to the earliest space rockets. ...

233

Parametric Modeling of Low-Frequency Water-Vapor-Induced ...  

Science.gov (United States)

indicated for the phase spectral density measurements; how- ever, Ref. 7 provides a very tentative estimate of : ORW ~ 2 ><10"'(RW); Ta = 1000 seconds ...

234

Numerical modeling of scanning laser-induced melting, vaporization and resolidification in metals subjected to step heat flux input  

Energy Technology Data Exchange (ETDEWEB)

We present a 1-D heat transfer, melting, vaporization and resolidification model describing the interaction of a scanning continuous-wave laser with a metal surface wherein the beam power is constant. A physical model based on the Stefan problem is developed with appropriate boundary conditions. The effects of processing parameters on process variables are investigated numerically by varying beam diameters, scan speeds and substrate temperatures for Nickel. Relations are derived for the times to initiate melting, to initiate vaporization, to reach maximum melting depth, for melting-resolidification, and for maximum melting and vaporization depths. Surface temperatures are compared with approximate closed form solutions. (Author)

2004-09-01

235

Interpolating atmospheric water vapor delay by incorporating terrain elevation information  

British Library Electronic Table of Contents (United Kingdom)

In radio signal-based observing systems, such as Global Positioning System (GPS) and Interferometric Synthetic Aperture Radar (InSAR), the water vapor in the atmosphere will cause delays during the signal transmission. Such delays vary significantly with terrain elevation. In the case when atmospheric delays are to be eliminated from the measured raw signals, spatial interpolators may be needed. By taking advantage of available terrain elevation information during spatial interpolation process, the accuracy of the atmospheric delay mapping can be considerably improved. This paper first reviews three elevation-dependent water vapor interpolation models, i.e., the Best Linear Unbiased Estimator in combination with the water vapor Height Scaling Model (BLUE?+?HSM), the Best Linear Unbiased Es...

2011-01-01

236

Instabilities during liquid migration into superheated hydrothermal systems  

Energy Technology Data Exchange (ETDEWEB)

Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into ...

1995-01-26

237

Fuel conversion apparatus and method  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and method are described for the vaporization of liquid fuel oils to produce a gaseous mixture suitable for burning in a burner normally designed for operation utilizing natural gas.

1981-11-24

238

Excitonic transitions in InGaP/InAlGaP strained quantum wells  

Science.gov (United States)

Excitonic transitions in metalorganic vapor phase epitaxially grown In[sub [ital x

1993-08-30

239

Changes of atmospheric water vapor budget in the Pearl River basin and possible implications for hydrological cycle  

British Library Electronic Table of Contents (United Kingdom)

In this study, we thoroughly analyzed abrupt behaviors, trends, and periodicity properties of water vapor flux and moisture budget entering and exiting the four edges of the Pearl River basin based on the NCAR/NCEP reanalysis dataset by using the continuous wavelet transform and the simple two-phase linear regression technique. Possible implications for hydrological cycle and water resource management of these changes are also discussed. The results indicate that: (1) the water vapor propagating through the four edges of the Pearl River basin is decreasing, and it is particularly true for the changes of the water vapor flux exiting from the north edge of the study river basin. The transition point from increase to decrease occurs in the early 1960s; (2) The wavelet transform spectra indica...

2010-01-01

240

Anesthetic stimulation of insect water receptors.  

UK PubMed Central (United Kingdom)

Halothane, chloroform, and carbon tetrachloride, in the vapor and liquid phases, stimulate the water receptor of the blowfly Phormia regina. There are three successive phases of response to long-lasting...Full Text Available

1976-09-01

242

The triaxial motion in Mo isotopes  

Energy Technology Data Exchange (ETDEWEB)

The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of [sup 87]Mo are studied in detail and explained by the evolution of the [gamma]-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N [>=] 47 for the spherical shape of the Mo isotopes. (orig.)

1993-11-22

243

The triaxial motion in Mo isotopes  

International Nuclear Information System (INIS)

The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of "8"7Mo are studied in detail and explained by the evolution of the #gamma#-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N #>=# 47 for the spherical shape of the Mo isotopes. (orig.).

244

The asymmetric rotator model applied to odd-mass iridium isotopes  

International Nuclear Information System (INIS)

The method of inversion of the eigenvalue problem previously developped for nuclei with axial symmetry is extended to asymmetric equilibrium shapes. This new approach to the asymmetric rotator model is applied to the odd-mass Iridium isotopes. A satisfactory and coherent description of the observed energy spectra is obtained, especially for the lighter isotopes. (orig.).

245

Laser-induced fluorescence measurement of sup(6,7)lithium isotope shift  

Energy Technology Data Exchange (ETDEWEB)

Values of frequency splittings in the lithium isotopes have been determined with the aid of laser-induced fluorescene in a supersonic beam, perpendicularly irradiated by a CW ring dye laser. The residual 2s-2p isotope shift has been found to bw 4721.8 +- 2.0 MHz, leading to a specific mass shift for the 2p level of -3610.8 +- 5 MHz.

1986-07-01

246

Isotope Production at the Hanford Site in Richland, Washington  

Energy Technology Data Exchange (ETDEWEB)

This report was prepared in response to a request from the Nuclear Energy Research Advisory Committee (NERAC) subcommittee on ''Long-Term Isotope Research and Production Plans.'' The NERAC subcommittee has asked for a reply to a number of questions regarding (1) ''How well does the Department of Energy (DOE) infrastructure sme the need for commercial and medical isotopes?'' and (2) ''What should be the long-term role of the federal government in providing commercial and medical isotopes?' Our report addresses the questions raised by the NERAC subcommittee, and especially the 10 issues that were raised under the first of the above questions (see Appendix). These issues are related to the isotope products offered by the DOE Isotope Production Sites, the capabilities and condition of the ...

1999-06-01

247

Enrichment of americium-242m and americium-242 isotopes by means of Szilard-Chalmers method using americium-241 diphthalocyanine complex  

International Nuclear Information System (INIS)

Results of americium-242m and americium-242 preparation by irradiating initial americium-241 at a reactor in the form of a diphtalocyanine complex are presented. The enrichment coefficient, equalling 10, has been obtained using the extraction method of recoil atom separation from the parent isotope. Application of the chromatographic column with Dowex-50 permits to increase the enrichment coefficient of isotopes upto 24.6.

248

Separation of lithium and calcium isotopes during chemical isotopic exchange in extraction systems with phosphoryl-containing podands  

International Nuclear Information System (INIS)

A study was made on extraction of a series of lithium and calcium salts by monopodands L with common formula R-C_6H_4-O-(CH_2CH_2O)_n-C_6H_4-R, where R - CH_2P(O)Ph_2, n 1-3. Extraction-chromatographic separation of lithium and calcium isotopes in systems of metal aquacomplex-solvatocomplex with L in organic phase was conducted. It was established that separation coefficients of "6Li/"7Li isotopes ranged between 1.003 #+-#0.001 and 1.017 #+-#0.002 at the maximal separation degree equal to 1.60. Separation of "4"0Ca/"4"4Ca isotopes was not fixed. 12 refs., 4 figs., 1 tab.

249

Investigation of the isotopic composition of lead and of trace elements concentrations in natural uranium materials as a signature in nuclear forensics  

International Nuclear Information System (INIS)

Lead is contained as trace element in uranium ores and propagates throughout the production process to intermediate products like yellow cake or uranium oxide. The lead isotopes in such material originate from two sources: natural lead and radiogenic lead. The variability of the isotopic composition of lead in ores and yellow cakes was studied and the applicability of this parameter for nuclear forensic investigations was investigated. Furthermore, the chemical impurities contained in these materials were measured in order to identify characteristic differences between materials from different mines. For the samples investigated, it could be shown, that the lead isotopic composition varies largely from mine to mine and it may be used as one of the parameters to distinguish between materials of different origins. Some of the chemical impurities show a similar pattern and support the conclusions drawn from the lead ...

250

Study of the Photon Strength Functions for Gadolinium Isotopes with the DANCE Array  

Science.gov (United States)

The gadolinium isotopes are interesting for reactor applications as well as for medicine and astrophysics. The gadolinium isotopes have some of the largest neutron capture cross sections. As a consequence they are used in the control rod in reactor fuel assembly. From the basic science point of view, there are seven stable isotopes of gadolinium with varying degrees of deformation. Therefore they provide a good testing ground for the study of deformation dependent structure such as the scissors mode. Decay gamma rays following neutron capture on Gd isotopes are detected by the DANCE array, which is located at flight path 14 at the Lujan Neutron Scattering Center at Los Alamos National Laboratory. The high segmentation and close packing of the detector array enable gamma-ray multiplicity measurements. The calorimetric properties of the DANCE array coupled with the neutron time-of-flight technique enables ...

2009-03-10

251

Research on development of adsorbent for separating and collecting light element isotopes  

International Nuclear Information System (INIS)

Lithium isotopes are used as the raw material of tritium which is the fuel for fusion power generation and the material for fusion reactors, accordingly those are indispensable for future nuclear fusion power generation. As for boron isotopes, the neutron absorption corss section is very large, therefore, they are used for shielding neutrons and controlling fast neutron reactors. In order to further develop the utilization of nuclear power, it is important to develop the technology for separating and refining light element isotopes in large amount. In fiscal year 1995, the relation of the ion sieve characteristics of inorganic ion exchanger and the behavior of lithium isotope separation was examined. The behavior of forming boron complex of polyol amine was examined by B-11 NMR. These experiments and the results are reported. It was shown to be feasible that lithium is adsorbed from seawater, and ...

252

Ground-state properties of exotic nuclei near Z=40 in the relativistic mean-field theory  

International Nuclear Information System (INIS)

Study of the ground-state properties of Kr, Sr and Zr isotopes has been performed in the framework of the relativistic mean-field (RMF) theory using the recently proposed relativistic parameter set NL-SH. It is shown that the RMF theory provides an unified and excellent description of the binding energies, isotope shifts and deformation properties of nuclei over a large range of isospin in the Z=40 region. It is observed that the RMF theory with the force NL-SH is able to describe the anomalous kinks in isotope shifts in Kr and Sr nuclei, the problem which has hitherto remained unresolved. This is in contrast with the density-dependent Skyrme-Hartree-Fock approach which does not reproduce the behaviour of the isotope shifts about shell closure. On the Zr chain we predict that the isotope shifts exhibit a trend similar to that of the Kr and Sr nuclei. The RMF theory also predicts ...

253

Stakeholder acceptance analysis: In-well vapor stripping, in-situ bioremediation, gas membrane separation system (membrane separation)  

Energy Technology Data Exchange (ETDEWEB)

This document provides stakeholder evaluations on innovative technologies to be used in the remediation of volatile organic compounds from soils and ground water. The technologies evaluated are; in-well vapor stripping, in-situ bioremediation, and gas membrane separation.

1995-12-01

254

Second harmonic generation of copper-vapor pulsed laser radiation  

Energy Technology Data Exchange (ETDEWEB)

An experimental study of second harmonic generation in a copper-vapor pulsed laser with an ADP crystal is presented. The ratio of the conversion into the second harmonic is found to depend on the average power of the exciting radiation. The maximum conversion ratio was 8.5%. Thermal self-defocusing is the main obstacle to obtaining high average powers at the double frequency.

1980-08-01

255

Recovery of Water from Boiler Flue Gas  

Energy Technology Data Exchange (ETDEWEB)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat ...

2008-09-30

256

Laser photochemical etching of molybdenum and tungsten thin films by surface halogenation  

Energy Technology Data Exchange (ETDEWEB)

Laser direct-write etching of the refractory metals Mo and W was developed using reactions in chlorine and nitrogen trifluoride vapors. Rate and high spatial resolution are simultaneously optimized using a two-vapor halogenation/development sequence, based on surface modification. Local-area laser chlorination of the metal surface is used to predispose areas to subsequent bulk etching.

1986-12-01

257

Double-electron-capture cross section for I/sup +/ in a magnesium-vapor target  

Energy Technology Data Exchange (ETDEWEB)

Measurements of the double-electron-capture process in which a positive ion of iodine becomes a negative ion in a single collision with a magnesium atom are reported between 20 and 90 keV. The cross section is comparable to that for the rare gases and not as large as might be expected from a two-valence-electron atom. This process is probably insignificant in the production of negative ion beams using a magnesium-vapor target.

1987-06-15

258

Chalk Point Cooling Tower Project. Environmental Systems Corporation's FY77 final report, July 1, 1976--August 31, 1977. Volume II. Cooling Tower Drift Dye Tracer Experiment. [Dye tests of vapor plume dispersion in coastal regions  

Science.gov (United States)

Results are reported from dye tests of the dispersion of the vapor plume from the natural draft cooling tower of a fossil-fuel power plant located in the coastal region of Maryland.

1977-12-01

259

Hydraulic device for control rod drive mechanisms  

International Nuclear Information System (INIS)

Purpose: To improve the reliability of control rod drive mechanisms for use in BWR type reactors by preventing erroneous insertion of control rods caused by the increase in the coolant pressure. Constitution: A pressure-releaf valve mechanism is provided which opens its valve when a detected difference between the pressure of the coolants flowing through coolant pipeways and the reactor pressure exceeds a predetermined pressure difference. If the coolant pressure increases abnormally, coolants in the coolant pipeway are released to lower the pressure. (Aizawa, K.).

1981-07-31

260

Adsorption of mercury vapor on particles  

Energy Technology Data Exchange (ETDEWEB)

The adsorption of mercury vapor on particles was studied by using soot particles generated by incineration of sewage sludge (EP-ash) and activated carbon particles. Through the experiments, it was found that, at 298 K, the EP-ash has a fairly high adsorption capacity for mercury vapor in the order of 10/sup -6/g/g, which is between that of the ordinary soils and that of activated carbon particles. Furthermore, it was found that physical adsorption of mercury vapor on the studied particles at high temperature is described by Dubinin's equation. On the basis of the equation, it was shown that EP-ash physically adsorbs very little mercury at high temperature, and therefore, most mercury in the EP-ash is chemically adsorbed or contained in a form of mercury compounds. Nevertheless, the total amount of mercury contained in the particles is very little compared to the total mercury in the exhaust gases so that most ...

1986-07-01

261

Design of a closed 4 MW spallation target module with heat removal system for an ADS system  

International Nuclear Information System (INIS)

At the Forschungszentrum Karlsruhe the HGF Strategy Fund project entitled 'Innovative Technology to Reduce Radiotoxicity' is performed which delivers an essential scientific contribution to the application oriented fundamental research for Accelerator Driven Systems (ADS). The addressed topics are in the areas of heavy liquid metal technology, thermalhydraulics and materials / corrosion. An ADS consists of three main components: an proton accelerator, a spallation target and a subcritical blanket. The strategic objective of an ADS is the transmutation of long-lived radioactive waste (plutonium, minor actinides and long-lived fission products) into short-lived isotopes or stable elements, thus closing the fuel cycle. The objective of one task of the HGF Strategy Fund Project is the numerical calculation of a closed spallation target module. In a consequent next step such a spallation target can be experimentally investigated at IKET and the numerical results can be ...

262

CO{sub 2} bands in the 3350 - 3700 cm{sup {minus}1} spectral region: Ro-vibrational constants and absolute intensities  

Energy Technology Data Exchange (ETDEWEB)

Spectroscopic constants and absolute intensities from more than 2150 transitions belonging to 52 bands of 7 isotopic species of carbon dioxide have been determined using a multispectrum nonlinear least-squares fitting technique. The spectral data (0.01 cm{sup -1} resolution) were obtained at room temperature and low pressure (<10 Torr) using the McMath-Pierce Fourier transform spectrometer of the National Solar Observatory on Kitt Peak, Arizona. A natural sample of carbon dioxide with absorption path lengths between 24 and 385m were used in recording the spectra. The first measurements have been made of the theoretically predicted 2v{sub 2}{sup 2} 2+v{sub 3} {open_quotes}forbidden{close_quotes} band of {sup 12}CO{sub 2}. Two bands which have not been predicted so far, one belonging to {sup 13}CO{sub 2} and the other to {sup 13}C{sup 16}O{sup 18}O, have been identified. The measured line intensities obtained for each band have been analyzed ...

1995-12-31

263

3D-nuclear heat generation in PCC-charcoal filter in TAPP-3 and 4  

International Nuclear Information System (INIS)

This paper deals with the calculations of 3D nuclear heat generation profile in the charcoal filter and subsequently the commencement time of Primary Containment Cleanup (PCC) system of 540MWe Pressurized Heavy Water Reactor (PHWR). Fuel failure is predicted due to overheating of the fuel under loss of Coolant Accident (LOCA) without Emergency Core Cooling System (LOCA without ECCS). Subsequently fission product gasses along with water vapours are released to Reactor Building (RB) atmosphere. Plate-out and water trapping mechanism stabilizes the concentration of significant fission products i.e. radioiodines in about 4 hours before being circulated through charcoal filters of Containment Cleanup system. After cleaning up the RB atmosphere, it is discharged to outside atmosphere through stack. The isotopes of radioiodine emit beta and gamma radiations. Gamma radiations are partly stopped within the charcoal and heat is generated. The part of ...

2006-11-13

264

Progress in development of controlled-clearance pressure balance in NMIJ  

International Nuclear Information System (INIS)

A new controlled-clearance pressure balance is under development with the aim of improving the hydraulic high-pressure standard up to 1 GPa. This pressure balance consists of three parts: (i) a pressure generation device up to 1 GPa, (ii) a weight-loading unit which can load/unload weights automatically and independently, (iii) a controlled-clearance piston-cylinder which is designed to allow the jacket pressure to be applied independently. Some adjustments were made for loading heavy weights on/off the piston safely, keeping them in balance, then generating the pressure stably. Stability of the generated pressure was checked for several piston-cylinders, and it was found that pressure fluctuation was less than a few parts per million. The jacket pressure coefficient of a 500 MPa controlled-clearance ...

2010-03-01

265

CO2 Capture by Absorption with Potassium Carbonate  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO3 promoted by piperazine (PZ). Pilot plant testing was performed in a 16.8-inch ID absorber and stripper with recirculation of air and CO{sub 2}. Three solvents (7 m MEA, 5 m K{sup +}/2.5 m PZ, and 6.4 m K{sup +}/1.6 m PZ) were tested in four campaigns with three different absorber packings. Pilot plant testing established that 5 m K{sup +}/2.5 m PZ requires two times less packing than 7 m MEA and three times less packing than 6.4 m K{sup +}/1.6 m PZ. A rigorous model of the thermodynamics and mass transfer was developed in the RateSep{trademark} block of AspenPlus{reg_sign}. The double matrix stripper reduces energy consumption by 5 to 15%. The best K{sup +}/PZ solvent, 4 m K{sup +}/4 m PZ, and the best process configuration, double matrix stripper with a double intercooled absorber, requires equivalent work of 40 ...

2007-08-31

266

Formation of organic thin film by hot wall vapor deposition. Hot wall jochakuho ni yoru yuki usumaku no keisei  

Energy Technology Data Exchange (ETDEWEB)

The process operation of the hot wall vapor deposition method, formation of dry organic thin film and the control of molecular arrangement were described. This equipment included a substrate on the upper end of the hot wall tube and the vapor source at the lower end. The remarkable features are the hot wall tube which plays the role to hold vaporizing molecules to the high temperature and to transport molecules, and the flip flop mechanism which gives some idle period for the molecular vaporization by shutter closing. Several experiments were carried out by using stearic acid and by changing the distance S from the upper end of hot wall quartz tube to the substrate, the furnace temperature T{sub f} and the substrate temperature T{sub s}. When T{sub f} is equal to or less than the melting point of stearic acid, molectles are preferentialy made to vertical arrangement. In the case of T{sub f} more than ...

1991-12-01

269

Review of isotope geochemical studies for Iceland. 1. Isotope-geochemical characterization of Icelandic hot spot; Doitai chikyu kagaku kara mita Iceland. 1. Iceland hot spot no doitai chikyu kagakuteki tokucho  

Energy Technology Data Exchange (ETDEWEB)

In this article, the isotope geochemical study for Iceland is reviewed. Iceland is geologically unique because it is a subaerial exposure of Mid-Atlantic Ridge, which is caused by the interaction between the ridge and the Icelandic hot spot. To investigate what is happening beneath Iceland, many geochemical studies have been done. The geochemical studies using conventional Sr, Nd, Pb, He and O isotope tracers revealed the heterogeneity not only of the oceanic mantle, but also of the Icelandic hot spot mantle itself. Furthermore, the oxygen isotope studies revealed the reworking of the Icelandic crust which is altered by meteoritic water. The characterization of the Icelandic hot spot from the isotope geochemistry is very important in testing the hypothesis of the mantle-crust recycling. In near future, new tracers such as Li, B or Ce will be applied to this problem, and new constraints will be obtained. ...

1995-11-05

270

Results of Am isotopic ratio analysis in irradiated MOX fuels  

Energy Technology Data Exchange (ETDEWEB)

For analysis of a small quantity of americium, it is necessary to separate from curium which has similar chemical property. As a chemical separation method for americium and curium, the oxidation of americium with pentavalent bismuth and subsequent co-precipitation of trivalent curium with BIP O{sub 4} were applied to analyze americium in irradiated MOX fuels which contained about 30wt% plutonium and 0.9wt% {sup 241}Am before irradiation and were irradiated up to 26.2GWd/t in the experimental fast reactor Joyo. The purpose of this study is to measure isotopic ratio of americium and to evaluate the change of isotopic ratio with irradiation. Following results are obtained in this study. (1) The isotopic ratio of americium ({sup 241}Am, {sup 242m}Am and {sup 243}Am) can be analyzed in the MOX fuels by isolating americium. The isotopic ratio of {sup 242m}Am and {sup 243}Am increases up to 0.62at% and ...

1997-04-01

271

High precision, in situ oxygen isotope ratio measurements obtained from geological and extra-terrestrial materials using an Isolab 54 ion microprobe  

Energy Technology Data Exchange (ETDEWEB)

We have developed an ion probe technique for the in situ measurement of oxygen isotope ratios, {sup 18}O/{sup 16}O and {sup 17}O/{sup 16}O, with high spatial resolution in polished thin sections of silicate minerals. This technique allows the isotopic analysis of samples as small as picomoles of material which represents only 10{sup -7} of the sample size required by conventional fluorination oxygen isotope measurement methods and thus has wide application to the study of many terrestrial and extra-terrestrial samples that have heterogeneous oxygen isotope compositions on a scale of tens of micrometres. To illustrate the breadth of studies that are made possible by the ion probe, we report here oxygen isotope measurements from an authigenic quartz overgrowth obtained from the Penrith sandstone, UK, and measurements of magnetite grains from the Orgueil and Yamato 82162 carbonaceous ...

1995-05-01

272

Fluctuation of lithium isotopic ratios induced by salt concentrations in a liquid-liquid extraction system  

International Nuclear Information System (INIS)

Liquid-liquid extractive separation of lithium isotopes was carried out in order to investigate the fluctuation of separation factors (a) as a function of salt concentrations in an aqueous phase. Two equations for separation factor (a_o_b_s) as a function of the concentration were introduced; one for the diluted region, and another for the concentrated region. In the former solution where hydrated lithium ions are predominant, 1n a_o_b_s = Ac + B, and in the latter where ion-pairs with anions are predominant, 1n a_o_b_s = Dc + E(c - F)"1"/"3 + G. Some guidelines are derived from the salt-specific constants A, B, D, E, F and G. The heavier isotopes are inclined to be in the more hydrated state in the diluted solution, while the lighter isotopes tend to be in a less hydrated state. In the concentrated solution, heavier isotopes are more likely to be in ion-pair form. Ionic association occurs from the ...

273

Alpha-n and spontaneous fission sources and spectra from individual plutonium isotopes in PuF{sub 4} and PuO{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

Plutonium-containing compounds vary widely in isotopic content, and as a result, the dose as function of isotopic content also varies considerably. Determination of the dose from neutrons, decay and capture gammas from plutonium in the form of compounds thus requires that the spontaneous fission and ({alpha},n) source and spectra from each individual isotope be known. To facilitate dose calculations from plutonium-containing compounds, we have calculated the spontaneous fission and ({alpha},n) sources and spectra for 1 g of each of the plutonium isotopes in the form of either PuF{sub 4} or PuO{sub 2}. As {sup 241}Am is often a component in a mixture of plutonium isotopic compounds, the source and spectra from 1 g of {sup 241}Am mixed with PuF{sub 4} or PuO{sub 2} has also been determined. Using these results, the neutron source and spectra may be determined for any sample ...

1996-10-01

274

Two-phase flow modeling in the rod bundle subchannel analysis; Modelisation d'ecoulement a deux phases dans l'analyse du sous-canal de grappe d'assemblages  

Energy Technology Data Exchange (ETDEWEB)

In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include also influences of the multi-dimensional ...

2006-07-01

275

Two-phase flow modeling in the rod bundle subchannel analysis  

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows:In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include also ...

2004-07-01

276

Two-phase flow modeling in the rod bundle subchannel analysis  

International Nuclear Information System (INIS)

In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include also influences of the multi-dimensional ...

2006-01-01

277

Ultrasensitive laser isotope analysis in an ion-storage ring  

Energy Technology Data Exchange (ETDEWEB)

We propose a novel method for ultrasensitive isotope analysis that combines magnetic mass selection, resonant charge-exchange neutralization, and resonant laser ionizaion. Our method attains high isotopic abundance selectivity by means of continuous multistage separation of ions stored in a small ring. For the environmentally interesting case of /sup 90/Sr versus /sup 88/Sr we estimate that sensitivity better than 10/sup -15/ for a throughput of 10/sup 13/ atoms/sec and an efficiency (after the ion source) greater than 10% are readily achievable.

1985-09-01

278

The use of the isotope "3"2P in the study of some ecological aspects of a laboratory stream ecosystem  

International Nuclear Information System (INIS)

A laboratory stream consisting of two stream sections interrupted by two pools was filled with a mixture of tap water and organically enriched water from rivers nearby. Bottom sediment material, Potamogeton pectinatus, macro-invertebrate organisms, as well as the mosquito fish, Aplocheilichthys johnstonii were collected from rivers around Johannesburg and introduced into the laboratory stream. After initial acclimatization, the distribution of the isotope "3"2P through this laboratory stream was followed. Absorption of this isotope by benthic algae, Potamogeton pectinatus, several macro-invertebrate organisms as well as Aplocheilichthys johnstonii was recorded.

279

Spectroscopy of neutron-rich Fe isotopes populated in the "6"4Ni+"2"3"8U reaction  

International Nuclear Information System (INIS)

The neutron-rich Fe isotopes from A=61 to 66 were studied through multinucleon transfer reactions by bombarding a "2"3"8U target with a 400 MeV "6"4Ni beam. Unambiguous identification of prompt #gamma# rays belonging to each nucleus was achieved using coincidence relationships with the ions detected in a high-acceptance magnetic spectrometer. The new data extend our knowledge of the level structure of Fe isotopes, which is discussed in terms of the systematics of the region and compared with large-scale shell-model calculations.

2007-09-01

280

Separation of lithium isotopes by counter-current flow of the coexisting phases of a lithium-ammonia solution  

Energy Technology Data Exchange (ETDEWEB)

A weak shift of the isotope concentration ratio Li{sup 6}/Li{sup 7} was measured in the coexisting phases of the miscibility gap of lithium-ammonia solutions. Li{sup 6} is slightly enriched in the concentrated metallic phase (enrichment factor {alpha} = 1.009 {+-} 0.002). This effect can be enhanced in a counter-current column to yield any desired enrichment of the two isotopes. The counter current system and its operation were tested succesfully with a sodium-potassium-ammonia solution.

1991-12-01

281

Proton beam monitoring and forming on the target of isotope complex at INR linac  

International Nuclear Information System (INIS)

Special beam extraction channel is used at INR linac for isotope production. It starts from 160 MeV measuring and matching area of accelerator. This choice of beam extraction enables to direct to the target of isotope complex a proton beam of wide energy range up to 160 MeV. It is important for production of different types of nuclides. The measuring results of proton beam behavior in this region are presented. Required beam forming in 160 MeV measuring and matching area of accelerator and in beam extraction channel is discussed.

2010-01-01

282

Operation of a high temperature ion source at the helium-jet on-line isotope separator facility HELIOS  

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented. (orig.).

1985-02-01

283

Operation of a high temperature ion source at the helium-jet on-line isotope separator facility HELIOS  

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented.

1985-02-01

284

On Cost Estimate for Decommissioning of one Isotope Central  

International Nuclear Information System (INIS)

The main scope of this study has been to calculate the future cost for decommission and dismantling the Isotope central at the Studsvik site using the OMEGA CODE. Detailed empirical information is used in the study for 'bench-marking' purposes, in such cases when there is a need to supplement and correct field data from the industry. In the present study, data has been retrieved and organized such that the estimated costs for decommissioning of the Isotope Central become transparent and reliable. This approach gives a preliminary qualitative indication about the accuracy of the cost estimate delivered by the industry

1994-04-25

285

Hyperfine structure studies with the COMPLIS facility  

International Nuclear Information System (INIS)

COMPLIS is an experimental facility designed to carry out spectroscopic studies on radioisotopes produced by disintegration of elements available at CERN's Booster-ISOLDE on-line isotope separator. During recent series of experimental runs, hyperfine structure measurements have yielded information on nuclear moments and deformations of platinum and iridium isotopes. For the first time, population by #alpha#-decay from Hg was exploited to investigate "1"7"8"-"1"8"1Pt--the most neutron-deficient Pt isotopes yet studied. Successful measurements have recently been carried out on "1"8"2"-"1"8"9Ir.

1998-12-16

286

Generator coordinate method for triaxial quadrupole collective dynamics in strontium isotopes  

Energy Technology Data Exchange (ETDEWEB)

We discuss the algebraic structure of the generator coordinate method for triaxial quadrupole collective motion. The collective solutions are classified according to the representations of the permutation group of the intrinsic axes. Our method amounts to an approximate angular-momentum projection. We apply it to a study of the spherical-to-deformed-shape transition in light even strontium isotopes {sup 78-88}Sr. We find that triaxial configurations play a significant role in explaining the structure of the transitional isotopes {sup 80-82}Sr. (orig.).

1991-07-29

287

Extraction of selectively ionised atomic isotopes from a laser-induced plasma  

Energy Technology Data Exchange (ETDEWEB)

A laser-induced plasma of alkali atoms was studied with a view to efficient recovery of isotope ions, with small charge exchange losses. The electron temperature was measured by the double-probe method for several kinds of excitation schemes, which gave the relationship between temperature and the energy given to ions by laser photons. A charge exchange process between lithium isotopes was also studied in an electromagnetic field. It was shown that optimum electrostatic and magnetic field strength exist which maximise the 'separative power'.

1982-10-14

288

Enriched lithium collection from lithium plasma flow  

International Nuclear Information System (INIS)

In order to understand the physical processes concerned with the selective heating by ion cyclotron resonance and with the subsequent collection of heated particles, experiments were carried out with the extraction of lithium samples, enriched with "6Li isotopes. Probe and integral extractors allow to collect enriched Li at the end of the selective heating region. Surface density distribution on the collector and local isotopic content of lithium are measured, as a function of the screen height and the retarding potential. Dependence of the collected amount of lithium and of its isotopic content on the value of the magnetic field is also measured. 4 figs., 2 tabs., 5 refs.

289

Elemental and stable isotopic approaches for studying the organic and inorganic carbon components in natural samples  

Energy Technology Data Exchange (ETDEWEB)

The carbon cycle is an important part of major biogeochemical cycles. Many techniques may be used to characterize carbon amounts and sources in the environment. Here we first review the most popular techniques for the determination of organic and inorganic carbon concentrations. Decarbonatation techniques are also reviewed in details since it is often an important part of organic carbon analysis. The second part of this paper addresses the use of carbon stable isotopes to characterize organic carbon sources and processes in the environment. An overview of general stable isotopes background and terminology is given as well as the most popular analytical techniques.

2009-01-01

290

Turn-key Raman lidar for profiling atmospheric water vapor, clouds, and aerosols at the US Southern Great Plains Climate Study Site  

Energy Technology Data Exchange (ETDEWEB)

There are clearly identified scientific requirements for continuous profiling of atmospheric water vapor at the Department of Energy, Atmospheric Radiation Measurement program, Southern Great Plains CART (Cloud and Radiation Testbed) site in northern Oklahoma. Research conducted at several laboratories has demonstrated the suitability of Raman lidar for providing measurements that are an excellent match to those requirements. We have developed and installed a ruggedized Raman lidar system that resides permanently at the CART site, and that is computer automated to eliminate the requirements for operator interaction. In addition to the design goal of profiling water vapor through most of the troposphere during nighttime and through the boundary layer during daytime, the lidar provides quantitative characterizations of aerosols and clouds, including depolarization measurements for particle phase studies.

1997-12-31

291

Health-hazard evaluation report HETA 86-132-1780, Alyeska Pipeline Service Company, Valdez, Alaska  

Energy Technology Data Exchange (ETDEWEB)

A study was made of employee exposure to oil sludge and vapors during oil-sludge removal and maintenance activities at the Alyeska Pipeline Service Company's Ballast Water Treatment Facility, Valdez, Alaska. Total hydrocarbons, except benzene, toluene, and xylene, showed concentrations from 371 to 1228mg/m3. Of eight maintenance workers, five reported headache, dizziness, or nausea when working without a respirator. The authors conclude that workers were potentially exposed to benzene vapors and total hydrocarbon vapors exceeding the evaluation criteria for these substances. The authors recommend the use of respiratory protection measures to reduce exposures during work operations.

1987-02-01

292

Effect of different treatments on acid centers of very high silicon zeolites studied by ir spectroscopy  

Science.gov (United States)

Using the infrared spectroscopy method, we have studied the effect of thermal dehydration (under vacuum and in air) and treatment with water vapor on the acid centers of very high silicon zeolites of the ZSM type. We have shown that dehydration under vacuum and in air completely and irreversibly removes the OH groups at 1120/sup 0/K, while treatment with water vapor removes these groups at 770/sup 0/K. The Lewis acid centers of dehydrated zeolites (represented by two types of centers) are more heat-stable than the Bronsted acid centers, but the vapor treatment at 1020/sup 0/K leads to the disappearance of the Lewis acid centers. In this work, we discuss the reasons for destruction of the acid centers of the zeolites under different treatment conditions.

1986-08-01

293

Dynamic and static error analyses of neutron radiography testing  

Energy Technology Data Exchange (ETDEWEB)

Neutron radiography systems are being used for real-time visualization of the dynamic behavior as well as time-averaged measurements of spatial vapor fraction distributions for two phase fluids. The data in the form of video images are typically recorded on videotape at 30 frames per second. Image analysis of he video pictures is used to extract time-dependent or time-averaged data. The determination of the average vapor fraction requires averaging of the logarithm of time-dependent intensity measurements of the neutron beam (gray scale distribution of the image) that passes through the fluid. This could be significantly different than averaging the intensity of the transmitted beam and then taking the logarithm of that term. This difference is termed the dynamic error (error in the time-averaged vapor fractions due to the inherent time-dependence of the measured data) and is separate from the static error (statistical ...

1999-03-01

294

Characterization of physically vapor deposited AF2400 thin films  

Energy Technology Data Exchange (ETDEWEB)

Anti-reflective coatings made with Teflon AF2400 had the highest damage thresholds recorded for physical vapor deposited coatings at the Lawrence Livermore National Laboratory damage facility. Physical vapor deposited layers of Teflon AF2400, a perfluorinated amorphous polymer, maintained the bulk optical properties of a high transmittance from 200 nm to 1600 nm, and a low refractive index. In addition, the refractive index can be intentionally reduced by control of two common deposition parameters, deposition rate and substrate temperature. Scanning electron microscopy and nuclear magnetic resonance observations indicated that morphological changes caused the variations in the refractive index rather than compositional changes. The coatings adhered to fused silica and silicon wafers under normal laboratory handling conditions.

1993-11-01

295

Analysis of plasma treatment and vapor heat treatment for thin-film transistors by extracting trap densities at front and back interfaces  

International Nuclear Information System (INIS)

Hydrogen (H) plasma treatment, oxygen (O) plasma treatment and water (H_2O)-vapor heat treatment for polycrystalline-silicon (poly-Si) thin-film transistors (TFTs) have been analyzed by separately extracting trap density at a front silicon-oxide interface (D_F) and trap density at a back interface (D_B). It is found that the H plasma treatment is apt to generate D_F and D_B. The O plasma treatment reduces D_F, while the H_2O-vapor heat treatment reduces both D_F and D_B. Improvement of transistor characteristics of poly-Si TFTs depends on understanding these results.

2004-05-17

297

Steady-state isotopic transient kinetic analysis investigation of CO-O_2 and CO-NO reactions over a commercial automotive catalyst  

International Nuclear Information System (INIS)

In this paper, steady-state isotopic transient kinetic analysis (SSITKA) is used to study two model reactions, CO oxidation and CO-NO reactions, on a typical formulation of a three-way auto-catalyst. Under steady-state conditions, abrupt switches in the isotopic composition of CO ("1"2C"1"6O/"1"3C"1"8O) were carried out to produce isotopic transients in both labeled reactants and products. Along with the determination of the average surface lifetimes and concentrations of reaction intermediates, an analysis of the transient responses along the carbon reaction pathway indicated that the distribution of active sites for the formation of CO_2 was bimodal for both reactions. Furthermore, relatively few surface sites contributed to the overall reaction rate.

1991-08-25

298

Rb-Sr isotopic studies on granodioritic rocks from the Mecsek mountains, Hungary  

Energy Technology Data Exchange (ETDEWEB)

New isotopic age determinations carried out with the rubidium-strontium method on granodioritic basement rocks from the Mecsek Mountains in Southeastern Transdanubia give further support to assumptions on a polyphase development of the Mecsek crystalline. As shown by initial Sr isotopic ratios, the protolith of the granodioritic assemblage of polymetamorphic-anatectic origin must have been strongly basic in its composition. The scatter of individual model ages obtained on total rock samples reflects the polymetamorphic-polytectonized character of the basement, and suggests that following a primary granitization process secondary events might have led to the total or partial recrystallization of the rocks in question. The tectonic development of the basement crystalline as reflected in the isotopic age data closed at about 270+-20 million years ago, with processes causing retrograde changes in the crystalline as a whole but ...

1981-01-01

299

Precise lithium isotopic analysis by thermal ionization mass spectrometry using lithium phosphate as an ion source material  

International Nuclear Information System (INIS)

A high-precision Li isotope analysis was developed for determining the Li"+ ion emitted from lithium phosphate as an ion source material by a Re double-filament ionization method in the thermal ionization mass spectrometry. In this method, Li isotopic fractionation is distinctly less sensitive to the filament temperature than those in the previous methods, and stable and high ion beam intensity of more than 8 x 10"-"1"1 A for "7Li is obtained. These advantages in determining the "7Li/"6Li ratio result in the analytical reproducibility of 0.26 per mille (1#sigma#). Furthermore, the sample preparation is simple and the low temperature (850degC) required by this method ensures the analysis of the isotopic composition of small amounts of Li with less influence of Li contamination to the sample, compared with the previous methods. (author).

300

Origin of water salinity in the coastal Sarafand aquifer (South-Lebanon)  

International Nuclear Information System (INIS)

Author.The geochemical and isotopic study, based on the analysis of twenty water samples from well in the coastal plain of Sarafand (South-Lebanon), permit to eliminate the hypothesis of marine intrusion in this aquifer. The increase of salinity observed in certain wells is due to the contamination of cretaceous aquifer water by the quaternary formations. The two poles of mixing are respectively characterized: by weak tritium contents (between 2 and 3 UT) and a value of stable isotopes (-5,9<0,18<-5,5) corresponding to the appearance of cretaceous formation area; by the high tritium contents and enrichment relative to heavy isotope in the mineralized water of superficial formations. On the other hand, the isotope contents permit the set a rapid renewal of the cretaceous aquifer water due to quick circulation in the Karstic system

301

Nuclear Charge Radius of Lithium-11  

Energy Technology Data Exchange (ETDEWEB)

We have determined the nuclear charge radius of 11Li by high-precision laser spectroscopy. The experiment was performed at the TRIUMF-ISAC facility where the 7Li-11Li isotope shift was measured in the 2s to 3s electronic transition using Doppler-free two-photon spectroscopy with a relative accuracy better than 10 5. The accuracy reached in previous experiments on the other lithium isotopes was improved. Most of the isotope shifts measured in the experiment are due to difference in the mass of the nuclei but small contributions are produced by the change in proton distribution, QED and relativistic effects have to be taken into account as well. By comparing the experimental results with sophisticated atomic calculations of the mass dependent effect the nuclear charge radii of the lithium isotopes are found to decrease monotonically from 6Li to 9Li while the nuclear charge radius of 11Li is about 11% ...

2006-07-01

302

New and old Sn isomers produced in heavy-ion collisions  

International Nuclear Information System (INIS)

The energy level schemes of tin isotopes produced in the heavy ion reactions are presented. The using of #gamma# spectroscopy technique is also described. 4 refs, 12 figs.

1991-12-01

303

Neutrons from interactions of deuterons with lithium isotopes  

International Nuclear Information System (INIS)

Neutron yield from the "6","7Li + d reaction has been investigated. The results obtained are compared with the published data with some theoretical models.

304

Lithium isotopic separation: preliminary studies; Separacao isotopica de litio: estudos preliminares  

Energy Technology Data Exchange (ETDEWEB)

In order to get the separation of natural isotopes of lithium by electrolytic amalgamation, an electrolytic cell with a confined mercury cathode was used to obtain data for the design of a separation stage. The initial work was followed by the design of a moving mercury cathode electrolytic cell and three experiments with six batches stages were performed for the determination of the elementary separation factor. The value obtained, 1.053, was ill agreement: with the specialized literature. It was verified in all experiments that the lithium - 6 isotope concentrated in the amalgam phase and that the lithium - 7 isotope concentrated in the aqueous phase. A stainless-steel cathode for the decomposition of the lithium amalgam and the selective desamalgamation were also studied. In view of the results obtained, a five stages continuous scheme was proposed. (author)

1998-07-01

305

Limitations of silicon devices for quantum computing  

Energy Technology Data Exchange (ETDEWEB)

There is considerable interest in the use of silicon devices as qubits for quantum computing. The existence of nuclear spin in a silicon isotope and the complex band structure of silicon are unfavourable for this application of silicon devices. (viewpoint)

2004-04-28

307

Failure location analysis for tagged reactor assemblies  

Science.gov (United States)

The location of defective LMFBR fuel pins by the determination of gas tag isotopic ratios is discussed. The application of this method to the FFTF Reactor briefly described.

1979-03-01

308

Elastic and inelastic 27.2 MeV alpha particle scattering on the nickel isotopes  

International Nuclear Information System (INIS)

Russian 1974. USSR Alekseev, VV Nemets, OF Stryuk, Yu.S. Tokarevskij,

1974-01-29

309

Clinical spectrum  

Energy Technology Data Exchange (ETDEWEB)

A tunable diode laser is used to obtain infrared spectra of carbon dioxide in biological materials. The spectral resolution is sufficient to readily distinguish differing isotopic species. The technique may prove useful in clinical tests.

1987-11-01

310

CONSEQUENCES OF DOMINANCE-MEDIATED HABITAT SEGREGATION IN AMERICAN REDSTARTS DURING THE NONBREEDING SEASON  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

311

Big bang nucleosynthesis  

Energy Technology Data Exchange (ETDEWEB)

A brief review of standard big bang nucleosynthesis theory and the related observations of the light element isotopes is presented. Implications of BBN on chemical evolution and constraints on particle properties will also be discussed.

2000-01-01

313

Age determination of meteorites using radioactive nuclides  

Energy Technology Data Exchange (ETDEWEB)

Recently, the precise isotope ratios of some refractory elements in meteorites have been reported using inductively coupled plasma mass spectrometry. The in situ decay of {sup 182}Hf (T{sub 1/2}=9 Myr), which was produced at the latest nucleosynthesis, is recognized in many meteorites as isotopic anomalies of its daughter isotope, {sup 182}W. The degrees of relative {sup 182}W isotopic deviation in extra-terrestrial and terrestrial silicate samples vary from +0.3% to {+-}0% related to the size of their parent bodies. One ready interpretation of its correlation is the difference in timing of metal-silicate separation in the parent bodies. Between the earth and meteorite parent bodies, the difference is calculated to be about four times of the half-life of {sup 182}Hf, equivalent to 36 Myr. (author)

2002-07-01

314

A method for determining the origin of bitumoids  

Energy Technology Data Exchange (ETDEWEB)

The invention is associated with organic geochemistry and may be used in conducting geological exploration operations for oil and gas. The purpose of the invention is to increase the precision of the method for determining the genesis of bitumoids. This is achieved through determining the isotopic composition of nickel or vanadium and from the anomalously high values of the isotopic ratio of Ni-58 to Ni-62 or from the anomalously low values of the isotopic ratio of vanadium, a conclusion is drawn about the epigenetic nature of the bitumoids. The proposed method is characterized by greater resolution due to the fact that the values of the isotopic ratios for oil bearing and water bearing structures are essentially not superimposed. The proposed method exceeds the resolution of metal metering studies in conducting geological exploration for oil and gas by 2 to 3 times.

1983-01-01

315

#beta#-decay log(ft) value for lithium isotopes  

International Nuclear Information System (INIS)

... Inst. of Modern Physics 7-5022-0983-2 180 p. beta decay ft value ground states

1993-12-01

316

Universal model for water costs of gas exchange by animals and plants  

UK PubMed Central (United Kingdom)

For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for...Full Text Available

2010-05-04

317

Plasma Treatment within Dielectric Fluids.  

Science.gov (United States)

A dielectric liquid having entrained bubbles of gas or vapor is subjected to an electric field applied between spaced electrodes (112, 116) which generates microdischarges (and thus plasma) within the bubbles, allowing modification of the properties of th...

2003-01-01

318

Nomographs for soil vapor extraction and off-gas treatment by activated carbon adsorption  

Energy Technology Data Exchange (ETDEWEB)

Soil vapor extraction (SVE) is a widely accepted in-place treatment technology that uses forced air to remove contaminant vapors from zones of permeable vapor flow, thereby enhancing the volatilization of contaminants from the subsurface. The resulting off-gases are contaminated with volatiles and semi-volatiles and have to treated by catalytic or thermal destruction systems, activated carbon adsorbers, or bioreactors. Of these, activated carbon adsorption is the most commonly used technology. From the theoretical foundation of SVE and carbon adsorption, two nomographs were developed for remedial investigation, feasibility studies, planning, operation, and preliminary design purposes. An advantage of such nomographs is that they graphically indicate the sensitivity of the remediation process to different design parameters and critical ranges within a given parameter. In effect, nomographs can help to foster an intuitive ...

1997-12-31

319

New intelligent monitor for CANDU type NPP  

International Nuclear Information System (INIS)

Nuclear energy provides a third of Europe's electricity with nearly no greenhouse-gas emissions. Sustained efforts are now being conducted to harmonize regulations all over Europe through WENRA and to converge on technical nuclear safety practices within the TSO network ETSON (European Technical Safety Organizations Network). In CANDU type NPP the tritiated water occurs by the neutron bombardment of deuterium. The tritiated water vapors imply health hazard (in the critical organs of the body the water presents a 10 day average biological half-life) and the early detection in nuclear plants of tritium emissions is important because the tritiated water vapors have the same characteristics as of atmospheric water vapors. By detecting tritiated vapors, the monitoring system ensures the following objectives: (a) indicates levels of tritium generally due to heavy water leakage, (b) reduces the possibility of ...

2009-10-12

320

Laboratory Investigation of Steam Adsorption in Geothermal Reservoir Rocks.  

Science.gov (United States)

Some vapor-dominated geothermal reservoirs and low-permeability gas reservoirs exhibit anomalous behavior that may be caused by surface adsorption. For example, geothermal reservoirs in the Larderello area of Italy and reservoirs in the Geysers Geothermal...

1988-01-01

321

Determination of vapor-liquid equilibrium data and decontamination factors needed for the development of evaporator technology for use in volume reduction of radioactive waste streams  

Energy Technology Data Exchange (ETDEWEB)

A program is currently in progress at Argonne National Laboratory to evaluate and develop evaporator technology for concentrating radioactive waste streams. By concentrating radioactive waste streams, disposal costs can be significantly reduced. To effectively reduce the volume of waste, the evaporator must achieve high decontamination factors so that the distillate is sufficiently free of radioactive material. One technology that shows a great deal of potential for this application is being developed by LICON, Inc. In this program, Argonne plans to apply LICON`s evaporator designs to the processing of radioactive solutions. Concepts that need to be incorporated into the design of the evaporator include, criticality safety, remote operation and maintenance, and materials of construction. To design an effective process for concentrating waste streams, both solubility and vapor-liquid equilibrium data are needed. The key issue, however, is the high decontamination ...

1993-10-01

322

Comparison of Indoor Mercury Vapor in Common Areas of Residential Buildings with Outdoor Levels in a Community Where Mercury Is Used for Cultural Purposes  

UK PubMed Central (United Kingdom)

Elemental mercury has been imbued with magical properties for millennia, and various cultures use elemental mercury in a variety of superstitious and cultural practices, raising health concerns for...Full Text Available

2006-01-01

323

Characterization of MJO ... - Microwave Limb Sounder (MLS) - NASA  

Science.gov (United States)

Feb 15, 2008 ... hydrological properties (e.g., hydrometeor budgets, cloud ice/water, transports ... cloud fraction, mass and particle size. In combination, these .... anomaly in the LS is not simply due isentropic movement of water vapor relative ...

324

4 - NASA Technical Reports Server  

Science.gov (United States)

Mar 1, 2011 ... The movement of hydrothermal fluids and/or fumarolic vapors through local rocks prior ... The Solar Energetic Particle Event of December 14, 2006 .... for measurement of non-precipitating cloud hydrometeors and aerosols, ...

325

Water chemistry in the water-vapor circuit at Angra II: evolution of the operational concepts and canceling of the condensed polishing system; Quimica da agua do circuito agua-vapor de Angra II: evolucao do conceito operacional e o cancelamento do sistema de polimento do condensado  

Energy Technology Data Exchange (ETDEWEB)

The chemical operational concept originally established for the water-steam circuit of Angra II nuclear power plant has undergone several modifications throughout the development of the project. This work discusses the two main modifications giving special attention to the costs involved and analyses the main points and the consequences of such modifications 1 ref., 4 figs., 2 tabs.

1995-12-31

326

Thermodynamic modeling of acidic gas solubility in aqueous solutions of MEA, MDEA and MEA-MDEA blends  

DEFF Research Database (Denmark)

The thermodynamic framework that was developed in a previous work [Vrachnos et al. Ind. Eng. Chem. Res. 2004, 43, 2798] for the description of chemical and vapor-liquid equilibria of carbon dioxide, hydrogen sulfide, and their mixtures in aqueous methyldiethanolamine (MDEA) solutions is revised and extended in this study to the absorption of carbon dioxide into aqueous monoethanolamine (MEA) solutions and aqueous MDEA-MEA blends. The results of the model are compared with experimental data taken from the literature. Very satisfactory predictions of acidic gas vapor-liquid equilibrium over MDEA, MEA, and their blends at various concentrations, acidic gas loadings, and temperatures are obtained.

2006-01-01

327

The natural convection cooling with vaporizing deuterium for the horizontally arranged cold neutron source of the HFR - Grenoble  

International Nuclear Information System (INIS)

Natural convection of vaporizing Deuterium at 25 K transports the heat generated in the moderator cell of the cold neutron source to a He cooled condenser. The thermohydraulics of this thermosiphon were precalculated and the results verified by experiments in a 1:1 model using D_2 as fluid. The experimental results show that the thermosiphon operates stable. The demanded liquid content of the cell as well as wall temperatures below 50 K can be ensured by a proper design of the cell outlet flow geometry. A 7 min. loss of cryogenic power results in transient temperatures of the cell wall of not more than 300 K.

1991-08-01

328

Production of polarized negative ion beams by collisional pumping  

Energy Technology Data Exchange (ETDEWEB)

The production of polarized negative ion beams by collisional pumping is described. Collisional pumping utilizes repeated charge changing collisions in a thick electron-spin-polarized gas or vapor target to form a polarized fast atom beam. The polarized fast atom beam is then partially converted into a polarized negative ion beam in a vapor target. Analysis is presented for a hydrogen beam passing through either a thick polarized H atom target or a thick polarized alkali target. Large polarizations and large currents may be possible.

1983-01-01

329

Production of polarized negative ion beams by ''collisional pumping''  

Energy Technology Data Exchange (ETDEWEB)

The production of polarized negative ion beams by ''collisional pumping'' is described. Collisional pumping utilizes repeated charge changing collisions in a thick electron-spin-polarized gas or vapor target to form a polarized fast atom beam. The polarized fast atom beam is then partially converted into a polarized negative ion beam in a vapor target. Analysis is presented for a hydrogen beam passing through either a thick polarized H atom target or a thick polarized alkali target. Large polarizations and large currents may be possible.

1984-03-01

330

Plasma production and flow in negative ion beams  

Science.gov (United States)

Plasma generated in low-density vapor by a negative ion beam has been studied experimentally and computationally. We show that space charge neutralization of the beam occurs at very low vapor density, and that correspondingly the electron density may be much less than the beam and plasma ion densities. When there is a large local gas density, as in a charge changing cell, the resulting high electron density is also localized to the same region. Therefore, very few electrons will reach a negative ion accelerator even if it is placed one or two beam diameters from such a cell.

1977-09-21

331

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO{sub 2}) in aqueous methyldiethanolamine (MDEA) solutions  

Energy Technology Data Exchange (ETDEWEB)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO{sub 2}) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO{sub 2} were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-15

332

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO_2) in aqueous methyldiethanolamine (MDEA) solutions  

International Nuclear Information System (INIS)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-01

333

Mercury vacuum cleaner operational test and evaluation  

Energy Technology Data Exchange (ETDEWEB)

The Dental Investigation Service, USAFSAM, Brooks AFB, has outlined the need for a vacuum unit to be used in the Air Force dental clinics. The unit must be capable of effectively picking up mercury and at the same time not redistribute mercury vapors throughout the dental clinic during normal operations or mercury-spill situations. The Dental Investigation Service selected the MRS-3, Minuteman Mercury Recovery System, product of American Cleaning Equipment Corporation as the mercury vacuum to be used for T E. The USAF OEHL/ECH was requested by the Dental Investigation Service to perform the T E on the MRS-3 for possible health hazards due to exposures of mercury vapors.

1981-03-01

334

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

Energy Technology Data Exchange (ETDEWEB)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

1992-03-01

335

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

International Nuclear Information System (INIS)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

336

Analysis of hydrogen vehicles with cryogenic high pressure storage  

Energy Technology Data Exchange (ETDEWEB)

Insulated pressure vessels are cryogenic-capable pressure vessels that can be fueled with liquid hydrogen (LIQ) or ambient-temperature compressed hydrogen (CH2). Insulated pressure vessels offer the advantages of liquid hydrogen tanks (low weight and volume), with reduced disadvantages (lower energy requirement for hydrogen liquefaction and reduced evaporative losses). This paper shows an evaluation of the applicability of the insulated pressure vessels for light-duty vehicles. The paper shows an evaluation of evaporative losses and insulation requirements and a description of the current experimental plans for testing insulated pressure vessels. The results show significant advantages to the use of insulated pressure vessels for light-duty vehicles.

1998-06-19

338

Stable isotopes in plant nutrition, soil fertility and environmental studies  

International Nuclear Information System (INIS)

The individual contributions in these proceedings are indexed separately. Main topics covered include the measurement of biological nitrogen fixation, studies of soil organic matter, investigations of nutrient uptake and use by plants, studies of plant metabolism and new methodologies in the analysis of stable isotopes. Refs, figs and tabs.

1990-10-01

339

Solvent isotope effect on the quartet #-># doublet intersystem crossing efficiencies of Cr(bpy)_3"3"+ and Cr(phen)_3"3"+"1  

International Nuclear Information System (INIS)

The intensity of luminescence from the "2E state of Cr(bpy)_3"3"+ (bpy = 2, 2'-bipyridine) is lower in D_2O, although the "2E lifetime is unchanged, indicating that the "4T_2 (precursor to "2E) is sensitive to the isotopic nature of the solvent. A photophysical mechanism is proposed for Cr(NN)_3"3"+ complexes.

340

Search for magnetic rotation in {sup 202}Pb and {sup 203}Pb  

Energy Technology Data Exchange (ETDEWEB)

High-spin states in {sup 202}Pb and {sup 203}Pb have been investigated by in-beam {gamma}-ray spectroscopy following the reaction {sup 198}Pt({sup 9}Be,xn). A search for magnetic rotational bands in these isotopes confirmed one of the two bands previously assigned to {sup 202}Pb and revealed a new band in this isotope. No evidence for magnetic rotation has been found in {sup 203}Pb. (orig.)

2000-11-01

341

Quantum theory of light interstitial diffusion and other aspects of inert gas motion in solids  

International Nuclear Information System (INIS)

Most diffusion phenomena in solids can be understood (or sometimes misunderstood) on a purely classical model. For light interstitials (hydrogen isotopes, the positive muon, and potentially He) there may be anomalous temperature dependences, and isotope effects, and anomalous response to electric fields and temperature gradients. Some of these anomalies are quantal in origin, and will be discussed. (author).

1980-03-01

342

Quantitative evaluation of simultaneous reconstruction with model-based crosstalk compensation for 99mTc?123I dual-isotope simultaneous acquisition brain SPECT  

UK PubMed Central (United Kingdom)

A model-based method has been previously developed to estimate and compensate for the crosstalk and downscatter contamination in simultaneous 123I∕99mTc dual-isotope SPECT...Full Text Available

2009-06-01

343

Preparation and separation of Tc-97 and development and application of a mass spectrometrical isotope dilution analysis for trace analysis of technetium, molybdenum and ruthenium. Herstellung und Isolierung von /sup 97/Tc sowie Entwicklung und Anwendung einer massenspektrometrischen Isotopenverduennungsanalyse zur Technetium-, Molybdaen- und Rutheniumspurenanalyse  

Energy Technology Data Exchange (ETDEWEB)

The thesis explains the development of a mass spectrometerical isotope dilution analysis (MS/DA) for determining trace amounts of Tc. The Tc-97 isotope has been prepared by in-core irradiation of Ru of natural isotopic composition, and used as the indicator isotope. For separation of Tc-97 from the Ru matrix, a method has been developed to quantitatively separate Tc-97 from a high Ru surplus. For determining the isotope ratio for the MS/DA, a mass spectrometrical measuring technique has been found which allows reproducible measurement of the Tc-99/Tc-97 isotope ratio. Positive and, for the first time, also negative thermoionisation has been used as a method of selective ionisation of Tc. The applicability of the MS/DA for Tc trace analysis has been verified using two Al foils doped with Tc-99 or Mo-98, respectively. These have been irradiated in a nuclear ...

1984-01-01

344

Nuclear effective forces and isotope shifts  

Energy Technology Data Exchange (ETDEWEB)

Presently available relativistic and nonrelativistic effective interactions do not predict the same behavior for the isotope shifts in the Pb region.We analyze this difference and find that it is related to the characteristics of the spin-orbit term used in the parametrizations. We show that a simple modification of the spin-orbit contribution to the nonrelativistic Skyrme functional solves this problem. ((orig.))

1995-02-27

345

Nitrogen isotope identification by Bragg-curve spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

Projectilelike fragments following the 80 MeV /sup 16/O+/sup 27/Al reaction have been detected using a Bragg-curve spectroscopy ionization chamber (BCS-IC). The atomic number is deduced from the Bragg-peak amplitude. Nitrogen isotopes are clearly resolved using either range or energy loss data. This is the first application of the BCS method for complete ion identification in a heavy-ion-induced reaction.

1984-07-14

346

Nitrogen isotope identification by Bragg-curve spectroscopy  

International Nuclear Information System (INIS)

Projectilelike fragments following the 80 MeV "1"6O+"2"7Al reaction have been detected using a Bragg-curve spectroscopy ionization chamber (BCS-IC). The atomic number is deduced from the Bragg-peak amplitude. Nitrogen isotopes are clearly resolved using either range or energy loss data. This is the first application of the BCS method for complete ion identification in a heavy-ion-induced reaction.

347

New nuclei near the proton drip line around Z=40  

International Nuclear Information System (INIS)

A "9"2Mo beam with an energy of E/A=70 MeV has been used to produce new isotopes near the proton drip line. The Michigan State University National Superconducting Cyclotron Laboratory A1200 fragment separator was used to detect the new isotopes "7"8Y, "8"2Nb, "8"5Mo, "8"6Tc, and "8"9","9"0Ru.

348

New nuclei near the proton drip line around Z =40  

Science.gov (United States)

A {sup 92}Mo beam with an energy of {ital E}/{ital A}=70 MeV has been used to produce new isotopes near the proton drip line. The Michigan State University National Superconducting Cyclotron Laboratory A1200 fragment separator was used to detect the new isotopes {sup 78}Y, {sup 82}Nb, {sup 85}Mo, {sup 86}Tc, and {sup 89,90}Ru.

1992-12-01

349

Lithium isotope ratio in Population II halo dwarfs - a proposed test of the late decaying massive particle nucleosynthesis scenario  

Energy Technology Data Exchange (ETDEWEB)

It is shown that observations of the lithium isotope ratio in high surface temperature Population II stars may be critical to cosmological nucleosynthesis models. In particular, decaying particle scenarios as derived in some supersymmetric models may stand or fall with such observations. 18 references.

1988-06-01

350

Integrated system for production of neutronics and photonics calculational constants. Volume 15, Part D. The LLL Evaluated Nuclear Data Library (ENDL): descriptions of individual evaluations for Z = 90 to 98  

Science.gov (United States)

Evaluation procedures used to produce sets of evaluated data for the 33 heavy isotopes that fall in the range Z = 90 to Z = 98 are described. At the beginning of the discussion for each individual isotope, a computer-generated listing is given which summarizes the main properties of the data sets that are contained in the evaluation. (RWR)

1977-06-17

351

Identification of source and recharge zones in an aquifer system from water stable isotope. Case Study Bajo Cauca Antioqueno  

International Nuclear Information System (INIS)

Hydrology and hydrogeochemical are auxiliary techniques to valid conceptual hydrogeology an recharge models. Stable isotopes from water trace sources and path flow and Tritium indicates age. This paper is about the use of D 18, D2H y 3H to study the aquifer system on Bajo Cauca antioqueno.

352

Hyperfine anomaly measurements in francium isotopes and the radial distribution of neutrons  

International Nuclear Information System (INIS)

We have performed precision measurements in a magneto-optical trap of the 7P1/2 hyperfine structure of the isotopes 209-210Fr. The ratio of these hyperfine constants to the previously measured 7S1/2 ground state values reveals a significant hyperfine anomaly. This anomaly results from the different radial dependence of the electron density in the two atomic levels. The measurements are sensitive to changes in the radial distribution of the neutron magnetism.

1999-09-01

353

Hydrogen, Oxygen, and Carbon Isotope Ratios of Cellulose from Submerged Aquatic Crassulacean Acid Metabolism and Non-Crassulacean Acid Metabolism Plants  

UK PubMed Central (United Kingdom)

Isotope ratios of cellulose and cellulose nitrate from aquatic Crassulacean acid metabolism (CAM) and non-CAM plants were determined. Cellulose oxygen istope ratios for all plants that grew together...Full Text Available

1984-09-01

354

Evaluation of prompt neutron spectra from fission of americium isotopes  

Energy Technology Data Exchange (ETDEWEB)

Prompt neutron spectra for Am isotopes ({sup 241}Am, {sup 242m}Am, {sup 243}Am) were calculated on the basis of a modified version of the Madland-Nix model combined with multimodal fission model. The predicted spectra were found to be in fair agreement with recent data. (author)

2002-06-01

355

Enrichment of americium 242m and americium 242 isotopes by the Szilard-Chalmers method using an americium-242 diphthalocyanine complex  

Science.gov (United States)

Americium 242m and americium 242 were prepared by reactor irradiation of americium 241 as its diphthalocyanine complex. The product atoms were extracted from the parent isotope at an enrichment factor of 10. A Dowex 50 chromatographic column raised the factor to 24.6.

1987-05-01

356

Enrichment of americium 242m and americium 242 isotopes by the Szilard-Chalmers method using an americium-242 diphthalocyanine complex  

International Nuclear Information System (INIS)

Americium 242m and americium 242 were prepared by reactor irradiation of americium 241 as its diphthalocyanine complex. The product atoms were extracted from the parent isotope at an enrichment factor of 10. A Dowex 50 chromatographic column raised the factor to 24.6.

357

Development of an experimental installation for short-lived isotopes production in INR linac  

International Nuclear Information System (INIS)

A possibility of short-lived isotopes production in inter-tank section between the first and the second drift tube tanks (20.45 MeV) in INR linac is considered. At the initial stage the main efforts are concentrated on production of fluorine-18 used for positron emission tomography. The results of beam forming calculations, target heating calculations, equipment activation calculations as well as installation configuration and design are presented.

2010-01-01

358

Cold fusion method  

International Nuclear Information System (INIS)

In a cold fusion method by electrolysis, a hydrogen occluding material mainly comprising vanadium is used as a material for a negative electrode, and lithium isotopes are incorporated in the material by more than 93%. That is, the ratio of lithium 7 ("7Li) isotope is increased to higher than the natural existent ratio, so that tritium ("3H) concentration in the hydrogen occluding material can be increased, to attain energy at high efficiency. (T.M.).

1993-03-02

359

Application of isotope-excitation x-ray fluorescence (XRF) analysis for aluminium production  

International Nuclear Information System (INIS)

An energy sensitive Si(Li) detector XRF analyzer built by ATOMKI, Hungary, has been applied for various analytical purposes in alumina production at the Almasfuezitoe Alumina Company, Hungary. Specifically, the CaO content in red mud was determined by the new XRF technique using isotope excitation sources. The analysis of other components is under way. (R.P.).

360

Strontium isotope ratios and the origin of anorthosites  

Energy Technology Data Exchange (ETDEWEB)

Anorthosites are rocks consisting almost completely of calcic plagioclase, usually from andesine to labradorite. They are not widespread, and until recently were of no economic interest. However, with the advance of the new global tectonics, which has excited considerable interest in the structure and composition of upper-mantle rocks, interest in the anorthosites has grown. This has particularly been the case since the discovery of anorthosites on the moon, where they appear to be more widespread than on the earth. Data have recently been obtained on the strontium isotope compositions of anorthosite intrusions in the Dzhugdzhur-Stanovoy zone and in the rocks surrounding them, which have revealed some unexpected features. The paper describes the geological features of anorthosites, initial concepts on strontium isotope geochemistry, strontium isotope compositions of this region, and discusses some genetic consequences from ...

1986-01-01

361

Myocardial perfusion SPECT in patients after myocardial infarction: Comparison of "2"0"1Tl and dual-isotope protocol (rest "2"0"1Tl/stress "9"9"mTc tetrofosmin)  

International Nuclear Information System (INIS)

The diagnostic accuracy is compared of the dual-isotope protocol and the conventional "2"0"1Tl protocol, for detection of the coronary artery disease (CAD) using data on a total of 69 patients after myocardial infarction (MI). The "2"0"1Tl protocol was used to examine 44 patients, the dual-isotope protocol was used with 25 patients. All patients were examined by coronarography; a narrowing of the artery by more than 50 % was considered significant for CAD. The sensitivity, specificity and diagnostic accuracy was 97.7 %, 100 % and 97.7 % resp. for the "2"0"1Tl protocol, and 95.2 %, 75 % and 92 % resp. for the dual-isotope protocol. A higher diagnostic accuracy of the dual-isotope protocol has not been proven, and the "2"0"1Tl protocol continues to be used for examinations of patients after MI

1998-08-01

362

Large deformation change in iridium isotopes from laser spectroscopy  

International Nuclear Information System (INIS)

Laser spectroscopy measurements have been performed on neutron-deficient iridium isotopes. The hyperfine structure and isotope shift of the optical Ir I transition 5d"76s"2 "4F_9_/_2#->#5d"76s6p "6F_1_1_/_2 have been studied for the "1"8"2"-"1"8"9Ir, "1"8"0Ir"m and "1"9"1","1"9"3Ir isotopes. The nuclear magnetic and quadrupole moments were obtained from the hyperfine splitting measurements and the changes of the mean square charge radii from the isotope shift measurements. A large deformation change between "1"8"7Ir and "1"8"6Ir and between "1"8"6Ir"m and "1"8"6Ir"g has been observed.

1999-11-16

363

Identification of recharge sources and dating of groundwater using isotope and CFC techniques  

International Nuclear Information System (INIS)

Due to severe drought conditions in Pakistan over the past several years, most of the areas are facing extinction of its potable water reserves and inadequate replenishment of groundwater aquifers. Due to over exploitation, the groundwater flow dynamics is changing and water quality is degrading due to induced infiltration from polluted surface sources. Isotope hydrology is relatively a new discipline having great potential for studying various water-related problems. RIAD, PINSTECH has established analytical facilities for commonly used environmental isotopes and applied to investigate various hydrological problems. This paper briefly describes practical examples on recharge mechanism and dating of groundwater in Lahore and Ziarat areas using isotopes like deuterium (/sup 2/H), Oxygen-18 (/sup 18/O), Tritium (/sup 3/H) and CFCs in water. In Lahore, the areas having different contribution of the river Ravi in groundwater ...

2004-06-07

364

Development of Improved Burnable Poisons for Commercial Nuclear Power Reactors  

Energy Technology Data Exchange (ETDEWEB)

Burnable poisons are used in nuclear reactors to produce a more level distribution of power in the reactor core and to reduce to necessity for a large control system. An ideal burnable poison would burn at the same rate as the fuel. In this study, separation of neutron-absorbing isotopes was investigated in order to eliminate isotopes that remain as absorbers at the end of fuel life, thus reducing useful fuel life. The isotopes Gd-157, Dy-164, and Er-167 were found to have desirable properties. These isotopes were separated from naturally occurring elements by means of plasma separation to evaluate feasibility and cost. It was found that pure Gd-157 could save approximately $6 million at the end of four years. However, the cost of separation, using the existing facility, made separation cost- ineffective. Using a magnet with three times the field strength is expected to reduce the cost by a factor of ...

2003-09-30

365

Nuclear charge radii of light isotopes based on frequency comb measurements  

Energy Technology Data Exchange (ETDEWEB)

Optical frequency comb technology has been used in this work for the first time to investigate the nuclear structure of light radioactive isotopes. Therefore, three laser systems were stabilized with different techniques to accurately known optical frequencies and used in two specialized experiments. Absolute transition frequency measurements of lithium and beryllium isotopes were performed with accuracy on the order of 10{sup -10}. Such a high accuracy is required for the light elements since the nuclear volume effect has only a 10{sup -9} contribution to the total transition frequency. For beryllium, the isotope shift was determined with an accuracy that is sufficient to extract information about the proton distribution inside the nucleus. A Doppler-free two-photon spectroscopy on the stable lithium isotopes {sup 6,7}Li was performed in order to determine the absolute frequency of the 2S {yields} 3S ...

2010-02-11

366

Novel reduced pressure-balance syringe for chromatographic analysis.  

Science.gov (United States)

When withdrawing a fluid sample (for additional chromatographic analyses) from an apparatus operated at a reduced pressure, a typical syringe proves to be ineffective (even if it is equipped with a gas tight plunger). It simply does not create enough pressure differential to remove a fluid sample from a reduced pressure environment. We encountered such a situation as part of efforts to extend the operation of the advanced distillation curve protocol to reduced pressures. The problem was solved by the development of a pressure balance syringe that allows reliable and precise sampling from an apparatus operating at sub-ambient pressures. This new device uses an external vacuum source to evacuate a syringe barrel, allowing a user to withdraw fluid samples from environments with pressures as low as 0.5kPa. To demonstrate the operation of the ...

2010-09-19

367

Reliability and Validity of the Sexual Pressure Scale for Women-Revised  

UK PubMed Central (United Kingdom)

Sexual pressure among young urban women represents adherence to gender stereotypical expectations to engage in sex. Revision of the original 5-factor Sexual Pressure Scale was undertaken in...Full Text Available

2009-02-01

368

Pressure Probe Technique for Measuring Water Relations of Cells in Higher Plants 1  

UK PubMed Central (United Kingdom)

A new method is described for continuously measuring cell turgor pressure (P), hydraulic conductivity (Lp), and volumetric elastic modulus (ε) in higher plant cells, using a pressure...Full Text Available

1978-02-01

369

Hydraulic system for driving control rods  

International Nuclear Information System (INIS)

Purpose: To enable safety reactor shut down upon occurrence of an abnormal excess pressure in a hydraulic control unit. Constitution: The actuation pressure for a pressure switch that generates a scram signal is set lower than the release pressure set to a pressure release valve. Thus, if the pressure of nitrogen gas in a nitrogen container increases such as upon exposure of the hydraulic control unit to a high temperature, the pressure switch is actuated at first to generate the scram signal and a scram valve is opened to supply water at high pressure to control rod drives under the driving force of the nitrogen gas at high pressure to rapidly insert the control element into the reactor and shut down it. If the pressure of the nitrogen gas still increases after the scram, the ...

1980-11-07

370

Differential control of systolic and diastolic blood pressure in blacks with essential hypertension.  

UK PubMed Central (United Kingdom)

OBJECTIVE: The risk of cardiovascular and renal diseases has been shown to be higher for systolic blood pressure than diastolic blood pressure. The aim of this study was to assess the differential control...Full Text Available

2004-03-01

371

Isotope and trace element systematics in a spinel-lherzolite-bearing suite of basanitic volcanic rocks from San Luis Potosi, Mexico  

Energy Technology Data Exchange (ETDEWEB)

Lherzolite-bearing basanitic magmas of Quaternary age have erupted to form maars, lava/cinder cones and lava flows in two volcanic fields (Ventura and Santo Domingo) in the central Mexican state of San Luis Potosi. The systematics of the radiogenic isotopes of Sr, Nd, and Pb and the relationship between these parameters and elemental compositions are used to investigate the petrogenesis of the volcanic rocks and the nature of their mantle sources. Sr and Nd isotopic data are presented for 19 basanitic rocks, 5 kaersutites, and 6 lherzolitic xenoliths; Pb data presented for the same 19 volcanic rocks and 4 of the 5 kaersutites. The isotopic compositions for all of these samples fall within the mantle range defined by MORBs and OIBs. The basanites generally plot within the OIB field on isotopic diagrams; most of the kaersutites are displaced to slightly more-depleted (i.e. MORB-like) values than the ...

1989-01-01

372

In vivo distribution and excretion studies and in vitro blood studies on the kinetics of lead-203 in beagle dogs. [Thesis  

Energy Technology Data Exchange (ETDEWEB)

The distribution of carrier free lead-203 between plasma and cells of canine blood in vitro was measured. Activity in the plasma decreased to less than 5% of the initial blood activity during the first 15 min and then exponentially with a half time of 160 min. Incubation in cell free plasma before addition to whole blood transformed the isotope, decreasing the amount subsequently associated with cells. In animal studies, activity was measured in plasma, blood cells, urine, and feces after exposure to lead-203. In one group, the animals were exposed by intravenous injection of dilute citric acid solutions of isotope. In a second group, carrier free isotope which had been transformed by incubation in plasma was injected intravenously. The kinetics of the distribution of the isotope differed between the two experimental groups. After injection of the transformed lead, the lead-203 content of the blood cell ...

1980-01-01

373

Granitoid formation is ineffective in isotopically homogenizing continental crust: Evidence from archean rocks of the Wind River Mountains, Wyoming  

Energy Technology Data Exchange (ETDEWEB)

The Archean core of the Laramide Wind River uplift records evidence of at least three major granitoid-forming episodes. The oldest, the Dry Creek gneiss (DCG), was emplaced by 2.8 Ga and occupies the northeastern part of the range. Mafic, pelitic and ultramafic inclusions occur in the DCG. Elsewhere in the Wind River Mountains there is evidence for crustal components as old as 3.8 Ga. The Bridger batholith (BB), intruded at 2.67 Ga, is found in the west-central Wind River Mountains. The Wind River batholith (WRB) refers to the youngest Late Archean granodiorites and granites which are found throughout the range and includes granitoids previously name the Louis Lake, Bears Ears, Popo Agie, and Middle Mountain intrusions. Although granitoids of the Wind River batholith have been dated at 2.63 and 2.55 Ga, they are considered together here because there is a complete gradation in rock type and because definite intrusive contacts are scarce. The DCG, BB, and WRB each span the ...

1992-01-01

374

"Hyperfine Splitting, Isotope Shift, and Level Energy of the 3S States of Li-6, Li-7."  

Energy Technology Data Exchange (ETDEWEB)

High-precision laser spectroscopy on lithium isotopes is of fundamental interest, experimentally as well as theoretically. The lithium atom has long served as a test system for the calculation of various atomic properties in few-electron atoms and significant advances have been made in the last decade[1-3]. Recently, calculations of transition energies for the 22S1/2 -> 32S1/2 and the 22S1/2 -> 22P1/2, 3/2 transitions and of the mass-dependant isotope shift (IS) in these transitions have been reported with a relative accuracy of better than 1 X 10-7 and 5 x 10-6, respectively[4, 5]. These calculations are the foundation for experimental efforts, currently underway at GSI Darmstadt, Germany, to determine the root-mean-square (rms) charge radius of the unstable lithium isotopes[6, 7]. The basic principle is that if all mass-dependent contributions to the IS can be calculated with sufficient accuracy, the ...

2003-07-25

375

Quantitation of Antibiotics by High-Pressure Liquid Chromatography: Cephalothin  

UK PubMed Central (United Kingdom)

A technique for quantitative determination of cephalothin and desacetylcephalothin in serum using a method based on high-pressure liquid chromatography is described. Both compounds were quantitatively...Full Text Available

1978-02-01

376

Pressure loss coefficients for staggered multiorifice/shield plates  

Science.gov (United States)

The hydraulic characteristics of flow control multiorifice plate assemblies designed for the FFTF reactor were investigated. The pressure drop flowrate characteristics determined in the test are presented. (JWR)

1973-10-01

377

Pressure Stabilization of Proteins from Extreme Thermophiles  

UK PubMed Central (United Kingdom)

We describe the stabilization by pressure of enzymes, including a hydrogenase from Methanococcus jannaschii, an extremely thermophilic deep-sea methanogen. This is the first published...Full Text Available

1994-03-01

378

Novel reduced pressure-balance syringe for chromatographic analysis  

British Library Electronic Table of Contents (United Kingdom)

When withdrawing a fluid sample (for additional chromatographic analyses) from an apparatus operated at a reduced pressure, a typical syringe proves to be ineffective (even if it is equipped with a gas tight plunger). It simply does not create enough pressure differential to remove a fluid sample from a reduced pressure environment. We encountered such a situation as part of efforts to extend the operation of the advanced distillation curve protocol to reduced pressures. The problem was solved by the development of a pressure balance syringe that allows reliable and precise sampling from an apparatus operating at sub-ambient pressures. This new device uses an external vacuum source to evacuate a syringe barrel, allowing a user to withdraw fluid samples from environments with pressures as l...

2010-01-01

379

Middle ear pressure variations during anesthesia  

UK PubMed Central (United Kingdom)

SUMMARYThe aim of this study was to determine middle ear pressure changes during the operation performed under anaesthesia induced by isoflurane or desflurane. This was a prospective,...Full Text Available

2010-12-01

380

Installations having pressurized fluid circuits  

International Nuclear Information System (INIS)

It is an object of the present invention to provide an improved installation having a pressurized fluid circuit incorporating fluidic brakes for restricting fluid flow through a breach of the installation. (author).

381

Initial post-buckling behavior of cylindrical shells under external pressure.  

Science.gov (United States)

Circular cylindrical shells with support subjected to lateral or hydrostatic pressure, using Koiter postbuckling theory

1968-01-01

382

Hydrogen adsorption by activated charcoal at low pressure and 20/sup 0/K  

Energy Technology Data Exchange (ETDEWEB)

Measurements of hydrogen adsorption capacity by activated charcoal has been made at a pressure minus than 10/sup -4/ Pa and at 18 K.

1984-04-01

383

Glassy Carbon, Alloys  

Science.gov (United States)

... 2.2.1 Polymerization of DVB Under Pressure DVB was polymerized at 300*C in thin-walled Pd-Ag capsules at pressures up to 60,000 psi. ...

1972-07-27

384

Cementless bipolar hemiarthroplasty in femoral neck fractures in elderly  

UK PubMed Central (United Kingdom)

Background:Cemented hip arthroplasty is an established treatment for femoral neck fracture in the mobile elderly. Cement pressurization raises intramedullary pressure and...Full Text Available

2011-05-01

385

Aerodynamic Static Differential Pressure  

Science.gov (United States)

aerodynamic force and moment values. Only the solid and the 25 percent porous dishes were tested for the static pressure values used primarily to determine ...

386

Transuranium isotopes production and their effect on the three-dimensional core calculation  

Energy Technology Data Exchange (ETDEWEB)

The operation of a nuclear power reactor necessarily implies the consumption or burnup of reactor fuel by fission and capture, which gives rise to a decrease in the reactivity of the reactor. The effect of americium formation on the criticality of a thermal power reactor using two types of fuel is studied. The three-dimensional core calculation is used to calculate the production of the transuranium isotopes and their effect on the effective multiplication factor (K[sub eff]). This effect cannot be neglected for thermal power reactors with UO[sub 2]-PuO[sub 2] fuel (3.11% after 70 weeks of operation). The effect of the transuranium isotopes on the K[sub eff] for a thermal power reactor with UO[sub 2] fuel is about 0.0018% and can be ignored. (author).

1993-02-01

387

Transuranium isotopes production and their effect on the three-dimensional core calculation  

International Nuclear Information System (INIS)

The operation of a nuclear power reactor necessarily implies the consumption or burnup of reactor fuel by fission and capture, which gives rise to a decrease in the reactivity of the reactor. The effect of americium formation on the criticality of a thermal power reactor using two types of fuel is studied. The three-dimensional core calculation is used to calculate the production of the transuranium isotopes and their effect on the effective multiplication factor (K_e_f_f). This effect cannot be neglected for thermal power reactors with UO_2-PuO_2 fuel (3.11% after 70 weeks of operation). The effect of the transuranium isotopes on the K_e_f_f for a thermal power reactor with UO_2 fuel is about 0.0018% and can be ignored. (author).

388

Spectroscopy of neutron-rich {sup 59-63}Mn isotopes  

Science.gov (United States)

The neutron-rich Mn isotopes from A=59 to 63 have been studied through multi-nucleon transfer reactions by bombarding a {sup 238}U target with a beam of {sup 70}Zn at an energy of E{sub lab}=460 MeV. Prompt {gamma} rays measured by the CLARA array have been identified unambiguously for each nucleus, using coincidence relationships with ions detected in the high-acceptance magnetic spectrometer PRISMA. The new data extends the knowledge of the low-lying level structure of Mn isotopes, which is discussed in terms of the systematics of the region. Results are compared with large-scale shell-model calculations using different effective interactions and valence spaces.

2008-08-15

389

Spectroscopy of neutron-rich "5"9"-"6"3Mn isotopes  

International Nuclear Information System (INIS)

The neutron-rich Mn isotopes from A=59 to 63 have been studied through multi-nucleon transfer reactions by bombarding a "2"3"8U target with a beam of "7"0Zn at an energy of E_l_a_b=460 MeV. Prompt #gamma# rays measured by the CLARA array have been identified unambiguously for each nucleus, using coincidence relationships with ions detected in the high-acceptance magnetic spectrometer PRISMA. The new data extends the knowledge of the low-lying level structure of Mn isotopes, which is discussed in terms of the systematics of the region. Results are compared with large-scale shell-model calculations using different effective interactions and valence spaces.

2008-08-01

390

Selection of IFE target materials from a safety and environmental perspective  

International Nuclear Information System (INIS)

Target materials for inertial fusion energy (IFE) power plant designs might be selected for a wide variety of reasons including wall absorption of driver energy, material opacity, cost and ease of fabrication. While each of these issues are of great importance, target materials should also be selected based upon their safety and environmental (S and E) characteristics. The present work focuses on the recycling, waste management and accident dose characteristics of potential target materials. If target materials are recycled so that the quantity is small, isotopic separation may be economically viable. Therefore, calculations have been completed for all stable isotopes for all elements from lithium to polonium. The results of these calculations are used to identify specific isotopes and elements that are most likely to be offensive as well as those most likely to be acceptable in terms of their S and E characteristics.

2001-05-21

391

Radiogenic age and isotopic studies  

International Nuclear Information System (INIS)

This is one of an annual collection of reports presenting data from the Geochronology Section of the Continental Geoscience Division of the Geological Survey of Canada (GSC). The main purpose of this collection is to make geochronological and other radiogenic isotope data produced by the section available promptly to the geological community. Reports make full presentation of the data, relate these to field settings and make comparatively short interpretations. Other geochronological and isotope data produced in the laboratory but published in outside journals or separate GSC publications are summarized at the end of this report. Report 5 contains 24 papers from most regions of Canada, but particularly from British Columbia. The Geochronology Laboratory has, over the years, provided substantial U-Pb dating for the Cordilleran Division of the Geological Survey of Canada in Vancouver, and the results of a number of these studies are presented ...

1999-02-01

392

Proton scattering by short lived sulfur isotopes  

Energy Technology Data Exchange (ETDEWEB)

Elastic and inelastic proton scattering has been measured in inverse kinematics on the unstable nucleus {sup 40}S. A phenomenological DWBA analysis yields a quadrupole deformation parameter {beta}{sub 2} = 0.35 {+-} 0.05 for the 2{sup +}{sub 1} state. Consistent phenomenological and microscopic proton scattering analyses have been applied to all even-even Sulfur isotopes from A = 32 to A = 40. The microscopic analysis used microscopic collective model densities and a modified Jeukenne-Lejeune-Mahaux effective interaction. This analysis suggests the presence of a neutron skin in the heavy sulfur isotopes. The analysis is consistent with normalization values for {lambda}{sub {upsilon}} and {lambda}{sub {omega}} of 0.95 for both the real and imaginary parts of the JLM potential. (author)

1999-07-01

393

Isotopes and groundwater management strategies under semi-arid area: Case of the Souss upstream basin (Morocco)  

International Nuclear Information System (INIS)

This study concerns the Souss upstream basin. The objective is to investigate the characteristics of surface water and groundwater, to assess the impact of artificial recharge as reinforcement of the natural replenishment and assess the renewal of groundwater under semi-arid area. Two major water types are observed: (i) surface waters and upstream springs (least mineralized) and (ii) all groundwater samples (prevailing calcium and magnesium bicarbonate water type). Water isotopes show a low evaporation of precipitations during infiltration. Impoverishment in heavy isotopes is the characteristic of mountain rainfalls, or of a climate colder and wetter than present. Carbon-14 activities (34-94 pmc) indicate a long residence time. The artificial recharge is low compared to the reservoir volume, due to which the renewal rate is also low.

2011-07-01

394

Isotope labeling strategies for NMR studies of RNA  

Energy Technology Data Exchange (ETDEWEB)

The known biological functions of RNA have expanded in recent years and now include gene regulation, maintenance of sub-cellular structure, and catalysis, in addition to propagation of genetic information. As for proteins, RNA function is tightly correlated with structure. Unlike proteins, structural information for larger, biologically functional RNAs is relatively limited. NMR signal degeneracy, relaxation problems, and a paucity of long-range {sup 1}H-{sup 1}H dipolar contacts have limited the utility of traditional NMR approaches. Selective isotope labeling, including nucleotide-specific and segmental labeling strategies, may provide the best opportunities for obtaining structural information by NMR. Here we review methods that have been developed for preparing and purifying isotopically labeled RNAs, as well as NMR strategies that have been employed for signal assignment and structure determination.

2010-01-15

395

Investigation of neutron and proton distributions of He, Li, and Be isotopes using the new Skyrme-Force parameters  

International Nuclear Information System (INIS)

The proton and neutron densities, root-mean-square (rms) radii of proton density and neutron density, and neutron skin thickness of "4"-"1"0He, "6"-"1"1Li, and "7"-"1"2Be isotopes are calculated using Skyrme-Hartree-Fock method with SLy4, SLy5, SLy6, and SLy7 force parameters. The evaluated results are compared with experimental data. Also, the results of halo nuclei ("6","8He, "1"1Li, and "1"1Be) are compared with the results of other isotopes for selected nuclei having the same neutron configuration.

2010-01-01

396

In vivo distribution and excretion studies and in vitro blood studies on the kinetics of lead-203 in beagle dogs  

International Nuclear Information System (INIS)

Studies on the kinetics of the distribution of lead-203 in body fluids have been carried out in vitro, and in animal studies using beagle dogs. In vitro, the distribution of carrier free lead-203 between plasma and cells of canine blood at 37"0C was measured after the addition of isotope. In animal studies, activity in plasma was measured for about 150 hours, and activity in blood cells, urine and feces measured for about 400 hours after exposure to lead-203. Linear compartmental models for distribution of the isotope are presented for both in vitro and in vivo experimental systems. The models contain compartments for both untransformed lead, for isotope added in saline or citric acid, and transformed lead, as obtained by lead-203 incubation in plasma.

397

Effect of carrier on surface decontamination efficiency  

International Nuclear Information System (INIS)

The dependence was determined of the decontamination factor ratio found in the presence of a carrier and in a carrier-free system on carrier concentration at different concentrations of a complexing agent in a solution. Bearing balls were used as contamination materials while a mixture of "1"5"2Eu and "1"5"4Eu isotopes was used as a contaminant, citric acid in a concentration of 5x10"-"3 to 1x10"-"1 mol/dm"3 as a complexing agent, and Eu, lanthanum and aluminium at a concentration range of 1x10"-"5 to 1x10"-"2 mol/dm"3 as carriers. While no increase in the decontamination factor was found for aluminium, a considerable increase was observed in the isotopic and homologic carriers and the concentration dependence of the carrier reached the maximum. An equation was derived explaining the effect by the isotope exchange between the contaminant and the carrier and by the reaction between the carrier and the complexing agent. ...

398

A calf for all seasons? The potential of stable isotope analysis to investigate prehistoric husbandry practices  

British Library Electronic Table of Contents (United Kingdom)

The Early Bronze Age barrows at Irthlingborough and Gayhurst in central England are notable for the large number of cattle (Bos taurus) remains associated with their human Beaker burials. Previous work using strontium isotope analysis has indicated that most of the cattle analysed, and one aurochs (Bos primigenius), were of local origin [Towers, J., Montgomery, J., Evans, J., Jay, M., Parker Pearson, M., 2010. An investigation of the origins of cattle and aurochs deposited in the Early Bronze Age barrows at Gayhurst and Irthlingborough. Journal of Archaeological Science 37, 508-515.]. In this study, stable isotope analysis of enamel and bone was carried out to investigate whether the mature cattle had experienced similar husbandry practices, climate and environment. Bulk carbon, nitrogen a...

2011-01-01

399

Investigation of the effect of laundering the ground crew chemical defense overgarment on toxic-free-area vapor transfer during shelter entry by initially contaminated personnel. Interim report, Oct 87-Jan 88  

Energy Technology Data Exchange (ETDEWEB)

A study by the U.S. Air Force School of Aerospace Medicine, Brooks AFB, Texas, has compared the shelter processing transfer of chemical warfare agent simulant vapor for subjects wearing unwashed and laundered ground-crew chemical defense overgarments. Twice laundered and four times laundered protective garments were included in the assessment. Test subjects, wearing the unwashed and laundered protective garments were initially sprayed with liquid simulant (methyl salicylate) to a target density of 5 g m-2. They were then sequentially processed into and through the USAFSAM Collective Protection Shelter (SCPS-2B) test facility. Immediately upon entry to the Toxic-Free Area, the subjects were confined in individual off gassing booths for 2 h while offgassed simulant vapor concentration in the booths was recorded. The resulting mean maximum vapor concentrations recorded in the booths for subjects who had worn unwashed and ...

1990-12-01

400

The feasibility study of hot cell decontamination by the PFC spray method  

International Nuclear Information System (INIS)

The characteristics of per-fluorocarbon compounds (PFC) are colorless, non-toxic, easily vaporized and nonflammable. Also, some of them are liquids of a high density, low surface tension, low latent heat and low specific heat. These particular chemical and physical properties of fluoro-organic compounds permit their use in very different fields such as electronics, medicine, tribology, nuclear and material science. The Sonatol process was developed under a contract with the DOE. The Sonatol process uses an ultrasonic agitation in a PFC solution that contains a fluorinated surfactant to remove radioactive particles from surfaces. Filtering the suspended particles allows the solutions to be reused indefinitely. They applied the Sonatol process to the decontamination of a heterogeneous legacy Pu-238 waste that exhibited an excessive hydrogen gas generation, which prevents a transportation of such a waste to a Waste Isolation Pilot Plant. Korea Atomic Energy Research ...

2008-01-01

401

Neutron beam experiments using nuclear research reactors: honoring the retirement of professor Bernard W. Wehring -I. 6. Neutronics Analyses for Beamline Upgrades to the High Flux Isotope Reactor  

International Nuclear Information System (INIS)

The High Flux Isotope Reactor (HFIR) located at Oak Ridge National Laboratory is one of the world's most powerful research reactors. In 1996, one year after the demise of the Advanced Neutron Source Project, the U.S. Department of Energy embarked on an aggressive program to upgrade the neutron scattering facilities at the HFIR. These upgrades, which are now in progress, include the installation of larger beam tubes, a high-performance hydrogen cold source, and additional neutron guides and neutron scattering instruments. An extensive analysis effort was performed over the past 4 yr to support the design of the modified beamlines and new user facilities and to assess the impact of the upgrades on the integrity of the existing reactor system. The results of three of these analyses are summarized here. Specifically, results are presented for analyses related to the design of the new cold neutron source (CNS), the assessment of beam tube changes on the anticipated ...

2001-06-17

402

Synopsis of hydrologic data collected by waste management for characterization of unsaturated transport at Area G  

Energy Technology Data Exchange (ETDEWEB)

Data which have been collected by Los Alamos National Laboratory waste management for the hydrologic characterization of the subsurface at the low level radioactive waste disposal facility, Area G, are reported and discussed briefly. The data includes Unsaturated Flow Apparatus measurements of the unsaturated conductivity in samples from borehole G-5. Analysis compares these values to the predictions from van Genuchten estimates, and the implications for transport and data matching are discussed, especially at the location of the Vapor Phase Notch (VPN). There, evaporation drives a significant vapor flux and the liquid flux cannot be measured accurately by the UFA device. Data also include hydrologic characterization of samples from borehole G-5, Area G surface soils, Los Alamos (Cerros de Rio) basalt, Tsankawi and Cerro-Toledo layers, the Vapor Phase Notch (VPN), and additional new samples from the uppermost tuff layer at ...

1998-03-01

403

Performance analysis on a hybrid air-conditioning system of a green building  

Energy Technology Data Exchange (ETDEWEB)

This paper presents the performance analysis on a hybrid air-conditioning system according to the hybrid building energy system of the green building demonstration project in Shanghai, in which a 150 m{sup 2} solar collector is used to power two 10 kW adsorption chillers, a vapor compression heat pump is used to cool air in the evaporating end while the condensing heating at about 80{sup o}C is fully used to regenerate a liquid desiccant dehumidification system. In the hybrid system, the sensible cooling to the air is treated mainly by solar adsorption cooling and vapor compression cooling, whereas the latent heat is treated by the liquid desiccant dehumidification system with regeneration from the condensing heat of the heat pump. The results show that the performance of this system is 44.5% higher than conventional vapor compression system at a latent load of 30% and this improving can be achieved by 73.8% at a 42% latent ...

2006-05-15

404

Investigation of natural circulation two-phase flow behaviour in header manifold using CFD code  

Energy Technology Data Exchange (ETDEWEB)

The three-dimensional (3-D), multiphase, computational fluid dynamic (CFD) code FLUENT is used to simulated two-phase flow behaviour in a CANDU header manifold under low (natural circulation) flow conditions. This behaviour was previously inferred from experimental data. The CFD simulations reported here are being used to support these inferences and to obtain a better understanding of phase distribution in the header manifold. The simulations seem to show that the vapor-water mixture models in the FLUENT code do not capture properly phase separation in the header and proper phase branching at the header-feeder connections that have been observed in experiments at low flows. The simulations using discrete-phase model in FLUENT, which tracks the pathlines of the individual vapor bubbles in the water continuum phase, show interesting, complicated and, in some cases, unexpected bubble trajectories from the point of injection of the bubbles at a ...

2006-07-01

405

WESTERN SANDPIPERS (CALIDRIS MAURI) DURING THE NONBREEDING SEASON: SPATIAL SEGREGATION ON A HEMISPHERIC SCALE  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

406

Urinary isotopic analysis in the UK Armed Forces: no evidence of depleted uranium absorption in combat and other personnel in Iraq  

UK PubMed Central (United Kingdom)

ObjectivesTo assess the distribution and risk factors of depleted uranium uptake in military personnel who had taken part in the invasion of Iraq in 2003.MethodsSector...Full Text Available

2007-12-01

407

The use of nitrogen isotopes in research on sheep nutrition  

International Nuclear Information System (INIS)

Using nitrogen-13 initial measurements have been made of rumen ammonia-nitrogen pool size and turnover, and rate of incorporation of ammonia into microbial protein. It is also feasible to measure the rate of incorporation of absorbed ammonia into urea and the appearance of label in saliva.

1985-08-26

408

Stable isotopes document the trophic structure of a deep-sea cephalopod assemblage including giant octopod and giant squid  

UK PubMed Central (United Kingdom)

Although deep-sea cephalopods are key marine organims, their feeding ecology remains essentially unknown. Here, we report for the first time the trophic structure of an assemblage of these animals (19...Full Text Available

2009-06-23

409

Stable Isotope-Coded Quaternization for Comparative Quantification of Estrogen Metabolites by High-Performance Liquid Chromatography-Electrospray Ionization Mass Spectrometry  

UK PubMed Central (United Kingdom)

A fast and sensitive LC-ESI-MS method is described for the comparative quantification of 16 estrogen metabolites based on the derivatization of estrogens with a novel derivatizing reagent, N-methyl-nicotinic...Full Text Available

2008-07-15

410

Solid-state 13C NMR spectroscopy of a 13C carbonyl-labeled polypeptide  

UK PubMed Central (United Kingdom)

High resolution structural elucidation of macromolecular structure by solid-state nuclear magnetic resonance requires the preparation of uniformly aligned samples that are isotopically labeled. In...Full Text Available

1992-06-01

411

Short-term effects of tumor necrosis factor on energy and substrate metabolism in dogs.  

UK PubMed Central (United Kingdom)

In vivo short-term effects of recombinant human TNF-alpha on lipolysis, FFA flux, fat oxidation, triglyceride-fatty acid cycling, and glucose kinetics were evaluated with stable isotopic tracers and...Full Text Available

1993-06-01

412

SNQ for medical research  

Energy Technology Data Exchange (ETDEWEB)

The planned spallation source can be of considerable significance for biomedical basic research and for clinically relevant diagnostic and therapeutic applications. The following gives a brief description and explanations for its possible use in clinical medicine: I. Treatment of Malignant Tumors II. Production of Isotopes for Biochemical Investigations in Living Organisms for Diagnostic Purposes.

1984-12-01

413

Resonance ionization spectroscopy at {sup 240f,242f}Am fission isomers  

Energy Technology Data Exchange (ETDEWEB)

Optical Isotope shift measurements have been performed for the {sup 240f,242f}Am fission isomers to test the stability of nuclear deformation as function of the neutron number. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with fission detection of the ionization process. The {sup 240f,242f}Am fission isomers have been produced by {sup 242}Pu(p, 3n), {sup 242}Pu(d, 2n) reactions, respectively. Relative isotope shift ratios X{sub exp}{sup 242f}(500 nm)=IS{sup 242f,241}/IS{sup 243,241}=41.4(8) and X{sub exp}{sup 240f}(500 nm)=IS{sup 240f,241}/IS{sup 243,241}=39.2(8) were measured. From these ratios a small difference {delta}{beta}{sub 2}{sup 242f,240f}=0.0076(14) of the deformation parameter {beta}{sub 2} can be deduced assuming that the isotope shift between the reference isotopes {sup 241,243}Am is caused by a pure volume change. (orig.)

1997-10-01

414

Nuclear moments of neutron deficient iridium isotopes from laser spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

Laser spectroscopy measurements have been performed on neutron deficient iridium isotopes. The hyperfine structure and isotope shift of the optical Ir I transition 5d{sup 7}6s{sup 24}F{sub 9/2} {sup {yields}} 5d{sup 7}6s6p {sup 6}F{sub 11/2} at 351.5 nm have been studied for the {sup 182-189}Ir, {sup 186}Ir{sup 1}m and {sup 191,193}Ir isotopes. The nuclear magnetic and quadrupole moments were obtained from the HFS measurements and the changes of the mean square charge radii from the IS measurements. A large mean square charge radius change between {sup 187}Ir and {sup 186}Ir and between {sup 186}Ir{sup 1}m and {sup 186}Ir{sup 1}g has been observed.

2000-08-15

415

Nuclear moments of neutron deficient iridium isotopes from laser spectroscopy  

International Nuclear Information System (INIS)

Laser spectroscopy measurements have been performed on neutron deficient iridium isotopes. The hyperfine structure and isotope shift of the optical Ir I transition 5d"76s"2"4F_9_/_2 "#-># 5d"76s6p "6F_1_1_/_2 at 351.5 nm have been studied for the "1"8"2"-"1"8"9Ir, "1"8"6Ir"1m and "1"9"1","1"9"3Ir isotopes. The nuclear magnetic and quadrupole moments were obtained from the HFS measurements and the changes of the mean square charge radii from the IS measurements. A large mean square charge radius change between "1"8"7Ir and "1"8"6Ir and between "1"8"6Ir"1m and "1"8"6Ir"1g has been observed.

2000-08-01

416

Normal parity states in lithium isotopes  

Energy Technology Data Exchange (ETDEWEB)

Shell model calculations are reported for the properties of normal parity states of /sup 7/Li, /sup 8/Li and /sup 9/Li. Fits to new experimental data are displayed, some ambiguities resolved, and structure information provided for help in further investigations.

1983-11-21

418

Hydrogen isotope effects in hydride transfer reactions of formaldehyde and glyoxal  

International Nuclear Information System (INIS)

In the presence of hydroxyl anion, both formaldehyde and glyoxal are known to undergo rearrangements involving intermolecular and intramolecular hydride transfer (the Cannizzaro and Benzilic acid rearrangements respectively). The authors report ab initio SCF-MO calculations of the transition state geometries, the activation barriers, and the hydrogen isotope effects for these two reactions. The structure of the transition state for the rection involving formaldehyde is usually basis set dependent, becoming more linear and symmetrical as the basis set size increases. In contrast, the analogous transition state for the glyoxal reaction involves a highly non-linear hydride transfer. They find the isotope effects to be quite low for the Cannizzaro reaction, and significantly larger for the non-linear benzilic acid rection, in apparent contradiction to Westheimer's suggestion the isotope effects reach a maximum for linear ...

1987-04-01

419

High-energy reaction cross sections of light nuclei  

Energy Technology Data Exchange (ETDEWEB)

The high-energy reaction cross sections of Li and Be isotopes are calculated using a simplified Glauber model and densities constrained by the empirical binding energies. We find excellent agreement with experiment, reproducing the large increase for the most neutron-rich nuclei.

1989-03-01

420

High-density multiplex detection of nucleic acid sequences: oligonucleotide ligation assay and sequence-coded separation.  

UK PubMed Central (United Kingdom)

We describe a non-isotopic, semi-automated method for large-scale multiplex analysis of nucleic acid sequences, using the cystic fibrosis transmembrane regulator (CFTR) gene as an example. Products...Full Text Available

1994-10-25

421

Experimental and theoretical isotope shifts of strontium levels subject to very strong configuration mixing  

Energy Technology Data Exchange (ETDEWEB)

The isotope shifts of the levels 5p/sup 2/ /sup 1/D/sub 2/, /sup 1/S/sub 0/ and 5sns /sup 1/S/sub 0/(n = 7,8) of strontium have been measured between the isotopes 84, 86, 87 and 88 in two-photon transitions from the ground state, using two lasers with different wavelengths. These levels occur below the beginning of the Rydberg series, and are known to exhibit very strong configuration mixing. Mass and field isotope shifts are calculated ab initio by means of the MCHF method for these levels and 5s4d /sup 1/D2, 5s6s /sup 1/S/sub 0/. The qualitative agreement between theory and experiment confirms the necessity of taking into account the mixing (up to 50%) with both the 5p/sup 2/ and 4d/sup 2/ perturbers in the wavefunction expansions.

1984-05-14

422

Enhancing nutrient management through use of isotope techniques  

International Nuclear Information System (INIS)

Enhanced nutrient cycling basically involves close interaction between inorganic and organic sources of nutrients. Contrasting scenarios of nutrient cycling are found under intensive cropping production systems in most industrialized countries and traditional production systems predominant in many developing countries, where there is a net mining of soil nutrients due to crop harvest removal and erosion. Therefore, to enhance nutrient management in marginal tropical soils it is necessary to maximize the efficiency of nutrient uptake from various inorganic and organic sources with minimal environmental impact. It is postulated that one of the main approaches will be the identification and/or selection of plant genotypes for enhanced nutrient acquisition, in particular at low levels of soil available nutrients. In this context, use of various isotope techniques in examining root activity/distribution pattern and plant nutrient uptake is examined. On the other hand, ...

1994-10-17

423

ESTIMATING ORIGINS OF THREE SPECIES OF NEOTROPICAL MIGRANT SONGBIRDS AT A GULF COAST STOPOVER SITE: COMBINING STABLE ...  

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

424

Development on the cryogenic hydrogen isotopes distillation process technology for tritium removal (Final report).  

Science.gov (United States)

While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose o...

1995-01-01

425

DETERMINATION OF 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY  

Energy Technology Data Exchange (ETDEWEB)

A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, ...

2010-07-26

426

Big bang nucleosynthesis  

Energy Technology Data Exchange (ETDEWEB)

The concordance of standard big bang nucleosynthesis theory and the related observations of the light element isotopes (including some new higher {sup 4}He abundances) will be reviewed. Implications of BBN on chemical evolution, dark matter and constraints on particle properties will be discussed.

1999-01-01

427

Atomic spectroscopy study of nuclear properties of francium and cesium isotopes; Etude par spectroscopie atomique de proprietes nucleaires d'isotopes de francium et de cesium  

Energy Technology Data Exchange (ETDEWEB)

This work is based on the study of cesium ({sup 118,146}Cs) and francium ({sup 207-213}Fr,{sup 220-228}Fr) isotopes by hyperfine atomic spectroscopy and on the interpretation of these results from the nuclear physics point of view. The measured nuclear quantities are: the spin, the magnetic moment, the electric quadrupole moment and the mean square charge radius. The experimental method which is based on hyperfine optical pumping with a tunable laser, followed by magnetic analysis of the atoms is described in the first part. Results related to atomic physics are also presented. In the second part, these data are interpreted in the framework of nuclear models. The deformation of light cesium isomers are compared to values obtained from a theoretical self-consistent calculation. Heavy francium isotopes are situated in an area where the existence of static octupole deformations have been predicted. The odd-even staggering measured on the mean ...

1986-04-15

428

{Beta} decay and isomeric properties of neutron-rich Ca and Sc isotopes.  

Energy Technology Data Exchange (ETDEWEB)

The isomeric and {beta}-decay properties of neutron-rich {sup 53-57}Sc and {sup 53,54}Ca nuclei near neutron number N = 32 are reported, and the low-energy level schemes of {sup 53,54,56}Sc and {sup 53-57}Ti are presented. The low-energy level structures of the {sub 21}Sc isotopes are discussed in terms of the coupling of the valence 1f{sub 7/2} proton to states in the corresponding {sub 20}Ca cores. Implications with respect to the robustness of the N = 32 subshell closure are discussed, as well as the repercussions for a possible N = 34 subshell closure.

2010-07-21

429

Use of stable isotopes in developing countries: safe markers for nutrition regime study  

International Nuclear Information System (INIS)

Possible use of stable radioisotopes in studies on nutrition and medicine problems that may be used in investigations of babies, children, pregnant women is shown. Attention is paid to behaviour of limited number of elements: hydrogen, carbon, nitrogen, oxygen. The IAEA plans implementation of a new coordinated research program on use of stable isotopes for studying nutrition problems and related diseases. The program emphasis will be placed on protein metabolism measurements and estimation of energy consumption in control population groups in developing countries.

430

The use of lead isotopic abundances in trace uranium samples for nuclear forensics analysis  

International Nuclear Information System (INIS)

Secondary ion mass spectrometry (SIMS), secondary electron microscopy (SEM) and X-ray analysis have been applied to the measurement of U-bearing particles with the intent of gleaning information concerning their history and/or origin. The lead isotopic abundances are definitive indicators that U-bearing particles have come from an ore-body, even if they have undergone chemical processing. SEM images and X-ray analysis can add further information to the study that may allude to the extent of chemical processing. The presence of 'common' lead that does not exhibit a radiogenic signature is clear evidence of anthropogenic origin. (author)

2010-06-01

431

The role of brachytherapy in radiation and isotopes centre of Khartoum (RICK)  

International Nuclear Information System (INIS)

As there are many efforts devoted in order to manage the cancer, here the researcher handle one of these efforts that play a major part in treating the cancer internationally, it is a brachytherapy system. Brachytherapy was carried out mostly with radium sources, but recently some artificial sources are incorporated in this mode of treatment such as Cs-137, Ir-192, Au-198, P-32, Sr-90 and I-125. The research cover history of brachytherapy and radioactive sources used in, techniques of implementation, radiation protection and methods of brachytherapy dose calculation, as well as brachytherapy in radiation and isotopes centre in Khartoum.

432

Signature Lipids and Stable Carbon Isotope Analyses of Octopus Spring Hyperthermophilic Communities Compared with Those of Aquificales Representatives  

Science.gov (United States)

This journal article reports a study originally intended to examine the microbial composition of Octopus Spring and nearby vent biofilms. The article compares the lipid profiles of several genera within the Aquificales as well as measurements of the isotopic carbon fractionation associated with autotrophic and heterotrophic growth of Thermocrinis ruber. Results of the study have led to improved understanding of population structure in the Octopus Spring pink streamer community, a hyperthermophilic chemolithotrophic ecosystem in Yellowstone National Park.

433

Recovery of radioactive thallium isotopes from lead and bismuth targets irradiated by 1-GeV protons  

Energy Technology Data Exchange (ETDEWEB)

A simple highly efficient procedure has been developed for recovery of thallium radioisotopes from lead and bismuth targets irradiated by 1-GeV protons. The procedure is based on the use of extraction chromatography. The cross-sections have been determined for formation of {sup 200}Pb, {sup 201}Pb, {sup 202m}Pb, and {sup 203}Pb radioisotopes in targets from lead with natural isotopic composition, irradiated by 1-GeV protons.

1995-03-01

434

Recovery of radioactive thallium isotopes from lead and bismuth targets irradiated by 1-GeV protons  

International Nuclear Information System (INIS)

A simple highly efficient procedure has been developed for recovery of thallium radioisotopes from lead and bismuth targets irradiated by 1-GeV protons. The procedure is based on the use of extraction chromatography. The cross-sections have been determined for formation of "2"0"0Pb, "2"0"1Pb, "2"0"2"mPb, and "2"0"3Pb radioisotopes in targets from lead with natural isotopic composition, irradiated by 1-GeV protons.

435

Rapid preparation of pyrogen-free 2H2(18)O for human-nutrition studies  

International Nuclear Information System (INIS)

We describe a compact ultrafiltration system for the removal of pyrogens and bacteria from water labeled with the stable isotopes of deuterium and oxygen-18. The ultrafiltration system is constructed from readily available commercial components and can achieve complete removal of pyrogens and bacteria from 1L contaminated water within 30 min. By use of our procedure, loss of the isotopically labeled water by retention in the filtration system was minimal. The purified water is suitable for both oral and intravenous administration to healthy human subjects participating in nutrition studies.

436

Nucleon induced reaction cross-sections for strontium and cesium at energies 1 MeV to 10 GeV  

Energy Technology Data Exchange (ETDEWEB)

Nuclear reaction cross-sections for stable strontium and cesium isotopes, which were calculated by different approaches, are compared to available experimental data. Neutron and proton induced reaction cross-sections for the long-lived radionuclides [sup 90]Sr and [sup 137]Cs have been calculated in the energy range from 1 MeV to 10 GeV. Recommendations concerning cross-section calculations for strontium and cesium isotopes at intermediate and high energies are given. (orig.)

1993-06-01

437

Manifestation of isotope effects in absorption spectra of "1"4"4Sm"3"+ and "1"5"4Sm"3"+ in solutions  

International Nuclear Information System (INIS)

Photoluminescence spectra for solutions containing Sm"3"+ isotope ions in heavy and normal water were studied in the wave length #lambda# = 500-700 nm and for absorption spectra and photoluminescence excitation spectra within the range of #lambda# = 260-600 nm. Differences in molar extinction coefficients for "1"4"4Sm"3"+ and "1"5"4Sm"3"+ were established both in the solutions with D_2O and by transition from the solutions with D_2O to the solutions with H_2O. New possible causes of the identified effects are discussed

1998-01-01

438

Lithium isotopes: differential effects in animals  

Energy Technology Data Exchange (ETDEWEB)

Differences in the biological disposition and in the effects of the stable lithium isotopes, Li-6 and Li-7, in animals were characterized. A somewhat higher toxicity was associated with WLiCl compared to XLiCl with NLiCl intermediate. All lithium treatments increased water intake and resulted in weight gain. Peak plasma concentration was slightly high for 6Li than 7LiCl suppressed action potential amplitudes during tetanic stimulation more than NaCl when added to Renger solution bathing ganglia.

1984-04-01

439

Isomeric island in the vicinity of 66Fe  

Science.gov (United States)

An island of isomers have recently been observed on both sides of the N=40 shell below the Ni isotopes. Isomeric states in the 65Fe and 67Fe allow the knowledge of the single particle structure around the {nu}g9/2 shell. Moreover, the excitation energy of the first 2+ and 4+ states in the 68Fe have been established by {beta}-{gamma} correlation. The evolution of the structure of the Fe isotopes going far away from the valley of stability is, for the first time, given for N>40.

2006-04-26

440

Isomeric island in the vicinity of 66Fe  

International Nuclear Information System (INIS)

An island of isomers have recently been observed on both sides of the N=40 shell below the Ni isotopes. Isomeric states in the 65Fe and 67Fe allow the knowledge of the single particle structure around the #nu#g9/2 shell. Moreover, the excitation energy of the first 2+ and 4+ states in the 68Fe have been established by #beta#-#gamma# correlation. The evolution of the structure of the Fe isotopes going far away from the valley of stability is, for the first time, given for N>40.

2006-04-26

441

Forthcoming (n, #gamma#) measurements on the Fe and Ni isotopes at CERN n_TOF  

International Nuclear Information System (INIS)

An overview of the past, present and future research activities at the CERN neutron time of flight facility n_TOF is given, with special focus on the astrophysical aspects. During the first campaign (Phase I), neutron capture cross sections of relevance for several aspects of the s-process nucleosynthesis have been measured. A second campaign has recently started (Phase II), aiming at the study of the weak s-process component via accurate (n,#gamma#) measurements of the Fe and Ni isotopes. Some changes in the facility will allow us to perform these measurements with improved experimental conditions.

2010-01-01

442

Collisional excitation transfer between lithium isotopes  

Energy Technology Data Exchange (ETDEWEB)

Excitation transfer between the 3S[sub 1/2] states of the lithium isotopes [sup 6]Li and [sup 7]Li is measured in a thermionic diode. The 3S level is excited by off-resonant two-photon transitions with a single mode cw laser. The relative densities of the directly excited and collisionally populated levels are probed by further laser excitation to the 12P levels. An energy transfer cross section of 585 A[sup 2] [+-] 160 A[sup 2] is found at the experimental temperature of about 850 K. A simple semiclassical calculation yields a cross section of 450 A[sup 2]. (orig.)

1995-01-01

443

Characterization of nuclear fuels by ICP mass-spectrometric techniques  

British Library Electronic Table of Contents (United Kingdom)

Isotopic analyses of radioactive materials such as irradiated nuclear fuel are of major importance for the optimization of the nuclear fuel cycle and for safeguard aspects. Among the mass-spectrometric techniques available, inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry are the most frequently applied methods for nuclear applications. Because of the low detection limits, the ability to analyze the isotopic composition of the elements and the applicability of the techniques for measuring stable as well as radioactive nuclides with similar sensitivity, both mass-spectrometric techniques are an excellent amendment to classical radioactivity counting methods. The paper describes selected applications of multicollector ICP-MS in combination with c...

2008-01-01

444

Beta-decay half-lives of new neutron-rich chromium-to-nickel isotopes and their consequences for the astrophysical r-process  

International Nuclear Information System (INIS)

Beta-decay studies of the new neutron-rich isotopes sup(58,59)Cr, "6"3Mn, sup(66,67)Co and "6"9Ni, yielding distinctly shorter half-lives than the corresponding theoretical predictions, are presented. The influence of the short half-lives on the r-process calculations of nuclear abundances is discussed. It is concluded that a significantly higher neutron density than the one obtained from explosive helium burning in supernovae is needed to reproduce the observed abundances around A = 80. (orig.).

445

Analysis of tritium mission FMEF/FAA fuel handling accidents  

Energy Technology Data Exchange (ETDEWEB)

The Fuels Material Examination Facility/Fuel Assembly Area is proposed to be used for fabrication of mixed oxide fuel to support the Fast Flux Test Facility (FFTF) tritium/medical isotope mission. The plutonium isotope mix for the new mission is different than that analyzed in the FMEF safety analysis report. A reanalysis was performed of three representative accidents for the revised plutonium mix to determine the impact on the safety analysis. Current versions computer codes and meterology data files were used for the analysis. The revised accidents were a criticality, an explosion in a glovebox, and a tornado. The analysis concluded that risk guidelines were met with the revised plutonium mix.

1997-11-18

446

? decay and isomeric properties of neutron-rich Ca and Sc isotopes  

International Nuclear Information System (INIS)

The isomeric and ?-decay properties of neutron-rich 53-57Sc and 53,54Ca nuclei near neutron number N=32 are reported, and the low-energy level schemes of 53,54,56Sc and 53-57Ti are presented. The low-energy level structures of the 21Sc isotopes are discussed in terms of the coupling of the valence 1f7/2 proton to states in the corresponding 20Ca cores. Implications with respect to the robustness of the N=32 subshell closure are discussed, as well as the repercussions for a possible N=34 subshell closure.

2010-07-01

447

cw operation of an AlGaInP double heterostructure laser diode at 77 K grown by atmospheric metalorganic chemical vapor deposition  

Science.gov (United States)

Continuous wave operation of an Al/sub 0.21/Ga/sub 0.31/In/sub 0.48/P /Ga/sub 0.52/In/sub 0.48/P /Al/sub 0.21/Ga/sub 0.31/In/sub 0.48/P double heterostructure (DH) laser diode was achieved for the first time at 77 K. The device was made from a DH wafer grown by atmospheric metalorganic chemical vapor deposition using triethyl metals and phosphine as source materials. At 77 K, the lasing wavelength was 0.653 ..mu..m and the threshold current was 55 mA for a diode with a nitride-insulated, 8-..mu..m-wide and 250-..mu..m-long stripe geometry.

1984-09-15

448

Waste minimization in a non-production oriented metal finishing operation  

Energy Technology Data Exchange (ETDEWEB)

This paper provides information on activities undertaken in a non- production oriented metal finishing operation to minimize waste and conserve resources. The facility is a 6000 sq foot shop that typically only deals with prototype parts. Utilizing a plan that includes employee awareness, common sense and existing technology, a noticeable reduction in waste volume has been obtained. Initiatives that are covered include: segregation of cyanide plating solutions, elimination of copper cyanide plating, elimination of hexavalent chromium plating, elimination of vapor degreasing, changing of rinsing practices, and changing a process for cleaning of aluminum parts. Some discussion is also presented on the effectiveness of combining the technologies of physical vapor deposition and electrodeposition to help minimize waste. Plans for additional initiatives including water recycling, elimination of cyanide plating and substitution of electrodeposition ...

1991-11-01

449

Thermal gradient humidification-dehumidification desalination system  

Energy Technology Data Exchange (ETDEWEB)

A solar energy desalination process utilizing solar radiation directly for the evaporation of salt water is described. Ambient air takes on water vapor as the air passes through an evaporative medium. It is then directed between a saline water-covered, solar absorbing surface and a solar collecting housing. The resulting heated and moisture-saturated air is cooled in a heat exchange means where condensation of fresh water occurs. Simultaneously, cool salt water is utilized as the cooling water in the heat exchange means, and takes on the heat of condensation given up by the condensing vapor. The heated salt water from the heat exchange means is partially directed over the solar absorbing surface, and at least a portion of it is also directed to wet the evaporative medium. Several optional sub-processes are described for operation of the system during periods of reduced insolation, and an alternative process is described for operation of the ...

1982-12-14

450

Tank 241-AZ-101 Mixer Pump Test Vapor Sampling and Analysis Plan  

Energy Technology Data Exchange (ETDEWEB)

This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for vapor samples obtained during the operation of mixer pumps in tank 241-AZ-101. The primary purpose of the mixer pump test (MPT) is to demonstrate that the two 300 horsepower mixer pumps installed in tank 241-AZ-101 can mobilize the settled sludge so that it can be retrieved for treatment and vitrification. Sampling will be performed in accordance with Tank 241-AZ-101 Mixer Pump Test Data Quality Objective (Banning 1999) and Data Quality Objectives for Regulatory Requirements for Hazardous and Radioactive Air Emissions Sampling and Analysis (Mulkey 1999). The sampling will verify if current air emission estimates used in the permit application are correct and provide information for future air permit applications.

2000-04-10

451

Separation of magnesium from magnesium chloride and zirconium and/or hafnium subchlorides in the production of zirconium and/or hafnium sponge metal  

International Nuclear Information System (INIS)

This patent describes the producing of a refractory metal wherein a sponge refractory metal is produced as an intermediate product by the use of magnesium with the incidental production of magnesium chloride, and wherein residual magnesium is separated from the magnesium chloride and from refractory metal to a vacuum distillation step which fractionally distills the magnesium, the magnesium chloride, and the metal sub-chlorides; the steps of: recovering fractionally distilled vapors of magnesium chloride and metal sub-chlorides from a sponge refractory metal; separately condensing the vapors as separately recovered; and recycling the separately recovered magnesium at a purity of at least about 96%.

1990-09-21

452

Selective formation of ZnO nanodots on nanopatterned substrates by metalorganic chemical vapor deposition  

International Nuclear Information System (INIS)

Selective formation of ZnO nanodots was accomplished by metalorganic chemical vapor deposition on nanopatterned SiO_2/Si substrates. Self-organized ZnO nanodots were selectively formed in nanopatterned lines of Si created by etching of SiO_2 with focused ion beam (FIB), whereas any nanodots were hardly observed on the SiO_2 surface in the vicinity of the FIB-sputtered Si areas. The mechanism of the selective formation of ZnO nanodots on FIB-nanopatterned lines is mainly attributed to the effective migration of Zn adatoms diffusing on the SiO_2 surface into the Si lines followed by the nucleation at surface atomic steps and kinks created by Ga"+ ion sputtering. Cathodoluminescence measurements confirmed that the emission originated from the selectively grown ZnO nanodots.

2003-10-27

453

PROBING NEAR-SURFACE ATMOSPHERIC TURBULENCE WITH LIDAR MEASUREMENTS AND HIGH-RESOLUTION HYDRODYNAMIC MODELS  

Energy Technology Data Exchange (ETDEWEB)

As lidar technology is able to provide fast data collection at a resolution of meters in an atmospheric volume, it is imperative to promote a modeling counterpart of the lidar capability. This paper describes an integrated capability based on data from a scanning water vapor lidar and a high-resolution hydrodynamic model (HIGRAD) equipped with a visualization routine (VIEWER) that simulates the lidar scanning. The purpose is to better understand the spatial and temporal representativeness of the lidar measurements and, in turn, to extend their utility in studying turbulence fields in the atmospheric boundary layer. Raman lidar water vapor data collected over the Pacific warm pool and the simulations with the HIGRAD code are used for identifying the underlying physics and potential aliasing effects of spatially resolved lidar measurements. This capability also helps improve the trade-off between spatial-temporal resolution and coverage of the ...

2000-11-01

454

Optoelectronic devices grown by metallo-organic chemical vapor deposition  

International Nuclear Information System (INIS)

The metallo-organic chemical vapor deposition (MOCVD) process has been used with great success to grow AlGaAs-GaAs and InGaAsP-InGaAs-InP heterostructure materials for electronic and optoelectronic applications. Devices fabricated from Al/sub x/Ga/sub 1-x/As-GaAs heterostructures grown by MOCVD include bipolar transistors, field-effect transistors (FETs), high-mobility (or modulation-doped) FETs, large-area high-efficiency solar cells, low-threshold lasers, high-power lasers, quantum-well lasers, and visible lasers. The state of the art for the MOCFD growth of optoelectronic devices is reviewed in this paper, and some comments are made regarding future trends in the growth of these materials by MOCVD.

455

Excess Gibbs free energies and excess volumes of mixtures containing normal alkanes or cyclohexane + thiaalkanes or dithiaalkanes  

Energy Technology Data Exchange (ETDEWEB)

Vapor-liquid equilibria, by head-space gas-chromatographic analysis of the equilibrated vapor phase directly withdrawn from the equilibration apparatus, and molar excess volumes, V[sup E], by means of a vibrating-tube densimeter, of binary mixtures containing thiaalkanes or dithiaalkanes with n-alkanes or cyclohexane, were determined at 298.15 K. The excess molar Gibbs free energies, GE, of the examined mixtures were obtained by a least-squares treatment of the equilibrium data. The GE and V[sup E] values indicate that the steric effect exerted by the alkyl groups adjacent to the S group causes a regular decrease of the G[sup E] (or V[sup E]) with increasing the number of alkyl groups in the thiaalkane. A tentative approach, based on an additivity scheme of surface interactions combined with the scaled particle theory, is presented to estimate the energies of solvation in terms of group contributions.

1993-10-01

456

Elucidating two-phase transport in a polymer electrolyte fuel cell, Part 1: Characterizing flow regimes with a dimensionless group  

British Library Electronic Table of Contents (United Kingdom)

This paper explores the through-/in-plane characteristics of water transport in the cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC). Theoretical analysis is performed on the non-isothermal two-phase flow under flow channels. A dimensionless group Da (Damkohler number for PEFC operation), defined as the ratio of water generation rate to water vapor-phase removal rate, is formulated to characterize the flow regimes in a PEFC. This group, lumping geometrical parameters and physical properties, compares the water vapor-phase removal capability (via water diffusion and holding capacity) with the rate of water production by the oxygen reduction reaction. We find that this dimensionless group can be used to characterize the non-isothermal, two-phase phenomena: when Da&...

2011-01-01

457

Demonstration of a Tunable-Bandwidth White Light Interferometer using Anomalous Dispersion in Atomic Vapor  

CERN Document Server

The concept of the 'white-light cavity' has recently generated considerable research interest in the context of gravitational wave detection. Cavity designs are proposed using negative (or anomalous) dispersion in an intracavity medium to make the cavity resonate over a large range of frequencies and still maintain a high cavity build-up. This paper presents the first experimental attempt and demonstration of white-light effect in a meter long ring cavity using an intracavity atomic medium. The medium's negative dispersion is caused by bi-frequency Raman gain in an atomic vapor cell. Although the white light condition was not perfectly achieved and improvements in experimental control are still desirable, significantly broad cavity response over bandwidth greater than 20 MHz has been observed. These devices will have potential applications in new generation laser interferometer gravitational wave detectors.

2006-01-01

458

A mobile remote sensing laboratory for water vapor, trace gas, aerosol, and wind speed measurements  

Energy Technology Data Exchange (ETDEWEB)

The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.

1993-03-19

460

Wolsung-1 NPP - electrictal systems  

International Nuclear Information System (INIS)

... power reactors pressure tube reactors reactors THERMAL REACTORS.

1980-06-18

461

Solar Radiation Pressure Binning for the Geosynchronous Orbit  

Science.gov (United States)

Orbital maintenance parameters for individual satellites or groups of satellites have traditionally

2011-01-01

463

Power fluidics for ventilation control  

International Nuclear Information System (INIS)

... amplification exhaust systems fluidic control devices gloveboxes pressure

1984-11-28

465

Modernization of high pressure steam turbines and low pressure steam turbines in the coal-fired power plant Bergkamen; Modernisierung der Hoch- und Niederdruckdampfturbinen im Kohlekraftwerk Bergkamen  

Energy Technology Data Exchange (ETDEWEB)

In the year 2008, the high pressure partial turbine and two low pressure partial turbines in the hard coal power station Bergkamen (Federal Republic of Germany) were modernized. A three-dimensional blade design and innovative seals were used. This resulted into a distinct increase in efficiency among other things.

2010-07-01

469

Ignition Phenomena in Developmental, Stick Propellant ...  

Science.gov (United States)

... TEMPERATURE, PRESSURE MEASUREMENT, GUN CHAMBERS, COMPACTING, COMBUSTIBLE CARTRIDGE CASES, FLASH RADIOGRAPHY ...

1984-07-01

470

High-pressure transport properties of CePd{sub 2}Si{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

We report resistivity and thermopower measurements of the heavy fermion compound CePd{sub 2}Si{sub 2} at pressures up to 56 kbar. At pressures from 21 to 34.5 kbar, we measured the resistivity down to 30 mK, for all other pressure steps the temperature range was 1.2-300 K. (orig.).

1996-07-01

471

High-pressure transport properties of CePd_2Si_2  

International Nuclear Information System (INIS)

We report resistivity and thermopower measurements of the heavy fermion compound CePd_2Si_2 at pressures up to 56 kbar. At pressures from 21 to 34.5 kbar, we measured the resistivity down to 30 mK, for all other pressure steps the temperature range was 1.2-300 K. (orig.).

476

Highly enriched isotope samples of uranium and transuranium elements for scientific investigation  

International Nuclear Information System (INIS)

The paper describes the production of highly enriched isotopes of uranium, plutonium, americium and curium by electromagnetic separation for scientific and applied researches in physics, chemistry, geology, medicine, biology and other fields. Using the equipment described, the isotopes are produced in quantities sufficient to set up nuclear physical experiments, to produce nuclear reference materials and standard sources for calibration of radiometrical and mass spectrometrical equipment, in radionuclide metrology, etc. For the following isotopes the indicated degrees of isotopic enrichment were achieved: "2"3"3U-99.97%; "2"3"5U-99.97%; "2"3"6U-98.0%; "2"3"8U-99.997%; "2"3"8Pu-99.6%; "2"3"9Pu-99.9977%; "2"4"0Pu-99.9-100%; "2"4"1Pu-96.998%; "2"4"2Pu-97.8-99.96%; "2"4"4Pu-96.7%; "2"4"1Am-99.6%; "2"4"2"mAm-73.6%; "2"4"3Am-99.2-99.94%; "2"4"3Cm-99.99%; "2"4"5Cm-99.998%; "2"4"6Cm-99.8%; "2"4"7Cm-90%, ...

477

Experience and recent developments in nuclear forensics at the Institute of Isotopes  

International Nuclear Information System (INIS)

Full text: Based on experience with nuclear material confiscated in Hungary from illicit trafficking activities in the nineties it has been decided that traditional gamma-spectrometry should be complemented by destructive analytical techniques. The 17/1996 (I. 31.) Korm. Governmental Decree delegated the identification, categorization and characterization tasks to the Institute of Isotopes, Budapest. Routine gamma-spectrometric methods have been further developed aiming at the i) age (production date) determination of seized samples and complete (nondismountable) uranium-bearing items (such as fresh fuel bundles and fission chambers) by HRGS technique, ii) improvement of measurement accuracy and reliability. Starting in 2005 mass spectrometry (ICP-SFMS) and scanning electron microscopy have been implemented to characterize nuclear samples in more detail and to analyze environmental samples both for isotopic and elemental composition focusing on ...

478

Role of cerebrospinal fluid pressure in the pathogenesis of glaucoma  

British Library Electronic Table of Contents (United Kingdom)

Abstract. The pathogenesis of normal (intraocular) pressure glaucoma has remained unclear so far. As hospital-based studies showed an association of normal-pressure glaucoma with low systemic blood pressure, particularly at night, and with vasospastic symptoms, it has been hypothesized that a vascular factor may play a primary role in the pathogenesis of normal-pressure glaucoma. That assumption may, however, be contradicted by the morphology of the optic nerve head. Eyes with normal-pressure glaucoma and glaucomatous eyes with high-intraocular pressure can show a strikingly similar appearance of the optic nerve head, including a loss of neuroretinal rim, a deepening of the optic cup, and an enlargement of parapapillary atrophy. These features, however, are not found in any (other) vascula...

2011-01-01

479

Relationship of blood lead to blood pressure in a longitudinal study of working men  

Energy Technology Data Exchange (ETDEWEB)

The relationship of lead exposure to blood pressure has been examined in a longitudinal study of a cohort of 89 Boston, Massachusetts, policemen. At the baseline examination, subjects had a blood lead determination and three consecutive blood pressure measurements. Triplicate blood pressure measurements were also taken at years 3, 4, and 5. Multivariate analysis revealed that, after correction for previous systolic blood pressure, body mass index, age, and smoking, a high level of blood lead was a significant predictor of subsequent elevation of systolic pressure. Bootstrap simulations of these models provided supporting evidence for the observed associations. These data suggest that lead exposure can significantly affect systolic pressure.

1986-05-01

480

Effect of injection pressure on heat release rate and emissions in CI engine using orange skin powder diesel solution  

British Library Electronic Table of Contents (United Kingdom)

Experiments have been conducted to study the effect of injection pressure on the combustion process and exhaust emissions of a direct injection diesel engine fueled with Orange Skin Powder Diesel Solution (OSPDS). Earlier investigation by the authors revealed that 30% OSPDS was optimum for better performance and emissions. In the present investigation the injection pressure was varied with 30% OSPDS and the combustion, performance and emissions characteristics were compared with those of diesel fuel. The different injection pressures studied were 215bar, 235bar and 255bar. The results showed that the cylinder pressure with 30% OSPDS at 235bar fuel injection pressure, was higher than that of diesel fuel as well as at other injection pressures. Similarly, the ignition delay was longer and wi...

2009-01-01

481

Development of technology on the material surveillance of CANDU pressure tubes  

International Nuclear Information System (INIS)

Material degradation of pressure tubes, which are the most important components in CANDU fuel channel, can only be evaluated by removing and examining them(material surveillance). This study aimed at establishment of overall evaluation technology including the evaluation of the material degradation for the integrity of pressure tubes of Wolsung units. Material tests for pressure tubes were performed as follows; (1) Evaluation on life limiting factors of pressure tubes (2) Review on leak-before-break and integrity maintenance technology of pressure tubes (3) Survey on selection criteria for tubes to be inspected and on related regulations for material surveillance (4) Analysis of material surveillance test procedure (5) Basic examinations of Wolsung unit 1 pressure tube material(TEM, texture, chemical component etc) (6) Manufacture of test equipments and test ...

1997-05-21

482

Determination and characteristics of the transition to two-phase slug flow in small horizontal channels  

Energy Technology Data Exchange (ETDEWEB)

Two-phase pressure drop and fluctuating static pressures were measured in a small horizontal rectangular channel (hydraulic diameter = 5.44 mm). The two-phase fluid was an air/water mixture at atmospheric pressure tested over a mass flux range of 50 to 2,000 kg/m[sup 2] [center dot] s. Two-phase flow patterns were identified and an objective method was found for determining the flow pattern transition from bubble or plug flow to slug flow. The method is based on an RMS static pressure measurement. In particular, it is shown that the transition is accompanied by a clear and abrupt increase in the RMS pressure when plotted as a function of mass quality. Use of the RMS pressure as a two-phase flow pattern transition indicator is shown to have advantages over pressure-versus-time trace evaluations reported in the literature. The transition is ...

1994-03-01

483

Optical pressure on thin film caused by a Gaussian beam-generated evanescent wave  

International Nuclear Information System (INIS)

The optical pressure exerted o a thin film, which is locked in the evanescent field formed at the plane interface with a totally-reflected Gaussian beam, is investigated. Some calculations of the pressure on the film caused by the evanescent field are presented in the different conditions of film thickness, film position, incident angle and polarization of a gaussian beam. The results show that the pressure exertion on the thin film can change from pushing to pulling as the parameters are varied. In particular, we find that the direction of optical pressure can act oppositely at the different positions of the film surface in the evanescent field.

1994-11-01

484

Integrity assessment of pressure tubes for Wolsung unit 2  

Energy Technology Data Exchange (ETDEWEB)

To improve operational safety of the fuel channel for Wolsung units the recommended primary heat transport system (PHTS) operating guidelines were developed, which provides a safe operation window in terms of pressure and temperature to maintain fuel channel integrity, which is similar to pressure-temperature curves used for primary pressure boundary integrity in PWRs and deterministic Leak-Before Break (LBB) analyses were conducted using recent understanding of delayed hydride cracking (DHC) mechanism. In addition, a comparative assessment of LBB analysis was made using the procedures of Fitness For Service Guidelines(FFSG) for pressure tubes rev. 0 and rev. 1.

1997-10-01

485

Fast Neutral Pressure Measurements in NSTX  

Energy Technology Data Exchange (ETDEWEB)

Several fast neutral pressure gauges have been installed on NSTX [National Spherical Torus Experiment] to measure the vessel and divertor pressure during inductive and coaxial helicity injected (CHI) plasma operations. Modified, PDX [Poloidal Divertor Experiment]-type Penning gauges have been installed on the upper and lower divertors. Neutral pressure measurements during plasma operations from these and from two shielded fast Micro ion gauges at different toroidal locations on the vessel mid-plane are described. A new unshielded ion gauge, referred to as the In-vessel Neutral Pressure (INP) gauge is under development.

2002-08-06

486

U.S. Department of Energy, Nevada Operations Office Environmental Monitoring Program, Summary Data Report, First Calendar Quarter 1996  

Energy Technology Data Exchange (ETDEWEB)

This report discusses environmental surveillance activities conducted on the Nevada Test Site during the first calendar quarter of 1996. Surveillance activities included collection and analysis of air, noble gas, tritiated water vapor, and other water samples. Samples were analyzed for both radiological and non-radiological effluents.

1996-11-01

487

Stored light and released fiction  

CERN Document Server

It is shown that the interpretation of the experimental results reported in the publication "Storage of Light in Atomic Vapor" by D.F.Phillips et al., Phys. Rev.Lett. 86, 783 (2001) [quant-ph/0012138] is incorrect. The experimental observation of this paper can be consistently explained in the framework of standard concepts of the physics of optical pumping and has nothing to do with "storage of light", or "dynamic reduction of the group velocity", or "light pulse compression".

2003-01-01

488

Pyrolysis of dichlorodithiourea cadmium(II)  

Energy Technology Data Exchange (ETDEWEB)

By means of infrared spectroscopy, x-ray diffraction, and differential thermal analysis, the authors investigate the pyrolysis of dichlorodithiourea cadmium, the vapor phase epitaxy of the cadmium sulfide film, and the composition of the solid and gaseous pyrolysis products. Those products are found to include the thiocyanates of guanidine, ammonium, and hydrogen along with cadmium oxides and sulfates and hydrochloric acid.

1987-02-20

489

Performance of a commercial heat pipe under operational conditions  

Energy Technology Data Exchange (ETDEWEB)

The performance of a commercial heat pipe was investigated both experimentally and theoretically. The effect of the temperature difference, the surface area ratio, and the operational conditions on the performance were studied. The heat flow rate and the vapor temperature were estimated on a ready-made commercial heat pipe. Its performance varied considerably with operational conditions. Theoretical consideration of a mathematical model and several nomographs are also presented. This work is applicable to the design and use of heat pipes in the field.

1983-04-01

490

Operational test report integrated system test (ventilation upgrade)  

Energy Technology Data Exchange (ETDEWEB)

Operational Final Test Report for Integrated Systems, Project W-030 (Phase 2 test, RECIRC and HIGH-HEAT Modes). Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks, including upgraded vapor space cooling and filtered venting of tanks AY101, Ay102, AZ101, AZ102.

1999-10-05

491

Nodalization schemes for PGV-440 steam generator model with RELAP5/MOD3  

Energy Technology Data Exchange (ETDEWEB)

Results of calculation of steady thermal-hydraulic characteristics of PVG-440 horizontal steam generator are presented. Steam flows in selected sections are compared to data provided by OKB Gidropress Calculated vapor void fractions are compared to measured ones. (orig.) (3 refs., 3 figs., 8 tabs.).

1993-12-31

492

Nodalization schemes for PGV-440 steam generator model with RELAP5/MOD3  

International Nuclear Information System (INIS)

Results of calculation of steady thermal-hydraulic characteristics of PVG-440 horizontal steam generator are presented. Steam flows in selected sections are compared to data provided by OKB Gidropress Calculated vapor void fractions are compared to measured ones. (orig.) (3 refs., 3 figs., 8 tabs.).

1992-09-29

493

Heat transfer in boiling liquified gas  

Energy Technology Data Exchange (ETDEWEB)

Means for increasing heat transfer characteristics between the surface of a solid and a boiling liquid are described in which the solid is immersed is comprised of a solid with passages which extend therethrough to the surface for the circulation of liquid through the passages for emergence from the surface to eliminate at least a portion of the unstable vapor film otherwise formed on the surface.

1980-09-23

494

Enhanced Control of Mercury by Wet Flue Gas Desulfurization Systems Site 3 Topical Report.  

Science.gov (United States)

The U.S. Department of Energy and EPRI have co-funded this project to improve the control of mercury emissions from coal-fired power plants equipped with wet flue gas desulfurization (FGD) systems. The project investigated catalytic oxidation of vapor-pha...

2004-01-01

495

EFFECTIVE CONTROL OF SECONDARY WATER POLLUTION FROM FLUE GAS DESULFURIZATION SYSTEMS  

Science.gov (United States)

The report describes tests to demonstrate the feasibility of using a vertical-tube, falling-film, vapor-compression evaporator to concentrate waste water from a flue gas desulfurization (FGD) process. Tests showed that waste water from the Chiyoda FGD process can be concentrated ...

496

Development of High-Efficiency Low-Lift Vapor Compression System - Final Report  

Energy Technology Data Exchange (ETDEWEB)

PNNL, with cofunding from the Bonneville Power Administration (BPA) and Building Technologies Program, conducted a research and development activity targeted at addressing the energy efficiency goals targeted in the BPA roadmap. PNNL investigated an integrated heating, ventilation and air conditioning (HVAC) system option referred to as the low-lift cooling system that potentially offers an increase in HVAC energy performance relative to ASHRAE Standard 90.1-2004.

2010-03-31

497

DOUBLE-SHELL TANK (DST) HYDROXIDE DEPLETION MODEL FOR CARBON DIOXIDE ABSORPTION  

International Nuclear Information System (INIS)

This document generates a supernatant hydroxide ion depletion model based on mechanistic principles. The carbon dioxide absorption mechanistic model is developed in this report. The report also benchmarks the model against historical tank supernatant hydroxide data and vapor space carbon dioxide data. A comparison of the newly generated mechanistic model with previously applied empirical hydroxide depletion equations is also performed.

2009-04-30

498

A review of mesospheric dynamics and chemistry  

Energy Technology Data Exchange (ETDEWEB)

Advances made in understanding the chemistry and dynamics of the atmosphere in the approximate altitude range of 50 to 90 km are addressed. Attention is given to mesospheric structure and seasonal variations, gravity waves and gravity wave saturation, the effects of gravity waves on thermal, momentum and constituent fluxes, and the effect of gravity waves on airglow emissions. A review of research on tides and planetary waves and their effects on the mesosphere are presented as well as discussions on ozone hydroxyl, water vapor, and noctilucent cloud research. 217 refs.

1991-01-01

499

A 3D tomographic EBSD analysis of a CVD diamond thin film  

Energy Technology Data Exchange (ETDEWEB)

We have studied the nucleation and growth processes in a chemical vapor deposition (CVD) diamond film using a tomographic electron backscattering diffraction method (3D EBSD). The approach is based on the combination of a focused ion beam (FIB) unit for serial sectioning in conjunction with high-resolution EBSD. Individual diamond grains were investigated in 3-dimensions particularly with regard to the role of twinning.

2008-09-15