WorldWideScience
1

Heber Ethanol Fuel Facility, Imperial Valley, California. Quarterly report No. 2, March 1981-May 1981  

Energy Technology Data Exchange (ETDEWEB)

The purposed project is a commercial-scale ethanol-fuel facility with a capacity of twenty million gallons per year of fuel-grade ethanol. In addition, 70,000 tons per year of distillers dried grains will be produced. The following tasks and issues are addressed: process engineering - process descriptions, plant layout, and design; economics and finance - overview of capital and operating costs; environmental analysis - preliminary project description; and permit processing and legal issues. (MHR)

1981-08-01

2

Inhibition effects on fermentation of hardwood extracted hemicelluloses by acetic acid and sodium  

British Library Electronic Table of Contents (United Kingdom)

Extraction of hemicellulose from hardwood chips prior to pulping is a possible method for producing ethanol and acetic acid in an integrated forest bio-refinery, adding value to wood components normally relegated to boiler fuel. Hemicellulose was extracted from hardwood chips using green liquor, a pulping liquor intermediate consisting of aqueous NaOH, Na2CO3, and Na2S, at 160degreeC, held for 110min in a 20L rocking digester. The extracted liquor contained 3.7% solids and had a pH of 5.6. The organic content of the extracts was mainly xylo-oligosaccharides and acetic acid. Because it was dilute, the hemicellulose extract was concentrated by evaporation in a thin film evaporator. Concentrates from the evaporator reached levels of up to 10% solids. Inhibitors such as acetic acid and sodium ...

2010-01-01

3

Benchmarking of refinery emissions performance : Executive summary  

International Nuclear Information System (INIS)

This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur ...

2003-01-01

7

Oil refinery waste disposal methods, quantities and costs, 1993 survey  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the information gathered by CONCAVE in a 1993 survey of waste generation and disposal by the oil refineries in Western Europe. The survey covered the types of waste produced, their quantities, disposal routes and costs of disposal. The results are compared with those from a 1986 survey, but because of the increased numbers of refineries reporting, comparison is difficult. The survey revealed wide variations in disposal costs depending on waste type and local circumstances.

1995-06-01

8

Waste generation and pollution prevention progress fact sheet: West Valley Demonstration Project  

Energy Technology Data Exchange (ETDEWEB)

This Fact Sheet presents the mission of the West Valley Demonstration Project and information on the 1994 pollution prevention and recycling accomplishments.

1994-12-31

10

Increasing alpine transit traffic through Switzerland will considerably enhance high altitude alpine pollutant levels  

Energy Technology Data Exchange (ETDEWEB)

Within the EU-Project VOTALP (Vertical Ozone Transports in the Alps), we have shown that deep alpine valleys like the Mesolcina Valley very efficiently transport air out of the polluted valley up to altitudes between 2000 and near 4000 m asl (above sea level). Pollutants emitted in these valleys are very efficiently transported up to high altitudes. (author) 2 figs., 1 tab., 2 refs.

1999-08-01

12

Atmospheric emissions as a tool in evaluation of sustainability research in oil industry; Emissao atmosferica como uma ferramenta na avaliacao do desenvolvimento sustentavel na industria do petroleo  

Energy Technology Data Exchange (ETDEWEB)

This work is directly to analysis of atmosphere surrounding Ipiranga Refinery; witch is located in the city of Rio Grande, in estate of Rio Grande do Sul. The refinery is surrounded by neighborhood, witch are impacted by atmospheric emissions of refinery. The objective of this work is correlating the refinery to the inhabitants that lives near the refinery, using an environmental sustainability index. This work will be achieve by analysis of Polycyclic Aromatic Hydrocarbons (PAH) bounded in particulate matter with diameter of 100 {mu}m (PTS), the acquisition of health data on the city hospitals and correlation of this data with PAH concentrations in Particulate Matter. The Samples were obtain by FEPAM, witch have three samples sites in the center of city. The samples was obtained by a High Volume Sampler equipped with quartz fiber filters. The meteorological data important to this ...

2008-07-01

13

Survey reveals Europe's refinery-waste disposal methods, amounts, and costs  

Energy Technology Data Exchange (ETDEWEB)

Results of a survey conducted by Concawe on 75 oil refineries in Europe show that the total quantity of waste requiring disposal in 1986 was 0.5 million metric tons. This quantity of waste is but 0.13% of the total refinery throughput of 387 million metric tons during 1986. The survey revealed a wide range of disposal costs, depending on the particular properties of the waste and local conditions. A summary of total waste generation and how the waste is disposed of is shown. Details on the types of waste disposed, the disposal methods used, and the costs of disposal are detailed in this excerpt from the Concawe survey.

1989-08-28

14

The effects of nicotine, hexamethonium and ethanol on the secretion of the antidiuretic and oxytocic hormones of the rat  

UK PubMed Central (United Kingdom)

The actions of nicotine, hexamethonium, and ethanol on the hypothalamo-hypophysial system have been investigated in the rat. The antidiuretic action of nicotine was not inhibited by ethanol, nor by...Full Text Available

1957-12-01

15

Alternative fuel trucks case studies: Running line-haul trucks on ethanol  

Energy Technology Data Exchange (ETDEWEB)

This bulletin describes case studies of trucks operating on ethanol fuel. Cost, maintenance and repair, as well as fuel economy are discussed.

1996-10-01

16

Modification of the Gaussian dispersion equation to accommodate restricted lateral dispersion in deep river valleys  

Energy Technology Data Exchange (ETDEWEB)

Lateral plume dispersion in deep river valleys during neutral and stable lapse rate conditions can be exceptionally high due to the intense horizontal turbulence generated by prominent variations in the width, orientation and surface roughness of the valley walls. Use of the standard Gaussian dispersion equation to represent this enhanced lateral plume spread in a narrow valley may be inappropriate since consideration should also be given to the restriction of the horizontal plume spread due to impingement against the valley walls. The basic concept employed in the modification of the Gaussian dispersion equation was to assume that multiple eddy reflections occur between the valley walls in a manner similar to the vertical eddy reflections between the ground plane and an inversion layer aloft. The expressions are developed, but no attempt has been made to validate them with actual ...

1986-02-01

17

Ethanol production and a case study of ethanol produced from sweet sorghum stalks via solid state fermentation  

Energy Technology Data Exchange (ETDEWEB)

Ethanol has excellent fuel properties, such as high octane, high heat of vaporization and low photochemical reactivity in the atmosphere. It is less volatile than gasoline and there is lower smog formation from evaporative emissions of pure ethanol compared to gasoline. As such, ethanol has emerged as an important alternative energy source that is sustainable, efficient, cost effective, convenient and safe. In 2006, global production of ethanol reached 13.5 billion gallons, up from 12.1 billion gallons in 2005. However, in light of the current debate of food versus fuel, the industry must shift to non-food feedstocks. This paper described an emerging technology to cost-effectively produce ethanol from sweet sorghum stalks, the most promising alternative feedstock to corn, via solid state fermentation (SSF). Experiments of advanced solid state fermentation (ASSF) for ...

2008-07-01

18

New steam heart for the Pernis refinery [in the Netherlands]; Nieuw stoomhart voor Pernis  

Energy Technology Data Exchange (ETDEWEB)

The Construction of a natural gas-fired combined heat and power plant at the site of the Pernis refinery will further reduce the emission of SO2 and NOx. [mk]. [Dutch] Met de bouw van een aardgasgestookte warmte/kracht-installatie op het terrein van de raffinaderij Pernis wordt de emissie van SO2 en NOx verder gereduceerd.

2009-05-15

19

A duplex real-time RT-PCR assay for the detection of California serogroup and Cache Valley viruses  

UK PubMed Central (United Kingdom)

A duplex TaqMan real-time RT-PCR assay was developed for the detection of California (CAL) serogroup viruses and Cache Valley virus (CVV), for use in human surveillance. The targets selected...Full Text Available

2009-10-01

20

A Helicopter-Borne Magnetic Survey over Dixie Valley Geothermal...  

Science.gov (United States)

Name U.S. Geological Survey A Helicopter-Borne Magnetic Survey over Dixie Valley Geothermal Field, Nevada: A Web Site for Distribution of Data by U. S. Geological Survey &...

2011-08-20

25

Experimental studies on fumigation of ethanol in a small capacity Diesel engine  

British Library Electronic Table of Contents (United Kingdom)

To diversify the mix of domestic energy resources and to reduce dependence on imported oil, ethanol is widely investigated for applying in combination with Diesel fuel to reduce pollutants, including smoke and NOx. Present work aims at developing a fumigation system for introduction of ethanol in a small capacity Diesel engine and to determine its effects on emission. Fumigation was achieved by using a constant volume carburetor. Different percentages of ethanol fumes with air were then introduced in the Diesel engine, under various load conditions. Ethanol is an oxygenated fuel and lead to smooth and efficient combustion. Atomization of ethanol also results in lower combustion temperature. During the present study, gaseous emission has been found to be decreasing with ethanol fumigation. ...

2011-01-01

26

Factors affecting actions of ethanol on GABA-activated chloride channels  

International Nuclear Information System (INIS)

Effects of ethanol in vitro on membrane vesicles were evaluated by monitoring "3"6Cl"- influx. Different assay parameters were tested to determine increased or decreased action of ethanol on GABA-activated chloride channels. The ability of 30 mM ethanol to augment "3"6Cl"- flux was seen at 0 degree C, in the absence of GABA, and at 34 degree C in the presence of GABA, using two different assay procedures. Picrotoxin blocked the direct effects of ethanol suggesting GABA_a involvement. Endogenous GABA in the medium surrounding the microsacs was assayed at different temperatures both in the presence and absence of GABA and ethanol. The direct effect of ethanol did not appear to involve the action of endogenous GABA. In addition to temperature effects on the assay, time of membrane storage also influenced ethanol action. Microsacs stored on ice ...

27

An enzyme-amplified microtiter plate assay for ethanol: Its application to the detection of peanut ethanol and alcohol dehydrogenase  

Energy Technology Data Exchange (ETDEWEB)

A calorimetric microliter plate assay for ethanol amplified by aldehyde dehydrogenase (ALDH) was developed. In the assay ethanol from a sample took part in a chain-reaction catalyzed by alcohol dehydrogenase (ADH) and amplified by ALDH in the presence of NAD{sup +}, diaphorase, and p-ibdonitrotetrazolium-violet (INT-violet)(a precursor of red product). The resultant reaction gave a red color, the intensity of which was proportional to the amount of ethanol present. Using the technique, the content of activity from peanuts of differing maturity and curing stages were determined respectively. Data showed that immature peanuts had a higher level of ethanol and a lower ADH activity than mature peanuts, and that the level of ethanol and ADH activity decreased with the curing time. This indicates that peanut maturity and curing have an effect on ethanol. Also, this ...

1995-12-01

28

The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils: A multi-technique investigation  

British Library Electronic Table of Contents (United Kingdom)

Aerial deposition of Ni from a refinery in Port Colborne, Ontario, Canada has resulted in the enrichment of 29km2 of land with Ni concentrations exceeding the Canadian Ministry of the Environment's remedial action level of 200mgkg-1. Several studies on these soils have shown that making the soils calcareous was effective at reducing chemically extractable Ni, as well as alleviating Ni phytotoxicity symptoms in vegetable crops grown in the vicinity of the refinery. Conversely, dolomitic limestone additions resulted in increased uptake of Ni in the Ni hyperaccumulator Alyssum murale `Kotodesh', a plant whose use was proposed as a remediation strategy for this area. In this paper we use multiple techniques to directly assess the role soil type and lime treatments play in altering the speciati...

2007-01-01

29

The Thai evolution  

International Nuclear Information System (INIS)

The effects of the fluctuations of the Thai economy of the country's petroleum industry and the outlook for the future are discussed. Thailand witnessed enormous economic growth during the 1980s and the first part of the 1990s, but events since 1997 have caused it to stutter. However, the petroleum industry remains buoyant with measures to stimulate gas and oil production and moves to privatise and deregulate energy markets. Key statistics for Thailand, historical demand trends for petroleum, the impact of the 1997 Asian economic crisis, regulation of the Thai oil market, crude and condensate production levels, refinery capacity, new entrants to the refinery sector, the Thai refinery expansion programme, the product trade balance, the challenges of fuel reformulation and demand scenarios are considered.

2001-08-01

30

The effect of ethanol on "3"5-S-TBPS binding to mouse brain membranes in the presence of chloride  

International Nuclear Information System (INIS)

The effect of in vitro and in vivo administration of ethanol on the binding of "3"5S-t-butyl-bicyclophosphorothionate ("3"5S-TBPS) to cortical brain membranes of C57B1 mice was investigated using KCl (100 mM) containing assay media. The in vitro addition of ethanol produced a dose-dependent inhibition of basal "3"5S-TBPS binding. In the presence of chloride ions, GABA and pentobarbital had a biphasic action (stimulation followed by inhibition) on "3"5S-TBPS binding, whereas diazepam only stimulated the binding. Ethanol reduced the stimulatory effects of GABA and pentobarbital in a dose-dependent manner, but had no effect on the enhancement of "3"5S-TBPS binding produced by diazepam. "3"5S-TBPS binding to cortical brain membranes was inhibited by the putative Cl"- channel blocking agent DIDS. This inhibitory action of DIDS was significantly, and dose-dependently reduced by ethanol (#<=# 100 mM ...

31

New views on the hypothesis of respiratory cancer risk from soluble nickel exposure; and reconsideration of this risk's historical sources in nickel refineries  

UK PubMed Central (United Kingdom)

IntroductionWhile epidemiological methods have grown in sophistication during the 20th century, their application in historical occupational (and environmental) health...Full Text Available

33

33 CFR 148.105 - What must I include in my application?  

Science.gov (United States)

...capacity, and ownership of all planned and existing onshore pipelines, storage facilities, refineries, petrochemical...will be served by the port, including: (i) Onshore pipelines; (ii) Storage facilities; (iii)...

2010-07-01

34

Refiners wrestle with air pollution  

Energy Technology Data Exchange (ETDEWEB)

Survey report: The Petroleum Association for the Conservation of the Canadian Environment is an organization of petroleum refiners that works closely with the Canadian government to set realistic air pollution control standards for refinery emissions. To date, the refiners have made a substantial investment in pollution abatement equipment. As a result, there have been no major pollution incidents traceable to refinery emissions. In the future, it will be essential that refiners continue to invest in air pollution abatement measures and continue to cooperate with the government in setting achievable pollution control standards. (1 photo, 1 table)

1980-01-01

35

A review and update of refining practice in Canada  

International Nuclear Information System (INIS)

This paper first reviews the history of the Port Hope uranium refinery of Eldorado Nuclear Limited. The current processes used for the production of UO_3, UO_2 and UF_6 from yellow cake are then discussed. Recent process changes and developments in the areas of solvent extraction and UO_3 production together with new processes for the production of ceramic UO_2 and UF_4, are described. Environmental and waste management problems, progress and solutions are next considered. Finally, some experience in siting a new UF_6 refinery, with respect to Environmental Impact Statements and public hearings, conclude the paper. (author).

1979-06-08

36

Simultaneous and Enhanced Production of Thermostable Amylases and Ethanol from Starch by Cocultures of Clostridium thermosulfurogenes and Clostridium thermohydrosulfuricum  

UK PubMed Central (United Kingdom)

Clostridium thermohydrosulfuricum and Clostridium thermosulfurogenes produced ethanol and amylases with different components as primary metabolites of starch fermentation....Full Text Available

1985-05-01

37

Protracted ethanol withdrawal in rats: Tolerance to the anxiolytic effects of diazepam and pentobarbital but not phenobarbital  

Science.gov (United States)

Anxiety is a common symptom during ethanol withdrawal contributing to its continuous abuse and alcoholism. Ethanol withdrawal in rats produces an interoceptive discriminative stimulus (IDS) similar to that produced by the anxiogenic drug pentylenetetrazol (PTZ). This stimulus peaks at 12 hours after last dose of ethanol and thereafter the IDS is detected for several days (protracted withdrawal) by sensitization to a probe drug. previously, the authors have shown that during the protracted withdrawal, the IDS is enhanced by GABA receptor antagonists suggesting alteration of brain GABA systems. This report provides further evidence that chronic ethanol alters GABAergic systems. Rats were trained to discriminate PTZ (20 mg/kg, ip) from saline. Diazepam, pentobarbital and phenobarbital blocked the PTZ-IDS dose dependently. Ethanol, 4.5% w/v, was then given in a nutritionally complete ...

1990-02-26

38

Prosocial effects of nicotine and ethanol in adolescent rats through partially dissociable neurobehavioral mechanisms  

UK PubMed Central (United Kingdom)

The widespread use of tobacco and alcohol among adolescents might be related to the ability of nicotine and ethanol to facilitate social interactions. To investigate the neurobehavioral mechanisms...Full Text Available

2009-11-01

39

Performance and Emission Characteristics of Diesel Engine Fueled with Ethanol-Diesel Blends in Different Altitude Regions  

UK PubMed Central (United Kingdom)

In order to investigate the effects ethanol-diesel blends and altitude on the performance and emissions of diesel engine, the comparative experiments were carried out on the bench of turbo-charged diesel...Full Text Available

2011-01-01

40

Interaction effects of ethanol and pyrazole in laboratory rodents  

UK PubMed Central (United Kingdom)

1. Interactions of pyrazole and ethanol were studied in three laboratory test procedures. They included sleeping time in mice, rotor rod balance in rats and lever pressing behaviour of rats. 2....Full Text Available

1971-09-01

41

Increased ethanol resistance in Ethanolic Escherichia coli by Insertion of heat-shock genes BEM1 and SOD2 from Saccharomyces cerevisiae  

British Library Electronic Table of Contents (United Kingdom)

Ethanol is generally toxic to microorganisms, and intracellular and extracellular accumulation of ethanol inhibits cell growth and metabolism. In this study, pyruvate decarboxylase (pdc) and alcohol dehydrogenase (adhB) were cloned into pET-32a vector and then introduced into E. coli BL21 to produce ethanol. Heat shock genes (BEM1 and SOD2) from Saccharomyces cerevisiae were inserted into recombinant ethanolic E. coli using pET28_a vector to improve ethanol shock resistance. Three different strains were constructed: Ethanolic E. coli (adhB and pdc genes inserted using pET32_a vector), BEM1 gene-inserted E. coli (BEM1 inserted using pET_28a), and SOD2-inserted E. coli (SOD2 inserted using pET28_a). Construction of these three different strains allowed comparison of the functions of these he...

2010-01-01

42

Disruption of Circulation by Ethanol Promotes Fetal Alcohol Spectrum Disorder (FASD) in Medaka (Oryzias latipes) Embryogenesis  

UK PubMed Central (United Kingdom)

Japanese medaka (Oryzias latipes) embryos exposed to ethanol have developed craniofacial, cardiovascular and skeletal defects which can be compared with the phenotypic features...Full Text Available

2008-09-01

43

Antinociceptive and Anti-Inflammatory Activities of the Ethanol Extract of Annona muricata L. Leaves in Animal Models  

UK PubMed Central (United Kingdom)

Antinociceptive and anti-inflammatory activities of the ethanol extract from Annona muricata L. leaves were investigated in animal models. The extract delivered per oral route (p.o.)...Full Text Available

44

Anti-ulcerogenic and in vitro antioxidant activities of Lagenaria breviflora (LB) whole fruit ethanolic extract in laboratory animals  

UK PubMed Central (United Kingdom)

Background:The present study was undertaken to evaluate the anti-ulcer and antioxidant activities of the ethanol extract of Lagenaria breviflora (EELB)...Full Text Available

2011-01-01

45

Adaptation to alcoholic fermentation in Drosophila: a parallel selection imposed by environmental ethanol and acetic acid.  

UK PubMed Central (United Kingdom)

Besides ethanol, acetic acid is produced in naturally fermenting sweet resources and is a significant environmental stress for fruit-breeding Drosophila populations and species. Although not related...Full Text Available

1993-04-15

46

Acetaldehyde and Ethanol Biosynthesis in Leaves of Plants 1  

UK PubMed Central (United Kingdom)

Leaves of terrestrial plants are aerobic organs, and are not usually considered to possess the enzymes necessary for biosynthesis of ethanol, a product of anaerobic fermentation. We examined the ability...Full Text Available

1987-08-01

47

Acamprosate and naltrexone treatment effects on ethanol and sucrose seeking and intake in ethanol-dependent and nondependent rats  

UK PubMed Central (United Kingdom)

RationaleTwo pharmacotherapies are approved for treating alcohol craving (acamprosate and naltrexone), but both have shown mixed findings in animals and humans.Full Text Available

2009-06-01

51

Lignocellulosic feedstock resource assessment  

Energy Technology Data Exchange (ETDEWEB)

This report provides overall state and national information on the quantity, availability, and costs of current and potential feedstocks for ethanol production in the United States. It characterizes end uses and physical characteristics of feedstocks, and presents relevant information that affects the economic and technical feasibility of ethanol production from these feedstocks. The data can help researchers focus ethanol conversion research efforts on feedstocks that are compatible with the resource base.

1998-09-01

52

Feasibility study for a 10 MM GPY fuel ethanol plant, Brady Hot Springs, Nevada. Volume II. Geothermal resource, agricultural feedstock, markets and economic viability  

Energy Technology Data Exchange (ETDEWEB)

The issues of the geothermal resource at Brady's Hot Springs are dealt with: the prospective supply of feedstocks to the ethanol plant, the markets for the spent grain by-products of the plant, the storage, handling and transshipment requirements for the feedstocks and by-products from a rail siding facility at Fernley, the probable market for fuel ethanol in the region, and an assessment of the economic viability of the entire undertaking.

1980-09-01

53

Extraction and analysis of antioxidant components from Origanum dictamnus  

British Library Electronic Table of Contents (United Kingdom)

Three alternative extraction procedures were carried out in order to separate the antioxidant components and isolate an efficient extract from Origanum dictamnus. Procedure A included sequential extractions with petroleum ether (PE), diethyl ether (DE) and ethanol; procedure B sequential extractions with PE and ethyl acetate (EAc); procedure C a single step extraction with ethanol. The most efficient radical scavengers, according to the DPPH method, were isolated in ethanol extract of procedure A (mainly rosmarinic acid), followed by ethanol extract of procedure C. However, both ethanol extracts had low solubility in oil and could not protect it. EAc and DE extracts, containing mainly apigenin and epirosmanol ethyl ether, presented lower radical scavenging activity but were very effective ...

2007-01-01

54

Distribution of Fuel-Grade Ethanol near a Dynamic Water Table  

British Library Electronic Table of Contents (United Kingdom)

Injections of fuel-grade ethanol (95% v/v ethanol, 5% v/v hydrocarbon mixture as a denaturant) near the water table were conducted in two-dimensional physical models tightly packed with fine sands under varying water-table conditions. As the fuel migrated in the porous media following injection, the denaturant phase separated leaving a residual Light Non-Aqueous Phase Liquid (LNAPL) phase that occupied a region with a volume similar to that of an equal-sized spill of 100% LNAPL without ethanol. When the water table was raised, as may be expected following a catastrophic release that reaches groundwater, most of the ethanol-fuel mixture was mobilized and the vertical distribution of the generated LNAPL was increased. The lower boundary of the residual LNAPL was established during the initia...

2011-01-01

55

Compact Single-Stage Fuel Processor for PEM Fuel Cells. Final report  

Energy Technology Data Exchange (ETDEWEB)

Based on observations during the steam reforming of ethanol, the authors conclude that carbon was forming in the steam generator due to the thermal decomposition of ethanol. Since ethanol is being thermally decomposed, they were operating the steam generator at too high of a temperature. The thermal degradation of ethanol was confirmed by using a GC with a flame ionization detector. They observed trace amounts of additional hydrocarbons other than methane in the effluent which we assume maybe ethane and ethylene. We identified the operating conditions that allowed us to steam reform ethanol for an acceptable amount of time. These conditions were a steam temperature of 200 C and a wall temperature of 400 C at the center of the reactor. The calculated ratios of CO{sub 2}/CO indicate that we can lower the potential for carbon deposition from the Boudouard further by reducing the ...

2000-01-01

56

Study of ethanol-lysozyme interactions using neutron diffraction  

International Nuclear Information System (INIS)

Single-crystal neutron diffraction has been used to observe the interactions between deuterated ethanol (CD3CD2OH) and lysozyme in triclinic crystals of hen egg white lysozyme soaked in 25% (v/v) ethanol solutions. A total of 6047 observed reflections to a resolution of 2 A were used, and 13 possible ethanol sites were identified. The three highest occupied sites are close to locations for bromoethanol found in an earlier study by Yonath et al. [Yonath, A., Podjarny, A., Honig, B., Traub, W., Sielecki, A., Herzberg, O., and Moult, J. (1978) Biophys. Struct. Mech. 4, 27-36]. Structure refinements including a model for the flat solvent lead to a final crystallographic agreement factor of 0.097. Comparison with earlier neutron studies on triclinic lysozyme showed that neither the molecular structure nor the thermal motions were affected significantly by the ethanol. A detailed analysis of the ...

57

Fish Research Project Oregon; Aspects of Life History and Production of Juvenile Oncorhynchus Mykiss in the Grande Ronde River Basin, Northeast Oregon, 1995-1999 Summary Report.  

Energy Technology Data Exchange (ETDEWEB)

Rotary screw traps, located at four sites in the Grande Ronde River basin, were used to characterize aspects of early life history exhibited by juvenile Onchorhychus mykiss during migration years 1995-99. The Lostine, Catherine Creek and upper Grande Ronde traps captured fish as they migrated out of spawning areas into valley rearing habitats. The Grande Ronde Valley trap captured fish as they left valley habitats downstream of Catherine Creek and upper Grande Ronde River rearing habitats. Dispersal downstream of spawning areas was most evident in fall and spring, but movement occurred during all seasons that the traps were fished. Seaward migration occurred primarily in spring when O. mykiss smolts left overwintering area located in both spawning area and valley habitats. Migration patterns exhibited by O. mykiss suggest that Grande Ronde Valley habitats are used for overwintering ...

2001-07-01

58

Prosocial effects of nicotine and ethanol in adolescent rats through partially dissociable neurobehavioral mechanisms  

Science.gov (United States)

The widespread use of tobacco and alcohol among adolescents might be related to the ability of nicotine and ethanol to facilitate social interactions. To investigate the neurobehavioral mechanisms underlying the prosocial effects of nicotine and ethanol, we focused on social play behavior, the most characteristic social activity in adolescent rats. Social play behavior is rewarding, and it is modulated through opioid, cannabinoid and dopaminergic neurotransmission, which are also involved in the reinforcing properties of nicotine and ethanol. We found that nicotine and ethanol increased social play, without affecting locomotion or social exploration. Their effects depended on the level of social activity of the partner, and were comparable in familiar and unfamiliar environments. At doses that increased social play, nicotine and ethanol had no anxiolytic effects in the elevated ...

2009-08-05

59

Enhanced ethanol production via fermentation of rice straw with hydrolysate-adapted Candida tropicalis ATCC 13803  

British Library Electronic Table of Contents (United Kingdom)

Neutralized hydrolysate and pretreated rice straw obtained from a 2% (w/v) sulfuric acid pretreatment were mixed at 10% (w/v) and subjected to simultaneous saccharification and co-fermentation (SSCF), with cellulase, b-glucosidase, and Candida tropicalis cells at 15FPU/g-ds, 15IU/g-ds and 1x10^9cells/ml, respectively. A 36-h SSCF with adapted cells resulted in YP/S and ethanol volumetric productivity of 0.36g/g and 0.57g/l/h, respectively. In addition to ethanol, insignificant amounts of glycerol and xylitol were also produced. Adapted C. tropicalis cells produced nearly 1.6 times more ethanol than non-adapted cells. Ethanol yield (Yp/s), ethanol volumetric productivity and a xylitol concentration of 0.48g/g, 0.33g/l/h and 0.89g/l, respectively, were produced from fermentation of remaining...

2010-01-01

60

Waste acid recycling via diffusion dialysis  

Energy Technology Data Exchange (ETDEWEB)

Inorganic acids are commonly used for surface cleaning and finishing of metals. The acids become unuseable due to contamination with metals or diluted and weakened. Diffusion dialysis has become a way to recover the useable acid and allow separation of the metals for recovery and sale to refineries. This technique is made possible by the use of membranes that are strong enough to withstand low ph and have long service life.

1995-05-26

61

State of the energy in Lebanon  

International Nuclear Information System (INIS)

The article describes the state of the energy in Lebanon. In 1996, Lebanon consumed 4647 Ktoe as a primary energy. 97% of this energy is imported mainly polluting oil products: 1623 Ktons fuel-oil, 1379 Ktons gasoline, 930 Ktons diesel, 200 Ktons coal, 124 Ktons LPG, 107 Ktons jet-fuel/Kerosene, 109 Ktons Asphaltic products. The remaining 3% of the energy consumption is renewable energy. As for production, the state owns two refineries which are not used anymore. The year 2000 plan includes an expansion project for the Tripoli refinery and an alternative plan for the Zahrani refinery. These refineries require a total investment in order to reach a production capacity of 50000 barrels a day. The article is a description of the pollution type sources and location in Lebanon. The combustion of the total energy produces yearly more than 15 Ktons of dust, 85 Ktons of SO_2, 40 Ktons of NOX and 3500 Ktons of ...

1998-04-01

62

Siemens provides treatment packages for oil production  

British Library Electronic Table of Contents (United Kingdom)

Modec International Inc has selected Siemens Water Technologies to provide sea-water reverse osmosis (SWRO) systems for several floating, production, storage and offloading (FPSO) vessels that are to be operated in deep-water locations. Siemens is also supplying a wastewater reuse system to one of Brazils largest refineries.

2010-01-01

63

High temperature heat transfer augmentation  

International Nuclear Information System (INIS)

The heat transfer augmentation is reviewed in view of high temperature heat exchangers illuminating the contribution of radiative heat transfer. A number of means and/or devices are presented as well as the sophisticated concept which will be promoted to the extended applications in matured industries such as iron and steel, oir refinery, petro-chemical. It should be emphasized that the more creative and innovatory technology has to be promoted in order to stimulate and refresh the foregoing industries, recognizing the increasing importance of the energy resources.

1985-08-01

64

Accelerated aging tests with a resid hydrotreating catalyst  

International Nuclear Information System (INIS)

The author discusses the accelerated aging tests performed using Hondo and Maya as aging resids with a commercial large pore hydrotreating catalyst. The results from these tests were compared with those obtained under a normal full life test. The test resid was a sample of a typical refinery charge and the activities for sulfur and vanadium removal were determined at 720"0F after successive brief periods of exposure to the heavier oils.

1988-12-02

65

Pyogenic abscess of the PSOAS - Description of cases registered in the university hospital of the valley  

International Nuclear Information System (INIS)

In this chart review the authors describe 51 cases of PSOAS abscess treated at Hospital Universitario del Valle in Cali, Colombia in the last 10 years. It is not a rare condition and require high index of suspicion. epidemiology, bacteriology, diagnosis and treatment are discussed.

2006-06-01

66

Preliminary parasitological results of a pilot mollusciciding campaign to control transmission of Schistosoma mansoni in St Lucia*  

UK PubMed Central (United Kingdom)

A mollusciciding campaign was begun in Cul-de-Sac Valley, St Lucia, at the end of 1970, following several years of epidemiological studies in which transmission of Schistosoma mansoni...Full Text Available

1976-01-01

67

Prediction of a Rift Valley fever outbreak  

UK PubMed Central (United Kingdom)

El Niño/Southern Oscillation related climate anomalies were analyzed by using a combination of satellite measurements of elevated sea-surface temperatures and subsequent elevated rainfall and...Full Text Available

2009-01-20

68

How representative was the 1996 VOTALP Mesolcina Valley campaign?  

Energy Technology Data Exchange (ETDEWEB)

Each meteorological measurement reflects the conditions under which it was obtained, e.g. site, weather, and instrumentation. It is shown how the VOTALP Intensive Observation Periods (IOPs) were embedded in the climatic context of the summer months of 1996. (author) 1 fig., 2 refs.

1999-08-01

69

Characterization of atmospheric aerosol near motor way: Bassa Valle Susa (Italy); Caratterizzazione dell`aerosol atmosferico in prossimita` di un`autostrada: Bassa Valle Susa  

Energy Technology Data Exchange (ETDEWEB)

Results related to the experimental measurement campaign to characterize atmospheric aerosol carried out near Avigliana (Turin) from 18 to 22 October 1994 are presented in this paper. In the frame of the project aimed at evaluating the impact of the mountain motor way A-32 Rivoli-Bardonecchia-Frejus on the Susa Valley environment and on man the present measurement campaign is the second, and last, one envisaged in the project. The sampling place is in the initial part of the Susa Valley while previous measurements were carried out in the high part of it. Mass mean concentrations result greater in the low than in the high part of the valley approximately by a factor of 3. It is not possible to prove a difference between the 3 sampling positions transversely placed from 20 to 80 m. in comparison with the motor way axis. Whereas mass mean concentrations dropped substantially due to atmospheric precipitations during the last ...

1995-10-01

70

A socioecological approach to the control of Schistosoma mansoni in St Lucia  

UK PubMed Central (United Kingdom)

Systematic observations of man/water contact in a valley endemic for S. mansoni in St Lucia were carried out prior to the introduction of a household water supply. The observations...Full Text Available

1976-01-01

71

Stratigraphy and sedimentary environment of the Coalspur Formation  

Energy Technology Data Exchange (ETDEWEB)

The Coalspur Formation is a continental succession of interbedded mudstone, siltstone and fine grained sandstone with subordinate coarser grained sandstone layers and channel lag deposits. Chert-pebble conglomerate (the Entrance conglomerate) occurs at the base of the formation, and coal beds interbedded with coaly shale and numerous thin bentonites occur in the upper part of the formation. An economically significant amount of high-quality thermal coal occurs within the upper, Paleocene part of the formation named the Coalspur coal zone. Coal from this zone, also known as the Coal Valley coal zone is being exploited in the Coal Valley Mine. 17 refs., 4 figs.

1990-01-01

72

Strained silicon for quantum computing  

Energy Technology Data Exchange (ETDEWEB)

Strains in multivalley semiconductors can destroy the strict equivalence of the valleys that is demanded by cubic symmetry. Significant changes in the properties of a semiconductor may result. A proposed implementation of quantum computing with donor atoms in silicon would suffer from alterations of the donor wave functions caused by strains that are produced by fabrication processes. Deliberately straining the silicon to an extent that removed all but one valley from participation in the lowest donor state, would prevent further changes in the wave function by strain. The strain required can be achieved with established technology for depositing silicon on SiGe alloys. (author)

2002-03-07

73

Combustion performance of Coal Valley coal in a pilot-scale utility boiler. Report No. ERL 87-18(CF)  

Energy Technology Data Exchange (ETDEWEB)

Combustion performance trials were conducted on a commercial sample of Coal Valley coal from the Coalspur coalfield in the foothills region of Alberta. The project included an analytical investigation of the coal and coal ash properties as well as combustion studies in the CCRL pilot-scale, pulverized coal-fired boiler, under conditions representative of those in large steam boilers. This report gives the objectives of the project, the analyses of the coals, and describes the facilities and operational procedures. An evaluation of the experimental results and the conclusions are presented.

1987-01-01

74

l-Proline-catalyzed one-pot expeditious synthesis of highly substituted pyridines at room temperature  

British Library Electronic Table of Contents (United Kingdom)

Only 15mol% of l-proline in ethanol proved to be a very efficient catalyst for the one-pot synthesis of a wide variety of highly substituted pyridines at room temperature. The methodology is mild, efficient, high yielding, and the products can be directly recrystallized from hot ethanol.

2010-01-01

75

Report on the engineering and economics of an ethanol/gasohol joint-venture project with Caldwell Sugars Co-op, Inc. at Thibodaux, Louisiana. Attachment B, Volume III. Definitive estimate. Section 1: terminal  

Energy Technology Data Exchange (ETDEWEB)

A detailed definitive cost estimate is given for an ethanol/gasohol storage and blending terminal serving a planned distillery at a Louisiana sugar factory. Included are an analysis of the accuracy of the estimate, labor rates efficiency, materials and labor escalation, as well as detailed calculations for each account of the project. (LEW)

1982-04-01

76

Conformational transitions of alternating purine-pyrimidine DNAs in perchlorate ethanol solutions.  

UK PubMed Central (United Kingdom)

Conformational transitions of poly(dA-dC).poly(dG-dT), poly(dA-dT).poly(dA-dT), and other alternating purine-pyrimidine DNAs were studied in aqueous ethanol solutions containing molar concentrations...Full Text Available

1995-11-01

77

Separation of the components of the binary mixture ethanol-water by steam flux in solid phase column; Separacao dos componentes da mistura binaria etanol-agua por passagem do vapor em coluna de fase solida  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

1987-12-31

78

Effect of ethanol-diesel blend fuels on emission and particle size distribution in a common-rail direct injection diesel engine with warm-up catalytic converter  

Energy Technology Data Exchange (ETDEWEB)

In this study, the exhaust gas from a common-rail direct injection diesel engine was investigated both upstream and downstream warm-up catalytic converters (WCC). Three different types of ultra-low sulfur fuels (ethanol-diesel blend, ethanol-diesel blend with cetane improver and pure diesel) were tested in this study. The objective of the work was to study the engine performance and the formation of THC (total hydro carbon), CO (carbon monoxide), NO{sub x} (nitrogen oxides), smoke and PM (particulate matters) when using these fuels. THC and CO emissions of the ethanol-diesel blend fuels were slightly increased, and about 50-80% mean conversion efficiencies of THC and CO on catalysts were achieved in the ECE R49 13-mode cycle. Smoke was decreased by more than 42% in the entire ECE 13-mode cycles. From the measurement of scanning mobility particle sizer (SMPS) for the particle size range of 10-385 nm, the total number and ...

2008-10-15

79

Techno-economic comparison of a biological hydrogen process and a 2nd generation ethanol process using barley straw as feedstock  

British Library Electronic Table of Contents (United Kingdom)

A process combining dark fermentation and photofermentation for production of hydrogen is interesting due to its potential of producing hydrogen at a high yields. In this study, the hydrogen process is compared to a 2nd generation ethanol process with respect to cost and with the aim of increasing our understanding of the pros and cons and giving a clear picture of the present status of the two processes. The hydrogen production cost was found to be about 20 times higher than the ethanol production cost, 421.7&z.euro;/GJ compared to 19.5&z.euro;/GJ. The main drawbacks of the hydrogen process are its low productivity, low energy efficiency, and the high cost of buffer and base required to control the pH.

2011-01-01

80

Reversed light-dark cycle and cage enrichment effects on ethanol-induced deficits in motor coordination assessed in inbred mouse strains with a compact battery of refined tests  

British Library Electronic Table of Contents (United Kingdom)

The laboratory environment existing outside the test situation itself can have a substantial influence on results of some behavioral tests with mice, and the extent of these influences sometimes depends on genotype. For alcohol research, the principal issue is whether genotype-related ethanol effects will themselves be altered by common variations in the lab environment or instead will be essentially the same across a wide range of lab environments. Data from 20 inbred strains were used to reduce an original battery of seven tests of alcohol intoxication to a compact battery of four tests: the balance beam and grip strength with a 1.25g/kg ethanol dose and the accelerating rotarod and open-field activation tests with 1.75g/kg. The abbreviated battery was then used to study eight inbred str...

2011-01-01

81

Recovery of transplutonium elements from aqueous and water-ethanol solutions of sulfuric acid and their separation from other actinides  

Energy Technology Data Exchange (ETDEWEB)

The behavior of Am, Cm, Bk, Cf, Es, and other actinides, as well as Zr, on anion and cation exchangers in aqueous and water-ethanol solutions of sulfuric acid as a function of the various components of the solution has been investigated. It has been discovered that the presence of ethanol in sulfuric acid solutions causes an increase in the distribution coefficients both on cation exchangers and on anion exchangers. The possibility of the use of ion exchangers for the preconcentration and separation of transplutonium elements from U, Np, Pu, Zr, and other elements which form strong complexes with sulfate ions over a broad range of concentrations of sulfuric acid has been demonstrated.

1988-05-01

82

Phase equilibrium measurements of ternary systems formed by linoleic and linolenic acids in carbon dioxide/ethanol mixtures  

British Library Electronic Table of Contents (United Kingdom)

This work reports phase equilibrium measurements for the ternary systems linoleic (acid+CO2+ethanol) and (linolenic acid+CO2+ethanol). The fatty acids present in the ternary systems were selected based on composition of banana peel oil extracted by supercritical CO2 at 20MPa and 313K. The motivation of this research relies on the fact that these unsaturated fatty acids are recognized to play an important role in lowering blood pressure and serum cholesterol and because they are present in high concentrations in banana peel extract. Besides that, equilibrium data of these compounds are scarce in literature. The phase equilibrium experiments were performed using a high-pressure variable-volume view cell over the temperature range of (303 to 343)K and pressures up to 19MPa. For both systems, ...

2009-01-01

83

Homolytic cleavage C-C bond in the electrooxidation of ethanol and bioethanol  

British Library Electronic Table of Contents (United Kingdom)

Nowadays, the studies are focused on the search of better electrocatalysts that promote the complete oxidation of ethanol/bioethanol to CO2. To that end, amorphous bi-catalytic catalysts of composition Ni59Nb40Pt1-xYx (Y=Cu, Ru, x=0.4% at.) have been developed, obtained by mechanical alloying, resulting in higher current densities and an improvement in tolerance to adsorbed CO vs. Ni59Nb40Pt1 catalyst. By using voltammetric techniques, the appearance of three oxidation peaks can be observed. The first peak could be associated with the electrooxidative process of ethanol/bioethanol to acetaldehyde, the second peak could be the oxidation of acetaldehyde to acetic acid, and the last peak might be the final oxidation to CO2. Chrono-amperometric experiments show qualitative poisoning of catalyt...

2011-01-01

84

Effect of charge dilution on gaseous and particulate emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol and ethanol  

British Library Electronic Table of Contents (United Kingdom)

In this study, the effect of intake charge dilution with carbon dioxide on the combustion and emission characteristics of a 4-cylinder direct-injection diesel engine fueled with biodiesel, ethanol-biodiesel and methanol-biodiesel were investigated. With increase of intake CO"2 concentration, CO, HC, particulate mass concentration, particle number concentration and geometric diameter (GMD) of all fuels increased while NO"x decreased obviously. After addition of methanol and ethanol in biodiesel, the NO"x, particulate mass concentration and particle number concentration decreased at each intake CO"2 concentration, compared with biodiesel. Moreover, as the intake CO"2 concentration increased from 2% to 5.6%, particulate mass concentration of the alcohol-biodiesel blends remained almost unchan...

2011-01-01

85

A study of binary mixture boiling: boiling site density and subcooled heat transfer  

Energy Technology Data Exchange (ETDEWEB)

(Boiling site densities and heat-transfer coefficients have been measured for ethanol-water and ethanol-benzene mixtures at 1.01 bar for a heated vertical brass disk. A strong effect of composition on the boiling site density was observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The boiling heat-transfer coefficient was found to decrease with increasin subcooling, but for the mixtures at a given level of subcooling the decrease was less than that for the single components and azeotropic mixtures.) The heat-transfer coefficient at a given heat flux was seen to be quite insensitive to the very large increase in boiling site density in comparing the pure water and the ethanol-water azeotrope results, leading one to question pool boiling models that predict heat-transfer rates on the basis of boiling site density.

1985-05-01

86

COMPARISON OF NATURAL BACKGROUND DOSE RATES FOR RESIDENTS OF THE AMARGOSA VALLEY, NV, TO THOSE IN LEADVILLE, CO, AND THE STATES OF COLORADO AND NEVADA  

Energy Technology Data Exchange (ETDEWEB)

In the latter half of 2005, the U.S. Environmental Protection Agency (USEPA) published a Proposed Rule (40 CFR Part 197) for establishing a dose rate standard for limiting radionuclide releases from the proposed Yucca Mountain high-level radioactive waste repository during the time period from 10{sup 4} to 10{sup 6} years after closure. The proposed standard was based on the difference in the estimated total dose rate from natural background in the Amargosa Valley and the ''average annual background radiation'' for the State of Colorado. As defined by the USEPA, ''natural background radiation consists of external exposures from cosmic and terrestrial sources, and internal exposures from indoor exposures to naturally-occurring radon''. On the basis of its assessments, the USEPA estimated that the difference in the dose rate in the two identified areas was 3.5 mSv y{sup -1}. The purpose of this ...

2006-02-24

87

Multi-unit Inertial Fusion Energy (IFE) plants producing hydrogen fuel  

International Nuclear Information System (INIS)

A quantitative energy pathway comparison is made between a modern oil refinery and genetic fusion hydrogen plant supporting hybrid-electric cars powered by gasoline and hydrogen-optimized internal combustion engines, respectively, both meeting President Clinton's goal for advanced car goal of 80 mpg gasoline equivalent. The comparison shows that a fusion electric plant producing hydrogen by water electrolysis at 80% efficiency must have an electric capacity of 10 GWe to support as many hydrogen-powered hybrid cars as one modern 200,000 bbl/day-capacity oil refinery could support in gasoline-powered hybrid cars. A 10 GWe fusion electric plant capital cost is limited to 12.5 B$ to produce electricity at 2.3 cents/kWehr, and hydrogen production by electrolysis at 8 $/GJ, for equal consumer fuel cost per passenger mile as in the oil-gasoline-hybrid pathway.

1994-06-20

88

Design of pilot-scale constructed wetlands for tertiary treatment of refinery effluent  

Energy Technology Data Exchange (ETDEWEB)

Two pilot-scale constructed wetlands (4:1 length:width aspect) were designed for tertiary treatment of refinery effluent. As requirements for removal of contaminants from NPDES effluents become more stringent, cost-effective technological approaches are needed to achieve the necessary treatment levels and be efficient, effective and low maintenance. The fundamental design of these constructed wetlands was based on biogeochemical principles that regulate the fate and persistence of the targeted elements (Cu, Zn, Pb). In order to maximize opportunities to learn more about the internal function of the wetlands, they were built to operate in series or in parallel permitting hydraulic retention times of 24 to 48 hours. The wetlands were lined with {approximately}76 cm of compacted clay as well as a 30 mil polyethylene liner. The hydrosoil selected for use in the constructed wetlands is 74.1% sand, 25.6% silt, 0.3% clay. Based on laboratory studies, this hydrosoil ...

1994-12-31

89

Accelerated aging tests with a resid hydrotreating catalyst  

Energy Technology Data Exchange (ETDEWEB)

The deactivation rate of a resid hydrotreating catalyst is determined by a complex set of factors involving both chemical and physical changes in the catalyst structure. The various chemical changes that are associated with resid conversion involve thermal and catalytic steps of relatively large molecular weight species with the overall rates significantly affected by mass transfer limitations. The deposition of coke and the variation in the effective promoter level by the accumulation of metals deposited from the resid are the principal factors governing deactivation. The relative importance of mass transfer restrictions on activity and catalyst deactivation can be observed in studies where the average pore diameter of the catalyst has been varied. Several models have been proposed to characterize the deactivation of resid hydroprocessing catalysts. In this paper, the authors discuss some accelerated aging tests with a relatively large pore commercial hydrotreating catalyst used in ...

1987-04-01

90

Wetland treatment of oil and gas well wastewaters. Quarterly technical report, May 25, 1992---August 24, 1992  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to extend the knowledge base for wetland treatment to include processes and substances of particular importance to small, on-site systems receiving oil and gas well waste water. Collection of data on the sorption of heavy metals and the degradation of toxic organics is one of the key tasks. The toxic organics phenolics and anthracene, and chromium and copper have been selected as target adsorbates. An information search was performed on oil refinery waste treatment wetland systems.

1995-11-01

91

Sophisticated applications of radiation heat transfer  

International Nuclear Information System (INIS)

A large amount of energy has been consumed so far in so called matured industries such as iron and steel, oil refinery, petrochemical, ceramic, paper and pulp manufacturing and so forth. A successive stimulation on the preceding industries has to be enhanced from a technological viewpoint in order to maintain a further development based on novel and innovative technologies. In this regard, energy technology has become and will be increasingly important in a high temperature system so that the basic concept for heat transfer augmentation methods by thermal radiation is reviewed briefly in accord with the recent developments together with theoretical background and the prominent features. The heat transfer augmentation related to thermal radiation is summarized.

1987-01-01

92

Problematic of atmospheric pollution in Lebanon: the better stake is apprehended, the best acts are taken  

International Nuclear Information System (INIS)

The article is an overview on atmospheric pollution in Lebanon. It presents an analysis of sources of pollution in the country and their impacts on local and global environment and describes their control. Air pollution is mainly due to the industrial, electrical and transportation sectors. Pollutants from fuel combustion are analyzed. It is estimated that in 2010, CO_2 emissions will reach 5987250 tons, SO_2 emissions is estimated to be 182950 tons, Nox to 105180 and dusts to 4965 tons. CFC consumption and measures of control according to Montreal protocol are described. Consumption of primary energy, consumption of petroleum products, quantity of petroleum in refineries and production of cement in Lebanon are also presented in tables

2000-02-01

93

Case studies of hazardous-waste treatment to remove volatile organics. Volume 2  

Energy Technology Data Exchange (ETDEWEB)

Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).

1987-11-01

94

Case studies of hazardous-waste treatment to remove volatile organics. Volume 1  

Energy Technology Data Exchange (ETDEWEB)

Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).

1987-11-01

95

Anaerobic fermenter-decanter for the purification of residual water from sugar refineries, with recovery of combustible methane  

Energy Technology Data Exchange (ETDEWEB)

An anaerobic fermenter-decanter for the purification of residual water from the sugar industry, with recovery of methane, consists of a tank with inclined walls, with a central agitator on a vertical shaft. A flexible cover anchored by its periphery to the walls of the tank and totally submerged forms a collecting pocket for the fermentation gases. The water to be purified is introduced, after being heated to about 35, towards the bottom of the tank near the agitator. A metal collecting bell with submerged edges and with the shaft of the agitator passing axially through it is connected by its edges to a central opening of the cover. The purification yields may exceed 90%.

1981-10-06

96

Waste to value  

Energy Technology Data Exchange (ETDEWEB)

The basic technology behind bioethanol production is tried and tested. Alcohol is produced through the fermentation of sugar, which when processed can be used as a biofuel. Now, however, a multitude of new technologies are set to also make cellulose available as a raw material for ethanol production. (orig.)

2010-07-01

97

Valuing climate protection through willingness to pay for biomass ethanol  

Energy Technology Data Exchange (ETDEWEB)

This study uses a multi-part, split-sample contingent valuation method (CVM) and fair share (FS) survey to better understand the public's valuation of mitigating global climate change through its willingness to pay for biomass or 'cellulosic' ethanol. In addition to a basic CVM question, a related scenario was developed that asked half of the survey respondents to state their fair share cost to lessen a potential food shortage in the next decade, also through the expanded use of cellulosic ethanol. Three alternative biomass feedstocks were assessed: farming residues, forestry residues and paper mill wastes, and municipal solid wastes. Overall a slightly larger proportion of respondents were WTP extra for cellulosic ethanol in the basic CVM scenario than in the FS scenario, though no significant differences were found in the WTP for the different feedstocks. Bid curve lognormal regression results ...

2009-05-15

98

The influence of the nature of the metal on the performance of cerium oxide supported catalysts in the partial oxidation of ethanol  

Energy Technology Data Exchange (ETDEWEB)

This work studied the effect of the nature of the metal on the performance of Co/CeO{sub 2}, Pd/CeO{sub 2} and Pt/CeO{sub 2} catalysts in the partial oxidation of ethanol. Infrared spectroscopy of adsorbed ethanol and temperature programmed desorption of ethanol were performed in order to establish the reaction mechanism. Catalytic experiments revealed that the product distribution is strongly affected by the nature of the metal. Acetaldehyde was practically the only product formed on a Co/CeO{sub 2} catalyst while methane was also produced on Pt/CeO{sub 2} and Pd/CeO{sub 2} catalysts. These results were explained through a reaction mechanism proposed by the characterization techniques. Co/CeO{sub 2} and Pt/CeO{sub 2} catalysts show mainly ethoxy species at room temperature whereas acetate species is mainly formed on the Pd/CeO{sub 2} catalyst. The ethoxy species can undergo further dehydrogenation and desorb as ...

2005-12-01

99

Structure and surface and catalytic properties of Mg-Al basic oxides  

Science.gov (United States)

Mg-Al mixed oxides with Mg/Al molar ratios of 0.5--9.0 were obtained by thermal decomposition of precipitated hydrotalcite precursors. The effect of composition on structure and surface and catalytic properties was studied by combining several characterization methods with ethanol conversion reactions. The nature, density, and strength of surface basic sites depended on the Al content. The catalyst activity and selectivity of Mg-Al mixed oxides in ethanol conversion reactions depended on composition. The dehydrogenation of ethanol to acetaldehyde and the aldol condensation to n-butanol both involved the initial surface ethoxide formation on a Lewis acid-strong base pair. The dehydration of ethanol to ethylene, and the coupling and dehydration to diethyl ether increased with Al content, probably reflecting the density increase of both Al{sup 3+}-O{sup 2{minus}} pairs and low- and medium-strength basic ...

1998-09-10

100

Preparation and characterization of iron oxide thin films by spray pyrolysis using methanolic and ethanolic solutions  

International Nuclear Information System (INIS)

Iron oxide thin films have been obtained by spray pyrolysis using 100% methanolic and ethanolic solutions of iron tri-chloride. The films were deposited onto ITO-coated glass substrates. The preparative conditions have been optimized to obtain compact, pin-hole-free and smooth thin films which are adherent to the substrate. The structural, morphological and compositional characterizations have been carried out by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. The films deposited using ethanolic solution results into pure hematite; #alpha#-Fe_2O_3 thin films, however, films deposited using methanolic solution consists of hematite and maghemite-c phases of iron oxide. The films are nanocrystalline with particle size of 30-40 nm. The optical absorbance of the film was of the order of 10"5 cm"-"1. The optical band gap of films was found to be 2.26 and 2.20 eV for the films deposited using methanolic and ...

2006-01-15

101

Preliminary investigation into the pressing process of sweet pearl millet and sweet sorghum biomass for ethanol production  

Energy Technology Data Exchange (ETDEWEB)

Corn is the main source for biofuel production in North America. However, both sweet pearl millet and sweet sorghum crops represent an interesting alternative to corn for ethanol production because of their high biomass yield under a wide range of environmental conditions and high concentration of readily fermentable sugars. Coproducts such as pressing residues can be also be utilized so that nothing is lost in the process. However, in order to improve the extraction of juice for ethanol production, the pressing process of this biomass must be optimized. Preliminary experiments were therefore conducted to optimize the juice extraction from sweet pearl millet and sweet sorghum using 2 different presses, notably a screw press and a manually operated hydraulic press. Both types of biomass were either chopped finely or coarsely and were exposed to various pressures with the hydraulic press. The volume of juice extracted from both crops increased ...

2010-07-01

102

Isolation, Purification, and Characterization of an Endogenous Root-promoting Factor Obtained from Basal Sections of Pear Hardwood Cuttings  

UK PubMed Central (United Kingdom)

Basal segments taken from Old Home and Bartlett pear hardwood cuttings collected at intervals during the rooting period in September were extracted with ethanol and fractionated by paper chromatography...Full Text Available

1967-04-01

103

Increased Ethanol Productivity in Xylose-Utilizing Saccharomyces cerevisiae via a Randomly Mutagenized Xylose Reductase?  

UK PubMed Central (United Kingdom)

Baker's yeast (Saccharomyces cerevisiae) has been genetically engineered to ferment the pentose sugar xylose present in lignocellulose biomass. One of the reactions controlling the...Full Text Available

2010-12-01

104

Hepatoprotective Effects of Orthosiphon stamineus Extract on Thioacetamide-Induced Liver Cirrhosis in Rats  

UK PubMed Central (United Kingdom)

Orthosiphon stamineus as medicinal plant is commonly used in Malaysia for treatment of hepatitis and jaundice; in this study, the ethanol extracts were applied to evaluate the...Full Text Available

2011-01-01

105

Fermentation of Barley by Using Saccharomyces cerevisiae: Examination of Barley as a Feedstock for Bioethanol Production and Value-Added Products ?  

UK PubMed Central (United Kingdom)

The objective of this study was to examine the ethanol yield potential of three barley varieties (Xena, Bold, and Fibar) in comparison to two benchmarks, corn and wheat. Very high gravity (VHG; 30%...Full Text Available

2009-03-01

106

Feasibility study for an ethanol plant in New Orleans, Louisiana. Book one. Executive summary. Volume 1 through 3  

Energy Technology Data Exchange (ETDEWEB)

The findings of a 9-month study of the feasibility of constructing and operating a 35 million gallon per year fermentation ethanol plant in the New Orleans area are presented. The unique features studied are the use of corn screenings, elevator by-products, and damaged grains as feedstock, and the use of municipal solid waste (MSW) as the process fuel. The plant will require investment outlays of $146 million, and the unit production cost for ethanol will be about $1.43 per gallon. The ethanol will be sold in the Louisiana and Texas markets. In Louisiana, gasohol benefits from an 8 cent per gallon state excise tax exemption as well as from the 4 cent per gallon federal excise tax exemption. The by-product, DDGS, will be sold to the overseas market. A large quantity of feedgrains and feedstuffs are exported from the port of New Orleans, and the plant's DDGS will have a price advantage over export feedgrains shipped ...

1982-04-01

107

Development of dual-fuel engine  

Energy Technology Data Exchange (ETDEWEB)

After a lot of efforts to develop a spark-ignition type dual-fuel engine which can separately use both gas and liquid fuels, a dual-fuel engine which uses ethanol as a liquid fuel has been developed. In this paper, a 13A/LPG dual-fuel engine which uses LPG as an emergency fuel is also introduced. During the development of a dual-fuel engine using city gas (13A)/liquid fuel such 4 kinds of liquid fuel as kerosene, gasoline, ethanol and isobutanol have been examined. As a result of testing, it was proved that ethanol is preferable and a 13A/ethanol DF engine can be used as a generator of different outputs, 100KW for normal service and 70KW for emergency service, without any problems in practical use. On the other hand, a city gas (13A)/LPG dual-fuel engine requires the modification of the fuel feed system and the installation of a ignition device which can change the ignition timing by means of the fuel ...

1988-09-10

108

Combining hot-compressed water and ball milling pretreatments to improve the efficiency of the enzymatic hydrolysis of eucalyptus  

UK PubMed Central (United Kingdom)

BackgroundLignocellulosic biomass such as wood is an attractive material for fuel ethanol production. Pretreatment technologies that increase the digestibility of cellulose and hemicellulose...Full Text Available

109

CHRONIC ETHANOL FEEDING AFFECTS PROTEASOME INTERACTING PROTEINS  

UK PubMed Central (United Kingdom)

Studies on alcoholic liver injury mechanisms show a significant inhibition of the proteasome activity. To investigate this phenomenon, we isolated proteasome complexes from the liver of rats...Full Text Available

2009-07-01

110

Alloys and oxides on carbon-supported Pt-Sn electrocatalysts for ethanol oxidation  

Energy Technology Data Exchange (ETDEWEB)

This work reports studies of ethanol oxidation on Pt-Sn/C catalysts with nearly the same particle size and identical overall composition having different amounts of oxide and alloyed phases. Results of characterization of physical properties by transmission electron microscopy (TEM), X-ray diffraction (XRD), differential scanning calorimetry (DSC), X-ray photoelectron spectroscopy (XPS), and in situ dispersive X-ray absorption spectroscopy (DXAS) are presented. The variation in the amount of oxide and alloyed phases, promoted by heat treatments in mild temperature conditions, does not produce any significant particle growth. Cyclic voltammetry and oxidation of adsorbed CO in acid medium are used to probe the surface conditions. Data on the electrocatalytic activity towards ethanol oxidation, obtained by potential sweeps and chronoamperometry, are discussed and correlate well with the physical properties. This study, carried out in the absence ...

2010-06-01

111

Fault detection by Turam TEM survey. Numerical model studies and a case history; TEM ho Turam sokutei haichi ni yoru danso kenshutsu no kokoromi. Model keisan to jisshirei  

Energy Technology Data Exchange (ETDEWEB)

With an objective to detect faults estimated to exist along the Shigesumi valley in the Kamioka mine, discussions were given by using electromagnetic survey, which uses the Turam measurement arrangement based on the TEM method, and three-dimensional model calculations. The Turam measurement arrangement, which installs transmission loop fixedly, is used to identify nature and distribution of electrically conductive objects upon noticing abnormal portions in magnetic fields in the measurement data. In the model calculation, the plate model calculation method and the FDTD method were used, and so was the calculation code TEM3DL. The result revealed that strong topographical influence is seen from steep V-shaped valley existing along the traverse line in the measurement data, but an abnormal resistivity band accompanying remarkable distortion in the curve was detected. According to the result of the model calculation, anomaly detection may be found ...

1997-05-27

112

Decision document for performing a long-term pumping test at the S-3 Site, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

Energy Technology Data Exchange (ETDEWEB)

One of the principal problems confronting the remediation of Bear Creek Valley is the cleanup of contaminated groundwater. The S-3 Site is one of the locations in the valley where groundwater is most contaminated, and contamination from the S-3 Site has also caused extensive contamination of downgradient groundwater. This groundwater plume, therefore, has a high priority in the Bear Creek Valley remedial process. Pumping and treating groundwater was identified early in the feasibility study as a likely remedial alternative for the S-3 Site groundwater plume. The hydrology and geochemistry of the plume are extremely complex. There is a high degree of uncertainty in the current understanding of how the aquifer will react physically and chemically to pumping, making evaluation of a pump-and-treat alternative impractical at the present time. Before a pump-and-treat alternative can be evaluated, its technical practicability, ...

1995-02-01

113

Stability constants of At(I)-complexes with thiourea, iodide and mixed ligands in ethanol and water  

International Nuclear Information System (INIS)

The ion mobilities of |"2"1"1At|At(I) in dependence on thiourea (tu) concentration, iodide concentration and a mixture of both ligands were measured by the electromigration method in free electrolytes. An equilibrium model was developed for the characterization of electromigration curves which permitted the calculation of stability constants and ion mobilities of the complexes |AtI|, |AtI_2|"-, |Attu|"+, |Attu_2|"+ and |AtItu| existing in these solutions. Ethanol and water served as solvents. The temperature was 298 K and the ionic strength was about 0.05 mol/dm"3. (author) 16 refs.; 2 figs.

114

Performance improvement by control of flow rates and diesel injection timing on dual-fuel engine with ethanol  

Energy Technology Data Exchange (ETDEWEB)

To utilize ethanol from agricultural residue as a fuel in diesel engines, a dual-fuel engine was developed. The engine, which was equipped with a system to electrically control diesel and alcohol flow rates, met basic requirements of a tractor engine, including engine speed control and setting of the torque curve. However, engine knock due to alcohol was a significant drawback. A diesel injection pump with a timing and flow rate control system was adapted, and the effect of injection timing on combustion and performance was investigated. It was observed that the timing control was effective in reducing engine knock caused by rapid alcohol combustion. (author)

1996-04-01

115

Wind turbulence estimates in a valley by coherent Doppler lidar  

British Library Electronic Table of Contents (United Kingdom)

Abstract In this paper, the effect of several turbulence parameters during various flow conditions in Owens Valley, educed from coherent Doppler lidar data have been studied. Radial velocity structure functions are processed to estimate the turbulent kinetic energy (TKE) dissipation rate, integral length scale and velocity variance, assuming a theoretical model for isotropic wind fields. Corrections for turbulence measurements have been considered to address the complications due to inherent volumetric averaging of radial velocity over each range gate, noise of the lidar data, and the assumptions required to estimate effects of smaller scales of motion on turbulence quantities. Using data from the Terrain-induced Rotor Experiment (T-REX) in April-May 2006, vertical profiles of wind and tur...

2011-01-01

116

Well log interpretation of certain geothermal fields in the Imperial Valley, California  

Energy Technology Data Exchange (ETDEWEB)

This study reviews the wireline log responses of some geothermal fields in the Imperial Valley, California. The fields under study include the Heber, the East Mesa, the Brawley, and the Westmoreland. The well logs used in the study did not include all the wireline surveys obtained by the operators. The selected well logs obtained under special arrangements with the operators were chosen to maintain the anonymity of specific well locations but are only representative of each area. Analysis of the well logs indicates that on an individual field basis, the well logs are excellent for correlation purposes. The presence of extremely saline fluids in some fields precludes the monitoring of Q/sub v/ (cation exchange capacity per unit volume) profile for detection of hydrothermally altered zones. The producing sections in all the fields are characterized by low porosity and high resistivity.

1984-03-01

117

Thermo-economic analysis of solar powered adsorption heat pump  

British Library Electronic Table of Contents (United Kingdom)

The economic feasibility of the residential solar thermal (ST) cooling system designed in the companion article [1] is ascertained by comparing it with a solar electric (SE) cooling system, and also with the baseline (i.e., control case), a grid dependent, highest efficiency COPC=5.66 heat pump. The economic scenario is analyzed for 24 cities across the southern USA, south of the 37degreeN. The SE cooling system provides lifecycle (20 year) savings to the homeowner only where electric rates are high and it is heavily subsidized. The overall societal effect (sum of taxpayer funded rebate and homeowner savings) is actually an increased cost everywhere except the California Central Valley, where the net savings is $1500. In the same valley, The ST cooling system provides greater lifecycle sav...

2007-01-01

118

List of Local Government Area (LGA) names - NPI  

Wastenet

...Albury NSW Armidale Dumaresq NSW Ashfield NSW Auburn NSW Ballina NSW Balranald NSW Bankstown NSW Bathurst Regional NSW Baulkham Hills NSW Bega Valley NSW Bellingen NSW Berrigan NSW Blacktown NSW Bland NSW Blayney NSW Blue Mountains NSW Bogan NSW Bombala NSW Boorowa NSW Botany Bay NSW Bourke NSW Brewarrina NSW Broken Hill NSW Burwood NSW Byron NSW Cabonne NSW Camden NSW Campbelltown NSW Canada Bay NSW Canterbury NSW Carrathool NSW Central Darling NSW Cessnock NSW Clarence Valley NSW Cobar NSW Coffs Harbour NSW Conargo NSW Coolamon NSW Cooma-Monaro NSW Coonamble NSW Cootamundra NSW Corowa NSW Cowra ...

119

LDL (Landscape Digital Library) a Digital Photographic Database of a Case Study Area in the River Po Valley, Northern Italy  

CERN Document Server

Landscapes are both a synthesis and an expression of national, regional and local cultural heritages. It is therefore very important to develop techniques aimed at cataloguing and archiving their forms. This paper discusses the LDL (Landscape Digital Library) project, a Web accessible database that can present the landscapes of a territory with documentary evidence in a new format and from a new perspective. The method was tested in a case study area of the river Po valley (Northern Italy). The LDL is based on a collection of photographs taken following a systematic grid of survey points identified through topographic cartography; the camera level is that of the human eye. This methodology leads to an innovative landscape archive that differs from surveys carried out through aerial photographs or campaigns aimed at selecting "relevant" points of interest. Further developments and possible uses of the LDL are also discussed.

2001-01-01

120

Geothermal Energy R&D Program Annual Progress Report for Fiscal Year 1992  

Energy Technology Data Exchange (ETDEWEB)

Geothermal budget actual amounts are shown for FY 1989 -1992, broken down by about 15 categories. Here, the main Program categories are: Exploration Technology, Drilling Technology, Reservoir Technology, Conversion Technology (power plants and materials), Industry-Coupled Drilling, Drilling Applications, Reservoir Engineering Applications, Direct Heat, Geopressured Wells Operation, and Hot Dry Rock Research. Here the title--Industry-Coupled Drilling--covered case studies of the Coso, CA, and Dixie Valley, NV, fields, and the Long Valley Exploratory Well (which had started as a magma energy exploration project, but reported here as a hydrothermal prospect evaluation well). (DJE 2005)

1993-07-01

121

Correlation and interpretation of three-component survey seismic anomalies, Zamora gas field, northern Sacramento Valley, California  

Energy Technology Data Exchange (ETDEWEB)

A three-component seismic line acquired over the Zamora gas field, northern Sacramento Valley, California, displays conventional (P-P) and converted-wave (P-SV) seismic anomalies. Well log and seismic modeling results indicate that bright-spot reflection strengths are related to variations in fluid saturation and lithology. The P-SV reflection strengths and interval velocities provide valuable information that complements more conventional strategies such as amplitude with offset and polarity analysis. This integrated strategy can improve risk evaluation and well-site selection in areas where rapid changes in reservoir quality impact resource evaluation.

1989-03-01

122

Correlation and interpretation of three-component survey seismic anomalies, Zamora Gas field, northern Sacramento Valley, California  

Energy Technology Data Exchange (ETDEWEB)

A three-component seismic line acquired over the Zamora gas field, northern Sacramento Valley, California, displays conventional (P-P) and converted-wave (P-SV) seismic anomalies. Well log and seismic modeling results indicate that bright-spot reflection strengths are related to variations in fluid saturation and lithology. The converted-wave reflection strengths and interval velocities provide valuable information that compliments more conventional strategies such as amplitude with offset and polarity analysis. This integrated strategy can improve risk evaluation and well site selection in areas where rapid changes in reservoir quality impact resource evaluation.

1989-04-01

123

Concentration of Melton Valley Storage Tank surrogates with a wiped film evaporator  

Energy Technology Data Exchange (ETDEWEB)

This report describes experiments to determine whether a wiped film evaporator (WFE) might be used to concentrate low-level liquid radioactive waste (LLLW). Solutions used in these studies were surrogates that contain no radionuclides. The compositions of the surrogates were based on one of Oak Ridge National Laboratory`s (ORNL`s) Melton Valley Storage Tanks (MVSTs). It was found that a WFE could be used to concentrate LLLW to varying degrees by manipulating various parameters. The parameters studied were rotor speed, process fluid feed temperature and feed rate, and evaporator temperature. Product consistency varied from an unsaturated liquid to a dry powder. Volume reductions up to 68% were achieved. System decontamination factors were consistently in the range of 10{sup 4}.

1994-08-01

124

Australia's Latrobe Valley brown coal fields  

Energy Technology Data Exchange (ETDEWEB)

Brown coal resources of the Latrobe Valley in Australia total 140 billion tons to a depth of 975 feet, while economically recoverable reserves have been calculated to total 57 billion tons. Although the coal provides only a very low heating value, about 3300 Btu/lb with 60% moisture content, the enormous seam thicknesses with little overburden allow large scale, open cut mining operations. The low cost and high reactivity of the coal is attracting extensive coal liquefaction research. Research into dewatering processes for the high moisture content brown coal is being conducted. The dried brown coal could be used both domestically and internationally for electricity generation and as an industrial fuel.

1984-02-01

125

Studies of the dissolution of geothermal scale  

Science.gov (United States)

Samples of geothermal scale formed from Magmamax No. 1 and Woolsey No. 1 wells in the Imperial Valley, Calif., were exposed to concentrated and dilute solutions of common laboratory reagents. The time of exposure and temperature of the reagent were also varied. Several reagents easily dissolved significant amounts of the scale. An in situ test was performed with marginal success.

1980-02-04

126

Snake River Sockeye Salmon Habitat and Limnological Research; 1995 Annual Report.  

Energy Technology Data Exchange (ETDEWEB)

This report contains studies which are part of the Bonneville Power Administration`s program to protect, mitigate, and enhance fish and wildlife affected by the development and operation of hydroelectric facilities on the Columbia River and its tributaries. Attention is focused on population monitoring studies in the Sawtooth Valley Lakes. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

1996-05-01

127

Role of paleogeomorphological research in analyzing the influence of deep-lying faults on the sediment accumulation conditions in the latter Cretaceous stage in the Western Capital Caspian Sea Valley  

Energy Technology Data Exchange (ETDEWEB)

The spatial connection between the zones of deep-lying faults and the narrowly-localized paleo-relief sections posessing an anomolous sedimentation condition in the latter Cretaceous is identified. It is established that this is of significance in choosing the primary regions for conducting oil exploration.

1980-01-01

128

NAME=\\  

Wastenet

... The moorland landscape looks especially colourful in late summer, while spring is the perfect time to come and see migrant birds like redstarts,...Valley This is a delightful oak woodland to walk through - especially in spring and early summer when lots of migrating birds come to breed ... Fowlmere Fowlmere's reedbeds and pools are fed by natural chalk springs, and a chalk stream runs through the reserve. Special birds ... There are common woodland birds in spring and turtle doves in spring and summer. Haweswater If you want to see a golden ...

129

NAME=\\  

Wastenet

... In spring, the marshes are filled with the atmospheric calls of lapwings and redshanks, all breeding on one of the UK's ...Butley river and Ore estuary, Boyton Marshes attracts breeding wading birds in spring and ducks, geese and swans in winter. It's also ... The moorland landscape looks especially colourful in late summer, while spring is the perfect time to come and see migrant birds like redstarts,...Valley This is a delightful oak woodland to walk through - especially in spring and early summer when lots of migrating birds come to breed ...

130

Mass-energy spectra of fission fragments in the reaction {sup 242m}Am(n{sub th},f)  

Energy Technology Data Exchange (ETDEWEB)

The mass-energy spectra of the fragments of thermal fission of {sup 242m}Am are measured using the time-of-flight technique. The resulting mass-yield curve and peak-to-valley ratio agree with radiochemical data. The parameters of the kinetic energy distribution of the fragments are determined for the first time. Data on the fine structure of mass spectra in the region of cold fragmentation are presented. 15 refs., 4 figs.

1994-12-01

131

HORIZON SENSING (PROPOSAL NO.51)  

Energy Technology Data Exchange (ETDEWEB)

Real-time horizon sensing on continuous mining machines is becoming an industry tool. Installation and testing of production-grade Horizon Sensor (HS) systems continued this quarter at Monterey Coal Company (ExxonMobil), Mountain Coal Company West Elk Mine (Arch), and Ohio Valley Coal Company (OVC). Monitoring of system function, user experience, and mining benefits is ongoing. All horizon sensor components have finished MSHA (U.S.) and IEC (International) certification.

2003-07-01

132

Development of the Decontamination Approach for the West Valley Demonstration Project Decontamination Project Plan  

Energy Technology Data Exchange (ETDEWEB)

This paper details the development of a decontamination approach for the West Valley Demonstration Project (WVDP), Decontamination Project Plan (Plan). The WVDP is operated by West Valley Nuclear Services Company (WVNSCO), a subsidiary of Westinghouse Government and Environmental Services, and its parent companies Washington Group International and British Nuclear Fuels Limited (BNFL). The WVDP is a waste management effort being conducted by the United States Department of Energy (DOE) at the site of the only commercial nuclear fuel reprocessing facility to have operated in the United States. This facility is part of the Western New York Nuclear Service Center (WNYNSC), which is owned by the New York State Energy Research and Development Authority (NYSERDA). As authorized by Congress in 1980 through the West Valley Demonstration Project Act (WVDP Act, Public Law 96-368), the DOE's primary mission at the WVDP is to ...

2002-02-25

133

Chemical evolution of formation waters in the Palm Valley gas field, Northern Territory  

International Nuclear Information System (INIS)

The chemical composition and evolution of formation waters associated with gas production in the Palm Valley field, Northern Territory, has important implications for reservoir management, saline water disposal, and gas reserve calculations. Historically, the occurrence of saline formation water in gas fields has been the subject of considerable debate. A better understanding of the origin, chemical evolution and movement of the formation water at Palm Valley has important implications for future reservoir management, disposal of highly saline water and accurate gas reserves estimation. Major and trace element abundance data suggest that a significant component of the highly saline water from Palm Valley has characteristics that may have been derived from a modified evaporated seawater source such as an evaporite horizon. The most dilute waters probably represent condensate and the variation in the chemistry of the ...

134

Inorganic profile of some Brazilian medicinal plants obtained from ethanolic extract and ''in natura'' samples  

Energy Technology Data Exchange (ETDEWEB)

The Anadenathera macrocarpa, Schinus molle, Hymenaea courbaril, Cariniana legalis, Solidago microglossa and Stryphnodendron barbatiman, were collected ''in natura'' samples (leaves, flowers, barks and seeds) from different commercial suppliers. The pharmaco-active compounds in ethanolic extracts had been made by the Mato Grosso Federal University (UFMT). The energy-dispersive x-ray fluorescence (ED-XRF) spectrometry was used for the elemental analysis in different parts of the plants and respective ethanolic extracts. The Ca, Cl, Cu, Fe, K, Mg, Mn, Na, Ni, P, Rb, S, Sr and Zn concentrations were determined by the fundamental parameters method. Some specimens showed a similar inorganic profile for ''in natura'' and ethanolic extract samples and some ones showed a distinct inorganic profile. For example, the Anadenathera macrocarpa showed a similar ...

2004-10-03

135

A study of the reactions of ethanol on CeO{sub 2} and Pd/CeO{sub 2} by steady state reactions, temperature programmed desorption, and in situ FT-IR  

Energy Technology Data Exchange (ETDEWEB)

The reaction of ethanol on unreduced and H{sub 2}-reduced CeO{sub 2} and 1 wt% Pd/CeO{sub 2} has been investigated by steady state reactions, temperature programmed desorption (TPD), and in situ Fourier transform infrared (FT-IR) spectroscopy. Steady state reactions have shown a zero reaction order dependency for diatomic oxygen at and above 20%, while the addition of Pd to CeO{sub 2} decreases the apparent activation energy of the reaction from 75 kJ/mol on CeO{sub 2} alone to 40 kJ/mol (Pd/CeO{sub 2}). TPD experiments following ethanol adsorption on both CeO{sub 2} and Pd/CeO{sub 2} have shown desorption profiles corresponding to unreacted ethanol and various reaction and decomposition products (acetaldehyde, acetone, CO, CO{sub 2}, and methane). Ethanol conversion to reaction products was increased by the addition of Pd, from 15 to 30% on CeO{sub 2} and H{sub 2}-reduced CeO{sub 2}, to 71 and 63% on ...

1999-09-10

136

The effect of the alcoholic solvent type on the formation of silica fine particles from alkoxide  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we investigated the effect of alcohol solvents (ethanol, n-propanol, and n-butanol) and isomeric alcohol solvents (iso-propanol, iso--butanol, and tert-butanol). In addition, we observed the effect of the mixed alcohol solvents on the particle formation as using a mixture od ethanol and butanol at a ratio od 30/70, 50/50 and 70/30 vol %, respectively. In case of ethanol solvent, particle size of silica showed the smallest and the narrowest size distribution among the various solvent. On the contrary, for the n-butanol solvent, largest broad distribution of particle size was observed. For the synthesis of particles having better spherical morphology and less agglomeration, alcohol solvent having no branches was considered appropriate. When mixed alcohol solvents were used, large silica particles with narrow size distribution were obtained, regardless of the ratio. 8 refs., 5 figs., 1 tab.

2000-04-01

137

New crystallization of fatty acids from aqueous ethanol solution combined with liquid-liquid extraction  

Energy Technology Data Exchange (ETDEWEB)

A new separation process of saturated fatty acids (lauric acid-myristic acid) using crystallization from an aqueous ethanol solution has been examined. There were two vessels in this separation process: an extraction vessel and a crystallization vessel. The fatty acids in the aqueous phase were first extracted from their organic phase (melt) in the extraction vessel. The fatty acids in the aqueous phase were continuously introduced to the crystallization vessel, and then the fatty acids were crystallized there. The crystals of the fatty acids were collected continuously above the aqueous phase in the crystallization vessel. In this process, the yield and the purity of the crystals over time were measured, and it was found that the purity of lauric acid increased unsteadily up to 0.98 mole fraction of lauric acid with an increase in the yield of the low yield range. The mole fraction of ethanol in the aqueous phase could be significant to ...

1999-06-01

138

Fuzzy-decision-making problems of fuel ethanol production using a genetically engineered yeast  

Energy Technology Data Exchange (ETDEWEB)

A fuzzy-decision-making procedure is applied to find the optimal feed policy of a fed-batch fermentation process for fuel ethanol production using a genetically engineered Saccharomyces yeast 1400 (pLNH33). The policy consisted of feed flow rate, feed concentration, and fermentation time. The recombinant yeast 1400 (pLNH33) can utilize glucose and xylose simultaneously to produce ethanol. However, the parent yeast utilizes glucose only. A partially selective model is used to describe the kinetic behavior of the process. In this study, this partially selective fermentation process is formulated as a general multiple-objective optimal control problem. By using an assigned membership function for each of the objectives, the general multiple-objective optimization problem can be converted into a maximizing decision problem. In order to obtain a global solution, a hybrid method of differential evolution is introduced to solve the maximizing decision ...

1998-08-01

139

Emission characterization of an alcohol/diesel-pilot fueled compression-ignition engine and its heavy-duty diesel counterpart. Final report, August 1980-August 1981  

Energy Technology Data Exchange (ETDEWEB)

This report describes results from emissions testing of a prototype diesel engine, developed by Volvo Truck Corporation of Sweden, which uses pilot injection of diesel fuel for compression ignition of alcohol fuel injection for main combustion. In addition to this dual-fuel engine, emission testing was also conducted on a heavy-duty diesel engine of similar design. Both engines were tested over the 1979 13-mode FTP, or shorter versions of this modal test, and over the 1984 Transient FTP as well as an experimental bus cycle. The dual-fuel engine was characterized with methanol, ethanol and ethanol with 30 percent water (wt %). An oxidation catalyst was also used with methanol and ethanol. Emission characterization included regulated emissions (HC, CO, and NOX) along with total particulate, unburned alcohols, individual hydrocarbons, aldehydes, phenols, and odor. The particulate matter was characterized in terms of particle ...

1981-08-01

140

Effects of biomass-generated producer gas constituents on cell growth, product distribution and hydrogenase activity of Clostridium carboxidivorans P7{sup T}  

Energy Technology Data Exchange (ETDEWEB)

In our previous work, we demonstrated that biomass-generated producer gas can be converted to ethanol and acetic acid using a microbial catalyst Clostridium carboxidivorans P7{sup T}. Results showed that the producer gas (1) induced cell dormancy, (2) inhibited H{sub 2} consumption, and (3) affected the acetic acid/ethanol product distribution. Results of this work showed that tars were the likely cause of cell dormancy and product redistribution and that the addition of a 0.025{mu}m filter in the gas cleanup negated the effects of tars. C. carboxidivorans P7{sup T} can adapt to the tars (i.e. grow) only after prolonged exposure. Nitric oxide, present in the producer gas at 150ppm, is an inhibitor of the hydrogenase enzyme involved in H{sub 2} consumption. We conclude that significant conditioning of the producer gas will be required for the successful coupling of biomass-generated producer gas with fermentation to produce ...

2006-07-15

141

ATF4 and the integrated stress response are induced by ethanol and cytochrome P450 2E1 in human hepatocytes  

British Library Electronic Table of Contents (United Kingdom)

Background & AimsMolecular mechanisms underlying alcoholic liver disease (ALD) are still not fully understood. Activating transcription factor-4 (ATF4) is the master coordinator of the integrated stress response (ISR), an adaptive pathway triggered by multiple stressors. which can promote cell death and induce metabolic dysregulation if the stress is intense or prolonged. The aim of this study was to assess the effect of alcohol on the ISR signaling pathway in human liver cells and to define the role of cytochrome P450 2E1 (CYP2E1) in this response. MethodsPrimary cultured human hepatocytes and human HepG2 cells over-expressing CYP2E1 by adenoviral infection were exposed to ethanol (25-100mM) for 8-48h. ResultsEthanol treatment of both liver cells up-regulated ATF4 as well as the pro-survi...

2011-01-01

142

Petroleum storage tank cleaning using commercial microbial culture products  

Energy Technology Data Exchange (ETDEWEB)

The removal of paraffinic bottom accumulations from refinery storage tanks represents an increasingly costly area of petroleum storage management. Microorganisms can be used to reduce paraffinic bottoms by increasing the solubility of bottom material and by increasing the wax-carrying capacity of carrier oil used in the cleaning process. The economic savings of such treatments are considerable. The process is also intrinsically safer than alternative methods, as it reduces and even eliminates the need for personnel to enter the tank during the cleaning process. Both laboratory and field sample analyses can be used to document changes in tank material during the treatment process. These changes include increases in volatile content and changes in wax distribution. Several case histories illustrating these physical and chemical changes are presented along with the economics of treatment.

1995-12-31

143

Logistics management of Paraho residual shale oil. Final report  

Energy Technology Data Exchange (ETDEWEB)

In January of 1977 the Paraho Development Company under contract with the United States Navy began a semi-works project to produce and refine up to 100,000 barrels of crude shale oil. Although the primary objective of the project was to produce specification turbine and diesel transportation fuels for field testing by the military field testing, the full-scale refinery run also produced a substantial quantity of hydrotreated shale oil residue. In 1978 the Electric Power Research Institute, recognizing the utilization potential of this material as a fuel for utility combustion turbines, obtained 4300 barrels of the residual shale oil product for future field testing. This report describes the processes involved in producing, handling, and storing the residual shale oil test material. The report also includes detailed chemical and physical analyses of the test material. In addition, guidelines which can be applied to future work with this type of synthetic fuel are ...

1980-03-01

144

Industry-identified combustion research needs: Special study  

Energy Technology Data Exchange (ETDEWEB)

This report discusses the development and demonstration of innovative combustion technologies that improve energy conservation and environmental practices in the US industrial sector. The report includes recommendations by industry on R&D needed to resolve current combustion-related problems. Both fundamental and applied R&D needs are presented. The report assesses combustion needs and suggests research ideas for seven major industries, which consume about 78% of all energy used by industry. Included are the glass, pulp and paper, refinery, steel, metal casting, chemicals, and aluminum industries. Information has been collected from manufacturers, industrial operators, trade organizations, and various funding organizations and has been supplemented with expertise at the Idaho National Engineering Laboratory to develop a list of suggested research and development needed for each of the seven industries.

1995-11-01

145

Development and application of gamma scanning technology for on-line investigation of industrial process columns and vessels  

International Nuclear Information System (INIS)

Plant Assessment Technology (PAT) group, in association with Intelligent System (IS) Group and Engineering Services Department of Malaysian Institute for Nuclear Technology Research (MINT) has developed gamma scanning facilities for on-line investigation of industrial process columns and vessels. The technology, based on the principle of gamma-ray absorption, has been successfully applied for troubleshooting of a number of distillation columns and process vessels in petroleum refineries, gas processing plants and chemical plants in the country and the region. This paper outlines basic characteristics of the system and describes the inspection procedures, and in addition, case studies are also presented. The case studies are purposely chosen to illustrate the versatility of the technology, and furthermore to demonstrate the economic benefits which can be realised from the application of this technology. (author)

1998-10-30

146

A novel gamma scanning system for on-line diagnostic inspection of industrial process columns  

International Nuclear Information System (INIS)

A computerised gamma scanning facilities for on-line investigation of industrial process columns and vessels has been developed by the Malaysian Nuclear Agency (Nuclear Malaysia). The technology, based on the principle of gamma-ray absorption, has been successfully applied for real-time troubleshooting, process investigation and predictive maintenance of a number of distillation columns and process vessels in petroleum refineries, gas processing plants and chemical plants in the country and the surrounding region. This paper outlines basic characteristics of the system and describes the inspection procedures, and in addition, presents a number of case studies. The case studies are purposely chosen to illustrate the versatility of the technology, and furthermore to demonstrate the economic benefits which can be realised from the application of this technology. (Author)

147

Woody biomass availability for bioethanol conversion in Mississippi  

British Library Electronic Table of Contents (United Kingdom)

This study evaluated woody biomass from logging residues, small-diameter trees, mill residues, and urban waste as a feedstock for cellulosic ethanol conversion in Mississippi. The focus on Mississippi was to assess in-state regional variations and provide specific information of biomass estimates for those facilities interested in locating in Mississippi. Supply and cost of four woody biomass sources were derived from Forest Inventory Analysis (FIA) information, a recent forest inventory conducted by the Mississippi Institute for Forest Inventory, and primary production costs. According to our analysis, about 4.0 million dry tons of woody biomass are available for production of up to 1.2 billion liters of ethanol each year in Mississippi. The feedstock consists of 69% logging residues, 21%...

2009-01-01

148

Intermediates of radiolytic transformations of 6-aminophenalenone in ethanol  

International Nuclear Information System (INIS)

Pulsed radiolysis method is used to study transformations intermediates of 6-aminophenalenone in ethanol. In alkaline medium the main product is radical-anion of 6-aminophenalenone, which optical absorption spectrum contains two bands with maxima at 355 and 400 nm. The particle precursors are e_s, CH_3CHOH and CH_3CHO"- radicals. In neutral and acid medium radical-anions are protonated in reactions with alcohol and hydrogen ions. The resulting H-adduct of 6-aminophenalenone has optical absorption maxima at 350 and 390 nm. Availability of two maxima is related to two various product structures. Molar extinction coefficients of radical-anions and H-adducts of 6-aminophenalenone and rate constants of reactions with their participation are estimated.

1992-01-01

149

Intermediate products of radiolytic conversions of 6-aminophenalenone in ethanol  

International Nuclear Information System (INIS)

Intermediate products of the conversions of 6-aminophenalenone in ethanol were investigated by pulse radiolysis. In alkaline medium the main product is the 6-aminophenalenone radical cation, the optical absorption spectrum of which contains two bands with maxima at 355 and 400 nm. The precursors of this particle are e_s, CH_3CHOH and CH_3CHO"- radicals. In neutral and acid medium, radical cations are protonated in reactions with alcohol and hydrogen ions. The H-adduct of 6-aminophenalenone that arises has optical absorption maxima at 350 and 390 nm. The presence of two maxima is due to two different structures of the product. The molar extinction coefficients of the radical anions and H-adducts of 6-aminophenalenone and the rate constants of the reactions involving them were estimated. 6 refs., 4 figs., 2 tabs.

1992-01-01

150

Heat and mass transfer analogy studies of binary liquid mixture in comparison with ethanol-n-heptane evaporating to air  

Energy Technology Data Exchange (ETDEWEB)

An experimental and theoretical study of heat and mass transfer analogy and a comparison of that to a binary liquid mixture evaporation is presented. Common organic solvents, ethanol and n-heptane, were used to form an alcohol - hydrocarbon mixture. Studies were carried out in a horizontal rectangular channel having air flow velocities of 0.2 - 0.9 m/s. Heat transfer coefficients were measured with a copper plate resistor and mass transfer coefficients with a square pool. The heat and mass transfer analogy is presented for a system having two evaporating compounds with a fixed value of air flow and verified by measuring and comparing mass transfer coefficients for distilled water with air flow velocities of 0.2 - 0.9 m/s. An illustrative example of the use of the theory for industrial ventilation is presented. (author)

1995-12-31

151

Feasibility study for Hilo Coast Processing Company, Pepeekeo, Hawaii: 11. 4-million gallon-per-year motor-fuel-grade ethanol plant. Volume X. Economic analysis  

Energy Technology Data Exchange (ETDEWEB)

An economic evaluation is presented for the proposed plant for producing 11,414,000 gallons per year of fuel-grade alcohol from 150,000 tons of molasses. The project is economically attractive at a 1981 ethanol sales price of $2.00 per gallon, a 1981 molasses price of $85.00 per ton, and a plant capital investment of $27.45 MM. The evaluation description includes: investment, operating costs, revenues, and economic analysis. Included in appendices are detailed computer printouts for the following scenarios: the constant dollar, the uniform escalation, and the current dollar.

1981-05-01

152

Extrusion as a thermo-mechanical pre-treatment for lignocellulosic ethanol  

British Library Electronic Table of Contents (United Kingdom)

Two physical pre-treatment methods, particle size reduction by grinding and thermo-mechanical extrusion, were evaluated as alternatives to traditional biomass pretreatments for lignocellulosic ethanol. Commonly available agricultural co-products wheat bran and soybean hull were the model substrates. Extrusion led to higher reducing sugar yields as compared to grinding for wheat bran, but not in the case of soybean hulls. The best combination of extrusion screw speed and maximum barrel temperature were 7 Hz/150 ?C and 3.7 Hz/110 ?C. The use of a solvent mixture (sodium hydroxide, urea, and thiourea) and calcium chloride solution in combination with extrusion treatment did not lead to improvement in reducing sugar yield. However, extensive washing to get rid of solvents and enzymatic inhibit...

2010-01-01

153

Experimental optimization of a real time fed-batch fermentation process using Markov decision process.  

Science.gov (United States)

This article describes a methodology that implements a Markov decision process (MDP) optimization technique in a real time fed-batch experiment. Biological systems can be better modeled under the stochastic framework and MDP is shown to be a suitable technique for their optimization. A nonlinear input/output model is used to calculate the probability transitions. All elements of the MDP are identified according to physical parameters. Finally, this study compares the results obtained when optimizing ethanol production using the infinite horizon problem, with total expected discount policy, to previous experimental results aimed at optimizing ethanol production using a recombinant Escherichia coli fed-batch cultivation. (c) 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 55: 317-327, 1997. PMID:18636490

1997-07-20

154

Evaluation of antiasthmatic activity of Clitoria ternatea L. roots  

British Library Electronic Table of Contents (United Kingdom)

Aim of study: Clitoria ternatea L. (Family: Fabaceae) is being used in traditional medicine for the treatment of severe bronchitis and asthma. So the aim of study was to evaluate antiasthmatic activity of ethanol extract of Clitoria ternatea roots. Materials and methods: In the present study ethanol extract of Clitoria ternatea root (ECTR) was evaluated for preliminary phytochemical screening, acute toxicity studies and antiasthmatic activity using milk induced leucocytosis and eosinophilia in mice, egg albumin induced mast cell degranulations in rats and passive cutaneous anaphylaxis in rats at doses (100-150mg/kg ip). Results: The results of present investigation showed that the LD50 of ECTR is more than 1300mg/kg. ECTR significantly decreases milk induced leucocytosis and eosinophilia, ...

2011-01-01

155

Electrophoretic deposition of ethanol steam-reforming catalysts on metal plates for the development of catalytic-wall reactors  

British Library Electronic Table of Contents (United Kingdom)

A procedure based on electrophoretic deposition (EPD) was developed to coat metal plates with powder catalysts. The method was tested on stainless-steel plates with three Ni-based catalysts for the steam reforming of ethanol. The catalysts (Ni/La2O3/g-Al2O3) contained 15% Ni and 8% La, and were prepared using three types of g-alumina with different textural properties. The powder catalysts were suspended in isopropanol, and EPD deposition was performed with a voltage of 100V and a distance between electrodes of 2cm. Deposition time was varied between 3 and 7min, which gave a thickness of the catalyst layer from around 30 to 100mm. The morphology of the catalyst layer was dependent on the textural characteristics of the g-Al2O3 used to prepare the catalyst. The activity of the catalyst plat...

2010-01-01

156

Antioxidant properties of chlorophyll-enriched and chlorophyll-depleted polyphenolic fractions from leaves of Vernonia amygdalina and Gongronema latifolium  

British Library Electronic Table of Contents (United Kingdom)

This study investigated the optimum polyphenol extraction conditions for two Nigerian green leafy vegetables, Vernonia amygdalina (VA) and Gongronema latifolium (GL) that are widely used for food and medicinal purposes. Seven different solvents were used to extract the total phenolic contents of the leaves; 100% acetone, 80% acetone, 50% acetone, 100% ethanol, 70% ethanol, 100% methanol and 70% methanol and their total phenolic contents were determined. The results showed that the 80% acetone was significantly (p<0.05) the most effective for polyphenol extraction from the leaves and generally the acetone-containing solvents were more effective than alcohol-containing solvents. The 80% acetone extract was fractionated on a silicic acid-packed column to give two main fractions: acetone elute...

2011-01-01

157

Antioxidant activity in banana peel extracts: Testing extraction conditions and related bioactive compounds  

British Library Electronic Table of Contents (United Kingdom)

Banana (Musa acuminata Colla AAA) peel extracts obtained in this work had a high capacity to scavenge 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2prime-azino-bis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS+) free radicals, and they were also good lipid peroxidation inhibitors. Acetone:water extracts were considerably more effective (compared with methanol, ethanol, acetone, water, methanol:water or ethanol:water) at inhibiting the peroxidation of lipids in the b-carotene/linoleic acid system or scavenging free radicals. However, aqueous extracts had a high capacity to protect lipids from oxidation in the thiobarbituric acid reactive substances (TBARS) test, as well as in the b-carotene bleaching assay. In addition, acetone:water most efficiently extracted all extractable components (54+-...

2010-01-01

158

A new zinc hydroxide nitrate heterogeneous catalyst for the esterification of free fatty acids and the transesterification of vegetable oils  

British Library Electronic Table of Contents (United Kingdom)

A new heterogeneous catalyst for the esterification of free fatty acids and the transesterification of vegetable oils is reported. The layered compound zinc hydroxide nitrate (Zn5(OH)8(NO3)22H2O) was very effective in the alcoholysis of palm oil and the esterification of lauric acid with m(ethanol), even when hydrated ethanol was used. Over the range of 100-140degreeC, the ester yield was the highest at 140degreeC, while the catalyst concentration had a much greater effect on ester yields than the molar ratio of alcohol to acid did. Total ester contents above 95wt% were obtained in both reactions and 93.2wt% glycerin streams were recovered as a result of methanolysis.

2008-01-01

159

Life Cycle Assessment of Potential Bio-jet Fuel Production in the United States.  

Science.gov (United States)

The objective of this paper is to reveal to what degree bio-based jet fuels (bio-jet) can reduce greenhouse gas (GHG) emissions from the US aviation sector. A model of the supply and demand chain of bio-jet involving farmers, bio-refineries, airlines, and policymakers is developed by considering factors that drive the decisions of actors (i.e. decision-makers and stakeholders) in the life cycle stages. Two kinds of feedstock are considered: oil-producing feedstock (i.e. camelina and algae) and lignocellulosic biomass (i.e. corn stover, switchgrass, and short rotation woody crops). By factoring in farmer/ feedstock producer and bio-refinery profitability requirements, land availability and suitability, as well as a time delay factor, a more realistic estimate of the level of bio-jet supply and emissions reduction can be developed under different oil price assumptions. Factors that drive bio-jet GHG emissions and unit production costs from each ...

2011-09-29

160

Improving cost-effectiveness for the furnace in a full-scale refinery plant with reuse of waste tail gas fuel  

Energy Technology Data Exchange (ETDEWEB)

The waste tail gas fuel emitted from refinery plant in Taiwan e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement fuel. In this study, it was slowly added to the fuel stream of a heater furnace to replace natural gas for powering a full-scale distillation process. The waste tail gas fuel contained on average 60 mol% of hydrogen. On-site experimental results show that both the flame length and orange-yellowish brightness decrease with increasing proportion of waste gas fuel in the original natural gas fuel. Moreover, the adiabatic flame temperature increases as the content of waste gas fuel is increased in the fuel mixture since waste gas fuel has a higher adiabatic flame temperature than that of natural gas. The complete replacement of natural gas by waste gas fuel for a heater furnace operating at 70% loading (i.e. 3.6 x 10{sup 7} kcal/h of combustion capacity) will save 5.8 x 10{sup 6} ...

2010-02-15

161

Environmental radioactivity on Suape (PE) estuary: impact of the installation of an oil refinery  

Energy Technology Data Exchange (ETDEWEB)

Nowadays there is a growing interest in the study of natural radioactivity levels, mainly of radionuclides; {sup 238}U, {sup 226}Ra, {sup 232}Th, {sup 40}K, and {sup 210}Pb present in the environment. The environmental radioactivity control is very important to obtain information on exposure of humans and vegetables to potential sources on natural radioactive occurrences. Industrial processes involving mining and extraction and production of oil foster concentration of radionuclides, contributing to the occurrence of what is known as 'TENORM' - Technologically Enhanced Naturally Occurring Radioactive Material. This work aims to assess the environmental radiological impact on the estuarine area of the Industrial Park of SUAPE, due the installation of an oil refinery and the consequent introduction on the environment of natural radioactive materials from other regions in that area. The radioisotopes {sup 238}U, {sup 226}Ra, {sup 232}Th , {sup 40}K ...

2009-07-01

162

Comparison of acute toxicity of process chemicals used in the oil refinery industry, tested with the diatom Chaetoceros gracilis, the flagellate Isochrysis galbana, and the zebra fish, Brachydanio rerio  

International Nuclear Information System (INIS)

Chemicals under the trade names Nalco 537-DA, Nalco 625, Nalco 7607, Nalco 5165, Ivamin, and technical monoethanolamine are used extensively in the oil refinery industry. Aquatic toxicity tests were conducted using zebra fish fry (Brachydanio rerio) and the unicellular algae Isochrysis galbana (a flagellate) and Chaetoceros gracilis (a diatom). Inhibition of cell division, chlorophyll content, and "1"4CO_2 uptake in the algae were sensitive end points. The effective concentrations (EC50s) of growth inhibition were 0.1 mg/L (Ivamin; I. galbana), 0.8 mg/L (Nalco 7607; I. galbana), 6 mg/L (Nalco 625; I. galbana), 10 mg/L (Nalco 5165; C. gracilis), and 15 mg/L (Nalco 537-DA; C. gracilis). The lethal concentrations (LC50s) (96 h) toward zebra fish fry was 1 mg/L for Nalco 7607, 6.5 mg/L for Nalco 537-DA, 7.1 mg/L for Nalco 625, and 20 mg/L for Ivamin 803. Monoethanolamine had an LC50 higher than 5,000 mg/L. Nalco 5165 was not tested on fish fry. The heartbeat frequency ...

163

Laboratory studies of gas generation and potential for tank wall corrosion during blending of high-level wastes at the West Valley Demonstration Project  

Energy Technology Data Exchange (ETDEWEB)

Laboratory experiments were conducted to simulate the transfer of acidic THOREX waste from Tank 8D-4 into the alkaline PUREX waste in Tank 8D-2 at West Valley. The purpose of the experiments was to explore means of minimizing the production of nitric oxide (NO) gas during mixing of the two wastes and to assess the potential for the gas to further react in the vapor space possibly leading to enhanced corrosion of the tank walls. Forty one THOREX/PUREX mixing tests were conducted to explore the effects of stirring rate, pH, THOREX addition rate, THOREX or PUREX dilution, and temperature. The two most important criteria for minimizing NO production were to maintain some degree of agitation and the keep the pH in the PUREX high, preferably >12. Steel corrosion tests were performed in the presence of low partial pressures of NO{sub 2} and liquid water or water vapor. The NO{sub 2} (from oxidation of NO in the vapor space) concentrations were representative of those ...

1995-05-01

164

Genetic control of cotton insects: The pink bollworm as a working programme  

International Nuclear Information System (INIS)

Establishment of a continuous population has been prevented over a 24 year period in the San Joaquin Valley, USA, through continuous, daily in-season release of sterile pink bollworms based on an extensive trap monitoring programme. A post-harvest crop destruction ordinance and occasional use of pheromones as disruptants were the only other factors used by programme management, except in 1990. In 1990, the programme used a conventional insecticide on 280 acres (113 ha) out of 1.18 million acres (477,546 ha) of cotton. During the four year period 1986-1989, a management system was explored using a high rate pheromone disruption system and sterile insects. Major reductions in conventional insecticide usage, while maintaining extremely low populations, were evident in this semi-isolated valley of southern California. It is hoped that this will provide a model for a future large scale test on up to 20,000 acres (8100 ha) of cotton. (author). 11 ...

1993-09-01

165

Mass distribution of fission products in the 28.5 MeV alpha particle induced fission of "2"3"2Th  

International Nuclear Information System (INIS)

Mass distribution in 28.5 MeV alpha particle induced fission of "2"3"2Th has been determined using gamma spectrometric technique. The chain yields of 24 different fission products covering both symmetric and asymmetric mass divisions were determined. The mass distribution was found to be asymmetric with peak positions at mass numbers 96 and 136 respectively while the peak to valley ratio was 3.86. The results are compared with the available literature on 14 MeV neutron induced fission of "2"3"5U. (orig.).

166

Mass distribution of fission products in the 28. 5 MeV alpha particle induced fission of sup 232 Th  

Energy Technology Data Exchange (ETDEWEB)

Mass distribution in 28.5 MeV alpha particle induced fission of {sup 232}Th has been determined using gamma spectrometric technique. The chain yields of 24 different fission products covering both symmetric and asymmetric mass divisions were determined. The mass distribution was found to be asymmetric with peak positions at mass numbers 96 and 136 respectively while the peak to valley ratio was 3.86. The results are compared with the available literature on 14 MeV neutron induced fission of {sup 235}U. (orig.).

1989-01-01

167

Isomeric island in the vicinity of 66Fe  

Science.gov (United States)

An island of isomers have recently been observed on both sides of the N=40 shell below the Ni isotopes. Isomeric states in the 65Fe and 67Fe allow the knowledge of the single particle structure around the {nu}g9/2 shell. Moreover, the excitation energy of the first 2+ and 4+ states in the 68Fe have been established by {beta}-{gamma} correlation. The evolution of the structure of the Fe isotopes going far away from the valley of stability is, for the first time, given for N>40.

2006-04-26

168

Isomeric island in the vicinity of 66Fe  

International Nuclear Information System (INIS)

An island of isomers have recently been observed on both sides of the N=40 shell below the Ni isotopes. Isomeric states in the 65Fe and 67Fe allow the knowledge of the single particle structure around the #nu#g9/2 shell. Moreover, the excitation energy of the first 2+ and 4+ states in the 68Fe have been established by #beta#-#gamma# correlation. The evolution of the structure of the Fe isotopes going far away from the valley of stability is, for the first time, given for N>40.

2006-04-26

169

High-level waste tank modifications, installation of mobilization equipment/check out  

Energy Technology Data Exchange (ETDEWEB)

PUREX high-level waste (HLW) is contained at the West Valley Demonstration Project (WVDP) in an underground carbon-steel storage tank. The HLW consists of a precipitated sludge and an alkaline supernate. This report describes the system that the WVDP has developed and implemented to resuspend and wash the HLW sludge from the tank. The report discusses Sludge Mobilization and Wash System (SMWS) equipment design, installation, and testing. The storage tank required modifications to accommodate the SMWS. These modifications are discussed as well.

1992-08-31

170

The interaction of alcohol radicals with human hemoglobin. Pt. 1. Spectral properties of hemoglobin in the visible range  

International Nuclear Information System (INIS)

Aqueous deoxyhemoglobin solutions (2 mg/ml) were gamma-irradiated by a "6"0Co source in the presence of methanol, ethanol, 1-butanol and t-butanol under N_2O or argon. The effects of the interaction of the particular alcohol radical species with hemoglobin were determined according to the detected spectral alterations in the visible range. The amounts of stable final products in the form of methemoglobin (MetHb) and the sum of hemichromes and cholehemichromes (Hemichr) were estimated in irradiated preparations. For preparations irradiated under N_2O, the radiation yield for MetHb formation was three-fold lower in the presence of ethanol and 1-butanol [G(MetHb) = 0.33[ compared with preparations irradiated in the presence of t-butanol or without alcohol [G(MetHb) = 1.00[. The yield of hemichromes and cholehemichromes in preparations irradiated under N_2O increased in the order: ethanol (G = 0.38), 1-butanol (B = 0.52), ...

171

Spectrophotometric determination of rhenium with acetylacetone  

Energy Technology Data Exchange (ETDEWEB)

The optimum conditions of complex formation of rhenium(IV) with acetylacetone in water-ethanol medium were found, and a spectrophotometric method for determining rhenium with limit of detection 0.1 ..mu..g/ml was proposed. Rhenium can be determined in the presence of a 1000-fold excess of molybdenum. The procedure was tested on model solutions and used for the determination of rhenium in alloys.

1987-10-10

172

Pre-treatment and ethanol fermentation potential of olive pulp at different dry matter concentrations  

Energy Technology Data Exchange (ETDEWEB)

Renewable energy sources have received increased interest from the international community with biomass being one of the oldest and the most promising ones. In the concept of exploitation of agro-industrial residues, the present study investigates the pre-treatment and ethanol fermentation potential of the olive pulp, which is the semi solid residue generated from the two-phase processing of the olives for olive oil production. Wet oxidation and enzymatic hydrolysis have been applied aiming at the enhancement of carbohydrates' bioavailability. Different concentrations of enzymes and enzymatic durations have been tested. Both wet oxidation and enzymic treatment were evaluated based on the ethanol obtained in a subsequent fermentation step by Saccharomyces cerevisiae and Thermoanaerobacter mathranii. It was found that a four-day hydrolysis time was adequate for a satisfactory release of glucose and xylose. The combination of wet ...

2009-11-15

173

Modern concept for ethanol distilleries: maximization of the electricity surplus  

Energy Technology Data Exchange (ETDEWEB)

Once again Brazil faces the possibility of an electricity shortage in the near future. The low level of rain and the consequent reduction of hydroelectric reservoirs (hydroelectric energy represents almost 80% the total Brazilian electricity generation) led to the dispatch of thermal plants based on natural gas and/or fuel oil. However, the recent crisis regarding the Bolivian natural gas supply to Brazil increased the risk of a shortage of this energy source. Hence, the uncertainty of the electricity supply scenario is pushing the electricity prices up in the near future. A possible alternative to increase the electricity supply is the maximization of the electricity surplus in sugarcane mills. Back in 1970's and 1980's, cogeneration plants in sugarcane mills were primarily designed to consume all bagasse, and produce steam and electricity to the process. The plants used medium pressure steam boilers (21 bar and 300 deg C) and back pressure steam turbines. Some ...

2008-07-01

174

Metabolism and Binding of 14C-Maleic Hydrazide 1  

UK PubMed Central (United Kingdom)

Maleic hydrazide (MH) is taken up by corn and pea seedling roots and bound to some material which is insoluble in 80% ethanol or 5% trichloroacetic acid. 14C-MH is stable metabolically; chromatography...Full Text Available

1970-01-01

175

Levels and distribution of BCNU in GBM tumors following intratumoral injection of DTI-015 (BCNU-ethanol)  

UK PubMed Central (United Kingdom)

The alkylation products formed by in vitro treatment of DNA with tritium-labeled 1,3-bis(2-chloroethyl)-1-nitrosourea (3H-BCNU) were identified and quantified. Twelve adducts were resolved...Full Text Available

2007-01-01

176

Development of a dedicated ethanol ultra-low emission vehicle (ULEV) system design  

Energy Technology Data Exchange (ETDEWEB)

The objective of this 3.5 year project is to develop a commercially competitive vehicle powered by ethanol (or ethanol blend) that can meet California`s ultra-low emission vehicle (ULEV) standards and equivalent corporate average fuel economy (CAFE) energy efficiency for a light-duty passenger car application. The definition of commercially competitive is independent of fuel cost, but does include technical requirements for competitive power, performance, refueling times, vehicle range, driveability, fuel handling safety, and overall emissions performance. This report summarizes a system design study completed after six months of effort on this project. The design study resulted in recommendations for ethanol-fuel blends that shall be tested for engine low-temperature cold-start performance and other criteria. The study also describes three changes to the engine, and two other changes to the vehicle to improve ...

1995-02-01

177

Complex formation of At(I) with halogenides in alcoholic solutions  

International Nuclear Information System (INIS)

The stability constants of [AtX_2]"- with X = Cl, Br and I in ethanol and methanol as well as their ion mobilities at a temperature of 298 K and an ionic strength of 0.05 were determined by horizontal zone electromigration in homogeneous electrolyte solution. The results are compared with existing data from aqueous electrolyte systems. (author).

178

Antiperoxidative and antiinflammatory effect of Sida cordifolia Linn. on quinolinic acid induced neurotoxicity.  

Science.gov (United States)

Sida cordifolia is a plant belonging to the Malvaceae family used in many ayurvedic preparations. This study aimed at assessing the effects of ethanolic extract of Sida cordifolia root on quinolinic acid (QUIN) induced neurotoxicity and to compare its effect with the standard drug deprenyl in rat brain. Rats were divided into six groups: (1) control group (2) QUIN (55 microg/100 g bwt/day) (3) 50% ethanolic plant extract treated group (50 mg/100 g bwt/day) (4) Deprenyl (100 microg/100 g bwt/day) (5) QUIN (55 microg/100 g bwt/day) + 50% ethanolic plant extract treated group (50 mg/100 g bwt/day) (6) QUIN (55 microg/100 g bwt/day) + Deprenyl (100 microg/100 g bwt/day). At the end of the experimental period a status of lipid peroxidation products, protein peroxidation product, activities of the scavenging enzymes and the activities of the inflammatory markers were analyzed. Results revealed that the lipid peroxidation products ...

2010-05-25

179

Receptor model applied to patterns in space (RMAPS). Part II - apportionment of airborne particulate sulfur from project MOHAVE  

Energy Technology Data Exchange (ETDEWEB)

Airborne fine particle sulfur data from the summer intensive of Project MOHAVE (Measurement of Haze and Visual Effects) was analyzed by the Receptor Model Applied to Patterns in Space (RMAPS) model, a novel multivariate receptor-oriented model that applies to secondary and primary species. The sulfur data from 17 sites were found to be well predicted by three spatial patterns interpreted as sources along the valley of the Colorado River (including the large Mohave coal-fired power plant, a smaller power plant and the city of Las Vegas); transport from sources located to the southwest; and transport from sources located to the southeast. The model was tested by using parameters derived from the 17-site data set to apportion sulfur for six sites that were not part of the original data set. The sulfur apportionment for these site sites was in agreement with the original apportionment and the physical interpretation of the spatial patterns given above. The effects of ...

1997-02-01

180

Quaternary tilt of Death Valley determined from landform modelling of alluvial fans  

Energy Technology Data Exchange (ETDEWEB)

Alluvial fans along the east side of central Death Valley are being actively back-tilted along the Death Valley fault zone. Initial modelling of the Copper Canyon and Furnace Creek fans led to recognition of distinct segments. Field reconnaissance and aerial photo mapping were conducted to check model results and improve segment discrimination. Surface roughness, relative position, vegetation distribution, and drainage patterns provided independent evidence for segment discrimination. Subsequent modelling of individual segments produced a range of tilt values from 0.275[degree] to 0.559[degree] down to the northeast. Continued analysis of these fan segments is concentrated on: (1) assigning confidence and error values to the tilt values; and (2) dating individual segments. Further work will compare the tilt rates of east-side fans with those from the west. The mean squared error (MSE) is currently being used as a first order assessment of the ...

1993-04-01

181

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia  

Energy Technology Data Exchange (ETDEWEB)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic compositions of the waters ({sup 87}Sr/{sup 86}Sr = 0.7041-0.7172) ...

2005-04-01

182

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia  

International Nuclear Information System (INIS)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic compositions of the waters ("8"7Sr/"8"6Sr = 0.7041-0.7172) are ...

2005-04-01

183

Multiphasic helical Computed Tomography of hepatocellular carcinoma. Evaluation after various percutaneous ablation procedures  

International Nuclear Information System (INIS)

The purpose of this paper is to report the personal experience with helical CT evaluation of hepatocellular carcinoma treated with various percutaneous interventional procedures. From December 1996 to September 1998 it were examined with helical CT 41 patients (73 nodules in all) with hepatocellular carcinoma treated with percutaneous ablation therapies: conventional ethanol injection in 18 subjects (31 nodules), one-shot ethanol injection 3 (8 nodules), radiofrequency thermal ablation in 16 (25 nodules), and combined chemo embolization and ethanol injection in 4 (9 nodules). CT performed was 4-27 days after the last session, acquiring biphasic volumetric images in 14 patients and triphasic volumetric images in 27. A second treatment with subsequent CT study was performed for 28 lesions; 15 underwent 3 serial studies and 6 underwent 4 studies. Compared with pretreatment findings, the diameter was unchanged in 62% of the ...

1999-12-01

184

Softwood forest thinning as a biomass source for ethanol production: A feasibility study for California  

Energy Technology Data Exchange (ETDEWEB)

A plan has been put forth to strategically thin northern California forests to reduce fire danger and improve forest health. The resulting biomass residue, instead of being open burned, can be converted into ethanol that can be used as a fuel oxygenate or an octane enhancer. Economic potential for a biomass-to-ethanol facility using this softwood biomass was evaluated for two cases: Stand-alone and co-located. The co-located case refers to a specific site with an existing biomass power facility owned by Wheelabrator Environmental Systems Inc. near Martell, California. A two-stage dilute acid hydrolysis process is used for the production of ethanol from softwoods, and the residual lignin is used to generate steam and electricity. For a plant processing 800 dry tonnes per day of feedstock, the co-located case is an economically attractive concept. Total estimated capital investment is approximately $ 70 million for the ...

2000-07-01

185

Thermophilic slurry-phase treatment of petroleum hydrocarbon waste sludges  

Energy Technology Data Exchange (ETDEWEB)

Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of hydrocarbon material was more pronounced ...

1995-12-31

186

Thermophilic slurry-phase treatment of petroleum hydrocarbon waste sludges  

International Nuclear Information System (INIS)

Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of hydrocarbon material was more pronounced ...

1995-04-24

187

The effect of particle inlet conditions on FCC riser hydrodynamics and product yields.  

Energy Technology Data Exchange (ETDEWEB)

Essential to today's modern refineries and the gasoline production process are fluidized catalytic cracking units. By using a computational fluid dynamics (CFD) code developed at Argonne National Laboratory to simulate the riser, parametric and sensitivity studies were performed to determine the effect of catalyst inlet conditions on the riser hydrodynamics and on the product yields. Simulations were created on the basis of a general riser configuration and operating conditions. The results of this work are indications of riser operating conditions that will maximize specific product yields. The CFD code is a three-dimensional, multiphase, turbulent, reacting flow code with phenomenological models for particle-solid interactions, droplet evaporation, and chemical kinetics. The code has been validated against pressure, particle loading, and product yield measurements. After validation of the code, parametric studies were performed on various parameters such ...

1999-10-11

188

The combined SOx/NOx/air toxics reduction process using activated coke and flue gas clean up  

Energy Technology Data Exchange (ETDEWEB)

The dry desulfurization, denitrification and air toxics removal process using activated coke (AC) has been commercially adapted for flue gas clean up of a power plant, an oil refinery plant, an iron ore sintering plant, and a refuse incinerator. This process can achieve 100% removal of SO{sub x}, over 80% removal of NO{sub x} and effective removal of air toxics such as Hg, HCL, dioxines, etc., by contacting flue gas with AC and injecting NH{sub 3} for DeNO{sub x} at temperature range of about 100-200{degrees}C. For flue gas treatment, AC has several functions, which basically depends on the chemical surface group on AC inner surface. As adsorbent, AC can adsorb SO{sub x} at the relatively basic oxygen group site, where the adsorbed SO{sub x} is stored as sulfuric acid into micropore structure of AC. As catalyst, AC can decompose NO{sub x} catalytically with addition of NH{sub 3}. The catalytic activity (NO{sub x} removal efficiency) correlates with oxygen and ...

1996-10-01

189

Recycling boosts profits and saves resources  

Energy Technology Data Exchange (ETDEWEB)

The Raywell Process Plants unit, which reclaims a wide range of organic solvents, including chlorinated hydrocarbons, is based on thin film evaporation and distillation rather than steam distillation, thus reducing the risk of contamination by water. Henry Balfour and Co.'s Pfaudler Solvent Recovery System gives 96% or better solvent recovery and produces a near-solid waste suitable for landfill disposal; like the Raywell system, it uses a mechanically wiped thin-film evaporator. Midland Oil Refineries uses sa Raywell thin-film evaporator for recovery of waste lubricating oils rather than the conventional sulfuric acid/clay treatment, thus avoiding formation of sulfuric acid sludge waste. The Henry Balfour Bioenergy anaerobic digestion system gives yields of fuel gas with 65-75% methane as high as 0.8 cu m/kg BOD; it achieves 95-98% BOD removal with no pH control or nutrient addition because it separates solids from liquid effluent and retains liquids for ...

1980-05-01

190

Preliminary assessment of future refining impacts of the Clean Air Act Amendments of 1990  

Energy Technology Data Exchange (ETDEWEB)

A preliminary assessment of the future refining impacts of the Clean Air Act Amendments of 1990 has been performed with the Navy Mobility Fuels Forecasting Systems. The assessment suggests that gasoline reformulation costs in domestic coastal and near-coastal refining regions in the year 2000 could be 3.5 to 5.6 cents per gallon (in terms of 1989 currency). For heating value equivalent to one gallon of conventional gasoline, the regional total added costs (including reformulation costs) for reformulated gasoline could be 5.9 to 8.0 cents. In blending reformulated gasolines, the reduction of butane for lower Reid vapor pressure and the reduction of reformate for lower aromatics are generally compensated by increased percentages of alkylate and/or straight run naphthas. Relatively larger refinery process capacity additions are required for butane isomerization, alkylation, aromatics recovery, and distillate hydrotreating. 21 refs., 3 figs., 18 tabs.

1991-09-01

191

Planning logistics operations in the oil industry  

International Nuclear Information System (INIS)

In this paper we apply stochastic programming modelling and solution techniques to planning problems for a consortium of oil companies. A multiperiod supply, transformation and distribution scheduling problem - the Depot and Refinery Optimization Problem (DROP) - is formulated for strategic or tactical level planning of the consortium's activities. This deterministic model is used as a basis for implementing a stochastic programming formulation with uncertainty in the product demands and spot supply costs (DROPS), whose solution process utilizes the deterministic equivalent linear programming problem. We employ our STOCHGEN general purpose stochastic problem generator to 'recreate' the decision (scenario) tree for the unfolding future as this deterministic equivalent. To project random demands for oil products at different spatial locations into the future and to generate random fluctuations in their future prices/costs a stochastic input data simulator is ...

192

Phytoremediation : an industry partner's perspective  

International Nuclear Information System (INIS)

As part of their corporate policy on environmental protection, Chevron, has taken an approach to work collaboratively with other industry members, universities and government agencies in phytoremediation research. The petroleum industry is interested in the integration of phytoremediation with the many biotechnology treatment technologies currently being used by the industry. Phytoremediation is a complex technology that does not just transfer wastes to another site, but offers in-situ final use and disposal treatment at sites anywhere in the world. Sites for potential remediation range from abandoned large refineries, chemical plants, or small urban gas stations. Research has focused on the cleanup of metals and hydrocarbons in diverse types of soil, water and groundwater conditions. This includes research into remediation of petroleum contaminants such as total petroleum hydrocarbon (TPH), polynuclear aromatic hydrocarbons as well as benzene in soil and the ...

193

Optoelectronic multipoint liquid level sensor for light petrochemical products  

Science.gov (United States)

In this article we describe an optoelectronic sensor for assessing the level of light petrochemical products in technological tanks at the oil refineries. This sensor employs the multi-element vertical array of discrete micro- optical refractometric transducers. The transducers are made of silica glass and have the conical shape. In the air, each transducer operates as a tiny retro-reflector that optically couple together two multimode optical fibers. The optical coupling in the transducer is due to the internal reflection at the conical surface. The amount of the coupling depends on the refractive index of the surrounding media. In a fluid, the total internal reflection vanishes and the coupling becomes negligibly small. The number of immersed transducers is a measure of the fluid level in the reservoir. Because of the significance of the transducer transmission function, it is evaluated in detail under various combinations of the geometrical parameters of the ...

2000-06-01

194

Hexene catalytic cracking over 30% sapo-34 catalyst for propylene maximization: influence of reaction conditions and reaction pathway exploration  

Scientific Electronic Library Online (English)

Abstract in english Higher olefins are produced as a by product in a number of refinery processes and are one of the potential raw materials to produce propylene. In the present study, FCC model feed compound was considered to explore the olefin cracking features and options to enhance propylene using 30% SAPO-34 zeolite as catalyst in a micro-reactor. The superior selectivity of propylene (73 wt%) and higher total olefin selectivity was obtained over 30% SAPO-34 catalyst than over Y or ZSM- (more) 5 zeolite catalysts. The thermodynamical constraints were found to be relatively less serious in the case of 1-hexene conversion. Most of the 1-hexene follows a direct cracking pathway to give two propylene molecules, due to weak acid sites and better diffusion opportunities. The higher temperature and short residence time could also suppress the hydrogen transfer reactions. From OPE (olefins performance envelop) the products were classified as primary, secondary, or ...

2009-12-01

195

Chemical source identifications for natural resource injury/damage assessments and site assessments  

International Nuclear Information System (INIS)

Current regulations guiding technical aspects of natural resource damage assessments combine source, exposure pathway, resource injury, and monetary damage components. In order to associate any observed injury to the uncontrolled release of chemicals (e.g. oil spills, contaminated sediments, in-place toxics, etc.), it is important to link the chemical ''release'' to the injured resource. In complex environmental settings where multiple sources of similar chemicals are combined, multicomponent chemical methods must be used to link the release to the environmental distribution of chemicals. Three examples of the utility of multicomponent organic chemical analyses linked to comprehensive and representative sampling strategies will be discussed--the Shell Martinez Refinery oil spill, the Exxon Valdez oil spill, and a contaminated sediment assessment. These NRDA-based source identifications are based on use of polycyclic aromatic hydrocarbons, nitrogen and ...

1993-11-14

196

Charts give vapor loss from internal floating-roof tanks  

Energy Technology Data Exchange (ETDEWEB)

Nomographs have been constructed to estimate the average evaporation loss from internal floating-roof tanks. Loss determined from the charts can be used to evaluate the economics of seal conversion and to reconcile refinery, petrochemical plant, and storage terminal losses. The losses represent average standing losses only. They do not cover losses associated with the movement of product into or out of the tank. The average standing evaporation loss from an internal floating-roof tank depends on: vapor pressure of the product; type and condition of roof seal; tank diameter; and type of fixed roof support. The nomographs can estimate evaporation loss for product true vapor pressures (TVP) ranging from 1.5 to 14 psia, the most commonly used seals for average and tight fit conditions, tank diameters ranging from 50 to 250 ft, welded and bolted designs, and both self-supporting and column-support fixed roof designs. The charts are purposely limited to tank diameters ...

1987-03-09

197

Binding of vapour-phase mercury (Hg{sup 0}) on chemically treated bauxite residues (red mud)  

Energy Technology Data Exchange (ETDEWEB)

The development and testing of novel control technologies and advanced adsorbent materials continue to be active areas of research. In the present study, Hg capture using adsorbent material derived from the bauxite residue (red mud) from two North American refineries was studied. The red mud, seawater-neutralised red mud, and acid-treated red mud were evaluated for their mercury adsorption capacity and compared with other, more conventional sorbent materials. Two different seawater-neutralised red mud (Bauxsol) samples were treated with HCl and HBr in an effort to increase the mercury sorption capacity. In all cases, the acid treatment resulted in a significant increase in the total surface area and an increase in the total pore volume. The fixed-bed mercury capture experimental results showed that the HBr activation treatment was very effective at increasing the mercury capture performance of both Bauxsol samples whereas the HCl treatment had no effect on the ...

2008-04-15

198

Air pollutants emissions from waste treatment and disposal facilities.  

Science.gov (United States)

This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some cases the levels exceeded the ...

2006-01-01

199

The biofuels excellence network; Rede de excelencia em biocombustiveis  

Energy Technology Data Exchange (ETDEWEB)

The organization of the Biofuels Excellence Network, inside PROMINP - the Program of Mobilization of the National Industry of Oil and Natural Gas, has the objective of improving the actions of technical innovation and management in the chain of Oil, Gas Natural and Biofuels, through the optimized use of physical, financial, technological resources, of information and staff, with maximum qualification in areas of the human knowledge, whose purpose is to make decisions on specific problems of improvement of processes and/or products, besides promoting actions for the development and reinforcement of the markets of ethanol and biodiesel. The organization of the Biofuels Excellence Network became necessary, in order to enable Brazil to reach vanguard standards in biofuels (ethanol and biodiesel) in a sustainable, competitive and environmentally responsible way. Among the main reasons for the creation of the Biofuels Excellence Network are: to speed ...

2008-07-01

200

Syntrophic microorganisms in anaerobic environments. Zettai kenki kankyoka ni okeru biseibutsu no kyosei  

Energy Technology Data Exchange (ETDEWEB)

The most classic information on the syntrophic microorganisms in an anaerobic bacteria symbiotic system may be methanobacillus omelianskii. These bacteria were isolated as ones degrading alcohols such as ethanol into methane and were stably preserved for more than 20 years. But, it was clarified by later researches that this was a kind of symbiotic cocultivation system of the bacteria (S strain) which oxidizes ethanol into acetic acid, hydrogen, and carbon dioxide, and a kind of bacteria of the methanobacterium genus which produces or synthesizes methane from hydrogen and carbon dioxide. Such a symbiotic system of two kinds of anaerobic bacteria is the one of a kind of bacteria which produces hydrogen by oxidizing substances and of another kind of bacteria which consume hydrogen. Various kinds of symbiotic systems including those of animal-and-bacteria, and those of plant-and-bacteria exist in the nature. Symbiotic microorganism systems under ...

1992-07-10

201

Studies on the biosorption of uranium by a thermotolerant, ethanol-producing strain of Kluyveromyces marxianus  

Energy Technology Data Exchange (ETDEWEB)

The ability of residual biomass from the thermotolerant ethanol-producing yeast strain Kluyveromyces marxianus IMB3 to function as a biosorbent for uranium has been examined. It was found that the biomass had an observed maximum biosorption capacity of 120 mg U/g dry weight of biomass. The calculated value for the biosorption maximum, obtained by fitting the data to the Langmuir model was found to be 130 mg U/g dry weight biomass. Maximum biosorption capacities were examined at a number of temperatures and both the observed and calculated values obtained for those capacities increased with increasing temperature. Decreasing the pH of the biosorbate solution resulted in a decrease in uptake capacity. When biosorption reactions were carried out using sea-water as the diluent it was found that the maximum biosorption capacity of the biomass increased significantly. Using transmission electron microscopy, uranium crystals were shown to be concentrated on the outer ...

1997-06-01

202

Lipiodol-CT in the detection of tumor persistence in hepatocellular carcinoma treated with percutaneous ethanol injection  

Energy Technology Data Exchange (ETDEWEB)

Our purpose was to investigate the usefulness of Lipiodol-CT for detection of residual viable neoplastic tissue in hepatocellular carcinoma (HCC) lesions treated by means of percutaneous ethanol injection (PEI). An emulsion of 5 to 20 ml iodized oil and 50 to 70 mg doxorubicin hydrochloride was intraarterially injected in 18 patients with 25 HCC lesions treated by means of PEI one to 24 months before. At CT performed 3 to 5 weeks after injection, retention of Lipiodol was observed in 9 of 13 tumors that still contained viable neoplastic tissue and in 2 of 12 tumors proven to have undergone complete necrosis after PEI. The sensitivity and specificity of Lipiodol-CT were 69.2% and 83.3%, respectively. Thus, Lipiodol-CT seems to have limited diagnostic value after PEI, probably as a consequence of the alcohol-induced vascular damage, accounting for both false-negative and false-positive results. (orig.).

1994-07-01

203

Extrusion as a thermo-mechanical pre-treatment for lignocellulosic ethanol  

Energy Technology Data Exchange (ETDEWEB)

Two physical pre-treatment methods, particle size reduction by grinding and thermo-mechanical extrusion, were evaluated as alternatives to traditional biomass pretreatments for lignocellulosic ethanol. Commonly available agricultural co-products wheat bran and soybean hull were the model substrates. Extrusion led to higher reducing sugar yields as compared to grinding for wheat bran, but not in the case of soybean hulls. The best combination of extrusion screw speed and maximum barrel temperature were 7 Hz/150 C and 3.7 Hz/110 C. The use of a solvent mixture (sodium hydroxide, urea, and thiourea) and calcium chloride solution in combination with extrusion treatment did not lead to improvement in reducing sugar yield. However, extensive washing to get rid of solvents and enzymatic inhibitors improved the conversion efficiency substantially, resulting in total reducing sugar yields of 60-73% and 25-36%, respectively, for wheat bran and soybean hull. (author)

2010-12-15

204

Evaluation of antioxidant and anti-atherogenic properties of Glycyrrhiza glabra root using in vitro models.  

Science.gov (United States)

The aim of present study was to evaluate antioxidant property of Glycyrrhiza glabra root extracts using in vitro models. The dose-dependent aqueous and ethanolic extracts demonstrated the scavenging activity against nitric oxide (concentration that caused 50% inhibition of nitric oxide radicals [IC(50)]=72 and 62.1 microg/ml, respectively), superoxide (IC(50)=64.2 and 38.4 microg/ml, respectively), hydroxyl (IC(50)=81.9 and 63 microg/ml, respectively), DPPH (IC(50)=43.6 and 28.3 microg/ml, respectively) and ABTS(*+) (IC(50)=77.3 and 57.2 microg/ml, respectively) radicals. Further, both extracts showed strong reducing power and iron-chelating capacities. In the Fe(2+)/ascorbate system, both extracts were found to inhibit mitochondrial fraction lipid peroxidation. In copper-catalyzed human serum and low-density lipoprotein oxidation models, both extracts significantly (P<0.05) lengthened the lag phase along with a decline in the oxidation rate, conjugated dienes, ...

2009-04-22

205

Electronic absorption and emission spectra of Alq3 in solution with special attention to a delayed fluorescence  

International Nuclear Information System (INIS)

Tris(8-quinolinolato)aluminum(III) (Alq3) shows electronic absorption bands at 378, 360 (in a 1:1 mixed solvent of methanol and ethanol (ME) at 77 K), 334, 316, 300, 263, 255.8, and 233 nm in ethanol at room temperature. According to the polarized fluorescence excitation spectrum together with MO calculations, for instance, the 360 nm band is assigned to an LL CT transition (an intramolecular charge transfer transition between two ligands), and the 378 nm band to an LM/ML CT one (an intramolecular charge transfer transition between ligand and metal). Alq3 shows a broad fluorescence band peaking at around 478 nm in the ME matrix at 77 K. The emission spectrum measured with a phosphoroscope has two emission bands at 567 and 478 nm. The 567 nm band accompanies vibronic bands at 578 and 605 nm, being safely assigned to a phosphorescence of Alq3. The lifetimes of the 478 and 567 nm bands are both 5.4 ms. The lifetime of the 478 nm band together with ...

2008-08-01

206

Different purification methods and quality of sunflower biodiesel  

Energy Technology Data Exchange (ETDEWEB)

Biodiesel is derived from triacylglycerides and is produced primarily through transesterification, a chemical reaction of vegetable oils with alcohol, methanol or ethanol. The cost of raw material should be considered since 85 per cent of production cost is related to vegetable oil. The purpose of this study was to evaluate oil expression of sunflower seed. It also examined the sunflower crude oil as a raw material for biodiesel by transesterification in both laboratory and pilot scale studies. Three different biodiesel purification methods were examined. The best result for oil expelling (68.4 per cent) at the experimental stage was obtained for seeds with a moisture content of 6.9 per cent at 25 degrees C and at a screw speed of 114 rpm. For biodiesel production at the laboratory scale, the best result for oil expelling was 87.5 per cent. It was obtained with an ethanol:oil molar ratio of 4.7:1 and with a 4.42 per cent catalyst concentration ...

2010-07-01

207

Breaking the Biological barriers to Cellulosic Ethanol: A Joint Research Agenda  

Energy Technology Data Exchange (ETDEWEB)

A robust fusion of the agricultural, industrial biotechnology, and energy industries can create a new strategic national capability for energy independence and climate protection. In his State of the Union Address (Bush 2006), President George W. Bush outlined the Advanced Energy Initiative, which seeks to reduce our national dependence on imported oil by accelerating the development of domestic, renewable alternatives to gasoline and diesel fuels. The president has set a national goal of developing cleaner, cheaper, and more reliable alternative energy sources to substantially replace oil imports in the coming years. Fuels derived from cellulosic biomass - the fibrous, woody, and generally inedible portions of plant matter - offer one such alternative to conventional energy sources that can dramatically impact national economic growth, national energy security, and environmental goals. Cellulosic biomass is an attractive energy feedstock because it is an abundant, domestic, renewable ...

2006-06-01

208

Assessment of energy potential from biomass in Louisiana. Final report  

Energy Technology Data Exchange (ETDEWEB)

The objective of this project is to identify feasible Louisiana-grown biomass crops and residues, to combine these with technically and economically feasible conversion processes, and to provide integrated biomass energy production systems in Louisiana. Among the recommended integrated systems are: cotton gin trash and rice hull processing residues used for either direct combustion or methane or ethanol production. Steam generation via direct combustion is recommended. Hardwood chips are economically feasible despite considerable price and supply instability, while high sugar or starch content crops are easily converted to ethanol but limited by price. Possible breakthroughs in biomass production or in the hydrolysis of starch or cellulose substrates may decrease processing costs. Recommended areas for future study dealing with production include: (1) increase biomass availability and density; (2) increase harvesting, transportation and storage ...

1983-12-01

209

Analgesic activity of the aqueous fraction from the ethanolic extract of Chrysanthemum indicum in mice.  

Science.gov (United States)

The aqueous fraction (AF) of an ethanolic extract from Chrysanthemum indicum was evaluated for analgesic activity in mice using chemical and thermal models of nociception. Given orally, AF at doses of 300 and 600 mg/kg produced significant inhibitions on chemical nociception induced by intraperitoneal acetic acid, subplantar formalin/capsaicin injections and on thermal nociception in the tail-flick test and in the hot plate test. In the pentobarbital sodium-induced sleeping time test and the open-field test, AF neither significantly enhanced the pentobarbital sodium-induced sleeping time nor impaired the motor performance, indicating that the observed analgesic activity was unlikely due to sedation or motor abnormality. In a measurement of core body temperature, AF did not affect temperature within 80 min. Moreover, the effective dose (600 mg/kg) also showed no toxicity within 7 days. These results suggested further that AF produced analgesic activity possibly ...

2011-07-01

210

Ammonia Fiber Expansion (AFEX) Pretreatment, Enzymatic Hydrolysis, and Fermentation on Empty Palm Fruit Bunch Fiber (EPFBF) for Cellulosic Ethanol Production  

British Library Electronic Table of Contents (United Kingdom)

Empty palm fruit bunch fiber (EPFBF), a readily available cellulosic biomass from palm processing facilities, is investigated as a potential carbohydrate source for cellulosic ethanol production. This feedstock was pretreated using ammonia fiber expansion (AFEX) and enzymatically hydrolyzed. The best tested AFEX conditions were at 135??C, 45?min retention time, water to dry biomass loading of 1:1 (weight ratio), and ammonia to dry biomass loading of 1:1 (weight ratio). The particle size of the pretreated biomass was reduced post-AFEX. The optimized enzyme formulation consists of Accellerase (84??L/g biomass), Multifect Xylanase (31??L/g biomass), and Multifect Pectinase (24??L/g biomass). This mixture achieved close to 90% of the total maximum yield within 72?h of enzymatic hydrolysis. Fer...

2010-01-01

211

A procedure for batch separation of sup 14 C-hexose from sup 14 C-sucrose  

Energy Technology Data Exchange (ETDEWEB)

This presentation describes a method for separating {sup 14}C-hexose from {sup 14}C-sucrose in extracts of plant tissue. Portions of ethanol extracts are treated with activated charcoal in microcentrifuge tubes. Aliquots are removed, ethanol evaporated and replaced with reaction mixture that phosphorylates hexose (HEPPS, K{sub 2}HPO{sub 4}, Mg(C{sub 2}H{sub 3}O{sub 2}){sub 2}, ovalbumen, Na{sub 2}ATP, yeast hexokinase). After a time course, the hexokinase reaction is stopped (slowed considerably) to minimize effects of contamination enzyme activities. The stopping agent used is lyxose, a nonphosphorylable analogue of glucose. The strong anionic charge of phosphate introduced through the hexokinase action results in binding (> 95%) of hexose-phosphate to anion-exchange resin. Sucrose remains unbound (> 95%) in solution. This batch ion-exchange is performed in microcentrifuge tubes to allow many samples to be processed simultaneously. ...

1991-05-01

212

Study for application of multi fuel technology in the Brazilian automobilistic market; Estudo para aplicacao da tecnologia multi combustivel no mercado automobilistico brasileiro  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is a study for the application of a new technology that will be used in the engine management system in the vehicle; where the final consumer can opt for the inquiry performance or seeking an economy for the fuel consumption depending on its daily use and of the prices offered in the gas stations. Flexible Fuel is a technology in development for the automobile market that mixes the use of two fuels (gasoline and ethanol) and their mixtures in the internal combustion engine. (author)

2006-07-01

213

Radioprotective activity in some medicinal herbs  

Energy Technology Data Exchange (ETDEWEB)

Water-soluble, ethanol-insoluble extracts prepared from several medicinal herbs of the Araliaceae and other families were tested for their radioprotective activity by either measuring 30 days survival rates (a commonly applied method) or counting the thrombocytes 14 days after irradiation (an improved method) in mice. The extracts were i.p. injected once within 4 min after the whole body X-ray irradiation. Of 12 materials examined, Aralia elata, Angelica acutiloba and Morus bombysis seemed to be good starting materials for preparing radioprotective substance(s) because of their relatively high specific activity and high yields of the extracts. (author).

1993-09-01

214

Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane  

Energy Technology Data Exchange (ETDEWEB)

A process is claimed for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons, namely, acetic acid, ethanol and acetaldehyde, by continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with one or more alkali metals selected from the group consisting of lithium, potassium, cesium and rubidium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.

1980-11-25

215

Platinum-based ternary catalysts for low temperature fuel cells. Part 1. Preparation methods and structural characteristics  

Energy Technology Data Exchange (ETDEWEB)

Pt-based ternary catalysts have been proposed as electrode materials for low temperature fuel cells. Pt-Ru-based ternary catalysts were tested as anode materials with improved CO tolerance or enhanced activity for methanol or ethanol oxidation. Ternary catalysts based on platinum alloyed with first row transition metals were tested as cathode materials with improved activity for the oxygen reduction. This paper presents an overview of the preparation methods and structural characteristics of these ternary catalysts. (author)

2007-07-31

216

Pilot plant studies of the bioconversion of cellulose and production of ethanol  

Science.gov (United States)

Progress is reported in several areas of research. The following cellulosic raw materials were selected for study: wheat, barley, and rice straws, rice hulls, sorghum, corn stover, cotton gin trash, newsprint, ground wood, and masonite steam-treated Douglas fir and redwood. Samples were collected, prepared, and analyzed for hexosans, pentosans, lignin, ash, and protein. Results of acid extraction and enzymatic hydrolysis are discussed. Yields of glucose, polyglucose, xylose, and arabinose are reported. Progress in process design and economic studies, as well as pilot plant process development and design studies, is summarized. (JGB)

1977-01-31

217

Mechanical properties of titanium-niobium carbon nitride  

Energy Technology Data Exchange (ETDEWEB)

A study was made of the variation in strength characteristics of group IV transition metal carbon nitrides alloyed with carbides or group V metal nitrides. A complex solid solution of titanium-niobium carbonitride was preliminarily synthesized to a homogeneous equilibrium state and then crushed. The calculated quantity of binder metal was added as elemental powders, the mixture was vibration ball milled in ethanol and the plasticized charge was used to press experimental specimens for mechanical testing. The studies showed that the high-temperature strength properties of the new cermet are superior to standard type KNT. The material is thus promising for use in the manufacture of tools. 8 references, 3 figures.

1984-07-01

218

Inhaled toluene produces pentobarbital-like discriminative stimulus effects in mice  

Science.gov (United States)

The abuse of volatile solvents may be due to their ability to produce an intoxication similar to that produced by classical central nervous system depressants such as the barbiturates and ethanol. To evaluate this hypothesis, mice were trained to discriminate pentobarbital from saline injections in a two-lever operant task. Stimulus generalization was examined following 20-min inhalation exposures to toluene (300-5400 ppm). In 8 of 10 subjects, pentobarbital-lever responding occurred following toluene exposure indicating an overlap in the discriminative stimulus properties of toluene and pentobarbital.

1985-10-07

219

Influence of wood extractives in the polymerization of methyl methacrylate by gamma irradiation  

International Nuclear Information System (INIS)

Those materials that can be extracted from pine or oak by ether, ethanol, methyl methacrylate (MMA), or benzene--alcohol all act as inhibitors in the #gamma# polymerization of MMA--wood composites. It was found that preirradiation of either the wood or of the wood--monomer combination reduces or eliminates the inhibitory effect. The most practical industrial solution to this problem is to increase the dose, thereby achieving high molecular polymer in the composite. However, the presence of a maximum in the molecular weight--dose curves means that each wood--monomer pair may have a different optimum dose.

1975-01-01

220

Influence of scattering on superluminescence in composites dye solution ? nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

Spectral and energy luminescence characteristics of R6G dye solutions in ethanol with addition of Ag nanoparticle suspensions in different aggregate states are experimentally investigated. It is demonstrated that incorporation of non-aggregated and aggregated nanoparticles causes the superluminescence thresholds in R6G solutions to decrease. It is established that the optical properties of the laser beam propagation channel are transformed when low-power (20?mW) cw laser radiation passes through the suspension of nanoparticles. This is manifested through the occurrence of a region with enhanced nanoparticle density in the laser beam center, on which diffraction of laser radiation is observed.

2011-01-01

221

Influence of scattering on superluminescence in composites dye solution - nanoparticles  

Science.gov (United States)

Spectral and energy luminescence characteristics of R6G dye solutions in ethanol with addition of Ag nanoparticle suspensions in different aggregate states are experimentally investigated. It is demonstrated that incorporation of non-aggregated and aggregated nanoparticles causes the superluminescence thresholds in R6G solutions to decrease. It is established that the optical properties of the laser beam propagation channel are transformed when low-power (20 mW) cw laser radiation passes through the suspension of nanoparticles. This is manifested through the occurrence of a region with enhanced nanoparticle density in the laser beam center, on which diffraction of laser radiation is observed.

2011-09-01

222

Genetic Modification of Short Rotation Poplar Biomass Feedstock for Efficient Conversion to Ethanol  

Energy Technology Data Exchange (ETDEWEB)

The Bioenergy Feedstock Development Program, Environmental Sciences Division, Oak Ridge National Laboratory is developing poplars (Populus species and hybrids) as sources of renewable energy, i.e., ethanol. Notable increases in adaptability, volume productivity, and pest/stress resistance have been achieved via classical selection and breeding and intensified cultural practices. Significant advances have also been made in the efficiencies of harvesting and handling systems. Given these and anticipated accomplishments, program leaders are considering shifting some attention to genetically modifying feedstock physical and chemical properties, so as to improve the efficiency with which feedstocks can be converted to ethanol. This report provides an in-depth review and synthesis of opportunities for and feasibilities of genetically modifying feedstock qualities via classical selection and breeding, marker-aided selection and breeding, and genetic ...

2000-08-30

223

First investigations of complex formation of At(I) with phosphorous organic compounds  

Energy Technology Data Exchange (ETDEWEB)

Reaction of At(I) with triphenylphosphine, triethylphosphite and tri-n-octylphosphine oxide was investigated in ethanolic solution by means of electromigration. A cationic complex with triphenylphosphine was identified being stable at pH = 1,9 in the concentration range of the ligand between c = 10{sup -5} to 10{sup -3} M. At a higher ligand concentration and at pH>2, the reduction effect of phosphine is superimposed on the complex formation. Complex formation is confirmed by ligand exchange reactions with Br{sup -} and I{sup -}. A comparatively weak complex is formed by triethylphosphite and At(I). No compound is formed by tri-n-octylphosphine oxide and At(I). (orig.).

1989-01-01

224

First investigations of complex formation of At(I) with phosphorous organic compounds  

International Nuclear Information System (INIS)

Reaction of At(I) with triphenylphosphine, triethylphosphite and tri-n-octylphosphine oxide was investigated in ethanolic solution by means of electromigration. A cationic complex with triphenylphosphine was identified being stable at pH = 1,9 in the concentration range of the ligand between c = 10"-"5 to 10"-"3 M. At a higher ligand concentration and at pH>2, the reduction effect of phosphine is superimposed on the complex formation. Complex formation is confirmed by ligand exchange reactions with Br"- and I"-. A comparatively weak complex is formed by triethylphosphite and At(I). No compound is formed by tri-n-octylphosphine oxide and At(I). (orig.).

225

Energy production on farms. Sustainability of energy crops  

International Nuclear Information System (INIS)

In this article the results of a study on sustainability of energy crops are discussed. Contribution to the reduction of the greenhouse effect and other environmental effects were investigated for the Netherlands. The study assumed that energy crops are grown on set-aside land or grain land. Generating electricity and/or heat from hemp, reed, miscanthus, poplar and willow show the best prospects. These crops are sustainable and may in the future be economically feasible. Ethanol from winter wheat shows the most favourable environmental effects, but is not economically efficient. Liquid fuels from oil seed rape and sugar beet are not very sustainable. 2 tabs., 4 refs.

1994-12-06

226

Composition of insoluble kerogen-like organic polymer in the carbonate rocks of Orenburg gas-condensate deposit  

British Library Electronic Table of Contents (United Kingdom)

The concentrates of scattered organic matter???kerogen-like polymer, which is insoluble in acids and organic solvents???were isolated from rock samples taken at different depths from various stratigraphic units at the productive deposits of the Orenburg oil-gas condensate field using chemical methods. The chemical composition of the kerogen-like polymer and the concentrations of trace elements in it were studied. The regularities of evolutionary changes in the composition of the organic matter and the concentrations of trace elements in it in the order of the kerogen-like polymer and the following its consecutive derivatives were established: asphaltenes, ethanol-benzene tars, benzene tars, oils, and paraffins

2011-01-01

227

Change in the chemical composition and surface properties of high-silica zeolites in activating treatments and during a catalytic reaction  

Science.gov (United States)

The surface composition and composition near the surface and properties of high-silica zeolites of the TsVK-1 type were studied by XPES, IRS, and low-temperature adsorption of N/sub 2/. It was found that changing the sequence of operations during preparation of the H form of the zeolites results in a different set of acid centers on their surface, caused by migration of cations into the bulk of the zeolites. Migration of elements is also observed during the catalytic reaction of conversion of ethanol.

1988-08-01

228

Technoeconomic assessment of biomass to energy  

International Nuclear Information System (INIS)

A spreadsheet-based decision support system has been developed that allows easy evaluation of integrated biomass to electricity and biomass to ethanol systems. The Bioenergy Assessment Model (BEAM) has been developed to allow the techno-economic assessment of biomass to electricity and biomass to ethanol schemes, including investigation of the interfacing issues. Technical and economic parameters can be assessed for a variety of feedstocks, conversion technologies and generating cycles. Production modules are currently available for biomass supply from short rotation coppice and conventional forestry relevant to conditions and practices in NW Europe. The biomass conversion modules include pre-treatment (reception, storage, handling, comminution, screening and drying); atmospheric gasification (generic gasifier, wet gas scrubbing, dual fuel engine); pressure gasification (generic gasifier, hot gas filtration, gas turbine combined cycle); fast ...

1995-03-23

229

Life-cycle analysis and external costs in transportation  

International Nuclear Information System (INIS)

The assessment of greenhouse gas impacts in the US shows that against a baseline gasoline vehicle, the impact of including the full fuel cycle generally reduces the relative advantages of alternative transportation fuels. While a switch to diesel is estimated to save 30% as compared to gasoline, the savings from natural gas/LPG are (around 20%), for ethanol from corn (8%) and for battery electricity vehicles using power from coal (6%) are much smaller. This is largely due to the use of LCA rather than end-use comparisons. However, the results also show that there would be large savings from the use of ethanol from fuel cells using methanol (39%) or natural gas (50%), while ethanol from wood in a conventional engine appears to have the greatest savings (63%). In external costs of motor vehicle use, analysis results were presented for both air pollution and energy security impacts (including SPR, military expenditures, ...

230

Anaerobic digestion as final step of a cellulosic ethanol biorefinery: Biogas production from fermentation effluent in a UASB reactor-pilot-scale results.  

Science.gov (United States)

In order to lower the costs for second generation bioethanol from lignocellulosic biomass anaerobic digestion of the effluent from ethanol fermentation was implemented using an upflow anaerobic sludge blanket (UASB) reactor system in a pilot-scale biorefinery plant. Both thermophilic (53 degrees C) and mesophilic (38 degrees C) operation of the UASB reactor was investigated. At an OLR of 3.5 kg-VS/(m(3) day) a methane yield of 340 L/kg-VS was achieved for thermophilic operation (53 degrees C) while 270 L/kg-VS was obtained under mesophilic conditions (38 degrees C). For loading rates higher than 5 kg-VS/(m(3) day) the methane yields were, however, higher under mesophilic conditions compared to thermophilic conditions. The conversion of dissolved organic matter (VS(diss)) was between 68% and 91%. The effluent from the ethanol fermentation showed no signs of toxicity to the anaerobic microorganisms. However, a high content of suspended matter ...

2010-09-01

231

Three-dimensional elastic lidar winds  

Energy Technology Data Exchange (ETDEWEB)

Maximum cross-correlation techniques have been used with satellite data to estimate winds and sea surface velocities for several years. Los Alamos National Laboratory (LANL) is currently using a variation of the basic maximum cross-correlation technique, coupled with a deterministic application of a vector median filter, to measure transverse winds as a function of range and altitude from incoherent elastic backscatter lidar data taken throughout large volumes within the atmospheric boundary layer. Hourly representations of three- dimensional wind fields, derived from elastic lidar data taken during an air-quality study performed in a region of complex terrain near Sunland Park, New Mexico, are presented and compared with results from an Environmental Protection Agency (EPA) approved laser doppler velocimeter. The wind fields showed persistent large scale eddies as well as general terrain following winds in the Rio Grande valley.

1996-07-01

232

Surface characteristics and overlaying properties of flat-pressed wood plastic composites  

British Library Electronic Table of Contents (United Kingdom)

This study evaluated surface characteristics and overlaying properties of wood plastic composite (WPC) panels made from dry-blended rubber wood fiber-polypropylene (PP) powder formulations using a conventional flat-press process under laboratory conditions. Three levels of rubberwood fibers (Hevea brasiliensis), 40%, 50%, and 60%, based on the composition by weight, were mixed with the PP powder without and with 3% (based on weight) maleic anhydride grafted PP (MAPP) as a coupling agent. Contact angle measurements on the WPC samples were performed using a goniometer connected with a digital camera which collected one image per second. Roughness measurements, average roughness (R a), mean peak-to-valley height (R z), and maximum roughness (R y), were taken from the sanded samples along and ...

2011-01-01

233

Status and progress in sludge washing: A pivotal pretreatment method  

Energy Technology Data Exchange (ETDEWEB)

Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and leaching operations involve batchwise mixing, settling, and decanting within the ...

1995-01-01

234

Redistribution of radionuclides between a microbial mat and a carbonate body at the Garga hot spring (Baikal Rift Zone)  

British Library Electronic Table of Contents (United Kingdom)

The features of present deposits that form in the vicinity of hot springs can provide clues to the parameters of paleowaters in places of past hydrothermal activity marked by remnant carbonate and/or siliceous sinter. We investigated a large carbonate body at the Garga hot spring developing in the Baikal zone of nitric hydrotherms in the Barguzin Rift Zone valley. The main focus was on the structure of the carbonate mound, as well as on the partitioning of radioactive elements between the cyanobacterial mat and the inorganic component of the body (the issue that has never been explored before). The cyanobacterial community of the Garga spring is an active biosorbent of 226Ra, 228Ra, 210Pb. The radionuclides accumulated by biosorption become preserved in minerals that form within the bacter...

2011-01-01

235

Public power's roots deep in the Northwest  

Energy Technology Data Exchange (ETDEWEB)

Municipal power systems developed early in the Pacific Northwest, but a new dimension was added in the 1930s when the public utility district (PUD) concept combining urban and rural areas encited vigorous debate and the public rejected private-utility candidates. A favorable national climate developed for consumer-owned systems during the 1920s and 30s encouraging the passage of the Federal Water Power Act, the creation of the Tennessee Valley Authority, the building of Hoover Dam, and the establishment of the Bonneville Power Administration. This article reviews developments following the Public Utility Act of 1935, which authorized the Federal Power Commission and the uniform system of accounts. After tracing the record of investigations and policy trends during the Roosevelt era, it concludes that utilities benefited from accounting regulations. (DCK)

1982-01-01

236

Plant maintenance and plant life extension issue, 2006  

Science.gov (United States)

The focus of the March-April issue is on plant maintenance and plant life extension. Major articles/reports in this issue include: Spent fuel: myths and facts, by Jeffrey S. Merrifield, U.S. Nuclear Regulatory Commission; Critical pipe replacement procedure, by Geoff Gilmore, Climax Portable Machine Tools Inc.; Improving maintenance performance, by Larry Meyer and Joe Giuffre, DC Cook Nuclear Plant, American Electric Power; Equipment deficiency intolerance index, by Douglas F. Helms, Tennessee Valley Authority; Plant profile: I and C modernization at Dukovany, by Josef Rosol, CEZ Dukovany NPP, Czech Republic; and, Report: new plant activities.

2006-03-15

237

New stratigraphic markers in the late Pleistocene Palouse loess: novel fossil gastropods, absolute age constraints and non-aeolian facies  

British Library Electronic Table of Contents (United Kingdom)

Abstract Four stratigraphic sections in the southern part of the Columbia Basin preserve a sequence of aeolian and non-aeolian sediments ranging in age from 943 to >470 14C ka based on accelerator mass spectrometry radiocarbon dating of fossil molluscs, geochemistry of Cascade Mountain-sourced tephra and association with formally recognized pedostratigraphic units (the Washtucna and Old Maid Coulee soils). Study sections are interpreted as representing concurrent deposition of loess and distal Missoula Flood rhythmites in valleys tributary to main drainages backflooded during the Missoula Floods, and formation of carbonate and iron-rich soils. Sediments belong to the formally recognized L-1 and L-2 loess units established for the Palouse loess, which were deposited in the Columbia Basin su...

2010-01-01

238

Mass distribution of fission products from moderately excited sup 236 U compound nucleus  

Energy Technology Data Exchange (ETDEWEB)

The chain yields of 30 fission products were determined in 38 MeV {alpha}-particle induced fission of {sup 232}Th. The mass yield curve was found to be primarily asymmtric with a peak to valley (p/v) ratio of 3.5. A small peak has also been observed in the symmetric region. The observed p/v ratio has been resolved into the p/v ratios of the individual mass distributions of the possible fissioning isotopes of uranium formed as a result of multichance fission. An attempt has been made to explain the p/v ratios thus obtained in the light of the available excitation energy in the system. (orig.).

1990-01-01

239

Hydraulic Fracture Stimulation Treatments at East Mesa, Well 58-30; Geothermal Reservoir Well Stimulation Program; Experiment 3 and 4  

Energy Technology Data Exchange (ETDEWEB)

The tests reported were part of the DOE Geothermal Reservoir Well Stimulation Program. This East Mesa (Imperial Valley, CA) well was successfully stimulated with two fracture treatments, a dendritic fracture and a planar fracture. The natural flow production of the well increased 114 percent, to 197,900 lb/hr. These tests were among the few successful attempts of this program to increase flow from geothermal production wells. The general belief is that these tests worked OK primarily because the formation was sedimentary rock (similar to rock in most oil and gas wells that have been stimulated successfully. Similar tests in geothermal hard rock reservoirs did not work very well. (DJE 2005)

1982-02-01

240

High-level waste canister storage final design, installation, and testing. Topical report  

Energy Technology Data Exchange (ETDEWEB)

This report is a description of the West Valley Demonstration Project`s radioactive waste storage facility, the Chemical Process Cell (CPC). This facility is currently being used to temporarily store vitrified waste in stainless steel canisters. These canisters are stacked two-high in a seismically designed rack system within the cell. Approximately 300 canisters will be produced during the Project`s vitrification campaign which began in June 1996. Following the completion of waste vitrification and solidification, these canisters will be transferred via rail or truck to a federal repository (when available) for permanent storage. All operations in the CPC are conducted remotely using various handling systems and equipment. Areas adjacent to or surrounding the cell provide capabilities for viewing, ventilation, and equipment/component access.

1998-04-01

241

Geology, physical properties, and surface effects at Discus Thrower Site, Yucca Flat, Nevada Test Site  

International Nuclear Information System (INIS)

Geologic studies in connection with Project Discus Thrower have furnished detailed stratigraphic and structural information about northwestern Yucca Flat, Nevada Test Site. The Paleozoic rocks consist of a lower carbonate sequence, argillite of the Eleana Formation, and an upper carbonate sequence. The distribution of these rocks suggests that both top and bottom of the Eleana are structural contacts, probably thrusts or reverse faults. The overlying tuff includes several units recognized in the subsurface, such as the Fraction Tuff and tuff of Redrock Valley. Other units recognized include bedded tuff associated with the Grouse Canyon Member of Belted Range Tuff, and the Rainier Mesa and Ammonia Tanks Members of the Timber Mountain Tuff. The Timber Mountain and Grouse Canyon are extensively altered to montmorillonite (a swelling clay), possibly as a result of ponding of alkaline water. The overlying alluvium locally contains at the base a clayey, tuffaceous ...

242

Geochemical features of re-deposited organic matter occurring in fluvioglacial sediments in the Racib?rz region (Poland): A case study  

British Library Electronic Table of Contents (United Kingdom)

The erosion of rocks rich in organic matter typically leads to the complete mineralization of the organic material. However, in some cases, it is re-deposited to become a part of sediments once more. This process should be considered to be a part of global carbon cycle, possibly much more significant than assumed to-date. The research presented here aims to characterize re-worked organic matter occurring in post-glacial sediments of southern part of Poland, in the Oder river valley (the Racib?rz town region, Miocene, Pleistocene and Holocene age). Organic substances extracted from the sediments originated from organic matter that had resided in rocks eroded by glaciers. Sediments were sampled in two boreholes which sediments were correlated. Sediments were extracted and extracts analyzed w...

2008-01-01

243

Forced convective heat transfer in cross-corrugated solar air heaters  

Science.gov (United States)

Forced convective heat transfer in a cross-corrugated channel solar air heater has been studied experimentally using air as a working fluid. The channel was formed by two transversely positioned corrugated sheets and two flat thermally insulated side walls. One corrugated sheet was heated by a radiant heater, while the other was thermally insulated. The fluid velocity and temperature, and the wall temperature and the local heat flux across the heated corrugated sheet were measured for a variety of operating flow rates. Experimental results for the channel geometry have yielded the correlation Nu = 0.0743 (Re)[sup 0.76]. This heat-transfer coefficient is about 2.8 times that of a smooth flat channel. The experiments showed that local heat transfer rate was smaller on the valley of the corrugation than that on the peak. The ratio of the local heat transfer rates on the two locations was related to the Reynolds number.

1994-11-01

244

Existing systems review of treatment media for the Bear Creek Valley treatability study, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

Energy Technology Data Exchange (ETDEWEB)

In situ treatment has been proposed as a remediation alternative for surface water and groundwater contaminated with uranium and nitrate as a result of former waste disposal practices in the S-3 Ponds. Interceptor trenches containing reactive media have been proposed to treat groundwater, and constructed wetlands and/or algal mats are potential alternatives for treating surface water. This report presents the results from testing of ten different reactive media, and combinations of media, that are candidates for use in the proposed interceptor trenches to remove uranium and nitrate from groundwater. It also presents the results of testing and evaluation of algal mats and wetlands for removing uranium and nitrate from surface water.

1998-01-01

245

Estimating the erosion and deposition rates in a small watershed by the 137Cs tracing method  

International Nuclear Information System (INIS)

Understanding the erosion and deposition rates in a small watershed is important for designing soil and water conservation measures. The objective of this study is to estimate the net soil loss and gain at points with various land use types and landform positions in a small watershed in the Sichuan Hilly Basin of China by the 137Cs tracing technique. Among various land use types, the order of erosion rate was bare rock > sloping cultivated land > forest land. The paddy field and Caotu (a kind of cultivated land located at the foot of hills) were depositional areas. The erosion rate under different landform was in this order: hillside > saddle > hilltop. The footslope and the valley were depositional areas. The 137Cs technique was shown to provide an effective means of documenting the spatial distribution of soil erosion and deposition within the small watershed.

2009-02-01

246

Chemical cotton stalk destruction for maintenance of host-free periods for the control of overwintering boll weevil in tropical and subtropical climates  

British Library Electronic Table of Contents (United Kingdom)

In the Lower Rio Grande Valley (LRGV) of Texas, cotton regrows and produces fruit from undestroyed stalks throughout the winter, and in spring weevils from such locations become a serious threat. The success of the boll weevil eradication program, which was reintroduced in the LRGV in 2005, will be dependent on thorough stalk destruction following harvest. However, adverse weather conditions and conservation tillage often impede immediate and complete stalk destruction using typical tool implements, and alternative stalk control methods are needed. This study provides an examination of the efficacy for cotton stalk destruction of different herbicides (thifensulfuron-methyl + tribenuron-methyl, dicamba-diolamine, 2,4-D-dimethylammonium, flumioxazin, 2,4-DB-dimethylammonium and carfentrazone...

2007-01-01

247

Autoradiographic study of regional distribution of gastric mucosal blood flow  

Energy Technology Data Exchange (ETDEWEB)

Iodo(/sup 14/C)antipyrine autoradiography was used to measure gastric mucosal blood flow in anesthetized rats and to study regional distribution. Blood flows of 61 +/- 8 ml.100 g-1.min-1 (means +/- SE) in corpus and 84 +/- 9 ml.100 g-1.min-1 in antral mucosa compared well with previously reported measurements by hydrogen clearance. Blood flow in the crests of corpus mucosal folds was significantly higher than in the valleys between folds, indicating that the greater susceptibility of the former areas to acute injury, documented in several studies, is not associated with a perfusion defect in the resting stomach. Corpus mucosal blood flow was also higher in the side walls of the stomach than in the greater curvature region, and in distal than in proximal locations. No systematic regional variations within antral mucosa were demonstrated.

1988-04-01

248

Assessing variability of water quality in a groundwater-fed perennial lake of Kashmir Himalayas using linear geostatistics  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a study on Manasbal lake, which is one of the high altitude lakes in the Kashmir Valley, India. Eighteen water samples were analysed for major ions and trace elements to assess the variability of water quality of the lake for various purposes. Geostatistics, the theory of regionalized variables, was then used to enhance the dataset and estimate some missing spatial values. Results indicated that the concentration of major ions in the water samples in winter was higher than in summer. The scatter diagrams suggested the dominance of alkaline earths over the alkali elements. Three types of water were identified in the lake that are referred to as Ca?HCO3, Mg?HCO3 and hybrid types. The lake water was found to be controlled by rock?water interaction with carbonate lithology ...

2011-01-01

249

Low-Cost Hydrogen Distributed Production System Development  

Science.gov (United States)

H{sub 2}Gen, with the support of the Department of Energy, successfully designed, built and field-tested two steam methane reformers with 578 kg/day capacity, which has now become a standard commercial product serving customers in the specialty metals and PV manufacturing businesses. We demonstrated that this reformer/PSA system, when combined with compression, storage and dispensing (CSD) equipment could produce hydrogen that is already cost-competitive with gasoline per mile driven in a conventional (non-hybrid) vehicle. We further showed that mass producing this 578 kg/day system in quantities of just 100 units would reduce hydrogen cost per mile approximately 13% below the cost of untaxed gasoline per mile used in a hybrid electric vehicle. If mass produced in quantities of 500 units, hydrogen cost per mile in a FCEV would be 20% below the cost of untaxed gasoline in an HEV in the 2015-2020 time period using EIA fuel cost projections for natural gas and untaxed gasoline, and 45% ...

2011-03-10

250

Waste management plan for Phase II of the Bear Creek Valley treatability study Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

Energy Technology Data Exchange (ETDEWEB)

This Waste Management Plant (WMP) for the Bear Creek Valley Treatability Study addresses waste management requirements for the Oak Ridge Y-12 Plant. The study is intended to produce treatment performance data required to design a treatment system for contaminated groundwater. The treatability study will consist of an evaluation of various treatment media including: continuous column tests, with up to six columns being employed to evaluate the performance of different media in the treatment of groundwater; an evaluation of the denitrifying capacity and metal uptake capacity of a wetland system; and the long-term denitrifying capacity and metal uptake capacity of algal mats. The Sampling and Analysis Plan (SAP) covers the project description, technical objectives, procedures, and planned work activities in greater detail. The Health and Safety Plan (HASP) addresses the health and safety concerns and requirements for the proposed sampling activities. This WMP ...

1997-05-01

251

Variability of indicator values for ozone production sensitivity: a model study in Switzerland and San Joaquin Valley (California)  

International Nuclear Information System (INIS)

The threshold values of indicator species and ratios delineating the transition between NO_x and VOC sensitivity of ozone formation are assumed to be universal by various investigators. However, our previous studies suggested that threshold values might vary according to the locations and conditions. In this study, threshold values derived from various model simulations at two different locations (the area of Switzerland by UAM Model and San Joaquin Valley of Central California by SAQM Model) are examined using a new approach for defining NO_x and VOC sensitive regimes. Possible definitions for the distinction of NO_x and VOC sensitive ozone production regimes are given. The dependence of the threshold values for indicators and indicator ratios such as NO_y, O_3/NO_z, HCHO/NO_y, and H_2O_2/HNO_3 on the definition of NO_x and VOC sensitivity is discussed. Then the variations of threshold values under low emission conditions and in two different days are examined in ...

252

Seismic stratigraphy in the South Cretan fault valley system: A comparison with the upper Quaternary gravitative sedimentation of the region  

Energy Technology Data Exchange (ETDEWEB)

A synthesis of the sedimentation processes as deduced from the seismic stratigraphy and the deduced facies associations suggests the following. Small fans developed along the northern major fault line of the SCFVS and contains sediment fed directly from Crete through a series of small canyons, most of which trend perpendicular to the coast. However, the main east-west-trending valley transects the mid- and lower fan sectors and contains several intravalley basinal areas, converging toward the main Messara basin. Thus much of the suprafan sediment is reworked and longitudinally transported into the deeper basins. In these deeper intrabasinal and main basinal areas the thickness of the post-Messinian sediments generally exceeds 800 m and in places exceeds 1,500 m. Toward the south the SCFVS receives additional sediment from the Ptolemy Mountains and the Gavdos rise. Cores recovered along the SCFVS contain a remarkable association of sedimentary sequences which are ...

1988-08-01

253

Reservoir anatomy within a sequence stratigraphic framework: The Pennsylvanian Breathitt group of Eastern Kentucky  

Energy Technology Data Exchange (ETDEWEB)

Detailed quantitative sequence stratigraphic analysis and three-dimensional (3-D) modeling of the fluvio-deltaic Pikeville, Hyden, and four Corners formations of the Breathitt Group, eastern Kentucky, indicate that it is possible to make confident deterministic correlations of sand bodies at offshore development well spacings. The key to high-confidence correlation is the delineation of the 3-D architecture of third-order composite sequences, which are seismically mappable, and the recognition of internal fourth-order sequences, which are stacked into lowstand, transgressive, and highstand sequence sets. Volumetric partitioning of reservoir sand bodies between systems tracts and sequences allows prediction of channel sandstone geometries and channel: crevasse splay ratios. Furthermore, channel-fill type is predictable from the sequence stratigraphy. Within 13 studied fourth-order sequences, incised valley fills represent the main reservoirs, which are laterally ...

1993-09-01

254

Remedial Investigation Work Plan for Chestnut Ridge Operable Unit 1 (Chestnut Ridge Security Pits) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

Energy Technology Data Exchange (ETDEWEB)

This Remedial Investigation (RI) Work Plan specifically addresses Chestnut Ridge Operable Unit 1, (OU1) which consists of the Chestnut Ridge Security Pits (CRSP). The CRSP are located {approximately}800 ft southeast of the central portion of the Y-12 Plant atop Chestnut Ridge, which is bounded to the northwest by Bear Creek Valley and to the southeast by Bethel Valley. Operated from 1973 to 1988, the CRSP consisted of a series of trenches used for the disposal of classified hazardous and nonhazardous waste materials. Disposal of hazardous waste materials was discontinued in December 1984, while nonhazardous waste disposal ended on November 8, 1988. An RI is being conducted at this site in response to CERCLA regulations. The overall objectives of the RI are to collect data necessary to evaluate the nature and extent of contaminants of concern (COC), support an ecological risk assessment (ERA) and a human health risk assessment (HHRA), support ...

1993-09-01

255

Quaternary faults near the proposed Eagle Flat low-level radioactive waste repository, Trans-Pecos Texas  

Science.gov (United States)

The Eagle Flat basin, an intermontane basin in Trans-Pecos Texas, is being considered as a possible site for the Texas repository of low-level radioactive wastes. Intermontane basins and associated normal faults formed in response to Basin and Range tectonism that began about 24 Ma ago. The most active late Tertiary and Quaternary faults occur within the Hueco Bolson (HB) and the Salt Basin/Salt Flat/Lobo Valley, west and east, respectively, of the proposed repository. Several faults of the southeast HB which are within 50 km of the site, displace middle Pleistocene deposits 10 to 24 m. The most recent surface rupture in the southeast HB probably occurred on the Amargosa fault during the Holocene. Upper Pleistocene deposits are offset 2.5 to 4.5 m, and middle Pleistocene deposits are displaced 24 m. Fault scarps within 50 km east of the proposed repository are associated with faults bounding the Salt Basin/Salt Flat/Lobo Valley. In the southern ...

1992-01-01

256

Feasibility of delivering grid therapy using a multileaf collimator  

International Nuclear Information System (INIS)

The feasibility of using a multileaf collimator (MLC) for grid therapy is demonstrated in this study. Grids with the projected field openings of 10 mmx10 mm and 5 mmx5 mm were created using multiple MLC-shaped fields. The deposited doses were measured with films at different depths in a solid water phantom and compared to those of Cerrobend grid collimators of similar hole sizes and hole separations. At the depth of maximum dose (d_m_a_x), the valley-to-peak dose ratios of the MLC grids were found to be about 11% and 19% for the respective 10 mmx10 mm and 5 mmx5 mm grid openings, and those of the corresponding grid blocks were about 15% and 20%. To quantify the dose contributed by transmission in the blocked areas due to the limited leaf thickness, Monte Carlo simulations (based on convolution/superposition method) were performed to calculate the doses in the solid water phantom using an ideal MLC with no leakage and perfect divergence in both the leaf end and ...

2006-01-01

257

Evaluation of potential hydrocarbon sources in lacustrine facies of Newark Supergroup, eastern United States  

Energy Technology Data Exchange (ETDEWEB)

Lacustrine rocks are a significant component of many rift-valley sequences. Comparisons of both active and ancient rift valleys indicate that the lacustrine facies are commonly rich in organic matter and may be important sources for oil. For example, Holocene sediments in Lake Tanganyika and Cretaceous lacustrine rocks in west Africa contain as much as 12% and 20% TOC, respectively. The Newark Supergroup contains abundant lacustrine rocks. The widespread occurrence of black shales, the general similarity to known organically rich rift systems, and a few isolated geochemical analyses have caused some speculation about the potential of the Newark Supergroup to be an effective source of oil and gas. Sufficient geochemical analyses are available from lacustrine rocks in the Newark, Connecticut, and Deep River basins to evaluate their potential as hydrocarbon sources. In general, both the quantity and quality of organic matter in these rocks are ...

1985-02-01

258

Electronic topological transition in an n-BiSb semiconductor alloy in the quantum limit range of magnetic fields for H-parallel C{sub 2}  

Science.gov (United States)

The galvanomagnetic properties of single-crystal samples of the Bi{sub 0.93}Sb{sub 0.07} semiconductor alloy with the electron density n = 1.6 x 10{sup 17} cm{sup -3} in magnetic fields up to 14 T at T = 1.6 K have been investigated. The resistivity {rho} and Hall coefficient R have been measured as functions of the magnetic field directed along the binary axis of a crystal for a current flowing through a sample along the bisector axis; i.e., the components {rho}{sub 22} and R{sub 32,1} have been measured. The strong anisotropy of the electron spectrum of the samples makes it possible to separately observe quantum oscillations of the magnetoresistance {rho}{sub 22}(H) for H -parallel C{sub 2} in low magnetic fields for two equivalent ellipsoids with small extremal cross sections (secondary ellipsoids) and in high magnetic fields for electrons of the ellipsoid with a large extremal cross section (main ellipsoid). An increase in the energy of the electrons of secondary ellipsoids in the ...

2010-08-15

259

Final Report for "Investigation of reaction networks and active sites in bio-ethanol steam reforming over Co-based catalysts" with all publications attached.  

Energy Technology Data Exchange (ETDEWEB)

This was a university-based research project in support of distributed reforming production technologies for hydrogen. Our objective was to examine the steam reforming of bio-ethanol and other related bio-derived liquids over non-precious metal catalyst systems to enable small-scale distributed hydrogen production technologies from renewable sources. The study targeted development of a catalytic system that does not rely on precious metals and that can be active in the 350-550 C temperature range, with high selectivity and high stability. To this end, we adopted a multi-prong research strategy, that included catalyst formulation and synthesis, detailed catalyst characterization, reaction kinetics and reaction engineering, molecular modeling and economic analysis studies. Our approach was an iterative one, where the knowledge gained in one aspect of the study was utilized to modify and fine-tune catalyst development. The research addressed many fundamental and ...

2011-03-31

260

The preparation and characterization of synthetic multi-element standards for testing the performance of k_0-NAA: the state of affairs  

International Nuclear Information System (INIS)

As part of the general QC/QA management of the k_0-standardization, three types of 'SMELS' (synthetic multi-element standards) are being developed to check the performance of k_0-NAA when implemented in a laboratory. Phenol-formaldehyde resin is proposed in this paper as the matrix of choice. Based on previous work, this material could be prepared with sufficient purity so as to make interferences with the spiking elements negligible. The matrix was found to be adequately resistant towards high neutron flux irradiation. A selection was made of compounds, soluble in ethyl alcohol, for spiking the prepolymer ethanolic solution with the elements of interest. Finally, some prototypes were prepared and a satisfactory homogeneity of the spiked elements was found for 50 mg sample intake.

2001-07-12

261

The effect of wood extractives on the thermal stability of different wood-LLDPE composites  

Energy Technology Data Exchange (ETDEWEB)

The thermal stability of wood polymer composites made with extractive-free wood from four different wood species was studied. Hot water (HW) extractives, ethanol/cyclohexane (E/C) extractives and both types of extractives were eliminated from A. cyclops, E. grandis, P. radiata and Q. alba. Composites of LLDPE and 10 wt% of wood were prepared, using poly vinyl alcohol-co-ethylene (EVOH) as a compatibilizer. The thermal degradation behavior of the composites was characterized with thermogravimetric analysis (TGA). The obtained results showed that in all cases, the degradation temperatures shifted to higher values after removal of the extractives. The removal of E/C extractives was less effective in its improvement of the thermal stability than the removal of HW extractives. The largest improvement on the thermal stability of WPCs was achieved when both types of extractives (E/C and HW) were removed.

2009-01-05

262

Systematic evaluation of pre-HPLC sample processing methods on total and individual isoflavones in soybeans and soy products  

British Library Electronic Table of Contents (United Kingdom)

There are mainly two protocols in isoflavone analysis, one that involves hydrolysis prior to HPLC analysis and the other direct HPLC analysis. In this study, three different hydrolysis methods were systematically re-evaluated, and compared with direct HPLC analysis. Acidic hydrolysis (1.2-3M HCl in ethanol at 80^oC) showed a maximum conversion of ca. 92% from glucosides to aglycones in 2h; however, longer reaction caused degradation of genistein. Alkaline hydrolysis using 2M NaOH converted acetylglucosides and malonylglucosides to their respective glucosides within 10min. Glucuronidase from H. pomatia effectively converted isoflavone glucosides and acetylglucosides to aglycones. Quantification of the total isoflavones in various soy food products showed no significant difference among dire...

2011-01-01

263

Synthesis and investigation of #pi#-conjugated azomethine self-assembled multilayers by layer-by-layer growth  

International Nuclear Information System (INIS)

Layer-by-layer formation for #pi#-conjugated azomethine multilayers bonded on substrates was investigated. The multilayers were synthesized using ethanol (EtOH) and dichloromethane (DCM) as reaction solvents. The multilayer characteristics were analyzed using UV-vis absorption spectroscopy, ellipsometric thickness, and atomic force microscopy. The absorption spectra and ellipsometric thicknesses of multilayers formed using EtOH and DCM were compared. The results indicate that EtOH is more suitable than DCM for such layer-by-layer formation. In addition, bandgaps estimated from the absorption edge of multilayers were investigated. The results indicate that the bandgap decreases as the number of benzene rings contained in the molecular chain of the multilayer increases. Also, a multilayer with four benzene rings bonded on a substrate had a bandgap close to that of a polymer with a similar chemical structure.

2010-07-01

264

Sulfonaphtholazoresorcinol as reagent for tungsten  

International Nuclear Information System (INIS)

Interaction of W(6) with sulphonaphtholazoresorcinol (SNAR) in aqueous solution has been studied. Tungsten is determined in the form of sulphonaphtholazoresorcinate by extraction with higher alcohols. The optimum conditions for the formation of a complex of W with SNAR in aqueous solution are as follows: a 10-fold excess of SNAR, concentration of HCl 1-1.5N, ethanol content 5-10 vol.%, time of formation of the complex 30 min. A component ratio for the complex has been established in the case of aqueous solution and extract; molar extinction coefficients are 0.9x10"4 and 1.7x10"4, respectively. The formation constant for the complex being extracted is 2.2x10"2"3. A method has been developed for determination of microgram quantities of W in a vanadium specimen.

1977-01-01

265

Spectroscopic studies on weak intermolecular interactions of fluoranthene derivatives with benzene or ethanol in cyclohexane  

International Nuclear Information System (INIS)

Complete text of publication follows. We have published on the spectroscopic study on the formation of a 1:1 molecular complex of fluoranthene (F) with benzene (B) in cyclohexane and estimated the equilibrium constant K(F-B) (0.147 dm3 mol-1 at 298 K), enthalpy change DH(F-B) (-5.9 kJ mol-1) and entropy change DS(F-B) (-36 JK-1mol-1 at 298 K) for this complex formation (S. Enomoto et al., Bull. Chem. Soc. Jpn., 75 (2002) 689-693). In this study, the electronic absorption spectra have been observed for the fluoranthene derivatives in cyclohexane-benzene and/or cyclohexane-ethanol mixed solvents to investigate the weak intermolecular interactions between fluoranthene derivatives and benzene or ethanol. The electronic absorption spectra of 3-aminofluoranthene (AF) in the mixed solvent mentioned above showed isosbestic points with varying B and ethanol (E) concentrations. These observations indicate that AF forms a 1:1 ...

2009-09-03

266

Specific consumption of liquid biofuels in gasoline fuelled engines  

Energy Technology Data Exchange (ETDEWEB)

Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline. 40 refs., 5 figs., 2 tabs.

2008-11-15

267

Specific consumption of liquid biofuels in gasoline fuelled engines  

British Library Electronic Table of Contents (United Kingdom)

Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline.

2008-01-01

268

Single-step mineralization of woodpile chitosan scaffolds with improved cell compatibility  

British Library Electronic Table of Contents (United Kingdom)

Abstract A facile and efficient single-step mineralization approach was exploited for achieving nanoscopic hydroxyapatite (HAP) crystal layer in chitosan porous matrix, wherein a mixed water-ethanol solvent was used to control the growth of minerals. The crystallographic structure, morphology, and mechanical properties of the scaffold were analyzed with XRD, FTIR, environmental scanning electric microscopy (ESEM), TEM, and compression tests. The behaviors and responses of MC3T3-E1 pre-osteoblast cells on the scaffolds were studied as well. The results showed that the scaffolds kept woodpile structure with predefined and controlled hierarchical structure after mineralization. The inorganic phase in the mineralized chitosan scaffolds was determined as pure rod-like HAP, which settled densely...

2011-01-01

269

Scientific challenges of bioethanol production in Brazil  

British Library Electronic Table of Contents (United Kingdom)

Bioethanol (fuel alcohol) has been produced by industrial alcoholic fermentation processes in Brazil since the beginning of the twentieth century. Currently, 432 mills and distilleries crush about 625 million tons of sugarcane per crop, producing about 27 billion liters of ethanol and 38.7 million tons of sugar. The production of bioethanol from sugarcane represents a major large-scale technology capable of producing biofuel efficiently and economically, providing viable substitutes to gasoline. The combination of immobilization of CO2 by sugarcane crops by photosynthesis into biomass together with alcoholic fermentation of this biomass has allowed production of a clean and high-quality liquid fuel that contains 93% of the original energy found in sugar. Over the last 30?years, several inn...

2011-01-01

270

Recent research efforts in the area of biotechnology for fuels and chemicals: Poster session papers  

Energy Technology Data Exchange (ETDEWEB)

This report presents research presented at the poster session of the Symposium covering a wide spectrum of current biotechnological research activities. Research focused mostly on ethanol production and methane generation from biomass material via microbial processing, as well as on enhanced hydrogen yield from algae. Several of the posters dealt with the pretreatment of cellulosic materials, and enzyme production/characterization, while a good number of papers displayed research efforts on bioremediation, photosynthesis, production of various useful chemicals from biomass by bioprocessing, and on other miscellaneous subjects. One of the papers treated a very interesting topic of cellulose-cellulase complexes. Many of the poster papers are included in this volume, and a synopsis of all the poster/papers presented is the subject of this article.

1992-01-01

271

Preparation and applications of novel fluoroalkyl end-capped vinyltrimethoxysilane oligomer/hydroxyapatite nanocomposites  

British Library Electronic Table of Contents (United Kingdom)

Novel fluoroalkyl end-capped vinyltrimethoxysilane oligomer/hydroxyapatite (HAp) nanocomposites were prepared by the reaction of calcium nitrate tetrahydrate and phosphoric acid in the presence of the corresponding oligomer. These fluorinated oligomer/HAp composites thus obtained are nanometer size-controlled fine particles (83-173 nm), and were found to exhibit good dispersibility in methanol, ethanol, and isopropyl alcohol. These fluorinated HAp nanocomposites were applied to the surface modification of glass and poly(methyl methacrylate) (PMMA) to exhibit good hydro- and oleophobic characteristics imparted by fluorine on their surface. In addition, the surface structural changes of the modified polyethylene terephtalate and PMMA films treated with these fluorinated nanocomposites before...

2009-01-01

272

Platinum-based ternary catalysts for low temperature fuel cells. Part 2. Electrochemical properties  

Energy Technology Data Exchange (ETDEWEB)

The development of high performance electrode materials is currently one of the main activities in the field of the low temperature fuel cells, fuelled with H{sub 2}/CO or low molecular weight alcohols. A promising way to attain higher catalytic performance is to add a third element to the best binary catalysts actually used as anode and cathode materials. In Part I of this review an overview of the preparation and structural characteristics of Pt-based ternary catalysts was presented. This part of the review deals with the electrochemical properties of these catalysts regarding their CO tolerance and electrocatalytic activity for methanol and ethanol oxidation in the case of anode materials, and their activity for oxygen reduction and stability in fuel cell conditions when used as cathode materials. (author)

2007-07-31

273

Nitrogen doping into titanium dioxide by the sol?gel method using nitric acid  

British Library Electronic Table of Contents (United Kingdom)

N-doped TiO2 has been prepared by use of sol?gel systems containing titanium alkoxide, with nitric acid as the nitrogen source. The time needed for gelation of the systems was drastically reduced by ultrasonic irradiation. The peaks assigned to the nitrate and nitrous ions were observed by FT-IR measurement during the sol?gel reaction. The N-doping was confirmed by the observation of N?O peaks in the XPS spectrum of the sample heated at 400??C. The nitrate ion acted as an oxidizer of the ethanol solvent and titanium species. The TiO2 became doped with nitrogen oxide species as a result of reduction of nitrate ion incorporated into the dried gel samples. These results indicated that the added nitric acid was reduced during the sol?gel transition and heating process, and the resulting NO spe...

2011-01-01

274

Nanostructured nickel ferrite: A liquid petroleum gas sensor  

British Library Electronic Table of Contents (United Kingdom)

The present investigation deals with the synthesis of nanostructured nickel ferrite (NiFe2O4) and their liquid petroleum gas-sensing characteristics. The 15-20nm size nickel ferrite has been synthesized at 700degreeC by a simple molten-salt route using sodium chloride as grain growth inhibitor. These nanoparticles exhibit significantly high response towards liquid petroleum gas (LPG) in comparison with ethanol vapor, hydrogen sulfide, ammonia and hydrogen. The gas response towards various gases at their 200ppm concentrations is investigated at 200-450degreeC. Different characterization techniques have been employed, such as differential thermal analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high resolution transmission elec...

2009-01-01

275

NONLINEAR OPTICAL PHENOMENA: Nonlinear optical properties of colloidal silver nanoparticles produced by laser ablation in liquids  

Science.gov (United States)

The optical and nonlinear optical properties of colloidal solutions of silver obtained by laser ablation in water and ethanol are studied. It is shown that freshly prepared colloids experience a full or partial sedimentation by changing their nonlinear optical properties. Aqueous colloids undergo a partial sedimentation and their nonlinear optical absorption changes to nonlinear optical transmission. The obtained results are interpreted using the Drude model for metal particles taking the particle size into account and can be explained by the sedimentation of larger silver particles accompanied by the formation of a stable colloid containing silver nanoparticles with a tentatively silver oxide shell. The characteristic size of particles forming such a stable colloid is determined and its optical nonlinearity is estimated.

2004-07-01

276

Large (≥2cm) non-hypervascular nodules depicted on MRI in the cirrhotic liver: fate and implications  

British Library Electronic Table of Contents (United Kingdom)

Aim To determine the fate and clinical implication of large (?2cm), non-hypervascular nodules depicted on magnetic resonance imaging (MRI) in the cirrhotic liver. Materials and methods In 21 patients with cirrhosis (14 hepatitis B, two ethanol abuse, four cryptogenic, one Wilson's disease), 25 large (?2cm in the longest dimension) non-hypervascular nodules were identified on dynamic MRI. The implications for diagnosis of the initial size, contour, and signal characteristics on MRI in addition to patients' age and cause of cirrhosis were assessed in our analysis. Results Twelve (75%) out of 16 lesions were malignant or potentially-malignant from 14 hepatitis B patients, while seven (78%) of the nine lesions from other patients were benign (p=0.016). The mean age of the patients who ha...

2008-01-01

277

Land use change in a biofuels hotspot: The case of Iowa, USA  

British Library Electronic Table of Contents (United Kingdom)

This study looks at the land use impact of the biofuels expansion on both the intensive and extensive margin, and its environmental consequences. We link economic, geographical and environmental models by using spatially explicit common units of analysis and use remote sensing crop cover maps and digitized soils data as inputs. Land use changes are predicted via economic analysis of crop rotation choice and tillage under alternative crop prices, and the Environmental Policy Integrated Climate (EPIC) model is used to predict corresponding environmental impacts. The study focuses on Iowa, which is the leading biofuels hotspot in the U.S. due to intensive corn production and the high concentration of ethanol plants that comprise 28% of total U.S. production. We consider the impact of the biof...

2011-01-01

278

Isoflavone content and apoptotic effect in HT-29 cancer cells of a soy germ extract  

British Library Electronic Table of Contents (United Kingdom)

Colon cancer is one of the leading causes of death and a major public health problem in western countries. We examined the isoflavone content of 70% ethanol extract of soy germ (SG) and its apoptotic effect in HT-29 colon cancer cells. Our results showed that the major isoflavones of the SG extract were daidzein and genistein, and it effectively induced apoptosis in HT-29 cancer cells. In addition, nuclear factor-kappa B (NF-kB) expression was reduced in cells treated with the SG extract, which reduced cyclooxygenase-2 (COX-2) and nitric oxide synthase (iNOS) expression. These combined effects ultimately resulted in apoptosis via caspase-3 activation. In addition, daidzein and genistein, the major isoflavones of SG extract, also exerted the apoptotic effect against HT-29 cancer cells. Thes...

2012-01-01

279

Improving acetic acid production of Acetobacter pasteurianus AC2005 in hawthorn vinegar fermentation by using beer for seed culture  

British Library Electronic Table of Contents (United Kingdom)

Summary Fruit vinegar can be obtained biologically from the fermentation of fruit wine using species of the genera Acetobacter. However, the productivity of vinegar is generally low because of the inhibition by substrate ethanol and product acetic acid. In this research, the yield of acetic acid, as well as the cell growth, in hawthorn vinegar fermentation was enhanced using beer for seed preparation. The higher yield of acetic acid of AC2005 was because of the higher alcohol dehydrogenase and aldehyde dehydrogenase activities caused by using beer for seed preparation. Furthermore, Acetobacter pasteurianus AC2005 showed acid stability during the fed batch fermentation of hawthorn vinegar.

2010-01-01

280

Gadolinium (III) chelates of O, N-donor Schiff bases derived from 2, 3-dimethyl-4-formyl-1-phenyl-3-pyrazoline-5-one and certain aromatic amines  

International Nuclear Information System (INIS)

New Schiff base chelating ligands were synthesized by reacting equimolar quantities of 2,3-dimethyl-4-formyl-1-phenyl-3-pyrazoline-5-one and o-anisidine, p-anisidine, m-anisidine, o-toluidine, p-toluidine, m-toluidine, 2,6-xylidine or 2,4-xylidine in ethanol medium. Their subsequent reaction with gadolinium (III) nitrate hexahydrate in 2:1 molar ratio gave complexes that were characterized by elemental analyses, molar conductances, magnetic measurements, electronic and I.R. spectral studies. All the chelates were found to be non-electrolytic in nature. (author). 15 refs., 1 fig., 1 tab.

1994-01-01

281

Flow cytometric analysis of respiratory tract cells exposed to oil shale and silica particulates. [Hamsters  

Science.gov (United States)

Flow cytometric techniques were used to measure the cytological and biochemical damage to respiratory tract cells in animals exposed to particulates. Hamsters were exposed to raw and spent oil shale particulates and silica by intratracheal instillation. Exfoliated lung cells were obtained by sacrificing the animals and lavaging the respiratory tract posterior to the trachea with saline. Cell samples were fixed in ethanol and stained with mithramycin for fluorescence analysis of DNA content. DNA content distributions from hamsters exposed to spent oil shale and silica particulates showed atypical changes 28 to 35 days later. Cell counts and total numbers of macrophages, leukocytes, and epithelial cells in the lavage fluid also showed marked changes related to time after exposure.

1979-01-01

282

Evaluation and optimization of organosolv pretreatment using combined severity factors and response surface methodology  

British Library Electronic Table of Contents (United Kingdom)

In this study, ethanol organosolv pretreatment was investigated and optimized for the pretreatment of empty palm fruit bunch using (1) response surface methodology based on three-variable central composite design and (2) the combined severity parameters. The reaction parameters studied were sulfuric acid concentration (0.5-2.0%), reaction temperature (160-200^oC) and residence time (45-90min). Both models provide valuable and complementary informations: using combined severity parameters, very good predictions were obtained concerning xylan and lignin extraction whereas central composite design is the best model for glucose production. The optimal values of the variables were as the followings: sulfuric acid 2.0% w/w, 160^oC, 78min and the experimental values (96.0%) concerning glucose and...

2011-01-01

283

Enhanced extraction yields and mobile phase separations by solvent mixtures for the analysis of metabolites in Annona muricata L. leaves  

British Library Electronic Table of Contents (United Kingdom)

The effects of five extraction solvents and their mixtures on the yield of metabolites in crude and fractionated extracts of Annona muricata L. leaves were investigated by direct comparison. Extraction media were prepared using simplex centroid mixtures of ethanol, ethyl acetate, dichloromethane, acetone, and chloroform. The effects of the mobile phase solvent strength and the analysis wavelength on the chromatographic separation were also investigated. Solvent mixtures rather than pure solvents were found to be the most efficient extractors for the different fractions. The results indicated that the mobile phase composed of methanol/acetonitrile/water (26:27:47 v/v/v) was most suitable for the basic fraction analysis at 254 nm, whereas the mobile phase composed of methanol/acetonitrile/wa...

2009-01-01

284

Energy recovery by production of fuel from citrus wastes  

Energy Technology Data Exchange (ETDEWEB)

A study to determine how much energy can be recovered from a Florida citrus processing plant was conducted. The production of ethyl alcohol in particular was examined as it is thought to represent the greatest potential for immediate energy recovery. Three-fourths of the energy expended to produce, harvest, process and market a box of fruit was recoverable using existing technology, i.e. 78,500 Btu/ box of fruit recoverable from a total energy expenditure of 107,800 Btu/ box of fruit. Aside from the actual cost benefits of recovering energy in the form of ethanol, the food processor is also helping to reduce the foreign-oil imports by the blending of ethyl alcohol with unleaded gasoline to form gasohol.

1982-05-01

285

Enantioselective separation of the carfentrazone-ethyl enantiomers in soil, water and wheat by HPLC  

British Library Electronic Table of Contents (United Kingdom)

A simple enantioselective HPLC method was developed for measuring carfentrazone-ethyl enantiomers. The separation and determination was accomplished on an amylose tris[(S)-a-methylbenzylcarbamate] (Chiralpak AS) column using n-hexane/ethanol (98:2, v/v) as mobile phase at a flow rate of 1.0 mL/min with UV detection at 248 nm. The effects of mobile-phase composition and column temperature on the enantioseparation were discussed. The accuracy, precision, linearity, LODs, and LOQ of the method were also investigated. LOD was 0.001 mg/kg in water, 0.015 mg/kg in soil and wheat, with an LOQ of 0.0025 mg/kg in water and 0.05 mg/kg in soil and wheat for each enantiomer of carfentrazone-ethyl. SPE was used for the enrichment and cleanup of soil, water, and wheat samples. Recoveries for two enantio...

2010-01-01

286

Development of a detailed kinetic model for gasoline surrogate fuels  

Energy Technology Data Exchange (ETDEWEB)

A detailed chemical kinetic model to describe the autoignition of gasoline surrogate fuels is presented consisting of the fuels iso-octane, n-heptane, toluene, diisobutylene and ethanol. Model predictions have been compared with shock tube ignition delay time data for surrogates of gasoline over practical ranges of temperature and pressure, and the model has been found to be sensitive to both changes in temperature and pressure. Moreover, the model can qualitatively predict the observed synergistic and antagonistic non-linear blending behaviour in motor octane number (MON) for different combinations of primary reference fuels (PRFs) and non-PRFs by correlating calculated autoignition delay times from peak pressures and temperatures in the MON test to experimental MON values. The reasons for the blending behaviour are interpreted in terms autoignition chemistry. 37 refs., 11 figs., 4 tabs.

2008-08-15

287

Cluster approach to quantum-chemical calculations of chemisorption and heterogeneous catalytic systems  

Energy Technology Data Exchange (ETDEWEB)

The increasing use of quantum-chemical methods in catalysis has underscored the importance of developing and improving semiempirical approximations oriented toward calculations of the total energy and geometry, offering a means for examining intermolecular interactions. In this article a general approach is proposed, using weighting factors for certain regions of distances, i.e., introducing different parametrization into the various regions. A scheme designated MINDO/3-HB is presented as an extension of the MINDO/3 scheme to the region of hydrogen bonds and ..pi..-complexes of olefins with Broensted acid centers (BACs). Examples of cluster calculations are given for the adsorption of ammonia, pyridine, ethylene, and ethanol on the BACs of zeolites. In the example of the process of zeolite synthesis, the possibilities of the cluster approach are discussed for calculations related to the formation of catalysts.

1987-07-01

288

Capsaicin-induced avoidance behavior in the terrestrial Gastropoda Megalobulimus abbreviatus: Evidence for TRPV-1 signaling and opioid modulation in response to chemical noxious stimuli  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to measure the nociceptive response (avoidance latency) of the land snail Megalobulimus abbreviatus (N=8 in each group) after topical capsaicin exposure (0.1% and 0.5% in 20% ethanol) and to compare it to a well-studied stressful (50??C) thermal stimulus model. We also tested if ruthenium red, and capsazepine, respectively nonselective and selective TRPV1 receptor antagonists, could modify both capsaicin- and thermal-evoked responses. Finally, animals were pretreated with morphine, naloxone or morphine plus naloxone prior to capsaicin stimuli. Latencies were measured when the animal lifted its head?foot complex 1?cm from the substrate. Data were compared using ANOVA and LSD post hoc, and the Student T Test (pM. abbreviatus.

2007-01-01

289

Biogenic methane from hydrothermal gasification of biomass; Biogenes Methan durch hydrothermale Vergasung von Biomasse  

Energy Technology Data Exchange (ETDEWEB)

This final report for the Swiss Federal Office of Energy (SFOE) reports on work done in the area of gasification of biomass. The use of dung, manure and sewage sludge as sources of energy is described and discussed. Hydrothermal gasification is proposed as an alternative to conventional gas-phase processes. The aim of the project in this respect is discussed. Here, a catalytic process that demonstrates the gasification of wet biomass to synthetic natural gas (SNG) in a continuously operating plant on a laboratory scale is being looked at. Difficulties encountered in preliminary tests are discussed. Long-term catalyst stability and the installations for the demonstration of the process are discussed, and gasification tests with ethanol are commented on.

2007-09-15

290

Bioconvertion of spent cellulose sausage casings  

British Library Electronic Table of Contents (United Kingdom)

Cellulose sausage cellulose casings are used extensively in the manufacture of sausages in meat packaging. After stripping the meat, spent casings mainly contain cellulose and residual meat juice with salt, nitrate and nitrite. Disposal of spent sausage casings has serious economic and environmental concerns for the sausage industry. This work describes bioconversion of spent cellulose casings (SCC) into enzymes, lactic acid and ethanol by using cellulolytic fungi, lactobacillus and yeasts. The solid substrate cultivation (SSC) of Trichoderma reesei RUT C-30 on SCC and blends gave a maximum of 152 filter paper cellulase (FPase) activity and about 100 carboxymethylcellulase activity (CMCase)/g dry weight substrate. The SSC produced enzyme-rich casing with 50 FPase when directly mixed as suc...

2008-01-01

291

A nontoxic antitumour compound from the leaves of Bauhinia scandens characterized as 1-O-alkyl glycerol by gas-liquid chromatography and evaluation of its antitumour property by Brine Shrimp bioassay  

British Library Electronic Table of Contents (United Kingdom)

This is a report of extraction and identification of 1-O-alkyl glycerol present in the dried leaves of Bauhinia scandens. Fifty percent aqueous ethanolic extract of the plant at room temperature was fractionated over petroleum ether and diethyl ether. The diethyl ether soluble fraction showed positive bioactivity in Brine Shrimp bioassay. Isolation and purification of the active principle was subsequently done from diethyl ether fraction. The diethyl ether fraction was separated into acidic and neutral part. The acid free fraction was screened to be positive in Brine Shrimp bioassay. The NMR spectra (in CDCl3) indicated the probability of its lipoidal nature. The total lipid fraction was resolved into neutral, glyco, and phospho-lipids by column chromatography. Only the neutral fraction sh...

2008-01-01

292

Research guidance studies. Quarterly progress report, April--June 1996  

Science.gov (United States)

The overall objective of this project is to provide research guidance and quantification of research progress in the areas of direct and indirect coal liquefaction, coal/waste coprocessing, refining of coal-derived liquid fuels, and natural gas conversion. Specifically, the work is divided into two subtasks that relate to whether the technology application is direct or indirect. In subtask (a), Direct Coal Liquefaction technology is the subject of the analyses, and in subtask (b), Indirect Liquefaction, technologies will be evaluated in accordance with the priorities of the COR. Mitretek Systems has been developing detailed computer simulation models of direct and indirect coal and natural gas conversion systems for several years. These models are constantly being updated and improved as more data and better cost information becomes available. These models also include detailed refinery models based on bench-scale upgrading data of coal derived liquid fuels to ...

1996-12-31

293

Isobutane/2-butene alkylation over potential heterogeneous catalysts in a slurry reactor  

Energy Technology Data Exchange (ETDEWEB)

The trend towards more effective use of fossil fuels and reduced environmental pollution represents a major task of improvement within the refinery processes. The highly isomerized and high octane paraffins produced from isobutane and light olefins by alkylation fulfill all the requirements for reformulated gasoline. This doctoral thesis discusses new catalyst systems because of their potential in alkylation. A slurry reactor apparatus for solid-acid catalysed isobutane/butene alkylation was developed and used to investigate the performance of various heterogeneous catalysts. The selected materials were mainly zeolite types with faujasite structures. The samples were characterized by various methods before alkylation. In general, the order of decreasing catalyst activity after 3 h of reaction at 80{sup o}C was found to be: H-EMT >> H-FAU, dealuminated H-FAU >> NS.500, TA-Y, CeY-98 > Nafion-H. The order of decreasing alkylate selectivity of the ...

1996-12-31

294

Conversion of heavy aromatic hydrocarbons to valuable synthetic feed for steamcrackers  

Energy Technology Data Exchange (ETDEWEB)

The scope of the present study was upgrading a set of heavy aromatic hydrocarbons mixtures whose commercial value ranks close to fuel oil and should become even lower in the next future because of the introduction of more stringent regulations on fuels, through hydro-conversion to a synthetic feed for steam-cracking. The resulting process provides an opportunity to improve the economic return of a steamcracking plant, offering the chance of converting low-value mixtures produced by the plant itself, such as fuel oil of cracking (FOK), saving an equivalent amount of naphtha. The method can also be used for converting pyrolysis gasoline (pygas). Although pygas has at present a fair commercial value, it could suffer a significant penalization in the future due to further limitations on total aromatic content in gasoline. Pygas hydro-conversion to a synthetic steam-cracking feedstock has been recently reported. Fractions from refinery, such as heavy distillates (e.g. ...

2007-07-01

295

Analysis of acidic compound classes in crude oil by negative ion electrospray ionization high resolution FT-ICR mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

Acidic constituents in crude oil are associated with the formation of stable emulsions during production and present a challenge for efficient oil recovery and processing. Acid molecules, including naphthenic acids and acidic sulfur in crude oil cause corrosion in refineries and pipelines. Naphthenic acids are also significant because of their surface activity and marginal water solubility, so that they may leach to wastewaters and cause adverse environmental effects. Acidic components of oil are not limited to carboxylic acids but also molecules that contain sulfur and nitrogen. As such, an improved understanding of the chemistry and physics of petroleum at the molecular level is needed in order to understand the range of problems associated with acidic oil components and to design better solutions. The applications of negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for speciation of acidic oil ...

2008-07-01

296

Air quality monitoring Lloydminster area : 2002, 2003 and 2004 seasonal monitoring : final report  

Energy Technology Data Exchange (ETDEWEB)

As part of its air quality monitoring activities, Alberta Environment conducts unannounced mobile air quality surveys each year using the Department's Mobile Air Monitoring Laboratory (MAML). This laboratory provides a snapshot of the air quality at the location monitored for a particular time and space. The MAML measures several pollutants in the air including ammonia, carbon monoxide, hydrocarbons, oxides of nitrogen, ozone, particulate matter, reduced sulphur compounds and sulphur dioxide. Alberta Environment conducted a series of ambient air quality monitoring surveys in the Lloydminster Area in 2002, 2003 and 2004. This report presents the results of the five monitored locations over eight seasons of monitoring, which were selected in consultation with stakeholders and staff from Alberta Environment's Central Region office. Canister samples were also collected during these surveys for later laboratory analyses of volatile organic compounds. Results from other ...

2005-11-01

297

A laboratory and field investigation of naphthenic acid corrosion inhibition  

Energy Technology Data Exchange (ETDEWEB)

This paper presents results of a laboratory and field study of naphthenic acid corrosion and the development of an effective chemical inhibitor for this type of corrosive attack. In the laboratory corrosion test, which involved 20 hour weight loss measurements in high flash solvent with a total acid number (TAN) of 16 mg KOH/gm at a temperature of 600 F (316 C), blank corrosion rates averaged 140 to 150 mpy (3.56 to 3.81 mm/y). Inhibited rates averaged about 10 to 12 mpy (0.254 to 0.305 mm/y). The field test was carried out on a heavy vacuum gas oil (HVGO) stream at 550 F (288 C) . Blanks varied from a high of 425 mpy (10.79 mm/y) for a 24 hour test to a low of about 100 mpy (2.54 mm/y) for a 150 hour test. Both electrical resistance (ER) probes and weight loss coupons showed corrosion rates below 5 mpy (0.127 mm/y) as long as they were adequately passivated. Passivation consisted of exposing the coupons to a high inhibitor dosage for a relatively short time to establish a protective ...

1995-11-01

298

White River Falls Fish Passage Project, Tygh Valley, Oregon : Final Technical Report, Volume III, Appendix B, Fisheries Report; Appendix C, Engineering Alternative Evaluation; Appendix D, Benefit/Cost Analysis.  

Energy Technology Data Exchange (ETDEWEB)

Studies were conducted to describe current habitat conditions in the White River basin above White River Falls and to evaluate the potential to produce anadromous fish. An inventory of spawning and rearing habitats, irrigation diversions, and enhancement opportunities for anadromous fish in the White River drainage was conducted. Survival of juvenile fish at White River Falls was estimated by releasing juvenile chinook and steelhead above the falls during high and low flow periods and recapturing them below the falls in 1983 and 1984. Four alternatives to provide upstream passage for adult salmon and steelhead were developd to a predesign level. The cost of adult passage and the estimated run size of anadromous fish were used to determine the benefit/cost of the preferred alternative. Possible effects of the introduction of anadromous fish on resident fish and on nearby Oak Springs Hatchery were evaluated. This included an inventory of resident species, a genetic study of native ...

1985-06-01

299

Transport of a power plant tracer plume over Grand Canyon National Park  

Energy Technology Data Exchange (ETDEWEB)

Meteorological and air-quality data, as well as surface tracer concentration values, were collected during 1990 to assess the impact of Navajo Generating Station (NGS) emissions on Grand Canyon National Park (GCNP) air quality. These data have been used in the present investigation to determine between direct and indirect transport routes taken by the NGS plume to produce measured high-tracer concentration events at GCNP. Results show that complex-terrain features affect local wind-flow patterns during winter in the Grand Canyon area. Local channelling, decoupled canyon winds, and slope and valley flows dominate in the region when synoptic systems are weak. Direct NGS plume transport to GCNP occurs with northeasterly plume-height winds, while indirect transport to the park is caused by wind direction shifts associated with passing synoptic systems. Calculated polluted airmass positions along the modeled streak lines match measured surface-tracer observations in ...

1999-08-01

300

Temperature histories in geothermal wells: survey of rock thermomechanical properties and drilling, production, and injection case studies  

Energy Technology Data Exchange (ETDEWEB)

Thermal and mechanical properties for geothermal formations are tabulated for a range of temperatures and stress conditions. Data was obtained from the technical literature and direct contacts with industry. Thermal properties include heat capacity, conductivity, and diffusivity. Undisturbed geothermal profiles are also presented. Mechanical properties include Youngs modulus and Poisson ratio. GEOTEMP thermal simulations of drilling, production and injection are reported for two geothermal regions, the hot dry rock area near Los Alamos and the East Mesa field in the Imperial Valley. Actual drilling, production, and injection histories are simulated. Results are documented in the form of printed GEOTEMP output and plots of temperatures versus depth, radius, and time. Discussion and interpretation of the results are presented for drilling and well completion design to determine: wellbore temperatures during drilling as a function of depth; bit temperatures over the ...

1981-07-01

301

Techno-economic assessment of anaerobic digestion systems for agri-food wastes  

Energy Technology Data Exchange (ETDEWEB)

Activities in British Columbia's Fraser Valley generate an estimated 3 million tones of agriculture and food wastes annually, of which 85 per cent are readily available for anaerobic digestion. The potential for energy generation from biogas through anaerobic digestion is approximately 30 MW. On-farm manure-based systems represent the most likely scenario for the development of anaerobic digestion in British Columbia in the near future. Off-farm food processing wastes may be an alternative option to large centralized industrial complexes. Odour control, pathogen reduction, improved water quality, reduced greenhouse gas emissions and reduced landfill usage are among the environmental benefits of anaerobic digestion. The economical benefits include power and heat generation, biogas upgrading, and further processing of the residues to produce compost or animal bedding. This paper described a newly developed anaerobic digestion (AD) calculator that helps users ...

2010-07-01

302

Shallow hydrothermal regime of the East Brawley and Glamis known geothermal resource areas, Salton Trough, California  

Energy Technology Data Exchange (ETDEWEB)

Thermal gradients and thermal conductivities were obtained in real time using an in situ heat-flow technique in 15 shallow (90 to 150 m) wells drilled between Brawley and Glamis in the Imperial Valley, Southern California. The in situ measurements were supplemented by follow-up conventional temperature logs in seven of the wells and by laboratory measurements of thermal conductivity on drill cuttings. The deltaic sedimentary material comprising the upper approx. 100 m of the Salton Trough generally is poorly sorted and high in quartz resulting in quite high thermal conductivities (averaging 2.0 Wm/sup -1/ K/sup -1/ as opposed to 1.2 to 1.7 for typical alluvium). A broad heat-flow anomaly with maximum of about 200 mWm/sup -2/ (approx. 5 HFU) is centered between Glamis and East Brawley and is superimposed on a regional heat-flow high in excess of 100 mWm/sup -2/ (> 2.5 HFU). The heat-flow high corresponds with a gravity maximum and partially with a minimum in ...

1981-01-01

303

Regulation of agricultural drainage to San Joaquin River  

Science.gov (United States)

A technical committee reported on: (1) proposed water quality objectives for the San Joaquin River Basin; (2) proposed effluent limitations for agricultural drainage discharges in the basin to achieve these objectives; and (3) a proposal to regulate these discharges. The costs and economic impact of achieving various alternative water quality objectives were also evaluated. The information gathered by the technical committee will be used by the Regional Board along with other information in their review of the San Joaquin River Basin Water Quality Control Plan and their actions to regulate agricultural drainage in the San Joaquin Valley. The results of the Technical Committee's efforts as reported in Regulation of Agricultural Drainage to the San Joaquin River, August 1987. Based on the available information, the improvement in water quality resulting from implementation of the interim selenium objective and long-term objectives for salts, molybdenum and ...

1989-02-01

304

Performance evaluation of corrosion probes in simulated WVNS tank 8D-2 waste: WVNS tank farm process support  

Energy Technology Data Exchange (ETDEWEB)

Five corrosion probes were received from West Valley Nuclear Services for evaluation in simulated tank 8D-2 3rd-stage sludge wash slurry. The same waste slurry simulated was also used in a series of ongoing corrosion studies assessing the effects of in-tank sludge washing on the integrity of tank 8D-2. Two of the corrosion probes were installed in the coupon corrosion test vessels operating at {approximately}150{degrees}F to compare performance of the probes with that observed by coupon tests conducted in the same vessels. Corrosion rate data calculated from electrical resistance measurements of the corrosion probes were evaluated for this study using two slightly different approaches. One approach uses the total length of exposure of the probe to give a ``time-averaged`` value of the corrosion rate. The other approach uses a shorter period of time (relative to the length of the test) in the calculation of corrosion rate, and is referred to as the ``instantaneous`` ...

1994-07-01

305

Nonlinear dynamic analysis of pipe whip tests. Final report  

Energy Technology Data Exchange (ETDEWEB)

This is a numerical verification of two groups of pipe whip tests sponsored or cosponsored by EPRI. Experimental data of the two pipe whip tests, one by Tennessee Valley Authority (TVA) and by FRAMATOME/CEA, were provided by EPRI. A nonlinear finite element code, ABAQUS-EPGEN, developed under partial sponsorship by EPRI was used for modeling the pipe whip tests. Beam elements together with an equivalent nonlinear spring element or a partial shell mesh were used to model pipes and elbow in the pipe whip tests. Material nonlinearity due to plasticity, strain rate effects, and temperature, as well as geometric nonlinearity due to large rotation and boundary conditions were included in the study. Effects of strain rate and modeling techniques were assessed. Results by current industry approach were also included as a reference solution. This report can be used as a guideline for numerical simulation of pipe whip phenomena. 74 figs.

1986-05-01

306

Monitoring the Effect of Longwall Mining on Agricultural Environments - Interim Report  

Energy Technology Data Exchange (ETDEWEB)

The project was designed to quantify the impacts of longwall mine subsidence (LWMS) on the production and quality of agricultural vegetated environments. This project utilised a variety of traditional ground based sampling techniques including biomass harvests and estimates, leaf area index (LAI), pasture height, species composition and soil sampling along with proximal sensor data capture using a Crop Circle{trademark} and an EM38. Satellite imagery was collected using the Quickbird satellite and the high resolution imagery was used to monitor large areas of LWMS affected areas and adjacent un-mined land. Two landscapes were investigated using a whole of mine site technique including remote sensing, ground survey and traditional agricultural monitoring methods. The landscapes were at the Kestrel site in Emerald, QLD including a forage sorghum and an improved pasture and at Beltana in the Hunter Valley, NSW including an irrigated lucerne pasture and an unimproved ...

2009-06-15

307

Molecular epidemiology of childhood leukemia with emphasis on chemical exposures  

Energy Technology Data Exchange (ETDEWEB)

Developing markets in the Pacific Basin depend heavily on the production and export of consumer goods. The generation of hazardous waste as a by-product of industrial production can be linked to adverse health outcomes, such as childhood leukemia, in ways that are presently unknown. In California, exposures resulting from hazardous waste disposal are of concern in the etiology of childhood cancer. Approximately 63% of the 57 hazardous waste sites that the U.S. Environmental Protection Agency (USEPA) included in the national priority list under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) statute were in the six-county San Francisco Bay area. This area includes California`s Silicon Valley, where a disproportionate majority of these sites are located. Although only one study links hazardous waste disposal to childhood leukemia evidence is accumulating that in utero and maternal pesticide exposures as well as chemical exposures ...

1996-12-31

308

Low-temperature properties of ternary magnetic rare-earth transition-metal germanides with the Sc sub 5 Co sub 4 Ge sub 10 -type structure  

Energy Technology Data Exchange (ETDEWEB)

DC resistivity, dc magnetization, and specific heat of eight Sc{sub 5}Co{sub 4}Ge{sub 10}-type crystal-structure compounds R{sub 5}T{sub 4}Ge{sub 10} for R = Dy, Ho, Er, Tm, and T = Rh and Ir are presented. The resistivity, single-crystal magnetization, and specific-heat results show that in all those compounds, the magnetic moments order antiferromagnetically in the c direction at low temperature. However, in the Er and Tm compounds, the magnetizations along x-y hard directions do not show any anomalies above 2.0 K. This suggests that the ordered Er and Tm ions, which have positive quadrupole coefficients, interact with a crystal field that has an electronic potential valley along the c axis. The fitting of the hard axis magnetizations to Curie-Weiss law suggests that the resulting antiferromagnetic-like {theta} reflects the strength of the crystal-field torque on the magnetic moments rather than the strength of antiferromagnetic exchange.

1988-01-01

309

Low-Cost, Robust, Threat-Aware Wireless Sensor Network for Assuring the Nation's Energy Infrastructure  

Energy Technology Data Exchange (ETDEWEB)

Eaton, in partnership with Oak Ridge National Laboratory and the Electric Power Research Institute (EPRI) has completed a project that applies a combination of wireless sensor network (WSN) technology, anticipatory theory, and a near-term value proposition based on diagnostics and process uptime to ensure the security and reliability of critical electrical power infrastructure. Representatives of several Eaton business units have been engaged to ensure a viable commercialization plan. Tennessee Valley Authority (TVA), American Electric Power (AEP), PEPCO, and Commonwealth Edison were recruited as partners to confirm and refine the requirements definition from the perspective of the utilities that actually operate the facilities to be protected. Those utilities have cooperated with on-site field tests as the project proceeds. Accomplishments of this project included: (1) the design, modeling, and simulation of the anticipatory wireless sensor network (A-WSN) that ...

2007-03-31

310

Low temperature properties of ternary magnetic rare earth transition metal germanides with the Sc/sub 5/Co/sub 4/Ge/sub 10/-type structure  

Energy Technology Data Exchange (ETDEWEB)

DC resistivity, dc magnetization, and specific heat of eight Sc/sub 5/Co/sub 4/Ge/sub 10/-type crystal structure compounds R/sub 5/T/sub 4/Ge/sub 10/ for R = Dy, Ho, Er, Tm, and T = Rh and Ir are presented. The resistivity, single crystal magnetization, and specific heat results show that in all those compounds, the magnetic moments order antiferromagnetically in the c direction at low temperature. However, in the Er and Tm compounds, the magnetizations along x-y hard directions do not show any anomalies above 2.0 K. This suggests that the ordered Er and Tm ions, which have positive quadrupole coefficients ..cap alpha../sub j/, interact with a crystal field that has an electronic potential valley along the c axis. The fitting of the hard axis magnetizations to Curie-Weiss law suggests that the resulting antiferromagnetic-like theta reflects the strength of the crystal field torque on the magnetic moments rather than the strength of antiferromagnetic exchange. 123 ...

1988-07-01

311

Local and regional ozone production: Chemistry and transport  

International Nuclear Information System (INIS)

The EUROTRAC sub-project ''Tropospheric Ozone Research'' (TOR) follows a dual strategy: - Observation of the chemical processes contributing to the oxygen balance directly in the atmosphere; - Establishment of a validated data base for model calculations. Both tasks require simultaneous measurements of a wide range of chemical and meteorological components. In the case of the investigation of the chemical processes, it is also desirable to measure the free radicals directly involved in ozone production. In the project described, a measuring station was set up. For a period of two years and a half, continuous measurements were made of ozone and its chemical precursors (NO, NO_2, NO_y, VOC, CO), as well as other photooxidants (H_2O_2 and organic hydroperoxides, organic nitrates), the photolysis frequency of NO_2, and meteorological parameters (wind, temperature, moisture, aerosols). The station was located on the Schauinsland mountain in the southern Black Forest, at the edge of the ...

312

Ion exchange at TNX using the SKID unit  

Energy Technology Data Exchange (ETDEWEB)

An ion exchange unit has been manufactured for WSRC by British Nuclear Fuels, Ltd. This unit consists of three columns, ancillary valving, pumps, lines, and computer controls. It has been delivered to TNX for use in testing a cesium-specific ion exchange resin, developed at WSRC as a potential second generation process for the decontamination of Defense Waste Processing Facility (DWPF) supernate. This resin also has Department of Energy applications at both Oak Ridge and Hanford. Oak Ridge is interested in decontaminating the Melton Valley storage tank supernate, while Hanford is interested in decontaminating the 101-AW and 101-SY supernate streams. Another potential developmental interest is the Savannah River Site (SRS) DWPF recycle stream. The three primary waste streams of interest are the Oak Ridge, Hanford, and SRS, SWPF supernate streams. For these three waste streams, the cesium decontamination factor (DF) will be measured for a non-radioactive, simulated, ...

1993-10-21

313

Integrated model of the shallow and deep hydrothermal systems in the East Mesa area, Imperial Valley, California  

Energy Technology Data Exchange (ETDEWEB)

Geological, geophysical, thermal, petrophysical and hydrological data available for the East Mesa hydrothermal system that are pertinent to the construction of a computer model of the natural flow of heat and fluid mass within the system are assembled and correlated. A conceptual model of the full system is developed and a subregion selected for quantitative modeling. By invoking the Boussinesq approximation, valid for describing the natural flow of heat and mass in a liquid hydrothermal system, it is found practical to carry computer simulations far enough in time to ensure that steady-state conditions are obtained. Initial calculations for an axisymmetric model approximating the system demonstrate that the vertical formation permeability of the deep East Mesa system must be very low (k/sub v/ approx. 0.25 to 0.5 md). Since subsurface temperature and surface heat flow data exhibit major deviations from the axisymmetric approximation, exploratory three-dimensional calculations are ...

1982-01-01

314

Deep Heat Mining Project - Technical report on the Otterbach 2 geothermal test borehole in Basel; Technischer Bericht Geothermie-Sondierbohrung Otterbach 2, Basel  

Energy Technology Data Exchange (ETDEWEB)

This report for the Swiss Federal Office of Energy (SFOE) describes the borehole that has been driven into the underlying crystalline rock of the Rhine valley near Basle. This work has been carried out within the framework of the 'Deep Heat Mining' project. The 2,755 metre deep borehole provides geological information essential for the realisation of a proposed geothermal power station using the 'Hot Dry Rock' process. The boring of the test borehole is described. The results obtained from samples taken from the test borehole and the measurements made in it are presented, including details on geological formations, temperature, gas measurements and rock strain values. The author is of the opinion that the chances of finding temperatures of at least 200 {sup o}C in a depth of 5 km - as foreseen in the 'Deep Heat Mining' project - can be considered as being quite high.

2001-07-01

315

Comparison of digital and analogue data acquisition systems for nuclear spectroscopy  

International Nuclear Information System (INIS)

In the present investigation the performance of digital data acquisition (DA) and analogue data acquisition (AA) systems are compared in neutron-induced fission experiments. The DA results are practically identical to the AA results in terms of angular-, energy- and mass-resolution, and both compare very well with literature data. However, major advantages were found with the digital techniques. DA allows for a very efficient #alpha#-particle pile-up correction. This is important when considering the accurate measurement of fission-fragment characteristics of highly #alpha#-active actinide isotopes relevant for the safe operation of Generation IV reactors and the successful reduction of long-lived radioactive nuclear waste. In case of a strong #alpha#-emitter, when applying the #alpha#-particle pile-up correction, the peak-to-valley ratio of the energy distribution was significantly improved. In addition, DA offers a very flexible expanded off-line analysis and ...

2010-12-21

316

Batch test equilibration studies examining the removal of Cs, Sr, and Tc from supernatants from ORNL underground storage tanks by selected ion exchangers  

Energy Technology Data Exchange (ETDEWEB)

Bench-scale batch equilibration tests have been conducted with supernatants from two underground tanks at the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to determine the effectiveness of selected ion exchangers in removing cesium, strontium, and technetium. Seven sorbents were evaluated for cesium removal, nine for strontium removal, and four for technetium removal. The results indicate that granular potassium cobalt hexacyanoferrate was the most effective of the exchangers evaluated for removing cesium from the supernatants. The powdered forms of sodium titanate (NaTiO) and cystalline silicotitanate (CST) were superior in removing the strontium; however, for the sorbents of suitable particle size for column use, titanium monohydrogen phosphate (TiHP {phi}), sodium titanate/polyacrylonitrile (NaTiO-PAN), and titanium monohydrogen phosphate/polyacrylonitrile (TiP-PAN) gave the best results and were about equally effective. ...

1995-06-01

317

Basin-wide architecture of sandstone reservoirs in the Fort Union Formation, Wind River basin, Wyoming  

Energy Technology Data Exchange (ETDEWEB)

Architecture of hydrocarbon-bearing sandstone reservoirs of the Paleocene Fort Union Formation in the Wind River basin, Wyoming, was studied using lithofacies, grain size, bounding surfaces, sedimentary structures, internal organization, and geometry. Two principal groups of reservoirs, both erosionally based and fining upward, consist of either conglomeratic sandstone or sandstone lithofacies. Two types of architecture were recognized in conglomeratic sandstone reservoirs: (1) heterogeneous, multistacked, lenticular and (2) homogeneous, multiscoured, wedge-sheet bodies. Three types of architecture were recognized in sandstone reservoirs: (3) heterogeneous, multistacked, elongate; (4) homogeneous, multilateral, lenticular; and (5) homogeneous, ribbon-lensoid bodies. Conglomeratic sandstone reservoirs in the southern and southwestern parts of the basin suggest deposition in gravel-bedload fluvial systems influenced by provenance uplift of the Granite and southern Wind River mountains. ...

1991-06-01

318

Analysis of organizational options for the uranium enrichment enterprise in relation to asset divesture  

International Nuclear Information System (INIS)

This report presents a comparison of the characteristics of some prominent examples of independent government corporations and agencies with respect to the Department of Energy's (DOE) uranium enrichment enterprise. The six examples studied were: the Bonneville Power Administration (BPA); the Tennessee Valley Authority (TVA); the Synthetic Fuels Corporation (SYNFUELS); the Consolidated Rail Corporation (CONRAIL); the British Telecommunications Corporation (British TELECOM); and the Communications Satellite Organization (COMSAT), in order of decreasing levels of government ownership and control. They range from BPA, which is organized as an agency within DOE, to COMSAT, which is privately owned and free from almost all regulations common to government agencies. Differences in the degree of government involvement in these corporations and in many other characteristics serve to illustrate that there are no accepted standards for defining the characteristics of ...

319

Anaerobic degradation of DCM diffusing through clay  

Energy Technology Data Exchange (ETDEWEB)

Two series of diffusion tests were performed to examine the degradation of dichloromethane (DCM) as it diffuses through clay. The first series showed the use of a synthetic leachate with no significant initial bacterial population diffusing through a plug of intact clay; there was an induction period of 95--135 d, during which diffusion was as expected in the absence of degradation, followed by a second stage, where degradation occurred with an apparent half-life of less than 55 d at a temperature of 24 C. The second series of tests examined the diffusion of an actual leachate from the Keele Valley Landfill (KVL) (which provided both nutrients and a source of bacteria), through a compacted clay. In these tests, the induction period was reduced to 40--60 d, after which the apparent half-life was 20 d or less at 27 C. The diffusion coefficient for DCM was approximately 8 {times} 10{sup {minus}10} m{sup 2}/s, with partitioning coefficient K{sub d} = 1.5 cm{sup 3}/g. ...

1997-12-01

320

#beta#-sialon via carbothermal reduction using brown coal  

International Nuclear Information System (INIS)

There has been a good deal of interest in the sialon system of ceramics in recent years due to their combination of important engineering properties #beta# including strength, hardness, low thermal expansion and good thermal shock resistance. #beta#-sialon (Si_6_-_zAl_zO_zN_8_-_z ;0Valley provided a novel and reactive source of carbon for the current investigation. This paper looks at the mechanisms of formation of #beta#-sialon via the carbothermal reduction route and reports specifically on the utilisation of "2"9Si and "2"7Al solid state Nuclear Magnetic Resonance techniques in determining the nature of intermediate phases which occur. 9 refs., 1 tab., 1 fig.

321

Vulnerability of soil resources to heavy metals contamination in Central Bekaa-Lebanon  

International Nuclear Information System (INIS)

Full text.Changes in land use and urbanization yield more pressure put on limited soil and water resources, including the risk of pollution with toxic heavy metals. The study area lies in the Bekaa valley totaling about 12753 ha. The valley receives from the west torrential fan deposits and a mixture of colluvial and alluvial material. The principal soil classes are Fluvisols, Cambisols, Regosols, Vertisols and Luvisols. The area is populated and also the most important agricultural part of the plain. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. The western surrounding area is being used mainly for terraced fruit trees. This Arab-German Technical Cooperation Project (ACSAD-BGR) aimed, following the ISO standards and Eikman-Klocke recommendations, at investigating the nature of the extends of soil pollution by heavy metals in two pilot areas: The central Bekaa-Lebanon and Ghouta-Damascus. Different ...

2000-11-23

322

Trends and Controls on Summer Surface-Water Temperatures in Salmonid-Bearing Headwater Streams in Two Common Geomorphic Settings, Kenai Peninsula, Alaska  

Science.gov (United States)

Stream temperature is an important physical characteristic of headwater streams that plays a critical role in the presence and health of juvenile salmonids. Headwater stream temperature was documented in two geomorphic settings on the Kenai Peninsula, Alaska, focusing on the variation in temperature induced by diffuse groundwater discharge and variable air temperature. Eighteen headwater stream reaches were studied in four watersheds, with 11 drainageway sites and seven discharge-slope sites. In drainageway sites, low-gradient streams flow through broad valleys with groundwater-fed fen wetlands; in discharge-slope sites, high-gradient streams flow through narrow valleys with groundwater-fed slope wetlands. At all 18 sites, hourly stream temperatures were measured for one year. At one drainageway and one discharge-slope site, groundwater temperatures, stream stages, and groundwater heads in the local groundwater flow systems were also measured ...

2010-12-01

323

Study on bubbly flow behavior in natural circulation reactor by thermal-hydraulic simulation tests with SF6-Gas and ethanol liquid  

Science.gov (United States)

An advanced experimental technique has been developed to simulate two-phase flow behavior in a light water reactor (LWR). The technique applies three kinds of methods; (1) use of sulfur-hexafluoride (SF6) gas and ethanol (C2H5OH) liquid at atmospheric temperature and a pressure less than 1.0MPa, where the fluid properties are similar to steam-water ones in the LWR, (2) generation of bubble with a sintering tube, which simulates bubble generation on heated surface in the LWR, (3) measurement of detailed bubble distribution data with a bi-optical probe (BOP), (4) and measurement of liquid velocities with the tracer liquid. This experimental technique provides easy visualization of flows by using a large scale experimental apparatus, which gives three-dimensional flows, and measurement of detailed spatial distributions of two-phase flow. With this technique, we have carried out experiments simulating two-phase flow behavior in a single-channel geometry, a ...

2009-02-01

324

Pyridostigmine bromide modulates the dermal disposition of [14C]permethrin.  

Science.gov (United States)

The cause of the Gulf War Syndrome may be related to soldiers being exposed to insecticides (e.g., permethrin (P)), insect repellents (e.g., N,N-diethyl-m-toluamide (DEET)), an organophosphate nerve agent simulant (e.g., diisopropyl fluorpohosphate (DFP)), and/or prophylactic treatment (e.g., pyridostigmine bromide (PB)) against potential nerve gas attacks. The purpose of this study was to assess the dermal disposition of [14C]permethrin in ethanol or ethanol:water (3:2) in the isolated perfused porcine skin flap (IPPSF) model with simultaneous dermal exposure to DEET or DFP. These IPPSFs were also simultaneously perfused arterially with or without PB, DFP, or DFP + PB. The results indicated that DFP + PB significantly increased [14C]permethrin absorption compared to controls (1.06% dose vs 0.14% dose). PB significantly increased [14C]permethrin disposition in the stratum corneum (SC) in aqueous mixtures only (9.40 vs 3.35% dose), while topical ...

2002-06-15

325

Life-cycle assessment of straw use in bio-ethanol production: A case study based on biophysical modelling  

Energy Technology Data Exchange (ETDEWEB)

Cereal straw, a by-product in the production of agricultural crops, is considered as a potentially large source of energy supply with an estimated value of 47 x 10{sup 18} J worldwide. However, there is some debate regarding the actual amounts of straw which could be removed from arable soils without jeopardizing their quality, as well as the potential trade-offs in the overall straw-to-energy chain compared to the use of fossil energy sources. Here, we used a deterministic model of C and N dynamics in soil-crop systems to simulate the effect of straw removal under various sets of soil, climate and crop management conditions in northeastern France. Model results in terms of nitrate leaching, soil C variations, nitrous oxide and ammonia emissions were subsequently inputted into the life-cycle assessment (LCA) of a particular bio-energy chain in which straw was used to generate heat and power in a plant producing bio-ethanol from wheat grains. Straw removal had ...

2008-05-15

326

Hydrogen generation via alcoholysis reaction using ball-milled Mg-based materials  

Energy Technology Data Exchange (ETDEWEB)

An investigation on the hydrogen generation by reacting ball-milled Mg-based materials in different alcoholic solutions (methanol, ethanol, 2-propanol) was performed. The MgH{sub 2} reactivity in methanol is very low (maximum conversion yield <10%) and no improvement is induced by the ball milling treatment. In contrast, the ball milling affects greatly the Mg reactivity in methanol. The Mg powder milled for 30min displays a maximum conversion yield of 47% compared to 3% for unmilled Mg powder. Its high reactivity is ascribed to the creation of numerous defects and fresh surfaces during the initial stage of the milling process, favoring the corrosion of Mg in methanol. In addition, the presence of water in the methanol solution inhibits drastically the alcoholysis reaction despite its low amount (0.3vol%). The higher hydrogen production is obtained with the composite Mg-10at% Ni milled for 30min leading to a conversion yield of 70% after 45min of reaction in ...

2006-08-15

327

Emission control cost-effectiveness of alternative-fuel vehicles  

Energy Technology Data Exchange (ETDEWEB)

Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquefied petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide, nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs. Emission control cost-effectiveness presented in dollars per ton of emission reduction was calculated for each alternative-fuel vehicle types ...

1993-06-14

328

Effect of safe environmental pre and post harvest treatments and irradiation on handling of some fruits  

International Nuclear Information System (INIS)

The present study was carried out during two successive seasons of 2005 and 2006 seasons on"Montakhab El-Kanater"guavas and"Hachiya"persimmons.two different experiments were studied, the first one for pre harvest and second post harvest. Regarding pre harvest experiment,hand or chemical flower thinning by urea or ethrel and date of fruit picking (maturity) were evaluated on both guavas and persimmons.All flower thinning treatments increased fruit set,total yield,average fruit weight and decreased fruit abscission.However,a great effect on fruit quality and chemical compositions were also found with flower thinning treatments. Chemical flower thinning was more effective than hand thinning in improving yield and quality in "Montakhab El-Kanater"guavas and "Hachiya"persimmons. However,early maturation(120 and 150 days for guava and persimmon respect.) produced poor fruit quality.Whereas, medium maturity(130 and 180 days for guava and persimmon respect.) produced fruit with high ...

329

Bio-fuels for the gas turbine: A review  

International Nuclear Information System (INIS)

Due to depletion of fossil fuel, bio-fuels have generated a significant interest as an alternative fuel for the future. The use of bio-fuels to fuel gas turbine seems a viable solution for the problems of decreasing fossil-fuel reserves and environmental concerns. Bio-fuels are alternative fuels, made from renewable sources and having environmental benefit. In recent years, the desire for energy independence, foreseen depletion of nonrenewable fuel resources, fluctuating petroleum fuel costs, the necessity of stimulating agriculture based economy, and the reality of climate change have created an interest in the development of bio-fuels. The application of bio-fuels in automobiles and heating applications is increasing day by day. Therefore the use of these fuels in gas turbines would extend this application to aviation field. The impact of costly petroleum-based aviation fuel on the environment is harmful. So the development of alternative fuels in aviation is important and useful. ...

2010-12-01

330

Development of a production technology for PbSnCaAl alloys for batteries  

Energy Technology Data Exchange (ETDEWEB)

A new generation of lead alloys for making lead batteries is being introduced in highly developed countries. A very important characteristic of these alloys is the presence of Ca, Al and Sn. Such alloys have the property of stabilizing the amount of gas emitted as a result of the decomposition of the electrolyte on the level of pure lead i.e. significantly smaller than lead alloys containing Se e.g. PbSb 1.7Se. Such alloys have not been produced in Poland so far. - In this paper we are presenting the method and equipment used to produce a pilot portion of PbSnCaAl alloy (mass approximately 80 Mg) on an industrial scale at HMN ''Szopienice'' S.A. lead refinery. We also present the results of the tests regarding the chemical homogeneity of the alloy produced, as well as its structural and casting properties. On the basis of the tests conducted it has been found that the method is industrially adequate and as such it has been ...

2000-07-01

331

Total phenolics and antioxidant activity of five medicinal plant; Fenois totais e atividade antioxidante de cinco plantas medicinais  

Energy Technology Data Exchange (ETDEWEB)

This paper describes total phenolics content and antioxidant activity in the ethanolic extract of leaves, bark and roots of five medicinal plants: Terminalia brasiliensis Camb., Terminalia fagifolia Mart. and Zucc., Copernicia cerifera (Miller) H.E. Moore, Cenostigma macrophyllum Tul. var. acuminata Teles Freire and Qualea grandiflora Mart. The total phenolics content of the plant extracts, determined by the Folin-Ciocalteu method, varied from 250.0 {+-}8,2 to 763,63 {+-}13.03 mg of gallic acid equivalent/g dry EtOH extract. The antioxidant activity of extracts was evaluated using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay system. Extract of bark from T. brasiliensis, the most active, with an EC{sub 50} value of 27.59 {+-} 0.82 {mu}g/mL, was comparable to rutin (EC{sub 50} = 27.80 {+-} 1.38) and gallic acid (EC{sub 50} = 24.27 {+-} 0.31), used as positive controls. The relationship between total phenolic content and antioxidant activity was positive and ...

2007-03-15

332

The nanostructure and microstructure of steels: Electrochemical Tafel behaviour and atomic force microscopy  

International Nuclear Information System (INIS)

The influence of chemical composition and heat treatment on a low-carbon steel, chromium steel and high speed steel has been examined by polarisation curves and electrochemical parameters deduced from the Tafel plots. The electrochemical corrosion resistance, which is small between the as-received steels become greater after heat treatment, following the order: carbon steel < chromium steel #approx# high speed steel. To explain these differences, the nano- and microstructure of the steels has been characterized by the ex situ techniques of atomic force microscopy and optical microscopy, before and after surface etching with Nital (a solution of 5% HNO_3 in ethanol). This causes preferential attack of the ferrite phases showing the carbide phases more clearly. From these nanostructural studies it was possible to better understand why the passive films formed on chromium steel and high speed steel have superior protective properties to those formed on carbon ...

2005-12-01

333

Supercritical fluid extraction from dried banana peel (Musa spp., genomic group AAB): Extraction yield, mathematical modeling, economical analysis and phase equilibria  

British Library Electronic Table of Contents (United Kingdom)

Supercritical fluid extraction from dried banana peel (Musa spp., subgroup Prata, genomic group AAB, popularly known in Brazil as Enxerto) was studied. The aspects investigated were: overall extraction curve (OEC), mass transfer modeling of the yield curves, economical analysis of the process and phase equilibrium data for the pseudo-ternary system of banana peel extract, carbon dioxide and ethanol. The extraction operating conditions evaluated were: pressure ranging from 100bar to 300bar, temperature from 40 to 50^oC and constant solvent flow rate of 5.0gCO2/min. Experimental extraction data were correlated using three kinetic models based on mass transfer equations (logistic, diffusion and Esquivel models). Phase equilibrium measurements were performed using pressure from 64.9bar to 239....

2010-01-01

334

Spontaneous transfer of ganglioside GM_1 between phospholipid vesicles  

International Nuclear Information System (INIS)

The transfer kinetics of the negatively charged glycosphingolipid II"3-N-acetylneuraminosyl-gangliotetraosylceramide (GM_1) were investigated by monitoring tritiated GM_1 movement between donor and acceptor vesicles. After appropriate incubation times at 45 "0C, donor and acceptor vesicles were separated by molecular sieve chromatography. Donors were small unilamellar vesicles produced by sonication, whereas acceptors were large unilamellar vesicles produced by either fusion or ethanol injection. Initial GM_1 transfer to acceptors followed first-order kinetics with a half-time of about 40 h assuming that GM_1 is present in equal mole fractions in the exterior and interior surfaces of the donor vesicle bilayer and that no glycolipid flip-flop occurs. GM_1 net transfer was calculated relative to that of ["1"4C]cholesteryl oleate, which served as a nontransferable marker in the donor vesicles. Factors affecting the GM_1 interbilayer transfer rate included phospholipid ...

335

Reduction of CO{sub 2} concentration in a zinc/air battery by absorption in a rotating packed bed  

Energy Technology Data Exchange (ETDEWEB)

The reduction of CO{sub 2} concentration in a gas stream containing 500ppm of CO{sub 2} by a technique combining chemical absorption with Higee (high gravity) was investigated in this study. Using a 2.0L aqueous amine-based solution to treat the feed gas with a flow rate which varied from 12.9 to 20.6Lmin{sup -1}, piperazine (PZ) was found to be more effective than 2-(2-aminoethylamino) ethanol (AEEA) and monoethanolamine (MEA) for reducing the CO{sub 2} concentration to a level below 20ppm. The effects of temperature, rotating speed, amine solution flow rate, and gas flow rate on the removal efficiency of CO{sub 2} were systematically examined. The results indicated that the proposed compact device could effectively reduce CO{sub 2} to a level below 20ppm, as required by a zinc/air battery, for a long period of time using PZ and its mixture with AEEA and MEA as the absorbents. (author)

2006-11-22

336

Molar extinction coefficients of some commonly used solvents  

International Nuclear Information System (INIS)

Molar extinction coefficients of some commonly used solvents (ethanol (C_2H_5OH), methanol (CH_3OH), propanol (C_3H_7OH), butanol (C_4H_9OH), water (H_2O), toluene (C_7H_8), benzene (C_6H_6), carbontetrachloride (CCl_4), acetonitrile (C_4H_3N), chlorobenzene (C_6H_5Cl), diethylether (C_4H_1O) and dioxane (C_4H_8O_2)) have been determined by a well-collimated narrow beam transmission geometry at 279, 356, 662, 1173, 1252 and 1332 keV #gamma# rays. The total #gamma# ray interaction cross sections of these solvents have also been determined. A good agreement has been obtained between the experimental results with the theoretical values evaluated through XCOM calculations.

2006-07-01

337

MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers chemiresistor and their application in low molecular weight alcohol vapours sensing  

British Library Electronic Table of Contents (United Kingdom)

Herein, we fabricated MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers by electrospinning and dip coating method. The amount of MWCNT-OH adsorbed to the pure electrospun nylon 6,6 nanofibers was 0.056wt%. The electrical conductivity of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers was 5.24x10^-^3Scm^-^1. We also investigated the sensing properties of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers by measuring its response upon exposure to low molecular weight alcohol vapours such as methanol, ethanol, 1-propanol, and 1-butanol. The changes of the electrical resistance of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers were demonstrated on the basis of hydrogen bonds among the alcohol vapours and hydroxyl groups (-OH) on MWCNT-OH, and amide groups (-NHCO-) in nylon 6,6. The fa...

2010-01-01

338

Luminescent determination of zirconium and hafnium with myricetin  

International Nuclear Information System (INIS)

Reaction of formation of 3, 5, 7, 3', 4', 5' - hexaoxiflavone - myricetin complexes with zirconium and hafnium ions has been the basis for development of luminescent method of determining these elements. Optimum conditions for complexing have been determined. For Hf they are : 8-9 HCl concentration, maximum fluorescence wave length (lambda fl.)of 520 nm, wave length of exciting light (lambda el) of 436 nm, for Zr lambda fl = 536nm, lambda el = 436 nm. Stable fluorescence establishes after 25 min. for Zr and after 15 min for Hf in the presence of 40% ethanol. Usage of various camouflage agents has permitted to attain high selectivity of the method. Possibility for determination of Zr with myricetin in the presence of a 10-time excess of Hf, Cr, Cu, 50-time excess of Mo and Ti is shown. Sensitivity of Zr determination is 2.0x10 #mu#g"-"2/ml, for Hf it is 9.0x10 #mu#g"-"3 and mineral waters.

339

Gas sensing behavior of SnO{sub 1.8}:Ag films composed of size-selected nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

Size-selected SnO{sub 1.8}:Ag mixed nanoparticle films have been prepared using a gas phase condensation method. Transmission electron microscopy showed that the applied size-selection technique yields well-defined, monodisperse and spherical SnO{sub 1.8} and Ag nanoparticles, both with a fixed diameter of 20 nm. The technique allows an independent variation of the particle size of both materials as well as the concentration of Ag. It allows to assess the influence of these parameters on the gas-sensing properties of the films, here for ethanol vapor in synthetic air. SnO{sub 1.8}:Ag nanoparticle films show optimal values of the sensor signal and response time at a Ag nanoparticle concentration of 5%. Due to the fact that the Ag nanoparticles are clearly distinct from the SnO{sub 1.8} nanoparticles in the film, the most probable mechanism leading to improved sensor properties is chemical sensitization via a spill-over effect.

2006-12-15

340

Evaluation of two streamlined life cycle assessment methods  

International Nuclear Information System (INIS)

Two different methods for streamlined life cycle assessment (LCA) are described: the MECO-method and SLCA. Both methods are tested on an already made case-study on cars fuelled with petrol or ethanol, and electric cars with electricity produced from hydro power or coal. The report also contains some background information on LCA and streamlined LCA, and a deschption of the case study used. The evaluation of the MECO and SLCA-methods are based on a comparison of the results from the case study as well as practical aspects. One conclusion is that the SLCA-method has some limitations. Among the limitations are that the whole life-cycle is not covered, it requires quite a lot of information and there is room for arbitrariness. It is not very flexible instead it difficult to develop further. We are therefore not recommending the SLCA-method. The MECO-method does in comparison show several attractive features. It is also interesting to note that the MECO-method produces ...

341

Environmental strategy for energy: hydrogen fuel cell bus for Brazil  

Energy Technology Data Exchange (ETDEWEB)

One of the most densely populated urban regions in the world is the Sao Paulo Metropolitan region (SPMR) in the State of Sao Paulo, Brazil. Air pollution is a real problem, mainly caused by vehicle exhaust fumes. The air pollution abatement measures adopted in the SPMR, such as the addition of ethanol to gasoline, the use of cars running on pure alcohol, the restrictions in the circulation of vehicles and the utilization of electronic fuel injection and catalyst have had a positive effect on the environment. The 25,000 buses and approximately 400,000 trucks, all operating on diesel, have not been affected by these measures, and it is believed that SPMR is the ideal location for testing new vehicular pollution reduction technologies. A project to this effect was launched by the Ministry of Mines and Energy in conjunction with a host of other partners, and it involved the operation of a fuel cell bus using hydrogen produced by electrolysis. The project was divided ...

2001-06-01

342

Effect of alcohols and temperature on the direct chiral resolutions of fipronil, isocarbophos and carfentrazone-ethyl.  

Science.gov (United States)

The enantiomeric separations of three pesticides fipronil (asymmetric nitrogen), isocarbophos (asymmetric phosphorus) and carfentrazone-ethyl (asymmetric carbon) were studied on cellulose-tri(3,5-dimethylphenylcarbamate) chiral stationary phase using high-performance liquid chromatography under normal phase. The mobile phase was n-hexane with alcohols including ethanol, n-propanol, iso-propanol, n-butanol and iso-butanol as polar modifiers. The flow rate was 1.0 mL/min with UV detection at 280, 225 and 230 nm for fipronil, isocarbophos and carfentrazone-ethyl respectively. The influence of the modifiers and their volume content and temperature from 0 to 50 degrees C on the separations was investigated. The chiral stationary phase showed excellent stereoselectivity for the two enantiomers of fipronil and isocarbophos and certain chiral recognition for carfentrazone-ethyl. Iso-propanol was more suitable for the chiral separation of isocarbophos and ...

2005-07-01

343

Crystal structure of ball-milled mixture of sodium chloride and magnesium chloride-ethanol adduct  

International Nuclear Information System (INIS)

NaCl doped MgCl_2.nEtOH adducts were prepared by ball-milling MgCl_2.2.5EtOH with NaCl. Both the ball-milled MgCl_2.nEtOH/NaCl mixture and pure MgCl_2.2.5EtOH adducts were analyzed by X-ray diffraction (XRD), transmission electron microscope (TEM), thermogravimetry (TG) and differencial scanning calorimetry (DSC). A simple MgCl_2.nEtOH/NaCl mixture without ball-milling treatment was also studied for comparison. Two kinds of mixed crystals, Na_2MgCl_4 and NaMgCl_3, were found to be formed in a ball-milled mixture that contained 16 mol.% NaCl. TG and DSC analysis of the samples also provided indirect evidences supporting the presence of the mixed crystals in the ball-milled mixture. Adding certain amounts of NaCl in MgCl_2.2.5EtOH adduct, either by co-milling or by simple mixing, greatly increased the thermal stability of the adduct, but thermal decomposition behaviour of the ball-milled mixture was still different from that of a simple mixture.

2008-02-05

344

Constituents from Maytenus ilicifolia leaves and bioguided fractionation for gastroprotective activity  

International Nuclear Information System (INIS)

Maytenus ilicifolia Mart. ex Reissek is traditionally used in Brazil for treatment of gastric ulcers. Here we report the phytochemical investigation of an ethanol extract of M. ilicifolia leaves (EEMIL) aiming at the isolation of constituents which were used as chemical markers to monitor an activity-guided fractionation of a lyophilized aqueous extract of M. ilicifolia leaves (LAEMIL). From EEMIL, four flavonoids were isolated, namely the tri-flavonoid glycosides mauritianin (1), trifolin, (2) hyperin (4), and epi-catechin (5). Fractionation of LAEMIL led to 5 fractions which afforded the tetra-glycoside kaempferol derivative (3), and galactitol (6). LAEMIL and its fractions were evaluated in rats for their effects on gastric secretion volume and pH. HPLC (High Performance Liquid Chromatography) analysis revealed that only fractions containing the tri- and tetra-flavonoid glycosides 1 and 3 caused significant increase of gastric volume and pH, thus indicating that ...

345

Comparison of maintenance energy expenditures and growth yields among several rumen bacteria grown on continuous culture.  

Science.gov (United States)

Maintenance energy expenditures were mesured for five rumen bacteria, Selenomonas ruminantium, Butyrivibrio fibrisolvens, Bacteroides ruminicola, Megasphaera elsdenii, and Streptococcus bovis, by using a complex medium with glucose as the carbon source. Large differences (as high as 8.5-fold) in maintenance energy expenditures were seen among these bacteria. The suggestion is made that maintenance requirements could be a significant determinant of bacterial competition in the rumen. Theoretical maximum growth yields, calculated from double reciprocal plots of yield versus dilution rate, were compared to theoretical Y(ATP) values in order to estimate minimum molar adenosine 5'-triphosphate yields from glucose for each bacterium. Results showed that relative yield among the bacteria was growth rate dependent. At high dilution rates, both S. ruminantium and S. bovis produced lactate as their principal fermentation product. At lower dilution rates very little lactate was formed and growth ...

1979-03-01

346

Binary copper(II) and uranyl(VI) complexes of glycocyamine, taurine and pyridoxal and ternary complexes involving 2,2'-bipyridine, 1,10-phenanthroline or nitrilotriacetic acid  

International Nuclear Information System (INIS)

Chelating tendencies of several biologically important compounds viz. glycocyamine (GCN: N-amidino-aminoethanoic acid) taurine (TRN: 2-aminoethanesulphonic acid) and pyridoxal [PDL: 3-hydroxy-5-(hydroxymethyl)-2-methyl-pyridine-4-carbaldehyde] have been examined by pH-metric titration technique in their binary complex formation with copper(II) and uranyl(VI) ions. The work has further been extended to investigating the ternary complex formation involving 2.2'-bipyridine. 1,10-phenanthroline or nitrilotriacetic acid as a primary and TRN and PDL as secondary ligands. All the experiments were carried out at 25"0C and at an ionic strength of 0.1M (NaCl0_4) in aqueous or 50% (v/v) aqueous-ethanol medium according to the suitability of the experimental conditions. Stabilities of ternary complexes as compared to those of the corresponding binary complexes of the secondary ligands have also been discussed. (author).

347

A new method of heat transfer augmentation by means of foreign gas jet impingement in liquid bath  

International Nuclear Information System (INIS)

The authors discuss a two-phase two-component experimental system developed to study enhancement of heat transfer from a vertical chip size heater to surrounding liquid (Freon 113 or Ethanol) due to air jet impingement. Heat transfer coefficient was measured as function of jet velocity, heat flux and the distance between exit of jet tube and heated surface. The injector was placed very close to the hot surface. It was found that the heat transfer was notably enhanced with foreign gas impingement, especially in the cases of small temperature differences between wall and coolant. In fact for higher jet velocities the heat transfer coefficients tended to infinite while the temperature differences between wall and coolant were zero. The heat transfer coefficients decreased with the increasing of heat flux. High-speed camera was used to study the behaviour of the gas bubbles which play very important role in the heat transfer process. A physical model of simultaneous ...

1985-10-01

348

HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model  

Energy Technology Data Exchange (ETDEWEB)

Experiments in a homogeneous charge compression ignition (HCCI) engine have been conducted with four gasoline surrogate fuel blends. The pure components in the surrogate fuels consisted of n-heptane, isooctane, toluene, ethanol and diisobutylene and fuel sensitivities (RON-MON) in the fuel blends ranged from two to nine. The operating conditions for the engine were p{sub in}=0.1 and 0.2 MPa, T{sub in}=80 and 250 C, {phi}=0.25 in air and engine speed 1200 rpm. A semidetailed chemical kinetic model (142 species and 672 reactions) for gasoline surrogate fuels, validated against ignition data from experiments conducted in shock tubes for gasoline surrogate fuel blends at 1.0{<=} p{<=}5.0MPa, 700{<=} T{<=}1200 K and {phi}=1.0, was successfully used to qualitatively predict the HCCI experiments using a single zone modeling approach. The fuel blends that had higher fuel sensitivity were more resistant to autoignition for low intake temperature ...

2009-04-15

349

Validation of the Canadian atmospheric dispersion model for small exclusion area boundaries  

International Nuclear Information System (INIS)

AECL is undertaking the validation of ADDAM, an atmospheric dispersion and dose code based on the Canadian Standards Association model CSA N288.2. The key component of the validation program involves the comparison of air concentrations predicted by the model with measured values. Measurements are available from field studies at two Canadian reactor sites and from a wind tunnel study of the CANDU site at Wol song, Korea. The measurements were obtained close enough to the release points to test the model for exclusion area boundaries as small as 500 m. Model predictions were higher than the observations almost 75 percent of the time and the magnitude of the over predictions was typically much larger than the magnitude of the under predictions. The effect of the topography at the Wol song site was limited to small changes in plume trajectory due to channeling in valleys and a small reduction in the lateral spread of the plume. The terrain did not substantially ...

1999-11-04

350

Unusual Recharge Processes near Arroyos of the Rio Grande Aquifer, El Paso/Juarez Area  

Science.gov (United States)

The twin-cities of El Paso and Juarez share the water resources of the Hueco Bolson aquifer and overlying Rio Grande aquifer. Both aquifers span the international border between Mexico and the United States. Salinity in the Rio Grande aquifer varies widely, some parts of the shallow aquifer containing less than 1,000 mg/L total dissolved solids (TDS), other parts of the aquifer exceeding 5,000 mg/L TDS. One sizable part of the "Lower Valley" area, approximately 45 km below El Paso contains very dilute water near the outer edge of the floodplain. Historically it had been thought that the dilute waters in this location were derived from recharge from arroyos that drained proximal parts of the Hueco Bolson. Instead, our hydrogen and oxygen isotope data and carbon-14 data indicate that these dilute waters were derived from pre-dam infiltration of the Rio Grande. Relatively light and slightly evaporated pre-dam waters (-11.5 del O18) at the arroyos are also ...

2005-12-01

351

US Department of Energy Region IV Unconventional Gas Program: summary and analysis  

Energy Technology Data Exchange (ETDEWEB)

The DOE Region IV Unconventional Gas Program involved the evaluation of unconventional gas resources at ten sites in the coal fields of the Eastern US. These projects dealt mainly with coalbed methane resources, although three of them also examined potential gas resources in Devonian black shales. The resource evaluations were accomplished primarily through recovery of core samples of potential gas-bearing strata and determination of specific gas content using the US Bureau of Mines direct method. In some cases actual gas production from the test holes was evaluated. Four of the projects were sited in the Warrior Basin, three in the Central Appalachian Basin, and one each in the Northern Appalachian Basin, the Deep River Basin of North Carolina, and the Valley Coal Fields of Virginia. Results from three of the projects, two in the Warrior Basin and one in the Northern Appalachian Basin, indicated the potential for economic recovery of coalbed methane. The projects ...

1984-12-01

352

The effect of local circulations on the variation of atmospheric pollutants in the northwestern Taiwan  

Energy Technology Data Exchange (ETDEWEB)

A field experiment was held in the northwestern Taiwan as a part of a long-term research program for studying Taiwan`s local circulation. The program has been named as Taiwan Regional-circulation Experiment (TREX). The particular goal of this research is to investigate characteristics of boundary layer and local Circulation and their impact on the distribution and Variation of pollutants in the northwestern Taiwan during Mei-Yu season. It has been known for quite sometime that land-sea breeze is very pronounced under hot and humid conditions. Extensive network includes 11 pilot ballon stations, 3 acoustic sounding sites, and 14 surface stations in about 20 km by 20 km area centered at National Central University, Chung-Li. In addition, there are ground temperature measurements at 3 sites, Integrated Sounding System (ISS) at NCU, air plane observation, tracer experiment with 10 collecting stations, 3 background upper-air sounding stations, 2 towers etc. NOAA and GMS satellite data, sea ...

1996-12-31

353

Spent Fuel Background Report Volume I  

Energy Technology Data Exchange (ETDEWEB)

This report is an overview of current spent nuclear fuel management in the DOE complex. Sources of information include published literature, internal DOE documents, interviews with site personnel, and information provided by individual sites. Much of the specific information on facilities and fuels was provided by the DOE sites in response to the questionnaire for data for spent fuels and facilities data bases. This information is as accurate as is currently available, but is subject to revision pending results of further data calls. Spent fuel is broadly classified into three categories: (a) production fuels, (b) special fuels, and (c) naval fuels. Production fuels, comprising about 80% of the total inventory, are those used at Hanford and Savannah River to produce nuclear materials for defense. Special fuels are those used in a wide variety of research, development, and testing activities. Special fuels include fuel from DOE and commercial reactors used in research activities at DOE ...

1994-03-01

354

Shawnee flue gas desulfurization computer model users manual  

Energy Technology Data Exchange (ETDEWEB)

In conjunction with the US Enviromental Protection Agency sponsored Shawnee test program, Bechtel National, Inc., and the Tennessee Valley Authority jointly developed a computer model capable of projecting preliminary design and economics for lime- and limestone-scrubbing flue gas desulfurization systems. The model is capable of projecting relative economics for spray tower, turbulent contact absorber, and venturi-spray tower scrubbing options. It may be used to project the effect on system design and economics of variations in required SO/sub 2/ removal, scrubber operating parameters (gas velocity, liquid-to-gas (L/G) ration, alkali stoichiometry, liquor hold time in slurry recirculation tanks), reheat temperature, and scrubber bypass. It may also be used to evaluate alternative waste disposal methods or additives (MgO or adipic acid) on costs for the selected process. Although the model is not intended to project the economics of an individual system to a high ...

1985-03-01

355

Sequence stratigraphy in frontier regions: An example from the Rebi Block, Arafura Sea, Eastern Indonesia  

Energy Technology Data Exchange (ETDEWEB)

The Rebi Block is currently in the early stages of hydrocarbon exploration. The subsurface geology of this area is only known from seismic reflection data. By applying seismic stratigraphy techniques, unconformities and condensed sections were recognized. These discontinuities were dated using paleontological information from the Kulka-1 well, Northwest Shelf of Australia. With these age constraints, seven unconformities and three condensed sections were dated and correlated to the Exxon global sea level curve. The chronostratigraphic charts for the Rebi Block and the Northwest Shelf of Australia have clarified the Mesozoic stratigraphy of the study area. The Exxon global sea level curve has refined the ages determined by conventional paleontological dating. The chart has also helped in predicting source, reservoir and seal potential within a time framework. Prospective stratigraphic traps were those related to the incised valleys at the southeastern part of the ...

1996-12-31

356

Quarterly progress report for the Chemical and Energy Research Section of the Chemical Technology Division: October-December 1997  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the major activities conducted in the Chemical and Energy Research Section of the Chemical Technology Division at Oak Ridge National Laboratory (ORNL) during the period October--December 1997. The section conducts basic and applied research and development in chemical engineering, applied chemistry, and bioprocessing, with an emphasis on energy-driven technologies and advanced chemical separations for nuclear and waste applications. The report describes the various tasks performed within six major areas of research: Hot Cell Operations, Process Chemistry and Thermodynamics, Separations and Materials Synthesis, Fluid Structure and Properties, Biotechnology Research, and Molecular Studies. The name of a technical contact is included with each task described, and readers are encouraged to contact these individuals if they need additional information. Activities conducted within the area of Hot Cell Operations included efforts to optimize the processing conditions ...

1999-02-01

357

New trends in electricity pricing in Sweden from a utility perspective  

Energy Technology Data Exchange (ETDEWEB)

Sweden is facing a re-structured electricity market beginning January 1, 1996, implying full competition in the purchasing and selling of electricity. The transmission and distribution of electricity will remain as a franchised monopoly and this business has to be strictly separated from the electricity trading. In the monopolistic environment, pricing of electricity has been based on more or less relevant costs and a resonable rate of return. The energy charges have reflected the system short range marginal costs while the demand and fixed charges have been adapted to give a total cost level corresponding to the system average cost. Tariffs of this type, known as time-of-use tariffs, have stimulated peak shaving during peak load (high cost hours) and valley filling during low load (low cost hours), increasing the load factor. Restructuring will influence the pricing in several ways. Pricing of transmission and distribution services will be based on costs and will ...

1996-03-01

358

Natural resource injury assessment of a crude oil spill  

International Nuclear Information System (INIS)

In January 1994, a 6.7 magnitude earthquake in southern California ruptured a pipeline releasing approximately 4,200 barrels of blended San Joaquin Valley crude oil. A smaller volume entered the Santa Clara River and flowed 25 km downstream to an emergency containment dam. Ruptured water mains and chlorinated discharges from a damaged sewage treatment plant also affected water quality in the river. Quantitative injury assessment studies were initiated within days of the spill and included water/sediment chemistry, benthic macroinvertebrate community analyses and aquatic toxicity tests. Water quality values for TPH, BTEX, and chlorine ranged from nondetectable to 78 mg/l (TPH), nondetectable to 5.4 microg/l (total BTEX constituents) and nondetectable to 600 microg/l (residual chlorine) within 72 hours of the spill. Ammonia concentrations ranged from nondetectable to 12.1 mg/l within 10 days of the spill. Hydrocarbon concentrations in sediments ranged from ...

1996-11-17

359

Monitoring, sampling and analysis of fine particulates -- Results and experiences from DOE's Federal Energy Technology Center  

Energy Technology Data Exchange (ETDEWEB)

The overall goal of the DOE fine particulate program is to ensure that the best science and technology is available for any regulatory decision-making related to the health and environmental impacts of ambient fine particulate matter and regional haze. Interest primarily lies in the particulate fraction having aerodynamic diameters of 2.5 microns and less (PM2.5). Particulates of this size are the focus of the newly established National Ambient Air Quality Standards. As such, the Federal Energy Technology Center (FETC) is establishing a fine particulate sampling station at the Center's Pittsburgh site located in South Park Township, PA. This sampling station is one of a group of stations scattered throughout Pennsylvania, West Virginia, and Ohio that constitute the Upper Ohio River Valley Project. The station is equipped with a full complement of fine particulate and gaseous monitors including the following: (1) R and P Sequential FRM sampler, (2) Grimm ...

1999-07-01

360

Mechanical properties and corrosion behavior of materials exposed to an experimental, atmospheric fluidized-bed combustor  

Energy Technology Data Exchange (ETDEWEB)

A joint materials test program developed by the Institute for Mining and Minerals Research (IMMR) and the Tennessee Valley Authority (TVA) involved the postexposure mechanical properties and corrosion behavior of candidate structural materials in an experimental, atmospheric fluidized-bed combustor (AFBC). This combustor was operated by Accurex Corporation at Research Triangle Park, North Carolina, under the direction of TVA. The materials studied were Type 304, Type 310, and INCOLOY alloy 800 in the form of disc coupons with and without crevice configurations. Type 304 was also used for mechanical property measurements. The alloys were exposed to the combustor environment at about840/sup 0/C for approximately 330 hours. The ranking in terms of decreasing weight loss was: (1) Type 304, (2) Type 310, and (3) INCOLOY alloy 800. The presence of tight crevices did not enhance the corrosion rate. In addition, the corrosion rates, based on the weight loss (typically 1 to ...

1984-06-01

361

Magnetobiostratigraphy of the continental Paleocene upper Coalspur and Paskapoo formations near Hinton, Alberta  

Energy Technology Data Exchange (ETDEWEB)

A chronology for Paleocene strata of the Hinton area of west-central Alberta was developed from the integration of a magnetostratigraphic and palynostratigraphic study of the upper Coalspur and middle to upper Paskapoo strata in the Coal Valley to Obed Mountain area. The study resulted in the compilation of a complete section of 1100 m of strata with a maximum sediment accumulation rate of 250 m/m.y. Four new informal biostratigraphic units were used to highlight stratigraphically useful bioevents not previously recognized in existing zonations. These strata range in age from magnetochron 29r to 24r and palynozones Wodehouseia spinata Zone, Aquilapollenites reticulatus Subzone through the Pistillipollenite mcgregorii Zone. The 3 intervals with the most rapid changes in the palynoflora were the earliest Paleocene; the transition from the early to middle Paleocene; and in the late Paleocene. Each coincides with critical times in basin development, notably the ...

2008-06-15

362

Less waste corn, more land in soybeans, and the switch to genetically modified crops: trends with important implications to wildlife management  

Science.gov (United States)

An abundance of waste corn, a key food of many wildlife species, has helped make possible the widespread success of wildlife management in the United States over the past half century. We found waste corn post harvest in Nebraska declined by 47% from 1978 to 1998 due primarily to improvements in combine headers resulting in a marked decline in ear loss. The reduction in waste coincided with major declines in fat storage by sandhill cranes and white-fronted geese during spring migration. Sandhill cranes, northern pintails, white-fronted geese, and lesser snow geese avoided soybeans while staging in spring in the Rainwater Basin Area and Central Platte River Valley. These findings and other literature suggest soybeans are a marginal food for wildlife particularly during periods of high energy requirements. Soybean acreage has increased by 600% in the United States since 1950 and now comprises nearly one-quarter of the nation>'s cropland. With over 80% of the ...

2004-01-01

363

Ground-level ozone: Our new environmental policy  

International Nuclear Information System (INIS)

The environmental problem of ground level ozone is discussed, and the Canadian strategy for dealing with it is explained. Ozone in the troposphere can cause serious health problems in susceptible persons, and is estimated to cause up to $70 million in crop damage per year. The Canadian Council of Ministers of the Environment (CCME) Plan calls for less than 82 ppB by volume of ozone in any one-hour period in all areas of Canada by 2005. Three areas of Canada regularly exceed this value: the Lower Frazer valley in British Columbia, Saint John in New Brunswick, and the Windsor-Quebec corridor along the lower Great Lakes and the St. Lawrence River. Ozone is formed by a photochemical reaction of ammonia gases, nitrogen oxides, hydrogen sulfide or sulfur dioxide. Historically, ozone control has concentrated on controlling hydrocarbon emissions, but to little effect. In most locations close to large cities, ozone production is nitrogen oxide-limited, and the most recent ...

364

Evaluation of impacts on wetlands: do NEPA analyses integrate wetland protection requirements  

Energy Technology Data Exchange (ETDEWEB)

The impacts of federal projects on wetlands should be included in documents prepared to comply with the National Environmental Policy Act (NEPA). NEPA assessments of impacts on wetlands are often related to requirements of other laws, regulations, and executive orders, such as permitting requirements under Section 404 of the Clean Water Act and those contained in Executive Order 11990, Protection of Wetlands. This paper reviews recent NEPA environmental impact statements that contained assessments of impacts on wetlands or that involved projects likely to affect wetlands. It covers documents prepared by several federal agencies, including the Army Corps of Engineers, Department of Energy, Federal Highway Administration, Soil Conservation Service, and Tennessee Valley Authority. The extent and depth of analyses of wetlands issues was found to be highly variable, both within and among agencies. Most analyses did not provide adequate geographical or ecological context ...

1991-01-01

365

Coal rank and coalbed methane potential of Cretaceous/Tertiary coals in the Canadian Rocky Mountain Foothills and adjacent Foreland. 1: Hinton and Grand Cache areas, Alberta  

Energy Technology Data Exchange (ETDEWEB)

The coal rank, coal distribution, and coalbed methane of four major coal zones in the Hinton and Grande Cache areas of Alberta were investigated. Coal rank in the study area ranges from subbituminous and high volatile C bituminous at surface for the Upper Cretaceous/Tertiary coal measures and semianthracite for the Lower Cretaceous Luscar Group in the Alberta Syncline. In the Rocky Mountain Foothills, maximum cumulative coal thicknesses occur in the Smoky River, Cadomin-Luscar, and Coal Valley coalfields. Cumulative coal thicknesses generally decrease east of the deformed belt; however, coal isopach maps indicate local cumulative coal thicknesses in excess of 25 m. A regional coalbed methane assessment for strata east of the deformed belt shows favorable coalbed methane adsorption capacities in Luscar Group coals. These coals occur, however, at depth levels [gt]2500 m. In contrast, Brazeau and Coalspur Formation coals occur at favorable depth levels ([lt] 1100 m) ...

1994-12-01

366

Characterization and geochemistry of Devonian oil shale: north Alabama, northwest Georgia, and south-central Tennessee (a resource evaluation). Final report  

Energy Technology Data Exchange (ETDEWEB)

A geochemical survey to assess and evaluate the Devonian oil shale resources of north Alabama, northwest Georgia, and south-central Tennessee has been performed. Information is provided on the location and extent of the more favorable kerogen-bearing Devonian shale, oil and uranium content of the shale, trace metal and standard rock analyses for shale, data on the physical properties of the shale rock, mineralogy of the shale, chemical properties of the oil, and other pertinent data deemed necessary for resource development. The results indicate that the oil yield from areas underlain by Chattanooga Shale can be divided into areas having greater than 7 g/t and areas having less than 7 g/t. In general, the oil yield by Fischer assay of samples from the folded Appalachian Valley and Ridge and the Appalachian Plateaus provinces is poor, all having less than 5 g/t and most samples closer to 0 g/t. The extreme variance of Fischer assay values in the Chattanooga Shale ...

1984-05-03

367

Characteristics of the Receptor for the Biosphere Model  

Energy Technology Data Exchange (ETDEWEB)

This analysis report is one of a series of technical reports that document the Environmental Radiation Model for Yucca Mountain, Nevada (ERMYN), a biosphere model supporting the total system performance assessment (TSPA) for the geologic repository at Yucca Mountain. This report is one of the five biosphere reports that develop input parameter values for the biosphere model. The ''Biosphere Model Report'' (BSC 2004 [DIRS 169460]) describes the conceptual model, as well as the mathematical model and its input parameters. Figure 1-1 is a graphical representation of the documentation hierarchy for the ERMYN. This figure shows relationships among the products (i.e., scientific analyses and model reports) developed for biosphere modeling and biosphere abstraction products for TSPA, as identified in the ''Technical Work Plan: for Biosphere Modeling and Expert Support'' (BSC 2004 [DIRS 169573]). The purpose of this ...

2004-09-09

368

Assessment Of Heavy Metal Contamination Of Arable Soils In Central Bekaa Plain, Lebanon  

International Nuclear Information System (INIS)

The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), solid and liquid wastes, and agricultural due ...

2004-12-04

369

Applications of high resolution sequence stratigraphy in North Sea syn-rift reservoir correlation and development  

Energy Technology Data Exchange (ETDEWEB)

Tectonically active basins may host a spectrum of sequence stratigraphic expressions previously considered to be spatially mutually exclusive. In low accommodation areas with high sediment supply, fourth order eustatic cyclicity results in high frequency sequence sets while within rapidly subsiding areas, time-equivalent Type-2 sequences are expressed by highly asymmetrical coarsening upward successions, resembling large parasequences. In the shallow marine Fulmar Formation, of the U.K. North Sea Central Graben a sequence boundary and overlying lowstand deposits, which illustrate the effects of laterally variable subsidence rate and intrabasinal topography on the expression of a eustatic sea-level fall, lie between the Glosense and Serratum (J54a and J54b) maximum flooding surfaces. The syn-rift physiography comprises major tilted fault blocks, with the Central Graben dipping parallel to the major faults, simulating a ramp setting. Where the throw of the faults were greatest (SE), the ...

1995-08-01

370

Anomalous zones in Gulf Coast Salt domes with special reference to Big Hill, TX, and Weeks Island, LA  

Energy Technology Data Exchange (ETDEWEB)

Anomalous features in Gulf Coast Salt domes exhibit deviations from normally pure salt and vary widely in form from one dome to the next, ranging considerably in length and width. They have affected both conventional and solution mining in several ways. Gas outbursts, insolubles, and potash (especially carnallite) have led to the breakage of tubing in a number of caverns, and caused irregular shapes of many caverns through preferential leaching. Such anomalous features essentially have limited the lateral extent of conventional mining at several salt mines, and led to accidents and even the closing of several other mines. Such anomalous features, are often aligned in anomalous zones, and appear to be related to diapiric processes of salt dome development. Evidence indicates that anomalous zones are found between salt spines, where the differential salt intrusion accumulates other materials: Anhydrite bands which are relatively strong, and other, weaker impurities. Shear zones and fault ...

1993-07-01

371

Accommodation controls on fluvial-deltaic reservoir architecture  

Energy Technology Data Exchange (ETDEWEB)

Hydrocarbon recovery efficiency is controlled by reservoir heterogeneities resulting from geometric arrangements of strata, or {open_quotes}stratal architecture{close_quotes}. Traditional reservoir characterization relates depositional systems to stratal architecture. High-resolution sequence stratigraphy of outcrop analogs provides a chronostratigraphic framework for evaluating accommodation conditions of depositional systems. Key stratigraphic surfaces and/or correlative strata define a hierarchy of chronostratigraphic units of different periodicities. The Upper Cretaceous Ferron Sandstone, an analog to high accommodation and sediment supply fluvial-deltaic reservoirs, comprises an intermediate-term stratigraphic sequence consisting of seven short-term stratigraphic cycles. Each short-term stratigraphic cycle contains fluvial- to storm-dominated shallow-marine deposits laterally replaced by distributary channel deposits. The Lower Cretaceous Fall River Formation, an analog to low ...

1995-08-01

372

Multiphasic helical Computed Tomography of hepatocellular carcinoma. Evaluation after various percutaneous ablation procedures; Tomografia Computerizzata spirale multifasica dell'epatocarcinoma. Valutazione dopo differenti procedure ablative percutanee  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to report the personal experience with helical CT evaluation of hepatocellular carcinoma treated with various percutaneous interventional procedures. From December 1996 to September 1998 it were examined with helical CT 41 patients (73 nodules in all) with hepatocellular carcinoma treated with percutaneous ablation therapies: conventional ethanol injection in 18 subjects (31 nodules), one-shot ethanol injection 3 (8 nodules), radiofrequency thermal ablation in 16 (25 nodules), and combined chemo embolization and ethanol injection in 4 (9 nodules). CT performed was 4-27 days after the last session, acquiring biphasic volumetric images in 14 patients and triphasic volumetric images in 27. A second treatment with subsequent CT study was performed for 28 lesions; 15 underwent 3 serial studies and 6 underwent 4 studies. Compared with pretreatment findings, the diameter was unchanged in 62% of the ...

1999-12-01

373

Reconsidering the site requirements for NPP on Olt River  

International Nuclear Information System (INIS)

Site studies for CANDU type NPP began in a careful manner since 1982 as a first part of the Nuclear Power Plant Romanian Program adopted by political and governmental authorities at the time. A team was charged to develop all packages of the necessary main studies. The first Romanian NPP CANDU 6 type reactor gone to erection on Cernavoda site, planned to have 5 units and, like Wolsong NPP, applied the same design for the nuclear island. For the BOP parts the ANSALDO-GE project was applied with a thorough concern about requirements raised by connection to NSP. The first mission of design and research multi-branch team was to adapt the NPP Cernavoda project having an open water cooling circuit 'once-through' to the new parameters of a close recirculation water cooling circuit. Also, the structural design was re-evaluated for the case of soft foundation strata instead of hard rock ones. The close recirculation water cooling circuit system was applied for PWR NPP type like in French or ...

2009-10-12

374

Recent environment, energy and resources cases and issues in Alberta  

Energy Technology Data Exchange (ETDEWEB)

Significant environmental issues and regulatory proceedings in Alberta were discussed. The Mackenzie Valley Pipeline Project was reviewed in relation to the Deh Cho First Nation's advanced actions in the federal court to enjoin the review panel from proceeding with the review process. The Deh Cho First Nation is seeking a declaration that the plan violates their rights under the Canadian Charter of Rights and Freedoms and the Constitution Act. Various regulatory and government agencies have now developed a plan to coordinate their different regulatory processes and approvals in the Cooperation Plan for the Environmental Impact Assessment and Regulatory Review of the Northern Gas Pipeline project. The Deh Cho allege that they were not afforded the opportunity to participate in the development and implementation of the plan. A review panel plans to proceed once the environmental and social impacts are determined, and the consortiums plan to minimize harm has ...

2005-07-01

375

Neutron activation analysis for determination of selected trace elements responsible for immunity in foodstuffs and water in egypt  

International Nuclear Information System (INIS)

Selenium (Se), zinc (Zn), magnesium (Mg), molybdenum (Mo) and vanadium (V) in 28 types of Egyptian common foodstuffs as well as drinking and irrigation water samples were determined using neutron activation analysis (NAA) and atomic absorption spectrometry (AAS). The samples were collected from 74 sites over 13 governorates as well as the Nile river, wells and tap water in the regions of the Nile Delta, Sinai, the east and west desert, and north and south Egypt. These trace elements were chosen according to international references, which show the close relationship of their deficiencies to immunity-related diseases. Calculation values of daily uptake per capita were made with the results of analysis. The results, as calculated per 100 g dry weight, showed that some Egyptian foods are rich in Se including such fish (0.94 #mu#g), sesame (0.88 #mu#g), beef meat (0.48 #mu#g), instant tea (0.42 #mu#g), mushroom (0.34 #mu#g) and eggs (0.3 #mu#g), whereas the vegetables contained less than ...

376

Characteristics of the Receptor for the Biosphere Model  

Energy Technology Data Exchange (ETDEWEB)

This analysis report is one of a series of technical reports that document the Environmental Radiation Model for Yucca Mountain, Nevada (ERMYN), a biosphere model supporting the total system performance assessment (TSPA) for the geologic repository at Yucca Mountain. This report is one of the five biosphere reports that develop input parameter values for the biosphere model. The ''Biosphere Model Report'' (BSC 2004 [DIRS 169460]) describes the conceptual model, as well as the mathematical model and its input parameters. Figure 1-1 is a graphical representation of the documentation hierarchy for the ERMYN. This figure shows relationships among the products (i.e., scientific analyses and model reports) developed for biosphere modeling and biosphere abstraction products for TSPA, as identified in the ''Technical Work Plan for Biosphere Modeling and Expert Support'' (BSC 2005 [DIRS 172782]). The purpose of this ...

2005-04-05

377

Buried Paleo-Phreatic Playa is the Primary Source of Salinity in the Rio Grande and Rio Grande Aquifer, El Paso-Juarez Valley  

Science.gov (United States)

The Rio Grande alluvial floodplain aquifer between El Paso/Juarez and Fort Quitman, Texas has been intensively tilled and irrigated since 1910. Almost since that time, the Rio Grande and its interconnected alluvial aquifer in this stream reach have been affected by excessive salinity problems. Presently, salinity of surface water and groundwater increases from 800 to 2000 mg/L total dissolved solids (TDS) near El Paso, Texas to 2500 to 5500 mg/L TDS near Fort Quitman, Texas, approximately 115 km downstream. Chloride (Cl) and Chloride/Bromide (Cl/Br) ratios increase downstream, with a marked increase in salinity beginning about 45 km below El Paso. Groundwater sampling in an intensively investigated reach of the floodplain aquifer, extending from 35 to 60 km below El Paso identified two distinct water types. The first water type (17 samples) is a relatively dilute groundwater containing 1000 to 2000 mg/L TDS, 250 to 600 mg/L Cl, and Cl/Br weight ratios of 550 to 900. The second ...

2005-12-01

378

Transcriptome sequencing and annotation of the microalgae Dunaliella tertiolecta: Pathway description and gene discovery for production of next-generation biofuels  

Science.gov (United States)

BackgroundBiodiesel or ethanol derived from lipids or starch produced by microalgae may overcome many of the sustainability challenges previously ascribed to petroleum-based fuels and first generation plant-based biofuels. The paucity of microalgae genome sequences, however, limits gene-based biofuel feedstock optimization studies. Here we describe the sequencing and de novo transcriptome assembly for the non-model microalgae species, Dunaliella tertiolecta, and identify pathways and genes of importance related to biofuel production.ResultsNext generation DNA pyrosequencing technology applied to D. tertiolecta transcripts produced 1,363,336 high quality reads with an average length of 400 bases. Following quality and size trimming, ~ 45% of the high quality reads were assembled into 33,307 isotigs with a 31-fold coverage and 376,482 singletons. Assembled sequences and singletons were subjected to BLAST similarity searches and annotated with Gene Ontology (GO) and ...

2011-03-14

379

Synthesis of (methine- sup 3 H)DDT and its nitro-analog, and isotope effects in their enzyme-catalyzed dehydrochlorination  

Energy Technology Data Exchange (ETDEWEB)

(methine-{sup 3}H)1,1-Di-(4-chlorophenyl)-2,2,2-trichloroethane ((methine-{sup 3}H)DDT) and its di-(4-nitrophenyl) analog, both of high purity with a moderately high specific activity were prepared. Chloro-benzene was condensed with (1-{sup 3}H)1-(4-chlorophenyl)-2,2,2-trichloro-ethanol, which has been synthesized by sodium boro({sup 3}H)hydride reduction of 4-chlorophenyl trichloromethyl ketone. The purified ({sup 3}H)DDT had a specific activity of 0.77 Ci/mmol (28.49 GBq/mmol). (methine-{sup 3}H)1,1-Diphenyl-2,2,2-trichloroethane was similarly synthesized and was nitrated to give (methine-{sup 3}H)1,1-di-(4-nitrophenyl)-2,2,2-trichloro-ethane of 1.63 Ci/mmol (60.31 GBq/mmol). Dehydrochlorination with housefly enzyme (glutathione-dependent DDT dehydrochlorinase) showed a remarkable isotope effect. For DDT, the observed tritium isotope effect on V{sub max}/K{sub m} was 11.51{plus minus}0.52. For the nitro-analog, the value was 11.3{plus minus}1.2. We measured ...

1989-08-01

380

Synthesis and spectral properties of diethyl organylchalcogenoalkyl(alkyl)malonates, RX(CH/sub 2/)/sub n/CR'(COOC/sub 2/H/sub 5/)/sub 2/, and 5-alkyl-5-(organylchalcogenoalkyl)barbiturates, RX(CH/sub 2/)/sub n/C(R')CONHC(Y)NHCO (X = Se, Te)  

Energy Technology Data Exchange (ETDEWEB)

Barbiturates substituted at the 5-position with organyltelluroalkyl or organylselenoalkyl groups were prepared by ring annulation of appropriately substituted diethyl malonates with urea or thiourea. The substituted diethyl malonates (phenyltellurobutyl(ethyl), i-propyltelluropropyl(ethyl), i-propyltelluropropyl(allyl), i-propyselenopropyl(ethyl), and phenylselenohexyl(methyl)) were prepared in 55-91% yield by reaction of diethyl omega-bromoalkyl(alkyl)malonates with organyltellurolates or selenolates (RXNa; X = Se, Te) in ethanol/benzene. The following barbiturates were obtained in 28-84% yield: phenyltellurobutyl(ethyl), m.p. 100/sup 0/C; i-propyltelluropropyl(ethyl), m.p. 119/sup 0/C; i-propylselenopropyl(ethyl), m.p. 137/sup 0/C; phenyl-selenohexyl(methyl), m.p. 124/sup 0/C. The 5-substituted thiobarbiturates i-propyltelluropropyl(ethyl)-(m.p. 75/sup 0/C) and i-propylselenopropyl(ethyl)thiobarbiturate (m.p. 83/sup 0/C) were isolated in 32 and 20% yield, ...

1983-01-01

381

Suspension and solution plasma spraying of finely structured layers: potential application to SOFCs  

International Nuclear Information System (INIS)

Suspension direct current plasma spraying allows achieving finely structured coatings whose thickness is between few tens and few hundreds of micrometres. Drops (200-300 ?m in diameter) or liquid jets are mechanically injected in the plasma jet. With radial injection they are rapidly (a few ?s) fragmented into droplets (a few ?m in diameter). The latter are vaporized (in a few ?s) and the solid particles contained in suspension droplets are accelerated and melted by the plasma jet. As in conventional plasma spraying (CPS), much smaller splats (with diameters between 0.2 and 3 ?m and thicknesses between 30 and 200 nm) are arranged in layers up to form the coating. The low inertia of particles requires spray distances between 40 and 60 mm which induces plasma heat fluxes up to 22 MW m-2 participating in coating densification. Even more than in CPS, the plasma jet fluctuations, particularly for plasmas containing di-atomic gases, perturb drops penetration and fragmentation. It has been ...

2007-04-21

382

Surfactant based sol-gel approach to nanostructured LiFePO{sub 4} for high rate Li-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Porous nanostructured LiFePO{sub 4} powder with a narrow particle size distribution (100-300nm) for high rate lithium-ion battery cathode application was obtained using an ethanol based sol-gel route employing lauric acid as a surfactant. The synthesized LiFePO{sub 4} powders comprised of agglomerates of crystallites <65nm in diameter exhibiting a specific surface area ranging from 8m{sup 2}g{sup -1} to 36m{sup 2}g{sup -1} depending on the absence or presence of the surfactant. The LiFePO{sub 4} obtained using lauric acid resulted in a specific capacity of 123mAhg{sup -1} and 157mAhg{sup -1} at discharge rates of 10C and 1C with less than 0.08% fade per cycle, respectively. Structural and microstructural characterization were performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) with energy dispersive X-ray (EDX) analysis while electronic conductivity and specific surface area ...

2007-01-01

383

Renewable energies and energy choices. Summary of the colloquium; Energies renouvelables et choix energetiques. Compte rendu du colloque  

Energy Technology Data Exchange (ETDEWEB)

This document is an executive summary of the colloquium organized by the French syndicate of renewable energies (SER) which took place at the Maison de l'UNESCO in Paris during the national debate on energies organized by the French government in spring 2003. The colloquium was organized around 6 round tables dealing with: the world perspectives and the environmental context of the contribution of renewable energies to the sustainable development (respect of Kyoto protocol commitments, contribution to the security of energy supplies, lack of large scale program of development of decentralized power generation in developing countries, lack of market tools linked with CO{sub 2} emissions, improvement of competitiveness); development of renewable energies in Europe (promotion and sustain in all European countries, obligation of supply and purchase, pricing regulation, European harmonization of practices); renewable electricity and its place in the new orientation law about ...

2003-05-01

384

Photophysical properties of new psoralen derivatives: psoralens linked to adenine through polymethylene chains  

International Nuclear Information System (INIS)

The model compounds, 8-methoxypsoralen-CH_2O(CH_2)_n-adenine (MOPCH_2OC_nAd, n=2,3,5,6,8, and 10) in which 5 position of 8-methoxypsoralen (8-MOP) is linked by various lengths of polymethylene bridge to N"9 of adenine. UV absorption spectra are identical with the sum of MOPCH_2OC3 and adenine absorption spectra. Solvent effect on the UV absorption and fluorescence emission spectra indicate that the lowest excited singlet state is the (#pi##->##pi#"*) state. The spectral characteristics of the fluorescence of MOPCH_2OC_nAd are strongly dependent upon the nature of the solvents. The fluorescence emission spectra in aprotic solvents are broad and structrueless due to the excimer formation through the folded conformation accelerated by hydrophobic #pi#-#pi# stacking interaction. Increasing polarity of the protic solvents leads to higher population of unfolded conformation stabilized through favorable solvation and H-bonding, and consequently to an increase in the fluorescence intensity, ...

2002-10-01

385

Microbial dynamics in upflow anaerobic sludge blanket (UASB) bioreactor granules in response to short-term changes in substrate feed  

Science.gov (United States)

The complexity and diversity of the microbial communities in biogranules from an upflow anaerobic sludge blanket (UASB) bioreactor were determined in response to short-term changes in substrate feeds. The reactor was fed simulated brewery wastewater (SBWW) (70% ethanol, 15% acetate, 15% propionate) for 1.5 months (phase 1), acetate / sulfate for 2 months (phase 2), acetate-alone for 3 months (phase 3), and then a return to SBWW for 2 months (phase 4). Performance of the reactor remained relatively stable throughout the experiment as shown by COD removal and gas production. 16S rDNA, methanogen-associated mcrA and sulfate reducer-associated dsrAB genes were PCR amplified, then cloned and sequenced. Sequence analysis of 16S clone libraries showed a relatively simple community composed mainly of the methanogenic Archaea (Methanobacterium and Methanosaeta), members of the Green Non-Sulfur (Chloroflexi) group of Bacteria, followed by fewer numbers of Syntrophobacter, ...

2010-08-01

386

Materials for power sources to meet military requirements  

Energy Technology Data Exchange (ETDEWEB)

Power source requirements for the military were presented to provide guidelines for research and development planning. Power sources that contain a high amount of energy and are small, light and durable are a common request from military users. Safety, reliability and low temperature performance are also important factors in the selection of power sources, as are cost and energy efficiency. Issues concerning advanced batteries were reviewed with reference to high energy density cathode materials. Various thermoelectric and renewable energy materials were discussed, with reference to recovery and conversion of waste heat. It was suggested that photovoltaic devices could help revolutionize military logistics by modifying energy re-supply requirements. Solid Oxide Fuel Cells (SOFC) were considered in relation to the high price of the ceramic materials required for operation. It was noted that the development of SOFC anodes capable of generating hydrogen from liquid fuels such as methanol ...

2005-07-01

387

ERK-dependent and -independent pathways trigger human neural progenitor cell migration  

International Nuclear Information System (INIS)

Besides differentiation and apoptosis, cell migration is a basic process in brain development in which neural cells migrate several centimeters within the developing brain before reaching their proper positions and forming the right connections. For identifying signaling events that control neural migration and are therefore potential targets of chemicals to disturb normal brain development, we developed a human neurosphere-based migration assay based on normal human neural progenitor (NHNP) cells, in which the distance is measured that cells wander over time. Applying this assay, we investigated the role of the extracellular signal-regulated kinases 1 and 2 (ERK1/2) in the regulation of NHNP cell migration. Exposure to model substances like ethanol or phorbol 12-myristate 13-acetate (PMA) revealed a correlation between ERK1/2 activation and cell migration. The participation of phospho-(P-) ERK1/2 was confirmed by exposure of the cells to the MEK inhibitor PD98059, ...

2007-05-15

388

Development and use of the GREET model to estimate fuel-cycle energy use and emissions of various transportation technologies and fuels  

Energy Technology Data Exchange (ETDEWEB)

This report documents the development and use of the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The model, developed in a spreadsheet format, estimates the full fuel- cycle emissions and energy use associated with various transportation fuels for light-duty vehicles. The model calculates fuel-cycle emissions of five criteria pollutants (volatile organic compounds, carbon monoxide, nitrogen oxides, sulfur oxides, and particulate matter measuring 10 microns or less) and three greenhouse gases (carbon dioxide, methane, and nitrous oxide). The model also calculates the total fuel-cycle energy consumption, fossil fuel consumption, and petroleum consumption using various transportation fuels. The GREET model includes 17 fuel cycles: petroleum to conventional gasoline, reformulated gasoline, clean diesel, liquefied petroleum gas, and electricity via residual oil; natural gas to compressed natural gas, liquefied petroleum gas, methanol, hydrogen, and ...

1996-03-01

389

Combustion characteristics of fuel droplets with addition of nano and micron-sized aluminum particles  

Energy Technology Data Exchange (ETDEWEB)

The burning characteristics of fuel droplets containing nano and micron-sized aluminum particles were investigated. Particle size, surfactant concentration, and the type of base fluid were varied. In general, nanosuspensions can last much longer than micron suspensions, and ethanol-based fuels were found to achieve much better suspension than n-decane-based fuels. Five distinctive stages (preheating and ignition, classical combustion, microexplosion, surfactant flame, and aluminum droplet flame) were identified for an n-decane/nano-Al droplet, while only the first three stages occurred for an n-decane/micron-Al droplet. For the same solid loading rate and surfactant concentration, the disruption and microexplosion behavior of the micron suspension occurred later with much stronger intensity. The intense droplet fragmentation was accompanied by shell rupture, which caused a massive explosion of particles, and most of them were burned during this event. On the ...

2011-02-15

390

Caldicellulosiruptor obsidiansis sp. nov., an anaerobic, extremely thermophilic, cellulolytic bacterium isolated from Obsidian Pool, Yellowstone National Park  

Energy Technology Data Exchange (ETDEWEB)

A novel, obligately anaerobic, extremely thermophilic, cellulolytic bacterium, designated OB47T, was isolated from Obsidian Pool, Yellowstone National Park, WY, USA. The isolate was a non-motile, non-spore forming, Gram-positive rod approximately 2 m long by 0.2 m wide and grew at temperatures between 55-85oC with the optimum at 78oC. The pH range for growth was 6.0-8.0 with values of near 7.0 being optimal. Growth on cellobiose produced the fastest specific growth rates at 0.75 hr-1. The organism also displayed fermentative growth on glucose, maltose, arabinose, fructose, starch, lactose, mannose, sucrose, galactose, xylose, arabinogalactan, Avicel, xylan, filter paper, processed cardboard, pectin, dilute acid-pretreated switchgrass and Populus. OB47T was unable to grow on mannitol, fucose, lignin, Gelrite, acetate, glycerol, ribose, sorbital, carboxymethylcellulose and casein. Yeast extract stimulated growth and thiosulfate, sulfate, nitrate, and sulfur were not reduced. Fermentation ...

2010-02-01

391

Antitumor and Antiviral Activity of Colombian Medicinal Plant Extracts  

Scientific Electronic Library Online (English)

Abstract in english Extracts of nine species of plants traditionally used in Colombia for the treatment of a variety of diseases were tested in vitro for their potential antitumor (cytotoxicity) and antiherpetic activity. MTT (Tetrazolium blue) and Neutral Red colorimetric assays were used to evaluate the reduction of viability of cell cultures in presence and absence of the extracts. MTT was also used to evaluate the effects of the extracts on the lytic activity of herpes simplex virus type (more) 2 (HSV-2). The 50% cytotoxic concentration (CC50) and the 50% inhibitory concentration of the viral effect (EC50) for each extract were calculated by linear regression analysis. Extracts from Annona muricata, A. cherimolia and Rollinia membranacea, known for their cytotoxicity were used as positive controls. Likewise, acyclovir and heparin were used as positive controls of antiherpetic activity. Methanolic extract from Annona sp. on HEp-2 cells presented a CC50 value at 72 hr of ...

1999-07-01

392

An EXAFS investigation of the structures of bromocopper(II) complexes in some solutions  

International Nuclear Information System (INIS)

The structures of bromocopper(II) complexes in methanolic (M1, M2, M3, M4), ethanolic (E), and aqueous (H) solutions were determined by the analyses of the Cu K- and Br K-edge EXAFS spectra using a curve-fitting method. The molar concentrations of Cu and Br in these solutions prepared by CuBr_2 and LiBr are 0.996 and 1.992 (M1), 1.015 and 5.381 (M2), 0.493 and 4.525 (M3), 0.260 and 4.073 (M4), 1.031 and 4.313 (E), and 0.982 and 5.426 (H). In M1 solution the interatomic distances for the Cu-O_e_q, Br_e_q-Cu, and Br_e_q-O_e_q (_e_q = equatorial) were 2.00A, 2.35A, and 3.15A respectively, and the Br_e_q-Cu-O_e_q angle was estimated as about 92 deg. Therefore, trans-dibromo bis(methanol)copper(II) complex with a slightly distorted planar structure was proposed to be dominant complex species in M1 solution. The interatomic distances in M2, M3, M4 and E solutions were 2.37A and 3.45A (average) for the Br_e_q-Cu and Br_e_q-Br_e_q respectively. The Br_e_q-Cu-Br_e_q angle, ...

393

Additives to lower and stabilize the viscosity of pyrolysis oils during storage  

Energy Technology Data Exchange (ETDEWEB)

The initial development of additives to stabilize the viscosity of biocrude during long-term storage has produced dramatic results. The additives investigated were ethyl acetate, methyl isobuyl ketone and methanol, acetone, methanol, acetone and methanol, and ethanol. These additives represent three chemical families, which all demonstrated the ability to drastically reduce the aging rate of biocrude, as defined by the increase in viscosity with time. Accelerated aging tests were run at 90{degree}C to screen the additives. The additives not only lowered the initial viscosity at 40{degree}C by half but also reduced the aging rate of a hot gas filtered pyrolysis oil made from hybrid poplar (NREL run 175) by factors of 1-18 compared to the original pure oil. With the best additive, methanol, at a 10 wt% level in the pyrolysis oil, the modified biocrude was still a single-phase liquid and still met the ASTM no. 4 diesel fuel specification for viscosity even after 96 h ...

1997-09-01

394

Catalytic hydrothermal gasification of biomass for the production of synthetic natural gas[Dissertation 17100  

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass serves as reaction ...

2007-07-01

395

Multidisciplinary Graduate Education in Bioprocess Engineering  

Energy Technology Data Exchange (ETDEWEB)

This report describes the accomplishments of the University of Georgia in establishing an academic program geared toward the emerging biobased products industry. By virtue of its strengths and structure, the University of Georgia is particularly well-suited for developing a program focused on plant- and microbial-based bioproducts, and it was in this general area that this program was developed. The program had several unique characteristics. First, we implemented a distinguished lecture series that brought outstanding scientists and engineers to our University to interact with students and share their vision of the biobased economy. Second, we offered industrially-oriented and multidisciplinary courses that provided students with a broad background on various facets of biobased business and technology. Third, we provided the students with opportunities to expand beyond the classroom by engaging in research lab rotations and industrial internships. Fourth, each student was engaged in a ...

2006-04-18

396

Effect of silver addition on the formation and deposition of titania nanoparticles produced by liquid flame spray  

Energy Technology Data Exchange (ETDEWEB)

In this study, liquid flame spray (LFS) was used to produce titania, silver and silver-titania deposits of nanoparticles. Titanium(IV)ethoxide (TEOT) and silver nitrate in ethanol solutions were used as precursors and sprayed into turbulent hydrogen-oxygen flame. Production rates of 1.5-40 mg/min of titania were used with silver additions of 1, 2, 4, and 8 wt% compared to titania. Nanoparticle deposits were collected by thermophoretic sampling at six different axial distances from the flame torch head: 3, 5, 10, 12, 15, and 20 cm, of which the all but the last one occurred inside the flame. The deposit samples were analysed by TEM and SAED analysis. The powder samples of the particles were also collected by electric precipitator to XPS and specific surface area analysis. Particle size and effective density after the flame in the aerosol were analysed with SMPS and ELPI. The results from the previous studies i.e. controlling the particle size by setting the ...

2007-08-15

397

Wien Automatic System Planning (WASP) Package. A computer code for power generating system expansion planning. Version WASP-IV. User's manual  

International Nuclear Information System (INIS)

As a continuation of its efforts to provide methodologies and tools to Member States to carry out comparative assessment and analyse priority environmental issues related to the development of the electric power sector, the IAEA has completed a new version of the Wien Automatic System Planning (WASP) Package WASP-IV for carrying out power generation expansion planning taking into consideration fuel availability and environmental constraints. This manual constitutes a part of this work and aims to provide users with a guide to use effectively the new version of the model WASP-IV. WASP was originally developed in 1972 by the Tennessee Valley Authority and the Oak Ridge National Laboratory in the USA to meet the IAEA needs to analyse the economic competitiveness of nuclear power in comparison to other generation expansion alternatives for supplying the future electricity requirements of a country or region. Previous versions of the model were used by Member States in ...

1997-12-01

398

Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants  

Energy Technology Data Exchange (ETDEWEB)

The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands ...

2005-08-30

399

European Space Agency announces contest to "Name the Cluster Quartet"  

Science.gov (United States)

1. Contest rules The European Space Agency (ESA) is launching a public competition to find the most suitable names for its four Cluster II space weather satellites. The quartet, which are currently known as flight models 5, 6, 7 and 8, are scheduled for launch from Baikonur Space Centre in Kazakhstan in June and July 2000. Professor Roger Bonnet, ESA Director of Science Programme, announced the competition for the first time to the European Delegations on the occasion of the Science Programme Committee (SPC) meeting held in Paris on 21-22 February 2000. The competition is open to people of all the ESA member states (*). Each entry should include a set of FOUR names (places, people, or things from history, mythology, or fiction, but NOT living persons). Contestants should also describe in a few sentences why their chosen names would be appropriate for the four Cluster II satellites. The winners will be those which are considered most suitable and relevant for the Cluster II mission. ...

2000-02-01