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1

Neutron spectroscopy study of L- and DL-valine  

Energy Technology Data Exchange (ETDEWEB)

Short communication. 2 figs., 1 tab.

1994-01-01

2

The Mitochondrial Isovaleryl-Coenzyme A Dehydrogenase of Arabidopsis Oxidizes Intermediates of Leucine and Valine Catabolism1  

UK PubMed Central (United Kingdom)

We recently identified a cDNA encoding a putative isovaleryl-coenzyme A (CoA) dehydrogenase in Arabidopsis (AtIVD). In animals, this homotetrameric enzyme is located in mitochondria and catalyzes the...Full Text Available

2001-06-01

3

Inelastic and non-single-diffraction factorial moments from phenomenological models for elastic hadron scattering  

International Nuclear Information System (INIS)

We calculate the normalized factorial moments of multiplicity distributions through three models for elastic hadron scattering (Chou-Yang, Henzi-Valin and Menon-Pimentel). Connections between the moments and the inelastic overlap function and/or eikonal function are obtained by means of an impact parameter representation for the multiplicity distribution. The predictions are compared with experimental data on factorial moments from both inelastic and non-single-diffractive events. The model results present best agreement with the inelastic events and data favour the model by Henzi and Valin. (author)

4

Monitoring amino acids, organic acids, and ripening changes in Cheddar cheese using Fourier-transform infrared spectroscopy  

British Library Electronic Table of Contents (United Kingdom)

Fourier-transform infrared (FTIR) spectroscopy was used to monitor amino acids, organic acids, and changes during ripening. Twelve Cheddar cheese samples were ripened for 73 days and samples were drawn periodically. Water-soluble fractions of samples were analyzed by gas chromatography (20 amino acids), liquid chromatography (three organic acids), and FTIR spectroscopy (4000-700 cm-1). Spectra were correlated with chromatographic data and ripening events and analyzed by multivariate statistics to develop prediction and classification models. Most models showed a good fit (correlation coefficient > or =0.89) and could predict the levels of amino acids and organic acids and age of the cheese in less than 20 min. Lactic acid, leucine, glutamic acid, asparagine, phenylalanine, and valine were ...

2011-01-01

5

Molar extinction coefficients in aqueous solutions of some amino acids  

International Nuclear Information System (INIS)

Mass attenuation coefficients of amino acids viz. glycerine (C_2H_5NO_2), 1-Serine (C_3H_7NO_3), 1-Theronine (C_4H_9NO_3), 1-Proline (C_5H_9NO_2), 1-Valine (C_5H_1_1NO_2) and 1-Phenylalanine (C_9H_1_1NO_2) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by the gamma-ray transmission method in a narrow beam good geometry setup. Precisely measured densities of these solutions were used for the determination of these coefficients which varied systematically with the corresponding changes in the concentrations (g/cm"3) of the solutions. Molar extinction coefficients of amino acids were then obtained at these energies and were found to be in good agreement with the theoretical results. In addition, total interaction cross sections of amino acids in aqueous solutions were also calculated. (author)

2002-09-01

6

Modelling fragmentations of amino-acids after resonant electron attachment: quantum evidence of possible direct -OH detachment  

International Nuclear Information System (INIS)

We investigate some aspects of the radiation damage mechanisms in biomolecules, focusing on the modelling of resonant fragmentation caused by the attachment of low-energy electrons (LEEs) initially ejected by biological tissues when exposed to ionizing radiation. Scattering equations are formulated within a symmetry-adapted, single-center expansion of both continuum and bound electrons, and the interaction forces are obtained from a combination of ab initio calculations and a nonempirical model of exchange and correlation effects developed in our group. We present total elastic scattering cross-sections and resonance features obtained for the equilibrium geometries of glycine, alanine, proline and valine. Our results at those geometries of the target molecules are briefly shown to qualitatively explain some of the fragmentation patterns obtained in experiments. We further carry out a one-dimensional (1D) modeling for the dynamics of intramolecular energy transfers ...

2010-10-01

7

Site-specific semisynthetic variant of human hemoglobin  

International Nuclear Information System (INIS)

A single round of Edman degradation was employed to remove the NH_2-terminal valine from isolated #alpha# chains of human hemoglobin. Reconstitution of normal #beta# chains with truncated or substituted #alpha# chains was used to form truncated (des-Val"1-#alpha#1) and substituted ([[1-"1"3C]Gly"1]#alpha#1) tetrameric hemoglobin analogs. Structural homology of the analogs with untreated native hemoglobin was established by using several spectroscopic and physical methods. Functional studies indicate that the reconstituted tetrameric protein containing des-Val"1-#alpha# chains has a higher affinity for oxygen, is less influenced by chloride ions or 2,3-biphosphoglycerate, and shows lower cooperativity than native hemoglobin. These results confirm the key functional role of the #alpha#-chain NH_2 terminus in mediating cooperative oxygen binding across the dimer interface. The NH_2-terminal pK/sub 1/2/ value was determined for the ["1"3C]glycine-substituted analog to ...

8

An analysis of selected atmospheric icing events on test cables  

Energy Technology Data Exchange (ETDEWEB)

In cold countries, the design of transmission lines and communication networks requires the knowledge of ice loads on conductors. Atmospheric icing is a stochastic phenomenon and therefore probabilistic design is used more and more for structure icing analysis. For strength and reliability assessments, a data base on atmospheric icing is needed to characterize the distributions of ice load and corresponding meteorological parameters. A test site where icing is frequent is used to obtain field data on atmospheric icing. This test site is located on the Mt. Valin, near Chicoutimi, Quebec, Canada. The experimental installation is mainly composed of various instrumented but non-energized test cables, meteorological instruments, a data acquisition system, and a video recorder. Several types of icing events can produce large ice accretions dangerous for land-based structures. They are rime due to in-cloud icing, glaze caused by freezing rain, wet snow, and mixtures of ...

1996-12-01