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1

Stress corrosion cracking in high-purity water of 3-31/2% NiCrMoV low-alloy steels for steam turbine disks and rotors. Pt. 1  

International Nuclear Information System (INIS)

In recent years intergranular stress corrosion cracking has occurred world-wide in the shrink-fitted discs of low pressure turbine rotors made of low alloy steels. Only in a few cases steam impurities such as NaOH, Na_2CO_3, Na_2SO_4, H_2S or NaCl, which initiate SCC, could be found. To clarify the SCC-behaviour experiments on turbine disc steels with different chemical compositions and yield strength were performed in high purity water. The results show, that chemical composition has no effect on the crack initiation. Under high purity water conditions no crack initiation due to stress corrosion cracking is observed on the steel with a yield strength of 850 N/mm"2. On the steel with a yield strength of 1250 N/mm"2 which is not used in service, crack initiation occurs in pure water. But if sharp cracks already exist, crack propagation occurs in both cases. The investigations showed, that stress corrosion cracking of turbine discs can be ...

2

Optimizing the microstructure of implant alloy TiAl5Fe2.5 by microprobe analysis  

International Nuclear Information System (INIS)

For optimizing the microstructure of the (#alpha# + #beta#)-titanium alloy TiAl5Fe2.5 the content of the two alloying elements aluminium and iron in the #alpha#- and #beta#-phase was determined by microprobe analysis. The alloys with the composition of the #alpha#- and of the #beta#-phase at 850 degC TiAl6Fe0.5 (#alpha#-phase) and TiAl3.5Fe6.5 (#beta#-phase) were prepared by arc melting and rolling at 850 degC. The mechanical properties of the '#alpha#'- and of the '#beta#'-phase-alloy are compared with the properties of the (#alpha# + #beta#)-alloy TiAl5Fe2.5 in the as rolled and swaged condition and after an additional aging at 550 degC. By this optimizing process it was possible to achieve a tensile strength of Rsub(m) = 1012 N/mm"2, an yield strength of Rsub(p0.2) 954 N/mm"2 and an elongation at fracture A = 14.5% in the TiAl5Fe2.5-alloy, although the degree of hot deformation was small. By a higher degree of deformation these properties ...

1985-05-13

3

The use of a mesoscale numerical model for evaluations of pollutant transport and diffusion in coastal regions and over irregular terrain  

Energy Technology Data Exchange (ETDEWEB)

A modelling approach is presented that appears to have the potential to provide reliable assessments of pollution concentration in coastal zones and complex terrain, where the assumptions behind current operational air quality models often are inadequate. With the use of a numerical mesoscale model (NMM), physically consistent flow fields can be predicted, thereby providing higher spatial and temporal resolution in the meteorological fields than would be available from a limited number of observation points. These predictions are used to calculate mean trajectories of pollutant parcels, as well as to provide quantitative estimates of pollution concentration using two techniques.

1983-03-01

4

The ternary system cerium-palladium-silicon  

British Library Electronic Table of Contents (United Kingdom)

Phase relations in the ternary system Ce-Pd-Si have been established for the isothermal section at 800degreeC based on X-ray powder diffraction and EMPA techniques on about 130 alloys, which were prepared by arc-melting under argon or powder reaction sintering. Eighteen ternary compounds have been observed to participate in the phase equilibria at 800degreeC. Atom order was determined by direct methods from X-ray single-crystal counter data for the crystal structures of t8-Ce3Pd4Si4 (U3Ni4Si4-type, Immm; a=0.41618(1), b=0.42640(1), c=2.45744(7)nm), t16-Ce2Pd14Si (own structure type, P4/nmm; a=0.88832(2), c=0.69600(2)nm) and also for t18-CePd1-xSix (x=0.07; FeB-type, Pnma; a=0.74422(5), b=0.45548(3), c=0.58569(4)nm). Rietveld refinements established the atom arrangement in the structures of...

2009-01-01

5

Synthesis, crystallographic data, solubility and electrokinetic properties of copper-, nickel- and cobalt-uranylphosphate  

Energy Technology Data Exchange (ETDEWEB)

A discussion is given concerning the transformation in acid medium of curite into copper-, nickel- and cobalt-uranylphosphate. From chemical, differential thermal and thermogravimetric analyses, the crystal-chemical formula are calculated as: Cu(UO/sub 2//PO/sub 4/)/sub 2/.8H/sub 2/O, Ni(UO/sub 2//PO/sub 4/)/sub 2/.7H/sub 2/O and Co(UO/sub 2//PO/sub 4/)/sub 2/.7H/sub 2/O. The two last compounds crystallize in the triclinic system with space group P1 or P1(overscore) and the first one crystallizes in the tetragonal system with space group P4/nmm. The cell parameters are calculated. From solubility data, the solubility products are computed as 10sup(-12.8), 10sup(-9.5) and 10sup(-9.9) for the copper-, nickel- and colbalt-compound respectively. The electrokinetic properties of the three species are closely similar to those of natural meta-torbernite: the zeta-potential is negative and the point of zero charge be reached cannot in the pH-range 2 to 9.

1981-01-01

6

Synthesis, crystallographic data, solubility and electrokinetic properties of copper-, nickel- and cobalt-uranylphosphate  

International Nuclear Information System (INIS)

A discussion is given concerning the transformation in acid medium of curite into copper-, nickel- and cobalt-uranylphosphate. From chemical, differentiel thermal and thermogravimetric analyses, the crystal-chemical formula are calculated as: Cu(UO_2/PO_4)_2.8H_2O, Ni(UO_2/PO_4)_2.7H_2O and Co(UO_2/PO_4)_2.7H_2O. The two last compounds crystallize in the triclinic system with space group P1 or P1(overscore) and the first one crystallizes in the tetragonal system with space group P4/nmm. The cell parameters are calculated. From solubility data, the solubility products are computed as 10sup(-12.8), 10sup(-9.5) and 10sup(-9.9) for the copper-, nickel- and colbalt-compound respectively. The electrokinetic properties of the three species are closely similar to those of natural meta-torbernite: the zeta-potential is negative and the point of zero charge be reached cannot in the pH-range 2 to 9.

7

Further development of the unified multiscale Eulerian model for a broad range of spatial and temporal scales within the new National Environmental Modeling System  

Science.gov (United States)

A unified Nonhydrostatic Multiscale Model on the Arakawa B grid (NMMB) designed for a broad range of spatial and temporal scales has been under development within the Earth System Modeling Framework (ESMF) at the National Centers for Environmental Prediction (NCEP) as a part of the new National Environmental Modeling System (NEMS). The model follows the general modeling philosophy of the NCEP's WRF NMM grid-point regional dynamical core. The model uses the regular latitude-longitude grid for the global domain, and a rotated latitude-longitude grid in regional applications. The nonhydrostatic component of the model dynamics is introduced through an add-on module that can be turned on or off depending on resolution. The "isotropic" quadratic conservative finite-volume horizontal differencing employed in the model conserves a variety of basic and derived dynamical and quadratic quantities and preserves some important properties of differential operators. Among these, ...

2009-04-01

8

Half-Heusler phase related structural perturbations near stoichiometric composition FeZnSb  

International Nuclear Information System (INIS)

Half-Heusler phases XYZ (Pearson symbol cF12) are chemically versatile and rich in physical properties. The half-Heusler phase in the Fe-Zn-Sb ternary system was reported in the year 2000. In this work, two new ternary phases are identified in the vicinity of the equiatomic composition FeZnSb in the same system: Fe1-xZnSb (tetragonal, space group P4/nmm, Pearson symbol tP6-?, Z=2: a=4.1113(6) A, c=6.0127(12) A for x=0.08 (1), and a=4.1274(6) A, c=6.0068(12) A for x=0.12 (2)); and Fe7.87Zn6.72Sb8 (Fe0.98Zn0.84Sb) (3) (cubic, space group Fm-3m, Pearson symbol cF96-?, Z=4, a=11.690(13) A). 1 and 2 crystallize in the PbFCl-type structure, and 3 adopts a unique 2x2x2 supercell of a normal half-Heusler structure. The structures of both the tetragonal and cubic phases can be described as assemblies of half-Heusler structure related subunits. Electrical resistivity measurement on the pure sample of 2 shows it has metallic-like behavior, and its thermal and magnetic ...

2011-05-01

9

Fracture toughness characterisation in the ductile-to-brittle transition and upper shelf regimes using pre-cracked Charpy single-edge bend specimens  

International Nuclear Information System (INIS)

Fracture toughness data of pre-cracked Charpy single-edge bend, SE(B), specimens are compared with those of standard compact, C(T), specimens in the upper shelf and ductile-to-brittle transition regimes. Charpy sized SE(B) specimens provide ductile fracture toughness data, which are compatible with those of standard C(T) specimens. Statistical methods such as the exponential curve fitting method (ECF), the engineering lower bound toughness method (ELB), and the Master Curve method (MC) are used to provide meaningful lower bound cleavage fracture toughness estimates from the toughness scatter of the Charpy sized SE(B) specimens in the ductile-to-brittle transition regime. In this regime, according to the ELB and MC methods, SE(B) specimens provide cleavage toughness data, which tend to be non-conservative compared to those of standard C(T) specimens. However, analyses based on the exponential curve fitting method show good agreement between the fracture toughness estimates for the C(T) ...

2005-08-01

10

The ternary system cerium-palladium-silicon  

International Nuclear Information System (INIS)

Phase relations in the ternary system Ce-Pd-Si have been established for the isothermal section at 800 deg. C based on X-ray powder diffraction and EMPA techniques on about 130 alloys, which were prepared by arc-melting under argon or powder reaction sintering. Eighteen ternary compounds have been observed to participate in the phase equilibria at 800 deg. C. Atom order was determined by direct methods from X-ray single-crystal counter data for the crystal structures of #tau#_8-Ce_3Pd_4Si_4 (U_3Ni_4Si_4-type, Immm; a=0.41618(1), b=0.42640(1), c=2.45744(7) nm), #tau#_1_6-Ce_2Pd_1_4Si (own structure type, P4/nmm; a=0.88832(2), c=0.69600(2) nm) and also for #tau#_1_8-CePd_1_-_xSi_x (x=0.07; FeB-type, Pnma; a=0.74422(5), b=0.45548(3), c=0.58569(4) nm). Rietveld refinements established the atom arrangement in the structures of #tau#_5-Ce_3PdSi_3 (Ba_3Al_2Ge_2-type, Immm; a=0.41207(1), b=0.43026(1), c=1.84069(4) nm) and #tau#_1_3-Ce_3_-_xPd_2_0_+_xSi_6 ...

2009-09-01

11

The ternary system cerium-palladium-silicon  

Science.gov (United States)

Phase relations in the ternary system Ce-Pd-Si have been established for the isothermal section at 800 deg. C based on X-ray powder diffraction and EMPA techniques on about 130 alloys, which were prepared by arc-melting under argon or powder reaction sintering. Eighteen ternary compounds have been observed to participate in the phase equilibria at 800 deg. C. Atom order was determined by direct methods from X-ray single-crystal counter data for the crystal structures of tau{sub 8}-Ce{sub 3}Pd{sub 4}Si{sub 4} (U{sub 3}Ni{sub 4}Si{sub 4}-type, Immm; a=0.41618(1), b=0.42640(1), c=2.45744(7) nm), tau{sub 16}-Ce{sub 2}Pd{sub 14}Si (own structure type, P4/nmm; a=0.88832(2), c=0.69600(2) nm) and also for tau{sub 18}-CePd{sub 1-x}Si{sub x} (x=0.07; FeB-type, Pnma; a=0.74422(5), b=0.45548(3), c=0.58569(4) nm). Rietveld refinements established the atom arrangement in the structures of tau{sub 5}-Ce{sub 3}PdSi{sub 3} (Ba{sub 3}Al{sub 2}Ge{sub 2}-type, Immm; a=0.41207(1), ...

2009-09-15