The effects of temperature and the use of macroreticular resins were studied in lithium isotope separation by an ion-exchange method. The isotope separation factors obtained decreased by increasing the temperature, and the factors for macroreticular resins were identical with those for the usual gel-type resins. However, the performance of isotope separation per unit band length in displacement chromatography was found to be improved by increasing the temperature and using macroreticular resins, because accelerating the interphase mass transfer caused the reduction of HETP (Height Equivalent to a Theoretical Plate).
Total thyroidectomy involving the adjacent structures of the trachea can cause tracheal damage such as early tracheal necrosis. The authors describe the first case of anterior tracheal necrosis following...Full Text Available
Components of various forest and agricultural residue biomass-including the polyphenolic compounds-were converted into aqueous solution and/or suspension by extraction and digestion. Some biomass components reacted vigorously under alkaline catalysis with formaldehyde and initially showed a high degree of exothermic reaction; however, other components did not react as vigorously under these conditions, indicating that different biomass materials require different methods to obtain optimum reactivity for the copolymerization with phenol. Our primary goal is to develop adhesives capable of producing acceptable bond quality, as determined by the wood products industries` standards, under a reasonable range of gluing conditions. Copolymer resins of phenol, formaldehyde, and biomass components were synthesized and evaluated for gluability of bonding exterior grade structural replaced with chemicals derived from peanut hulls, pecan shell flour, pecan pith, southern pine ...
Polycarbonate (PC), a non-crystalline resin, and polybutylene terephthalate (PBT), a crystalline resin, can be achieved by means of alloying of improving such various properties as chemical resistance, heat and impact resistance, and formability. This paper describes its manufacturing methods, properties, and market trends. A PC/PBT alloy improves the chemical resistance if the PBT composition ratio is high, but reduces thermal deformation temperature and impact strength. It is regarded adequate, therefore, that the PBT component ratio is set to 20% to 30%. The impact strength is improved by adding elastomer as a third component. The national production amount in 1992 was 4,800 tons a year; price per kilogram is 700 to 800 yen; and the main application is interior and exterior parts for automobiles. While PP and urethane are often used for interior and exterior automotive parts, there is a high possibility of transferring ...
A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, ...
Oils in Jinghu sag are abundant with high content of polar compounds and have a low ratio of saturate to aro-matic hydrocarbons and a high ratio of resin to asphaltene. The gross composition of oils in the Jinghu sag suggests typical immature to low mature characteristics. Some compounds with low thermal stability were identified. Light hy-drocarbons, a carbon preference index, an odd even index, n-alkane and hopane maturity parameters show mature fea-tures and little differences in the maturity level among oils. Sterane isomerization parameters indicate an immature to low mature status of oil. Transfer of the sedimentary center during sedimentation has led to different thermal histories among subsags and thus generated oils with different maturities. On the basis of source analyses, four ...
Norway spruce (Picea abies L. Karst) produces an oleoresin characterized by a diverse array of terpenoids, monoterpenoids, sesquiterpenoids, and diterpene resin acids that can protect...Full Text Available
Reduction of occupational radiation exposure dose in a BWR plant is achieved by an elimination of crud in a BWR primary loop condensate stream by condensate demineralizer. Crud removal by condensate polisher improves year by year, a phenomenon called the Aging Effect of Ion Exchange Resins. The cause of this phenomenon is assumed to be mainly due to changes in the cation resin property becoming more crud adsorptive, where a typical change in physical property of aged cation resin is an increase in water retention capacity. Assuming that the crud removal efficiency was influenced by a crosslinkage of cation resin, an attempt was made to enhance this removal efficiency by decreasing the crosslinkage and satisfactory results were obtained. As a result, new gel type cation resins were developed with lower crosslinkage and larger surface areas, as compared with conventional gel type ...
Reduction of occupational radiation exposure dose in a BWR plant is achieved by an elimination of crud in a BWR primary loop condensate stream by condensate demineralizer. Crud removal by condensate polisher improves year by year, a phenomenon called the Aging Effect of Ion Exchange Resins. The cause of this phenomenon is assumed to be mainly due to changes in the cation resin property becoming more crud adsorptive, where a typical change in physical property of aged cation resin is an increase in water retention capacity. Assuming that the crud removal efficiency was influenced by a crosslinkage of cation resin, an attempt was made to enhance this removal efficiency by decreasing the crosslinkage and satisfactory results were obtained. As a result, new gel type cation resins were developed with lower crosslinkage and larger surface areas, as compared with conventional gel type ...
The beater additive process for manufacturing combustible cartridge cases is superior to the solvent resin, post-impregnation process. However, the current beater additive resins do not produce as good a product as the solvent-resin system. The objective ...
The purpose of the work described in this dissertation is to increase the understanding of injection-pultrusion process. Three major substudies related to injection-pultrusion have been completed: measurement of the compressibility of fiber reinforcements, measurement of in-plane and transverse resin flow through fiber reinforcements, and development of a resin flow model. This dissertation also presents results of an experimental and analytical investigation of in-plane and transverse resin flow through fiber reinforcements.
The Dowex 50W-X8 and 50W-Xl2 resin samples are both strong acid cation materials in the hydrogen form. Each material has a water retention capacity characteristic of its respective marketed degree of cross-linking. Dowex 21K gives confirmatory responses to tests for a strong anion exchange resin in the nitrate form. All three resins have the manufacturer's specified ionic type and form, and the Dowex 50W resins have characteristic water retention capacities. These tests conclude that the ion exchange resins in use in FB-Line meet the approved safety document criteria for cross-linking, ionic form, and resin type.
The Dowex 50W-X8 and 50W-Xl2 resin samples are both strong acid cation materials in the hydrogen form. Each material has a water retention capacity characteristic of its respective marketed degree of cross-linking. Dowex 21K gives confirmatory responses to tests for a strong anion exchange resin in the nitrate form. All three resins have the manufacturer`s specified ionic type and form, and the Dowex 50W resins have characteristic water retention capacities. These tests conclude that the ion exchange resins in use in FB-Line meet the approved safety document criteria for cross-linking, ionic form, and resin type.
The development of crud removal technology has started with the finding of the resin aging effect that an old ion exchange resin, aged by long year of use in the condensate demineralizer, had an enhanced crud removal capability. It was confirmed that some physical properties such as specific surface area and water retention capacity were increased due to degradation caused by long year of contact with active oxygens in the condensate water. So, it was speculated that those degradation in the resin matrix enhanced the adsorption of crud particulate onto the resin surface, hence the crud removal capability. Based on this, crud removal resin with greater surface area was first developed. This resin has shown an excellent crud removal efficiency in an actual power plant, and the crud iron concentration in the condensate effluent was drastically reduced by this ...
The development of crud removal technology has started with the finding of the resin aging effect that an old ion exchange resin, aged by long year of use in the condensate demineralizer, had an enhanced crud removal capability. It was confirmed that some physical properties such as specific surface area and water retention capacity were increased due to degradation caused by long year of contact with active oxygens in the condensate water. So, it was speculated that those degradation in the resin matrix enhanced the adsorption of crud particulate onto the resin surface, hence the crud removal capability. Based on this, crud removal resin with greater surface area was first developed. This resin has shown an excellent crud removal efficiency in an actual power plant, and the crud iron concentration in the condensate effluent was drastically reduced by this ...
The 177 underground storage tanks at the DOE's Hanford Site contain an estimated 180 million tons of high-level radioactive wastes. It is desirable to remove and concentrate the highly radioactive fraction of the tank wastes for vitrification. Resorcinol-formaldehyde (R-F) resin, an organic ion-exchange resin with high selectivity and capacity for the cesium ion, which is a candidate ion-exchange material for use in remediation of tank wastes. The report includes information on the structure/function analysis of R-F resin and the synthetic factors that affect performance of the resin. CS-100, a commercially available phenol-formaldehyde (P-F) resin, and currently the baseline ion-exchanger for removal of cesium ion at Hanford, is compared with the R-F resin. The primary structural unit of the R-F resin was determined to consist of a ...
The evaluation methodology utilized in deciding to change over Oyster Creek plant operation from chemical regeneration of condensate demineralizer resin beds to throwaway of this spent resin is presented. Both the economic and operational aspects considered are discussed. The evaluation shows that potential savings in the $1.1M range are feasible over a 5 year cycle. Cost sensitivity analysis results define the throwaway versus regeneration breakeven point to be 47 condensate demineralization beds per 5 year cycle. The evaluation also discusses the trade off between resin and evaporator concentrates burial volumes. Analyses are given which show that the burial volume cost equivalency of resin to solidified concentrates is 150 ft./sup 3/ of resin equals 400 ft./sup 3/ of concentrates. Based on one year of power operation in the throwaway mode, the savings and operational value ...
Considerations were given on typical applications of nylon resin parts to automotive use and their future trends through news topics. GF strengthened nylon resin is used in cylinder head covers substituting aluminum because of advantages in nylon resin of weight reducibility, vibration suppressibility, and noise shielding capability. Radiator tank uses N66GF 30% strengthened nylon in more than 60% of bonnet type passenger cars. Nylon resin is used most in harness connectors installed in locations that require heat resistance. External car parts such as bumpers, fenders, and wheel caps use to some extent nylon resin in the form of strengthened and up-graded polymer alloy. BMW in Germany used in its high-class production cars intake manifolds made of GF strengthened Nylon 66. The majority of engine{prime}s gas intake system parts has been replaced with Nylon blow-formed parts. The ...
... Abstract : The beater additive process for manufacturing combustible cartridge cases is superior to the solvent resin, post-impregnation process. ...
A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of "1"3"7Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF ...
A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of {sup 137}Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF ...
In this report, the quantitative relation between the height equivalent to a theoretical plate (HETP) and the size of ion exchange resin is studied by enriching lithium isotopes with high pressure ion exchange displacement chromatography. The dependence of HETP on the size of the resin can be expressed as H = C x (anti r)sup( ) in which = 2.4 and it is found that Snyder's equation is suitable for such a system of isotope separation as may be explained by the simple displacement mechanism.
Phenolic resins have made a major breakthrough in the field of high technology in 80's. These are now active participants of "high tech' areas ranging from electronics, computers, communication, outer space, aerospace, advanced materials, bio materials and technology. A phenol - formaldehyde (1:1.5) resin having resin content of 70% synthesized in the laboratory has been applied for wood coating and reinforcing glass fiber. The weatherability and solvent resistance of these items have been studied and results discussed keeping in view the envisaged application for structural materials and chemical equipment. The toxic materials released during contact with solvents for chemical applications and during degradation general have been monitored. The results are discussed with reference to environmental pollution due to these resins and their composites under different conditions. (authors)
The radiation polymerization of multifunctional unsaturated polyester-monomer mixtures in wood forms interpenetrating network system. The mechanical resistance (compression, abrasion, hardness, etc.) of these composite materials are generally well over the original wood, however the impact strength is almost the same or even reduced, in comparison to the wood itself. An attempt is made using elastic polyester resins to produced wood-polyester composite materials with improved modulus of elasticity and impact properties. For the impregnation of European beech wood two types of elastic unsaturated polyester resins were used. The exothermic effect of radiation copolymerization of these resins in wood has been measured and the dose rate effects as well as hardening dose was determined. Felxural strength and impact properties were examined. Elastic unsaturated polyester resins improved the impact strength of ...
The evolution of these new ion-exchange resins hinges upon an understanding of the chemistry of actinide metal complexes as they exist in solution and when interacting with the cationic sites. Molecular modeling of electrostatic interactions between the metal complex and the cationic substrate is used to help visualize uptake mechanisms and, eventually, to predict optimized coordination sites. Thus, these new materials integrate the fields of ion-specific chelation and ion-exchange technology. Synthesized resins contain cationic sites designed to facilitate the uptake of plutonium nitrato complexes from high-nitrate solutions, and they exhibit distribution coefficients that are up to 10 times higher than those observed for commercial resins. Additionally, some new resins show surprisingly large Kd`s for anionic complexes of Am(III) and U(VI).
Benthic invertebrates can uptake metals through diffusion of free ion solutes, or ingestion of sediment-bound forms. This study investigated the efficacy of the metal chelating resin SIR 300TM in adsorbing porewater metals and isolating pathways of metal exposure. A field experiment (Botany Bay, Sydney, Australia) and a laboratory toxicity test each manipulated the availability of porewater metals within contaminated and uncontaminated sediments. It was predicted that within contaminated sediments, the resin would adsorb porewater metals and reduce toxicity to invertebrates, but in uncontaminated sediments, the resin would not significantly affect these variables. Whereas in the laboratory, the resin produced the predicted results, in the field the resin increased porewater metal concentrations of contaminated sediments for at least 34 days and decreased abundances of four ...
This paper introduces marketability and parts application of PBT in the automotive field. Based on the pursuits in automobiles of weight reduction as measures to improve engine performance, drive performance, and fuel consumption, as well as trends of higher class car orientation, market expansion is expected on engineering resins including PBT. Adoption of PBT/polycarbonate (PC)-based alloy resins is on increase for use in external car parts because of the chemical resistance in PBT, low-temperature shock resistance and appearance of PC. Substitution from Nylon resin in connector application is progressing rapidly because of problems in dimensional stability and compound noise. Air bag sensor parts need to be free of maloperation due to contamination and corrosion in metal contacts caused from gases generated from formed parts, hence development of resins of low gas generation grade is wanted. Valves ...
The treatment and disposal of oily waters from oil production and refining processes represent an important technological pass for attendance of the ambient legislation and to the politics of the Cia of search of the environmental excellence. The reuse or reinjection of the co-produced water has been considered an interesting strategical alternative, however, the water quality requirement for these processes demands a pretreatment step, considering the exit effluent from primary and secondary treatment processes currently used. This work presents resulted of the polymeric resin development for tertiary treatment of oily waters with low oil and grasses content and fine solids, including the dissolved fraction. These resins can adsorb, in reversible form, organic components. Its high adsorption capacity is determined by the polarity, superficial area, range of porosity and a wide distribution of particle size and pore. Another important ...
Decomposition of organic compounds contained in the spent ion exchange resins is considered effective in reducing the waste volume. A system using the wet-oxidation process has been studied for the treatment of the spent resins stored at Trino Nuclear Power Plant owned by SOGIN. Compared with various processes for treating sludge and resin, the wet-oxidation system is rather simple and the process conditions are mild. Not contaminated ion exchange resin samples similar to those ones used in Trino NPP were processed by wet-oxidation and appropriate decomposition of the organic compounds was verified. After decomposition the residue can be solidified with cement for final disposal. When compared with direct solidification without decomposition, the number of waste packages can be significantly reduced. Additional measures for conditioning secondary waste products have also been studied, and their ...
The effects of the rate of resin addition and moisture content (MC) on the static bending properties and creep behavior of phenol-resin-treated particleboards are investigated. The modulus of rupture (MOR) of phenol-resin-treated boards shows the maximum value at 7 to 9 percent MC and large decreases at 19 to 28 percent MC, retaining values about 30 to 40 percent lower than those in the oven dry condition. The bending property is improved with the increase of low molecular weight resin content, and the tendency is obvious when MC is high. Creep compliance tends to increase with the increase of MC, and the rate of increase is larger with smaller resin content. The value of creep compliance after 48 hours under load becomes about 1.8 times the value in the dry condition at 7 to 9 percent MC, and about 2 times the value when MC increases to 19 to 27 percent from 7 to 9 percent. In ...
Volume sources is used for standard sources by radioactive measurement using Ge semiconductor detector of environmental sample, e.g. water, soil and etc. that require large volume. The commercial volume source used in measurement of the water sample is made of agar-agar, and that used in measurement of the soil sample is made of alumina powder. When the plastic receptacles of this two kinds of volume sources were damaged, the leakage contents cause contamination. Moreover, if hermetically sealing performance of volume source made of agar-agar fell, volume decrease due to an evaporation off moisture gives an error to radioactive measurement. Therefore, we developed the two type methods using unsaturated polyester resin, vinilester resin, their hardening agent and acrylicresin. The first type is due to dispersing the hydrochloric acid solution included the radioisotopes uniformly in each resin and hardening the ...
The paper describes uptake of gaseous lodine-131 on silver impregnated organic resin, Amberlite IR-120, available at the Secondary Steam Generator (S.S.G.) Opening at T.A.P.S. in comparison with activated charcoal. The experiments are conducted in dry and wet conditions by soaking the impregnated resin and activated charcoal in distilled water for wet condition. The paper also describes the iodine sampler specially designed and fabricated for these experiments.
A report is given on an improved filler-binder mixing method in the manufacture of artificial graphite, the so-called coat-mix process. The individual graphite-filler grains are coated completely with uniform binder coatings (phenol formaldehyde resin) in a continuous process. Methanol is used as solvent for the resin. In a modified further development of the process, the use of organic solvents can be disregarded by dissolving the binder resin in caustic soda and injecting the slurry into water diluted acid. The manufacture of casting molds from coat-mix powders, their properties and industrial application are given. Finally, the advantages of using carbon bodies of coal-mix material for conversion to silicon carbide are indicated. (IHOE).
The report is divided into three sections. The first section contains a general introduction to ion exchange resins used in various processes, the second section describes characteristic properties of the polymer materials and the inter relation between them. This will, in turn, be useful to interpret the data obtained from the various tests carried out on the resins in the laboratory. In the third section of the report, are given the details of each method used for a particular test to be carried out on a routine basis. Each method describes the principle involved, the reagents and apparatus used in the experiment, the actual procedure and calculations and recording of the data. 3 refs. (author).
The novolac type phenolic resins were synthesized and electron beam curing was carried out to the prepolymer obtained by the reaction of the phenolic resin and glycidyl meth acrylate in the presence of triethylbenzyl ammonium chloride. When the prepolymer and its mixtures with monomers were irradiated using electron beams at a dose rate of 3 Mrad/sec, the curing were completed at a dose 2.5 and 3 Mrad respectively. The effects of oxygen and that of hydroxyl group in the prepolymer on electron beam curing were also examined. (author).
Three bonding agents were evaluated to determine which were most effective in enhancing the bond of resin composite to stainless steel. A light-activated resin composite was bonded to a total of 60 stainless steel specimens using Panavia, Cover-Up, or Silicoating. Tensile bond strength measurements revealed that all three agents provide a satisfactory means of increasing adherence of the esthetic veneer without decreasing bonding through thermocycling of the specimens. Panavia and Cover-Up were significantly more effective than Silicoating and appear to be easier to use. PMID:8297460
Total anthocyanins in different cultivars of mulberry were measured and a process for the industrial preparation of mulberry anthocyanins as a natural food colorant was studied. In 31 cultivars of mulberry,...Full Text Available
Aesthetic dentistry continues to evolve through innovations in bonding agents, restorative materials, and conservative preparation techniques. The use of direct composite restoration in posterior teeth...Full Text Available
The purpose of the present work is to investigate the effects of matrix resin and fiber content on the behavior of fatigue crack propagation in continuous-glass-fiber-mat reinforced CP-resin composites. For this purpose, ductile matrix resin and brittle one are used. These two kinds of resins have the characteristic that the elastic modulus and tensile strength are nearly the same with each other while the elongation is different. The composite specimens are made of these resins and continuous grass fiber mat of 20 wt.% and 60 wt% fiber contents. The fatigue crack propagation test was conducted by using the tapered DCB specimens to control the stress intensity factor range, {delta}K, during the test. The results obtained are as follows; (1) The relation between the crack propagation rate, da/dN, and {delta}K for all the present materials is shown by a straight line in logarithmic ...
... Abstract : The structural features of 25mm combustible cartridge cases, manufactured for this program and having nitrocellulose/resin/fiber ratios of ...
The synthesis, characterization, and some analytical applications of a new triazine resin are described. Separation of group IB, IIB, VIB, and VIIB metal ions from group VIII metal ions is achieved by this PDT-4 resin. Calcium(II) and magnesium(II) are taken up at pH = 6, 0.1 M acetate and are eluted at pH = 6, 0.1 M sodium nitrate. Copper(II) is retained at pH = 6, 0.1 M acetate and pH = 1 hydrochloric acid and is eluted subsequently by 5 M perchloric acid. Molybdenum(VI) is sorbed selectively from 0.1 N sulfuric acid or hydrochloric acid and is eluted in a tight band by 0.1 N sodium hydroxide. Numerous rapid column chromatographic separations are reported using this new resin, including analysis of NBS standard samples.
For the purpose of solving the limitations such as shape and dimension for magnetic compact fabricated by conventional anisotropic forming under magnetic orienting field, the feasibility of a new magnetic forming process was studied. Ferrite powder mixed with UV resin was compacted in the die mold and followed by alignment under the magnetic field. Effects of viscosity of UV resin and forming condition on magnetic characteristics of the compact was investigated. Maximum degree of alignment for the ferrite powder reached to 0.826. It was predicted that the proposed method had make it possible to fabricate a high performance magnet having the anisotropic alignment of the magnetic powder. The UV resin is desirable to have low viscosity, good properties such as formability and configuration stability for the compact and also parting- ability between the metal mold and the compact. (author)
Novel and unprecedented ion exchange resin cleaning system, for use in BWR plants and featuring a vibration separator and basic design factors of Radiological Solutions, Inc., had been delivered to Tokai No. 2 Power Station, Japan Atomic Power Company, in October 2005. This compactly-designed system effectively separates crud and resin fines from ion exchange resins, with no clogging of separation screens. It generates minimized waste liquid and has a specially designed over-pack cleaning tank. The system has been in operation for about 2 years and half now and favorable operational data, such as crud and sulfate concentration decrease in feed water and reactor water respectively, and evaluation results have been reported from Japan Atomic Power Company and so on. (author)
... turbine blade heat-transfer and study the heat-transfer augmentation in idealized geometry and its ... responsible for heat transfer augmentation. ...
Polyamide is a modifier which introduces flexibility and toughness to phenolic foam by non reactive approach. Phenol formaldehyde resin was physically modified by the addition of polyamide in different percentages ranging from 0.05% to 0.2% which introduced toughness to modified resole. The resultant polymers were characterized by thermal and mechanical analysis using Thermogravimetric Analyzer (TGA), Instron machine and Dynamic Mechanical Analyzer (DMA). (author)
The use of Chelex resin for the synthesis of radioactive lead complexes has been explored. The process involved immobilization of {sup 203}Pb on the resin and subsequent elution of complexed lead by chelating agents. {sup 203}Pb complexes derived from meso- and racemic dimercaptosuccinic acid (meso-DMSA, rac-DMSA) were prepared and assessed for stability in vitro.
The use of Chelex resin for the synthesis of radioactive lead complexes has been explored. The process involved immobilization of "2"0"3Pb on the resin and subsequent elution of complexed lead by chelating agents. "2"0"3Pb complexes derived from meso- and racemic dimercaptosuccinic acid (meso-DMSA, rac-DMSA) were prepared and assessed for stability in vitro.
Wood/polymer composites (WPC) have been prepared from pinewood with different compounds using gamma irradiation: butyl acrylate, butyl methacrylate, styrene, acrylamide, acrylonitrile, and unsaturated polyester styrene resin. The polymer loading was determined with respect to the compound concentration and the irradiation dose. The polymer loading increases generally with increase in the monomer or polymer concentration. Tensile and compression strength have been improved in the four cases, but no improvement was observed using unsaturated polyester styrene resin or acrylamide.
Details of a series of reactions for the production of ethylene glycol using a catalyst of Nafion solid perfluorosulfonic acid resin was detailed. The reactions included the carbonylation of formaldehyde and esterification and then hydrogenation of the product of the carbonylation, glycolic acid. Other preparations included in the work included methyl glycolate, acetylglycolic acid, methyl acetylglycolate, and methyl methoxyacetate.
Recent nuclear power plants require high purity water to protect nuclear reactors or steam generators from SCC and maintain in good condition. In this connection, it is especially important to minimize sulfate, which is a corrosive chemical originated from oxidative degradation of cation exchange resins during operation. Recently, uniform particle size (UPS) strong acid cation gel resin with 14% cross-linkage, which has excellent stability against oxidization, has been applied to several condensate purification systems. For further improvement of water quality, some methods for changing the configuration of condensate demineralizer's resin bed have been examined. For example, these methods correspond to anion under layer and cation over layer. We have tested these methods by cold column tests. Furthermore, we have developed the newly anion exchange resin having higher efficiency and capacity for ...
It is needless to say that one of the most important roles of the condensate demineralizer in Japanese boiling water reactors (BWR) is to eliminate such impurities during accidental occurrence of sea water leakage from condensate cooling system. Ion exchange resins packed in condensate demineralizer have also been expected to decrease crud, or corrosion products (CP) in condensate water in order to finally reduce activated corrosion products (ACP) in the reactor coolant loop. It is perceived that crud removal ability of a condensate demineralizer has been improved year by year. And we call this phenomenon as `Aging Effect`. Typical property changes of aged cation exchange resin consisted of an increase of water retention capacity and a change of surface texture. Based on these findings, we formulated a new concept and developed new gel type ion exchange resins for the better crud removal. The results from column tests using ...
To reduce the cost of the formed coke briquettes which can be used as a substitute fuel to the metallurgical coke for the blast furnace from the coke breeze alternative binders and their blends were used. The high temperature behavior was investigated. The binders tested were: the nitrogen blown, air blown coal tar pitch and the blend of air blown coal tar pitch with the phenolic resins blends. The phenolic resin blends were prepared by mixing equal amount of resole and novalac. From the results, nitrogen blowing resulted in the weakest briquettes. The air blowing procedure should be preferred in place of nitrogen blowing for this purpose. When the air blown coal tar pitch was used alone as a binder, the briquettes must be cured at 200^oC for 2h, then carbonized at a temperature above 670^...
Formulas were developed based on an aqueous solution of hydrolyzed polyacrylonitrile widely used in the oil industry. The additive used consisted of products of industrial production: synthetic resin TEG-1 with hardening agent PEPA (polyehtylene polyamine) and technical formalin. The mixtures containing about 80-85% by volume 5% hydrolyzed polyacrylonitrile, 10-15% by volume of resin TEG-1 with hardening agent PEPA and 3-5% by volume formalin satisfy the requirements made for the plugging materials. The initial mixtures are distinguished by technological efficiency of preparation and have controllable hardening periods. Physical-chemical properties are given for the gel polymers. In the set of properties, the mixtures based on hydrolyzed polyacrylonitrile, resin TEG-1 with hardening agent PEPA and formalin can be recommended as plugging materials of temporary action with complex treatment of the heterogeneous beds.
Abstract Flame retardants (FRs) are used for in protection against fire. Organic inorganic hybrids could become one of the most promising FR solution in the future. In this paper, the synthesis, the characterization and the use as FRs and filler of grafted titania and alumina with 2 chloroethylphosphonic acid are presented. These hybrids contain 3.8 3.24% P and have good flame retardance when they are incorporated into unsaturated polyester resins. Alumina treated with 2 chloroethylphosphonic acid performed better than titania. The advantage of this approach is the use of these hybrid materials as filler and FR, in the same time, and the increase in flame retardancy by synergistic effect between alumina phosphorus and chlorine, for unsaturated polyester resins. Copyright 2010 John Wiley & ...
Anion-exchange chromatography of element 105, dubnium (Db), produced in the {sup 248}Cm({sup 19}F, 5n){sup 262}Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (K{sub d}) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta{approx}Nb>Db{>=}Pa. (orig.)
Anion-exchange chromatography of element 105, dubnium (Db), produced in the "2"4"8Cm("1"9F, 5n)"2"6"2Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (K_d) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta#approx#Nb>Db#>=#Pa. (orig.)
Plastics debris in the marine environment, including resin pellets, fragments and microscopic plastic fragments, contain organic contaminants, including polychlorinated biphenyls (PCBs), polycyclic...Full Text Available
Peak expiratory flow rate (PEFR) has been measured hourly from waking to sleeping in 29 workers with respiratory symptoms exposed to the fumes of soft soldering fluxes containing colophony (pine resin)....Full Text Available
Results of the toxicological studies of working conditions, general and professional morbidity, and complex examinations carried out on workers engaged in the production of polyamides, polyacrylonitrile...Full Text Available
A laminated material composed of glass cloth/polyimide film/epoxy resin will be used as an insulating material for superconducting coil of International Thermonuclear Experimental Reactor (ITER). In order to keep safe and stable operation of the superconducting coil system, it is indispensable to evaluate radiation resistance of the material, because the material is exposed to severe environments such as high radiation field and low temperature of 4 K. Especially, it is important to estimate the amount of gases evolved from the insulating material by irradiation, because the gases affect on the purifying system of liquid helium in the superconducting coil system. In this work, the gas evolution from the laminated material by gamma ray irradiation at liquid nitrogen temperature (77 K) was investigated, and the difference of gas evolution behavior due to difference of composition in the epoxy resin was discussed. It was found that the main gases ...
In the second part of this paper the author concludes his examination of the application of thermoplastic materials and also considers alumina ceramics, cast basalt and glass, rubbers, resins and wear-resistant steels
Low molecular weight epoxy resin based on diglycidyl ether of bisphenol A was synthesized and mixed at constant percentages with natural rubber. The rubber epoxy system was cured with various types of curing agents such as ethylene diamine, maleic anhydride as well as the prepared resole phenol formaldehyde. A study of the photo-induced crosslinking of the prepared elastic adhesives and film samples was carried out by exposure to ultraviolet lamp (300 w) for 2 weeks at 20 deg. C. Samples containing ethylene diamine were cured at 25 + - 1 deg. C. for 24 h while samples containing maleic anhydride or resole phenol formaldehyde resins were thermally cured at 150-170 deg. C. for 10 min. Cured adhesive compositions were tested mechanically and physically and evaluated as wood adhesives. While hardness, chemical resistance as well as heat stability of the prepared cured film sample were investigated. The obtained data indicate that the highest epoxy ...
This invention relates to the production method of composite electrode substrate for fuel cell. An impermeable material is used for edge sealant. The sealant is put in the clearance between two electrodes consisting of porous carbon material via thermoplastic resin sheet, and heated while being pressed. This production method increases the adherence between the porous carbon bodies and reduces the contact resistivity at the joint interface. Consequently, it becomes possible to produce the composite electrode for fuel cell without separator, resulting in simplification of assembly work, weight reduction, and downsizing. The preferable porous carbon body is made from shrinkage-treated fiber. After sheet forming, the thermosetting resin is impregnated, and then it is burnt to carbonization. Or mixed sheet of rayon and acrylic fiber is laminated to be heated and pressed without impregnating the resin. The pressed ...
The structural features of 25mm combustible cartridge cases, manufactured for this program and having nitrocellulose/resin/fiber ratios of 85/10/5, 80/15/5, 75/20/5 and 75/10/15, were characterized through permeability measurements, respectively, about 10...
Three areas have been investigated: coal liquefaction with supercritical fluids, liquefaction by extraction with high boiling liquid solvents, and the production of resins from coal-derived hydrocarbons. The processes are described.
Simultaneously extracted metals (SEM) and acid volatile sulfide (AVS) show the potential for toxicity on the basis of their ratio. Accordingly, the authors spiked cadmium in a range for which Cd/AVS ratios were from 0.2 to 10 in the sediment with its weight about 8 kg in each batch. Dialysis samplers with a cation ion-exchange resin (Dowex 50W-X4) collection were used in a laboratory for the determination of free cadmium concentrations in pore water of the collected sediment. When equilibrium was reached among cadmium in pore water, sediment, and ion-exchange resin, cadmium exchanged onto resin phase was regenerated with 1 N hydrochloric acid (OPTIMA grade) and determined using an atomic absorption spectrophotometer (Zeeman 5000) with a graphite furnace accessory. Cadmium determined using the dialysis sampler is considered as free cadmium which is related to the metal bioavailability toward aquatic biota. The developed ...
One option in establishing advanced technology for disposing of high-level radioactive waste (HLW) is to remove TRU elements from HLW and then transform them into short-lived radionuclides. Tertiary pyridine-type anion exchange resin was investigated as a separation medium for spent fuel reprocessing using a HCl solution. Distribution coefficients of typical elements, along with uranium, were measured in the pyridine resin--HCl solution system, where HCl concentration was varied from 1 to 9 M. The results reveal: elements of the alkali metal, alkaline earth and lanthanide groups are not adsorbed, the adsorption patterns of the transition metals differ according to HCl concentration, and uranium is adsorbed in the high HCl concentration region. Furthermore, the present report describes the experimental results obtained for the adsorption behaviour of uranium, americium, curium and various lanthanide elements on tertiary pyridine-type anion ...
This is the first text and reference book to be devoted completely to the very important and timely subject of heat transfer augmentation. This book is of equal appeal to both researchers and designers of heat transfer equipment.
Results of an evaluation of 18 different products that can be used as waterstops in hydraulic dams to minimize or eliminate leaks at construction joints, were discussed. The materials were tested for permeability and adherence at 23, 15 and 5 degrees C. A two-component polyurethane resin product was found to be the one that best fulfilled the evaluation criteria. It was also found that the successful injection of a borehole depends not only on selecting the product with the best performance characteristics, but also on the technique used. Hence the preparation of the resin and the pressure at which it is injected are important performance criteria. 5 refs., 6 photos, 4 figs.
Using standards on phenol-formaldehyde resin base for assaying-activation analysis of geological specimens for gold and silver has bee the advantage of uniformly distributing Au and Ag in spesimens and possible preparing tablets of practically any form or size. The validity and accuracy of these standards have been studied for the cases of short irradiation. Conventional point standards were used as reference standards. The experiments carried out have shown that tablet resol standards are suitable for a mass assaying-activation analysis for gold and silver at practically any concentrations.
The following are reported: colorimetric determination of Ti in Cr, decontamination of metals by anodic dissolution, computer code for x-ray peak identification, gel-permeation chromatography of CoRezyn 1664 polyester resin, infrared monitoring of gases and vapors, particle size analysis of dusts, nondestructive analysis of Oralloy for removable alpha contamination, dissolution (digestion) of high-fired oxides, assay of U in a Pu-U alloy, measurement of oxide thickness on Pu metal by x-ray diffraction, analysis of precipitated Pu peroxide, differentiation of Dowex SBR and 11 resins, and determination of Pu solubility in simulated lung fluid.
A simple and rapid procedure was developed for the purification of cyclotron-produced {sup 203}Pb via the {sup 203}Tl(d,2n) {sup 203}Pb reaction. A Pb(II) selective ion-exchange resin, with commercial name Pb Resin from Eichrom Technologies, Inc., was used to purify {sup 203}Pb from the cyclotron-irradiated Tl target with excellent recovery of the enriched Tl target material. The purified {sup 203}Pb was used to radiolabel the monoclonal antibody Herceptin. The in vitro and in vivo properties of the {sup 203}Pb radioimmunoconjugate were evaluated.
A simple model is outlined to describe the collision of cast phenol-formaldehyde resin spheres such as the balls used in the parlor game of pocket billiards, based in part on the famous analysis of elastic collisions developed by Heinrich Hertz over 100 years ago. The analysis treats the normal and tangential components of the initial sphere's velocity independently as it collides with a stationary identical second sphere. The collective effects of these and other parameters on the trajectory of the second sphere are provided in the conclusions.
Epoxy-resin based neutron shielding material, NS-4-FR, is used for spent fuel transport and/or storage cask. In this paper the outline of thermal aging test performed to evaluate the heating effect on this neutron shielding material, NS-4-FR, is introduced. The test is consisted of two kinds of thermal aging test, one is 'Basic Test' and the other is 'Block Heating Test'. The former is cooperatively performed by ten Japanese Electrical Power Companies, and the latter is done by GESC and NOF Corporation. (authors)
Epoxy-resin based neutron shielding material, NS-4-FR, is used for spent fuel transport and/or storage cask. In this paper the outline of thermal aging test performed to evaluate the heating effect on this neutron shielding material, NS-4-FR, is introduced. The test is consisted of two kinds of thermal aging test, one is 'Basic Test' and the other is 'Block Heating Test'. The former is cooperatively performed by ten Japanese Electrical Power Companies, and the latter is done by GESC and NOF Corporation. (authors)
The purpose of this study was to evaluate the resin-dentin interfacial morphology and shear bond strength of several new and experimental dentin bonding systems classified as single-bottle/total etch, multi-step/total etch, and self-etching. Class 1 and 5 cavities were prepared from freshly extracted permanent molars and restored with composite resin. Each bonded sample was cross sectioned and one-half was completely demineralized and deproteinized, while the other half was polished along the cut surface to permit measurement of the thickness of resin-infiltrated dentin layer (RIDL) within intertubular dentin (iRIDL) and around the peritubular walls (pRIDL) of resin tags by SEM. Shear bond strength was measured for all the systems 2 minutes after photocuring. SEM showed iRIDL and resin tags of different morphology depending on material and dentin location. The iRIDL was thinner in ...
Gadolinium removal during the first approach to criticality of TAPP-4 540 MWe reactor using mixed bed resin (strong acid cation resin and weak base anion resin) topped with strong acid cation exchange resin yielded IX column outlet pH of >6 during the first 6 h of run during which [Gd] decreased from 2.1 to 1 mg/kg. However, the main moderator system pH was between 5.0-5.5. Technical specification for pH of moderator is in the range 5.0-5.5 as long as Gd is present. This is to avoid any precipitation of Gd in the core and a pH of 5.8 or even a pH of 5.6 when carbonate is present is specified as the upper limit of the moderator system pH for this purpose. The situation of IX column outlet pH being #>=# 6 mixing with a system water having Gd results in local mixing zone pH in the range of 6- 5.4. In order to have an iso-pH regime (5-5.5) both with respect to the IX outlet as well as in the system, ...
Addition of Gadolinium Nitrate as chemical shim to moderator heavy water of 540 MWe PHWR, at 15 mg/kg level (at a pH of 5.0) is practiced for reactor shutdown purposes. Presently a strong acid cation exchanger column is used for this purpose. During this operation, the moderator pH of 3.8, with the IX column outlet pH of ?3.5-3.6 was observed against the technical specification demand that when Gd is present, the pH of moderator must be in the range of 5.0-5.5. In order to achieve an iso-pH regime during Gd removal, studies were conducted using a mixed bed of strong acid cation resin plus a weak base anion resin (loaded in the volume ratio of 1 : 6), backed up in the same column (bottom most layer) by a 5 % nitric acid loaded weak base resin and topped by a strong acid cation resin (uppermost layer) simulating system flow velocity and percentage loading of resin. Using such a column ...
This volume is divided into the following sections: (1) fundamentals of convection heat transfer; (2) fundamentals of heat transfer with impinging jets; and (3) fundamentals of heat transfer augmentation. Separate abstracts were prepared for most papers in this volume.
The aim of the study is to prepare ionic exchangers using the polymerization of unsaturated polyster with monomeric styrene units in a ratio of 60%: 40% respectively. The type of method involved in this preparation, is called An Emulsion Polymerization. Such type of polymerization was carried out by two techniques: chemical and irradiation techniques. The first techniques requires the formation of free radical monomers by use of methyl Ethy Ketone Peroxide capable of decomposing into free radicals upon heating, while the other technique involves the use of gamma rays (using Co-60 source) capable of activating monomers towards free radical formations. A number of very effective chemical parameters and physical factors were used and investigated throughout the reactions such as: dispersant matrix, viscosity, rate of mixing, and irradiation dose. Besides, the study has included the study of the rate of Resin Beads Swelling which is thought to be another important part ...
Novel in situ polymerizable liquid three-arm biodegradable oligomeric polyesters based upon glycolic acid (GA), L-lactic acid (LLA), and their copolymers are synthesized and characterized. Injectable and in situ curable polymer neat resins and their composites formulated with bioabsorbable beta-tricalcium phosphate are prepared at room temperature using photo- and redox-initiation systems, respectively. The cured neat resins show the initial compressive yield strength (YCS, MPa), modulus (M, MPa), ultimate compressive strength (UCS, MPa), and toughness (T, kN mm), ranging from 4.0 to 20.1, 201.5 to 730.2, 82.7 to 310.5, and 1.02 to 3.93. The cured composites show the initial YCS, M, UCS and T, ranging from 27.7 to 56.4, 1440 to 4870, 81.6 to 158.9, and 0.94 to 1.97. Increasing GA/LLA ratio increases all the initial compressive strengths of both neat resins and composites. Increasing filler content increases YCS and M but ...
The chemical fixation of tritium in stearic acid followed by embedding the tritiated stearic acid into an epoxy resin proved to be a good method for permanent waste disposal of tritium gas. Tc-126 and Tc-136 hardener were used for this purpose. The polymerization temperature of the polymer products was found to be highly decreased by adding stearic acid and slightly decreased by adding stearic acid or by raising the temperature of the leachant medium and slightly decreased by irradiation. On the other hand, small improvement in the compressive strength of the polymer products was achieved by adding silica powder. The polymer product showed high flame points above 573 K although it contains stearic acid. DTA and TG analysis indicate that the thermal stability of polymer products containing stearic acid and silica powder is better than samples containing only stearic acid. Stearic acid was found to possess good resistance to irradiation and the amount of hydrogen and ...
In this article, the technical feasibility of the use of activated carbon, synthetic resins, and various low-cost natural adsorbents for the removal of phenol and its derivatives from contaminated water has been reviewed. Instead of using commercial activated carbon and synthetic resins, researchers have worked on inexpensive materials such as coal fly ash, sludge, biomass, zeolites, and other adsorbents, which have high adsorption capacity and are locally available. The comparison of their removal performance with that of activated carbon and synthetic resins is presented in this study. From our survey of about 100 papers, low-cost adsorbents have demonstrated outstanding removal capabilities for phenol and its derivatives compared to activated carbons. Adsorbents that stand out for high adsorption capacities are coal-reject, residual coal treated with H{sub 3}PO{sub 4}, dried activated sludge, red mud, and ...
In the stereolithography process, three dimensional parts are built layer by layer using a laser to selectively cure slices of a photocurable resin, one on top of another. As the laser spot passes over the surface of the resin, the ensuing chemical reaction causes the resin to shrink and stiffen during solidification. When laser paths cross or when new layers are cured on top of existing layers, residual stresses are generated as the cure shrinkage of the freshly gelled resin is constrained by the adjoining previously-cured material. These internal stresses can cause curling in the compliant material. A capability for performing finite element analyses of the stereolithography process has been developed. Although no attempt has been made to incorporate all the physics of the process, a numerical platform suitable for such development has been established. A methodology and code architecture have been ...
The possibility of switching the heat transfer consists of varying heat transfer surfaces and making the heat transfer temporarily more intensive. Heat tubes prove to be particularly suitable, which must be exposed to a heat carrier fluid or removed from its effect for switching the heat transfer. This report gives a survey of the possibilities of switching heat flows and for making the heat transfer more intensive. Further, the report contains a survey of patents limited to heat transfer in the fields of cooling internal combustion engines and exhaust systems. (orig.) With 17 figs., 183 refs.
Iron concentration control in feedwater is one of the most important subjects in water chemistry. Especially for the BWR plants without 100% flow volume of hollow fiber filter (HFF), rather high iron concentration in feedwater is one of the big issues as this causes relatively high radiation dose rate in drywell area. Cation exchange resins especially used in the plants with partial flow rate of HFF are expected to have the important role of capturing iron in feedwater. For this purpose, we have investigated the effective method for using iron absorption characteristics of cation exchange resin. The Cation-Over Layer method (COL) in condensate demineralizers (CD) effectively utilizes these characteristics. In order to demonstrate a performance of the cation overlay method, we had applied this method for three CD vessels at Fukushima Daiichi NPP Unit 3 for testing purpose. The result of this actual plant test indicated that the iron ...
A hose lining process, used widely for underground service structures, such as for city gas, and water and sewerage pipes, was adopted to repair interiors of underground wire raceways, and improvements were made for power cable pipe use, including long size construction, inner diameter assurance, and flame retardation. The sealing hose as a lining material consists of a fabric layer woven by warps of polybutylene terephthalate (PBT) and wefts of combined PBT fibers and glassfibers, the fabric being coated with polyurethane resin on one side. The other side of the fabric is coated with heat hardening resin made of epoxy resin as the main ingredient and aromatic amine as the hardening agent to assure close adhesion of the sealing hose onto the pipe interior. Mimic raceways were used to verify the lining material for its abrasion coefficient, mechanical strength, wear resistance, water cut-off performance, chemical resistance, ...
The purpose of this study is to acquire fundamental knowledge about the factors for production and the physical properties of boards when wood powder is used as the main material and powder adhesive is used as the binder in the formation of wood boards under heat and pressure. The effects of temperature for pressing, specific gravity of board, and the ratio of adhesive on bending strength, internal binding force, and size and stability against moisture are investigated. The temperature behavior at the central area of boards under heat and pressure shows similar tendency of stagnation near 140degC which increases thereafter irrespective of the temperature of the hot plate in this experiment. The bending property increases linearly when the resin content is low, and shows the tendency of leveling off gradually when the resin content is larger than 20%. Linear relation with specific gravity if obtained in the 0.6 to 1.0 specific gravity range. ...
The preparation of wood-plastic combinations (WPC) using combined methods for curing intermediate products and final products is described. In the first step, impregnated wood was irradiated using doses of 1 to 10 kGy in the presence of chemical initiators of polymerization. Thereafter, curing of this partly cured impregnating mixture was accomplished in the wood at elevated temperatures with the aid of chemical initiators of polymerization. Impregnation mixtures based on unsaturated polyester resins and methyl methacrylate, and the wood species European Beech (Fagus silvatica) and Black Alder (Alnus glutinosa) were used. The results indicate that this method of preparing WPC allows substantially lower radiation doses to be used, i.e., doses in the range of 1 to 2.5 kGy. These doses gelatinate the impregnation mixture in the wood so that the subsequent curing by chemical polymerization initiators proceeds without the impregnation mixture flowing out of the wood, ...
The preparation of wood-plastic combinations (WPC) using combined methods for curing intermediate products and final products is described. In the first step, impregnated wood was irradiated using doses of 1 to 10 kGy in the presence of chemical initiators of polymerization. Thereafter, curing of this partly cured impregnating mixture was accomplished in the wood at elevated temperatures with the aid of chemical initiators of polymerization. Impregnation mixtures based on unsaturated polyester resins and methyl methacrylate, and the wood species European Beech (Fagus silvatica) and Black Alder (Alnus glutinosa) were used. The results indicate that this method of preparing WPC allows substantially lower radiation doses to be used, i.e., doses in the range of 1 to 2.5 kGy. These doses gelatinate the impregnation mixture in the wood so that the subsequent curing by chemical polymerization initiators proceeds without the impregnation mixture flowing out of the wood, ...
Five cycles of loading, elution, and regeneration were performed to remove technetium from a Hanford waste sample retrieved from Tank 241-AW-101 using SuperLig 639 resin. The waste sample was diluted to 4.95 M Na plus and then was processed to remove 137Cs through dual ion exchange columns each containing 15 mL of SuperLig 644. To remove 99Tc, the cesium decontaminated solution was processed downwards through two ion exchange columns, each containing 12 mL of SuperLig 639 resin. The columns, designated as lead and lag, each had an inside diameter of 1.45 cm and a height of 30 cm. The columns were loaded in series, but were eluted and then regenerated separately. The average technetium loading for the cycles was 250 BV at 10 percent breakthrough. There was no significant difference in the loading performances among the five cycles. The percent removal of 99Tc was greater than 99.94 percent and the average decontamination factor (DF) was ...
The biosorption of Cu(II) from aqueous solutions by valonia tannin resin was investigated as a function of particle size, initial pH, contact time and initial metal ion concentration. The aim of this study was to understand the mechanisms that govern copper removal and find a suitable equilibrium isotherm and kinetic model for the copper removal in a batch reactor. The experimental isotherm data were analysed using the Langmuir, Freundlich and Temkin equations. The equilibrium data fit well in the Langmuir isotherm. The experimental data were analysed using four sorption kinetic models - the pseudo-first- and second-order equations, the Elovich and the intraparticle diffusion model equation - to determine the best fit equation for the biosorption of copper ions onto valonia tannin resin. Results show that the pseudo-second-order equation provides the best correlation for the biosorption process, whereas the Elovich equation also fits the ...
The Swedish State Power Board has together with Nukem, Hanau, West-Germany carried out pyrolysis o powder resins in a pilot plant with a capacity of about 30 kg/hr. The pyrolysis reactor with its afterburner and offgas scrubber system has been operated under steady state condition. About 2200 kg resins have been pyrolysed under November-December 1983 and the decontamination factor for Cs has been measured. Solidification of the residues from the pyrolysis reactor and scrubber water solutions has been carried out and various recipes with cement have been tested. The pyrolysis process has high decontamination factors and no offgas problems as the operating temperature of the reactor is Low. The residues from the reactor are chemically dead and can not cause swelling problems. Compared with a normal cementation process the final waste volume will be reduced with a factor of 4 if also the scrubber water after neutralization is solidified. The ...
ObjectivesThe aim of this study was to evaluate the relationship between micro-tensile bond strength (mTBS) and ultimate tensile strength (UTS) of resin composite restorations in cavities filled by a bulk or incremental technique using the micro-tensile test.MethodsClass I cavities (4mm long, 3mm wide, 3mm deep) were prepared into dentine of sixteen human molars. All cavities were bonded with Clearfil SE Bond and restored with AP-X composite with either a bulk or incremental technique. After storage in water for 24h, the teeth were vertically sectioned to yield two slabs. Each slab was sectioned into three sticks. Sticks of one slab were trimmed into an hourglass of 0.7mm2 area at resin-dentine interface for bond strength measurement while the other sticks were trimmed at the centre of the...
We describe a method for affinity purification of sequence-specific DNA binding proteins that is fast and effective. Complementary chemically synthesized oligodeoxynucleotides that contain a recognition site for a sequence-specific DNA binding protein are annealed and ligated to give oligomers. This DNA is then covalently coupled to Sepharose CL-2B with cyanogen bromide to yield the affinity resin. A partially purified protein fraction is combined with competitor DNA and subsequently passed through the DNA-Sepharose resin. The desired sequence-specific DNA binding protein is purified because it preferentially binds to the recognition sites in the affinity resin rather than to the nonspecific competitor DNA in solution. For example, a protein fraction that is enriched for transcription factor Sp1 can be further purified 500- to 1000-fold by two sequential affinity chromatography steps to give Sp1 of an estimated 90% ...
The project is intended to yield information on the transfer factors describing the transfer of ingested radionuclides to breast milk for the following elements: antimony, cerium, chromium, cobalt, gallium, lanthanum, molybdenum, niobium, radium, ruthenium, silver, thorium, titanium, and uranium. Those yet unknown or poorly known transfer factors are required in order to be able to develop a reliable model for description and assessment of the transfer of the radionuclides and the possibly resulting hazardous doses to infants, and for subsequent formulation of recommendations for radiological protection of the population. (orig./CB)
Technetium transfer from soil to edible parts of various agricultural plants is studied with application of the "9"5"mTc radioactive tracer. The samples of agricultural plants were grown on andesol typical for Japan soil. The technetium transfer factor to edible parts of cultivated lettuce was higher as compared to non foliate cultures. Relative low transfer factor were observed for fruit and pod like plants. the transfer factors for root crops were of intermediate value
Heat transfer augmentation by straight grid spacers in rod bundles is studied for single phase flow and for post critical heat flux dispersed flow. The heat transfer effect of swirling grid spacers in single phase flow is also examined. Governing heat transfer mechanisms are analyzed, and predictive formulations are established. For single phase flow, the local heat transfer at a straight spacer and at its upstream or downstream locations are treated separately. 18 refs.
Several aspects of heat transfer at the annular two phase flow regime are considered. Nucleate boiling is supposed to be absent. Theoretical solutions for cases of laminar and turbulent flow in the liquid film, respectively, are considered, when steam presence does not effect the heat transfer. Heat transfer in annular flows is also considered, where steam phase consists totally or partially of the so-called incondensable gas. In this case steam phase can be a considerable resistance to heat transfer.
This book contains nine selections. Some of the titles are: High Heat-Flux, Forced-Convection Heat Transfer for Tubes with Twisted-Tape Inserts; Heat Transfer Augmentation by Interrupted Surfaces - Experimental Consideration; Turbulent Flow Heat Transfer from Externally Roughened Tubes in Axial Flow in Concentric Pipe Heat Exchangers; and Heat Transfer Enhancement of Turbulent Flow in Pipes with an Internal Circular Rib.
This book contains nine selections. Some of the titles are: High Heat-Flux, Forced-Convection Heat Transfer for Tubes with Twisted-Tape Inserts; Heat Transfer Augmentation by Interrupted Surfaces - Experimental Consideration; Turbulent Flow Heat Transfer from Externally Roughened Tubes in Axial Flow in Concentric Pipe Heat Exchangers; and Heat Transfer Enhancement of Turbulent Flow in Pipes with an Internal Circular Rib.
Purpose: To enable the use of a vacuum container under a relatively high temperature or a high level radioactive dose. Constitution: Vacuum sealing materials for use in a vacuum container are made of resins such as polyimide and polyamide. The sealing materials are joined to the both surfaces of a plate-like insulator by means of adhesives or sealants, or the sealing materials are joined between two plate-like insulators by means of adhesives or sealants. They are situated within grooves of both of flanges, which are clamped tightly by insulation bolt and nut. Since the vacuum sealing materials are joined to the insulator by means of the adhesives or sealants, the reliability of the vacuum sealing can be improved without impairing the electrical insulation. The resin of the vacuum sealing material can be used for the radiation dose up to 10"8 rad, temperature up to 250"0C or more. (Seki, K.).
A method, based on anion exchange chromatography, is presented for the isolation of "1"3"9Ce after production by a proton-induced nuclear reaction on a thick praseodymium target. After bombardment the target is dissolved in nitric acid and "1"3"9Ce oxidised to the Ce(IV) oxidation state with bromic acid. "1"3"9Ce is then separated form the praseodymium by anion exchange chromatography on a Ag MP-1 resin column in a nitric acid - bromic acid mixture. "1"3"9Ce is sorbed onto the resin column and praseodymium eluted with the acid mixture. The bromic acid is washed out of the column with nitric acid and "1"3"9Ce finally eluted with dilute nitric acid containing sulphur dioxide.
We prepared macromer-grafted polymers (MGPs) containing suitable polymer side chains for improving solubility and pyrene units for improving adsorption on multiwalled carbon nanotube (MWCNT) surfaces, and demonstrated that these MGPs act as MWCNT solubilizers that improve solubility of MWCNTs in typically poor solvents such as alkanes and that improve flowability of polymer/MWCNT composites. The polydimethylsiloxane (PDMS)-MGPs, synthesized using PDMS macromers and pyrene-containing monomers, improved solubility of MWCNTs not only in chloroform but also in hexane, which is a poor solvent for MWCNTs. Moreover, the addition of PDMS-MGP-adsorbed MWCNTs (MWCNT/PDMS-MGPs) to epoxy resin monomers or polybutylene terephthalate (PBT) drastically reduced the viscosity of the obtained epoxy resin mo...
A novel adhesive for carbon materials composed of phenol-formaldehyde resin, boron carbide and fumed silica, was prepared. The adhesive property of graphite joints bonded by the above adhesive treated at high-temperatures was tested. Results showed that the adhesive was found to have outstanding high-temperature bonding properties for graphite. The adhesive structure was dense and uniform even after the graphite joints were heat-treated at 1500 deg. C. Bonding strength was 17.1 MPa. The evolution of adhesive structure was investigated. The results indicated that the addition of the secondary additive, fumed silica, improved the bonding performance greatly. Borosilicate phase with better stability was formed during the heat-treatment process, and the volume shrinkage was restrained effectively, which was responsible for the satisfactory high-temperature bonding performance of graphite.
A simple method is presented for the separation of lead-203 from copper-backed thallium cyclotron targets. The procedure involves cation-exchange chromatography in hydrochloric acid and hydrochloric acid-acetone mixtures. Further purification involves anion-exchange chromatography in nitric acid-hydrobromic acid mixtures. A cation-exchange column containing 3.0 g of resin can handle as much as 15 g of thallium and 160 mg of copper. An anion-exchange column containing 3.0 g of resin can separate lead from up to 200 mg of thallium and 10 mg of copper. Separations are extremely sharp and less than 0.1 ..mu..g of thallium and less than 0.1 ..mu..g of copper remain in the lead-203 fraction.
A simple method is presented for the separation of lead-203 from copper-backed thallium cyclotron targets. The procedure involves cation-exchange chromatography in hydrochloric acid and hydrochloric acid-acetone mixtures. Further purification involves anion-exchange chromatography in nitric acid-hydrobromic acid mixtures. A cation-exchange column containing 3.0 g of resin can handle as much as 15 g of thallium and 160 mg of copper. An anion-exchange column containing 3.0 g of resin can separate lead from up to 200 mg of thallium and 10 mg of copper. Separations are extremely sharp and less than 0.1 #mu#g of thallium and less than 0.1 #mu#g of copper remain in the lead-203 fraction. (author).
In this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewater treatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the...
A simple and rapid procedure was developed for the purification of cyclotron-produced "2"0"3Pb via the "2"0"3Tl(d,2n) "2"0"3Pb reaction. A Pb(II) selective ion-exchange resin, with commercial name Pb Resin from Eichrom Technologies, Inc., was used to purify "2"0"3Pb from the cyclotron-irradiated Tl target with excellent recovery of the enriched Tl target material. The purified "2"0"3Pb was used to radiolabel the monoclonal antibody Herceptin. The in vitro and in vivo properties of the "2"0"3Pb radioimmunoconjugate were evaluated.
Using the radiation chemical method it is possible to prepare wood-plastic composites using doses of 1 to 2.5 kGy. The impregnation mixture in the wood gelatinates and subsequent curing using chemical initiators takes place without outflow of the mixture from the wood and without formation of incrustations. The basic components of the impregnation mixtures used were unsaturated polyester resins; styrene or methyl methacrylate was used as the thinner. The proven initiator of polymerization was 2,2'-azobisisobutyronitrile. The technology is described of wood impregnation and radiation or chemical curing. The effects were monitored of viscosity, temperature, radiation dose and the concentrations of the individual components of the impregnation mixtures and initiators of polymerization on the process of the preparation of wood-plastic composites.
The volatility of some elements being determined in biological and environmental samples by NAA (neutron activation analysis) in case of their binding with phenolformaldehyde resin (PFR) is studied. Since the temperature is assumed to influence the volatility of elements stronger than radiation during irradiation of samples in nuclear pile the losses of Se, As, Sb, and Hg form samples on the basis of PFR after their heating at 100-300 deg C have been investigated. It is shown that the losses of Sb and As up to 300 deg C, Se up to 250 deg C, and Hg up to 150 deg C from PFR - based samples do not occur.
The improving uranium extraction efficiency of yellow cake production from shale deposit by acid pugging and curing with D263B resin adsorption is described in this paper. The analysis and examination show that the composition of uranium minerals in one of uranium ores is very complex, which directly influence the extraction efficiency of uranium and processing technology. Conventional experimental results indicate that uranium leaching efficiency is changed between 50?60% by conventional agitation method. In this case, acid pugging and curing experiments are employed in order to improving the extraction efficiency. A series of acid pugging and curing experiments are carried out to get parameters for heap leaching in pilot plant experiment. The experiment results by acid pugging and curing technology showed that uranium leaching efficiency can reach to 90% of extraction efficiency mixed with 1% manganese dioxide, 12% sulfuric acid pugging, curing 3 days and leached ...
The objectives of the project were to make significant improvements in the production of stall regulated blades in the areas of (a) the tip box, its housing, its mechanism and small GRP parts; (b) mould technology; (c) resins and glues and (d) root tooling. Although wood composite had been identified as a competitive technology for blades, compared with GRP blades, production volumes had been lower; reasons are given. The way in which the four areas identified for investigation were tackled are discussed. The study showed that the mould cycle time can be reduced to two days for a stall regulated blade and the blade quality can be improved by using the composite tip box and new resins. The time required for replication of moulds can be reduced by 40%.
Electrical penetration assemblies mounted on the containment wall are used to carry electrical power and signals from the equipment inside this containment (e.g. recirculation pumps, control rod position indications etc.) Todays BWR nuclear power plants apply epoxy resin sealed electric penetration. Contrariwise, the epoxy resin (organic sealant) was replaced with sodium barium glass (inorganic) by way of trial in search for a quality sealant. The glass sealant has been proved to have high temperature airtightness at 300 degC above from an evaluation test involving full-scale model parts. Environmental tests were conducted continuously as to heat cycle, vibration and LOCA etc. the specimens (module) of five types. They were made certain of conformity to the design requirements for boiling water operation. (author).
Describes a process for production of briquets for metallurgy with binder and coke fines or anthracite. The suggested binder is waste phenol resin from the production of phenol (cumene method). Resin properties are given. Possible reaction mechanisms yielding solidified matter are discussed. The production process requires 10-15% binder and applies charge heating up to 200 C over 30 min. Catalytic amounts of sodium hydroxide or sulfuric acid were also employed. The production process is shown in a flowsheet. Properties of produced briquets are tabulated. The briquets were used in a 8 t/h cupola furnace and their performance was compared to that of KL-1 coke. Performance was found to be comparable; the cost of coke briquets was less than that of heating coke. 2 refs.
Wood-Polymer Composites (WPC) was prepared from recycled films of agricultural use and wood wastes, and LLDPE and neat PE resin mixture were also utilized in order to compare the properties. Maleic anhydride (MA) and dicumyl peroxide were used as an adhesion promoter and an initiator, respectively. Tensile properties of WPC were measured via tensile test as a function of wood filler and MA content, and fracture surface was also investigated with SEM. As the content of wood filler increased, elongation decreased but modulus increased. However, tensile strength of WPC increased only when MA was used, and 1 wt.% of MA may be high enough to increase the tensile properties. The tensile properties of WPC prepared from recycled PE films were almost same as those of neat PE resin mixture. (author). 18 refs., 5 figs.
Charge-charge interactions dramatically influence the dissociation and proton transfer reactivity of large multiply protonated ions. In combination with tandem mass spectrometry, proton transfer...Full Text Available
... mass of gray gas by thermal radiation; An experimental study of the turbulent wake behind a cone at M = 5; Heat transfer augmentation by steady ...
heat transfer augmentation was found to increase with decreasing length scale but no optimum length scale was found. Heat transfer augmentation due to turbu- ...
The results of the thermal dissolution of Barzas sapromyxite coal in benzene under supercritical conditions in a flow system are reported. It was found that the mechanical pretreatment of coal under intense impact bending conditions resulted in an increase in the yield and a change in the group composition of the liquid products: in the high-temperature region of the process, the concentration of high-molecular-weight components (preasphaltenes, asphaltenes, and resins) increased.
As a new production technique of yellow cake, resorption with loaded resin-elution with acid ammonium nitrate-precipitation in two steps is studied. The results show that the produced yellow cake by the new production technique has better performance of settlement, filtration and dehydration. Each index of yellow cake accords with the first grade level issued by CNNC without washing, uranium and water content are 70% and 25%, respectively
The principle for working out the time-temperature schedule of the carbonization was determined through the investigation on the carbonization process of the green body and the phenol formaldehyde resin. During the carbonization process, the crack at lower temperatures is due to strain inhomogeneity produced in press. But the crack at higher temperatures results from the improper increasing rate of temperature. The application of the autoclave-carbonization process can increase the mechanical properties of the spherical fuel elements.
A description is given of sinterable powders and methods of producing sintered products using such powders. The powders consist of (a) a particulate ceramic material, e.g. SiC, having specified particle size and surface area; (b) a carbon source material, e.g. sugar or a phenol-formaldehyde resin; and (c) a residue from a solution of H3BO3, B2O3, or mixtures of these as sintering aid. (U.K.).
Only two years ago, plastic film recycling was considered an onerous task. Different resins had to be identified, colors had to be separated, and minute contaminants had to be weeded out almost by hand to produce a quality material. But the tide of plastic film recycling is changing now that new technologies have emerged and more organized collection infrastructure have been developed. Today, plastic film recycling maintains a lucrative market for those with the right combination of equipment and know-how.
A phantom simulation imaging quality control device is described that effectively simulates one centimeter lesions, using steel ball bearings as gamma ray attenuators. The bearings are mounted in a synthetic resinous sheet in an orthogonal pattern. The phantom can provide uniformity, resolution, linearity, distortion and field size checks, all with a single exposure.
New standardization techniques of samples in multielement instrumental neutron-activation analysis (INAA) of biological materials (BM) are considered. New methodical developments of sample preparation techniques, BM tableting, creation of comparison standards and standardization of packing material are suggested. Correlated data on concentration of different elements in standard specimens-comparison standards are presented for mass INAA, that is: for phenol-formaldehyde resin-base and human blood-base synthetic standards. 7 refs.; 3 tabs.
Achievements in the field of sorption recovery of uranium from sea water are considered in brief. Polyacryl amidoxime chelate iorites are shown to exceed in sorption properties both titanium dioxide base natural adsorbents and styrene base synthetic resins. Merits of sorbents containing fixed layer of humic acid are pointed out, different methods of their application are considered. The cost of uranium recovery from sea water using different sorbents is estimated.
The long-term durability of bonds between adhesive resins and dentin is of significant importance for the longevity of bonded restorations. We carried out an in vivo one-year study to evaluate the durability of resin-dentin bonds in the oral cavity, as well as to test the hypothesis that the adhesive interface would show morphological changes in vivo over time. Very shallow saucer-shaped dentin cavities were prepared in 12 intact teeth of one Japanese monkey (Macaca fuscata) under general anesthesia. The cavities were restored with Clearfil Liner Bond II and Clearfil Photo Posterior resin composite. The teeth were extracted at three different times: immediately, and 180 and 360 days after placement of the restorations. One day after the monkey was killed, specimens of the three time periods were subjected to the micro-tensile bond test at a crosshead speed of 1 mm/min. The surfaces of the failed bonds were observed under a ...
Silicon/carbon composite anode materials were prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with silicon and graphite powders. Scanning electron microscopic (SEM) observation showed that the morphology stability of the composite electrodes can be retained during cycling. A structure evolution mechanism is proposed to illuminate the enhancement of cycleability of the composite electrode. The composite used as anode material for lithium ion batteries possesses a reversible capacity of over 700 mAh/g.
A radiochemical method of separation of {sup 203}Hg from {sup 181}Hf is described. The method involves separation by Dowex 50W- X 8, 100-200 mesh, cation exchange resin using 1 M hydrochloric acid as the eluant. The chemical yield for the separation of mercury is > 85% and the decontamination factor is >10{sup 4}. The {sup 181}Hf can be eluted from the column by 4 M HCl.
Acoustic waves propagation of in composite of water with embedded double-layered silicone resin/silver rods is considered. Approximate values of effective dynamical constitutive parameters are obtained. Frequency ranges of simultaneous negative constitutive parameters are found. Localized surface states on the interface between metamaterial and ``normal'' material are found. Doppler effect in metamaterial is considered. Presence of anomalous modes is shown.
Proton and neutron transfer populating low-lying states have been studied in the system {sup 144}Sm+{sup 88}Sr at an energy below the Coulomb barrier. The experimental cross sections for the single proton transfer are well reproduced by DWBA-calculations using spectroscopic information from light ion reactions. The two-proton transfer appears enhanced relative to the uncorrelated sequential transfer of single protons. The same holds for the transfer of proton pairs, the enhancement is kept for the second pair. This is interpreted as a supercurrent between two superfluid nuclear proton-pair wave functions: More mass and charge is transported per time unit in pairs than by single nucleons. Neutron transfer is observed with large cross sections and is found to contribute to the energy loss observed in the transfer reactions. For mixed ...
Proton and neutron transfer populating low-lying states have been studied in the system "1"4"4Sm+"8"8Sr at an energy below the Coulomb barrier. The experimental cross sections for the single proton transfer are well reproduced by DWBA-calculations using spectroscopic information from light ion reactions. The two-proton transfer appears enhanced relative to the uncorrelated sequential transfer of single protons. The same holds for the transfer of proton pairs, the enhancement is kept for the second pair. This is interpreted as a supercurrent between two superfluid nuclear proton-pair wave functions: More mass and charge is transported per time unit in pairs than by single nucleons. Neutron transfer is observed with large cross sections and is found to contribute to the energy loss observed in the transfer reactions. For mixed proton-neutron ...
A method of augmenting heat transfer in the interior of a fluid or from the interface of a solid in contact to a fluid by utilizing electro hydrodynamic (EHD) phenomena has the following advantages: the heat transfer can be effected by using a relatively small, light-weight high voltage source and some simple structural members; no vibration and noise are generated; the method has a control function to control heat transfer by adjustment of field and voltage; and this method is effective in cost-saving. It is mass transfer by the electric force caused by interaction between true charges or polarized charges in a fluid and external electric filed that plays an important role in most of such heat transfer augmentation methods by EHD. Examples of heat transfer augmentation by EHD phenomena include electricaly induced convection, contribution of EHD effect to heat ...
This paper deals with construction types of high temperature heat exchangers, their circulation loops and temperature differences. Most attention is given to gas dynamics, convective heat transfer, convection and radiant heat transfer interaction in high temperature heat exchangers. The ways of heat transfer augmentation and efficient heat exchanger construction are discussed.
Heat transfer has emerged as a leading-edge technology supporting the rapid pace of developments in science and engineering ranging from energy production to electronic cooling. Subjects covered at the 6th UK National Conference on heat transfer held at Edinburgh from 15-16 September 1999 include: convection; boiling and evaporation; condensation; numerical techniques; heat exchangers; radiation and combustion; conduction; two-phase flow and heat transfer augmentation. Fifteen of the papers are abstracted here.
Experimental investigation was carried out for friction factor and heat transfer coefficient in the case of a rotating tube with a twisted-tape insert for heat transfer augmentation. The data obtained were compared with existing data for a stationary tube with a twisted-tape insert. It has been observed that the enhancement in heat transfer offsets the rise in friction factor due to rotation, with respect to a plain tube under stationary conditions. A correlation has been proposed for the data obtained.
In this paper, numerical simulation of a concentric tube heat exchanger is presented to determine the convective heat transfer coefficient and friction factor in a smooth tube. Increasing the convective heat transfer coefficient can increase heat transfer rate in a concentric tube heat exchanger from a given tubular surface area. This can be achieved by using heat transfer augmentation devices. This work constitutes the initial phase of the numerical simulation of heat transfer from tubes employing augmentation devices, such as twisted tapes, wire-coil inserts, for heat transfer enhancement. A computational fluid dynamics (CFD) simulation tool was developed with CFX software and the results obtained from the simulations are validated with the empirical correlations for a smooth tube heat exchanger. The difficulties associated with the simulation of a heat ...
This experiment investigated the effects of free-stream turbulence intensity, length scale, Reynolds number, and leading-edge velocity gradient on stagnation-region heat transfer. Heat transfer was measured in the stagnation region of four models with elliptical leading edges downstream of five turbulence-generating grids. Stagnation-region heat transfer augmentation increased with decreasing length scale but an optimum scale was not found. A correlation was developed that fit heat transfer data for isotropic turbulence to within {+-}4 percent but did not predict data for anisotropic turbulence. Stagnation heat transfer augmentation caused by turbulence was unaffected by the velocity gradient. The data of other researchers compared well with the correlation. A method of predicting heat transfer downstream of the stagnation point was developed. 28 refs., 12 ...
This experiment investigated the effects of free-stream turbulence intensity, length scale, Reynolds number, and leading-edge velocity gradient on stagnation-region heat transfer. Heat transfer was measured in the stagnation region of four models with elliptical leading edges downstream of five turbulence-generating grids. Stagnation-region heat transfer augmentation increased with decreasing length scale but an optimum scale was not found. A correlation was developed that fit heat transfer data for isotropic turbulence to within #+-#4 percent but did not predict data for anisotropic turbulence. Stagnation heat transfer augmentation caused by turbulence was unaffected by the velocity gradient. The data of other researchers compared well with the correlation. A method of predicting heat transfer downstream of the stagnation point was developed. 28 refs., 12 ...
This investigation concerns the nonlinear dynamics of heat transfer from a surface using an upstream eddy promoter. A numerical model is developed for the coupled fluid flow and heat transfer process based on a modified MacCormack scheme. Numerical simulations are carried out to determine the response and heat transfer enhancement due to the promoter. The average heat transfer from a cavity floor is seen to be increased by a factor of approximately five over the unpromoted'' flow. Another interesting feature of the study is the nonlinear viscous flow dynamics from the cylinder-wall interaction which differ significantly from the familiar cylinder-free stream patterns.
This investigation concerns the nonlinear dynamics of heat transfer from a surface using an upstream eddy promoter. A numerical model is developed for the coupled fluid flow and heat transfer process based on a modified MacCormack scheme. Numerical simulations are carried out to determine the response and heat transfer enhancement due to the promoter. The average heat transfer from a cavity floor is seen to be increased by a factor of approximately five over the unpromoted'' flow. Another interesting feature of the study is the nonlinear viscous flow dynamics from the cylinder-wall interaction which differ significantly from the familiar cylinder-free stream patterns.
Heat transfer augmentation has developed into a major specialty area in heat transfer research and development. A bibliography of world literature on augmentation is presented. The literature is classified into passive augmentation techniques, which require no external power, and active techniques, which do require external power. The fourteen techniques are grouped in terms of their application to the various modes of heat transfer. Mass transfer is included for completeness. Key words are included with each citation for technique/mode identification. The total number of publications cited is 1,967, including 75 surveys of various techniques and 42 papers on performance evaluation of passive techniques. Patents are not included as they will be the subject of a future topical report.
Heat transfer augmentation in a rib-roughened duct is affected by the rib configurations, such as rib height, angle of attack, shape, rib to rib pitch, and aspect ratio of a duct. These have been the main subjects in studying the average heat transfer and the friction loss of the fully developed flow. Investigating distributions of local heat transfer coefficients and flow patterns in a duct with the rib turbulators is necessary to find the characteristics of heat transfer augmentation and to decide the optimal configurations of ribs. In the present study the numerical analyses and the mass transfer experiments are performed to understand the flow through a rib roughened duct and the heat transfer characteristics with various angles of attack of ribs. A pair of counter-rotating secondary flow in a duct has a main effect on the lateral distributions of local mass ...
A heat transfer (condenser) of a domestic freezer was tested in a vertical channel in order to study the influence of the chimney effect in the optimization of the heat transfer coefficient. The variation of the opening of the channel, position and the heating power of the heat exchanger in the heat transfer coefficient was considered. The influence of the surface emissivity on the heat transfer by thermal radiation was studied with the heat exchanger testes without paint and with black paint. The air velocity entering the channel was measured with a hot wire anemometer. In order to evaluate the chimney effect, the heat exchanger was testes in a open ambient. This situation simulates its operational conditions when installed on the freezer system. The variables collected in the experimental procedures was gathered in the form of dimensionless parameters as Nusselt, Rayleigh, Grashof and Prandtl numbers, ...
The authors discuss a two-phase two-component experimental system developed to study enhancement of heat transfer from a vertical chip size heater to surrounding liquid (Freon 113 or Ethanol) due to air jet impingement. Heat transfer coefficient was measured as function of jet velocity, heat flux and the distance between exit of jet tube and heated surface. The injector was placed very close to the hot surface. It was found that the heat transfer was notably enhanced with foreign gas impingement, especially in the cases of small temperature differences between wall and coolant. In fact for higher jet velocities the heat transfer coefficients tended to infinite while the temperature differences between wall and coolant were zero. The heat transfer coefficients decreased with the increasing of heat flux. High-speed camera was used to study the behaviour of the gas bubbles which play ...
Several heat transfer augmentation mechanisms contribute to the heat transfer augmentation around the stagnation point in the gas-solid two-phase impinging jet flow. Among those contributions, that of heat exchange was numerically analyzed and characteristically elucidated by the unsteady direct contact heat conduction at the time of impingement between the laden particles and heat transfer surface. In other words, if the contact time is short between the particles and heat transfer surface, the former is heated by heat stored in the latter as a heat capacity. In such a region, the heat quantity to be transferred to the particles changes by not only the thermal property value (heat capacity multiplied by heat conduction coefficient) of particles but also that of heat transfer surface. Then by using several kinds of particles and heat ...
Heat fusion is the most common joining method for polyethylene gas distribution piping. Butt fusion was studied with the intent of relating the quality of the joint to the joining conditions. A semi-empirical approach was used. The thermofluid consequences of joining conditions such as heater temperature, heating time and joining parameter were calculated using a computer model. The model was validated by instrumented tests. The strength of the joints was gauged by destructive mechanical testing. Tensile and tensile impact tests were used. Over 150 joints were fabricated using four different polyethylene resins. Most of the data are given in GRI Report No. 88/0276.2 -- Volume 2: Technical Reference on Butt Heat Fusion Joining of Polyethylene Gas Pipes. A parameter, termed the Joining Parameter, was found to characterize the joining conditions. Of the mechanical tests parameters, the impact energy was found to have the best correlation with the joining parameter. ...
Heat fusion is the most common joining method for polyethylene gas distribution piping. Butt fusion was studied with the intent of relating the quality of the joint to the joining conditions. A semi-empirical approach was used. The thermofluid consequences of joining conditions such as heater temperature, heating time and joining parameter were calculated using a computer model. The model was validated by instrumented tests. The strength of the joints was gauged by destructive mechanical testing. Tensile and tensile impact tests were used. Over 150 joints were fabricated using four different polyethylene resins. Most of the data are given in GRI Report No. 88/0276.2 -- Volume 2: Technical Reference on Butt Heat Fusion Joining of Polyethylene Gas Pipes. A parameter, termed the Joining Parameter, was found to characterize the joining conditions. Of the mechanical tests parameters, the impact energy was found to have the best correlation with the joining parameter. ...
Boron carbide is a high-technological ceramic material (it is used for lightweight armor, neutron absorbers, wear pieces, etc.). Hot pressing (2200"0C, 40 MPa, Ar atmosphere) and recently high isostatic pressing, are the best know ways for industrial preparation of boron carbide items. Pressureless sintering using metallic, inorganic, B+C, additives is not successful, since, despite having a high density, impurities remain present. Pressureless sintering of boron carbide (or silicon carbide composite) using free carbon addition, produced by in-situ pyrolysis of a Novolaque-type phenol-formaldehyde resin (#approx =# 9 wt%), is now possible in industry. A promising new method is the use of organic precursors, e.g. polycarbosilane with a small amount of phenolic resin, giving CSi and C by in-situ pyrolysis; the resulting boron carbide ceramics have high density (> 92%) and contain no free carbon and a small amount of SiC (#approx =# 5 wt%). The ...
Pattern and model makers are skilled tradespersons who may be exposed to hardwoods, softwoods, phenol-formaldehyde resin-impregnated woods, epoxy and polyester/styrene resin systems, and welding and metal-casting fumes. The relationship of respiratory symptoms (wheezing, chronic bronchitis, dyspnea) and pulmonary function (FVC% predicted, FEV1% predicted, FEV1/FVC% predicted) with interview-derived cumulative exposure estimates to specific workplace agents and to all work with wood, plastic, or metal products was investigated in 751 pattern and model makers in southeast Michigan. In stratified analyses and age- and smoking-adjusted linear and logistic regression models, measures of cumulative wood exposures were associated with decrements in pulmonary function and dyspnea, but not with other symptoms. In similar analyses, measures of cumulative plastic exposures were associated with wheezing, chronic bronchitis, and dyspnea, but not with ...
Inexpensive activated carbon assembly(ACA) was prepared with glass fabrics coated by 10 wt%, 25 wt%, 50 wt% phenolic resin solution, followed by activation at 700{sup o} C under N{sub 2} atmosphere and subsequent surface modification with N{sub 2}, NH{sub 3}, CO{sub 2} gas, respectively. The conversion chemistry of resin to carbon was analyzed by using FT-IR, TGA, SEM, XPS, and the SO{sub 2} adsorption characteristics of the ACA were compared to that of commercial activated carbon fabrics(ACF). The ACA modified by NH{sub 3} showed the best SO{sub 2} adsorption behavior due to the presence of basic functional groups such as amine on the surface, confirmed by XPS. The ACA modified by NH{sub 3} displayed relatively high adsorption capacity of 116.5 mg/g carbon, which is corresponding to 75% adsorption of the commercial ACF(153.4 mg/g) treated with the same method. 14 refs., 6 figs., 2 tabs.
An ion exchange unit has been manufactured for WSRC by British Nuclear Fuels, Ltd. This unit consists of three columns, ancillary valving, pumps, lines, and computer controls. It has been delivered to TNX for use in testing a cesium-specific ion exchange resin, developed at WSRC as a potential second generation process for the decontamination of Defense Waste Processing Facility (DWPF) supernate. This resin also has Department of Energy applications at both Oak Ridge and Hanford. Oak Ridge is interested in decontaminating the Melton Valley storage tank supernate, while Hanford is interested in decontaminating the 101-AW and 101-SY supernate streams. Another potential developmental interest is the Savannah River Site (SRS) DWPF recycle stream. The three primary waste streams of interest are the Oak Ridge, Hanford, and SRS, SWPF supernate streams. For these three waste streams, the cesium decontamination factor (DF) will be measured for a ...
The effect of atmospheric pressure on tracking resistance of organic insulating materials were investigated in the range of 500 to 1007 hPa. The tracking resistance for Polycarbonate (PC), Modified Polyphenylene Oxide (M-PPO) and Paper Base Phenolic Resin Laminate (PL) increase with the decrease in atmospheric pressure. The scintillating discharges on these samples surface lead to the ignition. The tracking failure on these results from the ignition on the surface. For Polybutylene Terephthalate (PBT) and Polyethylene Terephthalate (PET), the tracking resistance decrease with the decrease in atmospheric pressure. The discharges observed on the these surface are the glow-like. The discharge area spreads on the surface between the electrodes at the lower pressure. The failure on this group results from the carbonization by the discharges on the surface. However, the tracking resistance for Unsaturated Polyester Resins (UP) has no significant ...
A suspension-firing type radioactive waste incineration system is developed and cold demonstration testing of ceramic filters for the system are carried out. The incineration system, which is useful for a wide variety of waste materials, can serve to simplify the facilities and to reduce the costs for waste disposal. The incineration system can be used for drying-processing of concentrated waste liquids and disposal of flame resistant materials including ion exchange resins and rubber, as well as for ordinary combustible solid materials. An on-line backwash system is adopted to allow the ceramic filters to operate stably for a long period of time. For one-step filtering using the ceramic filter, the decontamination factor is greater than 10"5 for the processing of various wastes. In a practical situation, there exist vapor produced by the spray drier and the cladding in used ion exchange resin, which act to increase the decontamination ...
In order to gain a wider knowledge of corrosion phenomena in OFHC (oxygen free high conductivity) copper pipes of the stator cooling circuit of a power plant turboalternator, a research program was laid out which is based on the use of an experimental loop simulating real operating conditions as closely as possible. The samples examined were either copper foils or hollow conductors of the type that is normally used in the stator cooling system, and the circulating fluid was high purity water with controlled O/sub 2/, H/sub 2/ and C0/sub 2/ contents. Investigations were focused on the kinetics of O/sub 2/ removal through catalytic resins covered with metallic palladium (at different temperatures and pressures) and on the kinetics of CO/sub 2/ removal through mixed bed resins. Subsequently, attention was directed to the corrosion of copper (in the form of foils or hollow conductors) under different experimental conditions simulating either ...
The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. Here we calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favourable for wave amplification from alpha energy. We find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy transfer, is investigated. This technique is ...
The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. Here we calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favourable for wave amplification from alpha energy. We find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy transfer, is investigated. This technique is ...
The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. An initial analytic study was done by Fisch and Rax. Here the authors calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favorable for wave amplification from alpha energy. They find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy ...
Heat-transfer augmentation by straight grid spacers in rod bundles is studied for single-phase flow and for post-critical heat flux dispersed flow. The heat transfer effect of swirling grid spacers in single-phase flow is also examined. Governing heat-transfer mechanisms are analyzed, and predictive formulations are established. For single-phase flow, the local heat transfer at a straight spacer and at its upstream or downstream locations are treated separately. The effect of local velocity increasing near swirling spacer is considered. For post critical heat flux (CHF) dispersed flow, the heat transfer by thermal radiation, fin cooling, and vapor convection near the spacer are calculated. The predictions are compared with experimental data with satisfactory agreement.
An experimental and theoretical study of heat and mass transfer analogy and a comparison of that to a binary liquid mixture evaporation is presented. Common organic solvents, ethanol and n-heptane, were used to form an alcohol - hydrocarbon mixture. Studies were carried out in a horizontal rectangular channel having air flow velocities of 0.2 - 0.9 m/s. Heat transfer coefficients were measured with a copper plate resistor and mass transfer coefficients with a square pool. The heat and mass transfer analogy is presented for a system having two evaporating compounds with a fixed value of air flow and verified by measuring and comparing mass transfer coefficients for distilled water with air flow velocities of 0.2 - 0.9 m/s. An illustrative example of the use of the theory for industrial ventilation is presented. (author)
The aim of this work was to study the energy transfer mechanisms from the ligand to the central lanthanide ion of tetracycline-europium (Tc-Eu) complex. The absorption spectra of a EuCl{sub 3}.H{sub 2}O solution was measured and absorption cross-section of Eu{sup 3+} was estimated. The observed overlap predicts a resonant energy transfer from Tetracycline to Eu{sup 3+}. The microscopic parameter of energy transfer was obtained using the overlap integral calculation considering a dipole-dipole energy transfer mechanism and results were compared considering an energy transfer by exchange. In this work, we report also the optical properties of Tc-Eu complex when urea hydrogen peroxide is added to the aqueous solution.
Fundamental phenomena of condensation heat transfer at a steam-water interface have been studied related to the thermo-hydrodynamics of the emergency core cooling system for light water reactors. In this study temperature fluctuations near the interface and in the liquid phase were measured using fine thermocouples for a saturated steam-subcooled water co-current stratified two-phase flow in a nearly horizontal rectangular channel, and heat transfer coefficients were determined experimentally. The values of the condensation heat transfer coefficients in this experiment are from 6 to 40 kW/m{sup 2}K. In the regions of high Reynolds numbers, as the steam Reynolds numbers become larger, the average interfacial heat transfer coefficients tend to increase. The corelations of Nusselt numbers were obtained from the heat transfer data. (author)
Fundamental phenomena of condensation heat transfer at a steam-water interface have been studied related to the thermo-hydrodynamics of the emergency core cooling system for light water reactors. In this study temperature fluctuations near the interface and in the liquid phase were measured using fine thermocouples for a saturated steam-subcooled water co-current stratified two-phase flow in a nearly horizontal rectangular channel, and heat transfer coefficients were determined experimentally. The values of the condensation heat transfer coefficients in this experiment are from 6 to 40 kW/m"2K. In the regions of high Reynolds numbers, as the steam Reynolds numbers become larger, the average interfacial heat transfer coefficients tend to increase. The corelations of Nusselt numbers were obtained from the heat transfer data. (author)
A metal matrix is inserted into a phase-change material to enhance the heat transfer during phase-change processes. The metal matrix tends to act like a heat transfer fin from the heated or cooled surface and to increase the effective thermal conductivity of the phase-change fluid. The scope of the study involves numerically modeling the heat transfer to and from constant-temperature cylindrical tubes surrounded by water during the freezing and melting processes. Comparisons of heat transfer with and without the metal matrix are made, with different porosities and densities of the metal matrix being examined. The results of this study are discussed in terms of the effectiveness of the metal matrix as a heat transfer enhancement device.
This document reports the results of testing of spent ion exchange media pretreatment technologies. Emphasis of the testing activities has been on screening pretreatment technologies, such as drying and emulsification, which are compatible with vitrification, cementation, and incineration. Ion exchange media tested for cementation and incineration pretreatment technologies were typical organic ion exchange resins and inorganic zeolites. The ion exchange medium tested for vitrification pretreatment technologies was inorganic zeolite. The results of testing activities are discussed in detail in this report.
Some aspects of metrological provision of X-ray radiometric analyzers for mineral raw composition and gamma-gamma-logging equipment are considered. Standard samples (SS) based on the phenol-formaldehyde resin with the introduced quantities calculated of element compositions in the form of oxides and salts are described. Principles of metrological provision developed are used when carrying out state acceptance tests of X-ray radiometric analyzer RAL-M-102 ''Ehkran'' and gamma-gamma-logging equipmnt RSK-102. Economic benefit from introduction of an SS set is #approx# 60-100 thousand roubles per year.
Separations of metal ions on the basis of Donnan dialysis across anion-exchange membranes should be possible if the receiver electrolyte composition favors the formation of selected anionic complexes of the sample metal ions. Moreover, such a separation has the possibility of being better suited from some applications than batch or column experiments with anion-exchange resins. The above hypothesis are tested on the platinum-group metal ions, Pt(IV), Rh(III), Pd(II), Ir(III), and Ir(IV). 13 references, 4 tables.
For the selective extraction of radionuclides from nitrate media, the extractabilities of organo-poly-phosphine poly-oxides were examined in the form of impregnated resins. It was found that the extractability of 1,1,3,5,5-pentaphenyl-1,3,5-tri-phospha-pentane trioxide (PPTPT) for U(VI) is quite unusual with very high values at both low and high concentrations of nitric acid, which is not observed for other types of extractants. Thus, this extractant might be promising for the selective extraction of U(VI) in very high concentrations of HNO3. (authors)
This year was spent in perfecting details of the new design blood irradiator, i.e., having male fittings made for shunt insertion and in acquiring preliminary biological data on its effectiveness. Fabrication of units was slowed by an unanticipated reaction of the resin with the steel injection mold, by occasional thrombogenic flaws in the blood interface layer, by thrombus formation at the points of connection to the shunt and by nonavailability of a reactor for activating the "1"6"9Tm to "1"7"0Tm. The remaining unsolved problem is that of thrombus formation at the connectors.
Recovery of uranium by ion-exchange processes from impure acid leach liquors is described, which produce a concentrated and pure eluate employing 10% sulphuric acid elution. In situations where resin is loaded to 45 g/ltr or more the acid consumption at ambient temperature is less than 4 kg of H_2SO_4 per kilogram of U_3O_8. Precipitation with an alkali such as ammonia or magnesia produces a yellow cake of high purity. (author).
A process is disclosed for the preparation of liquid, storage-stable, polyisocyanate compositions containing a release agent formed in situ which compositions are useful, for example, as binder resins in the formation of particle boards which latter, because of the presence of the release agent, show no tendency to adhere to the face of metal platens used in their formation. The process comprises heating an organic polyisocyanate (polymethylene polyphenyl polyisocyanate preferred) with an acid phosphate (e.g. a mixture of mono-and di-alkyl acid phosphates) under conditions controlled as to time and temperature so as to yield a product which is storage stable and shows no tendency to deposit solid or to separate into two liquid phases.
The reactor fuel cycle based on uranium is described. The various stages in the cycle include mining of uranium ores followed by crushing and grinding, leaching and purification of leach liquor by ion exchange resin process or solvent extraction process, refining of uranium concentrate (yellow cake) by digesting with HNO_3 and then solvent extracting uranyl nitrate with TBP, conversion of uranyl nitrate to uranium hexafluoride, production of uranium metal, uranium enrichment, fabrication of reactor fuel elements and reprocessing of the spent fuel. Chemical reactions wherever they are involved are explained. (M.G.B.).
The use of finely powdered ion exchange resins improve loading of specific ion exchange materials with better performance but as such these materials are not suitable for column operation. However, by proper selection of ion exchange support medium, it is possible to get better product. The radioactive solution can be treated by suspending this material, stirring and allowing to settle. The present method gives DF in the range of 70 - 80 even after repeated use as compared to DF in the range of 5 to 10 by single conventional chemical treatment process. (author)
Radioactive "1"4C sucrose was found to be an ideal marker for microleakage because it did not penetrate tooth tissue, dental cement, or mounting resin. The main finding is that the adhesive cements--the glass-ionomer and polycarboxylate--are significantly more effective at preventing microleakage than are the traditional phosphate cements--silicate and zinc phosphate. The differences can be as high as two orders of magnitude. The adhesive cements provide almost perfect and reliable seals. By contrast, the nonadhesive cements are erratic sealants with most of the restorations leaking.
This paper discusses the remote plugging of leaks in inaccessible pipework, with main reference to small leaks which frequently appear in ancillary cooling water circuits of nuclear reactors. Initially developed to cure problems of the pre-stressed concrete pressure vessels of UK reactors, the ZORIC sealant has been used to repair leaking biological shield pipework on six CANDU reactors. ZORIC is based on a water-soluble epoxy resin and an aqueous suspension of a refined mineral clay. This paper describes the evolution of the sealant, the qualification and testing program, and their application to CANDU reactor systems. 2 refs., 6 figs.
Scientists of the Institute of Wood Chemistry of the Latvian Academy of Sciences have developed two highly efficient processes for producing furfural, a feedstock for varnishes, synthetic resins and plastics. It is made of production wastes, including branches and small-dimension timber. By one process, the raw material is chipped, treated first with diluted sulphuric acid and then with steam heated to 250 degrees C. The other uses concentrated sulphuric acid as a catalyst. Besides furfural, this process also yields sugar solutions used in alcohol and nutrient yeast production.
The chemistries of reactants, plasticizers, solvents and additives in an epoxy paint are discussed. Polyamide additives may play an important role in the absorption of molecular iodine by epoxy paints. It is recommended that the unsaturation of the polyamide additive in the epoxy cure be determined. Experimental studies of water absorption by epoxy resins are discussed. These studies show that absorption can disrupt hydrogen bonds among segments of the polymers and cause swelling of the polymer. The water absorption increases the diffusion coefficient of water within the polymer. Permanent damage to the polymer can result if water causes hydrolysis of ether linkages. Water desorption studies are recommended to ascertain how water absorption affects epoxy paint.
A 20-cell PEFC stack was designed and built. Resin impregnated graphite was used as bipolar plate material. The air cooling of the stack was optimized by introducing high surface structures into the open space of the cooling plates. At {eta} (H{sub 2} LHV) = 0.5 a power of 880 W was obtained under conditions of low gas-pressures of 1.15 bar{sub a}. The auxiliary power for process air supply and cooling at 880 W power is less than 7% of the power output, indicating that the described system may be operated at a high efficiency. (author) 5 figs., 2 refs.
An apparatus was designed and built for the purpose of exposing samples of solid polymers to varying temperatures, atmospheres and stress levels while quantitatively recording the resulting chemiluminescence. Preliminary data were acquired with this apparatus that show a correlation between an enhanced chemiluminescence signal at a low level of applied stress and a decrease in tensile strength for the most commonly used epoxy resin in high performance fiber composites, TGMDA DDS. The studies with cellular silicone cushions (which are used to accommodate thermal expansion and contraction) have defined the temperature regimes in which accelerated aging tests are valid for extrapolation to ambient temperature. Preliminary data on Kevlar fibers is also discussed.
Selected samples of waste microbial biomass originating from various industrial fermentation processes and biological treatment plants have been screened for biosorbent properties in conjunction with uranium and thorium in aqueous solutions. Biosorption isotherms have been used for the evaluation of biosorptive uptake capacity of the biomass which was also compared to an activated carbon and the ion exchange resin currently used in uranium production processes. Determined uranium and thorium biosorption isotherms were independent of the initial U or Th solution concentration. Solution pH affected the exhibited uptake. 24 refs.
The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container.
The General-Purpose Heat Source (GPHS), an improved radioisotope heat source, employs a unique thermal insulation material, carbon-bonded carbon fiber (CBCF), to protect the fuel capsule and to help achieve the highest possible specific power. The CBCF insulation is made from chopped rayon fiber about 10 ..mu..m in diameter and 250 ..mu..m long, which is carbonized and bonded with phenolic resin particles. The CBCF shapes, both tubes and plates, are formed in a multiple molding facility by vacuum molding a water slurry of the carbonized chopped-rayon fiber (54 wt %) and phenolic resin (46 wt %). The molded shapes are subsequently dried and cured. Final carbonization of the resin is at 1600/sup 0/C. Machining to close tolerances (+-0.08 mm) is accomplished by conventional tooling and fixturing. The resulting material is an excellent lightweight insulation with a nominal density of 0.2 Mg/m/sup 3/ and a thermal conductivity ...
When solidified products made from low-level radioactive waste with melting treatment are disposed of in near surface repositories, concentrations of the radionuclides contained in the waste package have to be evaluated. Americium-242m is one of the targeted nuclides. In this study, simple analytical methods to evaluate the activity of "2"4"2"mAm are studied. Americium, Cm and Eu in a sample solution made from simulated solidified product and tracer of "1"5"2Eu and "2"4"4Cm and unknown solution of "2"4"1"+"2"4"2"m"+"2"4"3Am were separated from matrix elements with TRU resin. The fraction containing Eu, Am and Cm was passed through pyridine resin to separate Am from Eu and Cm. The contamination factor of "2"4"4Cm/"2"4"1Am was less than 3.0x10"-"3. Curium-242 generated from "2"4"2Am was measured to evaluate the activity of "2"4"2"mAm. The fraction containing Eu, Am and Cm was also passed through TEVA resin to separate Am and ...
Related to other research on the effectiveness of flow boiling heat transfer augmentation using various types of turbulators this investigation comprises a definitive study of the effect of large discrete roughness elements on heat transfer over the entir...
The effect of velocity gradient on stagnation region heat transfer augmentation by free stream turbulence was investigated. Heat transfer was measured in the stagnation region of four models with elliptical leading edges with ratios of major to minor axes of 1:1, 1.5:1, 2.25:1, and 3:1. Four geometrically similar, square bar, square mesh, biplane grids were used to generate free stream turbulence with different intensities and length. Heat transfer measurements were made for the following ranges of parameters: Reynolds number, based on leading edge diameter, 37,000 to 228,000; dimensionless leading edge velocity gradient, 1.20 to 1.80; turbulence intensity, 1.1 to 15.9%; and length scale to leading edge diameter ratio, 0.05 to 0.30. Stagnation point heat transfer augmentation by free stream turbulence can be predicted using a modified version of a previously developed correlation for a circular leading ...
Semiclassical analysis of heavy ion induced transfer reactions are discussed for the quasielastic region. Some unique aspects of these reactions are shown, the variety of features which can be understood semiclassically is demonstrated, and some open problems are indicated. 28 refs., 16 figs. (LEW)
Plasmid transfer between strains of Bacillus thuringiensis subsp. israelensis was studied under a range of environmentally relevant laboratory conditions in vitro,...Full Text Available
The Subseabed Disposal Program has recently completed a 30-day, 0.286-scale laboratory simulation of an In Situ Heat Transfer Experiment (ISHTE), scheduled for eventual deployment in the deep ocean 600 nautical miles north of Hawaii. 10 figures.
The Subseabed Disposal Program has recently completed a 30-day, 0.286-scale laboratory simulation of an In Situ Heat Transfer Experiment (ISHTE), scheduled for eventual deployment in the deep ocean 600 nautical miles north of Hawaii. 10 figures.
Tetracycline-resistant Lactococcus lactis strains originally isolated from Polish raw milk were analyzed for the ability to transfer their antibiotic resistance genes in vitro, using...Full Text Available
This textbook contains the following main topics: Heat conductivity, convection, condensation and evaporation, radiation heat transfer and heat exchangers. It includes the physical foundations for all these aspects and many examples. (orig.)
A compact heat exchanger pedestal array for augmenting heat transfer in a machine is disclosed. The compact heat exchanger pedestal array includes a wall having first and second surfaces. The first surface faces a heated flow path and the second surface p...
Heating and cooling by impinging jets is widely used in various engineering applications, due to the high heat transfer rates prevailing in the vicinity of the stagnation point. The authors have been able to utilize acoustically excited turbulence for the...
An experimental investigation of heat transfer characteristics for various configurations of air jets impinging on the leading edge inner surface of a gas turbine blade wall is presented. Three configurations were investigated, namely a slot jet, a round ...
Equinovarus of the foot is the most common lower extremity deformity following traumatic brain injury. We evaluated outcomes of the split anterior tibialis tendon transfer (SPLATT) for correction of...Full Text Available
Scraped-surface heat transfer augmentation is proposed as a possible technique for use in improved air-cooling designs. Although it has been in common use with liquids, the technique has apparently never been used with gases. An experimental investigation...
Nuclear transfer (NT) is a procedure by which genetically identical individuals can be created. The technology of pig somatic NT, including in vitro maturation of oocytes, isolation and treatment of...Full Text Available
On February 27, 1990, standards for Benzene were promulgated for benzene transfer and benzene waste operations. The benzene enabling document summarizes these standards. The basic purpose of the document is to assist the EPA regional enforcement personnel...
An attempt is made to augment the heat transfer efficiency by means of inserting an oscillating thin plate into a tube of the shell and tube heat exchanger. However, the heat transfer augmenting mechanism has not been fully explained. To elucidate this heat transfer augmenting mechanism, an investigation was given on the heat transfer characteristics of a tube inlet at its preliminary run area when a double-hinged oscillating thin plate is inserted in the inlet. As a result of the experiment, the heat transfer augmentation in the tube as a result of inserting the double-hinged oscillating thin plate was found effective when the preliminary inlet run area is treated as the object. However, in comparison of the effect with the heat transfer in a fully developed turbulent region, it was {eta}- 1. The result thus obtained explains that no sufficient turbulence can ...
... TTP tactics, techniques, and procedures UCP Unified ... be sold or transferred to Pakistan, pursuant to ... substantial amounts of those funds being spent ...
Ultrasonic enhancement of heat transfer on a narrow surface was measured by changing the width of the surface from 8 to 0.1 mm. Ultrasonic power of 600 W with a frequency of 40 kHz was used. Heat transfer on the narrow surface without ultrasonic vibration was correlated by the experimental equation for a thin wire. The cavitation intensity was measured by the cavitation erosion loss of an aluminum foil of 15 [mu]m thickness. The effects of acoustic streaming and cavitation were separated by this measurement. Heat transfer by acoustic streaming was predicted through forced convection. Enhancement by cavitation was explained by the turbulence thermal conductivity of the microjets.
The present study investigates the effect of the shear rate-dependent thermal conductivity of non-Newtonian fluids on the heat transfer enhancement in a pipe flow. The constant heat flux as thermal boundary condition was adopted in the thermally developed region. The present analytical results show the heat transfer enhancement over those of a shear rate-independent thermal conductivity fluid. The heat transfer coefficient ratio (h/h{sub 0}) linearly increase with the non-dimensional average velocity difference which is the product of the shear rate-dependence of the thermal conductivity and wall-shear rate.
A comprehensive presentation is made of state-of-the-art configurations and design methodologies for heat transfer devices applicable to industrial processes, automotive systems, air conditioning/refrigeration, cryogenics, and petrochemicals refining. Attention is given to topics in heat exchanger mechanical design, single-phase convection processes, thermal design, two-phase exchanger thermal design, heat-transfer augmentation, and rheological effects. Computerized analysis and design methodologies are presented for the range of heat transfer systems, as well as advanced methods for optimization and performance projection.
Unsteady impinging jets are systematically controlled with respect to their time dependence in order to investigate the influence of unsteadiness on the heat transfer performance. This is achieved by a special mass flow control device, which allows almost arbitrary shapes of unsteadiness to be imposed onto the impinging jet. Three different standard signals (sinusoidal, triangular, rectangular) and two specially designed signals are applied and their influence on heat transfer is determined in terms of an enhancement factor. Heat transfer augmentation up to 30% was found and could be physically explained with the help of PIV and hot-wire measurements of the flow field.
The concentric circular annular duct is a common geometry in many fluid flow and heat transfer devices. For the purpose of heat transfer augmentation, fins are often employed in the annular region, and such finned ducts find wide application in compact heat exchangers (5, 6). The analysis of flow and heat transfer in this geometry is, therefore, quite important from an engineering standpoint. For fully developed conditions, the problem has already been analyzed (7-10). However, no results are available for the developing flow in the entrance region. It is with this latter problem that the present paper is concerned.
This paper presents the results of the experimental investigation on heat transfer and fluid friction characteristics of a class of spiral spring coil used as a tube side forced convection heat transfer augmentation devices. Based on a lot of experimental data, the heat transfer correlation and fluid friction correlation revised by temperature were reached in terms of linear regression. At the same time, proper criteria were used to evaluate the economic performance of the spiral spring inserted tube according to the demand of practical application and some probing analysis were made.
One of the main disadvantages of solar air collectors in practical applications is their relatively low efficiency. In this experimental investigation, the shape and arrangement of absorber surfaces of the collectors were reorganized to provide better heat transfer surfaces suitable for the passive heat transfer augmentation techniques. The performance of such solar air collectors with staggered absorber sheets was tested. The experimental results show that it is possible to provide 10 to 25% enhancement in the efficiency compared to the conventional solar air collectors. (authors)
This book is organized under the following headings: Electrohydrodynamic heat transfer augmentation; Forced convection augmentation and heat transfer control; Turbulent heat transfer; Thermal problems in the environment; Energy conversion systems; Measurement, visualization, and imaging; Thermal problems in space technology; and Thermal properties.
The transfer function concept is well known as an additional method to evaluate the impulse test of power transformers in the test laboratory. Another application for the transfer function method is monitoring of transformers in service. Thereby, Off-line and On-line monitoring can be realized. Both kinds of monitoring are demonstrated with on-site measurements on a power transformer in service.
The Monte Carlo simulation method is applied to calculate the nucleon transfer part of the imaginary optical-model potential in colliding heavy ions. In the process of transfer of nucleons from one nucleus to the other, forward and backward neutrons and protons are treated separately by taking into consideration the effect of the Coulomb forces and the potential energy surfaces (driving forces). The Pauli exclusion principle is also incorporated properly in the calculation.
During the period covered by this report research has been concerned with the study of photo-induced electron transfer reactions from porphyrins to acceptor molecules with time-resolved Electron Paramagnetic Resonance (EPR) methods. Excited-state electron transfer reactions are of importance from a fundamental point of view and in connection with applications in homogeneous and heterogeneous photosensitization, photopolymerization, and solar energy conversions. For this reason, the study of photo-induced electron transfer reactions is of considerable interest.
The field trial of an unattended monitoring system for SF transfer verification ended in June 2005. The system is aiming to improve the safeguards measures applied during SF transfers and reduce inspection effort currently required by the Operator, NNCA and the IAEA. They were reviewed based on its technical performance and other issues in this paper.
The field trial of an unattended monitoring system for SF transfer verification ended in June 2005. The system is aiming to improve the safeguards measures applied during SF transfers and reduce inspection effort currently required by the Operator, NNCA and the IAEA. They were reviewed based on its technical performance and other issues in this paper.
In our previous theoretical analyses, solubility-limited mass transfer from waste solids applies if a species is at a constant elemental concentration in liquid at the waste surface. For an element with isotopes that decay appreciably during the time of interest, a solubility boundary condition results in a time-dependent boundary concentration of each isotope. Here we present mass-transfer equations that include the effects of isotopic decay boundary conditions. 9 refs., 1 fig.
The heat transfer augmentation is reviewed in view of high temperature heat exchangers illuminating the contribution of radiative heat transfer. A number of means and/or devices are presented as well as the sophisticated concept which will be promoted to the extended applications in matured industries such as iron and steel, oir refinery, petro-chemical. It should be emphasized that the more creative and innovatory technology has to be promoted in order to stimulate and refresh the foregoing industries, recognizing the increasing importance of the energy resources.
This paper presents a theoretical study of heat transfer from magneto-rheological fluid (MRF) dampers. A lumped system model is developed which is capable of predicting the temperature rise for any size MRF damper. As a case study example, finned and unfinned dampers are compared for automotive-size MRF dampers. The results demonstrate that heat transfer from these devices can be enhanced considerably with the use of fins.
An experimental study was undertaken to determine for the turbulent regime the heat transfer and fluid flow characteristics of a heat exchange array of unperforated, and perforated brass plates with 33% of the plate area open. In both cases, the plates were aligned parallel to the flow direction. For the flow conditions examined, the results showed enhancement of heat transfer and friction factor for the perforated array.
Analytical solutions are derived for a flow in a semi-infinite vertical porous medium with heat and mass transfer. When the temperature and mass concentration are uniform a constant pressure is possible and sustains a fully developed flow. Thereafter there is a small perturbation on the wall temperature and concentration and the subsequent two-dimensional problem is tackled for a large Prandtl number, free convection parameters and small Reynolds number. The heat transfer rate at the wall is discussed quantitatively.
This report focuses on a better understanding of the physical phenomenon related to the enhancement of boiling and non-boiling heat transfer by applying ultrasonic waves. Experimental results obtained both in a pool of water and in a vertically upward water flow proved clearly that macroscopic acoustic steam induced by ultrasonics is a major contribution to heat transfer augmentation. (author).
This report focuses on a better understanding of the physical phenomenon related to the enhancement of boiling and non-boiling heat transfer by applying ultrasonic waves. Experimental results obtained both in a pool of water and in a vertically upward water flow proved clearly that macroscopic acoustic stream induced by ultrasonics is a major contribution to heat transfer augmentation. (author).
The Fast Flux Test Facility (FFTF) bottom-loading transfer cask (BLTC) system is designed to provide ex-vessel fuel transfers of irradiated reactor components between the reactor containment building and the LMFBR shipping cask in the reactor service building. This system is being procured from National Lead Industries, Wilmington, Delaware, under management of Aerojet Manufacturing Company.
Granted patents are an important source of information on the potential commercialization of augmented heat transfer technology. This report presents a bibliography of US patents pertinent to that technology. The total number of patents cited is 321. They are presented in three separate lists: by patent number, alphabetically by first inventor, and by augmentation techniques (with secondary arrangement according to mode of heat transfer).
The behavior of air flows in complex heat exchanger passages is reviewed with a focus on the heat transfer effects of boundary-layer development, turbulence, spanwise and streamwise vortices, and wake management. Each of these flow features is discussed for the plain, wavy, and interrupted passages found in contemporary compact heat exchanger designs. Results from the literature are used to help explain the role of these mechanisms in heat transfer enhancement strategies.
The present study numerically investigates the enhancement of forced convective heat transfer from a single circular cylinder embedded in a packed bed of spherical particles confined by two impermeable parallel plates. The heat transfer results from the heated cylinder, with and without the presence of a porous medium, are compared. The results show that the presence of the porous particles enhances the heat transfer from the cylinder; however, the significant heat transfer augmentation is produced at high Re due to the effect of thermal dispersion. In addition, the effect of Re on Nut is much greater than that of kr and Bi in the porous channel. It is also found that the %?p is much higher than %HTE producing from packing the empty channel.
A numerical study has been conducted to examine the heat transfer from a metal foam-wrapped solid cylinder in cross-flow. Effects of the key parameters including the free stream velocity and characteristics of metal foam such as porosity, permeability, and form drag coefficient on heat and fluid flow are examined. Being a determining factor in pressure drop and heat transfer increment, the porous layer thickness is changed systematically to observe that there is an optimum layer thickness beyond which the heat transfer does not improve while the pressure drop continues to increase. This has been verified by the application of Bejan?s Intersection of Asymptotes method. Results have been compared to those of a finned-tube heat exchanger to observe much higher heat transfer rate with reasonab...
Mass transfer to a wall of a horizontal rectangular channel reactor was investigated by the limiting current technique for Reynolds numbers ranging from 200 to 32000. Overall mass transfer coefficients at various mass transfer surface angles were obtained while the reactor was operated under isothermal and non-isothermal conditions. Dimensionless correlations were developed for isothermal flows from 25 to 55{sup o}C and for non-isothermal flows with applied temperature differences up to 30{sup o}C. In the laminar flow range natural convection dominated, but under turbulent conditions combined natural and forced convection prevailed. Mass transfer was approximately doubled under optimum selection of channel surface rotation, temperature gradient and flow rate. (author)
Mass transfer to a wall of a horizontal rectangular channel reactor was investigated by the limiting current technique for Reynolds numbers ranging from 200 to 32000. Overall mass transfer coefficients at various mass transfer surface angles were obtained while the reactor was operated under isothermal and non-isothermal conditions. Dimensionless correlations were developed for isothermal flows from 25 to 55"oC and for non-isothermal flows with applied temperature differences up to 30"oC. In the laminar flow range natural convection dominated, but under turbulent conditions combined natural and forced convection prevailed. Mass transfer was approximately doubled under optimum selection of channel surface rotation, temperature gradient and flow rate. (author)
This paper describes the heat transfer augmentation and the flow situation around a single spacer (a cylindrical rod) on the heated surface of a parallel plate duct in order to examine basically the effects of the spacer in the fuel elements of a high temperature gas-cooled reactor. The ends of the cylindrical rod contact the upper and lower planes. A thermosensitive liquid crystal film is used to indicate the effective area for the heat transfer. The mean Nusselt number, which is estimated within the optional distance from the spacer to the downstream direction, peaks at a dimensionless distance of X/D = 1-3, and after that decreases gradually with the flow direction. The manner in which heat transfer corresponds to the flow situation is also examined. The horseshoe vortex, produced around the spacer, affects the wake and contributes to the increase of the local heat transfer. (author).
Forced convective heat transfer in a cross-corrugated channel solar air heater has been studied experimentally using air as a working fluid. The channel was formed by two transversely positioned corrugated sheets and two flat thermally insulated side walls. One corrugated sheet was heated by a radiant heater, while the other was thermally insulated. The fluid velocity and temperature, and the wall temperature and the local heat flux across the heated corrugated sheet were measured for a variety of operating flow rates. Experimental results for the channel geometry have yielded the correlation Nu = 0.0743 (Re)[sup 0.76]. This heat-transfer coefficient is about 2.8 times that of a smooth flat channel. The experiments showed that local heat transfer rate was smaller on the valley of the corrugation than that on the peak. The ratio of the local heat transfer rates on the two locations was related to the ...
The behavior of proton transfer facilitated by a novel thiazole derivative, N-methyl-4-(4-phenoxyphenyl)thiazol-2-amine (MPPT), across the water/1,2-dichloroethane (1,2-DCE) interface was investigated electrochemically. The ionic partition diagram for MPPT was obtained from interpretation of the cyclic voltammograms. The apparent partition coefficient of MPPT was evaluated by the shaking-flask method under experimental conditions, while that for the protonated form of MPPT was calculated from its transfer potential obtained from the ionic partition diagram. It was suggested that the mechanism for transfer of MPPT across the water/1,2-DCE) interface depends on the pH of the aqueous phase. The parameters of the facilitated proton transfer across the water/1,2-DCE interface were evaluated as ...
The portion of the potential energy surface (PES) of acetylacetone relevant for the intramolecular proton transfer reaction is studied using ab initio and DFT methods. The best estimate of the barrier governing proton transfer was found to be 3.4 kcal mol{sup -1} at the MP4(FC)/6-311 + G(2d,2p)//MP2(FC)/6-311 + G(2d,2p) level of theory. Six stationary points on the PES were characterized as well as the reaction paths connecting these points. Special attention paid to the pathway of intramolecular proton transfer reveals that the internal rotation of the methyl group adjacent to the carbonyl group and the proton transfer reaction are consecutive processes.
In order to reduce the size and cost of heat exchangers, an air-side wavy fin-and-tube heat transfer surface with three-row tubes needs to be replaced by two-row tubes with some appropriate enhancing techniques. The major purpose of the present paper is to search for such new structure by numerical simulation. First, longitudinal vortex generators of Delta-winglet type are tried. The influence of number and of arrangement of the winglets on the performance of the heat transfer surface is studied in detail. The numerical results show that the fin with two winglets aligned spanwise in the front and rear of each tube (Fin W6) has higher heat transfer capability than other enhanced structures with vortex generators, but it still unable to meet the heat transfer requirement. Then a combination ...
The analysis for the WITCH/LINER experiments was performed to investigate the heat transfer characteristics between the gas-agitated steel melt and the vertical surface. The applicability of heat transfer correlations for a gas-agitated fluid system was examined through the numerical analysis of the one-dimensional heat conduction taking into account the crust formation due to the solidification of the steel melt. The heat transfer correlation developed by Konsetov was modified for the application to fluids with low Prandtl number. The constant in the modified correlation was empirically found mainly through the comparison between the analysis and the experiments under conditions that a churn-turbulent two-phase flow regime was anticipated to form. The modified Konsetov correlation could predict the heat transfer characteristics observed through the experiments in an acceptable level. (author)
(Boiling site densities and heat-transfer coefficients have been measured for ethanol-water and ethanol-benzene mixtures at 1.01 bar for a heated vertical brass disk. A strong effect of composition on the boiling site density was observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The boiling heat-transfer coefficient was found to decrease with increasin subcooling, but for the mixtures at a given level of subcooling the decrease was less than that for the single components and azeotropic mixtures.) The heat-transfer coefficient at a given heat flux was seen to be quite insensitive to the very large increase in boiling site density in comparing the pure water and the ethanol-water azeotrope results, leading one to question pool boiling models that predict heat-transfer rates on the basis of boiling site density.
Counter rotating longitudinal vortices produced by winglet in a channel are known to enhance heat transfer. In the present investigation the flow structure and heat-transfer enhancement by a winglet pair of non-zero thickness has been studied. A delta winglet pair type vortex generator is placed in a hydrodynamically developed and thermally developing laminar channel flow. Computations are done by solving the unsteady, three-dimensional, incompressible Navier-Strokes equations and energy equation using a modified Marker-and-Cell (MAC) method. The flow structure is complex and consists of main, corner and induced vortices. It is observed that as compared to a channel without winglets, the heat transfer is enhanced by 33% when single winglet is used and by 67% when a winglet pair is employed. Effects of thickness of the winglets and Reynolds number on the heat transfer augmentation are presented.
This paper describes the heat transfer augmentation and flow situation around a single spacer (a circular cylinder) on a heated surface in a parallel plate duct in order to examine basically the effects of the spacer in the fuel elements of a High Temperature Gas-cooled Reactor. A thermosensitive liquid crystal film was used to clarify the effective region of the heat transfer. The mean Nusselt number, which was estimated within arbitrary distance from the spacer to the downstream direction, took a peak at the dimensionless distance X/D = 1 #approx# 3, and after that decreased gradually with flow direction. How heat transfer corresponds to the flow situation is also examined. The horseshoe vortex, produced around the spacer, affects the wake and contributes to the increase of the local heat transfer. (author).
1 - Description of program or function: The COOLOD-N2 code provides a capability for the analyses of the steady-state thermal-hydraulics of research reactors. This code is a revised version of the COOLOD-N code, and is applicable not only for research reactors in which plate-type fuel is adopted, but also for research reactors in which rod-type fuel is adopted. In the code, subroutines to calculate temperature distribution in rod-type fuel have been newly added to the COOLOD-N code. The COOLOD-N2 code can calculate fuel temperatures under both forced convection cooling mode and natural convection cooling mode. A 'Heat Transfer package' is used for calculating heat transfer coefficient, DNB heat flux etc. The 'Heat Transfer package' is a subroutine program and is especially developed for research reactors in which plate-type fuel is adopted. In case of rod-type fuel, DNB heat flux is calculated by both the 'Heat ...
The heavy chain (HC) subunits of the bikunin proteins are covalently attached to a single chondroitin sulfate (CS) chain originating from bikunin and can be transferred to different hyaluronan (HA) molecules by TSG-6/HC2. In the present study, we demonstrate that HCs transferred to HA may function as HC donors in subsequent transfer reactions, and we show that the CS of bikunin may serve as an HC acceptor, analogous to HA. Our data suggest that TSG-6/HC2 link HCs randomly on the CS chain of bikunin, in contrast to the ordered attachment observed during the biosynthesis. Moreover, the results show that the transfer activity is indifferent to the new HC position, and the relocated HCs are thus prone to further TSG-6/HC2-induced transfer reactions. The data suggest that HCs may be transferred directly from HA to HA without the involvement of the bikunin CS chain. ...
In the presence of hydroxyl anion, both formaldehyde and glyoxal are known to undergo rearrangements involving intermolecular and intramolecular hydride transfer (the Cannizzaro and Benzilic acid rearrangements respectively). The authors report ab initio SCF-MO calculations of the transition state geometries, the activation barriers, and the hydrogen isotope effects for these two reactions. The structure of the transition state for the rection involving formaldehyde is usually basis set dependent, becoming more linear and symmetrical as the basis set size increases. In contrast, the analogous transition state for the glyoxal reaction involves a highly non-linear hydride transfer. They find the isotope effects to be quite low for the Cannizzaro reaction, and significantly larger for the non-linear benzilic acid rection, in apparent contradiction to Westheimer's suggestion the isotope effects reach a maximum for linear hydrogen ...
High-performance heat transfer augmentation methods applicable in the forced convection field of heat exchangers include a method which requires no external drive means, such as the insertion of a turbulence augmentation object into the flow passage and the use of a wave-shaped flow passage, but disturbs the main stream of flow to raise the heat transportation effect thereby to augment heat transfer in the flow passage. The heat transfer characteristics and thermal performance ratio achieved when sinusoidal-shape plates are inserted instead of augmentation objects, such as cylinders, with a high shape-induced resistance were studied. As a result, the relationship between the resistance coefficient, average Nusselt number, heat transfer coefficient, and pitch was clarified. It has been revealed that the use of eddies with a large gap flow and recirculation area should be considered in order to get a ...
Experiments are performed to investigate the single-phase flow and flow-boiling heat transfer augmentation in 3D internally finned and micro-finned helical tubes. The tests for single-phase flow heat transfer augmentation are carried out in helical tubes with a curvature of 0.0663 and a length of 1.15 m, and the examined range of the Reynolds number varies from 1000 to 8500. Within the applied range of Reynolds number, compared with the smooth helical tube, the average heat transfer augmentation ratio for the two finned tubes is 71% and 103%, but associated with a flow resistance increase of 90% and 140%, respectively. A higher fin height gives a higher heat transfer rate and a larger friction flow resistance. The tests for flow-boiling heat transfer are carried out in 3D internally micro-finned helical tube with a curvature of 0.0605 and a length of 0.668 m. Compared with that in ...
The studies of forced jet augmentation of natural convection heat transfer are introduced. It investigates experimentally mixed convection and heat transfer augmentation by forced jets in a large rectangular enclosure with a vertical cooling surface. The experiment is designed to measure the key parameters governing the heat transfer augmentation by a forced jet, and to investigate the effects of geometric factors, including the jet diameter, jet injection orientation, interior structures, and enclosure aspect ratio, on conditions simulating those of actual passive containment cooling systems and scales approaching those of actual containment buildings or compartments. The tests that cover a variety of injection modes will contribute to reveal the nature of mixing and stratification phenomena under accident conditions to a new generation of inherently safe reactors. With similarity considerations on governing equations, the ...
Numerical investigations of three-dimensional flow and heat transfer in a finned tube with punched longitudinal vortex generators (LVG`s) are carried out for Reynolds number of 250 and 300. Air with a Prandtl number of 0.7 is used as the fluid. The flow is both thermally and hydrodynamically developing. The LVG is a delta winglet pair (DWP) punched out of the fin and is located directly behind the tube, symmetrically separated by one tube diameter. The DWP generates longitudinal vortices in the wake of the tube, defers flow separation on the tube, deflects the main stream into the tube wake, and strong reduces the ``dead water zone.`` Heat transfer reversal is avoided by the DWP. Comparison of the span-averaged Nusselt numbers for the fin with and without DWP shows significant local heat transfer enhancement of several hundred percent in the tube wake. For Re = 300 and Fi = 200 the global heat transfer ...
LEDF(Large Equipment Dismantling Facility) is the solid waste processing technology development facility that carries out high-volume reduction and low dosage processing. The high-volume reduction processing of the high dose {alpha}-waste configured with combustible waste, pvc and rubber, spent ion exchange resin, and noncombustible waste have been planned the incinerating and melting facility using the in-can type high frequency induction heating in LEDF. This test is intended to clarify the design data. It was confirmed that the incinerating and melting performance, molten solid properties and exhaust gas processing performance with pilot testing equipment and bench scale equipment. The result of this test are as follows. 1. Processing speed is 6.7 kg/h for the combustible waste, 13.0 kg/h for the ion exchange resin, and 30.0 kg/h for the noncombustible waste. For above optimum processing conditions are as follows. Operating temperature is ...
A viscoelastically prestressed polymeric matrix composite (VPPMC) is produced by applying tension to polymeric fibres, the tensile load being released prior to moulding the fibres into a matrix. Following matrix solidification, compressive stresses imparted by the viscoelastically strained fibres improve composite tensile, flexural and impact properties. This study focuses on the potential for useful life and impact protection capability by performing Charpy impact tests on nylon 6,6 fibre-polyester resin samples subjected to accelerated ageing. Prior to testing, time-temperature superposition principles were used, the samples being aged by heating to 60degreeC for periods representing a 10-fold increase over previous work. The results demonstrated no deterioration in impact performance ov...
The extraction of rare earth elements, yttrium and aluminium from red mud resulting from alumina production with the ion-exchange resin KU-2-8n was studied. Experimental results are presented. The technology of hydrometallurgical processing of pulps obtained by sorption extraction of scandium from red mud is developed. It is shown that in the process of precipitation from sulfate sulfuric acid desorbate it became possible to obtain a high degree of rare earths deposition. The use of sodium hydroxide makes it possible to obtain a maximum deposition of rare earths and aluminium - 99.9 %. Aluminium leaching from crude composite concentrate gives a possibility to get concentrates which 15 - 20 times richer in yttrium and rare earths
As part of the general QC/QA management of the k_0-standardization, three types of 'SMELS' (synthetic multi-element standards) are being developed to check the performance of k_0-NAA when implemented in a laboratory. Phenol-formaldehyde resin is proposed in this paper as the matrix of choice. Based on previous work, this material could be prepared with sufficient purity so as to make interferences with the spiking elements negligible. The matrix was found to be adequately resistant towards high neutron flux irradiation. A selection was made of compounds, soluble in ethyl alcohol, for spiking the prepolymer ethanolic solution with the elements of interest. Finally, some prototypes were prepared and a satisfactory homogeneity of the spiked elements was found for 50 mg sample intake.
A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.
A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.
The small pilot facility of a cyclone type suspension incineration system of radioactive waste was set up in order to evaluate the decontamination efficiency of a high efficiency ceramic filter. The evaluation was made by use of /sup 54/Mn, /sup 59/Fe, /sup 60/Co, /sup 65/Zn and /sup 137/Cs. 1. The decontamination factor by one line of ceramic filter for every species were over 10/sup 5/. 2. The decontamination factor increased by one oder when water vapor exists in off-gas. The same tendency was also observed when iron dioxide existed at the incineration of cation exchange resin.
The small pilot facility of a cyclone type suspension incineration system of radioactive waste was set up in order to evaluate the decontamination efficiency of a high efficiency ceramic filter. The evaluation was made by use of "5"4Mn, "5"9Fe, "6"0Co, "6"5Zn and "1"3"7Cs. 1. The decontamination factor by one line of ceramic filter for every species were over 10"5. 2. The decontamination factor increased by one oder when water vapor exists in off-gas. The same tendency was also observed when iron dioxide existed at the incineration of cation exchange resin. (author).
Optimum processing parameters were searched for the pilot-scale production of wood-polyester composites by irradiation of resin-impregnated wood material. The radiation initiation of the following systems were examined in wood and without wood matrix: methyl methacrylate, mixture of styrene and acrylonitryle, and their combination with unsaturated polyester. In the most cases the over-all rate of the complete polymerization process in wood matrix is proportional to the square root of the initiation rate. The parameters of the radiation technology of wood-polyester composites have been determined, using 260 TBq (7 kCi) "6"0Co radiation source. A pilot plant has been constructed using an underwater irradiation system of 1.85 PBq (50 kCi) "6"0Co. The successful production rate of 200 kg wood-polyester composite per day, as well as the application tests have demonstrated the technical feasibility of this new structural material. (author).
Twelve powders of TiO_2-Y_2O_3-ZrO_2 solid solution of the methodically changed composition were prepared by a coprecipitation-calcination technique. After mixing with phenol-formaldehyde resin, the powders were calcinated for 2 hours at 1200"oC in vacuum. The resultant composite powders contained TiC and non-reacted carbon. Green compacts were sintered in vacuum at 1500"oC for 2 hours. A temperature increase was stopped at 1200"oC to react remains of carbon. There were two carbides in the composites TiC and ZrC. TiC non-stoichiometry depended on carbon content in the system. Phase composition of the depended on of titania and yttria in zirconia solid solution. The majority of the samples showed two tetragonal zirconia phases differing in lattice parameter and tetragonality. (author)
This patent describes a method of reducing the hydrogen sulfide level in streams containing hydrogen sulfide at concentrations from about 2 ppm up to about 1,000 ppm. It comprises reacting the hydrogen sulfide with an unsaturated hydrocarbon in the presence of an acidic solid catalyst selected from the group consisting of polymeric sulfonic acid resins, solid polyphosphoric acid, supported sulfuric acid, supported boric acid, silica-aluminas, clays, faujasite, mordenite, and L, omega, X or Y zeolites at mercaptan-forming concentrations, and recovering a stream having a reduced hydrogen sulfide concentration and containing no more than 5 ppm hydrogen sulfide.
When operating a nuclear power plant the necessity arise to eliminate various defects of building constructions, to seal joints and transitional elements. The authors present data concerning the production of a sealing composition made of epoxy resin and used for NPP premises of emergency location. Analytical relations are presented between the properties of the composition (adhesion strength, water absorption and others) and its structure. Physical, mechanical and thermal properties and structural peculiarities are determined in the process of interaction between the filling and binding agents. The composition sustains sealing properties under environmental conditions at he presence of an air - vapour mixture with 160 degrees C"o temperature and 0.3 MPa surplus pressure. (author).
Many higher plants produce economically important organic compounds such as oils, resins, tannins, natural rubber, gums, waxes, dyes, flavors and fragrances, pharmaceuticals, and pesticides. However, most species of higher plants have never been described, much less surveyed for chemical or biologically active constituents, and new sources of commercially valuable materials remain to be discovered. Advances in biotechnology, particularly methods for culturing plants cells and tissues, should provide new means for the commercial processing of even rare plants and the chemicals they produce. These new technologies will extend and enhance the usefulness of plants as renewable resources of valuable chemicals. In the future, biologically active plant-derived chemicals can be expected to play an increasingly significant role in the commercial development of new products for regulating plant growth and for insect and weed control. 65 references.
The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.
Tests using reconstituted samples have been performed to assess the diffusive transport of 137Cs and 60Co through natural regolith materials from a region in South Australia being considered for a radioactive waste repository. A double diffusion cell apparatus made of polycarbonate resin was developed to estimate the effective diffusion (De) and sorption coefficients (Kd) that allowed large withdrawals from the source and collector cells and has enabled tests with low concentrations of radioactivity. An alternative to porous stainless steel filter plates has also been used to reduce uncertainty in test interpretation. Analysis of the transient data used a staged method of the Laplace transform to take into consideration the volume of the samples withdrawn from the apparatus during testing....
Using electrochemical techniques of pH-metry and conductimetry, the choice of a suitable complexing reagent was made amongst ethylene glycol, propylene glycol, dextrose and mannitol for cost-effective separation of isotopes of boron by ion exchange chromatography. Quantitative relationships between pH and concentration; pK_a and concentration of each of these complexing reagents were determined by least square polynomial curve fitting and an attempt was made to determine the formation constants of mannitol-borate complex. The results of experiments carried out for selection; regeneration of a resin; separation factor determinations using batch as well as column techniques and monitoring of band movements using these electrochemical techniques are discussed. (author).
The losses of Hg from phenol formaldehyde resin - bound standards and hair samples in neutron activation analysis in case of their irradiation in the water filled nuclear reactor channel is studied. The mean losses of Hg during 20-30 hrs irradiation at (2-3)x10"1"8 n/cm"2 are 15-20% with their stopping at double Al-covers. The mean losses of Hg from standards at 200, 250 and 300 deg C are 30, 61 and 86% respectively and do not occur at 150 deg C after their 5 hour heating. The losses of Hg from hair samples packed in polyethylene tubes through the package walls in experimental conditions are not observed.
An instrumental neutron activation technique of determining molybdenum in ores is based on measuring gamma-activity of the "9"9Mo isotope with the use of planar and coaxial semiconductor spectrometers. A lot consisting of 50 portions, 0.5 g each, is being irradiated for 10 hours by a flow of neutrons with the density of 10"1"2 n/cm"2xsec. On the lot being allowed to stay for 3-4 days, its activity is measured during 1-5 minutes. Monoethalons based upon phenol-formaldehyde resin are used as standards. The sensitivity of the technique is 10"-"4%, reproducibility error being not higher than 10%, efficiency up to 50 portions for a working shift.
Objectives: The aim of this study was to evaluate the in vitro behaviour of all-ceramic zirconia molar crowns in regard to different core designs and marginal fit. Methods: Identically shaped methacrylate molars were prepared according to the ceramic restoration directives resulting in a 1-mm deep circular shoulder preparation. They were embedded in polymethylmethacrylate resin after covering their roots with a polyether layer to simulate periodontal mobility. The crown cores were made of yttria-stabilized zirconia veneered with a corresponding veneering ceramic. The crowns were divided into 5 groups (n=8) which differed in core design and cement gap thickness: #1: simple core, 40mm cement; #2: core with minimal occlusal support, 40mm cement; #3: core with optimized cusp support, 40mm ceme...
Nanocomposites comprising nanocrystal silicon (Si), disordered carbon (DC), and multi-walled carbon nanotubes (MWCNTs) - denoted as Si/DC/MWCNTs - have been prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with Si and MWCNTs. This nanocomposite anode material showed a discharge capacity of 1216 mAh/g in the first cycle, and a charge capacity of 711 mAh/g after 20 charge-discharge, much higher than that of Si/DC composite. It can be observed that Si particles wrapped in MWCNTs were homogeneously embedded into the matrix of the DC. The improved electrochemical performance is hypothesized to be mainly attributed to the morphology stability of the composite due to the excellent resiliency and distinct electric conductivity of the MWCNTs.
Statement of problem Although the esthetic outcome of a collarless metal ceramic restoration is superior to that of a restoration with a metal margin, its mechanical strength has not been evaluated. Purpose The purpose of this study was to evaluate and compare the fracture resistance of metal ceramic restorations with metal margins to that of metal ceramic restorations with circumferential porcelain margins, after exposure to masticatory simulation. Material and methods Twenty-four metal ceramic restorations were fabricated and paired with 24 cobalt-chrome tooth analogs. Twelve of the specimens had metal margins, while the remainder had circumferential porcelain margins. The restorations were cemented on the metal tooth analogs with a resin-modified glass ionomer luting agent (FujiCEM). Al...
The formaldehyde surface emission monitor (FSEM) has been developed for passive non-destructive measurement of formaldehyde (CH/sub 2/O) emission rates from CH/sub 2/O resin-containing materials. It is envisaged as a potential quality control and in-situ monitoring technique. For quality control applications to pressed-wood products, strong correlations between the results of the FSEM and environmentally controlled (small scale) chamber tests were observed. The FSEM is used to measure the cumulative CH/sub 2/O emission from a finite area of pressed-wood product during a fixed test period. The final result is reported as an average CH/sub 2/O emission rate (mg CH/sub 2/O/m/sup 2/h).
Introduction The objective of this study was to investigate the in-vitro fluoride release from a glass ionomer orthodontic bonding system (Fuji I, GC Corporation, Tokyo, Japan) over a 2-month period and the in-vivo enamel fluoride uptake after 6 months. Methods Ten metal brackets were bonded with either glass ionomer or composite resin (Transbond XT, 3M Unitek, Monrovia, Calif; Light Cure), which served as controls, to recently extracted molars. The bonded teeth, cut at the level of their roots, were stored in distilled water that was renewed after every fluoride measurement at 1, 3, 7, 30, and 60 days. The in-vitro fluoride release was measured by using a fluoride ion-selective electrode, connected to an ion analyzer. Fifteen pairs of premolars were bonded with metal brackets with either ...
A method is described for determination of aluminium, cadmium, cobalt, chromium, copper, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, zinc, titanium and vanadium in iron ore. After dissolution, a 1 gram sample of iron ore is applied to a column of AGI-X8 anion exchange resin (chloride form), in 100 ml of 7M HCl. Aluminium, chromium, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, titanium and vanadium are eluted with 7M HCl; iron, copper and cobalt are eluted with 0.5M HCl; cadmium and zinc are eluted with 2M HNO_3. Iron is subsequently removed from copper and cobalt by a solvent extraction with methyl isobutyl ketone. The elements are determined in the eluates by atomic absorption spectrometry, except for titanium and vanadium, which are determined spectrophotometrically.
Abstract Lysis and extraction of cells are essential sample processing steps for investigations pertaining to metabolism of xenobiotics in cell culture studies. Of particular importance to these procedures are maintaining high lysis efficiency and analyte integrity as they influence the qualitative and quantitative distribution of drug and toxicant metabolites in the intra- and extracellular milieus. In this study we have compared the efficiency of different procedures viz. homogenization, sonication, bead beating, and molecular grinding resin treatment for disruption of HT-29 colon cells exposed to benzo(a)pyrene (BaP), a polycyclic aromatic hydrocarbon (PAH) compound and a suspected colon carcinogen. Also, we have evaluated the efficiency of various procedures for extracting BaP parent c...
Recently, great interest was paid to new technologies dealing with environmental aspect. Preservation of natural resources such as natural fibers forced the composite industry to search and examine "eco-friendly" components. Studies to find alternative reinforcements and resin systems that are environmentally friendly while providing the same performance as their synthetic counterparts are in continuous progress. The aim of this study is to investigate effect of different treatment process on the data palm fiber (DPF). Raw DPF underwent different surface modification methods such as alkali treatment with concentrations 0.5%, 1%, 1.5%, 2.5% and 5%, and acid treatment with 0.3, 0.9 and 1.6N. All treatments were performed at 100degreeC for 1h. The surface morphology, thermal gravimetry analys...
The project is intended to yield information on the transfer factors describing the transfer of ingested radionuclides to breast milk for the following elements: antimony, cerium, chromium, cobalt, gallium, lanthanum, molybdenum, niobium, radium, ruthenium, silver, thorium, titanium, and uranium. Those yet unknown or poorly known transfer factors are required in order to be able to develop a reliable model for description and assessment of the transfer of the radionuclides and the possibly resulting hazardous doses to infants, and for subsequent formulation of recommendations for radiological protection of the population. (orig./CB) [German] Ziel des Projektes ist die Ermittlung von Transferfaktoren fuer den Uebergang von Radionukliden aus der Nahrung der Muetter in die Muttermilch fuer die Elemente Antimon, Cer, Chrom, Cobalt, Gallium, Lanthan, Molybdaen, Niob, Radium, Ruthenium, Silber, Thorium, Titan ...
Experiments were performed to measure the transfer of trichloroethylene (TCE), a volatile organic compound (VOC), from tap water in showers to indoor air. In these experiments, the loss of TCE from tap water in the shower is based on the difference between influent and effluent concentrations.We have developed and previously published a three-compartment model, which we use to simulate the 24-h concentration history of VOCs in the shower, bathroom, and remaining household volumes resulting from the use of contaminated tap water. An important input to this model is the transfer efficiency of the VOC from water to air. The experiments reveal that the transfer efficiency of TCE from shower water to air has an arithmetic mean value of 51 percent and an arithmetic standard deviation of 9 percent. Analysis of the results shows that there is no statistically significant difference between the transfer ...
There are 4 CANDU reactors at Wolsung site together with a spent fuel dry storage associated with unit 1. These CANDU reactors, classified as On-Load Reactor (OLR) for Safeguards application, change 16- 24 fuel bundles with fresh fuel in everyday. Especially, the spent fuel bundles are transferred from spent fuel bays to dry storage throughout a year because of the insufficient capacity of spent fuel pond. Safeguards inspectors verify the spent fuel transfer to meet safeguards purposes according to the safeguards criteria by means of inspector's presence during the transfer campaign. For the verification, 60-80 person-days of inspection (PDIs) are needed during approximately 3 months for each unit. In order to reduce the inspection effort and operators' burden, an Unattended Monitoring System (UMS) was designed and developed by the IAEA for the verification of spent fuel bundles ...
A centrifugal pump was developed for the efficient and reliable transfer of liquid helium in space. The pump can be used to refill cryostats on orbiting satellites which use liquid helium for refrigeration at extremely low temperatures. The pump meets the head and flow requirements of on-orbit helium transfer: a flow rate of 800 L/hr at a head of 128 J/kg. The overall pump efficiency at the design point is 0.45. The design head and flow requirements are met with zero net positive suction head, which is the condition in an orbiting helium supply Dewar. The mass transfer efficiency calculated for a space transfer operation is 0.99. Steel ball bearings are used with gas fiber-reinforced teflon retainers to provide solid lubrication. These bearings have demonstrated the longest life in liquid helium endurance tests under simulated pumping conditions. Technology developed in the project also has application ...
The transfer kinetics of the monosiaylated glycosphingolipid, GM_1, between different size phospholipid vesicles was measured using molecular sieve chromatography. At desired time intervals, small unilamellar donor vesicles were separated from large unilamellar acceptor vesicles by elution from a Sephacryl S-500 column ["3H]-GM_1 net transfer was calculated relative to ["1"4C]-cholesteryl oleate, which served as a nontransferable marker in the donor vesicles. The initial GM_1 transfer rate between 1-palmitoyl-2-oleoyl phosphatidylcholine vesicles at 45"0C deviated slightly from first order kinetics and possessed a half time of 3.6 days. This transfer half time is an order of magnitude shorter than that observed from the desiaylated derivative of GM_1. The transfer kinetics are consistent with the authors recent electron microscopic results suggesting a molecular distribution of GM_1 ...
This research has been proceeded over the potential core region (H/B=2) of two-dimensional impinging air jet system, in which square rods(width of 6 mm) has been set up in front of heating surface in order to increase heat transfer. The objective of this research was to investigate the characteristics of heat transfer and air flow, in cases of the clearance from rods to heating surface (C = 1, 2, 4, 6 mm) and the pitch between each rods(P = 30, 40, 50 mm) changed. And this research compared the above with the experimentation without rods. As result, heat transfer performance was best under the condition of C = 1 mm, in case clearance changed, and there was no serious difference in the effect of heat transfer augmentation in the case of pitch of rods changed. (author) 11 refs. 12 figs.
The SMART (System-integrated Modular Advanced ReacTor) which is a 330 MWt advanced integral PWR was developed by the KAERI (Korea Atomic Energy Institute) for electricity generation and seawater desalination. A thermal hydraulic evaluation and analysis of the SMART is performed by the TASS /SMR-S (Transient And Setpoint Simulation/System integrated Modular Reactor-Safety). The TASS/SMR-S code has various models reflecting the design features of the SMART such as the drift flux model, the core models (core power and core heat transfer model), the component models, and the specific models. One of the core models is the core heat transfer model. The role of this model is to calculate the heat flux and radial temperature profiles at a fuel rod surface using the relevant heat transfer correlations for all of the heat transfer modes. Also it is modeled to meet the requirements of the 10 CFR 50 appendix K EM ...
Heat transfer tubes of a primary pressurized water cooled (PPWC) in the high temperature engineering test reactor (HTTR) form the reactor pressure boundary of the primary coolant, therefore are important from the viewpoint of safety. To establish inspection techniques for the heat transfer tubes of the PPWC, an automatic inspection system was developed. The system employs a bobbin coil probe, a rotating probe for eddy current testing (ECT) and a rotating probe for ultrasonic testing (UT). Nondestructive test of a half of the heat transfer tubes of the PPWC was carried out by the automatic inspection system during reactor shutdown period of the HTTR (about 55% in the maximum reactor power in this paper). The nondestructive test results showed that the maximum signal-to-noise ratio was 1.8 in ECT. Pattern and phase of Lissajous wave, which were obtained for the heat transfer tube of the PPWC, were ...
An impinging jet is a widely used technique for realizing high heat-transfer rates between a fluid and a surface. However, the area of enhanced heat transfer is limited to the neighborhood of the stagnation point. In this study, heat transfer is augmented remote from the stagnation point in an impinging plane jet system by a rod array located near the wall. Each square rod in the array was positioned normal to the flow direction and parallel to the flat plate surface. The distance between the nozzle and the flat plate (H) and the spacing between the rods and the flat plate surface (C) were changed to find the optimum values. The largest heat-transfer augmentation was obtained for C = 1 mm, H/B = 10, where the jet nozzle width is B. In this case, the heat-transfer coefficient averaged over an area 2B from the stagnation point is about 1.6 times greater compared to that without a rod ...
There are various interesting semantics' (extensions) designed for argumentation frameworks. They enable to assign a meaning, e.g., to odd-length cycles. Our main motivation is to transfer semantics' proposed by Baroni, Giacomin and Guida for argumetation frameworks with odd-length cycles to logic programs with odd-length cycles through default negation. The developed construction is even stronger. For a given logic program an argumentation framework is defined. The construction enables to transfer each semantics of the resulting argumentation framework to a semantics of the given logic program. Weak points of the construction are discussed and some future continuations of this approach are outlined.
Heat transfer and flow characteristics of water boiling flow were experimentally investigated in narrow horizontal rectangular channels with the gaps of 0.6mm-2.03mm. The heat transfer of two-phase boiling flow was weakend in smaller gap. The two-phase friction pressure drop decreased with the gap size and the two-phase friction multipliers were smaller compared with those in normal channels. Correlations to predict te boiling heat transfer coefficients were obtained. (author)
The rate at which full-scale technology transfer takes place depends on the quality of the supply companies, i.e. training, organisational development and product infrastructure. These parameters are discussed for the example of a water mill, and a flow diagram is presented. [Deutsch] Wie rasch ein umfassender Transfer in Frage kommt, entscheidet sich mit der Qualitaet und dem Niveau der zuliefernden Betriebe. Hierbei sind Ausbildung, Organisationsentwicklung und Produktionsinfrastruktur besonders angesprochen. Fuer eine Wassermuehle werden diese Parameter konkret eroertert und an Durchlaufdiagrammen erlaeutert. (GL)
A large amount of energy has been consumed so far in so called matured industries such as iron and steel, oil refinery, petrochemical, ceramic, paper and pulp manufacturing and so forth. A successive stimulation on the preceding industries has to be enhanced from a technological viewpoint in order to maintain a further development based on novel and innovative technologies. In this regard, energy technology has become and will be increasingly important in a high temperature system so that the basic concept for heat transfer augmentation methods by thermal radiation is reviewed briefly in accord with the recent developments together with theoretical background and the prominent features. The heat transfer augmentation related to thermal radiation is summarized.
In the present work the geometry of annular ducts with asymmetrical longitudinal fins is optimized in order to enhance the heat transfer under laminar coolant flow conditions. The heat transferred is also maximized for a given amount of material or hydraulic resistance. Polynomial profiles are assigned to the two lateral fin surfaces. Velocity and temperature distributions on the annular duct cross section are determined with the help of a finite-element model. A global heat transfer coefficient and an equivalent Nusselt number are then calculated. Lastly, optimum asymmetrical fins obtained by means of a genetic algorithm are shown for different situations and their performance is compared with those of optimum symmetrical fins.
This paper focuses on the design and modeling of the humidification dehumidification desalination (HDH) process. The process is only found on experimental or very small pilot scale. Literature studies are rather limited and it includes a number of experimental investigations, performance evaluation, and measurements of the heat and mass transfer coefficients. This study includes useful and new data on the evaluation of the heat transfer coefficient of the humid air stream in the condenser unit. The analysis develops a correlation for the heat transfer coefficient for the humid air stream as a function of the Reynolds and Prandtl numbers. Also, detailed evaluation of the system performance is presented as a function of the system temperatures and the inlet relative humidity of the air strea...
Numerical solutions for fully developed laminar flow in internally finned tubes with trapezoidal and triangular fin profiles were given with Finite Element Method (FEM): The heat transfer characteristics were obtained and compared under the boundary conditions of uniform heat flux, uniform wall temperature, and the third boundary condition with finite wall thermal conductivity considered. The numerical results show that boundary conditions have pronounced effects on the temperature field. Furthermore, a new mechanism on the heat transfer augmentation of internally finned tubes is proposed.
Analytical solutions are derived for a flow in a semi-infinite vertical porous medium with heat and mass transfer. When the temperature and mass concentration are uniform a constant pressure is possible and sustains a fully developed flow. Thereafter there is a small perturbation on the wall temperature and concentration and the subsequent two-dimensional problem is tackled for a large Prandtl number, free convection parameters and small Reynolds number. The heat transfer rate at the wall is discussed quantitatively. (author). 4 refs.
Experiments were conducted to study the condensation heat transfer characteristics of horizontal enhanced tubes. In the current experiment, six different enhanced tubes, including 26, 40 fpi low fin tubes and four three-dimensional-fin tubes, were tested. The working fluid used in the experiment was HCFC-22. Data were presented in the form of overall heat transfer coefficient at three working pressures, namely 1.32, 1.47 and 1.62 Mpa. In addition, the condensing heat transfer coefficients for the test tubes were obtained from the Wilson plot technique.
A computer code ICRKFLO was used to simulate the multiphase reacting flow of fluidized catalytic cracking (FCC) riser reactors. The simulation provided a fundamental understanding of the hydrodynamics and heat transfer processes in an FCC riser reactor, critical to the development of a new high performance unit. The code was able to make predictions that are in good agreement with available pilot-scale test data. Computational results indicate that the heat transfer and droplet evaporation processes have a significant impact on the performance of a pilot-scale FCC unit. The impact could become even greater on scale-up units.
Here I provide a brief overview of recent experimental gas-phase measurements using the Selected-Ion Flow Tube or SIFT technique at 294#+-#2 K with helium buffer gas at 0.35 Torr for reactions which remove electrons from the C_6_0 molecule or donate electrons to singly and multiply-charged C_6_0 cations. The results of these measurements have provided new insight into physicochemical aspects of electron transfer and have revealed the occurrence of unprecedented electron transfer reactions at thermal energies. (author).
The energy spectra of few-nucleon transfer reactions obtained by bombarding a /sup 197/Au nucleus with the 341 MeV /sup 20/Ne beam of the Berkeley cyclotron have been analysed successfully in terms of direct surface transfer reactions populating the continuum states. At the grazing angle we are dealing with one-step processes; at forward angle two-step processes have to be taken into account.
The Fast Flux Test Facility near Richland, Washington, utilizes computer control for reactor refueling and other related core component handling and processing tasks. The computer controlled tasks described in this paper include core component transfers within the reactor vessel, core component transfers into and out of the reactor vessel, remote duct measurements of irradiated core components, remote duct cutting, and finally, transferring irradiated components out of the reactor containment building for off-site shipments or to long term storage. 3 refs., 16 figs.
Excitation transfer between the 3S[sub 1/2] states of the lithium isotopes [sup 6]Li and [sup 7]Li is measured in a thermionic diode. The 3S level is excited by off-resonant two-photon transitions with a single mode cw laser. The relative densities of the directly excited and collisionally populated levels are probed by further laser excitation to the 12P levels. An energy transfer cross section of 585 A[sup 2] [+-] 160 A[sup 2] is found at the experimental temperature of about 850 K. A simple semiclassical calculation yields a cross section of 450 A[sup 2]. (orig.)
Constant property, laminar flow heat transfer in a semicircular tube with uniform wall temperature has been analyzed to define the lower bound of heat transfer augmentation in circular tubes with twisted-tape inserts. Two thermal boundary conditions, which correspond to the two extremes of the fin effect of twisted tapes encountered in practical applications, are considered. Numerical solutions, employing finite-difference formulations for the governing momentum and energy equations were carried out for the thermal entrance region and for fully developed flow.
The humidification?dehumidification process is an interesting technique that has been adapted for water desalination. Previous works experimentally investigated desalination processes in the shell and tube columns, where the humidification and dehumidification were thermally coupled and simultaneously performed at the tube and shell sides, respectively. In this work, a comprehensive steady-state mathematical model was developed for such a humidification?dehumidification desalination process by taking into account the heat and mass balances on both sides of the desalting column, the mass transfer rate at the humidification side, and the heat transfer rate between the dehumidification side and humidification side. Meanwhile, the mass transfer coefficient at the humidification side and the to...
the nozzle ring, the collector cup, and the impeller fuel-distribution ... sity of the vaned collector cup and the fuel-transfer passages ..... closure ...
If you are a FERS employee (the current retirement system), you lose your sick leave if you do not return to Federal service. If you separate from the Federal ...
In recent years, there has been increased emphasis on techniques to enhance two-phase flow heat transfer. The resulting increase in the use of heat transfer augmentation and the engineering importance of the subject presents this investigation in order to study the effect of different heater surface configurations on two-phase flow instabilities. The authors present the results of an experimental and theoretical study, summarized as: instabilities are not affected by small changes in heat transfer; nucleate boiling increases system unstability; amplitude of the oscillations increases as the axial temperature gradient over the heater increases; for the same type heater surfaces system stability increases with decreasing equivalent diameter; period of the oscillations depend on the heater surfaces; and linearized analysis and steady-state data can be used to determine the oscillation thresholds.
Transfer factors of "2"1"0Po from soil to parsley and mint have been determined. Artificial polonium isotope ("2"0"8Po) was used as a tracer to determine transfer factor of Po from soil to plant in pot experiments. Two plant growing systems were used for this study namely, an outdoor system and a sheltered system by a polyethylene tent. "2"0"8Po and "2"1"0Po were determined in soil and different parts of the studied plants (stem and leaf), using alpha spectroscopy. The results have shown that there was a clear uptake of "2"0"8Po by roots to leaves and stems of both plants. Higher values of transfer factors using the "2"1"0Po activity concentrations than the "2"0"8Po activity concentration were observed. Transfer factors of "2"1"0Po from soil to parsley varied between 20 x 10"-"2 and 50 x 10"-"2 and 22 x 10"-"3 and 67 x 10"-"3 in mint, while "2"0"8Po transfer factors varied between 4 ...
Nuclear transfer technology can be applied to produce autologous differentiated cells for therapeutic purposes, a concept termed therapeutic cloning. Countless articles have been published on the ethics...Full Text Available
The experimental survey about the heat transfer between the working fluid and the combustion chamber wall with a direct injection diesel engine has shown the production of a soot layer with increasing loads on the combustion chamber wall. Because the combustion process of methanol occurs without the formation of wall deposits, the same engine spark ignitioned with methanol at the same conditions has shown a higher heat transfer coefficient. Because the heat losses do not only depend on the heat transfer coefficient but also on the driving temperature difference between the working fluid and the combustion chamber wall, the methanol engine with corresponding process management showed lower heat losses than the diesel engine at nearly the same load. (orig./HW)
A theory for the mass transfer process was developed. It was assumed that the largest convective motions in the flow control the rate of mass transfer. Measurements of mass transfer coefficients for the absorption of oxygen by water films were made for concurrent flows in a horizontal rectangular channel, and for concurrent and free-falling downflow in a one-inch pipe. The measured values of the Sherwood number for concurrent flows were up to three times as great as would be predicted from this relation. This increase in Sherwood number was correlated with a dimensionless group similar to a Martinelli parameter which is characteristic of two phase flows. An explanation for this effect is given in terms of the way that the scales of the convective motions are related to bulk flow parameters.
Based on the enhanced cooperation between Republic of Korea (ROK) and International Atomic Energy Agency (IAEA), IAEA installed new safeguards equipment (Unattended Monitoring System, UMS) at Wolsung unit 2 on January, 2005. The UMS was utilized in parallel with traditional human surveillance during the transfer campaign of Wolsung unit 2 (7 March - 22 July). Installation of UMS at all Wolsung units will be decided on the basis of the result of this test. The transfer campaign with UMS at Wolsung units 2 and 4 was started from September 1, 2006 at the same time. Implementation of UMS to the transfer campaign in Wolsung site will be considerably reduced the IAEA's inspection effort and burden of operator.
Based on the enhanced cooperation between Republic of Korea (ROK) and International Atomic Energy Agency (IAEA), IAEA installed new safeguards equipment (Unattended Monitoring System, UMS) at Wolsung unit 2 on January, 2005. The UMS was utilized in parallel with traditional human surveillance during the transfer campaign of Wolsung unit 2 (7 March - 22 July). Installation of UMS at all Wolsung units will be decided on the basis of the result of this test. The transfer campaign with UMS at Wolsung units 2 and 4 was started from September 1, 2006 at the same time. Implementation of UMS to the transfer campaign in Wolsung site will be considerably reduced the IAEA's inspection effort and burden of operator.
We compare the accretion flow onto the neutron star induced by Roche lobe overflow with that by the overflow from the Be disk, in a zero eccentricity, short period binary with the same mass transfer rate, performing three-dimensional Smoothed Particle Hydrodynamics simulations. We find that a persistent accretion disk is formed around the neutron star in both cases. The circularization radius of the material transferred via Roche lobe overflow is larger than that of the material transfered from the Be disk. Thus, the growth of the accretion disk in the former case becomes significantly slower than in the latter case. In both cases, the mass accretion rate is very small and varies little with orbital phase, which is consistent with the observed X-ray behaviour of Be/X-ray binaries with circular orbits (e.g. XTE J1543-568).
Corrosion of steam generator heat transfer tubes (SGHTT) is one of the important problems which affect safety operation of nuclear power plants (NPP), and the hazard of pitting corrosion of heat transfer tubes is the most serious. With an acoustic emission device, the signals during a corrosion test on SGHTT were collected and analyzed, and the corrosion points in the tubes were located accurately. The results show that pitting corrosion of heat transfer tubes has passed through three periods in its development: expansion phase, stationary phase and rapid developing phase. The corrosion damage of HTT can be found earlier with acoustic emission than any other non-destructive testing methods. Acoustic emission can be used for on-line and real-time monitoring of the safety and operation of the steam generator and has therefore a great significance. (orig.)
Lentiviral vectors (LVs) have emerged as potent and versatile vectors for ex vivo or in vivo gene transfer into dividing and nondividing cells. Robust phenotypic correction...Full Text Available
This paper describes the construction of PWR horizontal steam generator in Soviet Union, the water chemistry treatment for secondary side, the design of steam separator, the test of heat transfer characteristics and operation. (author).
The goal of this experiment is to evaluate the usefulness of existing normal gravity two-phase flow heat transfer augmentation techniques under microgravity ...
This paper presents a set of heuristics useful for optimal design of heat-exchange networks and integrated heat and power systems. These heuristics consolidate other approaches reported in the literature in a formalism useful for design purposes.
o If retaining CSRS/FERS, transferred employee will be credited with accumulated sick leave o Be reimbursed for travel, transportation, relocation costs ...
A waterjet coating-removal system was developed at NASA's Marshall Space Flight Center in Huntsville, Ala., to remove thermal protective coatings from the ...
coupled heat/mass transfer Stefan problem. Taking the diffusion coefficient of Bi as a free parameter, the best fit was observed for the published value, ...
The kinetic energy transferred to some elements by an electron of kinetic energy 100 to 400 kV is discussed. The displacement rates are compared to the signal generation. (DCL)
The heat transfer augmentation effect by the unsteady heat conduction between the particles and heat transfer surface is one of the main factors, causing the heat transfer augmentation around the stagnation point in the gas-solid two-phase impinging jet flow. By separating and evaluating that effect, material influence on it was studied of particles and heat transfer surface, together with change by the jet flow condition. That effect enlarged with enlarging in heat capacity, multiplied by the heat conduction coefficient, of both the particles and heat transfer surface, and if both of them were constant in material combination, was dominated by the contact frequency of particles per unit time. Therefore in case of lading solid particles, equal in weight, that effect enlarges with diminishing in particle diameter. Such a heat transfer augmentation mechanism model ...
The efficiency of dendrosome (a gene porter) was assessed in transferring recombinant human rotavirus VP2 cDNA into A549, a human lung cell line. After gene transferring, transmission electron microscopy showed core-like particles (CLPs) formation in the transfected cells both with dendrosome and lipofectamine porters. In addition, western blotting analysis showed that the expression of VP2 gene was almost equal in the dendrosome and lipofectamine-transfected cells. Also, the cytotoxicity studies revealed that dendrosome had a lower cytotoxicity than lipofectamine. Therefore, our study may introduce dendrosome as a possible carrier for gene transferring into the human lung cell line, especially, for intranasally administration of DNA vaccines.
The measurement of local heat transfer coefficients is necessary to record the basic phenomena of heat transfer in thin-film apparatuses. For this reason the so-called electrochemical analogy method was developed and used for this application. The electrochemical method implies a specifically composed electrolyte which substitutes the fluid to be evaporated in the thin-film apparatus. Using the redox electrolyte (0,025 kmol/m/sup 3/ K/sub 4/Fe(CN)/sub 6/ resp. k/sub 4/Fe(CN)/sub 6/ and 2nNaOH) the viscosity was, for the first time, thickened until 0.4 Pa s by the help of hydroxyethyl-cellulose.
Means of intensifying heat transfer with nucleate boiling, based on boiling under constrained conditions (in slots, on a capillary-porous surface) are the most promising since a high intensity of heat transfer is ensured. In the present work we attempt to evolve the main assumptions for the physical model of the process of vapour formation under constrained conditions and to extend them to the boiling of cryogenic liquids on surfaces with a capillary-porous deposit; also, the results are given of experimental investigations of heat transfer with the boiling of nitrogen, oxygen and hydrogen at atmospheric perssures and below on capillary-porous surfaces of various metals of different structure produced by an electric arc method of gasothermal spray coating.
A numerical investigation for forced convection in a constant-temperature parallel plate channel with porous cavity and block alternately emplaced on the bottom plate is presented in this work. The Brinkman-Forchheimer-extended Darcy model, which accounts for the effects of impermeable boundary and inertia, is used to characterize the flow field inside the porous region. Solutions of the coupled governing equations are carried out through the stream function-vorticity analysis. The characteristics of fluid flow and forced convection heat transfer have been obtained by the examinations of various governing parameters, such as the Reynolds number, Darcy number, inertial parameter, Prandtl number, and two geometric parameters. Several interesting phenomena such as the heat transfer augmentation in the channel were presented and discussed. The results of this investigation indicate that the size of recirculation caused by porous block will have a ...
Ferrofluids have promising potential for heat transfer applications, since advective transport in a ferrofluid can be readily controlled by using an external magnetic field. However, unlike conventional free or forced convection, ferrohydrodynamic convection is not yet well characterized. A full understanding of the relationship between an imposed magnetic field, the resulting ferrofluid flow, and the temperature distribution is a prerequisite for the proper design and implementation of applications involving thermomagnetic convection. The literature variously assumes constant magnetic fields, does not completely represent the variation in the imposed field, or its descriptions are inaccurate, since the fields do not comply with the Maxwell's equations of electromagnetism. We address this by simulating two-dimensional forced convection heat transfer in a channel with a ferrofluid that is under the influence of a two-dimensional ...
Ferrofluids have promising potential for heat transfer applications, since advective transport in a ferrofluid can be readily controlled by using an external magnetic field. However, unlike conventional free or forced convection, ferrohydrodynamic convection is not yet well characterized. A full understanding of the relationship between an imposed magnetic field, the resulting ferrofluid flow, and the temperature distribution is a prerequisite for the proper design and implementation of applications involving thermomagnetic convection. The literature variously assumes constant magnetic fields, does not completely represent the variation in the imposed field, or its descriptions are inaccurate, since the fields do not comply with the Maxwell's equations of electromagnetism. We address this by simulating two-dimensional forced convection heat transfer in a channel with a ferrofluid that is under the influence of a two-dimensional magnetic field ...
A numerical analysis is made of the unsteady flow and heat transfer characteristics of mixed convection in a vertical block-heated channel with and without installing an inclined plate above an upstream block. Parameter studies including the inclined plate angle, Reynolds number (ranging from 260 to 530), and Grashof number (in the range of 0--3,200,000) on heat transfer performance have been explored in detail. The results show that the installation of an inclined plate in the vertical block-heated channel can effectively augment the blocks` heat transfer performance in the channel. This can be applied to heat exchangers.
This paper presents the experimental results of heat transfer augmentation in an axisymmetric jet impinging normally on a flat plate surface without the requirement of additional pumping power. The present technique of augmentation utilizes only a punched plate with circular holes arranged in a triangular array, fixed parallel to, just in front of the heated target plate. Near the optimum conditions determined, the heat transfer coefficient at the geometrical stagnation point can be increased 4 times. Additional flow visualization study indicates that this augmentation mechanism creates an improved flow field where the punched plate acts as a detached fin, the conductivity of which may be exploited for further augmentation. Besides augmentation, the present investigation foresees the possibility of manipulating the distribution of local heat transfer rate by varying few parameters.
Heat transfer augmentation based on the process intensification concept in heat exchangers and thermal reactors has received much attention in recent years, mainly due to energy efficiency and environmental considerations. The concept consists of the development of novel apparatuses and techniques that, compared to those commonly used today, are expected to bring dramatic improvements in manufacturing and processing, substantially decreasing equipment size, energy consumption, and ultimately resulting in cheaper, sustainable technologies. The objective of this paper was to investigate the heat transfer characteristics of tubular thermal reactor using static mixing technology. Glycerin and water were used as the test fluids and water was used as the heating source. The results for heat transfer rate were strongly influenced by tube geometry and flow conditions.
Summary brochure of GeoPowering the West (GPW) activities, and areas of technology transfer and market transformation. It also provides current contact information for key DOE and national laboratory staff representing the GPW program.
The flow and heat transfers associated with a plane laminar flow past a forward-facing step were analyzed using a power-law numerical scheme combined with a false vorticity-stream function approach. To improve the traditional wall-vorticity boundary condition, a novel method, based on an accurate description of the nonslip wall condition, was developed and utilized. The convergence for a 56 x 49 grid system was obtained in about 350 iterations. The computed reattachment distances in the upper separated region agree with the available experimental data for a blunt plate. The heat transfer augmentation is significant across the step; however, it is counterbalanced by the deterioration of heat transfer immediately upstream of the step.
Mixed convection heat transfer from longitudinal fins inside a horizontal channel has been investigated for a wide range of modified Rayleigh numbers and different fin heights and spacings. An experimental parametric study was made to investigate effects of fin spacing, fin height and magnitude of heat flux on mixed convection heat transfer from rectangular fin arrays heated from below in a horizontal channel. The optimum fin spacing to obtain maximum heat transfer has also been investigated. During the experiments constant heat flux boundary condition was realized and air was used as the working fluid. The velocity of fluid entering channel was kept nearly constant (0.15win0.16m/s) using a flow rate control valve so that Reynolds number was always about Re=1500. Experiments were conducted...
This research investigates experimentally mixed convection and heat transfer augmentation by forced jets in a large enclosure, at conditions simulating those of actual passive containment cooling systems and scales approaching those of actual containment buildings or compartments. The experiment was designed to measure the key parameters governing the heat transfer augmentation by forced jets and investigate the effects of geometric factors, including the jet diameter, jet injection orientation, interior structures, and enclosure aspect ratio. The tests cover a variety of injection modes leading to flow configurations of interest that contribute to reveal the nature of mixing and stratification phenomena in the containment under accident conditions of interest. The heat transfer of mixed convection can be predicted to be controlled by jet Archimedes number and geometric factors. Using a combining rule for mixed convection ...
note that this form for heat transfer augmentation has apparently never been used with other evaporation models, even though it is a natural extension of ...
Congruence is a broadly applied notion in evolutionary biology used to justify multigene phylogeny or phylogenomics, as well as in studies of coevolution, lateral gene transfer, and as evidence for...Full Text Available
The ISI (In-Service Inspection) system has been developed so as to maintain the structural integrity of heat transfer tubes in the primary pressurized water cooler in the HTTR (High Temperature Engineering Test Reactor). This system consists of eddy current probes, ultra-sonic probes, insertion and extraction units, positioning unit and so on. Verification and performance tests of the developed ISI system were carried out using mock-up heat transfer tubes in the primary pressurized water cooler. The constitution of the system, R and D results of the inspection probes, and verification and performance test results of the ISI system for heat transfer tubes are described in this paper. (author)
The ISI (In-Service Inspection) system has been developed so as to maintain the structural integrity of heat transfer tubes in the primary pressurized water cooler in the HTTR (High Temperature Engineering Test Reactor). This system consists of eddy current probes, ultra-sonic probes, insertion and extraction units, positioning unit and so on. Verification and performance tests of the developed ISI system were carried out using mock-up heat transfer tubes in the primary pressurized water cooler. The constitution of the system, R and D results of the inspection probes, and verification and performance test results of the ISI system for heat transfer tubes are described in this paper. (author)
Measurements of absolute differential cross sections for H"+-H_2 direct, single-, and double-charge-transfer scattering at 0.5, 1.5, and 5.0 keV are reported at laboratory scattering angles less than 1 degree with an angular resolution of approximately 0.02 degree. The cross sections exhibit deep interference oscillations in single-charge-transfer scattering, but no such oscillations are present in direct and double-charge-transfer scattering. Theoretical cross sections derived using the diatoms-in-molecules method to describe the molecular states in a semiclassical molecular-orbital three-state close-coupling model within a semiclassical framework agree satisfactorily with the experimental results.
A numerical analysis is performed to clarify the heat transfer characteristics of combined convection around the tubes which form a single row perpendicularly arranged to a forced flow in the direction of gravity. A boundary-fitted coordinate transformation technique is adopted to solve the governing equations numerically. It is found in the case of liquid sodium that gravity-induced flow gives no substantial effect to heat transfer augmentation in a low Reynolds number region while it can be sufficiently expected in the ordinary fluids in the same Reynolds number region. This means that such heat transfer augmentation as expected in ordinary fluids can not be realized when crossflow-type heat exchangers installed for decay-heat removal operates in a low Reynolds number region.
The heat transfer a characteristics and friction factor in the horizontal double pipes of flat tubes with full length helical screw element of different twist ratio and helical screw inserts with different spacer length are investigated. Cold and hot water are used as working fluid in tube side and shell side respectively. The experiments covered a range of Reynolds numbers 5.7x102Re1.31x103. The effect of spacer length on the heat transfer augmentation and friction factor and the effect of twist ratio on heat transfer augmentation and friction factor have been presented separately. The study shows that, the Nusslet number (Nu) and friction factor (f) decrease with the increase of S or Y for flat tube. The comparison between the data of present plain circular with that of previous plain ci...
... position must not be penalized in their NCO Evaluation Report (NCOER). ... failure to perform MOS-, SQI-, or ASI-related duties after counseling. ...
The major goal of this continuation project is to advance the utilization of heat transfer enhancement techniques in commercial heat exchange equipment. Thirteen heat transfer enhancement techniques have been identified as having potential for improving heat transfer coefficients in full-scale industrial equipment. The following tasks are part of this project, which was originally planned for three years: (1) expansion of technology information base; (2) evaluation of performance of enhanced surfaces and inserts; (3) correlation of data for spirally fluted surfaces; (4) study of structured surfaces in pool boiling; and (5) study of structured surface in spray film evaporation.
Angular dependence from L_3-subshell to M-shell vacancy transfer probabilities for selected heavy elements from Au to U have been measured by using a Si(Li) detector coupled to a model 1024 computerized multi-channel analyzer. Because the angular dependence from L_3-subshell to M-shell vacancy transfer probabilities is not found in the literature, to the best of our knowledge there are no experimental values for worked elements. Therefore, the results for the elements obtained in the present study constitute the first experimental measurements; the comparison has been not made with other experimental and theoretical results. It has been observed that angular dependence from L_3-subshell to M-shell vacancy transfer probabilities increase with increasing cos #theta#.
A numerical analysis is performed to clarify the heat transfer characteristics of combined convection around the tubes which form a single row perpendicularly arranged to a forced flow in the direction of gravity. A boundary-fitted coordinate transformation technique is adopted to solve the governing equations numerically. It is found in the case of liquid sodium that gravity-induced flow gives no substantial effect to heat transfer augmentation in a low Reynolds number region while it can be sufficiently expected in the ordinary fluids in the same Reynolds number region. This means that such heat transfer augmentation as expected in ordinary fluids can not be realized when crossflow-type heat exchangers installed for decay-heat removal operates in a low Reynolds number region. (author).
... with dynamic gridding capability to account for material ablation, as well as the addition of energy sources and heat transfer augmentation due to ...
Mar 1, 2011 ... heat transfer augmentation in the stagnation region is presented. The effects of free stream turbulence and surface roughness on spanwise ...
The integrity of a pipeline system is determined by its weakest links which may be the joints. Heat fusion is the most common method for joining gas distribution polyethylene (PE) piping. There are procedural, thermal, and mechanical aspects of making fusion joints. Acceptable procedural aspects, such as heater calibration and cleanliness, can be assured by rigorous training and certification of the operators. Thermal and mechanical aspects consist of specifying joining conditions such as the heater temperature, heating time, and joining pressure. In the absence of procedural errors, the strength of a fusion joint should depend on the pipe material, pipe dimensions, and the thermal and mechanical joining conditions. Socket heat fusion was studied both experimentally and analytically to determine how the strength of the joint varied with the conditions under which it was made. The standard tensile impact test was modified to test socket fusion joint samples in shear. The developed shear ...
The integrity of a pipeline system is determined by its weakest links which may be the joints. Heat fusion is the most common method for joining gas distribution polyethylene (PE) piping. There are procedural, thermal, and mechanical aspects of making fusion joints. Acceptable procedural aspects, such as heater calibration and cleanliness, can be assured by rigorous training and certification of the operators. Thermal and mechanical aspects consist of specifying joining conditions such as the heater temperature, heating time, and joining pressure. In the absence of procedural errors, the strength of a fusion joint should depend on the pipe material, pipe dimensions, and the thermal and mechanical joining conditions. Socket heat fusion was studied both experimentally and analytically to determine how the strength of the joint varied with the conditions under which it was made. The standard tensile impact test was modified to test socket fusion joint samples in shear. The developed shear ...
A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of "2"3"7Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry. "2"3"8U can interfere with "2"3"9Pu measurement by ICP-MS as "2"3"8UH"+ mass overlap and "2"3"7Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and ...
A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and ...
Gadolinium nitrate has been employed in Indian nuclear reactors for the first time as soluble neutron poison in the heavy water moderators of the 540 MWe PHWRs TAPS 3 and 4, as a fast acting secondary shut down system (SDS-2); and also for reactivity shim. For this purpose, the moderator purification system is currently equipped with special ion-exchange columns/schemes, developed by present authors. However, for gadolinium removal from moderator in the post SDS-2 scenario, the two stage ion-exchange - cation bed operation followed by mixed bed operation - results in low pH conditions persisting in the moderator for a few hours, which gives rise to certain operational problems. The present paper describes a mixed bed ion-exchange scheme employing macro-porous strong acid cation and macro-porous weak base anion resins, which has been developed to eliminate acidic conditions and gives a better pH control. The cation to anion capacity ratio in the mixed bed was ...
A series of separation experiment was performed in order to study a multi-functional spent fuel reprocessing process based on ion-exchange technique. The tertiary pyridine-type anion-exchange resin was used in this experiment and the mixed oxide fuel highly irradiated in the experimental fast reactor ''JOYO'' was used as a reference spent fuel. As the result, "1"0"6Ru + "1"2"5Sb, "1"3"7Cs + "1"5"5Eu + "1"4"4Ce, plutonium, americium and curium could be separated from the irradiated fuel by only three steps of ion-exchange. The decontamination factor of "1"3"7Cs and trivalent lanthanides ("1"5"5Eu, "1"4"4Ce) in the final americium product exceeded 3.9 x 10"4 and 1.0 x 10"5, respectively. The decontamination factor for the mutual separation of "2"4"3Cm and "2"4"1Am was larger than 2.2 x 10"3 for the americium product and, moreover, the content of "1"3"7Cs, trivalent lanthanides and "2"4"3Cm included in "2"4"1Am product did not exceed 2 ppm. These results prove that ...
The presence of the nitrogen-fixing shrub, Alnus incana ssp. rugosa, influences the concentration of inorganic nitrogen in surface waters in the Adirondack Mountain region of northern New York. - The purpose of this research was to determine the abundance of the nitrogen-fixing shrub, Alnus incana ssp. rugosa (speckled alder), in shrub wetlands of the Adirondack Mountain region of New York State and to determine whether its abundance affects the concentration or accumulation of inorganic nitrogen in wetland substrates. Alder/willow wetlands are the second most common wetland type in the Adirondack region. The Adirondack Park Agency's digital GIS database of wetland types was used to determine the areal extent of alder/willow wetlands in the Adirondacks. Randomly selected wetlands were sampled to determine the size and abundance of alder. Alder densities averaged {approx}7000 stems ha{sup -1} and alder was present in 75% of the wetlands. As an indication of short-term ...
Photoinduced charge separation reactions form the basis for energy storage processes in both natural and artificial photosynthesis. Moreover, rapid reversible photoinduced electron transfer reactions are a class of photophysical phenomena that can be exploited to develop schemes for optical switching. Examples from each of these fields are discussed.
Food animals are a potential source of CTX-M resistance genes for humans. We evaluated the transfer of the blaCTX-M-9 gene from an animal strain of Salmonella enterica...Full Text Available
The thermal and heat transfer characteristics of lauric acid during the melting and solidification processes were determined experimentally in a vertical double pipe energy storage system. In this study, three important subjects were addressed. The first one is temperature distributions and temporal temperature variations in the radial and axial distances in the phase change material (PCM) during phase change processes. The second one is the thermal characteristics of the lauric acid, which include total melting and total solidification times, the nature of heat transfer in melted and solidified PCM and the effect of Reynolds and Stefan numbers as inlet heat transfer fluid (HTF) conditions on the phase transition parameters. The final one is to calculate the heat transfer coefficient and the heat flow rate and also discuss the role of Reynolds and Stefan numbers on the heat transfer ...
Heat transfer augmentation techniques (passive, active or a combination of passive and active methods) are commonly used in areas such as process industries, heating and cooling in evaporators, thermal power plants, air- conditioning equipment, refrigerators, radiators for space vehicles, automobiles, etc. Passive techniques, where inserts are used in the flow passage to augment the heat transfer rate, are advantageous compared with active techniques, because the insert manufacturing process is simple and these techniques can be easily employed in an existing heat exchanger. In design of compact heat exchangers, passive techniques of heat transfer augmentation can play an important role if a proper passive insert configuration can be selected according to the heat exchanger working condition (both flow and heat transfer conditions). In the past decade, several studies on the passive techniques of heat ...
We used fast absorbance spectroscopy to investigate in vivo binding dynamics and electron transfer between plastocyanin (pc) and photosystem I (PSI), and cytochrome (cyt) f...Full Text Available
In this study, we examined the feasibility of using subzonal cell injection with electrofusion for interspecies somatic cell nuclear transfer (iSCNT) to produce sei whale embryos and to improve their...Full Text Available
The invention concerns a procedure for operating reactors in nuclear power plants. It aims at utilizing power reserves in nuclear power plants. This can be achieved by a steam-side connection of the steam generators of two reactors. The amount of steam exchanged between the units is chosen in such a way that power changes at the steam turbines feedback mainly to the corresponding reactor. In order to realize a high power transfer it is necessary to return the amount of condensate produced in the steam receiving unit and corresponding to the power transferred to the feedwater system of the steam donating unit.
The objectives of this R and D project are as follows : First, transferring developed technologies to outside companies and operating technology market to vitalize technology transactions, Second, developing commercial application projects to transfer technologies for commercial purposes and to solve interface problems in commercial applications, Third, enhancing commercial utilizations of developed accelerator and beam utilization technologies, Finally. preparing infra-structures for the development of over 30 venture- businesses based on achieved technologies through the Proton Engineering Frontier Project.
This paper presents a series of modeling experiences and problems in simulating the thermal-hydraulic behavior of large PWR steam generators using the RELAP4 and RELAP5 computer codes. Sensitivity studies investigating the heat transfer characteristics of both once-through and U-tube steam generators are discussed. Suggestions and recommendations are given for effective use and potential future improvements of these codes.
In this study, a high-resolution characteristic-based finite-volume (FV) method on unstructured grids [Int. J. Numer. Method Eng. 50 (2001) 11; Int. J. Heat Fluid Flow 21 (2000) 432] is extended by a matrix-free implicit dual-time stepping scheme for the numerical simulation of steady and unsteady flow and heat transfer with porous media. The method has been used to study the characteristics of a complex problem: flow and heat transfer in a channel with multiple discrete porous blocks, which was originally proposed by Huang and Vafai [J. Thermophys. Heat Transfer 8 (3) (1994) 563]. In addition, flow and heat transfer in a channel partially or fully filled with porous layers and containing solid protruding blocks with constant heat flux on its lower surface are also investigated in details. Hydrodynamic and heat transfer results are reported for both steady and transient flow cases. ...
To prove that two-layer, TBP-nitric acid mixtures can be safely stored in the canyon evaporators, it must be demonstrated that a runaway reaction between TBP and nitric acid will not occur. Previous bench-scale experiments showed that, at typical evaporator temperatures, this reaction is endothermic and therefore cannot run away, due to the loss of heat from evaporation of water in the organic layer. However, the reaction would be exothermic and could run away if the small amount of water in the organic layer evaporates before the nitric acid in this layer is consumed by the reaction. Provided that there is enough water in the aqueous layer, this would occur if the organic layer is sufficiently thick so that the rate of loss of water by evaporation exceeds the rate of replenishment due to mixing with the aqueous layer. This report presents measurements of mass transfer rates for the mixing of water and butanol in two-layer, TBP-aqueous mixtures, where the top layer ...
The distribution of mass, charge and angular momentum transfer among the products of 54-Fe (255 MeV) ions collisions with the 106 Cd target have been studied. The energy level schemes for 92-Mo, 60-Ni, 96-Ru and 56-Fe are presented. The production yields of different isotopes were also measured. 1 ref., 14 figs.
The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.
In scattering of channeled particles by point defects and in emission of gamma rays in the spontaneous-radiation spectral region conditions are attained where the momentum transferred to the defect is taken up by the crystal as a whole. This leads to coherent and interference effects in the radiation from the crystal defects. When the longitudinal momentum transferred is zero, an induced radiation effect appears in the transitions between the states of transverse motion.
A three-dimensional steady numerical computation was made for a component model of fin and tube type of compact heat exchangers situated in a uniform flow. In this study, in order to find a clue to design high-efficient heat exchangers, numerical computation was made in the case where two fences are attached on the plate fin surface and their geometrical effects such as their locations, their heights and their attack angles on flow and heat transfer characteristics were investigated especially in the low Reynolds number range. The effect of a hole, open in the plate fin behind the fence, on heat transfer and flow structures was also examined. This hole simulates the hole of the plate fin to be produced in practical application, when a fence is produced by punching from the original plain fin plate. Two fences with holes were found to show several important effects on flow and heat transfer structures and to work well in ...
Characteristics of pressure drop and heat transfer have been investigated for a lithium single-phase flow and a helium-lithium two-phase flow in a horizontal conducting circular channel in the presence of a uniform transverse magnetic field up to 1.4 T as related to the lithium cooling for magnetic-confinement fusion reactors. By the application of the magnetic field to the lithium single-phase flow, remarkable heat transfer enhancement has been observed at the top wall due to the suppression of the mixed convection occurring in the low Peclet number range, while appreciable heat transfer deterioration appeared in the high Peclet number range. It has been confirmed that the helium-lithium two-phase flow can reduce the high magnetohydrodynamic (MHD) pressure drop in a lithium single-phase flow, and it can provide much better heat transfer performance than that in a helium single-phase flow. In the ...
Means for increasing heat transfer characteristics between the surface of a solid and a boiling liquid are described in which the solid is immersed is comprised of a solid with passages which extend therethrough to the surface for the circulation of liquid through the passages for emergence from the surface to eliminate at least a portion of the unstable vapor film otherwise formed on the surface.
Experimental studies on the heat transfer and fluid dynamics of a high heat flux fuel rod for a very high temperature reactor (VHTR) were performed using a single channel test rig of a fuel stack test section (T{sub 1-s}) installed in a helium engineering demonstration loop (HENDEL). The fuel rod has been developed in order to enhance the turbulent heat transfer coefficient than that of the standard fuel rod obtained by the previous experiment. Two-dimensional square ribs were settled on the outer surface of the fuel rod axially to improve the heat transfer. The configuration of a square rib is 0.5 mm in width(w), 0.5 mm in height(h) and 5 mm in pitch(p): p/h=10. The experiment were carried out under the helium gas conditions of high temperature and pressure simulated the VHTR operation. For the turbulent region of Reynolds number 2,500{approx}8,000 of the VHTR core flow condition, it was found that the heat ...
BackgroundThe frequency of transfer of genes encoding resistance to antimicrobial agents was determined by conjugation in ESBL-producing and/or fluoroquinolone or aminoglycoside...Full Text Available
An experiment of heat transfer to CO{sub 2}, which flows upward and downward in a circular tube with an inner diameter of 6.32 mm, was carried out with mass flux of 285-1200 kg/m{sup 2} s and heat flux of 30-170 kW/m{sup 2} at pressures of 7.75 and 8.12 MPa, respectively. The corresponding Reynolds number at the tube test section inlet ranges from 1.8 x 10{sup 4} to 3.8 x 10{sup 5}. The tube inner diameter corresponds to the equivalent hydraulic diameter of the fuel assembly sub-channel, which is being studied at KAERI. Among the tested correlations, the Bishop correlation predicted the experimental data most accurately, but only 66.9% of normal heat transfer data were predicted within {+-}30% error range. The Watts and Chou correlation, which is claimed to be valid for both the normal and deteriorated heat transfer regime, showed unsatisfactory performance. A significant decrease in Nusselt number was observed in the range ...
The enhancement of longitudinal heat transfer by means of fluid pulsation in a pipe has been investigated analytically and numerically, including the transient state. The effects of pulsation amplitude, frequency, and pipe length on thermal properties such as effective thermal diffusivity and delay time are clarified. Their effects on numerical calculations are also presented and suggestions for efficient numerical calculations of this problem are made concerning the combination of parameters.
In this thesis the results are described of an investigation into the radiationless transfer of electronic excitation energies in various Eu"3"+ and Tb"3"+ compounds, which show structural peculiarities in the rare-earth sublattice. These peculiarities are an one-dimensional sublattice as well as two different crystallographic locations for the rare-earth ion. 154 refs.; 43 figs.; 12 tabs.
DescriptionFollowing publication of the Curry report, DEFRA have made a commitment to establish a number of pilot projects supporting a network of demonstration and development farms. These 'farms' are intended to support the process of technology transfer by giving free access to information on the practical application of new, emerging and best practice technologies. Protected Horticulture has been identified as a sub-sector requiring the establishment of one of these projects. One of the major pressures [continued...
Contacts with researchers, manufacturers, and users of enhanced heat transfer equipment are summarized. The Technical Literature file and the Patent File continue to be updated; the Patent File is the source for a patent technology report now in draft form. Application studies on a rationally-based friction correlation for internally-finned tubes and on the evaluation of candidate tube-side enhancements for OTEC applications are reported. The technology study on enhancement of spray evaporation is also discussed.
Based on results from recent studies of elemental dietary intake and organ or tissue content for adult Chinese men, quoted nationwide elemental concentrations in Chinese soil and newly published national average consumption of dietary foods, values of both transfer coefficients and discrimination factor (DF) for transfer from soil via the diet to both critical organs and the whole body have been calculated for important elements in radiation protection, including alkaline earths, alkali metals, rare earths and other related elements. These calculations have used both the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) model and the DF method. In the UNSCEAR model, the basic parameters used to describe the transport of radionuclides are the transfer coefficients P_i_j, which describe the relationship of concentrations or other amounts between compartment i and the following compartment j, ...
Response of control valves plays an important role in the dynamics of the flow system as a whole. Knowledge of its transfer function would facilitate analysis of the behaviour of the system. This paper presents the application of Levy's complex curve fitting method for determination of the transfer function of control valves used in Liquid Zone Control System of 540 MWe PHWR. (author)
Using ab initio (SCF/6-31G) method, mechanisms of proton migrations in methaboric acid dimers have studied. It is shown that in all the dimers considered a cooperative transfer of protons occurs. The calculated values of activation barriers of cooperative proton transfer reactions in the dimers are equal to 28.6 kcal/mol.
After a presentation of methods and tools for the basic and extensive characterization of polluted sites and the study of evolution and transfer of current organic pollutants in the ground, the example of the rehabilitation of an old Rhone-Poulenc site (at Chauny, France) polluted with metals and arsenic, is described: soil and aquifer diagnosis, risk analysis and determination of migration schemes
The paper presents a compilation of data and model interpretation of CO{sub 2} with mixtures of amines. The data includes both absorption and desorption conditions in the 288-313K range. The combined mass transfer/equilibrium model can effectively represent CO{sub 2} mass transfer rates for the various mixtures under a wide range of conditions.
During the last two decades, the demand for higher heat transfers in the heat exchangers has kept increasing. These high heat transfer rates can be obtained by using two-phase flows, or heat transfer augmented surfaces, or in some cases, both. Thus, the boiling flows and the associated two-phase flow instabilities have been studied by many investigators. Most of the work in boiling flows has been concentrated on single channel upflow systems or on parallel channel systems with plain heat transfer surfaces. The boiling flow instabilities in multi-channel systems should be covered to a greater extent, studying the effects of various parameters, such as inlet and outlet restriction, mass flow rates, the property variations, heat transfer coefficients, equal and unequal heat inputs on the stability. Also, the mathematical modeling needs to be developed for the parallel channel system to ...
What utilizes the effect of electrohydrodynamical technique (EHD), as one of heat transfer augmentation methods, is methodically frequented and partially prepared to be put to practical use. Then, the heat transfer augmentation effect on nucleate boiling, utilizing the EHD effect, was both experimentally and theoretically studied from both the applicative and basic viewpoints. By adding fleon with 2wt% ethyl alcohol, higher in electric conductivity, in order to have the mitigation time of electric charge correspond to the bubbling frequency of bubble, the heat transfer augmentation was enabled to be about 8.5 times as high as that without impressing the electric field. As a result of observing the behavior of bubble in the electric field, was observed a phenomenon of bubble, moving from place to place, without ascending, on the plane electrode plate, by which could be found one of causes of the heat ...
When a bipolar HVDC transmission system is operating monopolar using the earth as a return path, it is often desired to divert the return current from the earth to the line from the unused pole. To do so requires either that the system be shut down temporarily or that a dc circuit breaker be used. This paper describes the development of such a new dc circuit breaker, and its application on the Pacific Intertie as a Metallic Return Transfer Breaker (MRTB).
A pair of bundles is placed in a shuttle tube, which is enclosed by a carriage tube kept inside the Shuttle Transfer Station (STS). It takes about 90 minutes for the spent fuel bundles to travel from the reactor channel to Transfer Magazine (TM). Subsequently, the dry transfer operation takes about 4 minutes. An emergency air cooling flow rate of 600 m3/hr is supplied to cool the spent fuel bundles after they reach the STS, following lapse of 4 minutes of spent fuel dry transfer, in case the bundles are not submerged in the light water in STS. A thermal and hydraulic safety analysis has been done to estimate the maximum sheath temperature, if the spent fuel bundles are stuck at a location of 30 mm below the normal location aligned to the TM port. This position of the spent fuel will have least cooling from the emergency cooling airflow. At the same time, the shuttle tube carrying the spent fuel bundle ...
The augmentation of the heat transfer by inserting different type turbulators into the channels is the conventional passive enhancement method. The coiled wire is one of the common heat transfer enhancement devices. These turbulators generate almost-periodic vortices into the flow while increasing the heat transfer rate. In this study, the properties of these vortices (i.e. the vortex shedding frequency and amplitudes of the pressure fluctuations of the vortices), flow (vortex)-acoustic coupling and the relation between entropy generation and vortex characteristics were investigated experimentally. Strouhal-Re-N_s_,_a and P_r_m_s-Re-N_s_,_a variations were presented graphically. It was observed that as the pitch increases, the vortex shedding frequencies decrease and the maximum amplitudes of pressure fluctuation of vortices produced by coiled wire turbulators occur with small pitches. In addition, the effects of the ...
Pacific Northwest National Laboratory and a group of expert collaborators are using the U.S. Department of Energy Hanford Site 300 Area uranium plume within the footprint of the 300-FF-5 groundwater operable unit as a site for an Integrated Field-Scale Subsurface Research Challenge (IFRC). The IFRC is entitled Multi-Scale Mass Transfer Processes Controlling Natural Attenuation and Engineered Remediation: An IFRC Focused on the Hanford Site 300 Area Uranium Plume Project. The theme is investigation of multi-scale mass transfer processes. A series of forefront science questions on mass transfer are posed for research that relate to the effect of spatial heterogeneities; the importance of scale; coupled interactions between biogeochemical, hydrologic, and mass transfer processes; and measurements/approaches needed to characterize and model a mass transfer-dominated system. This Quality ...
The transfer kinetics of the negatively charged glycosphingolipid II"3-N-acetylneuraminosyl-gangliotetraosylceramide (GM_1) were investigated by monitoring tritiated GM_1 movement between donor and acceptor vesicles. After appropriate incubation times at 45 "0C, donor and acceptor vesicles were separated by molecular sieve chromatography. Donors were small unilamellar vesicles produced by sonication, whereas acceptors were large unilamellar vesicles produced by either fusion or ethanol injection. Initial GM_1 transfer to acceptors followed first-order kinetics with a half-time of about 40 h assuming that GM_1 is present in equal mole fractions in the exterior and interior surfaces of the donor vesicle bilayer and that no glycolipid flip-flop occurs. GM_1 net transfer was calculated relative to that of ["1"4C]cholesteryl oleate, which served as a nontransferable marker in the donor vesicles. Factors affecting the GM_1 ...
A comparative assessment of five different heat transfer configurations for operation in compact heat exchangers is presented. The configurations under consideration are four standaed heat exchanger surfaces - two plain fin, an offset strip and a louvered fin geometry - and one surface with so called vortex generators for heat transfer augmentation. In the case of the standard surfaces, the basic performance characteristics in the form of heat transfer and friction data versus the Reynolds number have been taken from published experimental results. In the case of the vortex generator surface, the performance characteristics have been derived from a numerical prediction of the flow and temperature field in a closely spaced parallel plate channel with vortex generators in the form of delta wings mounted on the channel walls. In comparison to the plain fin surfaces with a rectangular cross section, the vortex generator surface ...
Using a facility named SPHINX, which can accommodate a heat transfer test with CO{sub 2} at supercritical pressure, a series of tests was performed. The test geometries include tubes with the inner diameter of 4.4, 6.32 and 9 mm. a concentric annular passages with 8 x 10 mm, and an eccentric annular passages with 9.5 x 12.5 mm. Based on the test results, heat transfer correlations were developed and compared with the existing correlations. The heat transfer deterioration which may occur at certain conditions of heat and mass flux, were carefully studied and the published criteria were reviewed against our test results. Numerical calculation by using commercial CFD code, Fluent, were performed in order to provide the pre-test information for the heat transfer tests. Various turbulence models were evaluated and reliable models were suggested for each case
The paper investigates the effect of the wall heat flux ratio on the local heat transfer augmentation in a square channel with two opposite in-line ribbed walls for Reynolds numbers from 15,000 to 80,000. The square channel composed of 10 isolated copper sections has a length-to-hydraulic diameter ratio of 20. The rib height-to-hydraulic diameter ratio is 0.0625 and the rib pitch-to-height ratio equals 10. Six ribbed side to smooth side wall heat flux ratios are studied for four rib orientations. The results show that the ribbed side wall heat transfer augmentation increases with increasing ribbed side to smooth side wall heat flux ratios, but the reverse is true for the smooth side wall heat transfer augmentation. The average heat transfer augmentation of the ribbed side and smooth side wall decreases slightly with increasing wall heat flux ratios. The effect of wall heat flux ratio reduces with ...
The unsteady flow and heat transfer are simulated using LES and DNS for a channel with two angled ribs as a vee-shaped vortex generator to augment heat transfer. The vortex generators are attached on the bottom wall of the channel and their angles in respect to the main flow are between 10"o and 30"o. The Prandtl number is 0.71 and the Reynolds numbers based on the inflow velocity and the height of channel are from 200 to 2000. Based on the results of this work, the variations of the Nusselt number, pressure coefficient, bulk temperature, friction factor and Colburn factor with the Reynolds numbers and the incidence angles are provided. The relation between the key parameters of the velocity (friction factor f) and thermal (Colburn factor J) boundary layers is calculated for all cases and their values are compared with the predicted values by the Chilton-Colburn analogy. A comparison between the DNS and LES results is performed and it is found ...
Heat transfer enhancement in a heat exchanger tube by installing a baffle is reported. The effect of baffle size and orientation on the heat transfer enhancement was studied in detail. Three different baffle arrangements were considered. The results show that for the vertical baffle, an increase in the baffle height causes a substantial increase in the Nusselt number but the pressure loss is also very significant. For the inclined baffles, the results show that the Nusselt number enhancement is almost independent of the baffle inclination angle, with the maximum and average Nusselt number 120% and 70% higher than that for the case of no baffle, respectively. For a given baffle geometry, the Nusselt number enhancement is increased by more than a factor of two as the Reynolds number decreased from 20,000 to 5000. Simulations were conducted by introducing another baffle to enhance heat transfer. The results show that the ...
The purpose of the study is to investigate the heat transfer augmentation method for a wavy channel type heat exchanger. Experimental studies were carried out, by installation of flow guide-plates with simple structure, to clarify the effects on the augmentation whether the effects are brought by the flow acceleration or by the increase of intensity of turbulence due to the flow seperation, and to determine optimum shape of flow guide-plates. The shape and dimensions of the experimental apparatus are as follows; channel width H of 30 mm, rectangular section with breadth of 300 mm, wavy duct with a bend angle of 60/sup 0/ and straight pipe of 2H length. Air stream was flowed through the duct with Reynolds number of 1.7 x 10/sup 4/ only. As the results, following conclusions were obtained. (1) Wavy duct with large bend angle and without inserting flow guide-plates could not be expected large effects on the heat transfer augmentation. (2) An ...
In the utilization of the thermal energy by ocean temperature difference and factory waste heat, the high performance heating surfaces in pipes from which scale can be removed are required. As the method of removing scale, the method using sponge balls seems most suitable, but for applying this method, as the form of the protrusions attached to the inner surfaces of pipes, smooth circular are form is desirable. The promotion of heat transfer with the rows of circular arc protrusions like this is strongly related to the mode of flow and such structure as separation, recirculation flow, readhesion and turbulent energy generation. In this study, as the basic research to optimize the heating surface with the rows of smooth protrusions, the flow characteristics and the heat transfer characteristics including the turbulent structure of the wake of protrusions were experimentally determined, and the essence of the heat transfer ...
A numerical study of laminar flow and heat transfer in an array of stacked rectangular plates is presented. The array is placed in a uniform stream, and the plates are subjected to a constant surface heat flux. This flow configuration is relevant to a number of practical heat transfer devices with finned surfaces. The computations were performed using a finite volume solution of the steady, two-dimensional Navier-Stokes equations and energy equation. A numerical scheme that reduces numerical diffusion is used to discretize the equations. The dominant feature of the flow is the separation, and subsequent reattachment of, the boundary layer, which takes place at Reynolds numbers greater than about 75. The separation first occurs downstream of the leading edge of the plate; then as Re increases, the separation point moves upstream and remains fixed at the leading edge, and the reattachment length increases linearly with Re. The appearance and ...
A unique method, previously proposed by the author, was applied to the heat transfer augmentation in the flow boiling field. In this method a screen sheet was put on the horizontal heated surface where bubble nucleation occurred. Generated vapor bubbles were trapped between the screen and the wall, became flat and moved along the surface. This restricted bubble behavior caused the heat transfer enhancement. Three types of the screen were tested in the present experiment and the effect of the screen was investigated on the heat transfer and two-phase flow characteristics. In two cases of them, the screen was displaced upward by the bubble nucleation. Compared with the ordinary flow boiling case, heat transfer was enhanced by a factor of 1.2 to 6 within the present experimental range. By using a simple flow model, it was made clear that the effect of the height of the displaced screen was important to ...
An experimental study of forced convection heat transfer at the inner tube wall of a double pipe heat exchanger with coiled wire inserts as heat transfer augmentation devices was performed over a turbulent flow region. The test results from twelve augmented tubes with inserts of different combinations of wire diameters (0.813, 1.016 and 1.575 mm) and pitches (2.82, 3.63, 5.08 and 8.47 mm) indicate that the turbulence promoters studied improve heat transfer by a factor of 1.4 to 2.24 compared with a smooth tube, although at a cost of 10-30 times increase in friction factor. A formula for presenting dimensionless exergy losses in a tubular heat exchanger is derived first and then the thermohydrodynamic optimum instead of economic optimum is found by minimizing the exergy losses in the system. From the heat transfer improvement number defined, it is observed that coiled wire turbulence promoters are more ...
Experimental investigation of heat transfer and friction factor characteristics of circular tube fitted with full-length helical screw element of different twist ratio, and helical screw inserts with spacer length 100, 200, 300 and 400mm have been studied with uniform heat flux under laminar flow condition. The experimental data obtained are verified with those obtained from plain tube published data. The effect of spacer length on heat transfer augmentation and friction factor, and the effect of twist ratio on heat transfer augmentation and friction factor have been presented separately. The decrease in Nusselt number for the helical twist with spacer length is within 10% for each subsequent 100mm increase in spacer length. The decrease in friction factor is nearly two times lower than the full length helical twist at low Reynolds number, and four times lower than the full length helical twist at high Reynolds number for ...
To determine MTRs for normal structures and benign diseases in the breast two-dimensional magnetization transfer imaging was performed in 62 patients and in 3 young female volunteers. With regard to the MTRs of measurements in the normal breast tissues, fat tissues which is close to simple cysts in MTRs show little transfer of longitudinal magnetization. MTRs of the muscles was 15.15{+-}6.22%, which exceeded those of breast parenchyma. The breast parenchyma didn`t show the change of MTR value due to the difference of patient age and due to variable amount of fat and fibrous tissues. Breast parenchyma in the two young volunteers clearly showed biphasic change of MTR values in accordance with the menstrual cycle; little transfer value was due to hydration in the postovulatory period and high transfer value was due to dehydration in the preovulatory period. In the remaining one volunteer during lactation ...
In the development of high performance heat transfer surface on a compact heat exchanger, it was clarified that how reattachment point heat transfer and fluid flow are affected by channel width, at the same time, an evaluation of heat transfer performance and an investigation of optimum channel width were carried out. The channel system used in the experiment is as follows; (1) blow-off type with rectangular section channel, (2) span length of 200 mm, (3) wave length (pitch) of 80 mm, and (4) channel length of 12.5 wave length. The channel Reynolds number was set at about 10/sup 4/ which is relatively higher than the current studies. The results of the experiment were summarized as follows. (1) The channel width H has relevance to the phase difference between the fluid flow in cone portion of main stream and wave shape, the flow patterns are divided roughly into three types. These boundaries exist at P/H 3.0 and 1.5 (P: ...
The heat transfer a characteristics and friction factor in the horizontal double pipes of flat tubes with full length helical screw element of different twist ratio and helical screw inserts with different spacer length are investigated. Cold and hot water are used as working fluid in tube side and shell side respectively. The experiments covered a range of Reynolds numbers 5.7 x 10{sup 2} {<=} Re {<=} 1.31 x 10{sup 3}. The effect of spacer length on the heat transfer augmentation and friction factor and the effect of twist ratio on heat transfer augmentation and friction factor have been presented separately. The study shows that, the Nusslet number (Nu) and friction factor (f) decrease with the increase of S or Y for flat tube. The comparison between the data of present plain circular with that of previous plain circular tube showed a good agreement between them but the data of present plain flat tube showed ...
The present paper is concerned with development and application of a so-called Effective Convection Model (ECM), which aims to provide a detailed, mechanistic description of heat transfer processes in a BWR lower plenum. The ECM is a Computational Fluid Dynamics (CFD)-like tool which employs a simpler and more effective approach to compute heat transfer by solving only energy conservation equation instead of solving the full set of Navier-Stokes and energy equations by a CFD code. We implement the ECM in a CFD code (Fluent), with detailed description of the ECM development, implementation and validation. A dual approach is used to validate the ECM, namely validation against experimental data and against heat transfer results obtained by CFD predictions in the same geometries and conditions. Insights gained from CFD simulations are also used to improve ECM. The ECM capability as an effective tool to simulate heat ...
The present paper is concerned with development and application of a so-called Effective Convection Model (ECM), which aims to provide a detailed, mechanistic description of heat transfer processes in a BWR lower plenum. The ECM is a Computational Fluid Dynamics (CFD)-like tool which employs a simpler and more effective approach to compute heat transfer by solving only energy conservation equation instead of solving the full set of Navier-Stokes and energy equations by a CFD code. We implement the ECM in a CFD code (Fluent), with detailed description of the ECM development, implementation and validation. A dual approach is used to validate the ECM, namely validation against experimental data and against heat transfer results obtained by CFD predictions in the same geometries and conditions. Insights gained from CFD simulations are also used to improve ECM. The ECM capability as an effective tool to simulate heat ...
Research highlights: {yields} The use of resonant photoemission in its 'core-hole clock' expression for the study of the dynamical charge transfer across hybrid organic-inorganic interfaces and for the intermolecular charge transfer in the bulk of organic thin films is reviewed. {yields} The electronic coupling to the substrate and the efficiency of charge transport across hybrid interfaces is different for individual electronic subsystems of the molecular adsorbate. {yields} The intermolecular charge transfer in the bulk of discotic liquid crystals occurs on the order of a few femtoseconds and is faster than expected from the macroscopic charge transport characteristics of the material. -- Abstract: The focus of this brief review is the use of resonant photoemission in its 'core-hole clock' expression for the study of two important problems relevant for the field of organic electronics: ...
The Supercritical Water Cooled Reactor(SCWR) operates in a pressure around 25MPa and temperature of 293#approx#510 .deg. C. In order to study the heat transfer behaviors and good comparisons between the various fluids, a heat transfer test loop(SPHINX) using CO_2 has been constructed in KAERI as a part of international research program, I-NERI. At a supercritical pressure, the heat transfer coefficient is much larger than that estimated from the Dittus-Boelter correlation for a relatively large flow rate with moderate wall heat flux conditions. This phenomenon was explained by the rapid variations of the physical properties near the wall with the temperature. On the contrary, the heat transfer becomes worse when the bulk fluid enthalpy is below the pseudo-critical enthalpy under a low flow rate with large heat flux conditions. This phenomenon is called 'deteriorated heat transfer', ...
The transfer kinetics of the neutral glycosphingolipid gangliotetraosylceramide (asialo-GM1) were investigated by monitoring tritiated asialo-GM1 movement from donor to acceptor vesicles. Two different methods were employed to separate donor and acceptor vesicles at desired time intervals. In one method, a negative charge was imparted to dipalmitoylphosphatidylcholine donor vesicles by including 10 mol% dipalmitoylphosphatidic acid. Donors were separated from neutral dipalmitoylphosphatidylcholine acceptor vesicles by ion-exchange chromatography. In the other method, small, unilamellar donor vesicles and large, unilamellar acceptor vesicles were coincubated at 45 degrees C and then separated at desired time intervals by molecular sieve chromatography. The majority of asialo-GM1 transfer to acceptor vesicles occurred as a slow first-order process with a half-time of about 24 days assuming that the relative concentration of asialo-GM1 in the ...
Experimental studies on the heat transfer and fluid dynamics of a high heat flux fuel rod for a very high temperature reactor (VHTR) were performed using a single channel test rig of a fuel stack test section (T_1_-_s) installed in a helium engineering demonstration loop (HENDEL). The fuel rod has been developed in order to enhance the turbulent heat transfer coefficient than that of the standard fuel rod obtained by the previous experiment. Two-dimensional square ribs were settled on the outer surface of the fuel rod axially to improve the heat transfer. The configuration of a square rib is 0.5 mm in width(w), 0.5 mm in height(h) and 5 mm in pitch(p): p/h=10. The experiment were carried out under the helium gas conditions of high temperature and pressure simulated the VHTR operation. For the turbulent region of Reynolds number 2,500#approx#8,000 of the VHTR core flow condition, it was found that the heat ...
A radioactive Waste Incineration System (WIS) with suspension combustion is noticed as effective volume reduction technology of low level radiactive wastes that are increasing every year. In order to demonstrate the decontamination efficiency of ceramic filter used on WIS, this test has been carried out with the test facilities as joint research of Central Research Institute of Electric Power Industry (CRIEPI) and Sumitomo Heavy Industries, Ltd. Miscellaneous combustible waste and power resin, to which 5 nuclides (Mn-54, Fe-59, Co-60, Zn-65, Cs-137) were added, were used as samples for incineration. As the result of the test, it was verified that Decontamination Factor (DF) of the single stage ceramic filter was usually kept over 10/sup 5/ for every nuclide, and from the results of above DF, over 10/sup 8/ is expected for real commercial plant as a total system. Therefore, it is realized that the off-gas clean up system of the WIS composed of only single stage of ...
A radioactive Waste Incineration System (WIS) with suspension combustion is noticed as effective volume reduction technology of low level radiactive wastes that are increasing every year. In order to demonstrate the decontamination efficiency of ceramic filter used on WIS, this test has been carried out with the test facilities as joint research of Central Research Institute of Electric Power Industry (CRIEPI) and Sumitomo Heavy Industries, Ltd. Miscellaneous combustible waste and power resin, to which 5 nuclides (Mn-54, Fe-59, Co-60, Zn-65, Cs-137) were added, were used as samples for incineration. As the result of the test, it was verified that Decontamination Factor (DF) of the single stage ceramic filter was usually kept over 10"5 for every nuclide, and from the results of above DF, over 10"8 is expected for real commercial plant as a total system. Therefore, it is realized that the off-gas clean up system of the WIS composed of only single stage of ceramic ...
Three simulated low-level reactor wastes were dried using a spray dryer-baghouse system. The three aqueous feedstocks were sodium sulfate waste characteristic of a BWR, boric acid waste characteristic of a PWR, and a waste mixture of ion exchange resins and filter aid. These slurries were spiked with nonradioactive iron, cobalt, and manganese (representing corrosion products) and nonradioactive cesium and iodine (representing fission products). The throughput for the 2.1-m-diameter spray dryer and baghouse system was 160-180 kg/h, which is comparable to the requirements for a full-scale commercial installation. A free-flowing, dry product was produced in all of the tests. The volume reduction factor ranged from 2.5 to 5.8; the baghouse decontamination factor was typically in the range of 10"3 to 10"4. Using an overall system decontamination factor of 10"6, the activity of the off-gas was calculated to be one to two orders of magnitude less than the nuclide release ...
The potential retinal hazard of dental visible-light photopolymerization units and the efficacy of protective lenses for reducing the potential hazards were assessed. The spectral radiance profiles of 11 visible-light photopolymerization units were measured; and the results were then weighted according to the American Conference of Governmental Industrial Hygienists (ACGIH) Blue Light and Thermal Hazard Functions. The results indicate that there are no thermal hazards to the retina even for the worst case condition. None of the blue-light hazard maximum permissible exposure times is short enough to be of concern unless the individual operator chooses to focus on the light source for an extended period. Those individuals who elect to stare at the light during curing procedures should consider the purchase of protective lenses. The special transmission profiles of 16 protective lenses were measured and new permissible exposure limits calculated for each lens/unit combination. All lenses ...
Low-permeability reservoirs are currently being propped with sand, resin-coated sand, intermediate-density proppants, and bauxite. This wide range of proppant cost and performance has resulted in the proliferation of proppant selection models. Initially, a rather vague relationship between well depth and proppant strength dictated the choice of proppant. More recently, computerized models of varying complexity that use net-present-value (NPV) calculations have become available. The input is based on the operator's performance goals for each well and specific reservoir properties. Simpler, noncomputerized approaches include cost/performance comparisons and nomographs. Each type of model, including several of the computerized models, is examined here. By use of these models and NPV calculations, optimum fracturing treatment designs have been developed for such low-permeability reservoirs as the Prue in Oklahoma. Typical well conditions are used in each of ...
Recently, in various production engineering of inorganic chemistry system, a large quantity of acids such as nitric acid and hydrocholoric acid have been used, the examples that acid and slats with high concentration are included in the sewer, treatment technique of acid-effluent in the sewer has been known as the diffusion-dialysis, acid-retardation using anion exchange resin. In this report, treatment and properties of acid-effluent recovery and effect of a coexisting slat by the diffusion-dialysis and acid retardation were compared. In the acid retardation, the concentration beyond the solution system can be recovered when the flow interval between waste acid and water was selected appropriately. In the diffusion-dialysis, it has a tendency that rate of recovery was low in the week acid. However, even in the case of which metal irons form complex anion, it is possible that acid and slat were separated well. 7 refs., 11 figs., 2 tabs.
Molten salt oxidation (MSO) is a good alternative to incineration for the treatment of a variety of organic wastes such as explosives, low-level mixed waste streams, PCB contaminated oils, spent resins and carbon. Since mid-1990s, the U.S. Army Defense Ammunition Center (DAC) and the Department of Energy (DOE) have jointly invested in MSO development at the Lawrence Livermore National Laboratory (LLNL). LLNL first demonstrated the MSO process for the effective destruction of explosives, explosives-contaminated materials, and other wastes on a 1.5-kg/hr bench-scale unit, and then in an integrated MSO facility capable of treating 8 kg/hr of low-level radioactive mixed wastes. Several MSO systems have been built with sizes up to 10 ft in height and 16 inches in diameter. LLNL in 2001 completed a MSO plant for DAC for the destruction of explosives-contaminated sludge and explosives-contaminated carbon. We will present in this paper our latest demonstration data and our ...
The use of the ratio of the characteristic intensity to the continuum background intensity (P/B ratio) of the X-ray spectrum for a quantitative ion microprobe (IMP) or PIXE (particle induced X-ray emission) analysis of thin biological specimens was proposed previously. The IMP analysis of thick biological specimens is also of considerable practical use. In this paper, the possibility of using the P/B ratio to quantify minor elements in thick biological specimens is investigated. The epoxy resin based standards with gradual concentrations of KCNS up to 0.6 mol/kg and NBS bovine liver were analyzed by a 27 MeV {alpha} particle microprobe. The measured peak to background ratios (between 4.4 to 5.7 keV) agreed well with the theoretical calculations. The calculations showed that the concentration dependence of the P/B ratios was determined mainly by the absorption of X-rays in specimens. The results indicate that the P/B method is useful for IMP analysis of thick ...
Magnesium alloys have replaced resins as a material for the components of electronic products such as cell phone and notebook personal computer mainly, because of their lightness and rigidity. Thin walls, a complicated shape, and high appearance quality are all needed in the external parts. Die-casting and injection molding are the main method of manufacturing magnesium alloy parts. The optimal cast conditions and mold design have been investigated in order that a few defects such as surface cracks and mold cavities in casting parts would be reduced. Instead of cast, plastic forming technologies such as warm drawing and hot forging have been developed to form thinner walls and less defects. Plastic formability of magnesium alloy in hot working is dependent on a grain size of material. The material with fine grains has advantage of being formed at high strain rate. The characteristics of forming processes of magnesium parts for Japanese home electric appliances are ...
This paper introduces recent instances of polymerizers for highly viscous liquid needed in the field of synthetic resin and synthetic fiber. A horizontal twin-shaft type polymerizer has two horizontally rotating shafts with stirring blades of spectacle-shaped type, which are arranged at a 90 [degree] phase difference. As they rotate, they scrape highly viscous liquid sticking to the surface inside the polymerizer and on the rotating shafts. This polymerizer is capable of processing highly viscous liquid up to about 2000 Pa[center dot]s. A lattice-type twisting blade polymerizer is a vertical-type reactor and features a special stirring blade capable of stirring highly viscous liquid up to 5000 Pa[center dot]s This polymerizer has no central rotating shaft so that highly viscous liquid does not stick on it. A sloped blade-type thin-film evaporator has spiral blades in the longitudinal direction of the rotor. Process liquid pushed to the inner wall of the vessel by ...
The objectives of this project are to develop feasible synthetic routes to produce (1) 4(4{prime}-hydroxy-5{prime},6{prime},7{prime},8{prime}-tetrahydro-1{prime}-naphthylmethyl)-6-methyldibenzothiophene, and (2) a 1-hydroxynaphthalene-dibenzothiophene polymer. These compounds are thought to be representative of sulfur containing molecules in coal. The program is divided into three tasks, the first of which is a project work plan that has already been submitted. There are several possible synthetic routes to the target molecule (1). The authors are now investigating two general synthetic approaches: coupling of a dialkylated dibenzothiophene fragment with the phenol, and coupling of a monoalkylated dibenzothiophene fragment with a monoalkylated phenol fragment. This quarter they developed syntheses for the reaction fragments and conducted some preliminary coupling experiments. They found that polymerization of the fragments is a problem; however, using an acidic ...
A series of experiments were carried out to examine the resistant capacity of a chemically treated hard wood, Anthocephalus cadamba (Roxb) Miq. to thermal and termite degradation. The treatment with thermosetting resins viz. urea formaldehyde (UF), melamine formaldehyde (MF) and phenol formaldehyde (PF) at 31-33 levels of weight percent gain (WPG) increased the strength property i.e. modulus of rupture (MOR) by 7.50-21.02% and stiffness i.e. modulus of elasticity (MOE) by 9.50-12.18% over the untreated one with no remarkable effect on specific gravity. The treated samples were found resistant to termite attack, while the untreated one was badly damaged by termites on 12 months' exposure to a termite colony. The thermal degradations of untreated and treated wood samples were studied using thermogravimetric (TGA) and differential thermogravimetric (DTG) techniques at heating rates 20 and 30 {sup o}Cmin{sup -1} in temperature range 30-650{sup o}C. The treated ...
Spherical nanostructured Si/C composite was prepared by spray drying technique, followed by heat treatment, in which nanosized silicon and fine graphite particles were homogeneously embedded in carbon matrix pyrolyzed by phenol formaldehyde resin. Cyclic voltammetry tests showed two pairs of redox peaks corresponding to lithiation and delithiation of Si/C composite. The Si/C composite exhibited a reversible capacity of 635 mAh g"-"1 and good cycle performance used in lithium ion batteries. To improve cycle performance of this Si/C composite further, the carbon-coated Si/C composite was synthesized by the second spray drying and heat treatment processing. The cycle performance of carbon-coated Si/C composite was improved significantly, which was attributed to the formation of stable SEI passivation layers on the outer surface of carbon shell which protected the bared silicon from exposing to electrolyte directly.
The performance of larger than bench scale ion exchange systems is evaluated by using solutions containing trace amounts of "1"3"7Cs, "8"5Kr, and "1"3"1I, and large amounts of either NaCl or Na_2HPO_4, H_3BO_3, and LiOH. The significant finding in this study is that the empirical rules of ionic selectivity of strong acid cation and strong base anion resins were followed by all ionic species, even though concentrations of some macrocomponents were nearly 10"6 times those of trace components. Other results of possible importance are the correlation between the instantaneous decontamination factor (DF) and the efficiency of column exchange capacity utilization, and the concept of time average decontamination factor (anti DF). The plot of anti DF vs. feed throughput will serve as a guide in determining when the feed should be discontinued in order to achieve a desired anti DF. Both of these correlations are derived from the breakthrough curves.
Urea-formaldehyde resin bonded particle board, medium density fiberboard and plywood paneling are used as flooring, wall paneling, for cabinet work and in furniture, and are present in almost every office, home and public building. If large quantities of these products are used in poorly ventilated spaces, high manufacturing quality control is necessary to avoid problems of latent formaldehyde release. Indoor air formaldehyde concentrations depend on the nature of the product, the product surface to air volume (loading) factor, temperature, humidity, age and product emission rates. Standard test methods are now available for measuring product emission rates that make it possible to predict the performance of UF-bonded pressed wood materials if use conditions and environmental parameters are known. Recent modifications in adhesive and board manufacturing parameters have made it possible to reduce formaldehyde emission significantly, and UF-bonded wood products are ...
The optical properties of divalent europium activated Ca-#alpha#-SiAlON were investigated and the excitation and emission processes were discussed. The emission wavelength is influenced by the activator concentration of Eu more than the codopant concentration of Ca, in case of the same matrix composition of #alpha#-SiAlON. The red-shift of emission increases when the concentration of Eu increases. In addition, it was revealed that the red-shift of emission would be caused by the construction of the package of optical device. The correlated color temperature becomes low by the red-shift for the white light-emitting diode (LED) lamp using Ca-#alpha#-SiAlON:Eu phosphor when the phosphor powder concentration increases in the transparent resin which coats the primary light source of a blue LED die. The additional red-shift can be observed when the excessive amount of phosphor coating is intentionally poured to the white LED lamps. These red-shifts of emission wavelength ...
Products having balanced melting point and decomposition temperature have been developed by employing nylon 6T fundamental molecular structure and selected copolymer components, Arlen being one of the products. It has heat resistance as good as that of super-engineering plastics, low water absorption, and excellent cost-performance which can be used for normal injection molding machines. The unit price per kilogram is low when its high heat resistance is taken into consideration. The coefficient of water absorption is as low as about 1/3 of that of nylon 66, and it can be considered to be a low water absorbing amide. The molding temperature is from 320[degree]C to 350[degree]C, the decomposition temperature is 395[degree]C at 2% weight decreasing temperature, and normal injection molding can be employed. It has excellent soldering resistance, high temperature rigidity, dimensional stability, water absorbing coefficient, as well as good chemical resistance and sliding characteristics. ...
Composites based on pure gypsum and polyester-styrene resin have been prepared using various doses of gamma radiation. Some physical properties of the prepared composites and the influence of irradiation dose on it have been studied as: compression strength, hardness, thermal decomposition temperature in nitrogen or oxygen, and the change in weight in aqueous solutions with different pH values. The glass transition temperature of the pure polymer and the composites increases with increasing the irradiation dose up to a plateau, and the glass transition temperature of the pure polymer is lower than that of the composites. The irradiation dose does not seem to affect the decomposition temperature of the pure polymer or the composites significantly and the decomposition temperature in presence of nitrogen is higher than that in presence of oxygen. Increasing the irradiation dose leads to an enhancement of the compression strength of the pure polymer and the prepared ...
Pilot-scale pyrolysis units have been in operation since 1980 to test the efficiency of thermal treatment of transuranic (TRU) solid waste to retrieve the TRUs and to reduce the volume of wastes such as spent solvent, spent resin, and others. These wastes are generated by reprocessing, fuel production, and utilities. NUKEM has developed a criticality-safe, ring-slab reactor to decompose solid TRU waste. The plant processes 25 kg/h with a polyvinyl chloride content up to 70%. The overall throughput (inactive) up to the spring of 1982 was 2000 kg. The decontamination factor for the reactor itself is 1000. The liquid wastes, mainly spent solvent, are cracked under nitrogen at 400 to 700/sup 0/C in a reactor that is filled by a packed bed kept in motion by a specially designed agitator. This unit was built for 15 kg/h water equivalent evaporation. Up to 1982 the unit processed 2000 kg of spent solvent (simulated) overall. The decontamination factor is similar to the ...
Pilot-scale pyrolysis units have been in operation since 1980 to test the efficiency of thermal treatment of transuranic (TRU) solid waste to retrieve the TRUs and to reduce the volume of wastes such as spent solvent, spent resin, and others. These wastes are generated by reprocessing, fuel production, and utilities. NUKEM has developed a criticality-safe, ring-slab reactor to decompose solid TRU waste. The plant processes 25 kg/h with a polyvinyl chloride content up to 70%. The overall throughput (inactive) up to the spring of 1982 was 2000 kg. The decontamination factor for the reactor itself is 1000. The liquid wastes, mainly spent solvent, are cracked under nitrogen at 400 to 700"0C in a reactor that is filled by a packed bed kept in motion by a specially designed agitator. This unit was built for 15 kg/h water equivalent evaporation. Up to 1982 the unit processed 2000 kg of spent solvent (simulated) overall. The decontamination factor is similar to the figures ...
Studies were conducted to examine the pressure on fluid-filled cables of electric power transmission networks in the event of an oil leak. Transition splices between paper-insulated oil-impregnated cable systems (PILC) and solid dielectric cable is difficult to perform. A proper PILC is composed of a means to contain oil within the cable structure and to keep moisture out. A failure of the cable joint could occur if an oil leak dries out the paper. Since oil pressure in most PILC cables is high, strong mechanical means must be devised to contain the oil within the cable. Resin systems, heat shrink systems and wiped lead sleeves to reseal the PILC cable over the splice, are among the methods used to stop an oil leak. A system has been designed using an EPDM tube contained under mechanical pressure; it has proven to be effective over a wide range of pressure conditions. Test results utilizing this system were presented. 1 ref., 1 tab., 4 figs.
In the nuclear power stations of GDR the rough radioactive waste includes borat-containing evaporator bottoms and spent ion exchanger resins. For its final disposal in deep geological formations (rock salt mines) this waste has to be solidified. The experience of one year lasting operation of a steam heated thin-film evaporator (heating surface 2 m{sup 3}) for evaporator bottoms to be solidified with a solid content of 200-250 g/l are reported on. In short time such amount of water is abstracted from the rough waste that due to the borate content a hot high-viscous product passes from evaporator to waste drum and there solidifies like glass to monolith. The product quality depends on the adjustment of the flow-equilibrium in the evaporator. Boric acid is used as matrix for the radioactive residues. The residual water content of the solidified waste product was about 15-20%, the volume reduction was V{sub f}=5...6. In order to be sure to get a solidified product a ...
In the nuclear power stations of GDR the rough radioactive waste includes borat-containing evaporator bottoms and spent ion exchanger resins. For its final disposal in deep geological formations (rock salt mines) this waste has to be solidified. The experience of one year lasting operation of a steam heated thin-film evaporator (heating surface 2 m"3) for evaporator bottoms to be solidified with a solid content of 200-250 g/l are reported on. In short time such amount of water is abstracted from the rough waste that due to the borate content a hot high-viscous product passes from evaporator to waste drum and there solidifies like glass to monolith. The product quality depends on the adjustment of the flow-equilibrium in the evaporator. Boric acid is used as matrix for the radioactive residues. The residual water content of the solidified waste product was about 15-20%, the volume reduction was V_f=5...6. In order to be sure to get a solidified product a process ...
Ordered mesoporous C-TiO2 nanocomposites with crystalline framework were prepared by the evaporation-induced triconstituent co-assembly method. The products were characterized by XRD, TEM, N2 adsorption-desorption and TG. Their microwave absorption properties were investigated by mixing the product and epoxy resin. It is found that the peak with minimum reflection loss value moves to lower frequencies and the ordered mesoporous C-TiO2 nanocomposite possesses an excellent microwave absorbing property with the maximum reflection loss of -25.4 dB and the bandwidth lower than -10 dB is 6.6 GHz. The attenuation of microwave can be attributed to dielectric loss and their absorption mechanism is discussed in detail. The mesoporous C-TiO2 nanocomposites also exhibit a lower infrared emissivity in the wavelength from 8 to 14 ?m than that of TiO2-free powder. -- Graphical abstract: Ordered mesoporous C-TiO2 nanocomposite with crystalline framework possess excellent microwave ...
Quasi-carbon fibers (QCFs) were prepared from Polyacrylonitrile (PAN) precursor by pyrolysis in the temperature range from 400{degrees}C to 950{degrees}C. The QCF-reinforced composites were fabricated by impregnating the QCFs with the PAN resin. The microstructural changes of both QCFs and their composites were characterized by the X-ray diffraction method. The stacking size and the crystallinity of the QCFs increased with the increasing heat treatment temperature (HTT). The crystallinity of the PAN matrix in a composite was also affected by various QCFs. DSC data indicated that thermal reaction mechanism of the composite could be altered due to the interaction between the fiber and the matrix. DMTA studies showed that good adhesion existed at the interface of the QCF-reinforced composites containing lower HTT fibers. The modulus magnitudes of QCFs and their composites increased with the QCF pyrolysis temperature. Although the QCFs exhibited a decreasing trend in ...
The manufacture and use of wood/plastic composite (WPC) as an example of wood matrix and wood sawdust/plastic composites (SDP) as an example of plastic matrix are reviewed. The raw material for WPC are mostly vinyl monomers, particularly methyl methacrylate and styrene. The reaction in WPC polymerization is radical polymerization. Researches on the radiation sources mostly resulted in gamma-ray. Electron beam can be applied only to thin products. The future use of WPC may be for furnitures, sporting goods, decorative parts and the like. Vital study on the reduction of manufacturing costs is required, for example, the improvement of reaction and the adoption of continuous process must be considered. The raw materials for SDP are wood sawdust, vinyl monomer (mostly methyl methacrylate) and resins. Electron beam accelerators are the most preferable radiation source because of its high efficiency and safe operation. SDP shows good forming property. The most preferable ...
Improvement of hinge forming performance was tried in the injection molding of plastic. At first, pushing hinge forming in a mold was made by a movable pin with the die built-in an actuator, and thin hinges of 0.07mm and 0.1mm thickness which were greatly less than the conventional forming limit (0.2mm and 0.6mm respectively) of polyacetal (POM) and polybutylene terephthalate (PBT) could be formed. Hinge characteristics of POM (hinge thickness t < 0.4mm) and PBT (t < 0.7mm) which were made by the conventional forming and failed after 1 time, were improved respectively to 30,000 times or more and 300,000 times or more by pushing forming in the mold. The hinge characteristics were greatly affected by the plastic deformability of the hinge part resin and the improvement of deformability by the pushing forming were caused by the elimination of oriented layer and the expansion of hemispherical layer of the hinge part. 6 refs., 13 figs., 1 tab.
Formaldehyde release from building products is primarily due to incompletely reacted urea-formaldehyde resin (UFR) in particleboard, medium density fiberboard (MDF), and plywood. Formaldehyde is also released from urea-formaldehyde foam insulation (UFFI) that was popular during the 1970s for retrofitting building envelopes. Results of the authors test of commercial adhesives and UF-bonded wood products show that current state-of-the-art products yield air chamber test values below 0.25 mg/m/sup 3/ immediately after manufacture and are capable of meeting 0.12 mg/m/sup 3/ indoor air standards at the current product ratio unless these products are used in places where they are exposed to high temperature and humidity. In mobile homes placed in severe climates, wall-temperature profiles show large seasonal and diurnal variations that cause large changes in formaldehyde indoor air levels. The authors work shows that diurnal formaldehyde levels may change by a factor of ...
Through DNA methylation, histone modifications, and small regulatory RNAs the epigenome systematically controls gene expression during development, both in utero and throughout life. The epigenome is also a very reactive system; its labile nature allows it to sense and respond to environmental perturbations to ensure survival during fetal growth. This pliability can lead to aberrant epigenetic modifications that persist into later life and induce numerous disease states. Endocrine-disrupting compounds (EDCs) are ubiquitous chemicals that interfere with growth and development. Several EDCs also interfere with epigenetic programming. The investigation of the epigenotoxic effects of bisphenol A (BPA), an EDC used in the production of plastics and resins, has further raised concern over the impact of EDCs on the epigenome. Using the Agouti viable yellow (A(vy)) mouse model, dietary BPA exposure was shown to hypomethylate both the A(vy) and the Cabp(IAP) metastable ...
A novel method for the determination of metoclopramide (MCP) using electrogenerated chemiluminescence (ECL) is presented. A tris(2,2prime-bipyridyl)dichlororuthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticle/perfluoinated ion-exchange resin (Nafion) with nanocomposite membrane modified glassy carbon electrode (GCE) is used. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The analytical performance of this ECL sensor for MCP is shown in detail. Under optimal experimental conditions, it has good linearity in the concentration range from 2x10-8mol/L to 1x10-5mol/L (R=0.9989) with a detection limit of 7x10-9mo...
Polymers containing hydroquinone, catechol or their corresponding benzoquinones are a special class of redox polymers. Three pathways of their syntheses are possible: condensation polymerization of suitable monomers, addition polymerization of vinyl monomers containing redox moiety, and chemical attachment of redox unit onto pre-made polymeric matrix. A range of functionalized matrices have been employed such as polyethers, polyesters, polycarbonates, polyurethanes, polyamides and others. Protection of their phenolic functionality has conducted to chemically interesting redox polymer precursors. The presence of a redox moiety coupled with the extant functionalization of the polymer matrix makes the materials very valuable, of wide properties and consequently of vast applicability. For instance, in the oil field, some polymers such as carboxy-methyl-cellulose (CMC) are often applied as to bring about a viscosity improvement and therefore to facilitate the oil drilling. In this regard, ...
The real-time neutron radiography system of the Kyoto University Reactor (KUR) has been practically applied to penetrating the side plates containing boron burnable poison to test MTR type reactor fuels and to investigation of moving objects. Compared with the image obtained by the direct film method, however, the image from the TV system is in low-contrast and poor-resolution. This paper presents some digital processing approaches to improve the image quality and the neutron TV system is successfully applied to neutron computed tomography (NCT). The frame summing technique is effective to increase the quality of the radiographic image. By using the NTV system in NCT, the projection data are able to be acquired in a single measurement as observing the projection image on a CRT monitor. Two weighting functions based on the Fourier-convolution algorithm are employed to obtain the reconstructed image. The image quality could be satisfactory to distinguish acrylic ...
The real-time neutron radiography system of the Kyoto University Reactor (KUR) has been practically applied to penetrating the side plates containing boron burnable poison to test MTR type reactor fuels and to investigation of moving objects. Compared with the image obtained by the direct film method, however, the image from the TV system is in low-contrast and poor-resolution. This paper presents some digital processing approaches to improve the image quality and the neutron TV system is successfully applied to neutron computed tomography (NCT). The frame summing technique is effective to increase the quality of the radiographic image. By using the NTV system in NCT, the projection data are able to be acquired in a single measurement as observing the projection image on a CRT monitor. Two weighting functions based on the Fourier-convolution algorithm are employed to obtain the reconstructed image. The image quality could be satisfactory to distinguish acrylic ...
Ceramic matrix composites in the TiC-Ti, Y-TZP system can be synthesized by the reaction between carbon and the TiO_2-Y_2O_3-ZrO_2 solid solution nanopowder. This method results in the more homogeneous powders than those prepared by the physical mixing of TiC and zirconia s.s. powders. Twelve TiO_2-Y_2O_3-ZrO_2 solid solution nanopowders differing in the proportions of the constituent oxides were prepared by the coprecipitation- calcination route. They were reacted with the pyrolytic carbon evenly distributed within the system. Carbon was introduced by the thermal decomposition of the phenol-formaldehyde resin dissolved in ethyl alcohol and mixed with the zirconia s.s. nanopowder. Reaction was performed in vacuum. Compacts of the composite powders sintered in vacuum give dense materials of evenly distributed TiC inclusions of sizes not surpassing 400 nm. Hardness of such materials was dependent on their chemical and phase composition but was generally higher than ...
This report surveys the possibilities and restrictions of different construction materials for the purpose of the blades of a small stall regulated turbine. For example scaling up, material saving at decreasing of static or dynamic loads, comparisons of global costs based on prices per unit of weight, etc. For the mutual comparison of construction materials for turbine blades the starting point is a stall regulated horizontal axis turbine with a rotor diameter of 16 m and a tipvane speed of about 64 m/s. Short descriptions are given of the materials and of the applied production methods with the resulting blade geometry. The blade skins are dimensionized for storm loads after the optimalization of the blade geometry, needed for the design wind speed, is recorded. The resulting blade skins are mutually compared as for weight, mass inertia and bending stiffness. Also a comparison took place of the resulting reserve factors against load variations caused by gusts of wind and own weight, ...
A carbon-bonded carbon fiber (CBCF) insulation developed for a radioisotope heat source is made from chopped rayon fiber about 10..mu..m long, which is carbonized and bonded with phenolic resin particles. The CBCF is an excellent lightweight insulating material with a nominal density of 0.2 Mg/m/sup 3/ and a thermal conductivity of 0.24 W/(m-K) in vacuum at 2000/sup 0/C. (Several attributes that make CBCF particularly suitable for the heat source application have been identified.) These include light weight, low thermal conductivity, chemical compatibility, and hightemperature capabilities. The mechanical strength of CBCF insulation is satisfactory for the application. The basic fabrication technique was refined to eliminate undesirable large pores and cracks often present in materials fabricated by earlier techniques. Also, processing was scaled up to increase the fabrication rate by a factor of 10. The specific properties of the CBCF were tailored by adjusting ...
A carbon-bonded carbon fiber (CBCF) insulation developed for a radioisotope heat source is made from chopped rayon fiber about 10 ..mu..m in diameter and 250 ..mu..m long, which is carbonized and bonded with phenolic resin particles. The CBCF is an excellent lightweight insulating material with a nominal density of 0.2 Mg/m/sup 3/ and a thermal conductivity of 0.24 W/(m-K) in vacuum at 2000/sup 0/C. Several attributes that make CBCF particularly suitable for the heat source application have been identified. These include light weight, low thermal conductivity, chemical compatibility, and high-temperature capabilities. The mechanical strength of CBCF insulation is satisfactory for the application. The basic fabrication technique was refined to eliminate undesirable large pores and cracks often present in materials fabricated by earlier techniques. Also, processing was scaled up to increase the fabrication rate by a factor of 10. The specific properties of the CBCF ...
In this work, a feasible and simple method of assembling a micro MEMS-based ?PEMFC (about 0.35 ml in volume and 0.65 g in weight) with the help of a spiral micrometer was proposed. The micrometer provided a constant pressure between the two flow field plates and MEA in assembling for a short term while a special epoxy resin was applied to seal the cell and provide long term pressure between the above components after removing the micrometer. Tests showed that the as-assembled cell had a reasonable performance, which was proved by the linear polarization and EIS experiments. The long term behavior of the ?PEMFC was stable in general except for some fluctuation along time. We concluded that this fluctuation was due to a combined effect of heat produced and water management, which the as-assembled ?PEMFC has its own ability to adjust. More importantly, this experiment demonstrated the full feasibility and great promise of assembling ?FCs with the help of a spiral ...
Wastewater from a food-manufacturing plant with a low concentration of organic matter was treated at 37 centigrade in an anaerobic fluidized-bed reactor or in an upflow anaerobic sludge blanket. As the influent TOC (total organic carbon) concentration decreased, the TOC removal efficiency in these reactors decreased from 85% to 65%. The concentration of suspended solids in the effluent could be reduced to 20 mg/l, which corresponded to 7% of that in the influent. The effluent from both reactors was treated aerobically in a fixed-bed reactor. The TOC concentration and optical density of effluent from the aerobic treatment were reduced to 5 mg/l and 0.005, respectively. When the effluent treated anaerobically or aerobically was passed over an activated carbon column, the effluent TOC concentration was reduced to 2 to 3 mg/l. The conductivity in raw wastewater was remarkably reduced on an ion-exchange resin column. Ultra-pure water for industrial use was obtained by ...
A pretreatment flowsheet was tested for separating key radionuclide components from the sludge stored in one of the high level waste tanks (B-110) at the Hanford Site; this sludge resulted primarily from the bismuth phosphate process, which was one of the three major plutonium separation processes used at Handford. This test involved (1) washing with water, (2) caustic leaching, (3) acid dissolution, (4) separation of transuranic elements (TRUs) by extraction with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO), (5) separation of Sr by extraction with di-t-butylcyclohexano-18-crown-6, (6) separation of Cs from the acid-dissolved sludge solution by treatment with ammonium molybdophosphate (AMP), and (7) separation of Cs from the sludge wash and caustic leach solutions by ion exchange using a phenol-formaldehyde resin (CS-100). The results of the radionuclide separation steps indicated that the proposed flowsheet is a viable approach to pretreating ...
This presentation describes a method for separating {sup 14}C-hexose from {sup 14}C-sucrose in extracts of plant tissue. Portions of ethanol extracts are treated with activated charcoal in microcentrifuge tubes. Aliquots are removed, ethanol evaporated and replaced with reaction mixture that phosphorylates hexose (HEPPS, K{sub 2}HPO{sub 4}, Mg(C{sub 2}H{sub 3}O{sub 2}){sub 2}, ovalbumen, Na{sub 2}ATP, yeast hexokinase). After a time course, the hexokinase reaction is stopped (slowed considerably) to minimize effects of contamination enzyme activities. The stopping agent used is lyxose, a nonphosphorylable analogue of glucose. The strong anionic charge of phosphate introduced through the hexokinase action results in binding (> 95%) of hexose-phosphate to anion-exchange resin. Sucrose remains unbound (> 95%) in solution. This batch ion-exchange is performed in microcentrifuge tubes to allow many samples to be processed simultaneously. Recovery of radiolabel in ...
Large scale production of monoclonal antibodies has been accomplished using bioreactors with different length to diameter ratios, and diverse impeller and sparger designs. The differences in these physical attributes often result in dissimilar mass transfer, mechanical stresses due to turbulence and mixing inside the bioreactor that may lead to disparities in cell growth and antibody production. A rational analysis of impeller design parameters on cell growth, protein expression levels and subsequent antibody production is needed to understand such differences. The purpose of this study was to examine the impact of Rushton turbine and marine impeller designs on Chinese hamster ovary (CHO) cell growth and metabolism, and antibody production and quality. Experiments to evaluate mass transfer...