WorldWideScience
1

Lung scintigraphy following inhalation of the new ultrafine aerosol 'Technegas'  

International Nuclear Information System (INIS)

Evaporation of "9"9"mTc-pertechnetate at about 2500"0C on a carbon surface generates an ultrafine aerosol of labelled carbon clusters. Its particle size of about 2-5 nm enables the aerosol to behave similarly to a gas regarding the ability of penetration. After inhalation, the radioactive particles adhere to the walls of the respiratory bronchioli and alveoli. The high concentration of the radioactivity in the argon carrier gas makes it possible to record a scintigram after a single deep breath. We studied four healthy volunteers and 79 patients including 34 with a tentative diagnosis of pulmonary embolism, 20 with bronchus carcinoma, and 15 with various other lung diseases. Ten of these patients were infants, the youngest being nine months old. All patients also had a perfusion scintigraphy. (orig.).

2

Effects of ultrafine particles-induced oxidative stress on Clara cells in allergic lung inflammation  

UK PubMed Central (United Kingdom)

BackgroundClara cell protein (CC16), the main secretory product of bronchiolar Clara cells, plays an important protective role in the respiratory tract against oxidative stress and...Full Text Available

3

Phase formation in gas-phase combustion and pyrolysis reactions under spark and radio-frequency discharge conditions  

British Library Electronic Table of Contents (United Kingdom)

Doped ultrafine silicon dioxide powder with a narrow particle size distribution was obtained by RF discharge-stimulated dichlorosilane (SiH2C) oxidation at a low pressure using isobutylene as the combustion inhibitor and chromium hexacarbonyl (Cr(CO)6) as the dopant. The formation and morphology of the ultrafine particles are governed by the parameters of the RF discharge and by the chemical mechanism of the combustion reaction yielding the aerosol. Submicron-sized filamentous carbon structures can be obtained by isobutylene decomposition under spark discharge conditions in the presence of a molybdenum metal catalyst.

2009-01-01

4

A new method for quantifiable and controlled dosage of particulate matter for in vitro studies: The electrostatic particulate dosage and exposure system (EPDExS)  

British Library Electronic Table of Contents (United Kingdom)

An exposure chamber is described for the quantifiable addition of fine and ultrafine aerosol particulate matter directly to cells and used to demonstrate the in vitro cytotoxicity of fine 1,4-naphthoquinone particles to murine lung epithelial cells. The electrostatic particulate dosage and exposure system (EPDExS) operates on the principle of electrostatic precipitation and is shown to deposit fine and ultrafine aerosol particles directly to cells with 100% efficiency for particle diameters in the range of 40-530nm. This range is not limited by the EPDExS, but rather by the aerosolization method used for this study. Numbers of particles deposited onto the cells are counted with a condensation particle counter, negating any need to calculate or estimate particle exposure. The process of par...

2008-01-01

5

A new method for quantifiable and controlled dosage of particulate matter for in vitro studies: the electrostatic particulate dosage and exposure system (EPDExS).  

Science.gov (United States)

An exposure chamber is described for the quantifiable addition of fine and ultrafine aerosol particulate matter directly to cells and used to demonstrate the in vitro cytotoxicity of fine 1,4-naphthoquinone particles to murine lung epithelial cells. The electrostatic particulate dosage and exposure system (EPDExS) operates on the principle of electrostatic precipitation and is shown to deposit fine and ultrafine aerosol particles directly to cells with 100% efficiency for particle diameters in the range of 40-530nm. This range is not limited by the EPDExS, but rather by the aerosolization method used for this study. Numbers of particles deposited onto the cells are counted with a condensation particle counter, negating any need to calculate or estimate particle exposure. The process of particle ...

2008-06-08

6

Synthesis and electrochemistry properties of Sn-Sb ultrafine particles as anode of lithium-ion batteries  

International Nuclear Information System (INIS)

Ultrafine particles of Sn-Sb alloys with different chemical composition have been prepared by hydrogen plasma-metal reaction. Structure, morphology, size and chemical composition of the Sn-Sb ultrafine particles were investigated by transmission electron microscopy, X-ray diffraction, BET gas adsorption, and induction-coupled plasma spectroscopy. It was found that all the particles have spherical shapes, with average particle size in the range of 100-300 nm. The electrochemistry properties as an alternative anode material for lithium-ion batteries have been characterized by constant current cycling and cyclic voltammetry. Electrochemical measurements showed that the alloys with Sn-46.5 at.% Sb have best reversible capacity and capacity retention. It exhibited a high reversible lithium-ion storage capacity of 701 mAh g"-"1 in the initial cycle, which has remained ...

2007-07-31

7

Formation of Bimodal-Sized Structure and Its Tensile Properties in a Warm-Rolled and Annealed Ultrafine-Grained Ferrite/Cementite Steel  

British Library Electronic Table of Contents (United Kingdom)

An ultrafine-grained ferrite/cementite (UGF/C) steel with a local high density of cementite particles was fabricated through caliber-warm-rolling followed by annealing and resulted in a bimodal-sized microstructure. The characteristic bimodal-sized microstructure was attributed to the original ferrite-pearlite structure and cementite spacing, and reflected the original ferrite-pearlite structure. The smaller-sized clusters corresponded to the former pearlite regions and the larger-sized clusters to the proeutectoid ferrite regions. The cementite particles naturally localized within the former pearlite region. Most of the ferrite coarsening did not occur until the cementite particle spacing reached a critical value. The UGF/C microstructure with a bimodal grain size showed a yield strength ...

2008-01-01

8

Electrochemical hydrogen storage behaviors of ultrafine Co-P particles prepared by direct ball-milling method  

Energy Technology Data Exchange (ETDEWEB)

Ultrafine particles of Co-P were synthesized by direct ball milling of Co and P powders and also investigated as a reversible hydrogen storage electrode material. The electrochemical results demonstrated that the reversible charge-discharge capacity of the Co-P electrode can reach more than 300mAh/g. In addition, the cycling ability and high rate capability of the Co-P electrode are excellent with only 5% capacity decay after 100 cycles at a high rate of 300mA/g. The temperature-programmed desorption measurements (TPD) of the Co-P electrode revealed that the charge and discharge reactions of the Co-P electrode proceeds predominantly through electrochemical hydrogen storage mechanism and the electrooxidation of cobalt contributes only a negligible part to the reversible electrochemical capacity. (author)

2006-05-25

9

High performance ultra-steels with recyclable design  

Energy Technology Data Exchange (ETDEWEB)

The global production of steel is predicted to increase rapidly to meet future demands. In order to conserve the natural resources, certain measures must be taken. These include perfecting the recycling of steel, improving the performance to extend the life of the material, and reduce the need for massive production of steel by increasing the strength of the material. This paper presented a design concept for ultrafine complex microstructure steel. The National Research Institute for Metals in Japan has worked on a project which investigated 800 MPa ferrite steel for welded structures with a chemical composition similar to 400 MPa-class plain carbon steel. The doubled strength was attributed to grain refinement. Novel welding techniques were also used for joining the ultrafine microstructure. In this study, low carbon Si-Mn ferrite-pearlite steels were subjected to a thermo-mechanical treatment to produce a microstructure of 1 micron order ...

2000-07-01

10

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

Science.gov (United States)

The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. ...

2009-12-01

11

Continuous flow dielectrophoretic particle concentrator  

Energy Technology Data Exchange (ETDEWEB)

A continuous-flow filter/concentrator for separating and/or concentrating particles in a fluid is disclosed. The filter is a three-port device an inlet port, an filter port and a concentrate port. The filter separates particles into two streams by the ratio of their dielectrophoretic mobility to their electrokinetic, advective, or diffusive mobility if the dominant transport mechanism is electrokinesis, advection, or diffusion, respectively.Also disclosed is a device for separating and/or concentrating particles by dielectrophoretic trapping of the particles.

2007-04-17

12

Pressurized electroosmotic dewatering (PED) of fine coal suspensions  

Science.gov (United States)

Current dewatering methods for ultra-fine coal suspensions are inadequate and usually require subsequent expensive thermal drying. This unique dewatering method is based on pressurized electroosmosis, the movement of water by an electrical field through a porous medium, under modest pressure, e.g., 110 psi. More ultra-fine coal can be utilized since an effective dewatering process can be realized by combining known filtration techniques with electroosmosis. The dewatering efficiency can be significantly improved, the residual moisture of the cake can be substantially reduced and handling problems can be eliminated. Bench-scale testing is being used to optimize the parameters which influence pressurized electroosmotic dewatering (PED) of ultra-fine coal suspensions. Particle size distribution is being addressed to obtain a maximum density for a given pressure such that pore saturation is maintained ...

1985-01-01

13

Imaging-based dust sensors: equipment and methods  

Science.gov (United States)

Dust detection and control in real time, represent one of the most challenging problem in all those environments where fine and ultrafine airborne particulate solids products are present. The presence of such products can be linked to several factors, often directly related and influenced by the working-production actions performed. Independently from the causes generating dust, airborne contaminants are an occupational problem of increasing interest as they are related to a wide number of diseases. In particular, airborne dusts are well known to be associated with several classical occupational lung diseases, such as the pneumoconiosis, especially at high levels of exposure. Nowadays there is also an increasing interest in other dust related diseases, from the most serious as cancer and asthma, to those related with allergies or irritation and other illnesses, also occurring at lower levels of exposure. Among the different critical factors influencing health risk ...

2004-05-01

15

Preparation of ZnO varistors by solution nano-coating technique  

Energy Technology Data Exchange (ETDEWEB)

This paper introduces a new method to produce nano-composite powder for the preparation of high performance ZnO varistors. ZnO particles were coated with Bi{sub 2}O{sub 3}, Sb{sub 2}O{sub 3}, Co{sub 2}O{sub 3}, Cr{sub 2}O{sub 3} and other additives via liquid nano-coating technique. Then the prepared powder was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravity and differential scanning calorimetry (TG-DSC) and particle size distribution. The results showed that the ZnO composite powder is homogeneously coated and ultrafine. The densification, phase composition and microstructure of ZnO varistors was studied by linear shrinkage, X-ray diffraction (XRD) and SEM, respectively. The preliminary electrical parameters of ZnO varistors showed that the breakdown voltage V {sub b} (1 mA/cm{sup 2}) and nonlinear coefficient {alpha} is 5400 V/cm and 50, respectively, much ...

2006-06-15

16

Measurements of the concentration and composition of nuclei for cirrus formation  

UK PubMed Central (United Kingdom)

This article addresses the need for new data on indirect effects of natural and anthropogenic aerosol particles on atmospheric ice clouds. Simultaneous measurements of the concentration and composition...Full Text Available

2003-12-09

17

Entropic effects in channel-facilitated transport: Inter-particle interactions break the flux symmetry  

UK PubMed Central (United Kingdom)

We analyze transport through conical channels due to the difference in particle concentration on the two sides of the membrane. Because of the detailed balance, fluxes of non-interacting particles...Full Text Available

2009-08-01

18

Wear particle equilibrium measurements and their significance  

Energy Technology Data Exchange (ETDEWEB)

Ferrography is a technique for isolating wear particle debris from lubricating and hydraulic oils, the presence of which carry with them a history of the wear processes in the machine. Thus, the technique has fundamental applications in machine condition monitoring and failure prevention. The wear particles are significant in the metal types that are present in the particle distribution as an indication of the wearing machine components and in the particle size distribution and morphology which indicates the severity of wear in the system. In this paper, the fundamental principles which describe the working of the ferrograph, concentrating on the working of the on-line ferrograph are discussed. The significance of equilibrium particle concentration in the oil system and its measurement using the ferrograph are also discussed.

1980-11-01

19

Prototype exposure chamber of radon for animal experiments  

Energy Technology Data Exchange (ETDEWEB)

To evaluate a dose conversion factor from the `Working Level of Month` (WLM) of radon to the absorbed dose (mGy), the quality of radon and its progeny was assessed, and exposures controlled for each deposition region were planed as follows: 1) exposure of radon gas to the entire respiratory tract, 2) exposure of `unattached` fractions to the upper respiratory tract, 3) exposure of `attached` fractions onto ultrafine particles to the deep lung, 4) exposure of `attached` fractions onto fine particles to the lower respiratory tract, 5) exposure of `attached` fractions onto coarse particles to the upper respiratory tract. In this preliminary study, a prototype exposure system of radon and its progeny for small rodents was designed. A whole body exposure chamber with a volume of about 0.5 m{sup 3} was used, which it held 20 rats. The aging and mixing chamber separated by the exposure chamber had a volume of ...

1998-12-31

20

Experimental study of nanoparticles penetration through commercial filter media  

Energy Technology Data Exchange (ETDEWEB)

In this study, nanoparticle penetration was measured with a wide range of filter media using silver nanoparticles from 3 nm to 20 nm at three different face velocities in order to define nanoparticle filtration characteristics of commercial fibrous filter media. The silver particles were generated by heating a pure silver powder source via an electric furnace with a temperature of 870 deg. C, which was found to be the optimal temperature for generating an adequate amount of silver nanoparticles for the size range specified above. After size classification using a nano-DMA, the particle counts were measured by an Ultrafine Condensation Particle Counter (UCPC) both upstream and downstream of the test filter to determine the nanoparticle penetration for each specific particle size. Particle sampling time continued long enough to detect more than 10{sup 5} counts at ...

2007-01-15

21

Variable Frequency Microwave Synthesis of Silver Nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

Synthesis of silver nanoparticles based on a polyol process and variable frequency microwave (VFM) was investigated. Comparing to a thermal method, the reaction by VFM radiation was much faster. The effects of silver nitrate concentration, poly(N-vinylpyrrolidone) (PVP) concentration, reaction time and reaction temperature were studied. It was found that the higher concentration of silver nitrate, longer reaction time and higher temperature increased the particle size while the higher concentration of PVP decreased the particle size.

2006-02-15

22

Potentials of biofuels  

Energy Technology Data Exchange (ETDEWEB)

This paper discussed the potential of biofuels with particular reference to the situation in Germany and Europe. Emphasis was on technical potential, such as biofuel production, utilization and environmental aspects. The Institute of Agricultural Technology and Biosystems Engineering ran vTI emission tests on diesel engines to evaluate the environmental impacts of biofuels. This testing facility is able to drive heavy-duty diesel engines in both stationary and dynamic test cycles, such as the European ESC and ETC. Additional analyses were conducted to determine the fine and ultra-fine particles, polycyclic aromatic hydrocarbons (PAH), aldehydes, ketones, and the usual regulated exhaust gas compounds. Ames tests were conducted to assess the mutagenic potential of tailpipe emissions. Previous study results showed that neat vegetable oils can render the exhaust high in mutagenic potency. Some of the non-regulated exhaust gas compounds were found ...

2010-07-01

23

Microstructure engineering from metallic powder blends for enhanced mechanical properties  

International Nuclear Information System (INIS)

The present work focuses on the transformation of high-purity Ni powder blends of controlled volume fractions (40 and 60 %) of nanometre-sized (100 nm) and micrometre-sized (544 nm) particles into bulk samples as part of a strategy for producing ultrafine-grained materials usefully exhibiting both strength and ductility. The process involved cold isostatic pressing at 1.5 GPa and sintering. The resulting bulk samples had relative densities near 95 %, were texture-free, and exhibited two different grain size distributions with an average value of 600 #+-# 30 nm. The mechanical properties were investigated by compression and microhardness tests, both at room temperature, and compared to the behaviour of a sample processed from micrometre-sized powder only. Samples prepared from the blends exhibited high yield stresses of 440 and 550 MPa after compression, and they did sustain work hardening. Tests conducted before and after compression up to 50 % ...

2010-07-01

24

Advanced direct liquefaction concepts for PETC generic units. Quarterly report, October 1991--December 1991  

Science.gov (United States)

A laser pyrolysis technique has been used to produce ultrafine particles of iron carbide with diameters ranging from 2 to 20 nm. Catalysis using iron carbide was investigated in the liquefaction of Wyodak subbituminous coal; yields were determined. A study was carried out to examine the possibility of using an ultrasonic extraction technique as a rapid method of product work-up of samples following pretreatment or liquefaction experiments. A similar study had shown that extraction of coal-derived products by an ultrasonic method was rapid and gave yields and product distributions comparable to those obtained by Soxhlet extraction. On another project, three different types of supported catalysts were used to test activity for the combined water-gas shift hydrogenation of a synthetic donor solvent. The three catalysts tested were: (1) Alumina supported NiMo catalyst-Shell 324m; (2) Bulk hydrous TiO NiMo catalyst; (3) Thin film hydrous TiO ...

1991-12-31

25

Control of airborne particle concentration and draught risk in an operating room  

Energy Technology Data Exchange (ETDEWEB)

The influence of location of airborne particle source, ventilation rate, air inlet size, supply air velocity, air outlet location, and heat source on the distributions of airborne particle concentration and draught risk in an operating room is investigated. The investigation is carried out by using a flow program with the k-[epsilon] model of turbulence. Based on a standard case, five cases, each with one changed parameter, are computed, and the detailed field distributions of air velocity, temperature, airborne particle concentration, and draught risk are presented. The parametric study concludes that, for a better air quality and thermal comfort, it is desirable to use a higher inflow rate, a larger inlet area, and a uniform velocity profile of supply air. Outlet location and heat source have little influence on the distributions of the particle ...

1992-01-01

26

Effect of charge dilution on gaseous and particulate emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol and ethanol  

British Library Electronic Table of Contents (United Kingdom)

In this study, the effect of intake charge dilution with carbon dioxide on the combustion and emission characteristics of a 4-cylinder direct-injection diesel engine fueled with biodiesel, ethanol-biodiesel and methanol-biodiesel were investigated. With increase of intake CO"2 concentration, CO, HC, particulate mass concentration, particle number concentration and geometric diameter (GMD) of all fuels increased while NO"x decreased obviously. After addition of methanol and ethanol in biodiesel, the NO"x, particulate mass concentration and particle number concentration decreased at each intake CO"2 concentration, compared with biodiesel. Moreover, as the intake CO"2 concentration increased from 2% to 5.6%, particulate mass concentration of the alcohol-biodiesel blends remained ...

2011-01-01

27

Solidification of radioactive waste effluents  

Energy Technology Data Exchange (ETDEWEB)

A process and apparatus for solidifying radioactive waste liquid containing dissolved and/or suspended solids is disclosed. The process includes chemically treating for pH adjustement and precipitation of solids, concentrating solids with a thin-film evaporator to provide liquid concentrate containing about 50% solids, and drying the concentrate with heated mixing apparatus. The heated mixing apparatus includes a heated wall and working means for shearing dried concentrate from internal surfaces and subdividing dry concentrate into dry, powdery particles. The working means includes a rotor and helical means for positively advancing the concentrate and resulting dry particles from inlet to outlet of the mixing apparatus. The dry particles may also be encapsulated in a matrix material. Entrained ...

1983-10-11

28

Ultra fine grinding of low-rank coal. Progress report, April-June 1986  

Energy Technology Data Exchange (ETDEWEB)

The lignite used for Phase I of the project was a Texas lignite from the Martin Lake mine obtained from the stockpile for the Martin Lake Power Plant of the Texas Utilities Generating Company. The power requirements for the fluid-energy mill were determined from the measured steam (or air) temperatures, pressures and pressure drops and the lignite flow rate. The instrument locations for the tests are shown on Figure 1. All of the instruments were connected to a microcomputer via an analog input interface board. Data were recorded on disks periodically throughout the tests. Appropriate calibration procedures were followed to assure that reliable data were being obtained. The combined grinding/drying tests were conducted in Vicksbuth, MS at Ergon, Inc.'s fluid-energy-mill facility. both steam and air were used as grinding fluids. With steam, tests were used as grinding fluids. With steam, tests were run with the following temperatures maintained inside the pulverizer: 310/sup ...

1986-07-01

29

Microstructure evolution and strength-reduction in area balance of ultrafine-grained steels processed by warm caliber rolling  

British Library Electronic Table of Contents (United Kingdom)

Ultrafine grained steels with different carbon contents were produced through warm caliber rolling and evaluated for their stress-strain behavior along with the reduction in area. It was found that the reduction in area-tensile strength balance is far better than the conventional ferrite+pearlite steels and even superior to bainitic steels for all materials tested in the present study.

2006-01-01

30

Battery using a metal particle bed electrode  

Energy Technology Data Exchange (ETDEWEB)

A zinc-air battery in a case including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit.

1991-01-01

31

Battery using a metal particle bed electrode  

Energy Technology Data Exchange (ETDEWEB)

A zinc-air battery in a case is described including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit. 7 figures.

1991-04-09

32

A particle tracking transport method for the simulation of resident and flux-averaged concentration of solute plumes in groundwater models  

British Library Electronic Table of Contents (United Kingdom)

A new numerical technique called the convolution-based particle tracking (CBPT) method is developed to simulate resident or flux-averaged solute concentrations in groundwater models. The method is valid for steady-state flow and linear transport processes such as sorption with a linear sorption isotherm and first-order decay. The CBPT method uses particle tracking to take advantage of the ability of particle-based approaches to maintain sharp fronts for advection-dominated transport problems common in groundwater modeling and because of the flexibility of the random walk method to simulate a wide range of possible forms of the dispersion tensor. Furthermore, the algorithm for carrying out the convolution and superposition calculation from particle tracking results is very efficient. We sho...

2010-01-01

33

Development program for magnetically assisted chemical separation: Evaluation of cesium removal from Hanford tank supernatant  

International Nuclear Information System (INIS)

Magnetic particles (MAG*SEP"S"M) coated with various absorbents were evaluated for the separation and recovery of low concentrations of cesium from nuclear waste solutions. The MAG*SEP"S"M particles were coated with (1) clinoptilolite, (2) transylvanian volcanic tuff, (3) resorcinol formaldehyde, and (4) crystalline silico-titanate, and then were contacted with a Hanford supernatant simulant. Particles coated with the crystalline silico-titanate were identified by Bradtec as having the highest capacity for cesium removal under the conditions tested (variation of pH, ionic strength, cesium concentration, and absorbent/solution ratio). The MAG*SEP"S"M particles coated with resorcinol formaldehyde had high distribution ratios values and could also be used to remove cesium from Hanford supernant simulant. Gamma irradiation studies were performed on the MAG*SEP"S"M ...

1994-05-09

34

Radiative transfer in a solar absorbing particle laden flow  

Science.gov (United States)

A possible receiver configuration is a cavity in which a falling sheet of solid particles is directly irradiated by the concentrated solar flux passing through the aperture. Regardless of the particular geometry, the radiative transfer within the falling particle curtain must be studied in order to determine the net radiative heating rate for the particles. A discrete ordinate radiative transfer model has been developed to predict the radiative coupling within the falling particle curtain. The model determines how much energy is absorbed by the particles, how much is transmitted to the rear wall of the receiver, and determines the effects of particle scattering and thermal emission on the net radiation absorbed by the particles. The model accounts for the directional nature of the radiation field, ...

1985-11-01

35

Microstructure and properties of ultrafine WC-10Co composites with chemically doped VC  

British Library Electronic Table of Contents (United Kingdom)

Vanadium carbide is the most effective grain growth inhibitor for ultrafine WC-Co composites due to its high solubility and mobility in the cobalt phase at relatively low temperatures; however, there are still some debates over the best way to introduce it into the WC-Co formulation. In this paper, the differences between admixed and chemically doped grain growth inhibitors on the microstructural development and properties of an ultrafine WC-10Co composite are discussed. The densification rate of chemically doped samples is slower in the early stage of sintering and the WC grain sizes of the sintered alloys are finer than those of admixed samples, leading to the increase of hardness and transverse rupture strength of the sintered alloys. The effectiveness of the chemically doped inhibitor ...

2011-01-01

36

Local thermal property analysis by scanning thermal microscopy of an ultrafine-grained copper surface layer produced by surface mechanical attrition treatment  

International Nuclear Information System (INIS)

Scanning thermal microscopy (SThM) was used to map thermal conductivity images in an ultrafine-grained copper surface layer produced by surface mechanical attrition treatment (SMAT). It is found that the deformed surface layer shows different thermal conductivities that strongly depend on the grain size of the microstructure: the thermal conductivity of the nanostructured surface layer decreases obviously when compared with that of the coarse-grained matrix of the sample. The role of the grain boundaries in thermal conduction is analyzed in correlation with the heat conduction mechanism in pure metal. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a tool for the thermal property and microstructural analysis of ...

2006-06-15

37

Uncertainties of retrospective radon concentration measurements by multilayer surface trap detector  

Energy Technology Data Exchange (ETDEWEB)

The detector for retrospective radon exposure measurements is developed. The detector consists of the multilayer package of solid-state nuclear track detectors LR-115 type. Nitrocellulose films works both as {alpha}-particle detector and as absorber decreasing the energy of {alpha}-particles. The uncertainties of implanted {sup 210}Pb measurements by two- and three-layer detectors are assessed in dependence on surface {sup 210}Po activity and gross background activity of the glass. The generalized compartment behavior model of radon decay products in the room atmosphere was developed and verified. It is shown that the most influencing parameters on the value of conversion coefficient from {sup 210}Po surface activity to average radon concentration are aerosol particles concentration, deposition velocity of unattached {sup 218}Po and air exchange rate. It is demonstrated that with ...

2006-07-01

38

Effect of VC and NbC additions on microstructure and properties of ultrafine WC-10Co cemented carbides  

British Library Electronic Table of Contents (United Kingdom)

The nanocomposite WC-Co powders were prepared through planetary ball milling method. Effects of grain growth inhibitor addition and the vacuum sintering parameters on the microstructure and properties of ultrafine WC-10Co cemented carbides were investigated using X-ray diffractometer, scanning electron microscope and mechanical property tester. The results show that VC and NbC additions can refine the WC grains, decrease the volume fraction of Co3W3C phase in ultrafine WC-10Co cemented carbides, and increase the hardness and fracture toughness of the base alloys. After sintering for 60 min at 1400 degreeC, the average grain size and hardness of ultrafine-grained WC-10Co-1VC cemented carbide are 470 nm and HRA 91.5, respectively. The fracture toughness of cemented carbide WC-10Co-1NbC alloy...

2009-01-01

39

Solar thermal cracking of methane in a particle-flow reactor for the co-production of hydrogen and carbon  

British Library Electronic Table of Contents (United Kingdom)

An experimental investigation on the thermal decomposition of CH4 into C and H2 was carried out using a 5kW particle-flow solar chemical reactor tested in a solar furnace in the 1300-1600K range. The reactor features a continuous flow of CH4 laden with mm-sized carbon black particles, confined to a cavity receiver and directly exposed to concentrated solar irradiation of up to 1720 suns. The reactor performance was examined for varying operational parameters, namely the solar power input, seed particle volume fraction, gas volume flow rate, and CH4 molar concentration. Methane conversion and hydrogen yield exceeding 95% were obtained at residence times of less than 2.0s. A solar-to-chemical energy conversion efficiency of 16% was experimentally reached, and a maximum value of 31% was numer...

2009-01-01

40

One-step synthesis of Pt-supported carbon nanohorns for fuel cell electrode by arc plasma in liquid nitrogen  

International Nuclear Information System (INIS)

One-step synthesis of Pt-loaded carbon nanoparticles including single-wall carbon nanohorns (SWNHs) by arc plasma in liquid nitrogen was demonstrated using Pt-contained graphite anode. The size distribution of Pt particles can be controlled by adjusting the concentration of Pt in the graphite anode. In the observation by transmission electron microscope, the diameter of less than 5 nm of Pt particles were observed as approximately 90% among the Pt particles when Pt was contained in the anode at 1.3 at.%. When Pt concentration in the anode was decreased to 0.4 at.%, the percentage of Pt particles whose diameter is less than 5 nm decreased to approximately 60%. It was verified that the as-grown Pt-loaded products produced by this method can be useful for the power generation by polymer electrolyte fuel cell.

2006-10-10

41

Leaching of zinc sulfide by Thiobacillus ferrooxidans: Bacterial oxidation of the sulfur product layer increases the rate of zinc sulfide dissolution at high concentrations of ferrous ions  

Energy Technology Data Exchange (ETDEWEB)

This paper reports the results of leaching experiments conducted with and without Thiobacillus ferroxidans at the same conditions in solution. The extent of leaching of ZnS with Bacteria is significantly higher than that without bacteria at high concentrations of ferrous ions. A porous layer of elemental sulfur is present on the surfaces of the chemically leached particles, which no sulfur is present on the surfaces of the bacterially leached particles. The analysis of the data using the shrinking-core model shows that the chemical leaching of ZnS is limited by the diffusion of ferrous ions through the sulfur product layer at high concentrations of ferrous ions. The analysis of the data shows that diffusion through the product layer does not limit the rate of dissolution when bacteria are present. This suggests that the action of T.ferroxidans in oxidizing the sulfur formed on the ...

1999-12-01

42

Radiation electromagnetic effect in germanium crystals under high-energy #alpha#-particle irradiation  

International Nuclear Information System (INIS)

Results of experimental investigation into radiation electromagnetic effect (REM) in samples of germanium crystals under approximately 40 MeV #alpha#-particle irradiation in a cyclotron are presented. A high level of excitation, volumetric character of generation of non-equilibrium carriers and formation of defects as well as the form of their spatial distribution are shown to result in some peculiarities of the EMF of the REM effect on the particle flux, fluence and sample parameters. Agreement of theoretical calculations, conducted with account of specificity of #alpha#-particle interaction with a crystal, and experimental data is obtained. It is revealed that the REM effect can be applied in obtaining data on spatial distribution of non-equilibrium carrier concentrations along the particle trajectory in the crystal.

43

Kinetic behavior of solid particle in chemical-looping combustion: suppressing carbon deposition in reduction  

Energy Technology Data Exchange (ETDEWEB)

In order to apply chemical-looping combustion to a practical power plant, carbon deposition on the solid particle is one of the key problems to be overcome. Six kinds of solid particles were examined to clarify the kinetic behavior of carbon deposition. The effects of the solid composition, feed gas composition, and reaction temperature on carbon deposition were investigated by thermogravimetrical reactor on the basis of NiO/YSZ particle. From the viewpoints of both reactivity and resistance against carbon deposition, the particle of NiO mixed with YSZ (i.e., yttria-stabilized zirconia) was found to be a good candidate for chemical-looping combustion. It has been observed that carbon deposition could be completely avoided with very low concentration of water vapor. By means of a proposed model, the condition that carbon deposition would be avoided was identified. 12 refs., 8 figs., ...

1998-03-01

44

Crystallization fouling of calcium sulfate dihydrate on heat-transfer surfaces  

Energy Technology Data Exchange (ETDEWEB)

The present paper deals with the fouling process of calcium sulfate dehydrate on heat-transfer surfaces. The crystallization of calcium sulfate showed typical asymptotic fouling curves, the asymptotic value of which was greatly influenced by the surface temperature and fluid velocity. The fouling mechanism was discussed with a generalized fouling model and proved to be surface process controlled, where the activation energy was 6.2 {times} 10{sup 4} J/mol. The availability of mechanical cleaning against the formed scale was quantitatively evaluated by applying the particle abrasion method. The removal test verified that the removing rate per unit particle concentration decreased in an inverse proportion to the overall particle load, to the power of 0.8, and that it was affected by the fluid velocity. The observed final residual fouling resistance decreased asymptotically with an increase in ...

1996-02-01

45

ISDD: A Computational Model of Particle Sedimentation, Diffusion and Target Cell Dosimetry for In Vitro Toxicity Studies  

Energy Technology Data Exchange (ETDEWEB)

Background: The difficulty of directly measuring cellular dose is a significant obstacle to application of target tissue dosimetry for nanoparticle and microparticle toxicity assessment. As a consequence, the target tissue paradigm for dosimetry and hazard assessment of nanoparticles has largely been ignored in favor of using metrics of exposure (e.g. ?g particle/mL culture medium, particle surface area/mL, particle number/mL). We have developed a computational model of solution particokinetics (sedimentation, diffusion) and dosimetry for non-interacting spherical particles and their agglomerates in monolayer cell culture systems. Particle transport to cells is calculated by simultaneous solution of Stokes Law (sedimentation) and the Stokes-Einstein equation (diffusion). Results: The In vitro Sedimentation, Diffusion and Dosimetry model (ISDD) was tested against measured transport ...

2010-11-30

46

Transuranic separation using organophophorus extractants adsorbed onto superparamagnetic carriers.  

Energy Technology Data Exchange (ETDEWEB)

Polymeric coated ferromagnetic carriers with an absorbed layer of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) diluted by tributyl phosphate (TBP) are being evaluated for application in the separation and the recovery of low concentrations of americium, plutonium, and uranium from nuclear waste solutions. Due to their chemical nature, these extractants selectively complex americium and plutonium contaminants onto the particles and the complexed particles can be recovered from the solution using a magnet. Physical and chemical characterization of the extractant-absorbed particles were performed by gamma and liquid scintillation counting, scanning electron microscopic (SEM) micrograph, and other physical measurements. Plutonium, americium, and uranium separations have been performed at various HNO{sub 3} and HCl concentrations. Parameters were studied to determine ...

1998-10-07

47

The formation and removal characteristics of aerosols in ammonia-based wet flue gas desulfurization  

British Library Electronic Table of Contents (United Kingdom)

The characteristics of aerosol generation were studied experimentally in an ammonia-based wet flue gas desulfurization process. Particle size distributions and concentrations, morphologies and compositions before and after desulfurization were measured using an electrical low pressure impactor and scanning electron microscopy, respectively. The results show that aerosols can be generated between ammonia and sulfur dioxide resulting in gas-phase reaction and the aerosol concentration at the outlet of scrubber is significantly higher than at the inlet. Before desulfurization the particles are primarily silica-alumina minerals including O, Al, Si and C, while after ammonia-based desulfurization aerosol particles have smooth surfaces with regular structures, such as cubic and prismatic crystal...

2011-01-01

48

Investigation of the removal efficiency of gasborne particles in a scrubber column  

Energy Technology Data Exchange (ETDEWEB)

Tests on the scrubbing column have led to the following results: Use of a scrubbing column with Raschig rings is only meaningful for the sedimentation of particles exceeding diameters of 0.5 ..mu..m; drops of diameter size 1.5 ..mu..m are formed in the column; more efficient drop precipitators in the column air flow ease the load on subsequent suspended material filters thereby contributing to a longer life of these filters even at higher sodium ion concentrations in the washing water; with distillate of an 8% rather than 0.8% salt solution a decontamination factor greater than 10 can be calculated since larger particles precipitate more readily. This only applies, however, under the condition that the washing water is renewed regularly, if necessary daily where higher aerosol concentrations are present. If not, the decontamination factor will be reduced through the salt-containing secondary aerosols ...

1983-01-01

49

Investigation of the removal efficiency of gasborne particles in a scrubber column  

International Nuclear Information System (INIS)

Tests on the scrubbing column have led to the following results: Use of a scrubbing column with Raschig rings is only meaningful for the sedimentation of particles exceeding diameters of 0.5 #mu#m; drops of diameter size 1.5 #mu#m are formed in the column; more efficient drop precipitators in the column air flow ease the load on subsequent suspended material filters thereby contributing to a longer life of these filters even at higher sodium ion concentrations in the washing water; with distillate of an 8% rather than 0.8% salt solution a decontamination factor greater than 10 can be calculated since larger particles precipitate more readily. This only applies, however, under the condition that the washing water is renewed regularly, if necessary daily where higher aerosol concentrations are present. If not, the decontamination factor will be reduced through the salt-containing secondary aerosols from ...

50

Measurement of the concentration of coal slurry using microwave techniques; Maikuroha wo oyoshita konodo sekitan slurry no nodo sokutei ni tsuite  

Energy Technology Data Exchange (ETDEWEB)

The paper reported on an experiment on measurement of concentration of highly concentrated coal slurry using microwaves carried out at Miike coal preparation works. The purpose of the experiment was to investigate applicability of microwave moisture content measurement of slurry of a mixture of coal and coal particles and to use it to the control of process such as coal preparation and processing. In the experiment, a method for measuring the slurry concentration was adopted in which the container filled with highly concentrated coal slurry was irradiated with microwaves and the damping of strength of the penetrating microwaves was detected. As a result of the experiment, it was found out that there was a big correlation between the capacitive concentration of slurry and the damping ratio of microwaves. When irradiating slurry with microwaves of 1GHz frequency, ...

1996-09-30

51

Particle Swarm Optimization  

CERN Document Server

Particle Swarm Optimization

2006-01-01

52

In situ composite coating of titania-hydroxyapatite on titanium substrate by micro-arc oxidation coupled with electrophoretic deposition processing  

British Library Electronic Table of Contents (United Kingdom)

In situ composite coating of hydroxyapatite (HA)/TiO2 were produced on titanium (Ti) substrate by micro-arc oxidation coupled with electrophoretic deposition (MAO&EPD) technique with different concentrations of HA particles in the 0.2M NaOH electrolyte solution. The surface morphology and chemical composition of the hybrid coating were effected by HA concentration. The amount of HA particles incorporated into coating layer increased with increasing HA concentration used in the electrolyte solution. The corrosion behavior of the coating layer in simulated body fluids (SBF) was evaluated using a potentiodynamic polarization test. The corrosion resistance of the coated sample was increased compared to the untreated Ti sample. The in vitro bioactivity assessment showed that the MAO&EPD treated...

2011-01-01

53

Cloud-point measurement for (sulphate salts + polyethylene glycol 15000 + water) systems by the particle counting method  

International Nuclear Information System (INIS)

The phase separation of (water + salt + polyethylene glycol 15000) systems was studied by cloud-point measurements using the particle counting method. The effect of three kinds of sulphate salt (Na2SO4, K2SO4, (NH4)2SO4) concentration, polyethylene glycol 15000 concentration, mass ratio of polymer to salt on the cloud-point temperature of these systems have been investigated. The results obtained indicate that the cloud-point temperatures decrease linearly with increase in polyethylene glycol concentrations for different salts. Also, the cloud points decrease with an increase in mass ratio of salt to polymer.

2009-07-01

54

Particle emission from low energy proton bombardment of TiH{sub 2} and TiD{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

TiH{sub 2} and TiD{sub 2} thick targets were bombarded with 100 to 200 keV protons. Evidence for nuclear reactions was obtained by means of a surface barrier particle detector. Proton irradiation of TiD{sub 2} produced the following observations: {alpha} particle emission identified as (p, {alpha}) reactions from {sup 11}B and {sup 7}Li impurities in the target at ppm concentrations; and {approx}3 MeV proton and {approx}1 MeV triton emission from secondary D-D reactions caused by elastic scattering of the primary proton with a target deuteron. A 3.9 MeV {alpha} particle peak measured by others was not observed. (author)

2002-03-01

55

Combustion characteristics of fuel droplets with addition of nano and micron-sized aluminum particles  

Energy Technology Data Exchange (ETDEWEB)

The burning characteristics of fuel droplets containing nano and micron-sized aluminum particles were investigated. Particle size, surfactant concentration, and the type of base fluid were varied. In general, nanosuspensions can last much longer than micron suspensions, and ethanol-based fuels were found to achieve much better suspension than n-decane-based fuels. Five distinctive stages (preheating and ignition, classical combustion, microexplosion, surfactant flame, and aluminum droplet flame) were identified for an n-decane/nano-Al droplet, while only the first three stages occurred for an n-decane/micron-Al droplet. For the same solid loading rate and surfactant concentration, the disruption and microexplosion behavior of the micron suspension occurred later with much stronger intensity. The intense droplet fragmentation was accompanied by shell rupture, which caused a massive explosion of ...

2011-02-15

56

Development of a fine and ultra-fine group cell calculation code SLAROM-UF for fast reactor analyses  

International Nuclear Information System (INIS)

A cell calculation code SLAROM-UF has been developed for fast reactor analyses to produce effective cross sections with high accuracy in practical computing time, taking full advantage of fine and ultra-fine group calculation schemes. The fine group calculation covers the whole energy range in a maximum of 900-group structure. The structure is finer above 52.5 keV with a minimum lethargy width of 0.008. The ultra-fine group calculation solves the slowing down equation below 52.5 keV to treat resonance structures directly and precisely including resonance interference effects. Effective cross sections obtained in the two calculations are combined to produce effective cross sections over the entire energy range. Calculation accuracy and improvements from conventional 70-group cell calculation results were investigated through comparisons with reference values obtained with continuous energy Monte Carlo calculations. It was confirmed that ...

2006-08-01

57

Formation of Si-nanoparticles in a microwave reactor: Comparison between experiments and modelling  

International Nuclear Information System (INIS)

The formation and growth of silicon-nanoparticles from silane in a microwave reactor was investigated. Experiments were performed for the following conditions: precursor concentration 380-2530 ppm, pressures of 20-30 mbar, microwave powers 120-300 W. The formed particles were examined in-situ with a particle mass spectrometer. Additionally, particles were collected on grids and analyzed by transmission electron microscopy, X-ray diffraction, and by determining the specific surface area by BET. The particle size was found to be in the range of 5-8 nm in diameter. A simple model was used to simulate the particle formation processes taking place inside the reactor. The microwave energy coupled into the reactor flow was treated as a spatially distributed energy source resulting in a local temperature increase. The particles were assumed to have ...

2005-02-01

58

Strength and toughness tradeoffs for an ultrafine-grain size ferrite/cementite steel produced by warm-rolling and annealing  

British Library Electronic Table of Contents (United Kingdom)

For an ultrafine grain ferrite/cementite (UGF/C) steel, the Charpy impact energy was measured at temperatures from 373K to 4.2K, and tensile tests were carried out at temperatures between 323K and 77K. For the steel with annealed microstructure, the ductile-to-brittle transition appearance temperature (DBTT) was lower than the Charpy transition temperature (CTT). With increasing annealing time at 873K, the DBTT and the CTT increased, and the DBTT approached the CTT. The DBTT decreased with decreasing effective grain size. The effective grain size correlated to the grain size of the larger grain size peak in the distribution of grains with {100} planes. The annealed microstructures had higher yield strength for equivalent toughness (including upper shelf energy, DBTT and CTT) compared to th...

2011-01-01

59

Mechanism of filler action in reducing the wear of PTFE polymer by differential scanning calorimetry  

British Library Electronic Table of Contents (United Kingdom)

Two types of representative nanometer materials, i.e., fibroid nanometer attapulgite and approximate spherical ultrafine diamond, were selected as fillers of polytetrafluoroethylene (PTFE) to study the mechanism of the wear-reducing actions of the fillers in PTFE composites. The friction and wear tests were performed on a block-on-ring wear tester under dry sliding conditions. Differential scanning calorimetry (DSC) was used to investigate material microstructure and to examine modes of failure. No significant change in coefficient of friction was found, but the wear rate of PTFE composites was orders of magnitude less than that of pure PTFE. DSC analysis revealed that nanometer attapulgite and ultrafine diamond played a heterogeneous nucleation role in PTFE matrix and consequently resulte...

2007-01-01

60

Interfacial ultrafine-grained structures on aluminum alloy 6061 joint and copper alloy 110 joint fabricated by magnetic pulse welding  

British Library Electronic Table of Contents (United Kingdom)

Magnetic pulse welding is a solid state impact welding process, similar to explosive welding, which produces metallurgical bond by oblique high-speed impact between two metal bodies. This violent impact removes the metal surface oxide layers and then joins the two atomic level clean metal surfaces together by the incidental compression pressure. The impact velocity is at 200?400?m/s and the being welded metal surface undergoes severe plastic deformation with strain rate in the order of 106?107?s?1. The ultrafine-grained structure was observed on the welded interface. This article studied two types of similar material lap joint interfaces and the base metals were aluminum alloy 6061 and copper alloy 110. Nano-indentation testing shows that the welded interfaces have significantly greater ha...

2010-01-01

61

Cd speciation in biomass fly ash particles after size separation by centrifugal SPLITT  

Energy Technology Data Exchange (ETDEWEB)

The finest particle size fractions ({le} 25 {mu}m) in four fly ash samples from fluidised bed combustion of three biomass based fuels and a municipal solid waste fuel were size separated using a centrifugal SPLITT fractionation cell. The ashes were separated into different size fractions and the cadmium concentration, partition and speciation in each separated fraction were then investigated in relation to their possible leaching. The fractionation was evaluated by environmental scanning electron microscopy, which also provided indications of the associations between Cd and other main elements on the particles through the use of X-ray fluorescence mapping. The total concentration of Cd in each fraction was determined by AAS analysis which showed different dependence on the ash particle size in the case of biomass or waste fuels. In addition, the speciation of Cd in each fraction, ...

2002-08-01

62

Relationship between fabrication parameters and structural characteristics of sintered lithium orthosilicate  

International Nuclear Information System (INIS)

Lithium orthosilicate (Li_4SiO_4) powder was synthesized by the solid-state reaction of lithium oxide with amorphous silica, and the effects of fabrication parameters on the structural characteristics of the product were investigated. Processing considerations such as milling media, drying technique, calcination time and temperature, pressing behavior, sintering time and temperatures, and impurity concentration were addressed. The initial powder particle size was observed to be important in achieving high sintered density, with densities as high as 98% TD achieved with a particle size of approximately 1 #mu#m. 9 refs., 6 figs.

1988-04-10

63

Luminescent lanthanide-ion doped nanoparticles as single-biomolecule labels and oxidant sensors  

Science.gov (United States)

We report on the single-particle properties of lanthanide-ion doped oxide nanoparticles. We have demonstrated that their size can be accurately determined from their luminosity. The optically determined size distribution is in very good agreement with the distribution obtained from transmission electron microscopy (TEM). We also showed that the photobleaching of these nanoparticles is related to a reduction process and that we can use it to sense in a concentration-dependent manner the presence of an oxidant like H2O2. Finally, we propose a way to perform nanoparticle-protein coupling and to determine the protein-nanoparticle ratio at the single-particle level.

2007-02-01

64

Concentrated particle-hole strength observed in 0h#omega# stretched-state excitations  

International Nuclear Information System (INIS)

The wide-angle spectra of the 134-MeV (p,n) reaction on "4"8Ca, "5"4Fe, "8"8Sr, and "2"0"8Pb are each dominated by the excitation of a single state at low excitation energy. These excitations correspond to the ''0h#omega#'' stretched states and are seen to be fragmented much less than ''1h#omega#'' stretched states in medium- and heavy-mass nuclei. The normalization factors required for comparison with distorted-wave impulse-approximation calculations are >0.50 and indicate that these are the purest particle-hole states known in these nuclei.

65

Guideline for Sampling and Analysis of Tar and Particles in Biomass Producer Gases. Version 3.3  

Energy Technology Data Exchange (ETDEWEB)

This Guideline provides a set of procedures for the measurement of organic contaminants and particles in producer gases from biomass gasifiers. The procedures are designed to cover different gasifier types (updraft or downdraft fixed bed or fluidised bed gasifiers), operating conditions (0 - 900C and 0.6-60 bars) and concentration ranges (1 mg/m{sub n}{sup 3} to 300 g/m{sub n}{sup 3}). The Guideline describes a modular sampling train, and a set of procedures, which include: planning and preparation of the sampling, sampling and post-sampling, analysis, calculations, error analysis and reporting. The modular sampling train consists of 4 modules. Module 1 is a preconditioning module for isokinetic sampling and gas cooling. Module 2 is a particle collection module including a heated filter. Module 3 is a tar collection module with a gas quench (optionally by circulating a liquid), impinger bottles and a backup adsorber. Module ...

2002-07-01

66

Further evidence for particle nucleation in clear air adjacent to marine cumulus clouds  

Science.gov (United States)

Observational evidence is presented for the nucleation of condensation nuclei (CN) in the clear air adjacent to an isolated, marine, cumulus cloud. Two separate regions of particle nucleation are identified: one located above the cloud top, and the second located downwind of the cloud near the level of the anvil outflow. The regions of high CN concentrations were located in extremely clean marine air, with unactivated aerosol surface area (excluding the nucleation mode) less than 2 sq micrometers/cu cm, air temperature -31 C, and higher relative humidities than the undisturbed environment. Vertical profile measurements downwind of the cloud showed that CN concentrations at the level of the anvil outflow (4.9 km) were 8 times greater than at any other level between the surface and 5.3 km. A conceptual model is formulated in which aerosol particles, sulfur dioxide (SO2), sulfuric acid vapor (H2SO4), ...

1994-11-01

67

Nanoparticle formation during laser ablation of metals at different pressures of surrounding noble gases  

Energy Technology Data Exchange (ETDEWEB)

We demonstrate that the nanoparticle formation during laser ablation of metals by short (of a few tens of ps) laser pulses strongly depends on the concentration of surrounding gas. While, at vacuum conditions, nanoparticle formation shows very ''sharp'' atomic force microscope images of aggregated clusters, following with clear appearance of plasmon resonance on the absorption spectra of deposited films, an addition of gas particles starts to decrease the probability of cluster formation. This process shows a threshold for both helium (33 torr) and xenon (12 torr) above which no surface plasmon resonance and correspondingly no observable nanoparticles on the deposited surfaces were detected. The destruction of nanoparticle formation was attributed to the negative influence of surrounding gas particles on ablated particles aggregation. (orig.)

2010-07-15

68

Aromatics oxidation and soot formation in flames. Progress report, August 15, 1993--June 30, 1994  

Energy Technology Data Exchange (ETDEWEB)

This project is concerned with the kinetics and mechanisms of aromatic oxidation and soot and fullerenes formation in flames. The objective of the aromatics oxidation work is to identify and measure the concentration of important intermediates and products in benzene oxidation, and to determine reaction mechanisms and kinetics properties consistent with the behavior seen in flames. The research on soot formation is concerned primarily with the particle inception stages, but the work includes study of soot structure at all stages of growth in order to obtain mechanistic information from evidence of growth steps recorded in the structure of the particles. The ultimate objective is to understand how nascent soot particles are formed from high molecular weight compounds, including the roles of planar and curved PAH and the relationship between soot and fullerenes. The objective of the proposed research on ...

1994-10-01

69

A study on mesoscale atmospheric dispersion of radioactive particles released from nuclear power plants  

Energy Technology Data Exchange (ETDEWEB)

A three dimensional sea-land breeze model and lagrangian particle dispersion model have been employed for the study on the mesoscale atmospheric dispersion of radioactive materials released from Wolsung NPPs. In this study, atmospheric dispersion simulations are carried out under two synoptic weather conditions: the geostrophic flow is a weak northerly wind (CASE 1) and a strong northerly wind (CASE 2) on a clear day in spring. The results show that atmospheric dispersion is affected by sea-land breeze and the recirculation of particles by the change of wind direction between sea breeze and land breeze plays an important role in atmospheric concentration distribution of radioactive materials.

1997-12-01

70

A new method of imaging particle tracks in solid state nuclear track detectors  

British Library Electronic Table of Contents (United Kingdom)

Summary Solid state nuclear track detectors are used to determine the concentration of a particles in the environment. The standard method for assessing exposed detectors involves 2D image analysis. However 3D imaging has the potential to provide additional information relating to angle as well as to differentiate clustered hit sequences and possibly energy of a particles but this could be time consuming. Here we describe a new method for rapid high-resolution 3D imaging of solid state nuclear track detectors. A `LEXT' OLS3100 confocal laser scanning microscope (Olympus Corporation, Tokyo, Japan) was used in confocal mode to successfully obtain 3D image data on four CR-39 plastic detectors. Three-dimensional visualization and image analysis enabled characterization of track features. This ...

2010-01-01

71

Quantifying the Reactive Uptake of OH by Organic Aerosols in aContinuous Flow Stirred Tank Reactor  

Energy Technology Data Exchange (ETDEWEB)

Here we report a new method for measuring the heterogeneous chemistry of submicron organic aerosol particles using a continuous flow stirred tank reactor. This approach is designed to quantify the real time heterogeneous kinetics, using a relative rate method, under conditions of low oxidant concentration and long reaction times that more closely mimic the real atmosphere. A general analytical expression, which couples the aerosol chemistry with the flow dynamics in the chamber is developed and applied to the heterogeneous oxidation of squalane particles by hydroxyl radicals (OH) in the presence of O2. The particle phase reaction is monitored via photoionization aerosol mass spectrometry and yields a reactive uptake coefficient of 0.51+-0.10, using OH concentrations of 1-7x108 molec cdot cm-3 and reaction times of 1.5+-3 hours. This uptake coefficient is larger than that found for ...

2009-03-01

72

Characterisation and emissions of single fuel particles under fluidized bed combustor conditions  

Energy Technology Data Exchange (ETDEWEB)

Devolatilization, char combustion and emission characteristics of different single fuel particles were studied under various fluidized bed combustor conditions, in order to develop a classification system which enables prediction of the behaviour of different fuels ranging from fixed carbon rich coals to volatile rich woods and plastics. To investigate formation reaction, the concentration of CO, CO{sub 2}, total hydrocarbons, O{sub 2}, NO and N{sub 2}O were measured continuously. Additionally, temperature histories of the particles were recorded by implanting thermocouples. Devolatilization and char combustion were analysed by an integral and differential method. The integral analysis uses global rates which were compared with the ultimate and proximate analyses and used to classify the fuels. In the differential analysis the single physical and chemical steps viz mass transfer from the bulk gas to the ...

1995-12-31

73

Phonon relaxation and internal friction in heterogeneous systems based on poly(vinyl chloride)  

British Library Electronic Table of Contents (United Kingdom)

Phonon relaxation and internal friction in kaolin-and bentonite-filled PVC composites are studied. By varying the temperature and/or content of the ultrafine mineral filler in the PVC, one can control the contribution from phonon viscosity, damping force, and the effect of viscosity into the energy dissipation of ultrasonic oscillations in the MHz frequency interval. The dynamic character of the measurements makes it possible to differentiate between relaxation phenomena in the composites and to suggest methods for their controlled changes.

2010-01-01

74

Particokinetics In Vitro: Dosimetry Considerations for In Vitro Nanoparticle Toxicity Assessments  

Energy Technology Data Exchange (ETDEWEB)

The rapid growth in the use of in vitro methods for nanoparticle toxicity assessment has proceeded with limited consideration of the unique kinetics of these materials in solution. Particles in general and nanoparticles specifically, diffuse, settle and agglomerate in cell culture media as a function of several systemic and particle factors: media density and viscosity, particle size, shape and density. Cellular dose then is also a function of these factors as they determine the rate of transport of nanoparticles to cells in culture. Here we develop and apply the principles of particokinetics and dosimetry in vitro and outline an approach for simulation of nanoparticle particokinetics in cell culture systems. We illustrate that where equal mass concentrations (?g/ml) imply equal doses for dissimilar materials, the corresponding particle number or surface area ...

2007-02-01

75

Aerosol Physical, Optical and Chemical Properties during African Dust Events at Cape San Juan (CPR)  

Science.gov (United States)

Large amounts of atmospheric dust are lifted from the North African deserts and are transported by the trade winds over the Caribbean region, especially during the summer months. How African dust particles influence the earth's radiative budget is not well understood because these particles are highly variable and their physical, optical, and chemical properties are poorly characterized, especially when they are atmospherically processed as are those that travel from Africa to the Caribbean region. Here we present results of aerosol measurements performed at Cape San Juan (CPR), a ground-based station located at the northeastern tip of the Caribbean island of Puerto Rico. We used a condensation particle counter to determine the particle number concentration, a sunphotometer (part of the AErosol RObotical NETwork, AERONET, aeronet.gsfc.nasa.gov) to determine volume size ...

2008-12-01

76

Numerical simulation of trace tests in atmosphere in Daya Bay nuclear power site  

International Nuclear Information System (INIS)

The validation of the forecast model for early emergency response to nuclear accidents is evaluated by trace tests in atmosphere in Daya Bay nuclear power site. The simulation experiment of the Daya Bay nuclear power site shows that the particle spreading image and the time-integrated concentration distribution given by plume concentration prediction model can perform the variation of pathway of the pollutant transport, as well as the effects of topography on transport and diffusion of pollutants. The simulation of five trace tests in field shows that 59.1% of ratios between predicted results and observed results are within the range of 10, and 41% of ratios are within the range of 5 approximately. (authors)

2005-09-01

77

Fractal dimensionality of polymer networks formed by photopolymerization in a liquid crystal medium  

Energy Technology Data Exchange (ETDEWEB)

Fractal dimensional analysis was employed to obtain a quantitative measure of the morphology of polymer networks formed by UV irradiation induced polymerization of photo-reactive mesogenic monomers dissolved in a liquid crystal host medium. The fractal dimensions obtained, may be interpreted by polymer network growth following a percolation-like model for monomer concentrations well below the solubility limit. On passing the solubility limit, the polymerization process changes from a (radical chain) solution polymerization to a dispersion polymerization, with fractal dimensions decreasing and suggesting a cluster-cluster aggregation process for monomer concentrations above the solubility limit, similar to the aggregation of colloidal particles.

2002-10-21

78

Radon concentration measurements in the desert caves of Saudi Arabia  

Energy Technology Data Exchange (ETDEWEB)

Beneath the harsh deserts of Saudi Arabia lie dark chambers and complex mazes filled with strange shapes and wondrous beauty. Radon concentration measurements have been carried out in the desert caves of Al-Somman Plateau in the Eastern Province of Saudi Arabia. Passive radon dosimeters, based on alpha particle etch track detectors with an inlet filter, were used in this study. A total of 59 dosimeters were placed in five caves for a period of six months. Out of 59 dosimeters, 37 could be collected for analysis. Measurements showed significant variations in radon concentrations in caves depending upon their natural ventilation. The results of the study show that the average radon concentration in the different caves ranges from 74 up to 451Bqm{sup -3}. The average radon concentration in four of the caves was low in the range 74-114Bqm{sup -3}. However, one cave showed an average ...

2005-11-15

79

Radon concentration measurements in the desert caves of Saudi Arabia  

International Nuclear Information System (INIS)

Beneath the harsh deserts of Saudi Arabia lie dark chambers and complex mazes filled with strange shapes and wondrous beauty. Radon concentration measurements have been carried out in the desert caves of Al-Somman Plateau in the Eastern Province of Saudi Arabia. Passive radon dosimeters, based on alpha particle etch track detectors with an inlet filter, were used in this study. A total of 59 dosimeters were placed in five caves for a period of six months. Out of 59 dosimeters, 37 could be collected for analysis. Measurements showed significant variations in radon concentrations in caves depending upon their natural ventilation. The results of the study show that the average radon concentration in the different caves ranges from 74 up to 451Bqm"-"3. The average radon concentration in four of the caves was low in the range 74-114Bqm"-"3. However, one cave showed an average radon ...

2005-11-01

80

Quantative autoradiography of inhaled "2"3"9PuO_2 in the lung  

International Nuclear Information System (INIS)

PuO_2 particles behaved similarly in the lungs of rat and hamster. The relative concentrations of PuO_2 up to 1-yr postexposure were 1.0 for lung parenchyma, 1.3 for subpleural areas, 0.5 for peribronchiolar regions and 0.2 for perivascular regions in the lungs.

1977-05-01

81

Desulphurization of hot reducing gases in the entrained bed reactor  

Energy Technology Data Exchange (ETDEWEB)

Using an experimental pilot plant, designed and built for the tests, the influence of the following parameters was determined: desulphurization of the test gas, temperature, residence time in the reactor tube, concentration of the hydrogen sulphide and desulphurization agent, size of the particles which comprise the agent and composition of the gas. Allowance was made for the effect of calcination and carbonisation. Desulphurization was carried out with limestone on a gaseous mixture of CO and H/sub 2/. A mathematical description of the test findings and yield is presented. 8 refs.

1986-08-01

82

Concentration and Preservation of Very Low Abundance Biomarkers in Urine, such as Human Growth Hormone (hGH), by Cibacron Blue F3G-A Loaded Hydrogel Particles  

UK PubMed Central (United Kingdom)

Urine is a potential source of diagnostic biomarkers for detection of diseases, and is a very attractive means of non-invasive biospecimen collection. Nonetheless, proteomic measurement in urine...Full Text Available

2008-12-01

83

Indoor radon concentration measurements in some Spanish houses and dwellings with plastic nuclear track detectors  

Energy Technology Data Exchange (ETDEWEB)

A passive dosemeter, based on a Makrofol ED track detector covered with aluminized Mylar, enclosed in diffusion chamber, has been used for radon concentration studies. Detectors have been irradiated, using a {sup 241}Am source, at different energies and fluences in order to obtain the electrochemical etching conditions that allow the optimum registration of alpha particles having energies over 3 MeV. Thirty dosemeters have been sent to the UK National Radiation Protection Board (NRPB) Radon Environmental Chamber for calibration. The sensitivity of the dosemeter has been calculated. Several dosemeters have also been exposed in houses and dwellings in the Barcelona and Madrid areas for monitoring. Values for radon concentration in the areas under study are presented. (author).

1991-01-01

84

Indoor radon concentration measurements in some Spanish houses and dwellings with plastic nuclear track detectors  

International Nuclear Information System (INIS)

A passive dosemeter, based on a Makrofol ED track detector covered with aluminized Mylar, enclosed in diffusion chamber, has been used for radon concentration studies. Detectors have been irradiated, using a "2"4"1Am source, at different energies and fluences in order to obtain the electrochemical etching conditions that allow the optimum registration of alpha particles having energies over 3 MeV. Thirty dosemeters have been sent to the UK National Radiation Protection Board (NRPB) Radon Environmental Chamber for calibration. The sensitivity of the dosemeter has been calculated. Several dosemeters have also been exposed in houses and dwellings in the Barcelona and Madrid areas for monitoring. Values for radon concentration in the areas under study are presented. (author).

85

Preparation of AgBr Nanoparticles in Microemulsions Via Reaction of AgNO{sub 3} with CTAB Counterion  

Energy Technology Data Exchange (ETDEWEB)

Nanoparticles of AgBr were prepared by precipitating AgBr in the water pools of microemulsions consisting of CTAB, n-butanol, isooctane and water. An aqueous solution of AgNO{sub 3} added to the microemulsion was the source of Ag{sup +} ions. The formation of AgBr nanoparticles in microemulsions through direct reaction with the surfactant counterion is a novel approach aimed at decreasing the role of intermicellar nucleation on nanoparticle formation for rapid reactions. The availability of the surfactant counterion in every reverse micelle and the rapidity of the reaction with the counterion trigger nucleation within individual reverse micelles. The effect of the following variables on the particle size and size distribution was investigated: the surfactant and cosurfactant concentrations, moles of AgNO{sub 3} added, and water to surfactant mole ratio, R. High concentration of the surfactant or cosurfactant, or high water ...

2007-10-15

86

Formation of colloidal silver nanoparticles stabilized by Na+-poly(gamma-glutamic acid)-silver nitrate complex via chemical reduction process.  

Science.gov (United States)

Macromolecular and polyanionic Na(+)-poly(gamma-glutamic acid) (PGA) silver nitrate complex acted as both a metal ion provider and a particle protector to fabricate nanosized silver colloids under chemical reduction by dextrose. The formation and size of particles have been characterized from transmission electron microscopy (TEM), dynamic light scattering analysis and UV-vis spectrophotometer. The results showed that the average particle size was 17.2+/-3.4 to 37.3+/-5.5 nm, apparently depending on the complex concentration. It was found that the rate constant and conversion of silver nanoparticles were proportional to the concentration of PGA. The growth mechanism of nanosized silver colloid was fully discussed. In addition, the in vitro cytotoxicity evaluated by L929 fibroblasts proliferation and antibacterial activity against Gram-positive strain (methicillin-resistant S. aureus ...

2007-05-18

87

Aggregation of silica nanoparticles directed by adsorption of lysozyme.  

Science.gov (United States)

The interaction of the globular protein lysozyme with silica nanoparticles of diameter 20 nm was studied in a pH range between the isoelectric points (IEPs) of silica and the protein (pH 3-11). The adsorption affinity and capacity of lysozyme on the silica particles is increasing progressively with pH, and the adsorbed protein induces bridging aggregation of the silica particles. Structural properties of the aggregates were studied as a function of pH at a fixed protein-to-silica concentration ratio which corresponds to a surface concentration of protein well below a complete monolayer in the complete-binding regime at pH > 6. Sedimentation studies indicate the presence of compact aggregates at pH 4-6 and a loose flocculated network at pH 7-9, followed by a sharp decrease of aggregate size near the IEP of lysozyme. The structure of the bridged silica aggregates was studied by cryo-transmission ...

2011-07-20

88

Simulation of sludge deposit onto a 900 MW steam generator tubesheet with the 3D code GENEPI  

Energy Technology Data Exchange (ETDEWEB)

Heat transfer processes use fluids which are generally not pure and can react with transfer surfaces. These surfaces are subject to deposits which can be sediments harmful to heat transfer and to integrity of materials. For nuclear plant steam generators, sludge build-up accelerates secondary side corrosion by concentrating chemical species. A major safety problem involved with such a corrosion is the growing of circumferential cracks which are very difficult to detect and size with eddy current probes. With a view to understand and control this problem, it is necessary to develop a mathematical model for the prediction of sludge behavior in PWR steam generators. Based on fundamental principles, this work intends to use different models available in literature for the prediction of the phenomenon leading to the accumulation of sludge particles at the bottom (the tubesheet) of a PWR. For that, a three-dimensional simulation of magnetite ...

1998-07-01

89

Particle Detection with drift Chambers  

CERN Document Server

Particle Detection with drift Chambers

2008-01-01

90

The effects of ventilation, filtration, and outdoor air on the composition of indoor air at a telephone office building  

Energy Technology Data Exchange (ETDEWEB)

Sensors installed at a telephone office building in Neenah, WI, continuously monitor 24 parameters related to the operation of the building's heating, ventilating, and air conditioning (HVAC) system. This data is stored in a dedicated minicomputer and can be retrieved, in various formats, for subsequent analyses. For more than a year, we have measured indoor and outdoor concentrations of both fine and coarse airborne particles, their chemical constituents, and volatile organic compounds at this same location. Using this data, we have examined the composition of the indoor air as it correlates to the composition of the outdoor air and the various HVAC operating parameters. The steady-state indoor concentrations of the particles, particulate constituents, and organic vapors can be explained in the context of a mass balance model. This model can also be used to calculate the rate at which selected ...

1989-01-01

91

Silver nanoparticles directly formed on natural macroporous matrix and their anti-microbial activities  

Energy Technology Data Exchange (ETDEWEB)

In this study, silver nanoparticles were formed on a natural macroporous matrix, the stem of rice-paper plant, by reducing Ag{sup +} in aqueous solution through in situ processing without using any other stabilizers. The pores of the matrix, with their size of about 100 {mu}m, were thought to act as reaction compartments for the nucleation and growth of silver nanoparticles, and the control of nucleation of silver crystal during the reduction reaction was found to be important to the successful formation of nanosized silver particles onto the matrix. The diameter and amount of resultant silver particles can be controlled by changing the reaction conditions. Under optimized conditions, the content of silver particles in the matrix can reach as high as 1.8 wt% with the particle diameters being kept below 100 nm. The anti-microbial activities in terms of minimum inhibitory ...

2007-02-07

92

Pot-type catalyst carrier and manufacturing method  

Energy Technology Data Exchange (ETDEWEB)

This invention relates with a pot-type catalyst carrier which excels as a catalyst carrier when such heavy oils as ordinary pressure distillation residue, oil sand oil, and shale oil are decomposed or treated by hydrogenation. The conventional pot-type carrier is produced by dropping a small drop of a slurry (containing a catalyst component) onto a particle bed and drying it. But the demerit is a large particle size and less catalyst activity or strength. In this invention, a mixture of such carrier components as allophane, red mud, bauxite and latellite, etc.. 60 - 80 weight parts. and a binder 20 - 40 weight parts is added with water to form a slurry of 10 - 30 weight% solid concentration. Slurry is wet-crushed to make the average particle size 0.6 - 2.0 micron, then spray-dried and burned to obtain a pot-type catalyst carrier with average particle size 30 - 200 micron and ...

1988-02-25

93

Residence time probability analysis of sulfur concentrations at Grand Canyon National Park  

Energy Technology Data Exchange (ETDEWEB)

A statistical method is developed to determine the locations of major pollutant sources affecting a distant downwind receptor, provided that air trajectories can be estimated. Probability density functions are estimated which indicate the overall residence time of air parcels over a given geographic region as they travel toward a receptor and residence time for the case of high pollutant concentrations at the receptor. These functions are used to estimate a conditional probability function which indicates the potential for a source region to contribute to high air pollution concentrations. Finally, a source contribution function is formulated to indicate the relative contribution of different source regions to high concentrations at the receptor. The method is tested using data collected at Grand Canyon National Park in 1980. The dominant pathway for air masses arriving at Grand Canyon during this period was southern ...

1985-01-01

94

Solution and particle effects on the biosorption of heavy metals by seaweed biomass  

Energy Technology Data Exchange (ETDEWEB)

Biosorption of cadmium (Cd), cobalt (Co), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) by six fractions of particle sizes, ranging from 0.063 to 1.4 mm of dry marine algal biomass of Sargassum fluitans and Ascophyllum nodosum, is examined. Equilibrium metal uptake by larger particles was higher than that by smaller particles in the order of Pb > Cd > Cu > Co > Zn > Ni for both biomass types, with S. fluitans sorbing slightly more than A. nodosum. Uptakes of metals ranged from the highest, q{sub max} = 369 mg Pb/g (particle size 0.84-1.00 mm), to the low Zn and Ni uptakes, q{sub max} = 77 mg/g (size 0.84-1.00 mm) for S. fluitans. A. nodosum adsorbed metals in the range from q{sub max} = 287 mg Pg/g (particle size 0.84-1.00 mm) to q{sub max} = 73 mg Zn/g (particle size 0.84-1.00mm). Harder stipe fractions of S. fluitans demonstrated generally ...

1996-12-01

95

Influence of process changes on PCDD/Fs produced in an iron ore sintering plant  

Energy Technology Data Exchange (ETDEWEB)

This study investigated the influence of different charge typologies and additives on the PCDD/Fs amount produced and on the congener profiles in an iron ore sintering plant. Many tests were carried out combining different typologies of charge (iron materials) and solid fuel ('coke breeze' or 'anthracite') with or without the use of urea. The PCDD/Fs produced ranged from 1.2 to 22.7 {mu} g I-TEQ/ton of agglomerate, whereas the PCDD/Fs released to the ambient air ranged from 0.10 to 1.92 ng I-TEQ/Nm{sup 3} because of cleaning in an electrostatic precipitator (ESP) and a Wetfine scrubber (WS). A more homogeneous charge with a higher amount of fine particles charge appeared to produce a lower PCDD/Fs concentration due to a better combustion but this hypothesis needs further investigations on charges having different dimension particles. Only a synergitic action of urea and anthracite was ...

2009-01-15

96

Inhalation Exposure Input Parameters for the Biosphere Model  

Energy Technology Data Exchange (ETDEWEB)

This analysis is one of 10 reports that support the Environmental Radiation Model for Yucca Mountain, Nevada (ERMYN) biosphere model. The ''Biosphere Model Report'' (BSC 2004 [DIRS 169460]) describes in detail the conceptual model as well as the mathematical model and its input parameters. This report documents development of input parameters for the biosphere model that are related to atmospheric mass loading and supports the use of the model to develop biosphere dose conversion factors (BDCFs). The biosphere model is one of a series of process models supporting the total system performance assessment (TSPA) for a Yucca Mountain repository. Inhalation Exposure Input Parameters for the Biosphere Model is one of five reports that develop input parameters for the biosphere model. A graphical representation of the documentation hierarchy for the ERMYN is presented in Figure 1-1. This figure shows the interrelationships among the products (i.e., analysis ...

2004-09-10

97

Aerosol composition, chemistry, and source characterization during the 2008 VOCALS Experiment  

Energy Technology Data Exchange (ETDEWEB)

Chemical composition of fine aerosol particles over the northern Chilean coastal waters was determined onboard the U.S. DOE G-1 aircraft during the VOCALS (VAMOS Ocean-Cloud-Atmosphere-Land Study) field campaign between October 16 and November 15, 2008. SO42-, NO3-, NH4+, and total organics (Org) were determined using an Aerodyne Aerosol Mass Spectrometer, and SO42-, NO3-, NH4+, Na+, Cl-, CH3SO3-, Mg2+, Ca2+, and K+ were determined using a particle-into-liquid sampler-ion chromatography technique. The results show the marine boundary layer (MBL) aerosol mass was dominated by non- sea-salt SO42- followed by Na+, Cl-, Org, NO3-, and NH4+, in decreasing importance; CH3SO3-, Ca2+, and K+ rarely exceeded their respective limits of detection. The SO42- aerosols were strongly acidic as the equivalent NH4+ to SO42- ratio was only ~0.25 on average. NaCl particles, presumably of sea-salt origin, showed chloride deficits but retained ...

2010-03-15

98

Evolution of defect structures during cold rolling of ultrafine-grained Cu and Cu-Zn alloys: Influence of stacking fault energy  

Energy Technology Data Exchange (ETDEWEB)

Samples of pure Cu, bronze (Cu-10 wt.% Zn) and brass (Cu-30 wt.% Zn) with stacking fault energies (SFE) of 78, 35, and 14 mJ/m{sup 2}, respectively, were processed by high-pressure torsion (HPT) and by a combination of HPT followed by cold-rolling (CR). X-ray diffraction measurements indicate that a decrease in SFE leads both to a decrease in crystallite size and to increases in microstrain, dislocation and twin densities for the HPT and HPT + CR processed ultrafine-grained (UFG) samples. Compared with processing by HPT, subsequent processing by CR refines the crystallite size of all samples, increases the twin densities of UFG bronze and brass, and increases the dislocation density in UFG bronze. It also decreases the dislocation density in UFG brass and leads to an unchanged dislocation density in UFG copper. The results suggest there may be an optimum stacking fault energy for dislocation accumulation in UFG Cu-Zn alloys and this has important implications in ...

2008-02-15

99

Effect of V and W addition on the high temperature strength properties of 12%Cr-15%Mn austenitic steels. 12%Cr-15%Mn austenite ko no ondo kyodo ni oyobosu V to W tenka no eikyo  

Energy Technology Data Exchange (ETDEWEB)

Experimental discussions were given on effect of V and W addition on the high temperature strength properties of 12% Cr-15% Mn austenite steels. The test samples were added with W at 0% to 3.5% and V at 0% to 0.5% in addition to C and N, and were given aging treatment or solution treatment. This paper describes the following matters on the results of high-temperature strength measurements and structural observation: A remarkable trend was observed that M23 Cb type carbides precipitate in the aging treatment, wherein aging hardening appears prominently which is attributable to ultra-fine deposits of vanadium nitride (VN) in the V-added material; the V addition is very effective in increasing the high-temperature tensile strength and creep fracture strength as compared with single W addition, wherein the said carbides that accelerate the precipitation as a result of the V addition make a large contribution, in addition to that by ultra-fine VN ...

1992-11-01

100

Pseudospectral method calculation of tidal field and particle random walk simulation of radionuclides in Daya Bay  

International Nuclear Information System (INIS)

Presented here is the calculation results of tidal field of Daya Bay by using pseudospectral method. According to the calculation results about the tidal field and measured value of wind in Daya Bay area, the diffusion of radionuclide from Daya Bay Nuclear Power Plant is simulated by using particle random walk model. The simulation results about the relative concentration distribution of the radionuclides and the trajectory of the distribution centrode are obtained, taking account of tidal current, wind and turbulent current. These results can provide information not only for the reasonable discharge of the radionuclides from Daya Bay Nuclear Power Plant, but also for understanding the potential effect on environment due to the normal operation of Daya Bay Nuclear Power Plant. (authors)

2009-11-01

101

Nanowires of silicon carbide and 3D SiC/C nanocomposites with inverse opal structure  

International Nuclear Information System (INIS)

Synthesis, morphology, structural and optical characteristics of SiC NWs and SiC/C nanocomposites with an inverse opal lattice have been investigated. The samples were prepared by carbothermal reduction of silica (SiC NWs) and by thermo-chemical treatment of opal matrices (SiC/C) filled with carbon compounds which was followed by silicon dioxide dissolution. It was shown that the nucleation of SiC NWs occurs at the surface of carbon fibers felt. It was observed three preferred growth direction of the NWs: [111], [110] and [112]. HRTEM studies revealed the mechanism of the wires growth direction change. SiC/C- HRTEM revealed in the structure of the composites, except for silicon carbide, graphite and amorphous carbon, spherical carbon particles containing concentric graphite shells (onion-like particles).

2011-07-07

102

Microgel/clay nanohybrids as responsive scavenger systems  

British Library Electronic Table of Contents (United Kingdom)

Microgel-clay composite particles were prepared by one-step surfactant-free precipitation polymerization. Laponite nanoparticles present in the reaction mixture become encapsulated during the microgel formation process. Microgel-clay composites based on poly(N-vinylcaprolactam-co-acetoacetoxyethyl methacrylate) containing different amount of incorporated clay nanoparticles were synthesized. The clay content was varied from 2 wt% to 18 wt%. The extremely high incorporation efficiency of the clay nanoparticles into microgels was detected. The size of the hybrid microgels was decreased from 700 nm to 100 nm by increase of the clay concentration in the reaction mixture. Obtained hybrid microgels exhibit negative surface charge and excellent colloidal stability. Microgel-clay composite particle...

2010-01-01

103

Kinetics of a reactive dye adsorption onto dolomitic sorbents.  

Science.gov (United States)

A novel wastewater treatment technique has been investigated, for reactive dye removal, in batch kinetic systems. These experimental studies have indicated that charred dolomite has the potential to act as an adsorbent for the removal of Brilliant Red reactive dye from aqueous solution. The effect of initial dye concentration, adsorbent mass:liquid volume ratio, and agitation speed on dye removal have been determined with the experimental data mathematically described using empirical external mass transfer and intra-particle diffusion models. The experimental data show conformity with an adsorption process, with the removal rate heavily dependent on both external mass transfer and intra-particle diffusion. PMID:12691893

2003-05-01

104

Frequency distribution, isotopic composition and physical characterization of plutonium-bearing particles from the Fig-Quince zone on Runit Island, Enewetak Atoll  

British Library Electronic Table of Contents (United Kingdom)

Runit Island on Enewetak Atoll was very heavily impacted by the U.S. nuclear testing campaign in the northern Marshall Islands (1946?58). The primary source of contamination on Runit Island was the 1958 Quince safety test where a large quantity of device plutonium (Pu) was scattered over the area near the GZ. A second low-yield device was detonated on the same site 10?days later, further disturbing the soil and leaving behind a very heterogeneous pattern of contamination including milligram-size particles of plutonium. A limited cleanup of the Fig-Quince zone was carried out in 1979. During this period, the effectiveness of the cleanup operations was primarily evaluated on the basis of bulk soil concentration data with little consideration given to the heterogeneity and long-term material-...

2009-01-01

105

Feeding ecology of mesopelagic zooplankton of the subtropical and subarctic North Pacific Ocean determined with fatty acid biomarkers  

British Library Electronic Table of Contents (United Kingdom)

Mesopelagic zooplankton may meet their nutritional and metabolic requirements in a number of ways including consumption of sinking particles, carnivory, and vertical migration. How these feeding modes change with depth or location, however, is poorly known. We analyzed fatty acid (FA) profiles to characterize zooplankton diet and large particle (>51?m) composition in the mesopelagic zone (base of euphotic zone ?1000m) at two contrasting time-series sites in the subarctic (station K2) and subtropical (station ALOHA) Pacific Ocean. Total FA concentration was 15.5 times higher in zooplankton tissue at K2, largely due to FA storage by seasonal vertical migrators such as Neocalanus and Eucalanus. FA biomarkers specific to herbivory implied a higher plant-derived food sou...

2010-01-01

106

Aerosol characteristics over coastal regions of the Arabian Sea  

Energy Technology Data Exchange (ETDEWEB)

From aerosol spectral optical depths ({tau}{sub p{lambda}}) at wavelengths in the range 380 to 1025 nm estimated at different locations in the near and far coastal regions of the Arabian sea adjoining the western coast of central India, the spatial and spectral characteristics of coastal aerosols and the effect of the proximity to the (urban) continent are investigated. The Aangstroem parameters are deduced from {tau}{sub p{lambda}} values. A significant increase, both in aerosol optical depths at shorter (visible) wavelengths ({lambda} {<=} 600 nm) and the Aangstroem wavelength exponent are observed in the near coastal regions, suggesting an increase in the (relative) concentration of sub micron particles, apparently of anthropogenic origin. The Aangstroem turbidity coefficient remains nearly steady spatially, indicating a (spatially) uniform loading of large particles. 31 refs, 10 figs, 1 tab

1997-09-01

107

Adsorption rate of phenol from aqueous solution onto organobentonite: Surface diffusion and kinetic models.  

Science.gov (United States)

The concentration decay curves for the adsorption of phenol on organobentonite were obtained in an agitated tank batch adsorber. The experimental adsorption rate data were interpreted with diffusional models as well as first-order, second-order and Langmuir kinetic models. The surface diffusion model adjusted the data quite well, revealing that the overall rate of adsorption was controlled by surface diffusion. Furthermore, the surface diffusion coefficient increased raising the mass of phenol adsorbed at equilibrium and was independent of the particle diameter in the range 0.042-0.0126cm. It was demonstrated that the overall rate of adsorption was essentially not affected by the external mass transfer. The second-order and the Langmuir kinetic models fitted the experimental data quite well; however, the kinetic constants of both models varied without any physical meaning while increasing the particle size and the mass of ...

2011-08-22

108

R D for the storage, transport, and handling of coal-based fuels  

Energy Technology Data Exchange (ETDEWEB)

The product of several advanced physical coal cleaning processes is a dry, ultrafine coal (DUC), in the order of 10 microns mean mass diameter. To utilize this fuel commercially, cost-effective, environmentally safe systems must be provided for the storage, transport, and handling of this finely divided form of fuel. The objective of the project described herein is the development of total logistics systems for DUC, including experimental verification of key features. The systems to be developed will provide for safe, economic, and environmentally protective storage and delivery of DUC for residential, commercial, and industrial uses. 20 figs.

1991-01-01

109

Studies on formation and structures of ultrafine Cu precipitates in Fe-Cu model alloys for reactor pressure vessel steels using positron quantum dot confinement in the precipitates by their positron affinity. JAERI's nuclear research promotion program, H11-034 (Contract research)  

Energy Technology Data Exchange (ETDEWEB)

Positron annihilation experiments on Fe-Cu model dilute alloys of nuclear reactor pressure vessel (RPV) steels have been performed after neutron irradiation in JMTR. Nanovoids whose inner surfaces were covered by Cu atoms were clearly observed. The nanovoids transformed to ultrafine Cu precipitates by dissociating their vacancies after annealing at around 400degC. The nanovoids and the ultrafine Cu precipitates are strongly suggested to be responsible for irradiation-induced embrittlement of RPV steels. Effects of Ni, Mn and P addition on the nanovoid and Cu precipitate formations were also studied. The nanovoid formation was enhanced by Ni and P, but suppressed by Mn. The Cu precipitates after annealing around 400degC were almost free from these doping elements and hence were pure Cu in the chemical composition. Furthermore the Fermi surface of the 'embedded' Cu precipitates with a body centered cubic crystal structure was ...

2003-03-01

110

Ozone synthisis in charged particle induced noble gas-oxygen and noble gas-oxygen-sulfur hexafluoride discharges  

International Nuclear Information System (INIS)

A series of experimental measurements of ozone concentration produced by irradiation of noble gas (He, Ne, and Ar)-O_2 and noble gas-O_2- SF_6 mixtures with energetic (MeV) helium and lithium ions are reported. Continuous irradiations at dose rates of 10"1"5-10"1"7 eV cm"-"3 S"-"1 for a few hundred milliseconds were used. The resulting ozone concentration was found to be nonlinear with dose rate for a given irradiation time. This nonlinearity was effectively reduced by an increase in noble gas pressure. Few mole percent addition of SF_6 generally resulted in an increase in the ozone concentration. This increase was highest for lower noble gas pressures and longer irradiation times. Further SF_6 addition, however, caused a reduction in the ozone concentration. Results are explained by considering the relevant reactions responsible for ozone production and loss.

111

Paul Scherrer Institut Scientific Report 2001. Volume V: General Energy  

Energy Technology Data Exchange (ETDEWEB)

Major advances in 'Energy and Materials Cycles' have been achieved in the removal of heavy metals from the solid residues of municipal waste incineration. It has been conclusively shown that the oxidation/reduction conditions established during the thermal treatment of filter ash have a decisive influence on the evaporation of groups of heavy metals. With respect to biomass gasification, studies have been carried out with respect to the best way of extracting pure hydrogen from the low calorific value gas that is typically obtained from a biomass gasifier. The overarching goal of the laboratory 'High Temperature Solar Technology' is the use of solar energy for the production of solar fuels, or for the reduction of CO{sub 2} emissions in large scale industrial processes that are conventionally carried out with the use of fossil fuels. In a short-term project targeted at the solar production of lime, highly encouraging results (98% degree of ...

2002-03-01

112

Studies of aerosol formation in power plant plumes - II. Secondary aerosol formation in the Navajo generating station plume  

Energy Technology Data Exchange (ETDEWEB)

Aerosol and gas measurements were made with the University of Minnesota Mobile Laboratory (UMML) during the VISTTA programme near Page, Arizona. The UMML was stationed on Zilnez Mesa approx. 65 km east of the Navajo coal-fired power plant. Measurements were made both in and out of the power plant plume and were made during the day and night. Measured parameters included aerosol size distributions, Aitken nuclei count, ozone and sulphur dioxide concentrations, the aerosol light scattering coefficient, and meteorological parameters including ultraviolet radiation intensity. Concentrations of NO and NO/SUB/x were occasionally measured. Data show clear evidence of gas-to-particle conversion in the plume with aerosol volume being added in the 0.01 MUm - 0.32 MUm dia. range and new particles being formed. The observed excess aerosol volume depends strongly upon the SO/SUB/2 concentrations ...

1981-01-01

113

Structural, optical, photocatalytic and antibacterial activity of zinc oxide and manganese doped zinc oxide nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

Polycrystalline ZnO doped with Mn (5 and 10at%) was prepared by the co-precipitation method. The effect of Mn doping on the photocatalytic, antibacterial activities and the influence of doping concentration on structural, optical properties of nanoparticles were studied. Structural and optical properties of the particles elucidated that the Mn2+ ions have substituted the Zn2+ ions without changing the Wurtzite structure of ZnO. The optical spectra showed a blue shift in the absorbance spectrum with increasing dopant concentration. The photocatalytic activities of ZnO powders were evaluated by measuring the degradation of methylene blue (MB) in water under the UV region. It was found that undoped ZnO bleaches MB much faster than manganese doped ZnO upon its exposure to the U...

2010-01-01

114

Urea: An important piece of Water Soluble Organic Nitrogen (WSON) over the Eastern Mediterranean  

British Library Electronic Table of Contents (United Kingdom)

The role of atmospheric urea on the biogeochemical cycle of Water Soluble Organic Nitrogen (WSON) in the Eastern Mediterranean was assessed by collecting and analyzing wet and dry deposition samples and size segregated aerosols during a one year period (2006). In rain water volume weighted mean (VWM) concentration of urea was found equal to 5.5mM. In atmospheric particles the average concentration of urea in coarse and fine mode was 0.9+/-1.9nmolNm^-^3 (median 0.0nmolNm^-^3) and 2.2+/-3.0nmolNm^-^3 (median 1.1nmolNm^-^3), respectively. The percentage contribution of urea to WSON fraction was 0% and 20% in coarse and fine particles respectively. On an annual basis 0.81mmolm^-^2 and 1.78mmolm^-^2 of urea were deposited via wet and dry deposition, contributing to WSON by 10% and 11% respectiv...

2011-01-01

115

The peak to background method in quantitative ion microprobe analysis of thick biological specimens  

Energy Technology Data Exchange (ETDEWEB)

The use of the ratio of the characteristic intensity to the continuum background intensity (P/B ratio) of the X-ray spectrum for a quantitative ion microprobe (IMP) or PIXE (particle induced X-ray emission) analysis of thin biological specimens was proposed previously. The IMP analysis of thick biological specimens is also of considerable practical use. In this paper, the possibility of using the P/B ratio to quantify minor elements in thick biological specimens is investigated. The epoxy resin based standards with gradual concentrations of KCNS up to 0.6 mol/kg and NBS bovine liver were analyzed by a 27 MeV {alpha} particle microprobe. The measured peak to background ratios (between 4.4 to 5.7 keV) agreed well with the theoretical calculations. The calculations showed that the concentration dependence of the P/B ratios was determined mainly by the absorption of X-rays in specimens. The results indicate ...

1991-05-01

116

Identifying primary stressors impacting macroinvertebrates in the Salinas River (California, USA): Relative effects of pesticides and suspended particles  

International Nuclear Information System (INIS)

Laboratory dose-response experiments with organophosphate and pyrethroid pesticides, and dose-response experiments with increasing particle loads were used to determine which of these stressors were likely responsible for the toxicity and macroinvertebrate impacts previously observed in the Salinas River. Experiments were conducted with the amphipod Hyalella azteca, the baetid mayfly Procloeon sp., and the midge Chironomus dilutus (Shobanov, formerly Chironomus tentans). The results indicate the primary stressor impacting H. azteca was pesticides, including chlorpyrifos and permethrin. The mayfly Procloeon sp. was sensitive to chlorpyrifos and permethrin within the range of concentrations of these pesticides measured in the river. Chironomus dilutus were sensitive to chlorpyrifos within the ranges of concentrations measured in the river. None of the species tested were affected by turbidity as high as 1000 NTUs. The current ...

2006-06-01

117

Effect of silver addition on the formation and deposition of titania nanoparticles produced by liquid flame spray  

Energy Technology Data Exchange (ETDEWEB)

In this study, liquid flame spray (LFS) was used to produce titania, silver and silver-titania deposits of nanoparticles. Titanium(IV)ethoxide (TEOT) and silver nitrate in ethanol solutions were used as precursors and sprayed into turbulent hydrogen-oxygen flame. Production rates of 1.5-40 mg/min of titania were used with silver additions of 1, 2, 4, and 8 wt% compared to titania. Nanoparticle deposits were collected by thermophoretic sampling at six different axial distances from the flame torch head: 3, 5, 10, 12, 15, and 20 cm, of which the all but the last one occurred inside the flame. The deposit samples were analysed by TEM and SAED analysis. The powder samples of the particles were also collected by electric precipitator to XPS and specific surface area analysis. Particle size and effective density after the flame in the aerosol were analysed with SMPS and ELPI. The results from the previous studies i.e. controlling the ...

2007-08-15

118

[Reactivity of the limestone in wet flue gas desulfurization].  

Science.gov (United States)

On the basis of the analysis of chemical components of the natural limestones from different deposits in China, the pore structures of the typical limestones, with the different CaCO3 content, were examined. The reactivity of the limestones was investigated by sulfuric acid titration and gas-liquid absorption methods. The research results showed that the specific surface area of the natural limestones studied in this work was about 1.8 m2/g. It was seen that the pH of the limestone slurry rapidly decreased and then back up when the sulfuric acid was added. The higher the CaCO3 content was, or the smaller the particle size was, the larger the pH back-up rate was, and similarly the faster the SO2 concentration of the reactor outlet increased. The Reactivity of the limestone obtained by the sulfuric acid titration had the same features as that obtained by the gas liquid absorption. Compared with the specific surface area, the CaCO3 content had ...

2005-11-01

119

The influence of interfacial structure on the mechanical properties of liquid-phase-sintered aluminium-ceramic composites. [Al-Cu-Mg-Si/SiC  

Energy Technology Data Exchange (ETDEWEB)

The effect of interfacial structure on the mechanical properties of aluminum-ceramic composite materials fabricated by liquid phase sintering was studied. The composites were based on two matrix alloys (powder metallurgy alloys 201 and 601) reinforced with either Al{sub 2}O{sub 3} or SiC particulate. Characterization of the interfacial regions demonstrated that the SiC-matrix interfaces were faceted whereas the Al{sub 2}O{sub 3}-matrix interfaces had an incomplete layer of a silicon-rich amorphous phase. Preferential attack of the particles during sintering is believed to cause the crystallographic facets to form on SiC. Locally high silicon concentrations near Al{sub 2}O{sub 3} particles led to the formation of a glassy phase from the reduction of Al{sub 2}O{sub 3}. The difference in interfacial structure resulted in a higher particle-matrix bond strength and therefore improved composite mechanical ...

1990-10-01

120

Sediment trap fluxes and benthic recycling of organic carbon, polycyclic aromatic hydrocarbons, and polychlorobiphenyl congeners in Lake Superior  

Energy Technology Data Exchange (ETDEWEB)

Sediment trap fluxes of solids, organic carbon, polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs) were measured in Lake Superior in 1984 and 1985. Mass fluxes from surface waters ranged from 0.14 to 1.1 g/m{sup 2}{center dot}day and increased near the lake floor due to resuspension of surficial sediment and horizontal transport in the benthic nepheloid layer. Organic matter fluxes from surface water ranged from 60 to 90 mg of C/m{sup 2}{center dot}day, with {approximately}5% of organic carbon settling from surface waters accumulating in bottom sediments. Concentrations of PCBs and PAHs are enriched 10-100 times on settling particles relative to those on suspended particles. Resultant settling fluxes are 10-100 times greater for several PCB and PAH compounds than net accumulation rates in bottom sediments, indicating the effective and rapid recycling in the benthic region. Biological packaging of ...

1991-03-01

121

Quantitative assessment of cancer risk from exposure to diesel engine emissions  

Energy Technology Data Exchange (ETDEWEB)

Quantitative estimates of lung cancer risk from exposure to diesel engine emissions were developed using data from three chronic bioassays with Fischer 344 rats. Human target organ dose was estimated with the aid of a comprehensive dosimetry model. This model accounted for rat-human differences in deposition efficiency, normal particle clearance rates, transport of particles to lung-associated lymph nodes, respiration rates, and lung surface area, as well as high-dose inhibition of particle clearance. Recent evidence indicates that the inert carbon core of the diesel particulate matter is likely to be the primary source of carcinogenicity. The epithelial tissue lining the alveoli and lower airways is the primary target site for induction of lung tumors. Dose was therefore based upon the concentration of carbon particulate matter per unit lung surface area. Unit risk estimates were developed using either ...

1993-02-01

122

Phosphate/UO{sub 2} interaction during in vitro dissolution of inhalable particles in a medium simulating the phagolysosomal compartment  

Energy Technology Data Exchange (ETDEWEB)

Qualitative and quantitative methods have been developed to relate phosphate/UO{sub 2} interactions and U dissolution, in vitro, in a medium containing 0 or 10 mM phosphate concentrations at pH 5. This was performed by Energy Dispersive X ray Spectrometry (EDS) at 200 kV on entire particles and by fluorimetric measurement. The U dissolution rate was larger in a medium without phosphate than in a medium containing 10 mM phosphate. During the first day, the initial U dissolution involved 80.55% and 91.13% of the powder in media with and without phosphate respectively. From 5 to 15 d after beginning the assay, the dissolution half-times were longer than 92 d and 22 d for media with and without phosphate. EDS analyses have shown a constant P/U X ray intensity ratio for reference U{sub 2}O(PO{sub 4}){sub 2} for the same range of particle diameter. A gradual increase of this ratio was measured for UO{sub 2} incubated in a 10 mM ...

1998-07-01

123

Highly Porous, Water-Soluble, Superparamagnetic, and Biocompatible Magnetite Nanocrystal Clusters for Targeted Drug Delivery.  

Science.gov (United States)

Magnetic particles have become very promising materials for drug delivery. However, preparation of magnetite particles with high surface area, biocompatibility, strong magnetic response, and suitable particle size still remains a major challenge. In this report, magnetite nanocrystal clusters with high surface areas were fabricated through a solvothermal process by introducing ammonium acetate as a porogen and trisodium citrate as a surface modification agent. The porosity, which was controlled by the reactant concentration, has been investigated in detail. The surface area of the nanocrystal clusters was as high as 141?m(2) g(-1) . Ibuprofen, as a model drug, was entrapped into the magnetite carriers. The interfacial interaction between the carboxylic groups on the drug molecules and the carboxylate groups on the carriers enhanced the loading efficiency. Low cytotoxicity in MCF-7 cell and in vitro ...

2011-09-27

124

El Roque de Los Muchachos Site Characteristics. III. Analysis of Atmospheric Dust and Aerosol Extinction  

CERN Document Server

Canary Islands are normally interested by dominant North-East winds that, in some meteorological conditions, can transport sand at high altitude from the Sahara desert. The dust may affect the efficiency of the telescopes and decreases the transparency of the sky. In order to maximize the scientific return of the telescopes located at the ORM, we present an analysis of the atmospheric dust content and its effects on astronomical observations. B, V and I dust aerosol astronomical extinction are derived. Using a 5 years series database of data taken from the four channel TNG dust monitor, we compute a mean hourly and daily values of the dust content. We have detected particles having size 0.3, 0.5, 1.0 and 5.0 um. Using a power law we have derived the content of 10.0 um particles. We found a typical local dust concentration ranging from 3x10^6 particles per cubic meter at 0.3 um, to 10^3 at 5.0 um and 10 ...

2008-01-01

125

Simple model for characterizing the electrical resistivity in A-15 superconductors  

Science.gov (United States)

A discussion of some of the difficulties with previous analyses of the resistivity of A-15 compounds is given. Precise high-temperature data on ..cap alpha..-particle- and electron-damaged Nb/sub 3/Ge and Nb/sub 3/Sn samples with different defect concentrations are presented here and analyzed in a simple way with use of a phenomenological model based on the idea that the ideal resistivity must approach some limiting value in the regime where the mean free path becomes comparable to the interatomic spacing.

1977-04-04

126

Effects of thermophoresis and radiation on laminar flow along a semi-infinite vertical plate  

British Library Electronic Table of Contents (United Kingdom)

The present contribution deals with the thermophoresis particle deposition and thermal radiation effects on the flow, heat and mass transfer characteristics in a viscous fluid over a semi-infinite vertical porous plate. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically by means of the fourth-order Runge?Kutta method with a shooting technique. The effects of different parameters on the dimensionless velocity, temperature, and concentration profiles are shown graphically. In addition, results for the local skin-friction coefficient, the local Nusselt number, and the local Sherwood number are tabulated and discussed.

2011-01-01

127

Effects of thermophoresis and radiation on laminar flow along a semi-infinite vertical plate  

Science.gov (United States)

The present contribution deals with the thermophoresis particle deposition and thermal radiation effects on the flow, heat and mass transfer characteristics in a viscous fluid over a semi-infinite vertical porous plate. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically by means of the fourth-order Runge-Kutta method with a shooting technique. The effects of different parameters on the dimensionless velocity, temperature, and concentration profiles are shown graphically. In addition, results for the local skin-friction coefficient, the local Nusselt number, and the local Sherwood number are tabulated and discussed.

2011-04-01

128

Dry aerosol resuspension after a hydrogen deflagration in the containment  

International Nuclear Information System (INIS)

During a hypothetical severe incident in a nuclear power plant with core meltdown a large part of radioactive material is present as aerosol particles in the reactor containment. In current severe accident containment codes the potential influences of hydrogen combustions on the behaviour of aerosols are not considered. Among other effects dry resuspension can increase the aerosol concentration in the atmosphere. Already deposited aerosol material can be re-released into the containment atmosphere by atmospheric currents induced by hydrogen deflagrations or by other phenomena like steam explosions. The objective is to assess the possible influence of this dry resuspension effect on the radioactive source term. (author)

2007-09-10

129

Determination of the content of elements in some wild medicinal plants of Uzbekistan by radioactivation analysis  

Energy Technology Data Exchange (ETDEWEB)

The authors have developed a complex of activation methods of analysis using a nuclear reactor (nuclear activation analysis) and a cyclotron (charged-particle activation analysis). The methods have been used to determine the concentrations of more than 20 elements in five medicinal plants native to Uzbekistan: Syrian rue (Peganum harmala L.), plantain (Plantago lanceolata), peppermint (Mentha piperata L.), sage (Salvia officinalis L.), and ziziphora (Ziziphora bungeana Yur.). The results of radio-activation analysis were compared with the results of standard spectral analysis performed in another laboratory and the accuracy of the procedures developed was evaluated on the basis of the results.

1987-06-01

130

Use of coal as fuel for chemical-looping combustion with Ni-based oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas presents a monotonously increasing trend, whereas the dry basis ...

2008-12-15

131

Development of a thermographic measurement process as an alternative to gravimetry in determining Diesel engine particle emission. Final report; Entwicklung eines thermographischen Messverfahrens als Alternative zur Gravimetrie bei der Ermittlung von Dieselpartikel-Emissionen. Abschlussbericht  

Energy Technology Data Exchange (ETDEWEB)

Against the background of more severe limitation of particle emission in all application areas of Diesel engines, it is necessary to monitor the particle emission, but also the chemical composition of the particles. The basis of assessing particle emission is formed by gravimetric determination of the particle concentration from exhaust gas diluted with particle-free ambient air, with a maximum temperature of 52 degrees C at the sampling position. While it is already possible, using the part flow dilution system, to take samples locally, previously the subsequent particle determination and characterisation could only be done in a chemical laboratory. For this reason, the C/S particle measurement process was developed as an alternative to gravimetry, which can be used locally, eg: on ships and which ...

1994-12-31

132

Simulation of char combustion according to shrinking particle and shrinking core model in circulating fluidized bed boilers; Simulation des Koksabbrandes nach dem Shrinking Particle- und Shrinking Core Modell in zirkulierenden Wirbelschichtfeuerungen  

Energy Technology Data Exchange (ETDEWEB)

The presented paper describes the formulation of the fractional mass balances which are used to calculate the concentration and size distribution of char in the balance cells of a circulating fluidized bed boiler. In case of using the shrinking core model additionally the distribution of conversion of the char particles is calculated. Basically two reaction models (a shrinking particle and a shrinking core model) are available to describe the combustion process. The model considers all essential physico/chemical phenomena (primary fragmentation, attrition, mass transfer to gas phase) which have to be taken into account for the description of the combustion process. The model is part of an overall simulation program for circulating fluidized bed boilers. This engineering simulator has been developed to return the main performance parameters of such systems like temperature along the furnace height, size distribution of ...

1998-12-31

133

Quality of wooden chips produced by Claas Jaguar fitted with experimental CRA-ING rotor  

Energy Technology Data Exchange (ETDEWEB)

This paper described a newly developed chipper device for mounting on Claas Jaguar chipper harvesters for short rotation forestry harvesting. It was designed by the Agriculture Engineering Research Unit of the Agricultural Research Council in Rome, Italy. The new rotor has a lower number of blades compared to standard rotors and has a different cutting angle and drum insertion. This study evaluated the particle-size distribution of wood chips produced by standard rotors compared to those with the experimental rotor. The objective was to distinguish the particle size distribution of chips produced using the two types of chippers in order to evaluate the influence of wooden species in the chip formation process. Tests were conducted using 860 and 890 Claas Jaguar chipper harvesters, both equipped with standard and CRA-ING rotors. The experiment was conducted on poplar cultivations on biennial shift and on arboreal cultivations. Compared to ...

2010-07-01

134

Correlation between particle size, in vivo particle persistence, and lung injury.  

UK PubMed Central (United Kingdom)

Dosimetry parameters such as deposition, clearance, retention, and translocation and dissolution of inhaled particles in and to different lung compartments may be important for the persistence of particles...Full Text Available

1994-10-01

135

OZONE PRODUCTION IN THE PHILADELPHIA URBAN AREA DURING NE-OPS 99  

International Nuclear Information System (INIS)

As part of the 1999 NARSTO Northeast Oxidant and Particulate Study (NE-OPS) field campaign, the DOE G-1 aircraft sampled trace gases and aerosols in and around the Philadelphia metropolitan area. Twenty research flights were conducted between July 25 and August 11. The overall goals of these flights were to obtain a mechanistic understanding of O(sub 3) production; to characterize the spatial and temporal behavior of photo-oxidants and aerosols; and to study the evolution of aerosol size distributions, including the process of new particle formation. Within the NE-OPS program, other groups provided additional trace gas, aerosol, and meteorological observations using aircraft, balloon, remote sensing, and surface based instruments (Phillbrick et al., 2000). In this article we provide an overview of the G-1 observations related to O(sub 3) production, focusing on the vertical distribution of pollutants. Ozone production rates are calculated using a box model that is ...

136

Non-thermal atmospheric pressure HF plasma source: generation of nitric oxide and ozone for bio-medical applications  

International Nuclear Information System (INIS)

A new miniature high-frequency (HF) plasma source intended for bio-medical applications is studied using nitrogen/oxygen mixture at atmospheric pressure. This plasma source can be used as an element of a plasma source array for applications in dermatology and surgery. Nitric oxide and ozone which are produced in this plasma source are well-known agents for proliferation of the cells, inhalation therapy for newborn infants, disinfection of wounds and blood ozonation. Using optical emission spectroscopy, microphotography and numerical simulation, the gas temperature in the active plasma region and plasma parameters (electron density and electron distribution function) are determined for varied nitrogen/oxygen flows. The influence of the gas flows on the plasma conditions is studied. Ozone and nitric oxide concentrations in the effluent of the plasma source are measured using absorption spectroscopy and electro-chemical NO-detector at variable gas flows. Correlations ...

2010-01-01

137

Formation of ZnTe compounds by using the electrochemical ion exchange reaction in molten chloride  

Energy Technology Data Exchange (ETDEWEB)

The formation of ZnTe films was investigated on zinc substrates at 640 K by using the following ion exchange and chemical reaction processes,2Zn{sub (substrate)}+Te{sup 4+}{sub (inmoltensalts)}->2Zn{sup 2+}+Te{sub (onsubstrate)}Zn{sub (substrate)}+Te= {sub (onsubstrate)}-> ZnTe{sub (onsubstrate)}The Te{sup 4+} species was supplied to the substrate via the gas phase, vaporized from the eutectic LiCl-KCl molten salt containing TeCl{sub 4} (0.05-0.9 mol%). The phase of the films obtained depended on the reaction time and the TeCl{sub 4} content in the molten chloride. At low TeCl{sub 4} concentrations, ZnTe alloy was not formed over the entire surface even after 3.6 ks. On the other hand, at high TeCl{sub 4} concentrations, tellurium was detected in addition to the ZnTe compound during the first 0.3 ks of the reaction. By selecting appropriate TeCl{sub 4} concentrations and reaction times, a ZnTe film with a ...

2005-05-01

138

Application of radionuclide X-ray fluorescence analysis to the monitoring of the quality of air  

International Nuclear Information System (INIS)

An X-ray fluorometric train was set up for analyzing gravitational fallout, and tested on standard reference samples of fly ashes from conventional power plants. Analysis of thin layers proved inappropriate, and therefore pelletization of the samples, either alone or together with the X-ray MIX binder, was applied. Sample grinding in an agate mortar was found sufficient to suppress the particle size effect. The optimum pressure was 20 MPa. The optimum geometry was sought for "1"0"9Cd source, and limits of detection of 2.78-0.47 #mu#g were achieved for Cr-Zr elements. Tominaga's method was employed for matrix effect correction. Ti, Fe, Cu, Zn, As, Rb, Sr, Zr and Pb were determined in the SRM's; the relative errors ranged from units per cent (for Zn, Rb, Sr and Zr present in concentrations about 100 ppm and for Fe in concentrations of units per cent) up to 45% (for Ti present in a concentration of 0.67%). ...

1990-10-01

139

Cytotoxic evaluation of N-isopropylacrylamide monomers and temperature-sensitive poly(N-isopropylacrylamide) nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

The objective of this research project is to investigate the biocompatibility of N-isopropylacrylamide (NIPAAm) monomers and poly(N-isopropylacrylamide) (PNIPAAm) nanoparticles in vitro. PNIPAAm nanoparticles of different sizes were synthesized and characterized by transmission electron microscopy and dynamic light scattering. Cytotoxicity studies using MTS assays were conducted on fibroblasts, smooth muscle cells, and endothelial cells. In addition, the concentration of NIPAAm monomers remaining on PNIPAAm nanoparticles was determined using bromination and spectrophotometry. The cytotoxicity results did not show a significant difference in cell survival when cells were exposed to different particle sizes (100, 300, and 500 nm). Dose studies showed that all three cell types exposed to 100 nm PNIPAAm nanoparticles at concentrations less than or equal to 5 mg/mL were compatible, while cells exposed to NIPAAm monomers ...

2009-08-15

140

Study of the {sup 60}Co speciation in the aqueous radioactive waste of the la Hague nuclear reprocessing plant; environmental behaviour after discharges in the waters of the channel; Etude de la speciation du {sup 60}Co dans les effluents de l'usine de retraitement de combustibles irradies de la Hague; devenir apres rejet dans les eaux de la Manche  

Energy Technology Data Exchange (ETDEWEB)

{sup 60}Co is produced as an activation product and is present in the low-level aqueous radioactive waste released from the La Hague plant. At present, the concentration in the sea (non filtered at 0.45 {mu}m) at the Goury site are close to or even below, the detection limit: 0.2 mBq.l{sup -1}. The {sup 60}Co speciation depends on the type of effluent considered: in the effluent A ('active'), the cobalt is in the form of a stable trivalent complex; in the effluent V (to be checked), the cobalt is in majority (50% of the activity release) in the form of particles (>0.45 {mu}m), and then in the form of two soluble species: ionic divalent (Co{sup 2+}) and some stable complexes. The evolution of the reprocessing techniques used does not affect the speciation. So, since the nuclear reprocessing plant started at the La Hague plant in 1966, the chemical species discharged in the sea shows time variation related to the ...

1999-07-01

141

Precious Metals in Municipal Solid Waste Incineration Bottom Ash  

Energy Technology Data Exchange (ETDEWEB)

Municipal solid waste incineration (MSWI) bottom ash contains economically significant levels of silver and gold. Bottom ashes from incinerators at Amsterdam and Ludwigshafen were sampled, processed, and analyzed to determine the composition, size, and mass distribution of the precious metals. In order to establish accurate statistics of the gold particles, a sample of heavy non-ferrous metals produced from 15 tons of wet processed Amsterdam ash was analyzed by a new technology called magnetic density separation (MDS). Amsterdam's bottom ash contains approximately 10 ppm of silver and 0.4 ppm of gold, which was found in particulate form in all size fractions below 20 mm. The sample from Ludwigshafen was too small to give accurate values on the gold content, but the silver content was found to be identical to the value measured for the Amsterdam ash. Precious metal value in particles smaller than 2 mm seems to derive mainly from waste ...

2009-04-15

142

Production and characterization of ultrafine WC powders  

International Nuclear Information System (INIS)

The conventional Calzination-Reduction-Carburization (CRC) process offers the potential to manufacture commercial WC powders with median SEM grain sizes below 0.5 pm (ultra fine grades). Strict process control and a high degree of automation have led to increased powder uniformity and high lot-to-lot reliability. The high potential and flexibility of the CRC process is shown by the development of tailor made WC powders with regard to subsequent alloy manufacturing. R and D powders have successfully been processed in full-scale units exhibiting SEM grain sizes of 0.15 - 0.20 pm. This paper discusses the powder characteristics of various ultra fine WC powder grades, stemming from the conventional CRC process. Analytical characterization include also field-emission SEM, bright field TEM, EDX analysis and XRD-line broadening. (author)

2001-05-01

143

Space Radiation Detector with Spherical Geometry  

Science.gov (United States)

A particle detector is provided, the particle detector including a spherical Cherenkov detector, and

2011-01-01

144

Flawless start for world's mightiest particle collider  

CERN Document Server

Flawless start for world's mightiest particle collider

2008-01-01

146

Effect of secondary fuels and combustor temperature on mercury speciation in pulverized fuel co-combustion: part 1  

Energy Technology Data Exchange (ETDEWEB)

The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel ...

2007-08-15

147

[Preparation of titanium dioxide particles and properties for flue gas desulfurization].  

Science.gov (United States)

Under different sintering temperatures(340 degrees C, 440 degrees C, 540 degrees C, 640 degrees C), four TiO2 particles were prepared. The crystal types of all four samples were found to possess anatase structures by XRD. It was obtained by N2 experimental adsorption at low temperature (77K) that their surface areas and average pore size were between 79 and 124 m2/g, 56.8 and 254.8 A respectively. The pore structure of TiO2 particles was characterized by scanning electron microscope (SEM). The tests of adsorption dynamics for FGD and the performance of SO2 removal were investigated in a fixed-bed system for different samples. The results show that SG540 sample which made at 540 degrees C sintering temperature had the most quality among the four samples. It can adsorb SO2 of 38.9 mg for one gram SG540 sample. Different operating conditions for SG540 such as adsorption temperature, SO2 concentration in flue gas and the ...

2003-01-01

148

Particle emission from low energy nuclear reactions in solids. Preliminary results  

Energy Technology Data Exchange (ETDEWEB)

TiH{sub 2} and TiD{sub 2} thick targets were bombarded with 100 to 200 keV protons or deuterons. Evidence for nuclear reactions was obtained by means of a surface barrier particle detector. Deuteron irradiation of TiD{sub 2} produced these observations: copious {approx}2.5 MeV neutrons and {approx}3 MeV protons from direct D-D reactions; gamma rays from p,{gamma} and n,{gamma} reactions; {approx}14 MeV protons from the secondary d({sup 3}He, p){alpha} reaction; and a signal between {approx}6-12 MeV that Kasagi et al. has tentatively identified as protons from the fusion of three deuterium nuclei. However, this signal has in it a strong interference signal from either neutrons or gamma rays that directly deposit energy in the detector. This interference spectra was measured by placing a thick absorber in front of the detector that stops up to 20 MeV protons, but not gamma rays or neutrons. More experiments must be done before we can confirm or deny the existence in ...

2000-07-01

149

Frequency distribution, isotopic composition and physical characterization of plutonium-bearing particles from the Fig-Quince zone on Runit Island, Enewetak Atoll  

International Nuclear Information System (INIS)

Runit Island on Enewetak Atoll was very heavily impacted by the U.S. nuclear testing campaign in the northern Marshall Islands (1946-58). The primary source of contamination on Runit Island was the 1958 Quince safety test where a large quantity of device plutonium (Pu) was scattered over the area near the GZ. A second low-yield device was detonated on the same site 10 days later, further disturbing the soil and leaving behind a very heterogeneous pattern of contamination including milligram-size particles of plutonium. A limited cleanup of the Fig-Quince zone was carried out in 1979. During this period, the effectiveness of the cleanup operations was primarily evaluated on the basis of bulk soil concentration data with little consideration given to the heterogeneity and long-term material-, biological-, and environmental-specific impacts of residual high activity (hot) particle contamination. The aim of the present study ...

2009-12-01

150

Selecting soil amendment materials for removal of phosphorus  

Energy Technology Data Exchange (ETDEWEB)

Phosphorus sorption capacities of several different materials including Merribrook soil (a loamy sand) and some industrial solid wastes (red mud neutralized with gypsum, fly ash, bottom ash and black oxide) were determined in sorption isotherms by Langmuir and Freundlich equations. The materials were characterized by bulk density, particle density, total porosity and particle size distributions. Red mud gypsum possessed the best sorption capacity based on the Langmuir maxima. Alkaline fly ash and Merribrook soil had lower sorption maxima compared to the red mud gypsum. Bottom ash and acidic fly ash had very low sorption capacity at low concentrations. Merribrook soil had the highest hydraulic conductivity. The results suggested that alkaline fly ash may be a promising amendment for coarse sand bed to enhance phosphorus removal. Merribrook soil appears to be suitable for on-site wastewater treatment.

1994-12-31

151

Predictions of benefits and costs derived from improving indoor air quality in telephone switching offices  

Energy Technology Data Exchange (ETDEWEB)

Airborne pollutants can cause failures in switching and computing equipment. This paper focuses on a subset of such pollutants - airborne fine particles (<2.5 [mu]m diameter). It begins by examining the extent to which different improvements in heating, ventilating and air conditioning (HVAC) systems reduce indoor concentrations of fine particles. For each modification, the consequent reduction in soiling rate is derived. The concomitant increase in operating costs is also calculated. These costs are then compared with the costs of failures in telephone switching offices, leading to estimates of failure rate reductions that would make improvements cost-effective. Finally, the reduction in failures required to offset the costs of the improvements are compared with documented differences in failure rates between unimproved and improved environments. This study suggests that, in many telephone switching offices, the added ...

1991-01-01

152

Minority-carrier lifetime damage coefficient of irradiated InP  

Energy Technology Data Exchange (ETDEWEB)

Minority-carrier lifetime damage coefficients for 1 MeV electron, 3 MeV proton, and 6 MeV alpha particle irradiation of n-type (4.5{times}10{sup 15} and 1.3{times}10{sup 17}cm{sup {minus}3}) and p-type (2.5{times}10{sup 17}cm{sup {minus}3}) InP have been measured using time-resolved photoluminescence. These values are relatively insensitive to carrier type and show a slight increase with increasing carrier concentration. Evidence of comparable electron and hole capture lifetimes is found for the dominant recombination defect. The effect of 3 MeV proton and 6 MeV alpha particles relative to 1 MeV electrons is an increase in the lifetime damage coefficient by factors of about 10{sup 4} and 10{sup 5}, respectively. {copyright} {ital 1997 American Institute of Physics.}

1997-09-01

153

Characterization of atmospheric emissions produced by live gun firing : test on the M777 155 mm Howitzer  

Energy Technology Data Exchange (ETDEWEB)

This study analyzed the atmospheric emissions produced by the live firing of a 155 mm Howitzer gun. The study was conducted during a live firing training exercise at a Canadian Forces Base. Air emissions were sampled continuously for 3 hours. Particles and chemicals were accumulated on sampling media during the firing of 69 rounds. A single round was fired using 4 bags of propellants, and an additional 3 rounds were fired using 5 bags of propellant. Samples included particulate matter; hydrogen cyanide; polycyclic aromatic hydrocarbons (PAHs); dinitrotoluene compounds; benzene; toluene; ethylbenzene; xylene; metals; aldehydes; nitric acid; nitric oxide; nitrogen dioxide; hydrogen sulphide; and sulphur dioxide. Samples were collected at 8 m to the left of the gun as well as at 22 m in front of the gun muzzle in the line of fire. Results of the study showed that 60 per cent of the particles were below 10 {mu}m. Formaldehyde ...

2007-10-15

154

Carbon dioxide purification through two-stage combustion ENCAP. Final report; Koldioxidrening med tvaastegsforbranning ENCAP. Slutrapport  

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion (CLC), has previously been studied as a method for separating CO{sub 2} during combustion of gaseous fuels. In this project the possibility to apply this process for direct use of solid fuels has been investigated. The following has been accomplished: A 10 kW reactor system for CLC with solid fuels has been designed and built. Tests with solid fuel and metal oxid particles in a laboratory reactor show that it is possible to oxidize solid fuels with metal oxide particles in cyclic testing, thus giving proof of basic concept. They also show how the reaction rate is affected by temperature, steam concentration etc., and, most important of all, that the rates of reaction are realistic. Tests with metal oxide materials available at low costs have been successful. Chemical-looping combustion with solid fuels has a potential to achieve very low costs for separation of CO{sub 2}, below 10 Euro/ton CO{sub ...

2006-06-15

155

Anti-cancer drug loaded iron-gold core-shell nanoparticles (Fe@Au) for magnetic drug targeting.  

Science.gov (United States)

Magnetic drug targeting, using core-shell magnetic carrier particles loaded with anti-cancer drugs, is an emerging and significant method of cancer treatment. Gold shell-iron core nanoparticles (Fe@Au) were synthesized by the reverse micelle method with aqueous reactants, surfactant, co-surfactant and oil phase. XRD, XPS, TEM and magnetic property measurements were utilized to characterize these core-shell nanoparticles. Magnetic measurements showed that the particles were superparamagnetic at room temperature and that the saturation magnetization decreased with increasing gold concentration. The anti-cancer drug doxorubicin (DOX) was loaded onto these Fe@Au nanoparticle carriers and the drug release profiles showed that upto 25% of adsorbed drug was released in 80 h. It was found that the amine (-NH2) group of DOX binds to the gold shell. An in vitro apparatus simulating the human circulatory system was used to determine ...

2010-09-01

156

Transient heat transfer in a directly-irradiated solar chemical reactor for the thermal dissociation of ZnO  

International Nuclear Information System (INIS)

A numerical and experimental investigation is carried out in a solar thermochemical reactor for the thermal dissociation of ZnO at 2000 K using concentrated solar energy. The reactor consists of a cavity-receiver lined with ZnO particles and directly exposed to high-flux irradiation. A transient heat transfer model is formulated to link the rate of radiation, convection, and conduction heat transfer to the reaction kinetics. The radiosity and Monte Carlo methods are applied to obtain the distribution of net radiative fluxes at the internal surfaces of the reactor cavity and at the surface of the ZnO bed. Validation is accomplished in terms of the calculated and measured transient temperature profiles and chemical reaction rates.

2008-04-01

157

The influence of furnace geometry and wall materials on the combustion process and the prediction of problem areas in waste incinerators  

Energy Technology Data Exchange (ETDEWEB)

Based on the CFD-code FLUENT trademark, theoretical studies were conducted of the influences of incineration chamber geometry (direct, countercurrent and center flow) on the combustion process. The boundary conditions, e.g., the thermal input and the waste grate, were kept constant. Close attention was paid to the distribution of flow, spe-cies, and temperatures. In addition, the influence of a dis-placement body at the end of the combustion chamber was tested. The variation of different wall materials and the prediction of problem areas concerning corrosion, slagging, and contamination completed the studies. Close to the chamber walls, high CO-concentrations may indi-cate corrosion; particle flow may indicate where contami-nation, slagging or erosion could occur. (orig.)

2001-01-01

158

Study of Zircaloy-2 corrosion in high temperature water using ion beam methods  

Energy Technology Data Exchange (ETDEWEB)

Experiments have been carried out in water at 355 C to study transport of oxygen and hydrogen (as deuterium) in growing corrosion films. Composition of the films was also examined in 2.9 Mev and 3.9 Mev /alpha/-particle backscattering experiments. Corrosion occurs predominantly by oxygen diffusion through the film via grain boundary or similar short circuit diffusion paths, to form fresh oxide at the oxide metal interface. Increasing grain size within thick pre-breakaway films contributes to a decrease in diffusivity. The rate transition results from the generation of new diffusion pathways in previously protective oxide. Unexpectedly high concentrations of deuterium were observed. 26 refs.

1981-10-01

159

Sizing pumps for slurries  

Energy Technology Data Exchange (ETDEWEB)

Slurry characteristics have a significant impact on centrifugal pump performance. For instance, as particle size increases or the percent solids concentration increases, pump head and efficiency decrease. Therefore, before a slurry pump is selected, it is important to define the slurry characteristics as accurately as possible. The effect of the slurry characteristics on the head and efficiency of the centrifugal pump will be emphasized (the effect on flowrate is less significant). The effect of slurry characteristics is more predominant in smaller pumps (with smaller diameter impellers) than in larger pumps. The data and relationship between the various slurry parameters have been developed from correlations and nomographs published by pump vendors from their field data and test results. The information helps to avoid specifying an undersized pump/motor assembly for slurry service.

1996-11-01

160

Silver removal process development for the MEO cleanout  

Energy Technology Data Exchange (ETDEWEB)

The Mediated Electrochemical Oxidation (MEO) system is an aqueous process which treats low-level mixed wastes by oxidizing the organic components of he waste into carbon dioxide and water. As MEO system continues to run, dissolved ash and radionuclides slowly accumulate in the anolyte and must be removed to maintain process efficiency. At such time, all of the anolyte is pumped into a still feed tank, and the silver ions need to be removed before sending the solution to a thin-film evaporator for further concentration. The efficiency of removing silver ions in the solution needs to be high enough such that the residual silver sent to Final Forms would be less than 1% wt. The purpose of this work is to develop an efficient process to remove silver ions during the MEO cleanout and to demonstrate the capability of centrifugation for separating small silver chloride particles from the solution. This development work includes lab scale experiments ...

1996-02-01

161

Shutdown Chemistry Process Development for PWR Primary System  

Energy Technology Data Exchange (ETDEWEB)

This study report presents the shutdown chemistry of PWR primary system to reduce and remove the radioactive corrosion products which were deposited on the nuclear fuel rods surface and the outside of core like steam generator channel head, RCS pipings etc. The major research results are the follows ; the deposition radioactive mechanism of corrosion products, the radiochemical composition, the condition of coolant chemistry to promote the dissolution of radioactive cobalt and nickel ferrite, the control method of dissolved hydrogen concentration in the coolant by the mechanical and chemical methods. The another part of study is to investigate the removal characteristics of corrosion product ions and particles by the demineralization system to suggest the method which the system could be operate effectively in shut-down purification period. (author). 19 refs., 25 figs., 48 tabs.

1997-12-31

162

Polymeric nanosponges as an alternative carrier for improved retention of econazole nitrate onto the skin through topical hydrogel formulation  

British Library Electronic Table of Contents (United Kingdom)

The present study was carried out to exploit the feasibility of using polymeric nanosponges as an alternative carrier for targeting econazole nitrate (EN) to the skin through topical hydrogel formulation. Nanosponges prepared by emulsion solvent diffusion method were evaluated for various physicochemical parameters and in vitro drug release. The nanosponges of EN were discrete free flowing nanosized particles with perforated orange peel like morphology as visualized by SEM. The nanosponge formulated using PVA:EC (3:2) displayed highest in vitro release after 12 ?h in phosphate buffer (pH 6.8) that fitted matrix model. Selected nanosponge was formulated as Carbopol 934 NF hydrogel using varying concentrations of permeation enhancers propylene glycol and N-methyl-2-pyrrolidone. The EN nanosp...

2011-01-01

163

Occupational exposure to uranium oxides (UO{sub 2} - U{sub 3}O{sub 8}) - methods and results; Etude de l'exposition industrielle a des oxydes d'uranium (UO{sub 2} - U{sub 3}O{sub 8}) - methodes et resultats  

Energy Technology Data Exchange (ETDEWEB)

Chronic exposure to uranium compounds such as UO{sub 2} and U{sub 3}O{sub 8} led to the development of a methodology, based on the recommendation of ICRP, involving four main steps: the measurement of the uranium concentration and the particle size distribution at the workstation, the assessment of physico-chemical properties of the compound, the study of in-vitro solubility using a chemical test and the monitoring of workers. Results and comments on UO{sub 2} and U{sub 3}O{sub 8} are given. (author)

1992-07-01

164

Minimizing sulfur contamination and rinse water volume required following a sulfuric acid/hydrogen peroxide clean by performing a chemically basic rinse  

Energy Technology Data Exchange (ETDEWEB)

Sulfuric acid hydrogen peroxide mixtures (SPM) are commonly used in the semiconductor industry to remove organic contaminants from wafer surfaces. This viscous solution is very difficult to rinse off wafer surfaces. Various rinsing conditions were tested and the resulting residual contamination on the wafer surface was measured. The addition of small amounts of a chemical base such as ammonium hydroxide to the rinse water has been found to be effective in reducing the surface concentration of sulfur and also mitigates the particle growth that occurs on SPM cleaned wafers. The volume of room temperature water required to rinse these wafers is also significantly reduced.

1997-08-01

165

Light emission from hydrogen-copper interaction at grazing incidence  

Energy Technology Data Exchange (ETDEWEB)

The optical emission of excited H reflected from clean Cu(110) after impingement of H/sup +/ and H/sub 2//sup +/ in the energy range of 250 eV to 20 keV per nucleon at 70/sup 0/ angle of incidence to the surface normal was measured. For incident 10 keV H/sub 2//sup +/, the highest excited hydrogen state detected was the n=10 level. The Hsub(..cap alpha..) yield was found to be fluence and energy dependent. This effect is attributed either to fast sputtered hydrogen, surface roughness or to an increase with hydrogen concentration in electron states of p-like symmetry near the Fermi level of copper. The Hsub(..cap alpha..) yield per reflected nucleon shows approximately an exponential dependence on both projectile energy per nucleon and scattered particle reciprocal velocity perpendicular to the surface.

1984-03-01

166

Light emission from hydrogen-copper interaction at grazing incidence  

International Nuclear Information System (INIS)

The optical emission of excited H reflected from clean Cu(110) after impingement of H"+ and H_2"+ in the energy range of 250 eV to 20 keV per nucleon at 70"0 angle of incidence to the surface normal was measured. For incident 10 keV H_2"+, the highest excited hydrogen state detected was the n=10 level. The Hsub(#alpha#) yield was found to be fluence and energy dependent. This effect is attributed either to fast sputtered hydrogen, surface roughness or to an increase with hydrogen concentration in electron states of p-like symmetry near the Fermi level of copper. The Hsub(#alpha#) yield per reflected nucleon shows approximately an exponential dependence on both projectile energy per nucleon and scattered particle reciprocal velocity perpendicular to the surface. (orig.).

1983-07-01

167

Laser-generated PuO_2--UO_2 condensation aerosols  

International Nuclear Information System (INIS)

A 340-watt CO_2 laser is being used to generate PuO_2-UO_2 condensation aerosol from the surface of a Liquid Metal Fast Breeder Reactor (LMFBR) fuel pellet. A wide range of concentrations is achieved by varying the laser power, pulse width, and/or pulse period. The resulting aerosol is composed of branch chain-like aggregates, with the primary particle size ranging between 0.005 and 0.15 #mu#m. X-ray diffraction analyses show that these aerosols condense into a face-centered cubic crystal structure. The activity mean aerodynamic diameter (AMAD), for most power levels, is approximately 0.85 #mu#m with a geometric standard deviation of 1.5.

1977-05-01

168

Kinetics of hydrolysis of PET powder in nitric acid by a modified shrinking-core model  

Energy Technology Data Exchange (ETDEWEB)

Poly(ethylene terephthalate) (PET) powder from waste bottles was degraded at atmospheric pressure in 7--13 M nitric acid at 70--100 C for 72 h, to clarify the mechanism of a feed stock recycling process. Terephthalic acid (TPA) and ethylene glycol (EG) were produced by the acid-catalyzed heterogeneous hydrolysis of PET in nitric acid, and the resulting EG was simultaneously oxidized to oxalic acid. The kinetics of the hydrolysis of PET in nitric acid could be explained by a modified shrinking core model of chemical reaction control, in which the effective surface area is proportional to the degree of unreacted PET, affected by the deposition of the product TPA. The apparent rate constant was inversely proportional to particle size and to the concentration of the nitric acid. The activation energy of the reaction was 101.3 kJ/mol.

1998-02-01

169

Ion beam induced charge imaging of epitaxial GaN detectors  

Energy Technology Data Exchange (ETDEWEB)

We report the use of ion beam induced charge imaging to characterise the charge signal uniformity of epitaxial gallium nitride radiation detectors. The detectors were fabricated from 2 {mu}m thick semi-insulating gallium nitride, grown by MOCVD on a sapphire substrate. A carrier concentration of 1.4x10{sup 15} cm{sup -3} was measured using capacitance-voltage measurements. Ion beam induced charge imaging was carried out with a 2 MeV alpha particle beam focussed to a 3 {mu}m diameter and raster scanned across the device. The resulting ion beam images show excellent charge signal uniformity in this material with no evidence of material defects or polycrystalline structure on the micrometer length scale. No evidence of charge signal trapping was observed in these devices.

2004-09-21

170

Investigation of weld cracking in alloy 800  

Energy Technology Data Exchange (ETDEWEB)

The subscale Varestraint test has been used to determine the relative hot cracking susceptibility of the fusion zone in four commercial heats of alloy 800. Although all four heats were susceptible to cracking, one heat exhibited a significant increase in cracking relative to the other three. Optical metallography revealed that nearly all the cracking was localized along fusion zone grain boundaries. Microprobe analysis of the grain boundaries detected high concentrations of titanium, silicon, and niobium resulting from partitioning during solidification. The fusion zone hot cracking mechanism in alloy 800 involves the complex interaction of titanium, silicon, niobium, and carbon along the solidification boundaries. SEM and Auger analyses of the hot crack fracture surfaces revealed the presence of (Ti, Nb)-rich carbides, suggesting that these particles precipitate from the liquid which solidifies last on the fracture surface. 23 references.

1984-03-01

171

Inhibition of barium sulfate deposition by polycarboxylates of various molecular structures  

Energy Technology Data Exchange (ETDEWEB)

To establish a relationship between the molecular structure of polycarboxylates and their growth-retarding influence on barium sulfate, seeded-suspension-growth experiments were performed at various inhibitor concentrations and pH values. Two types of polycarboxylates with a molecular structure based on their polyacrylic or maleic acid were studied. The molecular structure of these compounds were varied by particle substitution with monomers containing hydroxyl, amide, and sulfonic acid, as well as hydrophobic groups. Hydrophobic groups are detrimental to good inhibitor performance, whereas the introduction of OH, NH {sub 2}, or SO {sub 3} H groups presents opportunities to enhance the inhibitor effectiveness. The sequence in performance of the compounds on barium sulfate was compared with the sequence formerly obtained for calcium sulfate dihydrate.

1990-02-01

172

Impact of the addition of chicken litter on mercury speciation and emissions from coal combustion in a laboratory-scale fluidized bed combustor  

Energy Technology Data Exchange (ETDEWEB)

Co-combustion of chicken litter with coal was performed in a laboratory-scale fluidized bed combustor to investigate the effect of chicken litter addition on the partitioning behavior of mercury. Gaseous total and elemental mercury concentrations in the flue gas were measured online, and ash was analyzed for particle-bound mercury along with other elemental and surface properties. The mercury mass balance was between 85 and 105%. The experimental results show that co-combustion of chicken litter decreases the amount of elemental and total mercury in the gas phase. Mercury content in fly ash increases with an increasing chicken litter share. 22 refs., 6 figs., 5 tabs.

2008-07-15

173

Effect of alleviating products with different mode of action on physiology and yield of olive under drought  

British Library Electronic Table of Contents (United Kingdom)

Two years old self-rooted Koroneiki olive trees (Olea europaea L.) were subjected to two irrigation regimes, i.e. the fully irrigated and the severely water stressed trees, while they were treated with three alleviating products of different mode of action. The products used were the osmolyte glycine betaine, the antioxidant Ambiol and the heat and irradiance reflecting kaolin clay particles. The effects of product application and water regime on leaf characteristics, shoot and root growth, photosynthesis, leaf compatible solids (carbohydrates) concentration and yield were evaluated. All products applied, exhibited significant alleviating action, based on the relative alleviation index. Irrigated trees exhibited greater growth than drought stressed ones, while the ameliorating products mai...

2010-01-01

174

Detection of free amino acids in proxies of marine aerosol by photoelectron resonance capture ionization aerosol mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

Photoelectron resonance capture ionization aerosol mass spectrometry (PERCI-AMS) has been applied to the analysis of proxies for marine aerosols with and without ozone; proxies used were mixed oleic acid-amino acid particles. The mechanism of ion formation for serine (104 m/z), glutamic acid (146 m/z), and phenylalanine (164 m/z) was dissociative electron attachment. This corresponds to loss of the hydrogen atom only, allowing for straightforward identification of the free amino acids. No ozonolysis products for the free amino acids were observed, even at high concentrations of ozone (500 ppm for 19 s). The direct detection of a novel gas-phase hydrated anion, [serine + H2O-H]-, is described. These preliminary results suggest that PERCI-AMS may provide an effective, simple and direct onlin...

2008-01-01

175

Characterization of the product of the thiosulfate process for desulfurization of flue gases  

Energy Technology Data Exchange (ETDEWEB)

X-ray diffraction, infrared spectroscopy, thermal analysis, scanning electron microscopy, and particle size analysis were used to characterize the product of the thiosulfate process. It was found to consist of a mixture of a solid solution of calcium sulfate in calcium sulfite hemihydrate, calcium sulfate dihydrate, and calcium carbonate. Reactions taking place on heating the byproduct were identified in oxidizing and reducing atmospheres. Pure calcium sulfite hemihydrate as well as solid solutions of CaSO[sub 4] in CaSO[sub 3] [center dot] (1/2)H[sub 2]O with different sulfate concentrations were synthesized in the laboratory. Thermal analyses of pure solid solutions proved that the higher the sulfate content, the higher is the dehydration temperature. Accordingly, taking SO[sub 4][sup 2[minus

1994-05-01

176

Characterization of enzyme-deproteinized skim rubber  

British Library Electronic Table of Contents (United Kingdom)

Skim natural rubber latex is a protein-rich byproduct obtained during the centrifugal concentration of natural rubber latex. Skim latex has a very low dry rubber content (4-8%), and the rubber particles are smaller in size. It has a higher proportion of nonrubber solids, which are mostly proteinaceous in nature. It is difficult to coagulate, and it takes more processing time. The proteins in skim latex can be decomposed by proteolytic enzymes. This article discusses the use of stabilized liquid papain from the papaya plant (Carica papaya) for deproteinization followed by creaming for quick and easy coagulation of skim latex. The technological properties and aging characteristics of the deproteinized skim rubber are compared with those of conventionally prepared skim rubber and block rubber...

2009-01-01

177

5. Sampling  

International Nuclear Information System (INIS)

The sampling is described for radionuclide X-ray fluorescence analysis. Aerosols are captured with various filter materials whose properties are summed up in the table. Fine dispersed solid and liquid particles and gaseous admixtures may be captured by bubbling air through a suitable absorption solution. The concentration of small amounts of impurities from large volumes of air is done by adsorbing impurities on surfactants, e.g., activated charcoal, silica gel, etc. Aerosols may be captured using an electrostatic precipitator and aerosol fractions may be separated with a cascade impactor. Water sampling differs by the water source, i.e., ground water, surface water, rain or waste water. Soil samples are taken by probes. (ES).

1983-12-01

178

Single-Electrode Capacitance and Charged State in Interfacial Region within Nano-Porous Carbon Electrode for Electric Double Layer Capacitor; Kasseitan denki 2jyuso kyapasita no tankyoku seiden yoryo to koeki kaimen chikuden jyotai  

Energy Technology Data Exchange (ETDEWEB)

The single-electrode capacitance of a nano-porous carbon electrode used as an electric double layer capacitor was measured. The charged state of the electrolyte ion was discussed from the results. Single-electrode capacitance was not proportional to the specific surface area of the electrode. This implies that the whole surface of the electrode is not effective for the formation of an electric double layer. It is considered that edge orientation of the carbon structure would give a dominant contribution to capacitance. For measurements with aqueous solutions of various electrolytes, capacitance was about the same value for each salt compound. For aqueous acid solution, on the other hand, capacitance was twice to three times as large as that for salt compounds. This difference, however, became negligibly small if the concentration of electrolyte solution was lowered. Taking account of the hydrated ionic radius of each ion, it was considered that ions in salt ...

1997-07-10

179

Separation of the components of the binary mixture ethanol-water by steam flux in solid phase column; Separacao dos componentes da mistura binaria etanol-agua por passagem do vapor em coluna de fase solida  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

1987-12-31

180

Reducing indoor air formaldehyde concentrations  

Energy Technology Data Exchange (ETDEWEB)

Urea-formaldehyde resin bonded particle board, medium density fiberboard and plywood paneling are used as flooring, wall paneling, for cabinet work and in furniture, and are present in almost every office, home and public building. If large quantities of these products are used in poorly ventilated spaces, high manufacturing quality control is necessary to avoid problems of latent formaldehyde release. Indoor air formaldehyde concentrations depend on the nature of the product, the product surface to air volume (loading) factor, temperature, humidity, age and product emission rates. Standard test methods are now available for measuring product emission rates that make it possible to predict the performance of UF-bonded pressed wood materials if use conditions and environmental parameters are known. Recent modifications in adhesive and board manufacturing parameters have made it possible to reduce formaldehyde emission significantly, and ...

1985-08-01

181

Gas sensing behavior of SnO{sub 1.8}:Ag films composed of size-selected nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

Size-selected SnO{sub 1.8}:Ag mixed nanoparticle films have been prepared using a gas phase condensation method. Transmission electron microscopy showed that the applied size-selection technique yields well-defined, monodisperse and spherical SnO{sub 1.8} and Ag nanoparticles, both with a fixed diameter of 20 nm. The technique allows an independent variation of the particle size of both materials as well as the concentration of Ag. It allows to assess the influence of these parameters on the gas-sensing properties of the films, here for ethanol vapor in synthetic air. SnO{sub 1.8}:Ag nanoparticle films show optimal values of the sensor signal and response time at a Ag nanoparticle concentration of 5%. Due to the fact that the Ag nanoparticles are clearly distinct from the SnO{sub 1.8} nanoparticles in the film, the most probable mechanism leading to improved sensor properties is chemical sensitization via a spill-over ...

2006-12-15

182

Experimental and theoretical studies of nuclear generation of ozone from oxygen and oxygen--sulfur hexafluoride mixtures  

International Nuclear Information System (INIS)

A series of experimental measurements of the yield of O_3 in nuclear-induced O_2 and O_2-SF_6 discharges are reported. The discharges were created by bombardment with energetic particles from the "1"0B(n,#alpha#)"7Li reaction. Continuous irradiation at dose rates of 10"1"5--10"1"7 eV cm"-"3 s"-"1 and pulsed irradiation (--10 ms FWHM) at a peak dose rate of --10"2"0 eV cm"-"3 s"-"1 were conducted. At the lower dose rates, the addition of SF_6 generally increased the ozone yield due to the slowing of ozone destruction by negative oxygen and ozone ions. In contrast, at the high dose rates, the ozone concentration decreased due to SF_6 suppression of atomic oxygen formation by ion--ion recombination. A numerical model was developed and tested against experimental conditions. This model indicates that the steady-state ozone concentration was limited by the reaction O"-_3+O_3#->#2O_2+O"-_2 with a rate coefficient of --1 x ...

183

Char particle fragmentation and its effect on unburned carbon during pulverized coal combustion. Quarterly report, October 1, 1993--December 31, 1993  

Energy Technology Data Exchange (ETDEWEB)

The information reported is for the period October I to December 31, 1993. During this quarter, activities were undertaken in Task 2. Oxygen concentrations were measured in the post-flame region of the entrained flow reactor. The sampling probe was used for the hot gas tests to sample the gas stream. Samples were injected into a gas chromatograph to determine the oxygen concentration. Results agreed with thermoequilibrium calculations that yield equilibrium compositions based on the stoichiometry of the feed gases. The axial temperature distribution along the reactor centerline was measured using a silica-coated platinum-rhodium thermocouple. Two coating techniques were tested and it was found that flame-plating silica to the thermocouple wires produced a thinner coating than a ceramic adhesive technique and therefore a smaller radiation correction. Other activities this quarter included the fabrication of a solids sampling probe support ...

1994-02-01

184

Nitrite in dew, fog, cloud and rain water: An indicator for heterogeneous processes on surfaces  

International Nuclear Information System (INIS)

Nitrite was measured in atmospheric liquid phase samples between 1998 and 2005 to investigate the heterogeneous formation of nitrous acid in the lower atmosphere, as well as to assess the quality of water recovered from dew. The samples were collected during ground-based cloud field experiments at different German mountain sites (Brocken, Schmucke, and Hohenpeissenberg) and at a site south of the Bordeaux urban area (France). Concentrations found in Bordeaux dew samples (up to 2800 ?gl-1) are comparable to those found elsewhere in urban fog and dew water and considerably higher than those detected in cloud water or rain. Particulate nitrite (and nitrate) as well as HNO2 (HNO3) data in air masses from a foothill site of Mt. Schmucke, before involved in cloud processing, are also presented. In clouds at Mt. Brocken, both the interstitial HNO2 gas and the aqueous phase nitrite concentration have been measured simultaneous. Significant deviations ...

185

Experimental and theoretical studies of nuclear generation of ozone and its photolysis into singlet delta oxygen  

International Nuclear Information System (INIS)

A series of measurements of O_3 yield in nuclear induced O_2 and O_2-SF_6 discharges created by bombardment with energetic particles from the "1"0B(n,#alpha#)"7Li reaction are reported. Continuous irradiation at dose ratios of 10"1"5-10"1"7 eV.cm"-"3.s"-"1 and pulsed irradiation (approx.10 ms FWHM) at a peak dose rate of approx.10"2"0 eV.cm"-"3.s"-"1 were conducted. At the lower dose rates, SF_6 addition generally increased the ozone yield, which at the high dose rates, SF_6 addition decreased the observed ozone concentration. A numerical model was developed and applied to experimental conditions. The steady-state ozone concentration was found to be limited by the reaction O_3"- + O_3 #-># 2O_2 + O_2"-. A simplified analytical model of steady-state conditions was used to predict model sensitivity to various parameters. In addition to dose rate effects, pressure and temperature effect on ozone production were discussed. ...

186

Temperature-induced fusion of small unilamellar vesicles formed from saturated long-chain lecithins and diheptanoylphosphatidylcholine  

Energy Technology Data Exchange (ETDEWEB)

Small unilamellar vesicles which form when gel-state long-chain phosphatidylcholines are mixed with micellar short-chain lecithins undergo an increase in size as the long-chain species melts to its liquid-crystalline form. Analysis of the vesicle population with quasi-elastic light scattering shows that the particle size increases from 90-A radius to greater than 5000-A radius. Resonance energy transfer experiments show total mixing of lipid probes with unlabeled vesicles only when the Tm of the long-chain phosphatidylcholine is exceeded. This implies that the large size change represents a fusion process. Aqueous compartments are also mixed during this transition. 31P NMR analysis of the vesicle mixtures above the phase transition shows a great degree of heterogeneity with large unilamellar particles coexisting with oligo- and multilamellar structures. Upon cooling the vesicles below the Tm, the original size distribution (e.g., small ...

1989-10-03

187

Feasibility study of iron mineral separation from red mud by high gradient superconducting magnetic separation  

International Nuclear Information System (INIS)

Research highlights: #-># Red mud residues (RM) were disposed in alumina production. #-># Utilization of Red mud residues was affected by its iron content. #-># Superconducting magnetic separation (HGSMS) was used in iron separation from RM. #-># RM with high and low iron contents were separated in HGSMS. - Abstract: The disposal of bayer red mud tailings now seriously threats the environment safety. Reduction and recycling of red mud is now an urgent work in aluminum industry. High gradient superconducting magnetic separation (HGSMS) system was applied to separate the extreme fine RM particles (<100 #mu#m) into high iron content part and low iron content part. Two sorts of RM were fed in the HGSMS. The iron oxide contents in concentrates were about 65% and 45% when RM 1 and RM 2 were fed respectively. Meanwhile, the residues contained 52.0% or 14.1% iron oxide in residues after eight separation stages when RM 1 and RM 2 were fed ...

2011-02-01

188

Catalytic wet air oxidation of phenol over CeO{sub 2}-TiO{sub 2} catalyst in the batch reactor and the packed-bed reactor  

Energy Technology Data Exchange (ETDEWEB)

CeO{sub 2}-TiO{sub 2} catalysts are prepared by coprecipitation method, and the activity and stability in the catalytic wet air oxidation (CWAO) of phenol are investigated in a batch reactor and packed-bed reactor. CeO{sub 2}-TiO{sub 2} mixed oxides show the higher activity than pure CeO{sub 2} and TiO{sub 2}, and CeO{sub 2}-TiO{sub 2} 1/1 catalyst displays the highest activity in the CWAO of phenol. In a batch reactor, COD and TOC removals are about 100% and 77% after 120 min in the CWAO of phenol over CeO{sub 2}-TiO{sub 2} 1/1 catalyst at reaction temperature of 150 {sup o}C, the total pressure of 3 MPa, phenol concentration of 1000 mg/L, and catalyst dosage of 4 g/L. In a packed-bed reactor using CeO{sub 2}-TiO{sub 2} 1/1 particle catalyst, over 91% COD and 80% TOC removals are obtained at the reaction temperature of 140 {sup o}C, the air total pressure of 3.5 MPa, the phenol concentration of 1000 mg/L for 100 h continue ...

2008-05-30

189

Synthesis of Ln_0_._6Sr_0_._4Co_0_._8Fe_0_._2O_3_-_#delta# powders through glycine-nitrate combustion process  

International Nuclear Information System (INIS)

Solid oxide fuel cell (SOFC) is a promising source of power generation in terms of conversion efficiency which is higher than the conventional one, as it is not limited by the Carnot efficiency. Theoretically, the SOFC have an efficiency of the order of 60-80 % but it is limited by the number of active side available for the reaction i.e. TPB (triple phase boundary) at the electrode-electrolyte interface which depends on the particle size of the materials employed during the fabrication of SOFC components (i.e. the method employed during the synthesis). Literally, there are several methods used in the syntheses of oxide materials such as conventional solid-state reaction, co-precipitation, hydrothermal rout, sol-gel and Glycine nitrate process (GNP) but among these GNP found to be effective over the other because of homogeneity, phase purity and smaller particle size of final product. In this work, the Nano-crystalline ...

2010-12-01

190

Strong ionizing events distributed along medium energy #alpha# particle tracks recorded in nuclear emulsion  

International Nuclear Information System (INIS)

Track analysis of medium energy #alpha# particle trajectories recorded in fine grain nuclear emulsion submitted to specific intensifying treatments led to the observation of strong ionizing events (SIE) sticking out of the primary's track core. Preliminary determinations showed that the number of SIEs increases with the primary's energy, and that their production is of more than one order of magnitude higher than the number of Rutherford recoils. The presence of SIEs on monoenergetic #alpha# tracks also has a significant influence on the measured range distribution, which, expressed in terms of energy loss, results in a mean contribution to the total energy loss of far reaching (SIEs (radial spread >= 0.458 #mu#m) of proportional 25 keV per 13.6 MeV #alpha# particle, instead of 0.75 keV in the case where only the Rutherford interactions are taken into account. Measurements carried out in detectors enriched with gelatin indicate an increase ...

191

ON THE POSSIBILITY OF ENRICHMENT AND DIFFERENTIATION IN GAS GIANTS DURING BIRTH BY DISK INSTABILITY  

International Nuclear Information System (INIS)

We investigate the coupling between rock-size solids and gas during the formation of gas giant planets by disk fragmentation in the outer regions of massive disks. In this study, we use three-dimensional radiative hydrodynamic simulations and model solids as a spatial distribution of particles. We assume that half of the total solid fraction is in small grains and half in large solids. The former are perfectly entrained with the gas and set the opacity in the disk, while the latter are allowed to respond to gas drag forces, with the back reaction on the gas taken into account. To explore the maximum effects of gas-solid interactions, we first consider 10 cm size particles. We then compare these results to a simulation with 1 km size particles, which explores the low-drag regime. We show that (1) disk instability planets have the potential to form large cores due to aerodynamic capturing of rock-size solids in spiral arms ...

2010-11-20

192

Multiphase integral reacting flow computer code (ICOMFLO): User`s guide  

Energy Technology Data Exchange (ETDEWEB)

A copyrighted computational fluid dynamics computer code, ICOMFLO, has been developed for the simulation of multiphase reacting flows. The code solves conservation equations for gaseous species and droplets (or solid particles) of various sizes. General conservation laws, expressed by elliptic type partial differential equations, are used in conjunction with rate equations governing the mass, momentum, enthalpy, species, turbulent kinetic energy, and turbulent dissipation. Associated phenomenological submodels of the code include integral combustion, two parameter turbulence, particle evaporation, and interfacial submodels. A newly developed integral combustion submodel replacing an Arrhenius type differential reaction submodel has been implemented to improve numerical convergence and enhance numerical stability. A two parameter turbulence submodel is modified for both gas and solid phases. An evaporation submodel treats not only droplet ...

1997-11-01

193

Evaluation of a process for the decontamination of radioactive hotspots due to activated stellite particles  

International Nuclear Information System (INIS)

Some of the Indian pressurized heavy water reactors (PHWRs) which use Stellite balls in the ball and screw mechanism of the adjustor rod drive mechanism in the moderator circuit have encountered high radiation fields in the moderator system due to "6"0Co. Release of particulate Stellite is responsible for the hotspots in addition to the general uniform contamination of internal surfaces with "6"0Co. Extensive laboratory studies have shown that it is possible to dissolve these Stellite particles by adopting a three-step redox process with permanganic acid as the oxidizing agent. These investigations with inactive Stellite in powder form helped to optimize the process conditions. Permanganic acid was found to have the highest dissolution efficiency as compared to alkaline and nitric acid permanganate. The susceptibility of Stellite to corrode or dissolve was found to depend on the concentration of the permanganate, pH and temperature of the ...

2011-06-01

194

Electrodeposition and electrochemical characterisation of thick and thin coatings of Sb and Sb/Sb{sub 2}O{sub 3} particles for Li-ion battery anodes  

Energy Technology Data Exchange (ETDEWEB)

The possibilities to electrodeposit thick coatings composed of nanoparticles of Sb and Sb{sub 2}O{sub 3} for use as high-capacity anode materials in Li-ion batteries have been investigated. It is demonstrated that the stability of the coatings depends on their Sb{sub 2}O{sub 3} concentrations as well as microstructure. The electrodeposition reactions in electrolytes with different pH and buffer capacities were studied using chronopotentiometry and electrochemical quartz crystal microbalance measurements. The obtained deposits, which were characterised with XRD and SEM, were also tested as anode materials in Li-ion batteries. The influence of the pH and buffer capacity of the deposition solution on the composition and particle size of the deposits were studied and it is concluded that depositions from a poorly buffered solution of antimony-tartrate give rise to good anode materials due to the inclusion of precipitated Sb{sub 2}O{sub 3} ...

2007-12-20

195

Development of methodics for the characterization of the composition of the ion-collision-induced secondary-particle flux by comparison of the yield contributions of photoinduced ion formation processes; Entwicklung einer Methodik zur Charakterisierung der Zusammensetzung des ionenbeschussinduzierten Sekundaerteilchenflusses durch Vergleich der Ausbeuteanteile photoinduzierter Ionenbildungsprozesse  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work was to develop a method to distinguish between different ion formation processes and to determine the influence of these processes on the total number of detected monatomic ions of a certain element. A vector/matrix-formalism was developed, which describes the physical processes of sputtering, ion formation, mass separation and detection in laser-SNMS. In the framework of the method developed, based on this theoretic formalism, changes in the secondary flux contribution of the respective element were observed by comparing the detected monatomic ion yield obtained in specifically aligned (SIMS and) laser-SNMS experiments. The yields resulting from these experiments were used to calculate characteristic numbers to compare the flux composition from different surfaces. The potential of the method was demonstrated for the elements boron, iron and gadolinium by investigating the changes in the flux composition of secondary particles sputtered from ...

2008-10-13

201

Solid particle receiver experiments: velocity measurements  

Energy Technology Data Exchange (ETDEWEB)

Laser Doppler velocimetry and other photometric techniques are evaluated for measuring the average particle velocity in an ensemble of free-falling particles. The ability to obtain measurements in the presence of a radiant flux as high as 0.6 MW/m/sup 2/ was part of the evaluation. Optically dissimilar particles with diameters ranging from 0.1 mm to 1 mm were used in the study. Experimental results indicate that ensembles of particles do not behave as single isolated particles. The particle motion is dependent on particle volume fraction, and is quite unstable for falls greater than one meter.

1984-10-01

202

Solid particle receiver experiments: velocity measurements  

Science.gov (United States)

Laser Doppler velocimetry and other photometric techniques are evaluated for measuring the average particle velocity in an ensemble of free-falling particles. The ability to obtain measurements in the presence of a radiant flux as high as 0.6 MW/m/sup 2/ was part of the evaluation. Optically dissimilar particles with diameters ranging from 0.1 mm to 1 mm were used in the study. Experimental results indicate that ensembles of particles do not behave as single isolated particles. The particle motion is dependent on particle volume fraction, and is quite unstable for falls greater than one meter.

1984-10-01

203

Small world when building a particle detector prototype, the devil is in the tiny details  

CERN Multimedia

Small world when building a particle detector prototype, the devil is in the tiny details

2004-01-01

204

Particle-Sizing System for Scanning Electron Microscope ...  

Science.gov (United States)

... THESIS PARTICLE-SIZING SYSTEM FOR SCANNING ELECTRON MICROSCOPE IMAGES OF SOLID-PROPELLANT COMBUSTION EXHAUST ...

1991-03-01

205

Fragmentation of nuclei by particles and nuclei of intermediate and high energies  

Energy Technology Data Exchange (ETDEWEB)

The present state of investigations into the fragmentation of target nuclei by particles and nuclei of intermediate and high energies is reviewed.

1983-11-01

206

A thermographic method as an alternative for gravimetric determination of the particulate diesel emissions; Ein thermographisches Messverfahren als Alternative zur Gravimetrie bei der Ermittlung von Dieselpartikel-Emissionen  

Energy Technology Data Exchange (ETDEWEB)

The basis of assessment for particulate exhaust emissions is the gravimetric analysis of the particle concentration of diluted exhaust gases at temperatures below 52 C. This is very time consuming and takes sufficient sensitivity at low particulate emission rates like downstream of particle filters. For this reason the C/S-method, based on the thermographic analysis of carbon and sulfur, has been developed as an alternative to the gravimetric anallysis. This method yields particle mass as well as the main particle compounds. Comparisons between both methods have been carried out for heavy duty and automobile diesel engines as well as road vehicles and large diesel engines. The tests were conducted with commercial diesel fuel and also with other fuels, such as heavy oils. It could be shown that the C/S-procedure yields the same results as the gravimetric procedure independent of ...

1995-09-01

207

Loss of light charged particles by nuclear interactions in BaF[sub 2] crystals  

Energy Technology Data Exchange (ETDEWEB)

The nuclear interaction probability of light charged particles in BaF[sub 2] crystals has been studied as a function of the incident particle energy. Light charged particles were identified in charge and mass by measuring their magnetic rigidity and their time-of-flight. The percentage of particles undergoing nuclear interactions has been measured for particles of charge from Z=1 to Z=6 and the experimental data are compared with the results of a model calculation. (orig.)

1993-07-15

208

Research and development on inhalation toxicologic evaluation of red phosphorus/butyl rubber combustion products  

Energy Technology Data Exchange (ETDEWEB)

Combinations of exposure concentrations, durations and frequencies were tested in four-week inhalation exposures followed by two weeks of recovery to define the interactive effects of these variables on biologic responses and to select the most-sensitive biologic response parameters for the subsequent subchronic studies. Response surface modeling was used for the experimental design and statistical analysis of the data. Results of preliminary testing suggested that exposure duration and frequency did not have major effects. Subsequently, male and female Sprague-Dawley rats were exposed in separate studies to RP/BR aerosols ranging from 0.40 to 1.20 mg/1 or to filtered air for 2.25 hr/day on four days/week for four weeks. Test-atmosphere monitoring data demonstrated that aerosol concentrations were consistently within 4% of the target values and mean particle size ranged from 0.44-0.64 ..mu..m with mean sigma g's of ...

1984-12-01

209

Influence of local waste burning on atmospheric aerosol properties in urban environment  

International Nuclear Information System (INIS)

Aerosols affect the radiative energy budget on both the regional and global scales. The wavelength-dependent aerosol optical depth (AOD) is a fundamental determinant of the amount by which extra-terrestrial incoming sunlight and outgoing terrestrial radiation are being attenuated in the atmosphere. The present study addresses the influence of local waste burning on aerosol characteristics, black carbon (BC) aerosol mass concentration and spectral solar irradiance using ground-based measurements over the tropical urban environment of Hyderabad, India. AOD has been observed to be maximum during burning days compared to normal days. Aerosol size spectra suggest bimodal distributions during pre-and post-burning periods and trimodal distributions during burning periods. Angstrom wavelength exponent estimated from spectral variation of AOD suggested dominance of accumulation mode particle loading during burning days compared to normal days. Diurnal ...

2006-03-01

210

Numerical modelling of surface hydrology and near-surface hydrogeology at Forsmark. Site descriptive modelling SDM. Site Forsmark  

Energy Technology Data Exchange (ETDEWEB)

SKB is currently performing site investigations at two potential sites for a final repository for spent nuclear fuel. This report presents results of water flow and solute transport modelling of the Forsmark site. The modelling reported in this document focused on the near-surface groundwater, i.e. groundwater in Quaternary deposits and shallow rock, and surface water systems, and was performed using the MIKE SHE tool. The most recent site data used in the modelling were delivered in the Forsmark 2.3 dataset, which had its 'data freeze' on March 31, 2007. The present modelling is performed in support of the final version of the Forsmark site description that is produced during the site investigation phase. In this work, the hydrological modelling system MIKE SHE has been used to describe near-surface groundwater flow and the contact between groundwater and surface water at the Forsmark site. The surface water system at Forsmark is described with the one-dimensional ...

2008-09-15

211

Prototype development and testing of ultrafine grain NZP ceramics. Final report, July 28, 1995--April 27, 1997  

Energy Technology Data Exchange (ETDEWEB)

The goal of this project was to demonstrate that a new low-expanding ceramic (Ca{sub 0.6},Mg{sub 0.4})Zr{sub 4}(PO{sub 4}){sub 6}, hereafter referred to as CMZP, could be used as an exhaust manifold liner in off-road diesel engines and provide improved engine efficiency (by permitting higher engine operating temperature). This study has successfully demonstrated this improvement and further engine testing (and possible manufacturing) is presently underway at Caterpillar Inc. Laboratories. Basically this program involved two subcontracts: one to Virginia Tech to develop sintering procedures for CMZP, and one to Caterpillar, Inc. to develop slip casting procedures for CMZP. Nearly 100kg of CMZP were prepared by MATVA, Inc. and Virginia Tech for use by Caterpillar. Virginia Tech developed detailed sintering procedures for CMZP and Caterpillar developed slip casting procedures and manufactured several exhaust manifold elbows. These elbows have been cast into prototype cylinder heads and ...

1997-08-04

212

Powder collection apparatus/method  

Energy Technology Data Exchange (ETDEWEB)

Device for separating and collecting ultrafine atomized powder from the gas stream of a gas atomizing apparatus comprises a housing having an interior wall oriented at an angle relative to horizontal so as to form a downwardly converging, conical expansion chamber, an inlet conduit communicated to the expansion chamber proximate an upper region thereof for receiving the gas stream, and an outlet proximate a lower region of the expansion chamber. The inlet conduit is oriented at a compound inclined angle (with respect to horizontal) selected to promote separation and collection of powder from the gas stream in the expansion chamber. The compound angle comprises a first entrance angle that is greater than the angle of repose of the powder on the housing interior wall such that any powder accumulation in the inlet conduit tends to flow down the wall toward the outlet. The second angle is selected generally equal to the angle of the housing interior wall measured from ...

1994-01-11

213

Morphology and thermal properties of electrospun fatty acids/polyethylene terephthalate composite fibers as novel form-stable phase change materials  

Energy Technology Data Exchange (ETDEWEB)

The ultrafine fibers based on the composites of polyethylene terephthalate (PET) and a series of fatty acids, lauric acid (LA), myristic acid (MA), palmitic acid (PA), and stearic acid (SA), were prepared successfully via electrospinning as form-stable phase change materials (PCMs). The morphology and thermal properties of the composite fibers were studied by field emission scanning electron microscopy (FE-SEM) and differential scanning calorimetry (DSC), respectively. It was found that the average fiber diameter increased generally with the content of fatty acid (LA) in the LA/PET composite fibers. The fibers with the low mass ratio maintained cylindrical shape with smooth surface while the quality became worse when the mass ratio is too high (more than 100/100). Moreover, the latent heat of the composite fibers increased with the increase of LA content and the phase transition temperature of the fibers have no obvious variations compared with LA. In contrast, ...

2008-11-15

214

Microstructural evolution of the surface of Mg-Al-based alloy by hydrogen treatment  

Energy Technology Data Exchange (ETDEWEB)

The present paper describes the development of ultra-fine grains on the surface of AZ31 alloys caused by hydrogenation and dehydrogenation treatment, so-called HDDR process. Upon hydrogenation process, disproportionation reaction occurred in forming of MgH{sub 2}, Mg{sub 0.42}Al{sub 0.58}, and Al phases. In the following desorption process, the three phases were re-solved into the AZ31 alloy. As a result of the HDDR phenomena, the grain size of AZ31 alloy powders was reduced down to about 100 nm after the heat treatment at 350 C under a hydrogen pressure of 7 MPa for 24 h. The grain size tended to be increased with increasing process temperatures. In addition, the HDDR process was also applied to AZ31 alloy plates. By the HDDR process at 450 C, the grain size was reduced to less than 500 nm, where hydrogenated layer thickness was limited to be in the range of about 20 {mu}m from the surface. The Vickers hardness of AZ31 alloy plates was increased from 51.9 to 59.4 ...

2003-07-01

215

Leading research on supermetal. Part 1. Large-scale materials (iron system); Super metal no sendo kenkyu. 1. Ogata sozai (tetsukei)  

Energy Technology Data Exchange (ETDEWEB)

Supermetal with critical characteristics is under advanced investigation for further improvement of metal materials. Although iron is most frequently used as structural material among various metals, it should be used more carefully and effectively because of resource limitation and global environmental problem. It is essential to draw various excellent properties much more from iron and to improve recyclability. In particular, the best way to meet these requirements is achievement of more fine structure and higher purity. Since the lowest crystalline grain size is now limited to nearly 10{mu}m, metallic structure composed of grains below 1{mu}m is expected by mesoscopic control. Various methods have been studied to achieve ultra-fine crystalline structure, and study of precise heat treatment control and ultra-strength metallurgy is required. Heat treatment in magnetic field and layered structure by mechanical alloying are also promising. Drastic enhancement of ...

1996-03-01

216

Co-precipitated ZnAl2O4 spinel precursor as potential sintering aid for pure alumina system  

British Library Electronic Table of Contents (United Kingdom)

Ultra-fine ZnAl2O4 spinel hydrogel precursor synthesized from mixed salt solutions of Zn^2^+ and Al^3^+ ions using ammonium hydroxide-hexamethylenetetramine as basic media for co-precipitation was used as bonding material and sintering aid for pure alumina system. The hydrogel powder exhibited some well-defined ZnAl2O4 spinel phases at 800^oC. Alumina compacts were fabricated by incorporating small proportions of the precursor in alumina powder and firing at different temperatures (1350-1500^oC). The degree of densification was studied by measurement of fired shrinkage, apparent porosity, bulk density and cold crushing strength. Phase compositions and microstructural features of sintered samples were evaluated by XRD and SEM respectively. Addition of 0.2% hydrogel powder to alumina exhibit...

2010-01-01

217

Effect of radiation on some prepared polymeric moulds for use in environmental applications  

International Nuclear Information System (INIS)

The aim of this study is to prepare some polymeric moulds using Natural rubber latex (NRL)- portland cement composites based on a delayed-action mechanism. Factors affecting the preparation process such as concentration, mixing percentage, additives and their effects on what is regarded as a delayed-action coacervant combination was studied. The effect of Gamma-radiation on the mechanical properties of these moulds was investigated. The effect of natural aging on the prepared moulds was investigated to determine the possibility of using the prepared product in the construction field as expansion joints and cracks filling materials ...etc. The results may be summarized as follows: 1) Composites of natural rubber latex (NRL)-portland cement mould were prepared as two separate parts. The stabilized natural rubber latex (NRL) with hydroxy ethyl cellulose (HEC) as stabilizer and a delayed-action coacervant (sodium meta silicate) present in the rubber mixture was ...

218

Tree data structures for N-body simulation  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we study data structures for use in N-body simulation. We concentrate on the spatial decomposition tree used in particle-cluster force evaluation algorithms such as the Barnes-Hut algorithm. We prove that a k-d tree is asymptotically inferior to a spatially balanced tree. We show that the worst case complexity of the force evaluation algorithm using a k-d tree is {Theta}(n log{sup 3} n log L) compared with {Theta}(n log L) for an oct-tree. (L is the separation ratio of the set of points.) We also investigate improving the constant factor of the algorithm, and present several methods which improve over the standard oct-tree decomposition. Finally, we consider whether or not the bounding box of a point set should be {open_quotes}tight{close_quotes}, and show that it is only safe to use tight bounding boxes for binary decompositions. The results are all directly applicable to practical implementations of N-body algorithms.

1996-12-31

219

Treatment of produced water using hydrocyclones; Tratamento de agua produzida usando hidrociclone  

Energy Technology Data Exchange (ETDEWEB)

Beyond a great number of applications in mineral process, the hydrocyclone separation has been used recently in an increasing number of fields, such as: environmental engineering, petrochemical engineering, food engineering, electrochemical engineering, pulp bioengineering, processes and paper industries, among others. Nowadays, the produced water is treated and then reinjected in the surface and also in return to the formation. In the offshore platforms, the produced water can be directly discarded in the ocean, since the dispersed phase concentration (oil) is according to Brazilian regulating agency limits. The basic principle used in hydrocyclone separation is the centrifugal sedimentation machine: the suspended particles are submitted to centrifugal acceleration, which separates them from the fluid. The basic geometry of a hydrocyclone consists of four parts: a cylindrical section for feeding, a conical section for swirling, an overflow and ...

2008-07-01

220

The CO{sub 2} gasification kinetics of olive residue  

Energy Technology Data Exchange (ETDEWEB)

Orujillo, sometimes called wood matter from pressed oil-stone (WPOS) is a residue from the olive oil mill industry. The generation of this biomass residue is concentrated in small areas allowing its use as fuel for medium size gasification and combustion plants. Rates of gasification of WPOS char were measured in a TGA at various temperatures (800-850-875-900-950{sup o}C), CO{sub 2} partial pressures (0.20-0.35-0.50 bar) and CO partial pressures (0.0-0.20 bar). The experiments were carried out with a monolayer bed of very fine particles well exposed to the gas so as to minimise mass and heat transfer resistances. Two kinetic models, the nth order model and Langmuir-Hinshelwood model, have been used to fit with the reactivity data. For pure CO{sub 2} experiments the kinetic parameters of nth order model were E=133 kJ/mol and n=0.43. The Langmuir-Hinshelwood kinetic model clearly describes the observed CO inhibition effect on the CO{sub 2} ...

2003-02-01

221

Testing Effective Quantum Gravity with Gravitational Waves from Extreme-Mass-Ratio Inspirals  

CERN Document Server

Testing deviation of GR is one of the main goals of the proposed {\\emph{Laser Interferometer Space Antenna}}, a space-based gravitational-wave observatory. For the first time, we consistently compute the generation of gravitational waves from extreme-mass ratio inspirals (stellar compact objects into supermassive black holes) in a well-motivated alternative theory of gravity, that to date remains weakly constrained by double binary pulsar observations. The theory we concentrate on is Chern-Simons (CS) modified gravity, a 4-D, effective theory that is motivated both from string theory and loop-quantum gravity, and which enhances the Einstein-Hilbert action through the addition of a dynamical scalar field and the parity-violating Pontryagin density. We show that although point particles continue to follow geodesics in the modified theory, the background about which they inspiral is a modification to the Kerr metric, which imprints a CS ...

2009-01-01

222

Synthesis and characterization of MoO_3 nanostructures by solution combustion method employing morphology and size control  

International Nuclear Information System (INIS)

Molybdenum oxide nanostructures were synthesized utilizing the solution combustion method where the ammonium molybdate powder and an organic additive were used as precursors. Different organic additives including ethylene diamine tetra-acetic acid (EDTA), polyethylene glycol 200 (PEG 200), sorbitol and urea were used as surfactants in order to investigate the effect of additive structure on morphology and particle size of products. Also various reaction parameters such as the additive/Mo molar ratio, concentration of metal ion in solution, pH of the reaction, and temperature of the synthesis media were changed to study effects on product morphology and size. Outcomes were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction, and Transmission Electron Microscopy (TEM) techniques. Results show a variety of MoO_3 nanoparticles and nanorods produced within the size range of 10-80 nm. Furthermore, microrods and microsheets were ...

2010-05-01

223

Subcritical measurements using the /sup 252/Cf source-driven neutron noise analysis method  

Energy Technology Data Exchange (ETDEWEB)

This paper describes recent measurements of the subcritical neutron multiplication factor using the /sup 252/Cf source-driven neutron noise analysis method. This work was supported by a program of collaboration between the United States Department of Energy and the Power Reactor and Nuclear Fuel Development Corporation of Japan related to the development of fast breeder technology. The experiment reported consists of a configuration of two interacting tanks of uranyl nitrate aqueous solution with different uranium concentrations in each tank. The /sup 252/Cf-source-driven neutron noise analysis method obtains the subcriticality from the signals of three detectors: the first, a parallel plate ionization chamber with /sup 252/Cf electroplated on one of its plates that is located in or near the system containing the fissile material, and produces an electrical pulse for every spontaneous fission that occurs and thereby serves as a timed source of fission neutrons; and ...

1985-01-01

224

Study of iodine migration in zirconia using stable and radioactive ion implantation  

Energy Technology Data Exchange (ETDEWEB)

The large uranium fission cross section leading to iodine and the behaviour of this element in the cladding tube during energy production and afterwards during waste storage is a crucial problem, especially for {sup 129}I which is a very long half-life isotope (T=1.59 x 10{sup 7} yr). Since a combined external and internal oxidation of the zircaloy cladding tube occurs during the reactor processing, iodine diffusion parameters in zirconia are needed. In order to obtain these data, stable iodine atoms were first introduced by ion implantation into zirconia with an energy of 200 keV and a dose equal to 8 x 10{sup 15} at cm{sup -2}. Diffusion profiles were measured using 3 MeV alpha-particle Rutherford backscattering spectrometry at each step of the annealing procedure between 700 C and 900 C. In such experiments a reduced iodine concentration was observed, which correlated to a diffusion-like process. Similar analysis has been performed using ...

1998-03-01

225

Studies on accumulation of uranium by fungus Lentinus sajor-caju  

Energy Technology Data Exchange (ETDEWEB)

The untreated, heat- and alkali-treated Lentinus sajor-caju mycelia were used for the recovery of uranium from aqueous solutions. The effect of pH, temperature, initial concentration of UO{sub 2} {sup 2+} ions and contact time parameters were investigated in a batch system. The particles sizes of the fungal mycelia were ranging from 100 to 200 {mu}m. Biosorption equilibriums were established in about 30 min and the correlation regression coefficients show that the adsorption process can be well defined by the Freundlich equation. The alkali treated form had a high biosorption capacity (378 mg/g) than those of the untreated (268 mg/g) and heat-treated fungal mycelia (342 mg/g). Optimum biosorption was observed at pH 4.5 for all the tested fungal preparations and was independent of temperature (5-35 deg. C). In addition, the polarity and surface energy of the fungal biomass film preparations were determined by contact angle measurement. The ...

2006-08-21

226

Radiant{trademark} Liquid Radioisotope Intravascular Radiation Therapy System  

Energy Technology Data Exchange (ETDEWEB)

RADIANT{trademark} is manufactured by United States Surgical Corporation, Vascular Therapies Division, (formerly Progressive Angioplasty Systems). The system comprises a liquid {beta}-radiation source, a shielded isolation/transfer device (ISAT), modified over-the-wire or rapid exchange delivery balloons, and accessory kits. The liquid {beta}-source is Rhenium-188 in the form of sodium perrhenate (NaReO{sub 4}), Rhenium-188 is primarily a {beta}-emitter with a physical half-life of 17.0 hours. The maximum energy of the {beta}-particles is 2.1 MeV. The source is produced daily in the nuclear pharmacy hot lab by eluting a Tungsten-188/Rhenium-188 generator manufactured by Oak Ridge National Laboratory (ORNL). Using anion exchange columns and Millipore filters the effluent is concentrated to approximately 100 mCi/ml, calibrated, and loaded into the (ISAT) which is subsequently transported to the cardiac catheterization laboratory. The delivery ...

1998-01-16

227

ROTAMIX process for the biotreatment of soil contaminated with pentachloro-phenol and petroleum hydrocarbons  

Energy Technology Data Exchange (ETDEWEB)

The ROTAMIX process for the treatment of contaminated soils, developed by GSI Environment of Sherbrooke, Quebec, is described. The technology combines the use of a self-propelled rotary turner with bioactivating nutrients and structuring agents. Results of various trials using this process showed that soils contaminated with pentachlorophenol and heavy petroleum hydrocarbons, substances that do not easily break down, were decontaminated to a level that corresponds to the C criterion of the Quebec Ministry of the Environment. The ROTAMIX process was found to improve solid/liquid/gas exchanges, and increased water retention capacity of the treated soil. The technology is not constrained by the fine particle concentration that may result from the addition of structuring agents. It produces no leachate water or gaseous emissions. It broadens the range of contaminants that can be treated, including contaminants that resist biodegradation. The ...

1999-02-01

228

Produced water treatment using polymeric resins; Resinas polimericas para tratamento da agua produzida  

Energy Technology Data Exchange (ETDEWEB)

The treatment and disposal of oily waters from oil production and refining processes represent an important technological pass for attendance of the ambient legislation and to the politics of the Cia of search of the environmental excellence. The reuse or reinjection of the co-produced water has been considered an interesting strategical alternative, however, the water quality requirement for these processes demands a pretreatment step, considering the exit effluent from primary and secondary treatment processes currently used. This work presents resulted of the polymeric resin development for tertiary treatment of oily waters with low oil and grasses content and fine solids, including the dissolved fraction. These resins can adsorb, in reversible form, organic components. Its high adsorption capacity is determined by the polarity, superficial area, range of porosity and a wide distribution of particle size and pore. Another important characteristic is the ...

2008-07-01

229

PIXE analysis of GaAs and ZnSe  

Energy Technology Data Exchange (ETDEWEB)

The optoelectronic compounds of GaAs and ZnSe are difficult to analyze by PIXE (particle-induced X-ray emission) due to the strong absorption of the As and Se K{sub {alpha}} X-rays. As part of a program to investigate optoelectronic materials using ion beam techniques, we have explored the possibility of using the high sensitivity of PIXE to check these materials for stoichiometry and dopant concentrations. The K{sub {alpha}} X-ray intensity ratios of Ga to As and Zn to Se have been investigated using H beams of 0.5 to 2.5 MeV and He beams of 1.0 to 2.5 MeV. The variation in the X-ray intensity ratio with beam energy and target thickness is modelled in terms of the cross section for X-ray production and the absorption coefficients of the X-rays in the target. The results of this model show the experimental conditions that must be satisfied in order that the X-ray intensity ratios are not strongly affected by X-ray absorption; and therefore, the ...

1990-01-01

230

PIXE analysis of GaAs and ZnSe  

International Nuclear Information System (INIS)

The optoelectronic compounds of GaAs and ZnSe are difficult to analyze by PIXE (particle-induced X-ray emission) due to the strong absorption of the As and Se K_#alpha# X-rays. As part of a program to investigate optoelectronic materials using ion beam techniques, we have explored the possibility of using the high sensitivity of PIXE to check these materials for stoichiometry and dopant concentrations. The K_#alpha# X-ray intensity ratios of Ga to As and Zn to Se have been investigated using H beams of 0.5 to 2.5 MeV and He beams of 1.0 to 2.5 MeV. The variation in the X-ray intensity ratio with beam energy and target thickness is modelled in terms of the cross section for X-ray production and the absorption coefficients of the X-rays in the target. The results of this model show the experimental conditions that must be satisfied in order that the X-ray intensity ratios are not strongly affected by X-ray absorption; and therefore, the ...

1989-06-01

231

OECD/CSNI specialist meeting on advanced instrumentation and measurements techniques: summary and conclusions  

International Nuclear Information System (INIS)

This specialist meeting on Advanced Instrumentation and Measurements Techniques was held in Santa Barbara (USA) in 1997 and attracted some 70 participants in ten technical sessions and a session of the round table discussions, with a total of 41 papers. It was intended to bring together the international experts in multi-phase flow instrumentation, experiment and modeling to review the state-of-the-art of the two-phase flow instrumentation methods and to discuss the relation between modeling needs and instrumentation capabilities. The following topics were included: Modeling needs and future direction for improved constitutive relations, interfacial area transport equation, and multi-dimensional two-fluid model formulation; local instrumentation developments for void fraction, interfacial area, phase velocities, turbulence, entrainment, particle size, thermal non-equilibrium, shear stress, nucleation, condensation and boiling; global instrumentation developments ...

1997-03-17

232

Kinetic and isotherm studies of Cu(II) biosorption onto valonia tannin resin  

Energy Technology Data Exchange (ETDEWEB)

The biosorption of Cu(II) from aqueous solutions by valonia tannin resin was investigated as a function of particle size, initial pH, contact time and initial metal ion concentration. The aim of this study was to understand the mechanisms that govern copper removal and find a suitable equilibrium isotherm and kinetic model for the copper removal in a batch reactor. The experimental isotherm data were analysed using the Langmuir, Freundlich and Temkin equations. The equilibrium data fit well in the Langmuir isotherm. The experimental data were analysed using four sorption kinetic models - the pseudo-first- and second-order equations, the Elovich and the intraparticle diffusion model equation - to determine the best fit equation for the biosorption of copper ions onto valonia tannin resin. Results show that the pseudo-second-order equation provides the best correlation for the biosorption process, whereas the Elovich equation also fits the ...

2009-03-15

233

Incorporation of Reaction Kinetics into a Multiphase, Hydrodynamic Model of a Fischer Tropsch Slurry Bubble Column Reactor  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the development of a computational multiphase fluid dynamics (CMFD) model of the Fischer Tropsch (FT) process in a Slurry Bubble Column Reactor (SBCR). The CMFD model is fundamentally based which allows it to be applied to different industrial processes and reactor geometries. The NPHASE CMFD solver [1] is used as the robust computational platform. Results from the CMFD model include gas distribution, species concentration profiles, and local temperatures within the SBCR. This type of model can provide valuable information for process design, operations and troubleshooting of FT plants. An ensemble-averaged, turbulent, multi-fluid solution algorithm for the multiphase, reacting flow with heat transfer was employed. Mechanistic models applicable to churn turbulent flow have been developed to provide a fundamentally based closure set for the equations. In this four-field model formulation, two of the fields are used to track the gas phase (i.e., ...

2008-11-01

234

Hybridization and Modification of the Ni/C{sub 60} Composites  

Science.gov (United States)

Hybridization and thermal evolution of the Ni+C{sub 60} composites, deposited on Si(001) at room temperature, were studied using Scanning Electron Microscopy, {mu}-Raman spectroscopy and Rutherford Backscattering. As-deposited, the hybrid films exhibited a granular nano-structure with Ni nano-particles encapsulated in C{sub 60} polymerized rinds. The Ni and C (C{sub 60}) distributions in a top layer were found homogeneous with a stable Ni/C (C{sub 60}) ratio; in the larger depth the distributions were inhomogeneous and their ratio dramatically varied. At elevated temperatures, all structural parameters were changed. In the subsurface layer Ni- and C (C{sub 60})-rich zones were formed (due to the induced phase separation), C{sub 60}-molecules decayed and their fragments were transformed into amorphous carbon (a-C). The free volume distribution of the stressed hybrid matter was analyzed by the Hg marker that (in a form of vapors) in-diffused in to the samples. The ...

2009-03-10

235

Facile synthesis of additive-assisted nano goethite powder and its application for fluoride remediation  

Energy Technology Data Exchange (ETDEWEB)

The present article describes a novel synthesis route for nano-sized goethite ({alpha}-FeOOH) using hydrazine sulphate as an additive. The X-ray diffraction (XRD) peaks of synthesized powder matched well with those of {alpha}-FeOOH. Transmission electron microscopy (TEM) showed the particles of irregular shape in the range of 1-10 nm. Batch adsorption experiments for fluoride uptake were performed to study the influence of various experimental parameters such as contact time (10 min to 7 h), initial fluoride concentration (10-150 mg L{sup -1}), pH (2-11.6) and the presence of competing anions. The time data fitted well to pseudo-second-order kinetic model. The fluoride removal passed through broad maxima in pH ranges of 6-8. High adsorption capacity of 59 mg g{sup -1} goethite was obtained. The isothermic data fitted well to Freundlich model. The presence of other ions namely chloride and sulphate adversely affected fluoride removal. Fluoride ...

2010-02-15

236

Effects of the structural nature of the anionic additives on the rheological behavior of bentonite suspensions; Effets de la nature structurelle des additifs anioniques sur le comportement rheologique de suspensions de bentonite  

Energy Technology Data Exchange (ETDEWEB)

Different experimental measurements (Theology, granulometry, XRD) were carried out in order to study the main properties of bentonite suspensions in presence of anionic additives at different concentrations. These additives are: Sodium Dodecyl Sulfate (SDS) as surfactant, a flexible polymer (Sodium Carboxy Methyl Cellulose, CMC) and a semi-rigid polymer (Xanthan gum). It has been shown that the structural nature of anionic additive influences directly the mixtures viscoelastic and flow behavior. The steric effect of the surfactant modifies the Face-Edge interactions and yields changes of the mixtures rheological behavior at low deformation rates. Polymers act by coating each clay particle and prevent their agglomeration. Therefore, bentonite has no direct effect on the rheological behavior of the mixtures: the additives are responsible for the mechanisms of de-structuration and structure reorganization as well as the mixtures viscous and ...

2005-07-01

237

Analytical surveys on water quality of Trasimeno Lake: Definition of trophic levels; Indagine sulla qualita` delle acque del Lago Trasimeno: Definizione dei livelli trofici  

Energy Technology Data Exchange (ETDEWEB)

The previous judgment of eutrophic state, once proposed for the Trasimeno Lake (Umbria region, Italy), has been revised. According to Vollenweider-OECD classification criterion, the lake waters are at present to be classified as mesotrophic waters, with phosphorus limitation. However this level of moderate productivity results to be conditioned by the hydrochemical characteristics of the lake waters, that control phosphorus concentrations independently from the loading coming from the basin, and prevent dangerous and massive algal blooms. Different processes of chemical nature, regulating the phosphorus amount in the lake waters, are then reviewed: adsorption of P/P0(4) onto suspended materials, particularly clay mineral particles, and direct precipitation as hydroxylapatite or co-precipitation with carbonates, are found to be the principal mechanisms that determine chemical removal of phosphorus from the water column. A preliminary mass ...

1995-06-01

238

Agglomeration and reaction characteristics of various coal chars in fluidized-bed coal gasifier; Ryudoso sekitan gas ka ronai deno sekitan no gyoshu tokusei to hanno tokusei  

Energy Technology Data Exchange (ETDEWEB)

With relation to the coals delivered as common samples in the coal fundamental technology development project, an experimental study was conducted on agglomeration characteristics and reaction characteristics in the fluidized-bed coal gasifier. For the experiment, used was a fluidized bed gasifier inserted with a cone-shape dispersion plate with a nozzle in the center. After raising the temperature of the gasifier up to 773K, gasification was conducted sending to the gasifier air from the nozzle and steam from the dispersion plate. The mean particle diameter and gas concentration of chars were measured till the temperature reaches 1373K. As a result of the experiment, it was confirmed that the carbon conversion ratio increases with a decrease in coalification degree of the coal. Moreover, influence of the coal kind was markedly observed at the grid zone of the lower part of the bed, and it was clarified that the lower carbon content ratio the ...

1996-10-28

239

Formation of particles in combustion of biofuels  

International Nuclear Information System (INIS)

Biomass combustion is an important part in a sustainable energy system, but as well a source of submicron (particles < 1 #mu#m) particles in the air. Consequently, to obtain a good air quality together with increased biomass combustion there is a need for a better understanding of particle formation. This work is a part of a larger project about formation and emissions of particles from biofuel combustion. The report includes the work performed in the project during the year 2004. The aim of the project is to describe the release of inorganic components, which cause particle emissions, during combustion of single fuel particles of biofuel, e.g. wood pellets. The work is carried out by emission measurements, systematic combustion experiments and modelling work. The results are expected to contribute to the understanding of which parameters that influence the ...

240

X-RAY MICROANALYSIS OF A RADIOACTIVE PARTICLE WITH THE AID OF THE ELECTRON MICROSCOPE  

Science.gov (United States)

A radioactive particle was analyzed to discover the composition of the inactive material of the particle. The method uses the x-ray line spectrum of the K series caused by electron irradiation of the particle in the electron microscope. Iron and aluminum or silicon (the last two could not be distinguished) were found as inactive components in the particle. (D.L.C.)

1962-07-28

241

Method of removing entrained particles from flue gas and composition of matter  

Energy Technology Data Exchange (ETDEWEB)

A composition of matter to treat particles entrained in flue gas, is described comprising: a caustic liquid used to adjust resistivity of the entrained particles; and inert particulate matter supporting the caustic liquid for inhibiting chemical action of the caustic liquid until used to adjust the resistivity of the entrained particles, the inert particulate matter supporting sufficient caustic liquid to adjust the resistivity of the entrained particles.

1988-04-19

242

Metal nanoparticle inks  

Energy Technology Data Exchange (ETDEWEB)

Stabilized silver particles comprise particles comprising silver, a short-chain capping agent adsorbed on the particles, and a long-chain capping agent adsorbed on the particles. The short-chain capping agent is a first anionic polyelectrolyte having a molecular weight (Mw) of at most 10,000, and the long-chain capping agent is a second anionic polyelectrolyte having a molecular weight (Mw) of at least 25,000. The stabilized silver particles have a solid loading of metallic silver of at least 50 wt %.

2011-04-12

243

Magnetic flocculation and filtration  

Energy Technology Data Exchange (ETDEWEB)

A model is available in predicting flocculation frequencies between particles of various properties under the influence of a magnetic field. This model provides a basic understanding of fundamental phenomena, such as particle-particle and particle-collector interactions, occurring in HGMF (high gradient magnetic field), and will be extended to describe experimental data of particle flocculation and filtration and predict the performance of high- gradient magnetic filters. It is also expected that this model will eventually lead to a tool for design and optimization of magnetic filters for environmental, metallurgical, biochemical, and other applications.

1996-10-01

244

Trivalent chromium removal from wastewater using low cost activated carbon derived from agricultural waste material and activated carbon fabric cloth  

International Nuclear Information System (INIS)

An efficient adsorption process is developed for the decontamination of trivalent chromium from tannery effluents. A low cost activated carbon (ATFAC) was prepared from coconut shell fibers (an agricultural waste), characterized and utilized for Cr(III) removal from water/wastewater. A commercially available activated carbon fabric cloth (ACF) was also studied for comparative evaluation. All the equilibrium and kinetic studies were conducted at different temperatures, particle size, pHs, and adsorbent doses in batch mode. The Langmuir and Freundlich isotherm models were applied. The Langmuir model best fit the equilibrium isotherm data. The maximum adsorption capacities of ATFAC and ACF at 25 deg. C are 12.2 and 39.56 mg/g, respectively. Cr(III) adsorption increased with an increase in temperature (10 deg. C: ATFAC-10.97 mg/g, ACF-36.05 mg/g; 40 deg. C: ATFAC-16.10 mg/g, ACF-40.29 mg/g). The kinetic studies were conducted to delineate the effect of temperature, ...

2006-07-31

245

The mechanism of metal nanoparticle formation in plants: limits on accumulation  

Energy Technology Data Exchange (ETDEWEB)

Metal nanoparticles have many potential technological applications. Biological routes to the synthesis of these particles have been proposed including production by vascular plants, known as phytoextraction. While many studies have looked at metal uptake by plants, particularly with regard to phytoremediation and hyperaccumulation, few have distinguished between metal deposition and metal salt accumulation. This work describes the uptake of AgNO{sub 3}, Na{sub 3}Ag(S{sub 2}O{sub 3}){sub 2}, and Ag(NH{sub 3}){sub 2}NO{sub 3} solutions by hydroponically grown Brassica juncea and the quantitative measurement of the conversion of these salts to silver metal nanoparticles. Using X-ray absorption near edge spectroscopy (XANES) to determine the metal speciation within the plants, combined with atomic absorption spectroscopy (AAS) for total Ag, the quantity of reduction of Ag{sup I} to Ag{sup 0} is reported. Transmission electron microscopy (TEM) showed Ag ...

2009-08-15

246

Synthesis, structural characterization, and performance evaluation of resorcinol-formaldehyde (R-F) ion-exchange resin  

International Nuclear Information System (INIS)

The 177 underground storage tanks at the DOE's Hanford Site contain an estimated 180 million tons of high-level radioactive wastes. It is desirable to remove and concentrate the highly radioactive fraction of the tank wastes for vitrification. Resorcinol-formaldehyde (R-F) resin, an organic ion-exchange resin with high selectivity and capacity for the cesium ion, which is a candidate ion-exchange material for use in remediation of tank wastes. The report includes information on the structure/function analysis of R-F resin and the synthetic factors that affect performance of the resin. CS-100, a commercially available phenol-formaldehyde (P-F) resin, and currently the baseline ion-exchanger for removal of cesium ion at Hanford, is compared with the R-F resin. The primary structural unit of the R-F resin was determined to consist of a 1,2,3,4-tetrasubstituted resorcinol ring unit while CS-100, was composed mainly of a 1,2,4-trisubstituted ring. CS-100 shows the ...

2004-09-10

247

Performance evaluation of Magma Power Company's reinjection well No. 46-7 at the East Mesa KGRA, California  

Energy Technology Data Exchange (ETDEWEB)

The performance of the Magma Power Company's reinjection well No. 46-7 at East Mesa has been examined. Water was cooled to 100/sup 0/F(+-) to simulate total heat extraction and then tested using membrane filter flow procedures. The cooled water contains particles which are in the high colloid size range, and formation impairment by these particles is unlikely. There is evidence that acid soluble corrosion products and calcium compounds constitute about two thirds of the particulates, and that the acid insoluble residue contains precipitated silica, insoluble corrosion products, and possibly formation fines carried in the produced water. Under stabilized conditions, the suspended solids content of the water is less than 2 parts per million. However, during the frequent production well start ups, a higher concentration of suspended solids is carried in the produced water and into the injection well, conceivably ...

1980-02-01

248

Experimental studies of the turbulence structures of impinging reacting jets using time-resolved particle image velocimetry visualisation, hot wire anemometry and acoustic signal processing  

Energy Technology Data Exchange (ETDEWEB)

In this paper, the turbulence structures of premixed impinging jets are investigated by three different experimental techniques: time-resolved particle image velocimetry (TPIV) visualisation, hot wire anemometry (HWA) and acoustic signal processing. The focus is on the TPIV, with the other two techniques providing supplementary information. The 2-D velocities of the impinging jets were obtained by TPIV. The contour maps of velocity derivatives were computed to facilitate the visualisation of the turbulence structure of the reactant part of turbulent impinging flames. Particular attention was concentrated on the turbulence structures out of the burner nozzle and their interactions with the combustion process. It was found that the contour plots are effective in visualising time-dependent structures. It is demonstrated that the derivatives of the velocity field are able to reveal many otherwise hidden turbulence patterns. Test cases were designed ...

2000-12-01

249

U of C site vies for new particle accelerator  

CERN Multimedia

"American dominance in the study and development of high-energy particle physics may be seriously compromised, according to a report issued by the National Academy of Sciences, unless efforts are made to ensure that the next high-energy particle accelerator - the International Linear Collider (ILC) - will be constructed in the U.S.

2006-01-01

250

Search for free quarks at PEP  

Energy Technology Data Exchange (ETDEWEB)

The results of a search for fractionally charged particles produced in e/sup +/e/sup -/ annihilation at 29 GeV/c/sup 2/ are discussed. Results from cosmic-ray searches for fractionally charged particles, tachyons, and massive particles using the same detector are also presented.

1982-01-01

251

Particle creation if a cosmic string snaps  

CERN Document Server

We calculate the Bogolubov coefficients for a metric which describes the snapping of a cosmic string. If we insist on a matching condition for all times {\\it and} a particle interpretation, we find no particle creation.

1994-01-01

252

Characterization of Two Unique Cholesterol-Rich Lipid Particles Isolated from Human Atherosclerotic Lesions  

UK PubMed Central (United Kingdom)

The authors' laboratory, using histochemicalmethods, previously identified two types of cholesterol-containing lipid particles in the extracellular spaces of human atherosclerotic lesions, one particle...Full Text Available

1990-01-01

253

Thermal performance and design of a solid particle cavity receiver  

Energy Technology Data Exchange (ETDEWEB)

A model for energy transport in a solid particle cavity receiver is developed and applied to the design and analysis of a receiver for the Central Receiver Test Facility (CRTF), Albuquerque, New Mexico. The model gives thermal performance results - including particle temperatures, cavity efficiencies, and wall temperatures - which directly affect the economic and technical feasibility of a solid particle receiver. In addition, design criteria relevant to the configuration of a solid particle cavity receiver are developed. Results for CRTF indicate that at design conditions particle temperatures will exceed 1200/sup 0/K with cavity efficiencies on the order of 75%.

1985-04-01

254

Understanding and predicting soot generation in turbulent non-premixed jet flames.  

Energy Technology Data Exchange (ETDEWEB)

This report documents the results of a project funded by DoD's Strategic Environmental Research and Development Program (SERDP) on the science behind development of predictive models for soot emission from gas turbine engines. Measurements of soot formation were performed in laminar flat premixed flames and turbulent non-premixed jet flames at 1 atm pressure and in turbulent liquid spray flames under representative conditions for takeoff in a gas turbine engine. The laminar flames and open jet flames used both ethylene and a prevaporized JP-8 surrogate fuel composed of n-dodecane and m-xylene. The pressurized turbulent jet flame measurements used the JP-8 surrogate fuel and compared its combustion and sooting characteristics to a world-average JP-8 fuel sample. The pressurized jet flame measurements demonstrated that the surrogate was representative of JP-8, with a somewhat higher tendency to soot formation. The premixed flame measurements revealed that flame temperature has a ...

2010-10-01

255

The performance tests used the water scrubber for ruthenium rejection  

Energy Technology Data Exchange (ETDEWEB)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level {alpha} solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends on the ruthenium concentration, harmful ...

2002-11-01

256

The performance tests used the water scrubber for ruthenium rejection  

International Nuclear Information System (INIS)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level #alpha# solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends on the ruthenium concentration, harmful ...

257

The effect of hydrogen peroxide solution on SO2 removal in the semidry flue gas desulfurization process.  

Science.gov (United States)

The present study attempts to use hydrogen peroxide solution to humidify Ca(OH)(2) particles to enhance the absorption of SO(2) to achieve higher removal efficiency and to solve the valuable reuse of the reaction product in the semidry flue gas desulfurization (FGD) process. Experiments were carried out to examine the effect of various operating parameters including hydrogen peroxide solution concentration, Ca/S molar ratio and approach to adiabatic saturation temperature on SO(2) removal efficiency in a laboratory scale spray reactor. The product samples were analyzed to obtain semi-quantitative measures of mineralogical composition by X-ray diffraction (XRD) with reference intensity ratio (RIR) method and the morphology of the samples was examined by scanning electron microscope (SEM). Compared with spraying water to humidify Ca(OH)(2), SO(2) removal efficiency was improved significantly by spraying hydrogen peroxide solution of 1-3 wt.% to ...

2009-04-24

258

Technical description of parameters influencing the pH value of suspension absorbent used in flue gas desulfurization systems.  

Science.gov (United States)

As a result of the large limestone deposits available in Poland, the low cost of reagent acquisition for the largescale technological use and relatively well-documented processes of flue gas desulfurization (FGD) technologies based on limestone sorbent slurry, wet scrubbing desulfurization is a method of choice in Poland for flue gas treatment in energy production facilities, including power plants and industrial systems. The efficiency of FGD using the above method depends on several technological and kinetic parameters, particularly on the pH value of the sorbent (i.e., ground limestone suspended in water). Consequently, many studies in Poland and abroad address the impact of various parameters on the pH value of the sorbent suspension, such as the average diameter of sorbent particles (related to the limestone pulverization degree), sorbent quality (in terms of pure calcium carbonate [CaCO3] content of the sorbent material), stoichiometric surfeit of CaCO3 in ...

2010-08-01

259

On the influence of microstructure and carbide content of steels on the electrochemical dissolution process in aqueous NaCl-electrolytes  

Energy Technology Data Exchange (ETDEWEB)

The electrochemical dissolution behaviour of armco-iron and of the steels C15, C45, C60 and 100Cr6 in concentrated sodium chloride media has been investigated. Anodic metal dissolution experiments have been carried out using the flow channel cell (parallel plate reactor), the rotating cylinder electrode (RCE) and the capillary cell. The microstructure of the steel has been varied through variation of carbon content and heat treatment (e.g. soft annealed with globular carbides or pearlitic). Current-efficiency values have been obtained by gravimetric measurements in the current-density range from i=5 to 60 A/cm{sup 2}. For the soft annealed steels, the divalent ferrite dissolution in combination with electroless cementite removal dominates. For the pearlitic steels, the occurrence of oxygen evolution electronically conductive metal carbides or trivalent ferrite dissolution, depending on the current density applied, was detected. Microstructure dependent ...

2002-10-01

260

Interface dissolution control of the [sup 14]C profile in marine sediment  

Energy Technology Data Exchange (ETDEWEB)

The process of carbonate dissolution at the sediment-water interface has two possible end-member boundary conditions. Either the carbonate particles dissolve mostly before they are incorporated into the sediment by bioturbation (interface dissolution), or the vertical mixing is rapid relative to their extermination rate (homogeneous dissolution). In this study, a detailed radiocarbon profile was determined in deep equatorial Pacific sediment that receives a high rate of carbonate supply. In addition, a box model of sediment mixing was used to simulate radiocarbon, carbonate content, and excess thorium profiles that result from either boundary process following a dissolution increase. Results from homogeneous dissolution imply a strong, very recent erosional event, while interface dissolution suggests that moderately increased dissolution began about 10,000 years ago. In order to achieve the observed mixed layer radiocarbon age, increased homogeneous dissolution ...

1993-08-01

261

Hydrogen analysis by p-p scattering in geological material  

International Nuclear Information System (INIS)

It has been concluded by geologists that a significant amount of hydrogen is stored as point defects in nominally anhydrous minerals. Determination of the amount of hydrogen bound in these minerals is a step towards determining the total water content of the earth mantle as well as comprehending its internal water cycle. The possibility to measure hydrogen in thin geological samples by elastic p-p scattering has been investigated at the Lund Nuclear Microprobe. In this work the development of the experimental procedure and standardisation of data analysis is described. Special emphasis has been put into doing the data analysis as simple as possible and at the same time applicable to all sorts of thin samples, even those of unknown nature. A special annular surface barrier detector composed of two insulated detector halves, which are read out simultaneously, is used to detect the recoiled proton and the scattered proton in coincidence. Conditions on the difference in time and energy of ...

2004-06-01

262

Evaluation of cobalt mobility in soils from the Nevada Test Site  

Energy Technology Data Exchange (ETDEWEB)

Nuclear testing at and around the Nevada Test Site (NTS) resulted in widespread contamination from transuranic and other radionuclides, as well as from other toxic inorganic and organic contaminants. The type of contamination, including spatial distribution and type of radionuclides present, depends on the type of testing performed. Remediation of the contaminated areas is currently under way. The optimum in situ or ex situ remediation technology depends on the degree of interaction between the particular radionuclide, or contaminant in general, and the soil matrix, among other factors. The objective of this project was to evaluate the sorption affinity of NTS soils for common non-transuranic radionuclides. The sorption of cobalt (Co) on soils from two different areas of the NTS, namely the Little Feller and Cabriolet event sites, was studied. Experiments were conducted as a function of pH, solid concentration, total Co concentration, ionic ...

1996-09-01

263

Effect of energy intake on the metabolism of glucose and glutamine in rumen epithelial tissue  

International Nuclear Information System (INIS)

Ten Holstein steers (579 kg average body weight) were fed either alfalfa hay (12.2% crude protein) or a 90% concentrate diet to supply 14.2 or 25.2 Mcal ME respectively for a minimum of 28 days. Samples of rumen epithelial tissue were removed at slaughter from the anterior ventral sac, washed free of feed particles and transported to the laboratory in oxygenated Krebs-Ringer bicarbonate buffer (KRB; pH 7.4). Papillae were weighed (100-200 mg) in triplicate into flasks containing 3 ml KRB with 1 mM glutamine or 5 mM glucose and acetate (50 mM), propionate (25 mM), butyrate (15 mM), lactate (1 mM) and glucose (5 mM) or glutamine (1 mM) as competing substrates. A parallel set of flasks contained 1 or .5 #mu#Ci of [U-"1"4C]-glutamine or glucose respectively for "1"4CO_2 production. There were no interactions with dietary energy intake and substrate addition. Increasing the dietary energy intake increased (P < .01) rates of uptake, "1"4CO_2 ...

1986-04-13

264

Direct screening of tetracyclines in water and bovine milk using room temperature phosphorescence detection  

Energy Technology Data Exchange (ETDEWEB)

A fast and simple flow-through optosensor was designed and characterized for the direct screening of four tetracycline (TCC) antibiotics (tetracycline, oxytetracycline, chlortetracycline and doxycycline) in water and bovine milk samples. The proposed optosensor provides rapid binary yes/no overall responses, being appropriate for the screening of this family of antibiotics above or below a pre-set concentration threshold. The experimental set-up is based on a flow-injection manifold coupled on-line to a phosphorescence detector. Aliquots of the samples are pretreated with Eu(III) to form room temperature phosphorescent metal chelates and injected in the flow manifold. Those chelates are then on-line retained on a conventional flow-cell (packed with polymeric Amberlite XAD-4 particles) which is placed inside the cell holder of the phosphorimeter. After the emission is registered, the antibiotic-metal complexes are eluted from the packed resin ...

2007-04-18

265

CHEMICAL TECHNOLOGY DIVISION, UNIT OPERATIONS SECTION MONTHLY PROGRESS REPORT, JULY 1960  

Science.gov (United States)

A critical review of the literature revealed no experiments on uranyl ion transfer from an aqueous to a tributyl phosphate phase which positively measured the kinetics of the chemical reaction at the interphase. Drawing isorhythmic lines on a three component diagram gives a complex correlation for the compaction of three sizes of glass beads. Neither the use of thoria sols nor high feed solution concentrations of thorium nitrate gave any significant increase in mean particle diameters over those obtained from nitrate solutions of lower concentrations in flame denitration. A hydraulic film resistance has been detected in the anion exchange of uranyl sulfate into Dowex 2lK, and chloride elution was found to give a higher apparent uranium diffusion coefficient than nitrate elution. The rate of dissolution of mixed thorium-uranium oxides was determined as a function of the per cent of mixed oxides ...

1960-10-27

266

UARS Particle Environment Monitor (PEM) Level 3AT - Mirador - NASA  

Science.gov (United States)

May 11, 2011 ... The Particle Environment Monitor (PEM) on NASA's Upper Atmosphere Research Satellite (UARS) measures the type, amount, energy, and ...

269

Smooth Particle Hydrodynamics for Surf Zone Waves  

Science.gov (United States)

... Zou, S. and RA Dalrymple, ``Coastal Sediment Transport Simulation by Smoothed Particle Hydrodynamics,'' Journal of Waterways, Ports, Coastal ...

2011-05-15

270

Non-equilibrium particle emission in 45 MeV #alpha# particle bombardment of "1"5"9Tb  

International Nuclear Information System (INIS)

Mar 1982. p. 36-37. Germany Didelez, JP Paris-11 Univ., 91 - Orsay (France).

1982-03-01

271

Monosodium titanate particle characterization  

Energy Technology Data Exchange (ETDEWEB)

A characterization study was performed on monosodium titanate (MST) particles to determine the effect of high shear forces expected from the In-Tank Precipitation (ITP) process pumps on the particle size distribution. The particles were characterized using particle size analysis and scanning electron microscopy (SEM). No significant changes in particle size distributions were observed between as-received MST and after 2--4 hours of shearing. Both as-received and sheared MST particles contained a large percentage of porosity with pore sizes on the order of 500 to 2,000 Angstroms. Because of the large percentage of porosity, the overall surface area of the MST is dominated by the internal surfaces. The uranium and plutonium species present in the waste solution will have access to both interior and exterior surfaces. Therefore, uranium and plutonium loading should ...

1993-01-12

272

Mechanical properties of surface composite particles coated with finer particles; Hyomen hifukugata fukuto biryushiso no rikigaku tokusei  

Energy Technology Data Exchange (ETDEWEB)

The effect of the coated composite surface of particles on the mechanical properties of the powder bed was investigated. Polyethylene-silica surface composite powder was prepared at several coating ratios with Hybridizer. Various tests on mechanical properties of the powder bed were carried out with the prepared powder, and the following results were obtained: The ultimate tensile strength depends only on the cohesive force between particles, and the contact probability model of composite particles led to good agreement between the experimental and calculated values. The coefficient of internal friction and cohesive shear strength were influenced due to the interlocking effect of the surface roughness of composite particles. The effects of coating particles became small with dynamic properties like angle of repose. It is possible to control the mechanical properties in a step wise ...

1996-05-10

273

Experts worry US may lose leadership in particle physics  

CERN Multimedia

"Physics in the United States is in a crisis that the country may lose the leadership in basic particle research in coming years, a report of the National Research Council warned." (1 page)

2006-01-01

274

Airborne minerals and related aerosol particles: Effects on climate and the environment  

UK PubMed Central (United Kingdom)

Aerosol particles are ubiquitous in the troposphere and exert an important influence on global climate and the environment. They affect climate through scattering, transmission, and absorption of...Full Text Available

1999-03-30

275

High resolution alpha-particle spectroscopy using CR-39 plastic track detector  

Energy Technology Data Exchange (ETDEWEB)

A technique has been developed for high resolution alpha particle spectroscopy from track length determination in CR-39 plastic. On individual tracks an energy resolution deltaE close to the range straggling limit is obtainable. For 6 MeV alpha-particle deltaE is proportional 35 keV on individual particles and for groups of particles deltaE proportional 20 keV can be achieved using certain data selection criteria. At 100 keV on individual particles deltaE is proportional 20 keV. The analysis requires 1) a knowledge of the track-etch rate (Vsub(T))-range relationship and 2) a theoretical understanding of alpha-particle track structure in CR-39 as a function of particle energy, dip angle and degree of etching. The structure of alpha-particle etched tracks in CR-39 is described and two methods of analysis discussed. ...

1984-06-15

280

Test of superconducting Nb/Al bilayers as particle detectors  

Energy Technology Data Exchange (ETDEWEB)

Superconducting thin film particle detectors can be very attractive due to the low sensitivity to radiation damage. We describe the fabrication procedure and the characterization of Nb/Al bilayers as particle detectors. First steady and dynamical results are reported from tests of 5 MeV alpha-particle detection.

2000-04-07

281

Tachyons: may they have a role in elementary particle physics  

International Nuclear Information System (INIS)

The possible role of space-like objects in elementary particle physics (and in quantum mechanics) is reviewed and discussed, mainly by exploiting the explicit consequences of the peculiar relativistic mechanics of Tachyons. Particular attention is paid: (i) to tachyons as the possible carriers of interactions; (ii) to the possibility of ''vacuum decays'' at the classical level; (iii) to a Lorentz-invariant bootstrap model; (iv) to the apparent shape of the tachyonic elementary particles and its possible connection with the de Broglie wave-particle dualism. (author).

285

Random motion of a particle emitting and absorbing tachyons  

International Nuclear Information System (INIS)

Random motion of a particle, emitting and absorbing tachyons, is investigated. It is shown that if bradyon is in equilibrium with neutral gas, i.e. it absorbs and emits tachyons, which do not have any charges, tha particle with each absorption-emittance of a tachyon changes its energy and momentum, never varying its own mass, and as a result it moves like a brownian particle. Thus, bradyon, interacting with tachyon gas, increases its momentum continuously in agreement with the Einstein-Fokker-Planck type equation.

286
288

Higher harmonics of spontaneous radiation of ultrarelativistic channeled particles  

International Nuclear Information System (INIS)

The case of spontaneous radiation of channeled ultrarelativistic particles is considered when the dipolarity condition is not satisfied. The change of the particle longitudinal velocity affecting the maximum radiation frequency is included. The angular and frequency characteristics of the radiation for superhigh energies are studied for the first time. It is shown that there is an optimum energy at which the radiation density is maximum. The influence of the angle at which electrons enter a crystal and of the beam divergence on the radiation is investigated. The problem of quasichanneled particle radiation and also the radiation in axis-plane transitions are considered. (author).

1980-06-01

289

Handling boundary constraints for numerical optimization by particle swarm flying in periodic search space  

CERN Document Server

The periodic mode is analyzed together with two conventional boundary handling modes for particle swarm. By providing an infinite space that comprises periodic copies of original search space, it avoids possible disorganizing of particle swarm that is induced by the undesired mutations at the boundary. The results on benchmark functions show that particle swarm with periodic mode is capable of improving the search performance significantly, by compared with that of conventional modes and other algorithms.

2005-01-01

290

Grassmann-odd Nambu bracket on Grassmann algebra  

International Nuclear Information System (INIS)

... Ukraine) INIS-UA--107 211 p. PHYSICS OF ELEMENTARY PARTICLES AND

2006-09-19

294

Fibrous Carbon  

Science.gov (United States)

... was noted. It was reported that similar fibers also grew on particles of thermal carbon black at a temperature of 10500 and in an atmosphere ...

1963-05-10

295

Electromagnetic properties of generalized Majorana particles  

Energy Technology Data Exchange (ETDEWEB)

We prove a theorem stating that a massive Majorana particle (a CPT-self-conjugate particle) with arbitrary spin J can possess only an anapole moment and multipoles of that. We also show that massless Majorana particles, except those of spin (1/2, do not have any single-photon electromagnetic form factor.

1989-02-20

299

Concept of Plasma Spraying System for Solid Oxide Fuel Cell: Heating Studies of YSZ Particle in Plasma Jet  

International Nuclear Information System (INIS)

One of several methods to build YSZ electrolyte of SOFC is plasma spraying. This system heats particle to a melting point and then pushing them into target and forming a deposition. This paper presents heating studies of YSZ particle in plasma jet. By simple model it is shown that the required time such those YSZ particle with grain size of 50 ?m to be melt is around 12 x 10-4 second. (author)

2006-07-01

300

Climate Change: The Role of Particles and Gases  

ScienceCinema

...global warming ...the effects of global warming ...also the ? that global warming ...

302

Bragg curve spectroscopy detector for particle identification  

International Nuclear Information System (INIS)

The operation principle, construction and characteristics of the Bragg curve spectroscopy detector (BCS detector) are described. The electric field of the BCS detector is parallel to the particle trajectories. The detector was tested by 8.78 MeV and 6.02 MeV #alpha# particles from a ThC-ThC's source. The energy resolutions are 1.5% and 2.6% respectively for two groups of #alpha# particles, and the charge resolution is 2.7%. Further test experiments with heavy ions will be arranged.

303

Application of alpha-particle spectrometry in post-irradiation research and reprocessing  

Energy Technology Data Exchange (ETDEWEB)

Current applications of ..cap alpha..-particle spectrometry in post-irradiation research and reprocessing are reviewed. Implementation of procedures and techniques described in the literature to the particular samples at S.C.K./C.E.N. often results in a combined radiochemical method where ..cap alpha..-particle spectrometry is used to complement or enforce results obtained by other methods. Typical cases are reported and results obtained by different methods are compared to the results obtained by ..cap alpha..-particle spectrometry.

1984-04-01

304

A Leptonic-Hadronic Model for the Afterglow of Gamma-Ray ...  

Science.gov (United States)

... PHYSICS ATOMIC AND MOLECULAR PHYSICS AND SPECTROSCOPY NUCLEAR PHYSICS & ELEMENTARY PARTICLE PHYSICS. ...

2010-11-20

305

7 - NASA Technical Reports Server  

Science.gov (United States)

... where the total palladium concentration equals that of silicon, the concentrations of palladium associated with various palladium silicides (Pd(x)Si , ...

306

Non-linearity and hysteresis of Hall effect in magnetorheological suspensions with conducting carrier  

Energy Technology Data Exchange (ETDEWEB)

In this article a production method of a magnetorheological suspension composed with silicon steel particles of size 0.1-0.15 mm and 4% silicon content is described. Steel particles were dispersed in a conducting carrier of a by mixture of graphite particles with size 2-5 {mu}m and cedar wood oil. The filling factor of the suspension with the silicon steel particles and with graphite particles amounted to 0.25-0.40. Samples of this suspension were placed in a rectangular vessel with electrodes and used for the investigation of the Hall effect in magnetic field with induction 0-8 T, generated by Bitter-type magnet. A non-linear dependence of Hall voltage on the induction of the applied magnetic field and a hysteresis loop of this voltage in the shape of inclined digit eight were found. The causes of the observed effects is the ordering of silicon steel particles ...

2003-08-01

307

Magnetospheric particle acceleration and X-ray emission of pulsars  

CERN Document Server

The available data on isolated X-ray pulsars, their wind nebulae, and the supernova remnants which are connected to some of these sources are analyzed. It is shown that electric fields of neutron stars tear off charged particles from the surface of neutron star and trigger the acceleration of particles. The charged particles are accelerated mainly in the field of magneto-dipole radiation wave. Power and energy spectra of the charged particles depend on the strength of the magneto-dipole radiation. Therefore, the X-ray radiation is strongly dependent on the rate of rotational energy loss and weakly dependent on the electric field intensity. Coulomb interaction between the charged particles is the main factor for the energy loss and the X-ray spectra of the charged particles.

2007-01-01

308

Complex plasma: dusts in plasma  

International Nuclear Information System (INIS)

Dust particles in a plasma are charged negatively and are subject to various types of forces, including a drag force by plasma particles and a force due to the collective nature of a plasma. Dust particles are found in a sheath in laboratories balanced by the gravitational force and the electric force, while dust particles in space are ubiquitous, including planetary magnetospheres and interstellar space. Because of the novel nature of a complex system involving plasma particles and dust particles in a collective way, the dusty plasma is often called a complex plasma. The complex plasma is characterized by two distinctly different scales in time and in space. The plasma with electrons, ions and neutrals is characterized by the collective motion with a fast time scale and a short wavelength, while the dust particles move in a slow time scale ...

2007-04-21

309

Comparative study of three dimensional numerical simulations of particle dispersion in a turbulent air flow  

International Nuclear Information System (INIS)

This paper describes the study of particles' dispersion in an isotropic turbulent flow. The particle's motion and the turbulent flow characteristics are calculated independently. While the particles' displacement is computed by the author's code, the flow is simulated with a commercial code : PowerFLOW. The particles and the flow are coupled through the relative velocity component of the aerodynamic force. When the simulated flow is turbulent, a turbulence regeneration model is used in order to get the flow instantaneous velocity. Validation of the method is done by comparing the particles' dispersion obtained with experimental results from literature and with the results calculated by FLUENT. Good accordance is found between numerical studies and experimental results. However, comparison between results of PowerFLOW coupled to the author's code and results from FLUENT shows ...

2004-05-09

310

Acceleration of particles in pulsar magnetosphere and the X-ray radiation  

CERN Document Server

The available data of single X-ray pulsars, their wind nebulae, and the SNRs which are connected to some of these sources are analysed. It is shown that electric field intensity of neutron stars tears off charged particles from the surface of neutron star and triggers the acceleration of particles. The charged particles are accelerated mainly in the field of magnetodipole radiation wave. Power and energy spectra of the charged particles depend on the strength of the magnetodipole radiation. Therefore, the X-ray radiation is strongly dependent on the rate of rotational energy loss and weakly dependent on the electric field intensity. Coulomb interaction between the charged particles is the main factor for the energy loss and the X-ray spectra of the charged particles.

2004-01-01

311

Quantum Secure Direct Communication with Four-Particle Genuine Entangled State and Dense Coding  

Science.gov (United States)

A quantum secure direct communication scheme using dense coding is proposed. At first, the sender (Alice) prepares four-particle genuine entangled states and shares them with the receiver (Bob) by sending two particles in each entangled state to him. Secondly, Alice encodes secret information by performing the unitary transformations on her particles and transmits them to Bob. Finally, Bob performs the joint measurements on his particles to decode the secret information. The two-step security test guarantees the security of communication.

2009-07-01

312

Numerical prediction of flow field and particle trajectory in a hard disk drive  

Energy Technology Data Exchange (ETDEWEB)

A flow field and particle trajectory in a HDD (Hard Disk Drive) between two rotating disks in axisymmetric enclosures is investigated using CFD code FLUENT/UNS. The RNG k-{epsilon} model is used as a turbulent model. In this study, the flow field between two disks are symmetric, and the flow field near the enclosure is very complex. Cross stream vectors are shown both for blowing and no blowing from the hub. The larger a particle, the more fast the particle deposits at the walls. In the case of blowing from the hub, the more fast the particle deposits at the walls. (author). 9 refs., 12 figs., 1 tab.

1999-11-01

313

Multigroup transfer matrices for charged-particle and neutron-induced reactions Part III: Energy conservation and local deposition  

Energy Technology Data Exchange (ETDEWEB)

Energy conservation and local energy deposition are investigated in the context of coupled-particle (i.e., neutrons, gamma rays, and charged particles) transport analysis. For charged particles, the concept of group splitting the 1 = 0 transfer matrix to ensure both particle and energy conservation is introduced. Although these procedures are more complex than those found in the usual neutron or coupled-neutron gamma-ray problem, they yield a consistent approach for the calculation of local energy deposition.

1983-11-01

314

Multigroup transfer matrices for charged-particle and neutron-induced reactions Part III: Energy conservation and local deposition  

International Nuclear Information System (INIS)

Energy conservation and local energy deposition are investigated in the context of coupled-particle (i.e., neutrons, gamma rays, and charged particles) transport analysis. For charged particles, the concept of group splitting the 1 = 0 transfer matrix to ensure both particle and energy conservation is introduced. Although these procedures are more complex than those found in the usual neutron or coupled-neutron gamma-ray problem, they yield a consistent approach for the calculation of local energy deposition.

1983-01-01

315

Method for production of uranium dioxide particles from uranium hexafluoride by growing process in fluidized bed  

International Nuclear Information System (INIS)

Processes of production and purification (necessary for fabricating fuel elements) of powdery uranium dioxide with particle size up to 1000 #mu#m and more have been studied. Developed is continuous process of UO_2 production with above particle size by converting uranium hexafloride into UO_2 solid particles in fluidized bed while their interaction with water vapor and hydrogen on the uranium dioxide nucleus material. The method allows to conduct continuous selection from the apparatus of UO_2 powder fraction with particle size near 1000 #mu#m without nucleus material additional feed.

316

In-place testing of HEPA filter systems by the single-particle, particle-size spectrometer method  

Energy Technology Data Exchange (ETDEWEB)

This standard describes the procedure and equipment for in-place testing of HEPA filter systems by the single-particle, particle-size (SPPS) spectrometer method. This method provides the capability for evaluating the effectiveness (i.e., decontamination factor or DF) of systems consisting of one or more stages of HEPA filters against submicrometer aerosols in discrete particle-size ranges. It is particularly useful for testing of multi-stage HEPA filter installations and for testing of very large (50,000 cfm installed capacity) single-stage systems where it is desired to minimize the quantity of challenge aerosol required.

1981-12-01

317

Development of thin foil Faraday collector as a lost alpha particle diagnostic for high yield D-T tokamak fusion plasmas  

Energy Technology Data Exchange (ETDEWEB)

Alpha particle confinement is necessary for ignition of a D-T tokamak fusion plasma and for first wall protection. Due to high radiation backgrounds and temperatures, scintillators and semiconductor detectors may not be used to study alpha particles which are lost to the first wall during the D-T programs on JET and ITER. An alternative method of charged particle spectrometry capable of operation in these harsh environments, is proposed: it consists of thin foils of electrically isolated conductors with the flux of alpha particles determined by the positive current flowing from the foils. 2 refs., 3 figs.

1994-07-01

318

Compound nucleus contribution to the alpha particle scattering from "2"8Si  

International Nuclear Information System (INIS)

In the case of inelastic scattering of alpha particles to the 3"+ state, the averaged angular distributions show a characteristic shape, corresponding to the excitation of such an unnatural parity state by alpha particles in the compound nucleus process. The modified Hauser-Feshbach cross-section calculations give a good description of the averaged distributions for the alpha particle scattering to the 3"+ state and the compound nucleus parameters could be extracted. The calculations of the compounds nucleus contributions to the other states in the case of 24 MeV alpha particle scattering from "2"8Si show that this contribution is not negligible and in the case of the scattering to the 4"+ state seems to be dominant. (Z.M.).

319

Biogenic iron oxyhydroxide formation at mid-ocean ridge hydrothermal vents: Juan de Fuca Ridge  

Energy Technology Data Exchange (ETDEWEB)

Here we examine Fe speciation within Fe-encrusted biofilms formed during 2-month seafloor incubations of sulfide mineral assemblages at the Main Endeavor Segment of the Juan de Fuca Ridge. The biofilms were distributed heterogeneously across the surface of the incubated sulfide and composed primarily of particles with a twisted stalk morphology resembling those produced by some aerobic Fe-oxidizing microorganisms. Our objectives were to determine the form of biofilm-associated Fe, and identify the sulfide minerals associated with microbial growth. We used micro-focused synchrotron-radiation X-ray fluorescence mapping (mu XRF), X-ray absorption spectroscopy (mu EXAFS), and X-ray diffraction (mu XRD) in conjunction with focused ion beam (FIB) sectioning, and highresolution transmission electron microscopy (HRTEM). The chemical and mineralogical composition of an Fe-encrusted biofilm was queried at different spatial scales, and the spatial relationship between primary ...

2008-05-22

320

Radium concentration factors and their use in health and environmental risk assessment  

Energy Technology Data Exchange (ETDEWEB)

Radium is known to be taken up by aquatic animals, and tends to accumulate in bone, shell and exoskeleton. The most common approach to estimating the uptake of a radionuclide by aquatic animals for use in health and environmental risk assessments is the concentration factor method. The concentration factor method relates the concentration of a contaminant in an organism to the concentration in the surrounding water. Site specific data are not usually available, and generic, default values are often used in risk assessment studies. This paper describes the concentration factor method, summarizes some of the variables which may influence the concentration factor for radium, reviews reported concentration factors measured in marine environments and presents concentration factors derived from data collected in a study in ...

1991-01-01

321

Radium concentration factors and their use in health and environmental risk assessment  

Energy Technology Data Exchange (ETDEWEB)

Radium is known to be taken up by aquatic animals, and tends to accumulate in bone, shell and exoskeleton. The most common approach to estimating the uptake of a radionuclide by aquatic animals for use in health and environmental risk assessments is the concentration factor method. The concentration factor method relates the concentration of a contaminant in an organism to the concentration in the surrounding water. Site specific data are not usually available, and generic, default values are often used in risk assessment studies. This paper describes the concentration factor method, summarizes some of the variables which may influence the concentration factor for radium, reviews reported concentration factors measured in marine environments and presents concentration factors derived from data collected in a study in ...

1991-12-31

322

Product moisture after the centrifugation of coarse coal  

Energy Technology Data Exchange (ETDEWEB)

The presence of water in export coals increases transport and handling costs. Coarse (+0.5 mm) coal constitutes the majority of the product, and small changes in its final moisture content will have a significant effect on overall product moisture. An on-line moisture monitor was installed on a product belt immediately after a coarse coal centrifuge to continuously measure the moisture content of the coal from a single centrifuge. Basic studies were also conducted with a laboratory centrifuge specifically designed to characterize various coarse coal samples in terms of their water retention capacity. The moisture of the coarse coal (typically 6 to 9%) was found to vary by at least 1% at a particular plant, and by a number of percentage points between plants. An empirical model has been developed which can explain about 80% of the moisture variation from the 25 samples investigated. The rank of the coals ranged from 0.7 to 1.65% mean reflectance. The model identified four principle ...

1998-12-31

323

Stochastic Finsler D-particle Space-Time Foam Enhances Dark Matter Relics  

CERN Document Server

Within the context of space-time (D-particle) foam in string/brane-theory it is demonstrated that it is possible to generate non-extensive statistics. The D-particle foam model involves point-like brane defects (D-particles), which provide the topologically non-trivial foamy structures of space-time. The D-particles can capture and emit stringy matter and this leads to a recoil of D-particles. It is indicated how one effect of such a recoil of D-particles is a back reaction on the space-time metric of Finsler type which is stochastic. We show that such a type of stochastic space-time foam can lead to cosmological effects similar to those induced by modifications of particle distributions within the framework of Tsallis entropies. The restrictions placed on the free parameters of the Finsler type metric are obtained from solving the Boltzmann ...

2010-01-01

324

A new lagrangian particle method to describe turbulent flows of fully compressible ideal gases  

CERN Document Server

There are several approaches to describe flows with particles e.g. Lattice-Gas Automata (LGA), Lattice-Boltzmann method (LBM) or smoothed particle hydrodynamics (SPH). These approaches do not use fixed grids on which the Navier-Stokes equations are solved via e.g. finite volume method. The flow is simulated using a multitude of particles or particle density distributions, which interacts and due to statistical laws and an even more fundamental approach than the Navier-Stokes equation, the averaged flow variables can be derived. After a short summary of the most popular particle methods the new DMPC (Dissipative Multiple Particles Collision) approach will be presented. The DMPC-model eliminates some of the weak points of the established particle methods and shows high potential for more accurate CFD solution especially in areas where standard ...

2008-01-01

325

Plutonium distribution and remobilization in sediments of the Rhone River mouth (North-Western Mediterranean); Distribution et remobilisation du plutonium dans les sediments du prodelta du Rhone (Mediterranee nord-occidentale)  

Energy Technology Data Exchange (ETDEWEB)

The aim of the present study was to describe the distribution and remobilization of plutonium (Pu) in the sediments off the Rhone river mouth. Most of the {sup 238}Pu and {sup 239,240}Pu isotopes introduced into the Rhone River were discharged by the liquid effluents released from the Marcoule reprocessing plant, located 120 km upstream the river mouth. Due to its high affinity for particles and its long half life, {sup 238}Pu is a promising tracer to follow the dispersion of particulate matter from the Rhone River to the Mediterranean Sea. During the 3 REMORA cruises, sediment samples were specifically collected in the Rhone pro-delta area and more offshore on the whole continental shelf of the Gulf of Lions. The measurements of alpha emitters gave a first detailed spatial distribution of Pu isotope concentrations in surface sediments off the Rhone mouth. Using {sup 137}Cs concentrations and their correlations with Pu ...

2004-06-15

326

Effects of human serum on bacterial competition with neutrophils for molecular oxygen.  

Science.gov (United States)

A dialyzable factor(s) in human serum is known to stimulate gonococcal oxygen consumption. Its effect on other human pathogens was investigated. A 10% serum solution increased peak O2 consumption for Escherichia coli and Staphylococcus aureus to 157% (P less than 0.05) and 199% (P less than 0.02), respectively, of their O2 consumption when suspended in Hanks balanced salt solution, compared with a 356% increase for Neisseria gonorrhoeae with serum. Dialyzed serum lacked stimulatory capacity. Bacteria, serum, and neutrophils are often incubated to evaluate neutrophil bactericidal activity. Samples of 10(8) N. gonorrhoeae, S. aureus, and E. coli turned resazurin colorless (anaerobic conditions, Eh less than -42 mV) after 7.4, 13.3, and 15.1 min, respectively. Because neutrophil formation of reactive oxygen intermediates requires ambient O2, the effect of live bacteria and serum on this process was explored. After 5 min of incubation of 10(8) N. gonorrhoeae or S. aureus in 10% normal or ...

1986-06-01

327

Preparation of ZnO-Al2O3 Particles in a Premixed Flame  

DEFF Research Database (Denmark)

Zinc oxide (ZnO) and alumina (Al2O3) particles are synthesized by the combustion of their volatilized acetylacetonate precursors in a premixed air-methane flame reactor. The particles are characterized by XRD, transmission electron microscopy, scanning mobility particle sizing and by measurement of the BET specific surface area. Pure (?-)alumina particles appear as dendritic aggregates with average mobile diameter 43-93 nm consisting of partly sintered, crystalline primary particles with diameter 7.1-8.8 nm and specific surface area 184-229 m2/g. Pure zinc oxide yields compact, crystalline particles with diameter 25-40 nm and specific surface area 27-43 m2/g. The crystallite size for both oxides, estimated from the XRD line broadening, is comparable to or slightly smaller than the primary particle diameter. The specific surface area ...

2000-01-01

328

A model for estimating the hydraulic conductivity of granular material based on grain shape, grain size, and porosity  

Energy Technology Data Exchange (ETDEWEB)

Particle shape is an important parameter in numerous civil, environmental, and petroleum engineering applications. In ground-water flow, the shape of individual particles comprising the soil affects the soil`s pore size distribution and, hence, the important flow characteristics such as hydraulic conductivity and headloss. A model for delineating the relative importance of particle size, particle shape, and porosity, (and their interactions), in explaining the variability of hydraulic conductivity of a granular porous medium is developed and tested. Three types of porous media are considered in this work: spherical glass beads; granular sand; and irregularly shaped, shredded glass particles. A reliable method for quantifying the three-dimensional shape and packing of large samples of irregular particles based on their angle of repose is presented. The results of ...

1995-11-01

329

Size and morphology of heavy-duty vehicle particle emissions; Raskaan ajoneuvokannan hiukkaspaeaestoen koko ja morfologia - HD-PM  

Energy Technology Data Exchange (ETDEWEB)

Formation of particles from heavy duty diesel and CNG vehicles was studied in laboratory conditions. PM, nano and soot mode particle emissions formed from buses of Euro 2-5 -emission levels were studied in relation to age and type approval characteristics of the vehicle. Characteristic particle emission factors from city driving were obtained by driving the buses on VTT's heavy duty chassis dynamometer applying the transient Braunschweig city cycle. The vehicles were a representative set of Euro 2 to 3 emission categories, supplemented with Euro 4-5 (EEV) -targeted CRT, CNG and DPF cars. Particle number emissions from Euro 4 to 5 buses were 1/100-1/1000 and mass emissions 1/10-1/100 of those of the current fleet. Particle emission from natural gas buses and after an advanced CRT trap contained almost entirely liquid < 60 nm nano particles, which ...

2006-10-15

330

The combustion aerodynamics of a pulverized coal low NO{sub x} swirl burner in an industrial boiler  

Energy Technology Data Exchange (ETDEWEB)

This paper discusses the application of a Computational Fluid Dynamics (CFD) code (FLUENT) to predict temperature and velocity profiles, and particle trajectories in an industrial fired by a low NO{sub x} pulverized coal swirl burner. The predictions of the code were compared to experimental measurements of gas temperature, particle size distribution, and particle velocities. The diagnostics employed were a suction pyrometer and a Particle Counter Sizer Velocimeter Probe (PCSV-P). Good agreement was found between the temperature predictions and the measurements. In situ particle size distributions were predicted accurately using the Baum and Street model with a swelling factor of zero. The numerical modeling indicated that the Type II flow issued from the burner could be transformed into Type III flow, by eliminating swirl from the primary air stream, which provided the preferred ...

1996-12-31

331

Synthesis of magnetic particles via a cationic-anionic surfactant vesicle method  

Energy Technology Data Exchange (ETDEWEB)

In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe{sup 3+} and Fe{sup 2+}) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.

2006-10-15

332

Synthesis of magnetic particles via a cationic-anionic surfactant vesicle method  

International Nuclear Information System (INIS)

In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe"3"+ and Fe"2"+) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.

2006-10-01

333

New wear resistant composite material  

Energy Technology Data Exchange (ETDEWEB)

A composite material consisting of WC-Co particles in a steel matrix was fabricated by sintering mixtures of WC-Co particles and a steel powder and infiltrating the sintered pieces with a copper alloy. Its wear resistance and mechanical properties were studied as a function of the content in WC-Co particles and other characteristics of the composite material microstructure. Infiltration provided a simple means to obtain a strong cohesion between WC-Co particles and the steel matrix. An effective matrix protection against wear is obtained with relatively low additions of particles especially with a silica abrasive which is soft with respect to cemented carbide. The experimental results show that this material has good mechanical properties and wear resistance. Depending upon abrasion resistance, wear losses are reduced up to 10 times by a 30 vol% addition of cemented carbide ...

1983-01-01

334

Molecular dynamics study of TiO2/poly(acrylic acid-co-methyl methacrylate) and Fe3O4/polystyrene composite latex particles prepared by heterocoagulation  

British Library Electronic Table of Contents (United Kingdom)

All-atom molecular dynamics simulations were used to study the morphology of polymer/inorganic composite particles prepared by heterocoagulation. The results were also compared to those of our previous study of the preparation of TiO2/poly(acrylic acid-co-methyl methacrylate) and Fe3O4/polystyrene composite particles. In the simulation system, polymer or inorganic particles were simulated by surface-charge-modified C60 or Na atoms. Through a combination of analysis of the radial distribution functions of charged atoms and snapshots of the equilibrated structure, three kinds of particle distributions were observed under different conditions. When the polymer and inorganic particles had opposite surface charges and their sizes were very different, the composite morphology showed a core-shell...

2010-01-01

335

Impact of Hight Velocity Cold Spray Particles  

Energy Technology Data Exchange (ETDEWEB)

This paper presents experimental data and an computational model of the cold spray solid particle impact process. Copper particles impacting onto a polished stainless steel substrate are examined. The high velocity impact causes significant plastic deformation of both the particle and the sub- strate, but no melting is observed. The plastic deformation exposes clean surfaces that, under the high impact pressures, result in significant bond strengths between the particle and substrate. Experimental measurements of the splat and crater sizes compare well with the numerical calculations. It is shown that the crater depth is significant and increases with impact velocity. However, the splat diameter is much less sensitive to the impact velocity. It is also shown that the geometric lengths of the splat and crater scale linearly with the diameter of the impacting particle. It is hoped ...

1998-12-01

336

Experimental limits on quarks, tachyons, and massive particles in cosmic rays  

Energy Technology Data Exchange (ETDEWEB)

A large detector with high redundancy is used to search for various types of anomalous particles in cosmic rays at sea level. The detector is sensitive to zenith angles between 45/sup 0/ and 90/sup 0/. Previously obtained limits on the fluxes of charge (1/3) and (2/3) particles are reduced to 2.9 x 10/sup -10/ and 2.6 x 10/sup -10/ cm/sup -2/sr /sup -1/ sec/sup -1/, respectively. The flux of ionizing tachyons is determined to be less than 2.4 x 10/sup -9/ cm/sup -2/ sr/sup -1/ sec/sup -1/. The massive-particle flux limit we obtain is inconsistent with previous claims of such particles assuming that these particles are isotropic in zenith angle.

1982-10-01

337

Experimental limits on quarks, tachyons, and massive particles in cosmic rays  

International Nuclear Information System (INIS)

A large detector with high redundancy is used to search for various types of anomalous particles in cosmic rays at sea level. The detector is sensitive to zenith angles between 45"0 and 90"0. Previously obtained limits on the fluxes of charge (1/3) and (2/3) particles are reduced to 2.9 x 10"-"1"0 and 2.6 x 10"-"1"0 cm"-"2sr "-"1 sec"-"1, respectively. The flux of ionizing tachyons is determined to be less than 2.4 x 10"-"9 cm"-"2 sr"-"1 sec"-"1. The massive-particle flux limit we obtain is inconsistent with previous claims of such particles assuming that these particles are isotropic in zenith angle.

338

An experimental method for measurement of strain distribution between wood the flour particles and polymer matrix on micro-mechanical level  

British Library Electronic Table of Contents (United Kingdom)

Wood plastic composites (WPCs) are comprised of wood flour and thermoplastic polymer. The matrix is typically high-density polyethylene, poly (vinyl chloride), or polypropylene. The effect of morphology and micromechanics of wood flour particles on the mechanical performance of the bulk composite is a relatively unexplored area. The knowledge about the in situ properties of wood particles and the interfacial properties between the wood particles and the polymer matrix in the bio-composites is very limited. The objective of this work is to characterize the full-field deformation and strain distribution in and around wood particles embedded in polymer matrix. The mechanical tests are performed in small-scale tensile loading stage on thin composite samples containing 1-3 wood particles orient...

2011-01-01

339

A principle of charged particle trapping by RF electromagnetic field in the spherical cavity  

Energy Technology Data Exchange (ETDEWEB)

A new principle of particle trapping in the simple spherical cavity using both electric and magnetic components of radiofrequency electromagnetic field is proposed. The electric component of H {sub 12} oscillating mode drives the fast particle oscillations, while the magnetic component synchronously bends the trajectories to the cavity center. A specially developed theory of particle stability predicts dense and energetic electron cluster in the trap. Numerical simulations of particle dynamics in the complete electromagnetic field taking into account both space charge and particle-induced magnetic field are in good agreement with the analytic results, giving a density of 2.6*10{sup 1} electrons/cm{sup 3} and an average kinetic energy of around 30 keV at an operating frequency of 3 GHz. Being used at lower frequency, spherical cavity can trap protons and heavier ions too, but with ...

2005-11-21

340

The operation status and prospect of radioisotope production facility in HANARO  

Energy Technology Data Exchange (ETDEWEB)

Researches and production of radio-isotopes, radio-pharmaceuticals and cold kits are carried out in the Radio-isotope Production Facility (RIPF). Four concrete hot cells in Bank-1 are to produce the Ir-192 source for NDT. Eleven lead hot cells in Bank-2 are to produce Ho-166, Cr-51, P-32/33, Tc-99m, Lu-177, Sr-90/Y-90 and W-188/Re-188 for research purpose. Six lead hot cells in Bank-3 are used for the production of I-131 for diagnosis and therapy of cancer in the hospital. A hot cell in Bank-3 is also utilized for the research of I-125 and Br-82. Four lead hot cells in Bank-4 are utilized for the production of Mo-99/Tc-99m generators since 2005. The major systems including the Heat and Ventilated Air Conditioning (HVAC) system and the air cleaning system such as charcoal and HEPA filter trains to filter the radioactive contaminants are in operation. So are the systems such as power supply and distribution system, UPS, fire protection system, liquid radioactive waste collection systems. ...

2008-11-15

341

Target fabrication of low-density and nano porous materials to generate extreme ultraviolet (EUV)  

Energy Technology Data Exchange (ETDEWEB)

Our institute has been investigating laser-produced tin, lithium and xenon plasma for extreme ultraviolet (EUV) light source of EUV lithography system, and found the highest conversion efficiency of 3% at 13.5 nm in 2% bandwidth. In the present paper, we introduce fabrication methods of density-controlled tin targets to generate relatively monochromatic EUV, and higher conversion efficiency than bulk tin. The first method is the nano-template method, where liquid tin solution was immersed into a polymer film with monodispersed size nano-particle. The density can be controlled by tin concentration of the solution. The target can be classified into mass-limited target. We have shown a tendency of monochromatic EUV emission around 13.5 nm with decreasing of tin density. The intensity was higher than tin foil with bulk density. The tendency has a merit to mitigate heat effect of the first EUV mirror. The fabrication method has another merit to ...

2006-06-15

342

Target fabrication of low-density and nano porous materials to generate extreme ultraviolet (EUV)  

International Nuclear Information System (INIS)

Our institute has been investigating laser-produced tin, lithium and xenon plasma for extreme ultraviolet (EUV) light source of EUV lithography system, and found the highest conversion efficiency of 3% at 13.5 nm in 2% bandwidth. In the present paper, we introduce fabrication methods of density-controlled tin targets to generate relatively monochromatic EUV, and higher conversion efficiency than bulk tin. The first method is the nano-template method, where liquid tin solution was immersed into a polymer film with monodispersed size nano-particle. The density can be controlled by tin concentration of the solution. The target can be classified into mass-limited target. We have shown a tendency of monochromatic EUV emission around 13.5 nm with decreasing of tin density. The intensity was higher than tin foil with bulk density. The tendency has a merit to mitigate heat effect of the first EUV mirror. The fabrication method has another merit to ...

2006-06-01

343

Structure and magnetic properties of nanostructural strontium ferrite prepared by mechanochemical treatment  

International Nuclear Information System (INIS)

Full text: It was recently-established for hexagonal barium ferrite-industrially important magnetically hard material that refinement of the crystallite dimensions into the nanoscale regime, typically #<=# 10 nm, leads after heat treatment at temperatures 800-1000 deg C to significant coercivity increase of up to 6.5 kOe (#approx#3-4 times) with saturation magnetisation values of 50-55 emu/g (#approx#95% of bulk at room temperature). High-energy mechanochemical processing has been applied to prepare nanostructural (nanocrystalline-amorphous) composites. High resolution electron microscopy studies reveal that the enhancement of the final magnetic properties was due to formation of magnetically noninteracting #approx#l,#mu#m Ba-ferrite particles with 5-10 nm amorphous surface layer - depending on annealing parameters. Similar situation was established also for ball milled strontium ferrite (SrFe_1_2O_1_9) powders where short annealing 4 h at 1000 deg C produced ...

344

Structural, morphological and surface chemical features of Al{sub 2}O{sub 3} catalyst supports stabilized with CeO{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

Two families of CeO{sub 2}/Al{sub 2}O{sub 3} (ACE) catalyst supports, containing 3 and 20 % wt CeO{sub 2} respectively, have been examined and compared with the pure oxides CeO{sub 2} and (transition-phase) Al{sub 2}O{sub 3}. Structural data indicate that, also in the presence of CeO{sub 2}, the Al{sub 2}O{sub 3} support undergoes all phase transitions at the usual temperatures. Electron micrographs show that particles morphology and crystals size are mainly imposed by the Al{sub 2}O{sub 3} support. The porosimetric texture indicates a more pronounced meso-porosity in the ACE systems than in pure Al{sub 2}O{sub 3}, especially in the case of low CeO{sub 2} loadings. FTIR spectra and volumetric/calorimetric data of the adsorption of CO at {approx}300 K show that the surface Lewis acidity of aluminas is severely modified by the presence of CeO{sub 2}: the overall CO uptake is increased, there is the formation of one additional family of Lewis acid sites (Ce{sup 4+} ...

1995-12-31

345

Oxygen plasma treatment and deposition of CN_x on a fluorinated polymer matrix composite for improved erosion resistance  

International Nuclear Information System (INIS)

The use of polymer matrix composites in aerospace propulsion applications is currently limited by insufficient resistance to erosion by abrasive media. Erosion resistant coatings may provide necessary protection; however, adhesion to many high temperature polymer matrix composite (PMC) materials is poor. A low pressure oxygen plasma treatment process was developed to improve adhesion of CN_x coatings to a carbon reinforced, fluorinated polymer matrix composite. Fullerene-like CN_x was selected as an erosion resistant coating for its high hardness-to-elastic modulus ratio and elastic resilience which were expected to reduce erosion from media incident at different angles (normal or glancing) relative to the surface. In situ x-ray photoelectron spectroscopy was used to evaluate the effect of the plasma treatment on surface chemistry, and electron microscopy was used to identify changes in the surface morphology of the PMC substrate after plasma exposure. The fluorine ...

2007-07-01

346

LS&T and CMS FY 2004 Feasibility Proposal 04-FS-006 - Ceramic Laser Materials Interim Report - June 8, 2004  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this memo is to give an update on our work on ceramic laser materials--feasibility proposal 04-FS-006. Transparent ceramic materials have several major advantages over single crystals in laser applications including, ease and robustness of manufacturing, large apertures, design flexibility, fracture toughness, high activator concentrations, uniformity of composition, no residual stress, and others discussed in the proposal. After a decade of working on making transparent YAG:Nd in 1995 Japanese workers demonstrated samples for the first time that performed as well in lasers as their single crystal counterparts. Since then several laser materials have been made and evaluated. For these reasons, developing ceramic laser materials is the most exciting and futuristic materials topic in today's major solid-state laser conferences. The highlights and executive summary of our work to date are: (1) Ordered a slab of transparent YAG:Nd from Konoshima ...

2005-02-03

347

Formation of silk fibroin nanoparticles in water-miscible organic solvent and their characterization  

Energy Technology Data Exchange (ETDEWEB)

When Silk fibre derived from Bombyx mori, a native biopolymer, was dissolved in highly concentrated neutral salts such as CaCl{sub 2}, the regenerated liquid silk, a gradually degraded peptide mixture of silk fibroin, could be obtained. The silk fibroin nanoparticles were prepared rapidly from the liquid silk by using water-miscible protonic and polar aprotonic organic solvents. The nanoparticles are insoluble but well dispersed and stable in aqueous solution and are globular particles with a range of 35-125 nm in diameter by means of TEM, SEM, AFM and laser sizer. Over one half of the {epsilon}-amino groups exist around the protein nanoparticles by using a trinitrobenzenesulfonic acid (TNBS) method. Raman spectra shows the tyrosine residues on the surface of the globules are more exposed than those on native silk fibers. The crystalline polymorph and conformation transition of the silk nanoparticles from random-coil and {alpha}-helix form ...

2007-10-15

348

Field-effect research at the High Voltage Transmission Research Center  

Energy Technology Data Exchange (ETDEWEB)

This report presents information obtained during five different studies of field effects from high voltage transmission lines performed at EPRI's High Voltage Transmission Research Center. The first study is the development of a methodology for the evaluation of the expected frequency of occurrence of specific short-term effects of spark discharges and induced currents caused by overhead high voltage transmission lines. The methodology is divided into the analysis of the expected frequency of occurrence of situations in which induction effects may occur, and the analysis of the expected severity of the effect. The second study is of the electric field in the surface and on the immediate proximity of the strands of stranded conductors used for overhead high voltage lines. In particular, the cases of deformations of stranded conductors, caused by air expansion or by popped out strands, are analyzed for the purpose of determining the conditions for occurrence of corona in fair ...

1991-02-01

349

Fatigue tests on a ferritic-martensitic steel at 420 C: Comparison between in-situ and postirradiation properties  

Energy Technology Data Exchange (ETDEWEB)

Strain-controlled fatigue experiments under simultaneous irradiation have been performed to investigate the specific loadings of structural materials in next-step fusion devices. All irradiations were done on specimens made of the tempered ferritic/martensitic Cr steel MANET-I at 420 C using a 104 MeV [alpha]-particle beam. Continuous push-pull cycling (R=-1) has been applied with total strain ranges [Delta][epsilon][sub t] between 0.5 and 1.0%. Under in-beam conditions at e.g. [Delta][epsilon][sub t]= 0.5% a number of cycles to failure of N[sub f]=42000, a He concentration of 400 appm and a damage dose of 1.6 dpa has been reached. This N[sub f] is by about a factor of two below the average N[sub f]-value of unirradiated reference tests, but seven times higher than N[sub f] of comparable postirradiated specimens. It was found, that at least at 420 C conventional postirradiation tests are a conservative approach to in-situ conditions, and that ...

1994-09-01

350

Development of PtRu-CeO{sub 2}/C anode electrocatalyst for direct methanol fuel cells  

Energy Technology Data Exchange (ETDEWEB)

Ceria (CeO{sub 2})-modified PtRu/C catalysts with different compositions of Ru and CeO{sub 2}, viz. PtRu{sub 0.9}(CeO{sub 2}){sub 0.1}/C, PtRu{sub 0.7}(CeO{sub 2}){sub 0.3}/C and PtRu{sub 0.5}(CeO{sub 2}){sub 0.5}/C and unmodified PtRu/C catalyst were synthesized by the sodium borohydride reduction method. Transmission electron microscopic results indicated that the lower concentrated CeO{sub 2}-modified PtRu/C catalysts had almost a similar morphological structure (well-dispersed particles with size around 2.3-2.5nm) with that of the unmodified PtRu/C catalyst. X-ray diffraction and X-ray photoelectron spectroscopy analyses indicated the formation of PtRu alloy and presence of CeO{sub 2} in an amorphous form with a mixed oxidation states (Ce{sup 3+}-Ce{sup 4+}). Electro-catalytic activity of these catalysts for methanol oxidation was investigated by linear sweep voltammetry and chronoamperometry and it was found that the PtRu{sub 0.7}(CeO{sub ...

2006-06-01

351

DIVALENT ION EXCHANGE WITH ALKALI  

Energy Technology Data Exchange (ETDEWEB)

Exchange of hardness ions is important in enhanced oil recovery with chemical additives. In both micellar-polymer and caustic flooding processes, multivalent ions released from rock surfaces can interact with anionic surfactants, rendering them preferentially oil soluble and/or insoluble in water. Because hardness cations are sparingly soluble and precipitate in alkaline solutions, such solutions may be more efficient as surfactant flood preflushes than are softened brines. Multivalent ion precipitation may also occur in alkaline waterflooding. To permit design of such processes, this paper presents a chromatographic theory for simultaneous ion exchange with precipitation of divalent ions. Theoretical effluent histories and concentration profiles are presented for the cases of finite pulses and continuous injection of hydroxide ions into linear cores. Complete capture of the insoluble salt particles is assumed. Results are given for the case of ...

1980-05-01

352

An example of alkalization of SiO{sub 2} in a blast furnace coke  

Science.gov (United States)

Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} ...

2007-09-15

353

Translocation of particles to the pleural space and tracheobronchial lymph nodes following lung deposition  

Energy Technology Data Exchange (ETDEWEB)

The translocation of particles from the alveolar compartment to the pleural space and tracheobronchial lymph nodes was investigated in rats over a 30 day period following the intrapulmonary instillation of 4 x 10/sup 8/ polystyrene microspheres (1.9 ..mu..m dia.). In initial studies, approx. =10/sup 4/ particles were found in the pleural space compartment on Days 1, 14 and 30 after particle deposition, and most of these were cell-associated. Subsequent pleural space studies indicated, however, that the particles found in this compartment were, at least in part, due to the pleural lavage technique, and, unlike observations reported for some fibers, the translocation of the particles used in our study to the pleural space does not represent an important lung clearance pathway. In regard to particle clearance to the tracheobronchial lymph nodes, the accumulation of ...

1985-01-01

354

On the properties of plasma crystals  

Energy Technology Data Exchange (ETDEWEB)

When a plasma becomes contaminated by foreign particles, generically referred to as dust, the result is called a dusty plasma. At the present time there is a great deal of interest in dusty plasmas because of their roles in terrestrial and extra-terrestrial processes - semiconductor processing, high temperature fusion experiments, stellar formation and the rings of Saturn. This thesis is concerned with the role of dust in processing type plasmas. In the following experiments, artificial dust is introduced into a parallel electrode plasma chamber. Ions and electrons in the plasma charge the dust particles and they become suspended in the plasma due to the balancing of electric and gravitational forces. By illuminating the suspended dust with laser light and using an extremely high speed camera fitted with a macro lens to look at the scattered light, the dust particles are observed directly. Specially written computer ...

1999-07-01

355

DYNAMICS OF SOLIDS IN THE MIDPLANE OF PROTOPLANETARY DISKS: IMPLICATIONS FOR PLANETESIMAL FORMATION  

International Nuclear Information System (INIS)

We present local two-dimensional and three-dimensional hybrid numerical simulations of particles and gas in the midplane of protoplanetary disks (PPDs) using the Athena code. The particles are coupled to gas aerodynamically, with particle-to-gas feedback included. Magnetorotational turbulence is ignored as an approximation for the dead zone of PPDs, and we ignore particle self-gravity to study the precursor of planetesimal formation. Our simulations include a wide size distribution of particles, ranging from strongly coupled particles with dimensionless stopping time #tau#_s #ident to# #OMEGA#t_s_t_o_p = 10"-"4 (where #OMEGA# is the orbital frequency, t_s_t_o_p is the particle friction time) to marginally coupled ones with #tau#_s = 1, and a wide range of solid abundances. Our main results are as follows. (1) Particles ...

2010-10-20

356

Characterization and Source Term Assessments of Radioactive Particles from Marshall Islands Using Non-Destructive Analytical Techniques  

Energy Technology Data Exchange (ETDEWEB)

A considerable fraction of radioactivity entering the environment from different nuclear events is associated with particles. The impact of these events can only be fully assessed where there is some knowledge about the mobility of particle bound radionuclides entering the environment. The behavior of particulate radionuclides is dependent on several factors, including the physical, chemical and redox state of the environment, the characteristics of the particles (e.g., the chemical composition, crystallinity and particle size) and on the oxidative state of radionuclides contained in the particles. Six plutonium-containing particles stemming from Runit Island soil (Marshall Islands) were characterized using non-destructive analytical and microanalytical methods. By determining the activity of {sup 239,240}Pu and {sup 241}Am isotopes from their gamma peaks ...

2005-06-11

357

The oncogenic transforming potential of the passage of single ? particles through mammalian cell nuclei  

UK PubMed Central (United Kingdom)

Domestic, low-level exposure to radon gas is considered a major environmental lung-cancer hazard involving DNA damage to bronchial cells by α particles from radon progeny. At domestic exposure...Full Text Available

1999-01-05

358

Study of particles trapped by a magnetic field  

Science.gov (United States)

A new type of radiation which occurs when particles are accelerated in the field of a longitudinal wave and in a transverse magnetic field is studied. The characteristics of such spontaneous radiation are obtained, and the influence of collective effects on the radiation is analyzed. The application of the findings to the theory of free electron lasers is discussed. 8 references.

1986-01-01

360

Particle size effect on strength, failure, and shock behavior in polytetrafluoroethylene-Al-W granular composite materials  

Science.gov (United States)

The variation of metallic particle size and sample porosity significantly alters the dynamic mechanical properties of high density granular composite materials processed using a cold isostatically pressed mixture of polytetrafluoroethylene (PTFE), aluminum (Al), and tungsten (W) powders. Quasistatic and dynamic experiments are performed with identical constituent mass fractions with variations in the size of the W particles and pressing conditions. The relatively weak polymer matrix allows the strength and fracture modes of this material to be governed by the granular type behavior of agglomerated metal particles. A higher ultimate compressive strength was observed in relatively high porosity samples with small W particles compared to those with coarse W particles in all experiments. Mesoscale granular force chains of the metallic particles explain this unusual ...

2008-11-01

361

Out of Gear $10 billion particle collider hasn't smashed a thing, but scientists still have high hop  

CERN Multimedia

Out of Gear $10 billion particle collider hasn't smashed a thing, but scientists still have high hop

2009-01-01

362

Organization of Bacteriophage Tail-Like Particles in Cells of Chromobacterium violaceum  

UK PubMed Central (United Kingdom)

A strain of Chromobacterium violaceum has been isolated which produces bacteriophage tail-like particles in high numbers. The extracellular morphology and the intracellular arrangement...Full Text Available

1972-05-01

363

Numerical calculations on flow and behavior of pulverized coal and ash particles in 2-stage entrained-flow gasifier  

Energy Technology Data Exchange (ETDEWEB)

Flow fields, temperature distributions, and particle trajectories in a 2-stage entrained-flow gasifier are calculated using a CFD code, FLUENT. Realizable k- {epsilon} model is used as a turbulent model. Because of swirling flow there appear recirculation regions near the burners. The characteristics of flow fields and temperature distributions in the gasifier are dependent on the swirl number of the system. Mean residence time of the particles in the reductor is inversely proportional to particle size, particle density and swirl number. As the swirl number is increasing, the particles injected from the combustor burners approach the wall near the combustor burners, which prevents the particles from entering the reductor and thus attaching the reductor wall. If the lower combustor burner angle is larger than the higher combustor burner angle for a given swirl ...

2001-07-01

365

Multiplicity distribution of charged particles in cosmic-ray proton induced nuclear reaction  

International Nuclear Information System (INIS)

The measured result of charged multiplicity in cosmic-ray proton induced nuclear reaction from Chinese satellite emulsion is reported. The correlation of shower and heavy particles is discussed and compared with p-emulsion interactions.

1993-01-01

366

Energetic constraints on the creation of cell membrane pores by magnetic particles.  

UK PubMed Central (United Kingdom)

Naturally occurring and contaminant ferromagnetic and ferrimagnetic particles have been found within or near cells, and might allow pulsed magnetic fields to create transient cell membrane opening ("pores")....Full Text Available

1996-08-01

367

Effect of Particle Size on Compaction of Materials with Different Deformation Mechanisms with and without Lubricants  

UK PubMed Central (United Kingdom)

This work investigates the effect of excipient particle size on compaction properties of brittle, plastic and viscoelastic materials with and without added lubricants. Sieve cuts of Microcrystalline...Full Text Available

368

Dissipative particle swarm optimization  

CERN Document Server

A dissipative particle swarm optimization is developed according to the self-organization of dissipative structure. The negative entropy is introduced to construct an opening dissipative system that is far-from-equilibrium so as to driving the irreversible evolution process with better fitness. The testing of two multimodal functions indicates it improves the performance effectively

2005-01-01

369

Bragg curves of fission fragments in gases  

Energy Technology Data Exchange (ETDEWEB)

An unexpectedly high probability of collisions between the fission particles and the atoms in an ionization chamber along the entire particle track causes a strong fluctuation of the shapes of the Bragg curves. This fluctuation imposes an upper limit of the charge resolution ..delta..Z/Z which can be achieved.

1986-03-01

370

Biopersistence of nonfibrous mineral particles in the respiratory tracts of subjects following occupational exposure.  

UK PubMed Central (United Kingdom)

Transmission electron microscopy analysis (TEMA) was used to analyze the bronchoalveolar lavage fluid (BALF) of 262 subjects occupationally exposed (OE) to nonfibrous mineral particles (NFMP) and 42...Full Text Available

1994-10-01

371

Bacterial Particle Endocytosis by Epithelial Cells Is Selective and Enhanced by Tumor Necrosis Factor Receptor Ligands?  

UK PubMed Central (United Kingdom)

Bacterial pathogens use virulence strategies to invade epithelial barriers, but active processes of epithelial cells may also contribute to the endocytosis of microbial particles. To focus on the latter,...Full Text Available

2009-03-01

373

A plasma process for the synthesis of cubic-shaped silicon nanocrystals for nanoelectronic devices  

International Nuclear Information System (INIS)

Low pressure silane plasmas are known for their ability to synthesize silicon nanoparticles via gas phase nucleation. While in the past this particle formation has often been considered from the viewpoint of a contamination problem in semiconductor processing, we here describe a silane low pressure plasma that enables the synthesis of highly oriented, cubic-shaped silicon nanocrystals with a rather monodisperse size distribution. These silicon nanocubes have successfully been used in the manufacture of single nanoparticle vertical transistors. We discuss the advantages of this new paradigm of building nanoelectronic devices. The plasma synthesis process is characterized in more detail than in prior work. The particle nucleation, growth and shape evolution are studied. Results indicate that the process provides two spatially distinct zones: a diffuse plasma for particle growth and a constricted plasma zone for ...

2007-04-21

374

14 - NASA  

Science.gov (United States)

... and mean rainfall rates, Rm, in the liquid hydrometeor layers using the .... large latitudinal movement of cirrus cloud cover with the changing seasons. ... We study the statistical distribution of PSCs by particle composition using .... the high resolution Cloud Particle Imager (CPI) and standard PMS 2D-C and ...

375

Versatile charged particle activation technique for the analysis of the noble metals  

Energy Technology Data Exchange (ETDEWEB)

The general usefulness of neutron activation analysis (NAA) for samples containing the platinum group elements (PGE) and Au, either as major or trace constituents, is discussed. Charged particle activation is shown to be a viable or complementary alternative. Proton (6-10 MeV) and alpha particle (9-15 MeV) beams, produced in a tandem Van de Graaff accelerator, have been established to be the most effective choice. By taking advantage of the Coulomb barrier effect and the fact that many charged particle induced reactions have relatively large threshold values, the same instrumental technique can be applied, with minor modifications, to a wide range of materials.

1982-01-01

376

Versatile charged particle activation technique for the analysis of the noble metals  

Energy Technology Data Exchange (ETDEWEB)

The general usefulness of neutron activation analysis (NAA) for samples containing the platinum group elements and Au, either as major or trace constituents, is discussed. Charged particle activation is shown to be a viable or complementary alternative. Proton (6-10 MeV) and alpha particle (9-15 MeV) beams, produced in a Tandem van de Graaff accelerator, have been established to be the most effective choice. By taking advantage of the Coulomb barrier effect and the fact that many charged particle induced reactions have relatively large threshold values, the same instrumental technique can be applied, with minor modifications, to a wide range of materials.

1983-01-01

377

V51 Knight Shift in Fine V3Si Particles  

Science.gov (United States)

The Knight shift of vanadium (KV) in fine V3Si particles was studied. The average diameter (\\bar{d}) ranged from 60 to 8000 A. The strong temperature dependence of the KV characteristic of high-Tc A-15 compounds was weakened in the particles. KV at 77 K increased with a decrease in \\bar{d}. The above-mentioned trends were consistent with a broadening of the sharp peak in the electronic density of states around the Fermi energy in particles resulting from a perturbation of the surface.

1987-12-01

378

The viscoelastic composite with interface debonding  

British Library Electronic Table of Contents (United Kingdom)

The effect of particle/matrix interface debonding on composites consisting of elastic particles and viscoelastic matrix is studied. The interface debonding is represented by a nonlinear cohesive law for the high explosive PBX 9501. The Mori-Tanaka method gives the constitutive relation of the composite in terms of the properties of elastic particles, viscoelastic matrix, and nonlinear cohesive law for interfaces. For the example of a composite with spherical particles subject to hydrostatic tension, simple analytical expressions of the composite stress-strain relation are obtained. The strain rate and temperature have strong effects on the composite behavior. High strain rate and low temperature give high strength of the composite. However, the rate and temperature effects decrease as the ...

2008-01-01

379

The Pinch Technique and its Applications to Non-Abelian Gauge Theories  

CERN Document Server

Describes the Pinch Technique for constructing Green's functions for elementary particle theorists and graduate students.

2010-01-01

380

Tachyons: may they have a role in elementary particle physics  

Energy Technology Data Exchange (ETDEWEB)

The possible role of space-like objects in elementary particle physics (and in quantum mechanics) is reviewed and discussed, mainly by exploiting the explicit consequences of the peculiar relativistic mechanics of Tachyons. Particular attention is paid: (i) to tachyons as the possible carriers of interactions; (ii) to the possibility of ''vacuum decays'' at the classical level; (iii) to a Lorentz-invariant bootstrap model; (iv) to the apparent shape of the tachyonic elementary particles and its possible connection with the de Broglie wave-particle dualism. (author).

1985-01-01

382

Saturn's Recycling Rings - Cassini Solstice Mission - NASA  

Science.gov (United States)

Dec 12, 2007 ... This is an artist concept of a close-up view of Saturn's ring particles.

383

STUDY AND MODIFICATION OF CONVECTIVE STORMS  

Science.gov (United States)

... small water or ice particles by impaction ... flight recording; principally the hydrometeor charge unit ... capability of directing aircraft movements by radio ...

1963-06-30

384

Rapid and continuous hydrothermal crystallization of metal oxide particles in supercritical water  

Energy Technology Data Exchange (ETDEWEB)

This paper reports on hydrolysis of 10 metal salt aqueous solutions of 6 metal oxides that was conducted in supercritical water. Continuous and rapid production of metal oxide fine particles was achieved by mixing a metal salt aqueous solution with preheated water fed from another line. The reaction time required was less than 2 min. Particle size, morphology, and crystal structure of the obtained metal (hydrous) oxides were examined. Particle size (20 to 600 nm) was different among the system but the size range was relatively narrow in all the cases.

1992-04-01

385

Radionuclide particle transport, sedimentation and resuspension in the Forsmark and Laxemar coastal regions  

Energy Technology Data Exchange (ETDEWEB)

In the safety assessment of a potential repository for spent nuclear fuel, it is important to assess the consequences of a hypothetical leak of radionuclides through the seabed and into a waterborne transport phase. Radionuclides adsorbed to sediment particles may be transported great distances through the processes of sedimentation and resuspension. This study investigates the transport patterns of sediment particles of two different sizes, released in the Forsmark and Laxemar area. The results show that the closed waters around Forsmark to a higher degree makes the particles stay in the area close to the release points

2007-12-15

386

Past, present and future of elementary particle physics  

International Nuclear Information System (INIS)

The 'elementary' particle physics began in 1935, when Hideki Yukawa published his pioneering pi-meson theory, and the problem of strong interaction was finally solved 40 years later by the establishment of the Standard Model. The composite models of hadrons by the Sakata school and Sin-itiro Tomonaga's renormalization theory for quantum electrodynamics played essential roles for finding this beautiful solution. It is really surprising that it took only 40 years to solve such desperately difficult problem. The 'elementary' particle physics then split into two new fields, quark-hadron physics' and 'unified (ultimate) theory of particle physics', which are now 30 years old already. (author)

2006-12-01

387

Particle emission in hydrodynamics: a problem needing a solution  

CERN Document Server

A survey of various mechanisms for particle emission in hydrodynamics is presented. First, in the case of sudden freeze out, the problem of negative contributions in the Cooper-Frye formula and ways out are presented. Then the separate chemical and thermal freeze out scenario is described and the necessity of its inclusion in a hydrodynamical code is discussed. Finally, we show how to formulate continuous particle emission in hydrodynamics and discuss extensively its consistency with data. We point out in various cases that the interpretation of data is quite influenced by the choice of the particle emission mechanism.

2004-01-01

388

Particle Entrainment Simulator at the US Army Engineer ...  

Science.gov (United States)

... operation, experimental data reduction, and application of PES results to studies related to estuarine and coastal sediment transport problems are ...

2005-09-01

389

One-particle characteristics in problems with allowance for complex configurations  

Energy Technology Data Exchange (ETDEWEB)

A method for the determination of different ''bare'' characteristics of the one-particle motion and one-particle basis in magic nuclei is described. The method is based on separating out the mixing with phonons from the phenomenological one-particle characteristics. By means of a generalization of the procedure for localization of the mass operator, relations linking the bare and phenomenological characteristics are obtained. The radial dependence of these characteristics in finite nuclei and the influence of the quasiparticle--phonon interaction on the phenomenological characteristics are studied. Calculations are performed for the neutrons in /sup 208/Pb.

1986-09-01

390

Numerical study of Cosmic Ray Diffusion in MHD turbulence  

CERN Document Server

We study diffusion of Cosmic Rays (CRs) in turbulent magnetic fields using test particle simulations. Electromagnetic fields are produced in direct numerical MHD simulations of turbulence and used as an input for particle tracing, particle feedback on turbulence being ignored. Statistical transport coefficients from the test particle runs are compared with earlier analytical predictions. We find qualitative correspondence between them in various aspects of CR diffusion. In the incompressible case, that we consider in this paper, the dominant scattering mechanism occurs to be the non-resonant mirror interactions with the slow-mode perturbations. Perpendicular transport roughly agrees with being produced by magnetic field wandering.

2010-01-01

392

Meteorologial Techniques  

Science.gov (United States)

... 2-93 An Atmospheric Particle Emits Electromagnetic ... atmospheric water vapor produces a hydrometeor. ... subject to wind movement (either blowing ...

2003-06-13

394

High Resolution Mesoscale Weather Data Improvement to ...  

Science.gov (United States)

... that defines hydrometeor categories for the duration of the simulation ... and to observe the movement of any particular system ... particle settling occurred ...

2007-03-01

395

Evaluation of Daytime Boundary Layer Heights from a ...  

Science.gov (United States)

... the vertical beam measures the movement of the ... be measured because the particle velocity in ... During precipitation, if the hydrometeor fall velocity is ...

2008-03-01

396

Emission of light charged particles accompanying uranium fission induced by 153-MeV protons  

Energy Technology Data Exchange (ETDEWEB)

The emission of light charged particles from heavy fragments of uranium fission induced by 153-MeV protons is studied. The probability of their emission is 2.7 x 10{sup - 2} per fission event. It is found that these particles affect the distribution of angles of fragment divergence and the angular distribution of heavy fragments with respect to the primary-proton beam. Experimental results suggest that the preequilibrium emission of particles is correlated with fission. Two mechanisms of interaction between 153-MeV protons and uranium nuclei are considered. 13 refs., 10 figs., 1 tab.

1995-12-01

397

Electrical properties of airborne nanoparticles produced by a commercial spark-discharge generator  

International Nuclear Information System (INIS)

A nanoparticle generator based on the principle of electrical discharge (PALAS GFG-1000) was used to produce nanoparticles of different chemical natures. The fractions of electrically neutral particles were then measured by means of a Spectrometre de Mobilite Electrique Circulaire (SMEC, i.e. radial-flow mobility analyzer) for different operating conditions. The experimental results were compared with the theoretical values calculated from the Fuchs extended charge equilibrium model for spherical particles and agglomerates. For the smallest particles (below 20 nm), the deviations observed remain below 10%, and tend towards 20% for larger particles (over 35 nm).

2010-08-01

398

EFFECTS OF QUARTZ PARTICLE SIZE AND SUCROSE ADDITION ON MELTING BEHAVIOR OF A MELTER FEED FOR HIGH-LEVEL GLASS  

Energy Technology Data Exchange (ETDEWEB)

The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had ...

2010-07-28

399

Deuteron break-up by the 27.2 MeV- alpha particle  

International Nuclear Information System (INIS)

Russian 1974. USSR Grantsev, VI Dryapachenko, IP Kornilov, VA Nemets,

1974-01-29

400

Deuteron break-up by the 27,2 MeV-alpha particle  

International Nuclear Information System (INIS)

Russian (Oct 1974). USSR Grantsev, VI Dryapachenko, IP Kornilov,

1974-01-29

402

Decontamination factors and release rates of UO/sub 2/ particles from boiling pools of sodium  

Energy Technology Data Exchange (ETDEWEB)

A semi-mechanistic model for calculating solid radionuclide release rates from bubbling pools of sodium was developed. The influence of particle spacial and size distributions on the decontamination of the releases was analysed and found significant. Decontamination factors are shown as a function of pool depth, bubbling characteristics and particle size distribution. The calculation of a decontamination factor for estimating the source term of large scale hypothetical core disruptive accidents is presented. The decontamination factor for a large scale accident was found to be two orders of magnitude greater than results obtained from small scale experiments conducted with uniform particle distributions.

1983-01-01

403

Decontamination factors and release rates of UO"2 particles from boiling pools of sodium  

International Nuclear Information System (INIS)

A semi-mechanistic model for calculating solid radionuclide release rates from bubbling pools of sodium was developed. The influence of particle spacial and size distributions on the decontamination of the releases was analysed and found significant. Decontamination factors are shown as a function of pool depth, bubbling characteristics and particle size distribution. The calculation of a decontamination factor for estimating the source term of large scale hypothetical core disruptive accidents is presented. The decontamination factor for a large scale accident was found to be two orders of magnitude greater than results obtained from small scale experiments conducted with uniform particle distributions. (orig.).

404

Decays of "8"8Kr and "8"8Rb  

International Nuclear Information System (INIS)

... isotopes minutes living radioisotopes nuclei odd-odd nuclei particle properties

405

Charged particles background due to electromagnetic processes at the VLEPP based Photon Linear Collider with ultimate luminosity  

Energy Technology Data Exchange (ETDEWEB)

We have made preliminary estimates of charged particles background at the 100x100 GeV Photon Linear Collider with ultimate luminosity. The charged particles background due to electromagnetic processes is located mainly in the small-angle range of the detector. At large angles, the number of background particles is much smaller. Analysis of the background (at least, in the range under consideration) shows that background conditions for the VLEPP-based Photon Linear Collider are better than at the VLEPP electron-positron collider. ((orig.)).

1995-02-01

407

Beam stability study based on the beam trajectory jitter in the KEKB injector linac  

International Nuclear Information System (INIS)

... Tsukuba, Ibaraki (Japan) 389 p. PARTICLE ACCELERATORS beam monitoring

2001-08-01

408

Angular distributions of light charged particles from /sup 252/Cf fission in the ranges 0-46/sup 0/ and 134-180/sup 0/  

Energy Technology Data Exchange (ETDEWEB)

Alpha particles, tritons, deuterons and protons accompanying /sup 252/Cf fission were registered in coincidence with both fission fragments by means of a system containing two-dimensional position-sensitive silicon detectors. Angular distributions, kinetic energy spectra of light charged particles as well as mass distributions of fission fragments in coincidence with light charged particles were measured. The experimental results are compared with some theoretical models.

1985-06-03

409

Analytic description of X-ray fluorescence intensity as a function of the particle size in powder samples and pulp upon X-ray fluorescence analysis  

International Nuclear Information System (INIS)

Analytic expression is derived for X-ray fluorescence dependence on the particle size of powder and slurry media. The expression is obtained for a model of powder medium containing particles of different size and random distribution in the bulk of the sample. Limiting cases of homogeneous and slurry-like media are considered and expressions for calculation of the fluorescence intensity are derived. The results reasonably match the experiment for binary powder mixtures and thus provide evaluation of the powder particle size on the fluorescence intensity for multicomponent polydisperse powder medium

2007-11-01

411

A multiple sampling proportional counter for particle identification of relativistic heavy ions  

Energy Technology Data Exchange (ETDEWEB)

A multiple sampling dE/dx counter using a multiwire proportional chamber equipped with catbode pads was constructed for the multiple detection of dE/dx values along a particle trajectory. For low-energy particles this counter was proved to be useful as a Bragg-curve detector. At relativistic energies around E=14.6 GeV/nucleon good particle identification was obtained by cathode pad signals as well as anode signals for the range of projectile fragments from Z=1 (minimum ionization) up to a beam charge of Z=14. (orig.).

1990-11-15

412

A Review of Test Medium Contamination Effects on Test ...  

Science.gov (United States)

... solid particle contamination. Solid particulate impact is a good mechanism for surface heat transfer augmentation. The aug ...

1998-01-01

413

Gingival crevicular fluid levels of clindamycin compared with its minimal inhibitory concentrations for periodontal bacteria.  

UK PubMed Central (United Kingdom)

Clindamycin concentrations in gingival crevicular fluid and in blood were determined over a 7-h period and were related to the minimal inhibitory concentrations of this agent for 340 bacterial strains...Full Text Available

1981-05-01

414

Fasting plasma magnesium concentrations and glucose disposal in diabetes.  

UK PubMed Central (United Kingdom)

Fasting plasma concentrations of magnesium were measured by neutron activation analysis in 30 non-diabetics and 87 diabetics (55 non-insulin-treated, 32 insulin treated). Plasma concentrations of magnesium...Full Text Available

1984-04-07

415

Test particle moving in an interior static spherically symmetric geometry  

Energy Technology Data Exchange (ETDEWEB)

The motion of a test particle moving in an interior static spherically symmetric geometry is investigated. The author concludes that an oscillatory motion with the test particle changing its motion from a free fall towards the center to an outward radial motion can not exist for any static interior spherically symmetric model.

1984-06-01

416

Spiral modes in the diffusion of a single granular particle on a vibrating surface  

International Nuclear Information System (INIS)

We consider a particle that is subject to a constant force and scatters inelastically on a vibrating periodically corrugated floor. At small friction and for small scatterers the dynamics is dominated by resonances forming spiral structures in phase space. These spiral modes lead to pronounced maxima and minima in the diffusion coefficient as a function of the vibration frequency, as is shown in computer simulations. Our theoretical predictions may be verified experimentally by studying transport of single granular particles on vibratory conveyors.

2004-11-29

417

Spinning tachyons as particle constituents  

International Nuclear Information System (INIS)

The motions of a classical free spinning point particle are extended to include the range of superluminal velocities. There is no formal change in the constraint-dependent functional relationship between observable mass and spin, i.e., trajectory, accompanying this extension. However, the theory now permits the specification, for superluminal velocities, of a linearly rising trajectory and naturally yields tachyon confinement. Therefore, unlike their subluminal counterparts, these tachyons can be considered candidates for elementary particle constituents.

418

Production of cumulative hadrons in quark models of flucton fragmentation  

International Nuclear Information System (INIS)

Quark models of production of cumulative particles and the EMC effect are analyzed. It is shown that all these models are characterized by a universal relation between the spectrum of cumulative nucleons and the cross section for cumulative particles containing valence quarks of the nucleus. This relation is tested for the deuteron, and the role of secondary nuclear processes for heavy nuclei is discussed. It is noted that the ''sea'' cumulative particles (K"-, p-bar) are particularly important for understanding the nature of the difference between the structure functions of a nucleus and of a free nucleon.

419

Particle identification through the measurement of the Bragg curve centroid  

Energy Technology Data Exchange (ETDEWEB)

A new method of particle identification of heavy ions through the measurement of the Bragg curve centroid and particle energy has been developed using a gas ionization chamber with a resistive anode layer. Z-resolutions comparable to the conventional ..delta..E-E counter telescope could be rather easily attained.

1983-07-01

420

Particle identification through the measurement of the Bragg curve centroid  

International Nuclear Information System (INIS)

A new method of particle identification of heavy ions through the measurement of the Bragg curve centroid and particle energy has been developed using a gas ionization chamber with a resistive anode layer. Z-resolutions comparable to the conventional #DELTA#E-E counter telescope could be rather easily attained. (orig.).

421

Optimizing semiconductor devices by self-organizing particle swarm  

CERN Document Server

A self-organizing particle swarm is presented. It works in dissipative state by employing the small inertia weight, according to experimental analysis on a simplified model, which with fast convergence. Then by recognizing and replacing inactive particles according to the process deviation information of device parameters, the fluctuation is introduced so as to driving the irreversible evolution process with better fitness. The testing on benchmark functions and an application example for device optimization with designed fitness function indicates it improves the performance effectively.

2005-01-01

422

Improved Conservation Properties for Particle-in-cell Simulations with Kinetic Electrons  

Energy Technology Data Exchange (ETDEWEB)

It is shown that a simple algorithm which exactly segregates between adiabatic and non-adiabatic electrons in particle-in-cell simulations of drift modes yields excellent conservation properties (e.g. particle number, energy) compared to the conventional df scheme. The removal of the free streaming term in the evolution of the marker weight is shown to be responsible for the improved linear and nonlinear properties of the simulated plasma.

2003-06-19

423

Hot Particles Research for Nuclear Power Plant in Wolsung  

Energy Technology Data Exchange (ETDEWEB)

The evaluation of the hazard posed to the skin by very small radioactive sources (diameter < 1mm) has become popularly known as the 'hot particle' problem in European and American nuclear reactor facilities. In this study, research to detect hot particle was performed in Wolsung Nuclear power plant (NPP) in Korea.

2007-10-15

424

Hot Particles Research for Nuclear Power Plant in Wolsung  

International Nuclear Information System (INIS)

The evaluation of the hazard posed to the skin by very small radioactive sources (diameter < 1mm) has become popularly known as the 'hot particle' problem in European and American nuclear reactor facilities. In this study, research to detect hot particle was performed in Wolsung Nuclear power plant (NPP) in Korea.

2007-10-01

425

Formation of nano-sized particles of a solid electrolyte by laser ablation  

Energy Technology Data Exchange (ETDEWEB)

Nano-sized particles of a lithium ion conductive solid electrolyte, LiTi{sub 2}(PO{sub 4}){sub 3}, were prepared by laser ablation. The obtained particles were ca. 10nm in diameter. X-ray powder diffraction and Raman spectroscopy showed that they were amorphous with local structure similar to the crystalline counterpart. They were crystallized by the heating at ca. 630{sup o}C. (author)

2005-08-26

426

Explicit equation for particle settling velocities in solid-liquid systems  

Energy Technology Data Exchange (ETDEWEB)

Zanker has recently presented nomographs for determining particle settling velocities in solid-liquid systems. These nomographs were based on the general correlations developed by Barnea and Mizrahi and Barnea and Mednick. This work presents an equation directly computing particle settling velocities, eliminating the uncertainty associated with nomographs.

1981-11-01

427

Experimental and evaluated nuclear plus interference cross sections for light charged particles  

Energy Technology Data Exchange (ETDEWEB)

Experimental and evaluated integral parameters derived from nuclear plus interference differential elastic scattering cross sections are presented for all projectile/target combinations of the particles p, d, t, /sup 3/He, and ..cap alpha... The data include reaction rates, average fractional energy losses per collision and per unit path length, and average laboratory scattering cosines. The resulting parameters are of potential use in analysis of charged-particle transport.

1980-07-04

428

Effect of WC particle size on grain growth inhibition in the WC-xVC-Co system  

Energy Technology Data Exchange (ETDEWEB)

The effect of WC particle size with the addition of VC as a grain growth inhibitor was investigated during the liquid phase sintering of WC-Co system. With increasing WC particle size at the same VC content, the effect of grain growth inhibition was increased. Also, with increasing the VC content, the grain shape of WC was changed from the faceted shape to the distorted shape, and the step density of the WC grain was increased. (orig.)

2003-07-01

429

Direct conversion of fusion energy into the electric one in the 'Dragon' magnetic confinement system  

International Nuclear Information System (INIS)

It is shown that recuperator in which the thermal energy of particles is transformed into electric oue under drift in crossed fields is naturally coupled with dragontype magnetic confinement system, so the recuperation process can be initiated in the dragon magnetic field. A number of questions occuring under analysis of recuperator-dragon system is considered, including the dynamics of particle transfer to the recuperator, the share of particles entering the recuperator, the effect of rotational transform and the recuperation efficiency.

430

Deposition and removal of sub-micron particles of magnetite at the surface of alloy 800. AECL research No. AECL-11015  

Energy Technology Data Exchange (ETDEWEB)

This report measured the rate of isothermal deposition of sub-micron particles of magnetite onto the surface of Alloy 800 at pH of 4.2-9.3 at Re=10,000 and a fluid temperature of 25C. Deposition is modelled as a two-step process, the transport of particles to the surface region followed by attachment to the surface.

1994-12-31

431

Cumulative hadron production in quark models of flucton fragmentation  

International Nuclear Information System (INIS)

Quark models of cumulative particle production and EMS effect are analyzed. All the models are characterized by a universal relationship between the spectrum of cumulative nucleons and the cross section of cumulative particles containing valence nuclear quarks. This relationship is tested for a deuteron. The role is discussed played by secondary nuclear processes for heavy nuclei. A special role of ''sea'' cumulative particles (K"-, p-bar) is pointed out in understanding the nature of the difference between the structure functions of a nucleus and of free nucleon.

432

Coincidence study of alpha particle fragmentation at E/sub alpha/ = 140 MeV  

Energy Technology Data Exchange (ETDEWEB)

Results of an experimental study of the interaction of 140 MeV alpha particles with /sup 90/Zr nuclei resulting in fragmentation of the alpha particle are reported. The experimental observations of the study are analyzed and are found to show that alpha particle breakup reactions leading to at least 4-body final states, composed of two charged alpha particle fragments, contribute significantly to the singles yield of charged fragments observed at a fixed forward angle. The conclusions are based on coincidence measurements where one charged fragment is detected at a small forward angle which remains fixed, while the second charged fragment is detected at a series of coplanar secondary angles. The largest coincidence charged particle yield for the multiparticle final state events results from /sup 90/Zr(..cap alpha..,pp)X reactions, where both of the measured protons have energy ...

1980-01-01

433

Coincidence study of alpha particle fragmentation at E/sub alpha/ = 140 MeV  

International Nuclear Information System (INIS)

Results of an experimental study of the interaction of 140 MeV alpha particles with _9_0Zr nuclei resulting in fragmentation of the alpha particle are reported. The experimental observations of the study are analyzed and are found to show that alpha particle breakup reactions leading to at least 4-body final states, composed of two charged alpha particle fragments, contribute significantly to the singles yield of charged fragments observed at a fixed forward angle. The conclusions are based on coincidence measurements where one charged fragment is detected at a small forward angle which remains fixed, while the second charged fragment is detected at a series of coplanar secondary angles. The largest coincidence charged particle yield for the multiparticle final state events results from _9_0Zr(#alpha#,pp)X reactions, where both of the measured protons have energy distributions ...

434

Cleavage of tRNA within the mature tRNA sequence by the catalytic RNA of RNase P: implication for the formation of the primer tRNA fragment for reverse transcription in copia retrovirus-like particles.  

UK PubMed Central (United Kingdom)

The retrovirus-like particles of Drosophila are intermediates of retrotransposition of the transposable element copia. In these particles, a 39-nucleotide-long fragment from the 5' region of Drosophila...Full Text Available

1990-10-01

435

Alfven Eigenmode Stability with Beams in ITER-like Plasma  

Energy Technology Data Exchange (ETDEWEB)

Toroidicity Alfven Eigenmodes (TAE) in ITER can be driven unstable by two groups of energetic particles, the 3.5 MeV {alpha}-particle fusion products and the tangentially injected 1MeV beam ions. Stability conditions are established using the perturbative NOVA/NOVA-K codes. A quasi-linear diffusion model is then used to assess the induced redistribution of energetic particles.

2004-07-16

436

Revised minimum nitrite concentration for ESP  

Energy Technology Data Exchange (ETDEWEB)

Nitrite is to be used to inhibit pitting corrosion during Extended Sludge Processing (ESP) at the Savannah River Plant. The required nitrite concentrations are expressed as a function of the slurries' nitrate ion concentration and temperature. In the most dilute slurries, the nitrite inhibitor requirement is independent of the nitrate ion concentration and depends only on the temperature of the waste. The nitrate-independent concentration ensures that there is sufficient inhibitor, in sludge slurries whose nitrate has been depleted by radiolysis, to prevent pitting corrosion induced by other corrosive anions (e.g., sulfate and chloride). The threshold nitrate concentration at which the nitrite level is expressed as a function only of temperature is 0.02 M.

1992-10-26

437

Revised minimum nitrite concentration for ESP  

Energy Technology Data Exchange (ETDEWEB)

Nitrite is to be used to inhibit pitting corrosion during Extended Sludge Processing (ESP) at the Savannah River Plant. The required nitrite concentrations are expressed as a function of the slurries` nitrate ion concentration and temperature. In the most dilute slurries, the nitrite inhibitor requirement is independent of the nitrate ion concentration and depends only on the temperature of the waste. The nitrate-independent concentration ensures that there is sufficient inhibitor, in sludge slurries whose nitrate has been depleted by radiolysis, to prevent pitting corrosion induced by other corrosive anions (e.g., sulfate and chloride). The threshold nitrate concentration at which the nitrite level is expressed as a function only of temperature is 0.02 M.

1992-10-26

438

Method for determining the concentration of atomic species in gases and solids  

Energy Technology Data Exchange (ETDEWEB)

Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a plasma containing the species after a sufficient time period has elapsed after the generation of the plasma and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample.

1999-01-01

439

Kinetics of salt concentration in heated crevices  

International Nuclear Information System (INIS)

In PWR steam-generators, the crevice between tube and tube-support plate tends to fill with porous deposits during operation and acts as a concentration site for chemicals in the boiler water, which may lead to corrosion of the tube and tube-support-plate. The rate of concentration, the magnitude of the concentration factor and the rate of release of solute when conditions change are important parameters for devising strategies to minimize corrosion. Values of these parameters for salt concentration have therefore been measured in a laboratory simulation of the crevice and are used to formulate a model of the concentrating process.

1985-03-01

440

Experimental studies on non-parabolic asymmetrical solar concentrators with evacuated receivers  

Energy Technology Data Exchange (ETDEWEB)

Asymmetrical solar concentrators may offer significant advantages over symmetrical ones by the higher yearly average energy input per unit aperture area and the wider range of flexibilities in the design and operation. This paper describes the design, construction and performance evaluation of a non-parabolic asymmetrical solar concentrator with an evacuated receiver. The concentrator has a concentration ratio of 3.25 and a theoretical optical efficiency of 0.67. Collector efficiency test results are presented and compared with another similar concentrator without an evacuated receiver.

1983-06-01

441

Salivary cotinine concentrations in daily smokers in Barcelona, Spain: a cross-sectional study  

UK PubMed Central (United Kingdom)

BackgroundCharacterizing and comparing the determinant of cotinine concentrations in different populations should facilitate a better understanding of smoking patterns and addiction....Full Text Available

442

Polycarbonate Bottle Use and Urinary Bisphenol A Concentrations  

UK PubMed Central (United Kingdom)

BackgroundBisphenol A (BPA) is a high-production-volume chemical commonly used in the manufacture of polycarbonate plastic. Low-level concentrations of BPA in animals and possibly...Full Text Available

2009-09-01

444

Neurotoxic and pharmacokinetic responses to trichloroethylene as a function of exposure scenario.  

UK PubMed Central (United Kingdom)

Strategies are needed for assessing the risks of exposures to airborne toxicants that vary over concentrations and durations. The goal of this project was to describe the relationship between the concentration...Full Text Available

2000-05-01

445

Manganese, Iodine and Sulfide Concentrations and Peroxide to ...  

Science.gov (United States)

Manganese, Iodine and Sulfide Concentrations and Peroxide to Oxygen Ratio Measured during the U.S. JGOFS Arabian Sea Process Study ...

446

Homocysteine and Familial Longevity: The Leiden Longevity Study  

UK PubMed Central (United Kingdom)

Homocysteine concentrations are a read-out of methionine metabolism and have been related to changes in lifespan in animal models. In humans, high homocysteine concentrations are an important predictor...Full Text Available

447

Evaluating concentration estimation errors in ELISA microarray experiments  

UK PubMed Central (United Kingdom)

BackgroundEnzyme-linked immunosorbent assay (ELISA) is a standard immunoassay to estimate a protein's concentration in a sample. Deploying ELISA in a microarray format permits simultaneous...Full Text Available

448

[Destruction of radioactive particles by strains of Cladosporium cladosporoides (FRES.) de Vries].  

Science.gov (United States)

Reactions on the ionizing radiation of 14 Cladosporium cladosporioides strains were studied. Only 5 of them displayed radiotropizm. The ability of C. cladosporioides strains 4 and 5 with positive radiotropizm and museum C. cladosporioides strain 396 and its alb-mutant SM without positive radiotropizm to destruct radioactive particles of Chernobyl and explosion origin was studied. Two ways of radioactive particles destruction by C. cladosporioides were established, one of them is a direct way by fungal overgrowth of hot particles and the second one an indirect way only by fungal metabolites. Mycelium of the studied C. cladosporioides strains sorbed radionuclides from radioactive particles during cultivation on the liquid and agarized media. No certain inclinations of the individual strains to accumulation of radionuclides 137Cs or 152Eu were ascertained. PMID:12664550

449

Unified semi-microscopic description of low-energy proton and. alpha. -particle scattering by nuclei  

Energy Technology Data Exchange (ETDEWEB)

We develop the formalism of a unified semi-microscopic description of low-energy proton and {alpha}-particle interaction with nuclei. We analyze elastic and inelastic proton scattering at the energy 25.05 MeV and {alpha}-particle scattering at the energy 104 MeV by the {sup 90}Zr nucleus. Information is obtained on differences in the deformation of the proton and neutron distributions. We study the energy dependence of the semi-microscopic {alpha}-particle potential including the energy dependence of the potential geometry.'' We analyze the change in angular distributions of elastically scattered {alpha} particles with increase of energy and the contribution to the scattering cross section from nucleon-nucleon correlations.

1989-07-01

450

Three-dimensional, three-component wall-PIV  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a new time-resolved three-dimensional, three-component (3D-3C) measurement technique called wall-PIV. It was developed to assess near wall flow fields and shear rates near non-planar surfaces. The method is based on light absorption according to Beer-Lambert's law. The fluid containing a molecular dye and seeded with buoyant particles is illuminated by a monochromatic, diffuse light. Due to the dye, the depth of view is limited to the near wall layer. The three-dimensional particle positions can be reconstructed by the intensities of the particle's projection on an image sensor. The flow estimation is performed by a new algorithm, based on learned particle trajectories. Possible sources of measurement errors related to the wall-PIV technique are analyzed. The accuracy analysis was based on single particle experiments and a three-dimensional ...

2010-06-15

451

Self-consistent calculations within the Green's function method including particle-phonon coupling and the single-particle continuum  

Energy Technology Data Exchange (ETDEWEB)

The Green's function method in the Quasiparticle Time Blocking Approximation is applied to nuclear excitations in {sup 132}Sn and {sup 208}Pb. The calculations are performed self-consistently using a Skyrme interaction. The method combines the conventional RPA with an exact single-particle continuum treatment and considers in a consistent way the particle-phonon coupling. We reproduce not only the experimental values of low-and high-lying collective states but we also obtain fair agreement with the data of non-collective low-lying states that are strongly influenced by the particle-phonon coupling. (orig.)

2008-09-15

452

Many-particle confinement by constructed disorder and quantum computing  

Energy Technology Data Exchange (ETDEWEB)

Many-particle confinement (localization) is studied for a 1D system of spinless fermions with nearest-neighbour hopping and interaction, or equivalently, for an anisotropic Heisenberg spin-1/2 chain. This system is frequently used to model quantum computers with perpetually coupled qubits. We construct a bounded sequence of site energies that leads to strong single-particle confinement of all states on individual sites. We show that this sequence also leads to a confinement of all many-particle states in an infinite system for a time that scales as a high power of the reciprocal hopping integral. The confinement is achieved for strong interaction between the particles while keeping the overall bandwidth of site energies comparatively small. The results show the viability of quantum computing with time-independent qubit coupling.

2005-10-01

453

Extraction of biologic particles by pumping effect in a p-shaped ultrasonic actuator  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a new method of extracting biologic particles from a mixture of particles. The method is based on the pumping effect in a p-shaped ultrasonic actuator, which has a gap between its two vibrating metal plates. An adhesive tape is placed at a proper position in the gap. Due to the pumping effect which is induced by the sound field in the gap, the particles with smaller mass and radius in the mixture can be pumped up to reach the adhesive tape; while the ones with larger mass cannot. Therefore, the particles with smaller mass and radius can be extracted from the mixture. A theoretical model which can well explain the operation principle and experimental phenomena is developed. By the experimental results and the theoretical analyses based on the model, the validity of the m...

2006-01-01

454

Embryo-damage induced nucleation of microcracks in an aluminum alloy under impact loading  

Energy Technology Data Exchange (ETDEWEB)

The nucleation of microdamage under dynamic loading was investigated through planar impact experiments accomplished with a light gas gun. The microscopic observation of recovered and sectioned specimens showed that microcracks were nucleated only by cracking of brittle particles inside material. However, for comparison the in situ static tensile tests on the same material conducted with a scanning electron microscope showed that the microcracks were nucleated by many forms those were fracture of ductile matrix, debonding particles from matrix and cracking of brittle particles. The quantitative metallographic observations of the specimens subjected to impact loading showed that most of the cracked particles were situated on grain boundaries of the aluminum matrix. These facts suggested the concept of critical size and incubation time of submicroscopic cavities in the dynamic case and the mechanism of ...

1995-06-01

455

Effects of surfaces and leachables on the stability of biopharmaceuticals  

British Library Electronic Table of Contents (United Kingdom)

Abstract Therapeutic proteins are exposed to various potential contact surfaces, particles, and leachables during manufacturing, shipping, storage, and delivery. In this review, we present published examples of interfacial- or leachable-induced aggregation or particle formation, and discuss the mitigation strategies that were successfully utilized. Adsorption to interfaces or interactions with leachables and/or particles in some cases has been reported to cause protein aggregation or particle formation. Identification of the cause(s) of particle formation involving minute amounts of protein over extended periods of time can be challenging. Various formulation strategies such as addition of a nonionic surfactant (e.g., polysorbate) have been demonstrated to effectively mitigate adsorption-i...

2011-01-01

456

Direct observation of polymerization in the oleic acid-ozone heterogeneous reaction system by photoelectron resonance capture ionization aerosol mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

High molecular weight products of the ozonolysis reaction of particle-phase 9-octadecenoic acid (oleic acid) have been studied by photoelectron resonance capture ionization (PERCI) mass spectrometry (MS). Oleic acid particles ( Formula Not Shown , Formula Not Shown ) were reacted with ozone (1.8x10-4atm) in a flow reactor at reaction times of 8 and 23s. Particles were sampled on-line with a differentially pumped particle inlet and chemically analyzed by PERCI-MS. PERCI is a soft ionization method that permits the direct measurement of relatively high molecular weight compounds, facilitating molecular identification. In addition to cyclic oxygenates, such as secondary ozonides and geminal diperoxides that were reported previously, we demonstrate the formation of polymers at the particle sur...

2006-01-01

457

Coupling of magnetostriction and electrostriction in the porous rheological composite  

Energy Technology Data Exchange (ETDEWEB)

The production method of the elastic composite containing ferrous particles and titanium barium particles dispersed in the porous silicone matrix is described in this article. Since it contains ferrous and titanium barium particles, this composite shows magnetorheological and also electrorheological properties. The electrostriction of composite samples in the electric field with maximal intensity 1.5x10{sup 6} V/m was investigated. The magnetostriction in the magnetic field with maximal induction 1 T was also investigated. It was found that samples elongate with increased electric field intensity, and the magnetic field induction was detected. By increasing the samples' elongation with increase of ferrous particles, titanium barium particles and pores number were also detected. In the investigated division of the electric and magnetic field the elongation changed in a ...

2008-08-15

458

Coenzyme Q10 nanoparticles prepared by a supercritical fluid-based method  

British Library Electronic Table of Contents (United Kingdom)

A supercritical fluid-based method is proposed to produce coenzyme Q10 (CoQ10) nanoparticles. First, CoQ10/polyethylene glycol 6000 composite particles are prepared by a modified PGSS (particles from gas-saturated solutions) process with controlling the flow rate of the gas-saturated solution. Then, CoQ10 nanoparticles are obtained by dissolving the composite particles into water. The effect of experimental variables of the modified PGSS process, including pressure, temperature, flow rate of the gas-saturated solution, and mass fraction of CoQ10, on the CoQ10 particle size and particle size distribution was investigated. Results show that CoQ10 slurry product with a median diameter of 190nm and yield of 89.8% can be prepared at an optimum condition (operating pressure of 25MPa, operating t...

2011-01-01

459

Chemical transformations of peptide containing fine particles: oxidative processing, accretion reactions and implications to the atmospheric fate of cell-derived materials in organic aerosol  

British Library Electronic Table of Contents (United Kingdom)

The atmospheric processing by ozone of peptide-containing mixed particles was investigated as proxies for biogenic and sea spray primary organic aerosol. Reactions were performed in a flow reactor and particle composition was monitored by photoelectron resonance capture ionization aerosol mass spectrometry. Mixed particles containing dipeptides in a saturated organic matrix of stearic and palmitic acids showed no reaction under ozonolysis at exposure levels of 2.5???10?4?atm s O3. However reactions of mixed particles of a dipeptide (Leu-Leu) in an unsaturated matrix (oleic acid) under the same conditions resulted in a rapid loss of the peptide ion signal, as well as the carrier matrix, and appearance of a number of ion signals corresponding to secondary products. High molecular weight imid...

2009-01-01

460

Asymmetry effect of particle size distribution on content uniformity and over-potency risk in low-dose solid drugs  

British Library Electronic Table of Contents (United Kingdom)

Most active pharmaceutical ingredients (API) exhibit particle size distributions with some degrees of asymmetry deviating from log-normality. A new log-skew-normal (L-S-N) distribution model is proposed for a systematic comparison of the asymmetry effect on content uniformity. The new model originated from the S-N model used by Azzalini gives a close approximation to real API particle size distribution. Monte-Carlo method was employed to simulate the dosage potency distribution. A high risk of over potency is uncovered when either the dose is low or API particle size distribution is positively skewed. This is due to the formation of pseudo heavy tail in potency distribution that decays slower than exponentially. Nomographs of API particle size versus dosage strength were constructed with a...

2010-01-01

461

Analysis of mixing in a Twin Cam mixer using smoothed particle hydrodynamics  

British Library Electronic Table of Contents (United Kingdom)

Smoothed Particle Hydrodynamics (SPH) is a Lagrangian, particle-based method that is well suited to industrial mixing simulations. Mass transport is simply the motion of the particles, and its grid-free nature means that it can easily accommodate complicated geometries involving moving parts and sharp corners. This article describes 2D SPH simulations of a Twin Cam mixer and compares the results against experimental data and results from two published finite element method (FEM) simulations. To analyze the mixing processes in the Twin Cam mixer, we present a method for calculating the Finite-Time Lyapunov Exponent (FTLE) using SPH particle data. The FTLEs can be used to locate the unstable and stable manifolds in the flow and indicate where mixing is either promoted or inhibited in the flo...

2008-01-01

462

Alpha energy distribution as a probe for the feeding of ND and SD bands in {sup 151,152}Dy nuclei  

Energy Technology Data Exchange (ETDEWEB)

The study of the {alpha}-particle energy distributions associated with ND and SD states in {sup 151,152}Dy has been carried out. The Dy isotopes were produced in the reaction {sup 37}Cl+{sup 123}Sb at 191 MeV via the ({alpha}5n) and ({alpha}4n) channels, respectively. In {sup 151}Dy the {alpha}-particle energy distributions associated to ND and SD are very different from each other, both at the low and high energy sides inducing a difference of 3 MeV in the {alpha}-particle mean energy. In {sup 152}Dy the situation is different; the {alpha}-particle spectral shapes are similar and a difference in the {alpha}-particle mean energy of only 0.7 MeV is deduced. A description in terms of energy localization of entry states is given. (orig.)

1999-10-01

463

A Neuro-Fuzzy Multi Swarm FastSLAM Framework  

CERN Document Server

FastSLAM is a framework for simultaneous localization using a Rao-Blackwellized particle filter. In FastSLAM, particle filter is used for the mobile robot pose (position and orientation) estimation, and an Extended Kalman Filter (EKF) is used for the feature location's estimation. However, FastSLAM degenerates over time. This degeneracy is due to the fact that a particle set estimating the pose of the robot loses its diversity. One of the main reasons for loosing particle diversity in FastSLAM is sample impoverishment. It occurs when likelihood lies in the tail of the proposal distribution. In this case, most of particle weights are insignificant. Another problem of FastSLAM relates to the design of an extended Kalman filter for landmark position's estimation. The performance of the EKF and the quality of the estimation depends heavily on correct a priori knowledge of the process ...

2010-01-01

464

Lead and calcium distributions in blood, plasma, and milk of the lactating mouse  

Energy Technology Data Exchange (ETDEWEB)

Although it has been established that lead is transferred in milk from mother to suckling offspring, the physiological processes and parameters involved are not well understood. Single i.v. doses (0.2 mg/kg) or p.o. doses (2 mg/kg) of radiolabeled lead were administered to lactating and nonlactating female mice, and lead concentrations in blood, plasma, and milk were determined during a 21-day period. Large differences in lead elimination were observed between lactating and nonlactation mice. A significant fraction (25%) of the initial maternal dose (absorbed dose) was transferred to the suckling pups. The ratio of lead concentration in milk to lead concentration in plasma was found to be nearly constant over time. However, the milk-to-blood concentration ratios decreased during the same period. Furthermore, the concentration of lead in milk exceeded the plasma ...

1980-01-01

465

Investigating of composition, structure and properties of Si modification under variable dose ions implantation influence  

International Nuclear Information System (INIS)

Interest to thin film of metals' silicides first of all is conditioned intrinsic al them unique physical properties. On their basis of it is possible to produce extremely sophisticated devices of solid-state electronics, production which needs the controlled change of physics, chemical and electrical properties with high-level of accuracy. On the present time most are in detail investigated composition, structure and properties of three-dimensional samples of metals' silicides. In the last years the intensive are led to researches in the direction of creation and study of physical-chemical properties thin (500-1000 Angstroms) and ultrafine (100-120 Angstroms) films silicides. It has information about composition, morphology of surface and emission of properties of thin film of silicides of barium, of cobalt and of palladium, was obtained in conditions of ultra-high vacuum. Low energy ion implantation and further annealing on composition, electronic and crystalline ...

466

Alpha particle destabilization of the toroidicity-induced Alfven eigenmodes  

Energy Technology Data Exchange (ETDEWEB)

The high frequency, low mode number toroidicity-induced Alfven eigenmodes (TAE) are shown to be driven unstable by the circulating and/or trapped {alpha}-particles through the wave-particle resonances. Satisfying the resonance condition requires that the {alpha}-particle birth speed v{sub {alpha}} {ge} v{sub A}/2{vert bar}m-nq{vert bar}, where v{sub A} is the Alfven speed, m is the poloidal model number, and n is the toroidal mode number. To destabilize the TAE modes, the inverse Landau damping associated with the {alpha}-particle pressure gradient free energy must overcome the velocity space Landau damping due to both the {alpha}-particles and the core electrons and ions. The growth rate was studied analytically with a perturbative formula derived from the quadratic dispersion relation, and numerically with the aid of the NOVA-K code. Stability criteria in terms of the ...

1990-10-01

467

Photochemistry on surfaces. 2. Intermolecular electron transfer on colloidal alumina-coated silica particles  

Energy Technology Data Exchange (ETDEWEB)

Reductive quenching of two photoexcited ruthenium(II) complexes by an anionic electron donor, 2,2{prime}-azinobis(3-ethyl-benzothiazoline-6-sulfonate) (ABTS{sup 2{minus}}), in aqueous solution was examined by laser flash photolysis before and after adding positively charged colloidal (250-{angstrom} diameter) alumina-coated silica particles. The kinetics and quantum yields of electron transfer with an anionic sensitizer, RuL{sub 3}{sup 4{minus}} (L = bathophenanthroline disulfonate), and a cationic one, Ru(bpy){sub 3}{sup 2+} (bpy = 2,2{prime}-bipyridine), were compared. Coadsorption of ABTS{sup 2{minus}} and RuL{sub 3}{sup 4{minus}} by the particles greatly enhanced the rate of quenching such that only the reaction occurring on the surfaces of the particles was observed. Electron transfer from ABTS{sup 2{minus}} to RuL{sub 3}{sup 4-*} occurred by a static (nondiffusional) process, and the quenching efficiency was maximal ...

1989-02-23

468

Electrochemical properties of LiFePO{sub 4} prepared via ball-milling  

Energy Technology Data Exchange (ETDEWEB)

LiFePO{sub 4} cathode materials with distinct particle sizes were prepared by a planetary ball-milling method. The effects of particle size on the morphology, thermal stability and electrochemical performance of LiFePO{sub 4} cathode materials were investigated. The ball-milling method decreased particle size, thereby reducing the length of diffusion and improving the reversibility of the lithium ion intercalation/deintercalation. It is worth noting that the small particle sample prepared using malonic acid as a carbon source achieved a high capacity of 161 mAh g{sup -1} at a 0.1 C rate and had a very flat capacity curve during the early 50 cycles. However, the big particle samples ({proportional_to}400 nm) decayed more dramatically in capacity than the small particle size samples ({proportional_to}200 nm) at high current densities. The improvement in electrode ...

2009-04-01

469

Development of magnetic separation system of magnetoliposomes  

Energy Technology Data Exchange (ETDEWEB)

The magnetic separation technology using sub-microsized ferromagnetic particle is indispensable in many areas of medical biosciences. For example, ferromagnetic particles (200-500 nm) are widely used for cell sorting in stem cell research with the use of cell surface-specific antigens. Nanosized ferromagnetic particles (10-20 nm) have been suggested as more suitable in drug delivery studies given their efficiency of tissue penetration, however, the magnetic separation method for them has not been established. One of the major reasons is that magnetic force acting on the object particles decreases drastically as a particle diameter becomes small. In this study, magnetic force acting on the targets was enhanced by the combination of superconducting magnet and the filter consisting of ferromagnetic particle. By doing so, we confirmed that Fe{sub 3}O{sub 4} of 20 nm ...

2009-10-15

470

Adsorption of mercury vapor on particles  

Energy Technology Data Exchange (ETDEWEB)

The adsorption of mercury vapor on particles was studied by using soot particles generated by incineration of sewage sludge (EP-ash) and activated carbon particles. Through the experiments, it was found that, at 298 K, the EP-ash has a fairly high adsorption capacity for mercury vapor in the order of 10/sup -6/g/g, which is between that of the ordinary soils and that of activated carbon particles. Furthermore, it was found that physical adsorption of mercury vapor on the studied particles at high temperature is described by Dubinin's equation. On the basis of the equation, it was shown that EP-ash physically adsorbs very little mercury at high temperature, and therefore, most mercury in the EP-ash is chemically adsorbed or contained in a form of mercury compounds. Nevertheless, the total amount of mercury contained in the particles is very little ...

1986-07-01

471

A model of coal particle drying in fluidized bed combustion reactor  

Energy Technology Data Exchange (ETDEWEB)

Experimental and theoretical investigation on drying of a single coal particle in fluidized bed combustor is presented. Coal particle drying was considered via the moist shrinking core mechanism. The results of the drying test runs of low-rank Serbian coals were used for experimental verification of the model. The temperature of the coal particle center was measured, assuming that drying was completed when the temperature equalled 100{sup o}C. The influence of different parameters (thermal conductivity and specific heat capacity of coal, fluidized bed temperature, moisture content and superheating of steam) on drying time and temperature profile within the coal particle was analyzed by a parametric analysis. The experimentally obtained results confirmed that the moist shrinking core mechanism can be applied for the mathematical description of a coal particle drying, while dependence ...

2007-02-15

476

Radon concentration measurements in caves Budapest  

International Nuclear Information System (INIS)

(1971). Hungary Viragh, E. Budapesti Muszaki Egyetem (Hungary).

482

GaInP/GaAs tandem concentrator cells  

Energy Technology Data Exchange (ETDEWEB)

We discuss the initial development of a concentrator device based on the GaInP/GaAs monolithic tandem cell structure. The very high one-sun efficiency of this device, coupled with its characteristic low operating current, make this a promising candidate for use under high concentration. Test results for a prototype device are presented. This device achieves an efficiency of 29.5% at a concentration of 102 suns.

1994-06-30

486

Coal liquefaction research  

Energy Technology Data Exchange (ETDEWEB)

EPRI research related to coal liquefaction has concentrated on the chemistry of the processes. Recent work is reviewed.

1984-01-01

487

Characterization of an improved disposal site for low and intermediate level waste using Cs-137 deposition profiles  

International Nuclear Information System (INIS)

According to the present concept, the low and intermediate level wastes generated during the Cernavoda NPP operation will be disposed in a near surface repository. The Saligny site, placed in the NPP protected area, has been proposed for their disposal. Geologically, the main components of this site are the quaternary loess, the Precambrian and Pre-quaternary clays, the Eocene and Barremian limestone. Hydrologically, the site can be divided into a vadose zone down to 45-50 m and three distinct aquifers, two of them in the limestone beds and the third in the lenses of sand and limestone existing in the pre-quaternary clay layer. A large research program for site characterization was initiated in 1996. At present, the site characteristics requested for safety analysis have been experimentally measured on soil samples or calculated by different computer programs. Hundreds of experimental values of the density, porosity, hydraulic conductivity, soil-water retention, moisture content or ...

2004-09-09

488

Issues in the use of short-term radon concentration measurements for estimating long-term exposures  

International Nuclear Information System (INIS)

Short-duration measurements have been widely used to screen for exposures to elevated radon concentrations in individual houses or at state or regional levels. However, a number of factors, including spatial and temporal variability in radon concentrations, must be considered before comparison to concentration guidelines can be made. Daily variations in radon concentration can lead to inherent measurement uncertainties ranging from 20 to 100+ percent. Differences in radon concentration due to seasonal effects and/or sampling location are also variable, and do not appear to be regionally consistent. Winter/summer concentration ratios, for example, have been observed to vary by as much as a factor of 10 in basements and by a factor of 5 in first floors. In this paper the implications of these uncertainties on the use of short-term sampling for inferring long-term ...

1990-02-19

489

Uranium isotopic assay instrument  

International Nuclear Information System (INIS)

Full text: The isotopic assay instrument under development at Pacific Northwest National Laboratory (PNNL) is capable of rapid prescreening to detect small and rare particles containing high concentrations of uranium in a heterogeneous sample. The isotopic measurement concept is based on laser vaporization of solid samples followed by sensitive isotope-specific detection using either uranium atomic fluorescence emission or uranium atomic absorbance. Both isotopes are measured concurrently, following a single ablation laser pulse using two external-cavity violet diode lasers. The simultaneous measurement of both isotopes enables the correlation of the fluorescence and absorbance signals on a shot-to-shot basis. This measurement approach demonstrated negligible channel crosstalk between isotopes. Scanning the heterogeneous samples provides high-resolution imagery of sample isotopic fluorescence and absorbance. Isotopically selective excitation of ...

2006-10-16

490

Solid state diffusion in metal silicides  

International Nuclear Information System (INIS)

Radioactive "3"1Si was used as a marker to study metal silicide formation. Activity profiles in the silicides were measured by a combination of ion beam sputtering, radioactivity counting and Rutherford backscattering of charged nuclear particles. It was found that the metal is the diffusing species during Co_2Si, Pt_2Si, NiSi and PtSi formation, while silicon diffuses during CrSi_2, TiSi_2 and ZrSi_2 formation. Silicon was also found to be the diffusing species during second phase formation of CoSi from Co_2Si. However, in this case it was established that the silicon diffuses by a grain boundary and/or interstitial mechanism. Both the metal and silicon diffuse during Ni_2Si and Pd_2Si formation. In an attempt to interpret complex radioactivity profiles a computer program, simulating various diffusion mechanisms during both first and second phase silicide formation, was written. A numerical approach was used whereby silicide growth occurs in small increments and ...

491

Characterization of chemical looping combustion of coal in a 1 kW{sub th} reactor with a nickel-based oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion is a novel technology that can be used to meet the demand on energy production without CO{sub 2} emission. To improve CO{sub 2} capture efficiency in the process of chemical looping combustion of coal, a prototype configuration for chemical looping combustion of coal is made in this study. It comprises a fast fluidized bed as an air reactor, a cyclone, a spout-fluid bed as a fuel reactor and a loop-seal. The loop-seal connects the spout-fluid bed with the fast fluidized bed and is fluidized by steam to prevent the contamination of the flue gas between the two reactors. The performance of chemical looping combustion of coal is experimentally investigated with a NiO/Al{sub 2}O{sub 3} oxygen carrier in a 1 kW{sub th} prototype. The experimental results show that the configuration can minimize the amount of residual char entering into the air reactor from the fuel reactor with the external circulation of oxygen carrier particles giving up to ...

2010-05-15

492

Size and morphology of fine particle emissions from heavy-duty vehicles; Raskaan ajoneuvokannan hiukkaspaeaestoen koko ja morfologia - HD-PM  

Energy Technology Data Exchange (ETDEWEB)

Exhaust fine and ultra fine particle numbers, particle sizes, mass, shape, structure and density were studied from Euro II - EEV emission level heavy-duty vehicles. For total particle emission factors city buses were run on dynamic conditions simulating city bus driving. The new heavy-duty chassis dynamometer of VTT was used. Vehicles were a comprehensive sample of current city bus fleet, the type approved emission level of which was Euro II - Euro III. Also cleaner engines of Euro IV to EEV targeted emission level were included: CRT, CNG, DPF. Particle emissions of these buses were extremely low; numbers 1/100 - 1/1000 and masses 1/10 - 1/100 of those of the predominating techniques. Morphological properties of fine particle populations that represent majority of particle size distribution (Da < 500 nm) are being analyzed by image processing (Matlab) ...

2004-07-01

493

Formation of the natural sulfate aerosol  

Energy Technology Data Exchange (ETDEWEB)

Anthropogenic sulfate aerosol, together with particles from biomass burning, may significantly reduce the climatic warming due to man-made greenhouse gases. The radiative forcing of aerosol particles is based on their ability to scatter and absorb solar radiation (direct effect), and on their influences on cloud albedos and lifetimes (indirect effect). The direct aerosol effect depends strongly on the size, number and chemical composition of particles, being greatest for particles of 0.1-1 {mu}m in diameter. The indirect aerosol effect is dictated by the number of particles being able to act as cloud condensation nuclei (CCN). For sulfate particles, the minimum CCN size in tropospheric clouds is of the order of 0.05-0.2 {mu}m. To improve aerosol parameterizations in future climate models, it is required that (1) both primary and secondary sources of various ...

1996-12-31

494

Charged particle spectra: 140 MeV #alpha# particle bombardment of "2"7Al, "5"8Ni, "9"0Zr, "2"0"9Bi, and "2"3"2Th  

International Nuclear Information System (INIS)

Complete energy spectra and angular distributions of the light charged particles (A < or = 4) were measured for the bombardment of "2"7Al, "5"8Ni, "9"0Zr, "2"0"9Bi, and "2"3"2Th with 140 MeV #alpha# particles. The spectral shapes of a given emitted particle are very similar for all target nuclei except in the region of the evaporation peak. The slopes of the energy spectra in the forward direction become steeper as the mass of the observed particle decreases and vary very rapidly with angles. The experimental data can be characterized by compound nuclear evaporation processes at low energies, or at backward angles, and by direct reactions, nonequilibrium components and projectile breakup processes at high energies and forward angles. The breakup cross section for #alpha# particles is found to be appreciable. The total yield of light charged particles is ...

495

Time-Resolved Aerosol Collector for CCSEM/EDX Single Particle Analysis  

Energy Technology Data Exchange (ETDEWEB)

An automated Time Resolved Aerosol Collector (TRAC) has been developed for sequential sampling of field-collected aerosols for laboratory-based Computer Controlled Scanning Electron Microscopy/Energy Dispersed X-ray (CCSEM/EDX) single particle analysis. The collector is optimized for use of grid-supported 20 nm carbon films as deposition substrates. The carbon films have low enough X-ray background to permit EDX analysis down to 0.1-0.2 ?m particles, including detection of low-Z elements: C, N, & O. The TRAC provides unattended sampling onto a set of 151 individual grids, at sequential time intervals as short as 1 min. After collection, the samples are sealed and refrigerated pending analysis. The utility of the TRAC-CCSEM/EDX approach is exemplified using the aerosol samples collected during the Texas 2000 Air Quality Studies (Aug. 15 ? Sept. 15, 2000). We are able to quantitatively follow the time evolution in the relative contribution of ...

2003-01-02

496

Pitting corrosion of copper coiled tubes in the air conditioning system having the open heat storage water tank; Kaihokei chikunetsuso reionsuika ni okeru kuchokiyo kokan no koshoku ni tsuite  

Energy Technology Data Exchange (ETDEWEB)

In order to investigate pitting corrosion of copper coiled tubes for air conditioning systems with an open heat storage water tank, the effect of carbon films on the inner surface of copper tubes and fine corrosion-product particles in water as environmental corrosion factor on pitting corrosion was studied by field test under real environmental conditions. As a result, pitting corrosion of copper tubes was caused by synergistic effect of fine corrosion-product particles in water and carbon films. Generation of pitting corrosion was derived from deposition of the films and particles, while considerable growth of pitting corrosion was dependent on the particles. Time variation of spontaneous electrode potential also showed the effect of the film and particle. Pitting corrosion potential was estimated to be nearly 100mV vs. SCE. The following measures against pitting corrosion were ...

1998-11-15

497

Particle production in nuclear collisions and dissociation of nuclei into nucleons  

International Nuclear Information System (INIS)

An attempt to classify experimental data and to present new approach for the problem of cumulative production of particles and high-transverse momentum particles (#pi#"#+-#, k"#+-#, p, p-bar, d) on Li"6, Be, Mg, Si, "5"4","5"6","5"8Fe, "5"8","6"1","6"4Ni, Cu, "6"4Zn, "1"1"2","1"1"8","1"2"4Sn, "1"4"4","1"5"4Sm, "1"8"2","1"8"6W, U nuclei is made in the review. Particle cumulative production, quark-parton structure function, A dependence of particle production on nuclei and in nuclear collisions and A dependence of inclusive cross sections of particle cumulative production are discussed. Reactions with dissociation on nucleons of deuteron, helium and compound nuclei are considered. Possibility of unified description of different processes is discussed in terms of nucleus flucton model. 35 refs.; 22 figs.

1988-06-14

498

High temperature strengthening mechanism of hafnium carbide in a tungsten-rhenium matrix  

Energy Technology Data Exchange (ETDEWEB)

The interrelationship between the testing temperature and HfC strength increment of an arc-melted W-3.6Re-0.4HfC was determined from 1950 K to 2980 K in a vacuum of better than 1.3{times}10{sup {minus}5} Pa (10{sup {minus}7} torr). The present research was focused on the characteristic temperature at which the rapid coarsening of HfC particles occurred and the effect of the second-phase particle size on the high temperature strength properties of this material. It was found that the HfC particle strengthening was effective in a W-Re matrix up to a characteristic temperature of 2450 K in the short-term tensile test. Carbon was found to be the rate-limiting solute in the HfC particle growth. The strength of HfC strengthened alloy at temperature above 0.5 T{sub m} is proportional to the square root of particle volume fraction. The yield strengths of W-3.6Re-0.26HfC calculated based on ...

1991-01-01

499

High temperature strengthening mechanism of hafnium carbide in a tungsten-rhenium matrix  

International Nuclear Information System (INIS)

The interrelationship between the testing temperature and HfC strength increment of an arc-melted W-3.6Re-0.4HfC was determined from 1950 K to 2980 K in a vacuum of better than 1.3x10"-"5 Pa (10"-"7 torr). The present research was focused on the characteristic temperature at which the rapid coarsening of HfC particles occurred and the effect of the second-phase particle size on the high temperature strength properties of this material. It was found that the HfC particle strengthening was effective in a W-Re matrix up to a characteristic temperature of 2450 K in the short-term tensile test. Carbon was found to be the rate-limiting solute in the HfC particle growth. The strength of HfC strengthened alloy at temperature above 0.5 T_m is proportional to the square root of particle volume fraction. The yield strengths of W-3.6Re-0.26HfC calculated based on the ...

1991-01-06

500

Computer image analysis of wear debris for machine condition monitoring and fault diagnosis  

Energy Technology Data Exchange (ETDEWEB)

Whenever moving surfaces interact, wear particles are produced. Microscopic examination of the morphology of such wear debris is an accepted method for machine condition monitoring and fault diagnosis. Wear particle analysis has not, however, been widely accepted in industry because it is dependent on expert interpretation of particle morphology and relies on subjective assessment criteria. Consequently, the methods are time consuming and expensive and are not always consistent. The use of automated computer image analysis systems to assess the morphology of debris promises to overcome these limitations by making the methods more time and cost efficient, and also more consistent and effective. The first step required for automation of the analysis procedure is to develop objective criteria for assessing the wear particle morphology. Numerical parameters to describe the morphology have been developed and ...

1995-03-01