British Library Electronic Table of Contents (United Kingdom)

Summary Background The incidence of food allergy to wheat is increasing. Its diagnosis depends on the purity of major allergens and their inclusion in tests. Isolation and characterization of wheat allergens are therefore of utmost importance. Objective To purify and identify wheat flour allergens most frequently recognized by patients' IgE antibodies and to study their allergenicity. Methods Water/salt-soluble extracts from wheat flour were prepared and separated using a combination of ultrafiltration, isoelectric focusing and liquid chromatography. Purified proteins were analysed by immunoblotting using pooled sera from patients with atopic dermatitis who possessed IgE specific to wheat. Wheat proteins found to bind IgE were subsequently identified by matrix-assisted laser desorption/ion...

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Biomimetic vesicle media which can selectivity extract and concentrate heavy metals (e.g., Pb{sup 2+}) from dilute solutions of 5 ppm and less have been prepared. At a concentration of only 1% 2/v, these non-covalently assembled, unilamellar, surfactant vesicles provide approximately 1,000m{sup 2} of exposed membrane surface area per liter of suspension which gives rise to very rapid rates of metal ion extraction. To facilitate the selective transport of heavy metal ions through the ion impermeable vesicle wall, the vesicles are doped with lipophilic ionophores, both natural and synthetic. In addition, the metal chelating agent, nitrolotriacetate, is encapsulated in the aqueous vesicle core to provide the driving force for metal ion uptake and concentration. Concentration factors in excess of 1000 fold have been observed. Metal-sorbing surfactant vesicles measuring approximately 100 nm in diameter are stable and have been tested in a ...

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A specific radiochemical procedure for indium determination in semiconductor-grade silicon, using an inorganic ion exchanger (cerium oxalate) is proposed.

UK PubMed Central (United Kingdom)

BackgroundLentiviral vectors (LVs) can efficiently transduce a broad spectrum of cells and tissues, including dividing and non-dividing cells. So far the most widely used method...Full Text Available

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Recently we have found that carbon nano-materials have ability to recognize softer actinides(III). In this presentation, separation of americium(III) from lanthanides(III) by chromatography with carbon nano-materials, such as carbon nano-tubes and graphite, has been investigated by batch adsorption experiments and chromatography. The separation factor (SF) between americium(III) and lanthanide(III) was about 2 in the range of pH from 1 to 4 by using carbon nano-tube, graphite and activated charcoal. The separation factor depended on the diameter of carbon nano-tubes. Smaller one, 3-20 nm diameter, showed the best selectivity for americium(III), which separation factor was about 2.0, although larger one, 40-70 nm, showed almost no selectivity. The same behavior has been observed by using graphite powder and activated charcoal although acid- or alkali pretreated ...

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The methods introduced for the field of cleaning waste water can be classified under various processes. Chemical oxidation is done with ozone, hydrogen peroxide and ultraviolet irradiation with subsequent biological decomposition. Another method is ultra-filtration with recovery of valuable materials or waste water ponds with algae biomass to decompose ammonium compounds, nitrates and phosphates. (EF) [Deutsch] Die auf dem Gebiet der Abwasserreinigung vorgestellten Methoden kann man in verschiedene Verfahren einordnen. Die chemische Oxidation erfolgt mit Ozon, Wasserstoff-Peroxid, UV Bestrahlung und anschliessenden biologischen Abbau. Eine andere Methode ist die Ultrafiltration mit Rueckgewinnung von Wertstoffen oder Abwasserteiche mit Algenbiomasse zum Abbau von Ammoniumverbindungen, Nitraten und Phosphaten. (EF)

British Library Electronic Table of Contents (United Kingdom)

Mechanistic studies on a charged ultrafiltration (UF) membrane fouled with natural organic matter (NOM) and colloidal particles are systematically investigated to understand the relative role of each NOM fraction and the presence of colloidal particulate to membrane fouling. Humic acid (HA), dextran, and kaolin were employed as surrogate model foulants representing the organic hydrophobic acid NOM, hydrophilic neutral NOM, and inorganic colloidal materials, respectively. The results obtained showed that the organic NOM of hydrophilic surrogate (dextran) plays a primary role in promoting membrane fouling, followed by hydrophobic acids and inorganic kaolin, but to a lesser extent than organic NOM compounds. Significant differences in the extent of fouling between dextran and HA have been obs...

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This project will determine whether electrolytic dialysis has promise in the separation of charged particles in an aqueous solution. The ability to selectively move ions from one aqueous solution to another through a semipermeable membrane will be studied as a function of emf, amperage, and particle electrical charge. The ions selected for the study are Cl{sup -} and SO{sub 4}{sup 2-}. These ions are of particular interest because of their electrical conduction properties in aqueous solution resulting with their association with the corrosive action of metals. The studies will be performed with commercial membranes on solutions prepared in the laboratory from reagent salts. pH adjustments will be made with dilute reagent acid and base. Specific objectives of the project include testing a selected membrane currently available for electrolytic dialysis, membrane resistance to extreme pH conditions, the ...

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Known trace-matrix-separation and enrichment procedures for the refractory metals Mo and W use very time-consuming batch-techniques. This paper presents the application of a quasicontinuous liquid chromatographic (LC) technique as a step towards automated ultratrace separation. The anionic peroxo complexes from Mo(VI) and W(VI) are used for the trace-matrix-separation. Optimization of the peroxide concentration permits a complete removal of all cationic analyte traces on the HPLC-suitable cation exchanger Nucleosil SA. The high chromato-graphic efficiency also allows a direct ion chromatographic separation of the removed traces. This leads to conclusions about the contribution of the analyte traces on the trace-matrix-separation column and the limits of determination. (author). 13 refs.; 12 figs.; 5 tabs.

International Nuclear Information System (INIS)

A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.

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In order to get the separation of natural isotopes of lithium by electrolytic amalgamation, an electrolytic cell with a confined mercury cathode was used to obtain data for the design of a separation stage. The initial work was followed by the design of a moving mercury cathode electrolytic cell and three experiments with six batches stages were performed for the determination of the elementary separation factor. The value obtained, 1.053, was ill agreement: with the specialized literature. It was verified in all experiments that the lithium - 6 isotope concentrated in the amalgam phase and that the lithium - 7 isotope concentrated in the aqueous phase. A stainless-steel cathode for the decomposition of the lithium amalgam and the selective desamalgamation were also studied. In view of the results obtained, a five stages continuous scheme was proposed. (author)

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Polymeric coated ferromagnetic carriers with an absorbed layer of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) diluted by tributyl phosphate (TBP) are being evaluated for application in the separation and the recovery of low concentrations of americium, plutonium, and uranium from nuclear waste solutions. Due to their chemical nature, these extractants selectively complex americium and plutonium contaminants onto the particles and the complexed particles can be recovered from the solution using a magnet. Physical and chemical characterization of the extractant-absorbed particles were performed by gamma and liquid scintillation counting, scanning electron microscopic (SEM) micrograph, and other physical measurements. Plutonium, americium, and uranium separations have been performed at various HNO{sub 3} and HCl concentrations. Parameters were studied to determine the limitations and capacity of the ...

Science.gov (United States)

Selenium 79 is a beta emitter produced from (235)U fission and is one of the long half-life radionuclides of interest in nuclear waste disposal problematic because of its potential migration capacity to the surface environment. Measurement of (79)Se is particularly difficult due to its low activity in waste matrices (about 10(-3)Bqg(-1)). A radiochemical procedure based on ion exchange separations was already described in a previous paper. This work presents different applications of the radiochemical separation to waste samples and an improvement of this procedure, including a selective extraction of selenium as diethylselenium in an organic solvent followed by a re-extraction in aqueous medium. This additional step allows the decontamination factor to be increased with the aim of counting (79)Se by liquid scintillation counting. PMID:19071740

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We propose a novel method for ultrasensitive isotope analysis that combines magnetic mass selection, resonant charge-exchange neutralization, and resonant laser ionizaion. Our method attains high isotopic abundance selectivity by means of continuous multistage separation of ions stored in a small ring. For the environmentally interesting case of /sup 90/Sr versus /sup 88/Sr we estimate that sensitivity better than 10/sup -15/ for a throughput of 10/sup 13/ atoms/sec and an efficiency (after the ion source) greater than 10% are readily achievable.

International Nuclear Information System (INIS)

Target materials for inertial fusion energy (IFE) power plant designs might be selected for a wide variety of reasons including wall absorption of driver energy, material opacity, cost and ease of fabrication. While each of these issues are of great importance, target materials should also be selected based upon their safety and environmental (S and E) characteristics. The present work focuses on the recycling, waste management and accident dose characteristics of potential target materials. If target materials are recycled so that the quantity is small, isotopic separation may be economically viable. Therefore, calculations have been completed for all stable isotopes for all elements from lithium to polonium. The results of these calculations are used to identify specific isotopes and elements that are most likely to be offensive as well as those most likely to be acceptable in terms of their S and E characteristics.

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This report contains studies which are part of the Bonneville Power Administration`s program to protect, mitigate, and enhance fish and wildlife affected by the development and operation of hydroelectric facilities on the Columbia River and its tributaries. Attention is focused on population monitoring studies in the Sawtooth Valley Lakes. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

International Nuclear Information System (INIS)

A rapid and sensitive method for the separation and determination of titanium and iron in thiocyanate system has been developed. The extractability of Ti(II) by high molecular weight (HMWA) in organic solvent (HCl/sub 3/) and its separation from Fe(III) was examined. The yellow coloured complex of Ti(II)-SCN in quantitatively extracted into the organic phase containing tribenzyl tribenzylamine (TBA) - a high molecular weight amine, whereas the blood red coloured complex of Fe(III)-SCN formed under the same conditions get separated in the aqueous phase. On the basis of the selective extractability, a method has been developed for the separation as well as simultaneous determination of Ti(II) and Fe(III) in presence of many other elements. The molar extinction coefficients were found to be 1.9 x 10/sup 5/ l mol/sup -1/ cm/sup -1/ and 1.11 x 10/sup 5/ l mol/sup -1/ cm/sup -1/ ...

British Library Electronic Table of Contents (United Kingdom)

An hydrazone derivative, 1,2-cyclohexanedione bis-benzoyl-hydrazone (1,2-CHBBH), has been used as a selective reagent for an advanced environmental application consisting of separating the different species of nickel in natural waters by solvent extraction. The effects of pH and reagent concentration on the extraction process were studied, as well as the influence of both organic (humic acids) and inorganic ligands (Cl-). Under natural conditions, organic and inorganic nickel species presented different extraction behaviors, and the variations in extraction yields could be correlated with the concentrations of organic complexes in the samples, allowing the separation of labile and non-labile nickel species in both fresh and marine waters.

International Nuclear Information System (INIS)

The synthesis, characterization, and some analytical applications of a new triazine resin are described. Separation of group IB, IIB, VIB, and VIIB metal ions from group VIII metal ions is achieved by this PDT-4 resin. Calcium(II) and magnesium(II) are taken up at pH = 6, 0.1 M acetate and are eluted at pH = 6, 0.1 M sodium nitrate. Copper(II) is retained at pH = 6, 0.1 M acetate and pH = 1 hydrochloric acid and is eluted subsequently by 5 M perchloric acid. Molybdenum(VI) is sorbed selectively from 0.1 N sulfuric acid or hydrochloric acid and is eluted in a tight band by 0.1 N sodium hydroxide. Numerous rapid column chromatographic separations are reported using this new resin, including analysis of NBS standard samples.

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This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, ...

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Tests on a sample of trench water from the Maxey Flats burial ground effectively demonstrated the new Reverse Osmosis Pilot Plant. The effluent from the 50% salt-rejection membrane was decontaminated well enough with the exception of tritium to be discharged to the environment. The performance of the 97% salt-rejection membrane was superior to that of the 50% membrane. A breakthrough and capacity experiment was conducted with Durasil 10 on a simulated Three Mile Island solution. The maximum decontamination factor was extrapolated to be 10/sup 6/, which would reduce the cesium level of TMI water to below the discard limit. Capacity (1/DF = 0.5) was reached at 1260 column volumes. Several adsorbents were tested in the engineering columns for decontamination of cesium-bearing solutions. Under the conditions of the experiment, these adsorbents were ineffective in removing cesium from the solution.

British Library Electronic Table of Contents (United Kingdom)

Humic acids are primarily a result of the microbiological degradation of surrounding vegetation and animal decay and enter surface waters through rain water run-off from the surrounding land. This often gives rise to large seasonal variations, high concentrations in the wet season and lower concentrations in the dry season. Alone humic acid is just a colour problem but when present in conventional treatment processes like chlorination, carcinogenic by-products like trihalomethane and haloacetic acid are formed. This, in addition to the demand for clean potable drinking water, has sparked extensive research into alternative processes for the production of drinking water from various natural/industrial sources. One of the major areas of focus in these studies is the use of membranes in micro...

Science.gov (United States)

Pulse radiolysis studies of the formation kinetics and the yields of various phenylcarbenium ions from several different solutes in 1,2-dichloroethane solution have been carried out. The results indicate that there are two kinetically distinguishable cationic species of the solvent which react selectively with the different solutes to form the phenylcarbenium ions. It is suggested that one is a cation radical (yield 0.68 molecule/100 eV) and the other a carbocation (yield 0.20 molecule/100 eV). Rate constants for their separate reactions with selected aromatic compounds and with ammonia have been determined. Molar extinction coefficients have been estimated for benzyl cation, diphenyl cation radical, and anthracene cation radical. 6 figures, 1 table.

Energy Technology Data Exchange (ETDEWEB)

The present work focuses on investigations of a highly selective ligand for Am(III)/Ln(III) separation: bis-triazinyl-pyridine (BTP). By means of nano-electro-spray mass spectrometry, complex formation of BTP with selected elements of the lanthanide series is investigated. We show that the diluent drastically influences complex speciation. Measurements obtained in the extraction-relevant diluent 1-octanol show the occurrence of Ln(BTP){sub i} (i 1-3) species in different relative abundances, depending on the lanthanide used. Here, the relative abundances of the Ln(BTP){sub 3} complexes correlate with the distribution ratios for extraction to the organic phase of the respective lanthanide. (authors)

British Library Electronic Table of Contents (United Kingdom)

This paper aimed to the evaluation of different kinds of sorbent material preparation and to the evaluation of their characteristics at different pH conditions by X-ray fluorescence analysis. This method is suitable for identification and determination of elements in samples of different character, state and origin because it is a polycomponent, non-destructive, fast and simple analytical method. Moreover, it allows time-advantageous and reliable measurements. This paper studies problems concerning the determination of some selected elements (Mn, Fe, Ni, Cu, Zn, Pb) in pharmaceutical samples of sodium chloride in the solid state as well as in its solution by sorption on chelating extraction membrane 3M Empore? and on the strongly acidic ion-exchanger Dowex 50Wx8. Conditions for the most ef...

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The French strategy of high level radioactive aqueous waste management is an incorporation in glassy fission products containers. Therefore, nitric acid soluble organic reagents needed for minor actinides and lanthanides selective separation from fission product solutions have to be sufficiently removed to reach carbon concentrations compatible with calcinator working. Thus, the ability of reagents to be oxidized under concentration conditions with or without denitration becomes a criteria of selection and have been studied. Further, if not working, other operations like hot hydrogen peroxide oxidation, catalyzed or not, are investigated. Reagents involved in this work are mainly complexing products (N-(2-Hydroxyethyl) Ethylene-diamine-tri-acetic Acid), pH keeping reagents (carboxylic acids like citric, glycolic, tartaric and lactic acid) and alkaline species (Tetramethylammonium hydroxide). Behaviour of acetic acid, which ...

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Data are presented from the intermediate scale borehole test, an in situ test fielded in the pillar separating Rooms C1 and C2 at the Waste Isolation Pilot Plant (WIPP). The test was to provide data on the influence of scale, if any, on the structural behavior of underground openings in salt. These data include selected fielding information, test configuration, instrumentation activities, and comprehensive results from a large number of gages. Construction of the test began in December 1989, with the drilling of the intermediate scale borehole in December 1990. Gage data in this report cover the period from January 1989 through June 1993.

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A laser-induced plasma of alkali atoms was studied with a view to efficient recovery of isotope ions, with small charge exchange losses. The electron temperature was measured by the double-probe method for several kinds of excitation schemes, which gave the relationship between temperature and the energy given to ions by laser photons. A charge exchange process between lithium isotopes was also studied in an electromagnetic field. It was shown that optimum electrostatic and magnetic field strength exist which maximise the 'separative power'.

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Unmanaged pollutants from putrescible farm, industrial, and municipal wastes degrade in the environment, and methane emitted from their decomposition may contribute to global climate change. Under modern environmental regulations, these wastes are becoming difficult to dispose of using traditional means. One waste management system, anaerobic digestion or AD, not only provides pollution prevention but can also convert a disposal problem into a new profit center. This report is drawn from a special session of the Second Biomass Conference of the Americas. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

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The first stage of the continuous coal hydrogenation unit has been used to test a number of coals with different processing strategies. This work has shown that conversion increases with product recycle, however after the second pass the increase is small but operability of the reactor is considerably improved. A kinetic model for the aromatic saturation of the recycle solvent in the second stage has been developed and will be used in the selection of conditions for oil upgrading processes. New insights into the structural composition of coal derived materials have been made due to the refinement of chromatographic or solubility separation analyses into routine operations and the development of a new technique in NMR spectroscopy.

International Nuclear Information System (INIS)

Development of techniques for separating isomeric nuclides is important to the investigation of schemes for gamma-ray lasers. In preparation for an experiment to separate 10_1_4 atoms of the /sub 197m/Hg (299 keV, tau/sub 1/2/ = 24 hours) isomer, we report isotopically selective resonance ionization of mercury atoms. This has been accomplished by three-step excitation via the 6_3P"1 and 8_1S"0 excited states, using three collinear pulsed laser beams of 254, 286, and 532 nm wavelengths from a Nd:YAG and two dye lasers. These beams were passed through a closed mercury-vapor cell containing electrostatic plates to which the ions were drawn. Ion current and fluorescent radiation were measured as a function of laser frequency. Hyperfine structures for the 254- and 286-nm transitions were observed.

International Nuclear Information System (INIS)

The purpose of this text is to train engineers and technologists not just to understand corrosion but to control it. Materials selection, coatings, chemical inhibitors, cathodic and anodic protection, and equipment design are covered in separate chapters. High-temperature oxidation is discussed in the final two chapters ne on oxidation theory and one on controlling oxidation by alloying and with coatings. This book treats corrosion and high-temperature oxidation separately. Corrosion is divided into three groups: (1) chemical dissolution including uniform attack, (2) electrochemical corrosion from either metallurgical or environmental cells, and (3) stress-assisted corrosion. Corrosion is logically grouped according to mechanisms rather than arbitrarily separated into different types of corrosion as if they were unrelated. For those university students and industry personnel who approach corrosion ...

International Nuclear Information System (INIS)

The unknown #beta#-decay half-lives of 22 isotopes far off stability (5 < T_Z < 10) in the region from Ti to Ni were measured at GSI, Darmstadt. The nuclei were produced in a fragmentation reaction of 500 A.MeV "8"6Kr-projectile impinging on a thick Be target. The isotopes of interest were separated and identified with the fragment separator, FRS, by a combination of B#rho#,Z, and ToF techniques. An additional range separation was performed by a selective implantation into granular detectors. The spatial and time correlations of the implant with the consecutively detected #beta#-particles were used to determine the unknown half-lives. For nuclei far off stability, #beta#-decay chains were measured and analyzed as well, leading to an even more reliable evaluation of the lifetimes. The large discrepancies found between the measured and the theoretical values emphasize that most recent theoretical ...

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The thesis explains the development of a mass spectrometerical isotope dilution analysis (MS/DA) for determining trace amounts of Tc. The Tc-97 isotope has been prepared by in-core irradiation of Ru of natural isotopic composition, and used as the indicator isotope. For separation of Tc-97 from the Ru matrix, a method has been developed to quantitatively separate Tc-97 from a high Ru surplus. For determining the isotope ratio for the MS/DA, a mass spectrometrical measuring technique has been found which allows reproducible measurement of the Tc-99/Tc-97 isotope ratio. Positive and, for the first time, also negative thermoionisation has been used as a method of selective ionisation of Tc. The applicability of the MS/DA for Tc trace analysis has been verified using two Al foils doped with Tc-99 or Mo-98, respectively. These have been irradiated in a nuclear reactor, the irradiation of Tc-99 yielding Ru-100, and irradiation of ...

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A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain adequate sulfide recoveries ...

British Library Electronic Table of Contents (United Kingdom)

The meiotic spindle in the oocyte is composed of microtubules and plays an important role during chromosome alignment and separation at meiosis. Polarized light microscopy (PLM) could be useful for a non-invasive evaluation of the meiotic spindle and may allow removal of nuclear structures without fluorochrome staining and ultraviolet exposure. In this study, PLM was used to assess its potential application in porcine reproductive technologies. The objectives of the present study were to assess the efficiency of PLM to detect microtubule-polymerized protein in in vitro-matured porcine oocytes; to examine its effects on the oocyte developmental competence; to select oocytes based on the presence of the meiotic spindle detected by PLM; and to assess the efficiency oocyte enucleation assisted...

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The conference was organized to bring together scientific and business people from Canada, United States, and Mexico to foster the protection and improvement of the environment and to promote sustainable development in the three NAFTA countries. The sessions are international cooperation and partnerships (panel discussion), markets, market access, economic instruments, venture and capital growth, economic instruments versus regulations, international financial institutions, partnerships and networks, government support programs (panel), acid rain, stratospheric ozone, smog and ground level ozone, innovative measurement methods, hazardous air pollutants, respirable fine particulates, climate change prevention technologies, pollution prevention technologies, indoor air technology, and posters. Selected papers have been abstracted separately.

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A fusion reactor (such as NET/ITER) which breeds its own tritium fuel requires tritium recovery, purification and separation from the other isotopes. Cyclic adsorption processes are strong candidates for several of the processes involved: amongst other advantages, they promise a low tritium inventory. A good adsorbent for such processes must have high adsorption capacity, high selectivity and very low tritium retention after each cycle. Pure zeolite powder is shown to have an excellent combination of these three properties. However, in practice problems can arise from tritium which is not removed by reactivation. In this paper we show that tritium retention in zeolites can be caused either by water retained in the zeolite structure, which can be removed by ore rigorous activation, or by water tapped on binders in commercial pellets. (orig.).

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In the frame of the comprehensive assessment of Swiss energy systems, air quality simulations were performed by using a 3-dimensional photo-chemical dispersion model. The objective is to investigate the impacts of pollutants in Switzerland for future options of Swiss energy systems. Four scenarios were investigated: Base Case: simulations with the projected emissions for the year 2030, Scenario 1) all nuclear power plants were replaced by oil-driven combined cycle plants (CCP), Scenarios 2 to 4) traffic emissions were reduced in whole Switzerland as well as in the cities and on the highways separately. Changes in the pollutant concentrations and depositions, and the possible short-term impacts are discussed on the basis of exceedences of critical levels for plants and limits given to protect the public health. (author) 2 figs., 7 refs.

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Membranes in Palladium and its alloys, in particular Pd/Ag alloys, are selectively permeable to hydrogen and can therefore be used to purify hydrogen. It is intended to use them as material for electrodes in fuel cells. As the manufacturing process of a substrate Pd/Ag-layer consists of several stages and is still not completely understood, it would be advantageous to be able to characterise separately the layers of noble metals obtained by electro-plating . Attempts are being made in this work to vary the cristallographical structure of the deposited alloy by the choice of test parameters and by sintering when depositing the Pd/Ag. The layers produced are to be examined using an interference microscope and X-ray diffraction. Moreover, the diffusion behaviour of the hydrogen is to be examined with an electro-chemical pulse method specifically developed for this purpose. figs., tabs., 27 refs.

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This patent describes an oil-filled electric cable and a manufacturing method for said cable, in which the solid insulation is formed, at least in part, by separately applied, alternate layers of cellulose paper tape and of film tapes made of plastic. Prior to application of the tapes around the cable conductor, the moisture content of the paper tape is selected and the swelling of the plastic tape by the oil after application is adjusted, if necessary, such as by immersing the plastic tape in the oil prior to application, so that the swelling of the plastic tape by the oil in the formed cable is offset by the shrinkage of the paper tape during drying of the cable. Also, an apparatus for pre-swelling the plastic tape is described. 4 figs.

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Selective catalytic reduction (SCR) is a method of reducing the emissions of nitrogen oxides into the atmosphere. Peerless Manufacturing Co. specialises in designing and building SCR systems. The company uses fluid flow modelling to design systems, creating physical and/or numerical flow models to normalise the flow and eliminate potential problems. Computational fluid dynamics (CFD) is used to visualise fluid flow within SCR units and other types of equipment involving phase separators, air intake systems etc. An example is given of use of the commercial CFD code FLUENT to create a full-scale model of an SCR unit so its design could be modified for optimum performance. 1 fig., 1 photo.

British Library Electronic Table of Contents (United Kingdom)

A qualitative method, involving supported liquid?liquid extraction (SLE) and ultra high pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS?MS), was developed for the rapid tentative identification of various drugs of abuse in urine. In this study, 28 drugs and metabolites were covered by the screening procedure. Before analysis, urine samples were extracted by SLE and good extraction recoveries were obtained for most investigated compounds. The UHPLC strategy was then selected for the rapid separation of amphetamines, cocaine, opiates and related compounds in urine. Using columns packed with sub-2??m particles, analysis time was reduced down to 2?min, while maintaining acceptable performance. Finally, the detection was by tandem MS operating in the single reaction...

British Library Electronic Table of Contents (United Kingdom)

As part of the United States Department of Agricultures (USDA) National Food and Nutrient Analysis Program (NFNAP), food composition data for vitamin D in the USDA National Nutrient Database for Standard Reference are being updated and expanded, focusing on high priority foods and validated analytical methodology. A lack of certified reference materials and analytical methods validated for these key foods required the development of five matrix-specific control composite materials (CC) (canned salmon and vitamin D3 fortified cereal, orange juice, milk, and cheese). Each of six experienced laboratories (research and commercial) analyzed vitamin D3 in five subsamples of each CC in five separate analytical batches, with one subsample of each material in each run. Research laboratories perform...

International Nuclear Information System (INIS)

The Cycle 8A static tests conducted in the Fast Flux Test Facility (FFTF) during 1986 have resulted in the separation of various feedback reactivity components. These feedback components, described by closed-form equations depending only on the reactor temperature field, can be regarded as database for the validation and/or calibration of feedback mechanistic models. The SASSYS safety analysis code contains the most developed feedback reactivity models and was selected for the comparison study between database and mechanistic calculations for the FFTF. Although detailed feedback models for control rod repositioning and core radial expansion/bowing exist, only the simple models were available in SASSYS at the time of this study. The results are described in this paper.

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A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

International Nuclear Information System (INIS)

The usage of biosorbents allows separation of scandium and yttrium from each other and from Fe, Al, Ti, Si, and Ca in hydrometallurgical processing of ores and wastes. It was shown that sorption of scandium and yttrium increased with the increase of pH of solution. Initial rate of scandium sorption depended on the biomass type; however 85-98% of scandium was sorbed within 10-30 min with most biomass types tested. The presence of aluminium, iron (III), and titanium in the solution inhibited sorption of scandium and particularly yttrium. After four cycles of sorption, 98.8% of scandium and 87% of yttrium was extracted from red mud leach solution by the biomass of Saccharomyces cerevisiae and Aspergillus terreus, respectively. Selectively of the process of scandium and yttrium recovery could be achieved during sorption and also desorption, when solubilization of sorbed associated elements was inhibited by high pH values. (Author).

Energy Technology Data Exchange (ETDEWEB)

The United States Department of Energy (DOE) at the Morgantown Energy Technology Center (METC) contracted with P.S. Lowell and Co. Inc. (Lowell and Co.) and Jay S. Dweck, Consultant, Inc., (JSD) to enhance the capability of ASPEN in simulating coal gasification and oil shale processing plants. Of particular concern was the capability to predict the distribution of environmentally significant components among the various aqueous and organic liquids and gas streams within or leaving the process. The project was divided into major task areas. The first was to develop and implement the calculational routines necessary for predicting aqueous electrolyte chemical reactions. Part of this effort also was to select a species list and collect and/or regress data for the necessary parameters. The second task was to develop and implement a multi-phase flash capability (including precipitated solids) and unit operations models for a venturi and a solid/liquid ...

International Nuclear Information System (INIS)

The relative roles of glomerular filtration, tubular reabsorption and tubular secretion in lead handling were evaluated using renal clearance technique, stop-flow analysis, and renal lead accumulation. In addition, the effect of altering acid-base status on renal handling of Pb was determined. Clearance of ultrafilterable lead was measured in anesthetized dogs during infusion of "2"0"3Pb with small doses of carrier Pb(0.5 to 50 #mu#g/kg/h). Filterable lead concentration was estimated by in vitro ultrafiltration of non-anticoagulated plasma. Fractional excretion of Pb was calculated using creatinine clearance to estimate glomerular filtration rate. Dogs in acute metabolic acidosis had the lowest fractional excretion of ultrafilterable Pb (< 0.1); those in alkalosis had high fractional Pb excretion (0.75 to 2.5) while normal dogs were intermediate (0.1 to .4). The fractional excretion of Pb during metabolic alkalosis varied with the dose of Pb administered; only ...

Energy Technology Data Exchange (ETDEWEB)

The oxidative dehydrodimerization of propylene to C/sub 3/-dimers (1,5-hexadiene and benzene) has been examined at 600/sup 0/C and atmospheric pressure using a (Bi/sub 2/O/sub 3/)/sub 0.85/(La/sub 2/O/sub 3/)/sub 0.15/ oxide ion-conducting catalyst in a reactor where a catalyst disk separates a feed of propylene in helium from air. The surface of the disk exposed to propylene was reoxidized not by gaseous O/sub 2/, but by the dissociative adsorption and reduction of dioxygen at the oxidant side of the disk, followed by oxide ion conduction to replace spent lattice oxygen. Selectivity to C/sub 3/-dimers when using lattice oxide migration to reoxidize the catalyst was considerably greater than when O/sub 2/ was added to the propylene feed under the same reaction conditions. This result supports the proposal that lattice oxygen is predominantly involved in the selective oxidation of propylene to C/sub 3/-dimers, and ...

International Nuclear Information System (INIS)

Selective alveolo-bronchography (SAB) has been routinely used to evaluate anatomical changes in the bronchiole and its distal air spaces. A narrowing of the bronchiole and abnormal pooling of contrast medium in the destroyed air space are the prime findings. Since the object of radiography is extremely thin, direct magnification radiography is mandatory to obtain radiologic details. However, the problem with this technique is that radiographic quality varies depending upon the size of the patient and the concentration of contrast medium to be introduced in the lung. This study had two goals. One was to improve the image quality of SAB by Fuji Computed Radiography (FCR). FCR provides radiographs with a good contrast and stable density throughout a wide range of exposure factors which occur in the use of SAB. The other goal was to separately evaluate morphological abnormalities in the outer and inner zones of the lung using X-ray CT. This idea ...

Science.gov (United States)

... Separation," AGARD,Rept 272, April 1960, ... Leading Edge Effect on Supersonic Boundary Layer Flow." ... of Gas Injection in Separated Flows." TCEA, ...

Science.gov (United States)

PMID:7075772

Science.gov (United States)

... Agard Report 272,1960 ... and reattached subsonic turbulent flows obtained downstream ... of flow separations due to deflected control surfaces. ...

Energy Technology Data Exchange (ETDEWEB)

The vast majority of fundamental studies of metal oxide selective oxidation catalysts have been performed with single phase systems. These investigations established the basic tenents of the redox mechanism of selective oxidation and ammoxidation catalysis. By comparison, structural and kinetic investigations of multiphase oxide catalysts are less numerous because of the inherent difficulties in understanding the relative contributions of separate phases to the catalytic behavior of the composite catalyst. Some attempts have been made in the past to understand the complex chemistry of multiphase catalysts and additional important insights have been realized more recently. However, a clear understanding of the most significant catalytic interactions between individual phases of a multiphase multicomponent redox catalyst is still lacking. In an effort to provide an understanding and a physical basis for the observed synergism ...

Energy Technology Data Exchange (ETDEWEB)

Gold and silver nanoparticles display extraordinarily large apparent refractive indices near their plasmon resonance (PR) wavelengths. These nanoparticles show good contrast in a narrow spectral band but are poorly resolved at other wavelengths in differential interference contrast (DIC) microscopy. The wavelength dependence of DIC contrast of gold/silver nanoparticles is interpreted in terms of Mie's theory and DIC working principles. We further exploit this wavelength dependence by modifying a DIC microscope to enable simultaneous imaging at two wavelengths. We demonstrate that gold/silver nanoparticles immobilized on the same glass slides through hybridization can be differentiated and imaged separately. High-contrast, video-rate images of living cells can be recorded both with and without illuminating the gold nanoparticle probes, providing definitive probe identification. Dual-wavelength DIC microscopy thus presents a new approach to the simultaneous ...

Science.gov (United States)

Simple hydroxamic acids have been shown to have useful applications in an Advanced Purex process for the reprocessing of irradiated nuclear fuel. They are especially suited to the separation of neptunium (IV) from uranium (VI) by the selective formation of a hydrophilic complex with Np(IV). U(VI) extraction in to 30% tributyl phosphate is unaffected. However, they have also been shown to be very fast reducing agents for Np(VI). The timescales of the reduction have been defined under a range of typical Purex Process conditions although the accurate determination of the reaction kinetics was not possible due to the rapidity of the reaction. U(VI) was shown not to be reduced. Therefore, Np(VI) can be efficiently reductively stripped when solvent phase (30% tributyl phosphate in odourless kerosene) solutions of Np(VI) and U(VI) are contacted with aqueous phase hydroxamic acid solutions. The slow reduction of plutonium (IV) to Pu(III) has also been ...

International Nuclear Information System (INIS)

A system for real-time neutron radiography of moving objects is described. It comprise a source adapted to generate a continuous uninterrupted series of neutron pulses. Each pulse has a predetermined peak power and duration compatible with the framing times of a real-time video imaging system. A transporter moves an object to be examined to bring sequentially position selected portions of the object in the path of the pulses. Where the object itself has moving components, pulses are sequentially incident on the object. According to any dissimilarities, the object will alter the intensity of the neutrons passing therethrough. In order to record separately the changes in the neutron intensity, for each pulse, an imager is positioned to receive the neutron beam pulses which have been altered by their passage through the object and produce images indicating intensity alterations. A refrigerated beryllium filter can be used to effectively eliminate ...

Energy Technology Data Exchange (ETDEWEB)

This study sought to quantitate lidocaine's interaction with alpha-1-acid glycoprotein (AAG), human serum albumin (HSA), and AAG in the presence of HSA, and to determine the extent of displacement of lidocaine from its binding site(s) by selected cardiovascular drugs (dipyridamole, disopyramide and quinidine). Since the limited experimental work reported in this area has involved the use of a single lidocaine concentration, this study involved the evaluation of a range of lidocaine concentrations. Lidocaine interaction with plasma proteins (AAG and HSA) was studied at 37/sup 0/C using an isothermal equilibrium dialysis system and /sup 14/C-lidocaine HCl. A dialysis membrane (M.W. cutoff 12,000 to 14,000) separated the two chambers of each dialysis cell. The extent of /sup 14/C-lidocaine dialysis was studied with respect to both drug and protein concentrations. Aliquots of each chamber of each of the cells were subjected to liquid ...

International Nuclear Information System (INIS)

The performance of larger than bench scale ion exchange systems is evaluated by using solutions containing trace amounts of "1"3"7Cs, "8"5Kr, and "1"3"1I, and large amounts of either NaCl or Na_2HPO_4, H_3BO_3, and LiOH. The significant finding in this study is that the empirical rules of ionic selectivity of strong acid cation and strong base anion resins were followed by all ionic species, even though concentrations of some macrocomponents were nearly 10"6 times those of trace components. Other results of possible importance are the correlation between the instantaneous decontamination factor (DF) and the efficiency of column exchange capacity utilization, and the concept of time average decontamination factor (anti DF). The plot of anti DF vs. feed throughput will serve as a guide in determining when the feed should be discontinued in order to achieve a desired anti DF. Both of these correlations are derived from the breakthrough curves.

International Nuclear Information System (INIS)

In conducting aircraft surveys for uranium, it is found that temperature inversions can give spurious results because they promote accumulation of radon gas in the atmosphere. The "2"1"4Bi (daughter product of radon) gamma-rays detected from the atmosphere-borne radon are difficult to separate from the "2"1"4Bi gamma-rays originating from the ground, and providing a signature for uranium deposits. The purpose of the present study was to examine the feasibility of making remote temperature soundings of the atmosphere below a low-flying aircraft (140 m or less above ground) by the inversion of radiance measurements taken in the 15-micron carbon dioxide absorption band. Such measurements would identify those temperature inversion conditions possibly leading to an unacceptably large background of gamma-rays from the atmospheric radon. Thus, the incidence of spurious aerial survey data could be greatly reduced. An atmospheric model was set up and the ...

Energy Technology Data Exchange (ETDEWEB)

The effects on engine emissions resulting from the intake manifold fumigation of oxygenated fuel and the addition of oxygenates to the fuel have been investigated using a direct-injection diesel engine. The results show that carefully selected oxygenated fuels effectively work to increase the ignition delay because of their low ignition quality and to decrease the combustion temperature due to the low compression gas temperature produced from their large heat of vaporization, thereby reducing levels of Bosch smoke and nitrogen oxides simultaneously. However, supplementary injection of the oxygenates into the intake air causes a drastic increase in the levels of exhaust total hydrocarbons and CO; thus, it can be said that the addition of oxygenates to the fuel is more practical and effective than fumigation if phase separation of the blended fuel may not be occurred. In the case of addition of the oxygenates to the fuel, it is clarified that ...

International Nuclear Information System (INIS)

The atomic explosions in Hiroshima and Nagasaki made the name radiation itself become a nightmare. Notwithstanding this, radiation continued to serve the mankind specially in diagnosis of several human diseases and in the treatment of intractable malignancies. With their latest research tools biologists have now shown a significant shift in the earlier paradigm; even the concept that radiation initiates cancer appears to be no longer tenable. On the contrary, selective radiation doses inhibit growth of cancer cells and radiation in combination with many chemotherapeutic drugs, radiosensitizing chemicals and/or hyperthermia, is emerging as a new modality for cancer treatment which offers high therapeutic advantages. In addition, the deleterious effects of radiation can now be strategically counter poised by the use of many drugs and chemicals. This has been possible by the newer insights gained in the mechanism of biological effects of radiation. The fate of ...

Energy Technology Data Exchange (ETDEWEB)

Quantitative trait loci (QTL) for growth traits, water use efficiency and tolerance/resistance against metals and herbivores have been identified. A hybrid F2 population originating from a cross between a Salix dasyclados-clone (SW901290) and a S. viminalis-clone ('Jorunn') was used for the different studies in this project. The growth response was analyzed in a greenhouse experiment with two water treatments, normal and drought. In addition, three field experiments with contrasting soils and climates were established. QTL specific for each treatment or field environment but also QTL stable over the treatments or field environments were detected. Each QTL explained from 8 to 29 % of the phenotypic variation depending on trait, treatment or field environment. Clusters of QTL for different traits were mapped indicating a common genetic base or tightly-linked QTL. Stable QTL identified for dryweight can be useful tools for early selection in Salix. ...

Energy Technology Data Exchange (ETDEWEB)

Ionic liquids can enhance the activity, selectivity, and stability of enzyme catalysts. Enzymes and ionic liquids as catalysts are seen as a more environmentally friendly technology than the use of traditional catalyst materials in biofuels production. This study investigated the lipase catalyzed esterification reaction for biodiesel production in the presence of the ionic liquid BMIM PF{sub 6}. Methyl acetate was used as the acyl acceptor. A titremetric assay was conducted to measure the activity of the lipase with various amounts of ionic liquid. Reaction parameters were investigated in order to determine their effects on biodiesel conversion. An 80 per cent overall methyl oleate biodiesel yield was successfully produced in the presence of the ionic liquid. The ionic liquid improved lipase activity as well as overall biodiesel yield. Results also showed that the addition of the ionic liquid facilitated the separation of methyl esters from ...

CERN Document Server

We present new low resolution Spitzer mid-infrared spectroscopy of a sample of 20 ROSAT selected local Narrow Line Seyfert 1 galaxies (NLS1s). We detect strong AGN continuum in all and clear PAH emission in 70% of the sources. The 6.2 micron PAH luminosity spans three orders of magnitudes, from ~10^(39) erg/s to ~10^(42) erg/s providing strong evidence for intense ongoing star formation in the circumnuclear regions of these sources. Using the IRS/Spitzer archive we gather a large number of additional NLS1s and their broad line counterparts (BLS1s) and constructed NLS1 and BLS1 sub-samples to compare them in various ways. The comparison shows a clear separation according to FWHM(H_beta) such that objects with narrower broad H_beta lines are the strongest PAH emitters. We test this division in various ways trying to remove biases due to luminosity and aperture size. Specifically, we find that star formation activity around NLS1 AGN is larger than ...

Energy Technology Data Exchange (ETDEWEB)

The goal of this project is to develop a bench-scale procedure to produce clean, desulfurized, premium-quality chars from the Illinois basin coals. This goal is achieved by utilizing the effective capabilty of smectites in combination with methane to manipulate the char yields. The major objectives are: to determine the optimum water- ground particle size for the maximum reduction of pyrite and minerals by the selective-bitumen agglomeration process; to evaluate the type of smectite and its interlamellar cation which enhances the premium-quality char yields; to find the mode of dispersion of smectites in clean coal which retards the agglomeration of char during mild gasification; to probe the conditions that maximize the desulfurized clean-char yields under a combination of methane+oxygen or helium+oxygen; to characterize and accomplish a material balance of chars, liquids, and gases produced during mild gasification; to identify the conditions which reject ...

Energy Technology Data Exchange (ETDEWEB)

Biocatalytic Desulfurization (BDS) represents an alternative approach to the reduction of sulfur in fossil fuels. The objective is to use bacteria to selectively remove sulfur from petroleum and middle distillate fractions, without the concomitant release of carbon. Recently, bacteria have been developed which have the ability to desulfurize dibenzothiophene (DBT) and other organosulfur molecules. These bacteria are being developed for use in a biocatalyst-based desulfurization process. Analysis of preliminary conceptual engineering designs has shown that this process has the potential to complement conventional technology as a method to temper the sulfur levels in crude oil, or remove the recalcitrant sulfur in middle distillates to achieve the deep desulfurization mandated by State and Federal regulations. This paper describes the results of initial feasibility studies, sensitivity analyses and conceptual design work. Feasibility studies with various crude oils ...

CERN Document Server

In this review, we show how advances in the theory of magnetic pseudodifferential operators (magnetic $\\Psi$DO) can be put to good use in space-adiabatic perturbation theory (SAPT). As a particular example, we extend results of [PST03] to a more general class of magnetic fields: we consider a single particle moving in a periodic potential which is subjectd to a weak and slowly-varying electromagnetic field. In addition to the semiclassical parameter $\\eps \\ll 1$ which quantifies the separation of spatial scales, we explore the influence of additional parameters that allow us to selectively switch off the magnetic field. We find that even in the case of magnetic fields with components in $C_b^{\\infty}(\\R^d)$, e. g. for constant magnetic fields, the results of Panati, Spohn and Teufel hold, i.e. to each isolated family of Bloch bands, there exists an associated almost invariant subspace of $L^2(\\R^d)$ and an effective hamiltonian which ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the work performed during FY 1995 by Pacific Northwest Laboratory in developing and optimizing analysis techniques for identifying organics present in Hanford waste tanks. The main focus was to provide a means for rapidly obtaining the most useful information concerning the organics present in tank waste, with minimal sample handling and with minimal waste generation. One major focus has been to optimize analytical methods for organic speciation. Select methods, such as atmospheric pressure chemical ionization mass spectrometry and matrix-assisted laser desorption/ionization mass spectrometry, were developed to increase the speciation capabilities, while minimizing sample handling. A capillary electrophoresis method was developed to improve separation capabilities while minimizing additional waste generation. In addition, considerable emphasis has been placed on developing a rapid screening tool, based on Raman and ...

Energy Technology Data Exchange (ETDEWEB)

A process is described for removing carbon dioxide from a feed stream of natural gas, having at least methane, ethane and heavier hydrocarbon, comprising: separating the feed stream in a first separator to form a first stream, having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane, and a second stream, having methane, carbon dioxide and ethane; mixing the second stream with a polar compound to form a third stream; separating the vapor and liquid of the third stream in the bottom portion of an absorber; absorbing carbon dioxide and ethane from the separated vapor of Step C in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane forming a fourth stream; separating the ethane from the polar compound and carbon dioxide in a separator; separating the first stream in a ...

International Nuclear Information System (INIS)

Full text: The isotopic assay instrument under development at Pacific Northwest National Laboratory (PNNL) is capable of rapid prescreening to detect small and rare particles containing high concentrations of uranium in a heterogeneous sample. The isotopic measurement concept is based on laser vaporization of solid samples followed by sensitive isotope-specific detection using either uranium atomic fluorescence emission or uranium atomic absorbance. Both isotopes are measured concurrently, following a single ablation laser pulse using two external-cavity violet diode lasers. The simultaneous measurement of both isotopes enables the correlation of the fluorescence and absorbance signals on a shot-to-shot basis. This measurement approach demonstrated negligible channel crosstalk between isotopes. Scanning the heterogeneous samples provides high-resolution imagery of sample isotopic fluorescence and absorbance. Isotopically selective excitation of uranium vapor also ...

Energy Technology Data Exchange (ETDEWEB)

Microwave assisted extraction (MAE) is a combination of a microwave technique and conventional solvent extraction used in the modernization of traditional Chinese medicine. The effective component of medicinal herbs is mostly cellular material which can be released via solvent extraction. The material is diffused to solvents via the porous membrane wall. The structure of herb morphology and characteristics of the solute's molecular weight play an important role in the extraction process of target compounds. Astragalus pieces were chosen for this study in which an ultra-filtration membrane method was used to determine the molecular weight distribution characteristics of Astragalus water extraction liquid in the process of MAE. The fine structure of matrix materials was also characterized by scanning election microscopy (SEM). The phenomenon of mass flow and mass transfer in the plant porous media was discussed along with the enhancement mechanism of ...

Energy Technology Data Exchange (ETDEWEB)

For the construction of underground facilities comprising access tunnels, connecting tunnels, main tunnels and disposal tunnels, a large number of tunnels will be excavated in deep rock formations. These excavations will extend hundreds kilometers in total length. Therefore, special attention must be paid, to transporting large volume of debris, ventilation, emergency escape routes in case of accident, and other factors. In addition, special attention must also paid to potential accidents which might in underground excavations, including unstable facing phenomena (such as collapse and swelling of facing at weak layer sections), spring water flow resulting collapse of rock, gas eruption, and rock burst. While considering these factors to be emphasized during the construction of geological disposal facilities, the investigation reviewed the existing working methods on individual construction technologies of access tunnels, main tunnels, connecting tunnels, disposal tunnels, and disposal ...

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The design of separation devices, particularly for solvent-based selective removal of H{sub 2}S from CO{sub 2}, requires an accurate mathematical model. Unfortunately, this requirement for high accuracy is often in conflict with the need for efficient computation. The addition of more and more complicated analyses, such as a move from Henry's law to a method incorporating gas and liquid activities for computing vapor liquid equilibria, may give a more accurate solution, but only at the cost of decreased computational efficiency. The efforts in this work have been directed toward two goals. The first was to develop an accurate mathematical model for the aqueous methyldiethanolamine (MDEA) system. The steady-state packed column model developed in this work has been tested with data from Schubert (1988) to verify its accuracy. The second goal was to modify the model to improve its computational efficiency. Areas such as vapor-liquid ...

Energy Technology Data Exchange (ETDEWEB)

The use of platinum(II) complexes as tags and probes for biomolecules is indeed advantageous for their reactivities can be selective for certain purposes through an interplay of mild reaction conditions and of the ligands bound to the platinum. The use of {sup 195}Pt NMR as a method of detecting platinum and its interactions with biomolecules was carried out with the simplest model of platinum(II) tagging to proteins. Variable-temperature {sup 195}Pt NMR spectroscopy proved useful in studying the stereodynamics of complex thioethers like methionine. The complex, Pt(trpy)Cl{sup +}, with its chromophore has a greater potential for probing proteins. It is a noninvasive and selective tag for histidine and cysteine residues on the surface of cytochrome c at pH 5. The protein derivatives obtained are separable, and the tags are easily quantitated and differentiated through the metal-to-ligand charge transfer bands which are ...

Science.gov (United States)

In this paper, necessary and sufficient conditions for successful detection of errors in a binary adder by any separate code are developed. The author demonstrates the existence of separate checking codes for addition modulo (2 sup n) ( n > or = 4) and mo...

Science.gov (United States)

Children Who Won't Go To School (Separation Anxiety) No. 7; Updated March 2011 Click here to ... and behaviors are common among children with separation anxiety disorder. The potential long-term effects (anxiety and ...

Science.gov (United States)

impflrtant to the understanding of complex vortical flows. ... tions like the slender wing, flow separations are controlled in the s,. ...... 10, AGARD LS-121, Dec. ...

Science.gov (United States)

flow over the suction surface of a modern low- ..... the flow because of its proximity to the separation point ..... Pressure Turbines, AGARD Lecture Series 167, ...

Energy Technology Data Exchange (ETDEWEB)

Methods were developed for the separation of radioactively labeled carbohydrate components of proteoglycans by isocratic ion-moderated partition HPLC. Neutral sugars were separated after hydrolysis in trifluoroacetic acid with baseline separation between glucose, xylose, galactose, fucose, and mannose. N-Acetylneuraminic acid, N-acetylated hexosamines, glucose, galactose, and xylitol were likewise well separated from each other under isocratic elution conditions. Glucuronic acid, iduronic acid, and their lactones were separated after hydrolysis in formic acid and sulfuric acid. Glucosamine, galactosamine, galactosaminitol, and glucosaminitol were separated by HPLC on a cation exchanger with neutral buffer after hydrolysis in hydrochloric acid. THe separation techniques also proved useful in fractionation of exoglycosidase digests of O- and ...

Science.gov (United States)

PMID:4317460

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

UK PubMed Central (United Kingdom)

Artificial selection and experimental evolution document natural selection under controlled conditions. Collectively, these techniques are continuing to provide fresh and important insights into the...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for removing carbon dioxide from a feed stream of natural gas having at least methane, ethane and heavier. It comprises: first, separating the feed stream in a first separator to form a first stream having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane and a second stream, having methane, carbon dioxide and ethane; separating the second stream in a second separator into a stream of carbon dioxide product and a third stream having ethane, methane and carbon dioxide: mixing at least a portion of the third stream with a polar compound; stream after the mixing in an absorber; separating the vapor and liquid of the third stream after the mixing in an absorber; absorbing the remaining unabsorbed carbon dioxide in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane with the ...

International Nuclear Information System (INIS)

The possibility of separation in plasma-mass-separator POMS-E-3 spent nuclear fuel (SNF) in 3 fractions: transuranic elements, and two groups of fission products. New scheme of compact energy-mass analyzer for monitoring the separation process spent nuclear fuel in the POMS-E- 3 offered.

Energy Technology Data Exchange (ETDEWEB)

Three papers are included. A separate abstract was prepared for each one. (MHR)

Medline Plus

... many bones. The bones are separated by special hinges called joints. Muscles make the bones move on ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared

Energy Technology Data Exchange (ETDEWEB)

Published in summary form only.

Science.gov (United States)

Feasibility of depositing continuous films of nano-porous alumino-silicates, primarily zeolites and MCM-41, on metallic and non-metallic substrates was examined with an aim to develop membranes for separation of gaseous mixtures and also for application as hydrogen storage material. Mesoporous silica was deposited in-side the pores of these nano-porous disks with an aim to develop membranes for selective separations. Our study involves supported zeolite film growth on substrates using in-situ hydrothermal synthesis. Faujasite, Silicalite and Mesoporous silica have been grown on various metallic and non-metallic supports. Metallic substrates used for film growth included anodized titanium, sodium hydroxide treated Titanium, Anodized aluminum, and sintered copper. A non-metallic substrate used was nano-porous aluminum oxide. Zeolite film growth was characterized using Scanning Electron Microscope (AMRAY 1820) and High ...

Science.gov (United States)

The technology for flue gas desulfurization (FGD) with seawater is widely adopted by coal-fired power plants in coastal areas. SO2 in the flue gas is absorbed by alkaline seawater and transfered in aqueous phase as sulfite (SO3(2-)), and most SO3(2-) is transformed to sulfate (SO4(2-)) after an aeration process. The remaining SO3(2-) in the seawater discharged to sea area may be harmful to marine organism because of its biological toxicity, thus it is necessary to determine the concentration of SO3(2-) in the seawater for desulfurization. In this study, the method of determination of SO3(2-) in the seawater by ion chromatography was investigated. The separation was achieved on an IonPac AS14A column with 14 mmol/L NaOH-12 mmol/L Na2 CO3 solution as the mobile phase at a flow rate of 1.2 mL/min, and the detection was performed by a pulsed amperometric detector. Formaldehyde was added as a protective agent when sampling because the SO3(2-) is easy to be oxidized. To ...

Energy Technology Data Exchange (ETDEWEB)

Following a referendum in Italy in 1987, the four Nuclear Power Plants (NPPs) owned and operated by the state utility ENEL were closed. After closing the NPPs, ENEL selected a ''safestore'' decommissioning strategy; anticipating a safestore period of some 40-50 years. This approach was consistent with the funds collected during plant operation, and was reinforced by the lack of both a waste repository and a set of national free release limits for contaminated materials in Italy. During 1999, twin decisions were made to privatize ENEL and to transform the nuclear division into a separate subsidiary of the ENEL group. This group was renamed Sogin and during the following year, ownership of the company was transferred to the Italian Treasury. On formation, Sogin was asked by the Italian government to review the national decommissioning strategy. The objective of the review was to move from a safestore strategy ...

Energy Technology Data Exchange (ETDEWEB)

Moisture profiles from neutron probe data provide valuable information in site characterization and to supplement ground water monitoring efforts. The neutron probe precision error (reproducibility) is found to be about 0.2 vol% under in situ field conditions where the slope in moisture content with depth is varying slowly. This error is about 2 times larger near moisture spikes (e.g., at the vapor phase notch), due to the sensitivity of the probe response to vertical position errors on the order of 0.5 inches. Calibrations were performed to correct the downhole probe response to the volumetric moisture content determined on core samples. Calibration is sensitive to borehole diameter and casing type, requiring 3 separate calibration relations for the boreholes surveyed here. Power law fits were used for calibration in this study to assure moisture content results greater than zero. Findings in the boreholes reported here confirm the broad features seen previously ...

International Nuclear Information System (INIS)

With the aim of preparing carrier-free "2"8Mg and "4"7Ca simultaneously, Ti, V and Fe targets were examined by irradiating with high-energy ions of "1"2C, "1"4N and "1"6O accelerated by the RIKEN ring cyclotron. Among the targets, V gave the highest cross section for the formation of both "2"8Mg and "4"7Ca irrespective of the kind of beams. The cross section for the formation of "2"8Mg by the reactions of Ti, V and Fe targets with ion beams increased in the order of "1"2C<"1"6O<"1"4N. On the other hand, the three beams exhibited almost the same cross sections for the formation of "4"7Ca by the reaction of a given target. Titanium and V were selected as prospective targets and "1"4N as a suitable beam for the production of "2"8Mg and "4"7Ca. Chemical separation procedures of the radiotracers in carrier- and salt-free states have been established by using cation exchange resins. The recovery yields of "2"8Mg and "4"7Ca from Ti target were ...

International Nuclear Information System (INIS)

A simple and rapid laser fluorometric determination of trace and ultra trace level of uranium in a wide variety of low uranium content materials like soil, basic and ultra basic rocks, plant ash, coal fly ash and red mud samples is described. Interference studies of some common major, minor and trace elements likely to be present in different geological materials on uranium fluorescence are studied using different fluorescence enhancing reagents like sodium pyrophosphate, orthophosphoric acid, penta sodium tri-polyphosphate and sodium hexametaphosphate. The accurate determination of very low uranium content samples which are rich in iron, manganese and calcium, is possible only after the selective separation of uranium. Conditions suitable for the quantitative single step extraction of 25 ng to 20 #mu#g uranium with tri-n-octylphosphine oxide and single step quantitative stripping with dilute neutral sodium pyrophosphate, which also acts as ...

Science.gov (United States)

The purpose of this study was to examine arachidonic acid (AA) metabolism and to characterize the type of adrenergic receptor (AR) involved in the production of the major metabolite of this fatty acid. ({sup 14}C)AA was incubated with GPT-rings and the radiolabelled products were extracted and separated by TLC method. The medium was also assayed for radiolabelled immunoreactive PG's (iPG's) and leukotrienes (LT) B4 and C4 by RIA or Enzyme immunoassay (EIA) after exposure to various AR agonists. ({sup 14}C)AA was incorporated into GPT-rings and metabolized mainly into iPGE2 and smaller amounts into PGF2{alpha}. Trace amounts of PGD2 and 6-keto-PGF1{alpha} but not LTB4 or LTC4 were detected by RIA and/or EIA. Incubation of GPT rings for 15 minutes with isoproterenol and salbutamol resulted in a significant increase of PGE2 synthesis (optimum conc: 10{sup {minus}7}, 10{sup {minus}7}M respectively). In contrast, dobutamine, norepinephrine, ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of the workshop was to determine the status of the field, to define instrumental and computational requirements, and to establish minimum specifications required by possible users. The most important message sent by implementers was the remainder that CMT is a tool. It solves a wide spectrum of scientific problems and is complementary to other microscopy techniques, with certain important advantages that the other methods do not have. High-resolution CMT can be used non-invasively and non-destructively to study a variety of hierarchical three-dimensional microstructures, which in turn control body function. X-ray computed microtomography can also be used at the frontiers of physics, in the study of granular systems, for example. With high-resolution CMT, for example, three-dimensional pore geometries and topologies of soils and rocks can be obtained readily and implemented directly in transport models. In turn, these geometries can be used to calculate fundamental physical ...

Energy Technology Data Exchange (ETDEWEB)

We labelled Lipiodol with yttrium-90 and analysed the biodistribution in rats after intrahepatic arterial injection. An RP-18 column was used to separate {sup 90}Y from strontium-90. {sup 90}Y was retained on the column, which had been pretreated with yttrium-selective extraction reagent, di(2-ethylhexyl) phosphate, while {sup 90}Sr was washed out. A hexadentate nitrogen-donor chelating ligand N,N,N`,N`-tetrakis(2-benzymidazolylmethyl)-1,2-ethanediamine (EDTB) was synthesized by condensation of 1,2-benzenediamine and ethylene diamine tetra-acetic acid (EDTA). Lipiodol was covalently conjugated with EDTB. The final product was obtained by eluting the retained {sup 90}Y from the RP-18 column with EDTB-Lipiodol. Sixteen male rats (Sprague-Dawley) were sacrificed at 1 h, 24 h, 48 h and 72 h (four rats at each time) after injection of approximately 0.1 mCi {sup 90}Y-Lipiodol via the hepatic artery. Samples of liver, spleen, muscle, lung, kidney, ...

International Nuclear Information System (INIS)

SX Holdings Limited intends to establish a rare earths plant at Port Pirie, South Australia. The proposal involves three stages of development, Stage 3 being to develop a monazite cracking plant and associated rare earths separation facility with the capacity to process up to 8,000 t/a of monazite-type ores. The proposed initial capacity is 4,000 t/a. This Draft Environmental Impact Statement relates to Stage 3 and is based on a monazite processing capacity of 8,000 t/a. The justification of the project is given in terms of use and the market for rare earths, the economic and environmental benefits of the proposal, the site selection process, site rehabilitation, and the consequences of not proceeding. A detailed description of the project is given, including the treatment process, site development and facilities, the supply of raw materials, product and waste handling, transport and storage, plant commissioning, operation and decommissioning, ...

Science.gov (United States)

We argue that published results demonstrate that new insights into human brain function may be obscured by poor and/or limited choices in the data-processing pipeline, and review the work on performance metrics for optimizing pipelines: prediction, reproducibility, and related empirical Receiver Operating Characteristic (ROC) curve metrics. Using the NPAIRS split-half resampling framework for estimating prediction/reproducibility metrics (Strother et al., 2002), we illustrate its use by testing the relative importance of selected pipeline components (interpolation, in-plane spatial smoothing, temporal detrending, and between-subject alignment) in a group analysis of BOLD-fMRI scans from 16 subjects performing a block-design, parametric-static-force task. Large-scale brain networks were detected using a multivariate linear discriminant analysis (canonical variates analysis, CVA) that was tuned to fit the data. We found that tuning the CVA model and spatial smoothing ...

Science.gov (United States)

In the self-cooling blankets of the Tokamak fusion reactor, a liquid metal, namely liquid lithium, is pumped through a system of ducts to transfer heat and capture neutrons. One of the blanket designs proposed in Argonne National Laboratory's Blanket Comparison and Selection study uses a combination of poloidal and toroidal ducts in order to maximize heat transfer while minimizing net pressure drop. In the design, the poloidal and toroidal ducts meet at sharp, abrupt corners. They were modelled as two identical, straight, semi-infinite, thin-walled, rectangular ducts with 45{degree} miters and joined at a 90{degree} angle in the plane of a strong, uniform magnetic field. While in the toroidal containment vessel (i.e. the blanket), the liquid lithium is subjected to a large electromagnetic body force due to the presence of a strong magnetic field. This body force so dominates the flow as to make the inertial and viscous forces negligible everywhere, except ...

International Nuclear Information System (INIS)

A selected series of 24 patients with displaced medial femoral neck fracture, treated with closed reduction and osteosynthesis with cancellous bone screws (ASIF), were investigated. During an observation period of 6 to 26 months, serial hip joint scintigraphies were performed and compared with serial X-ray examinations. At the first scintigraphic examination performed on average 5-6 weeks after the fracture, two separate investigators found a decreased amount of activity or no activity in the femoral head of 10 and 8 patients, respectively. At the second scintigraphic examination performed on average 11.1 weeks after the fracture both investigators found no activity or a decreased amount of activity in 8 patients. This figure declined to 7 during the following period, because one patient with decreased activity was recorded as having normal activity 15 months after the fracture. These 7 patients all developed radiological signs of femoral head ...

International Nuclear Information System (INIS)

Laser spectroscopy measurements have been performed on neutron-deficient and stable Ir isotopes using the COMPLIS experimental setup installed at ISOLDE-CERN. The radioactive Ir atoms were obtained from successive decays of a mass-separated Hg beam deposited onto a carbon substrate after deceleration to 1kV and subsequently laser desorbed. A three-color, two-step resonant scheme was used to selectively ionize the desorbed Ir atoms. The hyperfine structure (HFS) and isotope shift (IS) of the first transition of the ionization path 5d"76s"2"4F_9_/_2#->#5d"76s6p"6F_1_1_/_2 at 351.5nm were measured for "1"8"2"-"1"8"9Ir, "1"8"6Ir"m and the stable "1"9"1","1"9"3Ir. The nuclear magnetic moments #mu#_I and the spectroscopic quadrupole moments Q_s were obtained from the HFS spectra and the change of the mean square charge radii from the IS measurements. The sign of #mu#_I was experimentally determined for the first time for the masses 182#=#+0.2 for ...

International Nuclear Information System (INIS)

Derivatives of angiotensin with a sarcosine substitution at the carboxy terminus and an aliphatic amino acid substitution at the amino terminus have been shown to be competitive ligands for the angiotensin receptor. Scatchard plots derived from saturation isotherm data in bovine adrenal particulates consistently demonstrate three to five times the number of binding sites for "1"2"5I-Sarl,Ile8-AII ("1"2"5I-SI-AII) than for "1"2"5I-AII in experiments in which the two ligands are run side-by-side. A significant difference between "1"2"5I-AII and "1"2"5I-SI-AII binding to detergent solubilized angiotensin receptors was observed. Of the "1"2"5I-AII binding sites, about 85-90% were recovered upon solubilization. In contrast, the recovery of "1"2"5I-SI-AII binding sites was only 4-5%. To determine whether binding sites labeled in the soluble state represent biologically significant AII receptors, they examined the ability of selected angiotensin analogs to inhibit ...

Energy Technology Data Exchange (ETDEWEB)

Oxide catalysis plays a central role in hydrocarbon processing and improvements in catalytic activity or selectivity are of great technological importance because these improvements will translate directly into more efficient utilization of hydrocarbon supplies and lower energy consumption in separation processes. An understanding of the relationships between surface structure and catalytic properties is needed to describe and improve oxide catalysts. Our approach has been to prepare supported oxides that have a specific structure and oxidation state and then employ these structures in reaction studies. Our current research program is focused on studying the fundamental relationships between structure and reactivity for two important reactions that are present in many oxide-catalyzed processes, partial oxidation and carbon-carbon bond formation. Oxide catalysis can be a complex process with both metal cation and oxygen anions participating in ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes a gas transmission pipeline company with dissimilar local control and Supervisory Control and Data Acquisition (SCADA) systems that had formed over time, and the solution that was put into place to consolidate those systems. Great Lakes Gas Transmission Company (GLGT) had historically operated the pipeline from four geographically different locations with a combination of various local man-machine interface (MMI) control systems and an aging SCADA system. As new control systems were installed at compressor and meter stations, local and corporate data acquisition needs changed. It became apparent that the existing SCADA system which telemetered a minimal set of control data could no longer support growth requirements. The decision was made to replace the old SCADA system with a new open state-of-the-art architecture. As a result of competitive bidding, the Valmet OASyS (Open Architecture SyStem) was selected and installed at multiple locations ...

International Nuclear Information System (INIS)

Studies investigated whether changes in omega- and (omega-1)-hydroxylation (OH) of lauric acid (LA) occurred in renal microsomes prepared from SHR compared to Wistar-Kyoto (WK) control rats. Systolic blood pressure in age-matched adult SHR and WKR were 189 +/- 3 and 123 +/- 4 mm Hg(anti X +/- SE) respectively (p < 0.001). No significant differences between SHR and WKR were seen in body weight, kidney weight or renal microsomal protein content. Renal microsomes, prepared from whole kidneys, were incubated with 10 mM NADPH and ["1"4C]LA at concentrations between 5-50 #mu#M. The 11- and 12-OH metabolites of LA were separated by HPLC using a reverse phase column with a methanol:water:acetic acid (62:37.8:0.2) mobile phase. Apparent (app) V/sub max/ values for 12-OH in WKR and SHR were 0.87 +/- 0.19 vs 1.48 +/- .11 nmoles/mg protein/min (p < 0.05), respectively, while values for 11-OH were 0.51 +/- 0.12 vs 0.60 +/- .07, respectively. No significant differences ...

International Nuclear Information System (INIS)

This paper reports that only a few years ago superconducting magnetic separation was viewed as the next major market for superconducting magnets. The first commercial units had been installed, worked flawlessly, and demonstrated real economic viability. The potential market was seen as quite large, and many people believed that superconducting magnetic separation would soon show the same rapid growth that MRI had demonstrated after its initial success. These hopes even prompted IGC, one of the top MRI magnet builders, to form a separate division devoted to magnetic separation. Despite the existence of Magstream, IGC has not been overly active in the market. As a technology that has applications from the clay on the Earth to the soil on the moon, superconducting magnetic separation has yet to become widely used.

Science.gov (United States)

Economic and performance criteria that should be used in the selection of a scrubber system are presented. Selection should be based on the type of emissions put out by a plant and the removal efficiency required by pollution control standards. Costs and efficiencies for 10 different scrubber systems are reported. (10 diagrams)

UK PubMed Central (United Kingdom)

The development of several DDT-resistant strains of Anopheles atroparvus is described. They were selected by larval treatment only (RL), selection of larval and adult females (RLAF),...Full Text Available

Science.gov (United States)

... Title : Selection, Training, and Control Problems in the Use of the Military Working Dog. Descriptive Note : Final rept. 15 Jan 72-14 Sep 73,. ...

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass serves as reaction ...

UK PubMed Central (United Kingdom)

The chloroplast and cytoplasmic isoenzymes of phosphoglycerate kinase (PGK) (EC. 2.7.2.3) from Hordeum vulgare leaves have been separated and purified for the first time to apparent...Full Text Available

Science.gov (United States)

(accumulates & stores brine for disposal). Separator. (separates water from purge gases). ? Purge pump periodically vent ... Reactor Health. Sensor. ( verifies reactor is operating w/n limits) ... Waste and Hygiene Compartment ...

International Nuclear Information System (INIS)

A pretreatment flowsheet was tested for separating key radionuclide components from the sludge stored in one of the high level waste tanks (B-110) at the Hanford Site; this sludge resulted primarily from the bismuth phosphate process, which was one of the three major plutonium separation processes used at Handford. This test involved (1) washing with water, (2) caustic leaching, (3) acid dissolution, (4) separation of transuranic elements (TRUs) by extraction with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO), (5) separation of Sr by extraction with di-t-butylcyclohexano-18-crown-6, (6) separation of Cs from the acid-dissolved sludge solution by treatment with ammonium molybdophosphate (AMP), and (7) separation of Cs from the sludge wash and caustic leach solutions by ion exchange using a phenol-formaldehyde resin (CS-100). The results of the ...

Science.gov (United States)

comprehensive description for this model is available through AGARD, Reference [8]. ... Specifically, there is a pocket of flow separation at the side-of- body ...

Science.gov (United States)

... Dynamics Panel Executive AGARD 7 rue ... 4 AXIAL FLOW IN CORNERS AT SUPERSONIC ... AND HYPERSONIC FLOWS INCLUDING SEPARATION ...

Science.gov (United States)

... of drag measurements with the AGARD Nozzle Afterbody ... are discussed separately from flows with a ... bubbles introduce typical flow phenomena that ...

International Nuclear Information System (INIS)

... electrophoresis fission products gamma radiation gamma spectra half-life

Energy Technology Data Exchange (ETDEWEB)

This document requires a separate file for the figures. It is for DOE's Office of Vehicle Technologies Annual Report

Science.gov (United States)

... 65th AGARD Fluid Dynamics Symposium, Madrid, Spain, October ... of research programs on flow control ... separation, and delta wing flows formed the ...

Energy Technology Data Exchange (ETDEWEB)

The effects of temperature and the use of macroreticular resins were studied in lithium isotope separation by an ion-exchange method. The isotope separation factors obtained decreased by increasing the temperature, and the factors for macroreticular resins were identical with those for the usual gel-type resins. However, the performance of isotope separation per unit band length in displacement chromatography was found to be improved by increasing the temperature and using macroreticular resins, because accelerating the interphase mass transfer caused the reduction of HETP (Height Equivalent to a Theoretical Plate).

Energy Technology Data Exchange (ETDEWEB)

Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. The heavier lithium isotope was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was determined according to the method of Glueckauf from the elution curve and isotopic assays. The separation factor of {sup 6}Li{sup +} -{sup 7}Li{sup +} isotope pair fractionation was 1.018.

International Nuclear Information System (INIS)

... bismuth chlorides bismuth 207 cadmium chlorides efficiency evaporation high

Energy Technology Data Exchange (ETDEWEB)

This document provides stakeholder evaluations on innovative technologies to be used in the remediation of volatile organic compounds from soils and ground water. The technologies evaluated are; in-well vapor stripping, in-situ bioremediation, and gas membrane separation.

International Nuclear Information System (INIS)

The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.

International Nuclear Information System (INIS)

In order to facilitate observations of low energy nuclear reactions, a new type recoil mass-separator together with a new gas-jet target system is being developed at the tandem accelerator facility in Kyushu University. The expected mass-resolving power of the separator is 220 for a solid angle of 10 msr and the practical thickness of the gas-jet target will exceed 0.1 atm#centre dot#cm for the light elements of H and He. (author).

International Nuclear Information System (INIS)

This patent describes the producing of a refractory metal wherein a sponge refractory metal is produced as an intermediate product by the use of magnesium with the incidental production of magnesium chloride, and wherein residual magnesium is separated from the magnesium chloride and from refractory metal to a vacuum distillation step which fractionally distills the magnesium, the magnesium chloride, and the metal sub-chlorides; the steps of: recovering fractionally distilled vapors of magnesium chloride and metal sub-chlorides from a sponge refractory metal; separately condensing the vapors as separately recovered; and recycling the separately recovered magnesium at a purity of at least about 96%.

Energy Technology Data Exchange (ETDEWEB)

The law of the 30 December 1991 on the high activity long lived radioactive wastes reached the end. This synthesis final document presents the scientific and technological results, obtained still the end of 2005, on the separation and the transmutation of long lived radionuclides of high activity long lived radioactive wastes. It is organized in five chapters: a presentation of the context and the historical aspects, the researches, the objectives and the strategy of the axis 1, the researches results on the advanced separation, the researches results on the transmutation, the scenario of separation-transmutation and their environmental, technical and economical impacts. (A.L.B.)

International Nuclear Information System (INIS)

The presence of an extraneous light gas must be taken into account in consideration of centrifugal separation of uranium isotopes, when there is inevitable leakage of such a gas through the gas sealant and/or leaking in from the atmosphere. Consideration is first given to the influence of the presence of the light gas on the maximum separative power. Then the basic equation for isotope separation containing a light gas is derived from Hirschfelder's diffusion equations. This equation is solved and the separative performance is expressed in terms of the shape factor and reflux parameter. The formulas for expressing the flow configurations of the gases are obtained for a simple model in which inflow and outflow prevail throughout the centrifuge. The corresponding equation for a model in which the gases flow in two concentric thin streams is also derived. It is concluded that the influence provided by the ...

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

Published in summary form only.

Science.gov (United States)

... biologically important compounds is sharply lowered with passage of the solutions to the cell an organ, where their sensitivity ...

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Initially, the decision of the operator in Dortmund-Derne to select the impact-type separator concept is explained. None of the tenderers for this 52 t/h boiler could supply references for this fluidized bed steam generator concept with staged combustion in a high-expansion fluidized bed. Under the circumstances, the simple configuration of the Steinmueller fluidized bed steam generator, its compact construction, the reduced amount of refractory and the operational behaviour of the boiler resulting therefrom were decisive in the operator`s decision to select this concept. The development schedule shows the individual stages from cold and hot trials in various test rigs and pilot plants to the final design. So far, this fluidized bed steam generator concept has been realized in the plants Derne (52 t/h), commissioned in November 1989, and Brilon (100 t/h), commissioned in November 1990. The discussion on the essential design ...

Energy Technology Data Exchange (ETDEWEB)

Q/sub ..beta..-values are determined for 18 nuclei (Zr-, Nb-, Mo-, Tc-, Ru- and Rh-nuclides) with mass numbers 101 less than or equal toA less than or equal to106 and A=109 from measurements of beta decay energies which were carried out at the LOHENGRIN mass separator at the Institut Laue-Langevin in Grenoble (France). The given Q/sub ..beta..-values between 2 and 8 MeV show errors of about 1.5% (with the exception of /sup 103/Zr and /sup 105/Nb resp. and /sup 103/Tc for which larger errors result due to statistical resp. systematic reasons): /sup 101/Zr 5500+-70, /sup 101/Nb 4580+-45, /sup 102/Zr 4670+-40, /sup 102/Nb 7230+-70, /sup 103/Zr 6790+-240, /sup 103/ 5740+-70, /sup 103/Mo 3575+-80, /sup 103/Tc 2585+-70, /sup 104/Nb 8250+-130, /sup 104/Mo 2180+-40, /sup 104/Tc 5520+-100, /sup 105/Nb 6570+-150, /sup 105/Mo 4885+-80, /sup 105/Tc 3750+-60, /sup 106/Mo 3515+-45, /sup 106/Tc 6540+-70, /sup 109/Ru 4150+-80, /sup 109/Rh 2550+-50 (all values in keV). For the ...

Energy Technology Data Exchange (ETDEWEB)

Laser spectroscopy measurements have been performed on neutron-deficient and stable Ir isotopes using the COMPLIS experimental setup installed at ISOLDE-CERN. The radioactive Ir atoms were obtained from successive decays of a mass-separated Hg beam deposited onto a carbon substrate after deceleration to 1kV and subsequently laser desorbed. A three-color, two-step resonant scheme was used to selectively ionize the desorbed Ir atoms. The hyperfine structure (HFS) and isotope shift (IS) of the first transition of the ionization path 5d{sup 7}6s{sup 24}F{sub 9/2}{yields}5d{sup 7}6s6p{sup 6}F{sub 11/2} at 351.5nm were measured for {sup 182-189}Ir, {sup 186}Ir{sup m} and the stable {sup 191,193}Ir. The nuclear magnetic moments {mu}{sub I} and the spectroscopic quadrupole moments Q{sub s} were obtained from the HFS spectra and the change of the mean square charge radii from the IS measurements. The sign of {mu}{sub I} was experimentally determined for ...

CERN Document Server

Educational data mining (EDM) is a new growing research area and the essence of data mining concepts are used in the educational field for the purpose of extracting useful information on the behaviors of students in the learning process. In this EDM, feature selection is to be made for the generation of subset of candidate variables. As the feature selection influences the predictive accuracy of any performance model, it is essential to study elaborately the effectiveness of student performance model in connection with feature selection techniques. In this connection, the present study is devoted not only to investigate the most relevant subset features with minimum cardinality for achieving high predictive performance by adopting various filtered feature selection techniques in data mining but also to evaluate the goodness of subsets with different cardinalities and the quality of six filtered feature ...

Energy Technology Data Exchange (ETDEWEB)

Burnable poisons are used in nuclear reactors to produce a more level distribution of power in the reactor core and to reduce to necessity for a large control system. An ideal burnable poison would burn at the same rate as the fuel. In this study, separation of neutron-absorbing isotopes was investigated in order to eliminate isotopes that remain as absorbers at the end of fuel life, thus reducing useful fuel life. The isotopes Gd-157, Dy-164, and Er-167 were found to have desirable properties. These isotopes were separated from naturally occurring elements by means of plasma separation to evaluate feasibility and cost. It was found that pure Gd-157 could save approximately $6 million at the end of four years. However, the cost of separation, using the existing facility, made separation cost- ineffective. Using a magnet with three times the field strength is expected to reduce the ...

International Nuclear Information System (INIS)

The chemical separation of carrier-free "2"0"3Pb following deuterium bombardment of a "2"0"3Tl target is described. Coprecipitation from strontium sulphate was used to separate the "2"0"3Pb from a solution of the thallium target in sulphuric acid. The SrSO_4 precipitate was filtered, washed and dissolved in hydrochloric acid, from which "2"0"3Pb was again separated by precipitation on sodium chloride from a strongly acid solution. Advantages of the system are discussed and optimum conditions given. (U.K.).

International Nuclear Information System (INIS)

This paper describes the problems and capabilities of highly enriched actinide isotopes production by electromagnetic separation in the S-2 mass separator of VNIIEF. Isotope enrichment characteristics for uranium, plutonium, americium and curium isotopes, used in different nuclear physics experiments, and isotope contamination for single and double separations are presented. The capabilities for highly enriched "2"4"4Pu and "2"4"8Cm production for nuclear accelerator experiments and other applications are described, some details of the current and future programmes are given and the transport packaging is described. (orig.).

Energy Technology Data Exchange (ETDEWEB)

A heat storage compostion comprises sodium sulfate decahydrate as main component, a supercooling inhibitor, and a solid-liquid separation inhibitor. The composition is characterized in that hydraulic calcium sulfate and/or calcium sulfate dihydrate is contained as the solid-liquid separation inhibitor in an amount of 2-15 wt% base on the whole weight of the composition, whereby the solid-liquid separation, i.e. the sedimentation of the anhydrous sodium sulfate during the phase transition, is effectively prevented and the long-term stability is improved. The long-term stabilty of the composition can be more improved by addition of a silcia series of thickener.

Science.gov (United States)

... tests, one often encounters, for instance, separated flows with large ... It is suspected that the flow-quality criteria given in AGARD Report No. ...

UK PubMed Central (United Kingdom)

BackgroundVisual acuity, the ability of the visual system to distinguish two separate objects at a given angular distance, is influenced by the optical and neuronal properties of...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...

Science.gov (United States)

... 14(a)), a short laminar separation bubble is evident on the ... Natural Laminar Flow and Laminar Flow Control, RW Barnwell and MY ... AGARD CP No. ...

International Nuclear Information System (INIS)

Studies on the separation of Ag(I) during the recovery of Pu from analytical waste generated during potentiometric determination of Pu using AgO as oxidant, by precipitation of Pu as ammonium plutonium (III) oxalate have shown that most of the Ag(I) is separated during the reduction of Pu to Pu(III) state by ascorbic acid. A decontamination factor of 54 was obtained. Additional a decontamination factor of 5.8 was obtained during the precipitation of Pu as ammonium plutonium (III) oxalate. The Ag content was determined by gamma spectrometry, using "1"1"1Ag as a tracer (T_1_/_2 7.45 d, #gamma# 342.1 keV) and HPGe as detector. The studies indicate that Ag is preferentially separated almost quantitatively during the recovery of plutonium, when acidity adjustment is done with NaOH instead of NH_3. (author)

UK PubMed Central (United Kingdom)

The tegument of tapeworms is known to be composed of an outer syncytial cytoplasm layer which includes microtriches and cytoplasmic organelles (= syncytial layer), and a parenchymatous cytoplasm layer...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

A simple method is presented for the separation of lead-203 from copper-backed thallium cyclotron targets. The procedure involves cation-exchange chromatography in hydrochloric acid and hydrochloric acid-acetone mixtures. Further purification involves anion-exchange chromatography in nitric acid-hydrobromic acid mixtures. A cation-exchange column containing 3.0 g of resin can handle as much as 15 g of thallium and 160 mg of copper. An anion-exchange column containing 3.0 g of resin can separate lead from up to 200 mg of thallium and 10 mg of copper. Separations are extremely sharp and less than 0.1 ..mu..g of thallium and less than 0.1 ..mu..g of copper remain in the lead-203 fraction.

Energy Technology Data Exchange (ETDEWEB)

Bismuth radioisotopes, produced by 50-MeV proton bombardment of a lead target in a cyclotron, are separated from the lead target material by ion-exchange chromatography on a column containing 5.0 ml of Chelex 100. After a decay period of 24 hr, the /sup 203/Pb formed in situ is eluted from the column and then separated from /sup 200/Tl and /sup 201/Tl on a second ion-exchange column containing 0.5 ml of Chelex 100. Separations are sharp and carrier-free /sup 203/Pb is obtained.

Energy Technology Data Exchange (ETDEWEB)

This document details monthly activities at the Savannah River Laboratory. Topics addressed are reactor operation; tritium facilities and production; separation operations; environmental concerns; and waste management. (FI)

Science.gov (United States)

... After strip- ping off the chloroform, the dibromo ethyl (EDBEB) compounds are separated from the m-BDBEB using a thin film evaporator. ...

Energy Technology Data Exchange (ETDEWEB)

Separate abstracts were prepared for 62 papers in this volume of conference proceedings. Two other papers were previously abstracted for EDB. (LEW)

Energy Technology Data Exchange (ETDEWEB)

Separate abstracts were prepared for the 5 subprojects designated as projects 1 to 4 and 6 in this progress report. (KRM)

Energy Technology Data Exchange (ETDEWEB)

A complex modulated structure is described for reactive elements that have the capability of considerably more heat than organic explosives while generating a working fluid or gas. The explosive and method of fabricating same involves a plurality of very thin, stacked, multilayer structures, each composed of reactive components, such as aluminum, separated from a less reactive element, such as copper oxide, by a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures. The various layers of material, thickness of 10 to 10,000 angstroms, can be deposited by magnetron sputter deposition. The explosive detonates and combusts a high velocity generating a gas, such as CO, and high temperatures. 2 figs.

Energy Technology Data Exchange (ETDEWEB)

A LLX procedure for carrier-free separation of the radioisotopes, {sup 47}Sc, {sup 48}V and {sup 48},{sup 49},{sup 51}Cr, the 40 MeV {alpha}-particle activation products of titanium has been developed. Sequential separations of the radionuclides produced in the titanium matrix through the nuclear reactions ({alpha}, {alpha}p{chi}n), ({alpha}, p{chi}n) and {alpha}, ({chi}n) have been performed through LLX from aqueous H{sub 2}SO{sub 4} and HClO{sub 4} acid media using the liquid cation exchanger, HDEHP, as an extractant. Purity of the carrier-free radiotracers at different stages of their separations has been verified by {gamma}-ray spectrometry. (author).

Science.gov (United States)

indicate incipient flow separation. The peak stagnation line ...... culations of Transonic Fan Performance, AGARD Propul- sion and Energetics Symposium on ...

Science.gov (United States)

flow separation and reattachment. For lifting bodies, the ...... AGARD-CP-428, Apr. 1987. 18Kempel, Robert W., Weneth D. Painter, and ...

Science.gov (United States)

the booms, separated by 12.5 m, deployed using the well proven MILSTAR hinge technology. ...... MILSTAR. Military Strategic and Tactical Relay satellite ...

Science.gov (United States)

The Baldwin-Lomax model is used in many CFD codes because it is quick and easy to implement. In this

Energy Technology Data Exchange (ETDEWEB)

The symposium reviewed the use of electronics in mining today. Subjects covered include control systems; remote sensing; telemetry; data transmission; microprocessors and transportation systems. 15 papers have been abstracted separately.

Science.gov (United States)

verse pressure gradient, makes it susceptible to flow separation, ...... AGARD, Lecture Series LS-167. [25] Eifler, J., 1975, Zur Frage der freien ...

Science.gov (United States)

be due to flow separation and reattachment, rather than transition. The analysis predicted a .... lations of Transonic Fan Performance," AGARD Propulsion ...

Energy Technology Data Exchange (ETDEWEB)

Separate abstracts were prepared for 13 papers in these proceedings. Also included is an overview speech and a panel discussion. (LEW)

Science.gov (United States)

Traditional composite sandwich panels are composed of inner and outer facesheets separated by a core material such as balsa wood, polymeric foam, ...

Energy Technology Data Exchange (ETDEWEB)

It is shown numerically that on a time scale of order 1 msec a neutron star with pion condensation will undergo separation into a core and an envelope with a sharp interface. The envelope will not, however, be ejected.

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Cambridge scientists in the late 1980's. This same team, then headed by Professor John Baldwin, built the world's first separated-element optical/infrared aperture synthesis...

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Hamed, A. and A. Mohamed, "Assessment of Shock Induced Flow Separation and ...... AGARD Symposium on Combined Cycle Propulsion for Hypersonic Application, ...

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... For communication systems that employ spatial audio technology to separate intercom and/or radio channels, configurations of the spatial ...

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... Calculations of asymmetric separated flow past circular ... in Missile Aerodynamics, AGARD CP 336 ... three-dimensional vortex flows in aerodynamics. ...

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Two different approaches can be used in phylogenomics: combined or separate analysis. In the first approach, different datasets are combined in a concatenated supermatrix. In the second, datasets are...Full Text Available

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Separate entries were made for papers within subject scope of the data base.

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TRACON controller, traffic flow manager, or pilot. .... separation violations to individual controller and ..... System, AGARD Meeting on Machine Intelligence ...

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... of "position error" in the AGARD Multilingual Aeronautical ... when it cones into the aircraft flow field it ... on actual bank angle and separation, may be - ...

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flow separation and vortices shed from the airplane forebody when flying at ...... AGARD Conference Proceedings 548: Technologies for Highly Maneuverable ...

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High gradient magnetic separation (HGMS) of magnetic materials from fluids or waste products has many established industrial applications. However, there is currently no technology employing HGMS for ex-vivo biomedical applications, such as for the removal of magnetic drug- or toxin-loaded spheres from the human blood stream. Importantly, human HGMS applications require special design modifications as, in contrast to conventional use where magnetic elements are permanently imbedded within the separation chambers, medical separators need to avoid direct contact between the magnetic materials and blood to reduce the risk of blood clotting and to facilitate convenient and safe treatment access for many individuals. We describe and investigate the performance of a magnetic separator prototype designed for biomedical applications. First, the capture efficiency of a prototype HGMS ...

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The objectives of this study were to select and initially characterize mutants of soybean (Glycine max L. Merr. cv Williams) with decreased ability to reduce nitrate. Selection involved...Full Text Available

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Types of disorders in the earth's surface as a result of open pit mining operations are analyzed. Trends for recultivation of lands are defined. Formulas are presented for calculating the economic expediency of the selected direction of recultivation.

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The objectives of this research are: (1) to assess selected formulation-relevant physical properties of several commercial Feverfew extracts, including flowability, hygroscopicity, compressibility and...Full Text Available

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We evaluated whether ejaculatory dysfunction induced with a selective α1A-blocker influenced orgasm. Fifteen healthy male volunteers took silodosin or a placebo in a randomized, double-blind...Full Text Available

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BackgroundScorpion venom contains insect and mammal selective toxins. We investigated the venom of the South Indian red scorpion, Mesobuthus tamulus for the purpose...Full Text Available

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BackgroundMicroarray data are often used for patient classification and gene selection. An appropriate tool for end users and biomedical researchers should combine user friendliness...Full Text Available

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We compared MRSA Select to mannitol-salt agar with 8 μg/ml cefoxitin for the detection of methicillin-resistant Staphylococcus aureus (MRSA) from 6,199 clinical...Full Text Available

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In this paper, we propose an antenna selection method in a wireless cognitive radio (CR) system, namely difference selection, whereby a single transmit antenna is selected at the secondary transmitter out of $M$ possible antennas such that the weighted difference between the channel gains of the data link and the interference link is maximized. We analyze mutual information and outage probability of the secondary transmission in a CR system with difference antenna selection, and propose a method of optimizing these performance metrics of the secondary data link subject to practical constraints on the peak secondary transmit power and the average interference power as seen by the primary receiver. The optimization is performed over two parameters: the peak secondary transmit power and the difference selection weight $\\delta\\in [0, 1]$. We show that, difference ...

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OBJECTIVES: Although the tricyclic antidepressant amitriptyline is extensively used in the prophylactic treatment of chronic tension-type headache, only few studies have investigated the efficacy of...Full Text Available

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Surface temperature is measured with an infrared thermometer. Measuring Surface Temperature. Nine sample points are selected with a site of uniform land ...

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as magnetic forming and hot-drape forming. Details about the 25 techniques discussed incorporate the most recent improvements and ...

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... select moves. Greeno (1974) showed that only 3.6 repetitions of the Missionaries and Cannibals puzzle were required ...

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2.1.1 Levels of preservation and packaging and the levels of packing to be applied selectively are defined in MIL-STD-2073-1 and are mandatory for use or ...