Energy Technology Data Exchange (ETDEWEB)

In this study, the exhaust gas from a common-rail direct injection diesel engine was investigated both upstream and downstream warm-up catalytic converters (WCC). Three different types of ultra-low sulfur fuels (ethanol-diesel blend, ethanol-diesel blend with cetane improver and pure diesel) were tested in this study. The objective of the work was to study the engine performance and the formation of THC (total hydro carbon), CO (carbon monoxide), NO{sub x} (nitrogen oxides), smoke and PM (particulate matters) when using these fuels. THC and CO emissions of the ethanol-diesel blend fuels were slightly increased, and about 50-80% mean conversion efficiencies of THC and CO on catalysts were achieved in the ECE R49 13-mode cycle. Smoke was decreased by more than 42% in the entire ECE 13-mode cycles. From the measurement of scanning mobility ...

UK PubMed Central (United Kingdom)

The soil-isolated strain XP was identified as Rhodococcus erythropolis. R. erythropolis XP could efficiently desulfurize benzonaphthothiophene, a complicated model sulfur compound that...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The main pollutants from marine diesel engines are oxides of nitrogen (NOx), sulfur oxides (SOx) and particulates (soot). However, the proposed marine diesel engine emission regulations will primarily focus on the levels of NOx and SOx. In the future, once the proposed regulations are met, the limits and levels of other emissions will come under increasing scrutiny, such as particulates, hydrocarbons and carbon monoxide. Regardless of the type of pollutant, there are generally two classes of emission control: (1) techniques that reduce the amount of pollutant formed in the combustion process, or (2) prevent the pollutants from reaching the atmosphere. Unfortunately, some of these control techniques will not be able to meet the incoming regulations. Therefore, this paper identifies the diesel engine emissions of concern, the impending regulations, and the merits of current and future emission control ...

Energy Technology Data Exchange (ETDEWEB)

Biocatalytic Desulfurization (BDS) represents an alternative approach to the reduction of sulfur in fossil fuels. The objective is to use bacteria to selectively remove sulfur from petroleum and middle distillate fractions, without the concomitant release of carbon. Recently, bacteria have been developed which have the ability to desulfurize dibenzothiophene (DBT) and other organosulfur molecules. These bacteria are being developed for use in a biocatalyst-based desulfurization process. Analysis of preliminary conceptual engineering designs has shown that this process has the potential to complement conventional technology as a method to temper the sulfur levels in crude oil, or remove the recalcitrant sulfur in middle distillates to achieve the deep desulfurization mandated by State and Federal regulations. This paper describes the results of initial feasibility studies, sensitivity analyses and ...

International Nuclear Information System (INIS)

An Ultra-Low-Carbon 19% Cr-11% Ni Stainless Steels used in nuclear fuel reprocessing plants where highly corrosion resistance in nitric acid is required has been developed. This steel has optimized the chemistry composition to decrease inclusions and deformation-induced martensitic transformation. The formation of deformation-induced martensite has the potential danger of accelerating corrosion in nitric acid. In this paper, effects of cold reduction and martensitic transformation on corrosion resistance of Ultra-Low-Carbon Stainless Steels in nitric acid are discussed. The developed steel showed excellent corrosion resistance during long-term exposure to nitric acid. (author).

UK PubMed Central (United Kingdom)

In order to investigate the effects ethanol-diesel blends and altitude on the performance and emissions of diesel engine, the comparative experiments were carried out on the bench of turbo-charged diesel...Full Text Available

International Nuclear Information System (INIS)

Reducing count losses and pile-up pulse effects in quantitative and qualitative analysis is necessary for accuracy of analysis. Therefore, the optimum peaking time for particular detector systems is important. For this purpose, pure Se and Zn elements were excited by 59.5 keV ?-rays from a 50 mCi 241Am annular radioactive source in this study. The characteristic x-rays emitted from pure Se and Zn elements were detected by using an ultra low energy Ge (Ultra-LEGe) detector connecting Tennelec TC 244 spectroscopy amplifier at different peaking time modes. Overall pulse widths were determined by HM 203-7 oscilloscope connecting amplifier. The proper peaking time for ultra low energy germanium detector (Ultra-LEGe) is determined about 4 ?s.

Energy Technology Data Exchange (ETDEWEB)

The NREL Sensitized Solar Cell (SSC) Core Program supports the Solar America Initiative by: (1) targeting new devices and processes for commercialization by 2015 that are less expensive, more efficient, highly reliable, and environmentally benign; (2) collaborating with DOE OS/BES to conduct basic research targeting breakthroughs in key areas, such as ultra-high efficiency and/or ultra-low cost materials and devices.

Energy Technology Data Exchange (ETDEWEB)

A method based on the collection of [sup 99]Tc from 500 l sea water samples by anion exchange and further extraction of TcO[sub 4][sup -] into 5% triisooctylamine-xylene has been improved to include a decontamination factor 6.5x10[sup 5] for uranium. The detection limit for [sup 99]Tc is thereby reduced to 3 mBq/m[sup 3].

Energy Technology Data Exchange (ETDEWEB)

The basis of assessment for particulate exhaust emissions is the gravimetric analysis of the particle concentration of diluted exhaust gases at temperatures below 52 C. This is very time consuming and takes sufficient sensitivity at low particulate emission rates like downstream of particle filters. For this reason the C/S-method, based on the thermographic analysis of carbon and sulfur, has been developed as an alternative to the gravimetric anallysis. This method yields particle mass as well as the main particle compounds. Comparisons between both methods have been carried out for heavy duty and automobile diesel engines as well as road vehicles and large diesel engines. The tests were conducted with commercial diesel fuel and also with other fuels, such as heavy oils. It could be shown that the C/S-procedure yields the same results as the gravimetric procedure independent of engine, engine mode and ...

Science.gov (United States)

PMID:21807581

Energy Technology Data Exchange (ETDEWEB)

This patent describes a gas-diesel dual fuel engine apparatus having a diesel engine, a diesel fuel supply system including a diesel fuel injection pump, a gaseous fuel supply system including gaseous fuel regulating valve, and a governing and controlling device for governing the speed of the engine and controlling the switchover of the operation of the engine between a diesel fuel mode and a gaseous fuel mode.

International Nuclear Information System (INIS)

Potassium atoms in selected high-lying np Rydberg states (80 #<=# n #<=# 400) are being used as a tool to examine electron-polar molecule collisions at ultra-low energies (#approx#80 #mu#eV - 1 meV). This energy regime has not been investigated previously and is of interest because the corresponding electron de Broglie wavelength is large, #approx#1300 - 330 Angstrom, and because the collision time is comparable to the period of molecular rotation. A variety of target molecules has been studied, including simple rotors such as HF, and more complex species such as NH_3, CH_3I, CH_2Br_2 and C_6H_5NO_2. These targets encompass a range of dipole moments and rotational behavior, but analysis of the data shows that in each case the cross section #sigma#(#epsilon#) for rotationally-inelastic electron-polar molecule scattering varies approximately as 1/#epsilon# where #epsilon# is the electron energy. Such threshold behavior is not predicted by the Born approximation ...

Energy Technology Data Exchange (ETDEWEB)

In this work we present an ultra-low temperature method for the oxidation of an amorphous silicon-carbide-nitride (SiCN) material. The SiCN is deposited on silicon substrates by plasma enhanced chemical vapor deposition using CH{sub 4}, SiH{sub 4}, and N{sub 2} chemistry. The physical and chemical properties are characterized for the as-deposited SiCN and post-oxidized films are discussed. The SiCN film is exposed to oxygen plasma, where it undergoes a chemical transformation into a binary SiO{sub 2} material system. A 1.7 nm/min oxidation rate is typical for this process and compares favorably to oxidation methods utilizing much higher temperatures. The substrate temperature remains extremely low throughout the oxidation process, T{sub s} < 200 deg. C. Changes in film stress, optical constants, film thickness, surface roughness, and film density are measured. Chemical analysis by X-ray photoelectron spectroscopy is reported for both the as-deposited and ...

Energy Technology Data Exchange (ETDEWEB)

Fischer-Tropsch (F-T) diesel fuel is characterized by a high cetane number, a near-zero sulphur content and a very low aromatic level. On the basis of the recorded incylinder pressures and injector needle lifts, the combustion characteristics of an unmodified single-cylinder direct-injection diesel engine operating on F-T diesel fuel are analyzed and compared with those of conventional diesel fuel operation. The results show that F-T diesel fuel exhibits a slightly longer injection delay and injection duration, an average of 18.7% shorter ignition delay, and a comparable total combustion duration when compared to those of conventional diesel fuel. Meanwhile, F-T diesel fuel displays an average of 26.8% lower peak value of premixed burning rate and a higher peak value of diffusive burning rate. In addition, the F-T diesel ...

British Library Electronic Table of Contents (United Kingdom)

Diesel power technology has been utilized worldwide, especially in remote regions, because of its low initial capital cost. But it has negative effects on the surrounding environment and causes global warming. On the other hand, depleting oil and fuel resources has made it inevitable to seek alternative/renewable energy resources. In Iran, the cost of fuel is highly subsidized. If Iran removes the fuel subsidy, the cost of diesel fuel would increase and the photovoltaic (PV) or hybrid PV/diesel systems would become more attractive. Hybrid photovoltaic/diesel/battery (PV/diesel/bat) systems which use PV energy, combined with diesel generation power and battery bank storage are an excellent solution to decrease diesel generator costs, pollution, and electrification of remote rural areas. In ...

Science.gov (United States)

The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduce...

Energy Technology Data Exchange (ETDEWEB)

Double-crystal high-resolution x-ray fluorescence spectrometry was applied to the state analysis of sulfur in coal and related fly ash. For total sulfur, a proportional relationship exists between fluorescence intensities and the analytical values obtained by the oxygen-combustion method. Two oxidation states of sulfur were identified by a least square curve fitting method, by assuming that the spectrum profile is identical for each sulfur state but the intensity and position are different. The chemical state of sulfur in coal and remaining in fly ash is discussed.

International Nuclear Information System (INIS)

... filters molybdenum alloys production sulfuric acid alloys chemical reactions ...

Wastenet

...direct-injection systems Atomisation from hole-type nozzles (gasoline and diesel) under cavitating flow conditions Spray-wall interaction in gasoline direct injection engines Spray-wall interaction in direct-injection diesel engines Evaporation of multi-component fuels Cavitation in diesel injectors Nozzle flow, air motion, spray development and combustion in marine diesel engines ...

Energy Technology Data Exchange (ETDEWEB)

A single cylinder diesel engine study of water-in-diesel emulsions was conducted to investigate the effect of water emulsification on the engine performance and gases exhaust temperature. Emulsified Diesel fuels of 0, 5, 10, 15 and 20 water/diesel ratios by volume were used in a single cylinder, direct injection diesel engine, operating at 1200-3300 rpm. The results indicate that the addition of water in the form of emulsion improves combustion efficiency. The engine torque, power and brake thermal efficiency increase as the water percentage in the emulsion increases. The average increase in the brake thermal efficiency for 20% water emulsion is approximately 3.5% over the use of diesel for the engine speed range studied. The proper brake specific fuel consumption and gases exhaust temperature decrease as the percentage of water in the emulsion increases. ...

Science.gov (United States)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The collected sample ...

International Nuclear Information System (INIS)

Accelerator mass spectrometry (AMS) represents a powerful technique for the detection of long-lived radionuclides through ultra-low isotope ratio measurements. In many cases, counting atoms rather than decays yields much higher sensitivities. The potential of AMS will be demonstrated on typical radionuclides of interest with half-lives between some tens of years up to a hundred million years. The precise measurement of the 27Al(n,2n)26Al excitation function will be exemplified. Lack of information exists for a list of nuclides as pointed out by nuclear data requests. A brief overview on detection limits and some applications for selected long-lived radionuclides is given.

International Nuclear Information System (INIS)

In this paper, probabilistic safety assessment (PSA) of the station blackout (SBO) and 5th emergency diesel in Daya Bay NPP has been carried out, the calculation method of non-recover factors of power supplies is given, and sensitivity analysis on the connection duration of 5th emergency diesel has been executed. It is concluded that the core damage frequency (CDF) induced by SBO is relatively large, the addition of 5th emergency diesel is very helpful for the CDF reduction, and the connection duration of this diesel has great effect on the CDF reduction

Energy Technology Data Exchange (ETDEWEB)

In this paper, the control scheme of a liquefied petroleum gas (LPG)-diesel dual-fuel engine with electronic control is illustrated, the external characteristics and load characteristics of the LPG-diesel dual-fuel engine and the diesel engine are compared and analysed, and the results of automobile road tests are also given. The experimental results show that, compared with diesel, the output performance of dual fuel is not reduced, while smoke emission of dual fuel is significantly reduced, NO{sub x} emission of dual fuel is hardly changed, but HC emission and CO emission of dual fuel are increased and fuel consumption of dual fuel is reduced. (Author)

Energy Technology Data Exchange (ETDEWEB)

The oxidation of sulfur dioxide in gas diffusion electrodes (GDE) in the presence of a homogeneous catalyst, potassium iodide, is investigated. The influence of this catalyst on the voltage-current (V-I) characteristics of the electrodes and the utilization of sulfur dioxide is determined. It is shown that when using the homogeneous catalyst potassium iodide, the utilization can reach 95-100%.

International Nuclear Information System (INIS)

Published in summary form only.

Science.gov (United States)

The risk of lung cancer associated with diesel exhaust has been calculated from 14 case-control or cohort studies. We evaluated the findings from these studies to determine whether there is sufficient evidence to implicate diesel exhaust as a human lung carcinogen. Four studies found increased risks associated with long-term exposure, although two of the four studies were based on the same cohort of railroad workers. Six studies were inconclusive due to missing information on smoking habits, internal inconsistencies, or inadequate characterization of diesel exposure. Four studies found no statistically significant association. It can be concluded that short-term exposure to diesel engine exhaust (20 years) increases the risk of lung cancer for locomotive engineers, brakemen, and diesel engine mechanics. There is inconsistent evidence on the effects of long-term exposure to ...

International Nuclear Information System (INIS)

Ultra low loading noble metal (0.04-0.12 mg_P_t/cm"2) based electrodes were obtained by direct metallization of non-catalyzed gas diffusion layers via dual ion beam assisted deposition (IBAD) method. Fuel cell performance results reported earlier indicate significant improvements in terms of mass specific power density of 0.297 g_P_t/kW with 250 A thick IBAD deposit (0.04 mg_P_t/cm"2 for a total MEA loading of 0.08 mg_P_t/cm"2) at 0.65 V in contrast to the state of the art power density of 1.18 g_P_t/kW using 1 mg_P_t_(_M_E_A_)/cm"2 at 0.65 V. In this article we report the peroxide radical initiated attack of the membrane electrode assembly utilizing IBAD electrodes in comparison to commercially available E-TEK (now BASF Fuel Cell GmbH) electrodes and find the pathway of membrane degradation as well. A novel segmented fuel cell is used for this purpose to relate membrane degradation to peroxide generation at the electrode/electrolyte interface ...

Energy Technology Data Exchange (ETDEWEB)

Two natural gas/diesel dual fuel conversion systems for the Detroit Diesel 6V-71 transit bus engine were described. The basic concept of a dual fuel engine was to operate a diesel engine with both liquid fuel injection and a lean premixed gas mixture. The engine achieved high efficiency due to the high compression ratio typical of the diesel engine. Test results were obtained using three different calibrations on one engine. The objectives were to match existing engine performance with improved emissions and better overall fuel economics. Results showed that overall, engine conversion has both economic and emissions advantages over a straight diesel engine. However, the durability and in-use applicability of the system remains to be demonstrated with an in-bus demonstration project.. 3 tabs., 4 figs.

Energy Technology Data Exchange (ETDEWEB)

Double-crystal high-resolution X-ray fluorescence spectrometry was applied to the state analysis of sulfur in coal and related fly ash. For total sulfur, a proportional relationship exists between fluorescence intensities and the analytical values obtained by the oxygen-combustion method. Two oxidation states of sulfur were identified by a least square curve fitting method, by assuming that the spectrum profile is identical for each sulfur state but the intensity and the position are different. Sulfur in coal mainly consists of S/sup 2 -/, whereas that in coal fly ash mainly consists of S/sup 6 +/. As much as 0.04-0.08% of S/sup 2 -/ remains in fly ash.

British Library Electronic Table of Contents (United Kingdom)

Nineteen fungal strains having an ability to oxidize elemental sulfur in mineral salts medium were isolated from deteriorated sandstones of Angkor monuments. These fungi formed clearing zone on agar medium supplemented with powder sulfur due to the dissolution of sulfur. Representative of the isolates, strain THIF01, was identified as Fusarium solani on the basis of morphological characteristics and phylogenetic analyses. PCR amplification targeting 16S rRNA gene and analyses of full 16S rRNA gene sequence indicated strain THIF01 harbors an endobacterium Bradyrhizobium sp.; however, involvement of the bacterium in the sulfur oxidation is still unclear. Strain THIF01 oxidized elemental sulfur to thiosulfate and then sulfate. Germination of the spores of strain THIF01 was observed in a liqui...

UK PubMed Central (United Kingdom)

A historical prospective mortality study was conducted on a cohort of 34 156 male members of a heavy construction equipment operators union with potential exposure to diesel exhaust emissions. This...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Research indicates that diesel equipment can be used safely in undergound coal mines provided that certain conditions prevail. These conditions are: the machines and engines are approved for underground use, an adequate maintenance and training program is in effect, an adequate monitoring system with proper instrumentation is used, and adequate ventilation is maintained.

Energy Technology Data Exchange (ETDEWEB)

10 papers are presented with the following titles: coal fueled diesel engine development update at GE transportation systems; features and performance data of Cooper-Bassemer coal-fueled six-cylinder LSB engine; preliminary test data and systems analysis of a high pressure coal fuel processor/engine system concept; study for coal-water-slurry fuel combustion in a high speed diesel engine; design and operation of a medium speed 12-cylinder coal-fueled diesel engine; progress on the investigation of coal water slurry fuel combustion in a medium speed diesel engine: part 5 - combustion studies; injection characteristics of coal-water slurries in medium speed diesel equipment; coal-water slurry spray characteristics of a positive displacement fuel injection system; novel injector techniques for coal-fueled diesel engines; and investigation of break-in wear, ring ...

International Nuclear Information System (INIS)

A study was conducted on diesel engines to find out the effect of induction rate of biogas on engine performance indices. The results of dual fuel engine performance was compared with diesel mode for various levels of biogas induction rate (0.3 to 7.2 l/s) engine load (20% to full load) and injection timing (20.6 to 48 before top dead centre). At full and 80% brake load, the best energy mix between diesel and biogas was 1.5:1 and 4:1 respectively. (author). 7 refs., 7 figs., 4 tabs.

Energy Technology Data Exchange (ETDEWEB)

The design changes of the improved 2,5 l direct injection Diesel engine with the nominal power output of 52 kW and a maximum torque of 143 Nm are described. This engine which is installed in the Ford Transit meets all relevant exhaust emission standards that are presently in effect. (orig.).

Energy Technology Data Exchange (ETDEWEB)

As a maintenance optimization project to improve the safety of Wolsung NPP (Nuclear Power Plant), reliability of diesel generators are estimated based on the operating experience, and improvement options are suggested. A reliability measure is suggested for the estimation of reliability for standby safety systems to reflect availability. It is assessed that the reliability of diesel generators can be much improved if the suggested improvement options are implemented.

Energy Technology Data Exchange (ETDEWEB)

A high-speed light-Diesel engine with direct injection has been developed by the Institute of Combustion Engines, Graz. Thanks to light construction throughout, exhaust gas supercharger and noise-reduced composition a Diesel engine could be built that is comparable to Otto-cycle engines as regards performance, weight, aggregate size and noise production but far superior to these with respect to fuel consumption and exhaust gas emission.

Energy Technology Data Exchange (ETDEWEB)

In this paper coating developments for advanced gas turbine engines (diffusion aluminide coatings, overlay coatings, and ceramic thermal barrier coatings) were desorbed, a selection of current metallic coatings was made and their performance as outlined. Finally coating developments for advanced diesel engines with a view to improved turbocharging or to low heat rejection engines (adiabatic diesel concept) were dealt with. (IHOE).

Science.gov (United States)

The non-blast furnace coke produced in the shaft ovens of the Angarsk Semi-coking Plant is used principally in gas generator ovens and partially as a carbonaceous reducing agent in the ferroalloy process. The sulfur content of this coke is not limited by the standards documents, but it is significant, especially in the production of process gases. In a number of recent years the sulfur removal system of the gasification divisions have been experiencing difficulties, not achieving the assigned gas purification parameters, with a resulting H/sub 2/S concentration in the purified gas of 300-700 mg/m/sup 3/ as compared to the standard of 50. Realizing that in the gasification practically all the organic matter of the coke, including the sulfur, enters the gas, the impairment in the quality of the sulfur removal is related to the increase in the sulfur content of the coke. Thus, an ...

Energy Technology Data Exchange (ETDEWEB)

Dynamic behaviors of gaseous sulfur-containing compounds evolved from pyrolysis of six Chinese coals were studied in the temperature range of up to 800{sup o}C under N{sub 2} and H{sub 2}. The released amount of total sulfur-containing gases was traced by an online flame photometric detector (FPD). Simultaneously, the changes of different sulfur forms, including H{sub 2}S, SO{sub 2}, COS and CS{sub 2}, also were investigated using an online mass spectrometer (MS). FPD results show that the effect of H{sub 2} on gaseous sulfur evolved is complex, which promoted certain peak and suppresses other peaks. Based on the data from MS, it is suggested that a series of competitive reactions between active sulfur and other active matters during pyrolysis may impact on the sulfur form in gas phase. Interactions between active sulfur-containing ...

Science.gov (United States)

...f) Are there additional requirements that must be met? (1) A person subject to this section must: (i) For fuel oils and liquid fuels, obtain, record, and keep records of the percent sulfur by weight from the vendor for each...

Energy Technology Data Exchange (ETDEWEB)

Sulfuric acid hydrogen peroxide mixtures (SPM) are commonly used in the semiconductor industry to remove organic contaminants from wafer surfaces. This viscous solution is very difficult to rinse off water surfaces. Various rinsing conditions were tested and the resulting residual acid left on the water surface was measured. Particle growth resulting from incomplete rinse is correlated with the amount of sulfur on the wafer surface measured by Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS). The amount of sulfur on the wafer structure after the rinse step is strongly affected by the wafer film type and contact angle prior to the SPM clean.

Science.gov (United States)

Contents: Lead smelter operations generating SO2 and particulate; Sulfuric acid plant technology; Lead smelters with sulfuric acid plant SO2 control; Sulfuric acid plant operation with lead sinter machine problems and solutions; SO2 control for ASARCO lea...

British Library Electronic Table of Contents (United Kingdom)

Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...

British Library Electronic Table of Contents (United Kingdom)

In this article, the thermodynamic analysis of the existing diesel engine cogeneration system is performed. All necessary data are obtained from the actual diesel engine cogeneration plant located at Gaziantep, Turkey. The exergy analysis is aimed to evaluate the exergy destruction in each component as well as the exergetic efficiencies. The thermodynamic performance of a 25.32MW electricity and 8.1tons/h steam capacity diesel engine cogeneration system at full load conditions is analyzed. The thermal efficiency of the overall plant is found to be 44.2% and the exergetic efficiency is 40.7%. The exergy balance equations developed in this paper may also be utilized in the exergoeconomic analysis to estimate the production costs depending on various input costs in a diesel cogeneration syste...

Energy Technology Data Exchange (ETDEWEB)

The combustion characteristics of a turbocharged natural gas and diesel dual-fuelled compression ignition (CI) engine are investigated. With the measured cylinder pressures of the engine operated on pure diesel and dual fuel, the ignition delay, effects of pilot diesel and engine load on combustion characteristics are analysed. Emissions of HC, CO, NO{sub x} and smoke are measured and studied too. The results show that the quantity of pilot diesel has important effects on the performance and emissions of a dual-fuel engine at low-load operating conditions. Ignition delay varies with the concentration of natural gas. Smoke is much lower for the developed dual-fuel engine under all the operating conditions. (Author)

Energy Technology Data Exchange (ETDEWEB)

NO[sub x] emission legislation requirements for large-bore internal combustion engines have required engine manufacturers to continue to develop and improve techniques for exhaust emission reduction. This paper describes the development of the Cooper-Bessemer Clean Burn gas-diesel (dual-fuel) engine that results in NO[sub x] reductions of up to 92 percent as compared with an uncontrolled gas-diesel engine. Historically, the gas-diesel and diesel engine combustion systems have not responded to similar techniques of NO[sub x] reduction that have been successful on straight spark-ignited natural gas burning engines. NO[sub x] levels of a nominal 1.0 g/BHP-h, equal to the spark-ignited natural gas fueled engine, have been achieved for the gas-diesel and are described. In addition, the higher opacity exhaust plume characteristic of gas-diesel combustion is ...

Energy Technology Data Exchange (ETDEWEB)

We report the direct molecular dynamics simulations for molecular ball bearings composed of fullerene molecules (C{sub 60} and C{sub 20}) and multi-walled carbon nanotubes. The comparison of friction levels indicates that fullerene ball bearings have extremely low friction (with minimal frictional forces of 5.283 x 10{sup -7} and 6.768 x 10{sup -7} nN/atom for C{sub 60} and C{sub 20} bearings) and energy dissipation (lowest dissipation per cycle of 0.013 and 0.016 meV/atom for C{sub 60} and C{sub 20} bearings). A single fullerene inside the ball bearings exhibits various motion statuses of mixed translation and rotation. The influences of the shaft's distortion on the long-ranged potential energy and normal force are discussed. The phonic dissipation mechanism leads to a non-monotonic function between the friction and the load rate for the molecular bearings.

International Nuclear Information System (INIS)

We present an atomistic simulation of the Ostwald ripening of extrinsic defects (clusters, #left brace#1 1 3#right brace#s and dislocation loops) which occurs during annealing of ion implanted silicon. The model describes the capture and emission of Si interstitial atoms to and from extrinsic defects of sizes up to thousands of atoms and includes a loss term due to the flux of interstitials to the recombining surface. Key input parameters of the simulation are the variations of the formation energy and of the capture efficiency with the size of the different defects. This model shows that the kinetics of the well-known dissolution of #left brace#1 1 3#right brace# defects is only driven by the recombination efficiency at the surface and the distance from the defects to the sample surface. We have subsequently used this model to study defect evolution in low and ultra low energy (ULE) B implanted Si during annealing. Defect dissolution occurs ...

International Nuclear Information System (INIS)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P"+/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B"+ and BF_2"+ ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF_3 as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical insights explaining the technological benefit coming from PLAD technique over standard ion ...

Energy Technology Data Exchange (ETDEWEB)

Graphite fluoride (CF{sub x}) is investigated as an additive for WS{sub 2} thin films to reduce its sensitivity to moisture. The films are grown onto hardened 440C stainless steel disks by pulsed laser deposition using the 248 nm line from an excimer laser. Substrate temperature and additive concentration are varied to control film chemistry and crystal structure. The effect of relative humidity (i.e., < 1 to 85% RH) on friction is evaluated. Coatings grown at RT from targets with a low concentration of CF{sub x} exhibit ultra-low friction (ULF) behavior in dry air (i.e., {mu} {<=} 0.01), but friction increases with RH. Mechanisms for the ULF behavior are proposed which suggest that further reductions in friction are possible. Films grown at 300 C or with higher concentrations of CF{sub x} are relatively insensitive to humidity, but have more typical friction coefficients ({mu} {<=} 0.04) in dry air. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This paper reports the results of leaching experiments conducted with and without Thiobacillus ferroxidans at the same conditions in solution. The extent of leaching of ZnS with Bacteria is significantly higher than that without bacteria at high concentrations of ferrous ions. A porous layer of elemental sulfur is present on the surfaces of the chemically leached particles, which no sulfur is present on the surfaces of the bacterially leached particles. The analysis of the data using the shrinking-core model shows that the chemical leaching of ZnS is limited by the diffusion of ferrous ions through the sulfur product layer at high concentrations of ferrous ions. The analysis of the data shows that diffusion through the product layer does not limit the rate of dissolution when bacteria are present. This suggests that the action of T.ferroxidans in oxidizing the sulfur formed on the particle surface is to ...

International Nuclear Information System (INIS)

We investigated the electrical characteristics and the junction depth of ultra-shallow junctions formed by using the plasma-doping method. Compared with ultra-low energy boron-ion implantation at 500 eV, the junctions formed with the plasma-doping process exhibited shallow junction depths and low sheet resistances. The junction depths of the plasma-doped samples were 150 A and 330 A after annealing for 10 s at 900 .deg. C and 950 .deg. C, respectively. For the same junction depth, the sheet resistance of the B_2H_6 plasma-doped sample was an order of magnitude less than that of the 500-eV B-ion implanted sample. Cross-sectional transmission electron microscopy and deep level transient spectroscopy showed that the defects formed by the B_2H_6 plasma-doping process could be removed by annealing at 950 .deg. C for 10 s. The scaling of metal-oxide-semiconductor field-effect-transistor (MOSFET) device channel lengths for high-speed application requires the scaling down ...

International Nuclear Information System (INIS)

Very High Temperature gas cooled nuclear Reactor (VHTR), which was coupled with Sulfur-Iodine (SI) thermo-chemical cycle, has been selected for the Nuclear Hydrogen Development and Demonstration (NHDD) project in Korea Atomic Energy Research Institute. Among the various hydrogen production methods, Sulfur-Iodine (SI) thermo-chemical cycle is a good method as a massive hydrogen production without CO2 emission. In SI cycle, the sulfuric acid decomposition is one issue for the material corrosion on high temperature and pressure condition. For the simulation of the sulfuric acid decomposition, we designed a sulfuric acid loop with a small-scale gas loop which is simulated for the integrity and feasibility tests on a H2SO4 decomposition process. The primary objective of the loop is to validate the corrosion and the mechanical performances of a key component of the NHDD, Process Heat ...

Energy Technology Data Exchange (ETDEWEB)

Power output of a hydrogen-diesel dual-fuel engine is limited by the onset of knock as the percentage of heat input derived from hydrogen increased beyond a certain limit. Earlier work carried out at the Internal Combustion Engines Laboratory, Indian Institute of Technology, Madras, indicates that this knock sets in when the induced hydrogen exceeds about 60% of input energy at a pilot diesel quantity of 30% of full load diesel amount. At higher rates of hydrogen induction, the richer hydrogen-air mixture is more prone to knocking. Hardly any information is available on the possibilities of improving the knock limited power output of a hydrogen-diesel dual-fuel engine. Water can serve as a powerful internal coolant in decreasing the unburned mixture temperature because of its high latent heat. This paper presents the results of our investigation on improving the knock limited power output when water is ...

Energy Technology Data Exchange (ETDEWEB)

Partial combustion of biomass in the gasifier generates producer gas that can be used for heating purposes and as supplementary or sole fuel in internal combustion engines. In this study, the potential of coir-pith and wood chips as the feedstock for gasifier is analyzed. The performance of the gasifier-engine system is analyzed by running the engine for various producer gas-air flow ratios and at different load conditions. The system is experimentally optimized with respect to maximum diesel savings and lower emissions in the dual fuel mode operation while using coir-pith and wood chips separately. The performance and emission characteristics of the dual fuel engine are compared with that of diesel engine at different load conditions. Specific energy consumption in the dual fuel mode of operation is found to be in the higher side at all load conditions. The brake thermal efficiency of the engine while using wood chips in the dual mode ...

International Nuclear Information System (INIS)

Biodiesel is considered as an alternative fuel to Diesel fuel No. 2, which can be generally produced from different kinds of vegetable oils. Since the prices of edible vegetable oils are higher than that of Diesel fuel No. 2, waste vegetable oils and non-edible crude vegetable oils are preferred as potential low priced biodiesel sources. In addition, it is possible to use soapstock, a by-product of edible oil production, for cheap biodiesel production. In this study, a methyl ester biodiesel was produced from a hazelnut soapstock/waste sunflower oil mixture using methanol, sulphuric acid and sodium hydroxide in a two stage process. The effects of the methyl ester addition to Diesel No. 2 on the performance and emissions of a four cycle, four cylinder, turbocharged indirect injection (IDI) Diesel engine were examined at both full and partial loads. Experimental results showed that the hazelnut ...

Energy Technology Data Exchange (ETDEWEB)

A sequential port injection, lean-burn, fully electronically-controlled compressed natural gas (CNG)/diesel dual-fuel engine has been developed based on a turbo-charged and inter-cooled direct injection (D.I.) diesel engine. During the optimisation of engine overall performance, the effects of pilot diesel and premixed CNG/air mixture equivalence ratio on emissions (CO, HC, NO{sub x}, soot), knocking, misfire and fuel economy are studied. The rich and lean boundaries of the premixed CNG/air mixture versus engine load are also provided, considering the acceptable values of NO{sub x} and THC emissions, respectively. It is interesting to find that there is a critical amount of pilot diesel for each load and speed point, which proved to be the optimum amount of pilot fuel. Any decrease in the amount of pilot diesel from this optimum amount results in an increase of NO{sub x} emissions, ...

Science.gov (United States)

or third generation fuels. These are biofuels that can directly substitute for gasoline, jet fuel, and diesel. Today more than 9 billion gallons of biofuels are produced annually...

British Library Electronic Table of Contents (United Kingdom)

The ever increasing fossil fuel usage and cost, environmental concern has forced the world to look for alternatives. Straight vegetable oils in compression ignition engine are a ready solution available, however, with certain limitations and with some advantages as reported by many researchers. A comprehensive and critical review is presented specifically pertaining to straight vegetable oils usage in diesel engine. A detailed record of historical events described. Research carried out specifically under Indian conditions and international research work on the usage of straight vegetable oils in the diesel engine is separately reviewed. Many researchers have reported that straight vegetable oils in small percentage blends with diesel when used lower capacity diesel engines have shown great...

Energy Technology Data Exchange (ETDEWEB)

Biodiesel consists of long-chain fatty acid esters, derived from renewable sources such as vegetable oils, and its utilization is associated to the substitution of the diesel oil in engines. Depending on the raw material, bio diesel can contain more or less unsaturated fatty acids in its composition, which are susceptible to oxidation reactions accelerated by exposition to oxygen and high temperatures, being able to change into polymerized compounds. The objective of this work was to determine the oxidative stability of bio diesel produced by ethanolysis of neutralized, refined, soybean frying oil waste, and partially hydrogenated soybean frying oil waste. The evaluation was conducted by means of the Rancimat equipment, at temperatures of 100 and 105 deg C, with an air flow of 20 L h{sup -1}. The fatty acid composition was determined by GC and the iodine value was calculated. It was observed that even though the ...

Medline Plus

... Pressure Monitoring Better Than Office-Based, Stressful Work Environment Increases Cardiovascular Risks, Diesel Exhaust Linked to COPD ...

Science.gov (United States)

this, however, was a real environmental threat since various drums containing jet fuel, Bunker C, diesel and other petroleum derivatives were on fire. The CAPECO...

Science.gov (United States)

of different transportation fuels (e.g., gasoline, diesel fuel, aviation gasoline, jet fuel, residual fuel oil). Subsequent calculations are performed to estimate the share...

British Library Electronic Table of Contents (United Kingdom)

To diversify the mix of domestic energy resources and to reduce dependence on imported oil, ethanol is widely investigated for applying in combination with Diesel fuel to reduce pollutants, including smoke and NOx. Present work aims at developing a fumigation system for introduction of ethanol in a small capacity Diesel engine and to determine its effects on emission. Fumigation was achieved by using a constant volume carburetor. Different percentages of ethanol fumes with air were then introduced in the Diesel engine, under various load conditions. Ethanol is an oxygenated fuel and lead to smooth and efficient combustion. Atomization of ethanol also results in lower combustion temperature. During the present study, gaseous emission has been found to be decreasing with ethanol fumigation. ...

Energy Technology Data Exchange (ETDEWEB)

An experimental investigation has been carried out to examine for the first time the performance and combustion noise of an indirect injection diesel engine running with new fuel derived from pure jojoba oil, jojoba methyl ester, and its blends with gas oil. A Ricardo E6 compression swirl diesel engine was fully instrumented for the measurement of combustion pressure and its rise rate and other operating parameters. Test parameters included the percentage of jojoba methyl ester in the blend, engine speed, load, injection timing and engine compression ratio. Results showed that the new fuel derived from jojoba is generally comparable and a good replacement to gas oil in diesel engine at most engine operating conditions, in terms of performance parameters and combustion noise produced. (author)

Science.gov (United States)

...identified as oil when the shipment document accurately describes the material as: aviation fuel, diesel fuel, fuel oil, gasoline, jet fuel, kerosene, motor fuel, or...

Science.gov (United States)

In the prevention of atmospheric pollution by sulfur dioxide emissions from acid absorbers in contact process sulfuric acid plants in which the unconverted SO/sub 2/ is accumulated by adsorption in a zeolite adsorbent bed and desorbed back into the acid production system, it is found that ambient moist air, after partial dehydration in an acid scrubber is suitably used both to cool down and hot purge desorb the zeolite beds. In addition the pure water derived from the ambient air is advantageously used in the acid-making system.

Energy Technology Data Exchange (ETDEWEB)

Sulfur K-edge X-ray absorption spectroscopy is a powerful in situ probe of sulfur biochemistry in intact cells and tissues. Under favorable circumstances the technique can provide quantitative information on the chemical identify of the sulfur species that are present in a sample. Prange et al. have recently reported an X-ray absorption spectroscopic study of bacterial sulfur storage globules. Unfortunately there are substantial problems with the experimental technique employed that, they contend, lead to completely erroneous conclusions. In the more recent of their two papers Prange et al. employed a curve-fitting method similar to that used by us (for more than 10 years). In essence, the method employs simply fitting a linear combination of the spectra of standard compounds to that of the unknown, in this case cultures of bacterial cells. This type of analysis can provide quantitative estimates of the ...

Science.gov (United States)

... The phenol and cresylic acid stream is flashed in a thin film evaporator over a concentrated sulfuric acid mixture to remove pyridine type substances ...

International Nuclear Information System (INIS)

Exposure tests of candidate materials were carried out up to 1000 hr in the sulfuric acid environments of thermochemical hydrogen production IS process, focusing on the corrosion of welded portion and of crevice area. In the gas phase sulfuric acid decomposition condition at 850degC, welded samples of Alloy 800 and of Alloy 600 showed the same good corrosion resistance as the base materials. In the boiling condition of 95 wt% sulfuric acid solution, test sample of SiC showed the same good corrosion resistance. Also negligible corrosion was observed in crevice corrosion. (author)

International Nuclear Information System (INIS)

Russian (Dec 1973). USSR Chmovzh, VE Lipshtejn, RA Zalkind, I.Ya. Dik,

Energy Technology Data Exchange (ETDEWEB)

The main problems with the use of neat vegetable oils in diesel engines are higher smoke levels and lower thermal efficiency as compared to diesel. The problem can be tackled by inducting a gaseous fuel in the intake manifold along with air. In this investigation, hydrogen is used as the inducted fuel and rubber seed oil (RSO), rubber seed oil methyl ester (RSOME) and diesel are used as main fuels in a dual fuel engine. A single cylinder diesel engine with rated output of 4.4 kW at 1500 rpm was converted to operate in the dual fuel mode. Dual fuel operation of varying hydrogen quantity with RSO and RSOME results in higher brake thermal efficiency and significant reduction in smoke levels at high outputs. The maximum brake thermal efficiency is 28.12%, 29.26% and 31.62% with RSO, RSOME and diesel at hydrogen energy share of 8.39%, 8.73% and 10.1%, respectively. Smoke is reduced from ...

Energy Technology Data Exchange (ETDEWEB)

As a part of a phenomenological model, a method for simulating the wall/jet interaction in a direct injection diesel engine is proposed. The method is based on the application of the momentum conservation equation in the different directions in which the wall jet is spread, and takes into account both the interaction with the combustion chamber geometry and with swirl. It takes as initial conditions the results of calculating the free jet, which is divided into packages. The predictions provide good agreement with those by other researchers. (author).

Energy Technology Data Exchange (ETDEWEB)

Laser-Doppler anemometry was used to investigate mean flow and turbulence fields in a direct injection diesel engine, motored at speeds of 1500, 2250 and 3000 rev/min. Both cycle-resolved and ensemble-averaged measurements were made in the upper part of the cylinder during the inlet and compression strokes. The cycle-resolved measurements in the inlet stroke are discussed in this paper.

Energy Technology Data Exchange (ETDEWEB)

A new exhaust cleaning system is introduced, aiming to remarkably reduce NOx emission using a type of EGR method (hybrid EGR) of feeding back the exhaust from an exhaust cleaning ternary catalyst provided gasoline engine to the Diesel engine intake on one hand and, on the other hand, aiming to reduce even the emitted particulates using an exhaust supplying gasoline engine driven supercharger for an enhanced Diesel engine supercharging. The hybrid EGR system used here can uniformly reduce the emitted NOx under any load conditions and, as compared with the conventional type, is two to three times more effective, with the EGR rate kept constant. The exhaust concentration is approximately 10%. An sample of the hybrid EGR was simulated, and it was shown, as compared with the original non-supercharged Diesel engine, that the emitted NOx decreased to 1/3 or 1/4, that the exhaust concentration was approximately the same, and that ...

Energy Technology Data Exchange (ETDEWEB)

The exhaust emissions of a Diesel direct injection Perkins engine fueled with waste olive oil methyl ester were studied at several steady-state operating conditions. Emissions were characterized with neat biodiesel from used olive oil and conventional Diesel fuel. Results revealed that the use of biodiesel resulted in lower emissions of CO (up to 58.9%), CO{sub 2} (up to 8.6%, excepting a case which presented a 7.4% increase), NO (up to 37.5%), and SO{sub 2} (up to 57.7%), with increase in emissions of NO{sub 2} (up to 81%, excepting a case which presented a slight reduction). Biodiesel also presented a slight increase in brake-specific fuel consumption (lower than 8.5%) that may be tolerated due to the exhaust emission benefits. Combustion efficiency remained constant using either biodiesel or Diesel fuel. The proposed alternative for Diesel fuel could significantly decrease the enormous amount of ...

Energy Technology Data Exchange (ETDEWEB)

A natural gas and diesel dual-fuel turbocharged compression ignition (CI) engine is developed to reduce emissions of a heavy-duty diesel engine. The compressed natural gas (CNG) pressure regulator is specially designed to feed back the boost pressure to simplify the fuel metering system. The natural gas bypass improves the engine response to acceleration. The modes of diesel injection are set according to the engine operating conditions. The application of honeycomb mixers changes the flowrate shape of natural gas and reduces hydrocarbon (HC) emission under low-load and lowspeed conditions. The cylinder pressures of a CI engine fuelled with diesel and dual fuel are analysed. The introduction of natural gas makes the ignition delay change with engine load. Under the same operating conditions, the emissions of smoke and NO{sub x} from the dual-fuel engine are both reduced. The HC and CO emissions for the ...

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.

Energy Technology Data Exchange (ETDEWEB)

The equilibrium dynamic capacity of polymer materials based on 2,4,6-triamino-1,3,5-triazine has been determined. The possibility of their application as absorbents of sulfur dioxide from exhaust gases has been shown.

Energy Technology Data Exchange (ETDEWEB)

As part of the studies on coal utilization basics, considerations were given on quantification of sulfur forms of coal and the pyrolysis behavior of sulfur compounds. With the temperature raising oxidation method, a thermo-balance was connected directly to a mass analyzer, and the coal temperature was raised at a rate of 5{degree}C per minute and gasified. Peak division was performed on SO2 and COS production to derive sulfur forms of coal. Using the slow-speed pyrolysis method, production rates of H2S, COS, SO2 and mercaptans were measured at a temperature raising rate of 20{degree}C per minute. Sulfur content in char was also measured. With the quick pyrolysis method, a Curie point pyrolyzer was connected directly to a gas chromatograph, by which secondary reaction is suppressed, and initial pyrolytic behavior can be tracked. All kinds of coals produce a considerable amount of SO2 in the slow-speed ...

UK PubMed Central (United Kingdom)

We previously showed that very thin filamentous bacteria affiliated with the division green non-sulfur bacteria were abundant in the outermost layer of thermophilic methanogenic sludge granules fed...Full Text Available

Wastenet

...contributions from the following fields: Catalytic elimination of environmental pollutants, such as nitrogen oxides, carbon monoxide, sulfur compounds, chlorinated and other organic compounds, ...contributions from the following fields: Catalytic elimination of environmental pollutants, such as nitrogen oxides, carbon monoxide, sulfur compounds, chlorinated and other organic compounds, ...

Energy Technology Data Exchange (ETDEWEB)

A process is given for the removal of sulfur oxides from exhaust gases by absorbing with a slurry of red mud containing calcium ion which comprises the steps of: (1) contacting an exhaust gas containing sulfur oxides of not higher than about 100/sup 0/ C with a slurry of red mud containing calcium ion led from the next step (2) to take up sulfur oxides in the gas until ph of the slurry becomes in the range of 4.3 to less than 6 while maintaining the molar fraction of SO/sub 4/-- to total SO/sub 2/ in the slurry within the said pH range at 0.05 to 0.7; and then, (2) contacting the treated gas with a fresh slurry of red mud containing calcium ion to further take up sulfur oxides in the gas while maintaining the concentration of NaHSO/sub 3/ in the slurry at not more than about 8 g/l.

Energy Technology Data Exchange (ETDEWEB)

The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and ...

International Nuclear Information System (INIS)

Experiments have been conducted to study the effect of injection pressure on the combustion process and exhaust emissions of a direct injection diesel engine fueled with Orange Skin Powder Diesel Solution (OSPDS). Earlier investigation by the authors revealed that 30% OSPDS was optimum for better performance and emissions. In the present investigation the injection pressure was varied with 30% OSPDS and the combustion, performance and emissions characteristics were compared with those of diesel fuel. The different injection pressures studied were 215 bar, 235 bar and 255 bar. The results showed that the cylinder pressure with 30% OSPDS at 235 bar fuel injection pressure, was higher than that of diesel fuel as well as at other injection pressures. Similarly, the ignition delay was longer and with shorter combustion duration with 30% OSPDS at 235 bar injection pressure. The brake thermal efficiency was ...

Energy Technology Data Exchange (ETDEWEB)

This study aims to evaluate fatigue strength properties at long-term high temperature of 316FR steels developed for structural materials applied to high temperature components in the 21st Century such as Demonstration FBR, and to obtain design indicators on high temperature strength properties arranged on chemical composition and grain size on a base of 316FR stainless steels. As results obtained by the study, it could be found that as a result of systematic examinations on temperatures and strain rate dependence on symmetric triangular strain waveform of 316FR steels between 500 to 600degC, temperature of fatigue life, and strain rate dependence can be integrally evaluated by a parameter analysis method developed by authors and life prediction at ultra low strain rate of less than 10{sup -6}/s and its experimental verification could be carried out. And, it was also found that as a result of evaluation of creep fatigue life and creep rupture ...

Energy Technology Data Exchange (ETDEWEB)

A comprehensive understanding of dopant activation mechanisms in crystalline Si is required in order to form shallow junctions. In this paper, we will review several experimental assessments on boron clustering and novel methods to form shallow junctions. Boron marker-layer structures have been used to investigate the fundamental aspects of formation and ripening boron-interstitial clusters (BICs) and their influence on the associated transient enhanced diffusion (TED). The samples were damaged by Si implants at different doses in the sub-amorphizing range and annealed at high temperatures. We found that BICs act as a sink for interstitials at supersaturations values S(t)>10{sup 4}. This implies that silicon self-interstitial defects are the primary source of interstitials driving TED, and that BICs act as a secondary 'buffer' for the interstitial supersaturation. These clusters are less sensitive to the ripening process than pure interstitial clusters do, so ...

Energy Technology Data Exchange (ETDEWEB)

In order to realize simultaneous reduction of NO{sub x} and Particulate emissions, effects of combustion chamber geometry were investigated in a high speed direct-injection diesel engine. The reentrant combustion chambers with different throat diameter were compared in terms of engine performance, combustion characteristics and emissions such as NO{sub x}, particulate and THC. The phenomena of combustion process were also observed with endoscopic high speed photography. The results showed that when the throat diameter of a reentrant combustion chamber was reduced to an extent, NO{sub x} and particulate decreased simultaneously due to retarded injection timing and the intensified squish. (author)

Energy Technology Data Exchange (ETDEWEB)

Based on a multi-zone spray-mixing approach, an air-fuel mixing and combustion model for a Direct Injection Diesel engine is presented. The predictions from the model show very good agreement with the experimental data for various engines under a wide range of operating conditions. Major physical processes are modeled and validated independently. The atomisation process is based on Binary Drop Division concept. Fuel droplets are considered randomly distributed in the spray. A spherico-symmetrical transient drop evaporation model is used for evaporation calculation. A 3-dimensional spray-swirl interaction is modeled on centreline velocity vector/continuum approach. Turbulent mixing is characterised considering all possible available energy sources in DI diesel engines.

Energy Technology Data Exchange (ETDEWEB)

A method is described for controlling fuel injection in a diesel engine having a fuel injection nozzle, comprising the steps of: detecting an idling state of the diesel engine and pressure in a combustion chamber; obtaining a pressure increment rate from the pressure detected by the detecting step; selecting a valve opening pressure of the fuel injection nozzle at a relatively low level when the idling state is detected by the detecting step, thereby setting a two peaks characteristics of a fuel injection rate; and controlling the fuel injection nozzle in response to the pressure increment rate so that the pressure increment rate in the combustion chamber is maintained within a predetermined value by changing a fuel injection quantity of a pilot injection from the fuel injection nozzle.

Energy Technology Data Exchange (ETDEWEB)

Methane and carbon dioxide are the two main constituents of biogas. Biogas also contains traces of nitrogen, hydrogen, oxygen and hydrogen sulphide. When diesel engine runs on biogas, the combustion is poor as compared to diesel fuel. One of the reasons of poor combustion is the presence of carbon dioxide in the biogas. Percentage of methane and carbon dioxide in biogas varies with maturities of feed stock, temperature, water content, loading rate of raw material and bacterial actions. This paper examines the effect of variations of carbon dioxide in biogas on the performance of the engine to simulate the performance of the engine running with biogas from different sources (varying proportion of methane and carbon dioxide). (Author)

British Library Electronic Table of Contents (United Kingdom)

A detailed chemical kinetic reaction mechanism is developed for primary reference fuel mixtures of n-hexadecane and 2,2,4,4,6,8,8-heptamethyl nonane for diesel cetane ratings. The mechanisms are constructed using existing rules for reaction pathways and rate expressions developed previously for the primary reference fuels for gasoline octane ratings, n-heptane and iso-octane. These reaction mechanisms are validated by comparisons between computed and experimental results for shock tube ignition and for oxidation under jet-stirred reactor conditions. The combined kinetic reaction mechanism contains the submechanisms for the primary reference fuels for diesel cetane ratings and submechanisms for the primary reference fuels for gasoline octane ratings, all in one integrated large kinetic reac...

Energy Technology Data Exchange (ETDEWEB)

A multi-zone computational model in conjunction with some engine tests are used to examine the combustion process of gas fueled diesel engines commonly known as dual fuel engine to provide information about details of the production of exhaust emissions, especially at light load when very lean mixtures are employed. Detailed chemical reaction kinetic simulation is employed for each of these individual combustion zones so as to establish the associated temporal variations in the concentrations of reacting species right to the exhaust stage. The influence of changes in major operating and design parameters such as the concentration of the gaseous fuel in the cylinder charge, intake temperature and the size of the diesel pilot fuel employed on the production of the exhaust emissions are examined. It is demonstrated in general that any measure that tends to increase the size of the combustion regions within the overly lean cylinder charge will ...

International Nuclear Information System (INIS)

This work describes a three-step pre-treatment route for processing spent commercial Ni Mo/Al_2O_3 catalysts. Extraction of soluble coke with n-hexane and/or leaching of foulant elements with oxalic acid were performed before burning insoluble coke under air. Oxidized catalysts were leached with 9 mol L"-"1 sulfuric acid. Iron was the only foulant element partially leached by oxalic acid. The amount of insoluble matter in sulfuric acid was drastically reduced when iron and/or soluble coke were previously removed. Losses of active phase metals (Ni, Mo) during leaching with oxalic acid were compensated by the increase of their recovery in the sulfuric acid leachate. (author)

Energy Technology Data Exchange (ETDEWEB)

The first U.S. demonstration of the NGK sodium/sulfur battery technology was launched in August 2002 when a prototype system was installed at a commercial office building in Gahanna, Ohio. American Electric Power served as the host utility that provided the office space and technical support throughout the project. The system was used to both reduce demand peaks (peak-shaving operation) and to mitigate grid power disturbances (power quality operation) at the demonstration site. This report documents the results of the demonstration, provides an economic analysis of a commercial sodium/sulfur battery energy storage system at a typical site, and describes a side-by-side demonstration of the capabilities of the sodium/sulfur battery system, a lead-acid battery system, and a flywheel-based energy storage system in a power quality application.

Energy Technology Data Exchange (ETDEWEB)

Four commercial stainless steels (mat. Nos. 1.4539, 1.4586, 1.4571 and 1.4462) were tested in 96% and 90% sulfuric acid of 80/sup 0/C as to their corrosion fatigue strength by subjecting notched round bars to the rotary bending test. At the same time, the efficiency of anodic protection was examined. With all four steels, the alternating bending strength obtained in the air is essentially reduced. The semiaustenitic steel Nr. 1.4462 shows a lower corrosion fatigue strength than the three austenitic steels. Although making the corrosion fatigue strength of steels better calculable, anodic protection proves insufficient to completely prevent notched round bars from corrosion fatigue in concentrated sulfuric acid.

British Library Electronic Table of Contents (United Kingdom)

We investigate how corruption influences the income level at the turning point of the relationship between sulfur emissions and income, using a wide cross-national panel of countries, at different levels of development and with different degrees of corruption. Our results support the Environmental Kuznets Curve hypothesis for sulfur. We find evidence that the higher the country's degree of corruption, the higher the per capita income at the turning point, suggesting different income-pollution paths across countries due to corruption. We build upon a new specification for the EKC developed by Bradford et al. (2005) that avoids using nonlinear transformations of potentially nonstationary regressors in panel estimation. Also, we account for the indirect impact of corruption on emissions throu...

British Library Electronic Table of Contents (United Kingdom)

Experiments based on a 23 central composite full factorial design were carried out in 200-ml stainless-steel containers to study the pretreatment, with dilute sulfuric acid, of a sugarcane bagasse sample obtained from a local sugar?alcohol mill. The independent variables selected for study were temperature, varied from 112.5?C to 157.5?C, residence time, varied from 5.0 to 35.0 min, and sulfuric acid concentration, varied from 0.0% to 3.0% (w/v). Bagasse loading of 15% (w/w) was used in all experiments. Statistical analysis of the experimental results showed that all three independent variables significantly influenced the response variables, namely the bagasse solubilization, efficiency of xylose recovery in the hemicellulosic hydrolysate, efficiency of cellulose enzymatic saccharificatio...

Energy Technology Data Exchange (ETDEWEB)

With an objective to use reproducible vegetable oil as a substitute fuel, studies were performed to use emulsified rapeseed oil at an optimal mixing ratio with water in a direct injection diesel engine. The experiment used a water cooled, lateral installation, single-cylinder, direct injection, four-cycle diesel engine, and the tested fuel used an emulsified rapeseed oil fuel with rapeseed oil added with water at a rate of 20% by weight. As a result of the experiment using the emulsified rapeseed oil, it was found that reducing the injection opening diameter smaller than the standard opening diameter improves the engine performance and simultaneously reduces concentrations of HC, CO and exhaust smoke. The optimal opening diameter was about 0.22 mm. Increasing the valve opening pressure reduced the NOx concentration, but increased the HC concentration. Using the emulsified rapeseed oil fuel accumulated more carbon below the head, but much ...

Energy Technology Data Exchange (ETDEWEB)

Discussions were given on the characteristics of a diesel engine to emit unburned hydrocarbon (HC) created in a long idling operation. The engine tested in the experiment is a direct injection diesel engine with six water-cooled were investigated varying the jet hole diameter and length of the jet nozzle. In the initial operation period, the HC showed high values. This is thought because part of the injected fuel has deposited on the wall because of low combustion chamber wall temperature, and the fuel deposit that did not evaporate during combustion evaporated during expansion process and emitted unburned. The head was dismantled to investigate the carbon flowers deposited on the nozzle and the relationship between the carbon and the HC deposited on the head face and the combustion chamber wall. It was clarified that the HC increase was phenomenal compared with that of the carbon. This is because the injected fuel was adsorbed into the carbon, ...

Energy Technology Data Exchange (ETDEWEB)

Experimental investigations are being conducted on a single-cylinder direct-injection diesel engine to examine the transient heat transfer characteristics. Transient temperature data from stationary locations in the piston and cylinder head were used as the basis for determining the transient heat flux rates. Transient surface temperature was measured using the thin film thermocouples. At first, the transient heat flux rates calculated from the analysis method used in this paper were compared with the results from FEM. The results showed good agreement. Using this analysis method, the transient heat flux rates were calculated. The tests were performed at 1200 rpm with constant air flow. The parameters that were varied included the fuel rate and injection timing. Based on these results, the present paper discusses the mechanism of heat rejection in a direct-injection diesel engine. 8 refs., 16 figs.

Energy Technology Data Exchange (ETDEWEB)

This work presents an analysis of the operation of a multi-cylinder, tubro charged, indirect injection diesel engine from a second-law analysis point of view. For this purpose, a single-zone thermodynamic model following the filling and emptying modelling technique is developed. A second-law analysis is performed in all parts of the diesel engine plant, which provides all the existing availability terms and accounts for the evaluation of every component`s irreversibilities. A complete second-law terms tabulation is given for the maximum speed-full load operation case, which is compared with its first-law counterpart. A detailed parametric study is performed in all parts of the diesel engine plant comprising the effects of speed and load on the availability terms in a range that covers the whole operation of the engine under turbocharged action. Various second-law (availability) terms such as indicated and brake work, heat ...

Energy Technology Data Exchange (ETDEWEB)

Quantitative estimates of lung cancer risk from exposure to diesel engine emissions were developed using data from three chronic bioassays with Fischer 344 rats. Human target organ dose was estimated with the aid of a comprehensive dosimetry model. This model accounted for rat-human differences in deposition efficiency, normal particle clearance rates, transport of particles to lung-associated lymph nodes, respiration rates, and lung surface area, as well as high-dose inhibition of particle clearance. Recent evidence indicates that the inert carbon core of the diesel particulate matter is likely to be the primary source of carcinogenicity. The epithelial tissue lining the alveoli and lower airways is the primary target site for induction of lung tumors. Dose was therefore based upon the concentration of carbon particulate matter per unit lung surface area. Unit risk estimates were developed using either a time-to-tumor or a linearized ...

UK PubMed Central (United Kingdom)

Locomotive drivers in the steam engine era were exposed to asbestos during their vocational training for two years while training in workshops. Later in their career they had exposure to coal and diesel...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

For a direct injection diesel engine to exhibit its inherent low-emission characteristics, it is essential to improve control accuracy, in particular under transient operating conditions during which emissions are more noted. A model-based control system is established for exhaust gas recirculation (EGR) and air/fuel ratio, using a diesel-engine/vehicle model established on the CAD control system. Described herein are the results of simulation for optimizing control of transient conditions, and the emission-controlling effects confirmed by the field tests. The tests for verification of the established model have confirmed that there are good agreements between the simulated and observed results in terms of air/fuel ratio changing with EGR ratio, exhaust and intake gas and pressure levels, and vehicle speed. The model will be applicable to assessment of emission characteristics under varying conditions. Simulation of the transient conditions of ...

International Nuclear Information System (INIS)

A hydrogen combustion and exhaust emissions in a supercharged gas engine ignited with micro pilot diesel fuel was discussed in this presentation. A schematic diagram of the experimental study was first presented. The single cylinder, water-cooled, supercharged test engine was illustrated. Results were presented for the following: fuel energy and energy share (hydrogen and diesel fuel); pressure history and rate of heat release; engine performance and exhaust emissions; effect of nitrogen dilution on heat value per cycle; effect of N_2 dilution on pressure history and rate of heat release; and engine performance and exhaust emissions. This presentation demonstrated that smooth and knock-free engine operation results from the use of hydrogen in a supercharged dual-fuel engine for leaner fuel-air equivalence ratios maintaining high thermal efficiency. It was possible to attain mor3 than 90 per cent hydrogen-energy substitution to the ...

Science.gov (United States)

MWo = average molecular weight of fuel est. 105 g/mole for gasoline est. 165 g/mole for Jet fuel est. 230 g/mole for diesel fuel MWX = molecular weight of selected chemical...

Energy Technology Data Exchange (ETDEWEB)

Changes in the physical and chemical processes during the ignition delay period of a gas-fueled diesel engine (dual-fuel engine) due to the increased admission of the gaseous fuels and diluents are examined. The extension to the chemical aspects of the ignition delay with the added gaseous fuels and the diluents into the cylinder charge is evaluated using detailed reaction kinetics for the oxidation of dual-fuel mixtures at an adiabatic constant volume process while employing n-heptane as a representative of the main components of the diesel fuel. In the examination of the physical aspects of the delay period, the relative contributions of changes in charge temperature, pressure, physical properties, pre-ignition energy release, heat transfer, and the residual gas effects due to the admission of the gaseous fuels are discussed and evaluated. It is shown that the introduction of gaseous fuels and diluents into the diesel ...

Energy Technology Data Exchange (ETDEWEB)

By setting up a fully indicated, modern passenger car diesel engine, Mahle has created the basis for systematically testing current and future engine technologies. The experimental set-up has both an integrated high- and low-pressure EGR circuit and an open engine control unit, thus enabling efficient development of new systems under real-world conditions. The advantages of this comprehensive approach are illustrated below, using the example of different EGR technologies tested. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Coal-water-slurry (CWS) engine tests designed to evaluate a new accumulator-based injection system are described in this paper The new injection system was found to improve CWS burnout considerably at both full and part engine loads. The peak cylinder firing pressure when operating with CWS was no higher than when operating with diesel oil. These data demonstrates the improved engine performance that can be achieved with the accumulator-based injection system.

Energy Technology Data Exchange (ETDEWEB)

Since mid-1995, Audi is the second European producer to offer a direct-injection diesel engine for passenger cars. The 2.0 l engine is installed in the middle-class sedan Rover 620 SDi. (orig.) [Deutsch] Als nach Audi zweiter europaeischer Hersteller bietet Rover seit Mitte dieses Jahres einen Pkw-Dieselmotor mit direkter Einspritzung an. Eingesetzt wird das Aggregat mit 2,0 l Hubraum in der Mittelklasselimousine Rover 620 SDi. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This work reviews the differences in fuel economy between two direct injection diesel engine versions through the use of a First Law energy balance and a Second Law availability balance. Both experimental data and simulated results are used in the analysis. The use of an engine simulation allowed the important processes in each engine to be analyzed and a Second Law effectiveness calculated. The availability balances and effectiveness values are used to determine the effect of major engine components on the fuel economy. A comparison is also made with an ideal engine with selected perfect or reversible processes.

Energy Technology Data Exchange (ETDEWEB)

There is renewed interest in the development of natural gas vehicles in response to the challenge to reduce urban air pollution and consumption of petroleum. The natural gas/diesel dual fuel engine is one way to apply natural gas to the conventional diesel engine. Dual fuel engines operating on natural gas and diesel emit less nitrogen oxides, and less carbon soot to the air compared to conventional diesel engines. The problem is that at light loads, fuel efficiency is reduced and emissions of hydrocarbons and carbon monoxide are increased. This thesis focused on control methods for emissions of hydrocarbons and carbon monoxide in the dual fuel engine at light loads. This was done by developing a reverse flow catalytic converter to complement dual fuel engine exhaust characteristics. Experimental measurements and numerical simulations of reverse flow catalytic converters were conducted. Reverse flow ...

International Nuclear Information System (INIS)

Sulfonated poly(ether ether ketone) (SPEEK) membranes with various degrees of sulfonation (DS) have been prepared as a potential membrane material for proton exchange membrane by sulfonation process using mixtures of (15-30% concentration) fuming sulfuric acid and (95-98%) concentrated sulfuric acid as the sulfonating agent. The sulfonation process was conducted at room temperature by varying the acid ratio and reaction time. The produced membranes were then characterized by evaluating the ion exchange capacity (IEC), water uptake, thermal stability, proton conductivity and methanol permeability as a function of degree of sulfonation. The proton conductivity of the sulfonated PEEK membranes with various DS was within the magnitude of 10"-"3 and 10"-"2 S cm"-"1 at room temperature and the methanol permeability was in the range of 3.45 x 10"-"7 to 2.73 x 10"-"6 cm"2 s"-"1. The overall membrane performance of the SPEEK membrane with 80% DS was six ...

British Library Electronic Table of Contents (United Kingdom)

In this work, coals of various ranks were dissolved in an acid melange. With the use of IR spectroscopy, it was found that the mechanism of coal dissolution consists in the grafting of polar groups to the peripheral benzene rings of graphite-like systems.

UK PubMed Central (United Kingdom)

The asymmetric organocatalytic α-sulfenylation of substituted piperazine-2,5-diones is reported, with cinchona alkaloids as chiral Lewis bases and electrophilic sulfur transfer reagents....Full Text Available

UK PubMed Central (United Kingdom)

In this study we determined the composition and biogeochemistry of novel, brightly colored, white and orange microbial mats at the surface of a brine seep at the outer rim of the Chefren mud volcano....Full Text Available

International Nuclear Information System (INIS)

The devised radionuclide analyzer for the determination of total sulfur in coal includes two radionuclide sources with different energies, which are accommodated in collimators fitted with adjustable diaphramgs. The sample compartment is located between the two sources. Moreover, an X-ray fluorescence standard can be slid into the sample compartment. A proportional detector for X-ray fluorescence and scattered gamma radiation is located off the sample compartment. The input of the proportional detector is interfaced to the output of a high-voltage supply, the output, to the information input of a control-and-evaluation unit. One of the control outputs of the control-and-evaluation unit is connected to the input of the sliding mechanism for the X-ray fluorescence standard. This arrangement enables automatic energy calibration of the analyzer. The analyzer can measure not only total sulfur in coal by radionuclide X-ray fluorescence analysis but ...

Energy Technology Data Exchange (ETDEWEB)

Reinforced (heterogel) silicate materials containing an amorphous and a crystalline phase are being used more and more industry. Such systems are energetically unsaturated and therefore promising for use in catalysts. The authors used two reinforced materials as supports: an aluminosilicate containing a zeolite (the cracking catalyst, tseokar) and asbestos-containing aluminosilicate. The active component was introduced by impregnation, and this was followed by heat treatment during which the chemical composition and porous structure were formed. The impregnating mixture consisted of solutions of potassium sulfate and vanadate of the required concentrations. The testing shows that reinforced heterogel systems are promising as support materials for sulfuric acid catalysts.

Energy Technology Data Exchange (ETDEWEB)

The objective of this project is to develop a pellet formulation which is capable of achieving low sulfur partial pressures and a high capacity for sulfur, loaded from a hot fuel gas and which is readily regenerable. Furthermore the pellet must be strong for potential use in a fluidized bed and regenerable over many cycles of loading and regeneration. Regeneration should be in air or oxygen-depleted air to produce a high-concentration sulfur dioxide. Fixed-bed tests were conducted with several formulations of manganese sesquioxide and titania, and alumina They were subject to a simplified fuel gas of the oxygen-blown Shell type spiked with a 30,000ppmv concentration of H{sub 2}S. Pellet crush strengths for 4 and 2mm diameter pellets was typically 12 lbs per pellet and 4 lbs per pellet, respectively. For the most favorable of the formulations tested and under the criteria of break-through at less than 100ppmv H2S and loading ...

Energy Technology Data Exchange (ETDEWEB)

An estimate of the tritium dose to the public in the vicinity of the heavy water research reactor facility at AECL-Chalk River Laboratories, Ontario, Canada, has largely been accomplished from analyses on regularly-collected samples of air, precipitation, drinking water and foodstuffs (pasture, fruit, vegetables and milk) and environmental dose models. To increase the confidence with which public doses are calculated, tritium doses were estimated directly from the ratio of tritiated species in urine samples from members of the general public. Single cumulative 24 h urine samples from a few adults living in the vicinity of the heavy-water research reactor facility at Chalk River Laboratories, Canada were collected and analysed for tritiated water and organically bound tritium. The participants were from Ottawa (200 km east), Deep River (10 km west) and Chalk River Laboratories. Tritiated water concentrations in urine ranged from 6.5 Bq.l{sup -1} for the Ottawa resident to 15.9 Bq.l{sup ...

Energy Technology Data Exchange (ETDEWEB)

This article presents the comparative bench testing results of a naturally aspirated, four stroke, four cylinder, water cooled, direct injection Diesel engine when running on diesel fuel and shale oil that is produced in Estonia from local oil shale. The purpose of this research is to investigate the possibility of practical usage of the shale oil as the alternative fuel for a high speed Diesel engine as well as to evaluate the combustion efficiency, brake specific fuel consumption, emission composition changes and the smoke opacity of the exhausts. Test results show that when fuelling a fully loaded engine with shale oil, the brake specific fuel consumption at the maximum torque and rated power is correspondingly higher by 12.3% and 20.4%. However, the brake thermal efficiencies do not differ widely and their maximum values remain equal to 0.36-0.37 for Diesel fuel and 0.32-0.33 for shale oil. The ...

Energy Technology Data Exchange (ETDEWEB)

An experimental study was performed to provide the combustion and emission characteristics resulting from fuel-reactivity controlled compression ignition (RCCI) combustion mode utilizing dual-fuel approach in a light-duty, multi-cylinder diesel engine. In-cylinder fuel blending using port fuel injection of gasoline before intake valve opening (IVO) and early-cycle, direct injection of diesel fuel was used as the charge preparation and fuel blending strategy. In order to achieve the desired auto-ignition quality through the stratification of the fuel-air equivalence ratio ( ), blends of commercially available gasoline and diesel fuel were used. Engine experiments were performed at an engine speed of 2300rpm and an engine load of 4.3bar brake mean effective pressure (BMEP). It was found that significant reduction in both nitrogen oxide (NOx) and particulate matter (PM) was realized successfully through the RCCI combustion ...

Energy Technology Data Exchange (ETDEWEB)

An ambitious development programme culminated in late 1989 with the most modern diesel train available today entering commercial service. At the root of its development lay an overall concept which aimed at meeting the present-day and future requirements of railway administrations. Higher passenger revenues, lower operating costs and reduced maintenance are the result. An IC trainset is 58.8 m long and consists of three cars: Two identical power cars and one intermediate car. Each three-car trainset has 144 seats, 16 of which are reserved for first class. Up to five three-car trainsets can be coupled rogether to form a 15-car trainset. Four air-cooled 8-cylinder diesel engines with a combined rating of 294 kW power each three-car trainset, i.e. there are two engines installed in each of the power cars. The train has a maximum speed of 180 km/h. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Experimental investigations are being conducted on a single-cylinder direct-injection diesel engine to examine the effects of combustion chamber specifications and swirl ratios on the heat release and transient heat transfer characteristics. Heat rejection was examined on the basis of heat release calculations using cylinder pressure time histories. Transient surface temperature data obtained from stationary locations in the piston and cylinder head were used as the basis for determining the transient heat flux rates. The results showed good agreement with the heat rejection calculated from cylinder pressure data and that transient heat flux in a piston cavity was reduced with the larger cavity diameter and a higher swirl ratio. On the other hand, a transient heat flux in a piston head was not changed by the cavity diameter and swirl ratio. 5 refs., 19 figs.

Energy Technology Data Exchange (ETDEWEB)

The effects on engine emissions resulting from the intake manifold fumigation of oxygenated fuel and the addition of oxygenates to the fuel have been investigated using a direct-injection diesel engine. The results show that carefully selected oxygenated fuels effectively work to increase the ignition delay because of their low ignition quality and to decrease the combustion temperature due to the low compression gas temperature produced from their large heat of vaporization, thereby reducing levels of Bosch smoke and nitrogen oxides simultaneously. However, supplementary injection of the oxygenates into the intake air causes a drastic increase in the levels of exhaust total hydrocarbons and CO; thus, it can be said that the addition of oxygenates to the fuel is more practical and effective than fumigation if phase separation of the blended fuel may not be occurred. In the case of addition of the oxygenates to the fuel, it is clarified that smoke is directly ...

Energy Technology Data Exchange (ETDEWEB)

Various pollution abatement measures available to combat oil spills were reviewed with emphasis on biodegradation. Microorganisms naturally found in soils and groundwater can efficiently degrade a variety of organic contaminants. For certain sites, local temperature allows the microorganisms to reduce the contaminant concentrations without human intervention. In April 1994, a diesel fuel leak was found at a telecommunication station located in a park. The leak had already contaminated the surrounding soil. The first step of the clean-up procedure was to excavate the contaminated soil, followed by an evaluation to determine the extent of the remaining contamination. It was concluded that by using natural attenuation the deforestation of the remaining affected area could be prevented. In this instance, the natural attenuation process is expected to take five years for completion. 4 refs., 1 tab., 1 fig.

Energy Technology Data Exchange (ETDEWEB)

Increasingly stringent pollution regulations have spurred a broad interest in the reduction of engine emissions. Two strategies can be considered: after-treatment or engine emissions reduction. For Diesel engines, after-treatment has a high cost induced by the required technology and implementation issues. In this context, the Highly Premixed Combustion combustion mode (HP C) has emerged as a topic of major interest in recent years. It represents one of the most promising ways for new generation of CI engines using high Exhaust Gas Recirculation (EGR) rates. Experimentation on the test bench brought the proof of significant emission reduction. However, actual vehicle implementation implies frequent transient which fall far beyond steady state experimentation on the test bench. Several key challenges have to be addressed. With this combustion technology; accurate torque balancing at all engine modes is a requirement. Even slight unbalance between the cylinders can ...

Energy Technology Data Exchange (ETDEWEB)

This study is part of a greater project from IPT (Sao Paulo's Institute of Technology), which foresaw an energetic use for elephant-grass (Pennisetum purpureum). Biomass gasification is an sustainable option for energy supply, which presents low pollutants emission rate and allows - through the global cycle of growing and consumption of feedstock (vegetables), a balance between consumption and production of carbonic gas, preventing an increase of the carbonic gas levels in the atmosphere. A gasifier was built with internal diameter of 400 mm and total height of 4600 mm . The equipment was tested for gasification of elephant-grass (Pennisetum purpureum) at a 100 kg/h rate. The equipment was tested and some constructive faults were detected. In the countryside, this biomass is commonly used for cattle feeding It was evaluated an adequate diesel-electric-generator. to work at hybrid regime, using 70% biomass gas and 30% diesel. With the ...

Energy Technology Data Exchange (ETDEWEB)

An Allis-Chalmers, Model 2900, turbocharged diesel engine was converted to a dual-fuel engine in which ethyl alcohol was fumigated between the turbocharger and the intake manifold, and the diesel fuel was injected normally at a reduced rate. Tests were performed to determine if crankcase oil dilution that had occurred was caused by the following independent parameters: proof of the ethyl alcohol, crankcase oil temperature, engine load at maximum torque speed, and percentage of total energy in the form of ethyl alcohol. Engine tests were steady state for six hours, after which the crankcase oil was sampled for American Society for Testing and Materials (ASTM) laboratory tests for determination of flash points and fire points, water by centrifuge, water by distillation, and viscosity at room temperature. Results indicate a decrease in thermal efficiency and an increase in exhaust carbon monoxide as the percentage of total energy as alcohol is ...

Energy Technology Data Exchange (ETDEWEB)

Based on the tried and proven 32/40 diesel engine MAN B and W Diesel AG has developed a dual fuel gas engine covering a rate from 2.4 to 7.2 MW for stationary application in cogeneration and power stations. This paper reports the salient points of the 32/40 DG development project from the concept phase through to prototype testing. To reach the targets a dual fuel prechamber combustion system was developed using an externally arranged, cylinder individual gas admission for the main combustion chamber and a pilot fuel injection to the prechamber. Due to the high thermal and mechanical load sustaining capability of the strong-built heavy fuel diesel engine, bmep (19.9 bar) and efficiency (42.6%) in excess of the targets were achieved with a more than satisfactory life of components. Moreover, the NO{sub x} limit of 500 mg/m{sup 3} as specified in the German TA Luft was successfully met.

Energy Technology Data Exchange (ETDEWEB)

Corrosion test, as a material selection test method of nozzle to be used in the marine diesel engine, was adopted and discussed. Due to the heightening in output power and lengthening in stroke of the marine diesel engine, the fuel injection nozzle became so severe in working condition that the nozzle tip became in lift 1/6 to 1/18 time as long as that of short stroke type in past. Then upon investigating cause of damage, the damage was confirmed to be mainly caused by the high temperature sulfidization corrosion. Then by preparing 20 kinds of candidate test piece and making sulfidization corrosion test in accordance with the high temperature corrosion test procedure, corrosiveness was evaluated through change in weight between before and after testing. As a result of testing, three kinds of test piece, inclusive of high Ni-Cr-Al alloy's, showed a high anti-corrosiveness. Those kinds of test piece were then field tested on board of ...

Energy Technology Data Exchange (ETDEWEB)

With the launch of the new L 16/24 engine, Holeby Diesel is introducing a completely new diesel engine as part of a new family of 1000 and 1200 r/min, heavy-fuel auxiliary diesel sets. These cover a range between 425 and 770 kW at 50 Hz, or between 475 and 855 kW at 60 Hz electrical output. Said to be the first of a new generation, the L 16/24 engine family consists of 5 to 9 in-line cylinder versions with an output of 100 kW per cylinder at 1200 r/min. (Power is 10% less when running at 1000 r/min.) The specific fuel consumption is announced to be 187 g/kWh {+-}3% at 85% load, running on heavy fuel up to 700 cSt/150{degree}C from start to stop of the engine. Compactness was a further design criteria: the result is an auxiliary unit with only one meter in width, two meters in height, and 4.0 to 5.4 m in length, depending on the engine model used.

Energy Technology Data Exchange (ETDEWEB)

The high-speed direct-injection diesel engine for passenger cars has been a resounding success in the marketplace in the last few years. This was due to an intensive development process as a result of which the direct-injection diesel engine for passenger cars is currently setting new standards with regard to performance and fuel consumption in spite of the constant tightening of emission regulations. Of particular importance in this context is exhaust gas recirculation (EGR). This technology permits a considerable reduction in nitrogen oxide emissions, which are especially critical in the case of the direct-injection diesel engine. In addition, continuing development of supercharging technology, in particular the turbocharger with variable turbine geometry, have allowed further improvement of the full-load behaviour and the engine response and a considerable reduction in the fuel consumption of direct-injection ...

Energy Technology Data Exchange (ETDEWEB)

The influence of bowl offset on motored mean flow and turbulence in a direct injection diesel engine has been examined with the aid of a multi-dimensional flow code. Results are presented for three piston geometries. The bowl geometry of each piston was the same, while the offset between the bowl and the cylinder axis was varied from 0.0 to 9.6% of the bore. The swirl ratio at intake valve closing was also varied from 2.60 to 4.27. It was found that the angular momentum of the air at TDC was decreased by less than 8% when the bowl was offset. Nevertheless, the mean (squish and swirl) flows were strongly affected by the offset. In addition, the distribution of turbulent kinetic energy (predicted by the /delta/-e model) was modified. Moderate increases (10% or less) in mass averaged turbulence intensity at TDC with offset were observed.

Energy Technology Data Exchange (ETDEWEB)

Testbed trials of the Sulzer RTA84 dual-fuel engine were successfully completed at the IHI Aioi engine works (Japan) in April 1986. This newly-developed engine, output range 15 to 40 MW, can be operated with both diesel or heavy oil and methane gas at comparable thermal efficiency and unchanged output. The RTA dual-fuel engine was developed in close collaboration between Sulzer Brothers Limited, Switzerland and its Japanese licensees Ishikawajima-Harima Heavy Industries Co. Ltd. (IHI), Nippon Kokan KK (NKK) and Sumitomo Heavy Industries Ltd. (SHI). Intended for the propulsion of LNG carriers, where the boil-off gas from the ship's cargo is exploited or for the generation of electricity in stationary plants, the RTA dual-fuel engine is an economic and reliable alternative to the steam or gas turbines.

Energy Technology Data Exchange (ETDEWEB)

An experimental and modelling study was performed for a reverse flow catalytic converter attached to a natural gas/diesel dual fuel engine. The catalytic converter had a segmented ceramic monolith honeycomb substrate and a catalytic washcoat containing a predominantly palladium catalyst. A one-dimensional single channel model was used to simulate the operation of the converter. The kinetics of the CO and methane oxidation followed first-order behaviour. The activation energy for the oxidation of methane showed a change with temperature, dropping from a value of 129 to 35 kJ/mol at a temperature of 874 K. The reverse flow converter was able to achieve high reactor temperature under conditions of low inlet gas temperature, provided that the initial reactor temperature was sufficiently high. (author)

Energy Technology Data Exchange (ETDEWEB)

Test bed trials of the Sulzer RTA84 dual-fuel engine were successfully completed at the IHI Aioi engine works (Japan) in April 1986. This newly-developed engine-type, output range 15 to 40 MW, can be operated with both diesel or heavy oil and methane gas at comparable thermal efficiency and unchanged output. The RTA dual-fuel engine was developed in close collaboration between Sulzer Brothers Limited and its Japanese licenses. Intended for the propulsion of LNG carriers, where the boil-off gas from the ship's cargo is exploited for the generation of electricity in stationary plants, the RTA dual-fuel engines is an economic and reliable alternative to the steam or gas turbine. The performance of the engine is discussed.

Energy Technology Data Exchange (ETDEWEB)

In the GE 7FDL single cylinder research diesel engine, in-cylinder high-speed photographic studies were conducted on coal-water slurry (CWS) fuel combustion. Distinct flames of pilot and CWS combustion were noticed. It was proven that the coal fuel burns after piston impingement and secondary atomization. Agglomerated particles will develop when combustion conditions are not favorable. Cylinder pressure data were simultaneously recorded for each film frame. Heat release data can thus be produced for each photo study. Most of the findings of earlier combustion studies on engine performance were confirmed.

Energy Technology Data Exchange (ETDEWEB)

A compression ignition engine was operated on dual fuel principle inducting two commercial fuels and four pure hydrocarbon fuels in turn through intake manifold along with air and injecting diesel fuel to initiate the combustion in the conventional manner. The engine was operated at different loads and at each load the quantity of inducted fuel was increased gradually till knocking set in. The engine performance and exhaust pollutant emissions were recorded at different operating conditions. It was observed that the extent of induction and the effect on the performance depend on the properties of the inducted fuel such as volatility, self ignition temperature and oxidation characteristics. The energy release during the cycle was also observed to shift depending on the properties of inducted fuel. With the dual fuel operation, the thermal efficiency at part loads was observed to be less compared to neat diesel operation. The thermal efficiency ...

Energy Technology Data Exchange (ETDEWEB)

The majority of Brazilian big cities served by conventional railroad systems with routes starting in the center of the URBIS, destinate them the long distances transport of passengers and cargo. Actually, these systems are being transformed to become commuter trains which join a great capacity of transportation to a much lower costs of implantation than subway ones. The most important characteristic of this train, when talking about energy consumption, is the possibility of using different kinds of explosion engines from three cycles: Diesel, mixed (Diesel + Natural Gas), and Otto moved by natural gas, besides the traditional electric traction. The use of natural gas in Otto cycle engines shows itself competitive from the point of view of investments, operational costs and environmental preservation. (author). 10 refs., 1 fig

Energy Technology Data Exchange (ETDEWEB)

Measurements of smoke and NO emissions from a direct-injection diesel engine have shown that they are indeed influenced by inlet port design, even though the swirl numbers for the ports may be identical. The swirl numbers of the three ports used (tangential port, helical port and helical port with masked valve) were measured on a steady-state test rig using a paddle-wheel anemometer and impulse swirl meter. Flow measurements were carried out under motoring conditions with a constant-temperature, hot-wire anemometer. Is was possible to find a correlation between flow data and exhaust data as far as the in-cylinder air motion over a certain time interval is concerned.

Energy Technology Data Exchange (ETDEWEB)

This paper presents a reformer prototype for the production of the necessary H{sub 2} to supply a 5 kW PEMFC and its first results. The fuel processor consists of an OSR and a WGS and a PROX reactors. The design of the system was carried out with a one-dimensional model. The mixture chamber was specially studied with a CFD code (Fluent), taking into account the effect of fuel evaporation and the cool flame process. The aim of the designed facility is to be able of characterising each component and controlling each working parameter. Eventually, using diesel as fuel, results from the mixture chamber, OSR, WGS and PROX reactors are presented. It also includes conclusions and future works. (authors)

International Nuclear Information System (INIS)

Utilities are evaluating several electric generation and storage (G ampersand S) technologies for distributed utility (DU) applications. Attributes of leading DU technologies and implications for photovoltaics (PV) are described. Included is a survey of present and projected cost and performance for: (1) small, advanced combustion turbines (CTs); (2) advanced, natural gas-fired, diesel engines (diesel engines); and (3) advanced lead-acid battery systems (batteries). Technology drivers and relative qualitative benefits are described. A levelized energy cost-based cost target for PV for DU applications is provided. The analysis addresses only relative cost, for PV and for three selected alternative DU technologies. Comparable size, utility, and benefits are assumed, although relative value is application-specific and often technology- and site-specific.

British Library Electronic Table of Contents (United Kingdom)

In this study, the effect of intake charge dilution with carbon dioxide on the combustion and emission characteristics of a 4-cylinder direct-injection diesel engine fueled with biodiesel, ethanol-biodiesel and methanol-biodiesel were investigated. With increase of intake CO"2 concentration, CO, HC, particulate mass concentration, particle number concentration and geometric diameter (GMD) of all fuels increased while NO"x decreased obviously. After addition of methanol and ethanol in biodiesel, the NO"x, particulate mass concentration and particle number concentration decreased at each intake CO"2 concentration, compared with biodiesel. Moreover, as the intake CO"2 concentration increased from 2% to 5.6%, particulate mass concentration of the alcohol-biodiesel blends remained almost unchan...

British Library Electronic Table of Contents (United Kingdom)

Exposure to urban air pollution is an independent risk factor for increased cardiovascular diseases. Heat shock protein 70 (HSP70) has been implicated in the pathogenesis of vascular dysfunction and cardiovascular diseases. This study has been designed to determine whether inhalation of urban air induces HSP70 expression in the lung and blood as well as the association of HSP70 and air pollution-induced vascular dysfunction. Apolipoprotein E (Apo-E) deficient mice were exposed to diesel exhaust (DE) either acutely (3 days, 200 or 400 g/m3 for 6 h/day) or chronically (7 weeks, 200 or 400 g/m3 for 6 h/day). HSP70 was measured in the lung using immunohistochemistry, and in the plasma by ELISA. Abdominal aorta rings were used to determine vascular functional responses. Chronic DE-exposure incr...

Energy Technology Data Exchange (ETDEWEB)

The performance of a gas-fuelled diesel engine (dual fuel) is examined at light load and an effective threshold limit to the combustion of the gaseous fuel through bulk flame spread is identified. The relationship of such a limit to some of the key operating parameters is then discussed. A comparison between the measured values of the limit with those corresponding to the lower flammability limits of the gaseous fuel when evaluated under the prevailing cylinder conditions during pilot diesel fuel ignition showed similar trends. It is suggested that such a similarity may form a basis for estimating the lean operation limits for duel a fuel combustion in engines. A simple approach for estimating the limiting equivalence ratio for the apparent bulk flame spread limit is described for a methane-fuelled dual fuel engine. (Author)

Energy Technology Data Exchange (ETDEWEB)

A phenomenological model based on the multizone method is described. The model requires a relatively low amount of central processing unit (CPU) time and memory for each run and, consequently, is useful for parameter studies. The flame morphology predicted by the model is compared to that recently uncovered in experimental studies. As a demonstration of its utility, the model is used to study the effect of the oxygen content in intake air on the emission of particulate matter (PM) and NO{sub x} from a direct injection diesel engine. A parametric study reveals that while oxygen-enriched intake air is useful for reducing PM, the reduction comes with a large increase in NO{sub x} emission. The PM-NO{sub x} trade-off curve for the oxygenated intake air is worse than that for the baseline air case. (Author)

Energy Technology Data Exchange (ETDEWEB)

Recent studies indicate that [Fe]-hydrogenases and H{sub 2} metabolism are widely distributed among green algae. The enzymes are simple structured and catalyze H{sub 2} evolution with similar rates than the more complex [Fe]-hydrogenases from bacteria. Different green algal species developed diverse strategies to survive under sulfur deprivation. Chlamydomonas reinhardtii evolves large quantities of hydrogen gas in the absence of sulfur. In a sealed culture of C. reinhardtii, the photosynthetic O{sub 2} evolution rate drops below the rate of respiratory O{sub 2} consumption due to a reversible inhibition of photosystem II, thus leading to an intracellular anaerobiosis. The algal cells survive under these anaerobic conditions by switching their metabolism to a kind of photo-fermentation. Although possessing a functional [Fe]-hydrogenase gene, the cells of Scenedesmus obliquus produce no significant amounts of H{sub 2} under S-depleted ...

Energy Technology Data Exchange (ETDEWEB)

The influence of surface oxides of variable composition and nonstoichiometry formed at high temperatures in air on the general corrosion resistance of ferritic chromium steel type 08H17T (Fe-17Cr-1Ti) in weak sulfuric acid has been studied. Anodic passive films formed on steel with different pretreatments have also been examined. The surface oxide of nearly stoichiometric composition formed at 300 C provides for the passive state of steel in sulfuric acid despite its depletion by chromium when compared with that for nonstoichiometric Cr-enriched oxide formed at 600 C. The dissolution and transformation of nonstoichiometric thermal surface oxide in sulfuric acid appear to take place through defect sites, {minus}Fe{sup 2+} ions, and oxygen vacancies of the n-type conductor. The passive film formed on the nonstoichiometric oxide film, which had been produced at 600 C, was found to be more susceptible to open-circuit breakdown ...

International Nuclear Information System (INIS)

Two most important causes of portal hypertension are cirrhosis of liver and non-cirrhotic portal fibrosis (NCPF). The purpose of this study was to assess the scintigraphic appearances of "9"9"mTc sulfur colloid liver scan in differentiating liver cirrhosis from NCPF. Materials and Methods: Retrospective analysis records of 146 patients (91 male and 55 female) with diffuse hepatocellular disease was done for liver size, liver uptake, spleen size, spleen uptake, colloid shift to bone marrow and lungs. Results: Cirrhotic livers showed patchy and lower uptake than NCPF (59% vs. 20%, P-value 0.041). Spleen size was significantly increased in NCPF compared to cirrhosis (100% vs. 67%, P-value 0.0137). Significant colloid shift to bone marrow was noted in cirrhosis (84% vs. 7%, P-value<0.0001). Conclusion: "9"9"mTc sulfur colloid liver scan is a non-invasive procedure having a useful adjunctive role in clinical differentiation of cirrhosis from ...

Science.gov (United States)

III--V based devices such as field effect transistors, heterojunction bipolar transistors, and lasers often have surface leakage and thermal degradation problems due to surface states which pin the Fermi level to the midgap. Sulfur based passivation processes are known to improve device performance by altering surface-state densities. We have developed a voltage-controlled anodic sulfur passivation scheme using Na[sub 2]S dissolved in ethylene glycol. Our process has repeatedly produced a [similar to]25% improvement in peak output power near the catastrophic damage limit in visible ([lambda]=670 nm) AlGaInP edge-emitting lasers. The threshold current density before and after passivation, and the [ital I]--[ital V] characteristics before and after catastrophic failure, were essentially unchanged indicating that passivation raises the threshold for facet damage.

Energy Technology Data Exchange (ETDEWEB)

Stainless steel is pickled in pickling bath with the sulfuric acid and a mixture of hydrofluoric acid and nitric acid. Suitable equipment based on speedy and accurate chemical analysis for actual production lines has not been developed yet. The concentration of sulfuric acid can be analyzed by using the neutralization titration method. As a method of analyzing hydrofluoric acid in the mixed acid, the iron-acetylacetone complex discoloration absorbance method was adopted. For the concentration, of nitric acid, the method of subtracting the concentration of hydrofluoric acid from the total mixed acid amounts obtained by neutralization titration is adopted. Furthermore, the iron-salicylic acid complex absorbance method is adopted as a method of analyzing the iron content. By adopting these methods, the fully automated analyzer is developed. Completing analysis work can be shortened to 40 minutes by automated sampling from the acid pipes. The fully ...

Energy Technology Data Exchange (ETDEWEB)

The desorption of uranium from the granular titanium-activated carbon composite adsorbent (concentration of uranium: 25.5 mg/l-Ad), which adsorbed uranium from natural sea water, was examined by the column process with acidic eluent at room temperature. The column operation was able to be carried out without destruction of the granular adsorbent by the generation of the carbon dioxide, and free from disturbance of the eluent flow by precipitate of calcium sulfate dihydrate with sulfuric acid eluent. The amount of acid consumption by the adsorbent was 0.87 eq/l-Ad. The alkaline earth metals were eluted in the range of elution volume below 2l/l-Ad, whereas uranium, iron, and titanium were eluted above 2l/l-Ad. Therefore, uranium was separable from the alkaline earth metals which were adsorbed in the most quantity in the adsorbent. In the range of elution volume 2 to 12l/l-Ad, the percentage of desorbed uranium and the concentration ratio of uranium were 80%, 680 with ...

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Visible smoke of exhaust gas from iron ore sintering plants spoil the scenery around the works. In this paper, the mechanism of formation of visible smoke is discussed by detailed analysis of the exhaust gas components and dust in the Oita No. 1 sintering plant. The main substance of visible smoke was mist condensing in the air during the cooling of exhaust gas that contained 0.1 ppm of sulfuric acid. Sulfuric acid is considered to raise the dew point and so facilitate mist condensation, and to lower the vaporization of visible mist containing sulfuric acid solution. Dust in the exhaust gas is also considered to act as nucleation sites for mist condensation. This proposed mechanism was confirmed by the test remixing SOx-rich gas with desulfurization gas in the Nagoya No. 3 sintering plant. Long trails of visible smoke were observed by remixing SOx-rich gas with exhaust gas. In conclusion, in order to make exhaust gas ...

International Nuclear Information System (INIS)

Recent work has shown that natural hydrocarbon emissions can significantly affect the levels of urban and regional tropospheric ozone. We report on the reactivities of these biogenic trace gases, particularly isoprene, focusing on their importance in the production of aldehydes and peroxy radicals, leading to increased levels of hydrogen over regional forests. Hydrogen peroxide can lead to the wet oxidation of sulfur dioxide to acidic sulfate in aerosols, fogs, and clouds. In turn, acidic sulfate can act to as a light scattering aerosol and a source of cloud condensation nuclei (CCN), potentially leading to global cooling. Aerosol sulfate and other dissolved organic and inorganic compounds can also play important roles as a greenhouse species in the lower troposphere.

Science.gov (United States)

Macrokinetics of benzene sulfonation in liquid-liquid and gas-liquid systems has been studied in continuous mixed reactors. It has been shown that the rate of sulfonation of benzene at 25/sup 0/C in two liquid phases using concentrated sulfuric acid is kinetically controlled. Whereas the rate of the latter reaction by gaseous sulfur trioxide at the same temperature is largely affected by the diffusional phenomena. At this temperature, the rate of reaction in gas-liquid system was described by a model assuming a fast reaction in the liquid phase. However, by increasing the temperature, the fast reaction region gradually changed to instantaneous reaction regime. A model, describing such a regime has also been developed and verified experimentally.

British Library Electronic Table of Contents (United Kingdom)

Sulfur mustard (HD) is an alkylating and cytotoxic chemical warfare agent, which inflicts severe skin toxicity and an inflammatory response. Effective medical countermeasures against HD-caused skin toxicity are lacking due to limited knowledge of related mechanisms, which is mainly attributed to the requirement of more applicable and efficient animal skin toxicity models. Using a less toxic analog of HD, chloroethyl ethyl sulfide (CEES), we identified quantifiable inflammatory biomarkers of CEES-induced skin injury in dose- (0.05-2 mg) and time- (3-168 h) response experiments, and developed a CEES-induced skin toxicity SKH-1 hairless mouse model. Topical CEES treatment at high doses caused a significant dose-dependent increase in skin bi-fold thickness indicating edema. Histopathological e...

British Library Electronic Table of Contents (United Kingdom)

Flue gas desulfurization systems (FGDs) are operated in severely corrosive environments that cause sulfuric acid dew-point corrosion. The corrosion behavior of low-alloy steels was tested using electrochemical techniques (electrochemical impedance spectroscopy, potentiodynamic tests, potentiostatic tests), and the corrosion products were analyzed by scanning electron microscopy and X-ray photoelectron spectroscopy. The electrochemical results showed that alloying W with small amounts of Sb, Cu, and Co improves the corrosion resistance of steels. The results of surface analyses showed that the surface of the steels alloyed with W consisted of W oxides and higher amounts of Sb and Cu oxides. This suggests that the addition of W promotes the formation of a protective WO3 film, in addition to ...

British Library Electronic Table of Contents (United Kingdom)

Catalyst deactivation during steam reforming of transportation fuels, primarily due to sulfur poisoning and carbon deposition, is a major hurdle in the commercialization of fuel cell technologies. In an attempt to better understand the phenomena, a previously formulated multi-component (Ni, Pd, Rh) catalyst supported on g-Al2O3 was studied under steam reforming of Jet A spiked with thiophene to achieve a total sulfur content of 1000ppm by weight. Analysis of fresh catalysts showed the presence of two groups of active metal particles, primarily distinguished by their size and composition; small particles (1-5nm) largely comprised of Rh and large particles (10-20nm) that were predominantly Ni, with or without the presence of Pd. Analysis of used catalysts showed sintering of crystallites con...

Energy Technology Data Exchange (ETDEWEB)

Although sulfur is present in many forms in kerosene, mercaptans are most objectionable due to their obnoxious odour and corrosive action. In this study, removal of one of the mercaptans has been reported, using red mud as an unconventional adsorbent. Red mud is a waste product from aluminium producing industries and has been used as an adsorbent for the removal of sulfur compounds as well as for other purposes. Adsorption studies described in this paper indicate that low concentration and high temperature favour the removal of 1-butanethiol from kerosene oil by adsorption on red mud. A first order mechanism has been proposed to describe the adsorption in the present system. Equilibrium data at different temperatures fit well in the Langmuir isotherm equation. Thermodynamic parameters for the present system indicate the feasibility of removal of 1-butanethiol from kerosene oil by adsorption on red mud. 10 refs., 4 figs. 3 tabs.,

Energy Technology Data Exchange (ETDEWEB)

Details are given of the Sasol operation in South Africa. Flow sheets are provided for Sasol 1 and Sasol 2 and 3. The Sasol 1 plant produces waxes, liquid fuels, pipeline gas and chemicals; the Sasol 2 and 3 plants primarily produce ethylene, gasoline and diesel fuel. The versatility of the process is emphasized. The product selectivities of the fixed bed and Synthol reactors are shown and the properties of the products are compared. The influence of the catalyst on selectivity is examined.

Energy Technology Data Exchange (ETDEWEB)

The effect of open pit mine motor transport with ICE on the air basin is examined using the example of shale mines and open pits of the production association ''Estonslanets''. Efficient areas of use of different types of open pit mine motor transport, diesel-trolley tracks and electric cars are determined based on technical-economic and ecologic feasibility.

International Nuclear Information System (INIS)

Off-grid power generation is meant to supply remote or rural area, where grid connection is almost impossible in terms of cost and geography, such as island, aborigine's villages, and areas where nature preservation is concern. Harnessing an abundance renewable energy sources using versatile hybrid power systems can offer the best, least-cost alternative solution for extending modern energy services to remote and isolated communities. The conventional method for off-grid power generation is using diesel generator with a renewable energy (RE) technology utilizing solar photovoltaic, wind, biomass, biogas and/or mini/micro hydro. A hybrid technology is a combination of multiple source of energy; such as RE and diesel generator and may also include energy storage such as battery. In our design, the concept of solar hybrid system is a combination of solar with diesel genset and battery as an energy storage. The main objective ...

Energy Technology Data Exchange (ETDEWEB)

In this work the production of sustainable syngas has been investigated for use in a co-production plant for electricity and Fischer Tropsch diesel at the Willem-Alexander Centrale in Buggenum, the Netherlands, and has also been compared to the co-production of SNG. From the analysis for this specific situation it is determined that the co-production of Fischer Tropsch liquids is economically more beneficial than co-production of SNG.

Energy Technology Data Exchange (ETDEWEB)

Dual fuel operation, in which natural gas is mixed with the diesel engine intake air and ignition is by diesel fuel spray, has the advantage that engine conversion is simple. Under high load it has the same high efficiency as a diesel engine and it can be switched to normal diesel operation for long distance running. Also, NO{sub x} and black smoke emissions can also be reduced. However, the disadvantages are to increase HC and CO emissions, to reduce efficiency under low load, and to emit the large amount of NO{sub x} under high load. Waseda University was commissioned by Tokyo Gas Co., Ltd. to conduct research program involving experimentation ragarding a dual fuel engine. It was then discovered that the most effective means of solving the problems mentioned above is Exhaust Gas Recirculation (EGR) and that the effect can be increased by heating the intake air. An old engine before the current ...

Energy Technology Data Exchange (ETDEWEB)

Some 200 visitors attended the official opening of a new diesel engine driven cogeneration plant in the city of Hamburg at the end of March. The dual fuel engine built by Blohm+Voss will supply 7.7 MW of electricity to the grid and 8.26 MW of thermal power to generate steam and hot water. (author)

Energy Technology Data Exchange (ETDEWEB)

The methodology of achieving a high power density (HPD, or brake mean effective pressure) direct-injection Diesel engine has been studied, which is directed to using high fuel/air ratio, high-speed and ceramic engine components. Among the main thrust to achieve these engine changes for an advanced Diesel engine is the design of a high injection pressure (HIP) fuel system. During the course of the present study, two Cummins 903 engines mated with a Rutger-built HIP were employed to investigate the engine response to HIP and in-cylinder processes by using the Rutgers high-speed infrared (IR) spectral digital imaging system. Five separate technical publications were prepared to report results obtained from the study. The main findings include: The HIP system permits engine operation at an air/fuel ratio of as rich as 18 to 1 with smoke emission not worse than with the conventional mechanical (low pressure) injection system; A high injection ...

International Nuclear Information System (INIS)

The purpose of work is systematical studying of benzo (B) of thiophene-1,1-dioxides and their 2,3-di-hydro derivatives behaviour in the reactions of electrophflic, radical, nucleophilic nitration, reduction of nitro group, embodiment of synthesis of N-amino derivatives, investigation of sulfur containing hetero-cyclic compounds, including of residues of some steroids

Energy Technology Data Exchange (ETDEWEB)

The structure and composition of the passive films formed on 304 stainless steel in deaerated IN H{sub 2}SO{sub 4} were studied by RHEED, XPS and AES. The stability of the passive films as a function of passivation potential and passivation time were investigated. The role of bound water in affecting the stability of the passive films is discussed. 7 refs., 3 figs.

International Nuclear Information System (INIS)

Azobenzene dyes are effective inhibitors for austenitic 304 L and 316 L stainless steel corrosion in high acidic medium up to 7N. A good efficiency is obtained from weight loss and electrochemical Rsub(p) measurements in hydrochloric acid, while no inhibition is observed in sulfuric solutions. Transformation from the primarily azobenzene to other compounds give rise to enhanced protection of steel samples, and probable structures of the inhibiting species are proposed in view of our results.

Energy Technology Data Exchange (ETDEWEB)

Sulfuric acid and its partially or completely neutralized salts with ammonia are believed to result from the oxidation of sulfur dioxide in cloud water and in other heterogeneous media present in the atmosphere. Due to the natural abundance of ammonia and the ubiquitous presence of sulfur in the atmosphere, (NH/sub 4/)/sub 2/SO/sub 4/ is commonly the dominant chemical species in the ambient aerosol. The amounts of ammonium sulfates are expected to be very low in areas far removed from anthropogenic emissions of sulfur dioxide. The chemical composition of submicrometer aerosol particles was determined at the Mauna Loa Observatory (MLO) on Mauna Loa in Hawaii during an eight-day period in August 1986. The MLO site was selected for this measurement because it is the only ground-based aerosol observatory in the remote Pacific Ocean that allows extended sampling of aerosols in the free troposphere. ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the work performed at the Institute of Gas Technology (IGT) during the second program quarter from October 1, 1993 to December 31, 1993, under Department of Energy (DOE) Contract No. DE-AC22-93PC92114. This program has co-ordinated funding for Task 1 from IGT`s Sustaining Membership Program (SMP), while DOE is funding Tasks 2--8. Progress in all tasks are reported. The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each utilize catalysts and sulfur containing intermediates: (1) to convert natural gas to CS{sub 2} and (2) to convert CS{sub 2} to gasoline range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this quarter, progress in the following areas has been made. An existing unit at IGT was modified to accommodate the sulfur ...

Science.gov (United States)

The report gives results of economic evaluations of two processes: the Rockwell International aqueous carbonate process (ACP) and the Wellman-Lord process, the latter applied to a sulfuric acid plant, the Foster Wheeler Resox process, and the Allied Chemical coal reduction proces...

Energy Technology Data Exchange (ETDEWEB)

This paper describes New York State Electric and Gas Corporation`s concept for a comprehensive, centrally located data system for management of their continuous emission monitoring systems (CEMS) data. The topics of the paper include the power system`s mix of generating units; data reporting requirements; data base management; nitrogen oxides compliance tracking; sulfur dioxide, nitrogen oxides, carbon dioxide and flow monitoring; and allowance tracking.

Energy Technology Data Exchange (ETDEWEB)

The Bavarian Agency for Environmental Protection (LfU) is monitoring the air quality is several bavarian regions. The daily and monthly data of concentration ration of sulfur dioxide, nitrogen oxides, carbon monoxide, ozone and other pollutants are published in yearly reports, most often as diagrams with further statistica information.

International Nuclear Information System (INIS)

The author discusses the accelerated aging tests performed using Hondo and Maya as aging resids with a commercial large pore hydrotreating catalyst. The results from these tests were compared with those obtained under a normal full life test. The test resid was a sample of a typical refinery charge and the activities for sulfur and vanadium removal were determined at 720"0F after successive brief periods of exposure to the heavier oils.

Science.gov (United States)

An extended series of measurements at a conventional coal-fired boiler equipped with a wet-limestone flue gas desulfurization unit has shown that sulfate and sulfur dioxide removal efficiencies are dissimilar. The average SO2 scrubbing efficiency was 76% and was observed to decrease over a five-day operating cycle. Total sulfate scrubbing efficiency, averaging about 29%, was invariant throughout the operating cycle. (1 diagram, 3 tables)

International Nuclear Information System (INIS)

By treatment of ?-substituted acetylacetone derivatives with boron trifluoride etherate a series of earlier unknown boron difluoride complexes is obtained. The series includes binuclear complexes containing boron in the chelate fragment connected via sulfur or selenium atom. Gas chromatographic and spectral characteristics of the obtained compounds were investigated. By means of chromato-mass spectrometry their reaction with hydrazine in acidic and alkaline media was studied

Energy Technology Data Exchange (ETDEWEB)

Today, as a result of increase in oil prices, limited fossil fuel resources, environmental consideration and global warming, the methyl ester fuels have been focused on alternative fuels. Methyl ester fuels can be used more efficiently in low heat rejection engines (LHR), in which the temperature of combustion chamber is increased by creating a thermal barrier. In this study, the piston, cylinder head, exhaust and inlet valves of a diesel engine were coated with the ceramic material Al{sub 2}O{sub 3}-TiO{sub 2} by the plasma spray method. Thus, a thermal barrier was provided for the parts of the combustion chamber with these coatings. The effects of corn oil methyl ester that produced by the transesterification method, and No. D2 fuels' performance and exhaust emissions' rate were studied by using equal in every respect coated and uncoated engines. Tests were performed on the uncoated engine, and then repeated on the coated engine and the results ...

Energy Technology Data Exchange (ETDEWEB)

A mathematical model was developed to simulate the combustion process of a direct injection diesel engine. The model considers the key features of such a combustion process; namely fuel droplet evaporation, spray formation, mixing, ignition of heterogeneous burning of the fuel. To model mixing, great emphasis was placed on treating both large and small scale aspects of mixing, the model divides the combustion chamber into three distinct regions of air, fuel spray, and a turbulent plume that is formed once ignition occurs. The fuel spray itself is considered to be composed of multiple zones, which in turn are made of cells of equal mass and of different thermodynamic states. Micromixing of the fuel and air cells, within each zone of the jet and the turbulent plume, is then achieved by utilizing the concept of Monte Carlo stochastic coalescence dispersion technique. The frequency of such cell interactions within each zone is obtained by employing a K-1 turbulent ...

Energy Technology Data Exchange (ETDEWEB)

The cooperative project was a joint development program between Ceradyne and Oak Ridge National Laboratory through Lockheed Martin Energy Research (LMER). Cooperative work was of benefit to both parties. ORNL was able to assess the effect of the microwave nitridation process coupled with gas-pressure sintering for fabrication of parts for advanced diesel engines. Ceradyne gained access to gelcasting expertise and microwave facilities and experience for the nitridation of SRBSN materials. The broad objective of the CRADA between Ceradyne and OIWL was to (1) examine the applicability of the gelcasting technology to fabricate parts from SRBSN, and (2) to assess the effect of the microwave nitridation of silicon process coupled with gas-pressure sintering for fabrication of parts for advanced diesel engines. The following conclusions can be made from the work performed under the CRADA: (1) Gelcasting is a viable method to fabricate SRBSN parts ...

Energy Technology Data Exchange (ETDEWEB)

A methanol car means a car driven with a fuel that has part of or the whole of the gasoline or kerosene replaced with methanol. Fuel methanol is abundantly available, relatively easy to transport and store and has few environmental pollutants in its exhaust gas. Its octane value is high, but ignitionability is not good due to its low cetane value. It is good for Otto cycle engines, but not adequate for diesel cycle engines. As a technological problem, the point is ignitionability and development of Otto type methanol engines ahead of that of diesel type methanol engines. Evaluation of methanol cars is internationally high and its development is done vigorously, but there are also problems including a short continuous travel distance due to the low heating value of methanol. Although methanol cars are deemed to be most promising for commercialization among cars using alternative fuel, it is necessary to cope systematically and collectively in ...