Energy Technology Data Exchange (ETDEWEB)

In recent years, interest in the development of a polymer electrolyte fuel cell (PEFC) has considerably increased due to its advantages (e.g., high power density) compared with other fuel cell systems, and its potentials to become the power plant for the next generation, nonpolluting automobile engine. For large scale application of fuel cells, low platinum loading electrode structures are necessary. An electrode based on a highly porous carbonized polyacrylonitrile foam material with very low platinum loading ({approximately} 13 {micro}g/cm{sup 2}) was prepared. The performance of this electrode for oxygen reduction was evaluated and compared with bulk platinum and glassy carbon electrodes.

Energy Technology Data Exchange (ETDEWEB)

The deposition of platinum on various carbon blacks was carried out by forming active functional groups on the surface of the carbon support, and exchanging these active groups with different platinum complexes. Using H{sub 2}PtCl{sub 6} solution, an impregnation rather than an exchange takes place. However, using divalent platinum complexes [Pt(NH{sub 3}){sub 4}]{sup 2+}, a fast exchange takes place which leads to extremely small platinum particles highly dispersed on the surface of carbon black. A comparison of the catalytic activities of platinum supported on various carbon blacks was also carried out. The performances of PEFC (Polymer Electrolyte Fuel Cell) based on the process of the ion exchange are reported. (authors) 3 refs.

Energy Technology Data Exchange (ETDEWEB)

X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) have been conducted on a new fuel cell electrocatalytic material based on a highly porous carbonized polyacrylonitrile (PAN) microcellular foam with very low platinum loading ({approximately}13 to 23 {micro}g/cm{sup 2}). TEM images of this material clearly show the existence of nanometer size platinum particles which are homogeneously distributed in the highly porous carbonized PAN matrix. An XPS study of Pt-loaded PAN indicates that C 1s, O 1s, and N 1s peaks shift to lower binding energies, compared to virgin PAN. It was concluded that special metal-support interaction exists, through the formation of a charge-transfer complex between platinum and pyridine-type nitrogen atoms of PAN support. This interaction leads to the enhancement of the catalytic activity, and the improvement of the long-time ...

Energy Technology Data Exchange (ETDEWEB)

A comparison between the concepts of the hybrid electric vehicle (HEV) and the ultra low emission vehicle (ULEV) was presented. The ULEV uses a much larger engine compared to the HEV, but it uses a lower Kw generator/motor and inverter/charger to use the latest engine and battery technology. The underlying goal of the ULEV is to supply auxiliary power under start-up and heavy load conditions and to remove indirect systems such as steering, starting and blower control from the engine via small electric drives. The challenge is to build a ULEV that is robust enough to withstand any environmental conditions. Since the ULEV engine is larger, it can experience compartment temperatures greater than 125 degrees C, which limits the use of conventional filter capacitors. Nippon Chemi-Con has recently developed U787D, the world's first continuous 150 degrees C rated aluminum electrolytic capacitor designed to meet the ...

International Nuclear Information System (INIS)

A single plasma process involving three consecutive steps has been developed for producing high gas flow catalytic nanostructures on the electrodes of proton exchange membrane (PEM) fuel cells (FC). Using a high density helicon radio frequency (13.56 MHz) plasma, nickel is sputtered onto a porous carbon support. Changing the background gas from argon to methane/hydrogen allowed 2 ?m long, 37 nm diameter carbon nanofibres (CNFs) to be grown by diffusion through the nickel clusters in a 'tip growth' mechanism at the relatively low temperature of 400 deg. C. The third step involves plasma sputtering of platinum onto the CNFs, resulting in nanoclusters (3-8 nm) being formed on the periphery of the CNFs. Four FC cathodes were synthesized on carbon paper and PTFE/carbon loaded cloth (known as gas diffusion layer, GDL), both with and without CNFs, with the Pt/CNFs nanostructures grown on PTFE/carbon loaded cloth having the best FC ...

Science.gov (United States)

We describe the synthesis of metal-chelating polymers (MCPs) with four different pendant polyaminocarboxylate ligands (EDTA, DTPA, TTHA, DOTA) and an orthogonal end-group, either a fluorescein molecule or a bismaleimide linker for antibody attachment. Polymer characterization by a combination of (1)H NMR, UV/vis absorption measurements, and thermal gravimetric analysis (TGA) indicated that each chain of the fluorescein-terminated polymers contained one dye molecule. These polymer samples were loaded with three different types of lanthanide ions as well as palladium and platinum ions. The numbers of metal atoms per chain were determined by a combination of UV/vis and conventional ICP-MS measurements. The experiments with lanthanide ions demonstrated that a net anionic charge on the polymer is important for water solubility. These experiments also showed that at least one type of lanthanide ion (La(3+)) is capable of forming a bimetallic complex ...

International Nuclear Information System (INIS)

Graphical abstract: - Abstract: Low loading platinum-cobalt (Pt-Co) cathode catalyst on a Nafion(Na+)-bonded carbon layer is fabricated by using galvanostatic pulse technique to show the advantage of electrodeposition for high utilization of catalyst in proton exchange membrane fuel cell (PEMFC). We observed that Pt-Co catalysts evenly exist on the surface of carbon electrode and its thickness is about 5.8 ?m, which is four times thinner than conventional Pt/C. Improved single cell power performance of Pt-Co cathode catalysts with a ratio of 3.2:1 compared with Pt/C is clearly presented.

International Nuclear Information System (INIS)

Reducing count losses and pile-up pulse effects in quantitative and qualitative analysis is necessary for accuracy of analysis. Therefore, the optimum peaking time for particular detector systems is important. For this purpose, pure Se and Zn elements were excited by 59.5 keV ?-rays from a 50 mCi 241Am annular radioactive source in this study. The characteristic x-rays emitted from pure Se and Zn elements were detected by using an ultra low energy Ge (Ultra-LEGe) detector connecting Tennelec TC 244 spectroscopy amplifier at different peaking time modes. Overall pulse widths were determined by HM 203-7 oscilloscope connecting amplifier. The proper peaking time for ultra low energy germanium detector (Ultra-LEGe) is determined about 4 ?s.

Energy Technology Data Exchange (ETDEWEB)

The NREL Sensitized Solar Cell (SSC) Core Program supports the Solar America Initiative by: (1) targeting new devices and processes for commercialization by 2015 that are less expensive, more efficient, highly reliable, and environmentally benign; (2) collaborating with DOE OS/BES to conduct basic research targeting breakthroughs in key areas, such as ultra-high efficiency and/or ultra-low cost materials and devices.

Energy Technology Data Exchange (ETDEWEB)

A method based on the collection of [sup 99]Tc from 500 l sea water samples by anion exchange and further extraction of TcO[sub 4][sup -] into 5% triisooctylamine-xylene has been improved to include a decontamination factor 6.5x10[sup 5] for uranium. The detection limit for [sup 99]Tc is thereby reduced to 3 mBq/m[sup 3].

Science.gov (United States)

Platinum and ruthenium in carbon supported Pt and Pt-Ru catalysts were determined by direct and derivative spectrophotometric methods. Complexes of platinum and ruthenium with SnCl(3)(-) ligands (tin(II) chloride in HCl) were used to determine both metals in solutions obtained after digestion of the samples of the catalysts. Platinum in the Pt/C catalyst can be determined in solutions obtained by digestion of the samples in aqua regia. Derivative spectrophotometry was used to determine both metals in the presence of each other in solutions obtained after digestion of samples of the Pt-Ru/C catalyst in the mixture of HCl+HNO(3) (6:1). The first derivative at 377 nm (;zero-crossing' point of ruthenium) and the second-derivative values at 495 nm (;zero-crossing' point of platinum) were used to estimate the concentration of platinum and ruthenium, respectively. PMID:18967441

International Nuclear Information System (INIS)

Potassium atoms in selected high-lying np Rydberg states (80 #<=# n #<=# 400) are being used as a tool to examine electron-polar molecule collisions at ultra-low energies (#approx#80 #mu#eV - 1 meV). This energy regime has not been investigated previously and is of interest because the corresponding electron de Broglie wavelength is large, #approx#1300 - 330 Angstrom, and because the collision time is comparable to the period of molecular rotation. A variety of target molecules has been studied, including simple rotors such as HF, and more complex species such as NH_3, CH_3I, CH_2Br_2 and C_6H_5NO_2. These targets encompass a range of dipole moments and rotational behavior, but analysis of the data shows that in each case the cross section #sigma#(#epsilon#) for rotationally-inelastic electron-polar molecule scattering varies approximately as 1/#epsilon# where #epsilon# is the electron energy. Such threshold behavior is not predicted by the Born approximation ...

Energy Technology Data Exchange (ETDEWEB)

In this work we present an ultra-low temperature method for the oxidation of an amorphous silicon-carbide-nitride (SiCN) material. The SiCN is deposited on silicon substrates by plasma enhanced chemical vapor deposition using CH{sub 4}, SiH{sub 4}, and N{sub 2} chemistry. The physical and chemical properties are characterized for the as-deposited SiCN and post-oxidized films are discussed. The SiCN film is exposed to oxygen plasma, where it undergoes a chemical transformation into a binary SiO{sub 2} material system. A 1.7 nm/min oxidation rate is typical for this process and compares favorably to oxidation methods utilizing much higher temperatures. The substrate temperature remains extremely low throughout the oxidation process, T{sub s} < 200 deg. C. Changes in film stress, optical constants, film thickness, surface roughness, and film density are measured. Chemical analysis by X-ray photoelectron spectroscopy is reported for both the as-deposited and ...

Energy Technology Data Exchange (ETDEWEB)

A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode.

Energy Technology Data Exchange (ETDEWEB)

Our objective was to evaluate the feasibility of ultra-low-dose scanning for multislice CT colonography in the detection of colorectal lesions. Twenty-seven patients (14 men, 13 women) with clinical indication for conventional colonoscopy were recruited. Multislice spiral CT (Somatom Plus 4 Volume Zoom, Siemens, Germany) examinations were performed after standard oral colonoscopic preparation and colonic distension with room air. Images were acquired using 2.5-mm collimation, 3.0-mm slice thickness, standard reconstruction kernel, 140 kVp, and 10 mAs. Supine and prone acquisitions were obtained in all patients. Images were analyzed on a workstation by two gastrointestinal radiologists. Conventional colonoscopy was performed on the same day in all patients and represented the standard of reference. Total radiation exposure was also calculated. All colorectal cancers were correctly identified at CT colonography (9 of 9, sensitivity 100%). The CT colonography also ...

Energy Technology Data Exchange (ETDEWEB)

In this note it is suggested that binuclear platinum(II) complexes with a solely inorganic bridging pyrophosphito ligand also possess many of the complementary advantages of inorganic and organic dyes. They are evaluated for their potential use as a luminescent solar concentrator material. The disadvantages include: the high cost of platinum; the absorption spectra in solution shows a weaker absorption at 452 nm which may cause reabsorption of emitted light; the positions of the absorption and emission maxima are not at the optimal wavelengths for absorption of sunlight and emission to a solar cell. In spite of these drawbacks the author believes the platinum complexes merit consideration for fabrication of solar concentrator devices.

International Nuclear Information System (INIS)

We studied the optimum plasma conditions that are required for efficient high-order harmonic generation in platinum plume. Harmonics up to the 49th order (?=16.32 nm) are analyzed under various conditions of laser-plasma interaction. Time-resolved ultraviolet spectra of platinum plasma at both optimum and nonoptimum conditions of harmonic generation are presented. We calculated the ionization states of the plasma, free electron density, and singly charged ion density at different prepulse intensities and compared them with experimental results.

Energy Technology Data Exchange (ETDEWEB)

Availability of a natural gas-powered van that meets California`s ultra low emission vehicle requirements and has a 300-km range was reported. A similar van with an electric system giving a range of 240 km was also within sight. Regarding the limitations of electric batteries it was suggested that a super capacitor may allow systems to achieve higher energy densities; a refuelable zinc-air battery could be considered for vehicle use. While the prospect for emissions improvement of gasoline vehicles has clearly improved in recent years, the relative costs of infrastructure, vehicle and fuel for the the alternative fuels compared with gasoline demonstrate the difficulty the alternative fuels have in taking market share from gasoline. For the next decade, gasoline, propane and CNG are expected to be the dominant fuels for vehicles. After that, the leading fuel will be the one that has been most extensively researched and developed during the ...

British Library Electronic Table of Contents (United Kingdom)

We report the fabrication and characterization of glucose-tolerant Raney-platinum cathodes for oxygen reduction in potentially implantable glucose fuel. Fabricated by extraction of aluminum from 1mm thin platinum-aluminum bi-layers annealed at 300^oC, the novel cathodes show excellent resistance against hydrolytic and oxidative attack. This renders them superior over previous cathodes fabricated from hydrogel-bound catalyst particles. Annealing times of 60, 120, and 240min result in approximately 400-550nm thin porous films (roughness factors ~100-150), which contain platinum and aluminum in a ratio of ~9:1. Aluminum release during electrode operation can be expected to have no significant effect on physiological normal levels, which promises good biocompatibility. Annealing time has a dis...

Energy Technology Data Exchange (ETDEWEB)

A new fuel-cell electrocatalyst based on highly porous carbonized polyacrylonitrile (PAN) microcellular foam with platinum particles was prepared recently in this laboratory. Its surface morphology, one of the most important aspects of a practical electrocatalyst, has been examined in terms of fractal theory and methods. The fractal dimension of the platinum particles dispersed in porous carbonized PAN foam was determined by using chronometric and rotating-disk-electrode methods in oxygen-saturated solutions. A fractal dimension smaller than 2 was obtained, which was attributed to the partially active nature of the surface of this electrocatalytic material. This value of fractal dimension is also proposed to be considered as a reaction dimension. A reaction dimension smaller than 2 may indicate that not all of the platinum particle surface is accessible to the incoming oxygen molecules.

Energy Technology Data Exchange (ETDEWEB)

A series of (diamine)isopropylidenmalonatoplatinum(II) complexes and the oxidation products, (diamine)Pt(OOC){sub 2}C=C(CH{sub 3}){sub 2}(X){sub 2}, (diamine=ethylenediamine(en), 1,2-diaminopropan(dap), N-methylethylenediamine(men); X=OH, OCOCH{sub 3}, OCOCF{sub 3}), have been prepared, and their interaction with guanosine-5'-monophosphate (5'-GMP) have been examined by means of {sup 1}H NMR spectroscopy. The present platinum(II) complexes have shown to interact with 5'-GMP through N7 coordination in two consecutive steps in a similar way as with cisplatin, but no interaction between the present platinum(IV) complexes and 5'-GMP was observed. However, in the presence of ascorbic acid, the platinum(IV) complexes have been found to interest with 5'-GMP with the reation rate depending on their reduction rate.

Energy Technology Data Exchange (ETDEWEB)

The EXAFS spectra of the platinum(III) complexes Pt/sub 4/(OAc)/sub 10/(OH)/sub 2/ (I) and Pt/sub 4/ (OAc)/sub 4/(OH)/sub 8/(H/sub 2/O)/sub 2/ (II) have been investigated. It has been found by a curve-fitting method and with the aid of Fourier transformations that the shortest Pt-Pt distances are 2.61 A in complex I and 2.36 and 2.6 A in II. The values of the bond lengths obtained are consistent with the molecular structures proposed for complexes I and II, which contain skeletons of four platinum atoms in the form of a square or a rectangle, as well as with the known literature data on the lengths of Pt-Pt bonds in Pt(III) complexes.

Energy Technology Data Exchange (ETDEWEB)

The electronic structures of platinum group elements (Ru, Os, Rh, Ir, Pd, and Pt) silicides have been calculated. Ir{sub 3}Si{sub 5} is a semiconductor with the direct gap of 1.14 eV. Among monosilicides, RuSi and OsSi with the FeSi-type structure are semiconductors with the gap values of 0.21 and 0.41 eV but RhSi, IrSi, PdSi, and PtSi with the MnP-type structure are metals. No semiconducting compounds can be found in other platinum group elements silicides other than known Ru{sub 2}Si{sub 3}, Os{sub 2}Si{sub 3}, and OsSi{sub 2}.

CERN Document Server

Several observational studies suggest that solar wind dynamic pressure fluctuations can drive magnetospheric ultra-low frequency (ULF) waves on the dayside. To investigate this causal relationship, we present results from Lyon-Fedder-Mobarry (LFM) global, three-dimensional magnetohydrodynamic (MHD) simulations of the solar wind-magnetosphere interaction. These simulations are driven with synthetic solar wind input conditions, where idealized ULF dynamic pressure fluctuations are embedded in the upstream solar wind. In three of the simulations, a monochromatic, sinusoidal ULF oscillation is introduced into the solar wind dynamic pressure time series. In the fourth simulation, a continuum of ULF fluctuations over the 0-50 mHz frequency band is introduced into the solar wind dynamic pressure time series. In this numerical experiment, the idealized solar wind input conditions allow us to study only the effect of a fluctuating solar wind dynamic pressure, while holding ...

International Nuclear Information System (INIS)

We present an atomistic simulation of the Ostwald ripening of extrinsic defects (clusters, #left brace#1 1 3#right brace#s and dislocation loops) which occurs during annealing of ion implanted silicon. The model describes the capture and emission of Si interstitial atoms to and from extrinsic defects of sizes up to thousands of atoms and includes a loss term due to the flux of interstitials to the recombining surface. Key input parameters of the simulation are the variations of the formation energy and of the capture efficiency with the size of the different defects. This model shows that the kinetics of the well-known dissolution of #left brace#1 1 3#right brace# defects is only driven by the recombination efficiency at the surface and the distance from the defects to the sample surface. We have subsequently used this model to study defect evolution in low and ultra low energy (ULE) B implanted Si during annealing. Defect dissolution occurs ...

International Nuclear Information System (INIS)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P"+/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B"+ and BF_2"+ ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF_3 as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical insights explaining the technological benefit coming from PLAD technique over standard ion ...

Energy Technology Data Exchange (ETDEWEB)

In this study, the exhaust gas from a common-rail direct injection diesel engine was investigated both upstream and downstream warm-up catalytic converters (WCC). Three different types of ultra-low sulfur fuels (ethanol-diesel blend, ethanol-diesel blend with cetane improver and pure diesel) were tested in this study. The objective of the work was to study the engine performance and the formation of THC (total hydro carbon), CO (carbon monoxide), NO{sub x} (nitrogen oxides), smoke and PM (particulate matters) when using these fuels. THC and CO emissions of the ethanol-diesel blend fuels were slightly increased, and about 50-80% mean conversion efficiencies of THC and CO on catalysts were achieved in the ECE R49 13-mode cycle. Smoke was decreased by more than 42% in the entire ECE 13-mode cycles. From the measurement of scanning mobility particle sizer (SMPS) for the particle size range of 10-385 nm, the total number and total mass of the PM of the ethanol-diesel ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

UK PubMed Central (United Kingdom)

PurposePlatinum and taxane compounds have demonstrated activity in uterine carcinosarcoma (malignant mixed Mullerian tumor). Ifosfamide plus paclitaxel is the regimen with established...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Platinum complexes play an important role in the development of anticancer drugs. Their cytotoxicity can be influenced by the nature of the leaving ligands, due to the hydrolysis reaction that occurs prior to the binding of the platinum complex to DNA. Also, non-leaving groups such as lipophilic diamines may affect cellular uptake. In this work, we describe the synthesis of platinum(II) complexes having oxalato and long chain aliphatic N-alkyl ethylenediamines as ligands. The products were characterized by elemental analyses, infrared spectroscopy and {sup 1}H, {sup 13}C and {sup 195}Pt NMR spectroscopy. Biological activity was assessed against tumor cell lines (A{sub 549}, B16-F1, B16-F10, MDA-MB-231) and non-tumor cell lines (BHK-21 and CHO). The length of the carbon chain affects the cytotoxicity and the oxalato complexes were less cytotoxic than the respective chloride-containing analogues. (author)

UK PubMed Central (United Kingdom)

DNA interstrand cross-links (ICLs) are critical cytotoxic lesions produced by cancer chemotherapeutic agents such as the nitrogen mustards and platinum drugs; however, the exact mechanism of ICL-induced...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Crystalline bis(O,O'-di-sec-butyldithiophosphato)platinum(II) was prepared and studied by means of 13C, 31P CP/MAS NMR spectroscopy and single-crystal X-ray diffraction. The unit cell of the platinum(II) compound is comprised of one centrosymmetric mononuclear molecule [Pt{S2P(O-sec-C4H9)2}2], in which the dithiophosphate groups display structural equivalence in both 31P NMR and XRD data. A pair of the dithiophosphate ligands exhibit the same S,S'-bidentate chelating structural function and form two planar four-membered chelate rings, [PtS2P], in this molecule. The planar configuration of the [PtS4] chromophore in structure 1 is governed by the dsp2-hybrid state of platinum(II). The structural states of the dithiophosphate groups in two different samples of complex 1 (one crystallised from...

International Nuclear Information System (INIS)

We investigated the electrical characteristics and the junction depth of ultra-shallow junctions formed by using the plasma-doping method. Compared with ultra-low energy boron-ion implantation at 500 eV, the junctions formed with the plasma-doping process exhibited shallow junction depths and low sheet resistances. The junction depths of the plasma-doped samples were 150 A and 330 A after annealing for 10 s at 900 .deg. C and 950 .deg. C, respectively. For the same junction depth, the sheet resistance of the B_2H_6 plasma-doped sample was an order of magnitude less than that of the 500-eV B-ion implanted sample. Cross-sectional transmission electron microscopy and deep level transient spectroscopy showed that the defects formed by the B_2H_6 plasma-doping process could be removed by annealing at 950 .deg. C for 10 s. The scaling of metal-oxide-semiconductor field-effect-transistor (MOSFET) device channel lengths for high-speed application requires the scaling down ...

Energy Technology Data Exchange (ETDEWEB)

The first preparation and characterization of the platinum (II) complexes containing five phosphorus ligands are reported herein. The complexes are represented by the formulae (Pt(PP/sub 3/)(P(OR)/sub 3/)Cl/sub 2/, where R = Me or Et, and (Pt(PP/sub 3/)(PEt/sub 3/))Cl/sub 2/. The /sup 31/P spectra of the complexes are presented. 10 references, 2 tables.

Energy Technology Data Exchange (ETDEWEB)

Pt-based ternary catalysts have been proposed as electrode materials for low temperature fuel cells. Pt-Ru-based ternary catalysts were tested as anode materials with improved CO tolerance or enhanced activity for methanol or ethanol oxidation. Ternary catalysts based on platinum alloyed with first row transition metals were tested as cathode materials with improved activity for the oxygen reduction. This paper presents an overview of the preparation methods and structural characteristics of these ternary catalysts. (author)

Energy Technology Data Exchange (ETDEWEB)

Carbalkoxylation of vinyl electrophiles was investigated using platinum complexes. This reaction occurs in two steps: (a) carbonyl insertion of {sigma}-vinyl Pt(II) halides and (b) alcoholysis of vinylic acyl Pt(II) complexes. Alcoholysis of vinylic acyl Pt(II) triflate complexes is investigated kinetically. Vinylic acyl Pt(II) complexes were isolated and characterized. 51 refs., 5 figs., 6 tabs.

Science.gov (United States)

PMID:21807581

Science.gov (United States)

...2009-07-01 2009-07-01 false Loading and haulage equipment; operation. 77.1607 Section 77.1607...Loading and Haulage § 77.1607 Loading and haulage equipment; operation. (a) Vehicles shall follow...

Science.gov (United States)

...2010-07-01 2010-07-01 false Loading and haulage equipment; installations. 77.1605 Section 77.1605...Loading and Haulage § 77.1605 Loading and haulage equipment; installations. (a) Cab windows shall...

Energy Technology Data Exchange (ETDEWEB)

New platinum(II) complexes with asymmetrically substituted chiral diamine ligands A{sub 2}PtX{sub 2}, (A{sub 2}=NH{sub 2}CH(CH{sub 3})CH{sub 2}NH(c-C{sub 5}H{sub 9}) (apcpa), NH{sub 2}CH(CH{sub 3})CH{sub 2}NH(c-C{sub 6}H{sub 11}) (apcha); X{sub 2}=2Cl, isopropylidenmalonate (IPM), 1,1'-cyclobutandicarboxylate (CBDCA) have been synthesized and characterized by means of elemental analyses, infrared and NMR spectroscopies, and X-ray crystallography. The crystal structures of (S-apcha)Pt[CBDCA]{center_dot}3H{sub 2}O (orthorhombic, P2{sub 1}2{sub 1}2(No. 18), a=6.926(3), b=15.243(3), c=19.319(4) A, V=2039.5(10) A{sup 3}, Z=4, R=0.072) and (S-apcha)Pt[IPM]{center_dot}2.5H{sub 2}O (monoclinic, P2/c(No. 13), a=9.882(1), b=18.502(1), c=22.056(1) A, V=4032.8(5) A{sup 3}, Z=8, R=0.093) exhibit that the platinum atoms achieve a typical square planar arrangement with two nitrogen atoms in cis position and with the chiral center retained. The ...

British Library Electronic Table of Contents (United Kingdom)

Platinum(II) complexes (1-4) with bidentate N,Nprime-ligands, O,Oprime-dialkyl esters (alkyl = ethyl, n-propyl, n-butyl and n-pentyl), of (S,S)-ethylenediamine-N,Nprime-di-2-(4-methyl)pentanoic acid were synthesized and characterized by IR, 1H NMR and 13C NMR spectroscopy and elemental analysis. DFT calculations were performed for the complexes and it was found that only one diastereoisomer could be formed. Cytotoxic activity of complexes 1-4 was determined against chronic lymphocytic leukemia cells (CLL) and compared to the activity of ligand precursors L12HCl-L42HCl and corresponding palladium(II) complexes, [PdCl2L] (L = L1-L4). The complexes were found to exhibit significantly higher antitumor activities than cisplatin on CLL cells. Cytotoxic effect of platinum(II) complexes on CLL cel...

British Library Electronic Table of Contents (United Kingdom)

A variety of platinum(II) complexes of methimazole (2-mercapto-1-methylimidazole; HImS=neutral form and ImS=thiolate form), coordinated in both thione and thiolate forms, have been isolated by reacting methimazole with [PtCl(terpy)]Cl (terpy=2,2prime:6prime,2Prime terpyridine), [PtCl2(bipy)] (bipy=bipyridine), [PtCl2(o-phen)] (o-phen=o-phenanthroline), [PtCl2(CH3CN)2] and [PtCl2(COD)] (COD=1,5-cyclooctadiene). These complexes were characterized by electronic absorption, IR and NMR (1H, 13C, 195Pt) spectroscopies. Molecular structure of [Pt(bipy)(HImS)2]Cl23H2O (3a3H2O) has been established by single crystal X-ray crystallography. Platinum thiolate complex, [Pt(ImS)2(HImS)2] (5), could be obtained by treatment of [Pt(HImS)4]Cl2 with sodium methoxide in methanol. The solution of 5 in organic...

Energy Technology Data Exchange (ETDEWEB)

In Polymer Electrolyte Fuel Cell (PEFC) technology the reducing of volume and mass of the fuel cell stack and the improvement of catalyst utilization are of great interest. These parameters affect applicability and system cost. In this work we present an alternative way for reducing the stack volume by combining gas distribution and catalytic active area in one plate. Micro machined glassy carbon electrodes serve as support material for the platinum catalyst, as well as gas distributor at the same time. A comparison of these electrodes with conventional platinum-black gas diffusion electrodes under fuel cell conditions shows that the new system is a promising electrode type for enhanced power density and catalyst utilization. (author) 3 figs., 5 refs.

Energy Technology Data Exchange (ETDEWEB)

In 2003, Vehicle Emissions Team of the Clean Air Strategic Alliance (CASA) decided to explore ways to reduce vehicle emissions such as particulate matter, nitrogen oxides, carbon monoxide, and hydrocarbons from diesel engines. One of the options for reducing emissions from diesel engines, a diesel particulate filter (DPF), is the subject of a demonstration project to test the effectiveness of the Johnson Matthey diesel particulate filter called Continuously Regenerating Technology (CRT) under cold weather conditions. The project involved filter testing between January 2003 and January 2004 on two diesel buses in Edmonton Transit System's (ETS) fleet. Vehicle exhaust emissions were tested for total hydrocarbons, nitrogen oxides, carbon monoxide, carbon dioxide, and particulate matter. The objectives of the project were to: prove the effectiveness of DPF under cold weather conditions in Alberta; provide an opportunity for hands-on installation experience and use of CRT ...

International Nuclear Information System (INIS)

This study aims to evaluate fatigue strength properties at long-term high temperature of 316FR steels developed for structural materials applied to high temperature components in the 21st Century such as Demonstration FBR, and to obtain design indicators on high temperature strength properties arranged on chemical composition and grain size on a base of 316FR stainless steels. As results obtained by the study, it could be found that as a result of systematic examinations on temperatures and strain rate dependence on symmetric triangular strain waveform of 316FR steels between 500 to 600degC, temperature of fatigue life, and strain rate dependence can be integrally evaluated by a parameter analysis method developed by authors and life prediction at ultra low strain rate of less than 10"-"6/s and its experimental verification could be carried out. And, it was also found that as a result of evaluation of creep fatigue life and creep rupture ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

Reaction kinetics for the displacement of 5-aminoquinoline (5-Aq) and diethyl sulfide (SEt{sub 2}) from cis-[PtPh{sub 2}(CO)(L)] (L = 5-Aq or SEt{sub 2}) by aliphatic amines was measured for a wide array of amines. Reaction products were characterized by IR and NMR spectroscopies and crystalk structures of selected products were reported. Steric effects on the substitutions were discussed.

Energy Technology Data Exchange (ETDEWEB)

Hydrogen uptake and embrittlement of tantalum by electrolytically produced hydrogen is investigated on samples of varying composition and type of pretreatment. Of decisive influence on the uptake of hydrogen are the oxide layers present on the tantalum surface. By contact with platinum group metals as alloying constituents, surface coatings or anodic protection, a protection of tantalum can be obtained depending on the experimental conditions.

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the oxidative addition of CH/sub 3/I to platinum(II) complexes in aqueous solutions of K/sub 2/PtCl/sub 4/ and KPtCl/sub 3/(C/sub 2/H/sub 4/) have been studied by PMR and GLC. The second-order rate constants for the PtCl/sub 3/(H/sub 2/O)/sup -/ and PtCl/sub 4//sup 2 -/ particles are equal to 400 exp(-2.7 x 10/sup 3//T) and 3.18 x 10/sup 10/ exp(-9.2 x 10/sup 3//T) mole/sup -1/ x liter x sec/sup -1/, respectively. The introduction of a ..pi..-acceptor ligand, viz. ethylene, into the coordination sphere of platinum(II) results in a sharp drop in the rate, probably due to a decrease in the electron density on the platinum atom. According to the PMR data, the product of the oxidative addition of CH/sub 3/I to Zeise's salt is a methyl complex of platinum(IV), is identical to the complex obtained by reacting methyl iodide with K/sub 2/PtCL/sub 4/, and does not contain an olefin.

UK PubMed Central (United Kingdom)

Most mechanical forces acting on the skeleton are generated either through impact with the ground (i.e., gravitational loading) or through muscle contractions (i.e., muscle loading). If one...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

In this paper an attempt is made to forecast load using fuzzy neural network (FNN) for an integrated power system. Here, the proposed system uses a two stage FNN for a short term peak and average load forecasting (STPALF). The first stage FNN deals with the load forecasting and the second stage algorithm can be worked independently for network security. This technique is used to forecast load accurately on week days as well as holidays, weekends and some special occasions considering historical data of load and weather information and also take necessary control action for network security.

Science.gov (United States)

... Accession Number : ADD431225. Title : Influence of Fiber Loading on Thermal Ablation of PTFE,. Corporate Author : Personal Author(s) : Letson,KN. ...

Energy Technology Data Exchange (ETDEWEB)

This document is the annual update of the FFTF and Advanced Reactors Transition Program Resource Loaded Schedule for FY 2002 using current project direction and authorized funding levels

KoreaScience (Korea)

Full Text Available

International Science & Technology Center (ISTC)

Multi-functional Bioactive Nano-structured Coatings for Load-Bearing Implants

Energy Technology Data Exchange (ETDEWEB)

This document describes a simple and general way to generate House Simulation Protocol (HSP)-consistent internal sensible and latent loads in unoccupied homes. It is newly updated based on recent experience, and provides instructions on how to calculate and set up the operational profiles in unoccupied homes. The document is split into two sections: how to calculate the internal load magnitude and schedule, and then what tools and methods should be used to generate those internal loads to achieve research goals.

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The present invention concerns a high thermal load heat receiving plate such as a divertor plate of a thermonuclear device. The high thermal load heat receiving plate of the present invention has a cooling performance capable of suppressing the temperature of an armour tile to less than a threshold value of the material against high thermal loads applied from plasmas. Spiral polygonal pipes are inserted in cooling pipes at a portion receiving high thermal loads in the high temperature load heat receiving plate of the present invention. Both ends of the polygonal pipes are sealed by lids. An area of the flow channel in the cooling pipes is thus reduced. Heat conductivity on the cooling surface of the cooling pipes is increased in the high thermal load heat receiving plate having such a structure. Accordingly, temperature elevation of the armour tile can be ...

International Nuclear Information System (INIS)

Transmission electron microscope (TEM) specimens are today routinely prepared using focussed ion beam (FIB) instruments. Specifically, the lift-out method has become an increasingly popular technique and involves removing thin cross-sections from site-specific locations and transferring them to a TEM grid. This lift-out process can either be performed ex situ or in situ. The latter is mainly carried out on combined dual-beam FIB and scanning electron microscope (SEM) systems whereas conventional single-beam instruments often are limited to the traditional ex situ method. It is nevertheless desirable to enhance the capabilities of existing single-beam instruments to allow for in situ lift-out preparation to be performed since this technique offers a number of advantages over the older ex situ method. A single-beam FIB instrument was therefore modified to incorporate an in situ micromanipulator fitted with a tungsten needle, which can be attached to a cut-out FIB section using ion beam ...

British Library Electronic Table of Contents (United Kingdom)

A general approach has been designed to synthesize some mononuclear and binuclear cyclometalated platinum(II) complexes, containing aromatic N-donor ligands with the presence of one Cl- trans to carbon. In this way, cyclometalated platinum(II) complex [Pt(C^N)Cl(dmso)], 1, C^N = N(1),C(2prime)-chelated, deprotonated 2-phenylpyridine and dmso = dimethylsulfoxide, was used as a precursor to react with imidazole derivatives (1-methylimidazole, 2a, imidazole, 2b,), monodentate pyridine derivatives (4-methylpyridine, 2c, pyridine, 2d,) and bidentate pyridine derivative (4,4prime-bipyridine, 3 and 4,). Synthesized complexes were fully characterized by using multinuclear NMR spectroscopy (1H, 13C{1H} and 195Pt), correlation NMR spectroscopy (1H-1H COSY, 13C{1H}-1H Heteronuclear Multiple Quantum C...

Energy Technology Data Exchange (ETDEWEB)

The radiation reduction of bis(1-ethylimidazole)tartratoplatinum(II) (EITPt(II)) complexes in methanol-water solution have been examined. The yields of Pt(I) depend on the presence of O{sub 2} in solutions as well as the dose applied. The rate constants of e{sub s}{sup -} scavenging by EITPt(II) and cis(diammine-1,1-cyclobutanedicarboxylato) platinum(II) (CBDCAPt(II)) have been determined by pulse radiolysis to be equal to 5.4 x 10{sup 9} and 6.4 x 10{sup 9} M{sup -1} s{sup -1}, respectively. The efficiencies of e{sub t}{sup -} scavenging by EITPt(II) and the rate of e{sub t}{sup -} photobleaching have also been determined in LiCl : H{sub 2}O : CH{sub 3}OH and MgCl{sub 2} : H{sub 2}O : CH{sub 3}OH glasses, respectively. (author).

International Nuclear Information System (INIS)

Proton exchange membrane fuel cells (PEMFCs) are attractive because of their high conversion efficiency, low pollution, lightweight, and high power density. A major area of challenges is the design and engineering of active, robust, and low-cost electrocatalysts. This report discusses recent findings of our investigations of the design and nano-engineering of platinum-vanadium-iron catalysts for use in PEMFC. The membrane electrode assembly was prepared using nano-engineered PtVFe nanoparticles with controlled composition and size supported on carbon as cathode electrocatalysts. The electrocatalytic activity and stability of the catalysts have been characterized by both rotating disk electrode and membrane electrode assembly measurements. The trimetallic catalysts have been shown to exhibit excellent electrocatalytic performance in PEMFC in comparison with commercial platinum catalysts. The results exhibited a good agreement between obtained ...

Energy Technology Data Exchange (ETDEWEB)

A detailed kinetic study of the epoxidation of 1-octene with hydrogen peroxide catalyzed by Pt(II) complexes is reported. The two systems analyzed were (diphoe)Pt(CF/sub 3/)(OH)/1-octene/H/sub 2/O/sub 2//THF and ((diphoe)Pt(CF/sub 3/)(CH/sub 2/Cl/sub 2/))BF/sub 4//1-octene/H/sub 2/O/sub 2//H/sub 2/O/CH/sub 2/Cl/sub 2/. Rate data were determined with GLC from epoxide formed vs time plots. Evidence for many of the organometallic intermediates and the individual steps involved was gained from IR studies, /sup 19/F NMR studies, and especially designed experiments including studies of the acidity effect. In both cases the kinetic analysis suggests a mechanism in which the actual oxidant is a PtOOH species that interacts with a Pt-olefin complex in the oxygen-transfer step (second-order dependence on platinum). 29 references, 12 figures, 3 tables.

Energy Technology Data Exchange (ETDEWEB)

An estimate of the tritium dose to the public in the vicinity of the heavy water research reactor facility at AECL-Chalk River Laboratories, Ontario, Canada, has largely been accomplished from analyses on regularly-collected samples of air, precipitation, drinking water and foodstuffs (pasture, fruit, vegetables and milk) and environmental dose models. To increase the confidence with which public doses are calculated, tritium doses were estimated directly from the ratio of tritiated species in urine samples from members of the general public. Single cumulative 24 h urine samples from a few adults living in the vicinity of the heavy-water research reactor facility at Chalk River Laboratories, Canada were collected and analysed for tritiated water and organically bound tritium. The participants were from Ottawa (200 km east), Deep River (10 km west) and Chalk River Laboratories. Tritiated water concentrations in urine ranged from 6.5 Bq.l{sup -1} for the Ottawa resident to 15.9 Bq.l{sup ...

Energy Technology Data Exchange (ETDEWEB)

The general usefulness of neutron activation analysis (NAA) for samples containing the platinum group elements and Au, either as major or trace constituents, is discussed. Charged particle activation is shown to be a viable or complementary alternative. Proton (6-10 MeV) and alpha particle (9-15 MeV) beams, produced in a Tandem van de Graaff accelerator, have been established to be the most effective choice. By taking advantage of the Coulomb barrier effect and the fact that many charged particle induced reactions have relatively large threshold values, the same instrumental technique can be applied, with minor modifications, to a wide range of materials.

CERN Document Server

The dynamics of spin-lattice relaxation (slr) of metal-organic Pt(II) compounds is studied. Often, such systems are characterized by pronounced zero-field splittings (zfs) of the lowest-lying triplets. Previous expressions for the Orbach slr process do not allow to treat such splitting patterns properly. We discuss the behavior of a modified Orbach expression for a model system and present results of a fit of the temperature dependence of the spin-lattice relaxation rate of Pt(2-thpy)$_2$ based on the modified expression.

Energy Technology Data Exchange (ETDEWEB)

Polymer electrolyte membrane fuel cells (PEMFCs) are energy conversion devices that produce electricity from a supply of fuel, such as hydrogen. One of the major challenges in achieving efficient energy conversion is the development of cost-effective materials that can act as electrocatalysts for PEMFCs. In this letter, we demonstrate that, instead of conventional noble metals, such as platinum, chromium nitride nanocrystals of fcc structure exhibit attractive catalytic activity for PEMFCs. Device testing indicates good stability of nitride nanocrystals in low temperature fuel cell operational environment.

International Nuclear Information System (INIS)

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

International Nuclear Information System (INIS)

COMPLIS is an experimental facility designed to carry out spectroscopic studies on radioisotopes produced by disintegration of elements available at CERN's Booster-ISOLDE on-line isotope separator. During recent series of experimental runs, hyperfine structure measurements have yielded information on nuclear moments and deformations of platinum and iridium isotopes. For the first time, population by #alpha#-decay from Hg was exploited to investigate "1"7"8"-"1"8"1Pt--the most neutron-deficient Pt isotopes yet studied. Successful measurements have recently been carried out on "1"8"2"-"1"8"9Ir.

Energy Technology Data Exchange (ETDEWEB)

Cationic five-coordinate [Pt(3-R{sup 1}-4-R{sup 2}-C{sub 6}H{sub 3})(MeCN) (6-Me-py-2-CH=NPh)(C{sub 2}H{sub 4})]{sup +} complexes (R{sup 1}, R{sup 2} = H, Me, OMe) undergo an unexpected rearrangement at 0{degrees}C in chloroform solution, affording, after treatment with aqueous LiCl, the neutral four-coordinate species [Pt(2-Et-4-R{sup 1}-5-R{sup 2}-C{sub 6}H{sub 2})Cl(6-Me-py-1-CH=NPh)]. Pt-C{sub aryl} bond breaking and making is involved in the whole process, resulting in a 1,2-shift of the platinum atom to an adjacent position of the benzene ring. The same compound is obtained, together with products deriving from a typical insertion, when an equimolar amount of ethylene is added to a chloroform solution of [Pt(3-R{sub 1}-4-R{sup 2}-C{sub 6}H{sub 3})(MeCN)(6-Me-py-2-CH=NPh)]{sup +} at 0{degrees}C. When higher ethylene/Pt ratios are used, only five-coordinate [Pt(3-R{sup 1}-4-R{sup 2}-C{sub 6}H{sub 3}CH{sub 2}CH{sub 2})Cl(6-Me-py-2-CH{double_bond}NPh)(C{sub ...

Energy Technology Data Exchange (ETDEWEB)

Lithium (Li) plating-stripping reaction properties at the lithium phosphorus oxynitride glass electrolyte (LiPON)/copper thin film (Cu) interface is improved by the insertion of nano-thickness platinum (Pt) layer at the interface. The LiPON films are formed on mirror-polished lithium-ion conductive solid electrolyte sheets, and current collector thin films of Li, Cu-Pt multi layer, and Cu are formed on the LiPON films. The plating-stripping reactions at the LiPON/current collector films interface are carried out by galvanostatic and potential sweep measurements. Galvanostatic measurements reveal that Pt layer insertion reduces the overvoltage of the reaction and improves its coulomb efficiency. Also, cyclic voltammetry measurement suggests formation of Li-Pt alloys at higher voltages than 0 V (vs. Li/Li{sup +}) during the lithium plating process. Scanning electron microscopy observation clarifies that platinum insertion moderate non-uniform ...

International Nuclear Information System (INIS)

Grid connected photovoltaic systems is one of the most promising applications of photovoltaic systems. These systems are employed in applications where utility service is already available. In this case, there is no need for battery storage because grid power may be used to supplement photovoltaic systems (PV) when the load exceeds available PV generation. The load receives electricity from both the photovoltaic array and the utility grid. In this system, the load is the total electrical energy consumption. The main objective of the present work is to optimize the electrical load pattern in Kuwait using grid connected PV systems. In this situation, the electric load demand can be satisfied from both the photovoltaic array and the utility grid. The performance of grid connected photovoltaic systems in the Kuwait climate has been evaluated. It was found that the peak ...

Energy Technology Data Exchange (ETDEWEB)

An effect of load conditions on Corrosion Fatigue Crack Propagation (CFCP) behavior of High Performance Steel (HPS) under seawater environment was investigated. Fatigue crack propagation tests under several load conditions including stress ratio and load frequency were conducted in air and 3.5% NaCl solution environments. Corrosion/fatigue ratio factor, C/F, particularly was defined to analyze the effect of such conditions. As shown in the results, a decrease of load ratio and frequency leads to an increase of C/F factor. Consequently, under lower loading frequency and stress ratio, the seawater condition causes much more significant effect on CFCP behavior of HPS.

International Nuclear Information System (INIS)

Research highlights: #-># The building occupancy affecting the cooling load prediction is studied. #-># PENN model is adopted in this study for predicting the building cooling load. #-># Statistical approach is adopted to result a less prejudice prediction performance. #-># Results show that occupancy data can significantly improve the prediction. -- Abstract: Building cooling load prediction is one of the key factors in the success of energy-saving measures. Many computational models available in the industry today have been developed from either forward or inverse modeling approaches. However, most of these models require extensive computer resources and involve lengthy computation. This paper discusses the use of data-driven intelligent approaches, a probabilistic entropy-based neural (PENN) model to predict the cooling load of a building. Although it is common knowledge that the presence ...

UK PubMed Central (United Kingdom)

VACUTAINER PPT plasma preparation tubes were evaluated to determine the effects of various handling and shipping conditions on plasma human immunodeficiency virus (HIV) load determinations. Plasmas...Full Text Available

UK PubMed Central (United Kingdom)

There has been great interest in understanding the methods by which collagen-based load-bearing tissue is constructed, grown and maintained in vertebrate animals. To date, the responsibility for this...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This document presented the results of a full-scale pile load tests conducted on helix pile foundations supporting power transmission towers in northern Manitoba. The site conditions were described along with pile installation and the performance of the foundations. The pile load tests were carried out in 2 different soil conditions, notably soft to firm clays and stiff high plastic clays with silt varves. The performance of the helix pile foundations were examined under axial compressive and axial tension (uplift) loading conditions. The results of the compressive load tests were presented in the form of load settlement curves while the results of the uplift load tests were presented in the form of load displacement curves. Both types of load tests in soft or stiff clays showed the suitability of helical pile ...

UK PubMed Central (United Kingdom)

The association of dietary glycaemic index (GI) and glycaemic load (GL) with cardiovascular diseases has been examined in several populations with varying results. We tested the hypothesis that...Full Text Available

International Science & Technology Center (ISTC)

Thermodynamic Stable Metal Compositions for Improvement of an Operational Safety of Constructional Materials under Conditions of Multifactor Loadings of an Aggressive Environment

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

Adjusting generation to demand (load following) is compared with practical experience. The importance of pumped storage plants is emphasized.

Science.gov (United States)

... populations ..... 63 34 Vertebral ultimate compressive strength for various populations ..... 64 35 ...

International Nuclear Information System (INIS)

Cyclic strength of #alpha#+#beta#-titanium alloy BT3-1 is studied under load frequencies of 33 and 300 Hz. The increase in the cyclic strength with growing frequency is caused by formation of FCC interphase layers of titanium hydrides. Their formation is one of possible ways of raising the fatigue strength of titanium alloys. Peculiarities of FCC interlayer formation in #alpha#+#beta# phases under loading frequency variation are revealed.

British Library Electronic Table of Contents (United Kingdom)

Background, aim, and scope Semi-trailers with load boxes are the most important mode of grain transport by land in the world. Load boxes can be produced with different materials such as: wood, steel, and synthetic material. They are responsible for effectiveness retention and quality of grains during the transport. Among the main aspects to be considered and valued when selecting materials for load boxes are the final mass of the semi-trailer, loss of grains, and mechanical properties. Environmental performance is another important aspect to be taken into account for developing and selecting new materials in this kind of application. This study presents a comparative environmental evaluation of load boxes built from two different materials (a wood panel and a three-layer synthetic (TLS) pa...

Energy Technology Data Exchange (ETDEWEB)

This paper introduces the summary of design guideline (draft) for the limit state design method for foundation structures, and examples of calculations on pile foundations. The limit states were set using the load to transformation curves, and the limit state No. 3 in particular assumed a large earthquake, a state that a foundation is fatally damaged because of rarely acting loads that lead to generation of displacement and loss of stability and functions. Ground survey coefficient, ground resistance coefficient, and ground property coefficient were defined especially as the safety coefficients. With respect to the displacement in the limit state No. 3, a restriction value was set for the plasticity of the foundation. Loads were given considerations of combination of permanent load, variation load, and accidental load, each having been set with a ...

Energy Technology Data Exchange (ETDEWEB)

Taiheiyo coal deashed using acid treatment and loaded with potassium or calcium was hydro-cracked under gaseous phase to discuss effects of these metals on liquefaction reaction. In addition, the loaded coal was added with red mud catalyst to examine effects of the addition. The loaded potassium has a softening power, and particularly the potassium adsorbed into surface and micropores in the coal decomposes selectively HI-BS and BI-PS and generates gas and HS. On the other hand, potassium deposited on coal surface promotes direct gas production from the coal. Irrespective of its loading modes, calcium has a catalytic nature to produce HI-BS selectively. Calcium also acts to impede decomposition of HI-BS into HS. Adding red mud catalyst to potassium loaded coal increases the inversion rate and the liquefaction yield, and most of the increase is accounted for by HI -BS, and BI-PS. ...

British Library Electronic Table of Contents (United Kingdom)

Despite advances in polymer and drug technology, the underlying stent platform remains a key determinant of clinical outcome. A clear understanding of stent design and the differences between various stent platforms are of increasing importance for the interventional cardiologist. Reduction in stent strut thickness has been associated with improved stent deliverability, improved procedural outcome, and lower rates of subsequent restenosis. Newer-generation 316L-SS stent designs have enabled reduced strut thickness while retaining radial strength and minimizing recoil, but with significant loss of radiopacity, leading to reduced visibility. Cobalt chromium alloys have enabled a reduction in stent strut thickness to around 80?90 mm while retaining modest radiopacity, but due to higher elasti...

International Nuclear Information System (INIS)

The synthesis of 3-O-sulphamoyl derivatives of 1,2:5,6-di-O-isopropylidene-#alpha#-D-glucofuranose, 1,2-O-isopropylidene-#alpha#-D-glucofuranose, and 5,6-di-O-acetyl-1,2-O-isopropylidene-#alpha#-D-glucofuranose is described. A study of the reactions of carbohydrate chlorosulphates with azide has demonstrated the relative case with which certain chlorosulphonyloxy groups may be converted into azidosulphates. These azidosulphates could have potential synthetic value if a facile method for their conversion into sulphamoyl (aminosulphate) derivatives were available, since some sulphamoyl carbohydrates have been shown to possess antibiotic and antitrypanosomal activity. This report deals with the application of sodium borohydride and platinum oxide-hydrogen to the reduction of some 3-O-azidosulphate glucofuranose derivatives. "1H-n.m.r. spectra and infrared spectra were used.

Energy Technology Data Exchange (ETDEWEB)

Heavy ion irradiation on tantalum metal target with 57 MeV {sup 11}B{sup 4+} leads to the production of no-carrier-added radioisotopes of platinum, {sup 187,188}Pt and iridium, {sup 187,188}Ir in the matrix, which have been effectively separated from the bulk target and from each other with suitable anion exchangers employing liquid-liquid extraction (LLX). Also {sup 188,189}Pt and {sup 188,189}Ir radionuclides have been produced, from their short-lived precursors {sup 188,189}Au, in {sup 12}C{sup 6+} irradiated tantalum matrix. Gamma-spectroscopy has been utilised to determine the production, extent of separation and purity of the radiotracers at different stages of the experiment. (orig.)

International Nuclear Information System (INIS)

This pilot project was carried out for the purpose of testing methods for active biological monitoring. It covered a period of three years (until September 1994), including two years of exposure. The measurements served to determine pollutant levels in plants used as animal fodder and dust-borne heavy metal concentrations in different sites and, on this basis, to obtain indirect information on human exposure. Among others, the pilot project investigated the suitability of Italian rye-grass as a biological indicator for aluminium, arsenic, cadmium, cobalt, chromium, copper, iron, mercury, magnesium, manganese, nickel, lead, platinum, antimony, titanium, and zinc. (orig./GL).

Energy Technology Data Exchange (ETDEWEB)

This illustrated final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project concerning a new, highly active oxygen reduction electrode for PEM fuel cell and zinc/air battery applications. The goal of this project was, according to the authors, to increase the efficiency of the oxygen reduction reaction by lowering the activation polarisation through the right choice of catalyst and by lowering the concentration polarisation. In this work, carbon nanotubes are used as support material. The use of these nanotubes grown on perovskites is discussed. Theoretical considerations regarding activation polarisation are discussed and alternatives to the use of platinum are examined. The results of experiments carried out are presented in graphical and tabular form. The paper is completed with a comprehensive list of references.

Energy Technology Data Exchange (ETDEWEB)

Purpose: Antitumor activity of the dichloroplatinum(II)-histamine complexes labeled with I-125 or I-131 was investigated in a transplantable murine adenocarcinoma (MA) model. Methods: The tumor model was obtained in C3H/W female mice after subcutaneous inoculation of the tumor cells derived from the mice bearing a mammary tumor of spontaneous origin. Antitumor activities of the platinum-histamine complexes were investigated in three independent experiments, which differed in applied doses of preparations (PtCl{sub 2}Hist, PtCl{sub 2}[{sup 125}I]Hist, PtCl{sub 2}[{sup 131}I]Hist, PtCl{sub 2}Hist/PtCl{sub 2}[{sup 125}I]Hist and PtCl{sub 2}Hist/PtCl{sub 2}[{sup 131}I]Hist), treatment schedules as well as stages of the disease progress in the animals used. Experiment 1 included long-term, multidose treatment with low single doses (treatment duration 31-32 days; 8-10 doses of ca. 0.25{center_dot}MTD{sub Pt} each). Experiment 2 included short-term, multidose treatment ...

Energy Technology Data Exchange (ETDEWEB)

The palladium(II) and platinum(II)complexes(where, (M(L){sub 2}X{sub 2}), M=Pd(II), Pt(II); L=isoxazole (isox), 3, 5-dimethylisoxazole(3, 5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Ph-isox), and 4-amino-3, 5-di-methylisoxazole (4-ADI); X=Cl, Br) with isoxazole and its derivatives were investigated on antitumor activity by MM2 and EHMO calculation. Because for all the complexes the {sigma}MO energy level (E{sub {sigma}}{sub (M-X)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of halogen atom is less than {sigma}MO energy level E{sub {sigma}}{sub (M-N)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of N atom, without exception. And judging, from the lower E{sub {sigma}}{sub (M-X)} value in trans, the bonding strength was found to be weaker in trans isomer than in cis. For the Pd(II) and Pt(II) complexes which have planar ligands, it was shown that for all the complexes dissociation of ...

Energy Technology Data Exchange (ETDEWEB)

This report deals with the preliminary results of trials in the DATECA project with stage I, II and III patients with non-seminomatous germ cell tumours. Stage 1 patients were randomized between infradiaphragmatic irradiation and observation. No significant difference in recurrence rates has been observed as yet. Eighteen of 95 patients had recurrence with a median time to relapse of 3 months. Fifteen patients achieved complete remission after treatment by combination chemotherapy while 3 patients are still undergoing treatment. Stage II patients received 6 series of cis-platinum, bleomycin, and vinblastine. The patients were initially randomized to receive chemotherapy alone versus chemotherapy plus irradiation. Irradiation led to increased toxicity and decreased doses of the antineoplastic drugs. Fifty-one patients were studied. The overall complete remission rate was 89 per cent including 7 patients who achieved complete remission after secondary surgery. Three ...

International Nuclear Information System (INIS)

Quantitative I-131 labelled Peanut lectin (I-131-PNA) renal clearance was determined in dogs before and after a 5 day single cycle cis-platinum chemotherapy regimen (0.5mg/Kg/day). Results were statistically compared with E.R.P.F. (I-131-Hippuran), G.F.R. (Tc-99m-DTPA), and serum biochemistry and correlated with histopathology. I-131-PNA clearance was significantly reduced in all dogs 5 days after cessation of cis-platinum treatment (mean #DELTA#S% = 71.3%) and similar reductions in the gamma camera derived renogram peak were demonstrated (mean #DELTA#S% = 65.8%). E.R.P.F. was noted to drop by a minor degree (mean #DELTA#S% = 20.9%) post treatment. G.F.R. was diminished (mean #DELTA#S% = 46.6%) and serum creatinine elevated (mean #DELTA#S% = 42.7%) in all dogs compared to their pretreatment values. Histopathology demonstrated variable degrees of tubular toxicity ranging from mild to severe. The degree of change of the I-131-PNA values was ...

International Nuclear Information System (INIS)

Two osmium porphyrin complexes, Os(OEP)L_2 [OEP = octaethylporphin, L = py(pyridine) or NO], and PtOEP were investigated by picosecond laser spectroscopy with use of a double-beam, mode-locked Nd:glass system delivering 6-ps (fwhm) pulses at 527 nm with 1-2mJ/pulse. Time-resolved excited-state spectra were recorded from the time of photoexcitation to 5 ns after photoexcitation. The initial excited state, S_1, decayed in less than or equal to9 ps for the two osmium complexes and in less than or equal to15 ps for the platinum porphyrin. A second excited state, T_1, lived for 1, 9, and >50 ns respectively for Os(OEP)(py)_2, Os(OEP)(NO)_2, and PtOEP. The #DELTA#A spectra of the T_1 states of the osmium complexes were similar to those of previously reported (d/sub #pi#/,#pi#*) states for Os(OEP)(py)_2 and (#pi#,#pi#*) states for Os(OEP)(NO)_2. This finding supports prior assignments of these states on the basis of expected axial and equatorial back-bonding of the ...

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a three year DOE funded project titled ''A real-time coal content/ore grade (C{sub 2}OG) sensor''. The sensor, which is based on hyperspectral imaging technology, was designed to give a machine vision assay of ore or coal. Sensors were designed and built at Resonon, Inc., and then deployed at the Stillwater Mining Company core room in southcentral Montana for analyzing platinum/palladium ore and at the Montana Tech Spectroscopy Lab for analyzing coal and other materials. The Stillwater sensor imaged 91' of core and analyzed this data for surface sulfides which are considered to be pathfinder minerals for platinum/palladium at this mine. Our results indicate that the sensor could deliver a relative ore grade provided tool markings and iron oxidation were kept to a minimum. Coal, talc, and titanium sponge samples were also imaged and analyzed for content and grade with ...

Energy Technology Data Exchange (ETDEWEB)

A 25m wind turbine blade was tested to failure when subjected to a flapwise load. With the test setup, it was possible to test the blade to failure at three diffe-rent locations. The objective of these tests is to learn about how a wind turbine blade fails when exposed to a large flapwise load and how failures propagate. The report shows also results from ultra sonic scan of the surface of the blade and it is seen to be very useful for the detection of defects, especially in the layer between the skin laminate and the load carrying main spar. Acoustic emission was successfully used as sensor for the detection of damages in the blade during the test. The report contains measurements of the total deflection of the blade, the local deflection of the skin and the load carrying main spar and also measurement of strain all as a function of the applied load and up to failure of the blade. ...

Energy Technology Data Exchange (ETDEWEB)

The thermal contact resistance between balls and inner and outer rings of thermally steady space-use deep groove ball bearings was studied experimentally to verify the validity of the previously proposed calculation method for the resistance. The 440C stainless steel single row bearing was used for measuring its steady state temperature distributions in a vacuum environment under axial, radial and combined load conditions. As a result, the experimental results of the resistance well agreed with calculated ones under each load condition resulting in the sufficient validity at nearly the same surface roughness. It was necessary to apply a static equivalent radial load to calculation under the combined load that a contact angle is larger than the angle of resultant force dependent on both load components. In experiments under only radial load, measurement of outer ...

Energy Technology Data Exchange (ETDEWEB)

An experimental apparatus has been built that allows direct measurement of the oil film thickness in a bearing that is subjected to dynamic loads and shaft speeds representative of those occurring in automotive engine connecting rod, big-end bearings. Dynamic motion of the shaft, relative to the bearing, is measured as a function of shaft rotational angle, using non-contact, eddy-current probes. A computer based data acquisition system is used to measure, record, and analyze the journal position in the bearing. The test bearing is 63.5 mm in diameter by 25.4 mm long, and is loaded using a servo-hydraulic actuator rated at 98.3 kN. The journal has an operating speed of 500 to 3800 rpm. The actuator is controlled by a computer-generated waveform that can duplicate load profiles developed by various engines operating at a wide range of conditions. Measurements taken with the shaft statically loaded show ...

Energy Technology Data Exchange (ETDEWEB)

This paper presents a systematic approach to the automatic determination of the evolution of the rigid-plastic structural response caused by a proportional or single parameter pressure loading which varies with time in a monotonic non decreasing fashion. The frame structure is envisaged as a network, and the fundamental vectorial conditions characterising its behaviour at any instant of time are combined in a consistent manner. By considering the level of the pressure loading to be a single load parameter ranging monotonically from zero to infinity, the structural governing system may be regarded as a parametric linear complementary problem. (author). 13 refs., 2 figs.

Science.gov (United States)

ABS>A horizontal steam generator design for the SM-2 was lysis to determine the per formance of such a steam generator under steady state operating conditions and during load transients, The configuration for this design is a two- drum unit consisting of a heat exchanger unit and separator drum interconnected by integral riser and downcomer. An analog computer was used to analyze the steam generator behavior Wring load transients. The effect of various design changes on the response of the steam generator to step chages in load was determined. The horizontal steam generator design was compared to the existing vertical steam generator design for weight, size, price, and performance. (auth)

Energy Technology Data Exchange (ETDEWEB)

Long crack fatigue threshold ({delta} K{sub th}) and crack closure behaviour of two thermomechanically processed microalloyed (MA) ferrite-pearlite steels are reported. {delta} K{sub th} and crack closure were measured using a dynamic compliance measurement technique. Crack closure was observed at low load ratios (R < 0.5) and the fatigue thresholds decreased with increasing load ratio. In both steels, the closure-free intrinsic threshold ({delta} K{sub eff} {sub th}) was found to be independent of the load ratio. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The effect of additives on the grafting of a monomer, butylmethacrylate (BA), into simul (a soft wood) has been studied using {sup 60}Co source at 3 Mrad. The enhancement of polymer loading (grafting) by the addition of minute amounts (1%) of oligomers and of polyfunctional monomers into simul + BA system has been further increased in the presence of acid and urea. The synergistic polymer loading yields by acid addition cause substantial decrease of tensile strength values of wood-plastic composite; but urea increases both polymer loading and tensile strength values synergistically in these systems. (author).

Energy Technology Data Exchange (ETDEWEB)

An aspiration cover is proposed for the site of loading a belt conveyer including a housing arranged above the belt conveyer in whose cover there is an aspiration sleeve and a discharge chute from the upper wall and a guide having a cushioning plate on the lower end. It is distinguished by the fact that in order to improve the effectiveness of removing dust by decreasing the volume of aspirated air, the cover between the aspiration sleeve and the upper wall of the loading chute is convex in the inside of the housing and has a smooth connection to the upper wall of the discharge chute turned towards the cushioning plate.

Energy Technology Data Exchange (ETDEWEB)

The problem of pile groups subjected to lateral loads is of interest particularly in offshore and coastal regions. An understanding of pile-soil interaction is essential in designing such pile foundations. In this paper, a simplified finite element analysis in conjunction with Yegian and Wright approach has been presented to study the behavior of pile groups under lateral loads. The pile is treated as a shear beam and the soil media is assumed to be linear elastic. The results of the analysis are used to estimate: (1) Lateral Group Efficiency and (2) Extent of stress influence around the pile. The results obtained from the theoretical predictions are found to be reasonably in good agreement with the published literature.

Science.gov (United States)

... E. 3. Krasnicki, Lord Corporation, Erie, PA EFFECT OF AIR CAVITY ON THE VIBRATION ANALYSIS OF LOADED DRUMS S. Do. ...

International Nuclear Information System (INIS)

In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe"3"+ and Fe"2"+) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.

International Nuclear Information System (INIS)

Wood-polymer composites (WPC) have been prepared of pinewood with different monomers using Gamma radiation: acrylamide, butyl acrylate, butyl methacrylate, styrene, acrylonitrile, and polyester. The polymer loading was determined as a function of monomer concentration and absorbed dose. The data show that polymer loading increases by increasing the monomer concentration. In two cases, BMA and polyester, the polymer loading decreases at high concentrations. This can be explained by the increase of the viscosity. Thus the diffusion of the compound into bulk would be slower. The absorbed dose seems to play a positive role in enhancing the polymer loading by increasing the dose. The mechanical properties, tensile and compression strength, have been improved in the most cases for all monomer concentrations or absorbed doses. Using polyester there was no improvement in the mechanical properties, and using ...

Science.gov (United States)

ratio 2 with NACA 0005-63 thickness distribution in streamwise planes, and twisted and cambered for a trapezoidal span load distribution has ...

Energy Technology Data Exchange (ETDEWEB)

A method for determining the rational capacity of the shield supports under various geological conditions is proposed. Based on the instrumentation of the pressure histories of the shield legs in eight mines, the relation between the final load or the increment of support resistance in a mining cycle and the setting load is established. The relation is represented by a mathematical equation with characteristic constants. Those constants are related to the physical properties of the immediate and main roof strata. Nomographs were constructed for determining the constants under various geological conditions. The paper discusses the principles and step-by-step procedures for determining the rational setting and yield loads for all the shield supports employed in the eight mines. The predicted values are then compared with the actual ones used by the operators. 7 refs., 6 figs., 4 tabs.

Energy Technology Data Exchange (ETDEWEB)

The load-following operation of nuclear power plants will become inevitable due to the increased nuclear share in the total electricity generation. As a groundwork for the load-following capability of the Korean next generation PWRs, the state-of-the-art has been reviewed. The core control principles and methods are the main subject in this review as well as the impact of load-following operations on the fuel performance and on the mechanical integrity of components. To begin with, it was described what the load-following operation is and in what view point the technology should be reviewed. Afterwards the load-following method, performance and problems in domestic 900 MWe class PWRs were discussed, and domestic R and D works were summarized. Foreign technologies were also reviewed. They include Mode G and Mode X of Foratom, D and L bank method of KWU, the method using PSCEA of ...

Energy Technology Data Exchange (ETDEWEB)

0pen ended piles develop internal frictional resistance between the internal soil plug end the pile wall during axial loading. Current pipe pile design practice assumes that the ultimate internal skin friction is of the same order of magnitude as the outer skin friction. This paper describes a series of laboratory pile load tests on instrumented model pipe piles, designed to investigate the development of plug stresses and skin friction along the plug length during pile loading. The piles contain sand columns of various relative densities and of different heights. The soil plugs are loaded to failure under fully drained conditions. The test data indicate that internal skin friction in sand can be substantially higher than assumed in conventional design practice. This finding could lead to significant economical savings on future pipe pile foundations in sand.

UK PubMed Central (United Kingdom)

The fatigue and fracture behavior of hard tissues are topics of considerable interest today. This special group of organic materials comprises the highly mineralized and load-bearing tissues...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Heat transfer through the gas diffusion layer (GDL) is a key process in the design and operation of a PEM fuel cell. The analysis of this process requires the determination of the effective thermal conductivity as well as the thermal contact resistance between the GDL and adjacent surfaces/layers. The Part 1 companion paper describes an experimental procedure and a test bed devised to allow separation of the effective thermal conductivity and thermal contact resistance, and presents measurements under a range of static compressive loads. In practice, during operation of a fuel cell stack, the compressive load on the GDL changes. In the present study, experiments are performed on Toray carbon papers with 78% porosity and 5% PTFE under a cyclic compressive load. Results show a significant hy...

Science.gov (United States)

;Table of Contents: Legal authority; Summary of proposed regulations; Industry definition and waste streams; Industry description; Data and information gathering; Selection of pollutant parameters; Drilling wastes-characterization, control, and treatment technologies; Produced water-characterization, control, and treatment technologies; Miscellaneous waste-characterization, control, and treatment technologies; Cost and pollutant loading determination of drilling fluids and drill cuttings; Compliance cost and pollutant load determination of produced water; Compliance cost and pollutant load determination of well treatment, workover, and completion fluids; Cost and pollutant loading determination of deck drainage; Options selection-rationale and total costs; Pretreatment standards; Non-water quality environmental impacts and other factors; Best Management Practices; and Appendices.

British Library Electronic Table of Contents (United Kingdom)

Background Photopolymerizable poly(ethylene glycol) (PEG) hydrogels offer a platform to deliver cells in vivo and support three-dimensional cell culture but should be designed to degrade in sync with neotissue development and endure the physiologic environment. Questions/purposes We asked whether (1) incorporation of degradation into PEG hydrogels facilitates tissue development comprised of essential cartilage macromolecules; (2) with early loading before pericellular matrix formation, the duration of load affects matrix production; and (3) dynamic loading in general influences macroscopic tissue development. Methods Primary bovine chondrocytes were encapsulated in hydrogels (n?=?3 for each condition). The independent variables were hydrogel degradation (nondegrading PEG and degrading olig...

British Library Electronic Table of Contents (United Kingdom)

Varying load can cause changes in a measured gearbox vibration signal. However, conventional techniques for fault diagnosis are based on the assumption that changes in vibration signal are only caused by deterioration of the gearbox. There is a need to develop a technique to provide accurate state indicator of gearbox under fluctuating load conditions. This paper presents an approach to gear fault diagnosis based on complex Morlet continuous wavelet transform under this condition. Gear motion residual signal, which represents the departure of time synchronously averaged signal from the average tooth-meshing vibration, is analyzed as source data due to its lower sensitiveness to the alternating load condition. A fault growth parameter based on the amplitude of wavelet transform is proposed ...

Science.gov (United States)

of Aspect Ratio 2 With NACA 0005-63 Thickness Distribution,. Cambered and Twisted for a Trapezoidal Span Load Distribution. NACA RM A50K27a,, ...

International Nuclear Information System (INIS)

The experimental superconducting magnetic system of 0.5 MJ energy storage is described. The step variation of the winding inductance provides a control by the discharge current at the energy output on a high-ohmic load. The voltage on a load is 45 kV at the current 1100 A under the controllable discharge conditions. The energy transfer coefficient constitutes 0,76 under the maximum-to-minimal current ratio equal to 1.3. 7 refs., 3 figs., 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

Pile foundations are extensively used to support off-shore and on-shore structures. Under dynamic loads, the behavior of single pile is well understood. However the soil-pile-soil interaction studies are confusing, on which account the analyses do not necessarily predict response of the systems which may match satisfactorily with the performances. In this paper, the nature of dynamic loads is described, and solutions for soil-pile and pile-soil-pile interaction solutions by several authors are presented and a critical evaluation is made.

Energy Technology Data Exchange (ETDEWEB)

These ten chapters present an overview of floating production, storage and offloading (FPSO) vessels, and examines deep water developments; hydrostatic stability; production, storage and offloading systems; the configuration and structure of flexible risers and umbilicals; the structural and global dynamic analysis of flexible riser and umbilicals; verification of FPSO structural integrity; vessel global loading and rigid body response; environmental loading and vessel response; and mooring systems. (UK)

Science.gov (United States)

An analysis of the diagnosis of loading and service dependability of a rail-mounted excavator used in surface lignite mining is described. Wheel power vibrations in electric motor bearings and electric motor input bearings to the gearbox were measured in situ, in horizontal, vertical, and axial directions. The data were analyzed using a mathematical relationship. The results are presented in a loading diagram that shows the deterioration and the acceptable lower bound of machine conditions over time. Work is continuing. 5 refs., 1 fig.

Energy Technology Data Exchange (ETDEWEB)

The data center in this study had a total floor area of 8,580 square feet (ft{sup 2}) with one-foot raised-floors. It was a rack lab with 440 racks, and was located in a 208,240 ft{sup 2} multi-story office building in San Jose, California. Since the data center was used only for testing equipment, it was not configured as a critical facility in terms of electrical and cooling supply. It did not have a dedicated chiller system but served by the main building chiller plant and make-up air system. Additionally, it was served by a single electrical supply with no provision for backup power. The data center operated on a 24 hour per day, year-round cycle, and users had all hour full access to the data center facility. The study found that data center computer load accounted for 23% of the overall building electrical load, while the total power consumption attributable to the data center including allocated cooling load and ...

Energy Technology Data Exchange (ETDEWEB)

Aluminum hydroxide coating thicknesses were measured on fuel elements stored in aluminum canisters in K West Basin using specially developed eddy current probes . The results were used to estimate coating inventories for MCO fuel,loading. Brushing tests successfully demonstrated the ability to remove the coating if deemed necessary prior to MCO loading.

International Nuclear Information System (INIS)

This paper presents actual time/motion data for an oversize truck spent-fuel shipment from its origin, Surry, Virginia to its destination, Idaho National Engineering Laboratory (INEL). These data include the receipt of the empty cask at the reactor, wet-loading the cask, over-the-road or in-transit data, and receipt and dry unloading of the shipping cask at the receiving facility. Occupational doses were recorded at the Surry Power Plant as well as at INEL, and public doses were calculated for the in-transit dose analysis. This shipment was one of a series performed in support of a demonstration and evaluation of dry storage at INEL. The oversized shipment consisted of a TN-8L shipping cask loaded with three 10-yr-old pressurized water reactor assemblies. The total distance traveled was #approx#2800 miles, requiring 62 h including stops. The time required to receive and inspect the empty shipping cask and wet-load and ...

Energy Technology Data Exchange (ETDEWEB)

One of the most loaded parts of a steam generator of VVER 440 MW type are the bolts and thread holes of the primary collector cover sealing set. The strength calculations and tensometric measurings performed during operation proved the high degree of a load on the bolts. The conditions of the stress limitation are not met in some cases according to the pertinent standards. The untightnesses at nickel rings occurred during putting the units of Jaslovske Bohunice and Dukovany nuclear power stations into operation. With regard to improve the reliability, the producer has taken measures to improve the quality of the rings and users have introduced more strict regulations for bolts tightening. Due to these measures the high reliability of the set has been obtained from point of view of the tightness, but substantial reduction of bolts and holes threads loading have not been obtained. Several years operation experience proved ...

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) was designed to test fast-reactor fuels and other nonfuel materials. In its 37 reactor cycles of operations, the FFTF reactor has performed very well and successfully completed all the irradiation testings with an operating efficiency factor as high as 98%. Since FFTF is an experimental reactor, its core loading changed from cycle to cycle. Depending on the number of test assemblies in the core and their location, the core loading can change significantly from an essentially homogeneous core loading to a relatively nonhomogeneous or even highly localized heterogeneous loading. Consequently, the core reload design and initial criticality analyses were required for each operating cycle. The zero power initial critical control rod bank height was predicted before each reactor startup. The initial critical prediction depends on the reactivity conditions at the end of the ...

Energy Technology Data Exchange (ETDEWEB)

Zone modeling permits taking account of the effect of load-relieving air conduction systems in the planning of HVAC plants. Although this only supplies average values for the degree of load and height of the fresh air layer rather than a detailed description of concentration and temperature distributions in the room, it is quite sufficient for the planning of load-relieving air conduction systems. Moreover, the cost of zone modeling in the planning of HVAC plants remains within reasonable limits. Upscale planning, instruments can thus be reserved for more exacting problems. (orig.) [Deutsch] Zonenmodelle erlauben die Wirkung lastmindernder Luftfuehrungen bei der Planung von RLT-Anlagen zu beruecksichtigen. Sie liefern zwar nur Mittelwerte fuer den Belastungsgrad und die Hoehe der Zuluftschicht und keine detaillierte Konzentrations- und Temperaturverteilungen im Raum. Diese Werte reichen jedoch fuer die Planung ...

Energy Technology Data Exchange (ETDEWEB)

The synthesis, characterization, and emission properties of a series of Pt(L{sub 2})(S-S) complexes are reported. The (L{sub 2}) ligands include 4,7-diphenyl-1,10-phenanthroline (Ph{sub 2}phen), 4,4{prime}-dimethyl-2,2{prime}-bipyridine (Me{sub 2}bpy), 1,5-cyclo-octadiene (COD), trimethyl phosphite (P(OMe){sub 3}), and the {alpha}-C-deprotonated form of 2-phenylpyridine (2-phpy). The (S-S) ligands include 1-(tert-butoxycarbonyl)-1-cyanoethylene-2,2-dithiolate (tbcda), 1-(diethoxyphosphinyl)-1-cyanoethylene-2,2-dithiolate (cpdt), cis-1,2-dicarbomethoxyethylene-1,2-dithiolate (met), and N,N-diethyldithio-carbamate (Et{sub 2}dtc). The complexes are readily synthesized by the addition of the dithiolate or thiolate ligand to Pt(L{sub 2})Cl{sub 2} except for Pt(P(OMe){sub 3}){sub 2}(met), which is prepared by the addition of 2 equiv of trimethyl phosphite to Pt(COD)(met).

Energy Technology Data Exchange (ETDEWEB)

The role played by calcium sulfite in the flue gas desulfurization of lime/limestone scrubbers makes it desirable to work out its thermodynamic properties. A thermogravimetric apparatus was used to study the equilibria between calcium sulfite hemihydrate and calcium sulfite anhydrite under different conditions. Efforts were made to analyze the difficulties encountered in the dynamic approach to equilibration after calcium sulfate dihydrate failed in calibration of the apparatus. Finally, the kinetics and thermodynamics for the dissociation of calcium sulfite hemihydrate were examined. The confirmation of Engel-Brewer's correlation between the electronic configuration and crystal structure in metallic systems has long been pursued in this group by studying the Lewis-acid-base interactions. Tantalum-iridium alloys of different compositions were brought into equilibrium with various steam/hydrogen mixtures in the same thermogravimetric setup. Although the kinetics is limited by ...

International Nuclear Information System (INIS)

A semirelativistic two-component extended linear augmented plane-wave k#centre dot#p method is described. In order to ensure a high accuracy of the k#centre dot#p method, it is necessary to include into the radial-basis set, which is used for the augmentation of the plane waves, functions that are neither solutions of the Schrodinger equation nor their energy derivatives. The usual scalar relativistic procedure, which is nonlinear in energy, is not applicable to such basis sets. As an alternative, we suggest an approximation to the Foldy-Wouthuysen Hamiltonian that produces an explicitly Hermitean matrix in the augmented plane wave representation. The technique is applied to the calculation of the full dielectric matrix and optical properties of palladium and platinum metals over the photon energy region up to 100 eV. Special attention is paid to the far ultraviolet absorption by the excitations of semicore Pd 4p and Pt 5p and 4f states. A strong effect of local ...

Energy Technology Data Exchange (ETDEWEB)

In this paper the authors present the first emitter efficiency results for the thin film 40 percent Er-1.5 percent Ho YAG (Yttrium Aluminum Garnet, Y3Al5O12) and 25 percent Ho YAG selective emitter at 1500 K with a platinum substrate. Spectral emittance and emissive power measurements were made (1.2 less than lambda less than 3.2 microns). Emitter efficiency and power density are significantly improved with the addition of multiple rare earth dopants. Predicted efficiency results are presented for an optimized (equal power density in the Er, (4)I[sub 15/2]-(4)I[sub 13/2] at 1.5 microns, and Ho, (5)I[sub 7]-(5)I[sub 8] at 2.0 micron emission bands) Er-Ho YAG thin film selective emitter.

British Library Electronic Table of Contents (United Kingdom)

This study investigates the applicability of n-type TiO2 and p-type NiO on the FTO-glass (Fluorine doped tin oxide, SnO2:F) substrate of the working electrode in a dye-sensitized solar cell (DSSC). The working electrode was designed and fabricated by depositing a film of TiO2/NiO composite particles, which were prepared by mixing the Ni powder with TiO2 particles using dry mixing method, on a FTO-glass substrate using a spin coating process. The working electrode was then immersed in the solution of N-719 (Ruthenium) dye at a temperature of 70degreeC for 6h. Moreover, a thin film of platinum (Pt) was deposited on the FTO-glass substrate of the counter electrode using an E-beam evaporator. Finally, the DSSC was assembled, and the short-circuit photocurrent, the open-circuit photovoltage and...

Energy Technology Data Exchange (ETDEWEB)

Over a 5-year period (1976-1980) 499 patients with non-seminomatous testicular germ cell tumours were included in the Danish Testicular Carcinoma Study (DATECA). The 3-year crude survival for patients in clinical stages I, II and III was 91, 77 and 45 per cent, respectively. In stage I the relapse-free survival for patients given radiation combined with bleomycin and vincristine was significantly higher than that for patients given radiation alone. No difference in the crude survival for patients given radiation combined with bleomycin and vincristine was significantly higher than that for patients given radiation alone. No difference in the crude survival was observed. For stage II patients maintenance chemotherapy following radiation combined with bleomycin and vincristine did not improve relapse-free or crude survival. The survival of patients with non-seminomatous tumours improved significantly during the 5-year period. This improvement was probably due to the introduction of ...

Energy Technology Data Exchange (ETDEWEB)

Langmuir-Blodgett films have been made with 3-n-hexadecylpyrrole and 3-n-octadecylpyrrole monomers and copolymers with unsubstituted pyrrole made by chemical polymerization at the air-water interface on a subphase containing FeCl/sub 3/. Langmuir-Blodgett films consisting of mixtures of stearic acid and alkylsubstituted polythiophenes have also been made as bilayer films. The orientation of single and multilayer films on platinum substrates have been studied by Near Edge X-ray Absorption Fine Structure Spectroscopy which also gives information about charge transfer interactions between the aromatic groups and the metallic substrates. The alkylsubstituted pyrroles form highly ordered two-dimensional structures. FeCl/sub 3/ initiated copolymerization with unsubstituted pyrrole leads to a more disordered system. In the case of polythiophene-stearic acid bilayers, the stearic acid layers are highly ordered. The poly(alkyl thiophene) layers sandwiched between stearic ...

Energy Technology Data Exchange (ETDEWEB)

Carbon supported catalysts can lose their activity over a period of time due to the sintering of the nanometer-sized catalyst particles. The sintering of metal clusters on carbon supports can occur due to the weak interaction between the metal and the support and also due to the corrosion of carbon, especially in fuel cell electrocatalysts. The sintering may be reduced by increasing the interaction between the metal and the support and also by increasing the corrosion resistance of carbon supports. In an effort to mitigate the growth of the nanoparticles, carbon-substituted boron defects were introduced in the carbon lattice. The interaction between the Pt nanoparticles on the pure and boron-doped carbon supports was examined using X-ray photoelectron spectroscopy (XPS). The results indicate that the interaction between the Pt nanoparticles and the boron-doped carbon support was slightly stronger than the interaction between the Pt nanoparticles and the pure carbon support. Also, by ...

International Nuclear Information System (INIS)

In this work we investigate an iron oxide thin film grown with atomic layer deposition for a gas sensor application. The objective is to characterize the structural, chemical, and electrical properties of the film, and to demonstrate its gas-sensitivity. The obtained scanning electron microscopy and atomic force microscopy results indicate that the film has a granular structure and that it has grown mainly on the glass substrate leaving the platinum electrodes uncovered. X-ray diffraction results show that iron oxide is in the #alpha#-Fe_2O_3 (hematite) phase. X-ray photoelectron spectra recorded at elevated temperature imply that the surface iron is mainly in the Fe"3"+ state and that oxygen has two chemical states: one corresponding to the lattice oxygen and the other to adsorbed oxygen species. Electric conductivity has an activation energy of 0.3-0.5 eV and almost Ohmic current-voltage dependency. When exposed to O_2 and CO, a typical n-type response is ...

Energy Technology Data Exchange (ETDEWEB)

Modification of DNA and double-stranded deoxyoligonucleotides with antitumor 1,2-diamino-cyclohexanedinitroplatinum(II) (Pt-dach) complexes was investigated with the aid of physico-chemical methods and chemical probes of nucleic acid conformation. The three Pt-dach complexes were used which differed in isomeric forms of the dach non-leaving ligand-Pt(1R,2R-dach), Pt(1S,2S-dach) and Pt(1R,2S-dach) complexes. The latter complex has lower antitumor activity than the other two Pt-dach complexes. Pt(1R,2S-dach) complex exhibits the slowest kinetics of its binding to DNA and of the conversion of monofunctional binding to bifunctional lesions. The anomalously slow electrophoretic mobility of multimers of the platinated and ligated oligomers suggests that bifunctional binding of Pt-dach complexes to a d(GG) site within double-stranded oligonucleotides induces bending of the oligomer. It is proposed that different effects of the Pt-dach complexes on DNA observed in this work arise mainly from a ...

International Nuclear Information System (INIS)

One of the limiting contributors to the heat load constraint for a long term spent fuel repository is the decay of americium-241. A possible option to reduce the heat load produced by Am-241 is to eliminate it via transmutation in a light water reactor thermal neutron environment, in particular, by taking advantage of the large thermal fission cross section of Am-242 and Am-242m. In this study we employ lattice loading optimization techniques to define the loadings and arrangements of fuel pins with blended americium and uranium oxide in boiling water reactor bundles, specifically, by defining the incineration of pre-loaded americium as an objective function to maximize americium transmutation. Subsequently, the viability of these optimized lattices is tested by assembling them into bundles with Am-spiked fuel pins and by loading these bundles into realistic ...

Science.gov (United States)

A simple approach to controlling the loading percentage and size of zero-valent iron nanoparticles (ZVI NPs) immobilized within polyacrylic acid (PAA)/polyvinyl alcohol (PVA) nanofibrous mats for dye remediation applications is described. A functional "nanoreactor" comprised by electrospun PAA/PVA nanofibers served to bind ferric ions with the carboxyl groups of PAA, prior to their reduction to ZVI NPs. The resulting ZVI NP-immobilized hybrid polymer nanofibers were characterized using scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis. The morphology of the polymer nanofibers exhibited no appreciable change even after eight cycles of ferric ion binding/reduction, and the loading percentage and size of the ZVI NPs were controlled simply by varying the number of ferric ion binding/reduction cycles. Dye remediation experiments revealed that the decoloration effect of ZVI NPs immobilized within the ...

Energy Technology Data Exchange (ETDEWEB)

In general, the tickover speed of a car engine is made sufficiently high, in order to permit an assumed maximum load to be taken from the engine at tickover. This setting of the tickover speed is usually done by stops in the fuel supply. Matching the actual load would lead to lower fuel consumption, without any danger of the engine stalling. The purpose of the invention is to provide a tickover speed controller, so that the tickover speed is adjusted by electronic control equipment, independently of the machine load. The fuel consumption on tickover is reduced and the emission of noxious substances is decreased. The electro-magnetic control of the throttle valve tickover setting is explained by extensive section drawings of the system. This process dispenses with the special tickover cams for a cold start.

Energy Technology Data Exchange (ETDEWEB)

In order to match the output capacity of a geothermal heat pump system (GHPS) with the actual load requirement, research has been conducted in searching for suitable adjusting methods for the GHPS and on the subsequent effects on the working parameters of the GHPS. Firstly, several methods are compared, and it is found that the method of adjusting the compressor's rotation speed using a transducer is better than the others. Secondly, this method is experimented on a small scale GHPS at frequencies ranging from 30 to 55 Hz. The analysis of the experimental data reveals the relationships between the compressor frequency and other important parameters, such as coefficient of performance, heat capacity, cool capacity and compressor power input. The conclusions in the paper can serve as some guidance to the load adjustment of GHPS. (Author)

Energy Technology Data Exchange (ETDEWEB)

In order to perform the structural analysis and stress evaluation for frame structures in the nuclear power plants, ADAMS (AIJ Design Analysis and Modules System) has been developed by the addition of the following functions to the ICES-STRUDL system. 1. Load combination and stress evaluation on the basis of specifications for designing steel structure (issued by the Architecture Institute of Japan). 2. Combination of load and stress evaluation of piping support on the basis of the regulations of Ministry of International Trade and Industry. 3. Addition of other functions than that described above. ADAMS enables structural analysis and stress evaluation exactly and efficiently not only for a large scale structure such as the pipe whip protection structure installed inside of the primary containment vessel for many loading cases but also for a large number of structures such as piping support. This system can be applied not ...

British Library Electronic Table of Contents (United Kingdom)

The paper discusses the aspects of repair and retrofitting technique adopted for a damaged reinforced concrete beam-column joint specimen under cyclic loading. A specimen designed based on Indian Standard specifications with consideration of seismic load but without adopting ductile detailing (NonDuctile) was investigated under reverse cyclic loading. Then, the damaged nonductile specimen was repaired with epoxy mortar and grouted using low viscous polymer, and retrofitted using fiber reinforced plastic (FRP) wrapping in beam and column components and steel plate jacketing in joint region. The experimental results showed that the retrofitted specimen not only regained its original strength and stiffness but also has overcome the deficiencies of nonductile detailing. The present study shows...

Energy Technology Data Exchange (ETDEWEB)

The ability of the /sup 252/Cf-source-driven neutron noise analysis method to measure subcriticality has been demonstrated in a variety of experimental configurations of fissile materials. Calculations for an approximately 4-m-dia configuration of light water reactor (LWR) fuel elements indicated the feasibility of measuring the subcriticality of large, loosely coupled arrays of LWR fuel elements by this same method. These analysis suggested application to the initial loading of both pressurized and boiling water reactors, zero-power testing of reactors (such as shutdown margin measurements after initial loading), light water reactor refueling, and safe storage of LWR spent fuel. In the fuel storage application, direct measurement of subcriticality in the actual fuel storage facilities provides the parameter which is directly related to criticality safety.

Energy Technology Data Exchange (ETDEWEB)

A compression ignition engine was operated on dual fuel principle inducting two commercial fuels and four pure hydrocarbon fuels in turn through intake manifold along with air and injecting diesel fuel to initiate the combustion in the conventional manner. The engine was operated at different loads and at each load the quantity of inducted fuel was increased gradually till knocking set in. The engine performance and exhaust pollutant emissions were recorded at different operating conditions. It was observed that the extent of induction and the effect on the performance depend on the properties of the inducted fuel such as volatility, self ignition temperature and oxidation characteristics. The energy release during the cycle was also observed to shift depending on the properties of inducted fuel. With the dual fuel operation, the thermal efficiency at part loads was observed to be less compared to neat diesel operation. The ...

Energy Technology Data Exchange (ETDEWEB)

The Department of Energy has proposed a rulemaking process to set minimum standards for the efficiency of gas ranges under the National Appliance Energy Conservation Act (NAECA). The Gas Research Institute is compiling information on annual household range gas usage in order to prepare a response to the proposed rulemaking. The data base from the Northern Illinois Gas residential load study provides recent information (data taken from 1990 through 1992) over a comprehensive study of household types and appliance and user characteristics (150 variables noted for each household). The stated Objective is to study the Northern Illinois Gas residential load study data base and to evaluate its effectiveness in predicting annual household gas usage.

Energy Technology Data Exchange (ETDEWEB)

Bags of explosive are loaded rapidly into deep wellbores by suspending a rigid positioning tube partway into the wellbore, and loading the bags into the tube, the bags being prevented from dropping through the open bottom end of the tube by a cord attached to the lowermost bag and secured at the upper end of the tube when the tube-suspending cable is in tension by a cordsecuring/releasing means, E.G., a pivotable bar having a hook on one end. When the bag-laden tube is lowered to the bottom of the wellbore, or to a column of bags previously placed therein, the tension on the cable is relaxed and the cord is released, allowing the positioning tube thereafter to be raised to the surface for re-use, leaving the cord and bags in the wellbore. Freedom of the bag-supporting cord to move with respect to the positioning tube when the latter is raised to the surface is assured by threading the cord through plastic tubing mounted to the wall of the ...

Energy Technology Data Exchange (ETDEWEB)

Investigations were conducted on the range of emission rates of NO, NO[sub 2], CO and hydrocarbons, and the thermal efficiencies produced by each burner on three production cookers, supplied by different Australian manufacturers. It was found that the emissions and efficiencies were markedly affected by (1) the thermal input, both with and without a load on the burner, and (2) the load-height to flame-length ratio, with a load on the burner. The effect of hydrocarbon leakage into the secondary/dilution air was investigated, to explain the observed correlation of hydrocarbon emission rate with dilution air flow. The hydrocarbons were found to arise from two sources: -leakage from the stabilisation ports at the base of the burner, which was found to be significant at the higher thermal input; -incomplete combustion of the fuel in the premix, which was the dominant source of hydrocarbons emissions at the lower thermal input. ...

British Library Electronic Table of Contents (United Kingdom)

ABSTRACT Purpose: The aim of this two-center study was to evaluate screw-type titanium implants with a chemically modified, sandblasted and acid-etched surface when placed in the posterior maxilla or mandible, and loaded 21 days after placement. Material and Methods: All 56 patients met strict inclusion criteria and provided informed consent. Each patient displayed either a single-tooth gap, an extended edentulous space, or a distal extension situation in the posterior mandible or maxilla. Eighty-nine dental implants (SLActive, Institut Straumann AG, Basel, Switzerland) were inserted according to an established nonsubmerged protocol and underwent undisturbed healing for a period of 21 days. Where appropriate, the implants were loaded after 21 days of healing with provisional restorations i...

Energy Technology Data Exchange (ETDEWEB)

Microstructural observations of damage around indentations in Ti{sub 3}SiC{sub 2} are presented. The Vickers hardness decreased with increasing load and asymptotically approached 4 GPa at the highest loads. No indentation cracks were observed even at loads as high as 300 N. Preliminary strength versus indentation plots indicate that, at least for the large-grained material ({approx}100 {micro}m) studied here, Ti{sub 3}SiC{sub 2} is a damage-tolerant material able to contain the extent of microdamage to a small area around the indent. The following multiple energy-absorbing mechanisms have been identified from scanning electron micrographs of areas in the vicinity of the indentation: diffuse microcracking, delamination, crack deflection, grain push-out, grain pull-out, and the buckling of individual grains.

CERN Document Server

A non-resonant RF cavity loaded with amorphous alloy cores has been designed and tested. The cavity has a re-entrant structure loaded with 8 amorphous alloy toroidal core and its characteristic impedance is designed as 450 Omega . The RF power is fed by 1 kW solid state amplifier using a step-up transformer with 1:9 impedance ratio. In the high power test, an accelerating gap voltage of more than 900 V was measured with input power of 1 kW in the frequency range of 1 to 10 MHz. The voltage standing wave ratio (VSWR) was less than 2.0. The results prove that the cavity may be used successfully within a compact proton synchrotron for a cancer therapy facility. (3 refs).

Science.gov (United States)

Blade fatigue life is an important element in determining the economic viability of the Vertical-Axis Wind Turbine (VAWT). A principal source of blade fatigue is thought to be the stochastic (i.e., random) aerodynamic loads created by atmospheric turbulence. This paper discusses the development of a model for the simulation of these stochastic loads, given the rotor geometry, operating conditions, and assumed turbulence properties. A Double-Multiple-Streamtube analysis is employed, which includes the effects of wind shear. Reynolds number variations, different airfoil sections and chord lengths along the blade span, and an empirical model for dynamic stall effects. Calculations are presented for the VAWT 34-m Test Bed currently being assembled at Bushland, Texas. Time histories of the loads, as well as their Fourier spectra, are presented and discussed. An unexpected finding is that the average output power is predicted to ...

Energy Technology Data Exchange (ETDEWEB)

Most pumped-storage plants have the capability to operate as synchronous condensers. As such, they can be brought on line very quickly to support system load requirements. However, one of the effects of making a rapid transition from synchronous condenser operation to turbine/governor operation is an initial reverse power flow into the machine. This reverse power flow can be very undesirable at a time when the system is calling for load support. On weak or isolated systems, this reverse power flow can lead to objectionable voltage and frequency dips in the system. With the proper utilization of a static frequency converter (SFC) and its associated controls and auxiliary switchgear systems, the reverse power flow resulting from a transition from synchronous condenser operation can be eliminated. This paper will describe the method by which an SFC system can be used to make this rapid load response in pumped-storage plants ...

Science.gov (United States)

By placing a discharge or 'dump' tube across an exploding bridgewire load, it is possible to by-pass the electrical energy and terminate the explosion of the wire. The dump tube is triggered by a signal derived from the energy removed from the storage cap...

Energy Technology Data Exchange (ETDEWEB)

This work presents an analysis of the operation of a multi-cylinder, tubro charged, indirect injection diesel engine from a second-law analysis point of view. For this purpose, a single-zone thermodynamic model following the filling and emptying modelling technique is developed. A second-law analysis is performed in all parts of the diesel engine plant, which provides all the existing availability terms and accounts for the evaluation of every component`s irreversibilities. A complete second-law terms tabulation is given for the maximum speed-full load operation case, which is compared with its first-law counterpart. A detailed parametric study is performed in all parts of the diesel engine plant comprising the effects of speed and load on the availability terms in a range that covers the whole operation of the engine under turbocharged action. Various second-law (availability) terms such as indicated and brake work, heat transfer, inlet air, ...

Energy Technology Data Exchange (ETDEWEB)

The article presents measures for the solution of construction-biological problems and for reducing the pollutant load of buildings. (HW) [Deutsch] Der Artikel berichtet ueber Massnahmen ueber Sanierung von baubiologischen Schwachstellen und Schadstoffbelastungen in Gebaeuden. (HW)

International Nuclear Information System (INIS)

Purpose: In an experimental study, the correlation between the trabecular bone density of the different regions of the proximal femur and the fracture load in the setting of femoral neck fractures was examined. Methods: The bone mineral density 41 random proximal human femora was estimated by single-energy quanitative CT (SE-QCT). The trabecular bone density was measured at the greatest possible extracortical volume at midcapital, midneck and intertrochanteric level and in the 1 cm"3 volumes of the centres of these regions in a standardised 10 mm thick slice in the middle of the femoral neck axis (in mg/ml Ca-hydroxyl apatite). The proximal femora were then isolated and mounted on a compression/bending device under two-legged stand conditions and loaded up to the point when a femoral neck fracture occurred. Results: Statistical analysis revealed a linear correlation between the trabecular bone density and the fracture load ...

UK PubMed Central (United Kingdom)

Indomethacin, a potent nonsteroidal anti-inflammatory drug, has been used in the treatment of various kinds of pains, inflammation and arthritis. However, oral administration of indomethacin produces...Full Text Available

Science.gov (United States)

The Heliophysics roadmap: "The Solar and Space Physics of a New Era: ..... Improved materials and manufacturing processes to produce Iridium/Rhenium apogee class ... In addition to batteries, other advanced energy storage/load leveling ...

Science.gov (United States)

This study deals with the torsional response of Ti-8823 and 18Ni (200) maraging steel. The effect of different heat treatments and the subsequent change in microstructure are investigated. In the case of the Ti-8823, a comparison was made between the solu...

Energy Technology Data Exchange (ETDEWEB)

The first offshore wind farm in Sweden; Bockstigen, consists of five 500 kW stall controlled wind turbines on mono pile foundations. The main objectives of the technical evaluation are to verify the original design assumptions made for a load carrying mono pile and bedrock, investigate offshore power production versus onshore ditto as well as to determine park effects and analyse meteorological multi-mast statistics which serve as reference data to a newly developed computer code for offshore wind energy potential mapping. The 'main' measurement system has continuously been acquiring data at 1 and 20 Hz/channel since the summer of 1998. A 40 m meteorological mast was built within the wind farm in the summer of 1999 in order to acquire relatively undisturbed wind speed data from 'free' sectors as well as to enable wake measurements. The mono pile and tower of one of the turbines are equipped with strain gauges at several depths ...

Science.gov (United States)

No Abstract Available

UK PubMed Central (United Kingdom)

The water permeability of tissues was investigated by measuring the efflux of ³HHO from previously loaded (in darkness) etiolated bean buds (Phaseolus vulgaris L. var. Red...Full Text Available

UK PubMed Central (United Kingdom)

The definition of “minor” veins in leaves is arbitrary and of uncertain biological significance. Generally, the term refers to the smallest vein classes in the leaf, believed to function...Full Text Available

UK PubMed Central (United Kingdom)

Background:Stem cells can differentiate into multiple cell types, and therefore can be used for cellular therapies, including tissue repair. However, the participation of stem cells...Full Text Available

Science.gov (United States)

Under a cooperative agreement, the Bureau of Mines, Magma Copper Co., and ASARCO, Inc., tested backfilled ground support systems at two elevations in Magma's San Manuel, AZ, mine. The tests were mainly for guidance in designing the loading crosscuts of th...

Energy Technology Data Exchange (ETDEWEB)

Electrical power is generated by steam turbines (steam being produced by coal, oil, gas or nuclear reactors), hydro units, gas turbines, internal combustion engines, jet engines, and pumped storage plants. Nuclear Power Plants generate only 15% of the total electrical power in the US. Nuclear Power Plants being cheaper to run are generally base loaded. The pumped-storage and gas turbine plants have ideal characteristics for peaking duty. In the pumping mode, pumped storage plants are used to provide additional system load and in the generating mode, they supply reactive power during peak load demands. Gas turbine plants have higher running costs, but are used as peaking units with a fast start capability. Fossil power plants need a minimum of 1 hour to stabilize expansion in the boiler and turbine generator. Due to a more competitive power supply market due to deregulation, most of the utilizes plan generation only for the ...

Energy Technology Data Exchange (ETDEWEB)

The dispersion mechanism of highly loaded coal-water mixture (CWM) in the presence of a polyelectrolyte additive was investigated. Two important factors have been found: the ability of the additive to apply a sufficient electric repulsive force to the coal particles, and an appropriate affinity of the additive to the coal surface.

UK PubMed Central (United Kingdom)

The effects of events which occur prior to slaughter, such as loading, transport, and holding at an abattoir, on the prevalence of Campylobacter species, including Campylobacter...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

A new approach to dynamic security assessment in electric power systems is proposed. A power system is modeled as a dynamical system with random variable structure. Structural variations are caused by primary and secondary events. Primary events are state-independent disturbances representing line and unit faults and load changes and are modeled by random jump processes. Secondary events that represent forced line and unit outages and load sheddings are modeled through an aggregate representation of the protection system as random processes whose change in time corresponds to the crossing of switching surfaces by the state process. These switching surfaces are defined by the setting of the protective relays. Commensurate with this model a three-state decomposition of the operating conditions into normal, emergency, and partial load operating states is suggested. Transitions between these states are described in terms of ...

UK PubMed Central (United Kingdom)

Qualitative and quantitative aspects of the mechanisms involved in the regulation of cytoplasmic pH during an acid-load have been studied in Acer pseudoplatanus cells. Two main processes,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This report surveys the possibilities and restrictions of different construction materials for the purpose of the blades of a small stall regulated turbine. For example scaling up, material saving at decreasing of static or dynamic loads, comparisons of global costs based on prices per unit of weight, etc. For the mutual comparison of construction materials for turbine blades the starting point is a stall regulated horizontal axis turbine with a rotor diameter of 16 m and a tipvane speed of about 64 m/s. Short descriptions are given of the materials and of the applied production methods with the resulting blade geometry. The blade skins are dimensionized for storm loads after the optimalization of the blade geometry, needed for the design wind speed, is recorded. The resulting blade skins are mutually compared as for weight, mass inertia and bending stiffness. Also a comparison took place of the resulting reserve factors against ...

UK PubMed Central (United Kingdom)

Failure of bone under monotonic and cyclic loading is related to the bone mineral density, the quality of the bone matrix and the evolution of microcracks. The theory of linear elastic fracture...Full Text Available

UK PubMed Central (United Kingdom)

A bedload trap in the riverbed provided direct quantitative measurement of debris-transport rate in the East Fork River, Wyoming, a basin of 466 km² drainage area. Traction load moves only...Full Text Available

International Nuclear Information System (INIS)

The different radiation loads caused by natural and artificial radionuclides are compared in this paper. This examples will serve to illustrate that the problem of population exposure to radiation can only be solved in consideration of all components and to show which effects of the radiation from natural sources are of special importance in this connexion. (orig./AK).

UK PubMed Central (United Kingdom)

179 cognitively healthy adults enrolled in the Sun Health Brain Donation program between 7/91 and 12/07 were at least 60 years old and nondemented at the time of death (21 had developed mild...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundDuring normal breathing, the mesothelial surfaces of the lung and chest wall slide relative to one another. Experimentally, the shear stresses induced by...Full Text Available

Science.gov (United States)

Tests of Tail Buffet on the CF-18 Aircraft, AGARD Specialists' Meeting on Aircraft Loads due to. Flow Separation, Sorrento, Italy, Apr. 16, 1990. ...

Energy Technology Data Exchange (ETDEWEB)

This patent describes an automatic loading roller for transmitting torque in traction drive devices in manipulator arm joints includes a two-part camming device having a first cam portion rotatable in place on a shaft by an input torque and a second cam portion coaxially rotatable and translatable having a rotating drive surface thereon for engaging the driven surface of an output roller with a resultant force proportional to the torque transmitted. Complementary helical grooves on the respective cam portions interconnected through ball bearings interacting with those grooves effect the rotation and translation of the second cam portion in response to rotation of the first.

Energy Technology Data Exchange (ETDEWEB)

Design methods and parameters are described which are addressed when considering consequences of a postulated pipe rupture event in a nuclear plant design. Parameters discussed are break opening time and size, resultant blowdown characteristics of the effluent from the broken pipe, jet reaction and impingement loading, pipe motion, and pipe impact loading on steel and concrete structures. The impact the various parameters have on overall plant designs and conservatisms inherent in each consideration are evaluated in a qualitative nature. Finally, recommendations are provided for each parameter discussed for further evaluation and study.

International Nuclear Information System (INIS)

The layout of the network with its frequency and transmission power control shows how the time behaviour of power plants and consumers determines the frequency curve during sudden power disturbances. As for switching processes in the network for the turbine, network operation entails loads due to shock-like disturbance functions to which one should not normally respond by switching off. The interception controllers are therefore adjusted via a simulation model by which the vibrations of the turbine rotor can be modelled in real time under different network loads. (GL).

Energy Technology Data Exchange (ETDEWEB)

The general types of pumped-storage plants and considerations for determining their need, use, and selection are presented. A brief discussion of TVA's experience on two pumped-storage schemes is included. Pumped-storage plants have become an integral part of many hydropower systems. Most of these systems use pumped-storage plants to meet power requirements during the peak load demands. In any application, large or small, the expected load demand and supply source must be identified to select the best scheme required for the particular system.

Energy Technology Data Exchange (ETDEWEB)

A method for cleaning timing optimization in a parallel steam generator system is described. The method is based on the minimization of a suitable objective function, and takes into account the load allocation on steam generators. In order to establish appropriate fouling growth models the mechanism of the particle deposition and removal on heat transfer surfaces is analyzed. The objective function is related to the short time management costs which are based on depreciation of steam generators, fuel costs and the costs of cleaning interventions. The optimization problem is described; a direct one level method is compared with a two level method. Some applications and their results are reported and discussed. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper presents a new algorithm for the optimal long-range generation planning for a thermal system with pumped-storage plants. The algorithm is based upon the analytical production costing model developed under the assumption of Gaussian probabilistic distribution of random load fluctuations and plant outages. The optimization problem consists of the master problem to determine the annual investment, and the pumped-storage subproblem to determine the optimal pumped-storage operation. The master problem is formulated as a Hamiltonian minimization problem, and the pumped-storage subproblem is solved using the concept of peak-shaving operation on the original load curve.

International Nuclear Information System (INIS)

This invention concerns a hydraulic braking system for loads subjected to impacts and vibrations. These double acting telescopic type hydraulic braking systems possess significant drawbacks linked to possibly important hydraulic leaks due to (a) the use of many dynamic seals in such appliances and (b) the effects of the environment of the system on these seals, particularly when employed in nuclear power stations where the seals reach significant temperatures and are subjected to radiation. Under this invention a remedy is suggested to such drawbacks by integrating means to offset automatically the leaks and the accumulation of hydraulic fluid expansions, as well as facilities to show if such leaks have occurred.

Energy Technology Data Exchange (ETDEWEB)

Wood-plastic composites (WPC) have been prepared with five low-grade woods, native to Syria, using three monomer systems; acrylamide, butylmethacrylate, and styrene, with methanol as the swelling solvent. Polymerization was induced at various radiation doses (10, 20, and 30 kGy) at a dose rate of 3.5 kGy/h using a {sup 60}Co gamma radiation source. Some physical properties of WPC, namely polymer loading and compression strength have been measured. The polymer loading decreases approximately with increasing density of the wood species used.