Abstract We address the fundamental question of matching the rest-frame K-band luminosity function (LF) of galaxies over the Hubble time using semi-analytic models after modification of the stellar population modelling. We include the Maraston evolutionary synthesis models, which feature a higher contribution by the thermally pulsating asymptotic giant branch (TP-AGB) stellar phase, into three different semi-analytic models, namely the De Lucia and Blaizot version of the Munich model, morgana and the Menci model. We leave all other input physics and parameters unchanged. We find that the modification of the stellar population emission can solve the mismatch between models and the observed rest-frame K-band luminosity from the brightest galaxies derived from UKIRTInfraredDeep Sky Survey d...
The BL Lacertae object PKS 1413+135 is associated with a disk dominated galaxy which heavily absorbs the BL Lac nucleus at optical and X-ray wavelengths. It has been argued whether this galaxy is actually the host galaxy of PKS 1413+135 or whether the BL Lac is a background QSO, gravitationally lensed by the apparent host galaxy. We have obtained deep high resolution H-band images of this unusual BL Lac object using the UKIRT IRCAM3. Our observations show that the BL Lac nucleus is centered within < 0.05 arcsec of the galaxy. Based on this result we assess the probability for the lensing scenario and come to the conclusion that the disk galaxy is indeed the host of PKS 1413+135. The galaxy shows peanut-shaped isophotes, suggesting the presence of a central bar which is a common feature of AGN
A new era for the field of Galactic structure is about to be opened with the advent of wide-area digital sky surveys. In this article, the author reviews the status and prospects for research for 3 new ground-based surveys: the Sloan Digital Sky Survey (SDSS), the Deep Near-Infrared Survey of the Southern Sky (DENIS) and the Two Micron AU Sky Survey (2MASS). These surveys will permit detailed studies of Galactic structure and stellar populations in the Galaxy with unprecedented detail. Extracting the information, however, will be challenging.
From the COMBO-17 digital sky survey data, 1,231 faint blue galaxies with photometric redshifts of 0.1Deep Field South) are selected as the sample. We have studied the distributions of the photometric redshifts of these sample galaxies, in the conditions that the photometric redshifts are obtained respectively by using only optical data and by using both optical and near-infrared data. The results indicate that there are 183 galaxies whose photometric redshifts derived from both optical and infrared data are greater than 1.2, that the rms error of the derived photometric redshifts is 0.046, and that to increase the photometric SNR is also helpful for discriminating those misjudged low-redshift galaxies by using only the optical data. We have studied a...
Studies addressed to a deep understanding of the structure/property relationship on the near infrared (NIR)-emissive erbium-quinolinolate complexes, which are of interest for low-cost photonic systems, are reviewed. The role of the 8-quinolinolate ligand (Q), which studies also as sensitizer to overcome the weak absorptivity of lanthanide ion, is discussed. Synthetic and structural aspects are reported to revise the old assumption that these complexes are analogous in structure to AlQ3 and to point out the specificity of the lanthanide coordination chemistry. In fact depending on reaction conditions, species with high coordination numbers and differing for nuclearity and stoichiometry have been isolated and fully characterized. In some instances it has been shown that coordinated water mol...
We derive stellar masses, ages, and star formation histories (SFHs) of massive early-type galaxies in the z = 1.237 RDCS1252.9-2927 cluster and compare them with those measured in a similarly mass-selected sample of field contemporaries drawn from the Great Observatories Origin Deep Survey South Field. Robust estimates of these parameters are obtained by comparing a large grid of composite stellar population models with 8-9 band photometry in the rest-frame near-ultraviolet, optical, and IR, thus sampling the entire relevant domain of emission of the different stellar populations. Additionally, we present new, deep U-band photometry of both fields, giving access to the critical far-ultraviolet rest frame, in order to empirically constrain the dependence of the most recent star formation processes on the environment. We also analyze the morphological properties of both samples to examine the dependence of their scaling relations on their mass ...
BackgroundFunctional Near-Infrared Spectroscope (fNIRs) is one of the latest technologies which utilize light in the near-infrared range to determine brain activities. Near-infrared...Full Text Available
Optically stimulated luminescence (OSL) of synthetic stishovite was investigated for a future dating technique of meteor impact craters. Luminescence around 330 nm was measured on the #gamma#-ray irradiated stishovite under two stimulating light sources of infrared laser (830 nm) and blue light emitting diode set (470 nm). Thermoluminescence (TL) studies before and after the OSL measurements showed the intensities around 100-200 deg. C and 220-350 deg. C to increase and those around 350-450 deg. C to decrease. This indicates that a part of deep-trapped charges excited during the OSL measurements were retrapped by shallower traps. The infrared stimulated luminescence (IRSL) after the TL measurement up to 450 deg. C could not be detected, while the blue light stimulated luminescence (BLSL) after TL had about one-tenth of the intensity before TL. This indicates that a part of the charges in shallower traps were detrapped ...
We present the results of Near-Infrared Camera and Multi-Object Spectrometer (NICMOS) imaging of a sample of 19 high-mass passively evolving galaxies with 1.2 < z < 2, taken primarily from the Gemini DeepDeep Survey (GDDS). Around 80% of galaxies in our GDDS sample have spectra dominated by stars with ages #approx#>1 Gyr. Our rest-frame R-band images show that most of these objects have compact regular morphologies which follow the classical R "1"/"4 law. These galaxies scatter along a tight sequence in the size versus surface brightness parameter space which defines the Kormendy relation. Around one-third (3/10) of the massive red objects in the GDDS sample are extraordinarily compact, with effective radii under 1 kpc. Our NICMOS observations allow the detection of such systems more robustly than is possible with optical (rest-frame UV) data, and while similar systems have been seen at z #approx#> 2, this is ...
High-resolution near-infrared and far-infrared observations are presented of the southeastern molecular cloud fragment in the IC 5146 dark cloud. These observations rule out earlier suggestions for the formation of massive stars in this fragment.
Clicking on the image will bring up the highest resolution version available. The Whirlpool Galaxy in Infrared Dust Credit: Infrared: NASA, ESA, M. Regan & B. Whitmore (STScI),...
The differences are highlighted of various aspects of behaviour of the luminescence signal from feldspar when stimulated by green light and when stimulated by infrared radiation. In respect of bleaching, a comparison is made of the influence of white light (daylight) on the two stimulated luminescence signals, as well as a comparison of the influence of infrared exposure on the green-stimulated signal with the influence of green exposure on the infrared-stimulated signal. The influence of preheating on the two stimulated signals is also compared. Light-emitting diode systems were used for both green and infrared stimulation. The observations are considered in relation to the mechanism relevant to green- and infrared-stimulated luminescence from feldspar. (author).
The differences are highlighted of various aspects of behaviour of the luminescence signal from feldspar when stimulated by green light and when stimulated by infrared radiation. In respect of bleaching, a comparison is made of the influence of white light (daylight) on the two stimulated luminescence signals, as well as a comparison of the influence of infrared exposure on the green-stimulated signal with the influence of green exposure on the infrared-stimulated signal. The influence of preheating on the two stimulated signals is also compared. Light-emitting diode systems were used for both green and infrared stimulation. The observations are considered in relation to the mechanism relevant to green- and infrared-stimulated luminescence from feldspar. (author).
This data set contains data from in situ infrared thermometer measurements ... Surface temperature was measured using an Apogee Infrared Thermometer from 23 ...
Clicking on the picture will download the highest resolution version available. Whirlpool Galaxy Deep Field Credit & Copyright: Jon Christensen Explanation: Follow the handle...
We present the 24 #mu#m rest-frame luminosity function (LF) of star-forming galaxies in the redshift range 0.0 #<=# z #<=# 0.6 constructed from 4047 spectroscopic redshifts from the AGN and Galaxy Evolution Survey of 24 #mu#m selected sources in the Booetes field of the NOAO Deep Wide-Field Survey. This sample provides the best available combination of large area (9 deg"2), depth, and statistically complete spectroscopic observations, allowing us to probe the evolution of the 24 #mu#m LF of galaxies at low and intermediate redshifts while minimizing the effects of cosmic variance. In order to use the observed 24 #mu#m luminosity as a tracer for star formation, active galactic nuclei (AGNs) that could contribute significantly at 24 #mu#m are identified and excluded from our star-forming galaxy sample based on their mid-IR spectral energy distributions or the detection of X-ray emission. Optical emission line diagnostics are considered for AGN identification, ...
Samples of fat coal-E, its roof sandstone-A and blind coal-W from two coal mines in Hebei Province of China were brought to the laboratory to study the features of infrared thermal images and radiation temperature in the course of uni-axial load and uni-axial cycle load. To check the results of infrared remote sensing detection, two other methods, acoustic emission detection and electrical resistance detection were also used. The AGA-782 thermalvision detected change of the temperature field of the samples` surfaces. The study showed that: (1) coal rocks and sandstone in the course of loading have three types of infrared thermal image features and three types of infrared radiation temperature features; (2) infrared detection is comparable with acoustic emission detection and electrical resistance detection. Generally, the infrared forewarning of coal rocks` ...
ObjectivesWe have developed an image-guided surgery system based on invisible near-infrared (NIR) fluorescent light. Presently, the only clinically-available NIR...Full Text Available
The polarity of biological mediums controls a host of physiological processes such as digestion, signaling, transportation, metabolism, and excretion. With the recent widespread use of near-infrared...Full Text Available
The fraction of a given area of ground that is covered by hail can be determined by using an airborne infrared thermometer. If the ambient ground temperature and the hail-covered ground temperature are measured with the same thermometer, and the surface o...
BackgroundFourier Transform Infrared Imaging (FTIRI) is used to investigate the amide anisotropies at different surfaces of a three-dimensional cartilage or tendon block. With the...Full Text Available
A short account is given of the difficulties encountered in temperature measurement of boundary layers and a comparison of two types of thermometers, an infrared radiometer and mercury in glass thermometer. (Author)
Although deep-sea cephalopods are key marine organims, their feeding ecology remains essentially unknown. Here, we report for the first time the trophic structure of an assemblage of these animals (19...Full Text Available
The Subseabed Disposal Program has recently completed a 30-day, 0.286-scale laboratory simulation of an In Situ Heat Transfer Experiment (ISHTE), scheduled for eventual deployment in the deep ocean 600 nautical miles north of Hawaii. 10 figures.
The Subseabed Disposal Program has recently completed a 30-day, 0.286-scale laboratory simulation of an In Situ Heat Transfer Experiment (ISHTE), scheduled for eventual deployment in the deep ocean 600 nautical miles north of Hawaii. 10 figures.
PURPOSE The Wells rule is widely used for clinical assessment of patients with suspected deep vein thrombosis (DVT), especially in the secondary care setting. Recently a new clinical decision...Full Text Available
This table contains point-source catalogs for the ~2 Ms exposure of the Chandra Deep ... Source positions are determined using centroid and matched-filter techniques; .... The 1-sigma upper statistical error (Gehrels 1986, ApJ, 303, ...
We investigated the deep-sea fossil record of benthic ostracodes during periods of rapid climate and oceanographic change over the past 20,000 years in a core from intermediate depth in the northwestern...Full Text Available
Surface temperature is measured with an infrared thermometer. Measuring Surface Temperature. Nine sample points are selected with a site of uniform land ...
... significant change of spontaneous radiation intensity. It is very sensitive technique allowing the observation of small changes of light absorption. ...
... Problems investigated in various basic hollowness ratios include ultimate compressive strength, fatigue properties, buckling characteristics, and ...
A multi-spectral Schottky barrier infrared detector array in which individual pixels of radiation from a remote radiating object are detected by two or more Schottky barrier infrared radiation detectors each having a different spectral response so as to provide a ''color'' discrimination for the array.
A multi-spectral Schottky barrier infrared detector array in which individual pixels of radiation from a remote radiating object are detected by two or more Schottky barrier infrared radiation detectors each having a different spectral response so as to provide a ''color'' discrimination for the array.
Luminescence stimulated from feldspars using wavelengths in the infrared region can be applied to the dating of sedimentary grains. Reported stimulation spectra are very similar for a wide range of feldspars, but their emission spectra show greater variation. For accurate dating it is critical that unstable infrared-stimulated luminescence (IRSL) signals are removed from the laboratory-irradiated grains. Several approaches to isolate a thermally stable signal are described. (author).
Magnesium alloys and composites are potentially highly attractive materials for lightweight design in the automotive industry - if common forming technologies, i.e., deep drawing and cold extrusion, are applicable to them; so far, this is seldom the case. The authors have tested some candidate Mg alloys and discuss the results of their measurements in detail. The Figure shows a typical workpiece part obtained by a deep-drawing technique. (Abstract Copyright [2003], Wiley Periodicals, Inc.)
We present a study of the mid-infrared properties and dust content of a sample of 27 HII ``blobs'', a rare class of compact HII regions in the Magellanic Clouds. A unique feature of this sample is that even though these HII regions are of high and low excitation they have nearly the same physical sizes ~1.5-3 pc. We base our analysis on archival 3-8 microns infrared imagery obtained with the Infrared Array Camera (IRAC) on board the Spitzer Space Telescope. We find that despite their youth, sub-solar metallicity and varied degrees of excitation, the mid-infrared colors of these regions are similar to those of typical HII regions. Higher excitation ``blobs'' (HEBs) display stronger 8 micron emission and redder colors than their low-excitation counterparts (LEBs).
The dependence of the carrier concentrations, of the resistivity and of the Hall coefficient of irradiated silicon on the neutron fluences has been investigated, starting from the supposition that the main phenomena induced by irradiation in the semiconductor bulk are shallow-donor removal and deep-centres creation. The free parameters of the model are initial doping of the starting material, the permitted energy level values of the radiation-induced centres in the semiconductor band gap and their introduction rates. The influence of each parameter on the calculated dependences is studied in detail, for three cases: one deep acceptor-like centre, two deep acceptors and one deep acceptor plus one deep donor-like centre. each of the three cases is discussed in correspondence with different experimental results.
Proper assessment of the hypothesis which correlates polycyclic aromatic hydrocarbons (PAHs) with the unidentified infrared emission bands requires additional experimental laboratory data. In order to address this need, thermal infrared emission studies were performed on a subset of PAHs suggested to be of astrophysical importance. It was proposed that infrared emission from interstellar PAHs occurs following absorption of an ultraviolet photon. Since energy transfer to the ground electronic state can be rapid for a species in which intersystem crossing is negligible, the emission spectrum may be viewed as resulting from an equilibrium vibrational temperature (Leger and d'Hendecourt, 1987). This has been the basis for using infrared absorption spectra to calculate the corresponding emission spectra at various temperatures. These calculations were made using room temperature infrared ...
We have obtained for the first time $K$-band infrared spectra of the soft X-ray transient V616 Mon (=A0620--00). We determine the 2-sigma upper limit to the fraction of light arising from the accretion disc to be 27 percent. The effect this has on the binary inclination, determined from modelling the infrared ellipsoidal variations is to increase it by less than 7 degrees and decrease the mass of the black hole by less than 3.6 Msun.
The University of California at Los Angeles (UCLA) participated in a U.S. Nuclear Regulatory Commission research program to investigate methods to measure the effect of management and organization on nuclear plant safety. The UCLA research team focused its efforts on understanding {open_quotes}deep technical knowledge,{close_quotes} and its relation to probabilistic risk assessment. As a result, the research team combined deep technical knowledge with a commonly used rating system for understanding the effectiveness of management and organizations.
Today, the use of the arch bars in the treatment of mandibular fractures is common [1]. But it has complications such as damaged teeth, periodontal tissue [2], risk of blood transmitted disease [3] and premature contact with maxillary incisor teeth in anterior deep bite occlusion. Many techniques are used for resolving these problems. In this paper, we describe the technique of using Maxillo-Mandibular Fixation Screws (MMFS) with essig wiring of anterior mandibular teeth in the management of symphyseal fracture of deep bite patients.
The purpose of this paper is to describe a technique of forced surgical rotation of the mandible used in skeletal Class II patients with deep bite and prominent chin. Posterior occlusal composite onlays combined with preoperative orthodontic treatment without anterior intrusion increase the posterior rotational component of the surgical mandibular advancement, when removed during operation. This manoeuvre allows for the surgical closure of the posterior open bite, while anteriorly the deep bite is opened. This technique avoids bimaxillary rotation surgery with dorsal impaction in mild to moderate cases. In any case, a chin setback osteotomy with compromised aesthetics can be avoided.
The scenario of the development of a new procedure for cutting out the broken protective wells for thermocouples inside the deep holes in the tube plate in the moisture re-heater (MSR) at Daya Bay nuclear power station is presented. Focused in the innovation and improvement of the self-made tools, the new procedure produced an effective method to cut out swing long inserts stuck inside the deep holes. (authors)
Jul 21, 1998 ... Additional roof surface temperatures were taken with a handheld "heat spy," an infrared thermometer to help calibrate the ATLAS thermal ...
Apr 14, 2010 ... The payload uses a remote infrared thermometer (Kelvin-Video), a thermohygrometer (Iva-6A), a heat-loss thermoanemometer/thermometer (TTM-2) ...
There is a requirement for a noninvasive technique to monitor stem cell differentiation. Several candidates based on optical spectroscopy are discussed in this review: Fourier transform infrared (FTIR)...Full Text Available
light-emitting diode A light-emitting diode, or LED, is a semi-conductor light source that emits visible light or invisible infrared radiation. Semi-conductors ...
In this paper, a Kramers-Kronig (KK) analysis of infrared (IR) reflectance spectrum of quaternary In_0_._0_1Al_0_._0_6Ga_0_._9_3N film grown by molecular beam epitaxy (MBE) is reported. The infrared measurement is performed in the reflection mode at an incident angle of 15 degree sign by Fourier transform infrared (FTIR) spectroscopy at T = 300 K. The Kramers-Kronig analysis of the reflectivity data has been used to obtain the real and imaginary parts of the index of refraction (n and k), and the real and imaginary parts of the dielectric response function (#epsilon#' and #epsilon#') of the materials. Finally, the transverse optical and longitudinal optical phonons for quaternary In_xAl_yGa_1_-_x_-_yN were obtained.
May 1, 2011 ... Abstract: Diatek Corporation, San Diego, CA and the Jet Propulsion Lab developed the Diatek Model 7000 aural thermometer which weighs ...
A tunable diode laser is used to obtain infrared spectra of carbon dioxide in biological materials. The spectral resolution is sufficient to readily distinguish differing isotopic species. The technique may prove useful in clinical tests.
Cambridge scientists in the late 1980's. This same team, then headed by Professor John Baldwin, built the world's first separated-element optical/infrared aperture synthesis...
Feb 25, 2008 ... In the two Landsat scenes shown above, the pattern of deforestation can be clearly discerned. Deep green in these images shows lush ...
The unparticle stuff which is described by the theory with notrivial IR fixed point is recently suggested to exist in our world by Georgi. We illustrate its physical effects in deep inelastic scattering process in this letter.
Mycosis fungoides (MF) in deep-seated lymph nodes, spleen or liver appears to be associated with a lack of response of the disease to topical external therapy. Fourteen patients with mycosis fungoides...Full Text Available
A growing body of evidence in cognitive science and neuroscience points towards the existence of a deep interconnection between cognition, perception and action. According to this embodied perspective...Full Text Available
Federal regulators were set to vote on a plan to protect deep water corals and other sensitive fish habitats that will likely include a permanent ban on ...
Objective Comorbidities predisposing cardiac surgical patients toward deep sternal wound infection, such as diabetes and obesity, are rising in the United States. Longitudinal analysis of risk factors, morbidity, and mortality was performed to assessed effects of these health trends on deep sternal wound infection rates. Methods In this retrospective analysis of all median sternotomies performed at a single institution from 1991 through 2006, demographic and surgical characteristics were identified from a prospective database. The cohort was separated into periods from 1992 through 2001 and 2002 through 2006 to identify longitudinal trends in risk factors for deep sternal wound infection. Univariate and matched multivariable analyses were performed. Results Overall, study population had in...
INTRODUCTIONMany surgeons will have encountered the scissors that would not cut, and the artery clip that comes off in a deep difficult location, but it would be reasonable to assume...Full Text Available
We describe the stabilization by pressure of enzymes, including a hydrogenase from Methanococcus jannaschii, an extremely thermophilic deep-sea methanogen. This is the first published...Full Text Available
Necrotizing sialometaplasia, is a benign inflammatory lesion primarily involving the minor salivary glands of the hard palate. The lesion often presents itself as a deep-seated palatal ulcer with clinical...Full Text Available
Detailed geothermal studies of deep drill holes provide insights to heat transfer processes in the crust, and allow separation of different factors involved, such as palaeoclimatic and structural conductive effects as well as advective fluid flow effects. We present high resolution geothermal results of the 2516m deep Outokumpu Deep Drill Hole in eastern Finland drilled in 2004-2005 into a Palaeoproterozoic formation with metasedimentary rocks, ophiolite-derived altered ultramafic rocks and pegmatitic granite. The down-hole temperatures have been logged five times after end of drilling and extend to day 948 after drilling. The hole is completely cored (79% core coverage) and thermal conductivity measurements were done at 1m intervals. The geothermal results on temperature gradient, thermal...
ground strike hazards 3) Advancements in the initialization of numerical weather prediction models through better identification of deep convection 4) Improved routing of...
Briefly, 48 MOS microparticle sensors (essentially the same as those flown on .... at the Naval Research Lab to interpret the polarization of the incoming radio .... Adapter Satellite, to be published in Journal of Spacecraft and Rockets, 1994. ...
Jan 25, 2006 ... Source positions are determined using matched-filter and centroiding .... The upper 1-sigma statistical error in the full-band counts. ...
Human languages evolve continuously, and a puzzling problem is how to reconcile the apparent robustness of most of the deep linguistic structures we use with the evidence that they undergo possibly...Full Text Available
The salient features of the near-infrared free-electron laser (FEL) that is under construction at the new Darmstadt superconducting 130-MeV electron accelerator are discussed. Special attention is given to the layout and the parameters of the accelerator, the layout of the planned FEL experiment, the characteristics of the electron gun, the subharmonic chopper-buncher system, and the hybrid undulator system of the Darmstadt FEL. A comparison of the planned Darmstadt FEL with conventional lasers, with respect to the pulse and wavelength region, is presented. 15 refs.
A renormalization procedure is proposed which applies to lattice Feynman integrals containing zero-mass propagators and is analogous to the BPHZL renormalization procedure for continuum Feynman integrals. The renormalized diagrams are infrared convergent for non-exceptional external momenta, if the vertices of the theory satisfy a general infrared constraint. Under the same conditions as in the massive case, the continuum limit of the renormalized theory exists and is independent of the details of the lattice action.
Optical absorption measurements show that substitutional H"- ions, that is, protons with two electrons on anion sites, are thermally more stable than anion vacancies when thermochemically reduced CaO crystals are annealed in a reducing atmosphere. The H"- ions are identified by the infrared vibrational modes observed at 880 and 911 cm"-"1.
Dose-dependent behavior of the infrared stimulated luminescence (IRSL) decay from NaCl has been studied experimentally using only one aliquot irradiated with a range of 2-200 Gy {beta}-radiation doses. It was observed that the maximum IRSL intensity has not changed by an increase in dose though the total intensity increased as expected. Considering the possible implications of our findings for dosimeter, the results were compared with the other studies and discussed.
The generating functional in which the residual gauge freedom has been broken is related to the conventional generating functional for QED in arbitrary dimension. Closed expressions which relate ordinary N-point Green functions to N-point Green functions in the different gauges are derived. The leading logarithmic behaviour of the electron propagator in three dimensions is thus obtained. It is argued that one should not ascribe much importance to the infrared behaviour of the fermion propagator in the context of confinement.
The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.
The absolute absorption of ozone in the midinfrared has been measured relative to 253.7-nm ultraviolet absorption to an accuracy of 1% using a Bruker Fourier transform spectrometer. These new results agree with previous measurements by diode laser measurements after the latter are corrected for more recent infrared calculations and ultraviolet cross sections. They also agree with a determination based on refractive index measurements in the infrared. 16 refs., 4 figs., 3 tabs.
Aerobic chemoheterotrophic bacteria were isolated from surface soils and coastal plain subsurface (including deep aquifer) sediments (depths to 265 m) at a study site near Aiken, S.C., by plating on...Full Text Available
By using the quark-parton-flucton and Weinberg-Salam models, effects of interactions of weak neutral quark and neutrino currents were considered in deep - inelastic neutrino (anti)-nucleus scattering #nu# (anti-#nu#) A #-># #nu# (anti-#nu#) #gamma#X. The energy spectrum and degree of photon circular polarization were obtained in present paper. In particular for the nucleon (A = 1). The theoretical results were in a good agreement with data mentioned. (author). 6 refs., 4 figs.
The spatial connection between the zones of deep-lying faults and the narrowly-localized paleo-relief sections posessing an anomolous sedimentation condition in the latter Cretaceous is identified. It is established that this is of significance in choosing the primary regions for conducting oil exploration.
The paper deals with the disposal of radioactive waste and the plans for dealing with solid wastes of intermediate and low levels of activity, which are the responsibility of NIREX. NIREX is an executive body which co-ordinates the waste-disposal plans of the main radioactive waste producers. The disposal routes for the active wastes are described including the deep disposal of wastes containing material that will remain active for thousands of years. Requirements for deep burial are outlined with reference to the geology and hydrogeology of the site. Monitoring, maintenance and surveillance are mentioned for the protection of the public.
Radiation therapy has shown definite technical improvement due to application of proton beam irradiation. Clinical results of proton beam therapy also suggested enlargement of indication ranges in radial treatment and decrease of post radiation damages of the treatment of cancers in deep-seated organs. Inprovement of result in cancer therapy could be expected by this treatment technique in the future.
The P-odd asymmetries in deep inelastic scattering (DIS) of polarized leptons on nuclei are considered in the framework of the standard model and the parton-flucton model. The model predictions, within the experimental errors,agree well with the present data. 13 refs., 2 figs., 2 tabs. (author).
Computer programs have been developed to define the temperature increase which would be needed to bring deep-ocean water into density equilibrium with surface water for locations where data are available. A series of continuous-flow studies on phytoplankton blooms resulting from mixtures of 80 percent deep and 20 percent surface water in 2000-liter concrete culturing vessels (''reactors'') has been completed. A quantitative determination of nutrient utilization and flow through a combined primary and secondary trophic level system has been completed. This study utilized the clam Tapes semidecussata, fed from phytoplankton grown in 80 percent deep and 20 percent surface water. An analysis of the fate of the deep water discharged from a floating OTEC plant indicates that horizontal containment of the resulting deep water: surface water mixture is ...
Exposure of cells to light of less than 320 nanometers wavelengths may lead to lethal lesions and perhaps carcinogenesis. Many organisms have evolved mechanisms to repair U.V. light-induced damage. Organisms such as deep-sea bacteria are presumably never exposed to U.V. light and perhaps occasionally to visible from bioluminescence. Thus, the repair of U.V. damage in deep-sea bacterial DNA might be inefficient and repair by photoreactivation unlikely. The bacteria utilized in this investigation are temperature sensitive and barophilic. Four deep-sea isolates were chosen for this study: PE-36 from 3584 m, CNPT-3 from 5782 m, HS-34 from 5682 m, and MT-41 from 10,476 m, all are from the North Pacific ocean. The deep-sea extends from 1100 m to depths greater than 7000 m. It is a region of relatively uniform conditions. The temperature ranges from 5 to -1"0C. There is no solar light in the ...
The recently completed ''Deep River Study, Lower Mississippi River'' sponsored by the ''Governor's Task Force on Deep-Draft Vessel Access to the Lower Mississippi River'' contained the following recommended program: Dredge the present 40 foot deep channel to 45 feet initially from the Gulf via Southwest Pass to Mile 172 AHP to provide for two-way navigation of the deep draft vessels that would serve the forecasted most likely level of waterborne commerce (Alternative 9). Plan and seek authorization to further deepen the channel in stages to 55 feet in the future should actual increases in commerce equal the high level level of commerce (Alternative 11). Put into operation, as soon as possible, facilities for loading and topping-off grain ships midstream and topping-off coal carriers in the Gulf in order to attract and ...
We present mid-infrared spectro-imagery and high-resolution spectroscopy ofthe Orion bar and of a region in the Orion nebula. These observations have beenobtained in the Guaranteed Time with the Circular Variable Filters of the ISOcamera (CAM-CVF) and with the Short Wavelength Spectrometer (SWS), on board theEuropean Infrared Space Observatory (ISO). Our data shows emission fromamorphous silicate grains from the entire HII region and around the isolatedO9.5V star Theta2 Ori A. The observed spectra can be reproduced by a mixture ofinterstellar silicate and carbon grains heated by the radiation of the hotstars present in the region. Crystalline silicates are also observed in theOrion nebula and suspected around Theta2 Ori A. They are probably ofinterstellar origin. The ionization structure and the distribution of thecarriers of the Aromatic Infrared Bands (AIBs) are briefly discussed on thebasis of the ISO observations.
A method for preparing metal for heating by infrared radiance to enable uniform and consistent heating. The surface of one or more metal parts, such as aluminum or aluminum alloy parts, is treated to alter the surface finish to affect the reflectivity of the surface. The surface reflectivity is evaluated, such as by taking measurements at one or more points on the surface, to determine if a desired reflectivity has been achieved. The treating and measuring are performed until the measuring indicates that the desired reflectivity has been achieved. Once the treating has altered the surface finish to achieve the desired reflectivity, the metal part may then be exposed to infrared radiance to heat the metal part to a desired temperature, and that heating will be substantially consistent throughout by virtue of the desired reflectivity.
This paper studies the effect upon the thermoluminescence (TL) signal of four feldspar samples of exposing them to infrared stimulation, as occurs during infrared-stimulated luminescence (IRSL) measurement. Together with pulse annealing measurements these results are used to show which part of the TL signal is removed by exposure to IR and which part is directly related to the IRSL signal that is observed. When the samples are preheated prior to measurement in order to remove any low-temperature (< 200"oC) TL signals, a linear relationship is observed between the amount of TL that is lost and the IRSL light sum that is produced. The IRSL light sum is consistently four times larger than the amount of TL that is lost. Three possible explanations are proposed for this, but no conclusive evidence could be obtained to support any of them. A close similarity is observed in the pulse annealing results and the loss of TL due to IR exposure of the ...
An experiment lasting a number of hours was carried out with 6 men under standardised climate chamber conditions to find out to what extent wallpaper that reflects about 65-75% in the infra-red range by comparison with normal wallpaper that reflect only 3-5% of heat, has measurable positive effects on the thermoregulation of the human body and the human sensation of temperature. The measurements of skin temperature and heat flow intensity in the deeper areas of the body and the periphery, and metabolic heat conversion measurements (indirect calorimetry) confirm that infra-red reflection of the heat irradiated from the body lead to a measurable heat recovery on the body surface with a reduction of metabolic conversion. It was proved that it is possible to reduce the average room temperature by up to 4 K whilst maintaining the same degree of thermal comfort, which corresponds to a 20% saving in heating energy. (orig./BWI).
This paper introduces a parallel measurement approach for fast infrared-based human temperature screening suitable for use in a large public area. Our key idea is based on the combination of simple image processing algorithms, infrared technology, and human flow management. With this multidisciplinary concept, we arrange as many people as possible in a two-dimensional space in front of a thermal imaging camera and then highlight all human facial areas through simple image filtering, image morphological, and particle analysis processes. In this way, an individual's face in live thermal image can be located and the maximum facial skin temperature can be monitored and displayed. Our experiment shows a measured 1ms processing time in highlighting all human face areas. With a thermal imaging ca...
Effects of rolling conditions on warm deep drawability of cast magnesium alloy that were hot rolled after roll strip casting were investigated to ascertain the feasibility of twin-roll strip casting process of AZ31B magnesium alloy. Hot rolling and heat treatment conditions were changed to examine which conditions were appropriate for producing AZ31B wrought magnesium alloys after strip casting process. Microscopic observation of the crystals of the manufactured wrought magnesium alloys was performed. It has been found that a limiting drawing ratio of 2.7 was possible in a warm deep drawing test of the cast magnesium alloy sheets after being hot rolled. (orig.)
Changes in the properties of solonetzic soil associations (chestnut solonetzic soils and chestnut solonetzes) in the dry steppe after their reclamation have been studied for 30 years. The reclamation included the deep three-tier plowing and the approach of rotary tillage. A single rotary tillage operation resulted in the formation of fine aggregates of equal sizes in the plow layer; any morphological features of the restoration of solonetzic pedogenesis are absent. The atmospheric moisture easily penetrates into the soil, and soluble salts are leached off to a great depth. In 30 years since the soil amelioration with the use of a PMS-70 rotary tiller, the humus content has increased up to 3.3% in the upper 20-cm-thick layer and up to 2.4% in the layer of 20?40 cm. The content of adsorbed N...
Oct 20, 1997 ... The following requirements apply to the solar array: ..... housings will be coated with material meeting the program's outgassing requirements. ... The solar array temperature testing requirements will be determined by analysis. .... The ADS also generates attitude products for the project and science team. ...
Mar 2, 2011 ... CCT's software is capable of simultaneously handling incoming ... has been using CCTK to automate its remote control rocket cryogenic fueling systems. ... seismic, infrared, and proximity sensor data with auto-tracking ...
Jul 17, 2008 ... The first version uses a red-green-blue filter; the second, an infrared-green- blue. Videos credit: Donald J. Lindler, Sigma Space Corporation/GSFC; ... The video will help us connect a varying point of planetary light ...
We present photoelectric BVRI photometry for 16 T Tau and related stars in the Rho Oph dark cloud, as well as vidicon spectroscopic observations for nine stars. The color excesses of these stars favor circumstellar dust shells as the source of the observed infrared excesses.
IntroductionThe aim of this study was to evaluate the effects of red blood cell (RBC) transfusions on muscle tissue oxygenation, oxygen metabolism and microvascular reactivity in...Full Text Available
A new gadolinium chelating NIR fluorescent molecular probe increases T1 relaxivity of water protons, facilitating combined optical and magnetic resonance imaging.
Breath analysis is a powerful noninvasive technique for the diagnosis and monitoring of respiratory diseases, including asthma and chronic obstructive pulmonary disease (COPD). Nitric oxide...Full Text Available
We used the recuperation effect (see also 'Recuperation of infrared stimulated luminescence of feldspars' in this issue) for investigating the connection between infrared- and greenlight-stimulated luminescence (IRSL and GLSL) of feldspars by performing a 'double-bleach recuperation' experiment. A diode system was used for infrared (IR) stimulation, and a filtered-light unit for greenlight (GL) stimulation. Powdered feldspar samples (2 mg each) of known chemical characterisation from a mineral collection were used. After beta-irradiation with 180 Gy and storage in the dark for several weeks feldspar aliquots were bleached down to a residual level of {approx}1% of the initial level, first with IR and subsequently with GL. For both stimulations, detection of the stimulated luminescence was carried out in the near ultraviolet region (around 260-360 nm, peaked at 340 nm). Other aliquots were ...
We used the recuperation effect (see also 'Recuperation of infrared stimulated luminescence of feldspars' in this issue) for investigating the connection between infrared- and greenlight-stimulated luminescence (IRSL and GLSL) of feldspars by performing a 'double-bleach recuperation' experiment. A diode system was used for infrared (IR) stimulation, and a filtered-light unit for greenlight (GL) stimulation. Powdered feldspar samples (2 mg each) of known chemical characterisation from a mineral collection were used. After beta-irradiation with 180 Gy and storage in the dark for several weeks feldspar aliquots were bleached down to a residual level of #approx#1% of the initial level, first with IR and subsequently with GL. For both stimulations, detection of the stimulated luminescence was carried out in the near ultraviolet region (around 260-360 nm, peaked at 340 nm). Other aliquots were bleached in reverse order (1st GL, ...
BACKGROUND: Although the importance of lymphatic function is well recognized, the lack of real-time imaging modalities limits our understanding of its role in many diseases. In a phase...Full Text Available
Background and Objectives:Sound enamel manifests peak transparency in the near-IR (NIR) at 1310-nm, therefore the near-IR is ideally suited for high contrast imaging...Full Text Available
Infrared astronomical instruments require absorptive coatings on internal surfaces to trap scattered and stray photons. This is typically accomplished with any one of a number of black paints. Although inexpensive and simple to apply, paint has several disadvantages. Painted surfaces can be fragile, prone to shedding particles, and difficult to clean. Most importantly, the vacuum performance is poor. Recently a plasma enhanced chemical vapor deposition (PECVD) process was developed to apply thick (30 {micro}m) diamond-like carbon (DLC) based protective coatings to the interior of oil pipelines. These DLC coatings show much promise as an infrared black for an ultra high vacuum environment. The coatings are very robust with excellent cryogenic adhesion. Their total infrared reflectivity of < 10% at normal incidence approaches that of black paints. We measured outgas rates of <10{sup -12} Torr liter/sec cm{sup ...
Ultra-luminous infrared galaxies are among the most luminous objects in the local universe and are thought to be powered by intense star formation. It has been shown that in these objects the rotational spectral lines of molecular hydrogen observed at mid-infrared wavelengths are not affected by dust obscuration, leaving unresolved the source of excitation of this emission. Here I report an analysis of archival Spitzer Space Telescope data on ultra-luminous infrared galaxies and demonstrate that star formation regions are buried inside optically thick clouds of gas and dust, so that dust obscuration affects star-formation indicators but not molecular hydrogen. I thereby establish that the emission of H_2 is not co-spatial with the buried starburst activity and originates outside the obscured regions. This is rather surprising in light of the standard view that H_2 emission is directly associated with star-formation ...
Assessment of subtle changes in the primary macromolecular components of cartilage, proteoglycan (PG) and collagen, is critical for the diagnosis of early stages of osteoarthritis (OA), but...Full Text Available
Phonological density refers to the number of words that can be generated by replacing a phoneme in a target word with another phoneme in the same position. Although the precise nature of the...Full Text Available
Most Vega-like stars have far-infrared excess (60micron or longward in IRAS, ISO, or Spitzer MIPS bands) and contain cold dust (~ 4% of the stars in nearby young stellar associations.
... days after it burned, using a portable spectroradiometer (704 bands in the range 0.35 to 2.5 mu m) and an infrared thermometer (one band, 6 to 14 mu m). ...
Context: Mild primary hyperparathyroidism (PHPT) is characterized by asymptomatic hypercalcemia, most commonly in the absence of classical signs and symptoms. Hence, there is need to characterize...Full Text Available
The basic features and advantages of a turbodrill with a reducer insert are given, together with its characteristics in different compositions. The results of industrial tests of a test lot in three areas are given. The effectivenss of using a reducer turbodrill in super-deep holes is demonstrated.
Deep brain stimulation of the subthalamic nucleus (STN-DBS) is efficacious in treating the motor symptoms of Parkinson’s disease (PD). However, the impact of STN-DBS on the progression...Full Text Available
... presumed first instar Geocharidius. Anillines occur in deep forest litters, beneath rocks and in soil (endogean), or as ... their small size and cryptic mode of life. Forest litter inhabiting anillines ma...
This paper discusses the quality assurance requirements for high-level canistered waste form products which would be acceptable for disposal in a deep geologic repository. A review plan and guidelines are provided.
The present status of theoretical description of deep-inelastic lepton-nucleon as well as large angle Bhabha scattering with account for radiative corrections in the leading and next-to-leading approximations are reviewed. Also considered is a build-up principle and physical programme of the photon-photon colliders
Two gram-negative, motile bacteria isolated from deep subsurface sediments mineralized the nitrogen-containing polyaromatic hydrocarbon quinoline under aerobic conditions and transformed quinoline to...Full Text Available
The main subject of this thesis is the study of the hardronic final state in deep-inelastic electron-proton scattering. Theexperiment described in this thesis is performed with such a high resolution that the substructure of the proton is probed by the electron beam with a resolution of less than 10{sup -15} cm. (orig./HSI).
A 41-year-old white woman was referred to our Department to rule out the presence of a Fuch's corneal dystrophy. On slit-lamp biomicroscopy, small bilateral punctuate opacities appearing mostly in the...Full Text Available
From the gross conservation laws of thermodynamics in a convecting material we derive a bound on the ratio of the rate of production of mechanical or magnetic energy to the rate of internal radioactive...Full Text Available
... at depths greater than 29 m. Egmont Deep Seismic Stratigraphy Seismic profile data indicate that both the mouth ... 131. CrossRefDuncan, D. S. 1993. Neogene to Recent Seismic Stratigraphy of the Lower ...
Molecular life science is one of the fastest-growing fields of scientific and technical innovation, and biotechnology has profound effects on many aspects of daily life—often with deep, ethical...Full Text Available
IntroductionIn critically ill patients the relationship between the storage age of red blood cells (RBCs) transfused and outcomes are controversial. To determine if duration of RBC...Full Text Available
This report for the Swiss Federal Office of Energy (SFOE) describes the borehole that has been driven into the underlying crystalline rock of the Rhine valley near Basle. This work has been carried out within the framework of the 'Deep Heat Mining' project. The 2,755 metre deep borehole provides geological information essential for the realisation of a proposed geothermal power station using the 'Hot Dry Rock' process. The boring of the test borehole is described. The results obtained from samples taken from the test borehole and the measurements made in it are presented, including details on geological formations, temperature, gas measurements and rock strain values. The author is of the opinion that the chances of finding temperatures of at least 200 {sup o}C in a depth of 5 km - as foreseen in the 'Deep Heat Mining' project - can be considered as being quite high.
The soil-isolated strain XP was identified as Rhodococcus erythropolis. R. erythropolis XP could efficiently desulfurize benzonaphthothiophene, a complicated model sulfur compound that...Full Text Available
Previous ultrasound elasticity imaging experiments supported a generally accepted concept that the hardness of deep venous thrombi increases with thrombus aging. Results also showed that this...Full Text Available
RNAs transcribed from the mitochondrial genome of Physarum polycephalum are heavily edited. The most prevalent editing event is the insertion of single Cs, with Us and dinucleotides...Full Text Available
BackgroundMimivirus, a giant dsDNA virus infecting Acanthamoeba, is the prototype of the mimiviridae family, the latest addition to the family of the nucleocytoplasmic...Full Text Available
In this study we determined the composition and biogeochemistry of novel, brightly colored, white and orange microbial mats at the surface of a brine seep at the outer rim of the Chefren mud volcano....Full Text Available
BackgroundThe commonest pathogenic DMD changes are intragenic deletions/duplications which make up to 78% of all cases and point mutations (roughly 20%) detectable...Full Text Available
BackgroundDuring surgery, controlled haemostasis to prevent blood loss is vital for a successful outcome. It can be difficult to ligate vessels located deep in the abdomen. A device...Full Text Available
The description and results of the study on the free-electron laser (FEL) on 100 #mu#m, representing the first line of the FIAN multipurpose radiation complex, are presented. The electron beam with the energy of 6-8 MeV, once accelerated in a racetrack microtron and extracted into the FEL injection tract, is used for exciting this FEL. The system of the electron beam transport, injection and diagnostics are described. Additional works on increasing the beam emittance up to 0.4 A for one energy spread percent are carried out. The obtained electron beam parameters assure generation of the far infrared radiation in the FEL
Fourier Transform Infrared (FTIR) spectroscopy has been utilized during high rate E-beam evaporation/deposition of YBa2Cu3O7 (YBCO). The results demonstrate the great utility of FTIR as an in situ monitor of YBCO deposition and processing. We detect different (amorphous/fine polycrystalline) insulating pre-existing phases to the high Tc superconducting phase which appear to have distinct reflectivity fingerprints dominated by thin film interference effects, as a function of temperature and oxygen pressure. These fingerprints reveal some of the kinetic and thermodynamic pathways during the growth of YBCO.
In this paper we discuss recent work at the Advanced Technology Centre of BAE Systems on photonic technology, in particular photonic crystal fibres, applied to infra-red and electro-optic countermeasure systems. The use of Photonic Crystal fibres or holey fibres in countermeasure systems could significantly simplify platform integration by enabling remote location of laser sources, the generation of multiple wavelengths or continuum generation from a single pump source .The paper will describe the development of these fibres, drawing examples from recent civil collaborative research projects such as PFIDEL and LAMPS.
Hydroxyapatite samples were produced by two different wet-chemical methods, and characterized by x-ray diffraction, infrared and compression strength measurements. The x-ray diffraction measurements were simulated using the Rietveld method, and structural data as lattice parameters and average crystallite size were obtained. The infrared spectra showed the presence of CO$_3^{2-}$ ions in all samples, indicating a contamination by these ions. By mixing samples produced by both methods, a bioceramic was obtained and, after sintering, samples with very high compression strengths (26--30 MPa) were obtained.
Infrared (IR, 880 nm) stimulated luminescence (IRSL) signal was observed from quartz at room temperature. The characteristics of the signal such as its response to {gamma}-ray irradiation, thermal stability and thermal assistance energy show that the signal originates from different traps than those responsible for the luminescence signal stimulated by green light (GL, 514 nm). The IRSL signal's short lifetime (18 days at 15 deg. C) may have been the reason why it was not detected in previous experiments. The decay of the IR signal after GL illumination was observed. The thermoluminescence at 76 deg. C was enhanced after IR illumination.
Silicon nitride hybrid ball bearings used in high temperature applications undergo mechanical and environmental degradation. To study the surface chemistry of silicon nitride, a CAChe{trademark} Worksystem* has been used to generate the clusters and corresponding transmission vibrational spectra of silicon nitride. In the present study, the effect of surface conditions on the surface chemistry and wear degradation of silicon nitride was evaluated. Infrared reflection spectroscopy (IRRS) used to determine molecular orientations shows a difference in reflectance spectra for fractured and as-received.
BAE Systems is the leading producer of uncooled microbolometer based thermal imaging engines in the world. Initial investments to develop and produce uncooled infrared (IR) technology were primarily driven by military applications, but it was the commercial market with the potential for large product volumes which provided BAE Systems with the business model required for investment in uncooled IR technology. This paper reviews the heritage of BAE Systems technology and current products and is an example of the success of a Dual-Use technology area which DARPA invested in during the 1990s.
This paper describes a novel Fourier transform infrared (FTIR) spectroscopic method that can be used to rapidly screen soil samples from potentially hazardous waste sites. Samples are heated in a thermal desorption unit and the resultant vapors are collected and analyzed in a long-path gas cell mounted in a FTIR. Laboratory analysis of a soil sample by FTIR takes approximately 10 minutes. This method has been developed to identify and quantify microgram concentrations of explosives in soil samples and is directly applicable to the detection of selected volatile organics, semivolatile organics, and pesticides.
Total mercury content and its distribution in muscles and viscera of male and female blue crab (Callinectes sapidus Rothbum) and deep water pink shrimp (Parapenacus longirostris) collected from the 3 main fishing grounds near the Alexandria coast in the Mediterranean sea was estimated. The results indicate that the mercury content in the muscles of both species differ according to fishing areas, size, sex, and species. More than 75% of total mercury were accumulated in the viscera of both species which indicates that the mercury entered in these organisms via the feed chain. PMID:3696196
We report a 20-year-old woman who suffered headaches before presenting with a state of fluctuating vigilance. MRI showed diffuse high signal in the basal ganglia bilaterally on diffusion- and T2-weighted images, which had areas of both low and high apparent diffusion coefficient, presumed to correspond to cytotoxic and vasogenic oedema. MR venography showed no flow in the deep cerebral veins or straight sinus. Heparin was given, with clinical recovery. On follow-up MRI, the appearances became normal. (orig.)
In the development of a geothermal heat pump a water source heat pump was connected to a 1-1/2'' water line, 2200' long, buried in an endless loop 10' deep. The system is closed, circulating the same water continuously through the heat pump back to the field again. This water line 10' deep is the geothermal heat source. No matter how cold the air temperature gets on a winter day the water temperature to the heat pump will always be above 45/sup 0/F. This system has efficiently heated our house the past year using no supplemental heat.
The Infrared Camera (IRC) is one of the scientific focal plane instruments on board the ASTRO-F infrared astronomical satellite. The IRC is designed for wide field imaging and slit-less spectroscopic observations at near- and mid-infrared wavelengths. The IRC consists of three channels; NIR, MIR-S and MIR-L, each of which covers wavelengths of 2-5, 5-12 and 12-26 micron, respectively. All channels adopt compact refractive optical designs. Large format array detectors (a InSb 512 x 412 array and two Si:As IBC 256 x 256 arrays) are employed. Each channel has 10 x 10 arcminutes wide FOV with diffraction-limited angular resolution of 70cm aperture of the liquid helium cooled telescope at wavelengths over 5 micron. A 6-position filter wheel is placed at the aperture stop in each channel, and has three band-pass filters, two grisms/prisms and a mask for dark current measurements. The 5 sigma sensitivity of one pointed observation ...
Sulfuric acid and its partially or completely neutralized salts with ammonia are believed to result from the oxidation of sulfur dioxide in cloud water and in other heterogeneous media present in the atmosphere. Due to the natural abundance of ammonia and the ubiquitous presence of sulfur in the atmosphere, (NH/sub 4/)/sub 2/SO/sub 4/ is commonly the dominant chemical species in the ambient aerosol. The amounts of ammonium sulfates are expected to be very low in areas far removed from anthropogenic emissions of sulfur dioxide. The chemical composition of submicrometer aerosol particles was determined at the Mauna Loa Observatory (MLO) on Mauna Loa in Hawaii during an eight-day period in August 1986. The MLO site was selected for this measurement because it is the only ground-based aerosol observatory in the remote Pacific Ocean that allows extended sampling of aerosols in the free troposphere. Measurements were made using an attenuated total internal reflection (ATR) impactor system. ...
A petrographic comparison of Triassic, fluvial sandstones from the Deep River Basin in the eastern piedmont of North Carolina with nearby Holocene stream sands (1) indicates that he Triassic climate was more arid than today's and (2) distinguishes an eastern, more plutonic terrane from a western, more metamorphic source terrane. The paleoclimatic interpretation is based on differences in framework composition between modern and ancient sands of the same grain size, derived from the same rock type, transported similar distances and deposited in similar settings. The Triassic sandstones contain more lithic-fragments but less quartz than otherwise equivalent, modern sand in the Deep River Basin. Feldspar content is more complex, controlled by both source-rock composition and climate. Sand from the more plutonic terrane contains more feldspar and plutonic lithic-fragments than sand from the more metamorphic terrane, which contains more ...
CNPT-3 is the laboratory designation of a strain of bacteria that reproduces best at deep-sea pressures. It was isolated from a sample collected at a 5800 m depth of the Pacific Ocean. This isolation was achieved from a sample that had been retrieved without warning. This year we demonstrated that there are similarly behaving bacteria that can be isolated from samples even when retrieved with decompression. The purpose of this project was to define the temperatures and pressures over which CNPT-3 can exist and function. (1) At 2"0C CNPT-3 is eurybathic from about 1000 to 6500 m, as judged from an only slightly pressure dependent generation time. (2) CNPT-3 is unquestionably barophilic at 2"0C, with doubling times of 9 hours at 580 bars and over 18 hours at 1 bar. (3) At 10"0C, reproduction is adversely affected at 1 bar to the extent that CNPT-3 becomes obligately barophilic at 10"0C. Yet reproduction is enhanced above 280 bars and occurs with a regeneration time ...
Nitromethane (CH(3)NO(2)) and its chlorinated analogue, chloropicrin (CCl(3)NO(2)), were photolyzed at 193, 248, and 266 nm, and the products were observed by time-dependent Fourier transform infrared emission spectroscopy. At 193 and 248 nm, the primary photodissociation pathway for nitromethane was cleavage of the C-N bond to produce CH(3) + NO(2)(A (2)B(2)). At 266 nm, weak emission was observed following photodissociation of nitromethane, but an infrared spectrum could not be obtained. The photodissociation of chloropicrin at 193 nm produced the analogous product channel CCl(3) + NO(2)(A (2)B(2)) in addition to several other product channels. At 248 and 266 nm, only CCl(3) + NO(2)(A (2)B(2)) was observed. The production of phosgene (CCl(2)O) from chloropicrin photodissociation was not observed in this study. PMID:16571044
A strong dependence of thermal activation energy (TAE) on infrared (IR) stimulation time for the infrared stimulated luminescence (IRSL) signal was observed for K-feldspar grains extracted from several sediments and granites from China. A TAE value as low as {approx}0.1 eV was observed at the beginning of IR stimulation and increased to {approx}0.45 eV after 90 s. For a trap depth of {approx}2 eV below the conduction band for the IRSL traps, the TAE value of {approx}0.45 eV is consistent with the energy gap between the excited states ({approx}0.5 eV below the conduction band) and conduction band. This phenomenon is explained as the result of the coexistence of thermally assisted recombination via conduction band or band-tail states hopping and athermal tunnelling recombination of electrons from the excited states under IR stimulation, leading to the observation of a higher anomalous fading rate in the initial part of the IRSL decay curve.
We present a Hubble Space Telescope image of the FRII radio galaxy 3C 401, obtained at 1.6 microns with the NICMOS camera in which we identify the infrared counterpart of the brightest region of the radio jet. The jet has a complex radio structure and brightens where bending occurs, most likely as a result of relativistic beaming. We analyze archival data in the radio, optical and X-ray bands and we derive its spectral energy distribution. Differently from all of the previously known optical extragalactic jets, the jet in 3C401 is not detected in the X-rays even in a long 48ksec X-ray Chandra exposure and the infrared emission dominates the overall SED. We propose that the dominant radiation mechanism of this jet is synchrotron. The low X-ray emission is then caused by two different effects: i) the lack of any strong external photon field and ii) the shape of the electron distribution. This affects the location of the synchrotron peak in the ...
We present our discovery of a narrow-line Baldwin effect, an anti-correlation between the equivalent width (EW) of a line and the flux of the associated continuum, in 5-20$\\mu$m mid-infared lines from a sample of 68 Active Galactic Nuclei (AGN), located at z$<$0.5, observed with the Infrared Spectrograph on the {\\it Spitzer Space Telescope}. Our analysis reveals a clear anti-correlation between the EW of the [SIV] 10.51$\\mu$m, [NeII] 12.81$\\mu$m, and [NeIII] 15.56$\\mu$m lines and their mid-IR continuum luminosities, while the Baldwin effect for [NeV] 14.32$\\mu$m is not as obvious. We suggest that this anti-correlation is driven by the central AGN and not circumnuclear star formation in the host galaxy. We also find that the slope of the narrow-line Baldwin effect in the mid-infrared does not appear to steepen with increasing ionization potential. Examining the dependence of the EW to the Eddington Ratio ($L/L_{Edd}$) we find no strong ...
We investigate the influence of lunar-like satellites on the infrared orbital light curves of Earth-analog extra-solar planets. Such light curves will be obtained by NASA's Terrestrial Planet Finder (TPF) and ESA's Darwin missions as a consequence of repeat observations to confirm the companion status of a putative planet. We use an energy balance model to calculate disk-averaged infrared (bolometric) fluxes from planet-satellite systems over a full orbital period (one year). The satellites are assumed to lack an atmosphere, have a low thermal inertia like that of the Moon and span a range of plausible radii. The planets are assumed to have thermal and orbital properties that mimic those of the Earth while their obliquities and orbital longitudes of inferior conjunction remain free parameters. Even if the gross thermal properties of the planet can be independently constrained (e.g. via spectroscopy or visible-wavelength detection of specular ...
The highly irradiated transiting exoplanet, HAT-P-7b, currently provides one of the best opportunities for studying planetary emission in the optical and infrared wavelengths. We observe six near-consecutive secondary eclipses of HAT-P-7b at optical wavelengths with the EPOXI spacecraft. We place an upper limit on the relative eclipse depth of 0.055% (95% confidence). We also analyze Spitzer observations of the same target in the infrared, obtaining secondary eclipse depths of 0.098+/-0.017%, 0.159+/-0.022%, 0.245+/-0.031% and 0.225+/-0.052% in the 3.6, 4.5, 5.8 and 8.0 micron IRAC bands respectively. We combine these measurements with the recently published Kepler secondary eclipse measurement, and generate atmospheric models for the day-side of the planet that are consistent with both the optical and infrared measurements. The data are best fit by models with a temperature inversion, as expected from the high incident ...
Context. We present a multi-wavelength, high-resolution observational survey of the young binary system Haro 6-10 (GV Tau, IRAS 04263+2426), which is harbouring one of the few known infrared companions. Aims. The primary goal of this project is to determine the physical and geometrical properties of the circumstellar and circumbinary material in the Haro 6-10 system. Methods. High-resolution optical (HST/WFPC2) and near-infrared (VLT/NACO) images in different bands were analysed to investigate the large-scale structures of the material around the binary.Mid-infrared interferometry (VLTI/MIDI) and spectroscopy (TIMMI2 at the 3.6m ESO telescope) were carried out to determine the structure and optical depth of the circumstellar material around the individual components. Results. The multi-wavelength observations suggest that both components of the binary system Haro 6-10 are embedded in a common envelope. The measured ...
In VHTGR (Very High Temperature Gas-cooled Reactor), the radiation plays an important role in heat transfer through the cavity in RCCS (Reactor Cavity Cooling System). We performed the series of experiments to measure the emissivity using the infrared thermometer with wavelength range of 8#approx#14 #mu#m. As the first step, the transmittance of Zinc Selenide (ZnSe) window was measured to estimate the emissivity that can compensate the attenuation effect of window. The kind of gas with various concentrations in the cavity will be released during postulated accidents to the coolant type, so it is essential to estimate the effects of gas on the measurement of emissivity. In this manner we measured the emissivity with the air, the helium and the steam inside chamber. The results represent that the concentration of the air and the helium do not affect the emissivity significantly while the steam decreases the measured emissivity relatively. It means that the air and ...
We search for an infrared signature of the transiting extrasolar planet HD 209458b during secondary eclipse. Our method, which we call `occultation spectroscopy,' searches for the disappearance and reappearance of weak spectral features due to the exoplanet as it passes behind the star and later reappears. We argue that at the longest infrared wavelengths, this technique becomes preferable to conventional `transit spectroscopy'. We observed the system in the wing of the strong nu-3 band of methane near 3.6 microns during two secondary eclipses, using the VLT/ISAAC spectrometer at a spectral resolution of 3300. Our analysis, which utilizes a model template spectrum, achieves sufficient precision to expect detection of the spectral structure predicted by an irradiated, low-opacity (cloudless), low-albedo, thermochemical equilibrium model for the exoplanet atmosphere. However, our observations show no evidence for the presence of this spectrum ...
the development of lithium metal batteries is hindered by the bad reversibility of the Li{sup +}/Li pair, due to dendrites formation which limits the amount of active matter and can generate short-circuits. The chemical and electrochemical phenomena which take place at the electrode/organic electrolyte interface lead to the formation of a complex passivation film which is of prime importance for the functioning of this type of batteries. The in-situ infrared reflection spectroscopy is well adapted to the chemical study of the passivation layer. Two different techniques were used: the substraction normalized interfacial transform infrared spectroscopy (SNIFTIRS) and the electro-chemically modulated infrared reflectance spectroscopy. These methods have shown that the passivation layer that develops on the surface of the lithium electrode in contact with organic solutions (propylene carbonate, ethylene carbonate and ...
We describe the flight performance of the cryogenic system of the infrared astronomical satellite AKARI, which was successfully launched on 2006 February 21 (UT). AKARI carries a 68.5 cm telescope together with two focal plane instruments, Infrared Cameras (IRC) and Far Infrared Surveyor (FIS), all of which are cooled down to cryogenic temperature to achieve superior sensitivity. The AKARI cryogenic system is a unique hybrid system, which consists of cryogen (liquid helium) and mechanical coolers (2-stage Stirling coolers). With the help of the mechanical coolers, 179 L (26.0 kg) of super-fluid liquid helium can keep the instruments cryogenically cooled for more than 500 days. The on-orbit performance of the AKARI cryogenics is consistent with the design and pre-flight test, and the boil-off gas flow rate is as small as 0.32 mg/s. We observed the increase of the major axis of the AKARI orbit, which can be explained by the ...
Microwave dielectric properties and far-infrared reflectivity spectra of (Zr{sub 0.8}Sn{sub 0.2})TiO{sub 4} ceramics with 1.0mol.% Sb{sub 2}O{sub 5} or WO{sub 3} were investigated in the various sintering atmospheres. The Q{center_dot}f value of the specimens sintered in oxygen atmosphere was enhanced due to the decrease of lattice anharmonic interaction resulting from the decrease of oxygen vacancies, whereas the dielectric constants remained constant regardless of sintering atmosphere. The effects of the sintering atmosphere on the changes of ionic and electronic polarization and the intrinsic microwave losses of the specimens were investigated by using the infrared reflectivity spectra from 50 to 4000cm{sup -1}, which were evaluated using Kramers-Kronig analysis and classical oscillator model. The relative tendency of microwave dielectric properties of the specimens calculated from the reflectivity data was in good agreement with the results ...
We present the discovery of a Baldwin effect in 8 nearby Seyfert galaxies for the three most prominent mid-infrared forbidden emission lines observable from the ground that are commonly found in AGN, [ArIII](8.99 micron), [SIV](10.51 micron), and [NeII](12.81 micron). The observations were carried out using the VLT/VISIR imager and spectroraph at the ESO/Paranal observatory. The bulk of the observed line emission comes from the inner <0.4 arcsec which corresponds to spatial scales <100 pc in our object sample. The correlation index is approximately -0.6 without significant difference among the lines. This is the strongest anti-correlation between line equivalent width and continuum luminosity found so far. In the case of Circinus, we show that despite the use of mid-infrared lines, obscuration by either the host galaxy or the circumnuclear dust torus might affect the equivalent widths. Given the small observed spatial scales from which ...
Extensive investigations have been and are being carried out on a stiff clay from an underground research laboratory located at Mol (Belgium) called Boom clay, in the context of research into deep nuclear waste disposal. Suction effects in deep Boom clay block samples were investigated through the characterisation of the water retention and of the swelling properties of the clay. The data obtained allowed an estimation of the sample initial suction that was reasonably compatible with the in-situ state of stress at a depth of 223 m. The relationship between suction and stress changes during loading and unloading sequences were also examined by running oedometer tests with suction measurements. A rather wide range of the ratio s/sigma 'v (being s the suction and sigma 'v the effective vertical stress) was obtained (0.61 - 1), different from that proposed by Bishop et al; (1974). Finally, the effect of suction release under an isotropic stress ...
The effect of molybdenum on the electronic structure of the passive films formed on ferritic (Fe-Cr and Fe-Cr-Mo) stainless steels is examined by capacitance and photoelectrochemical measurements. The capacitance study is supported by a mathematical analysis of the Schottky barrier developed at the semiconductor-electrolyte interface in the case of a semiconductor with multiple bulk electronic states in the bandgap. The numerical simulations, based on the more general Mott-Schottky relation proposed, are in good agreement with the experimental results. It can be concluded that the capacitance behavior of the passive films is related to the contributions of a shallow donor level very close to the conduction band and a deep donor level at about 0.4 eV below the conduction band. The addition of molybdenum decreases the donor density of the deep level. Photoeffects observed for subbandgap photon energies reveal that this deep ...
The second and third member of the Qingshankou Formation recovered by CCSD-SK-Is borehole (China Cretaceous Continental Scientific Drilling-SongkeI-the south borehole) is 415.61 m long and 100% of cores recovery. The age of the member corresponds approximately to the Coniacian. The sequence and process of lithology-lithofacies and cyclic stratigraphy were revealed by a detailed core description. 12 rock types and 2 kinds of sedimentary subfacies including semi-deep lake and shallow lake were recognized from the drilling core of the second and third member of the Qingshankou Formation. 10 sedimentary microfacies are present, including dolomite, marl, limestone, oil shale, semi-deep lake turbidite, volcanic ash, seismite, semi-deep lake mudstone, shallow lake mudstone, and shallow lake turbi...
A model is presented that describes the development of texture during the production process of bake-hardening steel recrystallized in a batch-annealing furnace. Proper conditions are analyzed to generate a pronounced {gamma}-fiber texture and a pancake microstructure that shows superior deep drawability. The {gamma}-fiber texture is assumed to be caused by the interaction between tertiary precipitating aluminum nitride particles and the recrystallization process during heating in the furnace. Deep drawability is presented in terms of the logarithmic {gamma}- and {alpha}-fiber X-ray intensity ratio. The computer simulation of the coupled aluminum nitride precipitation and recrystallization kinetics is based on an iterative procedure. A comparison between simulation results and available experimental data proves the ability of the model to predict the final deep drawability, taking into account the initial aluminum and ...
A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400/sup 0/C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures.
This paper presents a method to evaluate and improve the performance of quantum dot infrared photodetectors (QDIPs). We proposed a device model for QDIPs. The developed model accounts for the self-consistent potential distribution, features of the electron capture and transport in realistic QDIPs in dark and illumination conditions. This model taking the effect of donor charges on the spatial distribution of the electric potential in the QDIP active region. The model is used for the calculation of the dark current, photocurrent and detectivity as a function of the structural parameters such as applied voltage, doping QD density, QD layers, and temperature. It explains strong sensitivity of dark current to the density of QDs and the doping level of the active region. In order to confirm our...
Earth degassing specifically of carbon dioxide CO2 is of increasing interest with respect to the global carbon budget, related climate effects, earthquake and volcano eruption mechanisms, as well as plant physiological reactions in gas-rich environments. Investigations in all of these disciplines require the detection of surface CO2 degassing structures and quantification of their emissions. We introduce minimal thermal change detection based on infrared imaging as a new remote sensing tool for the detection of earth surface thermal anomalies suiting among others to discover earth degassing locations of any origin. The method allows for seamless areal search and monitoring of degassing structures in any terrain. As proof of concept infrared imaging measurements were performed at the Bossol...
The objective of this study was to determine whether walking and running at different treadmill speeds resulted in different metabolic and cardiovascular responses in the vastus lateralis (VL) and lateral gastrocnemius (LG) by examining metabolite accumulation and tissue oxygen saturation. Ten healthy subjects (6 males, 4 females) completed a submaximal treadmill exercise test, beginning at 3.2?km?h?1 and increasing by 1.6?km?h?1 increments every 3?min until reaching 85% of age-predicted maximal heart rate. Muscle tissue oxygenation (SO2), total hemoglobin (HbT) and interstitial hydrogen ion concentration ([H+]) were calculated from near infrared spectra collected from VL and LG. The [H+] threshold for each muscle was determined using a simultaneous bilinear regression. Muscle and treadmil...
Fourier-transform infrared (FTIR) spectroscopy was used to monitor amino acids, organic acids, and changes during ripening. Twelve Cheddar cheese samples were ripened for 73 days and samples were drawn periodically. Water-soluble fractions of samples were analyzed by gas chromatography (20 amino acids), liquid chromatography (three organic acids), and FTIR spectroscopy (4000-700 cm-1). Spectra were correlated with chromatographic data and ripening events and analyzed by multivariate statistics to develop prediction and classification models. Most models showed a good fit (correlation coefficient > or =0.89) and could predict the levels of amino acids and organic acids and age of the cheese in less than 20 min. Lactic acid, leucine, glutamic acid, asparagine, phenylalanine, and valine were ...
In this article, we investigate the "naive non-abelianization" (NNA) contributions of the higher-twist Feynman diagrams to the large-$p_T$ inclusive pion production cross section in proton-proton collisions and present the general formulae for the higher-twist differential cross sections in the case of the running coupling and frozen coupling approaches. We compared the resummed "naive non-abelianization" higher-twist cross sections with the ones obtained in the framework of the frozen coupling approach and leading-twist cross section. The structure of infrared renormalon singularities of the higher twist subprocess cross section and it's resummed expression (the Borel sum) are found. It is shown that the resummed result depends on the choice of the meson wave functions used in the calculations. We discuss the phenomenological consequences of possible higher-twist contributions to the meson production in proton-proton collisions in within NNA at RHIC.
The high-frequency data from 12 sensors at the ITCE 1976 are analyzed to determine the Kolmogoroff constants for velocity, temperature and humidity fluctuations, ..cap alpha../sub u/, ..cap alpha../sub T/, and ..cap alpha../sub q/. The occurrence of aliasing in the spectral analysis in some cases together with the limited response of some sensors at the higher frequencies introduces some uncertainties into the analysis. The Soviet sonic anemometer, fine-wire thermometer and infrared hygrometer and the Australian infrared hygrometer provide the best information, namely that: ..cap alpha../sub u/ = 0.59 +/- 0.01, ..cap alpha../sub T/ = 0.68 +/- 0.02, ..cap alpha../sub q/ = 0.76 +/- 0.03, where the errors quoted refer solely to statistical errors. The other instruments provide general support to these values. The technique of using spectral density measurements to determine eddy fluxes is illustrated.
We report novel, high-angular resolution interferometric measurements that imply the near-infrared nuclear emission in NGC 4151 is unexpectedly compact. We have observed the nucleus of NGC 4151 at 2.2 microns using the two 10-meter Keck telescopes as an interferometer and find a marginally resolved source ~0.1 pc in diameter. Our measurements rule out models in which a majority of the K band nuclear emission is produced on scales larger than this size. The interpretation of our measurement most consistent with other observations is that the emission mainly originates directly in the central accretion disk. This implies that AGN unification models invoking hot, optically thick dust may not be applicable to NGC 4151.
Efficient, low-temperature conversion of infrared light into visible light (red, orange, green) is reported at single heterojunctions and undoped quantum wells of GaAs and ordered Al_xGa_1_-_xInP_2; an increase in photon energy of 700 meV is obtained. The signal originates from the high-band-gap layers and disappears only if the excitation energy is tuned below the GaAs band gap. The intensity of the up-converted photoluminescence (PL) is found to decrease significantly slower with increasing temperature than that of the regular PL and it remains observable up to 200 K. Interface-induced cold Auger processes along with the presence of trapped states for both electrons and holes in these ordered alloys account for this nonlinear mechanism. A colinear double-beam experiment confirms this. copyright 1996 The American Physical Society.
The effect of varying pD(11-13,7) on the reaction of hydrogen with (Co/sup 11/(CN)/sub 5/)/sup 3/- in deuterium oxide has been studied by using infrared spectroscopy to determine the ratio of (Co/sup 111/(CN)/sub 5/X)/sup 3/- (X=H,D) in the solids precipitated from the steady state under hydrogen. The results show that the uptake of hydrogen does not liberate a free proton and that the rate of (Co/sup 111/(CN)/sub 5/H)/sup 3/- -D/sub 2/,0 exchange increases with pD but becomes pD independent at pD 7 greater than 13,5.
The n3 and n4 vibrational transitions of CH3 and CD3 isolated in solid parahydrogen were studied by high-resolution infrared spectroscopy. The radicals were produced by in situ UV photolysis of methyl iodides trapped in solid parahydrogen. The observed spectra showed clear rotational fine structures, which were subjected to further splitting due to the electrostatic field of solid parahydrogen. The molecular constants and crystal field parameters of the radicals in solid parahydrogen were determined by analyzing the spectral structures of the n3 and n4 transitions of CD3 by the crystal field theory. The rotational constants of the CD3 radical were found to be only a few percent smaller than those in the gas phase. The determined crystal field parameters indicated significant quantum effect...
An 80 keV, 3.6 MW neutral beam injection system has recently been installed on Doublet III, and the installation of a second system is scheduled within several months. Armor plate consisting of /approximately equals/100 graphite tiles (10 cm x 10 cm) coated with TiC has been plated over portions of the inner vacuum wall lying in the line of sight of the ion sources. In order to monitor the condition of the armor plate an infrared camera and a set of optical pyrometers have been installed alongside the beamline and view the armor plate through a CaF/sub 2/ window. The pyrometers measure the temperature of the armor plate associated with the maximum of the intensity distribution of each ion source.
In a laser system for converting infrared laser light waves to visible light comprising a source of infrared laser light waves and means of harmoic generation associated therewith for production of light waves at integral multiples of the frequency of the original wave, the improvement of said means of harmonic generation comprising a crystal having the chemical formula X.sub.2 Y(NO.sub.3).sub.5 .multidot.2 nZ.sub.2 o wherein X is selected from the group consisting of Li, Na, K, Rb, Cs, and Tl; Y is selected from the group consisting of Sc, Y, La, Ce, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga, and In; Z is selected from the group consisting of H and D; and n ranges from 0 to 4.
It is known that the plant cuticle represents the first barrier that must be overcome by any chemical reaching the plant surface from the atmosphere before entering the plant. Because of the importance of the cuticle as a barrier to penetration of a wide variety of compounds, its morphology, chemistry, and permeability have been extensively studied. However, only limited information is available on the nature of functional chemical groups present and their interaction and role during the penetration process. The usefulness of in situ Fourier transform infrared spectroscopy studies in identifying functional groups present in isolated cuticles is described and their relationships to the structure of the cuticular membrane are discussed. Applications of infrared spectroscopy on the presence and role of phenolics in the cuticle structure and during the cuticle development, nitrogen oxide binding to isolated cuticles, and the interactions between ...
Disclosed is a gas-fired cooktop for a range which provides high thermal efficiency and low emissions of air pollutants, particularly low levels of NO{sub x}. The cooktop includes a perforated tile burner which radiates infrared energy upward at a high flux rate to rapidly quench burner gas temperatures and inhibit the formation of NO{sub x}. A perforated glass-ceramic jet plate positioned between the burner and a cooking vessel transmits most of the radiant infrared energy from the burner to the vessel and also forms jets of combustion products which are directed against the bottom of the vessel fo convective heating. Thermal efficiencies of up to about 70% and NO{sub x} emissions as low as about 15ppM are achieved by the cooktop.
The simultaneous hydrogen and silicon atom densities in amorphous silicon, a-Si, films prepared by the glow discharge technique have been measured by 25 MeV #alpha#-particle elastic scattering. Integrated band intensities for the silicon-hydrogen stretching modes, #omega#_1sup(s) and #omega#_2sup(s) in the region 1800 to 2200 cm"-"1 were determined for the same freely supported films. A similar analysis has been carried out for the bands observed at 890, 840 and 640 cm"-_1. Effective oscillator strengths for the #omega#_1sup(s) and #omega#_2sup(s) modes in a-Si films have been estimated and compared with the current theories on the effect of the silicon matrix on the infrared absorption characteristics. (author).
The preliminary design of a far-infrared free-electron laser with a Coaxial Hybrid Iron (CHI) wiggler is presented. The CHI wiggler consists of a central rod and outer ring of alternating ferrite and dielectric spacers. A periodic wiggler field is produced when the CHI structure is immersed in an axial magnetic field. The design under investigation makes use of 1A, 1MV annular electron beam interacting with the TE{sub 01} coaxial waveguide mode at approximately 1 THz ({lambda} = 300 {mu}m). The nominal wiggler period is 0.5 cm and the inner and outer waveguide radii are 0.4 and 0.8 cm, respectively. An axial guide field of 5-10 kG is used. The device performance is modeled with slow-time-scale nonlinear code. Self fields and axial velocity spread are included in the model. Theoretical results will be presented.
In this study, thermoluminescence (TL) dating of archaeological artefacts from Geboltskirchen (Upper Austria) and Haselbach (Lower Austria) has been carried out. To receive a comparison with TL dating, all samples have been investigated additionally by means of infrared-stimulated luminescence (IRSL) analysis. The samples were prepared according to the common fine-grain technique. All important dating parameters such as potassium concentration, thorium/uranium ratio, moisture content, etc. were determined. A methodology for IRSL was developed, describing all steps of the procedure from sample preparation to measurement for any kind of ceramic artefacts. Dating results from TL and IRSL investigations of ancient pottery from Geboltskirchen and Haselbach will be discussed.
The characteristics of infrared-stimulated luminescence (IRSL) from a sample of potassium feldspar at low temperatures are presented. These studies extend the previous work from this laboratory on the optical bleaching characteristics and emission spectra of feldspars at room temperature and recent measurements of the stimulated spectrum for a sample of potassium feldspar at room temperature. Stimulation spectra have been measured at 290, 160 and 145 K. By fitting Gaussian functions to the spectra, the peak position is shown to shift to higher photon energies at lower temperatures and the full-width half-maximum of the peak to reduce with decreasing temperature. The variation of IRSL intensity with temperature for several stimulating wavelengths has been determined and the form of the IRSL decay curve measured at 290 and 160 K. No substantial differences were observed in the form of the decay curves at each temperature. (author).
We have developed efficient spectrally selective infrared (IR) emitters that can be utilized for thermophotovoltaic (TPV) power generation by using stainless steel (SUS304) substrates coated with b- FeSi2 thin films. To develop spectrally selective emitters, we theoretically propose antireflection (AR) coatings consisting of a single layer of a dielectric material having a high refractive index (~5) and are appropriate for use with metals such as stainless steels in the IR region. This type of AR coating is fabricated by sputtering a b- FeSi2 thin film on a polished SUS304 substrate. The reflectance in the IR region is successfully reduced to less than 10%. In addition, the AR properties are stable even at 700 K in air. Therefore, metals with AR coatings of b- FeSi2 can be applied to IR em...
Thrust faulting, folding, and penetrative compressional fabrics (e.g. spaced cleavage, pencils, and coal cleats) have been found in several outcrops within the central Deep River Basin (the southern Durham subbasin to the northern Wadesboro subbasin). The trend of these structures is nearly parallel to the basin, and may locally control the present geometry of the basin boundaries. These features are distributed throughout the stratigraphic section and across the entire width of the basin. In outcrops where relative timing can be determined, the compressional structures post-date all extensional and intrusive features associated with basin formation. In particular, thrusts cut across and displace basin-parallel normal faults and basin-normal cross-faults. All thrusts found to date verge northwest, and displacements of cross-fault boundaries indicate that transport was approximately 325[degree].
The need for alternative energy increases steadily???especially due to the climate change and the limited availability of fossil fuels. Geothermal power uses the intrinsic heat which is stored in the accessible part of the Earth???s crust. Its importance among the renewable energy resources originates from the almost unlimited energy supply of the Earth and its independence from external influences such as seasonal or even daily climatic variability. Nevertheless, there are risks which have to be assessed. From a mathematical point of view there are four building blocks of the characterization of deep geothermal systems: seismic exploration, gravimetry, modeling transport processes, and modeling the stress field. In particular, local depletion poses a significant risk during the industrial...
We present a strong-weak coupling duality for quantum mechanical potentials. Similarly to what happens in quantum field theory, it relates two problems with inverse couplings, leading to a mapping of the strong coupling regime into the weak one, giving information from the nonperturbative region of the parameters space. It can be used to solve exactly power-type potentials and to extract deep information about the energy spectra of polynomial ones. We present a strong-weak coupling duality for quantum mechanical potentials. Similarly to what happens in quantum field theory, it relates two problems with inverse couplings, leading to a mapping of the strong coupling regime into the weak one, giving information from the nonperturbative region of the parameters space. It can be used to solve exactly power-type potentials and to extract deep information about the energy spectra of polynomial ones.
The passive films formed on 316L stainless steel in various NaCl solutions have been investigated by capacitance measurements (Mott-Schottky). Pitting parameters have been determined using the galvano-kinetic polarisation method. The obtained results reveal the existence of a shallow and a deep donor level localised in the band gap of the semiconducting oxide film. These energy levels are due to iron ions in the tetrahedral and octahedral positions. It also appears that the participation of the deep donor level effects the electric field. The study developed allows us to compare characteristic parameters of the electronic structure of the passive film to those related to pitting susceptibility. (authors) 25 refs.
The Department of Energy has issued a Quality Assurance (QA) specification for organizations involved in making a canistered high-level waste form product that is acceptable for storage in a deep geologic federal repository. The logic for the waste form acceptance process is described. In addition to NQA-1 requirements, fourteen supplemental QA requirements have been drafted to fit the waste form production process. A review plan for assuring complicance with the QA specification is provided. Guidelines for preparation of a waste form producer QA program are also presented. It is expected that the QA program description that result will be influential in supporting the acceptybility of the product to OCRWM and for ultimate disposal of the high-level waste in a deep geologic repository. (author) 3 figs., 4 refs.
After the successful completion of the development program of the 2000 m water depth HVDC Hawaii Deep Water Self Contained Fluid Filled Cable, the interconnection between Hawaii island and Oahu island is examined. Thermal, electrical, mechanical, hydraulic, corrosion, length aspects are developed for both fluid filled and paper impregnated (SOLID) cables which are foreseen in different portions of the approximately 250 km length connection. Considerations are also presented for the requirements of the cable ship: 12 m sheave diameter, 7000 t capacity for the rotating platform. The feasibility of manufacturing, transporting and laying such cables within a practical schedule is discussed in this paper.
The goal of the work this quarter has been to partition and high-grade the Greater Green River basin for exploration efforts in the Upper Cretaceous tight gas play and to initiate resource assessment of the basin. The work plan for the quarter of July 1-September 30, 1998 comprised three tasks: (1) Refining the exploration process for deep, naturally fractured gas reservoirs; (2) Partitioning of the basin based on structure and areas of overpressure; (3) Examination of the Kinney and Canyon Creek fields with respect to the Cretaceous tight gas play and initiation of the resource assessment of the Vermilion sub-basin partition (which contains these two fields); and (4) Initiation analysis of the Deep Green River Partition with respect to the Stratos well and assessment of the resource in the partition.
Lateral plume dispersion in deep river valleys during neutral and stable lapse rate conditions can be exceptionally high due to the intense horizontal turbulence generated by prominent variations in the width, orientation and surface roughness of the valley walls. Use of the standard Gaussian dispersion equation to represent this enhanced lateral plume spread in a narrow valley may be inappropriate since consideration should also be given to the restriction of the horizontal plume spread due to impingement against the valley walls. The basic concept employed in the modification of the Gaussian dispersion equation was to assume that multiple eddy reflections occur between the valley walls in a manner similar to the vertical eddy reflections between the ground plane and an inversion layer aloft. The expressions are developed, but no attempt has been made to validate them with actual measured field data. 4 references, 3 figures, 1 table.
Deep inelastic {ital e}{sup {minus}}{ital p} scattering has been studied in both the charged current (CC) and neutral current (NC) reactions at momentum transfers squared {ital Q}{sup 2} above 400GeV{sup 2} using the ZEUS detector at the HERA {ital ep} collider. The CC and NC total cross sections, the NC to CC cross section ratio, and the differential cross sections {ital d}{sigma}/{ital dQ}{sup 2} are presented. From the {ital Q}{sup 2} dependence of the CC cross section, the mass term in the CC propagator is determined to be {ital M}{sub {ital W}}=76{plus_minus}16{plus_minus}13 GeV.
Shallow-diving, coastal bottlenose dolphins (Tursiops truncatus) and deep-diving, pelagic pygmy and dwarf sperm whales (Kogia breviceps and K. sima) will experience vastly different ambient pressures at depth, which will influence the volume of air within their lungs and potentially the degree of thoracic collapse they experience. This study tested the hypotheses that lung size will be reduced and/or thoracic mobility will be enhanced in deeper divers. Lung mass (T. truncatus, n = 106; kogiids, n = 18) and lung volume (T. truncatus, n = 5; kogiids, n = 4), relative to total body mass, were compared. One T. truncatus and one K. sima were cross-sectioned to calculate lung, thoracic vasculature, and other organ volumes. Excised thoraxes (T. truncatus, n = 3; kogiids, n = 4) were mechanically ...
New photometric observations of the variable star FG Sge, a rapidly evolving planetary nebula nucleus, were performed in 2003?2008. On 230 nights, we obtained 86 UBV and 155 BV RI (or R c , I c ) magnitude estimates. The maximum amplitude of the V-band light variations was >8 m . Six deep minima and four high maxima were observed. Analysis of the light curve has shown that the pulsation period of the star remained constant since 1991 and was P = 115 days. We have studied the wavelength dependence of the extinction at various phases of the light curve. The blueing of the B-V color at deep minima is interpreted as the result of light scattering in the circumstellar dust shell of the star formed by preceding dust ejections since 1992. Our spectroscopic observations performed on nine nights in...
Geothermal energy appears as a viable economic alternative among the different renewable energy sources. The French bureau of geological and mining researches (BRGM) is involved in several research and development programs in the domain of geothermal energy and underground reservoirs. This document presents the content of 5 programs: the deep hot dry rock system of Soultz-sous-Forets (construction and testing of the scientific pilot, modeling of the reservoir structure), the development of low and high enthalpy geothermal energy in the French West Indies, the comparison of the geothermal development success of Bouillante (Guadeloupe, French West Indies) with the check of the geothermal development of Nyssiros (Greece) and Pantelleria (Italy), the development of the high enthalpy geothermal potentialities of Reunion Island, and the underground storage of CO{sub 2} emissions in geologic formations (deep aquifers, geothermal reservoirs, abandoned ...
The detection and characterization of deeply buried fatigue damage in thick, multi-layer airframe components pose significant technical challenges to the aviation safety community. Currently, no nondestructive evaluation technique is available to reliably detect such potential damage from the exterior of the airframe, which is highly desirable in light of inspection cost as well as avoidance of structure damage. Recent technological advances in high-sensitivity magnetic sensors, i.e., spin-dependent tunneling (SDT) sensors, make it feasible to employ electromagnetic inspection techniques for deep fatigue crack inspection. In this work, we report on the development and fabrication of a low frequency eddy current probe based on a magnetically shielded SDT pickup sensor concentrically located...
The Yaojia Formation recovered by CCSD-SK-Is borehole (China Cretaceous Continental Scientific Drilling-SongkeI-the south borehole) is 157.67 m long and 99.96% of cores recovery. The age of the formation corresponds with a range from the Santonian to the early Campanian. The sequences and processes of lithology-lithofacies and cyclic stratigraphy are revealed by a detailed core description. Eleven rock types and three kinds of sedimentary subfacies, including shallow lake, deep lake, and delta front, are recognized from the drilling core. There are eleven sedimentary microfacies including dolostone, argillaceous limestone, shallow lake turbidite, deep lake turbidite, subaqueous mouth bar, distal bar, sheet sandstone, subaqueous distributary bay, slump deposits, shallow lake mudstone, and d...
World demand for rare-earth elements and the metal yttrium?which are crucial for novel electronic equipment and green-energy technologies?is increasing rapidly. Several types of seafloor sediment harbour high concentrations of these elements. However, seafloor sediments have not been regarded as a rare-earth element and yttrium resource, because data on the spatial distribution of these deposits are insufficient. Here, we report measurements of the elemental composition of over 2,000 seafloor sediments, sampled at depth intervals of around one metre, at 78 sites that cover a large part of the Pacific Ocean. We show that deep-sea mud contains high concentrations of rare-earth elements and yttrium at numerous sites throughout the eastern South and central North Pacific. We estimate that an a...
A review of the deep-level defects observed in both electron- and proton-irradiated GaAs solar cells is presented. Studies of the effects of periodic and continuous thermal annealing on the radiation-induced electron and hole traps and the recombination parameters in GaAs solar cells were made for a wide range of electron and proton energies, fluence, annealing temperature and annealing time. A refined model for numerical simulations of the displacement damage was developed for computing the defect density and the cell parameters in the electron- and proton-irradiated GaAs solar cells. Excellent agreement was obtained between the calculated values and the experimental data for the proton-irradiated GaAs solar cells. (orig.).
Experimental studied of deep-inelastic scattering of neutrino, antineutrino, #mu#-mesons, electron reactions on He, D, Al, Fe, Au, Be, C, Ca, Ag, N nuclei conducted in recent years at different laboratories the world for consideration of modern status of the problems of R(x, Q"2) = #sigma#sub(L)/#sigma#sub(T) parameter variation and for study on nuclear effects in structural functions of nucleons are described in the review. Experimental information on measurements of the R parameter by data on EMS and SLAK groups is analyzed. It is noted that experimental data on measuring R contain essential errors that hampers unambiguous interpretation of data on nucleon structure. Present experimental data and predictions for explanation of the EMS effect are analyzed from the view point of quark and flucton models of a nucleus.
Energy flows in deep inelastic electron-proton scattering are investigated at a centre-of-mass energy of 296 GeV for the range Q{sup 2}{>=}10 GeV{sup 2} using the ZEUS detector. A comparison is made between events with and without a large rapidity gap between the hadronic system and the proton direction. The energy flows, corrected for detector acceptance and resolution, are shown for these two classes of events in both the HERA laboratory frame and the Breit frame. From the differences in the shapes of these energy flows we conclude that QCD radiation is suppressed in the large-rapidity-gap events compared to the events without a large rapidity gap. (orig.)
The effects of O and C ion implantation with different implantation doses on the yellow luminescence (YL) from unintentional doped n-type GaN have been studied by the photoluminescence (PL) spectra. O and C ions were implanted in the GaN samples with different doses from 1.0 x l013 to 1.0 x l017cm-2. Post-annealing was done in a quartz open-tube furnace under flowing N2 gas for 30 min at 950 degree C. By comparing with N ion implanted samples, it is assumed that different deep-level centers involving in the YL were produced in GaN after O and C ion implantation. In addition, with a dose of 1017 cm-2, the concentration of deep C centers involving in the YL was enhanced markedly. (authors)
Carbon fibre composite (CFC) was irradiated by hot plasma streams at plasma gun facility MK-200UG. The CFC targets were tested by plasma loads relevant to Edge Localized Modes (ELM) and mitigated disruptions in ITER. Onset condition of CFC evaporation and properties of evaporated carbon were studied by use of infrared pyrometry and visible spectroscopy.
Fourier transform infrared spectroscopy is a simple, fast, reliable and nondestructive analytical method. By using the method developed in Clark Atlanta University, consistent and reliable infrared spectral results can be obtained. An accurate radiant energy can be calculated from these infrared spectra by using a blackbody as the calibration standards. By means of the specially-designed-and-lab-made sampling inlet and the Horiba gas analyzers, the compositions of CO{sub 2}, CO, UCH, NOx and O{sub 2} etc. from the combustion exhaust gases have been on-line accurately analyzed. The commercial natural gas IR burner performed differently in the different conditions. For the methane-air combustion, at the equivalence ratio {Phi} = 1, the IR burner produced its maximum radiation efficiency, {approximately}31.4%, and the concentration of CO{sub 2} reached its maximum value, {approximately}10.7%. In the fuel-lean region, the O{sub ...
The fluorescence, absorption, infrared and Raman spectra of Sm_3Ga_5O_1_2 have been investigated. The energy-level schemes in the energy range 3000-16000 cm"-"1 have been determined. The number and symmetries of the Sm_3Ga_5O_1_2 crystal normal mode have been obtained by the molecular site group analysis and their comparison with the experiment has been made.
In this Brief Report, we analyze a generalized theory of massless scalar QED{sub 2} and show that, unlike the conventional scalar QED{sub 2}, it is free from infrared divergence problems. The model is exactly soluble and may describe, in a (1+1)-dimensional space-time, noninteracting spin-one tachyons. {copyright} {ital 1999} {ital The American Physical Society}
Computer simulations and experiments indicate that we can shape the infrared picosecond pulses of the Mark III FEL in amplitude, frequency, and phase. Strongly modulated fundamental and second harmonic pulses have been generated by operating the Mark III FEL in the regime of strong sideband growth. In this paper, we present the results of simulations and experiments for second harmonic generation with fundamental inputs from 2 to 3 {mu}m.
Research and development activities are reported on absorption spectroscopy, calorimetry, electrolysis, emission spectroscopy, fluorimetry gas chromatography, infrared spectroscopy, liquid chromatography, liquid scintillation counting, mass spectroscopy, microscopy, radiometric analysis, and thermal analysis. A group of miscellaneous projects are also described.
By means of infrared spectroscopy, x-ray diffraction, and differential thermal analysis, the authors investigate the pyrolysis of dichlorodithiourea cadmium, the vapor phase epitaxy of the cadmium sulfide film, and the composition of the solid and gaseous pyrolysis products. Those products are found to include the thiocyanates of guanidine, ammonium, and hydrogen along with cadmium oxides and sulfates and hydrochloric acid.
A general analysis is presented of a photon storage cavity, coupled to free-electron laser (FEL) cavity. It is shown that if the coupling between the FEL cavity and the storage cavity is unidirectional (for example, a ring resonator storage cavity) then storage is possible, but that if the coupling is bi-directional then storage is not possible. Parameters are presented for an infra-red FEL storage cavity giving an order of magnitude increase in the instantaneous photon power within the storage cavity. 4 refs., 3 figs.
The possibility of applying the near infrared gas dynamic lasers (GDL) for neutralization of negative ion beams is examined. A criterion of neutralization is suggested. The use of the criterion makes it possible to select an optically active medium for a negative ion neutralization. To demonstrate the method media containing hydrohalogens as imitating molecules are taken. ((orig.))
Anti-TAG-72 monoclonal antibodies target the tumor-associated glycoprotein (TAG)-72 in various solid tumors. This study evaluated the use of anti-TAG-72 monoclonal antibodies, both murine CC49...Full Text Available
Research continued on low severity coal liquefaction. Research using high temperature infrared of cyclic olefins progressed well during this quarter. Several fluorinated solvents were found that provide a high temperature medium for isotetralin and its aromatic and aliphatic analogues.
This past year has been very exciting for the experimental free-electron laser (FEL) programs. At three Laboratories, oscillator experiments were performed with wavelengths from the visible to far infrared. The output powers are steadily advancing. The status of these programs will be discussed. As shorter wavelengths and higher powers are pursued, higher currents with improved beam quality will be required. Advanced electron linacs should be developed to meet these demands. 13 references, 5 figures, 3 tables.
The interactions of the hydrophobic pulmonary surfactant proteins SP-B and SP-C with 1,2-dipalmitoylphosphatidylcholine in mixed, spread monolayer films have been studied in situ at the air/water interface...Full Text Available
An evaluation of eastern shale oil (ESO) residue as an asphalt additive to reduce oxidative age-hardening and moisture susceptibility was conducted. Rheological and infrared analyses of the unaged and aged asphalts and blends were then conducted to evaluate oxidative age-hardening. 18 refs., 5 figs., 6 tabs.
Moderate-resolution, near-infrared spectra between 0.8 and 5.2 #mu#m were obtained for 12 late-type (K0-M3) disk-bearing members of the #approx#5 Myr old Upper Scorpius OB association using SpeX on the NASA Infrared Telescope Facility. For most sources, continuum excess emission first becomes apparent between #approx#2.2 and 4.5 #mu#m and is consistent with that produced by single-temperature blackbodies having characteristic temperatures ranging from #approx#500 to 1300 K. The near-infrared spectra for 5 of 12 Upper Scorpius sources exhibit Pa#gamma#, Pa#beta#, and Br#gamma# emission, indicators of disk accretion. Using a correlation between Pa#beta# and Br#gamma# emission line luminosity and accretion luminosity, mass accretion rates ( M-dot ) are derived for these sources that range from M-dot = 3.5x10"-"1"0 to 1.5 x 10"-"8 M_s_u_n yr"-"1. Merging the SpeX observations with Spitzer Space Telescope ...
Results from scanning electron microscopy, Fourier transform infrared spectroscopy and the measurement of thermally stimulated current show that a high density of the physical defects and the chemical defects are introduced into the surface of the silicone rubber plates after they are treated by corona discharge plasma. These defects behave electrically as shallow electron traps, leading to the formation of a uniform discharge in air at higher pressure when the corona-modified silicone rubber is used in dielectric barrier discharge.
Amyloid-β (Aβ) deposits have been identified as key players in the progression of Alzheimer’s disease (AD). Recent evidence indicates that the deposits probably precede...Full Text Available
Polyacrylonitrile films have been spin cast and pyrolyzed to produce thin (500--1500 A) carbon films. These films have higher electrical conductivities than films produced by other methods at similar temperatures. The conductivity can be varied by at least four orders of magnitude by changing the pyrolysis temperature. Ultraviolet, infrared, and Raman spectroscopies were used to investigate the chemical structure of the films during different stages of processing.
The general n-point massless p-adic Feynman amplitude with arbitrary parameters of analytic regularization for each line is calculated. This result is presented in the form of a sum over hierarchies of a given graph. The structure of ultraviolet and infrared divergences of p-adic Feynman amplitudes is characterized and the star-triangle uniqueness identity in the p-adic case is derived. (orig.).
Using high resolution and high sensitivity IRAS data at 12 and 25 microns low mass stars were studied which have recently formed in the Ophiuchus, Corona Australis, and IC1396 dark clouds. The successful application of these techniques to the Rho Ophiuchi infrared cluster is briefly described. The status of research performed is also presented.
We discuss the determination of the infrared singularities of massive one-loop 5-point functions with Mellin-Barnes (MB) representations. Massless internal lines may lead to poles in the {epsilon} expansion of the Feynman diagram, while unresolved massless final state particles give endpoint singularities of the phase space integrals. MB integrals are an elegant tool for their common treatment. An evaluation by taking residues leads to inverse binomial sums. (orig.)
This critical review with 28 references examines absorption and emission in the v2 band of the carbon dioxide molecule at around the 15micron wavelength. The argument for additional infrared absorption, the enhanced greenhouse effect due to increased carbon dioxide concentrations, and radiation transport and increased emissions are discussed. Experiments studying the transmission spectra of pure carbon dioxide and carbon dioxide in nitrogen, and comparing them with the results of climate modelling using the HITRAN and GEISA databases, are described.
SummaryThe receptors for the second messenger InsP3 comprise a family of closely related ion channels that release Ca2+ from intracellular stores, most prominently...Full Text Available
The mechanism for afterglow suppression in codoped CsI:Tl,Eu reported in the preceding paper was investigated by combined radioluminescence and thermoluminescence experiments. Model rate equations informed by these experiments were employed to simulate afterglow. It was found that codoping with europium introduces deep electron traps, with room-temperature glow peaks, that effectively scavenge the electrons from shallow traps associated with thallium, thus suppressing afterglow in the time domain of tens of milliseconds.
The Mizunami Underground Research Laboratory (MIU) of the Japan Atomic Energy Agency is a major site for geoscientific research to advance the scientific and technological basis for geological disposal of high-level radioactive waste in crystalline rock. Studies on relevant engineering technologies in the MIU consist of a) research on design and construction technology for very deep underground applications, and b) research on engineering technology as a basis of geological disposal. In the Second Phase of the MIU project (the construction phase), engineering studies have focused on research into design and construction technologies for deep underground. The main subjects in the study of very deep underground structures consist of the following: 'Demonstration of the design methodology', 'Demonstration of existing and supplementary excavation methods', 'Demonstration of countermeasures during excavation' and 'Demonstration ...
In a slurry explosive, the fine droplets of the aqueous phase are dispersed in a continuous oily phase which comprises a thin film surrounding each droplet, the latter being less than one micron in size. The authors present these commercial explosives in three different forms, indicate their explosive properties and discuss their advantages from the safety viewpoint. They also report on tests undertaken with slurry explosives in quarries possessing different types of rock and using deep vertical shotholes.
Modec International Inc has selected Siemens Water Technologies to provide sea-water reverse osmosis (SWRO) systems for several floating, production, storage and offloading (FPSO) vessels that are to be operated in deep-water locations. Siemens is also supplying a wastewater reuse system to one of Brazils largest refineries.
70 patients with squamouscell carcinoma of larynx and hypopharynx were examined by computed tomography; the TNM staging of tumors by CT, by endoscopy and by surgical operation was reviewed. CT proved to be reliable both to recognize the presence of neoplasms, with the exception of those very superficial, and their deep spreading to preepiglottic and paralaryngeal spaces, to the soft tissues of the neck and to the cartilages. Therefore CT is the examination of choice in laryngeal neoplasms staging, because it precisely completes the clinical and endoscopical informations.
The coal bed methane (CBM) potential of five coal zones (the Kootenay, Gething, Gates, Brazeau, and Coalspur) in the Alberta foothills and mountains is re-evaluated. For evaluation, the coal zones are divided into shallow (200 to 2500 m depth) and deep (over 2500 m depth). The total gas content is estimated. Recommendations on how to obtain more reliable resource data and about producibility are included. 41 refs., 12 figs., 3 tabs., 2 apps.
We discuss the origin of Bloom-Gilman duality and the relationship between resonances and scaling in deep-inelastic scattering. We present a simple quantum mechanical model which reproduces the essential features of Bloom-Gilman duality at low Q{sup 2}, and describe applications of local duality relating structure functions at x{approximately}1 and elastic electromagnetic form factors.
The Subseabed Disposal Project (SDP) was part of an international program that investigated the feasibility of high-level radioactive waste disposal in the deep ocean sediments. This report briefly describes the seven-step iterative performance assessment procedures used in this study and presents representative results of the last iteration. The results of the performance are compared to interim standards developed for the SDP, to other conceptual repositories, and to related metrics. The attributes, limitations, uncertainties, and remaining tasks in the SDP feasibility phase are discussed.
An approach to high energy nuclear reactions (relativistic nuclear physics) is developed on the basis of the quark-parton-flucton concept. The main assumptions underlying the known parton chain model are briefly reformulated, modified and generalized to the flucton case. This new model is used to investigate electron-nuclei and muon-nuclei inclusive reactions within the framework of quantum electrodynamics. The theoretical results are fitted well with existing data. (Auth.).
The developments of fields in deep waters (5000 ft and more) is a common occurrence. It is inevitable that production systems will operate under multiphase flow conditions (simultaneous flow of gas-oil-and water possibly along with sand, hydrates, and wax...
This book presents the papers given at a conference on offshore platforms. Topics considered in this book include risk assessment, crack propagation, fracture control, stress corrosion, the reliability of pile foundations, the thermal conductivity of offshore pipeline coating material, economic analysis, hydrodynamics, simulation, Arctic structure design, composite materials, buoys, deep water drilling, corrosion protection, pollution control equipment, and subsea exhaust gas compressors.
Numerical errors of PALLAS calculation due to spatial mesh sizes are examined for a typical deep penetration shielding problem of isotropic incident fission neutrons penetrating a 200-cm-thick water slab. The exponential approximation for the source spatial distribution to solve the transport equation based on the direct integration method is verified to be effective for radiation transport in attenuating medium, while the linear approximation employed in the old PALLAS code is found to produce large errors for calculations with large mesh sizes.
Based on a hypothesis of multiquark states in nuclei, the nucleus structure functions are considered and the results are compared with experiment. It is shown that the multiquark state contributions are sufficiently high (Up to 20% in deuterium and 40% in iron) and must possess a greater, than in a nucleon, sea of quark-antiquark pairs. Also the comparison with the cumulative particle production cross sections is performed. The predictions are given for a further experimental test of that hypothesis.
This is a continuation of research that started in July 2007 at the Deep River Science Academy. The research was related to the effects of endplate thickness and misalignment of fuel bundles in the fuel channel on pressure losses of reactor coolant. Based on this research, a new approach to refueling of the CANDU reactor has been developed. It greatly simplifies fuel handling equipment and increases its reliability. It also reduces required staffing, as well as operating and maintenance costs associated with fuel handling. (author)
Features of deep inelastic nuclear reactions proceeding on dense fluctuations of nuclear matter (fluctons) are briefly considered. Fluctons, which can be many-quark bags or drops of quark-gluon plasma, are studied. Their properties are discussed, viz., characteristic parameters of nuclear matter inside a flucton - temperature and density close to the critical values for a phase transition. These values can be reached or exceeded if the flucton-flucton collision events are separated. The separation method is discussed
The reconstruction of coronal and Sagittal Image of Brain C. T. is helpful to diagnosis of Brain. Three Dimensional Reconstruction software package allows to display three dimensional Image clerived from a series of Horizontal, Sagittal and Coronal Brain C. T. images. It useful in determine approach of operation, to define portals of deep radiation therapy.
An animated test is made for mice with malignant tumors irradiated by a self-made millimetre wave radiator for medical purpose. It is observed that S-180 sarcomas in mice after irradiation has been distinctly suppressed. And remarkable effects are shown through a lot of clinical practices on peptic ulcer, skin-deep ulcer, acute and chromic soft tissue injuries etc.
Within the EU-Project VOTALP (Vertical Ozone Transports in the Alps), we have shown that deep alpine valleys like the Mesolcina Valley very efficiently transport air out of the polluted valley up to altitudes between 2000 and near 4000 m asl (above sea level). Pollutants emitted in these valleys are very efficiently transported up to high altitudes. (author) 2 figs., 1 tab., 2 refs.
Bahrain's Awali oil field is one of the oldest in the Arabian Gulf region. The recent sharp increase in produced water cut at Awali has resulted in higher oil carry-over in the produced water, which is currently disposed of in an aquifer about 700 ft (210 m) deep. The steps taken by Bahrain Natl. Oil Co. (Banoco) and the problems encountered in improving the quality of effluent are described in this paper.
One of the effective methods of deep modification of the surface of steels and alloys is the combination of ion implantation and plasma nitriding. In this work, the long-range effect is demonstrated in the case of combination of the effect of high- and low-energy ions of nitrogen on a martensitic steel for each ion implantation is usually not effective, and a titanium alloy used widely in industry.
The research of the CELLO collaboration is reviewed. After a description of the CELLO detector tests of QCD and hadronic final states by determination of the strong coupling constant and studies of inclusive production of electrons and muons in multihadronic events in e"+e"- annihilation are described. Then studies of deep inelastic e#gamma# scattering with lepton pair production and the study of the structure function of the photon are briefly described. Finally studies on QED processes are described together with tau decays. (HSI).
This report highlights the significance of the geological sciences to the nation and to society. Discussions include understanding plate tectonics and surface processes, exploring the continental crust, ocean basins and the deep earth, applications of geology to social problems such as mineral resources, waste disposal, siting of critical facilities, geological hazards, water resources management, and coastal zones. The state of health of geological research is also discussed. (ACR)
Focused ion beam (FIB) repair of chromium defects on photomasks and reticles leaves a post repair stain in the quartz substrate. The wavelength dependent absorption properties of typical stained regions have been measured, showing transition losses up to 80% in the deep uv. A simple model is in good qualitative agreement with the experimental results. (author).
These ten chapters present an overview of floating production, storage and offloading (FPSO) vessels, and examines deep water developments; hydrostatic stability; production, storage and offloading systems; the configuration and structure of flexible risers and umbilicals; the structural and global dynamic analysis of flexible riser and umbilicals; verification of FPSO structural integrity; vessel global loading and rigid body response; environmental loading and vessel response; and mooring systems. (UK)
A new reactor concept is described which would enable fission fragments to be continuously extracted from the reactor. Such a reactor has the potential of enabling extremely energetic and ambitious deep space missions. In this talk the basic physics issues involved in the operation of this type of reactor are outlined, and some possible applications to space exploration are described. 3 refs., 2 figs., 3 tabs.
The developments of oil and gas fields in deep waters (5000 ft and more) will become more common in the future. It is inevitable that production systems will operate under multiphase flow conditions (simultaneous flow of gas-oiland water possibly along wi...
The abundant microbial population in a 3,043-m-deep Greenland glacier ice core was dominated by ultrasmall cells (<0.1 μm3) that may represent intrinsically small organisms...Full Text Available
The gas composition of recent thermal waters is in perfect conformity with their geologic-tectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data the conclusion was drawn that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.
The oceanic bathypelagic realm (1000–4000 m) is a nutrient-poor habitat. Most fishes living there have pelagic larvae using the rich waters of the upper 200 m. Morphological...Full Text Available
Genome sequences are essential tools for comparative and mutational analyses. Here we present the short read sequence of mouse chromosome 17 from the Mus musculus domesticus derived...Full Text Available
Due to the increasingly stricter regulations for deep reduction of fuel sulfur content, development of new deep desulfurization processes for liquid transport fuels has become one of the major challenges to the refining industry and to the production of hydrocarbon fuels for fuel cell applications. The sulfur compounds in the current transport fuels corresponding to the S level of 350-500 ppm account for only about 0.12-0.25 wt % of the fuel. The conventional hydrotreating approaches will need to increase catalyst bed volume at high-temperature and high-pressure conditions for treating 100 % of the whole fuel in order to convert the fuel mass of less than 0.25 wt %. In the present study, we are exploring a novel adsorption process for desulfurization at low temperatures, which can effectively reduce the sulfur content in gasoline, jet fuel and diesel fuel at low investment and operating cost to meet the needs for ultra-clean transportation ...
Asymptotic giant branch stars are red supergiant stars of low-to-intermediate mass. This class of stars is of particular interest because many of these stars can have nuclear processed material brought up repeatedly from the deep interior to the surface where it can be observed. A review of recent theoretical and observational work on stars undergoing the asymptotic giant branch phase is presented. 41 refs.
The purpose of this study was to assess the agreement between rectal temperature and infrared emission detection (IRED). The specificity and sensitivity, the positive predictive value and the negative predictive value were calculated. It was a prospective, observational and unblinded study. Thermoscan-pro-1 was used to collect pairs of data in 41 patients, all hospitalised on an acute geriatric ward during a 4-month period. 41% of the patients were febrile. The 'bias' between rectal and tympanic measurement (left ear) was -0.64 degree C (d) and the standard deviation 0.58 degree C (s). The '95% Confidence Interval' for the bias was -0.82 degree C and -0.46 degree C. The '95% limits of agreement' between the rectal measurement and the tympanic measurement (left ear) was -1.78 degrees C and 0.50 degree C. Regression analysis taught us that bias was increasing with increasing temperature. If we take into account one measurement with the IRED ear thermometry, the ...
An ASTER (advanced spaceborne thermal emission and reflection radiometer) is one of the image sensors. It is to be installed in an earth survey polar orbit platform satellite, EOS-AM1, which is to be launched in 1998, and it is going to start its operation. Data observed by the thermal infrared remote sensing of ASTER include the spectral emissivity, and the spectral emission reflectivity which is expressed by the function of temperature. It is required to overcome technical problems how to extract the spectral emissivity from the observed data. The spectral emissivity extracted from the remote sensing data by the MMD method, measured for samples collected in Cuprite area, Nevada, and/or measured at sampled points were compared to each other and discussed. The hemisphere spectral reflectivity, which is indirect spectral emissivity, agreed well with the direct spectral emissivity. Data suggesting the establishment of Kirchhoff`s law were obtained even for the ...
Context. Study of open clusters is important not only for learning properties of these objects but also for understanding the process of formation and evolution of stars and the Milky Way. Aims. The paper contains determination of the global (geometrical and physical) characteristics of a large sample of Galactic open clusters from homogeneous near-infrared photometric data and analysis of mutual relations between those characteristics. Methods. The near-infrared JHK photometric data from the 2-Micron All Sky Survey were used to determine new coordinates of the centres, angular sizes and radial density profiles of 849 open clusters in the MilkyWay. Additionally, for 754 of these clusters age, reddening, distance and linear sizes were also derived. The sample contains 140 open clusters which have not been studied before. Results. The analysed sample contains open clusters with ages in the range from 7 Myr to 10 Gyr. The majority of these ...
Site-selective spectroscopy fluorescence experiments (emission and excitation) in the near-infrared region associated with the {sup 4}I{sub 15/24}I{sub 11/2} transitions of Er{sup 3+} ions have been successfully used to show the presence of two different Er{sup 3+} centres in the Bi{sub 12}SiO{sub 20} piezoelectric crystal. Green (545-570 nm), red (650-690 nm) and near-infrared (850-890 nm) up-converted emissions have been observed and resolved for each type of centre under excitation up to the {sup 4}{sub I11/2} state. The Stark energy level schemes of the three lower energy states of Er{sup 3+} ions have been determined and compared for both centres, showing two quite different crystalline field environments. The mechanisms responsible for the up-conversion process (excited state absorption and/or energy transfer up-conversion) are also analysed. (author)
Site-selective spectroscopy fluorescence experiments (emission and excitation) in the near-infrared region associated with the "4I_1_5_/_2_4I_1_1_/_2 transitions of Er"3"+ ions have been successfully used to show the presence of two different Er"3"+ centres in the Bi_1_2SiO_2_0 piezoelectric crystal. Green (545-570 nm), red (650-690 nm) and near-infrared (850-890 nm) up-converted emissions have been observed and resolved for each type of centre under excitation up to the "4_I_1_1_/_2 state. The Stark energy level schemes of the three lower energy states of Er"3"+ ions have been determined and compared for both centres, showing two quite different crystalline field environments. The mechanisms responsible for the up-conversion process (excited state absorption and/or energy transfer up-conversion) are also analysed. (author)
Seiberg duality in supersymmetric gauge theories is the claim that two different theories describe the same physics in the infrared limit. However, one cannot easily work out physical quantities in strongly coupled theories and hence it has been difficult to compare the physics of the electric and magnetic theories. In order to gain more insight into the equivalence of two theories, we study the ''e{sup +}e{sup -}'' cross sections into ''hadrons'' for both theories in the superconformal window. We describe a technique which allows us to compute the cross sections exactly in the infrared limit. They are indeed equal in the low-energy limit and the equality is guaranteed because of the anomaly matching condition. The ultraviolet behavior of the total ''e{sup +}e{sup -}'' cross section is different for the two theories. We comment on ...
We report on recent progress and improvements in the metal-organic chemical vapor deposition (MOCVD) growth of mid-infrared lasers and using a high speed rotating disk reactor (RDR). The devices contain AlAsSb active regions. These lasers have multi-stage, type I InAsSb/InAsP quantum well active regions. A semi-metal GaAsSb/InAs layer acts as an internal electron source for the multi-stage injection lasers and AlAsSb is an electron confinement layer. These structures are the first MOCVD multi-stage devices. Growth in an RDR was necessary to avoid the previously observed Al memory effects found in conventional horizontal reactors. A single stage, optically pumped laser yielded improved power (greater than 650 mW/facet) at 80K and 3.8um. A multi-stage 3.8-3.9um laser structure operated up to T=170K. At 80K, peak power greater than 100mW and a high slope- efficiency were observed in gain guided lasers.
An engineering tool incorporating a scanning infrared radiometer, an image digitizer, a microcomputer, and the software to drive the system was developed to allow remote mapping of the temperature distribution in solar cavity receivers. Using enclosure analysis, the infrared image processing program extracts the irradiance map from the radiosity map of the cavity to yield an emissive power map. Using the calibration curve of the radiometer and the emissivity of the surface of the cavity, the emissive power map is transformed into a temperature map. The system was tested by comparing its calculated temperatures to temperatures measured by thermocouples at several locations on the surfaces of heated model cavity receivers. The average relative error for the cavities ranged from 4.6%--34.9%, with the relative error on the base usually less than half that on the wall. Some work was also carried out to compensate the detected radiosity field for the ...
Highly resistant, high-transmittance woodceramic thin films were prepared using rf magnetron sputtering of a woodceramic disk in argon plasma. A film series was deposited based on substrate temperature, which was varied from 50 to 500 degree C. The film's electrical and optical properties depended on substrate temperature. Films deposited below 300 degree C were insulative, {rho}>10{sup 10} {omega} {center_dot} cm. Films deposited at 50 degree C had a density of 1.9-2.2 g/cm{sup 3} comparable to that of single crystal graphite. Below 200 degree C, films had higher transmittance than typical DLC films in the visible and infrared region. Infrared C-H absorption spectrum was observed by Ft-IR and there exist two types of bonding corresponding to sp{sup 2} or SP{sup 3}. (author)
Optically stimulated luminescence (OSL) and thermoluminescence are observed in polycrystalline RbMgF3:Eu2+ after x-ray, ?-ray, or ? irradiation. The main electron traps are F-centers but there are other unidentified traps. The main hole traps at room temperature are probably Eu3+ and thermal or optical stimulation leads to electron-hole recombination at the Eu3+ site and Eu2+ emissions arising from 6PJ to 8S7/2 and 4f5d(Eg) to 8S7/2 transitions. We find that some of the electron traps can be emptied by infrared stimulation and all of the electron traps can be emptied by white light stimulation. The OSL dark decay is long and exceeds 5 days for traps that are emptied by white light stimulation after initial infrared bleaching. Our results show that this compound can be used as a radiation dosimeter for intermediate dose levels where the 87Rb self-dose does not significantly affect the dose reading.
Low-frequency current noise and current-voltage (I-V) characteristics have been studied in InAs/GaAs self-assembled Quantum Dot Infrared Photodetectors in dark conditions and under illumination, at T = 77K and T = 5K. The noise behavior is consistent with a generation-recombination fluctuation process mainly related to thermally excited charge carriers at T = 77K. At T = 5K the current noise is consistent with a mechanism of fluctuations driven by the electric field, related to tunneling rather than emission-capture of charge carriers from the Quantum Dots. A very effective noise suppression mechanism, related to the tunneling regime, determines a decrease of fluctuation intensity as a function of the voltage. At T = 5K, an interesting behavior is observed in the current-voltage and noise power spectra for some of nominally identical QDIP structures in the presence of irradiation. Some devices indeed exhibit (i) a very high photoresponse and (ii) a 1/f-shaped noise ...
Reflectance anisotropy spectroscopy (RAS) has been used, together with scanning tunnelling spectroscopy (STS), to investigate the optical and electronic properties of nanodots formed by depositing Ag on the Si(111)-3 x 1-Ag surface. One-dimensional (1D) arrays of nanodots were grown on a single-domain (3 x 1)-Ag surface and the anisotropic optical response in the 0.5-5 eV range measured by RAS. Aligned, elongated Ag islands were also grown on this surface to compare their properties with those of the nanodots. STS of the Ag islands showed distinct metallic behaviour, whereas the nanodots revealed a bandgap of #approx#0.6 eV, indicating that the surface of the dots has a non-metallic character, similar to that of the Si(111)-3 x 1-Ag surface. RAS also showed substantial differences between the structures, with a large infrared anisotropy for the metallic Ag islands consistent with anisotropic Drude-like intraband transitions, whereas the nanodots gave a negligible ...
A new method, near-infrared laser desorption/ionization aerosol mass spectrometry (NIR-LDI-AMS), is described for the real time analysis of organic aerosols at atmospherically relevant mass loadings. Use of a single NIR laser pulse to vaporize and ionize particle components deposited on an aluminum probe results in minimal fragmentation to produce exclusively intact pseudomolecular anions at [M-H](-). Limits of detection (total particulate mass sampled) for oxidized compounds of relevance to atmospheric primary and secondary organic aerosol range from 89 fg for pinic acid to 8.8 pg for cholesterol. NIR-LDI-AMS was used in conjunction with the University of Vermont Environmental Chamber to study secondary organic aerosol (SOA) formation from ozonolysis of limonene at total aerosol mass loadings ranging from 3.2 to 25.0 ?g m(-3) and with a time resolution of several minutes. NIR-LDI-AMS permitted direct delineation between gas-phase, homogeneous SOA formation and ...
We report the growth and fabrication of midwave infrared InAs/GaSb strain layer superlattice (SLS) detectors. Growth of alternate interfaces leads to a reduced strain between the GaSb buffer and SLS ({delta}a{sub parallel}/a=-5x10{sup -4}), enabling the growth of active regions up to 3 {mu}m (625 periods). The structural, optical, and electrical properties of the active region were characterized using x-ray crystallography and photoluminescence, respectively. p-i-n detectors were grown using 625 periods of 8 ML (monolayer) InAs/8 ML GaSb as the active region. The {lambda}{sub cutoff} for the detectors was 4.6 {mu}m with a conversion efficiency of 32% at V{sub b}=-0.2 V. Detectivity was obtained using noise power spectral density measurements under 300 K 2{pi} field of view illumination and was equal to 5.2x10{sup 10} and 3x10{sup 10} cm Hz{sup 1/2}/W (V{sub b}=-0.02 V, T=80 K) in the white noise and 1/f noise limit (at 50 Hz)
The results of a comprehensive infrared imaging search for the putative 0.06 M{sub {circle_dot}} astrometric companion to the 4.4 pc white dwarf van Mannen 2 are reported. Adaptive optics images acquired at 3.8 {micro}m reveal a diffraction limited core of 0.09 inch and no direct evidence of a secondary. Models predict that at 5 Gyr, a 50 M{sub J} brown dwarf would be only 1 magnitude fainter than van Maanen 2 at this wavelength and the astrometric analysis suggested a separation of 0.2 inch. In the case of a chance alignment along the line of sight, a 0.4 mag excess should be measured. An independent photometric observation at the same wavelength reveals no excess. In addition, there exist published ISO observations of van Maanen 2 at 6.8 {micro}m and 15.0 {micro}m which are consistent with photospheric flux of a 6750 K white dwarf. If recent brown dwarf models are correct, there is no substellar companion with T{sub eff} {approx}> 500 K.
Ordered mesoporous C-TiO2 nanocomposites with crystalline framework were prepared by the evaporation-induced triconstituent co-assembly method. The products were characterized by XRD, TEM, N2 adsorption-desorption and TG. Their microwave absorption properties were investigated by mixing the product and epoxy resin. It is found that the peak with minimum reflection loss value moves to lower frequencies and the ordered mesoporous C-TiO2 nanocomposite possesses an excellent microwave absorbing property with the maximum reflection loss of -25.4 dB and the bandwidth lower than -10 dB is 6.6 GHz. The attenuation of microwave can be attributed to dielectric loss and their absorption mechanism is discussed in detail. The mesoporous C-TiO2 nanocomposites also exhibit a lower infrared emissivity in the wavelength from 8 to 14 ?m than that of TiO2-free powder. -- Graphical abstract: Ordered mesoporous C-TiO2 nanocomposite with crystalline framework possess excellent microwave ...
The traditional view that Ly-alpha emission and dust should be mutually exclusive has been questioned more and more often, notably the observations of Ly-alpha emission from ULIRGs seems to counter this view. In this paper we seek to address the reverse question: How large a fraction of Ly-alpha selected galaxies are ULIRGs? Using two samples of 24/25 Ly-alpha emitting galaxies at z = 0.3/2.3 we perform this test, also including results at z = 3.1, and find that whereas the ULIRG fraction at z = 3.1 is very small, it systematically increases towards lower redshifts. There is a hint that this evolution may be quite sudden and that it happens around a redshift of z ~ 2.5. Measuring the infrared luminosities of the Ly-alpha emitters, we find that they are in the normal to ULIRG range in the lower redshift sample, whereas the higher redshift galaxies all have luminosities in the ULIRG category. The Ly-alpha escape fractions for these infrared ...
In this study, two different humic acids extracted from England and China peat soil, as well as three purified products extracted from commercially available humic acids [Fluka (Fluka, Neu-Ulm, Germany, Alfa (Alfa Aesar, Ward Hill, USA) and Aldrich (Aldrich-Chemical Co, Gillingham-Dorset)] were obtained respectively with the modified IHSS (International humic substances society) procedure. The chemical and structural information of these humic acids were characterized by some techniques, such as elemental analysis, ultraviolet-visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FTIR) and electropotential titration. UV-Vis spectra, infrared spectra, values for elemental composition and the contents of carboxyls, phenolic hydroxyls and total acidities of these humic acids were acquired. It is indicated that all these humic acids are different in the aspect of chemical structure, respectively, and these humic acids would be ...
Efficient, low-temperature conversion of infrared light into visible light (red, orange, green) is reported at single heterojunctions and undoped quantum wells of GaAs and ordered Al{sub {ital x}}Ga{sub 1{minus}{ital x}}InP{sub 2}; an increase in photon energy of 700 meV is obtained. The signal originates from the high-band-gap layers and disappears only if the excitation energy is tuned below the GaAs band gap. The intensity of the up-converted photoluminescence (PL) is found to decrease significantly slower with increasing temperature than that of the regular PL and it remains observable up to 200 K. Interface-induced cold Auger processes along with the presence of trapped states for both electrons and holes in these ordered alloys account for this nonlinear mechanism. A colinear double-beam experiment confirms this. {copyright} {ital 1996 The American Physical Society.}
The IR double-resonance techniques IR/R2PI (infrared/resonant 2-photon ionization), IR/PIRI (infrared-photo-induced Rydberg ionization) and IR-photodissociation spectroscopy are valuable tools to investigate structure, vibrations, and dynamical processes of neutral and ionic hydrogen-bonded clusters containing aromatic molecules. In this paper we report on the application of the IR double-resonance techniques to determine the NH and OH stretching vibrations of 4-aminophenol and 4-aminophenol(H{sub 2}O){sub 1}, both in the neutral (S{sub 0}) and ionic (D{sub 0}) ground state. All vibrational frequencies obtained for 4-aminophenol and the cluster are compared with the values obtained from ab initio and DFT calculations. In the S{sub 0} state, a trans-linear arrangement of 4-aminophenol(H{sub 2}O){sub 1} is obtained containing an O-H. O hydrogen bond. In the D{sub 0} state an overlay of two spectra can be observed resulting from the trans-linear ...
The dependencies that limit high frequency operation of a vacuum microelectronic grating free-electron laser are examined. The important parameters are identified as the electron beam energy, emittance, and generalized perveance. The scaling of power with emittance and frequency is studied in the far-infrared spectral range using a modified scanning electron microscope (SEM) and submillimeter diffraction gratings. The SEM is suited to the task of generating and positioning a low emittance (10"-"2#pi#-mm-mrad), low current (100 #mu#A), but high current density (50-500 A cm"-"2) electron beam. It has been used to demonstrate the spontaneous emission process known as the Smith-Purcell effect. A vacuum microelectronic grating free-electron laser has the potential of generating radiation throughout the entire far-infrared spectral range which extends from approximately 10 to 10"3#mu#m. An introduction to the theory, initial results, and details of ...
Efficient and precise ablation of soft tissue is needed for non-invasive dermatological and corneal surgeries. Previous research has revealed that smooth and efficient cutting of certain soft tissues and gelatin is possible using a Free Electron Laser (FEL) with a wavelength of #lambda#=6.45 #mu#m, tuned to the amide-II band of protein. Gelatin ablation experiments have been carried out using a mid-infrared FEL within the waveband #lambda#=5.6-6.7 #mu#m by changing the primary absorbers such as water (#lambda#=6.1 #mu#m) and protein (#lambda#=6.45 #mu#m). The gelatin with 80 wt% water was efficiently ablated by FEL irradiation with the waveband #lambda#=#approx#5.95-6.19 #mu#m. On the other hand, using irradiation within #lambda#=#approx#6.4-6.6 #mu#m, many small bubbles were observed in the irradiated volume, and the gelatin was not ablated but significantly melted. Thus, it was found that the most effective wavelength was #approx#6.1 #mu#m, not #approx#6.45 ...
High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing layer of a BIB detector, has been achieved. The control of the donor concentration, however, was found to be insufficient for detector production. The growth by LPE of a high-purity film onto a commercially grown vapor-phase epitaxial (VPE) n-type GaAs doped absorbing layer resulted in a BIB device that showed a significant reduction in the low-temperature dark current compared to the absorbing layer only. Extended optical response was not detected, most likely due to the high ...
The KAERI compact far-infrared (FIR) free-electron laser (FEL) has been operated successfully in the wavelength range of 97-150 #mu#m. It is the first demonstration of FEL lasing by using a magnetron-based classical microtron. We developed a high precision undulator consisting of 80 periods, with each period being 25 mm. The field strength of the undulator can be changed from 4.5 to 6.8 kG with an amplitude deviation of only 0.05% in r.m.s value. The kinetic energy of the electron beam is 6.5 MeV. The average current and pulse duration of the electron beam macropulses are 45 mA and 5.5 #mu#s, respectively. The measured power of the FEL with the electron beam parameters was more than 50 W for a FIR macropulse having a duration of 4 #mu#s. The spectral width of the FEL was measured to be 0.5% of the central wavelength. The FEL system, aside from the racks for the controlling units, is compact enough to be located inside an area of 3x4 m"2.
The phase transition behaviour of polyethylene-b-poly(ethylene oxide) (PE-b-PEO) diblock copolymer with relatively short chain lengths has been studied on the basis of temperature dependent infrared and Raman spectral measurements and synchrotron WAXD/SAXS simultaneous measurements, from which the concrete structural changes were deduced successfully from the various levels of molecular chain conformation, chain packing mode and higher-order structure. The higher-order structure has been found to transform between lamella, perforated lamella, gyroid, cylinder and sphere structures. The inner structural changes occurring in the polyethylene and poly(ethylene oxide) parts have been related with these morphological changes. The morphological transition from lamella to gyroid occurs with keeping the crystalline state of polyethylene parts. This apparently curious transition can be interpreted reasonably by assuming the thermally-activated chain motion in the crystal ...
This paper studies the way in which confinement leads to chiral symmetry breaking (CSB) through a gap equation. We argue that entropic effects cut off infrared singularities in the standard confining effective propagator $1/p^4$, which should be replaced by $1/(p^2+m^2)^2$ for a finite mass $m\\sim K_F/M(0)$ [$M(0)$ is the zero-momentum value of the running quark mass]. Extension of an old calculation of the author yields a specific estimate for $m$. This cutoff propagator shows semi-quantitatively two critical properties of confinement: 1) a negative contribution to the confining potential coming from entropic forces; 2) an infrared cutoff required by gauge invariance and CSB itself. Entropic effects lead to a proliferation of pion branches and a $\\bar{q}q$ condensate, and contribute a negative term $\\sim -K_F/M(0)$ to the effective pion Hamiltonian allowing for a massless pion in the presence of positive kinetic energy and string energy. ...
Makrofol-De 1-1 CC Polycarbonate is a class of polymeric solid state nuclear track detectors which has many applications in various industrial fields. A study of the modification possibility of the dielectric properties of Makrofol polymer using laser irradiation has been carried out. In tbe present work, Makrofol samples were irradiated using different fluences between 0.47 and 10.4 J/cm"2 of 5 watt infrared pulsated laser. The mollifications in the laser irradiated Makrofol samples have been studied as a function of fluence using dielectric constant #epsilon#', dielectric loss #epsilon#"and AC conductivity #sigma#_AC measurements. Tbe frequency dependencies (100 Hz-5 MHz) of #epsilon#', #epsilon#"and #sigma#_AC at 35 degree c were investigated. The dielectric constant #epsilon#', dielectric loss #epsilon#"and AC conductivity #sigma#_AC were found to increase at heating up to 100 degree C. This indicates that #epsilon#', #epsilon#"#sigma#_AC depend not only on the ...
Electron paramagnetic resonance (EPR), optical, infrared and Raman spectral studies have been carried out on vanadyl ions doped in polyvinylalcohol (PVA) films. The spin-Hamiltonian parameters (g and A) and the molecular orbital coefficients (#beta#_2"*"2 and k) have been evaluated. The values of spin-Hamiltonian parameters confirm that the vanadyl ions are present in PVA films as VO"2"+ molecular ions in an octahedral site with a tetragonal compression (C_4_v). The temperature variation EPR studies reveal that the variation of number of spins with temperature is in accordance with Boltzmann law. It is interesting to observe that the variation of susceptibility with temperature obeys Curie-Weiss law. The FT-IR and FT-Raman spectrum exhibits few bands, which are attributed to O-H, C-H, C-C and C-O groups of stretching and bending vibrations. The optical absorption spectrum exhibits two bands, which are assigned to "2B_2_g->"2B_1_g and "2B_2_g->"2E_g ...
To understand evolutionary and environmental effects during the formation of high-mass stars, we observed three regions of massive star formation at different evolutionary stages that reside in the same natal molecular cloud. Methods. The three regions S255IR, S255N and S255S were observed at 1.3 mm with the Submillimeter Array (SMA) and followup short spacing information was obtained with the IRAM 30m telescope. Near infrared (NIR) H + K-band spectra and continuum observations were taken for S255IR with VLT-SINFONI to study the different stellar populations in this region. The combination of millimeter (mm) and near infrared data allow us to characterize different stellar populations within the young forming cluster in detail. While we find multiple mm continuum sources toward all regions, their outflow, disk and chemical properties vary considerably. The most evolved source S255IR exhibits a collimated bipolar outflow visible in CO and H2 ...
A new method is being developed to quickly screen for the human exposure potential to polycyclic aromatic hydrocarbons (PAHs) and organochlorines (OCs). The development involves two key elements: identifying suitable signals that represent intracellular changes that are specific to PAH and OC exposure, and constructing a device to guide the biological cell growth so that signals from individual cells are consistent and reproducible. We are completing the identification of suitable signals by using synchrotron radiation-based (SR) Fourier-transform infrared (FTIR) spectromicroscopy in the mid-infrared region (4000-400 cm-1). Distinct changes have been observed in the IR spectra after treatment of human cells in culture medium with PAHs and OCs. The potential use of this method for detecting exposure to PAHs and OCs has been tested and compared to a reverse transcription polymerase chain reaction (RT-PCR) assay that quantifies increased ...
This work investigates the potential use of simultaneously near-infrared (NIR) and mid-infrared (MIR) spectroscopies for the quantitative analysis of fatty acids and triacylglycerols and for identifying the Registered Designation of Origin (RDO) of extra virgin olive oils. The two spectral ranges were used separately using PLS and PLS-DA regressions. To combine both information, concatenated matrix was used at the first time, multiblock method using H-PLS models were constructed at the second time. The models were compared in terms of prediction errors. The results obtained with MIR spectroscopy are better than the ones obtained with NIR spectroscopy. The H-PLS methodology seems to be very interesting for quantitative analysis with the use of additional information in the NIR range, which is not present in the MIR one. For RDO identification by discriminant analysis, the use of multiblock method was less efficient. PMID:20433960
Recent X-ray and radio observations have identified a transient low-mass X-ray binary (LMXB) located only 0.1 pc in projection from the Galactic center, CXOGC J174540.0-290031. In this paper, we report the detailed analysis of X-ray and infrared observations of the transient and its surroundings. Chandra bservations detect the source at a flux of F_X = 2e-12 erg cm^-2 s^-1 (2-8 keV). After accounting for absorption both in the interstellar medium and in material local to the source, the implied luminosity of the source is only L_X = 4e34 erg/s (2-8 keV; D=8 kpc). However, the diffuse X-ray emission near the source also brightened by a factor of 2. The enhanced diffuse X-ray emission lies on top of a known ridge of dust and ionized gas that is visible infrared images. We interpret the X-ray emission as scattered flux from the outburst, and determine that the peak luminosity of CXOGC J174540.0-290031 was >2e36 erg/s. We suggest that the ...
This article discussed a project formed to develop innovative seismic imaging technologies. The Kaleidoscope project aims to accelerate the processing of seismic sound waves by several orders of magnitude using advanced computer-based techniques to reveal oil and gas deposits buried deep in the earth in a manner that is both cost-effective and efficient. It is expected that the technology will be used in deep water applications with massive untapped reserves. The seismic technology will be used to locate hydrocarbons and oil reserves buried 20,000 feet beneath the seabed. It is estimated that the Gulf of Mexico contains 56 billion barrels of oil equivalent worth nearly $6 trillion. However, the reserves are difficult to locate due to the interbedded salt bodies in the subsurface. The project is simultaneously working on both hardware and software applications, and are currently writing the first petascale set of seismic imaging applications. ...
The influence of small amounts of alloying elements (0.36% Cu and 0.47% Cr) on the semiconducting properties of passive films formed on weathering steels was investigated either in tetraborate/boric acid buffer solution (pH 9.2) or artificial atmospheric environment (SO{sub 2}-containing environment). The electrochemical behaviour was assessed by potentiodynamic polarisation, capacitance measurements and photoelectrochemistry. The chemical characterisation of the films was carried by Auger electron spectroscopy. The polarization results obtained in the buffer solution show that the addition of chromium decreases the passive current density. The capacitance results show that the films behave as an n-type semiconductor with shallow and deep donor levels situated in the forbidden gap. The presence of copper seems to affect the density of the shallow and of the deep donor levels in the forbidden gap, and as chromium, it also decreases the doping ...
The influence of small amounts of alloying elements (0.36% Cu and 0.47% Cr) on the semiconducting properties of passive films formed on weathering steels was investigated either in tetraborate/boric acid buffer solution (pH 9.2) or artificial atmospheric environment (SO_2-containing environment). The electrochemical behaviour was assessed by potentiodynamic polarisation, capacitance measurements and photoelectrochemistry. The chemical characterisation of the films was carried by Auger electron spectroscopy. The polarization results obtained in the buffer solution show that the addition of chromium decreases the passive current density. The capacitance results show that the films behave as an n-type semiconductor with shallow and deep donor levels situated in the forbidden gap. The presence of copper seems to affect the density of the shallow and of the deep donor levels in the forbidden gap, and as chromium, it also decreases the doping density ...
We study the redshift evolution of galaxy pair fractions and merger rates for different types of galaxies using kinematic pairs selected from the DEEP2 Redshift Survey. Parameterizing the evolution of the pair fraction as (1+z)^{m}, we find that the companion rate increases mildly with redshift with m = 0.41+-0.20 for all galaxies with -21 < M_B^{e} < -19. Blue galaxies show slightly faster evolution in the blue companion rate with m = 1.27+-0.35 while red galaxies have had fewer red companions in the past as evidenced by the negative slope m = -0.92+-0.59. We find that at low redshift the pair fraction within the red sequence exceeds that of the blue cloud, indicating a higher merger probability among red galaxies compared to that among the blue galaxies. With further assumptions on the merger time scale and the fraction of pairs that will merge, the galaxy major merger rates for 0.1 < z <1.2 are estimated to be ~10^{-3}h^{3}Mpc^{-3}Gyr^{-1} with a ...
The deep water parts of the Moere and Southern Voering Basins are large frontier areas, which are considered to contain significant undiscovered hydrocarbon resources, within Cretaceous and Paleogene reservoirs. PGS Reservoir AS have evaluated the Cretaceous and Paleogene successions of the shallow and deep water areas offshore Mid-Norway using high-resolution sequence stratigraphic techniques. The successions have been subdivided into about 20 stratigraphic sequences. The results are: (1) A more acurate and higher resolution stratigraphy, (2) Greater constraints on basin palaeoenvironmental and palaeogeographic reconstructions, (4) Fully integrated sandstone fairway models, with increased ability to reservoir and seal quality and continuity, (5) In addition to several obvious giant domal traps, subtler yet significant structural and stratigraphic leads and prospects can be identified, (6) The timing, volume and phase of hydrocarbon generation ...
Abstract This research aimed to investigate coarse root systems of Jarrah (Eucalyptus marginata Donn ex Sm.) trees at a 13-year-old restored bauxite mine site in south-western Australia. Excavations in an area with small trees (low-quality site) revealed that deep ripping equipment failed to penetrate the cemented lateritic subsoil, restricting coarse roots (roots >5 mm in diameter) to the top 0.5 m of the soil profile, resulting in fewer (1,344 stems/ha) and smaller (mean height 4.5 m) Jarrah trees. An adjacent area within the same pit (high-quality site), with a stand density of 3,256 stems/ha and a mean height of 8.0 m, had a kaolinitic clay subsoil which coarse roots penetrated to the average ripping depth (1.5 m). Trees at the low-quality site did not penetrate the subsoil with their ...
The purpose of this study was to determine the optimal technique for delivering postoperative radiotherapy for vulvar cancer and other tumors requiring treatment of the inguinal nodes. This project compared tumor coverage and normal tissue sparing for the 5 main radiotherapy techniques that are used to treat vulvar cancer. The intensity-modulated radiation therapy (IMRT) plan was undesirable because it resulted in an excessive dose to portions of the central pelvic structures. The photon thunderbird with skin match was unacceptable because it underdosed a portion of the groin region. The electron thunderbird was ideal for thin patients but was not applicable for most patients because of excessive dose to the skin and subcutaneous tissues. The photon through-and-through and the photon thunderbird with deep match were acceptable in most situations. In thin patients, where the depth of the inguinal vessels is less than 3 cm, the electron thunderbird is the technique ...
Geological, geophysical, thermal, petrophysical and hydrological data available for the East Mesa hydrothermal system that are pertinent to the construction of a computer model of the natural flow of heat and fluid mass within the system are assembled and correlated. A conceptual model of the full system is developed and a subregion selected for quantitative modeling. By invoking the Boussinesq approximation, valid for describing the natural flow of heat and mass in a liquid hydrothermal system, it is found practical to carry computer simulations far enough in time to ensure that steady-state conditions are obtained. Initial calculations for an axisymmetric model approximating the system demonstrate that the vertical formation permeability of the deep East Mesa system must be very low (k/sub v/ approx. 0.25 to 0.5 md). Since subsurface temperature and surface heat flow data exhibit major deviations from the axisymmetric approximation, exploratory three-dimensional ...
A cellular membrane exchanges substances into and from the cell and protects the cell interior by maintaining semi-fluidity rather than be being solid. It is known that microorganisms maintain the fluidity in correspondence with varying environmental temperatures by changing and adjusting the composition of fatty acids which constitute the cellular membrane lipids. As part of the studies to elucidate the pressure withstanding mechanism in deep-sea bacteria, this paper investigates what variations the fatty acid composition, which constitutes cellular membranes of the DSS12 strain, a pressure withstanding bacterium growing well under either normal pressure or high pressures, will show under different culturing temperatures and pressures. Culture under low temperatures and culture under high pressures increase content of unsaturated fatty acids including icosapentanoic acid. Culture under high temperatures or normal pressure increases content of such unsaturated ...
We investigated the isotropic diffusion coefficient (D') and fractional anisotropy (FA) in white matter (WM) during brain development, using an optimised diffusion-tensor imaging (DTI) method with whole brain coverage in a clinically acceptable time. We images 52 children with no evident neurological abnormality (30 boys, 22 girls aged 1 day-16 years) using high-angle DTI with optimised temporal gradient performance. D' and FA were calculated in 10 regions of interest in white matter. We saw that the age-related reduction in D' and increase in FA follow a mono- or biexponential model in white matter, probably depending on the compactness and myelination rate of the fibre tracts. In contrast to other areas, in which adult values were reached during the third year, there is a trend to continuous increase in FA in all deep white-matter areas, suggesting continuing maturation and organisation of deep tracts not detected on conventional MRI. (orig.)
We present the results of a search for Extreme Ultraviolet emission in A4059, a cluster with an X-ray emitting cluster gas. Our analysis of Extreme Ultraviolet Explorer (EUVE) Deep Survey observations of this cluster shows that it is associated with diffuse EUV emission. Outside the central 2 arcmin radius the entire EUV emission detected is explained by the low energy tail of the X-ray emitting gas. Within the central 2 arcmin region of the cluster we find a deficit of EUV emission compared to that expected from the X-ray gas. This flux deficit is discussed in the context of the cluster's cooling flow. The results derived for A4059 are compared to EUVE results obtained for other clusters such as Coma, Virgo, A1795, and A2199. As part of the study we have carried out a detailed investigation of the stability of the EUVE Deep Survey detector background. Based on long integrations of blank sky over 27 months we disprove claims of substantial time ...
The thermal contact resistance between balls and inner and outer rings of thermally steady space-use deep groove ball bearings was studied experimentally to verify the validity of the previously proposed calculation method for the resistance. The 440C stainless steel single row bearing was used for measuring its steady state temperature distributions in a vacuum environment under axial, radial and combined load conditions. As a result, the experimental results of the resistance well agreed with calculated ones under each load condition resulting in the sufficient validity at nearly the same surface roughness. It was necessary to apply a static equivalent radial load to calculation under the combined load that a contact angle is larger than the angle of resultant force dependent on both load components. In experiments under only radial load, measurement of outer ring temperatures was necessary at some points with no contact with balls to avoid the under estimation ...
The dynamical factors controlling the mean state and variability of the east Pacific intertropical convergence zone (ITCZ) and the associated cross-equatorial boundary layer flow are investigated using observations from the East Pacific Investigation of Climate (EPIC2001) project. The tropical east Pacific exhibits a southerly boundary layer flow that terminates in the ITCZ. This flow is induced by the strong meridional sea surface temperature (SST) gradient in the region. Away from the equator and from deep convection, it is reasonably well described on a day-to-day basis by an extended Ekman balance model. Variability in the strength and northward extent of this flow is caused by variations in free-tropospheric pressure gradients that either reinforce or oppose the pressure gradient associated with the SST gradient. These free-tropospheric gradients are caused by easterly waves, tropical cyclones, and the Madden Julian oscillation.Convergence in the boundary ...
We present deep two-dimensional spectra of 22 candidate and confirmed Lyman break galaxies (LBGs) at redshifts 2Deep Field (HDF) obtained at the Keck II telescope. The targets were preferentially selected with spatial extent and/or multiple knot morphologies, and we used slitmasks and individual slits tilted to optimize measurement of any spatially resolved kinematics. The median target magnitude was I_814=25.3, and total exposure times ranged from 10 to 50 ks. We measure redshifts, some new, ranging from z=0.2072 to z=4.056, including two interlopers at z<1, and resulting in a sample of 14 LBGs with a median redshift z=2.424. The morphologies and kinematics of the close pairs and multiple knot sources in our sample are generally inconsistent with galaxy formation scenarios postulating that LBGs occur only at the bottom of the potential wells of massive host halos; rather, they support ``collisional starburst'' ...
The analytical treatment of the nonperturbative QCD dynamics is one of the main open questions of the strong interactions. Currently, it is only possible to get some qualitative information about this regime considering other QCD-like theories, as, for example, the N=4 super Yang-Mills theory, where one can perform calculations in the nonperturbative limit of large 't Hooft coupling using the anti-de Sitter space/conformal field theory (AdS/CFT). Recently, the high energy scattering amplitude was calculated in the AdS/CFT approach, applied to deep-inelastic scattering and confronted with the F_2 HERA data. In this work we extend the nonperturbative AdS/CFT inspired model for diffractive processes and compare its predictions with a perturbative approach based on the Balitsky-Kovchegov equation. We demonstrate that the AdS/CFT inspired model is not able to describe the current F_2"D"("3") HERA data and predicts a similar behavior to that from the Balitsky-Kovchegov ...
Onshore and marine seismic-reflection data obtained near the Trans-Alaskan Crustal Transect (TACT), in the region of the eastern Aleutian trench and lower Cook Inlet, reveal highly reflective midcrustal layering that begins at a depth of 10-15 km within the upper plate of the Aleutian subduction zone. Beneath the continental shelf, midcrustal reflections were recorded over broad areas and occur in subhorizontal bands that are 1 to 3 s thick. The reflections extend beneath complexly deformed late Mesozoic and early Cenozoic accreted rocks that are exposed at the surface. Preliminary interpretation of seismic refraction data indicates that under the shelf the top of the reflections corresponds in depth with a sharp increase in rock velocity, from 5.9 km/s to 6.6 km/s. North and northwest of the shelf, beneath the Chugach and Kenai mountains, midcrustal features dip 20{degree}-30{degree} north or northwest, and below the Chugach Mountains, the top of the reflections corresponds to a ...
Experimental trials of autogenous deep penetration welding between dissimilar cast Ni-based superalloy K418 and alloy steel 42CrMo flat plates with 5.0 mm thickness were conducted using a 3 kW continuous wave (CW) Nd:YAG laser. The influences of laser output power, welding velocity and defocusing distance on the morphology, welding depth and width as well as quality of the welded seam were investigated. Results show that full keyhole welding is not formed on both K418 and 42CrMo side, simultaneously, due to the relatively low output power. Partial fusion is observed on the welded seam near 42CrMo side because of the large disparity of thermal physical and high-temperature mechanical properties of these two materials. The microhardness of the laser-welded joint was also examined and analyzed. It is suggested that applying negative defocusing in the range of Raylei length can increase the welding depth and improve the coupling efficiency of the laser materials ...
The DLTS technique was employed to study deep defect centers in Si doped epitaxial layers of Al_0_._3_7Ga_0_._1_6In_0_._4_7P grown by MOCVD as a part of epitaxial structure GaAs/AlGaInP/GaAs on GaAs substrates. A high concentration of DX centers located in a region near the inverted interface GaAs/Al_0_._3_7Ga_0_._1_6In_0_._4_7P was found. The width of this region with the maximum DX center concentration ranges from 5 to 20 nm. By filling the DX centers in the whole region, the activation energy for electron emission was found to be 0.48 eV. However, it is shown for the first time, that the activation energy of the DX center increases with increasing the distance from the GaAs/Al_0_._3_7Ga_0_._1_6In_0_._4_7P inverted interface. A nonuniform of the DX center concentration on the wafers is also observed. The concentration varies in the range of 1#centre dot#10"1"7 cm"-"3 - 10"1"8 cm"-"3. (author)
Because of its high price, the extra virgin olive oil is frequently target for adulteration with lower quality oils. This paper presents an innovative optical technique capable of quantifying the adulteration of extra virgin olive oil caused by lowergrade olive oils. It relies on spectral fingerprinting the test liquid by means of diffuse-light absorption spectroscopy carried out by optical fiber technology in the wide 400-1700 nm spectral range. Then, a smart multivariate processing of spectroscopic data is applied for immediate prediction of adulterant concentration.
In order to study the effects of microwaves on chemical reactions equipment was designed to acquire in-situ vibrational spectra of sol-gel components as they are irradiated with microwaves. Fourier Transform Infrared (FTIR) and Raman spectroscopy were used. A low temperature (10K) FTIR cell was used to trap samples in an argon matrix at 10{sup -7} Torr. For the liquid samples no differences were seen in spectra of irradiated and nonirradiated samples, but the argon matrix isolation technique showed dramatic differences.
The Drell-Yan mechanism for the production of lepton pairs is one of the most basic processes for physics studies at hadron colliders. It is therefore important to have accurate theoretical predictions. In this work we compute the two-loop virtual mixed QCD x QED corrections to Drell-Yan production. We evaluate the Feynman diagrams by decomposing the amplitudes into a set of known master integrals and their coefficients, which allows us to derive an analytical result. We also perform a detailed study of the ultraviolet and infrared structure of the two-loop amplitude and the corresponding poles in epsilon.
We report the first experimental achievement of a storage ring free-electron laser (FEL) oscillation on the third harmonic in the near-infrared region. The FEL gain was evaluated as 0.029% per mA. The measured linewidth of the third-harmonic FEL was less than that of the fundamental FEL, and the measured pulse width of the third-harmonic FEL was wider than that of the fundamental FEL. A higher-harmonic FEL should be developed not only to enhance the wavelength region of the FEL but also to vary the characteristics of an FEL micropulse. (author)
We present a high temperature heat oven with merits of conventional heat pipe oven and study ots thermal characteristics. The oven consists of stainless steel body and heating part of three layers of ceramic tubes. We obtained the maximum temperature of about 1350. deg. C at the center which was measured by thermocouple and infrared thermometer. And we compared the heating characteristics in the cases of external heating and no extent heating. It was applied to self diffraction experiment in the samarium gas which was one of the high melting point material.
The universe is full of exotic particles and waves. Some, such as neutrinos, pass through our neighbourhood unnoticed; others, such as extreme uv radiation, are absorbed by the upper atmosphere before they are able to do too much damage. For a long time, any systematic attempt to understand how our weather can be affected by extra-terrestrial sources other than solar visible and infrared radiation has been a lively and often controversial diversion from mainstream research. But recent scientific and technological breakthroughs and concern over long-term climate change have brought this subject into the spotlight.
Theoretical development for temperature measurements via narrow line, infrared absorption of carbon dioxide (CO{sub 2}) is presented. The proposed technique is based on rapid-scanning of two adjacent absorption line shapes. Spectroscopic considerations for sensitivity to temperature measurements are discussed. Several line pairs are evaluated, and the R(58) and R(60) transitions of the (00{sup 0}1){l_arrow}(00{sup 0}0) band are suggested for use in high temperature measurements for combustion systems.
A few metal complexes of isatin-isonicotinoylhydrazone with Ni(II), Cr(III), Co(II), Cu(II), Zn(II) and Cd(II) have been prepared and characterized on the basis of elemental analyses, infrared and electronic spectra as well as "1H NMR spectra, conductivity and magnetic measurements. In view of the results obtained, it has been found that two molecules of isatin-isonicotinoylhydrazone are chelated to the central metal ion as bis-uninegative ONO tridentate ligand forming non-electrolytic octahedral metal complexes. (author)
The fluorescence, absorption, infrared and Raman spectra of Sm/sub 3/Ga/sub 5/O/sub 12/ have been investigated. The energy-level schemes in the energy range 3000-16000 cm/sup -1/ have been determined. The number and symmetries of the Sm/sub 3/Ga/sub 5/O/sub 12/ crystal normal mode have been obtained by the molecular site group analysis and their comparison with the experiment has been made.
High-resolution spectroscopy of 13 bright red giants and Ba stars shows selective enhancement of Ba in three of them, HD 65699 (Ba 2), ..cap alpha..TrA (K4 III), and epsilonPeg (K2 Ib). Infrared spectra available for HD 65699 show that Sr is enhanced, too. This selective enhancement is discussed in terms of a modified s-process which converts some of the pre-existing r- and s-process matter into the magic nuclei /sup 88/Sr and /sup 138/Ba.
This report consists of three sections. The first section is a brief general overview of all the issues that impact the competition between natural gas and electricity in industrial applications. The second section of this report focus on the all the marketing issues and provides detail analysis of the status of these issues in Europe, Japan and United States. The third section of this report is a detail review of the current status of the competition between gas technologies and electro-technologies, it also make recommendation for developing new gas technologies. The fourth section is a contribution from M. Pettersson and S. Stenstroem, Sweden, on infrared dryers. (authors)
The following are reported: colorimetric determination of Ti in Cr, decontamination of metals by anodic dissolution, computer code for x-ray peak identification, gel-permeation chromatography of CoRezyn 1664 polyester resin, infrared monitoring of gases and vapors, particle size analysis of dusts, nondestructive analysis of Oralloy for removable alpha contamination, dissolution (digestion) of high-fired oxides, assay of U in a Pu-U alloy, measurement of oxide thickness on Pu metal by x-ray diffraction, analysis of precipitated Pu peroxide, differentiation of Dowex SBR and 11 resins, and determination of Pu solubility in simulated lung fluid.
We present a recent study of the QCD corrections to dilepton production near partonic threshold in transversely polarized {bar p}p scattering, We analyze the role of the higher-order perturbative QCD corrections in terms of the available fixed-order contributions as well as of all-order soft-gluon resummations for the kinematical regime of proposed experiments at GSI-FAIR. We find that perturbative corrections are large for both unpolarized and polarized cross sections, but that the spin asymmetries are stable. The role of the far infrared region of the momentum integral in the resummed exponent and the effect of the NNLL resummation are briefly discussed.
Microwave Electron Cyclotron Resonance (ECR) Plasma assisted Chemical Vapor Deposition (CVD) technology has been used to prepare Si_3N_4 films, which were analyzed by using infrared (IR) transmission spectroscopy and XPS. The analysis results show that with the increase of the deposition temperature, the H content decrease, and the densification of the film increases. When the temperature is up to 360 degree C, the stoichiometrical rate of Si:N is close to 0.75. The protective property of Si_3N_4 films is also examined
We have prepared a series of novel gemini surfactants having ester bonds in their structures. These surfactants possess two identical hydrophilic polyethylene glycol moieties, two hydrophobic alkyl group moieties, and an anionic spacer. The structures of these compounds were confirmed through infrared and nuclear magnetic resonance spectroscopic and elemental analyses. The novel gemini surfactants exhibit excellent surface activity in terms of their surface tension, low-foaming, wetting power, and fluorescence properties. The presence of the ester linkages made these structures cleavable surfactants.
Zeolite Y is the active component of most commercial cracking catalysts. Interaction of H[sub 3]PO[sub 4] with extraframework aluminum of ultra-stable zeolite (USY) leads to the formation of different types of aluminum phosphates, while there is no indication of the formation of SAPO zeotype structures. The total acidity of USY slightly decreases upon the H[sub 3]PO[sub 4] treatment, while the maximum in the distribution of acid strength is shifted to milder acidities. Dealumination of the zeolite and creation of POH sites associated with AIPO[sub 4] are responsible for the modifications observed. 37 refs., 8 figs., 3 tabs.
Initial design parameters and early operational results of a 50 MeV high brightness electron linear accelerator are described. The system utilizes a radio frequency electron gun operating at a frequency of 2.856 GHz and a nominal output energy of 4.5 MeV followed by two, 2#pi#/3 mode, disc loaded, traveling wave accelerating sections. The gun cathode is photo excited with short (6 psec) laser pulses giving design peak currents of a few hundred amperes. The system will be utilized to carry out infra-red FEL studies and investigation of new high gradient accelerating structures.
The influence of microalloying vanadium or titanium on improving the corrosion resistance of mild steel in saturated calcium hydroxide solution was investigated. Potential-time, potentiodynamic polarization, and impedance measurement techniques were employed. The corrosion products have been examined by infrared and X-ray diffraction analysis and by scanning electron microscopy. It has been shown that the grain refining, due to microalloying, plays an important role in enhancing the corrosion resistance of steel. Scales of calcite and iron oxides on top of a protective oxide are formed on the investigated steels.
The aim of this work is to determine and compare the dosimetric properties of NaCl and KCl samples using infrared-stimulated luminescence (IRSL) technique. For a material to be used as dosimeter, both the IRSL temperature dependence and the radiation dose response have critical importance. In this work the IRSL characteristics from NaCl and KCl samples were experimentally investigated as a function of temperature and laboratory radiation doses. Dosimetric properties of NaCl and KCl samples were found significantly different. The IRSL signals displayed by NaCl were found to be more stable, reliable and agreeable than those of KCl.
The crystal structure and optical reflectivity of AlP has been studied in a diamond anvil cell using energy dispersive x-ray diffraction to 43 GPa and micro-optical reflectance spectroscopy to 36 GPa. AlP undergoes a first order phase transformation from zincblende to a NiAs structure which exhibits metallic reflectivity in the near-infrared. The decrease in volume on transformation is 17%[plus minus]1%. The transformation is reversible but has large hysteresis. The equilibrium transformation pressure is 9.5[plus minus]5 GPa.
Compton backscattering of laser photons near the interaction point of an e"+e"- or e"-e"- collider can be used to produce a #gamma#-#gamma# or #gamma#-e"- collider. This paper describes the laser requirements, including pulse duration, intensity, energy, and wavelength, for such a collider. For most of the proposed, next generation, e"+e"- colliders, the laser wavelength should be in the near-infrared, with a pulse duration of 1 ps or less and an energy of similar 1 J per pulse. Current chirped pulse amplification laser systems in solid state lasing materials are well suited to meet these requirements. These systems are described. ((orig.)).
The authors describe measurements of emittance made on samples of solar cell coverglasses incorporating new coatings both on C-7940 fused silica and on CMX ceria doped microsheet. Samples of a conventional, MgF_2 coating on the same two types of coverglass substrates were included in the measurements as controls. Measurements were made by the calorimetric method of total hemispherical emittance within a cooled chamber as well as by the more common infrared reflectance method. Emittance enhancements from 1 to 4% were measured for the new coatings.
Coherent x-ray production by a seeded free electron laser (FEL) is important for next generation synchrotron light sources. The authors examine the feasibility and features of FEL emission seeded by a high-order harmonic generation (HHG) of an infrared laser. In addition to the intrinsic FEL chirp, the longitudinal profile and spectral bandwidth of the HHG seed are modified significantly by the FEL interaction well before saturation. This smears out the original attosecond pulselet structure. The authors introduce criteria for this smearing effect on the pulselet and the stretching effect on the entire pulse. They discuss the noise issue in such a seeded FEL.
Emission spectra obtained for three irradiated granular quartz samples under 1.43 eV excitation exhibited the 2.2 and 3.1 eV emission bands characteristic of feldspars. Excitation spectra of these same samples and several others show the 1.44 eV resonance typical of feldspars. This provides convincing evidence that the 2.2 and 3.1 eV infrared stimulated luminescence observed in these granular quartz samples arises from feldspar inclusions.
We demonstrated that the intensity levels and lifetimes of two-photon autofluorescences (2PAF) in human liver tissues can be exploited to diagnose hepatocellular carcinoma (HCC). Excited by an infrared femtosecond laser, we suppressed the two-photon autofluorescences of most endogenous fluorophores and made red autofluorescences more specific to particular molecules in the cryo-sectioned human livers. Using such fluorescence contrast, we found HCC tissues have reduced levels of 2PAF and longer fluorescence lifetime.
The foils of various materials were irradiated with "6"0Co with an activity of 11,538 TBq. The minimum radiation dose was 25 kGy. Changes in chemico-physical properties were evaluated by infrared spectroscopy and were not detected after irradiation with 25 kGy. Packing foils were subjected to the following tests: mechanical tests, tests of weld strength, tests of impact resistance, free fall tests, permeability tests for water vapour and microbiological tests. The results of all tests were tabulated. The tests showed that the foils are impermeable for microorganisms and provided the welds are airtight the packed products remain sterile. (J.P.).
There have been many recent explosive advances in both IR and Raman spectroscopy which have developed in response to industrial problems of increasing complexity. Probably the biggest factor in these advances has been computerization, which has contributed not only to substantial improvements in data handling but to enormous gains in sensitivities of analyses as well. In this paper numerous examples of Raman and IR applications in industry are given using many of these recent advances, including in-situ techniques, microprobe analyses, unusual combinations of instruments - i.e., hyphenated methods - and new sample handling techniques. The bright future of FT-IR and Raman spectroscopy is also briefly discussed.
Acetylacetone is isolated in hydrogen matrices and is investigated by means of infrared spectroscopy, combined with theoretical calculations. The two stable enol and keto tautomers are well characterized. The keto/enol ratio in solid parahydrogen is found to be higher than in classical matrices. While vibrational bands of the enol form are broad, with bandwidths depending on the vibrational mode, those of the keto form are narrow. A KrF laser excitation is used to induce the enol/keto tautomerization in solid parahydrogen. The kinetics of the interconversion is followed, highlighting a non-direct tautomerization process.
A new method is described for the analysis of high precision pulse annealing data obtained using IRSL measurements on potassium feldspars using a Risoe reader. Presenting the data as the percentage of the signal lost per annealing phase permits more detailed comparisons to be made between samples. In addition, it is possible to directly compare the temperatures at which the TL and IRSL signals are released, thus giving information about the relationship between them. This method of analysis is applied to pulse annealing data for natural, irradiated, preheated and IR bleached aliquots. (author).
A brief overview is given of the geological characteristics of each region of the state as they relate to potential geothermal development. Those exploration methods which can lead to the siting of a deep exploration well are described. Requirements and techniques needed for drilling deeper higher temperature exploration and production wells are presented. Electrical generation, direct utilization, and indirect utilization are reviewed. Economic factors of direct use projects are presented. A general guide to the regulatory framework affecting geothermal energy development is provided. The general steps necessary to gain access to explore, develop, distribute, and use geothermal resources are outlined. (MHR)
In this paper uptake of tritium by market foods from tritiated water vapor in the air is investigated using cereals and beans purchased in Deep River, Canada. The concentrations of tissue free water tritium (TFWT) and organically bound tritium (OBT) range from 12 to 79% and from 10 to 38% respectively, of that estimated for atmospheric water vapor of the sampling month. The specific activity ratios of OBT to TFWT were constant for cereals, but variable for beans. The elevated OBT was shown to be the result of isotopic exchange of labile hydrogen by the fact that washing the foods with tritium free-water reduced their tritium contents to levels characteristic of their production sites.
Physicists are no strangers to Feynman diagrams, but the meaning of the diagrams is not always clear, even to those who have used them. That confusion has deep roots, as Kaiser clearly and convincingly explains. To Feynman himself, a diagram depicted an actual physical process in space-time, such as the exchange of photons that occurs when an electron and proton collide. However, he also saw it as shorthand for the contributions to the amplitude of a physical process made by the element of the process it depicted. The best part of this new book covers the early history, social history and 'conceptual history' of Feynman diagrams. Disagreements and criticisms aside, the book will be invaluable to historians and sociologists of physics interested in the growth of Feynman diagrams. (U.K.)
Gas hydrates have impacted the oil and gas industry since 1934, when they were first found to plug pipelines. Today we know that in deep oceans and in permafrost, very substantial gas reserves are present in hydrated form. Concerns are being raised about in situ dissociation for both energy and greenhouse implications upon methane release. In Japan work is underway to consider the storage of carbon dioxide, concentrated in clathrates. This talk will deal with some basic questions. Why should we be interested in gas hydrates? What are gas hydrates? How do gas hydrates form? How might hydrates impact on the energy/environmental picture?
A subsurface imaging system is utilized to test the ability of the spectral polarization difference imaging technique for deep subsurface imaging in tissues. The illumination of the system is derived from compact class III lasers in the red and NIR spectral region and, alternatively, from a white light source and selection of the appropriate illumination wavelength using band-pass optical filters. The experimental results demonstrate detection and imaging of a high-scattering object located up to 1.5 cm underneath the surface of a host chicken tissue.
The structure functions (SF) of nuclei determined within the framework of the flucton model with rescaling (FMR) are compared with new experimental data of the ITEP on cumulative #pi#-meson yield in a wide range of the scale variable X (1deep inelastic lepton scattering by nuclei within the FMR framework and experimental data on #pi#"+-meson production on Be, Al, Cu, Ta nuclei in cumulative region has confirmed the hypothesis of limiting fragmentation.
This is a study done in collaboration with Deidre Hunter at Lowell Observatory studying star formation in two luminous spiral galaxies NGC 801 and UGC 2885. We used ultra-deep H? images taken at the KPNO 2.1 m telescope. We compare these data to stellar images at various wavelengths and to HI maps to determine the extent of star formation activity into the outer disk in these galaxies and its relationship to the gas and older stars. TW is grateful for an REU internship during the summer of 2010 at Northern Arizona University, funded by NSF through grant AST-1004107.
Thomas Jefferson National Accelerator Facility experiment E01-012 measured the 3He spin structure functions and virtual photon asymmetries in the resonance region in the momentum transfer range 1.0 < Q2 < 4.0 (GeV/c)2. Our date, when compared with existing deep inelastic scattering data, can be used to test quark-hadron duality in g1 and A1 for 3He and the neutron. Preliminary results for A{sub 1}{sup {sup 3}He} are presented, as well as some details about the experiment.
we report an ultrafast synchrotron x-ray phase contrast imaging study of the primary breakup mechanism of a coaxial air-assisted water jet. We demonstrate that there exist great similarities in the phenomenology of primary breakup with that of the secondary breakup. Especially, a membrane-mediated breakup mechanism dominates the breakup process for a wide range of air speeds. This finding reveals the intrinsic connections of these two breakup regimes and has deep implications on the unified theoretical approach in treating the breakup mechanism of high speed liquid jet.
The SRP Baseline Hydrogeologic Investigation was implemented for the purpose of updating and improving the knowledge and understanding of the hydrogeologic systems underlying the SRP site. Phase III, which is discussed in this report, includes the drilling of 7 deep coreholes (sites P-24 through P-30) and the installation of 53 observation wells ranging in depth from approximately 50 ft to more than 970 ft below the ground surface. In addition to the collection of geologic cores for lithologic and stratigraphic study, samples were also collected for the determination of physical characteristics of the sediments and for the identification of microorganisms.
SP-700, an emerging #beta#-rich #alpha#+#beta# titanium alloy, is designed to improve superplastic formability as well as mechanical properties over Ti-6Al-4V alloy. Owing to its fine microstructure and low #beta#-transus temperature, it is superplastic-formable at temperature below 1,073K (800 C) with low flow stress. Remarkable workability of this alloy is also retained in conventional Manufacturing processes. Another advantage of SP-700 is heat treatment response which includes deep hardenability and quick aging kinetics. Corrosion resistance and machinability are equivalent to or better than Ti-6Al-4V alloy.
Annual averages of the diurnal variation in cosmic ray intensity from neutron monitors in Deep River and Oulu and underground muon telescopes in Bolivia and at Embudo and Socorro, New Mexico, have been determined as a function of the sense of the interplantary magnetic field for the years 1965--1975. These data point to a cosmic ray density gradient, perpendicular to the ecliptic plane, pointing southward prior to 1969 and changing to a northward pointing gradient after the reversal of the sun's polar magnetic field in 1969--1971. This result supports numerical calculations for the prereversal and postreversal field configurations at intermediate and high cosmic ray rigidities.
This article considers the appeal of cognitive neuroscience research to the general public within the context of the deep puzzles involved in using our minds to understand how our minds work. It offers a few promising examples of findings that illuminate the ways of the mind and reveal these workings to be counter-intuitive with our subjective experience. However, this promise is tempered by the powerful role that perception, attention, and cognition play in how we reason about evidence. It argues that the interplay between what we believe about the nature of our minds and what the findings suggest constitutes a primary challenge in encouraging public understanding of cognitive neuroscience findings.
Fifty patients scheduled to undergo IVF received a standard anesthetic of fentanyl and propofol for induction, followed by propofol infusion, with Bispectral index values and modified Ramsey sedation scores recorded at 5-minute intervals for the duration of anesthesia care. Moderate sedation was found only transiently during the first 5-10 minutes of the oocyte retrieval, but thereafter the level of sedation increased, with deep sedation and general anesthesia measured in all patients as determined by both the Bispectral index scores and lack of response to painful stimulation.
Results are given for deep-level petroleum and gas drilling probes in various coastal zones of Southern Sakhalin covering the Poronai depression and the Aniv Bay trough. The exploratory probes indicate that the Middle Miocence deposits of the Boundary trough contain commercial-size deposits of petroleum, that commercial-size gas deposits are in the upper Myocene deposits of the Aliv Bay trough, and that the upper Cretaceous and Cenozoic deposits of the eastern section of Southern Sakhalin lack folded deformations. 7 references, 2 figures.
Convective losses arising from buoyancy driven flow were calculated for a two-dimensional model simulating a solar cavity receiver. The TEMPEST code, capable of fully three-dimensional coupled thermal-hydraulic transient calculations, was used for the simulation. Predicted velocity and temperature results for a 2.59 m deep by 2.88 m high rectangular cavity with an aperture opening of 1.72 m were used to determine convective losses for prescribed interior wall temperatures and cavity orientation. Velocity vector and temperature isotherm plots were used to analyze flow characteristics.
This talk reviews the history of the Canadian nuclear-electric program highlighting Canada's first nuclear power station, the Nuclear Power Demonstration or NPD. NPD was commissioned and delivered electricity to Canadian consumers for the first time on june 4, 1962. The Canadian nuclear-electric program is based on the CANDU-PHW (Canadian Deuterium Uranium - Pressurized Heavy Water) concept which was conceived between 1955 and 1958 at the Chalk River Nuclear Laboratory (CRNL) of AECL, located a few miles from Deep River. This talk covers the history of the Canadian nuclear-electric activities dating back to 1939.
A Monte Carlo method called transient curve fitting method was developed to calculate a eigenvalues by first simulating the existing neutrons and precursors in the system, then calculating the Eigen-distribution of neutron flux and calculating the a eigenvalues using the transient results based on the Eigen-distribution by the code TMCC. The results of this method are tested by calculating Godiva Benchmark problems and they agree well with the benchmark results. Then the reasonable results of Subcritical Facility in Tsinghua University are given by TMCC, and the results are compared with the experimental results measured by Rossi-a method. Even in the deep subcritical cases, the method can give results consistent with experimental results. (authors)
The ANDRA, the French national agency of radioactive wastes, is organizing today the information needs of tomorrow. The aim is to allow the future generations to have access to the knowledge of the existence of subsurface radioactive waste facilities and to understand the context and technologies of such facilities. The storage of this information is made on 'permanent paper', a high resistant paper with a lifetime of 600 to 1000 years. An updating of these data is made every 5 years for each waste disposal center. Another project, still in progress, concerns the memory management of deep geologic waste disposal facilities for which the time scale to be considered is of the order of millennia. (J.S.)
In this project we developed photonic crystal modeling capability and fabrication technology that is scaleable to large area. An intelligent optimization code was developed to find the optimal structure for the desired spectral response. In terms of fabrication, an exhaustive survey of fabrication techniques that would meet the large area requirement was reduced to Deep X-ray Lithography (DXRL) and nano-imprint. Using DXRL, we fabricated a gold logpile photonic crystal in the <100> plane. For the nano-imprint technique, we fabricated a cubic array of gold squares. These two examples also represent two classes of metallic photonic crystal topologies, the connected network and cermet arrangement.
In the United States, economic growth increasingly requires that greater volumes of freshwater be made available for new users, yet supplies of freshwater are already allocated to existing users. Currently, water for new users is made available through re-allocation of xisting water supplies-for example, by cities purchasing agricultural water rights. Water may also be made available through conservation efforts and, in some locales, through the development of ''new'' water from non-traditional sources such as the oceans, deep aquifer rackish groundwater, and water reuse.
A carbon nanotube (CNT) tip, which assembled on the sharp end of a Si tip by dielectrophoresis, was structurally modified using focused ion beam (FIB). We described the imaging characterization of the FIB-modified CNT tip in noncontact AFM mode in terms of wear, deep trench accessibility, and imaging resolution. Compared to a conventional Si tip, the FIB-modified CNT tip was superior, especially for prolonged scanning over 10 h. We conclude that modified CNT tips have the potential to obtain high-quality images of nanoscale structures.
In the groundwater flow modelling part of this work the effective dilution volume in the well scenario was estimated by means of transient simulations of groundwater flow and transport, which are coupled due to the varying salinity. Both deep, drilled wells and shallow surface wells in the vicinity of the repository were considered. The simulations covered the time period from the present to 1000 years after the present. Conceptually the fractured bedrock consists of planar fracture zones (with a high fracture density and a greater ability to conduct water) and the intact rock (in which the fracture density and the hydraulic conductivity are low). For them the equivalent-continuum model was applied separately. Thus, the fractured bedrock was considered as piecewise homogeneous (except for the depth dependence) and isotropic continuum with representative average characteristics. A generic simulation model for groundwater flow and solute transport was developed on ...
In a supercritical water-cooled reactor, property of water changes significantly around the critical point. It is expected that irradiation and change of water property will affect the chemistry and material corrosion. Deep understanding of interactions between supercritical water and materials under irradiation is important. However, comprehensive data on radiolysis, kinetics, corrosion and thermodynamics have not been obtained due to the severe experimental condition. To get such data by experiments and computer simulations, a national program funded by Ministry of Education, Culture, Sports, Science and Technology (MEXT) has been started since December 2002. (author)
We proposed and numerically investigated the influence of spatial symmetry on the terahertz frequency region response of composite planar metamaterials based on deformed split ring resonators. Compared with the original simple structures, the composite metamaterials with different spatial symmetries exhibited exotic electromagnetic properties. The electromagnetic response of a specific configuration with C4 symmetry was identical to the structure with simple lattice. Especially, for configurations with broken symmetry, very sharp Drude-like resonances with high quality factor were observed. The electric field and current distribution associated the resonances were analyzed for deep understanding of the underlying physical properties.
A clear and reproducible transition to a regime with an improved particle confinement is routinely observed on the CASTOR tokamak, if the biasing electrode is inserted deep enough into the plasma (r/a?0.5) and biased up to +250 V. The steepening of the radial profiles of the plasma density and potential demonstrate the formation of a transport barrier just inside the last closed flux surface. Fast relaxations of the edge plasma parameters, with a frequency of about 10 kHz, are observed when the average radial electric field within the barrier prevails values of about 20 kV/m. A detailed analysis of the spatial-temporal behaviour of these relaxations is presented.
An estimate of the tritium dose to the public in the vicinity of the heavy water research reactor facility at AECL-Chalk River Laboratories, Ontario, Canada, has largely been accomplished from analyses on regularly-collected samples of air, precipitation, drinking water and foodstuffs (pasture, fruit, vegetables and milk) and environmental dose models. To increase the confidence with which public doses are calculated, tritium doses were estimated directly from the ratio of tritiated species in urine samples from members of the general public. Single cumulative 24 h urine samples from a few adults living in the vicinity of the heavy-water research reactor facility at Chalk River Laboratories, Canada were collected and analysed for tritiated water and organically bound tritium. The participants were from Ottawa (200 km east), Deep River (10 km west) and Chalk River Laboratories. Tritiated water concentrations in urine ranged from 6.5 Bq.l{sup -1} for the Ottawa ...
It is noted that the existence of cosmic-ray semidiurnal anisotropy of interplanetary origin has generally been attributed to the symmetrically rising density gradients perpendicular to the solar equatorial plane. An increase in the magnitude of the semidiurnal anisotropy of cosmic rays during the years 1973-1975 by a factor of 2 is in theory expected to be associated with larger magnitudes of the heliolatitudinal density gradients. The distribution of cosmic-ray intensity in the heliolatitude range + or - 7.25 deg obtained using the data of the Deep River neutron monitor is shown not to support the density gradient hypothesis. The presence of symmetrical gradients at higher heliolatitudes, however, cannot be ruled out.
Optimal neutron energy for boron neutron capture therapy (BNCT) has been studied. Epithermal neutron is superior to thermal neutrons in treating deep-seated tumors. Design of the epithermal neutron column for BNCT has been performed by using a two-dimensional transport calculation code. Aluminum and heavy water are used as moderation materials. A thermal neutron column is also designed using heavy water as thermalization material. The configuration of the facility for treatment and research of BNCT and also for basic radio-biological studies of neutrons has been presented.
Optimal neutron energy for boron neutron capture therapy (BNCT) has been studied. Epithermal neutron is superior to thermal neutrons in treating deep-seated tumors. Design of the epithermal neutron column for BNCT has been performed by using a two-dimensional transport calculation code. Aluminum and heavy water are used as moderation materials. A thermal neutron column is also designed using heavy water as thermalization material. The configuration of the facility for treatment and research of BNCT and also for basic radio-biological studies of neutrons has been presented. (author).
Using near-field optical microscopy, the authors investigate propagation of channel plasmon polaritons excited in the wavelength range of 1425-1640 nm along smoothly bent and split V-shaped grooves milled in a gold film. We find that for 0.6-?m-wide and 1.1-?m-deep grooves bent with the smallest curvature radius of ?0.83 ?m, the double bend (for S bends) and splitting (for Y splitters) losses decrease for longer wavelengths approaching (in the wavelength range of 1600-1640 nm) the levels of ~0 and 0.5 dB, respectively.
We present a method for the analysis of singularities of Feynman amplitudes based on the Speer sector decomposition of the Schwinger parametric integrals combined with the Mellin-Barnes transform. The sector decomposition method is described in some details. We suggest the idea of applying the method to the analysis of collinear singularities in inclusive QCD cross sections in the mass-less limit regularizing the forward amplitudes by an off-shell choice of the initial particle momenta. It is shown how the suggested strategy works in the well known case of the one loop corrections to Deep Inelastic Scattering.
A brief overview is given of the geological characteristics of each region of the state as they relate to potential geothermal development. Those exploration methods which can lead to the siting of a deep exploration well are described. Requirements and techniques needed for drilling deeper higher temperature exploration and production wells are presented. Electrical generation, direct utilization, and indirect utilization are reviewed. Economic factors of direct use projects are presented. A general guide to the regulatory framework affecting geothermal energy development is provided. The general steps necessary to gain access to explore, develop, distribute, and use geothermal resources are outlined. (MHR)
A large acceptance, high stopping power Bragg curve spectrometer has been developed for use in coincidence experiments with heavy ions. The electron collection fields are radial and position information is obtained from a resistive anode. The detector is 60 cm deep and operates at pressures of up to 2.5 atm of P-10 gas. It is mated to a scattering chamber which allows it to be moved out of plane during coincidence measurements. Factors affecting the performance of the detector are discussed, and results obtained with the detector are presented. (orig.).
A large acceptance, high stopping power Bragg curve spectrometer has been developed for use in coincidence experiments with heavy ions. The electron collection fields are radial and position information is obtained from a resistive anode. The detector is 60 cm deep and operates at pressures of up to 2.5 atm of P-10 gas. It is mated to a scattering chamber which allows it to be moved out of plane during coincidence measurements. Factors affecting the performance of the detector are discussed, and results obtained with the detector are presented. (orig.).
The gas phase high resolution spectroscopic study of weakly bound clusters can provide the information necessary to develop an intermolecular potential energy surface. This surface can then be used to better understand condensed phases. In this work, a tunable far infrared laser spectrometer is used to study weakly bound dimers produced in the newly developed continuous planar supersonic jet expansion apparatus. The water dimer is an extensively studied hydrogen bonded dimer. It undergoes several tunneling motions which result in splittings and perturbations of the rovibrational energy levels. A review is presented of much of the experimental and theoretical work done on water dimer, including a description of the combined fit of all the high resolution spectroscopic results by Coudert and Hougen. Also included is a discussion of the measurement of the K = 1 lower {yields} K = 2 lower band performed using the tunable far infrared laser/planar ...
In order to investigate the systematics of the loop expansion in high temperature gauge theories beyond the leading order hard thermal loop (HTL) approximation, we calculate the two-loop electron proper self-energy #SIGMA# in high temperature QED. The two-loop bubble diagram of #SIGMA# contains a linear infrared divergence. Even if regulated with a nonzero photon mass M of order of the Debye mass, this infrared sensitivity implies that the two-loop self-energy contributes terms to the fermion dispersion relation that are comparable to or even larger than the next-to-leading order (NLO) contributions of the one-loop #SIGMA#. Additional evidence for the necessity of a systematic restructuring of the loop expansion comes from the explicit gauge-parameter dependence of the fermion damping rate at both one and two loops. The leading terms in the high temperature expansion of the two-loop self-energy for all topologies arise from an explicit ...
Infrared spectra of bicyclo[1.1.1]pentane (C5H8) have been recorded at a resolution (0.0015 cm-1) sufficient to resolve for the first time individual rovibrational lines. This initial report presents the ground state constants for this molecule determined from the detailed analysis of three of the ten infrared-allowed bands, v14(e?) at 540 cm-1, v17(a2?) at 1220 cm-1, v18(a2?) at 832 cm-1, and a partial analysis of the v11(e?) band at 1237 cm-1. The upper states of transitions involving the lowest frequency mode, v14(e?), show no evidence of rovibrational perturbations but those for the v17 and v18 (a2?) modes give clear indication of Coriolis coupling to nearby e? levels. Accordingly, ground state constants were determined by use of the combination-difference method for all three bands. The assigned frequencies provided over 3300 consistent ground state difference values, yielding the following constants for the ground state (in units of ...
The deep borehole heat exchanger (BHE) of Weggis is operational since 1994. During the years 1995 to 2000 the BHE has produced for both, direct heating and as a source for the heat pumps, a yearly amount of heat of 220 MWh. The share of direct heating has been more than 60%. The global average power delivered to all consumers has been about 100 kW. This has yielded to a mean source temperature out of the deep BHE of 40.5 {sup o}C and to a mean return temperature of 33.3 {sup o}C. During the years 2000 and 2001 three additional multi-family dwellings have been connected as heat consumers to the BHE. The amount of delivered heat has nearly been doubled (from 220 to 440 MWh per year) as well as the nominal load. This has induced a small reduction of the delivery temperature and a significant reduction of the return temperature to the BHE (37.2 {sup o}C and 29.9 {sup o}C respectively). As a result, the direct heating share has been reduced to 8%. ...
The long-term aim of our research is to develop humidification-dehumidification desalination technology for farms in arid coastal regions that are suffering from salt-infected soils and shortages of potable groundwater. The specific aim of our current study was to determine the influence of greenhouse-related parameters on a process, called Seawater Greenhouse, which combines fresh water production with growth of crops in a greenhouse system. A thermodynamic model was used based on heat and mass balances. The dimension of the greenhouse had the greatest overall effect on the water production and energy consumption. A wide shallow greenhouse, 200 m wide by 50 m deep gave 125 m{sup 3} d{sup -1} of fresh water. This was greater than a factor of two compared to the worst-case scenario with the same area (50 m wide by 200 m deep), which gave 58 m{sup 3} d{sup -1}. Low power consumption went hand-in-hand with high efficiency. The wide shallow ...
Coal is present in the Alberta Foothills/Mountains in five zones: the Kootenay, Gething, Gates, Brazeau and Coalspur coal zones. For coalbed-methane (CBM) evaluation purposes, they can be divided into shallow (less than 1000 m depth) and deep (greater than 1000 m depth) coal zones. The potential gas content of all shallow coal zones totals about 878x10{sup 9} m{sup 3} (31 Tcf) of CBM, which is considered an inferred, initial, in-place, coalbed-methane resource estimate based on limited data. The limited amount of data on formation testing and measured gas content indicate that the inferred resource is bordering on the speculative category. The gas content of all deep coal zones (deeper than 1000 m) totals 2.8x10{sup 12} m{sup 3} (about 99 Tcf) of in-place coalbed-methane gas. Consequently, the total ultimate coalbed-methane resource could be 3.7x10{sup 12} m{sup 3} (130 Tcf). However, coalbed-methane recovery from deep ...
The first sediments to onlap the metamorphosed Precambrian Arabian shield were Infracambrian (Proterozoic) to Middle Cambrian carbonates, clastics, and evaporites. The oldest Arabian reservoir rocks occur in the Precambrian to lower Paleozoic Era Salt of the Huqf Group, which forms the Birba field of Oman. The Middle Cambrian sequence was followed by Late Cambrian through Early Permian marine sandstones and continental to littoral siltstones and variegated shales. The first commercial oil discovered in the Arabian Gulf region occurs in fluvial sands of the Ordovician to Permian Haima and Haushi Groups of the Marmul field in south Oman. These strata are also productive in other fields and are sealed by unconformable contact with the Al Khlata Formation or beneath shale of the Albian Nahr Umr Formation. The deeply buried kerogen sediments of the Huqf Group to the southeast are believed to be the source rocks for these fields of south Oman. The Late Permian to Triassic deposits of the ...
The aim of the project is to study the conditions and processes occurring in permanently frozen crystalline bedrock, with special reference to deep (i.e., several hundreds of meters) bedrock conditions. The target of the study is the Lupin mine in Nunavut Territory, Northern Canada. The results may be utilized in assessing the long-term performance of deep underground constructions (e.g., nuclear waste repositories) in cooling climatic conditions. In Phase I of the project versatile background information was collected from the site e.g., on climate, geology and on hydrogeological and hydrogeochemical conditions. During Phase II a broad range of research was conducted including (i) electromagnetic soundings to investigate the distribution of permafrost in the surroundings of the mine; (ii) drilling of three research boreholes at the base of the permafrost for groundwater research; (iii) application of borehole video surveys to study the ...
This report covers the period from October 1, 1992 to March 1, 1993. The overall goals of the program task are to provide a final synthesis of six deep seismic reflection profiles and other geological and geophysical data from the southern Washington Cascades region where a probable extensive deep sedimentary basin has been discovered. This deep sedimentary basin is hypothesized from geological, regional magnetotelluric (MT), gravity, magnetic , and seismic reflection data as described in the American Association of Petroleum Geologists (AAPG) article by Stanley and others (1992). This report analyzed three seismic reflection profiles acquired by the Morgantown Energy Technology Centers in combination with the extensive MT and other data to outline a probable geological model for a thick conductive section of rocks in the southern Washington Cascades (called the Southern Washington Cascades conductor, SWCC). Earlier MT ...
Early in the Cold War, the United States adopted a policy of ''extended nuclear deterrence'' to protect its allies by threatening a nuclear strike against any state that attacks these allies. This threat can (in principle) be used to try to deter an enemy attack using conventional weapons or one using nuclear, chemical, or biological weapons. The credibility of a nuclear threat has long been subject to debate and is dependent on many complex geopolitical factors, not the least of which is the military capabilities of the opposing sides. The ending of the Cold War has led to a significant decrease in the number of strategic nuclear weapons deployed by the United States and Russia. START II, which was recently ratified by the Russian Duma, will (if implemented) reduce the number deployed strategic nuclear weapons on each side to 3500, compared to a level of over 11,000 at the end of the Cold War in 1991. The tentative limit established by Presidents ...
We create realistic, full-sky, half-arcminute resolution simulations of the microwave sky matched to the most recent astrophysical observations. The primary purpose of these simulations is to test the data reduction pipeline for the Atacama Cosmology Telescope (ACT) experiment; however, we have widened the frequency coverage beyond the ACT bands and utilized the easily accessible HEALPix map format to make these simulations applicable to other current and near future microwave background experiments. Some of the novel features of these simulations are that the radio and infrared galaxy populations are correlated with the galaxy cluster and group populations, the primordial microwave background is lensed by the dark matter structure in the simulation via a ray-tracing code, the contribution to the thermal and kinetic Sunyaev-Zel'dovich (SZ) signals from galaxy clusters, groups, and the intergalactic medium has been included, and the gas prescription to ...
This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies ...
The Dalia field is located 210 km north west of Luanda (Angola), about 140 km from shore in 1400 meter water-depth. It was the second major discovery out of 15 made in the block 17 operated by Total. The Dalia Umbilical, Flow lines and Risers EPCI Contract was awarded in 2003. The sea-line network to connect and control the 71 wells and 9 manifolds consist of the following: 40 km of insulated pipe in pipe (12 inches into 17 inches) production flow lines; 45 km of 12 inches water and gas injection lines; 6 off 1.7 km flexible water and gas injection risers; 8 off 1.65 km flexible Integrated Production Bundle (IPB) risers; 75 km of control umbilicals. The flow assurance and associated insulation requirement of the production transport system was one of the main challenges of the project. With a crude temperature of 45 deg C at the wellhead and the required minimum temperature of 35 deg C on arrival at the FPSO, this problem was complex. Understanding that, due to the Joule Thompson ...
The present paper is a comparative study of the cerium-containing nickel catalysts supported on x- and y-zeolites. In general, the addition of cerium ions caused an increase in the catalytic activity for CO hydrogenation and shifted the product selectivity to high molecular weight hydrocarbons. The degree of the effect of cerium additive depends on the ratio of cerium to nickel contents, the reduction temperature, and the nature of the supporting materials. Catalyst characterization, including volumetric hydrogen chemisorption, temperature programmed reduction/desorption, x-ray diffraction, surface area measurements, in-situ infrared spectroscopy and x-ray photoelectron spectroscopy, was performed in order to interpret the phenomena due to the effects of cerium additives and the support effect on Ni/zeolite catalysts.
The infrared spectrum of the rotovibrational band {ital v}=0{r_arrow}2 of parahydrogen has been observed in the condensed phases down to {ital T}=2 K. In the solid, phonon and roton sidebands exhibit peaks corresponding to those observed in the fundamental. Contributions arising from the reorientation of ortho-H{sub 2} impurities have been detected. The {ital Q}{sub 1}(0)+{ital S}{sub 1}(0) band has been resolved into an asymmetric doublet, and the origin of this latter is discussed. In the liquid phase the observed line shapes include strong translational contributions, and are accounted for by assuming that at short times the excited molecule is encapsulated in the cage of nearest neighbors.
Coal exploitation inevitably damages the natural ecological environment through large scale underground exploitation which exhausts the surrounding areas and is the cause of surface subsidence and cracks. These types of damage seriously lower the underground water table. Deterioration of the environment has certainly an impact on and limits growth of vegetation, which is a very important indicator of a healthy ecological system. Dynamically monitoring vegetation growth under coal exploitation stress by remote sensing technology provides advantages such as large scale coverage, high accuracy and abundant information. A scatter plot was built by a TM (Thematic Mapper) infrared and red bands. A detailed analysis of the distributional characteristics of vegetation pixels has been carried out. ...
We fabricate a low noise erbium-doped fiber ring laser that can be continuously tuned over 102nm by insertion of the fiber Fabry-Perot tunable filter (FFP-TF) in the ring cavity with a novel cavity structure and the optimal gain medium length. As an application of this fiber ring laser, we performed the absorption spectroscopy of acetylene (13C2H2) and hydrogen cyanide (H13C14N) and measure the absorption spectra of more than 50 transition lines of these gases with an excellent signal to noise ratio (SNR). The pressure broadening coefficients of four acetylene transition lines are obtained using this fiber ring laser and an external cavity laser diode.
A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.
Two analytical methods were proposed in this research, coupled electro-thermal finite element (FE) analysis and thermal-mechanical FE analysis, to analyze the mechanical behavior of bonding wire of power module under cyclic power loads, and the International Electrotechnical Commission standard is adopted in conducting a power cycling test. The exterior temperature distribution was measured by an infrared thermometer. Moreover, the junction temperature is calculated from the given thermal impedance of the semiconductor chip, chip power loss, and case temperature. Subsequently, the simulated temperature distribution via electro-thermal FE analysis is compared with experimental results to validate the methodology used in the aforementioned analysis. The analysis shows compressive stress at t...
Power loadings experienced by tokamak plasma-facing components during normal operation and during off-normal events are discussed. A model for power and particle flow in the tokamak boundary layer is presented and model predictions are compared to infrared measurements of component heating. The inclusion of the full three-dimensional geometry of the components and of the magnetic flux surface is very important in the modeling. Experimental measurements show that misalignment of component armour tile surfaces by only a millimeter can lead to significant localized heating. An application to the design of plasma-facing components for future machines is presented. Finally, thermal loads expected during tokamak disruptions are discussed. The primary problems are surface melting and vaporization due to localized intense heating during the disruption thermal quench and volumetric heating of the component armour and structure due to localised impact of runaway electrons. ...
In this study, wood samples were exposed to light irradiations (direct sunlight, xenon lamp, mercury vapour lamp) and thermal treatments were carried out in dry- and in humid conditions at 90degreeC. One part of the samples was covered by an aluminium plate during light irradiation. The samples under the aluminium plate also suffered considerable chemical changes, monitored by infrared technique and colour measurement. The sunlight produced greater colour change under the aluminium plate than the artificial light sources. During light irradiation, the carbonyl band having two maximum at 1700 and 1746cm-1 increased and the peak of the aromatic skeletal vibration arising from lignin (1510cm-1) decreased together with the guaiacyl vibrations at 1275cm-1. There was absorption decrease at 1174c...
Abstract Thermomechanical behavior of membranes based on blends of poly(vinyl alcohol) (PVA) with different weight percentage (wt %) of glycerol has been studied. Solid-state PVA/Glycerol polymer membranes were prepared by a solution casting method. The films were studied for thermal characteristics by differential scanning calorimetry (DSC) and thermogravimetric analysis and for the mechanical properties including hardness and modulus by nanoindentation method. The dispersion of glycerol within the polymer matrix was examined using scanning electron microscopy. Fourier transform infrared spectroscopy was used to confirm the formation of hydrogen bonding between the plasticizer and PVA in their blends and also to provide information on compatibility and physical interactions between the gl...
The synthesis of 3-O-sulphamoyl derivatives of 1,2:5,6-di-O-isopropylidene-#alpha#-D-glucofuranose, 1,2-O-isopropylidene-#alpha#-D-glucofuranose, and 5,6-di-O-acetyl-1,2-O-isopropylidene-#alpha#-D-glucofuranose is described. A study of the reactions of carbohydrate chlorosulphates with azide has demonstrated the relative case with which certain chlorosulphonyloxy groups may be converted into azidosulphates. These azidosulphates could have potential synthetic value if a facile method for their conversion into sulphamoyl (aminosulphate) derivatives were available, since some sulphamoyl carbohydrates have been shown to possess antibiotic and antitrypanosomal activity. This report deals with the application of sodium borohydride and platinum oxide-hydrogen to the reduction of some 3-O-azidosulphate glucofuranose derivatives. "1H-n.m.r. spectra and infrared spectra were used.
We synthesized Fe3O4Gg nanocomposites through a combination of solvothermal, hydrothermal, and chemical redox reactions. Characterization of the resulting samples by X-ray diffraction, Fourier-transform infrared spectroscopy, field-emission scanning and transmission electron microscopy, and magnetic measurement is reported. Compared to Fe3O4g nanocomposites, the Fe3O4Gg nanocomposites showed enhanced antibacterial activity. The Fe3O4Gg nanocomposites were able to almost entirely prevent growth of Escherichia coli when the concentration of Ag nanoparticles was 10mg/mL. Antibacterial activity of the Fe3O4Gg nanocomposites was maintained for more than 40h at 37^oC. The intermediate carbon layer not only protects magnetic core, but also improves the dispersion and antibacterial activity of the...
The direct addition of nickel powder to the reaction mixtures of 1,3-dialkyl-4,5-dioxoimidazolidine-2-thione (1) with the thionation Lawesson reagent produces [Ni{sup II}(R{sub 2}timdt{sup -}){sub 2}] (R{sub 2}timdt = 1,3-dialkylmidazolidine-2,4,5-trithione). These complexes belong to a new class of nickel-dithiolenes, showing remarkably high absorption ({epsilon} {approx} 80 000 dm{sup 3} mol{sup -1} cm{sup -1}, {lambda} {approx} 1000 nm) in the near-infrared region (near-IR), accompanied by high photochemical stability that makes these complexes promising near-IR dyes.
Quantitative determination of Broensted acid site concentrations in calcined H-mordenite and H-ZSM-5 by means of conductometric titration and infrared spectroscopy reveals that the concentration of Broensted acid sites present is lower than would be expected on the basis of the aluminum content. This discrepancy is attributed to dealumination and dehydroxylation processes occurring during calcination. A model is proposed according to which the degree of these processes strongly depends on the concentration of vicinal aluminum T sites in the zeolite: Broensted acid sites associated with these T sites are lost, and the remaining Broensted acidity is related to the concentration of the (remaining) isolated aluminum T sites. This model quantitatively correlates the experimentally determined concentration of Broensted acid sites with the concentration of isolated aluminum T sites. 33 refs., 4 figs., 2 tabs.
Medicinal plants i.e. dried seeds of myristica argentea, myristica fragrans, coriandrum sativum and foeniculum vulgare were stored for 0 and 6 months, with and without gamma irradiation at 5 kGy. No detectable changes were seen in infrared and UV spectra, GLC chromatograms and refraction indices of steam distilled, essential oils from the irradiated medicinal plants. The same results were also obtained from irradiated samples stored for 6 months at ambient conditions. Storage for 6 months caused significant changes in the gas liquid chromatograms and UV spectra of all samples compared to non-stored samples. The moisture content of all samples packed in polyethylene bags seems to be constant after 6 months of storage. No measurable changes were found in the amount of essential oil content caused by irradiation.
A number of materials of composition YSr{sub 2}Cu{sub 3-x}MxO{sub 7{+-}y} with M = Ti, Fe, Co, Al, Ga and Pb were prepared by solid state reactions. They belong to the tetragonal P4/mmm space group and their unit cell parameters were determined and refined from X-ray powder data. The infrared spectra of the compounds were also recorded and are briefly discussed on the basis of their structural characteristics and by comparison with those of related materials. (orig.) 23 refs.
We present physical properties of two submillimeter selected gravitationally lensed sources, identified in the Herschel Astrophysical Terahertz Large Area Survey. These submillimeter galaxies (SMGs) have flux densities > 100 mJy at 500 um, but are not visible in existing optical imaging. We fit light profiles to each component of the lensing systems in Spitzer IRAC 3.6 and 4.5 um data and successfully disentangle the foreground lens from the background source in each case, providing important constraints on the spectral energy distributions (SEDs) of the background SMG at rest-frame optical-near-infrared wavelengths. The SED fits show that these two SMGs have high dust obscuration with Av ~4 to 5 and star formation rates of ~100 M_sun/yr. They have low gas fractions and low dynamical masses compared to 850 um selected galaxies.
A widely used veterinary antibiotic, tetracycline (TC), has been incorporated in Langmuir-Blodgett (LB) films of dipalmitoylphosphatidic acid (DPPA) by means of two different procedures: co-transfer and incubation in solution. The resulting structures were characterized by means of contact angle and ellipsometric measurements. The presence of the antibiotic in the phospholipid film was evidenced by means of UV-Vis electronic absorption and infrared vibrational spectroscopy. The two sets of measurements unambiguously indicated the presence of the drug in the LB layer films obtained with both methods, although incubation led to a smaller content of immobilized tetracycline. In both cases, the drug was found to reside in the hydrophilic portion of the layers due to specific interactions of the dimethylamino group of the molecule with the polar head groups of the phospholipid.
By methods of vibrational (infrared, Raman) and PMR spectroscopy, crystallohydrate forms of monosubstituted uranyl orthophosphate have been examined. The vibrational frequencies of the groupings from the compounds were identified. The existence of non-equivalent H_2PO_4"--groups in the substances under investigation was ascertained. It has been suggested that one of them is a bridged group, and the other is the end group. A fragment of the VO_2(H_2PO_4)_2 hydrate structure is given, its main constituents being uranylphosphate chains. The analysis of water vibrations assumes coordination of one mole of H_2O in VO_2(H_2PO_4)_2:3H_2O to uranium, while two other molecules are only hydrogen-bonded with phosphate anions. Absorption within the region of 2100-2550 cm"-"1 is assigned to vibrations of O...H...O groupings.
Soluble starch?based biodegradable and microporous microspheres (SDM-Ms) were prepared by emulsion chemical cross-linking technique using trisodium trimetaphosphate (TSTP) as the cross-linker. The resultant amorphous SDM-Ms were excellently identified by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). The internal rupture and surface-controlled erosion were the predominant degradation mechanisms for SDM-Ms. The obtained SDM-Ms were applied to adsorb coix seed oil (CSO) by immersing method. The adsorption capacity of CSO within SDM-Ms was determined, namely 0.5238?g/g, and the thermal stability was shown higher than that of the free CSO. A burst release appeared in the second hour, followed by controlled release. Diffusion, d...
This paper describes in an apparatus for absorbing a beam of concentrated solar energy and which includes a cavity receiver with an inlet for transmission thereinto of solar radiation, a protective apertured shield means about the inlet. It comprises: rigid support means fixed to the periphery of the inlet and projecting radially inwardly therefrom to define a generally central aperture area through which the solar radiation can pass into the cavity receiver; and non-structural blanket means spread over the rigid support means between the periphery of the inlet and the aperture area, the material having a high temperature capability and providing for infra-red radiation insulation, while remaining relatively cool when subjected to solar radiation.
To elucidate biosorption mechanism and removal efficiency of plant residues as a biosorbent to abate polycyclic aromatic hydrocarbons (PAHs) in wastewater, sorption of PAHs onto wood chips (WC), ryegrass roots (RR), orange peels (OP), bamboo leaves (BL), and pine needles (PN) were investigated. The structural characterization of the biosorbents was analyzed by elemental composition, BET-N2 surface area, and Fourier transform infrared spectroscopy. PAHs sorption to the selected biosorbents were compared and correlated with their structures. Biosorption isotherms fit well with Freundlich equation and the mechanism was dominated by partition process. The magnitude of phenanthrene partition coefficients (Kd) followed the order of PN>BL>OP>RR>WC, ranged from 2484+/-24.24 to 5306+/-92.49L/kg. Ex...
A process is described for maintaining the proportions of each coal in a coal blend at a desired level. The process involves (1) making a spectral analysis, preferably by infrared spectrometry, of at least one sample of the coal blend, the sample having known desired proportions of each coal, (2) making a spectral analysis of the coal blend sample of unknown proportions of each coal, (3) comparing the spectral analyses of steps (1) and (2), and (4) upon noting a significant difference between the spectral analyses of steps (1) and (2), making adjustments to achieve a final coal blend having proportions of each coal closer to those of the blend of known desired proportions of each coal. The relationship of the aromatic to aliphatic groupings is preferably determined by spectral analysis of each coal sample. This process is particularly useful on-line in the production of blast furnace coke of high strength and high stability.
The present study is focused on preparation of nano composite materials and the effect of citric acid on their different properties. The formation of nano HA and its interaction with chitosan (C), gelatin (G) polymers and citric acid (CA) materials were studied. The Fourier Transformed Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), transmission electron microscope (TEM), and scanning electron microscope (SEM) were used to characterize these composite materials. The compressive strength (CS) was also measured to know the reinforcement of the prepared composites. The results show that carboxylic and amino groups play crucial role for HA formation on chitosan-gelatin polymeric matrix in the presence of citric acid (CA). The formation of nano HA part...
A novel composite charged mosaic membrane (CCMM) was prepared via interfacial polymerization (IP) of polyamine [poly(epichlorohydrin amine)] and trimesoyl chloride (TMC) on the polyethersulfone (PES) support. Fourier transform infrared spectroscopy (FT-IR), environmental scanning electron microscopy (ESEM), atomic force microscopy (AFM) and water contact angle analysis were applied to characterize the resulted CCMM. The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine. ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane. The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network. Several factors affecting the IP reaction and the performan...
In order to investigate the antioxidant properties of the polysaccharides from the brown alga Sargassum fusiforme, the crude polysaccharides from S. fusiforme (SFPS) were extracted in hot water, and the lipid peroxidation inhibition assay exhibited that SFPS possessed a potential antioxidant activity. Hence, two purely polymeric fractions, SFPS-1 and SFPS-2 were isolated by the column of DEAE (2-diethylaminoethanol)-Sepharose Fast Flow, with their molecular weights of 51.4 and 30.3 kDa determined by high performance gel permeation chromatography (HPGPC). They were preliminarily characterized using chemical analysis in combination of infrared (IR) and nuclear magnetic resonance (NMR) spectroscopies and found to contain large amounts of uronic acids and ?-glycosidical linkages. The antioxida...
This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained ...
This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained ...
Abstract Poly(butylene terephthalate) (PBT) composites containing multiwalled carbon nanotubes (MWCNTs) were prepared using a melt-blending process and used to examine the effects on the composite structure and properties of replacing PBT with acrylic acid-grafted PBT (PBT-g-AA). PBT-g-AA and multihydroxyl-functionalized MWCNTs (MWCNTs-OH) were used to improve the compatibility and dispersibility of the MWCNTs within the PBT matrix. The composites were characterized morphologically using transmission electron microscopy, and chemically using Fourier transform infrared, solid-state 13C NMR and UV-visible absorption spectroscopy. The antibacterial and electrical conductivity properties of the composites were also evaluated. MWCNTs or MWCNTs-OH enhanced the antibacterial activity and electric...
Thermoluminescence of inorganic dust extract from herbs and spices has been demonstrated to be a useful method to discriminate irradiated food products as well as to estimate the total dose exposure. The time evolution of infrared stimulated luminescence has been systematically investigated in potassium feldspar and albite minerals subjected to different doses of gamma irradiation (ranging from 0 to 8 kGy). Experimental results reveal a 300-600 nm signal which is greatly intensified for irradiated samples, following the same irradiation dose dependence observed in thermoluminescence. The luminescence intensity disappears after few seconds of illumination, following a time evolution which is proportional to (1 + Bt){sup -P}. The influence of both B and P factors upon the irradiation dose has been systematically analysed. (author)
Thermoluminescence of inorganic dust extract from herbs and spices has been demonstrated to be a useful method to discriminate irradiated food products as well as to estimate the total dose exposure. The time evolution of infrared stimulated luminescence has been systematically investigated in potassium feldspar and albite minerals subjected to different doses of gamma irradiation (ranging from 0 to 8 kGy). Experimental results reveal a 300-600 nm signal which is greatly intensified for irradiated samples, following the same irradiation dose dependence observed in thermoluminescence. The luminescence intensity disappears after few seconds of illumination, following a time evolution which is proportional to (1 + Bt)"-"P. The influence of both B and P factors upon the irradiation dose has been systematically analysed. (author)
Chemical modification of poly(?-caprolactone) PCL by oxidation with potassium permanganate in solution was investigated. According to the data obtained from Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance 1H NMR, after the oxidation reactions the PCL chains exhibited new functional groups (vinyl and hydroxyl) and possible intermolecular recombination, producing an oxidized-polycaprolactone (PCL-OX). Solution viscometry indicated that degradation also occurred during the oxidation reactions (30% drop in viscosity average molecular weight was detected). Differential scanning calorimetry (DSC) also indicated that PCL was chemically modified and degraded. The successive self-nucleation/annealing (SSA) treatment confirmed that a reduction (or interruption) in line...
Although infrared-stimulated luminescence (IRSL) signals in feldspars can be bleached rapidly by sunlight, there could still be a small amount of IRSL signal remaining in sediment grains if they have experienced only relatively short sunlight exposure before deposition. This remaining signal results in a ''remnant dose'' stored in the grain and is important for young samples but negligible for old samples. Several methods have been introduced to detect insufficient bleaching, and some of them can provide information on the extent of the bleaching. Others can only distinguish between samples bleached for a very long time and for a short time. Empirical methods are introduced to evaluate the possible values of equivalent dose accumulated since the grains were deposited. These methods involve the analysis of the equivalent doses and the natural IRSL signals obtained using single-disc dose determination methods. (author).
Raman and infrared spectroscopy of para-H{sub 2} to pressures in excess of 200GPa and to 8K using new ultrapure synthetic diamond anvils reveals numerous new vibrational excitations in the three high-pressure phases. Highly resolved Raman-active librons indicate differences in orientational ordering between phasesII and III, including evidence for changes within phaseII. The librons in phaseIII are strongly pressure dependent and reflect a substantial increase in ordering with pressure. Multiple vibrons in all three phases (I, II, and III) are observed. The results place new bounds on predicted crystal structures and dynamics of the dense molecular solid. {copyright} {ital 1997} {ital The American Physical Society}
This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The authors investigated the evolution and radiation characteristics of individual neutron stars and stellar systems. The work concentrated on phenomena where new techniques and observations are dramatically enlarging the understanding of stellar phenomena. Part of this project was a study of x-ray and gamma-ray emission from neutron stars and other compact objects. This effort included calculating the thermal x-ray emission from young neutron stars, deriving the radio and gamma-ray emission from active pulsars and modeling intense gamma-ray bursts in distant galaxies. They also measured periodic optical and infrared fluctuations from rotating neutron stars and search for high-energy TeV gamma rays from discrete celestial sources.
Abstract Aims: To develop a new nano composite of multi walled carbon nanotubes (MWNTs) with enhanced antimicrobial activity. Methods and Results: A novel antimicrobial nanocomposite [MWNT epilson polylysine (MEPs)] was synthesized via covalent attachment of epilson polylysine on MWNTs with hexamethylene diisocyanate (HDI) as the coupling agent. UV visible spectra and Fourier transform infrared spectra (FT IR) investigations indicate that MEPs is stable, with epilson polylysine leaching effectively eliminated. When compared to MWNTs, the new nano composite MEPs exhibits enhanced antimicrobial activities. In 20 mg l 1 suspensions, significant increases of 72 1, 64 5 and 69% against Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aureus can be observed. The deposited film of MEPs...
Polypyrrole (PPy) was prepared from different mixed-surfactant solutions with ammonium persulfate as an oxidant. Three types of combinations were selected, including cationic/anionic, cationic/nonionic, and anionic/nonionic mixed-surfactant solutions. The surfactants used in the experiments included cetyltrimethylammonium bromide (cationic surfactant), sodium dodecyl sulfate (anionic surfactant), sodium dodecyl sulfonic acid salt (anionic surfactant), poly(vinyl pyrrolidone) (nonionic surfactant), and poly(ethylene glycol) (nonionic surfactant). The morphology, structure, and conductivity of the resulting PPy were investigated in detail with scanning electron microscopy, Fourier transform infrared spectra, and the typical four-probe method, respectively. The results showed that the interac...
Commercially available organoclay (Closite 30B) was modified by using 3-aminopropyltriethoxysilane (APS) via a silylation reaction. Sodium clay (Closite Na) was treated by APS directly as a control. Such modified clays were further melt-compounded with polybutylene terephthalate (PBT). The morphology and properties of the modified organoclays were characterized with X-ray diffraction (XRD), transmission electrical microscopy (TEM), Infra-red spectroscopy, contact angle measurement, and thermogravimetric analysis (TGA). The effects of modified clays on the crystallization behavior of PBT were characterized by differential scanning calorimetry. The basal spacing of Closite Na was enlarged from 1.01 to 1.41 nm after APS treatment, indicating that the APS was intercalated into the clay interga...
Side-chain liquid crystalline ionomer (SLCI) containing sulfonic acid groups with a polymethylhydrosiloxane main-chain was used in the blends of polypropylene (PP) and polybutylene terephthalate (PBT) as a compatibilizer. The crystalline behavior, morphological, and mechanical properties of the blends were investigated in detail by differential scanning calorimetry (DSC), polarizing optical microscope (POM), Fourier transforms infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Revealed by the shift of Tm in DSC thermogram and the shift of the absorbed peak in FTIR spectra, specific interaction led to stronger interfacial adhesion between these phases, which resulted in much finer dispersion of the minor PBT phase in PP matrix. The SLCI containing sulfonate acid groups ac...
By applying lock-in thermography imaging, light-beam-induced current imaging, electron-beam-induced current imaging at different stages of sample preparation, and infrared light microscopy in transmission mode, the physical nature of the dominant material-induced shunts in multicrystalline solar cells made from p-type silicon material has been investigated. It turns out that these shunts are due to silicon carbide (SiC) filaments, which grow preferentially in grain boundaries and cross the whole cell. These filaments are highly n-type doped, like the emitter layer on the surface of the cells. They are electrically connected both with the emitter and with the back contact, thereby producing internal shunts in the solar cell.
By applying lock-in thermography imaging, light-beam-induced current imaging, electron-beam-induced current imaging at different stages of sample preparation, and infrared light microscopy in transmission mode, the physical nature of the dominant material-induced shunts in multicrystalline solar cells made from p-type silicon material has been investigated. It turns out that these shunts are due to silicon carbide (SiC) filaments, which grow preferentially in grain boundaries and cross the whole cell. These filaments are highly n-type doped, like the emitter layer on the surface of the cells. They are electrically connected both with the emitter and with the back contact, thereby producing internal shunts in the solar cell.
By applying lock-in thermography imaging, light-beam-induced current imaging, electron-beam-induced current imaging at different stages of sample preparation, and infrared light microscopy in transmission mode, the physical nature of the dominant material-induced shunts in multicrystalline solar cells made from p-type silicon material has been investigated. It turns out that these shunts are due to silicon carbide (SiC) filaments, which grow preferentially in grain boundaries and cross the whole cell. These filaments are highly n-type doped, like the emitter layer on the surface of the cells. They are electrically connected both with the emitter and with the back contact, thereby producing internal shunts in the solar cell.
Oxovanadium(IV) complexes with tridentate dibasic ONO donor schiff bases derived from salicylaldehyde, 5-chlorosalicylaldehyde, 3,5-dichlorosalicylaldehyde, 5-bromosalicylaldehyde, 3-methoxysalicylaldehyde, 2-hydroxynaphthaldehyde and 2-amino-1-propanol have been prepared and characterised by elemental analysis, infrared, electronic and ESR spectra and magnetic susceptibility measurements from 83 to 297 deg K. On the basis of these studies, presence of triplet state (S=1) and a dimeric structure with singlet ground state (S=0) have been suggested. The V=0 stretching frequencies of the complexes occur around 980 cm"-"1. (M.G.B.).
Luminescence properties of SiAlON phosphors codoped with Ca and Yb were investigated by changing the host lattice composition. These modifications of the host lattice were obtained by replacing Si-N bonds by Al-N and Al-O bonds. Their photoluminescence (PL) and cathodoluminescence (CL) properties were measured and compared with each other. PL allows observing the influence of the host lattice modifications by measuring wider areas. CL can excite all luminescent centers, in particular the UV luminescence centers, even if their amount is small. Thus, two additional peaks in the ultraviolet and infrared regions were observed in CL, which is not observed by PL. This work suggests that the combination of PL and CL gives more understanding about the luminescence of SiAlON phosphors, in particular the role of the secondary phases on their properties.
The luminescence techniques have evolved over the last 40 years to a powerful dating instrument in archaeology and geoscience. Depending on how the luminescence is stimulated, one distinguishes the phenomena of thermoluminescence (TL), optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL). Each of these phenomena has its specific potential for dating various archaeological materals in the time range from medieval back to palaeolithic periods, or, speaking in geological terms, for dating of Holocene and late Pleistocene objects. The OSL and IRSL techniques are sometimes treated together as 'optical dating'. The luminescence techniques differ from other major dating techniques, such as 14C, essentially by their applicability to inorganic materials, their wide age-range from about 100 years to more than 100,000 years and the kind of datable events which are the last exposure to heat or to light. (author). 10 refs., 3 figs.
The cephalosporin class antibacterial agent, cefazolin, was intercalated into layered double hydroxides (LDHs) in order to improve the drug efficiency as well as to achieve the controlled release property. Cefazolin molecules were incorporated into LDH through conventional ion exchange reaction. X-ray diffraction pattern analyses confirmed that cefazolin molecules were intercalated between the interlayer spaces of LDH. Fourier-transform infrared spectra and high performance liquid chromatographs clearly showed that the drug molecules were stabilized in LDH lattice through electrostatic interaction and released without any changes in their chemical integrity. Antibacterial activity of the cefazolin-LDH nanohybrid was also examined by an in vitro test, such as the minimal inhibitory concentr...
An 80-K Joule-Thomson (J-T) cooling system designed for the Probe Infrared Laser Spectrometer (PIRLS) proposed for the Huygens Titan Probe of the Cassini Saturn orbiter mission is presented. The cryogenic cooling requirements of the PIRLS instrument are listed, and the cooler system design including details of a J-T cryostat, cold head, and dewar design is described along with the results of a thermal modeling effort and lab cooler performance testing. It is shown that by using active feedback temperature control of the cold head in combination with the self-regulating action of the J-T cryostat, a temperature stability of less than 0.1 mK/min is achieved by the cooler weighting 1.8 kg.
The LCLS, a Free-Electron Laser (FEL) designed for operation at a first harmonic energy of 300 eV ({lambda} {congruent} 40{Angstrom}) in the Self-Amplified Spontaneous Emission (SASE) regime, will utilize electron bunches compressed down to durations of <0.5ps, or lengths of <150 {mu}. It is natural to inquire whether coherent radiation of this (and longer) wavelength will constitute a significant component of the total coherent output of the FEL. In this paper a determination of a simple upper bound on the IR that can be generated by the compressed bunches is outlines. Under the assumed operating parameters of the LCLS undulator, it is shown that that IR component of the coherent output should be strongly dominated by the x-ray component.
The enzyme TEM1-b-lactamase has been used as a model to study the impact of different cultivation and induction regimes on the structure of cytosolic inclusion bodies (IBs). The protein has been heterologously expressed in Escherichia coli in fed-batch cultivations at different temperatures (30, 37, and 40degreeC) as well as induction regimes that guaranteed distinct product formation rates and ratios of soluble to aggregated protein. Additionally, shake flask cultivations at 20, 30, and 37degreeC were performed. IBs were sampled during the whole bioprocess and structural analysis was performed by attenuated total reflectance Fourier transform infrared (ATR-FT-IR) spectroscopy. This work clearly demonstrates that the tested production regimes and rates had no impact on the IB structure, wh...
Abstract Background and Purpose: During laser lithotripsy, working instruments are often in close proximity to the distal fiber tip and may be damaged accidentally or even intentionally. The aim of this study was to compare the amount of damage to a standard guidewire and the nitinol wires of endourologic retrieval baskets that were affected by three different clinically available laser systems. Materials and Methods: The impact of pulsed laser irradiation on a standard hydrophilic guidewire and a retrieval basket were investigated. One infrared (IR) laser system (holmium:yttrium-aluminum-garnet [Ho:YAG]: ????=???2100???nm) and two laser systems emitting light in the visible (VIS) spectral range (frequency-doubled double-pulse neodymium:YAG [FREDDY]: ????=???532???nm/1064???nm and flashl...
Compton backscattering of laser photons near the interaction point of an e{sup +}e{sup -} or e{sup -}e{sup -} collider can be used to produce a {gamma}-{gamma} or {gamma}-e{sup -} collider. This paper describes the laser requirements, including pulse duration, intensity, energy, and wavelength, for such a collider. For most of the proposed, next generation, e{sup +}e{sup -} colliders, the laser wavelength should be in the near-infrared, with a pulse duration of 1 ps or less and an energy of similar 1 J per pulse. Current chirped pulse amplification laser systems in solid state lasing materials are well suited to meet these requirements. These systems are described. ((orig.)).
Thermophotovoltaic (TPV) converters were developed and tested at the heat source operating temperature of 1,700 K. Rare-earth-doped yttrium aluminum garnet (YAG) and lutetium yttrium aluminum garnet (Lu, YAG) selective emitters, as well as a blackbody emitter, were coupled to InGaAs/InP photovoltaic (PV) cells and bandpass/infrared (IR) reflector filters. YAG-based selective emitters were adopted with Ho, Tm, and Er. PV cells had bandgaps of 0.51, 0.57, and 0.69 eV. Converter energy conversion efficiencies approaching 30%, as well as electrical output power densities near 2 W/cm{sup 2} were demonstrated. The overall performance of the filtered blackbody-based converter was found to be superior to the selective emitter YAG-based converters. The details of the measurements performed on the above converters and their individual components are presented.
In the food, chemical and safety industry there is a demand for gas detectors for process control applications, like quality control of food or leakage control in chemical plants. Gas sensor array systems have the potential to be used in this areas, with the advantage of being also affordable systems compared to other systems like gaschromatographs (GC) or infrared detectors (NIR, FTIR). One of the main drawbacks of the gas sensors is their response to non interesting ambient factors like temperature, pressure and humidity. Metal oxide sensors (MOS) have a low ambient temperature and pressure dependency. Some of them (SnO + dopands) have some sensitivity to humidity. In many cases the response of the sensors is often non-linear, which implies a concentration dependant pattern of the samples. (orig.)
A new furnace for neutron diffraction experiments is capable of heating and cooling a sample very rapidly. The rapid heating is done by two circular infrared lamps placed over and under a sample, whose radiation is roughly focused on the sample by a reflector. The rapid cooling is done by high-pressure gas blows against the sample from two circular nozzles which are also placed over and under the sample. This system enables us to obtain the heating rate of over 1000"0C/min and cooling rate of -500"0C/min for an alloy of 10 mm diameter and 30 mm length. The performance is sufficient to carry out some kinetics measurements in real-time neutron diffraction by the use of a position-sensitive detector. This kind of experiment is demonstrated by the observation of the relaxation process of order--disorder transitions in CuZn and Ni_3Mn alloys.
Aim: This study was performed: 1) to assess the relationship between blood flow velocity in the internal carotid artery (CBFICA) and pial artery pulsation (cc-TQ) and 2) to evaluate flow-induced changes in pial artery compliance. Methods: Experiments were performed on 10 crossbred male rabbits. Heart rate (HR), blood pressure (BP), left ventricle ejection fraction (LVEF), CBFICA, the systolic-diastolic blood volume fraction in the brain circulation (CBFSDF) and cc-TQ were recorded after glucagon and acetazolamide administration. cc-TQ was measured with near-infrared transillumination back scattering sounding (NIR-T/BSS), LVEF and CBFSDF with gated scintigraphy and BP and CBFICA with electromagnetic pressure and flow transducers, respectively. Doses of drugs were chosen to exert a haemodyna...
A beam of 3.6 MeV electrons has been used to study the generation of radiation in far infra-red (FIR) by the Smith-Purcell mechanism. The dependence of wavelength on angle of emission, over angles from 56 deg to 150 deg and wavelengths from 350 #mu#m to 1860 #mu#m, is in excellent agreement with the Smith-Purcell dispersion relation. Comparison of the yield with that from a 5000 K source suggests that the spontaneous Smith-Purcell effect offers an easily tunable alternative to the synchrotron as a coherent FIR source, and could form the basis of a cheap, compact Free Electron Laser (FEL). (author) 6 refs.; 5 figs.
The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...
Chitosan was acetylated during 2, 5 and 10 h and physical gels were obtained at different polymer concentrations in N,N-dimethylacetamide containing 5% of LiCl. Acetylation was confirmed by infrared spectroscopy and "1"3C NMR, and degrees of acetylation in the range of 0.82-0.91 were determined by NMR. The O-acetylation degree (0.12-0.15) was exclusively determined by a volumetric method. Rheological studies showed that the storage modulus values were smaller for the more acetylated samples and increased with the temperature and the polymer concentration. All the gels presented storage modulus superior to loss modulus, evidencing more elastic than viscous characteristics. The results obtained in this work suggest a gelation process based on a balance between O and N-acetylation and intermolecular bonds. (author)
Successful electron capture dissociation (ECD) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) applications to peptide and protein structural analysis have been enabled by constant progress in implementation of improved electron injection techniques. The rate of ECD product ion formation has been increased to match the liquid chromatography and capillary electrophoresis timescales, and ECD has been combined with infrared multiphoton dissociation in a single experimental configuration to provide simultaneous irradiation, fast switching between the two techniques, and good spatial overlap between ion, photon, and electron beams. Here we begin by describing advantages and disadvantages of the various existing electron injection techniques for ECD in FT-ICR MS. We next ...
This research investigated the influence of stearic acid on the injection molding of alumina, by varying the concentration of stearic acid. The interaction between stearic acid and alumina was identified using transmission infrared spectroscopy, indicating stearic acid preferentially adsorbed onto the alumina powder surface. In addition to slightly modifying the intrinsic binder viscosity, stearic acid adsorbed onto the powder surface changed the flow behavior of the mixtures from dilatant flow to pseudoplastic flow at low temperatures. As a result, inhomogeneous distribution of binder in the injection-molded parts was minimized with increased stearic acid concentration. However, the possibility of forming bubbles in the mixtures arising from vaporization of stearic acid was enhanced. Additionally, the binder burnout temperature range was broadened with the increase of stearic acid concentration.
Radiation modification on liquid retention properties of native cassava starch, gelatinized at 85"0C, by graft copolymerization with acrylonitrile was carried out by mutual irradiation to #gamma#-rays. A thin aluminium foil was used to cover the inner wall of the reaction vessel so that the extent of homo polymer could be reduced to be less than 1.6% with a distilled water retention value of 665 g/g of the dry weight of the saponified grafted product. Confirmations of graft copolymerization and saponification reactions were made by the infrared spectrophotometric technique. The combined effect of radiation parameters in terms of an irradiation time and a dose rate to the same total dose on the extent of grafting reaction expressed in terms of grafting parameters which directly influenced liquid retention values was evaluated in conjunction with statistical analysis.
Using the infrared spectroscopy method, we have studied the effect of thermal dehydration (under vacuum and in air) and treatment with water vapor on the acid centers of very high silicon zeolites of the ZSM type. We have shown that dehydration under vacuum and in air completely and irreversibly removes the OH groups at 1120/sup 0/K, while treatment with water vapor removes these groups at 770/sup 0/K. The Lewis acid centers of dehydrated zeolites (represented by two types of centers) are more heat-stable than the Bronsted acid centers, but the vapor treatment at 1020/sup 0/K leads to the disappearance of the Lewis acid centers. In this work, we discuss the reasons for destruction of the acid centers of the zeolites under different treatment conditions.
Irradiation processing of food in the prepackaged form may affect chemical and physical properties of the plastic packaging materials. The effect of #gamma#-irradiation doses (2.5-10.0 kGy) on polypropylene (PP)-based retortable food packaging materials, were investigated using Fourier transform infrared (FTIR) spectroscopic analysis, which revealed the changes happening to these materials after irradiation. The mechanical properties decreased with irradiation while oxygen transmission rate (OTR) was not affected significantly. Colour measurement indicated that Nylon 6 containing multilayer films became yellowish after irradiation. Thermal characterization revealed the changes in percentage crystallinity.
A high-average power (kW) infrared (IR) free-electron laser (FEL) is currently being commissioned for the Jefferson Laboratory FEL User Facility. The IR FEL is driven by a unique superconducting rf linac which is recirculated to recover electron beam power that is not radiated in the FEL. The design and installation of the vacuum system for the FEL involved particular attention to minimizing particulate contamination which could cause problems with the superconducting acceleration cavities and the high power FEL optics. Particulate contamination levels of all vacuum components were monitored during the cleaning process using laser scattering. Cleaning, transport, and installation procedures were developed to minimize the contamination of the complete system. We will summarize a data base we compiled of particulate contamination levels of the various components installed in the FEL vacuum system.
The construction and the development of a UV free electron laser have been started under the cooperation of Nihon U, KEK, PNC, ETL and Tohaku U. The project requires a 100MeV S-band electron linear accelerator to expand the oscillation of FEL using fundamental mode to the UV region. The injection system consists of a thermionic RF-gun with a LaB cathode and an {alpha} magnet for magnetic bunching. We are studying to reduce the back-bombardment electrons to realize the macropulse length of 20{mu}sec. Electron beams, up to the energy of 100MeV, are injected into the optical oscillators. Changing the accelerating energy and/or undulator parameters, this system will cover the range from infrared to ultraviolet for the applications in various fields.
Paper presents conceptual design of free electron laser (FEL) complex for industrial applications. The FEL complex consists of three. FEL oscillators with the optical output spanning the infrared (IR) and ultraviolet (UV) wave-lengths (#lambda# = 0.3...20 #mu#m) and with the average output power 10 - 20 kW. The driving beam for the FELs is produced by a superconducting accelerator. The electron beam is transported to the FELs via three beam lines (125 MeV and 2 x 250 MeV). Peculiar feature of the proposed complex is a high efficiency of the. FEL oscillators, up to 20 %. This becomes possible due to the use of quasi-continuous electron beam and the use of the time-dependent undulator tapering.
This work reports a systematic comparative study of the technological properties of natural lattices and rubbers extracted from Hancornia speciosa Gomes and Hevea brasiliensis [(Willd. ex Adr. de Juss.) Muell.-Arg.] (clone RRIM 600) trees from 11 collections in Brazil throughout 2004. Natural rubber latex particle sizes and distributions were quite similar with an average diameter around 1 mm. Molecular weight, Wallace plasticity, and Mooney viscosity values were approximately the same for both rubbers. Fourier transform infrared spectroscopy peaks characteristic of natural rubber were observed for both Hancornia and Hevea. The measured differences in technological properties included lower values for Hancornia dry rubber content, % ash, % nitrogen, and plasticity retention index but highe...
Coherent spontaneous radiation has now been observed in several FELs, and is a subject of great importance to the design of self-amplified spontaneous emission (SASE) devices. We report observations of coherent spontaneous radiation in both FIREFLY and the mid-infrared FEL at the Stanford Picosecond FEL Center. Coherent emission has been observed at wavelengths as short as 5 microns, and enhancement over incoherent levels by as much as a factor of 4x10"4 has been observed at longer wavelengths. The latter behavior was observed at 45 microns in FIREFLY with short bunches produced by off-peak acceleration and dispersive compression. We present temporal measurements of the highly bunched electron distributions responsible for the large enhancements, using both transition radiation and energy-phase techniques.
Coherent Smith-Purcell radiation, emitted from short-bunched electrons passing by a lamellar-type grating of aluminum, has been observed in the millimeter wave region. The energy of the electrons is either 42 MeV when they are accelerated by an L-band linear accelerator or 150 MeV accelerated by an S-band one. The intensity of the radiation is proportional to the square of the beam current. The radiation is linearly polarized, and the electric vector of the radiation is in the plane defined by the observing point and the beam trajectory. The intensity decreases with the beam height, i.e. the distance of the beam from the surface of the grating, in accordance with the modified Bessel function of zeroth order. copyright 1996 American Institute of Physics.
Protein hydrogels were prepared by substituting ovalbumin with different concentrations of ethyl vinyl sulfone (EVS) or acrylic acid (AA) and crosslinking with divinyl sulfone (DVS). Fourier transform-infrared (FT-IR) spectroscopic studies confirmed the addition of EVS, AA, and DVS onto the protein. Swelling was assessed as a function of pH in the range of 2.5 to 9.4 and ionic strength. The elastic modulus of the gels was determined in shear and compression. Stress relaxation was assessed in compression. The substituent highly affected swelling and modulus with both hydrogels displaying non-Gaussian behavior in the range of hydrogel environments studied. Acrylic acid substituted ovalbumin exhibited a decreasing modulus with increasing swelling behaving as a polyelectrolyte with low added s...
SBA-15 supported nano-scaled copper oxide was synthesized by impregnation method via ultrasonic-assisted route. The removal test from gas mixture containing 0.1?vol.% hydrogen sulfide was carried out over this material at atmospheric conditions. The effects of the chemical nature of copper oxide and the textural properties of the material on removal capacity were studied. The materials before and after the removal test were analyzed by nitrogen adsorption, X-ray diffraction, Transmission Electron Microscope, X-ray photoelectron Spectroscopy, Fourier Transform Infrared Spectrometer and Inductive Coupled Plasma. The results showed that copper species are located predominantly in mesopore channels, existing as copper oxide nanoparticles. Mesopores are active sites for removal reaction. The ou...
X-ray diffraction, infrared spectroscopy, thermal analysis, scanning electron microscopy, and particle size analysis were used to characterize the product of the thiosulfate process. It was found to consist of a mixture of a solid solution of calcium sulfate in calcium sulfite hemihydrate, calcium sulfate dihydrate, and calcium carbonate. Reactions taking place on heating the byproduct were identified in oxidizing and reducing atmospheres. Pure calcium sulfite hemihydrate as well as solid solutions of CaSO[sub 4] in CaSO[sub 3] [center dot] (1/2)H[sub 2]O with different sulfate concentrations were synthesized in the laboratory. Thermal analyses of pure solid solutions proved that the higher the sulfate content, the higher is the dehydration temperature. Accordingly, taking SO[sub 4][sup 2[minus
Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...
A multivariate bioprocess control approach, capable of tracking a pre-set process trajectory correlated to the biomass or product concentration in the bioprocess is described. The trajectory was either a latent variable derived from multivariate statistical process monitoring (MSPC) based on partial least squares (PLS) modeling, or the absolute value of the process variable. In the control algorithm the substrate feed pump rate was calculated from on-line analyzer data. The only parameters needed were the substrate feed concentration and the substrate yield of the growth-limiting substrate. On-line near-infrared spectroscopy data were used to demonstrate the performance of the control algorithm on an Escherichia coli fed-batch cultivation for tryptophan production. The controller showed good ability to track a defined biomass trajectory during varying process dynamics. The robustness of the control was high, despite significant external disturbances on the ...
Abstract Jicama (Pachyrhizus erosus L.) is a root-based legume that has been cultivated in Mexico for centuries. Pectic polysaccharide from de-starched jicama pomace was extracted using an autoclave-assisted process and physicochemically characterized. The extracted polysaccharide (1.0 g L-1) was used for the formation of polyelectrolyte complexes (PECs) with water-soluble chitosan (WSCh; 0.5, 1.0 and 2.0 g L-1). The extraction yield of jicama pectic polysaccharide was 22.8 wt% (dry basis) and infrared spectroscopic analysis showed that it was methoxylated to a small degree. Thermogravimetric analysis indicated that this biopolymer was very stable, its weight loss being 51.2% after heating at 479 C. Anion-exchange chromatography showed it to have a wide and heterogeneous charge density. Th...
Readout integrated circuits (ROICs) for focal plane arrays (FPAs) have become increasingly complex to meet the needs of modern infrared systems. BAE Systems has pioneered a number of advanced signal processing architectures for FPA ROICs. Demonstrated signal processing capabilities of BAE Systems FPAs include analog-to-digital conversion, offset subtraction, individual pixel automatic gain compensation, transient noise suppression, on-FPA defect deselection, reconfigurable pixels, spatial neural network processing and subframe noise averaging. BAE Systems FPA advanced signal processing is not just for demonstrations, but is used in many of their deliverable FPAs, improving real system performance.
Since 1979, scientists and engineers at the Los Alamos National Laboratory have designed, constructed, and operated a radio-frequency (RF) linac free-electron laser (FEL) at wavelengths from 9 to 45 /mu/m. Coupled with success of other research centers investigating wavelengths from the visible to far-infrared, Los Alamos is now proposing a vacuum-ultraviolet and soft x-ray (referred to henceforth as extreme ultraviolet, (XUV)) FEL oscillator/Self-Amplified Spontaneous Emission amplifier with beam energies ranging from 100 MeV to 1 GeV. This paper will focus on the first milestone of the proposed Los Alamos XUV project, i.e., a 250-MeV linac with approximately 50 mA of average current, producing photons with wavelengths below 1000 /angstrom/. 3 refs., 3 figs.
A novel liquid phase alkylation of aniline with methanol over Zn/Cu salts modified kaolin assisted with a pair of porous carbon electrode in slurry-bed reactor under constant current intensity, room temperature and atmospheric pressure was reported. The Zn/Cu salts modified kaolin catalysts were synthesized and characterized by infrared spectrometer (IR), powder X-ray diffraction (XRD) and scanning electron microscopy (SEM), which showed that the transition metals were completely supported on kaolins structure and formed a pored one. The effect parameters, such as initial pH, electrolysis time, metal ratio with kaolin and salts composition in this electrochemical catalytic system, were studied. The procedure was inspected by ultraviolet-visible spectrum (UV-vis), and the product distributi...
In this Ph.D. thesis a model for graphene in presence of quantized electromagnetic interactions is introduced. The zero and low temperature properties of the model are studied using rigorous renormalization group methods and lattice Ward identities. In particular, it is shown that, at all orders in renormalized perturbation theory, the Schwinger functions and the response functions decay with interaction dependent anomalous exponents. Regarding the 2-point Schwinger function, the wave function renormalization diverges in the infrared limit, while the effective Fermi velocity flows to the speed of light. Concerning the response functions, those associated to a Kekul\\'e distortion of the honeycomb lattice and to a charge density wave instability are enhanced by the electromagnetic electron-electron interactions (their scaling in real space is depressed), while the lowest order correction to the scaling exponent of the density-density response function is vanishing. ...
Dy doped #alpha#-SiAlON ceramics prepared by the hot-pressing method show a high optical transmittance value, >70%, in the infrared region of 1.5-4.5 #mu#m. First principles calculations have been carried out to reveal the underlying transparency mechanism. It is found that the valence shell of doped Dy atoms interacts strongly with the doping states of #alpha#-SiAlON, resulting in the increase in the optical gap from 0.4 to 1.1 eV, which suppresses the photoabsorption in the wavelength region longer than 1.0 #mu#m and leads to the good transparency property. The calculated optical transmission spectra are in good agreement with the corresponding experiments.
Large optical surveys provide an unprecedented census of galaxies in the local Universe, forming an invaluable framework into which more detailed studies of objects can be placed. But how useful are optical surveys for understanding the co-evolution of black holes and galaxies, given their limited wavelength coverage, selection criteria, and depth? In this conference paper I present work-in-progress comparing optical and mid-IR diagnostics of three "unusual" low redshift populations (luminous Seyferts, dusty Balmer-strong AGN, ULIRGs) with a set of ordinary star-forming galaxies from the SDSS. I address the questions: How well do the mid-infrared and optical diagnostics of star formation and AGN strength agree? To what extent do optical surveys allow us to include extreme, dusty, morphologically disturbed galaxies in our "complete" census of black hole-galaxy co-evolution?
Highly water-repellent surfaces have been prepared from arrayed nanowires of zinc oxide (ZnO) by a treatment with stearic acid. The layers are electrochemically deposited on a nanocrystalline seed layer from an oxygenated aqueous zinc chloride solution. An advancing contact angle (CA) as high as 176{sup 0} is obtained with a very small hysteresis {approx}1{sup 0}. These results, supplemented by infrared spectroscopy, show that the stearic acid forms a very well-packed self-assembled monolayer. The CA measurements show a very good stability of the treated surface even when exposed to harsh conditions or long-term ambient illumination.