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Metals and alloy - Atmospheric corrosion testing

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Metals and alloys : atmospheric corrosion testing : General requirements for field tests

KoreaScience (Korea)

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In order to develop the filler metal for Hastelloy alloy XR structure with thick wall, the weldability and high temperature strength properties of Hastelloy alloy XR weldment were investigated using the filler metals, which were alloy-designed on the basis of multiple regression analysis. The former was examined through the chemical analysis in the deposited metal, bend test, FISCO cracking test, optical microscopy and hardness measurement. The latter was investigated by means of tensile and creep test. It was found from these results that the crack susceptibility in the weldment was apparent to be lowered without degrading the high temperature strength properties. Therefore, it is concluded that these filler metals possess excellent performance as the filler metal for Hastelloy alloy XR structure ...

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A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode.

International Nuclear Information System (INIS)

The following methods of quartz ceramics alloying were considered: alloying of initial quartz glass; introduction of alloying additive into water slip of quartz glass; porous materials impregnation with salt aqueous solutions and subsequent salt thermal decomposition with formation of stable oxides in pores of ceramics. Oxygen free compounds BN, SiB_4, SiC, Si_3N_4, REM oxides and transition metal oxides were used as alloying additives. Main properties of the materials and compositions obtained are presented.

International Nuclear Information System (INIS)

High temperature fatigue crack growth (FCG) and creep crack growth (CCG) experiments have been conducted in air on weld metal, heat affected zone (HAZ) and base metal of the austenitic Alloy 800 and the nickel base Alloy 617. Tests were performed on specimens machined from pipes, in the temperature range 550-900 deg. C. The crack propagation mode was examined. At all temperatures and for both materials, FCG of base metal was found to be the highest, whereas the weld metal exhibited the lowest FCG rate. The FCG rate in the HAZ was found to lie in between of those observed for base and weld metal. The crack propagation mode remained transgranular in base metal and transdendritic in weld metal at all temperatures. CCG behaviour could be described using the energy rate integral C*. Base ...

British Library Electronic Table of Contents (United Kingdom)

Abstract Purpose: Long-term success of metal ceramic restorations depends on metal ceramic bond strength. The purpose of this study was to determine whether recasting of base-metal alloys has any effect on metal ceramic bond strength. Materials and Methods: Super Cast and Verabond base-metal alloys were used to cast 260 wax patterns. The alloy specimens were equally divided into five groups and cast as: group A 0.0%, B 25%, C 50%, D 75%, and E 100% once-cast alloy. Each group was divided into two subgroups: the first group was cast with Super Cast and the second with Verabond. In each subgroup half of the cast alloys were veneered with Vita VMK 68 and the others with Ceramco 3. Results: Recasting decreased bond strength (p < 0.006) when used for 50% once-cast ...

British Library Electronic Table of Contents (United Kingdom)

Magnetic pulse welding is a solid state impact welding process, similar to explosive welding, which produces metallurgical bond by oblique high-speed impact between two metal bodies. This violent impact removes the metal surface oxide layers and then joins the two atomic level clean metal surfaces together by the incidental compression pressure. The impact velocity is at 200?400?m/s and the being welded metal surface undergoes severe plastic deformation with strain rate in the order of 106?107?s?1. The ultrafine-grained structure was observed on the welded interface. This article studied two types of similar material lap joint interfaces and the base metals were aluminum alloy 6061 and copper alloy 110. Nano-indentation testing shows that the welded interfaces have significantly greater ha...

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The weldability and high temperature strength properties of tungsten-inert-gas (TIG) weldments of Hastelloy alloy XR were investigated by using two different heats of filler metals; the first (HXRF1) was designed on the basis of multiple regression analysis; the second (HXRF2) was the reference material. Bend tests, the FISCO cracking test and optical metallography were used to evaluate weldability. Tensile and creep tests were performed at 900deg C to evaluate high temperature strength properties. The results of weldability tests for both alloys showed good performance. The tensile properties of the weldments were remarkably improved in particular with respect to high temperature ductility. The creep rupture strength in the weldments made with alloy-designed HXRF1 was much higher than those of the Hastelloy alloy XR-II base metal with a higher B content. ...

International Nuclear Information System (INIS)

Available data are presented which support the supposition that metals and alloys with a negative low-temperature Hall coefficient are apparently not superconducting. (author).

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In this work, we have investigated the capability of different bimetallic nanoparticle alloy combinations to be used in fibre optic temperature sensing based on the technique of surface plasmon resonance (SPR). The metals considered for the present analysis are silver, gold and aluminium. The analysis is derived mainly from the thermo-optic effect along with some fundamental concepts of metal optics such as surface scattering, phonon-electron scattering and electron-electron scattering. The performance of the sensor with three different bimetallic nanoparticle alloy combinations is evaluated and compared, numerically, in terms of its sensitivity and accuracy. On the basis of the comparison and some logistic criterion, we predict the best possible bimetallic alloy combination along with a requisite alloy composition ratio that simultaneously provides higher ...

Energy Technology Data Exchange (ETDEWEB)

In this work, we have investigated the capability of different bimetallic nanoparticle alloy combinations to be used in fibre optic sensors based on the technique of surface plasmon resonance. The metals considered for this analysis are silver, gold, copper and aluminium. The performance of the sensor with different bimetallic nanoparticle alloy combinations is evaluated and compared numerically. The performance is analysed in terms of three parameters: sensitivity, signal-to-noise ratio (SNR) and operating range for the sensing layer refractive index values. On the basis of the comparison and some logistic criteria, the best possible bimetallic alloy combinations along with a requisite alloy composition ratio are predicted. The bimetallic nanoparticle alloy combination is capable of simultaneously providing larger values of sensitivity, SNR and operating range, ...

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Refractory metal alloys based on Mo, W, Re, Ta, and Nb (Cb) find applications in a wide range of aerospace applications because of their high melting points and high-temperature strength. This paper, presents recent progress in understanding and applications of these alloys. Recent studies to improve the oxidation and mechanical behavior of refractory metal alloys, and particularly Nb alloys, are also discussed. Some Re structures, for extremely high temperature applications (> 2000C), made by CVD and P/M processes, are also illustrated. Interesting work on the development of new W alloys (W-HfC-X) and the characterization of some commercial refractory metals, e.g., K-doped W, TZM, and Nb-1%Zr, continues. Finally, recent developments in high temperature composites reinforced with refractory metal ...

British Library Electronic Table of Contents (United Kingdom)

A problem of the catalytic activity definition for metals, binary metallic alloys, and semiconductor materials is considered within new quantum mechanical and electrodynamics approach in the electron theory of catalysis. The quantitative link between the electron structure parameters of the materials and their catalytic activity on example of simple model reactions of the following type are found: H = H+ + e, O2 + e- = O2-. Copyright 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2009

International Nuclear Information System (INIS)

K?-to-K? X-ray intensity ratios of Ti and Ni have been measured in pure metals and in alloys of TixNi1-x (x=0.7, 0.6, 0.5, 0.4 and 0.3) following excitation by 22.69 keV X-rays from a 10 mCi 109Cd radioactive point source. The valence-electron configurations of these metals were determined by corporation of measured K?-to-K? X-ray intensity ratios with the results of multiconfiguration Dirac-Fock calculation for various valence-electron configurations. Valence-electron configurations of 3d-transition metals in alloys indicate significant differences with respect to the pure metals. Our analysis indicates that these differences arise from delocalization and/or charge transfer phenomena in alloys. Namely, the observed change of the valence-electron configurations of metals in alloys can be explained ...

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Metal dusting corrosion has been a serious problem in the petroleum and petrochemical industries, such as reforming and syngas production systems. This form of deterioration has led to worldwide material loss for 50 years. For the past three years, we have studied the mechanism of metal dusting for Fe- and Ni-base alloys. In this report, we present a correlation between the weight loss and depth of pits that form in Ni-base alloys. Nickel-base alloys were also tested at 1 and 14.8 atm (210 psi), in a high carbon activity environment. Higher system pressure was found to accelerate corrosion in most Ni-base alloys. To reduce testing time, a pre-pitting method was developed. Mechanical scratches on the alloy surface led to fast metal dusting corrosion. We have also developed preliminary data on the performance of weldments ...

International Nuclear Information System (INIS)

Effect of hydroxide nature, concentration and temperature on corrosion resistance of domestic steels and alloys to hot NaOH, KOH, LiOH solutions is considered. It is ascertained that by corrosion growth in relation to stainless steels and nickel alloys, the hydroxides are placed in the following sequence: LiOHalloy tendency to cracking is manifested, are determined. 12 refs., 12 figs.

International Nuclear Information System (INIS)

Magnetic properties of a recently developed Fe-based amorphous alloy with a high saturation induction of 1.65 T are reviewed. The increased saturation induction is fully utilized in transformers with reduced magnetic losses, physical sizes and audible noises, minimizing some of the drawbacks of amorphous metal-based transformers based on a currently available amorphous alloy. Impacts of this on the worldwide energy savings and reduction of greenhouse gas emissions are discussed. A recent effort in achieving a saturation induction beyond 1.65 T in nanocrystalline alloys is mentioned.

International Nuclear Information System (INIS)

In order to investigate the role of amorphous SiO2 particles in corrosion and wear resistance of Ni-based metal matrix composite alloying layer, the amorphous nano-SiO2 particles reinforced Ni-based composite alloying layer has been prepared by double glow plasma alloying on AISI 316L stainless steel surface, where Ni/amorphous nano-SiO2 was firstly predeposited by brush plating. The composition and microstructure of the nano-SiO2 particles reinforced Ni-based composite alloying layer were analyzed by using SEM, TEM and XRD. The results indicated that the composite alloying layer consisted of ?-phase and amorphous nano-SiO2 particles, and under alloying temperature (1000 deg. C) condition, the nano-SiO2 particles were uniformly distributed in the alloying layer and still kept the amorphous structure. The corrosion ...

Energy Technology Data Exchange (ETDEWEB)

Use of hydrogen absorbing alloys in various practical applications is always connected with the problem of production of starting alloys. The transition from laboratory samples to small-scale production involves the change of furnace and its operation mode and this has an effect on the preparation method of mixture of starting metal. Also, for some applications such as thermosorption compressors the exact values of thermodynamical parameters of reaction are needed. In the present work we present the results of investigation of series Laves phase hydrogen-absorbing alloys which can be promising in for use in different devices. 1 ref.

International Nuclear Information System (INIS)

The corrosion behavior of the sputter-deposited amorphous or nanocrystalline W-Nb alloys is studied in 10% NaCl, 0.1 and 1 M NaOH solutions at 24 deg. C, open to air using immersion tests and electrochemical measurements. Niobium metal acts synergistically with tungsten in enhancing the corrosion resistance of the W-Nb alloys so as to show lower corrosion rates than the corrosion rates of the alloy-constituting elements in almost all examined solutions. Corrosion rates of W-Nb alloys are about more than one order of magnitude less than that of the sputter-deposited tungsten and even lower than that of sputter-deposited niobium. The stability of the anodic passive films formed on the W-Nb alloys increase with niobium content.

International Nuclear Information System (INIS)

In this study, dissimilar welds between HP heat-resistant steel and Incoloy 800 were made with four different filler materials including: 309 stainless steel and nickel-based Inconel 82, 182 and 617. The microstructure of the base metals, weld metals and their interfaces were characterized by utilizing optical and scanning electron microscopy. Grain boundaries migration in the weld metals was studied. It was found that the migration of grain boundaries in the Inconel 82 weld metal was very extensive. Precipitates of TiC and M_2_3C_6 (M = Cr and Mo) in the Inconel 617 weld metal are identified. The necessary conditions for the formation of cracks close to the fusion line of the 309-HP joints are described. Furthermore unmixed zone near the fusion line between HP steel base metal and Inconel 82 weld metal is discussed. An epitaxial growth is ...

Energy Technology Data Exchange (ETDEWEB)

Dissimilar metal welds between ferritic low-alloy and austenitic stainless steels commonly occur in power plant application. In order to overcome some of the problems encountered here, a trimetallic configuration using an intermediate piece (such as Alloy 800) between the austenitic and ferritic steels has been suggested. This paper describes some features of the joints between modified 9Cr-1Mo steel and Alloy 800, produced with Inconel 82/182 filler material. The joints require heat-treatment after welding and the results have shown that a treatment at 760 C for 2 h would be optimal. Although most tensile failures occurred in the weld metal the welds were found to exhibit strength properties that are at least equal to those of Alloy 800, with a tensile elongation lying between those of the two base materials. Similarly, while the weld ...

International Nuclear Information System (INIS)

Preparation and electrocatalytic reactions of nano porous materials in biodegradable fluids were studied. Electrochemical etching was conducted to selectively extract metallic elements from alloys to form porous structures. Electrocatalytic properties of the porous electrodes were characterized. Comparative studies on the electrochemical activities of the nano porous metallic electrodes with bulk metallic wire catalysts were performed. It is found that the current density at the nano porous electrode is three times higher than that of the bulk electrode

International Nuclear Information System (INIS)

It is generally known that a number of metallic glasses have excellent corrosion resistance in a variety of chemically hostile environments. Consequently, the use of laser cladding to coat a massive crystalline material such as aluminium with a layer of a metallic glass has obvious advantages. In this paper, the authors will show that the formation of a predominantly amorphous layer of Zr_6_0Al_1_5NI_2_5 alloy by laser processing is possible, if the obstacles to amorphization are overcome. In addition, evidence of the excellent corrosion resistance of this alloy in a NaCl solution will be given. A comparative study of the corrosion behavior of this amorphous alloy with pure aluminium and Al-Cr alloy will be done, in order to complete previous studies of laser processed coatings of aluminum substrates.

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The advent of light metal alloys and advanced materials (polymer, composites, etc.) have brought the possibility of achieving important energy reductions into the full life cycle of these materials, especially in transportation applications. 1 These materials have gained acceptance in the aerospace industry but use of light metal alloys needs to gain wider acceptance in other commercial transportation areas. Among the main reasons for the relatively low use of these materials are the lack of manufacturability, insufficient mechanical properties, and increased material costs due to processing inefficiencies. Considering the enormous potential energy savings associated with the use of light metal alloys and advanced materials in transportation, there is a need to identify R&D opportunities in the fields of materials fabrication and forming aimed at ...

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It has been shown by recent experiments that bulk immiscible metals (e.g. Ag/Cu, Ag/Co and Au/Ni) can form binary alloys on certain surfaces where the substrate mediates the elastic misfits between the two components, thus relieving the elastic strain in the overlayer. These novel surface alloys exhibit a rich phase structure. We formulate a two-component Frenkel-Kontorova model in one dimension to study surface alloy formation. This model can naturally incorporate dislocation formation that plays a crucial role in determining the actual structure of the system. Using energy minimization calculations we provide a phase diagram in terms of average alloy composition and the energy of mixing. Monte Carlo simulations were also performed to study the structure and interaction of the emerging dislocations.

Science.gov (United States)

... having high fluidity. The SC-51A alloy contains 4.5 to 5.5% silicon, 1 to 1.5% coppers .4 to .6% magnesium, o35% sine, .8% iron, .5% manganes*, ...

UK PubMed Central (United Kingdom)

Many patients are currently suffering from nickel (Ni)-induced allergic contact dermatitis (ACD). There have been few Korean studies dealing with the threshold of Ni-induced ACD and quantifying the...Full Text Available

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The most typical kinds of corrosion of brasses are selective corrosion (dezincification) and stress corrosion. Prevention against these kinds of corrosion lies in application of arsenic alloy addition and appropriate heat treatment removing internal stresses as well as in maintaining the arsenic and phosphorus contents on a proper level. The most typical corrosion of cupronickels is the local corrosion. Selective corrosion occurs less often and corrosion cracking caused by stress corrosion in sea water does not usually occur. Crevice corrosion is found especially in places of an heterogeneous oxidation of the surface under inorganic deposits or under bio-film. Common corrosive phenomena for brasses and cupronickels are the effects caused by sea water flow and most often the impingement attack. Alloy additions improve resistance to the action of intensive sea water flow but situation in this field requires further improvement, especially if the ...

International Nuclear Information System (INIS)

As the first step for development of the corrosion resistant superheater tube materials of 500 C, 100 ata used in high efficient waste-to-energy plants, field corrosion tests of six conventional alloys were carried out at metal temperatures of 450 C and 550 C for 700 and 3,000 hours in four typical Japanese waste incineration plants. The test results indicate that austenitic alloys containing approximately 80 wt% [Cr+Ni] show excellent corrosion resistance. When the corrosive environment is severe, intergranular corrosion of 40#approx#200 microm depth occurs in stainless steel and high alloyed materials. It is confirmed quantitatively that corrosion behavior is influenced by environmental corrosion factors such as Cl concentration and thickness of deposits on tube surface, metal temperature, and flue gas temperature. The excellent corrosion resistance of high [Cr+Ni+Mo] ...

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The bibliography contains citations concerning the pitting corrosion of copper and copper alloys, in different media, with some references to methods for protecting against such corrosion. Included are factors contributing to the onset of pitting corrosion. Emphasis is placed on exposure to water, especially in tubing for heat exchangers and water conduits. Many of the citations present studies on exposure to sea water. Some references pertain to the detection of pitting corrosion in installations and the evaluation of the degree of pitting present. (Contains 250 citations and includes a subject term index and title list.)

International Nuclear Information System (INIS)

Iron alloys and aluminum were nitrogen implanted in a controlled oxygen atmosphere and the role of hydrogen on the surface etching mechanisms studied. The surface composition was analyzed by in situ photoemission electron spectroscopy (XPS). In iron alloys, hydrogen strongly etches oxygen, improving nitrogen retention on the surface. On the other hand, hydrogen removes nitrogen from aluminum surfaces, with a deleterious effect on the nitriding effectiveness. The oxygen removal in iron alloys is associated with the catalytic effect of electrons in d-orbitals and the nitrogen removal in aluminum is associated with a steric effect.

International Nuclear Information System (INIS)

Theoretical description of Raman scattering in disordered alloys of Ti and Zr with transition metals of groups 5-8 of the Mendeleev Periodic System in critical range of concentrations (CRC) is given. Results of Raman scattering experiment in the system Ti_1_-_xF_x at 0.0005alloys studied near CRC is shown.

International Nuclear Information System (INIS)

Repassivation behavior and IGA resistance of nickel base alloys containing 0#approx#30 wt% chromium was investigated in high temperature acid sulfate solution. (1) The repassivation rate was increased with increasing chromium content. And so the amounts of charge caused by the metal dissolution were decreased with increasing chromium content. (2) Mill-annealed Alloy 600 suffered IGA at low pH environment below about 3.5 at the fixed potentials above the corrosion potential in 10%Na_2SO_4+H_2SO_4 solution at 598K. On the other hand, thermally-treated Alloy 690 was hard to occur IGA at low pH environments which mill-annealed Alloy 600 occurred IGA. (3) It was considered that the reason, why nickel base alloys containing high chromium content such as Alloy 690 (60%Ni-30%Cr-10%Fe) had high IGA/SCC resistance in high temperature acidic solution ...

Energy Technology Data Exchange (ETDEWEB)

Some N-containing or S-containing organic substances and some acetylenic alcohols were tested as inhibitors of the corrosive attack suffered by Fe-based metallic glasses in deaerated 0.1 N sulfuric acid (H{sub 2}SO{sub 4}) solution at 25 C. It was verified that the specific action these compounds exerted on the corrosion process of the amorphous alloys was similar to the one these compounds exerted on polycrystalline iron. The most efficient substances were those containing a sulfur atom with available lone pairs, which chiefly inhibited the anodic reaction of both metal specimens. Owing to the chemical and physical homogeneity of the amorphous alloy, the chemisorbed inhibitor film that formed on the glassy surface was more stable and protective than that formed on the polycrystalline iron.

International Nuclear Information System (INIS)

The authors investigate the corrosion and anodic behavior of steels 12Kh18N10T, 08Kh21N6M2T, and 06KhN28MDT, nickel, and molybdenum in 10-40% naturally aerated solutions of H_2TiF_6 at 20 and 50 degrees C. The authors found that in solutions of fluotitanic acid, as also in tetrafluoroboric and hydrofluoric acids, the most stable alloys are chromium-nickel-molybdenum alloy of type 06KhN28MDT and (for acid concentrations above 20%) copper-nickel-alloys of the monel metal type. Steels 12Kh18N10T and 08Kh21N6M2T can be used in acid concentrations of less than 10% and temperatures up to 20 degrees C with anodic protection.

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3d occupation numbers of the transition elements corresponding to various types of atomic configurations are calculated by means of the linear muffin-tin orbital (LMTO) method. This data is used with the multiconfiguration Dirac-Fock (MCDF) X-ray intensity ratios to estimate the electron populations of the 3d metals in alloys.

Energy Technology Data Exchange (ETDEWEB)

Alloy 600 is commonly used in the primary systems of PWR plants because of its excellent resistance to a stress corrosion cracking and pitting. But a stress corrosion cracking and pitting corrosion are occasionally observed under PWR conditions, which may be correlated with the passive film on the Alloy 600 surface. There is little information on the composition of films growing on the surface of Alloy 600 at high temperature. Therefore, an understanding of the basic electrochemical behaviors about an anodic dissolution and the passivation of the bare surface of metals and alloys provides important information about localized corrosions like a SCC and pitting. Oxide on the steel surfaces in an aqueous solution above 100 .deg. C is composed of a duplex film structure. The inner layer of the oxide is dense and less porous, which is formed by a growth of the oxide layer on the ...

International Nuclear Information System (INIS)

K#beta#-to-K#alpha# x-ray intensity ratios of Fe and Ni in pure metals and in Fe_xNi_1_-_x alloys (x=0.20, 0.50, 0.58) exhibiting similar crystalline structure have been measured following excitation by 59.54 keV #gamma# rays from a 200 mCi "2"4"1Am point source to understand why the properties of the Fe_xNi_1_-_x (x=0.2) alloy are distinct from other alloy compositions. The valence electronic structure of Fe and Ni in the samples has been evaluated by comparing the measured K#beta#-to-K#alpha# intensity ratios with the results of multiconfiguration Dirac-Fock calculations. Significant changes in the 3d electron population (with respect to the pure metal) are observed for Fe and Ni for certain alloy compositions. These changes can be explained by assuming rearrangement of electrons between 3d and (4s,4p) band states of the individual metal ...

International Nuclear Information System (INIS)

Alloy 690 and Alloy600 are used as a material for the steam generator tubing in the pressurized water reactor(PWR) of nuclear power plants due to its high corrosion resistance. Although those are a highly corrosion resistance material, their stress corrosion cracking(SCC) have been found on occasion, which are deeply related to a surface oxide film on a base material which have occurred on the primary side as well as the secondary side of a tubing. And The SCC is accelerated in the existing Pb which is the impurity of secondary steam generator components. The Oxide on a steel surface in an aqueous solution above 100 .deg. C is composed of a duplex film structure. The inner layer of the oxide is dense and less porous, which is formed by a growth of the oxide layer on the metal surface. The outer layer of the oxide is less adhesive, which is formed by a dissolution and precipitation mechanism. Growth processes of the inner ...

Energy Technology Data Exchange (ETDEWEB)

At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic ...

Energy Technology Data Exchange (ETDEWEB)

Metallic components within or immediately adjacent to gasifiers, such as gas distributors, thermowells, transfer lines, and cyclones, are subjected to severe of temperature, pressure, and hostile multicomponent gas environments. Metallic heat exchangers/waste-heat boilers resistant to sulfidation, corrosion. and erosion in low- and medium-Btu gas environments are essential components in large-scale gasification schemes, in both dry ash and slogging type gasifiers. Components, in general. must be resistant to corrosion, erosion, and high-temperature creep. A substantial data base is needed on the mechanical properties of materials exposed to complex gas environments to provide a more viable basis for establishing long-term reliability of components. This work examines high-temperature creep of Alloy 800, a high-chromium alloy widely used in coal conversion systems, after exposure to oxygen and ...

International Nuclear Information System (INIS)

One of the major concerns during high speed welding of magnesium alloys is the presence of porosity in the weld metal that can deteriorate mechanical properties. This study seeks to analyze the presence method and quantity of pore during hybrid laser-tungsten inert gas arc (TIG) welding of magnesium alloy AZ31B by radiography, optical microscopy and electron probe microanalysis (EMPA). At the same time, it identifies both the mechanism of pore formation and a remedy for this problem. The experimental results indicate that lacking of shielding gas for laser beam is the dominant cause of macroporosity formation during the hybrid of laser-TIG welding of magnesium Alloys AZ31B plate, and hydrogen is not main cause to form large pores. A favorable weld without porosity can be obtained by appending lateral shielding gas for laser beam.

Energy Technology Data Exchange (ETDEWEB)

The effects of boron addition on weldability and high temperature strength properties were investigated for Hastelloy alloy XR used TIG welding process with the filler metals. Four versions of filler metals with different boron contents were used. The results obtained may be summarized as follows: (1) The influence of boron addition on weldability was not observed within the range of the present experiment. (2) The result of chemical analysis for deposited metals showed that boron desorption did not occur during welding. (3) The tensile properties of weldments, particularly in high temperature ductility were raised with increasing boron content. (4) In the creep properties of weldments, creep rupture life increased with increasing boron content under the given stress conditions. (author).

International Nuclear Information System (INIS)

Different semi precious alloys (Pd-Ag, Pd-Au) have been studied after thermal oxidation treatments to analyze the mechanical improvement of the interface between the metal and the ceramic. Using the four point bending test, the authors have analyzed the different steps corresponding to the mechanical evolution of the bi-material : cracking energy on the surface, relaxation energy after first cracking, propagation energy of cracks at the interface zone. It has been shown that some alloys only have a high resistance to the interface cracking and the role played by the interface reactions to improve this property. (orig.).

Energy Technology Data Exchange (ETDEWEB)

A method for preparing metal for heating by infrared radiance to enable uniform and consistent heating. The surface of one or more metal parts, such as aluminum or aluminum alloy parts, is treated to alter the surface finish to affect the reflectivity of the surface. The surface reflectivity is evaluated, such as by taking measurements at one or more points on the surface, to determine if a desired reflectivity has been achieved. The treating and measuring are performed until the measuring indicates that the desired reflectivity has been achieved. Once the treating has altered the surface finish to achieve the desired reflectivity, the metal part may then be exposed to infrared radiance to heat the metal part to a desired temperature, and that heating will be substantially consistent throughout by virtue of the desired reflectivity.

International Nuclear Information System (INIS)

Past elastic-plastic fracture studies for leak-before-break (LBB) assessment of low alloy steel pipings have been focused mostly on the behavior of base metals and their weld metals. In contrast, the heat-affected zone (HAZ) of a welded pipe has not been studied in detail primarily because the size of the HAZ is too small to make specimens for mechanical properties measurements. In this study, microstructural analyses, microhardness tests, tensile tests and J-R tests have been conducted as a function of distance from a fusion line and temperature for HAZ materials of SA106Gr.C low alloy piping steels. For the ferrite-pearlite steels such as SA106Gr.C, the HAZ specimens showed a higher yield strength and fracture toughness compared with those of its base metal. These characteristics, despite of grain coarsening, can be explained by cleaner microstructures of HAZ materials with a ...

International Nuclear Information System (INIS)

The recovery of noble metals from the quaternary Mo-Ru-Rh-Pd alloy in the simulated insoluble residue was studied by means of Pb extraction and the recovery yield was found to be more than 90% for Ru, Rh and Pd. The recovery yield of Mo was very small due to the oxidative vaporization in air. The decontamination factor for Ce as a stand-in of Pu was determined to be around 200 for one stage. These results on the recovery yields of noble metals from the quaternary alloy and the decontamination factor for Ce are in good agreement with those for the ternary Mo-Ru-Pd alloy previously reported by the present authors. The mutual separation of noble metal elements recovered in Pb button was examined by means of re-extraction with molten Zn and the dissolution in boiling 3M or 6M nitric acid solution. The dissolution fractions of Pd and Rh recovered in the Pb button in ...

International Nuclear Information System (INIS)

Austenitic stainless steels have been implanted with molybdenum ions (Mo"+, 100 keV, 2.5 x 10"1"6 atoms cm"-"2). The implanted material has been characterized by XPS and RBS. The implanted region has a thickness of #approx# 1000 A with a maximum molybdenum concentration of #approx# 9 at.% Mo located at #approx# 210 A from the surface. The effects of implanted molybdenum on the passivation of the alloy in 0.5 M H_2SO_4 have been investigated by electrochemistry and XPS. After XPS analysis the samples were transferred without exposure to air into a glove-box with an inert atmosphere. The electrochemical behaviour of the alloy is significantly modified by the implanted molybdenum. The major effect is that the activation peak disappears. A bilayer structure (outer hydroxide/inner oxide) of the passive film is observed for both the implanted and non-implanted alloys and the thicknesses of the films are similar. On the implanted ...

Energy Technology Data Exchange (ETDEWEB)

Superplasticity of polycrystalline metallic materials is a phenomenon which shows hundreds to thousands of percents of large plastic deformation without necking in a steady state of low stress, when the uni-axial tensile loading is done in some special thermo-mechanical conditions (some limited ranges of properly high temperature and low strain rate). The main mechanism of superplastic phenomenon is the grain boundary sliding, while the main mechanism of usual plastic deformation is the trans-granular sliding. In this research, the possibility of superplastic deformation in a magnesium alloy (AZ31Mg alloy) was experimentally investigated, because generally speaking, the magnesium alloy whose atomic structure is hexagonal does not have enough formability in a form of trans-granular sliding mechanism. In this paper, the detail of experimental results are shown and discussed. Moreover, the constitutive ...

International Nuclear Information System (INIS)

The development of light-weight vehicle is in great demand for enhancement of fuel efficiency and dynamic performance. The vehicle weight can be reduced effectively by using lightweight materials such as magnesium alloys. However, the use of magnesium alloys in sheet forming processes is still limited because of their low formability at room temperature and the lack of understanding of the forming process of magnesium alloys at elevated temperatures. In this study, uniaxial tensile tests of the magnesium alloy AZ31B-O at various temperatures were performed to evaluate the mechanical properties of this alloy relevant for forming of magnesium sheets. To construct a FLD (forming limit diagram), a forming limit test were conducted at temperature of 100 and 200 deg. C. For the evaluation of the effects of the punch temperature on the formability of a rectangular cup drawing with AZ31B-O, ...

International Nuclear Information System (INIS)

An analysis of the passive films formed on amorphous alloys of the system Fe-10% Cr-5% Mo-P-metalloid and Fe-10% Cr-5% Mo-B-Si revealed that they are more markedly enriched with chromium in silicon-free alloys. In silicon-containing amorphous alloys the passive films were highly enriched with silicon, which occurred in these films in the form of a corrosion product close to SiO_2. As shown by the investigations of a study of the anodic behavior of Fe_4_0Ni_4_0P_1_4B_6 and Fe_4_0Ni_3_8Mo_4B_1_8, phosphorus facilitates the passivation of amorphous alloys by reducing the solution current in the active state and enriching the surface layers of the metal in the form of a black prepassivation film which also contains nickel and iron. The behavior of Fe-Ni amorphous alloys containing only boron as metalloid additive differs little from that of crystalline ...

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. In the previous paper, corrosion mechanism was elucidated by the anodic protection-precipitates degradation model. This paper describes the roles on hydrogen pickup. 633 K pure water autoclave test was performed on high purity zirconium, Zr-0.2Fe, Zr-0.2Cr, and Zr-0.1Fe-0.1Cr alloys. Hydrogen analysis after the corrosion test showed that hydrogen pickup ratio of Zr-0.2Fe alloy was about 80%. It was much higher than about 30% of pure Zr and about 10% of both Zr-0.2Cr and Zr-0.1Fe-0.1Cr alloys. Larger hydrogen content was introduced into Zr-0.2Fe alloy than the other ones by the cathodic hydrogen charging under coulombic equivalence. The precipitates at ...

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Corrosion of several materials including pure metals Fe, Ni, Cr and also Fe-Cr, Fe-Ni-Cr alloys, has been studied in anisothermal Pb17Li (Tmax = 500 deg C; {Delta}T = 60 deg C). The corrosion rate of pure nickel is two orders of magnitude higher than the chromium one and about three orders of magnitude higher than the iron one. Fe-Cr alloys (1.4914) suffers a dissolution rate equal to the one of its major constituent, iron. With regard to the three austenitic materials (316L and NS20 steels, alloy 800), they exhibit a porous corrosion layer mainly constituted of ferrite but containing also a small amount of {sigma} phase in the case of the alloys with higher Ni content, NS30 steel and alloy 800. Mechanism of formation of this layer is discussed.

International Nuclear Information System (INIS)

This paper reports on the superiority of zeolites over amorphous solids which is well documented for solid acid catalysts of industrial use. Crystalline supports, likewise, open attractive perspectives for catalysis by metals, alloys, and ligated metal clusters. Size and location of clusters can be controlled by careful design of the preparation conditions. Pore dimensions control the access of reactants to active sites and escape paths for products. Cage dimensions determine which transition states can be attained; window apertures are functional in isolating metal clusters from each other, thus preventing ther coalescence and growth. The ship-in-a-bottle method permits deisgn of fairly large active complexes entrapped in zeolite cages. Orientation of non-spherical molecules in a zeolite proe helps to direct their collision with a metal particle to the head on mode; however, ...

International Nuclear Information System (INIS)

In this study, the corrosion behavior of commercially pure titanium (c.p. Ti), Ti-6Al-4V and five new experimental Ti-Cr alloys was evaluated through open-circuit potential (OCP) and potentiodynamic polarization measurement in an artificial saliva containing fluoride. Electron spectroscopy for chemical analysis (ESCA) was used to characterize the composition of the passive films on the alloy after potentiodynamic polarization measurement. It was found that in standard artificial saliva the OCP increases with higher Cr content in Ti-Cr alloys. In 0.5% NaF artificial saliva, the OCP decreases with decreasing Cr in Ti-Cr alloys, and all but Ti-5Cr remain consistently higher than those of c.p Ti and Ti-6Al-4V. Linear polarization results show that artificial saliva and artificial saliva containing 0.5% NaF result in different corrosion behavior in Ti-Cr alloys, c.p.Ti and Ti-6Al-4V. The ...

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To improve the surface properties of magnesium alloy, a lining process using shot peening was carried out. The lining of magnesium alloy with metals such as titanium and nickel is useful in heightening the corrosion and wear properties for the components. In the shot peening experiment, the foil set on the magnesium workpiece is pelted with many shots at a high velocity. The foil is bonded to the surface of the workpiece due to plastic deformation induced by the collision of the shots. A pure aluminum foil is inserted between the hard foil and magnesium workpiece to assist the bonding. To heighten the bondability, the foil and workpiece are heated and the flow stresses of the metals are reduced. In this experiment, a centrifugal shot peening machine with an electrical heater was employed. The workpieces were commercially magnesium alloys AZ31B and AZ91D, and the foils were ...

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A metal spray apparatus is provided with a supersonic nozzle. Molten metal is injected into a gas stream flowing through the nozzle under pressure. By varying the pressure of the injected metal, the droplet can be made in various selected sizes with each selected size having a high degree of size uniformity. A unique one piece graphite heater provides easily controlled uniformity of temperature in the nozzle and an attached tundish which holds the pressurized molten metal. A unique U-shaped gas heater provides extremely hot inlet gas temperatures to the nozzle. A particularly useful application of the spray apparatus is coating of threads of a fastener with a shape memory alloy. This permits a fastener to be easily inserted and removed but provides for a secure locking of the fastener in high temperature environments.

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Proposed ductile fracture toughness parameters from tensile tests have been successfully used to determine the post-weld heat treatment temperature for an alloy 800/(9Cr-1Mo) steel dissimilar metal weld joint that is optimum with respect to accelerated aging, which simulates service conditions. This approach proved superior to using microstructural analysis, microhardness profiles, and conventional tensile properties. (author).

British Library Electronic Table of Contents (United Kingdom)

Asymmetric Incremental Sheet Forming (AISF) is a relatively new manufacturing process. In AISF, a CNC driven forming tool imposes a localized plastic deformation as it moves along the contour of the desired part. Thus, the final shape is obtained by a sequence of localized plastic deformations. AISF is suitable for small series production of sheet metal parts as needed in aeronautical and medical applications. Two main process limits restrict the range of application of AISF in these fields. These are the low geometrical accuracy of parts made from titanium alloys or high strength steels and, for titanium alloys, the limited formability at room temperature. In this paper a new concept for laser-assisted AISF is introduced including the required components. Furthermore, the CAX tools used f...

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Membranes in Palladium and its alloys, in particular Pd/Ag alloys, are selectively permeable to hydrogen and can therefore be used to purify hydrogen. It is intended to use them as material for electrodes in fuel cells. As the manufacturing process of a substrate Pd/Ag-layer consists of several stages and is still not completely understood, it would be advantageous to be able to characterise separately the layers of noble metals obtained by electro-plating . Attempts are being made in this work to vary the cristallographical structure of the deposited alloy by the choice of test parameters and by sintering when depositing the Pd/Ag. The layers produced are to be examined using an interference microscope and X-ray diffraction. Moreover, the diffusion behaviour of the hydrogen is to be examined with an electro-chemical pulse method specifically developed for this purpose. figs., tabs., 27 refs.

International Nuclear Information System (INIS)

Passive films formed on Alloy 690 in high-temperature alkaline environments were investigated by potentiodynamic polarization, X-ray photoelectron spectroscopy, transmission electron microscopy and Mott-Schottky approach. Passive current density and donor density of the passive films increase with increasing temperature, due to increased diffusion rates of metallic ions and dehydration of hydroxide phases. The passive films show a duplex structure including an inner layer of fine-grained Cr oxide or spinel oxide and an outer layer of Ni-Fe spinel oxide and Ni hydroxide. A growth model of the passive films on Alloy 690 in high-temperature alkaline environments is proposed and discussed.

International Nuclear Information System (INIS)

We report studies of bimetallic nanoparticles with 15%-16% atomic crystal parameters size mismatch. The degree of alloying was probed in a 2-nm Pt core (smallest attainable core size) of Pt-Ag nanoparticles (completely immiscible in bulk) and 20-nm-diameter Pd-Ag nanowires (completely miscible in bulk). Particles were synthesized radiolytically, and depending on the initial parameters, they assume spherical or cylindrical (nanowire) morphologies. In all cases, the metals are seen to follow their bulk alloying characteristics. Pt and Ag segregate in both spherical and wire forms, which indicates that strain due to crystallographic mismatch overcomes the excess surface free energy in the small particles. The Pd-Ag nanowires alloy similar to previously reported spherical Pd-Ag particles of similar diameter and composition.

International Nuclear Information System (INIS)

The photon rupture method, by which oxide film and metal are removed by focused pulsed Nd-YAG laser beam irradiation, was applied to form artificial micro-pits in Zn-5 mass% Al alloy-coated steel. The zinc alloy-coated layer was removed by pulsed laser irradiation treatment for about one second in a neutral buffer solution with NaCl. The rest potential transient with the laser treatment was measured. In the early stage of the laser treatment the rest potential of zinc alloy-coated steel changed to the negative direction immediately after every irradiation of a laser pulse and then returned to the previous value. However, after the steel substrate was exposed to the solution, the rest potential moved to the positive direction immediately after every irradiation of a laser pulse and then returned to the previous value. The amplitude and duration of the potential change after the laser irradiation ...

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K{beta}-to-K{alpha} X-ray intensity ratios of Ti, Cr, Fe and Co in pure metals and in Cr{sub 0.26}Fe{sub 0.74}, Cr{sub 0.80}Co{sub 0.20} and Ti{sub 0.80}Cr{sub 0.20} alloys have been measured following excitation by 59.54 keV {gamma}-rays from a 7400 MBq (200 mCi) {sup 241}Am point-source. The valence electronic structure of Ti, Cr, Fe and Co in the samples have been evaluated by the comparison of the measured K{beta}-to-K{alpha} intensity ratios with the results of multiconfiguration Dirac-Fock calculations performed for various electronic configurations of these metals. The 3d-electron populations obtained for pure metallic Ti, Cr, Fe and Co agree well with the results of band structure calculations of Papaconstantopoulos (Handbook of band structure of elemental solids, Plenum Press, New York, 1986). Our analysis indicates significant increase of 3d-electron population of Ti, Cr and Fe in the ...

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The need for a hydrogen economy is driven by increasing fuel prices, depleting oil reserves and uncertainty over supplies, and concerns about global warming and environmental pollution. Alternative methods to portable energy sources such as fossil fuels are being developed that are more efficient and carbon-emission-neutral. A prospective method is to produce hydrogen as an energy carrier. This paper presented a study on the degradation of materials under conditions of the sulphur-iodine (SI) thermochemical cycle. The paper provided background information on the study and presented a schematic of the SI cycle. A literature review was presented along with materials selected, such as refractory metals, reactive metals, superalloys, glassy metals, ceramics, cermets, polymers, composites, and coatings. The experimental method was then described. A capsule method was developed to rapidly quantify the decomposition rate of the ...

International Nuclear Information System (INIS)

The following are reported: colorimetric determination of Ti in Cr, decontamination of metals by anodic dissolution, computer code for x-ray peak identification, gel-permeation chromatography of CoRezyn 1664 polyester resin, infrared monitoring of gases and vapors, particle size analysis of dusts, nondestructive analysis of Oralloy for removable alpha contamination, dissolution (digestion) of high-fired oxides, assay of U in a Pu-U alloy, measurement of oxide thickness on Pu metal by x-ray diffraction, analysis of precipitated Pu peroxide, differentiation of Dowex SBR and 11 resins, and determination of Pu solubility in simulated lung fluid.

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On the basis of observations of the JTEC team, it appears that Japanese universities and research institutes are leading long-term R&D thrusts for development of new materials casting technologies. Significant efforts include amorphous metals, intermetallics, application of MHD in continuous casting of steel, and energy efficient furnace technology. Industrial R&D seems focused more on process improvements than on new product technologies, but significant efforts in new cast materials included cast metal matrix composites, materials substitutions for thinner wall products, and advanced ceramic products for foundry industry applications.

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The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.

International Nuclear Information System (INIS)

To clarify the effects of the principal factors that govern the thermal fragmentation of a molten metallic fuel jet in the course of fuel-coolant interaction, which is important in evaluating the sequence of core disruptive accidents (CDAs) for metallic fuel fast reactors, basic experiments were carried out using molten metallic fuel simulants (copper and silver) and a sodium pool.Fragmentation of a molten metal jet with a solid crust was caused by internal pressure produced by the boiling of sodium, which is locally entrapped inside the jet due to hydrodynamic motion between the jet and the coolant. The superheating and the latent heat of fusion of the jet are the principal factors governing this type of thermal fragmentation. On the other hand, the effect of the initial sodium temperature is regarded as negligible in the case of thermal conditions expected to result in CDAs for practical ...

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Maximum metal loss rate of Alloy 800 coupons was about 0.5 mil/year and occurred at the maximum temperature of 600/sup 0/C. Significantly greater oxide penetration into the alloy occurred in unabraded as-received tubing. Since the corrosion rate of unabraded tubing was less temperature sensitive than polished coupons, and attained a maximum value at temperatures in the range of 550 to 565/sup 0/C, a value of 1 mil/year should be used as the corrosion rate for design purposes. Because daily thermal cycling is inherent in solar central receiver operation, oxidation and chromium depletion rates can be expected to increase if surface oxide layers spall. The oxide layers formed on Alloy 800 appeared to be adherent, and adherence will benefit further from growth-derived compressive stresses in oxide layers on the salt-exposed inner diameter of receiver tubes. Since the lower duty factor in diurnal solar ...

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For evaporation crystallization of extremely corrosive FGD scrubber solutions which - depending on the process - can lead all the way to a product suitable for depositing, an economic equipment concept based on metallic construction materials was to be investigated. In a parameter study, electrochemical test methods were used to determine the influence of the pH value, the Fe{sup 3+}, F and So{sub 2} contents in a solution containing 200 g/l CaCl{sub 2}+30 g/l NaCl at 80deg C on the resistance to pitting corrosion of stainless steels and NiCrMo alloys. In addition, electrochemical and wet corrosion tests (e.g. crevice corrosion) were conducted using original FGD scrubber solutions with 43-50% dry substance from the power plants Reuter-West, Oberhavel and Rudow of the BEWAG, Berlin. The results were compared to those of standardized and non-standardized short-term tests for determining the critical pitting corrosion and crevice corrosion ...

International Nuclear Information System (INIS)

We report the oxygen, hydrogen, and deuterium effects on nitrogen implantation of stainless steel. Oxygen is absorbed on the surface creating a potential barrier and diminishing the nitrogen retention. Deuterium removes more oxygen from the surface than hydrogen, augmenting the nitrogen chemical potential and yielding faster nitrogen diffusion into the bulk material.

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In this work a Ni-based superalloy GMR 235 was investigated. We determined convenient metallographic methods for preparation of bulk metallographic specimens, extraction carbon replicas, transparent metallic foils and minor phase extraction. In addition, the alloy microstructure was characterised using different metallographic techniques. (orig.)

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Hydrogen uptake and embrittlement of tantalum by electrolytically produced hydrogen is investigated on samples of varying composition and type of pretreatment. Of decisive influence on the uptake of hydrogen are the oxide layers present on the tantalum surface. By contact with platinum group metals as alloying constituents, surface coatings or anodic protection, a protection of tantalum can be obtained depending on the experimental conditions.

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Properties of highly correlated electrons, such as heavy fermion compounds, metal-insulator transitions, one-dimensional conductors and systems of restricted dimensionality are studied theoretically. The main focus is on Kondo insulators and impurity bands due to Kondo holes, the low-temperature magnetoresistivity of heavy fermion alloys, the n-channel Kondo problem, mesoscopic systems and one-dimensional conductors.

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A necessary condition for crevice corrosion is that a crevice former create a sufficiently tight, restricted geometry on the metal surface to support the development of critical crevice chemistry. Crevice corrosion is affected by the crevice geometry (tightness) and the properties of the crevice former. The objective of this study is to determine the effect of the crevice former material on the evolution of localized corrosion-damage. A standard crevice corrosion test method is modified by (a) the use of ceramic, metal or polymer materials as the crevice former and (b) the variation of size and shape of the crevice. This study focuses on the post initiation stage of crevice corrosion and addresses factors that may limit the initiation of localized corrosion and also slow or stop the continued propagation of corrosion. Controlled crevice corrosion tests are performed under aggressive, accelerated conditions on Ni-Cr-Mo alloy ...

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The effect of accelerated thermal cycling on a joint between modified 9Cr-1Mo steel (Grade 91) and Alloy 800 welded with Inconel 82 and 182 filler material is discussed. This is part of a trimetallic transition joint involving Grade 91-Alloy 800-316LN austenitic stainless steel for steam generator application. It has been shown that, during thermal cycling following the typical post-weld tempering treatment at 760 deg. C for 2 h, no carbon diffusion occurs from the ferritic steel towards the weld metal. There is, in fact, a hardness increase at the ferritic steel/weld metal interface which is probably a result of work hardening. Carbon migration sets in only after unusually long post-weld heat treatments for 20 and 50 h at 760 deg. C followed by thermal cycling. Significantly, even under the most severe thermal cycling test conditions imposed, no cracking or oxide notching could be detected, thus ...

International Nuclear Information System (INIS)

In situ spectroscopic ellipsometry was employed to investigate the initial regime of rare earth metal (REM) conversion coatings formation on AZ31 magnesium alloy. Three REM salts solutions, 0.05 mol.dm"-"3 Ce(NO_3)_3, La(NO)_3 and Sm(NO)_3 solutions, were used for REM conversion coatings preparation. By deconvoluting the ellipsometric data, the surface of the fresh well-polished AZ31 magnesium alloy was found to be covered with 15.80 nm thick native (hydr)oxide film; the refractive indices and the thickness of Ce, La and Sm conversion coatings were obtained. The formation kinetics of three REM coatings follows different exponential functions and the coatings exhibit different optical properties. La conversion coating has the largest n values and the lowest k values while Sm conversion coating is just opposite. Moreover, the pH variation of the bulk conversion solutions upon the coatings formation was recorded. It is ...

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The purpose of the invention is a process for the production of a particularly finely divided, homogeneous transition metal phosphide and transition metal chalcogenide of Daltonian stochiometry by the conversion of at least one powder transition metal or a transition metal alloy with phosphorus or with a chalcogen at raised temperature, which is characterized by the fact that the conversion is carried out in the presence of at least one inert finely divided auxiliary material which is soluble in water and does not sinter together at the reaction temperature, and that the conversion produce removes the auxiliary material. Even relatively small quantities of the auxiliary material are sufficient to ensure rapid and homogeneous conversion of the reaction partners to the reaction product having a large surface. A ratio of 1 part by volume of a mixture of a transition ...

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The alloying of steel surface with aluminum (Al) using Microsecond-pulsed Intense Electron Beams (MIEB-Al) was developed and optimized in order to be used for improving the corrosion resistance of the 316, 1.4970 and T91 steels, exposed to liquid Pb and Pb-Bi-eutectic. The procedure consists in two steps: (i) coating the steel surface with Al or an Al-containing alloy layer and (ii) melting the coating layer and the steel surface layer using intense pulsed electron beam. In order to cover the steel surface with an homogeneous and crack-free Al-alloyed layer, the following experimental conditions are required: Al coating thickness range 5-10mm, electron kinetic energy 120keV; pulse duration 30ms; energy density 40-45J/cm2; number of pulses 2-3. Using the mentioned procedure, the corrosion r...

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Increase usage of magnesium components in the portable electronics industries has propelled considerable research interest on the development of magnesium forging. There have been some studies done in the area of sheet metal forming and forging of axis-symmetrical parts of magnesium alloys but there are very little work done on the plane strain backward extrusion of magnesium alloy. This paper deals with the analysis of plane strain extrusion of magnesium alloy, AZ31, using numerical modeling at different extrusion conditions of temperatures and friction coefficients. A commercially available finite element package, ANSYS/LSDYNA, was used in the finite element analysis. FE simulated results, material deformation, punch force and stress/strain distributions, were compared with actual experimental data. From the numerical analysis, a decrease in forging temperature from 300 C to 250 C will lead to a ...

British Library Electronic Table of Contents (United Kingdom)

Laser consolidation (LC) developed by National Research Council???s Industrial Materials Institute (NRC-IMI-London) since mid-1990s, is a laser cladding based rapid manufacturing and material additive process that could fabricate a ???net-shape??? functional metallic shape through a ???layer-upon-layer??? deposition directly from a computer aided design model without using molds or dies. In order to evaluate the LC processability of different materials, some representative nickel-based superalloys (IN-625, IN-718, IN-738, and Waspaloy), stainless steels (austenitic SS316L and martensitic SS420), and lightweight alloys (Ti???6Al???4V titanium alloy and Al-4047 aluminum alloy) have been investigated. Like other laser cladding based processes, due to process-induced rapid directional solidifi...

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Acrylonitrile electropolymerization (in an aprotic and anhydrous medium) has been used as a way to build thin, homogeneous and covering polyacrylonitrile layers grafted on the surface of usual metals and specially on copper-based shape memory alloy: Cu-Zn-Al. The results of the study first confirm the possibility of grafting thin and covering polyacrylonitrile layers on Cu-Zn-Al surface. The morphology of the films however is influenced by the geometry of the polycristalline structure of the alloy and its superficial defects. Samples obtained after grafting polyacrylonitrile films were submitted to corrosion tests based on Electrochemical Impedance Spectroscopy (EIS) measurements in a NaCl/H{sub 2}O medium. Results show that some post-treatments of the grafted films are necessary to improve their protective role, while preserving the strong interfacial bondings. Actually, thermal and mechanical cycling of the shape memory ...

International Nuclear Information System (INIS)

Photoelectrochemical current response of passive film was investigated for pure Cr and Fe-xCr (x = 8, 14, 18) alloys polarised potentiostatically in 0.1 kmol m"-"3 H_2SO_4 solution. Photoelectrochemical action spectrum could be separated into two or three constituents. These components were considered to be derived from Cr_2O_3 (E_g"o"p"t#propor to#3.6 eV) and Cr(OH)_3 (E_g"o"p"t#propor to#2.5 eV), and possibly CrO OH. The optical band gap, E_g"o"p"t, of each component was almost constant for various applied potentials, polarisation periods, and substrate materials. Flat band potential E_j_b at which the polarity of photocurrent changes from negative to positive with increasing potential was determined for each phase. E_j_b for Cr(OH)_3 on Cr and Fe-Cr alloys was about 250 mV_A_g_/_A_g_C_l. E_j_b for Cr_2O_3 was about 700 mV for Cr and about 500 mV for Fe-Cr alloys. E_j_b of Cr_2O_3 for Fe-Cr alloys ...

International Nuclear Information System (INIS)

The corrosion and passivation behaviour of bulk polycrystalline martensite Ni50Mn30Ga20 and austenite Ni48Mn30Ga22 alloys was compared in electrolytes with different pH values. Linear anodic and cyclic potentiodynamic polarisation methods and anodic current transient measurements have been conducted for the alloys and their constituents to analyze free corrosion, anodic dissolution and passive layer formation processes. Electrochemically treated alloy surfaces were characterized with scanning electron microscopy (SEM) and angle-resolved x-ray photoelectron spectroscopy (XPS). The electrochemical response of both alloys is in principal similar and is dominated by the Ni oxidation. In acidic solutions (pH 0.5 and 5) a slightly higher reactivity is detectable for the martensitic alloy which is mainly attributed to enhanced dissolution processes at the multiple twin boundaries. In ...

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It is necessary to measure strength and creep behavior to guarantee the safe and reliable usage of refractory alloys at extremely high temperatures. In the literature there is very little information available about the properties of Mo-Re alloys at temperatures higher than 1000 C. A special test facility has been designed and built for stress-rupture testing at very high temperatures (up to 3000 C) of refractory metals and alloys in inert atmospheres. - The stress-rupture strength as well as the creep behavior of molybdenum-rhenium alloys with rhenium contents between 41 and 51 wt.% have been determined at temperatures ranging from 1200 to 2000 C, and rupture times of up to 10 hours using this facility. Previous measurements of stress-rupture strength and creep behavior of pure rhenium have been compared with the measurement results of Mo-Re alloys. - The ...

International Nuclear Information System (INIS)

Experimental results of compatibility tests on ceramics-metal bonded structures performed under high heat flux conditions in splash test apparatus are reported. Emphasis is placed on results of the channel wall design and its critical operating conditions under MHD environment. The module design of one cold type and three semihot type insulators have been tested. These materials were Al_2O_3, Al_2MgO_4, LaAlO_4, MgO and Sialon ceramics. The methods of cold type ceramics-metal bonding structure were studied on Al_2O_3 and Spinel spray coating technology. The refractory metallizing and ceramics-metal graded structure manufactured by HIP technologies were applied to bonding between the MgO or LaAlO_4 and metallic cooling system. The Sialon non-bonding structure was tested with mechanical supported cooling system by shrinc fitting method. The results indicated that the bonding ...

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The effect of alloying Sn, Pb, As, Sb and P on the dezincification of commercial brass 60Cu-39Zn-1Pb has been investigated in 1% CuCl{sub 2} solution by immersion studies and electrochemical measurements. Specimens with a smooth surface finish exhibited more resistance to dezincification. Appreciable inhibitive effect on dezincification was observed for the 55Cu-40Zn-3Pb-2Sn brass composition. The galvanic coupling of lead phase with the matrix accelerated corrosion. To improve the dezincification resistance of the Sn containing brass, As, Sb and P were added at two different levels (0.05% and 0.1%). Brass of composition 48.95Cu-45Zn-5Pb-1Sn-0.05As was more resistant indicating the synergistic effect of Sn and As. The effect of 0.05 and 0.1% of arsenic addition with various concentrations of zinc was also studied. The alloy of composition 57.90Cu-40Zn-2Pb-0.1As showed better corrosion resistance than the alloy containing 1% ...

International Nuclear Information System (INIS)

TIMETAL reg-sign 21S, which has the nominal weight percent composition 15Mo, 3Al, 3Nb, and 0.2Si, is a metastable beta titanium alloy that offers a unique combination of high strength, good elevated temperature properties, and extraordinary environmental degradation resistance. It was developed by TIMET in 1988 as a foil matrix material for titanium metal matrix composites for the NASP, but currently monolithic applications are of much more significance. Among the alloy's unique properties are a high resistance to attack by commercial aircraft hydraulic fluids (commonly referred to as Skydrol trademark, which will be the term used in this paper) at all temperatures, which has led to its use in nacelle components on the Boeing 777 and other commercial aircraft. This paper provides an overview of the physical and mechanical properties of TIMETAL reg-sign 21S.

International Nuclear Information System (INIS)

The temperature dependence of the average magnetization direction in an Fe_8_0B_2_0 glassy alloy (METGLAS 2605) is investigated by Moessbauer spectroscopy. Moessbauer spectra were recorded between 77 K and 363 K using a conventional constant-acceleration Moessbauer spectrometer with 10 mCi "5"7Co in Pd source. The direction of the easy magnetization is found to be strongly terperature dependent and the out-of-plane component turned to be unusually large. Comparing the magnetic moments some similarities between the electronic structure of the glassy alloy and the Fe_2B and FeB intermetallic compounds are established and discussed. (Sz.N.Z.).

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Although magnesium is not attacked by hydrocarbons, it reacts vigorously with anhydrous methanol, raising concerns about the compatibility of the metal with methanol blend fuels. This paper describes the behavior of magnesium alloys in laboratory tests in static contact with methanol-containing fuels at 110/sup 0/F. Water in small concentrations (above 0.25% by weight of the methanol content) is shown to prevent the destructive attack of magnesium by these fuels. The required water content is well within the water tolerance of methanol-GTBA (gasoline grade tertiary-butyl alcohol) cosolvent fuel blends. Die cast AZ91HP shows greater resistance to methanol reaction than does AZ31B sheet.

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Supermetal with critical characteristics is under advanced investigation for further improvement of metal materials. Although iron is most frequently used as structural material among various metals, it should be used more carefully and effectively because of resource limitation and global environmental problem. It is essential to draw various excellent properties much more from iron and to improve recyclability. In particular, the best way to meet these requirements is achievement of more fine structure and higher purity. Since the lowest crystalline grain size is now limited to nearly 10{mu}m, metallic structure composed of grains below 1{mu}m is expected by mesoscopic control. Various methods have been studied to achieve ultra-fine crystalline structure, and study of precise heat treatment control and ultra-strength metallurgy is required. Heat treatment in magnetic field and layered structure by mechanical ...

International Nuclear Information System (INIS)

The effect of electron beam welding parameters on fusion zone (FZ) microstructure and porosity in a Ti-6.8 Al-3.42 Mo-1.9 Zr-0.21 Si alloy (Russian designation VT 9) has been investigated. It has been observed that the FZ grain width increased continuously with increase in heat input when the base metal was in the #beta# heat-treated condition, while in the #alpha# + #beta# heat-treated base metal welds, the FZ grain width increased only after a threshold energy input. The difference is attributed to both the weld thermal cycle and the pinning effect of equiaxed primary alpha on grain growth in the heat-affected zone (HAZ) of #alpha# + #beta# heat-treated base metal. Postweld heat treatment (PWHT) in the subtransus and supertransus regions did not alter the columnar grain morphology in the FZ, possibly due to the lack of enough driving force for the formation of new grains by the breaking up of the ...

British Library Electronic Table of Contents (United Kingdom)

The corrosion behavior of hard metals with VC and Cr3C2 grain growth inhibitors was investigated in alkaline solutions by electrochemical methods. The two inhibitors have opposite effects on the corrosion behavior: Cr3C2 significantly improves the corrosion behavior, whereas VC-containing alloys show a poor resistance. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) and analytical transmission electron microscopy (TEM) analyses of the distributions of Cr and V in the composite material, as well as in the surface layers formed during corrosion were employed to clarify the influence of these elements on the corrosion behavior. The measurements showed that VC is precipitated mostly along the WC/binder interface after the liquid-phase sintering process, while Cr3C2 is almost homogene...

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Advances in the theory and practice of stress corrosion cracking (SCC) are reviewed for the period 1965-1990. The proceedings of two landmark conferences are used as a basis for discussion: Ohio State University (1967) and Kohler, WI (1988). The discussion is developed around the following topics: metal-environment combinations, testing, fractography, metallurgical aspects, electrochemical aspects and crack chemistry, mechanisms, and prediction and mitigation. It is concluded that the main developments since 1967 are the recognition of the lack of specificity of SCC environments, the use of slow strain rate and fracture mechanics testing, quantitative SEM fractography, studies of grain boundary structure and compositions, transient electrochemistry of bare metal surfaces, measurement and modelling of crack chemistry, elaboration of several SCC models, including slip-dissolution and film induced cleavage, and mitigation by ...

International Nuclear Information System (INIS)

To suit the needs of development for manufacture VLSI, we started to investigate liquid metal ion sources (LMIS) and focused ion beam (FIB) in 1984. Many kinds of emitters viz. neddle type, co-axial type and capillary type of Ga and Au LMIS and three kinds of eutectic alloys LMIS (Au-Si, Au-Si-Be, Pd-Ni-Si-Be-B) have been tested. A program which can calculate focused ion guns has been written. Four kinds of foused ion guns have been operated, a fine beam with diametic 0.1 #mu#m is obtained. Using the FIB a scanning ion microscope has been constructed. Some tests of etching and self-developing of nitrocellulose are described. (author).

International Nuclear Information System (INIS)

The use of Auger electron spectroscopy (AES) combined with in situ sputter etching for revealing the metallurgy of the metal-semiconductor interface is presented. The physical basis, measurement techniques, and data interpretation for Auger analysis of thin-film structures are briefly reviewed. Results of a detailed study of an alloyed multilayered contact (Ni/Au-Ge) on n-type epitaxial GaAs are summarized to illustrate how electrical and metallurgical contact properties can be correlated using AES. In addition, the results of a study of the growth kinetics and chemical phase identification of palladium silicide on single-crystal Si is given, as well as the initial results of a study of aluminum-palladium silicide interaction at elevated temperature.

International Nuclear Information System (INIS)

The concept of nanocrystal conversion chemistry, which involves the use of pre-formed nanoparticles as templates for chemical transformation into derivative solids, has emerged as a powerful approach for designing the synthesis of complex nanocrystalline solids. The general strategy exploits established synthetic capabilities in simple nanocrystal systems and uses these nanocrystals as templates that help to define the composition, crystal structure, and morphology of product nanocrystals. This article highlights key examples of 'conversion chemistry' approaches to the synthesis of nanocrystalline solids using a variety of techniques, including galvanic replacement, diffusion, oxidation, and ion exchange. The discussion is organized according to classes of solids, highlighting the diverse target systems that are accessible using similar chemical concepts: metals, oxides, chalcogenides, phosphides, alloys, intermetallic compounds, sulfides, and ...

International Nuclear Information System (INIS)

The main compositions of iron-base amorphous self-fluxing alloy powders of 150 mesh, used in this work, are Fe, Cr, Ni, W, Mo, B, Si and C. The ranges of each element in at% are (65-70)Fe, (3-5)Cr, (2-4)Ni, (2-4)W, (1-2)Mo, (10-14)B, (4-7)Si and (2-3)C. The atomic ratio of metal-metalloid is about 80:20, so this alloy is abbreviated as M_8_0X_2_0. The material on which coatings were deposited is 1020 steel, austenitized for 1h at 880 C, water quenched, and tempered at 180 C for 1h. This heat treatment resulted in a low carbon martensite structure with a hardness of HRC35-45. After cleaning, shot blasting and preheating the steel to about 200 C, the authors sprayed a thin Ni-Al alloy layer of about 0.1--0.15mm in thickness onto the specimen by means of an oxygen-acetylene torch to provide better bonding of the coating with substrate. Then the M_8_0X_2_0 and M_8_0X_2_0+8%CeO_2 alloy ...

Energy Technology Data Exchange (ETDEWEB)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, MoO{sub 3}(m), in air and the hydroxide, MoO{sub 2}(OH){sub 2}, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report the authors present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800 C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic ...

International Nuclear Information System (INIS)

Molar heat capacities have been measured for VHsub(n) and NbHsub(n) with n up to 1.93 at temperatures between 1.5 and 16 K. The height of the peak in plots of the electronic specific heat, indicating superconductivity, diminishes with increasing hydrogen content in the #alpha# + #beta# two-phase region, and can be taken as a measure of the fractional amount of #alpha#-phase present (lever-rule). In NbHsub(n) accordingly, the two-phase region presumably extends up to n = approximately 0.9 at helium temperatures. No hydride phase, including VH_2 and NbH_2, showed superconductivity above 1.5 K. The measured #gamma#-coefficients of the V/H-alloys agree with APW band-structure calculations for V metal in the range 5 =< nsub(e) =< 7 of band electron concentration. They coincide with the #gamma#-coefficients of V/Cr-alloys reported in the literature. Hence VHsub(n) represents another example of the 'shifting bands' concept ...

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Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. De Laval nozzles offer an alternative method to the more conventional spray nozzle designs. Two applications are described: high-volume production of aluminum alloy strip, and the production of specialized tooling, such as injection molds and dies, for rapid prototyping.

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In most industrial processes operating at elevated temperatures, protective oxide layers perform a vital duty in protecting the underlying metallic alloys from process gases. Coal-fired combined cycle power generation systems present a number of process conditions in which the properties of the protective oxide layers are particularly important. This paper discusses two of these particular conditions: (1) `erosion/corrosion` of in-bed heat exchanger tubing and (2) thermal cycling of hot gas path components. For both these situations, the desirable properties of protective scales are outlined. The behaviour of scales in practice are highlighted. 33 refs., 6 figs., 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

As part of our effort to develop a semicontinuous PuO/sub 2/ reduction process, we are investigating promising materials for containing a 900/sup 0/C molten CaCl/sub 2/ . CaO chlorination reaction. We want the material to contain this reaction and to be reusable. We tested candidate materials in a simulated salt (no plutonium) using anhydrous HCl as the chlorinating agent. Data are presented on the performance of 36 metals and alloys, 9 ceramics, and 3 coatings.

Energy Technology Data Exchange (ETDEWEB)

The characteristics of the temperature dependence of the upper critical magnetic field, Hc2(T), of structurally inhomogeneous superconductors (e.g., ternary molybdenum chalcogenides, A-15 compounds, transition metal alloys, and amorphous films) are investigated analytically. The MWGH equation for Hc2(T) is generalized to the case of weakly inhomogeneous systems with a characteristic inhomogeneity scale much smaller than the effective coherence length. It is shown that an increase in the dispersion of the diffusion coefficient leads to an increase in the slope and width of the linear section of the Hc2(T) curve. 11 references.

Energy Technology Data Exchange (ETDEWEB)

The permeation of hydrogen through steam generator tubes at high temperatures ({approx} 300 degrees C) has been studied using an electrochemical technique. With this technique, hydrogen is generated on one side of the tube and monitored on the other side. The time for the hydrogen to reach the other side is used to determine the diffusion coefficient of hydrogen in the tube. Boundary conditions at the entry and exit sides have been investigated separately. Preliminary studies were performed on Stainless Steel 316 and Nickel Alloy 800 to better understand the influence of the solution chemistry on the electrochemical evolution of hydrogen. The surface phenomena effect and the trapping effect are discussed to account for differences observed in the permeation response. The hydrogen permeation through oxides at the exit side has been studied. Two nickel alloys (Alloy 800 and Alloy 600), materials widely ...

International Nuclear Information System (INIS)

The temperature dependences of the heat capacity of commercial titanium VT1-0 and alloys on its base, VT5 and VT5-1, have been derived in the temperature range of 4 to 290 K. For comparison, similar measurements have been conducted on pure titanium and specially prepared solid solutions on its base (Ti+3.7 at.% Al and Ti+0.82 at.% Sn). The measurement accuracy has been sufficient for comparing the results with calculation data. The obtained results are interpreted using the known concepts of the role of the mass of interstitial atoms and changes in the interatomic bond forces. It is shown that the phonon components of the molar heat capacities of solid solutions of Al in titanium have lower values in the entire temperature range, as compared to titanium. The corresponding differences are proportional to the Al concentrations. The lower molar heat capacity in the case of dissolution of Al is due to the low mass of the impurity atoms and stronger interatomic bonds in ...

International Nuclear Information System (INIS)

Ti-10V-2Fe-3Al is high strength, metastable beta titanium alloy developed by the Timet Division, Titanium Metals Corporation of America for enhanced forgeability and excellent mechanical property combinations, including deep hardening characteristics. Ti-10-2-3 has been the subject of intense thermomechanical processing (TMP) development and reduction to commercial practice for the full range of open die, closed-die and precision forged products utilized in aerospace and other applications. With commercially proven TMP, Ti-10-2-3 forgings provide a range of strength-fracture toughness combinations from 180 Ksi (1,240 MPa) minimum U.T.S. to 140 Ksi (965 MPa) minimum U.T.S with commensurate fracture toughness. With optimal TMP and these strength-toughness combinations, Ti-10-2-3 forgings are found provide superior smooth and notched fatigue properties critical to aerospace applications over incumbent alpha-beta alloys. The ...

Energy Technology Data Exchange (ETDEWEB)

A device for detecting neutrons includes a semi-insulated bulk semiconductor substrate having opposed polished surfaces. A blocking Schottky contact comprised of a series of metals such as Ti, Pt, Au, Ge, Pd, and Ni is formed on a first polished surface of the semiconductor substrate, while a low resistivity ("ohmic") contact comprised of metals such as Au, Ge, and Ni is formed on a second, opposed polished surface of the substrate. In one embodiment, n-type low resistivity pinout contacts comprised of an Au/Ge based eutectic alloy or multi-layered Pd/Ge/Ti/Au are also formed on the opposed polished surfaces and in contact with the Schottky and ohmic contacts. Disposed on the Schottky contact is a neutron reactive film, or coating, for detecting neutrons. The coating is comprised of a hydrogen rich polymer, such as a polyolefin or paraffin; lithium or lithium fluoride; or a heavy metal fissionable ...

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Particulate Reinforced Titanium matrix composites (PRTi) exhibit some improved specific mechanical properties in comparison with those of unreinforced titanium alloys as a result of the combination of the high strength and stiffness of ceramic particles with the toughness and damage tolerance provided by the metal matrix. The poor tribological properties of the titanium exclude titanium alloys from applications where wear resistance is required (brakes, rotating parts, sliding parts). The addition of ceramic particles improves the tribological properties of metals sensitive to adhesive and /or abrasive wear significantly. In this work, the wear resistance and the friction coefficient of Ti6Al-6V-2Sn reinforced with TiC particles and Ti6Al-4V reinforced with SiC particles (prototype material) are compared with the unreinforced alloys. Pin on disc and pin on ring tests were carried ...

Energy Technology Data Exchange (ETDEWEB)

Various methods for storing hydrogen have been examined in an effort to find ways to store hydrogen in increasingly smaller volumes with decreasing weight of the whole hydrogen storage system. Metal hydrides, in which hydrogen is chemically bound to a metal atom, are considered to be very promising candidates for hydrogen storage because they have high gravimetric and volumetric storage capacities. This study investigated the effect of different magnesium (Mg) and aluminium (Al) ratios on the absorption and desorption properties of thin films. Neutron reflectometry (NR) was used in this study to better understand the absorption and desorption properties of commercially promising hydrogen storage materials. The large negative scattering length of hydrogen atoms changes the reflectivity curve substantially, so that NR can determine the total amount of stored hydrogen as well as the hydrogen distribution along the film normal, with nanometer ...

Energy Technology Data Exchange (ETDEWEB)

Under the direction of the NASA-Glenn Research Center, the Edison Welding Institute (EWI) in Columbus, OH performed a series of non-fusion joining experiments to determine the feasibility of joining refractory metals or refractory metal alloys to Ni-based superalloys. Results, as reported by EWI, can be found in the project report for EWI Project 48819GTH (Attachment A, at the end of this document), dated October 10, 2005. The three joining methods used in this investigation were inertia welding, magnetic pulse welding, and electro-spark deposition joining. Five materials were used in these experiments: Mo-47Re, T-111, Hastelloy X, Mar M-247 (coarse-grained, 0.5 mm to several millimeter average grain size), and Mar M-247 (fine-grained, approximately 50 {micro}m average grain size). Several iterative trials of each material combination with each joining method were performed to determine the best practice joining method. ...

International Science & Technology Center (ISTC)

Determination of Special Molybdenum Alloys Optimal Structure Using the Cybernetic Method

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Low operating power and short cycle life are 2 of the main draw-backs of zinc-air batteries, despite the fact that various attempts have been made to develop improved zinc (Zn) anodes. This study investigated the performance of a Zn anode with a substantial addition of aluminium (Al). Rolled sheets of Zn-Al alloys of varying amounts of Zn and Al were used to prepare the anodes. Results of the study showed that the cells had higher open circuit voltages (OCV) values as well as a higher specific anode capacity. It was observed that specific anode capacity increased with higher current loading. The Zn{sub 59}Al{sub 41} and Zn{sub 67}Al{sub 33} sheets showed the highest performance with high OCV values of between 1540 and 1560 mV, as well as the largest specific anode capacity of 750-800 mAh per g at a discharge current of 200 mA. The 2-phase structure of the Zn-Al sheets was considered to be useful in reducing anode-passivation, and increasing anode-utilization due to ...

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Electrodeposited Zn alloys with Fe group metals are known to be more resistant than pure Zn. However, the role of the corrosion products on the corrosion inhibition is not considered up to date. The aim of the present work was to examine the composition of corrosion products, which form on the Zn and Zn alloy surfaces under atmospheric corrosion conditions up to 3 year of exposure, trying to correlate it with the differences in their corrosion resistance. Zn corrosion products have been characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Corrosion film composition was determined to depend on the sample exposure she, as well on the coating type. During the initial exposure stages oxide film was found to be the principal reaction product (XPS data), which in marine station consists from hydroxide phase exceptionally, while in urban one, contain up to 6-12 % of oxide. Succeeding corrosion ...

International Nuclear Information System (INIS)

Several metallurgical coatings have been developed that provide good tribological performances in high-temperature liquid sodium and that are relatively unaffected by neutron fluences to 6 X 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV). The coatings that have consistently provided the best tribological performance have been the nickel aluminide diffusion coatings created by the pack cementation process, chromium carbide or Tribaloy 700 trade mark (a nickel-base hardfacing alloy) applied by the detonation-gun process, and chromium carbide and other hardfacing alloy) applied by the detonation-gun process, and chromium carbide and other hardfacing materials applied by the electro-spark deposition process. The latter process is a relatively recent development for nuclear applications and is expected to find wide usage. Other coating processes, such as plasma-spray coating, sputtering, and chemical vapor deposition, were candidates for use on various ...

British Library Electronic Table of Contents (United Kingdom)

Zirconium and particularly Zr-2.5wt%Nb (Zr2.5Nb) alloy are useful for engineering bearing applications because they can be oxidized in air to form a hard surface ceramic. Oxidized zirconium (OxZr) due to its abrasion resistant ceramic surface and biocompatible substrate alloy has been used as a bearing surface in total joint arthroplasty for several years. OxZr is characterized by hard zirconium oxide (oxide) formed on Zr2.5Nb using one step thermal oxidation carried out in air. Because the oxide is only at the surface, the bulk material behaves like a metal, with high toughness. The oxide, furthermore, exhibits high adhesion to the substrate because of an oxygen-rich diffusion hardened zone (DHZ) interposing between the oxide and the substrate. In this study, we demonstrate a two step pro...

Energy Technology Data Exchange (ETDEWEB)

Field corrosion tests were conducted on eight single tube materials and two welded overlay materials in three typical Japanese waste incineration plants in an effort to develop new corrosion-resistant superheater tubes capable of functioning efficiently under temperature and pressure conditions of 500 C and 100 kgf/cm{sup 2}-g in high-efficiency waste-to-energy (WTE) plants. Austenitic alloys containing higher concentrations of chromium, nickel, and molybdenum [Cr + Ni + Mo] showed excellent corrosion-resistant properties, and the new alloys JHN24 and HR30M showed good corrosion resistance. Different corrosion rates found in each of the three plants were explained by differences in operating conditions, such as gas temperature, concentration of molten salts resulting from chlorine (Cl) content of deposits, heavy metal (zinc oxide [ZnO] + lead oxide [PbO]) content, etc. It was confirmed that the corrosion rate of materials ...

Energy Technology Data Exchange (ETDEWEB)

During 17 years since the start of operation of the first commercial LWR in Japan, many LWRs have experienced various corrosion damages, but the causes of them were clarified, and the counter-measures were executed effectively in actual plants, as the results, the cause of corrosion damage decreased remarkably, and now, the high rate of operation has become to be maintained. In this paper, the major cases of corrosion damage experienced in LWRs in Japan and foreign countries, the causes of them and the countermeasures, the problems of hereafter and so on are described. The corrosion damage of metallic materials in the environment of LWRs occurs in the parts in contact with high temperature, high pressure water and steam, such as stainless steel piping in the primary cooling system of BWRs, and nickel alloy heating tubes of steam generators, carbon steel feed water piping and zirconium alloy fuel cladding tubes in PWRs. ...

Science.gov (United States)

Experimental trials of autogenous deep penetration welding between dissimilar cast Ni-based superalloy K418 and alloy steel 42CrMo flat plates with 5.0 mm thickness were conducted using a 3 kW continuous wave (CW) Nd:YAG laser. The influences of laser output power, welding velocity and defocusing distance on the morphology, welding depth and width as well as quality of the welded seam were investigated. Results show that full keyhole welding is not formed on both K418 and 42CrMo side, simultaneously, due to the relatively low output power. Partial fusion is observed on the welded seam near 42CrMo side because of the large disparity of thermal physical and high-temperature mechanical properties of these two materials. The microhardness of the laser-welded joint was also examined and analyzed. It is suggested that applying negative defocusing in the range of Raylei length can increase the welding depth and improve the coupling efficiency of the laser materials ...

Science.gov (United States)

Feasibility of depositing continuous films of nano-porous alumino-silicates, primarily zeolites and MCM-41, on metallic and non-metallic substrates was examined with an aim to develop membranes for separation of gaseous mixtures and also for application as hydrogen storage material. Mesoporous silica was deposited in-side the pores of these nano-porous disks with an aim to develop membranes for selective separations. Our study involves supported zeolite film growth on substrates using in-situ hydrothermal synthesis. Faujasite, Silicalite and Mesoporous silica have been grown on various metallic and non-metallic supports. Metallic substrates used for film growth included anodized titanium, sodium hydroxide treated Titanium, Anodized aluminum, and sintered copper. A non-metallic substrate used was nano-porous aluminum oxide. Zeolite film growth was characterized ...

Energy Technology Data Exchange (ETDEWEB)

A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400/sup 0/C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures.

Energy Technology Data Exchange (ETDEWEB)

Photocurrent and capacitance measurements of semiconductor passive films formed on metals and alloys can be used to study the electronic properties and reveal indirect information about structure and composition. The current work used these techniques to investigate the electronic properties of the passive films formed on three austenitic stainless steels, types 304L, 316L and 254SMO, in borate. Evidence was found for the existence of a large number of localised mid bandgap states, consistent with amorphous oxides. However, the flat-band potentials of the austenitic stainless steel passive films were found to be independent of both composition and measuring frequency. The most credible explanation for the bandgap values determined from photocurrent measurements is that the passive films are formed as dual layers, iron oxide outer layer and chromium oxide inner layer. This model does not need to evoke the potential dependent bandgaps used by ...

International Nuclear Information System (INIS)

Nonrelativistic band calculations of Mattheiss for Nb and Petroff and Viswanathan for Mo are used to calculate the imaginary part epsilon_2 of the dielectric function for these metals. The structure resulting from interband transitions in the frequency range 0.1--0.5 Ry is found to give fairly good agreement with experiment. The calculation indicates that structure in epsilon_2 can arise from transitions away from symmetry points and lines in the Brillouin zone. The difficulty in distinguishing between the direct and indirect transition models for epsilon_2 is shown to arise from a lack of strong optical critical points. Predictions of the rigid-band model for the optical properties of Nb-Mo alloys are presented.

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The divertor collector plate in the INTOR reactor will be subjected to high heat, particle, and neutron fluxes, making it the most severely damaged torus component. The collector plate is composed of a protection plate, which is directly exposed to the particle flux, and a heat sink which provides support for the protection plate and carries the water coolant. The high-Z refractory metals have been considered for use as the protection plate material, and austenitic stainless steels and copper alloys have been considered as the heat sink material. Tungsten and Type 316 stainless steels have been selected for the protection plate and heat sink, respectively. The protection plate has a sputtering lifetime of 1.75 y at a 50% duty factor, while the heat sink is expected to last the lifetime of the reactor.

Energy Technology Data Exchange (ETDEWEB)

A new interest in magnesium alloys has arisen since light-weight constructions have become more and more attractive. Products that are currently available are mostly cast, forged, and extruded. A cost-effective production of sheet metals will render new perspectives in the design of light-weight constructions. The development of new casting technologies like thin slab casting or strip casting with an in-line rolling process is expected to result in a shorter processing time featuring a high potential of saving energy, time, and cost. Particular attention is paid to the casting process parameters such as casting speed and solidification speed. This article deals with some aspects of a magnesium-adapted single-belt caster. Results of casting experiments and material examination are shown as well as some advices given concerning safety and handling of liquid magnesium. (orig.)

British Library Electronic Table of Contents (United Kingdom)

Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS) has been proposed several years ago as an approach for quantitative analysis of Laser-Induced Breakdown Spectroscopy spectra. Recently developed refinement of the spectral processing method is described in the present work. Accurate quantitative results have been demonstrated for several metallic alloys. However, the degree of accuracy that can be achieved with Calibration-Free Laser-Induced Breakdown Spectroscopy analysis of generic samples still needs to be thoroughly investigated. The authors have undertaken a systematic study of errors and biasing factors affecting the calculation in the Calibration-Free Laser-Induced Breakdown Spectroscopy spectra processing. These factors may be classified in three main groups: 1) experi...

International Nuclear Information System (INIS)

Liquid metal ion sources (LMISs) with Ga as ion species are widely used in focused ion beam (FIB) technology for micromachining and surface treatment on the sub-micron and nano-scale. Key features of a LMIS for investigating mechanical properties and 3D-microfabrication of materials are long life-time, high brightness, stable ion current and a highly effective milling ability for the material to be modified. In order to increase the material removal rate, heavier ions than Ga and their clusters should be applied. Bismuth (Bi) is the heaviest, non-radio-active element in the periodic table, is non-toxic and exhibits a low melting point. We have thus produced a long-life (about 1000 h) Bi LMIS with a good beam performance, applicable in any FIB system. Since Bi is the only element in this source, it is not necessary to separate it from other ions by a mass filter. Investigation of the sputtering rate of NiTi shape memory alloys using Ga and Bi ...

Science.gov (United States)

... MOLYBDENUM ALLOY GUN BARREL LINERS o0 in ... NEW POWDER TECHNOLOGIES FOR MOLYBDENUM ALLOY GUN BARREL LINERS ...

International Nuclear Information System (INIS)

... filters molybdenum alloys production sulfuric acid alloys chemical reactions ...

Energy Technology Data Exchange (ETDEWEB)

Exploratory experiments of laser welding cast Ni-based superalloy K418 turbo disk and alloy steel 42CrMo shaft were conducted. Microstructure of the welded seam was characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), energy-dispersive spectrometer (EDS). Mechanical properties of the welded seam were evaluated by microhardness and tensile strength testing. The corresponding mechanisms were discussed in detail. Results showed that the laser-welded seam had non-equilibrium solidified microstructures consisting of FeCr{sub 0.29}Ni{sub 0.16}C{sub 0.06} austenite solid solution dendrites as the dominant and some fine and dispersed Ni{sub 3}Al {gamma}' phase and Laves particles as well as little amount of MC short stick or particle-like carbides distributed in the interdendritic regions. The average microhardness of the welded seam was relatively uniform and lower than that of the base metal ...

Energy Technology Data Exchange (ETDEWEB)

In order to develop new corrosion resistant superheater tubes capable of functioning efficiency under temperature and pressure conditions of 500 C and 100 ata used in high efficient waste-to-energy (WTE) plants, field corrosion tests were conducted on eight single tube materials and two welded overlay materials at metal temperatures of 450 C and 550 C for 700 and 3,000 hours, respectively, in three typical japanese waste incineration plants. The test results indicate that austenitic alloys containing higher concentrations of [Cr + Ni + Mo] show excellent corrosion resistant properties and new alloys of JHN24 and HR30M have good corrosion resistance. The different corrosion rate found for each of the three plants could be explained by differences in the severity of corrosion factors, such as, gas temperature, concentration of molten salts due to Cl content of deposits, and heavy metal [ZnO + PbO] content ...

International Nuclear Information System (INIS)

Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS) has been proposed several years ago as an approach for quantitative analysis of Laser-Induced Breakdown Spectroscopy spectra. Recently developed refinement of the spectral processing method is described in the present work. Accurate quantitative results have been demonstrated for several metallic alloys. However, the degree of accuracy that can be achieved with Calibration-Free Laser-Induced Breakdown Spectroscopy analysis of generic samples still needs to be thoroughly investigated. The authors have undertaken a systematic study of errors and biasing factors affecting the calculation in the Calibration-Free Laser-Induced Breakdown Spectroscopy spectra processing. These factors may be classified in three main groups: 1) experimental aberrations (intensity fluctuations and inaccuracy in the correction for spectral efficiency of a detection system), 2) inaccuracy in theoretical ...

Energy Technology Data Exchange (ETDEWEB)

The 1977 version of the Simpson-Puls-Dutton model appears to be the most amenable with respect to utilizing known or readily estimated quantities. The Pardee-Paton model requires extensive calculations involving estimated quantities. Recent observations by Koike and Suzuki on vanadium support the general assumption that crack growth in hydride forming metals is determined by the rate of hydride formation, and their hydrogen atmosphere-displacive transformation model is of potential interest in explaining hydrogen embrittlement in ferrous alloys as well as hydride formers. The discontinuous nature of cracking due to hydrogen embrittlement appears to depend very strongly on localized stress intensities, thereby pointing to the role of microstructure in influencing crack initiation, fracture mode and crack path. The initiation of hydrogen induced failures over relatively short periods of time can be characterized with fair reliability using ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Science.gov (United States)

... Title : Effect of Yttrium on the Microstructure of Titanium Alloys,. ... The yttrium was added in the melting stage as an oxide or in the elemental form. ...

International Nuclear Information System (INIS)

The importance that must be attached to the phenomenon of stress corrosion cracking of austenitic alloys is emphasized. The relation between chemical composition of various alloys and their sensitivity to cracking is shown with particular reference to the behaviour of Alloy 800. The different effects of alkaline anc chloride environments are discussed. Studies are reported of the general corrosion of Alloy 800 and other alloys in an environment representative of the primary coolant of PWR reactors; and of the behaviour of various alloys (including Alloy 800) in the conditions envisaged for their use for steam generators with superheat up to about 550 deg.C. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

Metal hydrode stores are used as fuel tanks in vehicles or as stationary stores of high-purity hydrogen. Equilibrium isotherms at low pessures were measured in order to validate the laws of Henry or Sievert for hydrogen uptake of the alloy Ti{sub 0.98}Zr{sub 0.02}V{sub 0.43}Fe{sub 0.09}Cr{sub 0.05}Mn{sub 1.5} (patented by Daimler Benz AG, code DB5800). The laws were to provide information on whether hydrogen uptake is atomic or molecular and on the conditions in which isothermal measurements are possible. (orig.) [Deutsch] Metallhydridspeicher werden als Kraftstofftank in Fahrzeuge oder als stationaere Speicher zur Bereitstellung von Reinstwasserstoff verwendet. Fuer diese Arbeit wurden die Gleichgewichtsisothermen bei kleinen Druecken vermessen, um die Gesetze von HENRY oder SIEVERT fuer die Wasserstoffaufnahme in der Legierung Ti{sub 0.98}Zr{sub 0.02}V{sub 0.43}Fe{sub 0.09}Cr{sub 0.05}Mn{sub 1.5} zu pruefen. Anhand dieser Gesetze ist zu ...

Energy Technology Data Exchange (ETDEWEB)

Corrosion probes are being developed and combined with an existing measurement technology to provide a tool for assessing the extent of corrosion of metallic materials on the fireside in coal-fired boilers. The successful development of this technology will provide power plant operators the ability to (1) accurately monitor metal loss in critical regions of the boiler, such as waterwalls, superheaters, and reheaters; and (2) use corrosion rates as process variables. In the former, corrosion data could be used to schedule maintenance periods and in the later, processes can be altered to decrease corrosion rates. The research approach involves laboratory research in simulated environments that will lead to field tests of corrosion probes in coal-fired boilers. Laboratory research has already shown that electrochemically-measured corrosion rates for ash-covered metals are similar to actual mass loss corrosion rates. ...

International Nuclear Information System (INIS)

Due to the well-establish corrosion problems of Alloy 600 as a steam-generator material and the subsequent focus on thermally treated (TT) Alloy 690 and Alloy 800 as alternative materials, a systematic analysis of the corrosion behavior of these two latter alloys is warranted. Corrosion test results for Alloys 690 TT and 800 were collected and organized in the form of corrosion mode diagrams. Selected data for mill annealed (MA) Alloy 600 were also included for reference. The corrosion mode diagrams correlate the modes of corrosion degradation observed in tests as functions of the environment pH and electrochemical potential (ECP). The diagrams confirm that Alloys 690TT shows some susceptibility in caustic environments, and Alloy 800 shows susceptibility in both caustic and highly acidic environments. (authors). 6 figs., ...

International Science & Technology Center (ISTC)

Metal Matrix Composites on the Basis of Nano-Materials

Energy Technology Data Exchange (ETDEWEB)

Mott-Schottky (M-S) analysis is an effective approach to investigate the electronic property of passive films of metals, and it is well suitable for the passive film with single space charge capacitance. But there is no proper method to analyze the C{sub sc}{sup -2} vs. V{sub m} plots of passive films with several space charge capacitances in series connection, such as bipolar passive films. In this paper, the relationship between the space charge capacitance of the bipolar passive film and the applied potential was deduced and the features of corresponding plots were given out simultaneously. Accordingly, a non-linear fitting method was presented to analyze the C{sub sc}{sup -2} vs. V{sub m} plots of bipolar passive films. Then the method was used to study the semiconductor characteristics of bipolar passive films formed on the surface of Nickel base alloy after being corroded in the environments with high temperatures and high partial ...

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By using a plasma nitriding procedure at the PUPR Mirror Cusp Plasma machine, surface hardness is increased in 302/304-type stainless steel samples by exposing them to high-ion-density plasma at high vacuum. This method successfully dopes the surface of the material with strengthening nitrogen ions, without the use of chemical procedures that sacrifice the resistance to corrosion of the given material. A 500 V negative bias is placed on the sample exposed to the nitrogen plasma, where high-energy ions are therefore attracted and immersed into the metallic matrix microns into the surface of the stainless steel. This potential maintains a constant surface temperature at approximately 800 deg. C. The plasma parameters including ion density and plasma temperature were diagnosed using single Langmuir probes. The stainless steel samples were then tested using scanning electron microscopy (SEM), and Vickers micro-hardness testing to determine the increment in the surface ...

Energy Technology Data Exchange (ETDEWEB)

This paper introduces marketability and parts application of PBT in the automotive field. Based on the pursuits in automobiles of weight reduction as measures to improve engine performance, drive performance, and fuel consumption, as well as trends of higher class car orientation, market expansion is expected on engineering resins including PBT. Adoption of PBT/polycarbonate (PC)-based alloy resins is on increase for use in external car parts because of the chemical resistance in PBT, low-temperature shock resistance and appearance of PC. Substitution from Nylon resin in connector application is progressing rapidly because of problems in dimensional stability and compound noise. Air bag sensor parts need to be free of maloperation due to contamination and corrosion in metal contacts caused from gases generated from formed parts, hence development of resins of low gas generation grade is wanted. Valves for exhaust control require ...

Energy Technology Data Exchange (ETDEWEB)

The bullet evidence in the JFK assassination investigation was reexamined from metallurgical and statistical standpoints. The questioned specimens are comprised of soft lead, possibly from full-metal-jacketed Mannlicher-Carcano, 6.5-mm ammunition. During lead refining, contaminant elements are removed to specified levels for a desired alloy or composition. Microsegregation of trace and minor elements during lead casting and processing can account for the experimental variabilities measured in various evidentiary and comparison samples by laboratory analysts. Thus, elevated concentrations of antimony and copper at crystallographic grain boundaries, the widely varying sizes of grains in Mannlicher-Carcano bullet lead, and the 5-60 mg bullet samples analyzed for assassination intelligence effectively resulted in operational sampling error for the analyses. This deficiency was not considered in the original data interpretation and resulted in an ...

Energy Technology Data Exchange (ETDEWEB)

Al{sub x}Ga{sub 1{minus}x}P layers (0 {le} x {le} 0.7), with thicknesses of {ge}1 {micro}m were grown on Si (100) wafers by metal-organic molecular beam epitaxy (MOMBE) at 450 C. Transmission electron micrographs of the single crystal films revealed that the microstructure contains stacking faults and microtwins especially near the interface as well as both threading and misfit dislocations. Hardness and elastic modulus were measured using a Nanotest 500 indenter, which can probe the film properties without influence from the substrate. The hardness H varies linearly according to (11.8 {minus} 2.3x) GPa. The absence of alloy hardening is due to the fact that there is no difference in atomic size of Al and Ga. The indentation modulus E/(1{minus}v{sup 2}) decreases monotonically from 136 GPa for GaP to 129 GPa for Al{sub 0.7}Ga{sub 0.3}P and bows only slightly (about 2%) below the straight line of linear interpolation.

Energy Technology Data Exchange (ETDEWEB)

"What happens to conventional metals near the ocean?" you might ask the workers who are repairing the water tower at Jones Beach. They will tell you that both the tower's steel framework and copper roof show extensive corrosion from the salty air. To power future generations of cars, homes, utility plants, and even particle accelerators, unprecedented levels of efficiency will be needed. Such efficiency will require new unconventional alloys and composite materials that can also withstand high temperatures, intense radiation fluxes, high stresses, and other extreme conditions in highly corrosive environments that accelerate the aging and weakening of materials, as salty air weakens steel and copper. During the lecture, Simos will discuss the demands of next-generation energy systems and focus on the extreme conditions that materials used in these systems will perform under. He will also explain Brookhaven Lab's role in past, ...

Energy Technology Data Exchange (ETDEWEB)

The passive films formed on iron metal, alloys or stainless steel are extremely thin oxides or hydroxides and possess the properties of high chemical stability in the environment. These films show characteristics interested both electrical as well as electrochemical point of view due to the thin thickness of the films. Auger Electron Spectroscopy, X-ray Photoelectron spectroscopy and so on which are the conventional electrochemical measurement methods or the surface analysis methods are used for the analysis and evaluation of these films, however, at present, the application of research technique focusing the superconductor characteristics of the films are tried. Although, the potential modulation reflection spectroscopy method has merits like possibility of in-situ measurement, high precision, possibility of stable analysis even for extremely thin film and so forth, it has also demerits like difficulty to response the potential modulation of ...

Energy Technology Data Exchange (ETDEWEB)

Corrosion in drilling and well stimulation is described in relation to acid corrosion inhibition, acid inhibitors, acetylenic inhibitors, synergistic blends, metallurgy, wellbore tubulars, coiled tubing, and high alloy tubular materials. Acidizing is a procedure for stimulating oil and gas wells. Factors that have an important influence on the reaction rate and the way in which acid reacts with rock include temperature, acid concentration, acid volume, injection velocity, acid viscosity, and fluid loss properties of the formation. The cost of drill pipe failures are $1 per fot of hole drilled, which is a significant fraction of the drilling cost. Steps in a test procedure are listed, as well as factors which determine the extent of acid corrosion in a given situation including acid type and strength, metal type, temperature, contact time; pressure, and volume/surface area ratio. Underbalanced drilling is a method for completing oil and gas ...

International Nuclear Information System (INIS)

Rapid corrosion of PWR steam generator carbon steel support structures and consequential denting of steam generator tubes led to considerable investigation of the mechanism of corrosion and for palliatives. The basic mechanism is now fairly well understood. Chloride present in the boiler feedwater from condenser leakage is concentrated in the support plate crevice as a result of the superheat present. This leads to the formation of a low pH acid ferrous chloride environment either through the hydrolysis of a weak base chloride such as MgCl_2 or the combined action of a neutral chloride with an oxidizing agent. Rapid attack of the carbon steel ensues with the Fe_3O_4 corrosion product forming at the metal/oxide interface. This oxide has a volume approximately twice that of the steel consumed and thus eventually fills the crevice between the tube and the support plate. Oxide growth continues leading to compression of the Alloy 600 primary tube ...

International Nuclear Information System (INIS)

The aim of this paper is offering a critical review of Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS), the approach of multi-elemental quantitative analysis of LIBS spectra, based on the measurement of line intensities and plasma properties (plasma electron density and temperature) and on the assumption of a Boltzmann population of excited levels, which does not require the use of calibration curves or matrix-matched standards. The first part of this review focuses on the applications of the CF-LIBS method. Quantitative results reported in the literature, obtained in the analysis of various materials and in a wide range of experimental conditions, are summarized, with a special emphasis on the departure from nominal composition values. The second part is a discussion of the simplifying assumptions which lie at the basis of the CF-LIBS algorithm (stoichiometric ablation and complete atomization, thermal equilibrium, homogeneous plasma, thin radiation, detection of all ...

Energy Technology Data Exchange (ETDEWEB)

The processing characteristics, tensile properties, and oxidation response of two Nb-Ti-Al-Cr alloys were investigated. One creep test at 650 C and 172 MPa was conducted on the base alloy, which contained 40Nb-40Ti-10Al-10Cr. A second alloy was modified with 0.11 at.% C and 0.07 at.% Y. Alloys were arc melted in a chamber backfilled with argon, drop cast into a water-cooled copper mold, and cold rolled to obtain a 0.8-mm sheet. The sheet was annealed at 1,100 C for 0.5 h. Longitudinal tensile specimens and oxidation specimens were obtained for both the base alloy and the modified alloy. Tensile properties were obtained for the base alloy at room temperature, 400, 600, 700, 800, 900, and 1,000 C and for the modified alloy at room temperature, 400, 600, 700, and 800 C. Oxidation tests the base alloy ...

Energy Technology Data Exchange (ETDEWEB)

The use of nickel alloys in Flue Gas Desulfurization (FGD) applications is described. Recently, nickel alloys 625 and C-276 have been clad to carbon steel plate. Production and properties of the clad plate are reviewed and a brief discussion is presented on production, fabrication and welding. Laboratory and field corrosion tests in SO/sub 2/ scrubber environments suggest that alloy 625 and C-276 clad steel plates are as corrosion resistant as the solid alloy plate.

International Nuclear Information System (INIS)

The relationships of hydrogen alloyed #beta#-titanium alloy deformation behaviour to its microstructure and texture are investigated. It is shown that plasticity increases and strain induced texture changes at low hydrogen contents (0.1-0.2 mass %). Possible mechanisms responsible for specific features of #beta#-Ti alloy deformation are discussed. The study is made using alloy VT35 doped with hydrogen

International Nuclear Information System (INIS)

In analysis of hydrogen in metals and alloys by SIMS, control of the hydrogen blank mainly due to residual gases is a persistent problem. Contrarity, this problem becomes less important in case of deuterium analysis. The prescribed amounts of deuterium were introduced into a pure titanium and a beta-titanium alloy (Ti- 6.6wt%Fe) by the gas reaction method. Intensities of the various secondary ions sputtered from each sample were measured by the Hitachi Ion Microanalyzer with primary ions of Ar"+. Energy distributions of the various secondary ion species were measured with the energy window of about 15eV width. The effects of oxygen gas pressure in the target chamber and the bulk deuterium concentration on the shape of energy distribution curves are discussed. For all samples, intensity of D"- ions is higher than that of D"+ ions, especially at higher energy ranges. With increasing the deuterium concentration: a) intensities ...

International Nuclear Information System (INIS)

The micro-arrangement of hydrogen atoms and the electronic properties of hydrides LaNi_5H_x (0.5, 1.0, 2.0, 3.0, 4.0, 5.0, 6.0, 7.0) have been systematically investigated by means of the density functional theory using the full-potential linearized augmented plane wave (FLAPW) method with the generalized gradient approximation (GGA). The calculated results indicate that H atoms prefer to occupy the 12n site in the #alpha# solid solution phase. For the #beta# phase, once the first H atom locates in the basal plane (12n site), and because it is difficult for the second H atom to still locate in the 12n site, the second H atom would prefer to occupy the middle plane site (6m site). When the number of H atoms increases from 3 to 5, they would occupy the other 12n and 6m sites by turns. Furthermore, our optimized data indicate that the structures P3 and P63mc are the most favorable structures of LaNi_5H_6 and LaNi_5H_7, respectively. From the analysis of the densities of states and charge ...

International Nuclear Information System (INIS)

Three model boilers, manufactured to simulate full-size tube sheet crevices, were tested with various secondary side environments. The first was faulted with organics representative of the decomposition of humic acid. The second was faulted with sodium carbonate and sodium hydroxide, while the third was faulted with sodium sulfate and sodium hydroxide. Each model contained seven tubes, which included Alloy 600 in the mill-annealed (MA) and thermally-treated (TT) conditions and Alloy 690 in the thermally-treated condition. Two models contained Alloy 800 tubes in the mill-annealed condition and one had Alloy 800 in the mill-annealed/cold-worked/glass-bead-peened condition. Two different sizes of tubesheet crevices were used in all model boilers. In the organics-faulted boiler, tubes of Alloy 600MA, Alloy 690TT and Alloy 800MA experienced no ...

Energy Technology Data Exchange (ETDEWEB)

AZ31 and experimental ZMA611 alloys were strip cast into 2 mm thick strips. The as-cast AZ31 alloy strip consists of columnar dendrites. On the other hand, as-cast ZMA611 alloy strip shows equiaxed dendritic structure through the thickness of strip. These alloys were subjected to various thermomechanical treatments and their tensile properties were evaluated. Strip cast AZ31 alloy in H24 condition has equivalent yield and tensile strengths with similar ductility compared to commercial ingot cast AZ31-H24 alloy, indicating that strip casting is a viable process for the fabrication of Mg alloy strips. The ZMA611 alloy has a large volume fraction of fine dispersoid particles in the microstructure, resulting from the beneficial effect of strip casting on microstructural refinement. It has been shown that the ZMA611 ...

Energy Technology Data Exchange (ETDEWEB)

Resistance of ALLOY 800 as a PWR/SG tubings to IGC/IGSCC and Ni, Co release into high temperature water was evaluated as compared with ALLOYs 600 and 690. The study to improve the resistance to IGSCC and general corrosion was also made. From the results, ALLOY 800 was evaluated to be the most reliable among the high Ni alloys tested. In addition, the alloy would obtain further reliability in IGSCC and general corrosion resistance by the combined addition of Ti and Nb, and the prior oxidation treatments, respectively. (author).

International Nuclear Information System (INIS)

Prostate and cervical cancer patients are often treated with external X-ray beams of bi-lateral incidence. Such treatment may incur some dose effect that cannot be predicted precisely in commercial treatment planning systems (TPS) for patients having undergone total hip replacement. This study performs a Monte Carlo (MC) simulation and an analytical calculation (convolution superposition algorithm which is implemented in ADAC TPS) of a 6 MV, 5x5 cm"2 X-ray beam incident into water with the existence of hip prosthesis, e.g. Ti6Al4V and CoCrMo alloy. The results indicate that ADAC TPS cannot precisely account for the scatter and backscatter radiation that a metal hip prosthesis causes. For percent depth dose (PDD) curves, the maximum underdosage of ADAC TPS up to 5 mm above the interface between dense material and water is 5%, 20% and 27% for PDD_B_o_n_e, PDD_T_i and PDD_C_o, respectively. The dose re-buildup, which occurs behind the hip region, ...

International Nuclear Information System (INIS)

Al, Au, Ti/Al and Ti/Au contacts were prepared on n-GaN and annealed up to 900 deg. C. The structure, phase and morphology were studied by cross-sectional transmission and scanning electron microscopy as well as by X-ray diffraction (XRD), the electrical behaviour by current-voltage measurements. It was obtained that annealing resulted in interdiffusion, lateral diffusion along the surface, alloying and bowling up of the metal layers. The current-voltage characteristics of as-deposited Al and Ti/Al contacts were linear, while the Au and Ti/Au contacts exhibited rectifying behaviour. Except the Ti/Au contact which became linear, the contacts degraded during heat treatment at 900 deg. C. The surface of Au and Ti/Au contacts annealed at 900 deg. C have shown fractal-like structures revealed by scanning electron microscopy. Transmission electron microscopy and XRD investigations of the Ti/Au contact revealed that Au diffused into the n-GaN layer at ...

Energy Technology Data Exchange (ETDEWEB)

Experiments of autogenous laser full penetration welding between dissimilar cast Ni-based superalloy K418 and alloy steel 42CrMo flat plates with 3.5 mm thickness were conducted using a 3 kW continuous wave (CW) Nd:YAG laser. The influences of laser welding velocity, flow rate of side-blow shielding gas, defocusing distance were investigated. Microstructure of the welded seam was characterized by optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction (XRD) and energy dispersive spectrometer (EDS). Mechanical properties of the welded seam were evaluated by microhardness and tensile strength testing. Results show that high quality full penetration laser-welded joint can be obtained by optimizing the welding velocity, flow rate of shielding gas and defocusing distance. The laser-welded seam have non-equilibrium solidified microstructures consisting of {gamma}-FeCr{sub 0.29}Ni{sub 0.16}C{sub 0.06} austenite solid solution dendrites as the ...

Science.gov (United States)

Experiments of autogenous laser full penetration welding between dissimilar cast Ni-based superalloy K418 and alloy steel 42CrMo flat plates with 3.5 mm thickness were conducted using a 3 kW continuous wave (CW) Nd:YAG laser. The influences of laser welding velocity, flow rate of side-blow shielding gas, defocusing distance were investigated. Microstructure of the welded seam was characterized by optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction (XRD) and energy dispersive spectrometer (EDS). Mechanical properties of the welded seam were evaluated by microhardness and tensile strength testing. Results show that high quality full penetration laser-welded joint can be obtained by optimizing the welding velocity, flow rate of shielding gas and defocusing distance. The laser-welded seam have non-equilibrium solidified microstructures consisting of ?-FeCr0.29Ni0.16C0.06 austenite solid solution dendrites as the dominant and very small ...

Science.gov (United States)

... alloys--Lanthanum-- Magnesium--Magnasium &11oy8--Hagn*31Uft compounds--Manxganese--Manganes. alloys-- Mercury ...

Science.gov (United States)

Hilled Bend Spechene of an Alpha-Beta Titanium Alloy. Ti-6M14V. ..... The all beta titanium alloy was nllled from both sides; only the edges were taped. ...

Energy Technology Data Exchange (ETDEWEB)

The nickel-rich superalloys Alloy 600 and Alloy 800 have been corroded in mildly alkaline deuterated aqueous conditions typical of secondary coolant circuits in a nuclear power station. The oxide films and substrates of these alloys have been analysed by imaging SIMS depth profiling, which makes it possible to describe elemental distribution in all three dimensions. The measurement of the distribution of the secondary ions NiO[sup -], FeO[sup -] and CrO[sup -] appears useful for detailing the behaviour of nickel, iron and chromium within oxidized phases. The measurement of D[sup -] distribution outlines the extent of oxide hydration. For Alloy 800, evidence of sodium migration into the grain boundaries of the alloy substrate is found. For Alloy 600, no grain boundary sodium ingress can be identified under comparable corrosion conditions. (author).

Energy Technology Data Exchange (ETDEWEB)

The resistance to pitting of a Fe-17%Cr alloy in Cl[sup [minus

International Nuclear Information System (INIS)

The effect of various hydrogen concentrations on the crystal lattice period and the hardness of titanium alloy was examined, the alloy containing about 16 at.% Mo (27.5 wt. % Mo) and having #beta# structure. The peculiar features of the mechanism of plastic deformation of the alloy were studied after adding hydrogen to it. A dependence of the crystal lattice period on the concentration of hydrogen was obtained for TixMoxH_2 alloy. It has been established that the hardness of the Ti-Mo alloy does not change when hydrogen is added to it. The presence of hydrogen introduces changes into the mechanism of deformation of #beta#-titanium alloy. The configuration of the inverse pole figures after rolling proves that the transverse slip process in an alloy with hydrogen is hampered, and that the coplanar slip process is developing in it.

Science.gov (United States)

... CLOSURE DURING HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY (PREPRINT) ... HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY ...

Science.gov (United States)

... Accession Number : ADD336001. Title : Development of a FeCoNb Alloy to be used in Eddy Current Probes for Testing Ferromagnetic Tubes,. ...