Energy Technology Data Exchange (ETDEWEB)

In response to a request from the International Chemical Workers Union, Akron, Ohio, an investigation was made into possible hazardous working conditions at two American Smelting and Refining Company (SIC-1031) zinc mines (New Market and Young) in Mascot, Tennessee. Specifically, exposures to asbestos (1332214), silica (14808607), and diesel emissions were determined. At both mines overexposures were found to nitrogen-dioxide (10102440) (NO2) and coal-tar pitch volatiles. Twenty-four percent of the NO2 measurements taken were above the NIOSH recommended ceiling of 1 part per million (ppm), but none exceeded the Mine Safety and Health Administration's (MSHA) ceiling of 5ppm. Exposure to diesel particulates ranged from 0.24 to 1.06mg/cu m. None of the 52 respirable dust samples collected exceeded the calculated MSHA limits for free silica exposure. A medical evaluation was offered and 83 of the 400 current employees ...

Science.gov (United States)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and ...

Energy Technology Data Exchange (ETDEWEB)

The authors have examined the pyrolysis of Argonne samples of Wyodak and Illinois No. 6 coal in argon, undecane, Tetralin, and water. The effects of the pyrolysis on individual particles of coal were monitored visually in a cell with diamond windows capable of operation to temperature and pressures in excess of 500{degrees}C and 3000 psi. The changes in the particles from ambient to 460{degrees}C were recorded in real time on video tape, and images were then taken from the tape record and analyzed. The study showed that in argon both coals developed tars at 350{degrees}-370{degrees}C. The tars then quickly evaporated, leaving core particles remarkably similar in size and shape to the initial particles. These observations suggest that coal does not melt nor become fully liquid when heated. Nor does the softened coal undergo crosslinking to generate coke. Rather the simple loss of volatiles leaves behind the core residue as ...

Energy Technology Data Exchange (ETDEWEB)

Conversion of biomass into producer gas by thermal gasification broadens the scope of biomass applications. Usually, tar has to be removed from the producer gas. Tar recycling within the gasification process may solve the associated waste problem and increase the system efficiency, provided tar is broken down under gasification conditions. We present results of tar recycling experiments at a Circulating Fluidised Bed gasifier. At 830{sup o}C, from each of 15 main tar compounds 70-80% are broken down. Continuous recycling of tar would increase the tar content in raw producer gas by 50% at most and save about 3% fuel input. 10 refs., 3 figs., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

The elemental and mineralogical variation in a self-burning coal seam from Coalspur, Alberta, is determined using instrumental neutron activation analysis (INAA) and x-ray diffraction (XRD). The elemental variation in the coal seam is related to temperatures in the various alteration zones, i.e., oxidation, combustion, or carbonization and nature of elements. Mobilization of elements is greatest for As, Br, Cl, Mo, N, S, and Sb. Some of these elements are released to the atmosphere, as evident by the presence of orthorombic sulfur crystals on the surface or in vents at the top of the burning seam or saturation of oxidation char by volatile matter (tar). Whewellite (CaC{sub 2}O{sub 4}, H{sub 2}O) is the only Ca-bearing mineral found in the cooler area of the coal seam. Decomposition of this mineral, coupled with the presence of SO{sub 2} formed by reaction of organic sulfur with O{sub 2} in combustion, resulted in formation of a relatively high ...

Energy Technology Data Exchange (ETDEWEB)

Short communication.

Energy Technology Data Exchange (ETDEWEB)

With an objective to learn mechanisms in low-rank coal reformation processes, change of properties on coal surface was discussed. Difficulty in handling low-rank coal is attributed to large intrinsic water content. Since it contains highly volatile components, it has a danger of spontaneous ignition. The hot water drying (HWD) method was used for reformation. Coal which has been dry-pulverized to a grain size of 1 mm or smaller was mixed with water to make slurry, heated in an autoclave, cooled, filtered, and dried in vacuum. The HWD applied to Loy Yang and Yallourn coals resulted in rapid rise in pressure starting from about 250{degree}C. Water content (ANA value) absorbed into the coal has decreased largely, with the surface made hydrophobic effectively due to high temperature and pressure. Hydroxyl group and carbonyl group contents in the coal have decreased largely with rising reformation treatment temperature (according to FT-IR measurement). Specific surface ...

Energy Technology Data Exchange (ETDEWEB)

The desirable performance attributes of a vertical axis wind turbine (VAWT) include high starting torque, high peak efficiency, broad operating range and a reasonable insensitivity to the parameters that define its operation. The theoretical performance of three variable pitch mechanisms for VAWT are compared. Cycloturbines use cam devices or gears to impose a sinusoidal pitch regime. In the mass-stabilised system, pitch is determined by the interplay of two opposing moments on the blades. These two mechanisms are compared with Aeropitch, a hypothetical pitch control system in which stabilising moments are related to the blade relative velocity. (Author)

Energy Technology Data Exchange (ETDEWEB)

Gasification experiments were performed using urban waste wood (Altholz) with additions of polymers typical for separately collected waste plastics. The resulting tar product distributions are discussed in this paper. The amount of tars is shown to be a function of operation parameters of the gasifier as well as the fuel. Plastics admixture yields higher concentrations of aromatic tar compounds in the gases, even if the plastic used is not aromatic in its structure. Such mixtures can be gasified for the production of synthesis gas, but clearly a larger effort will be required in cleaning the gases. (author)

Science.gov (United States)

This bulletin traces development of high-pressure, coal and tar hydrogenation technology, based on an intensive review of pertinent literature. The bulletin written as part of the Bureau of Mines research program on synthetic liquid fuels covers the history and economics of the process; chemical aspects of hydrogenation of coal, tar, and middle oil; engineering aspects of converting coal and tar to liquid fuels, principally gasoline; and equipment for the process. The literature covered includes documents of United States and British governments, journals, and other publications. Bureau results in the hydrogenation field are also incorporated.

Energy Technology Data Exchange (ETDEWEB)

The effect of air addition on biomass tar conversion in catalytic packed bed crackers was studied using both an isothermal micro reactor and a fluidised bed bench scale biomass gasification set up with down stream tar crackers. The micro reactor was applied for experiments with artificial biomass producer gas containing naphthalene as a model tar compound. Experiments were carried out with inert silica and catalytically active calcined dolomite bed material both with and without air addition. Experimental results with real tar from the fluidised bed bench scale gasification set up were in qualitative agreement with results from the micro reactor experiments. (author)

Energy Technology Data Exchange (ETDEWEB)

There are 1.4 Gt (1.5 billion st) of recoverable coal under less than 914 m (3,000 ft) of cover in Colorado in pitching seams. Snowmass Coal Co., in cooperation with the US Department of Energy, introduced the longwall mining method in pitching seams to North America. This venture is a coal mining research program directed toward the profitable production of coal under difficult mining conditions as found in pitching seams of the western US. Snowmass Coal classifies pitching seams into the following categories for longwall on the strike in seams 3 m (10 ft) or less thick: Flat = 0 to 10/sup 0/: Normal continuous mines and shuttle cars work efficiently. Slight = 10/sup 0/ to 22/sup 0/: The maximum pitch that rubber tired equipment will function. Moderate = 22/sup 0/ to 40/sup 0/: The angle of repose of mined coal. Steep = 40/sup 0/ to 60/sup 0/: The limit of safe use of this roof ...

Energy Technology Data Exchange (ETDEWEB)

The further development of a Guideline (formerly Protocol) for sampling and analysis of 'tars' from biomass producer gases is reported. This Guideline is being developed as a project within the European Fifth Framework Programme with additional partners from Switzerland and North-America. In this paper an outline and the principle of the Guideline are given. The Guideline is based on isokinetic sampling of particles and 'tar' from the main producer gas duct, particle filtration at high temperature, gas cooling in a liquid quench, 'tar' absorption in a solvent at low temperatures, an optional backup adsorber, and flow measurement and control. The Guideline gives a definition for 'Gravimetric tar' which is the 'tar' number to be determined by the Guideline. Also, the Guideline gives procedures ...

UK PubMed Central (United Kingdom)

Although many studies have examined the performance of animals in detecting a frequency change in a sequence of tones, few have measured animals' discrimination of the fundamental frequency...Full Text Available

Science.gov (United States)

No Abstract Available

Science.gov (United States)

... TITLE (Include Security Classification) Sorption of Selected Volatile Organic Constituents of Jet Fuels and Solvents on Natural Sorbents from Gas ...

KoreaScience (Korea)

Full Text Available

Science.gov (United States)

Breath Tests; Human Volunteers; Pilot Study

British Library Electronic Table of Contents (United Kingdom)

The results of studies performed for the development of a new process of the thermal cracking of tar as a suspension with ground Baltic oil shale in order to obtain motor fuel components are reported. The experimental results suggest undoubted advantages of the process over industrial thermal cracking because the deep degradation of tar (the yields of a gasoline fraction with bp to 180?C, middle distillates with bp of 180?360?C, and feedstock for catalytic cracking with bp of 360?520?C were ~12, 43?44, and ~15?16 wt % on an initial tar basis) was achieved upon the single-stage processing of the raw material under relatively mild conditions (5 MPa, 425?C, and a feed space velocity of 1.0 h?1). The resulting coke-like products and V and Ni contained in the raw material were deposited on the ...

Energy Technology Data Exchange (ETDEWEB)

The concentrations of iron, chromium, zinc, and aluminum were measured by atomic absorption spectroscopy in the lipid-soluble fractions of tar from the process stream of an experimental coal gasifier as part of large study on the health risks of coal gasification. Lipid solubility was inferred from octanol/water-partitioning and benzene-solubility tests. The properties of the lipid-soluble metals were compared to reference compounds by Sephadex LH-20 chromatography. The ability of the lipid-soluble metals to remain lipid soluble after treatment with acid and base was also tested. Lipid-soluble iron, chromium, zinc, and aluminum were present at 360, 12, 3, and 1 ppM, respectively, in the gasifier coal tar. The presence of these metals in lipid-soluble form may have important consequences relative to the potential toxicity of the tar if persons are exposed to it.

Science.gov (United States)

The study is concerned with the Stefan problem of evaporation of a volatile component from its solution with a virtually non-volatile material. The analysis provides an analytical solution to the problem based on mass-transfer fundamentals. Results yield the evaporation rate, interfacial mole fractions, concentration profiles in the gas and liquid phases, and the location of the evaporation front. The analysis can be used to provide the binary liquid diffusion coefficient of the volatile component based on experimental data for the liquid gas interface position as a function of time. The requirements for such a measurement are discussed in terms of the volatility of the evaporating component and its initial concentration in the liquid mixture.[Figure not available: see fulltext.

British Library Electronic Table of Contents (United Kingdom)

This paper studies the pricing of variance swap derivatives with stochastic volatility by the control variate method. A closed form solution is derived for the approximate model with deterministic volatility, which plays the key role in the paper, and an efficient control variate technique is therefore proposed when the volatility obeys the log-normal process. By the analysis of moments for the underlying processes, the optimal volatility function in the approximate model is constructed. The numerical results show the high efficiency of our method; the results coincide with the theoretical results. The idea in the paper is also applicable for the valuation of other types of variance swap, options with stochastic volatility and other financial derivatives with multi-factor models.

Science.gov (United States)

This document presents regulations and research support the EPA`s effluent limitations for the paving and roofing materials point source category.

British Library Electronic Table of Contents (United Kingdom)

The concentrates of scattered organic matter???kerogen-like polymer, which is insoluble in acids and organic solvents???were isolated from rock samples taken at different depths from various stratigraphic units at the productive deposits of the Orenburg oil-gas condensate field using chemical methods. The chemical composition of the kerogen-like polymer and the concentrations of trace elements in it were studied. The regularities of evolutionary changes in the composition of the organic matter and the concentrations of trace elements in it in the order of the kerogen-like polymer and the following its consecutive derivatives were established: asphaltenes, ethanol-benzene tars, benzene tars, oils, and paraffins

Energy Technology Data Exchange (ETDEWEB)

The guiding mechanism is attached by a hinge (swivel) to the supporting frame, and the frame is equipped by hinges (swivels) with hydraulic or pneumatic cylinders mounted on its ends and is attached by hinges (swivels) to the coke ejector and guide respectively. This increases the productivity and efficiency of operating the system.

Science.gov (United States)

No Abstract Available

Energy Technology Data Exchange (ETDEWEB)

Red mud is a waste product of the aluminium refining industry. It is composed of aluminium hydroxide and iron oxide. This study examined the feasibility of using red mud as a catalyst to eliminate volatile organic compounds in atmospheric pollutants. Volatile organic compounds can be eliminated by thermal oxidation between 600 and 1100 degrees C. However, the oxidation of volatile organic compounds can also be accomplished at lower temperatures (200 to 450 degrees C) if a catalyst is present. Currently, the low temperature destruction of volatile organic compounds is not widespread because of the difficulty in deactivating the catalyst. In this study, red mud was calcined in air at 500 degrees C. Under such conditions, the red mud converts to aluminium oxide and iron oxide. These 2 oxides are active and are carbon dioxide selective in the oxidation of volatile organic compounds. The ...

International Nuclear Information System (INIS)

Inherent to helical tomotherapy is a dose variation pattern that manifests as a 'ripple' (peak-to-trough relative to the average). This ripple is the result of helical beam junctioning, completely unique to helical tomotherapy. Pitch is defined as in helical CT, the couch travel distance for a complete gantry rotation relative to the axial beam width at the axis of rotation. Without scattering or beam divergence, an analytical posing of the problem as a simple integral predicts minima near a pitch of 1/n where n is an integer. A convolution-superposition dose calculator (TomoTherapy, Inc.) included all the physics needed to explore the ripple magnitude versus pitch and beam width. The results of the dose calculator and some benchmark measurements demonstrate that the ripple has sharp minima near p=0.86(1/n). The 0.86 factor is empirical and caused by a beam junctioning of the off-axis dose profiles which differ from the ...

Science.gov (United States)

A method is disclosed for the production of form coke, such as coke for use in the smelting industry as blast furnace coke and also in electro-metallurgical facilities. The process consists of : coking a high volatile coal containing at least 35% volatile constituents so as to remove the volatile constituents to form a non-baking base coal; mixing a plurality of fine grain coal components together, of which at least one of the components comprises said non-baking base coal and at least one other component comprises a baking bituminous coal so as to form a mixture of such coals; subjecting the mixture to a degassing operation using highly volatile coals; coking the degassed mixture; and pressing the coke into briquettes.

British Library Electronic Table of Contents (United Kingdom)

Summary The aroma impact volatiles of twenty-four pine honey samples produced in Marmaris, Data and Fethiye regions of Turkey were evaluated by solid phase micro extraction/gas chromatography/mass spectrometry (MS) technique and the results were evaluated by using the analysis of variance and Duncan tests. A total of eight common volatiles nonanal, nonanol, decanal, octanal, 16-oxosalutaridine, dodecanal, nonadecane and pentadecane were detected in three regions. The total area of the common volatiles were 73.01%, 78.10% and 73.91% in Marmaris, Data, and Fethiye regions, respectively. There were not significant differences (P-<-0.05) between the common volatiles detected in pine honey samples from three different regions. The major contributers to the pine honey aroma seems to be nonanal (...

Energy Technology Data Exchange (ETDEWEB)

Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis ...

Energy Technology Data Exchange (ETDEWEB)

Managing public lands for maximum social benefit is becoming an increasingly complex task. The growing need for domestically produced mineral raw materials and energy, and the conflicting interests over the use of public lands, have added new dimensions to the management issues. This report covers the first phase of a long-term program initiated by the Division of State Lands to improve their capability to evaluate the tar-sand and oil-shale resources in Utah. The scope of this phase of the study was limited to examination and analysis of existing information and to development models for data processing and resource evaluation. The study was effective in identifying problem areas and demonstrating the potential value of the proposed systems for management of state lands. It is anticipated that effective evaluation of the oil-shale and tar-sand resources in Utah, supported by readily accessible physical data, will lead to improved management ...

International Nuclear Information System (INIS)

Differential phase-contrast X-ray imaging has been performed in a Talbot-Lau configuration, where a multiline X-ray source was used instead of a combination of a hard-X-ray multiple slit and a normal focus X-ray generator. When the multiple slit is used, a high aspect ratio structure is needed and slit width should be below 10 ?m for its function. The fabrication and use of such a multislit can be omitted using the presented configuration. The multiline X-ray source was developed by making grooves on a tungsten rotating anode, which was irradiated by an electron beam to generate X-rays. An array of 10?m line sources with a pitch of 30?m was formed and combined with a 4.5 ?m pitch phase grating and a 5.3 ?m pitch amplitude grating to generate differential phase contrast. With a total exposure time of 40 s, a differential phase image depicting cartilages was obtained. (author)

Science.gov (United States)

A series of questions and answers addresses issues related to developing synthetic fuels, including the potential supplies, regulatory road blocks, and development incentives to promote the role of the private sector. Chevron's efforts in the area of synfuels are aimed at shale oil tar sands and coal conversion. The status of these research and development projects and the projected recoverable reserves from each are summarized. (DCK)

Science.gov (United States)

The class of vertical axis wind turbines (VAWT) investigated use curved, fixed-pitch blades of constant section rigidly attached to a vertical rotating tower. Qualitatively, the main advantages of the VAWT over more conventional, propeller-type machines are the elimination of yaw controls, the placement of mechanical equipment at ground level, its amenability to simple, low-cost blade fabrication techniques, and aerodynamic stall characteristics which eliminate the need for active pitch control devices. The main disadvantages relative to modern propeller machines are a somewhat lower aerodynamic efficiency (about 10 percent lower), the limited ability of the rotor to self-start, and generally lower rotor operating RPM's, which leads to higher torque capacity requirements for the drive train.

Wastenet

...May 2011, 693-709 On the valuation of fader and discrete barrier options in Heston's stochastic volatility model by Susanne Griebsch & Uwe Wystup [Downloadable!... (restricted)] 863-881 Nonlinearities in stochastic clocks: trades and volume as subordinators of electronic markets by Rafael Velasco-Fuentes & Wing Lon Ng [...and estimation of stock prices and trading volume in Barndorff-Nielsen and Shephard stochastic volatility models by Friedrich Hubalek & Petra Posedel [Downloadable!... (restricted)] 665-691 Generic pricing of FX, inflation and stock options under stochastic interest rates and stochastic volatility by Alexander van Haastrecht & Antoon ...

International Nuclear Information System (INIS)

Mineralization and volatilization of ring labelled "1"4C-2,4-dichlorophenoxyacetic acid in soil was studied over a period of six weeks under laboratory conditions at 25 deg. C in three different soils collected from three sites, Delhi, Jaipur and Ludhiana. A very slow rate of both mineralization and volatilization was observed in all the three soils. The observed mineralization, was highest for the Delhi soil, 0.93%, followed by the Ludhiana soil, 0.73% and the Jaipur soil 0.14% in 42 days. The extent of volatilization was 0.46% for the Jaipur soil, 0.37% for the Ludhiana soil and 0.32% for the Delhi soil. (author)

Energy Technology Data Exchange (ETDEWEB)

In order to protect food from pathogenic microorganisms as well as to increase its shelf life while keeping sensorial properties (e.g. odor and taste), once the latter are one of the main properties required by spice buyers, it is necessary to analyze volatile formation from irradiation of medicinal and food herbs. The aim of the present study was to analyze volatile formation from Co irradiation of Laurus Cinnamomum, Piper Nigrum, Origanum Vulgare and Myristica Fragans. Possible changes on the odor of these herbs are evaluated by characterizing different radiation doses and effects on sensorial properties in order to allow better application of irradiation technology. l he samples have been irradiated in plastic packages by making use of a {sup 60}Co Gamma irradiator. Irradiation doses of 0, 5, 10, 15, 20 and 25kGy have been tested. For the analysis of the samples, SPME has been applied, while for the analysis of volatile ...

Science.gov (United States)

Experiments contributing to the understanding of the aerodynamics of airfoils operating in the vertical axis wind turbine (VAWT) environment are described. These experiments are ultimately intended to reduce VAWT cost of energy and increase system reliability. They include chordwise pressure surveys, circumferential blade acceleration surveys, effects of blade camber, pitch and offset, blade blowing, and use of sections designed specifically for VAWT application.

Science.gov (United States)

In order to reduce the potential for severe liquid pipeline accidents, the U.S. Materials Transportation Bureau (MTB) proposes to require a hydrostatic test on all onshore pipelines carrying highly volatile liquids which have not been previously tested to at least 1.25 times their maximum operating pressure for at least 24 hr. Comments should be received by the MTB by 2/15/79. Late filed comments will be considered as far as practicable.

Energy Technology Data Exchange (ETDEWEB)

This study was aimed to test and select hydrophobic activated charcoal, manufactured in Romania, used as adsorbents of solvents which partly compose diluters employed in car industry. With regard to the diluters, three of the seven types of activated charcoal studied (Sorbent 1, R - Cafs and AD3) showed the greatest capacity of adsorption, when determined under dynamic and static conditions. (authors) 8 refs.

International Nuclear Information System (INIS)

Papers presented at a meeting on indoor and outdoor climates on sites polluted with volatile organic chemicals. The papers deal with the subject of evaporation of organic chemicals on the polluted sites in relation to the influence on indoor and outdoor climates. Themes dealt with are diffusion through soils and transport of pollutants from the soil into buildings. (AB).

Energy Technology Data Exchange (ETDEWEB)

The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, (MoO3)m, in air and the hydroxide, MoO2(OH)2, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report we present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800°C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic ...

Energy Technology Data Exchange (ETDEWEB)

A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and toluene is added. These conditions have the following favourable effects: (I) significant size reduction of ...

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the ...

Energy Technology Data Exchange (ETDEWEB)

Tar sand bitumen is petroleum-based ultra-heavy oil, and has a great amount of reserve like coal. However, there are still a lot of problems for its highly effective utilization. This paper discusses whether the light components in bitumen show independent behavior during the thermal cracking of heavy components, or not. Solvent effect and reaction mechanism during the thermal cracking are also derived from the change of their chemical structures. Athabasca tar sand bitumen was separated into light and heavy fractions by vacuum distillation based on D-1660 of ASTM. Mixtures of the both fractions at various ratios were used as samples. Negative effect of the light fraction on cracking of the heavy fraction was observed with dealkylation and paraffin formation Polymerization of the dealkylated light fraction to the heavy fraction was suggested due to lack of hydrogen in the thermal cracking under nitrogen atmosphere, which resulted in the ...

Energy Technology Data Exchange (ETDEWEB)

Many rural industries generate amounts of biomass waste, such as rice husks, sawdust, wood chips, nutshells and plant stalks that represent a substantial energy resource. However, most often these biomass wastes are not utilized and are dumped or burned in the open. This paper will show the whole project cycle of an installation and commissioning of a thermal configuration of a BG-Systems in Indonesia. These projects highlight the economic, operational and environmental benefits of the BG-Systems. BG-Systems are small fixed-bed downdraft gasifier systems being marketed by BG Technologies that convert biomass into a producer gas that is essentially free of tars and can be used reliably in a diesel engine or thermal combustor. (author)

Energy Technology Data Exchange (ETDEWEB)

Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis ...

Energy Technology Data Exchange (ETDEWEB)

For the protection of buried steel pipeline, it is common practice to coat the pipelines with highly insulating coating and apply a cathodic current to insulate the pipe from the aggressive environment. Cathodic current protects holidays or damaged area of coating which required less current than would be needed for an uncoated pipe, but because of the cathodic reactions evolution will be taken H{sub 2} and OH{sup -} on holidays which exposed metal to the environment place. This effect is to cause loss bond of coating around the holidays called cathodic dis-bonding. In this paper we measured cathodic dis-bonding of three types of coatings at - 1.5 V(Cu/CuSO{sub 4}) according to ASTM G8. We studied on cathodic dis-bonding resistance of petroleum-base, coal tar-base and polyethylene plastic tape coatings. After 30 days immersion in electrolyte it was found that the cathodic disbanding resistance of polyethylene plastic tape coating is lower than others and high ...

International Nuclear Information System (INIS)

The volatility of some elements being determined in biological and environmental samples by NAA (neutron activation analysis) in case of their binding with phenolformaldehyde resin (PFR) is studied. Since the temperature is assumed to influence the volatility of elements stronger than radiation during irradiation of samples in nuclear pile the losses of Se, As, Sb, and Hg form samples on the basis of PFR after their heating at 100-300 deg C have been investigated. It is shown that the losses of Sb and As up to 300 deg C, Se up to 250 deg C, and Hg up to 150 deg C from PFR - based samples do not occur.

Energy Technology Data Exchange (ETDEWEB)

This publication compiles five documents on volatile organic compounds (VOCs) in wastewater collection systems. The first is a thesis describing experiments conducted to obtain parameters for determining the significance of biodegradation relative to volatilization as a VOC fate mechanism in sewers. The second is a compilation of three papers from the 1992-94 conferences of the Air & Waste Management Association (AWMA). The papers concern VOC emissions at sewer drop structures and an estimation method for determining VOC emissions from industrial sewers. The third is a compilation of two papers from the AWMA 1992 and 1994 conferences, covering the formation of chloroform from household sources. The fourth is a thesis on post-discharge formation of chloroform in untreated municipal wastewater. The final document is a report detailing the derivation of fate mechanism models in the TOXCHEM model.

Energy Technology Data Exchange (ETDEWEB)

The authors report experimental results of heat transfer in the region of transition to turbulence. The augmentation was induced through deployment of periodically placed cylindrical eddy promoters in parallel plane channel flows. Eight different configurations were used. The presence of eddy promoters displaced the point of transition from Reynolds number values of 1500 for the plane channel to around 400 for the least stable case. The value of Nusselt number at the transition for eddy promoters cases was up to 2.5 times higher than the one for the plane channel at the transition. Furthermore, the lower the transition Reynolds number, the higher the Nusselt number at the transition. For the cases where the diameter of the promoters was small and/or the pitch large, the heat transfer results in the transition region were consistent with values obtained from the Reynolds analogy when the analogy was based on the mean transport parameters, i.e., spatially averaged ...

Energy Technology Data Exchange (ETDEWEB)

In the development of high performance heat transfer surface on a compact heat exchanger, it was clarified that how reattachment point heat transfer and fluid flow are affected by channel width, at the same time, an evaluation of heat transfer performance and an investigation of optimum channel width were carried out. The channel system used in the experiment is as follows; (1) blow-off type with rectangular section channel, (2) span length of 200 mm, (3) wave length (pitch) of 80 mm, and (4) channel length of 12.5 wave length. The channel Reynolds number was set at about 10/sup 4/ which is relatively higher than the current studies. The results of the experiment were summarized as follows. (1) The channel width H has relevance to the phase difference between the fluid flow in cone portion of main stream and wave shape, the flow patterns are divided roughly into three types. These boundaries exist at P/H 3.0 and 1.5 (P: pitch, H: width). (2) ...

Energy Technology Data Exchange (ETDEWEB)

This research has been proceeded over the potential core region (H/B=2) of two-dimensional impinging air jet system, in which square rods(width of 6 mm) has been set up in front of heating surface in order to increase heat transfer. The objective of this research was to investigate the characteristics of heat transfer and air flow, in cases of the clearance from rods to heating surface (C = 1, 2, 4, 6 mm) and the pitch between each rods(P = 30, 40, 50 mm) changed. And this research compared the above with the experimentation without rods. As result, heat transfer performance was best under the condition of C = 1 mm, in case clearance changed, and there was no serious difference in the effect of heat transfer augmentation in the case of pitch of rods changed. (author) 11 refs. 12 figs.

Energy Technology Data Exchange (ETDEWEB)

An optimization of fuel bundle geometry using the subchannel code ASSERT is performed in support of Candu fuel design to enhance the thermohydraulics performance. The new bundle design is based on a reference CANFLEX bundle with changes to the centre and inner-ring element diameters and pitch-circle diameters (PCDs) of various element rings. Different methods of varying the PCDs for reaching the optimized geometry are considered in an attempt to minimize the optimization effort. The optimized geometry in the present analysis is the one that maximizes the dryout power and that has simultaneous CHF (critical heat flux) initiation involving more than one subchannel rings. (authors)

International Nuclear Information System (INIS)

Some examples are given of design adaptations, e.g. U-bend support, tube spacer grid, flow distribution baffle, triangular tube pitch, tube-tubeplate sheet connection, which reduce the tendency to various types of corrosion (stress corrosion cracking, tube denting, tube wastage, intergranular cracking). A basic diagram of the secondary circuit is shown. Oxygen, corrosion product and impurity control in the secondary circuit is described. (E.J.). 19 figs., 6 refs.

Energy Technology Data Exchange (ETDEWEB)

This work describes the use of volatile halocarbons in a pulp mill effluent, including chloroform, bromodichloromethane, and tri- and tetrachloroethylene, as tracers for the distribution and movements of effluent currents in a receiving water bay (Jackfish Bay) on the northern shore of Lake Superior. The results indicate the simplicity and usefulness of the technique and the significantly improved resolution of effluent plume delineation over the customary use of conductance profiles. Concentration patterns of the effluent volatiles suggest counterclockwise circulation of bay water that mixes with inflowing lake water at the eastern reach of the outer bay. The distribution of volatile contaminants is governed by the thermal regime of the receiving waters. During the summer months, the effluent plume wedges between the thermocline and epilimnion, mixing into the surface waters as the distance from the input source increases. ...

UK PubMed Central (United Kingdom)

Surface glandular trichomes distributed throughout the aerial parts of sweet basil (Ocimum basilicum) produce and store monoterpene, sesquiterpene, and phenylpropene volatiles. Three...Full Text Available

UK PubMed Central (United Kingdom)

This unit presents two basic protocols that offer rapid assessments of anosmia (the absence of a sense of smell) in mice. The buried food test is used to check for the ability to smell volatile...Full Text Available

UK PubMed Central (United Kingdom)

This study was conducted to determine by gas chromatography (GC) and mass spectrometry (MS) the identity and the quantity of volatile N products produced during the helium-purged in vivo...Full Text Available

UK PubMed Central (United Kingdom)

Simulations with a regional chemical transport model show that anthropogenic emissions of volatile organic compounds and nitrogen oxides (NO_x = NO + NO₂) lead to a dramatic diurnal...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundGlucosinolate breakdown products are volatile, therefore good candidates for insect fumigants. However, although they are insecticidal, the mode of action of such natural...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundEpidemiologic studies associate lung cancer in non-smoking Chinese women with Chinese-style wok cooking. Our goal was to quantify carcinogen and toxicant...Full Text Available

International Nuclear Information System (INIS)

Supplemental criticality safety analysis of a pool type storage for TRIGA spent fuel at 'Jozef Stefan' Institute in Ljubljana, Slovenia, is presented. Previous results (Ravnik, M, Glumac, B., 1996) have shown that subcriticality is not guaranteed for some postulated accidents. To mitigate this deficiency, a study was made about replacing a certain number of fuel elements in the rack with absorber rods (Glumac, B., Ravnik, M., Logar, M., 1997) to lower the supercriticality probability, when the pitch is decreased to contact (as a consequence of a severe earthquake) in a square arrangement. The criticality analysis for the hexagonal contact pitch is presented in this paper, following the same scenario as outlined above. The Monte Carlo computer code MCNP4B with ENDF-B/VI library and detailed three dimensional geometry was used. First, the analysis about the influence of the number of triangular fuel piles on the bottom that could appear, if the ...

Energy Technology Data Exchange (ETDEWEB)

This work demonstrate the gasoline volatility influence, at T 10%, T 50% and T 90% distillation points, on the dynamic performance of Otto cycle engines equipped with fuel sequential electronic injection system, by using test standard procedures in dynamometer. For each distillation points three value ranges were established, giving the rise of 27 different gasoline mixtures. The effects of variation in each point on consumption, power and acceleration were verified.

Energy Technology Data Exchange (ETDEWEB)

Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).

Energy Technology Data Exchange (ETDEWEB)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level {alpha} solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends on the ruthenium ...

Energy Technology Data Exchange (ETDEWEB)

A summary of the off-gas behavior in the HARVEST pot vitrification process is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The main volatile elements were Ru, B, Cs. Some volatility was also shown by Na and Li. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) proceses involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The ...

Energy Technology Data Exchange (ETDEWEB)

A 1 MWe power plant using waste wood fuel is to be installed at a US Marine Corps base, which will supply all wood from a landfill site. The core energy conversion technology is a down-draft gasifier supplying approximately 150 Btu/scf gas to both spark ignition and diesel dual-fuel engine-generator sets. Features of the plant design include: (1) grinding wood fuel from a wide range of waste resources, (2) specialized screening for fines removal, (3) complete tar and other waste product control without landfill disposal, and (4) use of process heat for bulk fuel drying, gasifier air pre-heating, and wastewater evaporation.

Energy Technology Data Exchange (ETDEWEB)

Oils, tars, and degraded oils of varying degrees of biodegradation occur in the Permian Phosphoria Formation along the eastern flank of the Wind River mountains, Wyoming, US. Biodegradation has altered the isomer distributions of steranes, the hopanes, and the mono- and triaromatised steroids in these oils. The conventional maturity parameters based on these biomarkers are of limited use in estimating their maturity. On the other hand, even in severely biodegraded oils the vanadylporphyrin distributions are unaltered. Because of this, the Porphyrin Maturity Parameter (PMP) derived from the vanadylporphyrin distribution is an ideal parameter for estimating the maturity of these oils. This study also confirms the previous observation that T[sub s] and T[sub m] are unaffected by even severe biodegradation. 14 refs., 5 figs., 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

Ruthenium is one of the fission products in the reprocessing of irradiated fuels that requires a specific processing management. Its elimination, upstream by the PUREX process, has been considered. A process, called electro-volatilization, which take advantage of the RuO{sub 4} volatility, has been optimised in the present study. It consists in a continuous electrolysis of ruthenium solutions in order to generate RuO{sub 4} species that is volatilized and easily trapped. This process goes to satisfying ruthenium elimination yields with RuNO(NO{sub 3}){sub 3}(H{sub 2}O){sub 2} synthetic solutions but not with fuel dissolution solutions. Consequently, this work consisted in the speciation studies of dissolved ruthenium species were carried out by simulating fuel solutions produced by hot acid attack of several ruthenium compounds (Ru(0), RuO{sub 2},xH{sub 2}O, polymetallic alloy). In parallel with dissolution kinetic studies, ...

Energy Technology Data Exchange (ETDEWEB)

In this paper, the combustible value (i.e. 100-Ash) and combustible recovery of coal flotation concentrate were predicted by regression and artificial neural network based on proximate and group macerals analysis. The regression method shows that the relationships between (a) in (ash), volatile matter and moisture (b) in (ash), in (liptinite), fusinite and vitrinite with combustible value can achieve the correlation coefficients (R{sup 2}) of 0.8 and 0.79, respectively. In addition, the input sets of (c) ash, volatile matter and moisture (d) ash, liptinite and fusinite can predict the combustible recovery with the correlation coefficients of 0.84 and 0.63, respectively. Feed-forward artificial neural network with 6-8-12-11-2-1 arrangement for moisture, ash and volatile matter input set was capable to estimate both combustible value and combustible recovery with correlation of 0.95. It was shown that the proposed neural ...

Energy Technology Data Exchange (ETDEWEB)

Cretaceous and Tertiary strata are known from outcrop in the northeast part of the area, while older rocks are presented in the southwest. The major structures are, from north to south: the Pedley Thrust, Coalspur Triangle Zone (formerly called Coalspur Anticline), Entrance Syncline, Mercoal Thrust, Brazeau Flats, Brazeau Thrust, Brazeau Syncline, Grave Flats Thrust, Cadomin syncline and Nikanassin Thrust. The economic coal seams of the Tertiary Coalspur Formation are of high volatile C rank and are present in three parallel bands in the Entrance Syncline and Coalspur Triangle Zone, where they have been mined extensively in the past. The Mercoal band is the southernmost and dips about 30[degree] to the northeast. The Coalspur band is in the middle and dips generally to the southwest. The Robb band is the northernmost band, contains northeast dipping strata and is less deformed than the Coalspur band. In the Entrance Syncline, the Coalspur coals are buried at ...

International Nuclear Information System (INIS)

In this work, the silicon oxynitride layer was studied as a tunneling layer for non-volatile memory application by fabricating low temperature polysilicon thin film transistors on glass. Silicon wafers were oxynitrided by only nitrous oxide plasma under different radio frequency powers and plasma treatment times. Plasma oxynitridation was performed in RF plasma using inductively coupled plasma chemical vapor deposition. The X-ray energy dispersive spectroscopy was employed to analyze the atomic concentration ratio of nitrogen/oxygen in oxynitride layer. The oxynitrided layer formed under radio frequency power of 150 W and substrate temperature of 623 K was found to contain the atomic concentration ratio of nitrogen/oxygen as high as 1.57. The advantage of high nitrogen concentration in silicon oxide layer formed by using nitrous oxide plasma was investigated by capacitance-voltage measurement. The analysis of capacitance-voltage characteristics demonstrated that ...

International Nuclear Information System (INIS)

The collision of the Earth with extra-terrestrial ice-volatile bodies is proposed as a mechanism to produce rapid changes in the geologic record. These bodies would be analogs of the ice satellites found for the Jovian planets and suspected for comets and certain low density bodies in the Asteroid belt. Five generic end-members are postulated: (1) water ice; (2) dry ice: carbon-carbon dioxide rich, (3) oceanic (chloride) ice; (4) sulfur-rich ice; (5) ammonia hydrate-rich ice; and (6) clathrate: methane-rich ice. Due to the volatile nature of these bodies, evidence for their impact with the Earth would be subtle and probably best reflected geochemically or in the fossil record. Actual boloids impacting the Earth may have a variable composition, generally some admixture with water ice. However for discussion purposes, only the effects of a dominant component will be treated. The general geological effects of such collisions, as a function of the ...

Science.gov (United States)

The Micro-X instrument is a NASA funded, rocket borne X-ray imaging spectrometer planned for launch in January 2011. An array of Transition Edge Sensors (TESs) will observe incoming photons in the 0.2-3 keV energy band with an energy resolution of 2-4 eV at 1 keV. This will be a substantial improvement over current non-dispersive detectors for X-ray spectroscopy of extended sources and will be the first demonstration of a TES-based microcalorimeter in space. The TESs will utilize the 50 mK stage of an Adiabatic Demagnetization Refrigerator (ADR) as a heat sink, and will be read out by a SQUID time division multiplexer. X-rays will be focused onto the TES array of 128 pixels on a 600 micron pitch by a conically approximated Wolter optic with an effective area of 200 cm2. The spectrometer will have a field of view of 11.8 arcmin. We describe the design and development progress of the instrument.

Science.gov (United States)

Theoretical and experimental research efforts in evaluating an innovative concept for vertical axis wind turbines (VAWT) are described. The concept is that of using straight blades composed of circulation controlled airfoil sections. The theoretical analysis has been developed to determine the unsteady lift and moment characteristics of multiple-blade cross-flow wind turbines. To determine the drag data needed as input to the theoretical analysis, an outdoor test model VAWT has been constructed; design details, instrumentation, and calibration results are reported. Initial testing is with fixed pitch blades having cross-sections of conventional symmetrical airfoils. Costs of building the test model are included, as well as estimates for blades constructed with composite materials. These costs are compared with those of other types of wind turbines.

Energy Technology Data Exchange (ETDEWEB)

Recent developments in rechargeable Li-ion battery technology include the use of lithium-carbon compounds instead of metallic anodes. Non-graphitizable carbons offer high capacity as the anode material but it's large irreversible capacity must be solved. The ultimate goals of the present work are to understand the origin of the high capacity and large irreversible capacity in conjunction with the structural change due to Li intercalation and thus to establish a scientific basis for optimizing their performance in real batteries. 'House of cards' model is considered and emphasis is given to find out the size of the pores present in the carbon fibers prepared from an isotropic petroleum pitch and heat treated at 1200degC. Small angle neutron scattering and wide angle neutron scattering results provide enlargement of pores and d-spacing of grapheme layers after Li intercalation. (author)

International Nuclear Information System (INIS)

We study the characteristics of cyclotron wave-particle interaction in a typical hydrogen plasma. The numerical calculations of minimum resonant energy Emin, resonant wave frequency ?, and pitch angle diffusion coefficient D?? for interactions between R-mode/L-mode and electrons/protons are presented. It is found that Emin decreases with ? for R-mode/electron, L-mode/proton and L-mode/electron interactions, but increase with ? for R-mode/proton interaction. It is shown that both R-mode and L-mode waves can efficiently scatter energetic (10 keV-100 keV) electrons and protons and cause precipitation loss at L=4, indicating that perhaps wave-particle interaction is a serious candidate for the ring current decay. (authors)

British Library Electronic Table of Contents (United Kingdom)

We investigate optimal horizons for targeting inflation in response to different shocks and their properties. Our analysis is based on a well specified macroeconometric model of Norway. We find that optimal horizons are highly shock-specific and do not increase with concern for output and/or interest rate fluctuations beyond some shock-specific levels. Optimal horizons increase with the degree of persistence in shocks while they are not affected by the size of a shock unless the central bank is averse to interest rate volatility. In the face of multiple shocks, however, sizes as well as signs of shocks become important for optimal horizons even when the central bank is not averse to interest rate volatility. This is because shocks of different signs and sizes may amplify or outweigh each o...

British Library Electronic Table of Contents (United Kingdom)

Biopharmaceutical R&D complexes are major emission sources of volatile organic compounds (VOCs), which may pose potential health risks for staff on site and residents nearby. In this paper health risk assessments were performed for the VOCs in the ambient air of a typical biopharmaceutical R&D complex in China. Results showed halogenated and alkyl compounds were dominant components among 24 major VOCs from 9 selected sampling sites, inside or around the complex. The principal component analysis (PCA) indicated VOCs were generated predominantly from the biopharmaceutical research activities (factor 1 (F1), 71.6%) and traffic vehicles (factor 2 (F2), 15.4%), which were confirmed by contour maps of five selected VOCs (benzene, toluene, chlorobenzene, methylene chloride and n-hexane) simulated...

Energy Technology Data Exchange (ETDEWEB)

From 1965 to 1980 ash content in anthracite from the Donbass supplied to power plants increased from 21.9 to 35.5%, moisture content increased from 7.6 to 10.1%, calorific value declined from 23.7 to 18.5 MJ/kg. Combustion of anthracite culm is stabilized by mazout combustion. Heat treatment of anthracite culm by means of plasma generators improves fuel quality. High temperature causes emission of volatile matter from anthracite and partial gasification of coke particles. Combustion of volatile matter from anthracite and coke is a reliable ignition method for anthracite culm. It also stabilizes combustion of pulverized anthracite. Heat treatment of about 20% anthracite by plasma generators reduces nitrogen oxide emission from a furnace by 30-40%. 5 refs.

British Library Electronic Table of Contents (United Kingdom)

Abstract Ovipositing females of the black swallowtail butterfly, Papilio polyxenes Fabricius (Lepidoptera: Papilionidae: Papilioninae), have an innate response to contact chemical cues, but it was not known how naive females would respond to volatile host plant chemicals. Naive and experienced females were tested in a free-flight experiment using model plants and volatile extracts from two hosts, carrot [Daucus carota L. (Apiaceae)] and poison hemlock [Conium maculatum L. (Apiaceae)], and one non-host, fava bean [Vicia faba L. (Fabaceae)]. Naive females responded to both host plant extracts with more approaches and landings than to non-host extracts, with poison hemlock receiving more responses than carrot. Females experienced with one of the two host plants also approached and landed freq...

Energy Technology Data Exchange (ETDEWEB)

Los Alamos National Laboratory (the Laboratory) is subject to emissions reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20 NMAC 2.73), Notice of Intent and Emissions Inventory Requirements. The Laboratory has the potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, and volatile organic compounds. For 1998, combustion products from the industrial sources contributed the greatest amount of criteria air pollutants from the Laboratory. Research and development activities contributed the greatest amount of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20 NMAC 2.72 Construction Permits.

International Nuclear Information System (INIS)

Soya- and oats-lipoxygenase (E.C. 1.13.1.13) are incubated by "1"4C-marked linoleic acid. The volatile aldehydes arising thereby are isolated. The activity of the components separated by gaschromatography is written down by a printing indicator and the impulses/min are registered and printed out by a ratemeter. Thus the aldehydes which are produced by the enzymatic oxydation with lipoxygenase from the molecule of the linoleic acid can be determined. The composition of the mixture of aldehydes is calculated in mol-% from the measured impulses for peak. A possible origin of pathway is indicated for the main reaction products hexanal (soyalipoxygenase) and non-trans-2-enal (oats-lipoxygenase). (orig.).

British Library Electronic Table of Contents (United Kingdom)

A recently developed hydrodistillation?solvent microextraction (HD?SME) method coupled to gas chromatography?mass spectrometry (GC?MS) was applied to the analysis of volatile components of aerial parts of Echinophora cinerea (Boiss). By the use of a simplex optimization method, the effects of extraction time, sample weight and microdrop volume on the extraction efficiency of the method were optimized. In the optimized conditions, 3??L of n-heptadecane was suspended in the headspace of 6?g of hydrodistillating sample, using a microsyringe. After 7?min, the solvent was retracted back into the syringe and directly injected into the GC?MS injection port. The HD?SME method was compared to a conventional hydrodistillation technique. In general, the extraction with HD?SME was relatively faster an...

CERN Document Server

Fragile volatile aggregates with extremely low albedo, gravitationally drawn into the solar system are likely from the dark matter dominating the universal mass. Characteristics of this meteoric population permitted avoiding detection through a half-century's search. Measurements from space probes and in the upper atmosphere prove their existence and confirm their elusive properties.

Energy Technology Data Exchange (ETDEWEB)

A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

UK PubMed Central (United Kingdom)

Plant roots release about 5% to 20% of all photosynthetically-fixed carbon, and as a result create a carbon-rich environment for numerous rhizosphere organisms, including plant pathogens and symbiotic...Full Text Available

UK PubMed Central (United Kingdom)

Stem-boring insects and methyl jasmonate (MeJA) are thought to induce similar complex chemical and anatomical defenses in conifers. To compare insect- and MeJA-induced terpenoid responses, we analyzed...Full Text Available

UK PubMed Central (United Kingdom)

One of the drawbacks in improving the aroma properties of tomato (Solanum lycopersicum) fruit is the complexity of this organoleptic trait, with a great variety of volatiles contributing...Full Text Available

International Nuclear Information System (INIS)

The involvement and relationship of carbon steel corrosion products in the tube denting phenomenon promoted an intensive research effort to: 1) understand, reproduce, and arrest the denting process, and 2) evaluate alternative tube support materials to provide additional corrosion resistance. The paper summarizes a corrosion testing program for the verification of type 405 stainless steel under acid or all volatile treatment conditions.

International Nuclear Information System (INIS)

Pollutant emissions due to fossil fuel and biomass energy utilization in Turkey have been estimated. Standard emission factors were used for estimating the levels of particulate matter, sulfur oxides, nitrogen oxides, carbon monoxide, volatile organic compounds, and aldehydes. The results are presented for different fuels and energy-consuming sectors for the reference year 1987. Total Turkish emissions vs energy consumption are presented for every fifth year since. 1960. (author).

Energy Technology Data Exchange (ETDEWEB)

By increasing the price of crude oil and natural gas and the decline in their stock a possibility of more intense use of coal reserves as a feedstock not only for energy purposes but also as a feedstock source for other industries, mainly chemical and steel industry, is opening up. At present brown coal exploited in the Czech Republic is explicitly burned in the power sources of various outputs. Coal pyrolysis under the defined conditions may be an outstanding way of non-energetic brown coal processing. The target of our work was to determine the behaviour of various types of brown coal from the North Bohemian Basin under the pyrolysis up to the temperature 750{sup o}C. At the same time, qualitative parameters of the pyrolysis products in dependence on the features of the input brown coal were observed. Various types of brown coal were used for the pyrolysis tests differing mainly in the content of ash, sulphur and tar. Within the work mass balances of the incurred ...

Science.gov (United States)

This document demonstrates the commercial status of the process units to be used in the Tri-State Synfuels Project at Henderson, Kentucky. The basic design philosophy as established in October, 1979, was to use the commercial SASOL II/III plants as a basis. This was changed in January 1982 to a plant configuration to produce gasoline via a methanol and methanol to gasoline process. To accomplish this change the Synthol, Oil workup and Chemical Workup Units were eliminated and replaced by Methanol Synthesis and Methanol to Gasoline Units. Certain other changes to optimize the Lurgi liquids processing eliminated the Tar Distillation and Naphtha Hydrotreater Units which were replaced by the Partial Oxidation Unit. The coals to be gasified are moderately caking which necessitates the installation of stirring mechanism in the Lurgi Dry Bottom gasifier. This work is in the demonstration phase. Process licenses either have been obtained or must be obtained for a number of ...

Science.gov (United States)

Extensive laboratory and industrial tests are being conducted at the Western Siberian Iron and Steel Works (I and SW) on the adoption of preheating of coking. The present article describes the results of laboratory investigations of the effect of the free oxygen content in the gaseous heat carrier and the final charge preheating temperature on the technological properties of the charge and the quality of the blast furnace coke, as well as the yield and quality of the coking products: 1. An increase in the free oxygen concentration in the heat carrier to 8% degrades the strength properties of the coke - the crushability and abradability are increased. 2. Charge preheating to 200 to 250/sup 0/C, even with a low oxygen concentration in the heat carrier, is accompanied by degradation of the physical and mechanical properties of the coke. 3. The optimal temperature of charge preheating before coking at the Western Siberia I and SW was found to be in the 150 to 200/sup 0/C range, and the ...

International Nuclear Information System (INIS)

An extensive set of benchmark measurement of PDDs and beam profiles was performed in a heterogeneous layer phantom, including a lung equivalent heterogeneity, by means of several detectors and compared against the predicted dose values by different calculation algorithms in two treatment planning systems. PDDs were measured with TLDs, plane parallel and cylindrical ionization chambers and beam profiles with films. Additionally, Monte Carlo simulations by meansof the PENELOPE code were performed. Four different field sizes (10x10, 5x5, 2x2, and1x1 cm"2) and two lung equivalent materials (CIRS, #rho#_e"w=0.195 and St. Bartholomew Hospital, London, #rho#_e"w=0.244-0.322) were studied. The performance of four correction-based algorithms and one based on convolution-superposition was analyzed. The correction-based algorithms were the Batho, the Modified Batho, and the Equivalent TAR implemented in the Cadplan (Varian) treatment planning system and the TMS Pencil Beam ...

Energy Technology Data Exchange (ETDEWEB)

Measurements are presented of the distribution of average friction factors (f) as well as local and average ({ovr Nu}) heat transfer coefficients for fully developed channel flows with two rib-roughened opposite walls. The temperature measurements were made by using both a laser holographic interferometer and thermocouples. In addition, the reattachment length was determined by flow visualization. The Reynolds number (Re) was varied from 5.0 {times} 10{sup 3} to 5.4 {times} 10{sup 4}; the rib pitch-to-height ratios (Pi/H) were 10, 15, 20; and the rib height-to-hydraulic diameter ratios (H/De) were 0.063, 0.081, and 0.106. The detailed results allowed the peaks of heat transfer augmentation and the regions susceptible to hot spots to be located and allowed the relative contribution of the rib surface and the channel wall to the heat transfer augmentation to be determined. Moreover, relative to a smooth duct, the enhancement of both {ovr Nu} and f at various Re, ...

International Nuclear Information System (INIS)

The energy spectra of energetic confined alpha particles are being measured using the pellet charge exchange method [R. K. Fisher, J. S. Leffler, A. M. Howald, and P. B. Parks, Fusion Technol. 13, 536 (1988)]. The technique uses the dense ablation cloud surrounding an injected impurity pellet to neutralize a fraction of the incident alpha particles, allowing them to escape from the plasma where their energy spectrum can be measured using a neutral particle analyzer. The signal calculations given in the above-mentioned reference disregarded the effects of the alpha particles' helical Larmor orbits, which causes the alphas to make multiple passes through the cloud. Other effects such as electron ionization by plasma and ablation cloud electrons and the effect of the charge state composition of the cloud, were also neglected. This report considers these issues, reformulates the signal level calculation, and uses a Monte-Carlo approach to calculate the neutralization fractions. The ...

Energy Technology Data Exchange (ETDEWEB)

Activated charcoal has so far taken a shape of particle or powder, but as the third activated charcoal, fibrous activated charcoal (ACF) has begun to be produced industrially. In comparison with the conventional activated charcoal, ACF has such characteristics as follows (1) its rate of absorption and desorption is very fast, (2) its specific area is large and it has high absorption performance, (3) it has wide absorption characteristics, and (4) its reactivation and reutilization are possible. In addition, because of its fibrous condition, it can be processed into compound materials of various shapes by utilizing the fiber processing technology. Furthermore, it can be combined with other functional fibrous material and used as multifunctional material. In this article, the production process, performance, characteristics and usage of ACF, which is an excellent absorbent as stated above, are outlined with a focus on the pitch-based ACF developed jointly by Osaka ...

Energy Technology Data Exchange (ETDEWEB)

Room temperature continuous wave operation of red ([lambda][sub 0] [approximately] 660 nm) vertical cavity surface emitting laser arrays is reported. The 1 [times] 64 arrays have a pitch of 100 [mu]m with device diameters of 15 [mu]m with device diameters of 15 [mu]m. Grown by metalorganic vapor phase epitaxy, the devices consist of an AlGaInP strained quantum well optical cavity active region surrounded by AlGaAs distributed Bragg reflectors (DBR's). The top coupling DBR includes a partial dielectric stack, deposited after implanted device fabrication. All 64 devices operation simultaneously with peak output powers >0.45 mW, threshold current <1.5 mA, and threshold voltages [<=] 2.7 V. The differential quantum efficiencies exceed 10%.

Energy Technology Data Exchange (ETDEWEB)

Microstructural evolution due to thermal effects was studied in micro solder joints (55 {+-} 5 {micro}m). The composition of the Sn/Pb solder studied was found to be hypereutectic with a tin content of 65--70 wt%.This was determined by Energy Dispersive X-ray analysis and confirmed with quantitative stereology. The quantitative stereological value of the surface-to-volume ratio was used to characterize and compare the coarsening during thermal cycling from 0--160 C to the coarsening during annealing at 160 C. The initial coarsening of the annealed samples was more rapid than the cycled samples, but tapered off as time to the one-half as expected. Because the substrates to which the solder was bonded have different thermal expansion coefficients, the cycled samples experienced a mechanical strain with thermal cycling. The low-strain cycled samples had a 2.8% strain imposed on the solder and failed by 1,000 cycles, despite undergoing less coarsening than the annealed samples. The ...

Science.gov (United States)

The paper investigates the effect of the wall heat flux ratio on the local heat transfer augmentation in a square channel with two opposite in-line ribbed walls for Reynolds numbers from 15,000 to 80,000. The square channel composed of 10 isolated copper sections has a length-to-hydraulic diameter ratio of 20. The rib height-to-hydraulic diameter ratio is 0.0625 and the rib pitch-to-height ratio equals 10. Six ribbed side to smooth side wall heat flux ratios are studied for four rib orientations. The results show that the ribbed side wall heat transfer augmentation increases with increasing ribbed side to smooth side wall heat flux ratios, but the reverse is true for the smooth side wall heat transfer augmentation. The average heat transfer augmentation of the ribbed side and smooth side wall decreases slightly with increasing wall heat flux ratios. The effect of wall heat flux ratio reduces with increasing Reynolds numbers. The 60-deg V-shaped rib and 60-deg ...

Energy Technology Data Exchange (ETDEWEB)

An experimental study was conducted to investigate the heat transfer and friction loss characteristics in a horizontal rectangular channel having attachments of hollow rectangular profile fins over one of its heated surface. The Reynolds number based on the flow averaged inlet velocity and the hydraulic diameter, ranged from 3000 to 32,000. The hollow rectangular profile fins in 10cm height and axb=2cmx4cm dimensions with a thickness of 0.2cm were mounted on a heating surface vertically. Reynolds number, fin arrangement and fin pitch in the flow direction were the experimental parameters. Both in-line and staggered fin arrangements were studied for one-fixed spanwise (S{sub x}/a=3) and four different streamwise (S{sub y}/b=1.5, 1.875, 2.5 and 3.75) distances. Correlation equations for Nu, f and thermal performances were determined for fin configurations and the straight channel case without fins. (author)

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An experimental study of forced convection heat transfer at the inner tube wall of a double pipe heat exchanger with coiled wire inserts as heat transfer augmentation devices was performed over a turbulent flow region. The test results from twelve augmented tubes with inserts of different combinations of wire diameters (0.813, 1.016 and 1.575 mm) and pitches (2.82, 3.63, 5.08 and 8.47 mm) indicate that the turbulence promoters studied improve heat transfer by a factor of 1.4 to 2.24 compared with a smooth tube, although at a cost of 10-30 times increase in friction factor. A formula for presenting dimensionless exergy losses in a tubular heat exchanger is derived first and then the thermohydrodynamic optimum instead of economic optimum is found by minimizing the exergy losses in the system. From the heat transfer improvement number defined, it is observed that coiled wire turbulence promoters are more effective at Reynolds numbers less than 5.0[times]10[sup 4] in ...

Energy Technology Data Exchange (ETDEWEB)

An experimental rig was set up to study the performance of a thermal storage unit using stearic acid as the heat storage medium. The unit mainly consists of an electrical heating rod and an outer tube, and the space between is an annulus that is filled with stearic acid. The thermal performance of the unit is measured, and the heat transfer characteristics of the melting processes of stearic acid are studied under different heat flux conditions to determine the influence of heat flux on the melting processes. A new type of fin is designed and fixed to the electrical heating rod to enhance the thermal response of the stearic acid. The experimental results show that the fin can improve the heat transfer of the melting process of the thermal storage unit greatly. The equivalent thermal conductivity of the PCM can be augmented by a factor up to 3. The analysis of the experimental results shows that the enhancement mechanism of the fin is attributed to its ability to improve both heat ...

Energy Technology Data Exchange (ETDEWEB)

The object of briquetting coal fines is to convert a low grade fuel into one of superior quality coal. Briquetting techniques make coal an attractive substitute fuel by converting it into a compact, stable and inexpensive fuel. The briquetting of coal fines and char fines from coal and lignite, coke breeze, charcoal fines and similar materials is an important process for producing shaped fuel for a number of uses. Formed-coke made from non-caking coal for use in a blast furnace or in a cupola furnace involves the briquetting of treated char fines and further processing of the briquettes by means of carbonizing and curing. Briquettes may be made with or without binders, brown coal is particularly suitable for briquetting without a binder. Heat treatment may enable a higher rank coal to be briquetted without a binder, but binders are usually used so as to improve the combustion properties of the coal, they may include pitch, bitumen, sulphite liquor, starches and ...

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The use of a non-dedicated GPS receiver system for attitude determination was assessed in airborne mode through a test conducted at Sandia National Laboratories. Four independent NovAtel GPSCard{trademark} receivers were installed in Sandia`s Twin Engine Otter with two antennas mounted on the fuselage and two on the wing tips at separations of 6 to 18 m. A strapdown INS was also on board the aircraft in order to provide an independent attitude reference at rates between 4 and 10 Hz. During the multi-day test, GPS measurements were recorded between 1 and 10 Hz. Carrier phase measurements were post-processed using a double difference approach developed at The University of Calgary in which integer ambiguities were resolved in seconds using the known antenna separations as constraints. The tracking capability of the system is demonstrated under dynamics consisting of roll and pitch angles up to 45 and 12 degrees, respectively. Comparisons between the GPS and INS ...

CERN Document Server

A comparison is carried out between two operational wave forecasting/assimilation models for the North Sea, with the emphasis on the assimilation schemes. One model is the WAM model, in combination with an optimal interpolation method (OIP). The other model, DASWAM, consists of the third generation wave model PHIDIAS in combination with an approximate implementation of the adjoint method. In an experiment over the period February 19 - March 30, 1993, the models are driven by the same wind field (HIRLAM analysis winds), and the same observation data set is assimilated. This set consists of a) spectra from three pitch-and-roll buoys and b) Synthetic Aperture Radar (SAR) spectra from the ERS-1 satellite. Three analysis/forecast runs are performed: one without assimilation, one with assimilation of buoy measurements only, and one with all data assimilated. For validation, observations from four buoys, altimeter data from ERS-1 and Topex-Poseidon, and scatterometer data ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this report is to review the different technologies for trapping the gaseous wastes containing Cs, Ru, Tc, {sup 14}C, Kr, Xe, I and {sup 3}H from a voloxidation process. Based on literature reviews and KAERI's experimental results on the gaseous fission products trapping, appropriate trapping method for each fission product has been selected considering process reliability, simplicity, decontamination factor, availability, and disposal. Specifically, the most promising trapping method for each fission product has been proposed for the development of the INL off-gas trapping system. A fly ash filter is proposed as a trapping media for a cesium trapping unit. In addition, a calcium filter is proposed as a trapping media for ruthenium, technetium, and {sup 14}C trapping unit. In case of I trapping unit, AgX is proposed. For Kr and Xe, adsorption on solid is proposed. SDBC (Styrene Divinyl Benzene Copolymer) is also proposed as a conversion media to HTO for {sup ...

Energy Technology Data Exchange (ETDEWEB)

We evaluated the similarities between ozone-induced and mite-induced emission of volatile organic compounds (VOCs) from lima beans, and tested the response of the natural enemies of herbivores to these emissions using trophic system of two-spotted spider mites and predatory mites. The acute ozone-exposure and spider mite-infestation induced the emission of two homoterpenes, (E)-4,8-dimethyl-1,3,7-nonatriene and (E,E)-4,8,12-trimethyl-1,3,7,11-tridecatetraene, and (Z)-3-hexenyl acetate. Only plants with spider mite-infestation emitted the monoterpene (E)-{beta}-ocimene. Predatory mites were equally attracted to ozone-exposed and unexposed plants, but discriminated between spider mite-infested and uninfested plants, when both were exposed to ozone. The similarities between ozone and herbivore-induced VOCs suggest that plant defence against phytotoxic ozone and the production of VOCs for attraction of the natural enemies of herbivores may have adaptive coevolution. ...

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Los Alamos National Laboratory is subject to annual emissions-reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), Notice of Intent and Emissions Inventory Requirements. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. For calendar year 2001, the Technical Area 3 steam plant was the primary source of criteria air pollutants from the Laboratory, while research and development activities were the primary source of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20.2.72 NMAC. Hazardous air pollutant emissions from chemical use for research and development activities were also reported.

Energy Technology Data Exchange (ETDEWEB)

The growth kinetics constants and concentration of active attached biomass in an anaerobic fluidized bed which decomposes acetic, propionic and butyric acid were estimated. The mixture of above mentioned fatty acids was supplied to the fluidized bed in the range of hydraulic retention time (HRT) from 0.25 to 2 days. After the effluent reached in a steady state in quality, batch experiments were conducted separately with each fatty acid as a substrate in order to investigate the decomposition characteristics of each substrate by attached biomass. In order to estimate the parameter values of the growth kinetics of the bacteria, batch experiments were also conducted under the completely mixed condition using detached biomass from a support material. The changes of fatty acid concentrations with time were clearly expressed with the Monod growth model. Maximum specific substrate decomposition rates and saturation constants, and active biomass concentrations were obtained by the curve ...

International Nuclear Information System (INIS)

An ion chromatograph has been modified to automatically sample ten liquid water streams from the secondary side of three pressurized water reactors, Calvert Cliffs, Unit One, Rancho Seco and McGuire, Unit 1. Sampling and measurement is semicontinuous with a cycle time of approximately five hours for 10 locations with sensitivities in the range of 0.1 to 0.5 ppb. The efficiency of the condensate polishing system and subsequent transport of sodium, chloride, and sulfate around the system can be readily followed. Sulfate has been shown to have unusual volatility into the steam phase from the steam generator as well as a tendency to pass through the condensate polisher.

International Nuclear Information System (INIS)

A review of the performance of steam generator tubes in 116 water-cooled nuclear power reactors showed that tubes were plugged at 54 (46 percent) of the reactors. The number of tubes removed from service decreased from 4 692 (0.30 percent) in 1981 to 3 222 (0.20 percent) in 1982. The leading causes of tube failures were stress corrosion cracking from the primary side, stress corrosion cracking (or intergranular attack) from the secondary side and pitting corrosion. The lowest incidence of corrosion-induced defects from the secondary side occurred in reactors that have used only volatile treatment, with or without condensate demineralization.

British Library Electronic Table of Contents (United Kingdom)

This paper introduces a new way of estimating parameters in a Brownian motion regime switching asset model to incorporate volatility clustering. The regime switching model is then applied to pricing of up-and-in barrier call options. We take the probability of crossing the barrier between simulation points into account, and we increase accuracy in simulations by importance sampling. The regime switching model is compared to the Normal Inverse Gaussian model and the traditional Black-Scholes model, and option prices from the regime switching model are compared to the closed form expression of up-and-in barrier calls in a Black-Scholes market.

International Nuclear Information System (INIS)

Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.

Energy Technology Data Exchange (ETDEWEB)

In situ air stripping (ISAS) technology was developed to remediate soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISAS employs horizontal wells to inject (sparge) air into the ground water and vacuum extract VOCs from vadose zone soils. The innovation is creation of a system that combines two somewhat innovative technologies, air sparging and horizontal wells, with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

Science.gov (United States)

The abuse of volatile solvents may be due to their ability to produce an intoxication similar to that produced by classical central nervous system depressants such as the barbiturates and ethanol. To evaluate this hypothesis, mice were trained to discriminate pentobarbital from saline injections in a two-lever operant task. Stimulus generalization was examined following 20-min inhalation exposures to toluene (300-5400 ppm). In 8 of 10 subjects, pentobarbital-lever responding occurred following toluene exposure indicating an overlap in the discriminative stimulus properties of toluene and pentobarbital.

Energy Technology Data Exchange (ETDEWEB)

In Situ Bioremediation (ISB), which is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation, remediates soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISB involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove .VOCs from the vadose zone concomitant with biodegradation of VOCs. The innovation is in the combination of 3 emerging technologies, air stripping, horizontal wells, and bioremediation via gaseous nutrient injection with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

Energy Technology Data Exchange (ETDEWEB)

Ash fallout from the Mount Saint Helens eruptions affected high-voltage transmission in a four-state area as volatile gases caused conductivity changes and corrosion. The Bonneville Power Authority (BPA) found that it was possible to maintain electric service except for a few short, localized outages. Cleaning ash from transformers and substations was the first priority. Tests were underway within 48 hours to determine ash characteristics and cleaning procedures. A summary to what happened and what was learned is presented in two lists. (DCK)

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This paper is a quarterly report describing the use of a new soil gas collection device which allows the collection of soil gas in the field for later analysis in the laboratory. It describes the installation of this sampling device and the procedure for setting the probe, extraction of soil gas beneath the surface, and sealing of the soil gas for transport. The sites used for initial testing was the top of Yucca Mountain and Crystal Spring in Ash Meadows National Wildlife Refuge. The results from this initial test showed no volatile matter present in the soil at these locations.

Energy Technology Data Exchange (ETDEWEB)

This paper describes a novel Fourier transform infrared (FTIR) spectroscopic method that can be used to rapidly screen soil samples from potentially hazardous waste sites. Samples are heated in a thermal desorption unit and the resultant vapors are collected and analyzed in a long-path gas cell mounted in a FTIR. Laboratory analysis of a soil sample by FTIR takes approximately 10 minutes. This method has been developed to identify and quantify microgram concentrations of explosives in soil samples and is directly applicable to the detection of selected volatile organics, semivolatile organics, and pesticides.

International Nuclear Information System (INIS)

A process has been developed that exploits the characteristics of microwave heating for the vitrification of high-level radioactive liquid waste. This process, microwave vitrification, has been successfully operated at pilot plant scale in an active cell using simulated liquid waste containing several curies of radioactivity. Excellent decontamination factors have been achieved for both volatiles and nonvolatiles with an average ruthenium decontamination factor of 490 and a gross alpha emitter decontamination factor of 100,000. Almost all the radioactivity is incorporated in a glass block.

Energy Technology Data Exchange (ETDEWEB)

Several Hungarian lignite and brown coal samples were studied by coal petrographical, palynological and organic geochemical methods. Three of these were chosen for a series of pyrolysis experiments. Thermal treatment was carried out on two H-rich Eocene brown coals (kerogen: Type II) and a H-poor Miocene lignite (kerogen Type III) between 200 and 500{degree}C. The products of experiments (insoluble residue, chloroform soluble bitumen and volatilized bitumen) were investigated. During diagenesis the hydrocarbon potential of lignite decreased by 75% and that of the coals diminished approximately 50%. The zone of the catagenesis was reached at 350{degree}C by lignite and at 375{degree}C by coals. The coal-2 is somewhat more resistant to thermal degradation than coal-1. Various hydrocarbon classes (alkanes, alkenes, phyllocladanes, isoprenoids) were measured in non-aromatic hydrocarbon fractions. Volatile bitumens contained much more unsaturated ...

Energy Technology Data Exchange (ETDEWEB)

A new air injection process called toe-to-heel air injection (THAI) has been developed to achieve very stable combustion performance in heavy oil wells by controlling gas override. In the THAI process, injected air migrates preferentially to the combustion front into a horizontal producer well by the oxygen diffusional gradient created under steady state conditions. This is possible because of the balance between the stoichiometric oxygen flux needed to burn the fuel (coke) laid down ahead of the combustion front and the removal of downstream combustion gases and mobilised fluids. This study involved a numerical simulation of the THAI process to increase the understanding of the processes involving fluid flow, heat transfer and chemical reactions taking place during in situ combustion. Two tests were conducted involving one dry and one wet combustion using heavy Wolf Lake Oil. The objective was to determine if the behaviour of the oil could be predicted. A corresponding ...

Energy Technology Data Exchange (ETDEWEB)

The cost of liquid fuels from coal is a complex function of many factors, such as capital investment, cost of coal and labor cost. Furthermore, the cost will depend on geographical position, the size of the operation and the efficiency of the process. There is no single answer and case studies will have to be made to establish economics at different locations. In the following, the 1980 order-of-magnitude investment costs and operating costs for a coal liquefaction plant are estimated. For a Sasol II type of plant with the product output indicated earlier, the total capital cost is estimated at $4 billion in 1980 dollars. Capital cost accounts for approximately 50%, utilities and materials for 30%, and labor for 20% of the total cost. Given the market value of by-product ethylene ($175/t), tar products ($300/t), chemicals ($300/t), ammonia ($200/t) and sulfur ($25/t), the credit for by-products is $146 million per year. The cost of motor fuel is thus estimated at ...

Energy Technology Data Exchange (ETDEWEB)

This report presents estimates of the annual anthropogenic UK emissions of greenhouse gases for the years 1990-93 for submission under the Framework Convention on Climate Change. The gases considered are carbon dioxide, methane, nitrous oxide, nitrogen oxides, carbon monoxide and non-methane volatile organic compounds. Emissions of all the gases have declined since 1990. In particular, those of carbon dioxide have fallen by 4%; those of methane by 8% and those of nitrous oxide by 28%. Emission estimates are reported in the IPCC Standard Tables format disaggregated by source category and fuel. The methodology used for the estimates and how they relate to the UK National Atmospheric Emissions Inventory is discussed in an appendix. (author)

International Nuclear Information System (INIS)

The partial pressures of the components (ThCl_4, MCl and MThCl_5) in the saturated vapours of ThCl_4 solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl_4 concentration (2 to 50 mol% ThCl_4) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl. (author).

Energy Technology Data Exchange (ETDEWEB)

Studies the quality of metallurgical coke produced from a mixture of USA (80%) and Soviet (20%) coking coals. Properties of coal were analyzed according to ICCP and ISO international standards, including mechanical and petrographic tests. Content of the coal mixture included 8.2% moisture, 7.6% ash, 0.98% sulfur, 27.7% volatiles. The swelling index was 6 and dilation index 15%. Properties of coke produced from this coal mixture in the Croatian Bakar coking plant are presented for lump sizes of 25-80 mm, 10-25 mm and 0-10 mm. The produced coke was of favorable quality, having a strength index of 4.70, an ASTM stability factor of 61, and an M40 strength of 73.3%. 9 refs.

Energy Technology Data Exchange (ETDEWEB)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1992. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) a membrane-assisted solvent extraction method for treating natural and process waters contaminated by volatile organic compounds and (2) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process.

Energy Technology Data Exchange (ETDEWEB)

Sasol Limited's 1986 annual report for the year ended June 30, 1986 reported an increase in profit of 14.8% for the year. Financial measures taken in order to counteract the effect of the lower oil prices are described. Operating results and technical modifications of the Sasol One, Two, and Three plants are discussed. Sasol believes that crude oil prices will remain volatile for some time and will fluctuate between $10 and $18 per barrel. A steady increase in crude oil prices will then occur in the 1990's. As a result of the conservative financial policy of the past few years, Sasol is well equipped to cope with low fuel prices in the short and medium term.

Science.gov (United States)

Hydrogenation of high-volatile bituminous coal under high temperatures and pressures produced low-sulfur fuel oils. At a coal conversion of 80 percent, the ratio of oil to gas yields was approximately 3 : 1 and 23 percent of the coal sulfur was contained in the oil. Sulfur content of the oil, however, remained the same at different coal-conversion levels. The data obtained in the semicontinuous dilute-phase hydrogenation system showed that the whole oil can be directly used as a fuel oil where 1 percent sulfur is tolerated. Fuel oils containing 0.5 percent and 0.25 percent sulfur were produced by desulfurization of the whole oil.

Science.gov (United States)

Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and/or sequester toxic heavy metal pollutants as an environmentally friendly alternative to physical remediation methods. We have focused this phytoremediation research on soil and water-borne ionic and methylmercury. Mercury pollution is a serious world-wide problem affecting the health of human and wild-life populations. Methylmercury, produced by native bacteria at mercury-contaminated wetland sites, is a particularly serious problem due to its extreme toxicity and efficient biomagnification in the food chain. We engineered several plant species (e.g., Arabidopsis, tobacco, canola, yellow poplar, rice) to express the bacterial genes, merB and/or merA, under the control of plant regulatory sequences. These transgenic plants acquired remarkable properties for mercury remediation. (1) Transgenic plants expressing merB (organomercury lyase) extract methylmercury from their growth substrate and ...

Energy Technology Data Exchange (ETDEWEB)

The removal of paraffinic bottom accumulations from refinery storage tanks represents an increasingly costly area of petroleum storage management. Microorganisms can be used to reduce paraffinic bottoms by increasing the solubility of bottom material and by increasing the wax-carrying capacity of carrier oil used in the cleaning process. The economic savings of such treatments are considerable. The process is also intrinsically safer than alternative methods, as it reduces and even eliminates the need for personnel to enter the tank during the cleaning process. Both laboratory and field sample analyses can be used to document changes in tank material during the treatment process. These changes include increases in volatile content and changes in wax distribution. Several case histories illustrating these physical and chemical changes are presented along with the economics of treatment.

Energy Technology Data Exchange (ETDEWEB)

A compression ignition engine was operated on dual fuel principle inducting two commercial fuels and four pure hydrocarbon fuels in turn through intake manifold along with air and injecting diesel fuel to initiate the combustion in the conventional manner. The engine was operated at different loads and at each load the quantity of inducted fuel was increased gradually till knocking set in. The engine performance and exhaust pollutant emissions were recorded at different operating conditions. It was observed that the extent of induction and the effect on the performance depend on the properties of the inducted fuel such as volatility, self ignition temperature and oxidation characteristics. The energy release during the cycle was also observed to shift depending on the properties of inducted fuel. With the dual fuel operation, the thermal efficiency at part loads was observed to be less compared to neat diesel operation. The thermal efficiency reduced with the ...

British Library Electronic Table of Contents (United Kingdom)

We investigate the intertemporal risk-return trade-off of foreign exchange (FX) rates for ten currencies quoted against the USD. For each currency, we use three risk measures simultaneously that pertain to that currency; its realized volatility, its realized skewness, and its value-at-risk. We apply monthly FX excess returns and risk measures calculated from daily observations. We find that there is a significant contemporaneous risk-return trade-off for the currencies under investigation. There is no evidence of noncontemporaneous risk-return trade-off. We pay special attention to the risk-return trade-off during the recent financial crisis.

British Library Electronic Table of Contents (United Kingdom)

Fragranced consumer products are pervasive in society. Relatively little is known about the composition of these products, due to lack of prior study, complexity of formulations, and limitations and protections on ingredient disclosure in the U.S. We investigated volatile organic compounds (VOCs) emitted from 25 common fragranced consumer products-laundry products, personal care products, cleaning supplies, and air fresheners-using headspace analysis with gas chromatography/mass spectrometry (GC/MS). Our analysis found 133 different VOCs emitted from the 25 products, with an average of 17 VOCs per product. Of these 133 VOCs, 24 are classified as toxic or hazardous under U.S. federal laws, and each product emitted at least one of these compounds. For ''green'' products, emissions of these c...

CERN Document Server

Using ultra-high-frequency data extracted from the order flows of 23 stocks traded on the Shenzhen Stock Exchange, we study the empirical regularities of order placement in the opening call auction, cool period and continuous auction. The distributions of relative logarithmic prices against reference prices in the three time periods are qualitatively the same with quantitative discrepancies. The order placement behavior is asymmetric between buyers and sellers and between the inside-the-book orders and outside-the-book orders. In addition, the conditional distributions of relative prices in the continuous auction are independent of the bid-ask spread and volatility. These findings are crucial to build an empirical behavioral microscopic model based on order flows for Chinese stocks.

British Library Electronic Table of Contents (United Kingdom)

The development of a new configuration of chemical ionization (CI)-based ion source is presented. The ambient air containing the gaseous sample is sniffed into an enclosed ionization chamber which is of sub-ambient pressure, and is subsequently mixed with metastable species in front of the ion inlet of the mass spectrometer. Metastable helium atoms (He*) are used in this study as the primary ionizing agents and are generated from a dielectric barrier discharge (DBD) source. The DBD is powered by an AC high-voltage supply and the configuration of the electrodes is in such a way that the generated plasma is confined within the discharge tube and is not extended into the ionization chamber. The construction of the ion source is simple, and volatile compounds released from the bulky sample can...

Energy Technology Data Exchange (ETDEWEB)

The use of dendrimers for preparing chemically sensitive interfaces for detecting volatile organic compounds (VOCs) using surface acoustic wave (SAW) device transducers is described. Specifically, the synthesis of the dendrimers and the means by which they are affixed to SAW devices is discussed, followed by a detailed spectroscopic analysis of the surface-confined dendrimers and a discussion of their interaction with different VOCs. Most of these preliminary experiments focus on dendrimer surface modification using benzoylchloride, which leads to phenyl terminal groups linked to the dendrimer via amide groups. The results of this study lead us to conclude that dendrimers: (1) provide general specificity towards classes of functional groups and are therefore suitable for array-based sensing schemes; (2) are intermediate in structure between monolayers and polymers and exhibit the desirable properties of both; (3) can be straightforwardly attached to the surfaces of ...

Energy Technology Data Exchange (ETDEWEB)

Several proposals have been made on the method of calculating generation of formaldehyde released from plywood. In calculating generation per hour of a volatile organic compound of adhesives or coatings using a chamber method, such models are frequently used that the generation is largest when the specimen is exposed in the chamber and that the generation attenuates with lapse of time. In the meantime, a number of studies for calculating formaldehyde generation from construction materials are often those determining a specific quantity of generation in a stationary state, while few studies are the observation of time series variation from immediately after the exposure into the chamber. Accordingly, the subject studies used lauan plywood as the samples and examined the method of calculating the change with lapse of time of the formaldehyde generation. (translated by NEDO)

International Nuclear Information System (INIS)

Polymer sealing parts are widely used in various branches of engineering as detachable joints that operate at normal and cryogenic temperatures. They are also used in nuclear-power engineering to seal pumps, pipelines, etc., where they operate at 600-650 K under a neutron fluence of around 10"1"6 cm"-"2 (E #>=# 0.18 MeV) and concomitant #gamma#-irradiation of about 10"6 R. The fluoroplastic-based materials currently used degrade when irradiated in water at 320-360 K with a neutron fluence of 10"1"5 cm"-"2 (thermal neutrons) or 10"1"4 cm"-"2 (fast neutrons), and a concomitant #gamma#-irradiation dose of 2 x 10"6 R. The strength of these fluoroplastics decreases markedly after #gamma#-irradiation (from a cobalt source) at room temperature at doses above 10"6 R. For this reason, flexible and swelling graphites are finding ever increasing application. Graflex foils made of extra-pure natural graphite were found to be radiation-resistant and suitable for use as seals and planar gaskets ...

International Nuclear Information System (INIS)

The advent of multislice spiral CT (MSCT) technique has led to new aspects of dose reduction, especially for the dedicated use of MSCT in children. Optimizing pediatric MSCT protocols according to the clinical problem allows reduction of radiation exposure to a minimum without loss of diagnostic quality. The different parameters that influence the degree of dose reduction, like tube current-time product (mAs), tube voltage (kV), collimation and pitch, are discussed in context with previously published data and our own experience in nearly 200 pediatric CT examinations. In our department, the effective mAs is calculated for a pediatric chest MSCT by multiplication of the body weight in kilogram with a factor of 1 to 1.5 and for a pediatric abdominal MSCT by multiplication with a factor of 2 to 2.5. To calculate the equivalent effective dose for a contrast media-enhanced 80 kV protocol, the effective mAs of the 120 kV protocol can be multiplied by 2.7. A factor less ...

Energy Technology Data Exchange (ETDEWEB)

For the performance analysis of Canadian deuterium uranium (CANDU) reactor shutdown system number 2 (SDS2), a computational fluid dynamics model of poison jet flow has been developed to estimate the flow field and poison concentration formed inside the CANDU reactor calandria. As the ratio of calandria shell radius over injection nozzle hole diameter is so large (1055), it is impractical to develop a full-size model encompassing the whole calandria shell. In order to reduce the model to a manageable size, a quarter of one-pitch length segment of the shell was modeled using symmetric nature of the jet; and the injected jet was treated as a source term to avoid the modeling difficulty caused by the big difference of the hole sizes. For the analysis of an actual CANDU-6 SDS2 poison injection, the grid structure was determined based on the results of two-dimensional real- and source-jet simulations. The maximum injection velocity of the liquid poison is 27.8 m/s and ...

International Nuclear Information System (INIS)

Heat transfer augmentation in narrow rectangular channels in a target system is a very important method to remove high heat flux up to 12 MW/m"2 generated at target plates of a high-intensity proton accelerator of 1.5 GeV and 1 mA with a proton beam power of 1.5 MW. In this report, heat transfer coefficients and friction factors in narrow rectangular channels with one-sided rib-roughened surface were evaluated for fully developed flows in the range of the Reynolds number from 6,000 to 1,00,000; the rib pitch-to-height ratios (p/k) were 10,20 and 30; the rib height-to-equivalent diameter ratios (k/De) were 0.025, 0.03 and 0.1 by means of previous existing experimental correlations. The rib-roughened surface augmented heat transfer coefficients approximately 4 times higher than the smooth surface at Re=10,000, p/k=10 and k/De=0.1; friction factors increase around 22 times higher. In this case, higher heat flux up to 12 MW/m"2 could be removed from the rib-roughened ...

Energy Technology Data Exchange (ETDEWEB)

Experimental studies on the heat transfer and fluid dynamics of a high heat flux fuel rod for a very high temperature reactor (VHTR) were performed using a single channel test rig of a fuel stack test section (T{sub 1-s}) installed in a helium engineering demonstration loop (HENDEL). The fuel rod has been developed in order to enhance the turbulent heat transfer coefficient than that of the standard fuel rod obtained by the previous experiment. Two-dimensional square ribs were settled on the outer surface of the fuel rod axially to improve the heat transfer. The configuration of a square rib is 0.5 mm in width(w), 0.5 mm in height(h) and 5 mm in pitch(p): p/h=10. The experiment were carried out under the helium gas conditions of high temperature and pressure simulated the VHTR operation. For the turbulent region of Reynolds number 2,500{approx}8,000 of the VHTR core flow condition, it was found that the heat transfer coefficient of the fuel rod and the friction ...

Energy Technology Data Exchange (ETDEWEB)

Frictional pressure drop and heat transfer performance in a very narrow rectangular channel having one-sided constant heat flux and repeated-ribs for turbulent flow have been investigated experimentally, and their experimental correlations were obtained using the least square method. The rib pitch-to-height ratios(p/k) were 10 and 20 while holding the rib height constant at 0.2mm, the Reynolds number(Re) from 2,414 to 98,458 under different channel heights of 1.2mm, 2.97mm, and 3.24mm, the rib height-to-channel equivalent diameter(k/De) of 0.03, 0.04, and 0.09 respectively. The results show that the rib-roughened surface augments heat transfer 2-3 times higher than that of the smooth surface with the expense of 2.8-4 times higher frictional pressure drop under Re=5000-10{sup 5}, p/k=10, and H=1.2mm. Experimental results obtained by channel height, H=1.2mm shows a little bit higher heat transfer and friction factor performance than the higher channel height, ...

Energy Technology Data Exchange (ETDEWEB)

Objective: To assess dynamic MRI with Gd-DTPA enhancement for evaluating inflammatory changes in the subacromial bursa. Design and patients: We detected the signal intensity changes in dynamic MRI of the subacromial bursa, and confirmed these macroscopically by arthroscopy and histologically. The signal intensity was measured using built-in software, and the enhancement ratio (E ratio) was calculated from dynamic MR images. In addition, as a parameter of the rate of the increase in the signal intensity from 0 to 80 s, the mean increase per second in the E ratio was obtained as the coefficient of enhancement (CE). The correlation was studied of the E ratio and CE with the arthroscopic findings (redness, villous formation, thickening and adhesion), and of the E ratio and CE with the histological findings (capillary proliferation, papillary hyperplasia, fibrosis and inflammatory cell infiltration) of the subacromial bursa. Of patients with shoulder pain, this study included those with ...

Energy Technology Data Exchange (ETDEWEB)

This paper reported on a new cutting mechanism that cuts fresh wood into small pieces instead of wood chips in order to avoid the problem of fermentation that occurs in storage. The prototype cutting device performs a gradual and oblique cut. It consists of a large auger in which a knife is inserted on the outer edge of the helicoid. Tree trunks up to 20 cm in diameter are fed perpendicularly into the machine and are pushed along the axis where slices are cut off against a fixed sharp-edged counter blade. The cylinder enclosing the auger is the main frame of the machine, and is closed at one end, where a heavy flywheel delivers the energy coming from the tractor's power take-off (PTO). The wood pieces ranging in length from 4 to 19 cm exit through the opposite end. The auger is 700 mm in diameter with a 300 mm pitch spacing. The logs are pushed into the machine by counter-rotating rollers placed in the feed funnel. Tests were conducted to determine the ...

International Nuclear Information System (INIS)

An effective procedure for removing _3H, Xe and Kr from irradiated fuels was demonstrated using Shippingport UO"2 fuel. The release characteristics of _3H, Kr, Xe, and I from irradiated nuclear fuel have been determined as a function of temperature and gaseous environment. Vacuum outgassing and a flowing gas stream have been used to vary the gaseous environment. Vacuum outgassing released about 99% of the _3H and 20% of both Kr and Xe within a 3 h at 1500_0C. Similar results were obtained using a carrier gas of He containing 6% H"2. However, a carrier gas containing only He resulted in the release of approximately 80% of the _3H and 99% of both Kr and Xe. These results indicate that the release of these volatile fission products from irradiated nuclear fuel is a function of the chemical composition of the gaseous environment. The rate of tritium release increased with increasing temperature (1100 to 1500_0C) and with the addition of hydrogen to the gas stream. ...

Energy Technology Data Exchange (ETDEWEB)

Reinforcement of the legislation concerning the emission of atmospheric pollutants, aerosols, refrigerants, solvents etc and the reduction of the greenhouse effect, has led to the development of performing instruments for the survey and control of ambient air quality and for the limitation of exhaust gases, combustion products, volatile organic compounds (VOC), particulates and noxious compounds in the atmosphere. This study is divided in 4 main parts. The first part describes the context of the air quality control: the problems linked with the environment and health, the pollutants characteristics, the pollution levels and the detection sensitivity of instruments according to the different type of pollutants (petroleum products, VOCs, ozone compounds, particulates, smells..), the protocols of air pollution measurements and their application (chimney smokes, industrial volatile compounds, indoor and ambient air quality, exhaust gases from ...

Energy Technology Data Exchange (ETDEWEB)

Prototype tests conducted during the winter of 1989/90 have successfully demonstrated an economical design for air stripping volatile hydrocarbons from oily tanker ballast water. The prototype air stripper, developed for Alyeska's Ballast Water Treatment (BWT) facility in Valdez, Alaska, ran continuously for three months with an average removal of 88% of the incoming volatile organics. Initially designed to remove oil and grease compounds from tanker ballast water, the BWT system has been upgraded to a three-step process to comply with new, stringent regulations. The BWT biological oxidation process enhances the growth of bacteria present in the incoming ballast water through nutrient addition, aeration, and recirculation within a complete-mixed bioreactor. The average removal of BETX is over 95%, however, occassional upsets required the placement of a polishing air stripper downstream of the aeration tanks. Packed-tower air stripping ...

Energy Technology Data Exchange (ETDEWEB)

The gasification reactivities of six typical Chinese anthracite chars with steam and CO{sub 2} at 0.02-0.1 MPa and 920-1050{sup o}C were investigated by using thermogravimetric analysis (TGA). The reactivities of anthracite chars during steam gasification were found to have a good correlation to the coal volatile matter contents. The higher the coal volatile matter content, the higher the reactivity. The difference in reactivities of anthracite chars during CO{sub 2} gasification seems to be more dependent on the catalytic effect of inherent minerals in anthracite. The results show that the greater the alkali index, the higher the reactivity. The reactivities of demineralized anthracite chars vary very little compared with those the undemineralized chars at higher temperatures, whereas the reactivities of demineralized chars from Jincheng and Rujigou are lower than those of undemineralized ones and the reactivities of demineralized chars from ...

Energy Technology Data Exchange (ETDEWEB)

A vendor glass formulation study was carried out at Pacific Northwest Laboratory (PNL), supporting the Phase I and Phase II melter vendor testing activities for Westinghouse Hanford Company. This study is built upon the LLW glass optimization effort that will be described in a separate report. For Phase I vendor melter testing, six glass formulations were developed at PNL and additional were developed by Phase I vendors. All the doses were characterized in terms of viscosity and chemical durability by the 7-day Product Consistency Test. Twelve Phase II glass formulations (see Tables 3.5 and 3.6) were developed to accommodate 2.5 wt% P{sub 2}O{sub 5} and 1.0 wt% S0{sub 3} without significant processing problems. These levels of P{sub 2}O{sub 5} and SO{sub 3} are expected to be the highest possible concentrations from Hanford Site LLW streams at 25 wt% waste loading in glass. The Phase H compositions formulated were 6 to 23 times more durable than the environmental assessment (EA) glass. ...

Science.gov (United States)

Microbial volatile organic compounds (MVOCs) emitted from the mould species Penicillium expansum, P. chrysogenum, Aspergillus versicolor, A. fumigatus, A. niger and Cladosporium cladosporoides were analyzed by means of solid phase microextraction (SPME) and GCMS. The mould species were cultivated on the synthetic agar dichloran chloramphenicol (DG 18) and on wet wall paper. The production of MVOCs was monitored over several weeks to detect changes in the emission rates between the initial stage and later periods of growth. The cultivation on the synthetic agar resulted in MVOC patterns with a wide variety of signals. In contrast, the growth on wet wall paper led to changed MVOC patterns with less signals. The emission rates were drastically reduced. Components emitted by all six fungi species on wall paper were 2-pentanol and 2-pentanone. 1-Octen-3-ol was emitted by five fungi species. 2-Pentanol was only detected in considerable amounts during the first days of ...

Energy Technology Data Exchange (ETDEWEB)

N/C and S/C ratios show only minor differences between asphaltenes and coal on this basis, the asphaltenes continue to appear to be good surrogates for the characterization of organic acid rain precursors in coal. Alkylmethoxythiophene carboxylic acids (ATCA) are detected in all dichromate oxidation products analyzed to date. Relative concentrations of ATCA compounds are directly proportional to the sample`s bulk organic sulfur contents. Concentrations of ATCA compounds in oxidation products decrease upon repeated oxidation. This may indicate that the thiophenic groups tend to be located in external positions on the coal macromolecular structure and a high proportion of them can be stripped away with only one mild oxidation step. If true, this may make industrial-scale removal of organic sulfur easier than expected. Using analytical micropyrolysis-gas chromatography with a sulfur-selective flame photometric detector, it is possible to easily see a full distribution of organic sulfur ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work is to investigate the possible role of Helical CT defecography in pelvic floor disorders by comparing the results of the investigations with those of conventional defecography. The series analyzed consisted of 90 patients, namely 62 women and 28 men, ranging in age 24-82 years. They were all submitted to conventional defecography, and 18 questionable cases were also studied with Helical CT defecography. The conventional examination was performed during the 4 standard phases of resting, squeezing, Valsalva and straining; it is used a remote-control unit. The parameters for Helical CT defecography were: 5 mm beam collimation, pitch 2, 120 KV, 250 m As and 18-20 degrees gantry inclination to acquire coronal images of the pelvic floor. The rectal ampulla was distended with a bolus of 300 mL nonionic iodinated contrast agent (dilution: 3g/cc). The patient wore a napkin and was seated on the table, except for those who could not hold the position ...

Energy Technology Data Exchange (ETDEWEB)

An automated Time Resolved Aerosol Collector (TRAC) has been developed for sequential sampling of field-collected aerosols for laboratory-based Computer Controlled Scanning Electron Microscopy/Energy Dispersed X-ray (CCSEM/EDX) single particle analysis. The collector is optimized for use of grid-supported 20 nm carbon films as deposition substrates. The carbon films have low enough X-ray background to permit EDX analysis down to 0.1-0.2 ?m particles, including detection of low-Z elements: C, N, & O. The TRAC provides unattended sampling onto a set of 151 individual grids, at sequential time intervals as short as 1 min. After collection, the samples are sealed and refrigerated pending analysis. The utility of the TRAC-CCSEM/EDX approach is exemplified using the aerosol samples collected during the Texas 2000 Air Quality Studies (Aug. 15 ? Sept. 15, 2000). We are able to quantitatively follow the time evolution in the relative contribution of non-volatile ...

International Nuclear Information System (INIS)

Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of hydrocarbon material was more pronounced ...

Energy Technology Data Exchange (ETDEWEB)

The compositions of the Earth's crust and mantle, and those of the Moon and Mars, are relatively well known both isotopically and elementally. The same is true of our knowledge of the asteroid belt composition, based on meteorite analyses. Remote measurements of Venus, the Jovian atmosphere, and the outer planet moons, have provided some estimates of their compositions. The Sun constitutes a large majority, > 99%, of all the matter in the solar system. The elemental composition of the photosphere, the visible 'surface' of the Sun, is constrained by absorption lines produced by particles above the surface. Abundances for many elements are reported to the {+-}10 or 20% accuracy level. However, the abundances of other important elements, such as neon, cannot be determined in this way due to a relative lack of atomic states at low excitation energies. Additionally and most importantly, the isotopic composition of the Sun cannot be determined astronomically ...

International Nuclear Information System (INIS)

PWR plants have made efforts to maintain the long-term integrity of the steam generators (SG) by reducing the amount of corrosion products entering the secondary side of the SG. Iron entered the SG can cause several problems: degraded heat conductivity of the SG tubes in locations where iron is deposited, water level oscillations in the SG due to tube support plate hole blockage, and initiation and propagation of inter-granular attacks (IGA) and stress corrosion cracking (SCC). One of the most effective measures, high all-volatile treatment (AVT) chemistry has been applied to actual plants to reduce the flow-accelerated corrosion (FAC) coming from the carbon steel piping. The secondary water chemistry at Genkai NPS 1 and 2 changed, from the Low AVT chemistry to the High AVT chemistry, in November 2006. In this paper, we will describe the results of experiments in applying the use of High pH water in the secondary water system at Genkai NPS. (author)

Energy Technology Data Exchange (ETDEWEB)

Soils and groundwater beneath an abandoned Process sewer line in the A/M Area of the Savannah River Site (SRS) contain elevated levels of volatile organic compounds, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE), two common chlorinated solvents. These compounds have low aqueous solubilities, thus when released to the subsurface in sufficient quantity, tend to exist as immiscible fluids or nonaqueous phase liquids (NAPLs). Because chlorinated solvents are also denser than water, they are referred to by the acronym DNAPLS, or dense non aqueous Phase liquids. Technologies targeted at the efficient characterization or removal of DNAPL are not currently proven. For example, most DNAPL studies rely on traditional soil and water sampling and the fortuitous observation of immiscible solvent. Once DNAPL is identified, soil excavation (which is only applicable to small contained spill sites) is the only ``proven`` cleanup method. New cleanup approaches ...

CERN Document Server

Terrestrial planets form in a series of dynamical steps from the solid component of circumstellar disks. First, km-sized planetesimals form likely via a combination of sticky collisions, turbulent concentration of solids, and gravitational collapse from micron-sized dust grains in the thin disk midplane. Second, planetesimals coalesce to form Moon- to Mars-sized protoplanets, also called "planetary embryos". Finally, full-sized terrestrial planets accrete from protoplanets and planetesimals. This final stage of accretion lasts about 10-100 Myr and is strongly affected by gravitational perturbations from any gas giant planets, which are constrained to form more quickly, during the 1-10 Myr lifetime of the gaseous component of the disk. It is during this final stage that the bulk compositions and volatile (e.g., water) contents of terrestrial planets are set, depending on their feeding zones and the amount of radial mixing that occurs. The main factors that influence ...

Energy Technology Data Exchange (ETDEWEB)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to ...

Energy Technology Data Exchange (ETDEWEB)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides ...

Energy Technology Data Exchange (ETDEWEB)

Results from ultimate analysis, proximate and petrographic analyses of a wide range of Kentucky coal samples were used to predict coal rank parameters (vitrinite maximum reflectance (R{sub max}) and gross calorific value (GCV)) using multivariable regression and artificial neural network (ANN) methods. Volatile matter, carbon, total sulfur, hydrogen and oxygen were used to predict both R{sub max} and GCV by regression and ANN. Multivariable regression equations to predict R{sub max} and GCV showed R{sup 2} = 0.77 and 0.69, respectively. Results from the ANN method with a 2-5-4-2 arrangement that simultaneously predicts GCV and R{sub max} showed R{sup 2} values of 0.84 and 0.90, respectively, for an independent test data set. The artificial neural network method can be appropriately used to predict R{sub max} and GCV when regression results do not have high accuracy. (author)

International Nuclear Information System (INIS)

Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the disturbance of the sediment. AVS and Simultaneously Extracted Metal (SEM) concentrations were compared to bioassay responses with the freshwater benthic macroinvertebrate Asellus aquaticus. Storage conditions and sediment treatment affected AVS but not SEM levels. AVS can be used as a proxy for sediment disturbance. The best way to pretreat the sediment for use in a bioassay in order to maintain initial AVS conditions was to sample the sediment with an Ekman grab, immediately store it in a jar without headspace, and freeze it as soon as possible. In a survey using seven different sediments, bioassay responses of A. aquaticus were correlated with SEM and AVS characteristics. - ...

Energy Technology Data Exchange (ETDEWEB)

Last year a team of US and French scientists using the Odeillo (France) 1MW/sub th/ solar furnace showed concentrated solar radiation to be an effective means for rapidly volatilizing biomass materials. The results of continuing research in the U.S. on radiant flash pyrolysis of biomass as a source of fluid fuels, industrial feedstocks and chemicals are described. Bench scale sources of intense, visible radiant energy have been used to simulate the concentrated solar flux available at the focus of solar towers. Windowed transport reactors are being developed, which act as cavity receivers for the focused radiant energy and provide a means for direct use of the radiation to rapidly pyrolyze the entering biomass. One of these reactors will be operated at the focus of the Georgia Tech 400kW/sub th/ solar furnace next August. Preliminary results from the bench scale reactor experiments, and plans for the Georgia Tech experiments are detailed.

Energy Technology Data Exchange (ETDEWEB)

The existence, in real-time, of transmission constraints, demand forecasting errors, generator failures, and other factors impose additional costs through the need to run more expensive generation. These costs can appear as a significant component of the wholesale price to demand served by electricity markets operated over transmission networks. In the England & Wales Pool these costs are passed through directly to supply companies. The Transmission System Operator ({open_quotes}TSO{close_quotes}) can exert significant influence on these costs through improved availability of transmission circuits and through appropriate investment, but has no incentive to do so. Since the inception of the Pool, these costs have increased in level and volatility, and have proved difficult to hedge. In response, St Clements Services were instrumental in assisting Pool members to develop an {open_quotes}Uplift Incentive Management Scheme{close_quotes} which has seen controllable ...

International Nuclear Information System (INIS)

As part of their corporate policy on environmental protection, Chevron, has taken an approach to work collaboratively with other industry members, universities and government agencies in phytoremediation research. The petroleum industry is interested in the integration of phytoremediation with the many biotechnology treatment technologies currently being used by the industry. Phytoremediation is a complex technology that does not just transfer wastes to another site, but offers in-situ final use and disposal treatment at sites anywhere in the world. Sites for potential remediation range from abandoned large refineries, chemical plants, or small urban gas stations. Research has focused on the cleanup of metals and hydrocarbons in diverse types of soil, water and groundwater conditions. This includes research into remediation of petroleum contaminants such as total petroleum hydrocarbon (TPH), polynuclear aromatic hydrocarbons as well as benzene in soil and the mechanism that occurs in ...

Energy Technology Data Exchange (ETDEWEB)

Working in partnership with industry, the US Department of Energy`s (DOE`s) Office of Industrial Technologies (OIT) is helping reduce industrial energy use, emissions, and waste while boosting productivity. Operating within the Office of Energy Efficiency and Renewable Energy (EE), OIT conducts research, development, demonstration, and technology transfer efforts that are producing substantial, measurable benefits to industry. This document summarizes some of the impacts of OIT`s programs through 1997. OIT tracks energy savings as well as other benefits associated with the successfully commercialized technologies resulting from OIT-supported research partnerships. Specifically, a chart shows current and cumulative energy savings as well as cumulative reductions of various air pollutants including particulates, volatile organic compounds (VOCs), nitrogen oxides (NO{sub x}), sulfur oxides (SO{sub x}), and the greenhouse gas, carbon dioxide (CO{sub 2}). The bulk of ...

Energy Technology Data Exchange (ETDEWEB)

PWR steam generators have suffered from a variety of degradation phenomena. This paper identifies the corrosion-related defects and their probable causes and suggests approaches to correct and prevent corrosive activity. In the attempt to solve the degradation problems, research programs have concentrated on modifying materials, stresses, and the chemical environment in both new and operating steam generators. The following corrosion-related defects have been studied: tube wastage, denting, primary side (ID) intergranular stress corrosion cracking (IGSCC), OD-initiated intergranular attack (IGA), pitting, and corrosion fatigue. Plants affected by wastage have greatly reduced their problem by adopting an all volatile treatment (AVT). In the case of denting, a less aggressive chemical environment is recommended. Primary side IGSCC responds to temperature reduction, stress relief, and material improvements, while flushing and boric acid addition minimizes OD-initiated ...

Energy Technology Data Exchange (ETDEWEB)

New alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2 (where x ranges between 0 and 1 and preferably has a value of about 0.75) and CuIn.sub.y Ga.sub.(1-y) Se.sub.2 (where y ranges between 0 and 1 and preferably has a value of about 0.90) in the form of single crystals with enhanced structure perfection, which crystals are substantially free of fissures are disclosed. Processes are disclosed for preparing the new alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2. The process includes placing stoichiometric quantities of a Cu, Ag, In, and Se reaction mixture or stoichiometric quantities of a Cu, In, Ga, and Se reaction mixture in a refractory crucible in such a manner that the reaction mixture is surrounded by B.sub.2 O.sub.3, placing the thus loaded crucible in a chamber under a high pressure atmosphere of inert gas to confine the volatile Se to the crucible, and heating the reaction mixture to its melting point. The melt can then be cooled slowly to form, by direct ...

Energy Technology Data Exchange (ETDEWEB)

The authors provide a detailed overview of an on-going, multinational test program that is developing aerosol data for some spent fuel sabotage scenarios on spent fuel transport and storage casks. Experiments are being performed to quantify the aerosolized materials plus volatilized fission products generated from actual spent fuel and surrogate material test rods, due to impact by a high-energy-density device. The program participants in the United States plus Germany, France and the United Kingdom, part of the international Working Group for Sabotage Concerns of Transport and Storage Casks (WGSTSC) have strongly supported and coordinated this research program. Sandia National Laboratories has the lead role for conducting this research program; test program support is provided by both the US Department of Energy and the US Nuclear Regulatory Commission. The authors provide a summary of the overall, multiphase test design and a description of all explosive ...

Energy Technology Data Exchange (ETDEWEB)

Influence of gamma irradiation and storage on the microbial load, chemical and sensory quality of chicken kabab was investigated. Chicken kabab was treated with 0, 2, 4 or 6 kGy doses of gamma irradiation. Treated and untreated samples were kept in a refrigerator (1-4 deg. C). Microbiological, chemical and sensory characteristics of chicken kabab were evaluated at 0-5 months of storage. Gamma irradiation decreased the microbial load and increased the shelf-life of chicken kabab. Irradiation did not influence the major constituents of chicken kabab (moisture, protein and fats). No significant differences (p>0.05) were observed for total acidity between non-irradiated (control) and irradiated chicken kabab. Thiobarbitric acid (TBA) values (expressed as mg malonaldehyde (MDA)/kg chicken kabab) and volatile basic nitrogen (VBN) in chicken kabab were not affected by the irradiation. Sensory evaluation showed no significant differences between irradiated and ...

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment ...

Energy Technology Data Exchange (ETDEWEB)

Using adsorption data, the authors get formulas for the calculation of fractal dimensions: log[A{sub CO{sub 2}(DP)}/A{sub N{sub 2}(BET)}] = {minus}5.3984(2 {minus} D{sub 1})/2 and log[A{sub CO{sub 2}(BET)}/A{sub N{sub 2}(BET)}] = {minus}4.9569(2 {minus} D{sub 2})/2. The fractal dimensions (D) of 27 coals and 2 cokes have been obtained. The D of coals decreased with the increase of f{sub a} and reached a maximum at H/C equal to 0.66 (or C{sub daf} about 86%). The fractal dimension is relative to ash and volatiles of coal: D = 2.2237 + 0.6249 V{sub daf} + 0.8863 A{sub d}. The relationship between D of coal coke and its conversions (X) obeys the following equation: D = a exp({minus}bX) + c.

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400-MWt, sodium-cooled reactor located on the Hanford Site near Richland, Washington, USA. The FFTF is owned by the U.S. Department of Energy and is operated by the Westinghouse Hanford Company. The FFTF was designed to test fuels and materials for use in liquid metal reactors. Since initial operation in 1982, anticipated breaches of experimental fuel pins have released fission products, including cesium, into the primary sodium. Because of its high volatility, cesium vaporizes into the cover gas space, where it condenses on components and equipment and is transported into the cover gas outlet. Because of the long half-life of "1"3"7Cs, these deposits result in long-term, local radiation levels that make contact maintenance difficult. Thus, a cesium trap was installed in FFTF to reduce the cesium level in the sodium. The trap could also permit a Run Beyond Cladding Breach (RBCB) program without compromising the sodium purity. ...

Energy Technology Data Exchange (ETDEWEB)

Relationships of ultimate and proximate analysis of 4540 US coal samples from 25 states with gross calorific value (GCV) have been investigated by regression and artificial neural networks (ANNs) methods. Three set of inputs: (a) volatile matter, ash and moisture (b) C, H, N, O, S and ash (c) C, H{sub exclusive} {sub of} {sub moisture}, N, O{sub exclusive} {sub of} {sub moisture}, S, moisture and ash were used for the prediction of GCV by regression and ANNs. The multivariable regression studies have shown that the model (c) is the most suitable estimator of GCV. Running of the best arranged ANNs structures for the models (a) to (c) and assessment of errors have shown that the ANNs are not better or much different from regression, as a common and understood technique, in the prediction of uncomplicated relationships between proximate and ultimate analysis and coal GCV. (author)

Energy Technology Data Exchange (ETDEWEB)

The mission of the Emerging Technologies thrust area at Lawrence Livermore National Laboratory is to help individuals establish technology areas that have national and commercial impact, and are outside the scope of the existing thrust areas. We continue to encourage innovative ideas that bring quality results to existing programs. We also take as our mission the encouragement of investment in new technology areas that are important to the economic competitiveness of this nation. In fiscal year 1992, we have focused on nine projects, summarized in this report: (1) Tire, Accident, Handling, and Roadway Safety; (2) EXTRANSYT: An Expert System for Advanced Traffic Management; (3) Odin: A High-Power, Underwater, Acoustic Transmitter for Surveillance Applications; (4) Passive Seismic Reservoir Monitoring: Signal Processing Innovations; (5) Paste Extrudable Explosive Aft Charge for Multi-Stage Munitions; (6) A Continuum Model for Reinforced Concrete at High Pressures and Strain Rates: ...

Energy Technology Data Exchange (ETDEWEB)

An experimental investigation was conducted to evaluate the effect of three different oxygenated compounds, diglyme, diethyl maleate and dibutyl maleate, on emissions from a Volkswagen 1.9 litre, turbocharged, direct injection diesel engine. Sampling was performed using a mini-dilution tunnel technique to obtain particulate matter and a Fourier transform infrared (FTIR) spectrometer for gaseous emissions. The particulate samples were analysed using thermal analysis and Soxhlet extraction to determine the fraction of volatile and soluble organic material respectively. All three oxygenated compounds were found to be effective at reducing particulate emissions, with the maleate compounds being more effective overall than the diglyme. Analysis of the relative contributions of changes in the soot and soluble organic fraction (SOF) to the reduction of particulate matter indicated that, for diethyl maleate and diglyme, reductions in soot were the dominant effect. No ...

Energy Technology Data Exchange (ETDEWEB)

The cost of transporting biogas digestate can be decreased by reducing its water content. However, the digestate emits volatile compounds during drying. This study investigated the drying behaviour and the change of digestate composition. Drying took place in a hybrid solar/waste-heat dryer that used solar energy as well as waste heat from a combined heat and power unit (CHP) and the exhaust air of a microturbine. The experiment involved the use of 60 t of liquid digestate. Climatic conditions were measured inside and outside the drying hall. Dry matter (DM) and organic dry matter (ODM) were also measured on a daily basis. In addition, the energy consumption of waste and solar heat were recorded and related to the quantity of dried feedstock. The total nitrogen, ammonium, phosphate, potassium oxide, magnesium oxide and calcium oxide in the digestate were subjected to chemical analysis before and after the drying process. Losses of nitrogen were calculated. Specific ...

Energy Technology Data Exchange (ETDEWEB)

An innovative horizontal drilling system was used to install two horizontal wells as part of an integrated demonstration project at the Savannah River Site (SRS), Aiken, South Carolina. The SRS is located in south-central South Carolina in the upper Coastal Plain physiographic province. The demonstration site is located near the A/M Area, and is currently known as the Integated Demonstration Site. The Department of Energy's Office of Technology Development initiated an integrated demonstration of innovative technologies for cleanup of volatile organic compounds (VOCS) in soils and groundwater at the SRS in 1989. The overall goal of the program is to demonstrate, at a single location, multiple technologies in the fields of drilling, characterization, monitoring, and remediation. Innovative technologies are compared to one another and to baseline technologies in terms of technical performance and cost effectiveness. Transfer of successfully demonstrated ...

Energy Technology Data Exchange (ETDEWEB)

For a better understanding of sulphidation mechanisms, some alloys (alloy 600, alloy 800, Uranus S, iron-chromium-aluminium-alloy) and metals (iron, chromium, nickel, molybdenum, titanium) were tested at 773, 873, 1 073 K in gaseous sulphur dioxide. Total pressure was 760 torrs. Sulphur dioxide pressure was 760, 100 and 10 torrs. Argon, oxygen, water vapor were used, successively, as pressure complement. Oxygen supply, generally speaking cause decay of corrosion resistance in SO/sub 2/ atmospheres especially at 1 073 K with low ratio p/sub O2//P/sub SO/sub 2//. Water vapor supply act similarly. Temperature laws and pressure laws do not give monotonous rise of corrosion values. There are maximas suggesting corrosion products undertaking a volatilization process. According to test conditions, Uranus S, chromium, alloy 800 (and titanium at some extent) showed good corrosion resistance. That results are supporting those obtained by JRC Ispra team, working with ...

Energy Technology Data Exchange (ETDEWEB)

Devolatilization, char combustion and emission characteristics of different single fuel particles were studied under various fluidized bed combustor conditions, in order to develop a classification system which enables prediction of the behaviour of different fuels ranging from fixed carbon rich coals to volatile rich woods and plastics. To investigate formation reaction, the concentration of CO, CO{sub 2}, total hydrocarbons, O{sub 2}, NO and N{sub 2}O were measured continuously. Additionally, temperature histories of the particles were recorded by implanting thermocouples. Devolatilization and char combustion were analysed by an integral and differential method. The integral analysis uses global rates which were compared with the ultimate and proximate analyses and used to classify the fuels. In the differential analysis the single physical and chemical steps viz mass transfer from the bulk gas to the particle surface, mass transfer through the ash layer and ...

International Nuclear Information System (INIS)

High and volatile natural gas prices have increasingly led to calls for investments in renewable energy. One line of argument is that deployment of these resources may lead to reductions in the demand for and price of natural gas. Many recent US-based modeling studies have demonstrated that this effect could provide significant consumer savings. In this article we evaluate these studies, and benchmark their findings against economic theory, other modeling results, and a limited empirical literature. We find that many uncertainties remain regarding the absolute magnitude of this effect, and that the reduction in natural gas prices may not represent an increase in aggregate economic wealth. Nonetheless, we conclude that many of the studies of the impact of renewable energy on natural gas prices appear to have represented this effect within reason, given current knowledge. These studies specifically suggest that a 1% reduction in US natural gas demand could lead to ...

International Nuclear Information System (INIS)

This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur oxides, nitrogen oxides, carbon monoxide, particulate, volatile organic compounds, ammonia and benzene. For ...

Energy Technology Data Exchange (ETDEWEB)

Simultaneously extracted metals (SEM) and acid volatile sulfide (AVS) show the potential for toxicity on the basis of their ratio. Accordingly, the authors spiked cadmium in a range for which Cd/AVS ratios were from 0.2 to 10 in the sediment with its weight about 8 kg in each batch. Dialysis samplers with a cation ion-exchange resin (Dowex 50W-X4) collection were used in a laboratory for the determination of free cadmium concentrations in pore water of the collected sediment. When equilibrium was reached among cadmium in pore water, sediment, and ion-exchange resin, cadmium exchanged onto resin phase was regenerated with 1 N hydrochloric acid (OPTIMA grade) and determined using an atomic absorption spectrophotometer (Zeeman 5000) with a graphite furnace accessory. Cadmium determined using the dialysis sampler is considered as free cadmium which is related to the metal bioavailability toward aquatic biota. The developed methodology provides a new technique for ...

Energy Technology Data Exchange (ETDEWEB)

The relationship between coal properties and liquefaction or gasification characteristics was analyzed by using the analysis and test results and liquefaction characteristics in the coal data base. On liquefaction reaction, the close relation between an oil yield and coal constituent composition or a coal rank is well-known. Various multivariable regression analyses were conducted by using 6 factors as variables such as calorific value, volatile component, O/C and H/C atomic ratios, exinite+vitrinite content and vitrinite reflectance, and liquefaction characteristics as variate. On liquefaction characteristics, the oil yield of dehydrated and deashed coals, asphaltene yield, hydrogen consumption, produced water and gas quantities, and oil+asphaltene yield were predicted. The theoretical gasification efficiency of each specimen was calculated to evaluate the liquefaction reaction obtained. As a result, the oil yield increased with H/C atomic ratio, while the ...

Science.gov (United States)

This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some cases the levels exceeded the ...

Energy Technology Data Exchange (ETDEWEB)

Volatile organic compounds (VOC) are an important group of pollutants with adverse effects on humans and the environment. Primary air pollution abatement measures aim at prevention or reduction of pollutant production in industrial production processes, e.g. by improved processes but also by other methods (closed cycle processes, different process materials, etc.). If these measures have been implemented and emissions are still too high, an off-air purification unit must be installed. Biological purification is the method of choice for low pollutant concentrations. Biological purification processes are based on the activity of microorganisms which are capable of biochemical oxidation of organic and some inorganic gaseous compounds into non-polluting or non-odorous compounds. These processes have the advantage that they work at ambient conditions and therefore remove relatively low pollutant concentrations at low investment and operating cost. Lately, biological ...

Energy Technology Data Exchange (ETDEWEB)

This document gathers the available presentations (articles and transparencies) given at this annual meeting, the 2007 topic of which was the technological, geopolitical, economical, environmental, societal and development stakes of energy. 1 - technological stakes - which energies for the future: new energies, illusion or solution of the future; the Lorraine region, an energy land: strategies and stakes for a sustainable development; from China to Brazil: understanding the nuclear energy revival; hydroelectric power: renewable and sustainable energy; renewable energies and environment protection: the contribution of biofuels; wind power in Germany between success and contestation; 2 - geopolitical stakes - energy levier of power: the Gulf of Guinea hydrocarbons: between development and geopolitics; the complex evaluation of resources and reserves between technology, market and geopolitics; the new Bakou-Tbilissi-Ceyhan pipeline: what impacts for Turkey and the European Union; 3 - ...

Energy Technology Data Exchange (ETDEWEB)

This paper presents a numerical study on the formation history of coalbed methane (CBM) reservoir in the southeast edge of Ordos Basin, China. The coal seams studied belong to the Late Palaeozoic coal-bearing series. These coal seams have a burial history and experienced the process of subsidence, rapid subsidence alternated with uplift and then uplift, sequentially, and underwent the geothermal actions at normal, extremely high, and then normal temperatures, respectively. Coal organic matter of the coal seams matured in the Triassic Period and in the Late Jurassic to Early Cretaceous Period. The results from numerical simulation reveal that CBM reservoir evolution history can be classified into five stages, namely primary, initial, stagnant, active and dissipative stages. In the first (primary) stage, coal rank was very low and there was little methane generated and stored in the coal seams. In the second (initial) stage, the coal was converted to middle-high ...

Energy Technology Data Exchange (ETDEWEB)

Acute thoracic aortic injuries account for up to 10-20% of fatalities in high-speed deceleration road accidents and have an estimated immediate fatality rate of 80-90%. Untreated survivors to acute trauma (10-20%) have a dismal prognosis: 30% of them die within 6 hours, 40-50% die within 24 hours, and 90% within 4 months. It was investigated the diagnostic accuracy of Helical Computed Tomography (Helical CT) in acute traumatic injuries of the thoracic aorta, and the role of this technique in the diagnostic management of trauma patients with a strong suspicion of aortic rupture. It was compared retrospectively the chest Helical CT findings of 256 trauma patients examined June 1995 through August 1999. Chest Helical CT examinations were performed according to trauma score, to associated traumatic lesions and to plain chest radiographic findings. All the examinations were performed with no intravenous contrast agent administration and the pitch 2 technique. After a ...

Energy Technology Data Exchange (ETDEWEB)

This is the first time that the adsorption of binary mixtures of polycyclic aromatic hydrocarbons (PAHs) has been studied. This study was carried out at laboratory scale in an experimental apparatus specially designed for this aim: with gas-phase fluorescence, a new detection procedure was used. Experimental conditions, mainly in terms of temperature (150C) and contaminant concentration (approximately 1 ppmv), close to the ones observed in energy generation systems, were applied. The PAH adsorption process interpretation was carried out by recording the experimentally obtained breakthrough curves. After the detection parameter optimization, the influence of adsorbate characteristics in the hot gas cleaning of PAH was studied. In this system, the adsorption of 10 binary mixtures of five PAH (naphthalene (Np), fluorene (Fu), phenanthrene (Phe), fluoranthene (Fl), and pyrene (Py)) on an activated carbon was investigated. It was found that the adsorbent efficiency is always determined by ...

International Nuclear Information System (INIS)

Since 1975 All Volatile Treatment (AVT) has been the preferred method for controlling the secondary system operating environment in Westinghouse PWR plants. However, since AVT provides no buffering action against corrodent species present in the water as trace contaminants, utilities have initiated programs which combine control of contaminant ingress with total steam generator sludge management. The earliest applications of boric acid, to control denting type corrosion, began in 1978 and have continued up to the present time. Boric Acid has also been added as an inhibitor for SCC/IGA type corrosion since 1985. There are now approximately 30 plants operating with boric acid or boric acid/morpholine chemistry in the secondary system, and a growing number of plants where morpholine is being used as an additive to maintain pH and reduce iron transport attributable to erosion/corrosion. The impact of these modifications in the operating chemistry environment are ...

Energy Technology Data Exchange (ETDEWEB)

This guide describes the simulator`s governing equations, constitutive functions and numerical solution algorithms of the STOMP (Subsurface Transport Over Multiple Phases) simulator, a scientific tool for analyzing multiple phase subsurface flow and transport. The STOMP simulator`s fundamental purpose is to produce numerical predictions of thermal and hydrologic flow and transport phenomena in variably saturated subsurface environments, which are contaminated with volatile or nonvolatile organic compounds. Auxiliary applications include numerical predictions of solute transport processes including radioactive chain decay processes. In writing these guides for the STOMP simulator, the authors have assumed that the reader comprehends concepts and theories associated with multiple-phase hydrology, heat transfer, thermodynamics, radioactive chain decay, and nonhysteretic relative permeability, saturation-capillary pressure constitutive functions. The authors further ...

Science.gov (United States)

The production of any form of coke is determined mainly by the raw material costs. Consequently for the production of special coke, of which the demand is satisfied at the present time by small size fractions of beehive coke or even blast furnace coke, it is necessary to use not only the plentiful coals but also the brown coals of the Kansk-Achinsk coalfield where mining is being expanded. The large reserves of the Kansk-Achinsk brown coals and the favorable geological conditions for recovery by the open-cast method make it possible to increase coal extraction from 31.6.10/sup 6/ tons in 1978 to 350.10/sup 6/ tons/yr in the next 15 to 20 years. In order to explain the high reactivity of heat treated brown coals we shall compare their properties with bituminous coal coke. During the heating of bituminous coals (with a high voltatile matter content) they are able to be weakly fused, to form a structure of coke whose pores are smooth because the coal is partially transformed into a ...

Energy Technology Data Exchange (ETDEWEB)

The coalbed methane (CBM) geology, resource and production potential in the Weibei Coalfield, southeastern Ordos Basin are studied based on geological surveys and laboratory measurements. The results showed that coal rank varies both laterally and vertically and changes from volatile bituminous coals in the margin to anthracites towards the basin (1.6-2.5% R{sub o}). Coals are composed of 60-85% vitrinite, 15-40% inertinite and a trace amount of minerals. Methane isothermal adsorption measurements of 20 coal samples revealed that the maximum adsorption capacity (on a dry and ash-free basis) of coals, which are affected by coal rank, coal maceral, coal lithotype and especially to the moisture content, varies from 13.91 to 29.54 m{sup 3}/t. Estimated gas contents range from 0 to 15 m{sup 3}/t. These data yield an estimated in-place CBM resource of 2.5 x 10{sup 11} m{sup 3} for the Weibei Coalfield. In combination with the geological information, the data indicated ...