WorldWideScience
1

Fourier-transform infrared anisotropy in cross and parallel sections of tendon and articular cartilage  

UK PubMed Central (United Kingdom)

BackgroundFourier Transform Infrared Imaging (FTIRI) is used to investigate the amide anisotropies at different surfaces of a three-dimensional cartilage or tendon block. With the...Full Text Available

2

Sidelobe Suppression in an Acousto-Optic Filer with a Raised ...  

Science.gov (United States)

... Abstract : The acousto-optic filter (AOF) is ... for large switch networks. ... FOURIER TRANSFORMATION, OPTICAL SWITCHING, SURFACE ACOUSTIC ...

1992-04-01

3

The forward modeling and reverse time migration of seismic wave field in complex medium  

Energy Technology Data Exchange (ETDEWEB)

The space derivation term of a wave equation is accurately calculated using Fourier transform method, and the wave equation only relating to time derivative in time-space domain is derived. Solving this equation with the aid of central difference method brings the numerical recursion formula for forward modeling or reverse time migration of seismic wave field in the medium in which seismic velocity varies. The key to this method lies in introducing two auxiliary wave fields relating to velocity and spacial frequency of Fourier transform respectively after multi-dimensional Fourier transform respectively after multi-dimensional Fourier transform of space vector is made. Theoretically, this method is suitable to the forward modeling and migration of seismic wave field in complex area where seismic velocity and structure ...

1988-01-01

4

Optical Spectroscopy for Noninvasive Monitoring of Stem Cell Differentiation  

UK PubMed Central (United Kingdom)

There is a requirement for a noninvasive technique to monitor stem cell differentiation. Several candidates based on optical spectroscopy are discussed in this review: Fourier transform infrared (FTIR)...Full Text Available

2010-01-01

6

The analysis of coupled heat and particle transport in Tokamaks by means of Fourier transform  

Energy Technology Data Exchange (ETDEWEB)

A method to deduce the 2 x 2 transport matrix for coupled heat and particle transport in Tokamaks is proposed. The method applies to perturbative experiments, and is based on a Fourier transform of the measured signals of temperature and density. By analyzing different linear combinations of temperature and density, the eigenvectors and eigenvalues of the transport matrix are determined. The method is tested for a number of illustrative cases using simulated data, and the sensitivity to noise on the signals is evaluated. (author).

1992-04-01

7

Quantum Discrete Fourier Transform in an Ion Trap System  

International Nuclear Information System (INIS)

We propose two schemes for the implementation of quantum discrete Fourier transform in the ion trap system. In each scheme we design a tunable two-qubit phase gate as the main ingredient. The experimental implementation of the schemes would be an important step toward complex quantum computation in the ion trap system.

2007-06-15

8

Cesium ion desorption ionization with Fourier transform mass spectrometry  

International Nuclear Information System (INIS)

Cesium ions (Cs"+) are used for the production of the feed ions necessary to obtain Fourier transform mass spectra (FTMS). The molecule chosen for the initial study of this Cs"+ desorption ionization (DI-FTMS) was vitamin B-12 because of its nonvolatile, thermally labile character. 21 references.

9

Transformation by complementation of an adenine auxotroph of the lignin-degrading basidiomycete Phanerochaete chrysosporium  

Science.gov (United States)

Swollen basiodiospores of an adenine auxotroph of Phanerochaete chrysosporium were protoplasted with Novozyme 234 and transformed to prototrophy by using a plasmid containing the gene for an adenine biosynthetic enzyme from Schizophyllum commune. Transformation frequencies of 100 transformants per {mu}g of DNA were obtained. Southern blot analysis of DNA extracted from transformants demonstrated that plasmid DNA was integrated into the chromosomal DNA in multiple tandem copies. Analysis of conidia and basiodiospores from transformants demonstrated that the transforming character was mitotically and meiotically stable on both selective and nonselective media. Genetic crosses between double mutants transformed for adenine prototrophy and other auxotrophic strains yielded Ade{sup {minus}} progeny, which indicated that ...

1989-02-01

10

Optimal oscillation-center transformations  

Energy Technology Data Exchange (ETDEWEB)

A variational principle is proposed for defining that canonical transformation, continuously connected with the identity transformation, which minimizes the residual, coordinate-dependent part of the new Hamiltonian. The principle is based on minimization of the mean-square generalized force. The transformation reduces to the action-angle transformation in that part of the phase space of an integrable system where the orbit topology is that of the unperturbed system, or on primary KAM surfaces. General arguments in favor of this definition are given, based on Galilean invariance, decay of the Fourier spectrum, and its ability to include external fields or inhomogeneous systems. The optimal oscillation-center transformation for the physical pendulum, or particle in a sinusoidal potential, is constructed.

1984-08-01

11

Computational Complexity of Cyclotomic Fast Fourier Transforms over Characteristic-2 Fields  

CERN Document Server

Cyclotomic fast Fourier transforms (CFFTs) are efficient implementations of discrete Fourier transforms over finite fields, which have widespread applications in cryptography and error control codes. They are of great interest because of their low multiplicative and overall complexities. However, their advantages are shown by inspection in the literature, and there is no asymptotic computational complexity analysis for CFFTs. Their high additive complexity also incurs difficulties in hardware implementations. In this paper, we derive the bounds for the multiplicative and additive complexities of CFFTs, respectively. Our results confirm that CFFTs have the smallest multiplicative complexities among all known algorithms while their additive complexities render them asymptotically suboptimal. However, CFFTs remain valuable as they have the smallest overall complexities for most practical lengths. Our ...

2011-01-01

12

Fourier Transform Infrared Imaging and MR Microscopy Studies Detect Compositional and Structural Changes in Cartilage in a Rabbit Model of Osteoarthritis  

UK PubMed Central (United Kingdom)

Assessment of subtle changes in the primary macromolecular components of cartilage, proteoglycan (PG) and collagen, is critical for the diagnosis of early stages of osteoarthritis (OA), but...Full Text Available

2007-03-01

13

Bone Quality determined by Fourier Transform Infrared Imaging Analysis in Mild Primary Hyperparathyroidism  

UK PubMed Central (United Kingdom)

Context: Mild primary hyperparathyroidism (PHPT) is characterized by asymptomatic hypercalcemia, most commonly in the absence of classical signs and symptoms. Hence, there is need to characterize...Full Text Available

2008-09-01

14

Use of real-time Fourier Transform Infrared Reflectivity as an in situ monitor of YBCO film growth and processing  

CERN Document Server

Fourier Transform Infrared (FTIR) spectroscopy has been utilized during high rate E-beam evaporation/deposition of YBa2Cu3O7 (YBCO). The results demonstrate the great utility of FTIR as an in situ monitor of YBCO deposition and processing. We detect different (amorphous/fine polycrystalline) insulating pre-existing phases to the high Tc superconducting phase which appear to have distinct reflectivity fingerprints dominated by thin film interference effects, as a function of temperature and oxygen pressure. These fingerprints reveal some of the kinetic and thermodynamic pathways during the growth of YBCO.

2007-01-01

15

A quantitative method to detect explosives and selected semivolatiles in soil samples by Fourier transform infrared spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a novel Fourier transform infrared (FTIR) spectroscopic method that can be used to rapidly screen soil samples from potentially hazardous waste sites. Samples are heated in a thermal desorption unit and the resultant vapors are collected and analyzed in a long-path gas cell mounted in a FTIR. Laboratory analysis of a soil sample by FTIR takes approximately 10 minutes. This method has been developed to identify and quantify microgram concentrations of explosives in soil samples and is directly applicable to the detection of selected volatile organics, semivolatile organics, and pesticides.

1995-06-01

16

Vibrations of circular cylindrical shells  

Science.gov (United States)

An exact solution method for the free vibration problem of thin circular cylindrical shells is presented. The differential equations of motion are solved directly with the use of simple Fourier series as the modal displacement functions. Stokes' transformation is exploited to obtain correct series expressions for the derivatives of the Fourier series. From this method an explicit expression of the exact frequency equation can be obtained for any kind of boundary conditions. The accuracy of the present method is checked against available data. The proposed method is then used to find the modal characteristics of the thermal liner of the Fast Test Reactor (FTR). The numerical results obtained are compared with finite element method solutions. (auth)

1975-07-01

17

Surface analysis by Fourier-transform infrared (FTIR) spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400/sup 0/C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures.

1981-08-12

18

Monitoring amino acids, organic acids, and ripening changes in Cheddar cheese using Fourier-transform infrared spectroscopy  

British Library Electronic Table of Contents (United Kingdom)

Fourier-transform infrared (FTIR) spectroscopy was used to monitor amino acids, organic acids, and changes during ripening. Twelve Cheddar cheese samples were ripened for 73 days and samples were drawn periodically. Water-soluble fractions of samples were analyzed by gas chromatography (20 amino acids), liquid chromatography (three organic acids), and FTIR spectroscopy (4000-700 cm-1). Spectra were correlated with chromatographic data and ripening events and analyzed by multivariate statistics to develop prediction and classification models. Most models showed a good fit (correlation coefficient > or =0.89) and could predict the levels of amino acids and organic acids and age of the cheese in less than 20 min. Lactic acid, leucine, glutamic acid, asparagine, phenylalanine, and valine were ...

2011-01-01

19

Fourier transform IR studies on the interaction of selected chemicals with isolated cuticles  

International Nuclear Information System (INIS)

It is known that the plant cuticle represents the first barrier that must be overcome by any chemical reaching the plant surface from the atmosphere before entering the plant. Because of the importance of the cuticle as a barrier to penetration of a wide variety of compounds, its morphology, chemistry, and permeability have been extensively studied. However, only limited information is available on the nature of functional chemical groups present and their interaction and role during the penetration process. The usefulness of in situ Fourier transform infrared spectroscopy studies in identifying functional groups present in isolated cuticles is described and their relationships to the structure of the cuticular membrane are discussed. Applications of infrared spectroscopy on the presence and role of phenolics in the cuticle structure and during the cuticle development, nitrogen oxide binding to isolated cuticles, and the interactions between ...

20

Electron Capture Dissociation Implementation Progress in Fourier Transform Ion Cyclotron Resonance Mass Spectrometry  

British Library Electronic Table of Contents (United Kingdom)

Successful electron capture dissociation (ECD) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) applications to peptide and protein structural analysis have been enabled by constant progress in implementation of improved electron injection techniques. The rate of ECD product ion formation has been increased to match the liquid chromatography and capillary electrophoresis timescales, and ECD has been combined with infrared multiphoton dissociation in a single experimental configuration to provide simultaneous irradiation, fast switching between the two techniques, and good spatial overlap between ion, photon, and electron beams. Here we begin by describing advantages and disadvantages of the various existing electron injection techniques for ECD in FT-ICR MS. We next ...

2008-01-01

21

Algebraic Topology Foundations of Supersymmetry and Symmetry Breaking in Quantum Field Theory and Quantum Gravity: A Review  

CERN Document Server

A novel algebraic topology approach to supersymmetry (SUSY) and symmetry breaking in quantum field and quantum gravity theories is presented with a view to developing a wide range of physical applications. These include: controlled nuclear fusion and other nuclear reaction studies in quantum chromodynamics, nonlinear physics at high energy densities, dynamic Jahn-Teller effects, superfluidity, high temperature superconductors, multiple scattering by molecular systems, molecular or atomic paracrystal structures, nanomaterials, ferromagnetism in glassy materials, spin glasses, quantum phase transitions and supergravity. This approach requires a unified conceptual framework that utilizes extended symmetries and quantum groupoid, algebroid and functorial representations of non-Abelian higher dimensional structures pertinent to quantized spacetime topology and state space geometry of quantum operator algebras. Fourier transforms, generalized ...

2009-01-01

22

Ferrihydrite phase transformation in the presence of aqueous sulfide and supercritical CO2  

British Library Electronic Table of Contents (United Kingdom)

The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...

2010-01-01

23

Longitudinal and transverse mode evolution in free electron laser  

Energy Technology Data Exchange (ETDEWEB)

We use the method of Padg approximants and Fourier transform techniques to treat analytically the problem of transverse and longitudinal mode evolution in FELs. We obtain simple relations providing a transparent understanding of the dynamic of pulse propagation effects and of transverse mode guiding. We discuss the interplay with inhomogeneous broadening effects and derive gain formulae including longitudinal and transverse mode couplings.

1995-12-31

24

Discrete phase retrieval in musical structures  

British Library Electronic Table of Contents (United Kingdom)

This paper describes phase-retrieval approaches in music by focusing on the particular case of the cyclic groups (beltway problem). After presenting some old and new results on phase retrieval, we introduce the extended phase retrieval for a generalized musical Z-relation. This concept is accompanied by mathematical definitions and motivations from computer-aided composition. We assume from the reader basic knowledge of groups, topological groups, group algebras, group actions, Lebesgue integration, convolution products, and Fourier transform.

2011-01-01

25

Dielectric barrier discharge using corona-modified silicone rubber  

Science.gov (United States)

Results from scanning electron microscopy, Fourier transform infrared spectroscopy and the measurement of thermally stimulated current show that a high density of the physical defects and the chemical defects are introduced into the surface of the silicone rubber plates after they are treated by corona discharge plasma. These defects behave electrically as shallow electron traps, leading to the formation of a uniform discharge in air at higher pressure when the corona-modified silicone rubber is used in dielectric barrier discharge.

2008-10-01

26

Absolute absorption of ozone in the midinfrared  

Energy Technology Data Exchange (ETDEWEB)

The absolute absorption of ozone in the midinfrared has been measured relative to 253.7-nm ultraviolet absorption to an accuracy of 1% using a Bruker Fourier transform spectrometer. These new results agree with previous measurements by diode laser measurements after the latter are corrected for more recent infrared calculations and ultraviolet cross sections. They also agree with a determination based on refractive index measurements in the infrared. 16 refs., 4 figs., 3 tabs.

1992-12-20

27

Ab initio calculations in a uniform magnetic field using periodic supercells  

Energy Technology Data Exchange (ETDEWEB)

We present a formulation of ab initio electronic structure calculations in a finite magnetic field, which retains the simplicity and efficiency of techniques widely used in first principles molecular dynamics simulations, based on plane-wave basis sets and Fourier transforms. In addition we discuss results obtained with this method for the energy spectrum of interacting electrons in quantum wells, and for the electronic properties of dense fluid deuterium in a uniform magnetic field.

2003-10-21

28

Energy saving dc-dc converter circuit  

Energy Technology Data Exchange (ETDEWEB)

An energy saving dc-dc converter circuit is disclosed having two energy efficient means which operate in tandem, an energy conserving means and a voltage doubling means. These energy efficient means are applied in combination with elements commonly found in dc-dc converter circuits, namely an ac voltage generator, a transformer for stepping up the generated ac voltage, and means for storing the converted dc voltage. The energy conserving means is connected to the dc voltage storage means. It comprises a resettable inhibit circuit which cuts off the provision of dc voltage for conversion for a predetermined interval when the output of the converter exceeds a predetermined level. The voltage doubling means is reponsive to outputs of the inhibit circuit of the energy conserving means and the ac voltage generator. It provides a phase inverted waveform of the generated ac voltage on one of two leads to the ac voltage step-up ...

1982-06-22

29

The optimization of gamma spectra processing in prompt gamma neutron activation analysis (PGNAA)  

International Nuclear Information System (INIS)

The uncertainty of the elemental analysis is one of the major factors governing the utility of on-line Prompt Gamma Neutron Activation Analysis (PGNAA) in the blending and sorting of bulk materials. In this paper, a general method applicable to Gamma spectra processing is presented and applied to PGNAA in mineral industry. Based on the Fourier transform of spectra and their de-correlation in the Fourier space (the improvement of the conditioning of the correlation matrix), processing of overlapping of characteristic peaks minimizes the propagation of random errors, which optimizes the accuracy and decreases the detection limits of elemental analyses. In comparison with classical methods based on the linear combinations of relevant regions of spectra the improvement may be considerable, especially when several elements are interfering. The method is applied to four case stories covering both borehole logging and on-line ...

2009-04-15

30

Structure analysis of cation selective Cr-goethite as protective rust of weathering steel  

International Nuclear Information System (INIS)

We have performed extended X-ray absorption fine structure (EXAFS) analysis for artificial Cr-goethite to elucidate the local structure around Cr in Cr-goethite. The spectra were obtained using synchrotron radiation X-rays at the Photon Factory in Tsukuba. The first shell contributions were isolated by Fourier filtering EXAFS data, and the inverse Fourier transformed single-shell data were analyzed using a curve fitting method. The results show that Cr is coordinated with (7#+-#1)O"2"- ions. The protective characteristics of the Cr-goethite protective rust layer on weathering steel can be interpreted in terms of the O"2"- coordination around Cr"3"+ resulting in the creation of negative fixed charge in the Cr-goethite particles. (author)

2005-02-01

31

Phase Information and the Evolution of Cosmological Density Perturbations  

CERN Document Server

The Fourier transform of cosmological density perturbations can be represented in terms of amplitudes and phases for each Fourier mode. We investigate the phase evolution of these modes using a mixture of analytical and numerical techniques. Using a toy model of one-dimensional perturbations evolving under the Zel'dovich approximation as an initial motivation, we develop a statistic that quantifies the information content of the distribution of phases. Using numerical simulations beginning with more realistic Gaussian random-phase initial conditions, we show that the information content of the phases grows from zero in the initial conditions, first slowly and then rapidly when structures become non-linear. This growth of phase information can be expressed in terms of an effective entropy: Gaussian initial conditions are a maximum entropy realisation of the initial power spectrum, gravitational evolution decreases the phase ...

2000-01-01

32

Predicting neuronal responses during natural vision.  

Science.gov (United States)

A model that fully describes the response properties of visual neurons must be able to predict their activity during natural vision. While many models have been proposed for the visual system, few have ever been tested against this criterion. To address this issue, we have developed a general framework for fitting and validating nonlinear models of visual neurons using natural visual stimuli. Our approach derives from linear spatiotemporal receptive field (STRF) analysis, which has frequently been used to study the visual system. However, prior to the linear filtering stage typical of STRFs, a linearizing transformation is applied to the stimulus to account for nonlinear response properties. We used this approach to compare two models for neurons in primary visual cortex: a nonlinear Fourier power model, which accounts for spatial phase invariant tuning, and a traditional linear model. We characterized prediction accuracy in terms of the total ...

33

Time-resolved Fourier transform emission spectroscopy of A2P-X2+ infrared transition of the CN radical  

British Library Electronic Table of Contents (United Kingdom)

The A2P-X2+Dv=-3 bands of the 12C14N radical have been observed by time-resolved Fourier transform spectroscopy in the 1850-3100cm-1 region with a wavenumber resolution of 0.025cm-1. The radical was produced in a pulsed positive column discharge in a cyanogene and helium mixture. Seven bands of v=0-3, 1-4, 2-5, 3-6, 4-7, 5-8, and 6-9 were analyzed to give the molecular constants of each state by least-squares fitting of 801 lines. The pulsed discharge was found to be efficient for production of CN in the excited A2P state. The vibrational excitation temperature was determined to be 6680+-835K and 6757+-534K for the A2P and X2+ states, respectively. The population of the A2P was found to be 4% of that of the X2+ state in the time after turning off the discharge.

2008-01-01

34

Real Paley-Wiener theorems and local spectral radius formulas  

CERN Document Server

We systematically develop real Paley-Wiener theory for the Fourier transform on R^d for Schwartz functions, L^p-functions and distributions, in an elementary treatment based on the inversion theorem. As an application, we show how versions of classical Paley-Wiener theorems can be derived from the real ones via an approach which does not involve domain shifting and which may be put to good use for other transforms of Fourier type as well. An explanation is also given why the easily applied classical Paley-Wiener theorems are unlikely to be able to yield information about the support of a function or distribution which is more precise than giving its convex hull, whereas real Paley-Wiener theorems can be used to reconstruct the support precisely, albeit at the cost of combinatorial complexity. We indicate a possible application of real Paley-Wiener theory to partial differential equations in this vein ...

2008-01-01

35

Matrix-assisted laser desorption fourier transform mass spectrometry for biological compounds  

Science.gov (United States)

The recent development of matrix-assisted UV laser desorption (LD) mass spectrometry has made possible the ionization and detection of extremely large molecules (with molecular weights exceeding 100,000 Daltons). This technique has generated enormous interest in the biological community for the direct examination of large peptides and oligonucleotides. Although this matrix-assisted ionization method has been developed and used almost exclusively with time-of-flight (TOF) mass spectrometers, research is currently in progress to demonstrate this technique with trapped ion mass spectrometers, such as Fourier transform ion cyclotron resonance mass spectrometry (FTMS). The potential capabilities of FTMS for wide mass range, high resolution measurement, and ion trapping experiments suggest that this instrumental technique should be useful for the detailed structural characterization of large ions generated by the matrix-assisted technique. We have ...

1990-01-01

36

Identification of protein phosphorylation sites within Ser/Thr-rich cluster domains using site-directed mutagenesis and hybrid linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

We describe a method for the analysis of multi-site phosphorylation in serine/threonine (Ser/Thr)-rich protein sequences. Site-specific mutagenesis was used to introduce tryptic cleavage sites in the serine glutamine/threonine glutamine cluster domain (SCD) of the human checkpoint protein kinase (Chk2). The mutant proteins were shown to autophosphorylate on residues that are inducibly phosphorylated when mammalian cells are exposed to ionizing radiation (serine 33/35, serine 516, threonine 68 and threonine 432). Five Ser/Thr clusters within the SCD were flanked by arginine or lysine residues to produce tryptic peptides for nanospray liquid chromatography (nanoLC)/linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry. Phosphorylation sites were assigned usin...

2007-01-01

37

Fluctuation properties of strength function phenomena: A model study  

Energy Technology Data Exchange (ETDEWEB)

We study fluctuation properties of strength function phenomena by employing a quantum mechanical model where a single parent state couples with a large number of background states. The background system is devised in such a way that the classical dynamics of the system may show a regular, an irregular, or a chaotic character as a function of a single parameter. The coupling of the parent state to the background states produces a fragmentation of the parent state, giving rise to a strength function phenomenon. We study various measures of the strength function that characterize its bulk structure or fluctuation properties. They include energy moments, strength distribution, fractal dimensions of the strength function, and Fourier transform of the autocorrelation function. Some of these measures, such as strength distribution or Fourier transform of the autocorrelation function, reflect characteristic ...

1997-07-01

38

Analysis of S-adenosylmethionine and related sulfur metabolites in bacterial isolates of Pseudomonas aeruginosa (BAA-47) by liquid chromatography/electrospray ionization coupled to a hybrid linear quadrupole ion trap and Fourier transform ion cyclotron resonance mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

A comprehensive and highly selective method for detecting in bacterial supernatants a modified sulfur nucleoside, S-adenosyl-L-methionine (SAM), and its metabolites, i.e., S-adenosylhomocysteine (SAH), adenosine (Ado), 5prime-deoxy-5prime-methylthioadenosine (MTA), adenine (Ade), S-adenosyl-methioninamine (dcSAM), homocysteine (Hcy) and methionine (Met), was developed. The method is based on reversed-phase liquid chromatography with positive electrospray ionization (ESI+) coupled to a hybrid linear quadrupole ion trap (LTQ) and 7-T Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS). A gradient elution was employed with a binary solvent of 0.05 M ammonium formate at pH 4 and acetonitrile. The assay involves a simultaneous cleanup of cell-free bacterial broths by solid-pha...

2009-01-01

39

Acidic and neutral polar NSO compounds in Smackover oils of different thermal maturity revealed by electrospray high field Fourier transform ion cyclotron resonance mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

Negative ion electrospray ionization (ESI) coupled with high field Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) allows for the direct detection of acidic NSO compounds in petroleum. The technique requires no chromatographic separation, is able to distinguish 18 different compound classes (e.g., neutral nitrogen, carboxylic acids and oxygenates), and can identify {approx}14,000 distinct masses by ultra-high mass resolution and mass accuracy. We previously studied three crude oils from different geological origins [Organic Geochemistry 33 (2002b) 743-759]. Here, we expand our research by comparing two source-equivalent Smackover oils of different levels of thermal maturity. We observe clear differences in the distribution of NSO compound classes, types (number of rings plus double bonds within a class), and number of alkyl carbons. With increasing thermal stress, the relative amount of sulfur and oxygen containing ...

2004-07-01

40

Vibrational spectroscopy of silica sol-gel components during microwave irradiation  

Energy Technology Data Exchange (ETDEWEB)

In order to study the effects of microwaves on chemical reactions equipment was designed to acquire in-situ vibrational spectra of sol-gel components as they are irradiated with microwaves. Fourier Transform Infrared (FTIR) and Raman spectroscopy were used. A low temperature (10K) FTIR cell was used to trap samples in an argon matrix at 10{sup -7} Torr. For the liquid samples no differences were seen in spectra of irradiated and nonirradiated samples, but the argon matrix isolation technique showed dramatic differences.

1995-12-31

41

Synthesis and characterization of Rosebengal/folicacid-functionalized multiwall carbon nanotubes  

British Library Electronic Table of Contents (United Kingdom)

Multiwall carbon nanotubes (MWCNTs) were functionalized with a photosensitizer, rosebengal (RB), and folicacid (FA), an anti-cancer drug simultaneously and individually, which was characterized with various analytical instruments like Fourier Transform Iinfrared (FTIR) spectroscopy, UV?Vis spectroscopy, Thermogravimetric analysis (TGA), Photoluminescence (PL) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Transmission electron microscopy (TEM). FTIR spectra confirmed the chemical modification of MWCNT. The chemical functionalization of MWCNT with RB was further supported by UV?Vis and PL spectra.

2011-01-01

42

State-of-the-art technique for power system stabilizer tuning  

Energy Technology Data Exchange (ETDEWEB)

Power System Stabilizers (PSS) have broad application throughout the world. PSS application requires careful tuning which is usually accomplished in the field with the generator and power system in an abnormal condition. Recently developed equipment which combines fast Fourier transform capability with digital computer technique provides a means of PSS tuning which is faster and more accurate than was previously obtainable. This paper describes a PSS tuning test conducted using the new technique. The advantages will be apparent to the reader. The described test is very poignant as evidenced by two unexpected occurrences of instability.

1983-03-01

43

Interpretation of EXAFS data from laser shock compressed plasmas  

Energy Technology Data Exchange (ETDEWEB)

Measurements on laser shock compressed aluminium using the EXAFS (Extended X-ray Absorption Fine Structure) technique on the Al K-edge are described. Two methods of analysis of this data were used for the determination of density: the standard EXAFS technique using Fourier transforms and curve fitting, and a method based on a bandstructure calculation of the absorption spectra as a function of compression. These two techniques give results which are in fairly good agreement with each other and also with a hydrodynamic simulation of the experiment. The ion correlation parameter is estimated and shows that two-sided laser irradiation of aluminium foils produces a dense plasma which is strongly coupled. (author).

1989-01-01

44

Discrete simulation of power law noise  

CERN Document Server

A method for simulating power law noise in clocks and oscillators is presented based on modification of the spectrum of white phase noise, then Fourier transforming to the time domain. Symmetric real matrices are introduced whose traces--the sums of their eigenvalues--are equal to the Allan variances, in overlapping or non-overlapping forms, as well as for the corresponding forms of the modified Allan variance. Diagonalization of these matrices leads to expressions for the probability distributions for observing a variance at an arbitrary value of the sampling or averaging interval $\\tau$, and hence for estimating confidence in the measurements. A number of applications are presented for the common power-law noises.

2011-01-01

45

Decontamination of the chemical warfare agent simulant dimethyl methylphosphonate by means of large-area low-temperature atmospheric pressure plasma  

British Library Electronic Table of Contents (United Kingdom)

Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.

2009-01-01

46

The Advanced Loose Parts Monitoring System (ALPS) and wavelet analysis  

International Nuclear Information System (INIS)

The Advanced Loose Parts monitoring System (ALPS), is installed in each Unit of Paks NPP. Its characteristics and some interesting results are presented. Wavelet analysis is being introduced to data evaluation techniques. The short-time Fourier transform and the continuous wavelet transform techniques have been used to present the time signal in a time-frequency and time-scale plane. Characteristic frequencies of the physical acoustic system and the growing frequencies of spectrum components during the start-up of the main coolant pumps are clearly seen on those pictures. The newly applied wavelet coherence promises to find new oscillation in the pair of signals, which remain hidden in time-dependent autospectra. (author)

47

Partition Functions of Normal Factor Graphs  

CERN Document Server

One of the most common types of functions in mathematics, physics, and engineering is a sum of products, sometimes called a partition function. After "normalization," a sum of products has a natural graphical representation, called a normal factor graph (NFG), in which vertices represent factors, edges represent internal variables, and half-edges represent the external variables of the partition function. In physics, so-called trace diagrams share similar features. We believe that the conceptual framework of representing sums of products as partition functions of NFGs is an important and intuitive paradigm that, surprisingly, does not seem to have been introduced explicitly in the previous factor graph literature. Of particular interest are NFG modifications that leave the partition function invariant. A simple subclass of such NFG modifications offers a unifying view of the Fourier transform, tree-based reparameterization, loop calculus, and ...

2011-01-01

48

No. 292-M:11/18/94:Tandem Thrust 95, a Joint Task Force Fie  

Science.gov (United States)

... The mission of Tandem Thrust is to employ a joint task force headquarters and appropriate forces in a realistic training exercise. ...

49

Fourier Analysis on GL(n,R)  

UK PubMed Central (United Kingdom)

Two problems of Fourier analysis on GL(n,R) are studied. The first concerns the decomposition of the additive Fourier operator in terms of the group representation...Full Text Available

1970-01-01

50

Production by surface sputtering and acceleration of heavy negative ions in tandem accelerators  

Energy Technology Data Exchange (ETDEWEB)

The main physical processes allowing negative ion production by surface sputtering for further acceleration in tandem acceleration are briefly reviewed. The sputtering yield and the probability of negative ion ejection are discussed. The properties of negative ion beams for an efficient acceleration in tandem accelerators are also discussed, with an emphasis on space charge problems. The main features and performances of the heavy negative ion injector of the Bucharest tandem accelerator are given.

1992-10-05

51

High-performance concentrator tandem solar cells based on IR-sensitive bottom cells  

Energy Technology Data Exchange (ETDEWEB)

Computer simulations of two-junction, concentrator tandem solar cell performance show that IR-sensitive bottom cells are required to achieve high efficiencies. Based on this conclusion, two novel concentrator tandem designs are under investigations: (1) a mechanically stacked, four-terminal GaAs/GaInAsP (0.95 eV) tandem, and (2) a monolithic, lattice-matched, three-terminal InP/GaInAs tandem. In preliminary experiments, terrestrial concentrator efficiencies exceeding 30% have been achieved with each of the above tandem designs. Methods for improving the efficiency of each tandem type are discussed. (orig.).

1991-05-01

52

Thermal and mechanical properties of poly(vinyl alcohol) plasticized with glycerol  

British Library Electronic Table of Contents (United Kingdom)

Abstract Thermomechanical behavior of membranes based on blends of poly(vinyl alcohol) (PVA) with different weight percentage (wt %) of glycerol has been studied. Solid-state PVA/Glycerol polymer membranes were prepared by a solution casting method. The films were studied for thermal characteristics by differential scanning calorimetry (DSC) and thermogravimetric analysis and for the mechanical properties including hardness and modulus by nanoindentation method. The dispersion of glycerol within the polymer matrix was examined using scanning electron microscopy. Fourier transform infrared spectroscopy was used to confirm the formation of hydrogen bonding between the plasticizer and PVA in their blends and also to provide information on compatibility and physical interactions between the gl...

2011-01-01

53

Synthesis and characterization of Fe3O4Gg nanocomposites and their antibacterial performance  

British Library Electronic Table of Contents (United Kingdom)

We synthesized Fe3O4Gg nanocomposites through a combination of solvothermal, hydrothermal, and chemical redox reactions. Characterization of the resulting samples by X-ray diffraction, Fourier-transform infrared spectroscopy, field-emission scanning and transmission electron microscopy, and magnetic measurement is reported. Compared to Fe3O4g nanocomposites, the Fe3O4Gg nanocomposites showed enhanced antibacterial activity. The Fe3O4Gg nanocomposites were able to almost entirely prevent growth of Escherichia coli when the concentration of Ag nanoparticles was 10mg/mL. Antibacterial activity of the Fe3O4Gg nanocomposites was maintained for more than 40h at 37^oC. The intermediate carbon layer not only protects magnetic core, but also improves the dispersion and antibacterial activity of the...

2011-01-01

54

Synthesis and characterization of Co-Ag core-shell nanoparticles  

Energy Technology Data Exchange (ETDEWEB)

A micellar method has been used to prepare silver-coated cobalt (Co-Ag) nanoparticles. The synthesized particles have been deeply characterized by several methods, i.e., XRD, UV-Vis, TEM, XPS, and electrochemical techniques. There is every indication that the obtained particles show a truly core-shell structure. All the nanoparticles obtained under different conditions are in the size range 3-5 nm. High-resolution TEM (HRTEM), Fast Fourier Transformation (FFT), and Selected Area Electron Diffraction (SAED) indicated that the presence of hcp-Co and fcc-Ag, in which cobalt is located in the central area; meanwhile silver is at the edges of the nanoparticle. The absorption band of the Co-Ag colloid shifts to a longer wavelength and broadens relative to that of pure silver colloid. Voltammetric characterization allowed to determine the coverage of the cobalt core.

2010-08-15

55

Submegahertz linewidth at 240 GHz from an injection-locked free-electron laser  

International Nuclear Information System (INIS)

Radiation from an ultrastable 240 GHz solid state source has been injected, through an isolator, into the cavity of the University of California, Santa Barbara millimeter-wave free-electron laser (FEL). High-power FEL emission, normally distributed among many of the cavity's longitudinal modes, is concentrated into the single mode to which the solid state source has been tuned. The linewidth of the FEL emission is 0.5 MHz, consistent with the Fourier transform limit for the 2 #mu#s pulses. This demonstration of frequency-stable, ultranarrow-band FEL emission is a critical milestone on the road to FEL-based pulsed electron paramagnetic resonance spectroscopy.

2007-10-22

56

Soluble starch?based biodegradable and microporous microspheres as potential adsorbent for stabilization and controlled release of coix seed oil  

British Library Electronic Table of Contents (United Kingdom)

Soluble starch?based biodegradable and microporous microspheres (SDM-Ms) were prepared by emulsion chemical cross-linking technique using trisodium trimetaphosphate (TSTP) as the cross-linker. The resultant amorphous SDM-Ms were excellently identified by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). The internal rupture and surface-controlled erosion were the predominant degradation mechanisms for SDM-Ms. The obtained SDM-Ms were applied to adsorb coix seed oil (CSO) by immersing method. The adsorption capacity of CSO within SDM-Ms was determined, namely 0.5238?g/g, and the thermal stability was shown higher than that of the free CSO. A burst release appeared in the second hour, followed by controlled release. Diffusion, d...

2011-01-01

57

Removal of polycyclic aromatic hydrocarbons from aqueous solution using plant residue materials as a biosorbent  

British Library Electronic Table of Contents (United Kingdom)

To elucidate biosorption mechanism and removal efficiency of plant residues as a biosorbent to abate polycyclic aromatic hydrocarbons (PAHs) in wastewater, sorption of PAHs onto wood chips (WC), ryegrass roots (RR), orange peels (OP), bamboo leaves (BL), and pine needles (PN) were investigated. The structural characterization of the biosorbents was analyzed by elemental composition, BET-N2 surface area, and Fourier transform infrared spectroscopy. PAHs sorption to the selected biosorbents were compared and correlated with their structures. Biosorption isotherms fit well with Freundlich equation and the mechanism was dominated by partition process. The magnitude of phenanthrene partition coefficients (Kd) followed the order of PN>BL>OP>RR>WC, ranged from 2484+/-24.24 to 5306+/-92.49L/kg. Ex...

2011-01-01

58

Preparation and characterization of nano hydroxyapatite/polymeric composites materials. Part I  

British Library Electronic Table of Contents (United Kingdom)

The present study is focused on preparation of nano composite materials and the effect of citric acid on their different properties. The formation of nano HA and its interaction with chitosan (C), gelatin (G) polymers and citric acid (CA) materials were studied. The Fourier Transformed Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), transmission electron microscope (TEM), and scanning electron microscope (SEM) were used to characterize these composite materials. The compressive strength (CS) was also measured to know the reinforcement of the prepared composites. The results show that carboxylic and amino groups play crucial role for HA formation on chitosan-gelatin polymeric matrix in the presence of citric acid (CA). The formation of nano HA part...

2011-01-01

59

Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane  

British Library Electronic Table of Contents (United Kingdom)

A novel composite charged mosaic membrane (CCMM) was prepared via interfacial polymerization (IP) of polyamine [poly(epichlorohydrin amine)] and trimesoyl chloride (TMC) on the polyethersulfone (PES) support. Fourier transform infrared spectroscopy (FT-IR), environmental scanning electron microscopy (ESEM), atomic force microscopy (AFM) and water contact angle analysis were applied to characterize the resulted CCMM. The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine. ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane. The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network. Several factors affecting the IP reaction and the performan...

2010-01-01

60

Polyester and multiwalled carbon nanotube composites: characterization, electrical conductivity and antibacterial activity  

British Library Electronic Table of Contents (United Kingdom)

Abstract Poly(butylene terephthalate) (PBT) composites containing multiwalled carbon nanotubes (MWCNTs) were prepared using a melt-blending process and used to examine the effects on the composite structure and properties of replacing PBT with acrylic acid-grafted PBT (PBT-g-AA). PBT-g-AA and multihydroxyl-functionalized MWCNTs (MWCNTs-OH) were used to improve the compatibility and dispersibility of the MWCNTs within the PBT matrix. The composites were characterized morphologically using transmission electron microscopy, and chemically using Fourier transform infrared, solid-state 13C NMR and UV-visible absorption spectroscopy. The antibacterial and electrical conductivity properties of the composites were also evaluated. MWCNTs or MWCNTs-OH enhanced the antibacterial activity and electric...

2011-01-01

61

PLZT spatial light modulator for a 1-D hologram memory.  

Science.gov (United States)

A 100-bit slitlike aperture array spatial light modulator has been developed using 8.8/65/35 PLZT for a high-bit-density 1-D hologram memory. The most desirable characteristics, such as distortion-free diffraction-limited Fourier transform patterns and good uniformity of displayed bit patterns over 100 bits, have been realized. The lowest SNR was 86, and rise time and fall time have been 30 microsec and 8 microsec, respectively, at 190-V halfwave voltage. One-dimensional holographic storage experiments have been successfully performed using this PLZT spatial light modulator. PMID:20216813

1980-01-01

62

Oxidation of polycaprolactone to induce compatibility with other degradable polyesters  

British Library Electronic Table of Contents (United Kingdom)

Chemical modification of poly(?-caprolactone) PCL by oxidation with potassium permanganate in solution was investigated. According to the data obtained from Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance 1H NMR, after the oxidation reactions the PCL chains exhibited new functional groups (vinyl and hydroxyl) and possible intermolecular recombination, producing an oxidized-polycaprolactone (PCL-OX). Solution viscometry indicated that degradation also occurred during the oxidation reactions (30% drop in viscosity average molecular weight was detected). Differential scanning calorimetry (DSC) also indicated that PCL was chemically modified and degraded. The successive self-nucleation/annealing (SSA) treatment confirmed that a reduction (or interruption) in line...

2007-01-01

63

Normalized noise power spectrum of full field digital mammography detector system  

International Nuclear Information System (INIS)

Full text: A method to measure noise power spectrum of a full field digital mammography system is presented. The effect of X-ray radiation dose, size and configuration of region of interest on normalized noise power spectrum (NNPS) was investigated. Flat field images were acquired using RQA-M2 beam quality technique (Mo/Mo anode-filter, 28 kV, 2 mm Al) with different clinical radiation doses. The images were cropped at about 4 cm from the edge of the breast wall and then divided into different size of non-overlapping or overlapping segments. NNPS was determined through de trending, 2-D fast Fourier transformation and normalization. Our measurement shows that high radiation dose gave lower NNPS at a specific beam quality. (author)

64

Normalized Noise Power Spectrum of Full Field Digital Mammography System  

International Nuclear Information System (INIS)

A method to measure noise power spectrum of a full field digital mammography system is presented. The effect of X-ray radiation dose, size and configuration of region of interest on normalized noise power spectrum (NNPS) was investigated. Flat field images were acquired using RQA-M2 beam quality technique (Mo/Mo anode-filter, 28 kV, 2 mm Al) with different clinical radiation doses. The images were cropped at about 4 cm from the edge of the breast wall and then divided into different size of non-overlapping or overlapping segments. NNPS was determined through detrending, 2-D fast Fourier transformation and normalization. Our measurement shows that high radiation dose gave lower NNPS at a specific beam quality.

2010-01-05

65

Multi walled carbon nanotubes/epilson polylysine nanocomposite with enhanced antibacterial activity  

British Library Electronic Table of Contents (United Kingdom)

Abstract Aims: To develop a new nano composite of multi walled carbon nanotubes (MWNTs) with enhanced antimicrobial activity. Methods and Results: A novel antimicrobial nanocomposite [MWNT epilson polylysine (MEPs)] was synthesized via covalent attachment of epilson polylysine on MWNTs with hexamethylene diisocyanate (HDI) as the coupling agent. UV visible spectra and Fourier transform infrared spectra (FT IR) investigations indicate that MEPs is stable, with epilson polylysine leaching effectively eliminated. When compared to MWNTs, the new nano composite MEPs exhibits enhanced antimicrobial activities. In 20 mg l 1 suspensions, significant increases of 72 1, 64 5 and 69% against Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aureus can be observed. The deposited film of MEPs...

2011-01-01

66

Morphology, structure, and conductivity of polypyrrole prepared in the presence of mixed surfactants in aqueous solutions  

British Library Electronic Table of Contents (United Kingdom)

Polypyrrole (PPy) was prepared from different mixed-surfactant solutions with ammonium persulfate as an oxidant. Three types of combinations were selected, including cationic/anionic, cationic/nonionic, and anionic/nonionic mixed-surfactant solutions. The surfactants used in the experiments included cetyltrimethylammonium bromide (cationic surfactant), sodium dodecyl sulfate (anionic surfactant), sodium dodecyl sulfonic acid salt (anionic surfactant), poly(vinyl pyrrolidone) (nonionic surfactant), and poly(ethylene glycol) (nonionic surfactant). The morphology, structure, and conductivity of the resulting PPy were investigated in detail with scanning electron microscopy, Fourier transform infrared spectra, and the typical four-probe method, respectively. The results showed that the interac...

2007-01-01

67

Molecular structure of platinum(III) hydroxoacetates according to data from EXAFS spectra  

Energy Technology Data Exchange (ETDEWEB)

The EXAFS spectra of the platinum(III) complexes Pt/sub 4/(OAc)/sub 10/(OH)/sub 2/ (I) and Pt/sub 4/ (OAc)/sub 4/(OH)/sub 8/(H/sub 2/O)/sub 2/ (II) have been investigated. It has been found by a curve-fitting method and with the aid of Fourier transformations that the shortest Pt-Pt distances are 2.61 A in complex I and 2.36 and 2.6 A in II. The values of the bond lengths obtained are consistent with the molecular structures proposed for complexes I and II, which contain skeletons of four platinum atoms in the form of a square or a rectangle, as well as with the known literature data on the lengths of Pt-Pt bonds in Pt(III) complexes.

1986-04-01

68

Mode shape and natural frequency identification for seismic analysis from background vibration  

International Nuclear Information System (INIS)

Background vibration in a CANDU plant can be used to determine the dynamic characteristics of major items of equipment, such as calandria, the fuelling machines and the primary heat transport pumps. These dynamic characteristics can then be used to verify the seismic response of the equipment which, at present, is based on theoretical models only. The feasibility and basic theory of this new approach (which uses accelerations measured at several points on a structure and does not require knowledge of the source of excitation) was established in Phase I of the study. This report is based on Phase II in which the methods of analysis developed in Phase I were improved and verified experimentally. A Fast Fourier Transform (FFT) algorithm was incorporated and an interactive curve fitting technique was developed to obtain the dynamic characteristics in the form of natural frequencies, mode shapes and damping ratios. The method is now available for ...

1984-02-06

69

Miscibility enhancement of PP/PBT blends with a side-chain liquid crystalline ionomer  

British Library Electronic Table of Contents (United Kingdom)

Side-chain liquid crystalline ionomer (SLCI) containing sulfonic acid groups with a polymethylhydrosiloxane main-chain was used in the blends of polypropylene (PP) and polybutylene terephthalate (PBT) as a compatibilizer. The crystalline behavior, morphological, and mechanical properties of the blends were investigated in detail by differential scanning calorimetry (DSC), polarizing optical microscope (POM), Fourier transforms infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Revealed by the shift of Tm in DSC thermogram and the shift of the absorbed peak in FTIR spectra, specific interaction led to stronger interfacial adhesion between these phases, which resulted in much finer dispersion of the minor PBT phase in PP matrix. The SLCI containing sulfonate acid groups ac...

2009-01-01

70

Layered double hydroxide as novel antibacterial drug delivery system  

British Library Electronic Table of Contents (United Kingdom)

The cephalosporin class antibacterial agent, cefazolin, was intercalated into layered double hydroxides (LDHs) in order to improve the drug efficiency as well as to achieve the controlled release property. Cefazolin molecules were incorporated into LDH through conventional ion exchange reaction. X-ray diffraction pattern analyses confirmed that cefazolin molecules were intercalated between the interlayer spaces of LDH. Fourier-transform infrared spectra and high performance liquid chromatographs clearly showed that the drug molecules were stabilized in LDH lattice through electrostatic interaction and released without any changes in their chemical integrity. Antibacterial activity of the cefazolin-LDH nanohybrid was also examined by an in vitro test, such as the minimal inhibitory concentr...

2010-01-01

71

Kramers-Kronig Analysis of Infrared Reflectance Spectra for Quaternary In_xAl_yGa_1_-_x_-_yN Alloy  

International Nuclear Information System (INIS)

In this paper, a Kramers-Kronig (KK) analysis of infrared (IR) reflectance spectrum of quaternary In_0_._0_1Al_0_._0_6Ga_0_._9_3N film grown by molecular beam epitaxy (MBE) is reported. The infrared measurement is performed in the reflection mode at an incident angle of 15 degree sign by Fourier transform infrared (FTIR) spectroscopy at T = 300 K. The Kramers-Kronig analysis of the reflectivity data has been used to obtain the real and imaginary parts of the index of refraction (n and k), and the real and imaginary parts of the dielectric response function (#epsilon#' and #epsilon#') of the materials. Finally, the transverse optical and longitudinal optical phonons for quaternary In_xAl_yGa_1_-_x_-_yN were obtained.

2010-07-07

72

Impedance Noise Identification for State-of-Health Prognostics  

Energy Technology Data Exchange (ETDEWEB)

Impedance Noise Identification is an in-situ method of measuring battery impedance as a function of frequency using a random small signal noise excitation source. Through a series of auto- and cross-correlations and Fast Fourier Transforms, the battery complex impedance as a function of frequency can be determined. The results are similar to those measured under a lab-scale electrochemical impedance spectroscopy measurement. The lab-scale measurements have been shown to correlate well with resistance and power data that are typically used to ascertain the remaining life of a battery. To this end, the Impedance Noise Identification system is designed to acquire the same type of data as an on-board tool. A prototype system is now under development, and results are being compared to standardized measurement techniques such as electrochemical impedance spectroscopy. A brief description of the Impedance Noise Identification hardware system and ...

2008-07-01

73

Impact of different cultivation and induction regimes on the structure of cytosolic inclusion bodies of TEM1-b-lactamase  

British Library Electronic Table of Contents (United Kingdom)

The enzyme TEM1-b-lactamase has been used as a model to study the impact of different cultivation and induction regimes on the structure of cytosolic inclusion bodies (IBs). The protein has been heterologously expressed in Escherichia coli in fed-batch cultivations at different temperatures (30, 37, and 40degreeC) as well as induction regimes that guaranteed distinct product formation rates and ratios of soluble to aggregated protein. Additionally, shake flask cultivations at 20, 30, and 37degreeC were performed. IBs were sampled during the whole bioprocess and structural analysis was performed by attenuated total reflectance Fourier transform infrared (ATR-FT-IR) spectroscopy. This work clearly demonstrates that the tested production regimes and rates had no impact on the IB structure, wh...

2008-01-01

74

High-throughput proteomics of breast carcinoma cells: a focus on FTICR-MS  

Energy Technology Data Exchange (ETDEWEB)

Discovery of better biomarkers for diagnosis, prognosis, and therapy-response prediction is the most critical task of a scientific quest aimed at developing newly designed, tailor-made therapies for patients with cancer. Consequently, a proteome wide analysis, in addition to genomic studies, is an absolute requirement for a complete functional understanding of tumor biology. Ultra-sensitive, high-performance Fourier transform ion cyclotron resonance (FTICR) mass spectrometry (MS) currently holds an important role in fulfilling the demands of biomarker discovery. In this review, we describe the applicability of FTICR MS for breast cancer proteomics, particularly for the analysis of complex protein mixtures obtained from a limited number of cells typically available from clinical specimens.

2008-06-05

75

High channel density wavelength division multiplexer with defined diffracting means positioning  

Energy Technology Data Exchange (ETDEWEB)

A wavelength division multiplexer/demultiplexer having optical path lengths between a fiber array and a Fourier transform lens, and between a dispersion grating and the lens equal to the focal length of the lens. The optical path lengths reduce losses due to angular acceptance mismatch in the multiplexer. Close orientation of the fiber array about the optical axis and the use of a holographic dispersion grating reduces other losses in the system. Multi-exposure holographic dispersion gratings enable the multiplexer/demultiplexer for extremely broad-band simultaneous transmission and reflection operation. Individual Bragg plane sets recorded in the grating are dedicated to and operate efficiently on discrete wavelength ranges.

1990-01-01

76

Final report: technical contributions to the development of incipient fault detection/location instrumentation  

Energy Technology Data Exchange (ETDEWEB)

The transmission of electrical energy by use of underground cables is increasing. Fault location techniques have certain limitations; incipient fault detection and location would help reduce the maintenance cost of these lines as well as improve the reliability of service. The report discusses some test results related to RF-probing techniques applied to high-voltage transmission lines. The high-frequency losses and attenuation in high-voltage cables places certain ultimate limitations on RF-probing techniques for incipient fault detection. Time-domain reflectrometry methods were employed to assess the RF-transmission properties of high-voltage cables at frequencies as high as 6 GHz. Fast-Fourier-transform deconvolution was used to obtain loss measurements as a function of frequency. The loss mechanisms were identified. The measurement hardware and methods are discussed as well as analysis approach leading to the conclusions.

1986-04-01

77

Effect of #gamma#-irradiation on commercial polypropylene based mono and multi-layered retortable food packaging materials  

International Nuclear Information System (INIS)

Irradiation processing of food in the prepackaged form may affect chemical and physical properties of the plastic packaging materials. The effect of #gamma#-irradiation doses (2.5-10.0 kGy) on polypropylene (PP)-based retortable food packaging materials, were investigated using Fourier transform infrared (FTIR) spectroscopic analysis, which revealed the changes happening to these materials after irradiation. The mechanical properties decreased with irradiation while oxygen transmission rate (OTR) was not affected significantly. Colour measurement indicated that Nylon 6 containing multilayer films became yellowish after irradiation. Thermal characterization revealed the changes in percentage crystallinity.

2007-07-01

78

Comparative study on the technological properties of latex and natural rubber from Hancornia speciosa Gomes and Hevea brasiliensis  

British Library Electronic Table of Contents (United Kingdom)

This work reports a systematic comparative study of the technological properties of natural lattices and rubbers extracted from Hancornia speciosa Gomes and Hevea brasiliensis [(Willd. ex Adr. de Juss.) Muell.-Arg.] (clone RRIM 600) trees from 11 collections in Brazil throughout 2004. Natural rubber latex particle sizes and distributions were quite similar with an average diameter around 1 mm. Molecular weight, Wallace plasticity, and Mooney viscosity values were approximately the same for both rubbers. Fourier transform infrared spectroscopy peaks characteristic of natural rubber were observed for both Hancornia and Hevea. The measured differences in technological properties included lower values for Hancornia dry rubber content, % ash, % nitrogen, and plasticity retention index but highe...

2009-01-01

79

Chemistry between crosslinks affects the properties of peptide hydrogels  

British Library Electronic Table of Contents (United Kingdom)

Protein hydrogels were prepared by substituting ovalbumin with different concentrations of ethyl vinyl sulfone (EVS) or acrylic acid (AA) and crosslinking with divinyl sulfone (DVS). Fourier transform-infrared (FT-IR) spectroscopic studies confirmed the addition of EVS, AA, and DVS onto the protein. Swelling was assessed as a function of pH in the range of 2.5 to 9.4 and ionic strength. The elastic modulus of the gels was determined in shear and compression. Stress relaxation was assessed in compression. The substituent highly affected swelling and modulus with both hydrogels displaying non-Gaussian behavior in the range of hydrogel environments studied. Acrylic acid substituted ovalbumin exhibited a decreasing modulus with increasing swelling behaving as a polyelectrolyte with low added s...

2011-01-01

80

Chemical and morphological characterization of mesoporous material supported copper oxide nanoparticles for potential application  

British Library Electronic Table of Contents (United Kingdom)

SBA-15 supported nano-scaled copper oxide was synthesized by impregnation method via ultrasonic-assisted route. The removal test from gas mixture containing 0.1?vol.% hydrogen sulfide was carried out over this material at atmospheric conditions. The effects of the chemical nature of copper oxide and the textural properties of the material on removal capacity were studied. The materials before and after the removal test were analyzed by nitrogen adsorption, X-ray diffraction, Transmission Electron Microscope, X-ray photoelectron Spectroscopy, Fourier Transform Infrared Spectrometer and Inductive Coupled Plasma. The results showed that copper species are located predominantly in mesopore channels, existing as copper oxide nanoparticles. Mesopores are active sites for removal reaction. The ou...

2011-01-01

81

Biosorption of reactive dye by waste biomass of Nostoc linckia  

British Library Electronic Table of Contents (United Kingdom)

Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...

2011-01-01

82

Banana peel extract mediated novel route for the synthesis of palladium nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

Bio-inspired palladium nanoparticles were synthesized by using banana peel extract (BPE), a non-toxic eco-friendly material. Boiled, crushed, acetone precipitated, air-dried peel powder was used to reduce palladium chloride. The palladium nanoparticles were characterized by using UV-Visible spectroscopy, scanning electron microscope-energy dispersive spectra (SEM-EDS) and X-ray diffraction (XRD) analysis. Dynamic light scattering (DLS) studies revealed the average size of nanoparticles to be 50nm. Fourier transform infra red spectroscopy (FTIR) implicated the role of carboxyl, amine and hydroxyl groups in the synthetic process. This paper thus describes a novel green method for the synthesis of palladium nanoparticles.

2010-01-01

83

Ising model for phase separation in alloys with anisotropic elastic interaction. 2: A computer experiment  

Energy Technology Data Exchange (ETDEWEB)

When a metallic alloy is quenched into a miscibility gap, a mixture of two phases develops, whose domain structure then coarsens because of the interfacial energy between the two phases. This spatial arrangement of the domains and the rate at which they evolve may be strongly influenced by elastic interactions. In a recent paper, the authors described a method for simulating the effect of anisotropic elastic interactions in a two-dimensional Ising model of a cubic alloy, using Kawasaki dynamics with the elastic interactions represented by a long-range two-body interaction potential. Here they present the results of such simulations at various temperatures, alloy compositions and misfits (by misfit they mean the difference in size between the two kinds of atom), exhibiting snapshots both of the microscopic configurations (corresponding to experimental measurements using transmission electron microscopy) and of their squared Fourier transforms ...

1996-08-01

84

CZT vs FFT: Flexibility vs Speed  

Energy Technology Data Exchange (ETDEWEB)

Bluestein's Fast Fourier Transform (FFT), commonly called the Chirp-Z Transform (CZT), is a little-known algorithm that offers engineers a high-resolution FFT combined with the ability to specify bandwidth. In the field of digital signal processing, engineers are always challenged to detect tones, frequencies, signatures, or some telltale sign that signifies a condition that must be indicated, ignored, or controlled. One of these challenges is to detect specific frequencies, for instance when looking for tones from telephones or detecting 60-Hz noise on power lines. The Goertzel algorithm described in Embedded Systems Programming, September 2002, offered a powerful tool toward finding specific frequencies faster than the FFT.Another challenge involves analyzing a range of frequencies, such as recording frequency response measurements, matching voice patterns, or displaying spectrum information on the face of an ...

2003-10-01

85

Experimental determination of line strengths for selected carbon monoxide and carbon dioxide absorption lines at temperatures between 295 and 1250 K  

Energy Technology Data Exchange (ETDEWEB)

Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO[sub 2] absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the [ital P] branch of the fundamental absorption band (2150--1950 cm[sup [minus]1]) while the CO[sub 2] vibrational-rotational lines were from the far wing of the [ital R] branch of the [nu][sub 3] fundamental band (2395--2380 cm[sup [minus]1]). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO[sub 2]/N[sub 2] gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite ...

1994-11-01

86

Experimental determination of line strengths for selected carbon monoxide and carbon dioxide absorption lines at temperatures between 295 and 1250 K  

International Nuclear Information System (INIS)

Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO_2 absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the P branch of the fundamental absorption band (2150--1950 cm"-"1) while the CO_2 vibrational-rotational lines were from the far wing of the R branch of the #nu#_3 fundamental band (2395--2380 cm"-"1). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO_2/N_2 gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak overlap. Line strength ...

87

Determination of Salirasib (S-trans, trans-farnesylthiosalicylic acid) in human plasma using liquid chromatography-tandem mass spectrometry  

UK PubMed Central (United Kingdom)

A liquid chromatography/tandem mass spectrometric (LC/MS/MS) assay was developed for the quantitative determination of salirasib (S-trans, trans-farnesylthiosalicylic acid,...Full Text Available

2008-06-15

88

METAL DEFORMATION PROCESSES/FRICTION AND ...  

Science.gov (United States)

... In the same year, the Revere Copper and Brass Company of America introduced the tandem cold mill, soon followed by ...

2011-05-14

89

Design of a tandem accelerator free electron laser  

International Nuclear Information System (INIS)

The motivation for using a tandem electrostatic accelerator as an electron accelerator for a free electron laser (FEL) is presented. The adaptation of the HVEC EN tandem at the Weizmann Institute for this purpose, electron beam optics and nonlinear FEL computation relevant for this FEL realization are described. In the tandem configuration the terminal is held at a positive potential. The electron beam is accelerated from ground potential to the terminal in one beam tube and then decelerated down the other beam tube. The FEL wiggler and cavity are at the terminal. Due to the beam energy recovery this scheme produces a high power beam at the terminal with a small investment in electrical power. (orig.).

91

3D Fourier synthesis of a new X-ray picture identical in projection to a previous picture  

Energy Technology Data Exchange (ETDEWEB)

A central problem in diagnostic radiology is to compare a new X-ray picture with a previous picture and from this comparison be able to decide if anatomical changes have occurred in the patient or not. It is of primary interest that these pictures are identical in projection. If not it is difficult to decide with confidence if differences between the pictures are due to anatomical changes or differences in their projection geometry. In this thesis we present a non invasive method that makes it possible to find the relative changes in the projection geometry between the exposure of a previous picture and a new picture. The method presented is based on the projection slice theorem (central section theorem). Instead of an elaborate search for a single new picture a pre-planned set of pictures are exposed from a circular orbit above the patient. By using 3D Fourier transform techniques we are able to synthesize a new X-ray picture from this set of ...

1993-11-01

92

X-ray scattering signatures of {beta}-thalassemia  

Energy Technology Data Exchange (ETDEWEB)

X-ray scattering from lyophilized proteins or protein-rich samples is characterized by the presence of two characteristic broad peaks at scattering angles equivalent to momentum transfer values of 0.27 and 0.6 nm{sup -1}, respectively. These peaks arise from the interference of coherently scattered photons. Once the conformation of a protein is changed, these two peaks reflect such change with considerable sensitivity. The present work examines the possibility of characterizing the most common cause of hemolytic anaemia in Egypt and many Mediterranean countries; {beta}-thalassemia, from its X-ray scattering profile. This disease emerges from a genetic defect causing reduced rate in the synthesis of one of the globin chains that make up hemoglobin. As a result, structurally abnormal hemoglobin molecules are formed. In order to detect such molecular disorder, hemoglobin samples of {beta}-thalassemia patients are collected, lyophilized and measured using a conventional X-ray ...

2009-08-11

93

Wind turbulence used as searching signal for MPPT in variable-speed wind energy conversion systems  

Energy Technology Data Exchange (ETDEWEB)

The control problem associated to a class of horizontal-axis fixed-pitch variable-speed low-power wind energy conversion systems, working in the partial load region, consisting in the energy conversion maximization, is approached here under the assumption that the wind turbine model and its parameters are poorly known. Using a new approach derived from the optimum seeking methods category, generically called Maximum Power Point Tracking (MPPT), the proposed control solution aims at driving the average position of the operating point near to optimality. Instead of inducing sinusoidal search signals, the wind turbulence is here used as search disturbance. The high-speed shaft's average rotational speed is slowly adjusted using the Fast Fourier Transform processing of some available measures from the system as an estimate of the operating point's position/distance to optimality. Numerical simulations are used for preliminary ...

2009-01-15

94

Vibrational spectroscopy of bacteriorhodopsin mutants: light-driven proton transport involves protonation changes of aspartic acid residues 85, 96, and 212  

Energy Technology Data Exchange (ETDEWEB)

Fourier transform infrared (FTIR) difference spectra have been obtained for the bR----K, bR----L, and bR----M photoreactions in bacteriorhodopsin mutants in which Asp residues 85, 96, 115, and 212 have been replaced by Asn and by Glu. Difference peaks that had previously been attributed to Asp COOH groups on the basis of isotopic labeling were absent or shifted in these mutants. In general, each COOH peak was affected strongly by mutation at only one of the four residues. Thus, it was possible to assign each peak tentatively to a particular Asp. From these assignments, a model for the proton-pumping mechanism of bR is derived, which features proton transfers among Asp-85, -96, and -212, the chromophore Schiff base, and other ionizable groups within the protein. The model can explain the observed COOH peaks in the FTIR difference spectra of bR photointermediates and could also account for other recent results on site-directed mutants of bR.

1988-11-15

95

Time-domain dynamic opto-rheology study of polymer films using step-scan FTIR time-resolved spectroscopy (S{sup 2}FTIR TRS)  

Energy Technology Data Exchange (ETDEWEB)

Step-scan Fourier transform infrared spectroscopy in conjunction with impulse stress on polymer films has been used to monitor dynamic rheological responses in real time. A novel piezo-electrically-driven polymer microrheometer was employed to apply repetitive impulses to the polymer sample while time-domain spectra were recorded. Recent results include the study of both semi-crystalline polymers such as isotactic polypropylene (iPP) and elastomers such as Estane polyester/polyurethane copolymer and Kraton tri-block copolymer. The spectral changes of iPP are consistent with frequency-domain results. For iPP at room temperature, large differences in the response times of different absorption bands are not seen. However, the orientation response of the CH{sub 3} rocking mode is slightly slower than the responses of the backbone modes. To the authors` knowledge, this is the first reported successful step-scan FTIR time-domain dynamic polymer ...

1998-07-01

96

Time-dependent infrared emission following photodissociation of nitromethane and chloropicrin.  

Science.gov (United States)

Nitromethane (CH(3)NO(2)) and its chlorinated analogue, chloropicrin (CCl(3)NO(2)), were photolyzed at 193, 248, and 266 nm, and the products were observed by time-dependent Fourier transform infrared emission spectroscopy. At 193 and 248 nm, the primary photodissociation pathway for nitromethane was cleavage of the C-N bond to produce CH(3) + NO(2)(A (2)B(2)). At 266 nm, weak emission was observed following photodissociation of nitromethane, but an infrared spectrum could not be obtained. The photodissociation of chloropicrin at 193 nm produced the analogous product channel CCl(3) + NO(2)(A (2)B(2)) in addition to several other product channels. At 248 and 266 nm, only CCl(3) + NO(2)(A (2)B(2)) was observed. The production of phosgene (CCl(2)O) from chloropicrin photodissociation was not observed in this study. PMID:16571044

2006-04-01

97

Thermal effect on superhydrophobic performance of stearic acid modified ZnO nanotowers  

Energy Technology Data Exchange (ETDEWEB)

The thermal desorption of stearic acid on superhydrophobic zinc oxide nanotowers has been investigated. The stearic acid passivated zinc oxide nanotowers provide a very high contact angle of {approx}173 {+-} 1.1 deg. with a very low hysteresis of {approx}1.4 {+-} 0.5 deg. due to the presence of a binary structure composed of several nanosteps on each nanotower of height {approx}700 nm that eventually reduces the area of contact between the drop and the nanotowers and trapping more air as revealed by the field emission scanning electron microscopy images. The superhydrophobic performance of these nanotowers, however, declines following annealing at elevated temperatures. Fourier transform infrared spectra show a reduction in the intensity of stearic acid -CH{sub n} peaks at elevated temperatures revealing the cause of the decrease in contact angle and confirming the occurrence of thermal desorption at 184 deg. C. The corresponding activation ...

2008-02-28

98

Temporal measures and controls in ultrafast laser domain; Mesures et controles temporels dans le domaine des lasers ultrabrefs  

Energy Technology Data Exchange (ETDEWEB)

This work presents the development of a streak camera 'jitter free' sweep unit synchronized on a femtosecond laser. This application of high voltage photoconductive switches ('High voltage Auston switch') yields subpicosecond resolution for accumulated images on streak camera on a few hundreds micro joule femtosecond laser. Two others applications of these photoconductive switches are studied: - ultrafast optical commutation by a Pockels cell directly driven by a photoconductive switch (rising edge < 100 ps and jitter < 2 ps), - laser pulse energy self-stabilization experimentally proving that driving a Pockels cell by a photoconductive switch can increase the stability of the laser pulse energy from 7 % to 0.7 % rms. Additionally, the application of the acoustic-optical programmable dispersive filter (Dazzler) to the self referenced spectral phase measurement is presented. As these measurements require a linear filter combined with a ...

2004-12-15

99

Synthesis of nanocrystalline YSZ (ZrO_2-8Y_2O_3) powder by polymerized complex method  

International Nuclear Information System (INIS)

In this study nanocrystalline powders of yttria-stabilized zirconia (ZrO_2-8Y_2O_3) have been synthesized through 'polymerized complex method'. Zirconium chloride, yttrium nitrate, citric acid and ethylene glycol were polymerized at 80 "oC to produce a gel-like mass in which metallic ions were uniformly distributed. During the thermal treatment of dried gel, nanocrystalline powder was formed at 450 "oC and 650 "oC for 2 h. Thermal reactions and crystalline phase formation of the dried gel were investigated through thermal analysis and X-ray diffraction analysis, respectively. The results of thermal analysis and XRD showed the formation of nanocrystalline powder at less than 600 "oC. Chemical bonding of the dried gel was investigated by Fourier transform infrared spectroscopy analysis. Morphology of powder calcined at 650 "oC was analyzed by scanning electron microscope. Yttria-stabilized zirconia powders with the mean crystallite size of 6 nm ...

2010-02-18

100

Study on performance of colloidal mixtures consisted of stearic acid and Na{sub 2}HPO{sub 4}.12H{sub 2}O for use as phase change materials of thermal energy storage  

Energy Technology Data Exchange (ETDEWEB)

The thermal energy storage performance and phase change stability of mix phase change materials consisted of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O are studied by means of Fourier transformation infrared spectrum analyses (FTIR) and Differential Scanning Calorimetry (DSC). The specific heat capacity of mix materials is also determined experimentally. The results show that all absorption peaks of functional groups and chemical bonds of stearic acid still exist, which suggests that these crystal materials composed of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O have good phase change stability and chemical compatibility. Thus, disadvantages caused by the subcooling of Na{sub 2}PO{sub 4}.H{sub 2}O and the low specific heat capacity of stearic acid can be solved, it is speculated that complement each other on the basis of organic/inorganic characteristics in itself is carried out for these two component materials of the mixture. ...

2010-07-15

101

Stearic acid gel derived MgTiO{sub 3} nanoparticles: A low temperature intermediate phase of Mg{sub 2}TiO{sub 4}  

Energy Technology Data Exchange (ETDEWEB)

Stearic acid gel is employed to study the phase evolution of MgTiO{sub 3} nanoparticles by thermal gravimetric analysis, X-ray diffraction, and Fourier transform infrared. During the preparation of stearic acid gel, tetrabutyl titanate easily absorbed moisture to hydrolyze into Ti(OH){sub 4} firstly, and then reacts with stearic acid and magnesium stearate to form magnesium-titanium oxide network polymer gel, meanwhile n-butanol is generated. When stearic acid gel is calcined in air, a series of oxidation and combustion reactions occur, meanwhile apparent heat is given off. The results show that a metastable intermediate phase Mg{sub 2}TiO{sub 4} is generated at 450 {sup o}C and nearly disappeared at 550 {sup o}C. Simultaneously, a new solid phase of MgTiO{sub 3} appears. The metastable intermediate phase Mg{sub 2}TiO{sub 4} is successfully identified in the current work.

2010-03-04

102

Size-dependent surface plasmon resonance in silver silica nanocomposites  

Energy Technology Data Exchange (ETDEWEB)

Silver silica nanocomposites were obtained by the sol-gel technique using tetraethyl orthosilicate (TEOS) and silver nitrate (AgNO{sub 3}) as precursors. The silver nitrate concentration was varied for obtaining composites with different nanoparticle sizes. The structural and microstructural properties were determined by x-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). X-ray photoelectron spectroscopic (XPS) studies were done for determining the chemical states of silver in the silica matrix. For the lowest AgNO{sub 3} concentration, monodispersed and spherical Ag crystallites, with an average diameter of 5 nm, were obtained. Grain growth and an increase in size distribution was observed for higher concentrations. The occurrence of surface plasmon resonance (SPR) bands and their evolution in the size range 5-10 nm is studied. For decreasing nanoparticle size, a redshift and ...

2008-02-20

103

Precise characterisation of nanochannels in track etched membranes by SAXS and SANS  

Energy Technology Data Exchange (ETDEWEB)

Poster session: Abstract is full text. Track membranes are thin polymer foils irradiated by heavy ions. The defects created by the heavy ions are located along the ions trajectory, the track. It is possible to open channels by etching with a chemical agent. These channels are very uniform. Small Angle Scattering (of X rays and neutrons) give global information about the characteristics of the channel shape. As the nanochannels are strictly parallel, an excellent sample orientation is required to obtain interpretable spectra. Then shoulders due to the oscillations of the Bessel function (radial part of the channel shape Fourier transform) are easily seen in the scattered intensity in the PXY data treatment software of SAS spectra allow to determine the channel diameter with its dispersion law, to demonstrate the existence of a wall thickness with a linearly varying density, and to assess the roughness. PXY can also detect non cylindric shapes ...

2003-05-01

104

Parameters determination of IEC-TDG by directly solving non-linear equation; Chokusetsuho ni yoru IEC-TDG hakei kaiseki  

Energy Technology Data Exchange (ETDEWEB)

An IEC-TDG waveform analysis program that can accurately calculate the waveform parameters in waveforms containing much noise as well as waveforms based on the IEC 1083-2 standard was developed in the impulse voltage and current test field. In the conventional curve fitting method, it is difficult to solve the non-linear equation directly when obtaining waveform parameters from the assigned discrete data. An approximate solution method is low in precision. Therefore, the residual between the standardized data and approximate function was calculated for high-speed Fourier transformation. Unrelated components were eliminated from the calculated frequency spectrum to synthesize waveforms. An L-M method is used for analysis. The solution is first tracked by a maximum diving method. If the convergence is judged to have been largely promoted, the method is switched into a Newton method to continue the calculation. The non-linear equation in a curve ...

1997-04-20

105

On-line analysis of chemical composition using an FT-Raman spectrometer in the near-ir  

Science.gov (United States)

Newly commercialized Fourier transform Raman spectroscopic instrumentation provides a simpler alternative for vibrational spectroscopic analysis. Instrument vendors currently design for laboratory use, but there are many potential process applications of these stable, easy to use instruments. Raman spectroscopy is highly suited to analysis of aqueous samples. Near infrared excitation minimized fluorescence interference and allows for remote operation via fiber optic probes. The Department of Energy has funded research at the Measurement and Control Center to establish the utility of this method for on-line composition analysis in distillation columns. Laboratory evaluation and instrument employs an air-cooled laser and a thermoelectrically cooled detector. The device is mounted on a three by foot cart for convenient location in control rooms. Current fiber optic extension cables allow for analysis in a cell thirty five meters from the ...

1992-01-01

106

Nuclear mass prediction as an image reconstruction problem: can observed pattern determine mass values?  

Energy Technology Data Exchange (ETDEWEB)

Theoretical prediction of nuclear masses is analyzed as a pattern recognition problem on the N-Z plane. A global pattern is observed by plotting the differences between measured masses and Liquid Drop Model (LDM) predictions. After unfolding the data by removing the smooth LDM mass contributions, the remaining microscopic effects have proved difficult to model, although they display a striking pattern. These deviations carry information related to shell closures, nuc]ear deformation and the residual nuclear interactions. In the present work the more than 2000 known nuclear masses are studied as an array in the N-Z plane viewed through a mask, behind which the approximately 7000 unknown unstable nuclei that can exist between the proton and neutron drip lines are hidden. We show here that employing a Fourier transform deconvolution method these by masses can be predicted with similar accuracy than standard methods. We believe that a more general ...

2006-07-01

107

Nuclear mass prediction as an image reconstruction problem: can observed pattern determine mass values?  

International Nuclear Information System (INIS)

Theoretical prediction of nuclear masses is analyzed as a pattern recognition problem on the N-Z plane. A global pattern is observed by plotting the differences between measured masses and Liquid Drop Model (LDM) predictions. After unfolding the data by removing the smooth LDM mass contributions, the remaining microscopic effects have proved difficult to model, although they display a striking pattern. These deviations carry information related to shell closures, nuc]ear deformation and the residual nuclear interactions. In the present work the more than 2000 known nuclear masses are studied as an array in the N-Z plane viewed through a mask, behind which the approximately 7000 unknown unstable nuclei that can exist between the proton and neutron drip lines are hidden. We show here that employing a Fourier transform deconvolution method these by masses can be predicted with similar accuracy than standard methods. We believe that a more general ...

108

Novel non-discoid chiral copper(II)-salen type [N2O2] donor Schiff base complexes with a cyclohexane diamine spacer: synthesis, electrochemistry, columnar mesomorphism and DFT study  

British Library Electronic Table of Contents (United Kingdom)

A series of new non-discoid chiral copper(ii)-salen type complexes, [Cu((4-CnH2n+1O)2salen)], n = 14, 16, 18 and salen = N,N'-cyclohexane bis (salicylideneiminato), containing 4-substituted alkoxy tails in the side aromatic rings and a cyclohexane spacer, have been prepared and their mesogenic properties investigated. The compounds were characterised by Fourier transform infra-red spectroscopy, 1H and 13C nuclear magnetic resonance spectroscopy, UV-vis spectroscopy and fast atom bombardment mass spectrometry. Mesomorphic properties of these compounds were studied by polarising optical microscopy, differential scanning calorimetry and X-ray diffraction (XRD). The ligands are non-mesogenic but the complexes exhibited enantiotropic rectangular columnar mesophases (Colr) with extended temperat...

2011-01-01

109

Micropatterned polysaccharide surfaces via laser ablation for cell guidance  

Energy Technology Data Exchange (ETDEWEB)

Micropatterned materials were obtained by a controlled laser ablation of a photoimmobilised homogeneous layer of hyaluronic acid (Hyal) and its sulphated derivative (HyalS). The photoimmobilisation was performed by coating the polysaccharide, adequately functionalised with a photoreactive group, on aminosilanised glass substrate and immobilising it on the surface under UV light. Hyal or HyalS photoimmobilised samples were then subjected to laser ablation with wavelengths in the UV regions in order to drill the pattern. Four different patterns with stripes of 100, 50, 25 and 10 {mu}m were generated. A chemical characterisation by attenuated total reflection/Fourier transform infrared (ATR/FT-IR) and time of flight-secondary ions mass spectrometry (TOF-SIMS) confirmed the success of the laser ablation procedure and the presence of alternating stripes of polysaccharide and native glass. The exact dimensions of the stripes were determined by atomic ...

2003-03-03

110

Merging of airborne gravity and gravity derived from satellite altimetry: Test cases along the coast of greenland  

DEFF Research Database (Denmark)

The National Survey and Cadastre - Denmark (KMS) has for several years produced gravity anomaly maps over the oceans derived from satellite altimetry. During the last four years, KMS has also conducted airborne gravity surveys along the coast of Greenland dedicated to complement the existing onshore gravity coverage and fill in new data in the very-near coastal area, where altimetry data may contain gross errors. The airborne surveys extend from the coastline to approximately 100 km offshore, along 6000 km of coastline. An adequate merging of these different data sources is important for the use of gravity data especially, when computing geoid models in coastal regions. The presence of reliable marine gravity data for independent control offers an opportunity to study procedures for the merging of airborne and satellite data around Greenland. Two different merging techniques, both based on collocation, are investigated in this paper. Collocation offers a way of combining the individual ...

2002-01-01

111

Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel(II) from aqueous solution  

British Library Electronic Table of Contents (United Kingdom)

The removal of Ni(II) from aqueous solution by magnetic nanoparticles prepared and impregnated onto tea waste (Fe3O4-TW) from agriculture biomass was investigated. Magnetic nanoparticles (Fe3O4) were prepared by chemical precipitation of a Fe^2^+ and Fe^3^+ salts from aqueous solution by ammonia solution. These magnetic nanoparticles of the adsorbent Fe3O4 were characterized by surface area (BET), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). The effects of various parameters, such as contact time, pH, concentration, adsorbent dosage and temperature were studied. The kinetics followed is first order in nature, and the value of rate constant was found to be 1.90x10^-^2min^-^1 at 100mgL^-^1 and 303K. Removal ef...

2011-01-01

112

Kinetic investigations of graft copolymerization of sodium styrene sulfonate onto electron beam irradiated poly(vinylidene fluoride) films  

Energy Technology Data Exchange (ETDEWEB)

Graft copolymerization of sodium styrene sulfonate (SSS) onto electron beam (EB) irradiated poly(vinylidene fluoride) (PVDF) films was investigated to find out a simple preparation process for sulfonic acid proton exchange membranes with respect to monomer concentration, absorbed dose, temperature, film thickness and storage time. The reaction order of the monomer concentration and absorbed dose of grafting was found to be 2.84 and 1.20, respectively. The overall activation energy for graft copolymerization reaction was calculated to be 11.36 kJ/mol. The initial rate of grafting was found to decrease with an increase in the film thickness. The trapped radicals in the irradiated PVDF films remained effective in initiating the reaction without considerable loss in grafting level up to 180 days, when stored under -60 {sup o}C. The presence and distribution of polystyrene sulfonate grafts in the obtained membranes were observed by Fourier transform ...

2011-01-15

113

Isolation and characterization of humic acids from peat soil  

International Nuclear Information System (INIS)

In this study, two different humic acids extracted from England and China peat soil, as well as three purified products extracted from commercially available humic acids [Fluka (Fluka, Neu-Ulm, Germany, Alfa (Alfa Aesar, Ward Hill, USA) and Aldrich (Aldrich-Chemical Co, Gillingham-Dorset)] were obtained respectively with the modified IHSS (International humic substances society) procedure. The chemical and structural information of these humic acids were characterized by some techniques, such as elemental analysis, ultraviolet-visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FTIR) and electropotential titration. UV-Vis spectra, infrared spectra, values for elemental composition and the contents of carboxyls, phenolic hydroxyls and total acidities of these humic acids were acquired. It is indicated that all these humic acids are different in the aspect of chemical structure, respectively, and these humic acids would be ...

2009-05-01

114

Interactions of metal cations with anionic groups on the cell Wall of the macroalga vaucheria sp.  

Energy Technology Data Exchange (ETDEWEB)

The aim of this article was to investigate the interactions of metal cations in aqueous solutions with the biomass of the freshwater macroalga Vaucheria sp. This problem is important when elaborating new applications of biosorption, e.g. the production of mineral feed additives for livestock from the biomass of algae enriched with microelement ions. Potentiometric titration was applied as a quick and cheap screening test to search for new efficient biosorbents. It revealed a variety of functional groups capable of cation exchange on the macroalgal surface, including carboxyl, phosphate, hydroxyl or amino groups. Fourier transform infrared spectroscopy on natural and chromium-loaded Vaucheria sp. confirmed that carboxyl groups played a dominant role in the biosorption. The study also showed that Ca(II), Na(I), K(I), and Mg(II) ions were released from the biomass after biosorption of Cu(II), Mn(II), Zn(II), and Co(II) ions, indicating that ion ...

2010-06-15

115

Interaction of bovine serum albumin with some novel PEG-containing diblock copolymers  

British Library Electronic Table of Contents (United Kingdom)

A comparative study on the interaction of different PEG-containing diblock copolymers including SA400, SA600, SA1500 and OA1500 (stearyl and oleyl esters of polyethylene glycol with 400, 600 and 1500 molecular weights, respectively) with bovine serum albumin (BSA) was carried out using isothermal titration calorimetry (ITC), attenuated total reflectance Fourier transform infrared (ATR-FTIR), circular dichroism (CD), and fluorescence spectroscopies. ITC data show that SA400, SA600, SA1500 and OA1500 bind to BSA, with association constants of (14.5, 3.16, 50.7 and 17.6)x103M-1, respectively. Results also show that the binding is enthalpically driven, disfavored by conformational entropy. Quantitative analysis of the FTIR absorbance spectra at amide Iprime (1600-1700cm-1) as well as far UV ci...

2008-01-01

116

Improvement of spatial resolution in the longitudinal direction for isotropic imaging in helical CT  

Energy Technology Data Exchange (ETDEWEB)

Experiments were conducted to confirm the isotropic spatial resolution of multislice CT with a 0.5 mm slice thickness. Isotropic spatial resolution means that the spatial resolution in the transaxial plane (X-Y plane) and that in the longitudinal direction (Z direction) are equivalent. To obtain point spread function (PSF) values in the X-Y-Z directions, three-dimensional voxel data were obtained by helical scanning of a bead phantom. The modulation transfer function (MTF) values were then obtained by three-dimensional Fourier transform of the PSF. Evaluation of the spatial resolution in the X-Y-Z directions by the MTF values showed that the spatial resolution in the Z direction does not depend on the reconstruction kernel used. It was also found that the spatial resolution in the Z direction, as compared with that in the X-Y plane, is superior with the standard kernel for the abdomen and is inferior with the high-definition kernel for the ...

2007-02-07

117

High resolution Fourier transform spectroscopy and crystal-field analysis in Tm,Ho:BaY{sub 2}F{sub 8}  

Energy Technology Data Exchange (ETDEWEB)

A Tm{sup 3+}- Ho{sup 3+} -codoped single crystal of monoclinic BaY{sub 2}F{sub 8} has been characterized by means of high resolution FTIR spectroscopy in the wave number range 2000-24000 cm{sup -1} and in the temperature range 9-300 K. The energy level schemes of the two lanthanide ions as determined by the optical absorption spectra is presented, analyzed, and fitted within a single ion Hamiltonian model. The very small energy separation (about 0.6-1.6 cm{sup -1}) measured between the first and second sublevels of the ground state manifolds for both the ions is in line with the theoretical predictions. The impurity-phonon coupling is put into evidence by the thermally induced line shift and broadening, and by the detection of vibronic replicas of a few lines. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2005-01-01

118

High resolution Fourier transform spectroscopy and crystal-field analysis in Tm,Ho:BaY_2F_8  

International Nuclear Information System (INIS)

A Tm"3"+- Ho"3"+ -codoped single crystal of monoclinic BaY_2F_8 has been characterized by means of high resolution FTIR spectroscopy in the wave number range 2000-24000 cm"-"1 and in the temperature range 9-300 K. The energy level schemes of the two lanthanide ions as determined by the optical absorption spectra is presented, analyzed, and fitted within a single ion Hamiltonian model. The very small energy separation (about 0.6-1.6 cm"-"1) measured between the first and second sublevels of the ground state manifolds for both the ions is in line with the theoretical predictions. The impurity-phonon coupling is put into evidence by the thermally induced line shift and broadening, and by the detection of vibronic replicas of a few lines. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2005-01-01

119

Functionalizing titania nanoparticle surfaces in a fluidized bed plasma reactor  

International Nuclear Information System (INIS)

Functionalizing nanoparticle surfaces is essential for achieving homogeneous dispersions of monodisperse particles in polymer nanocomposites for successful utilization in engineering applications. Functionalization reduces the surface energy of the nanoparticles, thereby limiting the tendency to agglomerate. Moreover, reactive groups on the surface can also participate in the polymerization, creating covalent bonds between the inorganic and organic phases. In this paper, a fluidized bed inductively coupled plasma (FB-ICP) reactor is used to break apart the agglomerates and functionalize commercial TiO2 nanoparticle powders in a batch of several grams. The fluidized bed could be implemented into a continuous flow reactor, potentially making this a viable method to treat larger quantities of commercial powders. The particles are treated with acrylic acid (AA) and tetraethylorthosilicate (TEOS) plasma and the functionalized particles were collected separately from bulk powder. High ...

2009-11-18

120

Evaluation of the potential of pentachlorophenol degradation in soil by pulsed corona discharge plasma from soil characteristics.  

Science.gov (United States)

Chlorinated organics are frequently found as harmful soil contaminants and persisted for extended periods of time. A novel approach, named pulsed corona discharge plasma (PCDP), was employed for the degradation of pentachlorophenol (PCP) in soil. Experimental results showed that 87% of PCP could be smoothly removed in 60 min. Increasing pulse voltage, enhancing soil pH, lowering humic acid (HA) in soil and reducing granular size of the soil were found to be favorable for PCP degradation efficiency. Oxidation and physical processes simultaneously contributed to PCP removal in soil and ozone was the main factor in PCDP treatment. C-Cl bonds in PCP were cleaved during PCDP treatment by Fourier transform infrared spectroscopy (FTIR) analysis. The mineralization of PCP was confirmed by total organic carbon (TOC) and dechlorination analyses. The main intermediate products such as tetrachlorocatechol, tetrachlorohydroquinone, acetic acid, formic acid, ...

2010-04-15

121

Electrochemical properties of Si/Ni alloy-graphite composite as an anode material for Li-ion batteries  

International Nuclear Information System (INIS)

Si/Ni alloy and graphite composites were synthesized using arc-melting followed by high energy mechanical milling (HEMM). Alloy particles comprising of NiSi2, NiSi and Si phases were distributed finely and uniformly on the surface of graphite in the composites obtained after Hem. The composite containing 60 wt.% of Si/Ni alloy exhibited a stable capacity of ?780 mAh/g. Fourier transform infrared spectroscopy (FTIR) analysis confirmed that some bonds were formed between alloy and graphite after HEMM, which appeared to retain the electrical connection between alloy and graphite during cycling. X-ray diffraction (XRD) analysis indicated that NiSi2 and NiSi phases, which acted as an inactive alloy matrix remained invariant during charge and discharge. In addition to NiSi2 and NiSi phases, disordered graphite layers also played the role of media for the accommodation of large volume change of Si during cycling. The large reversible capacity and good ...

2005-09-30

122

Effects of palladium particle size and palladium silicide formation on fourier transform infrared spectra of CO adsorbed on Pd/SiO sub 2 catalysts  

Energy Technology Data Exchange (ETDEWEB)

Two major modes of CO adsorption on SiO{sub 2}-supported Pd reflect different extents of back-donation, which is, at least in part, controlled by the local electron density at the adsorption site. The fraction of CO in the bridging mode (B) increases and that of the linear mode (L) decreases, with increasing size of the Pd particles, indicating high electron density at Pd atoms in terraces of close-packed crystal faces, in agreement with Smoluchowski's classical model. For samples reduced at 300{degree}C our data points and those of other authors are located on a common curve of B/L vs metal dispersion. Extensive reduction at 600{degree}C results in significantly lower B/L values, attributed to the incipient formation of a palladium silicide. Oxidation followed by reduction at 300{degree}C destroys the silicide, and the B/L value returns to the original curve.

1989-06-15

123

Effects of palladium particle size and palladium silicide formation on fourier transform infrared spectra of CO adsorbed on Pd/SiO sub 2 catalysts  

Science.gov (United States)

Two major modes of CO adsorption on SiO{sub 2}-supported Pd reflect different extents of back-donation, which is, at least in part, controlled by the local electron density at the adsorption site. The fraction of CO in the bridging mode (B) increases and that of the linear mode (L) decreases, with increasing size of the Pd particles, indicating high electron density at Pd atoms in terraces of close-packed crystal faces, in agreement with Smoluchowski's classical model. For samples reduced at 300{degree}C our data points and those of other authors are located on a common curve of B/L vs metal dispersion. Extensive reduction at 600{degree}C results in significantly lower B/L values, attributed to the incipient formation of a palladium silicide. Oxidation followed by reduction at 300{degree}C destroys the silicide, and the B/L value returns to the original curve.

1989-06-15

124

Effects of oxygenated blending compounds on emissions from a turbo-charged direct injection diesel engine  

Energy Technology Data Exchange (ETDEWEB)

An experimental investigation was conducted to evaluate the effect of three different oxygenated compounds, diglyme, diethyl maleate and dibutyl maleate, on emissions from a Volkswagen 1.9 litre, turbocharged, direct injection diesel engine. Sampling was performed using a mini-dilution tunnel technique to obtain particulate matter and a Fourier transform infrared (FTIR) spectrometer for gaseous emissions. The particulate samples were analysed using thermal analysis and Soxhlet extraction to determine the fraction of volatile and soluble organic material respectively. All three oxygenated compounds were found to be effective at reducing particulate emissions, with the maleate compounds being more effective overall than the diglyme. Analysis of the relative contributions of changes in the soot and soluble organic fraction (SOF) to the reduction of particulate matter indicated that, for diethyl maleate and diglyme, reductions in soot were the ...

2000-02-01

125

Detecting exposure to environmental organic toxins in individual cells: towards development of a micro-fabricated device  

Energy Technology Data Exchange (ETDEWEB)

A new method is being developed to quickly screen for the human exposure potential to polycyclic aromatic hydrocarbons (PAHs) and organochlorines (OCs). The development involves two key elements: identifying suitable signals that represent intracellular changes that are specific to PAH and OC exposure, and constructing a device to guide the biological cell growth so that signals from individual cells are consistent and reproducible. We are completing the identification of suitable signals by using synchrotron radiation-based (SR) Fourier-transform infrared (FTIR) spectromicroscopy in the mid-infrared region (4000-400 cm-1). Distinct changes have been observed in the IR spectra after treatment of human cells in culture medium with PAHs and OCs. The potential use of this method for detecting exposure to PAHs and OCs has been tested and compared to a reverse transcription polymerase chain reaction (RT-PCR) assay that quantifies increased expression of the CYP1A1 gene ...

1999-01-10

126

Deposition of plasma-polymerized hydroxyethyl methacrylate (HEMA) on silicon in presence of argon plasma  

International Nuclear Information System (INIS)

2-hydroxyethyl methacrylate (HEMA) has been deposited onto the surface of silicon substrate (thickness = 500 ?m) using plasma polymerization technique. Polymerization process was carried out in an in-house developed inductively coupled plasma polymerization setup. The depositions were carried out using RF power supply (13.56 MHz) at power of 75 W for 10 and 40 min. The RF supply was coupled to the inductance through a matching network. The effect of plasma polymerization (surface grafting) on the degree of surface modification has been investigated. The chemical changes on the polymer backbone are followed from the results of Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS), which show the peaks corresponding to the functional groups of the HEMA polymerized onto the silicon surface. The morphology of the modified surfaces has also been investigated using scanning electron microscopy (SEM) and atomic ...

2005-05-30

127

Cyclopropane isomerization over Eu[sup 3+]NaX zeolites  

Energy Technology Data Exchange (ETDEWEB)

Cyclopropane isomerization to propylene over various Eu[sup 3+] loadings in NaX zeolite have been studied by measurements of steady-state and transient kinetics and by Fourier transform infrared spectroscopy. As Eu[sup 3+] loading increases, the rate of deactivation increases, the conversion increases, apparent activation energies are lowered, and Bronsted acid site strength and amounts increase. Apparent activation energies of 13-15 kcal/mol for propylene formation have been observed for these systems, consistent with literature reports for other metal supported heterogeneous catalyst systems. Deactivation studies have shown that activity can be restored by heating in He at 380[degrees]C between various temperature runs, and that gases desorbed during regeneration are predominantly propylene. Poisoning studies of Bronsted sites with Na vapor lead to deactivation of these catalysts. A reaction mechanism scheme based on [pi] allyl intermediates ...

1992-11-01

128

Creating an EPICS Based Test Stand Development System for a BPM Digitizer of the Linac Coherent Light Source  

Energy Technology Data Exchange (ETDEWEB)

The Linac Coherent Light Source (LCLS) is required to deliver a high quality electron beam for producing coherent X-rays. As a result, high resolution beam position monitoring is required. The Beam Position Monitor (BPM) digitizer acquires analog signals from the beam line and digitizes them to obtain beam position data. Although Matlab is currently being used to test the BPM digitizer?s functions and capability, the Controls Department at SLAC prefers to use Experimental Physics and Industrial Control Systems (EPICS). This paper discusses the transition of providing similar as well as enhanced functionalities, than those offered by Matlab, to test the digitizer. Altogether, the improved test stand development system can perform mathematical and statistical calculations with the waveform signals acquired from the digitizer and compute the fast Fourier transform (FFT) of the signals. Finally, logging of meaningful data into files has been added.

2011-06-22

129

Controllable synthesis of graphene sheets with different numbers of layers and effect of the number of graphene layers on the specific capacity of anode material in lithium-ion batteries  

International Nuclear Information System (INIS)

High quality graphene sheets are synthesized through efficient oxidation process followed by rapid thermal expansion and reduction by H2. The number of graphene layers is controlled by tuning the oxidation degree of GOs. The higher the oxidation degree of GOs is getting, the fewer the numbers of graphene layers can be obtained. The material is characterized by elemental analysis, thermo-gravimetric analysis, scanning electron microscopy, atomic force microscopy, transmission electron microscopy and Fourier transform infrared spectroscopies. The obtained graphene sheets with single, triple and quintuplicate layers as anode materials exhibit a high reversible capacity of 1175, 1007, and 842 mA h g-1, respectively, which show that the graphene sheets with fewer layers have higher reversible capacity. -- Graphical abstract: The typical TEM images of the graphene sheets derived from GO3(a), GO2(b) and GO1(c). Display Omitted Highlights: ? With the ...

2011-05-01

130

Collection of VLE data for acid gas-alkanolamine systems using Fourier transform infrared spectroscopy. Technical report, October 1, 1994--July 31, 1995  

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. The natural gas industry requires vapor-liquid equilibrium (VLE) data to develop more energy efficient amine mixtures. Some energy reductions have been realized in the past decade by applying such amine systems as hindered amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate VLE data impedes the commercial application of these more efficient alkanolamine systems. The first objective of this project is to improve the accuracy of vapor-liquid equilibrium measurements at low hydrogen sulfide concentrations. The second objective is to make VLE measurements for amine mixtures. By improving the accuracy of the VLE data on MDEA and other amines, energy savings can be implemented in the many existing absorption units already in use. If ...

1995-08-01

131

Collection of VLE data for acid gas-alkanolamine systems using Fourier transform infrared spectroscopy. Phase 1, September 29, 1990--September 30, 1991  

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as ``hindered`` amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA and mixtures with other amines, energy ...

1991-09-01

132

Collection of VLE data for acid gas-alkanolamine systems using Fourier transform infrared spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as hindered'' amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA and mixtures with other ...

1991-09-01

133

Chemical imaging of wood-polypropylene composites.  

Science.gov (United States)

Recent investigations of wood plastic composites have revealed a detrimental effect of using lubricant systems in production. This includes nullifying part or all of the mechanical benefit of using a polar compatibilizer, maleic anhydride polypropylene (MAPP), in the composite formulation. This investigation utilizes lubricants labeled with deuterium in conjunction with Fourier transform infrared (FT-IR) spectroscopy to allow for the separation of individual lubricants from all other material constituents. All of the deuterium labeled lubricants, used without MAPP, revealed their expulsion from the wood interface during crystallization. MAPP coupling agent was found to exist near the wood, but it is unclear if any covalent bonding with the hydroxyl functionality on the wood surface occurred. The addition of zinc stearate lubricants appears to nullify the activity of the anhydride functionality near the wood surface as evidenced by a shift in ...

2006-08-01

134

Characterization and reactivity of Fe3O4/FeMnOx core/shell nanoparticles for methylene blue discoloration with H2O2  

British Library Electronic Table of Contents (United Kingdom)

A magnetic core/shell Fe3O4/FeMnOx catalyst was prepared by a simple oxidation-precipitation method. The catalyst was characterized by X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and cyclic voltammetry. The characterization studies verified that Fe3O4 core was coated with a layer of Fe-Mn oxide. The Fe3O4/FeMnOx was found to be an effective and stable heterogeneous catalyst for the discoloration of methylene blue (MB) in aqueous solution by H2O2. The high catalytic activity is due to the FeMnOx shell, which not only increased the surface hydroxyl groups, but also enhanced the interfacial electron transfer. The discoloration of MB could be due to the decomposition of H2O2 into ?OH ...

2011-01-01

135

Born-Oppenheimer breakdown effects and hyperfine structure in the rotational spectrum of strontium monosulfide, SrS  

Energy Technology Data Exchange (ETDEWEB)

A newly constructed Fourier transform microwave spectrometer has been used to record the pure rotational spectra of four isotopomers of SrS ({sup 88}Sr{sup 32}S, {sup 87}Sr{sup 32}S, {sup 86}Sr{sup 32}S, and {sup 88}Sr{sup 34}S) between 6 and 26 GHz. The molecules were produced by reacting laser ablated strontium with carbonyl sulfide (0.1% in argon). Pure rotational transitions in the ground, first and second vibrational states have been observed. The data set has enabled a multi-isotopomer fit. Born-Oppenheimer breakdown terms for both atoms have been determined. The {sup 87}Sr nuclear quadrupole coupling constant in {sup 87}Sr{sup 32}S has been determined for the first time.

2007-12-06

136

Application of spectroscopic techniques for the study of paper documents: A survey  

International Nuclear Information System (INIS)

For many centuries paper was the main material for recording cultural achievements all over the world. Paper is mostly made from cellulose with small amounts of organic and inorganic additives, which allow its identification and characterization and may also contribute to its degradation. Prior to 1850, paper was made entirely from rags, using hemp, flax and cotton fibres. After this period, due to the enormous increase in demand, wood pulp began to be commonly used as raw material, resulting in rapid degradation of paper. Spectroscopic techniques represent one of the most powerful tools to investigate the constituents of paper documents in order to establish its identification and its state of degradation. This review describes the application of selected spectroscopic techniques used for paper characterization and conservation. The spectroscopic techniques that have been used and will be reviewed include: Fourier-Transform Infrared spectroscopy, Raman ...

2009-06-01

137

Analysis of complex systems using neural networks  

Energy Technology Data Exchange (ETDEWEB)

The application of neural networks, alone or in conjunction with other advanced technologies (expert systems, fuzzy logic, and/or genetic algorithms), to some of the problems of complex engineering systems has the potential to enhance the safety, reliability, and operability of these systems. Typically, the measured variables from the systems are analog variables that must be sampled and normalized to expected peak values before they are introduced into neural networks. Often data must be processed to put it into a form more acceptable to the neural network (e.g., a fast Fourier transformation of the time-series data to produce a spectral plot of the data). Specific applications described include: (1) Diagnostics: State of the Plant (2) Hybrid System for Transient Identification, (3) Sensor Validation, (4) Plant-Wide Monitoring, (5) Monitoring of Performance and Efficiency, and (6) Analysis of Vibrations. Although specific examples described ...

1992-01-01

138

Analysis of complex systems using neural networks  

Energy Technology Data Exchange (ETDEWEB)

The application of neural networks, alone or in conjunction with other advanced technologies (expert systems, fuzzy logic, and/or genetic algorithms), to some of the problems of complex engineering systems has the potential to enhance the safety, reliability, and operability of these systems. Typically, the measured variables from the systems are analog variables that must be sampled and normalized to expected peak values before they are introduced into neural networks. Often data must be processed to put it into a form more acceptable to the neural network (e.g., a fast Fourier transformation of the time-series data to produce a spectral plot of the data). Specific applications described include: (1) Diagnostics: State of the Plant (2) Hybrid System for Transient Identification, (3) Sensor Validation, (4) Plant-Wide Monitoring, (5) Monitoring of Performance and Efficiency, and (6) Analysis of Vibrations. Although specific examples described ...

1992-12-31

139

Advanced nanoscale separations and mass spectrometry for sensitive high-throughput proteomics  

Energy Technology Data Exchange (ETDEWEB)

We review recent development in separations and mass spectrometric instrumentation for sensitive and high-throughput proteomic analyses. These efforts have been primarily focused on the development of high-efficiency (separation peak capacity of ~103) nanoscale liquid chromatography (nanoLC; e.g., flow rates extending down to ~20 nL/min at optimal separation linear velocities through narrow packed capillaries) in combination with advanced mass spectrometry (MS), including high sensitivity and high resolution Fourier transform ion cyclotron resonance (FTICR) MS. This technology enables MS analysis of low nanogram-level proteomic samples (i.e., nanoscale proteomics) with individual protein identification sensitivity at the low zeptomole-level. The resultant protein measurement dynamic range can reach 106 for nanogram-sized proteomic samples, while more abundant proteins can be detected from complex sub-picogram size proteome samples. The average ...

2005-06-01

140

A study of the physical-chemical mechanisms and variables which affect the transport of inorganic and organic heterogeneous systems  

Science.gov (United States)

In order to model transport of dissolved ions in subsurface environments, one should understand how these ions interact with solid phase adsorbents. Our primary goal has been investigating the reaction mechanisms which affect microcontaminant partitioning between aqueous solutions and solid phase adsorbents, using goethite ({alpha}-FeOOH) as a model adsorbent. Cylindrical internal reflection -- Fourier transform infrared (CIR-FTIR) spectroscopy has been developed as the primary technique for this study. Wet chemical adsorption studies, acoustophoresis and electrophoretic mobility have been used to obtain supporting information as needed. Phenol and o-nitrophenol did not adsorb to goethite. Benzoate, phthalate and p-hydroxybenzoate all adsorbed via a bidentate mechanism to two adjacent iron atoms, while salicylate and 2,4-dihydroxybenzoate formed a chelate complex to single iron atoms. Phosphate adsorption was predominately bidentate.

1990-07-01

141

A facile method for the room-temperature synthesis of water-soluble magnetic Fe3O4 nanoparticles: Combination of in situ synthesis and decomposition of polymer hydrogel  

British Library Electronic Table of Contents (United Kingdom)

We propose and demonstrate a facile room-temperature synthetic method for obtaining water-soluble magnetic Fe3O4 nanoparticles (NPs) by combining the in situ synthesis and decomposition of a magnetic polymer hydrogel. The Fe3O4 NPs with average diameters of 6.3-8.3nm were synthesized in a cross-linked polyacrylamide (PAAm) hydrogel by coprecipitating iron ions. The decomposition of the magnetic polymer hydrogel by an aqueous solution of sodium hydroxide led to the transfer of Fe3O4 NPs into the aqueous medium. The NPs can be dispersed stably in water for more than three months. The Fe3O4 NPs were characterized by X-ray photoelectron spectra (XPS), X-ray powder diffraction (XRD), transmission electron microscope (TEM), and Fourier transform infrared spectroscopy (FT-IR). The saturation magn...

2011-01-01

142

A comparative study of natural, formaldehyde-treated and copolymer-grafted orange peel for Pb(II) adsorption under batch and continuous mode  

Energy Technology Data Exchange (ETDEWEB)

Natural, formaldehyde-treated and copolymer-grafted orange peels were evaluated as adsorbents to remove lead ions from aqueous solutions. The optimum pH for lead adsorption was found to be pH 5. The adsorption process was fast, reaching 99% of sorbent capacity in 10 min for the natural and treated biomasses and 20 min for the grafted material. The treated biomass showed the highest sorption rate and capacity in the batch experiments, with the results fitting well to a pseudo-first order rate equation. In the continuous test with the treated biomass, the capacity at complete exhaustion was 46.61 mg g{sup -1} for an initial concentration of 150 mg L{sup -1}. Scanning electronic microscopy and energy dispersive X-ray spectroscopy indicated that the materials had a rough surface, and that the adsorption of the metal took place on the surface. Fourier transform infrared spectroscopy revealed that the functional groups responsible for metallic ...

2009-01-30

143

Development of a computerized portal verification scheme for pelvic treatment fields  

International Nuclear Information System (INIS)

Purpose/Objective: At present, treatment verification between portal and reference images is performed based on manually-identified features by radiation oncologist, which is both time-consuming and potentially error-prone. There is a demand for the computerized verification procedure in clinical application. The purpose of this study is to develop a computerized portal verification scheme for pelvic treatment fields. Materials/Methods: The automated verification system involves image acquisition, image feature extraction, feature matching between reference and portal images and quantitative evaluation of patient setup. Electronic portal images with a matrix size of 256 x 256 and 12 bit gray levels were acquired using a liquid matrix electronic portal imaging device. Simulation images were acquired by digitizing simulation films using a TV camera into images with 256 x 256 matrix and 8 bit gray levels. Initially a Canny edge detector is applied to identify the field edges and an ...

1996-09-01

144

GaInP[sub 2]/GaAs tandem cells: Problems and solutions  

Energy Technology Data Exchange (ETDEWEB)

The various factors that affect the open-circuit voltage ([ital V][sub oc]) of a two-terminal GaInP[sub 2]/GaAs tandem cell are examined. These include a) an anomalous problem associated with the GaAs bottom cell and b) back surface passivation of the thin GaInP[sub 2] top cell. Solutions to these problems are presented and yield tandem [ital V][sub oc]s close to the practical theoretical limits.

1992-12-01

145

Transformation and Transition: DARPA's Role in Fostering an ...  

Science.gov (United States)

Transformation and Transition: DARPA's Role in Fostering an Emerging Revolution ... IDA Paper P-3698 Transformation and Transition: DARPA's ...

2003-11-01

146

USIMINAS experience on the fabrication of work cylinders for the tandem cold mill; Fabricacao de cilindros de trabalho para o laminador continuo a frio: a experiencia da USIMINAS  

Energy Technology Data Exchange (ETDEWEB)

A description is given of the principal steps involved in `USIMINAS` work roll manufacturing project for its tandem cold mill. The service performance of these rolls was found to be similar to that rolls supplied by traditional manufacturers. (author). 5 refs., 5 figs., 3 tabs.

1991-12-31

147

The Friction of Vehicle Brake Tandem Master Cylinder  

International Nuclear Information System (INIS)

The behaviour of an elastomeric seal for vehicle brake Tandem master cylinder is measured and analyzed in temperature and brake fluids changed. Working conditions are simulated for different piston rod velocity and cylinder supply pressure, in temperature rising, brakefluid boundary and Nanoaluminum oxide brakefluid oxide brakefluid lubrication. The result shows that Nanoaluminum oxide brakefluid with its ball shape can highly reduce friction coefficient to avoid seal excessive wear and reduce slick slip in brake applications.

2006-10-01

148

JAERI TANDEM annual report 2000. April 1, 2000 - March 31, 2001  

Energy Technology Data Exchange (ETDEWEB)

This annual report describes research activities which have been performed with the JAERI tandem accelerator and the Van de Graaff accelerator from April 1, 2000 to March 31, 2001. Summary reports of 46 papers, and lists of publication, personnel and cooperative research with universities are contained. (author)

2001-11-01

149

GaInP/GaAs tandem concentrator cells  

Energy Technology Data Exchange (ETDEWEB)

We discuss the initial development of a concentrator device based on the GaInP/GaAs monolithic tandem cell structure. The very high one-sun efficiency of this device, coupled with its characteristic low operating current, make this a promising candidate for use under high concentration. Test results for a prototype device are presented. This device achieves an efficiency of 29.5% at a concentration of 102 suns.

1994-06-30

150

Effect of oxide treatment at the microcrystalline tunnel junction of a-Si:H/a-Si:H tandem cells  

Energy Technology Data Exchange (ETDEWEB)

The electrical transport taking place in the {mu}c-Si tunnel recombination junction (TRJ) of a-Si:H/a-Si:H tandem solar cells and the role of CO{sub 2} plasma oxidation performed between microcrystalline layers is investigated in this paper with the computer code AMPS. Oxidized interfaces were modelled as simple highly defective intrinsic {mu}c-Si layers. Two different tunnel junction structures are studied in this paper: (a) (n){mu}c-Si/oxide/(p){mu}c-Si and (b) (n){mu}c-Si/(i){mu}c-Si/(p){mu}c-Si. In the last configuration the oxide interface is removed and replaced by a thin defective (i) {mu}c-Si layer. Both tunnel junctions have comparable theoretical and experimental tandem solar cell efficiencies which indirectly proves that our modelling assumption for oxidised interfaces is correct. A-Si:H/a-Si:H tandem solar cell efficiencies depend on the thickness of the intrinsic layer introduced in the tunnel junction. The ...

2000-05-01

151

Rapid determination of granisetron in human plasma by liquid chromatography coupled to tandem mass spectrometry and its application to bioequivalence study  

British Library Electronic Table of Contents (United Kingdom)

A simple, sensitive and rapid method for analysis of granisetron in human plasma, utilizing liquid chromatography tandem mass spectrometry (LC-MS/MS), has been developed and validated to satisfy FDA guidelines for bioanalytical methods. The analyte and internal standard (IS) were isolated from 100ml plasma samples by liquid-liquid extraction (LLE). A Varian 1200l tandem mass spectrometer equipped with an electrospray ionization source was operated in selected reaction monitoring (SRM) mode with the precursor-to-product ion transitions m/z 313.4/138 for granisetron and m/z 270/201 for the IS used for quantitation. The assay exhibited a linear dynamic range of 0.02-20ng/ml for granisetron in human plasma. The lower limit of quantification (LLOQ) was 0.02ng/ml with a relative standard deviati...

2006-01-01

152

High-Throughput Screening of Drugs of Abuse in Urine by Supported Liquid?Liquid Extraction and UHPLC Coupled to Tandem MS  

British Library Electronic Table of Contents (United Kingdom)

A qualitative method, involving supported liquid?liquid extraction (SLE) and ultra high pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS?MS), was developed for the rapid tentative identification of various drugs of abuse in urine. In this study, 28 drugs and metabolites were covered by the screening procedure. Before analysis, urine samples were extracted by SLE and good extraction recoveries were obtained for most investigated compounds. The UHPLC strategy was then selected for the rapid separation of amphetamines, cocaine, opiates and related compounds in urine. Using columns packed with sub-2??m particles, analysis time was reduced down to 2?min, while maintaining acceptable performance. Finally, the detection was by tandem MS operating in the single reaction...

2009-01-01

153

Water structure as a function of temperature from X-ray scatteringexperiments and ab initio molecular dynamics  

Energy Technology Data Exchange (ETDEWEB)

We present high-quality X-ray scattering experiments on pure water taken over a temperature range of 2 to 77 C using a synchrotron beam line at the advanced light source (ALS) at Lawrence Berkeley National Laboratory. The ALS X-ray scattering intensities are qualitatively different in trend of maximum intensity over this temperature range compared to older X-ray experiments. While the common procedure is to report both the intensity curve and radial distribution function(s), the proper extraction of the real-space pair correlation functions from the experimental scattering is very difficult due to uncertainty introduced in the experimental corrections, the proper weighting of OO, OH, and HH contributions, and numerical problems of Fourier transforming truncated data in Q-space. Instead, we consider the direct calculation of X-ray scattering spectra using electron densities derived from density functional theory based on real-space ...

2003-03-01

154

Study of the electron beam irradiation effect on some properties of aromatic aliphatic copolyester films; Estudo do efeito da radiacao por feixe de eletrons nas propriedades de filmes de copoliester alifatico aromatico  

Energy Technology Data Exchange (ETDEWEB)

Biodegradable and green plastics are the new tendency in the world. The effect of the electron beam irradiation in aromatic aliphatic copolyester and the blend with corn starch films (Ecoflex{sup R} and Ecobras{sup R}) were studied by tensile strength at break, elongation at break, Scanning Electronic Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC), crosslinking degree and biodegradability. The measurements in both, the machine direction and the transverse direction were made for mechanical tests. It was found that, the electron irradiation caused an increase in the strength at break of the blend with corn starch film, when doses of up to 10 kGy were applied. A significant decrease of the elongation at break of the blend with corn starch was observed at doses of 10 kGy and 40 kGy. It was not found important change in tensile properties for aromatic aliphatic copolyester. Structural ...

2008-07-01

155

Study of the electron beam irradiation effect on some properties of aromatic aliphatic copolyester films  

International Nuclear Information System (INIS)

Biodegradable and green plastics are the new tendency in the world. The effect of the electron beam irradiation in aromatic aliphatic copolyester and the blend with corn starch films (Ecoflex"R and Ecobras"R) were studied by tensile strength at break, elongation at break, Scanning Electronic Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC), crosslinking degree and biodegradability. The measurements in both, the machine direction and the transverse direction were made for mechanical tests. It was found that, the electron irradiation caused an increase in the strength at break of the blend with corn starch film, when doses of up to 10 kGy were applied. A significant decrease of the elongation at break of the blend with corn starch was observed at doses of 10 kGy and 40 kGy. It was not found important change in tensile properties for aromatic aliphatic copolyester. Structural changes of the ...

156

Study of the Effects of Ambient Conditions Upon the Performance of Fan Powered, Infrared, Natural Gas Burners  

Energy Technology Data Exchange (ETDEWEB)

Fourier transform infrared spectroscopy is a simple, fast, reliable and nondestructive analytical method. By using the method developed in Clark Atlanta University, consistent and reliable infrared spectral results can be obtained. An accurate radiant energy can be calculated from these infrared spectra by using a blackbody as the calibration standards. By means of the specially-designed-and-lab-made sampling inlet and the Horiba gas analyzers, the compositions of CO{sub 2}, CO, UCH, NOx and O{sub 2} etc. from the combustion exhaust gases have been on-line accurately analyzed. The commercial natural gas IR burner performed differently in the different conditions. For the methane-air combustion, at the equivalence ratio {Phi} = 1, the IR burner produced its maximum radiation efficiency, {approximately}31.4%, and the concentration of CO{sub 2} reached its maximum value, {approximately}10.7%. In the fuel-lean region, the O{sub 2} concentration in ...

1997-03-31

157

Structures and properties of fluorinated amorphous carbon films  

International Nuclear Information System (INIS)

Fluorinated amorphous carbon (a-C:F) films were deposited by radio frequency bias assisted microwave plasma electron cyclotron resonance chemical vapor deposition with tetrafluoromethane (CF_4) and acetylene (C_2H_2) as precursors. The deposition process was performed at two flow ratios R=0.90 and R=0.97, where R=CF_4/(CF_4+C_2H_2). The samples were annealed at 300 deg. C for 30 min. in a N_2 atmosphere. Both Fourier transform infrared and electron spectroscopy for chemical analyzer were used to characterize the a-C:F film chemical bond and fluorine concentration, respectively. A high resolution electron energy loss spectrometer was applied to detect the electronic structure. The higher CF_4 flow ratio (R=0.97) produced more sp"3 linear structure, and it made the a-C:F film smoother and softer. A lifetime of around 0.34 #mu#s and an energy gap of #approx#2.75 eV were observed in both the as-deposited and after annealing conditions. The short ...

2004-07-01

158

Rheological phase synthesis and characterization of LiNiVO{sub 4} as a high voltage cathode material for lithium ion batteries  

Energy Technology Data Exchange (ETDEWEB)

A number of high voltage cathode materials are now being considered for their ability to increase the energy density of lithium-ion batteries. In this study, a lithium-nickel composite alloy (LiNiVO{sub 4}) was synthesized using a rheological phase reduction method that incorporated mixtures of LiOH-H{sub 2}O, Ni(CH{sub 3}COO){sub 2}, 4H{sub 2}O, NH{sub 4}VO{sub 3} and C{sub 2}H{sub 2}O{sub 4}-2H{sub 2}O. The rheological phase method was used to prepare the compounds from a solid-liquid rheological mixture. Solid reactants were first mixed in a proper molar ratio, and water or solvents were added to the solid-liquid rheological body. X-ray powder diffraction (XRD) and Fourier Transform (FT) analyses were conducted to characterize the powders. Scanning electron microscopy (SEM) was used to characterize the morphological features and particle sizes of the powders. Results of the analyses indicated that the single-phase LiNiVO{sub 4} composite is ...

2008-08-15

159

Raman spectroscopic studies of liquid phase ordering and dynamics for solutions of ME6N liquid crystal: the approach to simple molecule behavior at high dilutions.  

Science.gov (United States)

We have measured the Raman isotropic profiles of the ?(C?N) band at 2235 cm(-1) for five solutions of ME6N (4-cyanophenyl-4'-hexylbenzoate) liquid crystal dissolved in CCl(4) in the range from x = 0.12 to 0.007 (x, mole fraction of ME6N) and then obtained the corresponding vibrational correlation functions, C(v)(t), by time Fourier transformation. The increase with dilution of the dephasing times ?(v) complies with the behavior of the nonmonotonic concentration dependence predicted by the fluctuation concentration model for this concentration range (x Rothschild, which, being based on the assumption that the environmental modulation is described by a stretched exponential decay e(-(t/?(0))(?)), is more appropriate for the interpretation of the vibrational correlation function arising from a distribution of relaxation processes caused, as in the present case, by the persistence of pseudonematic domains. With dilution the dispersion parameter ? ...

2010-11-11

160

Radiation testing of organic ion exchange resins  

International Nuclear Information System (INIS)

A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of "1"3"7Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). Samples of the exchangers were irradiated with a "6"0Co source to a total absorbed dose ...

1983-04-11

161

Radiation testing of organic ion exchange resins  

Energy Technology Data Exchange (ETDEWEB)

A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of {sup 137}Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). Samples of the exchangers were irradiated with a {sup 60}Co source to a total ...

1995-09-01

162

Properties of cubic boron nitride films with buffer layer control for stress relaxation using ion-beam-assisted deposition  

Energy Technology Data Exchange (ETDEWEB)

Significant ion irradiation during film growth is required for the formation of cubic boron nitride (cBN) films. Meanwhile, a huge level of intrinsic stress possibly induced by the ion bombardment has been frequently reported to result in cracking and/or lack of adhesion of deposited cBN films. The present work has been performed to investigate the interfacial and/or the buffer layer structures with better matching to the cBN film by relaxation of the film stress using ion-beam-assisted deposition (IBAD). Boron nitride films have been synthesized on Si(100) wafer and tungsten carbide (WC) substrates by depositing boron vapor under simultaneous bombardment with nitrogen ions and nitrogen-argon mixture ions in the energy range of 0.5-10 keV. Cubic BN films with enhanced tribological properties have been explored by inserting a BN layer with various B/N compositions as a controlled buffer at the interface. Significant relaxation of the film stress has been observed for the buffer layer ...

1999-09-01

163

Photodegradation and photostabilization of weathered wood flour filled polyethylene composites  

Science.gov (United States)

Wood plastic composites (WPCs) have gained popularity as building materials because of their usefulness in replacing solid wood in a variety of applications. These composites are promoted as being low-maintenance, high-durability products. However, it has been shown that WPCs exposed to weathering may experience a color change and/or loss in mechanical properties. An important requirement for building materials used in outdoor applications is the retention of their aesthetic qualities and mechanical properties during service life. Therefore, it is critical to understand the photodegradation mechanisms of WPCs exposed to UV radiation and to develop approaches to stabilize these composites against ultraviolet light. In this dissertation, the surface chemistries of weathered composites (both unstabilized and stabilized) as well as the effect of weathering on the color fade and the retention of mechanical properties were characterized. Since different methods of manufacturing WPCs lead to ...

2003-01-01

164

Neutron-computer tomography using real-time neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

A real-time neutron radiography facility was constructed including the capability of neutron tomography. The neutron beam was measured for total neutron flux ((1.0 +/- 0.2) x 10/sup 11/ m/(m/sup 2/-sec)), gold cadmium ratio (52 +/- 3) and effective neutron temperature (83/sup 0/C +/- 8/sup 0/C). The angular divergence or nonparallelism of the neutron beam was measured to be 2.3/sup 0/ +/- 0.1/sup 0/ thereby providing a means of quantifying the collimator effectiveness. The resolution capabilities of both static film and real-time neutron radiographs were quantified using a Fourier transform algorithm to calculate the modulation transfer function of both types of radiographs. The contrast sensitivity of both types of radiographs. The contrast sensitivity of both types of radiographs was measured as 3.1% for film and 4.0% for real-time radiographs. Two tomography algorithms, the simultaneous iterative reconstruction technique (SIRT) and the ...

1986-01-01

165

Neutron-computer tomography using real-time neutron radiography  

International Nuclear Information System (INIS)

A real-time neutron radiography facility was constructed including the capability of neutron tomography. The neutron beam was measured for total neutron flux ((1.0 +/- 0.2) x 10"1"1 m/(m"2-sec)), gold cadmium ratio (52 +/- 3) and effective neutron temperature (83"0C +/- 8"0C). The angular divergence or nonparallelism of the neutron beam was measured to be 2.3"0 +/- 0.1"0 thereby providing a means of quantifying the collimator effectiveness. The resolution capabilities of both static film and real-time neutron radiographs were quantified using a Fourier transform algorithm to calculate the modulation transfer function of both types of radiographs. The contrast sensitivity of both types of radiographs. The contrast sensitivity of both types of radiographs was measured as 3.1% for film and 4.0% for real-time radiographs. Two tomography algorithms, the simultaneous iterative reconstruction technique (SIRT) and the convolution method, were ...

1986-01-01

166

Investigating the formation mechanism of soot-like materials present in blast furnace coke samples  

Science.gov (United States)

An attempt to gain an understanding of the formation mechanism of these 'soot-like' materials has been made by means of tracing the changes in the molecular-mass distribution and molecular structure of the NMP-extractable materials from an injectant coal as well as its partially gasified chars and its pyrolytic tars. Variations in the SEC chromatograms provide clues about changes in the apparent molecular-mass distributions of these NMP extracts. Results suggest that the build-up of 'soot-like' materials follows from the secondary reactions of tars evolved from the injectant coal. The likely secondary-reaction pathways have been probed by collating structural information on these NMP extracts. The time-resolved 13-16 and 22-25 min elution fractions from the SEC column have been characterized using UV fluorescence (UV F) spectroscopy. Greater concentrations of larger aromatic ring systems are found present in samples formed under conditions appearing ...

2008-09-15

167

In-situ FT-IR spectroscopic studies of coal drying. In-situ FT-IR ho wo mochiita sekitan no kanso ni kansuru kenkyu  

Energy Technology Data Exchange (ETDEWEB)

This paper discusses spectral change in brown coal and bituminous coal as a result of low-temperature drying. The experiment used a Fourier transform infrared (FT-IR) spectroscopy disposed with an in-situ diffuse reflector as a water content measuring method. The FT-IR spectra of coal showed the existence of two types of adsorbed water. One of the two spectral peaks was thought to have been caused by isolated water molecules which may have been hydrogen bonded to hydrocarbon in the coal molecules and weakly bound. The other peak was thought to have been caused by water which may have been hydrogen bonded to functional groups such as hydroxyl groups in the coal molecules and strongly bound. Drying behavior in brown coal and bituminous coal showed the absorption peak at 3640 cm[sup -1] reducing faster than the absorption peak at 3360cm[sup -1]. Depressurized drying was found to be more effective than flowing nitrogen gas. The extent of absorption ...

1993-01-29

168

Identification of hydrotreatment-resistant heteroatomic species in a crude oil distillation cut by electrospray ionization FT-ICR mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

The diminishing clean oil reserve is driving the search for new or improved ways to reduce the level of NSO-containing species found in high abundance in heavy crude oils. Hydrotreatment is the currently preferred technique to remove those polar species. Unfortunately, nitrogen-containing compounds cause coke formation on the surface of the hydrotreatment catalyst, leading to partial or complete deactivation. Here, positive- and negative-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) identify those nitrogen compounds that resist hydrotreatment. ESI preferentially ionizes polar (e.g., heteroatom-containing) species: basic molecules are detected as positive ions and acidic/neutral molecules as negative ions. FT-ICR MS resolves thousands of species in a single mass spectrum, allowing for unambiguous determination of elemental composition, C{sub c}H{sub h}N{sub n}O{sub o}S{sub s}, for ...

2006-10-15

169

Growth and characterization of new semi-organic L-proline strontium chloride monohydrate single crystals  

International Nuclear Information System (INIS)

The present communication deals with the synthesis, single crystal growth and characterization of a new nonlinear optical material L-proline strontium chloride monohydrate (L-PSCM). Single crystals have been grown using the slow solvent evaporation technique. Single crystal XRD analysis confirmed that the crystal belongs to the orthorhombic structure with lattice parameter a=6.6966(3) A, b=12.4530(5) A, c=15.2432(5) A and space group P2_12_12_1. Presence of various functional groups in L-PSCM and protonation of the ions were confirmed by Fourier transform infrared spectroscopy (FT-IR) analysis. The melting point of the single crystal was found to be 126 "oC using DSC. Ultraviolet-visible spectral analyses showed that the crystal has low UV cut-off at 226 nm combined with very good transparency of 90% in a wide range. The optical band gap was estimated to be 5.82 eV. Capacitance and dielectric-loss measurements were carried out at different ...

2011-01-01

170

General formulation of neutron noise for fast reactor systems  

Energy Technology Data Exchange (ETDEWEB)

A general space- and energy-dependent formalism is developed in order to analyze zero-power neutron noise experiments in fast reactor systems. A generalized dispersion equation is combined with theoretical expressions for the experimentally measured power spectral density and variance-to-mean ratio which makes it possible to express these quantities in terms of a double moment of the Laplace and Fourier transformed Green's function of a slowing-down operator rather than those of the full Boltzmann operator. Several spatial approximations are analyzed in the context of the general formalism. In each case, the power spectral density and variance-to-mean ratio are written in terms of an appropriate fast reactor dispersion law for the medium which can be calculated from the solution to a simple slowing-down equation. The resultant expression for the power spectral density are analyzed for various combinations of neutron migration ...

1982-01-01

171

Estimation of hydrogen bondings in coal utilizing FTir and differential scanning calorimetry (DSC); FTir to DSC wo mochiita sekitannai suiso ketsugo no teiryoteki hyoka no kokoromi  

Energy Technology Data Exchange (ETDEWEB)

With an objective to know coal condensation structure which has influence on coal conversion reaction, an attempt was made on quantitative evaluation of hydrogen bonding in coal. Using as test samples the VDC made from Taiheiyo coal swollen by tetralin and vacuum-dried, and its pyrolyzed char, DSC measurement and Fourier transform infrared spectroscopy (FT) were performed. An FT spectrum comparison revealed that the VDC swollen at 220{degree}C has the hydrogen bonding relaxed partly from the original coal. However, since the change is in a huge coal molecular structure restraining space, it has stopped at relaxation of the bonding energy without causing separation as far as free radicals. On the other hand, the DSC curve shows that the VDC has slower endothermic velocity than the original coal. In other words, the difference in heat absorption amounts in both materials is equivalent to the difference of enthalpy ({Delta} H) of both materials, ...

1996-10-28

172

Enhanced biosorption of nickel(II) ions by silica-gel-immobilized waste biomass: Biosorption characteristics in batch and dynamic flow mode  

Energy Technology Data Exchange (ETDEWEB)

Batch and dynamic flow biosorption studies were carried out using the waste biomass entrapped in silica-gel matrix for the removal of nickel(II) ions from synthetic solutions and real wastewater. Batch biosorption conditions were examined with respect to initial pH, S/L ratio, contact time, and initial nickel ion concentration. Zeta potential measurements showed that immobilized biosorbent was negatively charged in the pH range of 3.0-8.0. The immobilized biomass was found to possess relatively high biosorption capacity (98.01 mg g{sup -1}), and biosorption equilibrium was established in a short time of operation (5 min). The equilibrium data were followed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Scanning electron microscope analysis was used to screen the changes on the surface structure of the waste biomass after immobilization and nickel(II) biosorption. Sorbent-sorbate interactions were confirmed by Fourier ...

2009-04-30

173

Enhanced Activity of Nanocrystalline Zeolites for Selective Catalytic Reduction of NOx  

Energy Technology Data Exchange (ETDEWEB)

Nanocrystalline zeolites with discrete crystal sizes of less than 100 nm have different properties relative to zeolites with larger crystal sizes. Nanocrystalline zeolites have improved mass transfer properties and very large internal and external surface areas that can be exploited for many different applications. The additional external surface active sites and the improved mass transfer properties of nanocrystalline zeolites offer significant advantages for selective catalytic reduction (SCR) catalysis with ammonia as a reductant in coal-fired power plants relative to current zeolite based SCR catalysts. Nanocrystalline NaY was synthesized with a crystal size of 15-20 nm and was thoroughly characterized using x-ray diffraction, electron paramagnetic resonance spectroscopy, nitrogen adsorption isotherms and Fourier Transform Infrared (FT-IR) spectroscopy. Copper ions were exchanged into nanocrystalline NaY to increase the catalytic activity. ...

2006-12-31

174

Effects of inorganic cation templates on octahedral molecular sieves of manganese oxide  

Science.gov (United States)

Five hydrated inorganic divalent cations, Mg[sup 2+], Co[sup 2+], Ni[sup 2+], Cu[sup 2+], and Zn[sup 2+], have successfully been used as templates for the synthesis of manganese oxide octahedral molecular sieves (OMS-1) having the todorokite structure. The OMS-1 samples have been well characterized by X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy/energy dispersive X-ray studies, inductively coupled plasma analysis, electron paramagnetic resonance, Fourier transform infrared spectroscopy, thiosulfate titration, and cyclohexane sorption. Catalytic CO oxidation and 2-propanol decomposition were carried out. Results show that these OMS-1 samples with a tunnel size of about 6.9 angstroms are crystalline and chemically pure. They have the following formulas: Mg[sub 3.17]Mn[sub 5.05]O[sub 12] [center dot] 4.52H[sub 2]O, Co[sub 1.84]Mn[sub 5.59]O[sub 12] [center dot] 3.45H[sub 2]O, Ni[sub ...

1994-11-30

175

Dynamic behaviour of dc double anode plasma torch at atmospheric pressure  

International Nuclear Information System (INIS)

An original dc double anode plasma torch which provides a long-time and highly stable atmospheric plasma jet has been devised for the purpose of hazardous waste treatment. The arc fluctuations and dynamic behaviour of the argon and argon-nitrogen plasma jets under different operating conditions have been investigated by means of classical tools, such as the statistic method, fast Fourier transform (FFT) and correlation analysis. In our experiments, the takeover mode is identified as the fluctuation characteristic of the argon plasma jet while the restrike mode is typical in the argon-nitrogen plasma dynamic behaviour. In the case of pure argon, the FFT and correlation calculation results of electrical signals exhibit the only characteristic frequency of 150 Hz, which originates from the torch power and is independent of any change in the operating conditions. It indicates that the nature of fluctuations in an argon plasma jet is mainly induced ...

2007-07-07

176

Chemometric study of functional groups in Pennsylvanian gymnosperm plant organs (Sydney Coalfield, Canada): Implications for chemotaxonomy and assessment of kerogen formation  

Energy Technology Data Exchange (ETDEWEB)

The samples comprise the foliage of four pteridosperm-medullosalean plant fossil species of differing preservation states and one of a cordaitean species from two Canadian Maritime sub-basins of Carboniferous age (300 Ma; Sydney and Stellarton coalfields, Nova Scotia, respectively). Included in the sample set were some coal samples from Sydney Coalfield, along with published data for coal macerals for comparison. By applying Schulze's maceration process to the fossil foliage to obtain the cuticles, five sample forms evolved, viz. compressions, cuticles and fossilized cuticles, and acidic and alkaline solutions from Schulze's process, to which was added the Sydney coal samples as the sixth form. Area integration of the absorbance spectra from solid and liquid state Fourier transform infrared (FTIR) spectroscopy, produced functional chemical parameters which were organized into a data matrix of eight variables and 62 samples (8 ...

2010-12-15

177

CO{sub 2} bands in the 3350 - 3700 cm{sup {minus}1} spectral region: Ro-vibrational constants and absolute intensities  

Energy Technology Data Exchange (ETDEWEB)

Spectroscopic constants and absolute intensities from more than 2150 transitions belonging to 52 bands of 7 isotopic species of carbon dioxide have been determined using a multispectrum nonlinear least-squares fitting technique. The spectral data (0.01 cm{sup -1} resolution) were obtained at room temperature and low pressure (<10 Torr) using the McMath-Pierce Fourier transform spectrometer of the National Solar Observatory on Kitt Peak, Arizona. A natural sample of carbon dioxide with absorption path lengths between 24 and 385m were used in recording the spectra. The first measurements have been made of the theoretically predicted 2v{sub 2}{sup 2} 2+v{sub 3} {open_quotes}forbidden{close_quotes} band of {sup 12}CO{sub 2}. Two bands which have not been predicted so far, one belonging to {sup 13}CO{sub 2} and the other to {sup 13}C{sup 16}O{sup 18}O, have been identified. The measured line intensities obtained for each band have been analyzed ...

1995-12-31

178

Analysis of acidic compound classes in crude oil by negative ion electrospray ionization high resolution FT-ICR mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

Acidic constituents in crude oil are associated with the formation of stable emulsions during production and present a challenge for efficient oil recovery and processing. Acid molecules, including naphthenic acids and acidic sulfur in crude oil cause corrosion in refineries and pipelines. Naphthenic acids are also significant because of their surface activity and marginal water solubility, so that they may leach to wastewaters and cause adverse environmental effects. Acidic components of oil are not limited to carboxylic acids but also molecules that contain sulfur and nitrogen. As such, an improved understanding of the chemistry and physics of petroleum at the molecular level is needed in order to understand the range of problems associated with acidic oil components and to design better solutions. The applications of negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for ...

2008-07-01

179

A study of the reactions of ethanol on CeO{sub 2} and Pd/CeO{sub 2} by steady state reactions, temperature programmed desorption, and in situ FT-IR  

Energy Technology Data Exchange (ETDEWEB)

The reaction of ethanol on unreduced and H{sub 2}-reduced CeO{sub 2} and 1 wt% Pd/CeO{sub 2} has been investigated by steady state reactions, temperature programmed desorption (TPD), and in situ Fourier transform infrared (FT-IR) spectroscopy. Steady state reactions have shown a zero reaction order dependency for diatomic oxygen at and above 20%, while the addition of Pd to CeO{sub 2} decreases the apparent activation energy of the reaction from 75 kJ/mol on CeO{sub 2} alone to 40 kJ/mol (Pd/CeO{sub 2}). TPD experiments following ethanol adsorption on both CeO{sub 2} and Pd/CeO{sub 2} have shown desorption profiles corresponding to unreacted ethanol and various reaction and decomposition products (acetaldehyde, acetone, CO, CO{sub 2}, and methane). Ethanol conversion to reaction products was increased by the addition of Pd, from 15 to 30% on CeO{sub 2} and H{sub 2}-reduced CeO{sub 2}, to 71 and 63% on Pd/CeO{sub 2} and H{sub 2}-reduced ...

1999-09-10

180

Two tandemly linked identical genes code for the glycosomal glyceraldehyde-phosphate dehydrogenase in Trypanosoma brucei.  

UK PubMed Central (United Kingdom)

Trypanosoma brucei contains two isoenzymes for glyceraldehyde-phosphate dehydrogenase (GAPDH); one enzyme resides in a microbody-like organelle, the glycosome, the other one is found in the cytosol....Full Text Available

1986-05-01

181

Trypanosoma cruzi glycosomal glyceraldehyde-3-phosphate dehydrogenase does not conform to the 'hotspot' topogenic signal model.  

UK PubMed Central (United Kingdom)

The genes which encode glycosomal glyceraldehyde-phosphate dehydrogenase (gGAPDH) of Trypanosoma cruzi are arranged as a tandemly repeated pair on a single chromosome and are identical at the level...Full Text Available

1990-09-01

182

TassDB2 - A comprehensive database of subtle alternative splicing events  

UK PubMed Central (United Kingdom)

BackgroundSubtle alternative splicing events involving tandem splice sites separated by a short (2-12 nucleotides) distance are frequent and evolutionarily widespread in eukaryotes,...Full Text Available

183

Tandem repeats analysis for the high resolution phylogenetic analysis of Yersinia pestis  

UK PubMed Central (United Kingdom)

BackgroundYersinia pestis, the agent of plague, is a young and highly monomorphic species. Three biovars, each one thought to be associated with the last three Y....Full Text Available

184

Proton Transfer Reactivity of Large Multiply Charged Ions  

UK PubMed Central (United Kingdom)

Charge-charge interactions dramatically influence the dissociation and proton transfer reactivity of large multiply protonated ions. In combination with tandem mass spectrometry, proton transfer...Full Text Available

1996-08-01

185

Cerebrospinal Fluid Steroidomics: Are Bioactive Bile Acids Present in Brain?*  

UK PubMed Central (United Kingdom)

In this study we have profiled the free sterol content of cerebrospinal fluid by a combination of charge tagging and liquid chromatography-tandem mass spectrometry. Surprisingly, the most abundant cholesterol...Full Text Available

2010-02-12

186

Activity-Local Symbolic State Graph Generation for High-Level ...  

Science.gov (United States)

... ie on all paths from the root to a terminal node we ... (A) A stochastic Petri net ... Tandem Queueing Network [HMKS99] 63 26 19 173 2.297e4 7.148e ...

2005-09-01

187

A BPF-FBP tandem algorithm for image reconstruction in reverse helical cone-beam CT  

UK PubMed Central (United Kingdom)

Purpose: Reverse helical cone-beam computed tomography (CBCT) is a scanning configuration for potential applications in image-guided radiation therapy in which an accurate anatomic image...Full Text Available

2010-01-01

188

GaInP/GaAs monolithic tandem concentrator cells  

Energy Technology Data Exchange (ETDEWEB)

This paper discusses design considerations for the recently introduced GaInP/GaAs monolithic tandem concentrator cell. The prototype device achieves a peak efficiency of 30.2% in a range of 140--180 suns, making this the first two-terminal device to demonstrate a verified efficiency exceeding 30%. At 425 suns the efficiency is still above 29%. The authors focus on the issues of grid design, top-cell thickness, and antireflectance coat. They also examine ways in which these aspects of the device may be modified to provide further performance improvements for future devices.

1994-12-31

189

Criterion for Baldwin instability in a symmetric tandem mirror with hot-electron end plugs  

Science.gov (United States)

The stability of a symmetric tandem mirror with hot-electron end plugs against low-frequency modes is investigated using a model first proposed by Baldwin. The Baldwin instability, which is due to the coupling of a negative-energy mode in the plug and a shear Alfven mode in the center cell, is confirmed. It is found that this instability is confined to small ranges of value of L/sub c/, the length of the center cell. Under modest restriction of parameters, the unstable regions in L/sub c/ impose little limitation on L/sub c/.

1983-02-01

190

Fourier duality as a quantization principle  

Energy Technology Data Exchange (ETDEWEB)

The Weyl-Wigner prescription for quantization on Euclidean phase spaces makes essential use of Fourier duality. The extension of this property to more general phase spaces requires the use of Kac algebras, which provide the necessary background for the implementation of Fourier duality on general locally groups. Kac algebras - and the duality they incorporate are consequently examined as candidates for a general quantization framework extending the usual formalism. Using as a test case the simplest non-trivial phase space, the half-plane, it is shown how the structures present in the complete-plane case must be modified. Traces, for example, must be replaced by their noncommutative generalizations - weights - and the correspondence embodied in the Weyl-Wigner formalism is no more complete. Provided the underlying algebraic structure is suitably adapted to each case, Fourier duality is shown to be indeed a very powerful ...

1996-08-01

192

Dr Feynman's doodles: how one scientist's simple sketches transformed physics  

CERN Multimedia

Dr Feynman's doodles: how one scientist's simple sketches transformed physics

2005-01-01

193

Computer simulation of martensitic transformations  

Energy Technology Data Exchange (ETDEWEB)

The characteristics of martensitic transformations in solids are largely determined by the elastic strain that develops as martensite particles grow and interact. To study the development of microstructure, a finite-element computer simulation model was constructed to mimic the transformation process. The transformation is athermal and simulated at each incremental step by transforming the cell which maximizes the decrease in the free energy. To determine the free energy change, the elastic energy developed during martensite growth is calculated from the theory of linear elasticity for elastically homogeneous media, and updated as the transformation proceeds.

1993-11-01

194

Energy flux operator, current conservation and the formal Fourier's law  

International Nuclear Information System (INIS)

By revisiting previous definitions, we show that one can define an energy current operator that satisfies the continuity equation for a general Hamiltonian in one dimension. This expression is useful for studying electronic, phononic and photonic energy flow in linear systems and in hybrid structures. The definition allows us to deduce the necessary conditions that result in current conservation for general-statistics systems. The discrete form of the Fourier's law of heat conduction naturally emerges in the present definition.

2009-01-16

195

Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of ...

2010-05-15

196

Fatty acid/poly(methyl methacrylate) (PMMA) blends as form-stable phase change materials for latent heat thermal energy storage  

Energy Technology Data Exchange (ETDEWEB)

Fatty acids such as stearic acid (SA), palmitic acid (PA), myristic acid (MA), and lauric acid (LA) are promising phase change materials (PCMs) for latent heat thermal energy storage (LHTES) applications, but high cost is the most drawback which limits the utility area of them in thermal energy storage. The use of fatty acids as form-stable PCM will increase their feasibilities in practical LHTES applications due to reduced cost of the energy storage system. In this regard, a series of fatty acid/poly(methyl methacrylate) (PMMA) blends, SA/PMMA, PA/PMMA, MA/PMMA, and LA/PMMA were prepared as new kinds of form-stable PCMs by encapsulation of fatty acids into PMMA which acts as supporting material. The blends were prepared at different mass fractions of fatty acids (50, 60, 70, 80, and 90% w/w) to reach maximum encapsulation ratio. All blends were subjected to leakage test by heating the blends over the melting temperature of the PCM. The blends that do not allow leakage of melted PCM ...

2008-02-15

197

MINIMARS: An attractive small tandem mirror fusion reactor  

International Nuclear Information System (INIS)

Through the innovative design of a novel end plug scheme employing octopole MHD stabilization, the authors present the conceptual design of ''MINIMARS'', a small commercial fusion reactor based on the tandem mirror principle. The current baseline for MINIMARS has a net electric output of 600 MWe and they have configured the design for short construction times, factory-built modules, inherently safe blanket systems, and multiplexing in station sizes of #approx =# 600-2400 MWe. They demonstrate that the compact octopole end cell provides a number of advantages over the more conventional quadrupole (yin-yang) end cell encountered in the MARS tandem mirror reactor study, and enables ignition to be achieved with much shorter central cell lengths. Accordingly, being economic in small sizes, MINIMARS provides an attractive alternative to the more conventional larger conceptual fusion reactors encountered to date, and would contribute significantly to ...

198

Time-domain analysis of FPSO-tanker responses in tandem offloading operation  

British Library Electronic Table of Contents (United Kingdom)

Problems experienced during Floating Production, Storage and Offloading (FPSO) tandem offloading operations were investigated. The aim of this research was to improve the reliability of such systems, and it needed a means to assess them. Time-domain simulation and analysis of offloading systems was performed using the multi-body mooring software ARIANE 7.0. Hydrodynamic interaction between the vessels was considered. The responses of the offloading system in different loading cases, different parameters of offloading hawsers and the effects of challenging environmental conditions were calculated. There was a focus on the problems of relative motion between the two bodies and its effects on the intensity of hawser forces. Minimum relative distance, maximum relative headings and maximum tens...

2010-01-01

199

The addition of trim coils to the Tandem Mirror Experiment magnet system to improve the magnetic field mapping  

International Nuclear Information System (INIS)

The mapping of the magnetic flux bundle from the center cell to the Plasma Potential Control plates (PPC) on the end fan of the Tandem Mirror Experiment Upgrade (TMX-U), was improved by the addition of trim coils (12,000 amp-turns) on each side of each end fan next to the pump beam magnetic shields. The coils' axes are oriented perpendicular to the machine centerline. These coils made the necessary corrections to the field-line mapping, while keeping the field in the nearby pump beam magnetic shield below the saturation threshold. This paper briefly describes the problem, discusses the design as it evolved, and presents the results of the field testing. A brief description of the improvement in the machine performance is also included.

200

Research on optimizing pass schedule of tandem cold mill  

Energy Technology Data Exchange (ETDEWEB)

In this paper, research on pass schedule of tandem cold mill (TCM) is carried out. According to load (reduction, rolling force, motor power) balance, non-linear equations set with variables of inter-stand thickness is constructed. The pass schedule optimization is carried out by solving the non-linear equations set. As the traditional method, the Newton-Raphson method is used for solving the non-linear equations set. In this paper a new simple method is brought up. On basis of the monotone relations between thickness and load, the inter-stands thickness is adjusted dynamically. The solution of non-linear equations set can be converged by iterative calculation. This method can avoid the derivative calculation used by traditional method. So, this method is simple and calculation speed is high. It is suitable for on-line control. (author)

2000-07-01

201

Research on optimizing pass schedule of tandem cold mill  

International Nuclear Information System (INIS)

In this paper, research on pass schedule of tandem cold mill (TCM) is carried out. According to load (reduction, rolling force, motor power) balance, non-linear equations set with variables of inter-stand thickness is constructed. The pass schedule optimization is carried out by solving the non-linear equations set. As the traditional method, the Newton-Raphson method is used for solving the non-linear equations set. In this paper a new simple method is brought up. On basis of the monotone relations between thickness and load, the inter-stands thickness is adjusted dynamically. The solution of non-linear equations set can be converged by iterative calculation. This method can avoid the derivative calculation used by traditional method. So, this method is simple and calculation speed is high. It is suitable for on-line control. (author)

2000-08-20

202

Development and validation of a reference measurement procedure for certification of phenytoin, phenobarbital, lamotrigine, and topiramate in human serum using isotope-dilution liquid chromatography/tandem mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

Phenytoin (PHT), phenobarbital (PHB), lamotrigine (LTG), and topiramate (TPM) are some of the most widely used antiepileptic drugs (AEDs). Monitoring of their concentrations in serum is important for the treatment of epilepsy. A reference measurement procedure (RMP) for certification of PHT, PHB, LTG, and TPM in serum has been developed and critically evaluated. Isotopically labeled compounds of PHT, PHB, LTG, and TPM are used as internal standards for the four AEDs. The four drugs and their respective labeled internal standards are simultaneously extracted from serum using solid-phase extraction prior to reversed-phase liquid chromatography?tandem mass spectrometry (LC-MS/MS). Chromatographic separation was performed using a C18 column. Electrospray ionization (ESI) in the positive ion mo...

2011-01-01

203

Detection of 36 antibiotics in coastal waters using high performance liquid chromatography-tandem mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

Among pharmaceuticals and personal care products released into the aquatic environment, antibiotics are of particular concern, because of their ubiquity and health effects. Although scientists have recently paid more attention to the threat of antibiotics to coastal ecosystems, researchers have often focused on relatively few antibiotics, because of the absence of suitable analytical methods. We have therefore developed a method for the rapid detection of 36 antibiotic residues in coastal waters, including tetracyclines (TCs), sulfanilamides (SAs), and quinolones (QLs). The method consists of solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS) analysis, using electrospray ionization (ESI) in positive mode. The SPE was performed with Oasis HLB and Oasi...

2011-01-01

204

Fourier analysis of energy transfer data obtained by simulating a 14-MeV #alpha#-particle in water  

International Nuclear Information System (INIS)

Data from Monte Carlo transport codes are used to model radiobiological effects. We previously reported the Fourier analysis of ionization data generated by simulating a 500-keV proton traversing water. Here, we extend Fourier analysis to energy transfer data of another radiation type, a 14-MeV #alpha#-particle. A radiobiological model based on this frequency-domain analysis views cell as an information processing system . It lends itself naturally to traditional engineering analyses. One engineering principle-the output response of a linear system to random signal-is applied here to explain the fact that there is measurable difference in the magnitude of the biological effectiveness when a given biological system is irradiated with two different radiation types of the same Linear Energy Transfer (LET).

2010-01-15

205

Real time neutron transmission investigation of the austenite-bainite transformation in grey iron  

Energy Technology Data Exchange (ETDEWEB)

The first successful application of a new method to investigate phase transformations in real time, like the decomposition of austenite into bainite in grey iron, is described. During the ongoing transformation, transmission spectra of thermal neutrons, which contain Bragg edges corresponding to the crystal structure of the transforming phases, are recorded. By evaluating the height of these Bragg edges, which is a measure of the volume fraction of the phase, at different transformation times, the transformation can be followed in-situ in a time resolved manner. The method is compared to other previously used methods (micrographs, dilatometry, diffraction techniques); also a summary and an outlook are given. ((orig.))

1994-06-01

206

Real time neutron transmission investigation of the austenite-bainite transformation in grey iron  

International Nuclear Information System (INIS)

The first successful application of a new method to investigate phase transformations in real time, like the decomposition of austenite into bainite in grey iron, is described. During the ongoing transformation, transmission spectra of thermal neutrons, which contain Bragg edges corresponding to the crystal structure of the transforming phases, are recorded. By evaluating the height of these Bragg edges, which is a measure of the volume fraction of the phase, at different transformation times, the transformation can be followed in-situ in a time resolved manner. The method is compared to other previously used methods (micrographs, dilatometry, diffraction techniques); also a summary and an outlook are given. ((orig.)).

1994-01-01

207

Resolution enhancement by subtraction of confocal signals taken at different pinhole sizes.  

Science.gov (United States)

Subtractive imaging in confocal fluorescence light microscopy is based on the subtraction of a suitably weighted widefield image from a confocal image. An approximation to a widefield image can be obtained by detection with an opened confocal pinhole. The subtraction of images enhances the resolution in-plane as well as along the optic axis. Due to the linearity of the approach, the effect of subtractive imaging in Fourier-space corresponds to a reduction of low spatial frequency contributions leading to a relative enhancement of the high frequencies. Along the direction of the optic axis this also results in an improved sectioning. Image processing can achieve a similar effect. However, a 3D volume dataset must be acquired and processed, yielding a result essentially identical to subtractive imaging but superior in signal-to-noise ratio. The latter can be increased further with the technique of weighted averaging in Fourier-space. A comparison ...

2003-01-01

208

Global Environmental Data for Mapping Infectious Disease Distribution  

UK PubMed Central (United Kingdom)

This contribution documents the satellite data archives, data processing methods and temporal Fourier analysis (TFA) techniques used to create the remotely sensed datasets on the DVD distributed...Full Text Available

2006-01-01

209

Fourier-Domain Optical Coherence Tomography and Adaptive Optics Reveal Nerve Fiber Layer Loss and Photoreceptor Changes in a Patient With Optic Nerve Drusen  

UK PubMed Central (United Kingdom)

BackgroundNew technology allows more precise definition of structural alterations of all retinal layers although it has not been used previously in cases of optic...Full Text Available

2008-06-01

210

Calorimetric and spectroscopic studies of the polymorphic phase behavior of a homologous series of n-saturated 1,2-diacyl phosphatidylethanolamines.  

UK PubMed Central (United Kingdom)

The polymorphic phase behavior of a homologous series of n-saturated 1,2-diacyl phosphatidylethanolamines was investigated by differential scanning calorimetry, 31P-nuclear magnetic resonance, and Fourier...Full Text Available

1993-04-01

211

The LLNL computer control system  

Energy Technology Data Exchange (ETDEWEB)

Lawrence Livermore National Laboratory (LLNL) has implemented a computer control system for operation of an FN tandem accelerator. The control software utilized is the Thaumaturgic Automated Control Logic (TACL) written by the Continuous Electron Beam Accelerator Facility and co-developed with LLNL. Details of the design philosophy, hardware configuration, control software, and special control algorithms will be presented. 2 refs., 4 figs.

1991-10-03

212

Repetitive satellite-like sequences are present within or upstream from 3 avian protein-coding genes.  

UK PubMed Central (United Kingdom)

Peculiar DNA sequences made up by the tandem repetition of a 5 bp unit have been identified within or upstream from three avian protein-coding genes. One sequence is located within an intron of the...Full Text Available

1983-03-11

213

Quantum Afterburner Improving the Efficiency of an Ideal Heat Engine  

CERN Document Server

By using a laser and maser in tandem, it is possible to obtain laser action in the hot exhaust gases involved in heat engine operation. Such a "quantum afterburner" involves the internal quantum states of working gas atoms or molecules as well as the techniques of cavity quantum electrodynamics and is therefore in the domain of quantum thermodynamics. As an example, it is shown that Otto cycle engine performance can be improved beyond that of the "ideal" Otto heat engine.

2002-01-01

214

Development of a new secondary beam separator and a new gas-jet target at Kyushu University  

International Nuclear Information System (INIS)

In order to facilitate observations of low energy nuclear reactions, a new type recoil mass-separator together with a new gas-jet target system is being developed at the tandem accelerator facility in Kyushu University. The expected mass-resolving power of the separator is 220 for a solid angle of 10 msr and the practical thickness of the gas-jet target will exceed 0.1 atm#centre dot#cm for the light elements of H and He. (author).

1994-06-01

215

Destabilization of the hot-electron precessional mode in tandem mirrors and bumpy tori  

International Nuclear Information System (INIS)

The high-frequency precessional mode of a hot-electron-stabilized magnetic configuration has previously been shown to be stable in a window of core-plasma mass. Under conditions of frequency matching, the resulting stable negative-energy precessional wave can be destabilized by coupling to positive-energy shear-Alfven waves. Coupling is avoided when the hot-electron precession frequency exceeds the core-plasma ion gyrofrequency.

216

Cloning and characterization of a 77-kDa oestrogen receptor isolated from a human breast cancer cell line.  

UK PubMed Central (United Kingdom)

We have cloned and characterized a 77-kDa oestrogen receptor (ER) from an oestrogen-independent subclone of the MCF-7 human breast cancer cell line. This receptor contains an in-frame, tandem duplication...Full Text Available

1997-01-01

217

4.5S RNA is encoded by hundreds of tandemly linked genes, has a short half-life, and is hydrogen bonded in vivo to poly(A)-terminated RNAs in the cytoplasm of cultured mouse cells.  

UK PubMed Central (United Kingdom)

4.5S RNA is a group of RNAs 90 to 94 nucleotides long (length polymorphism due to a varying number of UMP residues at the 3' end) that form hydrogen bonds with poly(A)-terminated RNAs isolated from...Full Text Available

1986-05-01

218

(Evaluation of the high intensity plasma sputer negative ion source and to test the response of the University of Tsukuba 13-MV tandem accelerator to mA intensity level pulsed mode heavy negative ion beams)  

Energy Technology Data Exchange (ETDEWEB)

A working visit was made to the National Laboratory for High Energy Physics, Tsukuba, Japan, during the time periods May 16, 1988--June 15, 1988 for the purposes of further evaluation of the high intensity plasma sputter negative ion source and to test the response of the University of Tsukuba 13-MV tandem accelerator to mA intensity level pulsed mode heavy negative ion beams. During the visit, the traveler worked in collaboration with Japanese scientists in installing and testing of the source on the University of Tsukuba tandem electrostatic accelerator injector. During the course of preliminary testing of the ion source and prior to actual injection into the accelerator, sparking began in one or more tube sections, which ultimately led to the decision to replace the damaged tube sections. This problem led to postponement of the scheduled tandem accelerator tests. The traveler attended the Seventh International Conference ...

1988-07-06

219

Transforming Civil Engineering. Air Force Civil Engineer ...  

Science.gov (United States)

... Civil Engineering Page 2. ... 4. TITLE AND SUBTITLE Transforming Civil Engineering (Air Force Civil Engineer, Volume 15, Number 1, 2007) 5a. ...

2011-05-14

220

Transformation of Verapamil by Cunninghamella blakesleeana  

UK PubMed Central (United Kingdom)

A filamentous fungus, Cunninghamella blakesleeana AS 3.153, was used as a microbial model of mammalian metabolism to transform verapamil, a calcium channel antagonist. The metabolites...Full Text Available

2004-05-01

221

The Challenges of Colorectal Cancer Survivorship  

UK PubMed Central (United Kingdom)

With advances in treatment, colorectal cancer is being transformed from a deadly disease to an illness that is increasingly curable. With this transformation has come increased interest in the...Full Text Available

2009-09-01

222

A fast multipole transformation for global climate calculations  

Energy Technology Data Exchange (ETDEWEB)

A fast multipole transformation is adapted to the evaluation of summations that occur in global climate calculations when transforming between spatial and spherical harmonic representations. For each summation, the timing of the fast multipole transformation scales linearly with the number of latitude gridpoints, but the timing for direct evaluations scales quadratically. In spite of a larger computational overhead, this scaling advantage renders the fast multipole method faster than direct evaluation for transformations involving greater than approximately 300 to 500 gridpoints. Convergence of the fast multipole transformation is accurate to machine precision. As the resolution in global climate calculations continues to increase, an increasingly large fraction of the computational work involves the transformation between spatial and spherical harmonic ...

1996-01-01

223

Fourier Synthesization of Optical Pulses and "Polar'' Light  

CERN Document Server

It is shown that the direct Fourier synthesization of light beams allows one to create polarity-asymmetric waves, which are able, in the process of nonlinear interaction with a medium, to break its inversion symmetry. As a result, these "polar" waves may show the effect of optical rectification in nonlinear centrosymmetric media by generating light-induced dc electric polarization. At the same time, the waves of this type, due to their unusual symmetry properties, can be used for detecting the direction and sign of a dc electric field applied to the medium. The prospects of application of polar waves to data recording and processing are discussed.

2002-01-01

224

Environmental trace gas analysis by proton-transfer-reaction mass spectrometry (PTR-MS)  

International Nuclear Information System (INIS)

The work presented here demonstrates the ability of proton-transfer-reaction mass spectrometry (PTR-MS) to perform fast-response measurements of volatile organic compounds (VOCs) (including methanol, acetonitrile, acetaldehyde, acetone, PAN-type compounds, alpha- and beta-pinene, nopinone and pinonaldehyde) at the pptv level and its versatile applicability in the field of environmental trace gas analysis. Laboratory and field experiments including various calibration techniques and intercomparisons with other measurement techniques such as gas chromatography, atmospheric pressure chemical ionization and Fourier transformation infrared spectroscopy were performed providing a first characterization of the PTR-MS instrument performance (sensitivity, detection limit, precision, accuracy). Typically a detection limit (S/N=2) of 50 pptv for a 10 s signal integration time, a precision of 5 % and an accuracy in the range between 10 and 25 % were ...

230

Off-line and on-line-monitoring of power transformers using the transfer function method  

Energy Technology Data Exchange (ETDEWEB)

The transfer function concept is well known as an additional method to evaluate the impulse test of power transformers in the test laboratory. Another application for the transfer function method is monitoring of transformers in service. Thereby, Off-line and On-line monitoring can be realized. Both kinds of monitoring are demonstrated with on-site measurements on a power transformer in service.

1996-12-31

234

Cell culture systems to study glial transformation  

Energy Technology Data Exchange (ETDEWEB)

The transformation of two different types of glial cells has been studied using an in vivo-/in vitro model and a complete in vitro model. The purpose of the study and to define in vitro model systems is to study the the neoplastic transformation of pure populations of glial cells. Data are presented to demonstrate that the transformed cells are glial and tumorigenic. (ACR)

1980-01-01

235

Rough surface  

International Nuclear Information System (INIS)

For the determination of the thermal-hydraulic performances of rough surfaces, the method of evaluation is particularly important. In order to increase confidence in the results, a new evaluation procedure was introduced. This procedure is based on the transformation of simple channel experimental results to equal boundary conditions, and on the suitable application and confirmation of these transformed values in more complicated flow channel geometries. Existing methods, applied to the results obtained in an annular channel, do not fulfil all the transformation requirements. Thus a new, more complete transformation method, which uses the turbulent eddy diffusivity model, was developed. To check the quality of this transformation, within the scope of the new evaluation procedure, the results of experimental investigation in annular channels and in a bundle of hexagonal geometry were ...

2009-08-01

236

On the Potential for Vacancy Annihilation as a Mechanism for Conditioning in Pu-1.9 at.% Ga  

Energy Technology Data Exchange (ETDEWEB)

The {delta} {yields} {alpha}{prime} martensitic transformation in Pu-1.9 at.% Ga occurs when the alloy is cooled below about -100 C. This transformation exhibits anomalous behavior, where the isothermal transformation proceeds atypically with double-C kinetics. Recent work has revealed that an ambient temperature isothermal hold (referred to as conditioning) prior to the transformation has different effects depending on whether transformation proceeds in the upper- or lower-C of the double-C: the amount of transformation is increased with conditioning in the upper-C, while the transformation in the lower-C seems to be engendered by conditioning. The mechanism by which conditioning affects the low-temperature {delta} {yields} {alpha}{prime} transformation is thus of great importance to understanding the ...

2009-03-09

237

High pressure study of AlP: Transformation to a metallic NiAs phase  

Science.gov (United States)

The crystal structure and optical reflectivity of AlP has been studied in a diamond anvil cell using energy dispersive x-ray diffraction to 43 GPa and micro-optical reflectance spectroscopy to 36 GPa. AlP undergoes a first order phase transformation from zincblende to a NiAs structure which exhibits metallic reflectivity in the near-infrared. The decrease in volume on transformation is 17%[plus minus]1%. The transformation is reversible but has large hysteresis. The equilibrium transformation pressure is 9.5[plus minus]5 GPa.

1994-12-01

238

Extended covariance under nonlinear canonical transformation in Weyl quantization  

CERN Document Server

A theory of nonunitary-invertible as well as unitary canonical transformations is formulated in the context of Weyl's phase space representations. Exact solutions of the transformation kernels and the phase space propagators are given for the three fundamental canonical maps as fractional-linear, gauge and contact (point) transformations. Under the nonlinear maps a phase space representation is mapped to another phase space representation thereby extending the standard concept of covariance. This extended covariance allows Dirac-Jordan transformation theory to naturally emerge from the Hilbert space representations in the Weyl quantization.

2000-01-01

239

Ultrasonic Phased Array Implementation of the Inside Diameter Creeping Wave Sizing Method  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a technique for implementing the ultrasonic inside diameter (ID) creeping wave technique for detection and sizing ID connected defects using a phased array ultrasonic system. The technique uses multiple focal laws to produce the examination modes. The first focal law is designed to create a shear wave nominally at the critical angle for mode conversion to a longitudinal wave at the ID of a part, thus creating a creeping wave. This focal law is focused at the ID to improve sensitivity. The rest of the laws are designed to create tandem sound paths that progress up a vertical surface directly above the focal point of the creeping wave generation point. When a defect on the inner surface is detected with the creeping wave, the height of the defect can be measured from the response of a set of tandem laws without readjusting the position of the probe. Results from standard one-inch long notches of varying depths are presented.

2006-05-01

240

Technologies for high speed rolling and control of gauge in cold tandem mill for ultra-thin gauge strip; Gokuusu reikan atsuenki ni okeru kosoku atsuen gijutsu oyobi itaatsu seigyo gijutsu  

Energy Technology Data Exchange (ETDEWEB)

This paper describes high speed rolling and gauge control in cold tandem mill for ultra-thin gauge strip at the Chiba Works of Kawasaki Steel Corporation. To improve the plate-out property of rolling oil, cationic polymeric coagulant was prepared. Rolling oil with cohesion independent of inorganic inclusions or phosphatide was developed, to improve the lubrication for cold rolling, remarkably. In addition, a low-cost Ti-enhanced work roll having high wear resistance and excellent grindability was developed. Rolling can be conducted at the optimal rolling roughness and operation can be performed at the highest rolling speed independent of the rolling treatment amount. Rolling speed at 2800 m/min was confirmed by developing the rolling oil with excellent lubrication and the work roll having high wear resistance. For the improvement of strip thickness accuracy at the steady state rolling, use of the backup roll as roller bearing was more effective rather than the ...

1996-09-01

241

Ion sources for initial use at the Holifield radioactive ion beam facility  

Energy Technology Data Exchange (ETDEWEB)

The Holifield Radioactive Ion Beam Facility (HRIBF) now under construction at the Oak Ridge National Laboratory will use the 25-MV tandem accelerator for the acceleration of radioactive ion beams to energies appropriate for research in nuclear physics; negative ion beams are, therefore, required for injection into the tandem accelerator. Because charge exchange is an efficient means for converting initially positive ion beams to negative ion beams, both positive and negative ion sources are viable options for use at the facility; the choice of the type of ion source will depend on the overall efficiency for generating the radioactive species of interest. A high-temperature version of the CERN-ISOLDE positive ion source has been selected and a modified version of the source designed and fabricated for initial use at the HRIBF because of its low emittance, relatively high ionization efficiencies and species versatility, and because it has been ...

1994-12-31

242

Ion sources for initial use at the Holifield Radioactive Ion Beam Facility  

Energy Technology Data Exchange (ETDEWEB)

The Holifield Radioactive Ion Beam Facility (HRIBF) now under construction at the Oak Ridge National Laboratory will use the 25-MV tandem accelerator for the acceleration of radioactive ion beams to energies appropriate for research in nuclear physics; negative ion beams are, therefore, required for injection into the tandem accelerator. Because charge exchange is an efficient means for converting initially positive ion beams to negative ion beams, both positive and negative ion sources are viable options for use at the facility; the choice of the type of ion source will depend on the overall efficiency for generating the radioactive species of interest. A high-temperature version of the CERN-ISOLDE positive ion source has been selected and a modified version of the source designed and fabricated for initial use at the HRIBF because of its low emittance, relatively high ionization efficiencies and species versatility, and because it has been ...

1994-05-01

243

Improved method for producing negative ion beams from the group IIA elements for tandem Van de Graaff applications  

Energy Technology Data Exchange (ETDEWEB)

A brief description of a method for producing relatively intense molecular negative ion beams for the difficult Group IIA elements is given which offers considerable improvement in terms of source operation and beam intensity stability over other methods conventionally utilized. It is particularly suited for use in cesium plasma sources such as the Aarhus geometry and axial geometry versions of the source. The method utilizes H/sub 2/ source feed gas for the production of a hydrogen-rich plasma discharge which sputters a negatively biased probe made of elemental or copper alloy material. Negative ion beams of MgH/sub 3//sup -/>=12 ..mu.. A have been realized during routine operation of the 25 MV tandem accelerator. Negative ion beam intensity data, typical source operational parameters, and examples of mass spectra associated with their production are given. Interesting intermetallic molecular negative ion beams consisting of the particular Group IIA element and ...

1983-06-01

244

Confirmatory analysis method for zeranol, its metabolites and related mycotoxins in urine by liquid chromatography-negative ion electrospray tandem mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

The determination of the banned anabolic substance zeranol and the metabolites taleranol and zearalanone in bovine urine is complicated by the occurrence of the structurally-related mycotoxin zearalenone and the corresponding {alpha}- and {beta}-zearalenol metabolites which possess similar estrogenic properties. A liquid chromatography-negative ion electrospray tandem mass spectrometric method is presented for the confirmatory analysis of all six resorcylic acid lactones ('zeranols') in urine samples using deuterium-labelled internal standards. The method was validated as a confirmatory method for bovine urine samples according to new draft EU guidelines and showed good precision and linearity, and CC{alpha} and CC{beta} values of 0.02-0.30 and <1.0 ng ml{sup -1}, respectively. The applicability was demonstrated by comparing the results of an incurred sample with previous results on the same sample obtained by gas chromatography high ...

2002-11-25

245

Versatile charged particle activation technique for the analysis of the noble metals  

Energy Technology Data Exchange (ETDEWEB)

The general usefulness of neutron activation analysis (NAA) for samples containing the platinum group elements (PGE) and Au, either as major or trace constituents, is discussed. Charged particle activation is shown to be a viable or complementary alternative. Proton (6-10 MeV) and alpha particle (9-15 MeV) beams, produced in a tandem Van de Graaff accelerator, have been established to be the most effective choice. By taking advantage of the Coulomb barrier effect and the fact that many charged particle induced reactions have relatively large threshold values, the same instrumental technique can be applied, with minor modifications, to a wide range of materials.

1982-01-01

246

Versatile charged particle activation technique for the analysis of the noble metals  

Energy Technology Data Exchange (ETDEWEB)

The general usefulness of neutron activation analysis (NAA) for samples containing the platinum group elements and Au, either as major or trace constituents, is discussed. Charged particle activation is shown to be a viable or complementary alternative. Proton (6-10 MeV) and alpha particle (9-15 MeV) beams, produced in a Tandem van de Graaff accelerator, have been established to be the most effective choice. By taking advantage of the Coulomb barrier effect and the fact that many charged particle induced reactions have relatively large threshold values, the same instrumental technique can be applied, with minor modifications, to a wide range of materials.

1983-01-01

247

Radio frequency He/sup -/ source and a source of negative ions by cesium sputtering  

Energy Technology Data Exchange (ETDEWEB)

Two sources of negative ions are described. An rf source produces up to 14 ..mu..A beams of He/sup -/ by charge exchange in Rb vapor. The other Source of Negative Ions by Cesium Sputtering (SNICS) produces a wide variety of negative ion beams in the ..mu..A range. Two important features of SNICS are its simple, compact construction and its very good beam emittance (2 to 4..pi..mm mrad MeV/sup 1/2/). Both sources have lifetimes >200 hours and they are used extensively on the Wisconsin EN tandem.

1981-04-01

248

Improved four-stage accel-decel production of low energy highly stripped heavy ions  

Energy Technology Data Exchange (ETDEWEB)

The two model MP Tandem Van de Graaff accelerators at Brookhaven have been used in a four-stage accel-decel configuration to produce highly stripped low energy heavy ions. The performance in this mode of operation has now been substantially improved by modifications of the second accelerator. The inclined field acceleration tube electrodes at the exit of this accelerator were replaced by straight electrodes, the vacuum was improved and the maximum negative terminal potential was increased. Higher intensity beams of heavier highly stripped ions can now be produced at lower energies than before.

1983-04-01

249

Improved SSAMS performance  

British Library Electronic Table of Contents (United Kingdom)

We operate a new NEC 250kV single-stage accelerator mass spectrometer (SSAMS) next to our established 5MV tandem. This permits good comparison of 14C-AMS and challenges SSAMS performance. Initial SSAMS ion-optical deficiencies have been addressed by shimming the injection magnet and 3permil 14C/13C measurement with background limited by sample chemistry is routine. Higher-precision analysis is also achievable. A problematic measurement interference remains, however. The small spectrometer was procured to add measurement capacity, and for experiments with positive ions, but is now the preferred instrument for both convenience and measurement quality.

2010-01-01

250

Identification of the #pi#g_9_/_2 band new levels in "1"2"1Cs  

International Nuclear Information System (INIS)

The #pi#g_9_/_2 band structure in "1"2"1Cs is obtained. The experiment was performed at the HI-13 MV tandem accelerator of China Institute of Atomic Energy. The excited states of "1"2"1Cs were populated via the reaction "1"1"2Sn("1"2C, p2n). The #gamma#-#gamma# coincidence data were taken with five BGO-AC HpGe detectors at beam energy of 60 Mev. The energy-level schemes of "1"2"1Cs is presented.

1992-01-01

251

High efficiency GaInP/GaAs tandem solar cells  

Energy Technology Data Exchange (ETDEWEB)

We report on multijunction GaInP/GaAs photovoltaic cells with total-area efficiencies of 29.5% at one-sun concentration and air mass (AM) 1.5 global and 25.7% one-sun, AM0. These values represent the highest efficiencies achieved by any solar cell under these illumination conditions. Three key areas in this technology are identified and discussed: the grid design, front surface passivation of the top cell, and bottom surface passivation of both cells. Aspects of cell design related to its operation under different solar spectra and under concentration are also discussed.

1994-06-30

252

Fiber optic feedthrough module and method of making same  

International Nuclear Information System (INIS)

A fiber optic feedthrough module which comprises a metal sleeve, a fiber optic element extending through the sleeve in spaced relation thereto, and a tandem series of centrally-apertured mating annular sealant bodies of thermoplastic material surrounding the fiber optic element and compressed between it and the sleeve. The module is made by first providing a loose subassembly of a plurality of individual but interfitting sealant bodies on the fiber optic element and then inserting this subassembly into a metal sleeve, following by swaging the whole assembly which eliminates clearances and provides sealed interfaces between the various contacting components. (author).

1983-05-25

253

Electron Beam and Gamma Radiolysis of Solid-State Metoclopramide  

British Library Electronic Table of Contents (United Kingdom)

Purpose Study the radiolysis of solid-state metoclopramide hydrochloride at various absorbed doses. Elucidate the structure of the degradation products to gain information on the radiolysis mechanisms. Methods Solid-state metoclopramide samples were irradiated at several doses with gamma rays and high-energy electrons to evaluate the influence of the dose rate. High-performance liquid chromatography with a diode array detector was used to measure the chemical potency as a function of the absorbed dose and to quantify the degradation products. The characterization of degradation products was performed by liquid chromatography/atmospheric pressure chemical ionization/tandem mass spectrometry. Results The degradation of solid-state metoclopramide after irradiation was negligible. No qualitati...

2006-01-01

254

Allowable variation of cold-rolled strip transverse profiles in high tension  

Science.gov (United States)

The formation mechanism of the cold-rolled strip shape with high tension was studied. An advanced method to calculate the allowable variation of strip transverse profiles was established by the strip buckling criterion, which can be more properly used in cold rolling. With this method, the aim allowable variation of the product strip transverse profile and the required transverse profile range of incoming strips can be reached. Besides, this method has been successfully applied in a domestic tandem cold mill, and the transverse profile range of incoming strips suggested with this method is more practicable and complete. Consequently, the good performance is acquired.

2010-10-01

255

Structural Insights into the Interaction of the Evolutionarily Conserved ZPR1 Domain Tandem with Eukaryotic EF1A, Receptors, and SMN Complexes  

Energy Technology Data Exchange (ETDEWEB)

Eukaryotic genomes encode a zinc finger protein (ZPR1) with tandem ZPR1 domains. In response to growth stimuli, ZPR1 assembles into complexes with eukaryotic translation elongation factor 1A (eEF1A) and the survival motor neurons protein. To gain insight into the structural mechanisms underlying the essential function of ZPR1 in diverse organisms, we determined the crystal structure of a ZPR1 domain tandem and characterized the interaction with eEF1A. The ZPR1 domain consists of an elongation initiation factor 2-like zinc finger and a double-stranded {beta} helix with a helical hairpin insertion. ZPR1 binds preferentially to GDP-bound eEF1A but does not directly influence the kinetics of nucleotide exchange or GTP hydrolysis. However, ZPR1 efficiently displaces the exchange factor eEF1B from preformed nucleotide-free complexes, suggesting that it may function as a negative regulator of eEF1A activation. Structure-based mutational and ...

2007-01-01

256

Texture transformations in thermomechanically treated steels having increased nitrogen content and alloys  

International Nuclear Information System (INIS)

In this study the results of mathematical simulation and experimental research of texture transition in stress assisted shear phase transformations are discussed. The orientation distribution function (ODF) calculation model to the any type crystalline lattice symmetry materials has been suggested. By crystalline lattice symmetry analysis this computer program determines necessary amount of the initial experimental data. The experimental verification supports this model well. The ODF calculation model after shear phase transformation with equal use of all possible variants of orientation relationship or with various degrees of variant selection worked out. In this study the experimental and calculating data of the direct and reversal shear transformations #alpha# <=> #gamma# in Fe-alloys and B2 <=> B19' in Ti-Ni alloys are discussed. The stress assisted shear phase transformation model and ...

257

Investigation of the austenite-bainite transformation in gray iron using real time neutron transmission  

Energy Technology Data Exchange (ETDEWEB)

In globulitic gray iron (3.6 wt.% C, 2.4 wt.% Si and 0.45 wt.% Mn) the decomposition of austenite into bainite is investigated in real time using a new method based on neutron scattering. During the phase transformation transmission spectra of thermal neutrons are continuously recorded containing specific Bragg edges. Thus, the transformation is followed in-situ time resolved by evaluating the relative (micro)structural fractions of the transforming phases from the heights of the corresponding Bragg edges. The progression of the transformation is described and the results are discussed. The observed late time deviations from the Avrami law are explained by residual stresses of the second kind (homogeneous microstresses), which occur during the transformation because of the different specific volumes of the phases. ((orig.))

1994-11-30

258

Investigation of the austenite-bainite transformation in gray iron using real time neutron transmission  

International Nuclear Information System (INIS)

In globulitic gray iron (3.6 wt.% C, 2.4 wt.% Si and 0.45 wt.% Mn) the decomposition of austenite into bainite is investigated in real time using a new method based on neutron scattering. During the phase transformation transmission spectra of thermal neutrons are continuously recorded containing specific Bragg edges. Thus, the transformation is followed in-situ time resolved by evaluating the relative (micro)structural fractions of the transforming phases from the heights of the corresponding Bragg edges. The progression of the transformation is described and the results are discussed. The observed late time deviations from the Avrami law are explained by residual stresses of the second kind (homogeneous microstresses), which occur during the transformation because of the different specific volumes of the phases. ((orig.)).

1994-11-01

259

Non-isothermal Smoluchowski-Poisson equations as a singular limit of the Navier-Stokes-Fourier-Poisson system  

British Library Electronic Table of Contents (United Kingdom)

ResumeLa convergence des solutions faibles du systeme de Navier-Stokes-Fourier-Poisson compressible avec un terme de frottement est etudiee dans la limite dun frottement infini, la loi de pression incluant, comme cas particulier, celle correspondant aux particules de Fermi-Dirac. La limite se trouve etre une solution faible dun systeme de Smoluchowski-Poisson non isotherme, la temperature ne dependant que de la variable temporelle et etant determinee par la conservation de lenergie totale.

2007-01-01

260

Multifractal Fourier detrended cross-correlation analysis of traffic signals  

Science.gov (United States)

Multifractal detrended cross-correlation analysis (MF-DXA) has been developed to detect the long-range power-law cross-correlation of considered signals in the presence of non-stationarity. However, crossovers arising from extrinsic periodic trends make the scaling behavior difficult to analyze. We introduce a Fourier filtering method to eliminate the trend effects and systematically investigate the multifractal cross-correlation of simulated and real traffic signals. The crossover locations are found approximately corresponding to the periods of underlying trend. Traffic velocity on one road and flows on adjacent roads show strong cross-correlation. They also present weak multifractality after periodic trends are removed. The traffic velocity and flow are cross-correlated in opposite directions which is accordant to their actual evolution.

2011-10-01

261

[Malignant transformation of human fibroblasts by neutrons and by gamma radiation: Relationship to mutations induced  

Energy Technology Data Exchange (ETDEWEB)

A brief overview if provided of selected reports presented at the International Symposium on Molecular Mechanisms of Radiation- and Chemical Carcinogen-Induced Cell Transformation held at Mackinac Island, Michigan on September 19-23, 1993.

1993-12-31

262

Vectors containing a prokaryotic dihydrofolate reductase gene transform Drosophila cells to methotrexate-resistance.  

UK PubMed Central (United Kingdom)

Transformed Drosophila Kc cell lines, resistant to methotrexate, an inhibitor of de novo purine and pyrimidine synthesis, have been obtained by calcium phosphate transfection of plasmids containing...Full Text Available

1983-01-01

263

Transforming growth factor-?1 induces intestinal myofibroblast differentiation and modulates their migration  

UK PubMed Central (United Kingdom)

AIM: To investigate the effects of transforming growth factor β1 (TGF-β1) on the differentiation of colonic lamina propria fibroblasts (CLPF) into myofibroblasts in vitro.METHODS:...Full Text Available

2009-03-28

264

Product toxicity and cometabolic competitive inhibition modeling of chloroform and trichloroethylene transformation by methanotrophic resting cells.  

UK PubMed Central (United Kingdom)

The rate and capacity for chloroform (CF) and trichloroethylene (TCE) transformation by a mixed methanotrophic culture of resting cells (no exogenous energy source) and formate-fed cells were measured....Full Text Available

1991-04-01

265

Move or Die: the Fate of the Tax Oncoprotein of HTLV-1  

UK PubMed Central (United Kingdom)

The HTLV-1 Tax protein both activates viral replication and is involved in HTLV-1-mediated transformation of T lymphocytes. The transforming properties of Tax include altering the expression of select...Full Text Available

266

Modulating factors in the expression of radiation-induced oncogenic transformation  

Energy Technology Data Exchange (ETDEWEB)

Many assays for oncogenic transformation have been developed ranging from those in established rodent cell lines where morphological alteration is scored, to those in human cells growing in nude mice where tumor invasiveness is scored. In general, systems that are most quantitaive are also the least relevant in terms of human carcinogenesis and human risk estimation. The development of cell culture systems has made it possible to assess at the cellular level the oncogenic potential of a variety of chemical, physical and viral agents. Cell culture systems afford the opportunity to identify factors and conditions that may prevent or enhance cellular transformation by radiation and chemicals. Permissive and protective factors in radiation-induced transformation include thyroid hormone and the tumor promoter TPA that increase the transformation incidence for a given dose of radiation, and retinoids, ...

1990-08-01

267

Modulating factors in the expression of radiation-induced oncogenic transformation  

International Nuclear Information System (INIS)

Many assays for oncogenic transformation have been developed ranging from those in established rodent cell lines where morphological alteration is scored, to those in human cells growing in nude mice where tumor invasiveness is scored. In general, systems that are most quantitaive are also the least relevant in terms of human carcinogenesis and human risk estimation. The development of cell culture systems has made it possible to assess at the cellular level the oncogenic potential of a variety of chemical, physical and viral agents. Cell culture systems afford the opportunity to identify factors and conditions that may prevent or enhance cellular transformation by radiation and chemicals. Permissive and protective factors in radiation-induced transformation include thyroid hormone and the tumor promoter TPA that increase the transformation incidence for a given dose of radiation, and retinoids, ...

1990-01-01

268

Identification of the Neoplastically Transformed Cells in Marek's Disease Herpesvirus-Induced Lymphomas: Recognition by the Monoclonal Antibody AV37  

UK PubMed Central (United Kingdom)

Understanding the interactions between herpesviruses and their host cells and also the interactions between neoplastically transformed cells and the host immune system is fundamental to understanding...Full Text Available

2002-07-01

269

IEC steps up work on power transformers  

Energy Technology Data Exchange (ETDEWEB)

The technical committees of the International Electrotechnical Committee (IEC) play an important part in preparing international standards. In this report the chairman of the Technical Comittee 14 (Power Transformers) describes the present state and the progressive work.

1981-03-01

270

Factors Influencing the Tissue Culture and the Agrobacterium tumefaciens-Mediated Transformation of Hybrid Aspen and Poplar Clones  

UK PubMed Central (United Kingdom)

Tissue culture conditions and transformation have been established for both aspen and poplar. The use of previously described culture conditions resulted in shoot tip necrosis in the shoot cultures...Full Text Available

1990-07-01

271

Construction of DNA recognition sites active in Haemophilus transformation.  

UK PubMed Central (United Kingdom)

Competent Haemophilus cells recognize and preferentially take up Haemophilus DNA during genetic transformation. This preferential uptake is correlated with the presence on incoming DNA of an 11-base-pair...Full Text Available

1982-04-01

272

A plausible model for reversal of neoplastic transformations in plants based on multiple steady states.  

UK PubMed Central (United Kingdom)

We offer a plausible interpretation of some experiments on the reversal of neoplastic transformations in plants. We suggest that normal cells and tumorous cells represent multiple stable-steady states...Full Text Available

1991-12-01

273

Transformational Satellite (TSAT) Communications Systems. ...  

Science.gov (United States)

... The seven existing space/airborne programs are the Defense Satellite Com- munications System (DSCS), Milstar, communications re- lay ...

2007-07-01

274

The effect of oxide inclusions on the kinetics of the austenite to ferrite transformation in low alloy steel weld metal  

Energy Technology Data Exchange (ETDEWEB)

Isothermal transformation kinetics of austenite to acicular ferrite and allotriomorphic ferrite were measured in reheated low alloy steel weld deposits with similar weld compositions and austenite grain size but different inclusion characteristics. Accelerated kinetics of transformation to acicular ferrite were observed in weld metal containing coarser and titanium-rich inclusions. In contrast, kinetics of transformation to allotriomorphic ferrite were not influenced by inclusion characteristics, but, rather, by the austenite grain size and carbon concentration.

1994-09-01

275

Problem Definition Studies on Potential Environmental ...  

Science.gov (United States)

... mutagenic, while two potential environmental transformation products, 1,4- diaminoanthraq Ynone and 1,4-dihydroxyanthraquinone are strongly ...

1979-11-01

276

From Service Operational Headquarters to Joint Task Force ...  

Science.gov (United States)

... directed the transformation of designated Service operational headquarters into effective and scalable Joint Task Force headquarters capable of ...

2007-04-27

277

Ensemble Forecasting with the Ensemble Transform Kalman ...  

Science.gov (United States)

... of these points corresponds to the ( " 2) term in ... (d) is identical to the 1-sigma ellipse corresponding ... A new approach to linear filtering and predicted ...

2004-08-01

278

EMITTANCE AND ABSORPTANCE OF NASA CERAMIC ...  

Science.gov (United States)

... The data were transformed into total hemispherical emittance values and correlated with respect to ceramic coating thickness and temperature ...

1978-06-01

279

Devolution through Transformation  

Science.gov (United States)

... Training System (JMATS) for joint C-130J training. However, the ... the C-130J's being procured by the Air Force. A logical ...

2011-05-14

281

Annual Industrial Capabilities Report to Congress  

Science.gov (United States)

... Transforming the NDS into a Strategic Materials Security Program (SMSP), a more comprehensive and flexible risk management process would ...

2010-05-01

284

Type I (RI) and type II (RII) receptors for transforming growth factor-beta isoforms are expressed subsequent to transforming growth factor-beta ligands during excisional wound repair.  

UK PubMed Central (United Kingdom)

Transforming growth factor (TGF)-beta isoforms (TGF-beta 1, -beta 2, and -beta 3) regulate cell growth and differentiation and have critical regulatory roles in the process of tissue repair and remodeling....Full Text Available

1997-01-01

285

Transformation Isotherme beta to alpha Dans L 'uranium Pur et Faiblement Allie (Beta to alpha Isothermal Transformation in Pure and Weakly Alloyed Uranium).  

Science.gov (United States)

The TTT diagrams describing the beta to alpha isothermal transformation have been made by isothermal dilatometry for pure uranium and 21 alloys based on chromium, silicon, molybdenum, iron, aluminium, zirconium. The thermal cycle preceeding the isothermal...

1966-01-01

286

Reduction of wave-function which transforms as field associated with spin zero tachyons  

International Nuclear Information System (INIS)

Reduction of wavefunction which transforms as scalar field imaginary mass system has been derived in terms of irreducible representation of proper, orthochronous, inhomogeneous Lorentz group and it has been shown that only transformation properties of wavefunction are needed in the derivation while the reality condition and wave equations only restrict the number of independent representations. The properties of energy and momentum of tachyons have been analysed and it has been shown that the tachyons are unidirectional in space. (author).

287

Magnetic domains in martensite of Ni-Mg-Ga alloy  

International Nuclear Information System (INIS)

The structural changes attendant on intermartensitic transformation in a Ni-Mg-Ga shape memory alloy are considered using magneto-optical visualization with the help of ferrite-garnet monocrystalline films. It is established that on the intermartensitic transformation the complete reorganization of martensite macrostructure fails. Martensite crystals resulted from the basic transformation change somewhat their sizes on intermartensitic transition. The existence of large-scale labyrinth magnetic domain structure is revealed

2006-05-01

288

A new unified approach to bradyons and tachyons by conformal transformations  

International Nuclear Information System (INIS)

By using linearized conformal transformations in six dimensions, a new unified approach to bradyons (v"2< c"2) and tachyons (v"2>c"2) is suggested, the essential tool being (real and imaginary) dilatations. The usual ''Generalized Lorentz transformations'' are got, In six dimensions the quadrate form is always positive, both for bradyons and for tachyons.

289

Tachyons and the radiation of an accelerated charge  

Energy Technology Data Exchange (ETDEWEB)

The motion of an accelerated charge in a vacuum is analyzed, via the superposition principle and Fourier analysis, into uniform-motion components, which include bradyonic as well as tachyonic contributions. It is shown that the former contribute only to the induction fields whereas the latter are the source of the radiation emitted by the charge, via the Sommerfeld-Cerenkov mechanism. This result calls for a reexamination of some recently formulated theories of superluminal particles.

1982-10-15

290

Study of both nature and topology of the nano-porous materials by the positron annihilation spectroscopy  

International Nuclear Information System (INIS)

By the methods of the angular distribution of photon annihilation, time distribution of photon annihilation, photoluminescence spectroscopy, Fourier IR-spectroscopy, atomic force microscopy the detail information on relation of the structural and physical properties of the porous nano-structures is obtained. Study of pores sizes in a different nano-porous materials, such as the porous silicon, porous anode aluminium oxide, porous solids exposed to light atoms ion implantation (hydrogen, deuterium, helium) is carried out.

2003-09-15

291

Predictive wavefront control for Adaptive Optics with arbitrary control loop delays  

Energy Technology Data Exchange (ETDEWEB)

We present a modification of the closed-loop state space model for AO control which allows delays that are a non-integer multiple of the system frame rate. We derive the new forms of the Predictive Fourier Control Kalman filters for arbitrary delays and show that they are linear combinations of the whole-frame delay terms. This structure of the controller is independent of the delay. System stability margins and residual error variance both transition gracefully between integer-frame delays.

2007-10-30

292

Optical measurement of electron bunching in vacuum  

International Nuclear Information System (INIS)

We report the homodyne detection of phase modulation sidebands induced on a laser beam by a coherently bunched electron beam. This provides a sensitive and nonperturbing measurement of complex Fourier time series components of the electron density. A proof-of-principle measurement of the microwave frequency component of electron density in a crossed-field device, which agrees well with a calculation of the same quantity, is reported.

293

Experience with a digital noise analysis system in subcriticality measurements on a mockup of the FFTF  

Science.gov (United States)

From nuclear science symposium; San Francisco, California, USA (14 Nov 1973). A digital Fourier analyzer was programmed to perform reactor neutron noise analysis measurements and on-line processing of the data to obtain the steady-state reactivity. The system is suitable for recovering cross spectral density with low correlatedsignal component and for repetitive measurements with efficient use of reactor time. (auth)

1973-01-01

294

Malignant transformation of diploid human fibroblasts by transfection of oncogenes  

Energy Technology Data Exchange (ETDEWEB)

This document consist of brief reports prepared by postdoctoral students supported by the project, each describing his accomplishments under the grant. Topics include (1) Malignant Transformation of MSU-1. 1 Cells by Gamma Radiation, (2) Correlation between Levels of ras Expression and Presence of Transformed Phenotypes Including Tumorigenicity, Using a Modulatable Promoter, (3) Relation between Specific rad Oncogene Expression, (4) Correlation of Genetic Changes in Fibroblastic Tumors with Malignancies, (5)Transformation of MSU-1.1 Cells by sis Oncogene, (6) Malignant Transformation of MSU-1.0 Cells, (7) Correlation of Urokinase Plasminogen Activation (mu-PA) with Malignant Phenotype, (8)Two Dimensional Gel Electrophoresis Studies of the Proteins of the Major Cell Strains of the MSU-1 Family of Cells, and (9) Correlation between Proteinase Activity Levels and Malignancy.

1992-01-01

295

Investigation into #beta##reversible##omega#-transformation in pseudo -#beta# -titanium VT30 alloy, doped with hydrogen  

International Nuclear Information System (INIS)

To study #beta# #reversible# #omega#-transformation in pseudo-#beta#-titanium alloy VT30, doped by hydrogen, methods of X-ray diffraction and thermodifferential analyses are used. It is established that in the process of heating of the hardened alloy from 0.004-0.1% H first formation and then dissolution of #omega# phase take place. An increase in hydrogen content to 0.1% decreases thermal effect of the processes and does not affect the temperature of #beta# #reversible# #omega#-transformation. Introduction of hydrogen in the concentration of 0.2% and higher suppresses completely #beta# #reversible# #omega# - transformation. A decrease in heating rate displaces #beta# #reversible# #omega#-transformation to lower temperatures.

296

Gear Fault Diagnosis Based on Continuous Wavelet Transform  

Science.gov (United States)

A new approach of gear fault diagnosis based on continuous wavelet transform is presented. Continuous wavelet transform can provide a finer scale resolution than orthogonal wavelet transform. It is more suitable for extracting mechanical fault information. In this paper, the concept of time-averaged wavelet spectrum (TAWS) based on Morlet continuous wavelet transform is proposed. Two fault diagnosis methods named spectrum comparison method (SCM) and feature energy method (FEM) based on TAWS are established. The results of the application to gearbox gear fault diagnosis show that TAWS can effectively extract gear fault information. The feature energy of the TAWS features the gear fault advancement very well and is conically proportional to the gear fault advancement.

2002-03-01

297

Acoustic cloaking and transformation acoustics  

International Nuclear Information System (INIS)

In this review, we give a brief introduction to the application of the new technique of transformation acoustics, which draws on a correspondence between coordinate transformation and material properties. The technique is formulated for both acoustic waves and linear liquid surface waves. Some interesting conceptual devices can be designed for manipulating acoustic waves. For example, we can design acoustic cloaks that make an object invisible to acoustic waves, and the cloak can either encompass or lie outside the object to be concealed. Transformation acoustics, as an analog of transformation optics, can go beyond invisibility cloaking. As an illustration for manipulating linear liquid surface waves, we show that a liquid wave rotator can be designed and fabricated to rotate the wave front. The acoustic transformation media require acoustic materials which are anisotropic and ...

2010-03-24

298

The influence of target backing on ion-beam electron spectra  

International Nuclear Information System (INIS)

Several different aspects of the influence of the target backing on in-beam electron spectra following compound nuclear reactions induced by accelerated ions at tandem energies irradiating backed targets are discussed in detail. This discussion is illustrated by a few typical examples, such as "1"2C"5"+ and "3"1P"1"0"+ beams at 4 MeV/u bombarding Sn(+Be), Sn(+Au), Pb(+C) backed targets. Moreover, the relative influence of electron backscattering, electron Doppler shift and Doppler broadening as well as #delta#-electron emission on the low energy electron spectra (E_e#<=#100 keV) obtained under such conditions are investigated in the frame of the available experimental data. (orig.).

299

Selegiline-functionalized, PEGylated poly(alkyl cyanoacrylate) nanoparticles: Investigation of interaction with amyloid-b peptide and surface reorganization  

British Library Electronic Table of Contents (United Kingdom)

Alzheimer's disease (AD) is a neurodegenerative disorder for which the research of new treatments is highly challenging. Since the fibrillogenesis of amyloid-b peptide 1-42 (Ab1-42) peptide is considered as a major cause of neuronal degeneration, specific interest has been focused on aromatic molecules for targeting this peptide. In this paper, the synthesis of selegiline-functionalized and fluorescent poly(alkyl cyanoacrylate) nanoparticles (NPs) and their evaluation for the targeting of the Ab1-42 peptide are reported. The synthetic strategy relied on the design of amphiphilic copolymers by tandem Knoevenagel-Michael addition of cyanoacetate derivatives, followed by their self-assembly in aqueous solutions to give the corresponding NPs. Different cyanoacetates were used: (i) hexadecyl cy...

2011-01-01

300

Population studies of 16 bovine STR loci for forensic purposes  

British Library Electronic Table of Contents (United Kingdom)

As a consequence of the close integration of cattle into the food chain of humans, forensically relevant cases involving cattle (Bos taurus) DNA analysis are common. However, scientific publications reporting the information content of the commonly used bovine short tandem repeat (STR) loci remains scarce. Population studies were performed for 16 polymorphic STR loci (BM1818, BM1824, BM2113, CSRM60, CSSM66, ETH3, ETH10, ETH225, HAUT27, ILSTS006, INRA023, SPS115, TGLA53, TGLA122, TGLA126, and TGLA227) including 4,162 randomly selected cattle representing 20 distinct breeds. The power of parental exclusion, expected and observed heterozygosity, probability of identity, and non-amplifying (?null?) allele frequencies were calculated. Major differences existed in the information content between...

2011-01-01

301

Particle identification for heavy ions in a time-of-flight spectrometer  

Energy Technology Data Exchange (ETDEWEB)

A time-of-flight (TOF) spectrometer has been constructed at the JAERI 20 MV tandem accelerator facility. A position-sensitive start detector, which consists of a thin carbon foil, microchannel plates and a resistive plate, was developed for the TOF measurements through the spectrometer. The time and position resolutions obtained were 120 ps and 0.3 mm for ..cap alpha.. particles from /sup 241/Am, respectively. A two-dimensional position-sensitive detector was also developed to measure the solid angle of the spectrometer and the maximum solid angle obtained was 9.5 msr. As a particle detector a Bragg curve ionization chamber was developed. From the Bragg curves of heavy ions in the detector, energies, ranges and Bragg curve peaks were measured and used for particle identification. The resolving power Z/..delta..Z of the atomic number was about 50.

1982-05-01

302

Myocardial pharmacokinetics of ebastine, a substrate for cytochrome P450 2J, in rat isolated heart  

British Library Electronic Table of Contents (United Kingdom)

BACKGROUND AND PURPOSE It is well established that cytochrome P450 2J (CYP2J) enzymes are expressed preferentially in the heart, and that ebastine is a substrate for CYP2J, but it is not known whether ebastine is metabolized in myocardium. Therefore, we investigated its pharmacokinetics in the rat isolated perfused heart. EXPERIMENTAL APPROACH Rat isolated hearts were perfused in the recirculating mode with ebastine for 130-min. The concentrations of ebastine and its metabolites, hydroxyebastine and carebastine, were measured using liquid chromatography with a tandem mass spectrometry. The data were analysed by a compartmental model. The time course of negative inotropic response was linked to ebastine concentration to determine the concentration-effect relationship. KEY RESULTS Ebastine w...

2011-01-01

303

High-power rf-pulsed modulators for the Los Alamos free-electron laser  

Energy Technology Data Exchange (ETDEWEB)

In the rf-driven free-electron laser (FEL) at the Los Alamos National Laboratory, there are two pulsed-power rf modulators as sources for two tandem, side-coupled 20-MeV linear accelerators. The rf power used to control the cavity fields is supplied by two 5.5-MW modulating anode klystrons operating at a center frequency of 1300.2 MHz. The modulation of the 125 kV klystron is achieved by using a triode switch tube that provides a pulse width up to 300 ..mu..s and a pulse repetition rate up to 10 Hz. This paper describes the present configuration of these two duplicate systems and presents plans for meeting the requirements of future rf FEL experiments at Los Alamos. 12 refs., 5 figs.

1987-09-01

304

Automatic sample preparation of sulfonamide antibiotic residues in chicken breast muscle by using dynamic microwave-assisted extraction coupled with solid-phase extraction  

British Library Electronic Table of Contents (United Kingdom)

Abstract In the work, a rapid, simple and high-throughput sample preparation method was developed for the determination of sulfonamide (SA) antibiotic residues in chicken breast muscle. The extraction and clean-up were online combined and up to 20 samples can be treated simultaneously in 6-min. The SAs were first extracted with acetonitrile under the action of microwave energy, and then the extract was directly introduced into the SPE column for on-line clean-up and concentration. Subsequently, the SAs eluted from the SPE column were determined by liquid chromatography-tandem mass spectrometry. The precisions of extraction results of 20 samples were in the range of 4.9-7.4%. The limits of detection and quantification obtained were in the range of 2.4-3.6-ng/g and 8.6-11.3-ng/g for SAs, res...

2011-01-01

305

Approach to the homoerythrina alkaloids using a tandem N-alkylation/azomethine ylide cycloaddition.  

Science.gov (United States)

Synthetic efforts toward the homoerythrina alkaloids 1-3 are described. Two separate model systems guided the pivotal [3 + 2] azomethine ylide cycloaddition cascade to form the A-C rings of these alkaloids. The cycloaddition precursors 63 and 68, prepared in nine and ten steps, respectively, from alkyne 47, each contain an enolizable ketone, a tethered electrophile, and an electron-poor dipolarophile. Heating 63 and 68 with the stannyl amine 17 generated demethoxyschelhammeridine 65 and demethoxyschelhammericine 70, the products of intramolecular azomethine ylide cycloadditions. Subsequent attempts to install the C-3 methoxy group of 1-3 are also described. PMID:17465572

2007-04-28

306

The influence of martensitic transformation on mechanical properties of cast high alloyed CrMnNi-steel under various strain rates and temperatures  

International Nuclear Information System (INIS)

Metastable austenitic steels show excellent mechanical properties, such as high strength combined with excellent ductility and toughness due to martensitic transformation under mechanical loading (transformation induced plasticity effect). A good energy consumption, and, in the case of high-alloyed metastable austenitic steels, a high corrosion resistance, increase the potential of these materials for diverse applications, also in regard of safety requirements. Up to now, numerous wrought alloys were investigated concerning mechanical behaviour, TRIP-effect, martensitic transformation behaviour and modelling of transformation kinetics or stress-strain behaviour. New high alloyed cast CrMnNi-steels, developed at Technical University Bergakademie Freiberg, provide the chance to reduce processing steps, production time and costs. In order to understand the influence of temperature on the martensitic phase ...

2010-07-01

307

Online monitoring of power transformers - a new low-cost system for small and medium power transformers; Monitoring von Leistungstransformatoren - Jetzt auch fuer kleine und mittlere Baugroessen  

Energy Technology Data Exchange (ETDEWEB)

Until now, monitoring of power transformers focussed mainly large generator and network transformers. Siemens goes a step ahead and provides a system especially developed and designed for small and medium power transformers, e.g. for the 100 kV level. This low cost version could be achieved by restriction to really necessary measuring quantities. This allows to realize also for small and medium power transformers an online monitoring including an estimation of aging and as an option an early warning to avoid unexpected failures. (orig.) [German] Die Ueberwachung (Monitoring) von Leistungstransformatoren war bisher vor allem fuer Maschinentransformatoren und grosse Netzkuppeltransformatoren in der Diskussion. Siemens geht einen Schritt weiter und stellt nun auch ein System bereit, das speziell fuer kleine und mittlere Leistungstransformatoren, z.B. der 110-kV-Spannungsebene, konzipiert ist. Diese ...

1999-09-20

308

Long-term reliability of amorphous alloy wound core distribution transformers  

Energy Technology Data Exchange (ETDEWEB)

In order to verify long-term reliability of amorphous alloy wound core distribution transformers, accelerated aging tests and field trials used by actual transformers were practiced. As for accelerated aging tests, short-circuit tests were added to imitate mechanical stress in operation on a utility's distribution system. As a result, even after the equivalent of 30 years, which was the normal expected transformer's life, magnetic characteristic was unchanged, so these transformers could be operated. Also, about field trials, two hundred transformers of four kinds were installed on a utility's distribution system to look into no-load characteristics. They were equipped with a mechanism to measure load current, background vibration and lightning surge current, so the influence for magnetic characteristic could be inspected. As a result, remarkable change ...

1994-01-01

309

Evaluation of advanced technologies for power transformers. Final report  

Energy Technology Data Exchange (ETDEWEB)

The high insulating strength of certain gases, such as sulfur hexafluoride, when used at high pressure, suggests that there may be advantages to compressed gases as the insulating fluid in power transformers. However, simply exchanging the oil for compressed gas in an otherwise conventional transformer design will not yield a significant overall advantage. Compressed gases present the engineer with properties which are quite different from mineral oil. If gases are to be used as the major insulating fluid in power transformers, then virtually all aspects of the insulation and cooling of the apparatus must be reconsidered, affording an opportunity to introduce new design concepts, new materials, and new construction techniques. In this program, the feasibility of using the following principal design concepts has been explored: sheet conductors for the windings; a system of sealed, self-contained, annular cooling ducts ...

1981-01-01

310

The canonical form of the Rabi hamiltonian  

CERN Document Server

The Rabi Hamiltonian, describing the coupling of a two-level system to a single quantized boson mode, is studied in the Bargmann-Fock representation. The corresponding system of differential equations is transformed into a canonical form in which all regular singularities between zero and infinity have been removed. The canonical or Birkhoff-transformed equations give rise to a two-dimensional eigenvalue problem, involving the energy and a transformational parameter which affects the coupling strength. The known isolated exact solutions of the Rabi Hamiltonian are found to correspond to the uncoupled form of the canonical system.

1996-01-01

311

T-duality, space-time spinors and R-R fields in curved backgrounds  

Energy Technology Data Exchange (ETDEWEB)

We obtain the T-duality transformations of space-time spinors (the supersymmetry transformation parameters, gravitinos and dilatinos) of type-II theories in curved backgrounds with an isometry. The transformation of the spinor index is shown to be a consequence of the twist that T-duality introduces between the left- and right-moving local Lorentz frames. The result is then used to derive the T-duality action on Ramond-Ramond field strengths and potentials in a simple way. We also discuss the massive IIA theory and, using duality, give a short derivation of 'mass'-dependent terms in the Wess-Zumino actions on the D-brane world-volumes.

2000-02-28

312

Quantum mechanics of spin-1/2 tachyons  

International Nuclear Information System (INIS)

The wave equation for spin;1/2 tachyons is derived from the Dirac equation and the principle of relativity extended to superluminal Lorentz frames. From this wave equation and the Dirac equation infinite velocity spinor transformations are obtained. They yield bispinors of the plane-wave states of the tachyon, their interpretation and covariant orthogonality relations satisfied by them. The transformation properties of the bispinors under Lorentz transformation are discussed. The boundary conditions for the free propagator of wave functions of tachyons are obtained and the propagator is constructed. Then the covariant S-matrix for scattering from an electromagnetic field is derived. It is applied to the scattering of electron-tachyons from the Coulomb field.

313

Online tax payment systems as an emergent aspect of governmental transformation  

British Library Electronic Table of Contents (United Kingdom)

The achievement of governmental transformation through the use of electronically delivered services is a worthy goal that requires significant planning and research to achieve. In order to reach transformational paradigm shifts in governmental operation, it will first be necessary to understand and optimize present governmental e-Service provisions. Of these, the revenue function of taxation is paramount. This paper describes factors related to the use and acceptance by accounting professionals of information technology intended to facilitate electronic tax filing systems. Though tested in the context of governmental tax management systems in Turkey, our findings on the use and acceptance of e-Tax systems are relevant and applicable to a great number of nations and contexts as the ongoing ...

2011-01-01

314

Impacts of amorphous metal-based transformers on energy efficiency and environment  

International Nuclear Information System (INIS)

Magnetic properties of a recently developed Fe-based amorphous alloy with a high saturation induction of 1.65 T are reviewed. The increased saturation induction is fully utilized in transformers with reduced magnetic losses, physical sizes and audible noises, minimizing some of the drawbacks of amorphous metal-based transformers based on a currently available amorphous alloy. Impacts of this on the worldwide energy savings and reduction of greenhouse gas emissions are discussed. A recent effort in achieving a saturation induction beyond 1.65 T in nanocrystalline alloys is mentioned.

2008-10-01

315

Intensification of harmonic spontaneous radiation with a novel undulator  

International Nuclear Information System (INIS)

We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessivecurrent in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K1 is greatly enhanced for the approximate square-wave magnetic profile: the ratio of the power emitted at f=5 by the square-wave undulator to that of the sine-wave undulator is about 15 (whereas the corresponding ...

1999-07-01

316

Intensification of Harmonic Spontaneous Radiation with a Novel Undulator  

Science.gov (United States)

We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessive current in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K < 1, for spontaneous radiation emitted along the axis of the system. The emission at harmonics f > 1 is greatly enhanced for the approximate square-wave magnetic profile: the ratio of the power emitted at f=5 ...

1998-11-01

317

Estimation of seasonal correction factors through Fourier decomposition analysis-a new model for indoor radon levels in Irish homes  

Energy Technology Data Exchange (ETDEWEB)

Radon concentrations in homes have been shown to vary considerably with season. It is important to account for this by applying a correction factor to any home radon measurement of less than one year. To date, Irish radon measurement services have used correction factors based on data derived for the UK in the 1980s. In the absence of similar data for Ireland at the time, these were considered suitable for use due to the similarities between the climates, house types and lifestyles in the two countries. In order to better estimate the long-term radon concentration, measurements from 5640 Irish homes were used to derive a set of correction factors specifically for Ireland. These were generated by means of Fourier decomposition analysis and the new correction factors compared, using 95% confidence intervals, to those derived for the UK using the same analysis and to those currently in use for Ireland. In both cases, a significant difference was found between 10 of ...

2010-09-15

318

Bar strengths in spiral galaxies estimated from 2MASS images  

CERN Document Server

Non-axisymmetric forces are presented for 107 spiral galaxies using the 2 Micron All Sky Survey (2MASS) images. We apply both Cartesian integration and a polar grid integration utilizing a limited number of azimuthal Fourier components of density. We found that bar strength is independent of the method used to evaluate the gravitational potential. However, the polar method is more suitable for weak and noisy images. Bar strength was found to be sensitive to the Hubble-type dependent scale height of the disk, which has been ignored in the previous studies. On the other hand, the method is rather insensitive to the vertical model of the disk, as long as a same vertical dispersion is assumed, or to the boxy/peanut shaped structure, studied in terms of non-constant vertical scale height along the disk. In the near-IR most galaxies in our sample show non-axisymmetric forces in some level, and 40 percent of them have bars in a sense that they have regions with a constant ...

2002-01-01

319

Simultaneous determination of the 10 major components of Da-Cheng-Qi decoction in dog plasma by liquid chromatography tandem mass spectrometry.  

Science.gov (United States)

A liquid chromatography tandem mass spectrometry (LC-MS/MS) method was developed for the simultaneous determination of the 10 major components of Da-Cheng-Qi decoction (rhein, emodin, aloe-emodin, chrysophanol, rheochrysidin, naringin, naringenin, hesperidin, magnolol and honokiol) in dog plasma. Plasma samples were spiked with internal standard (ibuprofen), acidified with HCl and extracted twice by liquid-liquid extraction using ethyl acetate. Separation was performed on a YMC-Pack ODS-A C(18) column (5 microm, 150 mm x 4.6 mm) and a C(18) guard column (5 microm, 4.0 mm x 2.0 mm) with methanol-water (92:8, v/v) at a flow rate of 0.3 mL/min. The LC/MS system was operated under the multiple reaction monitoring mode using electrospray ionization in the negative ion mode. All analytes showed good linearity over a wide concentration range (r>0.99). The linear range of the calibration curves was 5000-19.53 ng/mL for rhein; 400-3.13 ng/mL for emodin; 800-3.13 ng/mL ...

2009-05-21

320

Selection and design of ion sources for use at the Holifield radioactive ion beam facility  

Energy Technology Data Exchange (ETDEWEB)

The Holifield Radioactive Ion Beam Facility now under construction at the Oak Ridge National Laboratory will use the 25 MV tandem accelerator for the acceleration of radioactive ion beams to energies appropriate for research in nuclear physics; negative ion beams are, therefore, required for injection into the tandem accelerator. Because charge exchange is an efficient means for converting initially positive ion beams to negative ion beams, both positive and negative ion sources are viable options for use at the facility. The choice of the type of ion source will depend on the overall efficiency for generating the radioactive species of interest. Although direct-extraction negative ion sources are clearly desirable, the ion formation efficiencies are often too low for practical consideration; for this situation, positive ion sources, in combination with charge exchange, are the logical choice. The high-temperature version of the CERN-ISOLDE ...

1994-06-01

321

Screening for congenital hypothyroidism in Lebanon - An example of newborn screening in absence of mandatory law  

International Nuclear Information System (INIS)

This paper presents a group's efforts to introduce national newborn screening in Lebanon. Tandem mass spectrometry (MS) technology offers the prospect of utilizing filter paper blood specimens to screen newborns for several metabolic disorders. In order to be cost-effective, it is necessary to have a mandatory newborn screening policy. At present such a policy is not available in Lebanon. A national screening survey for congenital hypothyroidism (CH) was carried out to assess the incidence of this anomaly in the Lebanese population. Such an initiative is essential as a first step for assessing the feasibility and cost of a national screening programme. Coated beads, blood spot standards for quality control and buffer solutions used for assays were prepared in-house to minimize costs. At first, samples of umbilical cord blood spots were assayed for TSH using IRMA technique. Those samples showing borderline or high values of TSH were then assayed for total T4 (TT4) ...

2004-10-01

322

Electron-beam-plasma ion source as source of negative fluorine  

Energy Technology Data Exchange (ETDEWEB)

Radioactive ion beams (RIBs) of short-lived isotopes of fluorine are in demand for investigating astrophysical phenomena related to the hot CNO cycle and rp processes responsible for stellar nucleosynthesis. Since negative ion beams are required for injection into tandem electrostatic accelerators, such as the 25 MV tandem accelerator used for post acceleration of RIBs for the Holifield Radioactive Ion Beam Facility (HRIBF) research program at the Oak Ridge National Laboratory (ORNL), efficient, direct-formation F{sup -} ion sources are highly desirable for RIB applications involving this type of post-accelerator. We have conceived and evaluated a direct extraction F{sup -} source for potential RIB applications which is predicated on the reverse polarity operation of a positive electron-beam-plasma target/ion source (EBPTIS) while simultaneously feeding fluorine rich compounds and Cs vapor into the source. The source is found to operate in two ...

1997-11-01

323

Cloning, Expression, Crystallization and Preliminary Crystallographic Analysis of a Pentapeptide-repeat Protein (Rfr23) from the Bacterium Cyanothece 51142l  

International Nuclear Information System (INIS)

A unique feature of cyanobacteria genomes is the abundance of genes that code for hypothetical proteins containing tandem pentapeptide repeats approximately described by the consensus motif A(N/D)LXX. To date, the structures of two pentapeptide-repeat proteins (PRPs) have been determined, with the tandem pentapeptide-repeat sequences observed to adopt a novel type of right-handed quadrilateral ?-helix, or Rfr-fold, in both structures. One structure, Mycobacterium tuberculosis MfpA, is a 183-residue protein that contains 30 consecutive pentapeptide repeats and appears to offer antibiotic resistance by acting as a DNA mimic. The other structure, Cyanothece 51142 Rfr32, is a 167-residue protein that contains 21 consecutive pentapeptide repeats. The function of Rfr32, like the other 35 hypothetical PRPs identified in the genome of Cyanothece, is unknown. In an effort to understand the role of PRPs in cyanobacteria and to better characterize the ...

2006-01-01

324

Wave extrapolation in the spatial wavelet domain with application to poststack reverse-time migration  

Energy Technology Data Exchange (ETDEWEB)

A wavelet transformation is performed over each of the spatial coordinates of the scalar wave equation. This transformed equation is solved directly with a finite-difference scheme for both homogeneous and smooth inhomogeneous media. Wavefield extrapolation is performed completely in the spatial wavelet domain without transforming back into the space domain at each time step. The wavelet coefficients are extrapolated, rather than the wavefield itself. The numerical solution of the scalar wave equation in the spatial wavelet domain is closely related to the finite-difference method because of the compact support of the wavelet bases. Poststack reverse-time migration is implemented as an application. The resolution spaces of the wavelet transform provide a natural framework for multigrid analysis. Migrated images are constructed from various resolution spaces.

1998-03-01

325

Transforming Clinic Environments into Information Workspaces for Patients  

UK PubMed Central (United Kingdom)

Although clinic environments are a primary location for exchanging information with clinicians, patients experience these spaces as harsh environments to access, use, exchange, and manage information....Full Text Available

2010-01-01

326

Topological field theories and duality  

Energy Technology Data Exchange (ETDEWEB)

Topologically non trivial effects appearing in the discussion of duality transformations in higher genus manifold are discussed in a simple example, and their relation with the properties of Topological Field Theories is established. (author). 16 refs.

1996-05-01

327

The effect of aqueous composition on diffusion coefficient in bentonite  

International Nuclear Information System (INIS)

The diffusion coefficients (De) in bentonite were measured to understand and quantify the influence of groundwater chemistry such as ionic strength and to quantify the alteration of smectite mineralogical transformations. (author)

2009-12-01

328

Telomeres and telomerase in cancer  

UK PubMed Central (United Kingdom)

Myriad genetic and epigenetic alterations are required to drive normal cells toward malignant transformation. These somatic events commandeer many signaling pathways that cooperate to endow aspiring...Full Text Available

2010-01-01

329

Tachyons in gravitational field  

International Nuclear Information System (INIS)

Behaviour of tachyons in gravitational field has been investigated by using imaginary as well as real superluminal Lorentz transformations. Using real superluminal transformations in four- and six-dimensional space-time, an expression for the gravitational force acting on a tachyon, moving along the tachyon corridor constructed to follow the tachyon geodesic, has been derived. The motion of a tachyon through a black hole has also been discussed and it is shown that the black hole acts like a gravitational tunnel for tachyons and the transition between the regions inside and outside the horizon can be understood as real superluminal transformations transforming a R"4=(r,t) world into a T"4=(t,r) world. 36 refs.. (author).

330

Tachyon Cerenkov radiation  

Energy Technology Data Exchange (ETDEWEB)

By proposing the four-dimensional, reciprocity transformations the appropriate condition for superluminal electromagnetic Cerenkov radiation is obtained by introducing the hypothesis that tachyons possess vector energy and scalar momentum.

1985-09-01

331

Stress-induced martensitic transformation of metastable #beta#-titanium alloy  

International Nuclear Information System (INIS)

The constituent phases and associated deformed microstructure of the quenched Ti-xNb-(0.5-1.5) at.% Si alloy consisting of non-cytotoxicity elements, where x = 24-30 at.%, were investigated to provide pseudoelasticity for biomedical and sensor applications. Optical microscopy revealed that stress-induced martensitic transformation takes place during the deformation in the present alloys. It is confirmed from the X-ray diffraction results of the deformed specimens that the crystal structure of the stress-induced martensite phase is the orthorhombic so-called #alpha#'' structure. Within the alloys having #beta#(bcc) phase studied Nb-poor region appeared to exhibit a dominant behavior for stress-induced martensitic transformation than Nb-rich region. This result suggests that metastable #beta# phase is superior to stable #beta# phase for the occurrence of stress-induced martensitic transformation in the present alloy system.

2007-03-25

332

Seven years of operating experience with amorphous metal transformers  

Energy Technology Data Exchange (ETDEWEB)

Amorphous metals have an atomic structure resembling that of glass, and have high strength, toughness, and excellent magnetic properties for transformer applications. This type of metal has the potential to reduce the core losses of electromagnetic apparatus by 70-75% compared to the best grain-oriented silicon iron currently used. If all 4 million distribution transformers now in service in Canada were replaced by the more efficient amorphous units, it is estimated that over 5.25 billion kWh of energy could be saved annually. The experience of the General Electric (GE) Company and other researchers with operation of amorphous transformers is described. GE first tried operating amorphous metal transformers on a utility distribution system in April 1982. The shell-type cruciform design showed stable, low-loss performance over eight years of service. GE and the Electric Power Research Institute cooperated ...

1991-05-01

333

Order in Spontaneous Behavior  

UK PubMed Central (United Kingdom)

Brains are usually described as input/output systems: they transform sensory input into motor output. However, the motor output of brains (behavior) is notoriously variable, even under identical sensory...Full Text Available

334

National Advisory Committee for Aeronautics 1950 - NASA Technical ...  

Science.gov (United States)

By Charles E. Watkins. 2065. A Transformation Theory of the Partial ..... Mr. Grover Loening. Prof. John R. Markham, Massachusetts Institute of Technology. ...

335

GeoPowering the West  

Energy Technology Data Exchange (ETDEWEB)

Summary brochure of GeoPowering the West (GPW) activities, and areas of technology transfer and market transformation. It also provides current contact information for key DOE and national laboratory staff representing the GPW program.

2007-02-01

336

Fermion-boson symmetry through superluminal transformations  

Energy Technology Data Exchange (ETDEWEB)

We consider the Pauli theorem on the spin-statistics connection for faster-than-light particles. As the consequence of the unlocalizability of tachyons in space we conclude that their spin-statistics correlations are inverted.

1985-08-01

337

Dysregulation of the mevalonate pathway promotes transformation  

UK PubMed Central (United Kingdom)

The importance of cancer metabolism has been appreciated for many years, but the intricacies of how metabolic pathways interconnect with oncogenic signaling are not fully understood. With a clear understanding...Full Text Available

2010-08-24

338

Dixon's Theorem and random synchronization  

CERN Document Server

A transformation monoid on a set Omega is called synchronizing if it contains an element of rank 1 (that is, mapping the whole of Omega to a single point). In this paper, I tackle the question: given n and k, what is the probability that the submonoid of the full transformation monoid T_n generated by k random transformations is synchronizing? This question is analogous to Dixon's Theorem that two random permutations generate the symmetric or alternating group with high probability. Following the technique of Dixon's theorem, we need to analyse the maximal non-synchronizing submonoids of T_n. I develop a very close connection between transformation monoids and graphs, from which we obtain a description of non-synchronizing monoids as endomorphism monoids of graphs satisfying some very strong conditions. However, counting such graphs, and dealing with the intersections of their endomorphism monoids, ...

2011-01-01

339

Disordered bcc γ-phase to δ-phase transformation in Zr-rich U-Zr alloy  

British Library Electronic Table of Contents (United Kingdom)

The transformation mechanism of hexagonal delta phase from the disordered bcc gamma phase has not been reported before in the Zr-rich U-Zr alloy system. With the help of X-ray diffraction, transmission electron microscopy (TEM) and high-resolution TEM analyses it was shown that the gamma to delta conversion takes place by the lattice collapse mechanism of omega transformation. It was also ascertained that a higher aging temperature or time promotes the growth of all four variants of the delta phase within a parent gamma grain. In addition, ab initio electronic structure calculations showed that the bcc to hexagonal transformation, involving partial ordering of the parent bcc phase followed by (111) plane collapse, is energetically favorable.

2011-01-01

341

Characteristics of radiation-induced neoplastic transformation in vitro  

Energy Technology Data Exchange (ETDEWEB)

Data are presented to support the hypothesis that the initial step in the morphologic transformation of irradiated rodent (BALB/3T3) cells is a frequent cellular event involving a large fraction of the irradiated population. This process appears to involve DNA damage, but not to represent a targeted mutation in specific structural gene(s). Morphologic transformation and immortalization appear to be distinct steps in the overall process of transformation. In contradistinction to rodent cells, immortalization is a very rare event in human diploid cells which is induced at extremely low frequencies. The hypothesis is presented that immortality develops among clones of cells bearing stable chromosomal rearrangements which emerge during the proliferation of a population of radiation damaged cells.

1986-01-01

342

Capturing energy in the air to power electronics | SmartPlanet  

Wastenet

...smart grid applications where you could place them very close to the high-voltage transmission lines , very close to transformers and so on. Photo:...

343

Army Transformation to Expeditionary Formations  

Science.gov (United States)

... gap" between the arrival ofquick response forces, such as the 82nd Airborne Division and the ... nd Airborne is just exactly that, light airborne infantry. ...

2011-05-14

344

Alpha/Beta Heat Treatment of a Titanium Alloy with a Non ...  

Science.gov (United States)

... transformed at 705°C. The cooling rate and temperature dependence of matrix decomposition for Ti6242 was thus similar to that for Ti64 x [9]. ...

2006-08-01

345

(Hadamard transform imaging)  

Science.gov (United States)

This report describes the design of, and image reconstruction capacity of a Hadamard Raman Microscopic imager. Microscopy of benzoic acid and graphite electrodes, as well as electrophoretic blotting, are described. (CBS)

1990-01-01

346

Selection of transverse modes in laser cavities containing waveguides and open parts  

International Nuclear Information System (INIS)

The transverse modes of a submillimetre laser cavity that contains waveguides and open parts were studied theoretically and experimentally with the purpose of finding methods for mode selection. Two methods based on the filtering of the Fourier spectra of the waveguide modes and the use of their interference were substantiated numerically and realised in experiment. Special attention was paid to the mode selection in tunable lasers. Scaling laws allowing one to use the obtained results in a wide range of the cavity parameters and wavelengths are presented. (laser applications and other topics in quantum electronics)

2001-04-30

347

Lack of oscillations in Dual-Phase-Lagging heat conduction for a porous slab subject to imposed heat flux and temperature  

Energy Technology Data Exchange (ETDEWEB)

This study shows that the physical conditions necessary for thermal waves to materialize in Dual-Phase-Lagging porous media conduction are not attainable in a porous slab subject to a combination of constant heat flux and temperature (Neumann and Dirichlet) boundary conditions. It is demonstrated that the approximate equivalence between Dual-Phase-Lagging (DuPhlag) heat conduction model and the Fourier heat conduction in porous media subject to Lack of Local Thermal Equilibrium (La Lotheq) that suggested the possibility of thermal oscillations and resonance reveals a condition that cannot be fulfilled because of physical constraints. (author)

2005-07-01

348

Application of the neutron television fluoroscopic system to neutron computed tomography  

Energy Technology Data Exchange (ETDEWEB)

Recently the real-time neutron radiography system of the Kyoto University Reactor (KUR) has been developed and practically applied to penetrating the side plates of the MTR type reactor fuels and investigation of moving objects. In this paper an application of the KUR neutron TV system to neutron computed tomography (NCT) is described. By using the NTV system, projection data can be acquired in a single measurement and simultaneously the projection image can be observed on a CRT monitor. The Fourier-convolution technique is used to produce the reconstructed image and its image has a good enough quality for revealing water in a small hole of 1.5 mm in diameter. (orig.).

1984-10-01

349

Application of the neutron television fluoroscopic system to neutron computed tomography  

Energy Technology Data Exchange (ETDEWEB)

Recently the real-time neutron radiography system of the Kyoto University Reactor (KUR) has been developed and practically applied to penetrating the side plates of the MTR type reactor fuels and investigation of moving objects. In this paper an application of the KUR neutron TV system to neutron computed tomography (NCT) is described. By using the NTV system, projection data can be acquired in a single measurement and simultaneously the projection image can be observed on a CRT monitor. The Fourier-convolution technique is used to produce the reconstructed image and its image has a good enough quality for revealing water in a small hole of 1.5 mm in diameter.

1984-10-01

350

An application of the neutron television fluoroscopic system to neutron computed tomography  

International Nuclear Information System (INIS)

Recently the real-time neutron radiography system of the Kyoto University Reactor (KUR) has been developed and practically applied to penetrating the side plates of the MTR type reactor fuels and investigation of moving objects. In this paper an application of the KUR neutron TV system to neutron computed tomography (NCT) is described. By using the NTV system, projection data can be acquired in a single measurement and simultaneously the projection image can be observed on a CRT monitor. The Fourier-convolution technique is used to produce the reconstructed image and its image has a good enough quality for revealing water in a small hole of 1.5 mm in diameter. (orig.).

1984-10-01

351

Alpha-particle scattering from Ca-nuclei  

International Nuclear Information System (INIS)

The possibilities, advantages, and difficulties of determining nuclear matter densities by elastic scattering of alpha-particles are generally discussed. On the basis of particular experimental data - 104 MeV alpha-particle scattering from "4"0,"4"2,"4"4,"4"8Ca - a refined folded potential is introduced using a density-dependent alpha-nucleon-interaction and target nucleus densities described by Fourier-Bessel-series. Thereby, the total nucleon densities of these isotopes were determined with little model dependence. The resulting root-mean-square radii and density differences are compared with other experimental results obtained by different methods. (orig.).

1979-07-01

352

The accurate magnetic structure of CeAl{sub 2} at various temperatures in the ordered state  

Energy Technology Data Exchange (ETDEWEB)

The magnetic structure of the cubic compound CeAl{sub 2} is incommensurate and double-k. The moments on the two Ce sites describe two elliptical helices of opposed chiralities and lie in the (11-bar0) plane, with their Fourier components m{sup k} close to the [111] direction. Recent symmetry considerations, including for the first time the inversion center of the crystal, have reduced the number of parameters of this structure and have underlined the existence of a phase difference between the projections m{sub x}{sup k}, m{sub y}{sup k} and m{sub z}{sup k} of m{sup k}. Up to now, although many neutron investigations have been carried out on CeAl{sub 2} single crystals, no set of magnetic intensities was available which was large and good enough to check whether this phase difference exists or not. We have measured such a set of data, taking great care of the instrumental resolution in order to avoid unwanted contributions to the intensities from other domains. As ...

2008-04-02

353

The accurate magnetic structure of CeAl_2 at various temperatures in the ordered state  

International Nuclear Information System (INIS)

The magnetic structure of the cubic compound CeAl_2 is incommensurate and double-k. The moments on the two Ce sites describe two elliptical helices of opposed chiralities and lie in the (11-bar0) plane, with their Fourier components m"k close to the [111] direction. Recent symmetry considerations, including for the first time the inversion center of the crystal, have reduced the number of parameters of this structure and have underlined the existence of a phase difference between the projections m_x"k, m_y"k and m_z"k of m"k. Up to now, although many neutron investigations have been carried out on CeAl_2 single crystals, no set of magnetic intensities was available which was large and good enough to check whether this phase difference exists or not. We have measured such a set of data, taking great care of the instrumental resolution in order to avoid unwanted contributions to the intensities from other domains. As the magnetic form factor of the #GAMMA#_7 ground ...

2008-04-02

354

Dynamic-stiffness matrix of embedded and pile foundations by indirect boundary-element method  

Energy Technology Data Exchange (ETDEWEB)

The boundary-integral equation method is well suited for the calculation of the dynamic-stiffness matrix of foundations embedded in a layered visco-elastic halfspace (or a transmitting boundary of arbitrary shape), which represents an unbounded domain. It also allows pile groups to be analyzed, taking pile-soil-pile interaction into account. The discretization of this boundary-element method is restricted to the structure-soil interface. All trial functions satisfy exactly the field equations and the radiation condition at infinity. In the indirect boundary-element method distributed source loads of initially unknown intensities act on a source line located in the excavated part of the soil and are determined such that the prescribed boundary conditions on the structure-soil interface are satisfied in an average sense. In the two-dimensional case the variables are expanded in a Fourier integral in the wave number domain, while in three dimensions, ...

1984-08-01

355

Transforming growth factor-? signaling mediates hypoxia-induced pulmonary arterial remodeling and inhibition of alveolar development in newborn mouse lung  

UK PubMed Central (United Kingdom)

Hypoxia causes abnormal neonatal pulmonary artery remodeling (PAR) and inhibition of alveolar development (IAD). Transforming growth factor (TGF)-β is an important regulator of lung development...Full Text Available

2008-07-01

356

The explicit Laplace transform for the Wishart process  

CERN Document Server

We derive the explicit formula for the joint Laplace transform of the Wishart process and its time integral which extends the original approach of Bru. We compare our methodology with the alternative results given by the variation of constants method, the linearization of the Matrix Riccati ODE's and the Runge-Kutta algorithm. The new formula turns out to be fast, accurate and very useful for applications when dealing with stochastic volatility and stochastic correlation modelling.

2011-01-01

357

Super schwarzian derivatives in N = 4 SU(2)-extended superconformal algebras  

Energy Technology Data Exchange (ETDEWEB)

The authors investigate anomalous terms in finite superconformal transformations in N = 4 SU(2)-extended superconformal algebras (SCA). Based on the superspace formalism they obtain super Schwarzian derivatives for the N = 4 SCA. Solutions for global superconformal transformations with the vanishing super-Schwarzian derivatives are given.

1990-05-10

358

Structural transformation and superconductivity in A-15 compounds  

International Nuclear Information System (INIS)

The correlation between superconductivity and structural transformation in the A-15 compounds are examined in a unified way on the basis of the Gor'kov three-dimensional model and the anisotropic pairing interaction. The temperature dependence of the elastic modulus, the strain order parameter and the energy gaps of superconductivity are obtained and compared with the experimental data. (auth.).

359

Permanental Vectors  

CERN Document Server

A permanental vector is a generalization of a vector with components that are squares of the components of a Gaussian vector, in the sense that the matrix that appears in the Laplace transform of the vector of Gaussian squares is not required to be either symmetric or positive definite. In addition the power of the determinant in the Laplace transform of the vector of Gaussian squares, which is -1/2, is allowed to be any number less than zero. It was not at all clear what vectors are permanental vectors. In this paper we characterize all permanental vectors in $R^{3}_{+}$ and give applications to permanental vectors in $R^{n}_{+}$ and to the study of permanental processes.

2011-01-01

360

On the GBDT version of the B\\"acklund-Darboux transformation and its applications to the linear and nonlinear equations and Weyl theory  

CERN Document Server

A general theorem on the GBDT version of the B\\"acklund-Darboux transformation for systems rationally depending on the spectral parameter is treated and its applications to nonlinear equations are given. Explicit solutions of direct and inverse problems for Dirac-type systems, including systems with singularities, and for the system auxiliary to the $N$-wave equation are reviewed. New results on explicit construction of the wave functions for radial Dirac equation are obtained.

2009-01-01

361

Nuclear electromagnetic currents from chiral EFT  

International Nuclear Information System (INIS)

Using the method of unitary transformation in combination with chiral effective field theory we derive the pion exchange contributions to the two-nucleon electromagnetic current. A formal definition of the current operator in this scheme and the power counting is presented. We discuss the implications of additional unitary transformations that have to be present to ensure the renormalizability of the one-pion exchange current. Further, we give explicit and compact results for the current in coordinate-space.

2010-03-15

362

New techniques of power transformers monitoring and diagnostic; Novas tecnicas de monitoramento e diagnostico de transformadores de potencia  

Energy Technology Data Exchange (ETDEWEB)

This article describes the techniques for monitoring electric power transformers applied by the Light to select and recover critical unities. The plan involved 20 and 40 MV A equipment and, as a reflex of the technique application, presented a substantial failure reduction.

2003-04-01

363

Four-nucleon force using the method of unitary transformation  

Energy Technology Data Exchange (ETDEWEB)

We discuss in detail the derivation of the leading four-nucleon force in chiral effective field theory using the method of unitary transformation. The resulting four-nucleon force is given in both momentum and configuration space. It does not contain any unknown parameters and can be used in few- and many-nucleon studies. (orig.)

2007-11-15

364

Duality rotations  

Energy Technology Data Exchange (ETDEWEB)

Irrespective of supersymmetry, it is interesting to understand the special properties of theories admitting duality rotations. The Lagrangian of such a theory is not invariant under the transformations, nor does it change by a total derivative, but it transforms in a particular way which implies that the system of the equations of motion is invariant and that observables, such as the energy momentum tensor and therefore the total energy and momentum, are invariant. The main results of a recent paper on the properties of theories admitting duality rotations written in collaboration with M. K. Gaillard (1981) are described.

1981-11-01

365

Direct conversion of fusion energy into the electric one in the 'Dragon' magnetic confinement system  

International Nuclear Information System (INIS)

It is shown that recuperator in which the thermal energy of particles is transformed into electric oue under drift in crossed fields is naturally coupled with dragontype magnetic confinement system, so the recuperation process can be initiated in the dragon magnetic field. A number of questions occuring under analysis of recuperator-dragon system is considered, including the dynamics of particle transfer to the recuperator, the share of particles entering the recuperator, the effect of rotational transform and the recuperation efficiency.

366

Cellular Sources of Transforming Growth Factor-? Isoforms in Early and Chronic Radiation Enteropathy  

UK PubMed Central (United Kingdom)

The three mammalian transforming growth factor (TGF)-β isoforms (TGF-β1, TGF-β2, and TGF-β3) differ in their putative roles in radiation-induced fibrosis in intestine...Full Text Available

1998-11-01

367

Carbide transformations in a gamma/gamma-prime nickel alloy during prolonged aging  

Energy Technology Data Exchange (ETDEWEB)

Carbide reactions occurring in a precipitation-hardening gamma/gamma-prime Ni-Cr alloy during prolonged high-temperature aging are investigated experimentally. It is found that the decomposition of primary MC carbides, which is accompanied by the precipitation of M23C6 particles, may lead to void nucleation and growth. The effect of carbide transformations on the residual properties of the material at temperatures above the equicohesion temperature is observed at the late stages of aging only. 6 references.

1988-08-01

368

Assessing the internal mechanical integrity of power transformers using vibration tests  

Energy Technology Data Exchange (ETDEWEB)

Machine condition monitoring (MCM) has the capability to predict equipment maintenance needs which can reduce forced down-time and facilitate the avoidance of catastrophic failures and the consequential secondary damage. It can be used to allow confident deferral of routine maintenance, and improve equipment performance, availability, reliability and safety. In order to capitalize on the potential benefits of MCM directed toward power transformers two types of vibration tests were conducted on transformers owned and operated by Cargill Inc. and IES Utilities at the Bridgeport corn plant in Eddyville, Iowa. These tests involved collecting vibration signals from the transformer tank walls during transformer energization at no-load and during steady state operation at various loads. These vibration signals were then used to detect deterioration of internal mechanical integrity. Both types of tests ...

1996-12-31

369

Multistep process of neoplastic transformation of normal human fibroblasts by 60Co gamma rays and Harvey sarcoma viruses  

Energy Technology Data Exchange (ETDEWEB)

As reported previously (Namba et al., 1985), normal human fibroblasts were transformed by 60Co gamma-ray irradiation into immortal cells with abnormal karyotypes. These transformed cells (KMST-6), however, showed a low cloning efficiency in soft agar and no transplantability. However, upon treatment with Harvey murine sarcoma virus (Ha-MSV), the cells acquired elevated clonability in soft agar and transplantability in nude mice. Ha-MSV alone, however, did not convert normal human fibroblasts into either immortal or tumorigenic cells. The Ha-MSV-transformed KMST-6 cells showed an enhanced expression of the ras oncogene, but normal and 60Co gamma-ray-transformed cells did not. Our current data suggest that gamma rays worked against normal human cells as an initiator, giving rise to chromosome aberrations and immortality, and that Ha-MSV, probably through its ras oncogene, played a role in the progression ...

1986-03-15

370

Interaction of x-rays and food pyrolysis products in producing oncogenic transformation in vitro  

International Nuclear Information System (INIS)

In recent years it has become evident from epidemiological and experimental data that a large number of environmental factors, including diet, play a role in modifying the incidence of cancer. Cell culture systems in which oncogenic transformation serves as an end point are powerful tools for evaluating these questions. Using such systems it has been shown recently that pyrolysis products from charred surfaces of broiled meat and fish can transform hamster embryo cells in vitro as well as produce tumors in the animal. Our studies in vitro have demonstrated the oncogenic potential of ionizing radiation in both hamster and human cells and have established in hamster cells the dose response relationship at doses ranging from 1 to 600 rad for x-rays and 0.1 to 150 rad for neutrons. The present work was aimed at evaluating whether there exists a cocarcinogenic interaction between a pyrolysis product and x-rays in their ability to ...

1981-07-01

371

Genome lability in radiation-induced transformants of C3H 10T1/2 mouse fibroblasts  

Energy Technology Data Exchange (ETDEWEB)

We have been investigating radiation-induced neoplastic transformants of C3H 10T1/2 mouse fibroblasts for evidence of heritable changes. C3H 10T1/2 cells were treated with 8 Gy X rays. After approximately 8 weeks of culture, type II/III foci were isolated from the monolayer using cloning rings. Cell lines developed from these foci, and clones established from these cell lines, were examined for DNA content. The isolated focus-derived populations and derived clones often display aneuploidy and/or polyploidization. In one instance a clone (derived from a single cell) displayed multiple polyploidies. During passage the ploidy of many of the anomalous populations gradually reverted to the ploidy of the non-neoplastically transformed state. The morphological features associated with the neoplastic transformation event were nevertheless retained. The results demonstrate that exposure to radiation can induce, in association with ...

1994-04-01

372

Feature extraction for rolling element bearing fault diagnosis utilizing generalized S transform and two-dimensional non-negative matrix factorization  

Science.gov (United States)

This paper presents a novel feature extraction scheme for roller bearing fault diagnosis utilizing generalized S transform and two-dimensional non-negative matrix factorization (2DNMF). The generalized S transform, which can make up the poor energy concentration of the standard S transform, is introduced to generate the time-frequency representation (TFR). Experiment results on simulated signal and vibration signals measured from rolling element bearings have revealed that the generalized S transform can obtain a more satisfactory TFR than other similar techniques. Furthermore, a new technique called two-dimensional non-negative matrix factorization (2DNMF), which can reduce the computation cost and preserve more structure information hiding in original 2D matrices compared to the NMF, is developed to extract more informative features from the time-frequency matrixes for accurate fault classification. ...

2011-05-01

373

Characteristic Of Induction Magnetic Field On The Laboratory Scale Superconducting Fault Current Limiter Circuit  

International Nuclear Information System (INIS)

Model construction of the laboratory scale superconducting fault current limiter circuit (SFCL) has been performed. The SFCL is fault current limiter and used as electric network security. It mainly consists of a copper coil, a superconducting ring and an iron core that are concentrically arranged. The SFCL circuit is essentially a transformer where the secondary windings are being replaced by the ring of YBa_2Cu_3O_7_-_x superconductor (HTS). The ring has critical transition temperature Tc = 92 K and critical current Ic = 3.61 A. Characterization of the SFCL circuit is simulated by ANSYS version 5.4 software. The SFCL circuit consists of load and transformer impedances. The results show that the inductions of magnet field flux in the iron core of primer windings and ring disappear to one other before fault state. It means that impedance of the transformer is zero. After the condition a superconductivity behavior of the ...

2004-06-01

374

Versatile high intensity plasma sputter heavy negative ion source  

Energy Technology Data Exchange (ETDEWEB)

A multicusp magnetic field plasma surface ion source, normally used for H/sup -/ ion beam formation, has been utilized for the generation of high intensity, pulsed, heavy negative ion beams suitable for a variety of uses including tandem electrostatic accelerator/synchrotron injection applications. Sputter probe voltage limited total ion currents of 5.5, 8.2, 5.1 and 4.5 mA (peak intensity) have been produced from Au, Cu, Ni and CuO sputter probes, respectively. The mass distributions of these ion beams are found to be dominated by Au/sup -/, Cu/sup -/, Ni/sup -/ and O/sup -/ atomic species, respectively. The source offers the interesting prospect of providing cw negative ion beams at mA intensity levels of the commonly used semiconducting material dopants (e.g. B/sup -/, P/sup -/, As/sup -/ and Sb/sup -/) as well as O/sup -/ for isolation barrier formation. Illustrative examples of intensity versus time and the mass distribution of ion beams extracted from a Ni ...

1988-07-01

375

Thymidylate synthase expression and genotype have no major impact on the clinical outcome of colorectal cancer patients treated with 5-fluorouracil  

British Library Electronic Table of Contents (United Kingdom)

Background and objectives.Thymidylate synthase (TS) expression levels appear to be related to response to 5-fluorouracil-(5-FU)-based chemotherapy in colorectal cancer (CRC) patients. Three polymorphisms have been proposed as modulators of TS expression: a tandemly repeated sequence (2R/3R) in the 5? UTR, a SNP (G > C) within the 3R allele and a 6 bp deletion in the 3' UTR.To evaluate the influence of TS expression and polymorphisms on clinical outcome of 5-FU-treated patients we performed a comprehensive genetic analysis on 63 CRC patients.Methods.TS expression levels were analyzed in normal and tumor tissues. TS coding sequence and UTR polymorphisms were investigated on DNA from normal tissue. LOH analysis was performed to determine tumor genotype.Results.A difference in disease-free sur...

2011-01-01

376

The mitochondrial genome of the entomophagous endoparasite Xenosvesparum (Insecta: Strepsiptera)  

Energy Technology Data Exchange (ETDEWEB)

In this study, the nearly complete sequence (14,519 bp) of the mitochondrial DNA (mtDNA) of the entomophagous endoparasite Xenos vesparum (Insecta: Strepsiptera) is described. All protein coding genes (PCGs) are in the arrangement known to be ancestral for insects, but three tRNA genes (trnA, trnS(gcu), and trnL(uag)) have transposed to derived positions and there are three tandem copies of trnH, each of which is potentially functional. All of these rearrangements except for that of trnL(uag) is within the short span between nad3 and nad4 and there are numerous blocks of unassignable sequence in this region, perhaps as remnants of larger scale predisposing rearrangements. X. vesparum mtDNA nucleotide composition is strongly biased toward As and Ts, as is typical for insect mtDNAs. There is also significant strand skew in the distribution of these nucleotides, with the J-strand being richer in A than T and in C than G, and the N-strand showing an opposite skew for ...

2005-12-01

377

Technical review, Vol. 29, No. 3, Ser. No. 85, October 1992  

Energy Technology Data Exchange (ETDEWEB)

Contents: expansion of pc mill application to plate mill and tandem cold mill; application of cluster type rolling mill (cr mill) for rolling of special steel (illustration); development of on-line roll grinding system with profile meter; development of new type jet pickling; new technology in continuous annealing furnace (illustration); anti-seismic testing system by 3-dimensional shaking table; development of mitsubishi hybrid desulfurization system; field performance of 500 mw advanced coal fired supercritical pressure operation boiler for unit no. 1 of tsuruga thermal power station, hokuriku electric power co., inc.; development of electronically controlled cylinder liner lubrication system for marine diesel engines; prediction technology on steady-state and transient performance of multi-air conditioners; a knowledge-based system approach to the autonomous piloting and navigation control of ships.

1992-01-01

378

Suppressive effects of cadmium on neurons and affected proteins in cultured developing cortical cells  

International Nuclear Information System (INIS)

The purpose of the present study was to examine the in vitro effects of low-dose cadmium (Cd) on developing cortical cells. The cortical cells removed from fetuses (embryonic day 15) were treated with 10 nM of Cd for 24 h. The effects of Cd on dendritic and synaptic development were immunocytochemically observed with anti-microtubule associated protein-2 (MAP2) and anti-synapsin I antibodies, respectively. Administration of Cd suppressed dendritic as well as synaptic development at 10 nM. By two-dimensional gel electrophoresis and liquid chromatography-tandem mass spectrometric (LC/MS/MS) analysis, we identified three proteins with different expression after Cd-treatment; dihydropyrimidinase-related protein 2 (DRP-2/CRMP-2), 14-3-3-epsillon and calmodulin (CaM). Though the number of identified proteins was small, these proteins are known to be involved in neuronal development. The present study demonstrated the morphological effects as well as affected proteins in ...

2008-11-20

379

Site characterization and petroleum hydrocarbon plume mapping  

Energy Technology Data Exchange (ETDEWEB)

This paper presents a case study of site characterization and hydrocarbon contamination plume mapping/delineation in a gas processing plant in southern Mexico. The paper describes innovative and cost-effective use of passive (non-intrusive) and active (intrusive) techniques, including the use of compound-specific analytical methods for site characterization. The techniques used, on a demonstrative basis, include geophysical, geochemical, and borehole drilling. Geochemical techniques used to delineate the horizontal extent of hydrocarbon contamination at the site include soil gas surveys. The borehole drilling technique used to assess the vertical extent of contamination and confirm geophysical and geochemical data combines conventional hollow-stem auguring with direct push-probe using Geoprobe. Compound-specific analytical methods, such as hydrocarbon fingerprinting and a modified method for gasoline range organics, demonstrate the inherent merit and need for such analyses to properly ...

1996-12-31

380

Radiation-induced mutations at mouse hemoglobin loci  

International Nuclear Information System (INIS)

In experiments designed to detect new mutations affecting hemoglobin, we irradiated the male or female parent in reciprocal crosses of two mouse strains that differ in alleles at the hemoglobin (Hba, Hbb) loci as well as at five other specific loci. Offspring were analyzed for hemoglobin properties (electrophoretic pattern, solubility, crystal pattern), serum albumin differences, erythrocyte lysis, reticulocyte count, and external appearance. Five hemoglobin variants were found among the mutants. In three, the genetic contribution from the irradiated father was not expressed with regard to the #alpha#-chain; one carried a tandem duplication (the first known case in the mouse) involving Hbb; and one probably resulted from double nondisjunction of chromosome 7. The finding that major chromosome aberratios can mimic hemoglobin mutations indicates the need, in similar experiments, to follow F_1 screening with thorough cytogenetic analysis. The variants in which there ...

381

Quantitation of acyl migration during lipase-catalyzed acidolysis, and of the regioisomers of structured triacylglycerols formed  

DEFF Research Database (Denmark)

Various MLM-type (M, medium-chain fatty acids; L, long-chain fatty acids) structured triacylglycerols were produced in pilot- or small-scale packed-bed reactors by lipase-catalyzed acidolysis. The incorporation and acyl migration of octanoic acid were measured by gas chromatography and Grignard degradation, and ranged from 39.0 to 48.7% and 0.6 to 9.3%, respectively. Quantitation of triacylglycerol molecular species was performed by ammonia negative ion chemical ionization (NICI) mass spectrometry (MS). The proportion of ACN (acyl carbon number) 34 species that contained one C-18 fatty acid and two C-8:0, in samples analyzed, varied from 12.5 to 23.2%. The selected regioisomers MLM and MML within the ACN 34 species group were quantified by NICI tandem MS (MS/MS) and were in the range of 97.1 to 98.4% and 1.6 to 2.9%, respectively. There was no correlation between the level of acyl migration during lipase-catalyzed esterification and the level of regioisomers of the ...

2001-01-01

382

Power system stabilizer application in a two unit plant analytical studies and field tests  

Energy Technology Data Exchange (ETDEWEB)

The use of excitation system controls, specifically the Power System Stabilizer (PSS), to improve damping of power system oscillations and thus extend steady-state stability limits has been a subject of great interest in recent years. The desire to more fully utilize transmission capacity led to the installation of PSS controls on greater numbers of generating units to maintain stability margins. This paper addresses the tuning and adjustment of PSS controls in a two unit power plant. Both analytical studies and field test confirmations are presented. The practical difficulties of verifying the PSS control loop gain margin by testing are explored. A simplified procedure is outlined. The Lower Colorado River Authority (LCRA), Fayette Power Project (FPP) consists of two 683.7 MVA tandem compound steam turbine driven generators. The excitation systems are of the alternator rectifier type and the PSS control utilizes shaft speed as an input signal. The units must ...

1983-02-01

383

Micro-strip metal foil detectors for the beam profile monitoring  

Energy Technology Data Exchange (ETDEWEB)

The Micro-strip Metal Foil Detectors (MMFD) designed and used for the Beam Profile Monitoring (BPM) are discussed. The results obtained for the MMFDs produced by different technologies are presented. The MMFD deposited onto the 20 {mu}m thick Si-wafer has been used for the BPM of the 32 MeV alpha-particle beam at the MPIfK (Heidelberg) Tandem generator. Another MMFD with totally removed Si-wafer at the working area has been applied for the on-line X-ray BPM at the HASYLAB (DESY). One may conclude that the developed technology of the micro-strip metal detector manufacturing allows to provide non-destructive measurement of X-ray intensity distribution over area of up to 50 mm{sup 2} with an accuracy of 10-20 {mu}m with a possibility of its improvement by a factor 5. A sub-micron position resolution is expected by applying electron lithography for the strip pattern production.

2005-07-01

384

Latest trends in rolling mill facilities toward the 21st century; 21 seiki ni muketa saishin atsuen setsubi no doko  

Energy Technology Data Exchange (ETDEWEB)

Described herein are the latest trends in rolling mill facilities toward the 21st. century and new techniques developed by Hitachi Ltd. These cover hot rolling facilities, such as two-stage twin, high crown control-roll cross mill, roll shaping machine and continuous hot rolling systems; cold rolling facilities, such as pickling line-tandem cold mill and other continuous systems; and fine steel rolling facilities, such as roll mill for very small diameter pipes and others to improve productivity and product quality. The other new techniques include systems to pursue reliability and maintainability, in which electric appliances, instruments and computers are integrated, or equipped with built-in large-capacity inverters and drivers. For hot rolling, the above techniques lead to development of a new system named Hi-HOT, which produces high-quality hot coils at a sufficient speed, while keeping rolled steel at a desired temperature. 1 ref., 3 figs.

1996-06-01

385

Intense negative-ion beams extracted from an ECR ion source coupled to a charge exchange canal  

Energy Technology Data Exchange (ETDEWEB)

Electron cyclotron resonance (ECR) ion sources possess several advantages over ion sources conventionally used for injectors of electrostatic accelerators: improved reliability, high efficiency, simplicity, and the capability of generating bright, high-current ion beams. We have adapted a high-current ECR source originally developed as an injector for a CW RFQ proton linac to serve as a source of intense negative-ion beams for the Tandem Accelerator Superconducting Cyclotron (TASCC) facility at Chalk River. The range of ion species of the source has been extended from H{sup 1+} alone up to Bi{sup 1+}, with both gaseous and nonvolatile feeds. Two intense negative-ion beams of He{sup -} and O{sup -} have been generated so far with the source coupled to a standard charge-exchange canal. We foresee no major problems generating a broad range of negative ions with this system. (author)

1993-07-01

386

Intense negative-ion beams extracted from an ECR ion source coupled to a charge exchange canal  

International Nuclear Information System (INIS)

Electron cyclotron resonance (ECR) ion sources possess several advantages over ion sources conventionally used for injectors of electrostatic accelerators: improved reliability, high efficiency, simplicity, and the capability of generating bright, high-current ion beams. We have adapted a high-current ECR source originally developed as an injector for a CW RFQ proton linac to serve as a source of intense negative-ion beams for the Tandem Accelerator Superconducting Cyclotron (TASCC) facility at Chalk River. The range of ion species of the source has been extended from H1+ alone up to Bi1+, with both gaseous and nonvolatile feeds. Two intense negative-ion beams of He- and O- have been generated so far with the source coupled to a standard charge-exchange canal. We foresee no major problems generating a broad range of negative ions with this system. (author)

1993-09-22

387

Influence of fly ash on soil physical properties and turfgrass establishment  

Energy Technology Data Exchange (ETDEWEB)

A field study (1993-96) assessed the benefits of applying unusually high rates of coal fly ash from power plants as a soil amendment to enhance water retention of soils without adversely affecting growth and marketability of the turf species, centipedegrass (Eremochloa ophiuroides (Munro) Hack.) A Latin Square plot design was employed that included 0 (control, no fly ash applied), 280, 560 and 1120 MgHa {sup -1} application rates of unweathered precipitator fly ash. The fly ash was spread evenly over each plot area, rototilled, and allowed to weather under natural conditions for 8 months before seeding. High levels of soluble salts, indicated by the electrical conductivity of soil extracts, in tandem with an apparent phytotoxic effect from boron, apparently inhibited initial plant establishment as shown by substantially lower germination counts in treated soil. However, plant height and rooting depth were not adversely affected, as were the dry matter yields ...

2001-04-01

388

INTRINSIC DOSIMETRY: A POTENTIAL NEW TOOL FOR NUCLEAR FORENSICS INVESTIGATIONS  

International Nuclear Information System (INIS)

Thermoluminescence (TL) dosimetry was used to measure dose effects on the raw stock material of borosilicate container glass from different geographical locations. Effects were studied at times up to 60 days post-irradiation at doses from 0.15 to 20 Gy. The minimum detectable dose using this technique was estimated to be 0.15 Gy which is roughly equivalent to a 24 hr irradiation 1 cm from a 50 ng source of 60Co. Two peaks were identified in the TL glow curve, a relatively unstable peak around 125 C and a more stable peak around 225 C. Differences in TL glow curve shape and intensity were also observed for the glasses from different geographical origins. We investigate radiation induced defects in glass to further develop the technique of intrinsic dosimetry - the measurement of the total absorbed dose received by the walls of a container holding radioactive material. Intrinsic dosimetry is intended to be used as an interrogation tool to provide enhanced pathway information on ...

2010-07-11

389

High-accuracy gauge control technologies over the full length and full width of cold rolled strip; Reikan tandemumiru ni okeru zencho{center_dot}zenpuku hanko seigyo gijutsu  

Energy Technology Data Exchange (ETDEWEB)

At tandem cold rolling mills in Kawasaki Steel, by means of applying newly developed strip longitudinal (rolling) and transverse gauge control systems, high accuracy of thickness of within {+-}0.5 % has been achieved over the full length and full width of cold rolled strip, as gauge accuracy in a coil in longitudinal and transverse directions has become an extremely important quality control item in the manufacturing of cold rolled sheets due to the stricter quality requirements of customers, in recent years. The longitudinal gauge accuracy has been improved by the development of a high-response drive system for a mill mair motor, an all-stands gauge control system and a dynamic set-up control system. The transverse gauge accuracy has been improved by applying a one-side tapered work roll shifting method and the development of an edge drop control system in terms of the optimum use of an edge drop sensor. (author)

1999-12-01

390

Hemoglobin of mice with radiation-induced mutations at the hemoglobin loci  

International Nuclear Information System (INIS)

Chemical analyses were done on the abnormal hemoglobins of the five (101 x SEC)F_1 offspring of X- irradiated adult SEC mice to determine which hemoglobin genes were expressed in each hemoglobin variant. Three offspring of irradiated SEC males did not express either of the two kinds of #alpha#-chains normally found in all SEC mice. The deficient #alpha#-chain synthesis caused these mice to exhibit an #alpha#-thalassemia similar to human #alpha#-thalassemia. Scanning electron microscopy was used to show that many erythrocytes of mice with #alpha#-thalassemia have bizarre shapes; e.g. many erythrocytes appeared flattened or had thorny projections (acanthocytes). One mutant with a tandem duplication of a segment of chromosome 7 (site of locus determining #beta#-chain structure) produced twice as much SEC as 101 #beta#-chain polypeptides. One mutant that probably arose by non-disjunction of chromosome 7's in its unirradiated 101 mother and loss of chromosome 7 from the ...

391

Edge-drop control of hot and cold rolled strip by tapered-crown work roll shifting mill. Kata taper tsuki work roll shifting mill ni yoru hakkoban no edge-drop seigyo tokusei  

Energy Technology Data Exchange (ETDEWEB)

Together with an investigation on the deformation behavior of hot and cold rolled strip edge, the edge-drop control was explained in characteristics and result of application to the commercial mill by the tapered-crown work roll (WR) shifting mill. From a cold rolling experiment, three-dimensional material flow was known to be generated in the vicinity of edge also at the time of rolling the strip, and which generation influences that of edge-drop. Almost linearly relative to the flattened deformation of WR, the edge-drop enlarges with enlargement in that deformation. The number of stands to be applied to the tapered-crown WR shifting mill in the tandem cold mill is determined by the location as far as which the strip is to be controlled in edge-drop. In case of improving it to obtain the edge-drop-free strip, all the stands are required to be equipped with tapered-crown WR shifting mill. By applying a tapered-crown WR shifting mill to the latter stands for the hot ...

1992-01-01

392

Challenges in fabrication of 180deg magnet chamber  

International Nuclear Information System (INIS)

180 deg magnet chamber is used in Folded Tandem Ion Accelerator for passage and 180 deg bending of ion beam. The chamber is placed between 180 deg terminal magnet (Electro-magnet), which is used for bending, and analysing the beams. Magnet with a particular magnetic field strength bends ions of only specified mass energy product through a precise path. There is also a space limitation in the direction of magnetic field. Both of them require the magnet chamber to be of a close tolerance. Accuracy of center distance between inlet and outlet port of the magnet chamber has to be at par with the concentricity of high energy and low energy beam line. To achieve this we started the fabrication of magnet chamber by following two methods: a) Circular rolling and bending of rectangular tube for 180 deg sector of magnet chamber b) Machining 180 deg sector in two half and welding. By first method we could not achieve the desired result although the method is very promising. ...

2006-11-01

393

Analysis of the requirements for economic magnetic fusion  

Energy Technology Data Exchange (ETDEWEB)

A generic reactor model is used to examine the economic viability of electricity generation by magnetic fusion. The simple model uses components which are representative of those used in previous reactor studies of deuterium-tritium burning tokamaks, stellarators, bumpy tori, reverse field pinches and tandem mirrors. Conservative costing assumptions are made. The generic reactor is not a tokamak but rather it is intended to emphasize what is common to all magnetic fusion reactors. The reactor uses a superconducting toroidal coil set to produce the dominant magnetic field. To this extent it is a less good approximation to systems, such as the reversed field pinch in which the main field is produced by a plasma current. The main output of the study is the cost of electricity as a function of the weight and size of the fusion core - blanket, shield, structure and coils. The model shows that a 1200 MW/sub e/ power plant with a fusion core weight of about 10,000 tonnes ...

1986-01-01

394

Analysis of pesticides in dried hops by liquid chromatography-tandem mass spectrometry.  

Science.gov (United States)

An analytical method was developed for the determination of eleven agrochemicals [abamectin (as B1a), bifenazate, bifenthrin, carfentrazone-ethyl, cymoxanil, hexythiazox, imidacloprid, mefenoxam, pymetrozine, quinoxyfen, and trifloxystrobin] in dried hops. The method utilized polymeric and NH2 solid phase extraction (SPE) column cleanups and liquid chromatography with mass spectrometry (LC-MS/MS). Method validation and concurrent recoveries from untreated dried hops ranged from 71 to 126% for all compounds over three levels of fortification (0.10, 1.0, and 10.0 ppm). Commercially grown hop samples collected from several field sites had detectable residues of bifenazate, bifenthrin, hexythiazox, and quinoxyfen. The control sample used was free of contamination below the 0.050 ppm level for all agrochemicals of interest. The limit of quantitation and limit of detection for all compounds were 0.10 and 0.050 ppm, respectively. PMID:18593182

2008-07-02

395

Al[sub 0. 3]Ga[sub 0. 7]As/GaAs heterojunction tunnel diode for tandem solar cell applications  

Energy Technology Data Exchange (ETDEWEB)

A p[sup +]-Al[sub 0.3]Ga[sub 0.7]As/n[sup +]-GaAs heterojunction tunnel diode was fabricated using Atomic Layer Epitaxy (ALE) growth technique. Background carbon doping of [similar to]10[sup 20] cm[sup [minus]3] was achieved in the p-side of the diode by optimizing growth conditions such as V/III ratio, exposure times to reactant gases, and growth temperature. In the n-side of the diode GaAs was doped with silane and doping concentrations as high as 7[times]10[sup 18] cm[sup [minus]3] were also achieved. The dopants are chosen to satisfy the high levels and low diffusion requirements. The diode can be used to interconnect the high and low band-gap cells in the AlGaAs/GaAs cascade solar cell structure. The reactor used in this investigation is a commercial MOCVD system which has been specially modified for dual operation of ALE and MOCVD growth modes.

1994-06-30

396

Affinity purification of sequence-specific DNA binding proteins.  

Science.gov (United States)

We describe a method for affinity purification of sequence-specific DNA binding proteins that is fast and effective. Complementary chemically synthesized oligodeoxynucleotides that contain a recognition site for a sequence-specific DNA binding protein are annealed and ligated to give oligomers. This DNA is then covalently coupled to Sepharose CL-2B with cyanogen bromide to yield the affinity resin. A partially purified protein fraction is combined with competitor DNA and subsequently passed through the DNA-Sepharose resin. The desired sequence-specific DNA binding protein is purified because it preferentially binds to the recognition sites in the affinity resin rather than to the nonspecific competitor DNA in solution. For example, a protein fraction that is enriched for transcription factor Sp1 can be further purified 500- to 1000-fold by two sequential affinity chromatography steps to give Sp1 of an estimated 90% homogeneity with 30% yield. In addition, the use of ...

1986-08-01

397

Accumulation levels and characteristics of some pesticides in human adipose tissue samples from Southeast China  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a comprehensive study of pesticide levels and bio-accumulation characteristics in human adipose tissues among residents of Southeast China. A large number of adipose samples (n=633) were selected for 58 pesticides and were analyzed by high sensitive Gas Chromatography-Tandem Mass Spectrometry (GC-MS/MS). The results showed that POPs pesticides were frequently detected, including 2,4prime-DDD, 2,4prime-DDE, 2,4prime-DDT, 4,4prime-DDD, 4,4prime-DDE, 4,4prime-DDT, a-HCH, b-HCH, g-HCH, d-HCH, hexachlorobenzene (HCB), and mirex. Other detected pesticide species were dicofol, methamidophos and chlordimeform, which have rarely been reported. Comparing to different countries, the concentrations of total DDT and HCH in these three Chinese southeastern sites were in the middle ra...

2011-01-01

398

Mechanics and mechanisms of cyclic fatigue-crack propagation in transformation-toughened zirconia ceramics  

Energy Technology Data Exchange (ETDEWEB)

Damage and cyclic fatigue failure under alternating loading in transformation-toughened zirconia ceramics is reviewed and compared to corresponding behavior under quasi-static loading (static fatigue). Current understanding of the role of transformation toughening in influencing cyclic fatigue-crack propagation behavior is examined based on studies which altered the extent of the tetragonal-to-monoclinic phase transformation in MG-PSZ through subeutectoid aging. These studies suggest that near-tip computations of the crack-driving force (in terms of the local stress intensity) can be used to predict crack-growth behavior under constant amplitude and variable-amplitude (spectrum) loading, using spatially resolved Raman spectroscopy to measure the extent of the transformation zones. In addition, results are reviewed which rationalize distinctions between the crack-growth behavior of preexisting, ...

1992-05-01

399

Evidence of network demixing in GeS2-Ga2S3 chalcogenide glasses: A phase transformation study  

International Nuclear Information System (INIS)

The information of phase transformation is attained by in situ XRD experiments leading to the knowledge of topological threshold in GeS2-Ga2S3 glasses. The turning point of phase transformation behavior is demonstrated to be glasses containing 14-15 mol% Ga2S3. To interpret it a network demixing model is further improved and proposed for the structure of these ternary or quasi-binary chalcogenide glasses. For the nearest-neighbor coordination environment of glass with a transitional composition of 85.7 mol% (6/7) GeS2.14.3 mol% (1/7) Ga2S3, six-coordinated [S3Ga-X-GaS3] units (X=S or None) are well isolated by the [GeS4] structures, which contributes to the decreasing of precipitation of Ga2S3 crystals in (100-x)GeS2-xGa2S3 (x?14.3) glasses corresponding to the experimental evidence of the phase transformation behavior. This scenario of intermediate-range structural order, firstly, includes the arrangement of structural ...

2011-03-01

400

Photoelectrochemical Water Splitting for Hydrogen Production Using Multiple Bandgap Combination of Thin-Film-Photovoltaic and Photocatalyst  

Science.gov (United States)

One of the NASA research activities was to identify, characterize, and simulate a series of technologies that could be used for hydrogen production at NASA Kennedy Space Center (KSC) using locally available sources. This project examined the production of hydrogen from solar energy. To produce hydrogen by water splitting, the operating voltage of conventional photovoltaic (PV) cells cannot supply the overvoltage required. Thus, the objective of this project was to research and develop photoelectrochemical (PEC) cells that can supply the required voltage for water splitting by constructing a multiple bandgap tandem PV cell and a photocatalyst that can be activated by infrared (IR) photons transmitted through the PV cell. The proposed concept is different from conventional PEC water splitting by using multiple band gap combinations. The advantages for this PEC cell concept is that the PV cells are not in contact with the electrolyte solution, thus reducing the ...

2009-01-01

401

Transformation kinetics and microstructures of Ti17 titanium alloy during continuous cooling  

International Nuclear Information System (INIS)

We have investigated the microstructure evolutions in the Ti17 near #beta# titanium alloy during heat treatments. The phase transformation has first been studied experimentally by combining X-ray diffraction analysis, electrical resistivity and microscopy observations. From a series of isothermal treatments, a IT diagram has been determined, which takes into account the different morphologies. Then, a Johnson-Mehl-Avrami-Kolmogorov (JMAK) model has been successfully used to describe the phase transformation kinetics during either isothermal or cooling treatments. Finally, the coupling of the JMAK model to the finite element software ZeBuLoN allowed us to investigate the evolution of the spatial distribution of the different morphologies during the cooling of an aircraft engine shaft disk after forging.

2007-03-15

402

SASE: Complex Event Processing over Streams  

CERN Document Server

RFID technology is gaining adoption on an increasing scale for tracking and monitoring purposes. Wide deployments of RFID devices will soon generate an unprecedented volume of data. Emerging applications require the RFID data to be filtered and correlated for complex pattern detection and transformed to events that provide meaningful, actionable information to end applications. In this work, we design and develop SASE, a com-plex event processing system that performs such data-information transformation over real-time streams. We design a complex event language for specifying application logic for such transformation, devise new query processing techniques to effi-ciently implement the language, and develop a comprehensive system that collects, cleans, and processes RFID data for deliv-ery of relevant, timely information as well as storing necessary data for future querying. We demonstrate an initial prototype of SASE ...

2006-01-01

403

Resonant overvoltage phenomena caused by transmission line faults  

Energy Technology Data Exchange (ETDEWEB)

Resonant overvoltages in EHV transformers can be initiated by transmission line faults. A series of field tests were performed on the 151 mile long Kammer-Marysville 765 kV line in which a sequence of single line to ground faults were applied to one outside phase at 4 different locations. Fault location criteria and fault initiation procedures are presented. Oscillograms recorded the 3 phase response at both terminals of the line; one is transformer terminated, the other is open-ended. A frequency spectrum analysis of the waveforms is provided showing transient frequencies of sufficient magnitude and duration near the EHV transformer's resonant frequency to stimulate internal winding resonant overvoltages. Digital computer studies are presented and agree with the field tests quite favorably.

1985-09-01

404

On the electrodynamics of tachyons  

International Nuclear Information System (INIS)

Electrodynamic properties of processes involving charged tachyons are considered in connection with the real superluminal Lorentz transformations. These transformations are interpreted without making use of a tachon corridor and so that the interaction of tachyons from subluminal sources with ordinary matter is Lorentz invariant. Transformations of the electromagnetic fields are deduced from the extended principle of relativity. They are necessary in order to obtain the field equations that are satisfied by fields obeying Maxwell equations relative to superluminal inertial frames with respect to subluminal inertial frames. The field equations allow one to get the dependence of the field energy density and its current on the field strengths. The resulting equations are applied in a discussion of plane electromegnetic waves, sent out by a superluminal source. The obtained electrodynamics allows the existence of charged tatric ...

405

Microstructural characterization of ZrO_2/O'-SiAlON composites  

International Nuclear Information System (INIS)

Zirconia has demonstrated a very moderate toughening effect in nitrogen-based ceramic composites because the reaction between tetragonal zirconia (t-ZrO_2) and nitrogen results in additional zirconia stabilization to a nontransformable t' or cubic structure. In O'-SiAlON matrices, the oxygen concentration increases and the oxygen-rich intergranular glassy phase prevents zirconia from nitridation. As a result, tetragonal ZrO_2 is maintained and is transformable in the O'-SiAlON materials. The present study has provided transmission electron microscopy (TEM) evidence of the zirconia transformation and the associated toughening effect in a ZrO_2/O'-SiAlON composite. The implications and limitations of the transformation on toughening of the material are discussed.

406

Herpesvirus saimiri infection of rhesus macaques: A model for acute rhadinovirus-induced t-cell transformation and oncogenesis  

British Library Electronic Table of Contents (United Kingdom)

Abstract Herpesvirus saimiri (HVS) causes acute lymphoma and leukemia upon experimental infection of various monkey species. HVS strain C488 is also capable of transforming human T-lymphocytes to stable growth in culture. The most susceptible species for oncogenesis are New World primates, in particular the cottontop tamarin (Saguinus oedipus). However, Old World monkeys such as macaques are the most used animal model for the close-to-human situation. The limited data on HVS infection in Old World monkeys prompted us to investigate susceptibility to infection and disease induction by HVS in macaques. After having established that rhesus macaques can be infected productively, and that rhesus T-cells can be transformed in vivo by HVS, we observed induction of lymphoma in all inoculated anima...

2011-01-01

407

Gear fault identification and classification of singular value decomposition based on Hilbert-Huang transform  

British Library Electronic Table of Contents (United Kingdom)

An improved singular value decomposition method of gear fault identification based on Hilbert-Huang transform was proposed to overcome the problem of reconstructing a feature matrix of singular value decomposition. The method includes three steps. First, the instantaneous frequency and amplitude matrices were acquired by Hilbert-Huang transform from faulted gear signals. Second, after the matrices were decomposed by singular value decomposition, the defined distances of singular value vectors and the optimal threshold of the distance for classification were calculated. Third, the fault characteristics of a gearbox were identified and classified by the threshold of the distances. The result demonstrates that the proposed method effectively identifies the gear fault and can realize an automa...

2011-01-01

408

Formation of AlN-polytypoid phases during #alpha#-SiAlON decomposition  

International Nuclear Information System (INIS)

Phase transformations from #alpha#- to #beta#-SiAlONs (i.e., from #alpha#' to #beta#') have been recently reported in a number of rare-earth SiAlON systems during postsintering heat treatment. In the present work, this transformation process in a Sm (#alpha# + #beta#)-SiAlON material is studied by using XRD, TEM, and EDS X-ray mapping techniques. It is observed that in addition to the formation of #beta#' and M' phases, the #alpha#'-to-#beta#' transformation is accompanied by a significant increase in the amount of an AlN-polytypoid phase. The results suggest that some #alpha#' phases are thermodynamically unstable at temperatures lower than the material sintering temperature and will decompose when conditions allow. For the composition studied in this work, the #alpha#-SiAlON decomposition can be described in general as #alpha#' #-># #beta#' + M' + AlN polytypoid.

409

Electron-phonon based local mode descriptions of displacive transformations  

Energy Technology Data Exchange (ETDEWEB)

As a general approach to the problem of precursive behavior in alloys that undergo a displacive transformation, defect theories are becoming increasingly popular. However, the microscopic origin of the proposed defects is usually not considered. Yu and Anderson (1984) have argued that properties of strong-coupling superconductors, such as the A-15 compounds, imply a breakdown of Migdal's theorem (the adiabatic, or Born-Oppenheimer approximation for separation of electrons and phonons) in these systems. The electron-phonon coupling is so strong that it must be incorporated already in zeroth order. This is the basis for local phonon models, in which the electron-phonon coupling provides an effective double well potential for a localized group of atoms. The Yu-Anderson model and an analogous local Jahn-Teller model (Abell, 1983) are reviewed in connection with displacive transformations in strong-coupling alloys.

1986-01-01

410

Effect of Si_3N_4 whisker and SiC platelet addition on phase transformation and mechanical properties of the #alpha#/#beta# sialon matrix composites  

International Nuclear Information System (INIS)

#alpha#/#beta# sialon based composites containing silicon nitride whisker and silicon carbide platelet were fabricated by hot pressing. Effect of the reinforcing agents on the #alpha# to #beta# phase transformation of the sialon as well as on the mechanical properties was investigated. Silicon nitride whisker and silicon carbide platelet promoted the phase transformation. TEM/EDS analysis revealed that the grain containing the whisker had 'core-rim' structure; core being high purity Si_3N_4 whisker and rim being #beta#-sialon. Flexural strength of the composite decreased with the reinforcement addition which, on the other hand, improved fracture toughness of it. High temperature strength was measured at 1300 deg C to be about 130 MPa lower than that measured at RT for the whisker reinforced composite. (author).

411

Control of quench distortion for steel parts  

Energy Technology Data Exchange (ETDEWEB)

There are two types in quench distortion of steel parts: thermal distortion and transformation distortion. Quench distortion is caused mainly by uneven cooling rate of steel parts from Austenitising temperature. The rapid cooled side is lengthened (convex deformation); the slow cooled side is shortened (concave deformation). So, to control the quench distortion, it is necessary to regulate the cooling rate of steel parts during quenching. TWO COMPONENTS produce the quench distortion of steel parts: the thermal stress and transformation stress. Generally, the effect of the thermal stress on the quench distortion is stronger than the transformation stress. The quench distortion is caused by uneven cooling rate of the steel parts, from Austenitising temperature to Ms point and Ms-Mf range. So, to control the quench distortion, it is very important to regulate the cooling rate of the steel parts during quenching. The purpose of ...

1996-12-31

412

Chemical transformations of organic matter during the composting of wood industry wastes (residues); Transformacoes quimicas da materia organica durante a compostagem de residuos da industria madeireira  

Energy Technology Data Exchange (ETDEWEB)

Composting of sawdust and paper mill sludge, using a 'Kneer' process reactor, was studied in an attempt to elaborate upon organic matter transformation during the process and to define parameters to measure the compost maturity level. Temperature, electron paramagnetic resonance data, ash and C, H, N and S contents, and a spectroscopic method using ultraviolet-visible (UV-VIS) for alkaline (pH = 8.5) and solid samples was used to study the maturity of the compost samples. These parameters were measured in 6 humic acids extracted from the compost samples during 29 days. The results of this work show that the 'Kneer' process is efficient in transforming ligno-celulitic residues in a short time (29 days), into an organic fertilizer material with application perspectives (author)

2004-06-01

413

Cell-mediated mutagenesis and cell transformation of mammalian cells by chemical carcinogens. [Rats, hamsters  

Science.gov (United States)

We have developed a cell-mediated mutagenesis assay in which cells with the appropriate markers for mutagenesis are co-cultivated with either lethally irradiated rodent embryonic cells that can metabolize carcinogenic hydrocarbons or with primary rat liver cells that can metabolize chemicals carcinogenic to the liver. During co-cultivation, the reactive metabolites of the procarcinogen appear to be transmitted to the mutable cells and induce mutations in them. Assays of this type make it possible to demonstrate a relationship between carcinogenic potency of the chemicals and their ability to induce mutations in mammalian cells. In addition, by simultaneously comparing the frequencies of transformation and mutation induced in normal diploid hamster cells by benzo(a)pyrene (BP) and one of its metabolites, it is possible to estimate the genetic target size for cell transformation in vitro.

1977-01-01

414

Assessment of periodic sub-diurnal Earth rotation variations at tidal frequencies through transformation of VLBI normal equation systems  

British Library Electronic Table of Contents (United Kingdom)

We present an empirical model for periodic variations of diurnal and sub-diurnal Earth rotation parameters (ERPs) that was derived based on the transformation of normal equation (NEQ) systems of Very Long Baseline Interferometry (VLBI) observing sessions. NEQ systems that contain highly resolved polar motion and UT1-TAI with a temporal resolution of 15?min were generated and then transformed to the coefficients of the tidal ERP model to be solved for. To investigate the quality of this model, comparisons with empirical models from the Global Positioning System (GPS), another VLBI model and the model adopted by the conventions of the International Earth Rotation and Reference Systems Service (IERS) were performed. The absolute coefficients of these models agree almost completely within 7.5?...

2011-01-01

415

3-D depth migration via McClellan transformations  

Energy Technology Data Exchange (ETDEWEB)

Three-dimensional seismic wavefields may be extrapolated in depth, one frequency at a time, by two-dimensional convolution with a circularly symmetric, frequency- and velocity-dependent filter. This depth extrapolation, performed for each frequency independently, lies at the heart of 3-D finite-difference depth migration. The computational efficiency of 3-D depth migration depends directly on the efficiency of this depth extrapolation. McClellan transformations provide an efficient method for both designing and implementing two-dimensional digital filters that have a particular form of symmetry, such as the circularly symmetric depth extrapolation filters used in 3-D depth migration. Given the coefficients of one-dimensional, frequency- and velocity-dependent filters used to accomplish 2-D depth migration, McClellan transformations lead to a simple and efficient algorithm for 3-D depth migration. 21 refs., 12 figs.

1990-01-01

416

Z-relation and homometry in musical distributions  

British Library Electronic Table of Contents (United Kingdom)

This paper defines homometry in the rather general case of locally-compact topological groups, and proposes new cases of its musical use. For several decades, homometry has raised interest in computational musicology and especially set-theoretical methods, and in an independent way and with different vocabulary in crystallography and other scientific areas. The link between these two approaches was only made recently, suggesting new interesting musical applications and opening new theoretical problems. We present some old and new results on homometry, and give perspective on future research assisted by computational methods. We assume from the reader's basic knowledge of groups, topological groups, group algebras, group actions, Lebesgue integration, convolution products, and Fourier trans...

2011-01-01

417

Theory of edge radiation  

CERN Document Server

We formulate a complete theory of Edge Radiation based on a novel method relying on Fourier Optics techniques. Similar types of radiation like Transition Undulator Radiation are addressed in the framework of the same formalism. Special attention is payed in discussing the validity of approximations upon which the theory is built. Our study makes consistent use of both similarity techniques and comparisons with numerical results from simulation. We discuss both near and far zone. Physical understanding of many asymptotes is discussed. Based on the solution of the field equation with a tensor Green's function technique, we also discuss an analytical model to describe the presence of a vacuum chamber. In particular, explicit calculations for a circular vacuum chamber are reported. Finally, we consider the use of Edge Radiation as a tool for electron beam diagnostics. We discuss Coherent Edge Radiation, Extraction of Edge Radiation by a mirror, and other issues ...

2008-01-01

418

Spectral Analysis of Radial Dirac Operators in the Kerr-Newman Metric and its Applications to Time-periodic Solutions  

CERN Document Server

We investigate the existence of time-periodic solutions of the Dirac equation in the Kerr-Newman background metric. To this end, the solutions are expanded in a Fourier series with respect to the time variable $t$ and the Chandrasekhar separation ansatz is applied so that the question of existence of a time-periodic solution is reduced to the solvability of a certain coupled system of ordinary differential equations. First, we prove the already known result that there are no time-periodic solutions in the non-extreme case. Then it is shown that in the extreme case for fixed black hole data there is a sequence of particle masses $(m_N)_{N\\in\\mathbb N}$ for which a time-periodic solution of the Dirac equation does exist. The period of the solution depends only on the data of the black hole described by the Kerr-Newman metric.

2006-01-01

419

Simulation Studies of the X-Ray Free-Electron Laser Oscillator  

Energy Technology Data Exchange (ETDEWEB)

Simulations of the x-ray free-electron laser (FEL) oscillator are presented that include transverse effects and realistic Bragg crystal properties with the two-dimensional code GINGER. In the present cases considered the radiation divergence is much narrower than the crystal acceptance, and the numerical algorithm can be simplified by ignoring the finite angular bandwidth of the crystal. In this regime GINGER shows that the saturated x-ray pulses have 109 photons and are nearly Fourier-limited with peak powers in excess of 1 MW. Wealso include preliminary results for a four-mirror cavity that can be tuned in wavelength over a few percent, with future plans to incorporate the full transverse response of the Bragg crystals into GINGER to more accurately model this tunable source.

2009-08-14

420

Propagation of pressure perturbations in bubbly air/water flows  

Energy Technology Data Exchange (ETDEWEB)

The propagation of acoustic pressure perturbations in an adiabatic low-quality air/water flow were investigated both theoretically and experimentally. A linearized dispersion model is correlated with data to extract information on the behavior of interfacial momentum transfer controlled by the virtual volume coefficient. The dispersion model is examined in limiting cases of low and high frequency and related to current models for critical flow velocity. Fourier decomposition techniques are employed to predict the dispersion of measured pressure pulses and to relate data for standing waves and propagating pulses. The dispersion model is based on a two-fluid model and is the most complete model available in the literature at this time. The dispersion data presented herein is also the best available to date for low frequency (i.e., frequencies less than bubble resonance) sound propagation in bubbly air/water mixtures.

1987-01-01

421

Prediction of thermal conductivity of ethylene glycol-water solutions by using artificial neural networks  

British Library Electronic Table of Contents (United Kingdom)

The objective of this study is to develop an artificial neural network (ANN) model to predict the thermal conductivity of ethylene glycol-water solutions based on experimentally measured variables. The thermal conductivity of solutions at different concentrations and various temperatures was measured using the cylindrical cell method that physical properties of the solution are being determined fills the annular space between two concentric cylinders. During the experiment, heat flows in the radial direction outwards through the test liquid filled in the annual gap to cooling water. In the steady state, conduction inside the cell was described by the Fourier equation in cylindrical coordinates, with boundary conditions corresponding to heat transfer between the solution and cooling water. ...

2009-01-01

422

Photoreceptor Inner and Outer Segment Defects in Myopic Foveoschisis  

British Library Electronic Table of Contents (United Kingdom)

PurposeTo evaluate pathologic features of the photoreceptors in myopic foveoschisis with the Fourier-domain optical coherence tomography (FD-OCT).DesignObservational case series.MethodsSeventeen eyes of 15 patients with myopic foveoschisis (foveal detachment type, six eyes; foveoschisis type, 11 eyes) were included. We observed the photoreceptor inner and outer segments (IS/OS) and evaluated the morphologic status using FD-OCT. Fundus photographs and time-domain OCT (TD-OCT) images also were obtained.ResultsIS/OS defects, which are uncommon in retinal detachments in eyes with myopia, were seen clearly in five eyes (three eyes [50%] with the foveal detachment type; two eyes [18%] with the foveal schisis type). Fundus photographs showed myopic chorioretinal atrophy in eight study eyes (47%),...

2008-01-01

423

Microstructure analysis of nanocrystalline powders by X-ray diffraction  

International Nuclear Information System (INIS)

The use of X-ray diffraction line profile analysis for the study of nanocrystalline powders is described. The fundamentals of the theory are presented in terms of crystallite/domain size, size distribution, lattice distortion, dislocations density and stacking faults. Line profile parameters and the methods of pattern fitting introduced to overcome the diffraction-line overlap problem are discussed. The approaches based of the integral breadth of the measured line profiles and the Fourier method are discussed. In addition, simplified approaches are also commented. Representative examples are selected to illustrate various cases of microstructure, such as nanomaterials with strain-free spherical nano crystallites, strain-free crystallites with anisotropic crystallite shape, anisotropic crystallites with microstrains and spherical crystallites with dislocation densities and crystallite size distributions. (author)

2001-09-23

424

Evidence for a supermassive black hole in the nucleus of M31  

International Nuclear Information System (INIS)

Stellar rotation velocities and velocity dispersions along three slit positions in M31 have been measured, and three-dimensional velocity and velocity dispersion fields are obtained in order to search for a central black hole. Synthetic apparent spectra are constructed to eliminate problems with the reaction of the Fourier quotient program to stellar population mixes. Models are constructed to explore parameter space. The large velocities and velocity gradients that are found imply that the total mass-to-light ratio rises sharply at r of 0.5 arcsec or less to values greater than 100. This is much larger than normal for old stellar populations. Velocity anisotropies are not a major uncertainty because of the rapid rotation. There is thus strong evidence for a dark central mass, probably a supermassive black hole. 48 references.

425

Diffuse X-ray scattering study of sublattice ordering among group III atoms in In_0_._5Ga_0_._5P and In_0_._5Al_0_._5P  

International Nuclear Information System (INIS)

The intensity of superstructure reflections and associated diffuse scattering from In_0_._5Ga_0_._5P and In_0_._5Al_0_._5P epitaxic layers grown on (001) GaAs substrates was mapped in reciprocal space. The Warren-Cowley short-range-order parameters were obtained through the usual process for evaluating Fourier coefficients. Varying values for the correlation length in different directions indicate how group III atoms stack up in ordered states. The resultant structure with long-range order confirms the hypothesis made on the basis of electron diffraction and high-resolution transmission electron microscopy studies. (orig.).

426

A study of reconstruction algorithms and filters for an industrial X-ray tomography system  

Energy Technology Data Exchange (ETDEWEB)

Computed tomography (CT) has been incorporated in an industrial Diode-Array Digital Radiography (DADR) system. An input data size of 512 pixel points x 400 projections yielded a 400x400 output image matrix. Reconstruction algorithms used are the filtered backprojection (FBP) and the direct Fourier reconstruction (DFR). Various filters were used in the FBP reconstruction process and their effects on image quality were evaluated. A spatial resolution of 100 {mu}m was measured with a block of plates and a minimum detectable feature size in the range of 10-100 {mu}m was measured using thin wires. Industrial specimens imaged have included ceramic samples, ball bearings and integrated circuits. A number of engineering problems have been solved, such as adjustment of the X-ray source, centering of the rotator spindle in the view field and beam-hardening corrections. (orig.).

1990-12-20

427

A Laplacian approach to multi-oriented text detection in video.  

Science.gov (United States)

In this paper, we propose a method based on the Laplacian in the frequency domain for video text detection. Unlike many other approaches which assume that text is horizontally-oriented, our method is able to handle text of arbitrary orientation. The input image is first filtered with Fourier-Laplacian. K-means clustering is then used to identify candidate text regions based on the maximum difference. The skeleton of each connected component helps to separate the different text strings from each other. Finally, text string straightness and edge density are used for false positive elimination. Experimental results show that the proposed method is able to handle graphics text and scene text of both horizontal and nonhorizontal orientation. PMID:20733217

2011-02-01

428

Workshop on In Situ Biogeochemical Transformation of ...  

Science.gov (United States)

... feet wide. Tree mulch, cotton gin trash, river sand VC: 11,600 Sulfate: 1,500 to 2,000 mg/L Parsons, 2007b PCE: 3,400 ...

2008-02-01

429

Violation of the second law of black hole physics by tachyons  

Energy Technology Data Exchange (ETDEWEB)

It is shown that the interaction of a class of positive energy tachyons decreases the area of the horizon of the T-S, delta = 3 metric even in the case of a reversible transformation (Msub(ir) = constant). This is a violation of the second law of black hole physics.

1982-10-01

430

Violation of the second law of black hole physics by tachyons  

International Nuclear Information System (INIS)

It is shown that the interaction of a class of positive energy tachyons decreases the area of the horizon of the T-S, delta = 3 metric even in the case of a reversible transformation (Msub(ir) = constant). This is a violation of the second law of black hole physics. (author).

431

Unified kinematics of bradyons and tachyons in six-dimensional space-time  

International Nuclear Information System (INIS)

An explicit form of the transformation matrix in sin-dimensional space-time is given both for subluminal and superluminal cases, and it is shown how a single formalism can be used for both bradyons and tachyons. (author).

432

Transforming growth factor-beta signaling in thoracic aortic aneurysm development: a paradox in pathogenesis  

UK PubMed Central (United Kingdom)

Thoracic aortic aneurysms (TAAs) are potentially devastating, and due to their asymptomatic behavior, pose a serious health risk characterized by the lack of medical treatment options and high...Full Text Available

2009-01-01

433

Transforming Growth Factor Beta One (TGF-?1) Enhancement of the Chondrocytic Phenotype in Aged Perichondrial Cells  

UK PubMed Central (United Kingdom)

BackgroundPerichondrium is recognized as a tissue with chondrogenic potential yielding cells which can be used for osteochondral repair. Factors which influence the proliferative...Full Text Available

2000-01-01

434

Transformation of human osteoblast cells to the tumorigenic phenotype by depleted uranium-uranyl chloride.  

UK PubMed Central (United Kingdom)

Depleted uranium (DU) is a dense heavy metal used primarily in military applications. Although the health effects of occupational uranium exposure are well known, limited data exist regarding the long-term...Full Text Available

1998-08-01

435

The protein encoded by the rolB plant oncogene hydrolyses indole glucosides.  

UK PubMed Central (United Kingdom)

The rolB gene of Agrobacterium rhizogenes, whose expression stimulates the formation of roots by transformed plant tissues and other growth alterations in transgenic plants, codes for a beta-glucosidase...Full Text Available

1991-11-01

436

The oncogenic transforming potential of the passage of single ? particles through mammalian cell nuclei  

UK PubMed Central (United Kingdom)

Domestic, low-level exposure to radon gas is considered a major environmental lung-cancer hazard involving DNA damage to bronchial cells by α particles from radon progeny. At domestic exposure...Full Text Available

1999-01-05

437

Targeting the p53 Pathway in Ewing Sarcoma  

UK PubMed Central (United Kingdom)

The p53 tumour suppressor plays a pivotal role in the prevention of oncogenic transformation. Cancers frequently evade the potent antitumour surveillance mechanisms of p53 through mutation of the TP53...Full Text Available

2011-01-01

438

Study of transformation behavior in a Ti-4.4 Ta-1.9 Nb alloy  

International Nuclear Information System (INIS)

An alloy of composition Ti-4.4 wt.% Ta-1.9 wt.% Nb is being developed as a structural material for corrosion applications, as titanium and its alloys possess excellent corrosion resistance in many oxidizing media. The primary physical metallurgy database for the Ti-4.4 wt.% Ta-1.9 wt.% Nb alloy is being presented for the first time. Determination of the #beta# transus, M_s temperature and classification of the alloy have been carried out, employing a variety of microscopy techniques, X-ray diffraction (XRD), micro-hardness and differential scanning calorimetry (DSC). The #beta# transition temperature or #beta# transus determined using different experimental techniques was found to agree very well with evaluations based on empirical calculations. Based on chemistry and observed room temperature microstructure, the alloy has been classified as an #alpha# + #beta# titanium alloy. The high temperature #beta# transforms to either #alpha#' or #alpha# + #beta# by a ...

2005-01-15

439

Shelterin complex and associated factors at human telomeres  

UK PubMed Central (United Kingdom)

The processes regulating telomere function have major impacts on fundamental issues in human cancer biology. First, active telomere maintenance is almost always required for full oncogenic transformation...Full Text Available

2011-03-01

440

Selection and characterization of ricin toxin A-chain mutations in Saccharomyces cerevisiae.  

UK PubMed Central (United Kingdom)

A DNA sequence encoding the A chain of ricin toxin (RTA) from the castor bean plant, Ricinus communis, was placed under GAL1 promoter control and transformed into Saccharomyces cerevisiae. Induction...Full Text Available

1989-02-01

441

Raiders of the Lost Bark: Orangutan Foraging Strategies in a Degraded Landscape  

UK PubMed Central (United Kingdom)

Deforestation is rapidly transforming primary forests across the tropics into human-dominated landscapes. Consequently, conservationists need to understand how different taxa respond and adapt to these...Full Text Available

442

Quaternionic formulation for electromagnetic-field equations  

Energy Technology Data Exchange (ETDEWEB)

The quaternionic formalism for subluminal field equations (Maxwell's equations) and its interrelationship with complex superluminal Lorentz transformations have been given and it has been shown that the quaternionic forms of relativistic equations describe tachyons.

1983-07-02

443

Perturbations of the Plebanski metric in general relativity. II. Perturbations of the fermion field.  

Science.gov (United States)

We obtain the radial Dirac equations for the Plebanski metric and transform these equations into one-dimensional wave equations. Finally we conclude with the result that the electron and the neutrino fields are not superradiant.

1986-09-01

444

Pathogenicity of molecularly cloned bovine leukemia virus.  

UK PubMed Central (United Kingdom)

To delineate the mechanisms of bovine leukemia virus (BLV) pathogenesis, four full-length BLV clones, 1, 8, 9, and 13, derived from the transformed cell line FLK-BLV and a clone construct, pBLV913,...Full Text Available

1993-12-01

445

On the sensitivity of IMRT dose optimization to the mathematical form of a biological imaging-based prescription function  

UK PubMed Central (United Kingdom)

Voxel-based prescriptions of deliberately non-uniform dose distributions based on molecular imaging, so-called dose painting or theragnostic radiation therapy, require specification of a transformation...Full Text Available

2009-03-21

446

Non-Abelian T-duality in pre-big-bang cosmology  

Energy Technology Data Exchange (ETDEWEB)

We study the impact of non-Abelian T-duality transformations on a string based cosmological model. The implementation of the pre-big-bang scenario is investigated. We found a region of the dual phase where such a picture is possible.

2003-02-17

447

Neoplastic transformation of prostatic and urogenital epithelium by the polyoma virus middle T gene.  

UK PubMed Central (United Kingdom)

Male transgenic mice expressing the polyomavirus middle T (PyV-MT) gene exhibited growth and developmental abnormalities in prostatic and other urogenital epithelium. Expression of PyV-MT was directed...Full Text Available

1996-10-01

448

Monitoring DC partial discharges with Nilsson Plate  

Energy Technology Data Exchange (ETDEWEB)

The Nilsson Plate High Frequency Adaptation of the Static Electrification Monitor developed by Electric Research and Management, Inc. for EPRI has demonstrated that the Nilsson Plate can be utilized as a practical high frequency antenna to record partial discharge activity within a transformer. Tests in the ABB factory at Muncie, IN on a 650 MVA, 345/20.9 kV, three-phase unit step-up transformer for TU Electric showed the Nilsson plate detecting partial discharge activity. Although this test was the first attempt at using the Nilsson plate in this manner, and in spite of higher than expected electrical noise levels, the data demonstrated that partial discharges can be detected. The tests also demonstrated that corona activity external to the transformer was not recorded by the plate. Some development work needs to be completed to eliminate the noise source from other monitors on the Static Electrification monitor, and to ...

1995-05-01

449

Microbial transformation of artificial estrogens of the allenolic group.  

UK PubMed Central (United Kingdom)

When 2,2-dimethyl 3-(2'-naphthyl 6'-hydroxy) pentanoic acid, an artificial estrogen of the allenolic acid group, was added to an exponential-phase growth culture of Neurospora crassa (in Horowitz medium),...Full Text Available

1975-06-01

450

Long-term synaptic transformation of hippocampal CA1 gamma-aminobutyric acid synapses and the effect of anandamide.  

UK PubMed Central (United Kingdom)

Evidence is presented for a distinctive type of hippocampal synaptic modification [previously described for a molluscan gamma-aminobutyric acid (GABA) synapse after paired pre- and postsynaptic excitation]:...Full Text Available

1995-10-24

451

Laboratory ageing of transformer oils  

Energy Technology Data Exchange (ETDEWEB)

The insulating oil used in a transformer is a critical component, as its service life is typically 20 years with possibly little or no maintenance. Partial discharges (PD), thermal overloads and static discharges continually subject the oil to chemical deterioration during its operating life. To ensure equipment reliability during service, it is important that the initial quality of the new insulating oil should meet the required acceptance specifications and preferably be pre-tested before use. Accelerated aging tests have been devised to determine the life expectancy of oil in service by using forced air or oxygen flow into the oil, the presence of a copper catalyst, and at elevated temperatures. The more important standards relating to transformer application are discussed and highlights of the more important aspects of the oxidation chemistry of hydrocarbons are included. The ultimate aim of the project is the formulation of better standard ...

1996-04-01

452

Isolation and characterization of quinoline-degrading bacteria from subsurface sediments.  

UK PubMed Central (United Kingdom)

Two gram-negative, motile bacteria isolated from deep subsurface sediments mineralized the nitrogen-containing polyaromatic hydrocarbon quinoline under aerobic conditions and transformed quinoline to...Full Text Available

1989-04-01

453

In Vivo Modulation of T-DNA Encoded Amidohydrolase Activity in Transformed Tobacco Cells 1  

UK PubMed Central (United Kingdom)

Auxin autonomous growth of most crown gall tumor cells requires the expression of two auxin biosynthesizing genes (tms 1 and tms 2) from the T-DNA of Agrobacterium...Full Text Available

1991-04-01

454

Hamiltonian BRST formalism for gauge-invariant systems with closed algebra  

International Nuclear Information System (INIS)

The systems for which the algebra of gauge transformations in the lagrangian formalism is closed, are considered. The hamiltonian BRST charge and the BRST-invariant hamiltonian are found explicitly. Their expansions in powers of the ghost variables contain, in general, an infinite number of terms. (orig.).

1991-11-01

455

Haloalkane Dehalogenase LinB Is Responsible for ?- and ?-Hexachlorocyclohexane Transformation in Sphingobium indicum B90A  

UK PubMed Central (United Kingdom)

Incubation of resting cells of Sphingobium indicum B90A, Sphingobium japonicum UT26, and Sphingobium francense Sp+ showed that they were able...Full Text Available

2006-09-01

456

Genetic aspects of birth defects: new understandings of old problems  

UK PubMed Central (United Kingdom)

Over the past two decades, combined advances in genetics, developmental biology and biochemistry have transformed the study of human birth defects. This review describes the importance of genome architecture,...Full Text Available

2007-07-01

457

Fyn Is a Novel Target of (?)-Epigallocatechin Gallate in the Inhibition of JB6 Cl41 Cell Transformation  

UK PubMed Central (United Kingdom)

The cancer preventive action of (−)-epigallocatechin gallate (EGCG), found in green tea, is strongly supported by epidemiology and laboratory research data. However, the mechanism by...Full Text Available

2008-03-01

458

Extended defects in A-15 superconductors  

International Nuclear Information System (INIS)

A brief review is given of the nature of lattice instabilities in high-T/sub c/ superconductors. The Frohlich instability in A-15 compounds is indicated to be a microdomain which acts as an embryo for the Martensitic transformations in these compounds.

459

Experience of static electrification in power transformer  

Energy Technology Data Exchange (ETDEWEB)

This document is a discussion of a static electrification event in each of the 1050 MVA units installed at the Koeburg Nuclear Power Plant in South Africa. Results of a tear-down inspection performed after the event are given, as is an analysis of the event. A number of photographs are included.

1995-05-01

460

Electromagnetic and hadronic properties of tachyons  

International Nuclear Information System (INIS)

After some preliminary comments on prevailing attitudes about tachyons, the author discusses superluminal transformations and the electromagnetic properties of tachyons. Their role in quantum mechanics is examined and a relativistically invariant hadron bootstrap model, which appears to account for many hadron states, is presented. (W.D.L).

461

Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump  

UK PubMed Central (United Kingdom)

Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes...Full Text Available

2008-09-02

462

Differential interleukin-6/Stat3 signaling as a function of cellular context mediates Ras-induced transformation  

UK PubMed Central (United Kingdom)

IntroductionTyrosine phosphorylated signal transducer and activator of transcription 3 (pStat3) is expressed in numerous cancers and is required for mediating tumorigenesis. Autocrine...Full Text Available

2010-01-01

463

Differential expression of prostaglandin-H synthase isoenzymes in normal and activated keratinocytes in vivo and in vitro.  

UK PubMed Central (United Kingdom)

Normal mouse epidermis constitutively expresses prostaglandin-H synthase 1 (PGHS-1) but no PGHS-2. Acute inflammation and epidermal hyperplasia, (hyperplastic transformation), as evoked in adult mouse...Full Text Available

1995-07-01

464

Deficiency of Phosphoinositide 3-Kinase Enhancer Protects Mice From Diet-Induced Obesity and Insulin Resistance  

UK PubMed Central (United Kingdom)

OBJECTIVEPhosphoinositide 3-kinase enhancer A (PIKE-A) is a proto-oncogene that promotes tumor growth and transformation by enhancing Akt activity. However, the physiological functions...Full Text Available

2010-04-01

465

Comparison of the e"+e"-, #gamma#e, #gamma##gamma# linear colliders  

International Nuclear Information System (INIS)

The possibility to transform the future linear e"+e"-colliders into the #gamma#e and #gamma##gamma# colliders with approximately the same energies and luminosities was shown earlier. Their properties are compared from the point of view of possible physical investigations on them. 10 refs.; 1 tab.

1992-06-02

466

Characterization of the 5'-terminal cap structures of early simian virus 40 mRNA.  

UK PubMed Central (United Kingdom)

Early simian virus 40-specific mRNA was isolated from lytically infected and stably transformed cells and analyzed with respect to the 5'-terminal cap content. An analogous diversity of capped structures...Full Text Available

1980-09-01

467

Automated Creation of Datamarts from a Clinical Data Warehouse, Driven by an Active Metadata Repository  

UK PubMed Central (United Kingdom)

A methodology and toolkit are described which enable the automated metadata-driven creation of datamarts from clinical data warehouses. The software uses schema-to-schema transformation driven by an...Full Text Available

1998-01-01

468

An introductory view about superluminal frames and tachyons  

International Nuclear Information System (INIS)

An introduction to the properties and behaviour of tachyons is presented. The extension of special relativity to include superluminal frames is discussed and the generalized Lorentz transformation is considered. The consequences of the existence of tachyous for general relativity and astrophysics are also summarised. (W.D.L.).

469

Amorphous to crystalline phase transformation in Metglas reg-sign studied by Moessbauer spectroscopy  

International Nuclear Information System (INIS)

The authors present differential scanning calorimetry (DSC) and in situ Moessbauer spectroscopy results for Metglas ribbons, to which different heat treatments were made. The Curie temperature of the amorphous phase is determined and the evolution of the magnetic field of this phase is studied as a function of temperature

1997-12-01

470

A relativistic semigroup, the Lorentz group and tachyons  

International Nuclear Information System (INIS)

The construction of the linear isomorphous and relativistic semigroup, of the Lorentz group and of tachyons was done using a dual pair of space-times, where the sought realization of the parametric semigroup is the semigroup of relativist endomorphisms. The obtained relativistic semigroup of dual space-time transformations possesses certain theoretical-probability properties.

471

A radiator of electromagnetic waves with a combined shape of generatrices  

British Library Electronic Table of Contents (United Kingdom)

The problem of optimizing a horn radiator of electromagnetic waves for the reflection coefficient and the coefficient of transformation of the fundamental mode into higher order modes is solved. Optimization is performed by means of selecting a combined shape of the radiator generatrices.

2008-01-01

472

A modular approach to DC to DC power converters  

Science.gov (United States)

A familiar power inverter circuit, combined with a ferroresonant transformer and a simple control circuit, provides the basis for an economically attractive modular family of DC to DC converters. The circuit is readily adaptable to a wide range of input voltages and single or multiple output voltages.

1974-01-01

473

13C-NMR Assessment of the Pattern of Organic Matter Transformation during Domestic Wastewater Treatment by Autothermal Aerobic Digestion (ATAD)  

UK PubMed Central (United Kingdom)

The pattern of biodegradation and the chemical changes occurring in the macromolecular fraction of domestic sludge during autothermal thermophilic aerobic digestion (ATAD) was monitored and characterised...Full Text Available

2009-08-01

474

Utilization of nonlinear programming techniques in problems of complex systems  

Energy Technology Data Exchange (ETDEWEB)

Optimization methods are applied to complex problems power systems, economics, and geodesy. Transformation methods and conjugated gradient methods are used to solve the constrained problems in power systems and economics. Conjugated gradient methods are used to solve the unconstrained geodesy problem. Broad applications of the transformation methods are emphasized. In the geodesy problem, the computational efficiency of the Fletcher-Reeves method for optimization of quadratic functions is emphasized. In this problem special storage schemes were used. The method of solution of the economics problem is compared with Beale's method.

1981-01-01

475

Unified description of bradyons and tachyons based on the dynamical SO(4,2) symmetry  

International Nuclear Information System (INIS)

Firstly the so called 'conformal relativity' in the 6-dimensional conformal space is formulated. In particular the concept of dilatational degree of freedom - scale - is introduced. The special conformal transformations are interpreted as the transformations connecting dilatationally moving frames (and objects). The ideas, similar to those by Kaluza and Klein, can be applied to the conformal space to obtain a unification of gravitation and electromagnetism. Lastly the conformal symmetry is extended to imaginary scales and to negative scales. Particles having imaginary scales are shown to be tachyons, whilst particles with negative scales correspond to antiparticles. (Auth.).

476

Structural transformations of metastable #alpha#''-phase during cold deformation  

International Nuclear Information System (INIS)

Phase transformations occuring during cold deformation in hardened #alpha#+#beta# titanium alloy of the Ti-Al-Mo-Zr-Sn-Si system with 10% summary content of alloying elements are studied by X-ray diffraction analysis. Two stages of trapsformation of metastable #alpha#''-phase are found. A conclusiop is made that ability of the alloy containing #alpha#''-phase to cold deformation is determined by the presence of favourable texture, by high degree of metastability and by volume portion of #alpha#''-phase in the alloy structure.

477

Precipitation, phase transformation, and enhanced diffusion in ion-implanted silicon  

International Nuclear Information System (INIS)

This paper describes Z-contrast scanning transmission electron microscopy used to study the connection between dopant precipitation and phase transformation in high dose In"+ and Sb"+ implanted Si. In the case of In, the observations confirm a heterogeneous nucleation model. Images of the precursor precipitates give the first measurement of the diffusion coefficient in amorphous Si, with an enhancement of 10"7 over tracer crystalline values. With Sb"+ implants enhanced homogeneous nucleation is observed. The connection between these results and the transient enhanced diffusion observed in crystallized Si is discussed.

478

PD and BD probability distribution and equiprobabilistic V-T characteristic of oil-filled transformer insulation  

Energy Technology Data Exchange (ETDEWEB)

Probability distributions of partial discharge (PD) and dielectric breakdown voltage were investigated for the typical components of oil-filled transformer insulation. The equi-probabilistic PD and BD V-t characteristics were obtained from experimental results in the time range from several ..mu..sec to 10 hours. The authors point out that there is a close relationship between the scattering of PD voltage and the inclination of V-t characteristics in a long term region for ac voltage.

1982-08-01

479

Oncogenic transformation produced by agents and modalities used in cancer therapy and its modulation  

International Nuclear Information System (INIS)

The long-term survival of certain patients after treatment with radiation or chemotherapeutic agents has allowed the realization that agents that effectively control cancer in the human subject may also possess an oncogenic potential, resulting in secondary malignancies in a significant proportion of surviving patients. A quantitative assessment of the oncogenic effects of these agents at a cellular level is important, as is information on conditions and agents that may effectively alter the development of the neoplastic state. Cell culture systems where the neoplastic transformation of cells can be scored after exposure to carcinogens offer powerful tools for evaluating the oncogenic potential of radiation and chemotherapeutic agents.

1982-01-01

480

Mechanodynamical analysis of nickel-titanium alloys for orthodontics application; Analise mecanodinamica de ligas de niquel-titanio para aplicacao ortodontica  

Energy Technology Data Exchange (ETDEWEB)

Nickel-titanium alloys may coexist in more than one crystalline structure. There is a high temperature phase, austenite, and a low temperature phase, martensite. The metallurgical basis for the superelasticity and the shape memory effect relies in the ability of these alloys to transform easily from one phase to another. There are three essential factors for the orthodontist to understand nickel-titanium alloys behaviour: stress; deflection; and temperature. These three factors are related to each other by the stress-deflection, stress-temperature and deflection-temperature diagrams. This work was undertaken with the objective to analyse commercial nickel-titanium alloys for orthodontics application, using the dynamical mechanical analyser - DMA. Four NiTi 0,017 X 0,025'' archwires were studied. The archwires were Copper NiTi 35 deg C (Ormco), Neo Sentalloy F200 (GAC), Nitinol Superelastic (Unitek) and NiTi (GAC). The different mechanodynamical ...

2002-07-01

481

Interferometry and refraction measurements in plasmas of elliptical cross-section  

Energy Technology Data Exchange (ETDEWEB)

The measurement of electron densities using interferometry and refraction measurements in plasmas with cross-sections where the electron density contours are concentric ellipses is examined. Transforms are found for both interferometrically deduced optical path-length differences and refraction angle data obtained from elliptical cross-section plasmas. The transformed data can be inverted to give electron densities using standard techniques developed for circular cross-section plasmas. Refraction of light in elliptical cross-section plasmas is examined using numerical ray tracing.

1984-04-14

482

Gauge equivalence of representations of symmetry groups in quantum mechanics  

International Nuclear Information System (INIS)

The equivalence of representations of symmetry groups operating upon wave-functions in configuration space is studied with regard to the (intuitive) notion of physical equivalence. A refinement of the usual projective equivalence relation is introduced, called gauge equivalence, for which the allowed unitary equivalence transformations are gauge transformations. For a Euclidean as well as for Newton-Hooke symmetry group the gauge equivalence classes of unitary multiplier representations are determined. These examples support the assertion that equivalence from a physical viewpoint corresponds better to this new gauge equivalence concept than to the usual notion of projective equivalence. (author).

483

Effects of thermophoresis and radiation on laminar flow along a semi-infinite vertical plate  

British Library Electronic Table of Contents (United Kingdom)

The present contribution deals with the thermophoresis particle deposition and thermal radiation effects on the flow, heat and mass transfer characteristics in a viscous fluid over a semi-infinite vertical porous plate. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically by means of the fourth-order Runge?Kutta method with a shooting technique. The effects of different parameters on the dimensionless velocity, temperature, and concentration profiles are shown graphically. In addition, results for the local skin-friction coefficient, the local Nusselt number, and the local Sherwood number are tabulated and discussed.

2011-01-01

484

Effects of thermophoresis and radiation on laminar flow along a semi-infinite vertical plate  

Science.gov (United States)

The present contribution deals with the thermophoresis particle deposition and thermal radiation effects on the flow, heat and mass transfer characteristics in a viscous fluid over a semi-infinite vertical porous plate. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically by means of the fourth-order Runge-Kutta method with a shooting technique. The effects of different parameters on the dimensionless velocity, temperature, and concentration profiles are shown graphically. In addition, results for the local skin-friction coefficient, the local Nusselt number, and the local Sherwood number are tabulated and discussed.

2011-04-01

485

Duality and dilation  

Energy Technology Data Exchange (ETDEWEB)

This paper reviews and elaborates on the issue of the dilaton transformation under the usual {tau} {yields} {alpha}{prime}/{tau} target space duality and its non-static generalization (or {sigma}-model duality). It is found that the transformation law {tau} {yields} {alpha}{prime}/{tau}, {phi} {yields} {phi} In ({tau}/{alpha}{prime}) which guarantees duality at the one-loop {sigma}-model level should be modified at two (and higher) loop order. The non-static duality is illustrated on the example of cosmological solutions in D {ge} 2 with time-dependent radii of space torus.

1991-06-21

486

Development of a synchronous key to controlled energization of three-phase transformers; Desenvolvimento de uma chave sincrona para energizacao controlada de transformadores trifasicos  

Energy Technology Data Exchange (ETDEWEB)

This work describes the development of a synchronous key based on micro controller to the switching of three-phase power transformers, which makes possible the achievement of tests to register the inrush current, and the previous establishment of the instantaneous values of the voltage firstly applied to different phases of the energy process. This key is a value tool to the development electric power system projects and to the teaching and researching activities at the laboratory related to transitory phenomena and electric system protection.

2009-07-01

487

Calculation of eddy current losses in metal parts of power transformers  

Energy Technology Data Exchange (ETDEWEB)

To maintain quality, performance and competitiveness, the eddy current losses in metal parts of power transformers in the range of 50-200 MVA are investigated in a more detailed form. The finite element calculations utilize different modelling strategies for the current carrying metal parts. Several global and local results are further used to obtain simplified calculation approaches for an inclusion in the initial design and the design optimization. The results from two finite element approaches using nodal and edge based formulations will be compared with measurements. (Author)

2003-04-01

488

Anomaliously high radiation hardening of iron-chromium alloys  

International Nuclear Information System (INIS)

Argon ions irradiation of 12% Cr steels and Fe/Cr alloys results in the hardening up to 10000 MPa. This value exceeds the hardening level even for martensitic transformation. Along with the increase of microhardness following irradiation the shape of X-ray graph of the affected materials changes considerable. Hardening value and behavior are determined by temperature radiation doze, preliminary ageing, extent of cold strain and alloying. The odserved phenomenon is supposed to be caused by irradiation-induced structural transformations. Reversibility of radiation hardening of the materials in question was observed.

489

Analysis of the chemical transformations induced at the surface of polyacrylonitrile and polymethacrylonitrile films by 5 keV proton beams  

Energy Technology Data Exchange (ETDEWEB)

In this work, the chemical transformations induced by 5 keV protons (10{sup 6} ion cm{sup -2}) at the surface of 0.4 {mu}m polyacrylonitrile and polymethacrylonitrile films are analysed by XPS and IRRAS. Spectroscopic changes in both the polymers are globally similar, the most significant feature being a lower relative concentration of nitrogen with respect to carbon closer to the surface. Quantitatively, this change is more marked in the case of polyacrylonitrile which suggests a direct relation with the hydrogen in {alpha} to the nitrile function.

1999-05-02

490

A Remark on Gauge Transformations and the Moving Frame Method  

CERN Document Server

In this note we give a shorter proof of recent regularity results by Riviere and Riviere-Struwe. We differ from the mentioned articles only in using the direct method of Helein's moving frame to construct a suitable gauge transformation. Though this is neither new nor surprising, it enables us to describe a proof of regularity using besides the duality of Hardy- and BMO-space only elementary arguments of calculus of variations and algebraic identities. Moreover, we remark that in order to prove Hildebrandt's conjecture one can avoid the Nash-Moser imbedding theorem. There are no new results presented here, nor are there any techniques we could claim originality for.

2009-01-01

491

In vivo distribution and excretion studies and in vitro blood studies on the kinetics of lead-203 in beagle dogs. [Thesis  

Energy Technology Data Exchange (ETDEWEB)

The distribution of carrier free lead-203 between plasma and cells of canine blood in vitro was measured. Activity in the plasma decreased to less than 5% of the initial blood activity during the first 15 min and then exponentially with a half time of 160 min. Incubation in cell free plasma before addition to whole blood transformed the isotope, decreasing the amount subsequently associated with cells. In animal studies, activity was measured in plasma, blood cells, urine, and feces after exposure to lead-203. In one group, the animals were exposed by intravenous injection of dilute citric acid solutions of isotope. In a second group, carrier free isotope which had been transformed by incubation in plasma was injected intravenously. The kinetics of the distribution of the isotope differed between the two experimental groups. After injection of the transformed lead, the lead-203 content of the blood cell fraction rose from ...

1980-01-01

492

Tests show ability of vacuum circuit breaker to interrupt fast transient recovery voltage rates of rise of transformer secondary faults  

Energy Technology Data Exchange (ETDEWEB)

A Vacuum Circuit Breaker demonstrated its ability to interrupt short circuits with faster than normal rates of rise of Transient Recovery Voltage (TRV) at levels greater than those produced by most transformer secondary faults. Two recent exploratory test programs evaluated the interrupting ability of a 15kV Vacuum Circuit Breaker containing interrupters of the rotating arc type with contacts made from a Chromium-Copper powder metal mixture. The interrupting conditions covered a wide range of currents from 10% to 130% of the 28kA rated short circuit current of the tested circuit breaker and a wide range of TRV rates of rise, including the relatively slow rate of rise, normally used in testing and found in most indoor circuit breaker applications; two faster rates of rise equaling and exceeding those found in a known power plant transformer secondary protection application; and the fastest rates of rise possible in the laboratory which exceed ...

1994-12-31

493

Modeling of the non isothermal and non isobaric transformations kinetics. Application to the kaolinite de-hydroxylation and to the tri-uranium octo-oxide reduction by hydrogen; Modelisation de la cinetique de transformations non isothermes et (ou) non isobares. Application a la deshydroxylation de la kaolinite et a la reduction de l'octooxyde de triuranium par l'hydrogene  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to be able to describe transformations, occurring when solids and gases are in non isothermal and non isobaric conditions, with kinetic models. A methodology has been used. Two essential processes have to be taken into account: the germination and the growth. The germs are supposed to be formed (at constant temperature and pressure) in the grains surface with a constant velocity by surface unit, (gamma), called germination surface frequency (number of germs.m{sup -2}.s{sup -1}. The growth velocity is characterized by a growth surface reactivity, (phi) (in mol.m{sup -2}.s{sup -1}). With an appropriate transformation model, it is possible to obtain the variations of (gamma) and (phi) in terms of the temperature and pressure which are then used in the calculation of the velocity in non isothermal and non isobaric conditions. In order to validate the developed method, two reactions have been studied. For the first one, the ...

2002-12-15

494

Structural transformation of Li{sub 2}CoPO{sub 4}F upon Li-deintercalation  

Energy Technology Data Exchange (ETDEWEB)

Electrochemical performance and structural properties of the high-voltage cathode material Li{sub 2}CoPO{sub 4}F have been investigated. The cyclic voltammetry and coulometry under potential step mode in the voltage range 3.0-5.1 V vs. Li revealed a structural transformation at potentials above 4.8 V. This transformation occurring upon Li-extraction appears to be irreversible: the subsequent Li-insertion does not result in restoration of the initial structure, but takes place within a new ''modified'' framework. According to the structure refinement this modification involves the mutual rotations of (CoO{sub 4}F{sub 2}) octahedra and (PO{sub 4}) tetrahedra accompanied by the considerable unit cell expansion which is expected to enhance the Li-transport upon subsequent cycling. The new framework demonstrates a reversible Li-insertion/extraction in a solid-solution regime with stabilized discharge capacity at ...

2011-01-01

495

Natural gels: crystal-chemistry of short range ordered components in Al, Fe, and Si systems  

Energy Technology Data Exchange (ETDEWEB)

In this review, the most important inorganic natural gels are presented: opal, aluminosilicate (allophanes) and hydrous iron oxides and silicates. It is demonstrated that natural gels are ordered at the atomic scale. In allophanes, Al is distributed between octahedral and tetrahedral sites. The amount of Al increases as Al/Si ratio decreases. Si-rich allophane have a local structure around Al and Si very different of that is known in kaolinite or halloysite. Transformation of Si-rich allophanes to crystallized minerals implies dissolution-recrystallization processes. On the contrary, in iron silicate with Fe/Si = 0.72, Si and Fe environments are close to those found in nontronite. The gel transformation to Fe-smectite may occur by long range ordering during ageing. In ferric silicate gels, the similarity of local structure around Fe in poorly ordered precursors and what is known in crystallized minerals suggests a solid ...

1997-07-01

496

Laser induced local and periodic phase transformations in iron oxide thin films obtained by chemical vapour deposition  

International Nuclear Information System (INIS)

Iron oxide films have been deposited on Si(100) substrates by chemical vapour deposition (CVD) of iron(III) tert-butoxide ([Fe(O "tBu)_3]_2) in the temperature range 350-450 deg. C. The precursor flux and substrate temperature were varied to control the phase composition, average grain size and film thickness. The nature of substrate and deposition temperature markedly influence the morphology and iron-oxygen stoichiometry in the CVD deposits. Phase transformations in iron oxide films were achieved through precise local and periodic heating of the films by interfering laser beams. The interaction of iron oxide films with short laser pulses (Nd:YAG, 355 nm) induced partial transformation of hematite (#alpha#-Fe_2O_3) to magnetite (Fe_3O_4) or magnetite to wuestite (Fe_1_-_xO), respectively. The phase characterization and morphology of the hematite and magnetite films were investigated before and after laser irradiation by X-ray diffractometry, ...

2005-07-15

497

Extension of QMD to the relativistic region and the calculation of proton induced reactions  

Energy Technology Data Exchange (ETDEWEB)

When quantum molecular dynamics (QMD) is applied to the nuclear reactions in theory of relativity region, a number of problems arise, and in order to solve them, the prescription of the extension of ordinary nonrelativistic QMD is introduced, and the analysis of proton incidence reaction by using it is shown. By introducing the interaction corresponding to Lorentz transformation, the problems were solved. QMD is the semiclassical simulation that treats the motion of nucleons represented by Gauss wave packet. The motion of wave packet center is expressed by Newton equations and two-nucleon collision. The introduction of the interaction corresponding to Lorentz transformation is explained. As the result of the introduction, through the relative distance of two particles, the interaction becomes to depend on momentum. The phase distribution function of one body corresponding to Lorentz transformation is used for calculating ...

1995-06-01

498

Experimental Electron Heat Diffusion in TJ-II ECRH Plasmas  

Energy Technology Data Exchange (ETDEWEB)

Interpretative transport has been used to revisit the global scalings of TJ-II ECRH plasmas from a local perspective. Density, rotational transform and ERCH power scans were analysed based upon Thomson Scattering data (electron density and temperature) in steady state discharges. A simple formula to obtain the thermal conductivity, assuming pure diffusion and negligible convective heat fluxes was used in a set of 161 discharges. All the analysis was performed with the ASTRA transport shell. The density scan indicates that inside n=0,4 there is no significant change of e with density in the range studied (0.4 <ne>(1019m-3) 1.0), while in 0,5 <0,8 approximately, e decreases with density. In the rotational transform scan it is found that the values of e when a low order rational of the rotational transform is present locally seem to be smaller for the corresponding range, although it is apparent a general ...

2006-07-01

499

Effect of chronic fractionated low-dose gamma irradiation on division potential of human embryonic cells in vitro  

Energy Technology Data Exchange (ETDEWEB)

We investigated the in vitro phenotypic transformation of human embryo (HE) cells that were repeatedly irradiated (7.5 cGy once a week) throughout their life-span. Irradiation was repeated until the cells had accumulated 195 cGy (equivalent to the 26th passage). Samples of cells were assayed for survival by colony formation, as well as for mutation at the hypoxanthine guanine phosphoribosyl transferase (HGPRT) locus and for transformation by focus formation. The life-span (mean number of population doublings) of multiply irradiated cells with a total dose of 97.5 cGy was slightly but significantly prolonged over that of controls. After HE cells had accumulated 195 cGy, the maximum number of divisions increased to 130-160% of the number in non-irradiated control cells. Transformed foci were not observed until cells had accumulated 97.5 cGy, and then increased with the increasing accumulation of radiation. However, no cells ...

1991-12-01

500

A wavelet approach to fault diagnosis of a gearbox under varying load conditions  

Science.gov (United States)

Varying load can cause changes in a measured gearbox vibration signal. However, conventional techniques for fault diagnosis are based on the assumption that changes in vibration signal are only caused by deterioration of the gearbox. There is a need to develop a technique to provide accurate state indicator of gearbox under fluctuating load conditions. This paper presents an approach to gear fault diagnosis based on complex Morlet continuous wavelet transform under this condition. Gear motion residual signal, which represents the departure of time synchronously averaged signal from the average tooth-meshing vibration, is analyzed as source data due to its lower sensitiveness to the alternating load condition. A fault growth parameter based on the amplitude of wavelet transform is proposed to evaluate gear fault advancement quantitatively. We found that this parameter is insensitive to varying load and can correctly indicate early gear fault. ...

2010-04-01