WorldWideScience

Sample records for sands high permeability

  1. Permeability Tests on Eastern Scheldt Sand

    DEFF Research Database (Denmark)

    Jakobsen, Kim Parsberg

    on the characteristics of the soil matrix, the permeability is determined for different void ratios. All tests are performed on reconstituted specimens of Eastern Scheldt Sand. The permeability is determined by use of a falling head apparatus. Finally the test results are briefly summarised and a relationship between......The flow through porous media plays an important role in various engineering disciplines, as for example in ground water hydrology and soil mechanics. In the present study the permeability is determined for a fine, saturated sand. As the flow through a porous media strongly depends...

  2. Permeability Tests on Silkeborg Sand No. 0000

    DEFF Research Database (Denmark)

    Lund, Willy; Jakobsen, Kim Parsberg

    on the characteristics of the soil matrix, the permeability is determined for different void ratios. All tests are performed on reconstituted specimens of Silkeborg Sand No. 0000. The permeability is determined by use of a falling head apparatus. The apparatus, test procedures and the analysis method are described......The flow through porous media plays an important role in various engineering disciplines, as for example in ground water hydrology and soil mechanics. In the present study the permeability is determined for a fine, saturated sand. As the flow through a porous media strongly depends...

  3. Study on the Permeability Characteristics of Polyurethane Soil Stabilizer Reinforced Sand

    Directory of Open Access Journals (Sweden)

    Jin Liu

    2017-01-01

    Full Text Available A polymer material of polyurethane soil stabilizer (PSS is used to reinforce the sand. To understand the permeability characteristics of PSS reinforced sand, a series of reinforcement layer form test, single-hole permeability test, and porous permeability test of sand reinforced with PSS have been performed. Reinforcement mechanism is discussed with scanning electron microscope images. The results indicated that the permeability resistance of sand reinforced with polyurethane soil stabilizer is improved through the formation of reinforcement layer on the sand surface. The thickness and complete degree of the reinforcement layer increase with the increasing of curing time and PSS concentration. The water flow rate decreases with the increasing of curing time or PSS concentration. The permeability coefficient decreases with the increasing of curing time and PSS concentration and increases with the increasing of depth in specimen. PSS fills up the voids of sand and adsorbs on the surface of sand particle to reduce or block the flowing channels of water to improve the permeability resistance of sand. The results can be applied as the reference for chemical reinforcement sandy soil engineering, especially for surface protection of embankment, slope, and landfill.

  4. Research on the performance of sand-based environmental-friendly water permeable bricks

    Science.gov (United States)

    Cai, Runze; Mandula; Chai, Jinyi

    2018-02-01

    This paper examines the effects of the amount of admixture, the water cement ratio, the aggregate grading, and the cement aggregate ratio on the mechanical service properties and of porous concrete pavement bricks including strength, water permeability, frost resistance, and wear resistance. The admixture can enhance the performance of water permeable brick, and optimize the design mix. Experiments are conducted to determine the optimal mixing ratios which are given as; (1) the admixture (self-developed) within the content of 5% of the cement quality; (2) water-cement ratio equal to 0.34; (3) cement-aggregate ratio equal to 0.25; (4) fine aggregate of 70% (particle size 0.6-2.36mm); and coarse aggregate of 30% (particle size: 2.36-4.75mm). The experimental results that the sand-based permeable concrete pavement brick has a strength of 35.6MPa and that the water permeability coefficient is equal to 3.5×10-2cm/s. In addition, it was found that the concrete water permeable brick has good frost resistance and surface wear resistance, and that the its production costs are much lower than the similar sand-based water permeable bricks in China.

  5. Permeability Characteristics of Compacted and Stabilized Clay with Cement, Peat Ash and Silica Sand

    Directory of Open Access Journals (Sweden)

    Seyed Esmaeil Mousavi

    2016-06-01

    Full Text Available The present paper investigates the influence of stabilization with cement, peat ash, and silica sand on permeability coefficient (kv of compacted clay, using a novel approach to stabilize the clay with peat ash as a supplementary material of cement in the compacted and stabilized soil. In order to assess the mentioned influence, test specimens of both untreated and stabilized soil have been tested in the laboratory so that their permeability could be evaluated. Falling head and one dimensional consolidation tests of laboratory permeability were performed on the clay specimens and the chemical compositions of the materials as well as microstructure of the stabilized soil with 18% cement, 2% peat ash, and 5% silica sand were investigated, using X-ray fluorescence and scanning electron microscopy respectively. Results show that for soil stabilization with up to 8% cement content (of the dry weight of the soil, the average value of coefficient of permeability (kv is very close to that of untreated soil, whereas the kv value decreases drastically for 18% cement under identical void ratio conditions. It is further revealed that addition of 18% cement, 2% peat ash, and 5% silica sand had decreased the coefficient of permeability by almost 2.2 folds after 24 h, while about 1.7 folds increase was observed in coefficient of permeability once 13.5% of cement, 1.5% of peat ash, and 20% of silica sand were added. The partial replacement of cement with the 2% peat ash can reduce the consumption of cement for soil stabilization.

  6. Gravel-Sand-Clay Mixture Model for Predictions of Permeability and Velocity of Unconsolidated Sediments

    Science.gov (United States)

    Konishi, C.

    2014-12-01

    Gravel-sand-clay mixture model is proposed particularly for unconsolidated sediments to predict permeability and velocity from volume fractions of the three components (i.e. gravel, sand, and clay). A well-known sand-clay mixture model or bimodal mixture model treats clay contents as volume fraction of the small particle and the rest of the volume is considered as that of the large particle. This simple approach has been commonly accepted and has validated by many studies before. However, a collection of laboratory measurements of permeability and grain size distribution for unconsolidated samples show an impact of presence of another large particle; i.e. only a few percent of gravel particles increases the permeability of the sample significantly. This observation cannot be explained by the bimodal mixture model and it suggests the necessity of considering the gravel-sand-clay mixture model. In the proposed model, I consider the three volume fractions of each component instead of using only the clay contents. Sand becomes either larger or smaller particles in the three component mixture model, whereas it is always the large particle in the bimodal mixture model. The total porosity of the two cases, one is the case that the sand is smaller particle and the other is the case that the sand is larger particle, can be modeled independently from sand volume fraction by the same fashion in the bimodal model. However, the two cases can co-exist in one sample; thus, the total porosity of the mixed sample is calculated by weighted average of the two cases by the volume fractions of gravel and clay. The effective porosity is distinguished from the total porosity assuming that the porosity associated with clay is zero effective porosity. In addition, effective grain size can be computed from the volume fractions and representative grain sizes for each component. Using the effective porosity and the effective grain size, the permeability is predicted by Kozeny-Carman equation

  7. Characterization of sand lenses and their role for subsurface transport in low-permeability clay tills

    DEFF Research Database (Denmark)

    Kessler, Timo Christian; Klint, K. E.; Nilsson, B.

    2011-01-01

    Glacial sediments dominate large parts of the geological topology in Denmark. They predominantly consist of lowpermeability tills, but fractures and sand-lenses constitute zones of enhanced permeability facilitating preferential flow. This study focuses on characterization of sand deposits with r...... the sand lenses in hydro-geological models to successfully characterize subsurface flow and transport, e.g. for remediation activities....

  8. Laboratory-scale measurements of effective relative permeability for layered sands

    Energy Technology Data Exchange (ETDEWEB)

    Butts, M.G.; Korsgaard, S.

    1996-12-31

    Predictions of the impact of remediation or the extent of contamination resulting from spills of gasoline, solvents and other petroleum products, must often be made in complex geological environments. Such problems can be treated by introducing the concept of effective parameters that incorporate the effects of soil layering or other heterogeneities into a large-scale flow description. Studies that derive effective multiphase parameters are few, and approximations are required to treat the non-linear multiphase flow equations. The purpose of this study is to measure effective relative permeabilities for well-defined multi-layered soils at the laboratory scale. Relative permeabilities were determined for homogeneous and layered, unconsolidated sands using the method of Jones and Roszelle (1978). The experimental data show that endpoint relative permeabilities are important in defining the shape of the relative permeability curves, but these cannot be predicted by estimation methods base on capillary pressure data. The most significant feature of the measured effective relative permeability curves is that the entrapped (residual) oil saturation is significantly larger than the residual saturation of the individual layers. This observation agrees with previous theoretical predictions of large-scale entrapment Butts, 1993 and (1995). Enhanced entrapment in heterogeneous soils has several important implications for spill remediation, for example, the reduced efficiency of direct recovery. (au) 17 refs.

  9. Laboratory-scale measurements of effective relative permeability for layered sands

    International Nuclear Information System (INIS)

    Butts, M.G.; Korsgaard, S.

    1996-01-01

    Predictions of the impact of remediation or the extent of contamination resulting from spills of gasoline, solvents and other petroleum products, must often be made in complex geological environments. Such problems can be treated by introducing the concept of effective parameters that incorporate the effects of soil layering or other heterogeneities into a large-scale flow description. Studies that derive effective multiphase parameters are few, and approximations are required to treat the non-linear multiphase flow equations. The purpose of this study is to measure effective relative permeabilities for well-defined multi-layered soils at the laboratory scale. Relative permeabilities were determined for homogeneous and layered, unconsolidated sands using the method of Jones and Roszelle (1978). The experimental data show that endpoint relative permeabilities are important in defining the shape of the relative permeability curves, but these cannot be predicted by estimation methods base on capillary pressure data. The most significant feature of the measured effective relative permeability curves is that the entrapped (residual) oil saturation is significantly larger than the residual saturation of the individual layers. This observation agrees with previous theoretical predictions of large-scale entrapment Butts, 1993 and (1995). Enhanced entrapment in heterogeneous soils has several important implications for spill remediation, for example, the reduced efficiency of direct recovery. (au) 17 refs

  10. Geo-environmental applications for permeable sand-shredded tyre mixtures; Applications geoenvironnementales de melanges sable-pneu permeables

    Energy Technology Data Exchange (ETDEWEB)

    Tabbaa, A.A. [Cambridge Univ. (United Kingdom). Dept. of Engineering; Cogswell, C.A. [Formely Cambridge University Engineering Dept., Cambridge (United Kingdom); Al-Tabbaa, A.M.B. [Kings College London (United Kingdom)

    2000-07-01

    This paper presents details and results of recent work conducted on the geo-environmental applications of permeable sand-tyre mixtures. This work is part of an extensive research programme initiated by the first author on the use of waste tyre in various geotechnical and geo-environmental applications. The paper considers sand-tyre in mixed and layered sample configurations as part of active containment or landfill leachate collection system. The paper first investigates the level of leached copper and zinc from the tyre and its capacity to absorb paraffin. It then looks at the in-situ mixing of tyre with soil using a laboratory-scale auger. The work produced encouraging results and showed that tyre is a suitable waste material for use in the above applications. (authors)

  11. Alteration behavior of bentonite barrier of radioactive waste disposal by alkaline solutions. Part 2. Effect of type of alkaline solution on permeability of compacted bentonite-sand mixture

    International Nuclear Information System (INIS)

    Yokoyama, Shingo; Nakamura, Kunihiko; Tanaka, Yukihisa; Hironaga, Michihiko

    2011-01-01

    Permeability tests were carried out using compacted bentonite-sand mixture with initial dry density of 1.55 Mg/m 3 and alkaline solutions at 50degC for about two years to estimate the alteration behavior and the change in the permeability. Bentonite-sand mixtures which contain bentonites of 15wt% were made using Na-bentonite or Ca-exchanged bentonite. 0.3M-NaOH solution with pH 13.3 and 5mM-Ca(OH) 2 solution with pH 12.0 were used to the permeability tests of Na-bentonite-sand mixture and of Ca-exchanged bentonite-sand mixture, respectively. In the case of the permeability test conducted using NaOH solution, montmorillonite and other associated minerals were dissolved, and consequently, the dry density and effective montmorillonite density of Na-bentonite-sand mixture were decreased. Furthermore, the mineralogical feature of montmorillonite was changed (i.e. beidellitization and an increase in the layer charge). The permeability of Na-bentonite-sand mixture was increased 5.6 times by the end of permeability test as a result of above alteration. In the case of the permeability test conducted using Ca(OH) 2 solution, montmorillonite and other associated minerals were dissolved, and calcium silicate hydrate (C-S-H) was precipitated. Consequently, the dry density of Ca-exchanged bentonite-sand mixture was increased, while the effective montmorillonite density was decreased. The mineralogical feature of montmorillonite was changed (i.e. beidellitization and an increase in the layer charge). The permeability of Ca-exchange bentonite-sand mixture was decreased by more than two orders of magnitude due to fill the pore of Ca-exchange bentonite-sand mixture by the precipitation of C-S-H. From above results, the type of alkaline solution affects the mineralogical alteration behavior of the compacted bentonite-sand mixture, and consequently, affects the changing trend of permeability. In conclusion, it is important not only to consider the dissolution of montmorillonite, but

  12. Permeability Characteristics of Compacted and Stabilized Clay with Cement, Peat Ash and Silica Sand

    OpenAIRE

    Seyed Esmaeil Mousavi; Leong Sing Wong

    2016-01-01

    The present paper investigates the influence of stabilization with cement, peat ash, and silica sand on permeability coefficient (kv) of compacted clay, using a novel approach to stabilize the clay with peat ash as a supplementary material of cement in the compacted and stabilized soil. In order to assess the mentioned influence, test specimens of both untreated and stabilized soil have been tested in the laboratory so that their permeability could be evaluated. Falling head and one dimension...

  13. Diel coral reef acidification driven by porewater advection in permeable sands, Heron Island, Great Barrier Reef

    DEFF Research Database (Denmark)

    Santos, Isaac R.; Glud, Ronnie N.; Maher, Damien

    2011-01-01

    Little is known about how biogeochemical processes in permeable sediments affect the pH of coastal waters. We demonstrate that seawater recirculation in permeable sands can play a major role in proton (H+) cycling in a coral reef lagoon. The diel pH range (up to 0.75 units) in the Heron Island...... lagoon was the broadest ever reported for reef waters, and the night‐time pH (7.69) was comparable to worst‐case scenario predictions for seawater pH in 2100. The net contribution of coarse carbonate sands to the whole system H+ fluxes was only 9% during the day, but approached 100% at night when small...... scale (i.e., flow and topography‐induced pressure gradients) and large scale (i.e., tidal pumping as traced by radon) seawater recirculation processes were synergistic. Reef lagoon sands were a net sink for H+, and the sink strength was a function of porewater flushing rate. Our observations suggest...

  14. Rapid increases in permeability and porosity of bentonite-sand mixtures due to alteration by water vapor

    International Nuclear Information System (INIS)

    Couture, R.A.

    1984-01-01

    Packed columns of canister packing material containing 25% bentonite and 75% quartz or basalt sand, were exposed to water vapor at temperatures up t 260 0 C. The permeabilities of the columns were subsequently measured after complete saturation with liquid water in a pressurized system. Exposure to water vapor caused irreversible increases in permeability by factors of up to 10 5 . After saturation with liquid water, the permeability was nearly independent of temperature. The increases in permeability were due to a large decrease in the ability of the bentonite to swell in water. Calculations suggest that swelling of bentonite altered at 250 0 C was not sufficient to fill the pore spaces. If the pore spaces are filled, the mixture will form an effective barrier against flow, diffusion, and transport of colloids. The results suggest that if bentonite-based canister packing material is exposed even briefly to water vapor at high temperatures in a high-level nuclear waste repository, its performance will be seriously impaired. The problem is less severe if the proportion of bentonite is high and the material is highly compacted. Previous results show significant degradation of bentonite by water vapor at temperatures as low as 150 0 C. This suggests that in some repositories, backfill in tunnels and drifts may also be affected. 9 references, 5 figures, 1 table

  15. Interpretation of the stiffness and permeability of Sand-Kaolin mixtures in the framework of homogenization

    Directory of Open Access Journals (Sweden)

    Claude Boutin

    2010-03-01

    Full Text Available This study deals with the behaviour of mixtures of sand and saturated kaolin paste considered as composite materials made of permeable and deformable (with non-linear behaviour matrix (the kaolin paste with rigid and impervious inclusions (the sand grains. Oedometric and permeability tests conducted on such mixtures highlight the key role of the state of the clay paste, and show the existence of a threshold of sand grain concentration above which a structuring effect influences both modulus and permeability. At the light of these experiments, the usual and tangent homogenization process (with simplifying assumptions to make the problem manageable has been applied to estimate the mixture permeability and tangent compressibility. Qualitative and quantitative comparisons with experimental data point out the domain of interest and the limitations of such approaches.O estudo lida com o comportamento de misturas compostas por areia e uma pasta de caulinita considerada um material composto feito de uma matriz (caulinita permeável e deformável (com comportamento não-linear com inclusões rígidas e impermeáveis (grãos de areia. Testes de permeabilidade e odométricos conduzidos nestas misturas enfatizam o papel chave de estado da pasta argilosa e mostram a existência de uma concentração crítica de grãos de areia com efeito estruturante que influencia o módulo e a permeabilidade. Sob a luz destes experimentos o processo de homogeneização usual e tangente (com hipóteses simplificadoras para tornar o problema tratável foi aplicado para estimar a permeabilidade da mistura e a compressibilidade tangente. Comparações qualitativas e quantitativas com dados experimentais apontam o domínio de interesse bem como a limitação destas abordagens.

  16. Field test on sand compaction pile method with copper slag sand; Dosuisai slag wo mochiita SCP koho no shiken seko

    Energy Technology Data Exchange (ETDEWEB)

    Minami, K.; Matsui, H.; Naruse, E.; Kitazume, M. [Port and Harbour Research Inst., Kanagawa (Japan)

    1997-09-20

    This paper describes the sand compaction pile (SCP) method using copper slag sand. The SCP method is a method by which sand compaction piles are constructed in the ground, and improvement can be obtained in a short period. This method has been widely used even in the port areas for enhancing the bearing power of soft clay ground and the lateral resistance of sheet pile. A great deal of sand is required as a material. The sand requires high permeability, proper size distribution with less fine particle fraction content, easy compaction property with enough strength, and easy discharging property from the casing of construction machines as required properties. Recently, it becomes hard to secure proper sand materials. The copper slag sand is obtained from refining process of copper as a by-product which is quenched in water flow and crushed in water. The copper slag sand has higher particle density than that of sand, excellent permeability, and similar size distribution to that of sand. From compaction drainage triaxial compression test and permeability test, it was found that the mechanical properties of copper slag sand did not change by the crushing of grains with keeping excellent permeability. Through the test construction, applicability of the copper slag sand to the SCP method could be confirmed as an alternate material of sand. 17 refs., 9 figs., 4 tabs.

  17. The Dependence of Water Permeability in Quartz Sand on Gas Hydrate Saturation in the Pore Space

    Science.gov (United States)

    Kossel, E.; Deusner, C.; Bigalke, N.; Haeckel, M.

    2018-02-01

    Transport of fluids in gas hydrate bearing sediments is largely defined by the reduction of the permeability due to gas hydrate crystals in the pore space. Although the exact knowledge of the permeability behavior as a function of gas hydrate saturation is of crucial importance, state-of-the-art simulation codes for gas production scenarios use theoretically derived permeability equations that are hardly backed by experimental data. The reason for the insufficient validation of the model equations is the difficulty to create gas hydrate bearing sediments that have undergone formation mechanisms equivalent to the natural process and that have well-defined gas hydrate saturations. We formed methane hydrates in quartz sand from a methane-saturated aqueous solution and used magnetic resonance imaging to obtain time-resolved, three-dimensional maps of the gas hydrate saturation distribution. These maps were fed into 3-D finite element method simulations of the water flow. In our simulations, we tested the five most well-known permeability equations. All of the suitable permeability equations include the term (1-SH)n, where SH is the gas hydrate saturation and n is a parameter that needs to be constrained. The most basic equation describing the permeability behavior of water flow through gas hydrate bearing sand is k = k0 (1-SH)n. In our experiments, n was determined to be 11.4 (±0.3). Results from this study can be directly applied to bulk flow analysis under the assumption of homogeneous gas hydrate saturation and can be further used to derive effective permeability models for heterogeneous gas hydrate distributions at different scales.

  18. FeS-coated sand for removal of arsenic(III) under anaerobic conditions in permeable reactive barriers

    Science.gov (United States)

    Han, Y.-S.; Gallegos, T.J.; Demond, A.H.; Hayes, K.F.

    2011-01-01

    Iron sulfide (as mackinawite, FeS) has shown considerable promise as a material for the removal of As(III) under anoxic conditions. However, as a nanoparticulate material, synthetic FeS is not suitable for use in conventional permeable reactive barriers (PRBs). This study developed a methodology for coating a natural silica sand to produce a material of an appropriate diameter for a PRB. Aging time, pH, rinse time, and volume ratios were varied, with a maximum coating of 4.0 mg FeS/g sand achieved using a pH 5.5 solution at a 1:4 volume ratio (sand: 2 g/L FeS suspension), three days of aging and no rinsing. Comparing the mass deposited on the sand, which had a natural iron-oxide coating, with and without chemical washing showed that the iron-oxide coating was essential to the formation of a stable FeS coating. Scanning electron microscopy images of the FeS-coated sand showed a patchwise FeS surface coating. X-ray photoelectron spectroscopy showed a partial oxidation of the Fe(II) to Fe(III) during the coating process, and some oxidation of S to polysulfides. Removal of As(III) by FeS-coated sand was 30% of that by nanoparticulate FeS at pH 5 and 7. At pH 9, the relative removal was 400%, perhaps due to the natural oxide coating of the sand or a secondary mineral phase from mackinawite oxidation. Although many studies have investigated the coating of sands with iron oxides, little prior work reports coating with iron sulfides. The results suggest that a suitable PRB material for the removal of As(III) under anoxic conditions can be produced through the deposition of a coating of FeS onto natural silica sand with an iron-oxide coating. ?? 2010 Elsevier Ltd.

  19. Modeling and Optimization of Phenol Formaldehyde Resin Sand Mould System

    Directory of Open Access Journals (Sweden)

    Chate G. R.

    2017-06-01

    Full Text Available Chemical bonded resin sand mould system has high dimensional accuracy, surface finish and sand mould properties compared to green sand mould system. The mould cavity prepared under chemical bonded sand mould system must produce sufficient permeability and hardness to withstand sand drop while pouring molten metal through ladle. The demand for improved values of permeability and mould hardness depends on systematic study and analysis of influencing variables namely grain fineness number, setting time, percent of resin and hardener. Try-error experiment methods and analysis were considered impractical in actual foundry practice due to the associated cost. Experimental matrices of central composite design allow conducting minimum experiments that provide complete insight of the process. Statistical significance of influencing variables and their interaction were determined to control the process. Analysis of variance (ANOVA test was conducted to validate the model statistically. Mathematical equation was derived separately for mould hardness and permeability, which are expressed as a non-linear function of input variables based on the collected experimental input-output data. The developed model prediction accuracy for practical usefulness was tested with 10 random experimental conditions. The decision variables for higher mould hardness and permeability were determined using desirability function approach. The prediction results were found to be consistent with experimental values.

  20. An integrated approach to permeability modeling using micro-models

    Energy Technology Data Exchange (ETDEWEB)

    Hosseini, A.H.; Leuangthong, O.; Deutsch, C.V. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Alberta Univ., Edmonton, AB (Canada)

    2008-10-15

    An important factor in predicting the performance of steam assisted gravity drainage (SAGD) well pairs is the spatial distribution of permeability. Complications that make the inference of a reliable porosity-permeability relationship impossible include the presence of short-scale variability in sand/shale sequences; preferential sampling of core data; and uncertainty in upscaling parameters. Micro-modelling is a simple and effective method for overcoming these complications. This paper proposed a micro-modeling approach to account for sampling bias, small laminated features with high permeability contrast, and uncertainty in upscaling parameters. The paper described the steps and challenges of micro-modeling and discussed the construction of binary mixture geo-blocks; flow simulation and upscaling; extended power law formalism (EPLF); and the application of micro-modeling and EPLF. An extended power-law formalism to account for changes in clean sand permeability as a function of macroscopic shale content was also proposed and tested against flow simulation results. There was close agreement between the model and simulation results. The proposed methodology was also applied to build the porosity-permeability relationship for laminated and brecciated facies of McMurray oil sands. Experimental data was in good agreement with the experimental data. 8 refs., 17 figs.

  1. Geotechnical properties of crude oil contaminated sand

    International Nuclear Information System (INIS)

    Puri, V.K.; Das, B.M.; Cook, E.E.; Shin, E.C.

    1994-01-01

    Contamination of soil due to an oil spill influences its subsequent engineering behavior. An investigation was conducted to study the effect of crude oil contamination on compaction characteristics, shear strength, one-dimensional compression, and coefficient of permeability. Water permeability was also determined by using commercial grade motor oils as contaminants. The test results indicate that the compaction characteristics are influenced by oil contamination. The angle of internal friction of sand (based on total stress condition) decreases due to presence of oil within the pore spaces in sand. One dimensional compression characteristics of sand are significantly influenced by oil contamination resulting in a decrease in the value of constrained modulus with increase in the degree of oil contamination compared to the case of dry sand. Water permeability was observed to be a function of the initial viscosity and the degree of saturation due to the contaminating oil

  2. Enhanced CAH dechlorination in a low permeability, variably-saturated medium

    Science.gov (United States)

    Martin, J.P.; Sorenson, K.S.; Peterson, L.N.; Brennan, R.A.; Werth, C.J.; Sanford, R.A.; Bures, G.H.; Taylor, C.J.; ,

    2002-01-01

    An innovative pilot-scale field test was performed to enhance the anaerobic reductive dechlorination (ARD) of chlorinated aliphatic hydrocarbons (CAHs) in a low permeability, variably-saturated formation. The selected technology combines the use of a hydraulic fracturing (fracking) technique with enhanced bioremediation through the creation of highly-permeable sand- and electron donor-filled fractures in the low permeability matrix. Chitin was selected as the electron donor because of its unique properties as a polymeric organic material and based on the results of lab studies that indicated its ability to support ARD. The distribution and impact of chitin- and sand-filled fractures to the system was evaluated using hydrologic, geophysical, and geochemical parameters. The results indicate that, where distributed, chitin favorably impacted redox conditions and supported enhanced ARD of CAHs. These results indicate that this technology may be a viable and cost-effective approach for remediation of low-permeability, variably saturated systems.

  3. Time-independent compaction behavior of quartz sands

    NARCIS (Netherlands)

    Brzesowsky, R. H.; Spiers, C. J.|info:eu-repo/dai/nl/304829323; Peach, C. J.|info:eu-repo/dai/nl/082101906; Hangx, Suzanne|info:eu-repo/dai/nl/30483579X

    Mechanisms such as grain rearrangement, coupled with elastic deformation and grain breakage, are believed to play an important role in the time-independent compaction of sands, controlling porosity and permeability reduction during burial of clastic sediments and during depletion of highly porous

  4. High-permeability criterion for BCS classification: segmental/pH dependent permeability considerations.

    Science.gov (United States)

    Dahan, Arik; Miller, Jonathan M; Hilfinger, John M; Yamashita, Shinji; Yu, Lawrence X; Lennernäs, Hans; Amidon, Gordon L

    2010-10-04

    The FDA classifies a drug substance as high-permeability when the fraction of dose absorbed (F(abs)) in humans is 90% or higher. This direct correlation between human permeability and F(abs) has been recently controversial, since the β-blocker sotalol showed high F(abs) (90%) and low Caco-2 permeability. The purpose of this study was to investigate the scientific basis for this disparity between permeability and F(abs). The effective permeabilities (P(eff)) of sotalol and metoprolol, a FDA standard for the low/high P(eff) class boundary, were investigated in the rat perfusion model, in three different intestinal segments with pHs corresponding to the physiological pH in each region: (1) proximal jejunum, pH 6.5; (2) mid small intestine, pH 7.0; and (3) distal ileum, pH 7.5. Both metoprolol and sotalol showed pH-dependent permeability, with higher P(eff) at higher pH. At any given pH, sotalol showed lower permeability than metoprolol; however, the permeability of sotalol determined at pH 7.5 exceeded/matched metoprolol's at pH 6.5 and 7.0, respectively. Physicochemical analysis based on ionization, pK(a) and partitioning of these drugs predicted the same trend and clarified the mechanism behind these observed results. Experimental octanol-buffer partitioning experiments confirmed the theoretical curves. An oral dose of metoprolol has been reported to be completely absorbed in the upper small intestine; it follows, hence, that metoprolol's P(eff) value at pH 7.5 is not likely physiologically relevant for an immediate release dosage form, and the permeability at pH 6.5 represents the actual relevant value for the low/high permeability class boundary. Although sotalol's permeability is low at pH 6.5 and 7.0, at pH 7.5 it exceeds/matches the threshold of metoprolol at pH 6.5 and 7.0, most likely responsible for its high F(abs). In conclusion, we have shown that, in fact, there is no discrepancy between P(eff) and F(abs) in sotalol's absorption; the data emphasize that

  5. Remediation of arsenic-contaminated groundwater using media-injected permeable reactive barriers with a modified montmorillonite: sand tank studies.

    Science.gov (United States)

    Luo, Ximing; Liu, Haifei; Huang, Guoxin; Li, Ye; Zhao, Yan; Li, Xu

    2016-01-01

    A modified montmorillonite (MMT) was prepared using an acid activation-sodium activation-iron oxide coating method to improve the adsorption capacities of natural MMTs. For MMT, its interlamellar distance increased from 12.29 to 13.36 Å, and goethite (α-FeOOH) was intercalated into its clay layers. Two novel media-injected permeable reactive barrier (MI-PRB) configurations were proposed for removing arsenic from groundwater. Sand tank experiments were conducted to investigate the performance of the two MI-PRBs: Tank A was filled with quartz sand. Tank B was packed with quartz sand and zero-valent iron (ZVI) in series, and the MMT slurry was respectively injected into them to form reactive zones. The results showed that for tank A, total arsenic (TA) removal of 98.57% was attained within the first 60 mm and subsequently descended slowly to 88.84% at the outlet. For tank B, a similar spatial variation trend was observed in the quartz sand layer, and subsequently, TA removal increased to ≥99.80% in the ZVI layer. TA removal by MMT mainly depended on both surface adsorption and electrostatic adhesion. TA removal by ZVI mainly relied on coagulation/precipitation and adsorption during the iron corrosion. The two MI-PRBs are feasible alternatives for in situ remediation of groundwater with elevated As levels.

  6. Methane Seep in Shallow-Water Permeable Sediment Harbors High Diversity of Anaerobic Methanotrophic Communities, Elba, Italy

    Science.gov (United States)

    Ruff, S. Emil; Kuhfuss, Hanna; Wegener, Gunter; Lott, Christian; Ramette, Alban; Wiedling, Johanna; Knittel, Katrin; Weber, Miriam

    2016-01-01

    The anaerobic oxidation of methane (AOM) is a key biogeochemical process regulating methane emission from marine sediments into the hydrosphere. AOM is largely mediated by consortia of anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB), and has mainly been investigated in deep-sea sediments. Here we studied methane seepage at four spots located at 12 m water depth in coastal, organic carbon depleted permeable sands off the Island of Elba (Italy). We combined biogeochemical measurements, sequencing-based community analyses and in situ hybridization to investigate the microbial communities of this environment. Increased alkalinity, formation of free sulfide and nearly stoichiometric methane oxidation and sulfate reduction rates up to 200 nmol g-1 day-1 indicated the predominance of sulfate-coupled AOM. With up to 40 cm thickness the zones of AOM activity were unusually large and occurred in deeper sediment horizons (20–50 cm below seafloor) as compared to diffusion-dominated deep-sea seeps, which is likely caused by advective flow of pore water due to the shallow water depth and permeability of the sands. Hydrodynamic forces also may be responsible for the substantial phylogenetic and unprecedented morphological diversity of AOM consortia inhabiting these sands, including the clades ANME-1a/b, ANME-2a/b/c, ANME-3, and their partner bacteria SEEP-SRB1a and SEEP-SRB2. High microbial dispersal, the availability of diverse energy sources and high habitat heterogeneity might explain that the emission spots shared few microbial taxa, despite their physical proximity. Although the biogeochemistry of this shallow methane seep was very different to that of deep-sea seeps, their key functional taxa were very closely related, which supports the global dispersal of key taxa and underlines strong selection by methane as the predominant energy source. Mesophilic, methane-fueled ecosystems in shallow-water permeable sediments may comprise distinct

  7. Methane Seep in Shallow-Water Permeable Sediment Harbors High Diversity of Anaerobic Methanotrophic Communities, Elba, Italy.

    Science.gov (United States)

    Ruff, S Emil; Kuhfuss, Hanna; Wegener, Gunter; Lott, Christian; Ramette, Alban; Wiedling, Johanna; Knittel, Katrin; Weber, Miriam

    2016-01-01

    The anaerobic oxidation of methane (AOM) is a key biogeochemical process regulating methane emission from marine sediments into the hydrosphere. AOM is largely mediated by consortia of anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB), and has mainly been investigated in deep-sea sediments. Here we studied methane seepage at four spots located at 12 m water depth in coastal, organic carbon depleted permeable sands off the Island of Elba (Italy). We combined biogeochemical measurements, sequencing-based community analyses and in situ hybridization to investigate the microbial communities of this environment. Increased alkalinity, formation of free sulfide and nearly stoichiometric methane oxidation and sulfate reduction rates up to 200 nmol g(-1) day(-1) indicated the predominance of sulfate-coupled AOM. With up to 40 cm thickness the zones of AOM activity were unusually large and occurred in deeper sediment horizons (20-50 cm below seafloor) as compared to diffusion-dominated deep-sea seeps, which is likely caused by advective flow of pore water due to the shallow water depth and permeability of the sands. Hydrodynamic forces also may be responsible for the substantial phylogenetic and unprecedented morphological diversity of AOM consortia inhabiting these sands, including the clades ANME-1a/b, ANME-2a/b/c, ANME-3, and their partner bacteria SEEP-SRB1a and SEEP-SRB2. High microbial dispersal, the availability of diverse energy sources and high habitat heterogeneity might explain that the emission spots shared few microbial taxa, despite their physical proximity. Although the biogeochemistry of this shallow methane seep was very different to that of deep-sea seeps, their key functional taxa were very closely related, which supports the global dispersal of key taxa and underlines strong selection by methane as the predominant energy source. Mesophilic, methane-fueled ecosystems in shallow-water permeable sediments may comprise distinct

  8. Defining clogging potential for permeable concrete.

    Science.gov (United States)

    Kia, Alalea; Wong, Hong S; Cheeseman, Christopher R

    2018-08-15

    Permeable concrete is used to reduce urban flooding as it allows water to flow through normally impermeable infrastructure. It is prone to clogging by particulate matter and predicting the long-term performance of permeable concrete is challenging as there is currently no reliable means of characterising clogging potential. This paper reports on the performance of a range of laboratory-prepared and commercial permeable concretes, close packed glass spheres and aggregate particles of varying size, exposed to different clogging methods to understand this phenomena. New methods were developed to study clogging and define clogging potential. The tests involved applying flowing water containing sand and/or clay in cycles, and measuring the change in permeability. Substantial permeability reductions were observed in all samples, particularly when exposed to sand and clay simultaneously. Three methods were used to define clogging potential based on measuring the initial permeability decay, half-life cycle and number of cycles to full clogging. We show for the first time strong linear correlations between these parameters for a wide range of samples, indicating their use for service-life prediction. Copyright © 2018 Elsevier Ltd. All rights reserved.

  9. Frac sand in the United States: a geological and industry overview

    Science.gov (United States)

    Benson, Mary Ellen; Wilson, Anna B.; Bleiwas, Donald I.

    2015-01-01

    A new mineral rush is underway in the upper Midwest of the United States, especially in Wisconsin and Minnesota, for deposits of high-quality frac sand that the mining industry calls “Northern White” sand or “Ottawa” sand. Frac sand is a specialized type of sand that is added to fracking fluids that are injected into unconventional oil and gas wells during hydraulic fracturing (fracking or hydrofracking), a process that enhances petroleum extraction from tight (low permeability) reservoirs. Frac sand consists of natural sand grains with strict mineralogical and textural specifications that act as a proppant (keeping induced fractures open), extending the time of release and the flow rate of hydrocarbons from fractured rock surfaces in contact with the wellbore.

  10. Seismic Anisotropy of Soft Sands, Offshore Western AUstralia

    Science.gov (United States)

    Urosevic, M.; Gurevich, B.

    2007-05-01

    Seismic anisotropy is commonly measured in sand shale environment. Intrinsic polar anisotropy of the shale and its effect on seismic data processing and analysis is well established and reasonably well understood. In sandstone, azimuthal anisotropy is often detected and is typically connected to an in situ stress regime and the brittleness of the rock. This type of anisotropy, commonly referred to as fractured induced anisotropy, has been widely and extensively studied as it directly affects both permeability and the strength of the rock. Hence fracture induced anisotropy is not only important for hydrocarbon exploration but also for geotechnical studies, underground mining, etc. Interestingly, in the last few years azimuthal anisotropy has also been detected in soft, poorly consolidated clean sands, mainly by cross-dipole sonic log measurements. This is somewhat surprising as in such soft, typically highly porous and permeable rocks stress induced fractures are unlikely to be abundant. In this study we analyse the anisotropy in such sand class using well-log measurements, three-component VSP data, as well as 2D and 3D surface seismic (reflection) data. High-quality cross-dipole sonic log measurements showed significant shear wave splitting over unconsolidated, highly porous and permeable sand interval. The shear wave anisotropy was computed to be around 10-15%. This is commonly seen as an indication that the rock is fractured and that the fractures are likely to be open. However, image log data over the same sand section suggested dilute most likely non-conductive fractures. Analysis of the shear wave splitting in VSP data also suggested low fracture density. The frequency content of the direct fast and slow shear waves on the VSP data was very similar, not supporting the presence of open fluid saturated fractures. Unfortunately, the evidence from the VSP data is not very compelling because the reservoir is thin compared to the wavelength and sampling interval of

  11. Retorting of bituminous sands

    Energy Technology Data Exchange (ETDEWEB)

    Chaney, P E; Ince, R W; Mason, C M

    1872-09-26

    This method of recovering oil from mined tar sands involves forming compacted tar sands pieces by special conditioning treatment that provides low internal permeability. The compacted pieces are then retorted in fixed bed form. The conditioning treatment can involve rolling of preformed pellets, compaction in a mold or pressure extrusion. Substantial collapsing of the bed during retorting is avoided. (9 claims) (Abstract only - original article not available from T.U.)

  12. Methane seep in shallow-water permeable sediment harbors high diversity of anaerobic methanotrophic communities, Elba, Italy

    Directory of Open Access Journals (Sweden)

    S Emil Ruff

    2016-03-01

    Full Text Available The anaerobic oxidation of methane (AOM is a key biogeochemical process regulating methane emission from marine sediments into the hydrosphere. AOM is largely mediated by consortia of anaerobic methanotrophic archaea (ANME and sulfate-reducing bacteria (SRB, and has mainly been investigated in deep-sea sediments. Here we studied methane seepage at four spots located at 12 m water depth in coastal, organic-carbon depleted permeable sands off the Island of Elba (Italy. We combined biogeochemical measurements, sequencing-based community analyses and in situ hybridization to investigate the microbial communities of this environment. Increased alkalinity, formation of free sulfide and nearly stoichiometric methane oxidation and sulfate reduction rates up to 200 nmol g-1 day-1 indicated the predominance of sulfate-coupled AOM. With up to 40 cm thickness the zones of AOM activity were unusually large and occurred in deeper sediment horizons (20–50 cm below seafloor as compared to diffusion-dominated deep-sea seeps, which is likely caused by advective flow of pore water due to the shallow water depth and permeability of the sands. Hydrodynamic forces also may be responsible for the substantial phylogenetic and unprecedented morphological diversity of AOM consortia inhabiting these sands, including the clades ANME-1a/b, ANME-2a/b/c, ANME-3 and their partner bacteria SEEP-SRB1a and SEEP-SRB2. High microbial dispersal, the availability of diverse energy sources and high habitat heterogeneity might explain that the emission spots shared few microbial taxa, despite their physical proximity. Although the biogeochemistry of this shallow methane seep was very different to that of deep-sea seeps, their key functional taxa were very closely related, which supports the global dispersal of key taxa and underlines strong selection by methane as the predominant energy source. Mesophilic, methane-fueled ecosystems in shallow-water permeable sediments may comprise

  13. High temperature thermal energy storage in moving sand

    Science.gov (United States)

    Turner, R. H.; Awaya, H. I.

    1978-01-01

    Several high-temperature (to 500 C) heat-storage systems using sand as the storage medium are described. The advantages of sand as a storage medium include low cost for sand, widespread availability, non-toxicity, non-degradation characteristics, easy containment, and safety. The systems considered include: stationary sand with closely spaced tubes throughout the volume, the use of a fluidized bed, use of conveyor belt transporter, and the use of a blower rapid transport system. For a stationary sand bed, very close spacing of heat transfer tubes throughout the volume is required, manifesting as high power related system cost. The suggestion of moving sand past or around pipes is intended to reduce the power related costs at the penalty of added system complexity. Preliminary system cost estimates are offered. These rough calculations indicate that mobile sand heat storage systems cost less than the stationary sand approach.

  14. On the origin of calcite-cemented sandstones in the clearwater formation oil-sands, Alberta

    Energy Technology Data Exchange (ETDEWEB)

    Colquhoun, I.M.

    1999-01-01

    This thesis examined the formation of calcite-cemented sandstones in the Clearwater Formation within the Cold Lake and southern Primrose areas of the Alberta oil sands. Three stages of diagenesis have been recognized, both in the calcite-cemented sandstones and reservoir sands. Diagenesis of the Clearwater Formation in the Cold Lake and southern Primrose areas ended once the reservoir filled with hydrocarbons, but in the Cold Lake area, diagenesis of water-saturated sands likely continued after hydrocarbon emplacement. The reservoir sands in the formation contain a diverse clay mineral assemblage. In general, 0.7 nm clays dominate the diagenetic clay mineralogy of the Clearwater sands. Reservoir sands that contain large amounts of detrital clays and early diagenetic, grain-coating chlorite/smectite have significantly reduced bitumen-saturation. The presence of detrital and diagenetic smectitic clays complicates the removal of bitumen from the Clearwater formation using cyclic steam stimulation techniques because they swell during steam stimulation and reduce porosity and permeability of reservoir sands. Reservoir sands that contain kaolinite, feldspar and calcite react to form smectitic clays, which swell upon cyclic steam stimulation and further reduce porosity and permeability of reservoir sands. However, in the Cold Lake and Primrose areas, the dominant clay mineral is berthierine, which is associated with high calcite, which help to preserve porosity, permeability and bitumen saturation. The porous nature of bitumen-saturated, calcite-cemented sandstones that are laterally extensive could possibly provide a preferential path for steam to initiate calcite dissolution and produce significant concentrations of dissolved carbon dioxide in injected fluids. It was noted that this may then precipitate as carbonate scale within the reservoir and could cause formation damage or affect production equipment. 207 refs., 9 tabs., 58 figs., 3 appendices.

  15. Creating fluid injectivity in tar sands formations

    Science.gov (United States)

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  16. Electrokinetic Enhanced Permanganate Delivery for Low Permeability Soil Remediation

    Science.gov (United States)

    Chowdhury, A. I.; Gerhard, J.; Reynolds, D. A.; Sleep, B. E.; O'Carroll, D. M.

    2016-12-01

    Contaminant mass sequestered in low permeability zones (LPZ) in the subsurface has become a significant concern due to back diffusion of contaminants, leading to contaminant rebound following treatment of the high permeability strata. In-situ remediation technologies such as in-situ chemical oxidation (ISCO) are promising, however, successful delivery of oxidants into silts and clays remains a challenge. Electrokinetics (EK) has been proposed as a technique that can overcome this challenge by delivering oxidants into low permeability soils. This study demonstrates the ability of EK to facilitate permanganate delivery into silt for treatment of trichloroethene (TCE). A two-dimensional sandbox was packed with alternate vertical layers of coarse sand and silt contaminated with high concentrations of aqueous phase TCE. Nine experiments were conducted to compare EK-enhanced in-situ chemical oxidation (EK-ISCO) to ISCO alone or EK alone. Frequent groundwater sampling at multiple locations combined with image analysis provided detailed mapping of TCE, permanganate, and manganese dioxide mass distributions. EK-ISCO successfully delivered the permanganate throughout the silt cross-section while ISCO without EK resulted in permanganate delivery only to the edges of the silt layer. EK-ISCO resulted in a 4.4 order-of-magnitude (OoM) reduction in TCE concentrations in the coarse sand compared to a 3.5 OoM reduction for ISCO alone. This study suggests that electrokinetics coupled with ISCO can achieve enhanced remediation of lower permeability strata, where remediation technologies for successful contaminant mass removal would otherwise be limited.

  17. Influence of porewater advection on denitrification in carbonate sands: Evidence from repacked sediment column experiments

    DEFF Research Database (Denmark)

    Santos, Isaac R.; Eyre, Bradley D.; Glud, Ronnie N.

    2012-01-01

    Porewater flow enhances mineralization rates in organic-poor permeable sands. Here, a series of sediment column experiments were undertaken to assess the potential effect of advective porewater transport on denitrification in permeable carbonate sands collected from Heron Island (Great Barrier Re...

  18. Improving the geotechnical behavior of sand through cohesive admixtures

    Directory of Open Access Journals (Sweden)

    Mohie eldin Mohamed Afify Elmashad

    2018-04-01

    Full Text Available Irrigation projects in Egypt have been facing tremendous challenges, mostly is the scarcity of irrigation water. The current research presents the effect of different cohesive admixture on the conductivity of siliceous sand in general and its other geotechnical properties. Two different types of conventional swelling clay from (Toshka, 6th of October as well as bentonite were used to construct the irrigation canals and embankment. The results indicated that increase in the plasticity properties of the treated soil also decrease the permeability and infiltration. Moreover, the dry density of 2.08 t/m3 was obtained from sand and 20% 6th of October mixture, also the CBR of 31.20% were obtained from sand and 8% 6th of October mixture. Increasing the bentonite ratio increases the cohesion and decreasing the permeability. The swelling ratios of sand 6th of October Clay mixture is equal to 0.28%, and the fictitious stress at which the swelling ratio is nil, is equal to 16 kPa. Keywords: Sand, Swelling clay, Bentonite, Compaction test, Consolidation test, Triaxial test

  19. Geotechnical properties of oil-contaminated Kuwaiti sand

    Energy Technology Data Exchange (ETDEWEB)

    Al-Sanad, H.A.; Eid, W.K.; Ismael, N.F. [Kuwait Univ., Safat (Kuwait). Dept. of Civil Engineering

    1995-05-01

    Large quantities of oil-contaminated sands resulted from exploded oil wells, burning oil fires, the destruction of oil storage tanks, and the formation of oil lakes in Kuwait at the end of the Gulf War. An extensive laboratory testing program was carried out to determine the geotechnical characteristics of this material. Testing included basic properties, compaction and permeability tests, and triaxial and consolidation tests on clean and contaminated sand at the same relative density. Contaminated specimens were prepared by mixing the sand with oil in the amount of 6% by weight or less to match field conditions. The influence of the type of oil, and relative density was also investigated by direct shear tests. The results indicated a small reduction in strength and permeability and an increase in compressibility due to contamination. The preferred method of disposal of this material is to use it as a stabilizing material for other projects such as road construction.

  20. Geotechnical properties of oil-contaminated Kuwaiti sand

    International Nuclear Information System (INIS)

    Al-Sanad, H.A.; Eid, W.K.; Ismael, N.F.

    1995-01-01

    Large quantities of oil-contaminated sands resulted from exploded oil wells, burning oil fires, the destruction of oil storage tanks, and the formation of oil lakes in Kuwait at the end of the Gulf War. An extensive laboratory testing program was carried out to determine the geotechnical characteristics of this material. Testing included basic properties, compaction and permeability tests, and triaxial and consolidation tests on clean and contaminated sand at the same relative density. Contaminated specimens were prepared by mixing the sand with oil in the amount of 6% by weight or less to match field conditions. The influence of the type of oil, and relative density was also investigated by direct shear tests. The results indicated a small reduction in strength and permeability and an increase in compressibility due to contamination. The preferred method of disposal of this material is to use it as a stabilizing material for other projects such as road construction

  1. Intestinal permeability study of minoxidil: assessment of minoxidil as a high permeability reference drug for biopharmaceutics classification.

    Science.gov (United States)

    Ozawa, Makoto; Tsume, Yasuhiro; Zur, Moran; Dahan, Arik; Amidon, Gordon L

    2015-01-05

    The purpose of this study was to evaluate minoxidil as a high permeability reference drug for Biopharmaceutics Classification System (BCS). The permeability of minoxidil was determined in in situ intestinal perfusion studies in rodents and permeability studies across Caco-2 cell monolayers. The permeability of minoxidil was compared with that of metoprolol, an FDA reference drug for BCS classification. In rat perfusion studies, the permeability of minoxidil was somewhat higher than that of metoprolol in the jejunum, while minoxidil showed lower permeability than metoprolol in the ileum. The permeability of minoxidil was independent of intestinal segment, while the permeability of metoprolol was region-dependent. Similarly, in mouse perfusion study, the jejunal permeability of minoxidil was 2.5-fold higher than that of metoprolol. Minoxidil and metoprolol showed similar permeability in Caco-2 study at apical pH of 6.5 and basolateral pH of 7.4. The permeability of minoxidil was independent of pH, while metoprolol showed pH-dependent transport in Caco-2 study. Minoxidil exhibited similar permeability in the absorptive direction (AP-BL) in comparison with secretory direction (BL-AP), while metoprolol had higher efflux ratio (ER > 2) at apical pH of 6.5 and basolateral pH of 7.4. No concentration-dependent transport was observed for either minoxidil or metoprolol transport in Caco-2 study. Verapamil did not alter the transport of either compounds across Caco-2 cell monolayers. The permeability of minoxidil was independent of both pH and intestinal segment in intestinal perfusion studies and Caco-2 studies. Caco-2 studies also showed no involvement of carrier mediated transport in the absorption process of minoxidil. These results suggest that minoxidil may be an acceptable reference drug for BCS high permeability classification. However, minoxidil exhibited higher jejunal permeability than metoprolol and thus to use minoxidil as a reference drug would raise the

  2. Influence of Binding Rates on Strength Properties of Moulding Sands with the GEOPOL Binder

    Directory of Open Access Journals (Sweden)

    Holtzer M.

    2014-03-01

    Full Text Available The results of investigations of moulding sands with an inorganic binder called GEOPOL, developed by the SAND TEAM Company are presented in the paper. Hardeners of various hardening rates are used for moulding sands with this binder. The main aim of investigations was determination of the influence of the hardening rate of moulding sands with the GEOPOL binder on technological properties of these sands (bending strength, tensile strength, permeability and grindability. In addition, the final strength of moulding sands of the selected compositions was determined by two methods: by splitting strength and shear strength measurements. No essential influence of the hardening rate on such parameters as: permeability, grindability and final strength was found. However, the sand in which the slowest hardener (SA 72 were used, after 1 hour of holding, had the tensile and bending strength practically zero. Thus, the time needed for taking to pieces the mould made of such moulding sand will be 1.5 - 2 hours.

  3. Cement technology for borehole plugging: an interim report on permeability measurements of cementitious solids

    International Nuclear Information System (INIS)

    McDaniel, E.W.

    1980-01-01

    The permeability of borehole plug solids and plug-wall rock junctions is a property of major interest in the Borehole Plugging Program. This report describes the equipment and techniques used to determine the permeabilities of possible borehole plugging materials and presents results from tests on various cementitious solids and plug-rock combinations. The cementitious solids were made from mixtures of cement, sand, salt, fly ash, and water. Three different types of cement and four different fly ashes were used. Permeabilities ranged from a high value of 3 x 10 -4 darcy for a neat cement paste to a low of 5 x 10 -8 darcy for a saltcrete containing 30 wt % sodium chloride. Miniature boreholes were made in the following four different types of rock: Westerly granite, Dresser basalt, Sioux quartzite, and St. Cloud granodiorite. These small holes were plugged with a mix consisting of 23 wt % Type I Portland cement, 20 wt % bituminous fy ash, 43.2 wt % sand, and 13.8 wt % water. After curing for 91 days at ambient temperature, the permeability of the plug-wall rock junctions ranged from 3 x 10 -5 to -8 darcy. Three of the four miniature plugged boreholes exhibited permeabilities of < 10 microdarcys

  4. The influence of pore-water advection, benthic photosynthesis, and respiration on calcium carbonate dynamics in reef sands

    NARCIS (Netherlands)

    Rao, A.M.F.; Polerecky, L.; Ionescu, D.; Meysman, F.J.R.; de-Beer, D.

    2012-01-01

    To investigate diel calcium carbonate (CaCO3) dynamics in permeable coral reef sands, we measured pore-water profiles and fluxes of oxygen (O2), nutrients, pH, calcium (Ca2+), and alkalinity (TA) across the sediment-water interface in sands of different permeability

  5. Evaluation of the potential for reduction in well spacing of the Bakken sand pool, Court Field

    Energy Technology Data Exchange (ETDEWEB)

    Majcher, M.B.; Estrada, C.A. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Nexen Inc., Calgary, AB (Canada); Archer, J.C. [Nexen Inc., Calgary, AB (Canada)

    2005-11-01

    For the past 15 years, the Court field has produced hydrocarbons from the Mississippian/Devonian middle Bakken sandstone reservoir. The formation is located in west central Saskatchewan and was deposited in a marine shelf environment and later reworked into tidally influenced sand ridges. Vertical wells and a waterflood recovery scheme have been used to produce heavy crude with an API gravity of 17. A better understanding of the reservoir behaviour is required in order to advance field development and maintain successful waterflood management. Three-dimensional seismic and well logs were used to map the structural complexity of the sand ridge. This study examined the feasibility of using production and seismic data to update and substantiate a simulation model which was used to evaluate downspace potential. Stratigraphic disparities were taken into account as discontinuous interbedded siltstones may be flow barriers that create anisotropy in the permeability zone. Grid orientation was altered to align axially with the permeability trends of the main sand ridge. This study also reviewed an earlier field simulation and generated an updated model. The potential to reduce well spacing was then identified and waterflood optimization of the middle Bakken reservoir was evaluated. It was concluded that the edges of the sand ridge and areas isolated from existing injectors have the greatest potential for infill drilling and additional water injection because of the high sinkhole density. It was noted that drilling edge regions with high oil saturations have a risk of low permeability zones, resulting in low production rates and the possibility of an ineffective waterflood scheme. Therefore, a successful waterflood in the edge zones would require injector-producer pairs in the equivalent sand facies. 4 refs., 36 figs.

  6. Hydrogeological Characterization of Low-permeability Clayey Tills

    DEFF Research Database (Denmark)

    Kessler, Timo Christian

    The topic of this PhD thesis is an integrated investigation of sand lenses in glacial diamictons. Sand lenses indicate various deposition regimes and glaciotectonic deformation styles and are as such important features in studies of glacial sediments. In a hydrogeological framework, sand lenses......-dimensional realizations indicate clear channel networks, whereas only limited connectivity was found for the two-dimensional case. This is an important aspect because it emphasizes the need to collect data and to represent this type of heterogeneity in 3D. The physical response of sand lens heterogeneity was evaluated...... enhance the horizontal spreading of contaminants without a significant increase of the equivalent permeability in the till. Overall, sand lenses occur in all types of glacial sediments and with a broad range of shapes and hydraulic properties. Geometric characterization enabled classification of the most...

  7. Experimental Measurement of Diffusive Extinction Depth and Soil Moisture Gradients in Southwestern Saudi Arabian Dune Sand

    KAUST Repository

    Mughal, Iqra

    2013-01-01

    In arid lands, a major contribution to water loss is by soil water evaporation. Desert sand dunes in arid regions are devoid of runoff and have high rates of infiltration. Rainwater is commonly stored within them because of the low permeability

  8. Effect of manufactured sand on the durability characteristics of concrete

    Directory of Open Access Journals (Sweden)

    S. S. SARAVANAN

    2016-12-01

    Full Text Available Concrete is the most sought after material due to increase in construction activities and infrastructural developments. Availability of natural sand is decreasing thereby increase in the cost of construction. In the present work undertaken, an attempt has been made to give an alternative to natural sand. Optimization of replacement of natural sand with manufactured sand in concrete, durability studies such as water absorption, rapid chloride permeability test, sorptivity, acid resistance, alkaline resistance, impact resistance and abrasion resistance of M40 and M50 grades of concrete have been studied with manufactured sand as fine aggregate and compared the results with the conventional sand concrete. The results shows that there is an increase in the durability properties up to 70 % level of replacements of sand with manufactured sand as fine aggregate and for 100 % use of manufactured sand also gives the better durability than the conventional sand concrete.

  9. Heat-resistant agent used for control sand of steam huff and puff heavy oil well

    Science.gov (United States)

    Zhang, F. S.; Liu, G. L.; Lu, Y. J.; Xiong, X. C.; Ma, J. H.; Su, H. M.

    2018-01-01

    Heat-resistant agent containing hydroxymethyl group was synthesized from coal tar, which has similar structure with phenolic resin and could improve the heat resistance of phenolic resin sand control agent. The results showed that the heat resistance of the sand control agent was improved by adding 10% to 30% heat-resistant agent, after 280°C high temperature treatment for 7d, the compressive strength of consolidated core was increased to more than 5MPa. The compressive strength of consolidation core was not decreased after immersion in formation water, crude oil, acid or alkaline medium, which showed good resistance to medium immersion. The sand control agent had small core damage and the core permeability damage ratio of sand control agent consolidation was only 18.7%.

  10. Simulating cold production by a coupled reservoir-geomechanics model with sand erosion

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Y.; Xue, S. [Petro-Geotech Inc., Calgary, AB (Canada)

    2002-06-01

    This paper presents a newly developed fully coupled reservoir-geomechanics model with sand erosion. Sand production occurs during aggressive production induced by the impact of viscous fluid flow and the in situ stress concentration near a wellbore, as well as by perforation tips in poorly consolidated formations. This compromises oil production, increases well completion costs, and reduces the life cycles of equipment down hole and on the surface. The proposed model can be used for sand production studies in conventional oil/gas reservoirs such as the North Sea as well as in heavy oil reservoirs such as in northwestern Canada. Instead of generating a high permeability network in reservoirs, the enhanced oil production is determined by the increase in the effective wellbore radius. This paper presents the general model. A detailed study on the capillary pressure and the impact of multiphase flow on sanding and erosion will be conducted at a later date. It appears that 2 phase flow can be important to elastoplasticity if no significant sand erosion has occurred. It was determined that high porosity is induced by erosion and capillary pressure. Two phase flow can be important when the built-up drag force carries sand-fluid slurry into the well. It is concluded that viscosity and flow velocity can help estimate the slurry transport, sand rate and enhanced oil production. 22 refs., 3 tabs., 11 figs.

  11. Study on HDPE Mixed with Sand as Backfilled Material on Retaining Structure

    Science.gov (United States)

    Talib, Z. A.

    2018-04-01

    The failure of the retaining wall is closely related to backfill material. Granular soils such as sand and gravel are most suitable backfill material because of its drainage properties. However two basic materials are quite heavy and contribute high amount of lateral loads. This study was to determine the effectiveness High Density Polyethylene (HDPE) as a backfill material. HDPE has a lighter weight compare to the sand. It makes HDPE has potential to be used as backfill material. The objective of this study is to identify the most effective percentage of HDPE to replace sand as a backfill material. The percentage of HDPE used in this study was 20%, 30%, 50%, 75% and also 100%. Testing involved in this study were sieve analysis test, constant head permeability test, direct shear test and relative density test. The result shows that the HDPE can be used as backfilled material and save the cost of backfill material

  12. The fraction dose absorbed, in humans, and high jejunal human permeability relationship.

    Science.gov (United States)

    Dahan, Arik; Lennernäs, Hans; Amidon, Gordon L

    2012-06-04

    The drug intestinal permeability (P(eff)) measure has been widely used as one of the main factors governing both the rate and/or extent of drug absorption (F(abs)) in humans following oral administration. In this communication we emphasize the complexity behind and the care that must be taken with this in vivo P(eff) measurement. Intestinal permeability, considering the whole of the human intestine, is more complex than generally recognized, and this can lead to misjudgment regarding F(abs) and P(eff) in various settings, e.g. drug discovery, formulation design, drug development and regulation. Setting the adequate standard for the low/high permeability class boundary, the different experimental methods for the permeability measurement, and segmental-dependent permeability throughout the human intestine due to different mechanisms are some of the main points that are discussed. Overall, the use of jejunal P(eff) as a surrogate for extent of absorption is sound and scientifically justified; a compound with high jejunal P(eff) will have high F(abs), eliminating the risk for misclassification as a BCS class I drug. Much more care should be taken, however, when jejunal P(eff) does not support a high-permeability classification; a thorough examination may reveal high-permeability after all, attributable to e.g. segmental-dependent permeability due to degree of ionization or transporter expression. In this situation, the use of multiple permeability experimental methods, including the use of metabolism, which except for luminal degradation requires absorption, is prudent and encouraged.

  13. Gravel Mobility in a High Sand Content Riverbed

    Science.gov (United States)

    Haschenburger, J. K.

    2017-12-01

    In sand-gravel channels, sand may modify gravel transport by changing conditions of entrainment and promoting longer displacements or gravel may inhibit sand transport if concentrated into distinct deposits, which restrict sand supply with consequences for migrating bedform size or form. This study reports on gravel mobility in the lower San Antonio River, Texas, where gravel content in the bed material ranges from about 1% to more than 20%. Sediment transport observations were collected at three U.S. Geological Survey gauging stations by deploying a Helley-Smith sampler with a 0.2 mm mesh bag from which transport rates and mobile grain sizes were determined. The flow rates sampled translate into an annual exceedance expectation from 0.2% to 98%. Gravel transport rates are generally two orders of magnitude smaller than the rates of sand transport. However, the finest gravels are transported at rates on the same order of magnitude as the coarsest sands. At all sites, the 2 and 2.8 mm fractions are transported at the lowest flow rate sampled, suggesting mobility for at least 38% to as much as 98% of the year. Fractions as large as 8 mm are mobilized at flow rates that are expected between 25% and 53% of the year. The largest fractions captured in the sampling (16 to 32 mm) require flows closer to bankfull conditions that occur no more than 0.8% of the year. Results document that some gravel sizes can be frequently transported in low gradient riverbeds with high sand content.

  14. Transverse Chemotactic Migration of Bacteria from High to Low Permeability Regions in a Dual Permeability Porous Microfluidic Device

    Science.gov (United States)

    Singh, R.; Olson, M. S.

    2011-12-01

    Low permeability regions sandwiched between high permeability regions such as clay lenses are difficult to treat using conventional treatment methods. Trace concentrations of contaminants such as non-aqueous phase liquids (NAPLs) remain trapped in these regions and over the time diffuse out into surrounding water thereby acting as a long term source of groundwater contamination. Bacterial chemotaxis (directed migration toward a contaminant source), may be helpful in enhancing bioremediation of such contaminated sites. This study is focused on simulating a two-dimensional dual-permeability groundwater contamination scenario using microfluidic devices and evaluating transverse chemotactic migration of bacteria from high to low permeability regions. A novel bi-layer polydimethylsiloxane (PDMS) microfluidic device was fabricated using photolithography and soft lithography techniques to simulate contamination of a dual- permeability region due to leakage from an underground storage tank into a low permeability region. This device consists of a porous channel through which a bacterial suspension (Escherchia Coli HCB33) is flown and another channel for injecting contaminant/chemo-attractant (DL-aspertic acid) into the porous channel. The pore arrangement in the porous channel contains a 2-D low permeability region surrounded by high permeability regions on both sides. Experiments were performed under chemotactic and non-chemotactic (replacing attractant with buffer solution in the non porous channel) conditions. Images were captured in transverse pore throats at cross-sections 4.9, 9.8, and 19.6 mm downstream from the attractant injection point and bacteria were enumerated in the middle of each pore throat. Bacterial chemotaxis was quantified in terms of the change in relative bacterial counts in each pore throat at cross-sections 9.8 and 19.6 mm with respect to counts at the cross-section at 4.9 mm. Under non-chemotactic conditions, relative bacterial count was observed

  15. Re-usage of waste foundry sand in high-strength concrete.

    Science.gov (United States)

    Guney, Yucel; Sari, Yasin Dursun; Yalcin, Muhsin; Tuncan, Ahmet; Donmez, Senayi

    2010-01-01

    In this study, the potential re-use of waste foundry sand in high-strength concrete production was investigated. The natural fine sand is replaced with waste foundry sand (0%, 5%, 10%, and 15%). The findings from a series of test program has shown reduction in compressive and tensile strengths, and the elasticity modulus which is directly related to waste foundry inclusion in concrete. Nevertheless the concrete with 10% waste foundry sand exhibits almost similar results to that of the control one. The slump and the workability of the fresh concrete decreases with the increase of the waste foundry sand ratio. Although the freezing and thawing significantly reduces the mechanical and physical properties of the concrete. The obtained results satisfies the acceptable limits set by the American Concrete Institute (ACI). 2010 Elsevier Ltd. All rights reserved.

  16. Colloid transport in dual-permeability media

    Science.gov (United States)

    Leij, Feike J.; Bradford, Scott A.

    2013-07-01

    It has been widely reported that colloids can travel faster and over longer distances in natural structured porous media than in uniform structureless media used in laboratory studies. The presence of preferential pathways for colloids in the subsurface environment is of concern because of the increased risks for disease caused by microorganisms and colloid-associated contaminants. This study presents a model for colloid transport in dual-permeability media that includes reversible and irreversible retention of colloids and first-order exchange between the aqueous phases of the two regions. The model may also be used to describe transport of other reactive solutes in dual-permeability media. Analytical solutions for colloid concentrations in aqueous and solid phases were obtained using Laplace transformation and matrix decomposition. The solutions proved convenient to assess the effect of model parameters on the colloid distribution. The analytical model was used to describe effluent concentrations for a bromide tracer and 3.2- or 1-μm-colloids that were observed after transport through a composite 10-cm long porous medium made up of a cylindrical lens or core of sand and a surrounding matrix with sand of a different grain size. The tracer data were described very well and realistic estimates were obtained for the pore-water velocity in the two flow domains. An accurate description was also achieved for most colloid breakthrough curves. Dispersivity and retention parameters were typically greater for the larger 3.2-μm-colloids while both reversible and irreversible retention rates tended to be higher for the finer sands than the coarser sand. The relatively small sample size and the complex flow pattern in the composite medium made it difficult to reach definitive conclusions regarding transport parameters for colloid transport.

  17. In situ recovery of oil from Utah tar sand: a summary of tar sand research at the Laramie Energy Technology Center

    Energy Technology Data Exchange (ETDEWEB)

    Marchant, L.C.; Westhoff, J.D.

    1985-10-01

    This report describes work done by the United States Department of Energy's Laramie Energy Technology Center from 1971 through 1982 to develop technology for future recovery of oil from US tar sands. Work was concentrated on major US tar sand deposits that are found in Utah. Major objectives of the program were as follows: determine the feasibility of in situ recovery methods applied to tar sand deposits; and establish a system for classifying tar sand deposits relative to those characteristics that would affect the design and operation of various in situ recovery processes. Contents of this report include: (1) characterization of Utah tar sand; (2) laboratory extraction studies relative to Utah tar sand in situ methods; (3) geological site evaluation; (4) environmental assessments and water availability; (5) reverse combustion field experiment, TS-1C; (6) a reverse combustion followed by forward combustion field experiment, TS-2C; (7) tar sand permeability enhancement studies; (8) two-well steam injection experiment; (9) in situ steam-flood experiment, TS-1S; (10) design of a tar sand field experiment for air-stream co-injection, TS-4; (11) wastewater treatment and oil analyses; (12) economic evaluation of an in situ tar sand recovery process; and (13) appendix I (extraction studies involving Utah tar sands, surface methods). 70 figs., 68 tabs.

  18. Effective High-Frequency Permeability of Compacted Metal Powders

    Science.gov (United States)

    Volkovskaya, I. I.; Semenov, V. E.; Rybakov, K. I.

    2018-03-01

    We propose a model for determination of the effective complex permeability of compacted metal-powder media. It is based on the equality of the magnetic moment in a given volume of the media with the desired effective permeability to the total magnetic moment of metal particles in the external high-frequency magnetic field, which arises due to excitation of electric eddy currents in the particles. Calculations within the framework of the proposed model allow us to refine the values of the real and imaginary components of the permeability of metal powder compacts in the microwave band. The conditions of applicability of the proposed model are formulated, and their fulfillment is verified for metal powder compacts in the microwave and millimeter wavelength bands.

  19. Treatment for cracked and permeable Houston clay

    International Nuclear Information System (INIS)

    Vipulanandan, C.; Leung, M.

    1991-01-01

    In this study, the treatability of a field clay (obtained from Houston, Texas) and a clay-sand mixture to reduce their hydraulic conductivity was evaluated. Remolded field clay and clay-sand mixture with and without methanol contamination were treated to reduce their hydraulic conductivity by permeating very dilute grout solutions. The concentration of sodium silicate in the grout solution was 8%, while the solid content in the cement grout was 0.3%. The hydraulic conductivity of permeable Houston clay (hydraulic conductivity >10 -5 cm/sec) could be reduced to less than 10 -7 cm/sec (U.S. EPA limit for soil barriers) by permeating with a selected combination of grout solutions

  20. Effect of Crushed Sandstone Sand on the Properties of High ...

    African Journals Online (AJOL)

    This paper presents results of the laboratory investigation on high performance concrete (HPC) using crushed sandstone sand as 20%, 40%, and 60% replacement of river sand together with superplastisizer and silica fume (SF). The fresh concrete properties such as slump, air content and fresh concrete density have been ...

  1. Effect of dissolved oxygen manipulation on diffusive emissions from NAPL-impacted low permeability soil layers.

    Science.gov (United States)

    Clifton, Lisa M; Dahlen, Paul R; Johnson, Paul C

    2014-05-06

    Aquifer physical model experiments were performed to investigate if diffusive emissions from nonaqueous phase liquid (NAPL)-impacted low-permeability layers into groundwater moving through adjacent NAPL-free high-permeability layers can be reduced by creating an aerobic biotreatment zone at the interface between the two, and if over time that leads to reduced emissions after treatment ceases. Experiments were performed in two 1.2-m long × 1.2-m high × 5.4 cm wide stainless steel tanks; each with a high-permeability sand layer overlying a low-permeability crushed granite layer containing a NAPL mixture of indane and benzene. Each tank was water-saturated with horizontal flow primarily through the sand layer. The influent water was initially deoxygenated and the emissions and concentration distributions were allowed to reach near-steady conditions. The influent dissolved oxygen (DO) level was increased stepwise to 6.5-8.5 mg/L and 17-20 mg/L, and then decreased back to deoxygenated conditions. Each condition was maintained for at least 45 days. Relative to the near-steady benzene emission at the initial deoxygenated condition, the emission was reduced by about 70% when the DO was 6.5-8.5 mg/L, 90% when the DO was 17-20 mg/L, and ultimately 60% when returning to low DO conditions. While the reductions were substantial during treatment, longer-term reductions after 120 d of elevated DO treatment, relative to an untreated condition predicted by theory, were low: 29% and 6% in Tank 1 and Tank 2, respectively. Results show a 1-2 month lag between the end of DO delivery and rebound to the final near-steady emissions level. This observation has implications for post-treatment performance monitoring sampling at field sites.

  2. Discrete element modeling of cemented sand and particle crushing at high pressures

    OpenAIRE

    de Bono, John Patrick

    2013-01-01

    This project aims to provide an insight into the behaviour of cemented sand under high pressures, and to further the understanding of the role of particle crushing. The discrete element method is used to investigate the micro mechanics of sand and cemented sand in high-pressure triaxial tests and one-dimensional normal compression. Using the software PFC3D, a new triaxial model has been developed, which features an effective flexible membrane that allows free deformation of the specimen ...

  3. EXPERIMENTAL DETERMINATION OF VARIABILITY IN PERMEABILITY OF SANDY SILT SOIL MIXED WITH FLY ASH IN PROPORTIONATE

    OpenAIRE

    Rasna Sharma*, Dr. M.K. Trivedi

    2016-01-01

    This paper presents the experimental determination of variability in permeability of sandy silt soil by blending with fly ash. The grain size, porosity, structure of the soil, specific gravity of the soil, viscosity and temperature are important factors in varying the permeability of the soil. Permeability is the flow conduction property of the soil. The void ratio with in the soil plays a vital role in varying the permeability. By blending with finer grains like fly ash in the soil with sand...

  4. Western Gas Sands Project: stratigrapy of the Piceance Basin

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, S. (comp.)

    1980-08-01

    The Western Gas Sands Project Core Program was initiated by US DOE to investigate various low permeability, gas bearing sandstones. Research to gain a better geological understanding of these sandstones and improve evaluation and stimulation techniques is being conducted. Tight gas sands are located in several mid-continent and western basins. This report deals with the Piceance Basin in northwestern Colorado. This discussion is an attempt to provide a general overview of the Piceance Basin stratigraphy and to be a useful reference of stratigraphic units and accompanying descriptions.

  5. Effect of injection water quality on permeability of productive sands in Shaimsk group of oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Andreeva, N I; Ivanov, V N; Lazarev, V N; Maksimov, V P

    1966-01-01

    Water from the Kond River is used to flood Shaimsk oil fields. Effect of raw and filtered waters on permeability of Shaimsk cores was experimentally determined. The raw river water contained 26 mg/liter of suspended solids, 10.7 mg/liter of total iron, 4.3 mg/liter of suspended iron oxide, and a pH of 6.4. The filtered river water was free of suspended solids and had a pH of 6.2. It was found that both raw and filtered water decreased core permeability. The unfiltered water decreased permeability 2 to 7 times more than the filtered water. Also, the decrease in permeability occurs much more slowly with the filtered than the unfiltered water. The effect of water on core permeability is essentially irreversible. Efforts to restore core permeability by reversing flow direction were not successful. Among the reasons for the permeability decrease were hydration and swelling of clays and evolution of gases from water in the cores. (10 refs.)

  6. ANN modelling for the determination of moulding sand matrix grain size

    Directory of Open Access Journals (Sweden)

    J. Jakubski

    2011-10-01

    Full Text Available One of the modern methods of the production optimisation are artificial neural networks. Neural networks are gaining broader and broader application in the foundry industry, among others for controlling melting processes in cupolas and in arc furnaces, for designing castings and supply systems, for controlling moulding sand processing, for predicting properties of cast alloys or selecting parameters of pressure castings. An attempt to apply neural networks for controlling the quality of bentonite moulding sands is presented in this paper. This is the assessment method of sands suitability by means of detecting correlations between their individual parameters. The presented investigations were obtained by using the Statistica 9.0 program. The aim of the investigations was to select the neural network suitable for prediction the moulding sand matrix grain size on the basis of the determined sand properties such as: permeability, compactibility, and compressive strength.

  7. Microbially induced carbonate precipitation (MICP) by denitrification as ground improvement method - Process control in sand column experiments

    Science.gov (United States)

    Pham, Vinh; van Paassen, Leon; Nakano, Akiko; Kanayama, Motohei; Heimovaara, Timo

    2013-04-01

    Calcite precipitation induced by microbes has been proven to be efficient in stabilizing granular soils, especially with urea hydrolysis, as it has been successfully demonstrated in a pilot application 2010. However, as a byproduct highly concentrated ammonium chloride (NH4Cl) solution is produced, which has to be removed and disposed and forms a significant disadvantage of the technique that makes an alternative process like denitrification preferred. The proof of principle of microbially induced calcite precipitation (MICP) by denitrification has been demonstrated by Van Paassen et al (2010) who suggested that instead of producing waste as a byproduct, different pre-treated waste streams could be used as substrates for in situ growth of denitrifying bacteria and simultaneous cementation without producing waste to be removed. In this study sand column experiments are performed in which calcium carbonate was successfully precipitated by indigenous denitrifying micro-organisms, which were supplied weekly with a pulse of a substrate solution containing calcium acetate and calcium nitrate. Besides the production of calcite and the growth of bacteria in biofilms, the reduction of nitrate resulted in the production of (nitrogen) gas. It was observed that this gas partly fills up the pore space and consequently contributed to a reduction of the permeability of the treated sand. The presence of gas in the pore space affected the flow of the injected substrates and influenced to the distribution of calcium carbonate. The effect of the mean particle size (D50) on the flow and transport of solutes and gas in the porous media has been evaluated by treating several columns with varying grain size distribution and comparing the change in permeability after each incubation period and analyzing the distribution of the gas throughout the columns using X-ray computed tomography (CT) scanning. The present results show that there is a considerable decrease of permeability - a

  8. Internal architecture, permeability structure, and hydrologic significance of contrasting fault-zone types

    Science.gov (United States)

    Rawling, Geoffrey C.; Goodwin, Laurel B.; Wilson, John L.

    2001-01-01

    The Sand Hill fault is a steeply dipping, large-displacement normal fault that cuts poorly lithified Tertiary sediments of the Albuquerque basin, New Mexico, United States. The fault zone does not contain macroscopic fractures; the basic structural element is the deformation band. The fault core is composed of foliated clay flanked by structurally and lithologically heterogeneous mixed zones, in turn flanked by damage zones. Structures present within these fault-zone architectural elements are different from those in brittle faults formed in lithified sedimentary and crystalline rocks that do contain fractures. These differences are reflected in the permeability structure of the Sand Hill fault. Equivalent permeability calculations indicate that large-displacement faults in poorly lithified sediments have little potential to act as vertical-flow conduits and have a much greater effect on horizontal flow than faults with fractures.

  9. Western Gas Sands Project. Status report, 1 January 1979--31 January 1979

    Energy Technology Data Exchange (ETDEWEB)

    Atkinson, C H

    1979-01-01

    Aim is to increase gas production from the low-permeability gas sands of the western U.S. Progress is reported on: project management, resource assessment, R and D at various facilities, and field tests and demonstrations. (DLC)

  10. The low/high BCS permeability class boundary: physicochemical comparison of metoprolol and labetalol.

    Science.gov (United States)

    Zur, Moran; Gasparini, Marisa; Wolk, Omri; Amidon, Gordon L; Dahan, Arik

    2014-05-05

    Although recognized as overly conservative, metoprolol is currently the common low/high BCS permeability class boundary reference compound, while labetalol was suggested as a potential alternative. The purpose of this study was to identify the various characteristics that the optimal marker should exhibit, and to investigate the suitability of labetalol as the permeability class reference drug. Labetalol's BCS solubility class was determined, and its physicochemical properties and intestinal permeability were thoroughly investigated, both in vitro and in vivo in rats, considering the complexity of the whole of the small intestine. Labetalol was found to be unequivocally a high-solubility compound. In the pH range throughout the small intestine (6.5-7.5), labetalol exhibited pH-dependent permeability, with higher permeability at higher pH values. While in vitro octanol-buffer partitioning (Log D) values of labetalol were significantly higher than those of metoprolol, the opposite was evident in the in vitro PAMPA permeability assay. The results of the in vivo perfusion studies in rats lay between the two contradictory in vitro studies; metoprolol was shown to have moderately higher rat intestinal permeability than labetalol. Theoretical distribution of the ionic species of the drugs was in corroboration with the experimental in vitro and the in vivo data. We propose three characteristics that the optimal permeability class reference drug should exhibit: (1) fraction dose absorbed in the range of 90%; (2) the optimal marker drug should be absorbed largely via passive transcellular permeability, with no/negligible carrier-mediated active intestinal transport (influx or efflux); and (3) the optimal marker drug should preferably be nonionizable. The data presented in this paper demonstrate that neither metoprolol nor labetalol can be regarded as optimal low/high-permeability class boundary standard. While metoprolol is too conservative due to its complete absorption

  11. Permeability of highly compacted bentonite

    International Nuclear Information System (INIS)

    Pusch, R.

    1980-12-01

    The object of the study was the water flow through the bentonite which is caused by hydraulic gradients. The study comprised laboratory tests and theoretical considerations. It was found that high bulk densities reduced the permeability to very low values. It was concluded that practically impervious conditions prevail when the gradients are low. Thus with a regional gradient of 10 -2 and a premeability of 10 -13 m/s the flow rate will not be higher than approximately 1 mm in 30 000 years. (G.B.)

  12. Experimental investigation on high performance RC column with manufactured sand and silica fume

    Science.gov (United States)

    Shanmuga Priya, T.

    2017-11-01

    In recent years, the use High Performance Concrete (HPC) has increased in construction industry. The ingredients of HPC depend on the availability and characteristics of suitable alternative materials. Those alternative materials are silica fume and manufactured sand, a by products from ferro silicon and quarry industries respectively. HPC made with silica fume as partial replacement of cement and manufactured sand as replacement of natural sand is considered as sustainable high performance concrete. In this present study the concrete was designed to get target strength of 60 MPa as per guide lines given by ACI 211- 4R (2008). The laboratory study was carried out experimentally to analyse the axial behavior of reinforced cement HPC column of size 100×100×1000mm and square in cross section. 10% of silica fume was preferred over ordinary portland cement. The natural sand was replaced by 0, 20, 40, 60, 80 and 100% with Manufactured Sand (M-Sand). In this investigation, totally 6 column specimens were cast for mixes M1 to M6 and were tested in 1000kN loading frame at 28 days. From this, Load-Mid height deflection curves were drawn and compared. Maximum ultimate load carrying capacity and the least deflection is obtained for the mix prepared by partial replacement of cement with 10% silica fume & natural sand by 100% M-Sand. The fine, amorphous and pozzalonic nature of silica fume and fine mineral particles in M- Sand increased the stiffness of HPC column. The test results revealed that HPC can be produced by using M-Sand with silica fume.

  13. Clinical research on high oxygen permeable contact lens used after photorefractive keratectomy surgery

    Directory of Open Access Journals (Sweden)

    Hao-Jiang Yang

    2013-07-01

    Full Text Available AIM: To evaluate the outcome of high oxygen permeable contact lens used after photorefractive keratectomy(PRKsurgery.METHODS: Totally 95 patients(190 eyesafter PRK were included. Patients were randomly assigned to wear high oxygen permeable contact lens in one eye and normal lens in the fellow eye after surgery. The subjective symptoms and corneal epithelial status after PRK were evaluated. Uncorrected visual acuity(UCVAand haze were assessed at 6 months after PRK.RESULTS: Complaints of blurred vision, pain and photophobia were statistically more among the normal lens group than high oxygen permeable contact lens group(PPP=0.35. There was no difference in UCVA and haze 6 months after surgery(P=0.55. CONCLUSION: High oxygen permeable contact lens can significantly produce less the corneal irritated symptoms, reduce the discomfort feeling and promote healing of corneal epithelium after PRK.

  14. Experimental Measurement of Diffusive Extinction Depth and Soil Moisture Gradients in Southwestern Saudi Arabian Dune Sand

    KAUST Repository

    Mughal, Iqra

    2013-05-01

    In arid lands, a major contribution to water loss is by soil water evaporation. Desert sand dunes in arid regions are devoid of runoff and have high rates of infiltration. Rainwater is commonly stored within them because of the low permeability soils in the underlying desert pavement. In such cases, moisture is confined in the sand dune below a depth, termed as the “extinction depth”, where it is protected from evaporation during long dry periods. Moreover, desert sand dunes have sparse vegetation, which results in low transpiration losses from the stored water. The water accumulated below the extinction depth of the sand dunes can be utilized for various purposes such as in irrigation to support desert agriculture. In this study, field experiments were conducted in Western Saudi Arabia to monitor the soil moisture gradients and determine the diffusive extinction depth of dune sand. The dune sand was saturated with water and was exposed to natural conditions (evaporation and precipitation). The decline of the water level in the sand column was continuously recorded using transducers and sensors installed at different depths monitored the temporal variation of temperature and moisture content within the sand. The hydrological simulator HYDRUS-1D was used to construct the vertical profiles of soil water content and temperature and the results obtained from HYDRUS-1D were compared to the gradients monitored by the sensors.

  15. Influence of the Reclaim Addition on Properties of Moulding Sands with the Geopol Binder

    Directory of Open Access Journals (Sweden)

    Drożyński D.

    2015-03-01

    Full Text Available The investigation results of the influence of the reclaim additions on the properties of moulding sands with the GEOPOL geopolymer binder developed by the SAND TEAM Company were presented. Two brands of hardeners were applied in the tested compositions, the first one was developed by the SAND TEAM Company, marked SA72 and the new hardener offered by the KRATOS Company, marked KR72. The main purpose of investigations was to determine the influence of reclaim fractions and the applied hardener on the basic moulding sands properties, such as: bending and tensile strength, permeability and grindability. The unfavourable influence of the reclaim additions into moulding sands on the tested properties as well as an increased hardening rate, were found. Moulding sands, in which the hardener KR72 of the KRATOS Company was used, were less sensitive to the reclaim additions

  16. Investigation on the Permeability Evolution of Gypsum Interlayer Under High Temperature and Triaxial Pressure

    Science.gov (United States)

    Tao, Meng; Yechao, You; Jie, Chen; Yaoqing, Hu

    2017-08-01

    The permeability of the surrounding rock is a critical parameter for the designing and assessment of radioactive waste disposal repositories in the rock salt. Generally, in the locations that are chosen for radioactive waste storage, the bedded rock salt is a sedimentary rock that contains NaCl and Na2SO4. Most likely, there are also layers of gypsum ( {CaSO}_{ 4} \\cdot 2 {H}_{ 2} {O)} present in the salt deposit. Radioactive wastes emit a large amount of heat and hydrogen during the process of disposal, which may result in thermal damage of the surrounding rocks and cause a great change in their permeability and tightness. Therefore, it is necessary to investigate the permeability evolution of the gypsum interlayer under high temperature and high pressure in order to evaluate the tightness and security of the nuclear waste repositories in bedded rock salt. In this study, a self-designed rock triaxial testing system by which high temperature and pressure can be applied is used; the μCT225kVFCB micro-CT system is also employed to investigate the permeability and microstructure of gypsum specimens under a constant hydrostatic pressure of 25 MPa, an increasing temperature (ranging from 20 to 650 °C), and a variable inlet gas pressure (1, 2, 4, 6 MPa). The experimental results show: (a) the maximum permeability measured during the whole experiment is less than 10-17 m2, which indicates that the gypsum interlayer has low permeability under high temperature and pressure that meet the requirements for radioactive waste repository. (b) Under the same temperature, the permeability of the gypsum specimen decreases at the beginning and then increases as the pore pressure elevates. When the inlet gas pressure is between 0 and 2 MPa, the Klinkenberg effect is very pronounced. Then, as the pore pressure increases, the movement behavior of gas molecules gradually changes from free motion to forced directional motion. So the role of free movement of gas molecules gradually

  17. Quantifying denitrification in rippled permeable sands through combined flume experiments and modeling

    DEFF Research Database (Denmark)

    Kessler, Adam J.; Glud, Ronnie N.; Cardenas, M. Bayani

    2012-01-01

    We measured denitrification in permeable sediments in a sealed flume tank with environmentally representative fluid flow and solute transport behavior using novel measurements. Numerical flow and reactive transport models representing the flume experiments were implemented to provide mechanistic...... insight into the coupled hydrodynamic and biogeochemical processes. There was broad agreement between the model results and experimental data. The model showed that the coupling between nitrification and denitrification was relatively weak in comparison to that in cohesive sediments. This was due...... of permeable sediments with nonmigratory ripples to remove bioavailable nitrogen from coastal ecosystems is lower than that of cohesive sediments. We conclude that while experimental measurements provide a good starting point for constraining key parameters, reactive transport models with realistic kinetic...

  18. Dosimetric properties of commercial glasses and sand for high doses

    International Nuclear Information System (INIS)

    Teixeira, Maria Ines

    2004-01-01

    Commercial glasses (transparent and colored) produced by Cebrace, Brazil, Sao Paulo, and sand samples of different Brazilian beaches were studied, due to their low cost and easy handling, to verify the possibility of their use in high dose dosimetry. The main dosimetric characteristics were determined using a densitometer, a spectrophotometer, a thermoluminescent (TL) reader and an electronic paramagnetic resonance system. The gamma irradiations were carried out using a Gamma-Cell 220 and a panoramic source ( 60 Co) of IPEN. An optical absorption band was observed at 420 nm in the glass samples. The TL glow curves presented peaks at 205 deg C, 135 deg C, 150 deg C and 145 deg C for the transparent, bronze, brown and green glass samples, respectively. All EPR spectra of the glasses showed Fe 3+ characteristic signals at g = 4.27 and 2.01. The gamma irradiated sand samples presented two peaks at 110 deg C and 170 deg C and an EPR signal at g= 1.999. However, these materials present a pronounced thermal fading at room temperature after irradiation. With the objective to minimize this thermal fading, both glass and sand samples were submitted to different pre- and post-irradiation thermal treatments. The glass and sand samples showed the possibility of utilization for high dose dosimetry and as Yes/No irradiation detectors. (author)

  19. Methane hydrate induced permeability modification for multiphase flow in unsaturated porous media

    Science.gov (United States)

    Seol, Yongkoo; Kneafsey, Timothy J.

    2011-08-01

    An experimental study was performed using X-ray computed tomography (CT) scanning to capture three-dimensional (3-D) methane hydrate distributions and potential discrete flow pathways in a sand pack sample. A numerical study was also performed to develop and analyze empirical relations that describe the impacts of hydrate accumulation habits within pore space (e.g., pore filling or grain cementing) on multiphase fluid migration. In the experimental study, water was injected into a hydrate-bearing sand sample that was monitored using an X-ray CT scanner. The CT images were converted into numerical grid elements, providing intrinsic sample data including porosity and phase saturations. The impacts of hydrate accumulation were examined by adapting empirical relations into the flow simulations as additional relations governing the evolution of absolute permeability of hydrate bearing sediment with hydrate deposition. The impacts of pore space hydrate accumulation habits on fluid migration were examined by comparing numerical predictions with experimentally measured water saturation distributions and breakthrough curves. A model case with 3-D heterogeneous initial conditions (hydrate saturation, porosity, and water saturation) and pore body-preferred hydrate accumulations best captured water migration behavior through the hydrate-bearing sample observed in the experiment. In the best matching model, absolute permeability in the hydrate bearing sample does not decrease significantly with increasing hydrate saturation until hydrate saturation reaches about 40%, after which it drops rapidly, and complete blockage of flow through the sample can occur as hydrate accumulations approach 70%. The result highlights the importance of permeability modification due to hydrate accumulation habits when predicting multiphase flow through high-saturation, reservoir quality hydrate-bearing sediments.

  20. Effects of Moisture Content on the Foundry Properties of Yola Natural Sand

    Directory of Open Access Journals (Sweden)

    Paul Aondona IHOM

    2012-08-01

    Full Text Available The effect of moisture content of Yola natural sand has been studied. The moisture content was varied from 1 to 9%. The effect of the moisture content on the green compression strength, green permeability and bulk density was investigated. Particle size distribution of the natural sand, the grain fineness number, average grain size, grain shape and the clay content of the natural sand were also studied. 5% moisture gave the optimum green compression strength of 118.6KN/m2. The dry compression strength increased with moisture content, an optimum value of 4000KN/m2 was obtained at 9% moisture. The Yola natural sand had a grain fineness number of 88.05AFS, average grain size of 335.78 microns and a clay content of 26%. A sand mixture containing 5% moisture was prepared and used to produce a test casting with aluminium scraps, the test casting was sound.

  1. Sand Transport under Highly Turbulent Airflow on a Beach Surface

    Science.gov (United States)

    Baas, A. C. W.; Jackson, D. W. T.; Cooper, J. A. G.; Lynch, K.; Delgado-Fernandez, I.; Beyers, J. H. M.

    2012-04-01

    The past decade has seen a growing body of research on the relation between turbulence in the wind and the resultant transport of sediment over active sand surfaces. Widespread use of sonic anemometry and high-frequency sand transport sensors and traps have facilitated recent field studies over dunes and beach surfaces, to move beyond monitoring of mean wind speed and bulk transport to more detailed measurements at much higher spatio-temporal resolutions. In this paper we present results of a field study conducted in the recirculation flow and re-attachment zone on a beach behind a foredune at Magilligan Strand, Northern Ireland. The offshore winds over the foredune at this site are associated with flow separation and reversal located over the beach surface in the lee of the dune row, often strong enough to induce sand transport toward the toe of the foredune ('against' the overall offshore flow). The re-attachment and recirculation zone are associated with strongly turbulent fluid flow and complex streamlines that do not follow the underlying topography. High frequency (25 Hz) wind and sand transport data were collected at a grid of point locations distributed over the beach surface between 35 m to 55 m distance from the 10 m high dune crest, using ultrasonic anemometers at 0.5 m height and co-located load cell traps and Safires at the bed surface. The wind data are used to investigate the role of Reynolds shear stresses and quadrant analysis techniques for identifying burst-sweep events in relation to sand transport events. This includes an assessment of the issues involved with data rotations for yaw, pitch, and roll corrections relative to complex flow streamlines, and the subsequently derived turbulence parameters based on fluctuating vector components (u', v', w'). Results illustrate how transport may exist under threshold mean velocities because of the role played by coherent flow structures, and the findings corroborate previous findings that shear velocity

  2. Polybenzimidazole-based mixed membranes with exceptional high water vapor permeability and selectivity

    KAUST Repository

    Akhtar, Faheem Hassan

    2017-09-13

    Polybenzimidazole (PBI), a thermal and chemically stable polymer, is commonly used to fabricate membranes for applications like hydrogen recovery at temperatures of more than 300 °C, fuel cells working in a highly acidic environment, and nanofiltration in aggressive solvents. This report shows for the first time use of PBI dense membranes for water vapor/gas separation applications. They showed an excellent selectivity and high water vapor permeability. Incorporation of inorganic hydrophilic titanium-based nano-fillers into the PBI matrix further increased the water vapor permeability and water vapor/N2 selectivity. The most selective mixed matrix membrane with 0.5 wt% loading of TiO2 nanotubes yielded a water vapor permeability of 6.8×104 Barrer and a H2O/N2 selectivity of 3.9×106. The most permeable membrane with 1 wt% loading of carboxylated TiO2 nanoparticles had a 7.1×104 Barrer water vapor permeability and a H2O/N2 selectivity of 3.1×106. The performance of these membranes in terms of water vapor transport and selectivity is among the highest reported ones. The remarkable ability of PBI to efficiently permeate water versus other gases opens the possibility to fabricate membranes for dehumidification of streams in harsh environments. This includes the removal of water from high temperature reaction mixtures to shift the equilibrium towards products.

  3. Polybenzimidazole-based mixed membranes with exceptional high water vapor permeability and selectivity

    KAUST Repository

    Akhtar, Faheem Hassan; Kumar, Mahendra; Villalobos, Luis Francisco; Shevate, Rahul; Vovusha, Hakkim; Schwingenschlö gl, Udo; Peinemann, Klaus-Viktor

    2017-01-01

    Polybenzimidazole (PBI), a thermal and chemically stable polymer, is commonly used to fabricate membranes for applications like hydrogen recovery at temperatures of more than 300 °C, fuel cells working in a highly acidic environment, and nanofiltration in aggressive solvents. This report shows for the first time use of PBI dense membranes for water vapor/gas separation applications. They showed an excellent selectivity and high water vapor permeability. Incorporation of inorganic hydrophilic titanium-based nano-fillers into the PBI matrix further increased the water vapor permeability and water vapor/N2 selectivity. The most selective mixed matrix membrane with 0.5 wt% loading of TiO2 nanotubes yielded a water vapor permeability of 6.8×104 Barrer and a H2O/N2 selectivity of 3.9×106. The most permeable membrane with 1 wt% loading of carboxylated TiO2 nanoparticles had a 7.1×104 Barrer water vapor permeability and a H2O/N2 selectivity of 3.1×106. The performance of these membranes in terms of water vapor transport and selectivity is among the highest reported ones. The remarkable ability of PBI to efficiently permeate water versus other gases opens the possibility to fabricate membranes for dehumidification of streams in harsh environments. This includes the removal of water from high temperature reaction mixtures to shift the equilibrium towards products.

  4. Method and Apparatus for High-Permeability Magnetostrictive/Piezo-Fiber Laminates Having Colossal, Near-Ideal Magnetoelectricity

    OpenAIRE

    2007-01-01

    An ME composite laminate of at least one (1-3) piezo-fiber layer coupled with high-permeability alloy magnetostrictive layers, optionally formed of FeBSiC or equivalent. The composite laminate alternates the (1-3) piezo-fiber and high-permeability alloy magnetostrictive layers in a stacked manner. Optionally, the magnetization direction of the high-permeability alloy magnetostrictive layers and polarization direction of the piezo-fiber layer are an (L-L) arrangement. Optionally, thin film pol...

  5. 21 CFR 876.5860 - High permeability hemodialysis system.

    Science.gov (United States)

    2010-04-01

    ... hemodialysis system. (a) Identification. A high permeability hemodialysis system is a device intended for use as an artificial kidney system for the treatment of patients with renal failure, fluid overload, or... system removes toxins or excess fluid from the patient's blood using the principles of convection (via a...

  6. Study on Type C Coal Fly ash as an Additive to Molding Sand for Steel Casting

    Science.gov (United States)

    Palaniappan, Jayanthi

    2017-04-01

    Study of physio-chemical properties studies such as granulometric analysis, moisture, X ray fluorescence etc. were performed with Type C coal—combustion fly ash to investigate their potential as a distinct option for molding sand in foundry, thereby reducing the dependency on latter. Technological properties study such as compressive strength, tensile strength, permeability and compaction of various compositions of fly ash molding sand (10, 20 and 30 % fly ash substitute to chemically bonded sand) were performed and compared with silica molding sand. Steel casting production using this fly ash molding sand was done and the casting surface finish and typical casting parameters were assessed. It was noted that a good quality steel casting could be produced using type C fly ash molding sand, which effectively replaced 20 % of traditional molding sand and binders thereby providing greater financial profits to the foundry and an effective way of fly ash utilization (waste management).

  7. Influence of shaly sands on continuous steam injection oil recovering method; Influencia de areias argilosas na recuperacao de petroleo por injecao de vapor

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, J.M.D.; Rodrigues, M.A.F.; Galvao, E.R.V.P.; Barillas, J.L.M.; Mata, W.; Dutra Junior, T.V. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    Steam flooding is one of the most used thermal recovery methods in Northeast Brazil, because of high occurrence of heavy oil reservoir. In this process, the oil into the reservoir is heated while reduces, substantially, its viscosity and improves the production. This process can be affected by various parameters, including reservoir heterogeneity and the presence of clay. This work studied the influence of the presence of shaly sand layers in the reservoir for this type of recovery. The studied models were synthetics, but the used reservoir data can be extrapolated to real situations of Potiguar Basin. The influence of reservoir parameters in this process is quite important to the oil industry, and some of them were tested, such as the horizontal permeability of the reservoir and clay, the vertical/horizontal permeability ratio, the influence of capillary pressure of shaly sand and how all heterogeneities are allowed to affect in the oil productivity. In this study the parameter of greater influence in the oil recovery was the horizontal permeability, and the configuration of the layer of clay and other parameters affected least the process. (author)

  8. Image Analysis and Estimation of Porosity and Permeability of Arnager Greensand, Upper Cretaceous, Denmark

    DEFF Research Database (Denmark)

    Solymar, Mikael; Fabricius, Ida

    1999-01-01

    Arnager Greensand consists of unconsolidated, poorly sorted fine-grained, glauconitic quartz sand, often silty or clayey, with a few horizons of cemented coarse-grained sand. Samples from the upper part of the Arnager Greensand were used for this study to estimate permeability from microscopic...... images. Backscattered Scanning Electron Microscope images from polished thin-sections were acquired for image analysis with the software PIPPIN(R). Differences in grey levels owing to density differences allowed us to estimate porosity, clay and particle content. The images were simplified into two...

  9. Vector soup: high-throughput identification of Neotropical phlebotomine sand flies using metabarcoding.

    Science.gov (United States)

    Kocher, Arthur; Gantier, Jean-Charles; Gaborit, Pascal; Zinger, Lucie; Holota, Helene; Valiere, Sophie; Dusfour, Isabelle; Girod, Romain; Bañuls, Anne-Laure; Murienne, Jerome

    2017-03-01

    Phlebotomine sand flies are haematophagous dipterans of primary medical importance. They represent the only proven vectors of leishmaniasis worldwide and are involved in the transmission of various other pathogens. Studying the ecology of sand flies is crucial to understand the epidemiology of leishmaniasis and further control this disease. A major limitation in this regard is that traditional morphological-based methods for sand fly species identifications are time-consuming and require taxonomic expertise. DNA metabarcoding holds great promise in overcoming this issue by allowing the identification of multiple species from a single bulk sample. Here, we assessed the reliability of a short insect metabarcode located in the mitochondrial 16S rRNA for the identification of Neotropical sand flies, and constructed a reference database for 40 species found in French Guiana. Then, we conducted a metabarcoding experiment on sand flies mixtures of known content and showed that the method allows an accurate identification of specimens in pools. Finally, we applied metabarcoding to field samples caught in a 1-ha forest plot in French Guiana. Besides providing reliable molecular data for species-level assignations of phlebotomine sand flies, our study proves the efficiency of metabarcoding based on the mitochondrial 16S rRNA for studying sand fly diversity from bulk samples. The application of this high-throughput identification procedure to field samples can provide great opportunities for vector monitoring and eco-epidemiological studies. © 2016 John Wiley & Sons Ltd.

  10. Direct Calculation of Permeability by High-Accurate Finite Difference and Numerical Integration Methods

    KAUST Repository

    Wang, Yi

    2016-07-21

    Velocity of fluid flow in underground porous media is 6~12 orders of magnitudes lower than that in pipelines. If numerical errors are not carefully controlled in this kind of simulations, high distortion of the final results may occur [1-4]. To fit the high accuracy demands of fluid flow simulations in porous media, traditional finite difference methods and numerical integration methods are discussed and corresponding high-accurate methods are developed. When applied to the direct calculation of full-tensor permeability for underground flow, the high-accurate finite difference method is confirmed to have numerical error as low as 10-5% while the high-accurate numerical integration method has numerical error around 0%. Thus, the approach combining the high-accurate finite difference and numerical integration methods is a reliable way to efficiently determine the characteristics of general full-tensor permeability such as maximum and minimum permeability components, principal direction and anisotropic ratio. Copyright © Global-Science Press 2016.

  11. Environmental characterization foundry sands used in sanitary landfills

    International Nuclear Information System (INIS)

    Domingues, L.G.F.; Ferreira, G.C.S.; Pires, M.S.G.; Teixeira, I.; Carnin, R.; Sarro, W.S.

    2016-01-01

    The national solid waste policy recommends reducing solid waste generation and reusing them in different applications. Preliminary studies show that the foundry sand generated from cast metal parts undercut, has excellent applicability in grain size stabilization of soils for geotechnical functions, and therefore, should not be discarded as waste. This study aimed at environmental characterization of two lots of waste foundry sand (WFS), from different industries, to the particle size stabilization of a clayey soil for use in coverage of solid waste in landfills. The methodology included physicochemical characterization tests (grain size, permeability, XRF and heavy metals) and environmental (NBR 10004: 2004, NBR 10005: 2004, NBR 10006: 20004 and acute toxicity with Vibrio fischeri). The results prove the environmental viability of using these lots of WFS as functional material in the composition of landfills. (author)

  12. Engineering properties of concrete with partial utilization of used foundry sand.

    Science.gov (United States)

    Manoharan, Thiruvenkitam; Laksmanan, Dhamothiran; Mylsamy, Kaliyannan; Sivakumar, Pandian; Sircar, Anirbid

    2018-01-01

    Solid wastes generated from manufacturing industries are increasing at an alarming rate and it is consistently increasing. One such industrial solid waste is Used Foundry Sand (UFS). On the other hand, fine aggregates involved in the concrete are generally river sand, which is scarce, high cost and excavation of the river sand that promote environmental degradation. So, there is an urge to find some alternative solution to dispose UFS and to limit the use of river sand. In this research work, river sand was partially replaced by UFS. The percentage replacements were 0, 5, 10, 15, 20 and 25 wt% respectively. Experimental investigations were carried out to evaluate the mechanical, durability and micro-structural properties of M20 concrete at the age of 7, 28 and 91 day. XRD (X-ray Diffraction), EDX (Energy Dispersive X-ray) and optical-microscopic imaging analysis were performed to identify the presence of various compounds and micro cracks in the concrete with UFS. Comparative studies on control mix against trial mix were carried out. It was found that compression strength, flexural strength and modulus of elasticity were approximately constant up to 20 wt% UFS and decreased with further addition. Whereas, split tensile strength was increased after 20 wt% addition but it affects the other properties of concrete. The durability test results showed that the resistance of concrete against abrasion and rapid chloride permeability of the concrete mixture containing UFS up to 20 wt% were almost similar to the values of control mix. The findings suggest that UFS can effectively replace river sand. However, it is recommended that the replacement should not exceed 20 wt%. Copyright © 2017. Published by Elsevier Ltd.

  13. High purity Fe3O4 from Local Iron Sand Extraction

    Science.gov (United States)

    Gunanto, Y. E.; Izaak, M. P.; Jobiliong, E.; Cahyadi, L.; Adi, W. A.

    2018-04-01

    Indonesia has a long coastline and is rich with iron sand. The iron sand is generally rich in various elements such as iron and titanium. One of the products processing of the iron sand mineral is iron (II) (III) oxide (magnetite Fe3O4). The stages of purification process to extracting magnetite phase and discarding the other phases has been performed. Magnetite phase analysis of ironsand extraction retrieved from Indonesia have been investigated. The result of analysis element of iron sand shows that it consists of majority Fe around 65 wt%. However, there are still 17 impurities such as Ti, Al, Ce, Co, Cr, Eu, La, Mg, Mn, Na, Sc, Sm, Th, V, Yb, and Zn. After extraction process, Fe element content increases up to 94%. The iron sand powder after milling for 10 hours and separating using a magnetic separator, the iron sand powders are dissolved in acid chloride solution to form a solution of iron chloride, and this solution is sprinkled with sodium hydroxide to obtain fine powders of Fe3O4. The fine powders which formed were washed with de-mineralization water. The X-ray diffraction pattern shows that the fine powders have a single phase of Fe3O4. The analysis result shows that the sample has the chemical formula: Fe3O4 with a cubic crystal system, space group: Fd-3m and lattice parameters: a = b = c = 8.3681 (1) Å, α = β = γ = 90°. The microstructure analysis shows that the particle of Fe3O4 homogeneously shaped like spherical. The magnetic properties using vibrating sample magnetometer shows that Fe3O4 obtained have ferromagnetic behavior with soft magnetic characteristics. We concluded that this purification of iron sand had been successfully performed to obtain fine powders of Fe3O4 with high purity.

  14. High Temperature Thermal Properties of Bentonite Foundry Sand

    Directory of Open Access Journals (Sweden)

    Krajewski P.K.

    2015-06-01

    Full Text Available The paper presents results of measuring thermal conductivity and heat capacity of bentonite foundry sand in temperature range ambient - 900­­°C. During the experiments a technical purity Cu plate was cast into the green-sand moulds. Basing on measurements of the mould temperature field during the solidification of the casting, the temperature relationships of the measured properties were evaluated. It was confirmed that water vaporization strongly influences thermal conductivity of the moulding sand in the first period of the mould heating by the poured casting.

  15. Effect of High-Intensity Wildfire and Silvicultural Treatments on Reptile Communities in Sand-Pine Scrub

    Science.gov (United States)

    Cathryn H. Greenberg; Daniel G. Neary; Larry D. Harris

    1994-01-01

    We tested whether the herpetofuunal response to clearcutting followed by site preparation was similar to high-intensity wildfire foIlowed by salvage logging in sand- pine scrub. Herpetofaunal communities were compared in three replicated 5- to 7-yearpost-disturbance treatments and mature sand-pine forest. The three disturbance treatments were (1) high-intensity...

  16. Western Gas Sands Project. Status report, 1 August-31 August, 1979

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    This status report summarizes progress of government-sponsored projects directed toward increasing gas production from the low-permeability gas sands of the western United States. Work on fracture conductivity, rock-fluid interaction, and log evaluation and interpretation techniques continued at Bartlesville. Work commenced on completing, testing and possible hydraulic fracturing of the Rio Blanco Natural Gas Company well No. 397-19-1 and on the evaluation of seismic data for stratigraphic studies of lenticular sands. LLL continued experimental and theoretical work on hydraulic fracturing mechanics and analysis of well test data. LASL worked on developing NMR methods to define fluid saturation, porosity, and permeability of western gas sands at in situ conditions. M.D. Wood, Inc. was involved in design and site preparation for two hydraulic fracture mapping jobs in the Cotton Valley Trend in Texas. Testing and analyses of the borehole seismic system and borehole hydrophone system continued at Sandia. Field tests and related activities for the WGSP progressed as scheduled in August. Cyclic injection of dehydrated natural gas and production in Colorado Interstate Gas Company's Miller No. 1 and Sprague No. 1 wells continued. The Gas Producing Enterprises, Inc. wells, Natural Buttes Units 9, 14, 18 and 20 flowed to sales. The Mitchell Energy Corporation Muse-Duke No. 1 was shut-in for a 15-day pressure buildup test. Hydraulic fracture containment experiments and activities in the multi-frac test series continued at the Nevada Test Site for Sandia Laboratories' mineback program.

  17. Error Analysis of High Frequency Core Loss Measurement for Low-Permeability Low-Loss Magnetic Cores

    DEFF Research Database (Denmark)

    Niroumand, Farideh Javidi; Nymand, Morten

    2016-01-01

    in magnetic cores is B-H loop measurement where two windings are placed on the core under test. However, this method is highly vulnerable to phase shift error, especially for low-permeability, low-loss cores. Due to soft saturation and very low core loss, low-permeability low-loss magnetic cores are favorable...... in many of the high-efficiency high power-density power converters. Magnetic powder cores, among the low-permeability low-loss cores, are very attractive since they possess lower magnetic losses in compared to gapped ferrites. This paper presents an analytical study of the phase shift error in the core...... loss measuring of low-permeability, low-loss magnetic cores. Furthermore, the susceptibility of this measurement approach has been analytically investigated under different excitations. It has been shown that this method, under square-wave excitation, is more accurate compared to sinusoidal excitation...

  18. High-frequency permeability in double-layered structure of amorphous Co-Ta-Zr films

    International Nuclear Information System (INIS)

    Ochiai, Y.; Hayakawa, M.; Hayashi, K.; Aso, K.

    1988-01-01

    The high-frequency permeability of amorphous Co-Ta-Zr films was studied and the frequency dependence was described in terms of the eddy-current-loss formula. For the double-layered structure intervened with SiO 2 film, the degradation of the permeability became apparent with the decrease of SiO 2 thickness

  19. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-07-15

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  20. Submarine sand ridges and sand waves in the eastern part of the China Sea

    Science.gov (United States)

    Wu, Ziyin; Li, Shoujun; Shang, Jihong; Zhou, Jieqiong; Zhao, Dineng; Liang, Yuyang

    2016-04-01

    Integrated with multi-beam and single-beam echo sounding data, as well as historical bathymetric data, submarine bathymetric maps of the eastern part of the China Sea, including the Bohai Sea, Huanghai Sea, and East China Sea, are constructed to systematically study submarine sand ridges and sand waves in the eastern part of the China Sea, combined with high-resolution seismic, sub-bottom profile and borehole data. Submarine sand ridges are extraordinarily developed in the eastern part of the China Sea, and 7 sand ridge areas can be divided from north to south, that is, the Laotieshan Channel sand ridge area in the Bohai Sea, the Korea Bay sand ridge area in the southern Huanghai Sea, the sand ridge area in the eastern Huanghai islands and the Huanghai Troughs, the Jianggang sand ridge area in the western Huanghai Sea, the sand ridge area in the East China Sea shelf, and the sand ridge and sand wave area in the Taiwan Strait and Taiwan Banks. The distribution area of the sand ridges and sand waves covers more than 450,000 km2, wherein ~10,000 km2 in the Bohai Bay, ~200,000 km2 in the Huanghai Sea, ~200,000 km2 in the East China Sea shelf, and ~40,000 km2 in the Taiwan Strait and Taiwan Banks, respectively. The great mass of sand ridges are distributed within water depth of 5-160 m, with a total length of over 160 km and a main width of 5-10 km. The inner structure of the sand ridges presents features of high-angle inclined beddings, with main lithology of sands, sand-mud alternations partly visible, and a small number of mud cores. Dating results indicate that the sand ridges in the eastern part of the China Sea are mainly developed in the Holocene. Sea-level variation dominates the sand ridge evolution in the eastern part of the China Sea since the LGM, and the sand ridges developed in the area of < 60m water depth are appeared in bad activity, meanwhile sand ridges with good activity are still developed in large scale.

  1. Numerical simulation of water and sand blowouts when penetrating through shallow water flow formations in deep water drilling

    Science.gov (United States)

    Ren, Shaoran; Liu, Yanmin; Gong, Zhiwu; Yuan, Yujie; Yu, Lu; Wang, Yanyong; Xu, Yan; Deng, Junyu

    2018-02-01

    In this study, we applied a two-phase flow model to simulate water and sand blowout processes when penetrating shallow water flow (SWF) formations during deepwater drilling. We define `sand' as a pseudo-component with high density and viscosity, which can begin to flow with water when a critical pressure difference is attained. We calculated the water and sand blowout rates and analyzed the influencing factors from them, including overpressure of the SWF formation, as well as its zone size, porosity and permeability, and drilling speed (penetration rate). The obtained data can be used for the quantitative assessment of the potential severity of SWF hazards. The results indicate that overpressure of the SWF formation and its zone size have significant effects on SWF blowout. A 10% increase in the SWF formation overpressure can result in a more than 90% increase in the cumulative water blowout and a 150% increase in the sand blowout when a typical SWF sediment is drilled. Along with the conventional methods of well flow and pressure control, chemical plugging, and the application of multi-layer casing, water and sand blowouts can be effectively reduced by increasing the penetration rate. As such, increasing the penetration rate can be a useful measure for controlling SWF hazards during deepwater drilling.

  2. Selected parameters of moulding sands for designing quality control systems

    Directory of Open Access Journals (Sweden)

    J. Jakubski

    2010-07-01

    Full Text Available One of the modern methods of production optimisation are artificial neural networks. Neural networks owe their popularity to the fact thatthey are convenient tools, which can be utilised in a wide scope of problems. They are capable of reflecting complex functions. Especiallytheir non-linearity should be emphasised. They are gaining wider and wider application in the foundry industry, among others, to controlmelting processes in cupolas and arc furnaces, designing castings and supply systems, control of moulding sands treatments, prediction ofproperties of cast alloys as well as selecting die casting.An attempt of the application neural networks to the quality control of moulding sands with bentonite is presented in the paper. This isa method of assessing the suitability of moulding sands by finding correlations in between individual parameters, by means of artificialneural network systems. The presented investigations were performed with the application of the Statistica 8.0 program.The investigations were aimed at the selection of the proper kind of a neural network for prediction a sand moistness on the bases ofcertain moulding sand properties such as: permeability, compactibility and friability. These parameters – determined as sand moistness functions - were introduced as initial parameters.Application of the Statistica program allowed for an automatic selection of the most suitable network for the reflection of dependencies and interactions existing among the proposed parameters. The best results were obtained for unidirectional multi-layer perception network (MLP. The neural network sensitivity to individual moulding sand parameters was determined, which allowed to reject not important parameters when constructing the network.

  3. Potential of the application of the modified polysaccharides water solutions as binders of moulding sands

    Directory of Open Access Journals (Sweden)

    K. Kaczmarska

    2015-10-01

    Full Text Available The results of preliminary tests of selected properties of the moulding sands with the binder in the form of a 5 % water solution of the sodium salt of carboxymethyl starch (with a degree of substitution (DS of 0,2 and 0,87 arepresented in this study. The moulding sand properties such as permeability, abrasion resistance, tensile and bendingstrength - after curing - are shown in series of tests. The cure process was conducted in a field of electromagnetic radiation within the microwave range. The effect of the microwave treatment on the moulding sand was evaporating of water (solvent in a binder and cross-linking of the polymeric binder. As a result the cured moulding sands with particular properties, essential in the context of its application in the mould technology in the foundry industry, were obtained.

  4. Stormwater infiltration and surface runoff pollution reduction performance of permeable pavement layers.

    Science.gov (United States)

    Niu, Zhi-Guang; Lv, Zhi-Wei; Zhang, Ying; Cui, Zhen-Zhen

    2016-02-01

    In this paper, the laboratory-scale permeable pavement layers, including a surface permeable brick layer, coarse sand bedding layers (thicknesses = 2, 3.5, and 5 cm), and single-graded gravel sub-base layers (thicknesses = 15, 20, 25, and 30 cm), were built to evaluate stormwater infiltration and surface runoff pollution reduction performance. And, the infiltration rate (I) and concentrations of suspended solids (SS), total phosphorus (TP), chemical oxygen demand (COD), ammonia nitrogen, and total nitrogen (TN) were measured under the simulated rainfall intensity of 72.4 mm/h over duration of 60 min. The results indicate that the thickness factor primarily influences the infiltration rate and pollutant removal rate. The highest steady infiltration rate was for surface brick layer 51.0 mm/h, for 5-cm sand bedding layer 32.3 mm/h, and for 30-cm gravel sub-base layer 42.3 mm/h, respectively. The SS average removal rate was relative higher (79.8 ∼ 98.6 %) for all layers due to the interception and filtration. The average removal rates of TP and COD were for surface layer 71.2 and 24.1 %, for 5-cm bedding layer 54.8 and 9.0 %, and for 20-cm sub-base layer 72.2 and 26.1 %. Ammonia nitrogen and TN cannot steadily be removed by layers according to the experiment results. The optimal thickness of bedding sands was 5 cm, and that of sub-base gravels was 20 ∼ 30 cm.

  5. Genesis and continuity of quaternary sand and gravel in glacigenic sediment at a proposed low-level radioactive waste disposal site in east-central Illinois

    Science.gov (United States)

    Troost, K.G.; Curry, B. Brandon

    1991-01-01

    The Illinois Department of Nuclear Safety has characterized the Martinsville Alternative Site (MAS) for a proposed low-level radioactive waste disposal facility. The MAS is located in east-central Illinois approximately 1.6 km (1 mi) north of the city of Martinsville. Geologic investigation of the 5.5-km2 (1380-acre) site revealed a sequence of chiefly Illinoian glacigenic sediments from 6 to 60 m (20-200 ft) thick overlying two major bedrock valleys carved in Pennsylvanian strata. Relatively permeable buried units include basal, preglacial alluvium; a complex of intraglacial and subglacial sediment; englacial deposits; and supraglacial fluvial deposits. Postglacial alluvium underlies stream valleys on and adjacent to the site. In most areas, the buried sand units are confined by low-permeability till, lacustrine sediment, colluvium, and loess. The distribution and thickness of the most extensive and continuous buried sand units have been modified considerably by subglacial erosion, and their distributions have been influenced by the buried bedrock valleys. The most continuous of the various sand units were deposited as preglacial and postglacial alluvium and are the uppermost and lowermost stratigraphic units at the alternative site. Sand units that were deposited in englacial or ice-marginal environments are less continuous. Aquifer pumping tests, potentiometric head data, and groundwater geochemistry analyses indicate minimal interaction of groundwater across localized interconnections of the permeable units. ?? 1991 Springer-Verlag New York Inc.

  6. Improvement of Dune Sands by Residual Oil in Order to Use in Construction of Lagoons

    Directory of Open Access Journals (Sweden)

    Alborz Hajian nia

    2011-10-01

    Full Text Available This research which is based on experimental work, devoted to study the improvement and stabilization of dune sands in order to create strong layer and stabilize slope and floor construction of sewage Lagoons. Materials used stabilizing these soils are residual oil from the refinery. To confirm the effectiveness of the use of residual oil to improve the mechanical properties of the sand, various samples with different percentages were tested. In besides, the geotechnical and environmental tests were done. Results demonstrate that samples made with 5% oil have highest shear and unconfined compaction strength. It revealed that in compare with natural samples, cohesion and loading capacity highly increased and permeability decrease well. Percentage of fine aggregate, minerals and durability of oil in soil material were also investigated. Finally, effects of sewage on the samples were analyzed, and performance the oils were evaluated in order to use in lagoons.

  7. Effect of permeability enhancers on paracellular permeability of acyclovir.

    Science.gov (United States)

    Ates, Muge; Kaynak, Mustafa Sinan; Sahin, Selma

    2016-06-01

    According to Biopharmaceutics Classification System (BCS), acyclovir is a class III (high solubility, low permeability) compound, and it is transported through paracellular route by passive diffusion. The aim of this study was to investigate the effect of various pharmaceutical excipients on the intestinal permeability of acyclovir. The single-pass in-situ intestinal perfusion (SPIP) method was used to estimate the permeability values of acyclovir and metoprolol across different intestinal segments (jejunum, ileum and colon). Permeability coefficient (Peff ) of acyclovir was determined in the absence and presence of a permeation enhancer such as dimethyl β-cyclodextrin (DM-β-CD), sodium lauryl sulfate (SLS), sodium caprate (Cap-Na) and chitosan chloride. All enhancers increased the permeability of paracellularly transported acyclovir. Although Cap-Na has the highest permeability-enhancing effect in all segments, permeation-enhancing effect of chitosan and SLS was only significant in ileum. On the other hand, DM-β-CD slightly decreased the permeability in all intestinal segments. These findings have potential implication concerning the enhancement of absorption of paracellularly transported compounds with limited oral bioavailability. In the case of acyclovir, Cap-Na either alone or in combination with SLS or chitosan has the potential to improve its absorption and bioavailability and has yet to be explored. © 2016 Royal Pharmaceutical Society.

  8. Understanding the mechanical and acoustical characteristics of sand aggregates compacting under triaxial conditions

    Science.gov (United States)

    Hangx, Suzanne; Brantut, Nicolas

    2016-04-01

    Mechanisms such as grain rearrangement, coupled with elastic deformation, grain breakage, grain rearrangement, grain rotation, and intergranular sliding, play a key role in determining porosity and permeability reduction during burial of clastic sediments. Similarly, in poorly consolidated, highly porous sands and sandstones, grain rotation, intergranular sliding, grain failure, and pore collapse often lead to significant reduction in porosity through the development of compaction bands, with the reduced porosity and permeability of such bands producing natural barriers to flow within reservoir rocks. Such time-independent compaction processes operating in highly porous water- and hydrocarbon-bearing clastic reservoirs can exert important controls on production-related reservoir deformation, subsidence, and induced seismicity. We performed triaxial compression experiments on sand aggregates consisting of well-rounded Ottawa sand (d = 300-400 μm; φ = 36.1-36.4%) at room temperature, to systematically investigate the effect of confining pressure (Pceff = 5-100 MPa), strain rate (10-6-10-4 s-1) and chemical environment (decane vs. water; Pf = 5 MPa) on compaction. For a limited number of experiments grain size distribution (d = 180-500 μm) and grain shape (subangular Beaujean sand; d = 180-300 μm) were varied to study their effect. Acoustic emission statistics and location, combined with microstructural and grain size analysis, were used to verify the operating microphysical compaction mechanisms. All tests showed significant pre-compaction during the initial hydrostatic (set-up) phase, with quasi-elastic loading behaviour accompanied by permanent deformation during the differential loading stage. This permanent volumetric strain involved elastic grain contact distortion, particle rearrangement, and grain failure. From the acoustic data and grain size analysis, it was evident that at low confining pressure grain rearrangement controlled compaction, with grain

  9. Investigation of Asphaltene Adsorption onto Zeolite Beta Nanoparticles to Reduce Asphaltene Deposition in a Silica Sand Pack

    Directory of Open Access Journals (Sweden)

    Kashefi Sepideh

    2018-01-01

    Full Text Available Zeolite beta nanoparticles were used as a new asphaltene adsorbent for reducing asphaltene deposition during fluid injection into a silica sand pack. At first, the asphaltene adsorption efficiency and capacity of zeolite beta nanoparticles were determined by UV-Vis spectrophotometer. It was found that the proper concentration of nanoparticles for asphaltene adsorption was 10 g/L and the maximum asphaltene adsorption onto zeolite beta was 1.98 mg/m2. Second, two dynamic experiments including co-injection of crude oil and n-heptane (as an asphaltene precipitant with and without use of zeolite beta nanoparticles in the sand pack was carried out. The results showed that the use of zeolite beta nanoparticles increased the permeability ratio and outlet fluid's asphaltene content about 22% and 40% compared to without use of nanoparticles, respectively. Moreover, a model based on monolayer asphaltene adsorption onto nanoparticles and asphaltene deposition mechanisms including surface deposition, entrainment and pore throat plugging was developed to determine formation damage during co-injection of crude oil and n-heptane into the sand pack. The proposed model presented good prediction of permeability and porosity ratios with AAD% of 1.07 and 0.07, respectively.

  10. Influence green sand system by core sand additions

    Directory of Open Access Journals (Sweden)

    N. Špirutová

    2012-01-01

    Full Text Available Today, about two thirds of iron alloys casting (especially for graphitizing alloys of iron are produced into green sand systems with usually organically bonded cores. Separation of core sands from the green sand mixture is very difficult, after pouring. The core sand concentration increase due to circulation of green sand mixture in a closed circulation system. Furthermore in some foundries, core sands have been adding to green sand systems as a replacement for new sands. The goal of this contribution is: “How the green sand systems are influenced by core sands?”This effect is considered by determination of selected technological properties and degree of green sand system re-bonding. From the studies, which have been published yet, there is not consistent opinion on influence of core sand dilution on green sand system properties. In order to simulation of the effect of core sands on the technological properties of green sands, there were applied the most common used technologies of cores production, which are based on bonding with phenolic resin. Core sand concentration added to green sand system, was up to 50 %. Influence of core sand dilution on basic properties of green sand systems was determined by evaluation of basic industrial properties: moisture, green compression strength and splitting strength, wet tensile strength, mixture stability against staling and physical-chemistry properties (pH, conductivity, and loss of ignition. Ratio of active betonite by Methylene blue test was also determined.

  11. Highly permeable, cement-bounded backfilling mortars for SMA repositories

    International Nuclear Information System (INIS)

    Jacobs, F.; Mayer, G.; Wittmann, F.H.

    1994-03-01

    In low- and intermediate-level waste repositories, gas is produced due e.g. to corrosion. This gas must be able to escape from the repository in order to prevent damage to the repository structure. A cement-based backfill should take over this function. For this purpose, the composition of cement-based materials was varied to study their influence on porosity and permeability. In parallel to this study the behaviour of fresh concrete, the liberation of the heat of hydration and the hardened concrete properties were investigated. To characterize the permeability of cement-based materials the following parameters are important: 1) composition of the material (pore fabric), 2) storage conditions (degree of saturation), 3) degree of hydration (age), 4) measuring fluid. A change in the composition of cement-based materials can vary the permeability by ten orders of magnitude. It is shown that, by using dense aggregates, the transport of the fluid takes place through the matrix and along the aggregate/matrix interface. By using porous aggregates the permeability can be increased by two orders of magnitude. In the case of a dense matrix, porous aggregates do not alter the permeability. Increasing the matrix content or interface content increases permeability. Hence light weight mortars are an obvious choice. Like-grained mixes showed higher permeabilities in combination with better mechanical properties but, in comparison to normal mixes, they showed worse flow properties. With the composition cement-: water-: aggregate content 1:0.4:5.33 the likegrained mix with aggregates ranging from 2 to 3 mm proved to be a suitable material. With a low compaction after 28 days this mix reaches a permeability of 4.10 -12 m 2 and an uniaxial cylinder compressive strength of 16 N/mm 2 . (author) 58 figs., 23 tabs., refs

  12. Influence of the reclamation method of spent moulding sands on the possibility of creating favourable conditions for gases flow in a mould

    Directory of Open Access Journals (Sweden)

    Łucarz M.

    2017-03-01

    Full Text Available The results of investigations concerning the influence of the applied sand matrix (fresh sand, reclaim on the properties of moulding sands used for production of large dimensional castings (ingot moulds, ladles, are presented in the hereby paper. The performed investigations were aimed at determining the influence of various reclamation methods of spent moulding sands on the quality of the obtained reclaimed material. Moulding sands were prepared on the fresh quartz matrix as well as on sand matrices obtained after various reclamation methods. The selected moulding sand parameters were tested (strength, permeability, grindability, ignition losses, pH reactions. It can be stated, on the basis of the performed investigations, that the kind of the applied moulding sand matrix is of an essential meaning from the point of view of creating conditions minimising formation of large amounts of gases and their directional migration in a casting mould.

  13. Pore-scale mechanisms of gas flow in tight sand reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Silin, D.; Kneafsey, T.J.; Ajo-Franklin, J.B.; Nico, P.

    2010-11-30

    Tight gas sands are unconventional hydrocarbon energy resource storing large volume of natural gas. Microscopy and 3D imaging of reservoir samples at different scales and resolutions provide insights into the coaredo not significantly smaller in size than conventional sandstones, the extremely dense grain packing makes the pore space tortuous, and the porosity is small. In some cases the inter-granular void space is presented by micron-scale slits, whose geometry requires imaging at submicron resolutions. Maximal Inscribed Spheres computations simulate different scenarios of capillary-equilibrium two-phase fluid displacement. For tight sands, the simulations predict an unusually low wetting fluid saturation threshold, at which the non-wetting phase becomes disconnected. Flow simulations in combination with Maximal Inscribed Spheres computations evaluate relative permeability curves. The computations show that at the threshold saturation, when the nonwetting fluid becomes disconnected, the flow of both fluids is practically blocked. The nonwetting phase is immobile due to the disconnectedness, while the permeability to the wetting phase remains essentially equal to zero due to the pore space geometry. This observation explains the Permeability Jail, which was defined earlier by others. The gas is trapped by capillarity, and the brine is immobile due to the dynamic effects. At the same time, in drainage, simulations predict that the mobility of at least one of the fluids is greater than zero at all saturations. A pore-scale model of gas condensate dropout predicts the rate to be proportional to the scalar product of the fluid velocity and pressure gradient. The narrowest constriction in the flow path is subject to the highest rate of condensation. The pore-scale model naturally upscales to the Panfilov's Darcy-scale model, which implies that the condensate dropout rate is proportional to the pressure gradient squared. Pressure gradient is the greatest near the

  14. Assessment of recycled PET properties for application on oil wells as sand control agents; Avaliacao de propriedades de PET reciclado para aplicacao em pocos de petroleo como agente de contencao de areia

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Alexandre Zacarias Ignacio [PETROBRAS, Rio de Janeiro, RJ (Brazil); Delpech, Marcia Cerqueira [Universidade do Estado do Rio de Janeiro (IQ/UERJ), RJ (Brazil). Inst. de Quimica], e-mail: mcd@uerj.br

    2008-07-01

    The Sand Control is fundamental for oil production in unconsolidated sandstone formations. It consists of the installation of a filter made of stainless steel screens and grained materials (sand control agents) which are, normally, high density inorganic substances (sand, ceramic, bauxite). Shallow formations, near to the sea bed, are more sensitive and need different kinds of sand control agents with low density. The objective of this work was the evaluation of recycled poly(ethylene terephthalate), PET, as sand control agent for oil wells. Pack permeability and thermal stability tests results, after up to six months of exposure to sea water and crude oil, have indicated that the recycled PET kept the necessary characteristics for the proposed application. Also, it was observed that the PET grain pack did not presented significant property modifications in the exposure conditions, when compared to the non-exposed samples. (author)

  15. High Guanidinium Permeability Reveals Dehydration-Dependent Ion Selectivity in the Plasmodial Surface Anion Channel

    Directory of Open Access Journals (Sweden)

    Abdullah A. B. Bokhari

    2014-01-01

    Full Text Available Malaria parasites grow within vertebrate erythrocytes and increase host cell permeability to access nutrients from plasma. This increase is mediated by the plasmodial surface anion channel (PSAC, an unusual ion channel linked to the conserved clag gene family. Although PSAC recognizes and transports a broad range of uncharged and charged solutes, it must efficiently exclude the small Na+ ion to maintain infected cell osmotic stability. Here, we examine possible mechanisms for this remarkable solute selectivity. We identify guanidinium as an organic cation with high permeability into human erythrocytes infected with Plasmodium falciparum, but negligible uptake by uninfected cells. Transport characteristics and pharmacology indicate that this uptake is specifically mediated by PSAC. The rank order of organic and inorganic cation permeabilities suggests cation dehydration as the rate-limiting step in transport through the channel. The high guanidinium permeability of infected cells also allows rapid and stringent synchronization of parasite cultures, as required for molecular and cellular studies of this pathogen. These studies provide important insights into how nutrients and ions are transported via PSAC, an established target for antimalarial drug development.

  16. Permeability of porour rhyolite

    Science.gov (United States)

    Cashman, K.; Rust, A.; Wright, H.; Roberge, J.

    2003-04-01

    The development of permeability in bubble-bearing magmas determines the efficiency of volatile escape during their ascent through volcanic conduits, which, in turn, controls their explosive potential. As permeability requires bubble connectivity, relationships between permeability and porosity in silicic magmas must be controlled by the formation, growth, deformation and coalescence of their constituent bubbles. Although permeability data on porous volcanic pyroclasts are limited, the database can be greatly extended by including data for ceramic and metallic foams1. Several studies indicate that a single number does not adequately describe the permeability of a foam because inertial effects, which predominate at high flow rates, cause deviations from Darcy's law. These studies suggest that permeability is best modeled using the Forschheimer equation to determine both the Darcy permeability (k1) and the non-Darcian (k2) permeability. Importantly, at the high porosities of ceramic foams (75-95%), both k1 and k2 are strongly dependent on pore size and geometry, suggesting that measurement of these parameters provides important information on foam structure. We determined both the connected porosity (by He-pycnometry) and the permeability (k1 and k2) of rhyolitic samples having a wide range in porosity (22-85%) and vesicle textures. In general, these data support previous observations of a power law relationship between connected porosity and Darcy permeability2. In detail, variations in k1 increase at higher porosities. Similarly, k2 generally increases in both mean and standard deviation with increasing porosity. Measurements made on three mutually perpendicular cores from individual pumice clasts suggest that some of the variability can be explained by anisotropy in the vesicle structure. By comparison with ceramic foams, we suggest that the remaining variability results from differences either in average vesicle size or, more likely, in the size of apertures

  17. BH5047 type depth sand moisture-meter of high sensitivity

    International Nuclear Information System (INIS)

    Ji Changsong; Xie Liangnian; Zhang Shulan; Zhang Shuheng

    2000-01-01

    A new depth neutron moisture meter BH5047 has been developed. BH5047 neutron moisture meter is characterised by it is high sensitivity and used for sand water content measurement at concrete mixer. Calibration function is obtained by the Method of Least Squares. Linear correlation efficiency is as good as 0.9977

  18. Numerical Simulation of Hydraulic Fracturing in Low-/High-Permeability, Quasi-Brittle and Heterogeneous Rocks

    Science.gov (United States)

    Pakzad, R.; Wang, S. Y.; Sloan, S. W.

    2018-04-01

    In this study, an elastic-brittle-damage constitutive model was incorporated into the coupled fluid/solid analysis of ABAQUS to iteratively calculate the equilibrium effective stress of Biot's theory of consolidation. The Young's modulus, strength and permeability parameter of the material were randomly assigned to the representative volume elements of finite element models following the Weibull distribution function. The hydraulic conductivity of elements was associated with their hydrostatic effective stress and damage level. The steady-state permeability test results for sandstone specimens under different triaxial loading conditions were reproduced by employing the same set of material parameters in coupled transient flow/stress analyses of plane-strain models, thereby indicating the reliability of the numerical model. The influence of heterogeneity on the failure response and the absolute permeability was investigated, and the post-peak permeability was found to decrease with the heterogeneity level in the coupled analysis with transient flow. The proposed model was applied to the plane-strain simulation of the fluid pressurization of a cavity within a large-scale block under different conditions. Regardless of the heterogeneity level, the hydraulically driven fractures propagated perpendicular to the minimum principal far-field stress direction for high-permeability models under anisotropic far-field stress conditions. Scattered damage elements appeared in the models with higher degrees of heterogeneity. The partially saturated areas around propagating fractures were simulated by relating the saturation degree to the negative pore pressure in low-permeability blocks under high pressure. By replicating previously reported trends in the fracture initiation and breakdown pressure for different pressurization rates and hydraulic conductivities, the results showed that the proposed model for hydraulic fracture problems is reliable for a wide range of

  19. Active binder content as a factor of the control system of the moulding sand quality

    Directory of Open Access Journals (Sweden)

    J. Jakubski

    2011-01-01

    Full Text Available One of the modern methods of the production optimisation are artificial neural networks. Neural networks are gaining broader and broaderapplication in the foundry industry, among others for controlling melting processes in cupolas and in arc furnaces, for designing castingsand supply systems, for controlling moulding sand processing, for predicting properties of cast alloys or selecting parameters of pressurecastings. An attempt to apply neural networks for controlling the quality of bentonite moulding sands is presented in this paper. This is theassessment method of sands suitability by means of detecting correlations between their individual parameters. The presentedinvestigations were obtained by using the Statistica 9.0 program. The presented investigations were aimed at the selection of the neuralnetwork able to predict the active bentonite content in the moulding sand on the basis of this sand properties such as: permeability,compactibility and the compressive strength. An application of the Statistica program allowed to select automatically the type of networkproper for the representation of dependencies occurring in between the proposed moulding sand parameters. The most advantageousconditions were obtained for the uni-directional multi-layer perception (MLP network. Knowledge of the neural network sensitivity to individual moulding sand parameters, allowed to eliminate not essential ones.

  20. Effect of persistent high intraocular pressure on microstructure and hydraulic permeability of trabecular meshwork

    International Nuclear Information System (INIS)

    Mei Xi; Ren Lin; Xu Qiang; Liu Zhi-Cheng; Zheng Wei

    2015-01-01

    As the aqueous humor leaves the eye, it first passes through the trabecular meshwork (TM). Increased flow resistance in this region causes elevation of intraocular pressure (IOP), which leads to the occurrence of glaucoma. To quantitatively evaluate the effect of high IOP on the configuration and hydraulic permeability of the TM, second harmonic generation (SHG) microscopy was used to image the microstructures of the TM and adjacent tissues in control (normal) and high IOP conditions. Enucleated rabbit eyes were perfused at a pressure of 60 mmHg to achieve the high IOP. Through the anterior chamber of the eye, in situ images were obtained from different depths beneath the surface of the TM. Porosity and specific surface area of the TM in control and high IOP conditions were then calculated to estimate the effect of the high pressure on the permeability of tissue in different depths. We further photographed the histological sections of the TM and compared the in situ images. The following results were obtained in the control condition, where the region of depth was less than 55 μm with crossed branching beams and large pores in the superficial TM. The deeper meshwork is a silk-like tissue with abundant fluorescence separating the small size of pores. The total thickness of pathway tissues composed of TM and juxtacanalicular (JCT) is more than 100 μm. After putting a high pressure on the inner wall of the eye, the TM region progressively collapses and decreases to be less than 40 μm. Fibers of the TM became dense, and the porosity at 34 μm in the high IOP condition is comparable to that at 105 μm in the control condition. As a consequent result, the permeability of the superficial TM decreases rapidly from 120 μm 2 to 49.6 μm 2 and that of deeper TM decreases from 1.66 μm 2 to 0.57 μm 2 . Heterogeneity reflected by descent in permeability reduces from 12.4 μm of the control condition to 3.74 μm of the high IOP condition. The persistently high IOP makes the

  1. The influence of slip velocity and temperature on permeability during and after high-velocity fault slip

    Science.gov (United States)

    Tanikawa, W.; Mukoyoshi, H.; Tadai, O.; Hirose, T.; Lin, W.

    2011-12-01

    Fluid transport properties in fault zones play an important role in dynamic processes during large earthquakes. If the permeability in a fault zone is low, high pore-fluid pressures caused by thermal pressurization (Sibson, 1973) or shear-induced compaction (Blanpied et al., 1992) can lead to an apparent reduction of fault strength. Changes in porosity and permeability of fault rocks within a fault zone during earthquakes and the subsequent progressive recovery of these properties may have a large influence on earthquake recurrence (Sleep and Blanpied, 1992). A rotary shear apparatus was used to investigate changes of fluid transport properties in a fault zone by real-time measurement of gas flow rates during and after shearing of hollow sandstone and granite cylinders at various slip rates. Our apparatus measures permeability parallel to the slip plane in both the slip zone and wall rocks. In all cases, permeability decreased rapidly with an increase of friction, but recovered soon after slip, reaching a steady state within several tens of minutes. The rate of reduction of permeability increased with increasing slip velocity. Permeability did not recover to pre-slip levels after low-velocity tests but recovered to exceed them after high-velocity tests. Frictional heating of gases at the slip surface increased gas viscosity, which increased gas flow rate to produce an apparent permeability increase. The irreversible permeability changes of the low-velocity tests were caused by gouge formation due to wearing and smoothing of the slip surface. The increase of permeability after high-velocity tests was caused by mesoscale fracturing in response to rapid temperature rise. Changes of pore fluid viscosity contributed more to changes of flow rate than did permeability changes caused by shear deformation, although test results from different rocks and pore fluids might be different. References Blanpied, M.L., Lockner, D.A., Byerlee, J.D., 1992. An earthquake mechanism

  2. Harding - a field case study: Sand control strategy for ultra-high productivity and injectivity wells

    Energy Technology Data Exchange (ETDEWEB)

    McKay, G.; Bennett, C.; Price-Smith, C.; Dowell, S.; McLellan, W. [British Petroleum (United Kingdom)

    1998-12-31

    The strategy adopted and the factors considered in the development of the sandface completion design for Phase One of the Harding Field in the unconsolidated Balder Massive Sand in the U.K. Sector of the North Sea is described. The field development utilizes a TPG 500 Jack-up Drilling and Production Unit in conjunction with a concrete gravity base tank (GBT). The first phase of the development involved drilling and completing horizontal wells sand-free, ultra-high production (over 30,000 BOPD/well, with PI in excess of 1,000 bbl/day/psi). The experiences showed that pre-packed screens can be successfully utilized to provide lasting sand control with high rate of production in clean homogenous sandstones, and that testing for fluid compatibility, formation damage, screen plugging, corrosion and erosion potential are essential pre-requisites in determining the optimal solution in any well with sand production potential.The experiences gained in Phase One have contributed to design enhancements for Phase Two of the project which include extended reach horizontal wells to neighbouring satellite pools. 3 refs., 1 tab., 8 figs.

  3. Oxidation of trichloroethylene, toluene, and ethanol vapors by a partially saturated permeable reactive barrier

    Science.gov (United States)

    Mahmoodlu, Mojtaba G.; Hassanizadeh, S. Majid; Hartog, Niels; Raoof, Amir

    2014-08-01

    The mitigation of volatile organic compound (VOC) vapors in the unsaturated zone largely relies on the active removal of vapor by ventilation. In this study we considered an alternative method involving the use of solid potassium permanganate to create a horizontal permeable reactive barrier for oxidizing VOC vapors. Column experiments were carried out to investigate the oxidation of trichloroethylene (TCE), toluene, and ethanol vapors using a partially saturated mixture of potassium permanganate and sand grains. Results showed a significant removal of VOC vapors due to the oxidation. We found that water saturation has a major effect on the removal capacity of the permeable reactive layer. We observed a high removal efficiency and reactivity of potassium permanganate for all target compounds at the highest water saturation (Sw = 0.6). A change in pH within the reactive layer reduced oxidation rate of VOCs. The use of carbonate minerals increased the reactivity of potassium permanganate during the oxidation of TCE vapor by buffering the pH. Reactive transport of VOC vapors diffusing through the permeable reactive layer was modeled, including the pH effect on the oxidation rates. The model accurately described the observed breakthrough curve of TCE and toluene vapors in the headspace of the column. However, miscibility of ethanol in water in combination with produced water during oxidation made the modeling results less accurate for ethanol. A linear relationship was found between total oxidized mass of VOC vapors per unit volume of permeable reactive layer and initial water saturation. This behavior indicates that pH changes control the overall reactivity and longevity of the permeable reactive layer during oxidation of VOCs. The results suggest that field application of a horizontal permeable reactive barrier can be a viable technology against upward migration of VOC vapors through the unsaturated zone.

  4. Tar sand extraction by steam stimulation and steam drive: measurement of physical properties

    Energy Technology Data Exchange (ETDEWEB)

    Linberg, W.R.

    1980-09-10

    The measurement of the following thermophysical properties of Utah tar sands is in progress: thermal conductivity, specific heat relative permeability, and viscosity (of the recovered bitumen). During the report period (October 1, 1978 to November 1, 1979), experimental procedures have been developed and a basic data set has been measured. Additionally, standard core analysis has been performed for four drill sites in the Asphalt Ridge, Utah area.

  5. Magnetic field extraction of trap-based electron beams using a high-permeability grid

    International Nuclear Information System (INIS)

    Hurst, N. C.; Danielson, J. R.; Surko, C. M.

    2015-01-01

    A method to form high quality electrostatically guided lepton beams is explored. Test electron beams are extracted from tailored plasmas confined in a Penning-Malmberg trap. The particles are then extracted from the confining axial magnetic field by passing them through a high magnetic permeability grid with radial tines (a so-called “magnetic spider”). An Einzel lens is used to focus and analyze the beam properties. Numerical simulations are used to model non-adiabatic effects due to the spider, and the predictions are compared with the experimental results. Improvements in beam quality are discussed relative to the use of a hole in a high permeability shield (i.e., in lieu of the spider), and areas for further improvement are described

  6. A low-frequency asymptotic model of seismic reflection from a high-permeability layer

    Energy Technology Data Exchange (ETDEWEB)

    Silin, Dmitriy; Goloshubin, Gennady

    2009-03-01

    Analysis of compression wave propagation through a high-permeability layer in a homogeneous poroelastic medium predicts a peak of reflection in the low-frequency end of the spectrum. An explicit formula expresses the resonant frequency through the elastic moduli of the solid skeleton, the permeability of the reservoir rock, the fluid viscosity and compressibility, and the reservoir thickness. This result is obtained through a low-frequency asymptotic analysis of the Biot's model of poroelasticity. A new physical interpretation of some coefficients of the classical poroelasticity is a result of the derivation of the main equations from the Hooke's law, momentum and mass balance equations, and the Darcy's law. The velocity of wave propagation, the attenuation factor, and the wave number, are expressed in the form of power series with respect to a small dimensionless parameter. The latter is equal to the product of the kinematic reservoir fluid mobility, an imaginary unit, and the frequency of the signal. Retaining only the leading terms of the series leads to explicit and relatively simple expressions for the reflection and transmission coefficients for a planar wave crossing an interface between two permeable media, as well as wave reflection from a thin highly-permeable layer (a lens). The practical implications of the theory developed here are seismic modeling, inversion, and attribute analysis.

  7. Study of Black Sand Particles from Sand Dunes in Badr, Saudi Arabia Using Electron Microscopy

    Directory of Open Access Journals (Sweden)

    Haider Abbas Khwaja

    2015-08-01

    Full Text Available Particulate air pollution is a health concern. This study determines the microscopic make-up of different varieties of sand particles collected at a sand dune site in Badr, Saudi Arabia in 2012. Three categories of sand were studied: black sand, white sand, and volcanic sand. The study used multiple high resolution electron microscopies to study the morphologies, emission source types, size, and elemental composition of the particles, and to evaluate the presence of surface “coatings or contaminants” deposited or transported by the black sand particles. White sand was comprised of natural coarse particles linked to wind-blown releases from crustal surfaces, weathering of igneous/metamorphic rock sources, and volcanic activities. Black sand particles exhibited different morphologies and microstructures (surface roughness compared with the white sand and volcanic sand. Morphological Scanning Electron Microscopy (SEM and Laser Scanning Microscopy (LSM analyses revealed that the black sand contained fine and ultrafine particles (50 to 500 nm ranges and was strongly magnetic, indicating the mineral magnetite or elemental iron. Aqueous extracts of black sands were acidic (pH = 5.0. Fe, C, O, Ti, Si, V, and S dominated the composition of black sand. Results suggest that carbon and other contaminant fine particles were produced by fossil-fuel combustion and industrial emissions in heavily industrialized areas of Haifa and Yanbu, and transported as cloud condensation nuclei to Douf Mountain. The suite of techniques used in this study has yielded an in-depth characterization of sand particles. Such information will be needed in future environmental, toxicological, epidemiological, and source apportionment studies.

  8. Effect of high density lipoproteins on permeability of rabbit aorta to low density lipoproteins

    International Nuclear Information System (INIS)

    Klimov, A.N.; Popov, V.A.; Nagornev, V.A.; Pleskov, V.M.

    1985-01-01

    A study was made on the effect of high density lipoproteins (HDL) on the permeability of rabbit aorta to low density lipoproteins (LDL) after intravenous administration of human HDL and human ( 125 I)LDL to normal and hypercholesterolemic rabbits. Evaluation of radioactivity in plasma and aorta has shown that the administration of a large dose of HDL decreased the aorta permeability rate for ( 125 I)LDL on an average by 19% in normal rabbits, and by 45% in rabbits with moderate hypercholesterolemia. A historadiographic study showed that HDL also decreased the vessel wall permeability to ( 125 I)LDL in normal and particularly in hypercholesterolemic animals. The suggestion was made that HDL at very high molar concentration can hamper LDL transportation through the intact endothelial layer into the intima due to the ability of HDL to compete with LDL in sites of low affinity on the surface of endothelial cells. (author)

  9. Permeability prediction in chalks

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Prasad, Manika

    2011-01-01

    The velocity of elastic waves is the primary datum available for acquiring information about subsurface characteristics such as lithology and porosity. Cheap and quick (spatial coverage, ease of measurement) information of permeability can be achieved, if sonic velocity is used for permeability p...... significantly using the effective specific surface as the fluid-flow concept. The FZI unit is appropriate for highly permeable sedimentary rocks such as sandstones and limestones that have small surface areas....

  10. The influence of microwave heating and water glass kind on the properties of molding sands

    Directory of Open Access Journals (Sweden)

    K. Granat

    2008-03-01

    Full Text Available This work presents rcsults of research on thc influcncc of microwave heating time on the process of hardening of warcr glass moldingsands. Essential influence of this drying process on basic properties such as: cornprcssion, bcnding mind tcnsitc strcng~h as well aspcrrneabili~y and war resistance, has bccn found. It has bccn proved, that at1 thc investigated sorts of sodium water glass could be uscd asbinding material of molding sands intended for curing with the microwave process healing. It has bccn found, while analyzing the rcsultsof property studics or microwavc heated molding sands with 2.5% addition of water glass, that aIl available on the markct kinds of thisbinding agent (inctuding the most frequently uscd in foundry 145 and 149 kinds after microwave heating guarantee very goodcompression, bending and tensile strength as well as permeability and wcar resistance. Moroovcr, it has bccn dctcrmined that the optimalcuring powcr of molding sands containing various kinds of water gIass is 560 W. AII values exceeding this rcsult in stabilization of basicpropcrtics of molding sands. The use of microwave curing of water glass molding sands results in a significant decrease of hardeningprocess time. full stabilization of molding sands as well as much lower energy consumption.

  11. Characterization for capillary barriers effects in a sand box test using time-lapsed GPR measurements

    Science.gov (United States)

    Kuroda, S.; Ishii, N.; Morii, T.

    2017-12-01

    Capillary barriers have been known as the method to protect subsurface regions against infiltration from soil surface. It is caused by essentially heterogeneous structure in permeability or soil physical property and produce non-uniform infiltration process then, in order to estimate the actual situation of the capillary barrier effect, the site-characterization with imaging technique like geophysical prospecting is effective. In this study, we examine the applicability of GPR to characterization for capillary barriers. We built a sand box with 90x340x90cm in which a thin high-permeable gravel layer was embedded as a capillary barrier. We conducted an infiltration test in the sand box using porous tube array for irrigation. It is expected to lead to non-uniform flow of soil water induced by capillary barrier effects. We monitored this process by various types of GPR measurements, including time-lapsed common offset profiling (COP) with multi- frequency antenna and transmission measurements like cross-borehole radar. At first, we conducted GPR common-offset survey. It could show the depth of capillary barrier in sand box. After that we conducted the infiltration test and GPR monitoring for infiltration process. GPR profiles can detect the wetting front and estimate water content change in the soil layer above the capillary barrier. From spatial change in these results we can estimate the effect of capillary barrier and the zone where the break through occur or not. Based on these results, we will discuss the applicability of GPR for monitoring the phenomena around the capillary barrier of soil. At first, we conducted GPR common-offset survey. It could show the depth of capillary barrier in sand box. After that we conducted the infiltration test and GPR monitoring for infiltration process. GPR profiles can detect the wetting front and estimate water content change in the soil layer above the capillary barrier. From spatial change in these results we can estimate the

  12. Integrated petrophysical approach for determining reserves and reservoir characterization to optimize production of oil sands in northeastern Alberta

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, A.; Koch, J. [Weatherford Canada Partnership, Bonneyville, AB (Canada)

    2008-10-15

    This study used logging data, borehole imaging data, dipole sonic and magnetic resonance data to study a set of 6 wells in the McMurray Formation of northeastern Alberta. The data sets were used to understand the geologic settings, fluid properties, and rock properties of the area's geology as well as to more accurately estimate its reservoir and production potential. The study also incorporated data from electric, nuclear and acoustic measurements. A shaly sand analysis was used to provide key reservoir petrophysical data. Image data in the study was used to characterize the heterogeneity and permeability of the reservoir in order to optimize production. Results of the shaly sand analysis were then combined with core data and nuclear resonance data in order to determine permeability and lithology-independent porosity. Data sets were used to iteratively refine an integrated petrophysical analysis. Results of the analysis indicated that the depositional environment in which the wells were located did not match a typical fluvial-estuarine sands environment. A further interpretation of all data indicated that the wells were located in a shoreface environment. It was concluded that the integration of petrophysical measurements can enable geoscientists to more accurately characterize sub-surface environments. 3 refs., 7 figs.

  13. Compressive behavior of fine sand.

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Bradley E. (Air Force Research Laboratory, Eglin, FL); Kabir, Md. E. (Purdue University, West Lafayette, IN); Song, Bo; Chen, Wayne (Purdue University, West Lafayette, IN)

    2010-04-01

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  14. Differentiation of Palaeogene sand by glauconitic and geochemical fingerprinting, Siri Canyon, Danish North Sea

    Energy Technology Data Exchange (ETDEWEB)

    Olivarius, M.; Knudsen, Christian; Svendsen, Johan B.

    2011-07-01

    The submarine Siri Canyon is NE-SW-oriented and located in the Danish North Sea. It contains a number of oil reservoirs with glauconite-rich sand. The reservoirs of interest in the Nini oil field are the Late Paleocene Tyr Member of the Lista Formation and the Kolga Member of the Sele Formation, presumably of Early Eocene age. These members have previously been known as the Ty and Hermod members. The sand shows signs of injection, both in cores and in seismic data. The aim of this work is to chemically characterise and fingerprint the sand in order to reveal the origin of the sand found in three horizontal wells, which could have been injected from one or both of the Tyr and Kolga members. Core samples were collected from two vertical wells of known stratigraphy to make a basis of comparison, whereas samples of the cuttings were collected from the three horizontal wells with ages primarily corresponding to the Kolga Member. The purpose was moreover to evaluate whether cuttings samples can be used for fingerprinting as an alternative to core samples. The interest in discriminating between the ages of the injected sand is the fact that the reservoir properties (porosity and permeability) are largely controlled by the original composition of the sand. Consequently, results from this study could affect the property modelling of the field. (LN)

  15. Removal of chromate in a permeable reactive barrier using zero-valent iron

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Locht, T

    2002-01-01

    Chromate is a commonly found groundwater contaminant. Permeable reactive barriers containing zero-valent iron as iron filings are able to remove the chromate by a combined reduction/precipitation reaction. However, due to the passivation of the reduction capability of the iron surfaces by the pre......). Mixing in sand had no significant enhancing effect on the removal capacity, in contrast to a pH adjustment of the groundwater to pH 4, which significantly increased the removal capacity....

  16. Vanadium alloy membranes for high hydrogen permeability and suppressed hydrogen embrittlement

    International Nuclear Information System (INIS)

    Kim, Kwang Hee; Park, Hyeon Cheol; Lee, Jaeho; Cho, Eunseog; Lee, Sang Mock

    2013-01-01

    The structural properties and hydrogen permeation characteristics of ternary vanadium–iron–aluminum (V–Fe–Al) alloy were investigated. To achieve not only high hydrogen permeability but also strong resistance to hydrogen embrittlement, the alloy composition was modulated to show high hydrogen diffusivity but reduced hydrogen solubility. We demonstrated that matching the lattice constant to the value of pure V by co-alloying lattice-contracting and lattice-expanding elements was quite effective in maintaining high hydrogen diffusivity of pure V

  17. Gassmann Modeling of Acoustic Properties of Sand-clay Mixtures

    Science.gov (United States)

    Gurevich, B.; Carcione, J. M.

    that the BM model predicts the fully relaxed moduli, wherein the fluid can move freely between sand and clay regions. In contrast, the CG scheme predicts the no-flow or unrelaxed moduli. Our analysis reveals that due to the extremely low permeability of clays, at seismic and higher frequencies the fluid has no time to move between sand and clay regions. Thus, the CG scheme is more appropriate for clay-rich rocks.

  18. Environmental Impacts of Sand Exploitation. Analysis of Sand Market

    Directory of Open Access Journals (Sweden)

    Marius Dan Gavriletea

    2017-06-01

    Full Text Available Sand is an indispensable natural resource for any society. Despite society’s increasing dependence on sand, there are major challenges that this industry needs to deal with: limited sand resources, illegal mining, and environmental impact of sand mining. The purpose of this paper is twofold: to present an overview of the sand market, highlighting the main trends and actors for production, export and import, and to review the main environmental impacts associated with sand exploitation process. Based on these findings, we recommend different measures to be followed to reduce negative impacts. Sand mining should be done in a way that limits environmental damage during exploitation and restores the land after mining operations are completed.

  19. Modelling of hydrogen permeability of membranes for high-purity hydrogen production

    Science.gov (United States)

    Zaika, Yury V.; Rodchenkova, Natalia I.

    2017-11-01

    High-purity hydrogen is required for clean energy and a variety of chemical technology processes. Different alloys, which may be well-suited for use in gas-separation plants, were investigated by measuring specific hydrogen permeability. One had to estimate the parameters of diffusion and sorption to numerically model the different scenarios and experimental conditions of the material usage (including extreme ones), and identify the limiting factors. This paper presents a nonlinear mathematical model taking into account the dynamics of sorption-desorption processes and reversible capture of diffusing hydrogen by inhomogeneity of the material’s structure, and also modification of the model when the transport rate is high. The results of numerical modelling allow to obtain information about output data sensitivity with respect to variations of the material’s hydrogen permeability parameters. Furthermore, it is possible to analyze the dynamics of concentrations and fluxes that cannot be measured directly. Experimental data for Ta77Nb23 and V85Ni15 alloys were used to test the model. This work is supported by the Russian Foundation for Basic Research (Project No. 15-01-00744).

  20. Permeability and 3-D melt geometry in shear-induced high melt fraction conduits

    Science.gov (United States)

    Zhu, W.; Cordonnier, B.; Qi, C.; Kohlstedt, D. L.

    2017-12-01

    Observations of dunite channels in ophiolites and uranium-series disequilibria in mid-ocean ridge basalt suggest that melt transport in the upper mantle beneath mid-ocean ridges is strongly channelized. Formation of high melt fraction conduits could result from mechanical shear, pyroxene dissolution, and lithological partitioning. Deformation experiments (e.g. Holtzman et al., 2003) demonstrate that shear stress causes initially homogeneously distributed melt to segregate into an array of melt-rich bands, flanked by melt-depleted regions. At the same average melt fraction, the permeability of high melt fraction conduits could be orders of magnitude higher than that of their homogenous counterparts. However, it is difficult to determine the permeability of melt-rich bands. Using X-ray synchrotron microtomography, we obtained high-resolution images of 3-dimensional (3-D) melt distribution in a partially molten rock containing shear-induced high melt fraction conduits. Sample CQ0705, an olivine-alkali basalt aggregate with a nominal melt fraction of 4%, was deformed in torsion at a temperature of 1473 K and a confining pressure of 300 MPa to a shear strain of 13.3. A sub-volume of CQ0705 encompassing 3-4 melt-rich bands was imaged. Microtomography data were reduced to binary form so that solid olivine is distinguishable from basalt glass. At a spatial resolution of 160 nm, the 3-D images reveal the shape and connectedness of melt pockets in the melt-rich bands. Thin melt channels formed at grain edges are connected at large melt nodes at grain corners. Initial data analysis shows a clear preferred orientation of melt pockets alignment subparallel to the melt-rich band. We use the experimentally determined geometrical parameters of melt topology to create a digital rock with identical 3-D microstructures. Stokes flow simulations are conducted on the digital rock to obtain the permeability tensor. Using this digital rock physics approach, we determine how deformation

  1. Numerical simulation of wind-sand movement in the reversed flow region of a sand dune with a bridge built downstream.

    Science.gov (United States)

    He, Wei; Huang, Ning; Xu, Bin; Wang, Wenbo

    2018-04-23

    A bridge built inside the reversed flow region of a sand dune will change the characteristics of wind-sand movement in this region. The Reynolds-averaged Navier-Stokes simulation and discrete particle tracing are used to simulate the wind-sand movement around a sand dune with a bridge built inside the reversed region. Three cases with different bridge positions are studied. The results show that 1) compared with the isolated dune case, a tall bridge built at the leeward toe leads to an increase in the deposition rate on the leeward slope and a longer reversed flow region downstream of the sand dune; meanwhile, the high speed of crosswind on the bridge indicates that some measures should be taken to protect trains from strong crosswind; 2) a low bridge at the leeward toe has little effect on the sand deposition and reversed flow region of the dune; however, low sand transport rate and crosswind speed on the bridge show that anti-crosswind/sand measures should be taken according to the actual situation and 3) a low bridge on the leeward slope has little effect on the length of reversed flow region, however, high crosswind speed and sand flux on the bridge reveal the need of anti-crosswind/sand measures on the bridge. Moreover, the bridges in the reversed flow region increase the sand flux near the leeward crest; as a result, the moving patterns of the sand dune are changed.

  2. Compact rock material gas permeability properties

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Huanling, E-mail: whl_hm@163.com [Key Laboratory of Coastal Disaster and Defence, Ministry of Education, Hohai University, Nanjing 210098 (China); LML, University of Lille, Cite Scientifique, 59655 Villeneuve d’Ascq (France); Xu, Weiya; Zuo, Jing [Institutes of Geotechnical Engineering, Hohai University, Nanjing 210098 (China)

    2014-09-15

    Natural compact rocks, such as sandstone, granite, and rock salt, are the main materials and geological environment for storing underground oil, gas, CO{sub 2,} shale gas, and radioactive waste because they have extremely low permeabilities and high mechanical strengths. Using the inert gas argon as the fluid medium, the stress-dependent permeability and porosity of monzonitic granite and granite gneiss from an underground oil storage depot were measured using a permeability and porosity measurement system. Based on the test results, models for describing the relationships among the permeability, porosity, and confining pressure of rock specimens were analyzed and are discussed. A power law is suggested to describe the relationship between the stress-dependent porosity and permeability; for the monzonitic granite and granite gneiss (for monzonitic granite (A-2), the initial porosity is approximately 4.05%, and the permeability is approximately 10{sup −19} m{sup 2}; for the granite gneiss (B-2), the initial porosity is approximately 7.09%, the permeability is approximately 10{sup −17} m{sup 2}; and the porosity-sensitivity exponents that link porosity and permeability are 0.98 and 3.11, respectively). Compared with moderate-porosity and high-porosity rocks, for which φ > 15%, low-porosity rock permeability has a relatively lower sensitivity to stress, but the porosity is more sensitive to stress, and different types of rocks show similar trends. From the test results, it can be inferred that the test rock specimens’ permeability evolution is related to the relative particle movements and microcrack closure.

  3. Bituminous sands : tax issues

    International Nuclear Information System (INIS)

    Patel, B.

    2004-01-01

    This paper examined some of the tax issues associated with the production of bitumen or synthetic crude oil from oil sands. The oil sands deposits in Alberta are gaining more attention as the supplies of conventional oil in Canada decline. The oil sands reserves located in the Athabasca, Cold Lake and Peace River areas contain about 2.5 trillion barrels of highly viscous hydrocarbons called bitumen, of which nearly 315 billion barrels are recoverable with current technology. The extraction method varies for each geographic area, and even within zones and reservoirs. The two most common extraction methods are surface mining and in-situ extraction such as cyclic steam stimulation (CSS); low pressure steam flood; pressure cycle steam drive; steam assisted gravity drainage (SAGD); hot water flooding; and, fire flood. This paper also discussed the following general tax issues: bituminous sands definition; bituminous sands leases and Canadian development expense versus Canadian oil and gas property expense (COGPE); Canadian exploration expense (CEE) for surface mining versus in-situ methods; additional capital cost allowance; and, scientific research and experimental development (SR and ED). 15 refs

  4. Acute high-intensity interval running increases markers of gastrointestinal damage and permeability but not gastrointestinal symptoms.

    Science.gov (United States)

    Pugh, Jamie N; Impey, Samuel G; Doran, Dominic A; Fleming, Simon C; Morton, James P; Close, Graeme L

    2017-09-01

    The purpose of this study was to investigate the effects of high-intensity interval running on markers of gastrointestinal (GI) damage and permeability alongside subjective symptoms of GI discomfort. Eleven male runners completed an acute bout of high-intensity interval training (HIIT) (eighteen 400-m runs at 120% maximal oxygen uptake) where markers of GI permeability, intestinal damage, and GI discomfort symptoms were assessed and compared with resting conditions. Compared with rest, HIIT significantly increased serum lactulose/rhamnose ratio (0.051 ± 0.016 vs. 0.031 ± 0.021, p = 0.0047; 95% confidence interval (CI) = 0.006 to 0.036) and sucrose concentrations (0.388 ± 0.217 vs. 0.137 ± 0.148 mg·L -1 ; p HIIT and resting conditions. Plasma intestinal-fatty acid binding protein (I-FABP) was significantly increased (p HIIT whereas no changes were observed during rest. Mild symptoms of GI discomfort were reported immediately and at 24 h post-HIIT, although these symptoms did not correlate to GI permeability or I-FABP. In conclusion, acute HIIT increased GI permeability and intestinal I-FABP release, although these do not correlate with symptoms of GI discomfort. Furthermore, by using serum sampling, we provide data showing that it is possible to detect changes in intestinal permeability that is not observed using urinary sampling over a shorter time-period.

  5. Southeast Florida Sediment Assessment and Needs Determination (SAND) Study

    Science.gov (United States)

    2014-09-01

    sand with some shell beds, sandstone , and limestone *Miami Limestone 0 to 80 ft Oolitic limestone, quartz sand, and sandstone Anastasia 0 to 100 ft...Sand, shell beds, marl, calcareous sandstone (coquina/calcarenite) Fort Thompson 0 to 80 ft Silty limestone, silty sand, clayey marl, shell marl...highly- to moderately- weathered quartzose sandstone , and highly-weathered (saprolitic) to moderately-weathered hard limestone. North-south and

  6. Different Methods of Predicting Permeability in Shale

    DEFF Research Database (Denmark)

    Mbia, Ernest Ncha; Fabricius, Ida Lykke; Krogsbøll, Anette

    by two to five orders of magnitudes at lower vertical effective stress below 40 MPa as the content of clay minerals increases causing heterogeneity in shale material. Indirect permeability from consolidation can give maximum and minimum values of shale permeability needed in simulating fluid flow......Permeability is often very difficult to measure or predict in shale lithology. In this work we are determining shale permeability from consolidation tests data using Wissa et al., (1971) approach and comparing the results with predicted permeability from Kozeny’s model. Core and cuttings materials...... effective stress to 9 μD at high vertical effective stress of 100 MPa. The indirect permeability calculated from consolidation tests falls in the same magnitude at higher vertical effective stress, above 40 MPa, as that of the Kozeny model for shale samples with high non-clay content ≥ 70% but are higher...

  7. Complementary analyses of hollow cylindrical unioriented permanent magnet (HCM) with high permeability external layer

    Science.gov (United States)

    Lobo, Carlos M. S.; Tosin, Giancarlo; Baader, Johann E.; Colnago, Luiz A.

    2017-10-01

    In this article, several studies based on analytical expressions and computational simulations on Hollow Cylindrical Magnets with an external soft ferromagnetic material (HCM magnets) are presented. Electromagnetic configurations, as well as permanent-magnet-based structures, are studied in terms of magnetic field strength and homogeneity. Permanent-magnet-based structures are further analyzed in terms of the anisotropy of the magnetic permeability. It was found that the HCM magnets produce a highly homogeneous magnetic field as long as the magnetic material is isotropic. The dependency of the magnetic field strength and homogeneity in terms of the anisotropy of the magnetic permeability is also explored here. These magnets can potentially be used in medium-resolution NMR spectrometers and high-field NMR spectrometers.

  8. Sedimentological Properties of Natural Gas Hydrates-Bearing Sands in the Nankai Trough and Mallik Areas

    Science.gov (United States)

    Uchida, T.; Tsuji, T.; Waseda, A.

    2009-12-01

    The Nankai Trough parallels the Japanese Island, where extensive BSRs have been interpreted from seismic reflection records. High resolution seismic surveys have definitely indicated gas hydrate distributions, and drilling the MITI Nankai Trough wells in 2000 and the METI Tokai-oki to Kumano-nada wells in 2004 have revealed subsurface gas hydrate in the eastern part of Nankai Trough. In 1998 and 2002 Mallik wells were drilled at Mackenzie Delta in the Canadian Arctic that also clarified the characteristics of gas hydrate-dominant sandy layers at depths from 890 to 1110 m beneath the permafrost zone. During the field operations, the LWD and wire-line well log data were continuously obtained and plenty of gas hydrate-bearing sand cores were recovered. Subsequence sedimentological and geochemical analyses performed on those core samples revealed the crucial geologic controls on the formation and preservation of natural gas hydrate in sediments. Pore-space gas hydrates reside in sandy sediments mostly filling intergranular porosity. Pore waters chloride anomalies, core temperature depression and core observations on visible gas hydrates confirm the presence of pore-space gas hydrates within moderate to thick sandy layers, typically 10 cm to a meter thick. Sediment porosities and pore-size distributions were obtained by mercury porosimetry, which indicate that porosities of gas hydrate-bearing sandy strata are approximately 45 %. According to grain size distribution curves, gas hydrate is dominant in fine- to very fine-grained sandy strata. Gas hydrate saturations are typically up to 80 % in pore volume throughout most of the hydrate-dominant sandy layers, which are estimated by well log analyses as well as pore water chloride anomalies. It is necessary for investigating subsurface fluid flow behaviors to evaluate both porosity and permeability of gas hydrate-bearing sandy sediments, and the measurements of water permeability for them indicated that highly saturated

  9. Gasification of oil sand coke: review

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E. [IMAF Group, Ottawa, ON (Canada)

    1998-08-01

    The production of synthetic crude from the tar sands in Western Canada has been steadily increasing. Most of the delayed coke produced by Suncor is combusted on site, whereas all fluid coke produced by Syncrude is stockpiled.The database on the chemical and physical properties of the oil sand coke, including the composition and fusion properties of the mineral matter, has been established. The reactivity of the coke was determined by oxygen chemisorption, fixed bed and fluid bed bench scale gasification and pilot plant gasification. The reactivity of the oil sand coke for gasification is rather low and comparable to high rank coals, such as anthracite. Slurrability tests revealed that a solid concentration in water, approaching 70 wt%, can be achieved. Gasification is the front runner among clean technologies for the conversion of carbonaceous solids to useful products. Several commercial gasifiers are available to cover the wide range of severity. Because of the low reactivity of oil sands coke, high severity conditions are required to achieve high gasification conversion. Such conditions can be attained in entrained bed gasifiers. Gasifiers employing both dry and slurry feeding systems are suitable. A high efficiency, low SO{sub x} and NO{sub x} emissions, as well as a low solid waste production are among the key advantages of the gasification technology compared with thecompeting technologies. Commercial gasification of oil sands coke is delayed because of the availability of natural gas on the site of the upgrading plants. Potential for the transportation of the oil sand coke to USA for electricity generation using the integrated gasification combined-cycle (IGCC) technology was evaluated. 27 refs., 17 figs., 9 tabs.

  10. Sand transportation and reverse patterns over leeward face of sand dune

    Science.gov (United States)

    Jiang, Hong; Dun, Hongchao; Tong, Ding; Huang, Ning

    2017-04-01

    Sand saltation has complex interactions with turbulent flow and dune form. Most models of wind-blown sand consider ideal circumstances such as steady wind velocity and a flat surface, and the bulk of data on wind flow and sand transport over an individual dune has focused mostly on the influence of dune shape or inter-dune space on the wind flow, neglecting the effect of morphology on sand saltation, particularly airflow and sand transportation over the leeward slope. Wind flow structures over the leeward slope of sand dunes have a fundamental influence on the organization of sand dunes. In order to understand sand dune dynamics, lee face airflow and sediment transportation should be paid more attention. Previous field observations could not measure turbulent flow structure well because of the limited observation points and the influence of experiment structure on wind field. In addition, the reverse sand particles over leeward face could not be collected by sand trap in field. Numerous field observations could not measure turbulent flow structure because of the limited observation points and the influence of experimental structures on the wind field. In addition, the reverse transport of sand particles over leeward face could not be collected by sand traps in field. Therefore, this paper aims to investigate the turbulent flow structure and sand transport pattern over the leeward slope. A numerical model of sand saltation over slope terrain is constructed, which also considers the coupling effects between air flow and sand particles. The large eddy simulation method is used to model turbulent flow. Sand transport is simulated by tracking the trajectory of each sand particle. The results show that terrain significantly alters the turbulent air flow structure and wind-blown sand movement, especially over the leeward slope. Here, mass flux increases initially and then decreases with height in the reversed flow region in the direction of wind flow, and the mass flux

  11. The potential of permeability damage during the thermal recovery of the Cold Lake bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Z.; Wiwchar, B.; Gunter, W. D. [Alberta Research Council, Devon, AB (Canada); Dudley, J. S. [Imperial Oil Ltd., Sarnia, ON (Canada). Research Dept.

    1997-08-01

    It has been suggested that hydrothermal reactions of clay minerals, present in all oil sands deposits in the Clearwater Formation at Cold Lake, may cause permeability damage during thermal recovery. To gain an idea of the extent of the damage, two corefloods were conducted at 250 degrees C. The first period of permeability damage occurred during and shortly after the core was heated to 250 degrees C, the second period was a gradual process , but resulted in 65 per cent and 78 per cent respectively, whereas the third period occurred when fresh water was injected into the core. These periods of damage were attributed to thermally activated grain crushing and fines migration, hydrothermal reactions, and osmotic swelling of the hydrothermal clay, respectively. Laboratory results do not agree with field experiments, although there is some field evidence for the disruption of berthierine (a form of clay) grain coats and permeability damage due to subsequent fines migration. In view of this evidence it was suggested that injection wells should not be placed in berthierine-rich zone. 15 refs., 2 tabs., 7 figs.

  12. Experimental study of very low permeability rocks using a high accuracy permeameter

    International Nuclear Information System (INIS)

    Larive, Elodie

    2002-01-01

    The measurement of fluid flow through 'tight' rocks is important to provide a better understanding of physical processes involved in several industrial and natural problems. These include deep nuclear waste repositories, management of aquifers, gas, petroleum or geothermal reservoirs, or earthquakes prevention. The major part of this work consisted of the design, construction and use of an elaborate experimental apparatus allowing laboratory permeability measurements (fluid flow) of very low permeability rocks, on samples at a centimetric scale, to constrain their hydraulic behaviour at realistic in-situ conditions. The accuracy permeameter allows the use of several measurement methods, the steady-state flow method, the transient pulse method, and the sinusoidal pore pressure oscillation method. Measurements were made with the pore pressure oscillation method, using different waveform periods, at several pore and confining pressure conditions, on different materials. The permeability of one natural standard, Westerly granite, and an artificial one, a micro-porous cement, were measured, and results obtained agreed with previous measurements made on these materials showing the reliability of the permeameter. A study of a Yorkshire sandstone shows a relationship between rock microstructure, permeability anisotropy and thermal cracking. Microstructure, porosity and permeability concepts, and laboratory permeability measurements specifications are presented, the permeameter is described, and then permeability results obtained on the investigated materials are reported [fr

  13. Western Gas Sands Project status report

    Energy Technology Data Exchange (ETDEWEB)

    Atkinson, C.H.

    1978-11-30

    Progress of government-sponsored projects directed toward increasing gas production from the low-permeability gas sands of the western United States is summarized. A Technology Implementation Plan (TIP) meeting was held at the CER office in Las Vegas, Nevada, October 16--19 to initiate the implementation phase of the Enhanced Gas Recovery (EGR) working group activities. A WGSP Logging Program meeting was conducted on October 24, 1978, at CER offices to define the problems associated with logs in tight gas sands. CER personnel and the project manager attended a two-day course on the fundamentals of core and reservoir analysis in Denver, Colorado, and met with USGS personnel to discuss USGS work on the WGSP. A meeting was held to discuss a contract for coring a Twin Arrow well on the Douglas Creek Arch, Colorado. CER Corporation personnel attended the Geological Society of America Annual Meeting held in Toronto, Canada, October 23--27 and a Gas Stimulation Workshop at Sandia Laboratories in Albuquerque, New Mexico, October 11 and 12 to discuss recent mineback experiments conducted at the Nevada Test Site. Fiscal year 1979 projects initiated by USGS and the Energy Technology Centers and National Laboratories are progressing as scheduled. Mobil Research and Development Corporation fractured zone 8 of the F-31-13G well in Rio Blanco County, Colorado. Colorado Interstate Gas Company poured the concrete pad for the compresser expected to be delivered in December and were laying pipeline between the wells at month end. The Mitchell Energy well, Muse Duke No. 1 was flowing on test at a rate of 2,100 Mcfd and preparations proceeded to fracture the well on November 15 with approximately 1,000,000 gal of fluid and 3,000,000 lb of sand. Terra Tek completed laboratory analyses of cores taken from the Mitchell Energy well.

  14. Influence of In-Situ Oil Sands Development on Caribou (Rangifer tarandus Movement.

    Directory of Open Access Journals (Sweden)

    Tyler Muhly

    Full Text Available In-situ oil sands development (ISD involves a network of facilities, wells, roads and pipelines to extract and transport subsurface bitumen. This technology is rapidly expanding and there is uncertainty whether ISDs restrict animal movement, leading to increased extinction probabilities for some wide-ranging species. Here we test for effects of simulated future (i.e., 50 years from now and current ISDs on simulated movements of woodland caribou (Rangifer tarandus, a threatened species across North America. In simulations of future scenarios, we varied the spacing and permeability of ISDs and the presence/absence of protected areas. Permeability was measured as the number of times simulated caribou crossed ISDs with different levels of modelled permeability. We estimated the effects of these factors on caribou step length and annual home range size, key metrics of small and large spatiotemporal scales of movement, respectively. Current caribou crossings of above-ground pipeline features of ISDs were measured using camera traps and compared to expected caribou crossing rates based on present-day caribou movement simulations. Current crossing rates were evaluated within the context of predicted future crossing success rates necessary to maintain caribou step lengths and home ranges. With few exceptions, permeability across ISDs was the main factor affecting caribou movement, more so than spacing between developments or the presence of protected areas. However, minimal permeability (crossing rates of c. 15% to 60%, relative to an undisturbed site was needed to maintain existing home range size and step lengths. The effect of permeability on home range size and step length was non-linear, suggesting that small increases in permeability would provide a disproportionately greater benefit to caribou movement. Our predictions demonstrate that maintaining permeability across ISDs is more important than spacing between leases or including protected areas

  15. Microstructure Based Material-Sand Particulate Interactions and Assessment of Coatings for High Temperature Turbine Blades

    Science.gov (United States)

    Murugan, Muthuvel; Ghoshal, Anindya; Walock, Michael; Nieto, Andy; Bravo, Luis; Barnett, Blake; Pepi, Marc; Swab, Jeffrey; Pegg, Robert Tyler; Rowe, Chris; hide

    2017-01-01

    Gas turbine engines for military/commercial fixed-wing and rotary wing aircraft use thermal barrier coatings in the high-temperature sections of the engine for improved efficiency and power. The desire to further make improvements in gas turbine engine efficiency and high power-density is driving the research and development of thermal barrier coatings and the effort of improving their tolerance to fine foreign particulates that may be contained in the intake air. Both commercial and military aircraft engines often are required to operate over sandy regions such as in the Middle-East nations, as well as over volcanic zones. For rotorcraft gas turbine engines, the sand ingestion is adverse during take-off, hovering near ground, and landing conditions. Although, most of the rotorcraft gas turbine engines are fitted with inlet particle separators, they are not 100 percent efficient in filtering fine sand particles of size 75 microns or below. The presence of these fine solid particles in the working fluid medium has an adverse effect on the durability of turbine blade thermal barrier coatings and overall performance of the engine. Typical turbine blade damages include blade coating wear, sand glazing, Calcia-Magnesia-Alumina-Silicate (CMAS) attack, oxidation, plugged cooling holes, all of which can cause rapid performance deterioration including loss of aircraft. The objective of this research is to understand the fine particle interactions with typical ceramic coatings of turbine blades at the microstructure level. A finite-element based microstructure modeling and analysis has been performed to investigate particle-surface interactions, and restitution characteristics. Experimentally, a set of tailored thermal barrier coatings and surface treatments were down-selected through hot burner rig tests and then applied to first stage nozzle vanes of the Gas Generator Turbine of a typical rotorcraft gas turbine engine. Laser Doppler velocity measurements were performed

  16. Developments in permeable and low permeability barriers

    International Nuclear Information System (INIS)

    Jefferis, S.A.; Norris, G.H.; Thomas, A.O.

    1997-01-01

    The concept of the reactive treatment zone whereby pollutants are attenuated as they move along a pathway in the ground has enabled a re-thinking of many of the concepts of containment. In particular it offers the potential for the control of the flux from a contaminated area by controlling the contaminant concentration in the pathway(s) as well as or instead of using a low permeability barrier. The paper outlines the basic concepts of the reactive treatment zone and the use of permeable and low permeability reactive systems. The paper then gives a case history of the installation of a permeable barrier using an in-situ reaction chamber

  17. Complementary analyses of hollow cylindrical unioriented permanent magnet (HCM) with high permeability external layer.

    Science.gov (United States)

    Lobo, Carlos M S; Tosin, Giancarlo; Baader, Johann E; Colnago, Luiz A

    2017-10-01

    In this article, several studies based on analytical expressions and computational simulations on Hollow Cylindrical Magnets with an external soft ferromagnetic material (HCM magnets) are presented. Electromagnetic configurations, as well as permanent-magnet-based structures, are studied in terms of magnetic field strength and homogeneity. Permanent-magnet-based structures are further analyzed in terms of the anisotropy of the magnetic permeability. It was found that the HCM magnets produce a highly homogeneous magnetic field as long as the magnetic material is isotropic. The dependency of the magnetic field strength and homogeneity in terms of the anisotropy of the magnetic permeability is also explored here. These magnets can potentially be used in medium-resolution NMR spectrometers and high-field NMR spectrometers. Copyright © 2017 Elsevier Inc. All rights reserved.

  18. Analysis of heterogeneous characteristics in a geothermal area with low permeability and high temperature

    Directory of Open Access Journals (Sweden)

    Alfonso Aragón-Aguilar

    2017-09-01

    Full Text Available An analytical methodology for reservoir characterization was applied in the central and southwestern zones of Los Humeros geothermal field (LHGF. This study involves analysis of temperature, pressure, enthalpy and permeability in wells and their distribution along the area. The wells located in the central western side of the geothermal field are productive, whereas those located at the central-eastern side are non-productive. Through temperature profiles, determined at steady state in the analyzed wells, it was observed that at bottom conditions (approximately 2300 m depth, temperatures vary between 280 and 360 °C. The temperatures are higher at the eastern side of central zone of LHGF. A review of transient pressure tests, laboratory measurements of core samples, and correlation of circulation losses during drilling suggest that permeability of the formation is low. The enthalpy behavior in productive wells shows a tendency of increase in the steam fraction. It was found that productivity behavior has inverse relation with permeability of rock formation. Further, it is observed that an imbalance exists between exploitation and recharge. It is concluded from the results that the wells located at central-eastern area have low permeability and high temperature, which indicates possibility of heat storage.

  19. Quantifying porosity, compressibility and permeability in Shale

    DEFF Research Database (Denmark)

    Mbia, Ernest Ncha; Fabricius, Ida Lykke; Frykman, Peter

    strain data. We found that Kozeny's modelled permeability fall in the same order of magnitude with measured permeability for shale rich in kaolinite but overestimates permeability by two to three orders of magnitudes for shale with high content of smectite. The empirical Yang and Aplin model gives good...... permeability estimate comparable to the measured one for shale rich in smectite. This is probably because Yang and Aplin model was calibrated in London clay which is rich in smectite....

  20. Thermoluminescent dosimetric properties of Descalvado sand

    International Nuclear Information System (INIS)

    Teixeira, M.I.; Caldas, L.V.E.

    2006-01-01

    Sand samples proceeding from Descalvado, Sao Paulo, were studied with regard to their dosimetric properties using the thermoluminescence technique (TL) for high doses. These sand samples present steady physical and chemical characteristics to the end items, and they are used in the glass industry and for casting. The TL curves of the samples were obtained after an irradiation at the Gamma-Cell system ( 60 Co), of IPEN. The glow curves present two peaks at 80 C and 220 C approximately. Calibration curves were obtained for doses between 50 Gy and 5 kGy. The results indicate that the sand samples can be used for high-doses dosimetry in several areas of applications of ionizing radiation. (Author)

  1. Thermoluminescent dosimetric properties of Descalvado sand

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, M.I.; Caldas, L.V.E

    2006-07-01

    Sand samples proceeding from Descalvado, Sao Paulo, were studied with regard to their dosimetric properties using the thermoluminescence technique (TL) for high doses. These sand samples present steady physical and chemical characteristics to the end items, and they are used in the glass industry and for casting. The TL curves of the samples were obtained after an irradiation at the Gamma-Cell system ({sup 60} Co), of IPEN. The glow curves present two peaks at 80 C and 220 C approximately. Calibration curves were obtained for doses between 50 Gy and 5 kGy. The results indicate that the sand samples can be used for high-doses dosimetry in several areas of applications of ionizing radiation. (Author)

  2. Crustal permeability

    Science.gov (United States)

    Gleeson, Tom; Ingebritsen, Steven E.

    2016-01-01

    Permeability is the primary control on fluid flow in the Earth’s crust and is key to a surprisingly wide range of geological processes, because it controls the advection of heat and solutes and the generation of anomalous pore pressures.  The practical importance of permeability – and the potential for large, dynamic changes in permeability – is highlighted by ongoing issues associated with hydraulic fracturing for hydrocarbon production (“fracking”), enhanced geothermal systems, and geologic carbon sequestration.  Although there are thousands of research papers on crustal permeability, this is the first book-length treatment.  This book bridges the historical dichotomy between the hydrogeologic perspective of permeability as a static material property and the perspective of other Earth scientists who have long recognized permeability as a dynamic parameter that changes in response to tectonism, fluid production, and geochemical reactions. 

  3. Reclaimability of the spent sand mixture – sand with bentonite – sand with furfuryl resin

    Directory of Open Access Journals (Sweden)

    J. Dańko

    2011-04-01

    Full Text Available Introduction of new binding materials and new technologies of their hardening in casting moulds and cores production requires theapplication of reclamation methods adequate to their properties as well as special devices realizing tasks. The spent sands circulationsystem containing the same kind of moulding and core sands is optimal from the point of view of the expected reclamation results.However, in the face of a significant variability of applied technologies and related to them various reclamation methods, the need - of theobtained reclamation products assessment on the grounds of systematic criteria and uniform bases – arises, with a tendency of indicatingwhich criteria are the most important for the given sand system. The reclaimability results of the mixture of the spent moulding sand withGeko S bentonite and the spent core sand with the Kaltharz 404U resin hardened by acidic hardener 100 T3, are presented in the paper.Investigations were performed with regard to the estimation of an influence of core sands additions (10 –25% on the reclaimed materialquality. Dusts and clay content in the reclaim, its chemical reaction (pH and ignition loss were estimated. The verification of the reclaiminstrumental assessment was performed on the basis of the technological properties estimation of moulding sand with bentonite, where the reclaimed material was used as a matrix.

  4. Soil gas measurements at high permeabilities and below foundation depth

    International Nuclear Information System (INIS)

    Johner, H.U; Surbeck, H.

    2000-01-01

    We started a project of soil gas measurements beneath houses. Since the foundations of houses often lie deeper than 0.5 to 1 m - the depth where soil gas measurements are often made - the first approach was to apply the method developed previously to deeper soil layers. The radon availability index (RAI), which was defined empirically, proved to be a reliable indicator for radon problems in nearby houses. The extreme values of permeability, non-Darcy flow and scale dependence of permeability stimulated the development of a multi-probe method. A hydrological model was applied to model the soil gas transport. The soil gas measurements below foundation depth provided a wealth of new information. A good classification of soil properties could be achieved. If soil gas measurements are to be made, the low permeability layer has to be traversed. A minimum depth of 1 .5 m is suggested, profiles to below the foundation depth are preferable. There are also implications for mitigation works. A sub-slab suction system should reach the permeable layer to function well. This also holds for radon wells. If a house is located on a slope, it is most convenient to install the sub-slab suction system on the hillside, as the foundation reaches the deepest levels there

  5. Oil sands and the environment

    Energy Technology Data Exchange (ETDEWEB)

    Seeley, R. [Shell Canada Ltd., Calgary, AB (Canada). Calgary Research Centre

    2004-07-01

    Oil sands are a significant resource for Alberta and Canada with continuing growth opportunity. There is a need to ensure sustainable development of the oil sands resources from a social, economic and environmental perspective. The industry has succeeded in terms of proven reserves, technology advancements, reduced operating costs, reliability and market accessibility. Some of the major challenges facing the industry include high capital cost, infrastructure, social services and keeping pace with growth. This presentation outlined the proactive measures that the oil sands industry has taken to manage environmental issues such as sulphur dioxide and nitrogen oxide emissions, greenhouse gases, water management and land reclamation. tabs., figs.

  6. Predicting chemically-induced skin reactions. Part II: QSAR models of skin permeability and the relationships between skin permeability and skin sensitization

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Vinicius M. [Laboratory of Molecular Modeling and Design, Faculty of Pharmacy, Federal University of Goiás, Goiânia, GO 74605-220 (Brazil); Laboratory for Molecular Modeling, Division of Chemical Biology and Medicinal Chemistry, Eshelman School of Pharmacy, University of North Carolina, Chapel Hill, NC 27599 (United States); Muratov, Eugene [Laboratory for Molecular Modeling, Division of Chemical Biology and Medicinal Chemistry, Eshelman School of Pharmacy, University of North Carolina, Chapel Hill, NC 27599 (United States); Laboratory of Theoretical Chemistry, A.V. Bogatsky Physical–Chemical Institute NAS of Ukraine, Odessa 65080 (Ukraine); Fourches, Denis [Laboratory for Molecular Modeling, Division of Chemical Biology and Medicinal Chemistry, Eshelman School of Pharmacy, University of North Carolina, Chapel Hill, NC 27599 (United States); Strickland, Judy; Kleinstreuer, Nicole [ILS/Contractor supporting the NTP Interagency Center for the Evaluation of Alternative Toxicological Methods (NICEATM), P.O. Box 13501, Research Triangle Park, NC 27709 (United States); Andrade, Carolina H. [Laboratory of Molecular Modeling and Design, Faculty of Pharmacy, Federal University of Goiás, Goiânia, GO 74605-220 (Brazil); Tropsha, Alexander, E-mail: alex_tropsha@unc.edu [Laboratory for Molecular Modeling, Division of Chemical Biology and Medicinal Chemistry, Eshelman School of Pharmacy, University of North Carolina, Chapel Hill, NC 27599 (United States)

    2015-04-15

    Skin permeability is widely considered to be mechanistically implicated in chemically-induced skin sensitization. Although many chemicals have been identified as skin sensitizers, there have been very few reports analyzing the relationships between molecular structure and skin permeability of sensitizers and non-sensitizers. The goals of this study were to: (i) compile, curate, and integrate the largest publicly available dataset of chemicals studied for their skin permeability; (ii) develop and rigorously validate QSAR models to predict skin permeability; and (iii) explore the complex relationships between skin sensitization and skin permeability. Based on the largest publicly available dataset compiled in this study, we found no overall correlation between skin permeability and skin sensitization. In addition, cross-species correlation coefficient between human and rodent permeability data was found to be as low as R{sup 2} = 0.44. Human skin permeability models based on the random forest method have been developed and validated using OECD-compliant QSAR modeling workflow. Their external accuracy was high (Q{sup 2}{sub ext} = 0.73 for 63% of external compounds inside the applicability domain). The extended analysis using both experimentally-measured and QSAR-imputed data still confirmed the absence of any overall concordance between skin permeability and skin sensitization. This observation suggests that chemical modifications that affect skin permeability should not be presumed a priori to modulate the sensitization potential of chemicals. The models reported herein as well as those developed in the companion paper on skin sensitization suggest that it may be possible to rationally design compounds with the desired high skin permeability but low sensitization potential. - Highlights: • It was compiled the largest publicly-available skin permeability dataset. • Predictive QSAR models were developed for skin permeability. • No concordance between skin

  7. Predicting chemically-induced skin reactions. Part II: QSAR models of skin permeability and the relationships between skin permeability and skin sensitization

    International Nuclear Information System (INIS)

    Alves, Vinicius M.; Muratov, Eugene; Fourches, Denis; Strickland, Judy; Kleinstreuer, Nicole; Andrade, Carolina H.; Tropsha, Alexander

    2015-01-01

    Skin permeability is widely considered to be mechanistically implicated in chemically-induced skin sensitization. Although many chemicals have been identified as skin sensitizers, there have been very few reports analyzing the relationships between molecular structure and skin permeability of sensitizers and non-sensitizers. The goals of this study were to: (i) compile, curate, and integrate the largest publicly available dataset of chemicals studied for their skin permeability; (ii) develop and rigorously validate QSAR models to predict skin permeability; and (iii) explore the complex relationships between skin sensitization and skin permeability. Based on the largest publicly available dataset compiled in this study, we found no overall correlation between skin permeability and skin sensitization. In addition, cross-species correlation coefficient between human and rodent permeability data was found to be as low as R 2 = 0.44. Human skin permeability models based on the random forest method have been developed and validated using OECD-compliant QSAR modeling workflow. Their external accuracy was high (Q 2 ext = 0.73 for 63% of external compounds inside the applicability domain). The extended analysis using both experimentally-measured and QSAR-imputed data still confirmed the absence of any overall concordance between skin permeability and skin sensitization. This observation suggests that chemical modifications that affect skin permeability should not be presumed a priori to modulate the sensitization potential of chemicals. The models reported herein as well as those developed in the companion paper on skin sensitization suggest that it may be possible to rationally design compounds with the desired high skin permeability but low sensitization potential. - Highlights: • It was compiled the largest publicly-available skin permeability dataset. • Predictive QSAR models were developed for skin permeability. • No concordance between skin sensitization and

  8. Consolidation of the formation sand by chemical methods

    Directory of Open Access Journals (Sweden)

    Mariana Mihočová

    2006-10-01

    Full Text Available The sand control by consolidation involves the process of injecting chemicals into the naturally unconsolidated formation to provide an in situ grain-to-grain cementation. The sand consolidation chemicals are available for some 30 years. Several types of consolidating material were tried. Presently available systems utilize solidified plastics to provide the cementation. These systems include phenol resin, phenol-formaldehyde, epoxy, furan and phenolic-furfuryl.The sand consolidation with the steam injection is a novel technique. This process provides a highly alkaline liquid phase and temperatures to 300 °C to geochemically create cements by interacting with the dirty sand.While the formation consolidation has widely applied, our experience has proved a high level of success.

  9. An Integrated Rock Typing Approach for Unraveling the Reservoir Heterogeneity of Tight Sands in the Whicher Range Field of Perth Basin, Western Australia

    DEFF Research Database (Denmark)

    Ilkhchi, Rahim Kadkhodaie; Rezaee, Reza; Harami, Reza Moussavi

    2014-01-01

    Tight gas sands in Whicher Range Field of Perth Basin show large heterogeneity in reservoir characteristics and production behavior related to depositional and diagenetic features. Diagenetic events (compaction and cementation) have severely affected the pore system. In order to investigate...... the petrophysical characteristics, reservoir sandstone facies were correlated with core porosity and permeability and their equivalent well log responses to describe hydraulic flow units and electrofacies, respectively. Thus, very tight, tight, and sub-tight sands were differentiated. To reveal the relationship...... between pore system properties and depositional and diagenetic characteristics in each sand type, reservoir rock types were extracted. The identified reservoir rock types are in fact a reflection of internal reservoir heterogeneity related to pore system properties. All reservoir rock types...

  10. Bentonite Permeability at Elevated Temperature

    Directory of Open Access Journals (Sweden)

    Katherine A. Daniels

    2017-01-01

    Full Text Available Repository designs frequently favour geological disposal of radioactive waste with a backfill material occupying void space around the waste. The backfill material must tolerate the high temperatures produced by decaying radioactive waste to prevent its failure or degradation, leading to increased hydraulic conductivity and reduced sealing performance. The results of four experiments investigating the effect of temperature on the permeability of a bentonite backfill are presented. Bentonite is a clay commonly proposed as the backfill in repository designs because of its high swelling capacity and very low permeability. The experiments were conducted in two sets of purpose-built, temperature controlled apparatus, designed to simulate isotropic pressure and constant volume conditions within the testing range of 4–6 MPa average effective stress. The response of bentonite during thermal loading at temperatures up to 200 °C was investigated, extending the previously considered temperature range. The results provide details of bentonite’s intrinsic permeability, total stress, swelling pressure and porewater pressure during thermal cycles. We find that bentonite’s hydraulic properties are sensitive to thermal loading and the type of imposed boundary condition. However, the permeability change is not large and can mostly be accounted for by water viscosity changes. Thus, under 150 °C, temperature has a minimal impact on bentonite’s hydraulic permeability.

  11. Western Gas Sands Project. Status report, 1 September 1979-30 September 1979

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    This report summarizes progress of the government-sponsored projects directed toward increasing gas production from the low-permeability gas sands of the western United States. Bartlesville Energy Technology Center continued work on rock-fluid interaction and advanced logging techniques. Lawrence Livermore Laboratory continued experimental and theoretical work on hydraulic fracturing mechanics and analysis of well test data. Los Alamos Scientific Laboratory continued work on permeability and porosity determination of core samples and geological support studies. Sandia Laboratories continued work on their EGR Instrumentation and Diagnostic Program. Cyclic gas injection continued at Colorado Interstate Gas Company's Miller No. 1 and Sprague No. 1 wells. The DOE Well Test Facility is continuing to provide technical support to the Gas Research Institute/Rio Blanco Natural Gas MHF experiment. The Gas Producing Enterprises, Inc. Natural Buttes Unit wells continued to flow to sales. The Mitchell Energy Corporation Muse-Duke No. 1 was opened after a 28-day shut-in period. The hydraulic fracturing containment experiment continued for the Sandia-mineback program.

  12. Relationship between permeability and damage in concretes at high temperature

    International Nuclear Information System (INIS)

    Dal Pont, St.

    2004-09-01

    Due to its technical and economical advantages, concrete is nowadays the most used building material in civil engineering. Even if its use is known since nearly two centuries, its behavior has not been yet completely explained due to the complexity of its porous microstructure. This fact is quite evident under particular conditions such as, by instance, during an elevation of temperature. This condition can mainly occur in two cases: due to a casualty (e.g. a fire) or in normal use conditions (e.g. storage of nuclear rejects). This work aims at contributing to the study of the phenomena that can be observed in concrete exposed to high temperatures and, in particular, focuses on the study of the evolution of intrinsic permeability. The characterisation of permeability (which is hardly measurable in hot conditions) is necessary for describing and modelling transport phenomena which occur in porous media. An experimental study has been made in collaboration with the CEA. A real-scale hollow cylinder has been instrumented with gauges for studying the evolution of temperature and gas pressure fields inside concrete. Later, the cylinder has been then numerically modelled by means of a thermo-hydro-chemical (THC) and a thermo-hydro-chemo-mechanical (THCM) model. The THC model, implemented by means of the finite volume method, has allowed a first, qualitative study of the behaviour of concrete submitted to high temperature. This model, which, for sake of simplicity, has neglected all mechanical effects, has allowed the description of the main phenomena occurring inside concrete: mass transport, phase changes, microstructure evolution. Later, the modelling has been completed by means of the THCM model using the Hitecosp code, implemented by means of the finite element method at the university of Padua. This code allows a very complete description of the phenomena occurring inside concrete and takes into consideration the mechanical behavior of concrete by means of an

  13. Gadolinium prevents high airway pressure-induced permeability increases in isolated rat lungs.

    Science.gov (United States)

    Parker, J C; Ivey, C L; Tucker, J A

    1998-04-01

    To determine the initial signaling event in the vascular permeability increase after high airway pressure injury, we compared groups of lungs ventilated at different peak inflation pressures (PIPs) with (gadolinium group) and without (control group) infusion of 20 microM gadolinium chloride, an inhibitor of endothelial stretch-activated cation channels. Microvascular permeability was assessed by using the capillary filtration coefficient (Kfc), a measure of capillary hydraulic conductivity. Kfc was measured after ventilation for 30-min periods with 7, 20, and 30 cmH2O PIP with 3 cmH2O positive end-expiratory pressure and with 35 cmH2O PIP with 8 cmH2O positive end-expiratory pressure. In control lungs, Kfc increased significantly to 1.8 and 3.7 times baseline after 30 and 35 cmH2O PIP, respectively. In the gadolinium group, Kfc was unchanged from baseline (0.060 +/- 0.010 ml . min-1 . cmH2O-1 . 100 g-1) after any PIP ventilation period. Pulmonary vascular resistance increased significantly from baseline in both groups before the last Kfc measurement but was not different between groups. These results suggest that microvascular permeability is actively modulated by a cellular response to mechanical injury and that stretch-activated cation channels may initiate this response through increases in intracellular calcium concentration.

  14. Transformable ferroelectric control of dynamic magnetic permeability

    Science.gov (United States)

    Jiang, Changjun; Jia, Chenglong; Wang, Fenglong; Zhou, Cai; Xue, Desheng

    2018-02-01

    Magnetic permeability, which measures the response of a material to an applied magnetic field, is crucial to the performance of magnetic devices and related technologies. Its dynamic value is usually a complex number with real and imaginary parts that describe, respectively, how much magnetic power can be stored and lost in the material. Control of permeability is therefore closely related to energy redistribution within a magnetic system or energy exchange between magnetic and other degrees of freedom via certain spin-dependent interactions. To avoid a high power consumption, direct manipulation of the permeability with an electric field through magnetoelectric coupling leads to high efficiency and simple operation, but remains a big challenge in both the fundamental physics and material science. Here we report unambiguous evidence of ferroelectric control of dynamic magnetic permeability in a Co /Pb (Mg1/3Nb2/3) 0.7Ti0.3O3 (Co/PMN-PT) heterostructure, in which the ferroelectric PMN-PT acts as an energy source for the ferromagnetic Co film via an interfacial linear magnetoelectric interaction. The electric field tuning of the magnitude and line shape of the permeability offers a highly localized means of controlling magnetization with ultralow power consumption. Additionally, the emergence of negative permeability promises a new way of realizing functional nanoscale metamaterials with adjustable refraction index.

  15. Eastern Scheldt Sand, Baskarp Sand No. 15

    DEFF Research Database (Denmark)

    Andersen, A. T; Madsen, E. B.; Schaarup-Jensen, A. L.

    The present data report contains data from 13 drained triaxial tests, performed on two different sand types in the Soil Mechanics Laboratory at Aalborg University in March, 1997. Two tests have been performed on Baskarp Sand No. 15, which has already ken extensively tested in the Soil Mechanics...... Laboratory. The remaining 11 triaxial tests have ben performed on Eastern Scheldt Sand, which is a material not yet investigated at the Soil Mechanics Laboratory. In the first pari of this data report, the characteristics of the two sand types in question will be presented. Next, a description...... will described. In this connection, the procedure for preparation of the soil specimens will be presented, and the actual performance of the tests will be briefly outlined. Finally, the procedure for processing of the measurements from the laboratory in order to obtain usable data will be described. The final...

  16. High frequency permeability and permittivity spectra of BiFeO{sub 3}/(CoTi)-BaM ferrite composites

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Yun; Wu, Xiaohan; Li, Qifan; Yu, Ting; Feng, Zekun, E-mail: fengzekun@hust.edu.cn [School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 (China); Chen, Zhongyan [School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 (China); Jiangmen Magsource New Material CO., LTD., 529000 Guangdong (China); Su, Zhijuan; Chen, Yajie; Harris, Vincent G. [Center for Microwave Magnetic Materials and Integrated Circuits, and Department of Electrical and Computer Engineering, Northeastern University, Boston, Massachusetts 02115 (United States)

    2015-05-07

    Low magnetic loss ferrite composites consisting of Ba(CoTi){sub 1.2}Fe{sub 9.6}O{sub 19} and BiFeO{sub 3} (BFO) ferrite were investigated for permeability, permittivity, and high frequency losses at 10 MHz–1 GHz. The phase fraction of BiFeO{sub 3} was quantitatively analyzed by X-ray diffraction measurements. An effective medium approach was employed to predict the effective permeability and permittivity for the ferrite composites, which was found to be in good agreement with experimental data. The experiment demonstrated low magnetic losses (<0.128), modified by BFO phase fraction, while retaining high permeability (∼10.86) at 300 MHz. More importantly, the BFO phase resulted in a reduction of magnetic loss by 32%, as BFO phase increased from 2.7 vol. % to 12.6 vol. %. The effect of BFO phase on magnetic and dielectric properties revealed great potential for use in the miniaturization of high efficiency antennas.

  17. Predicting chemically-induced skin reactions. Part II: QSAR models of skin permeability and the relationships between skin permeability and skin sensitization

    Science.gov (United States)

    Alves, Vinicius M.; Muratov, Eugene; Fourches, Denis; Strickland, Judy; Kleinstreuer, Nicole; Andrade, Carolina H.; Tropsha, Alexander

    2015-01-01

    Skin permeability is widely considered to be mechanistically implicated in chemically-induced skin sensitization. Although many chemicals have been identified as skin sensitizers, there have been very few reports analyzing the relationships between molecular structure and skin permeability of sensitizers and non-sensitizers. The goals of this study were to: (i) compile, curate, and integrate the largest publicly available dataset of chemicals studied for their skin permeability; (ii) develop and rigorously validate QSAR models to predict skin permeability; and (iii) explore the complex relationships between skin sensitization and skin permeability. Based on the largest publicly available dataset compiled in this study, we found no overall correlation between skin permeability and skin sensitization. In addition, cross-species correlation coefficient between human and rodent permeability data was found to be as low as R2=0.44. Human skin permeability models based on the random forest method have been developed and validated using OECD-compliant QSAR modeling workflow. Their external accuracy was high (Q2ext = 0.73 for 63% of external compounds inside the applicability domain). The extended analysis using both experimentally-measured and QSAR-imputed data still confirmed the absence of any overall concordance between skin permeability and skin sensitization. This observation suggests that chemical modifications that affect skin permeability should not be presumed a priori to modulate the sensitization potential of chemicals. The models reported herein as well as those developed in the companion paper on skin sensitization suggest that it may be possible to rationally design compounds with the desired high skin permeability but low sensitization potential. PMID:25560673

  18. UV-deprived coloration reduces success in mate acquisition in male sand lizards (Lacerta agilis.

    Directory of Open Access Journals (Sweden)

    Mats Olsson

    Full Text Available Recent work on animal signals has revealed a wide occurrence of UV signals in tetrapods, in particular birds, but also in lizards (and perhaps other Squamate reptiles. Our previous work on the Swedish sand lizard (Lacerta agilis has verified, both in correlative selection analyses in the wild and with laboratory and field experiments, the importance of the green 'badge' on the body sides of adult males for securing mating opportunities, probably mostly through deterring rival males rather than attracting females. The role of UV in communication has, however, never been examined.Here we show that when measured immediately after spring skin shedding, there is also signaling in the UV. By UV-depriving the signal (reflectance with sun block chemicals fixated with permeable, harmless spray dressing, we show that males in the control group (spray dressing only had significantly higher success in mate acquisition than UV-deprived males.These results suggest that at least two colour traits in sand lizards, badge area and UV, contribute to rival deterrence and/or female choice on UV characters, which elevates success in mate acquisition in UV intact male sand lizards.

  19. The Influences of a Clay Lens on the Hyporheic Exchange in a Sand Dune

    Directory of Open Access Journals (Sweden)

    Chengpeng Lu

    2018-06-01

    Full Text Available A laboratory flume simulating a riverbed sand dune containing a low-permeability clay lens was constructed to investigate its influence on the quality and quantity of hyporheic exchange. By varying the depths and spatial locations of the clay lens, 24 scenarios and one blank control experiment were created. Dye tracers were applied to visualize patterns of hyporheic exchange and the extent of the hyporheic zone, while NaCl tracers were used to calculate hyporheic fluxes. The results revealed that the clay lens reduces hyporheic exchange and that the reduction depends on its spatial location. In general, the effect was stronger when the lens was in the center of the sand dune. The effect weakened when the lens was moved near the boundary of the sand dune. A change in horizontal location had a stronger influence on the extent of the hyporheic zone compared with a change in depth. The size of the hyporheic zone changed with the depth and position of the clay lens. There was a maximum of hyporheic extent with the lens at a depth of 0.1 m caused by changes of water flow paths.

  20. High-temperature expansion and knock-out properties of moulding sands with water glass

    Directory of Open Access Journals (Sweden)

    Major-Gabryś K.

    2007-01-01

    Full Text Available The article focuses on the topic of improving the knock-out properties of moulding sand with water glass and ester hardener. It is settled that the cause of worse knock-out properties of moulding sand can be brought by their thermal expansion in increased temperatures. There is a presentation of the influence of different additives, containing Al2O3, on moulding sands’ expansion in increased temperatures. Within the frames of research, there was an elaboration of the influence of authors own additive- Glassex, on the expansion phenomenon of moulding sands with water glass and ester hardener. It is concluded, that the new additive stops the expansion of moulding sands and as well it improves their knock-out properties.

  1. Effects of specific surface area and porosity on cube counting fractal dimension, lacunarity, configurational entropy, and permeability of model porous networks: Random packing simulations and NMR micro-imaging study

    Science.gov (United States)

    Lee, Bum Han; Lee, Sung Keun

    2013-07-01

    Despite the importance of understanding and quantifying the microstructure of porous networks in diverse geologic settings, the effects of the specific surface area and porosity on the key structural parameters of the networks have not been fully understood. We performed cube-counting fractal dimension (Dcc) and lacunarity analyses of 3D porous networks of model sands and configurational entropy analysis of 2D cross sections of model sands using random packing simulations and nuclear magnetic resonance (NMR) micro-imaging. We established relationships among porosity, specific surface area, structural parameters (Dcc and lacunarity), and the corresponding macroscopic properties (configurational entropy and permeability). The Dcc of the 3D porous networks increases with increasing specific surface area at a constant porosity and with increasing porosity at a constant specific surface area. Predictive relationships correlating Dcc, specific surface area, and porosity were also obtained. The lacunarity at the minimum box size decreases with increasing porosity, and that at the intermediate box size (∼0.469 mm in the current model sands) was reproduced well with specific surface area. The maximum configurational entropy increases with increasing porosity, and the entropy length of the pores decreases with increasing specific surface area and was used to calculate the average connectivity among the pores. The correlation among porosity, specific surface area, and permeability is consistent with the prediction from the Kozeny-Carman equation. From the relationship between the permeability and the Dcc of pores, the permeability can be expressed as a function of the Dcc of pores and porosity. The current methods and these newly identified correlations among structural parameters and properties provide improved insights into the nature of porous media and have useful geophysical and hydrological implications for elasticity and shear viscosity of complex composites of rock

  2. Estimates of hydraulic fracturing (Frac) sand production, consumption, and reserves in the United States

    Science.gov (United States)

    Bleiwas, Donald I.

    2015-01-01

    The practice of fracturing reservoir rock in the United States as a method to increase the flow of oil and gas from wells has a relatively long history and can be traced back to 1858 in Fredonia, New York, when a gas well situated in shale of the Marcellus Formation was successfully fractured using black powder as a blasting agent. Nearly all domestic hydraulic fracturing, often referred to as hydrofracking or fracking, is a process where fluids are injected under high pressure through perforations in the horizontal portion of a well casing in order to generate fractures in reservoir rock with low permeability (“tight”). Because the fractures are in contact with the well bore they can serve as pathways for the recovery of gas and oil. To prevent the fractures generated by the fracking process from closing or becoming obstructed with debris, material termed “proppant,” most commonly high-silica sand, is injected along with water-rich fluids to maintain or “prop” open the fractures. The first commercial application of fracking in the oil and gas industry took place in Oklahoma and Texas during the 1940s. In 1949, over 300 wells, mostly vertical, were fracked (ALL Consulting, LLC, 2012; McGee, 2012; Veil, 2012) and used silica sand as a proppant (Fracline, 2011). The resulting increase in well productivity demonstrated the significant potential that fracking might have for the oil and gas industry.

  3. Experimental research on accelerated consolidation using filter jackets in fine oil sands tailings

    Energy Technology Data Exchange (ETDEWEB)

    Tol van, F.; Yao, Y.; Paaseen van, L.; Everts, B. [Delft Univ. of Technology, Delft (Netherlands). Dept. of Geotechnology

    2010-07-01

    This PowerPoint presentation discussed prefabricated vertical drains used to enhance the dewatering of fine oil sand tailings. Filtration tests conducted with thickened tailings on standard PVD jackets were presented. Potential clogging mechanisms included clogging of the filter jacket by particles, blinding of the jackets by filter cake, the decreased permeability of consolidated tailings around the drain, and the clogging of the filter jacket with bitumen. Polypropylene and polyester geotextiles were tested in a set-up that replicated conditions observed at 5 to 10 meters below mud level in an oil sand tailings pond. A finite strain consolidation model was used to interpret results obtained in the experimental study. The relationship between the void ratio and hydraulic conductivity was investigated. Results of the study showed that neither the bitumen nor the fines in the sludge cause serious blinding of the filter jackets during the 40 day test period. The consolidation process was adequately simulated with the finite strain consolidation model. tabs., figs.

  4. Numerical simulation of flow and compression of green sand

    DEFF Research Database (Denmark)

    Hovad, Emil

    The focus of the industrial PhD project was concentrated on the production of the sand mold (green sand) which gives the cast component its final geometrical shape. In order to ensure a high quality of the cast component, it is important to control the manufacturing process of the mold itself so...... that it is homogeneous and stable. Therefore gaining a basic understanding of how the flow and deposition of green sand should be characterized and modelled was important, so that it could be used for simulation of the manufacturing process of the sand mold. The flowability of the green sand is important when the sand...... flows down through the hopper filling the chamber with sand during the sand shot. The flowability of green sand is mostly governed by the amount of water and bentonite which both decrease it. The flowability and the internal forces thus control how well you can fill a complex mold geom-etry in which...

  5. Surface-subsurface turbulent interaction at the interface of a permeable bed: influence of the wall permeability

    Science.gov (United States)

    Kim, T.; Blois, G.; Best, J.; Christensen, K. T.

    2017-12-01

    Coarse-gravel river beds possess a high degree of permeability. Flow interactions between surface and subsurface flow across the bed interface is key to a number of natural processes occurring in the hyporheic zone. In fact, it is increasingly recognized that these interactions drive mass, momentum and energy transport across the interface, and consequently control biochemical processes as well as stability of sediments. The current study explores the role of the wall permeability in surface and subsurface flow interaction under controlled experimental conditions on a physical model of a gravel bed. The present wall model was constructed by five layers of cubically arranged spheres (d=25.4mm, where d is a diameter) providing 48% of porosity. Surface topography was removed by cutting half of a diameter on the top layer of spheres to render the flow surface smooth and highlight the impact of the permeability on the overlying flow. An impermeable smooth wall was also considered as a baseline of comparison for the permeable wall flow. To obtain basic flow statistics, low-frame-rate high-resolution PIV measurements were performed first in the streamwise-wall-normal (x-y) plane and refractive-index matching was employed to optically access the flow within the permeable wall. Time-resolved PIV experiments in the same facility were followed to investigate the flow interaction across the wall interface in sptaio-temporal domain. In this paper, a detailed analysis of the first and second order velocity statistics as well as the amplitude modulation for the flow overlying the permeable smooth wall will be presented.

  6. Influence of Local Sand on the Physicomechanical Comportment and Durability of High Performance Concrete

    Directory of Open Access Journals (Sweden)

    Nadia Tebbal

    2016-01-01

    Full Text Available This research consists of incorporating the crushed sand (CS in the composition of a concrete and studies the effect of its gradual replacement by the sand dune (SD on sustainability of high performance concrete (HPC in aggressive environments. The experimental study shows that the parameters of workability of HPC are improved when the CS is partially replaced by the SD (1/3 additional quantities of water is needed to meet the workability properties. The mechanical strengths decrease by adding the SD to CS, but they reach acceptable values with CS in moderate dosages. The HPC performances are significantly better than the control concrete made up with the same aggregates. The specification tests of durability show that the water absorbing coefficients by capillarity increase after adding SD to the CS.

  7. Suitability assessment of grey water quality treated with an upflow-downflow siliceous sand/marble waste filtration system for agricultural and industrial purposes.

    Science.gov (United States)

    Chaabane, Safa; Riahi, Khalifa; Hamrouni, Hédi; Thayer, Béchir Ben

    2017-04-01

    The present study examines the suitability assessment of an upflow-downflow siliceous sand/marble waste filtration system for treatment and reuse of grey water collected from bathrooms of the student residential complex at the Higher Institute of Engineering Medjez El Bab (Tunisia). Once the optimization of grey water pre-treatment system has been determined, the filtration system was operated at different hydraulic loading rate and media filter proportions in order to assess the suitability of treated grey water for irrigational purpose according to salinity hazard, sodium hazard, magnesium hazard, permeability index, water infiltration rate, and widely used graphical methods. Suitability of the treated grey water for industrial purpose was evaluated in terms of foaming, corrosion, and scaling. Under optimal operational conditions, results reveals that treated grey water samples with an upflow-downflow siliceous sand/marble waste filtration system may be considered as a good and an excellent water quality suitable for irrigation purpose. However, treated grey water was found not appropriate for industrial purpose due to high concentrations of calcium and sodium that can generate foaming and scaling harm to boilers. These results suggest that treated grey water with an upflow-downflow siliceous sand/marble waste filtration system would support production when used as irrigation water.

  8. Tacrolimus is a class II low-solubility high-permeability drug: the effect of P-glycoprotein efflux on regional permeability of tacrolimus in rats.

    Science.gov (United States)

    Tamura, Shigeki; Ohike, Atsuo; Ibuki, Rinta; Amidon, Gordon L; Yamashita, Shinji

    2002-03-01

    The objective of this study is to investigate the role of P-glycoprotein (P-gp), a membrane efflux pump associated with multidrug resistance (MDR) and a known substrate for tacrolimus, in determining the regional intestinal permeability of tacrolimus in rats. Thus, isolated segments of rat jejunum, ileum, or colon were perfused with tacrolimus solutions containing polyethoxylated hydrogenated castor oil 60 surfactant, and with or without verapamil, a P-gp substrate used to reverse the MDR phenotype. The results indicated that the intrinsic permeability of tacrolimus in the jejunum, calculated on the basis of the concentration of non-micellized free tacrolimus, was quite high ( approximately 1.4 x 10(-4) cm/s). The apparent permeability (P(app)) in the jejunum was unaffected by the presence of verapamil; however, the P(app) in the ileum and the colon increased significantly in the presence of verapamil and were similar to the values observed in the jejunum. The results suggest that systemic absorption of tacrolimus from the gastrointestinal tract could be significantly affected by P-gp efflux mechanisms. It is also possible that differences in P-gp function at various intestinal sites in a subject or at a given intestinal site in various subjects could lead to large intra- and interindividual variability in bioavailability of tacrolimus following oral administration. Copyright 2002 Wiley-Liss, Inc. and the American Pharmaceutical Association .

  9. Hydraulic properties of domestic bentonite-sand mixture as a backfill material in the high-level waste repository

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Won Jin; Lee, Jae Owan; Kang, Chul Hyung [Korea Atomic Energy Research Institute, Taejeon (Korea)

    2000-02-01

    This study is intended to investigate the effect of dry density and sand content on hydraulic conductivities of bentonite-sand mixtures. The hydraulic conductivities of bentonite-sand mixtures with dry densities of 1.6 and 1.8 Mg/m{sup 3} are lower than 10{sup -11} m/s if their sand contents are less than 70 wt%. However at the sand content of 90 wt%, the hydraulic conductivities increase sharply. In the case of sand contents not exceeding 70 wt%, the logarithm of the hydraulic conductivity of bentonite-sand mixture increase linearly with increasing sand content. The hydraulic conductivity of the mixture can be explained using 'effective clay dry density' concept. 16 refs., 21 figs., 5 tabs. (Author)

  10. Compressive Strength of Compacted Clay-Sand Mixes

    Directory of Open Access Journals (Sweden)

    Faseel Suleman Khan

    2014-01-01

    Full Text Available The use of sand to improve the strength of natural clays provides a viable alternative for civil infrastructure construction involving earthwork. The main objective of this note was to investigate the compressive strength of compacted clay-sand mixes. A natural clay of high plasticity was mixed with 20% and 40% sand (SP and their compaction and strength properties were determined. Results indicated that the investigated materials exhibited a brittle behaviour on the dry side of optimum and a ductile behaviour on the wet side of optimum. For each material, the compressive strength increased with an increase in density following a power law function. Conversely, the compressive strength increased with decreasing water content of the material following a similar function. Finally, the compressive strength decreased with an increase in sand content because of increased material heterogeneity and loss of sand grains from the sides during shearing.

  11. Surface sedimentation at permeable pavement systems

    DEFF Research Database (Denmark)

    Støvring, Jan; Dam, Torben; Jensen, Marina Bergen

    2018-01-01

    Newly installed permeable pavement (PP) systems provide high surface infiltration capacity, but the accumulation of sediments causes a decrease in capacity over time, eventually leading to surface clogging. With the aim of investigating local sedimentation processes and the importance of restorat......Newly installed permeable pavement (PP) systems provide high surface infiltration capacity, but the accumulation of sediments causes a decrease in capacity over time, eventually leading to surface clogging. With the aim of investigating local sedimentation processes and the importance...

  12. Suitability of Torrent Permeability Tester to measure air-permeability of covercrete

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, C.; Gonzales-Gasca, C. [Institute of Construction Sciences ' Eduardo Torroja' , Madrid (Spain); Torrent, R. [Portland Cement Institute, (Argentina)

    2000-07-01

    Suitability of the Torrent Permeability Tester (TPT) to measure the permeability of covercrete to air, both in the laboratory and the field, is investigated, and test results obtained in laboratory studies are discussed. The tests performed included the determination of air permeability (TPT method), oxygen permeability (Cembureau method) and capillary suction, rapid chloride permeability test (ASTM C 1202), as well as a one-year carbonation depth test. Concrete specimens of various compositions and curing regimes were used in the tests; the gas-permeability tests were repeated on the same specimens after 28 days, than again at 6 months and 12 months. Test results confirmed the suitability of the TPT as a useful tool in the characterization of the quality the of concrete cover. It was found to be sensitive to changes in concrete quality; repeatable for sensitive properties such as gas permeability ; also, it was found to correlate well with other durability-related properties. 10 refs., 8 tabs., 8 figs.

  13. Small intestinal efflux mediated by MRP2 and BCRP shifts sulfasalazine intestinal permeability from high to low, enabling its colonic targeting.

    Science.gov (United States)

    Dahan, Arik; Amidon, Gordon L

    2009-08-01

    Sulfasalazine is characterized by low intestinal absorption, which essentially enables its colonic targeting and therapeutic action. The mechanisms behind this low absorption have not yet been elucidated. The purpose of this study was to investigate the role of efflux transporters in the intestinal absorption of sulfasalazine as a potential mechanism for its low small-intestinal absorption and colonic targeting following oral administration. The effects of P-glycoprotein (P-gp), multidrug resistance-associated protein 2 (MRP2), and breast cancer resistance protein (BCRP) inhibitors on sulfasalazine bidirectional permeability were studied across Caco-2 cell monolayers, including dose-response analysis. Sulfasalazine in vivo permeability was then investigated in the rat jejunum by single-pass perfusion, in the presence vs. absence of inhibitors. Sulfasalazine exhibited 19-fold higher basolateral-to-apical (BL-AP) than apical-to-basolateral (AP-BL) Caco-2 permeability, indicative of net mucosal secretion. MRP2 inhibitors (MK-571 and indomethacin) and BCRP inhibitors [fumitremorgin C (FTC) and pantoprazole] significantly increased AP-BL and decreased BL-AP sulfasalazine Caco-2 transport in a concentration-dependent manner. No effect was observed with the P-gp inhibitors verapamil and quinidine. The IC50 values of the specific MRP2 and BCRP inhibitors MK-571 and FTC on sulfasalazine secretion were 21.5 and 2.0 microM, respectively. Simultaneous inhibition of MRP2 and BCRP completely abolished sulfasalazine Caco-2 efflux. Without inhibitors, sulfasalazine displayed low (vs. metoprolol) in vivo intestinal permeability in the rat model. MK-571 or FTC significantly increased sulfasalazine permeability, bringing it to the low-high permeability boundary. With both MK-571 and FTC present, sulfasalazine displayed high permeability. In conclusion, efflux transport mediated by MRP2 and BCRP, but not P-gp, shifts sulfasalazine permeability from high to low, thereby enabling its

  14. Fontainebleau Sand

    DEFF Research Database (Denmark)

    Leth, Caspar Thrane

    2006-01-01

    The report is a summary of results from laboratory tests in the geotechncial research group on Fontainebleau sand.......The report is a summary of results from laboratory tests in the geotechncial research group on Fontainebleau sand....

  15. The Geodiversity in Drift Sand Landscapes of The Netherlands

    Science.gov (United States)

    van den Ancker, Hanneke; Jungerius, Pieter Dirk; Riksen, Michel

    2015-04-01

    The authors carried out detailed field studies of more than twelve drift sand landscapes in The Netherlands. The objective of these studies was to restore Natura-2000 values by restoring the wind activity. Active drift sands occur almost exclusively in The Netherlands, Natura 2000 habitat 2330 'Inland dunes with open Corynephorus and Agrostis grasslands', for which reason our country is largely responsible for this European landscape. Active drift sands had almost disappeared for two reasons: first, the stabilization of the drift sands by air pollution, mainly nitrogen, which stimulates the growth of algae and grasses that initiate soil formation, and second, by the growth of forests surrounding the sands, which decreases the wind force. The restoration studies revealed differences in the geodiversity between and within the drift sand areas. Whereas the drift sands on geological and soil maps show as almost homogenous areas, they have in fact highly variable geo-conditions of which examples will be given. These geodiversity aspects concern differences in geomorphological structure, origin, sediments and age of the drift sands. Differences in wind and water erosion, trampling and soil formation add to the geodiversity within the drift sand areas. Especially in the primary stages of succession the differences in geodiversity are relevant for the Natura-2000 values. We discerned three main types of active sands. Firstly, the impressive drift sands with large parabolic dune structures, often consisting of series of interlocking parabolic dunes. They developed from the northeast towards the southwest, against the direction of the dominant wind, and must have taken centuries to develop. Small parts of these systems are still active, other parts show different degrees of soil formation. Their origin is still unclear but probably dates from medieval times (Heidinga, 1985, Jungerius & Riksen, 2008). Second are the drift sand areas with irregular hills from 0.5 to about 2

  16. Cell permeability beyond the rule of 5.

    Science.gov (United States)

    Matsson, Pär; Doak, Bradley C; Over, Björn; Kihlberg, Jan

    2016-06-01

    Drug discovery for difficult targets that have large and flat binding sites is often better suited to compounds beyond the "rule of 5" (bRo5). However, such compounds carry higher pharmacokinetic risks, such as low solubility and permeability, and increased efflux and metabolism. Interestingly, recent drug approvals and studies suggest that cell permeable and orally bioavailable drugs can be discovered far into bRo5 space. Tactics such as reduction or shielding of polarity by N-methylation, bulky side chains and intramolecular hydrogen bonds may be used to increase cell permeability in this space, but often results in decreased solubility. Conformationally flexible compounds can, however, combine high permeability and solubility, properties that are keys for cell permeability and intestinal absorption. Recent developments in computational conformational analysis will aid design of such compounds and hence prediction of cell permeability. Transporter mediated efflux occurs for most investigated drugs in bRo5 space, however it is commonly overcome by high local intestinal concentrations on oral administration. In contrast, there is little data to support significant impact of transporter-mediated intestinal absorption in bRo5 space. Current knowledge of compound properties that govern transporter effects of bRo5 drugs is limited and requires further fundamental and comprehensive studies. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. The effect of different surface materials on runoff quality in permeable pavement systems.

    Science.gov (United States)

    Li, Haiyan; Li, Zhifei; Zhang, Xiaoran; Li, Zhuorong; Liu, Dongqing; Li, Tanghu; Zhang, Ziyang

    2017-09-01

    To investigate the effect of different permeable pavement surface materials on the removal of pollutants from urban storm-runoff, six commonly surface materials (porous asphalt, porous concrete, cement brick, ceramic brick, sand base brick, and shale brick) were selected in this study and the research was carried out by column experiments. Except the concentrations of total suspended solids (TSS), chemical oxygen demand (COD), ammonia nitrogen (NH 4 -N), nitrate nitrogen (NO 3 -N), total nitrogen (TN), and total phosphorus (TP) in the influent and effluent that were measured, the removal mechanism of pollutants was discussed further. The results indicate that the surface materials influence the removal efficiency of pollutants greatly and have different effects on certain pollutant. Furthermore, the physical interception and adsorption would be the main mechanism for the removal of pollutants from runoff. For example, for all surface materials, the average removal efficiency of TSS is nearly about 90.0% because of physical interception. Due to the amount of iron oxide, the removal efficiency of COD, NO 3 -N, and TN of shale brick was 88.2, 35.1, and 17.5%, respectively. NH 4 -N and TN can be easily removed by porous asphalt due to the high content of organic matter. By lacking of useful adsorption sites, all the surface materials had little effect on the removal of TP from runoff. This research could offer useful guidelines for the better design of permeable pavement system and promote the insight into the removal mechanism of pollutants in permeable pavement system. Graphical abstract Different types of materials for the different types of pollutants in the runoff purification capacity were significantly different, overall, shale brick and porous asphalt Shale bricks and porous asphalt have a better purification effect according to the six kinds of materials.

  18. Developing new markets for oil sands products

    International Nuclear Information System (INIS)

    Crandall, G.

    2004-01-01

    This paper presents a review by Purvin and Gertz of western Canadian crude oil supply. This energy consulting firm provides advise to the energy sector. It suggests that oil sands production will surpass declining conventional production. Oil sands supply includes bitumen, synthetic crude oil (SCO), and diluent. It is forecasted that oil sands will increase from 42 per cent of western supply in 2002 to 78 per cent in 2015. The potential of Alberta's oil sands was discussed along with a recent study of refined products and petrochemicals from bitumen. Upgrading, refining and petrochemical case studies were presented. The author examined if a Canadian oil sands upgrading project with high capital costs can be competitive with competing projects in the United States and internationally. In addition to supply and demand issues, the presentation examined infrastructure capability and market potential in the United States. The economic potential and risks of preferred business cases compared to upgrading to SCO were also evaluated. 15 figs

  19. Road drainage system using highly compressible and long-term permeable geotextile. Evaluation of long-term permeability and application to trafficability in a tunnel; Kotaiatsu mezumari taikyugata geotextile haisuizai wo mochiita roban haisui taisaku. Mezumari taikyusei no hyoka to tunnel konai kasetsu doro no trafficability kaizen koka

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, S.; Yamagishi, K.; Hirama, K.; Ueno, T. [Obayashi Corp., Tokyo (Japan)

    1998-07-10

    A geotextile drainage material called ART-DRAIN has been developed. It was applied to temporary roads in a tunnel, to evaluate its permeability through a long-term permeability test using a model. The ART-DRAIN is a drainage material for protecting the roads from muddy conditions in a tunnel due to spring water. A filter for permeating fine soil particles was employed to keep the permeability. From the long-term permeability test using a model, appropriate permeability of ART-DRAIN was maintained for three years without blinding. There was only a slight inflow of fine grain soils into the ART-DRAIN. It was confirmed that the permeability was not obstructed by the fine grain soils. The ART-DRAIN was applied to tunnel construction works for the high-speed railway in Kyoto and the national road in mountains. From these applications, factors for enhancing the permeability effect were confirmed, which includes the selection of high quality muck, insurance of the road-bed strength by the initial compaction, use of road drainage materials with high compressible property and permeability of filter, and intervals of drainage. 1 ref., 19 figs., 1 tab.

  20. Sand dune tracking from satellite laser altimetry

    Science.gov (United States)

    Dabboor, Mohammed

    Substantial problems arise from sand movement in arid and semi-arid countries. Sand poses a threat to infrastructure, agricultural and urban areas. These issues are caused by the encroachment of sand on roads and railway tracks, farmland, towns and villages, and airports, to name a few. Sand movement highly depends on geomorphology including vegetation cover, shape and height of the terrain, and grain size of the sand. However, wind direction and speed are the most important factors that affect efficient sand movement. The direction of the movement depends on the main direction of the wind, but it has been shown that a minimum wind speed is required, e.g. wind gusts, to initiate sand transport. This fact prevents a simple calculation of sand transport from conventional wind data as wind records rarely contain sub-minute intervals masking out any wind gusts. An alternative of predicting sand transport is the direct observation of sand advance by in situ measurements or via satellite. Until recently, satellite imagery was the only means to compare dune shape and position for predicting dune migration over several years. In 2003, the NASA laser altimetry mission ICESat became operational and monitors elevations over all surface types including sand dunes with an accuracy of about 10-20 cm. In this study, ICESat observations from repeat tracks (tracks overlapping eachother within 50 m) are used to derive sand dune advance and direction. The method employs a correlation of the elevation profiles over several dunes and was sucessfully validated with synthetic data. The accuracy of this method is 5 meters of dune advance. One of the most active areas exhibiting sand and dune movement is the area of the Arabian Peninsula. Approximately one-third of the Arabian Peninsula is covered by sand dunes. Different wind regimes (Shamal, Kaus) cause sand dune movement in the selected study area in the eastern part of the Arabian Peninsula between 20-25 degrees North and 45-55 degrees

  1. Influence of limestone waste as partial replacement material for sand and marble powder in concrete properties

    Directory of Open Access Journals (Sweden)

    Omar M. Omar

    2012-12-01

    Full Text Available Green concrete are generally composed of recycling materials as hundred or partial percent substitutes for aggregate, cement, and admixture in concrete. Limestone waste is obtained as a by-product during the production of aggregates through the crushing process of rocks in rubble crusher units. Using quarry waste as a substitute of sand in construction materials would resolve the environmental problems caused by the large-scale depletion of the natural sources of river and mining sands. This paper reports the experimental study undertaken to investigate the influence of partial replacement of sand with limestone waste (LSW, with marble powder (M.P as an additive on the concrete properties. The replacement proportion of sand with limestone waste, 25%, 50%, and 75% were practiced in the concrete mixes except in the concrete mix. Besides, proportions of 5%, 10% and 15% marble powder were practiced in the concrete mixes. The effects of limestone waste as fine aggregate on several fresh and hardened properties of the concretes were investigated. The investigation included testing of compressive strength, indirect tensile strength, flexural strength, modulus of elasticity, and permeability. It was found that limestone waste as fine aggregate enhanced the slump test of the fresh concretes. But the unit weight concretes were not affected. However, the good performance was observed when limestone waste as fine aggregate was used in presence of marble powder.

  2. Basic study on the estimating the value of sand beach using amenities replace

    OpenAIRE

    Shin, B-S; Kim, K-H.

    2013-01-01

    The sand beach along the east coast of Korea offers beautiful scenery with high-quality sand for leisure, and is also famous for white-sand and pine-trees both of which are important scenic resources. Furthermore, the sand beach helps to maintain natural environment of the coastal area and has the function of a disaster prevention system against high waves. There are two major value evaluation methods, Travel Cost Method and Contingent Valuation Method, to assess the value of sand beach. Cont...

  3. Research for the development of the crushed sand (II)

    Energy Technology Data Exchange (ETDEWEB)

    Park, Chul Whan; Kang, Sun Duck; Min, Jeong Sik; Synn, Joong Ho; Park, Chan [Korea Institute of Geology Mining and Materials, Taejon (Korea)

    1998-12-01

    The sand obtained from river is not sufficient in amount for the demand of construction industry. The production of sand from sea and mountain is rapidly increasing for the substitution of the river sand. The industry of the crushed sand has recently been bricked for the above. Crushing, classification and dewatering are the main processes in the crushed sand production. This report concentrates the improvement of classification technology and the quality of ready mixed concrete. Air separator with testing size for the classification in the process of dry system was developed by the Yeung Nam university. This plant has the excellent efficiency for the collection of fine powder, but needs the improvement for separating function. The collection efficiency of the testing size air separator is reached to 99% in the condition of high revolution and low feeding speed. The classification efficiency is checked about 50% maximum in the condition of 200 rpm and dry sample. Energy saving test was carried out in the production process of the dry system with the rock samples of 14-17% of water content. The classification efficiency for dewatering sample passed the heating process was analysed 91.5%. But that for high water content sample skipped the heating process was analysed more or less 77%. Even though the heating process causes the classification efficiency being high, the energy consumption can also cause the price of the crushed sand high. Water content of sample as the effective element for the optimization of classification efficiency and energy saving should be studied next year. The quality of crushed sand in the mixing design. The test was carried out with the various content in mixing, the strength of ready mixed concrete has the maximum for the mould with 50-60% content of crushed sand. This strength is higher by 5-30% than 30% content and by 20-32% than 0% content, which means that the industry has the possibility of progress. (author). 10 refs., 31 tabs., 49

  4. Geophysical applications for oil sand mine tailings management

    Energy Technology Data Exchange (ETDEWEB)

    Parker, D.; Bauman, P. [WorleyParsons, Calgary, AB (Canada)

    2009-07-01

    Geophysical techniques are applied throughout a mine's life cycle to facilitate siting, constructing and monitoring of tailings dumps and ponds. This presentation described 3 case studies from the Athabasca region in northeast Alberta that demonstrated some of the concerns associated with oil sand mine tailings, and the information that geophysical surveys can provide. The objectives of these studies were to determine the lateral and depth extents of elevated conductivities of soil and groundwater that have high salt concentration from the tailings sand pore fluid. Due to high chloride concentrations within the tailings material, salt within the root zone may affect vegetation. A terrain conductivity survey was designed to map the lateral extents of salinity impact, while an electrical resistivity tomography (ERT) survey was used to delineate the tailings sand leachate at depth. The proper management of oil sand tailings facilities is vital to the life cycle of a mine. It was concluded that geophysical techniques can be instrumental in managing several engineering and environmental challenges, from Pleistocene channel mapping, to tailings pond settling characteristics, to reclaiming tailings sands. 1 ref., 7 figs.

  5. Final report on Thermally Modified Sand demonstration project

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-23

    The use of salt and salt/sand mixtures on icy roadway surfaces has dramatically increased during the past 30 years. Despite extensive documentation on salt related damage to the roadway improvements, vehicles and the environment, road maintenance departments have continued to rely on this practice. Road maintenance departments in northern climate areas have long recognized the safety benefits for public mobility on icy roadways from the use of sand. As an abrasive material, the sand improves the surface traction that results in more drivable and less hazardous road conditions during the winter months. Stockpiles of pure sand stored during the winter months oftentimes freeze into large unworkable, monolithic piles. To maintain a free-flowing condition, it has been found to be necessary to add salt to the sand. The addition of salt in amounts ranging from 5 to 10 percent to that of sand, is usually sufficient to provide relatively free-flowing abrasive material that could be stored in stockpiles and applied to icy road surfaces with conventional sand spreading trucks. Another alternative for winter storage of pure sand to maintain a free-flowing condition is in humidity-controlled, heated buildings. As would be expected, this method has high capital and operating costs. and not cost effective for general highway maintenance use. The invention demonstrated herein is a method of thermally modifying pure sand that will remain in a free-flowing state throughout the winter season without the need for the salt additive. The thermally modified sand provides an abrasive material that when applied to icy roads does not cause environmental and corrosive damage as done by the application of sand with salt. By employing a very simple process of freezing screened sand particles by forced air convection under subfreezing conditions, the invention creates a product that has significant value in terms of economic and environmental benefits.

  6. Monitoring CO2 gas-phase migration in a shallow sand aquifer using cross-borehole ground penetrating radar

    DEFF Research Database (Denmark)

    Lassen, Rune Nørbæk; Sonnenborg, T.O.; Jensen, Karsten Høgh

    2015-01-01

    and transversely to the groundwater flow direction. As the injection continued, the main flow direction of the gaseous CO2 shifted and CO2 gas pockets with a gas saturation of up to 0.3 formed below lower-permeable sand layers. CO2 gas was detected in a GPR-panel 5 m away from the injection point after 21 h...... of leakage from a CCS site, and that even small changes in the formation texture can create barriers for the CO2 migration....

  7. Use of geophysical logs to estimate the quality of ground water and the permeability of aquifers

    Science.gov (United States)

    Hudson, J.D.

    1996-01-01

    The relation of formation factor to resistivity of formation water and intergranular permeability has often been investigated, and the general consensus is that this relation is closest when established in a clean-sand aquifer in which water quality does not vary substantially. When these restrictions are applied, the following standard equation is a useful tool in estimating the resistance of the formation water: F = Ro/Rw, where F is the formation factor, which is a function of the effective porosity; Ro is the resistivity of a formation that is 100 percent saturated with interstitial water; and Rw is the resistivity of the water in the saturated zone. However, arenaceous aquifers can have electrical resistivities that are not directly related to resistivity of water or porosity. Surface conductivity and ion exchange are significant factors when the sediments are clay bearing. The solid constituents are a major component of the parameters needed to solve the equation for formation-water resistivity and estimates of aquifer permeability. A correction process needs to be applied to adjust the variables, Ro and F, to the equivalent of clean sand. This report presents an empirical method of using the neutron log and the electrical-resistivity values from long- and short-normal resistivity logs to correct for fine-grained material and the subsequent effects of low impedance to electrical flow that are not related to the resistance of formation water.

  8. Applications of sand control technology in thermal recovery systems

    Energy Technology Data Exchange (ETDEWEB)

    Rensvold, R F

    1982-01-01

    The ever-increasing application of thermal methods to recover low gravity crude oil has warranted the review of existing sand control techniques relative to their compatibility with high temperature environments. The advantages and limitations of a large number of materials are considered. Carrying fluids, granular pack solids, clay stabilizers, and resin-coated pack sands are discussed. Resins used for in situ sand consolidation processes also are reviewed, and their suitability for application in a high temperature steam environment is evaluated. The effects of highly deviated boreholes on the placement of pressure packs also are considered. Full scale gravel pack model studies have provided valuable clues to the procedures and materials that help to create optimum pressure packs. 58 references.

  9. Geohydrology of the valley-fill aquifer in the Jamestown area, Chautauqua County, New York

    Science.gov (United States)

    Anderson, H.R.; Stelz, W.G.; Belli, J.L.; Allen, R.V.

    1982-01-01

    This report is the sixth in a series of 11 map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on six maps at 1:24,000 scale. Together, the maps provide a comprehensive overview of a major valley-fill aquifer in southeastern Chautauqua County. The maps include surficial geology, geologic sections, water-infiltration potential of soil zone, aquifer thickness, potentiometric-surface elevations and land use. The valley-fill deposits consist of alluvial silt and sand, glacial-outwash (sand and gravel), ice-contact sand and gravel, till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities whereas the till, silt and clay deposits have relatively low permeabilities. Water-table conditions prevail in u nconfined sand and gravel beds along the valley margin. Artesian conditions prevail in confined sand and gravel buried under silt and clay in the middle of the valley. Recharge occurs mainly along the margin of the valley, where the land surface is highly permeable and runoff from the hillsides is concentrated. The use of land overlying the aquifer is predominantly agricultural and residential with lesser amounts of commercial and industrial uses. (USGS)

  10. Production of high quality water for oil sands application

    Energy Technology Data Exchange (ETDEWEB)

    Beaudette-Hodsman, C.; Macleod, B. [Pall Corp., Mississauga, ON (Canada); Venkatadri, R. [Pall Corp., East Hills, NY (United States)

    2008-10-15

    This paper described a pressurized microfiltration membrane system installed at an oil sands extraction site in Alberta. The system was designed to complement a reverse osmosis (RO) system installed at the site to produce the high quality feed water required by the system's boilers. Groundwater in the region exhibited moderate total suspended solids and high alkalinity and hardness levels, and the RO system required feed water with a silt density index of 3 or less. The conventional pretreatment system used at the site was slowing down production due to the severe fouling of the RO membranes. The new microfiltration system contained an automated PVDF hollow fiber microfiltration membrane system contained in a trailer. Suspended particles and bacteria were captured within the filter, and permeate was sent to the RO unit. Within 6 hours of being installed, the unit was producing water with SDI values in the range of 1.0 to 2.5. It was concluded that the microfiltration system performed reliably regardless of wide variations in feed water quality and flow rates. 3 refs., 1 tab., 8 figs.

  11. New generation expandable sand screens

    OpenAIRE

    Syltøy, Christer

    2014-01-01

    Master's thesis in Petroleum engineering This thesis aims to give a general insight into sand control and various sorts of sand control measures and applications of sand control tools. Special focus will be given to expandable sand screens – a technology which came about in the late 1990’s through the use of flexible, expandable tubulars as base pipe in sand screens. More specifically Darcy’s Hydraulic Endurance Screens, a compliant sand screen system using hydraulic activation, and the fu...

  12. Saltation of non-spherical sand particles.

    Directory of Open Access Journals (Sweden)

    Zhengshi Wang

    Full Text Available Saltation is an important geological process and the primary source of atmospheric mineral dust aerosols. Unfortunately, no studies to date have been able to precisely reproduce the saltation process because of the simplified theoretical models used. For example, sand particles in most of the existing wind sand movement models are considered to be spherical, the effects of the sand shape on the structure of the wind sand flow are rarely studied, and the effect of mid-air collision is usually neglected. In fact, sand grains are rarely round in natural environments. In this paper, we first analyzed the drag coefficients, drag forces, and starting friction wind speeds of sand grains with different shapes in the saltation process, then established a sand saltation model that considers the coupling effect between wind and the sand grains, the effect of the mid-air collision of sand grains, and the effect of the sand grain shape. Based on this model, the saltation process and sand transport rate of non-spherical sand particles were simulated. The results show that the sand shape has a significant impact on the saltation process; for the same wind speed, the sand transport rates varied for different shapes of sand grains by as much as several-fold. Therefore, sand shape is one of the important factors affecting wind-sand movement.

  13. Methane accumulation and forming high saturations of methane hydrate in sandy sediments

    Energy Technology Data Exchange (ETDEWEB)

    Uchida, T.; Waseda, A. [JAPEX Research Center, Chiba (Japan); Fujii, T. [Japan Oil, Gas and Metals National Corp., Chiba (Japan). Upstream Technology Unit

    2008-07-01

    Methane supplies for marine gas hydrates are commonly attributed to the microbial conversion of organic materials. This study hypothesized that methane supplies were related to pore water flow behaviours and microscopic migration in intergranular pore systems. Sedimentology and geochemistry analyses were performed on sandy core samples taken from the Nankai trough and the Mallik gas hydrate test site in the Mackenzie Delta. The aim of the study was to determine the influence of geologic and sedimentolic controls on the formation and preservation of natural gas hydrates. Grain size distribution curves indicated that gas hydrate saturations of up to 80 per cent in pore volume occurred throughout the hydrate-dominant sand layers in the Nankai trough and Mallik areas. Water permeability measurements showed that the highly gas hydrate-saturated sands have a permeability of a few millidarcies. Pore-space gas hydrates occurred primarily in fine and medium-grained sands. Core temperature depression, core observations, and laboratory analyses of the hydrates confirmed the pore-spaces as intergranular pore fillings. Results of the study suggested that concentrations of gas hydrates may require a pore space large enough to occur within a host sediments, and that the distribution of porous and coarser-grained sandy sediments is an important factor in controlling the occurrence of gas hydrates. 11 refs., 4 figs.

  14. Reuse of waste cutting sand at Lawrence Livermore National Laboratory

    International Nuclear Information System (INIS)

    Mathews, S.; Wilson, K.

    1998-01-01

    Lawrence Livermore National Laboratory (LLNL) examined the waste stream from a water jet cutting operation, to evaluate the possible reuse of waste garnet sand. The sand is a cutting agent used to shape a variety of materials, including metals. Nearly 70,000 pounds of waste sand is generated annually by the cutting operation. The Environmental Protection Department evaluated two potential reuses for the spent garnet sand: backfill in utility trenches; and as a concrete constituent. In both applications, garnet waste would replace the sand formerly purchased by LLNL for these purposes. Findings supported the reuse of waste garnet sand in concrete, but disqualified its proposed application as trench backfill. Waste sand stabilized in a concrete matrix appeared to present no metals-leaching hazard; however, unconsolidated sand in trenches could potentially leach metals in concentrations high enough to threaten ground water quality. A technical report submitted to the San Francisco Bay Regional Water Quality Control Board was reviewed and accepted by that body. Reuse of waste garnet cutting sand as a constituent in concrete poured to form walkways and patios at LLNL was approved

  15. Subsurface imaging of water electrical conductivity, hydraulic permeability and lithology at contaminated sites by induced polarization

    DEFF Research Database (Denmark)

    Maurya, P. K.; Balbarini, Nicola; Møller, I.

    2018-01-01

    At contaminated sites, knowledge about geology and hydraulic properties of the subsurface and extent of the contamination is needed for assessing the risk and for designing potential site remediation. In this study, we have developed a new approach for characterizing contaminated sites through time...... geological logs. On average the IP-derived and measured permeability values agreed within one order of magnitude, except for those close to boundaries between lithological layers (e.g. between sand and clay), where mismatches occurred due to the lack of vertical resolution in the geophysical imaging...

  16. Effects of eddy current and dispersion of magnetic anisotropy on the high-frequency permeability of Fe-based nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Han, M., E-mail: mangui@gmail.com [State Key Laboratory of Electronic Thin Films & Integrated Devices, University of Electronic Science and Technology of China, Chengdu (China); Rozanov, K.N.; Zezyulina, P.A. [Institute for Theoretical and Applied Electromagnetics, Russian Academy of Sciences, Moscow (Russian Federation); Wu, Yan-Hui [State Key Laboratory of Electronic Thin Films & Integrated Devices, University of Electronic Science and Technology of China, Chengdu (China)

    2015-06-01

    Fe–Cu–Nb–Si–B microflakes have been prepared by ball milling. The structural, magnetostatic and microwave permeability of the flakes and flake-filled composites have been studied. Two ferromagnetic phases, nanograins and amorphous matrix, are found in the flakes. The Mössbauer study shows that the nanograins are α-Fe{sub 3}(Si) with D0{sub 3} superlattice structure. High resolution transmission electron microscopy shows that the nanograins are well dispersed in the matrix. The microwave permeability of composites containing the flakes has been measured. The comparison of the intrinsic permeability of the flakes obtained from the permeability measurements and from the anisotropy field distribution reveals a disagreement in the magnetic loss peak location. It is concluded that the low-frequency loss in the composites is not due to the effect of eddy currents. The low-frequency loss may be attributed to other sources, such as domain wall motion or peculiarities of the magnetic structure of the flakes in the composite. - Highlights: • Hyperfine interactions have been studied for the Fe-based nanocomposites. Please see Fig. 3. • The distribution of magnetic anisotropy has been derived from the initial magnetization curve of the composite. Please see Fig. 6. • The magnetic loss peak has been reconstructed from the measured permeability of composites and from the anisotropy field distribution. Please see Fig. 9.

  17. Effects of eddy current and dispersion of magnetic anisotropy on the high-frequency permeability of Fe-based nanocomposites

    International Nuclear Information System (INIS)

    Han, M.; Rozanov, K.N.; Zezyulina, P.A.; Wu, Yan-Hui

    2015-01-01

    Fe–Cu–Nb–Si–B microflakes have been prepared by ball milling. The structural, magnetostatic and microwave permeability of the flakes and flake-filled composites have been studied. Two ferromagnetic phases, nanograins and amorphous matrix, are found in the flakes. The Mössbauer study shows that the nanograins are α-Fe 3 (Si) with D0 3 superlattice structure. High resolution transmission electron microscopy shows that the nanograins are well dispersed in the matrix. The microwave permeability of composites containing the flakes has been measured. The comparison of the intrinsic permeability of the flakes obtained from the permeability measurements and from the anisotropy field distribution reveals a disagreement in the magnetic loss peak location. It is concluded that the low-frequency loss in the composites is not due to the effect of eddy currents. The low-frequency loss may be attributed to other sources, such as domain wall motion or peculiarities of the magnetic structure of the flakes in the composite. - Highlights: • Hyperfine interactions have been studied for the Fe-based nanocomposites. Please see Fig. 3. • The distribution of magnetic anisotropy has been derived from the initial magnetization curve of the composite. Please see Fig. 6. • The magnetic loss peak has been reconstructed from the measured permeability of composites and from the anisotropy field distribution. Please see Fig. 9

  18. Use of Interface Treatment to Reduce Emissions from Residuals in Lower Permeability Zones to Groundwater flowing Through More Permeable Zones (Invited)

    Science.gov (United States)

    Johnson, P.; Cavanagh, B.; Clifton, L.; Daniels, E.; Dahlen, P.

    2013-12-01

    Many soil and groundwater remediation technologies rely on fluid flow for contaminant extraction or reactant delivery (e.g., soil vapor extraction, pump and treat, in situ chemical oxidation, air sparging, enhanced bioremediation). Given that most unconsolidated and consolidated settings have permeability contrasts, the outcome is often preferential treatment of more permeable zones and ineffective treatment of the lower permeability zones. When this happens, post-treatment contaminant emissions from low permeability zone residuals can cause unacceptable long-term impacts to groundwater in the transmissive zones. As complete remediation of the impacted lower permeability zones may not be practicable with conventional technologies, one might explore options that lead to reduction of the contaminant emissions to acceptable levels, rather than full remediation of the lower permeability layers. This could be accomplished either by creating a sustained emission reaction/attenuation zone at the high-low permeability interface, or by creating a clean soil zone extending sufficiently far into the lower permeability layer to cause the necessary reduction in contaminant concentration gradient and diffusive emission. These options are explored in proof-of-concept laboratory-scale physical model experiments. The physical models are prepared with two layers of contrasting permeability and either dissolved matrix storage or nonaqueous phase liquid (NAPL) in the lower permeability layer. A dissolved oxidant is then delivered to the interface via flow across the higher permeability layer and changes in contaminant emissions from the low permeability zone are monitored before, during, and after oxidant delivery. The use of three oxidants (dissolved oxygen, hydrogen peroxide and sodium persulfate) for treatment of emissions from petroleum hydrocarbon residuals is examined.

  19. Sand waves on an epicontinental shelf: Northern Bering Sea

    Science.gov (United States)

    Field, M.E.; Nelson, C.H.; Cacchione, D.A.; Drake, D.E.

    1981-01-01

    Sand waves and current ripples occupy the crests and flanks of a series of large linear sand ridges (20 km ?? 5 km ?? 10 m high) lying in an open-marine setting in the northern Bering Sea. The sand wave area, which lies west of Seward Peninsula and southeast of Bering Strait, is exposed to the strong continuous flow of coastal water northward toward Bering Strait. A hierarchy of three sizes of superimposed bedforms, all facing northward, was observed in successive cruises in 1976 and 1977. Large sand waves (height 2 m; spacing 200 m) have smaller sand waves (height 1 m; spacing 20 m) lying at a small oblique angle on their stoss slopes. The smaller sand waves in turn have linguoid ripples on their stoss slopes. Repeated studies of the sand wave fields were made both years with high-resolution seismic-reflection profiles, side-scan sonographs, underwater photographs, current-meter stations, vibracores, and suspended-sediment samplers. Comparison of seismic and side-scan data collected along profile lines run both years showed changes in sand wave shape that indicate significant bedload transport within the year. Gouge marks made in sediment by keels of floating ice also showed significantly different patterns each year, further documenting modification to the bottom by sediment transport. During calm sea conditions in 1977, underwater video and camera observations showed formation and active migration of linguoid and straight-crested current ripples. Current speeds 1 m above the bottom were between 20 and 30 cm/s. Maximum current velocities and sand wave migration apparently occur when strong southwesterly winds enhance the steady northerly flow of coastal water. Many cross-stratified sand bodies in the geologic record are interpreted as having formed in a tidal- or storm-dominated setting. This study provides an example of formation and migration of large bedforms by the interaction of storms with strong uniform coastal currents in an open-marine setting. ?? 1981.

  20. A Micro grid design for a kind of household energy efficiency management system based on high permeability

    Science.gov (United States)

    Li, Siwei; Li, Jun; Liu, Zhuochu; Wang, Min; Yue, Liang

    2017-05-01

    After the access of household distributed photovoltaic, conditions of high permeability generally occur, which cut off the connection between distributed power supply and major network rapidly and use energy storage device to realize electrical energy storage. The above operations cannot be adequate for the power grid health after distributed power supply access any more from the perspective of economy and rationality. This paper uses the integration between device and device, integration between device and system and integration between system and system of household microgrid and household energy efficiency management, to design household microgrid building program and operation strategy containing household energy efficiency management, to achieve efficient integration of household energy efficiency management and household microgrid, to effectively solve problems of high permeability of household distributed power supply and so on.

  1. Liquefaction resistance of calcareous sands

    International Nuclear Information System (INIS)

    Sandoval Vallejo, Eimar

    2012-01-01

    Calcareous sands are unique in terms of their origin, mineralogy, shape, fragility and intra particle porosity. This article presents results from an experimental program carried out to study the liquefaction resistance of a calcareous sand retrieved from Cabo Rojo at Puerto Rico. The experimental program included mineralogical characterization, index properties, and undrained cyclic triaxial tests on isotropically consolidated reconstituted samples. Due to the large variation in the calcareous sand properties, results are compared with previous researches carried out on other calcareous sands around the world. Results showed a wide range in the liquefaction resistance of the studied calcareous sands. Cabo Rojo sand experienced greater liquefaction resistance than most of the calcareous sands used for comparison. Important differences in the excess pore pressure generation characteristics were also found.

  2. Steady flow in voids and closed cracks in permeable media

    International Nuclear Information System (INIS)

    Rae, J.

    1985-03-01

    This paper considers what happens when a steady flow in a permeable medium meets two concentric spheres which have different permeabilities. This can form a first stage model for water flow near an engineered cavity in rock or a concreted waste package placed in filler material as in a nuclear waste repository. Results are obtained in terms of the simplest spherical harmonics, which lets them be used easily. Included are the well-known result that a highly permeable sphere will see only a few times the flux which would occur if it had the permeability of its surroundings, and the less well-known result, though unsurprising, that a spherical region surrounded by a highly permeable shell will see almost no flow, as it will almost all by-pass. A companion paper will include more geometrical effects by replacing the spheres by ellipsoids. (author)

  3. Potential building sand deposits in Songkhla province area

    Directory of Open Access Journals (Sweden)

    Kooptarnond, K.

    2002-10-01

    Full Text Available An investigation of potential building sand deposits in Songkhla province area subdivided them into four regions according to their accumulation in various alluvial plains, meanders throughout alluvial deposits and residual soils. Four selected deposits, were Rattaphum-Khuan Niang, U-Taphao river, Na Mom, and Chana-Thepha regions. Information obtained from these deposits revealed a good correlation between the geomorphological features as interpreted from aerial photographs and those identified from vertical electrical resistivity sounding results. Sand samples were analysed for their physical and chemical properties. Petrographic studies were also undertaken to characterize the composition types, texture and shapes. An overview of the sand properties was used them to be within the acceptable limits for building sand. However, relatively high organic impurities and soundness were found in sand from Khuan Niang and Na Mom deposits. The result indicated a potential reconnaissance mineral resource of about 46 square kilometres.A reserve evaluation for natural building sand was carried out by using Geographic Information System (GIS. Maps of the various parameters considered were constructed in digital database format with the aid of Arc/Info and ArcView software. Overlay mapping and buffer zone modules were performed to evaluate inferred resources of building sand. The key parameters of analysis included the distance from transportation, distance from streams, lithology and thickness of sand layers. The remaining inferred sand total was of about 386 million cubic metres or about 1,021 million metric tons was therefore estimated, of which 60 percent lies in the Rattaphum-Khuan Niang region and 40 percent in the other regions.

  4. A model experiment of liquefaction and fluid transport: quantifying the effect of permeability discontinuity

    Science.gov (United States)

    Yasuda, N.; Sumita, I.

    2013-12-01

    Model experiments of liquefaction of a water-saturated sand (quick sand) is commonly conducted in class and in public. Various phenomena caused by liquefaction are reproduced within a closed bottle containing push-pins (Nohguchi, 2004). Experiments for tilted and layered case have also been conducted (Peacock, 2006). However quantitative measurements of liquid transport in these experiments have rarely been made. Here we show that such measurements are possible by analyzing the video images taken during such experiments. In addition, we show that a simple physical model is capable of explaining the time scales needed to expel the interstitial liquid. An experimental cell (cross section 22.0 mm x 99.4 mm, height 107.6 mm) is filled with a granular matter and water. The lower 33.0 mm consists of a two-layered granular medium, the upper layer consists of fine particles and the lower layer consists of coarse particles, with particle sizes of 0.05 mm and 0.2 mm, respectively. Since permeability depends on the square of the particle size, the upper layer becomes a low-permeability layer. We liquefy the cell by an impulsive vibration and study how the liquid migrates afterwards. We also vary the particle size combinations (upper layer: 0.05-0.15 mm, lower layer: 0.15-0.6 mm) and the thickness ratio of the 2 layers, and study how the time scale of the liquid migration depends on these changeable parameters. In a two-layered medium, we find that the pore water which originated from the bottom layer temporary accumulates at the interface of the two layers, and then ascends through the upper layer in the form of horizontal sheet or vertical channels. We find that these two different discharge styles are controlled by the permeability ratio of the two layers. We study the temporal change of the thicknesses of the two layers and find that there are three stages; 1: the slope of the upper surface is leveled by the impulse, 2: the pore water is discharged from the bottom layer

  5. Log-inject-log in sand consolidation

    International Nuclear Information System (INIS)

    Murphy, R.P.; Spurlock, J.W.

    1977-01-01

    A method is described for gathering information for the determination of the adequacy of placement of sand consolidating plastic for sand control in oil and gas wells. The method uses a high neutron cross-section tracer which becomes part of the plastic and uses pulsed neutron logging before and after injection of the plastic. Preferably, the method uses lithium, boron, indium, and/or cadmium tracers. Boron oxide is especially useful and can be dissolved in alcohol and mixed with the plastic ingredients

  6. Hydraulic, water-quality, and temperature performance of three types of permeable pavement under high sediment loading conditions

    Science.gov (United States)

    Selbig, William R.; Buer, Nicolas

    2018-05-11

    three permeable surfaces.Temperatures below each permeable surface generally followed changes in air temperature with a more gradual response observed in deeper layers. Therefore, permeable pavement may do little to mitigate heated runoff during summer. During winter, deeper layers remained above freezing even when air temperature was below freezing. Although temperatures were not high enough to melt snow or ice accumulated on the surface, temperatures below each permeable pavement did allow void spaces to remain open, which promoted infiltration of melted ice and snow as air temperatures rose above freezing. These open void spaces could potentially reduce the need for application of deicing agents in winter because melted snow and ice would infiltrate, thereby preventing refreezing of pooled water in what is known as the “black ice” effect.

  7. Microbial communities in low permeability, high pH uranium mine tailings: characterization and potential effects.

    Science.gov (United States)

    Bondici, V F; Lawrence, J R; Khan, N H; Hill, J E; Yergeau, E; Wolfaardt, G M; Warner, J; Korber, D R

    2013-06-01

    To describe the diversity and metabolic potential of microbial communities in uranium mine tailings characterized by high pH, high metal concentration and low permeability. To assess microbial diversity and their potential to influence the geochemistry of uranium mine tailings using aerobic and anaerobic culture-based methods, in conjunction with next generation sequencing and clone library sequencing targeting two universal bacterial markers (the 16S rRNA and cpn60 genes). Growth assays revealed that 69% of the 59 distinct culturable isolates evaluated were multiple-metal resistant, with 15% exhibiting dual-metal hypertolerance. There was a moderately positive correlation coefficient (R = 0·43, P tailings depth was shown to influence bacterial community composition, with the difference in the microbial diversity of the upper (0-20 m) and middle (20-40 m) tailings zones being highly significant (P tailings zone being significant (P tailings environment, along with their demonstrated capacity for transforming metal elements, suggests that these organisms have the potential to influence the long-term geochemistry of the tailings. This study is the first investigation of the diversity and functional potential of micro-organisms present in low permeability, high pH uranium mine tailings. © 2013 The Society for Applied Microbiology.

  8. A non-erasable magnetic memory based on the magnetic permeability

    International Nuclear Information System (INIS)

    Petrie, J.R.; Wieland, K.A.; Burke, R.A.; Newburgh, G.A.; Burnette, J.E.; Fischer, G.A.; Edelstein, A.S.

    2014-01-01

    A non-erasable memory based on using differences in the magnetic permeability is demonstrated. The method can potentially store information indefinitely. Initially the high permeability bits were 10–50 μm wide lines of sputtered permalloy (Ni 81 Fe 19 ) on a glass substrate. In a second writing technique a continuous film of amorphous, high permeability ferromagnetic Metglas (Fe 78 Si 13 B 9 ) was sputtered onto a similar glass substrate. Low permeability, crystalline 50 μm wide lines were then written in the film by laser heating. Both types of written media were read by applying an external probe field that is locally modified by the permeability of each bit. The modifications in the probe field were read by a nearby set of 10 micron wide magnetic tunnel junctions with a signal-to-noise ratio of up to 45 dB. This large response to changes in bit permeability is not altered after the media has been exposed to a 6400 Oe field. While being immediately applicable for data archiving and secure information storage, higher densities are possible with smaller read and write heads. - Highlights: • We demonstrate a non-erasable memory based on changes in the magnetic permeability. • Large change in permeability occur when Metglas changes from amorphous to crystalline. • Micron size regions of Metglas can be crystallized using a laser. • Permeability changes read by observing deviations of a probe field with an MTJ

  9. MECHANICAL REGENERATION OF SAND WASTE

    Directory of Open Access Journals (Sweden)

    D. I. Gnir

    2005-01-01

    Full Text Available The experimental activation of the sand regenerator of the firm SINTO is carried out at ОАО “MZOO". It is shown that sand grains are cleared from films of binding agents, that allows to use the treated sand for preparation of agglutinant and core sands.

  10. Notional Permeability

    NARCIS (Netherlands)

    Kik, R.; Van den Bos, J.P.; Maertens, J.; Verhagen, H.J.; Van der Meer, J.W.

    2012-01-01

    Different layer design of a rock slope and under layers has a large effect on the strengths on the rock slope itself. In the stability formula developed of VAN DER MEER [1988] this effect is represented by the term Notional Permeability with symbol P. A more open, or permeable, structure underneath

  11. Practical technical solution for clay-contaminated sands used in concrete

    Directory of Open Access Journals (Sweden)

    Estephane Pierre

    2017-01-01

    Full Text Available Sand, whether natural or manufactured, shows in many instances varying degrees of high levels of clay contamination. This fact is encountered in different parts of the globe and can lead to serious problems in adjusting concrete mix proportions and requiring high water to cement ratios and/or high dosages of superplasticizers without necessarily meeting the workability requirements, even when the sand is previously washed with fresh water. In this paper, different types of sand from the Gulf Cooperation Council (GCC region are being screened, analysed for their clay contents and consequent effects on plastic concrete quality. A technical solution is being proposed based on engineered superplasticizers. A testing protocol has been established to verify the robustness of optimized mix designs demonstrating the performance of the admixture in terms of initial and extended workability. In particular, it will be demonstrated that the customized concrete admixtures constitute by themselves a stand-alone answer to the usage of clay-contaminated sands in concrete.

  12. The permeability and consolidation of deep-sea sediments

    International Nuclear Information System (INIS)

    Schultheiss, P.J.; Gunn, D.E.

    1985-01-01

    This report presents permeability and consolidation data for a wide range of sediment types. Permeability is one of the two parameters which are needed to directly quantify pore water advection in deep sea sediments and which are being investigated in high-level radioactive waste study areas. While it is desirable that these parameters should be measured in situ it is argued that values of permeability can be measured sufficiently accurately in the laboratory from core samples. Consequently, an apparatus has been developed which enables sediment permeability to be measured at decreasing void ratios during a back-pressured consolidation test. Data presented in this report from over 60 samples have established the major differences in permeability between various sediment types and how permeability changes as a function of burial depth and void ratio. Samples from two study areas in the North Atlantic Ocean, King's Trough Flank (KTF) and Great Meteor East (GME), have been compared with samples of Red Clay (RC) obtained from the NW Pacific Ocean. Results are presented and discussed. (author)

  13. Crushed rock sand – An economical and ecological alternative to natural sand to optimize concrete mix

    Directory of Open Access Journals (Sweden)

    Sanjay Mundra

    2016-09-01

    Full Text Available The study investigates the use of crushed rock sand as viable alternative to Natural River sand that is being conventionally used as fine aggregate in cement concrete. Various mix designs were developed for different grades of concrete based on IS, ACI and British codes using Natural River sand and crushed rock sand. In each case, the cube compressive strength test, and beam flexure tests were conducted. The results of the study show that, the strength properties of concrete using crushed rock sand are nearly similar to the conventional concrete. The study has shown that crushed stone sand can be used as economic and readily available alternative to river sand and can therefore help to arrest the detrimental effects on the environment caused due to excessive mining of river sand.

  14. Prebiotic milk oligosaccharides prevent development of obese phenotype, impairment of gut permeability, and microbial dysbiosis in high fat-fed mice.

    Science.gov (United States)

    Hamilton, M Kristina; Ronveaux, Charlotte C; Rust, Bret M; Newman, John W; Hawley, Melissa; Barile, Daniela; Mills, David A; Raybould, Helen E

    2017-05-01

    Microbial dysbiosis and increased intestinal permeability are targets for prevention or reversal of weight gain in high-fat (HF) diet-induced obesity (DIO). Prebiotic milk oligosaccharides (MO) have been shown to benefit the host intestine but have not been used in DIO. We hypothesized that supplementation with bovine MO would prevent the deleterious effect of HF diet on the gut microbiota and intestinal permeability and attenuate development of the obese phenotype. C57BL/6 mice were fed a control diet, HF (40% fat/kcal), or HF + prebiotic [6%/kg bovine milk oligosaccharides (BMO) or inulin] for 1, 3, or 6 wk. Gut microbiota and intestinal permeability were assessed in the ileum, cecum, and colon. Addition of BMO to the HF diet significantly attenuated weight gain, decreased adiposity, and decreased caloric intake; inulin supplementation also lowered weight gain and adiposity, but this did not reach significance. BMO and inulin completely abolished the HF diet-induced increase in paracellular and transcellular permeability in the small and large intestine. Both BMO and inulin increased abundance of beneficial microbes Bifidobacterium and Lactobacillus in the ileum. However, inulin supplementation altered phylogenetic diversity and decreased species richness. We conclude that addition of BMO to the HF diet completely prevented increases in intestinal permeability and microbial dysbiosis and was partially effective to prevent weight gain in DIO. NEW & NOTEWORTHY This study provides the first report of the effects of prebiotic bovine milk oligosaccharides on the host phenotype of high-fat diet-induced obesity in mice. Copyright © 2017 the American Physiological Society.

  15. Numerical Simulation of a Non-volcanic Hydrothermal System Caused by Formation of a High Permeability Fracture Zone

    Science.gov (United States)

    Oka, Daisuke; Ehara, Sachio; Fujimitsu, Yasuhiro

    2010-05-01

    Because in the Japanese islands the earth crust activity is very active, a disposal stratum for high-level radioactive waste produced by reprocessing the spent nuclear fuel from nuclear power plants will be selected in the tectonically stable areas in which the waste can be disposed underground safely for a long term and there is no influence of earthquakes, seismic activities, volcanic activities, upheaval, sedimentation, erosion, climate and global sea level change and so on, which causes the risk of the inflow of the groundwater to destroy the disposal site or the outflow to the ground surface. However, even if the disposal stratum in such condition will be chosen, in case that a new high permeability fracture zone is formed by the earthquake, and a new hydrothermal system may be formed for a long term (thousands or millions years) and the system may affect the disposal site. Therefore, we have to understand the feature of the non-volcanic hydrothermal system through the high permeability fracture zone. We estimated such influence by using HYDROTHERM Ver2.2 (Hayba & Ingebritsen, 1994), which is a three-dimensional numerical reservoir simulator. The model field is the northwestern part of Kego Fault, which was formed by a series of earthquakes called "the 2005 Fukuoka Prefecture Western Offshore Earthquakes" (the main shock of Mjma 7.0 on 20 March 2005) in Kyushu, Japan. The results of the numerical simulations show the development of a low temperature hydrothermal system as a new fracture zone is formed, in case that there is no volcanic heat source. The results of the simulations up to 100,000 years after formation of the fracture zone show that the higher heat flow and the wider and more permeable fracture zone accelerate the development of the hydrothermal system in the fracture zone. As a result of calculation of up to10 million years, we clarified the evolutional process of the non-volcanic hydrothermal system through the high permeability fracture zone. At

  16. Trajectories of saltating sand particles behind a porous fence

    Science.gov (United States)

    Zhang, Ning; Lee, Sang Joon; Chen, Ting-Guo

    2015-01-01

    Trajectories of aeolian sand particles behind a porous wind fence embedded in a simulated atmospheric boundary layer were visualized experimentally, to investigate the shelter effect of the fence on sand saltation. Two sand samples, one collected from a beach (d = 250 μm) and the other from a desert (d = 100 μm), were tested in comparison with the previous studies of a 'no-fence' case. A wind fence (ε = 38.5%) was installed on a flat sand bed filled with each sand sample. A high-speed photography technique and the particle tracking velocimetry (PTV) method were employed to reconstruct the trajectories of particles saltating behind the fence. The collision processes of these sand particles were analyzed, momentum and kinetic energy transfer between saltating particles and ground surface were also investigated. In the wake region, probability density distributions of the impact velocities agree well with the pattern of no-fence case, and can be explained by a log-normal law. The horizontal component of impact velocity for the beach sand is decreased by about 54%, and about 76% for the desert sand. Vertical restitution coefficients of bouncing particles are smaller than 1.0 due to the presence of the wind fence. The saltating particles lose a large proportion of their energy during the collision process. These results illustrate that the porous wind fence effectively abates the further evolution of saltating sand particles.

  17. Rheological Characterization of Green Sand Flow

    DEFF Research Database (Denmark)

    Jabbaribehnam, Mirmasoud; Spangenberg, Jon; Hovad, Emil

    2016-01-01

    The main aim of this paper is to characterize experimentally the flow behaviour of the green sand that is used for casting of sand moulds. After the sand casting process is performed, the sand moulds are used for metal castings. The rheological properties of the green sand is important to quantif...

  18. Geohydrology of the valley-fill aquifer in the Corning area, Steuben County, New York

    Science.gov (United States)

    Miller, Todd S.; Belli, J.L.; Allen, R.V.

    1982-01-01

    This report is the seventh in a series of 11 map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on six maps at 1:24,000 scale. Together, the maps provide a comprehensive overview of a major valley-fill aquifer in southeastern Steuben County. The maps include surficial geology, geologic sections, water-infiltration potential of soil zone, aquifer thickness, potentiometric-surface elevations, and land use. The valley-fill deposits consist of alluvial silt, sand, and gravel, glacial-outwash (sand and gravel), till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities, whereas the till and silt deposits have relatively low permeabilities. Water-table conditions prevail in unconfined sand and gravel along the valley margin. Artesian conditions are found locally in sand and gravel confined under silt and clay in the middle of the valley. Recharge occurs nearly everywhere on the valley floor, but principally along the margin of the valley, where highly permeable land surface conditions exist, and runoff from the hillsides is concentrated. The use of land overlying the aquifer is a mixture of residential, commercial, agricultural, and industrial uses. (USGS)

  19. Studies on the Gases Emission under High Temperature Condition from Moulding Sands Bonded by Modified Starch CMS-Na

    Directory of Open Access Journals (Sweden)

    Kaczmarska K.

    2017-03-01

    Full Text Available Emission of gases under high temperature after pouring molten metal into moulds, which contain the organic binder or other additives (solvents or curing agent, may be an important factor influencing both on the quality of the produced castings, and on the state of environment. Therefore, a comprehensive study of the emitted gases would allow to determine restrictions on the use of the moulding sands in foundry technologies, eg. the probability of occurrence of casting defects, and identify the gaseous pollutants emitted to the environment. The aim of the research presented in this paper was to determine the amount of gases that are released at high temperatures from moulding sands bonded by biopolymer binder and the quantitative assessment of the emitted pollutants with particular emphasis on chemical compounds: benzene, toluene, ethylbenzene and xylenes (BTEX. The water-soluble modified potato starch as a sodium carboxymethyl starch with low (CMS-NaL or high (CMS-NaH degree of substitution was a binder in the tested moulding sands. A tests of gases emission level were conducted per the procedure developed at the Faculty of Foundry Engineering (AGH University of Science and Technology involving gas chromatography method (GC. The obtained results of the determination of amount of BTEX compounds generated during the decomposition process of starch binders showed lower emission of aromatic hydrocarbons in comparison with binder based on resin Kaltharz U404 with the acidic curing agent commonly used in the foundries.

  20. Sand quarry wetlands provide high-quality habitat for native amphibians

    Directory of Open Access Journals (Sweden)

    M. Sievers

    2017-05-01

    Full Text Available Anthropogenic disturbances to habitats influence the fitness of individual animals, the abundance of their populations, and the composition of their communities. Wetlands in particular are frequently degraded and destroyed, impacting the animals that inhabit these important ecosystems. The creation of wetlands during and following sand extraction processes is inevitable, and thus, sand quarries have the potential to support aquatic animals. To determine how amphibians utilise these wetlands, I conducted nocturnal call surveys at wetlands within the Kables Sands quarry, New South Wales, Australia, and within surrounding reference wetlands, and quantified levels of developmental instability (DI as a proxy for fitness. Whilst quarry and reference wetlands were largely similar in terms of environmental characteristics, quarry wetlands consistently harboured more amphibian species and individuals. Using unsigned asymmetry as a measure of DI, frogs from the quarry sites exhibited significantly lower levels of DI compared to reference wetlands, indicating that quarry wetlands may be comparatively higher quality. Levels of DI within quarry wetlands also compared favourably to data from healthy frog populations extracted from the literature. Further enhancing the suitability of quarry wetlands would require minimal effort, with potentially significant increases in local and regional biodiversity. Documenting species presence and quantifying individual fitness by measuring limb lengths is an economically and logistically feasible method to assess the health of quarry wetlands. Overall, the methods outlined here provide a powerful, yet simple, tool to assess the overall health and suitability of quarry wetlands that could be easily adopted at quarries throughout the world.

  1. Negative permeability from random particle composites

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, Shahid, E-mail: shussain2@qinetiq.com

    2017-04-15

    Artificial media, such as those composed of periodically-spaced wires for negative permittivity and split ring resonators for negative permeability have been extensively investigated for negative refractive index (NRI) applications (Smith et al., 2004; Pendry et al., 1999) [1,2]. This paper presents an alternative method for producing negative permeability: granular (or particulate) composites incorporating magnetic fillers. Artificial media, such as split-ring resonators, are designed to produce a magnetic resonance feature, which results in negative permeability over a narrow frequency range about the resonance frequency. The position of the feature is dependent upon the size of the inclusion. The material in this case is anisotropic, such that the feature is only observable when the materials are orientated in a specific direction relative to the applied field. A similar resonance can be generated in magnetic granular (particulate) materials: ferromagnetic resonance from the natural spin resonance of particles. Although the theoretical resonance profiles in granular composites shows the permeability dipping to negative values, this is rarely observed experimentally due to resonance damping effects. Results are presented for iron in spherical form and in flake form, dispersed in insulating host matrices. The two particle shapes show different permeability performance, with the magnetic flakes producing a negative contribution. This is attributed to the stronger coupling with the magnetic field resulting from the high aspect ratio of the flakes. The accompanying ferromagnetic resonance is strong enough to overcome the effects of damping and produce negative permeability. The size of random particle composites is not dictated by the wavelength of the applied field, so the materials are potentially much thinner than other, more traditional artificial composites at microwave frequencies. - Highlights: • Negative permeability from random particle composites is

  2. Permeability measuremens of brazilian Eucalyptus

    Directory of Open Access Journals (Sweden)

    Marcio Rogério da Silva

    2010-09-01

    Full Text Available The permeability of Brazilian Eucalyptus grandis and Eucalyptus citriodora wood was measured in a custom build gas analysis chamber in order to determine which species could be successfully treated with preservatives. Liquid permeability was tested using an emulsion of Neen oil and a control of distillated water. Air was used to test the gas phase permeability. For both Eucalyptus grandis and Eucalyptus citriodora, the longitudinal permeability of gas was shown to be about twice as great as the liquid phase permeability. No radial permeability was observed for either wood. The permeability of air and water through the sapwood of Eucalyptus grandis was greater than that through the sapwood of Eucalyptus citriodora. The permeability of neen oil preservative through the sapwood of Eucalyptus grandis was also greater than through the sapwood of E. Citradora, but the difference was not statistically significant. Scanning Electron Microscopy images showed that the distribution and obstruction in the vessels could be correlated with observed permeability properties. Irrespective of the causes of differences in permeability between the species, the fluid phase flux through the sapwood of both species was significant, indicating that both Eucalyptus grandis and Eucalyptus citriodora could be successfully treated with wood preservative.

  3. Permeability testing of fractures in climax stock granite at the Nevada Test Site

    International Nuclear Information System (INIS)

    Murray, W.A.

    1980-01-01

    Permeability tests conducted in the Climax stock granitic rock mass indicate that the bulk rock permeability can be highly variable. If moderately to highly fractured zones are encountered, the permeability values may lie in the range of 10 -4 to 10 -1 darcies. If, on the other hand, only intact rock or healed fractures are encountered, the permeability is found to be less than 10 -9 darcies. In order to assess the thermomechanical effect on fracture permeability, discrete fractures will be packed off and tested periodically throughout the thermal cycle caused by the emplacement of spent nuclear fuel in the Climax stock

  4. Intestinal Permeability: The Basics

    Directory of Open Access Journals (Sweden)

    Ingvar Bjarnason

    1995-01-01

    Full Text Available The authors review some of the more fundamental principles underlying the noninvasive assessment of intestinal permeability in humans, the choice of test markers and their analyses, and the practical aspects of test dose composition and how these can be changed to allow the specific assessment of regional permeability changes and other intestinal functions. The implications of increased intestinal permeability in the pathogenesis of human disease is discussed in relation to findings in patients with Crohn’s disease. A common feature of increased intestinal permeability is the development of a low grade enteropathy, and while quantitatively similar changes may be found in Crohn’s disease these seem to predict relapse of disease. Moreover, factors associated with relapse of Crohn’s disease have in common an action to increase intestinal permeability. While increased intestinal permeability does not seem to be important in the etiology of Crohn’s disease it may be a central mechanism in the clinical relapse of disease.

  5. Urban evaporation rates for water-permeable pavements.

    Science.gov (United States)

    Starke, P; Göbel, P; Coldewey, W G

    2010-01-01

    In urban areas the natural water balance is disturbed. Infiltration and evaporation are reduced, resulting in a high surface runoff and a typical city climate, which can lead to floods and damages. Water-permeable pavements have a high infiltration rate that reduces surface runoff by increasing the groundwater recharge. The high water retention capacity of the street body of up to 51 l/m(2) and its connection via pores to the surface lead to higher evaporation rates than impermeable surfaces. A comparison of these two kinds of pavements shows a 16% increase in evaporation levels of water-permeable pavements. Furthermore, the evaporation from impermeable pavements is linked directly to rain events due to fast-drying surfaces. Water-permeable pavements show a more evenly distributed evaporation after a rain event. Cooling effects by evaporative heat loss can improve the city climate even several days after rain events. On a large scale use, uncomfortable weather like sultriness or dry heat can be prevented and the urban water balance can be attenuated towards the natural.

  6. The Alberta oil sands story

    Energy Technology Data Exchange (ETDEWEB)

    1974-01-01

    This report serves as a detailed introduction to the Alberta oil sands and their development. It includes a description of the oil sands deposits, an outline of crude bitumen recovery and upgrading processes, the role of Alberta Energy Company in oil sands development, environmental aspects, manpower requirements for oil sands development, research needs, and further oil sands projects. Presently proven recoverable reserves in the oil sands amount to 26.5 billion bbl of synthetic crude. Production from the Syncrude plant (125,000 bbl/d capacity) is expected to begin in 1977, followed by a Shell Canada operation around 1980. The provincial government will participate in the oil sand industry through its joint venture participation in Syncrude and its 50% share in Alberta Energy Company; the latter company participates in related aspects of the Syncrude project, such as pipelines. The result of Alberta's participation in the industry will mean that, directly or indirectly, the province will realize 60% of the total profits. The job creation potential of oil sands projects is estimated to be extensive, with a direct and indirect work force supported by oil sands activities possibly reaching 180,000 persons by the year 2000. Research needs have been identified, particularly in the area of in-situ thermal recovery technology, and the creation of the Alberta Oil Sands Technology and Research Authority has been authorized in order to meet these needs. Although current reserves are sufficient to support 20-30 synthetic crude plants, a number of factors will limit expansion of the industry. 8 figs., 5 tabs.

  7. Textural evidence for jamming and dewatering of a sub-surface, fluid-saturated granular flow

    Science.gov (United States)

    Sherry, T. J.; Rowe, C. D.; Kirkpatrick, J. D.; Brodsky, E. E.

    2011-12-01

    Sand injectites are spectacular examples of large-scale granular flows involving migration of hundreds of cubic meters of sand slurry over hundreds of meters to kilometers in the sub-surface. By studying the macro- and microstructural textures of a kilometer-scale sand injectite, we interpret the fluid flow regimes during emplacement and define the timing of formation of specific textures in the injected material. Fluidized sand sourced from the Santa Margarita Fm., was injected upward into the Santa Cruz Mudstone, Santa Cruz County, California. The sand injectite exposed at Yellow Bank Beach records emplacement of both hydrocarbon and aqueous sand slurries. Elongate, angular mudstone clasts were ripped from the wall rock during sand migration, providing evidence for high velocity, turbid flow. However, clast long axis orientations are consistently sub-horizontal suggesting the slurry transitioned to a laminar flow as the flow velocity decreased in the sill-like intrusion. Millimeter to centimeter scale laminations are ubiquitous throughout the sand body and are locally parallel to the mudstone clast long axes. The laminations are distinct in exposure because alternating layers are preferentially cemented with limonite sourced from later groundwater infiltration. Quantitative microstructural analyses show that the laminations are defined by subtle oscillations in grain alignment between limonite and non-limonite stained layers. Grain packing, size and shape distributions do not vary. The presence of limonite in alternating layers results from differential infiltration of groundwater, indicating permeability changes between the layers despite minimal grain scale differences. Convolute dewatering structures deform the laminations. Dolomite-cemented sand, a signature of hydrocarbon saturation, forms irregular bodies that cross-cut the laminations and dewatering structures. Laminations are not formed in the dolomite-cemented sand. The relative viscosity difference

  8. Canada's oil sands : opportunities and challenges to 2015 : an update

    International Nuclear Information System (INIS)

    2006-06-01

    This report updated an energy market assessment compiled and published by the National Energy Board (NEB) in 2004. Major changes resulting from recent developments in the oil sands industry were presented. The report was compiled from a series of informal meetings and discussions with a cross-section of oil sands stakeholders. Influences on recent oil sands development and production growth included market development and pipelines; rising capital and labour costs; operating costs; environmental impact management; high crude oil prices; rising global energy demand; technology innovations; and a more stable investment climate. A comparison of key assumptions between the current analysis and the 2004 report was presented, along with estimates of operating and supply costs for various types of oil sands recovery methods. Potential markets for oil sands production were reviewed. Environmental and socio-economic impacts on the industry included the larger than anticipated water withdrawals from the Athabasca River for mining operations; and uncertainties over land reclamation methods. The industry has also been impacted by a limited supply of skilled workers in Alberta. It was observed that the potential for building cogeneration capacity has decreased since the 2004 report. It was concluded that the oil sands industry will continue to grow rapidly, but the rate of development will depend on the balance that is reached between the opposing forces that affect the oil sands. Natural gas costs, high oil prices, air emissions management issues and water usage will continue to be of concern. 6 tabs., 7 figs

  9. Permeability change with dissolution and precipitation reaction induced by highly alkaline plume in packed bed with amorphous silica particles

    International Nuclear Information System (INIS)

    Komatsu, Kyo; Kadowaki, Junichi; Niibori, Yuichi; Mimura, Hitoshi; Usui, Hideo

    2008-01-01

    A large amount of cement is used to construct of the geological disposal system. Such a material alters the pH of groundwater to highly alkaline region. The highly alkaline plume contains rich Ca ion compared to the surrounding environment, and the Ca ion reacts with soluble silicic acid. Its product would deposit on the surface of flow-paths in the natural barrier and decrease the permeability. In this study, the influence of Ca ions in highly alkaline plume on flow-paths has been examined by using packed bed column. The column was packed with the amorphous silica particles of 75-150 μm in diameter. The Ca(OH) 2 solution (0.78 mM, 2.58 mM, 4.37 mM, and 8.48 mM, pH: 12.2-12.4) was continuously injected into the column at a constant flow rate (5 ml/min, and 2 ml/min), and the change of permeability was monitored. At the same time, the concentrations of [Ca] total and [Si] in the eluted solution were measured by the inductively coupled plasma atomic emission spectrometry (ICP-AES). The Ca(OH) 2 solutions were prepared with CO 2 -free pure water, and filtrated through 0.45 μm filter. The permeability was normalized by the initial permeability value. In the experiment results, the permeability dramatically changed with increasing Ca concentration, because Ca ions and H 4 SiO 4 (due to the dissolution of SiO 2 ) produce C-S-H gel between the packed particles in the column. The SEM images and XRD analyses showed that the surface of SiO 2 particles was covered with the C-S-H gel precipitation. On the other hand, when the Ca concentration was relatively low, the permeability did not show remarkable change. For the cross section of SiO 2 particles, EPMA analysis suggested the consumption of Ca in the inner pore of the SiO 2 particles. However, the time-change in the concentrations of Si and Ca was not always simple. Such time-change strongly depended not only on pH or Ca concentration, but also on the flow rates. This suggested that mass transport controls the chemical

  10. Environmental life cycle assessment of permeable reactive barriers: effects of construction methods, reactive materials and groundwater constituents.

    Science.gov (United States)

    Mak, Mark S H; Lo, Irene M C

    2011-12-01

    The effects of the construction methods, materials of reactive media and groundwater constituents on the environmental impacts of a permeable reactive barrier (PRB) were evaluated using life cycle assessment (LCA). The PRB is assumed to be installed at a simulated site contaminated by either Cr(VI) alone or Cr(VI) and As(V). Results show that the trench-based construction method can reduce the environmental impacts of the remediation remarkably compared to the caisson-based method due to less construction material consumption by the funnel. Compared to using the zerovalent iron (Fe(0)) and quartz sand mixture, the use of the Fe(0) and iron oxide-coated sand (IOCS) mixture can reduce the environmental impacts. In the presence of natural organic matter (NOM) in groundwater, the environmental impacts generated by the reactive media were significantly increased because of the higher usage of Fe(0). The environmental impacts are lower by using the Fe(0) and IOCS mixture in the groundwater with NOM, compared with using the Fe(0) and quartz sand mixture. Since IOCS can enhance the removal efficiency of Cr(VI) and As(V), the usage of the Fe(0) can be reduced, which in turn reduces the impacts induced by the reactive media.

  11. Documenting the global impacts of beach sand mining

    Science.gov (United States)

    Young, R.; Griffith, A.

    2009-04-01

    For centuries, beach sand has been mined for use as aggregate in concrete, for heavy minerals, and for construction fill. The global extent and impact of this phenomenon has gone relatively unnoticed by academics, NGOs, and major news sources. Most reports of sand mining activities are found at the very local scale (if the mining is ever documented at all). Yet, sand mining in many localities has resulted in the complete destruction of beach (and related) ecosystems along with severe impacts to coastal protection and tourism. The Program for the Study of Developed Shorelines at Western Carolina University and Beachcare.org have initiated the construction of a global database of beach sand mining activities. The database is being built through a combination of site visits and through the data mining of media resources, peer reviewed papers, and reports from private and governmental entities. Currently, we have documented sand mining in 35 countries on 6 continents representing the removal of millions of cubic meters of sand. Problems extend from Asia where critical infrastructure has been disrupted by sand mining to the Caribbean where policy reform has swiftly followed a highly publicized theft of sand. The Program for the Study of Developed Shorelines recently observed extensive sand mining in Morocco at the regional scale. Tens of kilometers of beach have been stripped of sand and the mining continues southward reducing hope of a thriving tourism-based economy. Problems caused by beach sand mining include: destruction of natural beaches and the ecosystems they protect (e.g. dunes, wetlands), habitat loss for globally important species (e.g. turtles, shorebirds), destruction of nearshore marine ecosystems, increased shoreline erosion rates, reduced protection from storms, tsunamis, and wave events, and economic losses through tourist abandonment and loss of coastal aesthetics. The threats posed by sand mining are made even more critical given the prospect of a

  12. The Effect of Water Cement Ratio on Cement Brick Containing High Density Polyethylene (HDPE as Sand Replacement

    Directory of Open Access Journals (Sweden)

    Ali Noorwirdawati

    2018-01-01

    Full Text Available Waste disposal can contribute to the problem of environmental pollution. Most of the waste material is plastic based, because the nature of difficult of plastic degradable by itself. In order to overcome the problem, many study has been conducted on the reuse of plastic material into various field such as civil engineering and construction. In this study, municipal solid waste (MSW in the form of High Density Polyethylene (HDPE plastic was used to replace sand in cement sand brick production. The HDPE used in this study was obtained from a recycle factory at Nilai, Negeri Sembilan. 3% of HDPE replacement was applied in this study, with the cement-sand mix design of 1:6 and water-cement ratio 0.35, 0.40, 0.45 and 0.50 respectively. All specimens were tested for compressive strength and water absorption at 7 and 28 days. The density of the bricks was also recorded. The finding show that brick with 3% HDPE content and 0.45 of water-cement ratio at 28 days of age curing show the highest compressive strength, which is 19.5N/mm2 compared to the control specimen of 14.4 N/mm2.

  13. Microwave permeability of stripe patterned FeCoN thin film

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Yuping [Temasek Laboratories, National University of Singapore, 5A Engineering Drive 1, Singapore 117411 (Singapore); Yang, Yong, E-mail: tslyayo@nus.edu.sg [Temasek Laboratories, National University of Singapore, 5A Engineering Drive 1, Singapore 117411 (Singapore); Ma, Fusheng; Zong, Baoyu; Yang, Zhihong [Temasek Laboratories, National University of Singapore, 5A Engineering Drive 1, Singapore 117411 (Singapore); Ding, Jun [Department of Materials Science and Engineering, National University of Singapore, Singapore 117574 (Singapore)

    2017-03-15

    Magnetic stripe patterns are of great importance for microwave applications owing to their highly tunable microwave permeability by adjusting the geometrical dimensions. In this work, stripe patterned FeCoN films with 160 nm thickness are fabricated by using standard UV photolithography. Their microwave permeability are investigated systematically via both experiment and micromagnetic simulation. The good agreement between experimental and simulation results suggests that stripe width is crucial for the microwave magnetic properties of the stripe pattern. It is demonstrated by simulation that with increasing stripe width from 1 to 80 µm the initial permeability shows a continuous growth from about 8–322, whiles the resonance frequency drops dramatically from 18.7 to 3.1 GHz at 4 µm gap size. Smaller gap size would result in slightly increased initial permeability due to larger magnetic volume ratio, accompanied by decreased resonance frequency because of stronger magnetostatic interaction. Moreover, the experimental investigation on stripe length effect indicates that the stripe length should be kept as long as possible to achieve uniform bulk resonance mode and high permeability value. Insufficient stripe length would result in low frequency edge mode and decayed bulk mode. This study could provide valuable guidelines on the selection of proper geometry dimensions of FeCoN stripe patterns for high frequency applications. - Highlights: • This work presents a systematic study on permeability of FeCoN stripe pattern. • Geometrical parameters of the stripe pattern are systematically optimized. • Several important conclusions has been obtained. • The results offer guideline on FeCoN stripe patterns for high frequency applications.

  14. Geomorphology and drift potential of major aeolian sand deposits in Egypt

    Science.gov (United States)

    Hereher, Mohamed E.

    2018-03-01

    Aeolian sand deposits cover a significant area of the Egyptian deserts. They are mostly found in the Western Desert and Northern Sinai. In order to understand the distribution, pattern and forms of sand dunes in these dune fields it is crucial to analyze the wind regimes throughout the sandy deserts of the country. Therefore, a set of wind data acquired from twelve meteorological stations were processed in order to determine the drift potential (DP), the resultant drift potential (RDP) and the resultant drift direction (RDD) of sand in each dune field. The study showed that the significant aeolian sand deposits occur in low-energy wind environments with the dominance of linear and transverse dunes. Regions of high-energy wind environments occur in the south of the country and exhibit evidence of deflation rather than accumulation with the occurrence of migratory crescentic dunes. Analysis of the sand drift potentials and their directions help us to interpret the formation of major sand seas in Egypt. The pattern of sand drift potential/direction suggests that the sands in these seas might be inherited from exogenous sources.

  15. Contamination Control of Freeze Shoe Coring System for Collection of Aquifer Sands

    Science.gov (United States)

    Homola, K.; van Geen, A.; Spivack, A. J.; Grzybowski, B.; Schlottenmier, D.

    2017-12-01

    We have developed and tested an original device, the freeze-shoe coring system, designed to recover undisturbed samples of water contained in sand-dominated aquifers. Aquifer sands are notoriously difficult to collect together with porewater from coincident depths, as high hydraulic permeability leads to water drainage and mixing during retrieval. Two existing corer designs were reconfigured to incorporate the freeze-shoe system; a Hydraulic Piston (HPC) and a Rotary (RC) Corer. Once deployed, liquid CO­2 contained in an interior tank is channeled to coils at the core head where it changes phase, rapidly cooling the deepest portion of the core. The resulting frozen core material impedes water loss during recovery. We conducted contamination tests to examine the integrity of cores retrieved during a March 2017 yard test deployment. Perfluorocarbon tracer (PFC) was added to the drill fluid and recovered cores were subsampled to capture the distribution of PFC throughout the core length and interior. Samples were collected from two HPC and one RC core and analyzed for PFC concentrations. The lowest porewater contamination, around 0.01% invasive fluid, occurs in the center of both HPC cores. The greatest contamination (up to 10%) occurs at the disturbed edges where core material contacts drill fluid. There was lower contamination in the core interior than top, bottom, and edges, as well as significantly lower contamination in HPC cores that those recovered with the RC. These results confirm that the freeze-shoe system, proposed for field test deployments in West Bengal, India, can successfully collect intact porewater and sediment material with minimal if any contamination from drill fluid.

  16. Sediment transport and mixing depth on a coral reef sand apron

    Science.gov (United States)

    Vila-Concejo, Ana; Harris, Daniel L.; Power, Hannah E.; Shannon, Amelia M.; Webster, Jody M.

    2014-10-01

    This paper investigates the mechanics of sediment transport on a subtidal sand apron located on a coral reef environment. In this environment 100% of the sediment is carbonate bioclasts generated in situ. The sand apron is located on the back reef and only affected by waves during high tides. It is commonly accepted in the literature that sand aprons are features that prograde lagoonwards and that most of the progradation occurs during high-energy events. Measurements of water depths, waves, currents and near bed suspended sediment concentrations (all at 10 Hz) on the sand apron were undertaken over a nine day intensive field campaign over both spring and neap tides; waves and tides were also measured in the lagoon. The topography and bathymetry of the sand apron were measured and mixing depth was obtained on three transects using depth of disturbance rods. We found that sediment transport on sand aprons is not solely restricted to high-energy events but occurs on a daily basis during spring tides. The main factor controlling the sediment transport was the water depth above the bed, with depths of 2-2.3 m allowing waves to promote the most sediment transport. This corresponds to a depth over the reef crest of 1.6-1.9 m. The second most important control was waves; transport was observed when Hs on the apron was 0.1 m or greater. In contrast, current magnitude was not a controlling mechanism for sediment entrainment but did affect sediment transport. The morphology of the sand apron was shown to affect the direction of currents with the currents also expected to influence the morphology of the sand apron. The currents measured during this field campaign were aligned with a shallow channel in the sand apron. Mixing depths were small (< 2.5 cm) yet they were larger than the values predicted by empirical formulae for gentle siliciclastic ocean beaches.

  17. Subsurface imaging of water electrical conductivity, hydraulic permeability and lithology at contaminated sites by induced polarization

    Science.gov (United States)

    Maurya, P. K.; Balbarini, N.; Møller, I.; Rønde, V.; Christiansen, A. V.; Bjerg, P. L.; Auken, E.; Fiandaca, G.

    2018-05-01

    At contaminated sites, knowledge about geology and hydraulic properties of the subsurface and extent of the contamination is needed for assessing the risk and for designing potential site remediation. In this study, we have developed a new approach for characterizing contaminated sites through time-domain spectral induced polarization. The new approach is based on: (1) spectral inversion of the induced polarization data through a reparametrization of the Cole-Cole model, which disentangles the electrolytic bulk conductivity from the surface conductivity for delineating the contamination plume; (2) estimation of hydraulic permeability directly from the inverted parameters using a laboratory-derived empirical equation without any calibration; (3) the use of the geophysical imaging results for supporting the geological modelling and planning of drilling campaigns. The new approach was tested on a data set from the Grindsted stream (Denmark), where contaminated groundwater from a factory site discharges to the stream. Two overlapping areas were covered with seven parallel 2-D profiles each, one large area of 410 m × 90 m (5 m electrode spacing) and one detailed area of 126 m × 42 m (2 m electrode spacing). The geophysical results were complemented and validated by an extensive set of hydrologic and geologic information, including 94 estimates of hydraulic permeability obtained from slug tests and grain size analyses, 89 measurements of water electrical conductivity in groundwater, and four geological logs. On average the IP-derived and measured permeability values agreed within one order of magnitude, except for those close to boundaries between lithological layers (e.g. between sand and clay), where mismatches occurred due to the lack of vertical resolution in the geophysical imaging. An average formation factor was estimated from the correlation between the imaged bulk conductivity values and the water conductivity values measured in groundwater, in order to

  18. Determination of hydrogen permeability in uncoated and coated superalloys

    Science.gov (United States)

    Bhattacharyya, S.; Vesely, E. J., Jr.; Hill, V. L.

    1981-01-01

    Hydrogen permeability, diffusivity, and solubility data were obtained for eight wrought and cast high temperature alloys over the range 650 to 815 C. Data were obtained for both uncoated alloys and wrought alloys coated with four commercially available coatings. Activation energies for permeability, diffusivity and solubility were calculated.

  19. Very high geothermal gradient in near surface of the Whataroa Valley adjacent to the Alpine Fault: topographic driving forces and permeable mountains

    Science.gov (United States)

    Upton, P.; Sutherland, R.; Townend, J.; Coussens, J.; Capova, L.

    2015-12-01

    The first phase of the Deep Fault Drilling Project (DFDP-1B) yielded a geothermal gradient of 62.6 ± 2.1 °C/km from a depth of 126 m where it intersected the Alpine Fault principal slip surface beneath Gaunt Creek (Sutherland et al. 2012). Ambient fluid pressures in DFDP-2B at Whataroa River were 8-10% above hydrostatic and a geothermal gradient of >130°C/km was determined, the geothermal gradient being considerably higher than we had predicted previously. 3D coupled thermal/fluid flow models have been generated of the Whataroa Valley and the DFDP-2 drill site. Modelling confirms that the following features, present in the Whataroa Valley, are a requirement for a geothermal gradient of >130°C/km at a depth of 1km beneath the valley; high topography, permeability on the order of 10-15 m2 in both the mountains and beneath the valleys to depths of > 1km below the valley floor, and abundant fluid. The high permeability and large topographic driving force leads to abundant meteoric water flowing downward through the mountains, hitting the permeability barrier of the Alpine Fault and being pushed upward into the valleys. The high geothermal gradient of the DFDP-2B borehole implies that the valleys also have a very high permeability which is likely a result of rock damage along the Alpine Fault.

  20. The use of stable isotopes to trace oil sands constituents

    International Nuclear Information System (INIS)

    Farwell, A.J.; Nero, V.; Dixon, D.G.

    2002-01-01

    A study was conducted to determine the biological effects of oil sands mining operations on aquatic ecosystems. The study focused on the Athabasca oil sand deposit, the largest of 4 deposits in northern Alberta. In particular, the study examined the cycling of oil sand constituents in Benthic invertebrates collected from test pits at Syncrude Canada Ltd.. The invertebrates were similar in size, but different in the quantity of process-affected water or mature fine tailings containing residual bitumen. Dragonflies and damselflies in particular, showed trends of depletion for the carbon 13 isotope and enrichment in nitrogen 15 isotope in pits where levels of process affected water was high. The depletion of carbon 13 isotope suggests that oil sand constituents assimilate into the benthic food chain. The greatest carbon 13 depletion, which was approximately 27 per cent, was found to be in test pits with high turbidity. This implies that oil sands constituents degrade microbially instead of by photosynthetic production. All benthic invertebrate group demonstrated an incremental enrichment in nitrogen 15 isotope from the control pit to the pit with greatest levels of mature fine tailings

  1. Provenance and recycling of Arabian desert sand

    Science.gov (United States)

    Garzanti, Eduardo; Vermeesch, Pieter; Andò, Sergio; Vezzoli, Giovanni; Valagussa, Manuel; Allen, Kate; Kadi, Khalid A.; Al-Juboury, Ali I. A.

    2013-05-01

    This study seeks to determine the ultimate origin of aeolian sand in Arabian deserts by high-resolution petrographic and heavy-mineral techniques combined with zircon U-Pb geochronology. Point-counting is used here as the sole method by which unbiased volume percentages of heavy minerals can be obtained. A comprehensive analysis of river and wadi sands from the Red Sea to the Bitlis-Zagros orogen allowed us to characterize all potential sediment sources, and thus to quantitatively constrain provenance of Arabian dune fields. Two main types of aeolian sand can be distinguished. Quartzose sands with very poor heavy-mineral suites including zircon occupy most of the region comprising the Great Nafud and Rub' al-Khali Sand Seas, and are largely recycled from thick Lower Palaeozoic quartzarenites with very minor first-cycle contributions from Precambrian basement, Mesozoic carbonate rocks, or Neogene basalts. Instead, carbonaticlastic sands with richer lithic and heavy-mineral populations characterize coastal dunes bordering the Arabian Gulf from the Jafurah Sand Sea of Saudi Arabia to the United Arab Emirates. The similarity with detritus carried by the axial Tigris-Euphrates system and by transverse rivers draining carbonate rocks of the Zagros indicates that Arabian coastal dunes largely consist of far-travelled sand, deposited on the exposed floor of the Gulf during Pleistocene lowstands and blown inland by dominant Shamal northerly winds. A dataset of detrital zircon U-Pb ages measured on twelve dune samples and two Lower Palaeozoic sandstones yielded fourteen identical age spectra. The age distributions all show a major Neoproterozoic peak corresponding to the Pan-African magmatic and tectonic events by which the Arabian Shield was assembled, with minor late Palaeoproterozoic and Neoarchean peaks. A similar U-Pb signature characterizes also Jafurah dune sands, suggesting that zircons are dominantly derived from interior Arabia, possibly deflated from the Wadi al

  2. Mobil Oil Canada : Kearl Oil Sands Mine

    International Nuclear Information System (INIS)

    1997-01-01

    The upgrader design at Mobil's Kearl Oil Sands Mine were described. Included were feed characteristics, upgrader products, process schemes and their overall economics and upgrader technologies in use, including coking, deasphalting, hydrocracking, hydrotreating and visbreaking. Advantages and disadvantages of the upgrader technologies were highlighted. As far as the product is concerned, much of it is destined to U.S. refineries that are equipped to process the material. The Kearl Oil Sands Mine upgrading facility will likely use a combination of coker/hydrotreating, which is a well proven process for high value products that has been used in all five of Mobil's refineries in the U.S., and visbreaker/deasphalting, which has shown promise in bench-scale testing, but at present still has some potential commercial difficulties. Foremost among these are the high softening product of asphalt from visbroken products, questionable commercial feasibility of the low yield of pitch, and problems in the disposal of asphalt. Severe visbreaking also yields unstable products. Details of Mobil Canada's oil sands project were also summarized 2 tabs., 9 figs

  3. Phase behaviour of disordered proteins underlying low density and high permeability of liquid organelles

    Science.gov (United States)

    Wei, Ming-Tzo; Elbaum-Garfinkle, Shana; Holehouse, Alex S.; Chen, Carlos Chih-Hsiung; Feric, Marina; Arnold, Craig B.; Priestley, Rodney D.; Pappu, Rohit V.; Brangwynne, Clifford P.

    2017-11-01

    Many intracellular membraneless organelles form via phase separation of intrinsically disordered proteins (IDPs) or regions (IDRs). These include the Caenorhabditis elegans protein LAF-1, which forms P granule-like droplets in vitro. However, the role of protein disorder in phase separation and the macromolecular organization within droplets remain elusive. Here, we utilize a novel technique, ultrafast-scanning fluorescence correlation spectroscopy, to measure the molecular interactions and full coexistence curves (binodals), which quantify the protein concentration within LAF-1 droplets. The binodals of LAF-1 and its IDR display a number of unusual features, including 'high concentration' binodal arms that correspond to remarkably dilute droplets. We find that LAF-1 and other in vitro and intracellular droplets are characterized by an effective mesh size of ∼3-8 nm, which determines the size scale at which droplet properties impact molecular diffusion and permeability. These findings reveal how specific IDPs can phase separate to form permeable, low-density (semi-dilute) liquids, whose structural features are likely to strongly impact biological function.

  4. Casting Ductile Iron in Layer Moulds Made from Ecological Sands

    Directory of Open Access Journals (Sweden)

    M. Rączka

    2012-09-01

    Full Text Available The article contains the results of tests performed under the target project in Hardtop Foundry Charsznica.The objective of the tests and studies was to develop a technology of making high-quality ductile iron castings, combined witheffective means of environmental protection. The studies presented in this article related to castings weighing from 1 to 300 kg made from ductile iron of grades 400-15 and 500-7, using two-layer moulds, where the facing and core sand was the sand with an alkaline organic binder, while backing sand was the sand with an inorganic geopolymer binder.A simplified method of sand reclamation was applied with possible reuse of the reclaim as an addition to the backing sand. The castiron spheroidising treatment and inoculation were selected taking into account the specific conditions of Hardtop Foundry. A pilot batch of castings was made, testing the gating and feeding systems and using exothermic sleeves on risers. The study confirmed the validity of the adopted concept of making ductile iron castings in layer moulds, while maintaining the content of sand with an organic binder at a level of maximum 15%.

  5. The Effect of Excipients on the Permeability of BCS Class III Compounds and Implications for Biowaivers

    OpenAIRE

    Parr, Alan; Hidalgo, Ismael J.; Bode, Chris; Brown, William; Yazdanian, Mehran; Gonzalez, Mario A.; Sagawa, Kazuko; Miller, Kevin; Jiang, Wenlei; Stippler, Erika S.

    2015-01-01

    Purpose Currently, the FDA allows biowaivers for Class I (high solubility and high permeability) and Class III (high solubility and low permeability) compounds of the Biopharmaceutics Classification System (BCS). Scientific evidence should be provided to support biowaivers for BCS Class I and Class III (high solubility and low permeability) compounds. Methods Data on the effects of excipients on drug permeability are needed to demonstrate that commonly used excipients do not affect the permea...

  6. Non-monotonic permeability variation during colloidal transport: Governing equations and analytical model

    Science.gov (United States)

    Chequer, L.; Russell, T.; Behr, A.; Genolet, L.; Kowollik, P.; Badalyan, A.; Zeinijahromi, A.; Bedrikovetsky, P.

    2018-02-01

    Permeability decline associated with the migration of natural reservoir fines impairs the well index of injection and production wells in aquifers and oilfields. In this study, we perform laboratory corefloods using aqueous solutions with different salinities in engineered rocks with different kaolinite content, yielding fines migration and permeability alteration. Unusual permeability growth has been observed at high salinities in rocks with low kaolinite concentrations. This has been attributed to permeability increase during particle detachment and re-attachment of already mobilised fines by electrostatic attraction to the rock in stagnant zones of the porous space. We refine the traditional model for fines migration by adding mathematical expressions for the particle re-attachment rate, particle detachment with delay relative to salinity decrease, and the attached-concentration-dependency of permeability. A one-dimensional flow problem that accounts for those three effects allows for an exact analytical solution. The modified model captures the observed effect of permeability increase at high water salinities in rocks with low kaolinite concentrations. The developed model matches the coreflooding data with high accuracy, and the obtained model coefficients vary within their usual intervals.

  7. Hydro-mechanical behaviour of bentonite-sand mixture used as sealing materials in radioactive waste disposal galleries

    International Nuclear Information System (INIS)

    Saba, Simona

    2013-01-01

    In order to verify the effectiveness of the geological high-level radioactive waste disposal, the French Institution of Radiation protection and Nuclear Safety (IRSN) has implemented the SEALEX project to control the long-term performance of swelling clay-based sealing systems, and to which this work is closely related. Within this project, In-situ tests are carried out on compacted bentonite-sand mixture in natural conditions and in a representative scale. This material is one of the most appropriate sealing materials because of its low permeability and good swelling capacity. Once installed, this material will be hydrated by water from the host-rock and start swelling to close all gaps in the system, in particular the internal pores, rock fractures and technological voids. Afterwards, swelling pressure will develop. In the present work, laboratory experiments were performed to investigate the sealing properties under this complex hydro-mechanical conditions taking into consideration the effect of technological voids. The microstructure of the material in its initial state was first examined by microfocus X-ray computed tomography (μCT). This allowed identification of the distribution of grains of sand and bentonite as well as the pores in the sample. Macro-pores are found concentrated at the periphery of the sample and between the grains of sand, which could affect in the short term the permeability. The hydration of the same material in limited swelling conditions was then observed by 2D photography and 3D μCT. The swelling mechanism with bentonite gel production, the swelling kinetics, the density decrease and the homogenisation of the material were analyzed. The hydration in the conditions of prevented swelling was also studied by swelling pressure tests with radial and axial measurements of swelling pressure. The difference found between the axial and radial swelling pressures suggested the presence of an anisotropic microstructure. Mock-up tests at a 1

  8. Hydro-mechanical behaviour of bentonite-sand mixture used as sealing materials in radioactive waste disposal galleries

    International Nuclear Information System (INIS)

    Saba, Simona

    2013-01-01

    In order to verify the effectiveness of the geological high-level radioactive waste disposal, the French Institute for Radiation protection and Nuclear Safety (IRSN) has implemented the SEALEX project to control the long-term performance of swelling clay-based sealing systems, and to which this work is closely related. Within this project, In-situ tests are carried out on compacted bentonite-sand mixture in natural conditions and in a representative scale. This material is one of the most appropriate sealing materials because of its low permeability and good swelling capacity. Once installed, this material will be hydrated by water from the host-rock and start swelling to close all gaps in the system, in particular the internal pores, rock fractures and technological voids. Afterwards, swelling pressure will develop. In the present work, laboratory experiments were performed to investigate the sealing properties under these complex hydro-mechanical conditions taking into consideration the effect of technological voids. The microstructure of the material in its initial state was first examined by microfocus X-ray computed tomography (μCT). This allowed identification of the distribution of grains of sand and bentonite as well as the pores in the sample. Macro-pores are found concentrated at the periphery of the sample and between the grains of sand, which could affect in the short term the permeability. The hydration of the same material in limited swelling conditions was then observed by 2D photography and 3D μCT. The swelling mechanism with bentonite gel production, the swelling kinetics, the density decrease and the homogenisation of the material were analyzed. The hydration in the conditions of prevented swelling was also studied by swelling pressure tests with radial and axial measurements of swelling pressure. The difference found between the axial and radial swelling pressures suggested the presence of an anisotropic microstructure. Mock-up tests at a 1

  9. On Pluvial Compaction of Sand

    DEFF Research Database (Denmark)

    Jacobsen, Moust

    At the Institute of Civil Engineering in Aalborg model tests on dry sand specimens have been carried out during the last five years. To reduce deviations in test results, the sand laying technique has been carefully studied, and the sand mass spreader constructed. Preliminary results have been...

  10. MORPHOMETRIC CHARACTERIZATION OF THE SAND FRACTION IN A SAND GRAIN IMAGE CAPTURE SYSTEM1

    Directory of Open Access Journals (Sweden)

    Lucimar Arruda Viana

    Full Text Available ABSTRACT Morphology studies assume significant importance in analysis of phenomena of granular systems packaging, in particular with a view to the use of the technique of soil stabilization named particle size correction in forest roads. In this context, this study aimed to develop and operationalize a Sand Grain Image Capture System and, hereby, determine the morphological indices of the sand fractions of two sandy soils called João Pinheiro (JP and Cachoeira da Prata (CP. Soil samples, air-dried, were sieved (2.0 mm nominal mesh size for removal of gravels. The materials that passed through the sieve were subjected to dispersion, washing in 0.053 mm nominal mesh size sieve, removal of organic matter and iron oxides to obtain the clean sand fractions. Subsequently, each soil sample was sieved for separation into twelve classes, between the diameters of 0.149 mm and 1.190 mm, using a Rotap shaker. Next, tests were carried out to characterize the morphometric attributes of the twelve classes of sand fractions of the soils studied. For validation of the performance of the Sand Grain Image Capture System, the results were compared to those obtained using a standard procedure for image analysis. The analysis of the results led to the following conclusions: (i the sand fraction of the JP soil presented higher values for the morphometric indices roundness, elongation and compactness compared to sand fraction of the CP soil; and (ii the Sand Grain Image Capture System worked properly, with practicality.

  11. Technology unlocks tar sands energy

    Energy Technology Data Exchange (ETDEWEB)

    Law, C

    1967-09-25

    Tar sand processing technology has been developed primarily in the categories of extraction techniques and in-situ processing. In October, a $235 million venture into tar sand processing will be inspected by visitors from many points on the globe. A synthetic crude of premium quality will be flowing through a 16-in. pipeline from the Tar Island plant site of Great Canadian Oil Sands to Edmonton. This processing plant uses an extractive mining technique. The tar sand pay zone in this area averages approximately 150 ft in thickness with a 50-ft overburden. It has been estimated that the tar sands cannot be exploited when the formation thickness is less than 100 ft and overburden exceeds the same amount. This indicates that extraction techniques can only be used to recover approximately 15% of the tar sand deposits. An in-situ recovery technique developed by Shell of Canada is discussed in detail. In essence it is selective hydraulic fracturing, followed by the injection of emulsifying chemicals and steam.

  12. Making synthetic mudstone: Parametric resedimentation studies at high effective stress to determine controls on breakthrough pressure and permeability

    Science.gov (United States)

    Guiltinan, E. J.; Cardenas, M. B.; Cockrell, L.; Espinoza, N.

    2017-12-01

    The geologic sequestration of CO2 is widely considered a potential solution for decreasing anthropogenic atmospheric CO2 emissions. As CO2 rises buoyantly within a reservoir it pools beneath a caprock and a pressure is exerted upon the pores of the caprock proportionally to the height of the pool. The breakthrough pressure is the point at which CO2 begins to flow freely across the caprock. Understanding the mineralogical and grain size controls on breakthrough pressure is important for screening the security of CO2 sequestration sites. However, breakthrough pressure and permeability measurements on caprocks are difficult to conduct in a systematic manner given the variability in and heterogeneity of naturally occurring mudstones and shales causing significant noise and scatter in the literature. Recent work has even revealed the ability for CO2 to pass through thin shale beds at relatively low pressures. To broaden the understanding of shale breakthrough and permeability, we developed an approach that allows for the creation of resedimented mudstones at high effective stresses. Resedimented samples also include calcium carbonate cement. Using this technique, we explore the controls on entry pressure, breakthrough pressure, and permeability of synthetic mudstones. Understanding the effect of mineralogy and grain size on the permeability and breakthrough pressure of mudstones at reservoir stresses will help in the selection and uncertainty quantification of secure CO2 storage sites.

  13. Essential application of depositional analysis and interpretation in hydrogeologic assessments of contaminated sites

    International Nuclear Information System (INIS)

    Sciacca, J.

    1991-01-01

    In most hydrogeologic studies of contaminated sites, little attention is given to analysis of depositional environments and associated depositional patterns. This analysis is essential for sedimentary deposits present at a majority of these sites. The depositional processes associated with alluvial, fluvial and deltaic environments yield heterogeneity ranging from large to small scale. These processes also yield preferential grain orientations in coarse grained units which result in preferential directions of increased permeability. Studies conducted in fluvial and deltaic petroleum reservoirs have shown varying permeabilities resulting from deposition that strongly control the flow of fluids. The marked heterogeneity evident in the sandy portion of a single 3 to 30-foot thick fluvial point bar deposit can exert significant differences in porous flow. Preferential permeability has been shown parallel to the long axis of fluvial channel sand units while barrier beach sands exhibit preferential permeability perpendicular to the long axis of the sand body. Such controls influence natural flow and transport of contaminants in groundwater. Hydrogeologic studies should: determine the depositional environment and facies present at the site; determine the propensity for heterogeneity within the entire vertical sequence investigated and within the different facies present; assess the potential for preferential permeability within sand bodies; and provide a predictive depositional model to assess potential connections between major high permeability units. Sand unit connections are commonly forced during cross section generation and subsequent aquifer analysis. Failure to incorporate the above objectives in hydrogeologic investigations ignores the basic precept that process controls the distribution of permeability and will result in poor prediction of natural and remedial transport of contaminants in groundwater

  14. Study on the basic properties of Indonesian oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qing; Jiang, Qian-qian; Bai, Jing-ru; Sun, Jian; Liu, Hong-peng [Northeast Dianli Univ., Jilin (China). Inst. of Energy and Power Engineering

    2013-07-01

    The basic properties of three Indonesian oil sands have been investigated. The results show that since the high content of volatile, heating value and oil yield, Indonesian oil sands could be combusted for power generation and retorting for oil refining. Moreover, oil sand ash with the low content of fixed carbon and high content of CaO, could not only be used as solid heat carrier during retorting, but also comprehensively used as construction material. Based on the thermogravimeric analysis (TGA), pyrolysis and combustion behaviors have been identified. As for pyrolysis, 350-520 C could be regarded as the major oil-producing region, the apparent activation energy E is not a constant obtained by distributed activation energy model (DAEM). For combustion, 620-800 C is the high-temperature oxidation (HTO) stage. TG-DTG extrapolation method was applied to determine the combustion characteristics parameters such as ignition temperature, burn-out temperature, combustion stability and combustion reactivity, and finally gave a comparison with those of oil shale and coal.

  15. Effect of the aggregate grading on the concrete air permeability

    Directory of Open Access Journals (Sweden)

    Argiz, C.

    2014-09-01

    Full Text Available Great durability problems are being found in concrete structures related to the penetrability of aggressive agents through the concrete (ie. chloride penetration, sulphate attack, carbonation, freezing and thawing, and so on. Air permeability coefficient is used as an effective tool to estimate the potential durability of concrete structures due to its direct relation with the microstructure and the moisture content. This paper discusses the effect of the aggregate grading and water/cement ratio on the air permeability coefficient. An aggregate grading with more sand than coarse aggregates has resulted more beneficial from the point of view of concrete air permeability. This fact can be attributed to a denser skeleton formed by the finer aggregates. With fine aggregates, the higher water/cement ratio, the lower air permeability. However, the contrary was found with coarse aggregates. Overall, a temperature increase from 20 °C to 60 °C during preconditioning led to a Dair increase of 40–80%.Se han encontrado una gran cantidad de problemas de durabilidad de estructuras de hormigón relacionados con la penetración de agentes agresivos externos (es decir, penetración de cloruros, ataque por sulfatos, carbonatación, hielo-deshielo, etc.. El coeficiente de permeabilidad al aire se utiliza como una herramienta eficaz para estimar la durabilidad potencial de las estructuras de hormigón debido a su relación directa con su microestructura y contenido de humedad. Se discute el efecto de la gradación de los áridos y relación agua/cemento en el coeficiente de permeabilidad al aire. Con áridos más finos que gruesos, el resultado es más beneficioso, lo que se atribuye a que la arena forma un esqueleto más denso. Con áridos más finos, al aumentar la relación agua/cemento, disminuye la permeabilidad al aire; pero con áridos más gruesos se ha observado lo contrario. Cuando se pre-acondiciona de 20 °C a 60 °C, se produce un aumento del Dair

  16. Geohydrology of the valley-fill aquifer in the Endicott-Johnson City area, Broome County, New York

    Science.gov (United States)

    Holecek, Thomas J.; Randall, A.D.; Belli, J.L.; Allen, R.V.

    1982-01-01

    This report is the tenth in a series of 11 map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on five maps at 1:24,000 scale. Together, the maps provide a comprehensive overview of a major valley-fill aquifer in southwestern Broome County. The maps include surficial geology, geologic sections, aquifer thickness, water-infiltration potential of soil zone, potentiometric-surface altitude, and land use. The valley-fill deposits consist of alluvial silt and sand, glacial outwash (sand and gravel), ice-contact sand and gravel, till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities whereas the till, silt, and clay deposits have relatively low permeabilities. Water-table conditions are found in unconfined sand and gravel, whereas artesian conditions prevail within sand and gravel confined by silty deposits. Recharge occurs over the entire surface of the aquifer, due to permeable land-surface conditions, but is greatest along the margin of the valley, where runoff from the hillsides is concentrated, and near streams. The use of land overlying the aquifer is predominantly commercial and residential with lesser amounts of agricultural and industrial uses. (USGS)

  17. Geohydrology of the valley-fill aquifer in the South Fallsburgh-Woodbourne area, Sullivan County, New York

    Science.gov (United States)

    Anderson, H.R.; Dineen, R.J.; Stelz, W.G.; Belli, J.L.

    1982-01-01

    This report is the ninth in a series of map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on six maps at 1:24,000 scale. Together the maps provide a comprehensive overview of a major valley-fill aquifer in southeastern Sullivan County. The maps include surficial geology, geologic sections, aquifer thickness, water-infiltration potential of soil zone, potentiometric surface elevations, well yields, and land use. The valley-fill deposits consist of alluvial silt and sand, glacial outwash (sand and gravel), ice-contact sand and gravel, till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities whereas the till, silt, and clay deposits have relatively low permeabilities. Water-table conditions prevail in unconfined sand and gravel whereas artesian conditions prevail within sand and gravel confined by silty deposits. The aquifer is recharged throughout, where the land surface is most permeable and is greatest along the margin of the valley, where runoff from the hillsides is concentrated. The use of land overlying the aquifer is predominantly commercial, agricultural, and residential with lesser industrial uses. (USGS)

  18. Oil sands tax expenditures

    International Nuclear Information System (INIS)

    Ketchum, K; Lavigne, R.; Plummer, R.

    2001-01-01

    The oil sands are a strategic Canadian resource for which federal and provincial governments provide financial incentives to develop and exploit. This report describes the Oil Sands Tax Expenditure Model (OSTEM) developed to estimate the size of the federal income tax expenditure attributed to the oil sands industry. Tax expenditures are tax concessions which are used as alternatives to direct government spending for achieving government policy objectives. The OSTEM was developed within the business Income Tax Division of Canada's Department of Finance. Data inputs for the model were obtained from oil sands developers and Natural Resources Canada. OSTEM calculates annual revenues, royalties and federal taxes at project levels using project-level projections of capital investment, operating expenses and production. OSTEM calculates tax expenditures by comparing taxes paid under different tax regimes. The model also estimates the foregone revenue as a percentage of capital investment. Total tax expenditures associated with investment in the oil sands are projected to total $820 million for the period from 1986 to 2030, representing 4.6 per cent of the total investment. 10 refs., 2 tabs., 7 figs

  19. The distribution and migration of sodium from a reclaimed upland to a constructed fen peatland in a post-mined oil sands landscape.

    Science.gov (United States)

    Kessel, Eric D; Ketcheson, Scott J; Price, Jonathan S

    2018-07-15

    Post-mine landscape reclamation of the Athabasca Oil Sands Region requires the use of tailings sand, an abundant mine-waste material that often contains large amounts of sodium (Na + ). Due to the mobility of Na + in groundwater and its effects on vegetation, water quality is a concern when incorporating mine waste materials, especially when attempting to construct groundwater-fed peatlands. This research is the first published account of Na + redistribution in groundwater from a constructed tailings sand upland to an adjacent constructed fen peat deposit (Nikanotee Fen). A permeable petroleum coke layer underlying the fen, extending partway into the upland, was important in directing flow and Na + beneath the peat, as designed. Initially, Na + concentration was highest in the tailings sand (average of 232mgL -1 ) and lowest in fen peat (96mgL -1 ). Precipitation-driven recharge to the upland controlled the mass flux of Na from upland to fen, which ranged from 2 to 13tons Na + per year. The mass flux was highest in the driest summer, in part from dry-period flowpaths that direct groundwater with higher concentrations of Na + into the coke layer, and in part because of the high evapotranspiration loss from the fen in dry periods, which induces upward water flow. With the estimated flux rates of 336mmyr -1 , the Na + arrival time to the fen surface was estimated to be between 4 and 11years. Over the four-year study, average Na + concentrations within the fen rooting zone increased from 87 to 200mgL -1 , and in the tailings sand decreased to 196mgL -1 . The planting of more salt-tolerant vegetation in the fen is recommended, given the potential for Na + accumulation. This study shows reclamation designs can use layered flow system to control the rate, pattern, and timing of solute interactions with surface soil systems. Crown Copyright © 2018. Published by Elsevier B.V. All rights reserved.

  20. Oxygen profile and clogging in vertical flow sand filters for on-site wastewater treatment.

    Science.gov (United States)

    Petitjean, A; Forquet, N; Boutin, C

    2016-04-01

    13 million people (about 20% of the population) use on-site wastewater treatment in France. Buried vertical sand filters are often built, especially when the soil permeability is not sufficient for septic tank effluent infiltration in undisturbed soil. Clogging is one of the main problems deteriorating the operation of vertical flow filters for wastewater treatment. The extent of clogging is not easily assessed, especially in buried vertical flow sand filters. We suggest examining two possible ways of detecting early clogging: (1) NH4-N/NO3-N outlet concentration ratio, and (2) oxygen measurement within the porous media. Two pilot-scale filters were equipped with probes for oxygen concentration measurements and samples were taken at different depths for pollutant characterization. Influent and effluent grab-samples were taken three times a week. The systems were operated using batch-feeding of septic tank effluent. Qualitative description of oxygen transfer processes under unclogged and clogged conditions is presented. NH4-N outlet concentration appears to be useless for early clogging detection. However, NO3-N outlet concentration and oxygen content allows us to diagnose the early clogging of the system. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Environmental characterization foundry sands used in sanitary landfills; Caracterizacao ambiental de areias descartadas de fundicao utilizadas na cobertura de residuos em aterros sanitarios

    Energy Technology Data Exchange (ETDEWEB)

    Domingues, L.G.F.; Ferreira, G.C.S.; Pires, M.S.G.; Teixeira, I.; Carnin, R.; Sarro, W.S., E-mail: lucienegferrari@gmail.com [Universidade Estadual de Campinas (UNICAMP), SP (Brazil)

    2016-07-01

    The national solid waste policy recommends reducing solid waste generation and reusing them in different applications. Preliminary studies show that the foundry sand generated from cast metal parts undercut, has excellent applicability in grain size stabilization of soils for geotechnical functions, and therefore, should not be discarded as waste. This study aimed at environmental characterization of two lots of waste foundry sand (WFS), from different industries, to the particle size stabilization of a clayey soil for use in coverage of solid waste in landfills. The methodology included physicochemical characterization tests (grain size, permeability, XRF and heavy metals) and environmental (NBR 10004: 2004, NBR 10005: 2004, NBR 10006: 20004 and acute toxicity with Vibrio fischeri). The results prove the environmental viability of using these lots of WFS as functional material in the composition of landfills. (author)

  2. Preliminary study of the irradiation-induced modification of skin permeability

    International Nuclear Information System (INIS)

    Coelho, R.; Istin, M.

    1978-01-01

    Irradiation of the skin of an animal leads immediately to a strong increase in vascular permeability. If a dye is at once injected intraveinously it diffuses very rapidly in the irradiated zone, this becomes highly coloured and the colour intensity measurement gives a clue to the severity of the lesions produced. This phenomenon has been used in the past as a pharmacological test to study vascular permeability and is employed in this work to observe the effect of diosmine-titrated flavonoids on vascular permeability in inflammatory diseases. The capillary permeability increase due to local γ irradiation of rabbit skin has been accurately determined by measurement of the colouration observed after injection of Geigy Blue. Diosmine, injected intraperitoneally, protects the vascular system against increased permeability due to ionising radiations [fr

  3. Permeability, storage and hydraulic diffusivity controlled by earthquakes

    Science.gov (United States)

    Brodsky, E. E.; Fulton, P. M.; Xue, L.

    2016-12-01

    Earthquakes can increase permeability in fractured rocks. In the farfield, such permeability increases are attributed to seismic waves and can last for months after the initial earthquake. Laboratory studies suggest that unclogging of fractures by the transient flow driven by seismic waves is a viable mechanism. These dynamic permeability increases may contribute to permeability enhancement in the seismic clouds accompanying hydraulic fracking. Permeability enhancement by seismic waves could potentially be engineered and the experiments suggest the process will be most effective at a preferred frequency. We have recently observed similar processes inside active fault zones after major earthquakes. A borehole observatory in the fault that generated the M9.0 2011 Tohoku earthquake reveals a sequence of temperature pulses during the secondary aftershock sequence of an M7.3 aftershock. The pulses are attributed to fluid advection by a flow through a zone of transiently increased permeability. Directly after the M7.3 earthquake, the newly damaged fault zone is highly susceptible to further permeability enhancement, but ultimately heals within a month and becomes no longer as sensitive. The observation suggests that the newly damaged fault zone is more prone to fluid pulsing than would be expected based on the long-term permeability structure. Even longer term healing is seen inside the fault zone of the 2008 M7.9 Wenchuan earthquake. The competition between damage and healing (or clogging and unclogging) results in dynamically controlled permeability, storage and hydraulic diffusivity. Recent measurements of in situ fault zone architecture at the 1-10 meter scale suggest that active fault zones often have hydraulic diffusivities near 10-2 m2/s. This uniformity is true even within the damage zone of the San Andreas fault where permeability and storage increases balance each other to achieve this value of diffusivity over a 400 m wide region. We speculate that fault zones

  4. Singing Sand Dunes

    Indian Academy of Sciences (India)

    ble low-frequency (s. 75–105 Hz), that can some- times be heard up to 10 km away. Scientific in- vestigations suggest that the sustained low fre- quency sound of sand dunes that resembles a pure note from a musical instrument, is due to the synchronized motion of well-sorted dry sand grains when they spontaneously ...

  5. Comparisons of Unconsolidated Sediments Analyzed by APXS (MSL-Curiosity) within Gale Crater, Mars: Soils, Sands of the Barchan and Linear Dunes of the Active Bagnold Dune Field, and Ripple-field Sands.

    Science.gov (United States)

    Thompson, L. M.; O'Connell-Cooper, C.; Spray, J. G.; Gellert, R.; Boyd, N. I.; Desouza, E.

    2017-12-01

    The MSL-APXS has analyzed a variety of unconsolidated sediments within the Gale impact crater, including soils, sands from barchan [High, Namib dunes], and linear dunes [Nathan Bridges, Mount Desert dunes], within the active Bagnold dune field, and sands from two smaller ripple fields ("mega-ripples"). The Gale "soils" (unsorted, unconsolidated sediments, ranging from fine-grained particles (including dust) to coarser "pebbly" material [>2 mm]), are, to a large degree, similar to Martian basaltic soils quantified by APXS, at Gusev crater (MER-A_Spirit) and Meridiani Planum (MER-B_Opportunity). Some local contributions are indicated by, for example, the enriched K levels (relative to a martian average basaltic soil [ABS]) within coarser Gale soil samples, and a Cr, Mn, Fe enrichment within finer-grained samples. Sands (grain size 62 µm to 2 mm) of the Bagnold dunes, generally, exhibit elevated Mg and Ni, indicating enrichment from olivine and pyroxene, but depleted S, Cl and Zn, indicating high activity levels and low dust. Compositional differences, related both to position within a dune (i.e., crest versus off-crest sand), and type of dune (linear versus barchan), are identified. Off-crest sands have Na, Al, Si, K, P contents similar to (or slightly depleted, relative to) the ABS, enrichment in Mg, and low dust content, whilst crest sands contain very high Mg and Ni (relative to the ABS), low felsic elemental concentrations and very low dust content. Cr is significantly enriched (and, to a lesser degree, Mn, Fe, Ti) in the off-crest sands of the linear dunes. In contrast, barchan dunes off-crest sands have Cr, Mn, Fe, and Ti abundances similar to those in the Gale soils. Additionally, Ni concentrations in barchan dunes off-crest sands are enriched relative to the linear dunes. Analyses from a small, isolated "mega-ripple" reveal a composition similar to that of the Gale soils, including a high dust content. The second mega-ripple, within a larger ripple field, is

  6. Varying Inundation Regimes Differentially Affect Natural and Sand-Amended Marsh Sediments.

    Directory of Open Access Journals (Sweden)

    C Wigand

    Full Text Available Climate change is altering sea level rise rates and precipitation patterns worldwide. Coastal wetlands are vulnerable to these changes. System responses to stressors are important for resource managers and environmental stewards to understand in order to best manage them. Thin layer sand or sediment application to drowning and eroding marshes is one approach to build elevation and resilience. The above- and below-ground structure, soil carbon dioxide emissions, and pore water constituents in vegetated natural marsh sediments and sand-amended sediments were examined at varying inundation regimes between mean sea level and mean high water (0.82 m NAVD88 to 1.49 m NAVD88 in a field experiment at Laws Point, part of the Plum Island Sound Estuary (MA. Significantly lower salinities, pH, sulfides, phosphates, and ammonium were measured in the sand-amended sediments than in the natural sediments. In natural sediments there was a pattern of increasing salinity with increasing elevation while in the sand-amended sediments the trend was reversed, showing decreasing salinity with increasing elevation. Sulfide concentrations generally increased from low to high inundation with highest concentrations at the highest inundation (i.e., at the lowest elevations. High pore water phosphate concentrations were measured at low elevations in the natural sediments, but the sand-amended treatments had mostly low concentrations of phosphate and no consistent pattern with elevation. At the end of the experiment the lowest elevations generally had the highest measures of pore water ammonium. Soil carbon dioxide emissions were greatest in the sand-amended mesocosms and at higher elevations. Differences in coarse root and rhizome abundances and volumes among the sediment treatments were detected with CT imaging, but by 20 weeks the natural and sand-amended treatments showed similar total belowground biomass at the intermediate and high elevations. Although differences in

  7. Modeling fine-scale geological heterogeneity-examples of sand lenses in tills

    DEFF Research Database (Denmark)

    Kessler, Timo Christian; Comunian, Alessandro; Oriani, Fabio

    2013-01-01

    that hamper subsequent simulation. Transition probability (TP) and multiple-point statistics (MPS) were employed to simulate sand lens heterogeneity. We used one cross-section to parameterize the spatial correlation and a second, parallel section as a reference: it allowed testing the quality......Sand lenses at various spatial scales are recognized to add heterogeneity to glacial sediments. They have high hydraulic conductivities relative to the surrounding till matrix and may affect the advective transport of water and contaminants in clayey till settings. Sand lenses were investigated...... on till outcrops producing binary images of geological cross-sections capturing the size, shape and distribution of individual features. Sand lenses occur as elongated, anisotropic geobodies that vary in size and extent. Besides, sand lenses show strong non-stationary patterns on section images...

  8. Sand dunes of the Gaza Strip (southwestern Palestine: morphology, textural characteristics and associated environmental impacts

    Directory of Open Access Journals (Sweden)

    Khalid Fathi Ubeid

    2014-07-01

    Full Text Available Sand dunes are wide spread in the Gaza Strip and are present in its northern, central and southern regions. Thirty sand samples were collected at seven locations along the middle region of the Strip. The coordinates for each sampling site were positioned using GPS and processed with ArcGIS software. Mechanical and chemical properties were examined to determine the textural characteristics and carbonate contents of the dune sands. The mean grain size is fine to medium, and the sands range from moderate- to well-sorting. The skewness is fine to very fine, and the kurtosis ranges from mesokurtic to very leptokurtic. Additionally, the results show that the carbonate content ranges from 1.5% to 5%. The high permeability, good porosity, and low carbonate content of the sand dunes in the Gaza Strip have led to more groundwater pollution via leachates percolating from the solid waste landfills and basins from wastewater treatments constructed above the sand dunes. Sand quarries have also changed the natural landscape of the Gaza Strip. These quarries were excavated randomly, used for a short period and then disused. This random and unregulated excavation has led to the destruction of natural habitats for flora and fauna.   Resumen Las dunas de arena se extienden ampliamente en la Franja de Gaza y hacen presencia en las regiones del norte, centro y sur. Para este trabajo se recolectaron treinta muestras de arena en siete puntos a lo largo de la región media de la Franja. Las coordenadas de cada muestra se marcaron con el GPS y se procesaron con el programa ArcGIS. Se examinaron las propiedades químicas y mecánicas para determinar las características de textura y los contenidos de carbonato de las dunas de arena. El tamaño del grano está entre fino y medio y las arenas oscilan entre moderadas y bien definidas. La asimetría estadística va desde fina hasta muy fina y la variedad de la curtosis se ubica entre mesocúrtica y muy leptoc

  9. Contemporary sand wedge development in seasonally frozen ground and paleoenvironmental implications

    Science.gov (United States)

    Wolfe, Stephen A.; Morse, Peter D.; Neudorf, Christina M.; Kokelj, Steven V.; Lian, Olav B.; O'Neill, H. Brendan

    2018-05-01

    Contemporary sand wedges and sand veins are active in seasonally frozen ground within the extensive discontinuous permafrost zone in Northwest Territories, Canada. The region has a subarctic continental climate with 291 mm a-1 precipitation, -4.1 °C mean annual air temperature, warm summers (July mean 17.0 °C), and cold winters (January mean -26.6 °C). Five years of continuous observations indicate that interannual variation of the ground thermal regime is dominantly controlled by winter air temperature and snow cover conditions. At sandy sites, thin snow cover and high thermal conductivity promote rapid freezing, high rates of ground cooling, and low near-surface ground temperatures (-15 to -25 °C), resulting in thermal contraction cracking to depths of 1.2 m. Cracking potentials are high in sandy soils when air temperatures are air temperatures are ≤-17 °C, and snow cover is conditions in peatlands maintain permafrost, but thermal contraction cracking does not occur because thicker snow cover and the thermal properties of peat prolong freezeback and maintain higher winter ground temperatures. A combination of radiocarbon dating, optical dating, and stratigraphic observations were used to differentiate sand wedge types and formation histories. Thermal contraction cracks that develop in the sandy terrain are filled by surface (allochthonous) and/or host (autochthonous) material during the thaw season. Epigenetic sand wedges infilled with allochthonous sand develop within former beach sediments beneath an active eolian sand sheet. Narrower and deeper syngenetic wedges developed within aggrading eolian sand sheets, whereas wider and shallower antisyngenetic wedges developed in areas of active erosion. Thermal contraction cracking beneath vegetation-stabilized surfaces leads to crack infilling by autochthonous host and overlying organic material, with resultant downturning and subsidence of adjacent strata. Sand wedge development in seasonally frozen ground

  10. Sub-core permeability and relative permeability characterization with Positron Emission Tomography

    Science.gov (United States)

    Zahasky, C.; Benson, S. M.

    2017-12-01

    This study utilizes preclinical micro-Positron Emission Tomography (PET) to image and quantify the transport behavior of pulses of a conservative aqueous radiotracer injected during single and multiphase flow experiments in a Berea sandstone core with axial parallel bedding heterogeneity. The core is discretized into streamtubes, and using the micro-PET data, expressions are derived from spatial moment analysis for calculating sub-core scale tracer flux and pore water velocity. Using the flux and velocity data, it is then possible to calculate porosity and saturation from volumetric flux balance, and calculate permeability and water relative permeability from Darcy's law. Full 3D simulations are then constructed based on this core characterization. Simulation results are compared with experimental results in order to test the assumptions of the simple streamtube model. Errors and limitations of this analysis will be discussed. These new methods of imaging and sub-core permeability and relative permeability measurements enable experimental quantification of transport behavior across scales.

  11. Augmenting Sand Simulation Environments through Subdivision and Particle Refinement

    Science.gov (United States)

    Clothier, M.; Bailey, M.

    2012-12-01

    Recent advances in computer graphics and parallel processing hardware have provided disciplines with new methods to evaluate and visualize data. These advances have proven useful for earth and planetary scientists as many researchers are using this hardware to process large amounts of data for analysis. As such, this has provided opportunities for collaboration between computer graphics and the earth sciences. Through collaboration with the Oregon Space Grant and IGERT Ecosystem Informatics programs, we are investigating techniques for simulating the behavior of sand. We are also collaborating with the Jet Propulsion Laboratory's (JPL) DARTS Lab to exchange ideas and gain feedback on our research. The DARTS Lab specializes in simulation of planetary vehicles, such as the Mars rovers. Their simulations utilize a virtual "sand box" to test how a planetary vehicle responds to different environments. Our research builds upon this idea to create a sand simulation framework so that planetary environments, such as the harsh, sandy regions on Mars, are more fully realized. More specifically, we are focusing our research on the interaction between a planetary vehicle, such as a rover, and the sand beneath it, providing further insight into its performance. Unfortunately, this can be a computationally complex problem, especially if trying to represent the enormous quantities of sand particles interacting with each other. However, through the use of high-performance computing, we have developed a technique to subdivide areas of actively participating sand regions across a large landscape. Similar to a Level of Detail (LOD) technique, we only subdivide regions of a landscape where sand particles are actively participating with another object. While the sand is within this subdivision window and moves closer to the surface of the interacting object, the sand region subdivides into smaller regions until individual sand particles are left at the surface. As an example, let's say

  12. Permeability criteria for effective function of passive countercurrent multiplier.

    Science.gov (United States)

    Layton, H E; Knepper, M A; Chou, C L

    1996-01-01

    The urine concentrating effect of the mammalian renal inner medulla has been attributed to countercurrent multiplication of a transepithelial osmotic difference arising from passive absorption of NaCl from thin ascending limbs of long loops of Henle. This study assesses, both mathematically and experimentally, whether the permeability criteria for effective function of this passive hypothesis are consistent with transport properties measured in long loops of Henle of chinchilla. Mathematical simulations incorporating loop of Henle transepithelial permeabilities idealized for the passive hypothesis generated a steep inner medullary osmotic gradient, confirming the fundamental feasibility of the passive hypothesis. However, when permeabilities measured in chinchilla were used, no inner medullary gradient was generated. A key parameter in the apparent failure of the passive hypothesis is the long-loop descending limb (LDL) urea permeability, which must be small to prevent significant transepithelial urea flux into inner medullary LDL. Consequently, experiments in isolated perfused thin LDL were conducted to determine whether the urea permeability may be lower under conditions more nearly resembling those in the inner medulla. LDL segments were dissected from 30-70% of the distance along the inner medullary axis of the chinchilla kidney. The factors tested were NaCl concentration (125-400 mM in perfusate and bath), urea concentration (5-500 mM in perfusate and bath), calcium concentration (2-8 mM in perfusate and bath), and protamine concentration (300 micrograms/ml in perfusate). None of these factors significantly altered the measured urea permeability, which exceeded 20 x 10(-5) cm/s for all conditions. Simulation results show that this moderately high urea permeability in LDL is an order of magnitude too high for effective operation of the passive countercurrent multiplier.

  13. Experimental and numerical study on thermal conductivity of partially saturated unconsolidated sands

    Science.gov (United States)

    Lee, Youngmin; Keehm, Youngseuk; Kim, Seong-Kyun; Shin, Sang Ho

    2016-04-01

    A class of problems in heat flow applications requires an understanding of how water saturation affects thermal conductivity in the shallow subsurface. We conducted a series of experiments using a sand box to evaluate thermal conductivity (TC) of partially saturated unconsolidated sands under varying water saturation (Sw). We first saturated sands fully with water and varied water saturation by drainage through the bottom of the sand box. Five water-content sensors were integrated vertically into the sand box to monitor water saturation changes and a needle probe was embedded to measure thermal conductivity of partially saturated sands. The experimental result showed that thermal conductivity decreases from 2.5 W/mK for fully saturated sands to 0.7 W/mK when water saturation is 5%. We found that the decreasing trend is quite non-linear: highly sensitive at very high and low water saturations. However, the boundary effects on the top and the bottom of the sand box seemed to be responsible for this high nonlinearity. We also found that the determination of water saturation is quite important: the saturation by averaging values from all five sensors and that from the sensor at the center position, showed quite different trends in the TC-Sw domain. In parallel, we conducted a pore-scale numerical modeling, which consists of the steady-state two-phase Lattice-Boltzmann simulator and FEM thermal conduction simulator on digital pore geometry of sand aggregation. The simulation results showed a monotonous decreasing trend, and are reasonably well matched with experimental data when using average water saturations. We concluded that thermal conductivity would decrease smoothly as water saturation decreases if we can exclude boundary effects. However, in dynamic conditions, i.e. imbibition or drainage, the thermal conductivity might show hysteresis, which can be investigated with pore-scale numerical modeling with unsteady-state two-phase flow simulators in our future work.

  14. INVESTIGATION OF GEOTECHNICAL SPECIFICATIONS OF SAND DUNE SOIL: A CASE STUDY AROUND BAIJI IN IRAQ

    Directory of Open Access Journals (Sweden)

    Abbas J. Al-Taie

    2013-11-01

    Full Text Available ABSTRACT: While more than half the land surface of Iraq consists of deserts covered mainly with sand dunes, little research has taken place to study the characteristics and the behavior of dune soils. This paper directed toward studying the geotechnical properties of dune sands taken from Baiji city (northwest of Iraq. A vast laboratory testing program was carried out to achieve the purpose of this paper. The physical tests, chemical tests, X-ray diffraction analysis, permeability test, compaction characteristics, compressibility and collapsibility tests; and shear strength tests were included in this program. The results indicate that soil of Baiji sand dune exhibits prefer engineering properties according to their state. As such, this soil is considered suitable for use in geotechnical constructions. ABSTRAK: Walaupun lebih separuh daripada bumi Iraq terdiri daripada gurun yang dipenuhi dengan bukit-bukit pasir, tidak banyak penyelidikan dijalankan untuk mengkaji sifat-sifat dan ciri-ciri tanah pasir  tersebut. Kertas kerja ini menyelidik sifat geoteknikal bukit pasir yang diambil dari pekan Baiji (di bahagian barat utara Iraq.  Program penyelidikan makmal yang menyeluruh telah  dijalankan bagi mencapai objektif kajian ini. Ujian fizikal, ujian kimia, analisis belauan sinar-x, ujian kebolehtelapan, ciri pemadatan, faktor ketermampatan, ujian keruntuhan dan ujian kekuatan ricih diambilkira dalam program ini. Keputusan menunjukkan bahawa tanih bukit pasir Baiji mengutamakan ciri kejuruteraan berdasarkan keadaannya. Oleh itu, tanah ini dianggap sesuai untuk kegunaan pembinaan geoteknikal.

  15. Rheology of oil sands slurries

    Energy Technology Data Exchange (ETDEWEB)

    Chow, R.; Zhou, J. [Alberta Research Council, Edmonton, AB (Canada). Mineral Oil Sands Unit; Wallace, D. [Dean Wallace Consulting Inc., Beaumont, AB (Canada)

    2006-07-01

    This study focused on integrating rheology and colloid science to improve recovery of bitumen in surface mined oil sands. Factors that influence recovery, such as conditions of particle interaction, solids concentration and shear rate, were reviewed. In an effort to understand the rheological behaviour of clay-in-water suspensions, an elaborate procedure was developed to separate an inter-bedded clay layer from a site at Albian Sands Energy Inc. The variables were water chemistry, solids concentration, and shear rate. The research study was conducted at the Alberta Research Council with the support of the CONRAD Extraction Group. A controlled stress rheometer was used to provide the quantitative evaluations of the clay slurry properties. The research results indicate that the viscoelastic properties of the slurry are highly influenced by the shear history of the slurry, solids content, calcium concentration, and sample aging. Shear thinning behaviour was observed in all slurry samples, but the slurry viscosity increased with test time for a given shear rate. In order to classify the slurries, a method was developed to distinguish the gel strength. The slurries were then classified into 3 distinct patterns, including no gel, weak gel and strong gel. The evolution of the experimental protocols were described along with the current stability maps that correlate the domains of the gel strength according to the solids concentration, calcium ion content, and shear rate. It was concluded that the rheological properties of oil sands slurries influence bitumen recovery in commercial surface-mined oil sands operations. tabs., figs.

  16. Geophysics comes of age in oil sands development

    Energy Technology Data Exchange (ETDEWEB)

    Bauman, P. [WorleyParsons Komex, Calgary, AB (Canada); Birch, R.; Parker, D.; Andrews, B. [Calgary Univ., AB (Canada). Dept. of Geology and Geophysics

    2008-07-01

    This paper discussed geophysical techniques developed for oil sands exploration and production applications in Alberta's oil sands region. Geophysical methods are playing an important role in mine planning, tailings containment, water supply, and land reclamation activities. Geophysics techniques are used to estimate the volume of muskeg that needs to be stripped and stored for future reclamation activities as well as to site muskeg piles and delineate the thickness of clay Clearwater formations overlying Cretaceous oil-bearing sands. 2-D electrical resistivity mapping is used to map river-connected deep bedrock Pleistocene paleovalleys in the region. Geophysical studies are also used to investigate the interiors of dikes and berms as well as to monitor salt migration within tailings piles. Sonic and density logs are used to create synthetic seismograms for mapping the Devonian surface in the region. The new applications included the calculation of bitumen saturation from surface sands and shales; muskeg thickness mapping; and non-intrusive monitoring of leachate plumes. Geophysical techniques included 2-D electrical resistivity imaging; transient electromagnetic (EM) technologies; ground penetrating radar; and high-resolution seismic reflections. Polarization, surface nuclear magnetic resonance and push-probe sensing techniques were also discussed. Techniques were discussed in relation to Alberta's Athabasca oil sands deposits. 4 refs.

  17. The Effect of the Kind of Sands and Additions on the Mechanical Behaviour of S.C.C

    Science.gov (United States)

    Zeghichi, L.; Benghazi, Z.; Baali, L.

    The sand is an inert element essential in the composition of concrete; its use ensures granular continuity between the cement and gravel for better cohesion of concrete. This paper presents the results of a study that investigated the influence of sand quality on the properties of fresh and hardened self-compacting concrete (SCC). The dune sands are very fine materials characterized by a high intergranular porosity, high surface area and low fineness modulus; on the other hand crushed (manufactured) sand has a high rate into thin and irregular shapes which are influencing the workability of concrete. The amount of dune sand varies from (0% 50%, to 100%) by weight of fine aggregates. The effect of additions is also treated (blast furnace slag and lime stone) The results show that the rheological properties favour the use of dune sands; however the mechanical properties support the use of crushed sand.

  18. Highly permeable polymeric membranes based on the incorporation of the functional water channel protein Aquaporin Z

    Science.gov (United States)

    Kumar, Manish; Grzelakowski, Mariusz; Zilles, Julie; Clark, Mark; Meier, Wolfgang

    2007-01-01

    The permeability and solute transport characteristics of amphiphilic triblock-polymer vesicles containing the bacterial water-channel protein Aquaporin Z (AqpZ) were investigated. The vesicles were made of a block copolymer with symmetric poly-(2-methyloxazoline)-poly-(dimethylsiloxane)-poly-(2-methyloxazoline) (PMOXA15-PDMS110-PMOXA15) repeat units. Light-scattering measurements on pure polymer vesicles subject to an outwardly directed salt gradient in a stopped-flow apparatus indicated that the polymer vesicles were highly impermeable. However, a large enhancement in water productivity (permeability per unit driving force) of up to ≈800 times that of pure polymer was observed when AqpZ was incorporated. The activation energy (Ea) of water transport for the protein-polymer vesicles (3.4 kcal/mol) corresponded to that reported for water-channel-mediated water transport in lipid membranes. The solute reflection coefficients of glucose, glycerol, salt, and urea were also calculated, and indicated that these solutes are completely rejected. The productivity of AqpZ-incorporated polymer membranes was at least an order of magnitude larger than values for existing salt-rejecting polymeric membranes. The approach followed here may lead to more productive and sustainable water treatment membranes, whereas the variable levels of permeability obtained with different concentrations of AqpZ may provide a key property for drug delivery applications. PMID:18077364

  19. Suitability of a South African silica sand for three-dimensional printing of foundry moulds and cores

    Directory of Open Access Journals (Sweden)

    Nyembwe, Kasongo

    2016-11-01

    Full Text Available Applications of three-dimensional printing (3DP to metal casting include, among other things, the direct manufacturing of foundry moulds and cores in refractory materials such as silica sand. The main properties of silica sand that are essentially related to the traditional moulding and core-making processes are: size distribution, clay content, pH, acid demand, and refractoriness. The silica sand used for 3DP must also be appropriately selected for the layer-based manufacturing process involved in 3DP. Properties such as grain size distribution, grain surface morphology, angularity, flowability, and recoating abilities have a particular importance when determining sand suitability. Because of these extra requirements, only a limited range of available foundry silica sands can be used for 3DP processes. The latter situation explains the scarcity and high cost of suitable silica sands, thus contributing to the relatively high operational costs of the 3DP processes for the production of sand moulds and cores. This research paper investigates the suitability of a locally-available silica sand for use in a Voxeljet VX1000 3DP machine. The local silica sand was assessed and compared with an imported silica sand recommended by the manufacturer of 3DP equipment in terms of foundry characteristics and recoating behaviour. The study shows that, despite the differences between the characteristics of the two silica sands, the local sand could be considered a suitable alternative to imported sand for rapid sand casting applications.

  20. Red and blue colouration of thermoluminescence from natural quartz sands

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T; Hayashi, Y; Koyanagi, A; Yokosaka, K; Kimura, K

    1986-01-01

    Quartz extracts, from a pegmatite rock, volcanic ashes and beach sands, were exposed to X-rays or gamma-rays upto 8.8kGy. The irradiated sands were observed through a thermoluminescence colour image technique (abbreviated to TLCI by the authors) using highly sensitive colour photographic system. The quartz sands from volcanic ash layers, containing ..beta..-quartz (mineralized at high temperature), always indicate a red TLCI, whereas the quartz rocks from pegmatite origin and granite strata, containing ..cap alpha..-quartz (mineralized at low temperature), gave a typical blue TLCI, being consistent with the well known quartz TL colour. Quartz fractions from the beach sands showed a mixture of both red and blue TLCI, probably reflecting the respective mixtures of ..beta..-(in their origin) and ..cap alpha..-quartz fractions along the riverside area. The search using X-ray diffractometry and instrumental neutron activation analysis proved that the cause of distinctly different colourations was attributable to the impurity atoms: light rare earth elements (Eu and/or Sm) bringing on red TLCI, while structural defects yielding the blue TLCI).

  1. Effect of desensitizing agents on dentin permeability.

    Science.gov (United States)

    Ishihata, Hiroshi; Kanehira, Masafumi; Nagai, Tomoko; Finger, Werner J; Shimauchi, Hidetoshi; Komatsu, Masashi

    2009-06-01

    To investigate the in vitro efficacy of two dentin desensitizing products at reducing liquid permeability through human dentin discs. The tested hypothesis was that the products, in spite of different chemical mechanisms were not different at reducing or eliminating flow through dentin discs. Dentin slices (1 mm thick) were prepared from 16 extracted human third molars and their permeability was indirectly recorded in a split chamber model, using a chemiluminescence technique, after EDTA treatment (control), after soaking with albumin, and after desensitizer application. Two products were studied: MS Coat, a self-curing resin-containing oxalate product, and Gluma Desensitizer, a glutaraldehyde/HEMA-based agent without initiator. The dentin slices were mounted between an upper chamber, filled with an aqueous solution of 1% potassium ferricyanide and 0.3% hydrogen peroxide, and a lower chamber filled with 1% sodium hydroxide solution and 0.02% luminol. The upper solution was pressurized, and upon contact with the luminol solution a photochemical signal was generated and recorded as a measure of permeability throughout two consecutive pressurizing cycles at 2.5 and 13 kPa (26 and 133 cm H2O), respectively. The permeability of the control and albumin-soaked samples was similarly high. After application of the desensitizing agents, dentin permeability was reduced to virtually zero at both pressure levels (P < 0.001).

  2. Moessbauer analysis of high-energy mechanical-milled sand fraction of a magnetic soil developing on basalt

    Energy Technology Data Exchange (ETDEWEB)

    Borges, Jose Flavio Marcelino; Hneda, Marlon Luiz; Brinatti, Andre Mauricio [State University of Ponta Grossa, Department of Physics (Brazil); Cunha, Joao Batista Marimon da [Federal University of Rio Grande do Sul, Institute of Physics (Brazil); Rosa, Jadir Aparecido [Polo Regional de Ponta Grossa, Agronomy Institute of Parana (Brazil); Fabris, Jose Domingos, E-mail: jdfabris@ufmg.br [Federal University of Jequitinhonha and Mucuri Valleys (UFVJM) (Brazil)

    2011-11-15

    A sample of the coarse sand fraction from the soil material of the A-horizon (0-0.2 m from the soil surface) of a dusky red magnetic Oxisol was submitted to high-energy mechanical milling for different times. This assay aimed mainly at (a) monitoring the individualization of strongly aggregated mineral particles, and (b) measuring the effect of the milling pressure on the mineralogy changes of the material. These data are also intended to experimentally subside any physical model describing the mechanical behavior of the superficial soil layer that is subjected to intensive machine management, in agriculture fields. Powder X-ray data reveal that some mineralogical phases, notably gibbsite, disappear soon after the first few hours milling. The 298 K-transmission Moessbauer spectrum for the non-milled sand sample shows a qualitatively typical pattern for the sand fraction of basalt derived soils, with magnetically ordered sextets, assignable mainly to hematite and maghemite, and an intense central (super)paramagnetic Fe{sup 3 + } doublet. For the milled samples, spectra revealed progressive spectral reduction of the magnetic hyperfine structure, with concomitant increase of relative subspectral areas due to (super)paramagnetic phases, as the milling time increased. This result is consistent with the reduction of measured saturation magnetization, from 4.96(8) J T{sup - 1} kg{sup - 1}, for the non-milled sample, to 3.26(7) J T{sup - 1} kg{sup - 1}, for the sample milled for 8 hours.

  3. Laboratory determination of migration of Eu(III) in compacted bentonite–sand mixtures as buffer/backfill material for high-level waste disposal

    International Nuclear Information System (INIS)

    Zhou, Lang; Zhang, Huyuan; Yan, Ming; Chen, Hang; Zhang, Ming

    2013-01-01

    For the safety assessment of geological disposal of high-level radioactive waste (HLW), the migration of Eu(III) through compacted bentonite–sand mixtures was measured under expected repository conditions. Under the evaluated conditions, advection and dispersion is the dominant migration mechanism. The role of sorption on the retardation of migration was also evaluated. The hydraulic conductivities of compacted bentonite–sand mixtures were K=2.07×10 −10 –5.23×10 −10 cm/s, The sorption and diffusion of Eu(III) were examined using a flexible wall permeameter for a solute concentration of 2.0×10 −5 mol/l. The effective diffusion coefficients and apparent diffusion coefficients of Eu(III) in compacted bentonite–sand mixtures were in the range of 1.62×10 –12 –4.87×10 –12 m 2 /s, 1.44×10 –14 –9.41×10 –14 m 2 /s, respectively, which has a very important significance to forecast the relationship between migration length of Eu(III) in buffer/backfill material and time and provide a reference for the design of buffer/backfill material for HLW disposal in China. - Highlights: • The migration progress of Eu(III) in compacted bentonite–sand mixtures was researched. • The hydraulic conductivity of cominpacted bentonite–sand mixtures was measured. • The migration length of Eu(III) in buffer/backfill material after a certain period of time was forecasted

  4. Comparative field permeability measurement of permeable pavements using ASTM C1701 and NCAT permeameter methods.

    Science.gov (United States)

    Li, Hui; Kayhanian, Masoud; Harvey, John T

    2013-03-30

    Fully permeable pavement is gradually gaining support as an alternative best management practice (BMP) for stormwater runoff management. As the use of these pavements increases, a definitive test method is needed to measure hydraulic performance and to evaluate clogging, both for performance studies and for assessment of permeability for construction quality assurance and maintenance needs assessment. Two of the most commonly used permeability measurement tests for porous asphalt and pervious concrete are the National Center for Asphalt Technology (NCAT) permeameter and ASTM C1701, respectively. This study was undertaken to compare measured values for both methods in the field on a variety of permeable pavements used in current practice. The field measurements were performed using six experimental section designs with different permeable pavement surface types including pervious concrete, porous asphalt and permeable interlocking concrete pavers. Multiple measurements were performed at five locations on each pavement test section. The results showed that: (i) silicone gel is a superior sealing material to prevent water leakage compared with conventional plumbing putty; (ii) both methods (NCAT and ASTM) can effectively be used to measure the permeability of all pavement types and the surface material type will not impact the measurement precision; (iii) the permeability values measured with the ASTM method were 50-90% (75% on average) lower than those measured with the NCAT method; (iv) the larger permeameter cylinder diameter used in the ASTM method improved the reliability and reduced the variability of the measured permeability. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. Compression characteristics and permeability of saturated Gaomiaozi ca-bentonite

    International Nuclear Information System (INIS)

    Sun Wenjing; Sun De'an; Fang Lei

    2012-01-01

    The compression characteristics and permeability of compacted Gaomiaozi Ca-bentonite saturated by the water uptake tests are studied by conducting a series of one-dimension compression tests. The permeability coefficient can be calculated by the Terzaghi's one-dimensional consolidation theory after the consolidation coefficient is obtained by the square root of time method. It is found that the compression curves of compacted specimens saturated by the water uptake tests tend to be consistent in the relatively high stress range. The compression indexes show a linear decrease with increasing dry density and the swelling index is a constant. The permeability coefficient decreases with increasing compression stress, and they show the linear relationship in double logarithmic coordinates. Meanwhile, the permeability coefficient shows a linear decrease with decreasing void ratio, which has no relationship with initial states, stress states and stress paths. The permeability coefficient k of GMZ Ca-bentonite at dry density Pd of 1.75 g/cm 3 can be calculated as 2.0 × 10 -11 cm/s by the linear relationship between Pd and log k. It is closed to the permeability coefficient of GMZ Ca-bentonite with the same dry density published in literature, which testifies that the method calculating the permeability coefficient is feasible from the consolidation coefficient obtained by the consolidation test. (authors)

  6. Contribution of sand-associated enterococci to dry weather water quality.

    Science.gov (United States)

    Halliday, Elizabeth; Ralston, David K; Gast, Rebecca J

    2015-01-06

    Culturable enterococci and a suite of environmental variables were collected during a predominantly dry summer at a beach impacted by nonpoint source pollution. These data were used to evaluate sands as a source of enterococci to nearshore waters, and to assess the relationship between environmental factors and dry-weather enterococci abundance. Best-fit multiple linear regressions used environmental variables to explain more than half of the observed variation in enterococci in water and dry sands. Notably, during dry weather the abundance of enterococci in dry sands at the mean high-tide line was significantly positively related to sand moisture content (ranging from sands. Tidal forcing modulated the abundance of enterococci in the water, as both turbidity and enterococci were elevated during ebb and flood tides. The probability of samples violating the single-sample maximum was significantly greater when collected during periods with increased tidal range: spring ebb and flood tides. Tidal forcing also affected groundwater mixing zones, mobilizing enterococci from sand to water. These data show that routine monitoring programs using discrete enterococci measurements may be biased by tides and other environmental factors, providing a flawed basis for beach closure decisions.

  7. Aeolian sand transport and aeolian deposits on Venus: A review

    Science.gov (United States)

    Kreslavsly, Mikhail A.; Bondarenko, Nataliya V.

    2017-06-01

    We review the current state of knowledge about aeolian sand transport and aeolian bedforms on planet Venus. This knowledge is limited by lack of observational data. Among the four planetary bodies of the Solar System with sufficient atmospheres in contact with solid surfaces, Venus has the densest atmosphere; the conditions there are transitional between those for terrestrial subaerial and subaqueous transport. The dense atmosphere causes low saltation threshold and short characteristic saltation length, and short scale length of the incipient dunes. A few lines of evidence indicate that the typical wind speeds exceed the saltation threshold; therefore, sand transport would be pervasive, if sand capable of saltation is available. Sand production on Venus is probably much slower than on the Earth; the major terrestrial sand sinks are also absent, however, lithification of sand through sintering is expected to be effective under Venus' conditions. Active transport is not detectable with the data available. Aeolian bedforms (transverse dunes) resolved in the currently available radar images occupy a tiny area on the planet; however, indirect observations suggest that small-scale unresolved aeolian bedforms are ubiquitous. Aeolian transport is probably limited by sand lithification causing shortage of saltation-capable material. Large impact events likely cause regional short-term spikes in aeolian transport by supplying a large amount of sand-size particles, as well as disintegration and activation of older indurated sand deposits. The data available are insufficient to understand whether the global aeolian sand transport occurs or not. More robust knowledge about aeolian transport on Venus is essential for future scientific exploration of the planet, in particular, for implementation and interpretation of geochemical studies of surface materials. High-resolution orbital radar imaging with local to regional coverage and desirable interferometric capabilities is the

  8. Performance of composite sand cement brick containing recycle concrete aggregate and waste polyethylene terephthalate with different mix design ratio

    Science.gov (United States)

    Azmi, N. B.; Khalid, F. S.; Irwan, J. M.; Mazenan, P. N.; Zahir, Z.; Shahidan, S.

    2018-04-01

    This study is focuses to the performance of composite sand cement brick containing recycle concrete aggregate and waste polyethylene terephthalate. The objective is to determine the mechanical properties such as compressive strength and water absorption of composite brick containing recycled concrete aggregate and polyethylene terephthalate waste and to determine the optimum mix ratio of bricks containing recycled concrete aggregate and polyethylene terephthalate waste. The bricks specimens were prepared by using 100% natural sand, they were then replaced by RCA at 25%, 50% and 75% with proportions of PET consists of 1.0%, 1.5%, 2.0% and 2.5% by weight of natural sand. Based on the results of compressive strength, it indicates that the replacement of RCA shows an increasing strength as the strength starts to increase from 25% to 50% for both mix design ratio. The strength for RCA 75% volume of replacement started to decrease as the volume of PET increase. However, the result of water absorption with 50% RCA and 1.0% PET show less permeable compared to control brick at both mix design ratio. Thus, one would expect the density of brick decrease and the water absorption to increase as the RCA and PET content is increased.

  9. Relative Permeability of Fractured Rock

    Energy Technology Data Exchange (ETDEWEB)

    Mark D. Habana

    2002-06-30

    Contemporary understanding of multiphase flow through fractures is limited. Different studies using synthetic fractures and various fluids have yielded different relative permeability-saturation relations. This study aimed to extend the understanding of multiphase flow by conducting nitrogen-water relative permeability experiments on a naturally-fractured rock from The Geysers geothermal field. The steady-state approach was used. However, steady state was achieved only at the endpoint saturations. Several difficulties were encountered that are attributed to phase interference and changes in fracture aperture and surface roughness, along with fracture propagation/initiation. Absolute permeabilities were determined using nitrogen and water. The permeability values obtained change with the number of load cycles. Determining the absolute permeability of a core is especially important in a fractured rock. The rock may change as asperities are destroyed and fractures propagate or st rain harden as the net stresses vary. Pressure spikes occurred in water a solute permeability experiments. Conceptual models of an elastic fracture network can explain the pressure spike behavior. At the endpoint saturations the water relative permeabilities obtained are much less than the nitrogen gas relative permeabilities. Saturations were determined by weighing and by resistivity calculations. The resistivity-saturation relationship developed for the core gave saturation values that differ by 5% from the value determined by weighing. Further work is required to complete the relative permeability curve. The steady-state experimental approach encountered difficulties due to phase interference and fracture change. Steady state may not be reached until an impractical length of time. Thus, unsteady-state methods should be pursued. In unsteady-state experiments the challenge will be in quantifying rock fracture change in addition to fluid flow changes.

  10. Improvement of air permeability of Bubbfil nanofiber membrane

    Directory of Open Access Journals (Sweden)

    Wang Fei-Yan

    2018-01-01

    Full Text Available Nanofiber membranes always have extremely high filter efficiency and remarkably low pressure drop. In order to further improve air permeability of bubbfil nanofiber membranes, the plasma technology is used for surface treatment in this paper. The results show that plasma treatment can improve air permeability by 4.45%. Under higher power plasma treatment, earthworm like etchings are produced on the membrane surface with fractal dimensions of about 1.138.

  11. PIXE analysis of sand and soil from Ulaanbaatar and Karakurum, Mongolia

    Science.gov (United States)

    Markwitz, A.; Barry, B.; Shagjjamba, D.

    2008-09-01

    Twenty-one sand and soil samples were collected at the surface from 22 to 25 June 2007 at sampling sites from Ulaanbaatar to Karakurum, Mongolia. The sand samples were collected from constantly changing sand dunes which may still contain salt from prehistoric oceans. The dry sand and soil samples were processed for PIXE and PIGE analyses. A clear division between soils and sand become apparent in the silicon results. Concentrations of all bulk elements in human habitation samples and of Si, Al, K and Fe in dry lake/flood plain samples are similar to those in the soils and sands. Among elements which could be regarded as being at trace concentrations the average S concentration in the soils is 0.9 g kg-1 whereas it is not detected in the sand samples. Zinc and Cu concentrations are both higher in the soils than the sands and are strongly correlated. A surprising presence of uranium at a concentration of 350 mg kg-1 was detected in the PIXE measurement on one of the dry lake samples. Gamma spectrometry confirmed the presence of U in this sample and also at a lower level in a sample from the lake shore, but in none of the other samples. Further, the gamma spectrometry showed that 238U decay products were present only at a level corresponding to about 3 mg kg-1 U for a system in radioactive equilibrium, a figure which is typical for U in the earth's crust. Disequilibria between 238U and its decay products occur naturally but such a high degree of separation at high concentration would be unique if confirmed. PIXE and PIGE measurements of these samples highlight the difficulty in correlating trace element measurements with occurrence of indicators of sea salt in air particulate samples.

  12. Transport processes in intertidal sand flats

    Science.gov (United States)

    Wu, Christy

    2010-05-01

    Methane rich sulfate depleted seeps are observed along the low water line of the intertidal sand flat Janssand in the Wadden Sea. It is unclear where in the flat the methane is formed, and how it is transported to the edge of the sand flat where the sulfidic water seeps out. Methane and sulfate distributions in pore water were determined along transects from low water line toward the central area of the sand flat. The resulting profiles showed a zone of methane-rich and sulfate-depleted pore water below 2 m sediment depth. Methane production and sulfate reduction are monitored over time for surface sediments collected from the upper flat and seeping area. Both activities were at 22 C twice as high as at 15 C. The rates in sediments from the central area were higher than in sediments from the methane seeps. Methanogenesis occurred in the presence of sulfate, and was not significantly accelerated when sulfate was depleted. The observations show a rapid anaerobic degradation of organic matter in the Janssand. The methane rich pore water is obviously transported with a unidirectional flow from the central area of the intertidal sand flat toward the low water line. This pore water flow is driven by the pressure head caused by elevation of the pore water relative to the sea surface at low tide (Billerbeck et al. 2006a). The high methane concentration at the low water line accumulates due to a continuous outflow of pore water at the seepage site that prevents penetration of electron acceptors such as oxygen and sulfate to reoxidize the reduced products of anaerobic degradation (de Beer et al. 2006). It is, however, not clear why no methane accumulates or sulfate is depleted in the upper 2 m of the flats.

  13. Maladaptively high and low openness: the case for experiential permeability.

    Science.gov (United States)

    Piedmont, Ralph L; Sherman, Martin F; Sherman, Nancy C

    2012-12-01

    The domain of Openness within the Five-Factor Model (FFM) has received inconsistent support as a source for maladaptive personality functioning, at least when the latter is confined to the disorders of personality included within the American Psychiatric Association's (APA) Diagnostic and Statistical Manual of Mental Disorders (DSM-IV-TR; APA, ). However, an advantage of the FFM relative to the DSM-IV-TR is that the former was developed to provide a reasonably comprehensive description of general personality structure. Rather than suggest that the FFM is inadequate because the DSM-IV-TR lacks much representation of Openness, it might be just as reasonable to suggest that the DSM-IV-TR is inadequate because it lacks an adequate representation of maladaptive variants of both high and low Openness. This article discusses the development and validation of a measure of these maladaptive variants, the Experiential Permeability Inventory. © 2012 The Authors. Journal of Personality © 2012, Wiley Periodicals, Inc.

  14. Measurement of radon permeability through polyethylene membrane using scintillation detector

    Energy Technology Data Exchange (ETDEWEB)

    Ashry, A.H.; Abou-Leila, M. [Department of Physics, Faculty of Education, Ain Shams University, Cairo (Egypt); Abdalla, A.M., E-mail: aymanabdalla62@hotmail.co [Department of Physics, Faculty of Education, Ain Shams University, Cairo (Egypt); Department of Physics, Faculty of Sciences and Arts, Najran University, Najran, P.O. Box. 11001 (Saudi Arabia); Advanced Materials and Nano-Engineering Laboratory (AMNEL), Centre for Advanced Materials and Nano-Engineering (CAMNE), Najran University, Najran, P.O. Box. 11001 (Saudi Arabia)

    2011-01-15

    The permeability of Radon 222 through polyethylene membranes has been studied using activated charcoal technique. The permeability constant of Radon 222 through low-density polyethylene, linear low-density Polyethylene and high density polyethylene samples has been measured. There is a considerable agreement between the values obtained by our method and the method suggested by W. Arafa [2002. Permeability of radon 222 through some materials. Radiat. Meas. 35, 207-211], and SSNTD technique suggested by A. Hafez and G. Somogyi [1986. Determination of radon and thoron permeability through some plastics by track technique. Int. J. Radiat. Appl. Instrum. Nucl. Track Radiat. Meas. 12 (1-6), 697-700]. In this work Radon permeability through different polyethylene membranes has been measured using three different methods, i.e. solid state nuclear track technique, W. Arafa [2002. Permeability of radon 222 through some materials. Radiat. Meas. 35, 207-211]method and our proposed method. In addition to this, in this study, the diffusion coefficient of radon in charcoal as well as solubility of Radon in polyethylene membrane has been taken into consideration.

  15. Measurement of radon permeability through polyethylene membrane using scintillation detector

    International Nuclear Information System (INIS)

    Ashry, A.H.; Abou-Leila, M.; Abdalla, A.M.

    2011-01-01

    The permeability of Radon 222 through polyethylene membranes has been studied using activated charcoal technique. The permeability constant of Radon 222 through low-density polyethylene, linear low-density Polyethylene and high density polyethylene samples has been measured. There is a considerable agreement between the values obtained by our method and the method suggested by W. Arafa [2002. Permeability of radon 222 through some materials. Radiat. Meas. 35, 207-211], and SSNTD technique suggested by A. Hafez and G. Somogyi [1986. Determination of radon and thoron permeability through some plastics by track technique. Int. J. Radiat. Appl. Instrum. Nucl. Track Radiat. Meas. 12 (1-6), 697-700]. In this work Radon permeability through different polyethylene membranes has been measured using three different methods, i.e. solid state nuclear track technique, W. Arafa [2002. Permeability of radon 222 through some materials. Radiat. Meas. 35, 207-211] method and our proposed method. In addition to this, in this study, the diffusion coefficient of radon in charcoal as well as solubility of Radon in polyethylene membrane has been taken into consideration.

  16. Selective and membrane-permeable small molecule inhibitors of nicotinamide N-methyltransferase reverse high fat diet-induced obesity in mice.

    Science.gov (United States)

    Neelakantan, Harshini; Vance, Virginia; Wetzel, Michael D; Wang, Hua-Yu Leo; McHardy, Stanton F; Finnerty, Celeste C; Hommel, Jonathan D; Watowich, Stanley J

    2018-01-01

    There is a critical need for new mechanism-of-action drugs that reduce the burden of obesity and associated chronic metabolic comorbidities. A potentially novel target to treat obesity and type 2 diabetes is nicotinamide-N-methyltransferase (NNMT), a cytosolic enzyme with newly identified roles in cellular metabolism and energy homeostasis. To validate NNMT as an anti-obesity drug target, we investigated the permeability, selectivity, mechanistic, and physiological properties of a series of small molecule NNMT inhibitors. Membrane permeability of NNMT inhibitors was characterized using parallel artificial membrane permeability and Caco-2 cell assays. Selectivity was tested against structurally-related methyltransferases and nicotinamide adenine dinucleotide (NAD + ) salvage pathway enzymes. Effects of NNMT inhibitors on lipogenesis and intracellular levels of metabolites, including NNMT reaction product 1-methylnicotianamide (1-MNA) were evaluated in cultured adipocytes. Effects of a potent NNMT inhibitor on obesity measures and plasma lipid were assessed in diet-induced obese mice fed a high-fat diet. Methylquinolinium scaffolds with primary amine substitutions displayed high permeability from passive and active transport across membranes. Importantly, methylquinolinium analogues displayed high selectivity, not inhibiting related SAM-dependent methyltransferases or enzymes in the NAD + salvage pathway. NNMT inhibitors reduced intracellular 1-MNA, increased intracellular NAD + and S-(5'-adenosyl)-l-methionine (SAM), and suppressed lipogenesis in adipocytes. Treatment of diet-induced obese mice systemically with a potent NNMT inhibitor significantly reduced body weight and white adipose mass, decreased adipocyte size, and lowered plasma total cholesterol levels. Notably, administration of NNMT inhibitors did not impact total food intake nor produce any observable adverse effects. These results support development of small molecule NNMT inhibitors as therapeutics to

  17. Electrokinetic effects and fluid permeability

    International Nuclear Information System (INIS)

    Berryman, J.G.

    2003-01-01

    Fluid permeability of porous media depends mainly on connectivity of the pore space and two physical parameters: porosity and a pertinent length-scale parameter. Electrical imaging methods typically establish connectivity and directly measure electrical conductivity, which can then often be related to porosity by Archie's law. When electrical phase measurements are made in addition to the amplitude measurements, information about the pertinent length scale can then be obtained. Since fluid permeability controls the ability to flush unwanted fluid contaminants from the subsurface, inexpensive maps of permeability could improve planning strategies for remediation efforts. Detailed knowledge of fluid permeability is also important for oil field exploitation, where knowledge of permeability distribution in three dimensions is a common requirement for petroleum reservoir simulation and analysis, as well as for estimates on the economics of recovery

  18. Economic Valuation of Sand and Gravel in Davao del Norte, Philippines

    OpenAIRE

    Tamayo, Adrian; Tagalo, Romulo

    2016-01-01

    The study aims to quantify the economic value of the sand and gravel which is deemed as a non-renewable resource. A survey was conducted to extract the consumer surplus of the households, also construct the demand equation for the resource. With the demand equation for sand and gravel at , the consumer surplus was estimated at P8271. Using the economic valuation technique, the economic value of sand and gravel was estimated at P729,568,368. Thus, a very high value imputed on the environmenta...

  19. Transport and Deposition of Suspended Soil-Colloids in Saturated Sand Columns

    DEFF Research Database (Denmark)

    Sharma, Anu; Kawamoto, Ken; Møldrup, Per

    2011-01-01

    Understanding colloid mobilization, transport and deposition in the subsurface is a prerequisite for predicting colloid‐facilitated transport of strongly adsorbing contaminants and further developing remedial activities. This study investigated the transport behavior of soil‐colloids extracted from...... caused tailing of colloid BTCs with higher reversible entrapment and release of colloids than high flow velocity. The finer Toyoura sand retained more colloids than the coarser Narita sand at low pH conditions. The deposition profile and particle size distribution of colloids in the Toyoura sand clearly...

  20. Effectiveness of Protective Action of Coatings from Moisture Sorption into Surface Layer of Sand Moulds

    Directory of Open Access Journals (Sweden)

    Kaźnica N.

    2016-12-01

    Full Text Available The results of investigations of the sorption process of surface layers of sand moulds covered by zirconium and zirconium - graphite alcohol coatings are presented in the paper. Investigations comprised two kinds of sand grains (silica sand and reclaimed sand of moulding sand with furan resin. Tests were performed under conditions of a high relative air humidity 75 - 85% and a constant temperature within the range 28 – 33°C. To evaluate the effectiveness of coatings protective action from moisture penetration into surface layers of sand moulds gravimetric method of quantitavie moisture sorption and ultrasonic method were applied in measurements.

  1. Galveston Island, Texas, Sand Management Strategies

    Science.gov (United States)

    2016-07-01

    billion m3 of beach quality sand . However, Texas projects to date have not utilized these sources because of transportation costs. The lack of nearby...estimate that the San Luis Pass flood shoal contains approximately 11.8 million yd3 of beach quality sand . However, it is expected that if permits...a source of beach- quality sand . 2. Sand could be intercepted before it reaches the present dry beach. ERDC/CHL TR-16-13 55 3. The volume of

  2. Sustainable water management in Alberta's oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Byers, Bill; Usher, Robyn; Roach, Andrea [CH2M HILL, Englewood, CO (United States); Lambert, Gord; Kotecha, Prit [Suncor Energy Inc., Calgary (Canada)

    2012-07-01

    The Canadian Association of Petroleum Producers forecast published in 2011 predicts that oil production from oil sands will increase by 50% in the next 3 years and double by 2020. This rate of growth will result in significant pressure on water resources; water use per barrel of oil sands production is comparable to other energy resources - about 2.5 barrels of fresh water per barrel of oil produced are used by mining operations and 0.5 barrels by in-situ operations. Suncor Energy Inc. (Suncor) was the first company to develop the oil sands in northern Alberta and holds one of the largest oil sands positions in Canada. In 2010, Suncor announced plans to increase production to more than 1 million barrels of oil equivalent per day by 2020, which it plans to achieve through oil sands production growth of approximately 10% per year. Because water supply and potential impacts to water quality are critical to its future growth, in 2010-2011 Suncor conducted a risk assessment to identify water-related business risks related to its northern Alberta operations. The assessment identified more than 20 high level business risks in strategic water risk areas including water supply, water reuse, storm water management, groundwater, waste management and river water return. The risk assessment results prompted development of a strategic roadmap to guide water stewardship across Suncor's regional operations. The roadmap describes goals, objectives, and specific activities for each of six key water risk areas, and informs prioritization and selection of prospective water management activities. Suncor is not only exploring water within its own boundaries, but is also collaborating with other oil sands producers to explore ways of integrating its water systems through industry consortia; Suncor is a member of the Oil Sands Leadership Initiative and of the recently formed Canadian Oil Sands Innovation Alliance, among others. (author)

  3. Microbial Characterization of Qatari Barchan Sand Dunes.

    Directory of Open Access Journals (Sweden)

    Sara Abdul Majid

    Full Text Available This study represents the first characterization of sand microbiota in migrating barchan sand dunes. Bacterial communities were studied through direct counts and cultivation, as well as 16S rRNA gene and metagenomic sequence analysis to gain an understanding of microbial abundance, diversity, and potential metabolic capabilities. Direct on-grain cell counts gave an average of 5.3 ± 0.4 x 105 cells g-1 of sand. Cultured isolates (N = 64 selected for 16S rRNA gene sequencing belonged to the phyla Actinobacteria (58%, Firmicutes (27% and Proteobacteria (15%. Deep-sequencing of 16S rRNA gene amplicons from 18 dunes demonstrated a high relative abundance of Proteobacteria, particularly enteric bacteria, and a dune-specific-pattern of bacterial community composition that correlated with dune size. Shotgun metagenome sequences of two representative dunes were analyzed and found to have similar relative bacterial abundance, though the relative abundances of eukaryotic, viral and enterobacterial sequences were greater in sand from the dune closer to a camel-pen. Functional analysis revealed patterns similar to those observed in desert soils; however, the increased relative abundance of genes encoding sporulation and dormancy are consistent with the dune microbiome being well-adapted to the exceptionally hyper-arid Qatari desert.

  4. Development tendencies of moulding and core sands

    Directory of Open Access Journals (Sweden)

    Stanislaw M. Dobosz1

    2011-11-01

    Full Text Available Further development of the technology for making moulding and core sands will be strictly limited by tough requirements due to protection of the natural environment. These tendencies are becoming more and more tense, so that we will reach a point when even processes, that from technological point of view fulfill high requirements of the foundry industry, must be replaced by more ecologically-friendly solutions. Hence, technologies using synthetic resins as binding materials will be limited. This paper presents some predictable development tendencies of moulding and core sands. The increasing role of inorganic substances will be noticed, including silicate binders with significantly improved properties, such as improved knock-out property or higher reclamation strength. Other interesting solutions might also be moulding sands bonded by geo-polymers and phosphate binders or salts and also binders based on degradable biopolymers. These tendencies and the usefulness of these binders are put forward in this paper.

  5. Numerical simulation of aeolian sand ripples

    International Nuclear Information System (INIS)

    Kang Liqiang; Guo Liejin

    2004-01-01

    With a new horizontal saltation displacement vector, a model is implemented to simulate the initiation and evolution of aeolian sand ripples. In the model, saltation distance considers the effects of surface height and slope. A linear stability analysis is also carried out for formation of sand ripples. The results show that, the model can be able to successfully reproduce sand ripples which can increase in scale by merging of small ripples. The linear stability analysis indicates that sand ripples appear when the relaxation rate parameter is below a threshold value and wind strength parameter is larger than a critical value. The results also verified that the formation of sand ripples is a self-organization process

  6. Experimental investigation on heat transport in gravel-sand materials

    DEFF Research Database (Denmark)

    Maureschat, Gerald; Heller, Alfred

    1997-01-01

    in sand-gravel material, the storage media is to be water satured. In this case, handling of such material on site is rather complex. The conduction is highly dependent on the thermal properties of the storage media and so is the overall thermal performance of a storage applying such media. For sandy...... out in a small size experiment. The experiment consists of a highly insulated box filled with two kinds of sand material crossed by a plastic heat pipe. Heat transfer is measured under dry and water satured conditions in a cross-section.The conclusions are clear. To obtain necessary heat conduction...

  7. Japan's involvement in oil sands development

    International Nuclear Information System (INIS)

    Sugiura, T.

    1994-01-01

    According to Japanese national policy, exploration and development by Japanese companies in overseas countries are promoted in order to ensure stable oil supplies. Japan Canada Oil Sands Limited (JACOS), part of the JAPEX group, was established during the 1978 world oil crisis to explore and develop Canadian oil sand resources in accordance with Japan's national policy. The JAPEX group, including JACOS, has invested $123 million in oil sands projects in Alberta. JAPEX's first involvement in oil sands was in the Primrose Project operated by Norcen in the Cold Lake area. Five years of cyclic steam stimulation pilot tests did not produce sufficiently good results to justify further operation. The second involvement was the PCEJ Project, a joint effort by four companies that are participating in a bitumen recovery test project in the Athabasca Deposit. JACOS holds 2,452 km 2 of oil sands leases in Alberta. Tests conducted since 1978 in the PCEJ Project include multiwell steam injection pilot tests, some of which showed promise. JACOS is also participating in steam assisted gravity drainage projects and in federal/provincial research programs. Obstacles identified in developing Alberta oil sands are the lack of a bitumen pipeline to Edmonton and the insufficient length of oil sands leases (currently 10 years), given the difficulties of oil sand development. 10 figs

  8. MouldingSandDB – a modern database storing moulding sands properties research results

    Directory of Open Access Journals (Sweden)

    J. Jakubski

    2011-01-01

    Full Text Available The complexity of foundry processes requires the use of modern, advanced IT tools for optimization, storage and analysis of t echnicaldata. Properties of moulding and core sands that are collected in research laboratories, manufacturers, and finally in the foundries, are not in use later on. It seems important to create a database that will allow to use the results stored, along with the possibility of searching according to set criteria, adjusted to casting practice. This paper presents part of the database named „MouldingSandDB”, which allows to collect and search data for synthetic moulding sands.

  9. A combined CFD-experimental method for developing an erosion equation for both gas-sand and liquid-sand flows

    Science.gov (United States)

    Mansouri, Amir

    gas-sand, water-sand and viscous liquid-sand flows with high accuracy. Furthermore, in order to gain a better understanding of the erosion mechanism, a comprehensive experimental study was conducted to investigate the important factors influencing the erosion rate in gas-sand and slurry flows. The wear pattern and total erosion ratio were measured in a direct impingement jet geometry (for both dry impact and submerged impingement jets). The effects of fluid viscosity, abrasive particle size, particle impact speed, jet inclination angle, standoff distance, sand concentration, and exposure time were investigated. Also, the eroded samples were studied with Scanning Electron Microscopy (SEM) to understand the erosion micro-structure. Also, the sand particle impact speed and angle were measured using a Particle Image Velocimetry (PIV) system. The measurements were conducted in two types of erosion testers (gas-solid and liquid-solid impinging jets). The Particle Tracking Velocimetry (PTV) technique was utilized which is capable of tracking individual small particles. Moreover, CFD modeling was performed to predict the particle impact data. Very good agreement between the CFD results and PTV measurements was observed.

  10. Microstructure and anisotropic swelling behaviour of compacted bentonite/sand mixture

    Directory of Open Access Journals (Sweden)

    Simona Saba

    2014-04-01

    Full Text Available Pre-compacted elements (disks, torus of bentonite/sand mixture are candidate materials for sealing plugs of radioactive waste disposal. Choice of this material is mainly based on its swelling capacity allowing all gaps in the system to be sealed, and on its low permeability. When emplaced in the gallery, these elements will start to absorb water from the host rock and swell. Thereby, a swelling pressure will develop in the radial direction against the host rock and in the axial direction against the support structure. In this work, the swelling pressure of a small scale compacted disk of bentonite and sand was experimentally studied in both radial and axial directions. Different swelling kinetics were identified for different dry densities and along different directions. As a rule, the swelling pressure starts increasing quickly, reaches a peak value, decreases a little and finally stabilises. For some dry densities, higher peaks were observed in the radial direction than in the axial direction. The presence of peaks is related to the microstructure change and to the collapse of macro-pores. In parallel to the mechanical tests, microstructure investigation at the sample scale was conducted using microfocus X-ray computed tomography (μCT. Image observation showed a denser structure in the centre and a looser one in the border, which was also confirmed by image analysis. This structure heterogeneity in the radial direction and the occurrence of macro-pores close to the radial boundary of the sample can explain the large peaks observed in the radial swelling pressure evolution. Another interesting result is the higher anisotropy found at lower bentonite dry densities, which was also analysed by means of μCT observation of a sample at low bentonite dry density after the end of test. It was found that the macro-pores, especially those between sand grains, were not filled by swelled bentonite, which preserved the anisotropic microstructure caused by

  11. Geohydrology of the valley-fill aquifer in the Ramapo and Mahwah rivers area, Rockland County, New York

    Science.gov (United States)

    Moore, Richard Bridge; Cadwell, D.H.; Stelz, W.G.; Belli, J.L.

    1982-01-01

    This report is the eighth in a series of 11 map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on six maps at 1:24,000 scale. Together, the maps provide a comprehensive overview of a major valley-fill aquifer in southeastern Rockland County. The maps include surficial geology, geologic sections, water-infiltration potential of soil zone, aquifer thickness, water-table elevations, well yields, and land use. The valley-fill deposits consists of alluvial silt and sand, glacial outwash (sand and gravel), ice-contact sand and gravel, till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities, whereas the till, silt, and clay deposits have relatively low permeabilities. Water-table conditions prevail in unconfined sand and gravel along the Ramapo River valley and much of the Mahwah River valley. Artesian conditions prevail in confined sand and gravel buried under silt and clay and till in parts of the Mahway valley. The aquifer is recharged throughout, where the land surface is most permeable and is greatest along the margin of the valley, where runoff from the hillsides is concentrated. The use of land overlying the aquifer is predominantly commercial, agricultural and residential, with lesser industrial uses. (USGS)

  12. Induced polarization of clay-sand mixtures: experiments and modeling

    International Nuclear Information System (INIS)

    Okay, G.; Leroy, P.; Tournassat, C.; Ghorbani, A.; Jougnot, D.; Cosenza, P.; Camerlynck, C.; Cabrera, J.; Florsch, N.; Revil, A.

    2012-01-01

    Document available in extended abstract form only. Frequency-domain induced polarization (IP) measurements consist of imposing an alternative sinusoidal electrical current (AC) at a given frequency and measuring the resulting electrical potential difference between two other non-polarizing electrodes. The magnitude of the conductivity and the phase lag between the current and the difference of potential can be expressed into a complex conductivity with the in-phase representing electro-migration and a quadrature conductivity representing the reversible storage of electrical charges (capacitive effect) of the porous material. Induced polarization has become an increasingly popular geophysical method for hydrogeological and environmental applications. These applications include for instance the characterization of clay materials used as permeability barriers in landfills or to contain various types of contaminants including radioactive wastes. The goal of our study is to get a better understanding of the influence of the clay content, clay mineralogy, and pore water salinity upon complex conductivity measurements of saturated clay-sand mixtures in the frequency range ∼1 mHz-12 kHz. The complex conductivity of saturated unconsolidated sand-clay mixtures was experimentally investigated using two types of clay minerals, kaolinite and smectite in the frequency range 1.4 mHz - 12 kHz. Four different types of samples were used, two containing mainly kaolinite (80% of the mass, the remaining containing 15% of smectite and 5% of illite/muscovite; 95% of kaolinite and 5% of illite/muscovite), and the two others containing mainly Na-smectite or Na-Ca-smectite (95% of the mass; bentonite). The experiments were performed with various clay contents (1, 5, 20, and 100% in volume of the sand-clay mixture) and salinities (distilled water, 0.1 g/L, 1 g/L, and 10 g/L NaCl solution). In total, 44 saturated clay or clay-sand mixtures were prepared. Induced polarization measurements

  13. Detection and control of as-produced pyrocarbon permeability in biso-coated high-temperature gas-cooled reactor fuel particles

    International Nuclear Information System (INIS)

    Stinton, D.P.; Thiele, B.A.; Lackey, W.J.; Morgan, C.S.

    1980-05-01

    About 60 Biso-coated particle batches with coatings deposited in either 0.13- or 0.24-m dia coaters were studied in this work. These batches were carefully characterized for permeability by neon-helium intrusion, long-term chlorination followed by radiography, and fission gas release. These methods of permeability measurement were compared and correlated with deposition conditions as well as pyrocarbon properties. The results from several irradiation tests were also used to evaluate the validity of the permeability measurements. The neon-helium and long-term chlorination techniques correlated very clearly. Coatings with neon-to-helium ratios below 0.3 were gastight by the chlorination procedure, whereas those with ratios above 0.4 were permeable. The fission gas release technique was unable to distinguish between slightly permeable coatings and gastight ones. Therefore, neon-helium and long-term chlorination procedures are preferred over the fission gas release technique. Results from several irradiation tests verified that coatings with neon-to-helium ratios below 0.3 were gastight, whereas those with ratios above about 0.4 were permeable. 10 figures, 2 tables

  14. Policy Analysis of the Canadian Oil Sands Experience

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2013-09-01

    For those who support U.S. oil sands development, the Canadian oil sands industry is often identified as a model the U.S. might emulate, yielding financial and energy security benefits. For opponents of domestic oil sands development, the Canadian oil sands experience illustrates the risks that opponents of development believe should deter domestic policymakers from incenting U.S. oil sands development. This report does not seek to evaluate the particular underpinnings of either side of this policy argument, but rather attempts to delve into the question of whether the Canadian experience has relevance as a foundational model for U.S. oil sands development. More specifically, this report seeks to assess whether and how the Canadian oil sands experience might be predictive or instructive in the context of fashioning a framework for a U.S. oil sands industry. In evaluating the implications of these underpinnings for a prospective U.S. oil sands industry, this report concentrates on prospective development of the oil sands deposits found in Utah.

  15. A study of global sand seas

    Science.gov (United States)

    McKee, Edwin D.

    1979-01-01

    The birth of the idea that led to this publication on "Global Sand Seas" dates back to the late 1920's. At that time I was engaged in a study of the Coconino Sandstone of Arizona's Grand Canyon. Considerable controversy existed then as to whether this sandstone was a subaqueous deposit or was composed of wind-formed dunes. It became apparent that definitive literature was sparse or lacking on types of dunes, global distribution of these types, the mechanics of their development, the precise nature of their internal structure of cross-stratificiation, and the relation of wind systems to these sand forms. Especially lacking were data on criteria that could confidently be used in the recognition of ancient dunes. The common denominator in this publication is eolian sand bodies. Although the book is concerned primarily with desert sand seas, the subject matter is not restricted to deserts; it includes many references to deposits of coastal sand and to sand bodies in humid climates. Nor does the book deal exclusively with dunes, which, according to most definitions, involve mounds or hills. Many references are made to sand sheets, sand stringers, and other types of sand deposits that have no prominent topographic expression. All sand bodies accumulated by the action of wind are discussed. Chapters A-J of this publication are primarily topical. Chapters cover the grain texture, the color, and the structure of modern dunes and other eolian sands. Special treatment is given to the relation of wind data to dune interpretation, the evolution of form in current-deposited sand bodies as determined from experimental studies, and the discriminant analysis technique for differentiating between coastal and inland desert sands. This topical part of the publication also includes an analysis of criteria used in ancient deposits to interpret their eolian genesis and a consideration of economic application of the principles described, including a discussion of potentials and problems

  16. A modified parallel artificial membrane permeability assay for evaluating the bioconcentration of highly hydrophobic chemicals in fish.

    Science.gov (United States)

    Kwon, Jung-Hwan; Escher, Beate I

    2008-03-01

    Low cost in vitro tools are needed at the screening stage of assessment of bioaccumulation potential of new and existing chemicals because the number of chemical substances that needs to be tested highly exceeds the capacity of in vivo bioconcentration tests. Thus, the parallel artificial membrane permeability assay (PAMPA) system was modified to predict passive uptake/ elimination rate in fish. To overcome the difficulties associated with low aqueous solubility and high membrane affinity of highly hydrophobic chemicals, we measured the rate of permeation from the donor poly(dimethylsiloxane)(PDMS) disk to the acceptor PDMS disk through aqueous and PDMS membrane boundary layers and term the modified PAMPA system "PDMS-PAMPA". Twenty chemicals were selected for validation of PDMS-PAMPA. The measured permeability is proportional to the passive elimination rate constant in fish and was used to predict the "minimum" in vivo elimination rate constant. The in vivo data were very close to predicted values except for a few polar chemicals and metabolically active chemicals, such as pyrene and benzo[a]pyrene. Thus, PDMS-PAMPA can be an appropriate in vitro system for nonmetabolizable chemicals. Combination with metabolic clearance rates using a battery of metabolic degradation assays would enhance the applicability for metabolizable chemicals.

  17. Permeability During Magma Expansion and Compaction

    Science.gov (United States)

    Gonnermann, Helge. M.; Giachetti, Thomas; Fliedner, Céline; Nguyen, Chinh T.; Houghton, Bruce F.; Crozier, Joshua A.; Carey, Rebecca J.

    2017-12-01

    Plinian lapilli from the 1060 Common Era Glass Mountain rhyolitic eruption of Medicine Lake Volcano, California, were collected and analyzed for vesicularity and permeability. A subset of the samples were deformed at a temperature of 975°, under shear and normal stress, and postdeformation porosities and permeabilities were measured. Almost all undeformed samples fall within a narrow range of vesicularity (0.7-0.9), encompassing permeabilities between approximately 10-15 m2 and 10-10 m2. A percolation threshold of approximately 0.7 is required to fit the data by a power law, whereas a percolation threshold of approximately 0.5 is estimated by fitting connected and total vesicularity using percolation modeling. The Glass Mountain samples completely overlap with a range of explosively erupted silicic samples, and it remains unclear whether the erupting magmas became permeable at porosities of approximately 0.7 or at lower values. Sample deformation resulted in compaction and vesicle connectivity either increased or decreased. At small strains permeability of some samples increased, but at higher strains permeability decreased. Samples remain permeable down to vesicularities of less than 0.2, consistent with a potential hysteresis in permeability-porosity between expansion (vesiculation) and compaction (outgassing). We attribute this to retention of vesicle interconnectivity, albeit at reduced vesicle size, as well as bubble coalescence during shear deformation. We provide an equation that approximates the change in permeability during compaction. Based on a comparison with data from effusively erupted silicic samples, we propose that this equation can be used to model the change in permeability during compaction of effusively erupting magmas.

  18. Bacterial diversity of the American sand fly Lutzomyia intermedia using high-throughput metagenomic sequencing.

    Science.gov (United States)

    Monteiro, Carolina Cunha; Villegas, Luis Eduardo Martinez; Campolina, Thais Bonifácio; Pires, Ana Clara Machado Araújo; Miranda, Jose Carlos; Pimenta, Paulo Filemon Paolucci; Secundino, Nagila Francinete Costa

    2016-08-31

    Parasites of the genus Leishmania cause a broad spectrum of diseases, collectively known as leishmaniasis, in humans worldwide. American cutaneous leishmaniasis is a neglected disease transmitted by sand fly vectors including Lutzomyia intermedia, a proven vector. The female sand fly can acquire or deliver Leishmania spp. parasites while feeding on a blood meal, which is required for nutrition, egg development and survival. The microbiota composition and abundance varies by food source, life stages and physiological conditions. The sand fly microbiota can affect parasite life-cycle in the vector. We performed a metagenomic analysis for microbiota composition and abundance in Lu. intermedia, from an endemic area in Brazil. The adult insects were collected using CDC light traps, morphologically identified, carefully sterilized, dissected under a microscope and the females separated into groups according to their physiological condition: (i) absence of blood meal (unfed = UN); (ii) presence of blood meal (blood-fed = BF); and (iii) presence of developed ovaries (gravid = GR). Then, they were processed for metagenomics with Illumina Hiseq Sequencing in order to be sequence analyzed and to obtain the taxonomic profiles of the microbiota. Bacterial metagenomic analysis revealed differences in microbiota composition based upon the distinct physiological stages of the adult insect. Sequence identification revealed two phyla (Proteobacteria and Actinobacteria), 11 families and 15 genera; 87 % of the bacteria were Gram-negative, while only one family and two genera were identified as Gram-positive. The genera Ochrobactrum, Bradyrhizobium and Pseudomonas were found across all of the groups. The metagenomic analysis revealed that the microbiota of the Lu. intermedia female sand flies are distinct under specific physiological conditions and consist of 15 bacterial genera. The Ochrobactrum, Bradyrhizobium and Pseudomonas were the common genera. Our results detailing

  19. Benthic fluxes of oxygen and nutrients in sublittoral fine sands in a north-western Mediterranean coastal area

    Science.gov (United States)

    Sospedra, J.; Falco, S.; Morata, T.; Gadea, I.; Rodilla, M.

    2015-04-01

    Traditionally, benthic metabolism in sublittoral permeable sands have not been widely studied, although these sands can have a direct and transcendental impact in coastal ecosystems. This study aims to determine oxygen and nutrient fluxes at the sediment-water interface and the study of possible interactions among environmental variables and the benthic metabolism in well-sorted fine sands. Eight sampling campaigns were carried out over the annual cycle in the eastern coast of Spain (NW Mediterranean) at 9 m depth station with permeable bottoms. Water column and sediment samples were collected in order to determine physico-chemical and biological variables. Moreover, in situ incubations were performed to estimate the exchange of dissolved solutes in the sediment-water interface using dark and light benthic chambers. Biochemical compounds at the sediment surface ranged between 160 and 744 μg g-1 for proteins, 296 and 702 μg g-1 for carbohydrates, and between 327 and 1224 μg C g-1 for biopolymeric carbon. Chloroplastic pigment equivalents in sediments were mainly composed by chlorophyll a (1.81-2.89 μg g-1). These sedimentary organic descriptors indicated oligotrophic conditions according to the biochemical approach used. In this sense, the most abundant species in the macrobenthic community were sensitive to organic enrichment. In dark conditions, benthic fluxes behaved as a sink of oxygen and a source of nutrients. Oxygen fluxes (between -26,610 and -10,635 μmol m-2 d-1) were related with labile organic fraction (r=-0.86, p<0.01 with biopolymeric carbon; r=-0.91, p<0.01 with chloroplastic pigment equivalents). Daily fluxes of dissolved oxygen, that were obtained by adding light and dark fluxes, were only positive in spring campaigns (6966 μmol m-2 d-1) owing to the highest incident irradiance levels (r=0.98, p<0.01) that stimulate microphytobenthic primary production. Microphytobenthos played an important role on benthic metabolism and was the main primary

  20. Constitutive Soil Properties for Mason Sand and Kennedy Space Center

    Science.gov (United States)

    Thomas, Michael A.; Chitty, Daniel E.

    2011-01-01

    Accurate soil models are required for numerical simulations of land landings for the Orion Crew Exploration Vehicle (CEV). This report provides constitutive material models for two soil conditions at Kennedy Space Center (KSC) and four conditions of Mason Sand. The Mason Sand is the test sand for LaRC s drop tests and swing tests of the Orion. The soil models are based on mechanical and compressive behavior observed during geotechnical laboratory testing of remolded soil samples. The test specimens were reconstituted to measured in situ density and moisture content. Tests included: triaxial compression, hydrostatic compression, and uniaxial strain. A fit to the triaxial test results defines the strength envelope. Hydrostatic and uniaxial tests define the compressibility. The constitutive properties are presented in the format of LSDYNA Material Model 5: Soil and Foam. However, the laboratory test data provided can be used to construct other material models. The soil models are intended to be specific to the soil conditions they were tested at. The two KSC models represent two conditions at KSC: low density dry sand and high density in-situ moisture sand. The Mason Sand model was tested at four conditions which encompass measured conditions at LaRC s drop test site.

  1. Comparison of Mass Transfer Models for Determination of the Intestinal Permeability

    Directory of Open Access Journals (Sweden)

    P Zakeri-Milani

    2008-09-01

    Full Text Available Background and the purpose of the study: In determination of the permeability of the intestinal wall by external perfusion techniques, several models have been proposed. In the present study three models were used for experimental results that differ in their convection and diffusion assumptions. Material and Methods: Permeability coefficients for 13 compounds (metoprolol, propranolol, naproxen, ketoprofen, furosemide, hydrochlorothiazide, cimetidine, ranitidine, atenolol, piroxicam, antipyrine, ibuprofen and carbamazepine with known human intestinal permeability values were determined in anaesthetized rats by different mass transfer models and plotted versus the observed human intestinal permeabilities. Results: The calculated dimensionless wall permeability values were in the range of 0.37 - 4.85, 0.38-6.54 and 0.41-16.59 for complete radial mixing, mixing tank and laminar flow models respectively. The results indicated that all of the models work relatively well for our data despite fundamentally different assumptions. The wall permeabilities were in the order laminar flow > mixing tank > complete radial mixing. Conclusion: Although laminar flow model provides the most direct measure of the intrinsic wall permeability, it has limitations for highly permeable drugs such as ibuprofen. The normal physiological hydrodynamics is more complex and more investigation is required to find out the real hydrodynamics.

  2. The diffusion of sulphur from moulding sand to cast and methods of its elimination

    Directory of Open Access Journals (Sweden)

    M. Hosadyna

    2009-10-01

    Full Text Available The care of high quality castings requires taking into account the possible negative influence of decomposition products of moulding and core sands on the structure of castings produced. Such products are emitted both from the sands of I generation, meaning sands bound by bentonite, especially those containing carbon forming additives, as well as from the sands of II generation, meaning the sands with the binding materials or even the sands without any binders, such as the forms produced by using the LOST FOAM technology. The literature often refers to the negative effects of nitrogen emitted from the sands with the urea resins on the tendency to create surface defects. That is why the aim of this study was to assess the degree of sulphur diffusion to the ferroalloy castings and the proposal of its limitation.

  3. Isoproterenol attenuates high vascular pressure-induced permeability increases in isolated rat lungs.

    Science.gov (United States)

    Parker, J C; Ivey, C L

    1997-12-01

    To separate the contributions of cellular and basement membrane components of the alveolar capillary barrier to the increased microvascular permeability induced by high pulmonary venous pressures (Ppv), we subjected isolated rat lungs to increases in Ppv, which increased capillary filtration coefficient (Kfc) without significant hemorrhage (31 cmH2O) and with obvious extravasation of red blood cells (43 cmH2O). Isoproterenol (20 microM) was infused in one group (Iso) to identify a reversible cellular component of injury, and residual blood volumes were measured to assess extravasation of red blood cells through ruptured basement membranes. In untreated lungs (High Ppv group), Kfc increased 6.2 +/- 1.3 and 38.3 +/- 15.2 times baseline during the 31 and 43 cmH2O Ppv states. In Iso lungs, Kfc was 36.2% (P Kfc increases at moderate Ppv, possibly because of an endothelial effect, but it did not affect red cell extravasation at higher vascular pressures.

  4. The search for a source rock for the giant Tar Sand triangle accumulation, southeastern Utah

    Science.gov (United States)

    Huntoon, J.E.; Hansley, P.L.; Naeser, N.D.

    1999-01-01

    A large proportion (about 36%) of the world's oil resource is contained in accumulations of heavy oil or tar. In these large deposits of degraded oil, the oil in place represents only a fraction of what was present at the time of accumulation. In many of these deposits, the source of the oil is unknown, and the oil is thought to have migrated over long distances to the reservoirs. The Tar Sand triangle in southeastern Utah contains the largest tar sand accumulation in the United States, with 6.3 billion bbl of heavy oil estimated to be in place. The deposit is thought to have originally contained 13-16 billion bbl prior to the biodegradation, water washing, and erosion that have taken place since the middle - late Tertiary. The source of the oil is unknown. The tar is primarily contained within the Lower Permian White Rim Sandstone, but extends into permeable parts of overlying and underlying beds. Oil is interpreted to have migrated into the White Rim sometime during the Tertiary when the formation was at a depth of approximately 3500 m. This conclusion is based on integration of fluid inclusion analysis, time-temperature reconstruction, and apatite fission-track modeling for the White Rim Sandstone. Homogenization temperatures cluster around 85-90??C for primary fluid inclusions in authigenic, nonferroan dolomite in the White Rim. The fluid inclusions are associated with fluorescent oil-bearing inclusions, indicating that dolomite precipitation was coeval with oil migration. Burial reconstruction suggests that the White Rim Sandstone reached its maximum burial depth from 60 to 24 Ma, and that maximum burial was followed by unroofing from 24 to 0 Ma. Time-temperature modeling indicates that the formation experienced temperatures of 85-90??C from about 35 to 40 Ma during maximum burial. Maximum formation temperatures of about 105-110??C were reached at about 24 Ma, just prior to unroofing. Thermal modeling is used to examine the history of potential source rocks

  5. Artificial neural network models for prediction of intestinal permeability of oligopeptides

    Directory of Open Access Journals (Sweden)

    Kim Min-Kook

    2007-07-01

    Full Text Available Abstract Background Oral delivery is a highly desirable property for candidate drugs under development. Computational modeling could provide a quick and inexpensive way to assess the intestinal permeability of a molecule. Although there have been several studies aimed at predicting the intestinal absorption of chemical compounds, there have been no attempts to predict intestinal permeability on the basis of peptide sequence information. To develop models for predicting the intestinal permeability of peptides, we adopted an artificial neural network as a machine-learning algorithm. The positive control data consisted of intestinal barrier-permeable peptides obtained by the peroral phage display technique, and the negative control data were prepared from random sequences. Results The capacity of our models to make appropriate predictions was validated by statistical indicators including sensitivity, specificity, enrichment curve, and the area under the receiver operating characteristic (ROC curve (the ROC score. The training and test set statistics indicated that our models were of strikingly good quality and could discriminate between permeable and random sequences with a high level of confidence. Conclusion We developed artificial neural network models to predict the intestinal permeabilities of oligopeptides on the basis of peptide sequence information. Both binary and VHSE (principal components score Vectors of Hydrophobic, Steric and Electronic properties descriptors produced statistically significant training models; the models with simple neural network architectures showed slightly greater predictive power than those with complex ones. We anticipate that our models will be applicable to the selection of intestinal barrier-permeable peptides for generating peptide drugs or peptidomimetics.

  6. Analytic Model for Predicting the Permeability of Foam-type Wick

    Energy Technology Data Exchange (ETDEWEB)

    Ngo, Ich-Long; Byon, Chan [Yeungnam Univ., Gyeongsan (Korea, Republic of)

    2016-06-15

    Wicks play an important role in determining the thermal performance of heat pipes. Foam-type wicks are known to have good potential for enhancing the capillary performance of conventional types of wicks, and this is because of their high porosity and permeability. In this study, we develop an analytic expression for predicting the permeability of a foam-type wick based on extensive numerical work. The proposed correlation is based on the modified Kozeny-Carman’s equation, where the Kozeny-Carman coefficient is given as an exponential function of porosity. The proposed correlations are shown to predict the previous experimental results well for an extensive parametric range. The permeability of the foam-type wick is shown to be significantly higher than that of conventional wicks because of their high porosity.

  7. [Removal of nitrate from groundwater using permeable reactive barrier].

    Science.gov (United States)

    Li, Xiu-Li; Yang, Jun-Jun; Lu, Xiao-Xia; Zhang, Shu; Hou, Zhen

    2013-03-01

    To provide a cost-effective method for the remediation of nitrate-polluted groundwater, column experiments were performed to study the removal of nitrate by permeable reactive barrier filled with fermented mulch and sand (biowall), and the mechanisms and influence factors were explored. The experimental results showed that the environmental condition in the simulated biowall became highly reduced after three days of operation (oxidation-reduction potential was below - 100 mV), which was favorable for the reduction of nitrate. During the 15 days of operation, the removal rate of nitrate nitrogen (NO3(-) -N) by the simulated biowall was 80%-90% (NO3(-)-N was reduced from 20 mg x L(-1) in the inlet water to 1.6 mg x L(-1) in the outlet water); the concentration of nitrite nitrogen (NO2(-) -N) in the outlet water was below 2.5 mg x L(-1); the concentration of ammonium nitrogen (NH4(+) -N) was low in the first two days but increased to about 12 mg x L(-1) since day three. The major mechanisms involved in the removal of nitrate nitrogen were adsorption and biodegradation. When increasing the water flow velocity in the simulated biowall, the removal rate of NO3(-) -N was reduced and the concentration of NH4(+) -N in the outlet water was significantly reduced. A simulated zeolite wall was set up following the simulated biowall and 98% of the NH4(+) -N could be removed from the water.

  8. The influence of groundwater depth on coastal dune development at sand flats close to inlets

    Science.gov (United States)

    Silva, Filipe Galiforni; Wijnberg, Kathelijne M.; de Groot, Alma V.; Hulscher, Suzanne J. M. H.

    2018-05-01

    A cellular automata model is used to analyze the effects of groundwater levels and sediment supply on aeolian dune development occurring on sand flats close to inlets. The model considers, in a schematized and probabilistic way, aeolian transport processes, groundwater influence, vegetation development, and combined effects of waves and tides that can both erode and accrete the sand flat. Next to three idealized cases, a sand flat adjoining the barrier island of Texel, the Netherlands, was chosen as a case study. Elevation data from 18 annual LIDAR surveys was used to characterize sand flat and dune development. Additionally, a field survey was carried out to map the spatial variation in capillary fringe depth across the sand flat. Results show that for high groundwater situations, sediment supply became limited inducing formation of Coppice-like dunes, even though aeolian losses were regularly replenished by marine import during sand flat flooding. Long dune rows developed for high sediment supply scenarios which occurred for deep groundwater levels. Furthermore, a threshold depth appears to exist at which the groundwater level starts to affect dune development on the inlet sand flat. The threshold can vary spatially depending on external conditions such as topography. On sand flats close to inlets, groundwater is capable of introducing spatial variability in dune growth, which is consistent with dune development patterns found on the Texel sand flat.

  9. Ammonia and urea permeability of mammalian aquaporins

    DEFF Research Database (Denmark)

    Litman, Thomas; Søgaard, Rikke; Zeuthen, Thomas

    2009-01-01

    significant at alkaline pH. It is debated whether the H(+) ion passes via the aquaporin or by some external route; the investigation of this problem requires the aquaporin-expressing cell to be voltage-clamped. The ammonia-permeable aquaporins differ from other aquaporins by having a less restrictive aromatic...... groups differ in the amino acid composition of their aromatic/arginine regions. The location of the ammonia-permeable aquaporins in the body parallels that of the Rh proteins. This applies to erythrocytes and to cells associated with nitrogen homeostasis and high rates of anabolism. In the liver, AQPs 8...

  10. Film Permeability Determination Using Static Permeability Cells

    Science.gov (United States)

    The permeability of tarps to soil fumigant pesticides varies depending on the active ingredient chemical: dimethyl disulfide (DMDS), methyl bromide, chloropicrin, or other. The diffusion rate can be represented by the mass transfer coefficient (MTC).

  11. Intermontane eolian sand sheet development, Upper Tulum Valley, central-western Argentina

    Directory of Open Access Journals (Sweden)

    Patrick Francisco Fuhr Dal' Bó

    Full Text Available ABSTRACTThe intermontane Upper Tulum eolian sand sheet covers an area of ca. 125 km² at north of the San Juan Province, central-western Argentina. The sand sheet is currently an aggrading system where vegetation cover, surface cementation and periodic flooding withhold the development of dunes with slipfaces. The sand sheet surface is divided into three parts according to the distribution of sedimentary features, which reflects the variation in sediment budget, water table level and periodic flooding. The central sand sheet part is the main area of eolian deposition and is largely stabilized by vegetation. The sedimentary succession is 4 m thick and records the vertical interbedding of eolian and subaqueous deposits, which have been deposited for at least 3.6 ky with sedimentation rates of 86.1 cm/ky. The construction of the sand sheet is associated with deflation of the sand-graded debris sourced by San Juan alluvial fan, which is available mainly in drier fall-winter months where water table is lower and wind speeds are periodically above the threshold velocity for sand transport. The accumulation of sedimentary bodies occurs in a stabilized eolian system where vegetation cover, thin mud veneers and surface cementation are the main agents in promoting accumulation. The preservation of the sand sheet accumulations is enabled by the progressive creation of the accommodation space in a tectonically active basin and the continuous burial of geological bodies favored by high rates of sedimentation.

  12. Permeability testing of biomaterial membranes

    Energy Technology Data Exchange (ETDEWEB)

    Dreesmann, L; Hajosch, R; Nuernberger, J Vaz; Schlosshauer, B [NMI Natural and Medical Sciences Institute at University Tuebingen, Markwiesenstr. 55, D-72770 Reutlingen (Germany); Ahlers, M [GELITA AG, Gammelsbacher Str. 2, D-69412 Eberbach (Germany)], E-mail: schlosshauer@nmi.de

    2008-09-01

    The permeability characteristics of biomaterials are critical parameters for a variety of implants. To analyse the permeability of membranes made from crosslinked ultrathin gelatin membranes and the transmigration of cells across the membranes, we combined three technical approaches: (1) a two-chamber-based permeability assay, (2) cell culturing with cytochemical analysis and (3) biochemical enzyme electrophoresis (zymography). Based on the diffusion of a coloured marker molecule in conjunction with photometric quantification, permeability data for a gelatin membrane were determined in the presence or absence of gelatin degrading fibroblasts. Cytochemical evaluation after cryosectioning of the membranes was used to ascertain whether fibroblasts had infiltrated the membrane inside. Zymography was used to investigate the potential release of proteases from fibroblasts, which are known to degrade collagen derivatives such as gelatin. Our data show that the diffusion equilibrium of a low molecular weight dye across the selected gelatin membrane is approached after about 6-8 h. Fibroblasts increase the permeability due to cavity formation in the membrane inside without penetrating the membrane for an extended time period (>21 days in vitro). Zymography indicates that cavity formation is most likely due to the secretion of matrix metalloproteinases. In summary, the combination of the depicted methods promises to facilitate a more rational development of biomaterials, because it provides a rapid means of determining permeability characteristics and bridges the gap between descriptive methodology and the mechanistic understanding of permeability alterations due to biological degradation.

  13. Permeability testing of biomaterial membranes

    International Nuclear Information System (INIS)

    Dreesmann, L; Hajosch, R; Nuernberger, J Vaz; Schlosshauer, B; Ahlers, M

    2008-01-01

    The permeability characteristics of biomaterials are critical parameters for a variety of implants. To analyse the permeability of membranes made from crosslinked ultrathin gelatin membranes and the transmigration of cells across the membranes, we combined three technical approaches: (1) a two-chamber-based permeability assay, (2) cell culturing with cytochemical analysis and (3) biochemical enzyme electrophoresis (zymography). Based on the diffusion of a coloured marker molecule in conjunction with photometric quantification, permeability data for a gelatin membrane were determined in the presence or absence of gelatin degrading fibroblasts. Cytochemical evaluation after cryosectioning of the membranes was used to ascertain whether fibroblasts had infiltrated the membrane inside. Zymography was used to investigate the potential release of proteases from fibroblasts, which are known to degrade collagen derivatives such as gelatin. Our data show that the diffusion equilibrium of a low molecular weight dye across the selected gelatin membrane is approached after about 6-8 h. Fibroblasts increase the permeability due to cavity formation in the membrane inside without penetrating the membrane for an extended time period (>21 days in vitro). Zymography indicates that cavity formation is most likely due to the secretion of matrix metalloproteinases. In summary, the combination of the depicted methods promises to facilitate a more rational development of biomaterials, because it provides a rapid means of determining permeability characteristics and bridges the gap between descriptive methodology and the mechanistic understanding of permeability alterations due to biological degradation

  14. Hybrid green permeable pave with hexagonal modular pavement systems

    International Nuclear Information System (INIS)

    Rashid, M A; Abustan, I; Hamzah, M O

    2013-01-01

    Modular permeable pavements are alternatives to the traditional impervious asphalt and concrete pavements. Pervious pore spaces in the surface allow for water to infiltrate into the pavement during rainfall events. As of their ability to allow water to quickly infiltrate through the surface, modular permeable pavements allow for reductions in runoff quantity and peak runoff rates. Even in areas where the underlying soil is not ideal for modular permeable pavements, the installation of under drains has still been shown to reflect these reductions. Modular permeable pavements have been regarded as an effective tool in helping with stormwater control. It also affects the water quality of stormwater runoff. Places using modular permeable pavement has been shown to cause a significant decrease in several heavy metal concentrations as well as suspended solids. Removal rates are dependent upon the material used for the pavers and sub-base material, as well as the surface void space. Most heavy metals are captured in the top layers of the void space fill media. Permeable pavements are now considered an effective BMP for reducing stormwater runoff volume and peak flow. This study examines the extent to which such combined pavement systems are capable of handling load from the vehicles. Experimental investigation were undertaken to quantify the compressive characteristics of the modular. Results shows impressive results of achieving high safety factor for daily life vehicles.

  15. Simulating Sand Behavior through Terrain Subdivision and Particle Refinement

    Science.gov (United States)

    Clothier, M.

    2013-12-01

    Advances in computer graphics, GPUs, and parallel processing hardware have provided researchers with new methods to visualize scientific data. In fact, these advances have spurred new research opportunities between computer graphics and other disciplines, such as Earth sciences. Through collaboration, Earth and planetary scientists have benefited by using these advances in hardware technology to process large amounts of data for visualization and analysis. At Oregon State University, we are collaborating with the Oregon Space Grant and IGERT Ecosystem Informatics programs to investigate techniques for simulating the behavior of sand. In addition, we have also been collaborating with the Jet Propulsion Laboratory's DARTS Lab to exchange ideas on our research. The DARTS Lab specializes in the simulation of planetary vehicles, such as the Mars rovers. One aspect of their work is testing these vehicles in a virtual "sand box" to test their performance in different environments. Our research builds upon this idea to create a sand simulation framework to allow for more complex and diverse environments. As a basis for our framework, we have focused on planetary environments, such as the harsh, sandy regions on Mars. To evaluate our framework, we have used simulated planetary vehicles, such as a rover, to gain insight into the performance and interaction between the surface sand and the vehicle. Unfortunately, simulating the vast number of individual sand particles and their interaction with each other has been a computationally complex problem in the past. However, through the use of high-performance computing, we have developed a technique to subdivide physically active terrain regions across a large landscape. To achieve this, we only subdivide terrain regions where sand particles are actively participating with another object or force, such as a rover wheel. This is similar to a Level of Detail (LOD) technique, except that the density of subdivisions are determined by

  16. Parcperdue geopressure-geothermal project. Study a geopressured reservoir by drilling and producing a well in a limited geopressured water sand. Final technical report, September 28, 1979-December 31, 1983

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, J.R.; Stanley, J.G. (eds.)

    1984-01-15

    The behavior of geopressured reservoirs was investigated by drilling and producing a well in small, well defined, geopressured reservoir; and performing detailed pressure transient analysis together with geological, geophysical, chemical, and physical studies. The Dow-DOE L. R. Sweezy No. 1 well was drilled to a depth of 13,600 feet in Parcperdue field, just south of Lafayette, Louisiana, and began production in April, 1982. The production zone was a poorly consolidated sandstone which constantly produced sand into the well stream, causing damage to equipment and causing other problems. The amount of sand production was kept manageable by limiting the flow rate to below 10,000 barrels per day. Reservoir properties of size, thickness, depth, temperature, pressure, salinity, porosity, and permeability were close to predicted values. The reservoir brine was undersaturated with respect to gas, containing approximately 20 standard cubic feet of gas per barrel of brine. Shale dewatering either did not occur or was insignificant as a drive mechanism. Production terminated when the gravel-pack completion failed and the production well totally sanded in, February, 1983. Total production up to the sanding incident was 1.94 million barrels brine and 31.5 million standard cubic feet gas.

  17. Influence of Geometric Parameters of the Hydrocyclone and Sand Concentration on the Water/Sand/Heavy-Oil Separation Process: Modeling and Simulation

    Directory of Open Access Journals (Sweden)

    F Farias

    2016-09-01

    Full Text Available In the oil exploitation, produced fluids are composed of oil, gas, water and sand (depending on the reservoir location. The presence of sand in flow oil leads to several industrial problems for example: erosion and accumulation in valves and pipeline. Thus, it is necessary to stop production for manual cleaning of equipments and pipes. These facts have attracted attention of academic and industrial areas, enabling the appearing of new technologies or improvement of the water/oil/sand separation process. One equipment that has been used to promote phase separation is the hydrocyclone due to high performance of separation and required low cost to installation and maintenance. In this sense, the purpose of this work is to study numerically the effect of geometric parameters (vortex finder diameter of the hydrocyclone and sand concentration on the inlet fluid separation process. A numerical solution of the governing equations was obtained by the ANSYS CFX-11 commercial code. Results of the streamlines, pressure drop and separation efficiency on the hydrocyclone are presented and analyzed. It was observed that the particles concentration and geometry affect the separation efficiency of the hydrocyclone.

  18. Group boundary permeability moderates the effect of a dependency meta-stereotype on help-seeking behaviour.

    Science.gov (United States)

    Zhang, Lange; Kou, Yu; Zhao, Yunlong; Fu, Xinyuan

    2016-08-01

    Previous studies have found that when low-status group members are aware that their in-group is stereotyped as dependent by a specific out-group (i.e. a dependency meta-stereotype is salient), they are reluctant to seek help from the high-status out-group to avoid confirming the negative meta-stereotype. However, it is unclear whether low-status group members would seek more help in the context of a salient dependency meta-stereotype when there is low (vs. high) group boundary permeability. Therefore, we conducted two experiments to examine the moderating effect of permeability on meta-stereotype confirmation with a real group. In study 1, we manipulated the salience of the dependency meta-stereotype, measured participants' perceived permeability and examined their help-seeking behaviour in a real-world task. Participants who perceived low permeability sought more help when the meta-stereotype was salient (vs. not salient), whereas participants who perceived high permeability sought the same amount of help across conditions. In study 2, we manipulated the permeability levels and measured the dependency meta-stereotype. Participants who endorsed a high-dependency meta-stereotype sought more help than participants who endorsed a low-dependency meta-stereotype; this effect was particularly strong in the low-permeability condition. The implications of these results for social mobility and intergroup helping are discussed. © 2015 International Union of Psychological Science.

  19. Prediction of Liquefaction Potential of Dredge Fill Sand by DCP and Dynamic Probing

    International Nuclear Information System (INIS)

    Alam, Md. Jahangir; Azad, Abul Kalam; Rahman, Ziaur

    2008-01-01

    From many research it is proved that liquefaction potential of sand is function of mainly relative density and confining pressure. During routine site investigations, high-quality sampling and laboratory testing of sands are not feasible because of inevitable sample disturbance effects and budgetary constraints. On the other hand quality control of sand fill can be done by determining in situ density of sand in layer by layer which is expensive and time consuming. In this paper TRL DCP (Transportation Research Laboratory Dynamic Cone Penetration) and DPL (Dynamic Probing Light) are calibrated to predict the relative density of sand deposit. For this purpose sand of known relative density is prepared in a calibration chamber which is a mild steel cylinder with diameter 0.5 m and height 1.0 m. Relative density of sand is varied by controlling height of fall and diameter of hole of sand discharge bowl. After filling, every time DPL and DCP tests are performed and for every blow the penetration of cone is recorded. N10 is then calculated from penetration records. Thus a database is compiled where N10 and relative densities are known. A correlation is made between N 10 and relative density for two types of sand. A good correlation of N 10 and relative density is found

  20. Permeability-Porosity Relationships of Subduction Zone Sediments

    Science.gov (United States)

    Gamage, K.; Screaton, E.; Bekins, B.; Aiello, I.

    2008-12-01

    Permeability-porosity relationships for sediments from Northern Barbados, Costa Rica, Nankai, and Peru subduction zones were examined based on their sediment type and grain size distribution. Greater correlation was observed between permeability and porosity for siliciclastic sediments, diatom oozes, and nannofossil chalk than for nannofossil oozes. For siliciclastic sediments, grouping of sediments by clay content yields relationships that are generally consistent with results from other marine settings and suggest decreasing permeability for a given porosity as clay content increases. Correction of measured porosities for smectite content generally improves the quality of permeability-porosity relationships. The relationship between permeability and porosity for diatom oozes may be controlled by the amount of clay present in the ooze, causing diatom oozes to behave similarly to siliciclastic sediments. For a given porosity the nannofossil oozes have higher permeability values by 1.5 orders of magnitude than the siliciclastic sediments. However, the use of a permeability-porosity relation may not be appropriate for unconsolidated carbonates such as nannofossil oozes. This study provided insight to the effects of porosity correction for smectite, variations in lithology and grain size in permeability-porosity relationships. However, further progress in delineating controls on permeability will require more careful and better documented permeability tests on characterized samples.

  1. Research in Seismology

    Science.gov (United States)

    1977-12-31

    for several sandstones (Fatt and Davis, 1952), Westerly granite ( Frangos , 1967), and Ottawa sand (Zoback and Byerlee, 1976). In general, permeability...an order of magnitude ( Frangos , 1967). However, since the effect of fluid flow is negligible in all but the highly permeable rocks, we need only

  2. POSSIBILITY OF BENEFICIATION OF SILICA SAND FROM THE CROATIAN DEPOSITS USING ATTRITION SCRUBBING

    Directory of Open Access Journals (Sweden)

    Ivan Sobota

    2011-12-01

    Full Text Available To meet high quality requirements defined for specific industrial applications, the raw sand often has to be subjected to extensive physical and chemical processing. The possibility of achieving silica sand concentrate of required quality depends mostly on raw sand properties, primarily mineral impurity types and contents, and features of applied beneficiation methods. When the impurities occur in the form of oxide coatings on the surfaces of the single sand grains, attriton scrubbing is applied. By reducing the proportion of oxide coatings on the grains, the quality of sand can be improved. With the aim to determine the possibilities of the beneficiation of silica sand from significant Croatian deposits (“Vrtlinska”, “Štefanac” and “Španovica” and achieve concentrate grade complying with the requirements of domestic industry, laboratory tests were conducted on three raw sand samples with different SiO2 and impurity contents. Grain size distribution, chemical and mineral composition of raw sand samples, and the possibility of their quality improvement by applying the washing, classification and attrition scrubbing were defined by analysis of test results (the paper is published in Croatian.

  3. A new low-cost method of reclaiming mixed foundry waste sand based on wet-thermal composite reclamation

    OpenAIRE

    Fan Zitian; Liu Fuchu; Long Wei

    2014-01-01

    A lot of mixed clay-resin waste sand from large-scale iron foundries is discharged every day; so mixed waste sand reclamation in low cost and high quality has a great realistic significance. In the study to investigate the possibility of reusing two types of waste foundry sands, resin bonded sand and clay bonded sand which came from a Chinese casting factory, a new low-cost reclamation method of the mixed foundry waste sand based on the wet-thermal composite reclamation was proposed. The wast...

  4. Gas and Water Permeability of Concrete

    Energy Technology Data Exchange (ETDEWEB)

    Villar, M. V.; Martin, P. L.; Romero, F. J.; Gutierrez-Rodirgo, V.; Barcala, J. M.

    2012-11-01

    The gas pressure of concrete samples was measured in an unsteady-state equipment working under low injection pressures and in a newly fine tuned steady-state setup working under different pressures. These measurements allowed the estimation of the intrinsic and relative gas permeability of the concrete and of the effect of boundary conditions on them. Permeability decreased with water content, but it was also greatly affected by the hydraulic history of concrete, i.e. if it had been previously dried or wetted. In particular, and for a given degree of saturation, the gas permeability of concrete previously saturated was lower than if the concrete had been just air dried or saturated after air drying. In any case, the gas permeability was about two orders of magnitude higher than the liquid water permeability (10-16 vs. 10-18 m2), probably due to the chemical reactions taking place during saturation (carbonation). The relative gas permeability of concrete increased sharply for water degrees of saturation smaller than 50%. The boundary conditions also affected the gas permeability, which seemed to be mostly conditioned by the back pressure and the confining pressure, increasing as the former increased and decreasing as the latter increased, i.e. decreasing as the effective pressure increased. Overall the increase of pressure head or injection pressure implied a decrease in gas permeability. External,microcracking during air-drying could not be ruled out as responsible for the decrease of permeability with confining pressure. The apparent permeability obtained applying the Klinkenberg method for a given effective pressure was only slightly smaller than the average of all the values measured for the same confining pressure range. For this reason it is considered that the Klinkenberg effect was not relevant in the range of pressures applied. (Author) 37 refs.

  5. The complex initial reluctivity, permeability and susceptibility spectra of magnetic materials

    Science.gov (United States)

    Hamilton, N. C.

    2015-03-01

    The HF complex permeability spectrum of a magnetic material is deduced from the measured impedance spectrum, which is then normalized to a series permeability spectrum. However, this series permeability spectrum has previously been shown to correspond to a parallel magnetic circuit, which is not appropriate. Some of the implications of this truth are examined. This electric/magnetic duality has frustrated efforts to interpret the shape of the complex magnetic permeability spectra of materials, and has hindered the application of impedance spectroscopy to magnetic materials. In the presence of magnetic loss, the relationship between the relative magnetic permeability and the magnetic susceptibility is called into question. The use of reluctivity spectra for expressing magnetic material properties is advocated. The relative loss factor, tanδm/μi is shown to be an approximation for the imaginary part of the reluctivity. A single relaxation model for the initial reluctivity spectra of magnetic materials is presented, and its principles are applied to measurements of a high permeability ferrite. The results are presented as contour plots of the spectra as a function of temperature.

  6. Analysis of Fault Permeability Using Mapping and Flow Modeling, Hickory Sandstone Aquifer, Central Texas

    Energy Technology Data Exchange (ETDEWEB)

    Nieto Camargo, Jorge E., E-mail: jorge.nietocamargo@aramco.com; Jensen, Jerry L., E-mail: jjensen@ucalgary.ca [University of Calgary, Department of Chemical and Petroleum Engineering (Canada)

    2012-09-15

    Reservoir compartments, typical targets for infill well locations, are commonly created by faults that may reduce permeability. A narrow fault may consist of a complex assemblage of deformation elements that result in spatially variable and anisotropic permeabilities. We report on the permeability structure of a km-scale fault sampled through drilling a faulted siliciclastic aquifer in central Texas. Probe and whole-core permeabilities, serial CAT scans, and textural and structural data from the selected core samples are used to understand permeability structure of fault zones and develop predictive models of fault zone permeability. Using numerical flow simulation, it is possible to predict permeability anisotropy associated with faults and evaluate the effect of individual deformation elements in the overall permeability tensor. We found relationships between the permeability of the host rock and those of the highly deformed (HD) fault-elements according to the fault throw. The lateral continuity and predictable permeability of the HD fault elements enhance capability for estimating the effects of subseismic faulting on fluid flow in low-shale reservoirs.

  7. Permeability of cork to gases.

    Science.gov (United States)

    Faria, David P; Fonseca, Ana L; Pereira, Helen; Teodoro, Orlando M N D

    2011-04-27

    The permeability of gases through uncompressed cork was investigated. More than 100 samples were assessed from different plank qualities to provide a picture of the permeability distribution. A novel technique based on a mass spectrometer leak detector was used to directly measure the helium flow through the central area of small disks 10 mm in diameter and 2 mm thick. The permeability for nitrogen, oxygen, and other gases was measured by the pressure rise technique. Boiled and nonboiled cork samples from different sections were evaluated. An asymmetric frequency distribution ranging 3 orders of magnitude (roughly from 1 to 1000 μmol/(cm·atm·day)) for selected samples without macroscopic defects was found, having a peak below 100 μmol/(cm·atm·day). Correlation was found between density and permeability: higher density samples tend to show lower permeability. However, boiled cork showed a mean lower permeability despite having a lower density. The transport mechanism of gases through cork was also examined. Calculations suggest that gases permeate uncompressed cork mainly through small channels between cells under a molecular flow regime. The diameter of such channels was estimated to be in the range of 100 nm, in agreement with the plasmodesmata size in the cork cell walls.

  8. bentonite-sand mixture as new backfill/buffer material

    International Nuclear Information System (INIS)

    Cui Suli; Liu Jisheng; Zhang Huyuan; Liang Jian

    2008-01-01

    The mixture of bentonite and quartz sand is suggested as a new backfill/buffer material for geological disposal of HLW. To improve the further design of underground laboratory and in-situ industrial construction test, the optimization of sand addition to bentonite is focused at present research stage. Based on summarizing the research results abroad, laboratory tests were conducted on the mixture of GMZ001 bentonite and quartz sand, such as compaction test and swelling tests etc. Test data shows that GMZ bentonite-sand mixture exhibits a favorite compaction with a 30% sand addition, a highest swelling pressure with a 20% sand addition, and a decreasing plasticity with increases in sand addition and pore liquid concentration. (authors)

  9. Decision trees to characterise the roles of permeability and solubility on the prediction of oral absorption.

    Science.gov (United States)

    Newby, Danielle; Freitas, Alex A; Ghafourian, Taravat

    2015-01-27

    Oral absorption of compounds depends on many physiological, physiochemical and formulation factors. Two important properties that govern oral absorption are in vitro permeability and solubility, which are commonly used as indicators of human intestinal absorption. Despite this, the nature and exact characteristics of the relationship between these parameters are not well understood. In this study a large dataset of human intestinal absorption was collated along with in vitro permeability, aqueous solubility, melting point, and maximum dose for the same compounds. The dataset allowed a permeability threshold to be established objectively to predict high or low intestinal absorption. Using this permeability threshold, classification decision trees incorporating a solubility-related parameter such as experimental or predicted solubility, or the melting point based absorption potential (MPbAP), along with structural molecular descriptors were developed and validated to predict oral absorption class. The decision trees were able to determine the individual roles of permeability and solubility in oral absorption process. Poorly permeable compounds with high solubility show low intestinal absorption, whereas poorly water soluble compounds with high or low permeability may have high intestinal absorption provided that they have certain molecular characteristics such as a small polar surface or specific topology. Copyright © 2015 Elsevier Masson SAS. All rights reserved.

  10. Comparison between predicted and observed sand waves and sand banks in the North Sea

    NARCIS (Netherlands)

    Hulscher, Suzanne J.M.H.; van den Brink, G.M.

    2001-01-01

    For the first time a prediction model of regular morphological patterns on the seabed was tested against observations of sand wave and sand bank occurrence in the entire North Sea. The model, which originates from first physical principles, predicts this occurrence via two dimensionless parameters

  11. Advanced CANDU reactor: an optimized energy source of oil sands application

    International Nuclear Information System (INIS)

    Hopwood, J.M.; Bock, D.; Miller, A.; Kuran, S.; Keil, H.; Fiorino, L.; Duffey, R.; Dunbar, R.B.

    2003-01-01

    Atomic Energy of Canada Limited (AECL) is developing the ACR-700 TM (Advanced CANDU Reactor-700 TM ) to meet customer needs for reduced capital cost, shorter construction schedule, high capacity factor while retaining the benefits of the CANDU experience base. The ACR-700 is based on the concept of CANDU horizontal fuel channels surrounded by heavy water moderator. The major innovation of this design is the use of slightly enriched uranium fuel in a CANFLEX bundle that is cooled by light water. This ensures: higher main steam pressures and temperatures providing higher thermal efficiency; a compact and simpler reactor design with reduced capital costs and shorter construction schedules; and reduced heavy water inventory compared to existing CANDU reactors. ACR-700 is not only a technically advanced and cost effective solution for electricity generating utilities, but also a low-cost, long-life and sustainable steam source for increasing Alberta's Oil Sand production rates. Currently practiced commercial surface mining and extraction of Oil Sand resources has been well established over the last three decades. But a majority of the available resources are somewhat deeper underground require in-situ extraction. Economic removal of such underground resources is now possible through the Steam Assisted Gravity Drainage (SAGD) process developed and proto-type tested in-site. SAGD requires the injection of large quantities of high-pressure steam into horizontal wells to form reduced viscosity bitumen and condensate mixture that is then collected at the surface. This paper describes joint AECL studies with CERI (Canadian Energy Research Institute) for the ACR, supplying both electricity and medium-pressure steam to an oil sands facility. The extensive oil sands deposits in northern Alberta are a very large energy resource. Currently, 30% of Canda's oil production is from the oil sands and this is expected to expand greatly over the coming decade. The bitumen deposits in the

  12. Fluid flow simulation and permeability computation in deformed porous carbonate grainstones

    Science.gov (United States)

    Zambrano, Miller; Tondi, Emanuele; Mancini, Lucia; Lanzafame, Gabriele; Trias, F. Xavier; Arzilli, Fabio; Materazzi, Marco; Torrieri, Stefano

    2018-05-01

    In deformed porous carbonates, the architecture of the pore network may be modified by deformation or diagenetic processes altering the permeability with respect to the pristine rock. The effects of the pore texture and morphology on permeability in porous rocks have been widely investigated due to the importance during the evaluation of geofluid reservoirs. In this study, these effects are assessed by combining synchrotron X-ray computed microtomography (SR micro-CT) and computational fluid dynamics. The studied samples pertain to deformed porous carbonate grainstones highly affected by deformation bands (DBs) exposed in Northwestern Sicily and Abruzzo regions, Italy. The high-resolution SR micro-CT images of the samples, acquired at the SYRMEP beamline of the Elettra - Sincrotrone Trieste laboratory (Italy), were used for simulating a pressure-driven flow by using the lattice-Boltzmann method (LBM). For the experiments, a multiple relaxation time (MRT) model with the D3Q19 scheme was used to avoid viscosity-dependent results of permeability. The permeability was calculated using Darcy's law once steady conditions were reached. After the simulations, the pore-network properties (effective porosity, specific surface area, and geometrical tortuosity) were calculated using 3D images of the velocity fields. These images were segmented considering a velocity threshold value higher than zero. The study showed that DBs may generate significant heterogeneity and anisotropy of the permeability of the evaluated rock samples. Cataclasis and cementation process taking place within the DBs reduce the effective porosity and therefore the permeability. Contrary to this, pressure dissolution and faulting may generate connected channels which contribute to the permeability only parallel to the DB.

  13. Seasonal variation in the prevalence of sand flies infected with Leishmania donovani.

    Science.gov (United States)

    Tiwary, Puja; Kumar, Dinesh; Mishra, Mukesh; Singh, Rudra Pratap; Rai, Madhukar; Sundar, Shyam

    2013-01-01

    Visceral Leishmaniasis (VL) is a life threatening neglected infectious disease in the Indian subcontinent, transmitted by the bite of female sand flies. Estimation of the infectivity in the vector population, collected in different seasons, may be useful to better understanding the transmission dynamics of VL as well as to plan vector control measures. We collected sand flies from highly endemic regions of Bihar state, India for one year over three seasons. The species of the sand flies were confirmed by species-specific PCR-RFLP. Leishmania donovani infection was investigated in 1397 female Phlebotomus argentipes using PCR, targeting the Leishmania specific minicircle of the kDNA region. Further, the parasitic load in the infected sand flies was measured using quantitative PCR. Though sand flies were most abundant in the rainy season, the highest rate of infection was detected in the winter season with 2.84% sand flies infected followed by the summer and rainy seasons respectively. This study can help in vector elimination programmes and to reduce disease transmission.

  14. Critical State of Sand Matrix Soils

    Science.gov (United States)

    Marto, Aminaton; Tan, Choy Soon; Makhtar, Ahmad Mahir; Kung Leong, Tiong

    2014-01-01

    The Critical State Soil Mechanic (CSSM) is a globally recognised framework while the critical states for sand and clay are both well established. Nevertheless, the development of the critical state of sand matrix soils is lacking. This paper discusses the development of critical state lines and corresponding critical state parameters for the investigated material, sand matrix soils using sand-kaolin mixtures. The output of this paper can be used as an interpretation framework for the research on liquefaction susceptibility of sand matrix soils in the future. The strain controlled triaxial test apparatus was used to provide the monotonic loading onto the reconstituted soil specimens. All tested soils were subjected to isotropic consolidation and sheared under undrained condition until critical state was ascertain. Based on the results of 32 test specimens, the critical state lines for eight different sand matrix soils were developed together with the corresponding values of critical state parameters, M, λ, and Γ. The range of the value of M, λ, and Γ is 0.803–0.998, 0.144–0.248, and 1.727–2.279, respectively. These values are comparable to the critical state parameters of river sand and kaolin clay. However, the relationship between fines percentages and these critical state parameters is too scattered to be correlated. PMID:24757417

  15. Alberta's oil sands fiscal system : historical context and system performance

    International Nuclear Information System (INIS)

    2007-01-01

    This report described the fiscal system applied to Alberta's oil sands. It is the first technical report forming part of a series designed to provide information and to invite comment as part of the Government of Alberta's public review of the fiscal system applied to the province's oil and gas resources. Specifically, this report assessed the robustness of Alberta's oil sands fiscal system and assessed how the regime balanced the risks and rewards to both investors and Albertans across a range of expected and probable economic outcomes. The report provided an explanation of the history and context of Alberta's royalty regime and included a case-by-case approach. It also provided a discussion of the oil sands fiscal system description. Next, it described the methodology employed for the analysis of the oil sands fiscal system. It also provided the assumptions for 5 scenario cases and presented the fiscal map approach for assessing project economics and fiscal system performance. Last, summary observations were presented. It was found that the oil sands fiscal system is very flexible for adverse economic conditions and much less so for highly profitable conditions. tabs., figs

  16. Architecture and reservoir quality of low-permeable Eocene lacustrine turbidite sandstone from the Dongying Depression, East China

    Science.gov (United States)

    Munawar, Muhammad Jawad; Lin, Chengyan; Chunmei, Dong; Zhang, Xianguo; Zhao, Haiyan; Xiao, Shuming; Azeem, Tahir; Zahid, Muhammad Aleem; Ma, Cunfei

    2018-05-01

    The architecture and quality of lacustrine turbidites that act as petroleum reservoirs are less well documented. Reservoir architecture and multiscale heterogeneity in turbidites represent serious challenges to production performance. Additionally, establishing a hierarchy profile to delineate heterogeneity is a challenging task in lacustrine turbidite deposits. Here, we report on the turbidites in the middle third member of the Eocene Shahejie Formation (Es3), which was deposited during extensive Middle to Late Eocene rifting in the Dongying Depression. Seismic records, wireline log responses, and core observations were integrated to describe the reservoir heterogeneity by delineating the architectural elements, sequence stratigraphic framework and lithofacies assemblage. A petrographic approach was adopted to constrain microscopic heterogeneity using an optical microscope, routine core analyses and X-ray diffraction (XRD) analyses. The Es3m member is interpreted as a sequence set composed of four composite sequences: CS1, CS2, CS3 and CS4. A total of forty-five sequences were identified within these four composite sequences. Sand bodies were mainly deposited as channels, levees, overbank splays, lobes and lobe fringes. The combination of fining-upward and coarsening-upward lithofacies patterns in the architectural elements produces highly complex composite flow units. Microscopic heterogeneity is produced by diagenetic alteration processes (i.e., feldspar dissolution, authigenic clay formation and quartz cementation). The widespread kaolinization of feldspar and mobilization of materials enhanced the quality of the reservoir by producing secondary enlarged pores. In contrast, the formation of pore-filling authigenic illite and illite/smectite clays reduced its permeability. Recovery rates are higher in the axial areas and smaller in the marginal areas of architectural elements. This study represents a significant insight into the reservoir architecture and

  17. Evaluation of Aguas Dulces Black sands reserves, Rocha, Uruguay

    International Nuclear Information System (INIS)

    Ferrando, L.; Bossi, J.; Maldonado, S.; Schipilov; Campal, N.

    2003-01-01

    Black sands data in Aguas Dulces (Rocha) studied by ANCAP during 60 were reanalyzed with geological criterion in order to redefine the prefactibility of economic explotation with the present infrastructure and world market conditions.The sand deposits is limited between a high slope palaeocost and the ocean, with medium depth of 10m and 2% of useful minerals:ilmenite, rutile, monazite and zircon.Mineral reserves expressed in thousands of tons are of 3 kinds:proved (3.600), probable (5.500) and possible (16.000=.Demonstrated reserves (proved + probable) allow to estimate a value of U$S 650 million, taking in account year 2000 prices. A factory to process about 7 millions ton of raw sand needs an investment of U$S 13 million and will produce a sale of U$S 8 million per year

  18. Elasticity of Moulding Sands – a Method of Reducing Core Cracking

    Directory of Open Access Journals (Sweden)

    Dobosz St. M.

    2017-03-01

    Full Text Available This paper focuses on mechanical properties of self hardening moulding sands with furfuryl and alkyd binders. Elasticity as a new parameter of moulding sands is investigated. With the use of presented testing equipment, it is possible to determine force kinetics and deformation of moulding sand in real time. The need for this kind of study comes from the modern casting industry. New foundries can be characterized with high intensity of production which is correlated with high level of mechanization and automatization of foundry processes. The increasingly common use of manipulators in production of moulds and cores can lead to generation of new types of flaws, caused by breakage in moulds and cores which could occur during mould assembly. Hence it is required that moulds and cores have high resistance to those kinds of factors, attributing it with the phenomenon of elasticity. The article describes the theoretical basis of this property, presents methods of measuring and continues earlier research.

  19. Studies on the sand fly fauna (Diptera: Psychodidae) in high-transmission areas of cutaneous leishmaniasis in the Republic of Suriname

    Science.gov (United States)

    2013-01-01

    Background Sand flies (Diptera: Psychodidae) are the vectors of Leishmania parasites, the causative agents of leishmaniasis. Cutaneous leishmaniasis is an increasing public health problem in the Republic of Suriname and is mainly caused by Leishmania (Vianna) guyanensis, but L. (V.) braziliensis, L. (L.) amazonensis, and L. (V.) naiffi also infect humans. Transmission occurs predominantly in the forested hinterland of the country. Information regarding the potential vectors of leishmaniasis in Suriname is limited. This study aims to broaden the knowledge about vectors involved in the transmission of cutaneous leishmaniasis in Suriname. For this purpose, sand flies were characterized in various foci of cutaneous leishmaniasis in the country, the districts of Para, Brokopondo, and Sipaliwini. Methods Sand flies were collected in areas around mining plots and villages using CDC light traps in the period between February 2011 and March 2013. They were categorized by examination of the spermathecea (females) and the external genitalia (males). Results A total of 2,743 sand fly specimens belonging to 34 different species were captured, including four species (Lutzomyia aragaoi, Lu. ayrozai, Lu. damascenoi, and Lu. sordellii) that had never before been described for Suriname. Five percent of the catch comprised Lu. squamiventris sensu lato, one female of which was positive with L. (V.) braziliensis and was captured in a gold mining area in Brokopondo. Other sand fly species found positive for Leishmania parasites were Lu. trichopyga, Lu. ininii, and Lu. umbratilis, comprising 32, 8, and 4%, respectively, of the catch. These were captured at gold mining areas in Brokopondo and Sipaliwini, but the Leishmania parasites they had ingested could not be identified due to insufficient amounts of DNA. Conclusions The sand fly fauna in Suriname is highly diverse and comprises Lutzomyia species capable of transmitting Leishmania parasites. Four new Lutzomyia species have been found

  20. Production and global transport of Titan's sand particles

    Science.gov (United States)

    Barnes, Jason W.; Lorenz, Ralph D.; Radebaugh, Jani; Hayes, Alexander G.; Arnold, Karl; Chandler, Clayton

    2015-06-01

    Previous authors have suggested that Titan's individual sand particles form by either sintering or by lithification and erosion. We suggest two new mechanisms for the production of Titan's organic sand particles that would occur within bodies of liquid: flocculation and evaporitic precipitation. Such production mechanisms would suggest discrete sand sources in dry lakebeds. We search for such sources, but find no convincing candidates with the present Cassini Visual and Infrared Mapping Spectrometer coverage. As a result we propose that Titan's equatorial dunes may represent a single, global sand sea with west-to-east transport providing sources and sinks for sand in each interconnected basin. The sand might then be transported around Xanadu by fast-moving Barchan dune chains and/or fluvial transport in transient riverbeds. A river at the Xanadu/Shangri-La border could explain the sharp edge of the sand sea there, much like the Kuiseb River stops the Namib Sand Sea in southwest Africa on Earth. Future missions could use the composition of Titan's sands to constrain the global hydrocarbon cycle.

  1. Clogging in permeable concrete: A review.

    Science.gov (United States)

    Kia, Alalea; Wong, Hong S; Cheeseman, Christopher R

    2017-05-15

    Permeable concrete (or "pervious concrete" in North America) is used to reduce local flooding in urban areas and is an important sustainable urban drainage system. However, permeable concrete exhibits reduction in permeability due to clogging by particulates, which severely limits service life. This paper reviews the clogging mechanism and current mitigating strategies in order to inform future research needs. The pore structure of permeable concrete and characteristics of flowing particulates influence clogging, which occurs when particles build-up and block connected porosity. Permeable concrete requires regular maintenance by vacuum sweeping and pressure washing, but the effectiveness and viability of these methods is questionable. The potential for clogging is related to the tortuosity of the connected porosity, with greater tortuosity resulting in increased potential for clogging. Research is required to develop permeable concrete that can be poured on-site, which produces a pore structure with significantly reduced tortuosity. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Effect of Natural Sand Percentages on Fatigue Life of Asphalt Concrete Mixture

    Directory of Open Access Journals (Sweden)

    Nahla Yassub Ahmed

    2016-03-01

    Full Text Available The design of a flexible pavement requires the knowledge of the material properties which are characterized by stiffness and fatigue resistance. The fatigue resistance relates the number of load cycles to failure with the strain level applied to the asphalt mixture. The main objective of this research is the evaluation of the fatigue life of asphalt mixtures by using two types of fine aggregate having different percentages. In this study, two types of fine aggregate were used natural sand (desert sand and crushed sand. The crushed sand was replaced by natural sand (desert sand with different percentages (0%, 25%, 75% and 100% by the weight of the sand (passing sieve No.8 and retained on sieve No.200 and one type of binder (40/50 penetration from Al-Daurah refinery. The samples of beams were tested by four point bending beam fatigue test at the control strain mode (250, 500 and 750 microstrain while the loading frequency (5Hz and testing temperature (20oC according to (AASHTO T321. The experimental work showed that fatigue life (Nf and initial flexural stiffness increased when control strain decreased for asphalt mixtures. Acceptable fatigue life at 750 microstrain was obtained with asphalt concrete mixtures containing 100% crushed sand as well as asphalt concrete contained 25% natural sand. The asphalt concrete contained 100% and 75% of natural sand exhibited high fatigue life at low level of microstrain (250. The main conclusion of this study found that best proportion of natural sand to be added to an asphaltic concrete mixture is falling within the range (0% and 25% by weight of fraction (passing No.8 and retained on No.200 sieve .

  3. Enhancing the intestinal membrane permeability of zanamivir: a carrier mediated prodrug approach.

    Science.gov (United States)

    Gupta, Sheeba Varghese; Gupta, Deepak; Sun, Jing; Dahan, Arik; Tsume, Yasuhiro; Hilfinger, John; Lee, Kyung-Dall; Amidon, Gordon L

    2011-12-05

    The purpose of this study was to improve the membrane permeability and oral absorption of the poorly permeable anti-influenza agent, zanamivir. The poor oral bioavailability is attributed to the high polarity (cLogP ∼ -5) resulting from the polar and zwitterionic nature of zanamivir. In order to improve the permeability of zanamivir, prodrugs with amino acids were developed to target the intestinal membrane transporter, hPepT1. Several acyloxy ester prodrugs of zanamivir conjugated with amino acids were synthesized and characterized. The prodrugs were evaluated for their chemical stability in buffers at various pHs and for their transport and tissue activation by enzymes. The acyloxy ester prodrugs of zanamivir were shown to competitively inhibit [(3)H]Gly-Sar uptake in Caco-2 cells (IC(50): 1.19 ± 0.33 mM for L-valyl prodrug of zanamivir). The L-valyl prodrug of zanamivir exhibited ∼3-fold higher uptake in transfected HeLa/hPepT1 cells compared to wild type HeLa cells, suggesting, at least in part, carrier mediated transport by the hPepT1 transporter. Further, enhanced transcellular permeability of prodrugs across Caco-2 monolayer compared to the parent drug (P(app) = 2.24 × 10(-6) ± 1.33 × 10(-7) cm/s for L-valyl prodrug of zanamivir), with only parent zanamivir appearing in the receiver compartment, indicates that the prodrugs exhibited both enhanced transport and activation in intestinal mucosal cells. Most significantly, several of these prodrugs exhibited high intestinal jejunal membrane permeability, similar to metoprolol, in the in situ rat intestinal perfusion system, a system highly correlated with human jejunal permeability. In summary, this mechanistic targeted prodrug strategy, to enhance oral absorption via intestinal membrane carriers such as hPepT1, followed by activation to parent drug (active pharmaceutical ingredient or API) in the mucosal cell, significantly improves the intestinal epithelial cell permeability of zanamivir and has the

  4. Influence of Fracture Width on Sealability in High-Strength and Ultra-Low-Permeability Concrete in Seawater

    OpenAIRE

    Fukuda, Daisuke; Nara, Yoshitaka; Hayashi, Daisuke; Ogawa, Hideo; Kaneko, Katsuhiko

    2013-01-01

    For cementitious composites and materials, the sealing of fractures can occur in water by the precipitation of calcium compounds. In this study, the sealing behavior in a macro-fractured high-strength and ultra-low-permeability concrete (HSULPC) specimen was investigated in simulated seawater using micro-focus X-ray computed tomography (CT). In particular, the influence of fracture width (0.10 and 0.25 mm) on fracture sealing was investigated. Precipitation occurred mainly at the outermost pa...

  5. Frac Sand Mines Are Preferentially Sited in Unzoned Rural Areas.

    Science.gov (United States)

    Locke, Christina

    2015-01-01

    Shifting markets can cause unexpected, stochastic changes in rural landscapes that may take local communities by surprise. Preferential siting of new industrial facilities in poor areas or in areas with few regulatory restrictions can have implications for environmental sustainability, human health, and social justice. This study focuses on frac sand mining-the mining of high-quality silica sand used in hydraulic fracturing processes for gas and oil extraction. Frac sand mining gained prominence in the 2000s in the upper midwestern United States where nonmetallic mining is regulated primarily by local zoning. I asked whether frac sand mines were more commonly sited in rural townships without formal zoning regulations or planning processes than in those that undertook zoning and planning before the frac sand boom. I also asked if mine prevalence was correlated with socioeconomic differences across townships. After creating a probability surface to map areas most suitable for frac sand mine occurrence, I developed neutral landscape models from which to compare actual mine distributions in zoned and unzoned areas at three different spatial extents. Mines were significantly clustered in unzoned jurisdictions at the statewide level and in 7 of the 8 counties with at least three frac sand mines and some unzoned land. Subsequent regression analyses showed mine prevalence to be uncorrelated with land value, tax rate, or per capita income, but correlated with remoteness and zoning. The predicted mine count in unzoned townships was over two times higher than that in zoned townships. However, the county with the most mines by far was under a county zoning ordinance, perhaps indicating industry preferences for locations with clear, homogenous rules over patchwork regulation. Rural communities can use the case of frac sand mining as motivation to discuss and plan for sudden land-use predicaments, rather than wait to grapple with unfamiliar legal processes during a period of

  6. Sand to Root Transfer of PAHs and PCBs by Carrots Grown on Sand with Pure Substances and Biosolids Amended Sand

    OpenAIRE

    Sablayrolles, Caroline; Montréjaud-Vignoles, Mireille; Silvestre, Jérôme; Patria, Lucie

    2006-01-01

    A study on behaviour of trace organic compounds (Polycyclic Aromatic Hydrocarbons, PAH, and Polychlorinated Biphenyls, PCB) in a sand-plant system has been carried out, with the reclamation of wastewater treatment plant biosolids for agriculture in mind. Carrot plants (Daucus carota) were grown on soilless culture (sand), to provide optimal transfer conditions, in plant containers inside a temperature regulated greenhouse. There were two types of experiment. The trace organic compounds have i...

  7. The Effect of Excipients on the Permeability of BCS Class III Compounds and Implications for Biowaivers.

    Science.gov (United States)

    Parr, Alan; Hidalgo, Ismael J; Bode, Chris; Brown, William; Yazdanian, Mehran; Gonzalez, Mario A; Sagawa, Kazuko; Miller, Kevin; Jiang, Wenlei; Stippler, Erika S

    2016-01-01

    Currently, the FDA allows biowaivers for Class I (high solubility and high permeability) and Class III (high solubility and low permeability) compounds of the Biopharmaceutics Classification System (BCS). Scientific evidence should be provided to support biowaivers for BCS Class I and Class III (high solubility and low permeability) compounds. Data on the effects of excipients on drug permeability are needed to demonstrate that commonly used excipients do not affect the permeability of BCS Class III compounds, which would support the application of biowaivers to Class III compounds. This study was designed to generate such data by assessing the permeability of four BCS Class III compounds and one Class I compound in the presence and absence of five commonly used excipients. The permeability of each of the compounds was assessed, at three to five concentrations, with each excipient in two different models: Caco-2 cell monolayers, and in situ rat intestinal perfusion. No substantial increases in the permeability of any of the compounds were observed in the presence of any of the tested excipients in either of the models, with the exception of disruption of Caco-2 cell monolayer integrity by sodium lauryl sulfate at 0.1 mg/ml and higher. The results suggest that the absorption of these four BCS Class III compounds would not be greatly affected by the tested excipients. This may have implications in supporting biowaivers for BCS Class III compounds in general.

  8. Geothermal Permeability Enhancement - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Joe Beall; Mark Walters

    2009-06-30

    The overall objective is to apply known permeability enhancement techniques to reduce the number of wells needed and demonstrate the applicability of the techniques to other undeveloped or under-developed fields. The Enhanced Geothermal System (EGS) concept presented in this project enhances energy extraction from reduced permeability zones in the super-heated, vapor-dominated Aidlin Field of the The Geysers geothermal reservoir. Numerous geothermal reservoirs worldwide, over a wide temperature range, contain zones of low permeability which limit the development potential and the efficient recovery of heat from these reservoirs. Low permeability results from poorly connected fractures or the lack of fractures. The Enhanced Geothermal System concept presented here expands these technologies by applying and evaluating them in a systematic, integrated program.

  9. Permeability of protective coatings to tritium

    International Nuclear Information System (INIS)

    Braun, J.M.

    1987-10-01

    The permeability of four protective coatings to tritium gas and tritiated water was investigated. The coatings, including two epoxies, one vinyl and one urethane, were selected for their suitability in CANDU plant service in Ontario Hydro. Sorption rates of tritium gas into the coatings were considerably larger than for tritiated water, by as much as three to four orders of magnitude. However, as a result of the very large solubility of tritiated water in the coatings, the overall permeability to tritium gas and tritiated water are comparable, being somewhat larger for HTO. Marked differences were also evident among the four coatings, the vinyl proving to be unique in behaviour and morphology. Because of a highly porous surface structure water condensation takes place at high relative humidities, leading to an abnormally high retention of free water. Desorption rates from the four coatings were otherwise quite similar. Of practical importance was the observation that more effective desorption of tritiated water could be carried out at relatively high humidities, in this case 60%. It was believed that isotopic exchange was responsible for this phenomenon. It appears that epoxy coatings having a high pigment-to-binder ratio are most suited for coating concrete in tritium handling facilities

  10. High-permeability region size on perfusion CT predicts hemorrhagic transformation after intravenous thrombolysis in stroke.

    Directory of Open Access Journals (Sweden)

    Josep Puig

    Full Text Available Blood-brain barrier (BBB permeability has been proposed as a predictor of hemorrhagic transformation (HT after tissue plasminogen activator (tPA administration; however, the reliability of perfusion computed tomography (PCT permeability imaging for predicting HT is uncertain. We aimed to determine the performance of high-permeability region size on PCT (HPrs-PCT in predicting HT after intravenous tPA administration in patients with acute stroke.We performed a multimodal CT protocol (non-contrast CT, PCT, CT angiography to prospectively study patients with middle cerebral artery occlusion treated with tPA within 4.5 hours of symptom onset. HT was graded at 24 hours using the European-Australasian Acute Stroke Study II criteria. ROC curves selected optimal volume threshold, and multivariate logistic regression analysis identified predictors of HT.The study included 156 patients (50% male, median age 75.5 years. Thirty-seven (23,7% developed HT [12 (7,7%, parenchymal hematoma type 2 (PH-2]. At admission, patients with HT had lower platelet values, higher NIHSS scores, increased ischemic lesion volumes, larger HPrs-PCT, and poorer collateral status. The negative predictive value of HPrs-PCT at a threshold of 7mL/100g/min was 0.84 for HT and 0.93 for PH-2. The multiple regression analysis selected HPrs-PCT at 7mL/100g/min combined with platelets and baseline NIHSS score as the best model for predicting HT (AUC 0.77. HPrs-PCT at 7mL/100g/min was the only independent predictor of PH-2 (OR 1, AUC 0.68, p = 0.045.HPrs-PCT can help predict HT after tPA, and is particularly useful in identifying patients at low risk of developing HT.

  11. High-permeability region size on perfusion CT predicts hemorrhagic transformation after intravenous thrombolysis in stroke

    Science.gov (United States)

    Puig, Josep; Blasco, Gerard; Daunis-i-Estadella, Pepus; van Eendendburg, Cecile; Carrillo-García, María; Aboud, Carlos; Hernández-Pérez, María; Serena, Joaquín; Biarnés, Carles; Nael, Kambiz; Liebeskind, David S.; Thomalla, Götz; Menon, Bijoy K.; Demchuk, Andrew; Wintermark, Max; Pedraza, Salvador

    2017-01-01

    Objective Blood-brain barrier (BBB) permeability has been proposed as a predictor of hemorrhagic transformation (HT) after tissue plasminogen activator (tPA) administration; however, the reliability of perfusion computed tomography (PCT) permeability imaging for predicting HT is uncertain. We aimed to determine the performance of high-permeability region size on PCT (HPrs-PCT) in predicting HT after intravenous tPA administration in patients with acute stroke. Methods We performed a multimodal CT protocol (non-contrast CT, PCT, CT angiography) to prospectively study patients with middle cerebral artery occlusion treated with tPA within 4.5 hours of symptom onset. HT was graded at 24 hours using the European-Australasian Acute Stroke Study II criteria. ROC curves selected optimal volume threshold, and multivariate logistic regression analysis identified predictors of HT. Results The study included 156 patients (50% male, median age 75.5 years). Thirty-seven (23,7%) developed HT [12 (7,7%), parenchymal hematoma type 2 (PH-2)]. At admission, patients with HT had lower platelet values, higher NIHSS scores, increased ischemic lesion volumes, larger HPrs-PCT, and poorer collateral status. The negative predictive value of HPrs-PCT at a threshold of 7mL/100g/min was 0.84 for HT and 0.93 for PH-2. The multiple regression analysis selected HPrs-PCT at 7mL/100g/min combined with platelets and baseline NIHSS score as the best model for predicting HT (AUC 0.77). HPrs-PCT at 7mL/100g/min was the only independent predictor of PH-2 (OR 1, AUC 0.68, p = 0.045). Conclusions HPrs-PCT can help predict HT after tPA, and is particularly useful in identifying patients at low risk of developing HT. PMID:29182658

  12. A Reconciliation of Packed Column Permeability Data: Column Permeability as a Function of Particle Porosity

    Directory of Open Access Journals (Sweden)

    Hubert M. Quinn

    2014-01-01

    Full Text Available In his textbook teaching of packed bed permeability, Georges Guiochon uses mobile phase velocity as the fluid velocity term in his elaboration of the Darcy permeability equation. Although this velocity frame makes a lot of sense from a thermodynamic point of view, it is valid only with respect to permeability at a single theoretical boundary condition. In his more recent writings, however, Guiochon has departed from his long-standing mode of discussing permeability in terms of the Darcy equation and has embraced the well-known Kozeny-Blake equation. In this paper, his teaching pertaining to the constant in the Kozeny-Blake equation is examined and, as a result, a new correlation coefficient is identified and defined herein based on the velocity frame used in his teaching. This coefficient correlates pressure drop and fluid velocity as a function of particle porosity. We show that in their experimental protocols, Guiochon et al. have not adhered to a strict material balance of permeability which creates a mismatch of particle porosity and leads to erroneous conclusions regarding the value of the permeability coefficient in the Kozeny-Blake equation. By correcting the experimental data to properly reflect particle porosity we reconcile the experimental results of Guiochon and Giddings, resulting in a permeability reference chart which is presented here for the first time. This reference chart demonstrates that Guiochon’s experimental data, when properly normalized for particle porosity and other related discrepancies, corroborates the value of 267 for the constant in the Kozeny-Blake equation which was derived by Giddings in 1965.

  13. Crustal permeability: Introduction to the special issue

    Science.gov (United States)

    Ingebritsen, Steven E.; Gleeson, Tom

    2015-01-01

    The topic of crustal permeability is of broad interest in light of the controlling effect of permeability on diverse geologic processes and also timely in light of the practical challenges associated with emerging technologies such as hydraulic fracturing for oil and gas production (‘fracking’), enhanced geothermal systems, and geologic carbon sequestration. This special issue of Geofluids is also motivated by the historical dichotomy between the hydrogeologic concept of permeability as a static material property that exerts control on fluid flow and the perspective of economic geologists, geophysicists, and crustal petrologists who have long recognized permeability as a dynamic parameter that changes in response to tectonism, fluid production, and geochemical reactions. Issues associated with fracking, enhanced geothermal systems, and geologic carbon sequestration have already begun to promote a constructive dialog between the static and dynamic views of permeability, and here we have made a conscious effort to include both viewpoints. This special issue also focuses on the quantification of permeability, encompassing both direct measurement of permeability in the uppermost crust and inferential permeability estimates, mainly for the deeper crust.

  14. An Experimental Study of Micron-Size Zero-Valent Iron Emplacement in Permeable Porous Media Using Polymer-Enhanced Fluids

    Energy Technology Data Exchange (ETDEWEB)

    Oostrom, Mart; Wietsma, Thomas W.; Covert, Matthew A.; Vermeul, Vince R.

    2005-12-22

    At the Hanford Site, an extensive In Situ Redox Manipulation (ISRM) permeable reactive barrier was installed to prevent chromate from reaching the Columbia River. However, chromium has been detected in several wells, indicating a premature loss of the reductive capacity in the aquifer. One possible cause for premature chromate breakthrough is associated with the presence of high-permeability zones in the aquifer. In these zones, groundwater moves relatively fast and is able to oxidize iron more rapidly. There is also a possibility that the high-permeability flow paths are deficient in reducing equivalents (e.g. reactive iron), required for barrier performance. One way enhancement of the current barrier reductive capacity can be achieved is by the addition of micron-scale zero-valent iron to the high-permeability zones within the aquifer. The potential emplacement of zero-valent iron (Fe0) into high-permeability Hanford sediments (Ringold Unit E gravels) using shear-thinning fluids containing polymers was investigated in three-dimensional wedge-shaped aquifer models. Polymers were used to create a suspension viscous enough to keep the Fe0 in solution for extended time periods to improve colloid movement into the porous media without causing a permanent detrimental decrease in hydraulic conductivity. Porous media were packed in the wedge-shaped flow cell to create either a heterogeneous layered system with a high-permeability zone in between two low-permeability zones or a high-permeability channel surrounded by low-permeability materials. The injection flow rate, polymer type, polymer concentration, and injected pore volumes were determined based on preliminary short- and long-column experiments.

  15. The complexity of intestinal permeability: Assigning the correct BCS classification through careful data interpretation.

    Science.gov (United States)

    Zur, Moran; Hanson, Allison S; Dahan, Arik

    2014-09-30

    While the solubility parameter is fairly straightforward when assigning BCS classification, the intestinal permeability (Peff) is more complex than generally recognized. In this paper we emphasize this complexity through the analysis of codeine, a commonly used antitussive/analgesic drug. Codeine was previously classified as a low-permeability compound, based on its lower LogP compared to metoprolol, a marker for the low-high permeability class boundary. In contrast, high fraction of dose absorbed (Fabs) was reported for codeine, which challenges the generally recognized Peff-Fabs correlation. The purpose of this study was to clarify this ambiguity through elucidation of codeine's BCS solubility/permeability class membership. Codeine's BCS solubility class was determined, and its intestinal permeability throughout the small intestine was investigated, both in vitro and in vivo in rats. Codeine was found to be unequivocally a high-solubility compound. All in vitro studies indicated that codeine's permeability is higher than metoprolol's. In vivo studies in rats showed similar permeability for both drugs throughout the entire small-intestine. In conclusion, codeine was found to be a BCS Class I compound. No Peff-Fabs discrepancy is involved in its absorption; rather, it reflects the risk of assigning BCS classification based on merely limited physicochemical characteristics. A thorough investigation using multiple experimental methods is prudent before assigning a BCS classification, to avoid misjudgment in various settings, e.g., drug discovery, formulation design, drug development and regulation. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Wear and microstructural characteristics of spray atomized zircon sand reinforced LM13 alloy

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, K.; Pandey, O.P. [School of Physics and Materials Science, Thapar University Patiala, Punjab (India)

    2010-07-15

    The requirement of the high performance light weight materials demands the development of varieties of materials within the economical range to get it commercialized. Light weight aluminium alloys are used in several structural applications like automotive, aerospace, defense industry and other fields of engineering. The ceramic particle reinforced aluminium metal matrix composites (AMCs) have emerged as a suitable candidate for commercial applications. A variety of processing routes have been adopted to manufacture AMCs. In the present work LM13 alloy reinforced with zircon sand is formed via spray forming. During experimentation a self prepared convergent-divergent nozzle is used for inert gas atomization of the melt which is subsequently deposited on copper substrate placed vertically below the atomizer. The zircon sand particles are injected in the atomization zone by external injectors aligned perpendicular to the gas atomization axis. Zircon sand has been found to have new promising economical commercial candidate due to its easy availability and good mechanical properties like high hardness, high modulus of elasticity and good thermal stability. The microhardness of cast alloy and spray formed composite shows that the spray formed zircon sand reinforced composite has higher hardness. Also the lower wear rate has been observed in case of the zircon sand reinforced AMC as compared to LM13 alloy. This behaviour is further analyzed in light of microstructural features of the spray deposited composite using optical and scanning electron microscope (SEM). A comparative study of this material (LM13/Zircon sand) with the parent alloy (LM13) is presented in this work. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  17. Microfluidic passive permeability assay using nanoliter droplet interface lipid bilayers.

    Science.gov (United States)

    Nisisako, Takasi; Portonovo, Shiva A; Schmidt, Jacob J

    2013-11-21

    Membrane permeability assays play an important role in assessing drug transport activities across biological membranes. However, in conventional parallel artificial membrane permeability assays (PAMPA), the membrane model used is dissimilar to biological membranes physically and chemically. Here, we describe a microfluidic passive permeability assay using droplet interface bilayers (DIBs). In a microfluidic network, nanoliter-sized donor and acceptor aqueous droplets are alternately formed in cross-flowing oil containing phospholipids. Subsequently, selective removal of oil through hydrophobic pseudo-porous sidewalls induces the contact of the lipid monolayers, creating arrayed planar DIBs between the donor and acceptor droplets. Permeation of fluorescein from the donor to the acceptor droplets was fluorometrically measured. From the measured data and a simple diffusion model we calculated the effective permeabilities of 5.1 × 10(-6) cm s(-1), 60.0 × 10(-6) cm s(-1), and 87.6 × 10(-6) cm s(-1) with donor droplets at pH values of 7.5, 6.4 and 5.4, respectively. The intrinsic permeabilities of specific monoanionic and neutral fluorescein species were obtained similarly. We also measured the permeation of caffeine in 10 min using UV microspectroscopy, obtaining a permeability of 20.8 × 10(-6) cm s(-1). With the small solution volumes, short measurement time, and ability to measure a wide range of compounds, this device has considerable potential as a platform for high-throughput drug permeability assays.

  18. Analysis of wind-blown sand movement over transverse dunes.

    Science.gov (United States)

    Jiang, Hong; Huang, Ning; Zhu, Yuanjian

    2014-12-01

    Wind-blown sand movement often occurs in a very complicated desert environment where sand dunes and ripples are the basic forms. However, most current studies on the theoretic and numerical models of wind-blown sand movement only consider ideal conditions such as steady wind velocity, flat sand surface, etc. In fact, the windward slope gradient plays a great role in the lift-off and sand particle saltation. In this paper, we propose a numerical model for the coupling effect between wind flow and saltating sand particles to simulate wind-blown sand movement over the slope surface and use the SIMPLE algorithm to calculate wind flow and simulate sands transport by tracking sand particle trajectories. We furthermore compare the result of numerical simulation with wind tunnel experiments. These results prove that sand particles have obvious effect on wind flow, especially that over the leeward slope. This study is a preliminary study on windblown sand movement in a complex terrain, and is of significance in the control of dust storms and land desertification.

  19. Recovering byproduct heavy minerals from sand and gravel, placer gold, and industrial mineral operations

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, J.M.; Martinez, G.M.; Wong, M.M.

    1979-01-01

    The Bureau of Mines, as part of an effort to maximize minerals and metals recovery from domestic resources, has investigated the feasibility of recovering heavy minerals as byproducts from sand and gravel, placer gold, and industrial mineral operations in northern California. Sand samples from about 50 locations were treated by gravity separation to yield heavy-mineral cocentrates (black sands). Mineral compositions of the concentrates were determined by chemical analysis and mineralogical examination. Individual zircon, ilmenite, magnetite, platinum-group metals, thoria, and silica products were prepared from heavy-mineral concentrates by selective separation using low- and high-intensity magnetic, high-tension, and flotation equipment.

  20. Sand consolidation

    Energy Technology Data Exchange (ETDEWEB)

    Spain, H H

    1965-01-21

    In a sand consolidation method in which there is injected a mixture of resin-forming liquids comprising an aryl-hydroxy low molecular weight compound, a water- soluble aldehyde, and a catalyst, an improvement is claimed which comprises diluting the resin-forming liquids with a diluent and with water so that the yield of the resin is sufficient to consolidate the sand particles with the minimum desirable pressure. The diluent may be mutually soluble in water and in the resin-forming liquids, and does not affect the setting time of the polymer. The aldehyde and the aryl-hydroxy compound may be in ratio of 5:1, and the diluent, methyl alcohol, is present in a ratio of 2:1 with reference to the water.

  1. Effect of temperature on sandstone permeability

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Kjøller, Claus

    Hot water injection in geothermal sandstone aquifers is considered for seasonal energy storage in Denmark. However, an increase in the aquifer temperature might reduce permeability, and thereby increase production costs. An understanding of the factors that control permeability is required in order...... and the Klinkenberg procedure showed the expected correlation between the two measures, however, differences could be around one order of magnitude. In tight gas sandstones, permeability is often sensitive to net stress, which might change due to the pore pressure change in the Klinkenberg procedure. Besides...... affecting the Klinkenberg procedure, the combined effect of slip and changes in permeability would affect production during pressure depletion in tight gas sandstone reservoirs; therefore effects of gas slip and net stress on permeability were combined in a model based on the Klinkenberg equation. A lower...

  2. Sands at Gusev Crater, Mars

    Science.gov (United States)

    Cabrol, Nathalie A.; Herkenhoff, Kenneth E.; Knoll, Andrew H.; Farmer, Jack D.; Arvidson, Raymond E.; Grin, E.A.; Li, Ron; Fenton, Lori; Cohen, B.; Bell, J.F.; Yingst, R. Aileen

    2014-01-01

    Processes, environments, and the energy associated with the transport and deposition of sand at Gusev Crater are characterized at the microscopic scale through the comparison of statistical moments for particle size and shape distributions. Bivariate and factor analyses define distinct textural groups at 51 sites along the traverse completed by the Spirit rover as it crossed the plains and went into the Columbia Hills. Fine-to-medium sand is ubiquitous in ripples and wind drifts. Most distributions show excess fine material, consistent with a predominance of wind erosion over the last 3.8 billion years. Negative skewness at West Valley is explained by the removal of fine sand during active erosion, or alternatively, by excess accumulation of coarse sand from a local source. The coarse to very coarse sand particles of ripple armors in the basaltic plains have a unique combination of size and shape. Their distribution display significant changes in their statistical moments within the ~400 m that separate the Columbia Memorial Station from Bonneville Crater. Results are consistent with aeolian and/or impact deposition, while the elongated and rounded shape of the grains forming the ripples, as well as their direction of origin, could point to Ma'adim Vallis as a possible source. For smaller particles on the traverse, our findings confirm that aeolian processes have dominated over impact and other processes to produce sands with the observed size and shape patterns across a spectrum of geologic (e.g., ripples and plains soils) and aerographic settings (e.g., wind shadows).

  3. Tritium Permeability of Incoloy 800H and Inconel 617

    Energy Technology Data Exchange (ETDEWEB)

    Philip Winston; Pattrick Calderoni; Paul Humrickhouse

    2012-07-01

    Design of the Next Generation Nuclear Plant (NGNP) reactor and its high-temperature components requires information regarding the permeation of fission generated tritium and hydrogen product through candidate heat exchanger alloys. Release of fission-generated tritium to the environment and the potential contamination of the helium coolant by permeation of product hydrogen into the coolant system represent safety basis and product contamination issues. Of the three potential candidates for high-temperature components of the NGNP reactor design, only permeability for Incoloy 800H has been well documented. Hydrogen permeability data have been published for Inconel 617, but only in two literature reports and for partial pressures of hydrogen greater than one atmosphere, far higher than anticipated in the NGNP reactor. To support engineering design of the NGNP reactor components, the tritium permeability of Inconel 617 and Incoloy 800H was determined using a measurement system designed and fabricated at Idaho National Laboratory. The tritium permeability of Incoloy 800H and Inconel 617, was measured in the temperature range 650 to 950°C and at primary concentrations of 1.5 to 6 parts per million volume tritium in helium. (partial pressures of 10-6 atm)—three orders of magnitude lower partial pressures than used in the hydrogen permeation testing. The measured tritium permeability of Incoloy 800H and Inconel 617 deviated substantially from the values measured for hydrogen. This may be due to instrument offset, system absorption, presence of competing quantities of hydrogen, surface oxides, or other phenomena. Due to the challenge of determining the chemical composition of a mixture with such a low hydrogen isotope concentration, no categorical explanation of this offset has been developed.

  4. Tritium Permeability of Incoloy 800H and Inconel 617

    Energy Technology Data Exchange (ETDEWEB)

    Philip Winston; Pattrick Calderoni; Paul Humrickhouse

    2011-09-01

    Design of the Next Generation Nuclear Plant (NGNP) reactor and its high-temperature components requires information regarding the permeation of fission generated tritium and hydrogen product through candidate heat exchanger alloys. Release of fission-generated tritium to the environment and the potential contamination of the helium coolant by permeation of product hydrogen into the coolant system represent safety basis and product contamination issues. Of the three potential candidates for high-temperature components of the NGNP reactor design, only permeability for Incoloy 800H has been well documented. Hydrogen permeability data have been published for Inconel 617, but only in two literature reports and for partial pressures of hydrogen greater than one atmosphere, far higher than anticipated in the NGNP reactor. To support engineering design of the NGNP reactor components, the tritium permeability of Inconel 617 and Incoloy 800H was determined using a measurement system designed and fabricated at Idaho National Laboratory. The tritium permeability of Incoloy 800H and Inconel 617, was measured in the temperature range 650 to 950 C and at primary concentrations of 1.5 to 6 parts per million volume tritium in helium. (partial pressures of 10-6 atm) - three orders of magnitude lower partial pressures than used in the hydrogen permeation testing. The measured tritium permeability of Incoloy 800H and Inconel 617 deviated substantially from the values measured for hydrogen. This may be due to instrument offset, system absorption, presence of competing quantities of hydrogen, surface oxides, or other phenomena. Due to the challenge of determining the chemical composition of a mixture with such a low hydrogen isotope concentration, no categorical explanation of this offset has been developed.

  5. Direct Chlorination of Zircon Sand

    International Nuclear Information System (INIS)

    Dwiretnani Sudjoko; Budi Sulistyo; Pristi Hartati; Sunardjo

    2002-01-01

    It was investigated the direct chlorination of zircon sand in a unit chlorination equipment. The process was in semi batch. The product gas was scrubbed in aqueous NaOH. It was search the influence of time, ratio of reactant and size of particle sand to the concentration of Zr and Si in the product. From these research it was found that as the times, ratio of reactant increased, the concentration of Zr increased, but the concentration of Si decreased, while as grain size of zircon sand decreased the concentration of Zr decreased, but the concentration of Si increased. (author)

  6. Permeability of commercial solvents through living human skin

    DEFF Research Database (Denmark)

    Ursin, C; Hansen, C M; Van Dyk, J W

    1995-01-01

    A procedure has been developed for measuring the steady state rate of permeation of commercial solvents through living human skin. To get the most consistent results, it was necessary with some solvents to normalize the solvent permeation rate of a given skin sample with its [3H]water permeation...... rate. For other solvents this was not necessary, so the un-normalized data were used. High [3H]water permeation rate also was used as a criterion for "defective" skin samples that gave erroneous permeability rates, especially for solvents having slow permeability. The linearity of the steady state data...... was characterized by calculation of the "percent error of the slope." The following permeability rates (g/m2h) of single solvents were measured: dimethyl sulfoxide (DMSO), 176; N-methyl-2-pyrrolidone, 171; dimethyl acetamide, 107; methyl ethyl ketone, 53; methylene chloride, 24; [3H]water, 14.8; ethanol, 11...

  7. Geomechanical properties of lime stabilized clayey sands

    International Nuclear Information System (INIS)

    Arabani, M.; Karami, M. Veis

    2007-01-01

    Clayey sands that have low plasticity, low compressibility and high strength under loads, are suitable as a base material for any engineering construction projects as well as for roads and building construction. Decrease of plasticity and compressibility as well as increase in strength of these materials can be obtained by many different methods. Of these methods, lime stabilization is a common, applicable, and easy to use approach that can improve geomechanical and geotechnical properties of clayey sand fills. In this study some important geomechanical properties and geotechnical properties of clayey sands including compressive strength, CBR and elastic plastic behavior are investigated. A range of gradations representative of those gradations found in situ in the north of Iran were selected for testing and samples were artificially rebuilt in the laboratory. The mixes were then stabilized with hydrated lime and cured. Different mechanical tests were performed on mature materials. The stress-strain behavior of lime-stabilized mixes was plotted and a parabolic function was used to estimate the trend of stress-strain behavior. The data show that there is a correlation among the results of uniaxial load test, tensile strength, and CBR of the tested specimens. Also, results of the unconfined compression test and the indirect tensile strength test show that an increase in clay content up to a certain percent, in the clay-sand fills, tends to increase the strength of the materials in compression as well as in tension. (author)

  8. Regulation of Aquaporin Z osmotic permeability in ABA tri-block copolymer

    Directory of Open Access Journals (Sweden)

    Wenyuan Xie

    2015-08-01

    Full Text Available Aquaporins are transmembrane water channel proteins present in biological plasma membranes that aid in biological water filtration processes by transporting water molecules through at high speeds, while selectively blocking out other kinds of solutes. Aquaporin Z incorporated biomimetic membranes are envisaged to overcome the problem of high pressure needed, and holds great potential for use in water purification processes, giving high flux while keeping energy consumption low. The functionality of aquaporin Z in terms of osmotic permeability might be regulated by factors such as pH, temperature, crosslinking and hydrophobic thickness of the reconstituted bilayers. Hence, we reconstituted aquaporin Z into vesicles that are made from a series of amphiphilic block copolymers PMOXA-PDMS-PMOXAs with various hydrophobic molecular weights. The osmotic permeability of aquaporin Z in these vesicles was determined through a stopped-flow spectroscopy. In addition, the temperature and pH value of the vesicle solutions were adjusted within wide ranges to investigate the regulation of osmotic permeability of aquaporin Z through external conditions. Our results show that aquaporin Z permeability was enhanced by hydrophobic mismatch. In addition, the water filtration mechanism of aquaporin Z is significantly affected by the concentration of H+ and OH- ions.

  9. Study on the application of permeable reactive barriers for remediation of uranium mine pit water

    International Nuclear Information System (INIS)

    Li Na'na; Zhu Yucheng

    2012-01-01

    Permeable reactive barrier (PRB) is economical and convenient on in suit remediation of polluted groundwater. In this paper, according to characteristics of uranium mine pit water, laboratory-scale PRB reactors were designed with the mixture of valent iron, active carbon, hydrated lime and quartz sands as reaction media. The feasibility and effectiveness of treating uranium mine pit water by PRB were tested under 3 different proportions of contaminants through dynamic simulation tests, which came out the optimal proportion of contaminants. The result indicated that the remediation effect of reactor B was the best, whose average removal rate to U was up to 99%. The quality of effluent attained the relevant standards, which indicated that the PRB technology is a feasible method for the treatment of uranium mine pit water. (authors)

  10. Final Oahe Dam/Lake Oahe Master Plan Missouri River, South Dakota and North Dakota

    Science.gov (United States)

    2010-09-01

    silty loams with moderate erosion and poor permeability. Normally used for pastureland. Sansarc- Opal : clays with minor erosion and permeability...One active sand and gravel mining area is located on Oahe project lands at Fort Yates, North Dakota. There is also a small amount of sand and...consist of sand and gravel deposits and Pierre Shale. The sand and gravel deposits are mined for road construction materials and concrete aggregate

  11. Parametric analysis of applicability of sand production control in oil wells; Analise parametrica da aplicabilidade do controle de producao de areia em pocos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Filipe S.B. da; Couto, Paulo [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Curso de Engenharia do Petroleo

    2008-07-01

    The present work discusses about the selection of the best sand control method to be adopted for offshore operations according to a specific technologic limitation and by demands imposed by the environment in which it is used. First of all, the paper mentions the phenomena of solids carrying. Then the source environments of the study are analyzed. This approach is considered important because it is the basis for understanding the final part of the research, composed of the method/environment correlation. Three fictitious offshore fields based on real data are presented. In each of them, two wells are studied, one cased, and one open holed. Parameters like permeability and UCS have the same conceptual relevance as the sand control methods presented. The analysis of methods follows those used for the environments. The following methods are presented: by restriction of solids flow, by drag strength reduction and by increase of cohesion strength. Emphasis is given on mechanic methods. Finally, this study concludes its initial purpose, which is selecting the best sand control method for each well, substantiating in each one, the reason for the choice. (author)

  12. Digital Rock Physics Aplications: Visualisation Complex Pore and Porosity-Permeability Estimations of the Porous Sandstone Reservoir

    Science.gov (United States)

    Handoyo; Fatkhan; Del, Fourier

    2018-03-01

    Reservoir rock containing oil and gas generally has high porosity and permeability. High porosity is expected to accommodate hydrocarbon fluid in large quantities and high permeability is associated with the rock’s ability to let hydrocarbon fluid flow optimally. Porosity and permeability measurement of a rock sample is usually performed in the laboratory. We estimate the porosity and permeability of sandstones digitally by using digital images from μCT-Scan. Advantages of the method are non-destructive and can be applied for small rock pieces also easily to construct the model. The porosity values are calculated by comparing the digital image of the pore volume to the total volume of the sandstones; while the permeability values are calculated using the Lattice Boltzmann calculations utilizing the nature of the law of conservation of mass and conservation of momentum of a particle. To determine variations of the porosity and permeability, the main sandstone samples with a dimension of 300 × 300 × 300 pixels are made into eight sub-cubes with a size of 150 × 150 × 150 pixels. Results of digital image modeling fluid flow velocity are visualized as normal velocity (streamline). Variations in value sandstone porosity vary between 0.30 to 0.38 and permeability variations in the range of 4000 mD to 6200 mD. The results of calculations show that the sandstone sample in this research is highly porous and permeable. The method combined with rock physics can be powerful tools for determining rock properties from small rock fragments.

  13. Thermal Conductivity of Polymer Composite poypropilene-Sand

    International Nuclear Information System (INIS)

    Betha; Mashuri; Sudirman; Karo Karo, Aloma

    2001-01-01

    Thermal conductivity composite materials polypropylene (PP)-sand have been investigated. PP composite with sand to increase thermal conductivity from the polymer. The composite in this observation is done by mixing matrix (PP melt flow 2/10)and filler sand)by means tool labo plastomil. The result of thermal conductivity is composite of PP-sand which is obtained increase and followed by the raising of filler particle volume fraction. The analysis of thermal conductivity based on the model Cheng and Vachon, model Lewis and Nielsen where this model has the function to support experiment finding. It is proved that Lewis' and Nielsen's model almost approach experiment result. And then thermal conductivity raising will be analyzed by the model of pararel-series conductive with the two (2)phases system. It is showed that sand in PP MF 2 composite have the big role to increase the thermal conductivity than sand in PP MF 10 composition, but it is not easy to shape conductive medium

  14. Evaluate of head loss, sediment value and copper removal in sand media (rapid sand filter

    Directory of Open Access Journals (Sweden)

    Daneshi Navab

    2014-06-01

    Full Text Available Along with the technology development and increasing consumption of water resources, we are experiencing low qualities in the mentioned resources. Copper brings about serious environment al pollution, threatening human health and ecosystem. This metal found variously in water resources and industrial activities. Therefore, it needs to treat the water resources from these excessive amounts. Different methods have used for this reason but the most used method during recent years has been the absorption by economic absorbers such as sand. Rapid sand filters usually used in water and wastewater treatment plants for water clarification. In this research, a single layer gravity rapid sand filter has used to reduce different concentrations of copper. sediment value and head loss arising in filter media is simulated by using combination of Carman-Kozeny, Rose and Gregory models in different discharges of rapid sand filter. Results have shown that with increasing in discharge and decreasing in input copper concentration, arriving time to given head loss, is increasing. In addition, results demonstrated that with increasing in copper concentration in influent, removal efficiency is decreasing somewhat. Results of this research can applied in an appropriate design of rapid sand filter to copper removal, a prediction of rapid sand filter ability to copper removal and an estimation of arising head loss during filter work thus evaluating of time interval backwash. DOI: http://dx.doi.org/10.3126/ije.v3i2.10641 International Journal of the Environment Vol.3(2 2014: 276-286

  15. Study on sand particles creep model and open pit mine landslide mechanism caused by sand fatigue liquefaction

    Science.gov (United States)

    Du, Dong-Ning; Wang, Lai-Gui; Zhang, Xiang-Dong; Zhang, Shu-Kun

    2017-06-01

    The sand particles in the sand - rock composite slope of the open pit mine occurs creep deformation and fatigue liquefaction under the action of vehicle load vibration and hydraulic gradient, which causes landslide geological disasters and it destroys the surface environment. To reveal the mechanism, a mechanics model based on the model considering the soil structural change with a new “plastic hinge” element is developed, to improve its constitutive and creep curve equations. Data from sand creep experiments are used to identify the parameters in the model and to validate the model. The results show that the mechanical model can describe the rotation progress between the sand particles, disclose the negative acceleration creep deformation stage during the third phase, and require fewer parameters while maintaining accuracy. It provides a new creep model considering rotation to analyze sand creep mechanism, which provides a theoretical basis for revealing the open pit mine landslide mechanism induced by creep deformation and fatigue liquefaction of sandy soil.

  16. Cemented Backfilling Technology of Paste-Like Based on Aeolian Sand and Tailings

    Directory of Open Access Journals (Sweden)

    Qinli Zhang

    2016-12-01

    Full Text Available Aeolian sand, tailings, and #32.5 Portland cement were used to produce backfilling aggregate, and physicochemical evaluations and proportioning tests were conducted. It is revealed that a mixture of aeolian sand and tailings can be used as a backfilling aggregate for the complementarities of their physicochemical properties; e.g., high Al2O3 content in the aeolian sand and CaO content in the tailings, coarse particles of aeolian sand and fine particles of tailings, etc. In addition, the optimal backfilling aggregate was shown to have a mass fraction of 72%–74%, a cement–sand ratio of 1:8, and an aeolian sand proportion of 25%. Furthermore, viscometer tests were used to analyze the rheological characteristics, and the slurry in these optimized proportions exhibited shear thinning phenomena with an initial yield stress, which belongs to paste-like—a cemented backfilling slurry with a higher mass fraction than a two-phase flow and better flowability than a paste slurry. Finally, the application of this backfilling technology shows that it can not only realize safe mining, but also bring huge economic benefits, and has some constructive guidance for environmental protection.

  17. Water and nonelectrolyte permeability of isolated rat hepatocytes

    International Nuclear Information System (INIS)

    Alpini, G.; Garrick, R.A.; Jones, M.J.; Nunes, R.; Tavoloni, N.

    1986-01-01

    We have measured the diffusive permeability coefficients of isolated rat hepatocytes to 3 H 2 O, [ 14 C]urea, [ 14 C]erythritol, [ 14 C]mannitol, [ 3 H]sucrose, and [ 3 H]inulin, employing a technique previously developed for erythrocytes (Redwood et al., J. Gen. Physiol 64:706-729, 1974). Diffusion coefficients for the tracer molecules were measured in packed hepatocytes, supernatant fluid, and intracellular medium (lysed hepatocytes) and were calculated assuming one-dimensional semi-infinite diffusion through a homogeneous medium. By applying the series-parallel pathway model, the following permeability coefficients (10(-5) cm/sec) for the hepatocyte plasma membrane were obtained. 3 H 2 O, 98.6 +/- 18.4; [ 14 C]urea, 18.2 +/- 5.3; [ 14 C]erythritol, 4.8 +/- 1.6; [ 14 C]mannitol, 3.1 +/- 1.4; [ 3 H]sucrose, 0; [ 3 H]inulin, 0. These results indicate that isolated rat hepatocytes are highly permeable to water and polar nonelectrolytes, when compared with other transporting epithelia. This relatively high cellular permeability is consistent with a model in which nonelectrolyte permeation is via an aqueous pathway of equivalent pore diameter of 8-12 A. The finding that [ 14 C]erythritol and [ 14 C]mannitol cross the hepatocyte plasma membrane indicates that these molecules enter the bile canaliculus through the transcellular route. Conversely, the failure of [ 3 H]sucrose and [ 3 H]inulin to permeate the hepatocyte in the isolated condition supports the concept that biliary entry of these large carbohydrates, at least that fraction which cannot be accounted for by a vesicular mechanism, must occur via the transjunctional shunt pathway

  18. Synthesis and characterization of silica gel from siliceous sands of southern Tunisia

    Directory of Open Access Journals (Sweden)

    Ali Sdiri

    2014-09-01

    Full Text Available The present work aimed to achieve valorization of Albian sands for the preparation of sodium silicates that are commonly used as a precursor to prepare silica gel. A siliceous sand sample was mixed with sodium carbonate and heated at a high temperature (1060 °C to prepare sodium silicates. The sodium silicates were dissolved in distilled water to obtain high quality sodium silicate solution. Hydrochloric acid was then slowly added to the hydrated sodium silicates to obtain silica gel. The collected raw siliceous sands, as well as the prepared silica gels, were characterized by different techniques, such as X-ray fluorescence (XRF, X-ray diffraction (XRD, scanning electron microscopy (SEM and thermal analysis (DSC. XRF confirmed that the detrital sand deposits of southern Tunisia contain high amounts of silica, with content ranging from 88.8% to 97.5%. The internal porosity varied between 17% and 22%, and the specific surface area was less than 5 m2/g. After the treatment described above, it was observed that the porosity of the obtained silica gel reached 57% and the specific surface area exceeded 340 m2/g. Nitrogen adsorption isotherms showed that the prepared silica gels are microporous and mesoporous materials with high adsorption capacities. These results suggest that the obtained silica gels are promising materials for numerous environmental applications.

  19. Survival potential of Escherichia coli and Enterococci in subtropical beach sand: implications for water quality managers.

    Science.gov (United States)

    Hartz, A; Cuvelier, M; Nowosielski, K; Bonilla, T D; Green, M; Esiobu, N; McCorquodale, D S; Rogerson, A

    2008-01-01

    Fecal bacteria have traditionally been used as indicator organisms to monitor the quality of recreational waters. Recent work has questioned the robustness of traditional indicators, particularly at seawater bathing beaches. For example, a study of Florida beaches found unexpectedly high abundances of Escherichia coli, fecal coliforms, and enterococci in beach sand. The aim of the present study was to explain these abundances by assessing the survival of E. coli and enterococci in beach sand relative to seawater. We used a combination of quantitative laboratory mesocosm experiments and field observations. Results suggested that E. coli and enterococci exhibited increased survivability and growth in sand relative to seawater. Because fecal bacteria are capable of replicating in sand, at least under controlled laboratory conditions, the results suggest that sand may be an important reservoir of metabolically active fecal organisms. Experiments with "natural" mesocosms (i.e., unsterilized sand or water rich in micropredators and native bacteria) failed to show the same increases in fecal indicators as was found in sterile sand. It is postulated that this was due to predation and competition with indigenous bacteria in these "natural" systems. Nonetheless, high populations of indicators were maintained and recovered from sand over the duration of the experiment as opposed to the die-off noted in water. Indicator bacteria may wash out of sand into shoreline waters during weather and tidal events, thereby decreasing the effectiveness of these indicators as predictors of health risk and complicating the interpretations for water quality managers.

  20. Use of sand wave habitats by silver hake

    Science.gov (United States)

    Auster, P.J.; Lindholm, J.; Schaub, S.; Funnell, G.; Kaufman, L.S.; Valentine, P.C.

    2003-01-01

    Silver hake Merluccius bilinearis are common members of fish communities in sand wave habitats on Georges Bank and on Stellwagen Bank in the Gulf of Maine. Observations of fish size v. sand wave period showed that silver hake are not randomly distributed within sand wave landscapes. Regression analyses showed a significant positive relationship between sand wave period and fish length. Correlation coefficients, however, were low, suggesting other interactions with sand wave morphology, the range of current velocities, and available prey may also influence their distribution. Direct contact with sand wave habitats varied over diel periods, with more fish resting on the seafloor during daytime than at night. Social foraging, in the form of polarized groups of fish swimming in linear formations during crepuscular and daytime periods, was also observed. Sand wave habitats may provide shelter from current flows and mediate fish-prey interactions. ?? 2003 The Fisheries Society of the British Isles.

  1. Virus Dynamics Are Influenced by Season, Tides and Advective Transport in Intertidal, Permeable Sediments.

    Science.gov (United States)

    Vandieken, Verona; Sabelhaus, Lara; Engelhardt, Tim

    2017-01-01

    Sandy surface sediments of tidal flats exhibit high microbial activity due to the fast and deep-reaching transport of oxygen and nutrients by porewater advection. On the other hand during low tide, limited transport results in nutrient and oxygen depletion concomitant to the accumulation of microbial metabolites. This study represents the first attempt to use flow-through reactors to investigate virus production, virus transport and the impact of tides and season in permeable sediments. The reactors were filled with intertidal sands of two sites (North beach site and backbarrier sand flat of Spiekeroog island in the German Wadden Sea) to best simulate advective porewater transport through the sediments. Virus and cell release along with oxygen consumption were measured in the effluents of reactors during continuous flow of water through the sediments as well as in tidal simulation experiments where alternating cycles with and without water flow (each for 6 h) were operated. The results showed net rates of virus production (0.3-13.2 × 10 6 viruses cm -3 h -1 ) and prokaryotic cell production (0.3-10.0 × 10 5 cells cm -3 h -1 ) as well as oxygen consumption rates (56-737 μmol l -1 h -1 ) to be linearly correlated reflecting differences in activity, season and location of the sediments. Calculations show that total virus turnover was fast with 2 to 4 days, whereas virus-mediated cell turnover was calculated to range between 5-13 or 33-91 days depending on the assumed burst sizes (number of viruses released upon cell lysis) of 14 or 100 viruses, respectively. During the experiments, the homogenized sediments in the reactors became vertically structured with decreasing microbial activities and increasing impact of viruses on prokaryotic mortality with depth. Tidal simulation clearly showed a strong accumulation of viruses and cells in the top sections of the reactors when the flow was halted indicating a consistently high virus production during low tide. In

  2. Upscaling verticle permeability within a fluvio-aeolian reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, S.D.; Corbett, P.W.M.; Jensen, J.L. [Heriot-Watt Univ., Edinburgh (United Kingdom)

    1997-08-01

    Vertical permeability (k{sub v}) is a crucial factor in many reservoir engineering issues. To date there has been little work undertaken to understand the wide variation of k{sub v} values measured at different scales in the reservoir. This paper presents the results of a study in which we have modelled the results of a downhole well tester using a statistical model and high resolution permeability data. The work has demonstrates and quantifies a wide variation in k{sub v} at smaller, near wellbore scales and has implications for k{sub v} modelling at larger scales.

  3. On the permeability of thermally damaged PBX 9501

    Energy Technology Data Exchange (ETDEWEB)

    Zerkle, David K. [Decision Applications Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Asay, Blaine W.; Parker, Gary R.; Dickson, Peter M. [Dynamic and Energetic Materials Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Smilowitz, Laura B.; Henson, Bryan F. [Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2007-06-15

    Theoretical analysis, modeling, and simulation are used to provide insight into the development of permeability during thermal damage of the high explosive PBX 9501. In a recently published article, Terrones et al. [1] conclude that samples of PBX 9501 thermally damaged at 186 C are not permeable to gas flow in a manner consistent with Darcy's Law. We disagree with their conclusion. We show that they have misreported data from the literature, and that their argument depends on a fluid flow model that is physically incorrect and is applied with inappropriate physical parameters. (Abstract Copyright [2007], Wiley Periodicals, Inc.)

  4. Tidal dynamics in the sand motor lagoon

    NARCIS (Netherlands)

    De Vries, S.; Radermacher, M.; De Schipper, M.A.; Stive, M.J.F.

    2015-01-01

    The Sand Motor is a mega-nourishment characterized by a very large sand volume of around 20 million m3 placed along the Dutch coast. The Sand Motor is a pilot project to evaluate the performance of an alternative nourishment strategy with respect to different functions of the coastal system. Within

  5. Valorisation du sable de concassage et du sable du désert dans la composition des bétons autoplaçants Valorization of the crushed sand and of the desert sand in the composition of the self compacting concrete

    Directory of Open Access Journals (Sweden)

    R’mili A.

    2012-09-01

    Full Text Available Les bétons autopla÷ants (BAP sont des bétons très fluides qui demandent des dosages élevés en sables et en éléments fins par rapport au béton ordinaire (BO. Le sable de concassage (SC, à granularité étalée, est un sous-produit de concassage des roches massives. Le sable du désert (SD est un sable extra-fin, caractérisé par une distribution serrée de grosseur des grains. Renfermant des teneurs importantes en fines, ces deux sables peuvent êtres des composants intéressants des BAP. Cette recherché consiste à incorporer le SC dans la composition des bétons et étudier l’effet de son remplacement progressif par le SD sur le comportement à l’état frais et durci des BAP. L’étude expérimentale montre que les paramètres d’ouvrabilité des BAP sont améliorés lorsque le SC est partiellement remplacé par le SD ( 30%, des quantités supplémentaires en eau et en superplastifiant sont nécessaires, pour répondre aux propriétés autopla÷antes. Les résistances mécaniques diminuent en ajoutant le SD au SC, mais elles atteignent des valeurs acceptables pour des dosages modérés en SD. Les performances des BAP sont nettement meilleures que celles des BO confectionnées avec les mêmes granulats. Les essais de spécification de la durabilité montrent que les coefficients d’absorption d’eau par capillarité et par immersion augmentent en ajoutant le SD au SC alors que le coefficient de perméabilité diminue. Self-compacting concretes (SCC are highly fluid concretes that require high proportions in sand and fine particles with respect to the ordinary concrete (OC. The crushed sand (CS, spread granulometry, is a by-product of crushing rock mass. The desert sand (DS is an extra fine sand, characterized by a tight distribution of grain size. Containing significant levels of fine sand, these two sands can be both interesting components of the SCC. This research is to incorporate the CS in the composition of concrete and

  6. Sand wave fields beneath the Loop Current, Gulf of Mexico: Reworking of fan sands

    Science.gov (United States)

    Kenyon, Neil H.; Akhmetzhanov, A.M.; Twichell, D.C.

    2002-01-01

    Extensive fields of large barchan-like sand waves and longitudinal sand ribbons have been mapped by deep-towed SeaMARC IA sidescan sonar on part of the middle and lower Mississippi Fan that lies in about 3200 m of water. The area is beneath the strongly flowing Loop Current. The bedforms have not been adequately sampled but probably consist of winnowed siliciclastic-foraminiferal sands. The size (about 200 m from wingtip to wingtip) and shape of the large barchans is consistent with a previously observed peak current speed of 30 cm/s, measured 25 m above the seabed. The types of small-scale bedforms and the scoured surfaces of chemical crusts, seen on nearby bottom photographs, indicate that near-bed currents in excess of 30 cm/s may sometimes occur. At the time of the survey the sand transport direction was to the northwest, in the opposite direction to the Loop Current but consistent with there being a deep boundary current along the foot of the Florida Escarpment. Some reworking of the underlying sandy turbidites and debris flow deposits is apparent on the sidescan sonar records. Reworking by deep-sea currents, resulting in erosion and in deposits characterised by coarsening upwards structures and cross-bedding, is a process that has been proposed for sand found in cores in shallower parts of the Gulf of Mexico. This process is more widespread than hitherto supposed. 

  7. Alberta oil sands royalty regime

    International Nuclear Information System (INIS)

    Asgarpour, S.

    2004-01-01

    The long term objective of the Oil Sands Business Unit of Alberta Energy is to pave the way for Alberta's bitumen production to reach 3 million barrels per day by 2020. This presentation described the national government's role in resource development. It was emphasized that since the Crown is the owner of the oil sands resource, it would benefit by providing strategic leadership and by generating a larger royalty base. The oil sands fiscal regime was described with reference to generic royalty, risk sharing, investment, and project economics. Business rule principles were also outlined along with criteria for project expansions. Both upstream and downstream challenges and opportunities were listed. 4 figs

  8. Experimental study of optimal self compacting concrete with spent foundry sand as partial replacement for M-sand using Taguchi approach

    Directory of Open Access Journals (Sweden)

    Nirmala D.B.

    2016-06-01

    Full Text Available This paper presents the application of Taguchi approach to obtain optimal mix proportion for Self Compacting Concrete (SCC containing spent foundry sand and M-sand. Spent foundry sand is used as a partial replacement for M-sand. The SCC mix has seven control factors namely, Coarse aggregate, M-sand with Spent Foundry sand, Cement, Fly ash, Water, Super plasticizer and Viscosity modifying agent. Modified Nan Su method is used to proportion the initial SCC mix. L18 (21×37 Orthogonal Arrays (OA with the seven control factors having 3 levels is used in Taguchi approach which resulted in 18 SCC mix proportions. All mixtures are extensively tested both in fresh and hardened states to verify whether they meet the practical and technical requirements of SCC. The quality characteristics considering “Nominal the better” situation is applied to the test results to arrive at the optimal SCC mix proportion. Test results indicate that the optimal mix satisfies the requirements of fresh and hardened properties of SCC. The study reveals the feasibility of using spent foundry sand as a partial replacement of M-sand in SCC and also that Taguchi method is a reliable tool to arrive at optimal mix proportion of SCC.

  9. Experimental study of optimal self compacting concrete with spent foundry sand as partial replacement for M-sand using Taguchi approach

    Science.gov (United States)

    Nirmala, D. B.; Raviraj, S.

    2016-06-01

    This paper presents the application of Taguchi approach to obtain optimal mix proportion for Self Compacting Concrete (SCC) containing spent foundry sand and M-sand. Spent foundry sand is used as a partial replacement for M-sand. The SCC mix has seven control factors namely, Coarse aggregate, M-sand with Spent Foundry sand, Cement, Fly ash, Water, Super plasticizer and Viscosity modifying agent. Modified Nan Su method is used to proportion the initial SCC mix. L18 (21×37) Orthogonal Arrays (OA) with the seven control factors having 3 levels is used in Taguchi approach which resulted in 18 SCC mix proportions. All mixtures are extensively tested both in fresh and hardened states to verify whether they meet the practical and technical requirements of SCC. The quality characteristics considering "Nominal the better" situation is applied to the test results to arrive at the optimal SCC mix proportion. Test results indicate that the optimal mix satisfies the requirements of fresh and hardened properties of SCC. The study reveals the feasibility of using spent foundry sand as a partial replacement of M-sand in SCC and also that Taguchi method is a reliable tool to arrive at optimal mix proportion of SCC.

  10. Large-eddy simulation of sand dune morphodynamics

    Science.gov (United States)

    Khosronejad, Ali; Sotiropoulos, Fotis; St. Anthony Falls Laboratory, University of Minnesota Team

    2015-11-01

    Sand dunes are natural features that form under complex interaction between turbulent flow and bed morphodynamics. We employ a fully-coupled 3D numerical model (Khosronejad and Sotiropoulos, 2014, Journal of Fluid Mechanics, 753:150-216) to perform high-resolution large-eddy simulations of turbulence and bed morphodynamics in a laboratory scale mobile-bed channel to investigate initiation, evolution and quasi-equilibrium of sand dunes (Venditti and Church, 2005, J. Geophysical Research, 110:F01009). We employ a curvilinear immersed boundary method along with convection-diffusion and bed-morphodynamics modules to simulate the suspended sediment and the bed-load transports respectively. The coupled simulation were carried out on a grid with more than 100 million grid nodes and simulated about 3 hours of physical time of dune evolution. The simulations provide the first complete description of sand dune formation and long-term evolution. The geometric characteristics of the simulated dunes are shown to be in excellent agreement with observed data obtained across a broad range of scales. This work was supported by NSF Grants EAR-0120914 (as part of the National Center for Earth-Surface Dynamics). Computational resources were provided by the University of Minnesota Supercomputing Institute.

  11. Permeability of commercial solvents through living human skin

    DEFF Research Database (Denmark)

    Ursin, C; Hansen, C M; Van Dyk, J W

    1995-01-01

    A procedure has been developed for measuring the steady state rate of permeation of commercial solvents through living human skin. To get the most consistent results, it was necessary with some solvents to normalize the solvent permeation rate of a given skin sample with its [3H]water permeation...... rate. For other solvents this was not necessary, so the un-normalized data were used. High [3H]water permeation rate also was used as a criterion for "defective" skin samples that gave erroneous permeability rates, especially for solvents having slow permeability. The linearity of the steady state data...... of DMSO and octyl acetate were measured. No octyl acetate was detected and the permeability of DMSO was proportional to its mole fraction in the mixture. The effect of two hours of solvent exposure on the viability of skin (based on DNA synthesis) was measured and found to be very dependent on the solvent....

  12. Oil sands tailings management project

    Energy Technology Data Exchange (ETDEWEB)

    Godwalt, C. [Alberta WaterSMART, Calgary, AB (Canada); Kotecha, P. [Suncor Energy Inc, Calgary, AB (Canada); Aumann, C. [Alberta Innovates - Technology Futures, Alberta Governement, AB (Canada)

    2010-11-15

    The Oil sands leadership initiative (OSLI) works with the Government of Alberta on the development of the oil sands industry, considering environmental, economical and social aspects. Water management was identified as one of most important areas to focus on. Alberta WaterSMART was requested to support the development and the management of projects resulting from the work done or underway in this field. The development of a regional water management solution stood out as the most interesting solution to obtain significant results. In the Athabasca Region, oil sands producers work independently on their water sourcing and disposal with particular attention to fresh water conservation and economics. The Athabasca River represents a source for mines and distant saline aquifers are the target of steam assisted gravity drainage (SAGD) operators. As part of a four-phase project aiming to study the environmental and economic footprint (EEF) benefit of alternatives for Athabasca oil sands production water supply and disposal, the purpose of the tailings water management project was to identify tailings treatment technologies that are ready to be implemented, and to design and evaluate solutions in order to improve regional oil sands production water sourcing and disposal. Alternatives were evaluated based on their total EEF, applying a lifecycle assessment methodology with a particular attention on the quantification of important performance indicators. 25 refs., 8 tabs., 40 figs.

  13. Oil sands tailings management project

    International Nuclear Information System (INIS)

    Godwalt, C.; Kotecha, P.; Aumann, C.

    2010-11-01

    The Oil sands leadership initiative (OSLI) works with the Government of Alberta on the development of the oil sands industry, considering environmental, economical and social aspects. Water management was identified as one of most important areas to focus on. Alberta WaterSMART was requested to support the development and the management of projects resulting from the work done or underway in this field. The development of a regional water management solution stood out as the most interesting solution to obtain significant results. In the Athabasca Region, oil sands producers work independently on their water sourcing and disposal with particular attention to fresh water conservation and economics. The Athabasca River represents a source for mines and distant saline aquifers are the target of steam assisted gravity drainage (SAGD) operators. As part of a four-phase project aiming to study the environmental and economic footprint (EEF) benefit of alternatives for Athabasca oil sands production water supply and disposal, the purpose of the tailings water management project was to identify tailings treatment technologies that are ready to be implemented, and to design and evaluate solutions in order to improve regional oil sands production water sourcing and disposal. Alternatives were evaluated based on their total EEF, applying a lifecycle assessment methodology with a particular attention on the quantification of important performance indicators. 25 refs., 8 tabs., 40 figs.

  14. The energy efficiency of oil sands extraction: Energy return ratios from 1970 to 2010

    International Nuclear Information System (INIS)

    Brandt, Adam R.; Englander, Jacob; Bharadwaj, Sharad

    2013-01-01

    It has been argued that the oil sands industry is not energy efficient: comparatively large energy inputs are required per unit of energy output from oil sands operations. Unfortunately, quantitative work to date in this area has suffered from poor data availability and uncertain methods. We apply a new methodology and new dataset to compute ERRs (energy return ratios) for the oil sands industry. We collected monthly oil sands energy consumption and output data from 1970 to 2010. Current oil sands operations have mine mouth NERs (net energy returns) of about 6 GJ output per GJ of energy consumed and point of use energy returns of about 3 GJ/GJ. Long-term trends show oil sands operations becoming significantly more efficient: point of use NER increased from about 1 GJ/GJ in 1970 to 3 GJ/GJ in 2010. These energy returns are lower than those observed in historical conventional oil operations, but low energy returns are not likely to hinder development of oil sands operations due to the large resource in place and the ability for largely self-fueled pathways to return significant amounts of energy to society for every unit of external energy supplied. - Highlights: • Oil sands operations have become significantly more energy efficient over the history of the industry. • Oil sands production is largely fueled with energy from the bitumen resource itself, making external energy returns high. • Oil sands production is still significantly less efficient than conventional oil production

  15. Magnetic permeability of stainless steel for use in accelerator beam transport systems

    International Nuclear Information System (INIS)

    Wilson, N.G.; Bunch, P.

    1991-01-01

    High-vacuum beam transport tubes are being designed for use in an accelerator under development at Los Alamos. In areas such as weld-heat-affected zones, the tubes will require localized magnetic permeability of less than 1.02. Seven austenitic stainless steel candidates, 304L, 310, 316L, 317LN, 20Cb-3, Nitronic 33, and Nitronic 40, have been evaluated to determine their permeability in cold-worked, annealed, and weld-affected zones. 310 and 20Cb-3 showed permeability after welding of less than 1.01. 1 ref., 1 fig., 1 tab

  16. Invasive plants on disturbed Korean sand dunes

    Science.gov (United States)

    Kim, Kee Dae

    2005-01-01

    The sand dunes in coastal regions of South Korea are important ecosystems because of their small size, the rare species found in this habitat, and the beautiful landscapes they create. This study investigated the current vegetative status of sand dunes on three representative coasts of the Korean peninsula, and on the coasts of Cheju Island, and assessed the conditions caused by invasive plants. The relationships between the degree of invasion and 14 environmental variables were studied. Plots of sand dunes along line transects perpendicular to the coastal lines were established to estimate vegetative species coverage. TWINSPAN (Two-Way Indicator Species Analysis), CCA (Canonical Correspondence Analysis), and DCCA (Detrended Canonical Correspondence Analysis) were performed to classify communities on sand dunes and assess species composition variation. Carex kobomugi, Elymus mollis, and Vitex rotundifolia were found to be the dominant species plotted on the east, the west, and the peripheral coasts of Cheju Island, respectively. Vegetation on the south coast was totally extinct. The 19 communities, including representative C. kobomugi, C. kobomugi- Ixeris repens, C. kobomugi- Oenothera biennis, E. mollis, Lolium multiflorum- Calystegia soldanella, and V. rotundifolia- C. kobomugi, were all classified according to TWINSPAN. Oenothera biennis and L. multiflorum were exotics observed within these native communities. CCA showed that invasive native and exotic species distribution was segregated significantly, according to disturbance level, exotic species number, gravel, sand and silt contents, as well as vegetation size. It further revealed that human disturbance can strongly favor the settlement of invasive and exotic species. Restoration options to reduce exotic plants in the South Korean sand dune areas were found to be the introduction of native plant species from one sand dune into other sand dune areas, prohibition of building and the introduction of exotic

  17. Advantageous Solubility-Permeability Interplay When Using Amorphous Solid Dispersion (ASD) Formulation for the BCS Class IV P-gp Substrate Rifaximin: Simultaneous Increase of Both the Solubility and the Permeability.

    Science.gov (United States)

    Beig, Avital; Fine-Shamir, Noa; Lindley, David; Miller, Jonathan M; Dahan, Arik

    2017-05-01

    Rifaximin is a BCS class IV (low-solubility, low-permeability) drug and also a P-gp substrate. The aims of this work were to assess the efficiency of different rifaximin amorphous solid dispersion (ASDs) formulations in achieving and maintaining supersaturation and to investigate the consequent solubility-permeability interplay. Spray-dried rifaximin ASDs were prepared with different hydrophilic polymers and their ability to achieve and maintain supersaturation was assessed. Then, rifaximin's apparent intestinal permeability was investigated as a function of increasing supersaturation both in vitro using the parallel artificial membrane permeability assay (PAMPA) and in vivo using the single-pass rat intestinal perfusion (SPIP) model. The efficiency of the different ASDs to achieve and maintain supersaturation of rifaximin was found to be highly polymer dependent, and the copovidone/HPC-SL formulation was found to be superior to the other two, allowing supersaturation of 200× that of the crystalline solubility for 20 h. In vitro, rifaximin flux was increased and the apparent permeability was constant as a function of increasing supersaturation level. In vivo, on the other hand, absorption rate coefficient (k a ) was first constant as a function of increasing supersaturation, but at 250×, the crystalline solubility k a was doubled, similar to the k a in the presence of the strong P-gp inhibitor GF120918. In conclusion, a new and favorable nature of solubility-permeability interplay was revealed in this work: delivering high supersaturation level of the BCS class IV drug rifaximin via ASD, thereby saturating the drugs' P-gp-mediated efflux transport, led to the favorable unique win-win situation, where both the solubility and the permeability increased simultaneously.

  18. Measurements of Dune Parameters on Titan Suggest Differences in Sand Availability

    Science.gov (United States)

    Stewart, Brigitte W.; Radebaugh, Jani

    2014-11-01

    The equatorial region of Saturn’s moon Titan has five large sand seas with dunes similar to large linear dunes on Earth. Cassini Radar SAR swaths have high enough resolution (300 m) to measure dune parameters such as width and spacing, which helps inform us about formation conditions and long-term evolution of the sand dunes. Previous measurements in locations scattered across Titan have revealed an average width of 1.3 km and spacing of 2.7 km, with variations by location. We have taken over 1200 new measurements of dune width and spacing in the T8 swath, a region on the leading hemisphere of Titan in the Belet Sand Sea, between -5 and -9 degrees latitude. We have also taken over 500 measurements in the T44 swath, located on the anti-Saturn hemisphere in the Shangri-La Sand Sea, between 0 and 20 degrees latitude. We correlated each group of 50 measurements with the average distance from the edge of the dune field to obtain an estimate of how position within a dune field affects dune parameters. We found that in general, the width and spacing of dunes decreases with distance from the edge of the dune field, consistent with similar measurements in sand seas on Earth. We suggest that this correlation is due to the lesser availability of sand at the edges of dune fields. These measurements and correlations could be helpful in determining differences in sand availability across different dune fields, and along the entire equatorial region of Titan.

  19. Characteristics of SCC with Fly Ash and Manufactured Sand

    Science.gov (United States)

    Praveen Kumar, K.; Radhakrishna

    2016-09-01

    Self compacting concrete (SCC) of M40 grade was designed. The binder in SCC consists of OPC and fly ash in the ratio of 65:35. River sand was replaced by manufactured sand (M-sand) at replacement levels of 20,40,60,80 and 100%. An attempt was made to evaluate the workability and strength characteristics of self compacting concrete with river sand and manufactured sand as fine aggregates. For each replacement level, constant workability was maintained by varying the dosage of superplasticizer. T50 flow time, V Funnel time, V-funnel T5 time as well as compressive, split tensile and flexural strength of SCC were found at each replacement level of M-sand. They were compared to SCC with river sand. Results indicate favourable use of M-sand in preparation of Self Compacting Concrete.

  20. Frac Sand Mines Are Preferentially Sited in Unzoned Rural Areas.

    Directory of Open Access Journals (Sweden)

    Christina Locke

    Full Text Available Shifting markets can cause unexpected, stochastic changes in rural landscapes that may take local communities by surprise. Preferential siting of new industrial facilities in poor areas or in areas with few regulatory restrictions can have implications for environmental sustainability, human health, and social justice. This study focuses on frac sand mining-the mining of high-quality silica sand used in hydraulic fracturing processes for gas and oil extraction. Frac sand mining gained prominence in the 2000s in the upper midwestern United States where nonmetallic mining is regulated primarily by local zoning. I asked whether frac sand mines were more commonly sited in rural townships without formal zoning regulations or planning processes than in those that undertook zoning and planning before the frac sand boom. I also asked if mine prevalence was correlated with socioeconomic differences across townships. After creating a probability surface to map areas most suitable for frac sand mine occurrence, I developed neutral landscape models from which to compare actual mine distributions in zoned and unzoned areas at three different spatial extents. Mines were significantly clustered in unzoned jurisdictions at the statewide level and in 7 of the 8 counties with at least three frac sand mines and some unzoned land. Subsequent regression analyses showed mine prevalence to be uncorrelated with land value, tax rate, or per capita income, but correlated with remoteness and zoning. The predicted mine count in unzoned townships was over two times higher than that in zoned townships. However, the county with the most mines by far was under a county zoning ordinance, perhaps indicating industry preferences for locations with clear, homogenous rules over patchwork regulation. Rural communities can use the case of frac sand mining as motivation to discuss and plan for sudden land-use predicaments, rather than wait to grapple with unfamiliar legal processes

  1. Properties of dune sand concrete containing coffee waste

    Directory of Open Access Journals (Sweden)

    Mohamed Guendouz

    2018-01-01

    Full Text Available In the last years, an increase of coffee beverages consumption has been observed all over the world; and its consumption increases the waste coffee grounds which will become an environmental problems. Recycling of this waste to produce new materials like sand concrete appears as one of the best solutions for reduces the problem of pollution. This work aims to study the possibility of recycling waste coffee grounds (Spent Coffee Grounds (SCG as a fine aggregate by replacing the sand in the manufacturing of dune sand concrete. For this; sand concrete mixes were prepared with substitution of sand with the spent coffee grounds waste at different percentage (0%, 5%, 10%, 15% and 20% by volume of the sand in order to study the influence of this wastes on physical (Workability, bulk density and porosity, mechanical (compressive and flexural strength and Thermal (Thermal conductivity and thermal diffusivity properties of dune sand concrete. The results showed that the use of spent coffee grounds waste as partial replacement of natural sand contributes to reduce workability, bulk density and mechanical strength of sand concrete mixes with an increase on its porosity. However, the thermal characteristics are improved and especially for a level of 15% and 20% of substitution. So, it is possible to obtain an insulating material which can be used in the various types of structural components. This study ensures that reusing of waste coffee grounds in dune sand concrete gives a positive approach to reduce the cost of materials and solve some environmental problems.

  2. Evaluation of the membrane permeability (PAMPA and skin) of benzimidazoles with potential cannabinoid activity and their relation with the Biopharmaceutics Classification System (BCS).

    Science.gov (United States)

    Alvarez-Figueroa, M Javiera; Pessoa-Mahana, C David; Palavecino-González, M Elisa; Mella-Raipán, Jaime; Espinosa-Bustos, Cristián; Lagos-Muñoz, Manuel E

    2011-06-01

    The permeability of five benzimidazole derivates with potential cannabinoid activity was determined in two models of membranes, parallel artificial membrane permeability assay (PAMPA) and skin, in order to study the relationship of the physicochemical properties of the molecules and characteristics of the membranes with the permeability defined by the Biopharmaceutics Classification System. It was established that the PAMPA intestinal absorption method is a good predictor for classifying these molecules as very permeable, independent of their thermodynamic solubility, if and only if these have a Log P(oct) value permeability is conditioned on the solubility of the molecule so that it can only serve as a model for classifying the permeability of molecules that possess high solubility (class I: high solubility, high permeability; class III: high solubility, low permeability).

  3. Uranium and Thorium in zircon sands processed in Northeastern Brazil

    International Nuclear Information System (INIS)

    Hazin, Clovis A.; Farias, Emerson E. G. de

    2008-01-01

    Zircon the main mineral of zirconium is a silicate mineral product (ZrSiO 4 ) obtained from beach sand deposits, along with other minerals such as kyanite, ilmenite, and rutile. All zircons contain some radioactive impurities due to the presence of uranium, thorium and their respective decay products in the crystalline structure of zircon, as well as potassium-40. Uranium and thorium substitute Zr 4+ in the mineral through an internal process called isomorphous replacement of zirconium. For this study, samples were collected both from a mineral sand processing plant located in the coastal region of Northeastern brazil and from the beach sands used in the process. The aim of this study was to assess the 238 U, 232 Th and 40 K contents in the beach sands and in the mineral products extracted from the sands in that facility, with special emphasis on zircon. Measurements were performed through gamma spectrometry, by using a high-purity germanium detector (HPGe) coupled to a multichannel analyzer. Activity concentration for 238 U and 232 Th in zircon sands ranged from 5462±143 to 19286±46 Bq kg -1 and from 1016±7 to 7162±38 Bq kg -1 , respectively. For 40 K, on the other hand, activity concentration values ranged from 81±14 to 681±26 Bq Kg -1 . The results of the measurements carried out for raw sand samples showed activity concentrations between 2.7±0.6 and 7.9±0.9 Bq kg -1 and 6.5±0.4 and 9.4±0.6 Bq kg -1 for 238 U and 23T h respectively, and from 48.8±3.1 to 76.1±2.4 Bq kg -1 for 40 K. Activity concentrations of 238 U and 232 Th in kyanite, ilmenite and rutile samples were also determined. (author)

  4. Population dynamics of the sand shiner (notropis stramineus) in non-wadeable rivers of Iowa

    Science.gov (United States)

    Smith, C.D.; Neebling, T.E.; Quist, M.C.

    2010-01-01

    The sand shiner (Notropis stramineus) is a common cyprinid found throughout the Great Plains region of North America that plays an important ecological role in aquatic systems. This study was conducted to describe population dynamics of sand shiners including age structure, growth, mortality, and recruitment variability in 15 non-wadeable rivers in Iowa. Fish were collected during June-August (2007-2008) using a modified Missouri trawl, a seine, and boat-mounted electrofishing. Scales were removed for age and growth analysis. A total of 3,443 fish was sampled from 15 populations across Iowa, of which 676 were aged. Iowa's sand shiner populations consisted primarily of age-1 fish (53% of all fish sampled), followed by age-2 fish (30%), age-0 fish (15%), and age-3 fish (2%). Sand shiners grew an average of 38.5 mm (SE = 5.7) during their first year, 13.8 mm (4.5) during their second year, and 9.0 mm (6.9) during their third year. Total annual mortality varied from 35.0% to 92.3% among populations with a mean of 77.9% (0.2). Incremental mortality rates were 84.5% (0.2) between age 1 and age 2, and 92.0% (0.1) between age 2 and age 3. Recruitment was highly variable, as indicated by a mean recruitment variation index of-0.12 (0.54). Overall, the sand shiner was characterized by relatively low mean age, fast growth, high mortality, and high recruitment variability. Indices of sand shiner population dynamics were poorly correlated with habitat characteristics.

  5. Stress-Dilatancy of Cambria Sand for Triaxial Tests at High Pressures

    Science.gov (United States)

    Szypcio, Zenon

    2017-12-01

    In this paper, the stress-dilatancy relationship of Cambria sand for drained triaxial compression and extension tests at high stress level is investigated. The stress dilatancy relationship is obtained by use of frictional state theory and experimental tests data published in literature. It is shown that stress-dilatancy relationship is bilinear, described by three parameters of frictional state theory: critical frictional angle and two other parameters. It is accepted that critical friction angle is independent of confining pressure. The two additional parameters are strongly dependent on confining pressure and different for initial and advanced stages. The point at which the values of these parameters change is termed as Transformation Shear Point. This point is not simply visible either in stress ratio-strain or the volume strain-shear strain relationship which are traditionally shown in soil mechanics papers. Transformation Shear Point is very characteristic in stress ratio-plastic dilatancy plane. Thus, stress ratio- plastic dilatancy is very important for describing stress-strain behaviour of soils. The relationship shown in the paper can be used in soil modelling in the future.

  6. Western Gas Sands Project. Status report, 1 March 1979--31 March 1979

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    Progress of the government-sponsored projects directed toward increasing gas production from low-permeability gas sands of the western United States is summarized. During March, National Laboratories and Energy Technology Centers generally progressed on schedule. Bartlesville Energy Technology Center continued work on fracture conductivity, rock-fluid interaction, and log evaluation techniques. Theoretical and experimental work on hydraulic fracturing mechanics and analysis of well test data continued at Lawrence Livermore Laboratory. Sandia Laboratories completed preparations for the NTS evaluation test of the borehole seismic system. M.D. Wood, Inc. monitored the formation of a hydraulic fracture in the Wattenburg gas field, Weld County, Colorado. Measurement of bottom-hole pressure in the Miller No. 1 and Sprague No. 1 wells for the CIG cyclic gas injection project continued. The Mitchell Energy Corporation Muse--Duke No. 1 was flowing 4,000 MCFD in March. Efforts to clean out Mobil's PCU F31-13G well continued.

  7. Investigation of guided waves propagation in pipe buried in sand

    International Nuclear Information System (INIS)

    Leinov, Eli; Cawley, Peter; Lowe, Michael J.S.

    2014-01-01

    The inspection of pipelines by guided wave testing is a well-established method for the detection of corrosion defects in pipelines, and is currently used routinely in a variety of industries, e.g. petrochemical and energy. When the method is applied to pipes buried in soil, test ranges tend to be significantly compromised because of attenuation of the waves caused by energy radiating into the soil. Moreover, the variability of soil conditions dictates different attenuation characteristics, which in-turn results in different, unpredictable, test ranges. We investigate experimentally the propagation and attenuation characteristics of guided waves in pipes buried in fine sand using a well characterized full scale experimental apparatus. The apparatus consists of an 8 inch-diameter, 5.6-meters long steel pipe embedded over 3 meters of its length in a rectangular container filled with fine sand, and an air-bladder for the application of overburden pressure. Longitudinal and torsional guided waves are excited in the pipe and recorded using a transducer ring (Guided Ultrasonics Ltd). Acoustic properties of the sand are measured independently in-situ and used to make model predictions of wave behavior in the buried pipe. We present the methodology and the systematic measurements of the guided waves under a range of conditions, including loose and compacted sand. It is found that the application of overburden pressure modifies the compaction of the sand and increases the attenuation, and that the measurement of the acoustic properties of sand allows model prediction of the attenuation of guided waves in buried pipes with a high level of confidence

  8. Studies on various characteristics of concrete structures using crushed sand

    International Nuclear Information System (INIS)

    Mimatsu, Makoto; Sugita, Hideaki; Yonemura, Masataka.

    1985-01-01

    With the recent advances of construction industry, the demands for concrete, hence for aggregate, are rising. The sand as such is in extreme shortage due to the exhaustion of river sand. Under the situation, the recent trends are for the use of crushed sand, i.e. the artificial sand obtained by crushing rocks, which have advantages of stabilized quality and adequate supplies. In building of nuclear power plants requiring large amounts of concrete, the usage of crushed sand is now unavoidable. The following are described : the situation of aggregate in Kyushu. production method of crushed sand and the quality standards, rocks used for crushed stone and sand and the properties, quality survey on crushed sand and the basic tests, characteristic tests of crushed-stone and -sand mixed concrete, the application of crushed sand in structures of the Sendai Nuclear Power Station. (Mori, K.)

  9. Ultra high pressure liquid chromatography. Column permeability and changes of the eluent properties.

    Science.gov (United States)

    Gritti, Fabrice; Guiochon, Georges

    2008-04-11

    The behavior of four similar liquid chromatography columns (2.1mm i.d. x 30, 50, 100, and 150 mm, all packed with fine particles, average d(p) approximately 1.7 microm, of bridged ethylsiloxane/silica hybrid-C(18), named BEH-C(18)) was studied in wide ranges of temperature and pressure. The pressure and the temperature dependencies of the viscosity and the density of the eluent (pure acetonitrile) along the columns were also derived, using the column permeabilities and applying the Kozeny-Carman and the heat balance equations. The heat lost through the external surface area of the chromatographic column was directly derived from the wall temperature of the stainless steel tube measured with a precision of +/-0.2 degrees C in still air and +/-0.1 degrees C in the oven compartment. The variations of the density and viscosity of pure acetonitrile as a function of the temperature and pressure was derived from empirical correlations based on precise experimental data acquired between 298 and 373 K and at pressures up to 1.5 kbar. The measurements were made with the Acquity UPLC chromatograph that can deliver a maximum flow rate of 2 mL/min and apply a maximum column inlet pressure of 1038 bar. The average Kozeny-Carman permeability constant of the columns was 144+/-3.5%. The temperature hence the viscosity and the density profiles of the eluent along the column deviate significantly from linear behavior under high-pressure gradients. For a 1000 bar pressure drop, we measured DeltaT=25-30 K, (Deltaeta/eta) approximately 100%, and (Deltarho/rho) approximately 10%. These results show that the radial temperature profiles are never fully developed within 1% for any of the columns, even under still-air conditions. This represents a practical advantage regarding the apparent column efficiency at high flow rates, since the impact of the differential analyte velocity between the column center and the column wall is not maximum. The interpretation of the peak profiles recorded in

  10. Oil sands development update

    International Nuclear Information System (INIS)

    1999-01-01

    A detailed review and update of oil sands development in Alberta are provided covering every aspect of the production and economic aspects of the industry. It is pointed out that at present oil sands account for 28 per cent of Canadian crude oil production, expected to reach 50 per cent by 2005. Based on recent announcements, a total of 26 billion dollars worth of projects are in progress or planned; 20 billion dollars worth of this development is in the Athabasca area, the remainder in Cold Lake and other areas. The current update envisages up to 1,800,000 barrels per day by 2008, creating 47,000 new jobs and total government revenues through direct and indirect taxes of 118 billion dollars. Provinces other than Alberta also benefit from these development, since 60 per cent of all employment and income created by oil sands production is in other parts of Canada. Up to 60 per cent of the expansion is for goods and services and of this, 50 to 55 per cent will be purchased from Canadian sources. The remaining 40 per cent of the new investment is for engineering and construction of which 95 per cent is Canadian content. Aboriginal workforce by common consent of existing operators matches regional representation (about 13 per cent), and new developers are expected to match these standards. Planned or ongoing development in environmental protection through improved technologies and optimization, energy efficiency and improved tailings management, and active support of flexibility mechanisms such as emission credits trading, joint implementation and carbon sinks are very high on the industry's agenda. The importance of offsets are discussed extensively along with key considerations for international negotiations, as well as further research of other options such as sequestration, environmentally benign disposal of waste, and enhanced voluntary action

  11. Comparative analysis of fiscal terms for Alberta oil sands and international heavy and conventional oils

    International Nuclear Information System (INIS)

    Van Meurs, P.

    2007-01-01

    There are considerable differences between international heavy oil and Alberta oil sands projects, notably the high viscosity of the bitumen in the oil sands reservoirs. The oil sands bitumen do not flow to wells without heating the bitumen, thereby adding to the already high cost of Alberta oil sand operations. This report provided an economic comparison of Alberta oil sands and international heavy oil projects. It also included a brief scoping review to compare with conventional oil regimes. Full exploration costs including the costs of dry holes were allocated to conventional oil operations in order to obtain a proper comparison. This investigation included the costs of dry holes. The report was a follow up to an earlier study released on April 12, 2007 on the preliminary fiscal evaluation of Alberta oil sand terms. The report provided an economic framework and described project selection. It then provided a discussion of production, costs and price data. Four adjusted projects were presented and compared with Alberta. The Venezuelan royalty formula was also discussed. Last, the report provided a detailed fiscal analysis. Comparisons were offered with Cold Lake and Athabasca Mine. A review of some other fiscal systems applicable to conventional oil were also outlined. It was concluded that Alberta oil sands developments are very competitive. It would be possible to modestly increase government revenues, without affecting the international competitive position of Alberta with respect to conventional oil. There is also some possibility to increase the base royalty on the Alberta oil sands without losing competitiveness. tabs., figs

  12. Microorganism Removal in Permeable Pavement Parking Lots ...

    Science.gov (United States)

    Three types of permeable pavements (pervious concrete, permeable interlocking concrete pavers, and porous asphalt) were monitored at the Edison Environmental Center in Edison, New Jersey for indicator organisms such as fecal coliform, enterococci, and E. coli. Results showed that porous asphalt had much lower concentration in monitored infiltrate compared to pervious concrete and permeable interlocking concrete pavers. Concentrations of monitored organisms in infiltrate from porous asphalt were consistently below the bathing water quality standard. Fecal coliform and enterococci exceeded bathing water quality standards more than 72% and 34% of the time for permeable interlocking concrete pavers and pervious concrete, respectively. Purpose is to evaluate the performance of permeable pavement in removing indicator organisms from infiltrating stormwater runoff.

  13. Road dust from pavement wear and traction sanding

    Energy Technology Data Exchange (ETDEWEB)

    Kupiainen, K.

    2007-07-01

    Vehicles affect the concentrations of ambient airborne particles through exhaust emissions, but particles are also formed in the mechanical processes in the tire-road interface, brakes, and engine. Particles deposited on or in the vicinity of the road may be re-entrained, or resuspended, into air through vehicle-induced turbulence and shearing stress of the tires. A commonly used term for these particles is 'road dust'. The processes affecting road dust emissions are complex and currently not well known. Road dust has been acknowledged as a dominant source of PM10 especially during spring in the sub-arctic urban areas, e.g. in Scandinavia, Finland, North America and Japan. The high proportion of road dust in sub-arctic regions of the world has been linked to the snowy winter conditions that make it necessary to use traction control methods. Traction control methods include dispersion of traction sand, melting of ice with brine solutions, and equipping the tires with either metal studs (studded winter tires), snow chains, or special tire design (friction tires). Several of these methods enhance the formation of mineral particles from pavement wear and/or from traction sand that accumulate in the road environment during winter. When snow and ice melt and surfaces dry out, traffic-induced turbulence makes some of the particles airborne. A general aim of this study was to study processes and factors underlying and affecting the formation and emissions of road dust from paved road surfaces. Special emphasis was placed on studying particle formation and sources during tire road interaction, especially when different applications of traction control, namely traction sanding and/or winter tires were in use. Respirable particles with aerodynamic diameter below 10 micrometers (PM10) have been the main concern, but other size ranges and particle size distributions were also studied. The following specific research questions were addressed: (i) How do traction

  14. Radiation protection in the sand pit

    International Nuclear Information System (INIS)

    Hewson, Greg

    1997-01-01

    Radiation protection in the Western Australian minerals sands industry has attracted considerable controversy over the last 20 years: firstly, in relation to environmental and public health issues associated with the indiscriminate disposal of radioactive tailings as landfill in the mid to late 1970s and, secondly, in relation to occupational health issues associated with excessive radiation exposures to some workers at some plants in the mid to late 1980s. The industry also attracts attention through its proximity to coastal regions and population centres and consequent land use conflicts. Owing to intense political and societal scrutiny, and the emotional responses evoked by radiation, the industry's survival depends on a continuing high level of environmental and safety performance. This article summarises the successes and failures of the mineral sands industry in managing radiation protection and highlights some future issues and challenges for the industry. (Author)

  15. Bayesian inference for heterogeneous caprock permeability based on above zone pressure monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Namhata, Argha; Small, Mitchell J.; Dilmore, Robert M.; Nakles, David V.; King, Seth

    2017-02-01

    The presence of faults/ fractures or highly permeable zones in the primary sealing caprock of a CO2 storage reservoir can result in leakage of CO2. Monitoring of leakage requires the capability to detect and resolve the onset, location, and volume of leakage in a systematic and timely manner. Pressure-based monitoring possesses such capabilities. This study demonstrates a basis for monitoring network design based on the characterization of CO2 leakage scenarios through an assessment of the integrity and permeability of the caprock inferred from above zone pressure measurements. Four representative heterogeneous fractured seal types are characterized to demonstrate seal permeability ranging from highly permeable to impermeable. Based on Bayesian classification theory, the probability of each fractured caprock scenario given above zone pressure measurements with measurement error is inferred. The sensitivity to injection rate and caprock thickness is also evaluated and the probability of proper classification is calculated. The time required to distinguish between above zone pressure outcomes and the associated leakage scenarios is also computed.

  16. Sand lance: A review of biology and predator relations and annotated bibliography

    Science.gov (United States)

    Robards, Martin D.; Willson, Mary F.; Armstrong, Robert H.; Piatt, John F.

    1999-01-01

    Six species of sand lance (Ammodytes) in temperate and boreal regions are currently recognized. Sand lance can occupy a wide range of environmental conditions, but all appear to be dormant predominantly in winter, and one species is in summer also. They lack a swim bladder and spend much of their time buried in specific substrates. Copepods are the primary food. Spawning usually occurs in fall or winter (although some species also spawn in spring), eggs are demersal, and larvae may hatch at times of low food abundance. Sand lance usually occur in schools and are regarded as a relatively high-quality forage fish.Sand lance constitute a major prey for at least some populations of over 100 species of consumer, including 40 species of birds, 12 species of marine mammals, 45 species of fishes, and some invertebrates. Variation in the availability of sand lance (and other forage fishes) can have major effects on the breeding success and survival of their predators. Commercial fishing and other pressures on sand lance populations potentially have ramifying effects on many species of wildlife.The bibliography contains over 1,700 references on the family Ammodytidae, with an emphasis on the genus Ammodytes. Keywords are provided for each reference and have been further organized into taxonomic, geographic, subject, and predator indexes.

  17. Steam-water relative permeability

    Energy Technology Data Exchange (ETDEWEB)

    Ambusso, W.; Satik, C.; Home, R.N. [Stanford Univ., CA (United States)

    1997-12-31

    A set of relative permeability relations for simultaneous flow of steam and water in porous media have been measured in steady state experiments conducted under the conditions that eliminate most errors associated with saturation and pressure measurements. These relations show that the relative permeabilities for steam-water flow in porous media vary approximately linearly with saturation. This departure from the nitrogen/water behavior indicates that there are fundamental differences between steam/water and nitrogen/water flows. The saturations in these experiments were measured by using a high resolution X-ray computer tomography (CT) scanner. In addition the pressure gradients were obtained from the measurements of liquid phase pressure over the portions with flat saturation profiles. These two aspects constitute a major improvement in the experimental method compared to those used in the past. Comparison of the saturation profiles measured by the X-ray CT scanner during the experiments shows a good agreement with those predicted by numerical simulations. To obtain results that are applicable to general flow of steam and water in porous media similar experiments will be conducted at higher temperature and with porous rocks of different wetting characteristics and porosity distribution.

  18. Influence of sand base preparation on properties of chromite moulding sands with sodium silicate hardened with selected methods

    Directory of Open Access Journals (Sweden)

    Stachowicz M.

    2017-03-01

    Full Text Available The paper presents a research on the relation between thermal preparation of chromite sand base of moulding sands containing sodium silicate, hardened with selected physical and chemical methods, and structure of the created bonding bridges. Test specimens were prepared of chromite sand - fresh or baked at 950°C for 10 or 24 hours - mixed with 0.5 wt.% of the selected non-modified inorganic binder and, after forming, were hardened with CO2 or liquid esters, dried traditionally or heated with microwaves at 2.45 GHz. It was shown on the grounds of SEM observations that the time of baking the base sand and the hardening method significantly affect structure of the bonding bridges and are correlated with mechanical properties of the moulding sands. It was found that hardening chromite-based moulding mixtures with physical methods is much more favourable than hardening with chemical methods, guaranteeing also more than ten times higher mechanical properties.

  19. Experimental perforation of tubing with a hydraulic sand jet

    Energy Technology Data Exchange (ETDEWEB)

    Semenov, Yu V

    1970-01-01

    A series of field tests has shown that perforation with a hydraulic sand jet improves the quality of well completion. The sand jet does not crack the cement sheath or the casing, and the perforations are larger and deeper than perforations formed by explosive charges. Fluid circulation during sand jet perforation can safely be stopped for at least 10 min. Water containing a surfactant can be used as a sand carrier. Sand jet perforation allows successful completion of wells cased by 2 tubing strings. Sand jet perforation can be used to clean the borehole well and to remove foreign objects from the well.

  20. Regional-dependent intestinal permeability and BCS classification: elucidation of pH-related complexity in rats using pseudoephedrine.

    Science.gov (United States)

    Fairstein, Moran; Swissa, Rotem; Dahan, Arik

    2013-04-01

    Based on its lower Log P value relative to metoprolol, a marker for the low/high-permeability (P(eff)) class boundary, pseudoephedrine was provisionally classified as BCS low-permeability compound. On the other hand, following oral administration, pseudoephedrine fraction dose absorbed (F(abs)) and systemic bioavailability approaches 100%. This represents a challenge to the generally recognized P(eff)-F(abs) correlation. The purpose of this study was to elucidate the underlying mechanisms behind the confusion in pseudoephedrine's BCS classification. Pseudoephedrine's BCS solubility class was determined, and its physicochemical properties and intestinal permeability were thoroughly investigated, both in vitro and in vivo in rats, considering the complexity of the whole of the small intestine. Pseudoephedrine was found to be unequivocally a high-solubility compound. All of the permeability studies revealed similar phenomenon; at any given intestinal segment/pH, the permeability of metoprolol was higher than that of pseudoephedrine, however, as the intestinal region becomes progressively distal, and the pH gradually increases, pseudoephedrine's permeability rises above that of metoprolol in the former segment. This unique permeability pattern likely explains pseudoephedrine's complete absorption. In conclusion, pseudoephedrine is a BCS Class I compound; no discrepancy between P(eff) and F(abs) is involved in its absorption. Rather, it reflects the complexity behind P(eff) when considering the whole of the intestine. We propose to allow high-permeability classification to drugs with P(eff) that matches/exceeds the low/high class benchmark anywhere throughout the intestinal tract and not restricted necessarily to the jejunum.

  1. Ascorbic acid attenuates endothelial permeability triggered by cell-free hemoglobin.

    Science.gov (United States)

    Kuck, Jamie L; Bastarache, Julie A; Shaver, Ciara M; Fessel, Joshua P; Dikalov, Sergey I; May, James M; Ware, Lorraine B

    2018-01-01

    Increased endothelial permeability is central to shock and organ dysfunction in sepsis but therapeutics targeted to known mediators of increased endothelial permeability have been unsuccessful in patient studies. We previously reported that cell-free hemoglobin (CFH) is elevated in the majority of patients with sepsis and is associated with organ dysfunction, poor clinical outcomes and elevated markers of oxidant injury. Others have shown that Vitamin C (ascorbate) may have endothelial protective effects in sepsis. In this study, we tested the hypothesis that high levels of CFH, as seen in the circulation of patients with sepsis, disrupt endothelial barrier integrity. Human umbilical vein endothelial cells (HUVEC) were grown to confluence and treated with CFH with or without ascorbate. Monolayer permeability was measured by Electric Cell-substrate Impedance Sensing (ECIS) or transfer of 14 C-inulin. Viability was measured by trypan blue exclusion. Intracellular ascorbate was measured by HPLC. CFH increased permeability in a dose- and time-dependent manner with 1 mg/ml of CFH increasing inulin transfer by 50% without affecting cell viability. CFH (1 mg/ml) also caused a dramatic reduction in intracellular ascorbate in the same time frame (1.4 mM without CFH, 0.23 mM 18 h after 1 mg/ml CFH, p < 0.05). Pre-treatment of HUVECs with ascorbate attenuated CFH induced permeability. CFH increases endothelial permeability in part through depletion of intracellular ascorbate. Supplementation of ascorbate can attenuate increases in permeability mediated by CFH suggesting a possible therapeutic approach in sepsis. Copyright © 2017 Elsevier Inc. All rights reserved.

  2. The Rheology of Acoustically Fluidized Sand

    Science.gov (United States)

    Conrad, J. W.; Melosh, J.

    2013-12-01

    The collapse of large craters and the formation of central peaks and peak rings is well modeled by numerical computer codes that incorporate the acoustic fluidization mechanism to temporarily allow the fluid-like flow of rock debris immediately after crater excavation. Furthermore, long runout landslides require a similar mechanism to explain their almost frictionless movement, which is probably also a consequence of their granular composition coupled with internal vibrations. Many different investigators have now confirmed the ability of vibrations to fluidize granular materials. Yet it still remains to fully describe the rheology of vibrated sand as a function of stress, frequency and amplitude of the vibrations in the sand itself. We constructed a rotational viscometer to quantitatively investigate the relation between the stress and strain rate in a horizontal bed of strongly vibrated sand. In addition to the macroscopic stain rate, the amplitude and frequency of the vibrations produced by a pair of pneumatic vibrators were also measured with the aid of miniaturized piezoelectric accelerometers (B&K 4393) whose output was recorded on a digital storage oscilloscope. The initial gathering of the experimental data was difficult due to granular memory, but by having the sand compacted vibrationally for 8 minutes before each run the scatter of data was reduced and we were able to obtain consistent results. Nevertheless, our major source of uncertainty was variations in strain rate from run to run. We find that vibrated sand flows like a highly non-Newtonian fluid, in which the shear strain rate is proportional to stress to a power much greater than one, where the precise power depends on the amplitude and frequency of the applied vibrations. Rapid flow occurs at stresses less than half of the static yield stress (that is, the yield stress when no vibration is applied) when strong vibrations are present. For a Newtonian fluid, such as water, the relation between

  3. A new infiltration method for coating highly permeable matrices with compound materials for high-power isotope-separator-on-line production target applications

    International Nuclear Information System (INIS)

    Kawai, Y.; Bilheux, Jean-Christophe; Stracener, Daniel W; Alton, Gerald D

    2005-01-01

    A new infiltration coating method has been conceived for uniform and controlled thickness deposition of target materials onto highly permeable, complex-structure matrices to form short-diffusion-length isotope-separator-on-line (ISOL) production targets for radioactive ion beam research applications. In this report, the infiltration technique is described in detail and the universal character of the technique illustrated in the form of SEMs of several metal-carbide, metal-oxide and metal-sulfide targets for potential use at present or future radioactive ion beam research facilities

  4. Microbial processes in the Athabasca Oil Sands and their potential applications in microbial enhanced oil recovery.

    Science.gov (United States)

    Harner, N K; Richardson, T L; Thompson, K A; Best, R J; Best, A S; Trevors, J T

    2011-11-01

    The Athabasca Oil Sands are located within the Western Canadian Sedimentary Basin, which covers over 140,200 km(2) of land in Alberta, Canada. The oil sands provide a unique environment for bacteria as a result of the stressors of low water availability and high hydrocarbon concentrations. Understanding the mechanisms bacteria use to tolerate these stresses may aid in our understanding of how hydrocarbon degradation has occurred over geological time, and how these processes and related tolerance mechanisms may be used in biotechnology applications such as microbial enhanced oil recovery (MEOR). The majority of research has focused on microbiology processes in oil reservoirs and oilfields; as such there is a paucity of information specific to oil sands. By studying microbial processes in oil sands there is the potential to use microbes in MEOR applications. This article reviews the microbiology of the Athabasca Oil Sands and the mechanisms bacteria use to tolerate low water and high hydrocarbon availability in oil reservoirs and oilfields, and potential applications in MEOR.

  5. Ecotoxicological impacts of effluents generated by oil sands bitumen extraction and oil sands lixiviation on Pseudokirchneriella subcapitata

    Energy Technology Data Exchange (ETDEWEB)

    Debenest, T., E-mail: tdebenest@yahoo.fr [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Turcotte, P. [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Gagne, F., E-mail: francois.gagne@ec.gc.ca [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Gagnon, C.; Blaise, C. [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada)

    2012-05-15

    The exploitation of Athabasca oil sands deposits in northern Alberta has known an intense development in recent years. This development has raised concern about the ecotoxicological risk of such industrial activities adjacent to the Athabasca River. Indeed, bitumen extraction generated large amounts of oil sands process-affected water (OSPW) which are discharged in tailing ponds in the Athabasca River watershed. This study sought to evaluate and compare the toxicity of OSPW and oil sands lixiviate water (OSLW) with a baseline (oil sands exposed to water; OSW) on a microalgae, Pseudokirchneriella subcapitata, at different concentrations (1.9, 5.5, 12.25, 25 and 37.5%, v/v). Chemical analyses of water-soluble contaminants showed that OSPW and OSLW were enriched in different elements such as vanadium (enrichment factor, EF = 66 and 12, respectively), aluminum (EF = 64 and 15, respectively), iron (EF = 52.5 and 17.1, respectively) and chromium (39 and 10, respectively). The toxicity of OSPW on cells with optimal intracellular esterase activity and chlorophyll autofluorescence (viable cells) (72 h-IC 50% < 1.9%) was 20 times higher than the one of OSW (72 h-IC 50% > 37.5%, v/v). OSLW was 4.4 times less toxic (IC 50% = 8.5%, v/v) than OSPW and 4.5 times more toxic than OSW. The inhibition of viable cell growth was significantly and highly correlated (<-0.7) with the increase of arsenic, beryllium, chromium, copper, lead, molybdenum and vanadium concentrations. The specific photosynthetic responses studied with JIP-test (rapid and polyphasic chlorophyll a fluorescence emission) showed a stimulation of the different functional parameters (efficiency of PSII to absorb energy from photons, size of effective PSII antenna and vitality of photosynthetic apparatus for energy conversion) in cultures exposed to OSPW and OSLW. To our knowledge, our study highlights the first evidence of physiological effects of OSPW and OSLW on microalgae.

  6. Experimental Study on Superfine Sand Concrete Mixed by Double Mixing Technology

    OpenAIRE

    yuqing zhao

    2013-01-01

    Traditional concept thought that medium sand and fine sand can be used to mix concrete, superfine sand can not used to mix concrete. This makes the source of superfine sand limited. With the shortage of medium sand and fine sand, it is imperative to exploit the resource of superfine sand. Superfine sand concrete is mixed by means of Double-doped Technology-ultra-fine fly ash and super plasticizer. Primary factor influencing superfine sand concrete strength is studied by orthogonal test, the o...

  7. Sulphur output from oil sands : dramatically changing Alberta's sulphur balance

    International Nuclear Information System (INIS)

    D'Aquin, G.

    2008-01-01

    This paper discussed sulphur production from Alberta's gas and oil sands industries. While sulfur derived from natural gas production in the province is expected to decline as natural gas reserves diminish, Alberta's oil sands contain high amounts of sulphur. It is not yet known how much sulphur will be produced from the province's oil sands facilities. Alberta had considerable stockpiles of sulphur in the 1970s. By 1980, inventories began to decline. By 1996, output had increased to 7.1 million tonnes. Alberta's sulphur inventory reached 9.7 million tonnes following the collapse of the Soviet Union's government mandated fertilizer industry. In 2006, sulphur supplies in Alberta reached 12 million tonnes. Reduced global output has now lowered sulphur stockpiles. Increases in sulphur prices tend to reduce market demand, and lower prices will not typically change the volume of sulphur produced as a byproduct of oil and gas operations. Bitumen-derived sulphur output is expected to exceed gas-derived sulphur output in the near future. Sulphur from oil sands processing is expected to increase by 5 million tonnes by 2017. Increased sulphur production levels in Alberta will present a significant challenge for all sectors of the hydrocarbon industry. It was concluded that developing a plan for storing, selling or disposing of the sulphur will help to ensure the profitability of oil sands operations

  8. Controlling DC permeability in cast steels

    Energy Technology Data Exchange (ETDEWEB)

    Sumner, Aaran, E-mail: aaran.sumner@nottingham.ac.uk [University of Nottingham, Nottingham University Park Campus, Nottingham NG7 2RD, England (United Kingdom); Gerada, Chris, E-mail: chris.gerada@nottingham.ac.uk [Electrical Machines, University of Nottingham, Tower Building, Nottingham NG7 2RD, England (United Kingdom); Brown, Neil, E-mail: neil.brown@cummins.com [Advanced Electrical Machines Research and Technology at Cummins Power Generation, Peterborough PE2 6FZ, England (United Kingdom); Clare, Adam, E-mail: adam.clare@nottingham.ac.uk [Advanced Manufacturing, University of Nottingham, University Park Campus, Nottingham NG7 2RD, England (United Kingdom)

    2017-05-01

    Annealing (at multiple cooling rates) and quenching (with tempering) was performed on specimens of cast steel of varying composition. The aim was to devise a method for selecting the steel with the highest permeability, from any given range of steels, and then increasing the permeability by heat treatment. Metallographic samples were imaged using optical microscopy to show the effect of the applied heat treatments on the microstructure. Commonly cast steels can have DC permeability altered by the careful selection of a heat treatment. Increases of up to 381% were achieved by annealing using a cooling rate of 6.0 °C/min. Annealing was found to cause the carbon present in the steel to migrate from grain boundaries and from within ferrite crystals into adjacent pearlite crystals. The migration of the carbon resulted in less carbon at grain boundaries and within ferrite crystals reducing the number of pinning sites between magnetic domains. This gives rise to a higher permeability. Quenching then tempering was found to cause the formation of small ferrite crystals with the carbon content of the steel predominately held in the martensitic crystal structures. The results show that with any given range of steel compositions the highest baseline DC permeability will be found with the steel that has the highest iron content and the lowest carbon content. For the samples tested in this paper a cooling rate of 4.5 °C/min resulted in the relative permeability of the sample with the highest baseline permeability, AS4, increasing from 783 to 1479 at 0.5 T. This paper shows how heat treatments commonly applied to hypoeutectoid cast steels, to improve their mechanical performance, can be used to also enhance electromagnetic properties of these alloys. The use of cast steels allows the creation of DC components for electrical machines not possible by the widely used method of stacking of electrical grade sheet steels. - Highlights: • A range of structural steels had their

  9. Controlling DC permeability in cast steels

    International Nuclear Information System (INIS)

    Sumner, Aaran; Gerada, Chris; Brown, Neil; Clare, Adam

    2017-01-01

    Annealing (at multiple cooling rates) and quenching (with tempering) was performed on specimens of cast steel of varying composition. The aim was to devise a method for selecting the steel with the highest permeability, from any given range of steels, and then increasing the permeability by heat treatment. Metallographic samples were imaged using optical microscopy to show the effect of the applied heat treatments on the microstructure. Commonly cast steels can have DC permeability altered by the careful selection of a heat treatment. Increases of up to 381% were achieved by annealing using a cooling rate of 6.0 °C/min. Annealing was found to cause the carbon present in the steel to migrate from grain boundaries and from within ferrite crystals into adjacent pearlite crystals. The migration of the carbon resulted in less carbon at grain boundaries and within ferrite crystals reducing the number of pinning sites between magnetic domains. This gives rise to a higher permeability. Quenching then tempering was found to cause the formation of small ferrite crystals with the carbon content of the steel predominately held in the martensitic crystal structures. The results show that with any given range of steel compositions the highest baseline DC permeability will be found with the steel that has the highest iron content and the lowest carbon content. For the samples tested in this paper a cooling rate of 4.5 °C/min resulted in the relative permeability of the sample with the highest baseline permeability, AS4, increasing from 783 to 1479 at 0.5 T. This paper shows how heat treatments commonly applied to hypoeutectoid cast steels, to improve their mechanical performance, can be used to also enhance electromagnetic properties of these alloys. The use of cast steels allows the creation of DC components for electrical machines not possible by the widely used method of stacking of electrical grade sheet steels. - Highlights: • A range of structural steels had their

  10. The physics of wind-blown sand and dust.

    Science.gov (United States)

    Kok, Jasper F; Parteli, Eric J R; Michaels, Timothy I; Karam, Diana Bou

    2012-10-01

    The transport of sand and dust by wind is a potent erosional force, creates sand dunes and ripples, and loads the atmosphere with suspended dust aerosols. This paper presents an extensive review of the physics of wind-blown sand and dust on Earth and Mars. Specifically, we review the physics of aeolian saltation, the formation and development of sand dunes and ripples, the physics of dust aerosol emission, the weather phenomena that trigger dust storms, and the lifting of dust by dust devils and other small-scale vortices. We also discuss the physics of wind-blown sand and dune formation on Venus and Titan.

  11. Phytoremediation of Alberta oil sand tailings using native plants and fungal endophytes

    Science.gov (United States)

    Repas, T.; Germida, J.; Kaminskyj, S.

    2012-04-01

    Fungal endophytes colonize host plants without causing disease. Some endophytes confer plant tolerance to harsh environments. One such endophyte, Trichoderma harzianum strain TSTh20-1, was isolated from a plant growing on Athabasca oil sand tailings. Tailing sands are a high volume waste product from oil sand extraction that the industry is required to remediate. Tailing sands are low in organic carbon and mineral nutrients, and are hydrophobic due to residual polyaromatic hydrocarbons. Typically, tailing sands are remediated by planting young trees in large quantities of mulch plus mineral fertilizer, which is costly and labour intensive. In greenhouse trials, TSTh20-1 supports growth of tomato seedlings on tailing sands without fertilizer. The potential use of TSTh20-1 in combination with native grasses and forbs to remediate under field conditions is being assessed. Twenty-three commercially available plant species are being screened for seed germination and growth on tailing sands in the presence of TSTh20-1. The best candidates from this group will be used in greenhouse and small scale field trials. Potential mechanisms that contribute to endophyte-induced plant growth promotion, such as plant hormone production, stress tolerance, mineral solubilization, and uptake are also being assessed. As well, TSTh20-1 appears to be remarkably frugal in its nutrient requirements and the possibility that this attribute is characteristic of other plant-fungal endophytes from harsh environments is under study.

  12. Sand Dunes with Frost

    Science.gov (United States)

    2004-01-01

    9 May 2004 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a suite of frost-covered sand dunes in the north polar region of Mars in early spring, 2004. The dunes indicate wind transport of sand from left to right (west to east). These landforms are located near 78.1oN, 220.8oW. This picture is illuminated by sunlight from the lower left and covers an area about 3 km (1.9 mi) across.

  13. Beta dose due to monazite sands of Kerala

    International Nuclear Information System (INIS)

    Massand, O.P.; Venkataraman, G.; Dhairyawan, M.P.

    1977-01-01

    The heavy black mineral sands of the sea coast of Kerala in India contain patches of monazite in concentrations varying between 0.5 to 5%. Monazite contains about 9.5% of thorium oxide (ThO 2 ) and 0.35% of uranium oxide (U 3 O 8 ). The high natural background radiation of this area had been a matter of concern and reports on the measured gamma radiation levels have appeared. The dose contribution due to beta rays emitted by the materials in the sand has been calculated using Loevinger's formula. The annual beta dose is of the order of 4200 mrad and 740 mrad at a height of 5 and 200 cm respectively from ground level. (author)

  14. Bacterial nitrogen fixation in sand bioreactors treating winery wastewater with a high carbon to nitrogen ratio.

    Science.gov (United States)

    Welz, Pamela J; Ramond, Jean-Baptiste; Braun, Lorenz; Vikram, Surendra; Le Roes-Hill, Marilize

    2018-02-01

    Heterotrophic bacteria proliferate in organic-rich environments and systems containing sufficient essential nutrients. Nitrogen, phosphorus and potassium are the nutrients required in the highest concentrations. The ratio of carbon to nitrogen is an important consideration for wastewater bioremediation because insufficient nitrogen may result in decreased treatment efficiency. It has been shown that during the treatment of effluent from the pulp and paper industry, bacterial nitrogen fixation can supplement the nitrogen requirements of suspended growth systems. This study was conducted using physicochemical analyses and culture-dependent and -independent techniques to ascertain whether nitrogen-fixing bacteria were selected in biological sand filters used to treat synthetic winery wastewater with a high carbon to nitrogen ratio (193:1). The systems performed well, with the influent COD of 1351 mg/L being reduced by 84-89%. It was shown that the nitrogen fixing bacterial population was influenced by the presence of synthetic winery effluent in the surface layers of the biological sand filters, but not in the deeper layers. It was hypothesised that this was due to the greater availability of atmospheric nitrogen at the surface. The numbers of culture-able nitrogen-fixing bacteria, including presumptive Azotobacter spp. exhibited 1-2 log increases at the surface. The results of this study confirm that nitrogen fixation is an important mechanism to be considered during treatment of high carbon to nitrogen wastewater. If biological treatment systems can be operated to stimulate this phenomenon, it may obviate the need for nitrogen addition. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Biopolymer system for permeability modification in porous media

    Energy Technology Data Exchange (ETDEWEB)

    Stepp, A.K.; Bryant, R.S.; Llave, F.M. [BMD-Oklahoma, Inc., Bartlesville, OK (United States)] [and others

    1995-12-31

    New technologies are needed to reduce the current high rate of well abandonment. Improved sweep efficiency, reservoir conformance, and permeability modification can have a significant impact on oil recovery processes. Microorganisms can be used to selectively plug high-permeability zones to improve sweep efficiency and impart conformance control. Studies of a promising microbial system for polymer production were conducted to evaluate reservoir conditions in which this system would be effective. Factors which can affect microbial growth and polymer production include salinity, pH, temperature, divalent ions, presence of residual oil, and rock matrix. Flask tests and coreflooding experiments were conducted to optimize and evaluate the effectiveness of this system. Nuclear magnetic resonance imaging (NMRI) was used to visualize microbial polymer production in porous media. Changes in fluid distribution within the pore system of the core were detected.

  16. Relationships between sand and water quality at recreational beaches.

    Science.gov (United States)

    Phillips, Matthew C; Solo-Gabriele, Helena M; Piggot, Alan M; Klaus, James S; Zhang, Yifan

    2011-12-15

    Enterococci are used to assess the risk of negative human health impacts from recreational waters. Studies have shown sustained populations of enterococci within sediments of beaches but comprehensive surveys of multiple tidal zones on beaches in a regional area and their relationship to beach management decisions are limited. We sampled three tidal zones on eight South Florida beaches in Miami-Dade and Broward counties and found that enterococci were ubiquitous within South Florida beach sands although their levels varied greatly both among the beaches and between the supratidal, intertidal and subtidal zones. The supratidal sands consistently had significantly higher (p sand) than the other two zones. Levels of enterococci within the subtidal sand correlated with the average level of enterococci in the water (CFU/100mL) for the season during which samples were collected (r(s) = 0.73). The average sand enterococci content over all the zones on each beach correlated with the average water enterococci levels of the year prior to sand samplings (r(s) = 0.64) as well as the average water enterococci levels for the month after sand samplings (r(s) = 0.54). Results indicate a connection between levels of enterococci in beach water and sands throughout South Florida's beaches and suggest that the sands are one of the predominant reservoirs of enterococci impacting beach water quality. As a result, beaches with lower levels of enterococci in the sand had fewer exceedences relative to beaches with higher levels of sand enterococci. More research should focus on evaluating beach sand quality as a means to predict and regulate marine recreational water quality. Copyright © 2011 Elsevier Ltd. All rights reserved.

  17. Recovery of ammonia and production of high-grade phosphates from side-stream digester effluents using gas-permeable membranes

    Science.gov (United States)

    Phosphorus recovery was combined with ammonia recovery using gas-permeable membranes. In a first step, the ammonia and alkalinity were removed from municipal side-stream wastewater using low-rate aeration and a gas-permeable membrane manifold. In a second step, the phosphorus was removed using magne...

  18. Permeability Estimation of Rock Reservoir Based on PCA and Elman Neural Networks

    Science.gov (United States)

    Shi, Ying; Jian, Shaoyong

    2018-03-01

    an intelligent method which based on fuzzy neural networks with PCA algorithm, is proposed to estimate the permeability of rock reservoir. First, the dimensionality reduction process is utilized for these parameters by principal component analysis method. Further, the mapping relationship between rock slice characteristic parameters and permeability had been found through fuzzy neural networks. The estimation validity and reliability for this method were tested with practical data from Yan’an region in Ordos Basin. The result showed that the average relative errors of permeability estimation for this method is 6.25%, and this method had the better convergence speed and more accuracy than other. Therefore, by using the cheap rock slice related information, the permeability of rock reservoir can be estimated efficiently and accurately, and it is of high reliability, practicability and application prospect.

  19. Influence of transport infrastructure on water permeability of soils of Western Siberia

    Science.gov (United States)

    Eremin, Dmitry; Eremina, Diana

    2017-10-01

    Correctly designed transport infrastructure should support the current economic relations. It should provide a reserve for development of economy of the region in the future. In Western Siberia, new highways are actively being built and major repairs of the operating roads are being conducted. Local materials are often used in the roadbed construction. In the Tyumen region, it is usually sandy silt and clayey sand. The soil has unfavourable physico-mechanical properties. The soil is prone to water and wind erosion. This type of ground gets on the adjacent to the road territory. Studies on the influence of highways on soil permeability were carried out on the basis of the federal highway Tyumen-Omsk. Three types of soils, which are actively used in the agricultural sector, were considered. It is found that the content of particles with the size less than 0.01 mm reaches 32% in the soil used in road construction. It is noted that a part of these particles accumulates on the adjacent to the road territory since it is being washed out from roadbed. The content of physical clay (initial values. The width of active accumulation of silt particles reaches 15-20 m along the roads. The soils at the distance up to 10 m from the highway are almost impermeable to water. Absence of a natural hydrological drain, results in the territory bogging. An inverse close correlation was established between the content of physical clay (<0.01 mm) and water permeability (r = 0.90).

  20. Plantar pressure distribution of ostrich during locomotion on loose sand and solid ground

    Directory of Open Access Journals (Sweden)

    Rui Zhang

    2017-07-01

    Full Text Available Background The ostrich is a cursorial bird with extraordinary speed and endurance, especially in the desert, and thus is an ideal large-scale animal model for mechanic study of locomotion on granular substrate. Methods The plantar pressure distributions of ostriches walking/running on loose sand/solid ground were recorded using a dynamic pressure plate. Results The center of pressure (COP on loose sand mostly originated from the middle of the 3rd toe, which differed from the J-shaped COP trajectory on solid ground. At mid-stance, a high-pressure region was observed in the middle of the 3rd toe on loose sand, but three high-pressure regions were found on solid ground. The gait mode significantly affected the peak pressures of the 3rd and 4th toes (p = 1.5 × 10−6 and 2.39 × 10−8, respectively, but not that of the claw (p = 0.041. The effects of substrate were similar to those of the gait mode. Discussion Ground reaction force trials of each functional part showed the 3rd toe bore more body loads and the 4th toe undertook less loads. The pressure distributions suggest balance maintenance on loose sand was provided by the 3rd and 4th toes and the angle between their length axes. On loose sand, the middle of the 3rd toe was the first to touch the sand with a smaller attack angle to maximize the ground reaction force, but on solid ground, the lateral part was the first to touch the ground to minimize the transient loading. At push-off, the ostrich used solidification properties of granular sand under the compression of the 3rd toe to generate sufficient traction.

  1. Frictional stability-permeability relationships for fractures in shales

    Science.gov (United States)

    Fang, Yi; Elsworth, Derek; Wang, Chaoyi; Ishibashi, Takuya; Fitts, Jeffrey P.

    2017-03-01

    There is wide concern that fluid injection in the subsurface, such as for the stimulation of shale reservoirs or for geological CO2 sequestration (GCS), has the potential to induce seismicity that may change reservoir permeability due to fault slip. However, the impact of induced seismicity on fracture permeability evolution remains unclear due to the spectrum of modes of fault reactivation (e.g., stable versus unstable). As seismicity is controlled by the frictional response of fractures, we explore friction-stability-permeability relationships through the concurrent measurement of frictional and hydraulic properties of artificial fractures in Green River shale (GRS) and Opalinus shale (OPS). We observe that carbonate-rich GRS shows higher frictional strength but weak neutral frictional stability. The GRS fracture permeability declines during shearing while an increased sliding velocity reduces the rate of permeability decline. By comparison, the phyllosilicate-rich OPS has lower friction and strong stability while the fracture permeability is reduced due to the swelling behavior that dominates over the shearing induced permeability reduction. Hence, we conclude that the friction-stability-permeability relationship of a fracture is largely controlled by mineral composition and that shale mineral compositions with strong frictional stability may be particularly subject to permanent permeability reduction during fluid infiltration.

  2. An asymptotic model of seismic reflection from a permeable layer

    Energy Technology Data Exchange (ETDEWEB)

    Silin, D.; Goloshubin, G.

    2009-10-15

    Analysis of compression wave propagation in a poroelastic medium predicts a peak of reflection from a high-permeability layer in the low-frequency end of the spectrum. An explicit formula expresses the resonant frequency through the elastic moduli of the solid skeleton, the permeability of the reservoir rock, the fluid viscosity and compressibility, and the reservoir thickness. This result is obtained through a low-frequency asymptotic analysis of Biot's model of poroelasticity. A review of the derivation of the main equations from the Hooke's law, momentum and mass balance equations, and Darcy's law suggests an alternative new physical interpretation of some coefficients of the classical poroelasticity. The velocity of wave propagation, the attenuation factor, and the wave number, are expressed in the form of power series with respect to a small dimensionless parameter. The absolute value of this parameter is equal to the product of the kinematic reservoir fluid mobility and the wave frequency. Retaining only the leading terms of the series leads to explicit and relatively simple expressions for the reflection and transmission coefficients for a planar wave crossing an interface between two permeable media, as well as wave reflection from a thin highly-permeable layer (a lens). Practical applications of the obtained asymptotic formulae are seismic modeling, inversion, and at-tribute analysis.

  3. Permeability, porosity and compressive strength of self-compacting concrete

    Directory of Open Access Journals (Sweden)

    Valcuende, M.O.

    2005-12-01

    Full Text Available Most deterioration affecting the durability of self-compacting concrete structures is mediated by water penetration in the concrete, a condition related to its porous structure. The present study analyzes these two factors. To this end, two types of concrete were prepared, a self-compacting and a traditional vibrated concrete, with different W/C ratios and different types of cement. The results of low-pressure water testing to evaluate permeability and analyses to determine compressive strength and pore size distribution showed that self-compacting concrete has lower capillary porosity than traditional concrete, which would explain its greater resistance to water penetration. Such concrete likewise reached higher strength values, except where large proportions of lime powder with low sand equivalents were used in its manufacture, when lower strength was recorded. Lastly, the depth of water penetration and compressive strength were found to be linearly correlated. That correlation was seen to depend, in turn, on the type of concrete, since for any given strength level, self-compacting concrete was less permeable than the traditional material.

    En este trabajo experimental se estudia la penetración de agua en hormigones autocompactables, analizando al mismo tiempo su estructura porosa, pues gran parte de los procesos de deterioro que afectan a la durabilidad de las estructuras están condicionados por estos dos aspectos. Para ello se han fabricado dos tipos de hormigones, uno autocompactable y otro tradicional vibrado, con diferentes relaciones A/C y distintos tipos de cemento. Tras determinar la permeabilidad al agua bajo presión, la resistencia a compresión y las distribuciones de tamaño de poro, los resultados obtenidos ponen de manifiesto que los hormigones autocompactables presentan menor porosidad capilar que los tradicionales, lo que les confiere mejores prestaciones frente a la penetración de agua. Asimismo, dichos hormigones

  4. Controls on the abruptness of gravel-sand transitions

    Science.gov (United States)

    Venditti, J. G.; Church, M. A.; Lamb, M. P.; Domarad, N.; Rennie, C. D.

    2014-12-01

    As gravel-bedded rivers fine downstream, they characteristically exhibit an abrupt transition from gravel- to sand-bed. This is the only abrupt transition in grain-size that occurs in the fluvial system and has attracted considerable attention. A number of competing theories have been proposed to account for the abruptness of the transition, including base-level control, attrition of ~10mm gravel to produce sand, and sediment sorting processes. The prevailing theory for the emergence of abrupt transitions is size selective sorting of bimodal sediment wherein gravel deposits due to downstream declining shear stress, fining the bedload until a sand-bed emerges. We explored this hypothesis by examining grain-size, shear stress, gravel mobility and sand suspension thresholds through the gravel-sand transition (GST) of the Fraser River, British Columbia. The Fraser GST is an arrested gravel wedge with patches of gravel downstream of the wedge forming a diffuse extension. There is an abrupt change in bed slope through the transition that leads to an abrupt change in shear stress. The GST, bed-slope change and backwater caused by the ocean are all coincident spatially, which enhances the sharpness of the GST. Interestingly, the bimodal reach of the river occurs downstream of the GST and exhibits no downstream gradients in shear stress, suspended sediment flux, gravel mobility or sand suspension thresholds. This calls into question the prevailing theory for the emergence of an abrupt GST by size selective sorting. We provide evidence, both empirical and theoretical, that suggests the emergence of an abrupt GST is caused by rapid deposition of sand when fine gravel deposits. We argue that the emergence of gravel-sand transitions is a consequence of gravel-bedded rivers adopting a steeper slope than sand-bedded rivers. The abruptness arises because the bed slope required to convey the gravel load fixes the distal location of a terminal gravel wedge, and once the river has

  5. Decontamination of Uranium-Contaminated Soil Sand Using Supercritical CO2 with a TBP–HNO3 Complex

    Directory of Open Access Journals (Sweden)

    Kwangheon Park

    2015-09-01

    Full Text Available An environmentally friendly decontamination process for uranium-contaminated soil sand is proposed. The process uses supercritical CO2 as the cleaning solvent and a TBP–HNO3 complex as the reagent. Four types of samples (sea sand and coarse, medium, and fine soil sand were artificially contaminated with uranium. The effects of the amount of the reagent, sand type, and elapsed time after the preparation of the samples on decontamination were examined. The extraction ratios of uranium in all of the four types of sand samples were very high when the time that elapsed after preparation was less than a few days. The extraction ratio of uranium decreased in the soil sand with a higher surface area as the elapsed time increased, indicating the possible formation of chemisorbed uranium on the surface of the samples. The solvent of supercritical CO2 seemed to be very effective in the decontamination of soil sand. However, the extraction of chemisorbed uranium in soil sand may need additional processes, such as the application of mechanical vibration and the addition of bond-breaking reagents.

  6. Oil sands to the rescue: oil sand microbial communities can degrade recalcitrant alkyl phenyl alkanoic acids

    Energy Technology Data Exchange (ETDEWEB)

    Whitby, Corinne [University of Essex (Canada)], email: cwhitby@essex.ac.uk

    2011-07-01

    Almost half of all global oil reserves are found as biodegraded heavy oils found in vast tar sand deposits located in North and South America and these account for 47% of Canadian oil production. Oil sand extraction generates large amounts of toxic waste water, known as oil sand process waters (OSPW), that are stored in large tailing ponds that contain toxic compounds like naphthenic acids (NAs). The presence of NAs creates problems like toxicity, corrosion, and the formation of calcium napthenate deposits which block pipelines and other infrastructure and need to be removed. This paper presents oil sand microbial communities that can degrade these NAs. The approach is to apply new aliphatic and aromatic NAs as substrates to supplement and identify NA degrading microbes and also to identify the metabolites produced and explain NA degradation pathways and the functional genes involved. The chemistry and the processes involved are explained. From the results, it is suggested that pure cultures of P. putida KT2440 be used against NAs.

  7. Intrinsic and extrinsic permeability of ferromagnetic thin films and multilayers for frequency dependence: comparison between theory and experiment

    International Nuclear Information System (INIS)

    Berthault, A.; Durbin, F.; Russat, J.

    1992-01-01

    Soft ferromagnetic thin films are attractive materials for read/write head applications because they exhibit a high magnetic permeability in the hundred MHz range. By contrast, due to their low electrical resistivity, their processability at higher frequency is somewhat limited. Using Maxwell equations and the geometry of the processed material, we have developed a theoretical model of the frequency-dependent magnetic permeability useful for multilayers design. We have distinguished different cases: - extrinsic (measured) vs intrinsic permeability in magnetic thin films and magnetic-insulator multilayers, - intrinsic vs extrinsic permeability in magnetic thin films, computes by the Newton iterative method. Using the well-know Landau-Lifshitz model for high frequency permeability, we have compared experimental and theoretical results. (orig.)

  8. The comparison of properties and cost of material use of natural rubber and sand in manufacturing cement mortar for construction sub-base layer

    Science.gov (United States)

    Rahman, R.; Nemmang, M. S.; Hazurina, Nor; Shahidan, S.; Khairul Tajuddin Jemain, Raden; Abdullah, M. E.; Hassan, M. F.

    2017-11-01

    The main issue related to this research was to examine the feasibility of natural rubber SMR 20 in the manufacturing of cement mortar for sub-base layer construction. Subbase layers have certain functions that need to be fulfilled in order to assure strong and adequate permeability of pavement performance. In a pavement structure, sub-base is below the base and serves as the foundation for the overall pavement structure, transmitting traffic loads to the sub-grade and providing drainage. Based on this research, the natural rubber, SMR 20 was with the percentages of 0%, 5%, 10% and 15% to mix with sand in the manufacture of the cement mortar. This research describes some of the properties and cost of the materials for the natural rubber and sand in cement mortar manufacturing by laboratory testing. Effects of the natural rubber replacement on mechanical properties of mortar were investigated by laboratory testing such as compressive strength test and density. This study obtained the 5% of natural rubber replaced in sand can achieved the strength of normal mortar after 7 days and 28 days. The strength of cement mortar depends on the density of cement mortar. According to the cost of both materials, sand shows the lower cost in material for the cement mortar manufacturing than the uses of natural rubber. Thus, the convectional cement mortar which used sand need lower cost than the modified rubber cement mortar and the most economical to apply in industrial. As conclusion, the percentage of 5% natural rubber in the cement mortar would have the same with normal cement mortar in terms of the strength. However, in terms of the cost of the construction, it will increase higher than cost of normal cement mortar production. So that, this modified cement mortar is not economical for the road sub-base construction.

  9. Modelling of water permeability in cementitious materials

    DEFF Research Database (Denmark)

    Guang, Ye; Lura, Pietro; van Breugel, K.

    2006-01-01

    This paper presents a network model to predict the permeability of cement paste from a numerical simulation of its microstructure. Based on a linked list pore network structure, the effective hydraulic conductivity is estimated and the fluid flow is calculated according to the Hagen-Poiseuille law....... The pressure gradient at all nodes is calculated with the Gauss elimination method and the absolute permeability of the pore network is calculated directly from Darcy's law. Finally, the permeability model is validated by comparison with direct water permeability measurements. According to this model...

  10. Influence of core sand properties on flow dynamics of core shooting process based on experiment and multiphase simulation

    Directory of Open Access Journals (Sweden)

    Chang-jiang Ni

    2017-03-01

    Full Text Available The influence of core sand properties on flow dynamics was investigated synchronously with various core sands, transparent core-box and high-speed camera. To confirm whether the core shooting process has significant turbulence, the flow pattern of sand particles in the shooting head and core box was reproduced with colored core sands. By incorporating the kinetic theory of granular flow (KTGF, kinetic-frictional constitutive correlation and turbulence model, a two-fluid model (TFM was established to study the flow dynamics of the core shooting process. Two-fluid model (TFM simulations were then performed and a areasonable agreement was achieved between the simulation and experimental results. Based on the experimental and simulation results, the effects of turbulence, sand density, sand diameter and binder ratio were analyzed in terms of filling process, sand volume fraction (αs and sand velocity (Vs.

  11. Cocrystals of Hydrochlorothiazide: Solubility and Diffusion/Permeability Enhancements through Drug-Coformer Interactions.

    Science.gov (United States)

    Sanphui, Palash; Devi, V Kusum; Clara, Deepa; Malviya, Nidhi; Ganguly, Somnath; Desiraju, Gautam R

    2015-05-04

    Hydrochlorothiazide (HCT) is a diuretic and a BCS class IV drug with low solubility and low permeability, exhibiting poor oral absorption. The present study attempts to improve the physicochemical properties of the drug using a crystal engineering approach with cocrystals. Such multicomponent crystals of HCT with nicotinic acid (NIC), nicotinamide (NCT), 4-aminobenzoic acid (PABA), succinamide (SAM), and resorcinol (RES) were prepared using liquid-assisted grinding, and their solubilities in pH 7.4 buffer were evaluated. Diffusion and membrane permeability were studied using a Franz diffusion cell. Except for the SAM and NIC cocrystals, all other binary systems exhibited improved solubility. All of the cocrystals showed improved diffusion/membrane permeability compared to that of HCT with the exception of the SAM cocrystal. When the solubility was high, as in the case of PABA, NCT, and RES cocrystals, the flux/permeability dropped slightly. This is in agreement with the expected interplay between solubility and permeability. Improved solubility/permeability is attributed to new drug-coformer interactions. Cocrystals of SAM, however, showed poor solubility and flux. This cocrystal contains a primary sulfonamide dimer synthon similar to that of HCT polymorphs, which may be a reason for its unusual behavior. Hirshfeld surface analysis was carried out in all cases to determine whether a correlation exists between cocrystal permeability and drug-coformer interactions.

  12. Magnetic Characterization of Sand and Boulder Samples from Citarum River and Their Origin

    Directory of Open Access Journals (Sweden)

    Sudarningsih

    2017-09-01

    Full Text Available The Citarum River is a nationally strategic river located near Bandung, the capital city of West Java Province. The feasibility of using magnetic methods for monitoring pollution level is currently being tested in the river. Due to its location in a volcanic area, the sediments from the river are expected to be highly magnetic. In this study, sand and boulder samples from Balekambang, a relatively pristine upstream area of the river, were subjected to magnetic and geochemical characterizations to establish the baseline for unpolluted sediments. Such baseline is important for future magnetic monitoring of sediments in the river. The mass-specific magnetic susceptibility of boulder samples was found to be varied from 819.2 to 2340.5 × 10-8m3 kg-1 while that of sand samples varied from 2293.9 to 3845.3 × 10-8m3 kg-1. These high magnetic susceptibility values infer that river sediments are highly magnetic even before being contaminated by industrial and household wastes. The predominant magnetic mineral in sand samples was multi-domain magnetite while that in boulder samples was single to pseudo-single domain magnetite. These differences were supported by the results from petrographic and XRF analyses, implying that the sand and boulder samples originated from different geological formations.

  13. Stakeholder relations in the oil sands : managing uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-05-15

    Alberta's oil sands are now at the crossroads of a series of significant and complex global issues that will require careful negotiation by all stakeholders involved in the oil sands industry. This paper discussed methods of managing uncertainty and risk related to the oil sands industry's agenda for the future. Oil sands developers must continue to secure permission from communities and other key stakeholders in order to develop oil sand projects. Stakeholder relations between oil sands operators, First Nations, and Metis Nation communities must ensure that respect is maintained while environmental impacts are minimized and long-term economic benefits are secured for all parties. Environmental non-governmental organizations (ENGOs) must ensure that oil sands resources are developed responsibly, and that environmental standards are maintained. Seven key shifts in stakeholder relations resulting from the recent economic crisis were identified. These included (1) withdrawal from the multi-stakeholder process, (2) increased focus on government to demonstrate policy leadership, (3) a stronger push from ENGOs to express environmental concerns, (4) global lobby and public relations efforts from ENGOs, (5) companies retreating to local community stakeholders, (6) more active demands from First Nations and Metis Nations groups, and (7) companies challenging ENGO campaigns. The study concluded by suggesting that government leadership is needed to clear policy and regulatory frameworks for Canada's oil sands.

  14. Providing floating capabilities in latest-generation sand screens

    Energy Technology Data Exchange (ETDEWEB)

    Bowen, E.G.; Coronado, M.P. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Baker Hughes, Houston, TX (United States)

    2008-10-15

    Alternative production methods are needed for the massive reserves located in the bitumen region of Canada's tar sands. The area has over 100 installations of sand screens/slotted liners in both injection and production legs using steam-assisted gravity drainage (SAGD) technology. Multiple wells must be drilled from a single pad because of the sensitive nature of the environment. With significant depths of these wells, a floating sand screen provides assurance that the sand screen will reach the desired depth. Paraffin is generally used to plug the flow access of the screen during installation. This paper discussed a new technology that has been developed to allow for sand screen installations without relying on paraffin wax to withstand differential pressure. The new technology uses a hydro-mechanical valving system incorporated into the screen design to temporarily close off the screen while being run in the hole. The paper described how the technology could provide a reliable, time-saving solution for SAGD installations when floating sand control screens are needed. The paper discussed current technology and its limitations, sand screen installation, screen design for floating applications, and additional applications. It was concluded that this technology solution provides a unique alternative to the methods currently used to install sand screens with SAGD technology in the fast growing Canadian market for bitumen recovery. 2 refs., 5 figs.

  15. Long-term evolution of sand waves in the Marsdiep inlet. II: Relation to hydrodynamics

    Science.gov (United States)

    Buijsman, Maarten C.; Ridderinkhof, Herman

    2008-05-01

    A discussion is presented about the mechanisms that govern the spatial and seasonal variability in sand-wave height and migration speed in the 4 km wide Marsdiep tidal inlet, the Netherlands. Since 1998, current velocities and water depths have been recorded with an ADCP that is mounted under the ferry 'Schulpengat'. In this paper, the current measurements were used to explain the sand-wave observations presented in Buijsman and Ridderinkhof [this issue. Long-term evolution of sand waves in the Marsdiep inlet. I: high-resolution observations. Continental Shelf Research, doi: 10.1016/j.csr.2007.10.011]. Across nearly the entire inlet, the sand waves migrate in the flood direction. In the flood-dominated southern part of the inlet, the 'measured' (i.e. based on sand-wave shape and migration speed) and predicted bedload transport agree in direction, magnitude, and trends, whereas in the ebb-dominated northern part the predicted bedload and suspended load transport is opposite to the sand-wave migration. In the southern part, 55% of the bedload transport is due to tidal asymmetries and 45% due to residual currents. In addition to the well-known tidal asymmetries, asymmetries that arise from the interaction of M2 and its overtides with S2 and its compound tides are also important. It is hypothesised that in the northern part of the inlet the advection of suspended sand and lag effects govern the sand-wave migration. The relative importance of suspended load transport also explains why the sand waves have smaller lee-slope angles, are smaller, more rounded, and more three-dimensional in the northern half of the inlet. The sand waves in this part of the inlet feature the largest seasonal variability in height and migration speed. This seasonal variability may be attributed to the tides or a seasonal fluctuation in fall velocity. In both cases sediment transport is enhanced in winter, increasing sand-wave migration and decreasing sand-wave height. The influence of storms

  16. K West Basin Sand Filter Backwash Sample Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Fiskum, Sandra K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Smoot, Margaret R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Coffey, Deborah S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Pool, Karl N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-03-01

    A sand filter is used to help maintain water clarity at the K West Basin where highly radioactive sludge is stored. Eventually that sand filter will require disposal. The radionuclide content of the solids trapped in the sand filter will affect the selection of the sand filter disposal pathway. The Pacific Northwest National Laboratory (PNNL) was contracted by the K Basin Operations & Plateau Remediation Project (operations contractor CH2M Hill) to analyze the radionuclide content of the solids collected from the backwash of the K West Basin sand filter. The radionuclide composition in the sand filter backwash solids will be used by CH2M Hill to determine if the sand filter media and retained sludge solids will be designated as transuranic waste for disposal purposes or can be processed through less expensive means. On October 19, 2015, K Basin Operations & Plateau Remediation Project staff backwashed the sand filter into the North Load-Out Pit (NLOP) and immediately collected sample slurry from a sampling tube positioned 24 in. above the NLOP floor. The 764 g sand filter backwash slurry sample, KW-105 SFBW-001, was submitted to PNNL for analysis on October 20, 2015. Solids from the slurry sample were consolidated into two samples (i.e., a primary and a duplicate sample) by centrifuging and measured for mass (0.82 g combined – wet centrifuged solids basis) and volume (0.80 mL combined). The solids were a dark brown/orange color, consistent with iron oxide/hydroxide. The solids were dried; the combined dry solids mass was 0.1113 g, corresponding to 0.0146 weight percent (wt%) solids in the original submitted sample slurry. The solids were acid-digested using nitric and hydrochloric acids. Insoluble solids developed upon dilution with 0.5 M HNO3, corresponding to an average 6.5 wt% of the initial dry solids content. The acid digestate and insoluble solids were analyzed separately by gamma spectrometry. Nominally, 7.7% of the 60Co was present

  17. Compositional Signatures in Acoustic Backscatter Over Vegetated and Unvegetated Mixed Sand-Gravel Riverbeds

    Science.gov (United States)

    Buscombe, D.; Grams, P. E.; Kaplinski, M. A.

    2017-10-01

    Multibeam acoustic backscatter has considerable utility for remote characterization of spatially heterogeneous bed sediment composition over vegetated and unvegetated riverbeds of mixed sand and gravel. However, the use of high-frequency, decimeter-resolution acoustic backscatter for sediment classification in shallow water is hampered by significant topographic contamination of the signal. In mixed sand-gravel riverbeds, changes in the abiotic composition of sediment (such as homogeneous sand to homogeneous gravel) tend to occur over larger spatial scales than is characteristic of small-scale bedform topography (ripples, dunes, and bars) or biota (such as vascular plants and periphyton). A two-stage method is proposed to filter out the morphological contributions to acoustic backscatter. First, the residual supragrain-scale topographic effects in acoustic backscatter with small instantaneous insonified areas, caused by ambiguity in the local (beam-to-beam) bed-sonar geometry, are removed. Then, coherent scales between high-resolution topography and backscatter are identified using cospectra, which are used to design a frequency domain filter that decomposes backscatter into the (unwanted) high-pass component associated with bedform topography (ripples, dunes, and sand waves) and vegetation, and the (desired) low-frequency component associated with the composition of sediment patches superimposed on the topography. This process strengthens relationships between backscatter and sediment composition. A probabilistic framework is presented for classifying vegetated and unvegetated substrates based on acoustic backscatter at decimeter resolution. This capability is demonstrated using data collected from diverse settings within a 386 km reach of a canyon river whose bed varies among sand, gravel, cobbles, boulders, and submerged vegetation.

  18. Compositional signatures in acoustic backscatter over vegetated and unvegetated mixed sand-gravel riverbeds

    Science.gov (United States)

    Buscombe, Daniel; Grams, Paul E.; Kaplinski, Matt A.

    2017-01-01

    Multibeam acoustic backscatter has considerable utility for remote characterization of spatially heterogeneous bed sediment composition over vegetated and unvegetated riverbeds of mixed sand and gravel. However, the use of high-frequency, decimeter-resolution acoustic backscatter for sediment classification in shallow water is hampered by significant topographic contamination of the signal. In mixed sand-gravel riverbeds, changes in the abiotic composition of sediment (such as homogeneous sand to homogeneous gravel) tend to occur over larger spatial scales than is characteristic of small-scale bedform topography (ripples, dunes, and bars) or biota (such as vascular plants and periphyton). A two-stage method is proposed to filter out the morphological contributions to acoustic backscatter. First, the residual supragrain-scale topographic effects in acoustic backscatter with small instantaneous insonified areas, caused by ambiguity in the local (beam-to-beam) bed-sonar geometry, are removed. Then, coherent scales between high-resolution topography and backscatter are identified using cospectra, which are used to design a frequency domain filter that decomposes backscatter into the (unwanted) high-pass component associated with bedform topography (ripples, dunes, and sand waves) and vegetation, and the (desired) low-frequency component associated with the composition of sediment patches superimposed on the topography. This process strengthens relationships between backscatter and sediment composition. A probabilistic framework is presented for classifying vegetated and unvegetated substrates based on acoustic backscatter at decimeter resolution. This capability is demonstrated using data collected from diverse settings within a 386 km reach of a canyon river whose bed varies among sand, gravel, cobbles, boulders, and submerged vegetation.

  19. Revegetation and management of tailings sand slopes from tar sand extraction: 1978 results

    Energy Technology Data Exchange (ETDEWEB)

    Rowell, M J

    1979-01-01

    The results are reported of research into the revegetation of two areas on a steeply sloping dike composed of tailings sand from tar sand extraction at the Great Canadian Oil Sand Limited plant at Fort McMurray, Alberta. One area was seeded with three pasture grasses and two legumes in 1971 after the slope surface had been mixed with peat to a depth of 15 cm. A second area had been amended with peat or peat and overburden and differing rates of fertilizer added. A mix containing nine grasses, four legumes, and oats, as a companion crop, was seeded in July 1976. The objectives of the research were to study methods for the establishment of a stable vegetative cover that would prevent erosion of the slope and, in time, might become a self maintaining unit. Tillage of soil amendments to a depth of 15 cm and 30 cm were compared in promoting deeper rooting and stabilizing of the slope.

  20. The behavior of gaseous iodine in sand

    International Nuclear Information System (INIS)

    Takahashi, Kanji

    1974-01-01

    Radioactive iodine gas was passed through 10 different sands collected at rivers and hills. The relation between the amount of the loaded gas and the amount of adsorbed gas was determined at room temperature, 50 -- 60 0 C, and 90 -- 100 0 C under humidity of 2 sand. This amount was about 1 -- 3 times as much as that of monomolecular membrane adsorption, 0.2 -- 0.3 μg/cm 2 . The decrease of adsorption amount that accompanies the increase of humidity is attributable to the decrease of effective surface area of sand due to the presence of water. The transport of iodine in sand was studied by passing gaseous iodine through a glass tubing packed with sand. The distribution in the flow direction of iodine indicated that the ease of desorption depends upon the situation of adsorption. Easily desorbed case was named Henry type adsorption. Hardly desorbed case was named absorption type. Discussion is made on experimental results. (Fukutomi, T.)