International Nuclear Information System (INIS)

Starting from the Molten Salt Breeder Reactor project of Oak-Ridge, we have performed parametric studies in terms of safety coefficients, reprocessing requirements and breeding capabilities. In the frame of this major re-evaluation of the molten salt reactor (MSR), we have developed a new concept called Molten Salt Fast Reactor or MSFR, based on the Thorium fuel cycle and a fast neutron spectrum. This concept has been selected for further studies by the MSR steering committee of the Generation IV International Forum in 2009. Our reactor's studies of the MSFR concept rely on numerical simulations making use of the MCNP neutron transport code coupled with a code for materials evolution which resolves the Bateman's equations giving the population of each nucleus inside each part of the reactor at each ...

International Nuclear Information System (INIS)

Consideration is given to results of investigation into thorium complexing with morin (H_2Mor) in extraction systems containing different carboxylic acids as well as different salt background. The obtained data enabled to suggest the method of photometric determination of thorium in the form of Th(HMor)_2Benz_2 different-ligand complex (where Benz-anion of benzilic acid) with 0.25 #mu#g/ml detection limit.

International Nuclear Information System (INIS)

Gamma-ray spectrometric analysis was employed to determine the nuclides formed in thorium by neutron irradiation. Thorium sample was irradiated by neutron from a pure thermal neutron field, neutron field of Cd ratio of about 4, and epithermal neutron field, respectively. The former irradiation was carried out in a thermal neutron column provided for medical uses of neutrons, and the latters were done in the F-ring position of TRIGA II research reactor of Musashi Institute of Technology. The gamma-ray spectra were obtained and analyzed by employing a fully automatic gamma-ray analysis system named ''GAMA: giant frog:-SYSTEM'' developped by Musashi Institute of Technology. The formation of Pa-233 (U-233) was discussed quantitatively with respect to the difference of the neutron field. (author).

International Nuclear Information System (INIS)

The results of calculational comparative study into radiotoxicity and residual power release time dependences for spent uranium-plutonium and thorium-uranium nuclear fuels from the WWER-1000 reactors during ling- time (up to 300 thousand years) storage are discussed. It is shown that the total radiotoxicities for actinides from uranium, uranium-plutonium and thorium-uranium spent fuels at storage period begin amount to 5.2 x 10"1"4, 1.3 x 10"1"5 and 1.5 x 10"1"4 kg of water per 1 t of discharged fuel, respectively. Radiotoxicity of actinides in uranium-plutonium fuel is revealed to be by the factor of 2.5 greater than that for ordinary uranium fuel because of greater accumulation of "2"3"9Pu, "2"4"0Pu, "2"4"1Pu and "2"4"4Cm. Radiotoxicity of actinides for thorium-uranium fuel calculated taking into account "2"3"4U is estimated to be by the factor 3.5 smaller than that for uranium fuel. The residual ...

International Nuclear Information System (INIS)

This paper examines the attractiveness of material mixtures containing special nuclear materials (SNM) associated with reprocessing and the thorium-based LWR fuel cycle. This paper expands upon the results from earlier studies that examined the attractiveness of SNM associated with the reprocessing of spent light water reactor (LWR) fuel by various reprocessing schemes and the recycle of plutonium as a mixed oxide (MOX) fuel in LWR. This study shows that "2"3"3U that is produced in thorium-based fuel cycles is very attractive for weapons use. Consistent with other studies, these results also show that all fuel cycles examined to date need to be rigorously safeguarded and provided moderate to high levels of physical protection. These studies were performed at the request of the United States Department of Energy (DOE), and are based on the calculation of 'attractiveness levels' that has been couched in terms chosen for ...

CERN Document Server

Safe management of wastes from the mining and milling of Uranium and Thorium ores

Energy Technology Data Exchange (ETDEWEB)

Inactive cells of Rhizopus arrhizus have been documented to exhibit a high thorium biosorptive uptake (170 mg/g) from aqueous solutions. The mechanism of thorium sequestering by this biomass type was investigated following the same method as for the uranium biosorption emchanism. The thorium sequestering mechanism appeared somewhat different from that of uranium. Experimental evidence is presented which indicates that, at optimum biosorption pH (4), thorium coordinates with the nitroge of the chitin cell wall network and, in addition, more thorium is adsorbed by the external section of the fungal cell wall. At pH 2 the overall thorium uptake is reduced. The kinetic study of thorium biosorption revealed a very rapid rate of uptake. Unlike uranium at optimum solution pH, Fe/sup 2 +/ and Zn/sup 2 +/ did not interfere significantly with the ...

Energy Technology Data Exchange (ETDEWEB)

The electrometallurgical treatment process described in this paper builds on our experience in treating spent fuel from the Experimental Breeder Reactor (EBR-II). The work is also to some degree, a spin-off from applying electrometallurgical treatment to spent fuel from the Hanford single pass reactors (SPRs) and fuel and flush salt from the Molten Salt Reactor Experiment (MSRE) in treating EBR-II fuel, we recover the actinides from a uranium-zirconium fuel by electrorefining the uranium out of the chopped fuel. With SPR fuel, uranium is electrorefined out of the aluminum cladding. Both of these processes are conducted in a LiCl-KCl molten-salt electrolyte. In the case of the MSRE, which used a fluoride salt-based fuel, uranium in this salt is recovered through a series of electrochemical reductions. Recovering ...

International Nuclear Information System (INIS)

Indian Nuclear Power Programme is based on closed nuclear fuel cycle for efficient utilization of its nuclear resources. This strategy also enables waste classification and gives an elegant solution to long-lived waste disposal problem. The three stage nuclear programme envisages mainly pressurized heavy water reactors in the first stage, fast breeder reactors in the second stage and thorium utilization in the third stage. Advanced Fuels in the context of this paper refer to Pu bearing fuels used or proposed to be used in our three stage programme. Fabrication of (U-Pu) Mixed Carbide fuel for FBTR is carried out at Radio Metallurgy Division at Trombay which has also an excellent Characterization facility required for development of all types of advanced Fuels. A (U-Pu) MOX fuel required for Proto-type Fast Breeder Reactor (PFBR-500 MWe) is carried out at Advanced Fuel Fabrication Facility (AFFF), ...

Energy Technology Data Exchange (ETDEWEB)

Decontamination and decommission activities related to the Molten Salt Reactor Experiment (MSRE) involve the trapping and recovery of radiolitically generated uranium hexafluoride and fluorine. Although fission product radiolysis was known to generate F{sub 2}, the formation of UF{sub 6} and its transport from the fuel salt was unexpected. Some of these gaseous radiolysis products have been moving through the gas piping to a charcoal bed since the reactor was shut down in 1969. Current and planned remediation and clean-up activities involve the trapping of the gaseous products, deactivation and treatment of the activated charcoal bed, stabilization and reconditioning of the fuel salt, and recovery of the uranium. The chemical aspects of these processes, including radiolytic generation mechanisms, reactions between uranium hexafluoride and fluorine and trapping materials such as ...

International Nuclear Information System (INIS)

The static thermodynamic properties of the molten salt system like LiF-NaF-BeF_2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF_2, over the temperature range of 873.15K to 1073.15K at one atmosphere pressure, is described using Peng-Robinson equation modified by us. And the density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermodynamic properties such as the enthalpy, entropy and heat capacity at constant pressure are estimated by the residual function method and the fugacity coefficient method respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat ...

International Nuclear Information System (INIS)

Uranium and thorium ores are the source of natural radionuclides. Briefly described are the original and current methods of long-lived nuclide separation ("2"3"8U, "2"3"5U, "2"2"6Ra, "2"3"0Th, "2"3"1Pa, "2"2"7Ac, "2"3"2Th, "2"2"8Ra+"2"2"8Ac, "2"2"8Th), some short-lived nuclides ("2"3"4Th and "2"2"8Ac), radon, short-lived radon daughter products and long-lived radon daughter products ("2"1"0Pb, "2"1"0Bi, "2"1"0Po). Some nuclides, such as "2"1"0Po or "2"3"1Pa can more easily be producedin reactors. (Ha).

Energy Technology Data Exchange (ETDEWEB)

The AVR experimental nuclear reactor was Professor Dr. Rudolf Schulten's brainchild. Visionary ideas led to the success of this technology: - Helium coolant because of the particularly high heat transfer coefficients; - an integrated primary system reactor concept as the basis of all safety considerations in the interest of maximum safety; - uranium-235 and thorium-232 fuel allowing new fuel to be bred; - high temperatures for electricity generation at maximum thermodynamic efficiencies, i.e. optimum fuel utilization; - the possibility to run chemical processes economically at high temperatures by means of nuclear fuels; - the inherent safety of the reactor, for a major accident accompanied by a complete loss of cooling cannot occur for nuclear physics reasons, as was tested twice in the AVR. The AVR attained its first criticality on August 28, 1968. It was operated for more than 20 years, ...

International Nuclear Information System (INIS)

The purpose of the present research is to find a suitable technique to measure trace amounts of uranium and thorium and to determine the surface #alpha#-flux in silicon compound (SiO) used for fabrication of integrated circuit packaging materials. Among several commonly-used detecting techniques, it was found that neutron activation analysis (NAA) was most promising. The results from NAA show a large difference in uranium and thorium concentrations when cadmium and boron carbide shields are used, whereas #alpha#-flux measurements show a low #alpha#-activity, which corresponds to the trace amounts of uranium and thorium expected to be present in these materials. (author) 13 refs.; 6 figs.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

In 1972 a consortium consisting of Gebruder Sulzer A.G., Winterthur and EVT, Energie- und Verfahrenstechnik G.m.b.H., Stuttgart, was awarded the contract by HBR, Hochtemperatur Reaktorbau G.m.b.H., Koln/Mannheim, for the design, manufacture and installation of the 6 steam generator units for the prototype 300 MWe Thorium High Temperature Reactor (THTR) at Schmehausen, Germany. The design and manufacture of the 6 units is done by Sulzer; installation of the units as well as the manufacture of the external pipework and headers is done by EVT. The units are built under semiclean conditions in a special workshop at CCM-Sulzer in mantes, France. This workshop had been used previously for the manufacture of the steam generators for the nuclear power plants St. Laurent I, II, Vandellos (500 Mwe each) and EL-4 (70 Mwe). The present paper defines the operating conditions and the chemical composition of the materials used, including Alloy 800. Reasons ...

Energy Technology Data Exchange (ETDEWEB)

This work concerns the development of nuclear energy and nuclear waste management in particular. Two parts of this study can be distinguished. In the first part (theoretical), a thorium-plutonium fuel based on MOX and dedicated for PWR was investigated in order to transmute plutonium in a potentially low waste fuel cycle. It was shown that this type of fuel is not regenerative but could be used for a transition to the industrial thorium fuel cycle without building new reactors. Thanks to moderated neutron spectra and high loaded actinide mass in the core, U-233 is quickly created ({approx}300 kg/y) for a loss of about {approx}1200 kg of fissile plutonium. In the second part (experimental), we have developed and built a new reaction chamber to measure neutron cross sections of actinides by alpha-gamma spectroscopy. This experimental device (in principle transportable) was commissioned in the high flux ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the progress of the Dutch RAS programme on `Recycling and Transmutation of Actinides and Fission Products` over the year 1995, which is the second year of the 4-year programme 1994-1997. An extensive listing of reports and publications from 1991 to 1995 is given. Highlights in 1995 were: -The completion of the European Strategy Study on Nuclear Waste Transmutation as a result of which the understanding of transmutation of plutonium, minor actinides and long-lived fission products in thermal and fast reactors has been increased significantly. Important ECN contributions were given on Am, {sup 99}Tc and {sup 129}I transmutation options. Follow-up contracts have been obtained for the study of 100% MOX cores and accelerator-based transmutation. - Important progress in the evaluation of CANDU reactors for burning very large amounts of transuranium mixtures in inert matrices. - The first RAS irradiation experiment in the HFR, in ...

Energy Technology Data Exchange (ETDEWEB)

The accuracy of the carbon 14 dating method is dependent on the fluctuations of carbon 14 in the atmosphere over long periods of time. Fossil corals that are dated by both carbon 14 and uranium-thorium methods allows the setting of calibration curves for the carbon 14 method for the last 50.000 years. The uranium-thorium method is based on the measurement of the ratio of 2 isotopes: thorium 230 and uranium 234 that are both present in the decay chain of uranium 238. (A.C.)

International Nuclear Information System (INIS)

Russian Mar 1973. German Democratic Republic Elovskaya, LT

International Nuclear Information System (INIS)

(Jun 1978). United States Parvez, A. Becker, M. Harris, DR Quan, B. Rensselaer

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work was to establish a new binary data base by compiling the activity coefficients of plutonium and uranium at oxidation state +IV to better account for media effects in the liquid-liquid extraction operations implemented to reprocess spent nuclear fuel. Chapter 1: first reviews the basic thermodynamic concepts before describing the issues involved in acquiring binary data for the tetravalent actinides. The difficulties arise from two characteristics of this type of electrolyte: its radioactive properties (high specific activity requiring nuclearization of the experimental instrumentation) and its physicochemical properties (strong hydrolysis). After defining the notion of fictive binary data, an approach based on the thermodynamic concept of simple solutions is described in which the activity coefficient of an aqueous phase constituent is dependent on two parameters: the water activity of the system and the total concentration of dissolved constituents. The method ...

International Nuclear Information System (INIS)

The RKR potential energy curves are constructed for the ground states of diatomic hafnium oxide and thorium oxide. Using Lippincott and Hulburt-Hirschfelder potential function the dissociation energies are estimated by curve fitting method. The H-H potential function was found to give a better fit in both cases. The dissociation energies of hafnium oxide and thorium oxide are estimated as 9.04 #+-# 0.02 eV and 10.34 #+-# 0.01 eV respectively. (author).

Energy Technology Data Exchange (ETDEWEB)

From their genesis by weathering and sedimentation, bauxites, the principal aluminium ores, contain appreciable amounts of uranium and thorium. High resolution gamma spectrometry with a high purity germanium detector was used for an analysis of four industrially used bauxites from Gondama, Sierra Leone; Boke, Guinea; Weipa, Queensland, Australia; Gove, Northern Territory, Australia. Significant differences in uranium to thorium ratios and in activities of the uranium and thorium daughters were observed for the four bauxites. It was found that the bauxite from Gondama, Sierra Leone has an activity of only 10% compared with the others. Red mud tailings from such a bauxite may well be used as an additive to bricks, which is now illegal for normal red mud from more active bauxites. (author).

Energy Technology Data Exchange (ETDEWEB)

Since actinide mononitride has several superior thermal and neutronic properties, nitride fuel is considered as a candidate for future nuclear systems, such as advanced fast reactors and accelerator-driven system. Establishing reprocessing technology is one of key technologies for the development of nitride fuel cycle. In addition to general advantages of pyrochemical process, such as the potential for economy, radiation and proliferation resistance, recycling of N-15 in nitride fuel seems to be practical in comparison with conventional hydro-process. Following the electrochemical measurements of nitride fuel in LiCl-KCl molten salt, the experimental study on closing nitride fuel cycle has been carried out in JAEA by used of TRU nitride and burnup simulated nitride samples. Recent progress of the study is summarized in this paper.

Energy Technology Data Exchange (ETDEWEB)

When thorium was biosorbed by biomass of Rhizopus arrhizus or Aspergillus niger it could be removed by treatment using carbonate solutions, but not by phosphates or distilled water. Desorption was rapid, reaching completion in 15 and 30 min respectively. Desorption efficiency was independent of the desorbent concentration above 0.05 mol dm[sup -3] but was strongly dependent on the biomass concentration, decreasing as the biomass concentration increased for both species. Biomass from both species could be regenerated by desorption using sodium carbonate solutions and reused for biosorption. In both species, the efficiency of biosorption and desorption fell as the number of exposures increased although there was an initial rise in desorption efficiency for R. arrhizus. Biosorption and desorption efficiencies of A. niger biomass showed the steeper decline but both were severely reduced in R. arrhizus after five treatments. There was also a significant loss of biomass ...

International Nuclear Information System (INIS)

For the advanced fusion reactor FFHR2 (Force Free Helical Reactor) that has been proposed by NIFS, molten salt Flibe (LiF:BeF2=64:36) breeder blanket system is selected because of Flibe's features such as chemical stability, low-pressure operation and low electric conductivity. The Flibe is however high Prandtl number fluid since it has high viscosity and low thermal conductivity. Therefore its heat transfer performance is low compared with liquid Li or Pb-Li. In addition to heat removal of 1MW/m2 on the first wall, electrolysis of molten salt due to MHD effect will take place under high flow rate condition. This indicates that heat transfer enhancement under low flow rate is essential for the Flibe blanket system. In our laboratory, heat transfer characteristics of molten salt HTS (KNO3:NaNO2:NaNO3=53:40:7), have been evaluated, which is used as a simulant fluid of Flibe from the ...

International Nuclear Information System (INIS)

... power reactors pressure tube reactors reactors THERMAL REACTORS.

UK PubMed Central (United Kingdom)

BackgroundGlycochenodeoxycholate (GCDA) is one of the major human bile salts. Bile salts stimulate cell survival and proliferation through the mitogen-activated protein kinase, but...Full Text Available

UK PubMed Central (United Kingdom)

Numerous bacteria from a salt-marsh environment are capable of degrading malathion, an organophosphate insecticide, when supplied with additional nutrients as energy and carbon sources. Seven isolates...Full Text Available

International Nuclear Information System (INIS)

The uptake of "2"3"8U and "2"3"2Th in different parts of some selected plants used in traditional treatment of hypertension and diabetes in south-eastern Morocco (Errachidia area) has been studied using two different types of solid state nuclear track detectors (SSNTDs) LR-115 type II and CR-39. Plant uptake of radionuclides is one of many vectors for introduction of contaminants into the human food chain. Thus, it is critical to understand soil-plant relationships that control nuclide bioavailability. Soil concentrations of uranium ranged from 6.10 to 11.62 ppm, with a mean of 7.90 ppm. Soil concentrations of thorium ranged from 2.70 to 4.80 ppm, with a mean of 3.41 ppm. Mean uranium specific activities were 8.38 Bq kg"-"1 in root tissue, 5 Bq kg"-"1 in stem tissue and 6.02 Bq kg"-"1 in leaf tissue. Mean thorium specific activities were 2.53 Bq kg"-"1 in root tissue, 1.64 Bq kg"-"1 in stem tissue and 1.96 Bq kg"-"1 in leaf tissue. The transfer ...

KoreaScience (Korea)

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KoreaScience (Korea)

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CERN Document Server

The Daya Bay reactor neutrino experiment

International Nuclear Information System (INIS)

The COSA II (computer codes for salt) benchmark problem has been pursued with the ADINA (Automatic Dynamic Incremental Nonlinear Analysis) program code. With the use of this, the code should be validated by means of experimental data and the ability to reproduce real-life calculation results of the KfK (Kernforschungszentrum Karlsruhe/Nuclear Research Center in Karlsruhe) should be proven. A successful validation of the code then forms the foundation stone for the ability to use different calculation problems in the final (ultimate) storage. This also accompanies the consequent reaction of replacing the STEALTH (Solids and Thermal Hydraulics Code for EPRI Adapted from LAGRANGE TOODY and HEMP) program which has a number of program-specific weaknesses compared to the ADINA computer code. In order to reproduce the approximate values from the KfK, the same values have been used. Differences were evident in the discretion and the selection of the initial values for ...

International Nuclear Information System (INIS)

Uranium dendrites which were deposited at a solid cathode of an electrorefiner contained a certain amount of salts. These salts should be removed for the recovery of pure metal using a cathode processor. In the uranium deposits from the electrorefining process, there are actinide chlorides and rare earth chlorides in addition to uranium chloride in the LiCl-KCl eutectic salt. The evaporation behaviors of the actinides and rare earth chlorides in the salts should be investigated for the removal of salts in the deposits. Experiments on the salt evaporation of rare earth chlorides in a LiCl-KCl eutectic salt were carried out. Though the vapor pressures of the rare earth chlorides were lower than those of the LiCl and KCl, the rare earth chlorides were co-evaporized with the LiCl-KCl eutectic salt. The Hertz-Langmuir ...

International Nuclear Information System (INIS)

... fast reactors fbr type reactors fuels liquid metal cooled reactors materials nuclear

Energy Technology Data Exchange (ETDEWEB)

Objective of the project is characterization of electrode reactions in molten salt by using metal oxides and silica-based electrode. The scope of project are characterization of metal oxide properties in molten salt and miniaturization of 3-electrode electrochemical test cell. Electrochemical micro-cell for actinide-LiCl-KCl molten salt was newly designed. Electroless and electrochemical deposition technique was applied to Mo coating on quartz tube. From the design of electrode and 3-electrode electrochemical cell suitable for the tests in molten salt electrolyte, so it is anticipated to get the information on the electrochemical behavior of metallic electrode in molten salt and to secure the information on oxidation/reduction behavior of actinide

British Library Electronic Table of Contents (United Kingdom)

Cobalt supported on Beta zeolite catalysts were prepared by impregnation of metal salts in aqueous solution and were tested for the Fischer Tropsch reaction. The support consisted of a Beta zeolite composed by crystallites of nanometric dimensions and a SiO2/Al2O3 molar ratio of about 50. This support was impregnated with Co(NO3)2 aqueous solution using different metal loads of 7.5, 10, 15 and 20wt% Co. These materials were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), N2 adsorption (BET), thermal programmed reduction (TPR) and FTIR of adsorbed pyridine (i.e., surface acid sites distribution). All the catalysts showed a significant catalytic activity for the F-T reaction from synthesis gas (CO+2H2), in a continuous fixed bed reactor sys...

International Nuclear Information System (INIS)

It is essential that alumina used for manufacturing electronic devices should contain an extremely low level of alpha-radiation. The principal source of alpha-radiation in alumina is uranium, a minor source being thorium. Uranium in bauxite dissolves into the liquor in the digestion process and is fixed to the red mud as the desilication reaction progresses. A part of uranium remaining in the liquor precipitates together with aluminum hydroxide in the precipitation process. The uranium content of aluminum hydroxide becomes lower as the precipitation velocity per unit surface area of the seed becomes slower. Organic matters in the Bayer liquor has an extremely significant impact on the uranium content of aluminum hydroxide. Aluminum hydroxide free of uranium is obtainable from the liquor that does not contain organic matters.

International Nuclear Information System (INIS)

In the early sixties it was decided to investigate salt formations on its suitability to host heat generating radioactive waste in Germany. In the reference repository concept consequently the emplacement of vitrified waste canisters in deep vertical boreholes inside a salt mine was considered whereas spent fuel should be disposed of in self shielding casks (type POLLUX) in horizontal drifts. The POLLUX casks, 65 t heavy carbon steel casks, will be laid down on the floor of a horizontal drift in one of the disposal zones to be constructed in the salt dome at the 870 m level. The space between casks and drift walls will be backfilled with crushed salt. The transport, the handling und the emplacement of POLLUX casks were subject of successfully performed demonstration and in situ tests in the nineties and resulted in an adjustment of the atomic law. The borehole disposal concept comprises the emplacement ...

International Nuclear Information System (INIS)

The phase separation of (water + salt + polyethylene glycol 15000) systems was studied by cloud-point measurements using the particle counting method. The effect of three kinds of sulphate salt (Na2SO4, K2SO4, (NH4)2SO4) concentration, polyethylene glycol 15000 concentration, mass ratio of polymer to salt on the cloud-point temperature of these systems have been investigated. The results obtained indicate that the cloud-point temperatures decrease linearly with increase in polyethylene glycol concentrations for different salts. Also, the cloud points decrease with an increase in mass ratio of salt to polymer.

Energy Technology Data Exchange (ETDEWEB)

Natural radioactivity of rocks is studied on the basis of core samples and radioactivity logs of marine deposits in Azerbaijan. Investigations have established mainly thorium-potassium nature of radioactivity. Data obtained are useful for identificafion of clay among other rocks, for determination of clayiness, and in presence of a corresponding relation - for determination of porosity according to the clayiness. It is shown that the clayiness may be determined from radioactive logs.

International Nuclear Information System (INIS)

Processing certain raw materials containing natural radioactive isotopes (e.g. U-238, Th-232 or K- 40) into products such as glas, abrasives, grinding materials or electrodes used for gasshielded tungsten-arc welding also leads to certain concentrations of industrial waste containing natural radioactive materials. Such industrial waste does not necessarily contain natural radioactive substances in concentrations exceeding the highest possible levels but nevertheless in significantly measurable quantities. This, however, frequently leads to confusion bordering on irritation by entities processing such substances as well as the general public, since they tend to believe natural radioactive substances in unobjectable concentration to cause similar or identical - health - consequences as man made radioactive substances in detrimental concentration. Radioactive materials may be incorporated intentionally or unintentionally into the product as main or additional ingredients. The recent ...

Energy Technology Data Exchange (ETDEWEB)

The conversion of highly radioactive waste liquor into glass by the pot vitrification process has been studied at Harwell using a full-scale inactive pilot plant. A summary of the off-gas behavior and its interpretation is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) processes involving the volatile species. Entrainment was enhanced when the feed contained free ...

UK PubMed Central (United Kingdom)

The sequence information available for homeodomains reveals that salt bridges connecting pairs 19/30, 31/42, and 17/52 are frequent, whereas aliphatic residues at these sites are rare and mainly restricted...Full Text Available

UK PubMed Central (United Kingdom)

Artifacts in two-dimensional electrophoresis (2-DE) caused by the presence of salts in isoelectric focusing (IEF) have been previously described as a result of increasing conductivity and inducing electroosmosis....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Cited are the results of physico-chemical studies and industrial tests of a copolymer of methacrylic acid and diethylammonium salt, used for limiting the influx of stratum waters into a well.

UK PubMed Central (United Kingdom)

The conformation of d (CG)n oligomers with n = 2,3 has been studied in aqueous solution in the presence of high salt concentration. A minimum n value of three is necessary to obtain a left-handed Z-helix....Full Text Available

International Nuclear Information System (INIS)

Interfacial tension at the aqueous solution of di-2-ethylhexylphosphoric acid or its copper salts/water solutions has been measured by the drop volume method.

Science.gov (United States)

... by the Bureau. A canvas of supply sources produced only one other, the Flexo roller bearing swivel. Accordingly, only the ...

International Nuclear Information System (INIS)

(1981). United States Kadar, I. Li, WT Todeschini, R. Wu, CL Bechtel, Downey,

J-STORE (Japan)

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British Library Electronic Table of Contents (United Kingdom)

Mentha pulegium L. is a medicinal and aromatic plant belonging to the Labiatae family present in the humid to the arid bioclimatic regions of Tunisia. We studied the effect of different salt concentrations on plant growth, mineral composition and antioxidant responses. Physiological and biochemical parameters were assessed in the plant organs after 2?weeks of salt treatment with 25, 50, 75 and 100?mM NaCl. Results showed that, growth was reduced even by 25?mM, and salt effect was more pronounced in shoots (leaves and stems) than in roots. This growth decrease was accompanied by a restriction in tissue hydration and K+ uptake, as well as an increase in Na+ levels in all organs. Considering the response of antioxidant enzymes to salt, leaves and roots reacted differently to saline conditions...

International Nuclear Information System (INIS)

In the electrorefining step of the pyrochemical process, actinide ions dissolved in the LiCl-KCl eutectic salt are recovered as pure actinide metals at a cathode for a re-use as a nuclear fuel from the aspect of its nonproliferation of the nuclear fuel cycles. The lanthanide species dissolved in the LiCl-KCl eutectic salt play an important role in an effective metal purification during the electrorefining step, so it is necessary to understand the chemical and physical behaviors of lanthanides in molten salt. The in situ spectroscopic measurement system and studies according to temperature changes are essential for better understandable information. To our knowledge, the absorption studies of lanthanides at high temperatures have been reported before, but the fluorescence studies of those at high temperature are not reported yet. We will discuss here the fluorescence behaviors of lanthanides in LiCl-KCl molten ...

Energy Technology Data Exchange (ETDEWEB)

During second quarter 1992, tritium, trichloroethylene, tetrachloroethylene, chloroethene, antimony, 1,1-dichloroethylene, lead, nonvolatile beta, radium-228, thorium-228, or total alpha-emitting radium (radium-226 and radium-228) exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) in groundwater samples from monitoring wells at the Mixed Waste Management Facility (MWMF) and adjacent facilities. Tritium and trichloroethylene were the most widespread constituents; 55 (48%) of the 115 monitored wells contained elevated tritium activities, and 23 (20%) wells exhibited elevated trichloroethylene concentrations. Sixty-three downgradient wells screened in Aquifer Zone IIB2 (Water Table), Aquifer Zone IIB[sub 2] (Barnwell/McBean), and Aquifer Unit IIA (Congaree) contained concentrations of tritium, trichloroethylene, tetrachloroethylene, chloroethene, antimony, 1,1-dichloroethylene, lead, nonvolatile beta, radium-228, ...

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass serves as reaction ...

International Nuclear Information System (INIS)

Most important radionuclides naturally appearing in minerals used to form building materials are described. The frequently met ranges of concentrations of these radionuclides in the building materials composed from natural products as well as from power-plant wastes and metallurgic plant wastes are discussed and propositions concerning the limitation of presence of radioactive nuclides in the building materials are given, with special concern paid to materials for dwelling and public utility buildings. The elaborated technique of measuring potassium 40, radium 226 and thorium 228 concentrations is presented. Data on the organization of controlling-and-measuring laboratories in this field are given. (author).

Energy Technology Data Exchange (ETDEWEB)

This report describes the results obtained during Stage 13 of a long-term research and development program concerning the development of diagnostics and monitoring methods for nuclear reactors. A brief proposal for the continuation of this program in Stage 14 is also given at the end of the report. The program executed in Stage 13 consists of three parts and the work performed in each part is summarized below. 1. Study of criticality, neutron kinetics and neutron noise in molten salt reactors (MSR). Although the original goal of the investigations of the MSR in Stage 13 was to calculate the neutron noise induced by the fluctuations of the fuel temperature, the study, solution and interpretation of the static problem, as well as to define an approximate version of the point kinetic approximation was necessary to perform. As it turned out, these tasks in themselves were more involved, and also very edifying, to solve. Hence, ...

International Science & Technology Center (ISTC)

Investigation of Destruction Mechanisms in Reactor Steels and Alloys under Cycling Deformation

Energy Technology Data Exchange (ETDEWEB)

Anomalous features in Gulf Coast Salt domes exhibit deviations from normally pure salt and vary widely in form from one dome to the next, ranging considerably in length and width. They have affected both conventional and solution mining in several ways. Gas outbursts, insolubles, and potash (especially carnallite) have led to the breakage of tubing in a number of caverns, and caused irregular shapes of many caverns through preferential leaching. Such anomalous features essentially have limited the lateral extent of conventional mining at several salt mines, and led to accidents and even the closing of several other mines. Such anomalous features, are often aligned in anomalous zones, and appear to be related to diapiric processes of salt dome development. Evidence indicates that anomalous zones are found between salt spines, where the differential salt intrusion ...

Energy Technology Data Exchange (ETDEWEB)

The composition of alkaline and neutral boric acid containing evaporator concentrates resulting from the treatment of radioactive waste water in nuclear power plants with WWER reactors is described as well as the processing of these concentrates to a product suitable for final disposal. Tests with mock solutions of these evaporator concentrates have been performed at the laboratory and teststand scale to produce a dry residue by continuous thickening, which can be processed into a highly leach resistant product, suitable for final disposal, by cementation. Ca-compounds must be added to the evaporator concentrates prior to the drying in an rotary thin-film evaporator (RTFE). The tests showed that neutral evaporator concentrates can be dried in a RTFE with addition of small amounts of Ca-compounds. The alkaline evaporator concentrates with high boric acid and total salt load require a multiple amount of Ca-compounds and diluting water to perform ...

Energy Technology Data Exchange (ETDEWEB)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO{sub 2}, PrO{sub 2}), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements ...

Energy Technology Data Exchange (ETDEWEB)

The patent is for a method of preparing drilling muds that are notable for their chemical resistance to Zechstein deposits, especially to magnesium, carbonate and carboxylic acid ions. To achieve chemical resistance of the drilling mud to Zechstein deposits, it is suggested to saturate them with salt (the amount of added salt depends on the absorption properties of the solution), and then to process them with caustic soda or potassium oxide hydrate and lime in proportions that would cause filtrate alkalinity not to exceed 0.5. For example, to prepare drilling solution to bore through mediums containing magnesium salts, potassium salts, rock salt, anhydrate, dolomite, limestone, red salt clay: add 340 kg potassium chloride into 1 m/sup 3/ drilling solution with weighed bentonic clay, 10 kg. ferro-chromate lignosulfite, 7 kg. unslaked lime, 2 kg. sodium hydroxide, ...

International Nuclear Information System (INIS)

Development of evaluation technology of electrochemical reactions is very essential to understand chemical behavior of actinides and lanthanides in molten salt media in relation to the development of Pyrochemical process. The on-line electrochemical/spectroscopic measurement system is to produce electrochemical parameters and thermodynamic parameters of actinides and lanthanides in molten salts by using spectroscopic techniques such as UV-VIS absorption as well as electrochemical in-situ measurement techniques. The on-line electrochemical/spectroscopic measurement system can be applied to understand the chemical reactions and oxidation states of actinides and lanthanides in molten salts eventually for the Pyrochemical process

Energy Technology Data Exchange (ETDEWEB)

As part of our effort to develop a semicontinuous PuO/sub 2/ reduction process, we are investigating promising materials for containing a 900/sup 0/C molten CaCl/sub 2/ . CaO chlorination reaction. We want the material to contain this reaction and to be reusable. We tested candidate materials in a simulated salt (no plutonium) using anhydrous HCl as the chlorinating agent. Data are presented on the performance of 36 metals and alloys, 9 ceramics, and 3 coatings.

International Nuclear Information System (INIS)

The mechanism of the salt concentration increase in pits and crevices formed in a steam generator due to its imperfect manufacture or to its design features is described. The probability of corrosion can be reduced by choosing a suitable steel and by securing low concentrations of salts (chlorides in particular) and corrosion products in the feedwater. Attention is paid to the distribution of salts in the water-steam circuit and to the conditions of erosion corrosion as the principal source of corrosion products in feedwater. Experience with the suppression of erosion corrosion at nuclear power plants abroad is described. (E.J.).

British Library Electronic Table of Contents (United Kingdom)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two sha...

International Nuclear Information System (INIS)

An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements

British Library Electronic Table of Contents (United Kingdom)

The design of a global steady-state thermal model of a 100kWt molten salt cavity receiver was developed as part of the key project of the Ministry of Science and Technology of People's Republic of China (MOST). In the design process, the following factors were analyzed: receiver area, heat loss (convective, emissive, reflective and conductive), number of tubes in the receiver panel, tube diameter and receiver surface temperature. The model was also used to calculate the receiver performance of the Sandia National Laboratories' molten salt electric experiment (MSEE). In addition, the thermal performance of the designed molten salt cavity receiver is presented for a fixed outlet flow rate and a fixed output temperature.

Science.gov (United States)

Adipocyte lipid-binding protein (ALBP or aP2) is an intracellular fatty acid-binding protein that is

International Nuclear Information System (INIS)

The electrochemical/spectroscopic integrated measurement system was designed and set up for spectro-electrochemical measurements of lanthanide and actinide ions in high temperature molten salt media. A compact electrochemical cell and electrode system was also developed for the minimization of reactants, and consequently minimization of radioactive waste generation. By applying these equipment, oxidation and reduction behavior of lanthanide and actinide ions in molten salt media have been made. Also, thermodynamic parameter values are determined by interpreting the results obtained from electrochemical measurements. Several lanthanide ions exhibited fluorescence properties in molten salt. Also, UV-VIS measurement provided the detailed information regarding the oxidation states of lanthanide and actinide ions in high temperature molten salt media

Energy Technology Data Exchange (ETDEWEB)

To our knowledge, the fluorescence studies of lanthanides in LiCl-KCl eutectic molten salt at a high temperature are not reported yet. The fluorescence of the lanthanide-ions was generally decreased when the temperature was increased. Moreover, the fluorescence of the lanthanides was strong when the sample was solidified to or from the melt. The temperature, where the fluorescence was decreased, was identified to be different depending on the species of the lanthanides and the substrates was considered to possibly be from quenching of the fluorescence due to either the collisions of melted samples induced by high temperature media or the re-absorption of fluorescence by the samples. Several comparison experiments were performed to explain and understand this phenomenon and improve the fluorescence. In this way, an on-line monitoring of chemical species and the concentration for lanthanides elements in molten salt media of pyrochemical process ...

Science.gov (United States)

Ultimate Compressive Strength of Short Sheet - Stringer Panels With Special. Reference to the Influence of the Riveted Connection Between Sheet and Stringer ...

Science.gov (United States)

... 3004505040***, MEDICAMENTS, DOSED, VITAMINS, MULTIPLE, OTHER COMBINATIONS, FD3***. 3104100000**, CARNALLITE, SYLVITE AND OTHER CRUDE POTASSIUM SALTS, FD3**. ...

International Nuclear Information System (INIS)

Pyrochemical processing of nuclear fuels using molten salts has attracted much attention because of its potential to be applied for a future spent nuclear fuel management. In the pyrochemical processing, there are a number of steps to electro-refine and electro-win each element of lanthanides and actinides, commonly called trans-uranic elements (TRU). In order to materialize the pyrochemical processing in the nuclear power plant environments, qualitatively and quantitatively monitoring of each elements is necessary. Thus, we have undertaken to develop an on-line observing system of the TRU in LiCl-KCl molten salt media by using electrochemical and spectroscopic methods. In this work, the electrochemical and spectroscopic behaviors of europium as a proxy material for TRU were investigated simultaneously in the LiCl-KCl molten salt

Science.gov (United States)

Interactions (FCCI) University of Wisconsin, Madison Thermal Properties of LiCl-KCl Molten Salt for Nuclear Waste Separation University of Wisconsin, Madison Next Generation...

International Nuclear Information System (INIS)

Recent achievements and tendency on reactor physics activities in Japan are reviewed according to topics published in journals or discussed at the Japan Research Committee on Reactor Physics.

Science.gov (United States)

... and support cost, and post-retirement disposal cost) of ... from reactors, and the reactors and other ... the ship's hull and reactor compartment enough to ...

International Nuclear Information System (INIS)

AECL Publications on Reactor Safety in CANDU Reactors are listed in this bibliography. The listing is chronological and the accompanying index is by subject. The bibliography will be brought up to date annually. (auth).

Energy Technology Data Exchange (ETDEWEB)

Advanced lithium batteries presently under development operate either at the high temperatures associated with the LiCl-KCl molten salt (350-450/degree/C), or at ambient temperatures employing organic solvent based electrolytes. An intermediate temperature lithium battery is proposed as an alternative if it reduces corrosion problems present at high temperatures and improved kinetic performance with respect to ambient temperature cells. 17 refs.

Energy Technology Data Exchange (ETDEWEB)

A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with an anion such as a dihydrogen phosphate anion or a dihydrogen phosphite anion and additionally with an ammonium salt other than a salt of an inorganic acid of phosphorus. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.

Science.gov (United States)

The phytomanagement of Se-polluted soil and water is one strategy that may be environmentally sustainable and cost-effective for soils and waters enriched with natural-occurring Se. Several plant species, including Indian mustard (Brassica juncea), pickleweed (Salicornia bigelovii), and other salt/S...

International Nuclear Information System (INIS)

Distribution of scattered elements in basic minerals of salt-rocks is studied. It is shown that rubidium and cesium are accumulated mainly in carnallites and are contained in small quantities halites. These elements are accumulated primarily in the carnallite production products, wherein their content in a number of cases exceeds by dozens and hundred times their content in source rocks. It is noted that only carnallites may be considered in the list of actual sources for rubidium and cesium separation

Energy Technology Data Exchange (ETDEWEB)

Ammonia is a common and highly toxic pollutant which, in sufficient quantities, will adversely affect aquatic organisms. This ammonia criteria document for salt water will allow establishment of regulatory standards for ammonia discharge into estuaries, near coastal zones and oceans. Possible adverse impacts in highly sensitive and abundant ecosystems such as estuaries make regulation particularly important.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared

International Nuclear Information System (INIS)

An overview is presented of the FFTF reactor and plant together with descriptions of core components, core internals, core system, primary and secondary control rod system, reactor instrumentation, reactor vessel and closure head, and supporting test programs.

Energy Technology Data Exchange (ETDEWEB)

This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in ...

CERN Document Server

We present measurements of the transmission of radio/microwave pulses through salt in the Cote Blanche salt mine operated by the North American Salt Company in St. Mary Parish, Louisiana. These results are from data taken in the southwestern region of the 1500 ft. (457 m) deep level of the mine on our third and most recent visit to the mine. We transmitted and received a fast, high-power, broadband pulse from within three vertical boreholes that were drilled to depths of 100 ft. (30 m) and 200 ft. below the 1500 ft. level using three different pairs of dipole antennas whose bandwidths span 125 to 900 MHz. By measuring the relative strength of the received pulses between boreholes with separations of 50 m and 169 m, we deduce the attenuation of the signal attributed to the salt medium. We fit the frequency dependence of the attenuation to a power law and find the best fit field attenuation lengths to be ...

British Library Electronic Table of Contents (United Kingdom)

Homozygous transgenic cotton (Gossypium hirsutum L.) plants that accumulated glycinebetaine (GB) in larger quantities were more tolerant to salt than wild-type (WT) plants. Four transgenic lines, namely 1, 3, 4, and 5, accumulated significantly higher levels of GB than WT plants did both before and after salt stress. At 175 and 275?mM NaCl, seeds of all the transgenic lines germinated earlier and recorded a higher final germination percentage, and the seedlings grew better, than those of the WT. Under salt stress, all the lines showed some characteristic features of salt tolerance, such as higher leaf relative water content (RWC), higher photosynthesis, better osmotic adjustment (OA), lower percentage of ion leakage, and lower peroxidation of the lipid membrane. Levels of endogenous GB in ...

International Nuclear Information System (INIS)

... 1343-3563 v. 57(1) SPECIFIC NUCLEAR REACTORS AND ASSOCIATED

International Nuclear Information System (INIS)

Progress on construction of the Cordoba reactor in Argentina and the Wolsung reactor in Korea is described. (E.C.B.).

International Nuclear Information System (INIS)

... Natural convection cooling of the channel type reactor performed with the fuel

International Nuclear Information System (INIS)

This handbook breaks down the complex field of nuclear reactor calculations into major steps. Each step presents a detailed analysis of the problems to be solved, the parameters involved, and the elaborate computer programs developed to perform the calculations. This book bridges the gap between nuclear reactor theory and the implementation of that theory, including the problems to be encountered and the level of confidence that should be given to the methods described. Volume II: Monte Carlo Calculations for Nuclear Reactors. In-Core Management of Four Reactor Types. In-Core Management in CANDU-PHW Reactors. Reactor Dynamics. The Theory of Neutron Leakage in Reactor Lattices. Index.

Energy Technology Data Exchange (ETDEWEB)

In the framework of the search for a ceramic material usable in the radioactive waste storage, uranium and thorium phosphates have been investigated. Their experimental synthesis conditions have been entirely reviewed, they lead to the preparation of four new compounds: U(UO{sub 2})(PO{sub 4}){sub 2}, U{sub 2}O(PO{sub 4}){sub 2}, UCIPO{sub 4}, 4H{sub 2}O, and Th{sub 4}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}. Experimental evidenced are advanced for non existent compounds such as: U{sub 3}(PO{sub 4}){sub 4}, U{sub 2}O{sub 3}P{sub 2}O{sub 7} and Th{sub 3} (PO{sub 4}){sub 4}. Characterization by several techniques (X-rays and neutron powder diffractions, UV-Visible and Infra-red spectroscopies, XPS,...) were performed. The ab initio structure determination of U(UO{sub 2})(PO{sub 4}){sub 2} has been achieved by X-rays and refined by neutron diffractions. Through its physico-chemical analysis, we found that this compound was a new mixed valence uranium phosphate in which ...

International Nuclear Information System (INIS)

The partial pressures of the components (ThCl_4, MCl and MThCl_5) in the saturated vapours of ThCl_4 solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl_4 concentration (2 to 50 mol% ThCl_4) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl. (author).

Energy Technology Data Exchange (ETDEWEB)

In this study, thermoluminescence (TL) dating of archaeological artefacts from Geboltskirchen (Upper Austria) and Haselbach (Lower Austria) has been carried out. To receive a comparison with TL dating, all samples have been investigated additionally by means of infrared-stimulated luminescence (IRSL) analysis. The samples were prepared according to the common fine-grain technique. All important dating parameters such as potassium concentration, thorium/uranium ratio, moisture content, etc. were determined. A methodology for IRSL was developed, describing all steps of the procedure from sample preparation to measurement for any kind of ceramic artefacts. Dating results from TL and IRSL investigations of ancient pottery from Geboltskirchen and Haselbach will be discussed.

International Nuclear Information System (INIS)

The TVR heavy water research reactor was deployed at Moscow Institute of Theoretical and Experimental Physics. In 1990, the final batch of the spent nuclear fuel from this reactor was shipped to Production Association (PA) 'Mayak' for reprocessing. The SNF removal was a stage of the reactor decommissioning activities. The designs of the TVR reactor and its fuel elements are similar to the RA reactor designs. Two ways of the RA reactor SNF transportation to PA 'Mayak' have been considered: in aluminum barrels and in additional canisters using respectively TUK-32 and TUK-19 shipping casks. The practical experience and the equipment used to prepare for the TVR reactor SNF removal can be helpful to the RA reactor personnel in finding the best way to perform these engineering operations. (author)

International Nuclear Information System (INIS)

The precipitation reaction of some rare earth chlorides (La/Ce/Nd/GdCl3) in a LiCl-KCl molten salt has been carried out by using the oxygen sparging method. In this study, regardless of the oxygen sparging time and the molten salt temperature, oxychlorides (REOCl) for LaCl3, NdCl3 and GdCl3, and an oxide (REO2) for CeCl3 are formed as a precipitate. The conversion of rare-earth chlorides into insoluble precipitates was described by using a conversion ratio. The conversion ratio increased exponentially with the oxygen sparging time and finally showed asymptotic value at 1,023K of the molten salt temperature condition. The conversion ratios of LaCl3, NdCl3 and GdCl3 were increased with the molten salt temperature, however, even though the conversion ratio was increased from 0.660 to 0.995 with increasing molten salt temperature from 823 to 923 K at 60 min of a sparging time, the ...

International Nuclear Information System (INIS)

Fusion energy has been studied in many countries such as U.S., France, Japan, Korea etc. Because it would provide much more energy for a given weight of fuel than any technology currently in use, and the fuel itself (primarily deuterium) exists abundantly in the Earth's ocean. Nuclear fusion reactor uses tritium and deuterium as fuel while nuclear fission reactor uses uranium and plutonium as fuel. Besides, inherent design characteristics and driving condition of nuclear fusion reactor is different from those of nuclear fission reactor. Therefore, we cannot apply the regulation rules of nuclear fission reactor to nuclear fusion reactor without change and thus it is needed to development of the safety regulation concept which reflects the characteristics of nuclear fusion reactor. Safety regulation of nuclear fusion ...

Energy Technology Data Exchange (ETDEWEB)

A solar energy desalination process utilizing solar radiation directly for the evaporation of salt water is described. Ambient air takes on water vapor as the air passes through an evaporative medium. It is then directed between a saline water-covered, solar absorbing surface and a solar collecting housing. The resulting heated and moisture-saturated air is cooled in a heat exchange means where condensation of fresh water occurs. Simultaneously, cool salt water is utilized as the cooling water in the heat exchange means, and takes on the heat of condensation given up by the condensing vapor. The heated salt water from the heat exchange means is partially directed over the solar absorbing surface, and at least a portion of it is also directed to wet the evaporative medium. Several optional sub-processes are described for operation of the system during periods of reduced insolation, and an alternative process is described for ...

Energy Technology Data Exchange (ETDEWEB)

Counter-current regeneration of 2-stage sodium zeolite softeners has been employed in reducing hardness leakage level of steamflooding water to less than 1 ppm when raw water contains as much as 5,000 ppm of the total dissolved solids. Hardness leakage is caused by sodium displacement of calcium and magnesium from the bottom of the exchanger bed. This study presents nomographs providing for rapid calculations to be made, for which a convenient operational mode does not already exist. The nomographs relate the hardness leakage as a function of salt quality and influent water quality and present solutions for predicting the leakage level, salt quality requirement or the treatability of raw water required for steamflooding projects.

British Library Electronic Table of Contents (United Kingdom)

The crystal structure of Ca2RuD6 has been determined by neutron powder diffraction: space group Fm3m, K2PtCl6 structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340K and 50K. The deuterium nuclear quadrupole coupling constant, 54.7kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A2MH6 salts are interpreted in terms of the ionization energies of the cation and the central metal atom.

International Nuclear Information System (INIS)

High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723 K by using Eu_2O_3 as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723 K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.

CERN Document Server

We review a new theoretical approach to the kinetics of surfactant adsorption at fluid-fluid interfaces. It yields a more complete description of the kinetics both in the aqueous solution and at the interface, deriving all equations from a free-energy functional. It also provides a general method to calculate dynamic surface tensions. For non-ionic surfactants the results coincide with previous models. Common non-ionic surfactants are shown to undergo diffusion-limited adsorption, in agreement with experiments. Strong electrostatic interactions in salt-free ionic surfactant solutions are found to lead to kinetically limited adsorption. In this case the theory accounts for unusual experimental results which could not be understood using previous approaches. Added salt screens the electrostatic interactions and makes the ionic surfactant adsorption similar to the non-ionic case. The departure from the non-ionic behavior as the ...

Energy Technology Data Exchange (ETDEWEB)

The peak evaluation in alpha liquid scintillation is known to be easy, mostly due to the gaussian shape of the peaks. However, we often observed a high-energy tail in addition to a pure gaussian function. This effect is only detectable with a high resolution {alpha} liquid scintillation spectrometer such as the PERALS trademark system. Indeed, its intrinsic resolution (180 keV for a 4 MeV {alpha} particle) is better than that obtained for conventional LSC spectrometers. The peak asymmetry was quantified using the Fisher's coefficient {gamma}{sub 1} (symmetry factor). We show that the main effect responsible for the asymmetry is internal conversion. Indeed, most of the even-even nuclides have low {alpha} intensity transitions leading to excited levels of their daughter nuclides. The internal conversion is almost equal to 100% and consequently produces a sum peak at higher energy. No generalization is possible for odd-even nuclides, but the knowledge of their disintegration ...

Energy Technology Data Exchange (ETDEWEB)

Samples of Parmelia sulcata and Xanthoria parietina from different biotopes have been analysed for elements of the series of uranium 238 and thorium 232. These species have been used as bio-monitors in different cases : urban areas, coal fired power plant, tip for uranium-mining residues. The concentration of most of these elements in lichens is decreasing as follows: radium waste-disposal site > area with uranium-rich soil > urban area > rural area. Road traffic was not found to increase notably the presence of radioactive lead in the environment. The two foliose lichens seem to have a comparable concentration ability, but Parmelia sulcata appeared to be more reliable. Some of the elements under investigation could be particularly problematic from a sanitary point of view: the intake limits in case of inhalation are very low and the atmospheric deposition is not negligible; this is particularly so for lead 210 and thorium 228. These ...

International Nuclear Information System (INIS)

The results for development of methods and computer programs for integrated optimization of parameters of perspective fast reactors are given. The possibilities of the program for the reactor campaign calculation are analysed. This program is based on utilisation of the Bubnov-Galerkin method and Wigner disturbance theory. The possibility of application of approximation methods for the optimization researches is discussed. The results of development of the programs for complex reactor computations with account of control rods system and change of physical parameters in the reactor campaign are discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

In the framework of a global analysis of the various available sources of energy, Japan has reserved a prominent place to the nuclear energy, and in the long-term view, to the breeder reactor which will be due for commercial deployment in 2010. To achieve these objectives, three stages are envisaged, one of the experimental reactor Joyo (in service), one of the demonstration reactor Monju (its construction has been decided), and one of the pre-commercial reactor (due to be taken in hand at the beginning of the Nineties). Efforts will be made in parallel concerning the fuel cycle.

Energy Technology Data Exchange (ETDEWEB)

Alpha continuous air monitors (CAMs) will be used at the Waste Isolation Pilot Plant (WIPP) to measure airborne transuranic radioactivity that might be present in air exhaust or in work-place areas. WIPP CAMs are important to health and safety because they are used to alert workers to airborne radioactivity, to actuate air-effluent filtration systems, and to detect airborne radioactivity so that the radioactivity can be confined in a limited area. In 1993, the Environmental Evaluation Group (EEG) reported that CAM operational performance was affected by salt aerosol, and subsequently, the WIPP CAM design and usage were modified. In this report, operational data and current theories on aerosol collection were reviewed to determine CAM quantitative performance limitations. Since 1993, the overall CAM performance appears to have improved, but anomalous alpha spectra are present when sampling-filter salt deposits are at normal to high levels. This ...

UK PubMed Central (United Kingdom)

In the labellar chemosensory hairs of the blowfly, Phormia regina Meigen, stationary amplitudes of the slow potentials induced by salt and sugar stimulations were decreased to 50–80%...Full Text Available

International Nuclear Information System (INIS)

Analysis of results of an investigation into the structure of lithium salt aqueous solutions is presented. An anomaly in lithium ion behaviour in solutions at the structural level is noted. 40 refs., 3 tabs.

UK PubMed Central (United Kingdom)

OBJECTIVE--To examine the effect of a reduced sodium and increased potassium and magnesium intake on blood pressure. DESIGN--Randomised double blind placebo controlled trial. SETTING--General population...Full Text Available

UK PubMed Central (United Kingdom)

Rat somatotropin (growth hormone) was labelled biosynthetically by incubating anterior pituitary lobes with radioactive amino acids for 24 h in a simple buffered salts medium containing glucose. The...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

The estimation of numerical values of the mean distance of closest approach of ions, a, of alkaline-earth metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.

Energy Technology Data Exchange (ETDEWEB)

For the development of high ionic conductive solid electrolyte, LiTi2(PO4)3 (LTP), one of the promising inorganic solid electrolyte, was synthesized to investigate an effect of additional lithium salt on the ion conductivity. Lithium salt added LTP composite electrolyte sintered at 900{degree}C exhibited highest conductivity, which was two order magnitude higher than pure LTP. Effects of lithium salt addition are as follows. Conductivity of the composite electrolyte provided larger sintering temperature dependence than the pure LTP. From X-ray diffraction analysis, structures and compositions were resemble between two composite electrolytes. Byproducts except LTP provided rather low conductivity. It was suggested that melted constitution in the composite can affect the sintering improvement by the additional lithium salt at temperatures over 800 {degree}C. From the observation of ruptured surface of ...

UK PubMed Central (United Kingdom)

Urmia Lake has been designated as an international park by the United Nations. The lake occupies a 5700 km2 depression in northwestern Iran. Thirteen permanent rivers flow into the lake. Water level...Full Text Available

UK PubMed Central (United Kingdom)

We compared MRSA Select to mannitol-salt agar with 8 μg/ml cefoxitin for the detection of methicillin-resistant Staphylococcus aureus (MRSA) from 6,199 clinical...Full Text Available

UK PubMed Central (United Kingdom)

Proline accumulation in NaCl-treated excised barley (Hordeum vulgare var Larker) leaves was studied. Leaves were treated by placing the cut end in NaCl solutions and allowing the salt...Full Text Available

International Nuclear Information System (INIS)

Development of the engineering technology basis of pyrometallurgical reprocessing is a key issue for industrialization. For development of the transport technologies of molten salt and liquid cadmium at around 500 deg. C, a salt transport test rig and a metal transport test rig were installed in Ar glove box. Function of centrifugal pump and 1/2'' declined tubing were confirmed with LiCl- KCl molten salt. The transport behavior of molten salt was found to follow that of water. Function of centrifugal pump, vacuum sucking and 1/2'' declined tubing were confirmed with liquid Cd. With employing the transport technologies, industrialization applicable electro-refiner was newly designed and engineering-scale model was fabricated in Ar glove box. The electro-refiner has semi-continuous liquid Cd cathode instead of conventional one used in small-scale tests. With using actinide-simulating elements, ...

UK PubMed Central (United Kingdom)

It is well known that DNA strands bind to silica surfaces in the presence of high concentrations of chaotropic salts. We developed simple methods to evaluate binding and recovery of DNA on flat...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Until 1990, in Tuscany, salt pollution of anti-salt insulators installed on high-tension transmission lines had led to rare breakdowns. On the contrary, in the last months of 1990, in most of Tuscany, following a strong libeccio wind coming from the Tyrrhenian Sea, and due to a long period of drought, salt deposits accumulated on the insulators of the high-voltage transmission lines (380 kV, 220 kV and 132 kV). This phenomenon not only took place in the coastal areas near Livorno, Pisa and Grosseto, but also in areas far away from the sea such as Florence, Prato, Arezzo and Siena. Following this, several high-tension lines, and whole sections of 380 kV electric stations went out of order, damaging the stations' equipment, insulators on the lines, and in particular porcelain insulators. The maintenance operations that were immediately undertaken consisted in washing operations, first focussed on stations, and then ...

UK PubMed Central (United Kingdom)

The antibacterial activity of aqueous solutions of paraformaldehyde in concentrations from 0.1 to 0.4% (w/v) is bacteriostatic rather than bactericidal in the presence or absence of ammonium chloride....Full Text Available

Science.gov (United States)

...visible damage. (k) Corrosion resistance. Each metal part of a...evidence of salt-spray corrosion resistance equal to or greater than...sample of test metal must show corrosion resistance equal to or better than...

British Library Electronic Table of Contents (United Kingdom)

Solution and dilution enthalpies of aqueous solutions of potassium diclofenac salt (K_DC) were measured by an isoperibolic calorimeter at 298.15 and 318.5?K. Heat capacities of the solutions with concentrations 0.002?0.09?mol?kg?1 were obtained at the temperature interval of 288.15?318.15?K using a scanning adiabatic microcalorimeter. The virial coefficients were derived from Pitzer?s model, and the excess thermodynamic functions of both the solvent and the solute of the solution were calculated. The concentration and temperature dependencies of thermodynamic characteristics of the solution were analyzed and discussed.

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for preparing poly(aryl ether ketones) by nucleophilic displacement polymerization in the presence of at least one alkali metal base selected from potassium, rubidium or cesium, and fluoride ions, which comprises adding to the polymerization: (a) an effective amount of at least one metal salt selected from lithium, sodium, alkaline earth or lanthanide chloride, bromide, iodide, sulfate, alkyl or aryl carboxylate, cyanide, borate or phosphate to slow or stop advancement of molecular weight and (b) an end-capping agent.

International Nuclear Information System (INIS)

Capsulation of terbium(III) chloride in porous glass in the amount of 1.5-150 #mu#mole g"-"1 was carried out by impregnation of the glass substrate with variable concentrations of the salt aqueous solutions. Maximum luminosity of terbium(III) chloride in porous glass is found at its concentration of 120 #mu#mole g"-"1, that is close to the corresponding monolayer surface filling. Concentration dependences of terbium(III) luminescence and its quenching by adsorbed water are in agreement with the ideas of molecular fragmentation and uniform distribution of capsulated salt on the substrate surface

Energy Technology Data Exchange (ETDEWEB)

This report documents results of a preliminary hazard analysis (PHA) covering the existing Crane Chempump and the new salt well pumping design. Three hazardous conditions were identified for the Chempump and ten hazardous conditions were identified for the new salt well pump design. This report also presents the results of the control decision/allocation process. A backflow preventer and associated limiting condition for operation were assigned to one hazardous condition with the new design.

Energy Technology Data Exchange (ETDEWEB)

A chromium-free conversion coating for magnesium alloys were described. The conversion coating could be obtained when AZ31D magnesium alloy was immersed in a solution containing a manganese salt, phosphate and an inhibitor. Corrosion resistance of the chemical conversion coating was evaluated by anodizing polarization curve and salt immersion. XRD analysis showed that the conversion coating was mainly composed of Mn{sub 3}(PO{sub 4}){sub 2}. The morphology of the coating is observed by using SEM. The effect of electrolyte pH and concentration of inhibitor on coating growth are investigated. (orig.)

Science.gov (United States)

The Eagle Flat basin, an intermontane basin in Trans-Pecos Texas, is being considered as a possible site for the Texas repository of low-level radioactive wastes. Intermontane basins and associated normal faults formed in response to Basin and Range tectonism that began about 24 Ma ago. The most active late Tertiary and Quaternary faults occur within the Hueco Bolson (HB) and the Salt Basin/Salt Flat/Lobo Valley, west and east, respectively, of the proposed repository. Several faults of the southeast HB which are within 50 km of the site, displace middle Pleistocene deposits 10 to 24 m. The most recent surface rupture in the southeast HB probably occurred on the Amargosa fault during the Holocene. Upper Pleistocene deposits are offset 2.5 to 4.5 m, and middle Pleistocene deposits are displaced 24 m. Fault scarps within 50 km east of the proposed repository are associated with faults bounding the Salt ...

Energy Technology Data Exchange (ETDEWEB)

The importance of indigenous soil Mn level on plant Mn uptake from metal salt or sewage sludge amended soils was investigated. Twelve soil materials, six surface and six subsurface, were amended with either varying rates of a composite of Cd, Cu, Ni, and Zn sulfate salts, equivalent to the total of these metals present in a digested sewage sludge (Washington, DC) at rates of 0 to 896 dry metric tons/ha or with the sludge itself, at 224 dry metric tons/ha. Corn (Zea mays L.) was grown in the greenhouse for 30 days, 1 year after amendment application. Two pH levels of about 5.5 and 6.5 were maintained during the experiment on the metal salt amended soil materials. Plant tissue Mn levels increased with the application of Cd, Cu, Ni, and Zn (in combination) as metal salts or as sewage sludge over the range of soil materials used. The amount of increase with a given increase in applied metals was greater for ...

Science.gov (United States)

Quantities and compositions of non-tritium radioactive waste are estimated for some current conceptual fusion reactor designs, and disposal of large amounts of radioactive waste appears necessary. Although the initial radioactivity of fusion reactor and f...

International Nuclear Information System (INIS)

The device of the present invention improves reactor safety by suppressing lowering of water level in a shroud which surrounds a reactor core, even upon occurrence of rupture of pipelines in an emergency reactor core cooling system in a recycling pump-incorporated type reactor. Namely, an opening of each of cooling systems which forms the emergency reactor core cooling device in a reactor pressure vessel is disposed above the upper end of the reactor core. Further, it also comprises an independent high pressure water injection system, gravitational dropping type water injection system and an automatic depressurization system. With such a constitution, even if rupture of pipelines in the system should be assumed, coolants never flow directly from the shroud which surrounds the reactor core. In addition, there are no ...

International Nuclear Information System (INIS)

THe high-temperature reactor is one of the alternatives for the now predominantly employed water-reactors. In a recently published book designer Rudolf Schulten outlines his concept. In this article the book is reviewed. (author). 1 ref.; 1 fig.

Energy Technology Data Exchange (ETDEWEB)

For light water reactors, loss of coolant is an important point in safety analysis, whereas for gas-cooled reactors the ingress of water into the core region is an incident of safety relevance. The applicability of the computer code system GAMTEREX to pebble beds of spherical high-temperature gas-cooled reactor fuel elements with simulated water ingress is verified by experiment. The measurements were performed at a Siemens-Argonaut reactor, using its ring core as a driver zone for a pebble-bed core in the center of the reactor.

International Nuclear Information System (INIS)

Actinides other than the main uranium or plutonium isotopes take a growing part in the different stages of the nuclear cycle. For the French nuclear power program based on the development of light water reactors and fast breeders, many evaluations of the secondary actinides build up are made for the both reactor types using mainly the existing reactor codes. The comparison of these foreseen compositions with experimental results allows to perform some adjustments of the neutronic data. The secondary actinide compositions are given for some typical fuels and their consequences on the nuclear cycle are discussed. An hypothetical burning of these wastes in fast reactors has been studied and the main conclusions are reported.

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion is a novel technology that can be used to meet the demand on energy production without CO{sub 2} emission. To improve CO{sub 2} capture efficiency in the process of chemical looping combustion of coal, a prototype configuration for chemical looping combustion of coal is made in this study. It comprises a fast fluidized bed as an air reactor, a cyclone, a spout-fluid bed as a fuel reactor and a loop-seal. The loop-seal connects the spout-fluid bed with the fast fluidized bed and is fluidized by steam to prevent the contamination of the flue gas between the two reactors. The performance of chemical looping combustion of coal is experimentally investigated with a NiO/Al{sub 2}O{sub 3} oxygen carrier in a 1 kW{sub th} prototype. The experimental results show that the configuration can minimize the amount of residual char entering into the air reactor from the fuel ...

International Nuclear Information System (INIS)

... excursions fftf reactor fuel elements lmfbr type reactors reactivity insertions

Energy Technology Data Exchange (ETDEWEB)

Four low activation alloy classes, two austenitic and two ferritic, have been incorporated into the MOTA-1B experiment in the FFTF reactor to provide an early assessment of the suitability of such alloys for reactor service.

International Science & Technology Center (ISTC)

Development of Technology for Producing High-Effective Nitride Fuel UN with Controlled Microstructure for Advanced Fast Neutron Nuclear Reactors

International Nuclear Information System (INIS)

... 1535-DR(Vol.4). Available from INIS in electronic form breeder reactors

Energy Technology Data Exchange (ETDEWEB)

This document is the annual update of the FFTF and Advanced Reactors Transition Program Resource Loaded Schedule for FY 2002 using current project direction and authorized funding levels

Energy Technology Data Exchange (ETDEWEB)

Published in summary form only.

International Nuclear Information System (INIS)

Of some interest is the comparison between the actinide nuclide burning up (fission) rates such as americium 241, americium 242, curium 244, and neptunium 237, in the reactors with fast or thermal neutron spectra.

Energy Technology Data Exchange (ETDEWEB)

This article gives an account of the recent development of light water reactors new concepts in the world. Different projects are being studied. The CE80+ from Combustion Engineering (CE) is a 1350 MWe-PWR-type reactor whose primary circuit is confined in a spherical metallic containment. This reactor was certified by NRC (national regulatory commission) in mid-1996. The APWR (advanced pressurized water reactor) is developed by MHI (Mitsubishi heavy industries) in a collaboration with Westinghouse, this PWR-type reactor fitted with 4 loops derived from the SP90 model that was developed by Westinghouse during the eighties. 2 units of ABWR (advanced boiling water reactor) were commissioned in Japan in 1996 and 1997, ABWR was certified by NRC in mid-1996. The BWR90+ is developed by ABB-atom (Sweden) and it represents a cautious advanced version of the BWR75. ...

Energy Technology Data Exchange (ETDEWEB)

The partial pressures of the components (ThCl/sub 4/, MCl and MThCl/sub 5/) in the saturated vapours of ThCl/sub 4/ solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl/sub 4/ concentration (2 to 50 mol% ThCl/sub 4/) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl.

Energy Technology Data Exchange (ETDEWEB)

Secondary ion mass spectrometry (SIMS) has been used to investigate changes that occur in an advanced Ir-0.3W alloy during high temperature aging. This alloy is used to clad /sup 238/PuO/sub 2/ heat sources used in thermoelectric generators for deep space reconnaissance satellites. Long-term direct contact with PuO/sub 2/ at 1400/sup 0/C leads to physical and chemical changes within the cladding alloy that affect its metallurgical properties. SIMS was used to show that Cr, Fe, Ni, and in some cases O, diffuse from the PuO/sub 2/ into the alloy. Thorium and aluminum diffuse out of the alloy in these same regions. This SIMS study suggests that inward O diffusion and subsequent formation of ThO/sub 2/ on grain boundaries may stabilize the alloy against enhanced grain growth.

Energy Technology Data Exchange (ETDEWEB)

The near normal incidence reflectivity of the ferromagnets U/sub 3/P/sub 4/ and U/sub 3/As/sub 4/ and the isostructural but diamagnetic compounds Th/sub 3/P/sub 4/ and Th/sub 3/As/sub 4/ has been measured from 0.03 to 12 eV. Trithorium tetraphosphide and tetraarsenide are shown to be indirect gap semiconductors with gap energies of 0.43 and 0.39 eV, respectively. U/sub 3/P/sub 4/ and U/sub 3/As/sub 4/ display similar sets of p..-->..d transitions than the corresponding thorium compounds, however, they are shifted by 0.85 eV to lower photon energies. It is concluded that the uranium compounds are metals due to a merging of the valence p band into the 6d conduction band giving direct experimental evidence for a p-f mixing effect of the same size. Energy level schemes are derived.

International Nuclear Information System (INIS)

Thorium-230, together with "2"3"8U and "2"2"6Ra, was determined (mainly by #gamma#-spectrometry) in samples from the waste piles at Borst and Jazbec in the vicinity of the former uranium mine at Zirovski vrh, Slovenia. Activity (and in the case of uranium, also mass) balances for these nuclides were constructed for the overall operation of the mine and yellow cake plant, using experimental data and known data on ore and uranium production, and nuclide emissions to the environment. All the "2"2"6Ra resulting from ore exploitation is presently contained in the Borst tailings pile. However, because of the very high content of "2"3"0Th in red mud deposited at Jazbec, where 60% of this nuclide is found, the majority of "2"2"6Ra will be found at the Jazbec pile in the future, due to its ingrowth from "2"3"0Th over the next few thousand years. (Author).

Energy Technology Data Exchange (ETDEWEB)

The Korea Atomic Energy Research Institute has launched a decommissioning program of uranium conversion plant. One of the important tasks in the decommissioning program is the treatment of the sludge, which was generated during operation and stored in the two ponds of the lagoon. The treatment requires the volume reduction of lagoon sludges for the low cost of the program and the conversion of the chemical forms, including uranium, for the acceptance at the final disposal site. The physical properties, such as densities, were measured and chemical compositions and radiological properties were analyzed. The denitration was a candidate process which would satisfy the requirements for sludge treatment, and the characteristics of thermal decomposition and dissolution with water were analyzed. The main compounds of the sludge were ammonium and sodium nitrate from conversion plant and calcium nitrate, calcium carbonate from Ca precipitation and impurities of the yellow cake. The content of ...

International Nuclear Information System (INIS)

Naturally occurring radionuclides are present in most material. The most common naturally occurring radionuclides in material are those of the uranium and thorium series and potassium-40. This material is commonly referred to as Naturally Occurring Radioactive Material (NORM). In some material the levels of naturally occurring radionuclides are significantly higher, to the extent that regulatory control may be required for radiation protection purposes. Regulation of NORM presents a range of new challenges for both regulators and operators. Unlike more traditional industries dealing with radionuclides, NORM industries have generally not had any radiological oversight and, for example, are not equipped for radiological monitoring. Some consumer goods containing NORM, which have not traditionally been considered as a radiological problem (such as some fertilizers), may require regulation and this may have social and economic consequences. The transport and disposal ...

Energy Technology Data Exchange (ETDEWEB)

Three phosphate based ceramics were studied for the immobilization of tri- and tetravalent actinides: britholites Ca{sub 9}Nd{sub 1-x}An{sub x} {sup IV}(PO{sub 4}){sub 5-x}(SiO{sub 4}){sub 1+x}F{sub 2}, monazites/brabantites Ln{sub 1-2x}{sup III}Ca{sub x}An{sub x}{sup IV}PO{sub 4} and Thorium Phosphate Diphosphate (TPD) Th{sub 4-x}An{sub x}{sup IV}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}. For each material, the incorporation of Th, U(IV), or Ce(IV) in the structure was examined. This work was the early beginning of the incorporation of {sup 239}Pu and/or {sup 238}Pu in order to evaluate the effects of {alpha} -decay on these three crystallographic structures. The syntheses were carried out using dry chemistry methods, involving mechanical grinding then heating treatment (1100 deg C {<=} {theta} {<=} 1400 deg C). For britholites, we showed that the incorporation of thorium was complete for weight loading lower than 20 wt.% through the ...

International Nuclear Information System (INIS)

... p. SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS algorithms

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

... bwr type reactors closures fluidic control devices operation performance pwr

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to describe instrumentation and control (I C) system improvements at Experimental Breeder Reactor 11 (EBR-11). The improvements are focused on three objectives; to keep the reactor and balance of plant (BOP) I C systems at a high level of reliability, to provide diagnostic systems that can provide accurate information needed for analysis of fuel performance, and to provide systems that will be prototypic of I C systems of the next generation of liquid metal reactor (LMR) plants.

International Nuclear Information System (INIS)

Short communication.

Energy Technology Data Exchange (ETDEWEB)

Results of tests on the 1 kg/h continuous reactor for the hydroliquefaction of coal are described. The reactor was operated at 415-435 C and 21 MPa using a continuous stirred reactor with a retention time of about 2 hours. All product oils were recovered by distillation. Sub-bituminous coal was found to give the best product yield. Tests using 5% red mud and 3% improved red mud showed significant increases in oil yield. (4 refs.)

International Nuclear Information System (INIS)

... 1343-3563 v. 57(1) SPECIFIC NUCLEAR REACTORS AND ASSOCIATED

Energy Technology Data Exchange (ETDEWEB)

A new reactor concept is described which would enable fission fragments to be continuously extracted from the reactor. Such a reactor has the potential of enabling extremely energetic and ambitious deep space missions. In this talk the basic physics issues involved in the operation of this type of reactor are outlined, and some possible applications to space exploration are described. 3 refs., 2 figs., 3 tabs.

Science.gov (United States)

Photographs are presented of the FFTF reactor facility, components, and some materials.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

The costs of establishing a computer-based training program for FFTF reactor operators are analyzed.

Science.gov (United States)

Not Available

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

The Salt Decontamination Demonstration confirmed that the precipitation process could be used for large-scale decontamination of radioactive waste sale solution. Although a number of refinements are necessary to safely process the long-term requirement of 5 million gallons of waste salt solution per year, there were no observations to suggest that any fundamentals of the process require re-evaluation. Major accomplishments were: (1) 518,000 gallons of decontaminated filtrate were produced from 427,000 gallons of waste salt solution from tank 24H. The demonstration goal was to produce a minimum of 200,000 gallons of decontaminated salt solution; (2) cesium activity in the filtrate was reduced by a factor of 43,000 below the cesium activity in the tank 24 solution. This decontamination factor (DF) exceeded the demonstration goal of a DF greater than 10,000; (3) average strontium-90 activity in the ...

Energy Technology Data Exchange (ETDEWEB)

A a result of its former role as a producer of nuclear weapons components, the Rocky Flats Environmental Technology Site (RFETS), Golden, Colorado accumulated a variety of plutonium-contaminated materials. When the level of contamination exceeded a predetermined level (the economic discard limit), the materials were classified as residues rather than waste and were stored for later recovery of the plutonium. Although large quantities of residues were processed, others, primarily those more difficult to process, remain in storage at the site. It is planned for the residues with lower concentrations of plutonium to be disposed of as wastes at an appropriate disposal facility, probably the Waste Isolation Pilot Plant (WIPP). Because the plutonium concentration is too high or because the physical or chemical form would be difficult to get into a form acceptable to WIPP, it may not be possible to dispose of a portion of the residues at WIPP. The pyrochemical salts are ...

Science.gov (United States)

Dr. Rudolf Schulten of West Germany and expert witnesses from national laboratories, utilities, and the nuclear industry testified on reactor safety issues as they relate to the Chernobyl accident and public concern that modern technology has not paid enough attention to public safety. Each of the witnesses contributed safety-related information based on what has been learned from the Soviet incident. Particular focus went to similarities and differences between the Chernobyl and US reactors in safety design and engineering and to the environmental effects of the accident. The N reactor near Richland and a commercial reactor at Fort St. Vrain, Colorado are the only two operating graphite reactors, but neither is a boiling water reactor.

International Nuclear Information System (INIS)

Since the first round of conceptual fusion reactor designs in 1973 - 1974, there has been considerable progress in design improvement. Two recent tokamak designs of the Wisconsin and Culham groups, with increased plasma beta and wall loading (power density), lead to more compact reactors with easier maintenance. The Reference Theta-Pinch Reactor has undergone considerable upgrading in the design of the first wall insulator and blanket. In addition, a conceptual homopolar energy storage and transfer system has been designed. In the case of the mirror reactor, there are design changes toward improved modular construction and ease of handling, as well as improved direct converters. Conceptual designs of toroidal-multiple-mirror, liner-compression, and reverse-field pinch reactors are also discussed. A design is presented of a toroidal multiple-mirror reactor that ...

International Nuclear Information System (INIS)

The invention concerns an integrated nuclear reactor comprising natural convection cooling of the supporting skirt on which rests the shield closing the reactor vessel. Cooling is achieved by making the air circulate from the bottom to the top around the skirt and removing this air by a stack. The air can be atmospheric air or air taken from the low parts of the reactor. In the latter case, the stack emerges near a metal roof releasing its heat to the atmosphere by radiation, the air then dropping to the low parts. Application to fast nuclear reactors.

International Nuclear Information System (INIS)

The most important and difficult part of materials research for fusion reactor is realized to be irradiation studies of fusion reactor materials. Irradiation studies of fusion reactor materials utilizing FFTF/MOTA, as one of Japan/U.S.A. Fusion Collaboration Programs, have important role to establish fundamental understanding of heavy irradiation effects on materials behavior and properties and to develop methods and technologies for advanced irradiation studies under fusion reactor environment. This paper briefly reviews the history, the state of the art, and the future of the FFTF/MOTA program. (author).

CERN Document Server

We improve the steady-state ab initio laser theory (SALT) of Tureci et al. by expressing its fundamental self-consistent equation in a basis set of threshold constant flux states that contains the exact threshold lasing mode. For cavities with non-uniform index and/or non-uniform gain, the new basis set allows the steady-state lasing properties to be computed with much greater efficiency. This formulation of the SALT can be solved in the single-pole approximation, which gives the intensities and thresholds, including the effects of nonlinear hole-burning interactions to all orders, with negligible computational effort. The approximation yields a number of analytic predictions, including a "gain-clamping" transition at which strong modal interactions suppress all higher modes. We show that the single-pole approximation agrees well with exact SALT calculations, particularly for high-Q cavities. Within this range of validity, ...

Energy Technology Data Exchange (ETDEWEB)

As the surroundings of objects of oil exploration grow more complicated, seismic survey methods have turned 3-dimensional and, in this report, several models are examined using the 3-dimensional simulation technology. The result obtained by the conventional wave tracking method is different from actual wavefields, and is unrealistic. The difference method among the fullwave modelling methods demands an exorbitantly long computation time and high cost. A pseudospectral method has been developed which is superior to the difference method, and has been put to practical use thanks to the advent of parallel computers. It is found that a 3-dimensional survey is mandatory in describing faults. After examining the SEG/EAGE Salt model, it is learned that the salt is well-developed and that 3-dimensional depth migration is required for sub-salt exploration. It is also found through simulation of the EAGE/S Overthrust model, which is ...

International Nuclear Information System (INIS)

A trans-uranium (TRU) fuel should be manufactured and loaded in transmutation systems in order to transmute the long-lived TRU nuclides into short-lived ones. However, since all of the TRU nuclides are not completely transmuted in one cycle lifetime in transmutation systems, the spent TRU fuel has to be treated to recover the long-lived radionuclides or fuel matrix materials. One concept to manufacture TRU fuel for transmutation is to recover uranium from TRU and molten salt. If this type of fuel is adopted for transmutation, uranium could also be an objective material to be recovered and recycled. Since electrowinning is a promising technology to be employed for the recovery of uranium from fuel materials, some experimental work of electrowinning using anode of Cd-Li alloy was carried out in this study. The basic salt chosen was a mixture of LiCl-KCl which has an eutectic point at 357 .deg. C

Energy Technology Data Exchange (ETDEWEB)

The United States Air Force School of Aerospace Medicine (USAFSAM) tests the quantitative fit of masks which are worn by military personnel during nuclear, biological, and chemical warfare. Subjects are placed in a Dynatech-Frontier Fit Testing Chamber, salt air is fed into the chamber, and samples of air are drawn from the mask and the chamber. The ratio of salt air outside the mask to salt air inside the mask is called the quantitative fit factor. A motion-time study was conducted to evaluate the efficiency of the layout and work method presently used in the laboratory. A link analysis was done to determine equipment priorities, and the link data and design guidelines were used to develop three proposed laboratory designs. The proposals were evaluated by projecting the time and motion efficiency, and the energy expended working in each design. Also evaluated were the lengths of the equipment links for each proposal, and ...

Energy Technology Data Exchange (ETDEWEB)

The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste form increased with brine temperature, and waste forms from brine at the boiling point exhibited a near ...

British Library Electronic Table of Contents (United Kingdom)

A series of spinel Li4Ti5O12 samples were synthesized via a composite molten-salt method (CMSM) using the mixtures of LiCl and KCl with different L values (L is defined as the molar ratio of LiCl:KCl) as the reaction media. It is found that the melting point of the composite molten salt can effectively influence the formation of particles, and leads to different electrochemical performances of the as-prepare Li4Ti5O12. The investigations of X-ray diffraction (XRD), particle size distribution (PSD), Brunauer-Emmet-Teller (BET) surface area, and scanning electron microscopy (SEM) indicate that the as-prepared Li4Ti5O12 with L=1.5 is a pure phase, and has uniform homogeneous octahedral shape particles, rather narrow PSD, and high BET surface area. Electrochemical tests show that the optimized...

Energy Technology Data Exchange (ETDEWEB)

Hydrolysis of olive oil by Chromobacterium viscosum lipase was studied in a reverse micellar system of a anionic surfactant Aerosol OT (AOT) and isooctane. Different methods of solubilization of the micellar system afford specific dependence of enzymatic activity of the lipase on the water content in the micelles. In an injection method, water content is controlled by the amount of injected water, which determines the micelle size and hydrophobicity of the micelle without salt addition and changes reversibly the conformation of lipase corresponding to the change of lipase activity. The activity reaches the maximum at a water content (water/AOT)of 7. In a phase transfer method, water content is determined by salt concentration in the aqueous phase in contact with micelles and the water content corresponding to the maximum activity is 12 to 13, below which the activity decrese drastically. Addition of taurodeoxycholic acid to the AOT micelles ...

International Nuclear Information System (INIS)

In order to effectively recover uranium, rotation speed of solid cathode was examined, and effect of uranium concentration and current density on electrodeposition were confirmed. And the potentiostatic and galvanostatic electrorefining experiments were conducted. Element used in the experiments were Zr, Nd, La chlorides. The reduction potentials of chlorides metals on liquid Cd cathode were measured by cyclic voltammetry experiments. The electrowinning experiments were performed in order to recover small amounts of uranium in salt. Experimental set-up for the batch type reductive extraction experiments were developed and installed. On the base of experimental results of batch type, multi-stage extraction equipment was set-up, and optimum number of stage and recover yield were measured. In the oxidative extraction study is examine selective separation behavior of the rare earth metals from alloy composed of actinide and lanthanide metals to determine the effective ...

British Library Electronic Table of Contents (United Kingdom)

Abstract The salts [Cnmim]2[Mo6Cl14] (mim = methylimidazolium; n = 4, 6, 12, 16, 18) have been obtained by reaction of CnmimCl with MoCl2. Thermal analysis shows the melting point decreases with increasing alkyl chain length of the cation. The imidazolium chloromolybdates(II) with n = 6-18 decompose above 340 C; [C18mim]2[Mo6Cl14] is thermally stable up to 390 C. All compounds are insensititve to the constituents of the atmosphere. Of the higher melting salts [Cnmim]2[Mo6Cl14] (n = 4, 6), high-quality single crystals could be obtained. Single-crystal X-ray structural analyses clearly show that the cluster complex anion [Mo6Cl14]2- has an electron-precise octahedral {Mo6} cluster. For [C4mim]2[Mo6Cl14], two polymorphs differing in the cation alkyl-side-chain conformation were obtained. The ...

Energy Technology Data Exchange (ETDEWEB)

The rate of the oxygen-exchange reaction in an aqueous solution of a heterocyclic oxygen compound, 2,4,6-trimethylpyrylium perchlorate, was quantitated. The /sup 18/O isotope effect in /sup 13/C NMR spectroscopy affords a direct, continuous, and relatively simple analysis of the reaction and was used to obtain data on the incorporation of /sup 18/O from solvent H/sub 2//sup 18/O into the pyrylium salt. Due to the low solubility of this salt in aqueous solutions, 2,4,6-trimethyl(2-/sup 13/C)pyrylium perchlorate and 2,4,6-trimethyl(2,6-/sup 13/C/sub 2/)pyrylium perchlorate were synthesized to facilitate the acquisition of the data on an NTC-200 spectrometer operating at 50.31 MHz. Upon incorporation of /sup 18/O into the pyrylium salt, the /sup 13/C NMR signal of the directly bonded carbon atom is shifted upfield 0.038 ppm. A /sup 13/C isotope effect is also detected in the doubly /sup 13/C-enriched pyrylium ...

Energy Technology Data Exchange (ETDEWEB)

A new technique has been developed for improving corrosion resistance on magnesium alloys. Specimens of AZ31 magnesium alloy were dipped into molten salt of NaBF{sub 4} at 723 K for various times, and then cooled, rinsed with water, and dried in air. Corrosion resistance in the surface treated specimens was evaluated by salt immersion test using 1% NaCl solution as a time for occurring filiform corrosion. On an un-treated AZ31 alloy, the time for starting the filiform corrosion was about 1.2 ks, while on the surface treated specimen, the time was prolonged into about 1300 ks. Moreover, the surface treated specimen showed corrosion resistance in low pH solutions, such as 1% HNO{sub 3} and HCl solutions. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and leaching operations involve batchwise mixing, settling, and ...

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This report documents the findings of the peer panel constituted by Argonne National Laboratory to review Region A of Westinghouse Electric Corporation's report entitled Waste Package Reference Conceptual Designs for a Repository in Salt. The panel determined that the reviewed report does not provide reasonable assurance that US Nuclear Regulatory Commission (NRC) requirements for waste packages will be met by the proposed design. It also found that it is premature to call the design a ''reference design,'' or even a ''reference conceptual design.'' This review report provides guidance for the preparation of a more acceptable design document.

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The kinetics of the solubilization of lauric acid, palmitic acid, stearic acid, and monopalmitin have been studied in detergent solutions as a function of concentration, temperature, and fluid flow. The detergents used were sodium dodecyl sulfate (an anionic surfactant), decyltrimethylammonium bromide (a cationic surfactant), sodium taurocholate (a trihydroxy bile salt), sodium taurodeoxycholate (a dihydroxy bile salt), and triton X-100 (a nonionic surfactant). At low temperature, solubilization can be described by a five-step mechanism is which micelle desorption and diffusion are rate controlling. At temperatures above the fatty acid penetration temperature, solubilization is governed by formation of a liquid crystalline phase at the fatty acid-detergent solution interface.

British Library Electronic Table of Contents (United Kingdom)

Proteins aggregated into spherulite structures of amyloid fibrils have been observed in patients with certain brain diseases such as Alzheimers and Parkinsons. The conditions under which these protein spherulites form and grow are not currently known. In order to illuminate the role of environmental factors on protein spherulites, this research aims to explore the kinetics and mechanisms of spherulite formation and growth, as monitored by optical microscopy, in a range of salt concentrations, and initial protein concentrations for two model proteins: bovine b-lactoglobulin and insulin. These two proteins are significantly different in their size and fibril growth rate, but both of these proteins have been shown previously to form amyloid fibrils and spherulites under low pH conditions. The...