An integrated plan on flood defence for the river Weser
In the wake of the disastrous flooding in 1997 on the river Oder and in 1994/95 on the river Rhine the 49{sup th} conference of the Environment Ministers appointed the river basin working groups in Germany to work out action plans on flood defence for all the large river basins. This was achieved in 1998. This year the five federal states Bremen, Hesse, Lower-Saxony, North-Rhine/Westfalia and Thuringia represented by the Working Group for the Protection of the River Weser ''ARGE Weser'', adopted this paper and published it in the recent weeks. This is the first time that the ARGE Weser has addressed flooding problems. A working group consisting of the flooding specialists of the five states and the Waterways administration was formed with the brief to analyse the existing system on flood defence. (orig.)
Comparison of tracer methods to quantify hydrodynamic exchange within the hyporheic zone
SummaryHydrodynamic exchange between surface-water and groundwater was studied at a river located within the Rhine Valley in Germany. Piezometric pressure heads and environmental tracers such as temperature, stable isotopes, chloride, X-ray contrast media, and artificial sweetener were investigated within the hyporheic zone and river water plume. Vertical profiles of environmental tracers were collected using multi-level wells within the neutral up-gradient zone, beneath the river bed, and within the horizontal proximal and distal down-gradient zone. Infiltration velocities were calculated from pressure heads, temperature fluctuations and gradients. The amount of river water within groundwater was estimated from vertical profiles of chloride, stable isotopes, and persistent pharmaceuticals...
Methyl tert-butyl ether (MTBE) in finished drinking water in Germany.
In the present study 83 finished drinking water samples from 50 cities in Germany were analyzed for methyl tert-butyl ether (MTBE) content with a detection limit of 10 ng/L. The detection frequency was 46% and the concentrations ranged between 17 and 712 ng/L. Highest concentrations were found in the community water systems (CWSs) of Leuna and Spergau in Saxony-Anhalt. These CWSs are supplied with water possibly affected by MTBE contaminated groundwater. MTBE was detected at concentrations lower than 100 ng/L in drinking water supplied by CWSs using bank filtered water from Rhine and Main Rivers. The results from Leuna and Spergau show that large groundwater contaminations in the vicinity of CWSs pose the highest risk for MTBE contamination in drinking water. CWSs using bank filtered water from Rhine and Main Rivers are susceptible to low MTBE contaminations in finished drinking water. All measured MTBE concentrations were below proposed limit values for drinking water. PMID:16171912
Genetic variation of Eryngium campestre L. (Apiaceae) in Central Europe.
In Germany, Eryngium campestre is restricted to dry habitats along the rivers Rhine and Elbe and to a few areas in Central Germany. This distribution pattern is usually regarded as a typical pattern of postglacial immigration. In the present study, we investigated whether these two geographically distinct distribution areas are genetically differentiated and whether conclusions can be drawn regarding colonization history. To analyse the phylogeographic structure of E. campestre in Central Europe, 278 individuals from 29 populations within Germany and from further reference populations within Europe were analysed. We applied amplified fragment length polymorphisms to examine their genetic relatedness. Our analyses revealed three groups: a Mediterranean group additionally including two Rhine populations; a Rhine-Main group which further includes the westernmost population from the central German dry area; and one group which includes all eastern populations. Our results show that the two geographically distinct areas are genetically differentiated. As genetic diversity within the Elbe populations is very low, we conclude that this area, which was strongly affected through the late glacial maximum, was colonized relatively recently. High genetic diversity in the Rhine populations indicates a contact zone where lineages of different origin met. This would imply that today's patterns of genetic variation were caused through glacial range contractions and expansions. The present study is one of the first studies that deal with the postglacial distribution pattern of a dry grassland plant species in Central Europe and the results suggest that a survival of E. campestre at least during the Dryas cold stage might be possible. PMID:18564089
Bankside groundwater is widely used as drinking water resource and, therefore, contamination has to be avoided. In the European Union groundwater protection is explicit subject to Water Framework Directive. While groundwater pollution may originate from different sources, this study investigated on impacts via flood events. Groundwater was sampled with increasing distance to the river Rhine near Karlsruhe, Germany. Samples were HPLC-MS-MS analyzed for the river contaminant carbamazepine to indicate river water infiltration, giving permanent presence in 250m distance to the river (14-47mgL-1). Following a flood event, concentrations of about 16-20mgL-1 could also be detected in a distance of 750m to the river. Furthermore, estrogenic activity as determined with the Yeast Estrogen Screen ass...
Reconstructing peak discharges for historic flood levels in the city of Cologne, Germany
Historic settlements which have developed in close proximity to rivers often contain numerous descriptions and/or epigraphic markings depicting flood levels relative to historic buildings, most of which are dated and have been inherited from long before the first river gauges were installed. Such evidence of historic flood water levels is regularly used to determine periods of increased flood frequency but, because of several methodological challenges, they are rarely used to calculate palaeodischarge. Due to missing information regarding the historic topography and hydraulic roughness of the floodplain and the river channel, the major problem tends to be the reconstruction of the river channel cross-section. The city of Cologne, located on the Lower Rhine in western Germany, has flood des...
Downstream migration of Anguilla anguilla silver eels was studied in the Lower Rhine, Germany, and the Rhine Delta, The Netherlands, in 2004-2006. Fish (n = 457) released near Cologne with implanted transponders were tracked by remote telemetry at 12 fixed detection locations distributed along the different possible migration routes to the North Sea. Relatively more A. anguilla migrated via the Waal than the Nederrijn, as would be expected from the ratio of river discharges at the bifurcation point at Pannerden. Downstream migration from the release site to Rhine-Xanten, close to the German-Dutch border, generally occurred in the autumn of the year of release but migration speeds tended to be low and variable and unaffected by maturation status or river discharge rates. Detection frequencies were not significantly related to discharge peaks or lunar cycles, but there was a minor detection peak 1-6 h after sunset. Between 2004 and 2009, 43% of the 457 A. anguilla released were never detected and of the 260 detected entering the Netherlands, 83 (32%) were detected escaping to the sea, 78 (94%) via the Nieuwe Waterweg and three (4%) and two (2%) via the sluices in the Haringvlietdam and Afsluitdijk, respectively. Possible causes of non-detections are discussed and it is suggested that many A. anguilla temporarily ceased migration, but that fishing mortality could have been important during passage through the Dutch parts of the Rhine. Practical implications of the results for predicting emigration routes, timings and magnitudes and use in management initiatives to promote escapement of A. anguilla silver eels to the sea are critically discussed. PMID:20735693
Regional climate change scenarios were studied with the water balance model GROWA (Kunkel and Wendland, 2002) to predict the temporal development of mean long - term total runoff, direct runoff and groundwater runoff, including regionally dif-ferentiated analyses for river basins, regions and administrative units. Special emphasizes was given to the regionally differentiated prediction of the mean long-term impacts on groundwater recharge, which determines both, the river discharge and ecological status of rivers during dry periods, as well as the upper limit for the sus-tainable abstraction of groundwater (e.g. prognosis of groundwater hydrograph trends in regions, where water supply is fed from groundwater). As a reference, the GROWA model was calibrated and validated for the hydrological period 1971 - 2000 in an area of ca. 90.000 km² in the North - Western part of Germany, i.e. for the entire Federal States of North Rhine - Westphalia, Lower Saxony, Hamburg and Bremen.
Acanthocephalus rhinensis n. sp. is described from the European eel. Anguilla anguilla (Linnaeus, 1758), collected in the Rhine River near the city of Karlsruhe, Germany. It is the sixth species of Acanthocephalus Koelreuther, 1771 described from European fish. Four other species are known from amphibians. The new species is distinguished from the other 5 species infecting fish by having a 1.2-mm-long proboscis armed with 15-21 rows of 13-16 hooks each, lemnisci about as long as receptacle, oblong and slightly pre-equatorial testes, and thin fusiform eggs, measuring 85-95 X 15-18 micro. Testes in the other European species are usually round to ovate, except in Ac. anguillae (Müller, 1780) Lühe, 1911 where they are also elongated but postequatorial. It aslo has an orange-brown belt encircling the anterior end of the trunk. The comparative distribution of Acanthocephalus in Europe and North America, and the validity of 2 presumably questionable species are discussed, Acanthocephalus falcatus (Froelich, 1789) Lühe, 1911 and Ac. Paronai (Cendorelli, 1897) Meyer, 1932. A dichotomus key distinguishing Ac. rhinensis from the other 9 European species is also included. The new species was only found in 3 of 390 eels examined during 11 yr; this may be related to the changing benthos community in the Rhine River. PMID:18576852
Effects of Climate Change on Water Resource and Hydrological Extremes in Germany
Different studies show that the expected climate change has already influenced the hydrological cycle and the runoff behavior of catchments in Germany, and the more frequent extreme events rose to be a particular concern during the recent years. In Germany, where hydrological and climatic patterns differ in various regions, it is an important task to assess both the extent and the spatial distribution of these impacts, as it helps an overall decision making for the country scale. The process-based ecohydrological model SWIM (Soil and Water Integrated Model) was applied for the whole of Germany, and the simulated results were calibrated (from 1981 to 1990) and validated (from 1961 to 1980) at several selected gauges in the five largest river basins (lower Rhine, upper Danube, Elbe, Weser and Ems). The potential effects of climate change on the hydrology and water resources are assessed by simulating with the scenarios derived from statistic downscaled climate model STAR (scenario period: 2009-2060) and the dynamic downscaled model CCLM (scenario period: 2001-2010). Different indicators were applied to compare the simulation results for the reference period (1961-1990) and scenario periods (2051-2060 for STAR with 100 realizations and 2011-2040, 2041-2070 and 2071-2100 for CCLM with 1 realization). The indicators, such as average seasonal river discharge, average annual water components (i.e., water runoff, groundwater flow and actual evapotranspiration) assess the impacts on hydrological cycle and the runoff pattern for the whole Germany, while the annual maximum daily discharge, the annual minimum 7-day average of discharge and the river discharge values exceeded between 0.1% and 99.9% of the time were used especially for extreme analysis. The results simulated with the realizations from model STAR show that in summer time, all the five rivers will have less river flows and the decline is substantially strong in river Elbe and Danube. Higher actual evapotranspiration is expected in most part of Germany mainly due to the increased temperature. The East Germany may face severe water stresses in the future while in northwest, it may become wetter especially in winters. The scenarios taken from the dynamic climate model CCLM lead to a moderate impact on the hydrological components. Floods may become higher and more frequently in the scenario periods in most rivers while the decreasing annual minimum low flow indicates that even in northwest wet regions, the summer low flow condition can be a serious problem and the river management should be adapted.
Changes in soil properties in a fluvisol (calcaric) amended with coal fly ash
Fluidized bed combustion ash (FBC) is a by-product from coal-fired power stations used for many decades in concrete, cement and brick manufacturing and more recently for trace metal immobilization and pesticide retention in soils. Moreover FBC ash has been recommended by some authors as a soil amendment in agriculture for its nutrient supply. In this study silico-aluminous (SiAl) and sulfo-calcic (SCa) fly ashes have been added to a fluvisol (calcaric) sampled in the Rhine River plain (Germany) in order to investigate the physical, chemical and physico-chemical possible modifications of the amended soil. Earthworms were introduced into microcosms hydrated with a solution of water and CaCl2 (3.7 10^-^4mg/L; pH=6.2) and stabilized during 7 and 14weeks. Batch leaching tests were performed dur...
Crocuta crocuta spelaea (Goldfuss, 1823) remains (NISP = 50) are present in the early to middle Upper Pleistocene Emscher River terrace open air den site along the Rhine-Herne Canal near Bottrop (Westphalia, NW Germany). The population includes bones from cubs and bones with pathological features from old animals but is predominantly made up of adult hyenas (NISP = 3820) found within the glacial mammoth steppe fauna of the Munsterland Bay Lowlands. A larger quantity of woolly rhinoceros (Coelodonta antiquitatis) bones (NISP = 1601) are present than in other bone-rich open air hyena den sites, of which about 67% are damaged. This damage can be shown to have resulted mainly from hyena activities, and shows repetitions of the same three stages of destruction on the massive woolly rhinoceros b...
From 1976 until 1982 854 fishes from the Rhine and in 1983 43 fishes from the Main-river were analysed for mercury, from 1980 until 1982 212 fishes from the Rhine and in 1983 43 fishes from the Main-river were analysed for lead and cadmium. The analytical behaviour of these elements with special emphasis on the digestion is described. The results demonstrate that the contamination of the fishes from the Rhine by mercury has decreased within the period. This becomes also evident by the decreasing number of samples which exceed the tolerances. For lead and cadmium no trend can be deduced from the results. The contamination, however is appreciably higher than in unpolluted waters. Cadmium and lead seem to increase in concentration during the course of the river as demonstrated by a comparison of results from different stretches of this river. BGA-guide values (Federal Office of Health) were exceeded in some samples.
Potential gains from mergers in local public transport: an efficiency analysis applied to Germany
We analyze potential gains from hypothetical mergers in local public transport using the non-parametric Data Envelopment Analysis with bias corrections by means of bootstrapping. Our sample consists of 41 public transport companies from Germany's most densely populated region, North Rhine-Westphalia...
School choice in German primary schools. How binding are school districts?
The paper analyzes school choice in primary schools in Germany. The data used is from Wuppertal, a major city in North-Rhine Westphalia (NRW), where primary school districts existed before 2008. It is shown that it is not uncommon to attend a primary school that is not the assigned public school. Pa...
For the first time ever in the Federal Republic of Germany a mediation procedure on a waste management concept has been carried out. It took place in Neuss in the German federal state of North Rhine-Westphalia. The interdisciplinary project group, Environmental Mediation, from the Science Centre Ber...
In many European rivers, including the major streams of the Rhine and Elbe basins, the nutrient load (N and P) still exceeds target levels. In this paper, a model is presented that describes the river nutrient load as a function of nutrient sources, runoff and lithology in the upstream basin. The mo...
Genetic diversity and differentiation were studied in Corrigiola litoralis L., an annual plant species growing on seasonally flooded river banks. Plant species that are restricted to river systems may consist of highly isolated populations. For this species, pronounced genetic differentiation among rivers was expected. Plants were sampled from the river Loire (France) representing subcentral populations and the rivers Rhine, Weser and Elbe (Germany) representing peripheral ones. Allozyme electrophoresis revealed 17 putative loci in 11 enzyme systems. At the species level, percentage polymorphic loci, mean number of alleles, observed heterozygosity and expected heterozygosity were P=29%, A=1.5 +/- 0.2, Ho=0.007 +/- 0.005 and He=0.065 +/- 0.035, respectively. Peripheral populations were smaller in number and showed decreased levels of genetic diversity relative to central populations. Corrigiola litoralis was highly inbreeding as indicated by a mean FIS of 0.755. Genetic differentiation among populations was high with a mean FST-value of 0.585. Hierarchical F-statistics revealed that genetic variability was partitioned at 57% among sites, 52% among countries and 11% among sites within countries. Genetic distances between French and German populations were 0.08, indicative of considerable differentiation at the intraspecific level. The overall low level of allozyme diversity is attributed to the breeding system and to habitat conditions homogenized by regular flooding. The decrease in diversity from subcentral to peripheral populations is considered to be a result of drift and founder effects during postglacial recolonization. Peripheral populations were characterized by a single fixed allele at locus IDH, thus representing an evolutionarily significant unit. PMID:10583550
Modelling sediment input in large river basins
Erosion and sediment redistribution play a pivotal role in the terrestrial ecosystem as they directly influence soil functions and water quality. In particular surface waters are threatened by emissions of nutrients and contaminants via erosion. The sustainable management of sediments is thus a key challenge in river basin management. Beside the planning and implementation of mitigation measures typically focusing on small and mesoscale catchments, the knowledge of sediment emissions and associated substances in large drainage basins is of utmost importance for water quality protection of large rivers and the seas. The objective of this study was thus to quantify the sediment input into the large drainage basins of Germany (Rhine, Elbe, Odra, Weser, Ems, Danube) as a basis for nutrient and contaminant emissions via erosion. The sediment input was quantified for all watersheds of Germany and added up along the flow paths of the river systems. Due to the large scale, sediment production within the watersheds was estimated based on the USLE for cultivated land and naturally covered areas and on specific erosion rates for mountainous areas without vegetation cover. To quantify the sediment delivery ratio a model approach was developed using data on calculated sediment production rates and long term sediment loads observed at monitoring stations of 13 watersheds located in different landscape regions of Germany. A variety of morphological parameters and catchment properties such as slope, drainage density, share of morphological sinks, hypsometric integral, flow distance between sediment source areas and the next stream as well as soil and land use properties were tested to explain the variation in the sediment delivery ratios for the 13 watersheds. The sediment input into streams is mainly controlled by the location of sediment source areas and the morphology along the flow pathways to surface waters. Thus, this complex interaction of spatially distributed catchment properties cannot be characterized using only spatially lumped parameters for watersheds located in very different landscape regions. From all parameters tested, the mean slope of the watersheds and the share of arable land located in a distance of 500 m revealed a significant relation to the sediment delivery ratio. Using both parameters the sediment input was quantified for all other watersheds of Germany showing a good agreement with observed long term sediment loads at monitoring stations.
In the past the quality of receiving waters has been continuously improved by upgrading measures on both industrial and urban waste water treatment plants (WWTP) and sewer systems. However, latest inventories of sources and pathways of pollutants originating from industrial and domestic use and activities, for example carried out for the river Rhine catchment, emphasize the importance of diffuse nonpoint pollution on water quality in urbanized river catchments in comparison to the loads of point sources form industrial or urban WWTPs, for which a reduction on about 70% of the status of 1985 was considered in 1995. In order to obtain detailed information on the fate of heavy metals in river catchments, this study was carried out mainly to collect representative literature about possible diffuse nonpoint pollution sources, to monitor concentration of heavy metals (Cd, Cr, Cu, Pb, Hg, Ni and Zn) in stormwater overflows and to assess these loads discharged into receiving waters. An extensive literature survey was carried out resulting in a database containing 121 references with more than 2100 values especially about the pollution sources FARMING and URBAN INFRASTRUCTURE. The database was adapted to the register on diffuse nonpoint pollution of the International Commission for the Protection of the Rhine (ICPR). While only a few references on diffuse nonpoint pollution sources were evaluated for Hg, Cr and Ni and the pathways within the urban drainage systems (e.g. effluents of stormwater retention basins, combined sewer overflows) a remarkable number of references could be collected for the other heavy metals and diffuse sources and pathways respectively. Due to the lack of precise data on the current state of the art of stormwater treatment in Germany a field study was carried out in Herrenberg. Objects of the investigation were two different stormwater retention basins (SRB) at two well defined catchments. In the field study about nine events of stormwater overflows at SRB 1 and eleven events at SRB 2 were sampled. The results (event mean concentration) indicate a high level but match the values of the evaluated references. However, specific heavy metal pollution loads referring to the impervious catchment area show high values in particular SRB 1 with its urbanized hinterland. Based on the evaluated literature database and observed EMCs in stormwater overflows a semi-empirical model has been developed to assess heavy metal loads in receiving waters from considered pollution sources. (orig.)
We have applied a recently introduced proxy, the BIT (branched and isoprenoid tetraether) index, to determine terrestrial organic matter (TOM) transport from the rivers Rhine and Meuse and their tributaries to the southern North Sea. This index is based on crenarchaeol, an isoprenoidal glycerol dial...
Genetic characterization of wild Dutch common carp (Cyprinus carpio L.)
Six male carp, caught in the water system surrounding the Anna Paulowna (AP) Polder in The Netherlands, were characterized using allozyme and microsatellite markers. At the sMDH-A1,2* loci an allele was found, which has previously only been found in wild River Rhine and wild Vietnamese common carp. ...
Heavy-metal pollution of the river Rhine and Meuse floodplains in the Netherlands
The embanked floodplains of the lower Rhine river in the Netherlands contain large amounts of heavy metals, which is a result of many years of deposition of contaminated overbank sediments. The metal pollution varies greatly between the various floodplain sections as well as in vertical direction wi...
This thesis examines sediment redox processes associated with organic matter degradation and their impact on the cycling of nutrients (N, P) and trace metals (Cd, Co, Ni, Pb, Zn). Our study site, Haringvliet Lake, is located in the Rhine-Meuse River Delta in the southwest of The Netherlands. This wa...
The Ponto-Caspian mysid Limnomysis benedeni was first recorded in Lake Constance in summer 2006, and a stable population developed at the site of discovery. Although this mysid is common in the Rhine and Danube rivers, little is known about its ecology and impact in systems of invasion. We investiga...
Oil and natural gas exploration in the Federal Republic of Germany in 1981
The primary target for oil and gas exploration in West Germany in 1981 was the Rotliegendes in northwest Germany and in the southern North Sea. The well-known targets in the Upper Rhine Valley and in the South German Molasse basin were further investigated with new wells. Four new gas discoveries were made in the Zechstein carbonates of Lower Saxony, one in the Rotliegendes of East-Friesland, and another in the Tertiary of the Upper Rhine Valley. Total footage drilled in 1981 was 853,359 ft., up 10% over 1980's level. Oil and gas reserves at year-end were, respectively, 67.75 million tons and 11.5 trillion CF, both only slightly down from the previous year despite production levels of 4.46 million tons and 708 TCF.
The dynamics of phyto-, bacterio-, proto- and metazooplankton were investigated for a period of 22 months fortnightly from March 1999 until December 2000 in the rivers Moselle, Saar and Rhine. Plankton abundances reached the lowest values in the Rhine and the highest in the Saar. Protozoa and not the much more studied metazoa clearly dominate the zooplankton not only by number but also by biomass by about 90%. We show that the plankton biomass in each of the rivers is the result of the interplay of the grazing by benthic predators and of the human induced factors such as river morphology, water residence time and nutrient load. Furthermore, we compare our study with the planktonic food web of three other large European rivers. The comparison between all studies revealed a general rise of t...
Reconstructing peak discharges of historic flood levels in urban areas
For historic settlement areas numerous flood level descriptions from times before the installation of river gauges are passed on, most of them are even dated. Typically, these written descriptions are qualitative such as "the water level peaked at 2 feet above the floor of the church" or "the water level topped the bridge before it failed". Furthermore, historic flood water levels are frequently marked at buildings and constructions. Such descriptions of flood water levels are used to determine periods of increased flood frequencies but are rarely transferred into palaeodischarge numbers due to methodological problems. One major problem is the estimation of the cross section area due to missing information on the topography and hydraulic roughness of the floodplain and the river channel in historic times. For the historic flood level records from the cities of Cologne (River Rhine) and Prague (River Vltava) an approach to estimate peak discharge is developed. Based on historic etchings, paintings and descriptions it is possible to reconstruct the characteristics of the river channel and floodplains to estimate cross-section areas during flood events. The reconstruction made use of all available data and estimations regarding channel incision as well as anthropogenic modification of the river and its floodplain. The mean flow velocity at the time of the historic flood events is estimated by the Manning-equation, based on the reconstructed river channel and floodplains. The slope of the water level is assumed to be comparable to recent values, while the estimation of the hydraulic roughness is a challenge as no studies on the hydraulic roughness of settled floodplains have been carried out so far. Sensitivity studies with different n-values within a reliable range of values are made to estimate the influence of this uncertainty. Finally, the reconstructed data are tested by estimating peak discharges of recent floods by the application of the described method and comparing the results with measured discharge data from the gauges located at Cologne and Prague. Herget, J. & H. Meurs (2009): Reconstructing peak discharges of historic flood levels in the citiy of Cologne, Germany. Global and Planetary Change (accepted)
Organic contaminants discharged to the aquatic environment exhibit a high diversity with respect to their molecular structures and the resulting physico-chemical properties. The chemical analysis of anthropogenic contamination in river systems is still an important feature, especially with respect to (i) the identification and structure elucidation of novel contaminants, (ii) to the characterisation of their environmental behaviour and (iii) to their risk for natural systems. A huge proportion of riverine contamination is caused by low-molecular weight organic compounds, like pesticides plasticizers, pharmaceuticals, personal care products, technical additives etc. Some of them, like PCB or PAH have already been investigated thoroughly and, consequently, their behaviour in aqueous systems is very well described. Although analyses on organic substances in river water traditionally focused on selected pollutants, in particular on common priority pollutants which are monitored routinely, the occurrence of further contaminants, e.g. pharmaceuticals, personal care products or chelating agents has received increasing attention within the last decade. Accompanied, screening analyses revealing an enormous diversity of low-molecular weight organic contaminants in waste water effluents and river water become more and more noticed. Since many of these substances have been rarely noticed so far, it will be an important task for the future to study their occurrence and fate in natural environments. Further on, it should be a main issue of environmental studies to provide a comprehensive view on the state of pollution of river water, in particular with respect to lipophilic low molecular weight organic contaminants. However, such non-target-screening analyses has been performed only rarely in the past. Hence, we applied extended non-target screening analyses on longitudinal sections of the rivers Rhine, Rur and Lippe (Germany) on the base of GC/MS analyses. The investigations revealed complex pattern of anthropogenic contaminants comprising a lot of still unnoticed pollutants (e.g. specific sulfones, trifluoromethyl substituted substances, nitrogen heterocycles etc.) or still unidentified compounds (such as selected brominated aromatics) of obviously high environmental relevance. In this presentation, a selection of several different contaminants will be discussed in detail comprising their emission sources, their emission behaviour, their fate within the river water bodies and in particular their structural properties. Generally. this investigation demonstrated the need to expand our analytical focus on a broader spectrum of organic contaminants, in particular to build up an adapted base for advanced monitoring studies.
The recombinant Salmonella typhimurium TA1535 strain carrying the SWITCH plasmid (combined construct of the SOS-Lux plasmid pPLS-1 and the LAC-Fluoro plasmid pGFPuv: pSWITCH) was treated with control substances for genotoxic (2-aminoanthracene) and cytotoxic (aureomycin) potency as well as with 18 environmental samples (groundwater, river water, sediments) provided at the SENSPOL Technical Meeting on Problems Related to Diffuse Pollution Sources (Characterization of Sediment, Dredged Material, and Groundwater) organized by the Federal Institute of Hydrology in Koblenz, Germany, during late October 2003. For metabolic activation the samples were treated with S9 mix (5% S9 fraction in cofactor mix, Aroclor 1254-induced rat liver microsomes, Moltox Inc., Mol, Belgium). Simultaneously determined cytotoxicity and genotoxicity data were derived through the Multilabel Counter 1420 Victor (PerkinElmer, Boston, MA, USA), by sequential measurement of luminescence, absorbance, and fluorescence. The newly designed SWITCH test, as it was applied at the Koblenz meeting, displays a comparable sensitivity for test samples with known cyto- and genotoxic potential. Groundwater samples from the wells at the former gas plant site Kiel Canal and the agricultural area at Niederwerth expressed neither genotoxic nor cytotoxic responses of the bacteria for both metabolic conditions (+/-S9). Spiked groundwater samples from the Niederwerth well BW1 and the Urmitz well U12 located on the river Rhine were identified to be positive in terms of genotoxicity for the direct and the metabolic approach. Samples from the lake Tiefer See in the city of Potsdam showed a reduction of GFPuv expression as an indication for cytotoxicity, while luminescence output of incubated bacteria remained unaffected. This reflects the well-known presence of contaminations (especially cyanides) in the lake sediment as well as in the acetonic extract. The results obtained at the SENSPOL Technical Meeting show the SWITCH test to be of major relevance not only for the analysis of chemicals under laboratory conditions but also for environmental samples polluted by diffuse industrial sources. PMID:15717775
Suspended particulate matter (SPM) sampled during a flood event in the year 2004 at the rivers Neckar and Rhine (Southwest Germany) was assessed for aryl hydrocarbon receptor (AhR)-mediated activities using EROD induction in the rainbow trout liver cell line RTL-W1. All EROD inductions were normalized to the positive control TCDD and given as bio-TEQ values. Since all samples indicated elevated AhR-mediated toxicities, an effect-directed analysis (EDA) was applied to identify substances causing the effects. In three primary fractions (F1 to F3) non-polar aliphatics, non-polar aromatic substances and more polar substances were separated. Fraction F2, co-eluting with non-polar polyaromatic substances (PACs) including polycyclic aromatic hydrocarbons (PAHs) gave highest AhR-agonistic effects and, thus, were sub-fractionated into seven secondary fractions (F2-1 to F2-7). Fraction F2-1, co-eluting with PCBs and PCDD/Fs, did not cause AhR-agonist activities. F2-2 to F2-4 containing PACs of less than 16 aromatic C-atoms produced minor activities. Highest inductions were detected with fraction F2-5 to F2-7, containing substances of more than 16 aromatic C-atoms (bio-TEQs up to approximately 4500 pg/g). Concentrations and relative potencies (REPs) of priority EPA-PAHs allowed the calculation of chemical toxicity equivalent concentrations (chem-TEQ values). Based on the chem-TEQs, EPA-PAHs explained between 5 and 58% of crude extract bio-TEQs from both rivers. Whereas fractions F2-1 to F2-4 indicated no biological activities, EPA-PAHs in fraction F2-5 to F2-7 accounted for 2 to 137% of AhR-related activities. PMID:20417549
The zebra mussel Dreissena polymorpha is widely used as sentinel organism for the assessment of environmental contamination in freshwater environments. However, in the River Rhine (Germany), the D. polymorpha population is declining, whereas the closely related quagga mussel D. bugensis is found in high numbers at some sites. In the present laboratory study, D. polymorpha and D. bugensis were exposed to resuspended native sediments for ?2 weeks. Wet sediments (Elbe in Dessau, a site known to be highly polluted with, e.g., organochlorine (OC) pesticides and (2) at a relatively unpolluted site in Havelberg in the River Havel, one of the Elbe's tributaries. Chemical analysis of persistent OC compounds (seven polychlorinated biphenyls [PCBs], DDT and its metabolites (DDX), hexachlorocylohexanes [HCHs], and hexachlorobenzene [HCB]) in soft tissue of mussels showed significantly greater values of PCBs 101, 118, 153, 138, 180, the sum of seven PCBs, and p,p'-DDD in D. bugensis compared with D. polymorpha. Fourteen days of exposure to Dessau sediment increased the concentration of p,p'-DDE and p,p'-DDD, as well as the sum of DDX, in both species compared with Havelberg sediment. Interspecific differences were less pronounced when regarding chemical concentrations with lipid content instead of dry-weight of tissue because D. bugensis had greater levels of total lipid than D. polymorpha. DNA damage in gills, as measured with the comet assay, was greater in D. bugensis compared with D. polymorpha. Simultaneously, the content of heat-shock protein (hsp70) in gills was greater in D. polymorpha than in D. bugensis. DNA damage and hsp70 were not induced by exposure time or sediment type. This study shows that D. bugensis and D. polymorpha may differ in their bioaccumulation potential of OC pesticides as well as their levels of DNA damage and hsp70. Therefore, more investigations are needed before quagga mussel can be used as alternative test organism for the zebra mussel. PMID:22231661
The worldwide decline of the eel population is thought to be caused by several factors, among which eel diseases. To investigate diseases of European silver eels Anguilla anguilla in the Netherlands, in Nov-Dec 2004 12 silver eels, and in Aug-Dec 2005 80 eels were caught in downstream parts (rivers) of the River Rhine and in Lake IJsselmeer. The eels were measured and weighed, necrotized, and individually checked for presence of external and internal parasites, bacterial infections and viruses, and blood smears were made for haematology. This is the first multidisciplinary study of the health of Dutch silver eels. In the small (2x6 eels) pilot study of 2004 in the River Rhine and Lake IJsselmeer respectively, most eels showed aspecific fin haemorrhages, some had ectoparasites, nearly none ...
Brominated flame retardants and dechloranes in eels from German Rivers
The levels of PBDEs, alternate BFRs and dechloranes in European Eel (Anguilla anguilla) samples (elvers, yellow and silver eels) were investigated to compare the contamination of eels from the rivers Elbe and Rhine and to estimate the BFR contamination throughout the eel's life cycle. PBDEs were the dominating flame retardants (FRs) in muscle tissues of yellow and silver eels, while the alternate BFR 2,3-dibromopropyl-2,4,6-tribromophenyl ether (DPTE) and the Dechlorane 602 were the dominating FRs in elvers (juvenile eels). Concentrations of FRs in silver eels from river Rhine were generally higher than concentrations in other eels analysed with up to 46ngg-1 wet weight (ww) PBDEs. The concentrations in yellow and silver eels from river Elbe were similar with an average of 9.0+-5.1ngg-1ww ...
Tree barks were used as biomonitors to evaluate past atmospheric pollution within and around the industrial zones of Strasbourg (France) and Kehl (Germany) in the Rhine Valley. The here estimated residence time for trace metals, PCBs and PCDD/Fs in tree bark is >10years. Thus, all pollution observed by tree bark biomonitoring can be older than 10years. The PCB baseline concentration (sum of seven PCB indicators (7PCBind)) determined on tree barks from a remote area in the Vosges mountains is 4ngg-1 and corresponds to 0.36x10-3ng toxic equivalent (TEQ) g-1 for the dioxin-like PCBs (DL-PCBs). The northern Rhine harbor suffered especially from steel plant, waste incinerator and thermal power plant emissions. The polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/Fs) concentrations analyz...
Organic matter processing in tidal estuaries
Processing of organic matter in tidal estuaries modifies its transfer from the river to the sea. We examined the distribution and the elemental and isotopic composition of organic matter in nine tidal estuaries along the Atlantic coast of Europe (Elbe, Ems, Thames, Rhine, Scheldt, Loire, Gironde, Douro and Sado). Short-residence time estuaries such as the Douro and Rhine estuaries have low suspended matter (SPM) contents with variable organic carbon (OC) concentrations, but rather uniform ?15N values and C/N ratios. Carbon isotope ratios vary from ?20 to ?22? in the marine end-member to ?26 to ?30? in the river end-member with conservative mixing in between. Tidal-dominated estuaries have high SPM contents, rather uniform OC contents and C/N ratios, and uniform and intermediate ?13C values...
While water quality strongly improved over decades in the Rhine River, sediments still reflect elapsed contaminations of organic pollutants and heavy metals. In comparing genotoxic effects induced by both sediment extracts and whole sediments, a ratio of bioavailable toxicity and total extractable toxicity is obtained. Since contaminated sites whose contaminants are toxic and as well bioavailable present an elevated risk to the ecosystem, such ratios may be used as a warning signal to identify sites of primary concern. Accordingly, two different exposure scenarios were compared to reveal the genotoxic potential of 18 sediment samples derived from 9 sample sites along the River Rhine. For assessment of effects on genome integrity, DNA fragmentation was measured using the comet assay with primary cells isolated from zebrafish embryos previously exposed to either organic sediment extracts or freeze-dried sediments at sublethal concentrations. Additionally, chemical data were used to determine responsible pollutants and correlate them with biological effects. (orig.)
The pore water transport of antimony and titanium, applied as nanoparticles (NPs), was studied by spiking stable suspensions of two different nanomaterials on the surface of an undisturbed floodplain soil. For preparation of stable dispersions, two different strategies were followed. (i) Comparable to those used in industrial applications: titanium dioxide nanoparticles, with an average diameter of 99 nm, were prepared by high-energy ball milling in water, whereas for (ii) antimony trioxide (Sb(2)O(3); average diameter 121 nm) a dispersing agent (sodium salt of poly[(naphthaleneformaldehyde)sulfonate] (pNFS) in water) was used. The upper 17 cm of a floodplain soil (river Rhine, Germany) was sampled using the minimally invasive sediment or fauna incubation experiment (SOFIE® two compartment cell; 3 l volume each), which preserved the pore system of the soil. The cells were equipped with 450 and 100 nm filter probes at different depths providing a non-invasive sampling of the pore water. The pore water was sampled at different times (T = 0, 24, 48, 96 and 196 h) and analysed by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS). Sb and Ti were transported via the pore water of the floodplain soil to a depth of 14 cm, corresponding to the maximum cell depth. The highest Sb concentration in the pore water was detected after 24 h at a depth of 5.5-8 cm. Although the spiked concentration was higher for Ti than for Sb, the total Ti concentration in the pore water of the spiked cell was lower. This indicates a stronger agglomeration of TiO(2) NPs or a more intensive interaction of Ti with the solid matrix and a faster transport of Sb towards deeper soil layers. The results show that metal(loid)s from metal oxide NPs are transported in the soil pore water and, hence, have the potential to act as the source of contamination of deeper soil layers after soil surface contamination. PMID:21403952
Within the frame of this project, a concept for setting up exemplary emission inventories for water was put forward. An overview is given of the international activities on emission inventories and the status of national emission inventories. Based on the data situation in Germany, it was necessary to include both plant-specific, aggregated and calculated data of the point sources in the inventories. Due to their increasing significance, diffuse material emissions into water were also taken into account. Based on the conceptual work, exemplary emission inventories were compiled for nitrogen, phosphorous and adsorbable organic combined halides (AOX) as well as the heavy metals arsenic, cadmium, chrome, copper, mercury, nickel, lead and zinc. These were evaluated according to the areas of origin (sectors) or the emission paths as well as according to the large river basins Danube, Rhine, Ems, Weser, Elbe, Oder, North Sea and Baltic Sea. In addition, lists of the ten largest industrial direct dischargers were compiled. (orig.) [German] Im Rahmen dieses Vorhabens wurde ein Konzept fuer die Erstellung von beispielhaften Emissionsinventaren fuer Gewaesser erarbeitet. Es wird ein Ueberblick ueber die internationalen Aktivitaeten zu Emissionsinventaren und den Stand beim Aufbau von nationalen Emissionsinventaren gegeben. Auf Grund der Datensituation in Deutschland war es erforderlich, dass sowohl anlagenspezifische als auch aggregierte sowie berechnete Daten der Punktquellen in die Inventare einbezogen wurden. Wegen ihrer zunehmenden Bedeutung werden die diffusen Stoffeintraege in die Gewaesser ebenfalls beruecksichtigt. Aufbauend auf den konzeptionellen Arbeiten wurden beispielhafte Emissionsinventare fuer Stickstoff, Phosphor und adsorbierbare organisch gebundene Halogene (AOX) sowie die Schwermetalle Arsen, Cadmium, Chrom, Kupfer, Quecksilber, Nickel, Blei und Zink zusammengestellt. Die Auswertung erfolgte sowohl nach den Herkunftsbereichen (Branchen) bzw. den Emissionspfaden als auch nach den grossen Flussgebieten Donau, Rhein, Ems, Weser, Elbe, Oder, Nordsee und Ostsee. Zusaetzlich wurden Listen der zehn groessten industriellen Direkteinleiter erstellt. (orig.)
Experts from Sulzer Infra have undertaken energy-saving measures in a number of buildings belonging to Hoffmann-La Roche, the pharmaceutical concern in Basle (Switzerland). The energy content of water from the river Rhine, which became heated during the cooling of installations, is now being put to good use. The concept for this was elaborated in close cooperation with the energy-saving office and the responsible planning engineer of Hoffroche. (author)
Dissolved copper, zinc and cadmium in the Southern Bight of the North Sea
Concentrations of dissolved copper, zinc and cadmium have been measured in the Dutch and Belgian coastal and offshore regions of the Southern Bight (North Sea), wih the aim to compare levels in the central, most saline part of the Bight with those in the coastal region that is under the influence of the rivers Rhine and Scheldt, as well as with those in open ocean surface waters.
Diversification of clonal complex 5 MRSA strains (Rhine-Hesse clone) within Germany.
Since 1995, a methicillin-resistant Staphylococcus aureus (MRSA) clone has spread in southern Germany. The strain was assigned to the Rhine-Hesse PFGE type by the staphylococcal reference center and was highly similar to epidemic clones known to belong to clonal complex 5 (CC5, USA100) based on multilocus sequence typing (MLST). Here we analysed a defined collection of strains assigned to the Rhine-Hesse/USA100 PFGE type. Using sequence-based typing methods (MLST, spa), the isolates were divided into two distinct clusters, ST5 and its single locus variant ST225. These two lineages are not distinguishable by PFGE or phage typing. Most of the ST5 isolates were derived from patients and volunteers from the Tübingen area in southwest Germany, whereas the ST225 isolates were mostly from other locations in Germany. The locally restricted ST5 isolates were shown to contain different SSCmec islands and exhibited different antibiotic resistance profiles. In contrast, the ST225 isolates form a highly homogenous group and are emerging all over Germany. The two lineages are clearly distinguishable by their phage content and spa type: ST5 strains from Tübingen are characterized by a Sa7int phage that carries the virulence gene sak, which codes for staphylokinase and ST225 isolates are characterized by a Sa1int phage. In conclusion, based on sequence typing and phage content CC5 strains can be subdivided into two distinct lineages with different epidemicity. PMID:23135939
In 1995, common tern (Sterna hirundo) eggs from the big German rivers, the Rhine, Weser and Elbe were collected to study the contamination with organochlorines and mercury. We found distinct differences between the rivers: Common tern eggs from the Rhine had higher concentrations of PCBs and HCHs, while eggs from the Elbe had higher residues of DDT, HCB and mercury. Also toxic PCB congeners had higher residue levels in the Rhine. Considering all organochlorines, samples from the Rhine also had the highest concentrations, while those from the Elbe were the lowest. With 5.7 anti {mu}gxg{sup -1} fresh weight, the {Sigma}PCBs had a level endangering breeding success. Fish eating birds should be used as indicators of the contamination of the rivers with environmental chemicals and should be included in monitoring programmes. (orig.) [Deutsch] 1995 wurden Eier der Flussseeschwalbe (Sterna hirundo) an Rhein, Weser und Elbe entnommen und auf Organohalogene und Quecksilber untersucht. Es gab deutliche Unterschiede zwischen den Fluessen: Die Eier der Flussseeschwalben waren am Rhein hoeher mit PCB und HCH kontaminiert, an der Elbe hoeher mit DDT, HCB und Quecksilber belastet. Auch die Konzentrationen toxischer PCB-Kongenere (Non-, Mono- und Di-ortho) waren am hoechsten in den Eiern vom Rhein. Bei Betrachtungen aller untersuchten Organohalogene enthielten Eier vom Rhein die meisten, von der Elbe die wenigsten Rueckstaende. Mit 5,7 anti {mu}g {Sigma}PCBxg{sup -1} Frischmasse erreichten die Eikonzentrationen am Rhein fuer den Bruterfolg kritische Werte. Eier fischfressender Voegel erweisen sich als geeignete Indikatoren der Belastung von Fluessen mit Umweltchemikalien und sollten in Monitoringprogramme aufgenommen werden. (orig.)
Lead isotope ratios were used to trace the origin of Pb in a soil-plant (Urtica dioica)-snail (Cepaea nemoralis) food chain in two polluted locations in the floodplains of the rivers Meuse and Rhine (Biesbosch National Park) and one reference location in the Netherlands. Lead isotope ratios and concentrations were determined in soil, litter, plant leaves, snails, rainwater and airborne particulate matter. Anthropogenic Pb in the soils of all locations was found to be derived from deposition of Pb polluted river sediments. Discharging rivers influenced the reference location before being reclaimed from the sea. The river sediment contains anthropogenic Pb from various sources related to industrial activities in the hinterland of the rivers Meuse and Rhine. Lead in the atmosphere contributed substantially to Pb pollution and Pb transfer in plant leaves and snails in all locations. Lead pollution in plant leaves and snails can be explained from a mixture of river sediment-Pb and atmospheric Pb from various transfer routes that involve low concentrations.
60th anniversary of Versuchsgrubengesellschaft
The Versuchsgrubengesellschaft was founded in 1927 for the purpose of carrying out scientific studies on the causes and prevention of accidents in coal mining. Today, the Versuchsgrubengesellschaft (financed since 1952 by the Federal Republic of Germany, the Land of North-Rhine Westphalia, and the Bergbau-Berufsgenossenschaft in equal shares) operates Tremonia test mine, whose equipment is unique in the world. A staff of 138 scientists, engineers, miners, technicians and craftsmen carry out investigations which help to improve the safety in mining and prevent hazards, e.g. from explosions, fires, faulty machinery, hazardous working materials, etc. (MOS).
Corrosion engineering aspects regarding MIC related failures on stainless steels
There are several chemical plants along the river Rhine that use river water as coolant in once through-systems. Microbially Influenced Corrosion (MIC) failures occur on stainless steel pipes and also in heat exchanger tubes coming in contact with this cooling water. This paper presents results of failure analysis of three case histories suspected to be caused by MIC. Afterwards several important corrosion engineering aspects are presented and discussed with respect to practical observations. Finally, a summary of the case histories and also some practical recommendations for MIC prevention in water handling units are given.
This study focuses on the feasibility of floodplain sediments and fluvial sediments in paleomeanders and ox-bows of two lowland rivers (River Havel, River Spree, Brandenburg State, Germany) as archives for quantitative paleolimnological reconstructions and potential basis of future river manageme...
Exploration of oil and natural gas in the Federal Republic of Germany in 1981
Target of oil and gas exploration in 1981 was predominantly the Rotliegendes in Northwest Germany and in the southern North Sea. The well known exploration targets in the Upper Rhine Valley and in the South German Molasse basin were further investigated with new wells. New gas discoveries (4 wells) however were made in the Zechstein Carbonates of Lower Saxony. Two further gas discoveries were made, one in the Rotliegendes of East-Friesland and the other in the Tertiary of the Upper Rhine Valley. Exploration for oil was successful in one well in East Holstein. The 1980 discoveries in North and South Germany were developed successfully by means of new pool tests and extension wells. In 1981 nearly 10% more meterage was drilled in relation to the preceding year. The oil reserves were estimated (31. Dec. 1981) as 67.75 million t in spite of an annual production of 4.46 million t. This is only 2.6 million t less than in the preceding year. The natural gas reserves on 309.4 x 10/sup 9/ m/sup 3/, also only about 6.3 x 10/sup 9/ m/sup 3/ less than in the preceding year, in spite of a production in 1981 of about 19 x 10/sup 9/ m/sup 3/.
Abstract Purpose To validate two established questionnaires [Morisky and Medication Adherence Report Scale (MARS-5)] for the measurement of medical adherence of patients treated with antihypertensive drugs in primary care in Germany. Setting General practitioners (GPs) and their patients in North Rhine-Westphalia, Germany. Methods GPs were asked to recruit 12 consecutive patients using blood-pressure-lowering medication for at least 12 months. Patients were asked to fill out both the Morisky and MARS-5 questionnaires. The medication possession ratio (MPR) was calculated as reference standard for patients' medication adherence by using GPs' electronic patient records. The results of the questionnaires were then compared with the reference standard. Results A total of 14 GPs recruited 163 pa...
129Iodine: a new tracer for surface water/groundwater interaction
We measured 129I/127I ratios in about 30 major rivers and found a strong signal of anthropogenic 129I in all of them (Moran et al., 1998). The effect of local point sources ,such as the Savannah River Facility and Hanford Facility are easily observed in the Savannah and Columbia Rivers, respectively. Likewise, the Rhine and Rhone rivers in Switzerland, have ratios well above ?background? due to their proximity to the main global source in northwest Europe. Away from local point sources, one observes a mixing trend between atmospherically-delivered 129I from European nuclear fuel reprocessing facilities, and low-ratio iodine derived from soil weathering (Moran et al., 1998). This anthropogenic 129I should be easily observable in soil water and shallow groundwater anywhere in the northern hemisphere.
Eutrophication, water management, and the functioning of dutch estuaries and coastal lagoons
A number of European rivers (especially the Rhine) have a prevailing influence on the nutrient cycling of most Dutch estuaries. Owing to the increased loading of the estuaries with nitrogen and phosphorous compounds, effects of eutrophication on the biological communities are most evident in the tidal Western Wadden Sea and in a nontidal brackish lagoon, Veerse Meer. Whether the relation between changed nutrient loadings and changed biomass and production of primary and secondary producers in the turbid tidal Dutch ecosystems should be considered as a causal relation is questionable. The very widespread practice of lagoon modification confuses the effects of nutrient loading. 29 refs., 7 figs., 2 tabs.
Genetic analysis of biodegradation of tetralin by a Sphingomonas strain
Tetralin (1,2,3,4-tetrahydronaphthalene) is produced for industrial purposes from naphthalene by catalytic hydrogenation or from anthracene by cracking. A strain designated TFA which very efficiently utilizes tetralin has been isolated from the Rhine river. The strain has been identified as Sphingomonas macrogoltabidus, based on 16S rDNA sequence similarity. Genetic analysis of tetralin biodegradation has been performed by insertion mutagenesis and by physical analysis and analysis of complementation between the mutants. The genes involved in tetralin utilization are clustered in a region of 9 kb, comprising at least five genes grouped in two divergently transcribed operons.
Because of their excellent properties as a biomonitor, yellow eels (Anguilla anguilla) have been used for time-trend monitoring of polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and tetrabrominated diphenylether (tetra-BDE). The program has now lasted for thirty years and has delivered valuable information on trends and spatial differences of these compounds in the delta of the rivers Rhine and Meuse and other Dutch canals, rivers and lakes. Specific local PCB, HCH and dieldrin contaminations were identified. Temporal trends show a slow decrease of PCB concentrations since 1977. Eels from the rivers Rhine and Meuse still exceed present European maximum residue limits for dioxin-like PCBs. Apart from some exceptions, OCP and tetra-BDE concentrations have also decreased, and more than those of PCBs. Fat contents of eel have decreased from an average of 21 to ca. 13%. This decrease in fat contents, coincides with the strong reduction of the European eel stock. - Results of thirty-year eel monitoring in The Netherlands reveal decreasing PCB and organochlorine pesticide concentrations, and the identification of specific local contaminations.
This paper describes an analysis of the observed up-river transport of fine sediments in the Ems River, Germany/Netherlands, using a 1DV POINT MODEL, accounting for turbulence-induced flocculation and sediment-induced buoyancy destruction. From this analysis, it is inferred that the net up-river tra...
The distribution and environmental state of vegetated islands within human-impacted European rivers
Summary 1.-Vegetated islands within river corridors are pivotal landscape features and are among the first to disappear as a consequence of flow regulation and channelisation. However, how vegetated islands vary along human-impacted rivers is poorly understood. 2.-We carried out a detailed analysis of the contemporary distribution, diversity and environmental state of vegetated islands within 12 human-impacted European rivers, using 75 Landsat 7 ETM+ satellite images (1999-2002), historical maps, DEM data and landscape metrics. We tested whether channel fragmentation, catchment land use and the environmental state of fringing floodplains determine the spatial patterns of the islands. We also analysed the historical change of islands within selected sections of the Upper Danube, Upper Rhine...
Chinese mitten crab (Eriocheir sinensis), a native species in China, has populated Continental Europe and North America since 1912. In this paper, the nucleotide variation in the fragments of mitochondrial COII (693?bp), Cytb (766?bp), and nucleotide ITS (706?bp) was analyzed in native (Yantgze, Yellow, and Liaohe Rivers in China) and colonized (Elbe, Rhine, and Thames Rivers in Europe, and San Francisco Bay in North America) populations of the Chinese mitten crab. The major findings are as follows. First, the genetic variability in the native populations is higher than that in the colonized European and North American populations, with the exception of the Elbe River population, which possesses a similar level of variability with the native populations. Second, a remarkable loss of single...
A survey of species belonging to the family Mysidae, conducted in June 2007 in fresh- to brackish waters of eastern France, revealed a recent range extension of the invasive Ponto-Caspian species Hemimysis anomala to the Moselle, Sa?ne, and Rh?ne rivers. In the estuary of the Grand Rh?ne it reached for the first time the Mediterranean coast. The network of navigation canals in NE France was likely a key element of its north to south pathway starting from the Rhine River. Important range extensions were also noted for Limnomysis benedeni in this network and in the Moselle River. The euryhaline species Neomysis integer, endemic in coastal waters of the NE Atlantic, was found in the Rh?ne delta, thus confirming previous very rare records in the 1930?1950s from the Mediterranean coast of Franc...
Different studies have shown that surface waters contain perfluorinated compounds (PFCs) in the low ng/L range. Surface waters are used to produce drinking water and PFCs have been shown to travel through the purification system and form a potential threat to human health. The specific physicochemical properties of PFCs cause them to be persistent and some of them to be bioaccumulative and toxic in the environment. This study investigates the evolvement of PFC concentrations in Rhine water and rainwater during dune water infiltration processes over a transect in the dune area of the western part of The Netherlands. The difference between infiltrated river water and rainwater in terms of PFC composition was investigated. Furthermore, isomer profiles were investigated. The compound perfluorobutanesulfonate (PFBS) was found at the highest concentrations of all PFCs investigated, up to 37 ng/L in infiltrated river water (71 ± 13% of ?PFCs). This is in contrast with the predominant occurrence of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) reported in literature. The concentrations of PFBS found in infiltrated river Rhine water were significantly higher than those in infiltrated rainwater. For perfluorohexanesulfonate (PFHxS) the opposite was found: infiltrated rainwater contained more than infiltrated river water. The concentrations of PFOA, perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA), PFBS, PFOS, and PFHxS in infiltrated river water showed an increasing trend with decreasing age of the water. The relative contribution of the branched PFOA and PFOS isomers to total concentrations of PFOA and PFOS showed a decreasing trend with decreasing age of the water. PMID:20831216
Background: Demographic change is a driving force of disease burden. The German population is aging and simultaneously shrinking, due to a rising life expectancy and a declining fertility rate. North Rhine-Westphalia (NRW) is the most populous federal state of Germany including the Ruhr metropolitan area. The NRW population is expected to shrink by 2.5% until 2025, the population of the Ruhr area by 9.5%. At the same time, the population forecast predicts a growth of 30% in the age group ?55 years for NRW. Methods: The `burden of disease' approach of the World Health Organisation (WHO) summarizes the health status of populations. This approach was used to predict the regional disease burden in 2025 by calculating disability adjusted life years (DALY) as the sum of life years lost due to...
The aim of the study was to identify the geogenic source for elevated arsenic (As) concentrations recently discovered in soils of the Heubach plain, North Rhine-Westphalia, Germany. Therefore, a catalogue of conditions that an As source has to fulfil in order to be considered as geogenic was formulated, including the source?s linkage to the sink, its mineralogy, As total content, As mobilization potential, groundwater redox conditions and As output. Accordingly, mineralogical, geo- and hydrochemical investigations were carried out, including X-ray diffractometry, microscopy, ICP-OES and AAS analysis and a sequential extraction procedure. Paleo bog iron ores (PBIOs) of Tertiary age, occurring within unconsolidated sands (Haltern-layers, Santonian?Lower Campanian), and glauconitic marlstones...
Bog Iron Ores and their Potential Role in Arsenic Dynamics: An Overview and a "Paleo Example"
Bog iron ores (BIOs), i.e. terrestrial accumulations of iron (Fe) minerals forming within the zone of groundwater oscillation, have been described in several regions in Germany and other countries. Since BIOs are composed of a variety of Fe minerals, primarily amorphous Fe hydroxides, they are likely to have an influence on the arsenic (As) dynamics of an area, as these minerals represent important natural As sources and sinks. In this study, mineralogical research results (XRD, microscopy) of altered BIOs of Tertiary age ("paleo" BIOs or PBIOs), occurring within Cretaceous sands in an area of North Rhine-Westphalia, are briefly presented. Genesis and mineralogical evolution of the categorized five different types of PBIOs, along with hydrogeochemical data from the literature, are discusse...
Near surface carbon dioxide within the urban area of Essen, Germany
The aim of this investigation was to determine the allocation between carbon dioxide concentrations, by mobile measurements at 1.5m a.g.l., within the urban canopy layer regarding different conditions: anticyclonic and cyclonic weather situations, on weekdays, at different times of the day and in different seasons. During winter 2002/2003 (December-February) and summer 2003 (June-August) 20 high frequency spatial and temporal mobile measurements of carbon dioxide were taken in the city of Essen (51degree 28primeN, 7degree 0primeE, North Rhine-Westphalia, Germany). The route of the taken measurements started in the southern part of the city and ended after 63km in the north of Essen, considering all different kinds of its land utilization. The contribution of motor vehicles to the carbon di...
Numerical Modeling of a Potential Geological CO 2 Sequestration Site at Minden (Germany)
We study opportunities for CO2 sequestration in geological formations of the state North Rhine Westphalia in Germany. Simulations are performed for evaluating a potential site within the Bunter sandstone formation near the town of Minden in a depth of around 3,000 m using the numerical simulator TOUGHREACT. Our focus is on three CO2 storage mechanisms: (1) hydrodynamic trapping, (2) dissolution trapping, and (3) mineral trapping. The results show that due to buoyancy the injected CO2 phase initially migrates towards the top of the reservoir and is hydrodynamically trapped beneath the confining layer of the cap rock. Then, the CO2 spreads laterally and dissolves partially in the formation water. The dissolution of CO2 results in an increase of the density of the brine causing a downward mig...
In 1975 in North Rhine-Westfalia, Federal Republic of Germany, according to the Federal Immission Control Act, five areas with high air pollution were determined. For these areas Clean Air Plans were drawn up. Clean Air Plans shall comprise a representation of emissions and immissions established for all or specific air pollutants, information about the impacts recorded for assets worthy of protection (human beings, animals and plants, water, the atmosphere etc.), any findings obtained as to the causes and effects of such air pollution, an assessment of any forthcoming changes in emission and immission conditions, details on immission levels and characteristic immission values and the measures envisaged for the reduction and prevention of air pollution. In accordance with these requirements epidemiological investigations of adults and children were performed in connection with the Clean Air Plans
Characteristics and therapy of premenopausal patients with early-onset breast cancer in Germany
Purpose The objective of the study is to investigate what kind of tumors young, premenopausal breast cancer patients in Germany show at diagnosis and how they are treated adjuvantly in comparison with a normally distributed cohort. Methods The study describes the data of 535 patients who were treated adjuvantly between 2002 and 2006 and participated in a resident mother???child program for rehabilitation (Groemitz cohort). The data includes TNM categories, biology of tumor and therapies. This population is being compared to an age-heterogeneous cohort from the state of Schleswig-Holstein and the DMP-report of the state of North Rhine-Westphalia. Results 45.8 % of the patients were diagnosed with tumor category pT1, 37 % pT2, 7.3 % pT3 and 1.9 % pT4. 5 % had merely DCIS. 48.8 % of the...
SummaryCurrent and future challenges of hydrologic sciences are to accurately predict and assess climate-driven impacts on water resources for the relevant scales of planning. However, process-based small-scale hydrologic modeling is data demanding and large uncertainties exist in data-sparse areas. The aim of our study was to test the applicability of the COSMO-DE analysis data (COSMO-DE-A) for hydrologic modeling. COSMO-DE-A data are a new meteorological data set with high temporal and spatial resolution that originates from the German Weather Service data assimilation system using the COSMO-DE weather prediction model. We collected field parameters in a small (10km2) mountainous catchment in the Upper Middle Rhine Valley (west Germany) to parameterize the static boundary conditions of t...
A two-band clear sky albedo model for a pine forest
A model based on the Dickinson/Sellers theory is developed for the annual variation of the shortwave clear sky albedo, applied to the specific case of a pine forest. The albedo calculation is carried out separately for two spectral bands: the photosynthetically active range (PAR) and the near-infrared (NIR) range. An incident radiation model is also developed, to treat direct and diffuse radiation in each band. The relative strengths of these components depend on atmospheric turbidity (also considered in two bands) which depends on water vapour pressure above the stand. With appropriate selection of parameter values, the model follows the long term averages measured at Hartheim, Germany (in the Upper Rhine valley) very well. An observed but unexpected average albedo increase in July was found to correlate closely with the water stress of the stand. (orig.).
Abstract A 7 year long data set of integrated high precision 14CO2 observations combined with occasional hourly 14CO2 flask data from the Heidelberg sampling site is presented. Heidelberg is located in the highly populated and industrialized upper Rhine valley in southwestern Germany. The 14CO2 data are used in combination with hourly carbon monoxide (CO) observations to estimate regional hourly fossil fuel CO2 ( FFCO2) mixing ratios. We investigate three different 14C calibration schemes to calculate FFCO2: (1) the long term median CO/ FFCO2 ratio of 14.6 ppb ppm 1 (mean: 15.5 5.6 ppb ppm 1), (2) individual (2 )week long integrated CO/ FFCO2 ratios, which take into account the large week to week variability of 5.6 ppb ppm 1 (1 ; interquartile range: 5.5 ppb ppm 1), and (3) a calibration w...
The aim of this study was to evaluate exposure and health outcome of children living close to industrial sources. Exposure and health outcome was assessed in nearly 1000 children at school beginner age living in the vicinity of industrial sources of three different hot spots (Duisburg North, Duisburg South and Dortmund Horde) and in a rural area of North Rhine Westphalia (NRW), Germany. The cross-sectional study was undertaken between March and May 2000. Exposure assessment comprised modelling of ambient air quality data and human biomonitoring (HBM). Depending on the site-specific contaminants, HBM included the measurement of PAH (polycyclic aromatic hydrocarbons) and benzene metabolites in urine as well as heavy metals in blood and urine. Markers of early effects were DNA strand breaks a...
The effect of free primary school choice on ethnic groups - Evidence from a policy reform
In 2008, school catchment areas were abolished in North Rhine-Westphalia (NRW), the most populous German federal state. Critics have argued that free school choice will lead to increased segregation and educational disparities. The data used is from Wuppertal, a major city in NRW. Since the Turkish population is the largest minority in Germany, but also one of the least integrated, the focus of this paper is on the effect of the new school law on the school choice of Turkish (Muslim) versus non-Turkish (non-Muslim) families. Free school choice has led, in fact, to increased choice on the part of both advantaged and (to a lesser extent) disadvantaged families. Motives behind choice include proximity and the academic quality of the school. The effect of this increased choice on segregation i...
Integration of spatial analyses into LCA?calculating GHG emissions with geoinformation systems
Purpose Spatial analyses in life cycle assessments are hardly ever conducted. The combination of geoinformation systems and life cycle assessments (LCA) databases is a way to realise such complex calculations. By the example of energetic utilisation of biomass via conditioned biogas a geoinformation systems-based calculation tool is presented which combines geodata on biomass potentials, infrastructure, land use, cost and technology databases with analysis tools for the planning of biogas plants to identify the most efficient plant locations, to calculate balances of emissions, biomass streams and costs. Methods The calculations include the impact categories greenhouse gases, acidification, and eutrophication and were tested for the Lower Rhine region and the Altmark region in Germany. The...
Outbreak of bluetongue disease (BTD) in Germany and the danger for Europe
In August 2006, the blue tongue virus (BTV-type South Africa serotype 8) was detected for the first time in cattle blood probes in the Netherlands, immediately followed by cases in Belgium and in cattle on German farms, which were situated close to Aachen at the border to those countries. Within less than 2?months the disease spread eastwards crossing the Rhine, southwards to Luxemburg and to Northern France. At the end of the year 2006, nearly 1,000 farms were affected in Germany. Catches on two German cattle farms proved that the ceratopogonid species Culicoides obsoletus was obviously the vector, since many females?fed and unfed ones?were found to be infected with this virus. This sudden outbreak of bluetongue disease (BTD) is surely not a primary result of global warming, but rather an...
Summary The deep structure of the Upper Rhine Graben (URG), a continental rift in SW Germany and E France, is still poorly known. This deficit impedes a full understanding of the geodynamic evolution of this prominent rift. We study the lithosphere-asthenosphere structure using teleseismic waveforms obtained from the passive broad-band TIMO project across the central URG. The recovered, crust-corrected traveltime residuals relative to the iasp91 earth model are tiny (mostly less than 0.2-0.3 s). The average measured slowness (<1 s deg-1) and backazimuth (<5) deviations are also very small and do not show any systematic wave front anomalies. These observed perturbation values are smaller than expected ones from synthetic 3-D ray tracing modelling with anomalies exceeding 2-3 per cent seismi...
In sandy grassland vegetation of Central Europe, extensive grazing is often a management tool to maintain and improve nature conservation value. As part of a long-term field experiment lasting 10 years we investigated the effects of sheep grazing as a type of moderate disturbance. As ''experiments by nature'' happened in this time period we were also able to study severe biotic (rabbit grazing) and abiotic (drought) disturbances, examining the recovery and resilience of the system after these severe disturbances. Within a six-fold replicated randomised split-plot design, 25-m^2 plots of Armerio-Festucetum trachyphyllae vegetation were studied from 2000 to 2009 in the northern upper Rhine valley (Germany). We analysed sheep-grazed and non-grazed plots (both with very low rabbit impact until...
Atmospheric pollen dynamics in M?nster, north-western Germany: a three-year study (2004?2006)
An aeropalynological study was carried out in the atmosphere of M?nster, the largest city in the region of North Rhine-Westphalia (north-western Germany), based on the data obtained during a 3 year of air-monitoring study (2004?2006) using a Hirst-type volumetric pollen trap. During the studied period, a total of 34 pollen types were identified in the atmosphere of the city, 20 corresponding to woody taxa and 14 to herbaceous taxa. The mean annual pollen index was 34,737, although there were important fluctuations from year to year. March to August was the period when more than 95% of the annual total was collected. The 10?most abundant pollen types detected were Betula, Urticaceae, Taxus/Cupressaceae, Quercus, Alnus, Poaceae, Pinus, Fraxinus, Platanus and Fagus, in order of abundance, whi...
For the entire Upper Rhine Valley between Karlsruhe and Basel, a long term simulation (1985-2002) with the GWN_BW model (partly physically based 1-D water balance model) resulted in the retrieval of the following hydrological process variables: daily potential and actual evaporation, surface runoff from sealed surfaces and groundwater recharge. Meteorological data has been interpolated from all available stations in France, Germany and Switzerland including the mountainous regions of the Vosges Mountains and the Black Forest. The primary grid size of the model was 500m; for landuse, the sub-grid variability has been taken into account additionally. In an alternative approach, Landsat-5 TM scenes from two different acquisition dates were integrated to model the daily rates of actual evapora...
In this article, we compared the resistance of two introduced populations of Elodea nuttallii and Elodea canadensis to two different herbivores. Samples were collected from the River Rhine and River Rh?ne in eastern France. The two populations of E. nuttallii differed in their introduction history, whereas E. canadensis was introduced at the same time in the two sites. The Daily Food Consumption (DFC) rates of the two macrophyte populations were evaluated in no-choice experiments using the scraper Lymnaea stagnalis and the shredder Gammarus roeseli. At the same time, we assessed four plant traits: dry matter content (DMC), total nitrogen content, carbon/nitrogen ratio and total phenolic content. The two populations of E. canadensis were consumed at low levels by both the herbivores. L. sta...
Accurate water level prediction for the design discharge of large rivers is of main importance for the flood safety of large embanked areas in The Netherlands. Within a larger framework of uncertainty assessment, this report focusses on the effect of uncertainty in roughness parameterization in a 2D hydrodynamic model. Two key elements are considered in this roughness parameterization. Firstly the manually classified ecotope map that provides base data for roughness classes, and secondly the lookup table that translates roughness classes to vegetation structural characteristics. The aim is to quantify the effects of these two error sources on the following hydrodynamic aspects: 1. the discharge distribution at the bifurcation points within the river Rhine 2. peak water levels at a stationary discharge of 16000 m3/s. To assess the effect of the first error source, new realisations of ecotope maps were made based on the current ecotope map and an error matrix of the classification. Using these realisations of the ecotope maps, twelve succesfull model runs were carried out of the Rhine distributaries at design discharge. The classification error leads to a standard deviation of the water levels per river kilometer of 0.08, 0.05 and 0.10 m for Upper Rhine- Waal, Pannerdensch Kanaal-Nederrijn-Lek and the IJssel river respectively. The range is maximum range in water levels is 0.40, 0.40 and 0.57 m for these river sections respectively. Largest effects are found in the IJssel river and the Pannerdensch Kanaal. For the second error source, the accuracy of the values in the lookup table, a compilation was made of 445 field measurements of vegetation structure was carried out. For each of the vegetation types, the minimum, 25-percentile, median, 75-percentile and maximum for vegetation height and density were computed. These five values were subsequently put in the lookup table that was used for the hydrodynamic model. The interquartile range in vegetation height and density in the lookup table led to a difference in water levels of 0.20, 0.20, and 0.36 m for Upper Rhine- Waal, Pannerdensch Kanaal-Nederrijn-Lek and the IJssel river respectively. The discharge distribution at the Pannerdensche Kop bifurcation point is 165 m3/s for both error sources, classification and lookup table. The discharge distribution at the IJsselkop is more sensitive for classification error than for errors in the lookup table (160 vs. 70 m3/s for range in classification error and interquartile range in lookup table error). Priority should be given to increasing the classification accuracy as this generates the largest error for water levels as well as discharge distribution. The quantification of the uncertainty in water levels and discharge distribution will help to make decisions more realistically as the error bands are substantiated. It can also influence the assessment of the height of the embankments as insight is given in the variability of the outcome of the flow models at design discharge. Moreover, the error bands may serve as an incentive to quantify the desired accuracy in the vegetation structural characteristics. This means that an upper limit can be put on the variation in water levels that is accepted from errors in the roughness parameterization.
Riverine discharge of perfluorinated carboxylates from the European continent.
The discharge of C6-C9 perfluorinated carboxylates (PFCAs) from major European rivers was studied and employed to assess European emissions of these compounds. Water samples were collected close to the mouths of 14 major rivers including the Rhine, Danube, Elbe, Oder, Seine, Loire, and Po. PFCA concentrations were determined using LC-MS/MS and used together with the mean annual water flow to estimate the riverine discharge of the PFCAs. The highest concentration measured was 200 ng/L for perfluorooctanoate (PFOA) in the Po River. The Po accounted for two-thirds of the total PFOA discharge of all the rivers studied, suggesting a major industrial source of PFOA in the Po watershed. All other nonremote rivers showed PFOA concentrations in the lower ng/L range, which indicates that widely distributed sources are also significant contributors to PFOA emissions in Europe. The total discharge of PFOA from the European rivers was estimated to be 14 tonnes/year, which is in reasonable agreement with reported emissions estimates. However, the total riverine discharge of perfluorohexanoate (PFHxA) of 2.8 tonnes/year estimated in this study was three times greater than the reported global emissions estimate, suggesting that there are significant, as yet unidentified sources of this compound. PMID:18044497
Macrobenthic assemblages of the lower, regulated and canalized Marne River (France) are dominated by several "exotic", recently introduced species. Arrival, installation and spread of such alien species were certainly promoted by (1) the close connection between French and other European river systems (Rhine, Danube), (2) the modification of natural river flow and benthic habitats. Both habitat characteristics (e.g. granulometric composition, organic content) and corresponding benthic assemblage structure were analysed to identify the substrate affinity of major taxa in the lower Marne River. The main aim of the study was to evaluate the possible biotic interactions (i.e. competition for food and/or space) among dominant taxa as function of habitat features and to predict the future development of newly established species, already known as potential invaders: Corbicula fluminea (Bivalvia), Hypania invalida (Polychaeta), Chelicorophium curvispinum (Amphipoda), etc. Most of the newly established species, coming from the same biogeographical area ("invasional meltdown" hypothesis?), are eurytopic, with high fecundity and large food spectrum. First results demonstrated the co-existence of such species in the Marne River. But the future ecological importance of these organisms in benthic assemblages of the river depends on their present population size, population dynamics, and ability to colonize bottom substrates.
This annual report is a data compilation on the water quality of the river Elbe in Germany. You can find here data on the ph value, oxygen content, water temperature, concentration of heavy metals, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons of several locations at the river Elbe. (SR)
Identification of Anopheles daciae in Germany through ITS2 sequencing.
Until the middle of the twentieth century, malaria was frequently endemic in parts of Germany; Anopheles maculipennis complex species were considered the primary vectors. Three species of this complex have been identified in Germany: A. maculipennis s.s., Anopheles messeae and Anopheles atroparvus; the last predominantly from the coastal regions of Northern Germany. Anopheles daciae is a recently described member of the A . maculipennis complex and resembles the well-characterised species A. messeae, although the two species can be distinguished through their egg morphology and sequencing of the internal transcribed spacer 2 (ITS2) region of their nuclear rDNA. In this study, we harvested larval and adult mosquito samples from five breeding sites and ten CO(2) trap collection sites in the Upper Rhine Valley of Southwestern Germany to analyse the complement of anopheline species present. Mosquito ITS2 DNA was extracted and polymerase chain reaction (PCR)-amplified using established protocols. Genomic analysis was performed by a species-diagnostic restriction fragment length polymorphism assay as well as by sequencing of PCR products; the data obtained were aligned against nucleic acid sequences from English mosquitoes retrieved from GenBank. Additionally, the larval breeding sites of A. messeae were characterised through water quality measurement. Forty-seven samples were successfully processed, of which 6 were identified as A. daciae and 41 as A. messeae. All samples of A. daciae, which has not previously been found in Central Europe, originated from one CO(2) trap collection site in Dettenheim, close to Karlsruhe, Southwestern Germany. The identification of this malarial vector in a novel area may have implications for the re-emergence of disease subsequent to climatic changes. PMID:23001548
Hydromorphological restoration of running waters: effects on benthic invertebrate assemblages
Summary 1.-River restoration has received considerable attention, with much recent focus on restoring river hydromorphology to improve impoverished aquatic communities. However, we still lack a clear understanding of the response of aquatic biota to river restoration. 2.-We studied the effects of hydromorphological restoration on benthic invertebrate assemblages in 25 river sites in Germany using standardised methods. Restoration efforts were primarily aimed to restore habitat heterogeneity; correspondingly, habitat diversity increased at most sites. 3.-Similarity of benthic invertebrate assemblages between restored and unrestored river sections was low (mean similarity was 0.32 for Jaccard and 0.46 for Srensen). Community-based metrics, such as the percentage of Ephemeroptera, Plecoptera ...
Phylogeography and postglacial dispersion of the chub (Leuciscus cephalus) in Europe.
A phylogeographic analysis of mitochondrial DNA variation was performed in order to test the hypothesis of a postglacial recolonization of mid- and north-European rivers from a Danubian refuge. Over 345 chub specimens from European rivers covering most of the species' native range were investigated using 600 bp of the cytochrome b gene. Chub in European rivers belong to four highly divergent mitochondrial groups (lineages) differing by mean divergence estimates from 5.2% to 7.89%. These four lineages have a largely allopatric distribution, implying four geographical sets: two Mediterranean, and two north-European sets. This pattern provided strong evidence for: (i) the eradication of this species from most of Europe during maximum ice extent; (ii) its survival in four refugia (Adriatic side of the Balkans, eastern Greece (Aegean Rivers), southern tributaries of the Danube, and periphery of Black and Caspian Seas); (iii) a differential postglacial recolonization of mid- and northern Europe from the last two refugia only; (iv) the occurrence of this recolonization in two steps for the Danubian (western) lineage that entered western Europe (Rhine-Rhone-Loire drainages) during the Riss-Würm interglacial period and survived the last glaciation there before colonizing Garonne, UK and German drainages up to the Elbe during the Holocene; and (v) the occurrence of this recolonization in a single step for the Ponto-Caspian (eastern) lineage that entered the Baltic area as far as the Oder in the Holocene. Both lineages came into contact in the River Elbe without evident mixing. PMID:10434419
Molecular confirmation of the occurrence in Germany of Anopheles daciae (Diptera, Culicidae).
ABSTRACT: BACKGROUND: Anopheles daciae, a newly described member of the Maculipennis group, was recently reported from western, southern and eastern Europe. Before its recognition, it had commonly been listed under the name of An. messeae, due to its extreme morphological and genetic similarities. As the sibling species of the Maculipennis group are known to differ in their vector competences for malaria parasites and other pathogens, the occurrence of An. daciae in a given region might have an impact on the epidemiology of mosquito-borne diseases. Mosquito collections from different localities in Germany were therefore screened for An. daciae. METHODS: Adult and immature Maculipennis group mosquitoes were collected between May 2011 and June 2012 at 23 different sites in eight federal states of Germany. A standard PCR assay was used to differentiate the previously known sibling species while the ITS2 rDNA of specimens preliminarily identified as An. messeae/daciae was sequenced and analysed for species-specific nucleotide differences. RESULTS: Four hundred and seventy-seven Anopheles specimens were successively identified to Maculipennis group level by morphology and to species level by DNA-based methods. Four species of the Maculipennis group were registered: An. messeae (n = 384), An. maculipennis (n = 82), An. daciae (n = 10) and An. atroparvus (n = 1). Anopheles daciae occurred at four sites in three federal states of Germany, three of the sites being located in north-eastern Germany (federal states of Brandenburg and Saxony) while one collection site was situated in the northern Upper Rhine Valley in the federal state of Hesse, south-western Germany. CONCLUSIONS: The detection of An. daciae represents the first recognition of this species in Germany where it was found to occur in sympatry with An. messeae and An. maculipennis. As the collection sites were in both north-eastern and south-western parts of Germany, the species is probably even more widely distributed in Germany than demonstrated, albeit apparently with low population densities. Research is needed that confirms the species status of An. daciae and elucidates its vector competence as compared to An. messeae and the other species of the Maculipennis group, in order to optimize management of possible future outbreaks of diseases caused by pathogen transmission through Maculipennis group mosquitoes. PMID:23146352
ABSTRACT. We discovered a free-living peritrich ciliate with outstanding features in the River Rhine. Its morphology and 18S rRNA gene sequence were studied with standard methods. Apocarchesium arndti n. sp. has several peculiarities. (i) There are ordinary zooids, macrozooids, and microzooids, which form a hemispherical rosette on a discoidal base, the stalk dish, locking the 18 mm wide and up to 2 mm long, spirally contracting colony stalk. (ii) The stalk myoneme is connected only to the microzooids. (iii) A rosette contains up to 50 zooids not connected to each other but individually attached to the stalk dish with the scopula. (iv) The ordinary zooids are epistylidid, trumpet-shaped (6:1 length:width), about 180 x 30 mm in size, and have an ellipsoidal macronucleus subapically between ...
This paper (re)considers the question if chronic and diffuse heavy metal pollution (cadmium, copper, lead and zinc) affects the structure and functioning of terrestrial ecosystems of Biesbosch National Park, the floodplain area of rivers Meuse and Rhine. To reach this aim, we integrated the results of three projects on: 1. the origin, transfer and effects of heavy metals in a soil?plant?snail food chain; 2. the impact of bioavailability on effects of heavy metals on the structure and functioning of detritivorous communities; 3. the risk assessment of heavy metals for an herbivorous and a carnivorous small mammal food chain. Metal pollution levels of the Biesbosch floodplain soils are high. The bioavailability of metals in the soils is low, causing low metal levels in plant leaves. Despite ...
Phthalates in surface water - a method for routine trace level analysis
A routine method for the determination of phthalates in water is presented. It is suitable for all kinds of water like surface water, waste water, landfill leachate, rain water and ground water. Unfiltered water samples including all suspended particulate matter are extracted by solid-phase extraction in an all-glass apparatus using RPC-18. The extracts are measured by GC/MSD in the SIM mode. Due to an easy but efficient decontamination technique, method blanks could be decreased below 0.02 [mu]g/l for all phthalates. The detection limits are 0.01 to 0.02 [mu]g/l, the determination limits are 0.02 to 0.05 [mu]g/l. Recovery for all phthalates is about 98% ([+-] 5%). Phthalates were measured in about 400 samples of water of the river Rhine and its main affluents in Northrhine-Westfalia. (orig.)
The onset of downstream migration of European eels is accompanied by a cessation of feeding and the start of sexual maturation which stresses the link between metabolism and sexual maturation, also suggesting an important role for exercise. Exercise has been tested with eels in swim tunnels and was found to stimulate the onset of sexual maturation. In this study, we have investigated the interplay between migration and maturation in the field during the downstream migration of female silver eels. Temporal changes in migratory status and sexual maturation among silver eels of the upstream Rhine River system over 3?months of the migration season (August, September and October) were determined in biometrical parameters, plasma 17?-estradiol and calcium levels, oocyte histology and gonadal fat...
This paper presents a dendrochronological study of Common Ivy in alluvial environment. Our objective was to analyse the response of ivy plants to hydrological and climatic variations. The study was carried out in three forests: Rhinau, which is regularly flooded; Erstein, where floods were eliminated with the canalization of the Rhine River in 1967 and Heiteren, an upland forest. Multivariate models performed for each forest showed that the response of ivy to temperature, precipitation and water table level depended on the hydrological history of the site. In the flooded forest of Rhinau, ground water depth in June and July, that is at the time when floods usually occur, was one of the main factors stimulating growth while in Erstein, rises of the ground water levels stimulated growth only...
Magmatism in the Cenozoic Central European Volcanic Province (CEVP) has been related to two geodynamic scenarios, either extensional tectonics in the north Alpine realm or upwelling of deep mantle material. The Oligocene (30-19 Ma) Siebengebirge Volcanic Field (SVF) is a major part of the German portion of the CEVP and consists of erosional remnants of mafic to felsic volcanic edifices. It covers an area of 35 km (NW-SE) by 25 km (SW-NE) with eruptive centres concentrated near the eastern shore of the Rhine river in the vicinity of the city of Bonn. Mafic rocks in the SVF comprise strongly SiO2-undersaturated basanites to alkaline basalts. Occurrences of alkaline basalts are confined to an inner NW-SE-striking zone, whereas the more SiO2-undersaturated basanites dominate the western and ea...
Within the 13th convention of EnergieAgentur.NRW (Duesseldorf, Federal Republic of Germany) at 10th February, 2009, in Essen (Federal Republic of Germany), the following lectures were held: (1) Future energies from North Rhine Westphalia (C. Thoben); (2) Climate change USA? American energy policy under president Barack Obama (A. Best); (3) Regenerative energy industry NRW Environment - Economy - Research (N. Allnoch); (4) Actual trends in the power plant technology (M. Neubronner); (5) Innovations and requirements at future electrical grids (C. Rehtanz); (6) Utilization of biomass in NRW (E. Uhlenberg); (7) CCS - Review of the state of the art (D. Goldschmidt); (8) CCS - EU boundary conditions (H. Bergmann); (9) CCS - Public acceptance in Germany (M. Donnermeyer); (10) CCS in Norway (A.M. Blaker); (11) Climatic protection by means of CCS - The point of view of a NRO in Norway (E. Hoff); (12) The NRW geotechnical research unit - A central laboratory for geothermal collaborative research for science and economy (R. Bracke); (13) Analysis of the value chain geothermal power in the metropolis Ruhr (B. Bruckhoff); (14) The geothermal drillings of SGG in the Bavarian Molasse basin (R. Baur); (15) Actual projects in the area of geothermal power at Stadwerke Bochum GmbH (F. Peper); (16) Geothermal projects of Evonik New Energies GmbH (A. Kany); (17) Geothermal projects of Daldrup and Soehne AG (A. Toenies); (18) Bio energy as a perspective for municipalities: Profitability, supply security and self supply of municipal real estates (U. Kreienmeier); (19) Public utilities as a partner in times of energetic change (F. Broesse); (20) Best practice bio energy: Technical transfer and financing (H. Jordan); (21) Bio energy registers for a sustainable development in European regions: Significance of regional bio energy grids as an active business development (G. Fritsch); (22) Industrial wastelands as an area perspective for cultivation of biomass: Perspectives for North Rhine Westfalia and innovative project approach using the biomass park Zeche Hugo as an example (R. Krumm); (23) Requirements, objectives from the practice according to the storage of electric power (J.-W. Biermann); (24) State of the art and future of lithium ion batteries as a stationary and mobile energy storage (G. Hoerpel); (25) Requirements, objectives from the practice according to hydrogen storage (B. Horbein); (26) Review on research and development activities in North Rhine Westfalia (M. Krupp); (27) Requirements, objectives from the practice according to thermal storage (C. Sattler); (28) Configuration of the research wind power in Germany - Results of a BMU study from 2008 (N. Allnoch); (29) Competency Centre wind power technology (V. Kaci); (30) Significance of test fields in the wind power (M. Kraemer); (31) Demand on research and testing from industrial view (A. Klein Hitpass); (32) Research projects in plant construction and machine construction: Gears (W. Predki); (33) Research projects in plant construction and machine construction: Simulation of dynamic loads of the powertrain of WEA (G. Jacobs).
In order to determine the origin and the propagation mechanisms of highly concentrated chloride brines within the Quaternary aquifer system in the southern part of the Upper Rhine Graben, a combined isotope (H, O, C) and hydrochemical analysis was carried out. Groundwater recharge in this area is a complex system, consisting of local precipitation, river bank filtration, lateral flow from the Graben borders and, to a minor extent, an old Pleistocene component. In some areas, groundwater consists of up to 90% of recent bank filtrate, reaching depths down to at least 100 m. The isotopic and hydrochemical results show, that the elevated chloride concentrations in the Quaternary aquifer mainly result from leaky settling basins charged by the French potash mines until the mid 1970s. Input of natural brines coming from tertiary salt diapirs is of only minor importance. While infiltrating, the anthropogenic brines were strongly diluted by local river bank filtrate of the Rhine. Nevertheless, maximum chloride concentrations nowadays still reach some 10,000 mg/l at the base of the aquifer at a depth of more than 100 m below surface. The main volume of the brines is stored in the less permeable lower part of the quaternary sediments (Breisgau-Formation) whereas only a minor part is transported northwards with the rapid convective groundwater flow. Brines undergoing only dilution preserve their hydrochemical characteristics (NaCl-type). In contrast, brines recirculated from the Breisgau-Formation show a northwards increasing alteration through ion exchange processes. Potassium and sodium may be fixed in the fine grained aquifer material while calcium is set free into the groundwater. After a flow distance of about 12 km, complex hydraulic interactions between groundwater and surface waters lead to the rise of strongly diluted and hydrochemically altered brines with chloride contents up to maximum 700 mg/l. The presented case study is an example for a detailed analysis of a multi-component groundwater mixing system using combined isotope and hydrochemical methods. Furthermore, cation exchange is shown as a major process affecting the hydrochemical evolution of the young groundwater in the southern Upper Rhine Graben which is locally strongly polluted by chloride as a consequence of former potash mining.
A total of 121 European eels (Anguilla anguilla) from 2 sampling sites on the River Rhine were investigated in respect of their parasite communities. Special attention was given to the swim bladders, intestines, gills and fins of the fish. Twelve different parasite species were found to live in and on the eels. Data from each sampling site were kept separate. Parasites found in descending order of prevalence were: Anguillicola crassus, Trypanosoma granulosum, Myxobolus sp., Paratenuisentis ambiguus, Pseudodactylogyrus sp., Bothriocephalus claviceps, Myxidium giardi, Pomphorhynchus laevis, Trichodina sp., Raphidascaris acus, Acanthocephalus lucii and Acanthocephalus anguillae. Significantly different prevalences were reported for L3 larvae of A. crassus, adult P. ambiguus, B. claviceps and Myxobolus sp. at the 2 sampling sites. The highest number of parasite species was recorded from the intestine, which contained up to 6 different helminths. The coexistence of the acanthocephalans P. laevis and P. ambiguus, which showed clear patterns of distribution within the intestine of the respective hosts, was reported for the first time. Up to 3 different helminth species were found in the intestine of individual fish. Among those, acanthocephalans were the most prevalent worms with the eel-specific parasite P. ambiguus as the dominant species not only of the intestinal but also of the total component communities. Both infra and component communities exhibited low diversity and were dominated by this single species. The evenness reached only approximately 50% or less and it remained unclear why the helminth communities of the eels from the River Rhine with its huge catchment area exhibit such a low parasite diversity and high dominance. PMID:10503258
This report ''development of runoff in subcatchments of the River Rhine - simulations of the current state and for climate change scenarios'' investigates the impacts of possible future climate changes on runoff and runoff regime in selected subcatchments of the River Rhine. The regional climate in the selected subcatchments Mosel (up to gauge Cochem), Sieg (gauge Menden 1) and Main (gauge Kemmern) is affected by the middle mountain ranges. In a first step, important model processes are parameterized according to catchment characteristics. A representation of the regional hydrology is then produced by using the hydrological model HBV-D. Based on time series of daily measurements (temperature, precipitation) at stations within the catchment, this representation can be used to realistically simulate time series of runoff and discharge. In all examined areas, the quality of simulations of the calibration and validation periods for the current state (standard period of measurements 01/01/1961-12/31/1999) can be regarded as good to excellent. To aid the catchment-specific, extensive and time-consuming data processing, a working environment for the hydrological model HBV-D has been developed. In a second step, the current states of areal precipitation, areal temperature and simulated mean discharge (MQ) are compared to the corresponding states for two scenarios of future climate changes (100 years later, 2061-2099). These scenarios are based on simulated global circulations of one model run for each of two global circulation models (GCM). These global circulations are regionalized (downscaled) using a statistical approach into scenario time series of daily values (temperature, precipitation - input for the hydrological model) at control stations within the individual catchments. (orig.)
Sediments are increasingly recognized as both a carrier and a possible source of contaminants in aquatic systems. Since the early part of the century, limnological research on eutrophication problems and acidification indicated that particle-interactions can affect aquatic ecosystems. In contrast to the eutrophication and acidification problems, research on toxic chemicals has included sediment aspects from its beginning. In the lecture notes, following the description of priority pollutants related to sedimentary phases, four aspects were covered, which in an overlapping succession also reflect the development of knowledge in particle-associated pollutants during the past 25 years: the identification, surveillance, monitoring and control of sources and distribution of pollutants; the evaluation of solid/solution relations of contaminants in surface waters; the study of in-situ processes and mechanisms in pollutant transfer in various compartments of the aquatic ecosystems and, the assessment of the environmental impact of particle-bound contaminants. The last chapter focuses on dredged materials, including their disposal and the treatment of strongly contaminated sediments. Cases studies include the Niagara River/Lake Ontario pollution; solid speciation of metals in river sediments; the Rhine River; Puget Sound; Rotterdam Harbor; and the mobilization of cadmium from tidal river sediments.
Evaluation of a grid-based river flow model using Regional Climate Model output over Europe
Regional Climate Models (RCMs) offer significant improvements over Global Climate Models in terms of their representation of rainfall at the spatial and temporal scales required for hydrological modelling. Here we test a new implementation of a grid-based hydrological model embedded in a model of land-surface climatology (the Joint UK Land Exchange Scheme; JULES) against observed river flows in several major NW European rivers, including the Rhine, Maas, Elbe, Danube, Loire, and Seine. Our hydrological model comprises a probability-distributed model of soil moisture and runoff production (PDM) coupled with a discrete approximation to the one-dimensional kinematic wave equation to route surface and subsurface water downslope (G2G). The model was driven with hourly output from the Hadley Centre regional climate model, which itself was driven using results from the ERA-40 reanalysis experiment (1961-2000). The results of simulations for river catchments in northwest Europe are presented and compared with measured river flows over the same time period, for the same locations. The success with which the runoff production and flow routing components of the land-surface model match observed flow data is evaluated.
[Concentration of heavy metals in brook trout in comparison to aquatic plants and sediments].
From 1974 to 1977 the heavy metal content of river water, fishes (Salmo trutta fario), three aquatic plants (Cladophora glomerata, Potamogeton pectinatus, Zannichellia palustris), one river-bank plant (Phalaris arundinacea), and sediments (clay fraction) taken from the River Leine, up and downstream of Göttingen, were determined. Galvanic-bath sewage containing heavy metals caused an increase (11-60%) in the concentration of nine elements in the water. The average level of heavy metals in the river water corresponded to that of the Ems, Elbe and Weser, but was lower than that of the Neckar, Rhine and Danube. It was also below the European Community Guidelines (1975) on the quality of water used for the artificial recharging of ground water. River water upstream of the city has been used for this recharging for many years. There is a good correlation between the metal content in the investigated samples and in the water. In the muscles, only Cd, Co and Mn, in the liver Cd, Co, Cr. Hg, Mn and Zn, and in the total fish Cd, Co, Cr, Cu and Zn had increased significantly. In contrast to all other elements, Cr shows the highest concentration in the muscles. A previous accumulation of Cr in the liver is not a prerequisite for the accumulation in the muscles. Mercury shows the highest accumulation in the muscles, apparently because of the high retention rate of this element. Muscles also are a good monitor for this element. The impact of heavy metals on the Leine water was reflected in aquatic plants, which showed an increase in concentration up to 95-fold (according to metal or plant) - but not in river-bank plants. C. glomerata has the remarkable capability of accumulating all ten elements. Since P. arundinacea cannot reflect the different load of heavy metals it is therefore less suitable as a biological monitor for these metals.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:6685956
A critical factor controlling changes in the acidity of coastal waters is the alkalinity of the water. Concentrations of alkalinity are determined by supply from rivers and by in situ processes such as biological production and denitrification. A 2-year study based on 15 cruises in Liverpool Bay followed the seasonal cycles of changing concentrations of total alkalinity (TA) and total dissolved inorganic carbon (DIC) in relation to changes caused by the annual cycle of biological production during the mixing of river water into the Bay. Consistent annual cycles in concentrations of nutrients, TA and DIC were observed in both years. At a salinity of 31.5, the locus of primary production during the spring bloom, concentrations of NO x decreased by 25 ± 4 ?mol kg-1 and DIC by 106 ± 16 ?mol kg-1. Observed changes in TA were consistent with the uptake of protons during primary biological production. Concentrations of TA increased by 33 ± 8 ?mol kg-1 (2009) and 33 ± 15 ?mol kg-1 (2010). The impact of changes in organic matter on the measured TA appears likely to be small in this area. Thomas et al. (2009) suggested that denitrification may enhance the CO2 uptake of the North Sea by 25%, in contrast we find that although denitrification is a significant process in itself, it does not increase concentrations of TA relative to those of DIC and so does not increase buffer capacity and potential uptake of CO2 into shelf seawaters. For Liverpool Bay historical data suggest that higher concentrations of TA during periods of low flow are likely to contribute in part to the observed change in TA between winter and summer but the appropriate pattern cannot be identified in recent low-frequency river data. On a wider scale, data for the rivers Mersey, Rhine, Elbe and Weser show that patterns of seasonal change in concentrations of TA in river inputs differ between river systems.
Modelling combined effects of nutrients and toxicants in a branch of the Rhine Delta
A model is presented in which fate and effects of both nutrients and toxicants are combined at the level of phytoplankton and zooplankton in a river system including its sedimentation area. Within water quality modelling emphasis has been on either eutrophication or on toxic fates. Eutrophication research mainly focuses on the relationship between nutrients and water quality parameters. Ecotoxicological studies on the other hand aim either at describing fate of toxic substances or estimating biological effects on or below organism level on the basis of dose-effect experiments. However, an integrated approach linking fate and effects of nutrients and toxic substances on the ecosystem level is demanded to understand the behavior of natural systems exposed to a mix of compounds. The model describes a branch of the river Rhine, the river IJssel, with its sedimentation areas, lake Ketelmeer and lake IJsselmeer, which have suffered severely from high inputs of both nutrients and heavy metals in the past. Only from the seventies onward international sanitation programs have significantly improved the situation. Despite the improvements further actions are required because the problems of high chlorophyll levels as well as high loading of metals remain. It is shown that nutrients may induce an increase in phytoplankton biomass due to less efficient zooplankton grazing. Model results show that in order to change the present state of eutrophication also the input of xenobiotic substances affecting the zooplankton must be decreased.
Protein-electrophoresis of 20 enzyme systems (representing 35 encoding loci) in 224 specimens of Salmo trutta from eleven populations in Baden- Wuerttemberg yielded ten allozyme polymorphisms. One locus, LDH-5*, shows a correlation with the Danube, respectively Rhine, catchments, with the allele LDH-5*105 being distinctly more frequent in the Danube system. Stocking measures lead to enhanced genetic variability and to the levelling of local forms. In populations from acidified brooks, genetic variability is reduced. A weir separates genetically distinct populations.- In 89 specimens of Cottus gobio from four populations in Baden- Wueertemberg, 14 enzyme systems representing 23 genetic loci were investigated. Five loci exhibited genetic polymorphisms. Genetic variability of the investigated specimens of this species from Baden-Wueertemberg within the populations and between the populations in either of the two river catchments, Rhine or Danube, is low. Great differences exist between the Rhine and Danube populations.- The European species Misgurnus fossilis may be under threat due to the introduction of Asian species. 16 enzyme systems representing 19 genetic loci were investigated. A fertile cross-breed of the two species and, thereby, the risk of genetic introgression seem unlikely on account of the genetic distance. Genetic markers for unequivocal determination of the two species and their possible hybrids are identified. (orig.) [Deutsch] Die proteinelektrophoretische Untersuchung von 20 Enzymsystemen (die 35 kodierende Loci repraesentieren) aus 224 Bachforellen von elf baden-wuerttembergischen Populationen erbrachte zehn Allozym-Polymorphismen. Ein Locus, LDH-5*, zeigt eine Korrelation mit dem Donau- bzw. Rheineinzugsgebiet, wobei das Allel LDH-5*105 im Donausystem deutlich haeufiger ist. Besatzmassnahmen fuehren zu einer Erhoehung der genetischen Vielfalt und zu einer Novellierung lokaler Formen. Die genetische Vielfalt ist bei Populationen aus versauerten Baechen verringert. Ein Stauwehr trennt genetisch distinkte Bestaende. Aus 89 Gruppen von vier baden-wuerttembergischen Populationen wurden 14 Enzymsysteme, die 23 genetische Loci darstellen, untersucht. Fuenf Loci zeigten genetischen Polymorphismus. Die genetische Vielfalt der untersuchten Gruppen in Baden-Wuerttemberg innerhalb der Bestaende und zwischen den Bestaenden eines Stromeinzugsgebiets, Rhein bzw. Donau, ist gering. Grosse Unterschiede bestehen zwischen Rhein- und Donaupopulationen. Der Europaeische Schlammpeitzger ist moeglicherweise durch Einbuergerung asiatischer Schlammpeitzgerarten bedroht. 16 Enzymsysteme, die 19 genetische Loci repraesentieren wurden untersucht. Eine fruchtbare Kreuzung der beiden Arten und damit die Gefahr einer genetischen Introgression scheint aufgrund der genetischen Distanz unwahrscheinlich. Genetische Marker zur eindeutigen bestimmung der beiden Arten und derer moeglichen Hybriden wurden identifiziert. (orig.)
The limited transparency of the river water of the Kromme Rijn, a dammed distributary of the Rhine River in the Netherlands, restricts the ecological function of the stream and the achievement of the EU-Water Framework Directive targets. To increase water transparency in this river, the 'Hoogheemraadschap De Stichtse Rijnlanden' (HDSR) water authority considers to design one or more large-scale sediment traps. For an optimal design of these possible sediment traps, further knowledge about the local sediment characteristics and sedimentation and resuspension rates is a prerequisite. At the request of the HDSR water authority, we studied the fine sediment characteristics and dynamics in the Kromme Rijn river and its tributaries. Between summer 2010 and summer 2011, eleven monthly water samples were collected from six monitoring locations in the 25 km long reach of the Kromme Rijn river between the inlet from the Nederrijn river and Utrecht. Additional samples were collected from seven monitoring locations in streams and canals discharging into the Kromme Rijn river. The water samples were analysed for suspended sediment concentration and the suspended sediment was analysed for loss on ignition and particle size distribution by laser diffraction. In addition, at these monitoring locations, small sediment traps with an 8 cm circular opening were installed at 0.7 m below the water surface to measure the gross long-term sedimentation rate. These sediment traps were emptied every two months. During the monitoring period, the average sediment load in the Kromme Rijn near the inlet was 112 g/s and decreased to about 90 g/s near Utrecht. The vast majority of the sediment load (91%) in the main branch of the Kromme Rijn originates from the inlet from the Nederrijn river. The 2-16 ?m and 16-63 ?m particle size classes comprise about 80% of the suspended sediment. The average organic fraction of the suspended sediment was 36%. The sediment collected from the sediment traps were slightly finer and contained less organic matter (20%). The long-term (>2 months) average gross sedimentation flux in the Kromme Rijn river was measured to be 330 g m-2 d-1. As the sediment load only decreases by 20% in the 25 km long studied reach of the Kromme Rijn river and the sediment supply from the tributary streams and canals is limited, this gross sedimentation flux should be compensated by an average gross resuspension flux of approximately 240 g m-2 d-1. This would imply that the river reach length over which the effect of a possible sediment trap is noticeable is limited to about 5-10 km.
Assessing the impact of non-point loading on river systems: A joint German-Canada study
Understanding the ecological effects of non-point sources of nutrient and contaminant loadings has become increasingly important in the management of riverine ecosystems, particularly since successes in controlling effluent emissions have resulted in the reduction of point-source loadings to rivers in industrialized nations. The federal governments of Canada and Germany recognize the need to evaluate the impact of non-point loading, particularly agricultural, on river systems since nutrients and agricultural contaminants can directly affect ecosystem structure and processes. Moreover, in Germany, the government`s target of achieving equal environmental conditions throughout its unified territory by the year 2000 has provided impetus to develop cost-effective methods for determining the effect of agricultural activity on aquatic ecosystems. The objective of this study is to combine biological, chemical and hydrological approaches for assessing non-point source loadings to rivers in Canada and the former German Democratic Republic, and to make recommendations for the design of future monitoring programs. Studies were recently initiated on small tributaries of the Elbe River, Germany, and the Athabasca River, Canada, to quantify non-point nutrient loading, identify reaches of nitrogen or phosphorus limitation, and evaluate changes in benthic algal and invertebrate communities in relation to land-use practices. Once methods have been established and validated, the project will be scaled up to large river catchment areas. This study also assesses several rapid bioassessment techniques for monitoring riverine ecosystems impacted by non-point loadings.
To study the behaviour of silver eels (Anguilla anguilla L.) during their downstream migration, particularly near a hydroelectric power dam, we tagged nine eels with ultrasonic transmitters and tracked their paths in the River Mosel, Germany. The onset of migration coincided with the first flood eve...
The biological phase of a wastewater treatment plant situated in the Ruhr River Region (Germany), has been monitored for about one year. The collected experimental data have been elaborated in this paper with the objective of an assessment of the reliability of some recent steady-state design criteria of the activated sludge process with biological nitrogen removal and chemical phosphorus removal.
The contribution under consideration is the first appendix to the environmental research plan of the Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (Berlin, Federal Republic of Germany) on ''Hydropower and Water Framework Directive''. This appendix contains a description of the locations in the tributaries of the German river Weser.
Synthetic musks in fish and other aquatic organisms
Musk compounds are widely spread environmental pollutants. Musk compounds were found in aquatic organisms from the North Sea, in rivers, lakes and estuaries in Canada, Czech Republic, Germany, Italy, Luxembourg, Japan, Norway, Switzerland, Sweden, and The Netherlands. Two nitro musks, musk xylene (M...
An application of a large scale conceptual hydrological model over the Elbe region
This paper investigates the ability of the VIC-2L model coupled to a routing model to reproduce streamflow in the catchment of the lower Elbe River, Germany. The VIC-2L model, a hydrologically-based land surface scheme (LSS) which has been tested extensively in the Project for Intercomparison of Lan...
The aim of the study was to identify the geogenic source for elevated arsenic (As) concentrations recently discovered in soils of the Heubach plain, North Rhine-Westphalia, Germany. Therefore, a catalogue of conditions that an As source has to fulfil in order to be considered as geogenic was formulated, including the source’s linkage to the sink, its mineralogy, As total content, As mobilization potential, groundwater redox conditions and As output. Accordingly, mineralogical, geo- and hydrochemical investigations were carried out, including X-ray diffractometry, microscopy, ICP-OES and AAS analysis and a sequential extraction procedure. Paleo bog iron ores (PBIOs) of Tertiary age, occurring within unconsolidated sands (Haltern-layers, Santonian-Lower Campanian), and glauconitic marlstones (Dülmen-layers, Lower Campanian) were examined. Results indicate that output from the PBIOs is responsible for the elevated As levels. Accounting their diverse mineralogy, five types of PBIOs were defined. Type-dependent, they at least partly fulfil all of the formulated requirements. The relations and behaviour of As sources and sinks in space and time could be clarified for the area of interest. The approach presented in this paper may offer a tool for identifying natural As sources worldwide.
New techniques have been developed for the analysis of stump horizons that result in a relatively detailed three-dimensional reconstruction of ancient forests. In addition, a rough estimate of their above-ground standing biomass can be calculated. These techniques are applied to an in-situ Miocene peat forest preserved in the Lower Rhine Embayment, northwestern Germany. In a study area of 2500 m[sup 2], 476 stumps were mapped and used in the forest reconstruction. Additionally, pollen samples and leaf remains have been analysed. The peat forest consists primarily of conifers (in particular Taxodiaceae and Pinaceae) with Sciadopitys being the most common genus. The only angiosperms in the wood flora were palms, but in the pollen flora, evidence for the Myricaceae, Mastixiaceae, Ericaceae and a few other angiosperms is also present. The forest was relatively dense with 1904 trees/ha and a basal area of 164 m[sup 2]. Mean trunk diameter was 28 cm, while mean tree height is calculated to have been 9.9 m. Estimated above ground biomass is 750 t/ha, but this value also includes dead or partly dead trees. This peat forest does not closely compare with previous reconstructions of Miocene peat forests. Its three dimensional structure and biomass differ from those of modern bald cypress swamps.
Rheinhafendampfkraftwerk (RDK) operated by EnBW Kraftwerke AG, Germany is located to the West of Karlsruhe town center and on the Rhine. A total of several power plant units were put into operation on this site in the period between 1955 and 1985. Today's RDK consists of four power plant units, 4,5,6 and 7 that have an overall capacity of 1270 MW, and with units 5 and 6 used as reserve capacity only. Unit 7 is hard-coal-fired, with a rated electrical output of 550 MW and 220 MW of heat extraction for the district heat network of Karlsruhe. It is designed for intermediate-load duty and operated for around 6500 hours a year. The paper described the reasons for deciding to modernise the computer systems for Unit 7. This involved replacing the burner management system for the main boiler prior to installing new automation systems, computer units and diagnostics systems. The I & C modernization was implemented without any additional outage time with no faults occurring on commissioning. The same approach is being implemented for other coal-fired power plants of the same vintage. 17 slides/overheads accompany the text of this presentation.
It is a long way from the first idea to the finished geothermal plant on which many obstacles must be mastered, from site selection to the provision of funds. This guide addresses investors, project managers and project controllers, all of whom are faced with a lack of demonstration objects in the upper Rhine graben which would enable them to calculate the cost, profits and risks of geothermal projects. The only geothermal power plant now in operation in Germany is in Neustadt-Glewe in the state of Mecklenburg-Vorpommern. The geothermal guide explains aspects of funding, obstacles and possible alternatives required for establishing and investment plan. The final investment plan of the pre-projecting phase provides information on the economic efficienc of a geothermal project in optimal conditions. The pre-projecting phase ends with the drilling of the first well. Currently, there are three projects in the state of Rheinland-Pfalz, at Speyer, Offenbach and Landau. Some of the experience gained will be unique while some will be applicable to other projects. The guide intends to make the applicable part as big as possible and help other and/or future investors, project managers and project controllers by providing them with useful addresses, hints and information on how to manage a complex geothermal project. (orig.)
Approximately 3 million Turkish immigrants are living in Germany, in North Rhine-Westfalia their share amounts to 4.7%. They use the same rehabilitation services as Germans, but their treatment usually shows less positive results - as other studies have shown. The aims of the research project "Immigration and Health Inequalities in Rehabilitation" were (a) to quantify the use of medical rehabilitation by Turkish immigrants in different diagnosis groups, (b) to compare outcomes in different diagnosis groups and (c) to find out whether the results will be explained by immigrant status, or by socio-economic factors accompanying immigrant status.An analysis of routine data from Deutsche Rentenversicherung Rheinland and Deutsche Rentenversicherung Westfalen (Rhineland and Westfalia Pension Insurances) was carried out, pertaining to 363?855 persons who had participated in at least one rehabilitation procedure between 2000 and 2006. 4.8% of all rehabilitees were identified as being of Turkish origin. A modified name-based algorithm was used to help to identify Turkish rehabilitees. The outcome of rehabilitation was measured by comparing the medical discharge assessments. Turkish people were in need of rehabilitation more often because of mental disorders/behavioural disturbances (Turkish men=22.0% vs. non-Turkish men=18.4% [pwomen=30.8% vs. non-Turkish women=21.6% [pwomen=6.4% vs. non-Turkish women=13.9% [pImmigrant status, hence, affects rehabilitation outcome and must receive attention in both rehabilitation plans and rehabilitation facilities. PMID:22673867
The status colloquy, which covers five subject areas and comprises 27 individual contributions, deals with the measurement of air pollutants and processes of the atmospheric chemism and their influence on trees and forest ecosystems, as well as with the development of methods for elucidating these relationships: (1) Development of methods of investigation for, and investigations on, atmospheric chemism, nuisances, and deposition of pollutants; (2) survey of damage in forest stands in North-Rhine-Westphalia (northwestern Germany); (3) influence of soil-related stress (for instance, heavy metals), on trees; (4) soil-chemical and mycorrhiza investigations in various damaged forests; and (5) with 14 papers alone: Biochemical and physiological investigations using the open-top chambers and regional research stations of the research group. These have particular attention to the effect of ozone and nutrient deficiency (Mg) on the biochemism of spruce needles. (UWA). [Deutsch] Das Statuskolloq umfasst in 5 Themenbloecken mit 27 Einzelbeitraegen die Messung von Luftschadstoffen und atmosphaerischen Prozessen und ihren Einfluss auf Baeume und Waldoekosysteme sowie die Methodenentwicklung zur Klaerung dieser Zusammenhaenge: (1) Methodenentwicklung und Untersuchungen zur Atmosphaerenchemie, Immission und Deposition von Stoffen; (2) Schadenserfassung in Waldbestaenden in Nordrhein-Westfalen (NW-Deutschland); (3) Einfluss von bodenbuertigem Stress (z.B. Schwermetalle) auf Baeume; (4) Bodenchemische und Mycarrhizauntersuchungen in verschiedenen geschaedigten Waeldern; und (5) mit allein 14 Beitraegen: Biochemische und physiologische Untersuchungen unter Nutzung der Open-Top-Kammer-Anlage und der regionalen Forschungsstandorte der Forschungsgruppe. Hierbei wird besonderes Augenmerk der Auswirkung von Ozon und Naehrstoffmangel (Mg) auf die Biochemie von Fichtennadeln geschenkt. (UWA).
Ultraviolet disinfection of treated municipal wastewaters
A wastewater disinfection system developed by a Canadian company, Trojan Technologies Inc., was discussed. Disinfection for pathogen reduction prior to discharge of treated municipal wastewater back into rivers and lakes has been either ignored or treated by the use of chemicals. In 1979 the first pilot ultraviolet (UV) wastewater disinfection system was established. Since then, over 500 municipal UV installations have been commissioned. The largest installation can process 212 million gallons of water per day. The advantages of UV as a disinfectant are: (1) It is more effective than chlorine. (2) There are no mutagenic/carcinogenic byproducts formed with UV. (3) No toxic chemical residuals are discharged. (4) UV is safe to both the operators and the public. (5) It is cost effective. Europe has not been as active in wastewater disinfection as has North America. One result of the absence of wastewater disinfection in Europe is that the Rhine River, for example, carries 50 million salmonella per second. Disinfection of wastewater effluents is, of course, indispensable in protecting our drinking water supply. 2 figs.
The Federal Institute of Hydrology has developed operating strategies in order to deal with dredged material within the scope of the Waterways and Shipping Administration. Sediments will be assessed based on certain quality parameters. The potential environmental impact at the source and relocation areas has to be evaluated in respect to ecological and economical issues. A coordinated sediment management plan for the Rhine River was commissioned. The most important contaminated sedimentation areas were identified, and special sedimentation areas were classified based on ecological impact or even risk. Proposals for economical and ecological strategies are discussed. Further developments for operational instructions dealing with sediments and dredged material in federal waterways are still being processed. The objectives of the river basin commissions as well as those of the stakeholders have to be met in an appropriate manner. In the framework of the analysis and impact of climate change on both sediment quantity and quality for optimizing sediment management, one or more dimensional hydraulic models will be applied. This will help gain a better insight into the understanding of contaminant transport in freshwater bodies. (orig.)
Suspended particulate matter is an important carrier for higher brominated diphenylethers in the aquatic environment. - Polybrominated diphenyl ethers (PBDEs) have been determined in 133 samples of suspended particulate matter (SPM), sediments, sewage treatment plant (STP) influents and effluents, fish and mussels from various locations in The Netherlands, as a part of a large Dutch national study on estrogenic contaminants in the aquatic environment (LOES project). Some PBBs were also analysed but not found in any of the samples at detectable levels. PBDEs and PBBs were included in this study because indications of long term effects on the balance of endocrine systems were found in the literature. High concentrations of decaBDE (up to 4600 {mu}g/kg dry weight) were found in SPM from the Western Scheldt. These levels are possibly related to spillage during use of PBDEs in industries upstream the river Scheldt in Belgium. SPM was identified as an important carrier for higher brominated diphenyl ethers in the aquatic environment. DecaBDE was not found at detectable levels in flounder, bream and mussels. The bioaccumulation of decaBDE in these fish and shellfish samples is apparently limited. Lower brominated PBDE congeners (tetra/penta) were also found in the Western Scheldt as well as in the Rhine delta and the river Meuse, but in much lower concentrations than the decaBDE. In contrast with decaBDE, the tetra and pentaBDEs were found in biota. It was concluded that at least a small part of the PBDE can pass STPs.
The Phaeocystis-dominated eastern Southern Bight of the North Sea is a highly dynamic system with water masses resulting from the variable mixing between the inflowing southwest Atlantic waters through the Strait of Dover and freshwater and nutrient inputs from the Seine, Scheldt and Rhine rivers. Here we use the complex ecosystem model MIRO to explore the dual role of short-term climate variability and nutrient loads of anthropogenic origin on the magnitude and extent of diatom-Phaeocystis blooms in the Southern Bight of the North Sea during the last decade. MIRO was established to resolve the changing nutrient loads, the complex biology and the tight coupling between the benthic and the pelagic realm that characterises this shallow coastal shelf ecosystem. The model was run to simulate the annual cycle of inorganic and organic nutrients, phytoplankton (diatoms and Phaeocystis), bacteria and zooplankton (microzooplankton and copepods) in the Southern Bight of the North Sea for the period 1989--2000. For this application MIRO was implemented in a multi-box frame delineated on the basis of the hydrological regime and river inputs. Model results give for the first time a general view of the interannual variability of blooms and nutrient cycling within the domain. Further C, N, P and Si budget calculations allow estimating the buffering capacity of the system with respect to the nutrient loads. Additional MIRO runs are conducted to explore the ecosystem response to several nutrient reduction scenarios under contrasting climate conditions.
Within the 3rd conference 'Geothermal technologies' of the VDI Wissensforum GmbH (Duesseldorf, Federal Republic of Germany) between 23rd and 24th March, 2010, in Potsdam (Federal Republic of Germany) the following lectures were held: (1) Economic energy yields of the use of geothermal power according to Renewable Energy Law (EEG) and Act on Power Generation from Renewable Energy (EEWaermeG) (M. Maslaton); (2) Investments in geothermal energy projects from the view of a power supply company (K. Winkler, O. Heil); (3) Legal aspects and risks of geothermal projects (H. Gassner); (4) Utilization options of deep geothermal projects - state of the art and perspectives (K. Erbas et al.); (5) Geothermal utilization in the Upper Rhine Graben Landau - Insheim (P. Hauffe); (6) Experiences from planning and operation of the geothermal project Pullach (M. Kaelcke); (7) Consideration and evaluation of risks in the planning of geothermal projects (W. Bauer); (8) Drilling aspects - an important step in the realization of a deep geothermal project (A. Sperber); (9) Technical deviations in the drilling program - Experiences with the digestion of the Malm deep groundwater aquifer in Bavaria (A. Schubert, M. Dax); (10) Technology transfer between oil and gas industry and geothermal (C. Teodoriu, C. Fichter); (11) Project planning of a deep drilling in the inner-city area (R. Jatho); (12) Requirements at underground components of geothermal power plants (J. Oppelt et al.); (13) Design of surface thermal water loop - solutions for different geological conditions (F. Kabus, G. Moellmann); (14) Plate-type heat exchanger for deep geothermal applications (J. Peschel); (15) Monitoring of geothermal plants - practical examples (P. Seibt et al.); (16) The geothermal project Erding - The construction of one of the greatest district heating systems based on geothermal energy (A. Boeffel); (17) Future personnel development for geothermal field of work in the deep geothermal energy (B. Kibellus); (18) Research for geothermal energy supply (E. Huenges).
Within the 5th International Geothermal Conference at 27th to 28th April, 2009, in Freiburg (Federal Republic of Germany) the following lectures were held: (a) Worldwide development of geothermal energy (Ladislaus Rypach); (b) Geothermal developments and applications in Turkey (Orhan Mertoglu); (c) Guermat Elektrik: Turkish experiences in geothermal financings (John F. Wolfe); (d) Geothermal exploration success: Using data and best practices from the oil and gas industry (Jan-Diederik van Wees); (e) Implementing geothermal power projects - risk management and financing from the investor's point of view (Christian Jokiel); (f) Risks and risk mitigation in the Upper Rhine Graben geothermal province (Christian Hecht); (g) The Soultz geothermal plant: from the concept to the first geothermal kWh (Albert Genter); (h) Binary power plant technologies for geothermal power generation (Kathrin Rohloff); (i) Kalina power plants - 10 years of operational experience (Gestur R. Bardarson); (j) 1,200 MW experience with innovative geothermal power plants (Hilel Legmann); (k) Challenges of managing geothermal power plant projects (Norbert Hartlieb); (l) Requirements for geothermal power plants (Athanasios Tsoubaklis); (m) Credit programme on productivity risk in deep geothermal projects (Karin Freier, Peter Hasenbein, Stephan Jacob); (n) Geothermal projects in the light of the financial crisis (Thomas G. Engelmann); (o) Insurability of geothermal projects (Matthias Kliesch); (p) Requirements for equity investors to finance a geothermal project (Thoma G. Engelmann); (q) Aspects of project development from an investor's perspective (Bernhard Gubo); (r) Project requirements and challenges in geothermal projects (Olaf Heil); (s) The 'quest' for appropriate locations for HFR projects in Southern Germany (Wolfgang Bauer); (t) Status of the Soultz geothermal power plant and the deep reservoir after some months of circulation (Albert Genter); (u) Hot-fractured-rock technology - risk or chance? (Ralph Weidler).
Fate of pharmaceuticals in rivers: Deriving a benchmark dataset at favorable attenuation conditions
Pharmaceutical residues are commonly detected organic micropollutants in the aquatic environment. Their actual fate in rivers is still incompletely understood as their elimination is highly substance specific and studies often report contradictory results. To elucidate the ceiling of attenuation rates of pharmaceuticals in rivers we carried out a study at a river with favorable conditions for the elimination of organic micropollutants. Experiments were carried out at a small stream in Germany. Composite samples were taken at both ends of a 12.5 km long river stretch located downstream of a sewage treatment plant and analyzed for 10 pharmaceuticals. Moreover, pore water samples were taken and in situ photolysis experiments at several sites within the river stretch were performed to assess t...
In Germany, the threshold value between small and large hydropower plants (HPP) is defined at a generator power of 1 MW. The present paper describes the status quo of large run-off river HPPs in the German catchment basin of the Elbe river. Currently, there are no conditions (weirs) for the utilization of the large hydropower potential (approx 1 TWh/a) of the Elbe river itself. However, there are thirty two HPPs at the tributaries of the Elbe river having a total installed power of 60 MW works, whereof 52 MW account for the Saale and Mulder river basins in nearly equal parts. The installation of new HPPs at existing weirs with a total power of 16 to 18 MW is under investigation. (orig.)
[Animal welfare aspects regarding the raising of breeding ostriches in Germany].
The commercial housing of African Ostriches in Germany for the breed and meat production still represents a disputed topic under the criterion of the animal's welfare. Above all critics state that the frequently wet-cold weather in Germany impairs the well-being and health of the animals. So far however there are just a few scientifically documented data about requirements for housing conditions of ostriches in Central Europe and thus hardly answers whether housing in Germany is possible under the criteria of the animal's welfare. This study tried to evaluate ostrich housing under South German climatic conditions (Rhine level), on the basis of behavioral observations of breeding ostriches. The use of the stable and the influence of different climatic parameters on the behavior were considered. In addition the behavior of 18 adult animals in 5 breeding groups from January to December 2002 was observed. Parallel various climatic data were raised. The housing of the animals took place in open stables with unrestricted pasture possibility. The ostriches reacted in their behavior to different climatic conditions. Particularly at cold weather and adverse soil conditions they used the open stable increasingly as weather protection. In addition, with increased wind velocities the animals spent more time in the stables. The daily amount of precipitation showed no influence on the frequency or duration of the stable use. Rainfall did not animate the animals to look for protection within the stable, but more to set itself on the ground in the external enclosure. The locomotion activity of the animals was strongly in dependence to the reproduction time and the territorial behavior and therefore highest in spring. On cold days the animals performed their reproduction behavior mainly in the stable. For the comfort behaviour distinct weather dependence was seen particularly for sand bathing. Warm temperatures and dry sand were the preconditions for it. Regarding the results it seems, that with the conditions existing on the examined farm, housing of ostriches under respect of animal welfare in Germany is possible. New regulations are to be demanded, adjusted to the newest level of knowledge about ostrich husbandry, with requirements for care, support, accommodation and nutrition of the animals as well as about the qualification of the owners. An occasional hobby animal husbandry limited to few single ostriches is to be rejected. Further scientific investigations at other farms, possibly also under variable climatic conditions are however necessary. PMID:15847067
Bayesian estimation of the maximum earthquake magnitude in a time horizon
We show how the maximum expected magnitude within a time horizon [0,T] may be estimated from earthquake catalog data within the context of truncated Gutenberg-Richter statistics. Instead of deriving point estimations of this parameter in terms of expectation value and variance, we focus on the calculation of precise confidence intervals based on an imposed level of confidence ? . In detail, we present a model for the estimation of the maximum magnitude that is expected in a time interval T in the future, given a complete earthquake catalog for a time period Tc in the past and optionally paleoseismic events. In contrast to the well-known approaches of extreme-value statistics, we use Bayesian analysis without imposing distributions for the fluctuation of the earthquake intensity ? (corresponding to the Richter-a value) and the Richter-b value. We solely assume that earthquakes follow a stationary Poisson process in time with unknown intensity ? and obey the Gutenberg-Richter law in magnitude domain with unknown b value. The random variables ? and b are estimated by means of Bayes' theorem with non-informative prior distributions. We argue that from a statistical point of view the expected maximum magnitude in a time window is a reasonable parameter for probabilistic seismic hazard assessment, while the commonly used maximum possible magnitude for all times is not robust and does not allow for calculation of proper confidence intervals. We apply the model to an earthquake catalog of Lower Rhine Embayment, Germany and take into account paleoseimological findings. We find that with a probability of 5% the maximum earthquake in the next 50 years in the Lower Rhine Embayment has magnitude m>6.0, which could have disastrous consequences in this highly populated region. In the case that such an earthquake occurs in the area of Cologne with 10 km focal depth, the estimated loss will be around US 14.5 billion. Finally we discuss the applicability of the model for long time horizons (10^5 sim 10^6$ years), which are relevant for nuclear power plants and nuclear waste deposits.
A comprehensive and renowned conference offers the opportunity to extend the scope beyond mere technical issues. It allows for having strategic presentations and discussing aspects of market introduction, industrial and Governmental target setting as well as approaches to and actions for implementation. The 18th World Hydrogen Conference 2010, WHEC2010, succeeded in exploiting this opportunity and satisfied the expectations. Strong political support in Germany and in the State of North Rhine Westphalia in particular made it possible to have high profile decision makers at the conference presenting their strategies first hand. Hence, a full day was dedicated to plenary speeches and overview talks. The WHEC2010 came handy at a time when fuel cells are developed to suit the requirements for vehicles, except for cost and durability. At a time when the competition with batteries and whether or how a hydrogen infrastructure can be established and afforded were hot topics in the public debate, which needed answers on a well informed basis. Considering fuel cells and hydrogen at a time at one conference and supplementing it with the current knowledge on batteries and hybridization clarity on the future role of these technologies was gained. Very likely fuel cells and batteries will coexist in a future of electrified vehicular transport. Their different technical characteristics will open the doors to different market segments. Implementing hydrogen infrastructure, being a requirement for fuel cells in transport, is considered doable and affordable. This book presents the speeches and overview papers from the plenary session of the WHEC2010 on May 17, 2010. Six further books of this issue contain the papers of the oral and poster presentations, except for the introductory talks of the sessions. The latter are published separately by Wiley in a book named Hydrogen and Fuel Cells. In total the 18th WHEC is documented on over 3800 pages in a structured way in order to reach the broad spectrum of potential readers. The editors gratefully acknowledge the strong and sustained support of the State of North Rhine Westphalia and the EnergieAgentur.NRW.
Hydrogeochemical investigations were carried out on oilfield waters from sedimentary basins and troughs in NW Germany (Lower Saxony Basin including the Gifhorn Trough as well as the East Holstein Trough) and the Upper Rhine Valley. These investigations were done to determine the origin and evolution of these brines. Previous research as wll as statistical methods were considered in order to judge the influence of secondary oil recovery on each oil field and to separate disturbed and undisturbed formation waters. Especially the amount of total dissolved solids (TDS) was suitable to determine whether the oilfield waters have been influenced by injection waters of lower salinity or not. The water samples taken from the East Holstein Trough and the Broistedt-Gifhorn Trough are from Jurassic strata, being mainly calcareous cemented sandstones. The oilfied waters of Jurassic-Cretaceous reservoirs in the western part of the Lower Saxony Basin are the most saline waters. Here the reservoir rocks are sandstones and partly limestones. In the Upper Rhine Valley all samples come from Tertiary sandstones except for those from Landau, which are from Triassic limestones and Tertiary sandstones. (orig.) [Deutsch] Im Rahmen dieser Arbeit wurden hydrogeochemische Untersuchungen an Oelfeldwaessern aus insgesamt elf Lagerstaetten durchgefuehrt. Im nordwestdeutschen Raum konnten Proben aus Erdoelfeldern des Niedersaechsischen Beckens einschliesslich des Gifhorner Troges sowie aus dem Ostholstein-Trog bearbeitet werden. Darueber hinaus wurden weitere Oelfelder im Oberrheingraben beprobt. Aufgrund der hydrogeochemischen Ergebnisse liessen sich, unter Beruecksichtigung der moeglichen Beeinflussung durch Injektionsmassnahmen, Aussagen zur Genese und Entwicklung dieser Erdoelbegleitwaesser treffen. Insbesondere statistische Verfahren waren geeignet, die durch Sekundaerverfahren beeinflussten und i.d.R. geringer mineralisierten Waesser von den originaeren Lagerstaettenwaessern zu unterscheiden. Auch die von den Betreiberfirmen zur Verfuegung gestellten aelteren Analysen der Oelfelderwaesser konnten zur Abschaetzung der Feldesentwicklung herangezogen werden. Die Oelfeldwaesser aus dem Ostholstein-Trog und dem Gifhorner Trog entstammen jurassischen Sandsteinen, die zumeist mit einem kalkigen Bindemittel zementiert sind. Die Waesser aus den Jura-Kreide-Reservoiren im westlichen Teil des Niedersaechsischen Beckens weisen die hoechsten Salinitaeten auf. In diesem Bereich besteht das Reservoirgestein aus Sandsteinen und Kalksteinen. Im Oberrheingraben stammen die Waesser ueberwiegend aus tertiaeren Sandsteinen. Nur im Erdoelfeld Landau wurden auch Waesser beprobt, die aus triassischen Kalksteinen und tertiaeren Sandsteinen gefoerdert werden. (orig.)
Coal 2005 - future needs coal; Steinkohle 2005 - Zukunft braucht Kohle
About 1.000 guests from politics, trade and industry and society, representatives of IG BCE, the church and press, radio and television journalists participated in the conference. Dr. Werner Mueller, president of the GVSt and chariman of the board of RAG Aktiengesellschaft, opened the conference. Dr. Wolfgang Reiniger, mayor of Essen, Christa Thoben, minister for economic affairs in North Rhine-Westphalia, and Albert Hettrich, minister of state in the economic ministry of Saarland, gave welcoming speeches at the Coal Conference. Guest speaker this year were the vice-chairman of the CDU/CSU-group in the Bundestag, Ronald Profalla, the outgoing minister for economic affairs, Wolfgang Clement, and the chairman of the IG BCE, Hubertus Schmold. In a turbulent time not only poritically, but in particular also from the energy point of view against the background of the developments on the international raw material markets with new elections and a probable grand coalition of CDU/CSU and SPD at Federal level following the anticipated end of the negotiations as well as the CDU/FDP coalition in office in North Rhine-Westphalia since May, the guests at the Coal Conference were, of course, particularly eager to hear the comments on the future prospects of the coal mining industry in Germany. Hence it is all the more satisfactory that there was no talk of a declining mining industry at least by the political representatives at Federal level. On the contrary there was general agreement that the principle of social compatibility is and will remain an absolute condition for all the measures affecting the coal mining industry. In his concluding remarks in the morning session Ulrich Weber, chairman of DMT and member of the board of RAG Aktiengesellschaft, again made this clear. During the afternoon session Bernd Toenjes, chairman of the board of DSK, examined the sometimes underestimated importance of the indigenous coal mining industry from the point of view of energy, raw material, structural and industrial policy in his papers on the subject of ''Indigenous coal - raw material problem''. The chairman of the board of Steag AG, Dr. Alfred Tacke, subsequently discribed how his company adapts to the market conditions in view of the prevailing political boundary conditions in his papers entitled ''Market prospects of conversion of coal to electricity''. (orig.)
Quantifying the proportion of tile-drained land in large river basins
A considerable reduction in the nutrient and pesticide inputs into the rivers and lakes of Germany is required in order to meet the "good ecological status" as demanded by the European Water Framework Directive (WFD). Subsurface tile drainage systems are one of the main pathways for such diffuse nutrient and pesticide inputs. However, the simulation of water and matter fluxes under tile-drained land on the landscape scale is still problematic in many countries, mainly due to a lack of data about the existing drainage systems. The present study examines for the first time whether an existing method to calculate the usually unknown proportions of tile-drained areas could be transferred to a large river basin, for which minimal data about drained areas is available. The study area was the Saale river basin (24,000 km 2 ) in central Germany, with a broad variety of soils and site characteristics. The share of tile-drained areas in the Saale river basin was calculated to be 11% of the agricultural area. Apart from that, the calculated proportion of tile-drained areas corresponded satisfactory with the statistical data of the meliorated areas of the former German Democratic Republic. The successful application of the promising method is considered as an important step towards the calculation of the proportion of tile-drained areas for the whole Germany and Europe.
Interest in the biodiversity value of urban waters is growing. Understanding key ecological processes is essential for effective management of these aquatic ecosystems. Our paper focuses on identifying the key factors that structure chironomid assemblages, such as water quality and dredging, in urban waters strongly influenced by seepage of large rivers. Chironomid assemblages were studied in urban surface-water systems (man-made drainage ditches) in polder areas along lowland reaches of the rivers Rhine-Meuse in The Netherlands. Multivariate analysis was used to identify the key environmental factors. Taxon richness, Shannon index (H'), rareness of species, and life-history strategies at urban locations were compared with available data from similar man-made water bodies in rural areas, and the effectiveness of dredging for restoring chironomid diversity in urban waters was tested. Three different chironomid associations were distinguished by Two-Way Indicator Species Analysis. Variation within and among chironomid associations were significantly related to substrate (sludge layer and substrate type: sand vs clay), %% cover of lemnids, submerged vegetation, filamentous algae, and water transparency. Chironomid taxon richness and H' were similar in urban and rural waters, probably because of their similar hydrologic, morphologic, and water-quality conditions and their similar dredging and weed-control regimes. Rareness was slightly higher in urban than in rural waters. In urban water systems, chironomid taxon richness was negatively related to sludge layer and %% cover of lemnids. Dredging changed chironomid species composition, and increased taxon richness and life-history strategies indicative of good O2 conditions. Therefore, dredging can be regarded as an effective measure to restore diversity of chironomid communities in urban waters affected by nutrient-rich seepage or inlet of river water
Trisiloxane surfactants, often referred to as superspreaders or superwetters, are added to pesticides to enhance the activity and the rainfastness of the active substance by promoting rapid spreading over hydrophobic surfaces. To fill the lack of data on the environmental occurrence of these compounds, we have developed and validated a method for their trace analysis in the aqueous environment. The method is based on liquid-liquid extraction followed by liquid chromatography and tandem mass spectrometry. The oligomeric distribution of trisiloxane surfactant in a reference solution was determined by a theoretical calculation and by experimental measurements. Based on these results, the quantification was performed by comparison with a calibration made with a single homologue instead of a mixture of homologues. This approach avoids a time-consuming synthesis of pure homologues and reduces the risk of wrong estimation of the concentration because of different response factors of the sample and the standard. Such an approach could be applied to the quantification of other ethoxylated surfactants following a similar distribution. The validation was performed from 2 to 250 ng/L (total surfactant concentration) in deionized water, tap water, and river water (Rhine water). Knowing the oligomeric distribution of the polymer in the reference solution, the corresponding calibration ranges were estimated for individual homologues. Limits of quantification were found to be between 0.37 ng/L and 15 ng/L. The total recovery of sample preparation was between 77% and 116%. Matrix effects were lower than 10% with river water and the relative standard deviation evaluated over ten identical samples of spiked river water was below 12%. PMID:22658138
Summary 1.-Freshwater ecosystems will be profoundly affected by global climate change, especially those in mountainous areas, which are known to be particularly vulnerable to warming temperatures. We modelled impacts of climate change on the distribution ranges of 38 species of benthic stream macroinvertebrates from nine macroinvertebrate orders covering all river zones from the headwaters to large river reaches. 2.-Species altitudinal shifts as well as range changes up to the year 2080 were simulated using the A2a and B2a Intergovernmental Panel on Climate Change climate-warming scenarios. Presence-only species distribution models were constructed for a stream network in Germany-s lower mountain ranges by means of consensus projections of four algorithms, as implemented in the BIOMOD pack...
The significance of floodplain channels to floodplain restoration and flood mitigation
This paper examines the significance of floodplain channels from both a restoration and flood protection point of view. In a project case study in the upper region of the river Weser Germany these two aspects, restoration and protection, are examined qualitatively and quantitatively. The quantitative analysis is applied in a section of the river with the help of a two dimensional flow model, RMA2. The essence of the contribution is to demonstrate that floodplain restoration can go hand in hand with flood protection. (orig.)
The highly invasive Chinese mitten crabs (Eriocheir sinensis) was studied to reveal the genetic relationship between three none self-sustainable population within the Polish Oder and Vistula River and Lake Vänern in Sweden. Crabs from self-sustainable populations were collected from the Elbe River (Germany), San Francisco Bay (USA) and five Asian river estuaries. Both parsimony and maximum likelihood analysis of the nuclear ITS 1 and ITS 2 regions reveal a similar topological pattern. The mitochondrial cytochrome c oxidase subunit I (COI) sequence had too low resolution to be informative. The Oder River haplotypes showed high sequence similarities to both the Elbe population and/or the native spawning areas in China. The Vistula River showed haplotypic similarity to specimens from the Oder River in Poland or the Elbe River. Also high sequence similarities were observed to the specimens from the Swedish Lake Vänern indicating to an origin from the River Elbe. Minor changes in evolutionary interpretation exist depending on how gaps are treated and the analytic method. There is a complex movement involving back and forth transoceanic colonization of the Chinese mitten crab haplotypes. Invasion routes are discussed in relation to ship transfer routes and canal waterways. PMID:22568700
Duckweed Lemna minor as a tool for testing toxicity of coal residues and polluted sediments
Duckweed, Lemna minor, was used for testing single elements and leachates of coal ashes and sediments by expressing growth as surface coverage. The EC50 for the elements Cd, Cu, Zn, As(III), As(V), Se(IV), Se(VI), SeO[sub 2] were 0.86, 2.2, 4.4, 8.4, 297, 21, 67, 37 [mu]M respectively. Leachates were tested of pulverized coal fuel ash (PFA), including 'low NO[sub x]' ashes, coal gasification slag (CGS), and, as a reference, the polluted sediments of a canal. The concentrations of elements in leachates of 'low NO[sub x]' PFA were higher than those in leachates of conventional PFA. The leaching of anions from PFA was quicker than the cations. CGS showed an absolutely minimal element leaching. Comparison of the effects of conventional PFA with sediments from Rotterdam harbor, River Rhine, and the canal shows PFA to be the far less toxic one. The sediment samples from the canal demonstrated strong growth inhibition, probably due to high zinc concentrations originating from industrial activity.
We discovered a free-living peritrich ciliate with outstanding features in the River Rhine. Its morphology and 18S rRNA gene sequence were studied with standard methods. Apocarchesium arndti n. sp. has several peculiarities. (i) There are ordinary zooids, macrozooids, and microzooids, which form a hemispherical rosette on a discoidal base, the stalk dish, locking the approximately 18 microm wide and up to 2 mm long, spirally contracting colony stalk. (ii) The stalk myoneme is connected only to the microzooids. (iii) A rosette contains up to 50 zooids not connected to each other but individually attached to the stalk dish with the scopula. (iv) The ordinary zooids are epistylidid, trumpet-shaped (approximately 6:1 length:width), about 180 x 30 microm in size, and have an ellipsoidal macronucleus subapically between oral cavity and dorsal side. (v) The myoneme system of the zooids, which can contract individually, forms a tube-like structure in the narrow posterior half of the cell. (vi) The silverline pattern belongs to the transverse-striate type. (vii) The oral apparatus is of usual structure, with kinety 1 of peniculus 3 distinctly shortened proximally. (viii) The 18S rRNA places A. arndti n. sp. as a distinct lineage near Vorticella and Carchesium. These data are used to provide an improved diagnosis of the genus Apocarchesium. Features (i)-(iii) and the molecular data indicate that Apocarchesium could be the type genus of a new peritrich family. PMID:20337807
Freshwater biodiversity has declined dramatically in Europe in recent decades. Because of massive habitat pollution and morphological degradation of water bodies, many once widespread species persist in small fractions of their original range. These range contractions are generally believed to be accompanied by loss of intraspecific genetic diversity, due to the reduction of effective population sizes and the extinction of regional genetic lineages. We aimed to assess the loss of genetic diversity and its significance for future potential reintroduction of the long-tailed mayfly Palingenia longicauda (Olivier), which experienced approximately 98% range loss during the past century. Analysis of 936 bp of mitochondrial DNA of 245 extant specimens across the current range revealed a surprisingly large number of haplotypes (87), and a high level of haplotype diversity (). In contrast, historic specimens (6) from the lost range (Rhine catchment) were not differentiated from the extant Rába population (, ), despite considerable geographic distance separating the two rivers. These observations can be explained by an overlap of the current with the historic (Pleistocene) refugia of the species. Most likely, the massive recent range loss mainly affected the range which was occupied by rapid post-glacial dispersal. We conclude that massive range losses do not necessarily coincide with genetic impoverishment and that a species' history must be considered when estimating loss of genetic diversity. The assessment of spatial genetic structures and prior phylogeographic information seems essential to conserve once widespread species. PMID:19876581
Triazine herbicide residues in central European streams.
Triazine herbicide residues were monitored in the rivers Adour, Danube, Garonne, Herault, Loire, Marne, Oise, Rhine, and Rhône from spring 1976 to fall 1977 to determine whether the continued use of the compounds resulted in accumulations of undesirable residues in the streams. Samples were generally collected monthly or bimonthly and analyzed for the parent compounds atrazine, simazine, terbumeton, terbuthylazine, and dealkylated metabolites GS 26571 (2-amino-4-etert-butylamino-6-methoxy-1,3,5-triazine) and G 30033 (2-amino-4-chloro-6-ethylamino-1,3,5-triazine). The compounds were extracted into dichloromethane and quantitated by gas chromatography (GC) with nitrogen-specific detection. Selected results were verified by GC with mass fragmentographic detection. Limit of detection was usually 0.4 mg/m3; 80 percent of all results were below 0.4 mg/m3, 14 percent were 0.4-1 mg/m3, 6 percent were 1-10 mg/m3, and 0.3 percent were higher than 10 mg/m3. Detectable residues were mainly atrazine from the downstream sampling sites. Residues usually peaked during June. PMID:537864
The toxic effects of pollutants on the mineralization of 2 [mu]g/L [U-[sup 14]C]-4-chlorophenol and benzoate were studied in microcosms with methanogenic sediment from a little harbor in the Rhine River. In contrast with studies using a high substrate concentration, no lag time was observed and the half-lives for 4-chlorophenol and benzoate were 1.6 and 0.55 h, respectively. The effect of increasing additions of benzene, chloroform, 1,2-dichloroethane, pentachlorophenol, and zinc on each mineralization reaction was measured. Toxicity data were fitted with a logistic dose-effect curve. The IC10 is defined as the concentration of a toxicant inhibiting the mineralization rate for 10%. The IC10 concentrations of benzene, chloroform, 1,2-dichloroethane, pentachlorophenol, and zinc on the benzoate mineralization were 150, 0.04, 71, 6, and 842 mg/kg sediment dry weight, respectively. This latter value includes the background concentration of 800 mg Zn/kg sediment. Their mineralization of 4-chlorophenol and benzoate showed similarities in the sensitivity to these toxicants. 4-Chlorophenol can be degraded via benzoate, which might explain the similarities in sensitivity of both mineralization reactions. Chloroform proved to be extremely toxic to anaerobic mineralization reactions, which might be attributed to the formation of very toxic and reactive intermediates formed during the slow anaerobic degradation of the chloroform in anaerobic sediments. Sediment quality criteria derived solely from standard toxicity tests using aerobic organisms may lead to complete inhibition of several important microbial processes in anaerobic sediments.
Degradation of 1,4-dichlorobenzene by enriched and constructed bacteria
Three strains, RHO1, R3 and B1, tentatively identified as a Pseudomonas sp., an Alcaligenes sp. and a Pseudomonas sp. which were able to use 1,4-dichlorobenzene as the sole carbon and energy source were isolated from water of the Rhine river and from the sewage plant at Leverkusen-Buerrig. A hybrid strain, WR1313, which uses chlorobenzene as the growth substrate, was obtained by mating the benzene-growing Pseudomonas putida strain F1 with strain B13, a Pseudomonas sp. degrading chlorocatechols. Further selection of this strain for growth on 1,4-dichlorobenzene allowed the isolation of strain WR 1323. During growth on 1,4-dichlorobenzene the strains released stoichiometric amounts of chloride. The affinity of the organisms to 1,4-dichlorobenzene was measured with strain R3 showing a K/sub s/ value of 1.2 mg/l. Respiration data and enzyme activities in cell extracts as well as the isolation of 3,6-dichlorocatechol from the culture fluid are consistent with the degradation of 1,4-dichlorobenzene via 3,6-dichlorocatechol, 2,5-dichloro-cis,cis-muconate, 2-chloro-4-carboxymethylenebut-2-en-4-olide.
Benzene biodegradation using an anaerobic column coupled to Mn(IV) reduction
Benzene, toluene, and o, m, p-xylene compounds make up a large proportion of gasoline. Due to spills and leaks from underground tanks, these compounds frequently contaminate groundwater and sediment. In particular the high solubility of benzene makes it very mobile and an extra danger to groundwater. Moreover, there are strong links between benzene and cancer and thus benzene is considered a serious pollutant. Contaminated sites usually become anaerobic due to microbe action. In this study, benzene biodegradation was done in a glass column inoculated with anaerobic Rhine River sediment and using Mn(IV) as the final electron acceptor. Under steady state operation, benzene biodegradation efficiency was as high as 95 per cent. Carbon dioxide and Mn(II) recovery rates were 81 and 77 per cent respectively. Reactor sediment was withdrawn on day 104 and subject to DGGE profiling. This sediment showed different band patterns than the original sediment that was not exposed to benzene. The authors conclude that the species associated with the degradation of benzene are of the genus Propionibacterium and Actinomyces. 17 refs., 2 figs.
The aim of this paper was to collect evidence for the effects of contaminants on biota in a highly dynamic river Rhine floodplain. To this purpose we reviewed the results of circa 10 studies performed in this floodplain. The floodplain was contaminated with elevated levels of cadmium, copper, PAHs, and PCBs and high levels of zinc which were at some sites above legislative values. The results showed that the present contaminants were accumulated by the floodplain inhabiting organisms, but meanwhile population and community effects were ambiguous. Only for the mayfly Ephoron virgo clear effects were detected at the level of the single floodplain. The absence of clear population and community effects is puzzling since at lower contaminant concentrations adverse effects were detected in other environments. Factors that may mask toxic effects include flooding and food quality and quantity. We conclude that given the site specific conditions, being an open, eutrophic system with a highly dynamic flooding pattern, assessment of the contribution of toxicants to observed population density or biomass and community composition requires 1] an increase in number of replicates; 2] a larger scale of investigation and 3] comparison to stable systems with comparable contamination levels.
1H-benzo-1,2,3-triazole (BTri) and its methylated analogues (tolyltriazole, TTri) are corrosion inhibitors used in many industrial applications, but also in households in dishwashing agents and in deicing fluids at airports and elsewhere. BTri and one of the TTri-isomers (4-TTri) are typical examples of polar and poorly degradable trace pollutants. Benzotriazole elimination in four wastewater treatment plants (WWTP) in Berlin ranged from 20 to 70% for 5-TTRi over 30 to 55% for BTri to insignificant for 4-TTri. WWTP effluent concentrations were in the range of 7-18 microg/L of BTri, 1-5 microg/L of 4-TTri and 0.8-1.2 microg/L of 5-TTri. BTri and 4-TTri proved to be omnipresent in surface waters of the rivers Rhine and Elbe with concentrations increasing from <0.05 microg/L to around 0.5 microg/L of BTri and 0.2-0.5 microg/L of 4-TTri over 600-700 km. Bank filtration is an important process to generate raw water for drinking water production from surface waters. Even after residence times of several months BTri and 4-TTri were determined in concentrations of a few hundred ng/L in bank filtration water. Isotherm data from batch experiments indicate that activated carbon filtration should be suitable to avoid intrusion of TTri into drinking water in partially closed water cycles. For BTri, however, sorption to activated carbon appears to be too weak and ozonation may be mandatory to remove it from raw waters. PMID:19666184
In the 1850's, the water quality of surface waters in the Moselle river drainage basin began to suffer from the development of heavy industrial activities (coal and iron ore mining, steel and soda making). Industrial development also fuelled a demographic impetus that proved detrimental to the quality of surface waters. This study uses archival sources to analyse the ineffectiveness of the policies that were launched to regulate pollution. In a region traumatized by the Prussian annexation of a quarter of its surface (1870), industrial production enjoyed a symbolic protection that allowed water pollution to go unabated. The fuzzy status of pollution in law contributed to the immunity of industrialists. From the 1950's on, fear that the region might experience severe water shortages due to the growth of water consumption by industries and cities alike enabled more stringent policies to be devised. They still had to take into account the interests of the heavy industry and their effectiveness is questionable. Hydrological planning was based upon a functionalist vision of water resources that did not take environmental issues into account. The situation changed in the 1970's and 1980's, when European integration and the Sandoz catastrophe in the Rhine (November 1986) tipped the scale in favour of more vigorous environmental policies. This study develops the concepts of a 'regional system' and of the 'mode of construction' of an environmental problem. These prove to be valuable theoretical elements to ground environmental geography studies. (author)
Only a few studies have attempted to quantify topography-depending water fluxes, to evaluate retention and reservoir capacities and surface run-off paths within large river basins because data availability and data quality are critical issues to face this objective. It becomes most relevant if water balance has to be calculated in large or transboundary river basins. The advance of space based earth observation data offers a solution to this information problem. Therefore, this paper mainly focuses on weaknesses and strengths analyzing topography with SRTM (Shuttle Radar Topography Mission) digital height data and thus provides techniques for their improved application in river network derivation, floodplain analysis, watershed hydrology in large as well as in large river basins (>1000 km2). In the analysis different types of digital elevation models (DEM), terrain models (DTM) and land cover classification data (biotope map, Corine Land Cover 1994) have been used. The DHMs are generated from Airborne Laser Scanning (0.5 m), topographic maps (10.0/50.0 m) and SRTM at 30.0 m and 90.0 m spatial resolution. SRTM digital height models are generated by Synthetic Aperture Radar (SAR) and show a high spatial variance in urban areas, regions of dense vegetation canopy, floodplains and water bodies. As study area serve the Elbe basin (Czech Republic, Germany) with its sub-basins and the Saale river basin (Germany, different federal countries Saxony-Anhalt, Saxony and Thuringia).
The hydroelectric power plant Harnrode at te river Werra in eastern Hessen was built in the years 1907 to 1909. It is an exceptionally small hydroelectric power plant with three structural Lawaczek turbines from the company Voith Hydro Holding GmbH and Co. KG (Heidenheim, Federal Republic of Germany). This turbine is a prototype and is positioned between a Francis turbine and a propeller turbine. This design is a good alternative especially in areas with varying slope ratios.
Sampling techniques and radiometric methods, developed and applied in a comprehensive radioecological study of the Danube River are presented. Results and radiometric data of sediment samples, collected by sediment traps in Austria and additionally by grab sampling in the Danube during research cruises between Germany and the delta (Black sea) are shown and discussed. Goal of the investigation is the protection of public and environment, especially the sustainable use and conservation of human freshwater resources against harmful radioactive exposure.
For twenty years, the occupational health physician Dr. Bernard Walters (Brilon, Federal Republic of Germany) bought old hydropower stations. Most of these old hydropower stations have been closed for years. Dr. Bernard Walters, however, gets them moving. The author of the contribution under consideration reports on the hydropower stations Ohl-Gruenscheid as well as Ehreshoven I and II at the river Agger in the Bergisches Land.
The wastewater treatments plants localized in the Ruhr River (Germany), generally present a typical wastewater temperature variation curve during the winter period. These temperature changes produce specific effects on the nitrogen removal efficiencies in the activated sludge systems. The so called `hysteresis` phenomenon is responsible for these effects. The paper deals with some simplified theoretical considerations and with a full scale experimental evaluations of the effects caused by the hysteresis phenomenon in the biological nitrogen removal.
River Basin Management Plans - Institutional framework and planning process : Cross-country analysis
The report it a deliverable to the Waterpraxis project, based on research carried out in WP3. It is based on country reports from analyses of water planning in one river basin district in each of the countries Sweden, Finland, Latvia, Lithuania, Poland, Germany and Denmark, and it compares the institutional set-up, the public participation and the potentials and barriers for implementing the water plans.
Effects of global change in the Czech Part of the River Elbe Basin and adaptation options
In Integrated Water Resources Management planning the effects of changing natural conditions (natural water availability) and socio-economic development (water demand) must be taken into consideration. Climate change will influence the water availability. In some sectors, e.g. agricultural irrigation, also the water demand is influenced by climatic conditions. Both, the development of natural water availability and water demand, are connected with certain levels of uncertainty. Therefore, scenarios of socio-economic development and climate change are required for Integrated Water Resources Management planning. The river Elbe basin (catchment area approximately 150,000 km²) is located in central Europe. The river Elbe basin is a trans boundary river basin. One third is located in the Czech Republic upstream of Germany, where two thirds of the basin is located. Therefore, inflows from the Czech part are important for instance for navigation in the German part. For navigation an inflow to Germany of 100 m3/s is required. Due to climate change the inflows are expected to decline. In the project GLOWA-Elbe a water management model for the whole river Elbe basin was developed. The model for the Czech part includes among others 52 reservoirs, 20 thermoelectric power plants, 70 hydroelectric power plants, 30 industrial users, 15 agricultural irrigation users, 40 public water utilities, and 160 waste water treatment plants. Two global socio-economic trends are renationalized and used in the simulations. Renationalized climate data are used to simulate the effects of climate change on natural discharges. Using the water management model the effects of global change on inflows from the Czech Republic to Germany are simulated. Using this model is it analyzed, if reservoir management in the Czech part can sustain a required inflow of 100 m3/s to Germany.
Heavy rains in Central Europe over the past few weeks have led to some of the worst flooding the region has witnessed in more than a century. The floods have killed more than 100 people in Germany, Russia, Austria, Hungary, and the Czech Republic and have led to as much as $20 billion in damage. This false-color image of the Elbe River and its tributaries was taken on August 20, 2002, by the Moderate Resolution Imaging Spectroradiometer (MODIS), flying aboard NASA's Terra satellite. The floodwaters that inundated Dresden, Germany, earlier this week have moved north. As can be seen, the river resembles a fairly large lake in the center of the image just south of the town of Wittenberg. Flooding was also bad further downriver in the towns of Maqgdeburge and Hitzacker. Roughly 20,000 people were evacuated from their homes in northern Germany. Fifty thousand troops, border police, and technical assistance workers were called in to combat the floods along with 100,000 volunteers. The floodwaters are not expected to badly affect Hamburg, which sits on the mouth of the river on the North Sea. Credit:Image courtesy Jacques Descloitres, MODIS Land Rapid Response Team at NASA GSFC
This paper analyses the potential gains and the main challenges for increased cross-border collaboration in the control of highly contagious livestock diseases in regions with cross-border reliance on production and consumption of livestock commodities. The aim of this intensification of cross-border collaboration is to retain the economic advantages of cross-border trade in livestock and livestock commodities while maintaining a low risk of highly contagious livestock diseases. From these two foci, possibilities for future policy making with respect to highly contagious livestock diseases are discussed: peacetime cross-border cooperation to improve the cost-effectiveness of routine veterinary measures and crisis time cross-border harmonization of current disease control strategies. A general disease management framework was used to describe the way in which these two fields are related to and affect the epidemiological system and, consequently, how they impact the stakeholders. In addition to this framework, the importance of a good understanding of influencing factors, that is, the production structure of livestock, was stressed because these factors are important determinants of the frequency and magnitude of highly contagious livestock diseases and their economic impact. The use of the suggested integrated approach was illustrated for the extended cross-border region of the Netherlands and Germany, that is, North Rhine Westphalia and Lower Saxony. For this region, current difficulties in cross-border trade in livestock and livestock commodities and possibilities for future cross-border collaboration were examined. The concepts and ideas presented in this paper should foster future development of cross-border collaboration in animal health control. PMID:23066698
A 500 year climate reconstruction of Southwest Germany based on documentary and direct data with a special focus on high resolute reconstructed extreme rain events Against the background of an increasing world population and the changes that this is causing to the earth, the increasing industrialisation resulting in more emissions of greenhouse gases, it is indispensable to differentiate between natural and anthropogenic climate changes. This applies equally to global as well as regional climates. Due to the fact, that the weather data measurement series in the upper Rhine valley go back a maximum of 150 years, it is not possible to use this data to grasp long term climate fluctuations. For example, the current climate is integrated in long scale climate cycles which last thousands of years. To describe these changes accurately, it is necessary to reconstruct the climate beyond that of instrumental series measurements. With the application of direct and indirect data (proxy data) a climate reconstruction will be attempted for the area of region TriRhena. With the application of documentary data it is possible to reconstruct the climate prior to instrumental measurements. These historical records are made up of, for e.g. weather descriptions, information about the wine harvest and other agricultural products, as well as their price fluctuations. Using this data it is possible to calculate meteorological parameters creating an index of air temperature and precipitation values. Climate is an integration of weather and therefore its worth to set the focus also on single interesting weather events. Especially extreme events can contribute to the thesis "learning from the past for a better future". Aim of the research is to identify and apply extreme flood events of the past 500 years as a basis for further analysis like a contribution to improve current flood hazard maps. The data which will be presented were extracted from historical records such as local annuals and chronologies from 1500-1900 and supplemented by instrumental observations since 1755.
Ship propellers in pictures; Zum Schiffspropeller - Eine Bilderreihe
This extensive series of pictures illustrates the creation of a propeller (casting, mechanical production, etc.), whereby various types of propeller and their specific problems (cavitation, surface roughness, etc.) are shown. The special shapes of modern-day propellers and screw spinners serve to improve propulsion, manoeuvrability and the creation of oscillatory pulses. Rudder bulbs are fitted and even high-performance propellers, in part rotational by 360 , are attached to pods under the ship. These pictures, which were collected during the author's many years of professional experience, show propellers of up to 8500 mm in diameter with outputs of up to 50,000 kW as well as a two-bladed propeller with a diameter of 2,500 mm and an output of only 1 kW, which was awarded the 1990 Environmental Technology Prize of the Rhine/Sieg region of Germany. (orig.) [German] In einer umfangreichen Bilderfolge wird von der Entstehung eines Propellers (Giesserei, mechanische Fertigung usw.) berichtet, es wird eine Darstellung von Propellern unterschiedlicher Ausfuehrungsformen gegeben und es werden spezielle Problematiken (Kavitation, Rauhigkeit usw.) gezeigt. Um Verbesserungen im Vortrieb, in der Manoevrierfaehigkeit oder auch in der Schwingungserregung zu erreichen, werden heute nicht nur Sonderformen fuer den Propeller, sondern auch fuer die Propeller-Haube gewaehlt. Es wird die Anordnung einer Ruderbirne vorgenommen und es werden Propeller bis zu grossen Leistungen an Gondeln unter dem Schiff angeordnet, auch z.B. um 360 Grad drehbar. Die breite Anwendung eines Propellers wird deutlich an Bildern aus der langjaehrigen Arbeit des Verfassers, welche Propeller von bis zu 8500 mm Durchmesser und fuer Leistungen von bis zu 50 000 kW zeigen oder an einem 2-fluegeligen Propeller von 2500 mm Durchmesser mit etwa lediglich 1 kW Leistung, der 1990 mit dem Umwelt-Technik-Preis des Rhein-Sieg-Kreises ausgezeichnet wurde. (orig.)
Utilization and disposal of coal mine wastes in the Ruhr
The largest amount of mining waste in the Ruhr area of Germany comes from watered mounds of coal wastes. Comprehensive guidelines for stock pile permits were put forward in the North Rhine-Westphalia in 1967. This paper documents the progress in the environmental management of stock piles since then. Until 1967, the danger of self-ignition was the major concern with erection and operation of stock piles. Now questions of stability arose, which were addressed by regulations in the stock pile guidelines. The new regulations included some aspects of protecting groundwater, surface water and the neighbourhood, and called for afforestation and vegetation cover for beautification of the landscape. The massive table mountains which dominate the Ruhr landscape in some areas today were developed instead of the previous tapered piles. These stock piles have ledges which provide better stability and utilisation. Growing environmental concern in the following years led to a rewording of the stock pile guidelines in 1984. Principles for the construction and reutilisation of stock piles in coal mining were compiled by a working group and published in 1985. With a scientifically secure and practically verifiable method, groundwater and water conditions were improved and measures for reutilisation of the piles by planting with trees and bushes realised. In addition, special conception measures for mounds, such as ecological systems and biotypes, and methods for fertilisation and care of recultivated areas were now generally regulated. Further increased environmental consciousness and water protection investigations led to revision of the `Principles` in July 1991, and a new wording of the stock pile guidelines is in preparation. 8 refs., 5 figs.
Pfalzwerke geofuture GmbH together with its general contractor BESTEC GmbH intend to build a geothermal power plant in Insheim using a single fault system in the crystalline rock for geothermal heat extraction. The Insheim site is located in the Upper Rhine Graben, about 4 km South of the geothermal power plant in Landau, Germany, and about 30 km North of the European EGS site at Soultz-sous-Forêts, France. In 2008 and 2009 two wells were successfully drilled to a depth of about 3,800 meters targeting the same fault system in the crystalline basement. The geothermal reservoir was tapped with a temperature of more than 165 degrees Celsius. In order to improve well properties and prepare both wells for safe, clean and viable power generation, circulation tests and hydraulic injections with gradually increasing flowrate were conducted in late 2009 and early 2010. Seismic monitoring networks, recording also ground velocities, along with an alarm plan ensured the success of the operations. The recorded peak ground velocities stayed far below the reference values of 3 and 5 millimeters per second, specified in the DIN 4150, while seismic activity obviously decreased during the hydraulic operations. In autumn 2010 a lateral well was drilled out of the injection well at approximately 2,500 meters, aiming to better distribute the fluid volume between the two injection branches and thus further minimize microseismic activity. During subsequent hydraulic injection tests no more seismicity was registered. The geothermal power plant in Insheim will have a capacity of 4 to 5 megawatts, capable of supplying about 8,000 homes with electrical energy. The beginning of electric power production is planned for summer 2012.
Peri-Tethys and hydrocarbons; Peri-Tethys et hydrocarbures
The Peri-Tethys program is a pluri-disciplinary paleo-geographic program carried out by 13 French and foreign partners belonging to universities, scientific institutes, industries and oil companies. The program was devoted to the study of the northern and southern peri-Tethyan platforms from the Carboniferous stage to the present day. The program started in 1993 as a successor of the former Tethys program and ended in 1998 with the publication of 24 paleo-geographic maps showing the paleo-environments and tectonics of the sedimentary basins of the northern margin (from the Atlantic ocean to the Ural and Aral sea) and of the southern margin (from Morocco to the Persian gulf) of the Tethyan domain. This article makes a detailed presentation of the hydrocarbon resources (oil and gas) of the peri-Tethyan sedimentary basins (geologic and geodynamical situation, reserves, source and reservoir rocks, traps, covers..). The main regions in concern are: the North Africa (Paleozoic systems, Mesozoic and Cenozoic systems, Syrt basin, Western Desert (Egypt), Pelagian basin (Gabes gulf), Suez gulf); the Middle East (infra-Cambrian systems, Paleozoic systems, Mesozoic systems, Cretaceous-Cenozoic systems); Russian platform and Caspian sea (Paleozoic systems, Volga-Ural basin, Pripyat-Dnepr-Donets basin, Pre-Caspian basin, Mesozoic systems, Cenozoic systems (South-Caspian basin)); Central Europe (Carpathian arc, flysch and molasse fronts, Pannonian basin, Vienna basin, Transylvanian basin, Black sea); North-West Europe (North Sea, Permian basin, centre and Northern grabens, Netherlands and Northern Germany oil provinces, Paris-England basin, Rhine graben); Southern Europe (Po basin, Adriatic sea and Sicily, Appennines (Italy), Aquitaine basin (France)). (J.S.)
BACKGROUND AND OBJECTIVE: We assessed the effect of regional deprivation on individual mortality by making use of a natural experiment: we followed up ethnic German resettlers from Former Soviet Union countries who were quasi-randomly distributed across the socioeconomically heterogeneous counties of Germany's federal state North Rhine-Westphalia (NRW). METHODS: We used data from the retrospective cohort study 'AMOR' on the mortality of resettlers in NRW (n=34 393). Based on the postcode of the last known residence we linked study participants to the 54 counties of NRW, which were aggregated in six deprivation clusters. Mortality rates and standardised mortality ratios (SMRs) were calculated for each cluster. After a mean follow-up of 10 years, 2580 resettlers were deceased. RESULTS: For male and female cohort members, mortality rates and SMRs were highest in the cluster 'poverty poles' (SMR men: 1.21, 95% CI 1.04 to 1.41; SMR women: 1.17, 95% CI 0.99 to 1.37), whereas they were lowest in the cluster 'prospering regions and suburban counties' (SMR women: 0.86, 95% CI 0.70 to 1.05) as well as in the cluster 'heterogeneous counties' (SMR men: 0.73, 95% CI 0.61 to 0.88). CONCLUSIONS: The population which was quasi-randomly distributed to counties of differing socioeconomic status experienced different levels of mortality. It was highest in regions with the highest level of regional deprivation. Previous studies describing this positive relationship between mortality and regional deprivation could not differentiate between compositional and contextual effects. Thus, our findings indicate that in terms of mortality, regional deprivation does matter. PMID:23093522
Lead contents in hair, whole blood and saliva were determined for 245 healthy children (121 male, 124 female, age: 8-10 years) from three residential areas of Duesseldorf (North-Rhine-Westphalia, Germany) with different traffic densities. The geometric mean for the lead content in hair was found to be 0.87 {mu}g/g (range: 0.2-9.9 {mu}g/g) for the entire test group. While the levels of lead in hair in the suburban population were significantly lower than in the two city centre populations, no significant difference concerning the lead content in hair could be detected in the latter. The geometric mean for lead concentration in whole blood amounted to 25.0 {mu}g/l (range: 8.0-154 {mu}g/l). There was no significant difference between the sub-groups. The lead concentrations found in saliva were rather low (range: <1.5-47.0 {mu}g/l). Of the values, 89% were below the detection limit of 1.5 {mu}g/l. Due to reduced levels of lead in fuel, the present study exposes that the amount of lead in the children examined has further decreased compared to preceding surveys. The correlation between the lead content in hair and the road traffic density was not corroborated by the findings with regard to amounts of lead found in blood, indicating that residual lead from fuel does not result in a substantial burden of lead found in the whole body. In contrast to levels of lead found in blood, levels of lead found in hair may be influenced more by environmental conditions. Saliva is not a suitable material for biological monitoring with respect to lead exposure in children.
Towards new Climate Scenarios for The Netherlands; connecting science and society
KNMI is working on a new set of Climate Scenarios for Dutch society based on the results of IPCCs AR5. These so called KNMI-next scenarios will replace the current KNMI-06 scenarios (based on AR4) published in 2006. KNMI-06 was adopted by the government as basis for the Dutch adaptation policy. As a result there are many users of these scenarios and KNMI is well aware of the large impact the new scenarios will have in the Netherlands. For this reason stakeholders are involved in the process from the start in 2009. Based on analysis of CMIP-5 runs, parameters are selected that discriminate different scenarios representing most of the uncertainty range. Various methods are used for downscaling to obtain better estimates of extremes and additional spatial detail. The concept of "future weather" is used to get more detailed insight in important meteorological phenomena such as periods of drought and long periods of precipitation and provide data for downstream impact studies. For the Dutch situation in particular, the combination of a North westerly flow on the coast (higher waves) and persistent rain in the catchment area of the river Rhine (high river water levels) is important. The KNMI development of updated climate scenarios is supported by the national programme Knowledge for Climate, in particular the subprogramme "High quality climate projections for adaptation in the Netherlands". This is a cooperation of 12 institutes, each with a different focus: meteorology, water management, ecology, agriculture, spatial planning and air quality. The project covers a whole range of activities: from improving our basic understanding of relevant meteorological processes, to utilisation, and to assessments and communications about the impact of climate change in various sectors of society. The project has work packages dealing with •Regional climate studies and projections of critical meteorological processes (WP1) •Assessment and propagation of uncertainty at various scales (WP2) •Application of climate projections to various sectors (WP3) •Communication of climate and climate change impact to users (WP4)
Assessing floodplain restoration success using soil morphology indicators
Floodplains are complex ecological systems that fulfil different ecological, economic and social functions related to physical, chemical, and biological processes. The fluvial dynamics of most rivers in industrialized countries have been altered to such an extent that floodplains are now one of the most threatened ecosystems worldwide. This adverse impact has been widely recognized and, nowadays, extensive attempts are underway to return rivers to more natural conditions and restore their ecological quality and essential ecosystem functions. As a consequence, the number of restoration projects worldwide is rapidly increasing. However, despite an estimated global cost of more than 1 billion dollars annually, there is a crucial lack of monitoring and quantitative evaluations. Indeed, most projects are never monitored post-restoration (NRC 1992). In Switzerland, only 35% of the projects include a monitoring program mainly based on flora and fauna (BAFU). The design, selection and optimization of indicators for project monitoring are of major importance for sustainable management of riverine ecosystems. However, despite the growing body of literature on potential indicators and criteria for assessing the success of restoration projects no standardised or generally applicable method exists. Furthermore, soils are rarely considered among the possible indicators despite their crucial roles in ecosystems such as decomposition, supplying resources (habitats, gene pool, biomass, and raw materials), and environmental interactions (storage, filtering, transformation). We therefore hypothesized that soils may constitute an appropriate synthetic and functional indicator for the evaluation of river restoration success, especially in the framework of river widening aiming to increase the terrestrial biodiversity. In agreement with the current concepts of river restoration, we propose an assessment tool for floodplain restoration based on three soil morphology criteria (soil diversity, soil typicality, and soil dynamism) and their associated indicators (for example soil Shannon indexes, frequency of soils with specific characteristics, elevation variations due to the fluvial dynamic). The success of floodplain restoration is assessed through comparisons of these criteria between the restored river sector and a reference that could be a near natural floodplain or an embanked floodplain. As a test case, we used a near natural floodplain along the Rhine River as reference site. We then assessed the performance of the method by assessing how well the selected indicators explained a data set of soil physico-chemical characteristics in a principal component analysis. We applied this pedological tool to assess the efficiency of two rivers widening: the Thur (River Thur, CCES project RECORD: http://www.swiss-experiment.ch/index.php/Record:Home), and the Emme River restorations (http://www.bve.be.ch/site/bve_tba_dok_down_wasserbau_emme.pdf). In agreement with other studies, our results confirmed that these restoration projects were partial success. This study demonstrated that soil morphology presents multiple advantages as an indicator of floodplain restoration: ease of use, spatial delimitation of the floodplain, information on past events and fluvial dynamic, and different spatial levels of observation (topsoil horizons, deep horizons, and complete soil profiles).
Large scale groundwater modeling using globally available datasets: A test for the Rhine-Meuse basin
Groundwater resources are vulnerable to global climate change and population growth. Therefore, monitoring and predicting groundwater change over large areas is imperative. However, large-scale groundwater models, especially those involve aquifers and basins of multiple countries, are still rare due to a lack of hydro-geological data. Such data may be widely available in developed countries but are seldom available in other parts of the world. In this study, we propose a novel approach to construct large-scale groundwater models by using global datasets that are readily available. As the test-bed, we choose the combined Rhine-Meuse basin (total area: ± 220000 km2) that contains ample data (e.g. groundwater head data) that can be used to verify the model output. However, while constructing the model, we use only globally available datasets such as the global GLCC land cover map [http://edc2.usgs.gov/glcc/glcc.php], global FAO soil map [1995], global lithological map of Dürr et al [2005], HydroSHEDS digital elevation map [Lehner et al, 2008], and global climatological datasets (e.g. the global CRU datasets [Mitchell and Jones, 2005 and New et al, 2002], ERA40 re-analysis data [Uppala et al, 2005], and ECMWF operational archive data [http://www.ecmwf.int/products/data/operational_system]). We started by building a distributed land surface model (1×1 km) to estimate groundwater recharge and river discharge. Then, a MODFLOW transient groundwater model is built and forced by the recharge and surface water levels calculated by the land surface model. We run the models for the period 1970-2008. The current results are promising. The simulated river discharges compare well to the discharge observation as indicated by the Nash-Sutcliffe model efficiency coefficients (68% for Rhine and 50% for Meuse). Moreover, the MODFLOW model can converge with realistic aquifer properties (i.e. transmissivities and storage coefficients) and can produce reasonable groundwater head spatial distribution that reflects the positions of major groundwater bodies and rivers in the basin. Subsequently, we compare the spatio-temporal pattern of the calculated groundwater head to the soil moisture products from AMSR-E and ERS/METOP. However, the resolution of soil moisture fields (25 km) is too coarse compared to our model resolution (1 km). For this reason, we use several 1 km MODIS products (e.g. land surface temperature, leaf area, and vegetation indices) to downscale the soil moisture fields. From the downscaled soil moisture fields, particularly during the dry summer, we distinguish wet areas that are associated with shallow groundwater table occurrence. These are compared to the groundwater head calculated by the groundwater model. Based on this comparison, model fallacies are identified and turned to improve the model. We argue that the combination of groundwater modeling and remote sensing may enable groundwater assessment in data-poor environments.
Conversion of grassland to arable land often causes enhanced nitrous oxide (N2O) emissions to the atmosphere. This is due to the tillage of the sward and subsequent decomposition of organic matter. Prediction of such effects is uncertain so far because emissions may differ depending on site and soil conditions. The processes of N2O turnover (nitrification, production by bacterial or fungal denitrifiers, bacterial reduction to N2) are difficult to identify, however. Isotopologue signatures of N2O such as ?18O, average ?15N (?15Nbulk) and 15N site preference (SP = difference in ?15N between the central and peripheral N positions of the asymmetric N2O molecule) can be used to characterize N2O turnover processes using the known ranges of isotope effects of the various N2O pathways. We aim to evaluate the impact of grassland-to-field-conversion on N2O fluxes and the governing processes using isotopic signatures of emitted N2O. At two sites, in Kleve (North Rhine-Westphalia, Germany, conventional farming) and Trenthorst (Schleswig-Holstein, Germany, organic farming), a four times replicated plot experiment with (i) mechanical conversion (ploughing, maize), (ii) chemical conversion (broadband herbicide, maize per direct seed) and (iii) continuous grassland as reference was started in April 2010. In Trenthorst we additionally established a (iv) field with continuous maize cultivation as further reference. Over a period of two years, mineral nitrogen (Nmin) content was measured weekly on soil samples taken from 0-10 cm and 10-30 cm depth. Soil water content and N2O emissions were measured weekly as well. Gas samples were collected using a closed chamber system. Isotope ratio mass spectrometry was carried out on gas samples from selected high flux events to determine ?18O, ?15Nbulk and SP of N2O. ?18O and SP of N2O exhibited a relatively large range (32 to 72 ‰ and 6 to 34 ‰, respectively) indicating highly variable process dynamics. The data-set is grouped according to conditions favouring nitrification (low soil water content, high NH4-N content) or denitrification (high soil water content, high NO3-N content, high availability of organic C after tillage of the sward). Isotopologue patterns are compared to known isotope effects of possible turnover processes. This is to verify if the data-set is promising to further constrain N2O processes by process-based isotope fractionation modelling.
Analysis of near surface CO{sub 2} variability within the urban area of Essen, Germany
Carbon dioxide is one greenhouse gas, which is responsible for the anthropogenic induced climate change. Above all, urban agglomerations like the German 'Ruhrgebiet' are a potential CO{sub 2}-source due to the usage of fossil energy sources. For example, in the city of Essen, Germany (North Rhine-Westphalia; 51 28'N, 7 0'E; 580,000 inhabitants; area = 210 km{sup 2}) the urban carbon dioxide was determined by taking 50 survey tests with the aid of the mobile laboratory from the Dept. of Applied Climatology, University of Duisburg-Essen, Campus Essen, Germany. These measurements were taken along a route of 63 kilometers. The purpose of this study was to analyze the relationship between urban CO{sub 2} concentration levels and temporal variables (e.g., air temperature, atmospheric stability) and invariable influencing factors (e.g., surface configuration) within the urban canopy layer. The results are based on a one-year period of data collection (December 2002-November 2003) with additional data collection in 2004 and 2005. This study proves how the urban CO{sub 2} concentration is influenced by spatial variations as well as diurnal and seasonal meteorological conditions. Thus, approximately more than 70 % of the near surface urban CO{sub 2} is mostly affected by traffic density and atmospheric stability. In addition, it is proven that CO and NO can help to verify the dependence on CO{sub 2} of the traffic density. Thus, the appearance of CO{sub 2} shows a close interdependence between CO (R{sup 2}{sub day} {sub time}= 0.57) and NO (R{sup 2}{sub day} {sub time}= 0.69). Other factors that were identified and analyzed include air temperature (9 %), relative humidity (6 %), the urban vegetation (5 %), or the surface configuration (4 %). However, these factors contributed only slightly in terms of explaining the impact of diurnal or seasonal urban CO{sub 2} pattern. Hence, it is clear that there should be mobile survey tests for at least one year while considering the urban types of land use. Otherwise, it is not possible to represent the seasonal and spatial variations of the near surface urban CO{sub 2}. (orig.)
Summary 1. River systems offer special environments for the dispersal of aquatic plants because of the unidirectional (downstream) flow and linear arrangement of suitable habitats. 2. To examine the effect of this flow on microevolutionary processes in the unbranched bur-reed (Sparganium emersum) we studied the genetic variation within and among nine (sub)populations along a 103 km stretch of the Niers River (Germany-The Netherlands), using amplified fragment length polymorphisms. 3. Genetic diversity in S. emersum populations increased significantly downstream, suggesting an effect of flow on the pattern of intrapopulation genetic diversity. 4. Gene flow in the Niers River is asymmetrically bidirectional, with gene flow being approximately 3.5 times higher in a downstream direction. The o...
A probabilistic finite element analysis of embankment stability under transient seepage conditions
Flood protection structures lend themselves to probabilistic design given the large uncertain variables. Taking into account the historical discharge statistics of rivers, the annual probability of failure by slope instability of an embankment along the river Elbe in Eastern Germany is determined using a finite element analysis. The effect of transient seepage within the embankment and its effect on embankment stability are considered. Whereas a steady-state seepage line is most critical for the embankment stability, a transient seepage calculation including the rise and drop of the river water level reveals stability reserves. It has been demonstrated that the First-Order Reliability Method with Adaptive Response Surface is an efficient calculation technique for coupling numerical simulat...
Abstract In December 2008, the draft programmes of measures (PoM) have been published in the EU member states, which list the measures that will be taken to enhance the ecological status of surface and groundwater bodies, and to reach the environmental objectives of the EU-Water Framework Directive (WFD). We have analysed the German PoM to identify the main pressures and the restoration measures water managers planned to implement in streams and rivers. The objective was to evaluate the PoM and to identify the main, practically relevant knowledge gaps in river management on which applied river research should focus on. In general, the selection of measures in the PoM was reasonable. In accordance with the analysis of pressures and impacts in Germany, the PoM focussed on measures addressing...
Mercury concentrations have been analysed in bream (Abramis brama L.) and zebra mussels (Dreissena polymorpha) collected at 17 freshwater sites in Germany from 1993-2009 and 1994-2009, respectively, within the German Environmental Specimen programme. Mercury concentrations in bream ranged from 21 to 881ngg-1 wet weight with lowest concentrations found at the reference site Lake Belau and highest in fish from the river Elbe and its tributaries. Statistical analysis revealed site-specific differences and significant decreasing temporal trends in mercury concentrations at most of the sampling sites. The decrease in mercury levels in bream was most pronounced in fish from the river Elbe and its tributary Mulde, while in fish from the river Saale mercury levels increased. Temporal trends seem t...
Large parts of the tidal estuary of river Elbe (Germany) are characterized by regular patterns of sand dunes. They evolve due to complex sand transport mechanisms and show multi-faceted migration patterns, which are influenced by hydrodynamic boundary conditions such as runoff and tidal forces. This study aims at increasing the understanding of the way hydrodynamic boundary conditions influence dune behavior. This is the basis of an effective sediment management as well as an important requirement for planning offshore structures. From a unique data set of up to six annual bathymetrical multibeam soundings between 1995 and 2010, bedform characteristics and migration rates were processed and analyzed with a set of automated methods. The influence of river runoff, water levels, current velocities, tidal range, and river depth on characteristics and migration were tested statistically. The results show that migration is mainly dominated by the incoming flood tide while rates and directions depend on the amount of runoff originating from the inland catchment.
Treatment of chlorobenzene-contaminated groundwater in a pilot-scale constructed wetland
At industrial megasites worldwide, the natural seepage of contaminated groundwater from surface-near layers into rivers and river floodplains may give rise to serious environmental hazards. To prevent adverse effects on the environment, affordable and energy-efficient treatment methods for these sites are required. Large-scale constructed wetlands (CW) may represent a promising approach to protect river catchment areas. A pilot-scale horizontal subsurface flow CW planted with Phragmites australis and an unplanted reference plot were investigated for the removal of monochlorobenzene (MCB), 1,4-dichlorobenzene (1,4-DBC) and 1,2-dichlorobenzene (1,2-DCB) from polluted groundwater in Bitterfeld (Germany). At inflow concentrations of 20mgL-1 MCB, 0.19mgL-1 1,2-DCB and 0.25mgL-1 1,4-DCB, the pla...
Monitoring terbutryn pollution in small rivers of Hesse, Germany.
Four small river systems in Hesse, Germany, were investigated with respect to seasonal and spatial concentrations of the herbicide terbutryn [2-(t-butylamino)-4-(ethylamino)-6-(methylthio)-s-triazine]. Despite introduction of a ban on its use as a herbicide in July 2003, terbutryn was still present in the rivers during the whole sampling period from September 2003 to September 2006, and there was no trend of decreasing concentration during this time. In the Weschnitz and Modau river systems the mean terbutryn concentration exceeded the German drinking water ordinance threshold value for single biocides. Maximum concentrations of up to 5.6 microg l(-1) were determined in the Weschnitz River. Higher terbutryn concentrations in summer are suggested to originate from agricultural sources, as well as from sediment redissolution. Effluents of two sewage treatment plants had high terbutryn concentrations, indicating that terbutryn enters the rivers from this source. Sources other than agriculture must explain terbutryn occurrence in the rivers during winter, when farm pesticide application typically ceases. The potential for mobilization of terbutryn from sediments and leaching from soils are discussed. PMID:18049772
River runoff estimates based on remotely sensed surface velocities
One promising technique for river runoff estimates from space is the retrieval of surface currents on the basis of synthetic aperture radar along-track interferometry (ATI). The German satellite TerraSAR-X, which was launched in June 2007, will permit ATI measurements in an experimental mode. Based on numerical simulations, we present findings of a research project in which the potential of satellite measurements of various parameters with different temporal and spatial sampling characteristics is evaluated. A sampling strategy for river runoff estimates is developed. We address the achievable accuracy and limitations of such estimates for different local flow conditions at selected test site. High-resolution three-dimensional current fields in the Elbe river (Germany) from a numerical model are used as reference data set and input for simulations of a variety of possible measuring and data interpretation strategies to be evaluated. Addressing the problem of aliasing we removed tidal signals from the sampling data. Discharge estimates on the basis of measured surface current fields and river widths from TerraSAR-X are successfully simulated. The differences of the resulted net discharge estimate are between 30-55% for a required continuously observation period of one year. We discuss the applicability of the measuring strategies to a number of major rivers. Further we show results of runoff estimates by the retrieval of surface current fields by real TerraSAR-X ATI data (AS mode) for the Elbe river study area.
4th international renewable energy storage conference (IRES 2009)
Within the 4th International Renewable Energy Storage Conference of The European Association for Renewable Energy (Bonn, Federal Republic of Germany) and The World Council for Renewable Energy (Bonn, Federal Republic of Germany) between 24th and 25 November, 2009, in Berlin (Federal Republic of Germany), the following lectures were held: (1) The World Wind Energy Association (A. Kane); (2) The contribution of wind power to the energy supply of tomorrow (H. Albers); (3) Intelligent energy systems for the integration of renewable energies (A.-C. Agricola); (4) 100% Renewable energies: From fossil baseload plants to renewable plants for basic supply (M. Willenbacher); (5) High-performance Li-ion technology for stationary and mobile applications (A. Gutsch); (6) Energy storage in geological underground - Competition of use at storage formations (L. Dietrich); (7) E-mobility concepts for model region ''Rhein-Ruhr'' in North Rhine Westphalia (G.-U. Funk); (8) Photovoltaic energy storage for a better energy management in residential buildings (S. Pincemin); (9) Self-consuming photovoltaic energy in Germany - Impact on energy flows, business cases, and the distribution grid (M. Braun); (10) Local energy systems -optimized for local consumption of self-produced electricity (B. Wille-Haussmann); (11) Assessing the economics of distributed storage systems at the end consumer level (K.-H. Ahlert); (12) A new transportation system for heat on a wide temperature range (S. Gschwander); (13) Latent heat storage media for cooling applications (C. Doetsch); (14) Numerical and experimental analysis of latent heat storage systems for mobile application (F. Roesler); (15) CO{sub 2}-free heat supply from waste heat (H.-W. Etzkorn); (16) Stationary Li-Ion-technology applications for dispatchable power (C. Kolligs); (17) Redox-flow batteries - Electric storage systems for renewable energy (T. Smolinka); (18) Energy storage by means of flywheels (H. Kielsein); (19) Renewable power (to) methane solution for renewable power integration and energy storage (M. Sterner); (20) Multi-source energy storage system integrated in buildings (MESSIB) (J. Gravalos); (21) Heat storage technologies for buildings with high solar fractions (H.Kerskes); (22) Solar combisystems and storage: The way to achieve high solar fraction (G. Tanguy); (23) LCA of 100% solar fraction thermal supply to a Swiss apartment building using water-based sensible heat storage (A. Simons); (24) WKSP Evaluation and optimisation of UTES systems of energy efficient office buildings (M.N. Fisch); (25) High-temperature storage for solar tower power plants (S. Zunft); (25) The power matching city field test (R. Kamphuis); (26) Smart energy storage: The sol-ion project (M. Lippert); (27) Wind diesel hybrid systems, engines to support wind power (C. Dommermuth); (28) BYD Energy storage system (C. Beck); (29) Zebra battery (M. Vona); (30) Grid-connected storage systems workshop (P. Malbranche); (31) Testing grid connected storage systems (M. Perrin); (32) Electrical storage applications and characteristics (P. Noegaard).
Latent heat fluxes and TKE dissipation rates over complex terrain from airborne lidar observations
The combination of a water vapour and a wind lidar on an aircraft is an interesting new tool that allows to measure latent heat flux profiles and the small- to mesoscale variability beneath the aircraft along the flight track. During the Convective and Orographically-induced Precipitation Study (COPS) in July 2007 over the Black Forest low-mountains in south-west Germany, a differential absorption lidar (DIAL) and a Doppler wind lidar were collocated nadir-viewing onboard the DLR Falcon research aircraft. One of the main goals was to measure the vertical humidity transport within the convective boundary layer (CBL) over the Rhine valley and the Black Forest on days when deep convection was expected to be mainly forced by the local orography and surface humidity. From the remotely-sensed wind and water vapour fluctuations at multiple heights within the CBL, a representative latent heat flux profile can be obtained from a single over-flight of the area under investigation using the eddy-correlation technique. The lidars' horizontal and vertical resolution is 200 m, which is just sufficient to resolve the dominant contributions to the flux, as parallel higher-resolved in-situ measurements by another research aircraft show. The flights were performed early enough, around noon, in order to avoid too many clouds that obstruct the lidar measurements. However, scattered fair-weather cumuli, as well as the presence of instrumental noise in the lidar signals do not significantly hinder the flux retrieval, as the comparisons with the in-situ measurements demonstrated. The presentation will highlight methodical advances, accuracy assessments, validations by the collocated in-situ aircraft measurements over the mountains, as well as the study of a post-frontal situation in which the latent heat flux played a key role in humidifying the boundary layer. On this exemplary day, 30. July 2007, the lidar-derived latent heat fluxes in the CBL over the mountains vary between 100 - 500 W/m2 on parallel flight tracks but are roughly constant with height. The observed positive fluxes moisten the growing CBL by upward transport of humidity from surface evaporation due to previous days' rain. However, they were probably too low to generate the deep convection predicted on that particular day. Fourier spectra of the wind lidar's vertical velocity measurements in the mid-CBL enable to estimate the dissipation rate of turbulent kinetic energy (TKE) following the Kolmogorov-Obukhov empirical relationship in the inertial subrange. It amounts to 5•10-4 m2 s-3 in the Rhine Valley between 400 and 1200 m height above ground, using a Kolmogorov constant of 0.55, valid for one-dimensional velocity spectra. This is in accordance with the mid-CBL results of the in-situ vertical velocity spectra in the valley. Over the mountains, the in-situ spectra show higher levels, as expected due to higher TKE, and bring dissipation rates of up to 10-3 m2 s-3.
The Timing of Oceanic Mantle Depletion
The oceanic mantle was depleted by the extraction of the continental crust. But when did this depletion take place? There is growing evidence that the continental crust grew primarily in a few pulses, at 1.2, 1.9 and 2.7 Ga. If so, the implication is that the oceanic mantle was depleted episodicall. The episodic depletion model is supported by new laser-ablation analysis of Os isotopes in ophiolite-derived platinum group alloy grains (PGA) from the Rhine river and the Philippines. The data indicate the oceanic mantle contains highly depleted harzburgite that was largely produced during the last major crustal growth episode around 1.2 Ga. This corroborates previous studies of Os isotopes in PGA and bulk peridotites that indicate a 1.2 Ga age peak in the oceanic mantle. Many ophiolite and abyssal peridotite suites show a correlation between extent of melt depletion and bulk sample Re-depletion age (TRD) that can be modeled as mixing between mantle with a TRD of ~1.2 Ga with modern basalts. The implication is that a significant component of the oceanic mantle is depleted and ancient, and that lherzolite may primarily be the result of refertilization of harzburgite by basalt melts. Direct evidence for this model is provided by harzburgites dredged from areas of the Gakkel ridge where no modern melting is occurring. These harzburgites have both Os and Hf isotopic data suggesting melting ages around 1.2 Ga for the most depleted samples [1,2]. Analysis of thousands of PGA derived from the mantle sections of ophiolites worldwide corroborates the episodic model implied by the whole rock data. Our new data on Rhine river and Philippines samples are consistent with our previous results from California/Oregon, Tasmania, Tibet and the Urals [3]. All six PGA suites have two peaks in their distribution of TRD. One peak varies with the age of the ophiolite itself and tracks the Os isotopic evolution of the mantle, and a second peak at 1.2 Ga, the same age seen in the whole rock data. The first peak is interpreted to reflect mixing in the mantle. The uniformity of the secondary 1.2 Ga age peak and its global occurrence indicates a major mantle depletion event at that time. The apparent mantle depletion event at 1.2 Ga corresponds closely to the age of the last apparent crustal growth peak and is also the age of assembly of the Rhodinian super-continent. This correlation implies crustal growth was episodic, and by extension, so was the depletion of the oceanic mantle. The abundance of PGA with TRD over 1.2 Ga decreases rapidly with age, implying either 1) that the timescale of heterogeneity destruction in the mantle is between 1 and 2 Ga or 2) that the melting event at 1.2 Ga overprinted existing depleted heterogeneities. A strong test of this model would be to analyze PGA from ophiolites with ages of 1.3-2.6 Ga, to look for the 1.9 and 2.7 Ga peaks in mantle that predates the 1.2 Ga melting event, but to date, such samples have not been found.
The European Water Framework Directive: Challenges For A New Type of Social and Policy Analysis
Water resources managment is facing increasing uncertainties in all areas. Socio- economic boundary conditions change quickly and require more flexible management strategies. Climate change, for example results in an increase in uncertainties, in par- ticular extreme events. Given the fact that current management practices deal with extreme events by designing the technical systems to manage the most extreme of all cases (e.g. higher dams for the protection against extreme floods, larger water reser- voirs for droughts and to meet daily peak demand) a serious problem is posed for long-term planning and risk management. Engineering planning has perceived the hu- man dimension as exogenous boundary conditions. Legislation focused largely on the environmental and technological dimensions that set limits and prescribe new tech- nologies without taking the importance of institutional change into account. However, technology is only the "hardware" and it is becoming increasingly obvious that the "software", the social dimension, has to become part of planning and management processes. Hence, the inclusion of the human dimension into integrated models and processes will be valuable in supporting the introduction of new elements into plan- ning processes in water resources management. With the European Water Framework Directive environmental policy enters a new era. The traditional approach to solving isolated environmental problems with technological fixes and end-of-pipe solutions has started to shift towards a more thoughtful attitude which involves the development of integrated approaches to problem solving. The WFD introduces the river basin as the management unit, thus following the experience of some European countries (e.g. France) and the example of the management of some international rivers (e.g. the Rhine). Overall the WFD represents a general shift towards a polycentric understand- ing of policy making that requires the involvement of stakeholders as active partic- ipants into the policy process at different levels of societal organization. The WFD requires the inclusion of stakeholders in the process of developing and adopting a river basin management plan. In order to improve stakeholder-based policy design and modeling processes innovation and research is required in linking analytical methods and participatory approaches. Factual knowledge and analytical techniques have to be combined with local knowledge and subjective perceptions of the various stakeholder groups. The talk will summarize current approaches and point out research needs.
The onset of downstream migration of European eels is accompanied by a cessation of feeding and the start of sexual maturation which stresses the link between metabolism and sexual maturation, also suggesting an important role for exercise. Exercise has been tested with eels in swim tunnels and was found to stimulate the onset of sexual maturation. In this study, we have investigated the interplay between migration and maturation in the field during the downstream migration of female silver eels. Temporal changes in migratory status and sexual maturation among silver eels of the upstream Rhine River system over 3 months of the migration season (August, September and October) were determined in biometrical parameters, plasma 17?-estradiol and calcium levels, oocyte histology and gonadal fat levels. Furthermore, the ecological relevant parameters age as determined by otolithometry and health aspects indicated by haematocrit, haemoglobin and swim-bladder parasite load were measured. Silver eels were estimated to be 14 years old. A strong temporal progression in migratory stage was shown over the months of downstream migration. Catches probably represented a mix of reproductive migrants and feeding migrants of which the ratio increased over time. Furthermore, this study confirmed our hypothesis linking the migratory stage to early maturation as indicated by enlargement of the eyes, oocyte growth and fat deposition in the oocytes, exactly the same changes as found induced by exercise but not ruling out environmental influences. Migrants show extensive fat uptake by the oocytes, probably stimulated by the swimming exercise. In addition, at least 83% of the silver eels in this spawning run may have suffered from negative effects of swim-bladder parasites on their swimming performance. PMID:21556699
The burbot, Lota lota, is the only freshwater species of the codfish family and has a Holarctic distribution. Pleistocene glaciations caused significant geographical differentiation in the past, but its life history characterized by winter spawning migrations over large distances is likely to homogenize populations by contemporary gene flow. We investigated the population genetic structure of 541 burbots from Lake Constance and adjacent Rhine and Danube tributaries in Europe using the entire mitochondrial DNA (mtDNA) control region and 11 microsatellites. Microsatellites revealed considerable population divergence (F(ST) = 0.26) and evidenced recent bottlenecks in two Central European rivers. In accordance to previous evidence two main phylogeographic lineages (Atlantic and Danubian) were found co-occurring at similar frequencies in Lake Constance, where they currently undergo random mating as indicated by microsatellites. The Danubian lineage contributed only a small proportion to the lake's mtDNA diversity, and probably expanded within the lake shortly after its formation approximately 10,000-15,000 BP. The larger Atlantic haplotype diversity suggested a population expansion older than the lake itself. Levels of admixture at microsatellite loci were less obvious due to their high variability, and coalescence methods were used to estimate past admixture proportions. Our results reinforce a model of a two-step colonization of Europe by burbot from an ancestral Danubian refuge, and confirm the persistence of a secondary Atlantic refuge, as proposed to exist for other freshwater fish. We conclude that the present-day burbot population in Lake Constance bears the genetic signature of both contemporary gene flow and historical separation events. PMID:17032259
The purpose of the EU water framework directive is to establish a good ecological status for inland surface waters, transition waters, groundwater and coastal waters until 2009. To achieve this goal a program of measures has to be defined in a management plan for each river basin. To date, methodological gaps exist regarding the scientific, economic and legal instruments available to implement the directive in Germany. The main aim of the project is to develop a decision support system for integrated river basin management based on a computer modelling system. Study area is the meso-scale river basin of the Weiße Elster river, flowing through three states, Thuringia, Saxony and Saxony-Anhalt. Currently, river basins in Germany are managed on a state level. Research is carried out in close cooperation with local authorities. In the context of the EU water framework directive scientific, economic, and legal methods and approaches will be coupled and developed further. The core of the decision support system is an object-oriented modelling system coupled with a multi-criteria analysis. The modelling system integrates water and substance transport as well as socio-economic forecasting models and methods. The system will be able to simulate and assess the scientific, economic and social effects of management measures. The results as well as interests of concerned stakeholders will be joined and evaluated in a subsequent multi-criteria analysis. Based on these results for decision support, programs of measures recognising interests of water management, industry, agriculture, politics and the public can be established in the management plans of the respective authorities.
Revising time series of the Elbe river discharge for flood frequency determination at gauge Dresden
The German research programme RIsk MAnagment of eXtreme flood events has accomplished the improvement of regional hazard assessment for the large rivers in Germany. Here we focused on the Elbe river at its gauge Dresden, which belongs to the oldest gauges in Europe with officially available daily discharge time series beginning on 1 January 1890. The project on the one hand aimed to extend and to revise the existing time series, and on the other hand to examine the variability of the Elbe river discharge conditions on a greater time scale. Therefore one major task were the historical searches and the examination of the retrieved documents and the contained information. After analysing this information the development of the river course and the discharge conditions were discussed. Using the provided knowledge, in an other subproject, a historical hydraulic model was established. Its results then again were used here. A further purpose was the determining of flood frequency based on all pre-processed data. The obtained knowledge about historical changes was also used to get an idea about possible future variations under climate change conditions. Especially variations in the runoff characteristic of the Elbe river over the course of the year were analysed. It succeeded to obtain a much longer discharge time series which contain fewer errors and uncertainties. Hence an optimized regional hazard assessment was realised.
Aquatic hyphomycete communities as potential bioindicators for assessing anthropogenic stress
With a profound knowledge of how physico-chemical parameters affect these communities, microbial communities could be used as indicators for environmental changes and for risk assessment studies. We studied aquatic hyphomycete communities in rivers and aquifers from sites shaped by intense mining activities (namely the ?Mansfeld region??) and chemical industry (cities of Halle and Bitterfeld) in Central Germany. Environmental stress factors such as high concentrations of heavy metals, sulphate, and nitrate as well as low concentrations of oxygen significantly reduced the diversity and biomass of hyphomycetes in the investigated samples. Redundancy analysis (RDA) indicates that variations in water chemistry cause a significant proportion of the change in fungal community structure (86.2%). ...
The role of habitat disturbance on biodiversity is central as it promotes changes in ecological systems. That said, still little is known about the functional consequences of such changes. Functional diversity can be used to revealing more mechanistically the disturbance effects on communities by considering the richness and the distribution of traits among the species. Here we analyzed the response of functional and species diversity of ground beetles to flood disturbance to better understand the functioning of alluvial invertebrate communities. Ground beetles were sampled in periodically flooded grasslands along the Elbe River in Germany. We used generalized linear mixed effects models to unveil the relationships between flood disturbance, species and functional diversity, respectively. ...
Abstract Question: What are the hydrological requirements for the successful reforestation of riparian Salix communities? Do differences in site conditions between various life stages of woody vegetation types need to be considered? Do interactions between hydrological factors influence distribution patterns? Location: Mid-reaches of the Elbe River, Germany. Methods: Young and old life stages of two different riparian Salix communities were surveyed in 1067 plots of 400-m2 to determine hydrological growth conditions using habitat distribution models. Models were extrapolated in a Geographic Information System to quantify the extent of potential stands available for reforestation measures. Results: Average water level and water level fluctuations were related to different vegetation types a...
Fate of pharmaceuticals in rivers: Deriving a benchmark dataset at favorable attenuation conditions.
Pharmaceutical residues are commonly detected organic micropollutants in the aquatic environment. Their actual fate in rivers is still incompletely understood as their elimination is highly substance specific and studies often report contradictory results. To elucidate the ceiling of attenuation rates of pharmaceuticals in rivers we carried out a study at a river with favorable conditions for the elimination of organic micropollutants. Experiments were carried out at a small stream in Germany. Composite samples were taken at both ends of a 12.5 km long river stretch located downstream of a sewage treatment plant and analyzed for 10 pharmaceuticals. Moreover, pore water samples were taken and in situ photolysis experiments at several sites within the river stretch were performed to assess the importance of these individual elimination mechanisms. Pharmaceutical concentration in the surface water at the first sampling site ranged from 3.5 ng L(-1) for propranolol to 1400 ng L(-1) for diclofenac. In comparison to carbamazepine which was used as persistent tracer, all other pharmaceuticals were attenuated along the river stretch. Their elimination was higher in a sunny, dry weather period (period I) compared to a period with elevated discharge after a heavy rainfall (period II). Overall, the measured elimination rates ranged from 25% for sulfamethoxazole (period II) to 70% for propranolol (period I). Photolysis was only a relevant elimination process for diclofenac and potentially also for sotalol; for these compounds phototransformation half-life times of some hours were determined in the unshaded parts of the river. Biotransformation in the sediments was also an important attenuation process since the concentrations of the other pharmaceuticals in the sediments decreased relative to carbamazepine with depth. For the chiral betablocker metoprolol this biotransformation was also confirmed by a decrease in the enantiomer fractionation from 0.49 at site A to 0.43 at site B and to sediments. PMID:22898670
Macrophytes respond to reach-scale river restorations
Summary 1.-In recent years, river restoration science has been searching for biological indicators of improvement in the physical habitats of streams. To date, research has mainly focused on the use of fish and macroinvertebrates as indicators. Despite their importance in aquatic ecosystems, the response of macrophytes to habitat restoration has been rarely studied. 2.-We investigated the macrophyte communities of 40 restored river reaches in the lowland and lower mountainous areas of Germany. Each restored reach was compared to an upstream, unrestored reach using a space-for-time-substitution approach. At each reach, a 100-m stretch was surveyed for submerged and emergent macrophytes, recording the quantity, abundance and growth form of each species. Additionally, microhabitat patterns (s...
A Water Framework Directive pilot project combines measured data and model approaches to calculate fluxes and mass balance of the pesticide bentazone in an 81 km section of the river Main (Germany). During the study period (six weeks in spring 2004) the observed bentazone inflow and outflow in the river section amounted to 52.8 and 53.1 kg, respectively; the maximum concentrations reached 220 and 290 ng l-1. Based on sampling of seven sewage treatment plants a specific loss of 0.87 g bentazone per farm was calculated. Extrapolation to the entire sub-basin results in 2.6 kg bentazone in total as point source contribution from farms. Diffuse input into the surface water network occurred after an intensive rainfall event on May 7th. Total bentazone load was simulated with the pesticide emissi...
Beside damages of infrastructure in industrial regions, extreme floods can cause contamination with particle-bound pollutants, e. g., due to erosion of soils and sediments. In order to predict contamination with inorganic pollutants, the transport and fate of arsenic, lead, and mercury during a fictive flood event of River Vereinigte Mulde in the region of Bitterfeld (Germany) with 200 years recurrence time was modeled. The finite element model system Telemac2D, which is subdivided into a hydrodynamic (Telemac-2D), a transport (Subief-2D), and a water quality module (wq2subief) was applied. The transport and water quality model models were calibrated using results of sediment trap exposures in the floodplain of River Vereinigte Mulde. Model results exhibited that the spatial patterns of pa...
Short-term monitoring of heavy metal concentrations along rivers affords the opportunity to examine the persistence of contaminants in the fluvial environment. This paper examines changes in the concentrations of Cu, Pb, and Zn at near-channel positions along a 75-km reach of the Lahn River, an agrarian watershed in central Germany, between 2000 and 2007. Thirty-three sites sampled in 2000 were re-sampled in 2007 in order to document changes in trace metal contamination. The concentrations of Cu and Pb decreased between 2000 and 2007, whereas the concentration of Zn was statistically unchanged. The Pb concentration decreased at 82% of the sample sites over the study period, whereas Cu concentrations decreased at 70% of the sites. Site-to-site variation in the concentrations of Pb with dist...
Restoration of the Upper Main and Rodach rivers - The success and its measurement
Large-scale restoration of streams and rivers is a mandatory prerequisite for the implementation of the European Water Framework Directive (WFD) to reach good ecological status of water bodies. This contribution analyzes the success of the largest river restoration in Germany at the Upper Main. Sections with a length of more than 18km were restored between 1990 and 2008, including re-connection of former oxbow-lakes, multiple-channelling, and establishment of wide riparian buffer zones. Measuring the success of restoration by means of a multimetric assessment system, we found a clear success of restoration indicated by the status of hydromorphology and by the biological parameters, including macroinvertebrates, fishes, and macrophytes. Unlike non-restored reaches, the restored reaches atta...
Distribution of cadmium among geochemical fractions in floodplain soils of progressing development.
Initial soil development in river floodplains influences soil properties and processes. In this study, suites of young floodplain soils sampled at three European rivers (Danube/Austria, Ebro/Spain and Elbe/Germany) were used to link soil development to the soils' retention capacity for cadmium. Geochemical fractionation of original and metal-spiked soils was conducted. Cadmium remained in weakly bound fractions in both original and spiked soils, representing an entirely different behaviour than observed for copper in an earlier study. The tendency of incorporation into more stable forms over time was only slightly expressed. Correlation analysis revealed the involvement of different sorption surfaces in soil, with no single soil constituent determining cadmium retention behaviour. Nevertheless, in the calcareous soils of the Danube floodplain, we found increased cadmium retention and decreased portions of desorbable cadmium with progressing soil development. PMID:18222578
In Central Europe, floodplain fragmentation by dykes and river regulation by dams has led to a fundamental loss of riparian softwood forests and dramatically restricted natural regeneration of the Salicaceae species involved. As a consequence, reforestation is one of the widely-used measures to maintain this valuable vegetation type. Knowledge about the genetic population structure of existing stands of willows and poplars is necessary to preserve their genetic potential in the long term. In this study, we investigated clonal and genetic diversity patterns of Salix viminalis for 23 stands, taking into account young and old age classes and locations in front of the dykes in the active floodplain and behind the dykes in the inactive floodplain along the Elbe River, Germany. Microsatellites w...
In April/May 1994 during a period of high discharge in the German part of the River Elbe (9 stations) and its main tributaries (3 stations) samples of suspended particulate matter (SPM) have been collected by means of sedimentation chambers with sampling periods of three or four weeks. Subsequent analyses for polychlorinated dibenzodioxins and dibenzofurans (PCDD/F) have shown that the river enters Germany with a rather low PCDD/F-load which almost steadily increases to below Hamburg. Major sources of contamination has been the input by the tributary Mulde and resuspension of contaminated sediments along the riversides. Downstream of Hamburg marine influence have caused a sharp decrease of PCDD/F-contents. Changes in the result of 1989, 1992/93 have been discussed. (orig.)
This paper focuses upon the Pleistocene terraces of the Sarre River, a right bank tributary of the Moselle River (NE France and SW Germany) flowing through the Vosges Massif, the eastern Paris Basin and the Rhenish Massif. Recent research has allowed the recognition of 12 well preserved alluvial terraces (Sa1 youngest to Sa12 oldest) between the present floodplain Sa0 and +120m relative height. The youngest terraces were dated using Optically Stimulated Luminescence (OSL). A first chronological framework was also provided for older terraces by Electron-Spin-Resonance (ESR) dating. The ages range between the end of the Early Pleistocene and the last glacial-interglacial cycle of the Late Pleistocene (ca. 1.1Ma to 50ka). Age ranges are consistent with the terrace elevation and stratigraphy, ...
The European Water Framework Directive (WFD) requires a good chemical and ecological status of water and groundwater resources in the EU member countries by 2015. However, for some river basins, the good status cannot be achieved by 2015, and therefore measures have to be taken to reduce the unacceptably high nutrient input. Therefore, a new approach was developed by using an interdisciplinary model network, consisting of the regionalized agricultural economic model RAUMIS and two hydro(geo)logical models GROWA/WEKU and MONERIS. For the 49,000km^2 Weser river basin, in Germany we: (1) analysed nitrogen surplus on agricultural land for 2003 and nitrogen emissions into ground and surface waters in an area-differentiated manner, (2) quantified the future impact of agro-political measures and ...
Prediction of mixing intensity of water masses in riverine Lake Tegel (Berlin, Germany) can be used to trace the fate of pollutants that enter the lake through several inflows. Because the contributions of each inflow have not yet been quantified and because the lake features complex bathymetry and numerous islands, a hydrodynamic circulation model with high spatial resolution and dynamic wind forcing is useful. We applied the two-dimensional version of the Princeton Ocean Model to separate the influences of wind and river discharge on the currents and mass transport in Lake Tegel. For model validation, we compared the simulation results with 1?year of electrical conductivity data, which was used as a conservative tracer to distinguish between water from the River Havel and water supplied ...
One of the most enigmatic problems in intraplate earthquake geology is the spatio-temporal recurrence pattern of large earthquakes. Intraplate regions such as the New Madrid seismic zone or the central European rift system are subject to considerable seismic hazards, because fault activity is highly disparate in space and time and our knowledge about the recurrence of large earthquakes is still rudimentary. The current debate in central Europe ranges from slip dominated by repeated large coseismic events to slip dominated by aseismic creep. Here, field evidence in support of the former is sparse, and hence, some authors concluded that many faults move by slow aseismic creep rather than by ground rupturing earthquakes. We report new results from a paleoseismic study carried out in the Lower Rhine Embayment across a subsidiary normal fault in the area of Germany's largest historical earthquake (1756 AD, ML 6.2±0.2) that clearly revealed field evidence of dynamic surface faulting. At the trench site, the fault is covered by fractures with aligned and broken clasts extending vertically throughout the entire gravel. Mapping of 237 fractured clasts and the long-axis orientation of ~10.000 clasts defines a deformation zone coinciding with the surface offset and two offset markers within the gravel layers. We interpret these features as the result of coseismic deformation at the near-surface end of the rupture. We rule out alternative processes which may lead to fracturing of pebbles such as freeze-thaw weathering or sediment loading effects, since both the gravel fabric and fracture planes coincide well with the fault orientation. We preclude slow deformation due to aseismic creep as governing process to cause rupturing of pebbles this close to the surface, as this would require an overburden stress of several hundreds of meters according to modelling results (e. g. Eidelmann, 1992, Geology). With a significantly smaller overburden, as in this study, a high differential acceleration force, such as a shock wave produced by an earthquake rupture or a seismic wave would be needed to overcome the pebble's shear resistance. Preliminary radiocarbon data bracket the youngest event horizon to Latest Holocene age. In conclusion, we identified coseismic deformation at the trench site, because special conditions produced a number of features not usually observed in other fault exposures. The thin sedimentary cover (shear strength of the pebbles, may have played an important role in producing this deformation pattern. Our results imply that large surface rupturing earthquakes in low-strain intraplate regions may be more common than previously thought.
High-resolution seismic imaging of near-surface fault structures in the Upper Rhine Graben, Germany
Faults systems are important targets in different fields of exploration geophysics. Recently, exploration is focussed on deep-seated faults systems for hydro-geothermal utilization, where fluid flow may be enhanced compared to the surrounding host rock (fracture dominated aquifers). In fault related exploration, special interest of geothermal research is given to size, shape and age of fault patterns as well as to the geological periods of fault activity, because fluid flow critically depends on those parameters. A well-established way to explore structural architecture of fault systems is the use of 3D reflection seismics. This technique, if applied to targets at several kilometers depth, inevitably leaves a gap in the near-surface domain due economic line spacing. To bridge the gap between target exploration at several kilometers depth (here 2-4 km) and the need to trace structures from the reservoir to the near surface, a study in the Upper Rhine Graben, Germany, was performed to supplement large-scale 3D seismic imaging of fault systems with high-resolution 2D reflection seismics. Here, we present results from three different high-resolution reflection seismic profiles, which were carried out across the projected outcrop of local fault structures. These structures appear in 3D seismic datasets recently acquired for hydro-geothermal exploration, but fade out towards surface. The new shallow seismic sections image Quaternary and Late Tertiary units between approximately 20 m and 1000 m depth. The sedimentary strata are resolved at high-resolution and different fault patterns can be identified therein. At one site, a 300 m wide normal fault zone was observed, while the other site shows a prominent horst structure with bounding faults branching into smaller ones at depth. From these fault images the last geological time of activity could be narrowed. Imaging limitations can be explained by an increasingly high-energy depositional system on one site, preventing unequivocal fault imaging into Quaternary times, or are methodology inherent to a depth of approximately 20 m at the other site, which reveals at least a sub-recent activity of this fault system. In summary, structures are visible and can be deduced from these 2D measurements, which are not apparent in the lower frequency, large-scale 3D datasets. Thus high-resolution 2D measurements are well suited for complementing the missing near-surface information of 3D datasets; the imaging of structural details allows a deeper insight into the architecture and kinematics of fault systems.
Radiation balance over low-lying and mountainous areas in south-west Germany
Surface radiative fluxes play a major role in the energy exchange process between the atmosphere and earth surface and are thus very crucial to climatic processes within the atmospheric boundary layer. Based on four years REKLIP (REgio-KLIma-Project) data set of measured radiative fluxes and additional supporting meteorological variables, the surface radiation regime for selected lowland site (Bremgarten 212m a.s.l.) and mountain sites (Geiersnest at 870m a.s.l.; Feldberg 1489m a.s.l.) in the southern Upper Rhine valley region (south-west Germany) has been reported. Time series of radiative fluxes and surface albedo showed significant inter-site differences. Possible reasons for the observed differences have been made. Downward atmospheric radiation Al at the study sites was parameterised in terms of air temperature, vapour pressure and cloud amount, all of which strongly govern the variation of Al. Effective terrestrial radiation amounted to about 50% of absorbed shortwave radiation at the study sites annually. During clear sky conditions, global solar irradiance Gs constituted about 76.0% of the incident extraterrestrial solar irradiance at Feldberg mountain site but only 68.5% of that at Bremgarten lowland site. Annual cumulative of net radiative flux Rn amounted to 1722MJm-2yr-1 at the lowland site, while that at Geiersnest and Feldberg mountain sites constituted 84% and 73% respectively of the corresponding magnitude for the lowland site. In the same vein, annual mean of radiation efficiency (defined here as Rn/Gs) amounted to 0.32 in Feldberg, 0.37 in Geiersnest and 0.41 in Bremgarten. Consequently the annual available energy, of which net radiative flux is representative, was smaller at the mountain ous sites relative to the lowland site during the study period. Inter-annual variability of net radiative flux, its constituent variables and derivatives at the study sites were generally below 10%, with longwave fluxes showing the lowest fluctuation. This renders the measured data quite suitable for modelling purposes. In winter, mean daily sums of Rn showed a slow rise with cloud amount N at the lowland site but a sharp rise with N at Feldberg mountain site. In summer however, mean daily sums of Rn declined significantly with N as well as Linke turbidity factor at the study sites.
Trend methods for the assessment of effectiveness of reduction measures in the water system
Riverine inputs are highly depending substance-specifically on flow rate and other climatic factors. In order to prevent that climatic influences deteriorate the trend detectability, an appropriate adjustment of the measurement data is necessary. Subject of the research project is therefore a concept for the adjustment and trend analysis of these input data. The basic concept for adjustment and trend analysis of riverine inputs is as follows: After providing monthly or biweekly data, monthly or biweekly adjusted loads are calculated with an adjustment procedure based on a dynamically specified concentration-flow function. Then the annual adjusted load is obtained by averaging the monthly or biweekly adjusted data. In the next step a trend analysis of the annual adjusted load is performed, using the LOESS smoother or the test of Mann-Kendall. Finally a power analysis is performed in order to assess the trend sensitivity of the method. Nine adjustment methods were tested at seven parameters (NO{sub 3}-N, NH{sub 4}-N, P{sub total}, PO{sub 4}-P, Cd, Pb and suspended matter) measured biweekly in the Rhine River (Lobith) and monthly in the Ems River (Herbrum). (orig.) [German] Flussfrachten sind in hohem Masse - je nach Substanz - von der Durchflussrate und anderen klimatischen Faktoren abhaengig, und um zu verhindern, dass klimatische Einfluesse die Nachweisbarkeit von zeitlichen Trends in diesen Eintragsdaten verschlechtern, ist eine Adjustierung der Messdaten erforderlich. Gegenstand des Vorhabens ist daher ein Konzept fuer die Adjustierung und Trendanalyse dieser Eintragsdaten. Das Konzept ist wie folgt strukturiert: Auf der Basis monatlicher oder vierzehntaegiger Messdaten werden monatliche bzw. vierzehntaegige adjustierte Frachten unter Verwendung einer dynamisch angepassten Konzentrations-Durchfluss-Funktion berechnet. Die adjustierte Jahresfracht ergibt sich dann mittels Durchschnittsbildung aus den monatlichen bzw. vierzehntaegigen adjustierten Frachten. Auf Basis dieser Jahreswerte wird schliesslich unter Verwendung des LOESS-Trendschaetzverfahrens eine Trendanalyse durchgefuehrt. Abschliessend wird im Rahmen einer Power-Analyse die Trendsensitivitaet des Verfahrens ueberprueft. Neun Adjustierungsmethoden wurden an sieben Parametern (NO{sub 3}-N, NH{sub 4}-N, P{sub total}, PO{sub 4}-P, Cd, Pb und Schwebstoffkonzentration) getestet, die vierzehntaegig im Rhein bei Lobith und monatlich in der Ems bei Herbrum bestimmt wurden. (orig.)
Within larger ice-free regions of the western Arctic Seas, subject to ongoing trophic cascades induced by past overfishing, as well as to possible future eutrophication of the drainage basins of the Yukon and Mackenzie Rivers, prior very toxic harmful algal blooms (HABs) - first associated with ˜100 human deaths near Sitka, Alaska in 1799 - may soon expand. Blooms of calcareous coccolithophores in the Bering Sea during 1997-1998 were non-toxic harbingers of the subsequent increments of other non-siliceous phytoplankton. But, now saxitoxic dinoflagellates, e.g. Alexandrium tamarense , were instead found by us within the adjacent downstream Chukchi Sea during SBI cruises of 2002 and 2003. A previous complex, coupled biophysical model had been validated earlier by ship-board observations from the Chukchi/Beaufort Seas during the summer of 2002. With inclusion of phosphorus as another chemical state variable to modulate additional competition by recently observed nitrogen-fixers, we now explore here the possible consequences of altered composition of dominant phytoplankton functional groups [diatoms, microflagellates, prymnesiophyte Phaeocystis colonies, coccolithophores, diazotrophs, and dinoflagellates] in relation to increases of the toxic A. tamarense , responding to relaxation of grazing pressure by herbivores north of Bering Strait as part of a continuing trophic cascade. Model formulation was guided by validation observations obtained during 2002-2004 from: cruises of the SBI, CHINARE, and CASES programs; moored arrays in Bering Strait; other RUSALCA cruises around Wrangel Island; and SBI helicopter surveys of the shelf-break regions of the Arctic basin. Our year-long model scenarios during 2002-2003 indicate that post bloom silica-limitation of diatoms, after smaller simulated spring grazing losses, led to subsequent competitive advantages in summer for the coccolithophores, dinoflagellates, and diazotrophs. Immediate top-down control is exerted by imposed grazing pressures of the model's herbivores and bottom-up control is also effected by light-, nitrate-, ammonium-, silicate-, and phosphate-modulated competition among the six functional groups of the simulated phytoplankton community. Similar to the history of the southern North Sea adjacent to the Rhine River, possible farming of northwestern Alaska and Canada, in conjunction with other human activities of ice retreat and overfishing, may lead to future exacerbations of poisonous phytoplankton. These potential killers include both toxic dinoflagellate and diazotroph HABs, deadly to terrestrial and marine mammals, as well as those of prymnesiophytes, some of which have already foamed beaches, while others have killed fishes of European waters.
According to international agreements, encouraging all partners to diminish the emission of priority pollutants into North- and Baltic Sea significantly within a time period of 1985 to 2000, the aim of this project was to quantify the changes in the emission situation for both heavy metals and lindane within the mentioned period To reach this aim the total emissions of heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, Zn) and the pesticide lindane ({gamma}-HCH) into German river systems were quantified for the periods of 1983-1985, 1993-1995 and 1999/2000. For the quantification of the emissions via point sources a nation-wide survey on heavy metal data of municipal wastewater treatment plants and industrial direct discharges was carried out. The input via diffuse pathways was calculated using an adapted version of the model MONERIS. This model accounts for the significant transport processes, and it includes a geographical information system (GIS) that provides digital maps as well as extensive statistical information. For a comparison of the calculated heavy metal emission with the measured heavy metal load at monitoring stations the losses of heavy metals due to retention processes within the river systems have to be considered. Therefore heavy metal retention was calculated according to the retention function given by Vink/Behrendt (2002). For the large river basins a good correspondence could be found between estimated and measured heavy metal loads in rivers. The total emission into the German river basins decreased for each metal during the period of 1985 to 2000. The reduction varies between 36 and 85% mainly caused by the decline of emissions via point sources. Today's emissions of heavy metals into river basins of Germany are dominated by the input via diffuse pathways. The most important diffuse pathways are paved urban areas (Cd, Cu, Hg, Pb, Zn), erosion (Pb, Cr) and groundwater (As, Ni). Since the application of the pesticide lindane is illegal today a reduction of lindane input of 67% was achieved for Germany within the period of 1985-1999/2000. Nevertheless there are significant emissions of lindane via diffuse pathways into German river systems due to the persistence of lindane in the environment. (orig.)
Coupled water and heat transport modelling to evaluate reach scale hyporheic exchange fluxes
Surface waters and groundwater are the interconnected hydrological main parts of stream catchments. They are coupled by variable water, solute and heat exchange processes through streambed sediments. The spatial and temporal variability of these exchange processes depend on the heterogeneity of hydraulic and thermal streambed properties and the interplay between stream and groundwater hydraulic conditions. Better understanding these processes facilitates the research on biogeochemical and ecological processes at the direct interface between river and aquifer (hyporheic zone) and their effects on ecosystem functioning in natural and human impacted water resources. Besides intense experimental investigations, simulation models are used to advance the process understanding and to develop predictive capability of such coupled hydrological systems. The aim of this study is the development of a 3-D, coupled water flux and heat transport model of an exemplary lowland river using the control-volume finite element model HydroGeoSphere to quantify heat exchange fluxes. HydroGeoSphere is a fully-integrated surface-subsurface flow and transport model including fully-integrated thermal energy transport. We will use river head and hyporheic temperature measurements to calibrate the numerical, process based model. Subsequent transient simulations based on an experimental data set will highlight the advantages of using HydroGeoSphere for identifying the complex water and heat flux patterns in natural systems. Field data were collected at an experimental river reach of about 100 m at the Selke River, which is a lowland gravel bed river in Germany, characterized by distinctive pool riffle sequences. Time series of hydraulic heads and temperatures were measured at different depth in the river bank and within the river. For the hyporheic zone temperature survey multi-level temperature lances, measuring surface water temperature and streambed temperatures at 7 different depths, up to 0.6 m deep, were permanently installed along the pool riffle sequences and within flat parts of the river channel. River exchange was furthermore investigated by active heat tracer experiments using heat pulse injection. The spatial variability of hydraulic conductivity of the streambed sediments will be estimated by Sequential Gaussian Simulation based on the evaluation of scattered slug tests. The results of the 3-D numerical model will clarify the spatial and temporal behavior of the surface water groundwater exchange flux and distinctive temperature patterns at the experimental site. The evaluation will highlight the benefit of coupled water and heat transport modelling to evaluate the spatial and temporal variability of reach scale hyporheic water and heat exchange fluxes.
The Government of the Netherlands requested an independent Committee of State (the Delta Committee) to give its advice on flood protection and flood risk management in the Netherlands for the next century, while keeping the country an attractive place to live, work and invest. Large parts of the Netherlands lie below sea level and are even now experiencing the effects of climate change and sea level rise. The Netherlands delta is safe, but preserving this safety over the long term involves action now. The Netherlands is the delta (with a coastline of approximately 350 kilometers long) where major European rivers like the Rhine and the Meuse flow into the North Sea. Problems occur where the rivers meet the sea if the rivers have to discharge more water while the sea level rises - both effects of climate change. The excess water in the rivers cannot flow into the sea when the sea level rises, leading to a drastically increased risk of flooding in large areas of the Netherlands. These regions lie along the coast and the rivers and are protected by dunes and dikes. Most of the population (nearly 11 million) lives in the threatened area, which is also the fulcrum of the Dutch economy: Schiphol Airport, the Port of Rotterdam, Amsterdam, the capital, and The Hague, seat of government. Roughly 65% of GNP is produced in the lowest region of the Netherlands, in some places several meters below sea level. The Netherlands is also home to a rich natural environment and has a wealth of history and culture, none of which can be lost. The Netherlands is safe, but has to start work on the future now. The Delta Committee has made twelve recommendations to 'future proof' the Netherlands, even over the very long term, securing the country against flooding, assured of adequate fresh water, while remaining an attractive place to live. The basic issue is security, but the advice interfaces with life and work, agriculture, ecology, recreation and leisure, landscape, infrastructure and energy. Together, the twelve recommendations make up the Delta Programme, which must be financially guaranteed by a Delta Fund. A new Delta Act will provide the legislative anchor for the political-administrative organization for the improvement of water security and the Delta Fund. [Dutch] De Deltacommissie is door de regering gevraagd advies uit te brengen over de bescherming van Nederland tegen de gevolgen van klimaatverandering. Daarbij gaat het om de vraag hoe Nederland zo ingericht kan worden dat het ook op de zeer lange termijn klimaatbestendig is, veilig tegen overstromingen, en een aantrekkelijke plaats is en blijft om te leven; wonen, werken, recreeren en investeren. Daarbij was de vraag breder te kijken dan naar (water)veiligheid alleen. In de visie is daarom ook gelet op samenhang met wonen en werken, landbouw, natuur, recreatie, landschap, infrastructuur en energie. Veiligheid en duurzaamheid zijn de twee pijlers voor de strategie van de komende eeuwen. Naast bescherming tegen het water, benadrukt en benoemt het advies de kansen voor de Nederlandse samenleving.
Validation of a social vulnerability index in context to river-floods in Germany
Social vulnerability indices are a means for generating information about people potentially affected by disasters that are e.g. triggered by river-floods. The purpose behind such an index is in this study the development and the validation of a social vulnerability map of population characteristics towards river-floods covering all counties in Germany. This map is based on a composite index of three main indicators for social vulnerability in Germany - fragility, socio-economic conditions and region. These indicators have been identified by a factor analysis of selected demographic variables obtained from federal statistical offices. Therefore, these indicators can be updated annually based on a reliable data source. The vulnerability patterns detected by the factor analysis are verified by using an independent second data set. The interpretation of the second data set shows that vulnerability is revealed by a real extreme flood event and demonstrates that the patterns of the presumed vulnerability match the observations of a real event. It comprises a survey of flood-affected households in three federal states. By using logistic regression, it is demonstrated that the theoretically presumed indications of vulnerability are correct and that the indicators are valid. It is shown that indeed certain social groups like the elderly, the financially weak or the urban residents are higher risk groups.
Throughout Europe the demands for improved flood protection on the one hand and the requirements to maintain and enhance floodplain forests on the other are perceived as conflicting goals in river-basin management, revealing the urgent need for strategies to combine both issues. We developed an interdisciplinary approach for floodplain-forest restoration identifying sites suitable for reforestations from both an ecological and hydraulic point of view. In the ecological module, habitat-distribution models are developed providing information on ecologically suitable sites. In the hydraulic module, a two-dimensional hydrodynamic-numerical model (2D-HN model) delivers the requested hydraulic information. The output of the two models is intersected. Subsequently, in an iterative procedure, the potential of plantings without exceeding critical water levels can be identified by hydraulic evaluation using the 2D-HN-model. The approach is exemplified using two reforestation scenarios at the Elbe River, Germany, showing considerable potential for softwood forest establishment without negative hydraulic effects. The approach reported here provides a solution for a severe conflict in river-basin management that hampers the reestablishment of the strongly threatened floodplain forests in Europe. Alternative measures to enhance floodplain-forest regeneration feasible under certain preconditions are discussed in the context of the current state of European large rivers. PMID:22471087
During the period 1983-1985 sediment samples of the River Elbe (and for comparison from the River Weser, North Sea, Baltic Sea) were taken from the sediment surface and from levels up to one meter below. Seston was collected from depths one meter below the water surface by continuous-flow centrifugation. Samples were analysed qualitatively and quantitatively for the concentrations of non-volatile chlorinated hydrocarbons. Sediment samples from different areas of the River Elbe show an Elbe-typical distribution pattern of chlorinated hydrocarbons compared to sediments from other waters of the Federal Republic of Germany, characterized by a dominating hexachlorobenzene peak and a marked octachlorostyrene peak in the capillary gaschromatogram. Concentrations of organochlorines in sediments from different parts of the River Elbe vary considerably. Correlations with the content of organic carbon can be made. Areas with a high sedimentation rate have twice as much chlorinated hydrocarbons in the first 4 to 5 cm of the sediment surface than in the layers below. In contrast to solutions with large amounts of hexachlorocyclohexanes, seston has a distribution pattern of organochlorines similar to sediment, although concentrations in general are much higher.
Water exchange processes in the floodplain of a lowland groundwater-surface water system are studied on the basis of a study site near Freienbrink, NE Germany. The surface water boundaries of this site are formed by an oxbow and the current bed of the river Spree, section Müggelspree. Surface and ground water levels and water temperatures were collected in 12 piezometers and 2 recording stage gauges of a 300 m long transect throughout a one-year-period. Due to water level fluctuations alternation of infiltration and exfiltration occurred. However, most of the time groundwater flux is directed into the river Spree and, river water infiltration events into the aquifer are usually short and of minor importance. Due to clogging of the oxbow bed with a mud layer of different thickness the hydraulic contact between the oxbow and the adjacent aquifer is heterogeneously distributed and partially marginal. These features are modelled quantitatively using SUTRA in order to simulate coupled ground water flow and heat transport. A two-dimensional vertical modelling approach along the piezometer transect is developed to study exchange processes close to the surface water bodies more in detail in order to quantify the hyporheic fluxes of both river sections and to identify the directions and quantities of mass and heat fluxes. With the results the following questions will be answered: (1) It is possible to identify and to quantify the hydraulic processes (in- and exfiltration) between both river sections and the aquifer? (2) How fast does the exchange between the surface water and the aquifer occur? (3) Is there a hyporheic zone between the river sections and the aquifer, where groundwater and surface water are mixed, and how much water and heat will be transferred through this zones?
Polychlorinated naphthalenes and other dioxin-like compounds in Elbe River sediments.
Contamination of Elbe River (Germany) sediments with dioxin-like toxicants was investigated following the 500-year flood (flood that statistically occurs once in 500 years) of 2002. It was hypothesized that large amounts of particulate matter from river beds and associated dioxin-like toxicants were mobilized and transported during this flood event. The investigation focused on polychlorinated naphthalenes (PCNs) that have not been determined previously in the Elbe River. The in vitro H4IIE-luc assay was used as an overall measure for toxicants capable of binding to the aryl hydrocarbon receptor (AhR). The assay was combined with congener-specific instrumental analyses and fractionation to quantify PCN contributions to total AhR-mediated activity relative to polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs). Penta- to octachloronaphthalene concentrations of 30 ng/kg dry weight up to 13 microg/kg dry weight were found in Elbe River sediments downstream of Bitterfeld. Concentrations of penta- to octachloronaphthalenes, however, were only approximately 3 microg/kg dry weight at a site in the vicinity of Bitterfeld, where a level of approximately 3 mg/kg dry weight was reported before the flood. Also, the congener pattern of PCNs at this site changed after the flood, and PCN patterns reported previously for Bitterfeld and assigned to chlor-alkali electrolysis with graphite electrodes could now be observed at the sites from downstream of Bitterfeld and Magdeburg. Whereas PCDD/Fs dominated the dioxin-like activity in the middle and lower Elbe River, PCNs contributed as much as 10% of the total AhR-mediated activity. The contribution of PCBs was less significant (maximum, 0.2%). Thus, in Elbe River sediments, PCNs should be considered as relevant contaminants and be included in future monitoring and risk assessment programs. PMID:17973563
Indicators for assessing anthropogenic impact on urban surface and groundwater
Background, aim and scope. Our study focuses on the indication of anthropogenic impacts on the urban surface and groundwater in large cities, demonstrated for the cities of Halle/Saale and Leipzig (Germany). For the study we selected indicator substances such as xenobiotics, trace elements, and stable isotopes which are connected to human activities in urban areas. The xenobiotics reported here are the pharmaceutical carbamacepine, the polycylic musk compounds galaxolide and tonalide, the life style product caffeine, and industrial chemicals such as bisphenol A and t-nonylphenol. The investigated xenobiotics pose largely unknown risks to human health and the aquatic ecosystem. Trace elements are represented by the rare earth element gadolinium (Gd), used as magnetic resonance imaging contrast substance. Nitrogen isotopes in dissolved nitrate characterize the origin of nitrogen compounds, mixing and reaction processes. Methodology. River water was sampled along the flow path of the rivers Saale and Weisse Elster through the city of Halle/Saale, the rivers Luppe and Weisse Elster through the city of Leipzig. Separate samples were collected from the effluent of the local waste water treatment plants. Groundwater from Quaternary plain aquifers along the rivers and from different urban locations was collected at the same time. The indicators were analysed and assessed according to their sources, concentration and distribution patterns. Results and discussion. Based on the nitrogen isotopic signature, dissolved nitrate in river water of the Saale was referred mainly to two sources: the effluent of the water treatment plant and a mixture of diffusive inputs from rain water channels, sewage leakages and agriculture activities along the rivers. The Gd anomaly was recognized in surface water of both cities, particularly in the effluent of the water treatment plants, but clearly attenuated in groundwater. We measured concentrations of xenobiotics in river and sewer water between 10 and 60,000 ng L{sup -1}, and, in groundwater, one order of magnitude lower. Distinctions of xenobiotic patterns were found in river water before and after the effluent of treated waste water into the rivers. Degradation of endocrine disrupters and fragrances, but also persistence of carbamacepine were recognized as essential processes during waste water treatment. At the study site Halle/Saale, mass balances were set up for xenobiotics and water fluxes. (orig.)
During the Late Cretaceous to Early Tertiary some parts of the Central European Basin System (CEBS) were uplifted along NW-SE to WNW-ESE striking compressive fault systems. As a result Pre-Zechstein (Permian) basement is exposed at the southern border of the CEBS from Central Germany to the sudetes still further east (e.g. Harz Mountains, Thuringian Forest). Thrust-related basins like the Subhercynian Cretaceous Basin (SCB) in the foreland of the Harz Mountains accumulated up to 2500m of siliciclastic and chemical sediments in only 10 million years (Late Turonian to Lower Campanian, Voigt et al., 2006). By means of low-temperature thermochronology it is possible to characterise these basin inversion processes with respect to timing, pattern and rates of cooling and exhumation. Differed authors have already applied Apatite Fission Track analysis (AFT) in certain areas of the southern margin of CEBS. Thomson and Zeh (2000) published AFT apparent ages of 69 to 81 Ma for the Ruhla Crystalline Complex in the Thuringian Forest. Similar AFT-ages (73-84 Ma) of granitoids from the Harz Mountains were reported by Thomson et al. (1997). The late Carboniferous felsic volcanic rocks near Halle yield a much broader range of AFT apparent ages (75-108 Ma; Jacobs and Breitkreuz, 2003). Comparable AFT-ages (84-90 Ma) had been also observed for gabbros from the north-eastern part of the Mid German Crystalline High (Ventura et al. 2003). The present study tries to bridge some of the major gaps in the regional distribution of thermochronological data by analysing samples from central and southern parts of the CEBS. Overall almost 50 AFT-ages from Saxony-Anhalt, Lower Saxony, Thuringia, Hesse and North Rhine-Westphalia were measured. Emphasis is placed on the regions from the Harz Mountains to the Rhenish Uplands and the Thuringian Forest and its foreland. Furthermore, apatite (U-Th)/He thermochronology is used to better constrain the time-temperature history models. Apart from some mixed age information two different age groups can be recognized. A major group that is similar to the one reported above points to a short but intense pulse of exhumation and inversion in Coniacian to Campanian time. A younger, less significant age cluster yields information on a second phase of cooling and exhumation in the Paleocene-Eocene. The length distribution of AFT data leads to the assumption of rapid, partially multi-phase, exhumation events. In addition, the data of this study provides indications for thick Jurassic burial that likely reflect phases of Mesozoic extensional tectonics in at least parts of the CEBS. Jacobs, J., Breitkreuz, C. (2003): Zircon and apatite fission-track thermochronology of Late Carboniferous volcanic rocks of the NE German Basin. International Journal of Earth Sciences (Geologische Rundschau), 92, 165-172. Thomson, S., Brix, M., Carter, A. (1997): Late Cretaceous denudation of the Harz Massif assessed by apatite fission track analysis. In: G. Büchel and H. Lützner (Editors), Regionale Geologie von Mitteleuropa, 149. Hauptversammlung Deutsche Geologische Gesellschaft, Jena. Schriftenreihe der Deutschen Geologischen Gesellschaft, 3, 115. Thomson, S.N., Zeh, A. (2000): Fission-track thermochronology of the Ruhla Crystalline Complex:. New constraints on the post-Variscan thermal evolution of the NW Saxo-Bohemian Massif. Tectonophysics, 324, 17-35. Ventura, B., Lisker, F., Kopp, J. (2003): Apatite fission track data from the dill-core Züllsdorf 1/63: implications for the reconstruction of the post Variscan exhumation of the Mid German Crystalline High. Zeitschrift für Geologische Wissenschaften, 31, 251-261. Voigt, T., Wiese, F., von Eynatten, H., Franzke, H.-J. & Gaupp, R. (2006): Facies evolution of syntectonic Upper Cretaceous deposits in the Subhercynian Cretaceous Basin and adjoining areas (Germany). Zeitschrift der Deutschen Gesellschaft für Geowissenschaften, 157/2, 203-244.
Scaling view by the Virtual Nature Systems
The Virtual Nature System is irreplaceable for research and evaluation for governing processes on the Earth. Processes on the Earth depends on external exogenous and endogenous influences, and on own dynamics of the Actual Nature Systems (ANS). To select part of the actors is impossible without take in account factor of the Time, factor for information safety during the Time. The stochastic nature of external influences and stochastic pattern for dynamics of Nature systems complicates evaluation of 2D threat of disasters. These are multi-layer, multi-scale, and multi-driven structures of surface processes. Their spatial-temporal overlapping of them generates relatively stable structure of river basins and of river net. Dynamics of processes in river basins results in remove of the former sediments and levels, and in displace of erosion/sedimentation pattern, in destroy and dissipation for a memory the ANS. This complex process results in the Information Loss Law (ILL) in the ANS, which gradually cut off own Past. This view on the GeoDynamics appeared after long time field measurements thousands of terrace levels, hundreds of terrace ranks, and terrace complexes in river basins (Klenov, 1986, 2004). Action of the ILL leads to blanks in natural records, which are non-linearly increasing to the Past, and in appearance of false trends in the records. This temporal barrier prevents evaluation of the history. The way to view spatial-temporal dynamics of the ANS is creation for the portrait Virtual Nature Systems, as acting doubles of the actual nature systems (ANS). Exogenous and endogenous influences are governing drivers of the ANS and of corresponding VNS. The VNS is necessary for research of spatial-temporal GeoDynamics. Unfortunately, the ILL is working not only for the Past, but also restrict ‘view' the Future. It is because of future drivers are yet unknown with necessary exactness, and due high sensitivity of nature systems to external pressure. However, a time for validation of the VNS is short to receive non distorted records, but it provides satisfactory validation of the VNS, and provides satisfactory evaluation for stochastic patterns of disasters (floods and debris flows). The VNS gives a chance to divide exogenous (climatic) from tectonic influences. This property is invaluable for monitoring and scenarios of land use, engineering, and other human activity, under simultaneous climatic and tectonic impacts, for evaluation of threat's areas and tracks. The continually measured stochastic spatial-temporal interception of external impacts (storms, precipitations, of tectonic distorts, earthquakes, and others), does not make problems for the VNS (acting by observed records), and by imply the Moving Digital Earth (MDE) technology (by immediate reforming of external drivers to natural processes). It is a goal for the VNS and MDE, which becomes possible by remote sensing, by powerful computers, and by fast communications. The VNS/MDE presents corresponding mapping for processes in any area. Instead of problems of scaling the current task is to provide necessary spatial resolution of the basic multi-layer Matrix of variables and parameters. Problems are in procedures for filling up of large multi-layer M, quick computing and mapping of large areas. The scaling depends on a task. The acceptable spatial resolution of the Matrix must perceive in view to hazardous processes with acceptable in resolution. During the VNS practice were evaluated any imagined combines of exogenous-endogenous impacts (from linear to circle distort, blocks, volcanoes, earthquakes, and others, in a variety of scales from local to sub-continental. The single principle for choose a scale is that spatial resolution (cell size) should not ignore important details of the Earth. For the Rhine Basin was computed influence of small smooth tectonic distorts in a large area. It was resulted in essential change for pattern of erosion/sedimentation on a land, and in Coastal Zone. For small basis were computed scenarios for complex tectonic distorts, earthqua
Aim: Stroke is one of the leading causes of death worldwide. Optimizing health care according to the "time is brain" concept is recommended by the Local Health Conferences (KGK) in North Rhine-Westphalia. In 2001, KGK managers from six neighboring districts and municipalities founded the "Healthy Lo...
The effects of using three alternative gasoline fuel blends on regional air quality of the upper Rhine valley have been investigated. The first of the tested fuels is oxygenated by addition of ethyl-tertio-butyl ether (ETBE), the second is based on a reformulation of its composition and the third on...
The effect of subsidizing continuous training investments: evidence from German establishment data
This paper evaluates the impact of a training voucher program on establishments' investments in further training. The voucher program that was implemented in the German federal state of North Rhine-Westphalia increased training incentives for employees in small and medium-sized establishments by red...
When diffusion is the rate-contyolling step, Co and Ci are given by Sievert's Law. ... assumed to vary with temperature according to the Arrhenius-type equations: ... thermic, reaction with carbon in the alloys to produce methane is known to occur. ..... 5-28. 3. F. N. Rhines, "Gas-Metal Diffusion and Internal Oxidation," in Atom ...
The book is based on detailed investigations of structural damage, carried out by the authors for the Minister of the Interior of the Land of North Rhine Westphalia. To limit the scope of the present volume, damage in technical installations have been excluded. Structural and non-structural interior walls, ceilings, floors and the surface layers of walls and ceilings are discussed.
Water-level fluctuations affect macrophyte richness in floodplain lakes
The characteristic ecology of floodplain lakes is in part due to their relatively strong water-level fluctuations. We analyzed the factors determining water-level fluctuations in 100 floodplain lakes (during non-flooded conditions) in the active floodplains of the Lower Rhine in the Netherlands. Fur...
Quantification of hyporheic exchange using conservative and reactive tracers
The transition zone between groundwater and surface water is commonly referred to as the hyporheic zone. In the so-called hyporheic exchange river water penetrates into the subsurface, remains there for a certain time, and then returns into the active water channel at a location further downstream. Hence, solutes enter the sediment where they can potentially be retained or degraded so that the hyporheic exchange is of particular importance for the prediction of reactive solute transport in rivers. In the past, tracer experiments where a conservative tracer is added into the river and measured further downstream were used to characterize hyporheic exchange. The problem is that the hyporheic exchange has similar effects on the measured tracer breakthrough curves than mixing processes in the river itself (e.g. dispersion). In order to separate these processes, we carried out tracer tests where the compound resazurin was used as a reactive tracer in addition to a conservative tracer (uranine). Resazurin degrades selectively and irreversibly in the hyporheic zone and thus provides additional information specifically on the hyporheic exchange. We performed a total of five tracer tests at two different tributaries of the river Neckar (Goldersbach and Steinlach) and at the river Selke in Germany. We used three-channel fluorometers that are able to measure resazurin, resorufin and uranine simultaneously and directly in the field. The high temporal resolution of the measurements and the avoidance of possible errors related to sample storage and contamination led to high quality data sets that were used as input for the subsequent modeling. The breakthrough curves of uranine and resazurin were analyzed simultaneously using a shape-free method for the determination of hyporheic travel time distributions (deconvolution). In comparison to the analysis of uranine alone, we were able to improve the determination of the strength of hyporheic exchange and hyporheic travel time distributions considerably. In particular, we could obtain consistent sets of parameters for river sections of different lengths. These parameters will be used in reactive transport models for biogeochemical major constituents (e.g. dissolved oxygen) in river water.
The catchment-scale hydrologic modelling approach PCRaster-POLFLOW permits the integration of environmental process modelling functions with classical GIS functions such as database maintenance and screen display. It has previously successfully been applied at relatively large river basins and catchments, such as Rhine, Elbe and Norrstroem, for modelling stream water flow and nutrient transport. In this study, we review the PCRaster-POLFLOW modelling approach and apply it using a relatively fine spatial resolution to the smaller catchment of Forsmark. As input we use data from SKB's database, which includes detailed data from Forsmark (and Simpevarp), since these locations are being investigated as part of the process to find a suitable location for a deep repository for spent nuclear fuel. We show, by comparison with independently measured, area-averaged runoff data, that the PCRaster-POLFLOW model produces results that, without using site-specific calibration, agree well with these independent measurements. In addition, we deliver results for four planned hydrological stations within the Forsmark catchment thus allowing for future direct comparisons with streamflow monitoring. We also show that, and how, the PCRaster-POLFLOW model in its present state can be used for predicting average seasonal streamflow. The present modelling exercise provided insights into possible ways of extending and using the PCRaster-POLFLOW model for applications beyond its current main focus of surface water hydrology. In particular, regarding analysis of possible surface water-groundwater interactions, we identify the Analytic Element Method for groundwater modelling together with its GIS-based pre- and post processor ArcFlow as suitable and promising for use in combination with the PCRaster-POLFLOW modelling approach. Furthermore, for transport modelling, such as that of radionuclides entering the coupled shallow groundwater-surface water hydrological system from possible deep repository leakage, a recent semi-analytical approach of Lindgren et al. to modelling solute transport through the integrated groundwater-stream system of a catchment may, for instance, be a fruitful tool to use in combination with the PCRaster-POLFLOW surface-hydrological approach. For more detailed results on the actual evapotranspiration distribution (used as critical input for the PCRaster-POLFLOW modelling, for determination of the local precipitation surplus), the remote sensing model SEBAL (Surface Energy Balance for Land) appears to be powerful, because it is based on physical concepts, and does not rely on land use classification.
In this project, a nation-wide, ecotoxicologically-based sediment survey was carried out. For this purpose, a total of about 200 sediment samples from 12 selected large German rivers (Danube, Elbe, Ems, Main, Mosel, Neckar, Neisse, Odra, Rhine, Ruhr, Saar and Weser) were analysed with regard to abiotic parameters (heavy metals, PAH, organic carbon content, particle size) and also by means of two biological test systems with benthic invertebrates (nematode test with the roundworm Caenorhabditis elegans and chironomid test with the non-biting midge Chironomus riparius). Subsequently, this comprehensive data set was analysed statistically. By means of an iterative method, a five-stage, statistically-derived assessment concept which is founded on the results of the biological tests, was developed following the EU water framework directive. In general, the classification with the nematode test turned out to be the more sensitive method. A principal component analysis and correlations showed that the parameters of both biotests provide different information which suggests a combined use of both tests. Correlations also indicate a connection of biotest results and abiotic parameters (organic carbon content, particle size and heavy metal contamination). (orig.) [German] Im Projekt wurde eine bundesweite oekotoxikologische Sedimentkartierung grosser Fliessgewaesser durchgefuehrt. Dazu wurden insgesamt etwa 200 Sedimentproben aus 12 ausgewaehlten grossen Fluessen Deutschlands (Donau, Elbe, Ems, Main, Mosel, Neckar, Neisse, Oder, Rhein, Ruhr, Saar und Weser) auf ihre abiotischen Parameter (Schwermetalle, PAK, organischer Kohlenstoffgehalt, Korngroesse) hin analysiert sowie mit zwei biologischen Testverfahren mit benthischen Invertebraten (Nematodentest mit dem Fadenwurm Caenorhabditis elegans und Chironomidentest mit der Zuckmuecke Chironomus riparius) untersucht. Dieses umfangreiche Datenmaterial wurde anschliessend statistisch ausgewertet und mit Hilfe eines iterativen Verfahrens ein fuenfstufiges, statistisch abgesichertes Bewertungskonzept in Anlehnung an die EU-Wasserrahmenrichtlinie entwickelt, welches auf den Ergebnissen der biologischen Tests beruht. Insgesamt erwies sich die Bewertung anhand des Nematodentests als deutlich sensitiveres Verfahren. Ueber eine Hauptkomponentenanalyse sowie Korrelationen konnte gezeigt werden, dass die Parameter der beiden Biotests unterschiedliche Informationen liefern und daher der kombinierte Einsatz beider Testverfahren sinnvoll ist. Korrelationen zeigten eine Abhaengigkeit der Biotestergebnisse von abiotischen Parametern (Kohlenstoffgehalt, Korngroesse sowie Schwermetallbelastung). (orig.)
A good understanding of the physical and chemical characteristics of groundwater-surface water interaction is essential for the protection of groundwater dependent ecosystems and aquatic ecology. Groundwater- surface water interactions occur at a broad range of spatial and temporal scales, involving complex and nested flow paths. Often, the interaction is studied at the local scale or smaller, which is helpful in identifying controlling processes, but has limitations in upscaling the results for management purposes. Dahl et al 2007 proposed a classification scheme to be used on a regional scale, which was based on qualitative mapping of characteristics of water course dimensions and aquifer-connectivity. In our project, we used a quantitative approach using the Dutch National Hydrological Instrument (NHI, www.nhi.nl) to study the dynamic behavior of groundwater-surface water interaction on the scale of The Netherlands. The NHI integrates information on the structure of the subsurface, the dimensions and connections between surface water courses and boundary fluxes, and includes coupled modules for the saturated and unsaturated zone and surface waters (based on MODFLOW, MetaSWAP, and SOBEK). In our study, we assessed the groundwater-surface water interaction by summarizing all fluxes to and from watercourses within predefined catchment boundaries for one-month intervals for a dry (2003), a wet (1998), and an average year (2004). We distinguished flow through tile drains, overland flow, and groundwater discharge of primary, secondary, and tertiary watercourses. The study yields a dynamic series of maps showing the net monthly discharge or recharge of groundwater for the 12 months of a dry, wet and average year. The maps show that groundwater-surface water interactions are very dynamic for most of the Netherlands. Especially the topographically low areas in the west of The Netherlands show a few winter months with net groundwater discharge towards the surface water and prolonged periods with surface water infiltration towards the groundwater . The infiltrating water is diverted from the Meuse and Rhine rivers and is distributed over large parts of the Netherlands in order to maintain sufficient surface water depths. About 70% of the Netherlands show this conversion between groundwater discharge in winter towards surface water infiltration in summer. We will present examples of the application of the groundwater-surface water interaction maps, such as the delineation of groundwater dependent nature reserves and the assessment of environmental flow needs for aquatic ecosystems. Another promising application of our methodology is linking the patterns of surface and groundwater quality to the groundwater-surface water interaction at the national scale, similar to a previous regional analysis (Rozemeijer & Broers (2007). Rozemeijer, J. and H.P. Broers (2007). Environm. Poll. 148: 695-706 Dahl M et al. 2007. J. of Hydr., 344:1-16
An investigation of the chlorinated volatile organic compound (CVOC) biodegradation processes at a reference site with a contaminant plume of 4 km length in a terrace gravel aquifer has revealed that simultaneously spilled non-chlorinated contaminants (which serve as electron donors for reductive dechlorination) caused a transformation of the parent contaminants to cis-1,2-dichloroethene (cDCE) and vinylchloride (VC). Secondary spills in the area of the plume have lead to a complex pattern of different redox zones. In deeper areas of the aquifer, a lack of electron donors due to their migration properties could be observed. The complete mineralization at the plume tip seems to occur under anaerobic conditions via oxidative biodegradation pathways, or under aerobic conditions. High waters of the nearby Rhine river cause a staggering of the plume tip which is likely accompanied by growth of the aerobic fringe area. Pump and treat measures to capture the source area and dissolved plume have substantially altered the biodegradation conditions. On the basis of the investigation results, a simple model was developed to evaluate whether MNA may be an option at CVOC contaminated sites. (orig.) [German] Die Untersuchung der Abbauvorgaenge von leichtfluechtigen chlorierten Kohlenwasserstoffen (LCKW) an einem Modellstandort mit einer etwa 4 km langen Schadstofffahne in einem Terrassenkies-Grundwasserleiter hat ergeben, dass gleichzeitig eingetragene nicht-chlorierte Schadstoffe, die als Elektronendonatoren fuer den reduktiven LCKW-Abbau dienen, lediglich eine Transformation der Parentalsubstanzen zu cis-1,2-Dichlorethen (cDCE) bzw. Vinylchorid (VC) erlauben. Sekundaereintraege innerhalb der Fahne mit chlorierten und nicht chlorierten Schadstoffen fuehren zu einem komplexen Muster an unterschiedlichen Redoxzonen, wobei in tieferen Bereichen des Aquifers wegen der Migrationseigenschaften der nicht-chlorierten Stoffe teilweise ein Mangel an Elektronendonatoren vorliegt. Eine vollstaendige Mineralisierung der Metabolite erfolgt anscheinend anaerob oxidativ bzw. unter aeroben Bedingungen an der Fahnenspitze (definiert als Ort {<=}25{mu}g/l LCKW). Hochwasserereignisse des in der Naehe gelegenen Rheins fuehren zu einem raschen und haeufigen Wechsel der Grundwasserstroemungsrichtung der Fahnenspitze und damit wahrscheinlich zu einer Verbreiterung des aeroben Saums. Pump-and-Treat-Massnahmen zur Sicherung der Quelle und innerhalb der Fahne fuehren zu einer signifikanten Veraenderung der Abbaubedingungen. Auf Grundlage der Untersuchungsergebnisse wurde ein einfaches Modell zur Abschaetzung, ob MNA als Handlungsoption an einem LCKW-kontaminierten Standort geeignet ist, entwickelt. (orig.)
Goal and scope. This study was undertaken to investigate the differences in heavy metal burden between the organisms and environmental compartments and to evaluate the role of Dreissena polymorpha as a bioindicator organism. Methods. The concentrations of zinc, copper, cadmium and lead in whole soft body and selected tissues of D. polymorpha at two river habitats in Austria were examined using atomic absorption spectroscopy (AAS). Concentrations in organisms were compared to those in sediment and water. Results and conclusion. Zebra mussels of the river Drau showed generally higher heavy metal concentrations as compared to mussels of the river Danube and contained elevated zinc and cadmium levels as compared to metal concentrations found in soft tissues of zebra mussels from uncontaminated sites in Germany and The Netherlands. The essential metals zinc and copper were mainly accumulated in gills, foot and byssal gland tissue of the mussel, in contrast to the non-essential metals cadmium and lead which were found predominantly in the midgut gland. The heavy metal concentrations in both, sediments and mussel tissue, were higher than in water samples. There was no correlation between the concentrations in water and in the organisms except for zinc. In contrast, correlations were found between concentrations in sediments and mussel soft tissue. Recommendation and perspective. Further investigations should include the examination of sediments and consider the mechanism of food uptake to assess the role of D. polymorpha as a bioindicator organism. (orig.)
Photolysis and biodegradation of selected resin acids in River Saale water, Germany.
The River Saale is the Elbe's major tributary flowing through the state of Thuringia, Germany and receives organics inputs from several industrial facilities including pulp and paper mills. Resin acids constitute a major class of polar organics and environmental toxins derived primarily from pulp and paper processing of softwoods. Since wastewater treatment methods at pulp and paper mills are not always capable of removing the persistent resin acids prior to effluent discharge, alternative or complementary degradation methods may be required. Here, the facile photodegradation of four resin acids--abietic, dehydroabietic, isopimaric, and pimaric--was observed with pseudo-first-order kinetics when exposed to broad band and UV254-radiation. Further experimentation in rotating annular biofilm reactors with UV-exposed and unexposed River Saale water spiked with abietic and dehydroabietic acids indicated that photolysis is an effective pretreatment method for resin acid biodegradation. The bacterial toxicity of the aqueous resin acids solutions as measured with Microtox luminescence assays decreased with exposure time. Consequently, photo- and biodegradation of the resin acids did not generate any notable amounts of toxic intermediates and/or the intermediates formed were further degraded into compounds of lower toxicity than the parents. With tandem photo- and biological treatment at pulp and paper mills, as well as in-situ degradation by solar radiation and natural biofilms within the River Saale, resin acid inputs can be reduced in both concentration and toxicity to near undetectable levels with little or no ecological significance. PMID:14672312
Investigation of DOM in a coastal discharge (Northwest Germany)
River systems play a major role in the global chemical cycles of carbon and nitrogen. DOM in rivers exhibits a wide compositional diversity reflecting different organic matter sources related to the bioproduction in the drainage area, seasonal variations and anthropogenic influence. The chemical structure of riverine DOM is still largely unknown. The major part of DOM in natural waters consists of humic matter which is formed during degradation of plant- and animal-derived organic matter as a result of various abiotic and microbial transformation processes. As a cosequence, humic matter has a complex polymer-like structure. Humic-matter-rich water was collected from the Neuharlingersieltief, which is a brown-water river in a marshy region in Northwest Germany. After filtration (carboxylic and phenolic hydroxyl groups into their methyl derivatives. In this study a large number of different compounds are presented. The identified compounds of isolated fractions show different abundances and cover a wide variety of different chemical structures which are mainly substituted aromatics such as benzenes, phenols and furans. Furthermore, the product distributions at different pyrolysis temperatures (300 - 700°C) were studied.
With the optically stimulated luminescence (OSL) dating method, the time elapsed since the last deposition of sediments can be determined. OSL-dating can be applied to sediments from different depositional environments. OSL-dating has therefore become an important tool in geochronological studies. Due to the sedimentation mechanism for fluvial sediments, incomplete bleaching of the mineral grains prior deposition can occur. This can result in a wide distribution of equivalent doses obtained from single aliquot or single grain measurements leading to an incorrect estimation of the depositional age. To overcome this problem, good measurement techniques and good data analysis with an adequate statistic are important. This is especially true in cases where other dateable material is missing and independent age control cannot be provided. In this study, fluvial samples from the Elbe River in northern Germany are investigated. Two sections have been sampled for OSL-dating. The samples are taken from sand layers deposited by the river. The quartz was extracted and dated using the single aliquot regenerative dose protocol. The OSL-properties of the quartz are good even though the luminescence signal is not very bright. Due to the dim signal, it was not useful to use the single grain approach. From each sample, 96 small aliquots are measured. The final equivalent dose was calculated using different statistical approaches, e.g. Leading Edge Model and Central Age Model. For each statistical method the age of deposition was calculated. The results are compared with the evolution of the river in this region, which is well-documented by historical records and maps. These records show changes in river morphology over the last 1000 years. The obtained OSL-ages of the river deposits fit well into the documented river evolution. It can be demonstrated that, depending on the statistical approach, the depositional age differs greatly from the most likely depositional age. Ages calculated using the Central Age Model or from the average or median of the dose distribution do not represent the depositional age. These methods lead to age-overestimation about three times higher than the depositional age documented by historical records. The best results that fit together with the historical evolution of the river are obtained from age models based on the lowest equivalent doses in a distribution, e.g. Leading Edge Model. This study shows that it is important to use an adequate statistical approach to calculate the equivalent dose to get reliable ages.
Impact of water overstock on groundwater quality of the Bassee plain area (France)
The project, inspired by the structural flood plain management measures of the Rhine River, consists in the temporal removal of a maximum amount of water from the Seine River in order to leave priority to the water from the River Yonne. Yonne River and the Seine are presenting their maximum water flow usually at a same time. The space located between Bray-sur-Seine and Montereau-Fault-Yonne corresponding to the La Bassée plain (agricultural area of 23 km2) is well adapted to this project of temporary and artificial flood. The objective of the project financed by the Institution Interdépartementale des barrages Réservoirs du Bassin de la Seine (IIBRBS), the BRGM, the Seine-Normandie Water Agency, the European Communauty through the Interreg IIIB SAND project is the evaluation, at a local scale, of the impact on groundwater quality of the temporal Seine water storage. Indeed, the water over storage i) changes hydraulic conditions and therefore modify water and pollutants transfers through the unsaturated and saturated zones and ii) bring at soil surface a water (Seine River) potentially containing contaminants that may move to groundwater and consequently changed physico-chemicals conditions (redox) of groundwater. The estimation of the vulnerability of groundwater to changes and loads needs hydraulic and geochemical modelling of transfer through the unsaturated zone as well as the study of pollutants fate in static conditions. Retention properties of some metals (Pb, Ni, Cu, Cr, Zn) in soils and materials of the unsaturated zone by chemical processes were performed determining adsorption coefficient (Kd) by laboratory experiments. These experiments are showing that nickel mobility is lower in the argillous layers than in the sandy part of the unsaturated zone. Ni mobility is controlled by iron hydroxides and precipitation of other secondary minerals. Its complexation on organic ligands increases its mobility in soils. Copper concentration is influenced by CaCO3 presence and soluble organic ligands. Zinc is strongly adsorbed on the solid matrix at all tested soils. At basic condition, such as normally encountered at the Bassée floodplain, chromium adsorption is very low or null. Based on these results, batch modelling (without transport) were carried out for Cu and Ni. That confirms that nickel adsorption is controlled by iron hydroxides in porous media. For copper, the main processes controlling adsorption is organic ligands complexation that increases the mobility of this element in the soils. To complement the information acquired on metal comportment in the unsaturated zone and because pesticides were detected in soils and groundwater, laboratory experiments were performed using glyphosate alone and combining this pesticide with the tested heavy metals. The tests are highlighting the strong relationships between metals and pesticides. For the 5 soils used glyphosate adsorption is increased when metals are added to the solution. At the opposite, the experiences for the evaluation of the impact of the increase of glyphosate on the quantity of metals adsorbed (Cu, Ni, Ni) were not conclusive. The geochemical calculation code PHREEQC was used to model reactive transfer of solutes in a 1 D saturated column. Results obtained indicate that some contaminants (nickel) are mainly retained at the iron hydroxides surfaces even at very high concentration. Stability of metal depends then on the maintaining of oxic conditions in the porous media. After adsorption, nickel concentrations in soils remains well under average natural concentrations. Results of the project allowed the risk evaluation of a groundwater contamination by the Seine River during overstock episodes. During derivation of the Seine River into the Bassée floodplain, infiltration of water and solutes in the unsaturated zones will be done quickly. Some metals (Zn, Ni, Cu), and the glyphosate, will stay in the first centimetres of the soils due to their intrinsic properties. Even if a change of the physico-chemical conditions (mainly redox, organic matter contents) of the Bassée floodplain has very little probability to occur, this change may lead to very important changes in the comportment of heavy metals and pesticides. Other elements (Cr and other anionic metals) are not retained in the shallow soil horizons and, as water, will infiltrate very quickly in the unsaturated zone during inundation phases. Persistence time, estimated by modelling, of dissolved elements in the unsaturated zone is few years. The results showed that the probability of groundwater contamination due to overstock episodes is very low to null but consequences may be important. This assessment obliges to consider the installation of a water quality monitoring program for the control of the Seine River upstream the alluvial plain about 5 days before filling up the retention basins and up to the end of the replenishment procedure.
In June and August 2003 Europe suffered a drought with extreme low flows and an extreme heat wave which caused about 35 000 fatalities and economic losses totalling 13 billion US-. Droughts and extreme low flows for Southwest Germany in summer and the vegetation period are mostly linked to a few special circulation types (CP). The methodology of a fuzzy rule based objective CP classification using NCAR-SLP data and time series of daily areal precipitation for several river basins of Southwest Germany will be described. 'Critical' drought-CPs, which are causing droughts and low flows in the study area are detected by using a wetness index. Spatial distribution of drought conditions will be illustrated by using maps of wetness index of specific CPs for the State of Baden-Württemberg. Time series of the frequencies and maximum persistence of the "critical" CPs will be analyzed for the observation period (1900-2007) and transient RCM-A1B-Scenario runs (2001- 2100) for three different RCMs. The KNMI RACMO2 model and the MPI REMO model, both driven by the A1B emission scenario of ECHAM5 and 3 ensemble runs of HadRM3 (2001-2099) of the UK Hadley Centre. The results of the statistical analysis of the 'critical' CPs will be demonstrated for summer (JJA) and the vegetation period (April-Sept.). A comparison of the results obtained for the observation period (1900-2007) and the transient A1B-scenario runs of 2001-2100 will indicate how the risk of extreme low flows and droughts in summer will change for Southwest Germany in the future for the different RCM runs.
Monazite and zircon, two heavy minerals which are rather stable against meteoric and intrastratal solutions, were investigated in drainage systems very much different as to the level of fluvial hierarchy (colluvial, alluvial, fluvial) and size (creek through trunk river) at the western edge of the Bohemian Massif, SE Germany, and in its immediate foreland. The variegated source rock lithologies and the good preservation potential of these minerals are the basis for this study of applied economic geology, aimed at finding out if these placer minerals may play a role as an ore guide to localize mineral deposits, constrain fertile source rock lithologies in the hinterland or simply be used as a provenance marker during the unroofing of a crystalline basement. In the current study mineralogica...
Environmental risk assessment of zinc in European freshwaters: A critical appraisal
A risk assessment report (RAR) on zinc and zinc compounds has recently been prepared in the framework of the European Union (EU) Council Regulation 793/93/EEC on Existing Chemicals. The EU Scientific Committee on Human and Environmental Risks (SCHER) has, however, expressed some fundamental, science-based concerns about the approach followed and the conclusions. The main objective of the present study was to assess the potential environmental risks associated with current use patterns of Zn in nine EU river basins in Germany, France and Belgium, thereby using more advanced methodologies which are largely in line with the recommendations made by SCHER. This included (i) avoiding working with measured Zn concentrations from monitoring stations that were potentially influenced by point source...
A multicriteria approach for flood risk mapping exemplified at the Mulde river, Germany
In this paper we develop a GIS-based multicriteria flood risk assessment and mapping approach. This approach includes flood risks which are not measured in monetary terms; it shows the spatial distribution of multiple risks, and it is able to deal with uncertainties in criteria values and to show their influence on the overall flood risk assessment. Additionally, the approach can be used to show the spatial allocation of the flood effects if risk reduction measures are implemented. The approach is applied to a pilot study for the River Mulde in Saxony, Germany, heavily affected by the hazardous flood in 2002. Therefore, a GIS database of economic, social and environmental risk criteria was created. Two different multicriteria decision rules, a disjunctive and an additive weighting approach...
The microbial degradation of pollutants in the aquatic environment essentially is influenced by the prevailing redox conditions and mass exchange processes (bioavailability). Within a new project, the Technologiezentrum Wasser TZW (Karlsruhe, Federal Republic of Germany) deals with the microbial conversion under dynamic conditions such as those expected in the area of the Three Gorges Dam at the Yangtze River. In particular, molecular-biological methods (PCR, polymerase chain reaction and DGGE Denatured gradient gel electrophoresis) are used for a targeted monitoring and further developed. The focus of the investigation initially focuses on the degradation of halogenated substances which are used as main substances for understanding the mass exchange between sediment and water as well as the microbial conversion processes. An enhanced understanding of the process and the compilation of the dynamic sales performance can be defined as a target.
As a result of intensive industrial, mining, and urban development, numerous large-scale contaminated areas exist in Germany. These so-called megasites represent a challenge to risk assessment and remediation strategies. At the Bitterfeld megasite, the contaminated groundwater interacts with the local streams. Along a stream reach 280 m long, the mass flow rates of chlorinated benzenes were estimated by combining integral pumping tests, streambed temperature mapping, and analyses of contaminant concentrations in the streambed sediments. On average, a total mass flow rate of 617 mg d-1 monochlorobenzene (MCB) and 157 mg d-1 dichlorobenzene (DCB) is released from the adjoining aquifer into the stream along the investigated reach. Further, the streambed sediment acts as the dominant contaminant source. Considering the streambed sediments, the contaminant mass flow rate to the river increases to values between 2,355 and 4,323 mg d-1 MCB and between 892 and 3,587 mg d-1 DCB.
Was god ever a `boss' at Wujal Wujal? Lutherans and Kuku-Yalanji: A socio-historical analysis
Lutheran missionaries from Germany arrived in 1887 to `care for' and to evangelise to the Kuku-Yalanji people of the Bloomfield River area of the north Queensland rainforests. They left fifteen years later without having converted a single soul. Was this failure the result of inept missionisation? Was Lutheranism at odds with Kuku-Yalanji religious beliefs? This paper argues that the answer lies rather at the core of the Kuku-Yalanji worldview and social universe. Using rich historical sources, this paper demonstrates that Kuku-Yalanji people-who have particular socio-territorial ties to the mission lands-instigated an experiment with the missionaries. Their assumption was that the missionaries held a role that was structurally equivalent to that of `majamaja' in their own system-key focal...
A spatial analytical approach for selecting reintroduction sites for burbot in English rivers
Summary 1.-Availability of suitable habitat is a prerequisite for species reintroduction success, and to ensure population persistence, investigations of a species- habitat utilisation throughout its life history should be conducted as part of a feasibility study. 2.-Habitat utilisation models for burbot, Lota lota, developed using data from field studies conducted in France and Germany and information from the literature were used to assess the feasibility of reintroducing burbot into rivers of its former native range in eastern England. 3.-Per cent tree roots, aquatic vegetation and flow types were important predictors of adult burbot abundance. Furthermore, the habitat utilisation models were supplemented with information from the literature, which suggested that off-channel habitat suc...
Hydrogeology and its effect on slope stability along the coastal aquifer of Nice, France
Along the Ligurian continental margin off Nice (Western Mediterranean) a considerable portion of the sediments is affected by pore pressure transients resulting from groundwater charging by the nearby river Var, and also from leaching clay-mineral bearing deposits, which results in sensitive, weak clays. In 1979 the area suffered a tsunamigenic landslide that generated several casualties and material damage to the coastal zone. The seafloor presently shows evidence for soft sediment deformation and pore water freshening. In this paper, we present the first comprehensive in situ pore pressure data set collected over space and time between 2006 and 2009 in a landslide-prone area. Using piezometers (IFREMER Brest, France) and dynamic cone penetrometers (FF-CPTu, MARUM Bremen, Germany) as well...
Integrated HSE management system of RWE Dea AG; Integriertes HSE-Managementsystem der RWE Dea AG
The core competences of RWE Dea AG are exploration and production of natural gas and petroleum. RWE Dea has more than 100 years of experience in drilling and production. It has foreign interests in Norway, Britain, Egypt, Libya, Kazakhstan, Poland and Denmark, some of which are worked in cooperation with competent partners. In Germany, RWE Dea focuses on natural gas exploration and production in Niedersachsen between the Elbe and Weser rivers, the development of the Mittelplate offshore field on the west coast of Schleswig-Holstein, and the operation of large-volume underground natural gas storage caverns in Bavaria. As its activities are related to health, safety and environment, RWE Dea developed a special management system for these aspects. (orig.)
Secondary succession in a fallow central European wet grassland
This long-term study (23yr) aims at specifying the characteristic features of secondary progressive successions in abandoned wet eutrophic grasslands as a precondition for better understanding causal relationships and improving the predictability of successions on such habitats. The vegetation of inundated fen grasslands (Calthion) at the lower course of the river Wümme near Bremen (Northwest Germany) was studied annually on three permanent plots (each 10×10m2) where hay making had ceased in 1983, 1985 and 1992, respectively. In the initial succession phase of three to five years a fast increase of tall-growing, rhizomatous, deciduous reed species (e.g. Phalaris arundinacea) occurred. This strongly changed vegetation structure and within-canopy light climate, which was the ...
Occurrence and temporal variations of TMDD in the river Rhine, Germany
Background, aim, and scope The chemical substance 2,4,7,9-tetramethyl-5-decyne-4,7-diol (TMDD) is a non-ionic surfactant used as an industrial defoaming agent and in various other applications. Its commercial name is Surynol 104? and the related ethoxylates are also available as Surfynol? 420, 440, 465 and 485 which are characterized by different grades of ethoxylation of TMDD at both hydroxyl functional groups. TMDD and its ethoxylates offer several advantages in waterborne industrial applications in coatings, inks, adhesives as well as in paper industries. TMDD and its ethoxylates can be expected to reach the aquatic environment due its widespread use and its physico-chemical properties. TMDD has previously been detected in several rivers of Germany with concentrations up to 2.5??g/L. In...
For a long time, watershed models focused on the transport of chemicals from the terrestrial part of the watershed to the surface water bodies by leaching and erosion. After the substances had reached the surface water, they were routed through the channel network often without any further transformation. Today, there is a need to extend watershed models with in-stream processes to bring them closer to natural conditions and to enhance their usability as support tools for water management and water quality policies. This paper presents experience with implementing in-stream processes in a ecohydrological dynamic watershed model and its application on the large scale in the Saale River basin in Germany. Results demonstrate that new implemented water quality parameters like chlorophyll a con...
Behavior of Gd-DTPA in simulated bank filtration
The behavior of Gd-DTPA during bank filtration was simulated in a 30 m column filled with Pleistocene sand and flushed by surface water from a lakeside in Berlin, Germany. The surface water is about a 1:1 mixture of river water and effluents from a sewage treatment plant. Throughout 34 days this water was continuously spiked with Gd-DTPA at a level of 60 ??¼g/L. The broad plateau of the Gd-DTPA pulse declined by 15.4% within 34 days by transmetallation. Nine percentage of the total decline is caused by Y and rare earth elements; the remaining part is attributed to Cu2+ which is the most influential metal in surface water. All other metals also contributing to transmetallation are combined with Cu to Cu equivalents because only the rate constant of transmetallation of Cu2+ is known. The an...
About one third of several hundred mining lakes in Eastern Germany are highly acidified, and there is a need to restore them to neutral conditions because they constitute an environmental hazard for water resources and downstream environments. The aim of this study is to evaluate the efficiency of three different acid pit lake water remediation treatments: dilution with alkaline (river) water, limestone treatment and biological neutralization by organic carbon-driven alkalinity generation. The efficiency is evaluated for the acidic mining lake Grünewalder Lauch by adjusting input values into a geochemical model and making future projections. Current approaches, such as flooding with neutral surface water or extensive liming, are not suitable for many lakes because of a limited supp...
Subaquatic sediment samples derived form Elbe and Mulde Rivers, Germany, were analyzed for extractable and non-extractable anthropogenic organic compounds by a non-target screening approach. Applied methodologies were gas chromatography-mass spectrometry, dispersion extraction and degradation procedures, particularly alkaline and acidic hydrolysis, boron tribromide treatment, ruthenium tetroxide oxidation as well as pyrolysis and TMAH (tetramethylammonium hydroxide)-thermochemolysis. Numerous compounds were identified, including halogenated benzenes, anisoles, styrenes, alkanes, diphenylmethane derivates, anilines, phenols and diphenyl ethers. The results were interpreted with respect to compound specific modes of incorporation as well as to potential sources (e.g. municipal, agricultural, industrial). Extractable and non-extractable fractions differed significantly with respect to their qualitative and quantitative composition. For example, quantities in the extractable and non-extractable fractions of chlorinated benzenes differed up to factor 50. Among other significant results, the investigation revealed hints for a dependence of the mode of incorporation of chlorinated benzenes on their substitution pattern. PMID:17070637
Summary The burbot (Lota lota) is the only cold-stenothermal gadoid inhabiting freshwaters with high temperature amplitudes. Summer temperatures up to 25C have been reported as being far above the thermal preferendum of this species. Thus this study aimed to determine gastric evacuation, daily food consumption and energy uptake of burbot at high temperatures under in situ conditions. These data are prerequisites for bioenergetics modelling of the adaptive physiological behaviour of burbot in summer-warm freshwaters. The study was conducted in the lower Oder River, Germany between May and October 2003 covering a temperature range between 4.6 and 23.4C. A total of 1683 burbot was caught in five successive 24-h fisheries. The mean index of stomach fullness showed a significant decrease with r...
One major scientific challenge posed by the EU Water Framework Directive (WFD) is the design of a decision support process that meets the Directive?s requirement to achieve ?good status? for all water bodies using a cost-effective combination of measures. This paper presents BASINFORM, a new decision methodology for selecting cost-effective management measures, developed in close co-operation with the water authorities and tested in the 5,154?km? mesoscale river Weisse Elster in central Germany. BASINFORM comprises (i) a procedure for framing the specific problems in the water bodies, including quantification of the need for action, (ii) modelling tools for quantifying the impacts of management measures, and (iii) a method for selecting cost-effective combinations of measures. One innovati...
Assessing the spatial and temporal variations of water quality in lowland areas, Northern Germany
SummaryThe pollution of rivers and streams with agro-chemical contaminants has become one of the most crucial environmental problems in the world. The assessment of spatial and temporal variations of water quality influenced by point and diffuse source pollution is necessary to manage the environment sustainably in various watershed scales. The overall objectives of this study were to assess the transferability of parameter sets between lowland catchments on different scales using the ecohydrological model SWAT (Soil and Water Assessment Tool) and to evaluate the temporal and spatial patterns of water quality in the whole catchments before and after implementation of best management practices (BMPs). The study area Kielstau catchment is located in Northern Germany as typical example of low...
Model-based predictions of the impact of land management practices on nutrient loading require measured nutrient flux data for model calibration and evaluation. Consequently, uncertainties in the monitoring data resulting from sample collection and load estimation methods influence the calibration, and thus, the parameter settings that affect the modeling results. To investigate this influence, we compared three different time-based sampling strategies and four different load estimation methods for model calibration and compared the results. For our study, we used the river basin model Soil and Water Assessment Tool on the intensively managed loess-dominated Parthe watershed (315 km2) in Central Germany. The results show that nitrate?N load estimations differ considerably depending on samp...
Model-based predictions of the impact of land management practices on nutrient loading require measured nutrient flux data for model calibration and evaluation. Consequently, uncertainties in the monitoring data resulting from sample collection and load estimation methods influence the calibration, and thus, the parameter settings that affect the modeling results. To investigate this influence, we compared three different time-based sampling strategies and four different load estimation methods for model calibration and compared the results. For our study, we used the river basin model Soil and Water Assessment Tool on the intensively managed loess-dominated Parthe watershed (315?km2) in Central Germany. The results show that nitrate?N load estimations differ considerably depending on samp...
Indices to assess the ecological status of water bodies according to the European Water Framework Directive (WFD) frequently produce widely differing results when applied to estuarine systems. Although several ecological indices have been employed to coastal environments and in estuaries in particular, there is still a lack of knowledge about their suitability for assessing the ecological status of heavily modified water bodies. Thus, we evaluated the performances of indices and fauna parameters (AMBI, M-AMBI, BOPA, BO2A, W-value, Shannon diversity, species richness, abundance) that have been discussed in the WFD context using data on invertebrates dwelling in two typical morphological units: the navigation channel and the river bank habitats of Elbe estuary (Germany). In addition, we test...
Long-term reactions of plants and macroinvertebrates to extreme floods in floodplain grasslands.
Extreme summertime flood events are expected to become more frequent in European rivers due to climate change. In temperate areas, where winter floods are common, extreme floods occurring in summer, a period of high physiological activity, may seriously impact floodplain ecosystems. Here we report on the effects of the 2002 extreme summer flood on flora and fauna of the riverine grasslands of the Middle Elbe (Germany), comparing pre- and post-flooding data collected by identical methods. Plants, mollusks, and carabid beetles differed considerably in their response in terms of abundance and diversity. Plants and mollusks, displaying morphological and behavioral adaptations to flooding, showed higher survival rates than the carabid beetles, the adaptation strategies of which were mainly linked to life history. Our results illustrate the complexity of responses of floodplain organisms to extreme flood events. They demonstrate that the efficiency of resistance and resilience strategies is widely dependent on the mode of adaptation. PMID:18831159
Soil-ecological evaluation of willows in a floodplain
Abstract Willows (Salix spp.) were supposed to be suitable candidates for the phytoremediation of polluted floodplain soils, but it is unknown how willow growth alters concentrations and mobility of pollutants under the conditions of ongoing periodically flooding. Therefore, effects of willow cropping on total concentrations and mobility of As and heavy metals and soil microbial properties were determined after three and four growing seasons under willows in comparison to native grassland in a flood channel of a River Elbe floodplain (Central Germany). After 4 y of willow coppice, the heavy metal concentrations (mg-kg-1) were increased not only in the grass control plots (final Cu 274, Pb 276, Zn 935) but also under the willows (final Cu 248, Pb 251, Zn 779) compared to the initial concent...
Abstract Extreme environmental events are predicted to increase in future due to global climate change. However, their effects on biodiversity still remain insufficiently understood because of the rarity and consequently the difficulty of studying the effects of extreme events. Here, we investigate the impacts on ground beetles of an unpredictable catastrophic flood event of the Elbe River in Germany in the year 2002 using pre- and post-flood data. We analysed the response of grassland communities differentially exposed to flooding and focused on the question of how long their response lagged behind this extreme flood. Ground beetles were sampled from 1998 to 1999 (pre-flood period) and from 2002 to 2006 (post-flood period) on 48 floodplain grassland plots with a stratified randomized samp...
Effect directed analysis and mixture effects of estrogenic compounds in a sediment of the river Elbe
Introduction Endocrine disrupting chemicals (EDCs) are present in the environment and can have serious effects on humans and wildlife. For the establishment of environmental quality guidelines and regulation of EDCs, a better understanding and knowledge of the occurrence and the behavior of environmental EDCs is necessary. The aim of the present study was to comprehensively identify substances that are responsible for the estrogenic effect of an environmental sediment sample taken from the river Elbe/Germany. Discussion The estrogenic effect of the organic sediment extract was determined using the yeast?estrogen?screen (YES). The sample was fractionated by liquid chromatography (LC) for effect directed analysis. The composition of estrogen-active fractions was further investigated by gas c...
Reliable well-characterised animal models of seizures are necessary in order to better understand the underlying pathophysiological mechanisms as well as to screen potential anticonvulsant drugs. We currently use the focal pilocarpine model as an acute limbic seizure model. Due to breeding problems at the vendor, and apparent changes in pilocarpine-induced seizure susceptibility, we were forced to change breeding locations and vendors over a period of 2 years. Male Wistar rats were either purchased from two breeding locations of Charles River Laboratories (France and Germany), or obtained from Harlan Laboratories (The Netherlands). In the present retrospective study we evaluated the impact of these vendor changes on ketamine dosing to establish anaesthesia, on pilocarpine-induced seizure s...
Lake Tegel (Berlin, Germany) is controlled by two main inflows: inflow #1 (River Havel) is heavily phosphorus-laden, whereas inflow #2 is an artificial confluence that includes discharge from a municipal wastewater treatment plant distinguished by high levels of phosphorus and pharmaceuticals. To reduce the phosphorus load on the lake, a phosphorus elimination plant (PEP) is situated at inflow #2. Moreover, the two inflows are short-circuited by a pipeline that transfers part of the inflow #1 water to the PEP and finally releases it into inflow #2. The pipeline and the PEP have contributed to a continuous reduction in the total phosphorus concentration of Lake Tegel in the past 25 years. We investigate the question of whether the existing lake pipeline can also be used to reduce the amount...
Thermal effects of electrically conductive deposits in melter
The radioactive waste processed by the Defense Waste Processing Facility melter at the Savannah river Site contains noble metal fission-products. Operation of waste-glass melters treating commercial power reactor wastes indicates that accumulation of noble metals on melter floors can lead to distortion of electric heating patterns, loss of power, and possible electrode damage. Changes in melter geometry have been developed in Japan and Germany to minimize these effects. The two existing melters for the US Department of Energy's Defense Waste Processing Facility were designed in 1982, before this effect was known or had been characterized. Modeling and pilot scale tests are being conducted in the Integrated DWPF melter system to determine if the effect is significant for melters processing defense wastes, and if the effect can be diagnosed and corrected without significant damage or changes to the melter design. This document provides a discussion of these tests.
Thermal effects of electrically conductive deposits in melter
The radioactive waste processed by the Defense Waste Processing Facility melter at the Savannah river Site contains noble metal fission-products. Operation of waste-glass melters treating commercial power reactor wastes indicates that accumulation of noble metals on melter floors can lead to distortion of electric heating patterns, loss of power, and possible electrode damage. Changes in melter geometry have been developed in Japan and Germany to minimize these effects. The two existing melters for the US Department of Energy`s Defense Waste Processing Facility were designed in 1982, before this effect was known or had been characterized. Modeling and pilot scale tests are being conducted in the Integrated DWPF melter system to determine if the effect is significant for melters processing defense wastes, and if the effect can be diagnosed and corrected without significant damage or changes to the melter design. This document provides a discussion of these tests.
Noble metal behavior during melting of simulated high-level nuclear waste glass feeds
Noble metals and their oxides can settle in waste glass melters and cause electrical shorting. Simulated waste feeds from Hanford, Savannah River, and Germany were heat treated for 1 hour in a gradient furnace at temperatures ranging from approximately 600{degrees}C--1000{degrees}C and examined by electron microscopy to determine shapes, sizes, and distribution of noble metal particles as a function of temperature. Individual noble metal particles and agglomerates of rhodium (Rh), ruthenium (RuO{sub 2}), and palladium (Pd), as well as their alloys, were seen. the majority of particles and agglomerates were generally less than 10 microns; however, large agglomerations (up to 1 mm) were found in the German feed. Detailed particle distribution and characterization was performed for a Hanford waste to provide input to computer modeling of particle settling in the melter.
We studied sequence variation in 16S rDNA in 204 individuals from 37 populations of the land snail Candidula unifasciata (Poiret 1801) across the core species range in France, Switzerland, and Germany. Phylogeographic, nested clade, and coalescence analyses were used to elucidate the species evolutionary history. The study revealed the presence of two major evolutionary lineages that evolved in separate refuges in southeast France as result of previous fragmentation during the Pleistocene. Applying a recent extension of the nested clade analysis (Templeton 2001), we inferred that range expansions along river valleys in independent corridors to the north led eventually to a secondary contact zone of the major clades around the Geneva Basin. There is evidence supporting the idea that the formation of the secondary contact zone and the colonization of Germany might be postglacial events. The phylogeographic history inferred for C. unifasciata differs from general biogeographic patterns of postglacial colonization previously identified for other taxa, and it might represent a common model for species with restricted dispersal. PMID:12389722
Acid rain: Rhetoric and reality
Acid rain is now one of the most serious environmental problems in developed countries. Emissions and fallout were previously extremely localized, but since the introduction of tall stacks policies in both Britain and the US - pardoxically to disperse particulate pollutants and hence reduce local damage - emissions are now lifted into the upper air currents and carried long distances downwind. The acid rain debate now embraces many western countries - including Canada, the US, England, Scotland, Wales, Sweden, Norway, Denmark, West Germany, the Netherlands, Austria, Switzerland - and a growing number of eastern countries - including the Soviet Union, Poland, East Germany, and Czechoslovakia. The problem of acid rain arises, strictly speaking, not so much from the rainfall itself as from its effects on the environment. Runoff affects surface water and groundwater, as well as soils and vegetation. Consequently changes in rainfall acidity can trigger off a range of impacts on the chemistry and ecology of lakes and rivers, soil chemistry and processes, the health and productivity of plants, and building materials, and metallic structures. The most suitable solutions to the problems of acid rain require prevention rather than cure, and there is broad agreement in both the political scientific communities on the need to reduce emissions of sulfur and nitrogen oxides to the atmosphere. Book divisions discuss: the problem of acid rain, the science of acid rain, the technology of acid rain, and the politics of acid rain, in an effort to evaluate this growing global problem of acid rain.
A modified soil water based Richards equation for layered soils
Most Soil-Vegetation-Atmosphere-Transfer (SVAT) models like TERRA-ML (implemented e.g. in the CCLM model (www.clm-community.eu)) use the soil moisture based Richards equation to simulate vertical water fluxes in soils, assuming a homogeneous soil type. Recently, high-resolution soil type datasets (e.g. BüK 1000, only for Germany (Federal Institute for Geosciences and Natural Resources, BGR, www.bgr.bund.de) or Harmonized World Soil Database (HWSD, version 1.1, FAO/IIASA/ISRIC/ISSCAS/JRC, March 2009)) have been developed. Deficiencies in the numerical solution of the soil moisture based Richards equation may occur if inhomogeneous soil type data is implemented, because there are possibly discontinuities in soil moisture due to various soil type characteristics. One way to fix this problem is to use the potential based Richards equation, but this may lead to problems in conservation of mass. This presentation will suggest a possible numerical solution of the soil moisture based Richards equation for inhomogeneous soils. The basic idea is to subtract the equilibrium state of it from soil moisture fluxes. This should reduce discontinuities because each soil layer aspires the equilibrium state and therefore differences might be of the same order. First sensitivity studies have been done for the Main river basin, Germany.
Methanol shutdowns cause anxiety
European methanol players face an anxious few weeks as unscheduled outages combine with planned turnarounds to make an increasingly tight market. Global markets are also described as tightening, with production problems widely reported in North America. Several European producers were in the middle of shutdown periods when problems at Condea`s 400,000-m.t./year unit at Wesseling, Germany reportedly caused production to run at only 50% of capacity. In addition, the methanol plant at the Leuna refinery is said to be operating at only 60% of capacity, and one producer has had to extend a turnaround period. River levels in Germany are also low, putting pressure on shipments from Rotterdam. {open_quotes}This is a very difficult situation and we`re living hand to mouth,{close_quotes} says one producer. Producer sources report bids from consumers up to DM280/m.t. T2 fob Rotterdam, but they are unable to obtain extra product. Derivatives makers may also face problems: One methyl tert-butyl ether producer predicts prices {open_quotes}may hit the roof{close_quotes} once feedstock sourcing problems hit home.
A large-scale conversion of permanent grassland into arable land was undertaken after World War II in West Germany to increase agricultural productivity. In the course of this process the total meadowland area decreased during the period 1965-1985 by 1.5 x 10{sup 6} ha, or 6% of the country`s total area. The environmental implications of this large-scale conversion have so far received little attention; the present study examined some of these implications. A review of research on soil physical and chemical aspects of the conversion of permanent grassland into arable land reveals that such a large-scale conversion may have considerable effects upon the environment. For example, due to the mineralization of soil organic matter a release of NO{sub 3} and CO{sub 2} into the environment can be expected on the order of 10 t N and 100 t C per hectare. Environmentally equally severe, if not worse, is the increased amount of surface runoff that can be expected from converted grassland soils in arable land during winter because of surface sealing and soil compaction. This increased surface runoff, in combination with the runoff from other farmland, may be one of the reasons for the growing frequency of floods along major German rivers in recent years. In view of the lasting adverse environmental effects of permanent grassland conversion and the subsidized agricultural surpluses in Germany today, we conclude that a reconversion of arable land into permanent grassland may be beneficial both environmentally and economically. (orig.)
This is the first documentation of a heat shock protein (hsp) response in sponges. Subjecting the freshwater sponge Ephydatia fluviatilis to temperature stress (18 to 33 C; 2 h) resulted in an increased expression (>10 times) of the M{sub r}70,000 (hsp70). The induction of hsp70 could be demonstrated on the level of gene expression and by quantification of the hsp70 protein. Temperature stress also resulted in a 25% reduction of sponge cell proliferation. A mixture of nonionic organic compound was extracted from water from the polluted Schwarzbach River (S. Hesse, Germany) by adsorption onto XAD-7 resin. Concentrations of this Schwarzbach River water extract at two and four items ambient levels resulted in decreases in cell proliferation by 53.6 and 99.4%, respectively. However, when cells were exposed to these levels of the Schwarzbach River water extract directly following a temperature stress (33 C for 2 h), cell proliferation was less affected by the extract than the absence of the temperature stress. In addition, the combination of temperature stress and exposure to the Schwarzbach River water extract resulted in higher levels of hsp70 than were observed for each stressor by itself. Northern and Western blotting as well as precipitation assay confirmed the interaction between heat treatment and exposure to different amounts of nonionic organic pollutants on the level of mRNA and protein expression of hsp70. From these data the authors conclude that a sublethal treatment of sponge with heat results in a higher tolerance of the animals to chemical stressors. These results are relevant to the real-world situation where organisms are often exposed simultaneously to a variety of stressors, in contrast to many laboratory exposures that aim to elucidate the effects of individual stressors.
Data on heavy metals in the Elbe River
In 1979/80 the Arbeitsgemeinschaft fuer die Reinhaltung der Elbe (ARGE Elbe) had carried out a systematic investigation. The concentrations of the heavy metals mercury, cadmium, lead, zinc, copper, arsenic and chromium were investigated in the water and the sediments of the Elbe River from Schnackenburg until Scharhoern. Additionally, the mercury, cadmium and lead contents in eight different organs of Elbe breams were determined. This can be assessed as follows: the Elbe River is highly polluted by heavy metals from the area above Schnackenburg. Within the tidal zone from Geesthacht until Scharhoern the heavy metal concentrations of the unfiltered river water were below the standards valid for drinking water. In comparison to other investigated metals the mercury concentrations showed high fluctuations. Sporadic measurements near Cuxhaven and Scharhoern showed extremely high values for mercury and cadmium. The heavy metals are partly added to suspended chemical agents. That is why the highest heavy metal concentrations in sediments were observed in low-turbulence zones. There were lower contents in those sediments found further inland. Compared with the natural ''clay-ground standard'' the Elbe sediments are highly polluted with mercury and cadmium within the stretch of Schnackenburg-Hamburg. As a biological indicator the fish species of breams was investigated. The heavy metal concentrations, especially mercury, observed in the fish organs show a clear relation to the sediment pollution in the fishing zones. It can be said that the heavy metal pollution of the Elbe River comes mainly from the area north of the F.R. of Germany.
Georeferenced model simulations efficiently support targeted monitoring
The European Water Framework Directive (WFD) demands the good ecological and chemical status of surface waters. To meet the definition of good chemical status of the WFD surface water concentrations of priority pollutants must not exceed established environmental quality standards (EQS). Surveillance of the concentrations of numerous chemical pollutants in whole river basins by monitoring is laborious and time-consuming. Moreover, measured data do often not allow for immediate source apportionment which is a prerequisite for defining promising reduction strategies to be implemented within the programme of measures. In this context, spatially explicit model approaches are highly advantageous because they provide a direct link between local point emissions (e.g. treated wastewater) or diffuse non-point emissions (e.g. agricultural runoff) and resulting surface water concentrations. Scenario analyses with such models allow for a priori investigation of potential positive effects of reduction measures such as optimization of wastewater treatment. The geo-referenced model GREAT-ER (Geography-referenced Regional Exposure Assessment Tool for European Rivers) has been designed to calculate spatially resolved averaged concentrations for different flow conditions (e.g. mean or low flow) based on emission estimations for local point source emissions such as treated effluents from wastewater treatment plants. The methodology was applied to selected pharmaceuticals (diclofenac, sotalol, metoprolol, carbamazepin) in the Main river basin in Germany (approx. 27,290 km²). Average concentrations of the compounds were calculated for each river reach in the whole catchment. Simulation results were evaluated by comparison with available data from orienting monitoring and used to develop an optimal monitoring strategy for the assessment of water quality regarding micropollutants at the catchment scale.
Within the Taklimakan Desert of Northwestern China, an area renowned for its extreme climate and vulnerable ecosystems, lies one of the largest inland rivers in the world, the Tarim River. Because the Tarim River is located in a remote area from the oceans, rainfall is extremely rare (less than 50 mm per year) but potential evaporation is high (3000 mm). Thus, the major source of water discharge comes from snowmelt and glacier-melt in the mountains. Though the water discharge into the Tarim River has experienced an increase over the past ten years, global climate change forecasts predict this water supply to decline within the century. The Tarim River is the major source of water in Northwestern China, and has become the hub of many economic activities related to agriculture and urban life. Over the past 50 years increased activity in the area has led to a severe decline in river flow. Both human and natural ecosystems have been impacted by water diversions. Since rainfall is rare, the majority of vegetation in this area depends solely on groundwater for survival, and plants are experiencing stress caused by decreasing groundwater levels. Recently nearby cities have experienced severe dust storms caused by the shrinking of the vegetative region along the river. SuMaRiO (Sustainable Management of River Oases) is a bundle project between Germany and China working to contribute to a sustainable land management which explicitly takes into account ecosystem functions (ESF) and ecosystem services (ESS). In a transdisciplinary research process, SuMaRiO will identify realizable management strategies, considering social, economic and ecological criteria. SuMaRiO is developing tools to work with Chinese decision makers to implement sustainable land management strategies. In addition, research is being conducted to estimate climate change impacts, floodplain biodiversity, and water runoff characteristics. The overarching goal of SuMaRiO is to support oasis management along the Tarim River under conditions of climatic and societal changes. A main deliverable of SuMaRiO will be an indicator-based decision support system (DSS) that allows a Sustainability Impact Assessment (SIA) within regional planning. This SIA will integrate the many specific research results obtained by SuMaRiO in the areas ESS/ESF, water resources and use, and land use including urban, agricultural and natural areas. It will take into account the perspectives of all relevant actors in the problem field of land and water management in the Tarim River Basin, which will be elicited and analyzed by actor modeling. Then, under given scenario assumptions, possible actions and their impacts are estimated in a semi-quantitative way. The SuMaRiO project (www.sumario.de) started in March 2011. First results of different interrelated work packages are presented. Especially an introduction to the model structure to estimate water demand, water quality and biomass production in the Tarim region is given. Additionally, an evaluation of ecosystem services and ecosystem functions along the Tarim River is shown.
Simulating Suspended Silt Concentrations in the Ems Estuary, The Netherlands
1 Introduction The Ems Estuary is situated in the North-east Netherlands on the border with Germany. Its area, including the tidal river and excluding the outer delta, is ± 500 km2. The area of the outer delta is ± 100 km2. The length of the estuary from the inlet to the town of Leer in Germany is approximately 75 km. The mean tidal range varies over years (de Jonge, 1992), but is approximately 2.3 m near the island of Borkum (tidal inlet) and approximately 3.2 m near the town of Emden in Germany. The estuary receives water from the rain-fed River Ems (approximately 115 m3/s on average). A second much smaller freshwater input emanates from the small canalized river Westerwoldsche Aa (12.5 m3/s on average). These discharges vary strongly within and between years. The result of the interaction between freshwater discharge and seawater brought in by the tide is a salinity gradient, the length and position of which is strongly dependent on the water discharge by the rivers. The present morphology of the estuary is the result of natural processes such as tidal currents, wind and wave driven currents and river discharge, resulting in sediment trans-port and sedimentation and erosion patterns. These natural processes are affected by human interferences like maintenance dredging of the navigation channels, land reclamation, building of dikes, etc. The greatest changes in the last 50 years in the physical functioning of the Ems estuary have been the increased sea level and tidal range, the increased amplitude and frequency of storm surge, and greatly increased turbidity and sediment concentrations (particularly near the estuarine turbidity maximum). Much of the changes can be traced directly or indirectly to anthropogenic influence. 2 Aim and approach We studied the hydrodynamics and morphodynamics of the Ems estuary. One of the aims was to gain more insight in the behaviour of the suspended silt concentrations in the estuary and the anthropogenic influence thereon. We applied a beta release of the state-of-the-art Delft3D numerical model for this purpose. The model includes a new sediment transport module published by Van Rijn (2007, 2007a). The vertical distribution of the suspended sediment concentration in the transport module depends on the effective settling velocity of the sediment, the bed shear velocity and the turbulence. The silt transport is simulated every time step together with the flow (online), which means that the impact of the calculated concentration is accounted for in the hydrodynamics. Major challenge was to accurately simulate the relatively high suspended silt concentrations observed near the estuarine turbidity maximum. 3 Results The paper will compare observed and predicted water levels, salinity distributions and suspended silt concentrations. Figure 1 shows an example of predicted depth-averaged suspended silt concentrations during spring high tide without waves. Under these conditions the depth-averaged concentrations decrease from about 2 kg/m3 in the Unterems (upstream of Emden) to almost zero seaward of Borkum. PIC Figure 1: Figure 2 Observed and predicted salinities in the upper part of the water column along the estuary The presence of waves will increase the concentrations on the shoals but have a limited effect on the concentrations in the channels. Figure 2 presents observed and predicted salinities along the estuary. The model results encouragingly agree with the observations. PIC 4 References De Jonge, V.N., 1992. Tidal flow and residual flow in the Ems estuary. Estuarine, Coastal and Shelf Science, 34: 1-22. Van Rijn, L.C., 2007. Unified View of Sediment Transport by Currents and Waves. I: Initiation of Motion, Bed Roughness, and Bed-Load Transport. Journal of Hydraulic Engineering, 133(6): 649-667. Van Rijn, L.C., 2007a. Unified View of Sediment Transport by Currents and Waves. II: Suspended Transport. Journal of Hydraulic Engineering, 133(6): 668-689.
The Sainte-Marie-aux-Mines (SMM) mines host one of the most famous and oldest silver deposits in Europe. The SMM district is located in the central part of the Vosges mountains, France, within gneiss and granites of the Moldanubian zone. The SMM district includes the Neuenberg E-W vein-type Cu-Ag-As/Pb-Zn deposit and the Altenberg N-S vein-type Pb-Zn-Ag deposit. Deposition of the SMM hydrothermal mineralization occurred under a brittle tectonic regime that might be connected to neo-Variscan and/or post-Variscan tectonics, in a similar way as the polymetallic vein deposits of the Black Forest, Germany. A structural study was done in the Neuenberg area, in the vicinity of the Saint-Jacques vein, and within the Gabe Gottes mine, considering the orientation, extent, chronology and density of faults as well as the nature of the infilling minerals. In the Gabe-Gottes mine, the Saint-Jacques vein comprises multiple successive, sub-parallel subvertical veinlets with gangue minerals, mostly carbonates and quartz, and metal-bearing phases, sulfides and sulfosalts. The veinlets are 2 to 50 cm thick and strike N80° to N110°, the earlier veins slightly dipping towards the north, and the latest one, to the south. Seven systems of faults were identified, which may be classified into three major groups formed respectively before, during and after the main stage of ore deposition: a) Pre-mineralization faults - These consist of sinistral NE-SW strike-slip faults, and NW-SE and NE-SW steeply dipping normal faults. These could be related to Carboniferous events considering their relationships with the granitoid intrusives present in the mine area (Brézouard leucogranite ~329 Ma), and the extensional tectonics developed during exhumation processes. b) Faults associated with the main ore-deposition - These faults could be related to late-Hercynian processes from compressional to extensional tectonic regimes. Mineralization controlling faults consist of dextral and sinistral E-W strike-slip faults. Early strike-slip movements are assessed by the presence of striated iron oxides, the crystallization of which is considered to be early during the ore deposition process. Mineralizing fluids were probably fluorine-rich as F-bearing minerals, sericite, chlorite and apatite are present in the chlorite zone associated with early sulphide-rich ores. The E-W mineralized faults are only easily compatible with the tectonics known in Permian times. c) Late-stage faults - These could be related to the numerous changes in plate configuration which occur during the Mesozoic and Cenozoic times, in accordance with the creation of the Paris basin, the opening of Atlantic ocean and Rhine Graben, as well as with the Tethys closure. For example, the vertical lineation superposed on an horizontal lineation observed on mineralized rocks indicate reactivation of the former E-W mineralized veins under a normal movement. The latter may correspond to an extensive regime known during Oligocene times. On the other hand, one of the major late-stage faults strikes N-S and is related to a dextral strike-slip system, which could be considered as Miocene. It is expected that fluid remobilization occurred during fault reactivation, a process which could have led to successive ore deposition following the emplacement of the major E-W mineralized veins. A fluid inclusion study in the gangue minerals of the Gabe Gottes is now under investigation. This together with isotopic studies will help to determine the source of the mineralizing fluids, as well as the conditions of ore deposition. Keywords: Faults, polymetallic mineralization, variscan orogeny, Gabe-Gottes, Sainte-Marie-aux-Mines, Vosges, F-rich fluids.
The aim of this study was to evaluate exposure and health outcome of children living close to industrial sources. Exposure and health outcome was assessed in nearly 1000 children at school beginner age living in the vicinity of industrial sources of three different hot spots (Duisburg North, Duisburg South and Dortmund Hörde) and in a rural area of North Rhine Westphalia (NRW), Germany. The cross-sectional study was undertaken between March and May 2000. Exposure assessment comprised modelling of ambient air quality data and human biomonitoring (HBM). Depending on the site-specific contaminants, HBM included the measurement of PAH (polycyclic aromatic hydrocarbons) and benzene metabolites in urine as well as heavy metals in blood and urine. Markers of early effects were DNA strand breaks as measured by the comet assay in lymphocytes and excretion of alpha-1-microglobuline and N-acetyl-beta-D-glucosamidase in urine. Health outcome was assessed by questionnaire, lung function test, dermatological examination as well as by RAST (radioallergosorbent test), patch tests and prick tests. The influence of exposure variables on biomarkers and health outcome was measured by means of multiple linear and logistic regression analysis. The most striking results were as follows. Children living close to a coke oven plant (Duisburg North) had increased levels of PAH metabolites in urine, and DNA exposure was increased. Children living at the Dortmund Hörde hot spot (increased chromium and nickel ambient air levels from a steel mill) revealed a high prevalence of allergic sensitizations. Sensitization, especially against nickel, was associated with the current internal nickel exposure, and nickel in ambient air was positively associated with the frequency of allergic symptoms. Children from the hot spot areas had increased specific airway resistance and total lung capacity as compared to those of the reference area. In Duisburg North particularly, specific airway resistance and total lung capacity significantly increased with increasing TSP (total suspended particulate). The only positive associations between external and internal exposure were found between benzo[a]pyrene in ambient air and 1-hydroxypyrene in urine, and between lead in ambient air and in the blood of the children. It is concluded that despite improvements of the general air quality during the last decades, living in the vicinity of industrial sources results to some extent in increased internal contaminant exposure and in effects on health outcome. Still ongoing studies are aimed to find out whether the increased PAH and DNA exposure of children from Duisburg North had decreased after the coke oven plant had been shut down in 2003, and if the striking results on the high prevalence of allergic sensitization can be confirmed by introducing an expanded cross-sectional study at four hot spots with increased chromium and nickel ambient air levels. PMID:17412639
By evaluating the primary data from 20 regional institutions in the period 1984-2002 about persistent chlorinated hydrocarbons (PCHC) in fishes (eels, Anguilla anguilla; breams, Abramis brama; barbs, Barbus barbus and reaches, Rutilus rutilus), sediment and suspended matter it was tried to mark the burdens and substance profiles for sampling sites on the river Rhine and rivers in BW, Hess, RP and NRW. The compounds investigated were the isomere di-, tri- and tetrachlorobenzenes, penta- and hexachlorobenzene, octachlorostyrene (OCS), hexachlorobutadiene (HCBD) as well as the 6 DIN (IUPAC, Ballschmiter) congeners of the PCB, substances which were - as to the REACH - described as PBT, partly as vPvB substances and regarded as ''priority harmful substances'' (PCBz; HCB, HCBD), respectively. The statistically elaborated single data were summarized in distance profiles and time series, aiming at marking local and regional immissions as well as hints to their origin and current importance. The background of these efforts is the lack of specialized publications about technical synthesis or compulsory yield of the compounds concerning kind, amount and period. Especially tetrachlorobenzene (mainly 1,2,4,5-TeCBz) and HCBD could be defined as indicator substances for past and recent technical synthesis of chloroorganic compounds. The higher chlorinated PCB congeners no. 138, 153 and 180 (HPCB) proved very persistent. The sites of chemical industry in the vicinity of the sampling points Rheinfelden, Grenzach, Lampertheimer Altrhein, Biebesheimer Rhein, Muendung Schwarzbach, Bischofsheim and Griesheim (Main), Hitdorf, Duisburg-Homberg und Huels (Lippe) could be made transparent by maxima and special substance patterns. (orig.) [German] Durch Auswertung von Primaerdaten ueber persistente chlorierte Kohlenwasserstoffe (PCKW) in Fischen (Aale, Anguilla anguilla; Brachsen, Abramis brama; Barben, Barbus barbus und Rotaugen, Rutilus rutilus), Sediment und Schwebstoffen, die in 20 zumeist Landesinstitutionen z. T. im Zeitraum von 1984-2002 erhoben worden waren, wurde der Versuch unternommen, die Belastungshoehen und Stoffmusterprofile fuer Probenahmelokalitaeten am Rhein und Fluessen in BW, Hess, RP und NRW kenntlich zu machen. Die untersuchten Verbindungen waren die isomeren Di-, Tri- und Tetrachlorbenzene, Penta- und Hexachlorbenzen, Ochtachlorstyren (OCS), Hexachlorbutadien (HCBD) sowie die 6 DIN-(IUPAC-, Ballschmiter)Kongenere der PCB, Substanzen, die zumeist im Sinne von REACH als PBT-, z. T. als vPvB-Stoffe bezeichnet wurden bzw. als ''prioritaer gefaehrliche Stoffe'' (PCBz, HCB, HCBD) eingestuft sind. Die statistisch verrechneten Einzeldaten wurden zu Streckenprofilen und Zeitreihen verarbeitet, mit dem Ziel, lokale oder regionale Immissionen, Hinweise zu ihrer Entstehung und gegenwaertigen Bedeutung kenntlich zu machen. Hintergrund dieser Bestrebungen ist, dass Fachpublikationen ueber technische Synthesen oder Zwangsanfall der Verbindungen nach Art, Menge und Zeitraum nicht vorliegen, was als Defizit zu betrachten ist. Besonders Tetrachlorbenzen (hauptsaechlich das 1,2,4,5-TeCBz) und das HCBD konnten als Indikatorsubstanzen fuer historische und rezente technische Synthesen chlororganischer Verbindungen sichtbar gemacht werden. Die hoeher chlorierten PCB-Kongenere Nr. 138, 153 und 180 (HPCB) erwiesen sich als ausserordentlich persistent. Die Chemiestandorte im Umfeld der Probenahmelokalitaeten Rheinfelden, Grenzach, Lampertheimer Altrhein, Biebesheimer Rhein, Muendung Schwarzbach, Bischofsheim und Griesheim (Main), Hitdorf, Duisburg-Homberg und Huels (Lippe) konnten durch Maxima und spezielle Stoffmusterverteilungen transparent gemacht werden. (orig.)
Hoyler M., Freytag T. and Mager C. Connecting Rhine-Main: the production of multi-scalar polycentricities through knowledge-intensive business services, Regional Studies. Most of the literature on polycentric urban regions has focused on the analysis of intra-regional rather than external linkages, while research on the emergence of a 'world city network' has analysed external city relations without explicitly addressing city-regional contexts. This paper aims to bring both perspectives together. Drawing on Taylor's interlocking network model, it presents a first analysis of multi-scalar inter-city connectivities within a specific city-regional context. Central to the analysis is the question how knowledge-intensive business service firms in Rhine-Main connect this multi-nodal metropolitan...
The Pb, Sr and Nd isotopic compositions of biomonitors (lichen, moss, bark) and soil litter from different regions in the Rhine valley, as well as of 206Pb/207Pb and 87Sr/86Sr isotope ratios are positively correlated. Most polluted samples from traffic-rich urban environments have the least radiogenic Pb and Sr isotopic compositions with 206Pb/207Pb and 87Sr/86Sr ratios of 1.11 and 0.7094, respectively. These ratios are very different from those of the atmospheric baseline for the Vosges mountains and the Rhine valley (206Pb/207Pb: 1.158-1.167; 87Sr/86Sr: 0.719-0.725; &z.epsiv;Nd: -7.5 to -10.1). However, this study indicates that the baseline of the atmospheric natural Pb and Sr isotopic compositions is affected by anthropogenic (traffic, industrial and urban) emissions even in remote are...
This report issued by the General Energy Research Department and its Laboratory of Atmospheric Chemistry at the Paul Scherrer Institute (PSI) reports on the results obtained from the measurement of fine-dust quantities and composition in the cantons of eastern Switzerland and the upper Rhine valley during the winter. The PSI analysed the samples on behalf of the Swiss cantons, Vorarlberg (Austria) and the Principality of Liechtenstein. The mobile equipment used and the measurements made in the Rhine Valley between Lake Constance and Chur as well as in the City of Zurich are presented and discussed. The results of the measurements are presented in graphical form and the chemical composition of the pollutants at the different locations are discussed. Details of the instruments used and the routes taken are noted in an appendix.
Brown coal of the quality found in the Rhine Mining District has a wide range of applications. Brown coal coke is used, for example, for biological wastewater purification of as an aborber or catalyst. Crude brown coal refined to fluidised-bed brown coal permits low emission values in circulating fluidised-bed boiler systems. State-of-the-art technology even permits the operation of such plants as closed systems. (orig.)
Coal mining and the environment. Bergbau und Umwelt
The papers facilitate access to the relation between black coal mining and different environmental aspects. The examples used to describe the problem and adequate solutions represent the situation of the Saar region and the North-Rhine Westphalian coal district. Among others, they point out the environmental effects of coal mines and deal with the environmental impact statement, the effects of landscaping on ecological functions and the securing of the resources left behind in shut-down coal districts.
With the crane house 1 directly at the Rhine and with view to the Dome of Cologne, a spectacular and innovative office building was built at the beginning of the year 2009. The crane house was awarded as the world-best office building on the international real estate fair MIPIM 2009 in Cannes (France). An indirect (adiabatic) evaporative cooling of the exhaust air for the cooling of the supply air provides an elevated energy efficiency with the air conditioning of the crane house.
Calibration of a model to calculate heat transport in an aquifer
Artifical lakes due to dredging cause the infiltration of warm water or cold water into the aquifer during summer or winter time, respectively. The temperature distribution within the aquifer has been measured in the Rhine valley near Bonn. These data were used to calibrate a numerical model, which describes the transport phenomena on a larger scale. The assumption of increasing hydrodynamic dispersion with distance from the source is necessary to fit the data. Furthermore, an anisotropic behaviour of the hydrodynamic dispersion is determined.
Tracking Down the Business Cycle a dynamic factor model for Germany 1820-1913
We use a Bayesian dynamic factor model to measure Germany’s pre World War I economic activity. The procedure makes better use of existing time series data than historical national accounting. To investigate industrialization we propose to look at comovement between sectors. We find that Germany’s in...
FBIS report. Science and technology: Europe/international, November 3, 1995
;Partial Contents: Netherlands: Program Gives Priority to Materials Research; Germany: Minister Ruettgers Outlines Biotechnology R&D Priorities; Germany: Structure of Defense-Related R&D Detailed; Germany: New Designs in Fiber Lasers Explored; France: CEA Carries Out Research on Cold Fusion; Germany: Research Society`s R&D Programs for 1996 Summarized; and EU Council Adopts Advanced Television Services Action Plan.
Two exemplary mesoscale river catchments at the northern slope of the High Venn mountains in the country triangle of Belgium, the Netherlands and Germany are compared. Here, an analysis of the fluctuations and temporal-spatial dispersal patterns of concentrations of inorganic nutrient compounds in relation to a satellite-derived land use classification has been carried out. The three countries are showing distinct discrepancies in land use patterns, water management and the evolution of the cultural landscape. Therefore, the ecological conditions of the fluvial systems vary considerably and are controlled by high nutrient influx from agriculture and settlements via point and non-point sources. In addition, seasonal effects and complex transport mechanisms have an impact. Our results emphasize the need to improve the water quality with the aid of an integrated catchment management, as it is provided by the European water framework directive. The reduction of nutrient inputs from non-point sources plays a major role in this task. Furthermore, the ecological classification of river systems in frontier areas should involve country-specific characteristics as the form of land use, the settlement structures, or the people's perception of the natural and cultural landscape. Such catchment parameters are apparently of significance for the water quality, their emphasis has to be specified in future investigations.
Environmental Assessment of Urgent-Relief Acceptance of Foreign Research Reactor Spent Nuclear Fuel
The Department of Energy has completed the Environmental Assessment (EA) of Urgent-Relief Acceptance of Foreign Research Reactor Spent Nuclear Fuel and issued a Finding of No Significant Impact (FONSI) for the proposed action. The EA and FONSI are enclosed for your information. The Department has decided to accept a limited number of spent nuclear fuel elements (409 elements) containing uranium that was enriched in the United States from eight research reactors in Austria, Denmark, Germany, Greece, the Netherlands, Sweden, and Switzerland. This action is necessary to maintain the viability of a major US nuclear weapons nonproliferation program to limit or eliminate the use of highly enriched uranium in civil programs. The purpose of the EA is to maintain the cooperation of the foreign research reactor operators with the nonproliferation program while a more extensive Environmental Impact Statement (EIS) is prepared on a proposed broader policy involving the acceptance of up to 15,000 foreign research reactor spent fuel elements over a 10 to 15 year period. Based on an evaluation of transport by commercial container liner or chartered vessel, five eastern seaboard ports, and truck and train modes of transporting the spent fuel overland to the Savannah River Sits, the Department has concluded that no significant impact would result from any combination of port and made of transport. In addition, no significant impacts were found from interim storage of spent fuel at the Savannah River Site.
Quasi 2D hydrodynamic modelling of the flooded hinterland due to dyke breaching on the Elbe River
In flood modeling, many 1D and 2D combination and 2D models are used to simulate diversion of water from rivers through dyke breaches into the hinterland for extreme flood events. However, these models are too demanding in data requirements and computational resources which is an important consideration when uncertainty analysis using Monte Carlo techniques is used to complement the modeling exercise. The goal of this paper is to show the development of a quasi-2D modeling approach, which still calculates the dynamic wave in 1D but the discretisation of the computational units are in 2D, allowing a better spatial representation of the flow in the hinterland due to dyke breaching without a large additional expenditure on data pre-processing and computational time. A 2D representation of the flow and velocity fields is required to model sediment and micro-pollutant transport. The model DYNHYD (1D hydrodynamics) from the WASP5 modeling package was used as a basis for the simulations. The model was extended to incorporate the quasi-2D approach and a Monte-Carlo Analysis was used to conduct a flood sensitivity analysis to determine the sensitivity of parameters and boundary conditions to the resulting water flow. An extreme flood event on the Elbe River, Germany, with a possible dyke breach area was used as a test case. The results show a good similarity with those obtained from another 1D/2D modeling study.
In contrast to younger periods, studies integrating archaeological and environmental records for the Palaeolithic are still rare. Especially our knowledge about interactions between the drastic climatic/environmental changes and cultural developments during the Late Glacial is very limited. This multidisciplinary case study from river Jeetzel, a western Elbe tributary in Northern Germany, combines high resolution palaeoenvironmental investigations with fine-scaled archaeological research on stratified and surface sites. Various dating methods (palynostratigraphy, radiocarbon- and OSL-dating) and analyses of environmental and climatological proxies (pollen and plant macro-remains, ostracods, diatoms and green algae) on river palaeochannel sediments allow detailed reconstruction of interactions between Late Glacial climate, vegetation and fluvial developments. Biostratigraphical analyses on stratified archaeological sites and dating of charcoal / bone fragments from artefact scatters place the Late Palaeolithic occupation of Early Federmesser groups in an environmental context. Thus the former production of hitherto unknown amber art (amongst others a figurine representing a moose) can be ascribed to the Older Dryas and Early Allerød, which are the periods of main Late Glacial afforestation. Therewith our investigations suggest that Final Palaeolithic cultural changes may have been triggered by climatic and environmental transformations.
Debris control at hydraulic structures in selected areas of Europe. Interim report No. 1
This interim report contains a review of methods for managing floating debris that have been tested, and employed, at hydraulic structures in Europe. The information is taken from papers, site observations and discussions with researchers and engineers at three major European hydraulic research centers: Delft Hydraulics, The Netherlands; The Hydraulics Institute of the Technical University of Munich, Germany; and the Institute of Hydraulics, Hydrology and Glaciology at the Technical University of Zurich, Switzerland. The interim report is divided into four sections covering different types of structure and the various solutions employed. Chapter one examines run-of-river debris detention and diversion devices. Chapter two discusses debris clogging problems at spillways and assess optimum spillway design with regard to passing debris. Chapter three describes the problem of debris collection at a river hydro-electric power station and examines the solutions tested to alleviate the problem. Chapter four reviews trashrack design criteria, raking equipment and rack vibration problems. The purpose of the European element of this project, together with an ongoing investigation of debris management at US structures, is the assessment of the major debris management systems that have been employed at hydraulic structures.
Runoff changes in Czech headwater regions after deforestation induced by acid rains
Tendencies in water regime resulting from land-use change represent an important subject for research and in the region of so called Black Triangle at the borders of Czech Republic, Germany and Poland urgent practical problem. Namely extensive deforestation in Czech hilly basins induced by acid rains, which appeared in seventies and eighties, requires attention. Discussions among professionals and public, sometimes having emotional character, took place after large floods on the rivers Odra and Morava in 1997 and in Vltava and Elbe river basins in August 2002. The influence of deforestation induced by acid rains in the Central Europe has been considered as important contribution to disastrous character of floods. Simulations of rainfall-runoff process in several catchments and experimental basins in two distinct headwater regions along German borders, with different extent of deforestation have been carried out using daily time series up to 40 years long. The outputs of two hydrological models of different structure have been compared in these investigations: - the conceptual model SAC-SMA - Sacramento soil moisture accounting - physically based 1- D model BROOK´90 The differences between observed and simulated discharge, which could show the tendencies in the runoff have been followed. They indicate increase of runoff after deforestation.
An ensemble forecasting system seeks to assess and to communicate the uncertainty of hydrological predictions by proposing, at each time step, an ensemble of forecasts from which one can estimate the probability distribution of the predictant (the probabilistic forecast), in contrast with a single estimate of the flow, for which no distribution is obtainable (the deterministic forecast). In the past years, efforts towards the development of probabilistic hydrological prediction systems were made with the adoption of ensembles of numerical weather predictions (NWPs). The additional information provided by the different available Ensemble Prediction Systems (EPS) was evaluated in a hydrological context on various case studies (see the review by Cloke and Pappenberger, 2009). For example, the European ECMWF-EPS was explored in case studies by Roulin et al. (2005), Bartholmes et al. (2005), Jaun et al. (2008), and Renner et al. (2009). The Canadian EC-EPS was also evaluated by Velázquez et al. (2009). Most of these case studies investigate the ensemble predictions of a given hydrological model, set up over a limited number of catchments. Uncertainty from weather predictions is assessed through the use of meteorological ensembles. However, uncertainty from the tested hydrological model and statistical robustness of the forecasting system when coping with different hydro-meteorological conditions are less frequently evaluated. The aim of this study is to evaluate and compare the performance and the reliability of 18 lumped hydrological models applied to a large number of catchments in an operational ensemble forecasting context. Some of these models were evaluated in a previous study (Perrin et al. 2001) for their ability to simulate streamflow. Results demonstrated that very simple models can achieve a level of performance almost as high (sometimes higher) as models with more parameters. In the present study, we focus on the ability of the hydrological models to provide reliable probabilistic forecasts of streamflow, based on ensemble weather predictions. The models were therefore adapted to run in a forecasting mode, i.e., to update initial conditions according to the last observed discharge at the time of the forecast, and to cope with ensemble weather scenarios. All models are lumped, i.e., the hydrological behavior is integrated over the spatial scale of the catchment, and run at daily time steps. The complexity of tested models varies between 3 and 13 parameters. The models are tested on 29 French catchments. Daily streamflow time series extend over 17 months, from March 2005 to July 2006. Catchment areas range between 1470 km2 and 9390 km2, and represent a variety of hydrological and meteorological conditions. The 12 UTC 10-day ECMWF rainfall ensemble (51 members) was used, which led to daily streamflow forecasts for a 9-day lead time. In order to assess the performance and reliability of the hydrological ensemble predictions, we computed the Continuous Ranked probability Score (CRPS) (Matheson and Winkler, 1976), as well as the reliability diagram (e.g. Wilks, 1995) and the rank histogram (Talagrand et al., 1999). Since the ECMWF deterministic forecasts are also available, the performance of the hydrological forecasting systems was also evaluated by comparing the deterministic score (MAE) with the probabilistic score (CRPS). The results obtained for the 18 hydrological models and the 29 studied catchments are discussed in the perspective of improving the operational use of ensemble forecasting in hydrology. References Bartholmes, J. and Todini, E.: Coupling meteorological and hydrological models for flood forecasting, Hydrol. Earth Syst. Sci., 9, 333-346, 2005. Cloke, H. and Pappenberger, F.: Ensemble Flood Forecasting: A Review. Journal of Hydrology 375 (3-4): 613-626, 2009. Jaun, S., Ahrens, B., Walser, A., Ewen, T., and Schär, C.: A probabilistic view on the August 2005 floods in the upper Rhine catchment, Nat. Hazards Earth Syst. Sci., 8, 281-291, 2008. Matheson, J. E. and Winkler, R. L.: Scoring rules for continuous probability distributions, Manage Sci., 22, 1087-1096, 1976. Perrin, C., Michel C. and Andréassian,V. Does a large number of parameters enhance model performance? Comparative assessment of common catchment model structures on 429 catchments, J. Hydrol., 242, 275-301, 2001. Renner, M., Werner, M. G. F., Rademacher, S., and Sprokkereef, E.: Verification of ensemble flow forecast for the River Rhine, J. Hydrol., 376, 463-475, 2009. Roulin, E. and Vannitsem, S.: Skill of medium-range hydrological ensemble predictions, J. Hydrometeorol., 6, 729-744, 2005. Talagrand, O., Vautard, R., and Strauss, B.: Evaluation of the probabilistic prediction systems, in: Proceedings, ECMWF Workshop on Predictability, Shinfield Park, Reading, Berkshire, ECMWF, 1-25, 1999. Velázquez, J.A., Petit, T., Lavoie, A., Boucher M.-A., Turcotte R., Fortin V., and Anctil, F. : An evaluation of the Canadian global meteorological ensemble prediction system for short-term hydrological forecasting, Hydrol. Earth Syst. Sci., 13, 2221-2231, 2009. Wilks, D. S.: Statistical Methods in the Atmospheric Sciences, Academic Press, San Diego, CA, 465 pp., 1995.
Renewable energy sources; Erneuerbare Energien
Under the umbrella of RAG Aktiengesellschaft (Herne, Federal Republic of Germany) the RAG Deutsche Steinkohle (Herne, Federal Republic of Germany), RAG Anthrazit Ibbenbueren (Ibbenbueren, Federal Republic of Germany), the RAG Montan Immobilien (Essen, Federal Republic of Germany) as well as the RAG Mining Solutions (Herne, Federal Republic of Germany) are unified. With their activities in the German coal mining industry RAG contributes to the national energy security and create employment effects far beyond the mining regions.
In terms of the European Water Framework Directive (WFD), post mining lakes are artificial water bodies (AWB). The sustainable integration of post mining lakes in the groundwater and surface water landscape and their consideration in river basin management plans have to be linked with various (geo)hydrological, hydro(geo)chemical, technological and socioeconomic issues. The Lower Lusatian lignite mining district in eastern Germany is part of the major river basins of river Elbe and river Oder. Regionally, the mining area is situated in the sub-basins of river Spree and Schwarze Elster. After the cessation of mining activities and thereby of the artificially created groundwater drawdown in numerous mining pits, a large number of post mining lakes are evolving as consequence of natural groundwater table recovery. The lakes' designated uses vary from water reservoirs to landscape, recreation or fish farming lakes. Groundwater raise is not only substantial for the lake filling, but also for the area rehabilitation and a largely self regulated water balance in post mining landscapes. Since the groundwater flow through soil and dump sites being affected by the former mining activities, groundwater experiences various changes in its hydrochemical properties as e.g. mineralization and acidification. Consequently, downstream located groundwater fed running and standing water bodies will be affected too. Respective the European Water Framework Directive, artificial post mining lakes are not allowed to cause significant adverse impacts on the good ecological status/potential of downstream groundwater and surface water bodies. The high sulphate concentrations of groundwater fed mining lakes which reach partly more than 1,000 mg/l are e.g. damaging concrete constructures in downstream water bodies thereby representing threats for hydraulic facilities and drinking water supply. Due to small amounts of nutrients, the lakes are characterised by oligo¬trophic to slightly mesotrophic conditions. The aquatic flora and fauna are limited to a few well adapted species. Therefore, the issue of hydrochemical constitution of the lakes' waters becomes more and more relevant. The prediction of water quality development in post mining lakes is a key requirement to regulate and manage the later hydrochemical conditions. Initially, this prediction was made by individual case studies for single lakes. By means of an iterative research process during the last years, hydrochemical lake models were developed as prediction tools, which allow a complex processing of interconnected post mining lakes and their integration in natural hydrography with respect to quantitative and qualitative evaluation. To counteract the poor water quality of mining lakes, flooding by surface water from neighbouring river basins, e.g. the river Neisse, shall support a quicker and thereby hydrochemically less damaging lake filling. However, this external flooding is only feasible under conditions of high runoff and therefore only as intermitted practice applicable. Additionally, technological measures of water treatment have to be applied to achieve the required effluent quality and to ensure the designated use. Regrettably, these technologies aren't commercially standard up to now and are not sustainable, while flooding or provides a huge amount itself of positive potential for hydrochemical stabilization. The river basin management of the rivers Spree and Schwarze Elster is attended by a common working group of the Federal States of Brandenburg and Berlin as well as the Free State of Saxony. The quantitative distribution of the regionally available water considers the potential use for drinking water supply, process water, …, and the flooding of open-pits. However, due to the formulated rank order, the flooding of the numerous mining open pits in Lusatia is on the last position. To guarantee a reliable flooding and a continuous water supply of the post mining lakes, additional water resources have to exploited. Additionally, the prospected climate induced changes in water supply have to be taken into account for a sustainable integrated water resources management in the Lusatian post-mining district.
Hillslope-channel coupling in a cuesta landscape (Swabian Alb, Germany)
Hillslope-channel coupling is an emergent, scale-dependent phenomenon, which is highly sensitive to environmental changes and leads to system transience. Existing classifications for hillslope-channel couplings are nearly all qualitative and dealing with the questions of scale and type of the contact zones, as well as with the direction of change. Therefore, the quantitative understanding of hillslope-channel coupling in less active environments is rather limited. This study focuses on the hillslope-channel coupling in the Fils catchment (Swabian Alb, SW Germany). The Swabian Alb is a typical jurassic cuesta landscape with back eroding rivers in front of the escarpments, generating deeply incised valleys. The steep slopes are consisting of unstable marls and clays and are affected by numerous landslides. The major aim of the study is to investigate the spatial distribution of landslides with different degrees of hillslope channel coupling at the catchment scale. The analysis is based on a high resolution 1m * 1m DEM and an existing landslide inventory for the Fils catchment. The landslides are visually classified from hillshades and by fieldwork according their degree of connectivity to the fluvial system, using a modified classification created by Korup (2005) for the alpine region. Adjoint catchments are hydrologically calculated from the DEM to compute the spatial statistical distribution of the landslides in relation to the river. Channel profiles and valley cross-sections are generated to analyse the impact of landslides on the fluvial system. The distribution of the coupled landslides shows a spatial concentration in those channel sections, which are characterized by high relief and low valley widths. Besides these coherences the geology seems to have a strong effect on the spatial distribution and the strength of the coupling. While the hillslope channel coupling seems to have influence on the valley cross sections, the river long profie does not show any effects.
Quantification of the retention and turnover of constituents in the hyporheic zone of rivers and streams is very challenging as a result of complex physical and biogeochemical processes. There is a tremendous potential of using processes based numerical models to advance our understanding of hyporheic processes. The presentation aims at the calibration and validation procedure for the NH4 and NO3 profiles at various section of a reach and specification of parameters of major significance among large number of parameters involved in the modeling procedure. A case study was conducted on a riffle-pool sequence of the river Lahn, Germany. Using the hydrodynamic TELEMAC2D model, the surface water profile was calibrated. The groundwater flow model, MODFLOW with its reaction module RT3D, was used for the analysis in the subsurface. The first order reaction module was coded for NH4-NO3-N2 conversion process. The water surface elevation data from the hydrodynamic model is integrated into the subsurface flow and reactive transport model. The measured concentration profile (over depth), at various points of River Lahn were calibrated and parameter sensitivity analysis were performed. The model is found to be highly sensitive to hydraulic conductivity, reaction parameters, specific storage, and longitudinal dispersivity; moderately sensitive to conductance; and slightly sensitive to specific yield and molecular dispersion coefficient. It was found that the beginning of the riffle is the location of the highest concentration gradient. The locations of highest hydraulic gradient as a result of morphological change (riffle), is the location of the highest water exchange and nitrogen transformation. In spite of uncertainties involved in the process-based models (data, parameters, and model structure) valuable conclusions can be made towards focused theoretical and experimental studies for new process understating. There is a need to improve the process based numerical models in a more sophisticated manner by stronger coupling of the surface and subsurface process, with due consideration the difficulties in data acquisition and parameter estimation.
Integrated monitoring of nitrogen dynamics in contrasting catchments
The research institute WESS (Water & Earth System Science) is monitoring three adjacent meso-scale catchments (72 - 140 km2) in southwest Germany with respect to water quantity and quality. Due to their spatial proximity, the studied catchments are similar regarding climatic conditions and water balance. Geology is characterized by sedimentary rocks which are partly karstified. The catchments contrast strongly in land use and show a range from predominantly agriculture to almost exclusively forestry. In this context, a special focus of our research is the distinction of matter coming from the catchment area versus substances stemming from urban point sources. One important compound representing inputs from the catchment area is nitrogen. Nitrogen is an essential nutrient governing plant growth. If available in excess it leads to eutrophication and is therefore one of the globally most widespread contaminants in aquatic ecosystems. Transport of human-derived nitrogen through landscapes including urban areas to the oceans predominantly occurs via river network systems. Hence, monitoring of nitrogen fluxes in streams and rivers reveals mechanisms and dynamics of its transport and gives also insight into hydrologic processes which influence the mobilization of nitrogen. Presently, the catchments are equipped with online probes enabling high resolution monitoring of nitrate concentrations and other parameters. We found that average nitrate concentrations in stream water perfectly reflect the portion of fertilized arable land. The dynamics of N transport, however, largely depends on the hydrologic system and is driven by the dominating runoff generation processes. The interplay between different hydrological storages, which eventually also act as N pools, turns out to be decisive for the temporal variability of N concentrations in stream discharge. Inversely, the study of N transport dynamics can be used to infer the hydrologic mechanisms responsible for N mobilization. Our results highlight drivers of N dynamics in river systems and will ultimately help to better understand and predict N budgets at catchment scales. The newly gained process understanding and the high resolution time series shall be used to setup and improve process models.
Recently, climatological studies report observational evidence of changes in the timing of the seasons, such as earlier timing of the annual cycle of surface temperature, earlier snow melt and earlier onset of the phenological spring season. Also hydrological studies report earlier timing and changes in monthly streamflows. From a water resources management perspective, there is a need to quantitatively describe the variability in the timing of hydrological regimes and to understand how climatic changes control the seasonal water budget of river basins. Here, the timing of hydrological regimes from 1930-2009 was investigated in a network of 27 river gauges in Saxony/Germany through a timing measure derived by harmonic function approximation of annual periods of runoff ratio series. The timing measure proofed to be robust and equally applicable to both mainly pluvial river basins and snow melt dominated regimes. We found that the timing of runoff ratio is highly variable, but markedly coherent across the basins analysed. Differences in average timing are largely explained by basin elevation. Also the magnitude of low frequent changes in the seasonal timing of streamflow and the sensitivity to the changes in the timing of temperature increase with basin elevation. This sensitivity is in turn related to snow storage and release, whereby snow cover dynamics in late winter explain a large part of the low- and high-frequency variability. A trend analysis based on cumulative anomalies revealed a common structural break around the year 1988. While the timing of temperature shifted earlier by 4 days, accompanied by a temperature increase of 1 K, the timing of runoff ratio within higher basins shifted towards occurring earlier about 1 to 3 weeks. This accelerated and distinct change indicates, that impacts of climate change on the water cycle may be strongest in higher, snow melt dominated basins.
Hyporheic exchange is believed to significantly contribute to the retention and degradation of pollutants during downstream transport in surface waters. A better understanding of the relevant hydraulic drivers of stream water infiltration into the hyporheic zone in conjunction with the associated biogeochemical processes is needed in order to quantify the self-cleaning potential of rivers and to predict water quality changes. Key parameters include the spatial and temporal variation of stream water infiltration (i.e. hyporheic exchange) and the distribution of hyporheic travel times. In this study we present the setup, performance and first results of a multi-disciplinary hyporheic monitoring program at the newly established Steinlach Test Site (STS) near Tübingen in Southern Germany. The STS covers an area of about 0.6 ha and consists of a river loop located within a sub-catchment of the Neckar river. The main objective is the quantification and interrelation of hyporheic processes including hyporheic exchange, travel-time distributions, microbial community dynamics and biochemical pollutant turnover at the groundwater-surface water interface. Here we will focus on the extent and time scale of hyporheic exchange fluxes at the STS derived from time series of temperature (T), specific electrical conductivity (EC), and ?18O of water. The STS is equipped with more than 30 piezometers, most of them containing automatic water level, T and EC probes. Additional water samples for major ions, stable isotopes and other water quality parameters were taken in the course of flood events in summer 2011. The sand and gravel aquifer in the subsurface of the STS is characterised by a complex geometry with heterogeneous hydraulic conductivity. Low residence times in the southern part are confirmed by a small to negligible response in EC and T at the respective piezometers compared to the large variation of EC in the stream water. Using deconvolution techniques, a mean travel time of 3 to 4 days can be estimated for the outlet from the EC and ?18O data after major flood events. However, the fitted models also indicate a significant contribution (about 30%) of a much older water component which has not been identified yet. Possible sources include less permeable flow paths across the river loop, discharging groundwater, or hillslope water. The latter most likely plays only a minor role based on simple chemical mixing calculations. Combining the spatial point information of estimated mean travel times with aquifer geometry derived by geophysical and exploratory methods will allow an estimation of the magnitude of hyporheic exchange through the river loop at the STS.
The uranium-series isotope signatures of the suspended and dissolved load of rivers have emerged as an important tool for understanding the processes of erosion and chemical weathering at the scale of a watershed. These signatures are a function of both time and weathering-induced fractionation between the different nuclides. Provided appropriate models can be developed, they can be used to constrain the residence time of river sediment. This chronometer is triggered as the bedrock starts weathering and the inferred timescale encompasses the residence time in the weathering profile, storage in temporary sediment deposits (e.g. floodplain) and transport in the river. This approach has been applied to various catchments over the past five years showing that river sediments can reside in a watershed for timescales ranging from a few hundreds of years (Iceland) to several hundreds of thousands of years (lowlands of the Amazon). Various factors control how long sediment resides in the watershed: the longest residence times are observed on stable cratons unaffected by glacial cycles (or more generally, climate variability) and human disturbance. Shorter residence times are observed in active orogens (Andes) or fast-eroding, recently glaciated catchments (Iceland). In several cases, the residence time of suspended sediments also corresponds to the time since the last major climate change. The U-series isotope composition of rivers can also be used to predict the river sediment yield assuming steady-state erosion is reached. By comparing this estimate with the modern sediment yield obtained by multi-year sediment gauging, it is clear that steady-state is seldom reached. This can be explained by climate variability and/or human disturbance. Steady-state is reached in those catchments where sediment transport is rapid (Iceland) or where the region has been unaffected by climate change and/or human disturbance. 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Palaeoecol.1941 32003139164TaylorA.J.D.BlumRelation between soil age and silicate weathering rates determined from the chemical evolution of a glacial chronosequenceGeology231995979982TaylorS.R.S.M.McLennanThe Continental Crust: Its Composition and Evolution1985BlackwellLondonTomkins, K.M., Humphreys, G.S., Wilkinson, M.T., Hesse, P.P., Doerr, S.H., Shakesby, R.A., Walbrink, P.J., in press. Contemporary versus long-term denudation along a passive plate margin, Australia: the role of extreme events. Earth Surf. Proc. Landforms.TriccaA.G.J.WasserburgD.PorcelliM.BaskaranThe transport of U- and Th-series nuclides in a sandy unconfined aquiferGeochim. Cosmochim. Acta658200111871210TurnerS.P.Van CalsterenN.VigierL.ThomasDetermination of thorium and uranium isotope ratios in low-concentration geological materials using a fixed multi-collector-ICP-MSJ. Anal. At. Spectrom.1662001612615VigierN.B.BourdonS.TurnerC.J.AllègreErosion timescales derived from U-decay series measurements in riversEarth Planet. Sci. Lett.1932001546563VigierN.B.BourdonÉ.LewinB.DupréS.TurnerP.Van CalsterenV.SubramanianC.J.AllègreMobility of U-series nuclides during basalt weathering: an example of the Deccan Traps (India)Chem. Geol.2191 420056991VigierN.K.W.BurtonS.R.GislasonN.W.RogersS.DucheneL.ThomasE.HodgeB.SchaeferThe relationship between riverine U-series disequilibria and erosion rates in a basaltic terrainEarth Planet. Sci. Lett.2493 42006258273von BlanckenburgF.The control mechanisms of erosion and weathering at basin scale from cosmogenic nuclides in river sedimentEarth Planet. Sci. Lett.2423 42006224239WestA.J.A.GalyM.BickleTectonic and climatic controls on silicate weatheringEarth Planet. Sci. Lett.2351 22005211228WhippleK.X.Fluvial landscape response time: how plausible is steady-state denudation? AmJ. Sci.3012001313325WhiteA.F.S.L.BrantleyThe effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field?Chem. Geol.2023 42003479506WhiteA.F.A.E.BlumM.S.SchulzT.D.BullenJ.W.HardenM.L.PetersonChemical weathering rates of a soil chronosequence on granitic alluvium. 1. Quantification of mineralogical and surface area changes and calculation of primary silicate reaction ratesGeochim. Cosmochim. Acta60199625332550Display Omitted Anthony Dosseto is a research fellow at the GEMOC Centre, Macquarie University, Sydney, Australia. He completed a PhD focusing on a U-series study of subduction magmatism and erosion timescales at IPGP/Université Paris 7 (France) in 2003. Anthony Dosseto has spent the past 3 years as a research fellow at the GEMOC Centre where he has been involved in the development of a laboratory dedicated to U-series isotopes. He has been using U-series isotopes to understand the links between erosion and external factors.Display Omitted Bernard Bourdon is a Professor of Isotope Geochemistry in the Department of Earth Sciences at ETH Zurich, Switzerland. He obtained his PhD at the Columbia University in 1994, working on U-series in volcanic rocks. His research focuses on understanding timescales and processes in the Earth using isotope geochemistry, with a special focus on U-series isotopes.Display Omitted Simon Turner is an ARC Federation Fellow and a Professor of Geochemistry at Macquarie University. His interests have ranged from the origins of post-orogenic granites and shoshonitic rocks to detrital mineral ages and sediment provenance, the origins and timing of continental flood basalts, the petrogenesis of ocean island basalts and the formation of subduction related magmas. Recent work has concentrated on short-lived (U-series) isotope studies and the timescales of natural processes, especially magma formation, segregation and differentiation as well as erosion and soil formation.
Decentralised flood protection in low mountain areas - the Upper Floeha case study
In the German-Czech border regions throughout the Ore Mountains storm runoff frequently causes severe damage in headwater areas as well as in lower reaches. The fact, that settlements along smaller tributaries (second order rivers) and towns near the receiving water (first order rivers) are affected simultaneously, requires the consideration of measures distributed throughout the entire drainage area. The concept of decentralised flood protection includes a large number of different measures, which are suitable for the application in low mountain ranges, e.g. small, decentralised retarding basins, river revitalisation, reforestation of floodplains or landuse changes. The presented study is part of the Interreg IIIA research project "DINGHO". Its aim is to show, how decentralised measures can contribute to an improvement of flood protection in low mountain areas using the example of the Upper Floeha watershed. On this background the investigations focus on headwater areas as well as downstream settlements. The study area extends between the town of Olbernhau (Free State of Saxony, Germany) and the large Rauschenbach reservoir, including two main tributaries (Natzschung and Schweinitz), and covers an area of 228 km². The geomorphology of the study area is characterised by plateau-like headwater areas with gentle slopes (above ~700 m a.s.l.) and steep and strongly dissected lower reaches. In a first step the local potentials for the implementation of decentralised measures were investigated on the basis of GIS analyses and field surveys. The second step included the assessment of the efficiency of the decentralised measures by the application of rainfall-runoff-models. Depending on the type of measures two different software packages were used: the model systems NASIM for measures along river courses and WaSiM-ETH for the watershed-wide retention (landuse changes). Potentials for water retention in small, decentralised retarding basins can be found especially in higher regions with more gentle slopes. Steep valleys in lower reaches are less suitable for such basins due to their steep gradient and the consequential limitation of storage capacities. Along most of the rivers potentials for an afforestation of the valley bottoms in order to increase the surface roughness were identified, but the hydrological effects depend on the shape of the valleys and their gradients. However potentials for river revitalisation are strongly limited. In addition, some areas can be reforested, since they have recently recovered from the SO2 pollution which affected the area until the late 1980s and caused serious forest decline. The modelling results indicate, that small retarding basins would lead to a reduction of peak discharges of a 100-year return period of up to 45 % at some tributaries and 10 % downstream in Olbernhau. By contrast local effects of the floodplain afforestation remain very low, whereas in Olbernhau a peak reduction of 4.2 % can be achieved. If only the Floeha floodplain with a wide valley and a low gradient is considered for the afforestation, the flood peaks were reduced by 3.5 % in the model. By reforestation of declined forests peak discharge can be reduced by about 13 %. On the whole the results show, that a significant improvement of flood protection in the Upper Floeha watershed can be achieved through the application of decentralised measures. The reduction of flood peaks includes the Floeha river itself, tributaries and headwater areas. However as far as measures along the rivers are concerned, the extent of the hydrological effects strongly depends on the retention potentials in subareas with more gentle valley gradients, i.e. in higher regions of the study area or along the Floeha valley.
Patterns in groundwater chemistry resulting from groundwater flow
Groundwater flow influences hydrochemical patterns because flow reduces mixing by diffusion, carries the chemical imprints of biological and anthropogenic changes in the recharge area, and leaches the aquifer system. Global patterns are mainly dictated by differences in the flux of meteoric water passing through the subsoil. Within individual hydrosomes (water bodies with a specific origin), the following prograde evolution lines (facies sequence) normally develop in the direction of groundwater flow: from strong to no fluctuations in water quality, from polluted to unpolluted, from acidic to basic, from oxic to anoxic-methanogenic, from no to significant base exchange, and from fresh to brackish. This is demonstrated for fresh coastal-dune groundwater in the Netherlands. In this hydrosome, the leaching of calcium carbonate as much as 15m and of adsorbed marine cations (Na+, K+, and Mg2+) as much as 2500m in the flow direction is shown to correspond with about 5000yr of flushing since the beach barrier with dunes developed. Recharge focus areas in the dunes are evidenced by groundwater displaying a lower prograde quality evolution than the surrounding dune groundwater. Artificially recharged Rhine River water in the dunes provides distinct hydrochemical patterns, which display groundwater flow, mixing, and groundwater ages. Résumé Les écoulements souterrains influencent les différents types hydrochimiques, parce que l'écoulement réduit le mélange par diffusion, porte les marques chimiques de changements biologiques et anthropiques dans la zone d'alimentation et lessive le système aquifère. Ces types dans leur ensemble sont surtout déterminés par des différences dans le flux d'eau météorique traversant le sous-sol. Dans les "hydrosomes" (masses d'eau d'origine déterminée), les lignes marquant une évolution prograde (séquence de faciès) se développent normalement dans la direction de l'écoulement souterrain : depuis des fluctuations fortes de la qualité de l'eau vers une absence de fluctuations, de polluées vers non polluées, d'acides vers basiques, d'oxygénées vers anoxiques et méthanogènes, depuis des échanges de base inexistants vers des échanges significatifs, de l'eau douce vers l'eau saumâtre. Ceci est montré pour une nappe d'eau douce dans une dune côtière des Pays-Bas. Dans "l'hydrosome", on montre que la disparition du carbonate de calcium par lessivage à plus de 15m et celle de cations adsorbés d'origine marine (Na+, K+ et Mg2+) à plus de 2500m vers l'aval-gradient correspond à environ 5000 ans d'écoulement, depuis que la barrière de la plage avec les dunes s'est mise en place. Les zones d'alimentation ponctuelle dans les dunes sont mises en évidence par l'eau souterraine montrant une plus faible évolution prograde de sa qualité que l'eau souterraine de la dune alentour. L'eau du Rhin utilisée pour la réalimentation artificielle dans les dunes a fourni des types hydrochimiques distincts, qui marquent l'écoulement, le mélange et les âges de l'eau souterraine. Resumen El flujo subterráneo tiene una gran importancia sobre la hidroquímica de un sistema ya que reduce la mezcla por difusión, transporta las huellas químicas y biológicas de las acciones antrópicas en la zona de recarga y drena el sistema acuífero. Las tendencias globales vienen regidas por las diferencias en el flujo de agua meteórica que atraviesa el subsuelo. En un hidrosoma individual (cuerpo de agua de un origen específico), se suele desarrollar la siguiente línea de evolución (secuencia de facies) en la dirección del flujo: de gran a nula fluctuación en la calidad del agua, de agua contaminada a no contaminada, de ácida a básica, de óxica a anóxica-metanogénica, de nulo a importante cambio de base y de agua dulce a salobre. Esto puede verse, por ejemplo, en las aguas dulces presentes en las dunas costeras de Holanda. En este hidrosoma, el lixiviado de carbonato cálcico, hasta 15m, y de cationes de adsorción marina (Na+, K+ and Mg2+), hasta 2500m en la dirección
In this paper we review threshold behaviour in environmental systems, which are often associated with the onset of floods, contamination and erosion events, and other degenerative processes. Key objectives of this review are to a) suggest indicators for detecting threshold behavior, b) discuss their implications for predictability, c) distinguish different forms of threshold behavior and their underlying controls, and d) hypothesise on possible reasons for why threshold behaviour might occur. Threshold behaviour involves a fast qualitative change of either a single process or the response of a system. For elementary phenomena this switch occurs when boundary conditions (e.g., energy inputs) or system states as expressed by dimensionless quantities (e.g. the Reynolds number) exceed threshold values. Mixing, water movement or depletion of thermodynamic gradients becomes much more efficient as a result. Intermittency is a very good indicator for detecting event scale threshold behavior in hydrological systems. Predictability of intermittent processes/system responses is inherently low for combinations of systems states and/or boundary conditions that push the system close to a threshold. Post hoc identification of "cause-effect relations" to explain when the system became critical is inherently difficult because of our limited ability to perform observations under controlled identical experimental conditions. In this review, we distinguish three forms of threshold behavior. The first one is threshold behavior at the process level that is controlled by the interplay of local soil characteristics and states, vegetation and the rainfall forcing. Overland flow formation, particle detachment and preferential flow are examples of this. The second form of threshold behaviour is the response of systems of intermediate complexity - e.g., catchment runoff response and sediment yield - governed by the redistribution of water and sediments in space and time. These are controlled by the topological architecture of the catchments that interacts with system states and the boundary conditions. Crossing the response thresholds means to establish connectedness of surface or subsurface flow paths to the catchment outlet. Subsurface stormflow in humid areas, overland flow and erosion in semi-arid and arid areas are examples, and explain that crossing local process thresholds is necessary but not sufficient to trigger a system response threshold. The third form of threshold behaviour involves changes in the "architecture" of human geo-ecosystems, which experience various disturbances. As a result substantial change in hydrological functioning of a system is induced, when the disturbances exceed the resilience of the geo-ecosystem. We present examples from savannah ecosystems, humid agricultural systems, mining activities affecting rainfall runoff in forested areas, badlands formation in Spain, and the restoration of the Upper Rhine river basin as examples of this phenomenon. This functional threshold behaviour is most difficult to predict, since it requires extrapolations far away from our usual experience and the accounting of bidirectional feedbacks. However, it does not require the development of more complicated model, but on the contrary, only models with the right level of simplification, which we illustrate with an instructive example. Following Prigogine, who studied structure formation in open thermodynamic systems, we hypothesise that topological structures which control response thresholds in the landscape might be seen as dissipative structures, and the onset of threshold processes/response as a switch to more efficient ways of depleting strong gradients that develop in the case of extreme boundary conditions.
In spring 2004 the airborne gamma spectrometry (AGS) equipment was used for the first time in a car borne survey searching for a lost {sup 137}CS source. Initial tests showed a smooth detection of a 500 MBq {sup 137}Cs source at a speed of 60 km/h. During the actual survey no radioactive source was found. In March 2004, the AGS equipment was employed during the exercise 'Braunbaer' of the Swiss National Emergency Operations Centre (NAZ). Three {sup 137}Cs sources with activities of 25 MBq, 860 MBq and 890 MBq were concealed in the exercise area. As expected, the two stronger sources could be localized and identified. Additionally, the exercise demonstrated the readiness of the AGS system within the scheduled deployment time of four hours. The measurement flights within the scope of the exercise UARM04, organised by Y. Loertscher (NAZ), were performed from June 14 to June 17. According to the alternating schedule of the annual UARM exercises the environs of the nuclear power plants Beznau and Leibstadt, the environs of the research facility Paul Scherrer Institute (PSI) and of the intermediate storage facility for nuclear waste (ZWILAG) were inspected. The aeroradiometric measurements showed similar results to those observed in the past. The nuclear power plant Leibstadt could be identified by its direct radiation which is characteristic for a boiling water reactor. Block I of the nuclear power plant Beznau was in revision during the survey. The aeroradiometric measurement identified {sup 58}Co activity, which is temporarily increasing in the fuel storage pool and in the reactor cooling system during the shut down. {sup 60}Co could be identified over the Federal intermediate storage facility, located on the PSI area. The exhaust stack at PSI West showed an elevated amount of annihilation radiation. The intermediate storage facility Wuerenlingen (ZWILAG) could not be detected by aeroradiometric measurements. Outside the fenced areas of the inspected nuclear facilities no man-made radiation was detected which could not be attributed to the nuclear weapons test fallout and the Chernobyl fallout. An aeroradiometric profile was flown along the rivers Rhine and Rhone from Chur to the Lake of Geneva. The results showed the highest radiation measurements according to the geology above the crystalline rocks of the Aar-massif. For the first time in Switzerland, surveys of cities were carried out over the cities of Lausanne and Davos demonstrating the feasibility of such operations. The results showed activity values which are corresponding to the local environment. A comparison with ground measurements yielded good agreement between the results of ground and aeroradiometric measurements. The vicinity of the former test reactor at Lucens was inspected after the last radioactive waste was transported to the intermediate storage facility ZWILAG. The aeroradiometric measurements showed no increased radiation values. (author)
During the last years there were several reports on the appearance of the biocides triclosan (TCS; 5- chloro-2-(2,4-dichlorophenoxy)phenol; CAS No. 3380-34-5) and chlorophene (CP; 4-Chloro-2- (phenylmethyl)phenol; CAS No. 120-32-1) in the environment. TCS is used in numerous personal care products like toothpaste and soaps, but also in textiles and shoes. The current annual consumption in Germany is estimated to be 40 t (0.5 g per capita and year). During use large amounts of TCS and CP are disposed into waste water. Modern waste water treatment plants (WWTP) eliminate approximately 95 % of TCS, mainly by biodegradation and adsorption to sludge. It was observed that during waste water treatment methyl-triclosan (MTCS; 5-chloro-2-(2,4-dichlorophenoxy)anisole; CAS No. 4640-01-1) is formed, probably due to microbial methylation. In a WWTP effluent up to 1 % MTCS in relation to TCS was detected. The environmental half-life of TCS is assumed to be low, mainly because it is susceptible to photodegradation at environmental pH levels while MTCS is stable under these conditions. The logPow values of 4.7 for TCS and 5.2 for MTCS (estimated with KowWin Vers. 1,67, respectively) indicate potential for bioaccumulation. Based in order to investigate the exposure of aquatic organisms towards CP, TCS and MTCS in Germany a retrospective monitoring of breams (Abramis brama) from representative rivers was initiated. Samples from the period 1994 to 2003 were taken from the archive of the German Environmental Specimen Bank (ESB) to evaluate temporal changes and regional differences of the occurrence of the target compounds.
Passive treatments rely on the autochthonous microflora of the contaminated site during bioremediation. The degradation of organic matter coupled to anaerobic respiration leads to alkalinity generation. This generally takes place in the anoxic environment of the sediment. Because of the abundance of iron and sulfate electron acceptors in acidic Pit Lakes, both iron and sulfate reduction are target processes for bioremediation. Approximately 90 lakes, with many being highly acidic, will come into existence in the lignite mining areas of East and Central Germany. Flooding with river water is only a solution for a restricted number of larger lakes. As a result, there is a need to develop remediation strategies for the vast number of smaller and already existing lakes. A pilot scale neutralization experiment was performed from 2001 to 2005 in acidic Pit Lake 111, located in Lusatia, East-Germany. Organic carbon sources, straw and carbokalk, sugar industry byproducts, were added to a 30 metre wide enclosure installed within the lake. A reaction zone was created in the surficial sediment, that demonstrated increased sulfate and iron reduction as well as an accumulation of reduced iron and sulfur compounds. A bacterial community analysis was then performed. This analysis involved cloning genes directly from sediment samples and fingerprinting of partial genes from dilution cultures selecting for iron and sulfate reducing bacteria under varying culture conditions. The clone libraries showed high bacterial diversities for treated and untreated sediments. They also revealed a definite shift in abundance of certain bacterial groups. The sulfate reducing cultures were dominated by species affiliated to the genus desulfosporosinus, while many different phylotypes were identified in iron reducing cultures. 34 refs., 1 tab., 3 figs.
Abstract.- Ringdn O, Labopin M, Beelen DW, Volin L, Ehninger G, Finke J, Greinix HT, Kyrcz-Krzemien S, Bunjes D, Brinch L, Niederwieser D, Arnold R, Mohty M, Rocha V, for the Acute Leukaemia Working Party of the European Group for Blood and Marrow Transplantation (EBMT) (Karolinska University Hospital Huddinge, Sweden; CEREST-TC EBMT, Paris, France; University of Duisburg-Essen, Germany; Helsinki University Central Hospital, Helsinki, Finland; University Hospital, Dresden, Germany; University Hospital, Freiburg, Germany; Medical University Vienna, Vienna, Austria; Medical University of Silesia, Katowice, Poland; University Hospital, Ulm, Germany; Rikshospitalet, Oslo, Norway; University Hospital, Leipzig, Germany; Charit University Hospital, Berlin, Germany; Universit de Nantes, Nantes, Fr...
The usefulness of various suggested species demarcation criteria was compared in attempts to determine the taxonomic status of ten new tombusvirus isolates. Five of them (Lim 1, 2, 3, 5 and 6) were obtained from different sources of commercially grown statice (Limonium sinuatum), two (Gyp 1 and 2) from different sources of commercially grown Gypsophila paniculata and three from water samples, i.e. from a small river (Schunter) in Northern Germany, from a brook (near Dossenheim) in Southern Germany and from the groundwater in a Limonium production glasshouse in the Netherlands (Lim 4). The immunoelectron microscopical decoration test allowed a quick preliminary assignment of various isolates to several known tombusviruses. A more precise analysis of the relationships was achieved by comparing the deduced amino acid sequences of the coat proteins. Sequence as well as serological data suggested that eight of the isolates should be classified as strains or variants of either Carnation Italian ringspot virus, Grapevine Algerian latent virus, Petunia asteroid mosaic virus or Sikte waterborne virus, respectively, whereas the 9th isolate (Lim 2) appears to represent a distinct new tombusvirus species. The case of the 10th isolate (Lim 5) illustrates the classification problems experienced when the properties of a virus place it close to the more or less arbitrary man-made borderline between virus species and virus strains. The coat protein gene sequences were also determined for some viruses for which these data had not yet been available, i.e. Neckar river virus, Sikte waterborne virus and Eggplant mottled crinkle virus. The sequences of the coat protein gene and also of ORF 1 of the latter virus proved to be almost identical to the corresponding genome regions of the recently described Pear latent virus, which for priority reasons should be renamed. Criteria which have been suggested in addition to serology and sequence comparisons for tombusvirus species demarcation, i.e. differences in natural and in experimental host ranges, in cytopathological features and in coat protein size, appear to be of little value for the classification of new tombusviruses. PMID:15593416
Parameterization of a hydrological model using remote sensing data
The alteration of land cover by humans has multiple consequences on biological systems ranging from local to global scales. The United Nations have rated land use changes as one of the major issues for the coming centuries. In Northern Germany a significant land use change can be observed since 2004, i.e. the amendment of the Renewable Energies Act. Since then, an increasing number of biogas plants have been built resulting in an increased cultivation of so-called energy crops, especially in direct neighbourhood to these plants. Conversion of land is known to alter hydrological processes such as the exchange of energy and water. To investigate the effects of land use change on the water cycle in lowland river catchments in Northern Germany, we used a series of land cover data for the Upper Stoer, a sub-catchment of the river Elbe, as the input for a hydrological model. To derive the land cover data, we applied maximum-likelihood classifications of Landsat TM data for the years 2003 and 2010. The open source model suite SWAT (Soil Water Assessment Tool) was used to model the water cycle. SWAT has proven to be a useful tool for simulating the effect of watershed processes and management practices on water resources. A comparison of the modelled and observed discharge at the outlet of the catchment (gauge Willenscharen) showed good results (Nash Sutcliffe = 0.62). However, the land use change had no measurable effect on the discharge at the outlet due to the masking influence of high groundwater levels in the catchment. Therefore focusing on the discharge at the outlet is not a suitable approach in such cases. To represent the spatial characteristics of a catchment as realistically as possible, the catchment area must be spatially discretized. The configuration used primarily within SWAT is the sub-watershed discretization scheme. This results in a loss of spatial information, which is problematic for our intended applications. Therefore we developed an alternative model interface to manage input and output data based on grid cells. This enabled us to model the changes in evapotranspiration patterns in the catchment with changing land use more realistically and to calculate the water balance for each grid cell without losing its geographic reference. Therefore, the grid cells can interact with each other and exchange matter and energy, which was not possible using the sub-watershed approach. Therefore, the grid-cell interface enables the implementation of remote sensing data to provide a spatially distributed modelling.
Indicating anthropogenic effectson urban water system - indicators and extension
Urban water systems are polluted by diffusive and direct contribution of anthropogenic activities. Besides industrial contaminants like aromatic and chlorinated HC and other persistent organic compounds, the urban aquatic environment is increasingly polluted by low concentrated but high eco-toxic compounds as pharmaceuticals, fragrances, plasticizers which most have disrupt endocrine functions, and trace elements carried in by surface and sub-surface waste water and seeping processes. This contamination could have a longtime impact on the urban ecosystem and on the human health. The interdisciplinary project on risk assessment of water pollution was initiated to explore new methodologies for assessing human activities on the urban water system and processes among urban watersheds. In a first assumption we used a flow model concept with in- and output and surface water transport represented by the city of Halle, Germany, and the river Saale. The river Saale acts as surface water system collecting waste water inputs along the city traverse. We investigated the anthropogenic effect on the urban water system using the indicators hydrological parameters, compound specific pattern of complex organic substances and trace elements, isotopic signatures of water (H, O) and dissolved substances (sulfate, DIC, nitrate), pathogens, and microbiota. A first balance modeling showed that main ions are not very sensitive concerning the direct urban input into the river. Depending on the discharge of the river in high and low flood stages the load of dissolved matter has no specific urban effect. However, the concentration pattern of fragrances (tonalid, galaxolid) and endocrine disrupters (t-nonylphenol) point to a different pollution along the city traverse: downstream of the sewage plant a higher load was observed in comparison to the upstream passage. Furthermore, a degradation ability of fungi and bacteria occurred in the bank sediments could be detected in lab experiments concerning the fragrances, and endocrine disrupters (t-nonylphenol, phthalate). The Saale water samples contain components able to eco-toxic and immunomodulated effects as measured on the vitality and cytokine-secretion profile of human peripheral blood mononuclear cells (PBMC). Even fragrances caused such effects which are unknown so far. The study of assessing urban effects onto the water system is still under investigation.
Helicopter-borne electromagnetics (HEM) is an important tool for hydrogeological questions. HEM investigations enable the differentiation of sandy and clayey sediments as well as saltwater and freshwater saturated sediments down to about 150 meters depth. The frequency-domain HEM system operated at the Federal Institute for Geosciences and Natural Resources (BGR) is the RESOLVE system manufactured by Fugro Airborne Surveys. In 2008 and 2009, BGR conducted airborne geophysical measurements for saltwater-freshwater investigation at several survey areas at the German North Sea coast. The surveys were carried out in cooperation with the Leibniz Institute for Applied Geosciences (LIAG) in frame of the project D-AERO. One of these survey areas covers the estuary of the Elbe river to the north-west of the city of Hamburg. Parts of the results of this survey are involved in the project KLIMZUG-NORD, where the Technical University Hamburg-Harburg investigates the environmental effects of the climate change on the estuary of the Elbe river. The HEM measurements reveal both the course of the Geest ridge (high-lying hinterland consisting of pleistocenic moraine sediments) and the swamp belt due to their elevated resistivities, whereas the Marsch land (plain holocenic wet land, alluvium) occurred more conductive. Here, an electrical conductivity anomaly was detected witch could neither be related with seawater intrusion nor with anthropogenic sources. The significant low-resistivity zone of about three square kilometers was identified as a saltwater-rising zone by water analyses of surface water and is an example for natural groundwater mineralization. A man-made groundwater mineralization was investigated by HEM in the Werra river valley in central Germany. About 1000 million cubic meters saline waste water from potash mining have been stored in a karstic limestone and dolomite bed to reduce the amount of saline water emissions directly into the river. BGR conducted surveys in 1996/97 and 2008 including an area where a test disposal of 9.5 million cubic meters saline waste water took place between 1999 and 2007. Changes of the near surface groundwater mineralization were monitored.
Basin-scale analysis of hillslope-channel coupling in a cuesta landscape (Swabian Alb, SW-Germany)
Since the quantitative revolution in geomorphology in the mid 20th century, fluvial dynamics and hillslope processes are generally studied independently from each other. However, the connectivity between geomorphological process domains is a major control of sediment flux in geomorphic systems. The few existing studies that focus hillslope channel coupling are mainly limited to highly active mountain ranges in alpine regions and/or the processes after extreme events. Hillslope-channel coupling is an emergent, scale-dependent phenomenon, which is highly sensitive to environmental changes and leads to system transience. Existing classifications for hillslope-channel couplings are nearly all qualitative and dealing with the questions of scale and type of the contact zones, as well as with the direction of change. Therefore, the quantitative understanding of hillslope-channel coupling in less active environments is rather limited. This study focuses on the hillslope-channel coupling in the Fils catchment (Swabian Alb, SW Germany). The Swabian Alb is a typical jurassic cuesta landscape with back eroding rivers in front of the escarpments, generating deeply incised valleys. The steep slopes are consisting of unstable marls and clays and are affected by numerous landslides. The major aim of the study is to investigate the spatial distribution of landslides with different degrees of hillslope channel coupling at the catchment scale. The analysis is based on a high resolution 1m * 1m DEM and an existing landslide inventory for the Fils catchment. The landslides are visually classified from hillshades and by fieldwork according their degree of connectivity to the fluvial system, using a modified classification created by Korup (2005) for the alpine region. Adjoint catchments are hydrologically calculated from the DEM to compute the spatial statistical distribution of the landslides in relation to the river. River long profiles and valley cross-sections are generated to analyse the impact of landslides on the fluvial system. The distribution of the coupled landslides shows a spatial concentration in those channel sections, which are characterized by high relief and low valley widths. Besides these coherences the geology seems to have a strong effect on the spatial distribution and the strength of the coupling. While the hillslope channel coupling seems to have influence on the valley cross sections, the river long profile does not show any effects.
Floodplains and wetlands in Central Europe have been affected by intensively changing landuse and management conditions within the last century. Formerly intensively agricultural used areas are often more extensively used today and nature conservation issues became more important. Nevertheless, a majority of floodplain water bodies are still under different pressures and alternative landuse targets of different stakeholders produce conflicts in management policies. The European Water Framework Directive (WFD) demands the evaluation of the status and, if necessary, the improvement of the surface and groundwater quality of water bodies. Therefore the current status of water bodies, as well as pressures on them, the risks and potential strategies for improvement need to be characterised. As detailed knowledge about impacts of landuse management changes on the the hydrology of floodplains and wetlands is often insufficient, impact assessment and the resulting argumentations are not always adequate. Exemplary for lowland floodplains in Central Europe a set of reasonable land use and management scenarios was developed for the Lower Havel river basin in North-eastern Germany. The scenarios were analysed for their ability to gain a sustainable improvement of the floodplain water balance as well as of the surface water and groundwater quality. The coupled groundwater - water balance model IWAN was used for the quantification of potential changes of the floodplain water balance and of the interactions between the groundwater and surface waters. It was possible to prove that the assumed land use changes effect the floodplain water balance only insignificantly although lateral processes as infiltration and evapotranspiration were modified. However, these alterations of vertical fluxes are widely compensated by the lateral impact of groundwater - surface water interactions within the intensively drained parts of the floodplain. The analysis of a further scenario assuming the deactivation of the currently very dense drainage network showed a more intensive change of the seasonal variability of the floodplain water balance which could possibly establish a compromise between agricultural and nature conservation targets. It could be proved that the effect of drainage reduction would cause a higher retention of the floodplain water balance during the dry summer season and that the ecological important flooding events from autumn to spring would mainly effect wetlands with a high river connectivity which are of minor importance for agricultural use only. A generally high importance of groundwater supply from the floodplain to the total river discharge could be quantified during the ecologically important low flow summer season. It was shown that a reduction of fertilizer and manure application could cause an improvement of the groundwater quality but that a subsequently improvement of the surface water quality would be limited to summer months only when the proportion of groundwater runoff on the river discharge exceeds its maximum.
Dynamically downscaled data from two Atmosphere-Ocean General Circulation Models (AOGCMs), ECHAM4 from the Max-Planck Institute (MPI), Germany and HadAm3H from the Hadley Centre (HAD), UK, driven with two scenarios of greenhouse gas emissions (IS92a and A2, respectively) were used to make climate change projections. These projections were then used to drive four effect models linked to assess the effects on hydrology, and nitrogen (N) concentrations and fluxes, in the Bjerkreim river basin (685-km{sup 2}) and its coastal fjord, southwestern Norway. The four effect models were the hydrological model HBV, the water quality models MAGIC, INCA-N and the NIVA FJORD model. The downscaled climate scenarios project a general temperature increase in the study region of approximately 1{sup o}C by 2030-2049 (MPI IS92a) and approximately 3{sup o}C by 2071-2100 (HAD A2). Both scenarios imply increased winter precipitation, whereas the projections of summer and autumn precipitation are quite different, with the MPI scenario projecting a slight increase and the HAD scenario a significant decrease. As a response to increased winter temperature, the HBV model simulates a dramatic reduction of snow accumulation in the upper parts of the catchment, which in turn lead to higher runoff during winter and lower runoff during snowmelt in the spring. With the HAD scenario, runoff in summer and early autumn is substantially reduced as a result of reduced precipitation, increased temperatures and thereby increased evapotranspiration. The water quality models, MAGIC and INCA-N project no major changes in nitrate (NO{sub 3}{sup -}) concentrations and fluxes within the MPI scenario, but a significant increase in concentrations and a 40-50% increase in fluxes in the HAD scenario. As a consequence, the acidification of the river could increase, thus offsetting ongoing recovery from acidification due to reductions in acid deposition. Additionally, the increased N loading may stimulate growth of N-limited benthic algae and macrophytes along the river channels and lead to undesirable eutrophication effects in the estuarine area. Simulations made by the FJORD model and the HAD scenario indicate that primary production in the estuary might increase up to 15-20%, based on the climate-induced changes in river flow and nitrate concentrations alone. (author)
The construction of the Three Gorges Dam in China induced a large scale land use change not only in the reservoir area itself, but also in the adjacent catchments. The Xiangxi is a 90 km long tributary of the Yangtze, whose lower reaches are now part of the Three Gorges Reservoir. The impoundment caused an uphill shift of agricultural areas from the valley bottoms to steep, formerly wooded slopes as well as the relocation of villages and towns and the construction of associated infrastructure. This leads to an increase in erosion, landslides and diffuse inputs of sediment and phosphorus to the rivers. As part of the BMBF-funded Sino-German YANGTZE-Project these processes are currently assessed under the topic "Land Use Change - Erosion - Mass Movements" by a total of five project groups from Germany together with cooperation partners from China. Among these, the Department of Hydrology and Water Resources Management at Kiel University focuses on the assessment of the impact of the land use change on water quantity and quality. The main tool used for this study is the ecohydrological model SWAT (Arnold et al. 1998). Taking the Xiangxi Catchment as an example for catchments impacted by large dam projects and characterized by a scarce database, the response of the water balance as well as the sediment and phosphorus transport processes to the large scale land use change are simulated. Based on this, sustainable land use concepts will be developed from an ecohydrological point of view. The input data required by the SWAT model were provided by the German project partners as well as Chinese cooperation partners and authorities. Additionally, the database is completed by the results of own field work. The field campaigns include the mapping of the channel morphology of Xiangxi River and sampling for the analysis of sediment and phosphorus concentrations in the water.
Beside damages of infrastructure in industrial regions, extreme floods can cause contamination with particle-bound pollutants, e. g., due to erosion of soils and sediments. In order to predict contamination with inorganic pollutants, the transport and fate of arsenic, lead, and mercury during a fictive flood event of River Vereinigte Mulde in the region of Bitterfeld (Germany) with 200 years recurrence time was modeled. The finite element model system Telemac2D, which is subdivided into a hydrodynamic (Telemac-2D), a transport (Subief-2D), and a water quality module (wq2subief) was applied. The transport and water quality model models were calibrated using results of sediment trap exposures in the floodplain of River Vereinigte Mulde. Model results exhibited that the spatial patterns of particle-associated arsenic and lead concentrations significantly changed. Extended, mostly agriculturally used areas showed arsenic and lead concentrations between 150 and 200 mg kg{sup -1}and 250 and 300 mg kg {sup -1}, respectively, while urban areas were to a great extent spared from high contamination with arsenic and lead. Concentrations of particle-associated mercury showed a pattern distinct from those of arsenic and lead. Outside of small patches with concentrations up to 63 mg kg {sup -1}, concentrations of particle-associated mercury remained close to zero. Differences in the spatial patterns of the three pollutants regarded mainly arise from significantly different initial and boundary conditions. Sensitivity analyses of initial and boundary conditions revealed a high sensitivity of particle-bound pollutant concentrations, whereas the sensitivities of concentrations of suspended sediments and soluble pollutants were mediocre to negligible. (Abstract Copyright [2009], Wiley Periodicals, Inc.)
Comparative studies on the retardation and reduction of glyphosate during subsurface passage.
The herbicide Glyphosate was detected in River Havel (Berlin, Germany) in concentrations between 0.1 and 2 ?g/L (single maximum outlier: 5 ?g/L). As the river indirectly acts as drinking water source for the city's 3.4 Mio inhabitants potential risks for drinking water production needed to be assessed. For this reason laboratory (sorption and degradation studies) and technical scale investigations (bank filtration and slow sand filter experiments) were carried out. Batch adsorption experiments with Glyphosate yielded a low K(F) of 1.89 (1/n = 0.48) for concentrations between 0.1 and 100 mg/L. Degradation experiments at 8 °C with oxygen limitation resulted in a decrease of Glyphosate concentrations in the liquid phase probably due to slow adsorption (half life: 30 days). During technical scale slow sand filter (SSF) experiments Glyphosate attenuation was 70-80% for constant inlet concentrations of 0.7, 3.5 and 11.6 ?g/L, respectively. Relevant retardation of Glyphosate breakthrough was observed despite the low adsorption potential of the sandy filter substrate and the relatively high flow velocity. The VisualCXTFit model was applied with data from typical Berlin bank filtration sites to extrapolate the results to a realistic field setting and yielded sufficient attenuation within a few days of travel time. Experiments on an SSF planted with Phragmites australis and an unplanted SSF with mainly vertical flow conditions to which Glyphosate was continuously dosed showed that in the planted SSF Glyphosate retardation exceeds 54% compared to 14% retardation in the unplanted SSF. The results show that saturated subsurface passage has the potential to efficiently attenuate glyphosate, favorably with aerobic conditions, long travel times and the presence of planted riparian boundary buffer strips. PMID:21496859
Evaluation of different calibration strategies for large scale continuous hydrological modelling
For the analysis of climate impact on flood flows and flood frequency in macroscale river basins, hydrological models can be forced by several sets of hourly long-term climate time series. Considering the large number of model units, the small time step and the required recalibrations for different model forcing an efficient calibration strategy and optimisation algorithm are essential. This study investigates the impact of different calibration strategies and different optimisation algorithms on the performance and robustness of a semi-distributed model. The different calibration strategies were (a) Lumped, (b) 1-Factor, (c) Distributed and (d) Regionalisation. The latter uses catchment characteristics and estimates parameter values via transfer functions. These methods were applied in combination with three different optimisation algorithms: PEST, DDS, and SCE. In addition to the standard temporal evaluation of the calibration strategies, a spatial evaluation was applied. This was done by transferring the parameters from calibrated catchments to uncalibrated ones and validating the model performance of these uncalibrated catchments. The study was carried out for five sub-catchments of the Aller-Leine River Basin in Northern Germany. The best result for temporal evaluation was achieved by using the combination of the DDS optimisation with the Distributed strategy. The Regionalisation method obtained the weakest performance for temporal evaluation. However, for spatial evaluation the Regionalisation indicated more robust models, closely followed by the Lumped method. The 1-Factor and the Distributed strategy showed clear disadvantages regarding spatial parameter transferability. For the parameter estimation based on catchment descriptors as required for ungauged basins, the Regionalisation strategy seems to be a promising tool particularly in climate impact analysis and for hydrological modelling in general.
PREFACE: Nuclear Cluster Conference; Cluster'07
The Cluster Conference is a long-running conference series dating back to the 1960's, the first being initiated by Wildermuth in Bochum, Germany, in 1969. The most recent meeting was held in Nara, Japan, in 2003, and in 2007 the 9th Cluster Conference was held in Stratford-upon-Avon, UK. As the name suggests the town of Stratford lies upon the River Avon, and shortly before the conference, due to unprecedented rainfall in the area (approximately 10 cm within half a day), lay in the River Avon! Stratford is the birthplace of the `Bard of Avon' William Shakespeare, and this formed an intriguing conference backdrop. The meeting was attended by some 90 delegates and the programme contained 65 70 oral presentations, and was opened by a historical perspective presented by Professor Brink (Oxford) and closed by Professor Horiuchi (RCNP) with an overview of the conference and future perspectives. In between, the conference covered aspects of clustering in exotic nuclei (both neutron and proton-rich), molecular structures in which valence neutrons are exchanged between cluster cores, condensates in nuclei, neutron-clusters, superheavy nuclei, clusters in nuclear astrophysical processes and exotic cluster decays such as 2p and ternary cluster decay. The field of nuclear clustering has become strongly influenced by the physics of radioactive beam facilities (reflected in the programme), and by the excitement that clustering may have an important impact on the structure of nuclei at the neutron drip-line. It was clear that since Nara the field had progressed substantially and that new themes had emerged and others had crystallized. Two particular topics resonated strongly condensates and nuclear molecules. These topics are thus likely to be central in the next cluster conference which will be held in 2011 in the Hungarian city of Debrechen. Martin Freer Participants and Cluster'07
Hyperspectral remote sensing technologies are predestined for analyses and monitoring tasks of coastal and shallow water regions. These technologies enable a simultaneous monitoring of an area which is efficient as well as time and cost saving compared to conventional mapping methods. The existing potential of airborne hyperspectral data to detect and monitor sublitoral vegetation has been proven in previous studies which were carried out mainly in clear and shallow coastal water bodies. To analyze the range of its application and the limitations of this technique we carried out a research study in the turbid water body along the rocky shores of the island Helgoland (Germany). The basis for the mapping of benthic vegetation and sediment is the characterization of the water body which strongly influences the down- and upwelling irradiance. To quantify the spectral response of the benthic areas, a water column correction is essential as the atmospheric correction. To provide hyperspectral data, a flight campaign has been carried out in 2010 using an AISAeagle instrument (420 to 900 nm with a sampling rate of 2 nm). In situ measurements were taken simultaneously to validate the AISAeagle data. RAMSES data and water constituent's analysis (suspended matter, phytoplankton, yellow substances and optical depth) as well as terrestrial reference measurements were carried out to provide a basis for the application of the water column correction. We present the procedure of the applied atmospheric correction as well as a water column unmixing using the modular inversion module (MIP) and classification approach. Special attention was laid to the water column correction: here, scattering and absorbing processes due to varying amounts of water constituents such as suspended sediments, salinity, nutrients, phytoplankton and yellow substance strongly influence the subsurface irradiation conditions. These components have to be quantified with their three dimensional distribution. Special focus had to be set on the concentrations of suspended sediments, because shallow waters in coastal regions contain high amounts of suspended sediments due to river inflow (i.e. river Elbe) and coastal erosion processes.
In flood modeling, many one-dimensional (1D) hydrodynamic and water quality models are too restricted in capturing the spatial differentiation of processes within a polder or system of polders and two-dimensional (2D) models are too demanding in data requirements and computational resources, especially if Monte-Carlo techniques are to be used for model uncertainty analyses. The first goal of this paper is to show the successful development of a quasi-2D modeling approach which still calculates the dynamic wave in 1D but the discretisation of the computational units is in 2D, allowing a better spatial representation of the flow and substance transport processes in the polders without a large additional expenditure on data pre-processing and simulation processing. The models DYNHYD (1D hydrodynamics) and TOXI (sediment and micro-pollutant transport) were used as a basis for the hydrodynamic and water quality simulations. An extreme flood event on the Elbe River, Germany, with a proposed polder system variant was used as a test case. The results show a plausible differentiation of suspended sediment and zinc concentrations within the polders both spatially and temporally. This fulfills the second goal of this research. The third goal of this work is to provide an example methodology of carrying out an environmental risk assessment in inundated areas by flood waters, as required by the European Union floods directive. The deposition of zinc in polders was used for this example, due to its high contamination potential in the Elbe River. The extended quasi-2D modeling system incorporates a Monte-Carlo uncertainty analysis to assess the environmental impact of heavy metal deposition in the polders during extreme flooding. The environmental risk computed gives a 48% chance of exceeding the inspection value of 500 mg zinc/kg sediment for a flood such as the August 2002 event. PMID:18400260
After impoundment of the Three Gorges Reservoir (TGR) in 2003, hydrological regimes of the Yangtze River, upstream and downstream of the Three Gorges Dam, have been changed enormously, leading to significant environmental, ecological and social impacts. Nutrients and pollutants from agriculture, industry and municipalities are of concern due to their impact on the aquatic environment and hence, transport behavior of sediment associated pollutants must be modeled and analyzed to establish a sustainable water reservoir management. As part of the Chinese-German Yangtze-Project [1], two-dimensional numerical model TELEMAC is applied to study the dissolved and particulate pollutant transport at different locations of concern in the TGR. In-situ measurement campaigns for morphology and water quality data using mobile measuring device (MINIBAT) are carried out to provide detailed information for the different water bodies at different time. Additional morphological data are taken from cross-section profiles in the literature, the digital elevation model (DEM) of Shuttle Radar Topography Mission (SRTM) from CGIAR. Daily and hourly water level and discharge, suspended sediment concentration and pollutant loads are obtained from the authorities and extracted from literature. The model describes the spatial-temporal flow field, transport and dispersion of sediment associated pollutants with emphasis on the dynamic interaction and mutual influence of the river Yangtze, its major tributaries and adjacent lagoon-like dead water bodies due to the 30 meter annual reservoir water level fluctuation. Since algae bloom, especially in the tributaries and side arms of the mainstream, is one of the major issues occurred after 2003, the results of the numerical modeling together with the statistical analysis of the MINIBAT measurements are used for the eutrophication status analysis. Acknowledgments The Yangtze-Project is funded by the Federal Ministry of Education and Research (BMBF grant no. 02WT1131) of Germany and the International Science and Technology Cooperation Program of China (NO. 2007DFA90510).
Water resources management and mining in Lusatia. Wasserwirtschaft und Bergbau in der Lausitz
For the past 100 years ground water has been pumped to dewater the deposits in the Lower Lusatian brown coal mining area. This encroachment on large static ground-water supplies, in particular as effected in accordance with the energy policy of the former German Democratic Republic, resulted in the formation of a large cone of depression extending over an area of more than 2100 km[sup 2]. This led to a deficit of more than 9 Gm[sup 3] in the water resources of Lower Lusatia. As a result of the discharge of sump waters into the public receiving watercourses the average run-off increased by more than 30%. The economic consequences that accompanied the social change in Germany from the end of 1989 onwards also had significant effects on the brown coal mining industry. To an increasing degree importance is attached to questions pertaining to the effect of a decrease in output on the water resources economy. During the period up to the year 2000 the average run-off in the River Spree will decrease to about 50% of the initial water level in the period up to the year 1990. A considerable proportion of the future water supply will be provided by the 5 longterm opencast mines of LAUBAG (Lusatian Brown Coal Corporation). With the aid of the sets of ground-water models available at the LAUBAG and an extensive data base, specified targets and concepts as regards water supplies can be converted into reliable forecasts for the water resources economy, taking into account actual planning measures. In this connection interest in focussed primarily not only on ensuring a steady flow into the rivers Spree and Schwarze Elster in future, but, above all, on accelerating replenishment of the ground water and the residual lakes. It is clearly evident that a solution of the water resources problem in Lower Lusatia cannot be reached solely by means of a water resources policy for surface waters that is based on storage systems. (Abstract Truncated)
Towards a New Philosophy of River Engineering in Japan
Rivers are an important part of nature. River regime always changes in accordance with natural law. Rivers react to human activity including river works, often with an undesirable effect. River management must be planned sensitively from upstream to the sea. River basin management is necessary for flood control, water resources development and conservation.
The field of wind power plants can celebrate several achievements. Several targets will have been reached by the end of this year. A major contribution to achieving these goals was made by the REN subsidy programme that pushed forward the set-up of wind power plants in North Rhine-Westphalia. An overview map shows which areas of the Land profited the most from the programme. (AKF) [Deutsch] Die Windkraft-Szene kann feiern: Gleich mehrere `runde Zahlen` werden noch in diesem Jahr erreicht. Kraeftigen Anteil daran hat auch das REN-Foerderprogramm, das den Ausbau in Nordrhein-Westfalen forciert hat. Welche Regionen des Bundeslandes davon am staerksten profitierten, zeigt eine Uebersichtskarte. (orig.)
The detailed characterization of the organic composition of industrial effluents discharged from various industrial branches and the distribution of the emitted pollutants in the surface waters in North Rhine-Westphalia have been done with the use of non-target screening analyses. Based on the characterization of molecular structures of wastewater constituents, their quantification as well as the available information on their origin and industrial applications, the identification of typical organic representatives for petrochemical and food effluents has been performed. Among a wide range of hydrocarbons detected in the petrochemical effluents, several novel organic wastewater constituents have been found for the first time. In the effluents from paper production plant, potential industri...
The object of the research program in allotments of the Rhine-Ruhr-Immission-Area was to establish heavy metal contents in soil and different vegetables. The soil contents of lead, cadmium and zinc are higher in the centre of the area than in the marginal area, where in turn they are higher than in rural areas. The heavy metal uptake of vegetables varies depending on species. Celery, spinach (Cd) and green cabbage (Pb) have the highest level. White and red cabbage and fruit vegetables take up least of both metals. Recommendations are made for soil treatment, the selection of vegetables and the preparating of the products. (orig.).
This paper tests the similarity between premonitory seismicity patterns in active seismic belts and in a platform area of low seismicity. This is of obvious theoretical interest as part of the general problem of similarity in geodynamic processes of different scales. From a more practical point of view, the prediction of earthquakes in platform areas such as the lower Rhine graben is important as the possible damage from earthquakes in this area is rapidly increasing because of the construction of high-risk objects such as dams and nuclear power plants, and the increase of vulnerability of many common structures and lifelines.
The energetic use of biomass experiences new attention in politics and public particularly due to high prices for fossil energy and climate protection. The German bioenergy boom is determined by political decisions. In this sense, the bioenergy markets can be characterized as 'political' markets. This is often ignored given the current euphoria over bioenergy. In the policy debate bioenergy is supported by several arguments including aspects of resources, environment, labour market, economy, technology develop, agriculture, regional and structural policy. While studies of energetic and ecological Life Cycle Assessment (LCA) of the biofuels are already present, the other political aspects are quite little investigated. Particularly against the background of an introduction of the European Agricultural Fund for Rural Development (EAFRD) and an examination of the efficiency of the promotion of biofuels, still, substantial research is needed. The goal of the work is to estimate whether biofuels allow new income possibilities and which rural areas in North Rhine-Westphalia could profit from these new prospects. A possible promotion policy for rural area is outlined which increases the income chances, and at the same time reduced negative environmental effects for the future. The work starts analysing the relevant policy framework of biofuel production in North-Rhine-Westphalia. Key question is which energy crop allows a positive income effect in which regions of North-Rhine-Westphalia. For this the procedure ''energy maize for biogas'' (rape seeds and wheat were already implemented) was integrated into the regionalised agricultural sector model RAUMIS. By the assumption of a completely elastic demand for biomass thereby the ''economic supply potential'' of the energy crops of the North-Rhine/Westphalian agriculture is illustrated under given agricultural and energy-political framework. Beside the quantitative analysis of energy crops which are already well-known in the agriculture by RAUMIS, qualitative analyses for so far few energy crops like Short Rotation Coppice and Miscanthus delivered regional yields, transport costs and profit possibilities. In selected regions it was then examined whether the socio-economic conditions necessary for a successful marketing are present or could be created. From the analysis of the development obstacles as well as from some best practice examples a draft of a promotion policy (recommendations) for rural areas has been developed.
Within the Mesoscale Alpine Programme MAP conducted in autumn 1999, the vertical structure and the temporal evolution of the planetary boundary layer (PBL) in the Rhine Valley 2 km south of Lake Constance were observed with a Remtech PA2 sodar (sound-detection-and-ranging instrument) rendering half-hour averages of the three-dimensional wind profile within the lowest kilometre above ground. During Foehn events, tethered balloon soundings and wind profiler measurements were conducted in addition to the rawinsonde network which was built up for the MAP field campaign.
Collaborative modelling for interactive participation in urban flood risk management
This paper presents an attempt to enhance the role of local stakeholders in dealing with urban floods. The concept is based on the DIANE-CM project (Decentralised Integrated Analysis and Enhancement of Awareness through Collaborative Modelling and Management of Flood Risk) of the ERANET CRUE programme. The main objective of the project was to develop and test the advanced methodology for enhancing the resilience of the local communities to flooding by a participative and interactive approach. Through collaborative modelling, a social learning process was initiated which will enhance the social capacity of the stakeholders due to the interaction process. The other aim of the project was to better understand how data from hazard and vulnerability analyses and improved maps, as well as from the near real time flood prediction, can be used to initiate a public dialogue (i.e. collaborative mapping and planning activities) in order to carry out more informed and shared decision making processes and to enhance flood risk awareness - which will improve the flood resilience situation. The concept of collaborative modelling was applied in two case studies: (1) the Roding river/Cranbrook catchment in the UK, with focus on pluvial flooding, and (2) the Alster catchment in Germany, with focus on fluvial flooding.
Occurrence of pharmaceuticals and personal care products in German fish tissue: a national study.
German Environment Specimen Bank (GESB) fish tissue samples, collected from 14 different GESB locations, were analyzed for 15 pharmaceuticals, 2 pharmaceutical metabolites, and 12 personal care products. Only 2 pharmaceuticals, diphenhydramine and desmethylsertraline, were measured above MDL. Diphenhydramine (0.04-0.07 ng g(-1) ww) and desmethylsertraline (1.65-3.28 ng g(-1) ww) were measured at 4 and 2 locations, respectively. The maximum concentrations of galaxolide (HHCB) (447 ng g(-1) ww) and tonalide (AHTN) (15 ng g(-1) ww) were measured at the Rehlingen sampling site in the Saar River. A significant decrease in HHCB and AHTN fish tissue concentrations was observed from 1995 to 2008 at select GESB sampling sites (r(2) = 0.69-0.89 for galaxolide and 0.89-0.97 for tonalide with p PPCP study conducted in 2006. Proximity of the sampling locations to the upstream wastewater treatment plant discharging point and mean annual flow at the sampling location were found to significantly predict galaxolide and tonalide fish tissue concentrations (HHCB: r(2) = 0.79, p = 0.021 and AHTN: r(2) = 0.81, p = 0.037) in Germany. PMID:22779714
RBIS - An Environmental Information System
The River Basin Information System (RBIS) developed at the Department of Geoinformatics at the Friedrich Schiller University of Jena provides a modular structured and web-based platform for environmental data management and data sharing (http://www.rbis.uni-jena.de). The system is used in several multidisciplinary research projects and provides user-friendly functions for the management, analysis, visualization and presentation of different types of data. These types of data include time series data (e.g. hydrological, climatologically …), geodata, documents and more domain specific modules for example related to soil, vegetation, scenarios, simulation models or indicators. One main focus lies on the maintenance on meta-data to make sure information about data provenance and responsible parties are preserved. Furthermore the fine grained user and permission management of RBIS take care about the access and manipulation rights of all stored data. For an easy data exchange of time series data and other data types RBIS provides several interfaces. One example is a prototypical implementation using OGC standards (Sensor Observation Service (SOS) and WaterML2.0). Since RBIS is used for data in research regions located in different countries (e.g. Brazil, Vietnam, Angola, Chile, Germany) a Multilanguage support was added to address not only research project partners but also local stakeholder and public. We will present the structure, modules, main functions, permission management and interfaces for data exchange of RBIS together with selected examples of RBIS instances.
Nuclear power, society and environment; Nucleaire, societe et environnement
This rubric reports on 12 short notes about scientific facts, and sociological, political and environmental aspects of nuclear power in France and other countries: a new micro-beam line for the nuclear micro-probe of Pierre Sue laboratory; the French government gives permission for the filling up of the Carnet swampy site for the possible sitting of a future nuclear power plant in the Loire river estuary; incident simulation exercise at Chooz B1 in January 1997: radioactive leak and population under shelter; about Superphenix, `Le Monde` newspaper disseminates false information; the anti-Superphenix lobby; Georges Charpak`s opinion about anti-nuclear propaganda; gamma radiation in the help of cultural heritage; a new ionizing particle detector developed by the CEA; dismantling of the FR-2 experimental reactor (Karlsruhe, Germany) and the safe confinement of the reactor vessel; the Russian specialists` proposal for the transformation of Tchernobyl`s sarcophagus into a monolith of concrete; Cogema`s support to scientific research devoted to environment and public health; three new member countries in the World Council of Nuclear Workers (WONUC). (J.S.)
The three papers in this report were presented at the second international workshop to feature the Waste Isolation Pilot Plant (WIPP) Materials Interface Interactions Test (MIIT). This Workshop on In Situ Tests on Radioactive Waste Forms and Engineered Barriers was held in Corsendonk, Belgium, on October 13--16, 1992, and was sponsored by the Commission of the European Communities (CEC). The Studiecentrum voor Kernenergie/Centre D`Energie Nucleaire (SCK/CEN, Belgium), and the US Department of Energy (via Savannah River) also cosponsored this workshop. Workshop participants from Belgium, France, Germany, Sweden, and the United States gathered to discuss the status, results and overviews of the MIIT program. Nine of the twenty-five total workshop papers were presented on the status and results from the WIPP MIIT program after the five-year in situ conclusion of the program. The total number of published MIIT papers is now up to almost forty. Posttest laboratory analyses are still in progress at multiple participating laboratories. The first MIIT paper in this document, by Wicks and Molecke, provides an overview of the entire test program and focuses on the waste form samples. The second paper, by Molecke and Wicks, concentrates on technical details and repository relevant observations on the in situ conduct, sampling, and termination operations of the MIIT. The third paper, by Sorensen and Molecke, presents and summarizes the available laboratory, posttest corrosion data and results for all of the candidate waste container or overpack metal specimens included in the MIIT program.
Mobilization of metals from aquatic sediments; Mobilisierung von Metallen aus aquatischen Sedimenten
In the present study the mobilization of metals from sediments obtained from contributories of the Elbe river (Germany) has been investigated under aerobic and anaerobic conditions. Kinetic experiments under aerobic conditions revealed that Fe plays a major role for the resolubilization of other metals. These are not solubilized until dissolved Fe(II) is oxidized to give Fe(III) and precipitated as iron hydroxide. Under anaerobic conditions Fe, Mn, As, and Cr are better mobilized than under aerobic conditions. Contrarily, Cu, Ni, and Cd are mobilized to a smaller extent because these elements are supposed to be bound in the sediments as insoluble sulfides. Experiments under aerobic conditions with exclusion of microbiological processes led to lower metal resolubilization except for Fe. Microorganisms increase the rate of metal solubilization from contaminated sediments. Finally, the solubility of metal ions has been calculated as a function of the pH value. Different models have been applied. It could be shown that in addition to precipitation, adsorption processes onto the sediment have to be taken into account to get good agreement between calculated and measured data. For metals like Ca, Ni, and Cd the organic content of the sediment as a binding site also had to be considered in the model to obtain satisfying results from model calculations. (orig.)
Over the recent years, several research efforts investigated the impact of climate change on water resources for different regions of the world. The projection of future river flows is affected by different sources of uncertainty in the hydro-climatic modelling chain. One of the aims of the QBic3 project (Québec-Bavarian International Collaboration on Climate Change) is to assess the contribution to uncertainty of hydrological models by using an ensemble of hydrological models presenting a diversity of structural complexity (i.e. lumped, semi distributed and distributed models). The study investigates two humid, mid-latitude catchments with natural flow conditions; one located in Southern Québec (Canada) and one in Southern Bavaria (Germany). Daily flow is simulated with four different hydrological models, forced by outputs from regional climate models driven by a given number of GCMs' members over a reference (1971-2000) and a future (2041-2070) periods. The results show that the choice of the hydrological model does strongly affect the climate change response of selected hydrological indicators, especially those related to low flows. Indicators related to high flows seem less sensitive on the choice of the hydrological model. Therefore, the computationally less demanding models (usually simple, lumped and conceptual) give a significant level of trust for high and overall mean flows.
The small-scale distribution pattern of macroalgae in the river Ilm, in Germany was monitored. These patterns were then related to abiotic factors and tested to discover whether the distribution of the common macroalgae, Cladophora glomerata (L.) Kütz. and Vaucheria sp., was linked to differences in their photosynthetic plasticity. Cladophora glomerata revealed higher maximum photosynthetic electron transport rates after acclimation to high light (HL) compared with low light (LL) acclimated samples. By contrast, Vaucheria sp. did not acclimate to different growth light conditions. The photosynthetic performance of both algae also varied according to diurnal conditions. High light caused a reversible decrease of the dark-adapted quantum yield (F(v)/F(m)) in C. glomerata and a concomitant reversible decrease of the light-adapted quantum yield (DeltaF/F'(m)). In Vaucheria sp., F(v)/F(m) remained mostly unchanged over the day, whereas DeltaF/F'(m) decreased during the morning at low light. Photosynthetic pigments confirmed acclimational differences between the species. HL C. glomerata showed increased chlorophyll a:chlorophyll b ratios, and higher amounts of xanthophyll-cycle pigments compared with LL samples, whereas Vaucheria sp. did not reveal differences between the light treatments. While preferences for substrate size, water velocity, and depth are similar for C. glomerata and Vaucheria sp., the physiological responses to light conditions are different. It is concluded that light conditions significantly affect the small-scale spatial distribution of macroalgae and that fitness is enhanced in species with a higher plasticity in photosynthetic acclimation in unstable environments. PMID:15996986
Subaquatic sediment samples derived form Elbe and Mulde Rivers, Germany, were analyzed for extractable and non-extractable anthropogenic organic compounds by a non-target screening approach. Applied methodologies were gas chromatography-mass spectrometry, dispersion extraction and degradation procedures, particularly alkaline and acidic hydrolysis, boron tribromide treatment, ruthenium tetroxide oxidation as well as pyrolysis and TMAH (tetramethylammonium hydroxide)-thermochemolysis. Numerous compounds were identified, including halogenated benzenes, anisoles, styrenes, alkanes, diphenylmethane derivates, anilines, phenols and diphenyl ethers. The results were interpreted with respect to compound specific modes of incorporation as well as to potential sources (e.g. municipal, agricultural, industrial). Extractable and non-extractable fractions differed significantly with respect to their qualitative and quantitative composition. For example, quantities in the extractable and non-extractable fractions of chlorinated benzenes differed up to factor 50. Among other significant results, the investigation revealed hints for a dependence of the mode of incorporation of chlorinated benzenes on their substitution pattern. - Analysis of both, extractable and non-extractable fraction of organic xenobiotics in sediments reveals a more detailed and comprehensive anthropogenic load profile.
Linking biological and physicochemical water quality.
To define water quality, the European Water Framework Directive (WFD) demands complex assessments through physicochemical, biological, and hydromorphological controls of water bodies. Since the biological assessment became the central focus with hydrochemistry playing a supporting role, an evaluation of the interrelationships within this approach deems necessary. This work identified and tested these relationships to help improve the quality and efficiency of related efforts. Data from the 384 km(2) Weisseritz catchment (eastern Erzgebirge, Saxony, Germany and northern Bohemia, Czech Republic) were used as a representative example for central European streams in mountainous areas. The data cover the time frame 1992 to 2003. To implement WFD demands, the analysis was based on accepted German methods and classifications, WFD quality standards, and novel German methods for the biological status assessment. Selected chemical parameters were compared with different versions of the German Saprobic Index, based on macroinvertebrate indicator taxa. Relevant dependencies applicable for integrated stream assessment were statistically tested. Correlation analysis showed significant relationships. The highest scores were found for nutrients (NO(2)(-), N(inorg), and total N), salinity (Cl(-), SO(4)(2-), conductivity), and microelements (K(+), Na(+), Ca(2+), Mg(2+)). The Saprobic Index used in the Integrated Assessment System for the Ecological Quality of Streams and Rivers throughout Europe using Benthic Macro-invertebrates program seems to be the most sensitive indicator to correlate with chemical parameters. PMID:19067209
In a 2-year research project the designation of heavily modified water bodies according to the European Water Framework Directive (WFD) has been examined on the basis of four case studies, namely the river basin districts of the Elbe, Lahn, Seefelder Aach and Dhuenn, in order to concretise the WFD requirements in Germany. In particular, the purpose of these case studies was to actively support the CIS working group 2.2 ''Heavily Modified Water Bodies'' during the development of the European guidance document for the identification and designation of heavily and artificial water bodies. The support was given by cooperating together with the international subgroups ''Navigation'' and ''Hydro Power Generation'' and by participating at European workshops on that topic. The study focuses on the development and testing of criteria to identify significant physical alterations, scenario development of measures to reach the good ecological status and their evaluation within an economic analysis. Furthermore, the identification of the conditions to achieve by establishing criteria for heavily modified water bodies with special emphasis on maximum and good ecological potential has been elaborated. Additional results refer to the scales that should be applied for the identification of water bodies, testing of criteria, evaluating ecological status and ecological potential and linking the IMPRESS and HMWB guidance documents produced by the CIS working groups. (orig.)
The aim of this diploma thesis is twofold: Firstly to show for a given subcatchment how the risk ''flood'' could possibly alter under climate change. Secondly it will be analysed how potentially affected persons individually perceive this change of risk. To accomplish this aim the thesis is based on an interdisciplinary approach which combines methods of the natural- and social sciences. The methods of the natural sciences are mainly based on hydrological techniques and the application of climate change scenarios while the methods of the social sciences deal with perception- and speculation horizons of individual persons. Within this context different definitions of the term ''risk'' will be discussed. Further it will be pointed out that the term risk can be understood as a result of different, respectively process related, correlations. The first part includes calculations on the possible future development of floodrisk in a subcatchment of the river Neckar in southwest Germany. These analyses will be based on applications of the hydrological model HBV-D and the integration of statistically downscaled and therefore regionalized climate change scenarios. The second part deals with the perceptions of selected stakeholders, who were confronted with the results from the hydrological studies. These analyses will primarily be based on statistical evaluations of interviews in the surrounding area of the city of Pforzheim, involving households, decision-makers and also pupils from two local grammar schools. (orig.)
Important aspects of LNG transport safety
Calculations made by West Germany's Liquid Gas Anlagen show that a worst-case collision between two LNG tankers traveling at 6 to 8 miles (10 to 14 km)/hr would cause damage to the cargo tanks, LNG spillage, and the subsequent formation of an explosive natural-gas cloud. The study focuses on river or coastal-water tankers with two specific hull designs - one having an inward-curved prow and the other a bulbous prow that juts out below the water line. At a velocity of 8 miles (14 km)/hr, a 6400-cu-ft (1800-cu-m), curved-prow tanker, colliding with the tank section of an identical vessel, would penetrate a distance of 3.8 in. (0.1 m) into the tank, causing a 2.7-sq-ft (0.25-sq-m) tear. A 9900-cu-ft (2800-cu-m) tanker with a bulbous prow would penetrate
