WorldWideScience
3

Total phenolic content and antioxidant capacity of extracts obtained from six important fruit residues  

British Library Electronic Table of Contents (United Kingdom)

The extracts from kinnow peel, kinnow seeds, litchi pericarp, litchi seeds, grape seeds, and banana peel were screened for total phenolic content (TPC), trolox equivalent antioxidant capacity (TEAC), 1,1 diphenyl-2-picryl hydrazyl (DPPH) radical scavenging activity, as well as reducing power. Kinnow peel extract exhibited the highest reducing power, TEAC, and DPPH free radical scavenging activity, whereas, the phenolic content of 37.4 mg GAE/g-dw was highest for grape seed extract. Banana peel extract with a low TPC showed the lowest reducing power, TEAC as well as DPPH free radical scavenging activity among the fruit residue extracts examined in the present study. Correlation analysis between the reducing power and DPPH radical scavenging ability; reducing power and ABTS radical scavengin...

2011-01-01

4

Use of absorbable mesh to displace bowel and avoid radiation enteropathy, during therapy of pelvic Ewing's sarcoma  

International Nuclear Information System (INIS)

The use of absorbable polyglactin 910 mesh (Vicryl) is described in a case of Ewing's sarcoma of the pelvis. An operation was performed to hold the small bowel and colon out of the pelvis for a temporary period during which radical radiotherapy was delivered. The mesh allowed the temporary displacement of bowel and obviated bowel radiation morbidity. (author).

5

Seismic proving test of heavy component with energy absorbing support. Proving seismic reliability of the system and developing characteristics evaluation equation of energy absorbing support  

International Nuclear Information System (INIS)

The Seismic Proving Test of Heavy Component with Energy Absorbing Supports has been conducted to prove the reliability of advanced seismic technology, supporting heavy component such as PWR steam generator with large capacity energy absorbing supports under the sponsorship of Ministry of Economical Trade and Industry. If energy absorbing supports are adopted for NPP heavy components, support structure of facility will be much simplified due to their seismic energy absorbing effect. The paper describes the results of lead damper element test and seismic test at Tadotsu Laboratory, using 1/2.5 scale PWR Steam Generator model supported by Lead Extraction Damper (LED) and development of characteristics evaluation formula of energy absorbing support. (author)

2003-09-15

6

Enhancement of Heat and Mass Transfer in Mechanically Contstrained Ultra Thin Films  

Energy Technology Data Exchange (ETDEWEB)

Oregon State University (OSU) and the Pacific Northwest National Laboratory (PNNL) were funded by the U.S. Department of Energy to conduct research focused on resolving the key technical issues that limited the deployment of efficient and extremely compact microtechnology based heat actuated absorption heat pumps and gas absorbers. Success in demonstrating these technologies will reduce the main barriers to the deployment of a technology that can significantly reduce energy consumption in the building, automotive and industrial sectors while providing a technology that can improve our ability to sequester CO{sub 2}. The proposed research cost $939,477. $539,477 of the proposed amount funded research conducted at OSU while the balance ($400,000) was used at PNNL. The project lasted 42 months and started in April 2001. Recent developments at the Pacific Northwest National Laboratory and Oregon State University suggest that the performance of absorption and desorption ...

2005-01-01

7

The effect of extraction temperature, time and number of steps on the antioxidant capacity of methanolic banana peel extracts  

British Library Electronic Table of Contents (United Kingdom)

A solvent extraction method was developed to obtain methanolic extracts rich in antioxidants from banana peel. Central composite design ''2^3+star'' and response surface methodology were used in order to optimise the number of extraction steps, extraction temperature and extraction time. The number of extractions was statistically the most significant factor in scavenging activity against both DPPH? and ABTS?^+ radicals and in the inhibition of TBARS formation, while the extraction temperature had an important impact on the capacity to prevent b-carotene bleaching. However, the effect of the extraction time on antioxidant activity was less important. The optimum values of the factors that influence the capacity to scavenge DPPH? and ABTS?^+ radicals or to inhibit b-carotene bleaching were ...

2010-01-01

8

Antioxidant activity in banana peel extracts: Testing extraction conditions and related bioactive compounds  

British Library Electronic Table of Contents (United Kingdom)

Banana (Musa acuminata Colla AAA) peel extracts obtained in this work had a high capacity to scavenge 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2prime-azino-bis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS+) free radicals, and they were also good lipid peroxidation inhibitors. Acetone:water extracts were considerably more effective (compared with methanol, ethanol, acetone, water, methanol:water or ethanol:water) at inhibiting the peroxidation of lipids in the b-carotene/linoleic acid system or scavenging free radicals. However, aqueous extracts had a high capacity to protect lipids from oxidation in the thiobarbituric acid reactive substances (TBARS) test, as well as in the b-carotene bleaching assay. In addition, acetone:water most efficiently extracted all extractable components (54+-...

2010-01-01

9

Semiactive field-controllable magneto-rheological fluid dampers for mountain bicycles  

Science.gov (United States)

This paper presents the development and evaluation of field- controllable, semi-active magneto-rheological fluid (MRF) shock absorbers for a mountain bicycle. Recent trends in the bicycle industry show a movement towards semi-active suspension systems. Two new MRF dampers are designed and tested with the intent of being used on the front and rear suspension of a modern mountain bicycle. The MRF shock absorbers are designed to emulate the performance of the original equipment manufacturer shock absorbers in passive mode. Application of an input electric current to the MRF shock absorber causes a dramatic increase in the damping capacity. Procedures and results are presented for the design and experimental characterization of these MRF dampers.

2000-06-01

10

Irradiation of polyethylene in the presence of antioxidants  

International Nuclear Information System (INIS)

The radiation induced reactions in LDPE in the presence of phenolic type antioxidants have been studied. It was shown that various antioxidants can influence the polyethylene network formation and the radical yield in different ways. The dependence of network structure on absorbed doses was determined by gel analysis, hot-set test and extraction of antioxidants for samples irradiated with accelerated electrons. It was found that the antioxidants eluted from polyethylene in higher percentage influence polymer crosslinking to a smaller degree. The ESR studies of #gamma#-irradiated blends of polyethylene with antioxidant indicate the presence of alkyl and phenoxyl radicals. The role of antioxidant molecules on radiation induced reactions in polyethylene-antioxidant systems is considered. The correlation between the network structure and the type of additive in polyethylene is also discussed. (author).

11

Sulfur dioxide adsorption from exhaust gases by adsorbents based on 2,4,6-triamino-1,3,5-triazine  

Energy Technology Data Exchange (ETDEWEB)

The equilibrium dynamic capacity of polymer materials based on 2,4,6-triamino-1,3,5-triazine has been determined. The possibility of their application as absorbents of sulfur dioxide from exhaust gases has been shown.

1995-05-10

12

Free radicals in lysozyme reacted with peroxidizing methyl linoleate  

International Nuclear Information System (INIS)

... electron spin resonance gamma radiation lipids lyophilization lysozyme radicals

13

Kinetics and mechanism of superoxide radical reactions with some biologically important compounds in aqueous solutions. Pulse radiolysis  

International Nuclear Information System (INIS)

Microsecond pulse radiolysis of oxygenated aqueous solutions containing 0.02 mol dm"-"3 sodium formate and 2 mmol dm"-"3 phosphate buffer at pH 7 was used to generate superoxide anion radicals. The influence of some biologically important compounds upon the rate of O_2"."-"b"a"r decay as monitored spectrophotometrically in the range of 245-300 nm. Hematoporphyrin (HP), hemin C (HC), catalase (Cat), cobalt sulfophthalocyanine (CoTSPc) were studied. Among the investigated compounds only Cat was found to show a high catalytic efficiency towards the self-decay of O_2"."-"b"a"r. A red shift of 0_2"."-"b"a"r absorption band and slowing down of its decay were observed to take place by adding HP or CoTSPc to the solutions containing formate ions in excess. This effect is associated with the formation of a transient superoxo-complex. An appearance of an intermediate species with absorption maxima at 350 nm and half-life of about 2 s was observed to accompany the ...

14

Photosensitization by drugs. [Ultraviolet radiation  

Science.gov (United States)

uv irradiation (365 nm) of air-saturated methanol solutions of 20 drugs absorbing in the 300 to 400 nm region gave rise to oxygen uptake, as determined with a polarographic oxygen electrode. The drugs were tested for photosensitizing capability by either a Type I (free radical) or a Type II (single molecular oxygen) mechanism. This testing was done by the inclusion of either acrylamide or 2,5-dimethylfuran in the irradiated drug solution, with observation of the subsequent polymerization or oxidation, respectively. Phenothiazine and thiazide derivatives appear capable of photosensitization by both mechanisms; promethazine, trifluoperazine, and furosemide show relatively high reactivity. Diazepam (weak), hexachlorophene, aminacrine, pyrilamine, tetracycline, demeclocyline, quinine, and anthracene (strong) react only by a Type II mechanism, with a photosensitizing efficiency increasing in the order given. A correlation appears to exist with ...

1977-09-01

15

Kinetic investigations of graft copolymerization of sodium styrene sulfonate onto electron beam irradiated poly(vinylidene fluoride) films  

Energy Technology Data Exchange (ETDEWEB)

Graft copolymerization of sodium styrene sulfonate (SSS) onto electron beam (EB) irradiated poly(vinylidene fluoride) (PVDF) films was investigated to find out a simple preparation process for sulfonic acid proton exchange membranes with respect to monomer concentration, absorbed dose, temperature, film thickness and storage time. The reaction order of the monomer concentration and absorbed dose of grafting was found to be 2.84 and 1.20, respectively. The overall activation energy for graft copolymerization reaction was calculated to be 11.36 kJ/mol. The initial rate of grafting was found to decrease with an increase in the film thickness. The trapped radicals in the irradiated PVDF films remained effective in initiating the reaction without considerable loss in grafting level up to 180 days, when stored under -60 {sup o}C. The presence and distribution of polystyrene sulfonate grafts in the obtained membranes were observed ...

2011-01-15

16

Transuranic separation using organophophorus extractants adsorbed onto superparamagnetic carriers.  

Energy Technology Data Exchange (ETDEWEB)

Polymeric coated ferromagnetic carriers with an absorbed layer of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) diluted by tributyl phosphate (TBP) are being evaluated for application in the separation and the recovery of low concentrations of americium, plutonium, and uranium from nuclear waste solutions. Due to their chemical nature, these extractants selectively complex americium and plutonium contaminants onto the particles and the complexed particles can be recovered from the solution using a magnet. Physical and chemical characterization of the extractant-absorbed particles were performed by gamma and liquid scintillation counting, scanning electron microscopic (SEM) micrograph, and other physical measurements. Plutonium, americium, and uranium separations have been performed at various HNO{sub 3} and HCl concentrations. Parameters were studied to determine the limitations and capacity of the ...

1998-10-07

17

A hydroxide mixture as working fluid for absorption heat pumps  

Energy Technology Data Exchange (ETDEWEB)

Basic experimental investigations were carried out with an aqueous solution of a mixture of KOH and NaOH for use as an absorbent in absorption heat pumps. Due to its thermophysical properties this mixture allows temperature lifts from evaporator to absorber of more than 75 K (135 F) in a single-stage absorption chiller. Thermophysical and hydrodynamical properties of the solution were measured. Vapor-liquid-equilibrium data and specific heat capacities were determined for concentrations ranging from 35% up to 75% and temperatures up to 200 C (392 F). From these data the enthalpy of the solution was calculated. Additionally the crystallization temperatures, the density, and the viscosity of the solution were determined. The experimental equipment is described. The data are presented as polynomials and diagrams including experimental accuracy. An apparatus was constructed to measure heat and mass transfer coefficients of the ...

1996-11-01

18

Evaluation of antioxidant and anti-atherogenic properties of Glycyrrhiza glabra root using in vitro models.  

Science.gov (United States)

The aim of present study was to evaluate antioxidant property of Glycyrrhiza glabra root extracts using in vitro models. The dose-dependent aqueous and ethanolic extracts demonstrated the scavenging activity against nitric oxide (concentration that caused 50% inhibition of nitric oxide radicals [IC(50)]=72 and 62.1 microg/ml, respectively), superoxide (IC(50)=64.2 and 38.4 microg/ml, respectively), hydroxyl (IC(50)=81.9 and 63 microg/ml, respectively), DPPH (IC(50)=43.6 and 28.3 microg/ml, respectively) and ABTS(*+) (IC(50)=77.3 and 57.2 microg/ml, respectively) radicals. Further, both extracts showed strong reducing power and iron-chelating capacities. In the Fe(2+)/ascorbate system, both extracts were found to inhibit mitochondrial fraction lipid peroxidation. In copper-catalyzed human serum and low-density lipoprotein oxidation models, both extracts significantly (P<0.05) lengthened the lag phase along with a decline ...

2009-04-22

19

Development program for magnetically assisted chemical separation: Evaluation of cesium removal from Hanford tank supernatant  

International Nuclear Information System (INIS)

Magnetic particles (MAG*SEP"S"M) coated with various absorbents were evaluated for the separation and recovery of low concentrations of cesium from nuclear waste solutions. The MAG*SEP"S"M particles were coated with (1) clinoptilolite, (2) transylvanian volcanic tuff, (3) resorcinol formaldehyde, and (4) crystalline silico-titanate, and then were contacted with a Hanford supernatant simulant. Particles coated with the crystalline silico-titanate were identified by Bradtec as having the highest capacity for cesium removal under the conditions tested (variation of pH, ionic strength, cesium concentration, and absorbent/solution ratio). The MAG*SEP"S"M particles coated with resorcinol formaldehyde had high distribution ratios values and could also be used to remove cesium from Hanford supernant simulant. Gamma irradiation studies were performed on the MAG*SEP"S"M particles with a gamma dose equivalent to 100 cycles of use. ...

1994-05-09

21

R and D on high efficiency CO{sub 2} separation processes for enhanced oil recovery at the University of Regina  

Energy Technology Data Exchange (ETDEWEB)

Research facilities and personnel in high efficiency separation processes for carbon dioxide removal from industrial sources, such as fossil fuel fired power stations, goal gasification plants, and hydrogen production units for enhanced oil recovery applications at the University of Regina were described. A brief summary of current projects, such as the determination of CO{sub 2} absorption capacity of sterically hindered amines, the formulation of high CO{sub 2} absorption capacity solvents, the search for high performance absorbers and regenerators, studies on material corrosion, and optimization and cost studies of co-production of CO{sub 2} and electricity, was also provided.

1997-02-01

22

ESR study on the reaction of MMA with the radicals in pre-irradiated wood  

International Nuclear Information System (INIS)

The nature of radicals in wood irradiated in vacuum was studied by ESR method. The decay rate of radicals changes in three temperature ranges. Long-lived radicals are very stable at 298"0K, at which the wood-plastics composite has often been studied. The number of radicals formed by irradiations shows fairly good agreement with the total number of radicals in each isolated wood component. The graft copolymerization of MMA to irradiated wood was also studied by means of ESR, and it was found that PMMA propagating radicals are formed in irradiated wood. These radicals are probably formed by the result of graft copolymerization of MMA of wood. (auth.).

1975-01-01

23

Heat capacity measurements of atoms and molecules adsorbed on evaporated metal films  

Energy Technology Data Exchange (ETDEWEB)

Investigations of the properties of absorbed monolayers have received great experimental and theoretical attention recently, both because of the importance of surface processes in practical applications such as catalysis, and the importance of such systems to the understanding of the fundamentals of thermodynamics in two dimensions. We have adapted the composite bolometer technology to the construction of microcalorimeters. For these calorimeters, the adsorption substrate is an evaporated film deposited on one surface of an optically polished sapphire wafer. This approach has allowed us to make the first measurements of the heat capacity of submonolayer films of /sup 4/He adsorbed on metallic films. In contrast to measurements of /sup 4/He adsorbed on all other insulating substrates, we have shown that /sup 4/He on silver films occupies a two-dimensional gas phase over a broad range of coverages and temperatures. Our apparatus has been used to ...

1989-05-01

24

Radiation-induced reduction of ditetrazolium salt in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

Color formation in aqueous solutions of the ditetrazolium salt blue tetrazolium (BT{sup 2+}) in the absence or presence of oxygen is a complex radiation chemical reaction. The final stable product is the poorly soluble diformazan violet to blue pigment having a broad spectral absorption band ({lambda}{sub max}=552 nm). The reaction of BT{sup 2+} with the hydrated electron proceeds by rapid reduction of BT{sup 2+} followed by protonation at the nitrogen closest to the unsubstituted phenyl group, via the two intermediate tetrazolinyl radicals shared by the ditetrazole ring nitrogens. The effect of solution pH, N{sub 2}O saturation, and the presence of the reducing agent dextrose are examined. The system serves as a radiochromic sensor and a dosimeter of ionizing radiations. Solutions of 5 mmol l{sup -1} BT{sup 2+} at pH 7.3 serve as dosimeters over an absorbed-dose range of approximately 0.2-6 kGy (dearated, with a range of 1-8 mmol l{sup -1} ...

2002-04-01

25

Role of nitroso radicals as drug targets in circulatory shock  

UK PubMed Central (United Kingdom)

A vast amount of circumstantial evidence implicates oxygen-derived free radicals (especially, superoxide and hydroxyl radical) and high-energy oxidants [such as peroxynitrite (OONO)]...Full Text Available

2009-06-01

26

Process for preparing inorganic particulate adsorbent and process for treating nuclear reactor core-circulating water  

Energy Technology Data Exchange (ETDEWEB)

An inorganic particulate adsorbent of a titania-alumina is described for treating a superheated water containing radioactive materials such as cobalt ions, which is free from release of corrosive impruities, and which has a high adsorption capacity of radioactive materials and a high mechanical strength is prepared by hydrolyzing a titanium alkoxide and an aluminum alkoxide, thereby forming a hydrous titanium oxide and a hydrous aluminum oxide, respectively; precalcining the hydrous titanium oxide and aluminum oxide, mixing and molding the resulting titania and alumina into a particulate mixture thereof having a titania mole fraction of 0.2 to 0.9, and calcining the particulate mixture at 500/sup 0/-700/sup 0/C. This absorbent is effectively used in treat boiling water-type nuclear reactor core-circulating water to remove radioactive substances therefrom.

1981-08-04

27

Radical Behaviorism and Buddhism: Complementarities and Conflicts  

UK PubMed Central (United Kingdom)

Comparisons have been made between Buddhism and the philosophy of science in general, but there have been only a few attempts to draw comparisons directly with the philosophy of radical behaviorism....Full Text Available

2008-01-01

28

Electroweak measurements at CDF  

Energy Technology Data Exchange (ETDEWEB)

The authors present some recent measurements on electroweak physics using data collected by the CDF experiment at the Tevatron proton anti-proton collider ({radical}s = 1.96 TeV) at Fermilab.

2005-06-01

29

The preparation of highly absorbing cellulosic copolymers -the cellulose acetate/propionate-g. co-acrylic acid system  

Energy Technology Data Exchange (ETDEWEB)

A series of copolymers based on the cellulose acetate/propionate-g.co-acrylic acid system has been prepared under radiation-induced control. These copolymers have been assessed for their water-retention capacity both in an unmodified state and after ''decrystallization'' or ''neutralization'' treatments. The grafting of acrylic acid onto the cellulose acetate/propionate had little effect on the water retention power of the cellulose acetate/propionate. However, improvements to the water retentivity was obtained after ''decrystallization'' procedures had been carried out on the copolymers using selected alkali metal salts with methanol as the continuous medium. The water-retentivity of the copolymers increased with increase in the extent of grafting, though the effect is less pronounced at high graft levels. Neutralization of the functional groups of the ...

1990-01-01

30

Fuel processing equipment for fuel cell plant. Nenryo denchi plant no nenryo shori sochi  

Energy Technology Data Exchange (ETDEWEB)

Activated charcoal which is the desulfurizing agent for the fuel cell plant can be used only at the normal temperature, and it must be placed upstream of the fuel gas, increasing the displacement flow of the fuel gas processed in the desulfurizer. In addition, a large quantity of activated charcoal must be filled or the frequency of its exchange must be increased because activated charcoal used at the normal temperature has little sulfur absorbing capacity. This invention is concerned with provision of a desulfurizer in the downstream of the fuel gas compressor of the fuel cell plant to remove sulfur content in the fuel gas by this desulfurizer. As a result, the displacement flow of the processing gas is decreased to increase the processing capacity of the desulfurizing agent. In addition, hydrogen recycling can be eliminated to realize compact arrangement of the equipment and economization of energy consumption. Metal ...

1993-02-19

35

Quantitative determination of atmospheric hydroperoxyl radical  

Energy Technology Data Exchange (ETDEWEB)

A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.

2007-10-23

37

Lysis of phespholipid membranes with radiation-induced free radicals  

International Nuclear Information System (INIS)

Phospholipid vesicles were found to be lysed by exposure to free radicals derived from irradiated glycine and galactose. The decomposition yield increased with vesicle concentration, and attained values of 0.0006 vesicles destroyed per radical added. Ionic charge at the phospholipid end groups was found to be more important than degree of unsaturation in determining this yield. Radicals derived from irradiated serine and alanine had no detectable lytic action at the vesicle concentrations tested.

1977-05-01

40

Retrospective individual dosimetry using luminescence and EPR after radiation accidents  

International Nuclear Information System (INIS)

In areas where radiation dose monitoring has not been performed, it is essential to use material available in the environment be able to rapidly assess doses to individuals for immediate emergency medical care or for general estimation of the radiological consequences. It was shown that certain types of telephone cards containing microchips have the potential to be used as individual radiation dosimeters in emergency situations to detect doses over 250 mGy by luminescence measurements. In order to understand the dosimetric properties of chip cards, the components obtained from INFINIEON Company at various stages of production were used for luminescence measurements. It is found that the protecting layer used above the chips so called 'globe top' is the main source of radiation induced signal in chip cards. The globe top produced by INFINIEON at that stage is found to contain SiO2 and Epoxy. In order to improve the dosimetric properties of the chip cards, the raw material of the globe ...

41

Free radicals and their transformations in irradiated proteins  

International Nuclear Information System (INIS)

Experimental investigation data are systematized of free radical states and processes in irradiated proteins. The investigation is performed by the radiospectral methods. Results are discussed in detail of the study of free radicals electronic structure of amino acids, peptides and proteins formed by the action of ionizing radiation. The specificity is stressed of the study of monocrystalls of these compounds by the method of electronic paramagnetic resonance. The nature is also studied of primary centres formed under the effect of radiation on biologically important compounds and their subsequent reactions in solid and liquid solutions. Ion-radical states of different functional groups of the protein molecule are studied. Prospects of the study and the role of anion-radicals in biological processes are discusses.

42

ESR spectra of radicals of gamma-irradiated wood and cellulose  

International Nuclear Information System (INIS)

Spectra of e.p.r. radicals in cellulose and timber gamma-irradiated at 77 and 300 K have been measured. Radiation yields and the kinetics of radicals accumulation have been studied. The effect of ionizing radiation on cellulose is the appearance of radicals resulting from rupture of C-H bonds in positions 1 and 4. Timber, additionally, forms ''lignin'' radicals. A mechanism of cellulose and timber radiolysis is suggested. ''Lignin''-type compounds present in timber protect polysaccharides from radiation-induced destruction.

43

Study of the physical and mechanical changes in packaging materials used in radiation processing - measuring methods of physical and mechanical properties  

International Nuclear Information System (INIS)

The behaviour of the packaging materials under radiation field has a great importance in radiation processing, because, in most cases, they are finally responsible for the preservation of the beneficent changes achieved in irradiated products. For example, in radiation sterilisation and food irradiation, the packages must preserve the sterilisation, respectively the sanitisation. They must preserve also the physical barrier feature. The radiation effects on plastics were extensively studied in the last decades for nuclear industry and more recently for radiation processing. The two major effects of nuclear radiation on polymeric materials are the degradation and cross-linking. The degradation consists in breaking of macromolecules after interaction with nuclear particles, amplified by the free radicals which persist long periods, especially in crystalline polymers. Oxygen could penetrate the sample and interact with free radicals so that the ...

44

ESR study of the aziridine and azetidine radical cations: evidence for the C...C ring-opened aziridine radical cation  

International Nuclear Information System (INIS)

The radical cations from aziridine and azetidine have been characterized by ESR spectroscopy following their generation in the solid state by #gamma# irradiation of dilute solutions of the parent compounds in the CFCl_3 matrix at 77 K. The ESR parameters of the azetidine radical cation are typical of those for nitrogen-centered amine radical cations such as Me_2NH*"+. On the other hand, the radical cation formed from aziridine has very different ESR parameters that compare closely to those for the isoelectronic C...C ring-opened form of the oxirane radical cation and the allyl radical. The radical cation formed from azetidine is therefore assigned a ring-closed structure with the unpaired electron in a 2p/sub z/ orbital on nitrogen perpendicular to the ring plane, whereas the cation from aziridine is an allylic C...C ring-opened planar ...

45

ESR study of the aziridine and azetidine radical cations: evidence for the C. C ring-opened aziridine radical cation  

Energy Technology Data Exchange (ETDEWEB)

The radical cations from aziridine and azetidine have been characterized by ESR spectroscopy following their generation in the solid state by ..gamma.. irradiation of dilute solutions of the parent compounds in the CFCl/sub 3/ matrix at 77 K. The ESR parameters of the azetidine radical cation are typical of those for nitrogen-centered amine radical cations such as Me/sub 2/NH*/sup +/. On the other hand, the radical cation formed from aziridine has very different ESR parameters that compare closely to those for the isoelectronic C...C ring-opened form of the oxirane radical cation and the allyl radical. The radical cation formed from azetidine is therefore assigned a ring-closed structure with the unpaired electron in a 2p/sub z/ orbital on nitrogen perpendicular to the ring plane, whereas the cation from aziridine is an allylic C...C ...

1986-05-22

46

Separation of the components of the binary mixture ethanol-water by steam flux in solid phase column; Separacao dos componentes da mistura binaria etanol-agua por passagem do vapor em coluna de fase solida  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

1987-12-31

47

Improvement of leaching characteristics of TOC from condensate demineralizers  

International Nuclear Information System (INIS)

Recent nuclear power plants require high purity water to protect nuclear reactors or steam generators from SCC and maintain in good condition. In this connection, it is especially important to minimize sulfate, which is a corrosive chemical originated from oxidative degradation of cation exchange resins during operation. Recently, uniform particle size (UPS) strong acid cation gel resin with 14% cross-linkage, which has excellent stability against oxidization, has been applied to several condensate purification systems. For further improvement of water quality, some methods for changing the configuration of condensate demineralizer's resin bed have been examined. For example, these methods correspond to anion under layer and cation over layer. We have tested these methods by cold column tests. Furthermore, we have developed the newly anion exchange resin having higher efficiency and capacity for absorbing leachables from cation exchange resins. ...

2009-10-01

48

Absorption of CO{sub 2}, H{sub 2}, S, and NO using dry FGD wastes  

Energy Technology Data Exchange (ETDEWEB)

Limestone-based sorbents are used extensively in utility boilers and tail-gas desulfurization units to remove sulfur oxides formed during the combustion of fossil fuels. Such units generate {approximately}20 million tons of flue-gas desulfurization (FGD) wastes in the U.S. annually, the bulk of which ({approximately}95%) are discarded in landfills or holding ponds. However, a significant portion of the Ca in these materials is not sulfated (remains as CaO or Ca(OH){sub 2}), particularly in units that generate dry wastes. When hydrated, such wastes exhibit a strong affinity to absorb acid gases at ambient temperature. This study represents a continuation of previously reported CO{sub 2}-absorption studies and includes more recent work on the absorption of H{sub 2}S and NO. Ten FGD-waste samples along with a control fly ash were examined. Absorption capacities, the role of available calcium and particle size, and mineralogic changes in the wastes ...

1996-10-01

49

The Abandoned Radical Hysterectomy for Cervical Cancer: Clinical Predictors and Outcomes  

UK PubMed Central (United Kingdom)

Objective. Cervical cancer patients who had an abandoned radical hysterectomy were evaluated for preoperative clinical predictors, complication rates, and outcomes. Study...Full Text Available

2010-01-01

51

Mechanism of atmospheric photooxidation of organic compounds. Reactions of alkoxy radicals in oxidation of n-butane and simple ketones  

Energy Technology Data Exchange (ETDEWEB)

The OH-initiated photo-oxidation of n-butane was used as a source of 1- and 2-butoxy radicals. Reactions producing ketones and other organic compounds are explained. Rates of photolysis were determined and are discussed.

1981-05-01

52

Impact of Posterior Urethral Plate Repair on Continence Following Robot-Assisted Laparoscopic Radical Prostatectomy  

UK PubMed Central (United Kingdom)

PurposeThe objective of this study is to evaluate the continence rate following reconstruction of the posterior urethral plate in robot-assisted laparoscopic radical prostatectomy...Full Text Available

2010-05-01

53

Free radical mediated cell toxicity by redox cycling chemicals.  

UK PubMed Central (United Kingdom)

Free radical formation has been implicated in the toxicity of a wide range of xenobiotics. In recent years, particular interest has been paid to compounds which can undergo a one electron reduction...Full Text Available

1987-06-01

54

Effects of Kombucha on oxidative stress induced nephrotoxicity in rats  

UK PubMed Central (United Kingdom)

BackgroundTrichloroethylene (TCE) may induce oxidative stress which generates free radicals and alters antioxidants or oxygen-free radical scavenging enzymes.MethodsTwenty...Full Text Available

55

Changes in health utilities and health-related quality of life over 12 months following radical prostatectomy  

UK PubMed Central (United Kingdom)

Introduction:Although radical prostatectomy (RP) is an effective treatment for prostate cancer, it has potentially deleterious effects on health-related quality of life (HRQoL)....Full Text Available

2009-12-01

56

Adherence to 7-Day Primaquine Treatment for the Radical Cure of P. vivax in the Peruvian Amazon  

UK PubMed Central (United Kingdom)

Despite being free of charge, treatment adherence to 7-day primaquine for the radical cure of Plasmodium vivax was estimated at 62.2% among patients along the Iquitos-Nauta road in...Full Text Available

2010-06-01

57

Chemical and electrochemical dehydriding characteristics of TiV{sub 2.1}Ni{sub 0.3}-Raney Ni composite prepared by ball-milling in the presence of a reducing agent  

Energy Technology Data Exchange (ETDEWEB)

Composite particles represented as TiV{sub 2.1}Ni{sub 0.3}-Raney Ni(R) were prepared by ball-milling a TiV{sub 2.1}Ni{sub 0.3} alloy with Raney Ni in the presence of 0.01 M sodium hypophosphite (NaH{sub 2}PO{sub 2}) aqueous solution as a reducing agent. The composite particles had different morphology from original TiV{sub 2.1}Ni{sub 0.3} alloy particles and TiV{sub 2.1}Ni{sub 0.3}-Raney Ni composite particles prepared by the ball-milling in the absence of the NaH{sub 2}PO{sub 2} aqueous solution. In charge-discharge cycle tests, the TiV{sub 2.1}Ni{sub 0.3}-Raney Ni(R) composite electrode showed the maximum discharge capacity of 620 mAh g{sup -1}, while its cycle durability was similar to the TiV{sub 2.1}Ni{sub 0.3} alloy electrode, which was explained from depth profiles of constituent elements by Auger electron spectroscopy (AES). In thermogravimetry (TG) and differential thermal analysis (DTA), two steps of dehydriding for hydrided TiV{sub 2.1}Ni{sub 0.3}-Raney ...

2004-02-25

58

Chemical and electrochemical dehydriding characteristics of TiV_2_._1Ni_0_._3-Raney Ni composite prepared by ball-milling in the presence of a reducing agent  

International Nuclear Information System (INIS)

Composite particles represented as TiV_2_._1Ni_0_._3-Raney Ni(R) were prepared by ball-milling a TiV_2_._1Ni_0_._3 alloy with Raney Ni in the presence of 0.01 M sodium hypophosphite (NaH_2PO_2) aqueous solution as a reducing agent. The composite particles had different morphology from original TiV_2_._1Ni_0_._3 alloy particles and TiV_2_._1Ni_0_._3-Raney Ni composite particles prepared by the ball-milling in the absence of the NaH_2PO_2 aqueous solution. In charge-discharge cycle tests, the TiV_2_._1Ni_0_._3-Raney Ni(R) composite electrode showed the maximum discharge capacity of 620 mAh g"-"1, while its cycle durability was similar to the TiV_2_._1Ni_0_._3 alloy electrode, which was explained from depth profiles of constituent elements by Auger electron spectroscopy (AES). In thermogravimetry (TG) and differential thermal analysis (DTA), two steps of dehydriding for hydrided TiV_2_._1Ni_0_._3-Raney Ni(R) composite started from much lower temperature than hydrided ...

2004-02-25

59

Catalytic effect of niobium oxide on hydrogen storage properties of mechanically ball milled MgH{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

We examined a catalytic effect of niobium oxide (Nb{sub 2}O{sub 5}) on the hydrogen storage properties of MgH{sub 2} prepared by mechanical ball milling method. The MgH{sub 2} composite doped with 1 mol% Nb{sub 2}O{sub 5} by ball milling for 20 h desorbed hydrogen up to {approx}6 mass% in the temperature range from 200 to 250 {sup o}C at the heating rate of 5 {sup o}C/min under a purified helium flow. After dehydrogenation at 200 {sup o}C, the product showed remarkable hydrogen absorption kinetics. A large amount of gaseous hydrogen up to {approx}4.5 mass% was absorbed even at room temperature under 1 MPa hydrogen pressure within 15 s and finally its capacity reached up to 5 mass%. Furthermore, the valence state of Nb{sub 2}O{sub 5} doped in MgH{sub 2} was examined by X-ray absorption near edge structure (XANES) measurement. The results indicated that additive Nb{sub 2}O{sub 5} was reduced by MgH{sub 2} during mechanical milling. This suggests ...

2006-08-15

60

Laser photoelectron spectroscopy of ions. Progress report, August 1, 1982-July 31, 1983  

Energy Technology Data Exchange (ETDEWEB)

We have undertaken a program which measures the photoelectron spectra of negative-ion beams. This experiment has afforded us direct information about these ions and the corresponding neutral radicals. Several ions and numerous radicals are believed to be crucial intermediates in combustion processes and flame chemistry. We have fabricated a spectrometer which directly measures electron affinities (EA). Knowledge of the EA and gas-phase acidity of a radical has enabled us to deduce several radical heats of formation and bond strengths.

1983-03-01

61

Determination of absorbed dose in a patient irradiated by beams of x or gamma rays in radiotherapy procedures  

CERN Document Server

Determination of absorbed dose in a patient irradiated by beams of x or gamma rays in radiotherapy procedures

1976-01-01

62

Tests for mutagencity of free radicals formed in irradiated sugars and amino acids  

International Nuclear Information System (INIS)

Radicals formed in gamma-irradiated crystals of galactose and glycine were found, upon dissolution, to cause mutagenesis of Salmonella typhimurium strains TA-98 and TA-100. Although the reproducibility of the results has not been adequately determined, they suggest the possibility of developing a test to measure the mutagenic-carcinogenic potential of radiation-induced free radicals with a microbial system.

1977-05-01

63

NAME=\\  

Wastenet

... Three prototype reactors were constructed and the photocatalysts used were TiO2 for hydroxyl radical generation, dyes such as methylene blue and rose bengal for singlet oxygen generation, and ferric chloride/hydrogen peroxide in Photo-Fenton OH radical generation. Singlet oxygen was effective against some of the pesticides but reacted slowly or not at all with others. All pesticides were degraded by OH radical generating agents (such as methylene blue)...

64

Market survey for nuclear power. Memorandum by the Director General  

International Nuclear Information System (INIS)

... Having established the required total capacity additions, the capacity available

1973-09-18

65

User involvement competence for radical innovation  

DEFF Research Database (Denmark)

One important market related capability for firms which seek to develop radical innovations is the competence to involve the 'right' users at the 'right' time in the 'right' form. While former studies have identified a rather passive role of users in the radical innovation process, this paper focuses on the involvement of such users that are in the position to play an active role as inventors and (co)-developers. A multiple case study analysis was conducted in the field of medical technology. Five radical innovation projects within four firms were selected including medical robots and computer-assisted navigation systems. The case study analysis reveals that firms who closely interact with specific users benefit significantly for their radical innovation work. These users have a high motivation toward new solutions, are open to new technologies, possess diverse competencies, and are embedded into a very ...

2007-01-01

66

Pulse radiolysis studies on [Fe(CN)_6]"4"- - BrO_3"- - CN"-system in ethylene glycol - water solutions  

International Nuclear Information System (INIS)

Formation of oxidizing and reducing radicals was studied by pulse radiolysis of [Fe(CN)_6]"4"- - BrO_3"- - CN"- system in ethylene glycol - water solvent mixture. Oxidizing #centre dot#BrO_2 and BrO radicals formed by electron scavenging with #centre dot#BrO_2"- were identified and their reactions were investigated. The reaction of hydroxyl radicals with ethylene glycol leads to formation of reactive radicals with reducing properties and of compounds which reduce slowly in dark the ferricyanide formed in the reaction of #centre dot#BrO_2 radical with ferrocyanide. (author) 21 refs.; 7 figs.

1991-01-01

67

Research and development activities on high efficiency separation process technologies for carbon dioxide removal from industrial sources at University of Regina, Canada  

Energy Technology Data Exchange (ETDEWEB)

This paper describes research and development activities at the University of Regina, Saskatchewan, Canada on Optimization of CO{sub 2} Extraction Process Technologies. The ultimate goal of this research is to develop better and more effective CO{sub 2} separation processes which can be used to recover CO{sub 2} from industrial sources such as coal-fired power plants and coal gasification complexes at the lowest possible capital and operating costs. The research program has been supported by Saskatchewan Power Corporation, Saskatchewan Energy and Mines, Prairie Coal Ltd., the Canada Centre for Mineral and Energy Technology (CANMET), Fluor Daniel Inc. (USA), Sulzer Chemtech (Switzerland), Wascana Energy Inc., and Natural Sciences and Engineering Research Council of Canada (NSERC). Currently, six parallel and complementary projects have been carried out at the Process Systems Laboratory. These projects are: (1) Searching for new sterically hindered amines for high ...

1996-05-01

68

Paper-based, printed zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

A flexible battery is printed on paper by screen-printing a zinc/carbon/polymer composite anode on one side of the sheet, polymerising a poly(3,4-ethylenedioxythiophene) (PEDOT) cathode on the other side of the sheet, and applying a lithium chloride electrolyte between the two electrodes. The PEDOT cathode is prepared by inkjet printing a pattern of iron(III)p-toluenesulfonate as a solution in butan-1-ol onto paper, followed by vapour phase polymerisation of the monomer. The electrolyte is prepared as a solution of lithium chloride and lithium hydroxide and also applied by inkjet printing on to paper, where it is absorbed into the sheet cross-section. Measurements on a zinc/carbon-PEDOT/air battery in a similar configuration on a polyethylene naphthalate substrate shows a discharge capacity of up to 1.4 mAh cm{sup -2} for an initial load of 2.5 mg zinc, equivalent to almost 70% of the zinc content of the anode, which generates 0.8 V at a ...

2009-12-01

69

Advanced Method for In-Field Measurement, Monitoring and Verification of Total Soil Carbon  

Science.gov (United States)

The Earth`s oceans, forests, agricultural lands and other natural areas absorb about half of the carbon dioxide emitted from anthropogenic sources. Terrestrial carbon sequestration strategies are immediately available to bridge the gap between current terrestrial sequestration capacity and high-capacity geologic sequestration projects available in 10 to 20 years. Terrestrial carbon sequestration strategies consist of implementing land management practices aimed at decreasing CO2 emitted into the atmosphere and developing advanced measurement tools to inventory and monitor carbon processes in soils and biota. In addition to atmospheric CO2 mitigation and carbon trading advantages, terrestrial carbon sequestration produces a variety of benefits which include reclamation of degraded lands, increased soil productivity, increased land value and a more secure food source. Carbon storage in soil depends on climate and ...

2005-12-01

76

Antimicrobials in the Management of Post-Irradiation Infection  

Science.gov (United States)

... develops. An alternative approach is the use of non-absorbable antibiot- ics such as polymyxin, neomycin, and bacitracin. ...

2011-05-13

79

Spectroscopic characterization of alkane radical cations: Pt. 1  

International Nuclear Information System (INIS)

Radical cations of various 3-methylalkanes (C_6-C_1_4) have been produced and stabilized by #gamma#-irradiation of the corresponding neutral compounds in saturated chlorofluorocarbon and perfluorocarbon matrices at 77 K. The perfluorocarbon matrices appeared more suitable for studies of the lighter radical cations, whereas the chlorofluorocarbon matrices were more suited for studies of the heavier radical cations; intermediary cations could be studied in both types of matrices. After irradiation, electronic absorptions associated with both the matrix and the alkane additive were observed. Pure spectra of the 3-methylalkane radical cations were obtained by difference spectrometry, after selective elimination of these cations by illumination. The electronic absorption spectra of the 3-methylalkane radical cations consist in all cases of a single broad absorption band. The spectral ...

1989-01-01

80

Ecological problems of natural gas cleansing  

International Nuclear Information System (INIS)

Full text: Chemical-technology approaches allowing to intensification the prevention processes of gas hydrates formation at motion of gas-liquid stream of natural gas in system natural gas well - gas wire have been worked up. Technological regimes of treatment of gas stream have been determined. Linear correlation dependences inhibitor electrolytes contained hydrated ions with different ion radii and charges of subgroups of alkali elements with one - type electron configuration were obtained. Important physico-chemical parameters of electrolytes have been determined: activity; coefficients of activity, viscosity, diffusion; density; heat capacity; heat conductivity; surface tension and freezing-point. The features of continuous influence of inhibitory factors on process of gas flow at low temperatures and relatively high pressure differences ?P have been studied by using of technological installation modulating the system natural gas well - gas wire. The ...

2007-06-01

81

Studies of initial stage in coal liquefaction. 4. Radical formation and structural change with thermal decomposition of coal; Ekika hanno no shoki katei ni kansuru kenkyu. 4. Netsubunkai ni tomonau radical seisei kyodo to kozo henka  

Energy Technology Data Exchange (ETDEWEB)

In relation to coal liquefaction reaction, the effect of the coexistence of transferable hydrogen (TH) from process solvent on reduction of radical concentration and the effect of pre-heat treatment on average structure of coals were studied. In experiment, change in radical concentration with temperature rise was measured using the system composed of Yallourn coal and process solvent. The results are as follows. Process solvent with a wide boiling point range of 180-420{degree}C is effective in suppressing an increase in radical concentration even at higher temperature. The effect of hydrogen-donating solvent increases with TH. It was also suggested that high-boiling point constituents in solvent stabilize radicals even over 400{degree}C by vapor phase hydrogenation. The experimental results of pre-heat treatment are as follows. Although the conversion improvement effect of TH is equivalent to that of ...

1996-10-28

82

Fragmentation and ion-molecule reaction of diethylmercury radical cations: an ESR study in irradiated frozen freon matrices and spin trapping in liquid phase  

International Nuclear Information System (INIS)

The mono- and intramolecular cation-radicals (CR) reactions of diethylmercury in the CFCl_3, CFCl_2CF_2Cl matrices and CF_2BrCF_2Br and CFCl_3 freons vitrified mixture (1:1) were studied through the EPR method. Formation of radical products of transformations of the initial CR diethylmercury (X-ray radiation dose - 100-200 Gy at the temperature of 293 K) was studied through the spin trap of 2.4.6 - tri-tret-butylnitrosebenzene.

83

ESR studies on reactivity of HO{sub 2} radicals in polycrystalline ice: non-monotonic changes of disproportionation rate in the temperature range 100-200 K  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of HO{sub 2} radicals in UV-irradiated frozen dilute solutions of H{sub 2}O{sub 2} were followed by the ESR technique. Radical disproportionations at the irradiation temperature were found to be adequately described in terms of dispersive kinetics by a second-order equal-concentration kinetic equation with rate parameters changing non-monotonically in the temperature range 100-200 K. These changes are thought to occur due to well separated structural relaxation regions of polycrystalline ice in the above temperature range. (author).

1994-11-01

84

The Development of 6061-Aluminum Windows for the MICE LiquidAbsorber  

Energy Technology Data Exchange (ETDEWEB)

The thin windows for the Muon Ionization Cooling Experiment (MICE) liquid Absorber will be fabricated from 6061-T6-aluminum. The absorber and vacuum vessel thin windows are 300-mm in diameter and are 180 mm thick at the center. The windows are designed for an internal burst pressure of 0.68 MPa (100 psig) when warm. The MICE experiment design calls for changeable windows on the absorber, so a bolted window design was adopted. Welded windows offer some potential advantages over bolted windows when they are on the absorber itself. This report describes the bolted window and its seal. This report also describes an alternate window that is welded directly to the absorber body. The welded window design presented permits the weld to be ground off and re-welded. This report presents a thermal FEA analysis of the window seal-weld, while the window is being welded. Finally, the results of a ...

2005-08-24

85

Similar Treatment Outcomes for Radical Cystectomy and Radical Radiotherapy in Invasive Bladder Cancer Treated at a United Kingdom Specialist Treatment Center  

British Library Electronic Table of Contents (United Kingdom)

PurposeTo conduct a retrospective analysis within a large university teaching hospital, comparing outcomes between patients receiving either radical surgery or radiotherapy as curative treatment for bladder cancer.Patients and MethodsBetween March 1996 and December 2000, 169 patients were treated radically for muscle-invasive bladder cancer. Data were collected from patient notes. Statistical analyses were performed using Kaplan-Meier methods and Cox proportional hazards regression analysis to compare radiotherapy and surgical outcome data.ResultsThere was no difference in overall, cause-specific, and distant recurrence-free survival at 5 years between the two groups, despite the radiotherapy group being older (median age, 75.3 years vs. 68.2 years). There were 31 local bladder recurrences...

2008-01-01

86

Robot-Assisted Laparoscopic Prostatectomy  

Medline Plus

ROBOT-ASSISTED RADICAL LAPAROSCOPIC PROSTATECTOMY WAKE FOREST UNIVERSITY BAPTIST MEDICAL CENTER WINSTON-SALEM, NC 00:00:08 ANTHONY ATALA, MD: I would like ...

87

Penile rehabilitation therapy with PDE-V inhibitors following radical prostatectomy: proceed with caution.  

Science.gov (United States)

Penile rehabilitation therapy following radical prostatectomy is a much debated topic. Erectile dysfunction is still a significant contributor to postoperative morbidity following radical prostatectomy, despite meticulous nerve-sparing technique. Secondary smooth muscle changes in the penis have been identified as the underlying causes of penile atrophy, veno-occlusive dysfunction, and fibrosis. Initial observations that intracavernous injection therapies used on a regular basis postoperatively resulted in improvements in the return of spontaneous erectile function led to the development of penile rehabilitation protocols. Chronic dosing of PDE-V inhibitors is now commonly used by urologists after radical prostatectomy. Despite the current enthusiasm of penile rehabilitation therapy, current scientific evidence with clinical trials is still limited. PMID:19255627

2009-01-25

88

Mitochondrial ROS production correlates with, but does not directly regulate lifespan in drosophila  

UK PubMed Central (United Kingdom)

The Mitochondrial Free Radical Theory of Aging (MFRTA) is currently one of the most widely accepted theories used to explain aging....Full Text Available

89

Intermediates of radiolytic transformations of 6-aminophenalenone in ethanol  

International Nuclear Information System (INIS)

Pulsed radiolysis method is used to study transformations intermediates of 6-aminophenalenone in ethanol. In alkaline medium the main product is radical-anion of 6-aminophenalenone, which optical absorption spectrum contains two bands with maxima at 355 and 400 nm. The particle precursors are e_s, CH_3CHOH and CH_3CHO"- radicals. In neutral and acid medium radical-anions are protonated in reactions with alcohol and hydrogen ions. The resulting H-adduct of 6-aminophenalenone has optical absorption maxima at 350 and 390 nm. Availability of two maxima is related to two various product structures. Molar extinction coefficients of radical-anions and H-adducts of 6-aminophenalenone and rate constants of reactions with their participation are estimated.

1992-01-01

90

Intermediate products of radiolytic conversions of 6-aminophenalenone in ethanol  

International Nuclear Information System (INIS)

Intermediate products of the conversions of 6-aminophenalenone in ethanol were investigated by pulse radiolysis. In alkaline medium the main product is the 6-aminophenalenone radical cation, the optical absorption spectrum of which contains two bands with maxima at 355 and 400 nm. The precursors of this particle are e_s, CH_3CHOH and CH_3CHO"- radicals. In neutral and acid medium, radical cations are protonated in reactions with alcohol and hydrogen ions. The H-adduct of 6-aminophenalenone that arises has optical absorption maxima at 350 and 390 nm. The presence of two maxima is due to two different structures of the product. The molar extinction coefficients of the radical anions and H-adducts of 6-aminophenalenone and the rate constants of the reactions involving them were estimated. 6 refs., 4 figs., 2 tabs.

1992-01-01

91

Infrared spectroscopy of rovibrational transitions of methyl radicals (CH3, CD3) in solid parahydrogen  

British Library Electronic Table of Contents (United Kingdom)

The n3 and n4 vibrational transitions of CH3 and CD3 isolated in solid parahydrogen were studied by high-resolution infrared spectroscopy. The radicals were produced by in situ UV photolysis of methyl iodides trapped in solid parahydrogen. The observed spectra showed clear rotational fine structures, which were subjected to further splitting due to the electrostatic field of solid parahydrogen. The molecular constants and crystal field parameters of the radicals in solid parahydrogen were determined by analyzing the spectral structures of the n3 and n4 transitions of CD3 by the crystal field theory. The rotational constants of the CD3 radical were found to be only a few percent smaller than those in the gas phase. The determined crystal field parameters indicated significant quantum effect...

2011-01-01

92

Comparison of antioxidant abilities of magnolol and honokiol to scavenge radicals and to protect DNA  

British Library Electronic Table of Contents (United Kingdom)

The antioxidant properties of magnolol and honokiol were evaluated in the experimental systems of reducing ONOO^- and ^1O"2, bleaching @b-carotene in linoleic acid (LH) emulsion, and trapping 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical (ABTS^+?) and 2,2'-diphenyl-1-picrylhydrazyl radical (DPPH), and then were applied to inhibit the oxidation of DNA induced by Cu^2^+/glutathione (GSH) and 2,2'-azobis(2-amidinopropane hydrochloride) (AAPH). Magnolol and honokiol were active to reduce ONOO^- and ^1O"2. Honokiol showed a little higher activity to protect LH and to inhibit Cu^2^+/GSH-induced oxidation of DNA than magnolol. In addition, honokiol exhibited higher activities to trap ABTS^+? and DPPH than magnolol. In particular, honokiol trapped 2.5 radicals while magnolol o...

2011-01-01

93

Advanced oxidation process based on ozone/electron beam irradiation for treating groundwater  

International Nuclear Information System (INIS)

There are several methods of generating OH free radicals from ozone and/or hydrogen peroxide and ultraviolet light. They all have in common that the OH free radicals originate in one single source only whereas in the combination of ozone with ionizing radiation two simultaneous working sources for the OH free radicals exist. The resulting higher OH free radical concentration makes this process especially apt for the remediation of low level contaminated groundwater as for example trichloroethylene (TCE) contamination in the sub-ppm range. A cost comparison between O_3/UV and O_3/electron beam for remediation of a groundwater contaminated with 100 ppb TCE indicated that for a throughput of about 5 million gallons/day the O_3/electron beam process is more cost-effective. (authors).

96

An analysis of a firm?s capacity in Mazda?s Keiretsu  

British Library Electronic Table of Contents (United Kingdom)

Capacity is defined as the power resulting from the specific position of a company in a network organization. This article extends the theory of network organizations to examine Mazda?s Yokokai Keiretsu, and proposes a new approach to calculating a firm?s capacity in a network. Capacity is divided into two categories, take-in capacity and take-out capacity, and the gap between them is called the capacity difference. We analyze the impact of capacity difference as a determinant of corporate performance in network organizations, thus providing a new perspective for successful corporate management.

2011-01-01

97

Annual Report  

Science.gov (United States)

... energy absorption characteristics of composite sandwich panels, thermoplastic energy-absorbing subfloor structures, and shoulder belt pre- tensioners. ...

98

Random motion of a particle emitting and absorbing tachyons  

International Nuclear Information System (INIS)

Random motion of a particle, emitting and absorbing tachyons, is investigated. It is shown that if bradyon is in equilibrium with neutral gas, i.e. it absorbs and emits tachyons, which do not have any charges, tha particle with each absorption-emittance of a tachyon changes its energy and momentum, never varying its own mass, and as a result it moves like a brownian particle. Thus, bradyon, interacting with tachyon gas, increases its momentum continuously in agreement with the Einstein-Fokker-Planck type equation.

99

Phase 2 report on the evaluation of polyacrylonitrile (PAN) as a binding polymer for absorbers used to treat liquid radioactive wastes  

Energy Technology Data Exchange (ETDEWEB)

The performance of PAN-based composite absorbers was evaluated in dynamic experiments at flow rates ranging from 25--100 bed volumes (BV) per hour. Composite absorbers with active components of ammonium molybdophosphate (AMP) PAN and K-Co ferrocyanide (KCoFC) PAN were used for separating Cs from a 1 M HNO{sub 3} + 1 M NaNO{sub 3} + 2 {times} 10{sup {minus}5} M CsCl acidic simulant solution. KCoFC-PAN and two other FC-based composite absorbers were tested for separating Cs from alkaline simulant solutions containing 0.01 M to 1 M NaOH and 1 M NaNO{sub 3} + x {times} 10{sup {minus}4} M CsCl. The efficiency of the Cs sorption on the AMP-PAN absorber from acidic simulant solutions was negatively influenced by the dissolution of the AMP active component. At flow rates of 50 BV/hr, the decontamination factor of about 10{sup 3} could be maintained for treatment of 380 BV of the feed. With the KCoFC-PAN ...

1996-05-01

100

Power control for wind turbines in weak grids: Project summary  

Energy Technology Data Exchange (ETDEWEB)

In many parts of the world and certainly in Europe large areas exist where the wind resources are good or very good and the grid is relatively weak due to a small population. In the areas the capacity of the grid can very often be a limiting factor for the exploitation of the wind resource. There are two main problems concerned with wind power and weak grids. The first is the steady state voltage level. The other main problem is voltage fluctuations. Some or all the these problems can be avoided if a so-called power control concept is applied together with the wind farm. The idea behind the power control concept is eliminate the violations of the steady state voltage level by buffering the power from the wind turbines in periods where the voltage limits might be violated and combine this ability with smoothing of the power output. The investigations have shown that the power control concept can compete with grid reinforcement and usually the dumping of wind energy ...

1999-03-01

101

Humidity impact on the thermal insulation in case of higher insulation levels; Feuchteeinfluesse auf den praktischen Waermeschutz bei erhoehtem Daemmniveau  

Energy Technology Data Exchange (ETDEWEB)

The article deals with the problem of a humidity addition to thermal conductivity, diffusion and latent heat effects in heat transfer through building components. It shows with examples humidity effects for exterior walls with core insulation, with composite insulation system as well as for insulated roof membrane assemblies. From these it can be summarized that - sorption humidity is for today`s construction conditions (good thermal insulation and humidity protection) a suitable reference quantity for the determination of practice-oriented, substance-specific and physically correct humidity additions to the thermal conductivity of hygroscopic components; - diffusion and latent heat effects are in case of good rain imperviousness and low water absorbing capacity of the exterior component layers of secondary importance for transmission heat losses; - an increase in insulating layer thickness in order to improve the thermal insulation is possible ...

1994-12-31

102

Fluxes of methane and nitrogen oxides in various boreal mire ecosystems. Effects of land-use activities and environmental changes  

Energy Technology Data Exchange (ETDEWEB)

Atmospheric impact of peatlands is a sum of their gas fluxes. In contrast to carbon dioxide, peatlands are net sources for methane (CH{sub 4}). Methane is an end product in the anaerobic decomposition processes and it has greater capacity to absorb infrared radiation than carbon dioxide. Most of the data on the CH{sub 4} release from northern peatlands is from North America. The total amount of methane released from wetlands is calculated to be 110 Tg yr{sup -1} of which 34 percent (38 Tg yr{sup -1}) is estimated to be emitted from the northern peatlands. Peat with high content of nitrogen is a potential source for gaseous nitrogen oxides, i.e. nitrous oxide (N{sub 2}O) and nitric oxide (NO). However, the importance of peatlands in producing these trace gases is poorly known. Nitrous oxide and nitric oxide are important components in the atmospheric chemistry and N{sub 2}O also is an effective greenhouse gas. Land-use activities and ...

1996-12-31

103

Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine  

Energy Technology Data Exchange (ETDEWEB)

Many commercial processes for the removal of carbon dioxide from high-pressure gases use aqueous potassium carbonate systems promoted by secondary amines. This paper presents thermodynamic and kinetic data for aqueous potassium carbonate promoted by piperazine. Research has been performed at typical absorber conditions for the removal of CO{sub 2} from flue gas. Piperazine, used as an additive in 20-30 wt% potassium carbonate, was investigated in a wetted-wall column using a concentration of 0.6 m at 40-80{sup o}C. The addition of 0.6 m piperazine to a 20 wt% potassium carbonate system decreases the CO{sub 2} equilibrium partial pressure by approximately 85% at intermediate CO{sub 2} loading. The distribution of piperazine species in the solution was determined by proton NMR. Using the speciation data and relevant equilibrium constants, a model was developed to predict system speciation and equilibrium. The addition of 0.6 m piperazine to 20 wt% potassium carbonate ...

2004-09-01

104

Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine  

Energy Technology Data Exchange (ETDEWEB)

This paper presents thermodynamic and kinetic data collected for aqueous blends of piperazine (PZ), an ethylamine, and potassium carbonate (K{sub 2}CO{sub 3}). Mixtures of K{sup +} and PZ have been investigated in a wetted-wall column at 40 to 80{sup o}C, typical conditions for an industrial absorber. The addition of 0.6 m PZ to 20 wt% (3.6 m) K{sub 2}CO{sub 3} increases the rate of CO{sub 2} absorption by a factor of ten from the value in unpromoted solutions at 60{sup o}C. The addition of PZ increases the heat of absorption from 4 kcal/mol in 3.6 m K{sup +} to 10 kcal/mol when 0.6 m PZ is added. The capacity, ranging from 0.4 to 0.7 mol-CO{sub 2}/kg-H{sub 2}O, approaches that of monoethanolamine (MEA) solutions and seems to be a strong function of K{sup +} concentration. Speciation of the solution was obtained using proton nuclear magnetic reasonance (NMR), verifying and quantifying the presence of three PZ species. An equilibrium model and a ...

2003-07-01

105

Reactivities of tetracycline and oxytetracycline with OH radicals  

Energy Technology Data Exchange (ETDEWEB)

Decomposition yields of tetracycline sulphate and oxytetracycline sulphate were determined in argon saturated 0.1N H/sub 2/SO/sub 4/ solutions. The decomposition yields of teracyclines decrease in the presence of the Cl/sup -/ ions. The reaction rate constants of the OH radicals with tetracyclines were also determined.

1982-05-03

106

Radiation-polymerizable mixture and recording material containing it  

International Nuclear Information System (INIS)

Esters of dihydric alcohols with alkenylphosphonic or alkenylphosphinic acids which are polymerizable by free radicals are described. They are combined with polymer binders, in particular water-soluble polymers, and photoinitiators forming free radicals to give photopolymerizable mixtures which are suitable for the production of photoresists and printing plates. The mixtures display low heat-sensitivity and have long shelf lives. (author) 1 tab.

1991-01-01

107

Radiation treatment of some poultry products  

International Nuclear Information System (INIS)

Practical procedures were developed for large-scale microbial decontamination of dry egg powder and gelatine with gamma radiation ("6"0Co). The formation and lifes of free organic radicals in these materials were examined by ESR measurements of powder samples. The concentration of these radicals was studied in dependence on the time of storage. Secondary oxidation of egg fats by air oxygen was investigated. Sensoric tests of irradiated gelatine, both in powder and hydrogel form, were performed. (author). 4 figs., 2 tabs., 2 refs.

1988-09-26

108

Pulsed plasma processing of effluent pollutants and toxic chemicals  

International Nuclear Information System (INIS)

The author is exploring the efficiency of pulsed plasma processing in the removal of nitrogen dioxide, nitrogen oxide, and other pollutants. This process uses an electrical discharge to create chemical radicals from air molecules. These radicals can react with pollutants and form harmless compounds. Additives such as hydrocarbons are also used to improve the efficiency of the removal. The efficient removal of nitrogen dioxide has required the presence of dilute aqueous solution of ammonia.

1994-05-01

109

Reactivity differences of hydroxyl radicals and hydrated electrons in destructing azo dyes  

International Nuclear Information System (INIS)

The high-energy radiation-induced degradation of an H-acid derivative azo dye, Apollofix-Red SF-28 (AR-28) was studied in aqueous solution by using pulse radiolysis with kinetic spectroscopic detection for transient measurements. Gamma radiolysis with UV-VIS spectroscopy and gradient ionpair HPLC separation with diode array detection were applied for following the destruction of AR-28 and measuring the products. The reactions of hydrated electron (e_a_q "-) and hydroxyl ("#centre dot#OH) radical were investigated separately. "#centre dot#OH reacts with the unsaturated bonds of the molecule. In the further reactions of the "#centre dot#OH adduct radicals, the AR-28 molecules partly reform with a slightly modified structure. The products formed in the first reaction of "#centre dot#OH and AR-28 molecules have also high reactivity towards the "#centre dot#OH radicals. For these reasons the efficiency of "#centre dot#OH ...

110

Radiation receiver. Strahlungsempfaenger  

Energy Technology Data Exchange (ETDEWEB)

The purpose of the invention is to improve a radiation receiver, consisting of a hollow body with an opening for the entry of radiation and a ceramic absorber situated in the hollow body, which absorbs the radiation energy entering through the opening, and emits it as thermal radiation to a heat medium, so that a higher efficiency can be achieved. According to the invention, the problem is solved by the fact that the absorber consists of ceramic material on the side towards the solar radiation, which has a low emission value and a high absorption value, and that the side of the absorber towards the heat medium has ceramic material of high emission value and low absorption value. This ensures that reradiation is prevented near the opening of the hollow body, and that the solar energy entering is largely absorbed in the hollow body.

1981-10-01

111

Optical effects of fine-particle carbon on urban atmospheres  

Energy Technology Data Exchange (ETDEWEB)

The effects of fine-particle C, such as diesel soot, on the optical properties of urban haze in the visible wavelength range were explored to determine the dominant effects and to see if simple parameters (such as visual range in green) provide an adequate measure of these effects. It is known that fine-particle C absorbs more strongly in the blue than in the red, so that when it is mixed with a white pigment, the resulting gray can appear somewhat brown. The possibility of a similar effect in urban hazes was investigated, but found not to occur. When the sun is overhead, the near-horizon sky chromaticities caused by mixtures of fine-particle C and non-absorbing aerosol can also be produced by non-absorbing aerosols alone. It is shown that absorbing aerosol will darken the horizon sky, and a simple equation for the radiance of the horizon sky is derived. The effect of absorbing ...

1986-01-01

112

Multiphase reacting flow modeling of singlet oxygen generators for chemical oxygen iodine lasers.  

Energy Technology Data Exchange (ETDEWEB)

Singlet oxygen generators are multiphase flow chemical reactors used to generate energetic oxygen to be used as a fuel for chemical oxygen iodine lasers. In this paper, a theoretical model of the generator is presented along with its solutions over ranges of parameter space and oxygen maximizing optimizations. The singlet oxygen generator (SOG) is a low-pressure, multiphase flow chemical reactor that is used to produce molecular oxygen in an electronically excited state, i.e. singlet delta oxygen. The primary product of the reactor, the energetic oxygen, is used in a stage immediately succeeding the SOG to dissociate and energize iodine. The gas mixture including the iodine is accelerated to a supersonic speed and lased. Thus the SOG is the fuel generator for the chemical oxygen iodine laser (COIL). The COIL has important application for both military purposes--it was developed by the US Air Force in the 1970s--and, as the infrared beam is readily absorbed by ...

2008-08-01

113

The interaction of alcohol radicals with human hemoglobin. Pt. 1. Spectral properties of hemoglobin in the visible range  

International Nuclear Information System (INIS)

Aqueous deoxyhemoglobin solutions (2 mg/ml) were gamma-irradiated by a "6"0Co source in the presence of methanol, ethanol, 1-butanol and t-butanol under N_2O or argon. The effects of the interaction of the particular alcohol radical species with hemoglobin were determined according to the detected spectral alterations in the visible range. The amounts of stable final products in the form of methemoglobin (MetHb) and the sum of hemichromes and cholehemichromes (Hemichr) were estimated in irradiated preparations. For preparations irradiated under N_2O, the radiation yield for MetHb formation was three-fold lower in the presence of ethanol and 1-butanol [G(MetHb) = 0.33[ compared with preparations irradiated in the presence of t-butanol or without alcohol [G(MetHb) = 1.00[. The yield of hemichromes and cholehemichromes in preparations irradiated under N_2O increased in the order: ethanol (G = 0.38), 1-butanol (B = 0.52), t-butanol (G = 0.59), and in the absence of ...

114

Implementation of an algorithm for absorbed dose calculation in high energy photon beams at off axis points  

International Nuclear Information System (INIS)

Full text: A semiempirical algorithm for absorbed dose calculation at off-axis points in irregular beams was implemented. It is well known that semiempirical methods are very useful because of their easy implementation and its helpfulness in dose calculation in the clinic. These methods can be used as independent tools for dosimetric calculation in many applications of quality assurance. However, the applicability of such methods has some limitations, even in homogeneous media, specially at off axis points, near beam fringes or outside the beam. Only methods derived from tissue-air-ratio (TAR) or scatter-maximum-ratio (SMR) have been devised for those situations, many years ago. Despite there have been improvements for these manual methods, like the Sc-Sp ones, no attempt has been made to extend their usage at off axis points. In this work, a semiempirical formalism was introduced, based on the works of Venselaar et al. (1999) and Sanz et al. (2004), aimed to the ...

2008-10-19

115

Radiation yield of oxygen-based radicals in hyperquenched glassy water gamma-irradiated at 77 K  

Energy Technology Data Exchange (ETDEWEB)

Hyperquenching of liquid water with cooling rates of 10{sup 6}-10{sup 7} K s{sup -1} yields glassy water. Upon {gamma}-irradiation at 77 K, the only paramagnetic species accumulating in hyperquenched glassy water are the hydroxyl and hydroperoxyl radicals. There are no hydrogen atoms or electrons seen by the ESR technique. For irradiation doses up to about 70 kGy, the relative contributions of hydroxyl and hydroperoxyl radicals to the total amount of paramagnetic species remain virtually constant. The total amount of paramagnetic species, n, is sublinear in dose, d, well approximated by n=8.55x10{sup 16}d{sup 0.8} for n in spin g{sup -1} and d in kGy.

1998-12-01

116

Low-temperature radiation polymerization of triethylene glycol. cap alpha. ,. omega. -dimethacrylate. [Gamma radiation  

Energy Technology Data Exchange (ETDEWEB)

Kinetics of postradiation polymerization of triethylene glycol ..cap alpha.., ..omega..-dimethacrylate has been studied by calorimetric method. The low-temperature radiolysis has been studied by ESR method. The radiation-chemical yield of radicals on ..gamma..-irradiation by /sup 60/Co is determined being equal to 6+-1 1/100 ev. Transformation of the radicals spectrum into the spectrum of propagating macroradicals proceeds at 140 K. After the transition from glassy to liquid state (Tsub(g)=193 K) the intensive postpolymerization begins. During the polymerization the disappearance of radicals is observed. For the low-temperature region the effective activation energy of polymerization is determined beina equal to 50.7+-0.8 kJ/mol.

1984-04-01

117

Identity and yield of positive charge centers in irradiated chloro hydrocarbon liquids and the rates of their interaction with solute molecules. [3-4 MeV electrons  

Science.gov (United States)

Pulse radiolysis studies of the formation kinetics and the yields of various phenylcarbenium ions from several different solutes in 1,2-dichloroethane solution have been carried out. The results indicate that there are two kinetically distinguishable cationic species of the solvent which react selectively with the different solutes to form the phenylcarbenium ions. It is suggested that one is a cation radical (yield 0.68 molecule/100 eV) and the other a carbocation (yield 0.20 molecule/100 eV). Rate constants for their separate reactions with selected aromatic compounds and with ammonia have been determined. Molar extinction coefficients have been estimated for benzyl cation, diphenyl cation radical, and anthracene cation radical. 6 figures, 1 table.

1979-07-26

118

Identity and yield of positive charge centers in irradiated chloro hydrocarbon liquids and the rates of their interaction with solute molecules  

International Nuclear Information System (INIS)

Pulse radiolysis studies of the formation kinetics and the yields of various phenylcarbenium ions from several different solutes in 1,2-dichloroethane solution have been carried out. The results indicate that there are two kinetically distinguishable cationic species of the solvent which react selectively with the different solutes to form the phenylcarbenium ions. It is suggested that one is a cation radical (yield 0.68 molecule/100 eV) and the other a carbocation (yield 0.20 molecule/100 eV). Rate constants for their separate reactions with selected aromatic compounds and with ammonia have been determined. Molar extinction coefficients have been estimated for benzyl cation, diphenyl cation radical, and anthracene cation radical. 6 figures, 1 table.

1979-07-01

119

Hydrogen-atom attack on methyl viologen in aqueous solution studied by pulse radiolysis  

International Nuclear Information System (INIS)

Using hydrogen at high pressures of up to 150 bar as an OH scavenger in aqueous MV"2"+ solutions (pH 1) it is possible to differentiate between two kinds of transient formed simultaneously by H-atom attack on methyl viologen. One of them is assigned to an H adduct on the N atom, MV"+H"+, with absorption bands identical to those of the radical cation, MV"+. The MV"+H"+ species deprotonates forming the long-lived radical cation, MV"+. The second type of transient produced is attributed to an H-adduct on the ring carbon, MV"2"+H, decaying by second-order kinetics. The formation of MV"+ by electron transfer from the propan-2-ol radical has been reinvestigated (pH 0 to 7); its absorption spectrum does not change in this pH range. Rate constants and molar extinction coefficients are presented. (U.K.).

1984-01-01

120

/sup 109/Ag NMR spectra of aqueous silver ions coordinated with nitroxide radical. Silver-TANOL complex and TANOL as a doping agent  

Energy Technology Data Exchange (ETDEWEB)

The effects of TANOL radical have been examined on chemical shifts and relaxation rates of /sup 109/Ag NMR in aqueous solution of silver salts. The silver ion in aqueous solution is found to coordinate with TANOL radical. A small amount of TANOL is added as a doping agent(0.020M), since /sup 109/Ag signals are obtained for (1.0M) silver ion within 30 minutes. The /sup 109/Ag chemical shifts of silver salt in aqueous solutions were found within the range of 0 to -1000 ppm relative to that of 1.0M AgNo/sub 3/.

1982-09-01

121

Radioactive iodine absorbing properties of tetrathiafulvalene  

Energy Technology Data Exchange (ETDEWEB)

For the purpose of searching some effective absorbents of gaseous radioactive iodine, 16 substances considered as having an affinity for iodine were investigated with regular iodine and /sup 125/I. In a preliminary survey, only tetrathiafulvalene (TTF) was found to have satisfactory absorbing properties comparable to activated charcoal. A further detailed comparison of the properties between TTF and activated charcoal led us to the conclusion that the former has more preferable properties as absorbent of radioactive iodine than the latter in all points studied. The results are summarized as follows: (1) The absorption of iodine on TTF in atmosphere was about twice as much as that on activated charcoal. Desorption of iodine from saturatedly absorbed iodine on TTF was practically negligible except trace amount of initial desorption, while that on activated charcoal was considerable (3%/50h) even in the ...

1989-05-01

122

Mesoporous Silicon-Based Anodes for High Capacity, High - NASA  

Science.gov (United States)

Aug 6, 2010 ... A new high capacity anode composite based on mesoporous silicon is proposed. By virtue of a structure that resembles a pseudo ...

123

Industrial-process control valves Part2 : Flow capacity Section Four : Inherent flow characteristics and rangeability  

CERN Document Server

Industrial-process control valves Part2 : Flow capacity Section Four : Inherent flow characteristics and rangeability

1989-01-01

124

Activation of stem cells in hepatic diseases  

UK PubMed Central (United Kingdom)

The liver has enormous regenerative capacity. Following acute liver injury, hepatocyte division regenerates the parenchyma but, if this capacity is overwhelmed during massive or chronic liver...Full Text Available

2008-01-01

125

Carbon dioxide absorption methanol process  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for removing carbon dioxide from a feed stream of natural gas having at least methane, ethane and heavier. It comprises: first, separating the feed stream in a first separator to form a first stream having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane and a second stream, having methane, carbon dioxide and ethane; separating the second stream in a second separator into a stream of carbon dioxide product and a third stream having ethane, methane and carbon dioxide: mixing at least a portion of the third stream with a polar compound; stream after the mixing in an absorber; separating the vapor and liquid of the third stream after the mixing in an absorber; absorbing the remaining unabsorbed carbon dioxide in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane with the ...

1989-08-29

126

Vitamin C and E Supplementation Effects in Professional Soccer Players Under Regular Training  

UK PubMed Central (United Kingdom)

Exercise training is known to induce an increase in free radical production potentially leading to enhanced muscle injury. Vitamins C and E are well known antioxidants that may prevent muscle cell damage....Full Text Available

127

Site-specific modification of albumin by free radicals. Reaction with copper(II) and ascorbate.  

UK PubMed Central (United Kingdom)

Exposure of albumin to Cu(II) (10-100 microM) and ascorbate (0.1-2 mM) results in extensive molecular modifications, indicated by decreased fluorescence and chain breaks. The rate of utilization of...Full Text Available

1986-06-01

128

Search for first-generation scalar leptoquarks in p anti-p collisions at s**(1/2) = 1.96-TeV  

Energy Technology Data Exchange (ETDEWEB)

The authors report on a search for pair production of first-generation scalar leptoquarks (LQ) in p{bar p} collisions at {radical}s = 1.96 TeV using an integrated luminosity of 252 pb{sup -1} collected at the Fermilab Tevatron collider by the D0 detector. They observe no evidence for LQ production in the topologies arising from LQ{ovr LQ} {yields} eqeq and LQ{ovr LQ} {yields} eqvq, and derive 95% C.L. lower limits on the LQ mass as a function of {beta}, where {beta} is the branching fraction for LQ {yields} eq. The limits are 241 and 218 GeV/c{sup 2} for {beta} = 1 and 0.5, respectively. These results are combined with those obtained by D0 at {radical}s = 1.8 TeV, which increases these LQ mass limits to 256 and 234 GeV/c{sup 2}.

2004-12-01

129

Response to a trial of physician-based inpatient order entry.  

UK PubMed Central (United Kingdom)

Our group has developed a physician-operated inpatient order-entry system (BICS-OE). Mindful of the problems inherent in bringing a radical cultural change such as this to the hospital, we conducted...Full Text Available

1993-01-01

130

Radical Resection After IORT-Containing Multimodality Treatment is the Most Important Determinant for Outcome in Patients Treated for Locally Recurrent Rectal Cancer  

UK PubMed Central (United Kingdom)

BackgroundThe optimal treatment for locally recurrent rectal cancer (LRRC) is still a matter of debate. This study assessed the outcome of LRRC patients treated with multimodality...Full Text Available

2008-07-01

131

Oxidative Stress and Longevity in Okinawa: An Investigation of Blood Lipid Peroxidation and Tocopherol in Okinawan Centenarians  

UK PubMed Central (United Kingdom)

Background. The Free Radical Theory of Aging mechanistically links oxidative stress to aging. Okinawa has among the world's longest-lived populations but oxidative stress in this...Full Text Available

2010-01-01

132

Obstructive Jaundice after Bilioenteric Anastomosis: Transhepatic and Direct Percutaneous Enteral Stent Insertion for Afferent Loop Occlusion  

UK PubMed Central (United Kingdom)

Recurrent tumour after radical pancreaticoduodenectomy may cause obstruction of the small bowel loop draining the liver. Roux-loop obstruction presents a particular therapeutic challenge, since the...Full Text Available

2010-09-01

133

Neural injury following stroke: are Toll-like receptors the link between the immune system and the CNS?  

UK PubMed Central (United Kingdom)

The CNS can exhibit features of inflammation in response to injury, infection or disease, whereby resident cells generate inflammatory mediators, including cytokines, prostaglandins, free radicals and...Full Text Available

2010-08-01

134

Intracellular Copper Does Not Catalyze the Formation of Oxidative DNA Damage in Escherichia coli?  

UK PubMed Central (United Kingdom)

Because copper catalyzes the conversion of H2O2 to hydroxyl radicals in vitro, it has been proposed that oxidative DNA damage may be an important component of copper toxicity....Full Text Available

2007-03-01

135

Glutamate 2,3-aminomutase: a new member of the radical SAM superfamily of enzymes  

UK PubMed Central (United Kingdom)

SUMMARYA gene eam in Clostridium difficile encodes a protein that is homologous to lysine 2,3-aminomutase (LAM) in many other species but does...Full Text Available

2007-02-01

136

Elucidation of hydrogen mobility in tetralin under coal liquefaction conditions using a tritium tracer method. Effects of the addition of H2S and H2O; Tritium tracer ho wo mochiita sekitan ekika hanno jokenka deno tetralin no suiso idosei hyoka. Ryuka suiso oyobi mizu no tenka koka  

Energy Technology Data Exchange (ETDEWEB)

It was previously reported that the tritium tracer method is useful for the quantitative consideration of hydrogen behavior in coal during coal liquefaction reaction. Tetralin is excellent hydrogen donating solvent, and is considered as one of the model compounds of coal. In this study, effects of H2S and H2O on the hydrogen exchange reaction between tetralin and gaseous hydrogen labeled by tritium were investigated. It was suggested that the conversion of tetralin and the hydrogen exchange reaction between gaseous hydrogen and tetralin proceed through the radical reaction mechanism with a tetralyl radical as an intermediate product. When H2S existed in this reaction, the hydrogen exchange yield increased drastically without changing the conversion yield. This suggested that the hydrogen exchange reaction proceeds even in the reaction where radical does not give any effect. In the case of H2O addition, the conversion yield ...

1996-10-28

137

EPR dosimetry in chemically treated fingernails  

UK PubMed Central (United Kingdom)

By using EPR measurements of radiation-induced radicals it is possible to utilize human fingernails to estimate radiation dose after-the-fact. One of the potentially limiting factors in this...Full Text Available

2007-08-01

138

Dissociation dynamics of methylal  

Energy Technology Data Exchange (ETDEWEB)

The dissociation of methylal is investigated using mass spectrometry, combined with a pyrolytic radical source and femtosecond pump probe experiments. Based on preliminary results two reaction paths of methylal dissociation are proposed and discussed. (author) 4 fig., 3 refs.

1999-08-01

139

Differing prognosis of cervical cancer patients with high risk of treatment failure after radical hysterectomy warrants trial treatment modification  

UK PubMed Central (United Kingdom)

ObjectiveThe aim of this study was to ascertain whether all cervical cancer patients who received adjuvant concurrent chemoradiation (CCRT) for high risk of treatment failure after...Full Text Available

2009-03-01

140

Detailed chemical kinetic reaction mechanism for oxidation of n-octane and iso-octane  

Energy Technology Data Exchange (ETDEWEB)

The development of detailed chemical kinetic reaction mechanisms for oxidation of n-octane and iso-octane is described, with emphasis on the factors which are specific to many large hydrocarbon fuel molecules. Elements which are of particular importance are found to include site-specific abstraction of H atoms, radical isomerization of alkyl radicals by internal H atom abstraction, and rapid ..beta..-scission of the alkyl radicals. These features, combined with distinctions in the types of intermediate olefin species produced, are used to explain the significant differences in the rate of oxidation between n-octane and iso-octane. Experimental results from the turbulent flow reactor and low pressure laminar flames, using both n-octane and iso-octane as fuels, are used to test the reaction mechanisms and indicate those parts of the total mechanisms which are in greatest need of further development and refinement. It is found ...

1986-04-15

141

Boundary conditions for the paleoenvironment: chemical and physical processes in the pre-solar nebula  

Energy Technology Data Exchange (ETDEWEB)

Two additional hyperfine components of the interstellar radical C3H were detected. In addition, methanol was discovered in interstellar clouds. The abundance of HCCN and various chemical isomers in molecular clouds was investigated.

1985-02-01

142

Blood Storage Duration and Biochemical Recurrence of Cancer After Radical Prostatectomy  

UK PubMed Central (United Kingdom)

OBJECTIVE: To test the hypothesis that perioperative transfusion of allogeneic and autologous red blood cells (RBCs) stored for a prolonged period speeds biochemical recurrence of prostate cancer...Full Text Available

2011-02-01

143

Antioxidant enzyme activities are not broadly correlated with longevity in 14 vertebrate endotherm species  

UK PubMed Central (United Kingdom)

The free radical theory of ageing posits that accrual of oxidative damage underlies the increased cellular, tissue and organ dysfunction and failure associated with advanced age. In support of this...Full Text Available

2010-06-01

144

Antimalarial activities and subacute toxicity of RC-12, a 4-amino-substituted pyrocatechol.  

UK PubMed Central (United Kingdom)

RC-12 [1,2-dimethoxy-4-(bis-diethylaminoethyl)-amino-5-bromobenzene] was evaluated for prophylactic, radical curative, and suppressive activities against infections with Plasmodium cynomolgi and subacute...Full Text Available

1985-11-01

145

Shock absorber for the leg structure of offshore jack-up rig  

Energy Technology Data Exchange (ETDEWEB)

A shock absorber mechanism and method for use on the leg structure of a jack-up offshore drilling rig is described. It is mounted on the bottom of each existing leg of a drilling rig and comprises a pointed piston member which is positioned on the bottom of the leg structure and projects downwards through the can/footing of the rig leg. The piston member is held in place by a resilient tension member which is designed to absorb shock forces during vertical/axial impact of the leg structure when contact is made with the ocean floor. (author).

1992-02-19

146

Application properties of AB{sub 2}-type hydrogen absorbing alloys  

Energy Technology Data Exchange (ETDEWEB)

Use of hydrogen absorbing alloys in various practical applications is always connected with the problem of production of starting alloys. The transition from laboratory samples to small-scale production involves the change of furnace and its operation mode and this has an effect on the preparation method of mixture of starting metal. Also, for some applications such as thermosorption compressors the exact values of thermodynamical parameters of reaction are needed. In the present work we present the results of investigation of series Laves phase hydrogen-absorbing alloys which can be promising in for use in different devices. 1 ref.

1998-07-01

147

THERMODYNAMICS AND KINETICS OF AQUEOUS PIPERAZINE WITH POTASSIUM CARBONATE FOR CARBON DIOXIDE ABSORPTION  

Energy Technology Data Exchange (ETDEWEB)

This work proposes an innovative blend of potassium carbonate (K{sub 2}CO{sub 3}) and piperazine (PZ) as a solvent for CO{sub 2} removal from combustion flue gas in an absorber/stripper. The equilibrium partial pressure and the rate of absorption of CO{sub 2} were measured in a wetted-wall column in 0.0 to 6.2 m K{sup +} and 0.6 to 3.6 m PZ at 25 to 110 C. The equilibrium speciation of the solution was determined by {sup 1}H NMR under similar conditions. A rigorous thermodynamic model, based on electrolyte non-random two-liquid (ENRTL) theory, was developed to represent equilibrium behavior. A rate model was developed to describe the absorption rate by integration of eddy diffusivity theory with complex kinetics. Both models were used to explain behavior in terms of equilibrium constants, activity coefficients, and rate constants. The addition of potassium to the amine increases the concentration of CO{sub 3}{sup 2-}/HCO{sub 3}{sup -} in solution. The buffer ...

2005-04-18

148

Pulse radiolysis of 2,4,5-trichlorophenol: Formation, kinetics, and properties of hydroxytrichlorocyclohexadienyl, trichlorophenoxyl, and dihydroxytrichlorocyclohexadienyl radicals  

International Nuclear Information System (INIS)

Pulse radiolysis has been used to optically and kinetically characterize the transient free radicals formed by the reaction of H"s"m"-"b"u"l"l"e"t, N_3"s"m"-"b"u"l"l"e"t, or OH"s"m"-"b"u"l"l"e"t with 2,4,5-trichlorophenol (TCP-OH). The hydroxy-2,4,5-trichlorocyclohexadienyl radical (H-TCP-OH) formed by H"s"m"-"b"u"l"l"e"t addition to TCP-OH [k = (1.1 #+-# 0.2) x 10"9 M"-"1 s"-"1] has an absorption maximum at 360 nm with #epsilon#_3_6_0 = (4700 #+-# 1000) M"-"1 cm"-"1. The 2,4,5-trichlorophenoxyl radical (TCP-O"s"m"-"b"u"l"l"e"t) formed by the reaction of N_3"s"m"-"b"u"l"l"e"t with TCP-O- [k = (4.3 #+-# 0.8) x 10"9 M"-"1 s"-"1] has an absorption maximum at 430 nm with #epsilon#_4_3_0 = (3600 #+-# 600) M"-"1 cm"-"1. The dihydroxy-2,4,5-trichlorocyclohexadienyl radical (HO-TCP-OH) formed by OH"s"m"-"b"u"l"l"e"t radical addition to TCP-OH [k = (1.2 #+-# 0.1) x 10"1"0 M"-"1 s"-"1] has an ...

149

One-electron oxidation of photosynthetic pigments in micelles. Bacteriochlorophyll a, chlorophyll a, chlorophyll b, and pheophytin a  

International Nuclear Information System (INIS)

Chlorophyll a, chlorophyll b, and bacteriochlorophyll a in aqueous micellar solutions of Trition X 100 (2%) are readily oxidized by pulse-radiolytically generated N_3., Br_2"-., and (SCN)_2"-. radicals at nearly diffusion-controlled rates. The kinetic study suggests that pigment molecules occupy multiple sites in the micelle. Pheophytin a is only oxidized by N_3. and Br_2"-. radicals. The absolute spectra and the molar extinction coefficients of chlorophyll a, bacteriochlorophyll a, chlorophyll b, and pheophytin a cations have been determined. The chlorophyll a cation has been observed in the presence of pigment aggregates.

1981-11-01

150

Megavoltage electron beam therapy in the treatment of basal and squamous cell carcinomata of the pinna  

Energy Technology Data Exchange (ETDEWEB)

Forty-three patients with basal and squamous cell carcinomata arising on the pinna were treated radically using a 10 MeV electron beam. The technique and dosage are described and discussed. Primary cancer control with retention of the pinna was achieved in 34 patients. Salvage pinnectomy was performed in four patients for recurrence and one patient for radiation necrosis. Two patients with large primary tumours failed to resolve and died of their disease. The advantages for the patient of the policy of primary radical electron beam therapy are discussed.

1982-05-01

151

MEASUREMENT OF HYDROPEROXIDES DURING THE TEXAS 2000 AIR QUALITY STUDY  

International Nuclear Information System (INIS)

Hydroperoxides are important atmospheric oxidants. They are responsible for most of the oxidation of aqueous-phase SO(sub 2) to sulfate in the northeastern United States, resulting in the formation of acid precipitation and visibility-reducing sulfate aerosol (Penkett et al., 1979; Lind et al., 1987; Madronich and Calvert, 1990; Tanner and Schorran, 1995). Atmospheric hydrogen peroxide (H(sub 2)O(sub 2) or HP) is produced by the self-reaction of hydroperoxyl radicals (HO(sub 2)); higher organic peroxides are produced by reaction of HO(sub 2) with alkylperoxyl radicals (RO(sub 2)). Peroxyl radicals, along with OH, are chain carriers in the complex photochemical process that produces tropospheric ozone. Thus, concentrations of peroxides and their free radical precursors depend on solar intensity and ambient concentrations of water vapor, ozone, NO(sub x) (NO+ NO(sub 2)), and VOCs (volatile organic ...

152

Determination of the b_s lifetime using hadronic decays  

Energy Technology Data Exchange (ETDEWEB)

The authors present a measurement of the B{sub s}{sup 0} meson lifetime using fully and partially reconstructed hadronic decays B{sub s}{sup 0} {yields} D{sub s}{sup -} {pi}{sup +}(X) followed by D{sub s}{sup -} {yields} {phi}{pi}{sup -}. The data sample was recorded with the CDF II detector at the Fermilab Tevatron and corresponds to an integrated luminosity of 1.3 fb{sup -1} from p{bar p} collisions at {radical}s = 1.96 TeV.

2008-07-01

153

Target stations and beam dumps for the CERN SPS  

International Nuclear Information System (INIS)

The design of the absorber blocks for internal and external dumping of the SPS proton beam is discussed. In addition, the external target stations for slow and fast extracted proton beams are described.

1977-03-16

154

Root Cause Analysis, Tank Fire Problem, M1A1 Main Battle ...  

Science.gov (United States)

... ammunition is stored. Combustible cartridge cases could absorb moisture, swell, and not chamber properly. Additionally, moisture ...

1989-02-01

155

Power efficiency for very high temperature solar thermal cavity receivers  

Science.gov (United States)

This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this ...

1984-01-01

156

Power efficiency for very high temperature solar thermal cavity receivers  

Energy Technology Data Exchange (ETDEWEB)

This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this ...

1984-10-30

157

Neutron physical investigations on the shutdown effect of small boronated absorbing spheres for pebble-bed high-temperature gas-cooled reactors  

Energy Technology Data Exchange (ETDEWEB)

An emergency shutdown system for high-temperature gas-cooled pebble-bed reactors is proposed in addition to the common absorber rod shutdown system. This system is based on the strongly absorbing effect of small boronated graphite spheres (called KLAK), which trickle in case of emergency by gravity from the top reflector into the reactor core. The inner reflector of the Siemens-Argonaut reactor was substituted by an assembly of spherical Arbeitsgemeinschaft Versuchsreaktor fuel elements, and the shutdown effect was examined by installing well-defined KLAK nests inside this assembly. The purpose was to develop and prove a calculational procedure for determining criticality values for assemblies of large fuel spheres and small absorbing spheres.

1987-09-01

158
159

Improved power efficiency for very-high-temperature solar-thermal-cavity receivers  

Energy Technology Data Exchange (ETDEWEB)

This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positiond in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts radiation from the front of the absorber. With this arrangement, a ...

1982-04-14

160

Experimental study on simultaneous desulfurization and denitrification from flue gas with composite absorbent  

British Library Electronic Table of Contents (United Kingdom)

Abstract The characteristics of desulfurization and denitrification with composite absorbent were researched through aqueous absorption experiments. The removal efficiencies of SO2 and NO were up to 100 and 95%, respectively. The composite absorbent included NaClO2 and component M. Existence of component M in the solution could reduce the absorbent cost compared with using sodium chlorite alone. Chlorine dioxide, as main reaction intermediate product, participated in oxidation reaction. The optimal experimental conditions involved NaClO2 concentration of1.13 mmol/L, solution pH of 5.5, molar ratio (M/NaClO2) of 4.1, reaction temperature of 323 K. The optimal solution pH and reaction temperature were both in the required ranges of limestone-gypsum wet flue gas desulfurization (FGD) process....

2011-01-01

161

Energy absorbers used against impact loading  

International Nuclear Information System (INIS)

In the WWER-440 reactor the primary piping consists of six horizontal loops going radially from the pressure vessel, each loop having a horizontal steam generator. In this reactor type the relatively long primary piping with many curved sections requires special attention in order to successfully eliminate the consequences of the design basis accident. Emergency supports are located in appropriate places to restrict the movements of the pipe. Under normal conditions there is a gap of some centimeters between the pipe and a support so that in the pipe can be deformed freely under changing loads. This paper deals with those energy-absorbing structures used at the Loviisa Nuclear Power Plant for protection against impact loading. Places and circumstances where energy-absorbing structures are employed are specified. Development and design of impact absorber elements are discussed and impact tests are described. (Auth.).

1975-09-08

162

Absorbed dose and dose reduction in mammography  

International Nuclear Information System (INIS)

First, absorbed dose at entrance surface was measured in routine mammography. Secondly, a possibility of dose reduction after introduction of Fuji computed radiography (FCR) system was examined. In a total of 350 mammographic studies including craniocaudal and medilateral projections, average thickness of compressed breast was less than 4 cm and most frequently recorded absorbed dose was 0.2-0.3 cGy (200-300 mrad). Minimum dose to obtain clinically acceptable mammograms in FCR system was estimated by comparing image quality of routine versus reduced dose studies. It was concluded that absorbed dose could be reduced to 1/4 of routine dose without creating significant drawback in diagnosis. (author).

1986-01-01

164

Similar Treatment Outcomes for Radical Cystectomy and Radical Radiotherapy in Invasive Bladder Cancer Treated at a United Kingdom Specialist Treatment Center  

International Nuclear Information System (INIS)

Purpose: To conduct a retrospective analysis within a large university teaching hospital, comparing outcomes between patients receiving either radical surgery or radiotherapy as curative treatment for bladder cancer. Patients and Methods: Between March 1996 and December 2000, 169 patients were treated radically for muscle-invasive bladder cancer. Data were collected from patient notes. Statistical analyses were performed using Kaplan-Meier methods and Cox proportional hazards regression analysis to compare radiotherapy and surgical outcome data. Results: There was no difference in overall, cause-specific, and distant recurrence-free survival at 5 years between the two groups, despite the radiotherapy group being older (median age, 75.3 years vs. 68.2 years). There were 31 local bladder recurrences in the radiotherapy group (24 solitary), but there was no significant difference in distant recurrence-free survival. In a more recent (2002-2006) ...

2008-02-01

166

Oxygen-induced enhancement of the adsorptive capacity of activated charcoal  

Energy Technology Data Exchange (ETDEWEB)

Adsorption isotherms for phenol and o-cresol on activated charcoal at neutral pH and several dissolved oxygen concentrations were conducted at 23{degree}C. Significant improvements in capacities were observed with increasing dissolved oxygen concentrations for the two adsorbates. These statistically-significant additional capacities were not due to biological activities but merely due to surface chemical reactions. The improvement in capacity was directly related to the amount of oxygen per unit mass of GAC.

1992-02-01

168

Heat capacities and densities of electrolyte mixtures in aqueous solution - application to the determination of apparent molar heat capacities and volumes for potassium triiodide and dioxoneptunium(V) perchlorate  

Energy Technology Data Exchange (ETDEWEB)

Apparent molar heat capacities for KI[sub 3](aq) were determined from flow-microcalorimetric measurements of KI(aq) solutions containing dissolved iodine. From these, the conventional partial molar heat capacity C[sub p,2][sup [infinity

1993-05-01

173

Combustion of Crop Production Wastes  

International Science & Technology Center (ISTC)

Development, Investigation and Improvement of a System of Incinerating Crop Production Wastes in Small Capacity Boilers

175

The effect of ductile connectors on the behaviour of timber-concrete composite beams  

British Library Electronic Table of Contents (United Kingdom)

The load-carrying capacity and ultimate deformation capacity of timber-concrete composite systems can be significantly influenced by the ductility of the connection between the two materials. The use of more ductile connections can increase the load-carrying capacity of the composite system as well as its ultimate deformation capacity. In this work, the potential increase that might be expected for these two parameters due to the use of ductile connections will be assessed through numerical simulations, taking the non-linear behaviour of the connections into account. Furthermore, the connection ductility required to achieve the maximum load capacity depends on the mechanical properties of the connection as well as on the geometric and mechanical properties of the composite system. There ar...

2011-01-01

176

Procedure for determining the criteria for rupture capacity in exposed sedimentary rocks in coal sections  

Energy Technology Data Exchange (ETDEWEB)

The control of piece size in ruptured rocks in coal sections is important as part of the general problem of increasing efficiency in the technology of open-pit mining operations. An attempt is made in this paper to estimate the rupture capacity of exposed rocks in coal sections based on a set of physicomechanical property indicators, using the methods of multidimensional statistical analysis. It was established that all the parameters for the physiocomechanical properties of the exposed rocks are highly correlated. The method proposed for determining criteria for explosive capacity is of interest in developing criteria for the destruction capacity (drillability, excavation capacity, etc.) in the exposed rocks of coal sections which are characterized by high variation in physical and mechanical properties.

1988-03-01

177

Thermal performance of solar air collectors with a passive heat transfer augmentation technique  

Energy Technology Data Exchange (ETDEWEB)

One of the main disadvantages of solar air collectors in practical applications is their relatively low efficiency. In this experimental investigation, the shape and arrangement of absorber surfaces of the collectors were reorganized to provide better heat transfer surfaces suitable for the passive heat transfer augmentation techniques. The performance of such solar air collectors with staggered absorber sheets was tested. The experimental results show that it is possible to provide 10 to 25% enhancement in the efficiency compared to the conventional solar air collectors. (authors)

2000-07-01

178

The trick with the heat pump; Der Trick mit der Waermepumpe  

Energy Technology Data Exchange (ETDEWEB)

The brochure reports on the construction and method of operation of heat pumps: - Efficiency and temperature difference - output figure - circuit processes - saving of primary energy - monovalent and bivalent plants - absorber, earth collectors - heat recovery. (HW) [Deutsch] Die Broschuere berichtet ueber den Aufbau und die Wirkungsweise von Waermepumpen: - Wirkungsgrad und Temperaturdifferenz - Leistungszahl - Kreisprozesse - Einsparung von Primaerenergie - monovalente und bivalente Anlagen - Absorber, Erdkollektoren - Waermerueckgewinnung. (HW)

1997-12-31

179

Investigation of carbon dioxide absorption by absorbents impregnated with alkanol amines  

Energy Technology Data Exchange (ETDEWEB)

In studying the absorption of carbon dioxide by absorbents impregnated with alkanol amines, researchers used a laboratory-scale packed column to determine the overall gas-phase mass-transfer coefficients and enhancement factors. A model derived for the mechanism of the chemical reaction taking place in the interfacial layer accounts for the effect of the reaction upon the absorption rate better than other models.

1981-01-01

180

Heat exchange in a multi-cavity volumetric solar receiver  

Energy Technology Data Exchange (ETDEWEB)

The concept of a multi-cavity volumetric solar receiver is very attractive for the profitability of certain of its characteristics such as high efficiency and economy. The absorber is based on a pack of small ceramic cavities which intercept and absorb the inherent high solar flux reflected from an array of mirrors. Atmospheric air acts as a coolant medium when it is drawn through the pack. A model for an overall heat transfer performance of the receiver is given and numerically solved.

1991-01-01

181

Body dose conversion factors for computerized tomography  

International Nuclear Information System (INIS)

While there have been many experimental and calculational investigations on absorbed dose distribution in the patient resulting from conventional X-ray procedures, such data for computerized tomography (CT) are still sparse. As this diagnostic procedure has shown a rapid increase in application during recent years, we have determined absorbed dose to body organs in a human phantom resulting from CT examinations. The exposure model consists of the heterogeneous MIRD-5 phantom and a suitable Monte-Carlo method to calculate absorbed dose to organs of interest. The exposure conditions are specified according to the exposure specifications of a CT-scanner currently in use. The calculations cover the range of body tissues of interest in terms of organ absorbed doses as well as a risk weighted absorbed dose. A detailed example showing the calculation of red bone marrow dose is given and a ...

1980-10-31

182

A water calorimeter for high energy x-rays and electrons  

CERN Document Server

The current primary standards at NPL for the measurement of absorbed dose to water in high energy photon and electron beams are graphite calorimeters. However, the quantity of interest in radiation dosimetry is absorbed dose to water. Therefore, a new absorbed dose to water standard based on water calorimetry has been developed for use in high energy photon and electron beams. The calorimeter operates at 4 deg C, with temperature control being provided by liquid cooling. The sealed glass inner vessel of the calorimeter was designed to minimise the effect of non-water materials on the measurement of absorbed dose. The temperature sensing thermistor probes were designed and constructed so that glass is the only material in contact with high purity water inside the vessel. Initial measurements of absorbed dose to water made in 6, 10, and 19 MV photons, and 16 MeV electrons agreed, ...

2000-01-01

183

Detailed Chemical Kinetic Reaction Mechanisms for Autoignition of Isomers of Heptane Under Rapid Compression  

Energy Technology Data Exchange (ETDEWEB)

Detailed chemical kinetic reaction mechanisms are developed for combustion of all nine isomers of heptane (C{sub 7}H{sub 16}), and these mechanisms are tested by simulating autoignition of each isomer under rapid compression machine conditions. The reaction mechanisms focus on the manner in which the molecular structure of each isomer determines the rates and product distributions of possible classes of reactions. The reaction pathways emphasize the importance of alkylperoxy radical isomerizations and addition reactions of molecular oxygen to alkyl and hydroperoxyalkyl radicals. A new reaction group has been added to past models, in which hydroperoxyalkyl radicals that originated with abstraction of an H atom from a tertiary site in the parent heptane molecule are assigned new reaction sequences involving additional internal H atom abstractions not previously allowed. This process accelerates autoignition in fuels with ...

2001-12-17

184

Removal of SO sub x in flue gas by polyacrylonitrile based active carbon fiber (PAN-ACF). Polyacrylonitrile no kassei tanso sen prime ikei (PAN-ACF) no haien datsuryuno  

Energy Technology Data Exchange (ETDEWEB)

Flue gas desulfurizing capacities of active carbon fibers (ACF) made from polyacrylonitrile (PAN-ACF) were studied, the features were clarified and at the same time the factors governing the capacities were studied to get guides for better products. Desulfurization capacities of 17 kinds of ACFs were studied. Two kinds of PAN-ACF, FE-200 and FE-300, especially the latter exhibited the higher desulfurization capacity. The capacity of FE-300 was about 20 times higher than those of fibers other than PAN systems and about 4 times higher than that of active coke for desulfurization. From the influence of reacting conditions on the desulfurizating capacity and the desorption profiles of adsorbed SO {sub 2}, it was concluded that the capacity was determined by the effective adsorption capacity of ACF and SO {sub 2} was retained ...

1991-04-10

185

Cellular dosimetry: Absorbed fractions for monoenergetic electron and alpha particle sources and S-values for radionuclides uniformly distributed in different cell compartments  

Energy Technology Data Exchange (ETDEWEB)

The importance of cellular dosimetry in both diagnostic and therapeutic nuclear medicine is becoming increasingly recognized. Experimental range-energy relations for electrons and alpha particles, along with derived geometric reduction factors, are used to calculate cellular absorbed fractions for these radiations. The resulting absorbed fractions are employed to calculate cellular S-values for several radionuclides. Cellular absorbed fractions for monoenergetic electron sources with energies ranging from 0.1 keV to 1 MeV, distributed uniformly in the source region, are calculated for several target {l_arrow} source combinations including cell{l_arrow}cell, cell{l_arrow}cell surface, nucleus{l_arrow}nucleus, nucleus {l_arrow}cytoplasm and nucleus {l_arrow}cell surface. Similar data are also provided for monoenergetic alpha particle sources with energies ranging from 3 to 10 MeV. S-values are also conveniently tabulated for ...

1994-02-01

186

Time-resolved Fourier transform emission spectroscopy of A2P-X2+ infrared transition of the CN radical  

British Library Electronic Table of Contents (United Kingdom)

The A2P-X2+Dv=-3 bands of the 12C14N radical have been observed by time-resolved Fourier transform spectroscopy in the 1850-3100cm-1 region with a wavenumber resolution of 0.025cm-1. The radical was produced in a pulsed positive column discharge in a cyanogene and helium mixture. Seven bands of v=0-3, 1-4, 2-5, 3-6, 4-7, 5-8, and 6-9 were analyzed to give the molecular constants of each state by least-squares fitting of 801 lines. The pulsed discharge was found to be efficient for production of CN in the excited A2P state. The vibrational excitation temperature was determined to be 6680+-835K and 6757+-534K for the A2P and X2+ states, respectively. The population of the A2P was found to be 4% of that of the X2+ state in the time after turning off the discharge.

2008-01-01

187

Rubidium uptake by mouse pancreatic islets exposed to 6-hydroxydopamine, ninhydrin, or other generators of hydroxyl radicals  

International Nuclear Information System (INIS)

The purpose was to study the toxicity of drugs known to generate free radicals on isolated pancreatic islets. The accumulattion of "8"6Rb"+ by mouse pancreatic islets was measured in vitro. Exposing the islets to 6-hydroxydopamine, minhydrin, or phenazine methosulphate + NADH inhibited the Rb"+ uptake, whereas paraquat or acetylphenylhydrazine had no effect. This effect of 6-hydroxydopamine was prevented by either of the hydroxyl radical scavengers, sodium benzoate and mannitol, but not by the non-scavenger,urea; ninhydrin was partially protected against by mannitol but not by benzoate. Protection against 6-hydroxydopamine was also afforded by D-glucose but not by L-glucose or 3-O-methyl-D-glucose; none of the sugars protected against ninhydrin. In damaging islet beta-cells and in being protected against by D-glucose, 6-hydroxydopamine closely resembles the diabetogenic drug, alloxan. It is suggested that protection against alloxan may involve ...

188

Novel InN growth method under In-rich condition on GaN/Al2O3(0001) templates  

International Nuclear Information System (INIS)

A novel technique is proposed for the growth of an InN film on a GaN/Al2O3(0001) template by radio-frequency plasma-excited molecular beam epitaxy (RF-MBE). The method involves 1) InN growth under an In-rich condition and 2) additional nitrogen radical irradiation after the InN growth under an In-rich condition. Excess In that appeared on the InN surface in the InN growth under an In-rich condition is transformed to InN by the additional nitrogen radical irradiation. The effective V/III ratio is easily controlled by monitoring the intensity in a reflection high-energy electron diffraction (RHEED) pattern. The growth of the InN film by repeating the InN growth under an In-rich condition and the additional nitrogen radical irradiation is also demonstrated. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2009-06-01

189

Mechanisms of radical removal by SO2  

DEFF Research Database (Denmark)

It is well established from experiments in premixed, laminar flames, jet-stirred reactors, flow reactors, and batch reactors that SO2 acts to catalyze hydrogen atom removal at stoichiometric and reducing conditions. However, the commonly accepted mechanism for radical removal, SO2 + H(+M) reversible arrow HOSO(+M), HOSO + H/OH reversible arrow SO2 + H-2/H2O, has been challenged by recent theoretical and experimental results. Based on ab initio calculations for key reactions, we update the kinetic model for this chemistry and re-examine the mechanism of fuel/SO2 interactions. We find that the interaction of SO, with the radical pool is more complex than previously assumed, involving HOSO and SO, as well as, at high temperatures also HSO, SH, and S. The revised mechanism with a high rate constant for H + SO2 recombination and with SO + H2O, rather than SO2 + H-2, as major products of the HOSO + H reaction is in agreement with a range of ...

2007-01-01

190

Lysozyme dimer formation on lysozyme oxidation with B./2 as studied by fluorescence evolution  

International Nuclear Information System (INIS)

Lysozyme dimers produced on oxidation of lysozyme with Br_2anion radicals in aqueous solutions exhibit a fluorescence spectrum (lambdasub(max) = 400 nm) closely similar to that of bi-tyrosine. This suggests that the dimer is likely to have a tyrosine-tyrosine bond resulting from the combination of tyrosine phenoxy radicals of two lysozyme molecules. Kinetic studies on dimer formation were made by measuring time-dependent fluorescence after pulsed-electron irradiation over wide pH range. The results lead to the following conclusions. The second-order growth of the dimer fluorescence observed at pH 10.7-12.5 reflects the combination process of the lysozyme radicals, which is rate-determining in the pH range. On the other hand, the first-order growth observed at pH 6.8-10.2 is attributable to the enolization of the keto-form of the dimer. A tentative reaction scheme is proposed for the dimer formation. (author).

191

Local control and survival of Ewing's sarcoma in children with radiotherapy and chemotherapy without radical surgery  

International Nuclear Information System (INIS)

The present study was undertaken in 27 children with localized Ewing's sarcoma treated at our hospital. In 9 cases the lesion was central and in 18 peripheral. Treatment consisted of: 1) Chemotherapy with 6 drugs (vincristine, cyclophosphamide, methotrexate, bleomycin, dactinomycin and doxorubicin) for one year in all patients; 2) Radiotherapy in 24 patients at a dose of 30-40 Gy in the entire bone with a booster dose of 10-15 Gy in the lesion. In 7 patients debulking surgery was performed followed by irradiation. Two cases with tumor in expendable bones and one with extensive destructive lesion in the tibia underwent radical surgery. One patient suffered local recurrence (femur) and 6 developed distant metastases. The remaining 20 (74%) patients were alive and tumor-free after follow-up periods of 17-80 months. Among the 12 patients with extremity lesions who were alive, 7 (58%) had minimal or mild treatment sequelae, 2 moderate, and 3 severe sequelae but no ...

192

Hydroxyl radical formation by UV-irradiated epidermal cells  

International Nuclear Information System (INIS)

To elucidate the mechanism of sunlight-induced skin damage, guinea pigs exposed to UV light (280-320 nm, UV B, 4J/cm"2) and a homogenate of the epidermis was examined by means of the thiobarbituric acid (TBA) test. Three hours after the exposure, TBA-malondialdehyde adducts had increased while glutathione reductase activity had decreased, indicating lipid peroxidation. To detect the initial species, spin trapping with 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) was applied to a suspension of illuminated epidermal cells (0.5 J/cm"2). An ESR signal obtained only with irradiation comprised a 1 : 2 : 2 : 1 quartet [a (N) =a (#beta#H) =1.49 mT] attributable to a spin adduct of hydroxyl radicals. These results suggest that sunlight exposure of skin may lead to hydroxyl radical generation and simultaneous lipid peroxidation. (author).

193

DNA alterations photosensitized by tetracycline and some of its derivatives  

Energy Technology Data Exchange (ETDEWEB)

Bacteriophage M13 mp10 DNA were irradiated with near-UV light in the presence of tetracycline derivatives and primed with synthetic oligonucleotide to be used for DNA synthesis using Escherichia coli DNA polymerase. Chain terminations were observed by denaturing polyacrylamide gel electrophoresis and mapped precisely. All the synthesis stops occurred before or at the level of guanine residues, showing that the photoreaction mediated by tetracycline derivatives led to a preferential alteration of guanine residues. These lesions were demonstrated to be induced in DNA through a pathway involving singlet oxygen. Tetracycline derivatives also photoinduced the breakage of the DNA sugar-phosphate backbone monitored by the conversion of supercoiled phi X174 DNA to a relaxed form. This lesion was shown to be initiated by hydroxyl radicals. The production of this free radical has been confirmed by electron paramagnetic resonance (EPR) spin trapping ...

1986-06-01

194

Comparison of methods to measure the rate of neutral free radical production by photo-deionization of negative ion beams  

Energy Technology Data Exchange (ETDEWEB)

Two measurement methods to determine the rate of neutral free radical production by the photo-deionization of negative ion beams (PDINIB) are introduced. These methods, namely, photoelectron-current measurement by low-frequency electro-modulation probe (PMMP) and measurement of decrease in the negative-ion beam current (DNIC) were employed to evaluate the production rate in a trial surface-processing apparatus developed in the author's laboratory utilizing a steady-flux refined beam of neutral free radicals (RBNR) produced by the PDINIB procedure. A {sup 63}Cu{sup -} negative ion beam of kinetic energy E{sub i} varied up to 15 keV was irradiated with a 514.5 nm visible light beam from a 25 W CW Ar{sup +} ion laser. The detection limit of the production rate by the PMMP setup was as high as 6 x 10{sup 9} s{sup -1} under the condition that E{sub i}=15 keV, the negative-ion beam current I{sub i}=4 {mu}A and the laser power P=6 W. The DNIC ...

2003-05-01

195

#gamma##gamma# Cross-sections and #gamma##gamma# colliders  

International Nuclear Information System (INIS)

We summarize the predictions of different models for total #gamma##gamma# cross-sections. The experimentally observed rise of #sigma#_#gamma#_#gamma# with s radical _#gamma#_#gamma#, faster than that for #sigma#_p_-_b_a_r_p, #sigma#_#gamma#_p is in agreement with the predictions of the Eikonalized Minijet Models as opposed to those of the Regge-Pomeron models. We then show that a measurement of #sigma#_#gamma#_#gamma# with an accuracy of < or approx. 8-9% (6-7%) is necessary to distinguish among different Regge-Pomeron type models (the different parameterisations of the EMM models) and a precision of < or approx. 20% is required to distinguish the predictions of the EMMs and of those models which treat 'photon like a proton', for the energy range 300< s radical_#gamma#_#gamma# <500 GeV. We further show that the difference in model predictions for #sigma#_#gamma#_#gamma# of about a factor 2 at s radical ...

2001-10-11

196

Deuterium isotope effect on molar heat capacities and apparent molar heat capacities in dilute aqueous solutions: A multi-channel heat-flow microcalorimeter study  

International Nuclear Information System (INIS)

The molar heat capacities of chloroform, dichloromethane, methanol, acetonitrile, acetone, dimethyl sulfoxide, benzene, dimethylformamide, toluene, and cyclohexane, as well as their deuterated isotopologues, were measured using a multi-channel heat conduction TAM (Thermal Activity Monitor) III microcalorimeter. In addition, the apparent molar heat capacities of some of the associated dilute aqueous solutions (0.0039 i < 0.0210) were also measured. A temperature drop method from (298.15 to 297.15) K at 0.1 MPa was employed. The corresponding heat capacities were determined from the integration of the measured heat flow. The heat capacity results are shown to be in good to very good agreement with the available literature values. In addition, good correlations were obtained for the effect of isotopic substitution on both molar heat capacity and apparent molar heat ...

2008-11-01

197

Preparation of wood-polymer composites using radiation  

International Nuclear Information System (INIS)

Wood-polymer composites (WPC) have been prepared of pinewood with different monomers using Gamma radiation: acrylamide, butyl acrylate, butyl methacrylate, styrene, acrylonitrile, and polyester. The polymer loading was determined as a function of monomer concentration and absorbed dose. The data show that polymer loading increases by increasing the monomer concentration. In two cases, BMA and polyester, the polymer loading decreases at high concentrations. This can be explained by the increase of the viscosity. Thus the diffusion of the compound into bulk would be slower. The absorbed dose seems to play a positive role in enhancing the polymer loading by increasing the dose. The mechanical properties, tensile and compression strength, have been improved in the most cases for all monomer concentrations or absorbed doses. Using polyester there was no improvement in the mechanical properties, and using acrylamide the ...

1976-11-25

198

Collection of athermal phonons into doped Ge thermistors using quasiparticle trapping  

Energy Technology Data Exchange (ETDEWEB)

We have developed a low-temperature particle detector that uses a novel quasiparticle trapping mechanism to funnel athermal phonon energy from an 80 mg Ge absorber into a 1.6 mg doped Ge thermistor via a superconducting Al film. We report on pulse height spectra obtained at 320 mK by scanning a {sup 241}Am alpha source along the device, and show that up to 20% of the energy deposited in the Ge absorber by a 5.5 MeV alpha particle interaction can be collected into a thermistor via quasiparticle trapping. We show that this device is sensitive to the position of an alpha particle interaction in the Ge absorber for interaction distances of up to 5 mm from a quasiparticle trap.

1995-05-15

199

Clinical application of dosimetry in electron beam therapy  

International Nuclear Information System (INIS)

In everyday radiotherapy we must carry out the determination of absorbed dose measurement according to JARP's protocol. We explained an outline of JARP's 1974 and 1986 protocol in electron beam therapy, and mentioned it about the matter that should examined. To use it easily in clinic, a simplified procedure based on precisely to JARP's 1986 protocol is practical, the character of this procedure settles briefly the determination of mean incident energy of electron beams and get ready to table of ionization to absorbed dose conversion factor for various ionization chamber. Also, this procedure almost not influence on the accuracy of determination. We described systematically practical procedure for requisite absorbed dose calculation in a patient in electron beam therapy. (author).

200

Tropospheric chemistry of natural hydrocarbons, aldehydes, and peroxy radicals: Their connections to sulfuric acid production and climate effects  

International Nuclear Information System (INIS)

Recent work has shown that natural hydrocarbon emissions can significantly affect the levels of urban and regional tropospheric ozone. We report on the reactivities of these biogenic trace gases, particularly isoprene, focusing on their importance in the production of aldehydes and peroxy radicals, leading to increased levels of hydrogen over regional forests. Hydrogen peroxide can lead to the wet oxidation of sulfur dioxide to acidic sulfate in aerosols, fogs, and clouds. In turn, acidic sulfate can act to as a light scattering aerosol and a source of cloud condensation nuclei (CCN), potentially leading to global cooling. Aerosol sulfate and other dissolved organic and inorganic compounds can also play important roles as a greenhouse species in the lower troposphere.

1993-08-08

201

Search for Z' ---> e+ e- using dielectron mass and angular distribution  

Energy Technology Data Exchange (ETDEWEB)

The authors search Z{prime} bosons in dielectron events produced in p{bar p} collisions at {radical}s = 1.96 TeV, using a 0.45 fb{sup -1} dataset accumulated with the CDF II detector at the Fermilab Tevatron. To identify the Z{prime} {yields} e{sup +}e{sup -} signal, both the dielectron invariant mass distribution and the angular distribution of the electron pair are used. No evidence of a signal is found, and 95% confidence level lower limits are set on the Z{prime} mass for several models. Limits are also placed on the mass and gauge coupling of a generic Z{prime}, as well as on the contact interaction mass scales for different helicity structure scenarios.

2006-02-01

202

Radiation therapy in the treatment of hilar cholangiocarcinoma  

International Nuclear Information System (INIS)

The incidence of hilar cholangiocarcinoma is very rare worldwide. Radical resection is the only prognostic factor for long survival in patients with hilar cholangiocarcinoma. Postoperative radiation therapy can improve local control and survival rates for patients with palliative resection, but it remains controversial in patients with radical resection. Biliary drainage can effectively release bile duct obstruction for the majority of patients with locally advanced disease, and may even prolong survival when combined with radiation therapy. Radiation therapy includes extrernal beam therapy alone, external beam therapy with intraluminal brachytheapy and new radiation technique, such as three dimentional conformal therapy and intensity modulated radiation therapy. The propective randomized clinical study is needed for further investigation in the role of combined modality therapy especially for hilar cholangiocarcinoma. (authors)

2007-10-01

203

Penile rehabilitation therapy following radical prostatectomy  

British Library Electronic Table of Contents (United Kingdom)

Purpose. To compare erectile function (EF) recovery of patients treated by early penile rehabilitation therapy (PRT) with sildenafil and with control group. Method. Forty men treated by bilateral nerve sparing radical prostatectomy (NSRP) and with a normal pre-operative EF were enrolled. Fourteen days after surgery, they were randomised to a flexible-dose sildenafil group and to a control group. The International Index of Erectile Function (IIEF) questionnaire was completed before surgery and at 3, 6, 12 and 24 weeks after NSRP. Results. In the group treated, the mean IIEF score before surgery was 26.2 and 14.1, 16.2, 22.5 and 25.2 at 3, 6, 12 and 24 weeks after NSRP, respectively. In the control group, the respective scores were 26.5 and 12.4, 15.8, 15.3 and 17.4. There was a significant ...

2010-01-01

204

Penile Rehabilitation after Radical Prostatectomy: Where Do We Stand and Where Are We Going?  

British Library Electronic Table of Contents (United Kingdom)

ABSTRACT Introduction. Postprostatectomy erectile dysfunction (ED) remains a serious quality-of-life issue. Recent advances in the understanding of the mechanism of postprostatectomy ED have stimulated great attention toward penile rehabilitation. Aim. This review presents and analyzes a contemporary series of the recent medical literature pertaining to penile rehabilitation therapy after radical prostatectomy (RP). Main Outcome Measures. The laboratory and clinical studies related to penile rehabilitation are analyzed. The validity of the methodology and the conclusion of the findings from each study are determined. Methods. The published and presented reports dealing with penile rehabilitation following RP in human and cavernous nerve injury in animal models are reviewed. Results. Exciti...

2007-01-01

205

Outcomes of extremely low risk prostate cancer following radical prostatectomy  

British Library Electronic Table of Contents (United Kingdom)

The optimal management of men with very favorable clinicopathological factors who develop biochemical recurrence (BCR) after radical prostatectomy (RP) has not been previously reported. Both local and systemic recurrences are unlikely in this cohort. This study examines their management and outcomes. Between October 2000 to March 2010, 1627 men underwent open RP by a single surgeon. In all, 448 (27.5%) met the following criteria for extremely low risk disease: preoperative PSA level <10?ng?ml?1, clinical stage T1c/T2a, Gleason score ?6, estimated cancer volume in the surgical specimen ?5% and no evidence for positive surgical margin. Undetectable PSA was defined as ?0.04?ng?ml?1. BCR was defined as PSA ?0.2?ng?ml&#...

2011-01-01

206

One-electron redox reactions of pyrazolin-5-ones. A pulse radiolysis study of antipyrine and analogues  

Energy Technology Data Exchange (ETDEWEB)

One-electron oxidation of several derivatives of pyrazolin-5-one, including the drug antipyrine, were studied by pulse radiolysis of aqueous solutions. All the compounds were found to be oxidized by Br2 rapidly but considerably more slowly by weaker oxidants, such as peroxyl radicals. From redox equilibria using p-methoxyphenol and N,N,N',N'-tetramethyl-p-phenylenediamine as reference compounds, the one-electron oxidation potentials of the methyl-substituted 2-pyrazolin-5-ones were found to be in the range of 0.32-0.39 V versus normal hydrogen electrode. The relevance of these findings to the properties of the drug nafazatrom is discussed. Antipyrine was found to have a much higher oxidation potential, estimated as 1.2-1.5 V, which is rationalized on the basis of the phenyl substitution and lack of resonance stabilization of the radical cation.

1985-10-01

207

GREEN TEA PHENOLS INTERFERENCE IN THE GLUCOSE OXIDASE/PEROXIDASE TEST  

British Library Electronic Table of Contents (United Kingdom)

Abstract Green tea extract showed false-negative results in the determination of glucose via glucose oxidase (GOD) test. This investigation was undertaken to verify and find out the precise mechanism underlying this interference by determining the reaction kinetics of production and reduction of end-point chromophore. The peroxidase step of the GOD test was found to be interfered and phenols of the green tea were the interfering compounds. Green tea interfered and exerted its influence in a dual fashion. A part of the interference was observed as a result of the reduction of the finally formed chromophore, whereas the other form of interference was due to its hydrogen peroxide/free radical-scavenging activity. Reducing potential and the free radical-scavenging activity of the phenols in th...

2011-01-01

208

Extraction and analysis of antioxidant components from Origanum dictamnus  

British Library Electronic Table of Contents (United Kingdom)

Three alternative extraction procedures were carried out in order to separate the antioxidant components and isolate an efficient extract from Origanum dictamnus. Procedure A included sequential extractions with petroleum ether (PE), diethyl ether (DE) and ethanol; procedure B sequential extractions with PE and ethyl acetate (EAc); procedure C a single step extraction with ethanol. The most efficient radical scavengers, according to the DPPH method, were isolated in ethanol extract of procedure A (mainly rosmarinic acid), followed by ethanol extract of procedure C. However, both ethanol extracts had low solubility in oil and could not protect it. EAc and DE extracts, containing mainly apigenin and epirosmanol ethyl ether, presented lower radical scavenging activity but were very effective ...

2007-01-01

209

Exciplex processes involving trans naphthylethylenes. Implications of ground-state conformeric equilibria  

Energy Technology Data Exchange (ETDEWEB)

Five arylethylenes with 1-naphthyl, 2-naphthyl, and phenyl groups in 1,2-positions have been studied for singlet-mediated charge-transfer interactions with several amines and paraquat dication. 1-Phenyl-2-(2-naphthyl)ethylene and 1,2-di(2-naphthyl)ethylene exhibit distinct dependence of exciplex emission maxima and lifetimes, and fluorescence quenching constants, on excitation and/or monitoring wavelengths; this is in conformity with the existence of ground-state rotamers for these systems, wtih distinguishable absorption-emission spectra and fluorescence lifetimes. The fluorescence quenching by aromatic amines and paraquat dication occurs with rate constants in the limit of diffusion control and is accompanied by the formation of radical ions in polar solvents (acetonitrile). The transient spectra and kinetics associated with the radical ions, observed by 337.1- and 355-nm laser flash photolysis, are also reported. 10 figures, 4 tables.

1983-05-12

210

Evidence for a Narrow Near-Threshold Structure in the $J/\\psi\\phi$ Mass Spectrum in $B^+\\to J/\\psi\\phi K^+$ Decays  

Energy Technology Data Exchange (ETDEWEB)

Evidence is reported for a narrow structure near the J/{psi}{phi} threshold in exclusive B{sup +} {yields} J/{psi}{phi}K{sup +} decays produced in {bar p}p collisions at {radical}s = 1.96 TeV. A signal of 14 {+-} 5 events, with statistical significance in excess of 3.8 standard deviations, is observed in a data sample corresponding to an integrated luminosity of 2.7 fb{sup -1}, collected by the CDF II detector. The mass and natural width of the structure are measured to be 4143.0 {+-} 2.9(stat) {+-} 1.2(syst) MeV/c{sup 2} and 11.7{sub -5.0}{sup +8.3}(stat) {+-} 3.7(syst) MeV/c{sup 2}.

2009-03-01

211

Complications of Urologic Laparoscopic Surgery: A Single Institute Experience of 1017 Procedures  

British Library Electronic Table of Contents (United Kingdom)

Abstract Purpose: We evaluated complications of urologic laparoscopic surgery at our institution. Patients and Methods: From December 1991 to January 2009, 1017 urologic laparoscopic surgical procedures were performed in Kansai Medical University, including 277 radical prostatectomies, 13 donor nephrectomies, 74 partial nephrectomies, 158 radical nephrectomies, 55 pyeloplasties, 97 nephrouretectomies, 54 simple nephrectomies, 128 adrenalectomies, 34 varicocelectomies, and 127 other procedures. Medical records of each procedure were retrospectively evaluated. The difficulty of each procedure was classified according to the European Scoring System (ESS). Intraoperative and postoperative complications were graded according to the Satava and Clavien classifications, respectively. Results: Amon...

2010-01-01

212

Catalyzed oxidative degradation of methylene blue by in situ generated cobalt (II)-bicarbonate complexes with hydrogen peroxide  

British Library Electronic Table of Contents (United Kingdom)

Oxidative degradation of methylene blue (MB) by Co^2^+-HCO3^- system with H2O2 in aqueous solution was studied. Nearly complete decolorization of the dye was obtained in less than 50min in diluted NaHCO3 solution (25mM) in the presence of only 20mM Co^2^+ ions. Meanwhile, the conjugated structure and phenyl rings of the MB molecule were destroyed or even broken down into small organic acids and inorganic ions, as indicated by FT-IR spectra and ion-chromatography. Photoluminescence probing and radical scavenging technologies suggested that the reaction of MB degradation in this system mainly involved the generation and participation of hydroxyl radicals. Furthermore, by cyclovoltammetric measurements, the in situ formed different complexes between Co^2^+ and HCO3^- were observed at differen...

2011-01-01

213

A study of the reactions CH[sub 4] + OH [yields] CH[sub 3] + H[sub 2]O and C[sub 2]H[sub 6] + OH [yields] C[sub 2]H[sub 5] + H[sub 2]O by ab initio  

Energy Technology Data Exchange (ETDEWEB)

The reactions of the hydroxyl radical with hydrocarbons and fluoro hydrocarbons attract significant attention due to their importance in atmospheric chemistry. Its reactions with the two first hydrocarbons, methane and ethane are of special interest because, owing to the small size of these systems, they serve as a prototype for the theoretical studies of hydrogen abstraction reactions. In this work, the reaction and activation energies of the hydroxyl radical abstraction reaction with methane and ethane have been investigated by correlated ab initio and DFT methods. The DFT reaction energies are in good agreement with experimental values, but the activation energies may be in severe error. (authors) 22 refs.

1999-04-01

214

A search for resonant Z pair production  

Energy Technology Data Exchange (ETDEWEB)

I describe a search for anomalous production of Z pairs through a new massive resonance X in 2.5-2.9 fb{sup -1} of p{bar p} collisions at {radical}s = 1.96 TeV using the CDFII Detector at the Fermilab Tevatron. I reconstruct Z pairs through their decays to electrons, muons, and quarks. To achieve perhaps the most efficient lepton reconstruction ever used at CDF, I apply a thorough understanding of the detector and new reconstruction software heavily revised for this purpose. In particular, I have designed and employ new general-purpose algorithms for tracking at large {eta} in order to increase muon acceptance. Upon analyzing the unblinded signal samples, I observe no X {yields} ZZ candidates and set upper limits on the production cross section using a Kaluza-Klein graviton-like acceptance.

2008-12-01

215

Surge Capacity for Response to Bioterrorism in Hospital Clinical Microbiology Laboratories  

UK PubMed Central (United Kingdom)

Surge capacity is the ability to rapidly mobilize to meet an increased demand. While large amounts of federal funding have been allocated to public health laboratories, little federal funding has been...Full Text Available

2003-12-01

216

Superior energy capacity of graphene nanosheets for a nonaqueous lithium-oxygen battery.  

Science.gov (United States)

Graphene nanosheets (GNSs) were synthesized and used as cathode active materials in a nonaqueous lithium-oxygen battery. The GNSs electrode delivered an extremely high discharge capacity in comparison to carbon powders, which is attributed to its unique morphology and structure. PMID:21779551

2011-07-21

217

Sexual Dimorphism in Primate Aerobic Capacity: A Phylogenetic Test  

UK PubMed Central (United Kingdom)

Male intrasexual competition should favour increased male physical prowess. This should in turn result in greater aerobic capacity in males than in females (i.e., sexual dimorphism), and a correlation...Full Text Available

2010-06-01

218

Only Slight Impact of Predicted Replicative Capacity for Therapy Response Prediction  

UK PubMed Central (United Kingdom)

BackgroundReplication capacity (RC) of specific HIV isolates is occasionally blamed for unexpected treatment responses. However, the role of viral RC in response to antiretroviral...Full Text Available

219

Muscle strength, endurance, and aerobic capacity in rheumatoid arthritis: a comparative study with healthy subjects.  

UK PubMed Central (United Kingdom)

Isometric/isokinetic muscle strength and isokinetic endurance of the lower extremities as well as aerobic capacity were evaluated in 67 patients (43 female, 24 male; mean age 53 years, range 23-65)...Full Text Available

1992-01-01

220

Maximum capacity of steam turbine units  

International Nuclear Information System (INIS)

The author investigates the question of the maximum capacity of steam turbines in nuclear power plants when towards the end of the nineties turbo-generator units of 3,000 MW and more will be necessary as a result of increased energy demand. (TK).

221

Lung diffusing capacity in a hyperbaric environment: assessment by a rebreathing technique.  

UK PubMed Central (United Kingdom)

A rebreathing method was developed for measuring diffusing lung capacity for carbon monoxide (DLCO) in a hyperbaric environment. Twenty two professional naval divers with normal lung function were included...Full Text Available

1992-04-01

222

Global Soil Water Holding Capacity Dataset from UNEP ... - GCMD - NASA  

Science.gov (United States)

Global Soil Water Holding Capacity Dataset from UNEP/GRID. Entry ID: GNV0025 ... Dao at unep.org. Contact Address: Head of Metadata & Socio-Economics Unit ...

223

Effect of forced swimming stress on in-vivo fertilization capacity of rat and subsequent offspring quality  

UK PubMed Central (United Kingdom)

AIMS:This study aimed to determine the effect of 50 days of forced swimming stress on fertilization capacity of rat and subsequent offspring quality.SETTING...Full Text Available

2010-01-01

224

The ''Complex Reality'' of Research Capacity Development in Mathematics Education in Southern African Development Community Countries  

Science.gov (United States)

This paper explores how an aid-funded Ph.D.-programme in mathematics education instituted in some Southern African Development Community countries measures up to issues related to research capacity development projects. The research capacity development programme is described and reflected against mutual benefit, relevance, sustainability and prioritization of the location of project funding expenditure--some of the constructs in the discourse on research capacity development initiatives. It is found that the benefits of the programme are indeed mutual; the outcomes regarding relevance and sustainability are more uncertain and the location of expenditure of the funding is not overtly in favour of the donor country.

2005-11-01

226

Abstracts by Mission Directorate - NASA  

Science.gov (United States)

A new high capacity anode composite based on mesoporous silicon is proposed. By virtue of a structure that resembles a pseudo one-dimensional phase, ...

227

Silicon nanopowder as active material for hybrid electrodes of lithium-ion batteries  

British Library Electronic Table of Contents (United Kingdom)

Cycling parameters (reversible specific capacity, first-cycle coulombic efficiency, accumulated irreversible capacity, and reversible capacity retention) of hybrid electrodes based on mechanical mixtures of a silicon nanopowder with KS6 and MAG-20 synthetic graphites and binders of varied nature were subjected to an integrated analysis in comparison with graphite electrodes.

2011-01-01

228

The use of nitrogen isotopes in research on sheep nutrition  

International Nuclear Information System (INIS)

Using nitrogen-13 initial measurements have been made of rumen ammonia-nitrogen pool size and turnover, and rate of incorporation of ammonia into microbial protein. It is also feasible to measure the rate of incorporation of absorbed ammonia into urea and the appearance of label in saliva.

1985-08-26

229

The Neutron Radiography Reactor (NRAD)  

Science.gov (United States)

The Neutron Radiography Reactor (NRAD) operated by Argonne National Laboratory is described in this paper. NRAD was designed to allow radiography of highly absorbing reactor fuel assemblies in the vertical position on the routine basis. 7 figs.

1990-01-01

230

The Chemical Reactions of Sulfur in the Citrate Process for Flue Gas Desulfurization.  

Science.gov (United States)

The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduce...

1981-01-01

231

The Atmospheric Trace ... - NASA Langley Science Directorate  

Science.gov (United States)

Trace gas molecules absorb specific wavelengths of incoming solar ... These data(with information collected from similar experiments carried on balloons, rockets, ... The ATMOS sensor instrumentis a state-of-the-art version of a 19th century ...

232

Remote disassembly of the absorber open-test assembly at the FFTF/IEM cell  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) interim examination and maintenance (IEM) cell is used for the remote disassembly of irradiated fuel and material experiments. The absorber open-test assembly (AOTA) is a 12-m (40-ft)-long instrumented absorber (control-rod-material) test assembly. Its primary purpose is to characterize the FFTF control-rod-material reaction rate during reactor operation. Instrumentation allowed temperature and pressure measurements at various locations in several absorber pins during reactor operation. After residing several months in the reactor, the assembly was transferred to the IEM cell by the closed-loop ex-vessel machine (CLEM) for separation of the irradiated portion of the experiment from the instrument stalk. After separation, the 3.6-m (12-ft)-long assembly was processed through the sodium removal system and shipped off-site for examination. This success allowed the timely completion of a major ...

1990-11-11

233

Pion-induced fission  

Energy Technology Data Exchange (ETDEWEB)

The A(..pi../sup +/,/sup 3/He)B reaction near threshold is studied in a model where the pion is absorbed by an /sup 4/He constituent of the target nucleus. The predictions of this model using harmonic oscillator cluster wave functions agree semi-quantitatively with the experimental data on the inverse reaction.

1982-03-10

234

Incorporate the latest FGD trends into mist-eliminator design. [Flue gas desulfurization  

Science.gov (United States)

Mist eliminators for flue gas desulphurisation units remove liquid droplets entrained in the flue gas leaving the SO/sub 2/-absorber vessels. The commercial designs currently available are described.

1984-03-01

235

Gun Barrel Vibration Absorber to Increase Accuracy  

Science.gov (United States)

Page 1. Page 2. Page 3. Page 4. Page 5. Page 6. Page 7. Page 8. Page 9. Page 10. Page 11. Page 12. Page 13. Page 14. Page 15. Page 16. Page ...

2002-02-01

236

GaAs Blocked-Impurity-Band Detectors for Far-Infrared Astronomy  

Energy Technology Data Exchange (ETDEWEB)

High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing layer of a BIB detector, has been achieved. The control of the donor concentration, however, was found to be insufficient for detector production. The growth by LPE of a high-purity film onto a commercially grown vapor-phase epitaxial (VPE) n-type GaAs doped absorbing layer resulted in a BIB device that showed a significant reduction in the low-temperature dark current compared to the absorbing layer only. Extended optical response was ...

2004-12-21

237

First Measurements of the Inclined Boron Layer Thermal-Neutron Detector for Reflectometry  

Energy Technology Data Exchange (ETDEWEB)

A prototype detector based on the inclined absorber layer principle is introduced. For the Liquids Reflectometer at the Spallation Neutron Source, it is shown to be a significant improvement over its current detector, which imposes an instantaneous count rate limitation of 50 kcps.

2008-10-01

238

Design and Validation of a Gun Barrel Vibration Absorber.  

Science.gov (United States)

Page 1. Page 2. Page 3. Page 4. Page 5. Page 6. Page 7. Page 8. Page 9. Page 10. Page 11. Page 12. Page 13. Page 14. Page 15. Page 16. Page ...

1997-05-01

239

Current state of methodology on hemoglobin oximetry in tissues.  

Science.gov (United States)

Photon migration provides sensitive tissue oximetry in which the optical pathlength is known. Phase array gives the precise location of a subnanomolar amount of hidden absorber in highly scattering medium. PMID:8079713

1994-01-01

240

Carbon dioxide, climate and the sea  

Energy Technology Data Exchange (ETDEWEB)

Only half of the carbon dioxide produced by burning fossil fuels stays in the atmosphere. It is thought that the oceans absorb the rest. To understand the world's climate it is necessary to know how the atmosphere, ocean and biosphere interact.

1985-11-21

241

Carbon dioxide absorption methanol process  

Energy Technology Data Exchange (ETDEWEB)

A process is described for removing carbon dioxide from a feed stream of natural gas, having at least methane, ethane and heavier hydrocarbon, comprising: separating the feed stream in a first separator to form a first stream, having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane, and a second stream, having methane, carbon dioxide and ethane; mixing the second stream with a polar compound to form a third stream; separating the vapor and liquid of the third stream in the bottom portion of an absorber; absorbing carbon dioxide and ethane from the separated vapor of Step C in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane forming a fourth stream; separating the ethane from the polar compound and carbon dioxide in a separator; separating the first stream in a third separator to separate the propane and heavier ...

1987-06-23

242

Black holes as detectors of tachyons  

International Nuclear Information System (INIS)

Tachyons fired into and absorbed by rotating black holes can violate the second and third laws of black hole physics. It is suggested that apparent break-downs of these laws in astrophysical black holes can indicate the existence of cosmic tachyons. (author).

243

Adaptive Gun Barrel Vibration Absorber.  

Science.gov (United States)

Gun barrel vibrations lead to dispersion in the shot patterns. Thus, reducing these vibrations should lead to increased accuracy. Since the muzzle is the anti-node for all vibration modes and its vibrations have the greatest effect on shot dispersion, it ...

2002-01-01

244

Absorption of tachyons in extended relativity an answer to Basano  

International Nuclear Information System (INIS)

It is answered to a previous letter by Basano, and shown that the difficulties met by that author within ''Extended relativity'' do not exist, but are due to the erroneous assumption that a certain condition for tachyons to be absorbed by a macro-object is sufficient (whilst it is only a necessary one).

245

A Prospective, Randomised, Controlled Trial Comparing Wound Dressings Used in Hip and Knee Surgery: Aquacel and Tegaderm Versus Cutiplast  

UK PubMed Central (United Kingdom)

INTRODUCTIONCutiplast (absorbent perforated dressing with adhesive border; Smith & Nephew) is commonly used following orthopaedic operation, but complications of its use...Full Text Available

2006-01-01

246

NEUTRON-ABSORBING BRICKS MADE FROM CaB$sup 6$  

Science.gov (United States)

nsive neutron-absorbing bricks from commercially available CaB/sub 6/ powder. The bricks are 2 x 3 x 5 in., and are strong enough to withstand normal handling. They last indefinitely; the ones described are now 7 years old, used and stored under normal room temperatures and humidities. The procedure is to make a thick, dry mud with the powder and water, followed by compression in a mold at pressures of about 1 ton/in./sup 2/ or more. The bricks are then baked for 2 hours or longer at a temperature of about 750 deg C. (auth)

1960-05-01

247

Multicellular level dosimetry and low dose rate effects  

International Nuclear Information System (INIS)

Building on the concepts of MIRD methods described by Webber, Watson and others at this Symposium on the Dosimetry of Administered Radionuclides, we will now consider how to apply these principles to several experimentally based open-quote macroclose quotes and multicellular models. Specifically, methods to calculate absorbed dose using different types of particulate emission (alpha, beta) with a variety of antibody carriers (IgG, F(ab')_2, Fab) for radioimmunotherapy (RIT) will be reviewed. Additionally, a discussion of direct measurement methods at the multicellular level will reveal the problems of tumor absorbed dose heterogeneity when applied to animal and clinical studies.

1989-09-21

248

Modeling and Experimental Study of Carbon Dioxide Absorption in a Membrane Contactor  

Energy Technology Data Exchange (ETDEWEB)

This dissertation deals with membrane gas absorption in the application of CO{sub 2} removal by aqueous alkanolamines, using microporous PTFE hollow fiber membranes. A new lab-scale apparatus was constructed and an extensive experimental study executed to determine the performance of the membrane gas absorber, with aqueous solutions of monoethanolamine (MEA) and methyldiethanolamine (MDEA) as absorbents. The important operation parameters CO{sub 2} partial pressure, gas velocity, liquid velocity, temperature and liquid CO{sub 2} loading were systematically varied within the range typically experienced in a process for exhaust gas CO{sub 2}-removal

2003-03-15

249

Estimation of X-rays dose in the crystals of final thickness  

International Nuclear Information System (INIS)

A calculation method of the X-ray radiation dose (energy of gamma- radiation remains in the range of energies where the mechanism of photoelectric absorption is the prevailing one) absorbed in the absorbers of final thickness is suggested. Calculations of resorption of secondary radiation (characteristic fluorescences) in the substance and kinetic energy of photoelectrons caused by this resorption (it would be enough to consider one or two hard series) are presented. Calculation of the spectrum of photoelectron energy yield in TeInSe_2 monocrystal for 0.1-0.5 A range of X-ray radiation is conducted by the developed methods.

250

Electron Beam and Gamma Radiolysis of Solid-State Metoclopramide  

British Library Electronic Table of Contents (United Kingdom)

Purpose Study the radiolysis of solid-state metoclopramide hydrochloride at various absorbed doses. Elucidate the structure of the degradation products to gain information on the radiolysis mechanisms. Methods Solid-state metoclopramide samples were irradiated at several doses with gamma rays and high-energy electrons to evaluate the influence of the dose rate. High-performance liquid chromatography with a diode array detector was used to measure the chemical potency as a function of the absorbed dose and to quantify the degradation products. The characterization of degradation products was performed by liquid chromatography/atmospheric pressure chemical ionization/tandem mass spectrometry. Results The degradation of solid-state metoclopramide after irradiation was negligible. No qualitati...

2006-01-01

251

Analysis of the thermal performance of dynamic solar systems  

Energy Technology Data Exchange (ETDEWEB)

This article proposes a model for estimating the effect of the overall thermal resistance of the absorber and the coolant on a solar thermal energy system utilizing advanced heat transfer mediums. Two equations can be used to model a dynamic system: one for the maximum conversion efficiency and one to specify the constraint that, in quasi-steady state, the net energy collected must be transferred to the coolant. These two equations define a constrained optimization problem in two variables, the fluid and the absorber temperatures. The results present interesting implications for liquid metal, direct absorption, and solar evaporating systems.

1996-03-01

252

A somatic dose index for diagnostic radiology  

International Nuclear Information System (INIS)

Irradiation of the human body in diagnostic X-ray procedures results in different absorbed doses in the various body organs. A somatic dose index in formulated by applying the relative sensitivity of the human to each of the most important somatic effects and utilizing the absorbed dose in the affected organs. This quantity is used to convey a cumulative somatic impact and is computed for common radiographic views in diagnostic radiology as a function of beam quality for a nominal IR entrance exposure. Using typical X-ray beam qualities and exposures, the frequency of the various radiographic views that make up an examination and the frequencies of the various examinations in the national population, illustrative examples of the application of the somatic dose index are presented. (author).

1978-01-01

253

Optimization of doubly Q-switched lasers with both an acousto-optic modulator and a GaAs saturable absorber  

Science.gov (United States)

A doubly Q-switched laser with both an acousto-optic (AO) modulator and a GaAs saturable absorber can obtain a more symmetric and shorter pulse with high pulse peak power, which has been experimentally proved. The key parameters of an optimally coupled doubly Q-switched laser with both an AO modulator and a GaAs saturable absorber are determined, and a group of general curves are generated for what we believe is the first time, when the single-photon absorption (SPA) and two-photon absorption (TPA) processes of GaAs are combined, and the Gaussian spatial distributions of the intracavity photon density and the initial population-inversion density as well as the influence of the AO Q-switch are considered. These key parameters include the optimal normalized coupling parameter, the optimal normalized GaAs saturable absorber parameters, and the normalized parameters of the AO Q-switch, which can maximize the output energy. ...

2007-08-20

254

The chemical properties of silica particle surface in relation to silica-cell interactions  

Energy Technology Data Exchange (ETDEWEB)

Although silicosis has been studied extensively, the mechanism is still not fully understood. Experiments do provide evidence that the actions of unique properties of silica surface on the cell membrane are the starting point of silicotic processes. This paper summarizes literature on chemical properties of silica surface, and the effect of particle size on silica toxicity. This paper also discusses the ways in which silica dusts are though to interact with the cell membrane, with emphasis on freshness, hydrogen bonding, and free-radical interactions.

1989-01-01

255

The Fenton oxidation mechanism: reactivities of biologically relevant substrates with two oxidizing intermediates differ from those predicted for the hydroxyl radical.  

UK PubMed Central (United Kingdom)

The application of kinetic probes that allow one to determine relative reactivities of biologically relevant substrates with oxidizing intermediates in the Fenton reagent (H2O2 plus Fe2+ in acidic aqueous...Full Text Available

1994-07-05

256

Synthesis, properties and biologic activity of nitro-benzo (B) of thiophene- and 2,3-di-hydro-benzo (B) thiophene-1,1-dioxides  

International Nuclear Information System (INIS)

The purpose of work is systematical studying of benzo (B) of thiophene-1,1-dioxides and their 2,3-di-hydro derivatives behaviour in the reactions of electrophflic, radical, nucleophilic nitration, reduction of nitro group, embodiment of synthesis of N-amino derivatives, investigation of sulfur containing hetero-cyclic compounds, including of residues of some steroids

1998-01-01

257

Polysulfone/Metal Nanocomposites by Simultaneous Photoinduced Crosslinking and Redox Reaction  

British Library Electronic Table of Contents (United Kingdom)

Abstract A diacrylate polysulfone oligomer is synthesized and used as the acrylic oligomer for the in situ synthesis of noble metal/PSU nanocomposites through UV-induced simultaneous radical polymerization of acrylic functionalities and NP formation by reduction of their precursors. Thus, silver or gold NPs are formed in situ during polymer network formation. FESEM analysis of the morphology of the cured systems demonstrates that the nanoparticles of the noble metals are homogeneously distributed in the network without macroscopic agglomeration.

2011-01-01

258

Nonuniqueness of self-propagating spiral galaxy models  

Energy Technology Data Exchange (ETDEWEB)

We demonstrate the nonuniqueness of the basic assumptions leading to spiral structure in self-propagating star formation models. Even in the case where star formation occurs purely spontaneously and does not propagate, we have generated spiral structure by adopting the radically different assumption where star formation is systematically inhibited.

1984-05-15

259

Mechanism of the caking property reducing the coking coal by addition of low-rank coal  

Energy Technology Data Exchange (ETDEWEB)

The use of low rank coal leads to a reduction of the coke strength because of the reduction of the caking property of coking coal. The authors have tried to understand this mechanism by extracting and analyzing the caking component of low rank coal and coking coal. It was found that the caking component is decreased by radical attack from the low rank coal, and thus the caking property is reduced. 11 figs., 3 tabs.

1994-12-31

260

Explosives and blasting  

Energy Technology Data Exchange (ETDEWEB)

There have been no radically new commercial bulk explosives since Atlas Powder Company's introduction of emulsions onto the market in 1968. But the effectiveness, safety and management of these familiar explosives is continuously being improved by the development of blast design techniques, explosives delivery and initiation systems, and monitoring methods. The author looks at developments in blasting technology and discusses experiences with Handibulk emulsion delivery systems.

1994-02-01

261

Environmental Nanoscience Initiative  

Environmental Research Database

DescriptionProgramme background Nanotechnology is the design and manufacture of substances typically between one and several hundred billionths of a metre in size. In this size range the properties of substances can change quite radically, offering potentially large socio-economic, health and environmental benefits. For example, nanofuel additives could help reduce emissions and particles from diesel engines. Nanoparticles may also be able to help remove persistent pollutants in soils and groundwaters. Th [continued...

2013-01-01

262

Current diagnosis of tumors developed in the internal auditory canal and cerebellopontine angle  

Energy Technology Data Exchange (ETDEWEB)

The introduction of CT scan and, more recently, magnetic resonance imaging, has radically changed the diagnostic approach to tumors developed in the internal auditory canal and cerebellopontine angle. CT scan with intravenous injection visualizes tumors lying in the cerebellopontine angle. Magnetic resonance imaging, especially using gadolinium, is a very accurate means for diagnosing tumors of both the auditory canal and cerebellopontine angle.

1988-10-13

263

Current applications of magnetic resonance in coal liquefaction research  

Energy Technology Data Exchange (ETDEWEB)

Some applications of magnetic resonance in coal liquefaction research described briefly are: (1) investigation of the nature of carbon deposits on used coal-liquefaction catalysts, (2) determination of the fate of hydrogen during coal liquefaction, and (3) observation of transient free radicals during coal pyrolysis. The first two applications make use of cross-polarization /sup 13/C magnetic resonance combined with magic angle spinning, and the third application is an electron spin resonance study. (BLM)

1982-01-01

264

Beyond the Flatline  

British Library Electronic Table of Contents (United Kingdom)

Abstract High Post-Modernism with its understanding of the significance of the image anticipated the flattening of culture, first in advertising and the printed media, and more recently online. Sam Jacob of FAT speculates on architecture's relationship with the Internet, -a flatland of undifferentiated information-, and how Radical Post-Modernism might be best placed to resist the ubiquity of global culture while reanimating the social and cultural agenda of Modernism and Post-Modernism. Copyright 2011 John Wiley & Sons, Ltd.

2011-01-01

265

Lithium intercalation in porous carbon electrodes  

Energy Technology Data Exchange (ETDEWEB)

Carbons derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon electrodes have a bulk density of 0.35-0.5 g/cm{sup 3}, relatively low surface areas (< 10 m{sup 2}/g), and micron-size cells. Pyrolysis temperature influences the reversible lithium intercalation and the irreversible capacity (associated with the formation of the passivating layer). Carbon electrodes pyrolyzed at 600{degrees}C have first-cycle capacity as high as 550 mAh/g as well as large irreversible capacity, 440 mAh/g. Electrodes prepared at 1050{degrees}C have reversible capacities around 270 mAh/g with relatively lower capacity losses (120 mAh/g). Doping the organic precursors with phosphoric acid, prior to pyrolysis at 1050{degrees}C, leads to carbon electrodes with reversible ...

1995-04-01

266

How to apply the uncertainties in estimating the vertical resistance of piles to limit state design; Kui no shijiryoku suitei ni okeru jikakujitsusei to genkai jotai sekkeiho eno tekiyo  

Energy Technology Data Exchange (ETDEWEB)

This paper describes effects of methods to calculate and analyze bearing capacities and transformation of pile foundations in the limit state design method. Different pile bearing capacity estimating expressions including criteria used in other countries were applied to the case of steel piles driven into the `diatomaceous mudstone ground` in Noto Peninsula, Ishikawa Prefecture where detailed ground and soil surveys have been made, and the case of piles driven in place into the `sandy and clayish soil alternating ground layers` at the Tennoji area in Osaka Prefecture. The results were compared with those of static loading tests. As a result, the estimated bearing capacity limit was found to agree relatively well with the measured values where uniaxial compression strength was used according to the reference architectural formula. The estimated bearing capacity limit using the N-value as the soil ...

1994-09-01

267

Carbon nanotube coating silicon doped with Cr as a high capacity anode  

Energy Technology Data Exchange (ETDEWEB)

Effects of dopant and coating carbon nanotube on anodic performance of Si were studied for metallic anode Li ion rechargeable battery with large capacity. Although the large Li intercalation capacity higher than 1500mAhg{sup -1} is exhibited on pure Si, it decreased drastically with increasing cycle number. Increasing the electrical conductivity by doping Cr or B is effective for increasing the initial capacity and the cycle stability of Si for Li intercalation. Coating semiconductive Si with the carbon nanotube by decomposition of hydrocarbon is effective for increasing the cycle stability, though the initial Li intercalation capacity slightly decreased. Conducting binder is also important for increasing the cycle stability and it was found that Li intercalation capacity higher than 1500mAhg{sup -1} can be sustained by using poly vinyliden fruolide. Consequently, reversible Li ...

2005-08-26

268

Stacking the Deck: Idling and Reactivation of Capacity in Offshore Drilling  

British Library Electronic Table of Contents (United Kingdom)

Independent drilling contractors own all offshore drilling rigs, which they lease to oil and gas companies for use in their pursuit of their exploration and development plans. Oil and gas companies' demand for these rigs can vary quickly and dramatically in response to changes in the world market for oil and natural gas. As a result, drilling contractors often try to manage excess capacity by idling rigs (known in the industry as "stacking" a rig), reactivating them when demand recovers. This paper examines these decisions over the course of a price cycle in 1998-2000 to investigate the role of firm and rig heterogeneity in determining drillers' decisions about idling and reactivating capacity.

2008-01-01

269

Seconds capacity reserve and heat consumption with different operating procedures of steam turbines. Sekundenleistungsreserve und Waermeverbrauch bei verschiedenen Betriebsarten von Dampfturbinen  

Energy Technology Data Exchange (ETDEWEB)

In order to ensure a power balance in an electrical network a spinning reserve has to be capable of activation within seconds. However, because of the need to vary the fuel flow in the steam generator, the run-up of output takes minutes. The required capacity response is therefore achieved by storage of steam from the steam generator. In this process the turbine control valves come into action in a specific manner. The paper describes the importance of the initial reserve for unit capacity control. (orig.).

1989-09-01

270

Pumped storage plants. Status and perspectives  

Energy Technology Data Exchange (ETDEWEB)

Pumped storage plants (PSP) enable the storage of energy with rated capacities of order of GW at a single site. Reservoirs allow charging and discharging times of at least hours, sometimes days or even up to several weeks. Short ramp-up times permit the participation in the secondary reserve market as a standing reserve. For bulk energy storage, PSP reach the lowest, specific costs. In the EU27 countries, Norway and Switzerland, a total of 44 GW of pumped storage capacity is installed. The utilisation of PSP strongly correlates with the amount of conventional generation capacity, rather than with topographical options. (orig.)

2011-07-01

271

High capacity heavy media processing  

Energy Technology Data Exchange (ETDEWEB)

Pittston Coal Company recognized the potential economic benefit of improving process efficiency with increased capacity at it`s U.K. No. 1 Coal Preparation Plant. Accordingly, extensive research, both domestically and internationally, was conducted to select the appropriate technologies to achieve the desired circuit in the most cost effective manner while, at the same time, sacrificing neither structural integrity nor process performance. Large diameter heavy media cyclone technology was combined with highly efficient banana type screens and improved high intensity magnetic separators to create a coordinated process circuit that provided high efficiency at very high capacities in an economically attractive package.

1996-12-31

272

High capacity anode materials for rechargeable sodium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Electrochemical techniques have been used to study the reversible insertion of sodium into hard-carbon host structures at room temperature. In this paper the authors compare these results with those for lithium insertion in the same materials and demonstrate the presence of similar alkali metal insertion mechanisms in both cases. Despite the gravimetric capacities being lower for sodium than lithium insertion, the authors achieved a reversible sodium capacity of 300 mAh/g, close to that for lithium insertion in graphitic carbon anode materials. Such materials may therefore be useful as anodes in rechargeable sodium-ion batteries.

2000-04-01

273

Heat capacity measurement of some breeder materials  

International Nuclear Information System (INIS)

Isobaric molar heat capacities of powder and microsphere form of Li2TiO3 (s) and powder form of LiAlO2 (s) and Li2ZrO3 (s) were measured using a heat flux type differential scanning calorimeter in the temperature range 320 - 870 K. Specific heat capacities of LiAlO2 (s) was found to be much larger compared to those of Li2TiO3 (s) and Li2ZrO3 (s). (author)

2009-01-07

274

Capacity of a Simultaneous Quantum Secure Direct Communication Scheme between the Central Party and Other M Parties  

Science.gov (United States)

We analyse the capacity of a simultaneous quantum secure direct communication scheme between the central party and other M parties via M+1-particle GHZ states and swapping quantum entanglement. It is shown that the encoding scheme should be secret if other M parties wants to transmit M+1 bit classical messages to the centre party secretly. However, when the encoding scheme is announced publicly, we prove that the capacity of the scheme in transmitting the secret messages is 2 bits, no matter how large M is.

2006-10-01

276

Strain-dependent variation in collateral circulatory function in mouse hindlimb  

UK PubMed Central (United Kingdom)

The extent (density and diameter) of the native (preexisting) collateral circulation in healthy tissues and the capacity of collaterals to enlarge/remodel in obstructive arterial disease are important...Full Text Available

2010-08-01

277

Regulatory T cells in human disease and their potential for therapeutic manipulation  

UK PubMed Central (United Kingdom)

Regulatory T cells are proposed to play a central role in the maintenance of immunological tolerance in the periphery, and studies in many animal models demonstrate their capacity to inhibit inflammatory...Full Text Available

2006-05-01

278

Magnetocaloric and magnetoresistance studies of GdPd{sub 2}Si  

Energy Technology Data Exchange (ETDEWEB)

The compound GdPd{sub 2}Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric effect and ...

2001-01-22

279

Magnetocaloric and magnetoresistance studies of GdPd_2Si  

International Nuclear Information System (INIS)

The compound GdPd_2Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric effect and magnetoresistance, ...

2001-01-22

280

Hydrogen adsorption by activated charcoal at low pressure and 20/sup 0/K  

Energy Technology Data Exchange (ETDEWEB)

Measurements of hydrogen adsorption capacity by activated charcoal has been made at a pressure minus than 10/sup -4/ Pa and at 18 K.

1984-04-01

281

Heat capacities of the mixtures of ionic liquids with acetonitrile  

International Nuclear Information System (INIS)

Isobaric specific heat capacities were measured for {1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF4) + acetonitrile (MeCN)} and {1-methyl-3-octylimidazolium tetrafluoroborate (OMIMBF4) + acetonitrile} within the whole range of composition and temperatures from (283.15 to 323.15) K. The excess molar heat capacities were calculated from the experimental results and satisfactorily fitted to Redlich-Kister type polynomials for several selected temperatures. Negative deviations from the additivity of molar heat capacities were observed within the whole composition range of (HMIBMF4 + MeCN) and (OMIMBF4 + MeCN). The results obtained have been interpreted in terms of interactions between ionic liquids and acetonitrile.

2010-02-01

282

Effect of lithium intercalation on the structure of non-graphitizable carbon: small-angle neutron scattering  

Energy Technology Data Exchange (ETDEWEB)

Recent developments in rechargeable Li-ion battery technology include the use of lithium-carbon compounds instead of metallic anodes. Non-graphitizable carbons offer high capacity as the anode material but it's large irreversible capacity must be solved. The ultimate goals of the present work are to understand the origin of the high capacity and large irreversible capacity in conjunction with the structural change due to Li intercalation and thus to establish a scientific basis for optimizing their performance in real batteries. 'House of cards' model is considered and emphasis is given to find out the size of the pores present in the carbon fibers prepared from an isotropic petroleum pitch and heat treated at 1200degC. Small angle neutron scattering and wide angle neutron scattering results provide enlargement of pores and d-spacing of grapheme layers after Li intercalation. ...

2001-03-01

283

Effect of initial conditions, boundary conditions and thickness on the moisture buffering capacity of spruce plywood  

Energy Technology Data Exchange (ETDEWEB)

In this paper, the moisture buffering capacity of spruce plywood is measured by recording the change in mass of a test specimen when the air relative humidity (RH) is changed between 33% RH and 75% RH. The aim is to represent diurnal cycles in indoor humidity with 33% RH maintained for 16 h and 75% RH maintained for 8 h. Measurements are taken using two different apparatuses, which provide different convective transfer coefficients between the air and the plywood, and the results are compared to a numerical model for validation. The validated numerical model is then used to investigate the effect of initial conditions, boundary conditions and thickness on the moisture buffering capacity of plywood. The results show that the buffering capacity of plywood depends on the initial conditions and thickness of the plywood as well as the surface film coefficient and humidity cycle. (author)

2006-07-01

285

Chris Kemp is Named NASA CTO for IT  

Science.gov (United States)

Jun 23, 2010 ... Recently, NASA CIO Linda Cureton tapped Chris Kemp as the Agency's new Chief Technology Officer for IT. In this new capacity, he will work ...

286

Building drought management capacity in the Mekong River basin  

British Library Electronic Table of Contents (United Kingdom)

Over the past decades the Mekong River basin has experienced several droughts, the most recent of which occurred in the hydrological year 2004/2005. Impacts extended across agriculture, forestry, water resources, supply, industry, transport and the environment. In early 2006, the Mekong River Commission Secretariat initiated close consultations with the MRC member states Cambodia, Lao PDR, Thailand and Vietnam, aiming at the formulation of a common Drought Management Programme, which would enhance the existing drought management capacity and ensure effective support. This paper draws attention to the programme formulation process. It shows how national capacity needs were assessed and synthesized into a basin-wide capacity development programme. The paper concludes that in the context of i...

2008-01-01

287

Alkaline treatment of biomass fly ash for reactive dye removal from aqueous solution  

British Library Electronic Table of Contents (United Kingdom)

Biomass fly ash was treated with alkaline solution to enhance its adsorption capacity of Reactive Black 5 dye. The results revealed that the alkaline concentration, solution to fly ash ratio, treatment temperature and treatment time had a positive effect on the dye adsorption capacity of the treated fly ash (TFA), due to dissolving SiO2 and increasing the proportion of unburned carbon. In addition, the dye adsorption behavior of the TFA in aqueous solution was investigated. The effects of various experimental parameters (initial pH, initial dye concentration and contact time) were determined spectrophotometrically. The dye adsorption capacity of the TFA was maximized at an alkaline pH (8.2-10.4). The adsorption capacity of dye by the TFA increased with increasing initial dye concentration....

2010-01-01

288

A nanosized silicon thin film as high capacity anode material for Li-ion rechargeable batteries  

Energy Technology Data Exchange (ETDEWEB)

Silicon thin film with thickness in range 1000-5300 A deposited on rough Cu foil by a radio frequency magnetron sputtering is used as anode materials for Li-ion rechargeable batteries. The SEM, XRD and TEM analysis reveals that the Si thin film has a floccular nano-sized multi-crystalline structure. Li ions insertion/extraction evaluation is performed mainly with constant current charge/discharge cycling and cyclic voltammetry (CV) at room temperature. The cycleability and reversible discharge capacity are found to depend on the film thickness, and thinner films give larger accommodation capacity. A 3120 A Si film provides a reversible specific capacity over 3500 mA hg{sup -1} with excellent cycleability under 0.5 C charge/discharge rate.

2006-07-15

289

(Hadamard transform imaging)  

Science.gov (United States)

This report describes the design of, and image reconstruction capacity of a Hadamard Raman Microscopic imager. Microscopy of benzoic acid and graphite electrodes, as well as electrophoretic blotting, are described. (CBS)

1990-01-01

290

Tin-oxide-coated anodized aluminium selective absorber surfaces. Pt. 2. Aging and durability  

Energy Technology Data Exchange (ETDEWEB)

Accelerated aging tests on tin-oxide-coated anodized aluminium selective absorber surfaces have been performed. It is shown that the tin oxide layer provides excellent protection for the anodized surface. The thermal stability of the double layer is equal to, or better than, the stability of the bare anodized surface. Both surfaces degrade very slowly at 450deg C. The anodic layer is porous and therefore not very scratch resistant and it degrades when exposed to humidity, both acidic and alcaline. It is shown that the tin oxide film, which is hard and chemically very stable, almost completely protects the anodized surface from chemical degradation. The mechanical wear resistance is also considerably improved. The optical selectivity does not quite match that of the the anodized surface, but the remarkable stability together with the solar parameters of {alpha}=0.91 and hemispherical emittance {epsilon}= 0.16 (normal emittance {epsilon}{sub n}=0.12) make this ...

1991-03-01

291

The distribution of Lyman-limit absorption systems during and after reionization  

CERN Document Server

Lyman-limit absorption systems can play many important roles during and after cosmological reionization. Unfortunately, due to the prohibitively large dynamic range required, it is impossible to self-consistently include these systems in cosmological simulations. Using fast and versatile semi-numeric simulations, we systematically explore the spatial distribution of absorption systems during and following reionization. We self-calibrate the resulting number of absorbers to the mean free path (mfp) of the ionizing ultraviolet background (UVB), and present results at a given mfp and neutral hydrogen fraction. We use a simple optical depth criterion to identify the locations of absorbers. Our approach is fairly robust to uncertainties such as missing subgrid structure. Unlike at lower redshifts where the UVB is relatively uniform, at higher redshifts the fluctuations in the UVB and the HII morphology of reionization can drive the large-scale ...

2010-01-01

292

Seismic migration and absorbing boundaries with a one-way wave system for heterogeneous media  

Energy Technology Data Exchange (ETDEWEB)

A first-order one-way wave system has been created based on characteristic analysis of the acoustic wave system and optimization of the dispersion relation. The authors demonstrate that this system is equivalent to a third-order scalar partial-differential equation which, for a homogeneous medium, reduces to a form similar to the 45{degree} paraxial wave equation. This system describes accurately waves propagating in a 2D heterogeneous medium at angles up to 75{degree}. The one-way wave system representing downgoing waves is used for a modified reverse time migration method. As a wavefield extrapolator in migration, the downgoing wave system propagates the reflection events backwards to their reflectors without scattering at the discontinuities in the velocity model. Hence, images with amplitudes proportional to reflectivity can be obtained from this migration technique. They present examples of the application of the new migration method to synthetic seismic data where P-P reflections ...

1996-07-01

293

Radiative transfer in a solar absorbing particle laden flow  

Science.gov (United States)

A possible receiver configuration is a cavity in which a falling sheet of solid particles is directly irradiated by the concentrated solar flux passing through the aperture. Regardless of the particular geometry, the radiative transfer within the falling particle curtain must be studied in order to determine the net radiative heating rate for the particles. A discrete ordinate radiative transfer model has been developed to predict the radiative coupling within the falling particle curtain. The model determines how much energy is absorbed by the particles, how much is transmitted to the rear wall of the receiver, and determines the effects of particle scattering and thermal emission on the net radiation absorbed by the particles. The model accounts for the directional nature of the radiation field, particle scattering, and the wavelength dependence of the optical properties. The discrete ordinate model has been used to assess the influence of ...

1985-11-01

294

Photon dosimetry using plastic scintillators in pulsed radiation fields  

Energy Technology Data Exchange (ETDEWEB)

Simulations and experiments have been carried out to explore using a plastic scintillator as a dosimetry probe in the vicinity of a pulsed bremsstrahlung source in the range 4 to 20 MeV. Taking advantage of the tissue-equivalent properties of this detector in conjunction with the use of a fast digital signal processor near real-time dosimetry was shown to be possible. The importance of accounting for a broad energy electron beam in bremsstrahlung production, and photon scattering and build-up, in correctly interpreting dosimetry results at long stand-off distances is highlighted by comparing real world experiments with ideal geometry simulations. Close agreement was found between absorbed energy calculations based upon spectroscopic techniques and calculations based upon signal integration, showing a ratio between 10 MeV absorbed dose to 12 MeV absorbed dose of 0.66 at a distance of 91.4 m from the accelerator. This is ...

2007-04-01

295

Parametric Resonance Ionization Cooling and Reverse Emittance Exchange for Muon Collider  

Energy Technology Data Exchange (ETDEWEB)

Two methods to cool muon beams deeply below the limit conventionally established for the ionization cooling are proposed. In Phase Ionization Cooling (PIC), the beam is focused at wedge absorber plates each half of particle oscillation period by imposing a weak parametric resonance along the beam path. The resonance growth of particle amplitude is surmounted by the ionization cooling. At optimum, such arrangement results in reduction of each of two transverse emittances by an order of value in addition to the preceding 6D ionization cooling. Next, resonance focusing and transverse cooling can be continued in the regime of a fast Reverse Emittance Exchange (REMEX). Here, the sign of the absorber wedge is opposite to PIC while the dispersion increased. REMEX to be accompanied by the bunch lengthening and acceleration in order to maintain the relative energy spread at an appropriate level. The limitations due to energy straggling in ...

2005-09-18

296

Osmoregulation in the Avena coleoptile: control of solute uptake in peeled sections  

Energy Technology Data Exchange (ETDEWEB)

Peeled Avena sativa coleoptile sections have been used to study the control of solute uptake under conditions where the uptake is not limited by the cuticular barrier. In the presence of 2% sucrose, auxin enhances the rate at which the total osmotic solutes increase, but this appears to be a response to the increased growth rate, inasmuch as the auxin effect is eliminated when growth is inhibited osmotically. When sections are incubated in sucrose or in 10 millimolar NaCl, the osmotic concentration increases until a plateau is reached after 8 to 24 hours. Auxin has no effect on the initial rate of increase in osmotic concentration. This difference in steady-state osmotic concentration is, in part, a response to auxin itself, as it persists when auxin-induced growth is inhibited osmotically. The upper limit for osmotic concentration does not appear to be determined by the turgor pressure, inasmuch as a combination of sucrose and NaCl gave a higher plateau osmotic concentration than did ...

1982-01-01

297

Dose planning and dose delivery in radiation therapy  

International Nuclear Information System (INIS)

A method has been developed for calibration of CT-numbers to volumetric electron density distributions using tissue substitutes of known elemental composition and experimentally determined electron density. This information have been used in a dose calculation method based on photon and electron interaction processes. The method utilizes a convolution integral between the photon fluence matrix and dose distribution kernels. Inhomogeneous media are accounted for using the theorems of Fano and O'Connor for scaling dose distribution kernels in proportion to electron density. For clinical application of a calculated dose plan, a method for prediction of accelerator output have been developed. The methods gives the number of monitor units that has to be given to obtain a certain absorbed dose to a point inside an irregular, inhomogeneous object. The method for verification of dose distributions outlined in this study makes it possible to exclude the treatment related ...

2008-08-01

298

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment  

Science.gov (United States)

The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were ...

2001-08-31

299

W. E. B. Du Bois's Basic American Negro Creed and the Associates in Negro Folk Education: A Case of Repressive Tolerance in the Censorship of Radical Black Discourse on Adult Education  

Science.gov (United States)

W. E. B. Du Bois, one of the brightest lights in African American history, wrote a sparkling critique of the American social and economic system originally planned as part of the Bronze Booklets series, edited and published by Alain Locke and the Associates in Negro Folk Education. The piece was never published and has, until now, been lost to the annals of adult education history. Using historical evidence, the authors examine Du Bois's Basic American Negro Creed and the circumstances that led to its exclusion from the series. It is argued that the Creed was far too radical for the liberal minded Carnegie Corporation and its leaders who were only interested in accommodating adult education for Blacks through the AAAE funded Bronze Booklets. The exclusion of the Creed represents an example of repressive tolerance by the AAAE.

2008-12-01

300

Search for excited and exotic muons in the mu gamma decay channel in p anti-p collisions at s**(1/2) = 1.96-TeV  

Energy Technology Data Exchange (ETDEWEB)

The authors present a search for excited and exotic muon states {mu}*, conducted using an integrated luminosity of 371 pb{sup -1} of data collected in p{bar p} collisions at {radical}s = 1.96 TeV at the Tevatron with the CDF II detector. They search for associated production of {mu}{mu}* followed by the decay {mu}* {yields} {mu}{gamma}, resulting in the {mu}{mu}{gamma} final state. They compare the data to model predictions as a function of the mass of the excited muon M{sub {mu}*}, the compositeness energy scale {Lambda}, and the gauge coupling factor f. No signal above the standard model expectation is observed in the {mu}{gamma} mass spectrum. In the contact interaction model, they exclude 107 < M{sub {mu}*} < 853 GeV/c{sup 2} for {Lambda} = M{sub {mu}*}; in the gauge-mediated model, they exclude 100 < M{sub {mu}*} < 410 GeV/c{sup 2} for f/{Lambda} = 10{sup -2} GeV{sup -1}. These 95% confidence level exclusions extend previous limits ...

2006-06-01

301

Redox reactions of Cu(II)-amine complexes in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

A number of amines can be employed for all volatile treatment (AVT) of steam generator (SG) systems of nuclear power reactors. These amines form complexes with Cu{sup 2+} and Ni{sup 2+} ions which come into water due to corrosion. The redox reactions of a number of Cu(II)-AVT amine complexes and the stability of the transient species formed have been studied by pulse radiolysis technique. Rate constants for the reaction of e{sub aq}{sup -} with a number of Cu(II)-amine complexes have been determined by following the decay of e{sub aq}{sup -} absorption. Stability of Cu(I)-amine complexes was studied by following the kinetics of the bleaching signal formed at the {lambda}{sub max} of the Cu(II) amine complex. Except for Cu(I)-triethanolamine complex all other Cu(I)-amine complexes were found to be stable. One-electron oxidation of Cu(II) amine complexes was studied using azidyl radicals for the oxidation reaction as OH radicals react with the ...

2003-03-01

302

Preclinical evidence for the benefits of penile rehabilitation therapy following nerve-sparing radical prostatectomy.  

Science.gov (United States)

Erectile dysfunction following radical prostatectomy remains a frequent problem despite the development of nerve-sparing techniques. This erectile dysfunction is believed to be neurogenic, enhanced by hypoxia-induced structural changes which result in additional veno-occlusive dysfunction. Recently, daily use of intracavernous vasoactive substances and oral use of PDE5-inhibitors have been clinically studied for treatment of postprostatectomy erectile dysfunction. Since these studies showed benefits of "penile rehabilitation therapy," these effects have been studied in a preclinical setting. We reviewed experimental literature on erectile tissue preserving and neuroregenerative treatment strategies, and found that preservation of the erectile tissue by the use of intracavernous nitric oxide donors or vasoactive substances, oral PDE5-inhibitors, and hyperbaric oxygen therapy improved erectile function by antifibrotic effects and preservation of smooth muscle. ...

2008-01-01

303

Measurement of the t anti-t production cross-section at s**(1/2) = 1.96-TeV in the combined lepton+track and e mu channel using 370 pb**-1 of D0 data  

Energy Technology Data Exchange (ETDEWEB)

A measurement of the t{bar t} production cross section at {radical}s = 1.96 TeV in the dilepton final states using a lepton+track selection and secondary vertex b-tagging is presented. One of the two leptons from the decay of the t{bar t} pair is allowed to be identified only as an isolated track to improve the selection efficiency. The result is combined with a measurement in the t{bar t} {yields} e{mu} final state. The measurements are based on 370 pb{sup -1} of data collected with the D0 experiment at the Tevatron collider. The preliminary cross section obtained in the combined lepton+track and e{mu} channel is: {sigma}{sub t{bar t}} = 8.6{sub -1.7}{sup +1.9}(stat) {+-} 1.1(syst) {+-} 0.6(lumi) pb.

2006-05-01

304

Measurement of the dipion mass spectrum in X(3872) ---> J/psi pi+ pi- decays  

Energy Technology Data Exchange (ETDEWEB)

The authors measure the dipion mass spectrum in X(3872) {yields} J/{psi}{pi}{sup +}{pi}{sup -} decays using 360 pb{sup -1} of {bar p}p collisions at {radical}s = 1.96 TeV collected with the CDF II detector. The spectrum is fit with predictions for odd C-parity ({sup 3}S{sub 1}, {sup 1}P{sub 1}, and {sup 3}D{sub J}) charmonia decaying to J/{psi}{pi}{sup +}{pi}{sup -}, as well as event C-parity states in which the pions are from {rho}{sup 0} decay. The latter case also encompasses exotic interpretations, such as a D{sup 0}{bar D}*{sup 0} molecule. Only the {sup 3}S{sub 1} and J/{psi} {rho} hypotheses are compatible with the data. Since {sup 3}S{sub 1} is untenable on other grounds, decay via J/{psi} {rho} is favored, which implies C = +1 for the X(3872). Models for different J/{psi}-{rho} angular momenta L are considered. Flexibility in the models, especially the introduction of {rho}-{omega} interference, enable good descriptions of the data for both L = 0 and 1.

2005-12-01

305

Manufacturing method of metal-hydrogen alkali storage battery. Kinzoku-suiso alkali chikudenchi no seizo hoho  

Energy Technology Data Exchange (ETDEWEB)

This invention is a manufacturing method of a metal-hydrogen alkali battery cell consisting of a positive electrode of metal oxides, alkaline electrolyte solution and a separator containing an amide-radical, wherein the above treating solution is aqueous solution of KOH (or NaOH) which is heated at least at 40 centigrade and the separator is first immersiion-treated and then water-washed and dried. The amide-radical-containing separaator uses a nylon non-woven fabrics. Average molecular weight of nylon 66 is 12,000 - 20,000. In this invention, in order to improve the storage ability and the cycle characteristics which are caused by corrosion of a separator which takes place in the cell after its assembly, the separator is immersed in a hot alkali in order to obtain a non-woven fabric of nylon 66 consisting of alkali-stable high molecular weight portion, which is assembled into a battery. By this, the dissolving of the non-woven fabric and the ...

1989-12-20

306

Local therapies to heal the penis: fact or fiction?  

Science.gov (United States)

Penile rehabilitation has been an area of intense study and debate over the last decade. Interest in this topic was stimulated by the observation that erectile dysfunction remained a significant problem after radical prostatectomy despite meticulous nerve-sparing technique. Smooth muscle alterations and fibrotic changes in the penis were identified as the underlying causes of penile atrophy, veno-occlusive dysfunction, and Peyronie's-like changes that were observed after surgery. Initial observations that intracavernous injection therapies used on a regular basis postoperatively resulted in improvements in the return of spontaneous erectile function led to the development of penile rehabilitation protocols. Chronic dosing of oral type V phosphodiesterase inhibitors is now commonly used by urologists after radical prostatectomy despite a lack of convincing evidence from randomized, placebo-controlled clinical trials. Use of local therapies to ...

2008-11-20

307

Local and regional ozone production: Chemistry and transport  

International Nuclear Information System (INIS)

The EUROTRAC sub-project ''Tropospheric Ozone Research'' (TOR) follows a dual strategy: - Observation of the chemical processes contributing to the oxygen balance directly in the atmosphere; - Establishment of a validated data base for model calculations. Both tasks require simultaneous measurements of a wide range of chemical and meteorological components. In the case of the investigation of the chemical processes, it is also desirable to measure the free radicals directly involved in ozone production. In the project described, a measuring station was set up. For a period of two years and a half, continuous measurements were made of ozone and its chemical precursors (NO, NO_2, NO_y, VOC, CO), as well as other photooxidants (H_2O_2 and organic hydroperoxides, organic nitrates), the photolysis frequency of NO_2, and meteorological parameters (wind, temperature, moisture, aerosols). The station was located on the Schauinsland mountain in the southern Black Forest, at ...

308

IN VACUUM UNDULATOR TASK FORCE REPORT  

Energy Technology Data Exchange (ETDEWEB)

The Green-Chasman lattice, which is the basis for both NSLS storage rings, was conceived with insertion devices in mind. Long, field-free straight sections were provided in the design. The electron optics were chosen so that these sections had zero dispersion and the effects of new magnetic structures placed in these regions would have minimal effect on the emittance of the electron beam. This design concept has been followed by all high-brightness rings which were built subsequent to the NSLS. The X-Ray Ring straight sections also have a very small vertical {beta} function, in addition to the zero dispersion. This was done to optimize the brightness of wiggler sources. There is a further benefit however. The {beta} function determines the beam size and divergence at a particular point in the storage ring lattice. The size is proportional to {radical}{beta} and the divergence is proportional to 1/{radical}{beta}. Thus the electron beam is very ...

1998-06-01

309

Endonuclease IV of Escherichia coli is induced by paraquat  

International Nuclear Information System (INIS)

The addition of paraquat (methyl viologen) to a growing culture of Escherichia coli K-12 led within 1 hr to a 10- to 20-fold increase in the level of endonuclease IV, a DNase for apurinic/apyrimidinic sites. The induction was blocked by chloramphenicol. Increases of 3-fold or more were also seen with plumbagin, menadione, and phenazine methosulfate. H_2O_2 produced no more than a 2-fold increase in endonuclease IV activity. The following agents had no significant effect: streptonigrin, nitrofurantoin, tert-butyl hydroperoxide, #gamma# rays, 260-nm UV radiation, methyl methanesulfonate, mitomycin C, and ascorbate. Paraquat, plumbagin, menadione, and phenazine methosulfate are known to generate superoxide radical anions via redox cycling in vivo. A mutant lacking superoxide dismutase was unusually sensitive to induction by paraquat. In addition, endonuclease IV could be induced by merely growing the mutant in pure O_2. The levels of endonuclease IV in uninduced or ...

310

Development of a methodology to assess organometallic effects on bioenergetic systems  

Energy Technology Data Exchange (ETDEWEB)

A methodology for assessing the impact of subacute concentrations of organometallic agents on bioenergetic and oxidative damage processes in animals, cells and energy transducing subcellular organelles is being developed. Several of the assays are noninvasive and thus lend themselves to human tests. At the whole-animal level we utilize a treadmill chamber where physiological parameters of exercising animals are monitored. These include parameters of whole animals' work performance such as oxygen consumption, carbon dioxide evolution and endurance. Oxidative damage can be monitored in experiments by analyzing expired air of the animals for ethane and n-pentane. These alkanes correlate with lipid peroxidation in vivo. At the cellular and subcellular levels, respiratory activity, lipid peroxidation and free radical species are assayed. Respiratory activity is measured in muscle homogenates and isolated mitochondria using substrates which feed into different ...

1981-06-01

311

Backward pion photoproduction  

Energy Technology Data Exchange (ETDEWEB)

We present a systematic analysis of backward pion photoproduction for the reactions {gamma}p{yields}{pi}{sup 0}p and {gamma}p{yields}{pi}{sup +}n. Regge phenomenology is applied at invariant collision energies above 3GeV in order to fix the reaction amplitude. A comparision with older data on {pi}{sup 0}- and {pi}{sup +}-photoproduction at {theta}=180 indicates that the high-energy limit as given by the Regge calculation could be reached possibly at energies of around {radical}(s){approx_equal}3 GeV. In the energy region of {radical}(s){<=}2.5 GeV, covered by the new measurements of {gamma}p{yields}{pi}{sup 0} p differential cross-sections at large angles at ELSA, JLab, and LEPS, we see no clear signal for a convergence towards the Regge results. The baryon trajectories obtained in our analysis are in good agreement with those given by the spectrum of excited baryons. (orig.)

2009-04-15

312

The full order weak schemes of the Langevin simulations  

Energy Technology Data Exchange (ETDEWEB)

New partial differential equations (PDEs) for the full order weak schemes of the Langevin simulations are formulated. They are solved recursively in full order series solutions with respect to {radical}(t) (the full order weak Taylor schemes). Arbitrariness involved in the solutions is analyzed and clarified in detail. Specific solutions within some orders are presented as examples of the weak Taylor schemes. These PDEs and their solutions will serve for further developments of efficient higher order Runge-Kutta-like schemes. The similar formulation is possible for the imaginary time Hamiltonian evolution kernels as well. (orig.). 9 refs.

1998-04-01

313

Spectral studies of intermediate species formed in one-electron reactions of bovine liver catalase at room and low temperatures. A comparison with peroxidase reactions  

Energy Technology Data Exchange (ETDEWEB)

The reactions of native bovine catalase with superoxide and solvated electrons have been investigated using three different methods for generating these reducing substrates: [gamma]-radiolysis of oxygenated or deaerated buffer solutions in the presence of an OH radical scavenger; either xanthine or acetaldehyde with xanthine oxidase; and low-temperature (77 K) [gamma]-radiolysis of buffered ethylene glycol/water solutions with subsequent annealing of samples at 183 K. (Author).

1992-11-01

314

Refocusing Forties operations engineering  

Energy Technology Data Exchange (ETDEWEB)

Faced with a changing business emphasis, plus the need to reduce operations and maintenance costs in the North Sea, the Forties Field engineering partnership between BP and Brown and Root recognised the need to make radical changes in its organisational structure. An innovative change management programme was planned and executed inside 12 months with the purpose of right-sizing the Forties Operations Engineering team. Not only has the initiative succeeded in cutting costs by 40 per cent; it has also enhanced the quality of engineering support services supplied to the BP Forties platforms. (author)

1996-12-31

315

Radiation therapy in Ewing's sarcoma: an update of the CESS 86 trial  

International Nuclear Information System (INIS)

Purpose: We present an update analysis of the multiinstitutional Ewing's sarcoma study CESS 86. Methods and Materials: From January 1986 through June 1991, 177 patients with localized Ewing's sarcoma of bone, aged 25 years or less, were recruited. Chemotherapy consisted of four 9-week courses of vincristine, actinomycin D, cyclophosphamide, and adriamycin (VACA) in low-risk tumors (extremity tumors =# 100 cm"3). Local therapy was an individual decision in each patient and was either radical surgery (amputation, wide resection) or resection plus postoperative irradiation with 45 Gy or definitive radiotherapy with 60 Gy (45 Gy plus boost). Irradiated patients were randomized concerning the type of fractionation in either conventional fractionation (once daily 1.8-2.0 Gy, break of chemotherapy) or hyperfractionated split-course irradiation simultaneously with the VACA/VAIA chemotherapy (twice daily 1.6 Gy, break of 12 days after 22.4 Gy and 44.8 Gy, total dose and ...

1995-07-15

316

Personality disorders and biosocial trait theories: The argument for radical legal reform.  

Science.gov (United States)

This article reviews antisocial personality disorder, psychopathy, and violence and develops a three factor model of personality traits. Then a discussion of related personality disorders precedes the development of a categorical two factor model of impulsive versus remorseless violence. A paradigm of proactive, medical, and school based early intervention and prevention is advocated as a useful addition to the reactive detention of criminal justice. Integration of psychological tests, neuroimaging, and genomic data in early childhood and school based intervention strategies to prevent the development of conduct disorder and attenuate criminal propensity inform this approach. PMID:20422651

317

Non-nitro radiation sensitizers  

International Nuclear Information System (INIS)

This short communication aims to update the review of non-nitro radiation sensitizers (Shenoy and Singh 1985) and correct omissions. Work is mentioned and bibliography given for studied of cis-platinum, potassium permanganate, cobalt hexammine, sodium bromide, dimethylsulphoxide, zinc and copper ions, organic nitroxyl free radicals (TAN,TMPN and NPPN + PNAP), halogenated pyrimidines, organic and inorganic iodine containing compounds, diacetyl, acetone and acetophenone, rho-hydrobenzoic acid and its esters, pentobarbitone and secobarbitone, heparin and 9-anilinoacridines, dehydropiandosterone and paraquat. (U.K.).

318

Nanoporous materials can be made stiffer than non-porous counterparts by surface modification  

Energy Technology Data Exchange (ETDEWEB)

Nano-materials in which a large fraction of atoms resides within a few atomic layers near the surface can be designed to have novel properties by manipulating their surface parameters. We show that the effective elastic constants of nano-porous/cellular materials can be made to exceed those of the parent materials provided the pore surface elastic parameters satisfy certain conditions. These stiff nano-porous materials herald a radical breakthrough in sandwich-type construction.

2006-06-15

319

Nanoporous materials can be made stiffer than non-porous counterparts by surface modification  

International Nuclear Information System (INIS)

Nano-materials in which a large fraction of atoms resides within a few atomic layers near the surface can be designed to have novel properties by manipulating their surface parameters. We show that the effective elastic constants of nano-porous/cellular materials can be made to exceed those of the parent materials provided the pore surface elastic parameters satisfy certain conditions. These stiff nano-porous materials herald a radical breakthrough in sandwich-type construction.

2006-06-01

320

Fractal dimensionality of polymer networks formed by photopolymerization in a liquid crystal medium  

Energy Technology Data Exchange (ETDEWEB)

Fractal dimensional analysis was employed to obtain a quantitative measure of the morphology of polymer networks formed by UV irradiation induced polymerization of photo-reactive mesogenic monomers dissolved in a liquid crystal host medium. The fractal dimensions obtained, may be interpreted by polymer network growth following a percolation-like model for monomer concentrations well below the solubility limit. On passing the solubility limit, the polymerization process changes from a (radical chain) solution polymerization to a dispersion polymerization, with fractal dimensions decreasing and suggesting a cluster-cluster aggregation process for monomer concentrations above the solubility limit, similar to the aggregation of colloidal particles.

2002-10-21

321

Effect of Cl substituent in the aromatic tetracycline ring on its reactivity with solvated electrons  

Energy Technology Data Exchange (ETDEWEB)

Decomposition yields of tetracycline hydrochloride (TC.HCl) and chlorotetracycline hydrochloride (ClTC.HCl) in methanol solution saturated with Ar or N/sub 2/O were determined. Rate constants of the reaction esub(s)/sup -/ with some antibiotics were obtained. It was demonstrated by /sup 1/H NMR that the radical formed by degradation of 7-C-Cl group is recombined with the H atoms leading to ClTC.HCl being converted into tetracycline hydrochloride (TC.HCl).

1984-09-18

322

Cosmic no-hair theorem in power-law inflation  

Energy Technology Data Exchange (ETDEWEB)

We prove a cosmic no-hair theorem for Bianchi models in power-law inflation. Provided that the potential of an inflaton {phi} is exp({minus}{lambda}{kappa}{phi}) with 0{le}{lambda}{lt} {radical}2/3 , we find that the isotropic power-law solution is the unique attractor for any initially expanding Bianchi-type models except type IX. For Bianchi type IX, this conclusion is also true if the initial ratio of the vacuum energy to the maximum three-curvature is larger than one half.

1992-02-15

323

A new technique for production of yellow cake with double precipitation  

International Nuclear Information System (INIS)

The author presents a new technique for production of yellow cake with double precipitation, thus solving a series of problems for precipitating uranium with traditional double precipitation. The new technique can not only remove ferric ions and sulfate radicals but also make solid-liquid separation easy, utilize effectively the sulfuric acid produced in ferric ions precipitation process, and increase uranium concentration of leaching liquor. To take it as producing yellow cake will save investment, simplify operation, and cut down the consumption of raw materials and energies. It is more competitive than ion-exchange or solvent extraction in the process of extracting-purifying and preparing yellow cake.

1997-01-01

324

Thermal gradient humidification-dehumidification desalination system  

Energy Technology Data Exchange (ETDEWEB)

A solar energy desalination process utilizing solar radiation directly for the evaporation of salt water is described. Ambient air takes on water vapor as the air passes through an evaporative medium. It is then directed between a saline water-covered, solar absorbing surface and a solar collecting housing. The resulting heated and moisture-saturated air is cooled in a heat exchange means where condensation of fresh water occurs. Simultaneously, cool salt water is utilized as the cooling water in the heat exchange means, and takes on the heat of condensation given up by the condensing vapor. The heated salt water from the heat exchange means is partially directed over the solar absorbing surface, and at least a portion of it is also directed to wet the evaporative medium. Several optional sub-processes are described for operation of the system during periods of reduced insolation, and an alternative process is described for operation of the ...

1982-12-14

325

Tertiary-Butanol: A toxicological review  

British Library Electronic Table of Contents (United Kingdom)

Tert-Butanol is an important intermediate in industrial chemical synthesis, particularly of fuel oxygenates. Human exposure to tert-butanol may occur following fuel oxygenate metabolism or biodegradation. It is poorly absorbed through skin, but is rapidly absorbed upon inhalation or ingestion and distributed to tissues throughout the body. Elimination from blood is slower and the half-life increases with dose. It is largely metabolised by oxidation via 2-methyl-1,2-propanediol to 2-hydroxyisobutyrate, the dominant urinary metabolites. Conjugations also occur and acetone may be found in urine at high doses. The single-dose systemic toxicity of tert-butanol is low, but it is irritant to skin and eyes; high oral doses produce ataxia and hypoactivity and repeated exposure can induce dependence...

2010-01-01

326

Labelling of "1"4C-M-ISP and its absorption, translocation and distribution in peanut and soybean seedling  

International Nuclear Information System (INIS)

Labelling of "1"4C-M-ISP and its absorption, translocation and distribution in peanut and soybean seedling were studied. The results of experiments showed that the radioactive substance could be translocated in xylem and phloem of two kinds of plants. The root of peanut seedling absorbed "1"4C-M-ISP from the nutrient solution more strong than the root of soybean seedling did. After leaf treatment with "1"4C-M-ISP, the soybean seedling absorbed more radioactive substance than peanut seedling did. But the translocation's speed of radioactive substance in pnloem of two kinds of plants were similar.

1990-01-01

327

Glass-heat-pipe evacuated-tube solar collector  

Science.gov (United States)

A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

1981-08-06

328

Flux enhancement options for an LEU-fueled MIT reactor  

International Nuclear Information System (INIS)

The Monte-Carlo transport code MCNP was used to evaluate possible arrangements of cores for the MIT Reactor using monolithic LEU fuel. Plate and moderator thicknesses were varied, and fixed absorbers and inner reflectors added in an effort to maximize available neutron fluxes at in-core and ex-core locations of experimental facilities. Addition of D_2O in the H_2O moderator was also evaluated. Comparisons of the fast, epithermal, and thermal fluxes were made at selected locations. Keff was also evaluated and critical blade heights compared with the existing HEU core. Results indicate that the LEU fluxes could approach HEU values with the use of a fueled in-core experimental facility, a fixed boron absorber spider and an inner beryllium reflector. (author)

2004-11-07

329

Enhanced carbon dioxide removal by promoted hot potassium carbonate in a split-flow absorber  

Energy Technology Data Exchange (ETDEWEB)

In this work, a comprehensive model has been developed for the absorption of carbon dioxide into promoted hot potassium carbonate solution. The model, which is based on penetration theory, incorporates an extensive set of important reactions and takes into account the coupling between mass transfer and chemical kinetics. The penetration theory provides an appropriate absorption rate and enhancement factor for the chemical absorption. Operating data for carbon dioxide absorption into DEA-hot potassium carbonate solution has been compared with model predictions. The impact of parameters such inlet temperature of lean solution, promoter concentration, liquid split fraction, hot feed location and type of promoter on the performance of a split-flow absorber have been examined. The use of other promoters is an efficient way to enhance the carbon dioxide absorption, which has been discussed in this paper.

2004-07-01

330

Dosimetry of iodine-123 iomazenil in humans  

International Nuclear Information System (INIS)

The distribution of the central benzodiazepine receptor specific ligand iodine-123 iomazenil was investigated in seven human adults from whole-body scans, blood samples and urine collected up to 24 h after injection. Using 12 source organs, the MIRD method was applied to calculate the absorbed radiation dose of the radioligand in various organs. The urinary bladder wall (0.15 mGy/MBq), lower large intestinal wall (0.071 mGy/MBq) testes (0.044 mGy/MBq) and upper large intestined wall (0.038 mGy/MBq) received the highest absorbed doses. The average effective dose equivalent of "1"2"3I-IBZM for adults was estimated to be 0.033 mSv/MBq. (orig.).

331

Combined radiation and convection in absorbing, emitting, nongray gas-particulate tube flow  

Energy Technology Data Exchange (ETDEWEB)

The interaction of thermal radiation with conduction and convection in thermally developing absorbing, emitting, nongray gas-particulate turbulent suspension flow through a circular tube is investigated. The contribution of thermal radiation is obtained through evaluation of the total hemispherical emittance of the particulate cloud and through evaluation of single band absorptances for molecular gases, modified to account for the interaction with the particles. The governing differential equation is derived as a (nonlinear) energy equation, coupled with integral equations to find the thermal radiation contributions. The energy equation is solved numerically by an implicit finite difference method with an iterative procedure. Qualitative results for Nusselt numbers are shown for a variety and range of parameters, such as optical thickness of particulates and single molecular gas bands, relative gas band position and band width, and temperature ratios (heated as ...

1987-05-01

332

Combined radiation and convection in absorbing, emitting, non-Gray gas-particulate tube flow  

Energy Technology Data Exchange (ETDEWEB)

The interaction of thermal radiation with conduction and convection in thermally developing absorbing, emitting, non-gray gas particulate turbulent suspension flow through a circular tube is investigated. The contribution of thermal radiation is obtained through evaluation of the total hemispherical emittance of the particulate cloud and through evaluation of single band absorptances for molecular gases, modified to account for the interaction with the particles. The governing differential equation is derived as a (nonlinear) energy equation, coupled with integral equations to find the thermal radiation contributions. The energy equation is solved numerically by an implicit finite difference with its iterative procedure. Qualitative results for Nusselt numbers are shown for a variety and range of parameters, such as optical thickness of particulates and single molecular gas bands, relative gas band position and band width, and temperature ratios (heated as well as ...

1985-01-01

333

Coloring of cultured pearls by gamma-rays irradiation  

International Nuclear Information System (INIS)

Changing cream pearls into bluish-grey by #gamma# ray irradiation is a technique in coloring of pearls. Irradiated pearls are similar in color to cultured blue pearls. The pearl layers hardly change their color but the nuclei change into dark brown by irradiation. Visible light (500 - 700 nm) penetrating the pearl layer is absorbed by dark brown nucleus. The intensity of reflecting light between 400 and 500 nm at pearl surface, therefore, becomes stronger than that between 500 and 700 nm; therefore color of irradiated pearls look bluish-grey. The density of bluish-grey color increases with increasing absorbed doses, but their luster at surface diminishes owing to the deterioration of the pearl layer by prolonged irradiation; high doses irradiation should be avoided. Irradiated pearls show no substantial fading of their color in a year and the rate of the fading is found to be lower than that for cultured blue pearls. (author).

334

Chatter resistance of non-uniform turning bars with attached dynamic absorbers—Analytical approach  

British Library Electronic Table of Contents (United Kingdom)

Forced harmonic vibration of a non-uniform elastic beam with attached dynamic vibration absorbers (DVA) is studied. Analytical approximation of the solution is obtained by the functional perturbation method (FPM). The problem has application to cutting tools operations where the resistance of the tool holder against regenerative chatter can be enhanced by optimizing the real part of the frequency response function (FRF). A test case of a beam with step-like heterogeneity and single DVA at the tip shows that the FPM solution is very accurate for up to ?40 percent deviation in both stiffness and mass density. Using the analytical results and Sims approach, optimal DVA tuning is found for each set of beam heterogeneity parameters by solving a set of nonlinear algebraic equations numer...

2010-01-01

335

Alpha-particle dose distribution effects at the cellular level  

International Nuclear Information System (INIS)

Ionizing radiations that differ in number, size, and distribution of energy deposition events might be expected to cause different effects for the same absorbed dose. Furthermore, microdosimetry calculations suggest that large variations in biological effectiveness might be expected for internally deposited alpha-emitting radionuclides for the same absorbed dose, depending upon the specific activity and spatial distribution of the sources in tissue. The study described in this article was designed to demonstrate these phenomena in vitro. Cultured Chinese hamster ovary (CHO-K1 BH4) cells were exposed in vitro to inert, insoluble ceramic microspheres in zirconium dioxide labeled with "2"3"9Pu. The average exit energy of the 5.15 MeV alpha particle was calculated to be 4.3 MeV. Exposure times varied from four to seven hours to achieve the desired dose level.

1985-02-01

336

Absorption of carbonyl sulfide in aqueous methyldiethanolamine  

Energy Technology Data Exchange (ETDEWEB)

The absorption of carbonyl sulfide in aqueous methyldiethanolamine (MDEA) was studied over a range of temperatures and MDEA concentrations. MDEA is commonly used for selective absorption of hydrogen sulfide in the presence of carbon dioxide. However, sulfur in the form of COS may also be present and it is necessary that estimates of absorption rates of this compound be made. The objective of this study is to determine the physiochemical properties needed to predict COS absorption rates in aqueous MDEA. Free gas solubility and the diffusivity of COS in MDEA solutions were measured over the temperature range 15 to 40{sup 0}C for MDEA concentrations up to 30 weight per cent using the nitrous oxide analogy method. Solubilities were measured volumetrically in an equilibrium cell and diffusivities were measured using a laminar liquid jet absorber. The kinetics of the reaction between COS and MDEA were studied by measuring absorption rates in a single wetted-sphere ...

1988-01-01

337

{gamma}{gamma} Cross-sections and {gamma}{gamma} colliders  

Energy Technology Data Exchange (ETDEWEB)

We summarize the predictions of different models for total {gamma}{gamma} cross-sections. The experimentally observed rise of {sigma}{sub {gamma}}{sub {gamma}} with s radical {sub {gamma}}{sub {gamma}}, faster than that for {sigma}{sub p-barp}, {sigma}{sub {gamma}}{sub p} is in agreement with the predictions of the Eikonalized Minijet Models as opposed to those of the Regge-Pomeron models. We then show that a measurement of {sigma}{sub {gamma}}{sub {gamma}} with an accuracy of < or approx. 8-9% (6-7%) is necessary to distinguish among different Regge-Pomeron type models (the different parameterisations of the EMM models) and a precision of < or approx. 20% is required to distinguish the predictions of the EMMs and of those models which treat 'photon like a proton', for the energy range 300< s radical{sub {gamma}}{sub {gamma}} <500 GeV. We further show that the difference in model predictions for ...

2001-10-11

338

Some relationships between ultraviolet light and heme-protein-induced peroxidative lipid breakdown in liposomes, as reflected by fluorescence changes: the effect of negative surface charge  

International Nuclear Information System (INIS)

The water soluble, photolabile nitrene precursor, azidonaphthalene-2,7-disulfonic acid (ANDS) was encapsulated in small unilamellar, isoelectric (egg PC) or negatively charged (egg PC + dihexadecylphosphate) liposomes. The individual and combined effects of heme-proteins and UV irradiation on the fluorescence of these vesicles under aerobic conditions were studied. Consistent with the catalytic action of heme-proteins on lipid peroxidation and peroxide decomposition, addition of cytochrome c (positively charged) or catalase (negatively charged) to the vesicles elicited immediate formation of a fluorescence band at 470 nm, characteristic of Schiff bases that form from aldehyde byproducts of decomposing hydroperoxides. Ultraviolet irradiation of liposomes caused no significant changes in the fluorescence spectrum, in spite of the radiolysis of ANDS inside the vesicles with consequent formation of nitrene radicals. When isoelectric vesicles were irradiated with UV ...

339

Solid state electrochemistry and spectroelectrochemistry of poly(arylene bisimide-alt-oligoether)s  

International Nuclear Information System (INIS)

Two electroactive polymeric arylene bisimides, namely poly[(4,7,10-trioxatrideca-1,13-diyl)-(1,4,5,8-naphthalenetetracarboxylic bisimide-N,N'-diyl)] and its perylene analogue - poly[(4,7,10-trioxatrideca-1,13-diyl)-(3,4,9,10-perylenetetracarboxylic bisimide-N,N'-diyl)] have been synthesized and studied by cyclic voltammetry, UV-vis-NIR as well as Raman spectroeletrochemistry. Contrary to low molecular weight arylene bisimides, which show a clear two electron, double-step electrochemical reduction (neutral form to radical anion and from radical anion to dianion), in the synthesized polymers multielectron transfers are observed, accompanied with a strong electrochromic effect. However, as probed by cyclic voltammetry, their first reduction step is retarded and covers a wider potential range. We attribute this effect to macromolecular nature of the compounds being reduced and their structural inhomogeneity caused by ?-stacking induced ...

2011-04-01

340

Rate and mechanism of the atmospheric degradation of 2 H-heptafluoropropane (HFC-227)  

Energy Technology Data Exchange (ETDEWEB)

The atmospheric chemical behaviour of 2H-Heptafluoropropane (CF[sub 3]CHFCF[sub 3], HFC-227) with respect to its rate and mechanism of degradation in the troposphere has been investigated. The rate coefficient for the reaction of HFC-227 with OH radicals has been determined in direct time resolved experiments using a combination of laser-pulse initiation and LIF. In the temperature range T=298-463 K the Arrhenius expression k(T)=(3.8[+-]0.8) 10[sup -13] exp(-1596[+-]77 K/T) cm[sup 3]/s, which corresponds to k (298 K) = (1.8[+-]0.3) 10[sup -15] cm[sup 3]/s, was found. The mechanism of the atmospheric degradation of HFC-227 has been investigated using both, laser-pulse initiated/time resolved and UV photolysis/FTIR product studies. It is concluded that the major carbonyl products are CF[sub 3]COF and CF[sub 2]O which result from the decomposition of the oxy radical CF[sub 3]CF(O)CF[sub 3] by C-C bound fission. The rate coefficient for this ...

1994-02-01

341

Radiotherapy versus surgery in good-risk Ewing's sarcoma. An analysis of the CESS 86-data  

International Nuclear Information System (INIS)

The evaluation of radiotherapy and surgery as exclusive local treatment in comparably selected subgroups of patients with Ewing's sarcoma on the basis of the CESS 86-data. In the German multicenter Ewing's sarcoma study CESS 86, treatment consisted for four 9-week-courses of VACA- or VAIA-chemotherapy plus local therapy. VACA (vincristine, actinomycin D, cyclophosphamide, adriamycin) was given in low-risk extremity tumors with a tumor volume below 100 cm"3. Highrisk patients with central lesions or a tumor volume >100 m"3 received VAIA (ifosfamide instead of cyclophosphamide). Local therapy started after one complete chemotherapy course in week 10. Based on an individual decision in each patient, local therapy was either radical surgery or resection plus postoperative irradiation with 45 Gy or definitive radiotherapy with 60 Gy. Because of poor results with radiotherapy in a preceeding study, it was intended to restrict irradiation to patients with small ...

342

Pulse radiolysis of aqueous solutions of tetraphenylphosphonium ions  

International Nuclear Information System (INIS)

The reactions of tetraphenylphosphonium ion (Ar_4P"+) with esub(aq)"-, H atoms and OH radicals have been investigated. The absorption spectra of three transient species were obtained. Ar_4Psup(.) radicals formed by the reaction: Ar_4P"+ + esub(aq)"- #-># Ar_4Psup(.) have a maximum absorption at 305 nm [epsilon _3_0_5 = (9400 +- 300)dm"3mol"-"1cm"-"1] and decays by second-order kinetics with the rate constant 2k = (2.7 +- 0.4) x 10"9dm"3mol"-"1s"-"1. H atoms and OH radicals form transient adducts to the phenyl groups of the Ar_4P"+ ion with the rate constants of (1.5 +- 0.3) x 10"9 dm"3mol"-"1s"-"1 and (3.0 +- 0.3) x 10"9dm"3mol"-"1s"-"1, respectively. Both adducts have broad absorption spectra at 300 approximately 380 nm (lambdasub(max) = 340 nm) with the molar extinction coefficients epsilonsub(340) = 5400 +- 300 dm"3mol"-"1cm"-"1 for the H adduct and epsilonsub(340) = 3500 +- 200 dm"3mol"-"1cm"-"1 for the OH adduct. ...

1976-01-01

343

Products of the Benzene + O(3P) Reaction  

Science.gov (United States)

The gas-phase reaction of benzene with O(3P) is of considerable interest for modeling of aromatic oxidation, and also because there exist fundamental questions concerning the prominence of intersystem crossing in the reaction. While its overall rate constant has been studied extensively, there are still significant uncertainties in the product distribution. The reaction proceeds mainly through the addition of the O atom to benzene, forming an initial triplet diradical adduct, which can either dissociate to form the phenoxy radical and H atom, or undergo intersystem crossing onto a singlet surface, followed by a multiplicity of internal isomerizations, leading to several possible reaction products. In this work, we examined the product branching ratios of the reaction between benzene and O(3P) over the temperature range of 300 to 1000 K and pressure range of 1 to 10 Torr. The reactions were initiated by pulsed-laser photolysis of NO2 in the presence of benzene and ...

2009-12-21

344

Effects of. gamma. -irradiation on isolated rat liver mitochondria  

Energy Technology Data Exchange (ETDEWEB)

Gamma-irradiation of isolated rat liver mitochondria with up to 475 Gy leading to hydrated electrons (G = 1.9, corrected for reaction with solutes), 30 Gy leading to carbohydrate radicals, (G = 5.6), 100 Gy leading to superoxide radicals (G = 6.2), and 130 Gy leading to formate radicals (G = 6.2) showed no effects on the rate of oxygen uptake in various respiratory states, the respiratory control ratio, or the adenosine diphosphate to atomic oxygen ratio. Typical values were 0.020-0.100 nmol O/sub 2/ s/sup -1/ mg protein/sup -1/ for State 1 respiration, 0.25-0.33 nmol O/sub 2/ s/sup -1/ mg protein/sup -1/ for State 4 respiration and 0.65-1.10 nmol O/sub 2/ s/sup -1/ mg protein/sup -1/ for State 3 respiration. Typical respiratory control ratios ranged from 2.0-3.5 for succinate and 4.0-6.5 for a 1:1 glutamate: malate substrate mixture. Adenosine diphosphate to atomic oxygen ratios with succinate as substrate varied from 1.6 ...

1987-01-01

345

A study on the development of hypo-stoichiometric Zr-based hydrogen storage alloys with ultra-high capacity for anode material of Ni/MH secondary battery  

Energy Technology Data Exchange (ETDEWEB)

Some hypo-stoichiometric Zr-based Laves phase alloys were prepared and studied from a viewpoint of discharge capacity for electrochemical application. After careful alloy design of ZrMn{sub 2}-based hydrogen storage alloys through changing their stoichiometry while substituting or adding some alloying elements, the Zr(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} alloy reveals relatively good properties with regard to hydrogen storage capacity, hydrogen equilibrium pressure and electrochemical discharge capacity. In order to improve the discharge capacity and rate-capability, Zr is partially replaced by Ti. The discharge capacity of Zr{sub 1-x}Ti{sub x}(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} (x=0.0, 0.2, 0.3, 0.4, 0.6) alloy electrodes at 30 C reaches a maximum value and decreases as the Ti fraction increases. In view of electrochemical and thermodynamic characteristics, the ...

2000-08-10

346

White oils for high voltage cables  

Energy Technology Data Exchange (ETDEWEB)

S-120 white oils are used to impregnate insulation and fill high voltage wires. Cooling oil flows of specified viscosities can increase the load capacity of wires. White oils are studied for viscosities and dielectric properties. To meet requirements, S-220 type oils of different medium or low viscosities are tested. Capacity can be increased by viscosity adjustment. Tests were also made to select optimum stabilizing additives to keep low-viscosity.

1983-05-01

347

Upper bounds of fissile fuel yield with fusion breeders  

Science.gov (United States)

The maximum fissile fuel production capacity of three conceptual fusion breeder systems is examined on the basis of the dominant isotopic-balance processes. Compact relationships involving system power output, plasma and energy multiplication, and parameters which describe the fuel cycle and neutron spectrum in the blanket are established. It is found that the fusion breeder, as characterized herein, possesses a substantial fissile fuel breeding capacity the extent of which is governed primarily by the neutron spectrum in the conversion blanket and the break-even condition of the plasma.

1976-08-01

348

Topological modeling of the reactive capacity and biological activity of some amino-polysaccharides  

British Library Electronic Table of Contents (United Kingdom)

The work is devoted to a microscopic analysis of the reactive capacity of chitin. An algorithm for modeling the deacetylation reaction in a monomeric unit of chitin is described. The reaction coordinate and the potential energy surface topography are determined taking into account the electron-vibrational interaction and low-symmetry perturbations within Jahn-Teller theory. Based on this algorithm, the topological modeling of the deacetylation process is performed for the first time and a mechanism of the biological activity of chitosan is proposed.

2011-01-01

349

Method of preparation of crystal borophosphate with zeolite structure. Sposob polucheniya kristallicheskogo borofosfata tseolitnoj struktury  

Energy Technology Data Exchange (ETDEWEB)

Hydrothermal method for preparing crystal borophosphate with zeolite structure is suggested. To increase absorption capacity and thermal stability of final product, aluminium hydroxide sol, ethylenediamine and ethyl acetate are added to the mixture of crystal boric and concentrated phosphoric acids. Thermal stability of the specimens prepared constitutes 880-950 deg, water absorption capacity is within the limits of 0.30-0.32 cmT/g. 1 table.

1984-12-24

350

Methane fermentation of agricultural wastes and domestic animal's wastes  

Energy Technology Data Exchange (ETDEWEB)

Cattle and pig wastes, orange peels, compost, and grain husks were hydrolyzed in an alkaline medium to investigate the CH4 generation capacity. The respective CH4 production capacities from pig wastes and rice hulls were approximately 1 and approximately 0.1 L/g. The CH4 produced can be used to supplement energy requirements of farms.

1981-01-01

351

Maintenance viewpoint of a successful reactor program  

International Nuclear Information System (INIS)

As the Operating and Support staffs of the FFTF organization have gained experience, the plant reliability and capacity factors have shown a steadily improving trend. The plant capacity factor for Cycle 4 was 99.5%. It is the purpose of this report to describe the evolution of the maintenance organization at the FFTF site from a general support organization to a technically proficient organization playing a major role in planning and performance of plant maintenance evolutions.

1984-06-03

352

Heat capacity of VT1-0 commercial titanium and VT5 and VT5-1 titanium base alloys at low temperature  

International Nuclear Information System (INIS)

The temperature dependences of the heat capacity of commercial titanium VT1-0 and alloys on its base, VT5 and VT5-1, have been derived in the temperature range of 4 to 290 K. For comparison, similar measurements have been conducted on pure titanium and specially prepared solid solutions on its base (Ti+3.7 at.% Al and Ti+0.82 at.% Sn). The measurement accuracy has been sufficient for comparing the results with calculation data. The obtained results are interpreted using the known concepts of the role of the mass of interstitial atoms and changes in the interatomic bond forces. It is shown that the phonon components of the molar heat capacities of solid solutions of Al in titanium have lower values in the entire temperature range, as compared to titanium. The corresponding differences are proportional to the Al concentrations. The lower molar heat capacity in the case of dissolution of Al is due to the low mass of the ...

1978-01-01

353

Flow control with variable inflow as an alternative to conventional nozzle group control - automatic control of large capacity steam turbines  

International Nuclear Information System (INIS)

In the case of large capacity steam turbines the conventional nozzle group control is, for mechanical and thermodynamic reasons, diminishing more and more in importance in favour of variable pressure control. A design for constant-pressure operation as an alternative to nozzle group control is described; this demonstrates a series of important advantages compared with the latter. (orig.).

354

Contribution of surface rayleigh waves to the heat capacity of poly(vinyl chloride)  

British Library Electronic Table of Contents (United Kingdom)

The method of surface acoustic waves is employed to determine the frequency and temperature dependences of the molar heat capacity of poly(vinyl chloride) on the contribution of Rayleigh local components of the longitudinal and transverse vibrations of structural units of the polymer. The calculated and experimental data are compared in terms of their dependence on the relaxation state of the system.

2009-01-01

355

Capacity analysis techniques for signalized intersections  

Energy Technology Data Exchange (ETDEWEB)

This book contains nomographs for analysis and design of signalized intersections and thoroughly explains how to use them. The nomographs simplify and reduce the work that otherwise would have to be done by hand. The nomograph method for computing capacity has a significant advantage over computerized methods: it provides insight into the interaction between the various factors in the solution process for design analysis.

1986-01-01

356

The Power Industry Reform and the lesson from California Situation  

Energy Technology Data Exchange (ETDEWEB)

What kind of lesson do we get from California situation? The first is that the sufficient investment to the operational regulation should be prepared as a system. It is necessary to introduce the systems related to capacity, such as the capacity market system that makes retail suppliers secure the fixed rate of their running peak-load as reserve capacity and other system that secure the 5-year supply capacity by a contract, in which suppliers can pay the penalty if they purchase more capacity than in the contract. The second is that the supplementary measures should be systematized for the supply system not to be in a panic in a case of the shortage situation of equipment. The exchange authority should control the regular inspection program on generators to reduce the market control of the supply companies. Through the supplementary system, the increase of electricity price must ...

2001-03-01

357

Studies on the biosorption of uranium by a thermotolerant, ethanol-producing strain of Kluyveromyces marxianus  

Energy Technology Data Exchange (ETDEWEB)

The ability of residual biomass from the thermotolerant ethanol-producing yeast strain Kluyveromyces marxianus IMB3 to function as a biosorbent for uranium has been examined. It was found that the biomass had an observed maximum biosorption capacity of 120 mg U/g dry weight of biomass. The calculated value for the biosorption maximum, obtained by fitting the data to the Langmuir model was found to be 130 mg U/g dry weight biomass. Maximum biosorption capacities were examined at a number of temperatures and both the observed and calculated values obtained for those capacities increased with increasing temperature. Decreasing the pH of the biosorbate solution resulted in a decrease in uptake capacity. When biosorption reactions were carried out using sea-water as the diluent it was found that the maximum biosorption capacity of the biomass increased significantly. Using transmission ...

1997-06-01

358

Calculation of the transmission capacity of long-distance EHV single-core submarine cable systems  

Energy Technology Data Exchange (ETDEWEB)

A general calculation method for the analysis of transmission capability of a long-distance single-core ac submarine cable system is presented. The method is based on modal transformation of voltages and currents in multiconductor cable systems. Using this method, numerical calculations on 500 kV submarine cable systems have been performed with particular reference to the effect of the distance between bonds connecting metallic sheath, outer conductor and armor on the transmission capacity of the system. It was clarified that the transmission capacity of the system increased with decreasing bond intervals. Examination of the current distributions between various conductors along the length showed that this increase of transmission capacity was mainly due to the dispersion of the charging current into the metallic sheath, outer conductor and armoring at the bonding points. Analytical results for the transmission ...

1981-11-01

359

TRIGA reactor spent fuel pool under severe earthquake conditions  

International Nuclear Information System (INIS)

Supplemental criticality safety analysis of a pool type storage for TRIGA spent fuel at 'Jozef Stefan' Institute in Ljubljana, Slovenia, is presented. Previous results (Ravnik, M, Glumac, B., 1996) have shown that subcriticality is not guaranteed for some postulated accidents. To mitigate this deficiency, a study was made about replacing a certain number of fuel elements in the rack with absorber rods (Glumac, B., Ravnik, M., Logar, M., 1997) to lower the supercriticality probability, when the pitch is decreased to contact (as a consequence of a severe earthquake) in a square arrangement. The criticality analysis for the hexagonal contact pitch is presented in this paper, following the same scenario as outlined above. The Monte Carlo computer code MCNP4B with ENDF-B/VI library and detailed three dimensional geometry was used. First, the analysis about the influence of the number of triangular fuel piles on the bottom that could appear, if the fuel rack, made of ...

1998-07-01

360

Scattered radiation effect on the defect image in high-energy bremsstrahlung introscopy  

International Nuclear Information System (INIS)

Results of the evaluation of the scattered radiation effect on the image of defects in examined products are given. The formula is suggested which characterizes the image of defects on a scintillation screen as well as accumulation factors are calculated by the Monte-Carlo method. Values of fluctuations of absorbed energy in the screen used for the evaluation of sensitivity are experimentally obtained. The effect of high-energy bremsstrahlung on the defect detection is analyzed.

361

Release of oxidized plastocyanin from photosystem I limits electron transfer between photosystem I and cytochrome b6f complex in vivo  

UK PubMed Central (United Kingdom)

We used fast absorbance spectroscopy to investigate in vivo binding dynamics and electron transfer between plastocyanin (pc) and photosystem I (PSI), and cytochrome (cyt) f...Full Text Available

2005-05-10

362

Relationships of Quality Characteristics with Size Exclusion HPLC Chromatogram of Protein Extract in Soft-White Winter Wheats.  

Science.gov (United States)

This study investigated relationships between molecular weight distributions of unreduced grain proteins and grain, flour, and end-use quality characteristics of soft white winter wheats grown in Oregon. Absorbance area and area % values of protein fractions separated by size exclusion HPLC (SE-HPL...

363

Redundancy of the off-shell parameters in chiral effective field theory with explicit spin-3/2 degrees of freedom  

Energy Technology Data Exchange (ETDEWEB)

In this note we prove to all orders in the small scale expansion that all off-shell parameters which appear in the chiral effective Lagrangian with explicit DELTA(1232) isobar degrees of freedom can be absorbed into redefinitions of certain low-energy constants and are therefore redundant.

2010-01-18

364

Pyrheliometry  

Energy Technology Data Exchange (ETDEWEB)

Pyrheliometric methods are described (particularly methods for measuring the solar constant), and theoretical and experimental studies in this field are surveyed and systematized. Particular attention is given to the analysis of instruments intended for pyrheliometers used as standards, reference instruments, and solar-constant meters is examined, and consideration is given to methods for determining the thermal-radiation properties of absorbing coatings and methods for calculating the absorption coefficients of cavity receivers.

1981-01-01

365

Principles of the coprecipitation of thorium and yttrium with organicinorganic salts of molybdenum polyacids  

Energy Technology Data Exchange (ETDEWEB)

This paper advances hypotheses on the chemistry of the interaction of thorium and yttrium with organic-inorganic salts of molybdenum polyacids. On the basis of an analysis of the data of an adsorption experiment and the quantitative relationships that follow from the law of mass action, it is shown that thorium is absorbed by the solid phase by coprecipitation with the participation of complex formation, while the coprecipitation of yttrium with salts of polyacids is due to a reaction of ion exchange chemisorption.

1986-03-01

366

Oxygen, hydrogen, and deuterium effects on plasma nitriding of metal alloys  

International Nuclear Information System (INIS)

We report the oxygen, hydrogen, and deuterium effects on nitrogen implantation of stainless steel. Oxygen is absorbed on the surface creating a potential barrier and diminishing the nitrogen retention. Deuterium removes more oxygen from the surface than hydrogen, augmenting the nitrogen chemical potential and yielding faster nitrogen diffusion into the bulk material.

2006-04-01

367

NAME=\\  

Wastenet

... Biodegradable plastics have the potential to be used in various flushable sanitary product applications such as sanitary towels, colostomy bags and other absorbent products. In addition, effluent from recycling activities must be treated in wastewater treatment plants and may contain biodegradable plastics. Flushable biodegradable plastics can have an adverse impact on wastewater treatment plants due to the very fast throughputs, typically 4 to 8 hours, from the drain to the plant. This length of time is insufficient for many biodegradable plastics to lose their structure. Such plastics can ...

368

Moored platform structure, in particular for earthquake areas offshore. Bunnforankret plattformkonstruksjon, saerlig for jordskjelvaktive havomraader  

Energy Technology Data Exchange (ETDEWEB)

The invention deals with an offshore drilling or production platform in particular designed for quake-active areas. The platform rests on the sea bed with a low-gravitational weight and anchored to stabilized pile foundations absorbing the horizontal and vertical acting forces from earthquakes. The platform including pillars can be made of different materials, prestressed concrete in particular. 3 figs.

1993-11-29

369

Improvement in loosening equipment  

Energy Technology Data Exchange (ETDEWEB)

The loosening equipment consists of a base machine and four-link suspension mechanism which is a cross frame with loosening gear connected to the base machine by universal hinges. In order to improve the reliability of the machine, the drive of transverse shifting in the cross frame is made of symmetrically arranged, shock-absorbing, hydraulic cylinders which are connected by additional universal hinges to the base machine and the lower pull rods. The design of the loosening machine guarantees its reliable operation on soil with significant quantity of hard inclusions.

1982-01-01

370

Features of laser damage to elastic polymers  

Energy Technology Data Exchange (ETDEWEB)

Threshold pump intensity values leading to irreversible damage to colored laser elements based on elastic polymers were measured. The damage to colored elastomers is connected with absorbing microinclusions but is independent of molecular absorption. It is shown that damage to the elastomers has a pronounced threshold character in contrast to the microdamage accumulation effect in glassy polymers. The damage threshold for elastomers is 1.5 times higher, which is connected with the absence of microstresses (characteristics for organic glasses) in the specimens. 13 references.

1988-03-01

371

Dosimetry in dental radiology. Dentascan spiral CT versus panoramic radiography  

International Nuclear Information System (INIS)

The study compares the doses absorbed by the dentomaxillary area in spiral CT and panoramic examinations. The dose measurements demonstrate that patients receive smaller doses with panoramic radiography than with spiral CT with Dentascan. After following for some variations from instrumental differences, they are in substantial agreement with literature data. Further investigations are needed considering the radiobiological risk related to the growing spread of Dentascan examinations.

1999-05-01

372

Decree of the Ministry of Health about conditions of irradiation of food, permissible additional substances or other food components, which can be subjected to ionizing radiation action, their specification, maximum irradiation doses as well as about requirements for marking and introducing into turnover  

International Nuclear Information System (INIS)

The decree refers to conditions of irradiation of food and its components for radappertization and radurization using gamma radiation from cobalt 60 or cesium 137, X radiation or electron beam up to maximum total medium absorbed dose 10 kGy.

2003-03-04

373

Calculated fluence spectra at neutron therapy facilities  

International Nuclear Information System (INIS)

The Monte Carlo transport codes LAHET and MCNP were used to calculate energy fluence spectra at three neutron therapy facilities. The results compare very favourably with measured data. Kerma spectra and the ratio of ICRU muscle tissue kerma to A-150 kerma, along the carbon to oxygen kerma ratio, were determined. Absorbed dose rate calculations are in reasonable agreement with measured values. Use of these codes to study modifications to existing therapy beams is briefly discussed. (author).

1995-11-13

374

Analysis of a manipulator in relation to collision between a link and an object  

British Library Electronic Table of Contents (United Kingdom)

In this article, equations of motion of a manipulator are derived after consideration of the characteristics of the driving source. By considering a collision between a link and an object, and considering the active motion to absorb the kinetic energy of the object, the trajectories for saving energy are calculated by the iterative dynamic programming (IDP) method. The dynamic characteristics of manipulator control based on the trajectory for saving energy are also analyzed theoretically and investigated experimentally.

2011-01-01

375

Accuracy of calculations for stereotactic radiotherapy of the lung. Comparison of dose calculation algorithms  

International Nuclear Information System (INIS)

The purpose of this study is to evaluate the accuracy of dose calculations by three algorithms. Depth dose, OPF (Output Factor) and dose profiles were measured in a heterogeneous phantom. These values were also calculated by three algorithms of the Batho power law (BPL), Equivalent-Tissue Air Ratio (ETAR) and Convolution superposition (CS). The data were obtained for 4, 6 and 10 MV photon beams with a linear accelerator (Varian 21EX). Field size ranged from 3 x 3 cm"2 to 10 x 10 cm"2. Dose profiles of beam penumbra were also measured by a 0.125 ml ionization chamber at the point of 8, 13 and 18 cm from the surface of the phantom at intervals of 1 mm. Differences between measured and calculated depth doses were within 2% in BPL and CS, but depth doses were overestimated in ETAR. OPFs were also overestimated with the error of more than 4% in ETAR. Absorbed dose calculated by CS were in agreement with the values measured by the ionization chamber. The ...

2004-12-01

376

Absorbed dose and dose equivalent depth distributions for protons with energies from 2 to 600 MeV  

Energy Technology Data Exchange (ETDEWEB)

Depth dose distributions for protons in the energy range from 2 to 600 MeV have been calculated by Monte Carlo and analytical methods. The dependence on energy of Maximum Dose Equivalent (MDE), quality factor and isotropic factor recommended for practical use are presented. The problems connected with regulation of maximum permissible proton fluxes are discussed. (author).

1989-01-01

377

A radiant temperature numerical method for laser-plasma diagnostic using SXRSC with absorption method  

International Nuclear Information System (INIS)

An numerical method was developed for measuring radiant temperature using a set of absorption-foils coupled to soft x ray streak camera, SXRSC, in laser plasma experiments. An numerical code, SCC, was given. An x-ray intensity ratio vs temperature was calculated for Parylene, C_3H_6, Mylar and Aluminium. A suitable range of the measuring temperature was discussed to some absorber.

1990-01-01

378

28: Calculation of 3D dose distribution for photons in inhomogeneous media  

International Nuclear Information System (INIS)

A method for calculation of absorbed dose distributions in three dimensions for 1-20 MeV photons is presented. The method uses convolution/superposition of photon fluence distributions with energy scattering kernels. Results for Co-60 and X-ray beams in homogeneous and inhomogeneous media are compared with measurements. Good agreement is found between calculations and measurements. 8 refs.; 3 figs.

379

Structural Investigations of Silica Polyamine Composites: Surface Coverage, Metal Ion Coordination, and Ligand Modification  

Science.gov (United States)

Silanization of the silica gel surface in the synthesis of silica gel polyamine composites uses (chloropropyl)-trichlorosilane (CPTCS). It is possible to substitute a molar fraction of reagent CPTCS with methyltrichlorosilane (MTCS), creating a mixed silane surface layer. Two types of silica gels were modified with a series of MTCS:CPTCS molar ratios. Solid-state CP/MAS 29Si and 13C NMR spectroscopies were used to evaluate the surface silane composition. Surface silane coverage was markedly improved for the resulting gels. When polyamines were grafted to the resultant MTCS:CPTCS silane layers, it was shown that the decrease in the number of propyl attachments to the polyamine resulted in increased quantities of ''free amines''. Optimum MTCS:CPTCS ratios were determined for three polyamines grafted onto one silica gel. A substantial free amine increase was observed for poly(allylamine) (PAA). Metal uptake studies show increases in Cu(II) ...

2006-09-13

380

Structural Investigations of Silica Polyamine Composites: Surface Coverage, Metal Ion Coordination, and Ligand Modification  

Energy Technology Data Exchange (ETDEWEB)

Silanization of the silica gel surface in the synthesis of silica gel polyamine composites uses (chloropropyl)-trichlorosilane (CPTCS). It is possible to substitute a molar fraction of reagent CPTCS with methyltrichlorosilane (MTCS), creating a mixed silane surface layer. Two types of silica gels were modified with a series of MTCS:CPTCS molar ratios. Solid-state CP/MAS 29Si and 13C NMR spectroscopies were used to evaluate the surface silane composition. Surface silane coverage was markedly improved for the resulting gels. When polyamines were grafted to the resultant MTCS:CPTCS silane layers, it was shown that the decrease in the number of propyl attachments to the polyamine resulted in increased quantities of ''free amines''. Optimum MTCS:CPTCS ratios were determined for three polyamines grafted onto one silica gel. A substantial free amine increase was observed for poly(allylamine) (PAA). Metal uptake studies show increases in Cu(II) ...

2006-09-13

381

An investigation of the origin of the electrochemical hydrogen storage capacities of the ball-milled Co-Si composites  

Energy Technology Data Exchange (ETDEWEB)

The Co-Si composites with a molar ratio of 2:1 are synthesized by ball-milling method and their potential as negative electrode materials of Ni-MH batteries is investigated. The microstructure, morphology and chemical state of the ball-milled Co-Si composites are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). XRD patterns show that the ball-milled samples for 10 and 20 h contain Co, Si and Co{sub 2}Si phases, and the ball-milled samples for 40 and 60 h are mainly amorphous Co{sub 2}Si alloys. In contrast to the high initial discharge capacity (1012 mAh/g) obtained for the sample ball-milled for 10 h, the discharge capacities of the samples ball-milled for 40 and 60 h are very low. It indicates that the hydrogen storage capacity of pure Co{sub 2}Si alloy is very low. It is found that the formation of active Co nanoparticles and Si oxidation are ...

2010-02-15

382

Theoretical and basic experimental analysis on load adjustment of geothermal heat pump systems  

Energy Technology Data Exchange (ETDEWEB)

In order to match the output capacity of a geothermal heat pump system (GHPS) with the actual load requirement, research has been conducted in searching for suitable adjusting methods for the GHPS and on the subsequent effects on the working parameters of the GHPS. Firstly, several methods are compared, and it is found that the method of adjusting the compressor's rotation speed using a transducer is better than the others. Secondly, this method is experimented on a small scale GHPS at frequencies ranging from 30 to 55 Hz. The analysis of the experimental data reveals the relationships between the compressor frequency and other important parameters, such as coefficient of performance, heat capacity, cool capacity and compressor power input. The conclusions in the paper can serve as some guidance to the load adjustment of GHPS. (Author)

2003-01-01

383

The lost heat capacity and entropy in the helical magnet MnSi  

Science.gov (United States)

We report results of measurements and analysis of the heat capacity of MnSi. The measurements included data collection at a magnetic field of 4T, which suppresses strongly the longitudinal spin fluctuations and the phase transition. To analyze the experimental data, calculations of the phonon spectrum and phonon density of states in MnSi were performed. Inelastic neutron scattering with a polycrystalline sample of MnSi was used to validate the computational results. The combination of the experimental and theoretical data turned out to be decisive in revealing some hidden features of the thermal excitations in MnSi. In particular, the analysis of the available data led conclusively to the existence of a negative contribution to the heat capacity and entropy in MnSi at T>Tc, implying that a specific spin ordering process did occur in the paramagnet phase of MnSi.

2011-03-01

384

Sustainable development at Canadian Electrolytic Zinc -- recent improvements  

Energy Technology Data Exchange (ETDEWEB)

A series of modifications which increased the capacity of Canadian Electrolytic Zinc's Valleyfield plant from 220,000 MT/year to 260,000 MT/year during the last decade is discussed, combined with an an overview of the plant's operations. The modifications included modernisation of the waste disposal methods and facilities, such as a new high-density sludge wastewater treatment process, a new process to remove selenium from weak acid solutions and the jarofix process. Roasting capacity also has been improved by recent investments in new cooling coils, rebricking, oxygen enrichment and process automation. In addition to increases in refining capacity, the improvements also enabled the company to minimize its impact on the environment and the community.

2001-07-01

385

Study of copper foam-supported Sn thin film as a high-capacity anode for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Three-dimensional porous Sn thin film electrodes were prepared by electroless deposition on copper foam, then its morphology and electrochemical property were studied by means of scanning electron microscope (SEM), X-ray diffraction (XRD), electrochemical cycling test and cyclic voltammetry (CV). The porous framework and micro-holes have shown a great structure advantage in restricting severe volume changes when the Sn thin film was employed as anode for lithium-ion battery. The film electrode of sample C with an initial capacity of 676 mAh g{sup -1} showed good cycle performance displayed by retaining a capacity of 313 mAh g{sup -1} after 100 cycles.

2009-10-01

386

Removal of uranium from solution using residual brewery yeast: combined biosorption and precipitation  

Energy Technology Data Exchange (ETDEWEB)

Whilst unwashed preparations of biomass from a local brewery had an apparent maximum biosorption capacity for uranium of 360 mg/g (dry weight biomass) washing reduced this maximum to 150 mg/g. Homogenization of both biomass preparations and recovery of cellular debris had no significant effect on the maximum biosorption capacities although at lower equilibrium concentrations of uranium differences in the biosorption capacities were detected. When unwashed biomass was retained by a semi-permeable membrane 40% of uranium used in the experiments precipitated outside that membrane. Therefore a significant proportion of the uranium removed from solution, and previously attributed to biosorption by the yeast biomass, resulted from precipitation brought about by interaction with low molecular weight components loosely associated with the biomass. (Author).

1997-04-01

387

Pirfenidone in idiopathic pulmonary fibrosis: the CAPACITY program  

British Library Electronic Table of Contents (United Kingdom)

Idiopathic pulmonary fibrosis is the most lethal form of diffuse lung fibrosis, killing approximately half of those affected within 2-3 years of diagnosis. Until recently, no therapies had been shown to have an impact on disease progression. The Clinical Studies Assessing Pirfenidone (Esbriet) in IPF: Research of Efficacy and Safety Outcomes (CAPACITY) program comprised two almost identical double-blind placebo-controlled studies assessing the effects of pirfenidone on change in forced vital capacity, the primary end point, over a 72-week period. One of these studies was positive, matching in magnitude the benefit seen in two previous positive Japanese studies. The other study did not meet its primary end point but positive trends were consistent in this and a number of secondary end point...

2011-01-01

388

National technical report (Matsushita Electric Industrial Company), Vol. 40, No. 4, August 1994. Special issue on batteries  

Energy Technology Data Exchange (ETDEWEB)

Contents: recent trend of battery technologies; alkaline manganese battery with no mercury addition; high capacity zinc-air battery series for hearing aids; characteristics of vanadium-niobium-lithium rechargeable battery; high-energy density lithium-ion rechargeable battery; lithium polymer rechargeable battery: polymer gel electrolyte and electrode; high-capacity ni-cd battery sm120; high-capacity nickel-metal hydride battery; sealed-type batteries for electric vehicles; high-temperature-durable calcium-type battery for automobiles; sealed lead acid batteries for upss; solar cell power unit; solid oxide fuel cell (1); battery management system.

1994-08-01

389

Nanocrystalline MnO thin film anode for lithium ion batteries with low overpotential  

Energy Technology Data Exchange (ETDEWEB)

Nanocrystalline MnO thin film has been prepared by a pulsed laser deposition (PLD) method. The reversible lithium storage capacity of the MnO thin film electrodes at 0.125C is over 472 mAh g{sup -1} (3484 mAh cm{sup -3}) and can be retained more than 90% after 25 cycles. At a rate of 6C, 55% value of the capacity at 0.125C rate can be obtained for both charge and discharge. As-prepared MnO thin film electrodes show the lowest values of overpotential for both charge and discharge among transition metal oxides. All these performances make MnO a promising high capacity anode material for Li-ion batteries. (author)

2009-04-15

390

Measuring capacity development and reform in the Royal Solomon Islands Police Force  

British Library Electronic Table of Contents (United Kingdom)

International police have been deployed on a number of peacekeeping missions, but providing capacity development and assisting in reform of local police in war-torn nations are only a relatively recent undertaking. The process of police reform is complicated because of the inherent difficulty in evaluating the impact of a development programme on police service delivery performance. This study reports on the results of a pilot survey of international police managers assessment of the level of competency of the Royal Solomon Islands Police Force following the introduction of a capacity development programme 3 years earlier. The results indicate that although the local police had improved operationally, and in some cases to an international standard, the Force had lower capability in strateg...

2010-01-01

391

High capacity orthorhombic LiMnO{sub 2} phases: role of piling up defects; Phases LiMnO{sub 2} orthorhombiques a haute capacite: role des defauts d`empilement  

Energy Technology Data Exchange (ETDEWEB)

The electrochemical performances of orthorhombic LiMnO{sub 2} compounds are analyzed in order to find a structural and/or morphological origin to the differences of electrochemical behaviours observed in compounds with different size of crystallites and different amounts of lattice defects. Energy capacity performances of 200 Ah/kg are reached for materials with crystallites of about 10{sup 7} Angstrom{sup 3} and with about 7% of defects, while energy capacities of only 80 Ah/kg are obtained for materials with ten times bigger crystallites. (J.S.) 3 refs.

1996-12-31

392

High capacity Si/DC/MWCNTs nanocomposite anode materials for lithium ion batteries  

International Nuclear Information System (INIS)

Nanocomposites comprising nanocrystal silicon (Si), disordered carbon (DC), and multi-walled carbon nanotubes (MWCNTs) - denoted as Si/DC/MWCNTs - have been prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with Si and MWCNTs. This nanocomposite anode material showed a discharge capacity of 1216 mAh/g in the first cycle, and a charge capacity of 711 mAh/g after 20 charge-discharge, much higher than that of Si/DC composite. It can be observed that Si particles wrapped in MWCNTs were homogeneously embedded into the matrix of the DC. The improved electrochemical performance is hypothesized to be mainly attributed to the morphology stability of the composite due to the excellent resiliency and distinct electric conductivity of the MWCNTs.

2010-03-18

393

Graphite as negative electrode in Li-ion batteries; Le graphite comme electrode negative dans les accumulateurs Li-ion  

Energy Technology Data Exchange (ETDEWEB)

The last developments in lithium batteries design have demonstrated the advantages of graphite: competitive cost, flat output curve, high capacity thanks to the obtention of a final compound close to LiC{sub 6}, good behaviour during cycling and a high mass energy. However, these advantages are slightly tarnished by parasite secondary reactions during the evolution of the element. Two different cases are encountered: the formation of a passivation layer (loss of Li ions and formation of irreversible bounds) and the formation of a passivation layer with a reaction between graphite and the solvent (partial destruction of the graphite crystal lattice). In the first case, the theoretical graphite insertion capacity remains at 372 mAh/g while in the second case the insertion capacity is greatly reduced. Abstract only. (J.S.)

1996-12-31

394

Experimental investigation and modelling of heat capacity, heat of fusion and melting interval of rocks  

Energy Technology Data Exchange (ETDEWEB)

The heat capacity and heat of fusion were measured for a number of minerals using differential scanning calorimetry (DSC). The DSC measurements showed that the heat of fusion for the minerals is very low compared to the heat of fusion for pure crystalline phases reported elsewhere. A model for the melting behaviour of mineral materials in terms of melting interval, heat capacities and heat of fusion has been developed. The only model input is the chemical composition of the mineral material. The model was developed to be implemented in a detailed model of a cupola furnace, thus the focus for the development was not only precision but also to obtain a model that was continuous and differentiable. The model is based on several different submodels that each covers a part of the heating and melting of rocks. Each submodel is based on large amounts of empirical data. Comparison of the model and the DSC measurements showed reasonable agreement for ...

2003-11-28

395

Evaluation of CO2 adsorption capacity of solid sorbents  

British Library Electronic Table of Contents (United Kingdom)

The CO2 adsorption capacity of the low-cost solid sorbents of waste tire char (TC) and chicken waste char (CW) was compared with commercial active carbon (AC) and 5?? zeolite (ZA) using thermogravimetric analysis (TG), pressurized TG, and differential scanning calorimetry (DSC). The sorbents were degassed in a TG up to 150??C to release all gases on the surface of the sample, then cooled down to the designed temperature for adsorption. TG results indicated that the CO2 adsorption capacity of TC was higher than that of CW, but lower than those of AC and ZA. The maximum adsorption rate of TC at 50??C was 0.61% min?1, lower than that of AC, but higher than that of CW, 0.44% min?1. The maximum adsorption rate of ZA at 50??C was 3.1% min?1. When the pressure was over 4?bar, the adsorption rate ...

2011-01-01

396

Electrospun porous SnO2 nanotubes as high capacity anode materials for lithium ion batteries  

British Library Electronic Table of Contents (United Kingdom)

Porous SnO2 nanotubes were prepared via electrospinning followed by calcination in air. As anode materials for lithium ion batteries, the porous nanotubes delivered a high discharge capacity of 807mAhg^-^1 after 50cycles. Even after cycled at high rates, the electrode still retained a high fraction of its theoretical capacity. Such excellent performances of porous SnO2 nanotubes could be attributed to the porous and hollow structure which facilitated liquid electrolyte diffusion into the bulk materials and buffered large volume changes during lithium ions insertion/extraction. Furthermore, the nanoparticles of nanotubes provided the shorter diffusion length for lithium ions insertion which benefited in retaining the structural stability and good rate performance. Our results demonstrated t...

2010-01-01

397

Electrochemical performance of flowerlike CaSnO{sub 3} as high capacity anode material for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Nanosized CaSnO{sub 3} is synthesized by a hydrothermal process and characterized by X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM). The SEM observation shows the sample has a porous flowerlike morphology. The electrochemical results exhibit that the stable and reversible capacity of 547 mAh g{sup -1} is obtained after 50 cycles at 60 mA g{sup -1} (0.1 C) and the corresponding charge capacity is determined to be 316 mAh g{sup -1} at the current density of 2.5 C. Cyclic voltammetry and electrochemical impedance spectroscopy data are analyzed to complement the galvanostatic results. The observed excellent performance is attributed to the porous structure and large surface area of flowerlike CaSnO{sub 3}.

2010-04-30

398

Electrochemical hydrogen storage behaviors of ultrafine Co-P particles prepared by direct ball-milling method  

Energy Technology Data Exchange (ETDEWEB)

Ultrafine particles of Co-P were synthesized by direct ball milling of Co and P powders and also investigated as a reversible hydrogen storage electrode material. The electrochemical results demonstrated that the reversible charge-discharge capacity of the Co-P electrode can reach more than 300mAh/g. In addition, the cycling ability and high rate capability of the Co-P electrode are excellent with only 5% capacity decay after 100 cycles at a high rate of 300mA/g. The temperature-programmed desorption measurements (TPD) of the Co-P electrode revealed that the charge and discharge reactions of the Co-P electrode proceeds predominantly through electrochemical hydrogen storage mechanism and the electrooxidation of cobalt contributes only a negligible part to the reversible electrochemical capacity. (author)

2006-05-25

399

Cycleable graphite/FeSi{sub 6} alloy composite as a high capacity anode material for Li-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

FeSi{sub 6}/graphite composite was prepared by mechanical ball milling. The FeSi{sub 6} alloy particles consist of an electrochemically active silicon phase and inactive phases FeSi{sub 2}, distributed uniformly in the graphite matrix. The composite anode offers a large reversible capacity (about 800 mAh g{sup -1}) and good cycleability, due to the buffering effect of the inactive FeSi{sub 2} phase and graphite layers on the volumetric changes of Si phase during lithium-Si alloying reaction. Since FeSi{sub 6} alloy is a low-cost industrial material, this alloy compound provides a possible alternative for development of high capacity lithium-ion batteries. (author)

2008-10-01

400

Cathode materials for lithium rocking chair batteries  

Energy Technology Data Exchange (ETDEWEB)

Cathode materials for rechargeable rocking chair or lithium-ion batteries, are reviewed. The emphasis is placed on the comparison between specific capacities and rechargeability of lithium-containing high voltage cathode materials such as manganese oxides and LiMO{sub 2} compounds, where M is Co or Ni. It is generally found that the maximum reversible capacities for the most promising materials fall in the range 100-120 mAh/g, and decaying to around 75 mAh/g after several hundred cycles. The rechargeability is similar for the most commonly considered materials: LiMn{sub 2}O{sub 4}, LiCoO{sub 2} and LiNiO{sub 2}. No improvements in capacity or rechargeability, beyond what have been found for these materials, is observed by substitution of other elements into these compounds

1996-03-29

401

As-synthesized MCM-41 silica: new adsorbent for perchlorate  

British Library Electronic Table of Contents (United Kingdom)

Here we demonstrate that the as-prepared MCM-41 mesoporous silica material, which is synthesized using cetyltrimethylammonium bromide as a cationic surfactant exhibits very high capacity for perchlorate uptake from solutions. Thus we discover a new function for the as-synthesized mesoporous materials containing cationic surfactants. These materials are shown to have better capacity than the currently used activated carbon, which is preloaded with cationic surfactant. As-synthesized MCM-41 has a higher removal of perchlorate with 0.378???0.038?meq/g than the surfactant modified activated carbon sample, which removed 0.304???0.005?meq/g i.e., MCM-41 has a 24 % higher capacity than the surfactant modified activated carbon sample for perchlorate uptake because of higher surfactant content and ...

2010-01-01

402

Synthesis of polyester styrene resin beads as polymeric ionic exchangers by using chemical and irradiation techniques  

International Nuclear Information System (INIS)

The aim of the study is to prepare ionic exchangers using the polymerization of unsaturated polyster with monomeric styrene units in a ratio of 60%: 40% respectively. The type of method involved in this preparation, is called An Emulsion Polymerization. Such type of polymerization was carried out by two techniques: chemical and irradiation techniques. The first techniques requires the formation of free radical monomers by use of methyl Ethy Ketone Peroxide capable of decomposing into free radicals upon heating, while the other technique involves the use of gamma rays (using Co-60 source) capable of activating monomers towards free radical formations. A number of very effective chemical parameters and physical factors were used and investigated throughout the reactions such as: dispersant matrix, viscosity, rate of mixing, and irradiation dose. Besides, the study has included the study of the rate of Resin Beads Swelling ...

3087-01-01

403

The role of water and oxygen impurities on ozone production in a negative corona discharge of CO_2  

International Nuclear Information System (INIS)

The production of ozone in a negative corona discharge fed by carbon dioxide with embedded traces of oxygen and water has been studied. The presence of traces of oxygen in both pure and dry CO_2 leads to an increase in nascent ozone concentrations. In contrast, traces of water vapour (0-800 ppm) are shown to rapidly suppress ozone concentrations with the largest decreases being observed at lowest gas pressures in the discharge (300 Torr). The presence of water vapour did not considerably affect the electrical properties of negative dc corona suggesting that a chemical process is responsible for the ozone loss. We have shown that the addition of water up to a concentration of 1500 ppm has only a marginal effect on the processes of ozone formation but the catalytic cycle of ozone destruction involving OH radicals can be the reason for observed decrease in the total ozone concentration with increasing water concentration.

2007-11-07

404

Structural analysis of a binary metallic glass model. I. - The Pd/sub 80/Si/sub 20/ alloy  

Energy Technology Data Exchange (ETDEWEB)

In the first paper of this series devoted to a structural analysis of a binary metallic glass model, we study a Pd/sub 80/Si/sub 20/ sample obtained by numerical relaxation. We discuss the reproducibility of the method and make a comparison with the experimental interference functions. Then we undertake a microscopic structural analysis from several point of view: we first study the number of neighbours of each type for each type of atoms; secondly, we analyse the structure by means of the radical plane method; at last, we show that it is possible to generalize the five fundamental characteristic units introduced by Bernal, so that we can define the environment of any Si atom without any ambiguity. All these methods reveal a certain tendency towards a prismatic environment for the metalloids.

1985-02-01

405

Self-valued health in Danish women after cervix cancer surgery-A retrospective questionnaire study  

British Library Electronic Table of Contents (United Kingdom)

Women treated of localised stages of cervix cancer have a very good prognosis. But do health care professionals have a tendency to underestimate the potential need for rehabilitation of this group? To be able to answer this question this study aimed to develop knowledge concerning these women's own perception of their health during a long period after surgical cancer treatment. A total of 398 women who underwent radical hysterectomy in the period from the 1 January 1983 to 31 December 2000 participated in the study at Aarhus University Hospital, Skejby in Denmark 2001-2003. All patients initially filled in an internally validated questionnaire. Subsequently a sample of 100 women filled in the questionnaires Short Form -36 and Sense of Coherence to evaluate their self-reported health. Analy...

2007-01-01

406

Role of antioxidants in the treatment of male infertility  

British Library Electronic Table of Contents (United Kingdom)

Abstract Male infertility continues to be a clinical challenge of increasing significance. While male factors such as decreased semen quality are responsible for 25% of all infertility issues, the etiology of suboptimal semen quality is poorly understood. Many physiological, environmental, and genetic factors have been implicated, including oxidative stress. Oxidative stress is induced by reactive oxygen species (ROS), or free radicals, and although ROS are required for critical aspects of sperm function, excessive levels of ROS can negatively impact sperm quality. The origin of ROS generation, and the etiologies of increased ROS in men with suboptimal sperm quality have only recently been elucidated, offering multiple targets for potential therapy. Here, we present a critical review of th...

2009-01-01

407

Photodegradation of polypropylene/polystyrene blends: Styrene-butadiene-styrene compatibilisation effect  

British Library Electronic Table of Contents (United Kingdom)

The mutual influence between the PP/PS polymer blend components during UV photodegradation was studied. Polypropylene (PP) and polystyrene (PS) have different photodegradation mechanisms, due to the larger UV absorption of polystyrene and formation of more stable tertiary carbon radicals. To compare the stabilities the kinetics of carbonyl formation was measured in different blend compositions. The results show that polystyrene presented a faster carbonyl formation than polypropylene, while the blends display faster kinetics than the isolated components. The kinetics of carbonyl formation of the blends was a function of polypropylene content. This result is unexpected if one considers the behaviour of each component alone. The kinetics and mechanism of UV degradation can be only explained ...

2008-01-01

408

Monte Carlo methods, models, and applications for the Advanced Neutron Source  

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional, continuous-energy, coupled neutron-gamma Monte Carlo model of the advanced neutron source (ANS) final preconceptual reference core design has been developed using MCNP Version 3b. This model contains the reactor core with control rods, the heavy-water reflector tank with shutdown rods and representative beam tubes, and the outer light-water poor. Eighty homogenized fuel zones per fuel element are used to represent the radical and axial {sup 235}U fuel grading. This model is the most sophisticated, physically accurate reactor physics model of the ANS currently available. The purpose of this summary is to demonstrate the MCNP methods and applications for the ANS.

1990-06-01

409

Measurement of skin dose in primary irradiation of maxillary sinus carcinoma  

Energy Technology Data Exchange (ETDEWEB)

Subcutaneous involvement frequently occurs in maxillary sinus carcinoma. Radical resection does not include removal of the skin at risk. In standard postoperative wedge-pair treatment plans, the surface dose is dependent upon beam weighting, beam energy, and patient contour. Thermoluminescent dosimetry (TLD) measurements were performed to evaluate the surface dose of patients undergoing postoperative irradiation of maxillary sinus carcinoma following primary resection. When 60 Gy was delivered to isocenter with a 45 degrees wedge pair and 6 MV photons with 1 cm bolus, the subcutaneous tissues at risk received {approximately} 30 Gy. Based upon presented TLD measurements, supplemental electron beam therapy to the subcutaneous tissues if primarily involved should be considered.

1991-03-01

410

Market based pollution abatement measures and creation of internal environmental diseconomies  

Energy Technology Data Exchange (ETDEWEB)

New market based approaches are becoming increasingly important as instruments of environmental policy. The two main market approaches, i.e., transferable pollution permits (experimented in America), and 'green' energy surcharges (European philosophy), are described and discussed. An analysis of information on their state of implementation shows that, in the case of the former method, the greatest sources of difficulty arise in the determination of acceptable ceiling levels of emissions, in the distribution of permits among the various polluting firms, and in the legality of granting rights to pollute. Instead, the European experience has evidenced that energy surcharges motivated by environmental policy cannot have an appreciable positive impact on consumers or the economic system in general unless they are accompanied by well defined measures geared towards the promotion or creation of alternative solutions such as to stimulate radical change in ...

1991-09-01

411

Long-term survival following radical surgery after chemotherapy for esophagogastric adenocarcinoma with extensive lymph node metastases: Report of a case  

British Library Electronic Table of Contents (United Kingdom)

A 46-year-old man was referred to us after he presented to his local physician complaining of difficulty eating. Upper gastrointestinal endoscopy revealed a tumor at the esophagogastric junction (EGJ), and moderately differentiated adenocarcinoma was diagnosed from the biopsy findings. Computed tomography (CT) showed apparent enlargement of the pretracheal lymph nodes, the lymph nodes around the bilateral recurrent laryngeal nerves, and the lower thoracic paraesophageal lymph nodes, confirming metastasis. Since the disease was far advanced esophagogastric cancer with marked lymph node metastases throughout the mediastinum, curative resection would have been unlikely. Thus, he was commenced on systemic chemotherapy with cisplatin (90 mg/body, day 8) + S-1 (120 mg/body/day, given for 3 weeks...

2011-01-01

412

Language morphology offset: Text classification on a Croatian-English parallel corpus  

British Library Electronic Table of Contents (United Kingdom)

We investigate how, and to what extent, morphological complexity of the language influences text classification using support vector machines (SVM). The Croatian-English parallel corpus provides the basis for direct comparison of two languages of radically different morphological complexity. We quantified, compared, and statistically tested the effects of morphological normalisation on SVM classifier performance based on a series of parallel experiments on both languages, carried over a large scale of different feature subset sizes obtained by different feature selection methods, and applying different levels of morphological normalisation. We also quantified the trade-off between feature space size and performance for different levels of morphological normalisation, and compared the resul...

2008-01-01

413

Irradiation of human insulin in aqueous solution, first step towards radiosterilization  

British Library Electronic Table of Contents (United Kingdom)

The degradation of irradiated human insulin in aqueous solutions was investigated in order to protect the protein against ionizing radiation. The influence of the drug concentration, excipients and irradiation temperature were studied.Aqueous solutions at pH 2 were irradiated by gamma rays or by accelerated electrons. Two different high-performance liquid chromatography (HPLC) methods were used: reverse-phase high-performance liquid chromatography (RP-HPLC)/UV and size exclusion liquid chromatography (SEC/UV) to investigate both the fragmentation and the formation of higher molecular weight proteins.In solution without excipients irradiated at ambient temperature at 10kGy, the loss of human insulin is almost complete. Addition of radio-protecting excipients (free radicals scavengers) and c...

2007-01-01

414

Inhibitor for aqueous acid solutions  

Science.gov (United States)

An organic inhibitor for acid corrosion inhibition is described. The inhibitor is a condensation product of a mixture of diethyl- and dibutyl-thiourea with hexamethylenetatramine. This condensation product is preferably made by reacting a mixture of diethyl- and dibutyl-thiourea, in a weight ratio of from 1:5 to 5:1, with 0.1 to 1 mole of hexamethylene tetramine per mole of the thiourea mixture, at temperatures of from 100 to 150 C. It is possible to modify this by using other organic thiourea derivatives containing organic radicals (aliphatic or aromatic) having up to 10 carbon atoms, for example, ditoluyl-thiourea, in addition to the mixture of diethyl- and dibutyl-thiourea, but the amount by weight of these other derivatives must not exceed 20% of the diethyl-dibutyl-thiourea mixture. The advantages of the inhibitor are observed mainly when it is used in hydrofluoric acid solutions. 6 claims.

1978-07-18

415

Incidence and management of secondary malignancies in patients with retinoblastoma and Ewing's sarcoma  

International Nuclear Information System (INIS)

Childhood cancer survivors at highest risk of developing a secondary malignancy are those with hereditary retinoblastoma. The majority of such secondary cancers will be sarcomas, most commonly of bone. One-third of these occur outside a typical radiation field, commonly in an extremity. Bone sarcoma is also the most commonly reported secondary cancer to develop among survivors of Ewing's sarcoma. In this group, radiation doses greater than 60 Gy as well as alkylating agent chemotherapy have been identified as contributors to the increased risk. The prognosis for patients with a secondary sarcoma has been poor, with few cures reported to date. However, an aggressive, combined modality approach, including radical resection, postoperative radiation, and adjuvant chemotherapy, may improve the survival rate.

416

Homogeneous models for mechanisms of surface reactions: Propylene ammoxidation  

Energy Technology Data Exchange (ETDEWEB)

The proposed active sites on the catalyst surface in heterogeneous propylene ammoxidation have been successfully modelled by structurally characterized pinacolato W(VI) tert-butylimido complexes. These compounds exist as an equilibrating mixture of amine-bis(imido) and imido-bis(amido) complexes, the position of this equilibrium is dependent on the electronic nature of the glycolate ligand. Both of the C-N bond-forming reactions proposed in recent studies by Grasselli et al. (1) have been reproduced using discrete Group VI d{sup 0} organoimido complexes under mild conditions suitable for detailed mechanistic studies. These reactions are: (1) oxidative trapping of radicals at molybdenum imido sites, and (2) migration of the allyl group from oxygen to an imido nitrogen atom.

1987-04-01

417

Green Tea Extract (Epigallocatechin-3-Gallate) Reduces Efficacy of Radiotherapy on Prostate Cancer Cells  

British Library Electronic Table of Contents (United Kingdom)

ObjectivesTo assess the influence of epigallocatechin-3-gallate (EGCG) on the efficacy of ionizing radiation on prostate cancer cells because of the increased use of dietary interventions, especially by patients with prostate cancer. Radiotherapy is used to treat localized prostate cancer. Some people consume green tea (EGCG) as a chemopreventive agent against prostate cancer. Green tea can act as an antioxidant and induce superoxide dismutase enzymes, which could scavenge the free oxygen radicals generated by radiotherapy. MethodsProstate cancer cell line DU145 cells were treated with EGCG or radiotherapy, or both. Cell death was assessed using trypan blue cell counting, and apoptosis was confirmed by assessing poly (adenosine phosphate ribose) polymerase cleavage. The antioxidant potenti...

2011-01-01

418

Free electron laser inertial thermonuclear synthesis  

International Nuclear Information System (INIS)

The paper proposes a concept of power driver for industrial thermonuclear reactor based on inertial thermonuclear synthesis (ITS). The circuit is based on the application of free electron laser (FEL) as a energy source for thermonuclear target compression which becomes feasible due to the application of a radically new circuit of FEL-amplifier. In the project under consideration the FEL-based laser system operates on the wave length of 0.5 micrometer. The full energy of laser radiation equals 1 MJ. This energy is delivered to the target in the pulse whose length is controlled within the range of 0.1-2 ns. The laser system brightness is 4 x 10"2"2 W cm"-"2. The FEL operating pulse repetition frequency is 40 Hz, full efficiency of electricity conversion into the energy of optical radiation is 11%. 9 refs., 3 figs., 2 tabs.

419

Electrochromic effects of charge separation in bacterial photosynthesis: theoretical models  

Energy Technology Data Exchange (ETDEWEB)

The primary charge separation in photosynthetic bacteria generates a dimeric bacteriochlorophyll (BChl) cation and a bacteriopheophytin (BPheo) anion which lie within close proximity of each other (approx. 10 A). The two radicals also lie within van der Waals contact on opposite sides of a lone BChl bridging molecule. Spectral changes in the red (Q/sub y/) band of the bridge BChls have been observed on picosecond time scales following excitation of the reaction center (RC) and have been variously attributed to the formation of a BChl anion, to a charge-transfer state, or to electrochromic effects. They present calculations here which suggest that electrochromic effects caused by the photogenerated cation and/or anion can rationalize the optical changes observed in the flash photolyses as well as in trapping experiments.

1987-07-22

420

Developing E-Business Dynamic Capabilities: An Analysis of E-Commerce Innovation from I-, M-, to U-Commerce  

British Library Electronic Table of Contents (United Kingdom)

This study uses an electronic commerce (E-commerce) innovation model to analyze the differences in technological knowledge, business model, and dynamic capability aspects used in Internet-enabled commerce (I-commerce) versus mobile commerce (M-commerce) versus ubiquitous commerce (U-commerce). The results indicate that the innovation from I-commerce to M-commerce is radical, leading to drastic changes in the business model. However, from M-commerce to U-commerce, disruptive changes occur in both technological and business model dimensions. A set of critical dynamic capabilities for each innovation is identified. These results provide great insight for practitioners and scholars for enhancing their understanding of E-commerce innovation, and provide guidelines to help practitioners adapt fr...

2008-01-01

421

Detection of irradiated chicken by ESR spectroscopy of bone  

Energy Technology Data Exchange (ETDEWEB)

Ionizing radiation has been used to treat poultry to remove harmful microorganisms, mainly Salmonella, which contaminates chicken, goose and other fresh and frozen poultry. This microorganism is sensitive to low dose radiation. Thus, irradiating these foods with doses between 1 to 7 kGy results in a large reduction of bacteria. Since it is necessary to determine whether irradiation has occurred and to what extend, this work studied the signal produced by ionizing radiation within the hard crystalline matrix of chicken`s bone to establish a control method. Chicken`s drumsticks were irradiated and bones separated from flesh were lyophilized and milled. ESR spectrum was then obtained. The ESR signal increased linearly with dose over the range 0.25 to 8.0 kGy. Free radicals evaluated during 30 days after irradiation showed stable in this period. (Author).

1995-10-01

422

Comparative studies on the characterization and antioxidant properties of biodegradable alginate films containing ginseng extract  

British Library Electronic Table of Contents (United Kingdom)

The physical and antioxidant properties of alginate biodegradable film incorporating white, red and extruded white ginseng extracts were investigated. No differences in moisture contents of all alginate film samples were noticeable (p>0.05) except those film samples incorporated without ginseng extract, which had the highest moisture content. The addition of ginseng extract to alginate film decreased tensile strength and elastic modulus (p<0.05) but increased the percent elongation at break. The presence of extracts did not significantly affect the water vapor permeability of the film samples. Alginate film containing extruded white ginseng extract at a barrel temperature of 130degreeC presented the highest (61.12%) free-radical scavenging activity against the 2,2-diphenyl-1-picryhydrazyl ...

2010-01-01

423

Coalification by clay-catalyzed oligomerization of plant monomers. [Methyleugenol  

Science.gov (United States)

During this report period, we have obtained a model of montmorillonite clay, and this model has been of great assistance in visualizing how the chemistry of substrate molecules might be altered as it occurs on the surface of the clay. A stereochemical representation of this montmorillonite model is shown. Of particular significance, this model indicates that hydroxyl groups are located in the center of each siloxane ring on the surface of the montmorillonite clay. These hydroxyl groups might serve to bond substrate molecules to the surface of the clay. The next step in our systematic examination of the radical cation-initiated dimerization of plant monomers from the C{sub 6}-C{sub 3} pool of shikimic acid metabolites was to study the dimerization of cinnamic acid and its derivatives. In the next block of research, we examined the reaction of montmorillonite clay (K-10) with methyleugenol. 2 refs.

1990-01-01

424

Antioxidant properties of 4-methylcoumarins in in vitro cell-free systems  

British Library Electronic Table of Contents (United Kingdom)

4-Methylcoumarins that possess two hydroxyl groups ortho to each other in the benzenoid ring have shown to have excellent antioxidant and radical-scavenging properties in different experimental models. Furthermore, they cannot be metabolized by the liver P450 monoxygenases and thus cannot form 3,4-coumarin epoxides, which are believed to be mutagenic. Herein, we present a study on the structure activity relationship of eight synthetic 4-methylcoumarins, carried out by employing a series of different chemical cell-free tests. These compounds were tested by means of three assays involving one redox reaction with the oxidant (DPPH assay, ABTS+ assay and FRAP). Other assays were employed to evaluate the antioxidant properties of the coumarins under investigation against NO, O2- and HClO, which...

2010-01-01

425

Analysis of recent {eta} photoproduction data  

Energy Technology Data Exchange (ETDEWEB)

Recent data on {eta} -meson photoproduction off a proton target in the energy range 2 {<=}{radical}(s){<=} 3 GeV are analyzed with regard to their overall consistency. Results from the ELSA and CLAS measurements are compared with predictions of a Regge model whose reaction amplitude was fixed via a global fit to pre-2000 measurements of differential cross sections and polarization observables for {gamma}p{yields}{eta}p at higher energies. We find that all recent experimental results on differential cross sections for {eta} -meson photoproduction are in good agreement with each other, except for the CLAS data from 2009. However, the latter can be made consistent with the other data at the expense of introducing an energy-dependent renormalization factor. We point out that there are indications in the data for a possible excitation of baryon resonances with masses around 2.1 and 2.4GeV. (orig.)

2010-12-15

426

Unique effect of mechanical crushing on the electrochemical intercalation of lithium in carbons of different morphologies; Effet unique du broyage mecanique sur l`intercalation electrochimique du lithium dans des carbones de morphologies differentes  

Energy Technology Data Exchange (ETDEWEB)

Lithium ion batteries use an oxide as a positive electrode and a carbon material as a negative electrode. The performances of carbon electrodes have rapidly evolved during the last years thanks to the substitution of soft carbons of Conoco or MCMB-2510 type by graphites (F-399, MCMB-2528) and then by hard carbons. These high capacity carbons (700 mAh/g) have higher service life and volume capacity than graphites but their irreversible losses are greater (>20%). In this work, materials with similar electrochemical performances are prepared by mechanical crushing. Mechanical crushing allows to obtain a wide range of carbon materials with various morphologies, specific surfaces and levels of disorder. The formation of the passivation film is directly linked with the surface of materials. A reaction scheme of the reversible and irreversible capacities has been defined and has permitted to obtain compounds with reversible ...

1996-12-31

427

Total Antioxidant Performance Is Associated with Diet and Serum Antioxidants in Participants of the Diet and Physical Activity Substudy of the Jackson Heart Study12  

UK PubMed Central (United Kingdom)

Total antioxidant performance (TAP) measures antioxidant capacities in both hydrophilic and lipophilic compartments of serum and interactions known to exist between them. Our objective was to assess...Full Text Available

2009-10-01

428

Top-down and bottom-up modulation in processing bimodal face/voice stimuli  

UK PubMed Central (United Kingdom)

BackgroundProcessing of multimodal information is a critical capacity of the human brain, with classic studies showing bimodal stimulation either facilitating or interfering in perceptual...Full Text Available

429

Thermal stability and acid resistance of aluminosilicophosphate zeolites  

Energy Technology Data Exchange (ETDEWEB)

By isomorphous replacement of silicon by phosphorus the authors have synthesized crystalline aluminosilicophosphates with structures of the zeolites type A and faujasite. They determine the adsorption capacity of specimens treated at 575-1275/sup 0/K. They show that the thermal stability and acid resistance of aluminosilicophosphates depend on the quantity of phosphorus in their structure.

1987-04-01

430

Synthesis of pellet-type red mud adsorbents for removal of heavy metal ions  

Energy Technology Data Exchange (ETDEWEB)

Red mud is generated as a by-product in the production of Al(OH){sub 3}/Al{sub 2}O{sub 3} from bauxite ore. In this study the pellet-type adsorbents have been made from the red mud, and their adsorption capacities of heavy metal ions have been tested. The pellet-type adsorbents were synthesized to utilize the excellent adsorption capacity of the powder-type adsorbent for industrial application. The pellet-type adsorbents were prepared by mixing several kinds of additives with the red mud. It is found that the pellet-type adsorbent, made by sintering a mixture of red mud (96.0 wt%), polypropylene (2.5 wt%), fly ash (0.5 wt%), and sodium meta-silicate (1.0 wt%) at 1200 deg.C for 30 minutes, has the highest adsorption capacity. In this work, the two kinds of pellet-type adsorbents (bead-type, crushed-type) were prepared. The crushed-type adsorbent was found to show a better adsorption/desorption performance than the bead-type ...

2000-02-28

431

Synthesis and electrochemistry properties of Sn-Sb ultrafine particles as anode of lithium-ion batteries  

International Nuclear Information System (INIS)

Ultrafine particles of Sn-Sb alloys with different chemical composition have been prepared by hydrogen plasma-metal reaction. Structure, morphology, size and chemical composition of the Sn-Sb ultrafine particles were investigated by transmission electron microscopy, X-ray diffraction, BET gas adsorption, and induction-coupled plasma spectroscopy. It was found that all the particles have spherical shapes, with average particle size in the range of 100-300 nm. The electrochemistry properties as an alternative anode material for lithium-ion batteries have been characterized by constant current cycling and cyclic voltammetry. Electrochemical measurements showed that the alloys with Sn-46.5 at.% Sb have best reversible capacity and capacity retention. It exhibited a high reversible lithium-ion storage capacity of 701 mAh g"-"1 in the initial cycle, which has remained at 81% (i.e., 566 mAh g"-"1) of its original ...

2007-07-31

432

Supply of medium and small hydropower equipment  

Energy Technology Data Exchange (ETDEWEB)

This paper presents a brief account of Lingling Hydroelectric Power Equipment General Works, the capacity of equipment production, the organization body, the quality assurance system and supervision of government department on its product quality.

1995-07-01

433

Silicates as Nonspecific Adsorbents of Bacteriophage: a Model for Purification of Water from Viruses  

UK PubMed Central (United Kingdom)

Amorphous silicates having small particles with a large surface area were found to have high nonspecific adsorption capacity. Investigations with Escherichia coli T4 bacteriophage have...Full Text Available

1980-01-01

434

Sexual behavior in Japanese quail as a test end point for endocrine disruption: effects of in ovo exposure to ethinylestradiol and diethylstilbestrol.  

UK PubMed Central (United Kingdom)

Chemicals having a capacity to disturb the endocrine system have attracted considerable interest during recent years. There is a shortage of well-characterized in vivo tests with which to study such...Full Text Available

1999-11-01

435

Reduced Accumulation of ABA during Water Stress in a Molybdenum Cofactor Mutant of Barley 1  

UK PubMed Central (United Kingdom)

A barley (Hordeum vulgare L.) mutant (Az34) has been identified with low basal levels of abscisic acid (ABA) and with reduced capacity for producing ABA in response to water stress....Full Text Available

1989-06-01

436

Receptor in group C and G streptococci detects albumin structures present in mammalian species.  

UK PubMed Central (United Kingdom)

The presence of albumin structures with the capacity to bind to a surface receptor in group C and G streptococci was studied in serum samples from 45 mammalian species representing 15 different orders,...Full Text Available

1982-05-01

437

Rapid Onset of Maternal Vocal Recognition in a Colonially Breeding Mammal, the Australian Sea Lion  

UK PubMed Central (United Kingdom)

BackgroundIn many gregarious mammals, mothers and offspring have developed the abilities to recognise each other using acoustic signals. Such capacity may develop at different rates...Full Text Available

438

Product toxicity and cometabolic competitive inhibition modeling of chloroform and trichloroethylene transformation by methanotrophic resting cells.  

UK PubMed Central (United Kingdom)

The rate and capacity for chloroform (CF) and trichloroethylene (TCE) transformation by a mixed methanotrophic culture of resting cells (no exogenous energy source) and formate-fed cells were measured....Full Text Available

1991-04-01

439

Pretreatment with a soluble activin type IIB receptor/Fc fusion protein improves hypoxia-induced muscle dysfunction  

UK PubMed Central (United Kingdom)

Hypoxia, or reduced oxygen, occurs in a variety of clinical and environmental situations. Hypoxic exposure is associated with decreased muscle mass and a concomitant reduction in exercise capacity,...Full Text Available

2010-01-01

440

Preparation and characterization of anion exchangers from petroleum asphaltites  

British Library Electronic Table of Contents (United Kingdom)

The chloromethylation reaction of an asphaltite and styrene graft copolymer followed by the amination of the chloromethylated products was optimized. New strongly basic anion exchangers with an exchange capacity of 2.5 mg-equiv/g and a mechanical strength of 93% were prepared.

2011-01-01

441

Powdering Characteristics of a Thin Film Evaporator: Drying and Powdering of a Solution.  

Science.gov (United States)

A thin-film evaporator requires only a short heating time to concentrate a solution since it has a high thermal efficiency and has a small capacity. Thus, the chemical industry often uses this type of evaporator for concentrating materials that are subjec...

1983-01-01

442

Isolation and characterization of a novel gamma-hexachlorocyclohexane-degrading bacterium.  

UK PubMed Central (United Kingdom)

The natural biotic capacity of soils to degrade gamma-hexachlorocyclohexane (gamma-HCH, lindane) was estimated using an enrichment technique based on the ability of soil bacteria to develop on synthetic...Full Text Available

1996-10-01

443

Induction of mortality and malformation in Xenopus laevis embryos by water sources associated with field frog deformities.  

UK PubMed Central (United Kingdom)

Water samples from several ponds in Minnesota were evaluated for their capacity to induce malformations in embryos of Xenopus laevis. The FETAX assay was used to assess the occurrence of malformations...Full Text Available

1998-12-01

444

Highly lytic and persistent lentiviruses naturally present in sheep with progressive pneumonia are genetically distinct.  

UK PubMed Central (United Kingdom)

Ovine and caprine lentiviruses share the capacity to induce slowly progressive and inflammatory diseases of the central nervous system (leukoencephalitis or visna), lungs (progressive pneumonia or maedi),...Full Text Available

1984-11-01

445

Growth, cell division and sporulation in mycobacteria  

UK PubMed Central (United Kingdom)

Bacteria have the ability to adapt to different growth conditions and to survive in various environments. They have also the capacity to enter into dormant states and some bacteria form spores when...Full Text Available

2010-08-01

446

Functional Analysis of the Murine Cytomegalovirus Chemokine Receptor Homologue M33: Ablation of Constitutive Signaling Is Associated with an Attenuated Phenotype In Vivo?  

UK PubMed Central (United Kingdom)

The murine cytomegalovirus (MCMV) M33 gene is conserved among all betaherpesviruses and encodes a homologue of seven-transmembrane receptors (7TMR) with the capacity for constitutive signaling. Previous...Full Text Available

2008-02-01

447

Expression Signatures of Metastatic Capacity in a Genetic Mouse Model of Lung Adenocarcinoma  

UK PubMed Central (United Kingdom)

BackgroundNon-small cell lung cancer (NSCLC) is the foremost cause of cancer-related death in Western countries, which is due partly to the propensity of NSCLC cells to metastasize....Full Text Available

448

Enzymic Capacities of Purified Cauliflower Bud Plastids for Lipid Synthesis and Carbohydrate Metabolism 1  

UK PubMed Central (United Kingdom)

Isolated cauliflower (Brassica oleracea) bud plastids, purified by isopycnic centrifugation in density gradients of Percoll, were found to be highly intact, to be practically devoid...Full Text Available

1985-10-01

449

Differential effects of the mottled yellow and pseudoagouti phenotypes on immunocompetence in Avy/a mice.  

UK PubMed Central (United Kingdom)

Whereas genetic factors are known to influence both susceptibility to carcinogens and the capacity to respond to specific antigenic stimuli, little is known regarding the influence of phenotype per...Full Text Available

1984-04-01

450

Cytokine signalling in rat pulp interstitial fluid and transcapillary fluid exchange during lipopolysaccharide-induced acute inflammation  

UK PubMed Central (United Kingdom)

The dental pulp consists of loose connective tissue encased in rigid dentinal walls. Because of its topography the tissue has low interstitial compliance and limited capacity to expand during fluid...Full Text Available

2006-05-15

451

Controllable synthesis of graphene sheets with different numbers of layers and effect of the number of graphene layers on the specific capacity of anode material in lithium-ion batteries  

International Nuclear Information System (INIS)

High quality graphene sheets are synthesized through efficient oxidation process followed by rapid thermal expansion and reduction by H2. The number of graphene layers is controlled by tuning the oxidation degree of GOs. The higher the oxidation degree of GOs is getting, the fewer the numbers of graphene layers can be obtained. The material is characterized by elemental analysis, thermo-gravimetric analysis, scanning electron microscopy, atomic force microscopy, transmission electron microscopy and Fourier transform infrared spectroscopies. The obtained graphene sheets with single, triple and quintuplicate layers as anode materials exhibit a high reversible capacity of 1175, 1007, and 842 mA h g-1, respectively, which show that the graphene sheets with fewer layers have higher reversible capacity. -- Graphical abstract: The typical TEM images of the graphene sheets derived from GO3(a), GO2(b) and GO1(c). Display Omitted Highlights: ? With the ...

2011-05-01

452

Cognitive Expertise, Emotional Development and Reflective Capacity: Clinical Skills for Improved Pain Care  

UK PubMed Central (United Kingdom)

The overarching goal of medical training is to nurture the growth of knowledgeable, caring and insightful clinicians guided by the ideals of medical professionalism. Recent definitions of professional...Full Text Available

2008-11-01

453

Changes in Rabbit and Cow Lens Shape and Volume upon Imposition of Anisotonic Conditions  

UK PubMed Central (United Kingdom)

In vivo, mammalian lenses have the capacity to effect fully reversible changes in shape, and possibly volume, during the accommodation process. Isolated lenses also change shape...Full Text Available

2009-10-01

454

Caveolin-1 as a Novel Indicator of Wound-Healing Capacity in Aged Human Corneal Epithelium  

UK PubMed Central (United Kingdom)

Excess caveolin-1 has been reported to play a role in age-dependent hyporesponsiveness to growth factors in vitro. Therefore, we hypothesized that caveolin-1–dependent hyporesponsiveness...Full Text Available

2010-11-01

455

Carbon Dioxide Capture Utilizing Solid Sorbents  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is to develop regenerable sorbents that have high selectivity, efficient regenerability, and high adsorption capacity for CO2 over wide temperature ranges. These properties are critical for the success of the PSA/PSS and TSA/TSS processes.

2006-09-01

456

Capacity of staphylococci to grow in the presence of ovotransferrin or CrCl3 as a character of potential pathogenicity.  

UK PubMed Central (United Kingdom)

A total of 150 strains of staphylococci, clinically isolated, were tested for sensitivity to ovotransferrin (conalbumin). Among these, all the 50 coagulase-positive, mannitol-positive, and deoxyribonuclease-positive...Full Text Available

1980-05-01

457

Capacity of deoxycytidine to selectively antagonize cytotoxicity of 5-halogenated analogs of deoxycytidine without loss of antiherpetic activity.  

UK PubMed Central (United Kingdom)

Enzyme kinetic studies from this laboratory (M. Dobersen and S. Greer, Biochemistry 17:920-928, 1978) suggested that deoxycytidine could antagonize the toxicity of 5-halogenated analogs of deoxycytidine...Full Text Available

1982-09-01

458

Bosjesspruit Colliery. [South Africa  

Energy Technology Data Exchange (ETDEWEB)

The reserves and the mine are described. Planned capacity is 27.5 million tonnes per year of coal for the Sasol II and Sasol III liquefaction plants. There will be 7 longwall faces, 15 entry workings with shotfiring, and 19 entries with continuous miners.

1982-02-18

459

Assessment of tumour response in a rat rhabdomyosarcoma.  

UK PubMed Central (United Kingdom)

A rhabdomyosarcoma in a WAG/Rij rat with capacity for colony growth after tumour excision and enzymatic dissociation has been used to study response to high and low LET radiation. End points are tumor...Full Text Available

1980-04-01

460

Arabidopsis thaliana auxotrophs reveal a tryptophan-independent biosynthetic pathway for indole-3-acetic acid.  

UK PubMed Central (United Kingdom)

We used tryptophan auxotrophs of the dicot Arabidopsis thaliana (wall cress) to determine whether tryptophan has the capacity to serve as a precursor to the auxin, indole-3-acetic acid (IAA). Quantitative...Full Text Available

1993-11-01

461

Adjusting output of bucket wheel excavators and belt conveyors in technological mining systems  

Energy Technology Data Exchange (ETDEWEB)

Analyzed are methods for optimizing productivity of coal surface mining systems which consist of bucket wheel excavators, belt conveyors, and dumping conveyors. System productivity depends on adjustment of belt conveyor capacity to productivity of bucket wheel excavators. Factors which influence productivity of bucket wheel excavators are analyzed: dimensions and geometry of bucket wheels, rated power of drive systems for bucket wheels and properties of mined materials (coal or overburden). Indices used in Czechoslovakia for assessing productivity of bucket wheel excavators are compared. Factors which influence capacity of belt conveyors are also analysed: belt dimensions, belt geometry, angle of repose of hauled coal or overburden, and haulage speed of a belt conveyor. Investigations carried out in brown coal surface mines in Czechoslovakia show that conveyor capacity should exceed productivity of bucket wheel excavators. ...

1983-09-01

462

Adipose Tissue Gene Expression of Factors Related to Lipid Processing in Obesity  

UK PubMed Central (United Kingdom)

BackgroundAdipose tissue lipid storage and processing capacity can be a key factor for obesity-related metabolic disorders such as insulin resistance and diabetes. Lipid uptake is...Full Text Available

463

Addressing the Question of the Effect of RBC Storage on Clinical Outcomes: The Red Cell Storage Duration Study (RECESS) (Section 7)  

UK PubMed Central (United Kingdom)

The question of whether storage of red blood cells (RBCs) alters their capacity to deliver oxygen and affects patient outcomes remains in a state of clinical equipoise. Studies of the changes...Full Text Available

2010-08-01

464

A novel approach to exploit LiFePO{sub 4} compound as an ambient temperature high capacity anode material for rechargeable lithium batteries  

Energy Technology Data Exchange (ETDEWEB)

An ever first attempt has been made to investigate the possible anode performance characteristics of LiFePO{sub 4}, popularly known so far as an environmentally compatible and economically viable lithium battery cathode material. The compound LiFePO{sub 4} has been synthesized via solid state method and explored for the first time as an anode material against lithium metal through the present study. Surprisingly, an initial capacity of circa 620 mAh/g has been exhibited by LiFePO{sub 4} anode, which is about 4-5 times higher than the capacity of the corresponding LiFePO{sub 4} cathodes. Also an excellent coulombic efficiency value of 99% has been shown by the compound, especially upon extended cycling. The extraordinarily higher specific capacity values of LiFePO{sub 4} anodes may be exploited suitably for practical lithium battery applications.

2004-11-01

465

A new gene (alkB) of Escherichia coli that controls sensitivity to methyl methane sulfonate.  

UK PubMed Central (United Kingdom)

Seven mutants of Escherichia coli were isolated that are sensitive to methyl methane sulfonate but not to UV light. They exhibited decreased host cell reactivation capacity for methyl methane sulfonate-treated...Full Text Available

1983-03-01

466

A Conserved Role for Phosphoinositide-3-Kinase but Not Akt Signaling in Mitochondrial Adaptations that Accompany Physiological Cardiac Hypertrophy  

UK PubMed Central (United Kingdom)

Physiological cardiac hypertrophy is associated with mitochondrial adaptations that are characterized by activation of PGC-1α and increased fatty acid oxidative (FAO) capacity. It is...Full Text Available

2007-10-01

467

3G279: the interaction of reagent-demulsifiers and oil components  

Energy Technology Data Exchange (ETDEWEB)

The adsorption interaction of different types of demulsifiers and the oils of Western Siberia is covered. The high adsorption capacity of Separol-5084 and disolvan-4490 reagents is established. The positive role of this phenomen in breaking aqueous oil emulsifiers is theoretically substantiated and experimentally confined.

1981-01-01

468

33 CFR 148.105 - What must I include in my application?  

Science.gov (United States)

...capacity, and ownership of all planned and existing onshore pipelines, storage facilities, refineries, petrochemical...will be served by the port, including: (i) Onshore pipelines; (ii) Storage facilities; (iii)...

2010-07-01

469

1996 Hazardous Substances and New Organisms No. 30  

Wastenet

ii) Flammability: (iii) A capacity to oxidise: (iv) Corrosiveness: (v) Toxicity (including chronic ...an explosion or fire: (d) For substances with corrosive properties: (i) To reduce the ...likelihood of any unintended corrosion:(ii) To control the adverse effects of any corrosion:

470

Use of the River Saale cascade in terms of energy supply and water control. Energetische und wasserwirtchaftliche Nutzung der Saale-Kaskade  

Energy Technology Data Exchange (ETDEWEB)

The river Saale cascade consists of seven reservoirs with a total capacity of approx. 415 Mio. m[sup 3]. The entire reservoir system covers a catchment area of 1665 km[sup 2]. The water management tasks extend to the following main fields: flood protection upkeep of minimum water stock, salt load control and power generation. The energy supply capacity of the cascade is mainly used by pumped storage plants. The last of these plants, Hohenwarte II, was put into service in 1963. (orig.)

1993-01-01

471

Upper bounds of fissile fuel yield with fusion breeders  

International Nuclear Information System (INIS)

The maximum fissile fuel production capacity of three conceptual fusion breeder systems is examined on the basis of the dominant isotopic-balance processes. Compact relationships involving system power output, plasma and energy multiplication, and parameters which describe the fuel cycle and neutron spectrum in the blanket are established. It is found that the fusion breeder, as characterized herein, possesses a substantial fissile fuel breeding capacity the extent of which is governed primarily by the neutron spectrum in the conversion blanket and the break-even condition of the plasma. (author).

472

Investigation of subsurface exploration methods for prevailing geologic conditions in South Carolina  

Science.gov (United States)

Subsurface conditions at sites in the coastal plains region of South Carolina were investigated using standard penetration and mechanical quasi-static cone penetration tests. The penetration test results are compared with measured static axial pile capacity. The cone penetration test results are compared with stratigraphy and soil types encountered at each site. Results show that with certain limitations, cone penetration test results can be used to assess general stratigraphy and soil type and predict static axial pile capacity with reasonable accuracy.

1985-11-01

473

High-tech hydro: an overview of pumped storage  

Science.gov (United States)

A growing number of pumped storage plants installed within the US brings attention to the increasing significance of pumped storage as a source of electrical generation capacity. Because of the special benefits this technology has to offer, hydroelectric pumped storage is an option that many utilities should consider for the supply of new capacity requirements. This article surveys the development and use of pumped storage in the US, and considers the potential for the future development of this technology. Although some of the problems that have occurred on recent projects highlight the role of pumped storage as a technological proving ground, the article puts forth the view that pumped storage is maturing to play a significant role in US electricity supply.

474

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

Energy Technology Data Exchange (ETDEWEB)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

1992-03-01

475

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

International Nuclear Information System (INIS)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

476

Electricity supply in Germany  

Energy Technology Data Exchange (ETDEWEB)

Data on various aspects of the electric power industry in Germany is presented in this article. A map of high voltage transmission lines used by the public utilities is included, which indicates the fuel used at each power station. Data on power generated by fuel used from 1991 to 1996 is given, and additional or new capacity for 1995 to 1999 is also noted. Other tables detail capital investment in public utilities energy input by fuel source, power capacity by utility or private power stations by energy source, utility ownership and electricity demand by consumer. (UK)

1997-09-01

477

Effect of additives in the positive active mass of lead batteries. Zur Wirkung von Zusaetzen in der positiven Aktivmasse des Bleiakkumulators  

Energy Technology Data Exchange (ETDEWEB)

In order to improve the capacity and service life of cathodes, the effect of carboxy-methyl cellulose, soot, silica gel and fibres was examined. Structural tests and electrical and electro-chemical measurements are used for this. The additives can affect crystallization in the manufacturing stage of the electrodes and can increase the storage capacity for water and the electronic conductivity. They act to stabilize the mass in cyclic operation. Soot additive has little effect on the properties of the electrode, but the other substances increase the service life or the use of the mass. (LU).

1984-01-01

478

Cross-stacked carbon nanotube sheets uniformly loaded with SnO{sub 2} nanoparticles: a novel binder-free and high-capacity anode material for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

SnO{sub 2}-carbon nanotube (CNT) composite sheets are synthesized using poly(vinylpyrrolidone) to uniformly load a monolayer of SnO{sub 2} nanoparticles onto the surfaces of CNTs and CNT bundles within cross-stacked CNT sheets. When they are used as high-capacity (over 850 mA h g{sup -1}) and binder-free anodes in rechargeable lithium-ion batteries, they exhibit good cycle performance. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

2009-06-12

479

CaSnO3:. a high capacity anode material for Li-ion batteries  

Science.gov (United States)

Calcium stannate (CaSnO3) powders with the distorted perovskite structure have been synthesized by solid state and the sol-gel methods and their electrochemical performance was compared. The sol-gel CaSnO3 shows stable cycling performance with a reversible capacity of 430-440 mAh/g (0.005-1.0 V; 60 mA/g) up to 50 cycles. The role of preparatory conditions, morphology and cycling conditions (current density and potential window) on the anodic performance of the compounds are addressed.

2002-12-01

480

A study on convective heat transfer with microcapsulated lauric acid slurry in circular pipe  

Energy Technology Data Exchange (ETDEWEB)

The objective of the present study is to reveal thermal characteristic of microcapsulated lauric acid slurry in circular pipe. Test were performed with microcapsulated lauric acid slurry in a heating test section with a constant heat flux boundary condition. Local Nusselt number and the effective thermal capacity were measured. As the size of microcapsulated lauric acid were increased, local Nusselt number of microcapsulated lauric acid slurry were increased. The effective thermal capacity of microcapsulated lauric acid slurry was 0.5 times than it of water.

2003-07-01

481

A high capacity, template-electroplated Ni-Sn intermetallic electrode for lithium ion battery  

British Library Electronic Table of Contents (United Kingdom)

In this paper we describe a Ni-Sn intermetallic material obtained via template electroplating synthesis. The structure and the morphology of this material are investigated by X ray diffraction (XRD) and Scanning Electron Microscopy (SEM) analyses. We demonstrate that Ni-Sn behaves as a sub-micrometric electrode showing a favourable response when cycled in a lithium cell. The results here reported suggest that the template electroplating is a promising synthetic approach that can lead to an optimized structure and morphology of the Ni-Sn electrode, such as to confer it a role of a high capacity anode in advanced lithium ion batteries.

2011-01-01

482

Technology base research on zinc/air battery systems: Final report  

Energy Technology Data Exchange (ETDEWEB)

The capacity extension of additives was tested in a 200 cm/sup 2/bi-cell and a Zn powder moving-bed slurry. It was found that for the Type A additives in 12 M KOH, 25 g/l of silicate provided higher capacity than stannate, titanate and aluminate additives. The optimum concentration of sorbitol (a Type B additive that stabilizes polymeric chains involving ZnO) was found to be 15 g/l in 12 M KOH. A silicate and sorbitol combination added to Zn powder slurry in 12 M KOH provided a 20% increase in discharge capacity (195 Ah/l at 200 A/cm/sup 2/) compared to the maximum capacity obtained with silicate alone. A much lower capacity (74 Ah/l) was realized with silicate as Type C additive (precipitation of ZnO away from the Zn surface, for low KOH concentrations). The mechanisms of passivation and capacity extension were discussed and a model presented. The cell voltage ...

1987-09-01

483

Regeneration of granular activated carbon using hydrothermal technology  

Energy Technology Data Exchange (ETDEWEB)

The economic feasibility of using granular activated carbon (GAC) to remove organic contaminants from industrial and municipal wastewater is contingent upon its reuse during multiple adsorption-regeneration cycles. The most common process for the regeneration of GAC is the thermal method. Drawbacks associated with thermal regeneration include a 5--10% loss of carbon due to oxidation and attrition, a decrease in adsorption capacity, and high energy costs. The purpose of this study was to investigate the regeneration of GAC using hydrothermal technology. Phenol contaminated and non-contaminated GAC samples were regenerated using supercritical water (411 deg C and 26.2 MPa) with dissolved oxygen concentrations of 0 mg/L, 5 mg/L, and 100 mg/L. For comparative purposes, GAC was regenerated using subcritical water (300 deg C and 12.4 MPa) with a dissolved oxygen concentration of 5 mg/L. Regenerated GAC samples were evaluated in terms of adsorption ...

1999-05-01

484

Molar heat capacities for (2-methyl-2-butanol + heptane) mixtures and cyclopentanol at temperatures from (284 to 353) K  

International Nuclear Information System (INIS)

Isobaric specific heat capacities were measured for (2-methyl-2-butanol + heptane) mixtures and cyclopentanol within the temperature range from (284 to 353) K, and for 2-methyl-2-butanol in the (284 to 368) K temperature interval by means of a differential scanning calorimeter. The excess molar heat capacities were calculated from the experimental results. For the temperature range from (284 to 287) K, the excess molar heat capacity is S-shaped with negative values in the 2-methyl-2-butanol rich region and with small negative values at low alcohol concentrations at temperatures from (295 to 353) K. The excess molar heat capacities are positive for all compositions under test at temperatures from (288 to 294) K. The results are explained in terms of the influence of the molecular size and configuration of the alkanols on their self-association capability and of the change in molecular structure of the ...

2009-03-01

485

Ultraviolet radiation in Finland  

Energy Technology Data Exchange (ETDEWEB)

Solar ultraviolet radiation is damaging for living organisms due to its high energy pro each photon. The UV radiation is often separated into three regions according to the wavelength: UVC (200-280 nm), UVB (280-320 nm) and UVA (320-400 nm). The most hazardous part, UVC is absorbed completely in the upper atmosphere by molecular oxygen. UVB radiation is absorbed by atmospheric ozone partly, and it is reaching Earth`s surface, as UVA radiation. Besides atmospheric ozone, very important factors in determining the intensity of UVB radiation globally are the solar zenith angle and cloudiness. It may be calculated from global ozone changes that the clear-sky UVB doses may have enhanced by 10-15 % during spring and 5-10 % during summer at the latitudes of Finland, following the decrease of total ozone between 1979-90. The Finnish ozone and UV monitoring activities have become a part of international activities, especially the EU Environment and ...

1996-12-31

486

The use of calcium silicate bricks for retrospective dosimetry  

International Nuclear Information System (INIS)

The suitability of calcium silicate bricks (CSBs) for the retrospective measurement of gamma dose using luminescence techniques has been investigated. Bricks of this type are distinguished from fired clay bricks by containing negligible clay and requiring comparatively low temperature treatment during manufacture. They have been used widely in the construction f buildings in the Former Soviet Union since the 1970s but hitherto have not been used for retrospective dosimetry measurements. A procedure based on the se of the 210 deg. C thermoluminescence (TL) peak of quartz was tested with granular quartz extracted from three types of CSB, one of which had been taken from a settlement downwind of Chernobyl. The degree to which the residual geological TL signal within the temperature range of the 210 deg. C L peak had been reduced during manufacture varied with brick type; the levels of residual TL corresponded, in the samples tested, to absorbed doses n the range ...

2004-02-01

487

Role of HCl in adsorption of elemental mercury vapor by calcium-based sorbents. Report for September 1998--May 1999  

Energy Technology Data Exchange (ETDEWEB)

The paper gives results of a study to identify active sites and surface functional groups that may contribute to the absorption of elemental mercury (Hg) by relatively inexpensive calcium (Ca)-based sorbents. The study investigated the formation of chlorine (Cl) sites in CA-based sorbents as well as their role and reactivity in the absorption of Hg. HCl-exposed calcium sulfate dihydrate (gypsum) exhibited a superior Hg sorption capability. Crystalline water molecules on the surface of the gypsum were confirmed to contribute indirectly to Hg uptake. These surface molecules may have absorbed HC1 through hydrogen bond formation between an oxygen atom of a crystalline water molecule and a hydrogen atom of an HCl molecule. Two adjacent, physically absorbed HCl molecules could then trap an Hg molecule through formation of a mercuric-chloride-like molecule. Significant correlations between Cl and Hg uptake by gypsum were noted.

1999-11-01

488

Role of HCl in adsorption of elemental mercury vapor by calcium-based sorbents. Report for September 1998--May 1999  

Energy Technology Data Exchange (ETDEWEB)

The paper gives results of a study to identify active sites and surface functional groups that may contribute to the absorption of elemental mercury (Hg) by relatively inexpensive calcium (Ca)-based sorbents. The study investigated the formation of chlorine (Cl) sites in CA-based sorbents as well as their role and reactivity in the absorption of Hg. HCl-exposed calcium sulfate dihydrate (gypsum) exhibited a superior Hg sorption capability. Crystalline water molecules on the surface of the gypsum were confirmed to contribute indirectly to Hg uptake. These surface molecules may have absorbed HC1 through hydrogen bond formation between an oxygen atom of a crystalline water molecule and a hydrogen atom of an HCl molecule. Two adjacent, physically absorbed HCl molecules could then trap an Hg molecule through formation of a mercuric-chloride-like molecule. Significant correlations between Cl and Hg uptake by gypsum were noted.

1999-01-01

489

Radon concentrations and absorbed dose measurements in a Pleistocenic cave  

International Nuclear Information System (INIS)

Radon concentration measurements were carried out using solid-state nuclear track-etch detectors (SSNTDs) type CA 80-15 cellulose nitrate films, in a Pleistocenic cave at Petralona, in Halkidiki, Northern Greece, at 55 km from the city of Thessaloniki. Radon levels as high as 88 kBqxm"-"3 (2.38 nCi x l"-"1) have been recorded inside the cave equivalent to 11.90 WL in terms of occupational exposure to radon and its decay products. Absorbed dose rates were performed using TL dosimeters, type TLD-200 (CaF_2-Dy) in a continuous monitoring program (integrated measurements). Dose rate levels as high as 110 nGy x h"-"1 were recorded inside the cave. In interpreting the high levels of radiation doses, radioactivity measurements regarding the naturally occurring "2"3"8U, "2"3"2Th and "4"0K radionuclides were carried out in various speleothems found at different sites in the cave. (author)

2003-10-01

490

Method of treating final products from flue gas desulfurization  

Science.gov (United States)

A method of treating final products from a flue gas desulfurization. The flue gas desulfurization is carried out by the absorption of sulfur oxide in a spray dryer with a suspension which contains lime, or in a reactor with a dry, fine-grained, absorbent which contains lime. Prior to desulfurization, the fly ash carried along by the flue gas which is to be desulfurized is separated entirely, partially, or not at all from the flue gas, and the final products from the flue gas desulfurization, prior to any further treatment thereof, amount to 1-99% by weight, preferably 1-70% by weight, of fly ash, and 1-99% by weight, preferably 30-99% by weight, of the sum of the desulfurization products, preferably calcium sulfite hemihydrate, and/or calcium sulfite, and/or calcium sulfate dyhydrate, and/or calcium sulfate hemihydrate, and/or calcium sulfate, as well as residue of the absorbent. The reduction of the amount of calcium sulfite is implemented by ...

1984-10-23

491

Medical irradiation and the use of the 'effective dose equivalent' concept  

International Nuclear Information System (INIS)

By applying the linear-dose effect relation, the weighting factors for total risks recommended by IRCP can be transformed to weighting factors for somatic effects. Another weighting factor Msub(s) has to be used which takes into account the dependence of the latent period for occurrence of malignant disease and the variation of the incidence with time. On this basis a somatically significant dose equivalent can be defined as 'the dose equivalent which if received by every member of the population, would be expected to produce the same total somatic injury to the population as does the actual dose equivalent received by the various individuals', and an approximation has been derived for this. Tables are presented of the somatic effective dose equivalents calculated for different x-ray examinations for various organs and tissues. The S.E.D. equivalents have also been calculated for some of the most frequent radiopharmaceutical examinations, together with the absorbed ...

1980-03-01

492

Measuring characteristics on emissivity using infrared thermometer for RCCS  

International Nuclear Information System (INIS)

In VHTGR (Very High Temperature Gas-cooled Reactor), the radiation plays an important role in heat transfer through the cavity in RCCS (Reactor Cavity Cooling System). We performed the series of experiments to measure the emissivity using the infrared thermometer with wavelength range of 8#approx#14 #mu#m. As the first step, the transmittance of Zinc Selenide (ZnSe) window was measured to estimate the emissivity that can compensate the attenuation effect of window. The kind of gas with various concentrations in the cavity will be released during postulated accidents to the coolant type, so it is essential to estimate the effects of gas on the measurement of emissivity. In this manner we measured the emissivity with the air, the helium and the steam inside chamber. The results represent that the concentration of the air and the helium do not affect the emissivity significantly while the steam decreases the measured emissivity relatively. It means that the air and the helium do not ...

2004-12-01

493

Laboratory differential simulation design method of pressure absorbers for carbonization of phenolate solution by carbon dioxide in coal-tar processing  

Energy Technology Data Exchange (ETDEWEB)

A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and toluene is added. These conditions have the following favourable effects: (I) significant size reduction of ...

2009-01-15

494

Histological changes in the ovaries of the females in three filial generations of spodoptera littoralis (boisd.) after being irradiated as full- grown Male pupae  

International Nuclear Information System (INIS)

the cotton leaf worm, Spodoptera littoralis (boisd.) were irradiated with 100,150 and 200 Gy to induce inherited sterility. the effects of the tested doses applied to these pupae through three consequent fillial generations and the retarded influence on their F_1,F_2 and F_3 generations progeny were examined . irradiation of parental male induced damage to their daughter females ovaries. the overioles of females among P_1 ,F_1 and F_2 generations showed that the follicular epithelial cells appeared abnormal beside their limited separation from developing oocytes which became shrinked, semi absorbed or completely absorbed leaving vacuoles. the nurse cells were reduced or absent in some parts. damage was obvious through the first and second generations especially at 150 and 200 Gy. in the third generation, ovaries were not greatly affected

2004-02-01

495

Geometry optimization of Fresnel-collectors with economic assessment  

Energy Technology Data Exchange (ETDEWEB)

The Fresnel solar collector is a promising concept to reduce the electricity cost price in solar thermal power plants. The optical performance of a Fresnel collector depends on material properties, on its geometric layout and on the level of optical accuracy that can be obtained. A variety of geometric parameters, e.g. the height of the absorber, the number, size and distance of primary mirrors in.uence the shading and blocking of rays and the amount of rays missing the absorber. To evaluate the in.uence of the parameter variation regarding the electricity cost price and to yield an optimization, the optical performance is assessed with an annual simulation based on hourly weather-data. To permit a consideration of changes in collector cost according to different geometric layouts, cost factors where allocated to geometric parameters. The paper presents the method and the simulation results of the optimization under different boundary ...

2004-07-01

496

Fuel bundle geometry and composition influence on coolant void reactivity reduction in ACR and CANDU reactors  

International Nuclear Information System (INIS)

It is very well known that the CANDU reactor has positive Coolant Void Reactivity (CVR), which is most important criticisms about CANDU. The most recent innovations based on using a thin absorbent Hafnium shell in the central bundle element were successfully been applied to the Advanced CANDU Reactor (ACR) project. The paper's objective is to analyze elementary lattice cell effects in applying such methods to reduce the CVR. Three basic fuel designs in their corresponding geometries were chosen to be compared: the ACR-1000TM, the RU-43 (developed in INR Pitesti) and the standard CANDU fuel. The bundle geometry influence on void effect was also evaluated. The WIMS calculations proved the Hafnium absorber suitability (in the latest 'shell design') to achieve the negative CVR target with great accuracy for the ACR-1000 fuel bundle design than for the other two projects. (authors)

2009-05-27

497

Development of Improved Burnable Poisons for Commercial Nuclear Power Reactors  

Energy Technology Data Exchange (ETDEWEB)

Burnable poisons are used in nuclear reactors to produce a more level distribution of power in the reactor core and to reduce to necessity for a large control system. An ideal burnable poison would burn at the same rate as the fuel. In this study, separation of neutron-absorbing isotopes was investigated in order to eliminate isotopes that remain as absorbers at the end of fuel life, thus reducing useful fuel life. The isotopes Gd-157, Dy-164, and Er-167 were found to have desirable properties. These isotopes were separated from naturally occurring elements by means of plasma separation to evaluate feasibility and cost. It was found that pure Gd-157 could save approximately $6 million at the end of four years. However, the cost of separation, using the existing facility, made separation cost- ineffective. Using a magnet with three times the field strength is expected to reduce the cost by a factor of ten, making isotopically separated burnable ...

2003-09-30

498

Antenna organization in green photosynthetic bacteria. Progress report, March 1986--February 1987  

Energy Technology Data Exchange (ETDEWEB)

This project is concerned with the structure and function of the unique antenna system found in the green photosynthetic bacteria. The antenna system in these organisms is contained within a vesicle known as a chlorosome, which is attached to the cytoplasmic side of the cell membrane. Additional antenna pigments and reaction centers are contained in integral membrane proteins. Energy absorbed by the bacteriochlorophyll c (BChl c) pigments in the chlorosome is transferred via a ``baseplate`` array of BChl a antenna pigments into the membrane and to the reaction center. This system is similar in some respects to the phycobilisome antenna system found in cyanobacteria and some types of algae, in that a membrane-associated structure absorbs light and transfers it to the membrane where conversion to chemical energy takes place. However, the overall structure, the type of pigments utilized and the nature of the proteins in these two types of ...

1987-12-31

499

An alternative explanation of the COBE data  

Energy Technology Data Exchange (ETDEWEB)

The COBE data on cosmic background radiation (CBR) isotropy and spectrum are generally considered to be explicable only in the context of the Big Bang theory and to be confirmation of that theory. However, this data can also be explained by an alternative, non-Big Bang model which hypothesizes an intergalactic radio-absorbing and scattering medium. Dense, force-free magnetic filaments generated by quasars, active galactic nuclei and Herbig-Haro objects can remain stable in the intergalactic medium for many Gy. They will be opaque to radiation with wavelengths longer than 100--400 microns, and essentially transparent to shorter wavelengths. They are thus capable of thermalizing and isotropizing the cosmic background radiation, and of accounting for the observed decrease of radio luminosity of galaxies within increasing distance from earth. A simple, inhomogeneous model of such an absorbing medium can reproduce both the isotropy and spectrum of ...

1994-12-31

500

A lysimeter study of nitrate leaching, optimum fertilisation rate and growth responses of corn (Zea mays L.) following soil amendment with water-saving super-absorbent polymer  

British Library Electronic Table of Contents (United Kingdom)

Abstract BACKGROUND: Nitrate leaching and the resulting groundwater contamination from intensive cereal production has become a major concern for long-term farmland efficiency and environmental sustainability in northern China. The aim of this study was to evaluate a water-saving super-absorbent polymer (SAP) for minimising NO3- leaching from soil and optimising corn growth and yield. Thirty-six undisturbed soil lysimeters were installed in a field lysimeter facility in drought-affected northern China to study the growth and yield characteristics of summer corn (Zea mays L.) as well as the amount of NO3-leaching losses under different fertiliser (standard, medium or 75% and low, or 50% of conventional fertilisation rate) and SAP (control, 0; level-1, 15 kg ha-1 and level-2, 30 kg ha-1) tre...

2011-01-01