WorldWideScience
1

Linearized augmented-plane-wave method for quasi-unidimensional systems: Carbyne and nanotube (Sc@C{sub 20})  

Energy Technology Data Exchange (ETDEWEB)

The advent of carbon nanotubes, which are graphite layers convoluted in cylinders several nanometers in diameter and several micrometers in length, as well as the experiments on implanting metal atoms in such tubes open the way to producing nanoconductors and other materials with unique properties. For theorists, the basic challenge is interpreting and predicting the structure and properties of these systems. The linearized augmented-plane-wave method (LAPW) is one of the most accurate methods in the theory of the electronic structure of solids. A generalization of this method for quasi-two-dimensional systems, surface electronic states, and layered crystals is known. The LAPW theory for quasi-unidimensional systems, which exhibit translational symmetry in one direction, has been absent thus far. In this paper, the authors suggest a version of such a theory and use this method to calculate the electronic structure of carbyne (a linear chain of ...

1995-10-01

2

Possible Stratification Mechanism in Granular Mixtures  

CERN Document Server

We propose a mechanism to explain what occurs when a mixture of grains of different sizes and different shapes (i.e. different repose angles) is poured into a quasi-two-dimensional cell. Specifically, we develop a model that displays spontaneous stratification of the large and small grains in alternating layers. We find that the key requirement for stratification is a difference in the repose angles of the two pure species, a prediction confirmed by experimental findings. We also identify a kink mechanism that appears to describe essential aspects of the dynamics of stratification.

1997-01-01

3

Effects of linear, ambient wind shear on simulated mammatus-like clouds  

British Library Electronic Table of Contents (United Kingdom)

A suite of numerical experiments is conducted to extend our previous studies to explore the effects of linear, ambient wind shear on simulated mammatus-like clouds. Increasing values of unidirectional shear result in banded cloud bases, and for the strongest shears roll-type quasi-two-dimensional convection results rather than three-dimensional lobe morphology. Two observed soundings were used, and the sounding with a drier, shallower sub-cloud layer appeared to be most strongly affected by the presence of the ambient shear. The drier sounding also had less snow in the mammatus lobes owing to sublimation. Copyright Copyright 2009 Royal Meteorological Society

2009-01-01

4

Nonlinear air-coupled emission: The signature to reveal and image microdamage in solid materials  

International Nuclear Information System (INIS)

It is shown that low-frequency elastic vibrations of near-surface planar defects cause high-frequency ultrasonic radiation in surrounding air. The frequency conversion mechanism is concerned with contact nonlinearity of the defect vibrations and provides efficient generation of air-coupled higher-order ultraharmonics, ultrasubharmonics, and combination frequencies. The nonlinear air-coupled ultrasonic emission is applied for location and high-resolution imaging of damage-induced defects in a variety of solid materials.

2007-12-17

5

Numerical study of thermoelectric characteristics of a planar solid oxide fuel cell with direct internal reforming of methane  

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional mathematical thermo-fluid model coupling the electrochemical kinetics with fluid dynamics was developed to simulate the heat and mass transfer in planar anode-supported solid oxide fuel cell (SOFC). The internal reforming reactions and electrochemical reactions of carbon monoxide and hydrogen in the porous anode layer were analyzed. The temperature, species mole fraction, current density, overpotential loss and other performance parameters of the single cell unit were obtained by a commercial CFD code (Fluent) and external sub-routine. Results show that the current density produced by electrochemical reactions of carbon monoxide cannot be ignored, the cathode overpotential loss is the biggest one among the three overpotential losses, and that the proper decrease of the operating voltage leads to the increase of the current density, PEN structure temperature, fuel utilization factor, fuel efficiency and power output of the ...

2009-01-15

6

Quantum frustration in organic Mott insulators: from spin liquids to unconventional superconductors  

CERN Document Server

We review the interplay of frustration and strong electronic correlations in quasi-two-dimensional organic charge transfer salts, such as k-(BEDT-TTF)_2X and Et_nMe_{4-n}Pn[Pd(dmit)2]2. These two forces drive a range of exotic phases including spin liquids, valence bond crystals, pseudogapped metals, and unconventional superconductivity. Of particular interest is that in several materials there is a direct transition as a function of pressure from a spin liquid Mott insulating state to a superconducting state. Experiments on these materials raise a number of profound questions about the quantum behaviour of frustrated systems, particularly the intimate connection between spin liquids and superconductivity. Insights into these questions have come from a wide range of theoretical techniques including first principles electronic structure, quantum many-body theory and quantum field theory. In this review we introduce the basic ideas of the field by discussing a simple ...

2010-01-01

7

Study on the crystallization behaviour and thermal stability of glass-ceramics used as solid oxide fuel cell-sealing materials  

British Library Electronic Table of Contents (United Kingdom)

Glass ceramics are commonly used as sealing materials for planar solid oxide fuel cells (SOFCs). The major requirements of stack and module builders for these materials are the stability of the coefficient of thermal expansion (CTE), excellent bonding (sticking) behaviour and the absence of volatile ingredients, which can lead to changes of the material properties and the sealing ability. SCHOTT Electronic Packaging has developed special glasses and glass-ceramics for various solid oxide fuel cell designs and operating temperatures. The glass compositions are based on the system MgO-Al2O3-BaO-SiO2-B2O3. In this study the evaluation of the developed materials was done by high temperature aging tests for up to 1000h, high temperature XRD-studies and Rietveld calculations, combined with scann...

2011-01-01

8

SOLID OXIDE FUEL CELL HYBRID SYSTEM FOR DISTRIBUTED POWER GENERATION  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the work performed by Honeywell during the October 2001 to December 2001 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a turbogenerator. The conceptual and demonstration system designs were proposed and analyzed, and these systems have been modeled in Aspen Plus. Work has also started on the assembly of dynamic component models and the development of the top-level controls requirements for the system. SOFC stacks have been fabricated and performance mapping initiated.

2003-08-01

9

Solid oxide fuel cells (Part 2)  

Energy Technology Data Exchange (ETDEWEB)

The project has been developing Yttria Stabilized Zirconia (YSZ)-Alumina Composites as an electrolyte of a self-support type planar Solid Oxide Fuel Cell (SOFC) from the following points of view: a path of alumina particles with high thermal conductivity can be designed as an electrolyte sheet; there are some possibilities that the electrolyte can be enhanced in mechanical strength. As previously reported, these composite materials have higher mechanical strength and better thermal shock resistance than those of YSZ. These composites containing 0-30 wt% of Al[sub 2]O[sub 3] were measured by AC impedance method at temperatures of 250-1,000[degree]C. Electrical conductivities of 8YSZ without Al[sub 2]O[sub 3] and a composite consisting of 80 wt% YSZ and 20 wt%Al[sub 2]O[sub 3] as sintered samples were 1.2 x 10[sup -1]S/cm and 1.0 x 10[sup -1]S/cm respectively at 1,000[degree]C. The composite containing 20 wt% of Al[sub 2]O[sub 3] is the most ...

1993-01-01

10

Effects of electric current pulse on stability of solid/liquid interface of Al-4.5wt.% Cu alloy during directional solidification  

British Library Electronic Table of Contents (United Kingdom)

This paper investigates the effects of the electric current pulse (ECP) on the interface stability of Al-4.5% Cu alloy during the directional solidification. Experimental results show both the cellular spacing and the mushy zone depth decrease with increasing current density, moreover, the solid-liquid interface morphology transforms from dendritic to cellular or even planar interface. The secondary dendrites are suppressed due to the homogeneous distribution of the solute and the increase of temperature gradient originated from ECP. The decrease of the cellular spacing results from branching of the cellular tip caused by Joule heat of the current exerting on cellular tip.

2007-01-01

11

3-D CFD MODEL OF A MULTI-CELL HIGH TEMPERATURE ELECTROLYSIS STACK  

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional computational fluid dynamics (CFD) electrochemical model has been created to model high-temperature electrolysis stack performance and steam electrolysis in the Idaho National Laboratory (INL) Integrated Lab Scale (ILS) experiment. The model is made of 60 planar cells stacked on top of each other operated as Solid Oxide Electrolysis Cells (SOEC). Details of the model geometry are specific to a stack that was fabricated by Ceramatec, Inc. and tested at INL. Inlet and outlet plenum flow and distribution are considered. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT. A solid-oxide fuel cell (SOFC) model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user defined subroutine was modified for this work to allow for operation in the SOEC mode. ...

2009-05-01

12

Development of a Novel Efficient Solid-Oxide Hybrid for Co-generation of Hydrogen and Electricity Using Nearby Resources for Local Application  

Energy Technology Data Exchange (ETDEWEB)

Developing safe, reliable, cost-effective, and efficient hydrogen-electricity co-generation systems is an important step in the quest for national energy security and minimized reliance on foreign oil. This project aimed to, through materials research, develop a cost-effective advanced technology cogenerating hydrogen and electricity directly from distributed natural gas and/or coal-derived fuels. This advanced technology was built upon a novel hybrid module composed of solid-oxide fuel-assisted electrolysis cells (SOFECs) and solid-oxide fuel cells (SOFCs), both of which were in planar, anode-supported designs. A SOFEC is an electrochemical device, in which an oxidizable fuel and steam are fed to the anode and cathode, respectively. Steam on the cathode is split into oxygen ions that are transported through an oxygen ion-conducting electrolyte (i.e. YSZ) to oxidize the anode fuel. The dissociated hydrogen and residual ...

2009-06-30

15

A structure modeling of metal-silicide layers by using axial and planar channeling techniques  

International Nuclear Information System (INIS)

Planar channeling effects are studied in such well-oriented polycrystalline layers as NiSi_2 and Pb_2Si layers formed on single crystalline Si. Crystalline perfection of such layers is discussed by using the energy- and angular dependences of the axial and planar channeling yields. It has been shown that, in suitable conditions, the energy dependence of the planar yield is more sensitive to the spread of crystallite orientations in polycrystals than that of the axial one. (Auth.).

17

A dinuclear Ni(I) system having a diradical Ni2N2 diamond core resting state: synthetic, structural, spectroscopic elucidation, and reductive bond splitting reactions.  

Science.gov (United States)

One-electron reduction of the square-planar nickel precursor (PNP)NiCl ( 1) (PNP (-) = N[2-P(CHMe 2) 2-4-methylphenyl] 2) with KC 8 effects ligand reorganization of the pincer ligand to assemble a Ni(I) dimer, [Ni(mu 2-PNP)] 2 ( 2), containing a Ni 2N 2 core structure, as inferred by its solid-state X-ray structure. Solution magnetization measurements are consistent with a paramagnetic Ni(I) system likely undergoing a monomer dimer equilibrium. The room-temperature and 4 K solid-state X-band electron paramagnetic resonance (EPR) spectra display anisotropic signals. Low-temperature solid-state X-band EPR data at 4 K reveal rhombic values g z = 1.980(4), g x = 2. 380(4), and g y = 2.225(4), as well as a forbidden signal at g = 4.24 for the Delta M S = 2 half field transition, in accord with 2 having two weakly interacting metal centers. Utilizing an S = 1 model, full spin Hamiltonian simulation of the ...

2008-10-15

18

Palladium(II) and platinum(II) saccharinate complexes containing pyridine and 3-acetylpyridine: Synthesis, crystal structures, fluorescence and thermal properties  

British Library Electronic Table of Contents (United Kingdom)

New palladium(II) and platinum(II) complexes of saccharinate (sac), trans-[Pd(py)"2(sac)"2] (1), cis-[Pt(py)"2(sac)"2] (2), trans-[Pd(3-acpy)"2(sac)"2] (3) and cis-[Pt(3-acpy)"2(sac)"2] (4) (py=pyridine and 3-acpy=3-acetylpyridine) have been synthesized. Elemental analysis, UV-Vis, IR, NMR and TG/DTA characterizations have been carried out. The structures of 1-4 were determined by X-ray diffraction. The palladium(II) and platinum(II) ions are coordinated by two N-bonded sac ligands, and two nitrogen atoms of py or 3-acpy, forming a distorted square-planar geometry. The palladium(II) complexes (1 and 3) are trans isomers, while the platinum(II) complexes (2 and 4) are cis isomers. The mononuclear species in the solid state are connected by weak intermolecular C-H...O hydrogen bonds, C-H...@...

2011-01-01

21

Recovering quantum graphs from their Bloch spectrum  

CERN Document Server

We define the Bloch spectrum of a quantum graph to be the collection of the spectra of a family of Schr\\"odinger operators parametrized by the cohomology of the quantum graph. We show that the Bloch spectrum determines the Albanese torus, the block structure and the planarity of the graph. It determines a geometric dual of a planar graph. This enables us to show that the Bloch spectrum completely determines planar 3-connected quantum graphs.

2011-01-01

22

Effects of coal syngas and H{sub 2}S on the performance of solid oxide fuel cells. Part 2. Stack tests  

Energy Technology Data Exchange (ETDEWEB)

The performance of two-cell planar solid oxide fuel cell stacks using coal syngas, with and without hydrogen sulfide (H{sub 2}S), was studied. All cells were tested at 850 C with a constant current load of 15.2 A (current density of 0.22 A cm{sup -2} per cell) and 30% fuel utilization. The H{sub 2}S injection immediately and significantly affected the power degradation of the stack system regardless of the carrier fuel. Results for the test with only H{sub 2} and N{sub 2} in the presence of H{sub 2}S (119-120 ppm) indicated that the power decay and area-specific resistance (ASR) degradation values were lower than those for the tests where simulated syngas containing CO and increased water content was used. The results indicate that contact points in the stack contributed to the power degradation of the system. Other factors, including contamination from the upstream fuel gas tubing, may have contributed to the higher degradation under simulated ...

2007-02-10

23

Synthesis, structure, and spectroscopic properties of ortho-metalated platinum(II) complexes  

Energy Technology Data Exchange (ETDEWEB)

The ortho-metalated Pt(II) complexes Pt(ppy)(CO)Cl (1), Pt(ptpy)(CO)Cl (2), and Pt(ppy)(Hppy)Cl (3) (where ppy and ptpy are respectively the ortho-C-deprotonated forms of 2-phenylpyridine and 2-p-tolylpyridine and Hppy is 2-phenylpyridine) have been prepared. The CO ligand is coordinated trans to the nitrogen atom of the ortho-metalated ligand and exerts a strong trans effect resulting in a relatively long Pt-N bond [2.114(19) {angstrom}]. This structure shows both the bidentate ppy ligand and the monodentate Hppy with the nitrogens of these ligands trans to each other. The UV/vis electronic absorption spectra of 1-3 have intense bands in the near-UV region ({approximately}375 nm) which have been assigned as metal to ligand charge transfer (MLCT) transitions, and higher energy bands were assigned as ligand-centered transitions. Each complex exhibits relatively long-lived structured emissions in the solid state at ambient temperature and at 77 K and 77 K glassy ...

1995-04-26

24

ESR study of the aziridine and azetidine radical cations: evidence for the C...C ring-opened aziridine radical cation  

International Nuclear Information System (INIS)

The radical cations from aziridine and azetidine have been characterized by ESR spectroscopy following their generation in the solid state by #gamma# irradiation of dilute solutions of the parent compounds in the CFCl_3 matrix at 77 K. The ESR parameters of the azetidine radical cation are typical of those for nitrogen-centered amine radical cations such as Me_2NH*"+. On the other hand, the radical cation formed from aziridine has very different ESR parameters that compare closely to those for the isoelectronic C...C ring-opened form of the oxirane radical cation and the allyl radical. The radical cation formed from azetidine is therefore assigned a ring-closed structure with the unpaired electron in a 2p/sub z/ orbital on nitrogen perpendicular to the ring plane, whereas the cation from aziridine is an allylic C...C ring-opened planar isomer with the unpaired electron in a nonbonding #pi# orbital centered mainly on the two end carbon atoms. ...

25

ESR study of the aziridine and azetidine radical cations: evidence for the C. C ring-opened aziridine radical cation  

Energy Technology Data Exchange (ETDEWEB)

The radical cations from aziridine and azetidine have been characterized by ESR spectroscopy following their generation in the solid state by ..gamma.. irradiation of dilute solutions of the parent compounds in the CFCl/sub 3/ matrix at 77 K. The ESR parameters of the azetidine radical cation are typical of those for nitrogen-centered amine radical cations such as Me/sub 2/NH*/sup +/. On the other hand, the radical cation formed from aziridine has very different ESR parameters that compare closely to those for the isoelectronic C...C ring-opened form of the oxirane radical cation and the allyl radical. The radical cation formed from azetidine is therefore assigned a ring-closed structure with the unpaired electron in a 2p/sub z/ orbital on nitrogen perpendicular to the ring plane, whereas the cation from aziridine is an allylic C...C ring-opened planar isomer with the unpaired electron in a nonbonding ..pi.. orbital centered mainly on the two ...

1986-05-22

26

Influence of defects in compound single crystals on the critical angle of planar channeling  

Energy Technology Data Exchange (ETDEWEB)

The theoretical treatment of the relation between the critical angle of planar channeling and the characteristics of crystal lattice defects is carried out. The predictions are made about some typical forms of the critical angle dependence on the mean-square static displacement produced by defects, and then these predictions are detailed for the cases of homogeneous disordering, spherical clusters of point defects and dislocation loops. Analytical results are supported by the exact computer calculations for the defects in the intermetallic A-15 compounds.

1985-01-01

27

Strange as it may seem: the many links between Wnt signaling, planar cell polarity, and cilia  

UK PubMed Central (United Kingdom)

Cilia are important cellular structures that have been implicated in a variety of signaling cascades. In this review, we discuss the current evidence for and against a link between cilia and both the...Full Text Available

2011-02-01

28

Mapping Proprioception across a 2D Horizontal Workspace  

UK PubMed Central (United Kingdom)

Relatively few studies have been reported that document how proprioception varies across the workspace of the human arm. Here we examined proprioceptive function across a horizontal planar workspace,...Full Text Available

29

Cerebral scintigraphy--the phoenix rises again.  

UK PubMed Central (United Kingdom)

This paper reviews the development of cerebral scintigraphy from its early days of planar imaging with simple technetium-99m labelled compounds to the recent revival of the technique in the form of...Full Text Available

1988-01-01

30

Single-shot diffusion-weighted echo-planar imaging of normal and cirrhotic livers using a phased-array multicoil  

Energy Technology Data Exchange (ETDEWEB)

Single-shot spin-echo diffusion-weighted echo-planar imaging using a phased-array multicoil was performed to distinguish between normal and cirrhotic livers. Sets of 6 images with different b-value were acquired with breath-holding. Significant differences were observed between controls and cirrhosis cases in the signal ratios when the b-value was 383 s/mm{sup 2}, and apparent diffusion coefficients. (orig.)

1998-07-01

31

Modified spontaneous emission rate in three-dimensional layer-by-layer photonic crystals with planar defects  

Science.gov (United States)

A finite three-dimensional layer-by-layer photonic crystal with planar defects in a layer is shown to drastically modify the spontaneous emission rate of an embedded dipole. Finite-difference time-domain calculations with one quarter symmetric boundary condition and perfectly matched layer demonstrate the strong enhancement effects induced by the cavity resonance of defect modes and band-edge resonant modes. Simulation shows that the emission spectra are quite different when the position or polarization of the dipole is changed. Moreover, the extraction efficiency is calculated to observe the percentage of light leakage through a substrate.

2010-01-01

32

High efficiency planar MCLEDs  

Energy Technology Data Exchange (ETDEWEB)

The physics of microcavities have been a subject of intense study over the past 25 years. This work stimulated a large body of experimental and theoretical work on the optimization of the light extraction properties of light-emitting diodes. Not only has this led to the current high efficiency microcavity LEDs but also to the high brightness LEDs based on other approaches, which are presently available on the market. An overview of the state of the art of planar semiconductor microcavity LEDs will be presented. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2005-09-01

33

A primer on elliptic functions with applications in classical mechanics  

CERN Document Server

The Jacobi and Weierstrass elliptic functions used to be part of the standard mathematical arsenal of physics students. They appear as solutions of many important problems in classical mechanics: the motion of a planar pendulum (Jacobi), the motion of a force-free asymmetric top (Jacobi), the motion of a spherical pendulum (Weierstrass), and the motion of a heavy symmetric top with one fixed point (Weierstrass). The problem of the planar pendulum, in fact, can be used to construct the general connection between the Jacobi and Weierstrass elliptic functions. The easy access to mathematical software by physics students suggests that they might reappear as useful tools in the undergraduate curriculum.

2007-01-01

38

Solid state chemistry in catalysis  

Energy Technology Data Exchange (ETDEWEB)

Correlations between structural aspects of solid materials and their behavior as catalysts are relatively recent. This 20-chapter book focuses on understanding of solid-state mechanisms in heterogeneous catalysis and relationship between catalytic behavior and solid state structure, emphasizing catalysis with oxides, sulfides, and zeolites.

1985-01-01

41

A simple dynamic model for solid transport in rotary dryers  

Energy Technology Data Exchange (ETDEWEB)

The solid particle movement in a rotary drum plays an important role in drying processes. The solid distribution in the drum affects the amount of contact surface between the solid and the gas. The retention time of solids influences the time particles can stay in contact with the gas in order to transfer heat and mass. Any heat and mass transfer model for a solid particle dryer must be able to predict solid flowrate and solid hold-up. There have been several reports in the literature regarding the modeling aspects of solid transport in dryers. If the model is developed for model-based control, it must be simple and yet represent dynamics of the system accurately. This paper addresses solid motion modeling and the effects of different variables involved in solid transport ...

2000-05-01

42

Radioanalytical methods of rare earth element determination  

International Nuclear Information System (INIS)

Instrumental neutron activation analysis (INAA) and radionuclide X-ray fluorescence analysis (RXFA) were used for the determination of rare earth elements. For INAA, solution obtained by sample decomposition was dripped onto filter paper, enclosed and sealed into a polyethylene foil. The sample was activated in reactor WWR-S over a period of 4 to 6 hours with a neutron fluence of 10"1"3cm"-"2. Gamma radiation measurement was carried out with a planar and a coaxial HP-Ge detector in three decay periods. La, Ce, Nd, Sm, Eu, Gd, Tb, Ho, Tm, Yb and Lu were determined. The advantage of the method is its accuracy and high sensitivity, the disadvantage is the time-consuming analysis. The RXFA method was used as a rapid and operative method for the analysis of loose ore samples, aqueous and organic solutions of rare earth elements. For exciting X-ray radiation, "2"4"1Am was used and the radiation of K-lines was detected with a planar Si(Li) detector. ...

1989-06-01

43

Task Statement - NEPP - NASA  

Science.gov (United States)

Commercial introduction of new polymer materials for use as the electrolyte in solid tantalum and solid aluminum electrolytic capacitors is underway. ...

44

Control of Effluent Gases from Solid Waste Processing Using Carbon Nanotubes  

Science.gov (United States)

One of the major problems associated with solid waste processing technologies is the release of

2005-01-01

45

A Review of Test Medium Contamination Effects on Test ...  

Science.gov (United States)

... solid particle contamination. Solid particulate impact is a good mechanism for surface heat transfer augmentation. The aug ...

1998-01-01

46

Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences  

British Library Electronic Table of Contents (United Kingdom)

Executive summaryForewordPublic awareness of solid-state chemistry, or more broadly solid-state science and technology rapidly grew along with the transistor revolution and the development of the integrated circuit. We are now at the half-way point in the solid state century [Scientific American The Solid-State Century 1997;8(1) [special issue

2008-01-01

47

Occurence of active layer optical properties on some Lasing characteristics dye-doped Ch LC  

CERN Document Server

Effect of a planar texture quality and its thickness on lasing spectrums and thresholds in dye-doped cholesteric liquid crystal (CLC) of steroid type is explored. Transition from the qualitative planar texture to the poor texture quality is accompanied by change of characteristic mode structures and by shift of barycentre in the long-wave side and the considerable growth of the lasing threshold. It is found that in the CLC texture created by substrates with perpendicular directions of orientation the stable single-mode lasing takes place. The nature of oscillated modes in such texture is caused by phase jump. The gained results show that in steroid CLC, unlike induced one, lasing spectrums is possible to feature with the coupled wave model. Key words: steroidal cholesteric liquid crystal, distributed feedback lasing, oscillation thresholds, phase defect of periodical structure, transmission and lasing spectra

2010-01-01

48

Approximate convolution with pairs of cubic B?zier LN curves  

British Library Electronic Table of Contents (United Kingdom)

In this paper we present an approximation method for the convolution of two planar curves using pairs of compatible cubic B?zier curves with linear normals (LN). We characterize the necessary and sufficient conditions for two compatible cubic B?zier LN curves with the same linear normal map to exist. Using this characterization, we obtain the cubic spline approximation of the convolution curve. As illustration, we apply our method to the approximation of a font where the letters are constructed as the Minkowski sum of two planar curves. We also present numerical results using our approximation method for offset curves and compare our method to previous results.

2011-01-01

49

A planar circular detector based on multiple point chemi- or bio-luminescent source within a coaxial cylindrical reactor  

British Library Electronic Table of Contents (United Kingdom)

An analytical method was proposed for calculating radiative fluxes incident on a planar circular detector from a volume multiple point chemi- or bio-luminescent source inside a coaxial cylindrical reactor. The method was designed for a cylindrical reactor when the surface reflections were neglected and when chemi- or bio-luminescence reaches a detector embedded in the same homogeneous optical medium as the point emitters of the volume multiple point source model. The radiative fluxes from arbitrarily distributed point emitters were expressed by one generalized quadruple-integral formula. Then some double- and single-integral formulas were obtained for calculating radiative fluxes from identically radiating point emitters uniformly distributed within the reactor. Selected results were compu...

2009-01-01

50

Preparation and characterization of a novel polymeric based solid-solid phase change heat storage material  

International Nuclear Information System (INIS)

Here we reported a two-step procedure for preparing a novel polymeric based solid-solid phase change heat storage material. Firstly, a copolymer monomer containing a polyethylene glycol monomethyl ether (MPEG) phase change unit and a vinyl unit was synthesized via the modification of hydrogen group of MPEG. Secondly, by copolymerization of the copolymer monomer and phenyl ethylene, a novel polymeric based solid-solid phase change heat storage material was prepared. The composition, structure and properties of the novel polymeric based solid-solid phase change material were characterized by IR, "1H NMR, DSC, WAXD, and POM, respectively. The results show that the novel polymeric based solid-solid phase change material possesses of excellent crystal properties and high phase change enthalpy.

2009-06-01

51

Void growth and softening of a single crystal with strain gradient effects  

Energy Technology Data Exchange (ETDEWEB)

The strain gradient crystal plasticity theory is applied to study the deformation of planar single crystal with a void under a nominally uniaxial tension. The crystal theory assumes elevated strain hardening due to slip gradients and has a constitutive length scale. The effects of the void size with respect to the constitutive length scale on the single crystal deformation are investigated.

1997-02-06

52

Study of fitness-for-purpose criteria shows promise for pipeline girth-weld quality  

Energy Technology Data Exchange (ETDEWEB)

This article illustrates what typical accept/reject curves might look like and discusses progress made in developing the required inspection techniques for flaw dimensioning. Consideration is given to the relative significance of blunt versus planar types of flaws, and of inherent limitations to the depths of certain types of flaws. Finally, consideration is given to the realities of implementing proposed procedures under field conditions. These are summarized in a series of technical options for implementation of program results.

1983-07-01

53

Results for the structural properties of random heaps of hard disks  

Energy Technology Data Exchange (ETDEWEB)

The average angle of repose and the packing density of random planar heaps of hard disks falling ballistically onto a sticky base line, where the first layer of disks is quenched in random positions, are computed for heaps with a small fixed number of gaps in the base layer. The results we find appear to be almost independent of the size of the heap and they agree with those obtained from computer simulations of large systems.

1995-01-01

54

Polarization characteristics of spontaneous emission and off-axis coherent gain in a free-electron laser  

Energy Technology Data Exchange (ETDEWEB)

The polarization characteristics of spontaneous radiation from relativistic electrons moving through helical and planar wiggler fields are evaluated for imperfect beam injection. Maximum coherent gain in free-electron laser systems are seen to occur in optical fields having these polarization characteristics rather than those of the wiggler magnets. Coupling coefficients for an electron beam skewed at an angle to the optical mode are presented.

1995-11-01

55

Fibre coupled dual-mode waveguide interferometer with $\\lambda $/130 fringe spacing  

CERN Document Server

Predictions and measurements of a multimode waveguide interferometer operating in a fibre coupled, ``dual-mode'' regime are reported. With a 1.32 micrometer source, a complete switching cycle of the output beam is produced by a 10.0 nanometer incremental change in the 8.0 micrometer width of the hollow planar mirror waveguide. This equates to a fringe spacing of $\\sim\\lambda /130$. This is an order of magnitude smaller than previously reported results for this form of interferometer.

2008-01-01

56

A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.  

Science.gov (United States)

Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316

2011-08-11

57

A Spindle Cell Predominant Pancreatic Solid-pseudopapillary Tumor  

UK PubMed Central (United Kingdom)

A hitherto unrecognized variant of solid-pseudopapillary tumor (SPT) of the pancreas is reported. The tumor presented in the pancreatic tail of a 44-year-old female patient. It was a well-defined, solid...Full Text Available

2008-08-30

58

40 CFR 261.2 - Definition of solid waste.  

Science.gov (United States)

...2009-07-01 false Definition of solid waste. 261.2 Section 261.2 Protection...PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.2 Definition...

2009-07-01

59

Study of radiation chemistry in solids using solid hydrogen  

Energy Technology Data Exchange (ETDEWEB)

Having simple and highly symmetric structure, solid hydrogen is a useful matrix on the study of radiation-chemical processes in solid phase which have been less understood in previous studies. We have found three outstanding findings: resonance effects on the tunneling reaction H+H{sub 2} {yields} H{sub 2} + H, effects of pressure on the dissociation and recombination of H{sub 2} molecules in solid hydrogen, and high-resolution ESR spectroscopy using a solid parahydrogen matrix. (author)

2002-03-01

60

Study of cytomorphology of solid pseudopapillary tumor of pancreas and its differential diagnosis  

UK PubMed Central (United Kingdom)

Background:Solid pseudopapillary tumor is a rare pancreatic neoplasm with uncertain to low malignant potential. This is an uncommon neoplasm with many pseudonyms, occurring...Full Text Available

2010-10-01

61

Solid serous microcystic adenoma of the pancreas  

UK PubMed Central (United Kingdom)

BackgroundCystic neoplasms of the pancreas are less common than solid tumors, and portend a better prognosis. They can be divided into serous and mucinous subtypes, with the former...Full Text Available

62

Solid Waste & Financial Assistance Program  

Science.gov (United States)

This program deals with solid waste disposal with topics/services covering: Reusable Building Materials and Large Household Items Exchange, Beneficial Use Determination, Biosolids, Certification, Compost Facil...

63

Gasless Combustion of Solid Fuel Mixtures  

International Science & Technology Center (ISTC)

Investigation of the Macrokinetics and Energy of Self-Oscillatory Processes of Gasless Combustion of Solid Fuel Mixtures Proposed for the Design of Short-Term Thermal and Electrical Sources

64

A Theoretical Solid Oxide Fuel Cell Model for - The NASA Glenn ...  

Science.gov (United States)

May 31, 2011 ... A Theoretical Solid Oxide Fuel Cell Model for System Controls and Stability Design AUTHOR(S): Kopasakis, George; Brinson, Thomas; Credle, ...

66

Integrated Models for Solid Waste Management in Tourism Regions: Langkawi Island, Malaysia  

Science.gov (United States)

The population growth, changing consumption patterns, and rapid urbanization contribute significantly to the growing volumes of solid waste that are generated in urban settings. As the rate of urbanization increases, demand on the services of solid waste management increases. The rapid urban growth in Langkawi Island, Malaysia, combined with the increasing rates of solid waste production has provided evidence that the traditional solid waste management practices, particularly the methods of waste collection and disposal, are inefficient and quite nonsustainable. Accordingly, municipal managers and planners in Langkawi need to look for and ...

2011-09-04

67

Structure and evolution of the stabilization point of a lifted reacting jet  

Energy Technology Data Exchange (ETDEWEB)

In this work the authors study the stabilization point of a lifted, reacting jet of nitrogen diluted methane in co-flowing air. The jet flow is acoustically forced so as to organize the large scale vortical structures. The validation of the numerical results is possible through a concurrent experimental investigation of a similar planar jet. The use of an acoustically forced planar jet allows for significant savings by the restriction of the computation to two dimensions; the model is otherwise applicable in three dimensions. The authors based their study on the following parameters, which are derived from the experimental setup: a jet width of 1.16 cm, a mean jet velocity of 0.8 m/s, and a coflow velocity of 0.1 m/s. The acoustical forcing is studied at frequencies of 7.5 MHz and 90 MHz, which have been established experimentally as being characteristic of two broad behavioral modes. The authors restrict themselves to five species and the ...

1997-11-01

68

Soil heterogeneity effects on O2 distribution and CH4 emissions from wetlands: In situ and mesocosm studies with planar O2 optodes and membrane inlet mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

The importance of soil heterogeneity for methane emission from a wetland soil is assessed by in situ point measurements of depth-specific O2 and CH4 concentrations and simultaneous soil CH4 fluxes at contrasting water levels. Profile measurements, and associated assumptions in their interpretation, were validated in a controlled mesocosm drainage and saturation experiment applying planar O2 optodes and membrane inlet mass spectrometry. Results show that peat soil is heterogeneous containing dynamic macropore systems created by both macrofauna and flora, which facilitate preferential flow of water, O2 and CH4 and vary temporally with changes in the moisture regime. The O2 content above the water table after drainage varied horizontally from 0 to 100% air saturation within few mm. Oxic zones...

2010-01-01

69

Optimizing the acquisition time profile for a planar integral measurement system with a spinning slat collimator  

International Nuclear Information System (INIS)

This article considers a hypothetical imaging device with a spinning slat collimator that measures parallel-planar-integral data from an object. This device rotates around the object 180 deg. and stops at N positions uniformly distributed over this 180 deg. . At each stop, the device spins on its own axis 180 deg. and acquires measurements at M positions uniformly distributed over this 180 deg. . For a fixed total imaging time, an optimal distribution of the scanning time among the data measurement locations is searched by a nonlinear programming method: Nelder-Mead's simplex method. The optimal dwell time is approximately proportional to the weighting factor in the backprojector of the reconstruction algorithm. By using an optimal dwell-time profile, the reconstruction signal-to-noise ratio has a gain of 23%-24% for the filtered backprojection algorithm and a gain of 10%-18% for the iterative algorithms, compared with the situation when a constant dwell-time ...

2005-09-01

70

Non-Riemannian geometrical asymmetrical damping stresses on the Lagrange instability of shear flows  

CERN Document Server

It is shown that the physical interpretation of Elie Cartan three-dimensional space torsion as couple asymmetric stress, has the effect of damping, previously Riemannian unstable Couette planar shear flow, leading to stability of the flow in the Lagrangean sense. Actually, since the flow speed is inversely proportional to torsion, it has the effect of causing a damping in the planar flow atenuating the instability effect. In this sense we may say that Cartan torsion induces shear viscous asymmetric stresses in the fluid, which are able to damp the instability of the flow. The stability of the flow is computed from the sectional curvature in non-Riemannian three-dimensional manifold. Marginal stability is asssumed by making the sectional non-Riemannian curvature zero, which allows us to determine the speeds of flows able to induce this stability. The ideas discussed here show that torsion plays the geometrical role of magnetic field in ...

2007-01-01

71

Low-dose O3+ ion-implanted active optical planar waveguides in Nd : YAG crystals: guiding properties and micro-luminescence characterization  

International Nuclear Information System (INIS)

We report, for the first time to our knowledge, on the active optical planar waveguides in Nd : YAG laser crystals fabricated by O3+ ion implantation at low doses of ?1014 ions cm-2. The reconstructed refractive index profiles based on the measured dark-mode spectroscopy show that an enhanced refractive index well is created in the near-surface region, forming a non-leaky waveguide structure. With thermal annealing treatment at 260 0C for 90 min, the propagation losses of the waveguides could be reduced to ?3 dB cm-1 at a wavelength of 632.8 nm. The micro-luminescence investigation reveals that the emission bands of Nd3+ ions are not significantly affected by the waveguide formation processing, which shows promising potentials for efficient waveguide laser operations at near-infrared wavelength bands.

2008-09-07

72

Hydrogen embrittlement of Ni-Cr-Fe alloys  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work was to investigate the role of chromium on hydrogen embrittlement of Ni-Cr-Fe alloys and thus to develop a better understanding of the low-temperature stress corrosion cracking (SCC) phenomenon. The effect of chromium on hydrogen embrittlement was examined using tensile tests followed by material evaluation via scanning electron microscopy (SEM) and light optical microscopy. Four alloys were prepared with chromium contents ranging from 6 to 35 wt pct. In the uncharged condition, ductility, as measured by the percent elongation or reduction in area, increased as the alloy chromium content increased. Hydrogen appeared to have only minor effects on the mechanical properties of the low-chromium alloys. The addition of hydrogen had a marked effect on the ductility of the higher-chromium alloys. In the 26 pct chromium alloy, the elongation to failure was reduced from 53 to 14 pct, with a change in fracture mode from mixed ductile dimple and ductile intergranular ...

1997-03-01

73

Disjoint Empty Convex Pentagons in Planar Point Sets  

CERN Document Server

Harborth [{\\it Elemente der Mathematik}, Vol. 33 (5), 116--118, 1978] proved that every set of 10 points in the plane, no three on a line, contains an empty convex pentagon. From this it follows that the number of disjoint empty convex pentagons in any set of $n$ points in the plane is least $\\lfloor\\frac{n}{10}\\rfloor$. In this paper we prove that every set of 19 points in the plane, no three on a line, contains two disjoint empty convex pentagons. We also show that any set of $2m+9$ points in the plane, where $m$ is a positive integer, can be subdivided into three disjoint convex regions, two of which contains $m$ points each, and another contains a set of 9 points containing an empty convex pentagon. Combining these two results, we obtain non-trivial lower bounds on the number of disjoint empty convex pentagons in planar points sets. We show that the number of disjoint empty convex pentagons in any set of $n$ points in the plane, no three on a line, is at ...

2011-01-01

74

Crystalline O,O'-di-sec-butyl and O,O'-diethyl dithiophosphate platinum(II) complexes: Synthesis, 13C and 31P CP/MAS NMR, single crystal X-ray diffraction studies and thermal behaviour  

British Library Electronic Table of Contents (United Kingdom)

Crystalline bis(O,O'-di-sec-butyldithiophosphato)platinum(II) was prepared and studied by means of 13C, 31P CP/MAS NMR spectroscopy and single-crystal X-ray diffraction. The unit cell of the platinum(II) compound is comprised of one centrosymmetric mononuclear molecule [Pt{S2P(O-sec-C4H9)2}2], in which the dithiophosphate groups display structural equivalence in both 31P NMR and XRD data. A pair of the dithiophosphate ligands exhibit the same S,S'-bidentate chelating structural function and form two planar four-membered chelate rings, [PtS2P], in this molecule. The planar configuration of the [PtS4] chromophore in structure 1 is governed by the dsp2-hybrid state of platinum(II). The structural states of the dithiophosphate groups in two different samples of complex 1 (one crystallised from...

2011-01-01

75

Characterization of 3D thermal neutron semiconductor detectors  

International Nuclear Information System (INIS)

Neutron semiconductor detectors for neutron counting and neutron radiography have an increasing importance. Simple silicon neutron detectors are combination of a planar diode with a layer of an appropriate neutron converter such as 6LiF. These devices have limited detection efficiency of not more than 5%. The detection efficiency can be increased by creating a 3D microstructure of dips, trenches or pores in the detector and filling it with a neutron converter. The first results related to the development of such devices are presented. Silicon detectors were fabricated with pyramidal dips on the surface covered with 6LiF and then irradiated by thermal neutrons. Pulse height spectra of the energy deposited in the sensitive volume were compared with simulations. The detection efficiency of these devices was about 6.3%. Samples with different column sizes were fabricated to study the electrical properties of 3D structures. Charge collection efficiencies in silicon ...

2007-06-11

76

An approximated secondary CPC, built of planar facets, adjustable for two solar central receivers  

Energy Technology Data Exchange (ETDEWEB)

Decreasing the aperture of a solar central receiver operating at high temperatures contributes significantly to the increase of the efficiency of energy absorption. However, decreasing the aperture also decreases the collection efficiency. A simple solution is using a 3D-CPC as secondary element for augmenting the energy collection, while the aperture can remain relatively small. Nevertheless, the receiver aperture as well as the secondary concentrator are usually rather large. For practical considerations an approximate solution may be chosen at times, designing the concentrator by a series of truncated cones. However, in particular cases, the solution of truncated cones remains expensive and unpractical and therefore the authors designed a CPC approximated by a series of trapezoidal planar facets. Under technical restrictions, there is an optimum for choosing the partition of the pure-CPC in truncated pyramids and the paper presents the method for a good ...

1994-12-31

77

The application of advanced techniques for complex focused-ion-beam device modification  

Energy Technology Data Exchange (ETDEWEB)

Advanced techniques for focused-ion-beam (FIB) device modification have been developed for complex, multistep modifications to circuitry on planar chip technology. Applying gas-assisted etching (GAE) techniques for high-aspect-ratio milling and the selective milling of both conductive and insulating films enhances process latitude. Localized ion-beam-induced deposition of an insulating film provides reconstructive capability in previously modified areas. The application of both techniques for complex device modification on VSLI devices fabricated with CMOS process technology is reviewed. (UK).

1996-12-31

78

Regenerative zinc/air and zinc/ferricyanide batteries for stationary power applications  

Energy Technology Data Exchange (ETDEWEB)

The authors report a novel configuration for a zinc-particle, packed-bed anode in which an open structure of high hydraulic permeability is maintained indefinitely in a cell with closely spaced walls by the formation of particle bridges and associated gaps. The configuration minimizes electrolyte pumping costs, allows rapid refueling and partial recharge, and provides for 100% zinc consumption. This approach benefits zinc/air fuel batteries by allowing nearly continuous operation and fuel recycle without commercial infrastructure; it benefits Zn/[Fe(CN){sub 6}]{sup {minus}3} batteries by eliminating shape-change and polarization problems found with planar anodes.

1994-05-01

79

Perturbation solution to heat conduction in melting or solidification with heat generation  

Science.gov (United States)

The Stefan problem involving a source term is considered in this technical note. As an example, planar solidification with time-dependent heat generation in a semi-infinite plane is solved by use of a perturbation technique. The perturbation solution is validated by reducing the problem to the case without heat generation whose exact solution is available. An application to the case with constant heat generation is presented, for which a closed-form solution is obtained. The effects of heat generation and Stefan number on the evolution of solidification are examined using the perturbation solution.

2010-04-01

80

Parameter optimization of a planar BEGe detector using Monte Carlo simulations  

International Nuclear Information System (INIS)

This work reports on the use of three state-of-the-art Monte Carlo codes (MCNPX, PENELOPE, FLUKA) in the efficiency calibration of a Broad-Energy Germanium (BEGe) detector. Initial discrepancies found between the experimental and computational efficiency values are related to the poor knowledge of some physical parameters of the detector (dead-layers, crystal dimensions, etc.). As a consequence, a sensitivity analysis was carried out. Each parameter was systematically analyzed, and an accurate model of the detector was determined. The obtained results are consistent, allowing this model to be used in computational efficiency calibrations of the equipment at stake.

2010-11-21

81

Method of the cementing of material  

Energy Technology Data Exchange (ETDEWEB)

Invention relates to woodworking industry and concerns method of cementing of materials of foam plastic with duralumin, glued plywood, etc. Known methods of cementing of materials by effect of electromagnetic field of superhigh frequencies are unproductive and do not make it possible to cement parts on the plane. Target of invention - acceleration of process of cementing of planar, including of complex configuration, parts and assemblies from wood, foam plastic, duralumin, glued plywood and other materials. For this material is cemented under the effect of directed electromagnetic field of superhigh frequency in the range 01-50 GHz, the specific power of 0.5-15 W/cm3.

1990-10-30

82

MITL - A 2-D code to investigate electron flow through non-uniform field region of magnetically insulated transmission lines  

Science.gov (United States)

Self-magnetically insulated, high-voltage transmission lines are used in inertial confinement fusion particle accelerators in order to transmit power from the vacuum insulator to the diode. This paper describes a time-dependent 2-D code (MITL) for calculating (for planar or triplate geometries) the motion of test electrons through the tapered input or output convolutes of such lines. MITL results show that the electron canonical momentum in the direction of the flow changes as the electron passes through the convoluted geometry; it is suggested that these electrons lead to losses observed in long self-magnetically insulated lines.

1979-01-01

83

Engineering electromagnetic response of composite terahertz metamaterial with broken symmetry  

Science.gov (United States)

We proposed and numerically investigated the influence of spatial symmetry on the terahertz frequency region response of composite planar metamaterials based on deformed split ring resonators. Compared with the original simple structures, the composite metamaterials with different spatial symmetries exhibited exotic electromagnetic properties. The electromagnetic response of a specific configuration with C4 symmetry was identical to the structure with simple lattice. Especially, for configurations with broken symmetry, very sharp Drude-like resonances with high quality factor were observed. The electric field and current distribution associated the resonances were analyzed for deep understanding of the underlying physical properties.

2011-09-01

84

Emission of photons by electrons and positrons passing through a thin single crystal  

Energy Technology Data Exchange (ETDEWEB)

We consider the radiation of particles (electrons and positrons) undergoing planar channeling in a single crystal of small thickness L. We show that for Lapprox...pi..b/theta/sub L/, where b is the lattice constant and theta/sub L/ is the Lindhard angle, in addition to the principal maxima of spontaneous radiation of channeled particles in the spectrum there are additional interference maxima, and the positions of all maxima of the radiation intensity depend on L. We discuss the dependence of the intensity of radiation at various frequencies on the crystal thickness.

1984-07-01

85

Creation of an antiferromagnetic exchange spring  

Science.gov (United States)

We present evidence for the creation of an exchange spring in an antiferromagnet due to exchange coupling to a ferromagnet. X-ray magnetic linear dichroism spectroscopy on single crystal Co/NiO(001) shows that a partial domain wall is wound up at the surface of the antiferromagnet when the adjacent ferromagnet is rotated by a magnetic field. We determine the interface exchange stiffness and the antiferromagnetic domain wall energy from the field dependence of the direction of the antiferromagnetic axis, the antiferromagnetic pendant to a ferromagnetic hysteresis loop. The existence of a planar antiferromagnetic domain wall, proven by our measurement, is a key assumption of most exchange bias models.

2004-04-06

86

Carbon fiber/epoxy matrix composite springs as self-centering supports: manufacture and evaluation  

Energy Technology Data Exchange (ETDEWEB)

A variety of engineering and experimental applications require primary support structures which are self-centering. High mechanical strength, low-density, carbon fiber/epoxy matrix composite springs are used in unique planar, cylindrical, conical, and spherical configurations to self-center components. The sinusoidal and triangular-shaped composite springs are readily manufactured and assembled into component hardware. Design considerations, flexural strength properties, load bearing and centering data plus procedures for the manufacture of composite springs are presented.

1984-01-01

87

2D Electrostatic Simulation of the Modulated Electron Beam Interaction with Inhomogeneous Plasma  

International Nuclear Information System (INIS)

Electrostatic plasma simulation code for 2D rectangular geometry is presented. Main distinguishing feature of the code is its orientation on the beam-plasma interaction. The code and its graphical interface were developed using MATLAB programming language. Simulation results of inhomogeneous plasma interaction with modulated electron beams of different width are compared. In case of wide beam the front of Langmuir waves generated in point of local plasma resonance is planar and in case of thin beam (or ribbon beam) the front has approximately half-circular form.

2006-01-01

88

Volatilization of fluorides from solid uranium(IV)fluoride  

International Nuclear Information System (INIS)

... deposition evaporation fission products fluorides iodine 134 laboratory

1971-02-01

90

The Growth of an Extrapancreatic Solid Pseudopapillary Tumor from the Greater Omentum: A Case Report  

Energy Technology Data Exchange (ETDEWEB)

A solid pseudopapillary tumor is an uncommon tumor of the pancreas that rarely metastasizes to other organs and usually shows good prognosis. An extrapancreatic tumor arising from a solid pseudopapillary tumor is very rare. We report a case of an atypical extrapancreatic solid pseudopapillary tumor that arose from the great omentum and disseminated to the peritoneum, and discuss the radiologic findings, including the CT, US, and MRI.

2010-01-15

91

The Growth of an Extrapancreatic Solid Pseudopapillary Tumor from the Greater Omentum: A Case Report  

International Nuclear Information System (INIS)

A solid pseudopapillary tumor is an uncommon tumor of the pancreas that rarely metastasizes to other organs and usually shows good prognosis. An extrapancreatic tumor arising from a solid pseudopapillary tumor is very rare. We report a case of an atypical extrapancreatic solid pseudopapillary tumor that arose from the great omentum and disseminated to the peritoneum, and discuss the radiologic findings, including the CT, US, and MRI

2010-01-01

94

Report of the Government Industrial Research Institute, Osaka, No. 388, February 1993. High lithium ion conductive solid electrolytes  

Energy Technology Data Exchange (ETDEWEB)

Research investigating applicability of lithium salts for solid electrolyte batteries was described. The studies included determinations of lithium ion conductivities in solid electrolyte systems based on Li4SiO4, LiTi2(PO4)3, and ceramic materials. Research on all solid state lithium cells utilizing TiS2 NiPS3 electrodes was also reported.

1993-01-01

96

Plasma Technologies for Fuel Processing  

International Science & Technology Center (ISTC)

Plasma Technologies of Solid Fuels Processing for Power Engineering and Metallurgy

103

Gravity settling  

Science.gov (United States)

Solids are separated from a liquid in a gravity settler provided with inclined solid intercepting surfaces to intercept the solid settling path to coalesce the solids and increase the settling rate. The intercepting surfaces are inverted V-shaped plates, each formed from first and second downwardly inclined upwardly curved intersecting conical sections having their apices at the vessel wall.

1979-01-01

106

[sup 123]I-MIBG myocardial scintigraphy in diabetic patients. Relationship with [sup 201]Tl uptake and cardiac autonomic function  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to investigate the influence of diabetic myocardial damage (suspected myocardial damage; SMD) diagnosed by [sup 201]Tl-SPECT and diabetic cardiac autonomic neuropathy (AN) on myocardial MIBG uptake in patients with NIDDM. Eighty-seven diabetic patients divided into four subgroups: 23 with SMD (+) AN (+); 19 with SMD (+) AN (-); 27 with SMD (-) AN (+); 18 with SMD (-) AN (-), and 10 controls were studied. Both planar and SPECT images were taken at 30 minutes (early) and 3 hours (delayed) after [sup 123]I-MIBG injection. The heart to mediastinum uptake ratio (H/M) and washout ratio of [sup 123]I-MIBG (WR) were obtained from both planar images. Similarly, the difference between the [sup 201]Tl image and the [sup 123]I-MIBG image in the total uptake score (TUS) was taken as the difference in the total uptake score ([Delta]TUS) representing cardiac sympathetic denervation without SMD. On both early and delayed ...

1998-12-01

107

Tunable far infrared laser spectroscopy of Van der Waals molecules in a planar supersonic jet expansion  

Energy Technology Data Exchange (ETDEWEB)

The gas phase high resolution spectroscopic study of weakly bound clusters can provide the information necessary to develop an intermolecular potential energy surface. This surface can then be used to better understand condensed phases. In this work, a tunable far infrared laser spectrometer is used to study weakly bound dimers produced in the newly developed continuous planar supersonic jet expansion apparatus. The water dimer is an extensively studied hydrogen bonded dimer. It undergoes several tunneling motions which result in splittings and perturbations of the rovibrational energy levels. A review is presented of much of the experimental and theoretical work done on water dimer, including a description of the combined fit of all the high resolution spectroscopic results by Coudert and Hougen. Also included is a discussion of the measurement of the K = 1 lower {yields} K = 2 lower band performed using the tunable far infrared laser/planar ...

1990-12-01

108

Solids distribution in tall tanks  

British Library Electronic Table of Contents (United Kingdom)

Abstract Uniformly distributing slurry solids in -tall- (-2:1 aspect ratio) process vessels is a significant challenge in the chemical industry. This work determined the performance of various multi-tier agitation systems in uniformly distributing a settling solid throughout water in a -tall- laboratory vessel. It used a 0.445-m ID Plexiglas tank, with a slurry height of 0.889-m, to determine how solids distribution changes with solids loading (wt.%), impeller speed, and impeller type. Some impeller types uniformly distributed the solids even before energy input exceeded 1.00-W/kg. Significantly higher energy improved solids distribution little because flow within the vessel eventually became choked.

2011-01-01

109

Solid state alkali metal-halogen cell  

Energy Technology Data Exchange (ETDEWEB)

A solid electrolyte cell comprises an alkali metal anode, e.g. lithium, a halogen-containing organic polymer cathode and a solid elecrolyte between the anode and the cathode. The cathode comprises iodine-containing vacuum-cyclised polyacrylonitrile, and the solid electrolyte is preferably lithium iodide and halogen-free vacuum-cyclised polyacrylonitrile. This patent also discloses the use of isotactic polyacrylonitrile, a method of making a cathode comprising iodine-containing vacuum-cyclised polyacrylonitrile, and novel methods of making the solid elecrolyte cells described.

1988-04-26

110

Anaerobic digestion of municipal solid waste: Technical developments  

Energy Technology Data Exchange (ETDEWEB)

The anaerobic biogasification of organic wastes generates two useful products: a medium-Btu fuel gas and a compost-quality organic residue. Although commercial-scale digestion systems are used to treat municipal sewage wastes, the disposal of solid organic wastes, including municipal solid wastes (MSW), requires a more cost-efficient process. Modern biogasification systems employ high-rate, high-solids fermentation methods to improve process efficiency and reduce capital costs. The design criteria and development stages are discussed. These systems are also compared with conventional low-solids fermentation technology.

1996-01-01

111

Two-Phase Stefan Problem with Interfacial Energy and Entropy.  

Science.gov (United States)

The classical Stefan theory for the melting of a solid or the freezing of a liquid is too simplistic to describe phenomena such as supercooling, in which a liquid supports temperatures below its freezing point, or superheating, the analog for solids, or d...

1985-01-01

112

Towards the solid-state rechargeable battery  

Energy Technology Data Exchange (ETDEWEB)

The Anglo-Danish programme of research on materials for advanced vehicular transport and other storage batteries is about to enter its fifth year. Here, the results of the work to date on solid electrolytes, electrode materials and cell design are reviewed and discussed as a systematic programme of cell testing gets underway.

1981-12-11

113

Solid-state 13C NMR spectroscopy of a 13C carbonyl-labeled polypeptide  

UK PubMed Central (United Kingdom)

High resolution structural elucidation of macromolecular structure by solid-state nuclear magnetic resonance requires the preparation of uniformly aligned samples that are isotopically labeled. In...Full Text Available

1992-06-01

114

Simulation of solid molecular hydrogen - a new twist to an old problem  

British Library Electronic Table of Contents (United Kingdom)

Solid molecular orthohydrogen exhibits orientational order at low temperatures. The orthohydrogen molecules, which are quadrupoles, order in the Pa3 structure. We have simulated this ordering, and explored the behaviour under dilution by spherical parahydrogen molecules.

2010-01-01

115

Quantum computing with solids  

Energy Technology Data Exchange (ETDEWEB)

Science and technology could be revolutionized by quantum computers, but building them from solid-state devices will not be easy. Robert W Keyes of IBM's research division outlines the challenges in scaling up the technology from lab experiments to practical devices. (U.K.)

2002-08-01

116

Process Waste Assessment for inorganic solid waste and empty containers <30 gallons  

Energy Technology Data Exchange (ETDEWEB)

This Process Waste Assessment was conducted to evaluate the two largest hazardous waste streams generated on-site at Sandia National Laboratory (SNL)/California -- ``Other Inorganic Solid Waste`` and ``Empty Containers <30 Gallons.``

1993-12-01

117

Prevention of guanine modification and chain cleavage during the solid phase synthesis of oligonucleotides using phosphoramidite derivatives.  

UK PubMed Central (United Kingdom)

Phosphoramidite reagents can phosphitylate guanine bases at the O6-position during solid phase synthesis and serious chain cleavage occurs if the base phosphitylation is not eliminated before the iodine/water...Full Text Available

1986-08-26

118

Pathological differential diagnosis of solid-pseudopapillary neoplasm and endocrine tumors of the pancreas  

UK PubMed Central (United Kingdom)

AIM: To investigate differential points of solid-pseudopapillary neoplasm (SPN) of the pancreas and pancreatic endocrine tumor (PET).METHODS: Ten cases of SPN and fourteen cases of PET were studied...Full Text Available

2010-02-28

119

Observations on the use of solid-phase-coupled antibodies in the radioimmunoassay of human placental lactogen  

UK PubMed Central (United Kingdom)

A detailed comparative assessment was made of the use of solid-phase-coupled antibodies in radioimmunoassay, by using an assay for human placental lactogen as a model system. The major advantages of...Full Text Available

1974-03-01

120

Membrane protein biosensing with plasmonic nanopore arrays and pore-spanning lipid membranes  

UK PubMed Central (United Kingdom)

Integration of solid-state biosensors and lipid bilayer membranes is important for membrane protein research and drug discovery. In these sensors, it is critical that the solid-state sensing...Full Text Available

2010-01-01

121

Inelastic x-ray scattering of dense solid oxygen: Evidence for intermolecular bonding  

UK PubMed Central (United Kingdom)

The detailing of the intermolecular interactions in dense solid oxygen is essential for an understanding of the rich polymorphism and remarkable properties of this element at high pressure. Synchrotron...Full Text Available

2008-08-19

122

Division of Materials Research Employment Opportunities for Program Directors--Dear Colleague Letter  

Science.gov (United States)

... materials science and engineering, condensed-matter or materials physics, solid-state or materials ... include materials theory, condensed-matter and materials physics, solid-state and materials ...

123

Cytological diagnosis of a rare case of solid pseudopapillary neoplasm of the pancreas  

UK PubMed Central (United Kingdom)

A 23-year-old woman presented to our hospital with nonspecific pain in the abdomen. She underwent radiological investigations, which revealed a solid and cystic mass in the tail end of the pancreas....Full Text Available

2010-01-01

124

Comparative Inhibitory Effects of Antigen and Antibody in the Staphylococcal Enterotoxin Solid-Phase Radioimmunoassay System  

UK PubMed Central (United Kingdom)

A solid-phase radioimmunoassay employing 125I-labeled enterotoxins and polystyrene tubes coated with specific antibody has been developed for assaying the relative concentrations of antibodies...Full Text Available

1975-06-01

125

Clinical Strategy for the Management of Solid Pseudopapillary Tumor of the Pancreas: Aggressive or Less?  

UK PubMed Central (United Kingdom)

Objective: To further delineate the clinicopathological and radiological features of solid pseudopapillary tumor (SPT) of the pancreas and summarize the surgical therapy strategy for this tumor. Methods:...Full Text Available

126

Aggressive behaviour of solid-pseudopapillary tumor of the pancreas in adults: A case report and review of the literature  

UK PubMed Central (United Kingdom)

Solid-pseudopapillary tumor (SPT) is a rare neoplasm of the pancreas that usually occurs in young females. It is generally considered a low-grade malignant tumor that can remain asymptomatic for several...Full Text Available

2008-02-14

127

Transport effect on He II film under conditions of weak interaction with the substrate  

Energy Technology Data Exchange (ETDEWEB)

The properties of a helium film on the surface of solid parahydrogen are investigated. It is shown that wetting of the solid hydrogen by the liquid helium occurs. The transport velocities along the He II film on the solid parahydrogen surface are measured in broad temperature, film height, and level difference ranges. It is shown that the transport velocity in this case has the least value as compared with its value on other substrates. The thickness of the helium-saturated film is determined on the solid hydrogen surface on the basis of the data obtained, and the value is in good agreement with the results of a computation performed within the framework of the Frenkel' theory.

1980-10-01

128

Thermal performance and design of a solid particle cavity receiver  

Energy Technology Data Exchange (ETDEWEB)

A model for energy transport in a solid particle cavity receiver is developed and applied to the design and analysis of a receiver for the Central Receiver Test Facility (CRTF), Albuquerque, New Mexico. The model gives thermal performance results - including particle temperatures, cavity efficiencies, and wall temperatures - which directly affect the economic and technical feasibility of a solid particle receiver. In addition, design criteria relevant to the configuration of a solid particle cavity receiver are developed. Results for CRTF indicate that at design conditions particle temperatures will exceed 1200/sup 0/K with cavity efficiencies on the order of 75%.

1985-04-01

129

Synchrotron Probes of Emergent Electronic States of Matter in Solids  

ScienceCinema

...of this article he quotes um i am told by my english ...

130

Process for retorting oil shale and the like  

Energy Technology Data Exchange (ETDEWEB)

The production of oil by retorting shale and other hydrocarbonaceous and lignocellulosic solid materials is facilitated by retorting in the presence of steam and acetic acid.

1983-08-02

131

PowerPoint Presentation  

Wastenet

facilities, building hygienic latrines and introducing regular solid waste collection systems . These methods are constantly being developed and

132

Passivation-free solid state battery  

Energy Technology Data Exchange (ETDEWEB)

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

1998-01-01

133

Passivation-free solid state battery  

Energy Technology Data Exchange (ETDEWEB)

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li{sub 4}Ti{sub 5}O{sub 12} anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2} and LiV{sub 2}O{sub 5} and their derivatives. 5 figs.

1998-06-16

134

Particle-Sizing System for Scanning Electron Microscope ...  

Science.gov (United States)

... THESIS PARTICLE-SIZING SYSTEM FOR SCANNING ELECTRON MICROSCOPE IMAGES OF SOLID-PROPELLANT COMBUSTION EXHAUST ...

1991-03-01

136

Electron Beam and Gamma Radiolysis of Solid-State Metoclopramide  

British Library Electronic Table of Contents (United Kingdom)

Purpose Study the radiolysis of solid-state metoclopramide hydrochloride at various absorbed doses. Elucidate the structure of the degradation products to gain information on the radiolysis mechanisms. Methods Solid-state metoclopramide samples were irradiated at several doses with gamma rays and high-energy electrons to evaluate the influence of the dose rate. High-performance liquid chromatography with a diode array detector was used to measure the chemical potency as a function of the absorbed dose and to quantify the degradation products. The characterization of degradation products was performed by liquid chromatography/atmospheric pressure chemical ionization/tandem mass spectrometry. Results The degradation of solid-state metoclopramide after irradiation was negligible. No qualitati...

2006-01-01

138

Autogenous electrolyte, non-pyrolytically produced solid capacitor structure  

Energy Technology Data Exchange (ETDEWEB)

A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.

1998-01-01

139

A NEW FORM OF SOLID STATE SOLAR GENERATOR  

Science.gov (United States)

... nent to the design and construction of metal-semiconductor solar cells, in that both the photovoltage and the efficiency of metal-semiconductor cells ...

1962-01-01

140

Response surface characterization of impact damage and residual strength degradation in composite sandwich panels  

Science.gov (United States)

The influence of material configuration and impact parameters on the damage tolerance characteristics of sandwich composites comprised of carbon-epoxy woven fabric facesheets and Nomex honeycomb cores was investigated using empirically based response surfaces. A series of carefully selected tests were used to isolate the coupled influence of various combinations of the number of facesheet plies, core density, core thickness, impact energy, impactor diameter, and impact velocity on the damage formation and residual strength degradation due to normal impact. The ranges of selected material parameters were typical of those found in common aircraft applications. The diameter of the planar damage area associated with Through Transmission Ultrasonic C-scan measurements and the peak residual facesheet indentation depth were used to describe the extent of internal and detectable surface damage, respectively. Standard analysis of variance techniques were used to assess the ...

2003-01-01

141

Spontaneous radiation emission during penetration of ions in solids  

International Nuclear Information System (INIS)

In this work, the principal continuum radiative emission processes, which occur during the penetration of ions in solids or gases, are resumed. The characteristics of the following processes are discussed: secondary electron bremsstrahlung (SEB), atomic bremsstrahlung (AB), and internuclear bremsstrahlung (INB). Recent advances of the ion channeling effects in crystal solids on the spontaneous radiative spectra are exposed. (A.C.A.S.).

1988-09-25

142

Resources | Environment Knowledge Hub  

Wastenet

... MUNICIPAL SOLID WASTES (MANAGEMENT AND HANDLING) RULES, 2000 Plastic Bag ban in Dhaka City, Bangladesh Private Sector Participation in Municipal Solid Waste Management SKAT 2000 TECHNICAL GUIDELINES ON MUNICIPAL SOLID WASTE MANAGEMENT Hazardous Waste Management Unit, Environmental Pollution Control Division, Central Environmental Authority, Sri Lanka 2004 Subregional ...

143

Pharmaceutics | Special Issue: Solid Dosage Forms  

Wastenet

...Pharmaceutics | Special Issue: Solid Dosage Forms LoginRegister mdpi.com Journals A-Z For Authors About Open Access Policy Title / Keyword Journal all Administrative Sciences Agriculture ...Establishing Differences from Adults Recent Developments and Future Perspectives in Dissolution Testing Solid Dosage Forms The 1st Electronic Conference on Pharmaceutical Science The Progress on Pharmaceutics ... 1 (2009) Special Issue \\

144

Peculiarities of #beta#-solid solution decomposition in (#alpha#+#beta#) titanium alloy at low temperature  

International Nuclear Information System (INIS)

The physical methods were used to study the decomposition of a metastable #beta#-solid solution in the VT22 two-phase titanium alloy. It is shown that the martensitic #beta# #-># #alpha#'' transformation in doped-element depleted microvolumes of the #beta#-solid solution are dominanted and the long-time multistage decomposition through a number of intermediate states in others.

145

ON THE POSSIBILITY OF ENRICHMENT AND DIFFERENTIATION IN GAS GIANTS DURING BIRTH BY DISK INSTABILITY  

International Nuclear Information System (INIS)

We investigate the coupling between rock-size solids and gas during the formation of gas giant planets by disk fragmentation in the outer regions of massive disks. In this study, we use three-dimensional radiative hydrodynamic simulations and model solids as a spatial distribution of particles. We assume that half of the total solid fraction is in small grains and half in large solids. The former are perfectly entrained with the gas and set the opacity in the disk, while the latter are allowed to respond to gas drag forces, with the back reaction on the gas taken into account. To explore the maximum effects of gas-solid interactions, we first consider 10 cm size particles. We then compare these results to a simulation with 1 km size particles, which explores the low-drag regime. We show that (1) disk instability planets have the potential to form large cores due to aerodynamic ...

2010-11-20

146

Microwave Oven for the Rapid Determination of Total Solids Content of Natural Rubber Latex  

British Library Electronic Table of Contents (United Kingdom)

The suitability of using the microwave oven for the rapid determination of total solids content (TSC) of natural rubber latex has been established over a broad range of dry rubber content (DRC). The total solids content values obtained by the microwave oven method are compared with the values obtained by heating in a conventional convection oven. Heating in a microwave oven is advantageous as the measurement time could be reduced considerably.

2008-01-01

147

Heat transfer in boiling liquified gas  

Energy Technology Data Exchange (ETDEWEB)

Means for increasing heat transfer characteristics between the surface of a solid and a boiling liquid are described in which the solid is immersed is comprised of a solid with passages which extend therethrough to the surface for the circulation of liquid through the passages for emergence from the surface to eliminate at least a portion of the unstable vapor film otherwise formed on the surface.

1980-09-23

148

GS1 - radiological protection objectives for the disposal of solid radioactive wastes  

Energy Technology Data Exchange (ETDEWEB)

A summary is given of the 1983 NRPB-GS1 Report on the 'Radiological protection objectives for the disposal of solid radioactive wastes'. The two principal difficulties in applying the ICRP system of dose limitation to some solid waste disposal methods are outlined. Despite these difficulties three radiological protection objectives for waste disposal were recommended based on the same fundamental principle as ICRP recommendations.

1984-01-01

149

Decomposition of metastable solid solution in #beta#-titanium alloy  

International Nuclear Information System (INIS)

Peculiarities of metastable #beta#-solid solution decmposition in titanium alloy VT30 in the process of isothermal ageing in the range 500-650 deg C are investigated. Using the methods of transmittion electron microscopy, X-ray diffraction analysis, etc., it is shown that in the case of alloy quenching from the temperature below the point of complete polymorphous transformation (T_t_._t_.), as well as after warm rolling the course of subsequent decomposition of solid solution can be consierably complicated.

150

Analysis of stability of semiconductor 5-component solid solutions of A"3B"5 compounds  

International Nuclear Information System (INIS)

With the use of the regular solutions model the expressions have been derived for calculation of boundaries of spinodal decomposition region as applied to five-component solid solutions of A"3B"5 compounds. The evaluation has been made of fields of stability for Al_x__1Ga_x__2In_1_-_x__1_-_x__2PyAs_1_-_y solid solution.

151

Ultraviolet detectors based on ZnO films by thermal oxidation of Zn metallic films  

British Library Electronic Table of Contents (United Kingdom)

Metallic Zn films were deposited on glass substrates by electron-beam evaporation. ZnO films were synthesized by thermal oxidation of Zn metallic films in air. At the annealing temperature of 550 ?C, ZnO nanowires appeared on the surface, which mainly result from the decrease of oxidation rate. A ZnO ultraviolet photodetector was fabricated based on a metal-semiconductor-metal planar structure. The detector showed a large UV photoresponse with an increase of two orders of magnitude. It is concluded that promising UV detectors can be obtained on ZnO films by thermal oxidation of Zn metallic films. The ways of performing spectral response measurements for polycrystalline ZnO films are also discussed.

2008-01-01

152

Three-dimensional, three-component wall-PIV  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a new time-resolved three-dimensional, three-component (3D-3C) measurement technique called wall-PIV. It was developed to assess near wall flow fields and shear rates near non-planar surfaces. The method is based on light absorption according to Beer-Lambert's law. The fluid containing a molecular dye and seeded with buoyant particles is illuminated by a monochromatic, diffuse light. Due to the dye, the depth of view is limited to the near wall layer. The three-dimensional particle positions can be reconstructed by the intensities of the particle's projection on an image sensor. The flow estimation is performed by a new algorithm, based on learned particle trajectories. Possible sources of measurement errors related to the wall-PIV technique are analyzed. The accuracy analysis was based on single particle experiments and a three-dimensional artificial data set simulating a rotating sphere. (orig.)

2010-06-15

153

Temperature-dependent characteristics and single-mode performance of AlGaInP-based 670--690-nm vertical-cavity surface-emitting lasers  

Science.gov (United States)

The authors report on temperature dependent characteristics and single mode performance of one-wave cavity, planar implanted, AlGaInP-based vertical-cavity surface emitting lasers. By optimizing the overlap between the gain peak and the cavity mode of the structure, they demonstrate record device performance, including 8.2 mW maximum output power and 11% power conversion efficiency for multimode operation and 1.9 mW and 9.6% power conversion efficiency for single mode operation at 687 nm. Improved performance at elevated temperatures is also achieved, with 1.5 mW output power demonstrated at 50 C from a 15-{micro}m-diameter device.

1995-07-01

154

Schottky barrier modulation on silicon nanowires  

Science.gov (United States)

Oxide charge on the sidewalls of SiO{sub 2} embedded silicon wires with 20x20 nm{sup 2} cross section is shown to influence the Schottky barrier height for Pd{sub 2}Si/Si junctions positioned on the end surfaces of the wires. Compared with results on planar silicon surfaces, the electron barrier height is 0.3 eV lower for wires investigated as fabricated. By increasing the oxide charge through irradiation by ultraviolet light, the electron barrier decreases by an additional 0.15 eV and the hole barrier correspondingly increases by about the same amount. The phenomenon is explained by assuming an oxide charge density in the range of 10{sup 12} cm{sup -2}.

2007-03-26

155

Room-temperature continuous-wave operation of a GaInP/AlGaInP multiquantum well laser grown by metalorganic chemical vapor deposition  

Science.gov (United States)

Room-temperature continuous-wave (cw) operation of a GaInP/AlGaInP multiquantum well (MQW) laser was achieved for the first time. The threshold current was 70 mA at 22 /sup 0/C for a device with an 8-..mu..m-wide and a 250-..mu..m-long planar stripe. The emission wavelength was 668 nm. The characteristic temperature T/sub 0/ was 138 K under cw operation. The wafer with the MQW structure composed of 100-A-thick GaInP wells and 40-A-thick AlGaInP barrier layers was grown by atmospheric pressure metalorganic chemical vapor deposition.

1987-04-20

156

Reborn quadrant anode image sensor  

International Nuclear Information System (INIS)

We describe a position sensitive photon counting microchannel plate based detector with an improved quadrant anode (QA) readout system. The technique relies on a combination of the four planar elements pattern and an additional fifth electrode. The charge cloud induced by single particle detection is split between the electrodes. The measured charge values uniquely define the position of the initial event. QA has been first published in 1976 by Lampton and Malina. This anode configuration was undeservedly forgotten and its potential has been hardly underestimated. The presented approach extends the operating spatial range to the whole sensitive area of the microchannel plate surface and demonstrates good linearity over the field of view. Therefore, the novel image sensor results in spatial resolution better then 50?m and count rates up to one million events per second.

2009-06-01

157

Reborn quadrant anode image sensor  

British Library Electronic Table of Contents (United Kingdom)

We describe a position sensitive photon counting microchannel plate based detector with an improved quadrant anode (QA) readout system. The technique relies on a combination of the four planar elements pattern and an additional fifth electrode. The charge cloud induced by single particle detection is split between the electrodes. The measured charge values uniquely define the position of the initial event. QA has been first published in 1976 by Lampton and Malina. This anode configuration was undeservedly forgotten and its potential has been hardly underestimated. The presented approach extends the operating spatial range to the whole sensitive area of the microchannel plate surface and demonstrates good linearity over the field of view. Therefore, the novel image sensor results in spatial...

2009-01-01

158

Real time automatic discriminating of ultrasonic flaws  

International Nuclear Information System (INIS)

This paper is concerned with the real time automatic discriminating of flaws from two categories; i. cracks (planar defect) and ii. Non-cracks (volumetric defect such as cluster porosity and slag) using pulse-echo ultrasound. The raw ultrasonic flaws signal were collected from a computerized robotic plane scanning system over the whole of each reflector as the primary source of data. The signal is then filtered and the analysis in both time and frequency domain were executed to obtain the selected feature. The real time feature analysis techniques measured the number of peaks, maximum index, pulse duration, rise time and fall time. The obtained features could be used to distinguish between quantitatively classified flaws by using various tools in artificial intelligence such as neural networks. The proposed algorithm and complete system were implemented in a computer software developed using Microsoft Visual BASIC 6.0 (author)

2009-07-20

159

Planar QED at finite temperature and density: Hall conductivity, Berry's phases and minimal conductivity of graphene  

CERN Document Server

We study 1-loop effects for massless Dirac fields in two spatial dimensions, coupled to homogeneous electromagnetic backgrounds, both at zero and at finite temperature and density. In the case of a purely magnetic field, we analyze the relationship between the invariance of the theory under large gauge transformations, the appearance of Chern-Simons terms and of different Berry's phases. In the case of a purely electric background field, we show that the effective Lagrangian is independent of the chemical potential and of the temperature. More interesting: we show that the minimal conductivity, as predicted by the quantum field theory, is the right multiple of the conductivity quantum and is, thus, consistent with the value measured for graphene, with no extra factor of pi in the denominator.

2009-01-01

160

Photoconductive ultraviolet detectors based on ZnO films  

British Library Electronic Table of Contents (United Kingdom)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8mA, and a slow photoresponse with a rise time of 5min and a decay time of 7min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the d...

2006-01-01

161

Palladium polypyridyl complexes: synthesis, characterization, DNA interaction and biological activity on Leishmania (L.) mexicana  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the search for new potential chemotherapeutic agents based on transition metal complexes with planar ligands. In this study, palladium polypyridyl complexes were synthesized and characterized by elemental analysis, NMR, UV-VIS and IR spectroscopies. The interaction of the complexes with DNA was also investigated by spectroscopic methods. All metal-to-ligand charge transfer (MLCT) bands of the palladium polypyridyl complexes exhibited hypochromism and red shift in the presence of DNA. The binding constant and viscosity data suggested that the complexes [PdCl{sub 2}(phen)] and [PdCl{sub 2}(phendiamine)] interact with DNA by electrostatic forces. Additionally, these complexes induced an important leishmanistatic effect on L. (L.) mexicana promastigotes at the final concentration of 10 {mu}mol L{sup -1} in 48 h. (author)

2008-07-01

162

Modelling and design of smoothing reactances. Application to air gap length calculation  

Energy Technology Data Exchange (ETDEWEB)

A new method for analysis and design of smoothing reactances utilising two-dimensional planar models is presented in this paper. Inductance and magnetic flux density are calculated, and their results compared with those measured experimentally. The results obtained are good if compared with those measured once the machine have been built. Moreover, the method herein developed is applied to the calculation of air gap lengths in terms of the desired current and inductance. The kind of reactances studied presents windings in both limbs and air gaps in the four corners (joint of limbs and yokes). The main contribution of this paper is the presentation of a method of industrial application, to be easily developed, with a very important reduction in the time of machine calculation (due to the decrease in the number of nodes and elements compared with the three-dimensional model) for the determination of the air gap length in smoothing reactances. (orig.)

2000-08-01

163

Low-cycle fatigue behaviour and microstructure of copper and alpha-brass under biaxial load paths  

Energy Technology Data Exchange (ETDEWEB)

The low-cycle fatigue behaviour of copper and a-brass CuZn30 was investigated in uniaxial and biaxial tests. Planar biaxial fatigue tests were carried out using cruciform samples with proportional stain paths with and without phase shift between the two axes. Microcharacterisation was performed by electron microscopy as well as by high-resolution X-ray line profile analysis. The biaxial cyclic stress-strain curves show good agreement with the uniaxial ones using the von Mises equivalent strain hypothesis. The dislocation densities and microhardness values of the biaxial case, however, show significantly lower values compared to the uniaxial case at equivalent von Mises stresses.

2010-07-01

164

Instrumental neutron activation analysis of copper-molybdenum ores for molybdenum content determination  

International Nuclear Information System (INIS)

An instrumental neutron activation technique of determining molybdenum in ores is based on measuring gamma-activity of the "9"9Mo isotope with the use of planar and coaxial semiconductor spectrometers. A lot consisting of 50 portions, 0.5 g each, is being irradiated for 10 hours by a flow of neutrons with the density of 10"1"2 n/cm"2xsec. On the lot being allowed to stay for 3-4 days, its activity is measured during 1-5 minutes. Monoethalons based upon phenol-formaldehyde resin are used as standards. The sensitivity of the technique is 10"-"4%, reproducibility error being not higher than 10%, efficiency up to 50 portions for a working shift.

165

Implementation and modification of a three-dimensional radiation stress formulation for surf zone and rip-current applications  

British Library Electronic Table of Contents (United Kingdom)

Regional Ocean Modeling System (ROMS v 3.0), a three-dimensional numerical ocean model, was previously enhanced for shallow water applications by including wave-induced radiation stress forcing provided through coupling to wave propagation models (SWAN, REF/DIF). This enhancement made it suitable for surf zone applications as demonstrated using examples of obliquely incident waves on a planar beach and rip current formation in longshore bar trough morphology (Haas and Warner, 2009). In this contribution, we present an update to the coupled model which implements a wave roller model and also a modified method of the radiation stress term based on Mellor (2008, 2011a,b,in press) that includes a vertical distribution which better simulates non-conservative (i.e., wave breaking) processes and ...

2011-01-01

166

Identification and validation of a logistic regression model for predicting serious injuries associated with motor vehicle crashes  

British Library Electronic Table of Contents (United Kingdom)

A multivariate logistic regression model, based upon National Automotive Sampling System Crashworthiness Data System (NASS-CDS) data for calendar years 1999-2008, was developed to predict the probability that a crash-involved vehicle will contain one or more occupants with serious or incapacitating injuries. These vehicles were defined as containing at least one occupant coded with an Injury Severity Score (ISS) of greater than or equal to 15, in planar, non-rollover crash events involving Model Year 2000 and newer cars, light trucks, and vans. The target injury outcome measure was developed by the Centers for Disease Control and Prevention (CDC)-led National Expert Panel on Field Triage in their recent revision of the Field Triage Decision Scheme (American College of Surgeons, 2006). The ...

2011-01-01

167

Hydraulic Fracture Stimulation Treatments at East Mesa, Well 58-30; Geothermal Reservoir Well Stimulation Program; Experiment 3 and 4  

Energy Technology Data Exchange (ETDEWEB)

The tests reported were part of the DOE Geothermal Reservoir Well Stimulation Program. This East Mesa (Imperial Valley, CA) well was successfully stimulated with two fracture treatments, a dendritic fracture and a planar fracture. The natural flow production of the well increased 114 percent, to 197,900 lb/hr. These tests were among the few successful attempts of this program to increase flow from geothermal production wells. The general belief is that these tests worked OK primarily because the formation was sedimentary rock (similar to rock in most oil and gas wells that have been stimulated successfully. Similar tests in geothermal hard rock reservoirs did not work very well. (DJE 2005)

1982-02-01

168

Embryo-damage induced nucleation of microcracks in an aluminum alloy under impact loading  

Energy Technology Data Exchange (ETDEWEB)

The nucleation of microdamage under dynamic loading was investigated through planar impact experiments accomplished with a light gas gun. The microscopic observation of recovered and sectioned specimens showed that microcracks were nucleated only by cracking of brittle particles inside material. However, for comparison the in situ static tensile tests on the same material conducted with a scanning electron microscope showed that the microcracks were nucleated by many forms those were fracture of ductile matrix, debonding particles from matrix and cracking of brittle particles. The quantitative metallographic observations of the specimens subjected to impact loading showed that most of the cracked particles were situated on grain boundaries of the aluminum matrix. These facts suggested the concept of critical size and incubation time of submicroscopic cavities in the dynamic case and the mechanism of embryo-damage induced nucleation by fracture of brittle particles ...

1995-06-01

169

Electron beam, ion beam, X-ray optical techniques for fabricating surface-acoustic-wave and thin-film optical devices  

International Nuclear Information System (INIS)

Most surface-acoustic-wave and thin-film optical devices are made by the planar fabrication process. The exposure of the pattern in the polymer film is the first and most crucial step in ensuring desired device geometry, dimensional control, and freedom from pattern distortion. The methods of exposing the polymer film include: optical projection, conventional contact printing, conformable photomask contact printing, holographic recording, scanning electron beam lithography, projection electron lithography, and x-ray lithography. In this paper scanning electron beam lithography, conformable photomask contact printing, holographic recording, and x-ray lithography are discussed. In the last section, ion beam etching of relief structures is discussed.

170

Design and fabrication of a micro zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

Micro-batteries are one of the key components that restrict the application of autonomous Microsystems. However little efforts were made to solve the problem. We have proposed a new planar zinc/air micro-battery, suitable for autonomous microsystem applications. The micro-battery has a layered structure of zinc electrode/alkaline electrolyte/air cathode. A 3D zinc electrode with a high density of posts was designed to obtain a high porosity, hence to offer a best performance. A model of the micro-battery is developed and the device performances were simulated and discussed. A four-mask process was developed to fabricate the prototype micro-batteries. The preliminary testing results showed the micro-batteries is able to deliver a maximum power up to 5 mW, and with an average power of 100 {mu}W at a steady period for up to 2hrs. Fabrication process is still under optimization for further improvement.

2006-04-01

171

Corrosion in steam generators of PWR type nuclear power plants  

International Nuclear Information System (INIS)

Problems are discussed of heat exchange tubes of Westinghouse type vertical steam generators exhibiting corrosion damage such as point corrosion, planar corrosion, tube denting, corrosion stress cracking, crevice corrosion, fretting corrosion and intergranular corrosion. Attention is also paid to problems of WWER-440 type horizontal steam generators, where the level fluctuation area is critical; noncompact porous deposits of the corrosion products give rise to crevice effects and cause significant concentration of chloride ions and other additions. This problem can be partly resolved by a modification of the collector design at the level variation area. An additional measure is the production of steel 08Kh18N10T with a very low level of harmful elements and inclusions. (Z.M.). 3 figs., 11 refs.

1988-03-01

172

Coordinated control of multiple manipulator systems  

Energy Technology Data Exchange (ETDEWEB)

A scheme for controlling multimanipulator systems is presented. The control objective is to coordinate the manipulators to perform parts-matching tasks such as screwing a nut onto a bolt. The task of moving a rigid object can be treated as a special case. Two secondary control objectives internal force control and load distribution can be accomplished within the structure of the control law. The internal force control mechanism keeps the internal forces on the object being manipulated at a desirable level. The load distribution mechanism distributes control effort to each manipulator according to a weighting factor. It is also shown that the control algorithm has a modular structure which facilitates its implementation on a multiprocessor computer. The scheme was tested on a planar scara type dual-manipulator system. A series of experimental results is included to demonstrate the system performance under various conditions.

1993-08-01

173

Conformational analysis of ethyl azidoformate  

International Nuclear Information System (INIS)

A conformational analysis of ethyl azidoformate (EAF) has been carried out by the MINDO/3 quantum-chemical method. It has been shown that EAF exists in the form of two conformers differing with respect to rotation around the C-N bond. Complete optimization of the geometry has been carried out for both conformers. It has been found that the transoid conformation is planar and that the cisoid conformation is nonplanar. The height of the rotation barrier is 15.4 kcal/mole. The optimal geometry of the transition state has been calculated. It has been noted that a significant role in the mechanism of the conformational transition is played by the inversion of a nitrogen, which facilitates the transition. The results of the calculation have been confirmed by IR-spectroscopic data.

174

Aromatics oxidation and soot formation in flames. Progress report, August 15, 1993--June 30, 1994  

Energy Technology Data Exchange (ETDEWEB)

This project is concerned with the kinetics and mechanisms of aromatic oxidation and soot and fullerenes formation in flames. The objective of the aromatics oxidation work is to identify and measure the concentration of important intermediates and products in benzene oxidation, and to determine reaction mechanisms and kinetics properties consistent with the behavior seen in flames. The research on soot formation is concerned primarily with the particle inception stages, but the work includes study of soot structure at all stages of growth in order to obtain mechanistic information from evidence of growth steps recorded in the structure of the particles. The ultimate objective is to understand how nascent soot particles are formed from high molecular weight compounds, including the roles of planar and curved PAH and the relationship between soot and fullerenes. The objective of the proposed research on fullerenes is to develop a more comprehensive understanding of ...

1994-10-01

175

Alignment of nematic liquid crystals on mixed Langmuir-Blodgett mono-layers  

CERN Document Server

Mono-layers of stearic and behenic acids and mixtures of them in different proportions, deposited with the Langmuir-Blodgett technique, were used to study the alignment and the alignment dynamics in nematic liquid crystal cells. A relaxation process from a splay-bend flow induced metastable orientation to the homeotropic one occurs. The lifetime of the metastable state was found to depend on the mono-layer composition. The transition between the homeotropic and the conical anchoring was found to be irreversible in the case of the mixed aligning mono-layers: on cooling from the isotropic phase a quasi-planar nematic state (schlieren texture) appears. It is stable in a range of a few degrees below the clearing point and, on decreasing the temperature, relaxes to the homeotropic state in form of expanding domains.

1998-01-01

176

Alignment and alignment dynamics of nematic liquid crystals on Langmuir-Blodgett mono-layers  

CERN Document Server

Mono-layers of stearic and behenic acids deposited with the Langmuir-Blodgett technique, were used as aligning films in nematic liquid crystal cells. During the filling process the liquid crystal adopts a deformed quasi-planar alignment with splay-bend deformation and preferred orientation along the filling direction. This state is metastable and transforms with time into homeotropic once the flow has ceased. The transition is accompanied by formation of disclination lines which nucleate at the edges of the cell. The lifetime of the metastable splay-bend state was found to depend on the cell thickness. On heating, anchoring transition from quasi-homeotropic to degenerate tilted alignment in form of circular domains takes place near the transition to the isotropic phase. The anchoring transition is reversible with a small hysteresis.

1998-01-01

177

X-ray studies of solid n-H/sub 2/  

Energy Technology Data Exchange (ETDEWEB)

Results of X-ray investigations of solid normal hydrogen are presented. Temperature dependences of the lattice parameteps, molar volumes, linear and volume expansion coefficients in the 2K-Tsub(melt) temperature range are obtaiped. An essential n-H/sub 2/ expansion anisotropy in the premelting temperature region is pointed out. It is shown that the hexagonal lattice parameter ratios over the whole investigated temperature range is considerably higher than for solid parahydrogen. A considerable difference in thermal expansion of normal hydrogen and parahydrogen in the low temperature region is revealed. It is caused by contribuation of a rotational subsystem, increasing with the temperature decrease to crystal expansion. A detailed analysis of solid n-H/sub 2/ thermodynamic properties is conducted. The data testifying to the presence of isomorphous phase transformation in the solid n-H/sub 2/ in the ...

1983-08-01

178

Theory of NMR multiple echoes in solid hydrogen  

Energy Technology Data Exchange (ETDEWEB)

We have examined the theory of NMR multiple echoes developed for solid {sup 3}He to determine whether multiple echoes could be observed in solid hydrogen. We were particularly interested in the possibility of testing for low frequency quantum tunneling motions in solid hydrogen by the observation of multiple echoes. We find that for easily accessible nuclear spin polarizations, P > 12%, multiple echoes would be observed for HD impurities in solid parahydrogen if motional narrowing is effective in increasing the HD nuclear spin-spin relaxation time T{sub 2} to the order of 1 msec. These values for T{sub 2}, which have been observed for HD impurity concentrations of the order of 1%, are larger than the calculated rigid lattice values and can be attributed to quantum tunneling at frequencies of the order of 1kHz.

1995-11-01

179

Solid suspension in stirred tanks: UVP measurements and CFD simulations  

British Library Electronic Table of Contents (United Kingdom)

Abstract Suspension of solids in stirred reactor is widely used for catalytic reactions, dissolution, etc. Quality of solid suspension is an important parameter required for the reliable design, optimum performance, and scale up of the system. Quality of suspension depends on local characteristics of solid velocity and hold up profiles. The present work was focused on investigating quality of solid suspension using ultrasound velocity profiler (UVP) measurements and CFD simulations. The slip velocity measurements carried out with UVP were used to evaluate different drag correlations used in CFD simulations. Results discussed in this work would be useful for extending the applications of CFD models for simulating large stirred slurry reactors.

2011-01-01

180

Self-inhibited rate in gas-solid noncatalytic reactions. The shrinking core model  

Energy Technology Data Exchange (ETDEWEB)

The shrinking core model is examined for gas-solid noncatalytic reactions with a self-inhibited rate form and it is shown that multiple reaction pathways are possible for solid particles reacted under identical conditions. The observed reaction rate can have up to two discontinuities (jumps) during reaction for particles of spherical and cylindrical shape. The geometric instability analysis reveals that the reaction interface is stable under a very limited set of conditions only for solid particles of slab geometry. For a sphere or cylinder at large Biot numbers the reaction interface is always potentially unstable. This model provides a plausible explanation for gas-solid reactions which exhibit erratic shrinking core behavior.

1984-02-01

181

Quantification of order in the liquid at a solid-liquid interface by High-Resolution Transmission Electron Microscopy (HRTEM)  

Energy Technology Data Exchange (ETDEWEB)

A number of different theoretical approaches have been used to model to atomic structure and properties of solid-liquid interfaces. Most calculations indicate that ordering occurs in the first several layers of the liquid, adjacent to the crystal surface. In contrast to the numerous theoretical investigations, there have been no direct experimental observations of the atomic structure of a solid-liquid interface for comparison. Saka et al. examined solid-liquid interfaces in In and In-Sb at lattice-fringe resolution in the TEM, but their data do not reveal information about the atomic structure of the liquid phase. The purpose of this study is to determine the atomic structure of a solid-liquid interface using a highly viscous supercooled liquid, i.e., a crystal-amorphous interface.

1996-12-31

182

Partial wave expansion of ion-atom elastic scattering in solids  

International Nuclear Information System (INIS)

Elastic scattering cross sections of keV protons in solids (Z=3-82) are calculated using the partial wave expansion technique and the ''muffin-tin'' bound-atom potential. The differential cross sections for small scattering angles of less than 10deg are smaller than those with the Ziegler-Biersack-Littmark potential at all energies and for all solids, although, for larger angles, the two cross sections agree with each other. The mean free paths of the protons in the solids, obtained from the total cross sections, decrease very slowly with decreasing energy. Furthermore, at low energies they approach half the nearest-neighbor distance, which is taken as the radius of the augmented plane wave sphere in the muffin-tin model of crystalline solids. (orig.).

183

On the solid-fluid transition zone in welding analysis  

Energy Technology Data Exchange (ETDEWEB)

Equilibrium and energy equations have been developed in describing the solid-fluid transition zone during the melting and solidification of the binary alloys. Due to the existence of the transition region exhibited both solid and fluid phases at the same material point from continuum point of view, mixture theory was utilized to analyze the region. Unlike the Stefan problem, the latent heat due to the phase change appears as a source term in the heat equation. The molten fluid is treated as a thermoviscous and incompressible fluid, whereas the solid is thermoviscoplastic described by the Bodner-Partom/Walker type of constitutive equations. Thermal mechanical behaviors of the solid and the fluid phases are determined separately because of insignificant mechanical interactions between them. Volume fractions of the phases are obtained according to the equilibrium phase diagram. The simulation process of ...

1993-01-01

184

Infrared spectroscopy of rovibrational transitions of methyl radicals (CH3, CD3) in solid parahydrogen  

British Library Electronic Table of Contents (United Kingdom)

The n3 and n4 vibrational transitions of CH3 and CD3 isolated in solid parahydrogen were studied by high-resolution infrared spectroscopy. The radicals were produced by in situ UV photolysis of methyl iodides trapped in solid parahydrogen. The observed spectra showed clear rotational fine structures, which were subjected to further splitting due to the electrostatic field of solid parahydrogen. The molecular constants and crystal field parameters of the radicals in solid parahydrogen were determined by analyzing the spectral structures of the n3 and n4 transitions of CD3 by the crystal field theory. The rotational constants of the CD3 radical were found to be only a few percent smaller than those in the gas phase. The determined crystal field parameters indicated significant quantum effect...

2011-01-01

185

Possible global environmental impacts of solid waste practices  

Energy Technology Data Exchange (ETDEWEB)

Pollutants resulting from the management of solid waste have been shown to affect the air, land, oceans, and waterways. In addition, solid wastes have other, more indirect impacts such as reduction in feedstocks of natural resources, because useful materials are disposed of rather than recycled. The objective of this study is to evaluate solid waste management practices that have negative implications on the global environment and develop recommendations for reducing such impacts. Recommendations identifying needed changes are identified that will reduce global impacts of solid waste practices in the future. The scope of this study includes the range of non-hazardous solid wastes produced within our society, including municipal solid waste (MSW) and industrial solid waste (ISW), as well as industry-specific wastes from activities such as ...

1994-09-01

186

Nanocrystal conversion chemistry: A unified and materials-general strategy for the template-based synthesis of nanocrystalline solids  

International Nuclear Information System (INIS)

The concept of nanocrystal conversion chemistry, which involves the use of pre-formed nanoparticles as templates for chemical transformation into derivative solids, has emerged as a powerful approach for designing the synthesis of complex nanocrystalline solids. The general strategy exploits established synthetic capabilities in simple nanocrystal systems and uses these nanocrystals as templates that help to define the composition, crystal structure, and morphology of product nanocrystals. This article highlights key examples of 'conversion chemistry' approaches to the synthesis of nanocrystalline solids using a variety of techniques, including galvanic replacement, diffusion, oxidation, and ion exchange. The discussion is organized according to classes of solids, highlighting the diverse target systems that are accessible using similar chemical concepts: metals, oxides, chalcogenides, phosphides, ...

2008-07-01

187

Carbon dioxide purification through two-stage combustion ENCAP. Final report; Koldioxidrening med tvaastegsforbranning ENCAP. Slutrapport  

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion (CLC), has previously been studied as a method for separating CO{sub 2} during combustion of gaseous fuels. In this project the possibility to apply this process for direct use of solid fuels has been investigated. The following has been accomplished: A 10 kW reactor system for CLC with solid fuels has been designed and built. Tests with solid fuel and metal oxid particles in a laboratory reactor show that it is possible to oxidize solid fuels with metal oxide particles in cyclic testing, thus giving proof of basic concept. They also show how the reaction rate is affected by temperature, steam concentration etc., and, most important of all, that the rates of reaction are realistic. Tests with metal oxide materials available at low costs have been successful. Chemical-looping combustion with solid fuels has a potential to achieve very low costs for ...

2006-06-15

188

Surface activity at the planar interface in relation to the thermodynamics of intermolecular interactions in the ternary system: maltodextrin-small-molecule surfactant-legumin.  

Science.gov (United States)

We report on the effect of potato maltodextrins with variable dextrose equivalent (Paselli SA-2, SA-6 and SA-10) on the surface behavior at the air-water interface of the mixture: legumin+small-molecule surfactant. Distinct in nature small-molecule surfactants (model: sodium salt of capric acid, Na-caprate; and commercially important: a citric acid ester of monoglyceride, CITREM) have been under our consideration. The role of the structure of both of the maltodextrins and the small-molecule surfactants in the effect studied has been elucidated by measurements in a bulk aqueous medium of the enthalpy of their interaction from mixing calorimetry, value of weight average molecular weight of the maltodextrins and the thermodynamics of the pair maltodextrin-solvent and maltodextrin-protein interactions from laser static light scattering. The combined data of mixing calorimetry and light scattering suggest some complex formation between the small-molecule surfactants and the maltodextrins. ...

2001-07-01

189

Square planar platinum(II) complexes: Synthesis, IR spectroscopy, and hydration equilibrium of Pt[sup II]L(CN)[sub 2] (L = 4,4[prime]-(t-Bu)[sub 2]-2,2[prime]-bpy)  

Energy Technology Data Exchange (ETDEWEB)

The hydration behavior of a number of square planar Pt(II) bis(cyano) complexes has been examined, and the limiting stoichiometries are related to the steric requirements of the dinitrogen bidentate ligands coordinated to the metal center. In particular, the IR, UV/vis, and [sup 1]H, [sup 13]C, and [sup 195]Pt NMR spectroscopic data for the compound Pt[sup II]dtbipy(CN)[sub 2] [dtbipy = 4,4[prime]-[l brace]C(CH[sub 3])[sub 3][r brace][sub 2]-2,2[prime]-bpy] have been determined and show that, at relative humidities (rh) above [approximately]40%, this complex sorbs five water molecules at room temperature. The sorption process consists of a rapid step in which one H[sub 2]O adds to the complex and which appears to be independent of rh, followed by a slower, rh-dependent step leading to the final stoichiometry. In contrast, the analogous 2,2[prime]-bpy complex sorbs no water under these conditions, while the 4,4[prime]-(CH[sub 3])[sub 2]-2,2[prime]-bpy complex sorbs ...

1992-12-23

190

An EXAFS investigation of the structures of bromocopper(II) complexes in some solutions  

International Nuclear Information System (INIS)

The structures of bromocopper(II) complexes in methanolic (M1, M2, M3, M4), ethanolic (E), and aqueous (H) solutions were determined by the analyses of the Cu K- and Br K-edge EXAFS spectra using a curve-fitting method. The molar concentrations of Cu and Br in these solutions prepared by CuBr_2 and LiBr are 0.996 and 1.992 (M1), 1.015 and 5.381 (M2), 0.493 and 4.525 (M3), 0.260 and 4.073 (M4), 1.031 and 4.313 (E), and 0.982 and 5.426 (H). In M1 solution the interatomic distances for the Cu-O_e_q, Br_e_q-Cu, and Br_e_q-O_e_q (_e_q = equatorial) were 2.00A, 2.35A, and 3.15A respectively, and the Br_e_q-Cu-O_e_q angle was estimated as about 92 deg. Therefore, trans-dibromo bis(methanol)copper(II) complex with a slightly distorted planar structure was proposed to be dominant complex species in M1 solution. The interatomic distances in M2, M3, M4 and E solutions were 2.37A and 3.45A (average) for the Br_e_q-Cu and Br_e_q-Br_e_q respectively. The Br_e_q-Cu-Br_e_q angle, ...

191

Solid radioactive waste management in Daya Bay Nuclear Power Station  

International Nuclear Information System (INIS)

This paper introduces the solid radwaste management system, treatment methods and its continuous improvement during the past 9 years in Guangdong Daya Bay Nuclear Power Station (GNPS). GNPS has paid great attention and made a lot of efforts to implement the principle of waste minimization with source control, improvement of treatment process and strict management, so the output of solid radwastes has annually decreased since 1994. In 2002, the output of solid radwastes in GNPS was 63.5 m"3, only 50% of 1995 (127 m"3), reached the advanced level as the same type NPPs in France. During the period 1994-2002, the accumulated production of solid radwaste Packages in GNPS is 1563.51 m"3 only 18% of the design value; all the packages meet the standard and requirement for safe disposal. Besides, this paper analyzes some new technical processes and presents some proposals for further decreasing the ...

2004-05-01

192

Separation of the components of the binary mixture ethanol-water by steam flux in solid phase column; Separacao dos componentes da mistura binaria etanol-agua por passagem do vapor em coluna de fase solida  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

1987-12-31

193

Promising electrolyte materials for the coming lithium secondary batteries. Lithium ion conductive inorganic solid electrolytes; Jisedai lithium niji denchiyo denkaishitsu. Muki kotai denkaishitsu  

Energy Technology Data Exchange (ETDEWEB)

This paper describes inorganic solid electrolytes from a viewpoint of electrolytes for lithium batteries. Lithium ion conductive inorganic solid electrolytes are largely divided into crystalline and amorphous substances. Crystalline substances are known as LiI and Li3N, and also oxygen acid salt. However, when considering application to a battery, its large grain boundary resistance and electrochemical instability would be a problem. Lithium ion conductive amorphous solid electrolytes are divided into an oxide system and a sulfide system. Since most of them do not contain transition metal elements, they are stable against electrochemical reduction, and ions move isotropically in electrolyte. Therefore, ion conduction paths across the grain boundaries may be connected more easily, forming an electrolyte with low grain boundary resistance. As a result of the efforts of the authors in searching new additives substituting LiI, ...

1997-11-05

194

Operation of a laboratory-scale tubular digester on pigery waste  

Energy Technology Data Exchange (ETDEWEB)

Three inclined tubular digesters of 13- to 15-litre volume were operated at temperatures between 20 and 30 degrees C with hydraulic retention times of 10-15 days on pig slurry of 10%, 5% and 2.5% Total Solids content. Tube inclination of 16-20 degrees gave no scumming problems. Solids were retained, giving improved gas yields when compared with literature values for conventional stirred digesters. Solids retention is affected by the size of the digester exit and appears to be greater with slurry of low solids content. There is a link between the movement of solids and gas along, and out of, the digester which can lead to unstable oscillating gas production. Tracer studies showed soluble components of the slurry mixed throughout the whole volume of the digester in 25% of the hydraulic retention time or less. Solids moved in well dispersed plug flow. Gas ...

1986-01-01

195

Methodology to evaluate the energy associated to the industrial solid wastes: application in a metropolitan region of Campinas, Sao Paulo state, Brazil; Metodologia para avaliacao da energia associada ao residuo solido industrial: aplicacao a regiao metropolitada de Campinas  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to the application of a methodology to evaluate the energy associated to the industrial solid wastes in the metropolitan region of Campinas. The methodological route proposed is: the characterization of the research area and the production/management of the industrial solid wastes; the energetic classification and the qualitative/quantitative research of the energy associated to the industrial solid wastes; and, the valuation of the applicability of the energetic utilization mechanisms proposed to the region. This methodology when applied at the Campinas metropolitan region proved to be valid and it resulted in a synthetically presentation of the social and environmental reality of the industrial sector and the destination of the wastes, as well as it indicated the potentialities related to the energetic utilization of the industrial solid waste in the region. With the obtained ...

2004-07-01

196

Maintenance Implementation Plan for solid waste  

Energy Technology Data Exchange (ETDEWEB)

This Maintenance Implementation Plan (MIP) has been developed for. implementation of the US Department of Energy (DOE) Order 4330.4A. Maintenance Implementation Program (DOE 1990) at the Hanford Site Solid Waste complex. It addresses maintenance functions associated with Solid Waste Management, which includes the field operational group and the facilities operational group. An assessment of the existing maintenance programs for Solid Waste was performed, and the results of this assessment were evaluated to determine corrective actions required to bring Solid Waste Maintenance into compliance with the order. The MIP assessment disclosed that most elements defined in the order are currently implemented for Solid Waste. It also identified issues which must be addressed to bring the maintenance function into full compliance with DOE Order 4330.4A. These include documentation of the ...

1992-06-01

197

Henry`s law gas-solid chromatography and correlations of virial coefficients for hydrocarbons, chlorofluorocarbons, ethers, and sulfur hexafluoride adsorbed onto carbon  

Energy Technology Data Exchange (ETDEWEB)

Gas-solid chromatography was used to determine the Henry`s law second gas-solid virial coefficients within the temperature range of 314--615 K for ethane, propane, butane, isobutane, pentane, hexane, heptane, chloromethane, dichloromethane, trichloromethane, tetrachloromethane, trichlorofluoromethane (Freon 11), chlorodifluoromethane (Freon 22), dichlorodifluoromethane (Freon 12), methyl ether, ethyl ether, and sulfur hexafluoride with Carbopack B, a microporous carbon adsorbent. The temperature dependence of the second gas-solid virial coefficients of these adsorbates was used in conjunction with analyses based on a graphical method, a single-surface numeric integration method, a single-surface analytic expression method, and a two-surface analytic expression method to determine the gas-solid interaction energies and other parameters. The interaction energies were correlated with a ratio of the ...

1995-07-01

198

Wet limestone FGD solids analysis by thermogravimetry  

Energy Technology Data Exchange (ETDEWEB)

Wet limestone scrubbing is once again becoming a popular technology for removal of sulfur dioxide (SO{sub 2}) from power plant emissions. Critical to the operation of wet limestone flue gas desulfurization (FGD) systems is accurate chemical analysis of scrubber solids. The analytical technique of thermogravimetry is ideal for this application, as the instrument can give precise readings of the principal scrubber solids components, calcium sulfite/sulfate hemihydrate, calcium sulfate dihydrate (gypsum), and unused calcium carbonate. The data provides plant chemists, engineers, and operators with information needed to fine-tune scrubber operation and detect process upsets. (orig.)

2004-07-01

199

Waste management units - Savannah River Site. Volume 1, Waste management unit worksheets  

Energy Technology Data Exchange (ETDEWEB)

This report is a compilation of worksheets from the waste management units of Savannah River Plant. Information is presented on the following: Solid Waste Management Units having received hazardous waste or hazardous constituents with a known release to the environment; Solid Waste Management Units having received hazardous waste or hazardous constituents with no known release to the environment; Solid Waste Management Units having received no hazardous waste or hazardous constituents; Waste Management Units having received source; and special nuclear, or byproduct material only.

1989-10-01

200

Solid State Photovoltaic Research Branch  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the progress of the Solid State Photovoltaic Research Branch of the Solar Energy Research Institute (SERI) from October 1, 1988, through September 30,l 1989. Six technical sections of the report cover these main areas of SERIs in-house research: Semiconductor Crystal Growth, Amorphous Silicon Research, Polycrystalline Thin Films, III-V High-Efficiency Photovoltaic Cells, Solid-State Theory, and Laser Raman and Luminescence Spectroscopy. Sections have been indexed separately for inclusion on the data base.

1990-09-01

201

Review on the status of solid radwaste management in Korean NPPs  

International Nuclear Information System (INIS)

To minimize the low and intermediate-level solid radwaste volume, the reduction efforts were persisted in Korean NPPs. As a result, annual average waste volumes were reduced to 194 drums per unit at last year. In this paper we confirmed 250 drums/unit-yr, EPRI URD management goal, and management condition for solid radwaste volume. Also, through the sample assessment of specific Korean NPP opened to the public, we could make sure that the prediction of saturation year for interim storage facility is fully suitable.

2003-10-01

202

Realization of entirely solid lithium ion batteries; Realisation d`accumulateurs a ions lithium entierement solides  

Energy Technology Data Exchange (ETDEWEB)

This paper presents a prototype of an entirely inorganic lithium ions battery cell. LiCoO{sub 2} thin film cathodes and Li{sub 4/3}Ti{sub 5/3}O{sub 4} thin film anodes have been deposited on Li{sub 3x}La{sub 2/3-x}TiO{sub 3} sintered solid electrolyte pellets and the performances of these battery cells have been tested. (J.S.) 5 refs.

1996-12-31

203

Multiple stress aging of solid-dielectric extruded dry-cured insulation systems for power transmission cables  

Energy Technology Data Exchange (ETDEWEB)

A detailed examination of the aging processes that may take place in solid-dielectric extruded-type high voltage transmission cables under dry conditions is presented. Particular emphasis is placed on the aging process as affected by the separate and simultaneous action of four main aging factors, namely the electrical, mechanical and thermal stresses, and the physical and chemical environment. A number of pertinent aging models are considered and their validity and applicability to accelerated aging tests on solid-type transmission cables are discussed.

1994-01-01

204

Heat storage composition  

Energy Technology Data Exchange (ETDEWEB)

A heat storage compostion comprises sodium sulfate decahydrate as main component, a supercooling inhibitor, and a solid-liquid separation inhibitor. The composition is characterized in that hydraulic calcium sulfate and/or calcium sulfate dihydrate is contained as the solid-liquid separation inhibitor in an amount of 2-15 wt% base on the whole weight of the composition, whereby the solid-liquid separation, i.e. the sedimentation of the anhydrous sodium sulfate during the phase transition, is effectively prevented and the long-term stability is improved. The long-term stabilty of the composition can be more improved by addition of a silcia series of thickener.

1987-05-05

205

Feasibility study on the management of the disposal of Bangkok municipal waste. Final report  

Energy Technology Data Exchange (ETDEWEB)

In January, 1985, the Government of Thailand sought assistance from the United States Trade and Development Program (USTDP) to undertake a feasibility study to review and update the solid waste management master plan, with particular emphasis to be placed on waste disposal methods. In April, 1985, the USTDP engaged the firm of Engineering and Economic Research, Inc. to carry out a definitional/prefeasibility study to assess the potential of a project for solid waste management and energy production using municipal solid waste as fuel.

1989-09-01

206

Child mortality from solid-fuel use in India: a nationally-representative case-control study - article no. 491  

Energy Technology Data Exchange (ETDEWEB)

Most households in low and middle income countries, including in India, use solid fuels (coal/coke/lignite, firewood, dung, and crop residue) for cooking and heating. Such fuels increase child mortality, chiefly from acute respiratory infection. There are, however, few direct estimates of the impact of solid fuel on child mortality in India. Methods: We compared household solid fuel use in 1998 between 6790 child deaths, from all causes, in the previous year and 609 601 living children living in 1.1 million nationally-representative homes in India. Analyses were stratified by child's gender, age (neonatal, post-neonatal, 1-4 years) and colder versus warmer states. We also examined the association of solid fuel to non-fatal pneumonias. Solid fuel use was very common (87% in households with child deaths and 77% in households with living children). After adjustment for ...

2010-08-17

207

Acetylacetone in hydrogen solids: IR signatures of the enol and keto tautomers and UV induced tautomerization  

British Library Electronic Table of Contents (United Kingdom)

Acetylacetone is isolated in hydrogen matrices and is investigated by means of infrared spectroscopy, combined with theoretical calculations. The two stable enol and keto tautomers are well characterized. The keto/enol ratio in solid parahydrogen is found to be higher than in classical matrices. While vibrational bands of the enol form are broad, with bandwidths depending on the vibrational mode, those of the keto form are narrow. A KrF laser excitation is used to induce the enol/keto tautomerization in solid parahydrogen. The kinetics of the interconversion is followed, highlighting a non-direct tautomerization process.

2011-01-01

210

The alkali sorption process by solid sorbents at high temperature  

Energy Technology Data Exchange (ETDEWEB)

The removal of toxic metals and alkalis from gas streams at high temperatures was investigated. This is important for the development of coal-fired combined cycle power generation systems.

2000-03-01

211

Solubility of AmOHCO{sub 3} in aqueous solution under atmospheric conditions  

Energy Technology Data Exchange (ETDEWEB)

Modeling calculations on the solubility of americium have indicated that basic americium carbonate, and not americium trihydroxide, is the solubility-controlling solid in the pH range from 6 to 10 under the influence of atmospheric CO{sub 2}. The solubility of crystalline {sup 243}AmOHCO{sup 3} has been investigated in batch experiments in near-neutral and basic solutions as a function of dissolution time in 0.1 M NaClO{sup 4} at room temperature under oxic conditions. After the solutions reached steady-state conditions, the influence of dissolved solids on the americium concentration in the supernatant solution was studied by utilizing several experimental methods to separate the solution phase from the solid. The solids were characterized by X-ray powder diffraction analysis.

1987-12-01

212

Solid-state fermentation of lignocellulotic materials for the production of enzymes by the white-rot fungus Trametes hirsuta in a modular bioreactor  

British Library Electronic Table of Contents (United Kingdom)

Abstract Trametes hirsuta, a filamentous basidiomycete, was successfully cultivated in solid-state fermentation (SSF) on a mixture of pine wood chips and orange peel in a novel bioreactor that allows mixing of the inoculated solid material during the fermentation. Copper sulfate or xylidine (2,5-dimethylaniline) were added to enhance the production of enzymes, especially laccases. For comparison, Trametes hirsuta was also cultivated in submerged conditions. The effect of additives in SSF was low, whereas the choice of the solid material and the rotation of the reactor vessel showed a significant influence on the enzyme production. The space-time yields for the fermentations were calculated and showed that SSF on low-cost substrates can effectively produce extracellular enzymes at a suffici...

2011-01-01

213

SOLID STATE RESEARCH OF THE APPLIED PHYSICS ...  

Science.gov (United States)

... 10 TIN TELLURIDE Preparation of Tin Telluride Single Crystals ..... 12 ... TIN TELLURIDE Preparation of Tin Telluride Single Crystals ...

1962-07-16

214

Radiation deamination of tetracycline. [Gamma radiation  

Energy Technology Data Exchange (ETDEWEB)

The fundamental product of tetracycline hydrochlorine gamma radiolysis was separated in its solid state. From the results of spectroscopic studies it has been established that it is des-N,N-dimethylaminotetracycline.

1980-01-01

215

Physics of laser fusion. Volume IV. The future development of high-power solid-state laser systems  

Energy Technology Data Exchange (ETDEWEB)

Solid state lasers, particularly neodymium glass systems, have undergone intensive development during the last decade. In this paper, we review solid state laser technology in the context of high-peak-power systems for inertial confinement fusion. Specifically addressed are five major factors: efficiency, wavelength flexibility, average power, system complexity, and cost; these factors today limit broader application of the technology. We conclude that each of these factors can be greatly improved within current fundamental physical limits. We further conclude that the systematic development of new solid state laser madia, both vitreous and crystalline, should ultimately permit the development of wavelength-flexible, very high average power systems with overall efficiencies in the range of 10 to 20%.

1982-11-01

216

Physicochemical investigation of the behavior of elements in chloride melts in the presence of solid phases based on phosphates of polyvalent elements. II. Behavior of strontium and barium  

Energy Technology Data Exchange (ETDEWEB)

The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.

1987-07-01

217

Non-Markovian dephasing in solid-state single photon sources  

CERN Document Server

Solid-state single-photon sources have many desirable features that make them attractive for applications in quantum information processing. However, the phase coherence of such devices can be severely compromised by coupling to the solid-state environment. Here, we study the effects of realistic dephasing environments on a pair of solid-state single photon sources in the context of quantum interference effects such as the Hong-Ou-Mandel dip. By means of exact solutions for the non-Markovian dynamics of the sources, we show that the resulting loss of visibility depends crucially on the timing of photon detection events. Our results demonstrate that the effective visibility can be improved via temporal post-selection, and also that time-resolved interference can be a useful probe of the interaction between the emitter and its host environment.

2008-01-01

218

NASA - Waste Not  

Science.gov (United States)

Jun 4, 2004 ... On a two-year trip to Mars, according to one estimate, a crew of six humans will generate more than six tons of solid organic waste--much of ...

219

Mucinous cystadenoma of the pancreas with predominant stroma creating a solid tumor  

UK PubMed Central (United Kingdom)

BackgroundMucinous cystic neoplasm (MCN) of the pancreas is basically cystic epithelial neoplasm, unilocular or multilocular, occurring almost exclusively in women.Case...Full Text Available

220

Molten Boron Phase-Change Thermal Energy Storage ...  

Science.gov (United States)

... Advanced thermal storage systems based on very high temperature solid materials such as boron carbide or graphite have been investigated for ...

2011-06-01

221
222

Measured Temperatures of Solid Rocket Motors Dump Stored ...  

Science.gov (United States)

... TARGET SENSOR-MK 80 SERIES BOMBS ... 5-inch-, and 2.75-inch- diameter rocket motors that ... balance when compared to incoming solar radiation ...

1989-07-01

223

Kinetic behavior of solid particle in chemical-looping combustion: suppressing carbon deposition in reduction  

Energy Technology Data Exchange (ETDEWEB)

In order to apply chemical-looping combustion to a practical power plant, carbon deposition on the solid particle is one of the key problems to be overcome. Six kinds of solid particles were examined to clarify the kinetic behavior of carbon deposition. The effects of the solid composition, feed gas composition, and reaction temperature on carbon deposition were investigated by thermogravimetrical reactor on the basis of NiO/YSZ particle. From the viewpoints of both reactivity and resistance against carbon deposition, the particle of NiO mixed with YSZ (i.e., yttria-stabilized zirconia) was found to be a good candidate for chemical-looping combustion. It has been observed that carbon deposition could be completely avoided with very low concentration of water vapor. By means of a proposed model, the condition that carbon deposition would be avoided was identified. 12 refs., 8 figs., 2 tabs.

1998-03-01

224

General Disclaimer One or more of the Following Statements may ...  

Science.gov (United States)

major radius of the toroidal containment volume. The containment time was calculated using equation (4) as derived in references 16 and 17. The solid ...

227

ELECTRIC AND GALVANOMAGNETIC PROPERTIES OF ...  

Science.gov (United States)

... Abstract : The electric resistance in weak (diluted) solid solutions of the Pd-Ag and Fe-W systems, as wellAS THE Hall effect in a Pd-Ag system ...

1961-06-27

229

Crystal Chemistry of Ceramic/Mineral Systems  

Science.gov (United States)

... 1. Reeber, RR, Kusy, RP, Yu, N. and Chu, WK " Formation of a Solid Lubricant in Boron Carbide by Nitrogen Ion Implantation and Laser Annealing ...

1992-12-08

230

Compaction of dust clumps in a protostellar cloud  

Energy Technology Data Exchange (ETDEWEB)

Necessary conditions are derived for compact aggregates of solid matter to develop from loose local clumps of dust grains in a contracting protostellar cloud.

1984-01-01

231

Bacterial body plans  

UK PubMed Central (United Kingdom)

The bacterium Serratia marcescens produces a plethora of multicellular shapes of different colorations on solid substrates, allowing immediate visual detection of varieties. Such a...Full Text Available

2008-07-01

232

Aerodynamic Static Differential Pressure  

Science.gov (United States)

aerodynamic force and moment values. Only the solid and the 25 percent porous dishes were tested for the static pressure values used primarily to determine ...

234

A simple model for explosives formulation  

Energy Technology Data Exchange (ETDEWEB)

A simple model based on surface chemistry is developed, based an simple concepts of contact angle, wetting and spreading. Results of the modeling can be stated by two simplified rules of thumb'': (1) A liquid will spread on the surface of a solid if the surface tension of the liquid is lose than the surface free energy of the solid, and (2) The liquid having the surface tension nearest that of the solid will preferentially wet the surface of the solid. These two rules can then be used to define the parameters that constitute a process for formulating a plastic bonded explosive (PBX), which is a crystalline high-explosive material coated with a small amount of plastic polymeric material (the binder). The PBX then can be pressed to a high density, and machined to a specific shape. The pressed and machined explosive material can then be used in a physics experiment to study fundamental ...

1993-01-01

235

A simple model for explosives formulation  

Energy Technology Data Exchange (ETDEWEB)

A simple model based on surface chemistry is developed, based an simple concepts of contact angle, wetting and spreading. Results of the modeling can be stated by two simplified ``rules of thumb``: (1) A liquid will spread on the surface of a solid if the surface tension of the liquid is lose than the surface free energy of the solid, and (2) The liquid having the surface tension nearest that of the solid will preferentially wet the surface of the solid. These two rules can then be used to define the parameters that constitute a process for formulating a plastic bonded explosive (PBX), which is a crystalline high-explosive material coated with a small amount of plastic polymeric material (the binder). The PBX then can be pressed to a high density, and machined to a specific shape. The pressed and machined explosive material can then be used in a physics experiment to study fundamental properties of ...

1993-04-01

236

A novel accelerated oxidative stability screening method for pharmaceutical solids  

British Library Electronic Table of Contents (United Kingdom)

Abstract Despite the fact that oxidation is the second most frequent degradation pathway for pharmaceuticals, means of evaluating the oxidative stability of pharmaceutical solids, especially effective stress testing, are still lacking. This paper describes a novel experimental method for peroxide-mediated oxidative stress testing on pharmaceutical solids. The method utilizes urea-hydrogen peroxide, a molecular complex that undergoes solid-state decomposition and releases hydrogen peroxide vapor at elevated temperatures (e.g., 30C), as a source of peroxide. The experimental setting for this method is simple, convenient, and can be operated routinely in most laboratories. The fundamental parameter of the system, that is, hydrogen peroxide vapor pressure, was determined using a modified spect...

2011-01-01

237

A Theoretical Solid Oxide Fuel Cell Model for Systems Controls and Stability Design  

Science.gov (United States)

As the aviation industry moves toward higher efficiency electrical power generation, all electric

2008-01-01

238

Time-resolved resonance and linewidth of an ultrafast switched GaAs/AlAs microcavity  

CERN Document Server

We explore a planar GaAs/AlAs photonic microcavity using pump-probe spectroscopy. Free carriers are excited in the GaAs with short pump pulses. The time-resolved reflectivity is spectrally resolved short probe pulses. We show experimentally that the cavity resonance and its width depend on the dynamic refractive index of both the lambda-slab and the lambda/4 GaAs mirrors. We clearly observe a double exponential relaxation of both the the cavity resonance and its width, which is due to the different recombination timescales in the lambda-slab and the mirrors. In particular, the relaxation time due to the GaAs mirrors approaches the photon storage time of the cavity, a regime for which nonlinear effects have been predicted. The strongly non-single exponential behavior of the resonance and the width is in excellent agreement to a transfer-matrix model taking into account two recombination times. The change in width leads to a change in reflectivity modulation depth. ...

2009-01-01

239

Synthesis, characterization and biological evaluation of mononuclear Co(II), Ni(II), Cu(II) and Pd(II) complexes with new N2O2 Schiff base ligands.  

Science.gov (United States)

New tetradentate N(2)O(2) donor Schiff bases and their mononuclear Co(II), Ni(II), Cu(II), and Pd(II) complexes were synthesized and characterized extensively by IR, (1)H-, (13)C-NMR, mass, ESR, conductivity measurements, elemental and thermal analysis. Specifically the magnetic and electronic spectral measurements demonstrate the octahedral structures of cobalt(II), nickel(II) complexes and square planar geometries of copper(II), palladium(II) complexes. All the ligands and complexes were screened for their in vitro antibacterial activity against two gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus) and two gram-negative bacteria (Escherichia coli, Klebsiella pneumonia). In this study, Pd(II) complexes exhibited potent antibacterial activity against B. subtilis, S. aureus whereas other metal complexes also exerted good activity towards all tested strains even than standard drugs streptomycin and ampicillin. PMID:21297294

2011-02-01

240

Synthesis and characterization of luminescent square-planar platinum(II) complexes containing dithiolate or dithiocarbamate ligands  

Energy Technology Data Exchange (ETDEWEB)

The synthesis, characterization, and emission properties of a series of Pt(L{sub 2})(S-S) complexes are reported. The (L{sub 2}) ligands include 4,7-diphenyl-1,10-phenanthroline (Ph{sub 2}phen), 4,4{prime}-dimethyl-2,2{prime}-bipyridine (Me{sub 2}bpy), 1,5-cyclo-octadiene (COD), trimethyl phosphite (P(OMe){sub 3}), and the {alpha}-C-deprotonated form of 2-phenylpyridine (2-phpy). The (S-S) ligands include 1-(tert-butoxycarbonyl)-1-cyanoethylene-2,2-dithiolate (tbcda), 1-(diethoxyphosphinyl)-1-cyanoethylene-2,2-dithiolate (cpdt), cis-1,2-dicarbomethoxyethylene-1,2-dithiolate (met), and N,N-diethyldithio-carbamate (Et{sub 2}dtc). The complexes are readily synthesized by the addition of the dithiolate or thiolate ligand to Pt(L{sub 2})Cl{sub 2} except for Pt(P(OMe){sub 3}){sub 2}(met), which is prepared by the addition of 2 equiv of trimethyl phosphite to Pt(COD)(met).

1994-06-22

241

Syntheses, characterizations and structures of NO donor Schiff base ligands and nickel(II) and copper(II) complexes  

British Library Electronic Table of Contents (United Kingdom)

New Schiff base derivatives (L1 and L2) were prepared by the condensation of 2-hydroxy-3-methoxybenzaldehyde (o-vanillin) and 3-hydroxy-4-methoxybenzaldehyde (iso-vanillin) with 5-methylfurfurylamine. Two new complexes [Ni(L1)2] and [Cu(L1)2] have been synthesized with bidentate NO donor Schiff base ligand (L1). The Ni(II) and Cu(II) atoms in each complex are four coordinated in a square planar geometry. Schiff bases (L1 and L2) and complexes [Ni(L1)2] and [Cu(L1)2] were characterized by elemental analyses, FT-IR, UV-vis, mass and 1H, 13C NMR spectroscopies. The crystal structures of the ligand (L2) and complexes [Ni(L1)2] and [Cu(L1)2] have also been determined by using X-ray crystallographic technique.

2011-01-01

242

SnPc on Ag(111) investigated by STM  

Energy Technology Data Exchange (ETDEWEB)

The investigation of interfaces between thin organic films and metal surfaces is a field of highest interest because it represents the basis for future applications of organic electronic devices. In this context, phtalocyanines are of particular interest since repulsive intermolecular interaction was found recently for this group of organic molecules. Tin(II)-phtalocyanine (SnPc) is non-planar and can adsorb in two different geometries: with the Sn atom pointing downwards (Sn down) or upwards (Sn up). In our group different Pc molecules have previously been studied using several experimental techniques like SPA-LEED or XSW. Here we present STM studies of SnPc on Ag(111), taken at different coverages and temperatures, and discuss the results in the context of our previous findings. At low coverages the formation of chains can be observed for Sn down molecules while Sn up molecules tend to stay separated. This originates from a strong interaction with the substrate ...

2010-07-01

243

Review and Understanding of Screen-Printed Contacts and Selective-Emitter Formation: Preprint  

Energy Technology Data Exchange (ETDEWEB)

A comparison of the loss mechanisms in screen-printed solar cells relative to buried contact cells and cells with photolithography-defined contacts is presented in this paper. Model calculations show that emitter recombination accounts for about 0.5% absolute efficiency loss in conventional screen-printed cells with low-sheet-resistance emitters. Ohmic contact to high-sheet-resistance emitters by screen-printing has been investigated to regain this efficiency loss. Our work shows that good quality ohmic contacts to high sheet-resistance emitters can be achieved if the glass frit chemistry and Ag particle size are carefully tailored. The melting characteristics of the glass frit determine the firing scheme suitable for low contact resistance and high fill factors. In addition, small to regular Ag particles were found to help achieve a higher open-circuit voltage and maintain a low contact resistance. This work has resulted in cells with high fill factors (0.782) on high sheet-resistance ...

2004-08-01

244

Quantum query complexity of minor-closed graph properties  

CERN Document Server

We study the quantum query complexity of minor-closed graph properties, which include such problems as determining whether a graph is planar, is a forest, or does not contain a path of a given length. We show that most minor-closed properties---those that cannot be characterized by a finite set of forbidden subgraphs---have quantum query complexity \\Theta(n^{3/2}). To establish this, we prove an adversary lower bound using a detailed analysis of the structure of minor-closed properties with respect to forbidden topological minors and forbidden subgraphs. On the other hand, we show that minor-closed properties (and more generally, sparse graph properties) that can be characterized by finitely many forbidden subgraphs can be solved strictly faster, in o(n^{3/2}) queries. Our algorithms are a novel application of the quantum walk search framework and give improved upper bounds for several subgraph-finding problems.

2010-01-01

245

Plane Shock Generator Explosive Lens: Shock characterization of 4340 and PH13-8Mo steels, C360 brass and PZT 65/35 ferro-electric ceramic  

Energy Technology Data Exchange (ETDEWEB)

Sandia National Laboratories is currently involved in the optimization of a Plane Shock Generator Explosive Lens (PSGEL). The PSGEL component consists of a detonator, explosive, brass cone and tamper housing. The purpose of the PSGEL component is to transmit a plane shock wave through the 4340 steel bulkhead (wave separator) which has a ferro-electric (PZT)ceramic disk attached to the opposite surface of the steel bulkhead. The planar shock wave depolarizes the PZT 65/35 ferro-electric ceramic to produce an electrical output. One aspect of the optimization program involves the possible replacement of 4340 steel with PH13-8Mo steel for the bulkhead. These materials, as well as the PZT 65/35 ferro-electric ceramic and the brass for the cone, required the stock characterization with respect to Hugoniot parameters. The work presented here gives the shock Hugoniot values for these four materials and documents their measurements.

1994-03-01

246

Planar excilamp on rare gas chlorides pumped by a transverse self-sustained discharge  

Science.gov (United States)

The design and parameters of a UV-VUV spontaneous radiation source - an excilamp operating on chlorides of rare gases ArCl{sup *}, KrCl{sup *} and XeCl{sup *} in the wavelength range 175-308 nm are presented. The Ne-Xe(Kr, Ar)-HCl mixtures were excited by a high-pressure self-sustained discharge with spark preionisation. It is shown that upon pumping mixtures of rare gases and halogens by a transverse discharge, the intensities of the B-X emission band of molecules ArCl{sup *}, KrCl{sup *} and XeCl{sup *} are comparable and up to 90% of the emission energy of excilamps can be concentrated in the UV region. The peak UV power density at 222 and 308 nm on the output window of the excilamp was {approx}2 kW cm{sup -2} for the pulse energy up to {approx} 3 mJ. The output emission energy of the excilamp at 175 nm achieved {approx}0.6 mJ and the peak power density was {approx}0.4 kW cm{sup -2}. (laser applications and other topics in quantum electronics)

2006-02-28

247

Photoconductive ultraviolet detectors based on ZnO films  

Energy Technology Data Exchange (ETDEWEB)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360 nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8 mA, and a slow photoresponse with a rise time of 5 min and a decay time of 7 min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the decrease of the barrier height between crystallites. The relaxation time constant {tau} obtained from the curve fitting represents the time accumulation during the process. The ...

2006-12-15

248

Photoconductive ultraviolet detectors based on ZnO films  

International Nuclear Information System (INIS)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360 nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8 mA, and a slow photoresponse with a rise time of 5 min and a decay time of 7 min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the decrease of the barrier height between crystallites. The relaxation time constant #tau# obtained from the curve fitting represents the time accumulation during the process. The ...

2006-12-15

249

On the origin of the Trojan asteroids Effects of Jupiter's mass accretion and radial migration  

CERN Document Server

We present analytic and numerical results which illustrate the effects of Jupiter's accretion of nebular gas and the planet's radial migration on its Trojan companions. Initially, we approximate the system by the planar circular restricted three-body problem and assume small Trojan libration amplitudes. Employing an adiabatic invariant calculation, we show that Jupiter's thirty-fold growth from a $10 M_\\oplus$ core to its present mass causes the libration amplitudes of Trojan asteroids to shrink by a factor of about 2.5 to $\\sim 40%$ of their original size. The calculation also shows that Jupiter's radial migration has comparatively little effect on the Trojans; inward migration from 6.2 to 5.2 AU causes an increase in Trojan libration amplitudes of $\\sim4%$. In each case, the area enclosed by small tadpole orbits, if made dimensionless by using Jupiter's semimajor axis, is approximately conserved. Similar adiabatic invariant calculations for inclined and ...

2000-01-01

250

New Tc-99m brain imaging agents  

Energy Technology Data Exchange (ETDEWEB)

In developing new Tc-99m brain perfusion imaging agents for SPECT, a series of BAT (bis-aminoethanethiol) derivatives was prepared. These N/sub 2/S/sub 2/ ligands formed stable and neutral complexes with reduced Tc-99m, either by Sn(II)-PPi or sodium borohydride reduction. The purity of the Tc-99m complexes was >95% (HPLC reverse-phase column, acetonitrile: pH 7.0 buffer, 85:15). The biodistribution in rats was evaluated using I-125 iodoantipyrine (IAP), a free diffusible tracer, as the internal reference. Compounds with a free hydroxyl group (I and IV) showed lower brain uptake, inspite of high P.C.; this may be related to in vivo instability of the complexes. High initial brain uptake was observed for three compounds (II, III and V), however, only compound V (P.C.=384) showed significant brain retention. Planar imaging with compound V in a monkey demonstrated that the compound localized in brain and the retention time was T/sub 1/2/=35 min. Compounds of this ...

1984-01-01

251

New Tc-99m brain imaging agents  

International Nuclear Information System (INIS)

In developing new Tc-99m brain perfusion imaging agents for SPECT, a series of BAT (bis-aminoethanethiol) derivatives was prepared. These N/sub 2/S/sub 2/ ligands formed stable and neutral complexes with reduced Tc-99m, either by Sn(II)-PPi or sodium borohydride reduction. The purity of the Tc-99m complexes was >95% (HPLC reverse-phase column, acetonitrile: pH 7.0 buffer, 85:15). The biodistribution in rats was evaluated using I-125 iodoantipyrine (IAP), a free diffusible tracer, as the internal reference. Compounds with a free hydroxyl group (I and IV) showed lower brain uptake, inspite of high P.C.; this may be related to in vivo instability of the complexes. High initial brain uptake was observed for three compounds (II, III and V), however, only compound V (P.C.=384) showed significant brain retention. Planar imaging with compound V in a monkey demonstrated that the compound localized in brain and the retention time was T/sub 1/2/=35 min. Compounds of this ...

1984-06-05

252

Moving finite element codes in one and two dimensions. Final report  

Energy Technology Data Exchange (ETDEWEB)

Many problems in physics necessitate the solution of equations which develop sharp gradients, such as shocks. These include atmospheric shocks near the earth's surface, plasma physics phenomena, both in the laboratory and in space, combustion, petroleum reservoir modelling, and light propagation in glass fibers. To deal with this situation, methods are needed which place a high density of nodes in the neighborhoods of the steep gradients. One of the most promising of these methods is the moving finite element method which was first invented by Miller. This approach, in which the nodes are moved so as to minimize the residual error, has been used successfully by Gelinas, Doss, and co-workers to study several different one-dimensional problems and shows great promise as well in dealing with two dimensions. A paper describing the one-dimensional results has already been published, and a paper describing the two-dimensional results is in preparation. The remainder of this report ...

1985-10-01

253

Monovalent cation-induced structure of telomeric DNA: The G-quartet model  

Energy Technology Data Exchange (ETDEWEB)

We have investigated the structures formed by oligonucleotides composed of two or four repeats of the telomeric sequences from Oxytricha and Tetrahymena. The Oxytricha four-repeat molecule (d(T4G4)4 = Oxy-4) forms structures with increased electrophoretic mobility in nondenaturing gels containing Na+, K+, or Cs+, but not in gels containing Li+ or no added salt. Formation of the folded structure results in protection of a set of dG's from methylation by dimethyl sulfate. Efficient UV-induced cross-links are observed in Oxy-4 and the related sequence from Tetrahymena (d(T2G4)4 = Tet-4), and join thymidine residues in different repeats. Models proposed to account for these data involve G-quartets, hydrogen-bonded structures formed from four guanosine residues in a square-planar array. We propose that the G-quartet structure must be dealt with in vivo by the telomere replication machinery.

1989-12-01

254

Large area, low capacitance Si(Li) detectors for high rate x-ray applications  

Energy Technology Data Exchange (ETDEWEB)

Large area, single-element Si(Li) detectors have been fabricated using a novel geometry which yields detectors with reduced capacitance and hence reduced noise at short amplifier pulse-processing times. A typical device employing the new geometry with a thickness of 6 mm and an active area of 175 mm 2 has a capacitance of only 0.5 pf, compared to 2.9 pf for a conventional planar device with equivalent dimensions. These new low capacitance detectors, used in conjunction with low capacitance field effect transistors, will result in x-ray spectrometers capable of operating at very high count rates while still maintaining excellent energy resolution. The spectral response of the low capacitance detectors to a wide range of x-ray energies at 80 K is comparable to typical state-of-the-art conventional Si(Li) devices. In addition to their low capacitance, the new devices offer other advantages over conventional detectors. Detector fabrication procedures, I-V and C-V ...

1992-10-01

255

Intensification of harmonic spontaneous radiation with a novel undulator  

International Nuclear Information System (INIS)

We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessivecurrent in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K1 is greatly enhanced for the approximate square-wave magnetic profile: the ratio of the power emitted at f=5 by the square-wave undulator to that of the sine-wave undulator is about 15 (whereas the corresponding ...

1999-07-01

256

Intensification of Harmonic Spontaneous Radiation with a Novel Undulator  

Science.gov (United States)

We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessive current in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K < 1, for spontaneous radiation emitted along the axis of the system. The emission at harmonics f > 1 is greatly enhanced for the approximate square-wave magnetic profile: the ratio of the power emitted at f=5 ...

1998-11-01

257

Influence of duration and rate of pulse rise of the applied voltage on ozone concentration in the barrier glow discharge  

International Nuclear Information System (INIS)

The barrier glow discharge between two planar electrodes, covered with dielectric, is studied under high-voltage pulsed power supply. Wide applications of such type of discharges, in particular, for ozone production, stimulated a number of investigations in this direction. In this work we investigated the dependence of ozone concentration on the duration and the rate of pulse rise of the applied voltage. The thyristor converter circuit with the shortening of input pulses on the base of the saturable throttle was used for the realization of this task. The output pulses with amplitude up to 15 kV, repetition frequency of 1 kHz, pulse duration of 0.3 #mu#s (or 7 #mu#s) and the rate of pulse rise of 0.1 #mu#s were generated with this scheme. Measurements of the ozone concentration produced in the air mixture have shown that its value increased by factor two with variation of the rate of pulse rise from 0.5 #mu#s to 0.1 #mu#s (for pulse duration of 7 #mu#s). The ...

2005-09-06

258

Improvement of the crossed undulator design for effective circular polarization control in X-ray FELs  

CERN Document Server

The production of X-ray radiation with a high degree of circular polarization constitutes an important goal at XFEL facilities. A simple scheme to obtain circular polarization control with crossed undulators has been proposed so far. In its simplest configuration the crossed undulators consist of pair of short planar undulators in crossed position separated by an electromagnetic phase shifter. An advantage of this configuration is a fast helicity switching. A drawback is that a high degree of circular polarization (over 90%) can only be achieved for lengths of the insertion devices significantly shorter than the gain length, i.e. at output power significantly lower than the saturation power level. The obvious and technically possible extension considered in this paper, is to use a setup with two or more crossed undulators separated by phase shifters. This cascade crossed undulator scheme is distinguished, in performance, by a fast helicity switching, a high degree ...

2011-01-01

259

High-resolution stratigraphy in a Miocene reservoir of the Niger delta  

Energy Technology Data Exchange (ETDEWEB)

High-resolution sequence stratigraphy concepts are applied to Erema, a Miocene onshore field of the Niger delta. The field's production is decreasing and an up-to-date geological model is essential to monitor the production. We aim to show an approach, using subsurface data and sequence stratigraphic concepts, which results in a time-line (Maximum Flooding Surfaces) correlation scheme. This scheme is based upon a facies model and is destined to guide the study of the characterization of reservoir heterogeneities. Using the cored well as a reference point, the facies model consists of shoreface dunes (planar tabular cross-stratified sandstones) changing landward into fluvial distributary deposits (through cross-stratified sandstones) via a tide-influenced coastal plain facies. The stacking pattern of genetic units shows a seaward stepping phase at the reservoir scale (sixty metres thick) with an abrupt deepening at the top of the reservoir. The proposed ...

1994-06-30

260

High temperature fatigue damage in three austenitic alloys  

Energy Technology Data Exchange (ETDEWEB)

A series of cyclic strain controlled tests have been carried out at 600/sup 0/C on three high temperature austenitic iron-based alloys, AISI type 316 stainless steel, Alloy 800 H and Sandvik 253 MA. The tests were carried out under constant total strain control using a constant strain rate of 0.005 s/sup -1/. By considering the changes in modulus throughout the life of each specimen it was found that damage evolution could be successfully predicted as a function of plastic strain range despite the fact that each alloy had been chosen because of a different stress response at 600/sup 0/C. Although each alloy accumulated fatigue damage in a similar manner the longer lives of Sandvik 253 MA and Alloy 800 H at a given total strain range were due to a smaller plastic strain component and a reduced stage I crack propagation rate. In the 253 MA alloy, slip was predominantly planar with some cells occasionally forming at high strain ranges. Slip was localized in Alloy 800 ...

1988-01-01

261

Generation of ozone by pulsed corona discharge over water surface in hybrid gas-liquid electrical discharge reactor  

International Nuclear Information System (INIS)

Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min"-"1), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production was obtained using high voltage pulses of approximately 150 ns duration in Ar/O_2 mixtures with the maximum efficiency (energy yield) of 23 g kW ...

2005-02-07

262

Fault-related-folding structure and reflection seismic sections. Construction of earth model using balanced cross section; Danso ga kaizaisuru shukyoku kozo no keitai to jishin tansa danmen. 1. Balanced cross section wo mochiita chika model no kochiku  

Energy Technology Data Exchange (ETDEWEB)

Pre-stacking depth migration treatment is studied for the estimation of the fold configuration from seismic survey cross sections. The estimation of a velocity structure is necessary for the execution of such treatment, and the utilization of structural-geological knowledge is required for its interpretation. The concept of balanced cross section in relation to the fault-bend fold constructs a stratum structure model under conditions that the deformation during fold and fault formation is a planar strain, that there is no change in volume due to deformation, and that a fold is a parallel fold. In addition to the above geometric and kinetic approach, there is another fold formation process simulation model using a Newtonian fluid for study from the viewpoint of dynamics. This simulation stands on the presumption that the boundary contains a ramp that had been in presence before fold formation and that an incompressible viscous matter is mounted on the top surface. ...

1997-05-27

263

Fabrication and characterization of Cu/YSZ cermet high temperature electrolysis cathode material prepared by high-energy ball-milling method  

Energy Technology Data Exchange (ETDEWEB)

Cu/YSZ cermet (40 and 60 vol.% Cu powder with balance YSZ) is a more economical cathode material than the conventional Ni/YSZ cermet for high temperature electrolysis (HTE) of water vapor and it was successfully fabricated by high-energy ball-milling of Cu and YSZ powders, pressing into pellets (o 13 mm x 2 mm) and subsequent sintering process at 700 deg. C under flowing 5%-H{sub 2}/Ar gas. The Cu/YSZ composite material thus fabricated was characterized using various analytical tools such as XRD, SEM, and laser diffraction and scattering method. Electrical conductivity of sintered Cu/YSZ cermet pellets thus fabricated was measured by using 4-probe technique for comparison with that of conventional Ni/YSZ cermets. The effect of composite composition on the electrical conductivity was investigated and a marked increase in electrical conductivity for copper contents greater than 40 vol.% in the composite was explained by percolation threshold. Also, Cu/YSZ cermet was selected as a ...

2009-01-07

264

Enhanced defect detection and sizing accuracy using matrix phased array ultrasonic tools  

Energy Technology Data Exchange (ETDEWEB)

Although ultrasonic testing inspection technology and tools have improved significantly, there is still a need for more reliable detection, monitoring, and accurate sizing of crack-like and planar defects, complex corrosion damage, and detection of secondary features within deformed pipe. Ultrasonic two dimensional (2D) matrix phased array technology offers some unique advantages that make the technology promising for improving detection and sizing of pipeline flaws resulting from welding or from in-service damage. Ultrasonic modeling and simulation has been conducted to evaluate the detection and sizing capabilities of 2D matrix arrays for various pipeline inspection concepts. Simulations have been performed using both flexible and rigid array probes. Inspection concepts using rigid probes were evaluated for inspections from both the outside and inside pipe surfaces, while flexible probes were evaluated primarily for inspection from the outside surface when dents ...

2009-07-01

265

Electrical biasing and voltage contrast imaging in a focused ion beam system  

Energy Technology Data Exchange (ETDEWEB)

We present two new techniques that enhance conventional focused ion beam (FIB) system capabilities for integrated circuit (IC) analysis: in situ electrical biasing and voltage contrast imaging. We have used in situ electrical biasing to enable a number of advanced failure analysis applications including (1) real time evaluation of device electrical behavior during milling and deposition, (2) verification of IC functional modifications without removal from the FIB system, and (3) ultraprecision control for cross sectioning of deep submicron structures, such as programmed amorphous silicon antifuses. We have also developed FIB system voltage contrast imaging that can be used for a variety of failure analysis applications. The use of passive voltage contrast imaging for defect localization and for navigation on planarized devices will be illustrated. In addition, we describe new, biased voltage contrast imaging techniques and provide examples of their application to ...

1995-09-01

266

Diaqua[N,Nprime-(o-phenylene)bis(pyridine-2-carboxamidato)-k4N]manganes e(III) perchlorate  

British Library Electronic Table of Contents (United Kingdom)

In the MnIII complex of the title compound, [MnIII(C18H12N4O2)(H2O)2]ClO4, the MnIII atom is coordinated by four N atoms from the bpb2- [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yielding a distorted MnN4O2 octahedral coordination geometry. The bpb2- ligand is nearly planar, with a maximum deviation of 0.2311 (3) A from the mean plane. The MnIII complex cation and the perchlorate anion, both of which are located on twofold rotation axes, are connected by O-H...O and C-H...O hydrogen bonds into a three-dimensional supramolecular network structure.

2007-01-01

267

Detection of Second-Layer Corrosion in Aging Aircraft Fuselage  

International Nuclear Information System (INIS)

A Digital X-ray imaging system using Compton backscattering has been developed to obtain a cross-sectional profile and mass loss of corroded lap-splices of aging aircraft from density variation. A slit-type camera was designed to focus on a small scattering volume inside the material, from which the backscattered photons are collected by a collimated scintillator detector for interpretation of material characteristics. The cross section of the lap-joint is scanned by moving the scattering volume through the thickness direction of the specimen. The mass loss of each layer has been estimated from a Compton backscatter A-scan to obtain the thickness of each layer including the aluminum sheet, the corrosion layer and the sealant. Quantitative information such as location and width of planar corrosion in the lap splices of fuselages is obtained by deconvolution using a nonlinear least-square error minimization method(BFGS method): A simple reconstruction model is also ...

2006-12-01

268

Detection of Second-Layer Corrosion in Aging Aircraft  

International Nuclear Information System (INIS)

The Compton backscatter technique has been applied to lap-joint in aircraft structure in order to determine mass loss due to exfoliative corrosion of the aluminum alloy sheet skin. The mass loss of each layer has been estimated from Compton backscatter A-scan including the aluminum sheet, the corrosion layer, and the sealant. A Compton backscattering imaging system has been also developed to obtain a cross-sectional profile of corroded lap-splices of aging aircraft using a specially designed slit-type camera. The camera is to focus on a small scattering volume inside the material from which the backscattered photons are collected by a collimated scintillator detector for interpretation of material characteristics. The cross section of the layered structure is scanned by moving the scattering volume through the thickness direction of the specimen. The theoretical model of the Compton scattering based on Boltzmann transport theory is presented for quantitative characterization of ...

2009-12-01

269

Crystallography of grain boundary #alpha# precipitates in a #beta# titanium alloy  

International Nuclear Information System (INIS)

The crystallography of #alpha#(hcp) precipitates formed on the #beta#(bcc) matrix grain boundaries has been studied with transmission electron microscopy (TEM) in a Ti-15V-3Cr-3Sn-3Al alloy. The #alpha# precipitates have a near-Burgers orientation relationship with respect to at least one of the adjacent #beta# grains. Among the possible 12 variants in this orientation relationship, the variant that [11 bar 20]_#alpha# is parallel to the _#beta# closest to the grain boundary plane tends to be preferred by the #alpha# precipitates. Additionally, further variant selections are made so as to minimize the deviation of orientation relationship with respect to the ''opposite'' #beta# grain from the Burgers one. Such rules in variant selection often result in the formation of precipitates with a single variant at a planar grain boundary. Prior small deformation of #beta# matrix changes the variant of #alpha# precipitates at the deformed portion of grain boundary. It is ...

1994-10-03

270

A comparison of the low-cycle fatigue behavior of Alloy 800 and Alloy 800H  

International Nuclear Information System (INIS)

At 650"0C, the low-cycle fatigue life was essentially the same for the two alloys on the basis of strain amplitude, but Alloy 800H had a longer life on the basis of stress amplitude. A 500"0C, Alloy 800 and 800H exhibited longer fatigue lifetime than at 650"0C, with Alloy 800 exhibiting a 2-3 times longer life than Alloy 800H when compared on the basis of plastic strain range, whereas the difference was less pronounced when compared on the basis of stress amplitude. When a creep effect was introduced either by way of a hold time or a reduced frequency, Alloy 800 exhibited a greater reduction in life than did Alloy 800H. The dislocation structure changed from planar to cellular with increase in strain range, and extensive precipitation of M_2_3C_6 was noted within the grains for Alloy 800H and along grain boundaries for both alloys. (Auth.).

271

Immunoscintigraphy with anti-225.28S for ocular melanoma - a comparison with histology and immunohistochemistry  

Energy Technology Data Exchange (ETDEWEB)

Aim: The purpose of this prospective study was to evaluate the value of immunoscintigraphy (ISG) with anti-225.28S in clinically suspected ocular melanoma. Methods: For this purpose standardized ISG was performed in 36 patients using both planar acquisition and emission computed tomography (ECT). Ocular melanoma was present in 31 patients. In 21 patients therapy was enucleation of the eye. These specimens were evaluated by histology and immunohistochemistry in 11 of 21 patients. Results: Regarding the clinical diagnosis, ISG was positive only in 15 of 31 patients with ocular melanoma, regarding histology in 11 of 21 and regarding immunohistochemistry in 5 of 6 patients with a positive immunoreaction. 5 patients showed no immunoreactivity, their ISG was negative. Conclusion: Thus a good correlation between ISG and immunohistochemistry was observed. However ISG using the cutaneous melanoma antibody 225.28S cannot be recommended for the diagnostic work-up of an ocular ...

1997-03-01

272

Treatment for dismantled radioactive solid waste from the TRIGA Mark-2 and 3  

Energy Technology Data Exchange (ETDEWEB)

Radioactive wastes are generally classified into 3 type depending on their physical property: liquid, solid and gaseous type. State-of -the art concerning liquid waste treatment has already been published; KAERI/TR-1315/99. Solid wastes classification package and treatment method will be studied to effectively manage them during the practical decommissioning work. All of the spent fuel produced during the operation of the TRIGA Mark-2 and 3 have been transported to the US last year, 1998, according to the spent fuel management strategy set-up by the US government for the non-proliferation of nuclear energy. Solid wastes are mainly all equipment existing inside of the reactors, activated concrete among the bio-shielded concrete, pipes, pimps, resin filter and it's housings, heat-exchangers, liquid waste storage tanks, to radioactive waste storage treatment facilities and so on. Solid wastes are ...

1999-06-01

273

Target R and D at JAERI  

Energy Technology Data Exchange (ETDEWEB)

We proposed a solid and a mercury target concepts through the preliminary conceptual design. To feasible these concepts, analysis and experimental works are being carried out. This paper introduces an outline of present status of target R and D such as heat transfer augmentation experiments for the solid target, mercury flow tests with a loop of maximum flow rate of 15L/min, flow pattern measurements for a cold source moderator etc. as well as preliminary conceptual design works. (author)

1999-03-01

274

Solid state NMR, basic theory and recent progress for quadrupole nuclei with half-integer spin  

International Nuclear Information System (INIS)

This review describes the basic theory and some recently developed techniques for the study of quadrupole nuclei with half integer spins in powder materials. The latter is connected to the introduction of the double rotation (DOR) by A. Samoson et al. (1) and to the introduction of the multiple quantum magic-angle spinning (MQ MAS) technique by L. Frydman et. al. (2). For integer spins, especially the solid-state deuterium magnetic resonance, we refer to the review of G.L. Hoatson and R.L. Vold: ''"2H-NMR Spectroscopy of Solids and Liquid Crystals'' (3). For single crystals we refer to O. Kanert and M. Mehring: ''Static quadrupole effects in disordered cubic solids''(4) and we would like also to mention the ''classic'' review of M.H. Cohen and F. Reif: ''Quadrupole effects in NMR studies of solids'' (5). Some more recent reviews in the field under study are D. Freude and J. Haase ''Quadrupole effects in ...

1998-12-01

275

Sealant Research for solid oxide fuel cells  

International Nuclear Information System (INIS)

The objective of this work is to develop sealing materials for solid oxide fuel cells (SOFCs). A suitable sealant must form strong, dense bonds with SOFC components, be chemically and mechanically compatible with the components, be stable at 1000 degrees C in the operating environment of the SOFC (H_2 and H_2O on the anode side, O_2 on the cathode side), and must be nonconductive.

1992-07-01

276

Satellite power systems (SPS) concept definition study (Exhibit D). Solid-state amplifier investigation. Final report  

Energy Technology Data Exchange (ETDEWEB)

Data resulting from a continuing effort to provide system/subsystem definition data to aid in the evaluation of the SPS program concept is presented. The specific data described relate to the proposed use of solid state devices as microwave power amplifiers in the satellite microwave power transmission subsystem.

1981-04-01

277

Room temperature synthesis of tri-, tetrasubstituted imidazoles and bis-analogues by mercaptopropylsilica (MPS) in aqueous methanol: application to the synthesis of the drug trifenagrel  

British Library Electronic Table of Contents (United Kingdom)

The heterogeneous solid catalyst, mercaptopropylsilica (MPS), has been prepared by a modified procedure in water and its structure confirmed by solid state carbon-13 CP-MAS NMR spectrum. This catalyst has been efficiently utilized for the synthesis of a wide variety of tri-, tetrasubstituted imidazoles and their bis-analogues at room temperature. The protocol was further explored for the synthesis of the drug trifenagrel.

2010-01-01

278

Quantum theory of light interstitial diffusion and other aspects of inert gas motion in solids  

International Nuclear Information System (INIS)

Most diffusion phenomena in solids can be understood (or sometimes misunderstood) on a purely classical model. For light interstitials (hydrogen isotopes, the positive muon, and potentially He) there may be anomalous temperature dependences, and isotope effects, and anomalous response to electric fields and temperature gradients. Some of these anomalies are quantal in origin, and will be discussed. (author).

1980-03-01

279

Process for uranium processing  

International Nuclear Information System (INIS)

To the crushed ore leaching is applied. The resulting solid-liquid mixture is fed to a hydro-cyclon grading facility; here the superfine grain is separated before the concentrated mixture can be filtered or centrifuged. The grading is done in several steps. From the liquid, ultimately ridded of the solid, uranium compounds are precipitated and the yellow cake is obtained. (DG).

1984-11-12

280

Municipal solid waste management in Lebanon: the need for an integrated approach  

International Nuclear Information System (INIS)

Full text.This study focuses on the management of municipal solid waste (MSW) in Lebanon. It addresses the current status of MSW management in Lebanon in terms of collection, transport and disposal, infers the associated impacts of such practices and discusses mitigation measures and finally proposes basic guidelines for a national strategy for solid waste management in the country. The study is based on available previous investigations and on a field survey of 113 villages in four different countries. The study revealed the absence of an effective environmental policy and poor collection and disposal methods throughout the country, except for the Greater Beirut Area (G A), where better solid waste management practices are employed. Although collection of MSW outside GBA was found to be acceptable by local authorities, resources (labor and equipment) were not used efficiently. Furthermore, treatment of collected waste is ...

2000-11-23

281

Microwave Combustion and Sintering Without Isostatic Pressure  

Energy Technology Data Exchange (ETDEWEB)

This investigation involves a study of the influence of key processing parameters on the heating of materials using microwave energy. Selective and localized heating characteristics of microwaves will be utilized in the sintering of ceramics without hydrostatic pressure. In addition, combustion synthesis will be studied for the production of powders, carbides, and nitrides by combining two or more solids or a solid and a gas to form new materials. The insight gained from the interaction of microwaves with various materials will be utilized in the mobilization and subsequent redeposition of uranium.

1998-10-20

282

Measurement of the susceptibility of solid "3He along the melting curve from 20 mK down to the nuclear ordering temperature  

International Nuclear Information System (INIS)

The susceptibility of solid "3He is deduced from multiple echoes observed in pulsed NMR experiments. It follows a Curie Weiss law at high temperature, increases faster than this law below 5 mK and drops abruptly around 1 mK. (Auth.).

1977-02-01

283

Limiting-dilution analysis of T cells extracted from solid human lung tissue: comparison of precursor frequencies for proliferative responses and lymphokine production between lung and blood T cells from individual donors.  

UK PubMed Central (United Kingdom)

This study evaluates the frequency and functions of immunocompetent T cells at the clonal level in solid human lung tissue versus peripheral blood. Enzymatic digestion of slices of histologically normal...Full Text Available

1988-08-01

284

Lattice parameters and thermal expansion of solid ortho-deuterium  

Energy Technology Data Exchange (ETDEWEB)

X-ray results on the lattice parameters, molar volume and thermal expansion coefficients of solid ortho-deuterium for the region from 2 K to the melting point are reported. It is found that the thermal expansion of ortho-deuterium crystals, similarly to parahydrogen is essentially anisotropic near the melting temperature. The vacancy density at the triple point is estimated. Some thermodynamic characteristics of ortho-deuterium are calculated and temperature dependences of heat capacity at constant volume, isothermal compressibility and Gruneisen constant are analyzed.

1984-01-01

285

Kinetics of achieving equilibrity at the sorption of radionuclides  

International Nuclear Information System (INIS)

Radionuclide (R) sorption from a solution (vapor) by freshly formed crystals with production of substitution solid solutions under different types of self-disordering is studied. Changes of self-defectiveness and macrodefectiveness with time and effect of radiation defects in the presence of P macroquantities are taken into account. An analysis for monodispersed sorbents is performed. It is shown that the achievement of equilibrium within a reasonable time in impurity-solid phase system depends on defectiveness which ensures a required level of the coefficient of impurity diffusion in sorbent crystals.

286

Investigation of radiation defects in solids using the EXAFS method  

International Nuclear Information System (INIS)

The exafs method is proposed as a more informative, universal one to investigate the radiation defects in solids. The successful results as obtained by the author using the synchrotron radiation source are reported for the first time. The measurements were carried out in GaAsP crystals irradiated with 50 MeV electrons.

1978-02-15

287

Interphase mass transfer in the separation of isotopes in countercurrent columns (liquid-solid systems)  

International Nuclear Information System (INIS)

The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.

288

Intermediates to ethylene glycol: carbonylation of formaldehyde catalyzed by Nafion solid perfluorosulfonic acid resin  

Energy Technology Data Exchange (ETDEWEB)

Details of a series of reactions for the production of ethylene glycol using a catalyst of Nafion solid perfluorosulfonic acid resin was detailed. The reactions included the carbonylation of formaldehyde and esterification and then hydrogenation of the product of the carbonylation, glycolic acid. Other preparations included in the work included methyl glycolate, acetylglycolic acid, methyl acetylglycolate, and methyl methoxyacetate.

1983-01-01

289

Influence of tumour volume and cell kinetics on the response of the solid Yoshida sarcoma to hyperthermia (42 degrees C).  

UK PubMed Central (United Kingdom)

The cytokinetic response of the solid Yoshida sarcoma to hyperthermia was examined at two tumour volumes, 1.0-1.5 ml and 3.0-3.5 ml. The tumour, growing on the feet of rats, was heated at 42 degrees...Full Text Available

1980-01-01

290

Formation of nano-sized particles of a solid electrolyte by laser ablation  

Energy Technology Data Exchange (ETDEWEB)

Nano-sized particles of a lithium ion conductive solid electrolyte, LiTi{sub 2}(PO{sub 4}){sub 3}, were prepared by laser ablation. The obtained particles were ca. 10nm in diameter. X-ray powder diffraction and Raman spectroscopy showed that they were amorphous with local structure similar to the crystalline counterpart. They were crystallized by the heating at ca. 630{sup o}C. (author)

2005-08-26

291

Explicit equation for particle settling velocities in solid-liquid systems  

Energy Technology Data Exchange (ETDEWEB)

Zanker has recently presented nomographs for determining particle settling velocities in solid-liquid systems. These nomographs were based on the general correlations developed by Barnea and Mizrahi and Barnea and Mednick. This work presents an equation directly computing particle settling velocities, eliminating the uncertainty associated with nomographs.

1981-11-01

292

Efficiency of selective IR multiphoton dissociation of molecules in a pulsed gas-dynamic flow interacting with a solid surface  

International Nuclear Information System (INIS)

Isotopically selective IR multiphoton dissociation of molecules (SF_6, CF_3I) in a pulsed gas-dynamic flow interacting with a solid surface was studied for the first time. A noticeable (severalfold) increase in the yield of products (compared to excitation of molecules in an unperturbed flow) without a substantial decrease in the selectivity of the process was observed. Possible reasons for the effect are discussed. (laser applications and other topics in quantum electronics)

2000-08-31

293

Basic study of solid oxide fuel cells. Part 5: investigation of fuel cell materials  

Energy Technology Data Exchange (ETDEWEB)

Solid Oxide Fuel Cell (SOFC) is expected as a new power generation source. The development of SOFC is being conducted by CRIEPI, and so far several reports of the reults were presented. This report examines materials of SOFC. For the purpose, cells were made using some of typical materials and manufacturing processes, and cell performance tests were carried out.

1991-01-01

294

Visualization and measurement of pressurized multiphase flow using neutron radiography of JRR-3M system  

Energy Technology Data Exchange (ETDEWEB)

Concerning the transient phenomenon of solid-gas two-phase flow, an attempt was made to visualize and measure a flow phenomenon in which three-dimensional bubbles occurred, grew and collapsed in the vicinity of a gas injection nozzle while solid particles were circulating. Such a phenomenon could not or hardly be visualized and measured by conventional methods. Such two-phase flow was visualized using neutron radiography, its characteristics measured and the usefulness of the visualization by neutron radiography confirmed. For this purpose, three-dimensional fluidized bed vessels, rectangular or cylindrical-shaped, made of steel or aluminum sheet, were prepared. Polyethylene or glass beads were used as solid particles and activated carbon particles as the tracer. In the experiment, nitrogen gas was blown into the vessel from one nozzle and distributors provided at the bottom of the vessel and exhausted from the top via the ...

1998-01-01

295

Toward a 2D SPH Multiphysic Code with Solid-Solid & Fluid Interactions for Industrial Related Problems  

CERN Document Server

In the present study, applications of the SPH method to industrial related issues are considered by starting from an existing open source 2D SPH code, namely the SPHYSICS code, which offers an effective ground for numerical developments, which are performed in order to bring an answer to industrial problems, such as simulations of solid/fluid coupling in a free surface flow context. The purpose of the present paper is therefore to expose the numerical developments which yield an enhanced version (referred to as "SPHYSIC2") of the initial code. Firstly, the different features added to obtain the operational code needed for engineering applications are described, and so are the problems raised on this way, offering a kind of review of SPH methods for engineers. Secondly, the validation of the proposed code is partially presented with two well known but difficult test cases, namely the classical "dam break" and "wedge entry" problems. Thirdly, principles of a method ...

2010-01-01

296

Solid waste research and development: A perspective from Pacific Northwest Laboratory  

Energy Technology Data Exchange (ETDEWEB)

The need for research and development (R&D) of technologies and approaches for sound, effective solid waste management is unquestionable. While many advances have been made by the government and private sectors, still more are needed. Resources for conducting R&D, even at the federal level, are limited however, and thus it is critical that resources be distributed as wisely as possible. The US Department of Energy has a vested interest in developing technologies and approaches for managing solid waste because solid waste management is strongly linked to energy use and environmental impacts. This federal role is needed to address the national and international impacts that can result from the cumulative effects of decisions being made at local, county, state, and regional levels. At Pacific Northwest Laboratory (PNL), one of DOE`s R&D laboratories, we are developing an integrated solid waste ...

1992-11-01

297

Regional integrated solid waste management: an optimization model for northern Lebanon  

International Nuclear Information System (INIS)

Full text.Increased environmental concerns and the emphasis on material and energy recovery are gradually changing the orientation of municipal solid waste (MSW) management and planning. In this context, the application of optimization techniques have been introduced to design the least cost solid waste management systems, considering the variety of management processes (recycling, composting, anaerobic digestion, incineration and land filling) and the existence of uncertainties associated with the number of system components and their interrelations. This study presents a model that was developed and applied to serve as a solid socio-economic and environmental considerations. The model accounts for solid waste generation rates, composition, collection, treatment, disposal as well as potential environmental impacts of various MSW management techniques. The model follows a linear programming formulation ...

2000-11-23

298

Recycling of AZ31 Mg alloy with high purity Mg deposition layer by hot working (solid recycling)  

Energy Technology Data Exchange (ETDEWEB)

Solid recycling of AZ31 Mg alloy with vapor deposition coating layer of high purity Mg was evaluated. In the open die forging experiments, two AZ31 Mg alloy specimens with the pure Mg layer were sufficiently bonded by forging at 673 K. Furthermore, the Al and Zn of the AZ31 substrate diffused up to the center of the pure Mg layer. By the theoretical analysis, it is suggested that the grain boundary diffusion enhanced by grain refinement due to hot forging contributes to the solid state bonding of the specimens. Also, the solid recycled specimen was fabricated from the AZ31 Mg substrate with pure Mg layer by hot extrusion at 673 K. The solid recycled specimen showed almost the same tensile properties as the virgin extruded specimen. This is probably related not only to the grain boundary diffusion but also severe plastic deformation by hot extrusion. (orig.)

2003-07-01

299

Parametric study of radiative cooling of solid antihydrogen. Master's thesis  

Energy Technology Data Exchange (ETDEWEB)

A computer model of cryogenic system for storing solid antimatter is used to explore the radiative cooling-power requirements for long-term antimatter storage. If vacuum-chamber pressures as low as 10 to -18th power torr can be reached, and the rest of the large set of assumptions is valid, milligram quantities of solid antimatter could be stored indefinitely at 1.5 K using cooling powers of less than a microwatt. Many of the assumptions made are problematic and need verification, as they could potentially change the results greatly. The system modeled is a sphere of solid anti-parahydrogen at 1.5 K or below levitated in a spherical cryogenic vacuum chamber. The free matter gas in the chamber is assumed to be molecular hydrogen, and sublimation of both matter and antimatter is assumed to be negligible. The antihydrogen is assumed to be in thermal equilibrium, although annihilation-energy deposition is localized and ...

1989-03-01

300

A New and Sound Technology for Biogas from Solid Waste and Biomass  

International Nuclear Information System (INIS)

Organic waste, as a main constituent of municipal solid waste, has as well as solid biomass a high potential for biogas generation. Despite the importance of biogas generation from these materials, the availability of large-scale biogas processes lacks behind the demand. A newly developed double-stage solid-liquid biogas process, consisting of an open hydrolysis stage and a fixed-bed methane reactor, allows the biogas production from almost all biodegradable solid waste and renewable resources like maize, grass, sugar cane, etc. Furthermore, residues from industrial processes, like the glycerine waste water from biodiesel production, can also be converted into biogas successfully. Due to the strong separation of hydrolysis and methanation, the process is extremely stable. No malfunction has been detected so far. The open hydrolysis releases CO_2 and allows oxidation of sulfur. Consequently, the biogas ...

2009-04-01

301

Evaluation of small-bowel transit for solid and liquid test meal in healthy men and women  

International Nuclear Information System (INIS)

Evaluation of severe functional gastrointestinal motility disorders requires an investigation of the entire gastrointestinal tract. This should be possible with a single radionuclide imaging study. The purpose of this study was (1) to define normal values of small-bowel transit in men and women and (2) to assess a possible difference between gender or test meal, since it has been shown that women have slower gastric emptying than men, and gastric emptying of solids is slower than liquids. A standard gastric-emptying test for a solid (technetium-99m sulphur colloids, 230 Kcal) and liquid (indium-111 DTPA water) test meal was performed in 12 healthy male and 12 healthy female volunteers. After 135 min, the volunteer was place in the supine position for static imaging of the abdomen every 15 min for 6 h. Decay and crossover-corrected geometric mean gastric-emptying data were fit to a modified power exponential function to determine the 10% stomach ...

1999-12-01

302

Method and device for the graduated charging of finely-particulate solid substances into an industrial furnace. Verfahren und Vorrichtung zum dosierten Einfuehren feinkoerniger Feststoffe in einen Industrieofen  

Energy Technology Data Exchange (ETDEWEB)

The invention concerns a method for the graduated introduction of finely-particulate and especially pulverously-particulate solid substance, in particular coal dust, from a pressurised proportioning tank containing a supply of solid matter into an industrial furnace with several supply points, in particular a shaft furnace such as a blast furnace or a cupola furnace, the solid matter being conveyed to the individual supply points in a flow of carrier gas heavily charged with solid matter, through a separate transport line for each supply point, the carrier gas being conveyed to the lower end section of the proportioning tank in a current which causes a local loosening in the lower section of the supply of solid matter, with the transport lines opening into the loosened area, whilst the proportioning tank that contains the solid matter is weighed continuously, ...

1987-09-09

303

VC- and Cr{sub 3}C{sub 2}-doped WC-NbC-Co hardmetals  

Energy Technology Data Exchange (ETDEWEB)

This study compares the microstructure and mechanical properties of plain and 0.9 or 3.6 wt% VC- or Cr{sub 3}C{sub 2}-doped WC-12 wt% Co hardmetals with 40 wt% NbC, prepared by pulsed electric current sintering (PECS) in the solid state for 4 min at 1240 deg. C and conventional pressureless liquid phase sintering (CS) for 1 h at 1420 deg. C. The addition of VC or Cr{sub 3}C{sub 2} was found to inhibit grain growth of the residual WC grains, whereas the size of the solid solution (Nb,W,V/Cr)C grains was hardly influenced. The type of grain growth inhibitor and densification temperature however, strongly influenced the composition of the NbC solid solution formed, which was thermodynamically and experimentally assessed.

2008-09-22

304

Study on possible fuel layering sequence for FIREX target  

International Nuclear Information System (INIS)

A new procedure of fuel layering for the Fast Ignition Realization Experiment (FIREX) target is proposed. A conical laser guide heating technique was experimentally demonstrated in principle as the followings. It employed the target consisting of a polystyrene (PS) shell, a fill tube and a conical laser guide. At first, liquid fuel was fed into the shell and existed around the conical laser guide because the surface tension of the fuel must cause it. Then, it was solidified. The laser light provided a heat source to the conical laser guide so that the solid fuel was moved to the other interior of the shell. This process resulted in missing solid fuel around the conical laser guide. To fill the vacant space, liquid fuel was added as temperature was raised to the melting point. After the liquid fuel addition, temperature was lowered to the solidification point again. During this process, most of the solid fuel could survive.

2010-08-01

305

Satellite power system (SPS) concept definition study (Exhibit D). Volume 2: systems/subsystems analyses. Final report  

Energy Technology Data Exchange (ETDEWEB)

Modifications to the reference concept were studied and the best approaches defined. The impact of the high efficiency multibandgap solar array on the reference concept design is considered. System trade studies for several solid state concepts, including the sandwich concept and a separate antenna/solar concept, are described. Two solid state concepts were selected and a design definition is presented for each. Magnetrons as an alternative to the reference klystrons for dc/rf conversion are evaluated. System definitions are presented for the preferred klystron and solid state concepts. Supporting systems are analyzed, with major analysis in the microwave, structures, and power distribution areas. Results of studies for thermal control, attitude control, stationkeeping, and details of a multibandgap solar cell study are included. Advanced laser concepts and the meteorological effects of a laser beam power transmission ...

1981-01-01

306

Properties of molecular solids and fluids at high pressure and temperatures  

Energy Technology Data Exchange (ETDEWEB)

This renewal request for DOE grant DE-FG02-86ER45238, is dedicated to providing a complete thermodynamic profile of solids fluids, and fluid mixtures, over a wide range of temperatures and pressures. We are partially motivated by technological interest in detonation, combustion, superhard high pressure materials, and high temperature superconductors, which are important components of interest of various DOE laboratories. Our work on fluids and solids, composed of simple molecules, involves the determination of structures, phase transitions, pressure-volume relations, phonon, vibron, and libron modes of excitation, sound velocities, specific heats, thermal expansion, virial coefficients, sublimation energies, and orientational translational, and magnetic correlations. We hope that the study of these systems under extreme thermodynamic conditions will lead to exotic new materials of value, as well as enhanced fundamental understanding.

1992-03-01

307

Media Choice in Environmental Information Dissemination for Solid Waste Management among Policy Formulators and Implementors: A Case Study of Oyo State, Nigeria  

British Library Electronic Table of Contents (United Kingdom)

Environmental information has been described as central to the issues of solid waste management and disposal. This study investigated the availability and accessibility of environmental information to the solid waste policy formulators and implementors with regard to the media/channels used for disseminating environmental information to the public. A descriptive survey design was adopted for the study. A purposive sampling technique was used to select the sample and the method produced 205 respondents that consisted of 185 Policy Implementors and 20 Policy Formulators. A total of 147 cases were finally analyzed, which included 16 Policy Formulators (80% of total sample) and 131 Policy Implementors (71% of total sample). Data collected were analyzed using descriptive statistics such as perc...

2009-01-01

308

Lithium carbon batteries with solid polymer electrolyte; Accumulateur lithium carbone a electrolyte solide polymere  

Energy Technology Data Exchange (ETDEWEB)

The lithium carbon batteries studied in this paper use plasticized polymer electrolytes made with passive polymer matrix swollen by a liquid electrolyte with a high ionic conductivity (> 10{sup -3} S/cm at 25 deg. C). The polymers used to prepare the gels are polyacrylonitrile (PAN) and vinylidene poly-fluoride (PVdF). The electrochemical and physical properties of these materials are analyzed according to their composition. The behaviour of solid electrolytes with different materials of lithium ion insertion (graphite and LiNiO{sub 2}) are studied and compared to liquid electrolytes. The parameters taken into account are the reversible and irreversible capacities, the cycling performance and the admissible current densities. Finally, complete lithium ion batteries with gelled electrolytes were manufactured and tested. (J.S.) 2 refs.

1996-12-31

309

Ionically conductive thin polymer films prepared by plasma polymerization. Pt. 7. Preparation and characterization of solid polymer electrolyte having fixed carboxylic acid groups with single mobile species  

Energy Technology Data Exchange (ETDEWEB)

Ultra-thin, uniform, pinhole-free solid polymer electrolyte films having a fixed carboxylic ester group of approximately 1 {mu}m thickness were prepared by polymerization of methyl acrylate and tris(2-methoxyethoxy)vinylsilane in a glow discharge plasma. The carboxylic ester group of the plasma polymer were transformed to lithium carboxylate groups by treatment with lithium iodide. This process give a single lithium ion conductive film. These solid polymer electrolyte films showed ionic conductivities of the order of 10{sup -8} S cm{sup -1} (10{sup 4} {omega} cm{sup 2} resistance per unit area) at room temperature. (orig.).

1990-08-01

310

Ionically conductive thin polymer films prepared by plasma polymerization  

International Nuclear Information System (INIS)

Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 #mu#m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60 degrees C of the order of 10"- "6 S cm"- "1 (10"2 #OMEGA# cm"2 resistance per unit area of as-prepared solid polymer electrolyte). This material shows promise for electrochemical applications such as all solid-state lithium batteries, sensors, and electrochemical display ...

311

Intravaginal immunization using the recombinant HIV-1 clade-C trimeric envelope glycoprotein CN54gp140 formulated within lyophilized solid dosage forms  

British Library Electronic Table of Contents (United Kingdom)

Vaccine-mediated prevention of primary HIV-1 infection at the heterosexual mucosal portal of entry may be facilitated by highly optimised formulations or drug delivery devices for intravaginal (i.vag) immunization. Previously we described hydroxyethylcellulose (HEC)-based rheologically structured gel vehicles (RSVs) for vaginal immunization of an HIV-1 vaccine candidate, a soluble recombinant trimeric HIV-1 clade-C envelope glycoprotein designated CN54gp140. Here we investigated the efficacy of lyophilized solid dosage formulations (LSDFs) for prolonging antigen stability and as i.vag delivery modalities. LSDFs were designed and developed that upon i.vag administration they would reconstitute with the imbibing of vaginal fluid to mucoadhesive, site-retentive semi-solids. Mice were immunize...

2011-01-01

312

Electrochemistry of a semiconductor chalcopyrite concentrate leaching by Thiobacillus ferrooxidans  

Energy Technology Data Exchange (ETDEWEB)

Using carbon-paste-CuFeS{sub 2} electrodes and a cyclic voltammetric technique, it was found that a large number of intermediate electrochemical oxidation reactions were associated with the dissolution of chalcopyrite in presence and absence of bacteria. The effects of concentrations of copper, ferrous and ferric ions, as well as of agitation on the peaks of cyclic voltammograms were measured. It was established that chalcopyrite oxidation was solid-state controlled as suggested by the data of chronopotentiometric and chronoamperometric measurements. The activation energy of solid state diffusion of chalcopyrite leaching was determined by the Sand's method to be {triangle}E{sub a} = 20.5 kJ. The leaching mechanism is discussed in terms of solid-state properties (energy bonding) of the n-type semiconductor chalcopyrite and energy density states of redox systems of acidic bacterial leach media. A generalized model ...

1991-01-01

313

Development of ball bearings with solid film for high-vacuum, high-temperature, high-speed application  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the experimental results of long-life solid lubricated ball bearings tested under high-vacuum of 10 exp -4 Pa, high-temperature of 300 C, and high-speed (9000 rpm) conditions. For full ball-type bearings, the thin soft metals, either Ag or Pb, which were coated on the races and balls, appeared to have good torque properties. However, the durability of such bearings was less than 300 hours. The transfer films from the lamellar solid MoS2 and metal composite retainers improved the torque and wear properties. For ceramic, i.e., silicon nitride, balls used with steel rings, wear occurred on the inner rings. All ceramic bearings with composite retainers showed improved torque and wear properties. 18 refs.

1993-04-01

314

Characterization of the product of the thiosulfate process for desulfurization of flue gases  

Energy Technology Data Exchange (ETDEWEB)

X-ray diffraction, infrared spectroscopy, thermal analysis, scanning electron microscopy, and particle size analysis were used to characterize the product of the thiosulfate process. It was found to consist of a mixture of a solid solution of calcium sulfate in calcium sulfite hemihydrate, calcium sulfate dihydrate, and calcium carbonate. Reactions taking place on heating the byproduct were identified in oxidizing and reducing atmospheres. Pure calcium sulfite hemihydrate as well as solid solutions of CaSO[sub 4] in CaSO[sub 3] [center dot] (1/2)H[sub 2]O with different sulfate concentrations were synthesized in the laboratory. Thermal analyses of pure solid solutions proved that the higher the sulfate content, the higher is the dehydration temperature. Accordingly, taking SO[sub 4][sup 2[minus

1994-05-01

315

Ability of a solid state fermentation technique to significantly minimize catabolic repression of. alpha. -amylase production by Bacillus licheniformis M27  

Energy Technology Data Exchange (ETDEWEB)

The production of {alpha}-amylase by Bacillus licheniformis M27 in submerged fermentation was completely inhibited due to catabolic repression in medium containing 1% glucose. In contrast, the enzyme production in a solid state fermentation system was 19,550 units/ml extract even when the medium contained 15% glucose. The peak in enzyme titre was, however, shifted from 48 to 72 h. The ability of the solid state fermentation system to significantly overcome catabolic repression was not known earlier and is probably conferred by various physico-chemical factors and culture conditions specific to the system. (orig.).

1991-08-01

316

A new method of imaging particle tracks in solid state nuclear track detectors  

British Library Electronic Table of Contents (United Kingdom)

Summary Solid state nuclear track detectors are used to determine the concentration of a particles in the environment. The standard method for assessing exposed detectors involves 2D image analysis. However 3D imaging has the potential to provide additional information relating to angle as well as to differentiate clustered hit sequences and possibly energy of a particles but this could be time consuming. Here we describe a new method for rapid high-resolution 3D imaging of solid state nuclear track detectors. A `LEXT' OLS3100 confocal laser scanning microscope (Olympus Corporation, Tokyo, Japan) was used in confocal mode to successfully obtain 3D image data on four CR-39 plastic detectors. Three-dimensional visualization and image analysis enabled characterization of track features. This ...

2010-01-01

317

Use of solid state nuclear track detectors for radon concentration measurements indoors  

International Nuclear Information System (INIS)

An indoor radioactive survey is being conducted in an Italian district. Preliminary results identified a zone with significant radioactive levels, in which a new specific survey has been planned. In this paper attention is dedicated mainly to radon measurement technique and results.

318

THEMIS-D - SPASE Resource Description  

Science.gov (United States)

Feb 23, 2011 ... THEMIS-D: The Solid State Telescope (SST) measures the incoming ... Each single sensor covers an angle of 36 degrees. .... The five small satellites were launched together on a Delta II rocket and they carry identical ...

319

Surgical Management of Solid-Pseudopapillary Neoplasms of the Pancreas (Franz or Hamoudi Tumors): A Large Single-Institutional Series  

UK PubMed Central (United Kingdom)

BACKGROUNDSolid-pseudopapillary neoplasms (SPNs) are rare pancreatic tumors with malignant potential. Clinicopathologic characteristics and outcomes of patients with...Full Text Available

2009-05-01

320

Sulfur dioxide oxidation catalyst and process  

Energy Technology Data Exchange (ETDEWEB)

A catalytic process for the oxidation of sulfur-containing gases , E.G., sulfur dioxide and simultaneous production of sulfuric acid wherein a sulfur-containing gas is reacted with an oxygencontaining gas in the presence of a catalyst comprising an iron group metal on a solid support comprising a zeolite in a silicaalumina matrix.

1981-01-13

321

Staphylococcal Enterotoxin B: Solid-Phase Radioimmunoassay  

UK PubMed Central (United Kingdom)

An immunoassay employing 125I-labeled enterotoxin B and polystyrene tubes coated with specific antibody was used for assaying purified and crude enterotoxin. Antibody was adsorbed to untreated...Full Text Available

1971-11-01

322

Solidification of radioactive waste effluents  

Energy Technology Data Exchange (ETDEWEB)

A process and apparatus for solidifying radioactive waste liquid containing dissolved and/or suspended solids is disclosed. The process includes chemically treating for pH adjustement and precipitation of solids, concentrating solids with a thin-film evaporator to provide liquid concentrate containing about 50% solids, and drying the concentrate with heated mixing apparatus. The heated mixing apparatus includes a heated wall and working means for shearing dried concentrate from internal surfaces and subdividing dry concentrate into dry, powdery particles. The working means includes a rotor and helical means for positively advancing the concentrate and resulting dry particles from inlet to outlet of the mixing apparatus. The dry particles may also be encapsulated in a matrix material. Entrained particles in the vapor stream from the evaporator and mixer are removed in an integral particle separator and ...

1983-10-11

323

Solid-state lithium battery with graphite anode  

Energy Technology Data Exchange (ETDEWEB)

Solid-state lithium batteries with a unique construction are reported in this paper. These batteries contain two kinds of lithium ion-conductive solid electrolytes, LiI-Li{sub 2}S-P{sub 2}S{sub 5} glass contacted with the anode material and Li{sub 3}PO{sub 4}-Li{sub 2}S-SiS{sub 2} glass or Li{sub 2}S-GeS{sub 2}-P{sub 2}S{sub 5} crystalline material contacted with the cathode. The former electrolyte was selected as that stable to electrochemical reduction, and the latter two to oxidation. This construction made it possible to use graphite as the anode and LiCoO{sub 2} as the cathode in the solid-state lithium battery. The energy density of the battery is 390 W h{center_dot}l{sup -1} and 160 W h{center_dot}kg{sup -1} per total volume and weight of the cathode and anode layers, respectively, which are comparable to those of commercialized Li-ion batteries.

2003-03-01

324

Solid-State Lighting at Sandia National Laboratory - Grand Challenge...  

Science.gov (United States)

Barbara), Arto Nurmikko (Brown U), Ed Petrow (DOE), Jim Brodrick (DOE), John Carrano (DARPA), Bob Karlicek (Gelcore), John Zolper (DARPA), and Steve Johnson (LBNL). This project...

2011-08-27

325

Solid-Phase Radioimmunoassay of Total and Influenza-Specific Immunoglobulin G  

UK PubMed Central (United Kingdom)

An antigen-antibody system of polystyrene tubes coated with immunoglobulin antibody was used for quantitating immunoglobulins. A similar radioimmunoassay method was adapted for a viral antigen-antibody...Full Text Available

1972-02-01

326

Solid state and materials research: metal-semiconductor interactions  

International Nuclear Information System (INIS)

This section of the report is concerned with the study of the metallisation, oxidation and doping of materials which are of importance to the micro-electronics industry. The Van de Graaff accelerator and radioactive tracers are used for studying surface and sub-surface behaviour of these materials.

327

Solid electrolyte and lithium battery employing it. Kotai denkaishitsu oyobi sore wo shiyo shite naru richiumu denchi  

Energy Technology Data Exchange (ETDEWEB)

Recently, the lithium ion-conductive solid electrolyte draws attention because there is a possibility of producing the maintenance-free battery which is characterized by having such advantages as high energy density and no possibility of electrolyte leak because of solid state structure. The invented lithium ion-conductive solid electrolyte is formed by sintering the granular electrolyte expressed in the following general formula: Li(1+(4-n)x)MxTi(2-x)(PO4)3 (M = mono- or di-valent cation, x = 0.1 - 0.5). Examples of the monovalent cation are Na[sup +], K[sup +], Rb[sup +], Cs[sup +], and Cu[sup +]. Examples of divalent cation are Mg[sup 2+], Fe[sup 2+], Be[sup 2+], Ca[sup 2+], Sr[sup 2+], Ba[sup 2+], Ra[sup 2+], Mn[sup 2+], Co[sup 2+], Cu[sup 2+], Ni[sup 2+], Zn[sup 2+], and Cd[sup 2+]. The electric conductivity of lithium ion is increased with the increase in the content of Li[sup +] in the electrolyte. 4 figs.

1993-11-12

328

Solid State Microelectrochemical Devices: Transistor and ...  

Science.gov (United States)

... Oliver, j. Egekeze, m. 7. Kennedy, JW Jorgenson, J. F. Parcher and ... 9. .:. W. Thackeray, HS White and MS Wrighton, J. Phys ... Dr. Harold H. Singerman ...

1989-10-01

329

Science of materials. Progress report, January 1-December 21, 1982  

Energy Technology Data Exchange (ETDEWEB)

Progress is reported in the following areas: metallurgy and ceramics (structure of materials, mechanical properties, physical properties), experimental research, and particle-solid interactions (irradiation effects on alloys). (DLC)

1982-01-01

330

Satellite power systems (SPS) concept definition study (exhibit d). Volume 4: operations analyses. Final report  

Energy Technology Data Exchange (ETDEWEB)

Using a coplanar, end-mounted antenna as a baseline, various configuration trades were performed to select a preferred solid state concept. The increase in efficiency that could be realized by use of multi bandgap solar cells, either with klystron or solid state antenna was evaluated. Satellite configurations were developed to exploit the sandwich antenna concept wherein solar cells are located on one side of the antenna panel and solid state dc/RF converters on the other side. These concepts entailed various primary and secondary reflector arrangements for directing solar energy to the solar cell side of the antenna with higher concentration ratios than used on the coplanar configurations. Operations analysis included development of a satellite construction scenario, a concept for the SCB, a top-level satellite construction operation, construction operation, construction timelines and crew sizes, mass flows to orbit, and a ...

1981-03-01

331

SPASE Resource Description - the VMO - NASA  

Science.gov (United States)

THEMIS-A: The Solid State Telescope (SST) measures the incoming intensity ... units (heads), each SST unit has two pairs of opposing ion and electron sensors. .... The five small satellites were launched together on a Delta II rocket and they ...

332

Research and development for the upgrading of Rhenish brown coal  

Energy Technology Data Exchange (ETDEWEB)

Product control procedures, the development of new technologies, and the extension of the applications of solid fuels are described. Hydrogasification and high-temperature Winkler gasification are discussed. The design and function of a continuous, semi-industrial plant for hydrogenating liquefaction in the sump phase are gone into. (MOS).

1988-07-01

333

Regulatory compliance | Mott MacDonald  

Wastenet

...broad range of experience in designing and building research and development laboratories for products such as vaccines, blood and sera, biological products, medical devices, solid dosage forms , highly potent products and cytotoxic material. We also have experience in a range of modular laboratories for TSE research, ...

334

Recycling of postconsumer plastic waste via new solid-state shear extrusion pulverization process  

Energy Technology Data Exchange (ETDEWEB)

We have demonstrated that the SSSE pulverization process can convert multicomponent plastic waste into a powder with very promising properties. A variety of mixed color plastic chips have been pulverized.

1996-12-31

335

Reaction of solid sorbents with hydrogen chloride gas at high temperature in a fixed-bed reactor  

Energy Technology Data Exchange (ETDEWEB)

The gas-solid reaction and breakthrough curves in the fixed-bed reactor are of great importance, and being influenced by a number of factors makes the prediction of these factors a difficult problem. In this study, the reaction rate between solid sorbents and hydrogen chloride gas at high temperature was first investigated. On the basis of a fixed-bed reactor, the experimental results were analyzed by the shrinking core model of diffusion and surface chemical reaction control. The results showed that reaction rates of two sorbents with hydrogen chloride gas were controlled by the combination of the surface chemical reaction and diffusion of product layers, and the reaction rates nearly keep constant within 15 h of the initial reaction period and then decrease gradually. The results of the breakthrough curves show that solid sorbents in the fixed-bed reactor are capable of reducing the HCl level to near-zero levels at ...

2005-12-01

336

Radon concentration measurement in dwellings in Belgrade  

International Nuclear Information System (INIS)

The results of the radon concentration measurements in dwellings in Belgrade were shown in this paper. The measurements were done using long term method with diffusion cups equipped with solid state nuclear track detector LR-115-II or CR-39. (author).

337

Properties of rare-gas solids. [Diffusion rate of xenon through epithelial tissue  

Science.gov (United States)

Results are reported from studies of the diffusion rate of xenon through frog abdominal skin and toad urinary bladders, typical epithelial membranes. It was concluded that intracellular water serves as the principal barrier for xenon passage through epithelial tissue.

1977-01-01

338

Power electronics in electrical propulsion  

Energy Technology Data Exchange (ETDEWEB)

Various energy sources and motors of divers types can be used in electric cars with operating modes subjected to a number of particular constraints. As a result, the possible structures of the converters, that are analysed in detail, are about a dozen in number. Also considered is the use of solid-state components - thyristors, power transistors and new components.

1982-12-01

339

Point defects in superconductors  

Energy Technology Data Exchange (ETDEWEB)

The federating theme of superconductivity has given rise to a number of experimental studies of point defects in solids as different as transition metals (V, Nb, ...), A-15 compounds (V{sub 3}Si, Nb{sub 3}Ge, ...), or perovskite-like copper oxides. Some of these experiments are presented here. (orig.).

1989-12-01

340

Point defects in superconductors  

International Nuclear Information System (INIS)

The federating theme of superconductivity has given rise to a number of experimental studies of point defects in solids as different as transition metals (V, Nb, ...), A-15 compounds (V_3Si, Nb_3Ge, ...), or perovskite-like copper oxides. Some of these experiments are presented here. (orig.).

341

Oxygen carriers for chemical looping combustion of solid fuels  

Energy Technology Data Exchange (ETDEWEB)

A thermal analyzer-differential scanning calorimeter-mass spectrometer (TG-DSC-MS) was used to study oxygen carriers (OC) for their potential use for the application of chemical looping combustion (CLC) to solid fuels. Reaction rates, changes in reaction rates with repeated oxidation-reductions, exothermic heats during oxidation, and the effect of changing reduction gas compositions were studied. Oxidation rates were greater than reduction rates and reaction rates were reproducible through multiple oxidation-reduction cycles except where agglomeration occurred with powders. Iron oxide (Fe{sub 2}O{sub 3} powder) and iron-based catalysts were found suitable for CLC of solid fuels having rapid reduction rates which increased with higher reducing gas concentrations. Fe{sub 2}O{sub 3} powder was used to oxidize a high carbon coal char in an inert gas removing 88% of the carbon from the char. Other properties such as cost and durability indicated ...

2009-05-15

343

New approach to study fast and slow motions in lipid bilayers: application to dimyristoylphosphatidylcholine-cholesterol interactions.  

UK PubMed Central (United Kingdom)

Natural abundance 13C solid-state nuclear magnetic resonance spectroscopy was used to investigate the effect of the incorporation of cholesterol on the dynamics of dimyristoylphosphatidylcholine (DMPC)...Full Text Available

1995-05-01

344

N A S A T'ECHNICAL, - NASA Technical Reports Server  

Science.gov (United States)

Four temperature sensors were provided instead of the previous two sensors. 4. ... Incoming signals from either one or two ground stations at a frequency of .... The propulsion subsystem consists of a single solid-propellant rocket motor. ...

345

Monte Carlo modeling of 60Co HDR brachytherapy source in water and in different solid water phantom materials  

UK PubMed Central (United Kingdom)

The reference medium for brachytherapy dose measurements is water. Accuracy of dose measurements of brachytherapy sources is critically dependent on precise measurement of the source–detector...Full Text Available

2010-01-01

346

Modification of guanine bases by nucleoside phosphoramidite reagents during the solid phase synthesis of oligonucleotides.  

UK PubMed Central (United Kingdom)

Nucleoside 3'-phosphoramidite and chlorophosphite reagents have been found to react with the lactam function of guanine. This reaction caused unsatisfactory results when oligodeoxyribonucleotides containing...Full Text Available

1985-09-25

347

Microstructure of the gravitationally settled region in a liquid-phase sintered dilute tungsten heavy alloy  

Energy Technology Data Exchange (ETDEWEB)

A dilute tungsten heavy alloy consisting of 50W-35Ni-15Fe (wt pct) was liquid phase sintered at 1,500 C for times ranging from 30 to 960 minutes. This alloy corresponds to a nominal solid content of 20 vol pct at the sintering temperature. Because of the excess liquid, the alloy densified easily and exhibited extensive liquid-solid separation due to the density difference between the phases. The solid content at the compact bottom ranged from 45 to 70 vol pct over position and time. The microstructure of the settled region was quantified for volume fraction of tungsten, grain size, connectivity, and settled solid angle of repose. These results provide a basis for extending the microstructural parameters to possible microgravity conditions. The grain growth rate constant varies with the inverse 2/3 power of the volume fraction of liquid, possibly reflecting combined coalescence and ...

1995-02-01

348

Microstructure of the gravitationally settled region in a liquid-phase sintered dilute tungsten heavy alloy  

International Nuclear Information System (INIS)

A dilute tungsten heavy alloy consisting of 50W-35Ni-15Fe (wt pct) was liquid phase sintered at 1,500 C for times ranging from 30 to 960 minutes. This alloy corresponds to a nominal solid content of 20 vol pct at the sintering temperature. Because of the excess liquid, the alloy densified easily and exhibited extensive liquid-solid separation due to the density difference between the phases. The solid content at the compact bottom ranged from 45 to 70 vol pct over position and time. The microstructure of the settled region was quantified for volume fraction of tungsten, grain size, connectivity, and settled solid angle of repose. These results provide a basis for extending the microstructural parameters to possible microgravity conditions. The grain growth rate constant varies with the inverse 2/3 power of the volume fraction of liquid, possibly reflecting combined coalescence and ...

349

Integrative Analysis of Epigenetic Modulation in Melanoma Cell Response to Decitabine: Clinical Implications  

UK PubMed Central (United Kingdom)

Decitabine, an epigenetic modifier that reactivates genes otherwise suppressed by DNA promoter methylation, is effective for some, but not all cancer patients, especially those with solid tumors. It...Full Text Available

350

Influence of the menstrual cycle and of menopause on the gastric emptying rate of solids in female volunteers  

Energy Technology Data Exchange (ETDEWEB)

The aim of this study was to assess the influence of the normal menstrual cycle and of menopause on the gastric emptying rate of solids. Gastric emptying was studied in 15 premenopausal and ten postmenopausal women with an isotopic technique after the ingestion of a radiolabelled test meal. Premenopausal women were studied twice: Within 1 week prior to menses and again 1 week after onset of menses. Postmenopausal women were studied only once. The emptying curves of the solid component of the meal fitted a linear model. The half-emptying time was 78[+-]5 min during the follicular phase, 75[+-]7 min during the luteal phase and 76[+-]6 min in postmenopausal women (differences not statistically significant). The mean percentages of the meal retained in the stomach at different time intervals were also similar in the three groups. These results suggest that the menstrual cycle does not influence the gastric emptying rate of ...

1993-07-01

351

Influence of the menstrual cycle and of menopause on the gastric emptying rate of solids in female volunteers  

International Nuclear Information System (INIS)

The aim of this study was to assess the influence of the normal menstrual cycle and of menopause on the gastric emptying rate of solids. Gastric emptying was studied in 15 premenopausal and ten postmenopausal women with an isotopic technique after the ingestion of a radiolabelled test meal. Premenopausal women were studied twice: Within 1 week prior to menses and again 1 week after onset of menses. Postmenopausal women were studied only once. The emptying curves of the solid component of the meal fitted a linear model. The half-emptying time was 78#+-#5 min during the follicular phase, 75#+-#7 min during the luteal phase and 76#+-#6 min in postmenopausal women (differences not statistically significant). The mean percentages of the meal retained in the stomach at different time intervals were also similar in the three groups. These results suggest that the menstrual cycle does not influence the gastric emptying rate of ...

352

In situ nanoindentation in a transmission electron microscope  

Science.gov (United States)

This dissertation presents the development of the novel mechanical testing technique of in situ nanoindentation in a transmission electron microscope (TEM). This technique makes it possible to simultaneously observe and quantify the mechanical behavior of nano-scale volumes of solids.

2002-12-02

353

Imaging Response in the Primary Index Lesion and Clinical Outcomes Following Transarterial Locoregional Therapy for Hepatocellular Carcinoma  

UK PubMed Central (United Kingdom)

ContextResponse Evaluation Criteria in Solid Tumors [RECIST (unidimensional)], World Health Organization [WHO (bi-dimensional)] and European Association for Study...Full Text Available

2010-03-17

354

Hydrodynamic and thermal modeling of solid particles in a multi-phase, multi-component flow. [LMFBR  

Energy Technology Data Exchange (ETDEWEB)

This paper presents the new thermal hydraulic models describing the hydrodynamics of the solid fuel/steel chunks during an LMFBR hypothetical core-disruptive accident. These models, which account for two-way coupling between the solid and fluid phases, describe the mass, momentum, and energy exchanges which occur when the chunks are present at any axial location. They have been incorporated in LEVITATE, a code for the analysis of fuel and cladding dynamics under Loss-of-Flow (LOF) conditions. Their influence on fuel motion is presented in the context of the L6 TREAT experiment analysis. It is shown that the overall hydrodynamic behavior of the molten fuel and solid-fuel chunks is dependent on both the size of the chunks and the power level. At low and intermediate power levels the fuel motion is more dispersive when small chunks, rather than large ones, are present. At high power levels the situation is reversed. These ...

1983-01-01

355

High Power, High Repetition Rate, Diode-Pumped, Solid State Laser ...  

Science.gov (United States)

Also, this laster will employ an acousto-optic Q-switch which will allow repetition rates greater than 50 kHz at reduced pulse energy. ...

356

HCN polymers characterized by solid state NMR: Chains and sheets formed in the neat liquid  

UK PubMed Central (United Kingdom)

Hydrogen cyanide polymerizes readily under a variety of conditions and significant prebiotic roles have been suggested for these polymers due to the abundance of HCN in universe. However, the structures...Full Text Available

2009-04-07

357

Flashlamp radiation recycling for enhanced pumping efficiency and reduced thermal load  

Energy Technology Data Exchange (ETDEWEB)

A method for recycling laser flashlamp radiation in selected wavelength ranges to decrease thermal loading of the solid state laser matrix while substantially maintaining the pumping efficiency of the flashlamp.

1989-01-01

358

Evaluation of solid phase system in radioimmunoassay of triiodothyronine (Preprint No. RA.24)  

International Nuclear Information System (INIS)

This paper describes the evaluation of antibody coated polystyrene beads using "1"2"5I-labelled T_3 ("1"2"5I-T_3). (author).

359

Evaluation of a solid hydrophone cable  

Energy Technology Data Exchange (ETDEWEB)

In marine seismic exploration, an approximately two-mile long hydrophone cable is towed behind the ship. The commonly employed cable consists of a kerosene-filled hose enclosing hydrophones, electrical wires, and steel ropes. The kerosene provides buoyancy while the steel ropes are for structural support. For deep-water operations, the cable is pulled through the water at a depth of 20-40 feet. For shallow water, a bottom reference configuration is used and the cable is dragged. This paper presents a comparison of electroacoustic properties between a newly designed, buoyant solid cable and those of the conventional kerosene-filled hose. The emphasis is on drag cable operations. Cable maintenance is a major problem. Jacket cuts occur because of improper handling or collisions with other ships, subsea structures, and debris. Kerosene leakage causes buoyancy loss and the need for immediate replacement. Salt water intrusion causes electrical shorts. Replacement rates ...

1982-07-01

360

Evaluation of Tumor Micro-Environment in an Animal Model using a Nanoparticle Contrast Agent in Computed Tomography Imaging  

UK PubMed Central (United Kingdom)

RATIONALE AND OBJECTIVESNon-invasive longitudinal imaging of tumor vasculature could provide new insights into the development of solid tumors, facilitating efficient...Full Text Available

2011-01-01

361

Energy transfer in solid explosives  

Energy Technology Data Exchange (ETDEWEB)

The nonequilibrium Zeldovich-von Neumann-Doring theory of detonation in solid explosives is extended to include recent nanosecond and picosecond experimental and theoretical results on each of the four main regions of the reaction zone. The first region is the three-dimensional, Mach stem dominated leading shock front which excites the phonon modes of the explosive molecules in less than a picosecond. The second region is the multiphonon up-pumping process in which the excited phonons anharmonically couple to the low frequency (doorway) vibrational modes which in turn equilibrate with the higher frequency modes by internal vibrational redistribution. This process may require on the order of tens of picoseconds. The third region is the chemical reconstitution region in which the vibrationally equilibrated transition state decomposes in a series of chain reaction steps into highly vibrationally excited diatomic and triatomic molecules in approximately one nanosecond. ...

1993-07-01

362

Energizing the batteries for electric cars  

Energy Technology Data Exchange (ETDEWEB)

This article reports of the nickel-metal-hydride battery and its ability to compete with the lead-acid battery in electric-powered vehicles. The topics of the article include development of the battery, the impetus for development in California environmental law, battery performance, packaging for the battery's hazardous materials, and the solid electrolyte battery.

1993-07-01

363

Effect of Dexrazoxane and Amifostine on the Vertebral Bone Quality of Doxorubicin Treated Male Rats  

UK PubMed Central (United Kingdom)

Doxorubicin (DOX) is widely used in combination cocktails for treatment of childhood hematological cancers and solid tumors. A major factor limiting DOX usage is DOX-induced cardiotoxicity. However,...Full Text Available

364

Dietary Ammonium Chloride for the Acidification of Mouse Urine  

UK PubMed Central (United Kingdom)

A novel therapeutic compound was found to induce bladder tumors in male rats. Given the location of the tumors and the increased amounts of calcium- and magnesium-containing solids found in the urine...Full Text Available

2009-03-01

365

Diagnosis of Plasmodium falciparum infection using a solid-phase radioimmunoassay for the detection of malaria antigens  

UK PubMed Central (United Kingdom)

A serodiagnostic test has been developed for the detection of Plasmodium falciparum in infected blood. Using parasite antigens and infected red blood cells from in vitro...Full Text Available

1980-01-01

366

Diagnosis and Management of Cystic Lesions of the Pancreas  

UK PubMed Central (United Kingdom)

Pancreatic cysts are challenging lesions to diagnose and to treat. Determining which of the five most common diagnoses—pancreatic pseudocyst, serous cystic neoplasm (SCN), solid pseudopapillary...Full Text Available

2011-01-01

367

Cumulative releases of radionuclides from uncontained waste packages  

Energy Technology Data Exchange (ETDEWEB)

This report describes mathematical predictions for the migration of radionuclides from an emplaced radioactive waste container. The model assumes a spherical-equivalent waste solid surrounded by backfill but neglects the effect of decay heat. 7 refs., 2 tabs. (TEM)

1986-07-01

368

Cost analysis of the ownership and use of traditional and innovative cooking appliances  

Energy Technology Data Exchange (ETDEWEB)

This study develops a framework for analysis and assessment of the cost of ownership and use of major cooking appliances. This involved an assessment of the monetary cost as well as the cost of human resources required to maintain and operate cooking systems. The goal was to provide information useful in making purchase decisions within a framework that can be used to organize information about cost beyond the initial purchase price. Five cooktops - conventional electric oil, induction, solid element with thermostatic control, solid element with thermal limiter, and gas - and a microwave oven were used to develop a decision-making matrix. Results were used to assign weights in the matrix used to develop a 10-point scale that represented the total cost of owning and using a cooking system in food preparation. Based on the matrix, the microwave oven received the highest score followed by gas, conventional electric coil, solid ...

1988-01-01

369

Contact Line Pinning by Microfabricated Patterns: Effects of Microscale Topography  

UK PubMed Central (United Kingdom)

We study how the microscale topography of a solid surface affects the apparent advancing and receding angles at the contact line of a liquid drop pinned to this surface. Photolithographic methods...Full Text Available

2009-05-05

370

Complexes of hepatitis B surface antigen and immunoglobulin M in the sera of patients with hepatitis B virus infection.  

UK PubMed Central (United Kingdom)

Hepatitis B surface antigen (HBsAg) bound to immunoglobulin M (IgM) was detected in sera of HBsAg carriers by a radioimmunoassay based on selective absorption of the immunoglobulin on a solid phase...Full Text Available

1983-09-01

371

Comparative Evaluation of Nanofibrous Scaffolding for Bone Regeneration in Critical-Size Calvarial Defects  

UK PubMed Central (United Kingdom)

In a previous study we found that nanofibrous poly(l-lactic acid) (PLLA) scaffolds mimicking collagen fibers in size were superior to solid-walled scaffolds in promoting osteoblast differentiation...Full Text Available

2009-08-01

372

Characterization of a 'Solid-State' Microelectrochemical Diode ...  

Science.gov (United States)

... Science: London, 1987; p. 237; (b) Ratner, MA; Shriver, D. F. Chem. ... 11. Lofton, EP; Thackeray, JW; Wrighton, MS J. ... (1) Dr. Harold H. Singerman (1) ...

1990-05-16

373

Characteristics of common solid liver lesions and recommendations for diagnostic workup  

UK PubMed Central (United Kingdom)

Due to the widespread clinical use of imaging modalities such as ultrasonography, computed tomography and magnetic resonance imaging (MRI), previously unsuspected liver masses are increasingly being...Full Text Available

2009-07-14

374

Cavity detection by the electric method: the 3-dimensional case  

Energy Technology Data Exchange (ETDEWEB)

In this paper the authors prove a uniqueness theorem for the electric detection of cavities in a three dimensional solid from Cauchy data measured on the surface. The cavities, finite in number, are assumed to be insulating. The surfaces of the cavities are assumed to be smooth on the complement of a set that is, in some sense, negligible. (orig.)

2004-02-01

375

Carbon Dioxide Capture Utilizing Solid Sorbents  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work is to develop regenerable sorbents that have high selectivity, efficient regenerability, and high adsorption capacity for CO2 over wide temperature ranges. These properties are critical for the success of the PSA/PSS and TSA/TSS processes.

2006-09-01

376

CD133 Positive Embryonal Rhabdomyosarcoma Stem-Like Cell Population Is Enriched in Rhabdospheres  

UK PubMed Central (United Kingdom)

Cancer stem cells (CSCs) have been identified in a number of solid tumors, but not yet in rhabdomyosarcoma (RMS), the most frequently occurring soft tissue tumor in childhood. Hence, the aim of this...Full Text Available

377

Base program on energy-related research. Quarterly report, February 1995--April 1995  

Energy Technology Data Exchange (ETDEWEB)

This report describes research performed by the Morgantown Energy Technology Center in the following areas: oil and gas; advanced systems describing a coal solid fuel and an eastern shale oil residue waste program; environmental remediation; and waste management technologies.

1995-06-01

378

Attachment Stimulates Exopolysaccharide Synthesis by a Bacterium  

UK PubMed Central (United Kingdom)

This study examined the hypothesis that solid surfaces may stimulate attached bacteria to produce exopolymers. Addition of sand to shake-flask cultures seemed to induce exopolymer synthesis by a number...Full Text Available

1993-10-01

379

A solid pseudopapillary tumor of the pancreas treated with laparoscopic distal pancreatectomy and splenectomy: a case report and review of the literature  

UK PubMed Central (United Kingdom)

IntroductionLaparoscopic distal pancreatectomy has been described for more than a decade now and has been considered technically feasible, safe, and with reproducible outcomes. It...Full Text Available

380

A double antibody solid phase assay for DNA autoantibodies for clinical use.  

UK PubMed Central (United Kingdom)

DNA antoantibodies in serum will bind to antigen-coated polystyrene tubes and can be detected by radiolabelled anti-immunoglobulin. The method is quantitative, gives information on the antibody class...Full Text Available

1976-08-01

381

A convenient and sensitive allergy test: IgE crosslinking-induced luciferase expression in cultured mast cells  

UK PubMed Central (United Kingdom)

BackgroundFor the detection of allergen-specific IgE in sera, solid-phase IgE-binding assays like the CAP test are commonly used. Although such immunochemical methods are very sensitive,...Full Text Available

2010-10-01

382

Waste Management Project fiscal year 1998 multi-year work plan, WBS 1.2  

Energy Technology Data Exchange (ETDEWEB)

The Waste Management Project manages and integrates (non-TWRS) waste management activities at the site. Activities include management of Hanford wastes as well as waste transferred to Hanford from other DOE, Department of Defense, or other facilities. This work includes handling, treatment, storage, and disposal of radioactive, nonradioactive, hazardous, and mixed solid and liquid wastes. Major Waste Management Projects are the Solid Waste Project, Liquid Effluents Project, and Analytical Services. Existing facilities (e.g., grout vaults and canyons) shall be evaluated for reuse for these purposes to the maximum extent possible.

1997-09-23

383

The HARP experiment first physics results  

CERN Document Server

The HARP experiment at CERN is performing extensive measurements of hadron production cross sections and secondary particle yields, in the momentum range 1.5-15 GeV/c, over the full solid angle and using a large set of cryogenic and solid targets. First measurements of hadron production cross-sections in the forward region are reported using an aluminium target 5% of an interaction length thick and a proton beam of 12.9 GeV/c. A preliminary analysis in the large angle region of elastic scattering events produced with the cryogenic hydrogen target at 3 GeV/c beam momentum is also presented.

2005-01-01

384

Solid-state ozone synthesis by energetic ions  

International Nuclear Information System (INIS)

We have synthesized ozone by irradiating thin solid films of oxygen and oxygen-water mixtures with 100 keV protons, motivated by recent reports of condensed O_3 on icy satellites in the outer Solar system. We measured the depth of the Hartley absorption band in the ultraviolet by reflectance spectroscopy and used it to quantify the column density of ozone. We analyzed the results using a three-component (O, O_2 and O_3) model that successfully explains the fluence dependence of ozone production.

1999-08-02

385

Solid-phase synthesis and pharmacological evaluation of novel nucleoside-tethered dinuclear platinum(II) complexes  

British Library Electronic Table of Contents (United Kingdom)

Three novel inosine-based dinuclear platinum complexes have been synthesized via a solid-phase strategy. In these compounds, the metal is linked both to the N-7 of the purine nucleus and to the terminal amine group of a hexylamine side chain installed on N-1. Cis- or trans- diamine as well as ethylenediamine ligands are coordinated to platinum along with a chloride. The synthesised complexes were tested against four different human tumor cell lines. One of these complexes proved to be more cytotoxic than cisplatin against the MCF7 cancer cell line in a short-term exposure assay.

2011-01-01

386

Solid state and materials research  

International Nuclear Information System (INIS)

Within about 10 years, microelectronic devices will be made with more than a billion (10"9) electronic components per chip. To implement such a sophisticated technology it will be essential to have a fundamental understanding of the solid state interaction between the different materials in thin film semiconductor structures. This is the main purpose of this research program. Characterization and analysis is carried out mainly by Rutherford backscattering spectrometry and channelling using accelerated nuclear particles from the Van de Graaff accelerator, while radioactive isotopes provide information about interaction mechanisms. 6 figs., 1 ref.

387

Process and system for treatment of radioactive waste  

Energy Technology Data Exchange (ETDEWEB)

In a treatment system of radioactive waste solution including sodium sulfate generated from a boiling water type nuclear reactor, waste solution is fed into a thin film evaporator where the waste solution is evaporated and made into powder while precipitating in a peripheral surface of the evaporator vessel. The surface of the precipitated solid is wiped by rotating wiper blades and removed off as radioactive solid powder. The rotational speed of a rotor to which the wiper blades are secured is controlled at a minimum and necessary rotational speed which contributes to make the waste solution into the powder so that the rate of worn out of the wiper blade is decreased.

1985-07-02

388

Passive dosimetry of radon and its daughters using solid state nuclear track detectors (SSNTDs)  

Energy Technology Data Exchange (ETDEWEB)

Indoor radon is a potential health hazard for the general public, especially in buildings with poor ventilation. A variety of dosemeters have been developed and used in surveys of radon concentration measurements. In this article the passive dosemeters which are based on solid state nuclear track detectors are reviewed. The principle of passive dosimetry and the factors affecting their performance are discussed. The characteristics of SSNTD materials in relation to their behaviour under different environmental conditions are tabulated and discussed. Results of radon surveys from selected studies are also presented. (Author).

1993-01-01

389

Method of calculation of positions of isotherms of spinodal for solid phase of the type A/sub x/B/sub y/C/sub 1-x-y/D  

Science.gov (United States)

The authors suggest a method of calculation of the isotherms of the spinodal and the heterogeneous equilibria in four-component systems in the framework of a unified thermodynamic model of the solution. The results of their calculations predict the existence of extended regions of immiscibility in the solid phase in the interval of temperatures usually used to obtain epitaxial layers of InAs/sub x/P/sub y/Sb/sub 1-x-y/ and AlAs/sub x/P/sub y/Sb/sub 1-x-y/.

1987-01-01

390

Method for determining the concentration of atomic species in gases and solids  

Energy Technology Data Exchange (ETDEWEB)

Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a plasma containing the species after a sufficient time period has elapsed after the generation of the plasma and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample.

1999-01-01

391

Lithium ionic conductivity in LiI?Li2S?La2O2Sm (m=1, 2) composite electrolyte by solid state reaction  

British Library Electronic Table of Contents (United Kingdom)

New lithium ion composite electrolyte, LiI?Li2S?La2O2Sm (m=1, 2) was synthesized from the binary Li2S?LaOI system through solid state reaction. The lithium ion conductive property was investigated by AC impedance spectroscopy. And the highest conductivity of the obtained electrolyte at room temperature was found to be 3.0?10?6?S cm?1. The notable ionic conduction was attributed to the in situ formed amorphous LiI.

2008-01-01

392

Large solid angle Bragg-curve spectrometer  

Energy Technology Data Exchange (ETDEWEB)

A conical Bragg-curve spectrometer (BCS) has been constructed. The outer case was a molded plastic cone. Printed circuit techniques were used to form an insert with inscribed equipotentials to approximate a 1/r/sup 2/ electric field shape. The charge and energy resolution were measured for elastically scattered beams of 206 MeV /sup 28/Si, 413 and 378 MeV /sup 56/Fe, and 670 MeV /sup 86/Kr ions. Performance of this detector, particularly its charge resolution, is discussed with respect to variation in solid angle.

1984-02-01

393

Identification of data gaps and research needs for solid wastes from synfuel technologies  

Science.gov (United States)

This report presents an overview of research activity currently being funded by the US Department of Energy (DOE) on solid wastes from coal gasification, coal liquefaction, and oil shale technologies, Projects conducted in the DOE energy technology centers and national laboratories, and in cooperative projects with other government agencies, private industry, and universities are developing the basic and applied technology and data on which present and future fuel-conversion and utilization processes depend. The report identifies data gaps and recommends research needs where warranted.

1982-03-01

394

Future algorithm research needs for partitioning in solid mechanics and coupled mechanical models  

Energy Technology Data Exchange (ETDEWEB)

Exceptional progress has been made in mathematical algorithm research leading to optimized mesh partitions for the highly unstructured grids occurring in finite element applications in solid mechanics. Today another research challenge presents itself. Research is needed to include boundary conditions into the algorithms for partitioning meshes. We describe below two methods we use currently to accomplish this and propose a more general approach be developed which would apply to our problems today as well as to the coupled models we envision for the future. Finally, we suggest research be considered that would incorporate partitioning methods into parallel mesh generation.

1997-10-06

395

Freezing phenomena in ice-water systems  

Energy Technology Data Exchange (ETDEWEB)

The characteristics of solidification and melting are reviewed. The properties of water and ice and the phase diagram of water are discussed with special emphasis on ice density. A concise account of the freezing process and the Stefan problem is presented. To this end, the four stages of freezing are identified, supercooling, nucleation and the formation of dendritic ice, the growth of concentric rings of solid ice at 0{sup o}C and the final cooling of the solid ice are treated in some detail. The subject of bursting of pipes is given particular emphasis. Attention is drawn to a common misconception on pipe bursting and to misleading relationships for the computation of freezing time for ice blockage. Several current applications of melting and freezing systems are outlined. (author)

2002-09-01

396

Experimental Proof Of Principle For The Link-Up Of A Solid Oxide Fuel Cell With A Counter-Current Wood Gasifier  

Energy Technology Data Exchange (ETDEWEB)

The combination of wood gasification and high temperature fuel cells like solid oxide fuel cells (SOFC) is an interesting approach to achieve high electrical efficiencies (40%) in small scale combined heat and power plants. This combination is called 'Biomass - Integrated Gasification Fuel Cell System' (B-IGFC). The main challenge is the adjustment of the three main components gasification, gas cleaning and fuel cell. In this technology, the first proof of principle by combining a gasifier with a SOFC in a laboratory scale for more than 100 hours was achieved. During this period, no deactivation of the system was found. (author)

2005-03-01

397

Dielectric properties of solid solutions on the base of PbSc_1_/_2Sb_1_/_2O_3 antiferroelectric material  

International Nuclear Information System (INIS)

The results of dielectric measurements in a wide frequency range have been used to find that solid solution samples on the basis of PbSc_1_/_2Sb_1_/_2O_3 have blurred phase transitions. The Curie-Weiss law is performed for different compositions in the temperature range 10-150 K above Curie point. The change of value and sign of the difference between Curie and Curie-Weiss temperatures is connected with the change of phase transition blurring degree.

1988-01-01

398

Dampers, fluidics and the failsafe fallacy [fire protection  

International Nuclear Information System (INIS)

The fire protection practices adopted at nuclear power stations generally follow the well established principles used throughout industry. Unfortunately, there is one particular area - the interaction with heating, ventilation and air conditioning (HVAC) services - where nuclear power stations pose a seemingly insoluble conflict: that between the need to contain and the need to ventilate. Now, however, solid state fire dampers using power fluidics may promise a solution. One of the key characteristics of a fluidic device is that it is 'solid state', i.e. it has no moving parts. Because of this, its inherent reliability is orders of magnitude greater than a mechanical device. (U.K.).

399

Corrosion resistance of #gamma#-solid solution and hardening #gamma#'-phase of nickel alloys in sodium sulfate and chloride melts  

International Nuclear Information System (INIS)

Corrosion testings of model alloys, corresponding by chemical composition to simple and complex-alloyed #gamma#- and #gamma#'-phases of nickel heat-resistant alloys are conducted in sodium sulfate and chloride melts. It is ascertained that heat resistant nickel alloys containing over 50 % of hardening #gamma#'-phase, are subject to disastrous sulfide corrosion (SC). Resistance against SC alloys containing below 50 % of #gamma#'-phase is determined by the resistance of #gamma#-solid solution. 10 refs., 3 figs., 2 tabs.

400

Concentrated Kondo systems in solid solutions on the base of europium ternary compounds  

Energy Technology Data Exchange (ETDEWEB)

The experimental results of the components substitution effect on crystal structure, electronic transport properties, and Eu effective valence in solid solutions based on EuCu{sub 2}Si{sub 2} and EuPd{sub 2}Si{sub 2} ternary compounds are presented. It is shown, that when the Eu effective valence reaches the critical value {nu}{sup cr}{sub eff}=2.1, corresponding to degeneration of the 4f{sup 7} and 4f{sup 6} configurations, the condition of the concentrated Kondo system and an essential perturbation of the band electron spectrum near the Fermi level occur. (orig.).

1990-10-01

401

Concentrated Kondo systems in solid solutions on the base of europium ternary compounds  

International Nuclear Information System (INIS)

The experimental results of the components substitution effect on crystal structure, electronic transport properties, and Eu effective valence in solid solutions based on EuCu_2Si_2 and EuPd_2Si_2 ternary compounds are presented. It is shown, that when the Eu effective valence reaches the critical value #nu#"c"r_e_f_f=2.1, corresponding to degeneration of the 4f"7 and 4f"6 configurations, the condition of the concentrated Kondo system and an essential perturbation of the band electron spectrum near the Fermi level occur. (orig.).

402

Application of the pM{sup '}-pC{sub H} diagrams in the determination of hydrolysis constants of the lanthanides; Aplicacion de los diagramas pM{sup '}-pC{sub H} en la determinacion de las constantes de hidrolisis de los lantanidos  

Energy Technology Data Exchange (ETDEWEB)

The pM{sup '}-pC{sub H} diagrams allowed to determine the saturation and non-saturation zones of Lu(OH){sub 3} in solid phase and those were applied for determining the hydrolysis and lutetium solubility constants, using the radioactive isotope Lu-177. The first constant of hydrolysis was also determined by the potentiometric method in absence of solid phase. (Author)

2001-07-01

403

Anaerobic digestion of orange peel  

Energy Technology Data Exchange (ETDEWEB)

Anaerobic digestions fed with waste orange peels are stable at loading rates up to 3.5 kg total solids (TS)/cubic m.d if the amount of peel oil introduced into the digestion is less than 0.075 g/L digestion liquor per day. The yield of gas (50-55% methane) is 0.5 cubic m/kg of TS; conversion of solids to gas approaches 100%. Oil content of peels can be reduced to non-toxic levels using commercial oil recovery equipment. Presence of aromatic acids in digestion liquors cannot serve as an indication of toxicity or overloading.

1984-03-01

404

A simplified approach to the drying of solids in a batch fluidised bed  

Scientific Electronic Library Online (English)

Abstract in english A simplified model for drying solids in the constant rate period in a batch fluidised bed was developed.It assumes the bed to be divided into dense and bubble phases with heat and mass transfer between the phases.The model predicts the constant-rate drying period, provided the fluid bed shape and material characteristics are known.The model is compared with experimental data reported in the literature covering a wide range of materials, gas flow rates, column diameters, m (more) aterial hold-ups, air temperatures and humidities.Model predictions compare satisfactorily with the experimental data.

2002-07-01

405

Solubility limits of #alpha#' SIAION solid solutions in the system Si,Al,Y/N,O  

International Nuclear Information System (INIS)

The solubility limit of #alpha#'-SiAlON solid solutions on the Si_3N_4-YN:3AlN composition join in the system Si_3N_4-YN-AlN has been determined at 1800 degrees C. The end members of these solid solutions are Y_0_._4_3Si_1_0_._7Al_1_._3N_1_6 and Y_0_._8Si_9_._6Al_2_._4N_1_6. Unit-cell dimensions of the #alpha#'-SiAlON solid solutions in the system Si,Al,Y/N,O can be expressed as follows: a_0 (Angstrom) = 7.752 + 0.045m + 0.009n, c_0 (Angstrom) = 5.620 + 0.048m + 0.009n, where the #alpha#'-SiAlON solid solution has the formula Y_xSi_1_2_-_(_m _+ _n_)Al_m_+_nN_1_6_-_nO_n. The single-phase boundary of the solid solution #alpha#'-SiAlON on the composition triangle Si_3N_4-YN:3AlN-Al;N:Al_2O_3 is delineated. The present paper also reports the phase relationships involving #alpha#'-SiAlON.

406

Numerical Modeling of Reactive Multiphase Flow for FCC and Hot Gas Desulfurization Circulating Fluidized Beds  

Energy Technology Data Exchange (ETDEWEB)

This work was carried out to understand the behavior of the solid and gas phases in a CFB riser. Only the riser is modeled as a straight pipe. A model with linear algebraic approximation to solids viscosity of the form, {musubs} = 5.34{epsisubs}, ({espisubs} is the solids volume fraction) with an appropriate boundary condition at the wall obtained by approximate momentum balance solution at the wall to acount for the solids recirculation is tested against experimental results. The work done was to predict the flow patterns in the CFB risers from available experimental data, including data from a 7.5-cm-ID CFB riser at the Illinois Institute of Technology and data from a 20.0-cm-ID CFB riser at the Particulate Solid Research, Inc., facility. This research aims at modeling the removal of hydrogen sulfide from hot coal gas using zinc oxide as the sorbent in a circulating fluidized bed ...

2005-07-01

407

Growth of Pinus radiada in soil containing solid waste from the kraft pulp industry  

Energy Technology Data Exchange (ETDEWEB)

The germination and growth of Pinus radials Don. plantlets in solid residues deriving from a Kraft pulp industry was evaluated. Plant conditions were monitored by histological studies of roots and shoot-tips, as well as by plant analyses of several essential and non essential elements. The solids employed consisted of ashes, fly-ashes, dregs, grits, primary sludge, brown stock screening rejects and various mixtures of them. Their addition, in a range of combinations to sandy/metamorphic or marine terrace/clay soils, resulted in effective and sustained growth under greenhouse conditions. Low proportions of wastes favored growth in most cases, indicating that they may act as fertilisers. In some experiments, especially in those where waste was added in proportions ranging from 50% to 60%, germination and/or development were slightly affected. Two-year old field experiments have confirmed that in spite of the high pH values, Na ion content or ...

2000-06-01

408

[sup 123]I-MIBG myocardial scintigraphy in diabetic patients. Association with autonomic neuropathy  

Energy Technology Data Exchange (ETDEWEB)

[sup 123]I-metaiodobenzylguanidine (MIBG) myocardial scintigraphy was performed in 20 diabetic patients (NIDDM) and 8 control subjects to investigate the association between clinical autonomic nerve dysfunction and myocardial accumulation of MIBG. We used coefficient variance of R-R interval (CV[sub R-R]) as a index of the autonomic neuropathy and categorized diabetes into two groups (CV[sub R-R][>=]2.0: non-autonomic neuropathy. CV[sub R-R]<2.0: autonomic neuropathy). In planar imaging studies, heart to mediastinum MIBG uptake ratio (H/M) was calculated on both early and delayed images. The washout ratio of [sup 123]I-MIBG in the heart (%WR) was also obtained using myocardial tracer activity on the both images. Mean value of these indices in diabetic group did not reveal any significant difference with the value in the control group. On the SPECT images, low uptake was observed in the posterior-inferior wall with normal uptake of [sup 201]Tl in diabetic ...

1994-09-01

409

Theoretical study on antitumor activity of palladium(II) and platinum(II) complexes with isoxazole and its derivatives  

Energy Technology Data Exchange (ETDEWEB)

The palladium(II) and platinum(II)complexes(where, (M(L){sub 2}X{sub 2}), M=Pd(II), Pt(II); L=isoxazole (isox), 3, 5-dimethylisoxazole(3, 5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Ph-isox), and 4-amino-3, 5-di-methylisoxazole (4-ADI); X=Cl, Br) with isoxazole and its derivatives were investigated on antitumor activity by MM2 and EHMO calculation. Because for all the complexes the {sigma}MO energy level (E{sub {sigma}}{sub (M-X)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of halogen atom is less than {sigma}MO energy level E{sub {sigma}}{sub (M-N)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of N atom, without exception. And judging, from the lower E{sub {sigma}}{sub (M-X)} value in trans, the bonding strength was found to be weaker in trans isomer than in cis. For the Pd(II) and Pt(II) complexes which have planar ligands, it was shown that for all the complexes dissociation of ...

1998-02-01

410

The application of 64 multidetector CT angiography in the evaluation of carotid stenosis and follow-up of carotid endarterectomy and percutaneous transluminal stenting  

International Nuclear Information System (INIS)

Objective: To evaluate the diagnostic value of 64 multidetector-row CT angiography for internal carotid artery (ICA) stenosis and the application in the follow-up of carotid endarterectomy and percutaneous transluminal stenting. Methods: Forty transient ischemic attack (TIA) patients with interpretable CTA and DSA of the cervical carotid arteries were selected from May 2005 to December 2005. This yielded a total of 80 vessels. The CTA curved planar reformations (CPR) and DSA images referenced to the distal cervical internal carotid were graded by two senior neuroradiologists blindly, according to the North American Symptomatic Carotid Endarterectomy Trial (NASCET) guidelines. The paired-t test was used to verify the statistical significant difference between pre-operating and post-operating of carotid endarterectomy or percutaneous transluminal stenting in measuring the vascular diameter and area of cross section using CTA. Results: When the 70% stenosis was used ...

2006-09-01

411

Tensile strain limits of buried defects in pipeline girth welds  

Energy Technology Data Exchange (ETDEWEB)

There are currently no accepted industry standards for the tensile strain limits of girth welds. This paper investigated the behavior of girth welds with buried defects subjected to high longitudinal strains caused by soil movement. A strain design methodology based on a crack driving method was used to examine the factors influencing stain limits along with a constraint-sensitive fracture mechanics approach. No strength undermatching was used in the welds, and the defect location had no influence on crack driving force. The weld joint was assumed to have uniform tensile properties. A 3D finite element (FE) model was used to simulate pipe behavior. Symmetric boundary conditions were imposed on the symmetry planes, and uniform remote axial displacement was applied as the primary loading. Automated data processing routines were developed to extract and analyze the data. The crack driving force was computed directly from a crack tip deformation profile at the deepest point of the defect ...

2004-07-01

412

Technology base research on zinc/air battery systems: Final report  

Energy Technology Data Exchange (ETDEWEB)

The capacity extension of additives was tested in a 200 cm/sup 2/bi-cell and a Zn powder moving-bed slurry. It was found that for the Type A additives in 12 M KOH, 25 g/l of silicate provided higher capacity than stannate, titanate and aluminate additives. The optimum concentration of sorbitol (a Type B additive that stabilizes polymeric chains involving ZnO) was found to be 15 g/l in 12 M KOH. A silicate and sorbitol combination added to Zn powder slurry in 12 M KOH provided a 20% increase in discharge capacity (195 Ah/l at 200 A/cm/sup 2/) compared to the maximum capacity obtained with silicate alone. A much lower capacity (74 Ah/l) was realized with silicate as Type C additive (precipitation of ZnO away from the Zn surface, for low KOH concentrations). The mechanisms of passivation and capacity extension were discussed and a model presented. The cell voltage and power densities were determined for the discharge process as a function of (a) current densities, (b) cathode depolarizer ...

1987-09-01

413

Synthesis, structure, and antitumor activity of novel platinum(II) complexes involving asymmetric chiral diamines as carrier ligands  

Energy Technology Data Exchange (ETDEWEB)

New platinum(II) complexes with asymmetrically substituted chiral diamine ligands A{sub 2}PtX{sub 2}, (A{sub 2}=NH{sub 2}CH(CH{sub 3})CH{sub 2}NH(c-C{sub 5}H{sub 9}) (apcpa), NH{sub 2}CH(CH{sub 3})CH{sub 2}NH(c-C{sub 6}H{sub 11}) (apcha); X{sub 2}=2Cl, isopropylidenmalonate (IPM), 1,1'-cyclobutandicarboxylate (CBDCA) have been synthesized and characterized by means of elemental analyses, infrared and NMR spectroscopies, and X-ray crystallography. The crystal structures of (S-apcha)Pt[CBDCA]{center_dot}3H{sub 2}O (orthorhombic, P2{sub 1}2{sub 1}2(No. 18), a=6.926(3), b=15.243(3), c=19.319(4) A, V=2039.5(10) A{sup 3}, Z=4, R=0.072) and (S-apcha)Pt[IPM]{center_dot}2.5H{sub 2}O (monoclinic, P2/c(No. 13), a=9.882(1), b=18.502(1), c=22.056(1) A, V=4032.8(5) A{sup 3}, Z=8, R=0.093) exhibit that the platinum atoms achieve a typical square planar arrangement with two nitrogen atoms in cis position and with the chiral center retained. The spectroscopic data disclose ...

1999-12-01

414

Synthesis and biodistribution of nitrido technetium-99m radiopharmaceuticals with dithiophosphinate ligands: a class of brain imaging agents  

Energy Technology Data Exchange (ETDEWEB)

The symmetrical complexes [{sup 99m}Tc][TcN(R{sub 2}PS{sub 2}){sub 2}] [R = CH{sub 3}, CH{sub 2}CH{sub 3}, CH{sub 2}CH{sub 2}CH{sub 3}, CH{sub 2}(CH{sub 3}){sub 2}], and the unsymmetrical complex [{sup 99m}Tc][TcN(Me{sub 2}PS{sub 2})(Et{sub 2}PS{sub 2})] have been prepared, at tracer level, through a two-step procedure involving the preliminary formation of a prereduced technetium nitrido intermediate followed by substitution reaction onto this species by the appropriate dithiophosphinate ligand [R{sub 2}PS{sub 2}]Na. The chemical identity of the resulting complexes have been established by comparison with the corresponding {sup 99}Tc-analogs prepared, at macroscopic level, by reacting the complex [{sup 99}TcNCl{sub 4}] [n-Bu{sub 4}N] (n-Bu = n-butyl) with an excess of ligand in methanol, and characterized by elemental analyses and spectroscopic techniques. The complexes are neutral and lipophilic, and possess a square pyramidal geometry, with an apical Tc N group and two ...

1995-04-01

415

Synthesis and biodistribution of nitrido technetium-99m radiopharmaceuticals with dithiophosphinate ligands: a class of brain imaging agents  

International Nuclear Information System (INIS)

The symmetrical complexes ["9"9"mTc][TcN(R_2PS_2)_2] [R = CH_3, CH_2CH_3, CH_2CH_2CH_3, CH_2(CH_3)_2], and the unsymmetrical complex ["9"9"mTc][TcN(Me_2PS_2)(Et_2PS_2)] have been prepared, at tracer level, through a two-step procedure involving the preliminary formation of a prereduced technetium nitrido intermediate followed by substitution reaction onto this species by the appropriate dithiophosphinate ligand [R_2PS_2]Na. The chemical identity of the resulting complexes have been established by comparison with the corresponding "9"9Tc-analogs prepared, at macroscopic level, by reacting the complex ["9"9TcNCl_4] [n-Bu_4N] (n-Bu = n-butyl) with an excess of ligand in methanol, and characterized by elemental analyses and spectroscopic techniques. The complexes are neutral and lipophilic, and possess a square pyramidal geometry, with an apical Tc N group and two dithiophosphinate ligands spanning the four positions on the basal plane through the four sulfur atoms of the >PS_2 group. ...

1995-04-01

416

Radiation resistance of flexible graphites  

International Nuclear Information System (INIS)

Polymer sealing parts are widely used in various branches of engineering as detachable joints that operate at normal and cryogenic temperatures. They are also used in nuclear-power engineering to seal pumps, pipelines, etc., where they operate at 600-650 K under a neutron fluence of around 10"1"6 cm"-"2 (E #>=# 0.18 MeV) and concomitant #gamma#-irradiation of about 10"6 R. The fluoroplastic-based materials currently used degrade when irradiated in water at 320-360 K with a neutron fluence of 10"1"5 cm"-"2 (thermal neutrons) or 10"1"4 cm"-"2 (fast neutrons), and a concomitant #gamma#-irradiation dose of 2 x 10"6 R. The strength of these fluoroplastics decreases markedly after #gamma#-irradiation (from a cobalt source) at room temperature at doses above 10"6 R. For this reason, flexible and swelling graphites are finding ever increasing application. Graflex foils made of extra-pure natural graphite were found to be radiation-resistant and suitable for use as seals and ...

417

Radiation hardening effects on localized deformation and stress corrosion cracking of stainless steels  

International Nuclear Information System (INIS)

Radiation hardening in austenitic stainless steels is shown to modify deformation characteristics and correlate well with an increased susceptibility to intergranular stress corrosion cracking (IGSCC). Available data on neutron-irradiated materials have been analyzed and correlations developed between fluence, yield strength and cracking susceptibility in high-temperature water environments. Large heat-to-heat differences in the critical fluence (0.2 to 2.5 x10"2"1 n/cm"2) for IGSCC are documented. In many cases, this variability is consistent with yield strength differences among irradiated materials. IGSCC correlates better to yield strength than to fluence for most heats suggesting a possible role of radiation-induced hardening and microstructure on cracking. Microstructural evolution during proton and heavy-ion irradiation has been characterized in low-carbon 304SSs. Hardening results from a dispersion of dislocation loops in the matrix which increase in density and size with ...

1993-08-01

418

Quantitative imaging of turbulent and reacting flows  

Energy Technology Data Exchange (ETDEWEB)

Quantitative digital imaging, using planar laser light scattering techniques is being developed for the analysis of turbulent and reacting flows. Quantitative image data, implying both a direct relation to flowfield variables as well as sufficient signal and spatial dynamic range, can be readily processed to yield two-dimensional distributions of flowfield scalars and in turn two-dimensional images of gradients and turbulence scales. Much of the development of imaging techniques to date has concentrated on understanding the requisite molecular spectroscopy and collision dynamics to be able to determine how flowfield variable information is encoded into the measured signal. From this standpoint the image is seen as a collection of single point measurements. The present effort aims at realizing necessary improvements in signal and spatial dynamic range, signal-to-noise ratio and spatial resolution in the imaging system as well as developing excitation/detection ...

1993-12-01

419

Prospective evaluation of femoral head viability following femoral neck fracture  

International Nuclear Information System (INIS)

The bone scans of 33 patients (pts) with recent subcapital fractures (fx) of the femur were evaluated prospectively to determine their value in predicting femoral head visability. Each of the 33 pts (ll men, 22 women, age range 30-92) had a pre-operative bone scan within 72 hrs of the fx (23 pts within 24 hrs). Anterior and posterior planar views of both hips and pinhole views (50% of pts) were obtained 2 hrs after administration of Tc-99m HDP. The femoral head was classified as perfused if it showed the same activity as the opposite normal side or if it showed only slightly decreased activity. Femoral heads showing absent activity were classified as nonperfused. Overall, 20 of the 33 pts showed a photopenic femoral head on the side of the fx. Only 2 pts showed increased activity at hte site of the fx. Internal fixation of the fx was performed in 23 pts, 12 of whom had one or more follow-up scans. Five of these 12 pts showed absent femoral head activity on their ...

1984-06-05

420

Optical Properties and Wave Propagation in Semiconductor-Based Two-Dimensional Photonic Crystals  

Energy Technology Data Exchange (ETDEWEB)

This work is a theoretical investigation on the physical properties of semiconductor-based two-dimensional photonic crystals, in particular for what concerns systems embedded in planar dielectric waveguides (GaAs/AlGaAs, GaInAsP/InP heterostructures, and self-standing membranes) or based on macro-porous silicon. The photonic-band structure of photonic crystals and photonic-crystal slabs is numerically computed and the associated light-line problem is discussed, which points to the issue of intrinsic out-of-lane diffraction losses for the photonic bands lying above the light line. The photonic states are then classified by the group theory formalism: each mode is related to an irreducible representation of the corresponding small point group. The optical properties are investigated by means of the scattering matrix method, which numerically implements a variable-angle-reflectance experiment; comparison with experiments is also provided. The analysis of surface ...

2002-12-31

421

Novel silicon fabrication process for high-aspect-ratio micromachined parts  

Energy Technology Data Exchange (ETDEWEB)

Bulk micromachining generally refers to processes involving wet chemical etching of structures formed out of the silicon substrate and so is limited to fairly large, crude structures. Surface micromachining allows intricate patterning of thin films of polysilicon and other materials to form essentially two-dimensional layered parts (since the thickness of the parts is limited by the thickness of the deposited films). There is a third type of micromachining in which the part is formed by filling a mold which was defined by photolithographic means. Historically micromachining molds have been formed in some sort of photopolymer, be it with x-ray lithography (``LIGA``) or more conventional UV lithography, with the aim of producing piece parts. Recently, however, several groups including ours at Sandia have independently come up with the idea of forming the mold for mechanical parts by etching into the silicon substrate itself. In Sandia`s mold process, the mold is recessed into the ...

1995-08-01

422

Metastability and dynamics of the shock-induced phase transition in iron  

Energy Technology Data Exchange (ETDEWEB)

The shock-induced {alpha}(bcc){r_arrow}{var_epsilon}(hcp) transition in iron begins at 13 GPa on the Hugoniot. In the two-phase region above 13 GPa, the Hugoniot lies well above the equilibrium surface defined by G{sub {alpha}}=G{sub {var_epsilon}}, with G the Gibbs free energy. Also, the phase transition relaxation time {tau} is uncertain, with estimates ranging from {lt}50 ns to {approx}180 ns. Here we present an extensive study of these important aspects, metastability and dynamics, of the {alpha}-{var_epsilon} transition in iron. Our primary theoretical tools are (a) accurate theoretically based free energies for {alpha} and {var_epsilon} phases of iron and (b) accurate calculations of the wave evolution following planar impacts. We define metastable surfaces for forward and reverse transitions by the condition that the thermodynamic driving force G{sub {alpha}}{minus}G{sub {var_epsilon}} is just balanced by an opposing force resulting from elastic stresses, ...

1997-02-01

423

LES study of heat transfer augmentation and wake instabilities of a rotating disk in a planar stream of air  

Energy Technology Data Exchange (ETDEWEB)

Large-eddy-simulations are performed for the heat transfer and the wake flow of a thin rotating disk subjected to an outer parallel passing stream of air. Above a critical value for the angular velocity of the disk, heat transfer augmentation sets on. This is strongly related to a flow instability that leads to a periodic vortex generation at the counter-moving disk side. The resulting phenomena are captured by the classical Landau model. For higher angular velocities the wake becomes fully turbulent, and here the transition to turbulence seems to be very abrupt. In this regime, a periodic vortex generation is observable at the co-moving disk side, too. (orig.) [German] Grobstruktur-Simulationen werden fuer die Waermeuebertragung und die Nachlaufstroemung fuer eine duenne rotierende Scheibe in einem aeusseren parallelen Luftstrom durchgefuehrt. Oberhalb eines kritischen Wertes fuer die Rotationsgeschwindigkeit setzt eine Verstaerkung der Waermeuebertragung ein. Dies ist eng mit einer ...

2004-02-01

424

Influence of sedation and data acquisition method on tracer uptake in animal models: ["1"2"3I]-2-iodo-L-phenylalanine in pentobarbital-sedated tumor-bearing athymic mice  

International Nuclear Information System (INIS)

Objectives: To minimize movement artifacts during tracer imaging studies, the animals are generally sedated. Although many reports describe the effect of barbiturates on brain function, less is published about the general impact on the extracerebral metabolism and tracer biodistribution. This report describes the influence of pentobarbital on tumor uptake of ["1"2"3I]-2-iodo-L-phenylalanine (["1"2"3I]-2I-L-PA) using dissection and nuclear imaging. Methods: R1M tumor-bearing athymic mice were divided into two populations: untreated and pentobarbital-treated. Each group was subjected to dynamic and static planar imaging and organ dissection after ["1"2"3I]-2I-L-PA injection. Two-compartment blood modeling was performed. Analysis of variance (ANOVA), t test and clustered boxplot analyses were used to compare the results between the treatment groups and between the data acquisition methods. Results: Two-compartment blood modeling demonstrated that pentobarbital ...

2006-01-01

425

Hydrogen embrittlement, revisited by in situ electrochemical nanoindentation  

Energy Technology Data Exchange (ETDEWEB)

The fine scale mechanical probing capability of NI-AFM was used to examine hydrogen interaction with plasticity. To realize this, an electrochemical three electrode setup was incorporated into the NI-AFM. The developed ECNI-AFM is capable of performing nanoindentation as well as imaging surfaces inside electrolytes. The developed ECNI-AFM setup was used to examine the effect of cathodically charged hydrogen on dislocation nucleation in pure metals and alloys. It was shown that hydrogen reduces the pop-in load in all of the tested materials except Cu. The reduced pop-in load can be interpreted as the HELP mechanism. Classical dislocation theory was used to model the homogeneous dislocation nucleation and it was shown that H reduces the activation energy for dislocation nucleation in H sensitive metals which are not undergoing a phase transformation. The activation energy for dislocation nucleation is related to the material specific parameters; shear modulus {mu}, dislocation core ...

2007-07-01

426

Effect of Ba on ferroelectric and piezoelectric properties of the PLZT (1.2/55/45) system  

International Nuclear Information System (INIS)

Ferroelectric Pb_0_._9_8_2_-_zLa_0_._0_1_2#DELTA#_0_._0_0_6Ba_z(Zr_0_._5_5Ti_0_._4_5)O_3 (PLZT; z = 0-6 mol%) ceramic compositions were fabricated by a mixed-oxide method. X-ray diffraction studies of sintered ceramics indicate the coexistence of rhombohedral and tetragonal phases in the 5 mol% Ba-doped PLZT composition. Grain growth is inhibited with increasing Ba concentration in the PLZT system as evidenced by scanning electron micrographs. Dielectric constant and dielectric loss as a function of temperature suggest that #epsilon#_r_t and tan #delta# are increased up to compositions containing 4 and 5 mol% Ba, respectively. The dielectric maximum (#epsilon#_T_c) decreased to 4 mol% Ba and gradually increased to 6 mol% Ba, whereas, with increasing Ba concentration in the PLZT system, the Curie temperature (T_C) decreased from the composition with no Ba to that with 6 mol% Ba. Relaxor behavior as a function of temperature and frequency was studied over the composition series. As the ...

2006-06-01

427

Dynamics of a very intense pulsed electron beam  

Energy Technology Data Exchange (ETDEWEB)

A unique beam of pulsed electrons has been developed using the 19-MeV, 700-kA Hermes-III accelerator. The extended planar-anode diode is used to extract at large radius an annular electron beam from the accelerator and inject the resulting beam at small angle into a low-pressure gas cell, where the beam is rapidly charge neutralized and almost current neutralized. Under these conditions, the beam propagates nearly ballistically to a focus downstream of injection, where objects can be placed for irradiation and study. For a focal length of 78 cm, measurements with a segmented calorimeter show that this configuration can deliver an energy deposition of 200 J/g [20 Mrad] over a useful area of 70 cm{sup 2} and a 4-cm depth in graphite in 25 ns. Increasing the injection angle by reducing the AK gap permits higher doses over smaller areas to be achieved. Such beams are of interest for the study of material property changes from short-pulse high-energy depositions and for ...

1994-12-31

428

Design and integration of a solar AMTEC power system with an advanced global positioning satellite  

Energy Technology Data Exchange (ETDEWEB)

A 1,200-W solar AMTEC (alkali metal thermal-to-electric conversion) power system concept was developed and integrated with an advanced global positioning system (GPS) satellite. The critical integration issues for the SAMTEC with the GPS subsystems included (1) packaging within the Delta 2 launch vehicle envelope, (2) deployment and start-up operations for the SAMTEC, (3) SAMTEC operation during all mission phases, (4) satellite field of view restrictions with satellite operations, and (5) effect of the SAMTEC requirements on other satellite subsystems. The SAMTEC power system was compared with a conventional planar solar array/battery power system to assess the differences in system weight, size, and operations. Features of the design include the use of an advanced multitube, vapor anode AMTEC cell design with 24% conversion efficiency, and a direct solar insolation receiver design with integral LiF salt canisters for energy storage to generate power during the ...

1996-12-31

429

Characterization and properties of monoammine nitroimidazole complexes of platinum (PtCl sub 2 (NH sub 3 )(NO sub 2 Im)). Crystal and molecular structure of cis-Amminedichloro(1-((((2-hydroxyethyl)amino)carbonyl)methyl)-2-nitroimidazole)platinum(II)  

Energy Technology Data Exchange (ETDEWEB)

The characterization of monoammine(nitroimidazole)platinum(II) complexes of structure (PtCl{sub 2}(NH{sub 3})(NO{sub 2}Im)) (NO{sub 2}Im = 1-((((2-hydroxyethyl)amino)carbonyl)methyl)-2-nitroimidazole, Etanidazole (I), 1-(2-nitro-1-imidazolyl)-3-methoxy2-propanol, Misonidazole (II), and 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole, Metronidazole (III)) is reported. Both is cis and trans isomers may be isolated for II and III. The crystal structure of cis-amminedichloro(1-((((2-hydroxyethyl)amino)carbonyl)methyl)-2-nitroimidazole)platinum(II) has been determined by X-ray diffraction. The crystals are orthorhombic, space group Pnab with cell dimensions a = 14.867 (7) {angstrom}, b = 9.915 (5) {angstrom}, c = 19.015 (9) {angstrom}, and Z = 8. The structure was refined to R = 0.062 and R{sub w} = 0.052. Platinum has the expected square-planar coordination. The Pt-Cl bond trans to the nitroimidazole ligand is shorter (2.269 (3) {angstrom}) than normal. The dihedral angle ...

1991-11-27

430

Application of constraint-sensitive fracture mechanics to the assessment of girth weld integrity  

Energy Technology Data Exchange (ETDEWEB)

The dominant fracture parameters used in fracture mechanics analyses of pipelines are related to the asymptotic crack-tip stress and strain fields at the crack tip. This paper reviewed new developments in constraint-sensitive fracture mechanics for the assessment of pipeline girth weld integrity. Constraint theories and experimental studies were evaluated. Constraint models included brittle fracture models and ductile fracture models. Constraint models for brittle fracture are based on weakest link statistics and Weibull distribution. Specifically designed experimental tests are often necessary to derive the damage parameters of ductile fracture models. Experimental test data must then be calibrated with finite element analyses (FEA) to ensure that the correct damage parameters are chosen. The effects of specimen geometry and loading condition are characterized by the T stress, while Q stress is the hydrostatic stress defined by the difference between stress fields, geometry and ...

2004-07-01

431

Spectroscopic investigation of the charge dynamics of heavy ions penetrating solid and gaseous targets  

Energy Technology Data Exchange (ETDEWEB)

This thesis presents the study of the slowing down process of fast heavy ions inside matter. In the framework of this research, the influence of the target density on the stopping process is investigated. Experiments on the interaction of {sup 48}Ca{sup 6+}-{sup 48}Ca{sup 10+} and {sup 26}Mg{sup 5+} ion beams with initial energies of 11.4 MeV/u and 5.9 MeV/u with solid and gaseous targets have been carried out. A novel diagnostic method, X-ray spectroscopy of K-shell projectile radiation, is used to determine the ion charge state in relation to its velocity during the penetration of fast heavy ions inside the stopping material. A spatially resolved analysis of the projectile and target radiation in solids is achieved for the first time. The application of low-density silica aerogels as stopping media provided a stretching of the ion stopping length by 20 - 100 times in comparison with solid quartz. The Doppler Effect ...

2007-01-15

432

Solid/liquid lubrication of ceramics at elevated temperatures  

Energy Technology Data Exchange (ETDEWEB)

This study investigates the effect of solid and liquid lubrication on friction and wear performance of silicon nitride (Si{sub 3}N{sub 4}) and cast iron. The solid lubricant was a thin silver film ({approx}2 {mu}m thick) produced on Si{sub 3}N{sub 4} by ion-beam-assisted deposition. A high-temperature polyol-ester-base synthetic oil served as the liquid lubricant. Friction and wear tests were performed with pin-on-disk and oscillating-slider wear test machines at temperatures up to 300{degrees}C. Without the silver films, the friction coefficients of Si{sub 3}N{sub 4}/Si{sub 3}N{sub 4} test pairs were 0.05 to 0.14, and the average wear rates of Si{sub 3}N{sub 4} pins were {approx}5 x 10{sup -8} mm{sup 3} N{sup -1}. The friction coefficients of Si{sub 3}N{sub 4}/cast iron test pairs ranged from 0.08 to 0.11, depending on test temperature. The average specific wear rates of cast iron pins were {approx}3 x 10{sup -7} mm{sup 3} N{sup -1} m{sup -1}. ...

1996-04-01

433

Solid state secondary battery with lithium ion conductive solid electrolyte, Li3PO4-Li2S-SiS2; Li3PO4-Li2S-SiS2 kei kotai denkaishitsu wo mochiita zenkotai richiumu niji denchi  

Energy Technology Data Exchange (ETDEWEB)

Powder mold type solid state battery was fabricated, and positive electrode compounding ratio and the battery characteristics were studied. The current density depended greatly on the TiS2 content of positive electrode material, and the current density showed maximum value of 800 {mu}A/cm{sup 2} at a TiS2 content of 40 wt%. This composition is expected to be the best to provide better charge-discharge characteristics. The rate capability of TiS2 is dominated by Li{sup +} ion in positive electrode. Further, the diffusion of lithium ion is greatly dominated by TiS2 in positive electrode, compounding ratio of solid state electrolyte and its particle size. Results of charge-discharge characteristics studied for various charge-discharge current densities revealed that the rate capability of TiS2 was more than 50% for a current density of less than 254 {mu}A/cm{sup 2}, and this battery system proved the possibility of high rate of charge-discharge. ...

1995-01-05

434

Removal of H2S and SO2 by CaCO3-Based Sorbents at High Pressure  

Energy Technology Data Exchange (ETDEWEB)

The theoretical and experimental investigation of the mechanism of SO2 and H2S removal by CaCO3 -based sorbents (limestones and dolomites) in pressurized uidized-bed coal combustors (PFBC) and high pressure gasiers, respectively, is the main objective of this study. It is planned to carry out reactivity evolution experiments under simulated high pressure conditions or in high pressure thermogravimetric and, if needed, uidized- bed reactor (high pressure) arrangements. The pore structure of fresh, heat-treated, and half-calcined solids (dolomites) will be analyzed using a variety of methods. Our work will focus on limestones and dolomites whose reaction with SO2 or H2S under atmospheric conditions has been studied by us or other research groups in past studies. Several theoret- ical tools will be employed to analyze the obtained experimental data including a variable diusivity shrinking-core model and models for diusion, reaction, and structure evolution in ...

1998-02-01

435

Phase reactions in Ti(C,N)/(Ti,W)C, Ti(C,N)/(Ti,Mo)C, (Ti,W)(C,N)/Co and (Ti,W)(C,N)/Ni diffusion couples  

International Nuclear Information System (INIS)

In order to investigate interactions of (Ti,W)(C,N) and (Ti,Mo)(C,N) with binder metals solid/solid diffusion couples were annealed. These two-dimensional arrangements provide good access to phase reactions occurring upon sintering already in the solid state. It was found in (Ti,W)(C,N)/Co- and (Ti,W)(C,N)/Ni-based couples that the reaction zone is thinner in contact with Co than with Ni. It was also observed that the reaction rate with both Co and Ni is lower if nitrogen is added to the hard phases. Beside a thickness variation of the diffusion zones a change in the microstructure was found. At the interface of nitrogen-free hard phases in contact with Co elongated microstructural constituents are formed with the main axis perpendicular to the interface, while at the interface of nitrogen-containing hard phases these elongated microstructural constituents were found in contact with Ni. Also phase reactions and the diffusion behavior between ...

2001-05-01

436

Nonstoichiometry and diffusion in ceria and ceria solid solutions  

Energy Technology Data Exchange (ETDEWEB)

Some of the results of property measurements of CeO{sub 2} and its solid solutions were reviewed. The deviation from stoichiometry of undoped and doped CeO{sub 2} was presented in several figures, which suggested that CeO{sub 2} fired at high temperatures in air might be nonstoichiometric in some degree. At low temperatures, the deviation from stoichiometry in doped CeO{sub 2} is higher than undoped CeO{sub 2}. As another interesting property, CeO{sub 2} shows high solubility to trivalent cations such as rare earth elements. A possible reason behind this high solubility was presented. The nonstoichiometric defect in undoped CeO{sub 2} and the trivalent cation in solid solution with CeO{sub 2} have to be compensated by other defects. The possible defect structures in this solid solution were reviewed and the most probable structure was chosen based on density measurement and impurity dependence of oxygen diffusion ...

2003-07-01

437

DYNAMICS OF SOLIDS IN THE MIDPLANE OF PROTOPLANETARY DISKS: IMPLICATIONS FOR PLANETESIMAL FORMATION  

International Nuclear Information System (INIS)

We present local two-dimensional and three-dimensional hybrid numerical simulations of particles and gas in the midplane of protoplanetary disks (PPDs) using the Athena code. The particles are coupled to gas aerodynamically, with particle-to-gas feedback included. Magnetorotational turbulence is ignored as an approximation for the dead zone of PPDs, and we ignore particle self-gravity to study the precursor of planetesimal formation. Our simulations include a wide size distribution of particles, ranging from strongly coupled particles with dimensionless stopping time #tau#_s #ident to# #OMEGA#t_s_t_o_p = 10"-"4 (where #OMEGA# is the orbital frequency, t_s_t_o_p is the particle friction time) to marginally coupled ones with #tau#_s = 1, and a wide range of solid abundances. Our main results are as follows. (1) Particles with #tau#_s #approx#> 10"-"2 actively participate in the streaming instability (SI), generate turbulence, and maintain the height of the ...

2010-10-20

438

Contaminant assimilation in newly created prairie wetlands  

Energy Technology Data Exchange (ETDEWEB)

Increased use of wetlands for habitat and water quality improvement emphasize the need for further study of abiotic-biotic interactions in these systems. This research examined contaminant assimilation within the water column of two newly created Colorado prairie wetlands (RMA3 and RMA4). To examine the influence of abiotic factors (e.g., alkalinity, suspended solids), ten chronic toxicity tests were performed from December 1991 through November 1993. In the first set of tests, Ceriodaphnia dubia were exposed to water from the two wetlands which was spiked with various concentrations of zinc. These tests suggested that water from RMA4 had higher contaminant assimilative capacity than water from RMA3. Preliminary analysis suggested suspended solids, pH, conductivity, and temperature were important factors affecting neonate production by C. dubia when exposed to zinc-spiked wetland water. To test the importance of suspended ...

1994-12-31

439

Upgrading of brown coal by slurry-dewatering; Kattan no yuchu dassui ni yoru clean kotai nenryo no seizo  

Energy Technology Data Exchange (ETDEWEB)

This paper describes an outline of solid fuel production process from brown coal and the investigation results of its elemental techniques. Dried coal is produced by this process which consists of a dewatering of crushed brown coal in oil-based solvent, a solid and liquid separation of slurry, and a remained oil recovery by heating. This process is characterized by the higher thermal efficiency compared with usual drying and the restraint of spontaneous combustion of product coal. It was revealed that solid fuel with low moisture, low ash, low sulfur, and suppressed spontaneous combustion property can be produced from Australian brown coal through this process. From the comparison between kerosene and fuel oil A, it was confirmed that the oil content during dewatering was smaller and the oil recovery by heating was easier by using a solvent with lower boiling point. It was also confirmed that the spontaneous combustion ...

1996-10-28

440

Thermodynamic and kinetic aspects of surface acidity  

Science.gov (United States)

Our research in the general area of acid catalysis involves the characterization of solid acidity and the corresponding assessment of catalytic performance of acidic materials. Acid characterization studies are required to provide essential information about the type of acid site (i.e., Lewis versus Bronsted), the strength of the sites, and the mobility of molecules adsorbed on the acid sites. An accurate measure of acid strength is given by the heat of adsorption of a basic probe molecule on the acid site. A thermodynamic representation of the mobility of adsorbed species on these sites is given by the entropy of adsorption. Important techniques used in these acid site characterization studies include microcalorimetry, thermogravimetric measurements, temperature programmed desorption, infrared spectroscopy and solid state nuclear magnetic resonance. The combination of these acid site characterization studies with reaction kinetics measurements ...

1992-01-01

441

Synthesis of novel high-voltage cathode material LiCoPO{sub 4} via rheological phase method  

Energy Technology Data Exchange (ETDEWEB)

For the first time, rheological phase method, a simple and effective route, is applied to synthesize novel cathode material LiCoPO{sub 4}. X-ray diffraction spectrometer (XRD), X-ray photoelectron spectrometer (XPS), transmission electron microscope (TEM) and electrochemical impedance spectroscopy (EIS) are taken to investigate this material, respectively. XRD figure shows that the rheological sample is better crystallized than the solid-state one. XPS result of the rheological sample exhibits that the valence of Co is 2+. TEM images show that better dispersed particles with smaller size can be formed by rheological method comparing to the solid-state route. Charge-discharge test is carried out in the range of 3.0-5.0 V at 0.2 mA cm{sup -2}. The initial discharge capacity for rheological phase and solid-state powder is 71.5 and 30.9 mAh g{sup -1}, respectively. The better electrochemical property should be ascribed to the ...

2010-07-23

442

Synthesis of novel high-voltage cathode material LiCoPO4 via rheological phase method  

International Nuclear Information System (INIS)

For the first time, rheological phase method, a simple and effective route, is applied to synthesize novel cathode material LiCoPO4. X-ray diffraction spectrometer (XRD), X-ray photoelectron spectrometer (XPS), transmission electron microscope (TEM) and electrochemical impedance spectroscopy (EIS) are taken to investigate this material, respectively. XRD figure shows that the rheological sample is better crystallized than the solid-state one. XPS result of the rheological sample exhibits that the valence of Co is 2+. TEM images show that better dispersed particles with smaller size can be formed by rheological method comparing to the solid-state route. Charge-discharge test is carried out in the range of 3.0-5.0 V at 0.2 mA cm-2. The initial discharge capacity for rheological phase and solid-state powder is 71.5 and 30.9 mAh g-1, respectively. The better electrochemical property should be ascribed to the better crystallized ...

2010-07-23

443

Stakeholder-based SWOT analysis for successful municipal solid waste management in Lucknow, India  

International Nuclear Information System (INIS)

The present investigation is a case study of Lucknow, the main metropolis in Northern India, which succumbs to a major problem of municipal solid waste and its management. A qualitative investigation using strengths, weaknesses, opportunities and threats analysis (SWOT) has been successfully implemented through this community participation study. This qualitative investigation emphasizes the limited capabilities of the municipal corporation's resources to provide proper facilitation of the municipal solid waste management (MSWM) services without community participation in Lucknow city. The SWOT analysis was performed to formulate strategic action plans for MSWM in order to mobilize and utilize the community resources on the one hand and municipal corporation's resources on the other. It has allowed the introduction of a participatory approach for better collaboration between the community and municipal corporation in Lucknow (India). With this ...

2260-01-01

444

Solid-pseudopapillary tumor of the pancreas in a 13-year-old girl - case report  

International Nuclear Information System (INIS)

The solid-pseudopapillary tumor (SPT) of the pancreas is a rare type of exocrine pancreatic neoplasm. SPT predominantly affects young women and female children, and is usually discovered incidentally. This tumor is generally benign with a low incidence of malignancy. A 13-year-old girl was admitted to the hospital with a few weeks' history of mild abdominal pain and jaundice. On physical examination, there was no palpable mass. The laboratory tests showed increased SR, CRP, high bilirubin, amylase and lipase serum levels. Ultrasound imaging revealed a solid lesion in the region of the pancreatic head. On MRI, precise tumor localization in the head of the pancreas with pancreatic duct dilatation and compression of the common bile duct were visualized. Pancreaticoduodenectomy and cholecystectomy was performed with good clinical outcome. Microscopic and immunohistochemical studies indicated that tumor cells were typical of SPT without any signs of ...

445

Solid fuels in chemical-looping combustion using a NiO-based oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

The feasibility of using three different solid fuels in chemical-looping combustion (CLC) has been investigated using NiO as oxygen carrier. A laboratory fluidized-bed reactor system for solid fuel was used, simulating a chemical-looping combustion system by exposing the sample to alternating reducing and oxidizing conditions. In each reducing phase 0.2g of fuel was added to the reactor containing 20g oxygen carrier. The experiments were performed at 970{sup o}C. Compared to previously published results with other oxygen carriers the reactivity of the used Ni-particles was considerably lower for the high-sulphur fuel and higher for the low-sulphur fuel. Much more unconverted CO was released and the fuel conversion was much slower for high-sulphur fuel such as petroleum coke, suggesting that the nickel-based oxygen carrier was deactivated by the presence of sulphur. The NiO particles also showed good reactivity with methane and a syngas mixture ...

2009-11-15

446

Recycling boosts profits and saves resources  

Energy Technology Data Exchange (ETDEWEB)

The Raywell Process Plants unit, which reclaims a wide range of organic solvents, including chlorinated hydrocarbons, is based on thin film evaporation and distillation rather than steam distillation, thus reducing the risk of contamination by water. Henry Balfour and Co.'s Pfaudler Solvent Recovery System gives 96% or better solvent recovery and produces a near-solid waste suitable for landfill disposal; like the Raywell system, it uses a mechanically wiped thin-film evaporator. Midland Oil Refineries uses sa Raywell thin-film evaporator for recovery of waste lubricating oils rather than the conventional sulfuric acid/clay treatment, thus avoiding formation of sulfuric acid sludge waste. The Henry Balfour Bioenergy anaerobic digestion system gives yields of fuel gas with 65-75% methane as high as 0.8 cu m/kg BOD; it achieves 95-98% BOD removal with no pH control or nutrient addition because it separates solids from liquid effluent and ...

1980-05-01

447

Observation of multiorder coherent Raman sidebands in solid hydrogen film  

Energy Technology Data Exchange (ETDEWEB)

We investigated the Raman coherence characteristics of a solid hydrogen film deposited on a sapphire substrate held at 5.3 K. Using Raman coherence prepared with two single-frequency pulsed lasers, we generated the multiorder coherent Raman sidebands in solid hydrogen film. The highorder Raman sidebands were obtained under strong pumping intensities (>= 230 MW/cm{sup 2}). The generated anti-Stokes(AS)-Raman sidebands extend from the ultraviolet (292 nm for the AS5 band) to the visible (565 nm for the AS1 band) region. The multiorder Raman sideband generation is found to be due to the parametric coupling of pump and coupling lasers. The frequency conversion efficiency from pumping beams to the first AS-Raman sideband shows a maximum (14 %) at a pumping intensity of 360 MW/cm{sup 2}. From an experiment that makes the multimode probe beam beat with the prepared Raman coherence, we found that the prepared Raman coherence replicates the probe ...

2004-07-15

448

Observation of multiorder coherent Raman sidebands in solid hydrogen film  

International Nuclear Information System (INIS)

We investigated the Raman coherence characteristics of a solid hydrogen film deposited on a sapphire substrate held at 5.3 K. Using Raman coherence prepared with two single-frequency pulsed lasers, we generated the multiorder coherent Raman sidebands in solid hydrogen film. The highorder Raman sidebands were obtained under strong pumping intensities (? 230 MW/cm2). The generated anti-Stokes(AS)-Raman sidebands extend from the ultraviolet (292 nm for the AS5 band) to the visible (565 nm for the AS1 band) region. The multiorder Raman sideband generation is found to be due to the parametric coupling of pump and coupling lasers. The frequency conversion efficiency from pumping beams to the first AS-Raman sideband shows a maximum (14 %) at a pumping intensity of 360 MW/cm2. From an experiment that makes the multimode probe beam beat with the prepared Raman coherence, we found that the prepared Raman coherence replicates the probe beam to its Raman ...

2004-07-01

449

Method for using fast fluidized bed dry bottom coal gasification  

Energy Technology Data Exchange (ETDEWEB)

Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at ...

1983-01-01

450

Measurement of the static magnetization of solid "3He through the ordering temperature  

International Nuclear Information System (INIS)

The static magnetization of solid "3He contained in sintered copper was measured. The results of the density on the melting curve show that below 5 mK, the magnetization M rises above the Curie-Weiss law extrapolated from high temperature. It reaches a maximum of twice as much as the Curie Weiss law value at temperature Tm, which would be somewhat below 1.25 mK if the system could be warmed up at infinitesimally slow rate. Below Tm, M decreases rapidly to 0.4 of its maximum, then appears to become independent of temperature. The previously reported decrease of specific heat below the Curie-Weiss law value in the range below 4 mK is apparently related to the increase of M in that range. At the low temperature end, apparent decrease of M is due to the fact that there is background magnetization which is out of equilibrium with the thermometer when there is solid "3He in the sample cell. It is suspected that the background signal comes primarily ...

1977-09-09

451

Lanthanum gallate and ceria composite as electrolyte for solid oxide fuel cells  

International Nuclear Information System (INIS)

The composite of doped lanthanum gallate (La_0_._9Sr_0_._1Ga_0_._8Mg_0_._2O_2_._8_5, LSGM) and doped ceria (Ce_0_._8Sm_0_._2O_1_._9, CSO) was investigated as an electrolyte for solid oxide fuel cell (SOFC). The LSGM-CSO composite was examined by X-ray diffraction (XRD) and impedance spectroscopy. It was found that the sintered LSGM-CSO composite contains mainly fluorite CeO_2 phase and a minority impurity phase, Sm_3Ga_5O_1_2. The LSGM-CSO composite electrolyte shows a small grain boundary response in the impedance spectroscopy as compared to LSGM and CSO pellets. The composite electrolyte exhibits the highest conductivity in the temperature range of 250-600 "oC, compared to LSGM and CSO. The LSGM-CSO composite can be expected to be an attractive intermediate temperature electrolyte material for solid oxide fuel cells.

2010-03-04

452

Ionic conductivity enhancement for lithium solid electrolyte; Lithium ion dodensei kotai denkaishitsu no dodensei kojo kiko no kaimei  

Energy Technology Data Exchange (ETDEWEB)

For the development of high ionic conductive solid electrolyte, LiTi2(PO4)3 (LTP), one of the promising inorganic solid electrolyte, was synthesized to investigate an effect of additional lithium salt on the ion conductivity. Lithium salt added LTP composite electrolyte sintered at 900{degree}C exhibited highest conductivity, which was two order magnitude higher than pure LTP. Effects of lithium salt addition are as follows. Conductivity of the composite electrolyte provided larger sintering temperature dependence than the pure LTP. From X-ray diffraction analysis, structures and compositions were resemble between two composite electrolytes. Byproducts except LTP provided rather low conductivity. It was suggested that melted constitution in the composite can affect the sintering improvement by the additional lithium salt at temperatures over 800 {degree}C. From the observation of ruptured surface of sintered specimens, grain growth was found ...

1996-08-01

453

Investigation of a mineral melting cupola furnace. Part II. Mathematical modeling  

Energy Technology Data Exchange (ETDEWEB)

A mathematical model of a mineral melting cupola furnace for stone wool production has been developed for improving cupola operation. The 1-D, first-engineering-principles model includes mass and heat balances for the gas phase, five solid phases, and four liquid phases. The gas and solid/liquid phases flow countercurrently. Seven chemical reactions account for the conversions of coke, iron oxide, limestone, and gaseous species. The heterogeneous reactions of coke conversion are limited by both kinetics and mass transport. Heat transfer between phases is modeled including both convection and radiation. The model predicts gas concentrations; mass flow rates; and temperature profiles of the solid, melt, and gas in the cupola, as well as heat loss to the water-cooled walls. Inputs to the model include the coke, rock, and blast air properties, the blast air amount, and the coke percentage in the charge. The unknown model ...

2003-12-24

454

Hydrothermal synthesis of semiconductive PZT solid solutions and electromechancal properties of sintered bodies. Suinetsuho ni yoru handosei PZT koyotai no gosei to shoketsutai no denki kikaiteki seishitsu  

Energy Technology Data Exchange (ETDEWEB)

Semiconductive crystalline PZT powders doped with Bi and K were synthesized by hydrothermal reaction at 200{degree}C for 48 hours. The synthesis of the crystalline powders became difficult with an increase in doped amount of Bi and K, and in Zr/(Ti+Zr) ratio. Since substantial amounts of Pb remained in solution after hydrothermal reaction, the addition of Pb in excess of 25% was necessary to obtain the stoichiometric composition of the PZT solid solution. Bi contents in the powders were identical to those in starting materials, while K contents were less than expected ones. The electromechanical properties of the sintered bodies could be precisely measured by an admittance-curve-fitting method. The electromechanical coupling factor and piezoelectric coefficient of the sintered bodies varied with the Bi content like those of specimens prepared by solid state reaction, and showed the maximum values at a given Bi content. However, the change in ...

1989-10-01

455

Heterogeneous radiolysis of HCN adsorbed on a solid surface  

International Nuclear Information System (INIS)

Hydrogen cyanide is a key molecule for chemical evolution studies because, when it is exposed to different sources of energy, it forms various compounds of biological importance. To understand the role of minerals in chemical evolution, a series of experiments was performed. First, the adsorption capacity of HCN on different surface minerals was studied; the results show that HCN is readily adsorbed onto the solids proposed (zeolite, serpentine, dolomite, and sodium montmorillonite), in particular zeolite and montmorillonite. Second, the radiolysis of HCN adsorbed on olivine (as an example of a mineral surface) was also followed; it was found that the rate of HCN decomposition by gamma irradiation is enhanced in the presence of the solid. The third series of studies show that organic material was produced in high abundance from HCN at high radiation doses. The radiolytic products included gases (CO_2, NH_4, and CO) and oligomeric materials that ...

2010-07-01

456

Equation of state of laser-shocked compressed iron; Equation d'etat du fer comprime par choc laser  

Energy Technology Data Exchange (ETDEWEB)

This thesis enters the field of highly compressed materials equation of state studies. In particular, it focuses on the case of laser shock compressed iron. This work indeed aims at getting to the conditions of the earth's core, comprising a solid inner core and a liquid outer core. The understanding of phenomena governing the core's thermodynamics and the geodynamic process requires the knowledge of iron melting line locus around the solid-liquid interface at 3.3 Mbar. Several experiments were performed to that extent. First, an absolute measurement of iron Hugoniot was obtained. Following is a study of partially released states of iron into a window material: lithium fluoride (LiF). This configuration enables direct access to compressed iron optical properties such as reflectivity and self-emission. Interface velocity measurement is dominated by compressed LiF optical properties and is used as a pressure gauge. Using a dual ...

2004-01-01

457

Effect of surface-perturbed intermolecular interaction on adsorption of simple gases on a graphitized carbon surface.  

Science.gov (United States)

In this paper, we investigate the effect of the solid surface on the fluid-fluid intermolecular potential energy. This modified fluid-fluid interaction energy due to the inducement of a solid surface is used in the grand canonical Monte Carlo (GCMC) simulation of various noble gases, nitrogen, and methane on graphitized thermal carbon black. This effect is such that the effective interaction potential energy between two particles close to surface is less than the potential energy if the solid substrate is not present. With this modification the GCMC simulation results agree extremely well with the experimental data over a wide range of pressures while the simulation results with the unmodified potential energy give rise to a shoulder near the neighborhood of monolayer coverage and the significant overprediction of the second and higher layer coverages. In particular the unmodified GCMC results exhibit very sharp change in ...

2004-08-31

458

Effect of rib height and pitch of the thermal performance of a passage disturbed by detached solid ribs  

Energy Technology Data Exchange (ETDEWEB)

Laser holographic interferometry and pressure measurements are presented for the effects of rib-to-duct height ratio (H/2B), rib pitch-to-height ratio (Pi/H), and Reynolds number (Re) on the spatially periodic-fully developed turbulent heat transfer and friction in a rectangular duct of width-to-height ratio of 4:1 with an array of ribs detached from one wall at a clearance to rib-height ratio of 0.38. The ranges of H/2B, Pi/H, and Re examined were 0.13 to 0.26, 7 to 13, and 5 {times} 10{sup 3} to 5 {times} 10{sup 4}, respectively. The difference in the H/2B dependence of the thermal performance between the detached and attached solid-rib array is documented H/2B = 0.17 and Pi/H = 10 are found to provide the best thermal performance for the range of parameters tested. Compact heat transfer and friction correlations are developed. Additionally, it is found that heat transfer augmentation with a detached solid-rib array is superior to with a ...

1998-07-01

459

Chip type aluminum solid electronic capacitor using polypyrrole. Polypyrrole wo mochiita chip gata aluminum kotai denkai condenser  

Energy Technology Data Exchange (ETDEWEB)

In the past, organic substance is generally deemed as electrical insulator, but in recent years, molecular crystals and polymers showing electroconductivity like metal were synthesized and even those showing superconductivity have appeared. These materials are called organic metals or synthetic metals and have peculiar solid state physical properties. Examples of real application of organic electroconductive materials are becoming available, but in this article, a chip type aluminum solid electrolytic capacitor using polypyrrole is introduced. There are four kinds of capacitors including ceramic capacitors and aluminum electrolytic capacitors, etc. The aluminum electrolytic capacitor is most retarded than any other type of capacitor in introducing its chip type since its use of electrolytic solution becomes an obstacle. Polypyrrole synthesized by electrolytic polymerization through anode oxidation of pyrrole has good stability and high ...

1990-07-05

460

Characterization of proton exchange membrane materials for fuel cells by solid state nuclear magnetic resonance  

Energy Technology Data Exchange (ETDEWEB)

Solid-state nuclear magnetic resonance (NMR) has been used to explore the nanometer-scale structure of Nafion, the widely used fuel cell membrane, and its composites. We have shown that solid-state NMR can characterize chemical structure and composition, domain size and morphology, internuclear distances, molecular dynamics, etc. The newly-developed water channel model of Nafion has been confirmed, and important characteristic length-scales established. Nafion-based organic and inorganic composites with special properties have also been characterized and their structures elucidated. The morphology of Nafion varies with hydration level, and is reflected in the changes in surface-to-volume (S/V) ratio of the polymer obtained by small-angle X-ray scattering (SAXS). The S/V ratios of different Nafion models have been evaluated numerically. It has been found that only the water channel model gives the measured S/V ratios in the normal hydration ...

2010-03-15

461

Assembly of Linear Nano-Chains from Iron Oxide Nanospheres with Asymmetric Surface Chemistry  

Science.gov (United States)

Besides the multifunctionality, another equally important aspect of nanoparticles is their engineerability to control the geometrical and chemical properties during fabrication. In this work, we exploited this aspect to define asymmetric surface chemistry of an iron oxide nanosphere by controlling the topology of ligand expression on its surface resulting in a particle with two faces, one displaying only amines and the other only thiols. Specifically, amine-functionalized iron oxide nanospheres were attached on a solid support via a crosslinker containing a disulfide bridge. Liberation of the nanosphere using thiolytic cleavage created thiols on the portion of the particle's surface that interacted with the solid support. Employing a solid-phase strategy and a step-by-step addition of particles, the two unique faces on the same nanosphere served as fittings to assemble them into linear nano-chains. Assembly of chains with ...

2011-01-06

462

A particulate model of solid waste incineration in a fluidized bed combining combustion and heavy metal vaporization  

Energy Technology Data Exchange (ETDEWEB)

This study aims to develop a particulate model combining solid waste particle combustion and heavy metal vaporization from burning particles during MSW incineration in a fluidized bed. The original approach for this model combines an asymptotic combustion model for the carbonaceous solid combustion and a shrinking core model to describe the heavy metal vaporization. A parametric study is presented. The global metal vaporization process is strongly influenced by temperature. Internal mass transfer controls the metal vaporization rate at low temperatures. At high temperatures, the chemical reactions associated with particle combustion control the metal vaporization rate. A comparison between the simulation results and experimental data obtained with a laboratory-scale fluid bed incinerator and Cd-spiked particles shows that the heavy metal vaporization is correctly predicted by the model. The predictions are better at higher temperatures because ...

2009-11-15

463

A Bragg curve counter with an internal production target for the measurement of the double-differential cross-section of fragment production induced by neutrons at energies of tens of MeV  

Energy Technology Data Exchange (ETDEWEB)

A Bragg curve counter equipped with an internal production target was developed for the measurements of double-differential cross-sections of fragment production induced by neutrons at energies of tens of MeV. The internal target permitted a large detection solid angle and thus the registration of processes at low production rates. In this specific geometry, the detection solid angle depends on the emission angle and the range of the particle. Therefore the energy, atomic number, and angle of trajectory of the particle have to be taken into account for the determination of the solid angle. For the selection of events with tracks confined within a defined cylindrical volume around the detector axis, a segmented anode was applied. The double-differential cross-sections for neutron-induced production of lithium, beryllium, and boron fragments from a carbon target were measured at 0 deg. for 65 MeV neutrons. The results are in ...

2009-11-11

464

Vibron and roton bands in the first overtone of solid and liquid parahydrogen  

Energy Technology Data Exchange (ETDEWEB)

The infrared spectrum of the rotovibrational band {ital v}=0{r_arrow}2 of parahydrogen has been observed in the condensed phases down to {ital T}=2 K. In the solid, phonon and roton sidebands exhibit peaks corresponding to those observed in the fundamental. Contributions arising from the reorientation of ortho-H{sub 2} impurities have been detected. The {ital Q}{sub 1}(0)+{ital S}{sub 1}(0) band has been resolved into an asymmetric doublet, and the origin of this latter is discussed. In the liquid phase the observed line shapes include strong translational contributions, and are accounted for by assuming that at short times the excited molecule is encapsulated in the cage of nearest neighbors.

1994-03-01

465

The effect of excimer laser pretreatment on diffusion and activation of boron implanted in silicon  

International Nuclear Information System (INIS)

We have investigated the effect of excimer laser annealing (ELA) on transient enhanced diffusion (TED) and activation of boron implanted in Si during subsequent rapid thermal annealing (RTA). It is observed that ELA with partial melting of the implanted region causes reduction of TED in the region that remains solid during ELA, where the diffusion length of boron is reduced by a factor of #approx#4 as compared to the as-implanted sample. This is attributed to several mechanisms such as liquid-state annealing of a fraction of the implantation induced defects, introduction of excess vacancies during ELA, and solid-state annealing of the defects beyond the maximum melting depth by the heat wave propagating into the Si wafer. The ELA pretreatment provides a substantially improved electrical activation of boron during subsequent RTA.

2005-11-07

466

Submegahertz linewidth at 240 GHz from an injection-locked free-electron laser  

International Nuclear Information System (INIS)

Radiation from an ultrastable 240 GHz solid state source has been injected, through an isolator, into the cavity of the University of California, Santa Barbara millimeter-wave free-electron laser (FEL). High-power FEL emission, normally distributed among many of the cavity's longitudinal modes, is concentrated into the single mode to which the solid state source has been tuned. The linewidth of the FEL emission is 0.5 MHz, consistent with the Fourier transform limit for the 2 #mu#s pulses. This demonstration of frequency-stable, ultranarrow-band FEL emission is a critical milestone on the road to FEL-based pulsed electron paramagnetic resonance spectroscopy.

2007-10-22

467

Status and progress in sludge washing: A pivotal pretreatment method  

Energy Technology Data Exchange (ETDEWEB)

Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and leaching operations involve batchwise mixing, settling, and ...

1995-01-01

468

Secondary ions from condensed gas solids by singly and multiply charged ion impacts  

International Nuclear Information System (INIS)

Ion desorption from a condensed gas solid Ne impacted by singly- and multiply-charged Ar"q"+ ions (q = 1-7) has been investigated. Various secondary ions such as cluster ions, Ne"+_n (n = 2-20) as well as atomic ions are observed. Mass spectral patterns, thickness dependence of the yields, and kinetic energy distributions of the desorbed Ne"+_n (n = 1,2) depend strongly on the projectile charge state. These results indicate that the dissipation of the projectile potential energy on the surface leads to the desorption of the monomer and small cluster ions by a Coulomb repulsion between adjacent target ions.

2009-11-01

469

Research on the preparation of coal water fuel (CWF) from Banko coal, south Sumatera  

Energy Technology Data Exchange (ETDEWEB)

Studies of CWF preparation at laboratory scale have been carried out using the type and amount of additives and coal content as process variables. Other factors such as particle size, time and rate of stirring were kept constant. CWF with 45 wt% of dry solids, heating value of 5,475 BTU/lb, and stable without the evidence of sedimentation for 9 weeks have been obtained using carboxy methyl cellulose (CMC) as the additive. Low coal content and low heating value can be increased by hydrothermal process on the elevated temperature and pressure. By this process, CWF with dry solid of 55 wt% and a heating value of 7,125 BTU/lb could be obtained. 6 refs., 8 figs., 2 tabs.

1994-01-01

470

Radon diffusion studies through building construction materials using solid state nuclear track detectors  

International Nuclear Information System (INIS)

Radon appears mainly by diffusion processes from the point of origin following #alpha#- decay of "2"2"6Ra in underground soil and building materials used, in the construction of floors, walls, and ceiling. The transport phenomenon of radon through diffusion is a significant contributor to indoor radon entry. In the present study radon diffusion through sand, cement, mixtures of sand + cement (1:1), sand + cement (2:1), sand + cement (3:1), sand + cement (4:1) has been carried out using LR-115 type II solid state nuclear track detectors (SSNTDs). The radon diffusion coefficient and diffusion lengths have been calculated for different materials. The effect of compaction, which changes the porosity and permeability of the materials, on radon diffusion has also been studied. (author)

2003-10-16

471

Production of titanium alloys with uniform distribution of heat resisting metals  

International Nuclear Information System (INIS)

Consideration is given to the process of the formation of a titanium sponge alloyed with niobium or tantalum, in the joint metallic reduction of titanium, niobium and tantanum chlorides. A percentage composition of the phases observed and the structure of the alloyed sponge have been studied. It is shown that after one remelting operation of the alloyed sponge the alloys of titanium with niobium and tantalum have a uniform component distribution. At the stage of chloride reduction there appear solid solutions based on titanium and an alloying component. The stage of vacuum separation of the reaction mass is associated with a mutual dissolution of the primary phases and the formation of the solid solutions of the alloyed titanium sponge, which, by their composition, are close to the desired alloy composition. The principal features of the formation of a titanium sponge alloyed with niobium and tantalum are in a perfect agreemet with those ...

472

Prediction of drug particle size and content uniformity in low-dose solid dosage forms  

British Library Electronic Table of Contents (United Kingdom)

Drug particle size distribution has a profound impact to the content uniformity in low-dose solid drug products. We derived theoretically the skewness of potency distribution as a function of particle size distribution and target dose. It was demonstrated that both skewness and coefficient of variation diverge simultaneously with inverse square root of the target dose. This scaling relation was observed in recent experiment and was verified by Monte Carlo (MC) simulation, which was employed for the first time to solve for the full potency distribution from a random retrieving model. When tested against the criteria from USP uniformity of dosage units, MC simulation showed a striking anisotropic distribution of the data. This suggests a full-scale consideration of the potency distribu...

2010-01-01

473

Phase Behavior and Interactions of the Membrane-Protein Bacteriorhodopsin  

Energy Technology Data Exchange (ETDEWEB)

We present a synchrotron x-ray diffraction study of melting in stacks of two-dimensional crystalline arrays of the membrane protein bacteriorhodopsin. Two distinct regimes have been found as a function of the intermembrane distance d . In the {open_quotes}coupled{close_quotes} regime for d{lt}250 {Angstrom} the temperature (T{sub m}) of the melting transition decreases with increasing d , demonstrating the effect of the repulsive membrane interactions on the intramembrane protein ordering. For d{gt}250 {Angstrom} a {open_quotes}decoupled{close_quotes} regime is found with higher T{sup *}{sub m} independent of d . Below T{sup *}{sub m} a solid-liquid-solid reentrant behavior is observed as d is increased. {copyright} {ital 1999} {ital The American Physical Society}

1999-04-01

474

Non-oxidative removal of hydrogen sulfide from gaseous, petrochemical, and other streams  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a method of reducing the hydrogen sulfide level in streams containing hydrogen sulfide at concentrations from about 2 ppm up to about 1,000 ppm. It comprises reacting the hydrogen sulfide with an unsaturated hydrocarbon in the presence of an acidic solid catalyst selected from the group consisting of polymeric sulfonic acid resins, solid polyphosphoric acid, supported sulfuric acid, supported boric acid, silica-aluminas, clays, faujasite, mordenite, and L, omega, X or Y zeolites at mercaptan-forming concentrations, and recovering a stream having a reduced hydrogen sulfide concentration and containing no more than 5 ppm hydrogen sulfide.

1991-07-23

475

Modeling of an Inductive Adder Kicker Pulser for a Proton Radiography System  

Energy Technology Data Exchange (ETDEWEB)

An all solid-state kicker pulser for a proton radiography system has been designed. Multiple solid-state modulators stacked in an inductive-adder configuration are utilized in this kicker pulser design. Each modulator is comprised of multiple metal-oxide-semiconductor field-effect transistors (MOSFETs) which quickly switch the energy storage capacitors across a magnetic induction core. Metglas is used as the core material to minimize loss. Voltage from each modulator is inductively added by a voltage summing stalk. A circuit model of a prototype inductive adder kicker pulser modulator has been developed to predict the performance of the pulser modulator. The modeling results are compared with experimental data.

2001-06-12

476

Measurement of the relaxation time of hot electrons in laser-solid interaction at relativistic laser intensities  

Energy Technology Data Exchange (ETDEWEB)

The authors have measured the relaxation time of hot electrons in short pulse laser-solid interactions using a picosecond time-resolved x-ray spectrometer and a time-integrated electron spectrometer. Employing laser intensities of 10{sup 17}, 10{sup 18}, and 10{sup 19} W/cm{sup 2}, they find increased laser coupling to hot electrons as the laser intensity becomes relativistic and thermalization of hot electrons at timescales on the order of 10 ps at all laser intensities. They propose a simple model based on collisional coupling and plasma expansion to describe the rapid relaxation of hot electrons. The agreement between the resulting K{sub {alpha}} time-history from this model with the experiments is best at highest laser intensity and less satisfactory at the two lower laser intensities.

2006-08-22

477

Measurement of the ratio of liquid to solid phases in a continuous ingot  

International Nuclear Information System (INIS)

A radiometric method of measuring the ratio of liquid and solid phases (crust thickness) in a continuous ingot for automation of the continuous steel casting process, has been proposed. The essence of the method is, that radiation flux, bearing information on the object tested, is transformed in a succession of electric pulses, which is processed afterwords for obtaining necessary information. In this case either the flux of non-scattered radiation, passed through the object, or the flux of single-scattered radiation reflected from the object is registered. Block-diagram and specifications of a radiometric device with the Co source of 50 gxequiv. Ra activity developed for this purpose are presented. The technique for calibration ob the device and the results of its tests, are described. It is shown, that introduction of such devices for the control crust thickness at the installations of continuous steel casting of metallurgical works would permit to exercise ...

478

Integrated coke, asphalt and jet fuel production process and apparatus  

Science.gov (United States)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

1991-01-01

479

High pressure in situ diffraction studies of metal-hydrogen systems  

British Library Electronic Table of Contents (United Kingdom)

''Hybrid'' hydrogen storage, where hydrogen is stored in both the solid material and as a high pressure gas in the void volume of the tank can improve overall system efficiency by up to 50% compared to either compressed hydrogen or solid materials alone. Thermodynamically, high equilibrium hydrogen pressures in metal-hydrogen systems correspond to low enthalpies of hydrogen absorption-desorption. This decreases the calorimetric effects of the hydride formation-decomposition processes which can assist in achieving high rates of heat exchange during hydrogen loading-removing the bottleneck in achieving low charging times and improving overall hydrogen storage efficiency of large hydrogen stores. Two systems with hydrogenation enthalpies close to -20kJ/mol H2 were studied to investigate the h...

2011-01-01

480

High power GaInP-AlGaInP quantum-well lasers grown by solid source molecular beam epitaxy  

Science.gov (United States)

AlGaInP-based quantum-well laser diodes operating at wavelengths near 680 nm have been grown by all solid source molecular beam epitaxy (SSMBE). The lowest room temperature threshold current densities obtained from shallow rid structures were 300 A/cm{sup 2} and 330 A/cm{sup 2} for pulsed and continuous wave operation, respectively. The dependences of the differential quantum efficiency and threshold current density on the cavity length were also studied in this preliminary SSMBE work. The internal quantum efficiency of 87--89% and the internal losses of 7--10 cm{sup {minus}1} were obtained.

1996-03-01

481

Fullerene-Derivatized Amino Acids: Synthesis, Characterization, Antioxidant Properties, and Solid-Phase Peptide Synthesis  

British Library Electronic Table of Contents (United Kingdom)

A series of [60]fullerene-substituted phenylalanine (Baa) and lysine derivatives have been prepared by the condensation of 1,2-(4prime-oxocyclohexano)fullerene with the appropriately protected (4-amino)phenylalanine and lysine, respectively. Conversion of the imine to the corresponding amine is achieved by di-acid catalyzed hydroboration. The reduction of the imine is not accompanied by hydroboration of the fullerene cage. The [70]fullerene phenylalanine derivative has also been prepared as have the di-amino acid derivatives. The compounds were characterized by MALDI-TOF mass spectrometry, UV/Vis spectroscopy, and cyclic voltammetry. 1H and 13C NMR spectroscopy allowed the observation of diastereomers. Fullerene-substituted peptides may be synthesized on relatively large scale by solid-pha...

2007-01-01

482

Formation of defects in epitaxial heterostructures and multicomponent solid solutions of semiconductor compounds  

International Nuclear Information System (INIS)

The authors discuss several aspects of defect formation in epitax heterostructures based on solid solutions of A"3B"5 semiconductor compounds; these heterstructures were prepared by liquid phase epitaxy by cooling suitable high-temperature solutions from the initial growth temperature. An analysis shows that the regions near heterojunctions are regions of increased defect density even in compositions based on Al /SUB x/ Ga /SUB 1-x/ As-GaAs, Al /SUB x/ Ga /SUB 1-x/ P-GaP, Al /SUB x/ Ga /SUB 1-x/ Sb-GaSb, where the differences in lattice parameters of the contacting materials are a minimum.

483

Exposure data for personal care products: Hairspray, spray perfume, liquid foundation, shampoo, body wash, and solid antiperspirant  

British Library Electronic Table of Contents (United Kingdom)

Reliable exposure information for cosmetic and other personal care products and ingredients is needed in order to conduct safety assessments. Essential information includes both the amount of product applied, and the frequency of use. To obtain current data, studies to assess consumer use practices were undertaken. Six widely used personal care product types were included in the studies. Five of the products were cosmetics (spray perfume, hairspray, liquid foundation, shampoo, body wash) and one product was a cosmetic/over-the-counter drug product (solid antiperspirant). Three hundred and sixty women, ages 19-65 years, who regularly use the products of interest, were recruited at 10 different geographical locations within the US. The number of recruits was chosen to ensure a minimum of thr...

2006-01-01

484

Evaluation of thin Pd, Pt and Ni silicides Schottky barriers for silicon solar cells. Large area uniform growth of Si layer by solid phase epitaxy (II). Final report  

Science.gov (United States)

The phase stability of silicides of Ni, Pt and Pd in contact with single crystal or amorphous silicon is examined. The presence of a particular silicide phase is identified by X-ray diffraction, and Rutherford backscattering is used to study composition. It is concluded that Pt or Pd silicides are suitable for Schottky barriers. Layers of silicon can be grown quickly by solid phase epitaxy at temperatures of 300-500C and using an intermediate metal film. Experimental results are reported. Doped layers have been obtained which have electrical characteristics suitable for the junctions in solar cells. The effects of impurities and orientation of the substrate on the growth kinetics are discussed.

485

Evaluation of CO2 adsorption capacity of solid sorbents  

British Library Electronic Table of Contents (United Kingdom)

The CO2 adsorption capacity of the low-cost solid sorbents of waste tire char (TC) and chicken waste char (CW) was compared with commercial active carbon (AC) and 5?? zeolite (ZA) using thermogravimetric analysis (TG), pressurized TG, and differential scanning calorimetry (DSC). The sorbents were degassed in a TG up to 150??C to release all gases on the surface of the sample, then cooled down to the designed temperature for adsorption. TG results indicated that the CO2 adsorption capacity of TC was higher than that of CW, but lower than those of AC and ZA. The maximum adsorption rate of TC at 50??C was 0.61% min?1, lower than that of AC, but higher than that of CW, 0.44% min?1. The maximum adsorption rate of ZA at 50??C was 3.1% min?1. When the pressure was over 4?bar, the adsorption rate ...

2011-01-01

486

Equilibrium headspace analysis of volatile flavor compounds extracted from soursop (Annona muricata) using solid-phase microextraction  

British Library Electronic Table of Contents (United Kingdom)

The influence of headspace solid-phase microextraction (HS-SPME) variables, namely, sample concentration, salt concentration and sample amount, on the equilibrium headspace analysis of the main volatile flavor compounds released from soursop was investigated. A total of 35 volatile compounds, comprising 19 esters, six alcohols, three terpenes, two acids, two aromatics, two ketones and an aldehyde, were identified. The results indicated that all response-surface models were significantly (p<0.05) fitted for 10 target volatile flavor compounds. The results further indicated that more than 65% of the variation in the equilibrium headspace concentrations of target volatile flavor compounds could be explained by the final reduced models, with high R2 values ranging from 0.658 to 0.944. Multiple...

2010-01-01

487

Environmental, scanning electron and optical microscope image analysis software for determining volume and occupied area of solid-state fermentation fungal cultures  

British Library Electronic Table of Contents (United Kingdom)

Abstract Here we propose a software for the estimation of the occupied area and volume of fungal cultures. This software was developed using a Matlab platform and allows analysis of high-definition images from optical, electronic or atomic force microscopes. In a first step, a single hypha grown on potato dextrose agar was monitored using optical microscopy to estimate the change in occupied area and volume. Weight measurements were carried out to compare them with the estimated volume, revealing a slight difference of less than 1.5%. Similarly, samples from two different solid-state fermentation cultures were analyzed using images from a scanning electron microscope (SEM) and an environmental SEM (ESEM). Occupied area and volume were calculated for both samples, and the results obtained w...

2011-01-01

488

Environmental assessment of alternative municipal solid waste management strategies. A Spanish case study  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study is to compare, from an environmental point of view, different alternatives for the management of municipal solid waste generated in the town of Castellon de la Plana (Spain). This town currently produces 207ton of waste per day and the waste management system employed today involves the collection of paper/cardboard, glass and light packaging from materials banks and of rest waste at street-side containers. The proposed alternative scenarios were based on a combination of the following elements: selective collection targets to be accomplished by the year 2015 as specified in the Spanish National Waste Plan (assuming they are reached to an extent of 50% and 100%), different collection models implemented nationally, and diverse treatments of both the separated biodegrad...

2010-01-01

489

Enhanced diffusion from interstitial trapping during solid-phase-epitaxial growth of silicon alloys. Draft  

Energy Technology Data Exchange (ETDEWEB)

During the recrystallization by solid-phase-epitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, we propose that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing.

1984-08-01

490

Enhanced diffusion from interstitial trapping during solid-phase-epitaxial growth of silicon alloys  

Energy Technology Data Exchange (ETDEWEB)

During the recrystallization by solid-phase-expitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +/- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, it is proposed that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing. 12 references, 6 figures.

1984-01-01

491

Electrode materials: a challenge for the exploitation of protonic solid oxide fuel cells  

International Nuclear Information System (INIS)

High temperature proton conductor (HTPC) oxides are attracting extensive attention as electrolyte materials alternative to oxygen-ion conductors for use in solid oxide fuel cells (SOFCs) operating at intermediate temperatures (400-700 "0C). The need to lower the operating temperature is dictated by cost reduction for SOFC pervasive use. The major stake for the deployment of this technology is the availability of electrodes able to limit polarization losses at the reduced operation temperature. This review aims to comprehensively describe the state-of-the-art anode and cathode materials that have so far been tested with HTPC oxide electrolytes, offering guidelines and possible strategies to speed up the development of protonic SOFCs. (topical review)

2010-08-01

492

Effects of sputtering pressure on the characteristics of lithium ion conductive lithium phosphorous oxynitride thin film  

British Library Electronic Table of Contents (United Kingdom)

Lithium phosphorous oxynitride(Lipon) thin films as a lithium ion conductive electrolyte were prepared by radio frequency reactive sputtering in N2 plasma. The properties of the amorphous Lipon solid electrolyte were investigated as a function of N2 pressure during reactive sputtering. The ionic conductivity and the electrochemical stability of Lipon thin films improved drastically as the N2 pressure decreased. The ionic conductivity closed to 10?6 S cm?1 and obtained a stability window of 1.0?5.0 V with an N2 pressure of 5 mTorr, where the number of nitrogen bonds between the phosphate groups were more than those formed at higher pressure. It was possible to fabricate the Li//LiCoO2 complete thin film battery using this Lipon solid electrolyte, which exhibited excellent discharge characte...

2006-01-01

493

Decontamination factor of an incinerator for radioactive solid wastes  

International Nuclear Information System (INIS)

An incinerator for the treatment of low-level radioactive solid wastes was installed in Tokai Research Establishment, JAERI, 1966. The incinerator was equipped with a scrubber, cyclone, electrostatic precipitator and HEPA filter. The retention factor (R.F.) of the furnace as well as the decontamination factors (D.F.) of each dust collector were measured using "3"2P as a tracer under various conditions. It was found that the overall D.F. of the incinerator was improved by the increase of the temperature in the furnace, decrease of the off gas flowrate, increase of the charged voltage of the electrostatic precipitator and by the increase of the liquid gas ratio of the scrubber. The overall D.F. of the incinerator (including the R.F. in the furnace) on the standard operating conditions was 9.1x10"6. (auth.).

494

Chondrocytes and bone marrow-derived mesenchymal stem cells undergoing chondrogenesis in agarose hydrogels of solid and channelled architectures respond differentially to dynamic culture conditions  

British Library Electronic Table of Contents (United Kingdom)

Abstract The objective of this study was to investigate how a combination of different scaffold architectures and rotational culture would influence the functional properties of thick cartilaginous tissues engineered using either chondrocytes or bone marrow-derived mesenchymal stem cells (BM-MSCs). Expanded porcine chondrocytes and BM-MSCs were suspended in 2% agarose and cast in custom-designed moulds to produce either regular solid or channelled construct cylinders. The study consisted of three seperate experimental arms. First, chondrocyte and BM-MSC constructs were cultured in free swelling conditions for 9 weeks. Second, constructs were subjected to rotational culture for a period of 3 weeks. Finally, BM-MSC-seeded constructs were subjected to delayed rotational culture, in which cons...

2011-01-01

495

Chemical Analysis of Solid-State Irradiated Human Insulin  

British Library Electronic Table of Contents (United Kingdom)

Purpose To study the chemical modifications induced upon irradiation of solid human insulin at radiosterilization doses and investigate the influence of the absorbed dose on radiolysis. Materials and Methods Volatile radiolytic products were monitored by gas chromatography coupled with mass spectrometry (GC-MS) and non-volatile products by two different high performance liquid chromatography (HPLC) methods: the formation of higher molecular weight proteins was assessed by size exclusion liquid chromatography whereas assays for related compounds and chemical potency tests were carried out using reverse-phase HPLC-UV. Conformational changes were investigated by measurements of circular dichroism. Results After gamma irradiation at 10?kGy, the recovery of insulin was 96.8%; higher molecular w...

2006-01-01

496

Calibration of solid state nuclear track detector CR-39 for radon measurements  

Energy Technology Data Exchange (ETDEWEB)

Solid state nuclear track detectors (SSNTD) are widely used for radon measurements and CR-39 is one of the most popular SSNTD. In this work it was determined the calibration factor for radon concentration measurements through the passive method with CR-39 detectors. The detectors were put in a proper device (an adapted Lucas cell) and exposed to the standard radon concentration through the Pylon Model RN-150 flow through radon gas source. After exposure, the detectors were etched for 5.5 hours in a KOH solution at 80 deg C in a bath at a constant temperature. The track density was read in an Axiolab-Zeiss optical microscope, with nominal magnification of X10 connected to a video camera and to a personal computer. The calibration factor was obtained through the relation between standard radon concentration, track density and exposure time. (author)

2007-07-01

497

Calibration of solid state nuclear track detector CR-39 for radon measurements  

International Nuclear Information System (INIS)

Solid state nuclear track detectors (SSNTD) are widely used for radon measurements and CR-39 is one of the most popular SSNTD. In this work it was determined the calibration factor for radon concentration measurements through the passive method with CR-39 detectors. The detectors were put in a proper device (an adapted Lucas cell) and exposed to the standard radon concentration through the Pylon Model RN-150 flow through radon gas source. After exposure, the detectors were etched for 5.5 hours in a KOH solution at 80 deg C in a bath at a constant temperature. The track density was read in an Axiolab-Zeiss optical microscope, with nominal magnification of X10 connected to a video camera and to a personal computer. The calibration factor was obtained through the relation between standard radon concentration, track density and exposure time. (author)

498

An empirical test of the environmental Kuznets curve in China: A panel cointegration approach  

British Library Electronic Table of Contents (United Kingdom)

This paper investigates the relationship between environmental pollution and economic growth in China based on the environmental Kuznets curve hypothesis, using Chinese provincial data over 1985?2005. Waste gas, waste water and solid wastes are used as environmental indicators and GDP is used as the economic indicator. It is found by panel cointegration test that there is a long-run cointegrating relationship between the per capita emission of three pollutants and the per capita GDP. According to comparisons with the dynamic OLS estimator and the Within OLS estimator, we find that panel cointegration estimation is preferable for all pollutants except for solid wastes. The results also show that all three pollutants are inverse U-shaped, and water pollution has been improved earlier than ga...

2008-01-01

499

A New Dry Flue Gas Desulfurization Process-Underfeed Circulating Spouted Bed  

Science.gov (United States)

Applying an underfeed system, the underfeed circulating spouted bed was designed as a desulfurization reactor. The main objective of the technology is to improve the mixing effect and distribution uniformity of solid particles, and therefore to advance the desulfurization efficiency and calcium utility. In this article, a series of experimental studies were conducted to investigate the fluidization behavior of the solid-gas two-phase flow in the riser. The results show that the technology can distinctly improve the distribution of gas velocity and particle flux on sections compared with the facefeed style. Analysis of pressure fluctuation signals indicates that the operation parameters have significant influence on the flow field in the reaction bed. The existence of injecting flow near the underfeed nozzle has an evident effect on strengthening the particle mixing.

2010-01-01