WorldWideScience
1

The effect of flow-hole structure and water chemistry on scale adhesion at the leading edge of a flow hole in a heat exchanger  

International Nuclear Information System (INIS)

In the heat exchangers of power plants, scale deposition may occur, especially at the leading edge of contraction. The growth of scale can lead to an increase in pressure and cause oscillation of the water level. In our previous study, the dependence of flow on contraction geometry was analyzed numerically and empirically. It was shown that the contraction ratio of hydraulic diameter of the flow path contributed greatly to the difference in pressure drop and turbulent kinetic energy at the leading edge of the flow path. In this study, the effect of contraction geometry and flow rate on scale adhesion was studied in AVT chemistry at 270degC using a high-velocity scale-adhesion test loop. The differential pressure and the amount of scale deposited due to scale adhesion at the leading edge of the flow path increased more in a quatrefoil-type flow path than in drill-type flow ...

1999-05-01

2

Augmenting Clinical Evaluation of Hemiparetic Arm Movement With a Laboratory-Based Quantitative Measurement of Kinematics as a Function of Limb Loading  

UK PubMed Central (United Kingdom)

BackgroundKinematic and kinetic measurements used in laboratory settings can quantify upper extremity movement impairment following stroke, but their relationship...Full Text Available

2008-01-01

3

Multigrid Particle-in-cell Simulations of Plasma Microturbulence  

Energy Technology Data Exchange (ETDEWEB)

A new scheme to accurately retain kinetic electron effects in particle-in-cell (PIC) simulations for the case of electrostatic drift waves is presented. The splitting scheme, which is based on exact separation between adiabatic and on adiabatic electron responses, is shown to yield more accurate linear growth rates than the standard df scheme. The linear and nonlinear elliptic problems that arise in the splitting scheme are solved using a multi-grid solver. The multi-grid particle-in-cell approach offers an attractive path, both from the physics and numerical points of view, to simulate kinetic electron dynamics in global toroidal plasmas.

2003-06-17

4

A quantitative method to detect explosives and selected semivolatiles in soil samples by Fourier transform infrared spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a novel Fourier transform infrared (FTIR) spectroscopic method that can be used to rapidly screen soil samples from potentially hazardous waste sites. Samples are heated in a thermal desorption unit and the resultant vapors are collected and analyzed in a long-path gas cell mounted in a FTIR. Laboratory analysis of a soil sample by FTIR takes approximately 10 minutes. This method has been developed to identify and quantify microgram concentrations of explosives in soil samples and is directly applicable to the detection of selected volatile organics, semivolatile organics, and pesticides.

1995-06-01

5

A dynamic approach to selectivity in heterogeneous partial oxidation  

Energy Technology Data Exchange (ETDEWEB)

Despite the rapid development of literature pertaining to fundamental (1-4) studies of oxidation catalysis, a general theory of heterogeneous selective oxidation catalysis explaining the selectivity behavior of different metal oxide systems has not yet been developed. Redox mechanisms have been widely invoked in the kinetic and mechanistic descriptions of selective oxidation reactions, suggesting a dynamic behavior of hydrocarbon and oxygen interactions with the catalyst surface. Nevertheless, most of the recent theoretical approaches of this subject matter (5-7) are essentially static in nature. Correlations are made with surface structure on the basis of crystallographic considerations with selectivity being related to the nature, number, bond-strength and nearness of oxygen atoms in the neighborhood of adsorption centers. The effect of the reaction medium on the configuration of the catalyst surface, and thus its influence on the reaction ...

1987-08-01

6

Quantifying regenerator thermal shorting; Bestimmung des thermischen Kurzschlusses von Regeneratorgeweben  

Energy Technology Data Exchange (ETDEWEB)

The regenerator of Stirling cycle machines has an relatively unknown potential for thermal shorting, because the thermal flow path within the solid of a randomly stacked wire mesh, which is defined by its 'connectivity', is unknown. Earlier publications have shown two principles of experimental techniques to quantify connectivity. One quantifies connectivity as a function of axial pressure using the electric current analogy, the other measures connectivity via the temperature gradients along a regenerator and a series-connected reference body of known conductivity. Both papers offer preliminary results of reduced usefulness related to the testing method or setup. This contribution describes a new setup and its technique, which results from the practical knowledge and experience of the first two attempts, and aims for an improved determination of connectivity of the original representative Stirling ...

2000-07-01

7

Single phase polycrystalline metastable (GaSb)/sub 1-x/Ge/sub x/ alloys from annealing of amorphous mixtures: Ion mixing effects during deposition  

International Nuclear Information System (INIS)

Low energy (<100 eV) Ar"+ ion bombardment of the growing film during the deposition of amorphous GaSb+Ge mixtures was found to affect both the transformation rate kinetics as well as the reaction path during subsequent annealing. Ion bombardment induced collisional cascades resulted in more random mixing in the growing films thus retarding the rate of the amorphous to equilibrium state phase transformation during annealing and allowing the formation of homogeneous metastable randomly oriented single phase (GaSb)/sub 1-x/Ge/sub x/ alloys. The films were approx.1.5 #mu#m thick and the average grain size in the metastable state was approx.300 A.

6180-01-01

8

Long Range Correlation in Granular Shear Flow II: Theoretical Implications  

CERN Document Server

Numerical simulations are used to test the kinetic theory constitutive relations of inertial granular shear flow. These predictions are shown to be accurate in the dilute regime, where only binary collisions are relevant, but underestimate the measured value in the dense regime, where force networks of size $\\xi$ are present. The discrepancy in the dense regime is due to non-collisional forces that we measure directly in our simulations and arise from elastic deformations of the force networks. We model the non-collisional stress by summing over all paths that elastic waves travel through force networks. This results in an analytical theory that successfully predicts the stress tensor over the entire inertial regime without any adjustable parameters.

2006-01-01

9

Quantification of antibiotic drug potency by a two-compartment radioassay of bacterial growth  

Energy Technology Data Exchange (ETDEWEB)

The two-compartment radioassay for microbial kinetics based on continuous measurement of the {sup 14}CO{sub 2} released by bacterial metabolism of 14C-labeled substrate offers a valuable approach to testing the potency of antimicrobial drugs. By using a previously validated radioassay with gram-positive and gram-negative bacteria, a group of protein synthesis inhibitors was evaluated for their effect on microbial growth kinetics. All tested drugs induced changes in both the slopes and intercepts of the growth curves. An exponential growth model was applied to quantify the drug effect on the processes of bacterial {sup 14}CO{sub 2} liberation and cell generation. The response was measured in terms of a generation rate constant. A linear dependence of the generation rate constant on the dose of spectinomycin was observed with Escherichia coli. Sigmoidal-shaped curves were found in the assays of chloramphenicol and ...

1990-06-01

10

Feynman-Wiener path integral representation for scalar advected diffusion  

Energy Technology Data Exchange (ETDEWEB)

We write a path-integral expression for the Green function of a advected scalar on a fluid flux. (author)

2000-07-01

11

Coupling of Realistic Rate Estimates with Genomics for Assessing Contaminant Attenuation and Long-Term Plume Containment - Task 4: Modeling - Final Report  

Energy Technology Data Exchange (ETDEWEB)

Trichloroethene (TCE), a common groundwater contaminant, can be degraded under certain conditions by microorganisms that occur naturally in the subsurface. TCE can be degraded under anaerobic conditions to less chlorinated compounds and ultimately into the non-chlorinated, non-hazardous end product, ethene, via anaerobic reductive dechlorination (ARD). ARD is widely recognized as a TCE degradation mechanism, and occurs in active groundwater remediation and can occur during monitored natural attenuation (MNA). MNA relies on natural processes, such as dispersion and degradation, to reduce contaminant concentrations to acceptable levels without active human intervention other than monitoring. TCE can also be biodegraded under aerobic conditions via cometabolism, in which microbial enzymes produced for other purposes fortuitously also react with TCE. In cometabolism, TCE is oxidized directly to non-hazardous products. Cometabolism as a TCE-degrading process under aerobic conditions is less ...

2005-10-31

12

A path model of factors influencing morbidity and mortality in Ontario feedlot calves.  

UK PubMed Central (United Kingdom)

The principles of path analysis and causal modelling are discussed. Path analysis was applied to three data sets to assess the relationship between group characteristics (number per group and "mixing"...Full Text Available

1986-01-01

13

Quantum Transition State Theory for proton transfer reactions in enzymes  

CERN Document Server

We consider the role of quantum effects in the transfer of hyrogen-like species in enzyme-catalysed reactions. This study is stimulated by claims that the observed magnitude and temperature dependence of kinetic isotope effects imply that quantum tunneling below the energy barrier associated with the transition state significantly enhances the reaction rate in many enzymes. We use a path integral approach which provides a general framework to understand tunneling in a quantum system which interacts with an environment at non-zero temperature. Here the quantum system is the active site of the enzyme and the environment is the surrounding protein and water. Tunneling well below the barrier only occurs for temperatures less than a temperature $T_0$ which is determined by the curvature of potential energy surface near the top of the barrier. We argue that for most enzymes this temperature is less than room temperature. For physically reasonable ...

2009-01-01

14

Energy-resolved electron particle and energy fluxes in positive column plasmas  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with electron flux densities and electron energy flux densities in positive column discharges. Recent kinetic calculations by Uhrlandt and Winkler have revealed the interesting physical phenomenon of radially inward directed energy flux densities in positive column plasmas. We have used a self-consistent positive column model, based on an accurate and highly detailed Monte Carlo code, to study this effect in more depth. The results of this study show a rather complex physical picture of electron particle and energy flux densities. Electrons with low energies usually exhibit radially outward directed particle and energy flux densities. At energies above the threshold for electronic excitation particle and energy flux densities are usually inward directed. Only close to the wall, at total energies above the wall potential energy, do these flux densities point towards the wall. The thickness of this 'wall loss region' scales with the ...

1999-11-07

15

Numerical integration of the Feynman Path Integral for radiative transport  

International Nuclear Information System (INIS)

The radiative transport problem is cast in integral form using a transport kernel. The transport kernel has an explicit representation in terms of a Feynman Path Integral over all paths between selected points in a volume. This representation is setup in detail. Numerical evaluation of this Path Integral is formulated with a Frenet-Serret based procedure for generating valid random paths, and with a numerical evaluation of the weight for each valid path. Very early sanity checks of a numerical implementation are reported. Approaches to optimization are identified. (authors)

2009-05-03

16

Analytical study on integrity of BWR reactor internal structures against water hammer under RIA conditions  

Energy Technology Data Exchange (ETDEWEB)

The integrity of the RPV head and reactor internals was assessed by means of fluid-structural analyses using a coupled method to evaluate the water hammer phenomenon arising from high burnup fuel failure under RIA conditions. The fluid viscosity effect on the water column burst as well as the complex three-dimensional flow paths caused by a core shroud and standpipes were considered in this study. The three analysis scenarios were designed to investigate the above mentioned influential factors separately. In the first scenario, a two-dimensional axisymmetric reactor vessel model without any reactor internals was modeled to assess the influence of the fluid dynamics in the NSC RIA regulatory evaluation. This model has an actual RPV geometry and can be simply separated from other influential factors in order to concentrate only on investigation of the fluid viscosity effect. In the second scenario, a two-dimensional axisymmetric reactor vessel model with major ...

2003-07-01

17

The Successive Approximation Approach for Multi-path Utility Maximization Problem  

CERN Document Server

The network utility maximization (NUM) problem for multi-path is a problem which is non-strictly convex and non-separable. Using Jensen's inequality, we approximate the NUM to a strictly convex and separable problem which can be solved efficiently by the dual decomposition method. After a series of approximations, the result of the approximation problem converges to the globally optimal solution of the original NUM. Moreover, because of the separable and dual-based natures of the proposed algorithm, we utilize the reverse engineering frameworks of the current TCPs to develop a series of multi-path TCPs which are totally compatible with current TCPs. The multi-path users using our protocols can run simultaneously with the single-path users using the current TCPs. The simulations of our Multi-path Reno on ns-2 show the compatibility and the fairness among ...

2011-01-01

18

Feynman path integral representations for wave scattering by anisotropic perturbations  

Energy Technology Data Exchange (ETDEWEB)

We write a space-time Feynman Path Integral representation for scattered wave fields from a weakly/compact supported anisotropic non-homogeneity. (author)

2007-07-01

19

Quantifying the Reactive Uptake of OH by Organic Aerosols in aContinuous Flow Stirred Tank Reactor  

Energy Technology Data Exchange (ETDEWEB)

Here we report a new method for measuring the heterogeneous chemistry of submicron organic aerosol particles using a continuous flow stirred tank reactor. This approach is designed to quantify the real time heterogeneous kinetics, using a relative rate method, under conditions of low oxidant concentration and long reaction times that more closely mimic the real atmosphere. A general analytical expression, which couples the aerosol chemistry with the flow dynamics in the chamber is developed and applied to the heterogeneous oxidation of squalane particles by hydroxyl radicals (OH) in the presence of O2. The particle phase reaction is monitored via photoionization aerosol mass spectrometry and yields a reactive uptake coefficient of 0.51+-0.10, using OH concentrations of 1-7x108 molec cdot cm-3 and reaction times of 1.5+-3 hours. This uptake coefficient is larger than that found for the reaction carried out under high OH concentrations (~;;1x1010 ...

2009-03-01

20

Fundamental Elements of Geologic C02 Sequestration in Saline Aquifers  

Energy Technology Data Exchange (ETDEWEB)

Geologic sequestration represents a promising strategy for isolating CO{sub 2} waste streams from the atmosphere. Successful implementation of this approach hinges on our ability to predict the relative effectiveness of subsurface CO{sub 2} migration and sequestration as a function of key target-formation and cap-rock properties, which will enable us to identify optimal sites and evaluate their long-term isolation performance. Quantifying this functional relationship requires a modeling capability that explicitly couples multiphase flow and kinetically controlled geochemical processes. We have developed a unique computational package that meets these criteria, and used it to model CO{sub 2} injection at Statoil's North-Sea Sleipner facility, the world's first saline-aquifer storage site. The package integrates a state-of-the-art reactive transport simulator (NUFT) with supporting geochemical software and databases (SUPCRT92). ...

2001-11-19

21

The effect of aqueous composition on diffusion coefficient in bentonite  

International Nuclear Information System (INIS)

The diffusion coefficients (De) in bentonite were measured to understand and quantify the influence of groundwater chemistry such as ionic strength and to quantify the alteration of smectite mineralogical transformations. (author)

2009-12-01

22
23

JAVA PathFinder  

Science.gov (United States)

JPF is an explicit state software model checker for Java bytecode. Today, JPF is a swiss army knife

2005-01-01

24

Products of the Benzene + O(3P) Reaction  

Science.gov (United States)

The gas-phase reaction of benzene with O(3P) is of considerable interest for modeling of aromatic oxidation, and also because there exist fundamental questions concerning the prominence of intersystem crossing in the reaction. While its overall rate constant has been studied extensively, there are still significant uncertainties in the product distribution. The reaction proceeds mainly through the addition of the O atom to benzene, forming an initial triplet diradical adduct, which can either dissociate to form the phenoxy radical and H atom, or undergo intersystem crossing onto a singlet surface, followed by a multiplicity of internal isomerizations, leading to several possible reaction products. In this work, we examined the product branching ratios of the reaction between benzene and O(3P) over the temperature range of 300 to 1000 K and pressure range of 1 to 10 Torr. The reactions were initiated by pulsed-laser photolysis of NO2 in the presence of benzene and helium buffer in a ...

2009-12-21

25

Reduction of RF-sheaths potentials by compensation or suppression of parallel RF currents on ICRF antennas  

International Nuclear Information System (INIS)

Radio frequency (RF) sheaths are suspected of limiting the performance of present-day ion cyclotron range of frequencies (ICRFs) antennas over long pulses and should be minimized in future fusion devices. Within the simplest models, RF-sheath effects are quantified by the integral VRF = ? E|| ? dl where the parallel RF field E|| is linked with the slow wave. On 'long open field lines' with large toroidal extension on both sides of the antenna it was shown that VRF is excited by parallel RF currents j|| flowing on the antenna structure. In this paper, the validity of this simple sheath theory is tested experimentally on the Tore Supra (TS) ITER-like antenna prototype (ILP), together with antenna simulation and post-processing codes developed to compute VRF. The predicted poloidal localization of high-|VRF| zones is confronted to that inferred from experimental data analysis. Surface temperature distribution on ILP front face, as well as ILP-induced modifications of ...

2010-02-01

26

STOMP Subsurface Transport Over Multiple Phases Version 1.0 Addendum: ECKEChem Equilibrium-Conservation-Kinetic Equation Chemistry and Reactive Transport  

Energy Technology Data Exchange (ETDEWEB)

Geologic sequestration is currently being practiced and scientifically evaluated as a critical component in a broad strategy, comprising new practices and technologies, for mitigating global climate change due to anthropogenic emissions of CO2. Demonstrating that geologic sequestration of CO2 is safe and effective, and gaining public acceptance of sequestration technologies are critically important in meeting these global climate change challenges. Monitored field-scale demonstrations of geologic sequestration of carbon dioxide will contribute greatly toward growing trust and confidence in the technology; however, pilot demonstrations ultimately will not be the norm for new geological sequestration deployments. Instead, scientists, engineers, regulators, and ultimately the public will rely on numerical simulations to predict the performance of geologic repositories for carbon dioxide sequestration. The U.S. Department of Energy (DOE), through the National Environmental Technology ...

2005-12-01

29

Photolabelling kinetics of ATP-ase of sarcoplasmatic reticulum by 3'-ARILAZIDO-ATP  

International Nuclear Information System (INIS)

... atp-ase azido compounds biochemical reaction kinetics endoplasmic reticulum

1984-05-02

30

Interrelationships between postpartum events, hormonal therapy, reproductive abnormalities and reproductive performance in dairy cows: a path analysis.  

UK PubMed Central (United Kingdom)

Path analysis was used to determine the interrelationships between postpartum administration of gonadotrophin releasing hormone and cloprostenol and the occurrence of reproductive disease and reproductive...Full Text Available

1985-07-01

31

Interrelationships between ambient temperature, age at calving, postpartum reproductive events and reproductive performance in dairy cows: a path analysis.  

UK PubMed Central (United Kingdom)

Path analysis was used to determine the interrelationships between ambient temperature, age at calving, postpartum reproductive events and reproductive performance in dairy cows. The data used in the...Full Text Available

1985-07-01

32

Model Checking Real Time Java Using Java PathFinder  

Science.gov (United States)

The Real Time Specification for Java (RTSJ) is an augmentation of Java for real time applications of

2005-01-01

33

Broadcast Analysis for Large Cooperative Wireless Networks  

CERN Document Server

The capability of nodes to broadcast their message to the entire wireless network when nodes employ cooperation is considered. We employ an asymptotic analysis using an extended random network setting and show that the broadcast performance strongly depends on the path loss exponent of the medium. In particular, as the size of the random network grows, the probability of broadcast in a one-dimensional network goes to zero for path loss exponents larger than one, and goes to a nonzero value for path loss exponents less than one. In two-dimensional networks, the same behavior is observed for path loss exponents above and below two, respectively.

2011-01-01

34

Multiphasic helical Computed Tomography of hepatocellular carcinoma. Evaluation after various percutaneous ablation procedures  

International Nuclear Information System (INIS)

The purpose of this paper is to report the personal experience with helical CT evaluation of hepatocellular carcinoma treated with various percutaneous interventional procedures. From December 1996 to September 1998 it were examined with helical CT 41 patients (73 nodules in all) with hepatocellular carcinoma treated with percutaneous ablation therapies: conventional ethanol injection in 18 subjects (31 nodules), one-shot ethanol injection 3 (8 nodules), radiofrequency thermal ablation in 16 (25 nodules), and combined chemo embolization and ethanol injection in 4 (9 nodules). CT performed was 4-27 days after the last session, acquiring biphasic volumetric images in 14 patients and triphasic volumetric images in 27. A second treatment with subsequent CT study was performed for 28 lesions; 15 underwent 3 serial studies and 6 underwent 4 studies. Compared with pretreatment findings, the diameter was unchanged in 62% of the nodules and increased in 38%. Morphology was unchanged in 63% of ...

1999-12-01

35

Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants  

Energy Technology Data Exchange (ETDEWEB)

The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, was re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for coal/IGCC powerplants. The new program was re-titled ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants''. This final report summarizes the work accomplished from March 1, 2003 to March 31, 2004 on the four original tasks, and the work accomplished from April 1, 2004 to July 30, 2005 on the two re-directed tasks. The program Tasks are summarized below: Task 1--IGCC Environmental Impact on high Temperature Materials: The first task was refocused to address IGCC environmental impacts on high temperature materials used in gas turbines. This task ...

2005-12-01

36

Coal liquefaction research, October 1, 1978-September 30, 1981. [Comparison between fixed bed and slurry type reactors  

Energy Technology Data Exchange (ETDEWEB)

Progress reports are presented for the following two areas: catalytic cracking studies with water-wet silica-alumina catalysts; and Fischer-Tropsch reactor studies where similarities and differences between fixed bed and slurry type reactors are investigated and further experiments conducted to measure mass transfer coefficients and reaction kinetics which are to be used in a model slurry reactor. The following are some of the conclusions. (1) The premise that the presence of liquid water might increase catalytic cracking activity was found to be invalid. It was demonstrated that cracking can occur at previously unobserved low temperatures (though at low conversions) and that an anomaly exists in that one of the catalysts tested shows an entirely different cracking behavior and probably follows a different cracking mechanism. (2) the diameter of a fixed-bed Fischer-Tropsch reactor critically affected the resistance of the reactor to plugging caused by the build up ...

1981-09-01

38

Effects of timber extraction on herb diversity in the Little Tennessee watershed.  

Science.gov (United States)

... study is to collect data in previously harvested timber stands to quantify the differences in herbaceous diversity ... ...

39

Patterns of proliferation related to vasculature in human head-and-neck carcinomas before and after transplantation in nude mice  

International Nuclear Information System (INIS)

Purpose: The predictive potential of tumor cell kinetic parameters may be improved when they are studied in relation to other microenvironmental parameters. The purpose of this investigation was to quantitatively categorize human tumor samples according to proliferation patterns. Second, it was examined whether these characteristics are retained after xenotransplantation. Methods and Materials: Fifty tumor samples from head-and-neck cancer patients were immunohistochemically stained for Ki-67 and vessels. Also, parts of the samples were transplanted into nude mice. Tumors were categorized according to previously described patterns of proliferation. Vascular and proliferation patterns were analyzed using an image processing system. Results: The 50 tumors were categorized into four patterns of proliferation by visual assessment: marginal (6), intermediate (10), random (21), and mixed (12). One tumor could not be classified. These patterns were ...

2001-12-01

40

Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine  

Energy Technology Data Exchange (ETDEWEB)

This paper presents thermodynamic and kinetic data collected for aqueous blends of piperazine (PZ), an ethylamine, and potassium carbonate (K{sub 2}CO{sub 3}). Mixtures of K{sup +} and PZ have been investigated in a wetted-wall column at 40 to 80{sup o}C, typical conditions for an industrial absorber. The addition of 0.6 m PZ to 20 wt% (3.6 m) K{sub 2}CO{sub 3} increases the rate of CO{sub 2} absorption by a factor of ten from the value in unpromoted solutions at 60{sup o}C. The addition of PZ increases the heat of absorption from 4 kcal/mol in 3.6 m K{sup +} to 10 kcal/mol when 0.6 m PZ is added. The capacity, ranging from 0.4 to 0.7 mol-CO{sub 2}/kg-H{sub 2}O, approaches that of monoethanolamine (MEA) solutions and seems to be a strong function of K{sup +} concentration. Speciation of the solution was obtained using proton nuclear magnetic reasonance (NMR), verifying and quantifying the presence of three PZ species. An equilibrium model and a ...

2003-07-01

41

Path integrals in quantum physics. Lectures given at ETH Zurich during summer semester 1997; Pfadintegrale in der Quantenphysik. Vorlesung im Sommersemester 1997 an der ETH Zuerich  

Energy Technology Data Exchange (ETDEWEB)

This lectures aim at giving graduate students an introduction to a working knowledge of path integral methods in a wide variety of fields in physics. Consequently, the the lecture notes are organized in three main parts dealing with non-relativistic quantum mechanics, many-body physics and field theory. In the first part the basic concepts of path integrals are developed in the usual heuristic, non-mathematical way followed by the standard examples of quadratic Lagrangians for which the path integrals can be solved exactly. Applications include semi-classical expansions, scattering problems and the representation of Green functions as path integrals. In the last chapter of this part it is shown how (euclidean) path integrals can be treated numerically by Monte-Carlo methods with a program for the anharmonic oscillator as an explicit example. The second part deals with the ...

1997-12-01

42

Path integral of the hydrogen atom, Jacobi's principle of least action and one-dimensional quantum gravity  

International Nuclear Information System (INIS)

A path integral evaluation of the Green's function for the hydrogen atom initiated by Duru and Kleinert is studied by recognizing it as a special case of the general treatment of the separable Hamiltonian of Liouville type. The basic dynamical principle involved is identified as Jacobi's principle of least action for given energy which is reparametrization invariant, and thus the appearance of a gauge freedom is naturally understood. The separation of variables in the operator formalism corresponds to a choice of gauge in the path integral, and the Green's function is shown to be gauge independent if the operator ordering is properly taken into account. Unlike the conventional Feynman path integral, which deals with a space-time picture of particle motion, the path integral on the basis of Jacobi's principle sums over orbits in space. We illustrate these properties by evaluating an exact ...

43

Acousto-optic multiplexing and demultiplexing  

Energy Technology Data Exchange (ETDEWEB)

A system is claimed for multiplexing or demultiplexing pulsed laser radiation having an acousto-optical device which is electrically controlled to switch a common path of high pulse rate laser radiation between a plurality of spatially distinct paths for relatively lower pulse rate laser radiation at which the pulses are sequenced according to a predetermined time pattern. The acousto-optical element typically includes a Bragg cell which is electrically driven by a set of distinct frequencies, causing deflection of radiation passing therethrough at a predetermined set of angles whereby pulsed radiation on a single path may be distributed onto the plural separate paths or radiation on plural separate paths of time-sequenced pulses of radiation can be combined into a single path of augmented pulse rate. The control of the acousto-optical element may be provided by ...

1980-06-03

44

Solar thermal production of zinc: Program strategy  

Energy Technology Data Exchange (ETDEWEB)

The solar thermal production of zinc is considered for the conversion of solar energy into storable and transportable chemical fuels. The ultimate objective is to develop a technically and economically viable technology that can produce solar zinc. The program strategy for achieving such a goal involves research on two paths: a direct path via the solar thermal splitting of ZnO in the absence of fossil fuels, and an indirect path via the solar carbothermal/CH{sub 4}-thermal reduction of Zn O, with fossil fuels (coke or natural gas) as chemical reducing agents. Both paths make use of concentrated solar energy for high-temperature process heat. The direct path brings us to the complete substitution of fossil fuels with solar fuels for a sustainable energy supply system. The indirect path creates a link between today`s fossil-fuel-based technology and tomorrow`s ...

1999-08-01

45

Medium voltage analytical electron microscopy microanalysis versus radiation damage  

Energy Technology Data Exchange (ETDEWEB)

The kinetic energy transferred to some elements by an electron of kinetic energy 100 to 400 kV is discussed. The displacement rates are compared to the signal generation. (DCL)

1985-09-01

46

Kinetic energy dependence of the reactions of N"+ ions with NO, CO, CO_2, N_2O and SO_2  

International Nuclear Information System (INIS)

... kinetics chemical reactions energy dependence ion-molecule collisions milli

1977-07-01

47

A Hybrid Kinetic Model of Asymmetric Thin Current Sheets ...  

Science.gov (United States)

... Accession Number : ADA539720. Title : A Hybrid Kinetic Model of Asymmetric Thin Current Sheets with Sheared Flows in a Collisionless Plasma. ...

2010-12-27

48

Gravitational Waves and the Sagnac Effect  

CERN Document Server

We consider light waves propagating clockwise and other light waves propagating counterclockwise around a closed path in a plane (theoretically with the help of stationary mirrors). The time difference between the two light propagating path orientations constitutes the Sagnac effect. The general relativistic expression for the Sagnac effect is discussed. It is shown that a gravitational wave incident to the light beams at an arbitrary angle will not induce a Sagnac effect so long as the wave length of the weak gravitational wave is long on the length scale of the closed light beam paths. The gravitational wave induced Sagnac effect is thereby null.

2003-01-01

50

Range-resolved gas concentration measurements using tunable semiconductor lasers  

British Library Electronic Table of Contents (United Kingdom)

A method for range-resolved gas sensing using path-integrated optical systems is presented. The method involves dividing an absorption path into several measurement segments and extracting the gas concentration in each segment from two path-integrated measurements. We implemented the method with tunable lasers (a 1389-nm VCSEL and a 10.9-?m pulsed quantum cascade laser) and a group of retro reflectors (RRs) distributed along absorption paths. Using a rotating mirror with the VCSEL configuration, we could scan a group of seven tape RRs spaced by 10?cm in ??9?ms to extract an H2O concentration profile. Reduced H2O concentrations were recorded in the segments purged with dry air. Hollow corner cube RRs were used in the quantum cascade laser configuration at distances up to 1.1?km from the las...

2008-01-01

51

Limiting factors and landscape connectivity: the American marten in the Rocky Mountains  

British Library Electronic Table of Contents (United Kingdom)

In mobile animals, movement behavior can maximize fitness by optimizing access to critical resources and minimizing risk of predation. We sought to evaluate several hypotheses regarding the effects of landscape structure on American marten foraging path selection in a landscape experiencing forest perforation by patchcut logging. We hypothesized that in the uncut pre-treatment landscape marten would choose foraging paths to maximize access to cover types that support the highest density of prey. In contrast, in the post-treatment landscapes we hypothesized marten would choose paths primarily to avoid crossing openings, and that this would limit their ability to optimally select paths to maximize foraging success. Our limiting factor analysis shows that different resistant models may be sup...

2011-01-01

52

LHC magnet alignment  

CERN Document Server

Checks are performed on the alignment of the magnets in the LHC tunnel. It is vital that each magnet is placed exactly where it has been designed so that the path of the beam is precisely controlled.

2007-01-01

53

Effect of Stress and Strain Path on Cavity Closure During Hot ...  

Science.gov (United States)

... CLOSURE DURING HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY (PREPRINT) ... HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY ...

2007-07-01

54

Quantifying Risk Factors for Human Brucellosis in Rural Northern Tanzania  

UK PubMed Central (United Kingdom)

BackgroundBrucellosis is a zoonosis of veterinary, public health and economic significance in most developing countries. Human brucellosis is a severely debilitating disease that...Full Text Available

55

Particle-Gas Dynamics and Primary Accretion - Space Science and ...  

Science.gov (United States)

the revealed stage of T Tauri star evolution, is only a mere shadow of its former self. Once primary accretion starts, one has the (poorly quantified) ...

56

In vivo range of motion of the lumbar spinous processes  

UK PubMed Central (United Kingdom)

The study design included an in vivo laboratory study. The objective of the study is to quantify the kinematics of the lumbar spinous processes in asymptomatic patients during un-restricted functional...Full Text Available

2009-09-01

57

A Caution Against Interpreting and Quantifying Oyster Habitat Loss from Historical Surveys  

Science.gov (United States)

... surveys, and increasing interest in both developing an oyster aquaculture industry and scaling up restoration efforts by federal, ... ...

58

Transfer of lead through the rats intestinal wall  

International Nuclear Information System (INIS)

... females in vitro intestines lead 203 mucous membranes radionuclide kinetics

59

Contribution to the radiation preparation of wood-plastic materials Pt. 3  

International Nuclear Information System (INIS)

... compounds plants radiation effects radioisotopes reaction kinetics trees

1974-01-01

61

Unified interpretation for second-order subwavelength interference based on Feynman's path-integral theory  

International Nuclear Information System (INIS)

The second-order spatial subwavelength interference pattern is observed in a modified Michelson interferometer with single-mode continuous-wave laser beams. By analyzing our subwavelength interference experiment based on Feynman's path integral theory, a unified interpretation for all the second-order subwavelength interference is suggested.

2010-07-01

62

Learning Online Social Support: An Investigation of Network Information Technology Based on UTAUT  

British Library Electronic Table of Contents (United Kingdom)

ABSTRACT Extending the unified theory of acceptance and use of technology (UTAUT) model, this study postulates a model of online social support. The model is empirically tested using data from undergraduates in Taiwan regarding their usage of instant messaging (IM). The test results indicate that all model paths are significant, except that the path between online social support and facilitating conditions is insignificant. This study offers limitations and implications.

2008-01-01

63

Monte Carlo verification of point kinetics for safety analysis of nuclear reactors  

Energy Technology Data Exchange (ETDEWEB)

Monte Carlo neutron transport methods can be used to verify the applicability of point kinetics for safety analysis of nuclear reactors. KENO-NR was used to obtain the transfer function of the Advanced Neutron Source reactor and the time delay between the core power production and the external detectors, a parameter of interest to the safety systems design. The good agreement between the Monte Carlo generated transfer function and the point kinetics transfer function validates that the uncommon ANS geometry does not preclude the use of point kinetics in the frequency range that was investigated. Various features of the power spectral densities also demonstrated the applicability of point kinetics. The time delay was obtained from the cross-power spectral density (CPSD) and is {approximately}15 ms. These analyses show that frequency analysis can be used experimentally to investigate the validity of the ...

1995-06-01

64

Spin injection in quantum wells with spatially dependent rashba interaction  

Energy Technology Data Exchange (ETDEWEB)

We consider Rashba spin-orbit effects on spin transport driven by an electric field in semiconductor quantum wells. We derive spin diffusion equations that are valid when the mean free path and the Rashba spin-orbit interaction vary on length scales larger than the mean free path in the weak spin-orbit coupling limit. From these general diffusion equations, we derive boundary conditions between regions of different spin-orbit couplings. We show that spin injection is feasible when the electric field is perpendicular to the boundary between two regions. When the electric field is parallel to the boundary, spin injection only occurs when the mean free path changes within the boundary, in agreement with the recent work by Tserkovnyak et al (Preprint cond-mat/0610190)

2007-09-15

65

Parenteral Glucose and Glucose Control in the Critically Ill: A Kinetic Appraisal  

UK PubMed Central (United Kingdom)

BackgroundWe investigated the influence of parenteral glucose infusion on insulin-driven tight glucose control (4.4–6.1 mmol/liter) in the critically ill by appraising kinetic...Full Text Available

66

Multiple-Bond Kinetics from Single-Molecule Pulling Experiments: Evidence for Multiple NCAM Bonds  

UK PubMed Central (United Kingdom)

The kinetic parameters of single bonds between neural cell adhesion molecules were determined from atomic force microscope measurements of the forced dissociation of the homophilic protein-protein bonds....Full Text Available

2005-11-01

67

Maximum proton kinetic energy and patient-generated neutron fluence considerations in proton beam arc delivery radiation therapy  

UK PubMed Central (United Kingdom)

Several compact proton accelerator systems for use in proton therapy have recently been proposed. Of paramount importance to the development of such an accelerator system is the maximum kinetic energy...Full Text Available

2009-02-01

68

Kinetics of chlorinated hydrocarbon degradation by Methylosinus trichosporium OB3b and toxicity of trichloroethylene.  

UK PubMed Central (United Kingdom)

The kinetics of the degradation of trichloroethylene (TCE) and seven other chlorinated aliphatic hydrocarbons by Methylosinus trichosporium OB3b were studied. All experiments were performed with cells...Full Text Available

1991-01-01

69

Kinetic Properties of Pyrophosphate:Fructose-6-Phosphate Phosphotransferase from Germinating Castor Bean Endosperm 1  

UK PubMed Central (United Kingdom)

Pyrophosphate:fructose-6-phosphate phosphotransferase (PFP) was purified over 500-cold from endosperm of germinating castor bean (Ricinus commiunis L. var. Hale). The kinetic properties...Full Text Available

1984-02-01

70

Kinetic Complexity of the Global Response to Glucocorticoid Receptor Action  

UK PubMed Central (United Kingdom)

We have characterized the kinetic response of gene targets throughout the murine genome to transcriptional modulation by the glucocorticoid receptor (GR). In contrast to a model in which multiple genes...Full Text Available

2009-04-01

71

Immunoglobulins in myasthenia gravis. Kinetic properties of the acetylcholine-receptor antibody studied during lymph drainage.  

UK PubMed Central (United Kingdom)

A specific immunoglobulin, the receptor antibody, can be found in most patients with myasthenia gravis. In order to study the kinetic properties of this antibody, serial determinations of receptor antibody,...Full Text Available

1978-10-01

72

Force-dependent chemical kinetics of disulfide bond reduction observed with single-molecule techniques  

UK PubMed Central (United Kingdom)

The mechanism by which mechanical force regulates the kinetics of a chemical reaction is unknown. Here, we use single-molecule force–clamp spectroscopy and protein engineering to study the effect...Full Text Available

2006-05-09

73

Fibroblast cell population kinetics in the mouse molar periodontal ligament and tooth eruption.  

UK PubMed Central (United Kingdom)

Fibroblast cell population kinetics in the developing molar periodontal ligament was investigated in 10, 12, 16 and 20 days old mice by autoradiography after the administration of [3H]thymidine. Labelled...Full Text Available

1981-09-01

74

Determination of antibody response to influenza virus surface glycoproteins by kinetic enzyme-linked immunosorbent assay.  

UK PubMed Central (United Kingdom)

We modified an existing enzyme-linked immunosorbent assay (ELISA) to be able to use new spectrophotometers which can measure the rate of color development in microtiter wells. This new kinetic-based...Full Text Available

1988-10-01

75

A prospective, randomized clinical trial comparing bipolar plasma kinetic resection of the prostate versus conventional monopolar transurethral resection of the prostate in the treatment of benign prostatic hyperplasia  

UK PubMed Central (United Kingdom)

BACKGROUND AND OBJECTIVE:For treatment of benign prostatic hyperplasia (BPH), Plasma Kinetic loop Resection of the Prostate (PKRP) is an alternative to conventional monopolar...Full Text Available

2009-11-01

76

A model for the kinetics of homotypic cellular aggregation under static conditions.  

UK PubMed Central (United Kingdom)

We present the formulation and testing of a mathematical model for the kinetics of homotypic cellular aggregation. The model considers cellular aggregation under no-flow conditions as a two-step process....Full Text Available

1997-01-01

77

Environmental trace gas analysis by proton-transfer-reaction mass spectrometry (PTR-MS)  

International Nuclear Information System (INIS)

The work presented here demonstrates the ability of proton-transfer-reaction mass spectrometry (PTR-MS) to perform fast-response measurements of volatile organic compounds (VOCs) (including methanol, acetonitrile, acetaldehyde, acetone, PAN-type compounds, alpha- and beta-pinene, nopinone and pinonaldehyde) at the pptv level and its versatile applicability in the field of environmental trace gas analysis. Laboratory and field experiments including various calibration techniques and intercomparisons with other measurement techniques such as gas chromatography, atmospheric pressure chemical ionization and Fourier transformation infrared spectroscopy were performed providing a first characterization of the PTR-MS instrument performance (sensitivity, detection limit, precision, accuracy). Typically a detection limit (S/N=2) of 50 pptv for a 10 s signal integration time, a precision of 5 % and an accuracy in the range between 10 and 25 % were observed. Due to its compactness and ruggedness ...

78

Electro-volatilization of ruthenium in nitric medium: influences of ruthenium species nature and models solutions composition; Electro-volatilisation du ruthenium en milieu nitrique: influence de la nature des formes chimiques du ruthenium et de la composition des solutions modeles de dissolution  

Energy Technology Data Exchange (ETDEWEB)

Ruthenium is one of the fission products in the reprocessing of irradiated fuels that requires a specific processing management. Its elimination, upstream by the PUREX process, has been considered. A process, called electro-volatilization, which take advantage of the RuO{sub 4} volatility, has been optimised in the present study. It consists in a continuous electrolysis of ruthenium solutions in order to generate RuO{sub 4} species that is volatilized and easily trapped. This process goes to satisfying ruthenium elimination yields with RuNO(NO{sub 3}){sub 3}(H{sub 2}O){sub 2} synthetic solutions but not with fuel dissolution solutions. Consequently, this work consisted in the speciation studies of dissolved ruthenium species were carried out by simulating fuel solutions produced by hot acid attack of several ruthenium compounds (Ru(0), RuO{sub 2},xH{sub 2}O, polymetallic alloy). In parallel with dissolution kinetic studies, the determination of dissolved species ...

2004-12-15

79

Safety calculation for an underground repository for radioactive waste: the first objective of the alliances calculation software platform  

International Nuclear Information System (INIS)

The aim of the safety calculation is to quantify through numerical modelling the radiological impact (molar flow, human dose) of a potential repository for radioactive waste on the Meuse/Haute Marne site at Bure. A selection process is underway for safety scenarios and their phenomenological and numerical conceptual models upstream from the safety calculation. This involves defining and quantifying the geometric and dimensional representations of the repository for each scenario plus the physical, mathematical and numerical models that reflect its behaviour and the uncertainties associated with all the parameters required to quantify the impact. A summary will be given of these various aspects. The numerical simulations are then performed on the Alliances platform which integrates the various computer codes required for the physical representation of the system. (authors)

2005-03-14

80

Efficient methodologies for sensitive HIV-1 RNA quantitation from plasma and vaginal secretions  

British Library Electronic Table of Contents (United Kingdom)

Background: Quantifying HIV levels in mucosal secretions is essential to study compartmentalized expression of HIV and facilitate development of intervention strategies to prevent disease progression and transmission. Objectives: To develop a sensitive, reliable, and cost-effective technique to quantify HIV from blood and vaginal secretions that is compatible with efficient implementation in clinical research environments. Study design: A sensitive, reliable, internally-controlled real-time reverse transcriptase (RT) PCR assay, which uses the HIV-1 pol gene as a target (Hpol assay) was developed to quantify HIV levels in plasma and genital secretions, and compared to the widely used Roche Amplicor(TM) HIV-1 Monitor assay. In addition, a simplified method of sample collection and processing...

2009-01-01

81

Characterization and uncertainty analysis of VOCs emissions from industrial wastewater treatment plants  

British Library Electronic Table of Contents (United Kingdom)

Air toxics from the industrial wastewater treatment plants (IWTPs) impose serious health concerns on its surrounding residential neighborhoods. To address such health concerns, one of the key challenges is to quantify the air emissions from the IWTPs. The objective here is to characterize the air emissions from the IWTPs and quantify its associated uncertainty. An IWTP receiving the wastewaters from an airplane maintenance facility is used for illustration with focus on the quantification of air emissions for benzyl alcohol, phenol, methylene chloride, 2-butanone, and acetone. Two general fate models, i.e., WATER9 and TOXCHEM+V3.0 were used to model the IWTP and quantify the air emissions. Monte Carlo and Bootstrap simulation were used for uncertainty analysis. On average, air emissions fr...

2010-01-01

82

The effect of oxide inclusions on the kinetics of the austenite to ferrite transformation in low alloy steel weld metal  

Energy Technology Data Exchange (ETDEWEB)

Isothermal transformation kinetics of austenite to acicular ferrite and allotriomorphic ferrite were measured in reheated low alloy steel weld deposits with similar weld compositions and austenite grain size but different inclusion characteristics. Accelerated kinetics of transformation to acicular ferrite were observed in weld metal containing coarser and titanium-rich inclusions. In contrast, kinetics of transformation to allotriomorphic ferrite were not influenced by inclusion characteristics, but, rather, by the austenite grain size and carbon concentration.

1994-09-01

84

Kinetics of reduction of iron oxides using microwaves as power source  

Energy Technology Data Exchange (ETDEWEB)

This work deals with kinetic description of carbothermic reduction of iron oxides using microwaves as power source. Previous researches show that it is possible to conduct this kind of process successfully, but real kinetic comparisons between conventional and microwaves procedure have been presented partially. The aim of this work is to describe reduction kinetics, taking into account how the iron oxide is reduced by microwaves compared with conventional energy supply. In this study the authors used iron ore in pellet shape and dust. They found that both, pellet and dust reduction stops when it reaches approximately 40%, even at whole power.

1996-12-31

85

Kinetic Roughening and Energetics of Tetragonal Lysozyme Crystal Growth  

Science.gov (United States)

Lysozyme crystal growth rates over 5 orders of magnitude in range can be described using a

2003-01-01

86

Dialysis kinetics of motor oil additives  

Energy Technology Data Exchange (ETDEWEB)

Studies dialysis kinetics of zinc dialkyldithiophosphates, detergent-dispersing agents, alkyl-phenols and base oils. It was established that diffusion kinetics of oil hydrocarbons through membrane of individual compounds and narrow fractions is described by Brinzinger's formula, which is identical to the kinetic reaction formula of the 1st order. It was shown that dialysis can be utilized to determine the content of the ''active substance'' only in sulphonate and alkylsalycilate additives. Increasing temperature from 20 to 40/sup 0/ results in an increased dialysis constant for all studied products by 1.4-1.9 times.

1982-01-01

87

Physical Basis for the Lg/P Discriminant: General Properties and Preliminary Modeling.  

Science.gov (United States)

A critical problem for reliable implementation of regional discrimination is incomplete understanding of how regional seismic signals depend on physical characteristics of the source and propagation path to the recording station. This research is directed...

1997-01-01

88

Numerical simulations of quantized Bianchi type IX cosmological models  

International Nuclear Information System (INIS)

This paper reports on Monte Carlo path integral simulations of a Bianchi Type IX cosmology which yield a wave function which reflects the known chaotic dynamics of the classical system and predicts a significant probability for a correlation between large universe volume and large anisotropy.

1988-08-08

89

Integrated interpretation of AE clusters and fracture system in Hijiori HDR artificial reservoir; Hijiori koon gantai jinko choryuso no AE cluster to kiretsu system ni kansuru togoteki kaishaku  

Energy Technology Data Exchange (ETDEWEB)

With regard to a fracture system in the Hijiori hot dry rock artificial reservoir, an attempt was made on an interpretation which integrates different data. Major factors that characterize development and performance of an artificial reservoir are composed of a fracture system in rocks, which acts as circulating water paths, a heat exchange face and a reservoir space. The system relates not only with crack density distribution, but also with cracks activated by water pressure fracturing, cracks generating acoustic emission (AE), and cracks working as major flow paths, all of which are characterized by having respective behaviors and roles. Characteristics are shown on AE cluster distribution, crack distribution, production zone and estimated stress fields. Mutual relationship among these elements was discussed based on the Coulomb`s theory. The most important paths are characterized by distribution of slippery cracks. ...

1997-05-27

90

Information-seeking behavior of women in their path to an innovative alternate treatment for symptomatic uterine fibroids  

UK PubMed Central (United Kingdom)

Objectives: The purpose of the study was to discover how women found out about uterine fibroid embolization (UFE) for the treatment of symptomatic uterine fibroids.Methods:...Full Text Available

2007-04-01

91

Heat Transfer Augmentation in a Compact Heat Exchange Pedestal Array.  

Science.gov (United States)

A compact heat exchanger pedestal array for augmenting heat transfer in a machine is disclosed. The compact heat exchanger pedestal array includes a wall having first and second surfaces. The first surface faces a heated flow path and the second surface p...

2004-01-01

92

ELECTRONIC COMPONENT COOLING ALTERNATIVES: COMPRESSED AIR AND LIQUID NITROGEN  

Science.gov (United States)

The goal of this study was to evaluate topics used to troubleshoot circuit boards with known or suspected thermally intermittent components. Failure modes for thermally intermittent components are typically mechanical defects, such as cracks in solder paths or joints, or broken b...

93

Dissociation dynamics of methylal  

Energy Technology Data Exchange (ETDEWEB)

The dissociation of methylal is investigated using mass spectrometry, combined with a pyrolytic radical source and femtosecond pump probe experiments. Based on preliminary results two reaction paths of methylal dissociation are proposed and discussed. (author) 4 fig., 3 refs.

1999-08-01

94

An analytic representation of the radial distribution of dose from energetic heavy ions in water, Si, LiF, and NaI  

International Nuclear Information System (INIS)

An earlier representation of the radial distribution of dose about the path of a heavy ion in liquid water is modified and extended to include silicon, lithium fluoride, and sodium iodide. 6 refs., 5 figs., 1 tab.

1989-09-01

95

Activity-Local Symbolic State Graph Generation for High-Level ...  

Science.gov (United States)

... ie on all paths from the root to a terminal node we ... (A) A stochastic Petri net ... Tandem Queueing Network [HMKS99] 63 26 19 173 2.297e4 7.148e ...

2005-09-01

96

A Research Agenda for Malaria Eradication: Drugs  

UK PubMed Central (United Kingdom)

Antimalarial drugs will be essential tools at all stages of malaria elimination along the path towards eradication, including the early control or “attack” phase to drive down transmission...Full Text Available

2011-01-01

97

Solvent effects on the solvation shell exchange kinetics  

Energy Technology Data Exchange (ETDEWEB)

Classical molecular dynamics simulations are carried out to investigate the salvation shell exchange kinetics of potassium ion in bulk water, chloroform, and carbon tetrachloride. The reactive flux method is used to compute the dissociation rates. The influence of the solvent on the reaction rates and kinetic properties of this exchange process will be discussed. Comparison will be also be made to the prediction of the Grote-Hynes theory.

1997-12-31

98

Relativistic kinetics of baryon production in the big bang  

Energy Technology Data Exchange (ETDEWEB)

The baryogenesis process in the early hot universe is investigated by means of relativistic kinetic theory. An exact solution to the kinetic equations for supermassive bosons serves to refine previous results: the optimum baryon-production domain is now complemented by bosons of low mass, thus removing the cosmological lower bound that had limited the mass of superheavy bosons. 14 references.

1985-08-01

99

Kinetics of low-temperature radiation hardening of metallic materials under irradiation  

British Library Electronic Table of Contents (United Kingdom)

A formula is obtained which describes the kinetics of low-temperature radiation hardening caused by creation of dislocation loops of interstitial type during irradiation. The radiation hardening of aluminum and vanadium is estimated using this formula and results of experiments on studying processes of nucleation and growth of interstitial dislocation loops in these materials by transparent electron microscopy. It is shown that the proposed formula is valid for description of the kinetics of low-temperature radiation hardening.

2011-01-01

100

Kinetics of lead retention and distribution in suckling and adult rats  

International Nuclear Information System (INIS)

The kinetics of lead distribution was studied in suckling and adult rats 8 days after a single intraperitoneal injection of "2"0"3Pb. Marked differences were observed in the kinetics of lead retention and distribution in suckling as compared to adult rats. The rate of "2"0"3Pb disappearance was lower in the whole body, blood and kidneys, but higher in the liver, while the deposition processes predominated in the brain, femur and teeth of sucklings as compared to adult animals. (auth).

101

Kinetics of chlorination of phosphates of actinides and fission elements in chloride melts. II. Zirconium phosphates  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the reaction of zirconium phosphates with carbon tetrachloride in sodium and potassium chloride melt as well as the effect of temperature, gas flow, solubility and weight of the solid phase of the phosphate, and stirring of the melt on the chlorination rate has been studied. The kinetic parameters of the reaction (rate constants, activation energy, etc.) have been calculated.

1987-07-01

102

Investigation of dissolution kinetics of tungsten minerals in hydrochloric acid solutions of citric acid  

Energy Technology Data Exchange (ETDEWEB)

Thermodynamic analysis of dissolution processes of tungsten minerals in citric acid solutions in the absence and in the presence of hydrochloric acid has been carried out by means of calculation of Gibbs energy of the chemical reactions. Kinetic characteristics, such as specific dissolution rates and activation energies, are determined. It is established that the dissolution reactions studied take place in kinetic region. A possibility of scheelite selective dissolution in the presence of other tungsten minerals is shown.

1985-03-01

103

Determination of reactor kinetic parameters in a two-core reactor  

Energy Technology Data Exchange (ETDEWEB)

The kinetic parameters, ..cap alpha.. the coupling coefficient and tau-bar the mean neutron transit time have been determined using a reactor oscillator on the coupled-core of the Queen Mary College research reactor. By using correlation techniques it has proved possible to use detectors small enough to be inserted in the fuel tanks. It is shown that the simplified Baldwin model with one-group diffusion theory is inadequate to describe the kinetic behaviour and the experimentally-determined parameters are dependent upon the positioning of the detectors.

1982-01-01

104

Quantum Computation with Nonlinear Optics  

International Nuclear Information System (INIS)

We propose a scheme of quantum computation with nonlinear quantum optics. Polarization states of photons are used for qubits. Photons with different frequencies represent different qubits. Single qubit rotation operation is implemented through optical elements like the Faraday polarization rotator. Photons are separated into different optical paths, or merged into a single optical path using dichromatic mirrors. The controlled-NOT gate between two qubits is implemented by the proper combination of parametric up and down conversions. This scheme has the following features: (1) No auxiliary qubits are required in the controlled-NOT gate operation; (2) No measurement is required in the course of the computation; (3) It is resource efficient and conceptually simple.

2008-01-15

105

Off-shell amplitudes for open bosonic strings  

Energy Technology Data Exchange (ETDEWEB)

An extension of the Polyakov path-integral formulation to compute off-shell amplitudes for open bosonic strings is derived. Boundary conditions require evaluating the path integral on open surfaces with corners on the boundaries. The contribution to the topological term in the action from the corners is exactly that required for unitarity. The presence of corners introduces a Weyl anomaly in the Polyakov measure. This requires a gauge-fixing procedure for the off-shell amplitudes. Consistent factorization of amplitudes with one or two off-shell strings and any number of on-shell tachyons is established.

1988-02-15

106

Neutron resonances in /sup 100/Mo and valence neutron capture  

Science.gov (United States)

Neutron resonance interactions with /sup 100/Mo were studied at a time-of-flight facility. The transmission of two oxide samples (97.4% /sup 100/Mo) was measured at a 78.20 m flight path and the neutron capture cross section was measured at 40.12 m. Resonance analyses yielded parameters of 124 resonances. Capture ..gamma..-ray spectra from 11 resolved resonances were measured with a Ge(Li) detector at a 10.45 m flight path. In contrast to neighboring nuclei, partial radiation widths of strong p-wave resonances are not in agreement with valence model predictions.

1979-07-01

107

Investigation of FP paths during hypothetical severe accident as a result of Small Break LOCA of WWER-1000 reactor type  

International Nuclear Information System (INIS)

Modelling the behaviour of fission product (FP) in a nuclear reactor coolant system (RCS) undergoing a hypothetical severe accident is an important step in the evaluation of radioactive release outside a nuclear power plant. This paper scrutinize Small Break LOCA sequence for WWER1000 reactor in order to investigate the possible paths for release of FP from fuel pallets to the reactor containment. Contemporaneous computer code for simulation of RCS will be use for the analysis. The results from analysis of fuel damage and release of FP trough the break of cold leg are present. (author)

2006-04-01

108

Xylem Embolism in Response to Freeze-Thaw Cycles and Water Stress in Ring-Porous, Diffuse-Porous, and Conifer Species 1  

UK PubMed Central (United Kingdom)

Vulnerability to xylem embolism by freeze-thaw cycles and water stress was quantified in ring-porous (Quercus gambelii Nutt.), diffuse-porous (Populus tremuloides Michx.,...Full Text Available

1992-10-01

109

Variability In Motor Learning: Relocating, Channeling and Reducing Noise  

UK PubMed Central (United Kingdom)

Variability in motor performance decreases with practice but is never entirely eliminated, due in part to inherent motor noise. The present study develops a method that quantifies how performers...Full Text Available

2009-02-01

110

Transcription induces strand-specific mutations at the 5? end of human genes  

UK PubMed Central (United Kingdom)

A regional analysis of nucleotide substitution rates along human genes and their flanking regions allows us to quantify the effect of mutational mechanisms associated with transcription in germ line...Full Text Available

2008-08-01

111

Three-Dimensional Traction Force Microscopy: A New Tool for Quantifying Cell-Matrix Interactions  

UK PubMed Central (United Kingdom)

The interactions between biochemical processes and mechanical signaling play important roles during various cellular processes such as wound healing, embryogenesis, metastasis, and cell migration. While...Full Text Available

112

The effect of maternal anthropometric characteristics and social factors on gestational age and birth weight in Sudanese newborn infants  

UK PubMed Central (United Kingdom)

BackgroundIn Africa low birth weight (LBW) (<2500 g), is the strongest determinant of infant morbidity and mortality. The aim of this study was to quantify the effect of...Full Text Available

113

The Trade-Off between Costs and Outcomes: The Case of Acute Myocardial Infarction  

UK PubMed Central (United Kingdom)

ObjectiveTo investigate and to quantify the relationship between hospital costs and health outcomes for patients with acute myocardial infarction (AMI) in Veterans Health Administration...Full Text Available

2010-12-01

114

Quantifying the accuracy of automated structure segmentation in 4D CT images using a deformable image registration algorithm  

UK PubMed Central (United Kingdom)

Four-dimensional (4D) radiotherapy is the explicit inclusion of the temporal changes in anatomy during the imaging, planning, and delivery of radiotherapy. One key component of 4D radiotherapy planning...Full Text Available

2008-04-01

115

Quantifiable Biomarkers of Normal Aging in the Japanese Medaka Fish (Oryzias latipes)  

UK PubMed Central (United Kingdom)

BackgroundSmall laboratory fish share many anatomical and histological characteristics with other vertebrates, yet can be maintained in large numbers at low cost for lifetime studies....Full Text Available

116

Proteome-wide Anti-HCV and Anti-HIV Antibody Profiling for Predicting and Monitoring Response to HCV Treatment in HIV Co-infected Patients  

UK PubMed Central (United Kingdom)

We quantified antibody responses to the HCV proteome that are associated with sustained virologic response (SVR) in HIV/HCV co-infected patients treated with pegylated interferon and ribavirin....Full Text Available

2010-09-15

117

Prevalence and trends of selected urologic conditions for VA healthcare users  

UK PubMed Central (United Kingdom)

BackgroundConducted as part of the Urologic Diseases in America project whose aim was to quantify the burden of urologic diseases on the American public, this study focuses on Veterans...Full Text Available

118

Predictive Value of Kushida Index and Acoustic Pharyngometry for the Evaluation of Upper Airway in Subjects With or Without Obstructive Sleep Apnea  

UK PubMed Central (United Kingdom)

Acoustic pharyngometry is a relatively new noninvasive method that quantifies geometrically complexed pharyngeal dimensions. Our study aimed to investigate the predictability and usefulness of acoustic...Full Text Available

2004-10-01

119

Predicting Airborne Particle Levels Aboard Washington State School Buses  

UK PubMed Central (United Kingdom)

School buses contribute substantially to childhood air pollution exposures yet they are rarely quantified in epidemiology studies. This paper characterizes fine particulate matter (PM2.5)...Full Text Available

2008-10-01

120

Physical fitness and occupational demands of the Belfast ambulance service.  

UK PubMed Central (United Kingdom)

The objectives of this study were to evaluate the current fitness of an area ambulance service based in Belfast and to quantify the physiological demands of accident and emergency work. From a total...Full Text Available

1991-09-01

121

Physical Morphology and Quantitative Characterization of Chemical Changes of Weathered PVC/Pine Composites.  

Science.gov (United States)

This study investigated weathering effects on polyvinyl chloride (PVC) based wood plastic composites (WPC), with a focus on the color and structure that is attributed to the material composition. It is directed towards quantifying the main chemical modifi...

2009-01-01

122

Online quasi-continuous measurement of organic acids in the atmosphere  

Energy Technology Data Exchange (ETDEWEB)

The concentration of some organic acids in the atmosphere was determined using a wet effluent diffusion denuder-aerosol collector coupled with Ion Chromatography. Three organic acids and four inorganic anions were identified and quantified in the air sample, taken from the backyard of PSI. (author)

2002-03-01

123

Methods to Quantify Pharmacologically Induced Alterations in Motor Function in Human Incomplete SCI  

UK PubMed Central (United Kingdom)

Spinal cord injury (SCI) is a debilitating disorder, which produces profound deficits in volitional motor control. Following medical stabilization, recovery from SCI typically involves long term rehabilitation....Full Text Available

124

In situ nanoindentation in a transmission electron microscope  

Science.gov (United States)

This dissertation presents the development of the novel mechanical testing technique of in situ nanoindentation in a transmission electron microscope (TEM). This technique makes it possible to simultaneously observe and quantify the mechanical behavior of nano-scale volumes of solids.

2002-12-02

125

Heritability of Lumbar Trabecular Bone Mechanical Properties in Baboons  

UK PubMed Central (United Kingdom)

Genetic effects on mechanical properties have been demonstrated in rodents, but not confirmed in primates. Our aim was to quantify the proportion of variation in vertebral trabecular bone mechanical...Full Text Available

2010-03-01

126

Evaluation of patients' assessment of day hospital care.  

UK PubMed Central (United Kingdom)

The method of linear analogue self-assessment (LASA) was used to quantify the views concerning day care which were held by patients attending a geriatric day hospital. The results suggest that day hospitals...Full Text Available

1977-09-01

127

Evaluating the Nickel Content in Metal Alloys and the Threshold for Nickel-Induced Allergic Contact Dermatitis  

UK PubMed Central (United Kingdom)

Many patients are currently suffering from nickel (Ni)-induced allergic contact dermatitis (ACD). There have been few Korean studies dealing with the threshold of Ni-induced ACD and quantifying the...Full Text Available

2008-04-01

128

Elevated Levels of Volatile Organic Carcinogen and Toxicant Biomarkers in Chinese Women Who Regularly Cook at Home  

UK PubMed Central (United Kingdom)

BackgroundEpidemiologic studies associate lung cancer in non-smoking Chinese women with Chinese-style wok cooking. Our goal was to quantify carcinogen and toxicant...Full Text Available

2010-05-01

129

Effect of pH and Temperature on Denitrification Gene Expression and Activity in Pseudomonas mandelii?  

UK PubMed Central (United Kingdom)

Pseudomonas mandelii liquid cultures were studied to determine the effect of pH and temperature on denitrification gene expression, which was quantified by quantitative reverse transcription-PCR....Full Text Available

2009-06-01

130

Effect of Breast Milk Lead on Infant Blood Lead Levels at 1 Month of Age  

UK PubMed Central (United Kingdom)

Nursing infants may be exposed to lead from breast milk, but relatively few data exist with which to evaluate and quantify this relationship. This route of exposure constitutes a potential infant hazard...Full Text Available

2004-10-01

131

Detection and Analysis of Tumor Fluorescence Using a Two-Photon Optical Fiber Probe  

UK PubMed Central (United Kingdom)

The utility of a two-photon optical fiber fluorescence probe (TPOFF) for sensing and quantifying tumor fluorescent signals was tested in vivo. Xenograft tumors were developed in athymic mice using MCA207...Full Text Available

2004-06-01

132

Deploying Flowbee Tripod  

USGS Gallery

As part of an investigation of the mechanisms of coastal change in the Carolinas (http://woodshole.er.usgs.gov/project-pages/cccp/index.html), instrumented tripods were deployed on Diamond Shoals near Cape Hatteras, NC. These tripods recorded data quantifying the currents, waves, turbidity, temperat...

2010-01-26

133

Comparison of Optical and SEM BSE Imaging Techniques for Quantifying Alpha-Beta Titanium Alloy Microstructures (Preprint).  

Science.gov (United States)

Quantitative metallography is often used to confirm the proper processing of aerospace metallic materials. A microstructural feature of great importance for titanium alloys processed in the alpha-beta phase field is the volume fraction of primary alpha. S...

2006-01-01

134

Community-based incidence of acute renal failure  

UK PubMed Central (United Kingdom)

There is limited information about the true incidence of acute renal failure (ARF). Most studies could not quantify disease frequency in the general population as they are hospital-based and...Full Text Available

2007-07-01

135

Alcohol-folate interactions in women's oral cancer risk: A prospective cohort study  

UK PubMed Central (United Kingdom)

BackgroundThe aim of this cohort study was to quantify the effect of alcohol in the risk of oral cancer in different strata of folate intake, controlling for known...Full Text Available

2010-10-01

136

A field study on the effects of dietary monensin on milk production and milk composition in dairy cows  

UK PubMed Central (United Kingdom)

The objectives of this study were to quantify the effect of 16 ppm of dietary monensin on milk production and composition of dairy cows, and to investigate factors having a potential impact on this...Full Text Available

2010-04-01

137

The kinetic model of the shikimate pathway as a tool to optimize enzyme assays for high-throughput screening.  

Science.gov (United States)

Four-enzyme section of the shikimate pathway (Aro B, D, E, and K) of Streptococcus pneumoniae has been studied. Kinetic properties of the individual enzymes and three- and four-enzyme linked reactions have been characterized in vitro. On the basis of the data measured in spectrophotometric and LC-MS experiments, kinetic mechanisms of the enzymes have been suggested and all kinetic parameters have been identified. Kinetic models for these three- and four-enzyme sections of the shikimate pathway have been constructed and validated. The model of the four-enzyme section of shikimate pathway has been employed to design an inhibition-sensitive reconstituted pathway for a high-throughput screening effort on the shikimate pathway. It was demonstrated that using the model it was possible to optimize this reconstituted pathway in such a way to provide equal sensitivity of the enzymes to inhibition. PMID:16921527

2006-11-01

138

Surface modification of the pure iron by the pulse plasma nitriding: Application of a kinetic model  

Energy Technology Data Exchange (ETDEWEB)

In this work, the pulse plasma nitriding process of pure iron is modelled using a kinetic model derived from the Fick's laws. This approach based on the error function model allows to simulate the growth kinetics of a biphase configuration consisting of {gamma}'-Fe{sub 4}N{sub 1-x} and {epsilon}-Fe{sub 2-3}N iron nitrides under specified conditions. By coupling the kinetics data about the diffusivities of nitrogen in {alpha}-Fe, {gamma}' and {epsilon} phases to the thermodynamic description of the Fe-N phase diagram, it is possible to evaluate the kinetic constant at each growing phase interface, the thickness of nitrided layer, and predict the nitrogen concentration profiles. The comparison between the experimental and theoretical results shows the reliability of the simulation results.

2007-07-25

139

Surface modification of the pure iron by the pulse plasma nitriding: Application of a kinetic model  

International Nuclear Information System (INIS)

In this work, the pulse plasma nitriding process of pure iron is modelled using a kinetic model derived from the Fick's laws. This approach based on the error function model allows to simulate the growth kinetics of a biphase configuration consisting of #gamma#'-Fe_4N_1_-_x and #epsilon#-Fe_2_-_3N iron nitrides under specified conditions. By coupling the kinetics data about the diffusivities of nitrogen in #alpha#-Fe, #gamma#' and #epsilon# phases to the thermodynamic description of the Fe-N phase diagram, it is possible to evaluate the kinetic constant at each growing phase interface, the thickness of nitrided layer, and predict the nitrogen concentration profiles. The comparison between the experimental and theoretical results shows the reliability of the simulation results.

2007-07-25

140

Ozonation kinetics of phenolic acids present in wastewaters from olive oil mills  

Energy Technology Data Exchange (ETDEWEB)

A kinetic study of the degradation by ozone of eight phenolic acids present in wastewaters from olive oil mills has been performed by using a competition kinetic method. The selected phenolic acids are: caffeic, p-coumaric, syringic, vanillic, 3,4,5-trimethoxybenzoic, veratric, p-hydroxy-benzoic, and protocatechuic. The influence of the operating variables (temperature, pH, and ozone partial pressure in the gas stream) is established, and the stoichiometric ratios for the individual direct reactions between ozone and each acid are determined. Once the reaction rate constants are evaluated, they are correlated as a function of temperature and pH into kinetic expressions which are provided for every phenolic acid. The global process occurs in the fast and pseudo-first-order kinetic regime of absorption, a condition required by the competition model to be used.

1997-03-01

141

Detailed Chemical Kinetic Reaction Mechanisms for Incineration of Organophosphorus and Fluoro-Organophosphorus Compounds  

Energy Technology Data Exchange (ETDEWEB)

A detailed chemical kinetic reaction mechanism is developed to describe incineration of the chemical warfare nerve agent sarin (GB), based on commonly used principles of bond additivity and hierarchical reaction mechanisms. The mechanism is based on previous kinetic models of organophosphorus compounds such as TMP, DMMP and DIMP that are often used as surrogates to predict incineration of GB. Kinetic models of the three surrogates and GB are then used to predict their consumption in a perfectly stirred reactor fueled by natural gas to simulate incineration of these chemicals. Computed results indicate that DIMP is the only one of these surrogates that adequately describes combustion of GB under comparable conditions. The kinetic pathways responsible for these differences in reactivity are identified and discussed. The most important reaction in GB and DIMP that makes them more reactive than TMP or DMMP ...

2001-12-13

142

Seismic and Rockphysics Diagnostics fo Multiscale Reservoir Textures  

Energy Technology Data Exchange (ETDEWEB)

We have continued to finish up our work on analyzing relationships between elastic properties and rock microstructure. We have worked on theoretical models for the effects of sorting and packing on elastic moduli and seismic velocities. After analyzing the scanning acoustic images of shales to quantify textures at different scales, we are now using theoretical inclusion models to quantify the elastic property variation with texture. In the closing phases of this project most of our efforts are now focused on writing up the results and preparing the final reports.

2005-02-01

143

Correlations in Werner States  

International Nuclear Information System (INIS)

Werner states are paradigmatic examples of quantum states and play an innovative role in quantum information theory. In investigating the correlating capability of Werner states, we find the curious phenomenon that quantum correlations, as quantified by the entanglement of formation, may exceed the total correlations, as measured by the quantum mutual information. Consequently, though the entanglement of formation is so widely used in quantifying entanglement, it cannot be interpreted as a consistent measure of quantum correlations per se if we accept the folklore that total correlations are measured (or rather upper bounded) by the quantum mutual information.

2008-02-15

144

A framework for the financial evaluation of household biogas plants in India  

Energy Technology Data Exchange (ETDEWEB)

A generalised procedure for quantifying the benefits of household biogas plants is presented. The sensitivity of the procedure to the uncertainty in input prices is reduced through the assumption of incremental benefits from the biogas plant. These benefits are quantified in terms of the quantity of fuelwood for which the biogas substitutes in cooking, the quantity of kerosene replaced through the use of biogas for lighting and the diesel fuel displaced through the use of a biogas fuelled dual-fuel engine for motive power. Sensitivity of the monetary benefits for these parameters is examined in order to identify variables which influence the viability of the technology to the end user. (author).

1990-01-01

145

A critical look at the kinetic models of thermoluminescence-II. Non-first order kinetics  

Energy Technology Data Exchange (ETDEWEB)

Non-first order (FO) kinetics models are of three types; second order (SO), general order (GO) and mixed order (MO). It is shown that all three of these have constraints in their energy level schemes and their applicable parameter values. In nature such restrictions are not expected to exist. The thermoluminescence (TL) glow peaks produced by these models shift their position and change their shape as the trap occupancies change. Such characteristics are very unlike those found in samples of real materials. In these models, in general, retrapping predominates over recombination. It is shown that the quasi-equilibrium (QE) assumption implied in the derivation of the TL equation of these models is quite valid, thus disproving earlier workers' conclusion that QE cannot be held under retrapping dominant conditions. However notwithstanding their validity, they suffer from the shortcomings as stated above and have certain lacunae. For example, the ...

2005-01-07

146

Some computer simulations of semiconductor thin film growth and strain relaxation in a unified atomistic and kinetic model  

Energy Technology Data Exchange (ETDEWEB)

An overview is provided of an evolving atomistic and kinetic model of semiconductor growth that unifies the main features of strain relaxation in low and high lattice misfit heteroepitaxy. The model reveals a kinetic pathway for dislocation formation during growth with little or no energy cost at low misfits, thus providing a way out of the longstanding dilemma of too high dislocation nucleation energies predicted by classical theories of the equilibrium behavior of a fixed number of particles at low misfits. The essential kinetic process underlying the model are identified on the basis of comparison of the predictions of kinetic Monte-Carlo simulations of growth with real-time or in-situ data obtained in such experiments as reflection high-energy electron diffraction (RHEED) and scanning probe microscopy (SPM). Relative significance of these atomistic kinetic processes is shown to ...

1996-12-31

147

Peculiarities of crack propagation in laminated composite materials and their influence on resilience absorbed energy  

International Nuclear Information System (INIS)

Presented are the results of the investigation of the kinetics and micromechanism of the failure in impact bending of oriented-crystallized specimens having the eutectic composition Ni_3Al-Ni_3Nb and of the bimetal composed of 45 steel + M3 copper. The failure kinetics was studied by high-speed filming, whereas the fractures were studied by electron fractography. The particularities of the failure of the laminar-type composite materials were found. Analyzed was the effect of the kinetic factors and the mechanism of failure upon its energy consumption.

148

Kinetic studies of alkali metal gallide decomposition in aqueous hydroxide solutions  

International Nuclear Information System (INIS)

Kinetics of decomposition of gallium and alkali metal intermetallic compounds in the systems LiGa-LiOH, LiGa-NaOH and LiGa-KON was studied in the temperature range of 40-80 deg C. It was ascertained that increase in temperature gives rise to increase in decomposition rate, whereas increase in hydroxide concentration involves the reaction deceleration. An assumption was made that the decomposition occurs with superimposing of two mechanisms, i.e. chemical and electrochemical decomposition. Basic kinetic characteristics of the process were determined - decomposition rate constant and current density

2002-01-01

149

ESR studies on reactivity of HO{sub 2} radicals in polycrystalline ice: non-monotonic changes of disproportionation rate in the temperature range 100-200 K  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of HO{sub 2} radicals in UV-irradiated frozen dilute solutions of H{sub 2}O{sub 2} were followed by the ESR technique. Radical disproportionations at the irradiation temperature were found to be adequately described in terms of dispersive kinetics by a second-order equal-concentration kinetic equation with rate parameters changing non-monotonically in the temperature range 100-200 K. These changes are thought to occur due to well separated structural relaxation regions of polycrystalline ice in the above temperature range. (author).

1994-11-01

150

Detailed kinetic modeling of autoignition chemistry  

Energy Technology Data Exchange (ETDEWEB)

The development of detailed chemical kinetic reaction mechanisms for analysis of autoignition and knocking of hydrocarbon fuels is described. In particular, kinetic processes of concern for the oxidation of complex hydrocarbon fuel molecules are emphasized. The wide ranges of temperature and pressure which are encountered by end gases in automobile engine combustion chambers result in extreme demands on reaction mechanisms which are intended to describe knocking conditions and predict rates of combustion and ignition. The reactions and chemical species which are most important in each temperature and pressure regime are discussed, and the validation of these reaction mechanisms through comparison with idealized experimental results is described. 53 refs., 8 figs., 5 tabs.

1987-07-22

151

Vulnerability Analysis of Physical Protection System at Wolsung Nuclear Power Plant  

Energy Technology Data Exchange (ETDEWEB)

The 9/11 event in the U.S.A has increased international terror possibilities against nuclear facilities including nuclear power plants(NPPs). It is necessary to assess the performance of an existing physical protection system(PPS) at nuclear facilities based on such malevolent acts. A PPS is a complex configuration of detection, delay, and response elements. Several methods are available to analyze a PPS and evaluate its effectiveness. Sandia National Laboratory(SNL) in the USA was developed a System Analysis of Vulnerability to Intrusion (SAVI) computer code for this purpose. It is powerful software for evaluating the effectiveness of PPS against outsider threats. This study presents the performance assessment of the PPS at Wolsung NPP using SAVI code. First, the site-specific Adversary Sequence Diagrams(ASDs) of the PPS is constructed. It helps to understand the functions of the existing PPS composed of physical areas and Protection Elements(PEs) at Wolsung NPP. Then, the most ...

2006-07-01

152

Vulnerability Analysis of Physical Protection System at Wolsung Nuclear Power Plant  

International Nuclear Information System (INIS)

The 9/11 event in the U.S.A has increased international terror possibilities against nuclear facilities including nuclear power plants(NPPs). It is necessary to assess the performance of an existing physical protection system(PPS) at nuclear facilities based on such malevolent acts. A PPS is a complex configuration of detection, delay, and response elements. Several methods are available to analyze a PPS and evaluate its effectiveness. Sandia National Laboratory(SNL) in the USA was developed a System Analysis of Vulnerability to Intrusion (SAVI) computer code for this purpose. It is powerful software for evaluating the effectiveness of PPS against outsider threats. This study presents the performance assessment of the PPS at Wolsung NPP using SAVI code. First, the site-specific Adversary Sequence Diagrams(ASDs) of the PPS is constructed. It helps to understand the functions of the existing PPS composed of physical areas and Protection Elements(PEs) at Wolsung NPP. Then, the most ...

2006-05-25

153

Performance Assessment of Physical Protection System at Wolsong Nuclear Power Plant using SAVI code  

Energy Technology Data Exchange (ETDEWEB)

The 9/11 event in the U.S.A has increased international terror possibilities against nuclear facilities including nuclear power plants(NPPs). It is necessary to assess the performance of existing physical protection system(PPS) at nuclear facilities based on such malevolent acts. A PPS is a complex configuration of detection, delay, and response elements. Several techniques are available to analyze a PPS and evaluate its effectiveness. Sandia National Laboratory(SNL) in the USA was developed a System Analysis of Vulnerability to Intrusion (SAVI) computer code for this purpose. It is powerful software for evaluating the effectiveness of PPS against outsider threats. This study presents the performance assessment of the PPS at Wolsong NPP using SAVI code. The first is that the SAVI constructs the site-specific Adversary Sequence Diagram (ASD) of the PPS. This provides a methods of graphically representing the PPS composed of physical areas and Protection Elements(PEs) at Wolsung NPP. The ...

2005-07-01

154

Nearly metastable rhombohedral phases of bcc metals  

International Nuclear Information System (INIS)

The energy E(c/a) for a bcc element stretched along its [001] axis (the Bain path) has a minimum at c/a=1, a maximum at c/a=#sq root#(2), and an elastically unstable local minimum at c/a>#sq root#(2). An alternative path connecting the bcc and fcc structures is the rhombohedral lattice. The primitive lattice has R3m symmetry, with the angle #alpha# changing from 109.4 deg. (bcc), to 90 deg. (simple cubic), to 60 deg. (fcc). We study this path for the non-magnetic bcc transition metals (V, Nb, Mo, Ta, and W) using both all-electron linearized augmented plane wave and projector augmented wave VASP codes. Except for Ta, the energy E(#alpha#) has a local maximum at #alpha#=60 deg., with local minima near 55 deg. and 70 deg., the latter having lower energy, suggesting the possibility of a metastable rhombohedral state for these materials. We first examine the elastic stability of the 70 deg. minimum structure, and determine ...

2008-02-01

155

Vehicle-Dependent Disposition Kinetics of Fluoranthene in Fisher-344 Rats  

UK PubMed Central (United Kingdom)

The objective of this study was to evaluate how the vehicles of choice affect the pharmacokinetics of orally administered Fluoranthene [FLA] in rats. Fluoranthene is a member of the family of...Full Text Available

2008-03-01

156

Time-resolved triple-axis spectroscopy - a new method for real-time neutron scattering  

International Nuclear Information System (INIS)

A new method for kinetic experiments with neutrons is described. This method combines the conventional triple-axis neutron spectroscopy with relaxation-type experiments. Whereas the former method yields information about the microscopic dynamics of solids, the latter provides macroscopic relaxation times. The combination of both methods allows to determine the microscopic mechanism of relaxation processes. The time-resolved triple-axis spectroscopy is limited to reversible processes and to time scales from 10"-"3 to 10"4 s. Typical applications are the kinetics of phase transformations (structural and dynamical changes), kinetics of domain distributions, kinetics of (spinodal) decomposition, reversible solid state reactions, time-dependent occupation of phonon states or phonon lifetimes. (orig.).

1990-04-01

157

The chain mechanism in catalytic cracking. The chain mechanism in catalytic cracking  

Energy Technology Data Exchange (ETDEWEB)

The cracking of 2-methylpentane on USHY at 300, 400, 450, and 500[degrees]C is interpreted in detail in terms of a chain mechanism. The kinetic equation developed from this mechanism fits the experimental data very well. The contribution of chain processes to the overall rate of conversion depends on the kinetic chain length, which in turn depends on the surface coverage by carbenium ions and their reactivities. Kinetic parameters were obtained at all four temperatures. A detailed examination of the kinetics shows that chain processes are more important at low reaction temperatures, whereas protolytic cracking dominates at higher temperatures. The parameters also show that both competitive inhibition by products and the rate of catalyst decay increase with increasing reaction temperature. Furthermore, they show that carbenium ions formed on Broensted sites are more stable than carbonium ions. 39 refs., ...

1993-03-01

158

Spatial Relationships between Drug Binding Sites on the ...  

Science.gov (United States)

... determination of the molar extinction coefficients, e, were measured by the Lowry method with native a-toxin as a standard. Binding Kinetics. ...

1987-10-15

159

Shock Tunnel Studies of Scramjet Phenomena - NASA Technical Report ...  

Science.gov (United States)

Kinetic reaction mechanisms have a hierarchical smacture with mechanisms for complex fuels built up on sub-mechanisms for simple fuel molecules ...

160

Self-similarity and power-like tails in nonconservative kinetic models  

CERN Document Server

In this paper, we discuss the large--time behavior of solution of a simple kinetic model of Boltzmann--Maxwell type, such that the temperature is time decreasing and/or time increasing. We show that, under the combined effects of the nonlinearity and of the time--monotonicity of the temperature, the kinetic model has non trivial quasi-stationary states with power law tails. In order to do this we consider a suitable asymptotic limit of the model yielding a Fokker-Planck equation for the distribution. The same idea is applied to investigate the large-time behavior of an elementary kinetic model of economy involving both exchanges between agents and increasing and/or decreasing of the mean wealth. In this last case, the large-time behavior of the solution shows a Pareto power law tail. Numerical results confirm the previous analysis.

2010-01-01

161

Reactions of thiocyanogen and thiocyanogen halides with unsaturated compounds  

Energy Technology Data Exchange (ETDEWEB)

Data on the reactions of thiocyanogen and thiocyanogen halides with unsaturated compounds are systematised. The kinetic and stereo- and regiochemical regularities of these reactions are analysed. The bibliography includes 81 references.

1998-05-31

162

Physiologic changes during growth and development.  

UK PubMed Central (United Kingdom)

To express growth-related changes in physiologic or other functions in forms usable for kinetic modeling, we are interested in identifying regular relationships that take the form of simple mathematical...Full Text Available

1994-12-01

163

Photodegradation of polypropylene/polystyrene blends: Styrene-butadiene-styrene compatibilisation effect  

British Library Electronic Table of Contents (United Kingdom)

The mutual influence between the PP/PS polymer blend components during UV photodegradation was studied. Polypropylene (PP) and polystyrene (PS) have different photodegradation mechanisms, due to the larger UV absorption of polystyrene and formation of more stable tertiary carbon radicals. To compare the stabilities the kinetics of carbonyl formation was measured in different blend compositions. The results show that polystyrene presented a faster carbonyl formation than polypropylene, while the blends display faster kinetics than the isolated components. The kinetics of carbonyl formation of the blends was a function of polypropylene content. This result is unexpected if one considers the behaviour of each component alone. The kinetics and mechanism of UV degradation can be only explained ...

2008-01-01

164

LIONEL V. BALDWIN  

Science.gov (United States)

Aug. 24, 1965. L. V. BALDWIN ETAL. 3202915. PARTICLE BEAM MEASUREMENT APPARATUS USING BEAM KINETIC. ENERGY TO CHANGE TIIE HEAT SENSITIVE RESISTANCE OF ...

165

Kinetic and mass transfer analyses of metal biosorption by Caulerpa lentillifera  

British Library Electronic Table of Contents (United Kingdom)

This study examined kinetics and mass transfer in the biosorption of heavy metals onto Caulerpa lentillifera. The sorption capacity of Cu^2^+, Pb^2^+ and Cd^2^+ from aqueous solution increased with initial metal concentration and decreased with biosorbent dose. Kinetic data were well described using the pseudo-second-order model. Results showed that both external mass transfer and intraparticle diffusion were rate limiting steps in the biosorption process. Activation energy of biosorption kinetics fell in the range of 3-13kJ/mol. The biosorption of Cu^2^+, Cd^2^+ and Pb^2^+ on the biomass correlated well with the Langmuir isotherm (R^2>0.99) with maximum sorption capacities at 293K of 0.169, 0.085 and 0.177mol/kg for Cu^2^+, Cd^2^+ and Pb^2^+ ions, respectively. Thermodynamic studies demon...

2011-01-01

166

Dynamic Weapon-Target Assignment Problems with ...  

Science.gov (United States)

... defense's weapons are Space-based kinetic-kill vehicles ... I ti I obtained by dividing the weapons as ... of the optimal weapon-arge assigntments and ...

1988-06-01

167

Diffusion examined by diffraction  

Science.gov (United States)

X-ray diffraction offers a unique combination of advantages for kinetic study which include the non-destructive nature of the measurement, the use of bulk crystals, and the convenience of the experimental arrangements. These attributes and the availability of position-sensitive detectors and high-flux synchrotron radiation sources make this technique most useful for in situ, dynamical investigations. When using diffraction techniques to determine a diffusion coefficient, the principle of analysis entails a scattering theory and a kinetic model. The former allows the kinetic parameter(s) to be extracted from measured intensity, while the latter relates the kinetic parameter(s) to the diffusion coefficient(s). Three examples are demonstrated: (1) Palladium Silicide (Pd{sub 2}Si) Layer Growth on Silicon, (2) Decomposition of an Ni-12.5at%Si Superalloy, and (3) Short-range Ordering in Cu-Au Solid Solutions.

168

Detailed chemical kinetic reaction mechanisms for primary reference fuels for diesel cetane number and spark-ignition octane number  

British Library Electronic Table of Contents (United Kingdom)

A detailed chemical kinetic reaction mechanism is developed for primary reference fuel mixtures of n-hexadecane and 2,2,4,4,6,8,8-heptamethyl nonane for diesel cetane ratings. The mechanisms are constructed using existing rules for reaction pathways and rate expressions developed previously for the primary reference fuels for gasoline octane ratings, n-heptane and iso-octane. These reaction mechanisms are validated by comparisons between computed and experimental results for shock tube ignition and for oxidation under jet-stirred reactor conditions. The combined kinetic reaction mechanism contains the submechanisms for the primary reference fuels for diesel cetane ratings and submechanisms for the primary reference fuels for gasoline octane ratings, all in one integrated large kinetic reac...

2011-01-01

169

Bicarbonate kinetics and predicted energy expenditure in critically ill children2  

UK PubMed Central (United Kingdom)

Background:To determine nutrient requirements by the carbon oxidation techniques, it is necessary to know the fraction of carbon dioxide produced during the oxidative...Full Text Available

2008-08-01

170

Adsorption rate of phenol from aqueous solution onto organobentonite: Surface diffusion and kinetic models.  

Science.gov (United States)

The concentration decay curves for the adsorption of phenol on organobentonite were obtained in an agitated tank batch adsorber. The experimental adsorption rate data were interpreted with diffusional models as well as first-order, second-order and Langmuir kinetic models. The surface diffusion model adjusted the data quite well, revealing that the overall rate of adsorption was controlled by surface diffusion. Furthermore, the surface diffusion coefficient increased raising the mass of phenol adsorbed at equilibrium and was independent of the particle diameter in the range 0.042-0.0126cm. It was demonstrated that the overall rate of adsorption was essentially not affected by the external mass transfer. The second-order and the Langmuir kinetic models fitted the experimental data quite well; however, the kinetic constants of both models varied without any physical meaning while increasing the particle size and the mass of ...

2011-08-22

171

Adsorption Kinetics of Surfactants at Fluid-Fluid Interfaces  

CERN Document Server

We review a new theoretical approach to the kinetics of surfactant adsorption at fluid-fluid interfaces. It yields a more complete description of the kinetics both in the aqueous solution and at the interface, deriving all equations from a free-energy functional. It also provides a general method to calculate dynamic surface tensions. For non-ionic surfactants the results coincide with previous models. Common non-ionic surfactants are shown to undergo diffusion-limited adsorption, in agreement with experiments. Strong electrostatic interactions in salt-free ionic surfactant solutions are found to lead to kinetically limited adsorption. In this case the theory accounts for unusual experimental results which could not be understood using previous approaches. Added salt screens the electrostatic interactions and makes the ionic surfactant adsorption similar to the non-ionic case. The departure from the non-ionic behavior as ...

1997-01-01

172

3 - NASA Technical Reports Server  

Science.gov (United States)

Mar 1, 2011... properties to a complex model demanding full combustion kinetics, transport properties, and poppet valve flow characteristics. ...

173

Topological Analysis of Large-scale Biomedical Terminology Structures  

British Library Electronic Table of Contents (United Kingdom)

ObjectiveTo characterize global structural features of large-scale biomedical terminologies using currently emerging statistical approaches.DesignGiven rapid growth of terminologies, this research was designed to address scalability. We selected 16 terminologies covering a variety of domains from the UMLS Metathesaurus, a collection of terminological systems. Each was modeled as a network in which nodes were atomic concepts and links were relationships asserted by the source vocabulary. For comparison against each terminology we created three random networks of equivalent size and density.MeasurementsAverage node degree, node degree distribution, clustering coefficient, average path length.ResultsEight of 16 terminologies exhibited the small-world characteristics of a short average path le...

2007-01-01

174

The Meaning of Cause and Prevent: The Role of Causal Mechanism  

British Library Electronic Table of Contents (United Kingdom)

How do people understand questions about cause and prevent? Some theories propose that people affirm that A causes B if A's occurrence makes a difference to B's occurrence in one way or another. Other theories propose that A causes B if some quantity or symbol gets passed in some way from A to B. The aim of our studies is to compare these theories' ability to explain judgements of causation and prevention. We describe six experiments that compare judgements for causal paths that involve a mechanism, i.e. a continuous process of transmission or exchange from cause to effect, against paths that involve no mechanism yet a change in the cause nevertheless brings about a change in the effect. Our results show that people prefer to attribute cause when a mechanism links cause to effect. In contr...

2011-01-01

175

Particle Swarm Optimization for Realizing Intelligent Routing in Networks with Quality Grading  

CERN Document Server

Significant research has been carried out in the recent years for generating systems exhibiting intelligence for realizing optimized routing in networks. In this paper, a grade based twolevel based node selection method along with Particle Swarm Optimization (PSO) technique is proposed. It assumes that the nodes are intelligent and there exist a knowledge base about the environment in their local memory. There are two levels for approaching the effective route selection process through grading. At the first level, grade based selection is applied and at the second level, the optimum path is explored using PSO. The simulation has been carried out on different topological structures and it is observed that a graded network produces a significant reduction in number of iteration to arrive at the optimal path selection.

2011-01-01

176

Optimal haulage routing of off-road dump trucks in construction and mining sites using Google Earth and a modified least-cost path algorithm  

British Library Electronic Table of Contents (United Kingdom)

This study presents new software, called Google Earth-based Optimal HAulage RouTing System (GEOHARTS), to improve the functionality of Google Earth for optimal haulage routing of off-road dump trucks in construction and mining sites. A modified least-cost path algorithm, which is applicable to working areas with both paved and unpaved temporary roads and can consider the effects of terrain relief and curves along a route on the route planning, was proposed and utilized for the software development. GEOHARTS can determine optimal haulage routes between loaders and dumps that ensure the least travel time or fuel consumption of off-road dump trucks and can visualize the results using an embedded 3D render window of Google Earth. The application to the Pasir open-pit coal mine in Indonesia dem...

2011-01-01

177

Neutron resonances in "1"0"0Mo and valence neutron capture  

International Nuclear Information System (INIS)

Neutron resonance interactions with "1"0"0Mo were studied at a time-of-flight facility. The transmission of two oxide samples (97.4% "1"0"0Mo) was measured at a 78.20 m flight path and the neutron capture cross section was measured at 40.12 m. Resonance analyses yielded parameters of 124 resonances. Capture #gamma#-ray spectra from 11 resolved resonances were measured with a Ge(Li) detector at a 10.45 m flight path. In contrast to neighboring nuclei, partial radiation widths of strong p-wave resonances are not in agreement with valence model predictions.

178

Low-cycle fatigue behaviour and microstructure of copper and alpha-brass under biaxial load paths  

Energy Technology Data Exchange (ETDEWEB)

The low-cycle fatigue behaviour of copper and a-brass CuZn30 was investigated in uniaxial and biaxial tests. Planar biaxial fatigue tests were carried out using cruciform samples with proportional stain paths with and without phase shift between the two axes. Microcharacterisation was performed by electron microscopy as well as by high-resolution X-ray line profile analysis. The biaxial cyclic stress-strain curves show good agreement with the uniaxial ones using the von Mises equivalent strain hypothesis. The dislocation densities and microhardness values of the biaxial case, however, show significantly lower values compared to the uniaxial case at equivalent von Mises stresses.

2010-07-01

179

Linac Coherent Light Source Experiments Commence  

British Library Electronic Table of Contents (United Kingdom)

The Linac Coherent Light Source [1] (LCLS) at SLAC National Accelerator Laboratory is preparing for the arrival of its first scientific users in the fall of 2009. LCLS is the world's first free-electron in the spectral range 800-8,000 eV, producing intense, sub-picosecond pulses of Xrays with very high spatial coherence. The accelerator facility has been commissioned in stages, beginning in April 2007 [2] with the injector linac and culminating in December 2008 [3] with the first transport of electrons through the complete beam path. On April 10, 2009, the LCLS Project team was rewarded for years of planning, design, construction, and checkout with a dream-come-true: as undulators were placed on the beam path one-by-one, the laser simply turned on without drama in the course of one hour [4...

2009-01-01

180

High channel density wavelength division multiplexer with defined diffracting means positioning  

Energy Technology Data Exchange (ETDEWEB)

A wavelength division multiplexer/demultiplexer having optical path lengths between a fiber array and a Fourier transform lens, and between a dispersion grating and the lens equal to the focal length of the lens. The optical path lengths reduce losses due to angular acceptance mismatch in the multiplexer. Close orientation of the fiber array about the optical axis and the use of a holographic dispersion grating reduces other losses in the system. Multi-exposure holographic dispersion gratings enable the multiplexer/demultiplexer for extremely broad-band simultaneous transmission and reflection operation. Individual Bragg plane sets recorded in the grating are dedicated to and operate efficiently on discrete wavelength ranges.

1990-01-01

181

Exact Simulation of Bessel Diffusions  

CERN Document Server

We consider the exact path sampling of the squared Bessel process and some other continuous-time Markov processes, such as the CIR model, constant elasticity of variance diffusion model, and hypergeometric diffusions, which can all be obtained from a squared Bessel process by using a change of variable, time and scale transformation, and/or change of measure. All these diffusions are broadly used in mathematical finance for modelling asset prices, market indices, and interest rates. We show how the probability distributions of a squared Bessel bridge and a squared Bessel process with or without absorption at zero are reduced to randomized gamma distributions. Moreover, for absorbing stochastic processes, we develop a new bridge sampling technique based on conditioning on the first hitting time at zero. Such an approach allows us to simplify simulation schemes. New methods are illustrated with pricing path-dependent options.

2009-01-01

182

Epitaxial bain path in transition metals  

Energy Technology Data Exchange (ETDEWEB)

Epitaxial films grown pseudomorphically on substrates provide a way to stabilise non-equilibrium structures of materials. Obviously, there always is a certain lattice misfit between substrate and film material in its bulk equilibrium structure. In the pseudomorphic regime, this misfit can either lead to the growth of films in a strained bulk structure or even yield structures that are not stable in the bulk. Large misfits do not necessarily imply large lateral stress. Theory can help to predict e.g. geometry, stress and magnetic properties of pseusomorphically grown metal films. In this work, we considered the fcc-bcc epitaxial Bain path of 3d, 4d, and 5d transition metals, which provides a reasonable description of tetragonally distorted films on substrates. We carried out density functional calculations in the implementation of the full potential local orbital program package FPLO. Emphasis is put on similarities among the transition metals.

2010-07-01

183

Dynamic Adjustment of Irrigation Technology/Water Management in Western U.S. Agriculture: Toward a Sustainable Future  

British Library Electronic Table of Contents (United Kingdom)

Changing water demands induced through climate change and a growing biofuel energy sector throughout the western States are expected to increase pressures on the present allocation mechanisms for an increasingly scarce resource, raising uncertainty about the sustainability of irrigated agriculture in the West. In this paper, we first present the policy motivation for examining continued producer adoption of water conserving irrigation production systems as a foundation for providing a sustainable future for western irrigated agriculture. Second, we summarize the historical transitions that help to define the adjustment path to increased sustainability for the sector. While western irrigated agriculture is on a path toward greater sustainability, evidence suggests that the sustainability go...

2010-01-01

184

A new formulation of asset trading games in continuous time with essential forcing of variation exponent  

CERN Document Server

We introduce a new formulation of asset trading games in continuous time in the framework of the game-theoretic probability established by Shafer and Vovk (2001). In our formulation, the market moves continuously but an investor trades in discrete times, which can depend on the past path of the market. We prove that an investor can essentially force that the asset price path behaves with the variation exponent exactly equal to two. Our proof is based on embedding high-frequency discrete time games into the continuous time game and the use of the Bayesian strategy of Kumon, Takemura and Takeuchi (2007b) for discrete time coin-tossing games. We also clarify that the main growth part of the investor's capital processes is lucidly described by the information quantities, which are derived from the Kullback-Leibler information with respect to the empirical fluctuation of the asset price.

2007-01-01

185

Subclinical interstitial lung involvement in rheumatic diseases. Correlations of high-resolution Computed Tomography patterns with functional and cytologic findings  

International Nuclear Information System (INIS)

The aims of this study were to quantify the severity and extent of subclinical interstitial lung disease as depicted on HRCT and to study the relationship between the patterns of lung disease quantified by HRCT and the functional parameters and bronchoalveolar lavage findings in patients with rheumatic diseases. The results confirm that HRCT is a sensitive tool in detecting interstitial lung disease in patients with rheumatic diseases with no signs and symptoms of pulmonary involvement. The relationship between the different HRCT patterns and bronchoalveolar lavage cell profiles can identify patients at higher risk of developing irreversible lung fibrosis. A long-term, prospective follow-up study is needed to determine whether these patients will develop over pulmonary disease.

1999-01-01

186

Quantifying the thermal flowering rates of eighteen species of annual bedding plants  

British Library Electronic Table of Contents (United Kingdom)

The effect of mean daily air temperature (MDT) on flowering rate (the reciprocal of days to flower) was quantified for 18 species of annual bedding plants. Plants were grown in environmental growth chambers at constant air temperature set points of 5, 7.5, 10, 15, 25, or 30^oC and under an irradiance of 160-180mmolm^-^2s^-^1, with a 16-h photoperiod. Nonlinear mathematical equations were developed to predict the effect of MDT on flowering rate and to estimate the base, optimum, and maximum temperatures (Tmin, Topt, and Tmax), which are the temperatures at which flowering rates are zero (low temperature), maximal, and zero once again (high temperature), respectively. The estimated Tmin varied among species and ranged from 1.1^oC in French marigold (Tagetes patula L.) to 9.9^oC in angelonia ...

2011-01-01

187

Methods for proving the equivalency of detonator performance  

Energy Technology Data Exchange (ETDEWEB)

One of the challenges facing engineers is developing newer, safer detonators that are equivalent to devices currently in use. There is no clear consensus on an exact method for drawing equivalence of detonators. This paper summarizes our current efforts to develop diagnostics addressing various aspects of detonator design to better quantify and prove equivalency. We consider various optical techniques to quantify the output pressure and output wave shape. The development of a unique interpretation of streak camera breakouts, known as the apparent center of initiation, will be discussed as a metric for detonation wave shape. Specific examples apply these techniques to the comparison of a new laser-driven detonator with an existing exploding bridgewire (EBW) detonator. Successes and short-comings of the techniques will be discussed.

2009-01-01

188

Mapping burned areas and burn severity patterns in SW Australian eucalypt forest using remotely-sensed changes in leaf area index  

British Library Electronic Table of Contents (United Kingdom)

Remote sensing is the most practical method available to managers of fire-prone forests for quantifying and mapping fire impacts. Differenced Normalised Burn Ratio (?NBR) is among the most widely used spectral indices for the mapping of burn severity but is difficult to interpret in terms of fire-related changes in key biophysical attributes and processes. We propose to quantify burn severity as a change in the leaf area index (?LAI) of a stand. LAI is a key biophysical attribute of forests, and is central to understanding their water and carbon cycles. Previous studies have suggested that changes in canopy LAI may be a major contributor to ?NBR and to the composite burn index (CBI) that is frequently used in combination with the NBR to assess burn severity on the ground. We applied remote...

2008-01-01

189

Language morphology offset: Text classification on a Croatian-English parallel corpus  

British Library Electronic Table of Contents (United Kingdom)

We investigate how, and to what extent, morphological complexity of the language influences text classification using support vector machines (SVM). The Croatian-English parallel corpus provides the basis for direct comparison of two languages of radically different morphological complexity. We quantified, compared, and statistically tested the effects of morphological normalisation on SVM classifier performance based on a series of parallel experiments on both languages, carried over a large scale of different feature subset sizes obtained by different feature selection methods, and applying different levels of morphological normalisation. We also quantified the trade-off between feature space size and performance for different levels of morphological normalisation, and compared the resul...

2008-01-01

190

Example of second-law efficiency of solar-thermal cavity receivers  

Energy Technology Data Exchange (ETDEWEB)

Properly quantified performance of a solar-thermal cavity receiver must not only account for the energy gains and losses as dictated by the First Law of thermodynamics, but it must also account for the quality of that energy. Energy quality can only be determined from the Second Law. In this paper, an equation developed for the Second-Law efficiency of a cavity receiver is presented as an evolution from the definition of available energy or ''availability'' (occasionally called exergy). The variables required are all either known or readily determined. The importance of considering the Second-Law is emphasized by a comparison of the First- and Second-Law efficiencies around an example of data collected from two receivers that were designed for different purposes, where the attempt was made to demonstrate that a Second-Law approach to quantifying the performance of a solarthermal cavity receiver lends more ...

1986-02-01

191

Environmental costs and benefits case study: nuclear power plant. Quantification and economic valuation of selected environmental impacts/effects. Final report  

International Nuclear Information System (INIS)

This case study is an application, to a nuclear power plant, of the methodology for quantifying environmental costs and benefits, contained in the regional energy plan, adopted in April, 1983, by the Northwest Power Planning Council, pursuant to Public Law 96-501.The study is based on plant number 2 of the Washington Public Power Supply System (WNP-2), currently nearing completion on the Hanford Nuclear Reservation in eastern Washington State. This report describes and documents efforts to quantify and estimate monetary values for the following seven areas of environmental effects: radiation/health effects, socioeconomic/infrastructure effects, consumptive use of water, psychological/health effects (fear/stress), waste management, nuclear power plant accidents, and decommissioning costs. 103 references.

192

Dialysis membrane for separation on microchips  

Energy Technology Data Exchange (ETDEWEB)

Laser-induced phase-separation polymerization of a porous acrylate polymer is used for in-situ fabrication of dialysis membranes inside glass microchannels. A shaped 355 nm laser beam is used to produce a porous polymer membrane with a thickness of about 15 .mu.m, which bonds to the glass microchannel and forms a semi-permeable membrane. Differential permeation through a membrane formed with pentaerythritol triacrylate was observed and quantified by comparing the response of the membrane to fluorescein and fluorescently tagging 200 nm latex microspheres. Differential permeation was observed and quantified by comparing the response to rhodamine 560 and lactalbumin protein in a membrane formed with SPE-methylene bisacrylamide. The porous membranes illustrate the capability for the present technique to integrate sample cleanup into chip-based analysis systems.

2010-07-13

193

Blood flow quantification with MRI using the phase mapping method. Moeglichkeiten und Grenzen der Blutflussquantifizierung peripherer arterieller Gefaesse mit der MRT unter Anwendung des Phase-Mapping-Verfahrens  

Energy Technology Data Exchange (ETDEWEB)

MRT is able to demonstrate arteries while MR angiography can quantify blood flow by a non-invasive method. In the present paper blood flow measurements were carried out in four selected cases on the basis of phase mapping. In 3 patients with lesions in the pelvis or thigh, angiography was performed in order to localise the stenosis or occlusion and this was followed by qantitative blood flow measurements. The results showed that angiography may not always provide all necessary information concerning a haemodynamically significant stenosis. The method may also be used for quantifying blood flow in the renal arteries and that it has significant advantages over the colour Doppler method. (orig.).

1992-08-01

194

A novel method for quantifying scanner instability in fMRI  

British Library Electronic Table of Contents (United Kingdom)

Abstract A method was developed to quantify the effect of scanner instability on functional MRI data by comparing the instability noise to endogenous noise present when scanning a human. The instability noise was computed from agar phantom data collected with two flip angles, allowing for a separation of the instability from the background noise. This method was used on human data collected at four 3 T scanners, allowing the physiological noise level to be extracted from the data. In a -well-operating- scanner, the instability noise is generally less than 10% of physiological noise in white matter and only about 2% of physiological noise in cortex. This indicates that instability in a well-operating scanner adds very little noise to functional MRI results. This new method allows researcher...

2011-01-01

195

A new method for quantifiable and controlled dosage of particulate matter for in vitro studies: The electrostatic particulate dosage and exposure system (EPDExS)  

British Library Electronic Table of Contents (United Kingdom)

An exposure chamber is described for the quantifiable addition of fine and ultrafine aerosol particulate matter directly to cells and used to demonstrate the in vitro cytotoxicity of fine 1,4-naphthoquinone particles to murine lung epithelial cells. The electrostatic particulate dosage and exposure system (EPDExS) operates on the principle of electrostatic precipitation and is shown to deposit fine and ultrafine aerosol particles directly to cells with 100% efficiency for particle diameters in the range of 40-530nm. This range is not limited by the EPDExS, but rather by the aerosolization method used for this study. Numbers of particles deposited onto the cells are counted with a condensation particle counter, negating any need to calculate or estimate particle exposure. The process of par...

2008-01-01

196

a Kinetic Model of Interface Motion  

Science.gov (United States)

We study a kinetic model for a system of two species of particles interacting via a repulsive long range potential and with a reservoir at fixed temperature. The interaction between the particles is modeled by a Vlasov term and the thermal bath by a Fokker-Planck term. We show that in the diffusive and sharp interface limit the motion of the interfaces at low temperature is described by a Stefan problem or a Mullins-Sekerka motion, depending on the time scale.

2004-01-01

197

Substrate Kinetics of the Tonoplast H+-Translocating Inorganic Pyrophosphatase and Its Activation by Free Mg2+1  

UK PubMed Central (United Kingdom)

To clarify the kinetic characteristics and ionic requirements of the tonoplast H+-translocating inorganic pyrophosphatase (H+-PPiase), PPi hydrolysis and PPi-dependent H+...Full Text Available

1990-07-01

198

Mechanism of the heterophase of polyacrylonitrile in aqueous and aqueous-alcoholic solution  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the hydrolysis of polyacrylonitrile in aqueous and aqueousalcoholic solution have been studied. The effects of the solvent on the kinetics of the hydrolysis have been demonstrated, together with the role of diffusion and adsorption of the hydrolyzing agent on the surface of the macromolecules. It has also been shown to be possible to control the extent of hydrolysis and the hydrophilicity of the product.

1985-09-01

199

Low-Concentration Kinetics of Atmospheric CH4 Oxidation in Soil and Mechanism of NH4+ Inhibition  

UK PubMed Central (United Kingdom)

NH4+ inhibition kinetics for CH4 oxidation were examined at near-atmospheric CH4 concentrations in three upland forest soils. Whether NH4+-independent...Full Text Available

1998-11-01

200

Localization of an anti-tumour monoclonal antibody in human tumour xenografts: kinetic and quantitative studies with the 791T/36 antibody  

International Nuclear Information System (INIS)

Studies have been performed with an anti-osteogenic sarcoma monoclonal antibody 791T/36 and human tumour xenografts to examine some of the quantitative and kinetic aspects of tumour localization. The influence of variations in tumour size and site and antibody dose on the extent and rate of specific antibody localization have been examined, together with the site of intratumoural deposition of the antibody. (UK).

201

Kinetics of the urea-induced dissociation of human plasma alpha 2-macroglobulin as measured by small-angle neutron scattering.  

UK PubMed Central (United Kingdom)

The kinetics of the urea-induced dissociation of human plasma alpha 2-macroglobulin into two half-molecular fragments was investigated at 21.0 degrees C by using small-angle neutron scattering. The...Full Text Available

1991-09-01

202

Kinetics of carbon dioxide absorption in solutions of methyldiethanolamine  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the reaction of carbon dioxide in MDEA solutions were studied both experimentally and theoretically. It is concluded that MDEA acts as a homogeneous catalyst for CO/sub 2/ hydrolysis, and as a result the rate of absorption in aqueous MDEA solutions is significantly larger than one would calculate by simply taking into account the alkalinity of the reaction. A possible zwitterion mechanism is proposed for this reaction. The minor effect of ionic strength were also studied with the presence of other ions. 19 references, 6 figures.

1985-01-01

203

Kinetic Parameters of Efflux of Penicillins by the Multidrug Efflux Transporter AcrAB-TolC of Escherichia coli?  

UK PubMed Central (United Kingdom)

The multidrug efflux transporter AcrAB-TolC is known to pump out a diverse range of antibiotics, including β-lactams. However, the kinetic constants of the efflux process, needed for the quantitative...Full Text Available

2010-05-01

204

Higgs Chaotic Inflation  

CERN Document Server

We construct a chaotic inflation model in which the Higgs fields play the role of the inflaton in the singlet extension of the supersymmetric standard model. The key idea is to impose a shift symmetry on the D-flat direction Hu Hd in the Kahler potential. The model is a realization of the recently proposed running kinetic inflation, in which the coefficient of the kinetic term grows as the inflaton field. The inflaton potential depends on the structure of the Higgs sector. For instance, the inflaton potential is proportional to phi^{2/3} during inflation in the NMSSM.

2010-01-01

205

Heat and Kinetic Theory in 19th-Century Physics Textbooks The Case of Spain  

CERN Document Server

Spain was a scientifically backward country in the early 19th-century. Thecauses were various political events, the War of Independence, and the reign ofFernando VII. The introduction of contemporary physics into textbooks wastherefore a slow process. An analysis of the contents of 19th-century Spanishtextbooks is here presented, centred on imponderable fluids, the concept ofenergy, the mechanical theory of heat, and the kinetic theory of gases.

2001-01-01

206

Dendrite spacings in directionally solidified superalloy PWA-1480  

Energy Technology Data Exchange (ETDEWEB)

Primary dendrite spacings and side-branch coarsening kinetics were examined in specimens of the single-crystal multicomponent commercial superalloy PWA-1480, which were directionally solidified in a psoitive thermal gradient. The experimentally observed dependence of primary dendrite spacings and side-branch coarsening kinetics on growth rate and thermal gradient were in agreement with the behavior predicted by analytical models developed for binary alloys. (orig.).

1991-02-01

207

A phenomenological analysis of sintering kinetics of alumina  

Energy Technology Data Exchange (ETDEWEB)

In this paper a phenomenological analysis of the sintering kinetics of alumina powder compacts with different proportions of small and large particles has been made. A phenomenological approach enables definition of functional connections between parameters characteristic of a certain material and the sintering time. A phenomenological equation is defined, which can be used to describe the densification process of alumina during isothermal sintering. Its parameters enable identification of the dominant diffusion mechanism. (orig.)

2004-07-01

208

A kinetic study of ozone and nitric oxides in dielectric barrier discharges for O_2/NO_x mixtures  

International Nuclear Information System (INIS)

A simple model is described to simulate kinetic processes in dielectric barrier discharges for O_2/NO_x mixtures. A threshold of ozone production found experimentally is confirmed by the calculations of this modeling, and the underlying chemical reaction mechanisms are discussed. It is also found that the effects of diffusion processes in the period of the lifetime of O atoms are not important to micro-discharge channels with a large radius, i.e. larger than 150 #mu#m

2002-04-01

209

Non-isothermal oxidation of ceramic nanocomposites using the example of Ti-Si-C-N powder: Kinetic analysis method  

Energy Technology Data Exchange (ETDEWEB)

A method of kinetic analysis applicable to non-isothermal oxidation processes of ceramic nanocomposites is presented using Ti-Si-C-N powder as the substrate. The nanoparticle size and phase composition were determined using high-resolution transmission electron microscopy and X-ray diffraction (XRD). Thermogravimetric measurements were carried out for powder samples in dry air in the temperature range 298-1770 K. The following heating rates were applied: 3, 5, 10, 20 K min{sup -1}. Mass spectrometry was used to analyze gaseous oxidation products and solid products were identified by the XRD technique. The Coats-Redfern equation was applied for the kinetic analysis. For each stage of the oxidation kinetic models, the best accuracy was achieved using a series of criteria, and then the A and E parameters of the Arrhenius equations were estimated. Both linear regression and artificial neural networks were applied in testing ...

2008-08-15

210

Kinetics of self-interstitial cluster aggregation near dislocations and their influence on hardening  

International Nuclear Information System (INIS)

Kinetic Monte Carlo (KMC) computer simulations are performed to determine the kinetics of SIA cluster 'clouds' in the vicinity of edge dislocations. The simulations include elastic interactions amongst SIA clusters, and between clusters and dislocations. Results of KMC simulations that describe the formation of 'SIA clouds' during neutron irradiation of bcc Fe and the corresponding evolution kinetics are presented, and the size and spatial distribution of SIA clusters in the cloud region are studied for a variety of neutron displacement damage dose levels. We then investigate the collective spatio-temporal dynamics of SIA clusters in the presence of internal elastic fields generated by static and mobile dislocations. The main features of the investigations are: (1) determination of the kinetics and spatial extent of defect clouds near static dislocations; (2) assessment of the influence of localized ...

2009-08-01

211

Watching Systems in graphs: an extension of Identifying Codes  

CERN Document Server

We introduce the notion of watching systems in graphs, which is a generalization of that of identifying codes. We give some basic properties of watching systems, an upper bound on the minimum size of a watching system, and results on the graphs which achieve this bound; we also study the cases of the paths and cycles, and give complexity results.

2010-01-01

212

The effect of the Sep wind park near Oosterbierum, Friesland, The Netherlands, on birds. De invloed van de Sep-proefwindcentrale te Oosterbierum (Friesland) op vogels; Deel 3: Aanvlieggedrag overdag  

Energy Technology Data Exchange (ETDEWEB)

The study concerns 1984-1991. The wind park consists of 18 three-bladed 300 kW horizontal axis wind turbines of 35 meters height, and a rotor diameter of 30 meters, seven meteorological towers, and three cluster and control buildings. Aspects studied included disturbance of breeding, resting or feeding, and migrating birds, behavior of birds approaching the wind turbines during the day and night, and bird victims due to collision with the wind turbines and the meteorological towers. The flight behavior of birds approaching the wind park system during daylight is also dealt with. For at least a fifth of the observations it was noted whether the birds passing within 100 meters distance of a turbine showed a reaction or not. The proportion of the reactions was related to the wind park in operation or not in operation, and to the distance between the wind turbines, species, flight height, the passing distance, wind direction and wind force. Secondly the flight path of ...

1992-01-01

213

Scots seek soft path  

International Nuclear Information System (INIS)

Energy policy is discussed, with particular reference to Scotland. The plans for nuclear power are analyzed in comparison with developments in coal mining, use of oil and gas and other possible energy sources such as wind and wave power. Arguments against the development of nuclear power are raised on grounds of economics, employment potential, and problems of waste disposal. (U.K.).

1979-03-01

214

New concept in transmission line reclosure using high-frequency fault transients  

Energy Technology Data Exchange (ETDEWEB)

The authors present a new concept: 'adaptive optimal reclosure' under transmission line faults by integrating the adaptive and optimal reclosure techniques. Simulation studies prove that the proposed technique is able to first detect the persistence time of fault path arc and then capture the optimal reclosure time, thereby enhancing system stability. (author)

1997-07-01

215

Influence of rotation on the initial state of the Universe  

Energy Technology Data Exchange (ETDEWEB)

We apply Hawking's proposal for the initial state of the Universe to a rotating Bianchi type-IX minisuperspace model in order to examine the problem of rotation in a closed cosmology. Using the Feynman path-integral techniques instead of the Wheeler-DeWitt equation, we are able to say that for a small angular velocity the closed Friedmann-Robertson-Walker model is indeed the most probable initial state for the Universe.

1989-12-15

216

Influence of rotation on the initial state of the Universe  

International Nuclear Information System (INIS)

We apply Hawking's proposal for the initial state of the Universe to a rotating Bianchi type-IX minisuperspace model in order to examine the problem of rotation in a closed cosmology. Using the Feynman path-integral techniques instead of the Wheeler-DeWitt equation, we are able to say that for a small angular velocity the closed Friedmann-Robertson-Walker model is indeed the most probable initial state for the Universe.

217

Identification of source and recharge zones in an aquifer system from water stable isotope. Case Study Bajo Cauca Antioqueno  

International Nuclear Information System (INIS)

Hydrology and hydrogeochemical are auxiliary techniques to valid conceptual hydrogeology an recharge models. Stable isotopes from water trace sources and path flow and Tritium indicates age. This paper is about the use of D 18, D2H y 3H to study the aquifer system on Bajo Cauca antioqueno.

218

Halflives of rp-Process Waiting Point Nuclei  

Energy Technology Data Exchange (ETDEWEB)

The fragment separator at GSI, Darmstadt, has been used to produce and separate very proton rich nuclei in the {sup 100}Sn region. By fragmentation of a {sup 112}Sn beam at 1 A{center_dot}GeV we produced nuclei along the rp-process path between {sup 77}Y and {sup 98}In. By implanting these ions into a silicon detector stack we were able to determine their halflives. Preliminary data are presented.

1999-12-31

219

Gravity settling  

Science.gov (United States)

Solids are separated from a liquid in a gravity settler provided with inclined solid intercepting surfaces to intercept the solid settling path to coalesce the solids and increase the settling rate. The intercepting surfaces are inverted V-shaped plates, each formed from first and second downwardly inclined upwardly curved intersecting conical sections having their apices at the vessel wall.

1979-01-01

220

Fuel injector  

Energy Technology Data Exchange (ETDEWEB)

A fuel injector comprises first and second housing parts, the first housing part being located within a bore or recess formed in the second housing part, the housing parts defining therebetween an inlet chamber, a delivery chamber axially spaced from the inlet chamber, and a filtration flow path interconnecting the inlet and delivery chambers to remove particulate contaminants from the flow of fuel therebetween.

2001-02-27

221

Fuel ignition by high voltage capacitive discharges  

Energy Technology Data Exchange (ETDEWEB)

The study examined the possibility for fuel ignition by spark discharge caused by induction effects under high voltage transmission lines. Theoretical background information on capacitive spark discharges and fuel ignition processes is given. Laboratory experiments were conducted to test the dependence of fuel ignition on three parameters: impedance in discharge path, multiple discharges, and larger electrode shapes. The results of these tests are discussed in terms of fuel ignition possibilities under high voltage transmission lines.

1983-03-01

222

Feynman rules for gauge fields in the presence of a dielectric medium  

Energy Technology Data Exchange (ETDEWEB)

T. D. Lee's method for developing the Feynman rules for gauge fields in a cavity is reformulated in terms of path integral. His work is then extended by deriving these rules, in the Feynman gauge, for a spherical cavity. In any gauge only the gauge particle propagator is altered, while all the Feynman rules for gauge field couplings are left unaltered by the presence of a dielectric medium.

1983-10-15

223

Experimental and evaluated nuclear plus interference cross sections for light charged particles  

Energy Technology Data Exchange (ETDEWEB)

Experimental and evaluated integral parameters derived from nuclear plus interference differential elastic scattering cross sections are presented for all projectile/target combinations of the particles p, d, t, /sup 3/He, and ..cap alpha... The data include reaction rates, average fractional energy losses per collision and per unit path length, and average laboratory scattering cosines. The resulting parameters are of potential use in analysis of charged-particle transport.

1980-07-04

224

Device for marking and searching for information on a magnetic carrier  

Science.gov (United States)

A device for marking and searching for information on a magnetic carrier is described. In order to increase the noise immunity and reliability of the data recording and reading paths, the recording head is included between the amplifier of the clock pulses for the master oscillator and through the amplifier of the code pulses for the logical element unit. The reproduction head is connected through the code pulse shaper-amplifier with a switch which is connected with the display unit, and through another analogous clock pulse amplifier with a multivibrator.

1984-03-01

225

CLIC High-Gradient Test Results  

CERN Document Server

The CLIC (Compact Linear Collider) high-gradient RF structure testing program has been carried out in order to gain insight into the physical processes involved in RF breakdown, determine the mechanisms that limit gradient and produce damage so that technical concepts can be developed which allow higher accelerating gradients. Two main paths towards higher gradients have emerged from this program, and the performances of two new structures which incorporate them are presented.

2002-01-01

226

Adiabatic theory of Wannier threshold laws and ionization cross sections  

Energy Technology Data Exchange (ETDEWEB)

The Wannier threshold law for three-particle fragmentation is reviewed. By integrating the Schroedinger equation along a path where the reaction coordinate R is complex, anharmonic corrections to the simple power law are obtained. These corrections are found to be non-analytic in the energy E, in contrast to the expected analytic dependence upon E.

1994-12-31

227

A New DC Breaker Used as Metallic Return Transfer Breaker.  

Energy Technology Data Exchange (ETDEWEB)

When a bipolar HVDC transmission system is operating monopolar using the earth as a return path, it is often desired to divert the return current from the earth to the line from the unused pole. To do so requires either that the system be shut down temporarily or that a dc circuit breaker be used. This paper describes the development of such a new dc circuit breaker, and its application on the Pacific Intertie as a Metallic Return Transfer Breaker (MRTB).

1982-10-01

228

Multiphasic helical Computed Tomography of hepatocellular carcinoma. Evaluation after various percutaneous ablation procedures; Tomografia Computerizzata spirale multifasica dell'epatocarcinoma. Valutazione dopo differenti procedure ablative percutanee  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to report the personal experience with helical CT evaluation of hepatocellular carcinoma treated with various percutaneous interventional procedures. From December 1996 to September 1998 it were examined with helical CT 41 patients (73 nodules in all) with hepatocellular carcinoma treated with percutaneous ablation therapies: conventional ethanol injection in 18 subjects (31 nodules), one-shot ethanol injection 3 (8 nodules), radiofrequency thermal ablation in 16 (25 nodules), and combined chemo embolization and ethanol injection in 4 (9 nodules). CT performed was 4-27 days after the last session, acquiring biphasic volumetric images in 14 patients and triphasic volumetric images in 27. A second treatment with subsequent CT study was performed for 28 lesions; 15 underwent 3 serial studies and 6 underwent 4 studies. Compared with pretreatment findings, the diameter was unchanged in 62% of the nodules and increased in 38%. Morphology was unchanged in 63% of ...

1999-12-01

229

Summary of Omega West Reactor, Level 1, probabilistic risk assessment  

International Nuclear Information System (INIS)

This paper reports on a Level 1 PRA performed on the Omega West Reactor at Los Alamos National Laboratory. A Master Logic Diagram was used to identify possible initiating events. A chi-square distribution was used to quantify initiating event frequencies given that no initiating events have occurred in 30 years of OWR operation. The PRA results are presented as both probability density function and cumulative distribution function curves.

1990-10-04

230

Secondary co-refining of petroleum and coal distillates, and the evaluation of coal cleaning in coal liquefaction  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a research and development project to quantify the effects of cleaning the coal feed on the yield patterns and processing rates for the Liquid Solvent Extraction (LSE) direct coal liquefaction process and to obtain information on the effect of the co-refining of coal-derived and petroleum distillates to premium transport fuels. 6 refs., 25 figs., 40 tabs.

1992-12-31

231

Quantifying octahedral rotations in strained perovskite oxide films.  

Energy Technology Data Exchange (ETDEWEB)

We have measured the oxygen positions in LaNiO{sub 3} films to elucidate the coupling between epitaxial strain and oxygen octahedral rotations. The oxygen positions are determined by comparing the measured and calculated intensities of half-order Bragg peaks, arising from the octahedral rotations. Combining ab initio density-functional calculations with these experimental results, we show how strain systematically modifies both bond angles and lengths in this functional perovskite oxide.

2010-07-20

232

Petroleum waxes in solvent systems  

Energy Technology Data Exchange (ETDEWEB)

Wax appearance temperature (WAT) of three petroleum waxes in different solvent systems under varying thermal conditions has been determined. It is observed that this temperature mainly is a function of the concentration of the wax and the solubility parameter ([delta]) of the solvent taken. This dependence of WAT has been quantified in terms of these variables in the form of mathematical equation and nomographs. (orig.)

1994-01-01

233

PIXE analysis of trace elements in relation to chlorophyll concentration in Plantago ovata Forsk  

Energy Technology Data Exchange (ETDEWEB)

Plantago ovata Forsk - an economically important medicinal plant - was analyzed for trace elements and chlorophyll in a study of the effects of gamma radiation on physiological responses of the seedlings. Proton-induced X-ray emission (PIXE) technique was used to quantify trace elements in unirradiated and gamma-irradiated plants at the seedling stage. The experiments revealed radiation-induced changes in the trace element and chlorophyll concentrations.

2010-03-15

234

Measurement and apportionment of radon source terms for modeling indoor environments  

Energy Technology Data Exchange (ETDEWEB)

This research has two main goals; (1) to quantify mechanisms for radon entry into homes of different types and to determine the fraction of indoor radon attributable to each source and (2) to model and calculate the dose (and therefore alpha particle fluence) to cells in the human and animal tracheobronchial tree that is pertinent to induction of bronchogenic carcinoma from inhaled radon daughters.

1990-01-01

235

Levels and distribution of BCNU in GBM tumors following intratumoral injection of DTI-015 (BCNU-ethanol)  

UK PubMed Central (United Kingdom)

The alkylation products formed by in vitro treatment of DNA with tritium-labeled 1,3-bis(2-chloroethyl)-1-nitrosourea (3H-BCNU) were identified and quantified. Twelve adducts were resolved...Full Text Available

2007-01-01

236

Experts' discussion on the possibility of quantification of the radiation hazard  

International Nuclear Information System (INIS)

Due to the intensity and vast number of subjects, this Bremen experts' discussion, too, could discuss only part of the problem of the possibilitiy to quantify the radiation hazard. One preliminary result is that there is no scientific proof of the harmlessness of radiation exposure during normal operation of a nuclear power plant, either within the plant or in its vicinity. Other results are that some important questions can not be answered yet, and that there are important hints on the dangers even of low radiation doses. (GL).

1978-01-01

237

Effects of 2 commercially-available 9-way killed vaccines on milk production and rectal temperature in Holstein-Friesian dairy cows.  

UK PubMed Central (United Kingdom)

Veterinarians and farmers employing multivalent killed vaccines in lactating dairy cows have reported transient losses in milk production. Few studies have quantified this loss. In this report, effects...Full Text Available

2001-10-01

238

Effectiveness of information provision in reducing risks to the environment  

Environmental Research Database

DescriptionAs part of a wider effort to develop new approaches to evaluating and quantifying the benefits of chemicals regulation, this project will review the effectiveness of existing information provision tools (such as classification and labelling for hazardous properties) in terms of affecting user behaviour. As some EC legislation relating to regulation of chemicals has been in place for some time, an assumption is made that the information provided by it is leading to an improvement in the way chem [continued...

2005-01-30

239

Complex fractal dimensions describe the hierarchical structure of diffusion-limited-aggregate clusters  

Energy Technology Data Exchange (ETDEWEB)

We analyze large diffusion-limited aggregates and uncover a {ital discrete} scaling invariance in their inner structure, which can be quantified by the introduction of a set of {ital complex} fractal dimensions. We provide a theoretical framework and prediction of their values based on renormalization group theory and a previous wavelet analysis. {copyright} {ital 1996 The American Physical Society.}

1996-01-01

240

Clinical helical tomotherapy commissioning dosimetry  

International Nuclear Information System (INIS)

Helical tomotherapy presented many unique dosimetric challenges and solutions during the initial commissioning process, and some of them are presented. The dose calculation algorithm is convolution/superposition based. This requires that the energy fluence spectrum and magnitude be quantified. The methodology for doing so is described. Aspects of the energy fluence characterization that are unique to tomotherapy are highlighted. Many beam characteristics can be measured automatically by an included megavoltage computed tomography imaging system. This greatly improves data collection efficiency.

2003-12-01

241

Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors  

Energy Technology Data Exchange (ETDEWEB)

This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of ...

2008-03-31

242

The silver catalyst process for converting methanol to formaldehyde - kinetic investigations  

Energy Technology Data Exchange (ETDEWEB)

In pre-experiments a tubular reactor was checked whether it is suitable for kinetic measurement on the system of the silver-catalysed partial oxidation of methanol to formaldehyde. Detrimental effects of heat-transfer and mass-transfer on the experimental results were ruled out. Investigations on the characteristics of the reaction showed that it is possible to manipulate the composition of the product mixture by changing the inlet concentration of the reactants. A modified power-law model was established to describe the reaction kinetics. It considers the preadsorption step of oxygen on the catalysts surface and fits the experimental data quite well. During the rapid oxidation the catalysts surface undergoes a drastic change. It gets coarse and has an adsorption capacity of 11 m{sup 2}/g after being exposed to the reaction mixture. (orig.)

1998-12-31

243

Summary of denting mechanism and kinetic studies with seawater  

International Nuclear Information System (INIS)

Studies at Commissariat a l'Energie Atomique (CEA) have been under way for three years in an attempt to find methods for preventing and stopping denting. Tests have been performed in 28 model boilers (Ajax with U tubes and Clarinette with straight tubes). In these boilers, with continous injection and blowdown, and heat flux is about 40 W X cm"-"2 (126900 Btu/ft"2 X h). The kinetics of denting has been studied with different levels of faulting. Some high-temperature electrochemical measurements established the mechanism of denting in the boiler tests. Denting kinetics can be rationalized in terms of three main parameters: faulting level, heat flux, and relative mechanical strength of the tube compared to the support plate.

244

Sorption of Brilliant Red HE-3B Reactive Dye from Aqueous Solution onto Seashells Waste: Equilibrium and Kinetic Studies  

British Library Electronic Table of Contents (United Kingdom)

The potential of waste seashells powder, as a new adsorbent for Brilliant Red HE-3B reactive dye removal from aqueous solutions, was examined by the batch technique. The Freundlich, Langmuir, and Dubinin-Radushkevich adsorption models were applied to describe the equilibrium sorption data and to determine the corresponding isotherm constants. The values of the thermodynamic parameters, ?G, ?H, and ?S, indicate that the sorption of reactive dye is a spontaneous and endothermic process. The kinetic data evaluated by pseudo-first order, pseudo-second order, and intraparticle diffusion kinetic models suggested that the sorption of reactive dye onto seashell is a complex process and both surface sorption and intraparticle diffusion contributes to the rate limiting step.

2011-01-01

245

Simultaneous ozonation kinetics of phenolic acids present in wastewaters  

Energy Technology Data Exchange (ETDEWEB)

Among the several chemical processes conducted for the removal of organic matter present in wastewaters coming from some agro-industrial plants (wine distilleries, olive oil mills, etc), the oxidation by ozone has shown a great effectiveness in the destruction of specially refractory pollutants: it is demonstrated that the biodegradability of those wastewaters increases aflcer an ozonation pretreatment. Their great pollutant character is imputed to the presence of some organic compounds, like phenols and polyphenols, which are toxic and inhibit the latter biological treatments. In this research, a competitive kinetic procedure reported by Clurol and Nekouinaini is applied to determine the degradation rate constants by ozone of several phenolic acids which are present in the wastewaters from the olive oil obtaining process. The resulting kinetic expressions for the ozonation reactions are useful for the successful design and operation of ozone ...

1996-12-31

246

Radiochemical investigation of chalcogenide films. XI. Method for investigating sorption kinetics without separation of the phases  

Energy Technology Data Exchange (ETDEWEB)

The design of a reaction cell which permits the investigation of the sorption kinetics of microcomponents without separation of the phases under automated condition has been described. The use of thin-layer inorganic sorbents obtained by depositing films of a sorbing substance from aqueous solutions on flat substrates of small thickness makes it possible to determine the extent of sorption even at small values in the case of /beta/ emitters with a low energy and /alpha/ emitters. Detailed observation of the kinetics of isotopic exchange in the CdS-/sup 115m/Cd-HNO/sub 3/ system has made it possible to reveal at least four stages in the process during the time of observation.

1988-09-01

247

Precipitation mechanisms and subsequent hardening kinetics in the #beta#-CEZ alloy  

International Nuclear Information System (INIS)

The #beta#-CEZ alloy : Ti-5%Al-2%Sn-4%Zr-4%Mo-2%Cr-1%Fe is a near #beta# titanium alloy. Since its processing routes include heat treatment (consisting of solution treatment and ageing), it has been decided to study the influence of the #beta# phase stability on #alpha# phase precipitation and hardening kinetics. Small sized specimens, coming from industrial heats, have been heat treated above and below the #beta# transus, and then water quenched. Therefore, several degree of #beta# stability are obtained. When it is increased (i.e. the solution treatment temperature is lowered), #alpha# or #omega# phases precipitations are delayed, as well as the hardening phenomena. Moreover, the #omega# stability domain is reduced. The mechanisms of #alpha# or #omega# precipitation are discussed, and related to the hardening kinetics. (orig.).

248

Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies  

British Library Electronic Table of Contents (United Kingdom)

A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function...

2011-01-01

249

Lipase-mediated hydrolysis of corn DDGS oil: Kinetics of linoleic acid production  

British Library Electronic Table of Contents (United Kingdom)

In this study, we investigated the kinetics of linoleic acid production via lipase-mediated hydrolysis of corn DDGS oil in a batch reactor with continuous mechanical agitation and developed a kinetic model that incorporated the product inhibition to study the complete hydrolysis. The model agreed very well with observed data; though situations with low enzyme dosage or low stirring rates were modeled successfully without product inhibition, actual product concentration in such situations was too low to exert any inhibitory effects. Increasing the enzyme concentration increased hydrolysis, and beyond certain enzyme concentrations, effects tended to fade away because of excessive enzyme desorption from the interface. An enzyme dosage within the range of 40-60KLU/L of oil dispersion could be ...

2010-01-01

250

Kinetics of uranium (VI) ions adsorption on activated charcoal from aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

The temperature and concentration dependence of the kinetics of uranium(VI) ions adsorption onto activated charcoal from aqueous solutions has been studied. The adsorption proceeds via a rather fast stage followed by a slower one, with activation energies of 5.41 and 17.46 kJ . mol[sup -1] respectively. The diffusion of uranium ions into the pores of the activated charcoal controls the kinetics of adsorption which follows the Langmuir isotherm equation in the concentration range studied. The adsorption equilibrium constant k[sub c] has been derived at temperatures between 283 K and 323 K as well as [Delta] G, [Delta] H and [Delta] S. The results indicate that the adsorption of uranium ions on activated charcoal is an endothermic process. (orig.)

1994-01-01

251

Kinetics of the methylparathion hydrolysis in aqueous medium; Cinetica de la hidrolisis del metilparation en medio acuoso  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of alkaline hydrolysis of methylparathion was studied at different temperatures (0-50 Centigrade) in the p H range of 8-12 by ultraviolet-visible absorption spectroscopy. Optimum p H and wavelength conditions were defined to carry out the simultaneous determination of methylparathion and one of its hydrolysis product, paranitrophenol, in buffered aqueous medium. Based on the experimental data and the mathematical equation of the kinetics, a rate constant (k) of first-order and an activation energy (Ea) of 9.2 Kcal/mol, were estimated. (Author) activation energy (Ea) of 9.2 Kcal/mol, were estimated. (Author)

1997-12-31

252

Kinetic study of the cracking, isomerization, and disproportionation of n-heptane on a chromium-exchanged Y zeolite  

Science.gov (United States)

The kinetic rate constants for the cracking, isomerization, and disproportionation of n-heptane over a CrHNaY (32% chromium exchanged) zeolite catalyst at 400, 450, and 470/sup 0/C have been calculated. The interaction of n-heptane with a model Lewis acid such as BF/sub 3/ and progress along the reaction coordinate have been studied by means of molecular orbital calculations. From the kinetic results, i.e., activation energies and frequency factors, and the theoretical calculations, it can be concluded that the controlling step in these reactions is not the formation of the carbonium ion, but the subsequent transformation of this carbonium ion. In addition, the theoretical calculations show that the attack of a Lewis acid is more likely to occur on a carbon atom than on a C-H bond.

1982-09-01

253

Jets and accretion processes in Active Galactic Nuclei further clues  

CERN Document Server

We present evidence in favour of a link between the luminosity radiatively dissipated in the central engine of radio-loud Active Galactic Nuclei and the kinetic power in their jets. This piece of evidence is based on the relation we find between the luminosity in broad emission lines and the kinetic power in pc-scale radio jets, for a sample of radio-loud quasars for which suitable data are available in the literature. We find that the ionizing luminosity and the kinetic one are of the same order of magnitude, suggesting that the processes responsible for them are somehow related. A strong magnetic field in equipartition with the radiation field could be responsible for regulating both processes. BL Lac objects seem to follow a similar behaviour, but with comparatively fainter broad line emission.

1996-01-01

254

First-order kinetics-controlled multiple species reactive transport of dissolved organic compounds in groundwater: Development and application of a numerical model  

Energy Technology Data Exchange (ETDEWEB)

Reactive chemical transport models developed over the past decade have generally relied on the assumption that local thermodynamic equilibrium is achieved at all times between aqueous species in a given system. Consequently, homogeneous aqueous systems characterized by a number of kinetically slow reactions, particularly problems involving organic species, cannot be satisfactorily modeled. In this study, we present a prototype computer model, KINETRAN, which is designed to handle kinetically-controlled homogeneous reactions in the aqueous phase, along with the transport of the various species involved, through geologic media. 31 refs., 53 figs., 10 tabs.

1990-05-01

255

Final Report for Award DE-FG02-99ER54554 Kinetics of Electron Fluxes in Low-Pressure Nonthermal Plasmas  

Energy Technology Data Exchange (ETDEWEB)

This grant has focused on the study of several aspects of electron kinetics in low pressure plasmas. Entirely new effects arise from the fact that the electron kinetics is governed by non-local effects, in which the electron distribution function is not equilibrium with the local electric field but is governed by spatial transport effects. In this grant, we were able to demonstrate several previously un-studied effects which are a direct result of the nonlocal transport. These are: (1) The existence of a ''convective cell' in electron phase space. The phenomenon was observed and studied in CW plasma conditions. (2) The occurrence of non-collisional cooling of electrons through an effect known as ''diffusive cooling''.

2004-12-13

256

Desorption of b-carotene from mesoporous carbon coated monolith: Isotherm, kinetics and regeneration studies  

British Library Electronic Table of Contents (United Kingdom)

b-carotene, a natural antioxidant, beneficial form human health prospective. In this study we had examined the recovery of b-carotene form mesoporous carbon coated monolith (MCCM) by batch process. Desorption kinetics and isotherm studies were carried out by using n-hexane as an eluent. Isotherm studies showed better applicability of Langmuir model. The first-order two-compartment three-parameter kinetics model as a function of initial loading concentration and reaction temperature was applied. It was observed that b-carotene desorption process is controlled by both rapid and slow desorption. Results showed that the slow desorption fraction increases from 0.8446 to 0.9007 with increase in initial loading concentration from 10.83 to 39.72mg/g while, the slow desorption fraction decreases fr...

2011-01-01

257

Chemical kinetic modeling of chlorinated hydrocarbons under stirred-reactor conditions  

Energy Technology Data Exchange (ETDEWEB)

The combustin of chloroethane is modeled as a stirred reactor so that we can study critical emission characteristics of the reactor as a function of residence time. We examine important operating conditions such as pressure, temperature, and equivalence ratio and their influence on destructive efficiency of chloroethane and production of other chlorinated products. The model uses a detailed chemical kinetic mechanism that we have developed previously for C{sub 3} hydrocarbons. We have added to this mechanism the chemical kinetic mechanism for C{sub 2} chlorinated hydrocarbons developed by Senkan and coworkers. Some reactions have been added to Senkan's mechanism and some of the reaction-rate expressions have been updated to reflect recent developments in the literature. In the modeling calculations, sensitivity coefficients are determined to find which reaction-rate constants have the largest effect on destructive efficiency. 25 refs., ...

1990-10-04

258

Binary kinetics in the Y-Ba-Cu system. 1: Mixed powders  

International Nuclear Information System (INIS)

The kinetics of the reactions between mixed powders of BaCO_3 and CuO, as well as BaCO_3 and Y_2O_3, have been studied using DXRD techniques as a function of particle size, temperature, and CO_2 pressure. Except for initial nucleation phenomena, the reaction rates are governed by shrinking core behavior for BaCO_3 particle sizes between 6 and 33 #mu#m. During the initial stages of the reactions, the surface reaction kinetics are governing, whereas the diffusion of CuO, Y_2O_3, and CO_2 are limiting factors at later stages in the reactions. Quantitative conversion data were used to determine the values of the activation energies and the pertinent diffusivities in these systems.

259

Asymmetric Hydrogenation with Highly Active IndolPhos-Rh Catalysts: Kinetics and Reaction Mechanism  

British Library Electronic Table of Contents (United Kingdom)

The mechanism of the IndolPhos-Rh-catalyzed asymmetric hydrogenation of prochiral olefins has been investigated by means of X-ray crystal structure determination, kinetic measurements, high-pressure NMR spectroscopy, and DFT calculations. The mechanistic study indicates that the reaction follows an unsaturate/dihydride mechanism according to Michaelis-Menten kinetics. A large value of KM (KM=5.01+-0.16 M) is obtained, which indicates that the Rh-solvate complex is the catalyst resting state, which has been observed by high-pressure NMR spectroscopy. DFT calculations on the substrate-catalyst complexes, which are undetectable by experimental means, suggest that the major substrate-catalyst complex leads to the product. Such a mechanism is in accordance with previous studies on the mechanism...

2010-01-01

260

Aromatics oxidation and soot formation in flames. Progress report, August 15, 1993--June 30, 1994  

Energy Technology Data Exchange (ETDEWEB)

This project is concerned with the kinetics and mechanisms of aromatic oxidation and soot and fullerenes formation in flames. The objective of the aromatics oxidation work is to identify and measure the concentration of important intermediates and products in benzene oxidation, and to determine reaction mechanisms and kinetics properties consistent with the behavior seen in flames. The research on soot formation is concerned primarily with the particle inception stages, but the work includes study of soot structure at all stages of growth in order to obtain mechanistic information from evidence of growth steps recorded in the structure of the particles. The ultimate objective is to understand how nascent soot particles are formed from high molecular weight compounds, including the roles of planar and curved PAH and the relationship between soot and fullerenes. The objective of the proposed research on fullerenes is to develop a more ...

1994-10-01

261

p53 mutation in breast cancer. Correlation with cell kinetics and cell of origin  

UK PubMed Central (United Kingdom)

Aim: Several studies have investigated the expression of the cytokeratins (CKs), vimentin, the epithelial growth factor receptor (EGFR), the oestrogen receptor (ER), and the progesterone...Full Text Available

2002-06-01

262

X-ray stars in globular clusters  

Science.gov (United States)

The properties and kinetics of x-ray stars in globular clusters are described. Locations, configurations, star evolution, massive close binary systems, various mechanisms, and the x-ray burster properties are included. (JFP)

1977-10-01

263

Uracil-DNA glycosylase: Structural, thermodynamic and kinetic aspects of lesion search and recognition  

UK PubMed Central (United Kingdom)

Uracil appears in DNA as a result of cytosine deamination and by incorporation from the dUTP pool. As potentially mutagenic and deleterious for cell regulation, uracil must be removed from DNA....Full Text Available

2010-03-01

264

Theory of chemical reaction dynamics. Volume 3  

Energy Technology Data Exchange (ETDEWEB)

This book examines some of the basic principles behind chemical reaction kinetics. Topics considered include the classical trajectory approach to reactive scattering; periodic orbits and theory of reactive scattering; and semiclassical reactive scattering.

1985-01-01

265

The hemoglobins of the trematodes Fasciola hepatica and Paramphistomum epiclitum: A molecular biological, physico-chemical, kinetic, and vaccination study  

UK PubMed Central (United Kingdom)

The trematode Fasciola hepatica (Fa.he.) is a common parasite of human and livestock. The hemoglobin (Hb) of Fa.he., a potential immunogen, was chosen for characterization...Full Text Available

2008-10-01

266

The CO{sub 2} gasification kinetics of olive residue  

Energy Technology Data Exchange (ETDEWEB)

Orujillo, sometimes called wood matter from pressed oil-stone (WPOS) is a residue from the olive oil mill industry. The generation of this biomass residue is concentrated in small areas allowing its use as fuel for medium size gasification and combustion plants. Rates of gasification of WPOS char were measured in a TGA at various temperatures (800-850-875-900-950{sup o}C), CO{sub 2} partial pressures (0.20-0.35-0.50 bar) and CO partial pressures (0.0-0.20 bar). The experiments were carried out with a monolayer bed of very fine particles well exposed to the gas so as to minimise mass and heat transfer resistances. Two kinetic models, the nth order model and Langmuir-Hinshelwood model, have been used to fit with the reactivity data. For pure CO{sub 2} experiments the kinetic parameters of nth order model were E=133 kJ/mol and n=0.43. The Langmuir-Hinshelwood kinetic model clearly describes the observed CO inhibition effect on ...

2003-02-01

267

Sucrose Uptake by Sugar Beet Tap Root Tissue 1  

UK PubMed Central (United Kingdom)

Sucrose uptake by discs of mature sugar beet root tissue incubated in [14C]-sucrose exhibited nonsaturating kinetics over the concentration range of 1 to 500 millimolar. Uptake was inhibited...Full Text Available

1979-11-01

268

Sonic hedgehog controls growth of external genitalia by regulating cell cycle kinetics  

UK PubMed Central (United Kingdom)

During embryonic development, cells are instructed which position to occupy, they interpret these cues as differentiation programmes, and expand these patterns by growth. Sonic hedgehog...Full Text Available

2010-06-01

269

Short-term effects of tumor necrosis factor on energy and substrate metabolism in dogs.  

UK PubMed Central (United Kingdom)

In vivo short-term effects of recombinant human TNF-alpha on lipolysis, FFA flux, fat oxidation, triglyceride-fatty acid cycling, and glucose kinetics were evaluated with stable isotopic tracers and...Full Text Available

1993-06-01

270

STS-83 - Johnson Space Center - NASA  

Science.gov (United States)

Radiation Measurement in Crew Compartment. DTO 805: .... spacecraft and aircraft propulsion, and hazardous waste disposal. ...... combustion reactions in a turbulent chemical kinetic flow reactor using laser induced fluorescence and ...

271

Role of serum carrier proteins in the peripheral metabolism and tissue distribution of thyroid hormones in familial dysalbuminemic hyperthyroxinemia and congenital elevation of thyroxine-binding globulin.  

UK PubMed Central (United Kingdom)

To investigate the role of thyroxine-binding globulin (TBG) and albumin in the availability of thyroid hormones to peripheral tissues, comprehensive kinetic studies of thyroxine (T4) and triiodothyronine...Full Text Available

1987-08-01

272

Rheological Characterization of in situ Crosslinkable Hydrogels Formulated from Oxidized Dextran and N-Carboxyethyl Chitosan  

UK PubMed Central (United Kingdom)

The gelation kinetics of an in situ gelable hydrogel formulated from oxidized dextran (Odex) and N-carboxyethyl chitosan (CEC) were investigated rheologically. Both Schiff base...Full Text Available

2007-04-01

273

Physiological calcium concentrations regulate calmodulin binding and catalysis of adenylyl cyclase exotoxins  

UK PubMed Central (United Kingdom)

Edema factor (EF) and CyaA are calmodulin (CaM)-activated adenylyl cyclase exotoxins involved in the pathogenesis of anthrax and whooping cough, respectively. Using spectroscopic, enzyme kinetic and...Full Text Available

2002-12-16

274

On the Uptake of Materials by the Intact Liver. THE TRANSPORT AND NET REMOVAL OF GALACTOSE  

UK PubMed Central (United Kingdom)

D-galactose, a monosaccharide rapidly phosphorylated within liver cells, is irreversibly removed from the portal circulation. We have studied the kinetic relations between the hepatic cell entry process...Full Text Available

1973-05-01

275

On the Uptake of Materials by the Intact Liver THE CONCENTRATIVE TRANSPORT OF RUBIDIUM-86  

UK PubMed Central (United Kingdom)

In this study we use the multiple indicator dilution technique to outline the kinetic mechanisms underlying the uptake of rubidium, a cation which, in the steady state, is concentrated by hepatic parenchymal...Full Text Available

1973-05-01

276

Nitrite Uptake into Intact Pea Chloroplasts 1  

UK PubMed Central (United Kingdom)

The uptake of nitrite into intact pea chloroplasts was observed and its relationship with internal nitrite reduction was assessed. Net nitrite uptake exhibited saturation kinetics and an alkaline pH...Full Text Available

1988-02-01

277

Molecular and Kinetic Comparison of the Novel Extended-Spectrum ?-Lactamases CTX-M-25 and CTX-M-26  

UK PubMed Central (United Kingdom)

CTX-M-25 is a novel extended-spectrum β-lactamase isolated from a single Canadian Escherichia coli isolate. Susceptibility testing demonstrated that this enzyme confers resistance...Full Text Available

2004-12-01

278

Microstructural transformations and kinetics of high-temperature heterogeneous gasless reactions by high-speed x-ray phase-contrast imaging  

Science.gov (United States)

Heterogeneous gasless reactive systems, including high-energy density metal-nonmetal compositions, have seen increasing study due to their various applications. However, owing to their high reaction temperature, short reaction time, and small scale of heterogeneity, investigation of their reaction mechanisms and kinetics is very difficult. In this study, microstructural changes and the kinetics of product layer growth in the W-Si system was investigated using a high-speed x-ray phase-contrast imaging technique. Using the Advanced Photon Source of Argonne National Laboratory, this method allowed direct imaging of irreversible reactions in the W-Si reactive system at frame rates up to 36 000 frames per second with 4 {mu}s exposure and spatial resolution of 10 {mu}m. Details of the Si melt and reactions between W and Si, that are unable to be viewed with visible-light imaging, were revealed. These include processes such as the initiation of ...

2009-12-01

279

Microstructural transformations and kinetics of high-temperature heterogeneous gasless reactions by high-speed x-ray phase-contrast imaging  

International Nuclear Information System (INIS)

Heterogeneous gasless reactive systems, including high-energy density metal-nonmetal compositions, have seen increasing study due to their various applications. However, owing to their high reaction temperature, short reaction time, and small scale of heterogeneity, investigation of their reaction mechanisms and kinetics is very difficult. In this study, microstructural changes and the kinetics of product layer growth in the W-Si system was investigated using a high-speed x-ray phase-contrast imaging technique. Using the Advanced Photon Source of Argonne National Laboratory, this method allowed direct imaging of irreversible reactions in the W-Si reactive system at frame rates up to 36 000 frames per second with 4 #mu#s exposure and spatial resolution of 10 #mu#m. Details of the Si melt and reactions between W and Si, that are unable to be viewed with visible-light imaging, were revealed. These include processes such as the initiation of ...

2009-12-01

280

Kinetics of the Vacuolar H+-Pyrophosphatase 1  

UK PubMed Central (United Kingdom)

The responses of the vacuolar membrane (tonoplast) proton-pumping inorganic pyrophosphatase (H+-PPase) from oat (Avena sativa L.) roots to changes in Mg2+ and...Full Text Available

1992-12-01

281

Kinetics of nucleotide transport in rat heart mitochondria studied by a rapid filtration technique  

Energy Technology Data Exchange (ETDEWEB)

A rapid filtration technique has been used to measure at room temperature the kinetics of ADP and ATP transport in rat heart mitochondria in the millisecond time range. Transport was stopped by cessation of the nucleotide supply, without the use of a transport inhibitor, thus avoiding any quenching delay. The kinetics of ({sup 14}C)ADP transport in energized mitochondria were apparently monophasic. The rate of transport of ({sup 14}C)ATP in energized mitochondria was 5-10 times lower than that of ({sup 14}C)ADP. Upon uncoupling, the rate of ({sup 14}C)ATP uptake was enhanced, and that of ({sup 14}C)ADP uptake was decreased. However, the two rates did not equalize, indicating that transport was not exclusively electrogenic. Transport of ({sup 14}C)ADP and ({sup 14}C)ATP by resting mitochondria followed biphasic kinetics. Depletion of nucleotides in resting mitochondria resulted in a greater decrease in the extent of the slow ...

1990-10-01

282

Inhibition of beta-lactamase of Bacillus licheniformis 749/C by compound PS-5, a new beta-lactam antibiotic.  

UK PubMed Central (United Kingdom)

By use of a new computer-assisted u.v.-spectrophotometric assay method, the kinetic parameters of the reaction catalysed by Bacillus licheniformis 749/C beta-lactamase were re-examined and the mode...Full Text Available

1980-01-01

283

Including the relativistic kinetic energy in a spline-augmented plane-wave band calculation  

International Nuclear Information System (INIS)

The first-order relativistic correction to the kinetic energy of an electron, the mass-velocity term, is not bounded from below. It can, therefore, not be used within a variational framework. To overcome this deficiency we developed a method to include the entire relativistic kinetic energy #sq root#(p"2c"2+m_0"2c"4)-m_0c"2 in a spline-augmented plane-wave band calculation. The first results for silver are quite promising, especially for d and p states: The analysis of the energies of the core states as well as of the valence band structure suggests that the energies of d bands are reproduced within 1 mRy. However, the combination of the relativistic kinetic energy with the Darwin term leads to energies which are too low for s-like valence states by 10 mRy. Therefore, the s and d valence band complex is spread out and the Fermi level is lowered by the same amount as the s states. We expect to overcome these deficiencies in ...

284

In vitro selection of RNA molecules that displace cocaine from the membrane-bound nicotinic acetylcholine receptor  

UK PubMed Central (United Kingdom)

The nicotinic acetylcholine receptor (AChR) controls signal transmission between cells in the nervous system. Abused drugs such as cocaine inhibit this receptor. Transient kinetic investigations indicate...Full Text Available

1998-11-24

285

In vitro antigen-induced antibody responses to hepatitis B surface antigen in man. Kinetic and cellular requirements.  

UK PubMed Central (United Kingdom)

In this report we define the parameters of the human immune response after immunization with hepatitis B vaccine. 2 wk after booster immunization, there is significant spontaneous secretion of antibody...Full Text Available

1984-10-01

286

Image-based modeling of tumor shrinkage in head and neck radiation therapy1  

UK PubMed Central (United Kingdom)

Purpose: Understanding the kinetics of tumor growth∕shrinkage represents a critical step in quantitative assessment of therapeutics and realization of adaptive radiation therapy....Full Text Available

2010-05-01

287

Gas electrode reactions in molten carbonate media. Pt. 2. Oxygen reduction kinetics on conductive oxide electrodes in (Li+K)CO/sub 3/ eutectic at 650/sup 0/C  

Energy Technology Data Exchange (ETDEWEB)

The electrode kinetics for oxygen reduction on conducting metal oxides, including lithiated NiO (formed in situ) and Sb-doped SnO/sub 2/, have been investigated. Kinetic measurements were carried out by using ac impedance and coulostatic relaxation methods. The ac behavior on the oxide electrodes was analyzed on the basis of a modified Randles-Ershler type equivalent circuit which takes into account the effect of non-faradaic components due to the semiconducting oxide films. The kinetic parameters (the charge transfer resistance and Warburg coefficient) and the interfacial parameters (the double layer capacity, film capacity and film resistance) were obtained by a least squares curve fitting method under P/sub O2//P/sub CO2/=0.9/0.1 atmosphere. The exchange current density was found to be 10 to 20 mA cm/sup -2/ at the oxide electrodes, assuming n=2. The coulostatic relaxation experiments supported the magnitude of the i/sub ...

1986-01-01

288

Force enhancement without changes in cross-bridge turnover kinetics: the effect of EMD 57033.  

UK PubMed Central (United Kingdom)

The thiadiazinon derivative EMD 57033 has been found previously in cardiac muscle to increase isometric force generation without a proportional increase in fiber ATPase, thus causing a reduction in...Full Text Available

1997-01-01

289

Effect of naproxen on glucose metabolism and tolbutamide kinetics and dynamics in maturity onset diabetics.  

UK PubMed Central (United Kingdom)

1 The influence of the nonsteroidal anti-inflammatory drug naproxen on glucose metabolism and on tolbutamide pharmacokinetics and pharmacodynamics has been studied in ten maturity-onset diabetics. 2...Full Text Available

1981-03-01

290

Early inflammatory markers in elicitation of allergic contact dermatitis  

UK PubMed Central (United Kingdom)

BackgroundAllergic Contact Dermatitis (ACD) is regarded as a T-cell-mediated delayed-type hypersensitivity reaction. We studied the kinetics of the expression of CS-1 fibronectin,...Full Text Available

291

Dissolved Hydrocarbons and Related Microflora in a Fjordal Seaport: Sources, Sinks, Concentrations, and Kinetics  

UK PubMed Central (United Kingdom)

The continuous addition of toluene as a solute of treated ballast water from oil tankers into a well-defined estuary facilitated the study of the dynamics of dissolved hydrocarbon metabolism in seawater....Full Text Available

1981-10-01

292

Direct measurement of the alpha-epsilon transition stress and kinetics for shocked iron  

Energy Technology Data Exchange (ETDEWEB)

Iron undergoes a polymorphic phase transformation from alpha phase (bcc) to the epsilon phase (hcp) when compressed to stresses exceeding 13 CPa. Bccause the epsilon phase is denser than the alpha phase, a single shock wave is unstable and breaks up into an elastic wave, a plastic wave, and a phase transition wave. Examination of this structured wave coupled with various phase transformation models has been used to indirectly examine the transition kinetics. Recently, multimillion atom simulations (molecular dynamics) have been used to examine the shock-induced transition in single crystal iron illustrating an orientation dependence of the transition stress, mechanisms, and kinetics. The objective of the current work was to perform plate impact experiments to examine the shock-response of polycrystalline and single crystal iron with nanosecond resolution for impact stresses spanning the {alpha} - {epsilon} transition. The current data reveal an ...

2009-01-01

293

Development of a physiologically based pharmacokinetic model of trichloroethylene and its metabolites for use in risk assessment.  

UK PubMed Central (United Kingdom)

A physiologically based pharmacokinetic (PBPK) model was developed that provides a comprehensive description of the kinetics of trichloroethylene (TCE) and its metabolites, trichloroethanol (TCOH),...Full Text Available

2000-05-01

294

Computing the Partition Function for Kinetically Trapped RNA Secondary Structures  

UK PubMed Central (United Kingdom)

An RNA secondary structure is locally optimal if there is no lower energy structure that can be obtained by the addition or removal of a single base pair, where energy is defined according...Full Text Available

295

Cluster-assisted multiple ionization of methyl iodide by a nanosecond laser: Influence of laser intensity on the kinetic energy and peak profile of multicharged ions  

International Nuclear Information System (INIS)

The dependences of kinetic energies and peak profiles of multicharged ions of I "q"+ (q = 2-3) and C"2"+ on the laser intensity have been studied in detail by time-of-flight mass spectrometry, those multicharged ions are produced by irradiation of methyl iodide cluster beam with a nanosecond 532 nm Nd-YAG laser. Our experiments show that the kinetic energies released of multicharged ions increase linearly with the laser intensity in the range of 3 x 10"9-2 x 10"1"1 W/cm"2. The peaks of multicharged ions are split to forward ions and backward ions, and the ratio of the backward ions to forward ions decreases exponentially with laser intensity. The decreasing of backward ions is probably due to Coulomb scattering by the heavier I"+ ions when they turn around through the laser focus point. The linear dependence of kinetic energy of multicharged ions on laser intensity is interpreted by the ionization mechanism, in which the ...

2006-03-20

296

Characterization and catalytic oxidation activity of uranium-bismuth mixed oxides  

International Nuclear Information System (INIS)

Bi-U mixed oxides were synthesized by two methods and characterized by X-ray diffraction and X-ray photoelectron spectroscopy. The samples were tested for the catalytic oxidation of carbon monoxide by oxygen. A stepwise redox mechanism consistent with the kinetic results is proposed. (orig.).

297

Cell kinetics of growth cartilage of achondroplastic (cn) mice.  

UK PubMed Central (United Kingdom)

Mice homozygous for the recessive gene achondroplasia (cn) aged 16 and 17 days and some homozygotes aged 22-34 days have disruptions in the growth of the proximal tibial growth plate which are due solely...Full Text Available

1985-05-01

298

Capacity of deoxycytidine to selectively antagonize cytotoxicity of 5-halogenated analogs of deoxycytidine without loss of antiherpetic activity.  

UK PubMed Central (United Kingdom)

Enzyme kinetic studies from this laboratory (M. Dobersen and S. Greer, Biochemistry 17:920-928, 1978) suggested that deoxycytidine could antagonize the toxicity of 5-halogenated analogs of deoxycytidine...Full Text Available

1982-09-01

299

Calorimetric studies of the kinetic unfreezing of molecular motions in hydrated lysozyme, hemoglobin, and myoglobin.  

UK PubMed Central (United Kingdom)

Differential scanning calorimetric (DSC) studies of the glassy states of as-received and hydrated lysozyme, hemoglobin, and myoglobin powders, with water contents of < or = 0.25, < or...Full Text Available

1994-01-01

300

Biosorption of heavy metals by free and immobilised biomass  

Energy Technology Data Exchange (ETDEWEB)

A review of the research activities carried out by the authors on biosorption of heavy metals is reported in this work. In particular, biomass characterisation, biosorption equilibrium with single metal system, biomass immobilisation in polymeric matrix and related kinetics, biosorption in membrane reactor systems are the main aspects reported in the paper. (orig.)

2000-07-01

301

Biosorption of cadmium(II), zinc(II) and lead(II) by Penicillium simplicissimum: Isotherms, kinetics and thermodynamics  

Energy Technology Data Exchange (ETDEWEB)

The isotherms, kinetics and thermodynamics of Cd(II), Zn(II) and Pb(II) biosorption by Penicillium simplicissimum were investigated in a batch system. The effects of pH, initial metal ions concentration, biomass dose, contact time, temperature and co-ions on the biosorption were studied. Adsorption data were well described by both the Redlich-Peterson and Langmuir model. Chemical ion-exchange was found to be an important process based on free energy value from Dubini-Radushkevich isotherm for all metal ions. The results of the kinetic studies of all metal ions at different temperature showed that the rate of adsorption followed the pseudo second-order kinetics well. The thermodynamics constants {delta}G{sup o}, {delta}H{sup o} and {delta}S{sup o} of the adsorption process showed that biosorption of Cd(II), Zn(II) and Pb(II) ions on Penicillium simplicissimum were endothermic and spontaneous.

2008-12-30

302

Binding of a Fluorescent Lipid Amphiphile to Albumin and its Transfer to Lipid Bilayer Membranes  

UK PubMed Central (United Kingdom)

Kinetics and thermodynamics of the binding of a fluorescent lipid amphiphile, Rhodamine Green™-tetradecylamide (RG-C14:0), to bovine serum albumin were characterized in an equilibrium...Full Text Available

2003-01-01

303

Adaptation of a Foot Plate for Use in an Isokinetic and Isotonic Leg Press  

UK PubMed Central (United Kingdom)

The use of isokinetic equipment and the leg press exercise have been major components of rehabilitation for the past several years when redeveloping muscular strength. Recently, closed kinetic chain...Full Text Available

1996-04-01

304

Acetylcholine receptor kinetics. A description from single-channel currents at snake neuromuscular junctions.  

UK PubMed Central (United Kingdom)

Single-channel currents from acetylcholine receptor channels of garter snake neuromuscular junctions were recorded using the patch-clamp technique. Low concentrations of acetylcholine or carbamylcholine...Full Text Available

1982-09-01

305

A generalized Fisher equation and its utility in chemical kinetics  

UK PubMed Central (United Kingdom)

A generalized Fisher equation (GFE) relates the time derivative of the average of the intrinsic rate of growth to its variance. The GFE is an exact mathematical result that has been widely used in population...Full Text Available

2010-07-20

306

A Substructure Combination Strategy to Create Potent and Selective Transthyretin Kinetic Stabilizers that Prevent Amyloidogenesis and Cytotoxicity  

UK PubMed Central (United Kingdom)

Transthyretin aggregation-associated proteotoxicity appears to cause several human amyloid diseases. Rate-limiting tetramer dissociation and monomer misfolding of transthyretin (TTR) occur before...Full Text Available

2010-02-03

307

A Kinetic Model of Dopamine- and Calcium-Dependent Striatal Synaptic Plasticity  

UK PubMed Central (United Kingdom)

Corticostriatal synapse plasticity of medium spiny neurons is regulated by glutamate input from the cortex and dopamine input from the substantia nigra. While cortical stimulation alone results in long-term...Full Text Available

2010-02-01

308

[Experimental and kinetic modeling of acid/base and redox reactions over oxide catalysts  

Energy Technology Data Exchange (ETDEWEB)

The research has involved the characterization of catalyst acidity, [sup 2]D NMR studies of Bronsted acid sites, and kinetic, calorimetric, and spectroscopic studies of methylamine synthesis and related reactions over acid catalysts. Approach of this work was to explore quantitative correlations between factors that control the generation, type, strength, and catalytic properties of acid sites on zeolite catalysts. Microcalorimetry, thermogravimetric analysis, IR spectroscopy, and NMR spectroscopy have provided information about the nature and strength of acid sites in zeolites. This was vital in understanding the catalytic cycles involved in methylamine synthesis and related reactions over zeolite catalysts.

1993-01-01

309

Submonolayer nucleation and growth and the initial stage of multilayer kinetic roughening during Ag/Ag (100) homoepitaxy  

Energy Technology Data Exchange (ETDEWEB)

A comprehensive Scanning Tunneling Microscopy (STM) study of submonolayer nucleation and growth of 2D islands in Ag/Ag(100) homoepitaxy for temperature between 295K and 370K is presented. The initial stages of multilayer kinetic roughening is also studied. Analysis of an appropriate model for metal (100) homoepitaxy, produces estimates of 350 meV for the terrace diffusion barrier, 400 meV for the adatom bond energy, and 25 meV for the additional Ehrlich-Schwoebel step-edge barrier.

1996-08-01

310

Real-time neutron diffraction measurements of the kinetics of first-order phase transitions  

International Nuclear Information System (INIS)

The wide-angle neutron diffractometer recently installed at the HFIR has the capability of performing time-resolved or time-slicing measurements. One of the interesting problem areas the authors have explored using this time-slicing function of the diffractometer is the kinetics of structural changes occurring after a temperature jump across a value at which a first-order phase transition occurs. Two measurements of this sort have been carried out: the phase III to II transition in RbNO_3 and the transition between the alpha and beta phases in Sn.

1985-03-01

311

PAMELA results on the cosmic-ray antiproton flux from 60 MeV to 180 GeV in kinetic energy  

CERN Document Server

The satellite-borne experiment PAMELA has been used to make a new measurement of the cosmic-ray antiproton flux and the antiproton-to-proton flux ratio which extends previously published measurements down to 60 MeV and up to 180 GeV in kinetic energy. During 850 days of data acquisition approximately 1500 antiprotons were observed. The measurements are consistent with purely secondary production of antiprotons in the galaxy. More precise secondary production models are required for a complete interpretation of the results.

2010-01-01

312

Non-thermal plasma destruction of allyl alcohol in waste gas: kinetics and modelling  

International Nuclear Information System (INIS)

Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.

2008-02-01

313

Kinetics of the direct electric heating of a stationary bed of activated charcoal  

Energy Technology Data Exchange (ETDEWEB)

Direct electric heating by passing an electrical current directly through a bed of adsorbent may prove to be an efficient means of regenerating activated charcoal in continuous and batch adsorption processes. Obvious advantages of this type of regeneration are its almost complete lack of inertia, which makes it possible to reduce the number and dimensions of the adsorbers, and its highly efficient use of energy due to the small number of steps in the conversion of the energy, as well as the reduction of heat losses involved in warming the structure and making up for losses to the surroundings. The authors consider the kinetics of direct electric heating of a stationary bed of activated charcoal not containing adsorbed substances.

1987-08-20

314

Self-Interacting Dark Matter Halos and the Gravothermal Catastrophe  

CERN Document Server

We study the evolution of an isolated, spherical halo of self-interacting dark matter (SIDM) in the gravothermal fluid formalism. We show that the thermal relaxation time, $t_r$, of a SIDM halo with a central density and velocity dispersion of a typical dwarf galaxy is significantly shorter than its age. We find a self-similar solution for the evolution of a SIDM halo in the limit where the mean free path between collisions, $\\lambda$, is everywhere longer than the gravitational scale height, $H$. Typical halos formed in this long mean free path regime relax to a quasistationary gravothermal density profile characterized by a nearly homogeneous core and a power-law halo where $\\rho \\propto r^{-2.19}$. We solve the more general time-dependent problem and show that the contracting core evolves to sufficiently high density that $\\lambda$ inevitably becomes smaller than $H$ in the innermost region. The core undergoes secular collapse to a ...

2002-01-01

315

Proactive product and process qualification in steam turbine development; Proaktive Produkt- und Prozessqualifikation in der Dampfturbinenentwicklung  

Energy Technology Data Exchange (ETDEWEB)

Proactive qualification is today an integral part of the development process for steam turbines used in steam and combined cycle power plants. By providing experimentally based `random` variables, such as the steam path efficiency and blading reliability, it makes a valuable contribution to the economic `random` variables of the power plant, e.g. the rate of return, as viewed by the customer. One of the areas in which proactive product and process qualification plays an important role is the development of LP steam paths. (orig.) [Deutsch] Die proaktive Qualifikation ist heute fester Bestandteil des Entwicklungsprozesses bei Dampfturbinen, die fuer den Einsatz in Dampf- und Kombikraftwerken bestimmt sind. Sie leistet mit Hilfe experimentell ermittelter `Zufalls`-Variablen, wie z.B. Wirkungsgrad der Fluten und Zuverlaessigkeit der Beschaufelungen, einen wertvollen Beitrag zu den fuer die Kunden wichtigen wirtschaftlichen `Zufalls`-Variablen des ...

1998-10-01

316

Market-based pricing of wholesale electric services  

Energy Technology Data Exchange (ETDEWEB)

Traditionally, the Federal Energy Regulatory Commission has implemented its statutory requirement that wholesale electric rates be just and reasonable by comparing a seller's proposed rates to its own cost of service. In the last four years, 40 requests for market-based prices have opened up an alternate path for just and reasonable rates. The common characteristic of these 40 requests is that the price is not tied directly to the seller's own costs but rather to market conditions. To date, the Commission has approved 28 of these requests and rejected eight. Four are pending. In this paper the authors assess what has happened, and describe the common standards that have been developed on a case-by-case basis in the last four years. In particular, they examine how these standards have been applied in cases involving affiliates of traditional utilities. Finally, they discuss some of the unresolved issues and possible implications of the new ...

1991-12-01

317

Enhanced Genetic Algorithm approach for Solving Dynamic Shortest Path Routing Problems using Immigrants and Memory Schemes  

CERN Document Server

In Internet Routing, the static shortest path (SP) problem has been addressed using well known intelligent optimization techniques like artificial neural networks, genetic algorithms (GAs) and particle swarm optimization. Advancement in wireless communication lead more and more mobile wireless networks, such as mobile networks [mobile ad hoc networks (MANETs)] and wireless sensor networks. Dynamic nature of the network is the main characteristic of MANET. Therefore, the SP routing problem in MANET turns into dynamic optimization problem (DOP). Here the nodes ae made aware of the environmental condition, thereby making it intelligent, which goes as the input for GA. The implementation then uses GAs with immigrants and memory schemes to solve the dynamic SP routing problem (DSPRP) in MANETS. In our paper, once the network topology changes, the optimal solutions in the new environment can be searched using the new immigrants or the useful information stored in the ...

2011-01-01

318

Determination of seepage path in a river levee; Sulla determinazione della linea d'infiltrazione al'interno di un argine fluviale  

Energy Technology Data Exchange (ETDEWEB)

After a short review of the classical simplified expressions able to evaluate the seepage path in the core of a river levee, this paper first discusses the results obtained assuming the Dupuit approximation. Dimensionless nomographs are then showed, obtained by means of numerical integration of the seepage equations, These nomographs allow a quick levee design to be developed, after the definition of flood hydrography, seepage and embankment characteristics. [Italian] Dopo un sintetico richiamo di alcune classiche formulazioni semplificate per la determinazione dell'andamento della linea di infiltrazioner in un rilevato arginale, nell'articolo vengono presentati e discussi i risultati conseguiti prima assumendo la sola ipotesi di Dupuit e, successivamente, risolvendo l'equazione completa del moto di filtrazione. In particolare, vengono forniti abachi adimensionali che consentono, una volta fissate le caratteristiche ...

1999-10-01

319

Concrete as secondary containment for interior wall embedded waste lines  

International Nuclear Information System (INIS)

Throughout the DOE complex there are numerous facilities that handle hazardous and radioactive waste solutions. Due to the hazardous constituents of the mixed waste, secondary containment of tank systems and their ancillary piping, in accordance with Resource Conservation and Recovery Act, is a concern for such existing facilities. The Idaho Division of Environmental Quality was petitioned in 1990 for an Equivalent Device determination regarding secondary containment of waste lines embedded in interior concrete walls. The petition was granted; however, it expires in 1996. To address the secondary containment issue, additional studies were undertaken. One study verified the hypothesis that an interior wall pipe leak would follow the path of least resistance through the naturally occurring void found below a rigidly supported pipe and pass into an adjacent room where detection could occur, before any significant deterioration of the concrete takes place. Other tests ...

1993-08-17

320

Calculating electron dose using a convolution/superposition method. 120  

International Nuclear Information System (INIS)

The calculation of electronn beam dose using an algorithms similar to convolution/superposition methods for photon beams [1,2,3,4] is explored. The distribution of dose deposited by a number of monoenergetic, point-monodirectional electron pencil beams is first determined using the Monte Carlo method [5,6]. These elementary distributions are combined to model distributions that would result from the spectrum of incident energies and angles [6,7] present in a clinical beam. These modified distributions are then stored for use as kernels in the dose calculation. In the case of a homogeneous phantom, the relative fluence distribution is convolved with the stored kernels to obtain thhe dose distributions in 3 dimensions. Since the kernels cannot be assumed to be spatially invariant in a heterogeneous water-like phantom, the dose deposited on paths from the interaction site to all the dose deposition sites is approximated by scaling the kernels to reflect the average ...

321

Bern-Kosower rule for scalar QED  

International Nuclear Information System (INIS)

We derive a full Bern-Kosower-type rule for scalar QED starting from quantum field theory: we derive a set of rules for calculating S-matrix elements for any processes at any order of the coupling constant. A gauge-invariant set of diagrams in general is first written in the world line path-integral expression. Then we integrate over x(#tau#), and the resulting expression is given in terms of a correlation function on the world line left-angle x(#tau#)x(#tau#"')right-angle. Simple rules to decompose the correlation function into basic elements are obtained. A gauge transformation known as the integration by parts technique can be used to reduce the number of independent terms before integration over proper-time variables. The surface terms can be omitted provided the external scalars are on shell. Also, we clarify correspondence to the conventional Feynman rule, which enabled us to avoid any ambiguity coming from the infinite dimensionality of the ...

322

Assessment of oil shale technologies  

Energy Technology Data Exchange (ETDEWEB)

For many decades, the oil shale resources of the western United States have been considered possible contributors to the Nation's liquid fuel supply. This volume reviews several paths to development of these resources and the likely consequences of following these paths. A chapter providing background information about the nature of oil shale is followed by an evaluation of technologies for recovery of shale oil. The economics and finances of establishing an industry of various sizes are analyzed. The fact that much of the best shale is located on Federal land is examined in light of the desire to increase use of the resources. The consequences of shale development in terms of impact on the physical and social environments, and a discussion of the availability of water complete the report. Policy options addressing barriers that could hinder the establishment of the industry are presented. These options, designed primarily for ...

1980-06-01

323

Vegetation re-establishment on a hardwood forest site denuded by brine  

Energy Technology Data Exchange (ETDEWEB)

Brine from active oil wells seeped through the soil of a forested site in north-western Pennsylvania and killed all vegetation in its path, leaving the affected area unproductive and unsightly. After the brine source was eliminated, herbaceous plants, shrubs and forest tree seedlings became established and developed rapidly. Establishment began in the first year and by Year 4 the site had developed into a healthy young forest. Results show that Allegheny hardwood forest sites damaged by brine water will rapidly revegetate once the brine water discharge is stopped if there is a seed supply and if the area is fenced to exclude deer. 3 figs., 12 refs.

1989-04-01

324

Tissue banking for research: connecting the disconnected  

British Library Electronic Table of Contents (United Kingdom)

Delivering the promise of personalised medicine is the challenge that the current generation of scientists face. The variations in human physiology and disease are considerable, and designing appropriate strategies to deliver what has been promised will require access to tissue from a large number of volunteers. The NHS provides an ideal infrastructure for sample acquisition, but requires two things to make this available?public consent and support for extra manpower and administration. There is a disconnection between the NHS and tissue based research that needs to be addressed on a number of levels to provide a translational platform. This should enable the path to be beaten to provide the ideal tailored treatment for future patients; one that preserves quality of life by curing the dise...

2011-01-01

325

Three-frame Algorithm of Car Path Reconstruction from Airborne Traffic Data  

CERN Document Server

The airborne traffic monitoring system forms a novel technology of detecting vehicle motion. An optical digital camera located on an airborne platform produces a series of images which then are processed to recognized the fixed vehicles. In this way the video data are converted into the time sequence of frames containing the vehicle coordinates. In the present work a three-frame algorithm is developed to identify the succeeding vehicle positions. It is based on finding the neighboring points in the frame sequence characterized by minimal acceleration. To verify and optimize the developed algorithm a ``Virtual Road'' simulator was created. Finally available empirical data are analyzed using the created algorithm.

2007-01-01

326

Temperature Dependences of Leakage Currents of ZnO Varistors Doped with Rare-Earth Oxides  

British Library Electronic Table of Contents (United Kingdom)

Rare-earth oxides are doped into ZnO varistors as grain growth inhibitors for increasing the varistors' voltage gradients. However, their leakage currents become large and their nonlinear coefficients decrease at the same time. The reasonable explanation for such a phenomenon has not yet been available. In this paper, the temperature dependences of varistor samples' leakage currents are investigated, which reveal that the increased leakage currents of ZnO varistors with Y2O3 doping are mainly due to the bypass paths through the intergranular materials at grain corners.

2010-01-01

327

Spinodal decomposition and giant magnetoresistance  

International Nuclear Information System (INIS)

We explore the relation of nanostructures with the appearance of giant magnetoresistance (GMR) in melt-spun CuCo ribbons. We find by energy-filtered transmission electron microscopy that the ribbons are composed of a periodic distribution of Co within the Cu, as in spinodal decomposition. The lamellar structure should thus be associated with GMR, as only a small percentage of the Co is present in the form of grains. This is counterintuitive, for no clear interfaces are present as required by standard models, and the period of the composition oscillation (43-52 nm) is an order of magnitude larger than the mean free paths for electrons. Upon annealing, a secondary spinodal decomposition appears following the same direction as the original.

2006-10-01

328

Simple model for characterizing the electrical resistivity in A-15 superconductors  

Science.gov (United States)

A discussion of some of the difficulties with previous analyses of the resistivity of A-15 compounds is given. Precise high-temperature data on ..cap alpha..-particle- and electron-damaged Nb/sub 3/Ge and Nb/sub 3/Sn samples with different defect concentrations are presented here and analyzed in a simple way with use of a phenomenological model based on the idea that the ideal resistivity must approach some limiting value in the regime where the mean free path becomes comparable to the interatomic spacing.

1977-04-04

329

Sharp regularity for certain nilpotent group actions on the interval  

CERN Document Server

According to the classical Plante-Thurston Theorem, all nilpotent groups of $C^2$-diffeomorphisms of the closed interval are Abelian. Using techniques coming from the works of Denjoy and Pixton, Farb and Franks constructed a faithful action by $C^1$-diffeomorphisms of $[0,1]$ for every finitely-generated, torsion-free, non-Abelian nilpotent group. In this work, we give a version of this construction that is sharp in what concerns the H\\"older regularity of the derivatives. Half of the proof relies on results on random paths on Heisenberg-like groups that are interesting by themselves.

2011-01-01

330

Selected topics in transient response of aerial lines to high-altitude electromagnetic pulse  

International Nuclear Information System (INIS)

Aerial lines or cables, as one mainly energy transport path of electronic system when illuminated by HEMP, has been often modeled by field-to-transmission line model. However, in many cases, authors too often encounter some confusing statements to the lines effects during experimental procedure. The aim of this paper is to present and discuss these cases, such as the electromagnetic environment above the ground plane, the contribution of the different electromagnetic field component to the induced current and voltage, variations of the load current for different line heights and ground conductivities etc. (authors)

2005-11-01

331

Rocket borne solar eclipse experiment to measure the temperature structure of the solar corona via lyman-. cap alpha. line profile observations  

Energy Technology Data Exchange (ETDEWEB)

A rocket borne experiment to measure the temperature structure of the inner solar corona via the doppler broadening of the resonance hydrogen Lyman-..cap alpha.. (lambda1216A) radiation scattered by ambient neutral hydrogen atoms was attempted during the 16 Feb 1980 solar eclipse. Two Nike-Black Brant V sounding rockets carrying instrumented payloads were launched into the path of the advancing eclipse umbra from the San Marco satellite launch platform 3 miles off the east coast of Kenya.

1981-01-01

332

Regional paths diverge  

Energy Technology Data Exchange (ETDEWEB)

Over the last year, the energy industry firmly established itself as the premier borrowing sector in the international financial markets. While Europe and North America's major energy companies continue to access the loan market as their main source of financing, with a steady flow of new international borrowings, their peers from other areas of the world, such as Latin America and the Middle East, are in the process of positioning themselves in the market as regular borrowers and have become an important new source of fee income for industry's bankers. (Author).

1992-06-01

333

Protective oxides in coal-fired combined cycle power systems  

Energy Technology Data Exchange (ETDEWEB)

In most industrial processes operating at elevated temperatures, protective oxide layers perform a vital duty in protecting the underlying metallic alloys from process gases. Coal-fired combined cycle power generation systems present a number of process conditions in which the properties of the protective oxide layers are particularly important. This paper discusses two of these particular conditions: (1) `erosion/corrosion` of in-bed heat exchanger tubing and (2) thermal cycling of hot gas path components. For both these situations, the desirable properties of protective scales are outlined. The behaviour of scales in practice are highlighted. 33 refs., 6 figs., 2 tabs.

1995-12-31

334

Principle, classification and functions of geochemical modeling codes  

International Nuclear Information System (INIS)

Geochemical model is a kind of concept model which describes geochemical processes by means of chemical reaction equations and mathematical formula, and the software based on the concept model are called geochemical modeling code. Geochemical modeling codes can be divided into three categories: mass equilibrium, mass transfer and mass transport code. The major functions of geochemical codes include the calculation of forms of occurrence of elements, the prediction of direction of various geochemical reaction, the dissolution and precipitation of elements, the pH and Eh value, the rate and path of geochemical reaction in aqueous solution.

335

Power systems for space exploration  

Energy Technology Data Exchange (ETDEWEB)

The Outreach Program was designed to solicit creative ideas from academia, research institutions, private enterprises, and the general public and is intended to be helpful in defining promising technical areas and program paths for more detailed study. To the Outreach Program, a number of power system concepts were proposed. In conclusion, there are a number of advanced concepts for space power and propulsion sources that deserve study if we want to expand our ability to not only explore space, but to utilize it. Advanced nuclear concepts and power beaming concepts are two areas worthy of detailed assessments.

1992-01-01

336

Oman: current status, upstream and export developments, investment opportunities  

Energy Technology Data Exchange (ETDEWEB)

Oman is an attractive and welcoming country, well-ordered and unpretentious. It has benefited from remarkable achievements of economic and social development since 1970. It now has a resource base that should be sufficient to keep it on continuing path of further development. However, the second 20-years of modern Oman will inevitable contain some testing challenges. These are centred in two main areas - the economic, where expenditure has already outstripped revenue and where firm controls are needed to maintain a reasonable balance; and the social, where the pressures from an increasingly literate and numerous population will demand changes to the autocratic traditional system of government. (author)

1995-11-01

337

Non-Abelian duality, parafermions, and supersymmetry  

Energy Technology Data Exchange (ETDEWEB)

Non-Abelian duality in relation to supersymmetry is examined. When the action of the isometry group on the complex structures is nontrivial, extended supersymmetry is realized nonlocally after duality, using path-ordered Wilson lines. Prototype examples considered in detail are, hyper-Kahler metrics with SO(3) isometry and supersymmetric WZW models. For the latter, the natural objects in the nonlocal realizations of supersymmetry arising after duality are the classical non-Abelian parafermions. The canonical equivalence of WZW models and their non-Abelian duals with respect to a vector subgroup is also established. {copyright} {ital 1996 The American Physical Society.}

1996-07-01

338

Medium carbon vanadium micro alloyed steels for drop forging  

International Nuclear Information System (INIS)

Growing competitiveness of alternative manufacturing routes requires cost minimization in the production of drop forged components. The authors analyse the potential of medium carbon, vanadium microalloyed steels for drop forging. Laboratory and industrial experiments have been carried out emphasizing deformation and temperature cycles, strain rates and dwell times showing a typical processing path, associated mechanical properties and corresponding microstructures. The steels the required levels of mechanical properties on cooling after forging, eliminating subsequent heat treatment. The machinability of V-microalloyed steels is also improved when compared with plain medium carbon steels. (author)

339

Mechanisms of Alloy 800 corrosion in helium  

International Nuclear Information System (INIS)

Cr_2O_3 scales are found to form on Alloy 800 and a similar pure ternary alloy in air, and 1 and 50 atm. helium containing oxidizing impurities typical of those in an SGHTR. The strong temperature dependence and neglibible helium overpressure dependence indicate that gas transport through the scales is not rate controlling. Surface oxidation rates are therefore controlled by solid state diffusion and the low oxygen partial pressure dependence of the oxidation rate in Alloy 800 is ascribed to the presence of extrinsic defects in the Cr_3O_3 (due to doping by alloying elements) or to the presence of short circuit diffusion paths. (Auth.).

340

Interferometry and refraction measurements in plasmas of elliptical cross-section  

Energy Technology Data Exchange (ETDEWEB)

The measurement of electron densities using interferometry and refraction measurements in plasmas with cross-sections where the electron density contours are concentric ellipses is examined. Transforms are found for both interferometrically deduced optical path-length differences and refraction angle data obtained from elliptical cross-section plasmas. The transformed data can be inverted to give electron densities using standard techniques developed for circular cross-section plasmas. Refraction of light in elliptical cross-section plasmas is examined using numerical ray tracing.

1984-04-14

341

Hot-air turbine plant at Voelklingen model power plant  

Energy Technology Data Exchange (ETDEWEB)

The integration of a gas turbine into a new type of coal-fired combined cycle power plant necessitates a multiplicity of far-reaching changes compared with a normal design. The extremely high pre-heating temperature of the air emanating from the heat exchanger of the fluidized bed for the gas turbine combustion chamber has necessitated extensive development work and associated combustion trials. It was possible for these results to influence the design of the burners whereas the manufacture of other components which was on the critical path was already far advanced.

1984-06-01

342

Home shrines in Britain and associated spiritual values  

British Library Electronic Table of Contents (United Kingdom)

In a quantitative survey of religious attitudes and practices in a multi-religious sample of 369 school pupils aged between 13 and 15 in London, the presence of a home shrine was found widespread in 11% of adolescents spanning several religious affiliations and ethnicities - especially Buddhists, Hindus and those of Indian, Chinese and 'Other Asian' ethnicity. Having a home shrine correlated significantly with spiritual attitudes such as agreement with filial piety, the Eightfold Path, subjectivity of happiness, meditation, Sikh festivals, reincarnation and opening Gurdwaras to all. It is suggested that teachers and the social services should be aware of the importance of shrines to many religious communities and recognise their potential as a spiritual asset and manifestation of religion ...

2010-01-01

343

Gamma-gamma collider based on Compton back-scattering  

International Nuclear Information System (INIS)

A #gamma##gamma# collider would extend and complement the physics capability of a linear collider; e.g. it would be suitable for direct measurement of the partial decay width of a Higgs boson into two gamma quanta. This paper discusses choice of laser parameters, luminosity optimization, electron and laser parameters for a gamma- gamma collider as a second interaction region for the Next Linear Collider, laser path, and the lasers. It is concluded that a gamma- gamma collider is technically feasible; however it will require a significant investment in preparatory R ampersand D.

1996-08-25

344

From biomass to producer gas  

Energy Technology Data Exchange (ETDEWEB)

This article outlines the use of gasifiers during World War II and how, with soaring fuel prices, producer gas may provide an alternate energy path for agribusiness and farms today. In the last few years, the University of California has become a focus of producer gas research in the US. Biomass fuels used include crushed walnut shells, fruit pits, cereal straw and corn cobs. Particle size, moisture content and slagging create problems and the right kind of gas producer must be used to obtain reliable conversion to producer gas.

1980-09-08

345

Feynman integral treatment of the Bargmann potential  

International Nuclear Information System (INIS)

A method based on path integral formulation is given for obtaining exact solution of the s states for the Bargmann potentialV(r)=1ka"2#beta#(#beta#-1)e"-"2"r"/"a1-e"-"r"/"a"2-Ae"-"r"/"a1-e"-"r"/"a,where #beta# and k are parameters. The exact energy spectrum and the normalised s-state eigenfunctions are obtained from the poles of the Green function and their residues, respectively. The results are compared with their of Schrodinger formalism, special cases are also discussed.

2005-06-01

346

Failure analysis on a ruptured petrochemical pipe  

Energy Technology Data Exchange (ETDEWEB)

The failure took place on a welded elbow pipe which exhibited a catastrophic transverse rupture. The failure was located on the welding HAZ region, parallel to the welding path. Branching cracks were detected at the edge of the rupture area. Deposits of corrosion products were also spotted. The optical microscope analysis showed the presence of transgranular failures which were related to the stress corrosion cracking (SCC) and were predominantly caused by the welding residual stress. The significant difference in hardness between the welded area and the pipe confirmed the findings. Moreover, the failure was also caused by the low Mo content in the stainless steel pipe which was detected by means of spark emission spectrometer. (orig.)

2010-08-15

347

Electromagnetic characterization of superconducting radio-frequency cavities for gw detection  

International Nuclear Information System (INIS)

The electromagnetic properties of a prototype gravitational wave detector, based on two coupled superconducting microwave cavities, were tested. The radio-frequency (rf) detection system was carefully analysed. With the use of piezoelectric crystals small harmonic displacements of the cavity walls were induced and the parametric conversion of the electromagnetic field inside the cavities explored. Experimental results of bandwidth and sensitivity of the parametric converter versus stored energy and voltage applied to the piezoelectric crystal are reported. A rf control loop, developed to stabilize phase changes on signal paths, gave a 125 dBc rejection of the drive mode on a time scale of 1 h.

2004-03-07

348

Different paths: gender, immigration and political participation.  

Science.gov (United States)

"Building on arguments made by Grasmuck and Pessar (1991), Hardy-Fanta (1993), and Hondagneu-Sotelo (1994), among others, this article makes the case for a gendered understanding of immigrant political socialization. Looking at recent Latin American immigrants to New York City, the article argues that immigrant Latino men are more likely to favor continuity in patterns of socialization and organization, and immigrant Latinas are more likely to favor change. This finding helps bridge theoretical and empirical literatures in immigration studies, applying the logic of gender-differentiated decisionmaking to the area of immigrant political socialization and behavior." PMID:12293595

1998-01-01

349

CyberKnife SRS: new technologies that enhance the treatment of cancer  

International Nuclear Information System (INIS)

The CyberKnife Robotic Radiosurgery System (Accuracy Incorporated, Sunnyvale, CA, USA) is used worldwide to treat tumors and neurological disorders anywhere in the body with sub-millimetre beam delivery accuracy. Accuracy has developed a number of new technologies in recent years to enhance the treatment of cancer patients. Such new technologies include a fast Monte Carlo Dose Calculation algorithm, Sequential Optimization dose planning, the IrisTM Variable Aperture Collimator, an 800 MU/min Linear Accelerator, and Optimized Path Traversal. These technologies enable physicists and physicians to plan treatments quickly and easily and deliver them with unrivalled accuracy and precision

2008-11-26

350

Grid-Search Location Methods for Ground-Truth Collection from Local and Regional Seismic Networks  

Energy Technology Data Exchange (ETDEWEB)

The objective of this project is to develop improved seismic event location techniques that can be used to generate more and better quality reference events using data from local and regional seismic networks. Their approach is to extend existing methods of multiple-event location with more general models of the errors affecting seismic arrival time data, including picking errors and errors in model-based travel-times (path corrections). Toward this end, they are integrating a grid-search based algorithm for multiple-event location (GMEL) with a new parameterization of travel-time corrections and new kriging method for estimating the correction parameters from observed travel-time residuals. Like several other multiple-event location algorithms, GMEL currently assumes event-independent path corrections and is thus restricted to small event clusters. The new parameterization assumes that travel-time corrections are a function of both the event ...

2003-07-24

351

Diverter/bop system and method for a bottom supported offshore drilling rig  

Energy Technology Data Exchange (ETDEWEB)

A system is described adapted for alternative use as a diverter or a blowout preventer for a bottom supported drilling rig and adapted for connection to a permanent housing attached to rig structural members beneath a drilling rig rotary table, the permanent housing having an outlet connectable to a rig fluid system flow line. The system consists of: a fluid flow controller having a controller housing with a lower cylindrical opening and an upper cylindrical opening and a vertical path therebetween and a first outlet passage and a second outlet passage provided in its wall, a packing element disposed within the controller housing, and annular piston means adapted for moving from a first position to a second position, whereby in the first position the piston means wall prevents interior fluid from communicating with the outlet passages in the controller housing wall and in the second position the piston means wall allows fluid communication of interior fluid with ...

1986-07-01

352

Analysis of log rate noise in Ontario's CANDU reactors  

Energy Technology Data Exchange (ETDEWEB)

In the fall of 2003, the operators noticed that in the recently-refurbished Bruce A Shutdown System no. 1 (SDS1) the noise level in Log Rate signals were much larger than before. At the request of the Canadian Nuclear Safety Commission (CNSC), all Canadian CANDU reactors took action to characterize their Log Rate noise. Staff of the Inspection and Maintenance Services division of Ontario Power Generation (OPG) has collected high-speed high-accuracy noise data from nearly all 16 Ontario reactors, either as part of routine measurements before planned outages or as a dedicated noise recording. This paper gives the results of examining a suitable subset of this data, with respect to the characteristics and possible causes of Log Rate noise. The reactor and instrumentation design is different at each station: the locations of the moderator injection nozzles, the location of the ion chambers for each system, and the design of the Log Rate amplifiers. It was found that the Log noise (source ...

2007-07-01

353

The effects of surface damage on RF cavity operation  

Energy Technology Data Exchange (ETDEWEB)

We describe a model of damage in rf cavities and show how this damage can limit cavity operation. We first present a review of mechanisms that may or may not affect the ultimate fields that can be obtained in rf cavities, assuming that mechanical stress explains the triggers of rf breakdown events. We present a method of quantifying the surface damage caused by breakdown events in terms of the spectrum of field enhancement factors, Beta, for asperities on the surface. We then model an equilibrium that can develop between damage and conditioning effects, and show how this equilibrium can determine cavity performance and show experimental evidence for this mechanism. We define three functions that quantify damage, and explain how the parameters that determine this performance can be factored out and measured. We then show how this model can quantitatively explain the dependence of cavity performance on material, frequency, pulse length, gas, ...

2006-04-14

354

The effect of welding parameters on hydrogen distribution in pipeline welds  

Energy Technology Data Exchange (ETDEWEB)

There is currently considerable interest in identifying and quantifying the effects of welding procedure parameters and steel composition factors on the risk of cracking in pipeline girth welds that may be experienced during winter construction. Although low ambient temperatures, that may be experienced during winter construction, are generally assumed to increase the risk of cracking there has been little work to quantify the effects and to suggest how welding procedures should be modified for winter conditions. The present work was undertaken to calculate the effects of changes in welding parameters on the thermal cycle and the diffusion of hydrogen for a typical pipeline girth weld. A simple analytical method and the finite element method (FEM) were used. Both methods gave similar results but the simple method was very sensitive to the value of heat transfer coefficient. The results showed that the relation between the hydrogen diffusion ...

1990-03-01

355

The Effects of Exurbanization on Bird and Macro invertebrate Communities in Deciduous Forests on the Cumberland Plateau, Tennessee  

International Nuclear Information System (INIS)

To investigate the potential causes of changes to bird communities in exurban areas, we examined the relationship between bird and macro invertebrate communities in exurbanized forest. We randomly located sampling points across a gradient of exurbanization. We used point counts to quantify bird communities and sweep netting, soil cores, pitfalls, and frass collectors to quantify macro invertebrates. Bird communities had higher richness and abundance in exurban areas compared to undeveloped forests, and lost some species of conservation concern but gained others. The macro invertebrate community was slightly more abundant in exurban areas, with a slight shift in taxonomic composition. The abundance of macro invertebrates in soil cores (but not pitfalls) predicted the abundance of ground-foraging birds. The abundance of macro invertebrates in sweep nets was not associated with the abundance of aerial insectivore birds. Exurbanization therefore ...

356

Second-law efficiency of solar-thermal cavity receivers  

Energy Technology Data Exchange (ETDEWEB)

Properly quantified performance of a solar-thermal cavity receiver must not only account for the energy gains and losses as dictated by the First Law of thermodynamics, but it must also account for the quality of that energy. However, energy quality can only be determined from the Second Law. In this paper an equation for the Second-Law efficiency of a cavity receiver is derived from the definition of available energy or availability (occassionally called exergy), which is a thermodynamic property that measures the maximum amount of work obtainable when a system is allowed to come into unrestrained equilibrium with the surrounding environment. The fundamental concepts of the entropy and availability of radiation are explored from which a convenient relationship among the reflected cone half angle, the insolation, and the concentrator geometric characteristics is developed as part of the derivation of the Second-Law efficiency. A comparison is made between First- ...

1983-10-01

357

Quantification of the local glucose utilization and local blood flow in the heart of the awake rat using the /sup 14/C-2-deoxyglucose and /sup 14/C-iodoantipyrine methods  

Science.gov (United States)

Local cardiac glucose utilization (LCarGU) was quantified in the rat heart according to the Sokoloff model and local cardiac blood flow (LCarBF) according to the /sup 14/C-iodoantipyrine method. For quantitative autoradiography calibration curves for heart slices were performed. They differed from the brain calibration curves by 8%. The lumped constant was 0.377 in isolated working hearts. LCarGU and LCarBF could then be quantified in awake rats. At different locations mean LCarGU of different hearts varied from 85 to 200 ..mu..moles/100g/min and mean LCarBF from 390 to 831 ml/100g/min. The ratio subendocardial/subepicardial glucose utilization or blood flow was not systematically different from 1. The results indicate that glucose can be an important fuel in the heart of the awake rat, although its contribution to overall metabolism varies from animal to animal.

1986-03-05

358

Data report of BWR post-CHF tests. Transient core thermal-hydraulic test program. Contract research  

Energy Technology Data Exchange (ETDEWEB)

JAERI has been performing transient core thermal-hydraulic test program. In the program, authors performed BWR/ABWR DBE simulation tests with a test facility, which can simulate BWR/ABWR transients. The test facility has a 4 x 4 bundle core simulator with 15-rod heaters and one non-heated rod. Through the tests, authors quantified the thermal safety margin for core cooling. In order to quantify the thermal safety margin, authors collected experimental data on post-CHF. The data are essential for the evaluation of clad temperature transient when core heat-up occurs during DBEs. In comparison with previous post-CHF tests, present experiments were performed in much wider experimental condition, covering high clad temperature, low to high pressure and low to high mass flux. Further, data at wider elevation (lower to higher elevation of core) were obtained in the present experiments, which make possible to discuss the effect of axial position on ...

2001-03-01

359

An objective indicator for two-phase flow pattern transition  

Energy Technology Data Exchange (ETDEWEB)

This work concerns the development of a methodology the objective of which is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. During the first time, the efforts focused on: (1) the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; (2) the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; and (3) the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. During the second time, in order to verify the fundamental assumption, a series of experiments were conducted, the objective of which was to demonstrate the correlation between ...

1998-08-01

360

An objective indicator for two-phase flow pattern transition  

International Nuclear Information System (INIS)

This work concerns the development of a methodology the objective of which is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. During the first time, the efforts focused on: (1) the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; (2) the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; and (3) the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. During the second time, in order to verify the fundamental assumption, a series of experiments were conducted, the objective of which was to demonstrate the correlation between ...

1998-08-01

361

A new method for quantifiable and controlled dosage of particulate matter for in vitro studies: the electrostatic particulate dosage and exposure system (EPDExS).  

Science.gov (United States)

An exposure chamber is described for the quantifiable addition of fine and ultrafine aerosol particulate matter directly to cells and used to demonstrate the in vitro cytotoxicity of fine 1,4-naphthoquinone particles to murine lung epithelial cells. The electrostatic particulate dosage and exposure system (EPDExS) operates on the principle of electrostatic precipitation and is shown to deposit fine and ultrafine aerosol particles directly to cells with 100% efficiency for particle diameters in the range of 40-530nm. This range is not limited by the EPDExS, but rather by the aerosolization method used for this study. Numbers of particles deposited onto the cells are counted with a condensation particle counter, negating any need to calculate or estimate particle exposure. The process of particle introduction, assessed using Trypan blue dye exclusion, had no effect on cell viability. In combination with a differential mobility classifier, the EPDExS can deliver ...

2008-06-08

362

A carbon monoxide passive sampler: Research and development needs  

Energy Technology Data Exchange (ETDEWEB)

In rare instances, carbon monoxide (CO) levels in houses can reach dangerously high concentrations, causing adverse health effects ranging from mild headaches to, under extreme conditions, death. Hundreds of fatal accidental carbon monoxide poisonings occur each year primarily due to the indoor operation of motor vehicles, the indoor use of charcoal for cooking, the operation of malfunctioning vented and unvented combustion appliances, and the misuse combustion appliances. Because there is a lack of simple, inexpensive, and accurate field sampling instrumentation, it is difficult for gas utilities and researchers to conduct field research studies designed to quantify the concentrations of CO in residences. Determining the concentration of CO in residences is the first step towards identifying the high risk appliances and high-CO environments which pose health risks. Thus, there exists an urgent need to develop and field-validate a ...

1991-11-01

363

Visible and near-infrared spectral signatures for adulteration assessment of extra virgin olive oil  

Science.gov (United States)

Because of its high price, the extra virgin olive oil is frequently target for adulteration with lower quality oils. This paper presents an innovative optical technique capable of quantifying the adulteration of extra virgin olive oil caused by lowergrade olive oils. It relies on spectral fingerprinting the test liquid by means of diffuse-light absorption spectroscopy carried out by optical fiber technology in the wide 400-1700 nm spectral range. Then, a smart multivariate processing of spectroscopic data is applied for immediate prediction of adulterant concentration.

2010-04-01

364

Use of activated charcoal for the purification of neon in the CLEAN experiment  

Energy Technology Data Exchange (ETDEWEB)

Passage of neon gas through activated charcoal is planned to be the primary method of removing impurities from the liquid neon scintillator in the CLEAN experiment. In order to quantify this technique, the breakout curves for hydrogen, nitrogen, argon and krypton impurities in neon-saturated activated charcoal were measured. Adsorption coefficients and the number of theoretical stages were measured for hydrogen in the temperature range between 300 and 80 K, nitrogen between 300 and 200 K, and argon between 300 and 190 K. The adsorption coefficient for krypton was measured at 300 K.

2007-01-21

365

Upgraded coal interest group. Quarterly report, July 1, 1995--September 30, 1995  

Energy Technology Data Exchange (ETDEWEB)

The objectives of the Upgraded Coal Interest Group (UCIG) are as follows: Review and update the status of various coal upgrading technologies and developments and critically assess the results. Perform engineering screening analyses on various coal upgrading approaches. Perform commercialization analyses that will promote the availability and use of upgraded coal products by quantifying the benefits of using them. Identify market opportunities for introduction of upgraded coals. Perform critical analyses on a variety of coals and technologies in areas important to users but not readily available. Perform critical experiments which will show the differences between technologies.

1995-12-31

366

Towards an understanding of the light scalar mesons  

Energy Technology Data Exchange (ETDEWEB)

Although studied for many years the nature of the light scalar mesons remains controversial. Here we shall present a method, applicable for s-wave states located close to a threshold, that allows one to quantify the molecular part of a given state. When applied to the f{sub 0}(980) a dominance of the molecular component is found. In the second part, we show that requirements of field-theoretic consistency and chiral symmetry, when applied to the scattering of light pseudo-scalars, naturally lead to the appearance of dynamical poles in the scalar sector. A program is proposed on how to further investigate experimentally the mixing between these dynamical states and possible genuine quark states. (orig.)

2007-03-15

367

The new thermal comfort equation to qualify air in buildings. De nieuwe behaaglijkheidsbalans voor de kwaliteit van de lucht in gebouwen  

Energy Technology Data Exchange (ETDEWEB)

In the 1988 February issue of this magazine the units olf and decipol were introduced. Olf is a measure for the pollution load and decipol for the indoor air quality. This article discusses a new ventilation theory which is quantified by the new indoor air quality thermal comfort balance based on the units olf and decipol. This balance requires more ventilation air than for the present regulations. It takes into account all pollution sources. 2 figs., 9 refs., 3 tabs.

1990-05-01

368

Solid-state ozone synthesis by energetic ions  

International Nuclear Information System (INIS)

We have synthesized ozone by irradiating thin solid films of oxygen and oxygen-water mixtures with 100 keV protons, motivated by recent reports of condensed O_3 on icy satellites in the outer Solar system. We measured the depth of the Hartley absorption band in the ultraviolet by reflectance spectroscopy and used it to quantify the column density of ozone. We analyzed the results using a three-component (O, O_2 and O_3) model that successfully explains the fluence dependence of ozone production.

1999-08-02

369

Radiation risk in diagnostic radiology  

International Nuclear Information System (INIS)

An attempt was made to quantify the radiation risk of diagnostic radiology. After a general introduction of terms as radiation damage, radiation risk and effective dose equivalent, based on publications of the ICRP, somatic dose indexes were computed for several radiologic investigations, that comprise organ doses committed to red bone marrow, lung, female breast and thyroid with and without considering the rest of the body. The dose for the rest of the body was assumed to be equal to the dose received by the red bone marrow, that is also distributed over the whole body. Neglecting the exposure of the rest of the body resulted in an insignificant increase in the estimated somatic risk, with its experimental determination not being necessary. (author).

1984-01-01

370

Quantification of uranium transport away from firing sites at Los Alamos National Laboratory: A mass balance approach  

Science.gov (United States)

Investigations were conducted at Los Alamos National Laboratory to quantify the extent of migration of depleted uranium away from firing sites. Extensive sampling of air particles, soil, sediment, and water was conducted to establish the magnitude of uranium contamination throughout one watershed. The uranium source term was estimated, and mass balance calculations were performed to compare the percentage of migrated uranium with original expenditures. Mass balance calculations can be powerful in identification of the extent of waste migration and used as an aid in planning future waste investigations.

1992-02-01

371

Low-level and transuranic waste transportation, disposal, and facility decommissioning cost sensitivity analysis  

Energy Technology Data Exchange (ETDEWEB)

The Systems Design Study (SDS) identified technologies available for the remediation of low-level and transuranic waste stored at the Radioactive Waste Management Complex's Subsurface Disposal Area at the Idaho National Engineering Laboratory. The SDS study intentionally omitted the costs of transportation and disposal of the processed waste and the cost of decommissioning the processing facility. This report provides a follow-on analysis of the SDS to explore the basis for life-cycle cost segments of transportation, disposal, and facility decommissioning; to determine the sensitivity of the cost segments; and to quantify the life-cycle costs of the 10 ex situ concepts of the Systems Design Study.

1992-05-01

372

Low-level and transuranic waste transportation, disposal, and facility decommissioning cost sensitivity analysis  

Energy Technology Data Exchange (ETDEWEB)

The Systems Design Study (SDS) identified technologies available for the remediation of low-level and transuranic waste stored at the Radioactive Waste Management Complex`s Subsurface Disposal Area at the Idaho National Engineering Laboratory. The SDS study intentionally omitted the costs of transportation and disposal of the processed waste and the cost of decommissioning the processing facility. This report provides a follow-on analysis of the SDS to explore the basis for life-cycle cost segments of transportation, disposal, and facility decommissioning; to determine the sensitivity of the cost segments; and to quantify the life-cycle costs of the 10 ex situ concepts of the Systems Design Study.

1992-05-01

373

Intergranular corrosion of Alloy 800 by the electrochemical potentiokinetic reactivation method  

Energy Technology Data Exchange (ETDEWEB)

The 'Electrochemical Potentiokinetic Reactivation' method has been employed to quantify the degree of intergranular corrosion of Alloy 800, with different Ti + Al content, aged in the range 500-650/sup 0/C for times up to 5000 hours. The results were compared with the classical Rollason's curves obtained by means of the Strauss' test and a satisfactory agreement was found. An explanation of the slight differences between both methods has been proposed on the basis of the passivity film morphology.

1981-08-01

374

Hideout return testing from support crevices  

International Nuclear Information System (INIS)

The objectives of the project were to develop operational techniques for promoting contaminant hideout return from tube support crevices and to identify the effect of chemical inhibitor application on corrodent transport. The implementation of routine procedures for promoting the return of sequestered corrodents could retard the progression of denting or other corrosion processes and improve steam generator availability. Tests also quantified the effect of inhibitor application on crevice hideout and hideout return processes, with the intention of developing a better understanding of the inhibition mechanism. By carefully monitoring the hideout and hideout return inventories, the program also has provided the opportunity to study steam generator concentration processes in general.

1985-03-01

375

Experimental Uncertainty for the Thermal Expansion of a Simulated Fuel  

Energy Technology Data Exchange (ETDEWEB)

Thermal expansions of a simulated fuel (SS-1) were measured by using a Dilatometer (DIL402C) from room temperature to 1900 K. The main procedure of an uncertainty evaluation followed the strategy of the UO{sub 2} fuel. Referring to the ISO (International Organization for Standardization) guide, the uncertainties of the thermal expansion were quantified in three parts - the initial length, the length variation, and the system calibration factor. The uncertainty of the thermal expansion for a simulated fuel was also compared with those of UO{sub 2} fuel.

2006-07-01

376

Entangled quantum currents in distant mesoscopic Josephson junctions  

Energy Technology Data Exchange (ETDEWEB)

Two mesoscopic SQUID rings which are far from each other are considered. A source of two-mode nonclassical microwaves irradiates the two rings with correlated photons. The Josephson currents are in this case quantum mechanical operators, and their expectation values with respect to the density matrix of the microwaves yield the experimentally observed currents. Classically correlated (separable) and quantum mechanically correlated (entangled) microwaves are considered, and their effect on the Josephson currents is quantified. Results for two different examples that involve microwaves in number states and coherent states are derived. It is shown that the quantum statistics of the tunnelling electron pairs through the Josephson junctions in the two rings are correlated.

2004-12-22

377

Electron Beam and Gamma Radiolysis of Solid-State Metoclopramide  

British Library Electronic Table of Contents (United Kingdom)

Purpose Study the radiolysis of solid-state metoclopramide hydrochloride at various absorbed doses. Elucidate the structure of the degradation products to gain information on the radiolysis mechanisms. Methods Solid-state metoclopramide samples were irradiated at several doses with gamma rays and high-energy electrons to evaluate the influence of the dose rate. High-performance liquid chromatography with a diode array detector was used to measure the chemical potency as a function of the absorbed dose and to quantify the degradation products. The characterization of degradation products was performed by liquid chromatography/atmospheric pressure chemical ionization/tandem mass spectrometry. Results The degradation of solid-state metoclopramide after irradiation was negligible. No qualitati...

2006-01-01

378

Comparison of the TESLA, NLC and CLIC Beam-Collimation System Performance  

CERN Document Server

This report describes studies performed in the framework of the Collimation Task Force organized to support the work of the second International Linear Collider Technical Review Committee. The post-linac beam-collimation systems in the TESLA, JLC/NLC and CLIC linear-collider designs are compared using the same computer code under the same assumptions. Their performance is quantified in terms of beam-halo and synchrotron-radiation collimation efficiency. The performance of the current designs varies across projects, and does not always meet the original design goals. But these comparisons suggest that achieving the required performance in a future linear collider is feasible.

2004-01-01

379

Commercial Credit Value Evaluation and Illustration Analysis on Internet  

Science.gov (United States)

Taobao website online transaction evaluation has been well accepted, but its value has not been measured. This paper quantifies the value of commercial credit of salers in bringing sale purchase on Taobao website through three aspects of data as credit score buyer to saler, number of comments and rate of bad comments. The illustration results on Taobao online transaction credit evaluation show that number of comments, credit score and rate of bad comments have significant impact on sale revenue.

2011-01-01

380

Climate change - the contribution from air travel  

International Nuclear Information System (INIS)

The paper discusses the Intergovernment Panel on Climate Change (IPCC) report on Aviation and the Global Atmosphere (published in 1999). It was considered necessary to treat air transport on its own since aircraft are unique in delivering emissions into the upper atmosphere rather than at ground level. The study was commissioned at the request of the International Civil Aviation Organisation and the Montreal Protocol. More than 300 experts contributed and the report has quantified the effect of aviation on the atmosphere on a world wide basis and highlighted areas where improved data are required. (UK)

2000-04-01

381

Characterization of Mixed Wettability at Different Scales and its Impact on Oil Recovery Efficiency  

Energy Technology Data Exchange (ETDEWEB)

The objectives of this project was to: (1) quantify the pore scale mechanisms that determine the wettability state of a reservoir, (2) study the effect of crude oil, brine and mineral compositions in the establishment of mixed wet states, (3) clarify the effect of mixed - wettability on oil displacement efficiency in waterfloods, (4) develop a new tracer technique to measure wettability, fluid distributions, residual saturation's and relative permeabilities, and (5) develop methods for properly incorporating wettability in up-scaling from pore to core to reservoir scales.

2002-01-28

382

Chandler Slavin | Greener Package  

Wastenet

...it only highlights the different feedstocks used in the production of fiber-based packaging materials or fossil-fuel ones; what about the energy required to convert ...feedstock, is unacceptable in trying to quantify the overall burden a specific packaging material has on the environment. As an aside, the point ... Consequentially, it is difficult to speculate on how much packaging material a company diverts from the landfill by switching from one material to another ...without specifying what geographical region said packaging material resides in. In addition, there is a lot of interest in diverting PET thermoforms from ...

383

AFS Cupola Model Verification--Initial Investigations  

Science.gov (United States)

The cupola furnace is used to melt scrap steel, pig iron, foundry returns, and alloying additives to a prescribed tapping chemistry and temperature for iron casting applications. The melting process within the cupola is highly complex and not well quantified. The American Foundrymen's Society is developing a mathematical model to aid in the understanding of these processes. This model is reaching maturity, and has been successful in estimating a number of melting parameters. This paper details the results of efforts to verify the model in a controlled system, equipped wit the appropriate sensors, for model verification. The work was performed on a research-scale cupola furnace located at the Department of Energy's Albany Research Center.

1998-01-01

384

A mathematical model for simulating shallow solar ponds for treatment of industrial wastewater  

Energy Technology Data Exchange (ETDEWEB)

This paper presents a mathematical model to analyze the solar evaporation in a shallow pond in steady state, when the inlet flow rate, concentration, surface area and solar radiation are given. The simultaneous heat and mass transfer mechanisms are considered for quantifying the amount of evaporated water to the atmosphere and the actual absorbed heat by wastewater is calculated to obtain the bottom temperature of water pond. The heat losses to air by radiation and convection mechanisms are considered and the heat transmission across the water film is evaluated by the forced convection mechanism. 6 refs., 5 figs., 1 tab.

1996-12-31

385

A Virtual Young's Double Slit Experiment for Hard X-ray Photons  

CERN Document Server

We have implemented a virtual Young's double slit experiment for hard X-ray photons with micro-fabricated bi-prisms. We observe fringe patterns with a scintillator, and quantify interferograms by detecting X-ray fluorescence from a scanned 30nm Cr metal film. The observed intensities are best modeled with a near-field, Fresnel analysis. The maximum fringe number in the overlap region is proportional to the ratio of real to imaginary parts refractive index of the prism material. The horizontal and vertical transverse coherence lengths at beamline APS 8-ID are measured.

2009-01-01

386

Spent fuel sabotage aerosol ratio program : FY 2004 test and data summary  

International Nuclear Information System (INIS)

This multinational, multi-phase spent fuel sabotage test program is quantifying the aerosol particles produced when the products of a high energy density device (HEDD) interact with and explosively particulate test rodlets that contain pellets of either surrogate materials or actual spent fuel. This program has been underway for several years. This program provides data that are relevant to some sabotage scenarios in relation to spent fuel transport and storage casks, and associated risk assessments. The program also provides significant technical and political benefits in international cooperation. We are quantifying the Spent Fuel Ratio (SFR), the ratio of the aerosol particles released from HEDD-impacted actual spent fuel to the aerosol particles produced from surrogate materials, measured under closely matched test conditions, in a contained test chamber. In addition, we are measuring the amounts, nuclide content, size distribution of the ...

387

Thermochemistry of mixed explosives  

Energy Technology Data Exchange (ETDEWEB)

In order to predict thermal hazards of high-energy materials, accurate kinetics constants must be determined. Predictions of thermal hazards for mixtures of high-energy materials require measurements on the mixtures, because interactions among components are common. A differential-scanning calorimeter (DSC) can be used to observe rate processes directly, and isothermal methods enable detection of mechanism changes. Rate-controlling processes will change as components of a mixture are depleted, and the correct depletion function must be identified for each specific stage of a complex process. A method for kinetics measurements on mixed explosives can be demonstrated with Composition B is an approximately 60/40 mixture of RDX and TNT, and is an important military explosive. Kinetics results indicate that the mator process is the decomposition of RDX in solution in TNT with a perturbation caused by interaction between the two ...

1982-01-01

388

Modeling of the non isothermal and non isobaric transformations kinetics. Application to the kaolinite de-hydroxylation and to the tri-uranium octo-oxide reduction by hydrogen; Modelisation de la cinetique de transformations non isothermes et (ou) non isobares. Application a la deshydroxylation de la kaolinite et a la reduction de l'octooxyde de triuranium par l'hydrogene  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to be able to describe transformations, occurring when solids and gases are in non isothermal and non isobaric conditions, with kinetic models. A methodology has been used. Two essential processes have to be taken into account: the germination and the growth. The germs are supposed to be formed (at constant temperature and pressure) in the grains surface with a constant velocity by surface unit, (gamma), called germination surface frequency (number of germs.m{sup -2}.s{sup -1}. The growth velocity is characterized by a growth surface reactivity, (phi) (in mol.m{sup -2}.s{sup -1}). With an appropriate transformation model, it is possible to obtain the variations of (gamma) and (phi) in terms of the temperature and pressure which are then used in the calculation of the velocity in non isothermal and non isobaric conditions. In order to validate the developed method, two reactions have been studied. For the first one, the kaolinite ...

2002-12-15

389

Kinetic and thermodynamic studies of the biosorption of Cr(VI) by Pinus sylvestris Linn  

Energy Technology Data Exchange (ETDEWEB)

Biosorption equilibrium, kinetics and thermodynamics of chromium(VI) ions onto cone biomass were studied in a batch system with respect to temperature and initial metal ion concentration. The biosorption efficiency of chromium ions to the cone biomass decreased as the initial concentration of metal ions was increased. But cone biomass of Pinus sylvestris Linn. exhibited the highest Cr(VI) uptake capacity at 45 {sup o}C. The biosorption efficiency increased from 67% to 84% with an increase in temperature from 25 to 45 deg. C at an initial Cr(VI) concentration of 300 mg/L. The Langmuir isotherm model was applied to experimental equilibrium data of Cr(VI) biosorption depending on temperature. According to Langmuir isotherm, the monolayer saturation capacity (Q{sub max}) is 238.10 mg/g. The pseudo-first-order and pseudo-second-order kinetic models were applied to test the experimental data for initial Cr(VI). The pseudo-second-order ...

2008-05-01

390

Growth and cell kinetic changes of HeLa S-3 spheroids following hyperfractionated irradiation  

International Nuclear Information System (INIS)

Optimal design of the hyperfractionated radiotherapy requires basic radiobiological data such as the critical dose per fraction, number of fractions per day and total equivalent dose, to name a few. As a prelude to in vivo hyperfractionated irradiation, the authors carried out experiments to determine quantitative changes in the proliferation and cell kinetic parameters of multicellular spheroids after hyperfractionated irradiation. Experiments were carried out with HeLa S-3 spheroid growing in MEM culture media. Hyperfractionated irradiation schedules were 1.5 Gy/f, 2f/day and 1.0 Gy/f, 3 f/day. At intervals after irradiation, cell numbers, growth delays and cell cycle distribution of spheroids were determined. The kinetic data were obtained by the use of flow cytometry. The most pronounced changes in cell kinetic parameters were early G/sub 2/M block, proportional to single radiation dose up to 4.0 Gy. There was a ...

391

Assessment of bone formation and bone resorption in osteoporosis: a comparison between tetracycline-based iliac histomorphometry and whole body /sup 85/Sr kinetics  

Energy Technology Data Exchange (ETDEWEB)

Bone formation and resorption have been measured in patients with idiopathic osteoporosis by histomorphometry of 7.5-mm trephine biopsies and in the whole body by 85Sr radiotracer methodology and calcium balances. The studies were synchronized and most were preceded by double in vivo tetracycline labeling. Correlations between histological and kinetic bone formation indices were better when better when based on the extent of double tetracycline labels than on measurements of osteoid by visible light microscopy. Correction of the kinetic data for long-term exchange, using 5 months' serial whole body counting of retained 85Sr, improved the fit of the kinetic to the histological data. A statistical analysis of the measurement uncertainties showed that the residual scatter in the best correlations (between exchange-corrected bone formation rates and double-labeled osteoid surface indices) could be attributed to ...

1987-12-01

392

Thermodynamic and kinetic aspects of surface acidity  

Science.gov (United States)

Our research in the general area of acid catalysis involves the characterization of solid acidity and the corresponding assessment of catalytic performance of acidic materials. Acid characterization studies are required to provide essential information about the type of acid site (i.e., Lewis versus Bronsted), the strength of the sites, and the mobility of molecules adsorbed on the acid sites. An accurate measure of acid strength is given by the heat of adsorption of a basic probe molecule on the acid site. A thermodynamic representation of the mobility of adsorbed species on these sites is given by the entropy of adsorption. Important techniques used in these acid site characterization studies include microcalorimetry, thermogravimetric measurements, temperature programmed desorption, infrared spectroscopy and solid state nuclear magnetic resonance. The combination of these acid site characterization studies with reaction kinetics measurements of selected ...

1992-01-01

393

Steady-state passive films; Interfacial kinetic effects and diagnostic criteria  

Energy Technology Data Exchange (ETDEWEB)

This paper reports that the point defect model for steady-state passive films formed anodically on metal s in aqueous environments has been extended to include irreversible dissolution of the film and the irreversible generation and annihilation of cation and oxygen vacancies at the metal/film and film/solution interfaces. THe model yields a number of diagnostic criteria that can be used to identify the majority (vacancy) charge carrier and to characterize the kinetic nature of the interfacial vacancy generation and annihilation processes. We use these criteria to show that the steady-state passive film that forms on nickel in acidic phosphate buffer solutions is a cation conductor and that cation transport from the metal to the solution involves irreversible ejection of cations from the film. On the other hand, the passive film that forms on tungsten in the same environment under steady-state conditions is found to be an oxygen ion conductor with the passive ...

1992-01-01

394

Photochemical reactivity of the homologous proteins. cap alpha. -lactalbumin and lysozyme  

Energy Technology Data Exchange (ETDEWEB)

The fluorescent behaviour and the photodynamic effect was studied in native and structurally modified lysozyme and ..cap alpha..-lactalbumin. The Tyr residues in lysozyme and ..cap alpha..-lactalbumin show different sensitivities to the photodynamic effect. The effect is zero in the case of Tyr from native lysozyme. In contrast, the Tyr residues in ..cap alpha..-lactalbumin are susceptible to photooxidation, which indicates a greater degree of exposure to the solvent. The three His residues of ..cap alpha..-lactalbumin have different degrees of exposure and show two different kinetics of photooxidation whereas the His residue of lysozyme is photooxidized with a single kinetic. Two photooxidation kinetics were obtained for the Trp residues of both native proteins, an indication that in both cases there are Trp residues that are differently exposed to the solvent. The wavelengths of maximum fluorescent emission of the Trp ...

1985-04-01

395

Minimal Curvature Trajectories: Riemannian Geometry Concepts for Model Reduction in Chemical Kinetics  

CERN Document Server

In dissipative ordinary differential equation systems different time scales cause anisotropic phase volume contraction along solution trajectories. Model reduction methods exploit this for simplifying chemical kinetics via a time scale separation into fast and slow modes. The aim is to approximate the system dynamics with a dimension-reduced model after eliminating the fast modes by enslaving them to the slow ones via computation of a slow attracting manifold. We present a novel method for computing approximations of such manifolds using trajectory-based optimization. We discuss Riemannian geometry concepts as a basis for suitable optimization criteria characterizing trajectories near slow attracting manifolds and thus provide insight into fundamental geometric properties of multiple time scale chemical kinetics. The optimization criteria correspond to a suitable mathematical formulation of "minimal relaxation" of chemical forces along reaction ...

2009-01-01

396

Mechanisms controlling the leaching kinetics of fixated flue gas desulfurization (FGD) material under neutral and acidic conditions.  

Science.gov (United States)

A number of agricultural and engineering uses for fixated flue gas desulfurization (FGD) material exist; however, the potential for leaching of hazardous elements has limited widespread application and the processes controlling the leaching of this material are poorly understood. In this study, a flow-through rotating-disk system was applied to elucidate the relative importance of bulk diffusion, pore diffusion, and surface chemical reaction in controlling the leaching of fixated FGD material under pH conditions ranging from 2.2 to 6.8. Changing the hydrodynamics in the rotating disk system did not affect the leaching kinetics at both pH 2.2 and 6.8, indicating that bulk diffusion was not the kinetic-limiting step. Application of the shrinking core model (SCM) to the data suggested a surface reaction-controlled mechanism, rather than a pore diffusion mechanism. The leaching of fixated FGD material increased with decreasing pH, suggesting it can ...

2007-05-07

397

Kinetic study of the epoxidation of 1-octene with hydrogen peroxide catalyzed by platinum(II) complexes. Evidence of the involvement of two metal species in the oxygen-transfer step  

Energy Technology Data Exchange (ETDEWEB)

A detailed kinetic study of the epoxidation of 1-octene with hydrogen peroxide catalyzed by Pt(II) complexes is reported. The two systems analyzed were (diphoe)Pt(CF/sub 3/)(OH)/1-octene/H/sub 2/O/sub 2//THF and ((diphoe)Pt(CF/sub 3/)(CH/sub 2/Cl/sub 2/))BF/sub 4//1-octene/H/sub 2/O/sub 2//H/sub 2/O/CH/sub 2/Cl/sub 2/. Rate data were determined with GLC from epoxide formed vs time plots. Evidence for many of the organometallic intermediates and the individual steps involved was gained from IR studies, /sup 19/F NMR studies, and especially designed experiments including studies of the acidity effect. In both cases the kinetic analysis suggests a mechanism in which the actual oxidant is a PtOOH species that interacts with a Pt-olefin complex in the oxygen-transfer step (second-order dependence on platinum). 29 references, 12 figures, 3 tables.

1988-06-01

398

Kinetic study of steam gasification of coke: II-Study in fluidized bed reactor  

Energy Technology Data Exchange (ETDEWEB)

This work reports an experimental study on the steam gasification of an anthracite coke in a fluidized bed reactor, with the aim of evaluating the reaction kinetics. Isothermal runs were carried out with samples of 91 to 275 g of coke, at temperatures between 799 and 928{sup 0}C and for steam partial pressures between 0.3 and 0.9 atm. The conversion decreases as the amount of coke is increased and it is very sensitive to the temperature. Neither the volumetric reaction model nor the unreacted shrinking core model can satisfactorily fit the experimental results. That is why empirical models have been used. The first one is derived from the unreacted shrinking core model. An activation energy of 219 kJ. mol{sup -1} and a reaction order with respect of steam of 0.57 have been identified. In the second model, the conversion has been correlated as a function of a dimensionless time. A comparison of the results obtained in the fluidized bed with other ones obtained in a ...

1989-01-01

399

Kinetic and isotherm studies of Cu(II) biosorption onto valonia tannin resin  

Energy Technology Data Exchange (ETDEWEB)

The biosorption of Cu(II) from aqueous solutions by valonia tannin resin was investigated as a function of particle size, initial pH, contact time and initial metal ion concentration. The aim of this study was to understand the mechanisms that govern copper removal and find a suitable equilibrium isotherm and kinetic model for the copper removal in a batch reactor. The experimental isotherm data were analysed using the Langmuir, Freundlich and Temkin equations. The equilibrium data fit well in the Langmuir isotherm. The experimental data were analysed using four sorption kinetic models - the pseudo-first- and second-order equations, the Elovich and the intraparticle diffusion model equation - to determine the best fit equation for the biosorption of copper ions onto valonia tannin resin. Results show that the pseudo-second-order equation provides the best correlation for the biosorption process, whereas the Elovich equation also fits the ...

2009-03-15

400

Influence of excited molecules on electron swarm transport coefficients and gas discharge kinetics  

Energy Technology Data Exchange (ETDEWEB)

In this paper we study different effects of excited molecules on swarm parameters, electron energy distribution functions and gas discharge modeling. First we discuss a possible experiment in parahydrogen to resolve the discrepancy in hydrogen vibrational excitation cross section data. Negative differential conductivity (NDC) is a kinetic phenomenon which manifests itself in a particular dependence of the drift velocity on E=N and it is affected by superelastic collisions with excited states. A complete kinetic scheme for argon required to model excited state densities in gas discharges is also described. These results are used to explain experiments in capacitively and inductively coupled RF plasmas used for processing. The paper illustrates the application of atomic and molecular collision data, swarm data and the theoretical techniques in modeling of gas discharges with large abundances of excited molecules. It is pointed out that swarm ...

1997-09-01

401

Incorporation of Reaction Kinetics into a Multiphase, Hydrodynamic Model of a Fischer Tropsch Slurry Bubble Column Reactor  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the development of a computational multiphase fluid dynamics (CMFD) model of the Fischer Tropsch (FT) process in a Slurry Bubble Column Reactor (SBCR). The CMFD model is fundamentally based which allows it to be applied to different industrial processes and reactor geometries. The NPHASE CMFD solver [1] is used as the robust computational platform. Results from the CMFD model include gas distribution, species concentration profiles, and local temperatures within the SBCR. This type of model can provide valuable information for process design, operations and troubleshooting of FT plants. An ensemble-averaged, turbulent, multi-fluid solution algorithm for the multiphase, reacting flow with heat transfer was employed. Mechanistic models applicable to churn turbulent flow have been developed to provide a fundamentally based closure set for the equations. In this four-field model formulation, two of the fields are used to track the gas phase (i.e., small spherical and ...

2008-11-01

402

In-situ X-ray diffraction approach to surface film growth kinetics  

Science.gov (United States)

A knowledge of surface film growth kinetics can be quite useful in the production of materials for uses ranging from protective coatings to microelectronic devices. A technique for determining the kinetics of film growth is presented which should prove to be a valuable alternative to the array of spectroscopies (AES, RBS, etc.) currently favored for these measurements. Some of the virtues of this X-ray diffraction approach are its non-destructive nature, thickness resolution better than 50 {angstrom} and conventional equipment requirements. Results obtained for the growth of Pd{sub 2}Si films during thermal annealing of Pd coatings on Si, indicate parabolic growth over a temperature range of 160-222 C. The rate constant was found to be k{prime} = 7 {times} 10{sup {minus}4} exp ({minus}1.06 eV/kT) cm{sup 2}/sec, where (film thickness){sup 2} = k{prime} x time. This activation energy is in agreement with results obtained by other techniques. A ...

403

Hydrolysis kinetics of lead silicate glass in acid solution  

International Nuclear Information System (INIS)

Hydrolysis kinetics of the lead silicate glass (LSG) with 40 mol% PbO in 0.5 N HNO_3 aqueous acid solution was investigated. The surface morphology and the gel layer thickness were studied by scanning electron microscopy (SEM) micrographs. Energy dispersive X-ray spectroscopy (EDS) and inductively coupled plasma spectroscopy (ICP) were used to determine the composition of the gel layer and the aqueous solution, respectively. The silicon content of the dissolution products was determined by using weight-loss data and compositions of the gel layer and the solution. The kinetic parameters were determined using the shrinking-core-model (SCM) for rate controlling step. The activation energy obtained for hydrolysis reaction was Q_c_h_e = 56.07 kJ/mole. The diffusion coefficient of the Pb ions from the gel layer was determined by using its concentration in solution and in LSG. The shrinkage of the sample and the gel layer thickness during dissolution ...

2009-06-01

404

Ganglioside GM_1 spontaneous transfer between phospholipid vesicles  

International Nuclear Information System (INIS)

The transfer kinetics of the monosiaylated glycosphingolipid, GM_1, between different size phospholipid vesicles was measured using molecular sieve chromatography. At desired time intervals, small unilamellar donor vesicles were separated from large unilamellar acceptor vesicles by elution from a Sephacryl S-500 column ["3H]-GM_1 net transfer was calculated relative to ["1"4C]-cholesteryl oleate, which served as a nontransferable marker in the donor vesicles. The initial GM_1 transfer rate between 1-palmitoyl-2-oleoyl phosphatidylcholine vesicles at 45"0C deviated slightly from first order kinetics and possessed a half time of 3.6 days. This transfer half time is an order of magnitude shorter than that observed from the desiaylated derivative of GM_1. The transfer kinetics are consistent with the authors recent electron microscopic results suggesting a molecular distribution of GM_1 in liquid-crystalline phosphatidylcholine ...

1986-06-08

405

Equilibrium, thermodynamic and kinetic studies for the biosorption of aqueous lead(II) ions onto the seed husk of Calophyllum inophyllum  

British Library Electronic Table of Contents (United Kingdom)

Biosorption of lead(II) ions from aqueous solution onto the seed husk of Calophyllum inophyllum was investigated in a batch system. Equilibrium, thermodynamics and kinetic studies were conducted by considering the effects of pH, initial metal ion concentration, contact time, and temperature. The results showed that the uptake of the metal ions increased with increase in initial metal ion concentration. The pH for optimum adsorption was 4 for the Pb(II) ions (q=4.86mg/g and 97.2% adsorption). Langmuir isotherm described the biosorption of Pb(II) ions onto the biomass (R^2=0.9531) better than the Freundlich model (R^2=0.7984), and the Temkin model (R^2=0.8761). Biosorption kinetics data obtained for the metal ions sorption were fitted using pseudo-first-order and pseudo-second-order. It was ...

2010-01-01

406

Equilibrium and kinetic studies for the biosorption system of copper(II) ion from aqueous solution using Tectona grandis L.f. leaves powder  

Energy Technology Data Exchange (ETDEWEB)

The biosorption of copper(II) ions from aqueous solution by Tectona grandis L.f. was studied in a batch adsorption system as a function of pH, metal ion concentration, adsorbent concentration and adsorbent size. The biosorption capacities and rates of copper(II) ions onto T. grandis L.f. were evaluated. The Langmuir, Freundlich, Redlich-Peterson and Temkin adsorption models were applied to describe the isotherms and isotherm constants. Biosorption isothermal data could be well interpreted by the Langmuir model with maximum adsorption capacity of 15.43 mg/g of copper(II) ion on T. grandis L.f. leaves powder. The kinetic experimental data properly correlated with the second-order kinetic model. Various thermodynamic parameters such as {delta}G{sup o}, {delta}H{sup o}, and {delta}S{sup o} were calculated indicating that this system was a spontaneous and exothermic process.

2006-09-21

407

Early stages during plasma nitriding of pure iron  

Energy Technology Data Exchange (ETDEWEB)

The sequence of nitride formation during the early stages of plasma nitriding of pure iron was studied by optical microscopy, SEM, TEM and x-ray diffraction. Plasma nitriding at {approximately}490 C in a 25 vol.%H{sub 2} + 75 vol.%N{sub 2} mixture starts with the formation of {gamma}{prime}-Fe{sub 4}N after 40s. Once {gamma}{prime} nucleates, it mainly spreads laterally due to diffusion shortcuts in the discontinuous surface nitride layer. Before {gamma}{prime} is continuous on the surface, {epsilon} nucleates on top of it shortly after 40S. Epsilon is then observed to grow, both inwardly and laterally along with {gamma}{prime}. A compact {gamma}{prime}/{epsilon} bilayer forms on the surface at around 100s. The kinetics of nucleation, growth and compactation of the nitrides observed in the present work was significantly more rapid than in any of the nitriding process reported in the literature, including plasma nitriding. The acceleration of the nitriding ...

1995-12-31

408

Dissolution Kinetics of Zirconia Calcine  

International Nuclear Information System (INIS)

Liquid radioactive raffinates from nuclear fuel reprocessing at the Idaho National Engineering and Environmental Laboratory were solidified, or calcines, in a fluidized bed reactor at approximately 500 C to form a dry granular material. This calcine has been provisionally stored near-surface in concrete-encased stainless steel bins at the Idaho Nuclear Technology Engineering Center. Research addressing the permanent immobilization of radioactive waste has been ongoing. One option is to separate the radioactive constituents from the calcine, thereby reducing the radioactive waste volume to be ultimately stored at a national nuclear waste repository. Nitric acid dissolution of the calcine is a key front-end unit operation in the separations option. In order to design calcine dissolution equipment, quantification of dissolution reaction rate parameters is required. A pilot-plant-produced, non-radioactive calcine was utilized to study the dissolution kinetics of a ...

409

CO oxidation over Pt/. gamma. -Al sub 2 O sub 3 under high pressure  

Energy Technology Data Exchange (ETDEWEB)

The oxidation of CO over a Pt/{gamma}-Al{sub 2}O{sub 3} catalyst was studied by cyclic injection of CO and O{sub 2} pulses under CO and O{sub 2} pressures of 2 and 1 kPa, respectively, at temperatures of 330-650 K. A boundary reaction model yielded kinetic parameters in agreement with the results of published low-pressure studies. For CO{sub 2} formation from O{sub 2}(g) + (CO){sub ad}, CO desorption was the most important step and showed multipeak characteristics and a low activation energy (10 kJ/mol) for the boundary reaction was found. CO{sub 2} formation from O{sub 2}(g) + (CO) as well as from CO(g) + (O){sub ad} resulted from boundary reaction at oxygen island. A reaction mechanism was proposed to account for kinetics observed and interpret the varying observations noted in low-pressure studies in terms of diffusion-disguised kinetics.

1989-07-01

410

Biosorption of total chromium from aqueous solution by red algae (Ceramium virgatum): Equilibrium, kinetic and thermodynamic studies  

Energy Technology Data Exchange (ETDEWEB)

This study focused on the biosorption of total chromium onto red algae (Ceramium virgatum) biomass from aqueous solution. Experimental parameters affecting biosorption process such as pH, contact time, biomass dosage and temperature were studied. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) models were applied to describe the biosorption isotherms. Langmuir model fitted the equilibrium data better than the Freundlich isotherm. The biosorption capacity of C. virgatum biomass for total chromium was found to be 26.5 mg/g at pH 1.5 and 10 g/L biomass dosage, 90 min equilibrium time and 20 deg. C. From the D-R isotherm model, the mean free energy was calculated as 9.7 kJ/mol, indicating that the biosorption of total chromium was taken place by chemisorption. The calculated thermodynamic parameters ({delta}G{sup o}, {delta}H{sup o}and {delta}S{sup o}) showed that the biosorption of total chromium onto C. virgatum biomass was feasible, spontaneous and exothermic at 20-50 deg. C. ...

2008-12-30

411

Biosorption of cadmium(II) from aqueous solution by red algae (Ceramium virgatum): Equilibrium, kinetic and thermodynamic studies  

Energy Technology Data Exchange (ETDEWEB)

The biosorption characteristics of Cd(II) ions using the red alga (Ceramium virgatum) were investigated. Experimental parameters affecting the biosorption process such as pH, contact time, biomass dosage and temperature were studied. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) models were applied to describe the biosorption isotherms. The biosorption capacity of C. virgatum biomass for Cd(II) ions was found to be 39.7 mg/g. From the D-R isotherm model, the mean free energy was calculated as 12.7 kJ/mol, indicating that the biosorption of Cd(II) the metal ions was taken place by chemisorption. The calculated thermodynamic parameters ({delta}G{sup o}, {delta}H{sup o} and {delta}S{sup o}) showed that the biosorption of Cd(II) ions onto C. virgatum was feasible, spontaneous and exothermic at 293-323 K. Evaluation of experimental data in terms of biosorption kinetics showed that the biosorption of Cd(II) C. virgatum followed well pseudo-second-order ...

2008-09-15

412

A kinetic and microautoradiographic study of sup 14 C-sucrose translocation into developing wheat grains  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of {sup 14}C-photosynthate import by developing wheat grains was followed after pulse-labeling the flag leaf with {sup 14}CO{sub 2}. Samples were collected from four successive points along the transport pathway to and within the grain: exuding aphid stylets on the peduncle, exuding grain pedicels, the grain crease tissues, and the liquid contents of the endosperm cavity. In addition, microautoradiographs were prepared of the grain crease tissues during movement of the {sup 14}C pulse into the grain. At all times, sucrose accounted for 93 to 97% of the total {sup 14}C present at all four sampling sites. The main features of the {sup 14}C kinetics could be accounted for by a simple compartmental model consisting of sucrose pools in series. Microautoradiographs of the crease tissues showed fairly uniform labeling of vascular parenchyma at all times, with a sharp gradient in labeling across the chalaza to the nucellus. Thus the ...

1991-05-01

413

Variable elimination in chemical reaction networks with mass action kinetics  

CERN Document Server

We consider chemical reaction networks taken with mass action kinetics. The steady states of such a system are solutions to a system of polynomial equations. Even for small systems the task of finding the solutions is daunting. We develop an algebraic framework and procedure for linear elimination of variables. The procedure reduces the variables in the system to a set of "core" variables by eliminating variables corresponding to a set of non-interacting species. The steady states are parameterized algebraically by the core variables, and a graphical condition is given for when a steady state with positive core variables necessarily have all variables positive. Further, we characterize graphically the sets of eliminated variables that are constrained by a conservation law and show that this conservation law takes a specific form.

2011-01-01

414

Transformation kinetics and microstructures of Ti17 titanium alloy during continuous cooling  

International Nuclear Information System (INIS)

We have investigated the microstructure evolutions in the Ti17 near #beta# titanium alloy during heat treatments. The phase transformation has first been studied experimentally by combining X-ray diffraction analysis, electrical resistivity and microscopy observations. From a series of isothermal treatments, a IT diagram has been determined, which takes into account the different morphologies. Then, a Johnson-Mehl-Avrami-Kolmogorov (JMAK) model has been successfully used to describe the phase transformation kinetics during either isothermal or cooling treatments. Finally, the coupling of the JMAK model to the finite element software ZeBuLoN allowed us to investigate the evolution of the spatial distribution of the different morphologies during the cooling of an aircraft engine shaft disk after forging.

2007-03-15

415

Thermo-transferred thermoluminescence (TTTl) in potassium-yttrium double fluoride doped with terbium  

International Nuclear Information System (INIS)

This paper presents results of studying the thermo-transferred thermoluminescence (TTTl) phenomenon in potassium-yttrium double fluoride doped with terbium (K_2YF_5_:Tb) at different impurity concentrations (0.8%, 0.95% and 0.99%). Previously to study the TTTl phenomenon, structural characterization and chemical composition of the materials were determined. The structural studies were conducted using a scanning electron microscope; meanwhile, chemical composition was analyzed using energy dispersive X-ray spectroscopy. Thermoluminescence kinetics was studied irradiating the samples with "1"3"7Cs gamma rays as well as with "9"0Sr/"9"0Y beta rays, analyzing the glow curves by the deconvolution method for obtaining the kinetic parameters. (Author)

2011-02-01

416

The oxidation of n-butylbenzene: Experimental study in a JSR at 10atm and detailed chemical kinetic modeling  

British Library Electronic Table of Contents (United Kingdom)

The oxidation of n-butylbenzene was studied in a jet-stirred reactor (JSR) at 10atm in dilute conditions providing new experimental results over the low- and high-temperature range 550-1180K, and variable equivalence ratio (0.25ϕ1.5). They consisted of concentration profiles of the reactants, stable intermediates and final products, measured as a function of temperature, at a constant residence time of 1s, by sonic probe sampling followed by on-line GC-MS and off-line GC-TCD-FID and GC-MS analyses. The oxidation of n-butylbenzene in these conditions was modeled using a detailed chemical kinetic reaction mechanism (404 species and 2210 reactions, most of them reversible) deriving from a previous scheme proposed for the ignition, oxidation, and combustion of simple aromatics (benzene,...

2011-01-01

417

The kinetics of the tissue distribution of silver nanoparticles of different sizes  

British Library Electronic Table of Contents (United Kingdom)

Blood kinetics and tissue distribution of 20, 80 and 110 nm silver nanoparticles were investigated in rats up to 16 days after intravenous administration once daily for 5 consecutive days. Following both single and repeated injection, silver nanoparticles disappeared rapidly from the blood and distributed to all organs evaluated (liver, lungs, spleen, brain, heart, kidneys and testes) regardless of size. The 20 nm particles distributed mainly to liver, followed by kidneys and spleen, whereas the larger particles distributed mainly to spleen followed by liver and lung. In the other organs evaluated, no major differences between the sizes were observed. Size-dependent tissue distribution suggests size-dependent toxicity and health risks. Repeated administration resulted in accumulation in li...

2010-01-01

418

The high-density regime of kinetic-dominated loop quantum cosmology  

CERN Document Server

We study the dynamics of states perturbatively expanded about a harmonic system of loop quantum cosmology, exhibiting a bounce. In particular, the evolution equations for the first and second order moments of the system are analyzed. These moments back-react on the trajectories of the expectation values of the state and hence alter the energy density at the bounce. This analysis is performed for isotropic loop quantum cosmology coupled to a scalar field with a small but non-zero constant potential, hence in a regime in which the kinetic energy of matter dominates. Analytic restrictions on the existence of dynamical coherent states and the meaning of semi-classicality within these systems are discussed. A numerical investigation of the trajectories of states that remain semi-classical across the bounce demonstrates that, at least for such states, the bounce persists and that its properties are similar to the standard case, in which the moments of the states are ...

2010-01-01

419

The effect of sodium on the MoO sub 3 -SiO sub 2 -catalyzed partial oxidation of methane  

Energy Technology Data Exchange (ETDEWEB)

The effect of sodium on the partial oxidation of methane over MoO{sub 3}-SiO{sub 2} in the presence of molecular oxygen has been investigated. As in the sodium-free case, the major products are formaldehyde, carbon monoxide, carbon dioxide, and water. Kinetic analysis indicates that methane is directly oxidized to formaldehyde and carbon dioxide. Formaldehyde is oxidized to carbon monoxide, which is itself further oxidized, providing an alternative route to carbon dioxide. The kinetic model shows that sodium poisons the direct oxidation of methane to formaldehyde and carbon dioxide, but promotes the oxidation of formaldehyde and carbon monoxide. Model predictions of rates and selectivities are in good agreement with the experimental data. A mechanism that explains both the poisoning and promotion effects of sodium on MoO{sub 3}-SiO{sub 2} is proposed.

1990-12-01

420

The comparative kinetic analysis of Acetocell and Lignoboost lignin pyrolysis: The estimation of the distributed reactivity models  

British Library Electronic Table of Contents (United Kingdom)

The non-isothermal pyrolysis kinetics of Acetocell (the organosolv) and Lignoboost (kraft) lignins, in an inert atmosphere, have been studied by thermogravimetric analysis. Using isoconversional analysis, it was concluded that the apparent activation energy for all lignins strongly depends on conversion, showing that the pyrolysis of lignins is not a single chemical process. It was identified that the pyrolysis process of Acetocell and Lignoboost lignin takes place over three reaction steps, which was confirmed by appearance of the corresponding isokinetic relationships (IKR). It was found that major pyrolysis stage of both lignins is characterized by stilbene pyrolysis reactions, which were subsequently followed by decomposition reactions of products derived from the stilbene pyrolytic pr...

2011-01-01

421

Sucrose accumulation in mature sweet melon fruits. [Cucumis melo  

Energy Technology Data Exchange (ETDEWEB)

Mesocarp tissue from sucrose-accumulating sweet melon (Cucumis melo cv. Galia) showed sucrose synthase activity (ca 1 nkat/gfw) while soluble acid invertase and sucrose phosphate synthase activities were not observed. Sucrose uptake into mesocarp discs was linear with sucrose concentration (1-500 mM) and unaffected by PCMBS and CCCP. Sucrose compartmentation into the vacuole also increased linearly with sucrose concentration as indicated by compartmental efflux kinetics. Mesocarp discs incubated in /sup 14/C-fructose + UDP-glu synthesized /sup 14/C-sucrose and efflux kinetics indicated that the /sup 14/C-sucrose was compartmentalized. These data support the hypothesis that two mechanisms are involved in sucrose accumulation in sweet melon: (1) compartmentation of intact sucrose and (2) synthesis of sucrose via sucrose synthase and subsequent compartmentation in the vacuole.

1987-04-01

422

Stoichio-kinetic modeling and optimization of chemical synthesis: Application to the aldolic condensation of furfural on acetone  

British Library Electronic Table of Contents (United Kingdom)

The condensation reaction of furfural (F) on acetone (Ac) gives a high added value product, the 4-(2-furyl)-3-buten-2-one (FAc), used as aroma in alcohol free drinks, ice, candies, gelatines and other products of current life. This synthesis valorises the residues of sugar cane treatment since furfural is obtained by hydrolysis of sugar cane bagasse followed by vapor training extraction. In the face of numerous and complex reactions involved in this synthesis, it is very complicated to define the kinetic laws from exact stoichiometry. A solution allowing to cope the problem consists in identifying an appropriate stoichiometric model. It does not attempt to represent exactly all the reaction mechanisms, but proposes a mathematical support to integrate available knowledge on the transformati...

2008-01-01

423

Steady-state isotopic transient kinetic analysis investigation of CO-O_2 and CO-NO reactions over a commercial automotive catalyst  

International Nuclear Information System (INIS)

In this paper, steady-state isotopic transient kinetic analysis (SSITKA) is used to study two model reactions, CO oxidation and CO-NO reactions, on a typical formulation of a three-way auto-catalyst. Under steady-state conditions, abrupt switches in the isotopic composition of CO ("1"2C"1"6O/"1"3C"1"8O) were carried out to produce isotopic transients in both labeled reactants and products. Along with the determination of the average surface lifetimes and concentrations of reaction intermediates, an analysis of the transient responses along the carbon reaction pathway indicated that the distribution of active sites for the formation of CO_2 was bimodal for both reactions. Furthermore, relatively few surface sites contributed to the overall reaction rate.

1991-08-25

424

Role of the diffuse layer in acidic and alkaline fuel cells  

British Library Electronic Table of Contents (United Kingdom)

A numerical model is developed to study electrolyte dependent kinetics in fuel cells. The model is based on the Poisson-Nernst-Planck (PNP) and generalized-Frumkin-Butler-Volmer (gFBV) equations, and is used to understand how the diffuse layer and ionic transport play a role in the performance difference between acidic and alkaline systems. The laminar flow fuel cell (LFFC) is used as the model fuel cell architecture to allow for the appropriate comparison of equivalent acidic and alkaline systems. We study the overall cell performance and individual electrode polarizations of acidic and alkaline fuel cells for both balanced and unbalanced electrode kinetics as well as in the presence of transport limitations. The results predict cell behavior based on electrolyte composition that strongly...

2011-01-01

425

Removal of reactive textile dyes (Remazol Brillant Blue R and Remazol Yellow) by surfactant-modified natural zeolite  

British Library Electronic Table of Contents (United Kingdom)

Abstract In this study, surfactant-modified zeolite (SMZ) was used to remove Remazol Brillant Blue R and Remazol Yellow reactive dyes from aqueous solutions. The influences of suspension pH, temperature, agitation rate, and the SMZ dosage on reactive dyes removal and adsorption capacity were investigated by conducting a series of batch adsorption experiments. The adsorption kinetics was tested for pseudo-first-order, pseudo-second order, intraparticle diffusion model, Elovich, and Bangham models, and rate constants of the kinetic models were calculated. Equilibrium isotherms for the adsorption of reactive dyes were analyzed by the Freundlich, Langmuir, Dubinin-Radushkevich, and Tempkin isotherm models. The Langmuir monolayer adsorption capacities of Remazol Brillant Blue R and Remazol Yell...

2011-01-01

426

Removal of reactive dye Brilliant Red HE-3B from aqueous solutions by industrial lignin: Equilibrium and kinetics modeling  

British Library Electronic Table of Contents (United Kingdom)

The lignin, one of the main by-products of the pulp industry, can be used to remove dyes from textile wastewaters. The potential of the lignin for Brilliant Red HE-3B reactive dye removal from aqueous solutions at pH=1.5 was examined by the batch technique as a function of dye concentration, solution temperature and contact time. The Freundlich, Langmuir, Dubinin-Radushkevich and Tempkin adsorption isotherms were used to describe the data of sorption equilibrium and to determine its corresponding isotherm constants. The thermodynamic parameters DG, DH and DS were also determined; the obtained values show that the sorption of reactive dye on lignin is a spontaneous, endothermic and entropy-driven process. The kinetic of reactive dye sorption was analyzed using the pseudo-first order and pse...

2010-01-01

427

Real-time neutron diffraction study of crystallization kinetics in amorphous Fe_7_8B_1_3Si_9 alloy  

International Nuclear Information System (INIS)

The transformation from the as-quenched amorphous to the crystalline state in Fe_7_8B_1_3Si_9 alloy has been investigated using a new-type neutron diffractometer. The time resolved diffraction patterns clearly show that this alloy crystallizes into FeSi alloy and Fe_2B in that order. The time evolution of these crystalline phases can be analyzed by the Kolmogorov-Johnson-Mehl-Avrami equation with the exponent of about 2.5 over a wide temperature range. This suggests that the crystallization occurs by the diffusion-controlled growth with a constant nucleation rate. The scaling behavior in the crystallization kinetics is also discussed. (author).

1987-01-01

428

Real-time neutron diffraction study of crystallization kinetics in amorphous Fe/sub 78/B/sub 13/Si/sub 9/ alloy  

Energy Technology Data Exchange (ETDEWEB)

The transformation from the as-quenched amorphous to the crystalline state in Fe/sub 78/B/sub 13/Si/sub 9/ alloy has been investigated using a new-type neutron diffractometer. The time resolved diffraction patterns clearly show that this alloy crystallizes into FeSi alloy and Fe/sub 2/B in that order. The time evolution of these crystalline phases can be analyzed by the Kolmogorov-Johnson-Mehl-Avrami equation with the exponent of about 2.5 over a wide temperature range. This suggests that the crystallization occurs by the diffusion-controlled growth with a constant nucleation rate. The scaling behavior in the crystallization kinetics is also discussed.

1987-09-01

429

Radiation oxidation of phenol in petrochemical waste water. II  

International Nuclear Information System (INIS)

The rate was studied of radiation destruction of phenol aqueous solutions at a concentration range of 1 to 100 ppm. Irradiated were model solutions containing additions of some organic and inorganic substances typical of the petrochemical industry. In view of the fact that the radiation destruction kinetics is determined by the amount of dissolved oxygen in the sample and by the phenol concentration, relatively low doses were used. Thus, a sufficient amount of oxygen in the sample and therefore the oxidation mechanism of radiolysis were ensured. The dose-response relationships for phenol destruction were studied using doses of 50, 100, 200 and 400 J.kg"-"1; the limit dose was 500 J.kg"-"1. From the results obtained, a kinetic model was constructed of radiation phenol oxidation in aqueous solutions in the presence of various organic and inorganic additions. (B.S.).

1981-01-01

430

Photosynthetic energy storage efficiency in Chlamydomonas reinhardtii, based on microsecond photoacoustics  

British Library Electronic Table of Contents (United Kingdom)

Using a novel, pulsed micro-second time-resolved photoacoustic (PA) instrument, we measured thermal dissipation and energy storage (ES) in the intact cells of wild type (WT) Chlamydomonas reinhardtii, and mutants lacking either PSI or PSII reaction centers (RCs). On this time scale, the kinetic contributions of the thermal expansion component due to heat dissipation of absorbed energy and the negative volume change due to electrostriction induced by charge separation in each of the photosystems could be readily distinguished. Kinetic analysis revealed that PSI and PSII RCs exhibit strikingly different PA signals where PSI is characterized by a strong electrostriction signal and a weak thermal expansion component while PSII has a small electrostriction component and large thermal expansion....

2011-01-01

431

Phase-Separation Kinetics and Mechanism in a Methylcellulose/Salt Aqueous Solution Studied by Time-Resolved Small-Angle Light Scattering (SALS)  

British Library Electronic Table of Contents (United Kingdom)

Abstract Phase-separation dynamics are investigated by SALS in aqueous MC solutions in the presence of 5% NaCl, promoted by a quench temperature. The observed scattering peak indicates that the phase separation occurs by the SD mechanism, leading to a bicontinuous structure. A semilog plot of I(q) against time in the early stage of SD gives a straight line, but the position of qmax varies; also, a Cahn-Hilliard plot indicates that diffusive processes dominate and the data can be described by linear CHC theory. Dapp shows a kinetic dependency on the quench temperature. The spinodal temperature of the sample is 41-C. In the late stages, S(q,t) collapses into a universally time-independent curve.

2011-01-01

432

Non-dissipative kinetic simulation and analytical solution of three-mode equations of ion temperature gradient instability  

Energy Technology Data Exchange (ETDEWEB)

A non-dissipative drift kinetic simulation scheme, which rigorously satisfies the time-reversibility, is applied to the three-mode coupling problem of the ion temperature gradient (ITG) instability. It is found from the simulation that the three-mode ITG system repeats growth and decay with a period which shows a logarithmic divergence for infinitesimal initial perturbations. Accordingly, time average of the mode amplitude vanishes, as the initial amplitude approaches to zero. An exact solution is analytically given for a class of initial conditions. An excellent agreement is confirmed between the analytical solution and numerical results. The results obtained here provide a useful reference for basic benchmarking of theories and simulation of the ITG modes. (author)

1999-12-01

433

Modelling of the partial oxidation of {alpha}, {beta}-unsaturated aldehydes on Mo-V-oxides based catalysts  

Energy Technology Data Exchange (ETDEWEB)

A kinetic model based on the Mars-van Krevelen mechanism that allows to describe the microkinetics of the heterogeneously catalysed partial oxidation of {alpha}, {beta}-unsaturated aldehydes is presented. This conversion is represented by a network, composed of the oxidation of the {alpha}, {beta}-unsaturated aldehyde towards the {alpha}, {beta}-unsaturated carboxylic acid and the consecutive oxidation of the acid as well as the parallel reaction of the aldehyde to products of deeper oxidation. The reaction steps of aldehyde respectively acid oxidation and catalyst reoxidation have been investigated separately in transient experiments. The combination of steady state and transient experiments has led to an improved understanding of the interaction of the catalyst with the aldehyde and the carboxylic acids as well as to a support of the kinetic model assumptions. (orig.)

1998-12-31

434

Kinetics of the azidization of 2,4-dinitrohalogenobenzenes with tetraethylammonium azide in acetonitrile and mixed acetonitrile-dioxane solvent  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the reaction of 2,4-dinitrohalogenobenzenes (chlorine, bromine, and iodine derivatives) with tetraethylammonium azide in acetonitrile and in a mixed acetonitrile-dioxane solvent (80 vol. % dioxane) were studied. It was established that there is a marked increase (by more than three orders of magnitude) in the azidization rate constant in the transition from protic solvents to aprotic media, due to the decrease in the activation energy barrier of the reaction. The nucleophilicity parameters N/sup +/ for the azide ion in the investigated solvents were determined in terms of Ritchie's relationship. It was established that the effect of the nature of the leaving group on the rate constant of the reactions is complex in character, and it was shown that treatment of the relative reactivity series for the investigated substrates must be based on an analysis of the activation parameters and not restricted to data obtained at only one temperature.

1986-03-20

435

Kinetics of spherulite formation and growth: Salt and protein concentration dependence on proteins b-lactoglobulin and insulin  

British Library Electronic Table of Contents (United Kingdom)

Proteins aggregated into spherulite structures of amyloid fibrils have been observed in patients with certain brain diseases such as Alzheimers and Parkinsons. The conditions under which these protein spherulites form and grow are not currently known. In order to illuminate the role of environmental factors on protein spherulites, this research aims to explore the kinetics and mechanisms of spherulite formation and growth, as monitored by optical microscopy, in a range of salt concentrations, and initial protein concentrations for two model proteins: bovine b-lactoglobulin and insulin. These two proteins are significantly different in their size and fibril growth rate, but both of these proteins have been shown previously to form amyloid fibrils and spherulites under low pH conditions. The...

2009-01-01

436

Kinetics of pore coarsening in glassy carbon  

Energy Technology Data Exchange (ETDEWEB)

One third of the microstructure of glassy carbon (GC) consists of closed pores. Density measurements indicate that the total pore volume depends only on the heat treatment temperature and not on the heat treatment time, a characteristic of coarsening. The kinetics of coarsening of these pores on heat treatment has been investigated by analyzing the changes in specific surface area of the pores as determined by the small angle X-ray scattering (SAXS) technique. A part of the surface area change is due to thermal expansion induced microcracking. Both the superposition method after correcting the thermal expansion induced surface area change and the curve fitting method give an activation energy of 64 +/- 10 kcal/mole. This value is compared with the activation energies of various rate processes in graphite. A model of coarsening of the pores based on a vacancy migration mechanism is proposed.

1981-01-01

437

Kinetics of inhibition of green crab (Scylla serrata) alkaline phosphatase by sodium (2,2'-bipyridine) oxodiperoxovanadate.  

Science.gov (United States)

Green crab (Scylla serrata) alkaline phosphatase (EC 3.1.3.1) is a metalloenzyme, which catalyzes the nonspecific hydrolysis of phosphate monoesters. The kinetics of inhibition of the enzyme by sodium (2, 2'-bipyridine) oxodiperoxovanadate, pV(bipy), has been studied. The time course of the hydrolysis of p-nitrophenyl-phosphate catalyzed by the enzyme in the presence of different pV(bipy) concentrations showed that at each pV(bipy) concentration, the rate decreased with increasing time until a straight line was approached, the straight line slopes are the same for all concentrations. The results suggest that the inhibition of the enzyme by pV(bipy) is a slow, reversible reaction with fractional remaining activity. The microscopic rate constants are determined for the reaction of inhibitor with the enzyme. PMID:10691182

1999-10-01

438

Kinetics of hydrolysis of PET powder in nitric acid by a modified shrinking-core model  

Energy Technology Data Exchange (ETDEWEB)

Poly(ethylene terephthalate) (PET) powder from waste bottles was degraded at atmospheric pressure in 7--13 M nitric acid at 70--100 C for 72 h, to clarify the mechanism of a feed stock recycling process. Terephthalic acid (TPA) and ethylene glycol (EG) were produced by the acid-catalyzed heterogeneous hydrolysis of PET in nitric acid, and the resulting EG was simultaneously oxidized to oxalic acid. The kinetics of the hydrolysis of PET in nitric acid could be explained by a modified shrinking core model of chemical reaction control, in which the effective surface area is proportional to the degree of unreacted PET, affected by the deposition of the product TPA. The apparent rate constant was inversely proportional to particle size and to the concentration of the nitric acid. The activation energy of the reaction was 101.3 kJ/mol.

1998-02-01

439

Kinetics of carbon dioxide absorption in aqueous solutions of diisopropanolamine  

Energy Technology Data Exchange (ETDEWEB)

A bubble column absorber was used to investigate kinetics of the reaction between carbon dioxide and aqueous solutions of diisopropanolamine (DIPA), by means of gas absorption experiments. These were conducted in the temperature range of 10 to 40deg C, with DIPA concentrations from 5 to 500 mol/m{sup 3}, and CO{sub 2} partial pressures between 5 and 101 kPa. A model based on the Danckwerts' surface reneval theory was used to analyze the experimental results and to determine the rate constant. The obtained data support the assumption of a second-order overall reaction, with the rate constants being well correlated by the Arrhenius equation: k{sub 2} = 1.112 x 10{sup 10} exp(-4848/T). (orig.).

1992-04-01

440

Kinetics of a reactive dye adsorption onto dolomitic sorbents.  

Science.gov (United States)

A novel wastewater treatment technique has been investigated, for reactive dye removal, in batch kinetic systems. These experimental studies have indicated that charred dolomite has the potential to act as an adsorbent for the removal of Brilliant Red reactive dye from aqueous solution. The effect of initial dye concentration, adsorbent mass:liquid volume ratio, and agitation speed on dye removal have been determined with the experimental data mathematically described using empirical external mass transfer and intra-particle diffusion models. The experimental data show conformity with an adsorption process, with the removal rate heavily dependent on both external mass transfer and intra-particle diffusion. PMID:12691893

2003-05-01

441

Kinetics and mechanism of the reaction between portland cement and clinoptilolite  

International Nuclear Information System (INIS)

When clinoptilolite is immobilized in cement-based composites, a series of reactions occur, leading to release of Cs. These reactions occur in three overlapping stages: a rapid ion exchange, followed by a somewhat slower reaction between clinoptilolite and principally the Ca(OH)_2 component of cement, and, in the longer term, slower reactions with C-S-H leading either to formation of low-lime C-S-H at temperatures below 100"0C or 11 A (1.1 nm) tobermorite at higher temperatures. Kinetic data are presented to evaluate the rate of physical consumption of the zeolites at 70 and 150"0C. Reactions occurring above 100"0C appear to result in the development of extensive microcracking of cement-zeolite composites containing 50% zeolite.

442

Kinetic manifestation of cooperative interaction between quinuclidinyl benzilate and rat brain muscarine cholinoreceptors  

Energy Technology Data Exchange (ETDEWEB)

A study was made of the kinetics of L-(/sup 3/H)quinuclidinyl benzilate binding with membrane-bound muscarine cholinoreceptors from the rat brain. Determination was made of the rate constants of this process, and constants as a function of ligand concentration was investigated, indicating that there is a complex mechanism of interaction of antagonists with muscarine receptor. With up to 3.5 nM concentrations of L-(/sup 3/H)quinuclidinyl benzilate, the binding reaction occurs in two stages: rapid equilibrated binding is followed by a slow process of conformational isomerization of the receptor-ligand complex. At higher ligand concentrations, there is additional drastic increase in constant of rate of ligand binding a new plateau is reached. Such dependence of rate constant on ligand concentration is indicative of the cooperative nature of interaction between antagonists and muscarine receptors. This is possible if there are in the receptor complex several binding ...

1985-01-01

443

Kinetic behavior of solid particle in chemical-looping combustion: suppressing carbon deposition in reduction  

Energy Technology Data Exchange (ETDEWEB)

In order to apply chemical-looping combustion to a practical power plant, carbon deposition on the solid particle is one of the key problems to be overcome. Six kinds of solid particles were examined to clarify the kinetic behavior of carbon deposition. The effects of the solid composition, feed gas composition, and reaction temperature on carbon deposition were investigated by thermogravimetrical reactor on the basis of NiO/YSZ particle. From the viewpoints of both reactivity and resistance against carbon deposition, the particle of NiO mixed with YSZ (i.e., yttria-stabilized zirconia) was found to be a good candidate for chemical-looping combustion. It has been observed that carbon deposition could be completely avoided with very low concentration of water vapor. By means of a proposed model, the condition that carbon deposition would be avoided was identified. 12 refs., 8 figs., 2 tabs.

1998-03-01

444

Investigation of a hydraulic impact: a technology in rock breaking  

CERN Document Server

The finite element method and dimensional analysis have been applied in the present paper to study a hydraulic impact, which is utilized in a non-explosive rock breaking technology in mining industry. The impact process of a high speed piston on liquid water, previously introduced in a borehole drilled in rock, is numerically simulated. The research is focused on the influences of all the parameters involved in the technology on the largest principal stress in the rock, which is considered as one of the key factors to break the rock. Our detailed parametric investigation reveals that the variation of the isotropic rock material properties, especially its density, has no significant influence on the largest principal stress. The influences of the depth of the hole and the depth of the water column are also very small. On the other hand, increasing the initial kinetic energy of the piston can dramatically increase the largest principal stress and the best way to ...

2009-01-01

445

Influence of mass transfer on thermogravimetric analysis of combustion and gasification reactivity of coke  

British Library Electronic Table of Contents (United Kingdom)

Non-isothermal TG/DTG measurements are widely used to determine kinetic parameters of oxidation and gasification of carbons, e.g. by multi-heating rate methods. Thereby it is important to avoid spurious effects due to diffusion limitations. In this work, TG/DTG experiments with activated carbon were conducted under isothermal and non-isothermal conditions. The agreement of the experimental results with results of simulations based on the intrinsic kinetics, pore diffusion and external diffusion in/to the sample (crucible) is very good. The simulations show that mass transfer has an unwanted influence on TG measurements, if the concentration of the gaseous reactant (O2 and CO2) is too low and/or the heating rate is too high. Based on literature data, the simulation was extended to blast fur...

2010-01-01

446

Influence of Pressurisation on SOFC Performance and Durability: ATheoretical Study  

British Library Electronic Table of Contents (United Kingdom)

Abstract Hybrid power plants consisting of a solid oxide fuel cell (SOFC) and a gas turbine show high electrical efficiencies, however require pressurisation of the SOFC to several bar. This paper presents a theoretical investigation of the pressure influence on SOFC performance and durability. A two-dimensional elementary kinetic model is used to predict the performance of a single cell in the pressure range of 1-20-bar. The influence of pressure on thermodynamics, reaction kinetics, porous electrode diffusion, channel transport and efficiency is assessed. It was found that polarisation resistance decreases with increasing pressure due to increased diffusion through porous electrodes and a higher electrode surface coverage with reactant species. Furthermore, open-circuit voltage increases...

2011-01-01

447

In vivo distribution and excretion studies and in vitro blood studies on the kinetics of lead-203 in beagle dogs  

International Nuclear Information System (INIS)

Studies on the kinetics of the distribution of lead-203 in body fluids have been carried out in vitro, and in animal studies using beagle dogs. In vitro, the distribution of carrier free lead-203 between plasma and cells of canine blood at 37"0C was measured after the addition of isotope. In animal studies, activity in plasma was measured for about 150 hours, and activity in blood cells, urine and feces measured for about 400 hours after exposure to lead-203. Linear compartmental models for distribution of the isotope are presented for both in vitro and in vivo experimental systems. The models contain compartments for both untransformed lead, for isotope added in saline or citric acid, and transformed lead, as obtained by lead-203 incubation in plasma.

448

Impaired mitochondrial energy metabolism and kinetic properties of cytochrome oxidase following acute aluminium phosphide exposure in rat liver  

British Library Electronic Table of Contents (United Kingdom)

The present study was designed with an aim to analyze the effect of acute aluminium phosphide (ALP) exposure (10mg/kg b.wt, intragastrically) on the kinetic characteristics of cytochrome oxidase and energy metabolism in male Wistar rat liver mitochondria. Liver mitochondrial preparations from ALP-treated rats exhibited significant decrease (66%) in the activity of cytochrome oxidase suggesting that there was a decrease in the catalytic efficiency of the active oxidase molecules on ALP treatment. The decreased activity of cytochrome oxidase with altered NADH and succinic dehydrogenase activities might have contributed towards a significant decline in state 3 and state 4 respiration as observed. These alterations in the electron transport chain complexes in turn adversely affected the ATP sy...

2010-01-01

449

Identity and yield of positive charge centers in irradiated chloro hydrocarbon liquids and the rates of their interaction with solute molecules. [3-4 MeV electrons  

Science.gov (United States)

Pulse radiolysis studies of the formation kinetics and the yields of various phenylcarbenium ions from several different solutes in 1,2-dichloroethane solution have been carried out. The results indicate that there are two kinetically distinguishable cationic species of the solvent which react selectively with the different solutes to form the phenylcarbenium ions. It is suggested that one is a cation radical (yield 0.68 molecule/100 eV) and the other a carbocation (yield 0.20 molecule/100 eV). Rate constants for their separate reactions with selected aromatic compounds and with ammonia have been determined. Molar extinction coefficients have been estimated for benzyl cation, diphenyl cation radical, and anthracene cation radical. 6 figures, 1 table.

1979-07-26

450

Identity and yield of positive charge centers in irradiated chloro hydrocarbon liquids and the rates of their interaction with solute molecules  

International Nuclear Information System (INIS)

Pulse radiolysis studies of the formation kinetics and the yields of various phenylcarbenium ions from several different solutes in 1,2-dichloroethane solution have been carried out. The results indicate that there are two kinetically distinguishable cationic species of the solvent which react selectively with the different solutes to form the phenylcarbenium ions. It is suggested that one is a cation radical (yield 0.68 molecule/100 eV) and the other a carbocation (yield 0.20 molecule/100 eV). Rate constants for their separate reactions with selected aromatic compounds and with ammonia have been determined. Molar extinction coefficients have been estimated for benzyl cation, diphenyl cation radical, and anthracene cation radical. 6 figures, 1 table.

1979-07-01

451

Hydriding properties of a mechanically milled Mg-50 wt.% ZrFe{sub 1.4}Cr{sub 0.6} composite  

Energy Technology Data Exchange (ETDEWEB)

The ball-milling method was used to produce Mg-50 wt.% ZrFe{sub 1.4}Cr{sub 0.6} composite. The thermodynamic, kinetic, and cycling properties, as well as the resistance to oxidation were examined. This composite possesses excellent kinetic properties, even at moderate temperature. Scanning electron microscopy, energy-dispersive spectrum, transmission electron microscopy and X-ray diffraction were used to characterize the composite before and after hydriding. The fine ZrFe{sub 1.4}Cr{sub 0.6} particles covering Mg particles acting as a ''catalytic film'', a significant amount of imperfections and some alloy powder in the Mg matrix introduced by ball milling all contributed to the enhanced absorption/desorption rate. (orig.)

2000-02-02

452

Green synthesis of iron nanoparticles and their application as a Fenton-like catalyst for the degradation of aqueous cationic and anionic dyes  

British Library Electronic Table of Contents (United Kingdom)

Iron nanoparticles were produced using extracts of green tea leaves (GT-Fe NPs). The materials were characterized using TEM, SEM/EDX, XPS, XRD, and FTIR techniques and were shown to contain mainly iron oxide and iron oxohydroxide. The obtained nanoparticles were then utilized as a Fenton-like catalyst for decolorization of aqueous solutions containing methylene blue (MB) and methyl orange (MO) dyes. The related experiments investigated the removal kinetics and the effect of concentration for both MB and MO. The concentrations of dyes in aqueous solution were monitored using ultraviolet-visible (UV-vis) spectroscopy. The results indicated fast removal of the dyes with the kinetic data of MB following a second order removal rate, while those of MO were closer to a first order removal rate. T...

2011-01-01

453

Formation of complex Langmuir and Langmuir-Blodgett films of water soluble rosebengal  

British Library Electronic Table of Contents (United Kingdom)

This communication reports the formation of complex Langmuir monolayer at the air-water interface by charge transfer types of interaction with the water soluble N-cetyl Formula Not Shown -trimethyl ammonium bromide (CTAB) molecules doped with rosebengal (RB), with the stearic acid (SA) molecules of a preformed SA Langmuir monolayer. The reaction kinetics of the formation of RB-CTAB-SA complex monolayer was monitored by observing the increase in surface pressure with time while the barrier was kept fixed. Completion of interaction kinetics was confirmed by FTIR study. This complex Langmuir films at the air-water interface was transferred onto solid substrates at a desired surface pressure to form multilayered Langmuir-Blodgett films. Spectroscopic characterizations reveal some molecular lev...

2007-01-01

454

Erosive radially-slotted discharge in sheet current mode  

CERN Document Server

New non-stationary non-contracted form of the erosive radially-slotted discharge as a thin round sheet with the current of the azimuth direction have been discovered, its existence beings stipulated by a radial transport-wave fluxes. Characteristic features of this discharge is self-confinement of the discharge current magnitude, corresponding decrease of the current pulse duration and occurrence of an energy and substance ejection with rather unusual properties. Measurements of kinetics of the discharge current, the plasma radiation intensity and an electrical probe signal, as well as the transmission electron microscope investigations of characteristic aerodisperse aggregates arising the erosive phase, have been carried out. The probe signal duration was about 10 times greater than that of the current; its kinetics was complicated suggesting existence in the slot of two components with fundamentally different properties and states of the ...

2001-01-01

455

Electrochemical and ellipsometric investigations of Passive Films formed on iron in borate solutions: the kinetics of film growth on iron at constant anodic potentials  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of passive film formation on iron in borate buffer solution has been studied at different anodic potentials. The process of film growth has been found to occur in four distinct stages. About 80-90% of the total film thickness formed in 1h grows during the initial two stages which last for only 1-3s (depending upon potential). The electric field strength across the film is not constant but decreases with progressing film growth. The thickness of the film determined ellipsometrically is less than that calculated from the electric charge consumed. The process of anodic film formation is accompanied by the dissolution of iron which occurs over the whole range of potentials.

1984-02-01

456

Dye Removal, Energy Consumption and Operating Cost of Electrocoagulation of Textile Wastewater as a Clean Process  

British Library Electronic Table of Contents (United Kingdom)

Abstract In this research, the efficiency of electrocoagulation treatment process using aluminum electrodes to treat synthetic wastewater containing Reactive Red198 (RR198) was studied. The effects of parameters such as voltage, time of reaction, electrode connection mode, initial dye concentration, electrolyte concentration, and inter electrode distance on dye removal efficiency were investigated. In addition, electrical energy consumption, electrode consumption, and operating cost at optimum condition have been investigated. The results showed that dye and chemical oxygen demand removals were 98.6 and 84%, respectively. Electrode consumption, energy consumption and operating cost were 0.052-kg/m3, 1.303-kWh/m3 and 0.256-US$/m3, respectively. Dye removal kinetic followed first order kinet...

2011-01-01

457

Does external pressure explain recent results for molecular clouds?  

British Library Electronic Table of Contents (United Kingdom)

Abstract The recent paper by Heyer et al. indicates that observations of size, linewidth and column density of interstellar clouds do not agree with simple virial equilibrium (SVE) as a balance between gravitational and kinetic energies in the sense that the clouds either have too much kinetic energy or too little mass to be bound. This may be explained by violation of SVE as suggested by Dobbs et al., by observational underestimation of the masses as suggested by Heyer et al. or by an external pressure acting as an additional confining force as suggested earlier by Heyer et al. The data of Heyer et al. cannot be explained with a single value for the external pressure, but if different clouds in the sample have different external pressures in the range of Pe/k= 104-107 cm-3-K, then most of...

2011-01-01

458

Development of a detailed kinetic model for gasoline surrogate fuels  

Energy Technology Data Exchange (ETDEWEB)

A detailed chemical kinetic model to describe the autoignition of gasoline surrogate fuels is presented consisting of the fuels iso-octane, n-heptane, toluene, diisobutylene and ethanol. Model predictions have been compared with shock tube ignition delay time data for surrogates of gasoline over practical ranges of temperature and pressure, and the model has been found to be sensitive to both changes in temperature and pressure. Moreover, the model can qualitatively predict the observed synergistic and antagonistic non-linear blending behaviour in motor octane number (MON) for different combinations of primary reference fuels (PRFs) and non-PRFs by correlating calculated autoignition delay times from peak pressures and temperatures in the MON test to experimental MON values. The reasons for the blending behaviour are interpreted in terms autoignition chemistry. 37 refs., 11 figs., 4 tabs.

2008-08-15

459

Continuous-distribution kinetics for degradation of polybutylene terephthalate (PBT) in supercritical methanol  

British Library Electronic Table of Contents (United Kingdom)

The depolymerization of polybutylene terephthalate (PBT) in supercritical methanol was investigated by using a batch autoclave reactor. Continuous kinetics analysis was applied to experimental data. It was observed that PBT could dissolve into supercritical methanol quickly and decompose completely in a homogeneous phase. PBT with average molecular weight of about 29 700 was converted to oligomer with that of 4200 within 10 min and with that of 2700 in 15 min at 513 K and converted into monomer completely within 22 min. The main reaction products decomposed of PBT were dimethylterephthalate (DMT) and 1, 4-butanediol (BG) by methanolysis. The yields of monomer components of the decomposition products, including byproducts were measured. The yields of DMT and BG could reach 94.5% and 70.1%, ...

2009-01-01

460

Concordant Chemical Reaction Networks  

CERN Document Server

We describe a large class of chemical reaction networks, those endowed with a subtle structural property called concordance. We show that the class of concordant networks coincides precisely with the class of networks which, when taken with any weakly monotonic kinetics, invariably give rise to kinetic systems that are injective --- a quality that, among other things, precludes the possibility of switch-like transitions between distinct positive steady states. We also provide persistence characteristics of concordant networks, instability implications of discordance, and consequences of stronger variants of concordance. Some of our results are in the spirit of recent ones by Banaji and Craciun, but here we do not require that every species suffer a degradation reaction. This is especially important in studying biochemical networks, for which it is rare to have all species degrade.

2011-01-01

461

Biosorption and biodegradation interactions - a study on lindane  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of biosorption and desorption of lindane by live activated sludge and the fungus R. arrhizus was studies. The results from the use of live activated sludge suggest that besides biosorption, other lindane removal mechanisms acted in parallel. Most probably, biodegradation. A relationship between biodegradation and bisorption-desorption was established. Mass spectroscopy and gas chromatography studies suggested the presence of lindane biodegradation by products. Lindane accumulated by the live activated sludge could be desorbed while being biodegraded at the same time. Values for lindane biokinetic constants were estimated. Biosorption of lindane by live R. arrhizus is a rapid and reversible process with no indication of biodegradation. Values for the lindane biotransformation kinetic coefficients were estimated. (orig.).

1991-03-01

462

Bimodal colloidal mixtures: From fast to slow aggregation regions  

British Library Electronic Table of Contents (United Kingdom)

A Brownian dynamics simulation has been used to investigate the aggregation kinetics of bimodal colloidal mixtures with similar surface chemistries but different sizes, driven by the DLVO interaction potential. The time evolution of structural formation is examined by the mean number of neighbors under fast and slow aggregation regions. It was found that the electrolyte ionic strength affects the kinetic pattern of colloidal aggregation. Under the high electrolyte ionic strength conditions (fast aggregation), the selective aggregation of the least stable single component can take place in the early stage, while the other component is enriched in this least stable component in the later stage. With the ionic strength decreasing (towards the slow aggregation), the hybrid aggregation (selecti...

2011-01-01

463

An Accurate Numerical Solution to the Kinetics of Breakable Filament Assembly  

CERN Document Server

Proteinaceous aggregation occurs through self-assembly-- a process not entirely understood. In a recent article [1], an analytical theory for amyloid fibril growth via secondary rather than primary nucleation was presented. Remarkably, with only a single kinetic parameter, the authors were able to unify growth characteristics for a variety of experimental data. In essence, they seem to have uncovered the underlying allometric laws governing the evolution of filament elongation simply from two coupled non-linear ordinary differential equations (ODEs) stemming from a master equation. While this work adds significantly to our understanding of filament self-assembly, it required an approximate analytical solution representation. Here, we show that the same results are found by purely numerical means once a straightforward and reliable numerical solution to the set of ODEs has been established.

2010-01-01

464

A principle of charged particle trapping by RF electromagnetic field in the spherical cavity  

Energy Technology Data Exchange (ETDEWEB)

A new principle of particle trapping in the simple spherical cavity using both electric and magnetic components of radiofrequency electromagnetic field is proposed. The electric component of H {sub 12} oscillating mode drives the fast particle oscillations, while the magnetic component synchronously bends the trajectories to the cavity center. A specially developed theory of particle stability predicts dense and energetic electron cluster in the trap. Numerical simulations of particle dynamics in the complete electromagnetic field taking into account both space charge and particle-induced magnetic field are in good agreement with the analytic results, giving a density of 2.6*10{sup 1} electrons/cm{sup 3} and an average kinetic energy of around 30 keV at an operating frequency of 3 GHz. Being used at lower frequency, spherical cavity can trap protons and heavier ions too, but with lower density and kinetic energy.

2005-11-21

465

Water management studies in PEM fuel cells, part III: Dynamic breakthrough and intermittent drainage characteristics from GDLs with and without MPLs  

British Library Electronic Table of Contents (United Kingdom)

The transport of liquid water and gaseous reactants through a gas diffusion layer (GDL) is one of the most important water management issues in a proton exchange membrane fuel cell (PEMFC). In this work, the liquid water breakthrough dynamics, characterized by the capillary pressure and water saturation, across GDLs with and without a microporous layer (MPL) are studied in an ex-situ setup which closely simulates a real fuel cell configuration and operating conditions. The results reveal that recurrent breakthroughs are observed for all of the GDL samples tested, indicating the presence of an intermittent water drainage mechanism in the GDL. This is accounted for by the breakdown and redevelopment of the continuous water paths during water drainage as demonstrated by Haines jumps. For GDL ...

2010-01-01

466

Theory of oiligopoly: Cournot equilibrium in exhaustible resource markets with fixed supplies  

Energy Technology Data Exchange (ETDEWEB)

Assuming Cournot behavior in open loop strategies by the several sellers, an imperfectly competitive market for an exhaustible resource is studied. An equilibrium develops with the following properties: industry production declines over time, as does the present value of market price net of unit extraction cost. The degree of concentration in supply increases over time, tending toward monopoly. Larger firms earn a lower rate of return on their endowment, and perceive a smaller increment to profits from the acquisition of new stocks. Industry prices and supply paths are insensitive to a local redistribution of endowments. The relative deadweight burden of oiligopoly is small for plausible values of market parameters. 14 references.

1983-01-01

467

The results of physical modeling of flow in an axial cyclone combustion chamber; Ergebnisse physikalischer Modellierung der Stroemung in einer Axialzyklonbrennkammer  

Energy Technology Data Exchange (ETDEWEB)

The isothermal flow field for the axial cyclone has been experimentally determined. The velocity fields are used for determination particle paths (particle removal and suspended state), and inter alia of heat and mass transfer processes in the axial cyclone combustion chamber. The results are extremely significant as input value approximations for mathematical modelling, since experimentally obtained results are indispensable for complex flows and geometries. (orig.) [Deutsch] Es ist fuer den Axialzyklon experimentell das isotherme Stroemungsfeld ermittelt. Die Geschwindigkeitsfelder dienen zur Ermittlung der Partikelbahnen (Partikelabscheidung, Schwebebedingung), der Waerme- und Stoffuebertragungsprozesse u.a. in der Axialzyklonbrennkammer. Die Ergebnisse sind als Startwertnaeherung bei einer mathematischen Modellierung sehr wichtig, da bei komplexen Stroemungen und Geometrien versuchstechnische Ergebnisse unumgaenglich sind. (orig.)

1994-12-31

468

The Xygra gun simulation tool.  

Energy Technology Data Exchange (ETDEWEB)

Inductive electromagnetic launchers, or coilguns, use discrete solenoidal coils to accelerate a coaxial conductive armature. To date, Sandia has been using an internally developed code, SLINGSHOT, as a point-mass lumped circuit element simulation tool for modeling coilgun behavior for design and verification purposes. This code has shortcomings in terms of accurately modeling gun performance under stressful electromagnetic propulsion environments. To correct for these limitations, it was decided to attempt to closely couple two Sandia simulation codes, Xyce and ALEGRA, to develop a more rigorous simulation capability for demanding launch applications. This report summarizes the modifications made to each respective code and the path forward to completing interfacing between them.

2008-12-01

469

The Path to Metallicity: Synthesis of CNO Elements inStandard BBN  

Energy Technology Data Exchange (ETDEWEB)

We perform an analysis of the production of elements with mass number A {ge} 12 in a standard Big Bang Nucleosynthesis scenario. The goal is to provide a more accurate estimate of the very low and yet poorly explored abundance of such elements, relevant for the pristine Population III stars. We examine the synthesis channels for these elements in a critically revised and updated version of the Wagoner-Kawano code, as well as in a further enlarged version including four additional nuclides and a significantly extended nuclear network. Our results show no major discrepancies with the ones obtained using a smaller nuclear network. The robustness of the standard predictions--the early generation of star developed in a metal-free environment--is confirmed.

2007-02-12

470

The Environmental Kuznets Curve. An empirical analysis for OECD countries  

Energy Technology Data Exchange (ETDEWEB)

This paper tests the Environmental Kuznets Curve hypothesis for four local (SOx, NOx, CO, VOC) and two global (CO2, GHG) air pollutants. Using a new panel data set of thirty OECD countries, the paper finds that the postulated inverted U-shaped relationship between income and pollution does not hold for all gases. A meaningful Environmental Kuznets Curve exists only for CO, VOC and NOx, where for CO2 the curve is monotonically increasing. For GHG there is indication of an inverted U-shaped relationship between income and pollution, but still most countries are on the increasing path of the curve and hence the future development of the curve is uncertain. For SOx it was found that emissions follow an U-shaped curve. Based on the empirical results, the paper concludes that the Environmental Kuznets Curve does not hold for all gases, it is rather an empirical artefact than a regularity.

2008-09-15

471

The Environmental Kuznets Curve. An empirical analysis for OECD countries  

International Nuclear Information System (INIS)

This paper tests the Environmental Kuznets Curve hypothesis for four local (SOx, NOx, CO, VOC) and two global (CO2, GHG) air pollutants. Using a new panel data set of thirty OECD countries, the paper finds that the postulated inverted U-shaped relationship between income and pollution does not hold for all gases. A meaningful Environmental Kuznets Curve exists only for CO, VOC and NOx, where for CO2 the curve is monotonically increasing. For GHG there is indication of an inverted U-shaped relationship between income and pollution, but still most countries are on the increasing path of the curve and hence the future development of the curve is uncertain. For SOx it was found that emissions follow an U-shaped curve. Based on the empirical results, the paper concludes that the Environmental Kuznets Curve does not hold for all gases, it is rather an empirical artefact than a regularity.

2008-01-01

472

Study of Zircaloy-2 corrosion in high temperature water using ion beam methods  

Energy Technology Data Exchange (ETDEWEB)

Experiments have been carried out in water at 355 C to study transport of oxygen and hydrogen (as deuterium) in growing corrosion films. Composition of the films was also examined in 2.9 Mev and 3.9 Mev /alpha/-particle backscattering experiments. Corrosion occurs predominantly by oxygen diffusion through the film via grain boundary or similar short circuit diffusion paths, to form fresh oxide at the oxide metal interface. Increasing grain size within thick pre-breakaway films contributes to a decrease in diffusivity. The rate transition results from the generation of new diffusion pathways in previously protective oxide. Unexpectedly high concentrations of deuterium were observed. 26 refs.

1981-10-01

473

Rondonia Deforestation (WMS)  

Science.gov (United States)

Throughout much of the 1980s, deforestation in Brazil eliminated more than 15,000 square kilometers (9000 square miles) of forest per year. Data gathered by several satellites in the Landsat series of spacecraft shows enormous tracts of forest disappearing in Rondonia, Brazil from 1975 through 2001. The human phenomenon of deforestation starts, especially in the dense tropical forests of Brazil, when systematic cutting of a road opens new territory to potential deforestation by penetrating into new areas. Clearing of vegetation along the sides of those roads then tends to fan out to create a pattern akin to a fish skeleton. As new paths appear in the woods, more areas become vulnerable. Finally, the spaces between the skeletal bones fall to defoliation.

2005-02-17

474

Real-time monitoring of moisture levels in wound dressings in vitro: An experimental study  

British Library Electronic Table of Contents (United Kingdom)

Retaining an appropriate level of moisture at the interface between a healing wound and an applied dressing is considered to be critical for effective wound healing. Failure to control exudate at this interface can result in maceration or drying out of the wound surface. The ability to control moisture balance at the wound interface is therefore a key aspect of wound dressing performance. To date it has not been possible to monitor in any effective manner the distribution of moisture within dressings or how this varies with time.A new measurement system is presented based on sensors placed at the wound/dressing interface which are capable of monitoring moisture levels in real time. The system comprises a model wound bed and sensor array complete with fluid injection path to mimic exudate f...

2007-01-01

475

Radiation Protection Aspects of the Linac Coherent Light Source Front End  

Energy Technology Data Exchange (ETDEWEB)

The Front End Enclosure (FEE) of the Linac Coherent Light Source (LCLS) is a shielding housing located between the electron dump area and the first experimental hutch. The upstream part of the FEE hosts the commissioning diagnostics for the FEL beam. In the downstream part of the FEE, two sets of grazing incidence mirror and several collimators are used to direct the beam to one of the experimental stations and reduce the bremsstrahlung background and the hard component of the spontaneous radiation spectrum. This paper addresses the beam loss assumptions and radiation sources entering the FEE used for the design of the FEE shielding using the Monte-Carlo code FLUKA. The beam containment system prevents abnormal levels of radiations inside the FEE and ensures that the beam remains in its intended path is also described.

2010-08-26

476

Quick. How much material in that pile  

Energy Technology Data Exchange (ETDEWEB)

Presented are nomographs for calculating volume of bulk materials (e.g. coal, ores, sand, limestone) in conical or oblong piles formed by means of throwers and other mechanical transporting devices. The author explains that when a thrower is stationary, the pile formed resembles a cone and its projection on the ground is roughly circular. If thrower is moving, in general along a straight path, the final shape is more oblong, resulting from overlapping of separately formed cones. Slope of piles depends on the angle of repose which material makes with the horizontal when piled. This angle depends on such factors as internal friction of material stored, the throwing impact, fineness of grains, and moisture content. Volume is determined from the angle of repose and geometrical data on the area occupied by the pile.

1982-10-01

477

Quantum coherence in ion channels: resonances, transport and verification  

Energy Technology Data Exchange (ETDEWEB)

Recently it was demonstrated that long-lived quantum coherence exists during excitation energy transport in photosynthesis. It is a valid question up to which length, time and mass scales quantum coherence may extend, how one may detect this coherence and what, if any, role it plays in the dynamics of the system. Here we suggest that the selectivity filter of ion channels may exhibit quantum coherence, which might be relevant for the process of ion selectivity and conduction. We show that quantum resonances could provide an alternative approach to ultrafast two-dimensional (2D) spectroscopy to probe these quantum coherences. We demonstrate that the emergence of resonances in the conduction of ion channels that are modulated periodically by time-dependent external electric fields can serve as signatures of quantum coherence in such a system. Assessments of experimental feasibility and specific paths towards the experimental realization of such experiments are ...

2010-08-15

478

Point-splitting regularization of composite operators and anomalies  

CERN Document Server

The point-splitting regularization technique for composite operators is discussed in connection with anomaly calculation. We present a pedagogical and self-contained review of the topic with an emphasis on the technical details. We also develop simple algebraic tools to handle the path ordered exponential insertions used within the covariant and non-covariant version of the point-splitting method. The method is then applied to the calculation of the chiral, vector, trace, translation and Lorentz anomalies within diverse versions of the point-splitting regularization and a connection between the results is described. As an alternative to the standard approach we use the idea of deformed point-split transformation and corresponding Ward-Takahashi identities rather than an application of the equation of motion, which seems to save the complexity of the calculations.

2000-01-01

479

Perceived service quality and self-concept influences on consumer attitude and purchase process: A comparison between physical and internet channels  

British Library Electronic Table of Contents (United Kingdom)

This study aimed to explore the impact of perceived service quality and self-concept on consumer attitude and purchase process using channel type (physical and Internet) as a segmentation variable. From the perspective of consumer behaviour, this study attempted to estimate a relational model and perform an empirical validation using female cosmetics and skincare products as an example. It was discovered that the influence of perceived service quality and self-concept on consumer attitude, purchase intention and behaviour, satisfaction, and loyalty varied with channel type. The analysis result revealed that physical stores presented higher levels of agreement with all research perspectives than Internet stores. However, only two relational paths have a higher influencing effect in physical...

2011-01-01

480

Partial wave expansion of ion-atom elastic scattering in solids  

International Nuclear Information System (INIS)

Elastic scattering cross sections of keV protons in solids (Z=3-82) are calculated using the partial wave expansion technique and the ''muffin-tin'' bound-atom potential. The differential cross sections for small scattering angles of less than 10deg are smaller than those with the Ziegler-Biersack-Littmark potential at all energies and for all solids, although, for larger angles, the two cross sections agree with each other. The mean free paths of the protons in the solids, obtained from the total cross sections, decrease very slowly with decreasing energy. Furthermore, at low energies they approach half the nearest-neighbor distance, which is taken as the radius of the augmented plane wave sphere in the muffin-tin model of crystalline solids. (orig.).

481

PROSPECTS AND STATUS OF LOW-ASPECT-RATIO TOKAMAKS  

Energy Technology Data Exchange (ETDEWEB)

The prospects for the low-aspect-ratio (A) tokamak to fulfill the requirements of viable fusion power plants are considered relative to the present status in data and modeling. Desirable physics and design features for an attractive Blanket Test Facility and power reactors are estimated for low-A tokamaks based on calculations improved with the latest data from small pioneering experiments. While these experiments have confirmed some of the recent predictions for low-A, they also identify the remaining issues that require verification before reliable projections can be made for these deuterium-tritium applications. The results show that the low-A regime of small size, modest field, and high current offers a path complementary to the standard and high A tokamaks in developing the full potential of fusion power.

1995-01-01

482

Minimum work requirement for water production in humidification?dehumidification desalination cycle  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a theoretical analysis based on the second law of thermodynamics for estimating the minimum work required for air dehumidification process to produce potable water in a humidification-dehumidification (HD) desalination cycle. The general air dehumidification process is analyzed through an equivalent path consisting of an isothermal dehumidification followed by a sensible cooling Dehumidification is treated as separation process of an ideal mixture consisting of two components, namely air and water vapor. The present analysis assumes the dead state to be the dry ambient and the final state for complete dehumidification to be saturated air at 0.01?C. Contours of the minimum work are plotted on psychrometric chart and presented as a handy engineering tool to estimate the p...

2007-01-01

483

Mechanisms of obesity-induced male infertility  

British Library Electronic Table of Contents (United Kingdom)

Male infertility, characterized by hypogonadism, decreased semen quality or ejaculatory dysfunction, accounts for approximately 20% of infertility cases. Obesity and metabolic dysfunction have been identified, among other causal factors, to contribute to male infertility. In the context of the Western world's `obesity epidemic', this article discusses three main biological mechanisms linking obesity to impaired male reproductive function: hypogonadism, testicular heat stress/hypoxia-induced apoptosis and endocrine disruption by `obesogens'. Among these, obesity-induced hypogonadism is undoubtedly the most clinically significant and is easily assessed. Rapidly expanding areas of research in this area include leptin modulation of kisspeptins and hypothalamic-pituitary-testicular hormone path...

2010-01-01

484

Matching of water and temperature fields in proton exchange membrane fuel cells with non-uniform distributions  

British Library Electronic Table of Contents (United Kingdom)

In this work, a three-dimensional multiphase non-isothermal model incorporated with a capillary-extended sub-model in gas channels is used to investigate the coupled phenomena of water and thermal transport in proton exchange membrane fuel cells. Distributions of water and temperature along the flow path in the channel are highlighted and the pros and cons of various operating temperatures are elaborated. In addition, this work also sheds light on the impacts of temperature variations of bipolar plates induced by non-uniform cooling conditions, which have been overlooked by most previous works. An important phenomenon of water distribution, dry-out at inlets and flooding at outlets (DIFO), is observed and this non-uniform distribution is revealed to be greatly influenced by the operating t...

2011-01-01

485

Joint implementation for cost-effective carbon dioxide emission-reductions: An analysis of options in eastern Europe  

Energy Technology Data Exchange (ETDEWEB)

The costs of greenhouse gas emission-reductions vary among countries depending on emission levels, technologies used, past emission-reduction achievements, path of economic development, fuel mix, and initial endowment of hydrocarbon resources. The criterion of cost-effectiveness therefore suggests that the ways should be found to encourage emission reductions in the countries where the required costs of reduction of additional unit of emissions are the lowest. These countries usually face crucial capital constraints and have other development priorities than investing in reduction of greenhouse gas emissions. Developed countries could invest their resources in the former Soviet Union and the east European countries to achieve the same level of reduction of greenhouse gases with lower costs than they could in their own countries.

1996-12-31

486

Increased capability of Strassy: the decision making aid for the inspection of nuclear materials; Prolongement des capacites de Strassy: systeme d`aide a la decision pour le controle des matieres nucleaires  

Energy Technology Data Exchange (ETDEWEB)

The paper describes the latest developments in STRASSY (Strategy Assistance System), the strategy assistance system for the inspection of nuclear materials. The user can now select the fuel cycle he wishes to investigate from an initial range of 19 facilities. An inspection interface has been developed to enable the details and dates of inspections to be modified. One of the special features of the application of STRASSY in international safeguards is the taking into account of timeliness of detection; certain aspects of the time manager algorithms are presented and analysed, including the guaranteed existence of a solution. The results of a study of diversion paths in a simplified cycle consisting of our facilities are presented. Finally, the modifications necessary to enable STRASSY to be used for a posterior analysis of inspection results are discussed. (authors). 7 refs., 3 figs.

1994-12-31

487

Implantation of a essential diesel generator CN Vandellos II and fifth emergency diesel generator Asco  

International Nuclear Information System (INIS)

This article describes the project for the installation of an additional emergency diesel generator in both Asco and Vandellos NPPs. The basic objectives of this project are to improve the availability of the emergency generation system, in order to provide greater ability to address potential contingencies, and also to increase the flexibility of the preventive periodic maintenance of the emergency diesel generators. This maintenance, that is currently a milestone of the critical path of the refueling outage, will be performed on-line. The new diesel generator will be sized to support all the loads considered in the safety case and also the consumption of its own auxiliary systems, and will be tested for operability assessment on the same periodical basis than the existing ones. The solution adopted will also permit that the N diesel generator may be connected to any bus bar class 1E in a station black-out scenario. (Author)

488

For its batteries, the automobile imitates the cellular phone; Pour ses batteries, la voiture imite le telephone mobile  

Energy Technology Data Exchange (ETDEWEB)

To gain in efficiency, lightness and volume, the hybrid and electric-powered cars will certainly follow the cellular phone path. The key of success of todays hybrid cars is the Ni-MH battery developed by Matsushita (87.5% of the market in 2004). The lithium-ion batteries will be the next step and would allow to supply 80 to 100% of the energy of the vehicle, the thermal engine becoming just an auxiliary system for additional power, autonomy and air-conditioning. Prototypes can reach today 200 to 450 km of autonomy and 130 km/h speeds with batteries of about 200 kg. If most of the safety problems linked with the Li technology have been solved, the main drawback remains the cost of the Li-ion technology. Short paper. (J.S.)

2005-09-28

489

Exploring the potential energy surface for proton transfer in acetylacetone  

Energy Technology Data Exchange (ETDEWEB)

The portion of the potential energy surface (PES) of acetylacetone relevant for the intramolecular proton transfer reaction is studied using ab initio and DFT methods. The best estimate of the barrier governing proton transfer was found to be 3.4 kcal mol{sup -1} at the MP4(FC)/6-311 + G(2d,2p)//MP2(FC)/6-311 + G(2d,2p) level of theory. Six stationary points on the PES were characterized as well as the reaction paths connecting these points. Special attention paid to the pathway of intramolecular proton transfer reveals that the internal rotation of the methyl group adjacent to the carbonyl group and the proton transfer reaction are consecutive processes.

2004-11-15

490

Equipment hardening and hardness assurance  

International Nuclear Information System (INIS)

The introduction of tolerance to radiation (''radiation-hardness'') into large electronic systems is one of the major tasks to which this Handbook will be put. The practices recommended here for inculcating radiation-tolerance in equipment require advanced physical modeling techniques, precise engineering procedures, and firm assurance procedures. The degree to which these procedures should be used in an equipment project can be measured by the severity of the raw radiation environment, the desired reliability of the system, and the requirement of that project for radiation-sensitive technologies. The balance of device/circuit design versus shielding will depend on whether the radiation is highly penetrating -- as in isotope handling or military environments -- or readily attenuated, as in space. In this chapter the authors have attempted to summarize the essential features of the radiation hardening of large assemblies of equipment and how effective control of radiation effects, that ...

491

Effect of decrease of molybdenum radiation hardening at high energy proton irradiation  

International Nuclear Information System (INIS)

By method of transmission electron microscopy and measuring of microhardness the peculiarities of influence of radiation defect clusters on molybdenum radiation hardening along range path of protons with 30 MeV initial energy are studied. Decrease effect of hardening growth value and even its absence depending on irradiation dose in the range of 10-20 MeV proton energies in presence of high density of radiation defect dispersed clusters is revealed. It is shown experimentally that this effect is connected with accumulation of hydrogen up to not very high concentrations (not more than 5x10"-"4 at.%) at the expense of elastic and inelastic proton scattering. 5 refs.; 5 figs.

1990-05-22

492

Corruption and the environmental Kuznets Curve: Empirical evidence for sulfur  

British Library Electronic Table of Contents (United Kingdom)

We investigate how corruption influences the income level at the turning point of the relationship between sulfur emissions and income, using a wide cross-national panel of countries, at different levels of development and with different degrees of corruption. Our results support the Environmental Kuznets Curve hypothesis for sulfur. We find evidence that the higher the country's degree of corruption, the higher the per capita income at the turning point, suggesting different income-pollution paths across countries due to corruption. We build upon a new specification for the EKC developed by Bradford et al. (2005) that avoids using nonlinear transformations of potentially nonstationary regressors in panel estimation. Also, we account for the indirect impact of corruption on emissions throu...

2010-01-01

493

Comparative study of three dimensional numerical simulations of particle dispersion in a turbulent air flow  

International Nuclear Information System (INIS)

This paper describes the study of particles' dispersion in an isotropic turbulent flow. The particle's motion and the turbulent flow characteristics are calculated independently. While the particles' displacement is computed by the author's code, the flow is simulated with a commercial code : PowerFLOW. The particles and the flow are coupled through the relative velocity component of the aerodynamic force. When the simulated flow is turbulent, a turbulence regeneration model is used in order to get the flow instantaneous velocity. Validation of the method is done by comparing the particles' dispersion obtained with experimental results from literature and with the results calculated by FLUENT. Good accordance is found between numerical studies and experimental results. However, comparison between results of PowerFLOW coupled to the author's code and results from FLUENT shows differences when the particle's path goes through the turbulent boundary layer. (author)

2004-05-09

494

Comparative planetology, climatology and biology of Venus, Earth and Mars  

British Library Electronic Table of Contents (United Kingdom)

Spacecraft studies of the three terrestrial planets with atmospheres have made it possible to make meaningful comparisons that shed light on their common origin and divergent evolutionary paths. Early in their histories, all three apparently had oceans and extensive volcanism; Mars and Earth, at least, had magnetic fields, and Earth, at least, had life. All three currently have climates determined by energy balance relationships involving carbon dioxide, water and aerosols, regulated by solar energy deposition, atmospheric and ocean circulation, composition, and cloud physics and chemistry. This paper addresses the extent to which current knowledge allows us to explain the observed state of each planet, its planetology, climatology and biology, within a common framework. Areas of ignorance...

2011-01-01

495

A review of eighteen years of operation based on the most significant performance indicators; Un repaso a dieciocho anos de operacion a travges de los indicadores de funcionamiento mas significativos  

Energy Technology Data Exchange (ETDEWEB)

This month, the Cofrentes Nuclear Power Plant celebrates its 18th year of operation, this path is supported rom source by excellent operating results and is cause for the professional pride of those who throughout the years, have been involved on a day to-day basis is its evolution. This article describes the Plant's most significant milestones from the time of its construction up to the present. The different sections cover everything from the most relevant performance indicators to such specific aspects as optimization of refueling times. (Author)

2002-07-01

496

A methodology to estimate travel time using dynamic traffic assignment (DTA) under incident conditions  

British Library Electronic Table of Contents (United Kingdom)

This paper presents results from a research case study that examined the distribution of travel time of origin-destination (OD) pairs on a transportation network under incident conditions. Using a transportation simulation dynamic traffic assignment (DTA) model, incident on a transportation network is executed under normal conditions, incident conditions without traveler information availability, and incident conditions assuming that users had perfect knowledge of the incident conditions and could select paths to avoid the incident location. The results suggest that incidents have a different impact on different OD pairs. The results confirm that an effective traveler information system has the potential to ease the impacts of incident conditions network wide. Yet it is also important to n...

2011-01-01

497

A Network Coding Approach to Loss Tomography  

CERN Document Server

Network tomography aims at inferring internal network characteristics based on measurements at the edge of the network. In loss tomography, in particular, the characteristic of interest is the loss rate of individual links. There is a significant body of work dedicated to this problem using multicast and/or unicast end-to-end probes. Independently, recent advances in network coding have shown that there are several advantages from allowing intermediate nodes to process and combine, in addition to just forward, packets. In this paper, we pose the problem of loss tomography in networks that have network coding capabilities. We design a framework for estimating link loss rates, which leverages network coding capabilities and we show that it improves several aspects of tomography, including the identifiability of links, the tradeoff between estimation accuracy and bandwidth efficiency, and the complexity of probe path selection. We discuss the cases of inferring: the ...

2010-01-01

498

A Detailed Investigation on Human-Related Unplanned Reactor Trip Events in Korea  

International Nuclear Information System (INIS)

Human errors have been reported as one of the most significant causes of major events in nuclear power plants (NPPs). For example, Kim and Park found that about 23% of the major events that occurred at NPPs in Republic of Korea from 1986 to 2006 were caused by human errors. For this reason, a detailed analysis on human errors is an important task for increasing the safety of NPPs. Kim and Choi?2 analyzed 100 human-related unplanned reactor trip events in the Republic of Korea from 1986 to 2006 to consider the type of human errors based on the simple path model for human-induced unplanned reactor trips developed by Kim and Park. In this paper, we will investigate and perform a detailed analysis of the data to identify human-related unplanned reactor trip trends

2010-10-01