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Sample records for permian c1 coal

  1. Nanoquartz in Late Permian C1 coal and the high incidence of female lung cancer in the Pearl River Origin area: a retrospective cohort study

    Zhou Yiping

    2008-12-01

    Full Text Available Abstract Background The Pearl River Origin area, Qujing District of Yunnan Province, has one of the highest female lung cancer mortality rates in China. Smoking was excluded as a cause of the lung cancer excess because almost all women were non-smokers. Crystalline silica embedded in the soot emissions from coal combustion was found to be associated with the lung cancer risk in a geographical correlation study. Lung cancer rates tend to be higher in places where the Late Permian C1 coal is produced. Therefore, we have hypothesized the two processes: C1 coal combustion --> nanoquartz in ambient air --> lung cancer excess in non-smoking women. Methods/Design We propose to conduct a retrospective cohort study to test the hypothesis above. We will search historical records and compile an inventory of the coal mines in operation during 1930–2009. To estimate the study subjects' retrospective exposure, we will reconstruct the historical exposure scenario by burning the coal samples, collected from operating or deserted coal mines by coal geologists, in a traditional firepit of an old house. Indoor air particulate samples will be collected for nanoquartz and polycyclic aromatic hydrocarbons (PAHs analyses. Bulk quartz content will be quantified by X-ray diffraction analysis. Size distribution of quartz will be examined by electron microscopes and by centrifugation techniques. Lifetime cumulative exposure to nanoquartz will be estimated for each subject. Using the epidemiology data, we will examine whether the use of C1 coal and the cumulative exposure to nanoquartz are associated with an elevated risk of lung cancer. Discussion The high incidence rate of lung cancer in Xuan Wei, one of the counties in the current study area, was once attributed to high indoor air concentrations of PAHs. The research results have been cited for qualitative and quantitative cancer risk assessment of PAHs by the World Health Organization and other agencies. If

  2. Palynomorphs of Permian Gondwana coal from borehole GDH-38, Barapukuria Coal Basin, Bangladesh

    Akhtar, A.; Kosanke, R.M. [Geological Survey of Bangladesh, Dhaka (Bangladesh)

    2000-07-01

    Thirty-two core samples of Permian Gondwana coal from three coal beds of borehole GDH-38, Barapukuria Coal Basin, Dinajpur, Bangladesh, were collected for palynological analysis. The lower coal bed (331.5-372.5 m) can easily be differentiated from the upper two coal beds by the presence of Alisporites, Cordaitina, Corisaccites, Hamiapollenites, Leuckisporites, Nuskoisporites, Tumoripollenites, Vestgisporites and Vittatina. It is difficult to palynologically differentiate the middle (198.1-208 m) and upper (162.3-172.9 m) coal beds as they contain a very limited number of specimens by which they can be identified. The middle bed is distinguished by the presence of Microbaculispora and Weylandites and the upper bed by the presence of a single taxon Acanthotriletes. Some of the vesiculate or saccate taxa extracted from these coal beds are typical of those occurring in Permian strata of Gondwana in India, South Africa, South America, Russia, Australia and Antarctica. They are thought to be derived from Glossopteris flora, which is characterised by an abundance of Pteridospermic plants of the gymnosperm group.

  3. Palynomorphs of Permian Gondwana coal from borehole GDH-38, Barapukuria Coal Basin, Bangladesh

    Akhtar, A.; Kosanke, R. M.

    2000-07-01

    Thirty-two core samples of Permian Gondwana coal from three coal beds of borehole GDH-38, Barapukuria Coal Basin, Dinajpur, the north-northwestern part of Bangladesh, have been collected for palynological analysis. All samples except one yielded palynomorphs and some samples contain well-preserved and abundant palynomorphs of the gymnospermal and cryptogamic groups that are considered to be useful for future correlation studies. The lower coal bed (331.6-372.5 m) can easily be differentiated from the upper two coal beds by the presence of Alisporites, Cordaitina, Corisaccites, Hamiapollenites, Leuckisporites, Nuskoisporites, Tumoripollenites, Vestgisporites and Vittatina. It is difficult to palynologically differentiate the middle (198.1-208 m) and upper (162.3-172.9 m) coal beds as they contain a very limited number of specimens by which they can be identified. The middle bed is distinguished by the presence of Microbaculispora and Weylandites and the upper bed by the presence of a single taxon Acanthotriletes. Some of the vesiculate or saccate taxa extracted from these coal beds are typical of those occurring in Permian strata of Gondwana in India, South Africa, South America, Russia, Australia and Antarctica. They are thought to be derived from Glossopteris flora, which is characterised by an abundance of Pteridospermic plants of the gymnosperm group.

  4. Mineralogical characterization of ambient fine/ultrafine particles emitted from Xuanwei C1 coal combustion

    Lu, Senlin; Hao, Xiaojie; Liu, Dingyu; Wang, Qiangxiang; Zhang, Wenchao; Liu, Pinwei; Zhang, Rongci; Yu, Shang; Pan, Ruiqi; Wu, Minghong; Yonemochi, Shinich; Wang, Qingyue

    2016-03-01

    Nano-quartz in Xuanwei coal, the uppermost Permian (C1) coal deposited in the northwest of Yuanan, China, has been regarded as one of factors which caused high lung cancer incidence in the local residents. However, mineralogical characterization of the fine/ultrafine particles emitted from Xuanwei coal combustion has not previously been studied. In this study, PM1 and ultrafine particles emitted from Xuanwei coal combustion were sampled. Chemical elements in the ambient particles were analyzed by inductively coupled plasma mass spectrometry (ICP-MS), and mineralogical characterization of these ambient particles was investigated using scanning electronic microscopy (SEM/EDX) and transmission electronic microscopy, coupled with energy-dispersive spectroscopy (TEM/EDX). Our results showed that the size distribution of mineral particles from the coal combustion emissions ranged from 20 to 200 nm. Si-containing particles and Fe-containing particles accounted for 50.7% of the 150 individual particles measured, suggesting that these two types of particles were major minerals in the ambient particles generally. The nano-mineral particles were identified as quartz (SiO2) and gypsum (CaSO4) based on their crystal parameters and chemical elements. Additionally, there also existed unidentified nano-minerals. Armed with these data, toxicity assessments of the nano-minerals will be carried out in a future study.

  5. STUDY ON REGULATIONS OF.SULFUR OCCURRENCE AND PYRITE MAGNETISM OF LATE PERMIAN COALS IN SOUTHWEST CHINA

    任德贻; 唐跃刚; 雷加锦

    1994-01-01

    The Permian coal In southwest China contains highest sulfur among the Chinese coal. Compositional variations of sulfur in coal are mainly controlled by paiaogeographicai environments during peat accumulation. High organic sulfur coal is formed in peat swamp developing in tidal flat of limited carbonate platform, and it is provided with especial petrological and geochemical characteristics, and its organosuLfur-containing compounds are mainly thiophene series. The macroscopical and microscopical shapes or types of pyrites in Late Permian coal are diversified. Bituminous coal and anthracite are diamagnetic, but the pyrites are paramagnetic. The magnetic susceptibility of the pyrites is depended on the content of paramagnatic elements associated with pyrites.

  6. Inorganic chemistry, petrography and palaeobotany of Permian coals in the Prince Charles Mountains, East Antarctica

    Holdgate, G.R.; McLoughlin, S.; Drinnan, A.N.; Finkelman, R.B.; Willett, J.C.; Chiehowsky, L.A.

    2005-01-01

    Sampled outcrops of Permian coal seams of the Bainmedart Coal Measures in the Lambert Graben, eastern Antarctica, have been analysed for their proximates, ultimates, ash constituents and trace elements. A similar series of samples has been analysed for their principle maceral and microlithotype components and vitrinite reflectance. The coals are sub-bituminous to high volatile bituminous in rank; maturity increases markedly in southern exposures around Radok Lake where the oldest part of the succession is exposed and some strata have been intruded by mafic dykes and ultramafic sills. The coal ash is mostly silica and aluminium oxides, indicating that the mineral ash component is mostly quartz and various clay minerals. The ratio of silica to aluminium oxides appears to increase in an upward stratigraphic direction. The coal macerals include a relatively high liptinite content (mainly sporinite) that is significantly higher than for typical Gondwana coals. Greater degrees of weathering within the floodbasin/peat mire environments associated with climatic drying towards the end of the Permian might account for both preferential sporopollenin preservation and increased silica:aluminium oxide ratios up-section. Correlation of the coal maceral components to adjacent peninsula India coals indicates the closest comparative coals of similar age and rank occur within the Godavari Basin, rather then the Mahanadi Basin, which is traditionally interpreted to have been contiguous with the Lambert Graben before Gondwanan breakup. The petrological characteristics suggest that either previous interpretations of Palaeozoic basin alignments between Antarctica and India are incorrect, or that environmental settings and post-Permian burial histories of these basins were strongly independent of their tectonic juxtaposition. A permineralized peat bed within the succession reveals that the coals predominantly comprise wood- and leaf-rich debris derived from low-diversity forest

  7. Geochemical characteristics of Guizhou Permian coal measure strata and analysis of the control factors

    YANG Rui-dong; LIU Ling; WEI Huai-rui; CUI Yu-chao; CHENG Wei

    2011-01-01

    Based on element geochemical studies of the main Permian exploitable coal measure strata in Western Guizhou, the element geochemical distribution characteristics of the main exploitable coal measures were revealed in the regions of Dafang,Qianxi, Weining, Hezhang, Zhijin, etc., of Guizhou Province, and the results show that their element contents are mainly affected by terrestrial material supply. Coal measures formed in the delta plain environment where sufficient terrestrial materials are supplied contain relatively abundant trace elements and rare-earth elements, whereas those formed in the tidal-flat environment influenced greatly by seawater have relatively low contents of trace elements and rare-earth elements, mainly controlled by the geological fact that basalts the parent rocks from source regions contain high trace elements and rare-earth elements. In addition, coal measures affected by later hydrothermal activities and fault tectonics contain a large amount of harmful elements. According to the rules of distribution of elements in coal measures, a new idea was put forward to classify coal-forming environments by using the geochemical composition characteristics, which is of great significance in dissolving the problem of whether coal measures were formed either in delta environments or in tidal-flat environments in Western Guizhou. At the same time, the rules of distribution of elements in the main exploitable coal measures in Western Guizhou were fully understood, which is of direct significance in utilizing coal resources on the basis of classification of coals, as well as in developing the coal chemical industry.

  8. Geochemistry of rare earth elements in Permian coals from the Huaibei Coalfield, China

    Zheng, Lingyun; Liu, Gaisheng; Chou, C.-L.; Qi, C.; Zhang, Y.

    2007-01-01

    The rare earth elements (REEs) in coals are important because of: (a) REE patterns can be an indicator of the nature of source rocks of the mineral matter as well as sedimentary environments; (b) REEs abundance in coal may have industrial-significance. In this study, a total of thirty-four samples of Permian coal, partings, roof, and floor were collected from the Huaibei Coalfield, Anhui Province, China. Abundances of rare earth elements (REEs) and other elements in the samples were determined by inductively coupled-plasma mass spectrometry (ICP-MS) and inductively coupled-plasma atomic emission spectrometry (ICP-AES). The results show that the REEs are enriched in coals in the Huaibei Coalfield as compared with Chinese and U.S. coals and the world coal average. Coals in the Lower Shihezi Formation (No. 7, 5, and 4 Coals) and Upper Shihezi Formation (No. 3) have higher REE abundances than the coals in Shanxi Formation (No. 10). Magmatic intrusion resulted in high enrichment of REEs concentrations in No. 5 and 7 Coals. The REE abundances are positively correlated with the ash content. The mineral matter in these coals is mainly made up of clay minerals and carbonates. The REEs are positively correlated with lithophile elements including Si, Al, Ti, Fe, and Na, which are mainly distributed in clay minerals, indicating that REEs are contained mainly in clay minerals. The REE abundances in coals normalized by the ash are higher than that in partings. REEs abundances of coals cannot be accounted for by the REE content in the mineral matter, and some REEs associated with organic matter in coals. ?? 2007 Elsevier Ltd. All rights reserved.

  9. Permian Mengkarang coal facies and environment, based on organic petrology study

    Nana Suwarna

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol1no1.20061aThe Permian Mengkarang Coal Measures is situated in the middle part of Sumatera Island. Some fresh outcrop samples of the Permian Mengkarang coals have been analyzed both macroscopically and microscopically, to asses their depositional environment. On the basis of organic-petrological analysis, the coal seams show variation in the predominance of some macerals, indicating successions of environmental changes. The dominant maceral group is vitrinite, present in very low to very high values; whilst the minor one is inertinite showing low amount. Environmental information derived from the organic facies study shows that the coals were deposited in wet zone of mire, ranges from wet limnic-telmatic zone to telmatic wet forest swamp under rapid burial condition, due to rapid basin subsidence. The organic facies concept is thus applicable in basin studies context and has potential to become an additional tool for interpretation of depositional environment.    

  10. Geochemistry of Permian Coal and Its Combustion Residues in Huainan Coalfield, China

    2001-01-01

    INAA (instrumental neutron activation analysis) was used to determine the contents of trace elements in coal samples from 11 workable Permian coal seams in Huainan coalfield. With XRFS (X-ray fluorescence spectrometry), the geochemical composition of its combustion residues from Tianjiaan Power Plant and Luohe Power Plant was analyzed. In addition, the electron microprobe was employed to study the chemical composition of some fly ashes and bottom ashes. Compared with those of the coals around the world, most trace elements of the Huainan coal are characterized by a normal abundance.Like most coals worldwide, the elements Se, S, As, Sb, Br, U and Cl are enriched in Huainan coal according to Clarks value, while the other elements tend to be diluted. The large fluctuation in the contents of trace elements in this kind of coal demonstrates great differences in coal seams. On the other hand, the contents of these elements are very similar in different bottom and fly ash samples. The elements with low organic affinity tend to concentrate in fly and bottom ash than in coal, especially those elements associated with Fe. However, the elements with strong organic affinity tend to be volatile during the combustion. Moreover, the abundance of the elements in fly ash and bottom ash changes with different densities and with different particle sizes. The bottom and fly ashes consist of glass, lime,mullite, coal residues and ferrite minerals. Some residual chars contain higher contents of volatile elements, such as S, P, Cl and As, indicating that the ash containing more residual chars has a strong adsorption of some hazardous elements, suggesting a possible utilization of power plant ash in the field of water cleaning.

  11. The flora of Early Permian coal measures from the Parana Basin in Brazil: A review

    Iannuzzi, Roberto [Centro de Investigacoes do Gondwana, Instituto de Geociencias, Universidade Federal do Rio Grande do Sul, Av. Bento Goncalves, 9500, Porto Alegre, RS, 91.509-900 (Brazil)

    2010-08-01

    This paper presents an updated overview integrating both previous and newly published data on the most important floras found associated with Early Permian coal seams in the Parana Basin, Brazil. These floras occur within the Rio Bonito Formation and correspond to the Gondwana ''Glossopteris Flora.'' For this review, five floras are selected, in ascending stratigraphic order: the ''Sao Joao do Triunfo,'' ''Figueira,'' ''Quiteria,'' ''Morro do Papaleo'' and ''Irapua Bed'' floras. They are the best-known floras of the basin in terms of taxonomic composition, paleoecology and environments of deposition. An early-mid Sakmarian to earliest Artinskian age is indicated for the Rio Bonito Formation based on absolute radiometric and relative biostratigraphic ages. Integration of available information about the selected floras allows evaluation of taphonomic and paleoecological factors to provide a more comprehensive understanding of the Early Permian floral record in the Parana Basin. The variation observed in both the taxonomic composition of individual floras and in the frequency of occurrence of different plant groups is due to the broad range of environmental/edaphic conditions that prevailed in the many different depositional settings represented in the Rio Bonito Formation. A more precise age determination obtained for the plant-bearing deposits permits the establishment of a more confident correlation between the Early Permian floral succession in the Parana Basin and other Early Permian floral successions in other basins. The Sakmarian global warming favored the appearance of pecopterid and sphenopterid ferns amongst the spore-producing plants, and the glossopterids amongst the pollen-producing plants. (author)

  12. Mineralogical and Geochemical Characteristics of Late Permian Coals from the Mahe Mine, Zhaotong Coalfield, Northeastern Yunnan, China

    Xibo Wang

    2015-07-01

    Full Text Available This paper reports the mineralogical and geochemical compositions of the Late Permian C2, C5a, C5b, C6a, and C6b semianthracite coals from the Mahe mine, northeastern Yunnan, China. Minerals in the coals are mainly made up of quartz, chamosite, kaolinite, mixed-layer illite/smectite (I/S, pyrite, and calcite; followed by anatase, dolomite, siderite, illite and marcasite. Similar to the Late Permian coals from eastern Yunnan, the authigenic quartz and chamosite were precipitated from the weathering solution of Emeishan basalt, while kaolinite and mixed-layer I/S occurring as lenses or thin beds were related to the weathering residual detrital of Emeishan basalt. However, the euhedral quartz and apatite particles in the Mahe coals were attributed to silicic-rock detrital input. It further indicates that there has been silicic igneous eruption in the northeastern Yunnan. Due to the silicic rock detrital input, the Eu/Eu* value of the Mahe coals is lower than that of the Late Permian coals from eastern Yunnan, where the detrital particles were mainly derived from the basalt. The high contents of Sc, V, Cr, Co, Ni, Cu, Ga, and Sn in the Mahe coals were mainly derived from the Kangdian Upland.

  13. Geochemistry and mineralogy of the Late Permian coals from the Songzao Coalfield, Chongqing,southwestern China

    2007-01-01

    Mineralogy and geochemistry of the four main workable coal seams (No.6, No.7, No.8, and No.11) of Late Permian age from the Songzao Coalfield, Chongqing, Southwest China, were examined using in- ductively coupled plasma-mass spectrometry (ICP-MS), X-ray fluorescence spectrometry (XRF), cold-vapor absorption spectrometry (CV-AAS), ion-selective electrode (ISE), scanning electron mi- croscopy equipped with an energy-dispersive X-ray spectrometer (SEM-EDX), and X-ray diffraction analysis (XRD). The results showed that the main workable No.8 Coal that accounts for about 60% of the total coal reserves in the Songzao Coalfield was not enriched in hazardous trace elements. The No.11 Coal has high concentrations of alkaline elements, Be (9.14 μg/g), Sc (12.9 μg/g), Ti (9508 μg/g), Mn (397 μg/g), Co (23.7 μg/g), Cu (108 μg/g), Zn (123 μg/g), Ga (32 μg/g), Zr (1304 μg/g), Nb (169 μg/g), Hf (32.7 μg/g), Ta (11.4 μg/g), W (24.8 μg/g), Hg (0.28 μg/g), Pb (28.1 μg/g), Th (24.1 μg/g), and rare earth elements (509.62 μg/g). The concentration of Nb and Ta in the No. 11 Coal is higher than the industrial grade, and their potential utilization should be further studied. Besides pyrite, quartz, calcite, and clay minerals, trace minerals including chalcopyrite, marcasite, siderite, albite, mixed-layer clay minerals of illite and smectite, monazite, apatite, anatase, chlorite, and gypsum were found in the No.11 Coal. It should be noted that alabandite of hydrothermal origin and anatase occurring as cement were identi- fied in coal. In addition, the clayey microbands derived from alkaline volcanic ashes were identified in the coal. The dominant compositions of these clayey microbands were mixed-layer clay minerals of illite and smectite, which were interlayered with organic bands. The modes of occurrence of alkaline volcanic ash bands indicate that the volcanic activities were characterized by the multiple eruptions, short time interval and small scale for each eruption

  14. [Research on hydrocarbon-generation mechanism of upper permian coals from Leping, Jiangxi, based on infrared spectroscopy].

    Yu, Hai-yang; Sun, Xu-guang

    2007-05-01

    Fourier transform infrared microspectroscopy (Micro-FTIR) technique was used to investigate the chemical compositions and structures of kerogen from the Late Permian bark coal in the B3 coal seam in mingshan mine, Leping, Jiangxi, at different temperatures. With the observation and the statistics of organic macerals under microscope, the author analysed the model of hydrocarbon generation of the bark coal in the B3 coal seam in mingshan mine, Leping, Jiangxi. And the author also estimated the oil and gas resources in Leping. The results indicate that the chemical composition of the coal is composed by aliphatic structure, heteroatomic compounds and aromatic structure, and their activation energy reduces in turn. Along with the rise in temperature, the intensity of aliphatic structure and heteroatomic compounds decreases obviously, however the aromatic structure changes little. The deamocollinite of B type and barkinite in the bark coal all can generate oil and gas easy, so the bark coal in Leping has a great petroleum-generating potential. PMID:17655089

  15. Depositional setting, petrology and chemistry of Permian coals from the Paraná Basin: 2. South Santa Catarina Coalfield, Brazil

    Kalkreuth, W.; Holz, M.; Mexias, A.; Balbinot, M.; Levandowski, J.; Willett, J.; Finkelman, R.; Burger, H.

    2010-01-01

    In Brazil economically important coal deposits occur in the southern part of the Paran?? Basin, where coal seams occur in the Permian Rio Bonito Formation, with major coal development in the states of Rio Grande de Sul and Santa Catarina. The current paper presents results on sequence stratigraphic interpretation of the coal-bearing strata, and petrological and geochemical coal seam characterization from the South Santa Catarina Coalfield, Paran?? Basin.In terms of sequence stratigraphic interpretation the precursor mires of the Santa Catarina coal seams formed in an estuarine-barrier shoreface depositional environment, with major peat accumulation in a high stand systems tract (Pre-Bonito and Bonito seams), a lowstand systems tract (Ponta Alta seam, seam A, seam B) and a transgressive systems tract (Irapu??, Barro Branco and Treviso seams).Seam thicknesses range from 1.70 to 2.39. m, but high proportions of impure coal (coaly shale and shaley coal), carbonaceous shale and partings reduce the net coal thickness significantly. Coal lithoypes are variable, with banded coal predominant in the Barro Branco seam, and banded dull and dull coal predominantly in Bonito and Irapu?? seams, respectively. Results from petrographic analyses indicate a vitrinite reflectance range from 0.76 to 1.63 %Rrandom (HVB A to LVB coal). Maceral group distribution varies significantly, with the Barro Branco seam having the highest vitrinite content (mean 67.5 vol%), whereas the Irapu?? seam has the highest inertinite content (33.8. vol%). Liptinite mean values range from 7.8. vol% (Barro Branco seam) to 22.5. vol% (Irapu?? seam).Results from proximate analyses indicate for the three seams high ash yields (50.2 - 64.2wt.%). Considering the International Classification of in-Seam Coals, all samples are in fact classified as carbonaceous rocks (>50wt.% ash). Sulfur contents range from 3.4 to 7.7 wt.%, of which the major part occurs as pyritic sulfur. Results of X-ray diffraction indicate the

  16. Composition and mode of occurrence of minerals in Late Permian coals from Zhenxiong County, northeastern Yunnan, China

    Tian Li; Shi-Feng Dai; Jian-Hua Zou; Sen Zhang; He-Hing Tian; Li-Xin Zhao

    2014-01-01

    Minerals in the Late Permian coals from the Niuchang-Yigu mining area, Zhenxiong County, northeastern Yunnan, China, were investigated using optical microscopy and low temperature ashing plus X-ray diffraction (LTA ? XRD). The results showed that minerals in the coal LTAs are mainly quartz, kaolinite, chamosite, mixed-layer illite/smectite (I/S), pyrite, and calcite, with trace amounts of marcasite, dolomite, and bassanite. The authigenic quartz generally occurs in collodetrinite or as a filling in cleats or cell cavities. This silica was mainly derived from aqueous solutions produced by the weathering of basaltic rocks in the Kangdian Upland and from hydrothermal fluids. The presence of b-quartz paramorph grains in collodetrinite probably indicates that these grains were detrital and came from a volcanic ash. Clay minerals are generally embedded in collodetrinite and occur as cell-fillings. Pyrite occurs as framboidal, anhedral, and euhedral grains and a cell-filling. The coals are high in pyrite and the high pyrite content probably results from seawater invading during the stage of peat accumulation. Calcite generally occurs as vein-fillings, indicating an epigenetic origin.

  17. Occurrence and origin of minerals in a chamosite-bearing coal of Late Permian age, Zhaotong, Yunnan, China

    Dai, S.; Chou, C.L. [China University of Mining and Technology, Beijing (China)

    2007-08-15

    The minerals found in the no. 5 coal (Late Permian) from the Zhaotong Coalfield, Yunnan Province, southwestern China, have been examined and found to consist mainly of kaolinite, pyrite, chamosite, quartz, and calcite, with trace amounts of illite and mixed-layer illite-smectite. The proportion of chamosite in clay minerals ranges from 32 to 56 wt%, with an average of 46 wt%. Chamosite is distributed not only in collodetrinite, but also occurs as cell fillings in fusinite, semifusinite, and telinite. The high content and mode of occurrence of chamosite in this mine indicate its formation by interaction of kaolinite with Fe-Mg-rich fluids during early diagenesis. Except for a minor amount of terrigenous quartz, most quartz is of authigenic origin and formed from kaolinite desilication. The calcite content of the no. 5 coal is 1.4-6.3% (with an average of 3%) and is distributed in collodetrinite and as cell fillings of coal-forming plants. Calcite originated from seawater invasion during peat accumulation. Pyrite occurs in several ways: as massive, framboidal, isolated enhedral/anhedral, and euhedral forms. In addition, the presence of a large amount of pyritized red algae provides strong evidence of seawater invasion during peat accumulation. The red algae may have played an important role in the enrichment of sulfur in the coal. The characteristic assemblage of minerals in this mine resulted from a unique basinal environment in which the mineral matter was derived from a basaltic source region, volcanic activity, and seawater transgression during coal formation.

  18. In Vitro Toxicity of Naturally Occurring Silica Nanoparticles in C1 Coal 
in Bronchial Epithelial Cells

    Guangjian LI

    2012-10-01

    Full Text Available Background and objective China’s Xuan Wei County in Yunnan Province have the world’s highest incidence of lung cancer in nonsmoking women-20 times higher than the rest of China. Previous studies showed, this high lung cancer incidence may be associated with the silica particles embedded in the production combustion from the C1 coal. The aim of this study is to separate the silica particles from production combustion from the C1 bituminous coal in Xuan Wei County of Yunnan Province, and study in vitro toxicity of naturally occurring silica particles on BEAS-2B. Methods ①Separating the silica particles from combustion products of C1 bituminous coal by physical method, observing the morphology by Scanning Electron Microscope, analysis elements by SEM-EDX, observed the single particle morphology by Transmission Electron Microscope, analyed its particle size distribution by Laser particle size analyzer, the surface area of silica particles were determined by BET nitrogen adsorption analysis; ②Cell viability of the experimental group (silica; naturally occurring, control group (silica; industrial produced and crystalline silica was detected by assay used the 3-(4,5-dimethylthiazol-2-yl-2,5-diphenyltetrazolium bromide (MTT method, and the reactive oxygen species (ROS, lactate dehydrogenase (LDH were determined after 24 h-72 h exposed to these particles. Results ①The physical method can separate silica particles from production combustion from the C1 bituminous coal, which have different size, and from 30 nm to 120 nm particles accounted for 86.8%, different morphology, irregular surface area and containing trace of aluminum, calcium and iron and other elements; ②Under the same concentration, the experiment group have higher toxicity on BEAS-2B than control groups. Conclusion ①Physical method can separate silica particles from production combustion from the C1 bituminous coal and not change the original morphology and containing trace;

  19. Age and significance of the Platypus Tuff Bed, a regional reference horizon in the Upper Permian Moranbah Coal Measures, north Bowen Basin

    Michaelsen, P.; Henderson, R.A.; Crosdale, P.J.; Fanning, C.M. [James Cook University of North Queensland, Townsville, Qld. (Australia). School of Earth Science

    2001-07-01

    The Platypus Tuff Bed in the Permian Moranbah Coal Measures provides a basin-wide marker horizon traceable for over 300 km along strike. The bed is a tephra event unit, the product of a large-scale volcanic eruptive episode involving a pyroclastic volume {gt} 10 km{sup 3}. The relatively even thickness of the tuff across the entire northern Bowen Basin implies a distant source. The tuff is ash-rich and its original geochemistry has been compromised by diagenetic alteration. Crystal content (10-15%) is dominated by quartz, suggesting a rhyolitic association. SHRIMP U-Pb analysis of zircons indicates an age of 258.9 +/- 2.7 Ma for the Platypus Tuff Bed, confirming the Late Permian age that has generally been assigned to the Blackwater Group. The age framework now apparent for the coal-bearing Blackwater Group suggests an average depositional rate ranging from about to 133 m/10{sup 6} years for its eastern depocentre in the northern Bowen Basin to similar to 70 m/10{sup 6} years in more marginal settings to the west.

  20. Age and significance of the Platypus Tuff Bed, a regional reference horizon in the upper Permian Moranbah coal measures, north Bowen Basin

    The Platypus Tuff Bed in the Permian Moranbah Coal Measures provides a basin-wide marker horizon traceable for over 300 km along strike. The bed is a tephra event unit, the product of a large-scale volcanic eruptive episode involving a pyroclastic volume > 10 km3. The relatively even thickness (∼1-1.5 m) of the tuff across the entire northern Bowen Basin (∼10 000 km2) implies a distant source. The tuff is ash-rich and its original geochemistry has been compromised by diagenetic alteration. Crystal content (10-15%) is dominated by quartz, suggesting a rhyolitic association. SHRIMP U-Pb analysis of zircons indicates an age of 258.9 ± 2.7 Ma for the Platypus Tuff Bed, confirming the Late Permian age that has generally been assigned to the Blackwater Group. The age framework now apparent for the coal-bearing Blackwater Group suggests an average depositional rate ranging from ∼133 m/106 years for its eastern depocentre in the northern Bowen Basin to ∼70 m/106 years in more marginal settings to the west. Copyright (2001) Geological Society of Australia

  1. Geochemistry of the late Permian No. 30 coal seam, Zhijin Coalfield of Southwest China: influence of a siliceous low-temperature hydrothermal fluid

    This paper describes the influence of siliceous low-temperature hydrothermal fluid on the elemental concentrations and mineralogical characteristics of the late Permian anthracitic (Ro,max=3.58%) coal seam (No. 30) from the Zhijin Coalfield in western Guizhou Province, SW China. Coal samples were examined using instrumental neutron activation analysis, inductively coupled plasma-mass spectroscopy, inductively coupled plasma-atomic emission spectrometry, X-ray fluorescence, powder X-ray diffraction, scanning electron microscopy equipped with energy-dispersive X-ray, and isotope analysis. The modes of occurrence of elements were determined using a sequential chemical extraction procedure. The studies indicate that the No. 30 coal seam has a very high content of veined quartz (vol. 9.4%), whose isotope values of δ30Si and δ18O are 0.6 per mille and 15.4 per mille, respectively, indicating that the quartz originated from siliceous low-temperature hydrothermal fluid (formation temperature 160-220 deg. C) rather than detrital material of terrigenous origin or magmatic hydrothermal inputs. Results of scanning electron microscopy equipped with energy-dispersive X-ray and sequential chemical extraction procedure show that the veined quartz is the dominant source of Fe, Cu, U, Pd, Pt and Ir, which are as high as 2.31%, 356, 8, 2.1, 2.43, and 0.006 μg/g in this coal seam, respectively. The studies have also found that elements, such as Fe and Cu are mainly in the veined quartz and they do not occur as sulfides in this coal seam, in sharp contrast to many other coal seams in China. The geochemical and mineralogical anomalies of the coal are attributed to the siliceous low-temperature hydrothermal fluid

  2. Sill-induced evaporite- and coal-metamorphism in the Tunguska Basin, Siberia, and the implications for end-Permian environmental crisis

    Svensen, Henrik; Polozov, Alexander G.; Planke, Sverre

    2014-05-01

    The emplacement of the Siberian Traps Large igneous province is regarded as the main processes behind the end-Permian environmental crisis. The details of this link are however still under investigation. Among the suggestions are lava degassing of mantle- and crustal-derived gases, explosive lava and phreatomagmatic eruptions, and gas release from contact metamorphism related to the sub-volcanic sill complex. Whereas the lava pile is relatively well studied and investigated, the sub-volcanic sills, dikes, and contact aureoles are poorly studied and documented. We present borehole and field data of sills and contact aureoles from across the Siberian Traps, from Norilsk in the north to Bratsk in the south. The data have been compiled during three field campaigns in 2004, 2006, and 2010. The sill geometries and thicknesses vary considerably from kilometer-scale intrusive complexes to individual thin sills of a few tens of meters. In contrast to several other LIPs, sills are also emplaced within the extrusive pile. Thick sills (up to 900 meters in thickness) occur in high abundance in the upper part of the sedimentary succession, affecting the coal-rich Tungusska Series sediments. Moreover, very thick sills (100-300 meters) are also emplaced within the vast Cambrian salt formations. Petrographic investigations of the metamorphic sediments demonstrate that widespread high temperature devolatilization took place. We show that depending on the specific location within the province and the emplacement depth, the potential for degassing of both greenhouse gases (CH4, CO2), aerosols (SO2), and ozone destructive gases (CH3Cl, CH3Br) was substantial and can explain the crisis.

  3. Palynological resolution of Permian sequence in Ib-River coalfield, Orissa and its environmental significance

    Goswami, S. [Fakir Mohan University, Vyasa Vihar (India). PG Dept. of Environmental Science

    2007-07-15

    The Ib-River coalfield, a part of Mahanadi Master Basin has rich deposit of Lower Permian Barakar coal. The palynological analysis of sediments from this coalfield has revealed the presence of distinct palynoassemblages. These assemblages represent Permian sequence from Lower Barakar (Early Permian) to Lower Kamthi (Late Permian) sediments. The present palynological studies help in redefining the status of Barakar and Kamthi Formations and in classifying them. Here the palynological assessment has been compared with the megafossil work of the author. Based on the palaeobotanical data, the stratigraphy of this coalfield has been proposed and the environment during Permian time has been discussed in this paper.

  4. Anomaly and geochemistry of rare earth elements and yttrium in the late Permian coal from the Moxinpo mine, Chongqing, southwestern China

    Jianhua Zou; Dong Liu; Heming Tian; Tian Li; Feng Liu; Lin Tan

    2014-01-01

    The rare earth elements and yttrium (REY) of the K2 coal from the Moxinpo mine, Chongqing, were deter-mined using inductively coupled plasma mass spectrometry (ICP-MS). The results show that REY are enriched in the K2 coal, with the average content up to 462 lg/g, much higher than average values of most coals in the world. The REY distribution patterns indicate that the light REY is enriched and show a well-pronounced Eu minimum. The fractionation of individual light-REY is higher than that of the heavy-REY. The REY distribution through the K2 coal seam shows that the top and bottom portion of the coal seam have a lower content of REY than the middle portion. Goyazite and rhabdophane were identified with a scanning electron microscope equipped with an energy-dispersed X-ray spectrometer (SEM-EDX). The REY distributions through the coal seam, SEM-EDX data and the correlation analysis between ash yields and the concentrations have revealed that the REY mainly occurs in the organic matter. The K2 coal is a potential rare-metal resource due to its high REY contents, and the coal ash could be regarded as a new and promising raw material for recovery of REY as a by-product.

  5. Mineralogical and compositional characteristics of Late Permian coals from an area of high lung cancer rate in Xuan Wei, Yunnan, China: Occurrence and origin of quartz and chamosite

    Dai, S.; Tian, L.; Chou, C.-L.; Zhou, Y.; Zhang, M.; Zhao, L.; Wang, Jingyuan; Yang, Z.; Cao, H.; Ren, D.

    2008-01-01

    Some townships in Xuan Wei County, Yunnan Province, have one of the highest lung cancer mortality rates in China and the epidemic disease in the area has generally been attributed to the polycyclic aromatic hydrocarbons (PAHs) released from domestic coal burning. However, the cancer-causing culprit is not settled as Tian [Tian, L., 2005. Coal Combustion Emissions and Lung Cancer in Xuan Wei, China. Ph.D. thesis, University of California, Berkeley.] found nanometer quartz in these coals, soot emissions, and lung cancer tissues. We have conducted mineralogical and geochemical studies of the coals from Xuan Wei for the purpose of shedding light on the minerals which may be related to the epidemic lung cancer. In this paper, abundances, modes of occurrence, and origins of minerals and elements in the coals from two mines in Xuan Wei have been studied using optical microscope, low-temperature ashing, X-ray diffraction analysis, scanning electron microscope equipped with energy-dispersive X-ray spectrometer, and inductively-coupled plasma mass spectrometry. The minerals in the coals are mainly composed of quartz, chamosite, kaolinite, and calcite. The particle size of quartz is rather small, mostly less than 20????m and it is of authigenic origin. Chamosite occurs mainly as cell-fillings. The occurrence of quartz and chamosite indicates that they were derived from the hydrothermal fluids. Epigenetic calcite is derived from calcic fluids. Kaolinite is derived mainly from sediment source region of Kangdian Oldland to the west of coal basin. The composition of Xuan Wei coal is high in SiO2, Fe2O3, TiO2, CaO, MnO, V, Co, Ni, Cu, and Zn. The high SiO2 content is attributed to quartz, and the Fe2O3 content to chamosite. The high Mn and low Mg contents in the coal indicate the inputs of hydrothermal fluids. CaO occurs mainly in epigenetic calcite. Elements Ti, Co, Ni, Cu, Zn, and rare earth elements were derived from the basaltic rocks at sediment source region. ?? 2008

  6. Relationship between high incidence of lung cancer among non-smoking women and silica in C1 bituminous coal in Xuanwei, Yunnan Province, China%云南省宣威地区非吸烟女性肺癌与C1烟煤中二氧化硅的关系

    李光剑; 黄云超; 田林玮; 刘拥军; 郭律; 肖义泽; 侯文俊; 杨堃; 陈颖

    2013-01-01

    二氧化硅颗粒物进入室内空气中随悬浮颗粒物吸入肺部”的迁移富集路线.%Objective To measure the content of silica in C1 bituminous coal and its combustion products in the high-incidence area of lung cancer in Xuanwei,Yunnan Province,China and to investigate the relationship between high incidence of lung cancer among non-smoking women and silica produced naturally in C1 bituminous coal in Xuan Wei.Methods The C1 bituminous coal widely used in the high-incidence area of lung cancer in Xuanwei was selected as experiment group,while the C2+1,K7,and M30 bituminous coal that was mined and used in the low-incidence area of lung cancer in Xuanwei for more than 10 years were selected as control group.Fourteen paraffin-embedded cancer tissue samples from the non-smoking women with non-small cell lung cancer who were born in Xuanwei and were at least the 3rd generation of the family living there were collected from the department of pathology,the ahird affiliated hospital of kunming medical university (tumor hospital of yunnan province).Titrimetric potassium silicofluoride method was used to measure the content of silica in raw coal and its bottom ashes in 20 samples from the experimental group and control group.Scanning electron microscopy (SEM) was used to observe the morphology of silica particles in C1 bituminous coal and its bottom ashes,and scanning electron microscopy coupled with energy dispersive X-ray analyzer (SEM-EDX) was used to analyze the microscopic composition.Transmission electron microscope (TEM) was used to observe the morphology of silica particles in the bottom ashes and coal soot of C1 bituminous coal as well as the lung cancer tissue from the non-smoking women in Xuanwei,and transmission electron microscope coupled with energy dispersive X-ray analyzer (TEM-EDX) was used to analyze the microscopic composition.The silica particles were separated from the coal soot and bottom ashes and characterized by physical method

  7. The Permian system in Kansas

    US Fish and Wildlife Service, Department of the Interior — Rocks of Permian age in Kansas were first recognized in 1895, and by the early 21st century the internationally accepted boundary between the Permian and the...

  8. COAL GEOLOGY

    2013-01-01

    <正>20132555 Bao Yuan(School of Resources and Geosciences,China University of Mining and Technology,Xuzhou 221008,China);Wei Chongtao Simulation of Geological Evolution History of the Upper Permian Coal Seam No.8in Shuigonghe Syncline,Zhina Coalfield,Guizhou Province(Coal Geology&Exploration,ISSN1001-1986,CN61-1155/P,40(6),2012,p.13-16,23,1illus.,1table,17refs.)

  9. Extinguishing a Permian World

    Schneebeli-Hermann, E.

    2012-01-01

    At the end of the Permian, ca. 252 Ma ago, marine and terrestrial fauna were facing the most extensive mass extinction in Earth history (Raup and Sepkoski, 1982). 80%–95% of all species on Earth, on land and in the oceans, became extinct (Benton et al., 2004) within an estimated time interval of les

  10. Coal

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  11. Middle-Late Permian mass extinction on land

    Retallack, G.J.; Metzger, C.A.; Greaver, T.; Jahren, A.H.; Smith, R.M.H.; Sheldon, N.D. [University of Oregon, Eugene, OR (United States). Dept. of Geological Science

    2006-11-15

    The end-Permian mass extinction has been envisaged as the nadir of biodiversity decline due to increasing volcanic gas emissions over some 9 million years. We propose a different tempo and mechanism of extinction because we recognize two separate but geologically abrupt mass extinctions on land, one terminating the Middle Permian (Guadalupian) at 260.4 Ma and a later one ending the Permian Period at 251 Ma. Our evidence comes from new paleobotanical, paleopedological, and carbon isotopic studies of Portal Mountain, Antarctica, and comparable studies in the Karoo Basin, South Africa. Extinctions have long been apparent among marine invertebrates at both the end of the Guadalupian and end of the Permian, which were also times of warm-wet greenhouse climatic transients, marked soil erosion, transition from high- to low-sinuosity and braided streams, soil stagnation in wetlands, and profound negative carbon isotope anomalies. Both mass extinctions may have resulted from catastrophic methane outbursts to the atmosphere from coal intruded by feeder dikes to flood basalts, such as the end-Guadalupian Emeishan Basalt and end-Permian Siberian Traps.

  12. Permian potentiometric analysis

    Devary, J.L.

    1983-09-01

    Pacific Northwest Laboratory (PNL) was requested to analyze potentiometric data from the Wolfcamp Formation of the Permian System to evaluate the recommendations by the University of Texas/Bureau of Economic Geology (UT/BEG) that additional geohydrologic boreholes be drilled into the Wolfcamp. The UT/BEG recommended that two stratigraphic and two geohydrologic borings be drilled into the Permian System during FY83 and that several shallow hydrologic tests be made in the Dockum Formation. A geostatistical technique known as kriging was applied to objectively evaluate these geohydrologic borehole recommendations. The Deaf Smith County location appears to be an excellent choice for a borehole. No high quality potentiometric data are available from Deaf Smith County and a borehole location immediately upgradient from the candidate repository site is needed. Adding this borehole location to the potentiometric data base will significantly reduce field data uncertainty near the location being studied. The Swisher County location does not appear to be the best choice. High quality data values H2206 and H2360 are located immediately upgradient from the proposed repository site. The best placement of additional geohydrological boreholes in the Wolfcamp Formation depends strongly upon the proposed repository location. The variability of the potentiometric data causes estimation errors to rapidly increase away from locations of field measurements. Suggested locations for additional boreholes for the Deaf Smith investigations are in northwest Randall or central Potter Counties. Ideal borehole locations for the Swisher county studies appear to be in southeast Randall and Armstrong Counties.

  13. Permian potentiometric analysis

    Pacific Northwest Laboratory (PNL) was requested to analyze potentiometric data from the Wolfcamp Formation of the Permian System to evaluate the recommendations by the University of Texas/Bureau of Economic Geology (UT/BEG) that additional geohydrologic boreholes be drilled into the Wolfcamp. The UT/BEG recommended that two stratigraphic and two geohydrologic borings be drilled into the Permian System during FY83 and that several shallow hydrologic tests be made in the Dockum Formation. A geostatistical technique known as kriging was applied to objectively evaluate these geohydrologic borehole recommendations. The Deaf Smith County location appears to be an excellent choice for a borehole. No high quality potentiometric data are available from Deaf Smith County and a borehole location immediately upgradient from the candidate repository site is needed. Adding this borehole location to the potentiometric data base will significantly reduce field data uncertainty near the location being studied. The Swisher County location does not appear to be the best choice. High quality data values H2206 and H2360 are located immediately upgradient from the proposed repository site. The best placement of additional geohydrological boreholes in the Wolfcamp Formation depends strongly upon the proposed repository location. The variability of the potentiometric data causes estimation errors to rapidly increase away from locations of field measurements. Suggested locations for additional boreholes for the Deaf Smith investigations are in northwest Randall or central Potter Counties. Ideal borehole locations for the Swisher county studies appear to be in southeast Randall and Armstrong Counties

  14. Palinspastic reconstruction and geological evolution of Permian residual marine basins bordering China and Mongolia

    Gen-Yao Wu

    2014-01-01

    One main feature of the tectono-paleogeographic evolution of the southern branch of the Paleo-Asian Ocean was that there developed residual marine basins in former backarc/forearc regions after the disappearance of oceanic crust. The paper illustrates the viewpoint taking the evolution of Dalandzadgad and Solonker oceanic basins as examples. The Dalandzadgad ocean subducted southwards during the Silurian-Devonian, created an intra-oceanic arc and a backarc basin in southern Mongolia. In addition, a continent marginal arc formed along the national boundary between China and Mongolia, the south of which was a backarc basin. The oceanic basin closed and arc-arc (continent) collision occurred dur-ing the early Early Permian, followed by two residual marine basins developing in the former backarc regions, named the South Gobi Basin in southern Mongolia and the Guaizihu Basin in western Inner Mongolia. The Solonker ocean subducted southwards and ifnally disappeared during the early Middle Permian. Afterwards, two residual marine basins occurred in northern China, the Zhesi Basin being situated in the former backarc region and the Wujiatun Basin in the former forearc region. The late Middle Permian was the most optimum period for the de-veloping residual marine basins, when they covered a vast area. The basin evolution differenti-ated during the early Late Permian, with a general trend of uplift in the east and of subsidence in the west. The Upper Permian in the South Gobi Basin was characterized by coal-bearing strata hosting economically valuable coal ifelds. A transgression invaded westwards and the Chandmani-Bayanleg Basin was created in southwest Mongolia during the middle-late stage of the Late Permian. Correspondingly, the coal formation entered a lfourishing time, with thick coal beds and sedimentary interbeds. All of these basins, namely, both the marine and non-marine residual basins, reversed and closed by the end of Permian.

  15. Palinspastic reconstruction and geological evolution of Permian residual marine basins bordering China and Mongolia

    Gen-Yao; Wu

    2014-01-01

    One main feature of the tectono-paleogeographic evolution of the southern branch of the Paleo-Asian Ocean was that there developed residual marine basins in former backarc/forearc regions after the disappearance of oceanic crust.The paper illustrates the viewpoint taking the evolution of Dalandzadgad and Solonker oceanic basins as examples.The Dalandzadgad ocean subducted southwards during the Silurian-Devonian,created an intra-oceanic arc and a backarc basin in southern Mongolia.In addition,a continent marginal arc formed along the national boundary between China and Mongolia,the south of which was a backarc basin.The oceanic basin closed and arc-arc(continent) collision occurred during the early Early Permian,followed by two residual marine basins developing in the former backarc regions,named the South Gobi Basin in southern Mongolia and the Guaizihu Basin in western Inner Mongolia.The Solonker ocean subducted southwards and finally disappeared during the early Middle Permian.Afterwards,two residual marine basins occurred in northern China,the Zhesi Basin being situated in the former backarc region and the Wujiatun Basin in the former forearc region.The late Middle Permian was the most optimum period for the developing residual marine basins,when they covered a vast area.The basin evolution differentiated during the early Late Permian,with a general trend of uplift in the east and of subsidence in the west.The Upper Permian in the South Gobi Basin was characterized by coal-bearing strata hosting economically valuable coal fields.A transgression invaded westwards and the Chandmani-Bayanleg Basin was created in southwest Mongolia during the middle-late stage of the Late Permian.Correspondingly,the coal formation entered a flourishing time,with thick coal beds and sedimentary interbeds.All of these basins,namely,both the marine and nonmarine residual basins,reversed and closed by the end of Permian.

  16. Palaeomagnetic data for Permian and Triassic rocks from drill holes in the Southern Sydney Basin, New South Wales

    Facer, R. A.

    1981-04-01

    A section 300 m thick across the Permian—Triassic boundary has been sampled in the Southern Coalfield of the Sydney Basin, New South Wales. 55 samples, mainly grey to drab sandstones, were collected from 9 diamond drill holes which penetrated the entire Narrabeen Group and the upper part of the conformably underlying Illawarra Coal Measures, as well as a sill emplaced into the coal measures. The samples included fully oriented cores. Additional reconnaissance samples from two further drill holes were also studied. Partial alternating field demagnetization and petrography indicate the magnetic remanence to be a stable DRM. Partial thermal demagnetization above 300°C or 400°C caused large increases in magnetic susceptibility. Partial chemical demagnetization did not cause significant changes in remanence directions. For the Coal Cliff Sandstone (basal Narrabeen Group, Triassic) the palaeomagnetic pole position (Normal) was calculated to be at 59°N 322°E (dp = 27°, dm = 29°), which agrees with previously published data. For the uppermost coal measures (Permian) the pole position was calculated as 58°N 340°E (dp = 09°, dm = 10°). Data for samples from the lower to middle coal measures yield a pole position which is between the new Permian—Triassic pole position and that for the underlying Middle Permian igneous rocks. The top of the Reversed "Kiaman Magnetic Interval" (Permian) may be near the Tongarra coal and Appin Formation boundary — (early) Late Permian.

  17. Coal potential of Antartica

    Rose, G.; McElroy, C.T.

    1987-01-01

    This report attempts to bring together available information on the coal deposits of Antarctica and discuss factors that would be involved if these deposits were to be explored and mined. Most of the reported principal coal deposits in Antarctica lie generally within the Transantarctic Mountains: the majority are of Permian age and are present in the Victoria Group of the Beacon Supergroup. Several other deposits have been recorded in East Antarctica and in the Antarctic Peninsula, including minor occurrences of Mesozoic and Tertiary coal and carbonaceous shale.

  18. Permian reptilian fauna from the Kundaram Formation, Pranhita-Godavari Valley, India

    Ray, Sanghamitra

    1999-07-01

    The Kundaram Formation of the Pranhita-Godavari Valley yields the only Permian reptilian fauna in India. It is composed essentially of a dicynodont assemblage and includes Endothiodon, Cistecephalus, Pristerodon, Oudenodon and Emydops-like forms. The only non-dicynodont member is a captorhinid reptile. These taxa allow the correlation of the Kundaram Formation with the Tropidostoma and/or Cistecephalus Assemblage Zones of the Beaufort Group of South Africa, the basal beds of Madumabisa Mudstones of Zambia, the Ruhuhu and lower part of the Kawinga Formation of Tanzania and the Morro Pelado member of the Rio do Rasto Formation of Brazil, indicating a Late Permian (Tatarian) age. The Kundaram fauna helps in fixing the upper age of the coal-bearing Damuda Group more precisely at Tatarian. The distribution of the Late Permian dicynodonts in the now widely separated geographic areas suggests the close proximity of the continents and a lack of endemism or provinciality.

  19. Arsenic concentrations in Chinese coals

    The arsenic concentrations in 297 coal samples were collected from the main coal-mines of 26 provinces in China were determined by molybdenum blue coloration method. These samples were collected from coals that vary widely in coal rank and coal-forming periods from the five main coal-bearing regions in China. Arsenic content in Chinese coals range between 0.24 to 71 mg/kg. The mean of the concentration of Arsenic is 6.4 ± 0.5 mg/kg and the geometric mean is 4.0 ± 8.5 mg/kg. The level of arsenic in China is higher in northeastern and southern provinces, but lower in northwestern provinces. The relationship between arsenic content and coal-forming period, coal rank is studied. It was observed that the arsenic contents decreases with coal rank in the order: Tertiary > Early Jurassic > Late Triassic > Late Jurassic > Middle Jurassic > Late Permian > Early Carboniferous > Middle Carboniferous > Late Carboniferous > Early Permian; It was also noted that the arsenic contents decrease in the order: Subbituminous > Anthracite > Bituminous. However, compared with the geological characteristics of coal forming region, coal rank and coal-forming period have little effect on the concentration of arsenic in Chinese coal. The average arsenic concentration of Chinese coal is lower than that of the whole world. The health problems in China derived from in coal (arsenism) are due largely to poor local life-style practices in cooking and home heating with coal rather than to high arsenic contents in the coal

  20. Petrographic compositions of Paleozoic coals of Mongolia

    Jargal, Luvsanchultem; Erdenetsogt, Bat-Orshikh

    2016-04-01

    In Mongolia, the deposition of coal bearing strata commenced in Pennsylvanian, and continued in Upper Permian, in Lower-Middle Jurassic and finally in Lower Cretaceous time. Pennsylvanian coal seams were deposited in Western Mongolia, where peat formation was initially developed in the southernmost part and later gradually shifted to northward. By the Late Permian, the locus of coal formation had changed and main peat accumulation took place in southern Mongolia. Lower-Middle Jurassic coal was accumulated in western, northern and eastern Mongolia. During this time, peat forming condition was comparatively stable in entire Mongolia. In the Early Cretaceous, thick and extensive coal was formed in the Eastern Mongolia. Due to this general trend of peat accumulation, coal rank decreases from west (bituminous) to east (lignite). The significant portion of Pennsylvanian and Upper Permian coal reserves, existed in western and southern Mongolia, are coking coal. Thus, petrographical studies of the coals are notably important. However, previous studies of Paleozoic coals have been sparse, and only few deposits have been conducted. The maceral compositions of Western Mongolian Pennsylvanian coals such as Khushuut, Maanit, Khurengol, Zeegt, Tsagaangol, Nuurstkhotgor, Khartarvagatai and Olonbulag were studied. The results show that the coals are dominated by vitrinite (45 vol.% to 71 vol.%) and inertinite (28 vol.% to 53vol.%) macerals. Liptinite contents are low, less than 4 vol.%. In addition, vitrinite reflectance values (Rmax in oil) of Khushuut (1.85%), Maanit (0.92%), Khurengol (1.4%), Zeegt (0.86%), Tsagaangol (3.6%), Nuurstkhotgor (0.9%), Khartarvagatai (1.1%) and Olonbulag (1.7%) were determined. Upper Permian coals in southern Mongolia (Tavantolgoi, Nariinsukhait, Jargalant, Tsagaantolgoi, Buduuniikhyar) are dominated by vitrinite (55 vol.% to 78 vol.%) and inertinite macerals (19 vol.% to 44 vol.%). Liptinite contents range from 1 vol.% to 7 vol.%. The vitrinite

  1. Strontium isotope evolution of Late Permian and Triassic seawater

    Korte, Christoph; Kozur, Heinz W.; Bruckschen, Peter; Veizer, Ján

    2003-01-01

    The 87Sr/ 86Sr values based on brachiopods and conodonts define a nearly continuous record for the Late Permian and Triassic intervals. Minor gaps in measurements exist only for the uppermost Brahmanian, lower part of the Upper Olenekian, and Middle Norian, and only sparse data are available for the Late Permian. These 219 measurements include 67 brachiopods and 114 conodont samples from the Tethyan realm as well as 37 brachiopods and one conodont sample from the mid-European Middle Triassic Muschelkalk Sea. The Late Permian/Lower Triassic interval is characterized by a steep 1.3 × 10 -3 rise, from 0.7070 at the base of the Dzhulfian to 0.7082 in the late Olenekian, a rate of change comparable to that in the Cenozoic. In the mid-Triassic (Anisian and Ladinian), the isotope values fall to 0.7075, followed again by a rise to 0.7081 in the Middle/Late Norian. The 87Sr/ 86Sr values decline again in the Late Norian (Sevatian) and Rhaetian to 0.7076. The sharp rise in the 87Sr/ 86Sr values during the Late Permian/Early Triassic was coincident with widespread clastic sedimentation. Because of the paucity of tectonic uplifts, the enhanced erosion may have been due to intermittent humid phases, during mainly an arid interval, coupled with the absence of a dense protective land plant cover following the mass extinction during the latest Permian. The apex of the 87Sr/ 86Sr curve at the Olenekian/Anisian boundary coincides with cessation of the large-scale clastic sedimentation and also marks the final recovery of land vegetation, as indicated by the renewed onset of coal formation in the Middle Triassic. The rising 87Sr/ 86Sr values from the Middle Carnian to the Late Norian coincide with the uplift and erosion of the Cimmeride-Indosinian orogens marking the closure of the Palaeotethys. The subsequent Rhaetian decline that continues into Jurassic (Pliensbachian/Toarcian boundary), on the other hand, coincides with the opening of the Vardar Ocean and its eastern continuation

  2. Cooperative Research in C1 Chemistry

    Gerald P. Huffman

    2000-10-27

    C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F

  3. Late Permian to Early Triassic magnetostratigraphy

    Haag, Maja; Heller, Friedrich

    1991-10-01

    A Late Permian to Early Triassic magnetostratigraphic reference section is presented. The Lower Triassic part is based on results from marine limestone sections in South China published earlier [1,2]. Reliable new Permian data are added here which have been collected in the Nammal gorge (Salt Range, Northwest Pakistan) where marine sediments have been deposited quasi-continuously with occasional minor hiatuses during the late Palaeozoic to early Mesozoic. About 50% of the Permian samples from the Nammal section contain, hidden beneath a strong recent or Tertiary overprint, a characteristic remanent magnetization (ChRM) which is very likely of Permian age. This component, which was imprinted on the southern hemisphere, has normal as well as reversed polarity with a normal mean direction (Decl. = 289.3°, Incl. = -50.3°, α 95 = 4.3° , N = 113) which is in close agreement with the palaeofield direction expected for a site belonging to the Indian plate as part of Gondwanaland during the Permian. In the lower Upper Permian several normal polarity zones are recognized. This contradicts the current assumption that rocks of this age belong to the long, reversely polarized Kiaman hyperzone. The Kiaman interval must end and the Illawarra hyperzone of mixed polarity must begin in or prior to the lowermost Upper Permian. The Permian/Triassic boundary at Nammal as well as in the Chinese sections is situated very close to a transition from a reversed to a normal polarity zone. The Upper Permian at Nammal together with the Lower Triassic South China sections is estimated to cover about 20 Ma. Nearly 30 polarity changes are observed which result in an average reversal frequency very similar to that observed during the early Tertiary. The reversal rate after the end of the long-lasting reversed Kiaman hyperchron apparently increases in a manner similar to that after the end of the Cretaceous Long Normal Superchron. Only a few polarity zones are found in the lower Upper Permian

  4. Coking coals of Mongolia: Distribution and resources

    Erdenetsogt, Bat-Orshikh; Jargal, Luvsanchultem

    2016-04-01

    The coal deposits of Mongolia tend to become younger from west to east and can be subdivided into two provinces, twelve basins, and three areas. Main controlling factor of coal rank is the age of coal bearing sequences. Western Mongolian coal-bearing province contains mostly high rank bituminous coal in strata from Late Carboniferous. The basins in southern Mongolia and the western part of central Mongolia have low rank bituminous coal in strata from the Permian. The northern and central Mongolian basins contain mainly Jurassic subbituminous coal, whereas the Eastern Mongolian province has Lower Cretaceous lignite. Mongolian known coking coal reserves are located in western, southern and northern Mongolia and related to Carboniferous, Permian and Jurassic sequences, respectively. Pennsylvanian Nuurstkhotgor coal deposit is located in northwestern Mongolia (in Western Mongolian coal-bearing province). The coals have 1-7.5 crucible swelling number (CSN) and 0-86 G-index. Vitrinite reflectance value (Rmax in oil) varies from 0.7% to 1.2% and sulfur content is low, ranging from 0.3% to 0.6% with an average of 0.4%. Coal reserve is estimated to be 1.0 billion ton, of which half is coking coal. Upper Permian Khurengol deposit is situated in western Mongolia (in Western Mongolian coal-bearing province). CSN and G-index of coal are 8-9 and 54-99, respectively. The coals have Rmax of 1.1 to 1.7% (average 1.4%) and sulfur content of 0.2 to 0.6% (average 0.4%). Coking coal reserve of the deposit is estimated to be 340 million ton. Upper Permian Tavantolgoi, the largest coking coal deposit, lies in southern Mongolia (in South Gobi coal-bearing basin). The coals have CSN of 1 to 7.5 and Rmax of 0.7% to 1.2%. Sulfur content is low, ranging from 0.5% to 0.9%. Coal reserve is estimated to be 6.0 billion ton, of which 2.0 billion ton is accounted as coking coal. Lower-Middle Jurassic Ovoot coal is located in northern Mongolia (in Orkhon-Selenge coal-bearing area). This is one of

  5. The Saint Martin de Belleville syncline and its uraniferous permian sandstone

    This dissertation (these de specialite) is a study of the geology of the St.Martin d.B. syncline and the uranium prospect 'le Cochet' in the Carboniferous Brianconnais Zone of Savoy. Stratigraphy and sedimentology: This syncline presents continental detrital sediments ranging from U.Carboniferous to L.Triassic. In the U.Carboniferous, magmatic activity begins with the Moriaz Layers acid volcanics that are considered as a lateral equivalent of the Stephanian Courchevel Conglomerates. In Permian times, parts of an alluvial fan seem to occupy the north of the study area (gray and green conglomeratic sandstone). Southwards these inter-finger with flood plain sediments (red slate) including a locally oolitic limestone. Volcanic detritus is important in the Permian. Tourmalinite pebbles are frequent and seem to be related to the regional Permian magmatism. Albitization of feldspars is general in the Carboniferous and the Permian. The Permo-triassic typically shows microcline bearing dolomitic sandstones. In the Scythian quartzites orthoclase is the dominant feldspar. The quartzites are overlain by L.Triassic evaporites identified by the sulfur isotope ratio of their gypsum. The morphology of the zircons in the sandstones has been investigated using the typological method of J.P. Pupin. Regional Permian magmatism apparently produces volcanics of the calc-alkalic and tholeiitic series as well as a high level granitic intrusion of anatectic origin. The uranium occurrences are strata-bound on a kilometric and hecto-metric scale. They are developed almost exclusively in the gray variety of the Permian sandstones whose gray and red varieties are always barren. Within this unit, the mineralization impregnates irregularly distributed lenses and pods of coal material. Uranium is accompanied by vanadium occurring as roscoelite. The association U-V, of bio-philic character, reflects the concentration in the sedimentary environment and argues for a quite indirect relation with the

  6. Mechanism on bipolar distribution of Permian brachiopods

    Chengwen WANG; Songmei ZHANG

    2008-01-01

    By reasearch on geographic distribution, nine genera in bipolar distribution are selected from Permian brachiopods. These taxa originated from middle-high latitude areas in the boreal realm, of which five genera were derived from Late Carboniferous, and other four genera originated from Permian. They were all in bipolar distribution during some different stages in Permian. Specific diversity for each genus was high in the boreal realm, whereas in the Gondwana realm was very low. Perdurability was long in the boreal realm, and short in the Gondwana realm. It was the time when these nine genera came to their maximum diversity that these genera appeared in the Gondwana and formed bipolar distribution; while they also migrated to the low latitude from high latitude. This shows very close relationship between several main cooling events in Permian and the migration of genera from the boreal realm to the Gondwana realm through the Tethys. Therefore, the cooling events might be the main drive which caused these cold-water-type brachiopods migrated to the Gondwana realm and being bipolar distribution. In this process, the planula tolerance to warm water would be another important factor.

  7. Distribution Characteristics of Sulfur and the Main Harmful Trace Elements in China's Coal

    TANG Shuheng; SUN Shenglin; QIN Yong; JIANG Yaofa; WANG Wenfeng

    2008-01-01

    To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for content, and analyzed. Coal in northwestern China is characterized by low to extremely low levels of sulfur; the coal of the Taiyuan Formation in northern China mainly has high-sulfur content; that of the Shanxi Formation is mainly characterized by low sulfur coal; and the Late Permian coal in southern China has overall higher sulfur content; other regions have low sulfur coal. The average content of harmful trace elements in the bulk of China's coal is similar to the corresponding content in the coal of the North America and the rest of the world, whereas the content of various elements (Hg, Sb and Se) is different in magnitude to the corresponding percentage in the crust. The average content of the elements Cr, Se, Co, Be, U, Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and Ci in the coals of Late Carboniferous to Early Permian age in N China are the highest. The average content of Mn in Early and Middle Jurassic coal is higher in NW China. The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.

  8. The terminal Permian in European Russia: Vyaznikovian Horizon, Nedubrovo Member, and Permian-Triassic boundary

    Lozovsky, V. R.; Balabanov, Yu. P.; Karasev, E. V.; Novikov, I. V.; Ponomarenko, A. G.; Yaroshenko, O. P.

    2016-07-01

    The comprehensive analysis of the data obtained on terrestrial vertebrata, ostracods, entomologic fauna, megaflora, and microflora in deposits of the Vyaznikovian Horizon and Nedubrovo Member, as well as the paleomagnetic data measured in enclosing rocks, confirms heterogeneity of these deposits. Accordingly, it is necessary to distinguish these two stratons in the terminal Permian of the East European Platform. The combined sequence of Triassic-Permian boundary deposits in the Moscow Syneclise, which is considered to be the most complete sequence in the East European Platform, is as follows (from bottom upward): Vyatkian deposits; Vyaznikovian Horizon, including Sokovka and Zhukovo members; Nedubrovo Member (Upper Permian); Astashikha and Ryabi members of the Vokhmian Horizon (Lower Triassic). None of the sequences of Permian-Triassic boundary deposits known in the area of study characterizes this sequence in full volume. In the north, the Triassic deposits are underlain by the Nedubrovo Member; in the south (the Klyazma River basin), the sections are underlain by the Vyaznikovian Horizon. The Permian-Triassic boundary adopted in the General Stratigraphic Scale of Russia for continental deposits of the East European platform (the lower boundary of the Astashikha Member) is more ancient than the one adopted in the International Stratigraphic Chart. The same geological situation is observed in the German Basin and other localities where Triassic continental deposits are developed. The ways of solving this problem are discussed in this article.

  9. Exploratory shaft facility preliminary designs - Permian Basin

    The purpose of the Preliminary Design Report, Permian Basin, is to provide a description of the preliminary design for an Exploratory Shaft Facility in the Permian Basin, Texas. This issue of the report describes the preliminary design for constructing the exploratory shaft using the Large Hole Drilling method of construction and outlines the preliminary design and estimates of probable construction cost. The Preliminary Design Report is prepared to complement and summarize other documents that comprise the design at the preliminary stage of completion, December 1982. Other design documents include drawings, cost estimates and schedules. The preliminary design drawing package, which includes the construction schedule drawing, depicts the descriptions in this report. For reference, a list of the drawing titles and corresponding numbers are included in the Appendix. The report is divided into three principal sections: Design Basis, Facility Description, and Construction Cost Estimate. 30 references, 13 tables

  10. Lithostratigraphy and depositional environments of the Pyeongan Supergroup (Carboniferous Permian) in the Taebaek area, mid-east Korea

    Lee, H. S.; Chough, S. K.

    2006-03-01

    The Pyeongan Supergroup (Carboniferous-Permian) consists of a thick siliciclastic sequence (1700 m thick). Recent sedimentological work in the Taebaek area has refined the lithostratigraphic units: Manhang, Geumcheon-Jangseong, Hambaeksan, Dosagok, Gohan and Donggo formations in ascending order. The entire sequence is represented by thirteen sedimentary facies, which can be organized into seven facies associations (FA). The lower part of the Manhang Formation (FA 1) (Moscovian) consists of crudely cross-stratified conglomerate, massive sandstone and gray homogeneous siltstone, formed in shoreface off river mouth, whereas purple siltstone and grainstone of the upper part (FA 2) probably formed in a coastal plain environment. The Geumcheon-Jangseong Formation (Moscovian-Artinskian) consists of dark gray sandstone, dark gray shale, coal and bioturbated wackestone (FA 3) formed in a lagoonal environment. The Hambaeksan Formation (Kungurian) comprises milky white, crudely stratified, conglomerate, gray coarse sandstone and partly laminated black shale (FA 4), representing a shoreface progradation. The Dosagok Formation (Late Permian) is characterized by an alternation of purple fine sandstone and conglomerate (FA 5), formed in a bedload-dominated fluvial system. The Gohan Formation (Late Permian) is mostly composed of upward-fining units (massive sandstone to dark gray siltstone) (FA 6), suggesting a restricted inter-distributary bay environment. The Donggo Formation (?Late Permian) consists of cross-stratified coarse sandstone and purple sandstone (FA 7), interpreted as deposits of perennial, sandy braided river system.

  11. Palynology of the Permian succession of Spitsbergen, Svalbard

    Mangerud, G.; Konieczny, R. M.

    1993-01-01

    Palynological investigations of 16 sections from Spitsbergen, Svalbard, covering the uppermost Carboniferous, Permian and lowermost Triassic succession have been carried out. Because of general poor preservation and barrenness of the majority of the samples, it was not possible to establish a formal zonation for the Permian succession. The study resulted, however, in the recognition of three Permian palynological assemblages, restricted downwards by a Carboniferous assemblage and upwards by a...

  12. On the origin of the Southern Permian Basin, Central Europe

    J.-D. van Wees; Stephenson, R.A.; Ziegler, P. A.; Ulf Bayer; McCann, T; R. Dadlez; Gaupp, R; M. Narkiewicz; F. Bitzer; Scheck, M.;  

    2000-01-01

    A detailed study of the structural and stratigraphic evolution of the Southern Permian Basin during latest Carboniferous to Early Jurassic times, supported by quantitative subsidence analyses and forward basin modelling for 25 wells, leads us to modify the conventional model for the Rotliegend-Zechstein development of this basin. The Late Permian-Early Jurassic tectonic subsidence curves are typical for a Permian to Early Triassic extensional stage that is followed by thermal subsidence. Howe...

  13. Permian polar forests: deciduousness and environmental variation.

    Gulbranson, E L; Isbell, J L; Taylor, E L; Ryberg, P E; Taylor, T N; Flaig, P P

    2012-11-01

    Forests are expected to expand into northern polar latitudes in the next century. However, the impact of forests at high latitudes on climate and terrestrial biogeochemical cycling is poorly understood because such forests cannot be studied in the modern. This study presents forestry and geochemical analyses of three in situ fossil forests from Late Permian strata of Antarctica, which grew at polar latitudes. Stem size measurements and stump spacing measurements indicate significant differences in forest density and canopy structure that are related to the local depositional setting. For forests closest to fluvial systems, tree density appears to decrease as the forests mature, which is the opposite trend of self-thinning observed in modern forests. We speculate that a combination of tree mortality and high disturbance created low-density mature forests without understory vegetation near Late Permian river systems. Stable carbon isotopes measured from permineralized wood in these forests demonstrate two important points: (i) recently developed techniques of high-resolution carbon isotope studies of wood and mummified wood can be applied to permineralized wood, for which much of the original organic matter has been lost and (ii) that the fossil trees maintained a deciduous habit at polar latitudes during the Late Permian. The combination of paleobotanical, sedimentologic, and paleoforestry techniques provides an unrivaled examination of the function of polar forests in deep time; and the carbon isotope geochemistry supplements this work with subannual records of carbon fixation that allows for the quantitative analysis of deciduous versus evergreen habits and environmental parameters, for example, relative humidity. PMID:22845834

  14. The carbon and sulfur cycles and atmospheric oxygen from middle Permian to middle Triassic

    Berner, Robert A.

    2005-07-01

    The results of a theoretical isotope mass balance model are presented for the time dependence of burial and weathering-plus-degassing fluxes within the combined long-term carbon and sulfur cycles. Averaged data for oceanic δ 13C and δ 34S were entered for every million years from 270 to 240 Ma (middle Permian to middle Triassic) to study general trends across the Permian-Triassic boundary. Results show a drop in the rate of global organic matter burial during the late Permian and a predominance of low values during the early-to-middle Triassic. This overall decrease with time is ascribed mainly to epochs of conversion of high biomass forests to low biomass herbaceous vegetation resulting in a decrease in the production of terrestrially derived organic debris. Additional contributions to lessened terrestrial carbon burial were increased aridity and a drop in sea level during the late Permian which led to smaller areas of low-lying coastal wetlands suitable for coal and peat deposition. Mirroring the drop in organic matter deposition was an increase in the burial of sedimentary pyrite, and a dramatic increase in the calculated global mean ratio of pyrite-S to organic-C. High S/C values resulted from an increase of deposition in marine euxinic basins combined with a decrease in the burial of low-pyrite associated terrestrial organic matter. The prediction of increased oceanic anoxia during the late Permian and early Triassic agrees with independent studies of the composition of sedimentary rocks. Weathering plus burial fluxes for organic carbon and pyrite sulfur were used to calculate changes in atmospheric oxygen. The striking result is a continuous drop in O 2 concentration from ˜30% to ˜13% over a twenty million year period. This drop was brought about mainly by a decrease in the burial of terrestrially derived organic matter. but with a possible contribution from the weathering of older organic matter on land. It must have exerted a considerable influence on

  15. Depositional cyclicity and paleoecological variability in an outcrop of Rio Bonito Formation, Early Permian, Parana Basin, Rio Grande do Sul, Brazil

    Jasper, A.; Menegat, R.; Guerra-Sommer, M.; Cazzulo-Klepzig, M.; de Souza, P.A. [UNIVATES, Lajeado (Brazil)

    2006-07-15

    This article integrates faciological, paleobotanical, and palynological analyses to establish the relationship between depositional cyclicity and paleoecological patterns for the (Early Permian) Quiteria outcrop, Rio Bonito Formation, southern Parana Basin, Rio Grande do Sul state. The record in some coal palynofloras of Striadopodocarpites fusus, a component of the Hamiapollenites karrooensis subzone, as defined in the palynostratigraphic framework for the Parana Basin, indicates a Kungurian age for the palynoflora.

  16. Permian magmatism, Permian detachment faulting, and Alpine thrusting in the Orobic Anticline, southern Alps, Italy

    Pohl, Florian; Froitzheim, Niko; Geisler-Wierwille, Thorsten; Schlöder, Oliver

    2014-05-01

    The Grassi Detachment Fault is located in the Orobic Alps east of Lake Como and was described by Froitzheim et al. (2008) as an Early Permian extensional structure. Many issues still remained unclear, like the exact timing of faulting and the extension from the well-exposed part of the detachment towards west. The Grassi Detachment Fault separates the Variscan Basement in its footwall from the volcanic and sedimentary rocks of the Early Permian Collio Formation within its hanging wall, marked by a mylonitic and cataclastic layer whose textures indicate top-to-the-southeast displacement. The footwall basement is formed by the Variscan Morbegno Gneiss and two granitic intrusions, the Val Biandino Quarz Diorite (VBQD) and the Valle Biagio Granite (VBG). The former is syntectonic with respect to the detachment, whereas for the latter, the relation to the detachment is unknown. The age of the VBQD is poorly defined as 312 Ma ± 48 Ma (Thöni et al. 1992); the VBG has not been dated. Volcanic rocks of the Collio Formation in the hanging wall may represent the extrusive part of the magmatic system. In our study area west of Val Biandino, several faults and shear zones are exposed: (1) The Grassi Detachment Fault is represented by mylonites and cataclasites with top-SE shear sense, between basement rocks and the Collio Volcanics. Towards NW, it is truncated by the unconformably overlying Late Permian Verrucano Lombardo. This may reflect the eroded culmination of a Permian metamorphic core complex. (2) A steeply NW-dipping, brittle normal fault is found further west in the footwall between VBQD and VBG. It is sealed by the basal unconformity of the Verrucano Lombardo and therefore should also be of Early Permian age (Sciunnach, 2001). It may represent an antithetic fault with respect to the detachment, accommodating the uplift of the magmatically inflated core complex. (3) The Biandino Fault is a steeply SE-dipping reverse fault, affecting also the Late Permian Verrucano

  17. Phreatomagmatic Pipes of the Tunguska basin (Siberia): Improvement of End-Permian Mass Extinction Model

    Polozov, Alexander; Svensen, Henrik; Planke, Sverre; Jerram, Dougal

    2014-05-01

    Formation of the Siberian Traps Large Igneous Province is regarded as key phenomena responsible for the end-Permian mass extinction. Extinct event was accelerating due to release of enormous amount of gases throughout numerous basalt pipes, originated from contact aureoles of dolerite sills intruded into Tunguska Basin. Tunguska sedimentary basin consists of Precambrian and Paleozoic evaporites, carbonates and terrigenous rocks including Late Paleozoic coal-bearing strata. Precambrian and early Paleozoic oil source rocks contain numerous high potential oil and gas fields. Paleozoic evaporites contain rock and potassium salts deposits of commercial grade. Tunguska Basin evaporites are considered as a regional seal for the mineralizing brines. Permian-Triassic volcaniclastic rocks overlie this sequence and intrusive rocks have the numerous evidences of magma-sediment interaction result in basalt pipes formation. Compilation of available Russian literature gives us a chance to make a conclusion that hundreds of basalt pipes occur in the Tunguska Basin. The basalt pipes cross over all known dolerite intrusions and are filled with breccias of magmatic, volcaniclastic and sedimentary rocks altered to varying extents. Pipes from the Tunguska Basin south have a phreatomagmatic origin that is supported by ubiquitous occurrence of altered sedimentary clasts and volcaniclastic lapilli, corroded by brine during initial stages of magma-evaporite (brine) interaction. Corroded lapilli rimmed by diopside, chlorine-bearing hornblende, apatite and magnetite. Our recent study of magnetite-rich coarse lapilli tuffs revealed the garnet lapilli rimmed with magnetite cemented by altered clay groundmass enriched by native metals (Cu, Sn, Zn). This result corroborates our hypothesis about magnetite formation during initial stage of magma-sediment-brine interaction. We suggest that these observations could shed light on end-Permian aerosol flux originated from basalt pipes and could provide

  18. Coal geopolitics

    This book divided into seven chapters, describes coal economic cycle. Chapter one: coals definition; the principle characteristics and properties (origin, calorific power, international classification...) Chapter two: the international coal cycle: coal mining, exploration, coal reserves estimation, coal handling coal industry and environmental impacts. Chapter three: the world coal reserves. Chapter four: the consumptions, productions and trade. Chapter five: the international coal market (exporting mining companies; importing companies; distributors and spot market operators) chapter six: the international coal trade chapter seven: the coal price formation. 234 refs.; 94 figs. and tabs

  19. Carboniferous-Permian rugose coral Cyathaxonia faunas in China

    2010-01-01

    The Cyathaxonia faunas are widely distributed in the Carboniferous and Permian strata in China.The fauna in China contains 12 families and 40 genera,and can be recognized as three episodes from Early Carboniferous to the end-Permian in terms of their occurrence and composition:1) Mississippian;2) Pennsylvanian-Early Permian;3) Middle Permian-Late Permian.They were relatively abundant in episodes 1 and 2.A decrease of family Antiphyllidae and an increase of family Hapsiphyllidae can be observed from Early Carboniferous to the end-Permian.Two case studies are given to illustrate the bio-facies of the Cyathaxonia faunas,which are from the Mississippian of Baoshan,West Yunnan and the Mississippian of Chaohu,South Anhui.In both areas,Cyathaxonia faunas occur just below the large dissepimented solitary and compound coral assemblages in a continuous sequence in a single section,which implies that the occurrence of these small,non-dissepimented solitary corals is not strictly related with Gondwanan or Peri-gondwanan cold water environment,but might be controlled by such benthic conditions as deeper,mud-rich,quieter,and darker sedimentary environments.

  20. Effects of Igneous Intrusion on Microporosity and Gas Adsorption Capacity of Coals in the Haizi Mine, China

    Jingyu Jiang; Yuanping Cheng

    2014-01-01

    This paper describes the effects of igneous intrusions on pore structure and adsorption capacity of the Permian coals in the Huaibei Coalfield, China. Twelve coal samples were obtained at different distances from a ~120 m extremely thick sill. Comparisons were made between unaltered and heat-affected coals using geochemical data, pore-fracture characteristics, and adsorption properties. Thermal alteration occurs down to ~1.3 × sill thickness. Approaching the sill, the vitrinite reflectance (R...

  1. C1q and systemic lupus erythematosus.

    Walport, M J; Davies, K A; Botto, M

    1998-08-01

    In this chapter we review the association between SLE and C1q. In the first part of the chapter we discuss the clinical associations of C1q deficiency, and tabulate the available information in the literature relating to C1q deficiency and autoimmune disease. Other clinical associations of C1q deficiency are then considered, and we mention briefly the association between other genetically determined complement deficiencies and lupus. In the review we explore the relationship between C1q consumption and lupus and we discuss the occurrence of low molecular weight (7S) C1q in lupus, which raises the possibility that increased C1q turnover in the disease may result in unbalanced chain synthesis of the molecule. Anti-C1q antibodies are also strongly associated with severe SLE affecting the kidney, and with hypocomplementaemic urticarial vasculitis, and these associations are also examined. We address the question of how C1q deficiency may cause SLE, discussing the possibility that this may be due to abnormalities of immune complex processing, which have been well characterised in a umber of different human models. There is clear evidence that immune complex processing is abnormal in patients with hypocomplementaemia, and this is compatible with the hypothesis that ineffective immune complex clearance could cause tissue injury, and this may in turn stimulate an autoantibody response. We have also considered the possibility that C1q-C1q receptor interactions are critical in the regulation of apoptosis, and we explore the hypothesis that dysregulation of apoptosis could explain important features in the development of autoimmune disease associated with C1q deficiency. An abnormally high rate of apoptosis, or defective clearance of apoptotic cells, could promote the accumulation of abnormal cellular products that might drive an autoimmune response. Anti-C1q antibodies have been described in a number of murine models of lupus, and these are also briefly discussed. We focus

  2. Microbial growth on C1 compounds: proceedings

    This book contains individual papers prepared for the 4th International Symposium on Microbial Growth on One Carbon Compounds. Individual reports were abstracted and indexed for EDB. Topics presented were in the areas of the physiology and biochemistry of autotraps, physiology and biochemistry of methylotrophs and methanotrops, physiology and biochemistry of methanogens, genetics of microbes that use C1 compounds, taxonomy and ecology of microbes tht grow on C1 compounds, applied aspects of microbes that grow on C1 compounds, and new directions in C1 metabolism. (DT)

  3. Autoantibodies against complement C1q specifically target C1q bound on early apoptotic cells.

    Bigler, Cornelia; Schaller, Monica; Perahud, Iryna; Osthoff, Michael; Trendelenburg, Marten

    2009-09-01

    Autoantibodies against complement C1q (anti-C1q) are frequently found in patients with systemic lupus erythematosus (SLE). They strongly correlate with the occurrence of severe lupus nephritis, suggesting a pathogenic role in SLE. Because anti-C1q are known to recognize a neoepitope on bound C1q, but not on fluid-phase C1q, the aim of this study was to clarify the origin of anti-C1q by determining the mechanism that renders C1q antigenic. We investigated anti-C1q from serum and purified total IgG of patients with SLE and hypocomplementemic urticarial vasculitis as well as two monoclonal human anti-C1q Fab from a SLE patient generated by phage display. Binding characteristics, such as their ability to recognize C1q bound on different classes of Igs, on immune complexes, and on cells undergoing apoptosis, were analyzed. Interestingly, anti-C1q did not bind to C1q bound on Igs or immune complexes. Neither did we observe specific binding of anti-C1q to C1q bound on late apoptotic/necrotic cells when compared with binding in the absence of C1q. However, as shown by FACS analysis and confocal microscopy, anti-C1q specifically targeted C1q bound on early apoptotic cells. Anti-C1q were found to specifically target C1q bound on cells undergoing apoptosis. Our observations suggest that early apoptotic cells are a major target of the autoimmune response in SLE and provide a direct link between human SLE, apoptosis, and C1q. PMID:19648280

  4. New data on the formation of Carboniferous coal balls

    Scott, A.C.; Mattey, D.P.; Howard, R. [University of London, Egham (United Kingdom). Royal Holloway and Bedford New College, Dept. of Geology

    1996-10-01

    Coal balls are formed from the precipitation of carbonate minerals, predominantly calcite, from water during or immediately post-peat formation. Previous petrological studies suggest permineralization occurred at various stages during the peatificiation process by precipitation from a mixture of marine and meteoric freshwater. The geochemical studies reported here aimed to test previous theories of coal ball formation. The coal balls studied are from Upper Carboniferous and Carboniferous/Permian coal seams in Britain, United States of America, Belgium and China. Stable carbon isotopic values of calcites range from {delta}{sup 13}C of -5 to -35 parts per thousand indicating highly variable contribution of decayed organic matter to the carbonate cement. Oxygen isotopic values of delta({sup 18}) range from -3 to -15 parts per thousand suggest both marine and meteoric freshwater sources. The range, in the British coal balls in particular, with {delta}{sup 13}C ranging from -7 to -25 parts per thousand indicates the complexity of carbonate generation. Isotopic data support at least four theories of carbonate coal ball formation. This makes their absence from post-Permian coals the more puzzling and it is suggested that the overall structure of the peat may play a role.

  5. Platinum and Palladium in Coal Rock and Geochemical Anomaly in Eastern Yunnan Province,Southwest China

    Xia Qinglin; Zhao Pengda; Cheng Qiuming; Chen Yongqing; Zhang Shengyuan

    2008-01-01

    A series of geochemical anomalies of Pt and Pd were found in 1 358 recombined samples from a geochemical stream sediment survey in eastern Yunnan (云南) Province, China. Chemical optical emission spectroscopy, X-ray fluorescence analysis, and inductively coupled plasmas atomic emission spectrometry analyses of 22 elements and chemical compositions of 21 samples from coal-bearing strata from the Late Paleozoic, Mesozoic, and Cenozoic show Pt and Pd concentrated to some extent in coal rocks, with Pd/Ptcoal-bearing strata of the Wanshoushan (万寿山) Formation; B, Mo, As, Pt, U, W, Pb, Pd, and V are enriched in the Lower Permian coal-bearing strata of the Liangshan (梁山) Formation; Pt, Cu, Mo, Pd, As, V, and Ag are enriched in the Upper Permian coal-bearing strata of the Xuanwei (宣威) Formation; As, B, Pb, Pt, Pd, U, W, Sb, Mo, Zn, and Ag are enriched in the Upper Triassic coal-bearing strata of the Xujiahe (须家河) Formation; and Pt, As, and Pb are enriched in the lignite of the Pliocene Ciying (茨营) Formation. Combining analyses of the sedimentary environment and local volcanic activity reveal that the coal-bearing strata in the Xuanwei Formation are possibly related to the permian Emeishan(峨眉山)basalt.

  6. Aromatized arborane/fernane hydrocarbons as molecular indicators of floral changes in Upper Carboniferous/Lower Permian strata of the Saar-Nahe Basin, southwestern Germany

    Vliex, M.; Hagemann, H. W.; Püttmann, W.

    1994-11-01

    Thirty-seven coal samples of Upper Carboniferous and Lower Permian age from three boreholes in the Saar-Nahe Basin, Germany, have been studied by organic geochemical and coal petrological methods. The investigations were aimed at the recognition of floral changes in the Upper Carboniferous and Lower Permian strata. The results show that compositional changes in the extracts are only partly caused by variations in coalification. Specific aromatic hydrocarbons appear in Upper Westphalian D coal seams and increase in concentration up to the Rotliegendes. The dominant compound has been identified by mass spectrometry and NMR-spectroscopy as 5-methyl-10-(4-methylpentyl)-des- A-25-norarbora(ferna)-5,7,9-triene (MATH) and always occurs associated with 25-norarbora(ferna)-5,7,9-triene. Both compounds are thought to originate from isoarborinol, fernene-3β-ol, or fernenes. The strongly acidic conditions during deposition of the coals might have induced the 4,5-cleavage combined with a methyl-shift in an arborane/fernane-type pentacyclic precursor yielding the MATH. Based on petrological investigations, palynomorphs related to early Gymnospermopsida such as Pteridospermales and Coniferophytes ( Cordaitales and Coniferales) increased in abundance in the strata beginning with the Upper Westphalian D concomitant with the above mentioned biomarkers. The results suggest the arborane/fernane derivatives originate from the plant communities producing these palynomorphs.

  7. Abundance of $C^1$-robust homoclinic tangencies

    Bonatti, C

    2009-01-01

    A diffeomorphism $f$ has a $C^1$-robust homoclinic tangency if there is a $C^1$-neighbourhood $\\cU$ of $f$ such that every diffeomorphism in $g\\in \\cU$ has a hyperbolic set $\\La_g$, depending continuously on $g$, such that the stable and unstable manifolds of $\\La_g$ have some non-transverse intersection. For every manifold of dimension greater than or equal to three, we exhibit a local mechanism (blender-horseshoes) generating diffeomorphisms with $C^1$-robust homoclinic tangencies. Using blender-horseshoes, we prove that homoclinic classes of $C^1$-generic diffeomorphisms containing saddles with different indices and that do not admit dominated splittings (of appropriate dimensions) display $C^1$-robust homoclinic tangencies.

  8. Interpretation of "fungal spikes" in Permian-Triassic boundary sections

    Hochuli, Peter A.

    2016-09-01

    Abundant occurrences of the palynomorph Reduviasporonites have been described as "fungal spike" from several Permian/Triassic boundary sections and related to the supposed destruction of woody vegetation by fungal pathogens during the Permian/Triassic extinction event. The biological affinity of this taxa considered by some authors of fungal origin is still controversially discussed since there is geochemical evidence that it is most probably related to algae. The abundance peak of this species is used by some authors as a stratigraphic marker, notably in terrestrial Permian/Triassic boundary sections from South China. Illustrations of the reported fungal remains however show potentially erroneous taxonomic identification of Reduviasporonites, and, based on differences in thermal maturation, they may represent recent contamination. Here Reduviasporonites chalastus of Early Triassic age is illustrated together with recent fungal remains originating from a strongly weathered and otherwise barren sample from a Middle Triassic section.

  9. The late Paleozoic oxygen pulse and accumulations of petroleum source rocks and coal

    PAVLE I. PREMOVIC

    2006-02-01

    Full Text Available Recent geophysical and geochemical data and theoretical modeling indicate high levels of atmospheric O2 (up to 35% during the Carboniferous-Permian. I suggest that this O2 pulse had a substantial impact on global accumulations of petroleum source rocks and coal during this geological period.

  10. Maceral Characteristics and Vitrinite Reflectance Variation of The High Rank Coals, South Walker Creek, Bowen Basin, Australia

    Asep K. Permana; Ward, C. R.; L. W. Gurba

    2014-01-01

    DOI: 10.17014/ijog.v8i2.156The Permian coals of the South Walker Creek area, with a vitrinite reflectance (Rvmax) of 1.7 to 1.95% (low-volatile bituminous to semi-anthracite), are one of the highest rank coals currently mined in the Bowen Basin for the pulverized coal injection (PCI) market. Studies of petrology of this coal seam have identified that the maceral composition of the coals are dominated by inertinite with lesser vitrinite, and only minor amounts of liptinite. Clay minerals, quar...

  11. Abundance of $C^1$-robust homoclinic tangencies

    Bonatti, C.; Diaz, L. J.

    2009-01-01

    A diffeomorphism $f$ has a $C^1$-robust homoclinic tangency if there is a $C^1$-neighbourhood $\\cU$ of $f$ such that every diffeomorphism in $g\\in \\cU$ has a hyperbolic set $\\La_g$, depending continuously on $g$, such that the stable and unstable manifolds of $\\La_g$ have some non-transverse intersection. For every manifold of dimension greater than or equal to three, we exhibit a local mechanism (blender-horseshoes) generating diffeomorphisms with $C^1$-robust homoclinic tangencies. Using bl...

  12. Anti-C1q autoantibodies.

    Kallenberg, Cees G M

    2008-09-01

    Autoantibodies to complement components are associated with various diseases. Anti-C1q antibodies are present in all patients with hypocomplementemic urticarial vasculitis, but also, with varying prevalence, in other conditions. In SLE, these antibodies are neither sensitive nor specific for this condition. They occur, however, more frequently in (proliferative) lupus nephritis, particularly during active disease. Furthermore, levels of anti-C1q rise, in many cases, prior to a relapse of lupus nephritis, suggesting a pathogenic role for the autoantibodies. Indeed, experimental studies strongly support a pathogenic role for anti-C1q in immune complex-mediated renal disease. In addition, anti-C1q may interfere with the clearance of apoptotic cells, so influencing induction and expression of autoimmunity. PMID:18606253

  13. A Selection of Recent Advances in C1 Chemistry.

    Mesters, Carl

    2016-06-01

    This review presents a selection of recent publications related to the chemistry and catalysis of C1 molecules, including methane, methanol, carbon monoxide, and carbon dioxide. These molecules play an important role in the current supply of energy and chemicals and will likely become even more relevant because of the need to decarbonize fuels (shift from coal to natural gas) in line with CO2 capture and use to mitigate global warming, as well as a gradual shift on the supply side from crude oil to natural gas. This review includes both recent industrial developments, such as the huge increase in methanol-to-olefins-capacity build in China and the demonstration of oxidative coupling of methane, and scientific developments in these chemistries facilitated by improved capabilities in, for example, analytical tools and computational modeling. PMID:27276549

  14. Gondwana basins and their coal resources in Bangladesh

    Fault bounded five Gondwana basins have been discovered in the north western Bangladesh. Among these basins show considerable amount of coal deposits. The Gondwana rocks are highly formed during the Permo-carboniferous diastrophism and later on acquired dynamic characters. In almost all basins, the Permian rocks overlie the Precambrian basement and underlie either the Tertiary or the Cretaceous sediments, structural, stratigraphic, and depositional history of these basins is more or less similar. The sedimentary sequences are composed of light to dark gray, fine to very coarse grained, sub angular to sub rounded felspathic sandstone, dark grey carbonaceous shale and sandstone, variegated conglomerate and thick coal seams (single seam max. 42.38m). The rocks are often alternated and bear the characteristics of cyclic sedimentation. The depositional environments varied from restricted drainage to open fluvial dominated low to moderate sinuous drainage system. The coal bearing basins were flanked by vegetated and swampy over bank. Age of these coals is suggested to be the late permian. Proved and probable reserves of coal in Jamalganj-Paharpur basin are 670 and 1,460 million metric tons, in Barapukuria basin 303 and 3899 million metric tons; in Barapukuria basin 303 and 389 million metric tons; and in Khalaspir basin 143 and 685 million metric tons respectively. The coal is high volatile, low sulphur, bituminous type. It can be used for different forms of thermal conversion. (author)

  15. Catalysis Action of Mineral/Metal Elements during Coalderived Hydrocarbons Process: An Example of the Late Permian Coal from Dahebian Coal Mine in Eastern Yunnan and Western Guizhou%矿物/金属元素在煤成烃过程中的作用——以黔西滇东上二叠统大河边煤矿煤样为例

    吴艳艳; 秦勇; 刘金钟; 王爱宽

    2012-01-01

    通过对原煤及添加过渡金属元素Mo(钼)和黄铁矿的原煤进行不同升温速率条件下煤层气生成热模拟实验,论述黄铁矿和Mo对于原煤热解生烃过程的影响。结果表明:矿物/过渡金属元素使原煤有机质具有更大的生烃潜力。黄铁矿对CH。具有显著的正催化作用;同时加入黄铁矿和Mo时,生成的气体中会含有更多数量的重烃气,并有利于烯烃的产出;Mo对C_7-C_14。具有显著的催化作用,但当同时有黄铁矿的参与时则会使C_7C_14。产率降低;黄铁矿/Mo的加入,则会影响到芳烃的产率高峰;较高的过渡金属单质含量对煤中本身含有的硫元素转化为H。S气体有抑制作用。在中-高温度范围内,催化剂对有机质生烃具有催化作用,升温条件能明显影响黄铁矿对芳烃、饱和烃和沥青质的催化作用,反映古地温场条件是催化生烃的一个重要影响因素。%The pyrolysis of coal with presence and absence of pyrite or Mo were carried out with different hearing ratios to study the coal bed gas formation process. The influence of pyrite and Mo on coal pyrolysis hydrocarbongenerating process was discussed. The results show that the mineral/transition metal elements make the coal have greater potential of hydrocarbon generation. Pyrite makes a positive and significant catalytic role to the methane generation. The presence of pyrite and Mo at the same time made the coal generate a few amount of heavier hydrocarbon gases,and the presence of pyrite and Mo is helpful to olefins output. Transition metal Mo has the remarkable catalytic effect on the C_7-C_14 generation, but the yield of C_7-C_14 components reduce if the presence of pyrite and Mo coexists. Pyrite and Mo influence the peak aromatics hydrocarbon and asphalt generation. High content of transition metal elements inhibit the H2 S formation from the sulfur in the coal. Catalysts have catalytic action for

  16. Gas hydrate contribution to Late Permian global warming

    Majorowicz, J.; Grasby, S. E.; Šafanda, Jan; Beauchamp, B.

    2014-01-01

    Roč. 393, May (2014), s. 243-253. ISSN 0012-821X Institutional support: RVO:67985530 Keywords : Latest Permian extinction * gas hydrates * carbon isotope shift Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 4.734, year: 2014

  17. Carboniferous and permian noeggerathialean plants and their spores; preliminary report

    Bek, Jiří; Wang, J.

    Prague : National Museum, 2006. ISBN 80-7036-198-0. [European Palaeobotany- Palynology Conference /7./. 06.09.2006-11.09.2006, Prague] R&D Projects: GA AV ČR IAA3013902 Institutional research plan: CEZ:AV0Z30130516 Keywords : Noeggerathiales * in situ spores * Palaeozoic-Permian Subject RIV: EF - Botanics

  18. Late Carboniferous to Late Permian carbon isotope stratigraphy

    Buggisch, Werner; Krainer, Karl; Schaffhauser, Maria;

    2015-01-01

    An integrated study of the litho-, bio-, and isotope stratigraphy of carbonates in the Southern Alps was undertaken in order to better constrain δ13C variations during the Late Carboniferous to Late Permian. The presented high resolution isotope curves are based on 1299 δ13Ccarb and 396 δ13Corg...

  19. Permian karst topography in the Wichita uplift, southwestern Oklahoma

    Donovan, R.N. Busbey, A.B. (Texas Christian Univ., Ft. Worth, TX (United States). Geology Dept.)

    1993-02-01

    The Wichita uplift in southwestern Oklahoma is one part of a record of Pennsylvania and early Permian deformation that affected the Southern Oklahoma aulacogen. As a result of a partial inversion, the Lower Paleozoic section of this aulacogen was sequentially stripped off an uplift between the Wichita uplift and the Anadarko basin, resulting in the exposure of ultrabasic rocks deep in the Cambrian igneous fill of the aulacogen. Following the late Paleozoic tectonism, the topography of the uplift was entombed beneath Permian sediments and remained essentially undisturbed until exhumation during the present erosional cycle. Modern erosion is gradually exposing this topography, permitting morphometric analysis of the Permian hill forms. Because of the variation of lithology in the uplift, it is possible to isolate the effects of weathering processes such as intense hydrolysis of the igneous rocks (producing, among other features, or topography) and limestone dissolution, in the form of a surface and subsurface karst imprint. The latter process resulted in a network of small caves that are essentially fissures eroded along tectonic fractures. These small caves can be found in all the exposed areas of limestone. They are particularly noteworthy for three reasons: in at least five examples they contain a complex fauna of Permian vertebrates (mostly fragmentary), speleothems in some examples contain hydrocarbon inclusions, derived from the underlying Anadarko basin, some of the caves yield evidence of post burial evolution in the form of clay infiltration from the surface and brine flushing from the underlying Anadarko basin.

  20. Terrestrial Permian - Triassic boundary sections in South China

    Bercovici, Antoine; Vajda, Vivi

    2016-08-01

    The Permian-Triassic boundary interval in China comprises a significant record of faunal and floral changes during this important extinction event. Here we discuss the details of palynomorph preservation at the classical Western Guizhou and Eastern Yunnan sections in an effort to expand the stratigraphy and paleontology from these earlier studies.

  1. Terrestrial acidification during the end-Permian biosphere crisis?

    Sephton, Mark A.; Jiao, Dan; Engel, Michael H.; Looy, Cindy V.; Visscher, Henk

    2015-01-01

    Excessive acid rainfall associated with emplacement of the Siberian Traps magmatic province is increasingly accepted as a major contributing factor to the end-Permian biosphere crisis. However, direct proxy evidence of terrestrial acidification is so far not available. In this paper, we seek to dete

  2. Coal upgrading

    Nunes, S. [IEA Clean Coal Centre, London (United Kingdom)

    2009-10-15

    This report examines current technologies and those likely to be used to produce cleaner coal and coal products, principally for use in power generation and metallurgical applications. Consideration is also given to coal production in the leading coal producing countries, both with developed and developing industries. A range of technologies are considered. These include the coal-based liquid fuel called coal water mixture (CWM) that may compete with diesel, the production of ultra-clean coal (UCC) and coal liquefaction which competes with oil and its products. Technologies for upgrading coal are considered, especially for low rank coals (LRC), since these have the potential to fill the gap generated by the increasing demand for coal that cannot be met by higher quality coals. Potential advantages and downsides of coal upgrading are outlined. Taking into account the environmental benefits of reduced pollution achieved through cleaner coal and reduced transport costs, as well as other positive aspects such as a predictable product leading to better boiler design, the advantages appear to be significant. The drying of low rank coals improves the energy productively released during combustion and may also be used as an adjunct or as part of other coal processing procedures. Coal washing technologies vary in different countries and the implications of this are outlined. Dry separation technologies, such as dry jigging and electrostatic separation, are also described. The demonstration of new technologies is key to their further development and demonstrations of various clean coal technologies are considered. A number of approaches to briquetting and pelletising are available and their use varies from country to country. Finally, developments in upgrading low rank coals are described in the leading coal producing countries. This is an area that is developing rapidly and in which there are significant corporate and state players. 81 refs., 32 figs., 3 tabs.

  3. The Permian Dongfanghong island-arc gabbro of the Wandashan Orogen, NE China: Implications for Paleo-Pacific subduction

    Sun, Ming-Dao; Xu, Yi-Gang; Wilde, Simon A.; Chen, Han-Lin; Yang, Shu-Feng

    2015-09-01

    The Dongfanghong hornblende gabbro is located in the western part of the Wandashan Orogen and to the east of the Jiamusi Block in NE China. It was emplaced into Early Paleozoic oceanic crust (i.e. Dongfanghong ophiolite) at ~ 275 Ma and both later collided with the eastern margin of the Jiamusi Block. The Dongfanghong gabbro is sub-alkaline with high Na2O contents and is characterized by enrichment in light rare earth elements (LREE), large ion lithosphile elements (LILE), Sr, Eu, and Ba, and depletion in high field strength elements (HFSE). The enriched isotopic signatures (87Sr/86Sri = ~ 0.7065, εNd(t) = ~- 0.5, 208Pb/204Pbi = ~ 38.05, 207Pb/204Pbi = ~ 15.56, 206Pb/204Pbi = ~ 18.20 and zircon εHf(t) = ~+ 5.8) indicate an enriched mantle (EM2) source, with some addition of continental material. It has arc geochemical affinities similar to Permian arc igneous rocks in the eastern margin of the Jiamusi Block, the Yakuno Ophiolite in SW Japan, arc rocks along the western margin of the North America Craton, and also the Gympie Group in eastern Australia. All these features, together with information from tectonic discrimination diagrams, suggest that the Dongfanghong gabbro formed in an immature island arc. The spatial configuration of ~ 290 Ma immature continental arc rocks in the eastern part of the Jiamusi Block and the ~ 275 Ma immature island arc Dongfanghong gabbro in the Wandashan Orogen to the east is best explained by eastward arc retreat and slab roll-back of the Paleo-Pacific Plate. This model is also supported by the Carboniferous-Permian stratigraphic transition in the Jiamusi Block from oceanic carbonate rocks to coal-bearing terrestrial clastic rocks and andesites. We thus suggest that both Paleo-Pacific subduction and roll-back occurred in the Early Permian along the eastern margin of Asia.

  4. Early Triassic alternative ecological states driven by anoxia, hyperthermals, and erosional pulses following the end-Permian mass extinction

    Pietsch, C.; Petsios, E.; Bottjer, D. J.

    2015-12-01

    The end-Permian mass extinction, 252 million years ago, was the most devastating loss of biodiversity in Earth's history. Massive volcanic eruptions of the Siberian Traps and the concurrent burning of coal, carbonate, and evaporite deposits emplaced greenhouse and toxic gasses. Hyperthermal events of the surface ocean, up to 40°C, led to reduced gradient-driven ocean circulation which yielded extensive equatorial oxygen minimum zones. Today, anthropogenic greenhouse gas production is outpacing carbon input modeled for the end-Permian mass extinction, which suggests that modern ecosystems may yet experience a severe biotic crisis. The Early Triassic records the 5 million year aftermath of the end-Permian mass extinction and is often perceived as an interval of delayed recovery. We combined a new, high resolution carbon isotope record, sedimentological analysis, and paleoecological collections from the Italian Werfen Formation to fully integrate paleoenvironmental change with the benthic ecological response. We find that the marine ecosystem experienced additional community restructuring events due to subsequent hyperthermal events and pulses of erosion. The benthic microfauna and macrofauna both contributed to disaster communities that initially rebounded in the earliest Triassic. 'Disaster fauna' including microbialites, microconchids, foraminifera, and "flat clams" took advantage of anoxic conditions in the first ~500,000 years, dominating the benthic fauna. Later, in the re-oxygenated water column, opportunistic disaster groups were supplanted by a more diverse, mollusc-dominated benthic fauna and a complex ichnofauna. An extreme temperature run-up beginning in the Late Dienerian led to an additional hyperthermal event in the Late-Smithian which co-occurred with increased humidity and terrestrial run-off. Massive siliciclastic deposits replaced carbonate deposition which corresponds to the infaunalization of the benthic fauna. The disaster taxa dominated

  5. On orientifolds of c=1 orbifolds

    Dijkstra, T.P.T. [NIKHEF, PO Box 41882, 1009 DB Amsterdam (Netherlands); Gato-Rivera, B. [NIKHEF, PO Box 41882, 1009 DB Amsterdam (Netherlands); Riccioni, F. [NIKHEF, PO Box 41882, 1009 DB Amsterdam (Netherlands)]. E-mail: f.riccioni@damtp.cam.ac.uk; Schellekens, A.N. [NIKHEF, PO Box 41882, 1009 DB Amsterdam (Netherlands)

    2004-10-25

    The aim of this paper is to study orientifolds of c=1 conformal field theories. A systematic analysis of the allowed orientifold projections for c=1 orbifold conformal field theories is given. We compare the Klein bottle amplitudes obtained at rational points with the orientifold projections that we claim to be consistent for any value of the orbifold radius. We show that the recently obtained Klein bottle amplitudes corresponding to exceptional modular invariants, describing bosonic string theories at fractional square radius, are also in agreement with those orientifold projections.

  6. On Orientifolds of c=1 Orbifolds

    Dijkstra, T P T; Riccioni, F; Schellekens, Adrian Norbert

    2003-01-01

    The aim of this paper is to study orientifolds of c=1 conformal field theories. A systematic analysis of the allowed orientifold projections for c=1 orbifold conformal field theories is given. We compare the Klein bottle amplitudes obtained at rational points with the orientifold projections that we claim to be consistent for any value of the orbifold radius. We show that the recently obtained Klein bottle amplitudes corresponding to exceptional modular invariants, describing bosonic string theories at fractional square radius, are also in agreement with those orientifold projections.

  7. Coal-92

    Swedish consumption of coal and coke during 1991 and trends in technology, environment and market aspects of coal use are reported. Steam coal use in the heating sector was unchanged from 1991, 1.2 Mtons. Reduced consumption in smaller district heating units (due to conversion to biofuels and gas) was compensated by increased use for power generation in cogeneration plants. Coal consumption in industry fell 0.10 Mton to 0.84 Mton due to lower production in one industry branch. Import of steam coal was 1.1 Mton (down 0.5 Mton from 1990) since new rules for strategic reserves allowed a reduction of stocks. During the last five years stocks have been reduced by 2 Mtons. Import of metallurgical coal was 1.6 Mton, unchanged from 1990. The report also gives statistics for the coal using plants in Sweden, on coal R and D, and on emission laws for coal firing. (9 tabs., 2 figs.)

  8. Palaeotopography-governed sediment distribution—a new predictive model for the Permian Upper Rotliegend in the Dutch sector of the Southern Permian Basin

    Mijnlieff, H.F.; Geluk, M.

    2011-01-01

    The Southern Permian Basin (SPB) formed a large, elongated saucer-shaped inland depression extending from the UK to Poland and from Belgium to Denmark. During the Middle to early Late Permian the SPB was filled progressively by playa sediments from its centre in northwestern Germany before it was fl

  9. Anti-C1q autoantibodies

    Kallenberg, Cees G. M.

    2008-01-01

    Autoantibodies to complement components are associated with various diseases. Anti-C1q antibodies are present in all patients with hypocomplementemic urticarial vasculitis, but also, with varying prevalence, in other conditions. In SLE, these antibodies are neither sensitive nor specific for this co

  10. Sequence-Stratigraphic Framework from the Carboniferous to the Permian Chuanshanian Epoch in Dianqiangui Basin and Its Adjacent Areas, Southwest China

    Mei Mingxiang; Ma Yongsheng; Deng Jun; Meng Qingfen; Li Donghai

    2005-01-01

    The Carboniferous can be divided into four series in the Dianqiangui basin and its adjacent areas, Southwest China: the Yanguanian series, the Datangian series, the Weiningian series and the Mapingian series. The Maping Formation, traditionally used as the lithostratigraphic unit of the Upper Carboniferous, became an inter-system unit from the Carboniferous to the Permian. Thus, the top part of the Carboniferous and the bottom part of the Permian (Chuanshanian series) constitute a third-order sequence in the Dianqiangui basin and its adjacent areas. In the study area, the Carboniferous system and the Chuanshanian series of the Permian constitute a second-order sequence that can be subdivided into 6 third-order sequences. The bottom boundary of this second-order sequence is an unconformity formed in the principal episode of the Ziyun movement (the second episode), and the top boundary is also an unconformity formed in the principal episode of the Qiangui movement (the second episode). In different paleogeographical backgrounds, the strata from the Carboniferous to the Permian Chuanshanian epoch are marked by different sedimentary features. For example, coal measures and more dolomitic strata are developed in the attached platform; carbonate rocks mainly constitute the isolated platform strata; the inter-platform ditch strata are mainly composed of dark and fine sediments. Therefore, third-order sequences with different architectures of sedimentary-facies succession are formed in different paleogeographical backgrounds. Although the third-order sequences are different in the architecture of sedimentary-succession in space, the processes of their depositional environmental changes due to the third-order relative sea-level changes are simultaneous. Biostratigraphically, the surfaces of the third-order sequences can be correlated and traced in space; the framework of sequence stratigraphy from the Carboniferous to the Chuanshanian epoch of the Permian can be established

  11. A Review on Permian to Triassic Active or Convergent Margin in Southeasternmost Gondwanaland: Possibility of Exploration Target for Tin and Hydrocarbon Deposits in the Eastern Indonesia

    Amiruddin Amiruddin

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol4no1.20094An active convergence of continental margin is probably generated in Gondwanaland during Permian to Triassic period which is characterized by the presence of magmatic and volcanic belts and back-arc ba- sins occupied respectively by Permian to Triassic rocks. The magmatic belt is occupied by peraluminous granitic plutons showing characteristics of S- type granite and is considered as tin-bearing granites. The back-arc basins are occupied by the Southern Papua and Galille-Bowen-Gunnedah-Sydney Basins. Those large basins are respectivelly filled by fluvial, fluvio- deltaic to marine Permian-Triassic sediments, which are unconformably overlain by the Jurrassic-Cretaceous marine succession. The paleomagnetic data, confirmed by flora content found in Australia and Papua, indicate that those areas initially belong to the Gondwanaland before part of them were drifted and rotated into the present day position. Tectonically, the presence of those Permian-Triassic magmatic-volcanic belts and back-arc basins in behind, indicates that at the time there were huge compressive activities: convergence of paleo-oceanic Pasific Plate moving westward, collided and subducted into the Southeastern Gondwana Continental Plate, moved relatively eastwards. This phenomenon resembles to the formation of Sumatera Tertiary tectonic zones producing back-arc basins, i.e. South Sumatera, Central, and North Sumatera Basins including the Tertiary Magmatic Arc. Concerning the similarity of Permian-Triassic geological condition of the magmatic arc and back-arc basins in Eastern Indonesia and Eastern Australia including paleoposition, paleotectonic setting, strati- graphic succession, and lithologic composition, it is suggested to carry out an increase in a more intens- ive tin exploration in the Eastern Indonesia, e.g. Bird Head area and Banggai Sula Island, and also for hydrocarbon target (coal, coalbed methane, oil and gas, and oil

  12. Influence of palaeotopography on the distribution of coal in the Western Coalfield, Sydney basin, Australia: comparison with South African coals

    Hutton, A. C.; Feldtmann, R.

    1996-07-01

    The Western Coalfield of New South Wales, centred on the town of Lithgow, is one of several areas of the Sydney Basin (Australia) that produces Permian coals for export and for domestic: use. The lowermost seam of the Illawarra Coal Measures, the Lithgow seam, was deposited in an alluvial fan to proximal braidplain complex. The style of clastic sedimentation and coal seam development was strongly influenced by the palaeotopography, especially basement highs which represent erosional remnants of the pre-Permian erosional cycle. The influence of the palaeotopography is seen in the distribution of the basal conglomerate, the thickness of the basal Shoalhaven Group (which is thinnest on and near the basement highs), the location of the alluvial fan facies of the Illawarra Coal Measures (which are adjacent to the highs and received a large proportion of the clastic detritus from these highs) and the development of the coal seams (which are distal to the basement highs). Of great significance is the location of economic sections of the Lithgow seam with respect to palaeotopographic highs. Adjacent to the highs the Lithgow seam is either too thin or contains too many claystone bands to allow mining. Between the highs: and further to the east and north of the highs, where the precursor peats formed on the floodplain and interfan areas, the seam is of significantly better quality and has been mined.

  13. Palynostratigraphy of Permian succession in the Mand–Raigarh Coalfield, Chhattisgarh, India and phytogeographical provincialism

    Srikanta Murthy; Ram-Awatar; Saurabh Gautam

    2014-12-01

    Palynofloras have been recorded from the Barakar Formation in the Borehole MBKW-3, Barpali–Karmitikra Block, Mand–Raigarh Coalfield, Chhattisgarh. Three distinct palynoassemblages have been identified and referred to the following palynoassemblage zones – Gondisporites raniganjensis (Latest Permian); Faunipollenites varius (latest Early Permian), and Scheuringipollenites barakarensis (late Early Permian). It is inferred that these deposits contain the representative palynoassamblages of Early to Late Permian in age. The First Appearance Datum (FAD)s of Arcuatipollenites pellucidus, A. ovatus, Guttulapollenites hannonicus, Lundbladispora microconata, Alisporites opii, Klausipollenites sp., and Goubinispora indica (at 41.95, 45.90, 98.35 m depths), indicate the closing phase of Permian, as these elements are the key species that mark a transition from Permian to the Lower Triassic. An attempt has been made here to reconstruct the phytogeographical provincialism on the basis of Guttulapollenites recorded in this basin.

  14. Permian-Triassic mafites of Sette-Daban

    The paper describe the ores which form the Permian-Triassic dike zones of the Southern part of the Sette-Daban fold-blowing structure adjacent to the Siberian platform. The data are presented on K-Ar age of gabbro-diabase dike in the basin of Ariavkan River: the age of plagioclase is 276 ± 1 million years and that of kali feldspar - 222 ± 30 million years. It agrees with potassium - argon dating of mafites with similar compositions in the Northern part of the region. It is shown that the Permian-Triassic dikes can be of interest for the prospecting of the deposits of lead, zinc, phosphates and other minerals. 10 refs., 1 fig., 1 tab,

  15. Descriptive Study on the Epidemiology of Lung Cancer in Coal-producing Area in Eastern Yunnan, China

    Li, Jihua; Yunsheng ZHANG; Li, Yun; Guoqing YIN; Li, Yuebing; Bofu NING; Jiamin GUO

    2011-01-01

    Background and objective Xuanwei county is located at Late Permian coal-accumulating area in eastern Yunnan and western Guizhou, China. The lung cancer mortality rate in Xuanwei county is among the highest in China and has been attributed to exposure to indoor smoky coal emissions that contain very high levels of polycyclic aromatic hydrocarbons (PAHs). Recent years, the pollution and the higher mortality rate of lung cancer has been watched in the area around Xuanwei, and there is no report ...

  16. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  17. Lower Permian brachiopods from Oman : their potential as climatic proxies

    Angiolini, L.; D. P. F. Darbyshire; Stephenson, Michael; Leng, Melanie; Brewer, T. S.; F. Berra; F. Jadoul

    2008-01-01

    The Lower Permian of the Haushi basin, Interior Oman (Al Khlata Formation to Saiwan Formation/lower Gharif member) records climate change from glaciation, through marine sedimentation in the Haushi sea, to subtropical desert. To investigate the palaeoclimatic evolution of the Haushi sea we used O, C, and Sr isotopes from 31 brachiopod shells of eight species collected bed by bed within the type-section of the Saiwan Formation. We assessed diagenesis by scanning electron microscopy of ultrastr...

  18. The Permian-Triassic boundary & mass extinction in China

    Ian Metcalfe; Lance Black; Qu Xun; Mao Xiaodong; Robert S. Nicoll; Roland Mundil; Clinton Foster; Jonathan Glen; John Lyons; Wang Xiaofeng; Wang Cheng-yuan; Paul R. Renne

    2001-01-01

    @@ The first appearance of Hindeodus parvus (Kozur & Pjatakova) at the Permian-Triassic (P-T) GSSP level (base of Bed 27c) at Meishan is here confirmed. Hindeodus changxingensis Wang occurs from Beds 26 to 29 at Meishan and appears to be restricted to the narrow boundary interval immediately above the main mass extinction level in Bed 25. It is suggested that this species is therefore a valuable P-T boundary interval index taxon.

  19. Coal desulfurization

    Corcoran, William H. (Inventor); Vasilakos, Nicholas P. (Inventor); Lawson, Daniel D. (Inventor)

    1982-01-01

    A method for enhancing solubilizing mass transport of reactive agents into and out of carbonaceous materials, such as coal. Solubility parameters of mass transfer and solvent media are matched to individual peaks in the solubility parameter spectrum of coals to enhance swelling and/or dissolution. Methanol containing reactive agent carriers are found particularly effective for removing organic sulfur from coals by chlorinolysis.

  20. Spiral-shaped graphoglyptids from an Early Permian intertidal flat

    Minter, Nicholas J.; Buatois, Luis A.; Lucas, Spencer G.; Braddy, Simon J.; Smith, Joshua A.

    2006-12-01

    Spiral-shaped foraging trace fossils, assigned to the grapho glyptid cf. Spirorhaphe azteca, are reported from an Early Permian intertidal flat in the Robledo Mountains of southern New Mexico, USA. Remarkably similar spiral-shaped structures are produced in modern intertidal flats by the paraonid polychaete Paraonis fulgens, and function as traps to capture mobile microorganisms migrating in the sediment in response to tides. We envisage a similar function for the Early Permian trace fossils. Previous studies have suggested that the lack of P. fulgens type traces from ancient intertidal deposits indicates that such behavior only evolved geologically recently in such settings. However, this report demonstrates that such specialized foraging behavior was present in intertidal settings by at least the Early Permian. Graphoglyptids are typical of deep-marine settings, and characteristic of the Nereites ichnofacies. This represents their first undoubted occurrence in intertidal facies in the geological record. We postulate that the occurrence of graphoglyptids in deep-marine and intertidal settings is related to the predictability of resources. The scarcity of intertidal graphoglyptids in the geological record is most likely a preservational effect.

  1. Lower Permian Dry Mountain trough, eastern Nevada: preliminary basin analysis

    Schwarz, D.L.; Snyder, W.S.; Spinosa, C.

    1987-08-01

    The Lower Permian Dry Mountain trough (DMT) is one of several basins that developed during the Late Pennsylvanian to Permian along the western edge of the North American continent. A tectonic mechanism has been suggested for the subsidence of the DMT, possibly due to reactivation of the Antler orogenic belt during the waning stages of Ancestral Rocky Mountain deformation. The DMT records marked subsidence with the appearance during the Artinskian (latest Wolfcampian) of a deeper water facies that consists of thin-bedded silty micrites and micritic mudstones rich in radiolarians and sponge spicules, characterized by a relative abundance of ammonoids, and rarer conodonts and Nereites ichnofacies trace fossils. Taxa recovered from a distinctive concretionary horizon at various locations provide an Artinskian datum on which to palinspastically reconstruct the DMT paleogeography. These taxa include ammonoids: Uraloceras, Medlicottia, Marathonites, Crimites, Metalegoceras, properrinitids; and conodonts: Neogondolella bisselli, Sweetognathus whitei, S. behnkeni, and Diplognathodus stevensi. The western margin facies of the DMT consists of Permian Carbon Ridge/Garden Valley Formations. Here, lowermost black Artinskianage euxinic micrites, considered a potential source rock for petroleum generation, are overlain by base-of-slope carbonate apron deposits, which, in turn, are overlain by base-of-slope carbonate apron deposits, which, in turn, are overlain by a thick, eastwardly prograding conglomerate wedge. Seismic profiles across Diamond Valley indicate a 3.0-4.6-km thick Tertiary sequence above the Paleozoic strata.

  2. Thecamoebians from Late Permian Gondwana sediments of peninsular India.

    Farooqui, Anjum; Aggarwal, Neha; Jha, Neerja

    2014-02-01

    The evolutionary history of thecamoebians (testate amoebae) extends back to the Neoproterozoic Era. However, until now, these have had a restricted, discontinuous and modest record across the world. The studied sediment of Raniganj Formation (Godavari Graben), Andhra Pradesh, India has been assigned as Late Permian on the basis of co-occurring age-diagnostic Late Permian palynomorphs. About sixteen thecamoebian species and one taxon incertae sedis have been recorded here in the palynological slides on the basis of shell morphology and morphometry. Out of these, five belong to the family Arcellidae, seven to Centropyxidae, two to Trigonopyxidae, one to Difflugiidae, one to Plagiopyxidae, and one is regarded incertae sedis. The morphometric characteristics of fossil forms resemble their corresponding extant species studied from ecologically diverse fresh water wetlands in India. In general, the ratio of shell diameter and aperture diameter of Late Permian fossil and extant specimens show significant correlation in all the studied species. Except that, the ratio of shell length and breadth is the distinguishing feature between Centropyxis aerophila and C. aerophila 'sylvatica', rather than the ratio of shell length and longest diameter of the shell aperture in both fossil and extant forms. The study elucidates the minimal morphological evolution in thecamoebians and their survival during mass extinction periods and stressful environmental conditions over the geological timescale. PMID:23876495

  3. Hooked: Habits of the Chinese Permian gigantopterid Gigantonoclea

    Seyfullah, Leyla J.; Glasspool, Ian J.; Hilton, Jason

    2014-04-01

    Based upon anatomical evidence, Permian aged gigantopterid fossils are in general reconstructed as climbing or scrambling plants. Gigantonoclea, a genus of adpressed gigantopterid foliage from the Permian of northern China, has been reported to co-occur with hook-like organs that were interpreted as indicating a scrambling/climbing habit. We reinvestigated these hook-like structures and re-evaluated the nature of the co-occurrences in context with the flora preserved in each plant-bearing fossil 'bed' in the North China sedimentary succession. New findings show that the species Gigantonoclea hallei probably climbed using specially adapted clusters of compound grappling hook-like shoots borne on the stems. This structural arrangement comprising shoots of hooks is new to the scrambling/climbing concept in gigantopterids. However, a key figured specimen previously reported as showing intermediate hook-tipped leaf morphology on a sole pinnule tip is discounted as such and is reinterpreted as a 'normal' pinnule partially hidden under sediment that results in an unusual appearance to this pinnule tip. Adaptations for climbing or scrambling based upon 'hooked leaves' observed in Gigantonoclea lagrelii are no longer supported and are reinterpreted as incompletely expanded leaves where the vernation process was interrupted. These data weaken prior interpretations of G. lagrelii as a climber/scrambler and raise doubts about the ubiquity of hooks amongst the gigantopterids as structures enabling them to climb or scramble their way through the Permian world.

  4. Monitoring light hydrocarbons in Brazilian coal mines and in confined coal samples

    Monitoring light hydrocarbons (LHCs) in coal mines, particularly methane, is important not only because of their implications for global climate change but also for economic and safety reasons. Furthermore, the identification and quantification of LHCs in coal mine air samples and desorbed from confined coal may contribute to a better understanding of coal seam characteristics. The paucity of information about the levels of methane in Brazilian underground coal mines can be attributed to their difficult access and a lack of adequate procedures for correct gas sampling. The aim of this study is to optimize and apply standard gas chromatography procedures to determine LHC levels in the air of coal mines and in confined coal from five mines under operation, three underground (A, B, C) and two surface (D, E) mines, in southern Brazil. The results indicate methane (C1) levels varying from 3 ppm to 27% in the atmosphere of the underground mines. Mine A presented high levels of all LHCs analyzed (C1 to C5), while only C1 and C2 were detected in mine B, and hydrocarbons ranging from C1 to C4 were found in mine C. On the other hand, surface mines presented narrow concentration range for C1 (3 ppm to 470 ppm) and C2-C3, with higher levels observed for puncture explosive points. Among LHCs, methane is desorbed in higher concentrations from confined coals and the presence of C2 was detected in all samples while C3-C5 were only observed in coals from underground mines. These data are consistent with those obtained from the air gas samples collected in the mines under study. Geological events such as faulting and intrusions can accelerate the release of gas or the trapping of large amounts of previously released methane. The LHC emissions from coal mines were found to be highly variable, indicating the need for a comprehensive survey of Brazilian coal mine emissions. (author)

  5. Geology and coal bed methane resource potential of the Gondwana Barapukuria Coal Basin, Dinajpur, Bangladesh

    Islam, Md. Rafiqul; Hayashi, Daigoro [Department of Physics and Earth Sciences Faculty of Science, University of the Ryukyus, Okinawa, 903-0213 (Japan)

    2008-08-05

    With an area of 5.16 km{sup 2}, the Barapukuria coal deposit is one of the five largest Gondwana coal basins in Bangladesh, and is located in the north west of the country close to the towns of Dinajpur and Saidpur. The existence of the basin was initially indicated by a negative gravity anomaly in oil and gas exploration. Exploration for the deposit was commenced by the Geological Survey of Bangladesh (GSB), with seven surface boreholes that confirmed the existence of a significant coal deposit. The deposit occurs as an asymmetrical synclinal structure with an axis striking approximately N-S. The deposit is limited to the east by a large normal fault which has displaced Archaean metamorphics against the Gondwana sediments. The coal-bearing sediments are comprised of Gondwana Permian-age sandstones, siltstones, subordinate carbonaceous shales, and six correlated coal seams. The Gondwana sediments are unconformably overlain by Tertiary and Quaternary deposits, against which the coal seams are successively subcropped to the west. Within the structural limits of the basin, approximately 377 Mt coal in-situ has been quantified in the six coal seams that range in depth from 118 to 518 m below surface. Due to the synclinal nature of the deposit, the upper coal seams, designated I to V, occur over diminishing areal extent with decreasing depth. The principal seam of interest is the lowermost Seam VI, with a variable thickness across the deposit from 22 m in the northern part of the deposit to more than 42 m in the southern and eastern areas. Development of the Barapukuria Mine, the country's first coal mine, commenced in 1996 with the construction of two vertical shafts. Coal production from Seam VI began in 2005 and continues at the present time. Seam VI coal is high volatile B bituminous rank. About 34 Mt of coal has been estimated as recoverable resources, utilising descensional multi-slice longwall mining. The mine design and development have been severely

  6. COOPERATIVE RESEARCH IN C1 CHEMISTRY

    Gerald P. Huffman

    2001-04-30

    Faculty and students from five universities (Kentucky, West Virginia, Utah, Pittsburgh and Auburn) are collaborating on a basic research program to develop novel C1 chemistry processes for the production of clean, high quality transportation fuel. An Industrial Advisory Board (IAB) with members from Chevron, Eastman Chemical, Energy International, Teir Associates, and the Department of Defense has been formed to provide practical guidance to the program. The program has two principal objectives. (1) Develop technology for conversion of C1 source materials (natural gas, synthesis gas, carbon dioxide and monoxide, and methanol) into clean, high efficiency transportation fuel. (2) Develop novel processes for producing hydrogen from natural gas and other hydrocarbons. Some of the principal accomplishments of the program in its first two years are: (1) The addition of acetylenic compounds in Fischer-Tropsch synthesis is found to produce significant amounts of oxygenated products in FT diesel fuels. Such oxygenated products should decrease particulate matter (PM) emissions. (2) Nanoscale, binary, Fe-based catalysts supported on alumina have been shown to have significant activity for the decomposition of methane into pure hydrogen and potentially valuable multi-walled carbon nanotubes. (3) Catalytic synthesis processes have been developed for synthesis of diethyl carbonate, higher ethers, and higher alcohols from C1 source materials. Testing of the effect of adding these oxygenates to diesel fuel on PM emissions has begun using a well-equipped small diesel engine test facility. (4) Supercritical fluid (SCF) FT synthesis has been conducted under SCF hexane using both Fe and Co catalysts. There is a marked effect on the hydrocarbon product distribution, with a shift to higher carbon number products. These and other results are summarized.

  7. C1q protein binds to the apoptotic nucleolus and causes C1 protease degradation of nucleolar proteins.

    Cai, Yitian; Teo, Boon Heng Dennis; Yeo, Joo Guan; Lu, Jinhua

    2015-09-11

    In infection, complement C1q recognizes pathogen-congregated antibodies and elicits complement activation. Among endogenous ligands, C1q binds to DNA and apoptotic cells, but whether C1q binds to nuclear DNA in apoptotic cells remains to be investigated. With UV irradiation-induced apoptosis, C1q initially bound to peripheral cellular regions in early apoptotic cells. By 6 h, binding concentrated in the nuclei to the nucleolus but not the chromatins. When nucleoli were isolated from non-apoptotic cells, C1q also bound to these structures. In vivo, C1q exists as the C1 complex (C1qC1r2C1s2), and C1q binding to ligands activates the C1r/C1s proteases. Incubation of nucleoli with C1 caused degradation of the nucleolar proteins nucleolin and nucleophosmin 1. This was inhibited by the C1 inhibitor. The nucleoli are abundant with autoantigens. C1q binding and C1r/C1s degradation of nucleolar antigens during cell apoptosis potentially reduces autoimmunity. These findings help us to understand why genetic C1q and C1r/C1s deficiencies cause systemic lupus erythematosus. PMID:26231209

  8. Hereditary Angioedema due to C1 Inhibitor Deficiency: C1-INH Replacement Therapy

    Mauro Cancian

    2014-04-01

    Full Text Available Hereditary angioedema (HAE is a rare condition affecting about 1 in 50.000 individuals and caused by a mutation in the gene encoding the C1-esterase inhibitor (C1-INH, which is involved in the control of complement, clotting, fibrinolytic and kinin pathways. HAE is characterized by plasma outflow from blood vessels, leading to fluid collecting (edema in the deep tissue layers of the face, larynx, abdomen, and extremities. Three different types of HAE have been identified: in type I the mutation leads to the lack of production of C1-INH, in type II the mutation leads to the production of dysfunctional C1-INH, while type III is extremely rare and still not fully understood. Therapeutic approaches for HAE include on-demand treatments to stop angioedema attacks and prophylactic treatment to prevent attacks both by pre-procedural (short-term and routine (long-term prophylaxis. Aim of the present review is to present an overview of C1-INH replacement therapy with the plasma-derived concentrate of C1-INH Berinert® (CSL Behring GmbH in the treatment of type I and II HAE.http://dx.doi.org/10.7175/rhc.v5i2.913

  9. Permian U-Pb (CA-TIMS) zircon ages from Australia and China: Constraining the time scale of environmental and biotic change

    Denyszyn, S. W.; Mundil, R.; Metcalfe, I.; He, B.

    2010-12-01

    In eastern Australia, the interconnected Bowen and Sydney Basins are filled with terrestrial sediments of late Paleozoic to early Mesozoic age. These sedimentary units record significant evolutionary events of eastern Gondwana during the time interval between two major mass extinctions (end Middle Permian and Permian-Triassic), and also provide lithological evidence for the Carboniferous-Permian Late Paleozoic Ice Age of southern Pangea, considered to be divisible into up to seven discrete glaciation events in Australia [e.g., 1]. These glaciations are currently assigned ages that indicate that the last of the glaciations predate the end Middle Permian mass extinction at ca. 260 Ma. However, the estimates for the time and durations are largely based on biostratigraphy and lithostratigraphy that, in the absence of robust and precise radioisotopic ages, are unacceptably fragile for providing an accurate high-resolution framework. Interbedded with the sediments are numerous tuff layers that contain zircon, many of which are associated with extensive coal measures in the Sydney and Bowen Basins. Published SHRIMP U-Pb zircon ages [2, 3] have been shown to be less precise and inaccurate when compared to ages applying the CA-TIMS method to the same horizons. Also within the late Middle Permian, the eruption of the Emeishan flood basalts in SW China has been proposed to have caused the end Middle Permian mass extinction [e.g., 4], though a causal link between these events demands a rigorous test that can only be provided by high-resolution geochronology. We present new U-Pb (CA-TIMS) zircon ages on tuff layers from the Sydney and Bowen Basins, with the purpose of generating a timescale for the Upper Permian of Australia to allow correlation with different parts of the world. Initial results, with permil precision, date a tuff layer within the uppermost Bandanna Fm. to ca. 252 Ma, a tuff within the Moranbah Coal Measures to ca. 256 Ma, and a tuff within the Ingelara Fm. to

  10. Explanation for peat-forming environments of coal seam 2 and 9-2 based on the maceral composition and aromatic compounds in the Xingtai coalfield, China

    SUN Yu-zhuang; QIN Shen-jun; LI Yan-heng; LIN Ming-yue; DING Shu-li

    2009-01-01

    Maceral composition and aromatic compounds were determined on column samples to study the peat-forming environments of Permian coal seam 2 and Carbonifer-ous coal seam 9-2 from the Xingtai coalfield,China.The macerals were dominated by iner-tinite in seam 2 and by vitrinite in seam 9-2.Three maceral groups were selected as indi-cators of peat-forming environments.Two triangle diagrams were drawn based on the in-dicators to explicate the peat-forming environments of permian seam 2 and Carboniferous seam 9-2.The results indicate that the peat of carboniferous seam 9-2 formed dominantly in wet swamps,whereas the peat of Permian seam 2 formed dominantly in dry swamps and open moor environments.

  11. COAL GEOLOGY

    2014-01-01

    <正>20141574 Chen Hao(Exploration and Development Research Institute,Daqing Oilfield Company,Daqing 163712,China)High-Resolution Sequences and Coal Accumulating Laws in Nantun Formation of Huhe Lake Sag(Petroleum Geology&Oilfield Development in Daqing,ISSN1000-3754,CN23-1286/TQ,32(4),2013,p.15-19,5 illus.,15 refs.)Key words:coal accumulation regularity,coal

  12. COAL GEOLOGY

    2011-01-01

    <正>20110359 Feng Lijuan(Graduate School,Southwest Petroleum University,Chengdu 610500,China);Guo Dali Experimental Study on the Stress Sensitivity of Coal and Its Impact on the Filtration of the Fracturing Fluid(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,38(2),2010,p.14-17,4 illus.,5 tables,9 refs.)Key words:coal seam,stressIn the paper,the relationship between the stress and permeability in the coal r

  13. Coal - 96

    The report deals mainly with coal consumption, but also gives some information about technology, environmental aspects and markets. Data have been collected by questionnaires or via telephone. The use of steam coal for heating was 0.8 Mtons (down 20% from 1994). Cogeneration plants were the main users. Taxes and environmental reasons cause a reduction of the coal use that will probably continue the next years. Use of steam coal in industry has been constant at a level of 0.7 Mtons. The import of metallurgical coal rests constant at a level of 1.6 Mtons. 1.2 Mtons of coke was produced, and 0.3 Mtons imported. The PFBC-plant at Vaertan, Stockholm used 0.13 Mtons of coal, while some coal fired power plants have been converted to peat and wood fuels. The average price of steam coal imported to Sweden in 1995 was 333 SEK/ton, 6% higher than in 1994. The contract prices for delivery 1996 are about the same as at the end of 1995. All cogeneration plants have some sort of SO2 removal system, mostly wet-dry. The largest plant, at Vaesteraas, has recently invested in a SCR system for NOx removal. Most other plants are using low NOx burners or SNCR systems, based on ammonia or urea, which reduce the emissions 50 - 70%. Some statistic about the world coal market is also given in the report

  14. Coal technology

    The coal- and gas-fueled cogeneration plants develop rapidly and according to all the scenarios will continue to grow with ever improving power generation effect in counterpressure mode. As there is no 'cooling water waste', a greater percentage of houses should be heated electrically. The coal combustion technologies mentioned here will probably converge around 53-55% coefficient of performance. Emission requirements can be fulfilled by use of modern coal technologies. Coal will stay as a competitive fuel for cogeneration as other more advanced technologies are often yet at the demonstration stage. (EG)

  15. Permian and Triassic Sequence Stratigraphy and Sea Level Changes of Eastern Yangtze Platform

    1999-01-01

    The Permian and marine Triassic of eastern Yangtze platform, situated in eastern China, involve 19 orthosequences lasting about 2.7 Ma on average, which can be combined into five orthosequence sets ranging from 8 Ma to 12 Ma. Affected by the regional Dongwu and Indosinian movements, the sequence stratigraphic pattern and sea level changes in the Permian and Triassic of this region are distinctive and obviously different from most other regions in the world, but typical in the broad eastern Tethys and its neighboring areas. In this region not only did the continuous marine Permian and Triassic boundary sequences cause the orthosequence crossing the boundary belonging to type-Ⅱ sequence but also the mesosequence including these stratigraphic intervals had its basal boundary in the upper Longlinian (Artinskian) (ca. 278 Ma), that is, the traditional Carboniferous and Permian boundary, and its top boundary moved from the Permian and Triassic boundary upward into the Anisian of Middle Triassic.

  16. Palynology of Permian Gondwana sequence of Umrer coalfield, Maharashtra

    Jha, N.; Tewari, R.; Rajanikanth, A. [Birbal Sahni Institute of Paleobotany, Lucknow (India)

    2007-04-15

    Quantitative and qualitative palynological analysis of Early Permian sediments, Umrer Coalfield, Wardha Basin has been carried out. The microspore assemblage consists of 22 genera and 40 species. It is characterized by dominance of radial monosaccates chiefly, Parasacciles and subdominance of non-striate disaccates chiefly, Scheuringipollenites. Presence of Crucisaccites and Caheniasaccites suggests Upper Karharbari (Late Sakmarian-Early Artinskian) affinity. The presence of the Karharbari palynozone has been demarcated in lithologically designated Barakar Formation. The present finding corroborates the earlier studies by Bharadwaj and Anand Prakash (1974).

  17. Complete cDNA sequence of human complement C1s and close physical linkage of the homologous genes C1s and C1r

    Overlapping molecular clones encoding the complement subcomponent C1s were isolated from a human liver cDNA library. The nucleotide sequence reconstructed from these clones spans about 85% of the length of the liver C1s messenger RNAs, which occur in three distinct size classes around 3 kilobases in length. Comparisons with the sequence of C1r, the other enzymatic subcomponent of C1, reveal 40% amino acid identity and conservation of all the cysteine residues. Beside the serine protease domain, the following sequence motifs, previously described in C1r, were also found in C1s: (a) two repeats of the type found in the Ba fragment of complement factor B and in several other complement but also noncomplement proteins, (b) a cysteine-rich segment homologous to the repeats of epidermal growth factor precursor, and (c) a duplicated segment found only in C1r and C1s. Differences in each of these structural motifs provide significant clues for the interpretation of the functional divergence of these interacting serine protease zymogens. Hybridizations of C1r and C1s probes to restriction endonuclease fragments of genomic DNA demonstrate close physical linkage of the corresponding genes. The implications of this finding are discussed with respect to the evolution of C1r and C1s after their origin by tandem gene duplication and to the previously observed combined hereditary deficiencies of Clr and Cls

  18. Sequence-stratigraphic frameworks and their palaeogeographic patterns for the Permian Lopingian of the Dianqiangui Basin and its adjacent areas of Southwestern China

    2007-01-01

    The Permian Lopingian in the Dianqiangui Basin and its adjacent areas is marked by the coal measures of the Wuchiapingian and the carbonate strata of the Changhsingian stages. For the Lopingian of the Dianqiangui Basin and its adjacent areas,the diversity of sedimentary facies and the obviousness of facies change provide an advantaged condition on a study of sequence stratigraphy. Approximately,the Wuchiapingian stage constitutes a third-order sequence and the Changhsingian stage forms an-other. For the Wuchiapingian stage in the study area,coal-measures were developed on the attached platform and,in addition,a special coal-measure that is composed of both limestone beds and coal beds was also developed in the central part of some isolated platforms. Grain-bank grainstones and packstones were formed on the margin of the attached platform as well as in the windward part of iso-lated platforms. For the Changhsingian stage in the study area,open-platform limestones were formed on the attached platform,while sponge-reef limestones were developed both on the margin of the at-tached platform and on the isolated platforms. The Lopingian Series is a set of basin-facies muddy shales with interbeds of silicalites in the inter-platform basin,which appears a set of the large-thick coarse clastic strata of molasses covering direct the deep-water strata from the Devonian to the Per-mian Yangsingian in the Qinzhou-Fangcheng region in the southern part of the study area. All of these features indicate the complexity of temporal-spatial facies-changes. Sequence-stratigraphic frame-works could be established,which would illustrate two types of facies-changing surfaces and dia-chronisms in the stratigraphic records,based on the combination of both biostratigraphic and chronostratigraphic materials and the regularity reflected by temporal evolutionary succession of sediments as well as spatial distributional patterns of sedimentary facies. Ultimately,features of sedi

  19. C1-inhibitor (C1-INH) autoantibodies in hereditary angioedema. Strong correlation with the severity of disease in C1-INH concentrate naïve patients.

    Varga, Lilian; Széplaki, Gábor; Visy, Beáta; Füst, George; Harmat, George; Miklós, Katalin; Németh, Julianna; Cervenak, László; Karádi, István; Farkas, Henriette

    2007-02-01

    The presence of autoantibodies to C1-inhibitor (C1-INH-Abs) is a hallmark of acquired C1-inhibitor deficiency. However, only scarce data are available on their prevalence in hereditary angioedema (HAE). In a prospective study performed between 2001 and 2004 in 95 patients with Type I or II HAE, serum samples were taken one to three times a year and clinical status of the patients was registered. Serum samples were tested for total activity of the classical pathway, C1q, C3, C4 and C1-inhibitor (C1-INH) concentration and activity levels, as well as the presence of IgG, IgA and IgM type anti-C1-inhibitor antibodies (C1-INH-Ab). Fifty-four healthy age and gender matched persons served as control. Significant differences between the patients and controls in the occurrence of elevated (2S.D. higher than mean of control) C1-INH-Abs titers was found only in the case of IgM type C1-INH-Abs. Elevated (>4.22AU/ml) IgM C1-INH-Abs levels were found in 31 and 4% of the patients and controls, respectively (p<0.001). Surprisingly, high titer IgM C1-INH-Abs were present with equal frequency in the 41 HAE patients ever treated with C1-INH concentrate and in the 54 C1-INH treatment naïve patients. In the latter group, strong positive correlation between the levels of the IgM C1-INH-Abs and the most severe disease (score 1) (p=0.0021) and the yearly attack rate (p=0.0173) were obtained. In addition, the levels of the IgM C1-INH-Abs exhibited strong negative correlation to the C1-inhibitor concentration and functional activity, total classical complement pathway activity, and a positive correlation to total IgM concentration. Taken together, these data indicate that IgM type C1-INH-Abs are present with highly elevated frequency in HAE patients irrespectively of the previous treatment with C1-INH concentrate. Most probable production of these autoantibodies is the consequence of the activation of complement and other plasma enzyme systems during HAE attacks. Determination of IgM C1

  20. Depositional Environment of Permian Tak Fa Formation, Nakhonsawan, Northern Thailand

    Ketwetsuriya, Chatchalerm; Nützel, Alexander; Kanjanapayont, Pitsanupong

    2016-04-01

    The carbonate rocks of the study area at Amphoe Tak Fa and Amphoe Takhli, Changwat Nakhon Sawan belong to the Tak Fa Formation, Saraburi Group. This formation crops out in the Khao Khwang Platform and consists of late Palaeozoic carbonate platform deposits. It reaches a thickness of 900 meters and crops out in a vast area. The exposures have been measured and samples were collected for petrographic study. The rock consists of limestones, argillaceous limestones, mudstones and dolomites with nodular and banded cherts, which comprise many invertebrate fossils such as fusulinids, ammonoid, pelecypod, gastropod, coral and bryozoa. Many of the fossils are silicified. The gastropod assemblage is currently under study and represents one of the most diverse faunas reported from SE Asia. The age of the rock is Yakhtashian or Artinskian (late Early Permian) to Midian or Capitanian (late Middle Permian). The study of carbonate facies and fauna indicates that the depositional environment was on shelf lagoon within the carbonate platform varying from shallow marine to barrier bar.

  1. Flourishing ocean drives the end-Permian marine mass extinction.

    Schobben, Martin; Stebbins, Alan; Ghaderi, Abbas; Strauss, Harald; Korn, Dieter; Korte, Christoph

    2015-08-18

    The end-Permian mass extinction, the most severe biotic crisis in the Phanerozoic, was accompanied by climate change and expansion of oceanic anoxic zones. The partitioning of sulfur among different exogenic reservoirs by biological and physical processes was of importance for this biodiversity crisis, but the exact role of bioessential sulfur in the mass extinction is still unclear. Here we show that globally increased production of organic matter affected the seawater sulfate sulfur and oxygen isotope signature that has been recorded in carbonate rock spanning the Permian-Triassic boundary. A bifurcating temporal trend is observed for the strata spanning the marine mass extinction with carbonate-associated sulfate sulfur and oxygen isotope excursions toward decreased and increased values, respectively. By coupling these results to a box model, we show that increased marine productivity and successive enhanced microbial sulfate reduction is the most likely scenario to explain these temporal trends. The new data demonstrate that worldwide expansion of euxinic and anoxic zones are symptoms of increased biological carbon recycling in the marine realm initiated by global warming. The spatial distribution of sulfidic water column conditions in shallow seafloor environments is dictated by the severity and geographic patterns of nutrient fluxes and serves as an adequate model to explain the scale of the marine biodiversity crisis. Our results provide evidence that the major biodiversity crises in Earth's history do not necessarily implicate an ocean stripped of (most) life but rather the demise of certain eukaryotic organisms, leading to a decline in species richness. PMID:26240323

  2. Application of Markov chain and entropy analysis to lithologic succession – an example from the early Permian Barakar Formation, Bellampalli coalfield, Andhra Pradesh, India

    Ram Chandra Tewari; D P Singh; Z A Khan

    2009-10-01

    A statistical approach by a modified Markov process model and entropy function is used to prove that the early Permian Barakar Formation of the Bellampalli coal field developed distinct cyclicities during deposition.From results,the transition path of lithological states typical for the Bellampalli basin is as:coarse to medium-grained sandstone → interbedded fine-grained sandstone/shale → shale → coal and again shale.The majority of cycles are symmetrical but asymmetrical cycles are present as well.The chi-square stationarity test implies that these cycles are stationary in space and time.The cycles are interpreted in terms of in-channel,point bar and overbank facies association in a fluvial system.The randomness in the occurrence of facies within a cycle is evaluated in terms of entropy,which can be calculated from the Markov matrices.Two types of entropies are calculated for every facies state;entropy after deposition (post)and entropy before deposition (pre),which together form entropy set;the entropy for the whole system is also calculated.These values are plotted and compared with Hattori ’s idealized plots,which indicate that the sequence is essentially a symmetrical cycle (type-B of Hattroi). The symmetrical cyclical deposition of early Permian Barakar Formation is explained by the lateral migration of stream channels in response to varying discharge and rate of deposition across the alluvial plain.In addition,the fining upward cycles in the upper part enclosing thick beds of fine clastics,as well as coal may represent differential subsidence of depositional basin.

  3. Studies on Parataxospermum taiyuanensis gen. et sp. nov. from coal balls

    Li, Z.M. (Academia Sinica, Beijing (China). Institute of Botany)

    1993-05-03

    This paper reports on a new genus and a new species of the Order Cardiocarpales, Parataxospermum taiyuanensis gen. et sp. nov., which is described from coal balls of the Upper Carboniferous (or lower Permian) in the Shanxi Province, China. The taxon is described and its taxonomic position and affinities are discussed in detail. In addition, a three-dimensional reconstruction technique using computer graphics is utilized to reconstruct external images of the seeds.

  4. Coal Rank and Stratigraphy of Pennsylvanian Coal and Coaly Shale Samples, Young County, North-Central Texas

    Guevara, Edgar H.; Breton, Caroline; Hackley, Paul C.

    2007-01-01

    Vitrinite reflectance measurements were made to determine the rank of selected subsurface coal and coaly shale samples from Young County, north-central Texas, for the National Coal Resources Database System State Cooperative Program conducted by the Bureau of Economic Geology at The University of Texas at Austin. This research is the continuation of a pilot study that began in adjacent Archer County, and forms part of a larger investigation of the coalbed methane resource potential of Pennsylvanian coals in north-central Texas. A total of 57 samples of coal and coaly shale fragments were hand-picked from drill cuttings from depths of about 2,000 ft in five wells, and Ro determinations were made on an initial 10-sample subset. Electric-log correlation of the sampled wells indicates that the collected samples represent coal and coaly shale layers in the Strawn (Pennsylvanian), Canyon (Pennsylvanian), and Cisco (Pennsylvanian-Permian) Groups. Coal rank in the initial sample subset ranges from lignite (Ro=0.39), in a sample from the Cisco Group at a depth of 310 to 320 ft, to high volatile bituminous A coal (Ro=0.91) in a sample from the lower part of the Canyon Group at a depth of 2,030 to 2,040 ft.

  5. COAL GEOLOGY

    2011-01-01

    <正>20111830 Cai Hou’an(State Key Laboratory of Coal Resources and Safety Mining,China University of Mining and Technology,Beijing 100083,China);Xu Debin The Discovery of Thrust Nappe Structure in Zhangwu-Heishan Area,Liaoning Province and Its Significance for Coal-Searching(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,38(5),2010,p.1-6,5 illus.,31 refs.)Key words:coalfield prediction,nappe structure,Liaoning Province Zhangwu-Heishan area in west Liaoning Province is an important perspective area for alternative resources in the periphery of Fuxin Basin.Based on r

  6. COAL GEOLOGY

    2012-01-01

    <正>20122522 Guo Dongxin ( School of Energy Resource,China University of Geosciences,Bei-jing 100083,China );Tang Shuheng Sequence Strata and the Coal Accumulation of Wunite Coafield,Inner Mongolia ( Coal Geology & Exploration,ISSN1001-1986,CN61-1155 / P,39 ( 6 ), 2011,p.1-5,5illus.,16refs. ) Key words:sequence stratigraphy,coal accumulation regularity,Inner Mongolia Based on the study of the stratigraphy sequence of the Bayanhua Formation of Lower Cretaceous in Wunite coafield ,

  7. The Cathaysia Flora and the Mixed Late Permian Cathaysian-Angaran Floras in East Asia

    2006-01-01

    The Cathaysia flora, one of the most prominent floras of the Carboniferous and Permian, was mainly distributed in East Asia and was characterized by numerous endemic elements. China is one of the most important localities of the Cathaysia flora and it is also the center of origin of this flora. This paper reviews and discusses the characteristics of the Cathaysia flora and the biogeographically mixed Permian Cathaysian-Angaran floras of East Asia. In addition, the formative mechanism of the mixed Permian floras is also discussed.

  8. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  9. Climate, decay, and the death of the coal forests.

    Hibbett, David; Blanchette, Robert; Kenrick, Paul; Mills, Benjamin

    2016-07-11

    After death, most of the biological carbon in organisms (Corg) is returned to the atmosphere as CO2 through the respiration of decomposers and detritivores or by combustion. However, the balance between these processes is not perfect, and when productivity exceeds decomposition, carbon sequestration results. An unparalleled interval of carbon sequestration in Earth's history occurred during the Late Carboniferous (Pennsylvanian) and Permian Periods (ca. 323-252 Ma), when arborescent vascular plants related to living club mosses (Lycophytes), ferns (Monilophytes), horsetails (Equisetophytes) and seed plants (Spermatophytes) formed extensive forests in coastal wetlands. On their death, these plants became buried in sediments, where they transformed into peat, lignite, and, finally, coal. PMID:27404250

  10. Interaction between complement subcomponent C1q and bacterial lipopolysaccharides.

    Zohair, A; Chesne, S; Wade, R H; Colomb, M G

    1989-02-01

    The heptose-less mutant of Escherichia coli, D31m4, bound complement subcomponent C1q and its collagen-like fragments (C1qCLF) with Ka values of 1.4 x 10(8) and 2.0 x 10(8) M-1 respectively. This binding was suppressed by chemical modification of C1q and C1qCLF using diethyl pyrocarbonate (DEPC). To investigate the role of lipopolysaccharides (LPS) in this binding, biosynthetically labelled [14C]LPS were purified from E. coli D31m4 and incorporated into liposomes prepared from phosphatidylcholine (PC) and phosphatidylethanolamine (PE) [PC/PE/LPS, 2:2:1, by wt.]. Binding of C1q or its collagen-like fragments to the liposomes was estimated via a flotation test. These liposomes bound C1q and C1qCLF with Ka values of 8.0 x 10(7) and 2.0 x 10(7) M-1; this binding was totally inhibited after chemical modification of C1q and C1qCLF by DEPC. Liposomes containing LPS purified from the wild-strain E. coli K-12 S also bound C1q and C1qCLF, whereas direct binding of C1q or C1qCLF to the bacteria was negligible. Diamines at concentrations which dissociate C1 into C1q and (C1r, C1s)2, strongly inhibited the interaction of C1q or C1qCLF with LPS. Removal of 3-deoxy-D-manno-octulosonic acid (2-keto-3-deoxyoctonic acid; KDO) from E. coli D31m4 LPS decreases the binding of C1qCLF to the bacteria by 65%. When this purified and modified LPS was incorporated into liposomes, the C1qCLF binding was completely abolished. These results show: (i) the essential role of the collagen-like moiety and probably its histidine residues in the interaction between C1q and the mutant D31m4; (ii) the contribution of LPS, particularly the anionic charges of KDO, to this interaction. PMID:2649081

  11. Calculating eustatic amplitude of Middle Permian from reefs

    WU; Yasheng; (吴亚生); FAN; Jiasong; (范嘉松)

    2002-01-01

    Methods for calculating ancient eustatic change amplitudes according to reef fabric- facies are proposed, with a new method for determining sediment-loading subsidence. Compared with methods based on non-reefal deposits, these methods are more accurate in restoration of original sediment thickness, determination of sediment-loading subsidence, as well as restoration of ancient water depth. According to the reef in Guangxi, China, the amplitude of sea-level rise during Middle Permian (Neoschwagerina-Yabeina zone) is 249.5 m. According to the coeval reef of the Guadalupe Mountains, New Mexico and Texas, the coeval sea-level rise is 247 m. With these effective methods available, it is feasible to establish more accurate eustatic curve of Phanerozoic.

  12. Ocean redox change at the Permian-Triassic mass extinction

    Ruhl, Micha; Bjerrum, Christian J.; Canfield, Donald Eugene; Stemmerik, Lars

    (anoxic but not euxinic) coinciding with the main extinction event. Molybdenum enrichments, often indicative for freely available sulfide in the water-column, only occur dur¬ing the second phase of euxinia. This pattern of ocean redox-change in Svalbard direct¬ly reflects similar trends in Greenland and...... ocean redox change over the largest mass extinction event in Earth history, at the Permian-Tri¬assic boundary (at ~252 Ma). This event is marked by a major perturbation in the global exogenic carbon cycle (and associated major negative carbon isotope excursion (CIE)), likely initiated by carbon...... oceanographic changes to similar observations for the Triassic-Jurassic mass extinction and discuss environmental forcing, poten¬tially inherent to major volcanic events and leading to global environmental change and extinction...

  13. Mg Isotopes of the Late Permian Evaporites, New Mexico, USA

    Feng, C.; Gao, C. H.; Chang, S. C.

    2015-12-01

    Mg isotope holds promise to decipher the evaporative environment of evaporites. High-precision Mg isotope compositions of the late Permian langbeinites have been measured by using MC-ICPMS. The equilibrium Mg isotope fractionation factor between langbeinite and aqueous Mg2+ solutions has been determined using quantum chemistry calculations. All computations are employed at B3LYP/6-311++G(2d,2p) level and solvation effects are treated by solvent model ("water-droplet" approach), mineral structures are constructed using volume variable cluster models (VVCM). The Mg isotope compositions of the langbeinite samples, whose total formation thickness ranges up to 100 meters, are extremely isotopically lighter than that of modern seawater and relatively homogeneous (δ26MgDSM3 is from -4.12±0.03‰ to -3.81±0.07‰ v.s. -0.83‰ of modern seawater). The computed equilibrium Mg isotope fractionation factors between langbeinite and aqueous Mg2+ solutions are -2.73‰, -2.66‰ and -2.53‰ at 25, 30 and 40 ℃, respectively. These significant equilibrium fractionation factors indicate that a huge equilibrium Mg isotope fractionation between langbeinite and its parent brine can happen during langbeinite depositions, and langbeinites are enriched in isotopically light 24Mg comparing to the brine. Using the computed fractionation factors to simulate a Rayleigh fractionation process of langbeinite Mg precipitation, we find that a significant Mg isotope difference between langbeinite and its growing brine (seawater) is indeed present but the Mg isotope composition of langbeinite merely increase monotonically in a closed system. Because of that, the homogenous Mg isotope compositions of such a thick evaporite sequence suggest a disequlibrium effect rather than an equilibrium Mg isotope fractionation behavior during its formation. Combined with its prevailing Mg-bearing character, the homogenous Mg isotope compositions reveal that this the late Permian langbeinite sequence has

  14. Shadowing and Inverse Shadowing for C1 Endomorphisms

    Yu Jun ZHU; Jin Lian ZHANG; Lian Fa HE

    2006-01-01

    In this paper, we consider the shadowing and the inverse shadowing properties for C1 endomorphisms. We show that near a hyperbolic set a C1 endomorphism has the shadowing property, and a hyperbolic endomorphism has the inverse shadowing property with respect to a class of continuous methods. Moreover, each of these shadowing properties is also "uniform" with respect to C1 perturbation.

  15. Coal -98

    The following report deals with the use of coal and coke during 1997. Some information about technic, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from SCB have also been used. The use of steam coal for heating purposes during 1997 was 730 000 tons and about 500 000 tons lower than in 1996. The extremely high figures of 1996 were due to twice the production of electricity because of lack of hydro power. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. Some foreign analysts, however, estimate a doubled use of coal for energy use after 2020 because of the plans to phase out the nuclear power. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. 1997 these figures are 2 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1997 was 1.6 mill tons like the year before. 1.2 mill tons coke were produced. The coke consumption in the industry was 1.5 Mill tons. 0.3 mill tons of coke were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has plans to build a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has taken a fluid bed boiler for different fuels in operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm

  16. Coal 99

    The following report deals with the use of coal and coke during 1998. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used. The use of steam coal for heating purposes during 1998 was 680 000 tons and somewhat lower than in 1997. The extremely high figures of 1996 were due to twice the production of electricity because of lack of waterpower. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. During 1998 these figures are 1 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. Steel-works, however, increase their use of steam coal in order to replace the more expensive coke. The import of metallurgical coal in 1998 was 1.6 mill tons like the year before. 1.1 mill tons of coke were produced. The coke consumption in the industry was 1.4 mill tons from which 0.3 mill tons were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has ordered a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has put a fluid bed boiler for various fuels into operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm Energi, Haesselbyverket, has invested

  17. Revisiting the mechanism of the autoactivation of the complement protease C1r in the C1 complex: structure of the active catalytic region of C1r.

    Kardos, József; Harmat, Veronika; Palló, Anna; Barabás, Orsolya; Szilágyi, Katalin; Gráf, László; Náray-Szabó, Gábor; Goto, Yuji; Závodszky, Péter; Gál, Péter

    2008-03-01

    C1r is a modular serine protease which is the autoactivating component of the C1 complex of the classical pathway of the complement system. We have determined the first crystal structure of the entire active catalytic region of human C1r. This fragment contains the C-terminal serine protease (SP) domain and the preceding two complement control protein (CCP) modules. The activated CCP1-CCP2-SP fragment makes up a dimer in a head-to-tail fashion similarly to the previously characterized zymogen. The present structure shows an increased number of stabilizing interactions. Moreover, in the crystal lattice there is an enzyme-product relationship between the C1r molecules of neighboring dimers. This enzyme-product complex exhibits the crucial S1-P1 salt bridge between Asp631 and Arg446 residues, and intermolecular interaction between the CCP2 module and the SP domain. Based on these novel structural information we propose a new split-and-reassembly model for the autoactivation of the C1r. This model is consistent with experimental results that have not been explained adequately by previous models. It allows autoactivation of C1r without large-scale, directed movement of C1q arms. The model is concordant with the stability of the C1 complex during activation of the next complement components. PMID:17996945

  18. Characteristics and exploration prospects of Middle Permian reservoirs in the Sichuan Basin

    Guang Yang

    2015-11-01

    Full Text Available In recent years, encouraging progress has been made in the Middle Permian natural gas exploration in the Sichuan Basin – numerous wells have obtained high-yield industrial gas flows in the dolomite porous reservoir sections in the Middle Permian Maokou Formation and the Qixia Formation, making the Middle Permian one of the most realistic replacement strata at present. In order to clarify the further exploration prospect of the basin, the Middle Permian depositional settings and prospective reservoir types were analyzed. The results show that: (1 the depositional environment was predominately open, shallow water; the paleogeomorphology was high in the west and low in the east, with bioclastic flat reservoirs more extensive in the middle-west part than the east part; crustal extension made Middle Permian deposits have good conditions for thermal water deposition and hydrothermal alteration; and (2 the prospect reservoirs for exploration were shoal facies dolomite porous reservoir of the Qixia Formation, thermal water dolomite porous reservoir and karst reservoir of the Maokou Formation, thus, dolomite porous reservoir was the most perspective target in the Middle Permian. It is concluded that Middle Permian limestone source rocks have large hydrocarbon generation intensity in the northern part of Western and Central Sichuan Basin and have the material basis for the formation of large-medium gas fields; the thick dolomite reservoir of the Qixia Formation in the Western Sichuan Basin is the most prospective reservoir in the Middle Permian; three types of reservoirs are distributed in the Central Sichuan Basin, and they are superimposed vertically with large exploration potential; Jiange–Nanchong–Fengdu region is located in the thermal sub-basin zone, where the thermal water dolomite reservoir of the Maokou formation is pervasive and superimposed on the karst reservoir of the Maokou Formation, showing good natural gas exploration prospects.

  19. Coal 95

    The report deals with the use of coal and coke in Sweden during 1994. Some information about technology, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used.The use of steam coal for heating purposes has been unchanged during 1994 at a level of 1 Mtons. The production in the cogeneration plants has been constant, but has increased for electricity production. The minor plants have increased their use of forest fuels. The use of steam coal will probably go down in the next years both for heat and cogeneration plants. During the top year 1987 coal was used in 18 hot water and 11 cogeneration plants. 1994 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in industry has been constant at the level 0.7 Mtons. The import of metallurgical coal in 1993 was 1.6 Mtons, like 1992. Import of 0.3 Mtons of coke gives the total consumption of coke in industry as 1.5 Mtons. the average price of steam coal imported to Sweden was 317 SEK/ton, 3% higher than 1993. All Swedish plants meet their emission limit of dust, SO2 and NOx as given by county administrations or concession boards. The cogeneration plants all have some SO2 removal system. The biggest cogeneration plant (Vaesteraas) has recently invested in a SCR NOx cleaning system. Most other plants use low NOx burners or SNR injection systems based on ammonia or urea. 2 figs, 13 tabs

  20. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    Olsen, D.K.; Johnson, W.I.

    1993-05-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10'' to 20'' API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area.

  1. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    Olsen, D.K.; Johnson, W.I.

    1993-05-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10`` to 20`` API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area.

  2. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10'' to 20'' API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area

  3. COAL GEOLOGY

    2009-01-01

    <正>20091749 Cai Hou’an(College of Energy Geology,China University of Geosciences,Beijing 100083,China);Xu Debin SHRIMP U-Pb Isotope Age of Volcanic Rocks Distributed in the Badaohao Area,Liaoning Province and Its Significance(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,36(4),2008,p.17-20,2 illus.,1 table,16 refs.)Key words:coal measures,volcanic rocks,U-Pb dating,LiaoningA set of andesite volcanic rocks distributes in the Badaohao area in Heishan County,Liaoning Province.It’s geological age and stratigraphy sequence relationship between the Lower Cretaceous Badaohao Formation and the volcanic rocks can not make sure till now and is influencing the further prospect for coals.Zircon

  4. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  5. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

  6. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  7. Characterization of an Upper Permian tight aas reservoir : a multidisciplinary, multiscale analysis from the Rotliegend, Northern Germany

    Antrett, Philipp

    2011-01-01

    This thesis describes a multidisciplinary, multiscale approach to the analysis of tight gas reservoirs. It focused initially on the facies architecture of a Permian tight gas field in the Southern Permian Basin (SPB), East Frisia, Northern Germany. To improve field development, 3D seismic data, wireline and core data were compared to a reservoir analogue in the Panamint Valley, California, United States. Depositional environments of the Permian Upper Rotliegend II included perennial saline la...

  8. Content of arsenic, selenium, mercury in the coal, food, clay and drinking water on the Zhaotong fluorosis area, eastern Yunnan Province

    Luo Kun-li; Li Hui-jie; Chen Tong-bin (and others) [Chinese Academy of Sciences, Beijing (China). Institute of Geographic Sciences and Natural Resources Research

    2008-03-15

    About 160 samples of coal, corn, capsicum and drinking water were collected from the endemic fluorosis area of Zhenxiong and Weixin County, Zhaotong City of Yunnan Province, to determine the arsenic (As), selenium (Se) and mercury (Hg) content by AAF-800. The study found that the As content in the main coal seam from the Late Permian coal mines in Zhaotong City is 8.84 mg/kg and some civil coal can reach 89.09 mg/kg. The Se and Hg in the coal samples of Late Permian is lower, but Se and Hg are more concentrated in the pyritic coal balls and the pyritic gangue of the coal seam. The As content in corn and capsicum dried by coal-burning is more than 0.7 mg/kg, the natural standard amount of arsenic content permitted in food by China. The Se and Hg content in corn dried by coal-burning is lower than the natural standard of Se and Hg content in food in China but the Se and Hg content of capsicum dried by coal-burning exceeds the amount permitted by the natural standard for food in China. Clay, used as an additive for the coal-burning process and as a binder in making briquettes, contains a high content of As, generally more than 16 mg/kg. However, the Se and Hg content of clay itself are low. The As, Se and Hg content of drinking water are lower than the natural standard of As, Se and Hg content in the drinking water. So, there is high-As content coal and high-As content dried corn and capsicum in the endemic fluorosis area of Zhaotong City of Yunnan Province. The high As content of the dried corn and capsicum might have originated from the high arsenic content of burnt coal and clay. 30 refs., 4 tabs.

  9. Grain-rimming kaolinite in Permian Rotliegend reservoir rocks

    Waldmann, Svenja; Gaupp, Reinhard

    2016-04-01

    Upper Rotliegend sediments of Permian age from the northeast Netherlands show moderate to good reservoir qualities. The predominant control is by the presence of authigenic grain-rimming kaolinite, which has a negative, but in some parts also a positive, effect on reservoir quality. To better understand the formation and distribution of grain-rimming kaolinite, reservoir rocks were studied in terms of composition and diagenetic processes. Petrographic evidence, summarized as a paragenetic sequence, is integrated with geochemical modeling results to identify early mesodiagenetic water-rock interactions under the participation of gases, i.e., CO2 and H2S, released from underlying Carboniferous source rocks. The sediments investigated were deposited at varying distance from the southern flank of the Southern Permian Basin. Sediments near the basin margin are mainly attributed to a fluvial environment and comprise medium to coarse-grained sandstones and conglomerates. There, vermicular kaolinite occurs with a lath-like structure. Distal to the basin margin, mainly in sandstones intercalated with fine-grained playa sediments, comparatively high amounts of grain-rimming kaolinite occur. There, the presence of this mineral has a significant influence on the rock properties and the reservoir quality. Geochemical modeling suggests that the formation of such kaolinites cannot be explained exclusively by in situ feldspar dissolution. The modeling results support evidence that kaolinite can be formed from precursor clay minerals under the presence of CO2-rich formation waters. Such clay minerals could be corrensite, smectite-chlorite mixed-layer minerals, or chlorite that is potentially present in Rotliegend sediments during early diagenesis. Furthermore, the geochemical modeling can reflect several mineral reactions that were identified from petrographic analysis such as the formation of illite and kaolinite at the expense of feldspar dissolution and consequent silica

  10. Raining lead around 250mya a smoking gun for an Australian impact origin of the Permian Extinction

    Standard, J C

    2003-01-01

    Recent documentation of extreme atmospheric sulfur and methane contents at the time of the vast Permo-Triassic (P-T) extinction makes it possible to interpret an observation that has lain unnoticed in the geological literature for 40 years. This is the finding of microscopic metallic lead tear drops in the fluvial strata of the early Triassic sandstones that overlie Permian coal beds and other sedimentary deposits in the Sydney basin of Australia. Elemental lead is almost unknown in nature, so its occurrence in these graphite-loaded sandstones is a provocative finding. While climate change and vulcanism could explain the carbon and sulfur anomalies, the only way to account for metallic lead aerodynamic droplets is by massive impact and vaporization of lead mineral-containing formations. Since lead occurs geologically as the sulfide and since lead is an easily reduced element, its occurrence in conjunction with sulfur and carbon count anomalies suggests a bolide impact on carbon-loaded strata in a sulfide mine...

  11. Anti-C1q antibodies in systemic lupus erythematosus

    Orbai, A-M; Truedsson, L; Sturfelt, G;

    2015-01-01

    OBJECTIVE: Anti-C1q has been associated with systemic lupus erythematosus (SLE) and lupus nephritis in previous studies. We studied anti-C1q specificity for SLE (vs rheumatic disease controls) and the association with SLE manifestations in an international multicenter study. METHODS: Information...... serologies. Anti-C1q in combination with anti-dsDNA and low complement was the strongest serological association with renal involvement. These data support the usefulness of anti-C1q in SLE, especially in lupus nephritis....

  12. Hereditary angioedema with normal C1-INH (HAE type III).

    Riedl, Marc A

    2013-01-01

    Hereditary angioedema (HAE) with normal C1 inhibitor (C1-INH), also known as HAE type III, is a familial condition only clinically recognized within the past three decades. Similar to HAE from C1-INH deficiency (HAE types I and II), affected individuals experience unpredictable angioedema episodes of the skin, gastrointestinal tract, and airway. Unique clinical features of HAE with normal C1-INH include the predominance of affected women, frequent exacerbation by estrogen, and a prominence of angioedema that involves the face and oropharynx. The underlying pathophysiology of HAE with normal C1-INH is poorly understood, but indirect evidence points to contact pathway dysregulation with bradykinin-mediated angioedema. Currently, evaluation is complicated by a lack of confirmatory laboratory testing such that clinical criteria must often be used to make the diagnosis of HAE with normal C1-INH. Factor XII mutations have been identified in only a minority of persons affected by HAE with normal C1-INH, limiting the utility of such analysis. To date, no controlled clinical studies have examined the efficacy of therapeutic agents for HAE with normal C1-INH, although published evidence supports frequent clinical benefit with medications shown effective in HAE due to C1-INH deficiency. PMID:24565612

  13. Origin of banded structure and coal lithotype cycles in Kargali coal seam of East Bokaro sub-basin, Jharkhand, India: Environmental implications

    Ram Chandra Tewari; Zahid A Khan

    2015-04-01

    The Kargali seam of Early Permian Barakar cyclothems of East Bokaro sub-basin of Jharkhand, India is 12–30 m thick, splits into two parts, and extends throughout the length of the basin. It is made up of interbedded sequences and variable proportions of Vitrain, Clarain, Durain and Fusain. Application of embedded Markov chain model rejects the phenomenon of randomness in the repetition of coal lithotypes. The preferential upward transition path for coal lithotypes that can be derived for the Kargali top coal seam is: Vitrain → Clarain → Durain ↔ Fusain → Vitrain, and for the Kargali bottom coal seam is: Clarain ↔ Vitrain → Fusain → Durain → Clarain. By and large, the cyclic repetition of coal lithotypes is similar in the Kargali bottom and top seams. Among the noteworthy features are two-way transitions between Durain and Fusian in Kargali top and between Clarain and Vitrain in the case of Kargali bottom coal seam. Entropy analysis corroborates Markov chain and indicates the presence of type A-4 asymmetrical cycles of coal lithotypes. It is suggested that the banded structure of a coal seam is not a random feature and follows a definite cyclic pattern in the occurrence of coal lithotypes in vertical order and is similar to that described in Australian and European coal seams. Asymmetrical cyclic sequences are a normal, rather than an unusual condition, within coal seams. It is visualized that a gradual decline of toxic environment and ground water level resulted in the coal lithotype cycles in the Kargali seam of East Bokaro sub-basin. The close interbedding of Vitrain and Clarain is suggestive of seasonal fluctuation in anaerobic and aerobic conditions during peat formation.

  14. An Early Permian fusuline fauna from southernmost Peninsular Thailand: Discovery of Early Permian warming spikes in the peri-Gondwanan Sibumasu Block

    Ueno, Katsumi; Arita, Michiko; Meno, Satomi; Sardsud, Apsorn; Saesaengseerung, Doungrutai

    2015-05-01

    An Early Permian fusuline fauna is reported from the Tarn To Formation of the Yala area in southernmost Peninsular Thailand, which geotectonically belongs to the peri-Gondwanan Sibumasu Block. The fauna consists of Pseudofusulina and Praeskinnerella? species, including forms closely resembling Tethyan and Panthalassan Pseudofusulina fusiformis and Pseudofusulina ex gr. kraffti. A Yakhtashian-Bolorian age is estimated for this fauna. In Sibumasu, shallow-marine biotas showing similar Tethyan affinities, such as the fusulines Misellina and alatoconchid bivalves, also occur in the Early Permian succession of the Kinta Valley area in western Peninsular Malaysia. These unusual Tethyan faunas within Early Permian peri-Gondwanan fossil records suggest episodic influences from paleo-tropical Tethyan biotas. They are here interpreted as showing short-term warming spikes during the late Yakhtashian-Bolorian transgression, which would facilitate sporadic migration and temporal inhabitation of warm-water dwellers into the eastern Cimmerian areas. The Yala and Kinta Valley fusuline and other invertebrate faunas would give us a new insight for the Permian geohistory and environmental change of the peri-Gondwanan Sibumasu Block.

  15. Coal Mines Security System

    Ankita Guhe; Shruti Deshmukh; Bhagyashree Borekar; Apoorva Kailaswar; Milind E. Rane

    2012-01-01

    Geological circumstances of mine seem to be extremely complicated and there are many hidden troubles. Coal is wrongly lifted by the musclemen from coal stocks, coal washeries, coal transfer and loading points and also in the transport routes by malfunctioning the weighing of trucks. CIL —Coal India Ltd is under the control of mafia and a large number of irregularities can be contributed to coal mafia. An Intelligent Coal Mine Security System using data acquisition method utilizes sensor, auto...

  16. Extremely acid Permian lakes and ground waters in North America

    Benison, K.C.; Goldstein, R.H.; Wopenka, B.; Burruss, R.C.; Pasteris, J.D.

    1998-01-01

    Evaporites hosted by red beds (red shales and sandstones), some 275-265 million years old, extend over a large area of the North American mid- continent. They were deposited in non-marine saline lakes, pans and mud- flats, settings that are typically assumed to have been alkaline. Here we use laser Raman microprobe analyses of fluid inclusions trapped in halites from these Permian deposits to argue for the existence of highly acidic (pH lakes and ground waters. These extremely acidic systems may have extended over an area of 200,000 km2. Modern analogues of such systems may be natural acid lake and groundwater systems (pH ~2-4) in southern Australia. Both the ancient and modern acid systems are characterized by closed drainage, arid climate, low acid-neutralizing capacity, and the oxidation of minerals such as pyrite to generate acidity. The discovery of widespread ancient acid lake and groundwater systems demands a re-evaluation of reconstructions of surface conditions of the past, and further investigations of the geochemistry and ecology of acid systems in general.

  17. Simulated warm polar currents during the middle Permian

    Winguth, A.M.E.; Kutzbach, J.E. [Wisconsin Univ., Madison, WI (USA). Center for Climatic Research; Heinze, C.; Maier-Reimer, E.; Mikolajewicz, U. [Max-Planck-Institut fuer Meteorologie, Hamburg (Germany); Rowley, D.; Rees, A.; Ziegler, A.M. [Chicago Univ., IL (United States). Dept. of Geophysical Sciences

    2001-05-01

    During Permian Stage 6 (Wordian, Kazanian) the Pangaean supercontinent was surrounded by a superocean - Panthalassa. An ocean general circulation model has been coupled to an atmospheric energy balance model to simulate the sensitivity of the Wordian climate ({proportional_to}265 million years ago) to changes in greenhouse gas concentrations, high latitude geography, and Earth orbital configurations. The model shows a high sensitivity of the ocean circulation to changes in the greenhouse gas forcing, ranging from a forceful southern circulation at low CO{sub 2} concentration (present level) to a more symmetric circulation cell with deep water formation in both hemispheres at high CO{sub 2} concentration (8 x present level). The simulated climate with 4 x present level CO{sub 2} concentration agrees generally well with climate-sensitive sediments and phytogeographic patterns. In this experiment, the model simulates strong subtropical gyres with similarities to the modern South Pacific circulation and moderate surface temperatures on the southern continent Gondwana, resulting from a strong poleward heat transport in the ocean. An even more moderate climate can be generated if high latitude land is removed so that ocean currents can penetrate into the polar regions or if orbital configurations favor high summer insolation over Gondwana. (orig.)

  18. Electrokinetic transport behavior of phenol in upper Permian soils

    Haus, R.; Zorn, R.; Czurda, K.; Ruthe, H. [Dept. of Applied Geology, Univ. Karlsruhe (Germany)

    2001-07-01

    Electrokinetic experiments with upper Permian, phenol contaminated soils ('Solaris'-area Chemnitz) were performed. Bench scale results show the successful removal of phenol. The developing soil-pH during electroremediation tests is found to affect the transport behavior of phenol strongly. If buffer solutions are used at the electrode compartments, phenol could be removed from the soils. By neutralizing the generating hydrogen ions at the anode reservoir the hydroxyl ions developing at the cathode by the electrolysis of water enter the soil and propagate to the anode by increasing the soil pH. The pH dependent dehydroxylation of phenol promotes the electromigration of negative charged phenolate ions from the cathode to the anode. At the anode the coupling of phenoxyl-radicals supports the formation of non toxic, water insoluble polyoxyphenylene by electro-polymerization. In the case of buffering the pH at the cathode uncharged phenol is transported by electroosmosis from the anode to the cathode because of the nonexisting base front and the unhindered production of hydrogen ions at the anode. (orig.)

  19. Did the Middlesboro, Kentucky, bolide impact event influence coal rank?

    Hower, J.C.; Greb, S.F.; Kuehn, K.W.; Eble, C.F.

    2009-01-01

    The Middlesboro Basin, southeastern Kentucky, occurs on the Cumberland Overthrust Sheet and includes a ca. 5.5-km diameter impact structure. The Lower and Middle Pennsylvanian coal-bearing strata are faulted, with some evidence for shock metamorphism. The event post-dated the latest-Pennsylvanian-early-Permian thrusting and was likely prior to late-Mesozoic entrenchment of drainages. The impact of a 0.5-km meteor traveling at ca. 60,000??km/h would release about 1??EJ, the approximate equivalent of the instantaneous combustion of 30??Mt of coal. The coal rank, while increased slightly above the regional level, still is within the upper portion of the high volatile A bituminous rank range. This helps to constrain the depth of burial at the time of the impact. The coal would have had to have been at a depth of a few kilometers to have avoided a more substantial rank increase. In addition, it is possible that some of the coal rank increase might be attributable to movements along the cross-cutting Rocky Face fault, unrelated to the impact. ?? 2009 Elsevier B.V. All rights reserved.

  20. 26 CFR 31.3402(c)-1 - Wage bracket withholding.

    2010-04-01

    ... 26 Internal Revenue 15 2010-04-01 2010-04-01 false Wage bracket withholding. 31.3402(c)-1 Section... SOURCE Collection of Income Tax at Source § 31.3402(c)-1 Wage bracket withholding. (a) In general. (1) The employer may elect to use the wage bracket method provided in section 3402(c) instead of...

  1. Anti-C1q in systemic lupus erythematosus.

    Stojan, G; Petri, M

    2016-07-01

    C1q is the first component of the classical complement pathway. Both clinically validated in-house ELISA assays as well as commercial ELISA kits are used for detection of anti-C1q antibodies. Anti-C1q autoantibodies can be detected in a wide range of autoimmune diseases and are highly sensitive for hypocomplementemic uticarial vasculitis. In SLE, anti-C1q are strongly associated with proliferative lupus nephritis, and their absence carries a negative predictive value for development of lupus nephritis of close to 100%. Anti-C1q in combination with anti-dsDNA and low complement has the strongest serological association with renal involvement. The anti-C1q titers correlate with global disease activity scores in patients with renal involvement, and higher titers seem to precede renal flares. After the successful treatment of a renal flare, anti-C1q has the tendency to decrease or even become undetectable. The main obstacle to the inclusion of anti-C1q in the classification criteria and clinical management of SLE is the lack of standardized laboratory assays. PMID:27252264

  2. Bioessential element-depleted ocean following the euxinic maximum of the end-Permian mass extinction

    Takahashi, Satoshi; Yamasaki, Shin-ichi; Ogawa, Yasumasa; Kimura, Kazuhiko; Kaiho, Kunio; Yoshida, Takeyoshi; Tsuchiya, Noriyoshi

    2014-05-01

    We describe variations in trace element compositions that occurred on the deep seafloor of palaeo-superocean Panthalassa during the end-Permian mass extinction based on samples of sedimentary rock from one of the most continuous Permian-Triassic boundary sections of the pelagic deep sea exposed in north-eastern Japan. Our measurements revealed low manganese (Mn) enrichment factor (normalised by the composition of the average upper continental crust) and high cerium anomaly values throughout the section, suggesting that a reducing condition already existed in the depositional environment in the Changhsingian (Late Permian). Other redox-sensitive trace-element (vanadium [V], chromium [Cr], molybdenum [Mo], and uranium [U]) enrichment factors provide a detailed redox history ranging from the upper Permian to the end of the Permian. A single V increase (representing the first reduction state of a two-step V reduction process) detected in uppermost Changhsingian chert beds suggests development into a mildly reducing deep-sea condition less than 1 million years before the end-Permian mass extinction. Subsequently, a more reducing condition, inferred from increases in Cr, V, and Mo, developed in overlying Changhsingian grey siliceous claystone beds. The most reducing sulphidic condition is recognised by the highest peaks of Mo and V (second reduction state) in the uppermost siliceous claystone and overlying lowermost black claystone beds, in accordance with the end-Permian mass extinction event. This significant increase in Mo in the upper Changhsingian led to a high Mo/U ratio, much larger than that of modern sulphidic ocean regions. This trend suggests that sulphidic water conditions developed both at the sediment-water interface and in the water column. Above the end-Permian mass extinction horizon, Mo, V and Cr decrease significantly. On this trend, we provide an interpretation of drawdown of these elements in seawater after the massive element precipitation event

  3. Coal industry annual 1997

    NONE

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  4. Coal industry annual 1997

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs

  5. Coal Industry Annual 1995

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995

  6. Coal Industry Annual 1995

    NONE

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  7. Coal industry annual 1996

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs

  8. Coal industry annual 1996

    NONE

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  9. Two pulses of oceanic environmental disturbance during the Permian-Triassic boundary crisis

    Shen, Jun; Feng, Qinglai; Algeo, Thomas J.; Li, Chao; Planavsky, Noah J.; Zhou, Lian; Zhang, Mingliang

    2016-06-01

    Pyrite morphology, iron speciation, and pyrite sulfur isotope data from the Xiakou section (Hubei Province, South China) were integrated to explore oceanic environmental variations through the Permian-Triassic transition and their possible relations to the largest mass extinction in Earth history. High ratios of highly-reactive iron to total iron (FeHR/FeT > 0.6) and pyrite iron to highly-reactive iron (FePy/FeHR > 0.7) together with a high abundance of small (mean diameter 0.6) along with lower values of FePy/FeHR (punctuated by episodic euxinic events in the latest Permian to earliest Triassic (post-extinction interval). The largest fluctuations of these redox proxies are observed in the ∼1.0 m of strata directly overlying the first (latest Permian) extinction horizon, indicating unsettled marine environmental conditions marked by frequent perturbations during the ∼60-kyr interval immediately following the mass extinction. The two largest redox events at Xiakou coincided with deposition of volcanic ash layers that have been correlated with Beds 25 and 28 of the Meishan D section, each of which was associated with an extinction pulse (the first and second extinction horizons of latest Permian and earliest Triassic age, respectively). Thus, our observations document two pulses of oceanic environmental change during the Permian-Triassic transition, each associated with a faunal crisis and possibly triggered by contemporaneous volcanic activity.

  10. Coal wizards of Oz

    Hornsby, D.T.; Partridge, A.C. [Australian Coal Preparation Society, Indooroopilly, Qld. (Australia)

    1998-03-01

    The first of two parts of a paper discusses how the Australian coal industry has grown to become the world`s largest coal exporter. Bar charts show coal product, exports, and consumption of metallurgical and steaming coal for the years 1987 to 1996. The importance of coal preparation is discussed. 8 figs., 2 photos.

  11. Coal and Energy.

    Bryant, Reba; And Others

    This teaching unit explores coal as an energy resource. Goals, student objectives, background information, and activity options are presented for each major section. The sections are: (1) an introduction to coal (which describes how and where coal was formed and explains the types of coal); (2) the mining of coal (including the methods and ways of…

  12. 12 CFR 204.125 - Foreign, international, and supranational entities referred to in §§ 204.2(c)(1)(iv)(E) and 204.8...

    2010-01-01

    ....2(c)(1)(iv)(E) and 204.8(a)(2)(i)(B)(5) are: Europe Bank for International Settlements. European Atomic Energy Community. European Central Bank. European Coal and Steel Community. The European Communities. European Development Fund. European Economic Community. European Free Trade Association....

  13. Report on 30th IGC field trip T306. Coal, geology and nature Northern Ordos Plateau, Inner Mongolia (excursion); Dai 30 kai IGC (Beijing) T306 chishitsu junken sanka hokoku. Uchimongoru jichiku hokubu Ordos kogen no sekitan chishitsu shizen (junken)

    Tokuhahi, S.; Suzuki, Y. [Geological Survey of Japan, Tsukuba (Japan)

    1997-06-01

    This is the second report, and describes the details of the excursion. Eleven participants from various countries left Beijing on August 14, 1996, and broke up at Huhehaote on August 20. During the tour, the participants visited the Heidaigou surface coal mine at Jungar, Ordovician Period coal section, Permian Period Shanxi formation, Shenshangou section of the Dosheng coal mine, and Majiatadong surface mine of the Donsheng coal mine. On the way, the tourists visited historical sites such as Genghis Khan Mausoleum. The report is written like a travel piece describing people`s customs and beautiful scenes, but is also elaborate on the geology and physiognomy of the visited locations including lithofacies. For instance, the Heidaigou surface coal mine has a reserve of 1.49 giga-ton of coal in its complicated coal layers which include 1 to 36 partings. 3 refs., 50 figs.

  14. COAL GEOLOGY

    2014-01-01

    <正>20140318Chen Xinwei(Reserves Evaluation Center of Xinjiang,Urumqi 830000,China);Li Shaohu Analysis on Sequence Stratigraphy Based on Jurassic Outcrop in Kuqa-Bai Coalfield(Xinjiang Geology,ISSN1000-8845,CN65-1092/P,32(1),2013,p.77-82,2illus.,12refs.,with English abstract)Key words:sequence stratigraphy,coal accumulation regularity,Xinjiang

  15. Coal-93

    The following report deals with the use of coal and coke during 1992. Some information about technics, environmental questions and markets are also given. The use of steamcoal for heating purposes has been reduced by about 10 percent during 1992 to the level of 1.1 million ton. This is the case for both heat generating boilers and co-generation boilers. On the other hand, the electricity production in the cogeneration plants have increased, mainly for tax reasons. The minor plants have increased their use of forest fuels, LPG and NG. During 1987 coal was used in 18 hotwater plants and 11 cogeneration plants. For 1992 these figures are 5 and 9. Taxes and environmental reasons explain this trend. The industry has reduced its use of steamcoal by 140 000 tons to about 700 000 tons. The reason is a cut down of production in particularly the cement industry and the mineral wool industry. The steamcoal import was 1.2 million tons during 1992, the same as the year before. The import has been lower than the consumption during the last years. The companies have reduced their stocks because of changed laws about emergency stocks. The average price of steamcoal imported in Sweden in 1992 was 272 SEK/ton or 25 SEK/ton lower than in 1991. The coal market during 1992 was affected by smaller consumption in Europe, shut downs of European mines and decreasing prices. Among other things independent mines in Russia and Poland have dumped low quality coals. A structuring of both process and quality has now begun. Western companies have for instance started joint ventures with Russian companies and supplied washing- and classifying equipments. All Swedish plants meet their emission limits of dust, SO2 and NOx given by county administrations or concession boards. 13 tabs

  16. Petrographic and geochemical contrasts and environmentally significant trace elements in marine-influenced coal seams, Yanzhou mining area, China

    Liu, Gaisheng; Yang, P.; Peng, Z.; Chou, C.-L.

    2004-01-01

    The Yanzhou mining area in west Shandong Province, China contains coals of Permian and Carboniferous age. The 31 and 32 seams of the Permian Shanxi Formation and seams 6, 15-17 of the Carboniferous Taiyuan Formation were analyzed for coal petrology, mineralogy and geochemical parameters. The parameters indicate that the coal is high volatile bituminous in rank. The coal is characterized by high vitrinite and low to medium inertinite and liptinite contents. These properties may be related to evolution of the coal forming environment from more reducing conditions in a marine influenced lower delta plain environment for the early Taiyuan coals to more oxidizing paleoenvironments in an upper delta plain for the upper Shanxi coal seams. The major mineral phases present in the coal are quartz, kaolinite, pyrite and calcite. Sulfur is one of the hazardous elements in coal. The major forms of sulfur in coal are pyritic, organic and sulfate sulfur. Pyritic and organic sulfur generally account for the bulk of the sulfur in coal. Elemental sulfur also occurs in coal, but only in trace to minor amounts. In this paper, the distribution and concentration of sulfur in the Yanzhou mining district are analyzed, and the forms of sulfur are studied. The sulfur content of the Taiyuan coal seams is considerably higher than that of the Shanxi coals. Organic sulfur content is positively correlated to total and pyritic sulfur. The vertical variation of Cu, Zn, Pb, As, Th, U and sulfur contents in coal seam 3 of the Shanxi Formation in the Xinglongzhuang mine show that all these trace elements, with the exception of Th, are enriched in the top and bottom plies of the seam, and that their concentrations are also relatively high in the dirt bands within the seam. The pyritic sulfur is positively correlated with total sulfur, and both are enriched in the top, bottom and parting plies of the seam. The concentrations of the trace elements are closely related to sulfur and ash contents. Most of

  17. Ocean anoxia did not cause the Latest Permian Extinction

    Proemse, Bernadette C.; Grasby, Stephen E.; Wieser, Michael E.; Mayer, Bernhard; Beauchamp, Benoit

    2014-05-01

    The Latest Permian Extinction (LPE, ~252 million years ago) was a turning point in the history of life on Earth with a loss of ~96% of all marine species and ~70% of all terrestrial species. While, the event undoubtedly shaped the evolution of life its cause remains enigmatic. A leading hypothesis is that the global oceans became depleted in oxygen (anoxia). In order to test this hypothesis we investigated a proxy for marine oxygen levels (molybdenum isotopic composition) in shale across the LPE horizon located on the subtropical northwest margin of Pangea at that time. We studied two sedimentary records in the Sverdrup basin, Canadian High Arctic: Buchanan Lake (eastern Axel Heiberg Island; 79° 26.1'N, 87° 12.6'W), representing a distal deep-water slope environment, and West Blind Fiord (southwest Ellesmere Island; 78° 23.9'N, 85° 57.2'W), representing a deep outer shelf environment (below storm wave base). The molybdenum isotopic composition (δ98/95Mo) of sediments has recently become a powerful tool as a paleo-oceanographic proxy of marine oxygen levels. Sample preparation was carried out in a metal-free clean room facility in the isotope laboratory of the Department of Physics and Astronomy, University of Calgary, Canada, that is supplied by HEPA-filtered air. Molybdenum isotope ratios were determined on a Thermo Scientific multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS) with an uncertainty better than ±0.10o for δ98/95Mo values. Results from the Buchanan Lake section show a large shift in δ98/95Mo values from 2.02o to +2.23o at the extinction horizon, consistent with onset of euxinic conditions. In contrast, West Blind Fiord shales, representing the sub-storm wave base shelf environment, show little change in the molybdenum isotopic composition (1.34o to +0.05), indicating ongoing oxic conditions across the LPE (Proemse et al., 2013). Our results suggest that areas of the Pangea continental shelf (North West Pangea) experienced

  18. Distribution of the Permian Monodiexodina in Karakorum and Kunlun and its Geological Significance

    YAO Jianxin; WANG Naiwen; XIAO Xuchang; JI Zhansheng; WU Guichun; WU Zhenjie; LI Boqin; WANG Jun; WANG Yong; ZHAI Qingguo

    2009-01-01

    The Permian fusulinoidean genus Monodiexodina is widely distributed in east Tethys. The genus might be an important indicator for the northern margin of Gondwana in northwestern China, but this is disputed. Monodiexodina.bearing areas can be restored as in either northern or southern middle latitudes with a symmetrical distribution between a high latitudinal, cool/cold water climatic realm and a paleotropical, warm water realm. Permian strata bearing Monodiexodina in Karakornm, Muztag Pear, and Buka Daban Pear of the east Kunlun Mountains can be correlated with each other. Faunal analyses and the stratigraphical position of Monodiexodina.bearing strata indicate that both Karakorum, east Kunlun, and the Pamirs were formed in a cool temperate sea area of the northern hemisphere in middle latitudes during the Permian, rather than at the Gondwana margin.

  19. Early Permian intrusions in the Paleozoic sediments of the Eastern North Sea area

    Clausen, O.R.; Andresen, Katrine Juul; Rasmussen, Jens Andreas

    Permian Kupfershiefer which is a potential source rock, has local depositional maxima associated to the basement faults. Salt structures which have been periodically active during the post Paleozoic dominate the northern part of the study area. The Paleozoic intrusions observed in the hanging-wall segment......This study presents the geometry of Paleozoic intrusions in the Skagerrak area located at the northern flank of the Ringkøbing-Fyn High and suggests factors controlling the formation of the intrusions. The intrusions have here been mapped in detail using 3D seismic data. The study area is located...... recorded across the entire North Sea Basin. The easternmost intrusions and extrusions have been associated to the “Skagerrak-Centered Large Igneous Province” that has an early Permian age of c. 297 Ma. Compared to the Southern Permian Basin which historically has been intensely investigated because of the...

  20. Evolutionary patterns of Productida (Brachiopoda) morphology during the Permian in South China

    2008-01-01

    The evolutionary patterns of Productida (brachiopod) morphology throughout the Permian show that while the percentage proportion of Productida (brachiopod) with strongly concentric and radial ornamentation declined from the Cisuralian to the Guadalupian, and then increased towards the Changhsingian via Wuchiapingian, the percentage proportion of Productida (brachiopod) with fine concentric and radial ornamentation distinctly increased from the Cisuralian to the Guadalupian, slightly declined towards the Wuchiapingian, and then increased towards the Changhsingian. From the Cisuralian to the Changhsingian, the percentage proportion of brachiopods with spinose ornamentation shows a persistent declining trend. The shell size generally indicates a miniaturization trend at species level during the Wuchiapingian to Changhsingian (including the transitional bed). These evolutionary patterns of brachiopod ornamentation and size are possibly related to the anoxia, food shortage, sea-level fluctuation, and change of substrate in the Permian (including the Permian-Triassic transitional interval) in South China.

  1. Coal -94

    This report deals with use of coal and coke during 1993; information about techniques, environmental questions and markets are also given. Use of steamcoal for heating purposes has been reduced about 3 % during 1993 to 1,0 mill tons. This is the case especially for the heat generating boilers. Production in co-generation plants has been constant and has increased for electricity production. Minor plants have increased their use of forest fuels, LPG and NG. Use of steamcoal will probably go down in the immediate years both in heat generating and co-generating plants. Coal-based electricity has been imported from Denmark during 1993 corresponding to about 400 000 tons of coal, when several of our nuclear plants were stopped. Use of steamcoal in the industry has been constant at 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1993 was 1,6 mill tons like the year before. 1,2 mill tons coke were produced. Coke consumption in industry was 1,4 mill tons. 0,2 mill tons of coke were imported. Average price of steamcoal imported to Sweden in 1993 was 308 SEK/ton or 13 % higher than in 1992; this can be explained by the dollar price level increasing 34% in 1993. For the world, the average import price was 50,0 USD/ton, a decrease of 6 %. The coal market during 1993 was affected by less consumption in Europe, shut downs of European mines and decreasing prices. High freight price raises in Russia has affected the Russian export and the market in northern Europe. The prices have been stabilized recently. All Swedish plants meet emission limits of dust, SO2 and NOx. Co-generation plants all have some sort of SO2-removal system; the wet-dry method is mostly used. A positive effect of the recently introduced NOx-duties is a 40% reduction

  2. Coal industry annual 1993

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993

  3. Coal industry annual 1993

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  4. Coal blending and coal homogenisation facilities

    Toerslev Jensen, P. [I/S ELSAM, Fredericia (Denmark)

    1997-12-31

    Blending is becoming increasingly important as a way of improving the quality of coal fired in power plants. This paper gives a basic description of the purposes of coal blending. Although indices for estimating (properties, slagging and fouling propensity, reactivity, etc.) of coal and coal blends exist, these are not considered reliable for coals of widely different origin, and experience will be emphasised as a better tool. The pros and cons of different blending methods are discussed together with the environmental impact of coal blending facilities. Finally, the blending facilities of ELSAM, a power pool serving the western part of Denmark, are described. 7 refs., 5 figs., 4 tabs.

  5. Sedimentary features and exploration targets of Middle Permian reservoirs in the SW Sichuan Basin

    Guoming Xu

    2015-11-01

    Full Text Available The exploration direction and targets for the large-scale Middle Permian gas reservoirs in the Sichuan Basin are hot spots and challenges in current exploration researches. The exploration successes of large gas field of Cambrian Longwangmiao Formation in Gaoshiti-Moxi region, Central Sichuan Basin, indicated that prospective sedimentary facies belt was the basis for the formation of large gas fields. In this paper, based on seismic data, outcrop data and drilling data, the tectonic framework and sedimentary features of the Middle Permian in the SW Sichuan Basin were comprehensively studied. The following conclusions were reached from the perspective of sedimentary facies control: (1 during the Middle Permian, this region was in shallow water gentle slope belts with high energy, where thick reef flat facies were deposited; (2 the basement was uplifted during Middle Permian, resulting in the unconformity weathering crust at the top of Maokou Formation due to erosion; the SW Sichuan Basin was located in the karst slope belt, where epigenic karstification was intense; and (3 reef flat deposits superimposed by karst weathering crust was favorable for the formation of large-scale reef flat karst reservoirs. Based on the combination of the resources conditions and hydrocarbon accumulation conditions in this region, it was pointed out that the Middle Permian has great potential of large-scale reef flat karst gas reservoir due to its advantageous geological conditions; the Middle Permian traps with good hydrocarbon accumulation conditions were developed in the Longmen Mountain front closed structural belt in the SW Sichuan Basin and Western Sichuan Basin depression slope belt, which are favorable targets for large-scale reef flat karst reservoirs.

  6. Anoxia duirng the Late Permian Binary Mass Extinction and Dark Matter

    Abbas, S; Mohanty, S; Abbas, Samar; Abbas, Afsar; Mohanty, Shukadev

    2000-01-01

    Recent evidence quite convincingly indicates that the Late Permian biotic crisis was in fact a binary extinction with a distinct end-Guadalupian extinction pulse preceding the major terminal end-Permian Tartarian event by 5 million years. In addition anoxia appears to be closely associated with each of these end-Paleozoic binary extinctions. Most leading models cannot explain both anoxia and the binary characteristic of this crisis. In this paper we show that the recently proposed volcanogenic dark matter scenario succeeds in doing this.

  7. Permian continental basins in the Southern Alps (Italy) and peri-mediterranean correlations

    Cassinis, Giuseppe; Perotti, Cesare R.; Ronchi, Ausonio

    2012-01-01

    The Late Carboniferous to Permian continental successions of the Southern Alps can be subdivided into two main tectono-sedimentary Cycles, separated by a marked unconformity sealing a Middle Permian time gap, generally estimated at over 10 Ma. The lower cycle (1), between the Variscan crystalline basement and the Early Permian, is mainly characterised by fluvio-lacustrine and volcanic deposits of calc-alkaline acidic-to-intermediate composition, which range up to a maximum thickness of more than 2,000 m. The upper cycle (2), which is devoid of volcanics, is mostly dominated through the Mid?-Late Permian by alluvial sedimentation which covered the previous basins and the surrounding highs, giving rise to the subaerial Verrucano Lombardo-Val Gardena (Gröden) red-beds, up to about 800 m thick. The palaeontological record from the terrigenous deposits of both the above cycles consists mainly of macro- and microfloras and tetrapod footprints. The age of the continental deposits is widely discussed because of the poor chronological significance of a large number of fossils which do not allow reliable datings; however, some sections are also controlled by radiometric calibrations. The comparison with some selected continental successions in southern Europe allows to determine their evolution and set up correlations. A marked stratigraphic gap shows everywhere between the above-mentioned Cycles 1 and 2. As in the Southern Alps, the gap reaches the greatest extent during the Mid-Permian, near the Illawarra Reversal geomagnetic event (265 Ma). In western Europe, however, such as in Provence and Sardinia, the discussed gap persists upwardly to Late Permian and Early Triassic or slightly younger times, i.e. to the onset of the "Alpine sedimentary Cycle", even though in northeastern Spain (Iberian Ranges, Balearic Islands) this gap results clearly interrupted by late Guadalupian-Lopingian deposits. The above two major tectonosedimentary cycles reflect, in our view, two main

  8. NEW FINDINGS OF PERMIAN FUSULINIDS AND CORALS FROM WESTERN KARAKORUM AND E HINDU KUSH (PAKISTAN

    ERNST JA. LEVEN

    2007-07-01

    Full Text Available Additional findings of fusulinids and corals from Permian rocks of Western Karakorum and Eastern Hindu Kush are reported. The Lashkargaz Fm. of Western Karakorum (Sakmarian - Kubergandian in age, is redefined in its uppermost part. A new unit of sucrosic dolostone, the Ini Sar Fm., of early Murgabian age in its basal part, is established for a level previously attributed to the Ailak Fm. The Ailak Fm. is confirmed to be Late Permian in its lower part. A rich fusulinid fauna of early Kubergandian age was found in a carbonate nappe previously unidentified, along the Pakistan-Afghanistan border in the Eastern Hindu Kush. 

  9. Events during Early Triassic recovery from the end-Permian extinction

    Tong, Jinnan; Zhang, Suxin; Zuo, Jingxun; Xiong, Xinqi

    2007-01-01

    The Palaeozoic-Mesozoic transition is characterized not only by the biggest Phanerozoic mass extinction, at the end of Permian, but also a prolonged period of recovery of the biota during the succeeding Early Triassic. The delayed recovery is generally attributed to the effects of extreme environmental conditions on the Early Triassic ecosystem. However, there has been very little study of the cause and mechanism of the environmental conditions that prevailed during the period of extinction and subsequent recovery. Research on the Permian-Triassic boundary and Lower Triassic, especially that on environmental events at the beginning of the Triassic in South China, indicates that the slowness of the recovery may be the result of three factors: (1) extreme environmental conditions that persisted through the transitional period and which were maintained by, for example, intermittent contemporary volcanism; (2) a passive evolutionary and ecologic strategy of the biota, in which r-selection taxa were dominant and K-selection forms insignificant; (3) an immature, poorly functioning ecosystem, which had difficulty in responding to and withstanding extreme environmental changes. According to data from South China, environmental changes were frequent during the Late Permian, and especially serious at the Permian-Triassic boundary. The Late Permian ecosystem was well structured and fully functioning as a result of a long period of steady development during the late Palaeozoic, and was capable of resisting general environmental changes. However, increasingly frequent and probably more extreme environmental events in the latest Permian may have led to a general collapse of this ecosystem and to the mass extinction at the end of the Permian. The Early Triassic ecosystem was immature, functioned poorly, and was unable to respond effectively to environmental changes, so that persisting extreme environmental conditions slowed ecosystem reconstruction considerably, and the recovery

  10. A comparison of the biological,geological events and environmental backgrounds between the Neoproterozoic-Cambrian and Permian-Triassic transitions

    2010-01-01

    extinction of many different taxa at class and order levels.Although it caused the extinction of 95% of marine species and 75% of terrestrial species as well as complete cessation of coal and reef deposits after the mass extinction,this high-level biological re-organization still occurred within an established ecosystem,however drastic it may seem.Survived or Lazarus taxa re-occupied the existing ecospace in a relatively short duration after the end-Permian mass extinction.C-isotope excursions display large perturbations during both transitions,yet also in different magnitudes and frequencies,which suggest different atmospheric and oceanic conditions.The recurrent geological and geochemical events as well as the coupled major biological turnovers during the two transitions provide new clues to understanding the interplays among the earth-life system.Thus,it is essential to carry out multidisciplinary studies from the deep internal system to the surface of the Earth as a whole in order to unravel the interactions of different spheres of the earth.

  11. An Exact Bosonization Rule for c=1 Noncritical String Theory

    Ishibashi, N.; A. Yamaguchi

    2007-01-01

    We construct a string field theory for c=1 noncritical strings using the loop variables as the string field. We show how one can express the nonrelativistic free fermions which describes the theory, in terms of these string fields.

  12. Unilateral extended suboccipital approach for a C1 dumbbell schwanoma

    Gorgan R.M.

    2015-03-01

    Full Text Available Craniovertebral junction tumors represent a complex pathology carrying a high risk of injuring the vertebral artery and the lower cranial nerves. Dumbbell C1- C2 schannomas are very rare tumors in this location. We present a case of a 66 years old male accepted for left laterocervical localized pain, headache and vertigo, with a large C1 dumbbell schwannoma extending in lateral over the C1 arch and displacing the C3 segment of the vertebral artery superiorly and anteriorly. Complete removal of the tumor was achieved using a far lateral approach. The approach is discussed with focus on the vertebral artery anatomy as the approach should give enough space to gain control of the artery without creating instability. Safe removal of C1 nerve root schwanomas can be achieved even if they compress and displace the vertebral artery by entering a fibrous tissue plane between the tumor and the vertebral artery.

  13. 26 CFR 1.1402(c)-1 - Trade or business.

    2010-04-01

    ...)-7, inclusive, the term “trade or business”, for the purpose of the tax on self-employment income... 26 Internal Revenue 12 2010-04-01 2010-04-01 false Trade or business. 1.1402(c)-1 Section 1.1402(c... (CONTINUED) INCOME TAXES Tax on Self-Employment Income § 1.1402(c)-1 Trade or business. In order for...

  14. Evaluation report on CCTF core-I reflood tests C1-6 (RUN 15), C1-9 (RUN 18), C1-11 (RUN 20) and C1-13 (RUN 22)

    The present report describes the effects of the Emergency Core Cooling (ECC) water injection rate on the reflooding phenomena observed in the Cylindrical Core Test Facility (CCTF). The evaluation is based on the data of Tests C1-5, C1-6, C1-9, C1-11 and C1-13 of the CCTF Core-I test series. In these tests, the injection rates of an accumulator system (Acc) and a low pressure coolant injection system (LPCI) and the injection duration of the Acc were parametrically varied from Test C1-5 (base case test). The higher ECC water injection rate caused the downcomer water head and core flooding rate to be higher resulting in the better core cooling. However, there was little effect of the LPCI injection rate on the core cooling once the downcomer water head reached the maximum level. Although the effects of the Acc injection rate and duration on the primary system thermo-hydrodynamic behavior and the core cooling behavior were dominant in an early period of the transient, they also significantly influenced the core cooling behavior through the whole transient. The similar trends of the effect of Acc injection rate on the core cooling behavior were observed in the CCTF and the FLECHT-SET Phase A experiments. (author)

  15. Assessment of undiscovered copper resources associated with the Permian Kupferschiefer, Southern Permian Basin, Europe: Chapter U in Global mineral resource assessment

    Zientek, Michael L.; Oszczepalski, Sławomir; Parks, Heather L.; Bliss, James D.; Borg, Gregor; Box, Stephen E.; Denning, Paul D.; Hayes, Timothy S.; Spieth, Volker; Taylor, Cliff D.

    2015-01-01

    This study synthesizes available information and estimates the location and quantity of undiscovered copper associated with a late Permian bituminous shale, the Kupferschiefer, of the Southern Permian Basin in Europe. The purpose of this study is to (1) delineate permissive areas (tracts) where undiscovered reduced-facies sediment-hosted stratabound copper deposits could occur within 2.5 kilometers of the surface, (2) provide a database of known reduced-facies-type sediment-hosted stratabound copper deposits and significant prospects, and (3) provide probabilistic estimates of amounts of undiscovered copper that could be present within each tract. This assessment is a contribution to a global assessment conducted by the U.S. Geological Survey (USGS).

  16. Basin-scale distribution of sill intrusions in the Tunguska Basin, East Siberia, and the implications for the end-Permian environmental crisis

    Svensen, Henrik H.; Frolov, Sergei; Akhmanov, Grigorii G.; Polozov, Alexander G.; Planke, Sverre

    2015-04-01

    The emplacement of the Siberian Traps Large igneous province through the Tunguska Basin is regarded as the main processes behind the end-Permian environmental crisis. Still, the lack of data from the Tunguska Basin represents one of the main uncertainties in understanding this link. Degassing from contact metamorphic aureoles in evaporites is suggested as key to the continental mass extinction, but very little is known about the actual distribution of sills within these lithologies. We present results from a unique borehole database with more than 700 boreholes, where 293 boreholes are studied in detail and presented here. The boreholes cover large parts of the basin, from Norilsk in the north (N69) to Bratsk in the south (N55), with a bias towards petroleum-bearing regions. In total, 93.5% of the selected boreholes contain sill intrusions. The sill thicknesses vary considerably from kilometer-scale intrusive complexes to individual thin sills of a few tens of meters. Locally, thick sills (up to 900 meters in thickness) occur in the upper part of the sedimentary succession, affecting the coal-rich Tunguska Series sediments. However, on average, the thickest sills in the basin are emplaced within the vast Cambrian salt formations, with average thicknesses in the 115-130 meter range. Accompanying petrographic investigations of metamorphic sediments demonstrate that widespread high temperature devolatilization took place. Degassing to the atmosphere took place via explosive pipe degassing and seepage. We show that depending on the specific location within the province and the emplacement depth, the potential for degassing of both greenhouse gases (CH4, CO2), aerosols (SO2), and ozone destructive gases (CH3Cl, CH3Br) was substantial and can explain the end-Permian mass extinction.

  17. Mineralogical and Geochemical Compositions of the No. 5 Coal in Chuancaogedan Mine, Junger Coalfield, China

    Ning Yang

    2015-11-01

    Full Text Available This paper reports the mineralogy and geochemistry of the Early Permian No. 5 coal from the Chuancaogedan Mine, Junger Coalfield, China, using optical microscopy, scanning electron microscopy (SEM, Low-temperature ashing X-ray diffraction (LTA-XRD in combination with Siroquant software, X-ray fluorescence (XRF, and inductively coupled plasma mass spectrometry (ICP-MS. The minerals in the No. 5 coal from the Chuancaogedan Mine dominantly consist of kaolinite, with minor amounts of quartz, pyrite, magnetite, gypsum, calcite, jarosite and mixed-layer illite/smectite (I/S. The most abundant species within high-temperature plasma-derived coals were SiO2 (averaging 16.90%, Al2O3 (13.87%, TiO2 (0.55% and P2O5 (0.05%. Notable minor and trace elements of the coal include Zr (245.89 mg/kg, Li (78.54 mg/kg, Hg (65.42 mg/kg, Pb (38.95 mg/kg, U (7.85 mg/kg and Se (6.69 mg/kg. The coal has an ultra-low sulfur content (0.40%. Lithium, Ga, Se, Zr and Hf present strongly positive correlation with ash yield, Si and Al, suggesting they are associated with aluminosilicate minerals in the No. 5 coal. Arsenic is only weakly associated with mineral matter and Ge in the No. 5 coals might be of organic and/or sulfide affinity.

  18. Significance of Caucasian Sections for Working out Carbon-Isotope Standard for Upper Permian and Lower Triassic (Induan) and Their Correlation with the Permian of North-Eastern Russia

    Yuri D Zakharov; Alexander S Biakov; Aymon Baud; Heinz Kozur

    2005-01-01

    Data obtained on conodont distribution in the Permian-Triassic Sovetashen Section of Transcaucasia provide further limitations on the age of the carbon-isotopic anomalies discovered by Baud et al. (1989). The significance of Caucasian sections for working out the carbon-isotope standard for the Upper Permian and Lower Triassic (Induan) is shown. Original data on carbon-isotope composition of bivalve and brachiopod shells from Permian sediments of North-Eastern Russia (Omolon and Okhotsk areas) have been obtained, which may be used for their correlation.

  19. Carnivorous dinocephalian from the Middle Permian of Brazil and tetrapod dispersal in Pangaea

    Cisneros, Juan Carlos; Abdala, Fernando; Atayman-Güven, Saniye; Rubidge, Bruce S.; Celâl Şengör, A. M.; Schultz, Cesar L.

    2012-01-01

    The medial Permian (∼270-260 Ma: Guadalupian) was a time of important tetrapod faunal changes, in particular reflecting a turnover from pelycosaurian- to therapsid-grade synapsids. Until now, most knowledge on tetrapod distribution during the medial Permian has come from fossils found in the South African Karoo and the Russian Platform, whereas other areas of Pangaea are still poorly known. We present evidence for the presence of a terrestrial carnivorous vertebrate from the Middle Permian of South America based on a complete skull. Pampaphoneus biccai gen. et sp. nov. was a dinocephalian "mammal-like reptile" member of the Anteosauridae, an early therapsid predator clade known only from the Middle Permian of Russia, Kazakhstan, China, and South Africa. The genus is characterized, among other features, by postorbital bosses, short, bulbous postcanines, and strongly recurved canines. Phylogenetic analysis indicates that the Brazilian dinocephalian occupies a middle position within the Anteosauridae, reinforcing the model of a global distribution for therapsids as early as the Guadalupian. The close phylogenetic relationship of the Brazilian species to dinocephalians from South Africa and the Russian Platform suggests a closer faunistic relationship between South America and eastern Europe than previously thought, lending support to a Pangaea B-type continental reconstruction.

  20. A tale of two extinctions : converging end-Permian and end-Triassic scenarios

    van de Schootbrugge, Bas; Wignall, Paul B.

    2016-01-01

    The end-Permian (c. 252 Ma) and end-Triassic (c. 201 Ma) mass-extinction events are commonly linked to the emplacement of the large igneous provinces of the Siberia Traps and Central Atlantic Magmatic Province, respectively. Accordingly, scenarios for both extinctions are increasingly convergent and

  1. Marine anoxia and delayed Earth system recovery after the end-Permian extinction.

    Lau, Kimberly V; Maher, Kate; Altiner, Demir; Kelley, Brian M; Kump, Lee R; Lehrmann, Daniel J; Silva-Tamayo, Juan Carlos; Weaver, Karrie L; Yu, Meiyi; Payne, Jonathan L

    2016-03-01

    Delayed Earth system recovery following the end-Permian mass extinction is often attributed to severe ocean anoxia. However, the extent and duration of Early Triassic anoxia remains poorly constrained. Here we use paired records of uranium concentrations ([U]) and (238)U/(235)U isotopic compositions (δ(238)U) of Upper Permian-Upper Triassic marine limestones from China and Turkey to quantify variations in global seafloor redox conditions. We observe abrupt decreases in [U] and δ(238)U across the end-Permian extinction horizon, from ∼3 ppm and -0.15‰ to ∼0.3 ppm and -0.77‰, followed by a gradual return to preextinction values over the subsequent 5 million years. These trends imply a factor of 100 increase in the extent of seafloor anoxia and suggest the presence of a shallow oxygen minimum zone (OMZ) that inhibited the recovery of benthic animal diversity and marine ecosystem function. We hypothesize that in the Early Triassic oceans-characterized by prolonged shallow anoxia that may have impinged onto continental shelves-global biogeochemical cycles and marine ecosystem structure became more sensitive to variation in the position of the OMZ. Under this hypothesis, the Middle Triassic decline in bottom water anoxia, stabilization of biogeochemical cycles, and diversification of marine animals together reflect the development of a deeper and less extensive OMZ, which regulated Earth system recovery following the end-Permian catastrophe. PMID:26884155

  2. Integrated Sr isotope variations and global environmental changes through the Late Permian to early Late Triassic

    Song, Haijun; Wignall, Paul B.; Tong, Jinnan; Song, Huyue; Chen, Jing; Chu, Daoliang; Tian, Li; Luo, Mao; Zong, Keqing; Chen, Yanlong; Lai, Xulong; Zhang, Kexin; Wang, Hongmei

    2015-08-01

    New 87Sr/86Sr data based on 127 well-preserved and well-dated conodont samples from South China were measured using a new technique (LA-MC-ICPMS) based on single conodont albid crown analysis. These reveal a spectacular climb in seawater 87Sr/86Sr ratios during the Early Triassic that was the most rapid of the Phanerozoic. The rapid increase began in Bed 25 of the Meishan section (GSSP of the Permian-Triassic boundary, PTB), and coincided closely with the latest Permian extinction. Modeling results indicate that the accelerated rise of 87Sr/86Sr ratios can be ascribed to a rapid increase (>2.8×) of riverine flux of Sr caused by intensified weathering. This phenomenon could in turn be related to an intensification of warming-driven runoff and vegetation die-off. Continued rise of 87Sr/86Sr ratios in the Early Triassic indicates that continental weathering rates were enhanced >1.9 times compared to those of the Late Permian. Continental weathering rates began to decline in the middle-late Spathian, which may have played a role in the decrease of oceanic anoxia and recovery of marine benthos. The 87Sr/86Sr values decline gradually into the Middle Triassic to an equilibrium values around 1.2 times those of the Late Permian level, suggesting that vegetation coverage did not attain pre-extinction levels thereby allowing higher runoff.

  3. The continental Permian-Triassic boundary in the Netherlands: Implications for the geomagnetic polarity time scale

    Szurlies, M.; Geluk, M.C.; Krijgsman, W.; Kürschner, W.M.

    2012-01-01

    In Central and NW Europe, the transition from the Permian to the Triassic (i.e., the Zechstein–Buntsandstein boundary interval) is developed mainly in red bed facies. This continental sedimentary succession is marked by relatively high sedimentation rates providing a high temporal resolution favorab

  4. Provincialization of terrestrial faunas following the end-Permian mass extinction.

    Sidor, Christian A; Vilhena, Daril A; Angielczyk, Kenneth D; Huttenlocker, Adam K; Nesbitt, Sterling J; Peecook, Brandon R; Steyer, J Sébastien; Smith, Roger M H; Tsuji, Linda A

    2013-05-14

    In addition to their devastating effects on global biodiversity, mass extinctions have had a long-term influence on the history of life by eliminating dominant lineages that suppressed ecological change. Here, we test whether the end-Permian mass extinction (252.3 Ma) affected the distribution of tetrapod faunas within the southern hemisphere and apply quantitative methods to analyze four components of biogeographic structure: connectedness, clustering, range size, and endemism. For all four components, we detected increased provincialism between our Permian and Triassic datasets. In southern Pangea, a more homogeneous and broadly distributed fauna in the Late Permian (Wuchiapingian, ∼257 Ma) was replaced by a provincial and biogeographically fragmented fauna by Middle Triassic times (Anisian, ∼242 Ma). Importantly in the Triassic, lower latitude basins in Tanzania and Zambia included dinosaur predecessors and other archosaurs unknown elsewhere. The recognition of heterogeneous tetrapod communities in the Triassic implies that the end-Permian mass extinction afforded ecologically marginalized lineages the ecospace to diversify, and that biotic controls (i.e., evolutionary incumbency) were fundamentally reset. Archosaurs, which began diversifying in the Early Triassic, were likely beneficiaries of this ecological release and remained dominant for much of the later Mesozoic. PMID:23630295

  5. Taeniopterid lamina on Phasmatocycas megasporophylls (Cycadales) from the Lower Permian of Kansas, U.S.A.

    Gillespie, W.H.; Pfefferkorn, H.W.

    1986-01-01

    New specimens of Phasmatocycas and Taeniopteris from the original Lower Permian locality in Kansas demonstrate organic attachment of the two and corroborate Mamay's hypothesis that Phasmatocycas and Taeniopteris were parts of the same plant. These forms also suggest that cycads evolved from taxa with entire leaves; i.e. Taeniopteris, rather than from pteridosperms with compound leaves. ?? 1986.

  6. Anatomy of a Permian Erg sequence: the De La Cuesta Formation (northwestern Argentina)

    This work is about the Permian red beds of the La Cuesta Formation (Sierra de Narvaez, northwestern Argentina) which is composed of sandstones associated with mud stones and subordinate conglomerates. The sediments obtained from the interaction between aeolian and ephemeral fluvial systems, are represented by aeolian dune, dry aeolian inter dune and aeolian sand sheet, mud flat, wet aeolian inter dune, and fluvial deposits

  7. The Permian Rotliegend reservoir architecture of the Dutch Koekoekspolder geothermal doublet

    Mijnlieff, H.F.; Bloemsma, M.R.; Donselaar, M.E.; Henares, S.; Redjosentono, A.E.; Veldkamp, J.G.; Weltje, G.J.

    2014-01-01

    The Dutch Koekoekspolder geothermal doublet was drilled in 2011 targeting the Permian Rotliegendreservoir. The encountered reservoir properties were less favorable than expected pre-drill. Post-drill integrated evaluation of vintage data and the new data from the geothermal wells resulted in a refin

  8. Pangean Reconstruction of the Yucatan Block and its Permian, Triassic, and Jurassic Geologic and Tectonic History

    Steiner, M.

    2004-12-01

    Paleomagnetic studies of Paleozoic sedimentary and plutonic rocks demonstrate that the Yucatan Block lay inverted off the NW coast of South America (SA) in Pangea, and rotated in a series of clockwise motions as SA and NA separated. Mid-Permian Yucatan was a fragment of the western margin of Pangea, just south of the equator. By 230 Ma, Yucatan rotated ˜20° clockwise and moved to the equator. Clockwise rotation continued through the Jurassic: ˜54° between 230 Ma and about Oxfordian, and another ˜32° between ˜Oxfordian and Tithonian, when the approximate present orientation was achieved. Passage of the Yucatan Block into the gap created by the separation of North and South America requires left-lateral motion relative to North America, perhaps by translation along the Mojave Sonora megashear. One remanence, carried by magnetite in red bed strata from the margins of the marine Santa Rosa basin (Maya Mtns), decays exceedingly linearly to the origin of orthogonal-axes plots. Biostratigraphy indicates a Late Pennsylvanian to Middle Permian age, and the presence of dual polarities in a 110 m, four polarity, magnetostratigraphic sequence demonstrates a post-Late Paleozoic Reversed Superchron (i.e., Middle Permian) age. Plutonic rocks exhibit a second, also dual-polarity, remanence, which corresponds to a paleopole 60° clockwise of the mid-Permian pole. The spatial relationship between the Permian and pluton paleopoles is very similar to that of the North American Permian and Late Triassic poles. Moreover, exceedingly uniform K/Ar ages of 231±7 Ma characterize all Maya Mtns plutons and the southern volcanic complex, indicating a 230 Ma resetting of the K/Ar radiometric systems of plutons dated by U/Pb as Late Silurian (Steiner and Walker, 1996). Metamorphic aureoles developed in the Pennsylvanian-Permian Santa Rosa strata bordering the Silurian plutonic complexes suggest the occurrence of a post-intrusion hydrothermal event. The 230 Ma reset K/Ar systems

  9. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe

  10. Coal processing and utilization

    Schilling, H.-D.

    1980-04-01

    It is noted that the rising price of oil as well as supply concerns have lead to an increase in the use of coal. It is shown that in order for coal to take a greater role in energy supply, work must commence now in the areas of coal extraction and processing. Attention is given to new technologies such as coke production, electricity and heat generation, coal gasification, and coal liquifaction. Also covered are a separator for nitrogen oxides and active coal regeneration. Finally, the upgrading of coal is examined.

  11. Safety and Usage of C1-Inhibitor in Hereditary Angioedema

    Riedl, Marc A; Bygum, Anette; Lumry, William;

    2016-01-01

    ) and 16.6 IU/kg (prophylaxis). Approximately 95% of infusions were administered outside of a health care setting. No adverse events (AEs) were reported in retrospective data. Among prospective data (n = 296 subjects; 9148 infusions), 252 AEs were reported in 85 (28.7%) subjects (rate of 0.03 events....../infusion); 9 events were considered related to pnfC1-INH. Two thromboembolic events were reported in subjects with thrombotic risk factors. No patient was noted to have undergone viral testing for suspected blood-borne infection during registry participation. CONCLUSIONS: The findings from this large......, international patient registry documented widespread implementation of pnfC1-INH self-administration outside of a health care setting consistent with current HAE guidelines. These real-world data revealed pnfC1-INH usage for a variety of reasons in patients with HAE and showed a high level of safety regardless...

  12. The structure and processes of the Siberian Traps sub-volcanic complex and consequences for end-Permian environmental crisis

    Svensen, H.; Polozov, A. G.; Planke, S.

    2013-12-01

    The emplacement of the Siberian Traps Large igneous province is regarded as the key processes that initiated the end-Permian environmental crisis. The details of this link are however still under investigation. Among the suggestions are lava degassing of mantle- and crustal-derived gases, explosive lava and phreatomagmatic eruptions, and gas release from contact metamorphism related to the sub-volcanic sill complex. Whereas the lava pile is relatively well studied and investigated, the sub-volcanic sills, dikes, and contact aureoles are poorly studied and documented. We present borehole and field data of sills and contact aureoles from across the Siberian Traps, from Norilsk in the north to Bratsk in the south. The data have been compiled during three field campaigns in 2004, 2006, and 2010. The sill geometries and thicknesses varies considerably from kilometer-scale intrusive complexes to individual thin sills of a few tens of meters. In contrast to several other LIPs, sills are also emplaced within the extrusive pile. Thick sills (30-80 meters) occur in high abundance in the upper part of the sedimentary succession, affecting the coal-rich Tungusska Series sediments. Moreover, very thick sills (100-300 meters) are also emplaced within the vast Cambrian salt formations. We show that depending on the specific location within the province and the emplacement depth, the potential for degassing of both greenhouse gases (CH4, CO2), aerosols (SO2), and ozone destructive gases (CH3Cl, CH3Br) was in the 103 to 104 Gt range.

  13. Stratigraphic and palaeoenvironmental framework of the Early Permian sequence in the Salt Range, Pakistan

    Shahid Ghazi; Nigel P Mountney; Aftab Ahmad Butt; Sadaf Sharif

    2012-10-01

    The Early Permian Gondwana regime succession of the Nilawahan Group is exposed only in the Salt Range of Pakistan. After a prolonged episode of non-deposition that spanned much of the Palaeozoic, the 350 m thick predominantly clastic sequence of the Nilawahan Group records a late glacial and post-glacial episode in which a range of glacio-fluvial, marine and fluvial environments evolved and accumulated. The Early Permian succession of the Salt Range has been classified into four formations, which together indicates a changing climatic regime during the Early Permian in the Salt Range region. The lower-most, Tobra Formation unconformably overlies a Cambrian sequence and is composed of tillite, diamictite and fresh water facies, which contain a floral assemblage (Gangamopteris and Glossopteris) that confirms an Asselian age. The Tobra Formation is overlain by marginal marine deposits of the Dandot Formation (Sakmarian), which contain an abundant brachiopods assemblage (Eurydesma and Conularia). Accumulation of the Dandot Formation was terminated by a regional sea-level fall and a change to the deposition of the fluvial deposits of the Warchha Sandstone (Artinskian). The Warchha Sandstone was deposited by high sinuosity meandering, avulsion prone river with well developed floodplains. This episode of fluvial sedimentation was terminated by a widespread marine transgression, as represented by the abrupt upward transition to the overlying shallow marine Sardhai Formation (Kungurian). The Early Permian Gondwana sequence represented by the Nilawahan Group is capped by predominantly shallow shelf carbonate deposits of the Tethyan realm. The sedimentologic and stratigraphic relationship of these four lithostratigraphic units in the Salt Range reveals a complex stratigraphic history for the Early Permian, which is mainly controlled by eustatic sea-level change due to climatic variation associated with climatic amelioration at the end of the major Gondwana glacial episode

  14. Paleoenvironment of the Permian rocks: a comparison between central and eastern Alborz, Iran

    Lankarani, M.; Amini, A.; Mosadegh, H.

    2009-04-01

    The succession of Permian rocks in Alborz region is composed of siliciclastic and carbonate facies. All of the sediments were deposited in the Paleotethyan passive continental margin but they show different facies architecture and paleoenvironmental condition in various parts of the region. This study, as part of a wider project, has investigated sedimentary facies and paleoenvironment of the Permian rocks in central and eastern Alborz. The Permian rocks in central Alborz are dominated by siliciclastic facies (Doroud Formation) in the lower, and carbonate facies (Ruteh Formation) in the upper half. Field studies and laboratory measurements resulted in recognition of 4 terrigenous and 13 carbonate facies in the succession. A siliciclastic shallow marine system was determined as depositional environment of the terrigenous facies. A homoclinal carbonate ramp, with scattered patch reefs, was determined as depositional environment of the carbonate facies. Dasycladacean green algae, ancestral red algae, hermatypic corals and bryozoans were the major bioconstructors of the ramp. The abundance of skeletal shoals respect to ooidal shoals in the ramp margin was high. The Permian rocks in eastern Alborz are dominated by mixed siliciclastic-carbonate facies (Ruteh Formation) in the lower, and siliciclastic facies (Nesen Formation) in the upper half. The studies resulted in recognition of 5 terrigenous and 6 carbonate facies in the succession. A mixed siliciclastic-carbonate shelf with high sediment influx was determined as depositional environment of the mixed siliciclastic-carbonate facies. Occurrence of the small patch reefs with high coral diversity in this mixed shelf indicates normal marine (hyposaline) condition. Upper terrigenous facies were deposited in fluvial-flood plain system. Difference in paleoclimate and tectonic activity of two sub-basins seems to be the major cause of the differences between the Permian facies in central and eastern Alborz.

  15. Tectonic Evolution of the Junggar Foreland Basin in the Late Carboniferous-Permian

    2001-01-01

    A comprehensive study has been carried out to subdivide andcorrelate the Upper Carboniferous and Permian sedimentary successions in the Junggar basin based on outcrops and drilling and geophysical data. The study results, combined with geological analyses of the basin's periphery and the basement, as well as studies of the sedimentary rocks within the basin, the unconformities, tectonic geometry, kinematics and geodynamics, lead to the conclusion that the Junggar basin was characterized by the development of foreland basin systems during the Late Carboniferous and Per mian, During that period, three foreland basin systems were developed: (1) the northwest foreland basin system, which trended nearly north-south from Mahu to the Chepaizi Palaeo-mountain during its early stage of development and thus it was also referred to as the west foreland basin system; (2) the Karamaili foreland basin system in the east and (3) the Northern Tianshan foreland basin system in the south. These systems are different in size, development stage and time of formation. The first two are developed earlier than the third, but they are smaller in size. All the structures in the Junggar basin have resulted from the integration and superposition of structural elements in the above three systems. In general, the development of the Junggar basin can be divided into four stages. Stage I was marked by the creation and evolution of the marginal western foreland and the peripheral Karamaili foreland basin systems during the Late Carboniferous-early Early Permian (C3-Pja). Stage Ⅱ was characterized by the development of complicated foreland basin systems during the mid dle-late Early Permian (Pjb-Pf) when the three foreland basin systems took their shapes. Stage Ⅲ was the integration stage of peripheral foreland basin systems during the Middle Permian (P2) in which steady and slow tectonic subsidence prevailed. Stage Ⅳ coincided with the shrinking of foreland basin development during the Late

  16. Ostracods (Crustacea associated with microbialites across the Permian-Triassic boundary in Dajiang (Guizhou Province, South China

    Marie-Beatrice FOREL

    2012-08-01

    Full Text Available 26 samples were processed for a taxonomic study of ostracods from the Upper Permian (Changhsingian - Lower Triassic (Griesbachian interval of the Dajiang section, Guizhou Province, South China. 112 species belonging to 27 genera are recognized. Five new species are described: Acratia candyae sp. nov, Bairdia adelineae sp. nov., Bairdia? huberti sp. nov., Bairdia jeromei sp. nov., Orthobairdia jeanlouisi sp. nov. The unexpected survival faunas associated with microbial formations in the aftermath of the end-Permian extinction are documented for the first time. Ostracod biodiversity variations and palaeo-environmental modifications associated with microbial growth through the Permian-Triassic boundary (PTB are discussed.

  17. Novel C-1 Substituted Cocaine Analogs Unlike Cocaine or Benztropine

    Reith, Maarten E.A.; Ali, Solav; Hashim, Audrey; Sheikh, Imran S.; Theddu, Naresh; Gaddiraju, Narendra V.; Mehrotra, Suneet; Schmitt, Kyle C.; Murray, Thomas F.; Sershen, Henry; Unterwald, Ellen M.; Davis, Franklin A.

    2012-01-01

    Despite a wealth of information on cocaine-like compounds, there is no information on cocaine analogs with substitutions at C-1. Here, we report on (R)-(−)-cocaine analogs with various C-1 substituents: methyl (2), ethyl (3), n-propyl (4), n-pentyl (5), and phenyl (6). Analog 2 was equipotent to cocaine as an inhibitor of the dopamine transporter (DAT), whereas 3 and 6 were 3- and 10-fold more potent, respectively. None of the analogs, however, stimulated mouse locomotor activity, in contrast...

  18. Topological cigar and the c=1 string: Open and closed

    We clarify some aspects of the map between the c=1 string theory at self-dual radius and the topologically twisted cigar at level one. We map the ZZ and FZZT D-branes in the c=1 string theory at self dual radius to the localized and extended branes in the topological theory on the cigar. We show that the open string spectrum on the branes in the two theories are in correspondence with each other, and their two point correlators are equal. We also find a representation of an extended N = 2 algebra on the worldsheet which incorporates higher spin currents in terms of asymptotic variables on the cigar. (author)

  19. Lax matrix solution of c=1 Conformal Field Theory

    Eynard, Bertrand

    2013-01-01

    To a correlation function in a two-dimensional conformal field theory with the central charge c=1, we associate a matrix differential equation \\Psi'=L\\Psi, where the Lax matrix L is a matrix square root of the energy-momentum tensor. Then local conformal symmetry translates into isomonodromy of the differential equation. This provides a justification for the recently observed relation between four-point conformal blocks and solutions of the Painleve VI equation. This also provides a direct way to compute the three-point function of Runkel-Watts theory - the common c->1 limit of Minimal Models and Liouville theory.

  20. Assessing coal burnout

    Lowe, A. [Pacific Power, Sydney, NSW (Australia)

    1999-11-01

    Recent research has allowed a quantitative description of the basic process of burnout for pulverized coals to be made. The Cooperative Research Centre for Black Coal Utilization has built on this work to develop a coal combustion model which will allow plant engineers and coal company representatives to assess their coals for combustion performance. The paper describes the model and its validation and outlines how it is run. 2 figs.

  1. Inorganic Constituents in Coal

    Rađenović A.

    2006-01-01

    Coal contains not only organic matter but also small amounts of inorganic constituents. More thanone hundred different minerals and virtually every element in the periodic table have been foundin coal. Commonly found group minerals in coal are: major (quartz, pyrite, clays and carbonates),minor, and trace minerals. Coal includes a lot of elements of low mass fraction of the orderof w=0.01 or 0.001 %. They are trace elements connected with organic matter or minerals comprisedin coal. The fract...

  2. Coal data: A reference

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  3. Conditions for the formation and atmospheric dispersion of a toxic, heavy gas layer during thermal metamorphism of coal and evaporite deposits by sill intrusion

    Storey, Michael; Hankin, Robin K. S.

    2010-05-01

    There is compelling evidence for massive discharge of volatiles, including toxic species, into the atmosphere at the end of the Permian. It has been argued that most of the gases were produced during thermal metamorphism of coal and evaporite deposits in the East Siberia Tunguska basin following sill intrusion (Retallack and Jahren, 2008; Svensen et al., 2009). The release of the volatiles has been proposed as a major cause of environmental and extinction events at the end of the Permian, with venting of carbon gases and halocarbons to the atmosphere leading to global warming and atmospheric ozone depletion (Svensen et al., 2009) Here we consider the conditions required for the formation and dispersion of toxic, heavier than air, gas plumes, made up of a mixture of CO2, CH4, H2S and SO2 and formed during the thermal metamorphism of C- and S- rich sediments. Dispersion models and density considerations within a range of CO2/CH4 ratios and volatile fluxes and temperatures, for gas discharge by both seepage and from vents, allow the possibility that following sill emplacement much of the vast East Siberia Tunguska basin was - at least intermittently - covered by a heavy, toxic gas layer that was unfavorable for life. Dispersion scenarios for a heavy gas layer beyond the Siberian region during end-Permian times will be presented. REFERENCES G. J. Retallack and A. H. Jahren, Methane release from igneous intrusion of coal during Late Permian extinction events, Journal of Geology, volume 116, 1-20, 2008 H. Svensen et al., Siberian gas venting and the end-Permian environmental crisis, Earth and Planetary Science Letters, volume 277, 490-500, 2009

  4. Isometric C1-immersions for pairs of Riemannian metrics

    Let h1, h2 be two Euclidean metrics on Rq, and let V be a C∞-manifold endowed with two Riemannian metrics g1 and g2. We study the existence of C1-immersions f:(V,g1,g2)→(Rq,h1,h2) such that f*(hi)=gi for i=1,2. (author)

  5. Pediatric hereditary angioedema due to C1-inhibitor deficiency

    Farkas Henriette

    2010-07-01

    Full Text Available Abstract Hereditary angioedema (HAE resulting from the deficiency of the C1 inhibitor (C1-INH is a rare, life-threatening disorder. It is characterized by attacks of angioedema involving the skin and/or the mucosa of the upper airways, as well as the intestinal mucosa. In approximately 50 per cent of cases, clinical manifestations may appear during childhood. The complex management of HAE in pediatric patients is in many respects different from the management of adults. Establishing the diagnosis early, preferably before the onset of clinical symptoms, is essential in cases with a positive family history. Complement studies usually afford accurate diagnosis, whereas molecular genetics tests may prove helpful in uncertain cases. Appropriate therapy, supported by counselling, suitable modification of lifestyle, and avoidance of triggering factors (which primarily include mechanical trauma, mental stress and airway infections in children may spare the patient unnecessary surgery and may prevent mortality. Prompt control of edematous attacks, short-term prophylaxis and intermittent therapy are recommended as the primary means for the management of pediatric cases. Medicinal products currently used for the treatment of children with hereditary angioedema include antifibrinolytics, attenuated androgens, and C1-INH replacement therapy. Current guidelines favour antifibrinolytics for long-term prophylaxis because of their favorable safety profile but efficacy may be lacking. Attenuated androgens administered in the lowest effective dose are another option. C1-INH replacement therapy is also an effective and safe agent for children. Regular monitoring and follow-up of patients are necessary.

  6. 26 CFR 1.514(c)-1 - Acquisition indebtedness.

    2010-04-01

    ... (CONTINUED) INCOME TAXES (CONTINUED) Taxation of Business Income of Certain Exempt Organizations § 1.514(c)-1... where State law provides that a tax lien attaches to property prior to the time when such lien becomes... and payable and the organization has had an opportunity to pay such lien in accordance with State...

  7. Evidence of lacustrine sedimentation in the Upper Permian Bijori Formation, Satpura Gondwana basin: Palaeogeographic and tectonic implications

    Tapan Chakraborty; Soumen Sarkar

    2005-06-01

    The Upper Permian Bijori Formation of the Satpura Gondwana basin comprising fine- to coarsegrained sandstone, carbonaceous shale/mudstone and thin coal bands was previously interpreted as the deposits of meandering rivers. The present study documents abundance of wave ripples, hummocky and swaley cross-stratification and combined flow bedforms in the Bijori Formation, suggesting that a significant part of the formation was deposited in a wave-agitated environment. Evidence of near-emergent depositional conditions provided by repeated occurrence of rootlet beds and hydromorphic paleosols, local flooding surfaces denoting rapid fluctuation of water level, occurrences of temnospondyl vertebrate fossils, and absence of tidal signatures and marine fossils suggest a lacustrine rather than marine depositional regime. Five facies associations recognised within the Bijori Formation are inferred to represent fluvial channels and associated floodplains (FA1), lake shorelines (FA2), subaqueous distributary channels and associated levees (FA3), wave- and storm-affected delta front (FA4), and open lacustrine/lower shoreface (FA5) deposits. The planoconcave fluvial channel-fill sandbodies with unidirectional cross-beds are clearly distinguishable from the delta front bars that show a convexo-plan or bi-convex sandbody geometry and dominance of wave and combined flow bedforms. Some of the distributary channels record interaction of fluvial and wave-dominated basinal processes. Major distributary sandbodies show a north to northwest flow direction while wave-affected delta front sandbodies show very complex flow patterns reflecting interaction between fluvial discharge and wave processes. Wave ripple crest trends show that the lake shoreline had an overall east–northeast to west–southwest orientation. The lack of documented contemporaneous lacustrine or marine sediments in the Satpura Gondwana basin posed a major problem of basin-scale palaeogeographic reconstruction. The

  8. 3-D Imaging of Cleat and Micro-cleat Characteristics, South Walker Creek Coals, Bowen Basin, Australia: Microfocus X-ray Computed Tomography Analysis

    Asep Kurnia Permana

    2014-01-01

    DOI: 10.17014/ijog.v7i1.131The Permian coals of the South Walker Creek area have a moderately to highly developed cleat system. The cleat fractures are well developed in both bright and dull bands, and generally parallel, inclined or perpendicular to the bedding planes of the seam, with the spaces open or filled by mineral matter, such as clay and carbonate minerals. Microfocus X-ray computed tomography (CT) technique was performed to identify cleat characteristics in the coal seams. This tec...

  9. Coal information 1996

    Coal Information (1997 edition) is the latest edition of a publication that has been produced annually by the IEA since 1983. The report is intended to provide both Member countries of the OECD and those employed in all sectors of the coal industry with information on current world coal market trends and long-term prospects. It includes information on coal prices, demand, trade, supply, production capacity, transport, environmental issues (including emission standards for coal-fired boilers), coal ports, coal-fired power stations and coal used in non -OECD countries. Part I of the publication contains a wide ranging review of world coal market developments in 1996 and current prospects to 2010. The review is based on historical data of OECD energy supply and demand, data on other world regions, projections of OECD coal supply, demand and trade and information provided by the CIAB. Part II provides, in tabular and graphical form, a more detailed and comprehensive statistical picture of coal developments and future prospects for coal in the OECD, by region and for individual Member countries. Readers interested in projections are strongly advised to read the notes for individual countries in Principles and Definitions in Part II. Coal statistics for non-OECD countries are presented in Part III of the book. Summary data are available on hard coal supply and end-use statistics for about 40 countries and regions world-wide. Data are based on official national submissions to the United Nations in Geneva and New York, national energy publications, information provided to the IEA Secretariat by national statistical offices as well as other unofficial Secretariat sources. Further information on coal used in non-OECD countries is published annually by the IEA in Energy Statistics and Balances of Non-OECD Countries. Also included in Part III are the Survey of Coal Ports world-wide and the Survey of Coal-fired Power Stations in coal-importing countries

  10. Shallow marine ecosystem feedback to the Permian/Triassic mass extinction

    Yongbiao WANG; Zheng MENG; Wei LIAO; Zeting WENG; Hao YANG

    2011-01-01

    Late Permian reefs developed widely on shallow marine carbonate platforms in South China but disappeared far below the main mass extinction level of the latest Permian. The collapse of reef ecosystem may be related to the enhanced volcanism at the end of Late Permian. Notably, some colony corals and reef-building sponges were found to occur near the mass extinction boundary, inferring the eclipse of reef ecosystem is ahead of the disappearance of reef-building organisms, and the triggers would be present long before the main mass extinction. As the primary producers, the calcareous algae are rich in platform limestones of Late Permian and played a very important role in maintaining the shallow benthic ecosystems. The calcareous algae were found to disappear synchronously with the great reduction of foraminifers,which were ecologically associated with these algae. The extinction of Late Permian calcareous algae greatly reduced the biodiversity of primary producers in the shallow marine environment and destroyed in part the structure and the base of the shallow marine ecosystems,which in turn cause the extinction of ecologically associated metazoan. Microbialites developed on carbonate platforms immediately after the end-Permian mass extinction, representing a simple and unique microbial ecosystem. Widespread occurrence of microbialites symbolized the deterioration of marine environmental conditions and the dramatic revolution of marine ecosystems. As the new primary producers instead of the extinguished calcareous algae, cyanobacteria in the microbialites were an important base of this peculiar ecosystem and contributed greatly to the survival of the remnant faunas after the mass extinction. Widespread occurrence of microbialites in shallow marine environment is suggested to be related to the elevated level of volcanism-induced greenhouse gases and enhanced evaporation and hypersaline condition in addition to the decrease of metazoan grazing pressure. The change

  11. Solar coal gasification

    Gregg, D. W.; Aiman, W. R.; Otsuki, H. H.; Thorsness, C. B.

    1980-01-01

    A preliminary evaluation of the technical and economic feasibility of solar coal gasification has been performed. The analysis indicates that the medium-Btu product gas from a solar coal-gasification plant would not only be less expensive than that from a Lurgi coal-gasification plant but also would need considerably less coal to produce the same amount of gas. A number of possible designs for solar coal-gasification reactors are presented. These designs allow solar energy to be chemically stored while at the same time coal is converted to a clean-burning medium-Btu gas.

  12. Hard coal; Steinkohle

    Loo, Kai van de; Sitte, Andreas-Peter [Gesamtverband Steinkohle e.V., Herne (Germany)

    2012-07-01

    While the black coal markets are expanding worldwide in 2011, the consumption of black coal in Germany stagnated in spite of positive economic impacts. A strong long-term decline may be expected by the structural change in the energy sector and the energy policy turnaround in Germany. Also, the accelerated phasing out nuclear power in 2011 brought any increases for the black coal. Now the discharge of domestic black coal until 2018 has become definitive. The imported coal now covers almost 80 % of the German black coal market.

  13. Clean coal technology

    Coal is the major source of energy in India at present as well as in foreseeable future. With gradual deterioration in coal quality as well as increased awareness on environmental aspects, clean coal technologies have to be adopted by major coal consuming sectors. The probable routes of restricting environmental degradation in power generation include beneficiation of power coal for maintaining consistency in coal supply and reducing pollutant emission, adoption of fluidized bed combustion on a larger scale, adoption of technologies for controlling SOx and NOx emission during and after combustion, adoption of larger capacity and improved and non-recovery type coke ovens

  14. Coal extraction - environmental prediction

    C. Blaine Cecil; Susan J. Tewalt

    2002-08-01

    To predict and help minimize the impact of coal extraction in the Appalachian region, the U.S. Geological Survey (USGS) is addressing selected mine-drainage issues through the following four interrelated studies: spatial variability of deleterious materials in coal and coal-bearing strata; kinetics of pyrite oxidation; improved spatial geologic models of the potential for drainage from abandoned coal mines; and methodologies for the remediation of waters discharged from coal mines. As these goals are achieved, the recovery of coal resources will be enhanced. 2 figs.

  15. Coal desulfurization process

    Hsu, G. C.; Gavalas, G. R.; Ganguli, P. S.; Kalfayan, S. H.

    1978-01-01

    A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

  16. First evidence for Permian-Triassic boundary volcanism in the Northern Gemericum: geochemistry and U-Pb zircon geochronology

    Vozárová Anna

    2015-10-01

    Full Text Available Several magmatic events based on U-Pb zircon geochronology were recognized in the Permian sedimentary succession of the Northern Gemeric Unit (NGU. The Kungurian magmatic event is dominant. The later magmatism stage was documented at the Permian-Triassic boundary. The detrital zircon assemblages from surrounding sediments documented the Sakmarian magmatic age. The post-orogenic extensional/transtensional faulting controlled the magma ascent and its emplacement. The magmatic products are represented by the calc-alkaline volcanic rocks, ranging from basaltic metaandesite to metarhyolite, associated with subordinate metabasalt. The whole group of the studied NGU Permian metavolcanics has values for the Nb/La ratio at (0.44–0.27 and for the Nb/U ratio at (9.55–4.18, which suggests that they represent mainly crustal melts. Magma derivation from continental crust or underplated crust is also indicated by high values of Y/Nb ratios, ranging from 1.63 to 4.01. The new 206U–238Pb zircon ages (concordia age at 269 ± 7 Ma confirm the dominant Kungurian volcanic event in the NGU Permian sedimentary basin. Simultaneously, the Permian-Triassic boundary volcanism at 251 ± 4 Ma has been found for the first time. The NGU Permian volcanic activity was related to a polyphase extensional tectonic regime. Based on the new and previous U-Pb zircon ages, the bulk of the NGU Permian magmatic activity occurred during the Sakmarian and Kungurian. It was linked to the post-orogenic transpression/transtension tectonic movements that reflected the consolidation of the Variscan orogenic belt. The Permian-Triassic boundary magmatism was accompanied by extension, connected with the beginning of the Alpine Wilson cycle.

  17. First evidence for Permian-Triassic boundary volcanism in the Northern Gemericum: geochemistry and U-Pb zircon geochronology

    Vozárová, Anna; Presnyakov, Sergey; Šarinová, Katarína; Šmelko, Miloš

    2015-10-01

    Several magmatic events based on U-Pb zircon geochronology were recognized in the Permian sedimentary succession of the Northern Gemeric Unit (NGU). The Kungurian magmatic event is dominant. The later magmatism stage was documented at the Permian-Triassic boundary. The detrital zircon assemblages from surrounding sediments documented the Sakmarian magmatic age. The post-orogenic extensional/transtensional faulting controlled the magma ascent and its emplacement. The magmatic products are represented by the calc-alkaline volcanic rocks, ranging from basaltic metaandesite to metarhyolite, associated with subordinate metabasalt. The whole group of the studied NGU Permian metavolcanics has values for the Nb/La ratio at (0.44-0.27) and for the Nb/U ratio at (9.55-4.18), which suggests that they represent mainly crustal melts. Magma derivation from continental crust or underplated crust is also indicated by high values of Y/Nb ratios, ranging from 1.63 to 4.01. The new 206U-238Pb zircon ages (concordia age at 269 ± 7 Ma) confirm the dominant Kungurian volcanic event in the NGU Permian sedimentary basin. Simultaneously, the Permian-Triassic boundary volcanism at 251 ± 4 Ma has been found for the first time. The NGU Permian volcanic activity was related to a polyphase extensional tectonic regime. Based on the new and previous U-Pb zircon ages, the bulk of the NGU Permian magmatic activity occurred during the Sakmarian and Kungurian. It was linked to the post-orogenic transpression/transtension tectonic movements that reflected the consolidation of the Variscan orogenic belt. The Permian-Triassic boundary magmatism was accompanied by extension, connected with the beginning of the Alpine Wilson cycle.

  18. Tiarajudens eccentricus and Anomocephalus africanus, two bizarre anomodonts (Synapsida, Therapsida) with dental occlusion from the Permian of Gondwana

    Cisneros, Juan Carlos; Abdala, Fernando; Jashashvili, Tea; de Oliveira Bueno, Ana; Dentzien-Dias, Paula

    2015-01-01

    Anomodontia was a highly successful tetrapod clade during the Permian and the Triassic. New morphological information regarding two bizarre basal anomodonts is provided and their palaeoecological significance is explored. The osteology of the recently discovered Tiarajudens eccentricus Cisneros et al. 2011, from the Brazilian Permian, is described in detail. The taxon exhibits unusual postcranial features, including the presence of gastralia. Additional preparation and computed tomography sca...

  19. Benthic aquatic ecosystems across the Permian-Triassic transition: record from biogenic structures in fluvial sandstones, central Transantarctic Mountains

    Miller, M. F.

    2000-07-01

    The effect of the Permian extinction in communities inhabiting sandy stream bottoms can be evaluated using trace fossils as proxies for body fossils. Permian and Triassic sandstones exposed in the Beardmore and Shackleton Glacier areas (central Transantarctic Mountains) were deposited in sandy braided streams and contain four types of trace fossils (vertical shafts and horizontal, bilobed and chevron traces). These traces were produced by a single type of animal that moved in the top 30 cm of sediment and dominated the benthic community. Evidence for a single producer includes similar size (diameter) of all traces and change within single specimens from one trace type to another. The animal was not affected by the Permian extinction event, as evidenced by its equal abundance within the Permian (Buckley Formation) and Triassic (Fremouw Formation) fluvial sandstones in the Beardmore Glacier area. Based on trace morphology and on domination of modern sandy river ecosystems by insects, the producer most likely was an insect, although its more precise identity is problematic. Although families of insects with modern aquatic burrowers are not known before the Jurassic, these trace fossils may show that these burrowers were present earlier than the insect body-fossil record suggests. Alternatively, archaic insect groups, many of which became extinct at the end-Permian and are known to have been aquatic but not infaunal, may have included some active burrowers that were unscathed by the Permian extinction.

  20. Distribution, Mineralogy, Petrography, Provenance and Significance of Permian Ash-Carrying Deposits in the Paraná Basin

    José Moacyr Vianna Coutinho

    Full Text Available The study of thin sections taken from drill core samples and outcrops in southern Brazil has demonstrated the occurrenceof repeated ash fall episodes during the Permian period between 280 and 245 Ma. Scattered or concentrated altered volcanicglass shards were detected in strata of Permian sedimentary rocks of the Rio Bonito and Tatui Formations. The shardcarryingsediment is usually a silty or cherty mudstone with variable amounts of calcrete calcite. Burial and alteration ofunstable glass debris led to the development of analcite and less commonly, calcite, silica minerals, zeolites or montmorillonite.Sources of explosive Permian volcanism, responsible for ample ash falls have been sought in South Africa, in the AndeanCordillera and along the Paraná Basin margin. A swarm of rhyolitic centers described in the Cordillera Frontal and in theCentral Argentinian Provincia de La Pampa (Patagonia is here proposed as the most adequate Permian source. In that area,volcanoes must have expelled ashes that traveled thousands of kilometers before settling in deltaic or shallow marineenvironments. Twenty-three occurrences of Permian shard-carrying sediments have been plotted in a Paraná Basin map. Thenumber of ash-carrying sediments decreases northeastward. The authors envisage dense clouds originated in Patagoniatraveling NE, depositing progressively smaller quantities of ashes but reaching Australia in pre-drift Gondwana. Shardcarrying sediments must be distinguished from “tonstein”, ash fall or ash flow tuffs, also recorded in the Permian Gondwana,which would indicate closer ash source area.

  1. Quantum and classical aspects of deformed c = 1 strings

    The quantum and classical aspects of a deformed c=1 matrix model proposed by Jevicki and Yoneya are studied. String equations are formulated in the framework of the Toda lattice hierarchy. The Whittaker functions now play the role of generalized Airy functions in c<1 strings. This matrix model has two distinct parameters. Identification of the string coupling constant is thereby not unique, and leads to several different perturbative interpretations of this model as a string theory. Two such possible interpretations are examined. In both cases, the classical limit of the string equations, which turns out to give a formal solution of Polchinski's scattering equations, shows that the classical scattering amplitudes of massless tachyons are insensitive to deformations of the parameters in the matrix model. (author)

  2. On consistent boundary conditions for c = 1 string theory

    O'Loughlin, M H

    1995-01-01

    We introduce a new parametrisation for the Fermi sea of the c = 1 matrix model. This leads to a simple derivation of the scattering matrix, and a calculation of boundary corrections in the corresponding 1+1--dimensional string theory. The new parametrisation involves relativistic chiral fields, rather than the non-relativistic fields of the usual formulations. The calculation of the boundary corrections, following recent work of Polchinski, allows us to place restrictions on the boundary conditions in the matrix model. We provide a consistent set of boundary conditions, but believe that they need to be supplemented by some more subtle relationship between the space-time and matrix model. Inspired by these boundary conditions, some thoughts on the black hole in c=1 string theory are presented.

  3. Coal Combustion Science

    Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  4. Intestinal and Hepatic Niemann-Pick C1-Like 1

    Sung-Woo Park

    2013-01-01

    Polytopic transmembrane protein, Niemann-Pick C1-Like 1 (NPC1L1) is localized at the apical membrane of enterocytes and the canalicular membrane of hepatocytes. It mediates intestinal cholesterol absorption and prevents extensive loss of cholesterol by transporting biliary cholesterol into hepatocytes. NPC1L1 is a molecular target of ezetimibe, an agent for hypercholesterolemia. Recently, NPC1L1 inhibition has been shown to prevent metabolic disorders such as fatty liver disease, obesity, dia...

  5. $C^{1,\\alpha}$ estimates for the parallel refractor

    Abedin, Farhan; Tralli, Giulio

    2016-01-01

    We consider the parallel refractor problem when the planar radiating source lies in a medium having higher refractive index than the medium in which the target is located. We prove local $C^{1,\\alpha}$ estimates for parallel refractors under suitable geometric assumptions on the source and target, and under local regularity hypotheses on the target set. We also discuss existence of refractors under energy conservation assumptions.

  6. On Consistent Boundary Conditions for c=1 String Theory

    O'Loughlin, Martin

    1995-01-01

    We introduce a new parametrisation for the Fermi sea of the $c = 1$ matrix model. This leads to a simple derivation of the scattering matrix, and a calculation of boundary corrections in the corresponding $1+1$--dimensional string theory. The new parametrisation involves relativistic chiral fields, rather than the non-relativistic fields of the usual formulations. The calculation of the boundary corrections, following recent work of Polchinski, allows us to place restrictions on the boundary ...

  7. Double-scaled field theory at c=1

    We investigate the double-scaled free fermion theory of the c=1 matrix model. We compute correlation functions of the eigenvalue density field and compare with the predictions of a relativistic boson theory. The c=1 theory behaves as a relativistic theory at long distances, but has softer behavior at short distances. The soft-distance behavior is closely related to the breakdown of the topological expansion at high energies. We also compute macroscopic loop amplitudes at c=1, finding an integral representation for n-loop amplitudes to all orders of perturbation theory. We evaluate the integrals explicitly for two, three, and four macroscopic loops. The small loop length asymptotic expansion then gives correlation functions of local operators in the theory. The two-macroscopic-loop formula gives information on the spectrum and wave functions in the theory. The three- and four-loop amplitudes give scattering amplitudes for tachyon operators to all orders of perturbation theory. Again, the topological expansion breaks down at high energies. We compare our amplitudes with predictions from the Liouville theory. (orig.)

  8. International perspectives on coal preparation

    NONE

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  9. Hydrotreating of coal-derived liquids

    Stohl, F.V.; Lott, S.E.; Diegert, K.V.; Goodnow, D.C.; Oelfke, J.B.

    1995-06-01

    The objective of Sandia`s refining of coal-derived liquids project is to determine the relationship between hydrotreating conditions and Product characteristics. The coal-derived liquids used in this work were produced In HTI`s first proof-of-concept run using Illinois No. 8 coal. Samples of the whole coal liquid product, distillate fractions of this liquid, and Criterion HDN-60 catalyst were obtained from Southwest Research Inc. Hydrotreating experiments were performed using a continuous operation, unattended, microflow reactor system. A factorial experimental design with three variables (temperature, (310{degrees}C to 388{degrees}C), liquid hourly space velocity (1 to 3 g/h/cm{sup 3}(cat)), pressure (500 to 1000 psig H{sub 2}) is being used in this project. Sulfur and nitrogen contents of the hydrotreated products were monitored during the hydrotreating experiments to ensure that activity was lined out at each set of reaction conditions. Results of hydrotreating the whole coal liquid showed that nitrogen values in the products ranged from 549 ppM at 320{degrees}C, 3 g/h/cm{sup 3}(cat), 500 psig H{sub 2} to <15 ppM at 400{degrees}C, 1 g/h/ cm{sup 3}(cat), 1000 psig H{sub 2}.

  10. Physiological implications of the abnormal absence of the parietal foramen in a late Permian cynodont (Therapsida)

    Benoit, Julien; Abdala, Fernando; Van den Brandt, Marc J.; Manger, Paul R.; Rubidge, Bruce S.

    2015-12-01

    The third eye (pineal eye), an organ responsible for regulating exposure to sunlight in extant ectotherms, is located in an opening on the dorsal surface of the skull, the parietal foramen. The parietal foramen is absent in extant mammals but often observed in basal therapsids, the stem-group to true mammals. Here, we report the absence of the parietal foramen in a specimen of Cynosaurus suppostus, a Late Permian cynodont from South Africa (SA). Comparison with Procynosuchus delaharpeae, a contemporaneous non-mammalian cynodont from SA, demonstrates that the absence of this foramen is an abnormal condition for such a basal species. Because seasonality was marked during the Late Permian in SA, it is proposed that the third eye was functionally redundant in Cynosaurus, possibly due to the acquisition of better thermoregulation or the evolution of specialized cells in the lateral eyes to compensate for the role of the third eye.