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1

Present and future position of palm oil industry in Malasia  

This paper introduces the present and future problems on the palm oil industry in Malaysia. The author was dispatched as an expert to the Malaysia Palm Oil Laboratory which is a governmental investigation organization. The cultivation area of oil palms were increased with the production of palm oil in 1990 - 1985. The oil mills produce average 20,000 tons/year of raw palm oil. 38 refining factories of the approved 75 factories are in work. The treatment capability of raw palm oil is 8.86 million tons/year. The palm oil is a solid vegetable oil at room temperature. For use the palm oil is fractionated into liquid palm olein, solid palm stearin, and palm oil with an intermediate melting point. About 90% of palm oil is edible. The leaves contain about 0.49% of alpha-tocopherol. The future problems to be solved lie in that the palm oil is improved to have a high liquid content, the production cost is reduced, and new uses for the palm oil are developed. (15 tabs, 37 refs)

2

An alternative energy source from palm wastes industry for Malaysia and Indonesia  

Malaysia and Indonesia are the largest producers of palm oil product. The palm oil industry has contributed the biggest income to the countries for many years. Moreover, palm oils has emerged as one of the most important oils in the world's oils and the market of fats. About 90% of palm oil is used as food related products worldwide, and the other 10% is used for basic raw material for soap. There are more than a hundred palm oil processing mills in the two countries. As such, a lot of savings can be done by using the fiber and shell from the processing wastes as an alternative fuel for electricity generation for this industry. This paper deals with energy conversion from the fiber and shell of the industry wastes as an alternative energy source for the palm oil mill industry in the two countries mentioned. The study concentrates on using the fiber and shell obtained from the processing of palm oil as fuels for the boiler instead of fossil fuel. In addition, the possibility of excess air and fuel air ratio for the fiber and shell combustion process is also discussed. Furthermore, it has been found that the shell and fiber alone can supply more steam and electricity than is required. Some palm oil mills in Malaysia and Indonesia have applied this strategy successfully. The FELDA palm oil mill, with the capacity 30-60 tons FFB/h, in Sungai Tengi, Selangor, Malaysia has been selected for this research. (Author)

3

Modern mill technology and centralised processing system, an alternative for improving performance of palm oil mills in Abia State, Nigeria  

An assessment of palm fruit processing technologies in Abia State palm oil industry was carried out in this study. About 95% of the mills were in the small scale category with capacities in the range 0.2-3.0 t/hr. Majority (80-90%) of the mills still utilized local drums for sterilisation of fruit and clarification of oil. Palm fruit digestion and oil extraction operations have been mechanised to some extent with about 90% of the mills having one device or the other to handle the operations. Hand-operated screw press was predominant (80%) in most of the mill as a device for palm oil extraction. Fruit stripping was manually carried out. Nut/fibre separation by mechanical method is adopted by small group (40%) of the mills and 90% of the mills utilize nut cracker to crack their nuts. Most of...

4

Life cycle assessment of two palm oil production systems  

In 2009 approx. 40 Mt of palm oil were produced globally. Growing demand for palm oil is driven by an increasing human population as well as subsidies for biodiesel and is likely to increase further in coming years. The production of 1 t crude palm oil requires 5 t of fresh fruit bunches (FFB). On average processing of 1 t FFB in palm oil mills generates 0.23 t empty fruit bunches (EFB) and 0.65 t palm oil mill effluents (POME) as residues. In this study it is assumed that land use change does not occur. In order to estimate the environmental impacts of palm oil production a worst and a best case scenario are assessed and compared in the present study using 1000 kg of FFB as functional unit. The production and treatment of one t FFB causes more than 460 kg CO"2"e"q in the worst case scenar...

5

Utilization of oil palm as a source of renewable energy in Malaysia  

Malaysia is currently the world's largest producer and exporter of palm oil. Malaysia produces about 47% of the world's supply of palm oil. Malaysia also accounts the highest percentage of global vegetable oils and fats trade in year 2005. Besides producing oils and fats, at present there is a continuous increasing interest concerning oil palm renewable energy. One of the major attentions is bio-diesel from palm oil. Bio-diesel implementation in Malaysia is important because of environmental protection and energy supply security reasons. This palm oil bio-diesel is biodegradable, non-toxic, and has significantly fewer emissions than petroleum-based diesel (petro-diesel) when burned. In addition to this oil, palm is also a well-known plant for its other sources of renewable energy, for example huge quantities of biomass by-products are developed to produce value added products such as methane gas, bio-plastic, organic acids, bio-compost, ply-wood, activated carbon, and animal feedstock. Even waste effluent; palm oil mill effluent (POME) has been converted to produce energy. Oil palm has created many opportunities and social benefits for the locals. In the above perspective, the objective of the present work is to give a concise and up-to-date picture of the present status of oil palm industry enhancing sustainable and renewable energy. This work also aims to identify the prospects of Malaysian oil palm industry towards utilization of oil palm as a source of renewable energy. (author)

6

Processing of fresh palm fruits using microwaves.  

Microwave heating was determined in this study to be suitable for the detachment and drying of palm fruits from whole bunches, cut bunches and spikelets. Microwave treatment of the palm fruits was able to attain the objectives of conventional fresh palm fruits sterilization processeses such as fruit softening, nut conditioning and halting of enzymatic lipolysis. Palm oil and kernel oil solvent extracted respectively from the microwave treated whole fruits and kernel were found to have a good quality of low free fatty acid content. This technology, together with the solvent extraction of the dehydrated fruits, may have the potential to be a continuous, dry and clean technology for palm oil milling. PMID:17645207

7

An experimental investigation to evaluate the heating value of palm oil waste by calorimetry. Paper no. IGEC-1-040  

A palm oil mill produces palm oil and kernel palm oil as main products and biomass residue (fiber and shell). This excess biomass residue can be used as fuel in boilers to meet energy and process heat demand in the industries. Quality of the palm oil waste (POW) is characterized by low fixed carbon and relatively high moisture content which may affect the heating value (HV). By applying the principle of calorimetry, a bomb calorimeter is utilized to evaluate the heating value of POW. From the experimental results, it is found that higher heating value (HHV) varies with the moisture content (MC) and it is observed as a function of MC. (author)

8

Innovation in the Malaysian Waste-to-Energy Sector: Applications with Global Potential  

Malaysia's innovations in electricity generation from waste incineration, landfill gas capture, and conversion of palm oil mill effluent and empty fruit bunches offer global lessons for converting trash and biomass into usable energy.

9

Integrated palm oil processing  

Tree palms are a promising source of fuel extenders and substitutes. They are perennials which bear oil for a period of two to three decades after a roughly four year preliminary growth period. Tree palms are now one of the most efficient energy crops: the best modern varieties can provide up to 6 tonnes per hectare per year of mesocarp and kernal oils. Palms are particularly attractive in areas where more conventional farming would pose a significant threat of laterization of cause major ecological problems. Technology for palm oil production is can range between village level manual operations and highly industrialized mills. Process energy is often supplied by combustion of byproducts. Although palm oil is a good energy crop, its physical and combustion properties preclude most use in conventional diesel engines, although palm oil could be directly blended with residual fuel oils for use in some large engines. At present, two uses for palm oil as a diesel fuel extender or substitute appear attractive: microemulsion blends using palm soapstock and monoesters produced by exchanging small alcohols for the glycerol in triglycerides. The amount of alcohols required for conversion of a substantial fraction of palm oil or palm oil soapstock to fuel extenders or substitutes is proportionately small, and, to a major extent, can be supplied by palm processing waste materials. Fermentation and gasification produced alcohols in the one to four carbon range are suitable for use in formulating palm oil based fuels. On a stoichiometric basis, it appears that the value of the palm oil and alcohols are very close to their value as export items. Use of these palm oil fuels could help to decrease balance of payments problems for developing countries, as well as provide a secure market for agricultural products and improved rural employment.

10

Insight into the applications of palm oil mill effluent: A renewable utilization of the industrial agricultural waste  

Water scarcity and pollution rank equal to climate change as the most intricate environmental turmoil for the 21st century. Today, the percolation of palm oil mill effluents into the waterways and ecosystems, remain a fastidious concern towards the public health and food chain interference. With the innovation of palm oil residue into a high valuable end commodity, there has been a steadily growing interest in this research field. Confirming the assertion, this paper presents a state of art review of palm oil mill effluent industry, its fundamental characteristics and environmental implications. Moreover, the key advance of its implementations, major challenges together with the future expectation are summarized and discussed. Conclusively, the expanding of palm oil mill effluent in numerous field of application represents a plausible and powerful circumstance, for accruing the worldwide environmental benefit and shaping the national economy. (author)

11

Numerical analysis of emission component from incineration of palm oil wastes  

In the last decade, there has been an increasing awareness of the use of by-products and wastes from palm oil mills with the dual objective of reducing their environmental impacts and enhancing the economic viability of the crop. The recycling aspects of palm oil cultivation and palm oil processing have been reviewed and have provided an indication of the present and future use of palm oil biomass current applications being mainly for organic fertilizers and fuel. In the present work, the emissions from incineration of two types of palm oil wastes (POW) fibre and shell are considered, and compared to fuel oil. The results, which indicate less pollutant emission from incineration of POW compared to that of fuel oil, have been presented graphically. (author)

12

Sustainability of palm oil production and opportunities for Finnish technology and know-how transfer  

The global demand for palm oil is growing, thus prompting an increase in the global production particularly in Malaysia and Indonesia. Such increasing demand for palm oil is due to palm oil's relatively cheap price and versatile advantage both in edible and non-edible applications. Along with the increasing demand for palm oil, particularly for the production of biofuel, is a heated debate on its sustainability. Ecological degradation, climate change and social issues are among the main sustainability issues pressing the whole palm oil industry today. Clean Development Mechanism (CDM) projects fulfilling the imperatives of the Kyoto Protocol are starting to gain momentum in Malaysia as reflected by the increasing registration of CDM projects in the palm oil mills. Most CDM projects in palm oil mills are on waste-to-energy, cocomposting, and methane recovery with the latter being the most common. The study on greenhouse gases (GHG) in the milling process points that biogas collection and energy utilisation has the greatest positive effect on GHG balance. On the other hand, empty fruit bunches (EFB) end-use as energy and high energy efficiency of the mill have the least effect on GHG balance of the mill. The range of direct GHG emissions from the palm oil mill is from 2.5 to 27 gCO{sub 2}e/MJ{sub CPO}, while the range of GHG emissions with all indirect and avoided emissions included is from -9 to 29 gCO{sub 2}e/MJ{sub CPO}. Comparing this GHG balance result with that of the EU RES-Directive suggests a further check on the values and emissions consideration of the latter. (orig.)

13

Biomass residues from plam oil mills in Thailand: an overview on quantity and potential usage  

Palm oil production is one of the major industries in the south of Thailand. A study of the quantity and potential usage of palm oil mill wastes was carried out. Sixteen palm oil mills in the region generate 386,930 tons/yr, 165,830 tons/yr and 110,550 tons/yr of empty fruit bunches, palm press fiber and palm kernel shell, respectively. In addition, 1,202,260 tons/yr of waste water is being treated anaerobically. Only the pericarp fiber is used for boiler feed. Empty fruit bunches and the shell are disposed of by the land filling method, which is very costly. In some factories the empty fruit bunches are burnt in the furnaces, which cause air pollution. The study suggests potential usages of the solid and liquid wastes. (author)

14

Isolation and characterization of high hydrogen-producing strain Clostridium beijerinckii PS-3 from fermented oil palm sap  

Felled oil palm trunk (OPT) (25 years old) is an abundant biomass in Southern Thailand. The OPT composition was 31.28-42.85% cellulose, 19.73-25.56% hemicellulose, 10.74-18.47% lignin, 1.63-2.25% protein, 1.60-1.83% fat, 1.12-1.35% ash and trace amount of minerals (0.01-0.40%). Oil palm sap extracted from OPT was found to contain 15.72 g/L glucose, 2.25 g/L xylose, and 0.086 g/L arabinose. A total of twenty samples from hot springs (45-75 ^oC and pH 6.5-8.4), oil palm sap and palm oil mill effluent were enriched for isolation of hydrogen-producing bacteria. The highest hydrogen-producing strain was isolated from oil palm sap and identified as Clostridium beijerinckii PS-3 using biochemical test and 16S rRNA gene analysis. Among various carbon sources tested, glucose, xylose, starch and cel...

15

Land application of biomass residue generated from palm oil processing: its potential benefits and threats  

Man???s increased demand for food and better living conditions has led to over exploitation of resources and the consequent generation of enormous amounts of liquid and solid waste materials. This is one of the global challenges for mankind. In Malaysia, palm oil mill waste (POMW) contributes the highest proportion of industrial solid wastes produced yearly. Wastes from the mills include palm oil mill effluent, decanter cake, empty fruit bunches, seed shells and the fibre from the mesocarp. Direct application of POMW into agricultural soil has resulted in a number of problems such as water pollution, leaching. However, with application rates specific for targeted plant species, land application can be employed as a permanent solution to the problem of waste from palm oil mills. This review...

16

Land application of biomass residue generated from palm oil processing: its potential benefits and threats  

Manâ??s increased demand for food and better living conditions has led to over exploitation of resources and the consequent generation of enormous amounts of liquid and solid waste materials. This is one of the global challenges for mankind. In Malaysia, palm oil mill waste (POMW) contributes the highest proportion of industrial solid wastes produced yearly. Wastes from the mills include palm oil mill effluent, decanter cake, empty fruit bunches, seed shells and the fibre from the mesocarp. Direct application of POMW into agricultural soil has resulted in a number of problems such as water pollution, leaching. However, with application rates specific for targeted plant species, land application can be employed as a permanent solution to the problem of waste from palm oil mills. This review...

17

Range of Choice in Palm Oil Processing Technologies for Cameroon.  

The report discusses the ecological, agronomic, and industrial factors affecting the economics of palm oil production. It begins by describing the characteristics of palm oil and palm kernel oils, and the cultivation and harvesting of oil palm. The curren...

18

Soft energy from palm oil and its wastes  

A time series analysis of energy sources showed that about 90% of the present energy needs of Malaysia come from petroleum. However, the photosynthetic conversion of sunlight to plant matter has been supplying energy to man for a long time. Traditionally firewood has been the direct source of photosynthetic energy, but this study proposes that energy can be obtained from the oil palm through the use of its product: the bunches, the fiber, the oil and the mill effluent. A scheme for the bioconversion of palm oil mill effluent through anaerobic digestion is presented. It was found that biogas generated from this process has an energy content of about 24.1 MJ/cubic meters of gas. The energy equivalent of this for a 60 ton/h mill was calculated at about 180 barrels of oil per day. An energy evaluation of all the wastes from the palm oil fruit was made and it revealed that this can satisfy approximately 17% of Malaysia's energy requirements, thus reducing her dependence upon petroleum. This study also suggests that with rising oil prices it will be appropriate to consider palm oil itself as an alternative fuel in our search for soft energy paths as it can account for about 20% of Malaysia's energy consumption. Developing countries in the tropics which depend heavily on imported petroleum can thus turn to bioconversion energy from the palm oil tree. (Refs. 13).

19

Economic analysis of biogas and compost projects in a palm oil mill with clean development mechanism in Malaysia  

This article is a case study to compare the economic viabilities of biogas generation and compost projects in a palm oil mill in Malaysia with and without clean development mechanism (CDM). Biogas is captured from anaerobic ponds or digester tanks treating palm oil mill effluent (POME) and converted to green renewable electricity for grid connection, while compost is produced from the shredded empty fruit bunch and raw untreated POME. The both technologies were compared by considering the changes of the materials flow and energy balances. A palm oil mill with a capacity of 54?t fresh fruit bunch per hour has the potential to produce either 6.9?GWh of electricity from biogas or fertilizer equivalent to 488?t of nitrogen, 76?t of phosphorus and 1,065?t of potassium per year. The economic ana...

20

Economic analysis of biogas and compost projects in a palm oil mill with clean development mechanism in Malaysia  

This article is a case study to compare the economic viabilities of biogas generation and compost projects in a palm oil mill in Malaysia with and without clean development mechanism (CDM). Biogas is captured from anaerobic ponds or digester tanks treating palm oil mill effluent (POME) and converted to green renewable electricity for grid connection, while compost is produced from the shredded empty fruit bunch and raw untreated POME. The both technologies were compared by considering the changes of the materials flow and energy balances. A palm oil mill with a capacity of 54 t fresh fruit bunch per hour has the potential to produce either 6.9 GWh of electricity from biogas or fertilizer equivalent to 488 t of nitrogen, 76 t of phosphorus and 1,065 t of potassium per year. The economic ana...

 
 
 
 
21

Benefits of clean development mechanism application on the life cycle assessment perspective: a case study in the palm oil industry.  

This study performed an assessment on the beneficial of the Clean Development Mechanism (CDM) application on waste treatment system in a local palm oil industry in Malaysia. Life cycle assessment (LCA) was conducted to assess the environmental impacts of the greenhouse gas (GHG) reduction from the CDM application. Calculations on the emission reduction used the methodology based on AM002 (Avoided Wastewater and On-site Energy Use Emissions in the Industrial Sector) Version 4 published by United Nations Framework Convention on Climate Change (UNFCC). The results from the studies showed that the introduction of CDM in the palm oil mill through conversion of the captured biogas from palm oil mill effluent (POME) treatment into power generation were able to reduce approximate 0.12 tonnes CO2 equivalent concentration (tCO2e) emission and 30 kW x hr power generation per 1 tonne of fresh fruit bunch processed. Thus, the application of CDM methodology on palm oil mill wastewater treatment was able to reduce up to 1/4 of the overall environment impact generated in palm oil mill. PMID:22482288

22

Potential for using enriched cultures and thermotolerant bacterial isolates for production of biohydrogen from oil palm sap and microbial community analysis  

A limited number of bacteria can convert oil palm (Elaeis guineensis) sap to hydrogen with satisfactory yield and productivity. In this study, a total of 18 fermentative enriched cultures and 36 newly isolated thermotolerant bacterial strains were compared for hydrogen production from oil palm (OP) sap. The new isolates were obtained from hot springs, palm oil mill effluent and oil palm sap. The test was conducted in three steps: (i) a test for hydrogen production from mixed substrates (cellulose, starch, xylose, and glucose) and OP sap; (ii) a test for substrate concentration tolerance; and (iii) a test for thermotolerance. Five enriched candidates for each of the hydrogen producers were selected according to the criteria defined for the screening test. The hydrogen production of these se...

23

Cogeneration potential in the Columbian palm oil industry: Three case studies  

The palm oil mills are characterized by the availability of considerable amounts of by-products of high-energy value such as empty fruit bunches (EFB), fibers, shells and liquid effluents with high content of organics called palm oil mill effluent (POME). A palm oil mill produces residues equivalent to almost three times the amount of oil produced by biomass, showing a huge potential for increasing the power efficiency of the plants and installed power, mainly by the use of by-products in cogeneration plants with high steam parameters and by reducing steam consumption in process. The objective of this paper is to present the results of the study about the cogeneration potential for three representative palm oil mills located in two important palm oil producing regions in Colombia (South-America), fifth palm oil producers of the world. The sizing of the cogeneration system was made assuming it operation during the greatest possible number of hours throughout the year (based on the seasonal availability of fruit) considering parameters for the steam at 2 MPa and 350 C, using a condensing-extraction turbine. The balance of mass and energy was made by using the Gate Cycle Enter Software, version 5.51, to estimate the potential of electricity generation. The results showed that for fresh fruit bunch (FFB) processing capacities between 18 and 60 t FFB h{sup -1}, it is possible to have surplus power ranging between 1 and 7 MW, if the plants are self-sufficient in electric energy and steam for process. With an average Capacity Factor (approximately 0.4), it is possible to expect a generation index of 75 and 160 kWh t{sup -1} FFB when the processing plant is operating or shutdown, respectively, 3 or 4 times better than when a traditional system with a back-pressure steam turbines is used. This analysis used up to 60% of EFB produced in plant as fuel, considering its value as fertilizer for the palm crop. Several economic conditions were considered to estimate the economic and technical feasibility of cogeneration systems in palm oil mill for Colombian palm oil sector. (author)

24

Biotechnological applications for the utilisation of wastes from palm oil mills  

The milling of oil palm fruits produces about two-and-a-half to three times as much effluent as oil does. It also generates a large amount of lignocellulosic wastes, mainly in the form of empty fruit bunches, press cake fibres and nut shell. Research efforts at PORIM have been directed towards the utilisation of these wastes as a means to solve the problem of environmental pollution as well as for the generation of economic returns for the mills. We have studied a thermophilic contact process for the anaerobic digestion of palm oil mill effluent and its potential for generating biogas for energy uses. Our work has also shown that the condensate derived from the fruit sterilisation process during milling is amenable to fermentation for the production of single cell protein (SCP) and exo-enzymes. The enzymes produced have been applied for oil clarification, oil recovery from press cake fibers and saccharification of the fibers for the production of sugar feedstocks. This paper will also introduce the concept of integrated waste management for the palm oil mill through the implementation of these technologies.

25

Producer gas from palm fruit shells as fuel for small internal combustion engines  

The palm oil industry is one of the agro-industrial sectors producing the highest quantities of residues in Malaysia. Approximately 1.4 million metric tonnes of palm fruit were are produced by palm oil mills throughout Malaysia in 1993. Its utilisation is merely confined to producing heat in furnaces for steam raising and the sterilization of oil palm fruits. A small gasification plant using palm fruit shells as fuel feed has been developed to address the issue of disposing this excessive agricultural residue. The system is capable of producing gaseous fuel with heating value of 4.5 MJ/m{sup 3}. The plant consist of a 15kg-capacity downdraft gasifier, a gas cleaning tray, a gas combustion chamber and an engine-dynamometer arrangement. Metered quantity of the gas is supplied to the engine whilst the balance is flared in the gas combustion chamber. With the engine subjected to the gaseous and liquid fuels alternately, a comparative study was made pertaining to its performance. The early findings have indicated that the palm oil mills by-product is a potential fuel for internal combustion engines as well as for heating if it is properly synthesized. (author)

26

An experimental investigation to evaluate the heating value of palm oil waste by calorimetry  

Malaysia is one of the world's largest palm oil producing countries, accounting for nearly 50 per cent of the total world production. Palm oil mills produce palm oil and kernel palm oil as the main products. Excess biomass residue in the form of fiber and shell is also produced, which can be used as fuel in boilers to meet energy and process heat demand in the industries. The total biomass energy potential is estimated to be equivalent to 2 to 3 per cent of the total power produced in the country. In order to evaluate the potential of biomass solid as a fuel in the combustion system, it is necessary to know the heating value of the biomass solid. This parameter is typically a function of the fuel composition. The key parameter that influences the thermal efficiency of palm oil waste (POW) is moisture content when it is burned. This paper described how the higher heating value (HHV) of POW is determined using a calorimeter. HHV was correlated as a function of moisture content (MC) for palm oil fibre and shells. In this study, the quality of the POW was characterized by low fixed carbon and relatively high moisture content that could influence the heating value. Experimental results indicate that HHV varies with MC. A linear correlation was made between HHV and MC. 8 refs., 4 tabs., 3 figs.

27

Baseline study of methane emission from anaerobic ponds of palm oil mill effluent treatment  

The world currently obtains its energy from the fossil fuels such as oil, natural gas and coal. However, the international crisis in the Middle East, rapid depletion of fossil fuel reserves as well as climate change have driven the world towards renewable energy sources which are abundant, untapped and environmentally friendly. Malaysia has abundant biomass resources generated from the agricultural industry particularly the large commodity, palm oil. This paper will focus on palm oil mill effluent (POME) as the source of renewable energy from the generation of methane and establish the current methane emission from the anaerobic treatment facility. The emission was measured from two anaerobic ponds in Felda Serting Palm Oil Mill for 52 weeks. The results showed that the methane content was between 35.0% and 70.0% and biogas flow rate ranged between 0.5 and 2.4 L/min/m{sup 2}. Total methane emission per anaerobic pond was 1043.1 kg/day. The total methane emission calculated from the two equations derived from relationships between methane emission and total carbon removal and POME discharged were comparable with field measurement. This study also revealed that anaerobic pond system is more efficient than open digesting tank system for POME treatment. Two main factors affecting the methane emission were mill activities and oil palm seasonal cropping. (author)

28

Discrimination of palm olein oil and palm stearin oil mixtures using a mass spectrometry based electronic nose  

To discriminate mixing ratios for mixtures of palm olein oil and palm stearin oil, an electronic nose based on mass spectrometer (MS-electronic nose) and GC were used. The intensities of each fragment from the palm olein oil and palm stearin oil by the MS-electronic nose were used for discriminant function analysis (DFA). When palm olein oil is mixed with palm stearin oil, more than 3% of stearin oil can be estimated by DFA. The obtained data were used for DFA. DFA plot indicated a significant separation of pure palm olein oil and palm stearin oil. The added concentration of palm stearin oil to palm olein oil was highly correlated with the first discriminant function score (DF1). When palm stearin oil was added to palm olein oil, it was possible to predict the following equation; DF1= ?0.1...

29

Life cycle assessment of palm biodiesel: Revealing facts and benefits for sustainability  

Similarity between the properties of biodiesel and petroleum-derived diesel has made the former one of the most promising alternatives to a renewable and sustainable fuel for the transportation sector. In Malaysia, palm oil can be a suitable feedstock for the production of biodiesel due to its abundant availability and low production cost. However, not many assessments have been carried out regarding the impacts of palm biodiesel on the environment. Hence, in this study, life cycle assessment (LCA) was conducted for palm biodiesel in order to investigate and validate the popular belief that palm biodiesel is a green and sustainable fuel. The LCA study was divided into three main stages, namely agricultural activities, oil milling and transesterification process for the production of biodiesel. For each stage, the energy balance and green house gas assessments were presented and discussed. These are important data for the techno-economical and environmental feasibility evaluation of palm biodiesel. The results obtained for palm biodiesel were then compared with rapeseed biodiesel. From this study, it was found that the utilization of palm biodiesel would generate an energy yield ratio of 3.53 (output energy/input energy), indicating a net positive energy generated and ensuring its sustainability. The energy ratio for palm biodiesel was found to be more than double that of rapeseed biodiesel which was estimated to be only 1.44, thereby indicating that palm oil would be a more sustainable feedstock for biodiesel production as compared to rapeseed oil. Moreover, combustion of palm biodiesel was found to be more environment-friendly than petroleum-derived-diesel as a significant 38% reduction of CO{sub 2} emission can be achieved per liter combusted. (author)

30

Phytonutrient deficiency: the place of palm fruit.  

The oil palm (Elaeis guineensis) is native to many West African countries, where local populations have used its oil for culinary and other purposes. Large-scale plantations, established principally in tropical regions (Asia, Africa and Latin America), are mostly aimed at the production of oil, which is extracted from the fleshy mesocarp of the palm fruit, and endosperm or kernel oil. Palm oil is different from other plant and animal oils in that it contains 50% saturated fatty acids, 40% unsaturated fatty acids, and 10% polyunsaturated fatty acids. The fruit also contains components that can endow the oil with nutritional and health beneficial properties. These phytonutrients include carotenoids (alpha-,beta-,and gamma-carotenes), vitamin E (tocopherols and tocotrienols), sterols (sitosterol, stigmasterol and campesterol), phospholipids, glycolipids and squalene. In addition, it is recently reported that certain water-soluble powerful antioxidants, phenolic acids and flavonoids, can be recovered from palm oil mill effluent. Owing to its high content of phytonutrients with antioxidant properties, the possibility exists that palm fruit offers some health advantages by reducing lipid oxidation, oxidative stress and free radical damage. Accordingly, use of palm fruit or its phytonutrient-rich fractions, particularly water-soluble antioxidants, may confer some protection against a number of disorders or diseases including cardiovascular disease, cancers, cataracts and macular degeneration, cognitive impairment and Alzheimer's disease. However, whilst prevention of disease through use of these phytonutrients as in either food ingredients or nutraceuticals may be a worthwhile objective, dose response data are required to evaluate their pharmacologic and toxicologic effects. In addition, one area of concern about use of antioxidant phytonutrients is how much suppression of oxidation may be compatible with good health, as toxic free radicals are required for defence mechanisms. These food-health concepts would probably spur the large-scale oil palm (and monoculture) plantations, which are already seen to be a major cause of deforestation and replacement of diverse ecosystems in many countries. However, the environmental advantages of palm phytonutrients are that they are prepared from the readily available raw material from palm oil milling processes. Palm fruit, one of only a few fatty fruits, is likely to have an increasingly substantiated place in human health, not only through the provision of acceptable dietary fats, but also its characteristic protective phytonutrients. PMID:14506002

31

Oil palm plantation effects on water quality in Kalimantan, Indonesia  

Global demand for palm oil has stimulated a 7-fold increase in oil palm (Elaeis guineensis) plantation area in Indonesia since 1990. Expansion will continue as Indonesia plans to double current production by 2020. Oil palm fertilizers, effluent from oil palm mills, and erosion from land clearing and roads threaten river water quality near plantations. These rivers provide essential ecosystem services including water for drinking, cooking, and washing. Robust empirical measurements of plantation expansion impacts on water resources are necessary to discern the effects of agribusiness on local livelihoods and ecosystems. In Ketapang District, West Kalimantan, Indonesian Borneo, we evaluated the effects of land cover change on water quality by assessing water chemistry in streams draining four end-member watersheds ( ~600-1900 ha watershed-1): Logged forest, mixed agro-forest dominated by rubber and upland rice fallows, young oil palm forest (0-5 years), and old oil palm forest (10-15 years). To assess land cover change, we used CLASLite software to derive fractional cover from a time series (1989-2008) of Landsat data. Nearest neighbor classification and post-classification change detection yielded classes including primary forest, logged forest, secondary forest regrowth, smallholder agriculture, and oil palm. Stream water quality (temperature, dissolved oxygen, turbidity, optical chlorphyll, and pH) and quantity (discharge) were quantified with the YSI 6600-V2 sonde. The sonde was deployed in each stream for month-long intervals 2-3 times from 2009-2010. Such extended deployment captures episodic events such as intense storms and allows examination of interdiel dynamics by sampling continuously and at high frequency, every 10 minutes. We find that across the Ketapang District study region (~12,000 km2), oil palm has cleared mostly forests (49%) and agroforests (39%). What are the impacts of such land cover changes on water quality? Compared to forests and agroforests, streams draining oil palm show greater biological activity, as indicated by elevated pH and reduced dissolved oxygen levels. Moreover, turbidity is elevated in young oil palm plantations watersheds compared to forest, agroforest, and old oil palm land covers. We discuss the implications of these findings for communities and ecosystems.

32

Simultaneous thermophilic hydrogen production and phenol removal from palm oil mill effluent by Thermoanaerobacterium-rich sludge  

Thermoanaerobacterium-rich sludge was used for hydrogen production and phenol removal from palm oil mill effluent (POME) in the presence of phenol concentration of 100-1000 mg/L. Thermoanaerobacterium-rich sludge yielded the most hydrogen of 4.2 L H"2/L-POME with 65% phenol removal efficiency at 400 mg/L phenol. Butyric acid and acetic acid were the main metabolites. The effects of oil palm ash, NH"4NO"3 and iron concentration (Fe^2^+) on hydrogen production and phenol removal efficiency from POME by Thermoanaerobacterium-rich sludge was investigated using response surface methodology (RSM). The RSM results indicated that the presence of 0.2 g Fe^2^+/L, 0.3 g/L NH"4NO"3 and 20 g/L oil palm ash in POME could improved phenol removal efficiency, with predicted hydrogen production and phenol r...

33

Heat of hydration of blended cement containing treated ground palm oil fuel ash  

The aim of this paper is to study the heat of hydration of blended cement containing ground palm oil fuel ash and treated ground palm oil fuel ash (without unburned carbon), with and without superplasticizer (SP). The palm oil fuel ash (POFA) was ground in a ball mill to produce ground POFA (GPOFA). Unburned carbon, which is a major part of unburned residue in GPOFA, was removed by heat treatment at 500^oC for 1h, producing treated GPOFA (TGPOFA). This result shows that the total heat of hydration of blended cement pastes containing GPOFA and TGPOFA are lower than OPC paste, proving that GPOFA and TGPOFA are good pozzolanic materials which can be used in massive concrete for preventing volume change and micro-cracks (caused by thermal stresses). Also, GPOFA and TGPOFA have low pozzolanic r...

34

Effect of steam pretreatment on oil palm empty fruit bunch for the production of sugars  

Lignocellulose into fuel ethanol is the most feasible conversion route strategy in terms of sustainability. Oil palm empty fruit bunch (EFB) generated from palm oil production is a huge source of cellulosic material and represents a cheap renewable feedstock which awaits further commercial exploitation. The purpose of this study was to investigate the feasibility of using steam at 0.28 MPa and 140 ^oC generated from the palm oil mill boiler as a pretreatment to enhance the digestibility of EFB for sugars production. The effects of steam pretreatment or autohydrolysis on chemical composition changes, polysaccharide conversion, sugar production and morphology alterations of four different types of EFB namely fresh EFB (EFB1), sterilized EFB (EFB2), shredded EFB (EFB3) and ground EFB (EFB4) w...

35

Environmental sustainability assessment of palm biodiesel production in Thailand  

The study assesses the environmental sustainability of palm biodiesel production systems in Thailand by focusing on their energy efficiency and environmental impact potentials. The Net Energy Balance (NEB) and Renewability indicate energy gain for palm biodiesel and its co-products as compared to fossil energy inputs. In addition, life cycle assessment also reveals lower values of environmental impact potentials of biodiesel as compared to conventional diesel. For example, palm biodiesel can provide greenhouse gas (GHG) reduction of around 46-73% as compared to diesel. Nitrogen-fertilizer production and application in the plantation and the air emissions from the ponds treating palm oil mill effluent (POME) are found to be the major environmental aspects. However, the energy and environmen...

36

Pollution control technologies for the treatment of palm oil mill effluent (POME) through end-of-pipe processes.  

Palm oil production is one of the major industries in Malaysia and this country ranks one of the largest productions in the world. In Malaysia, the total production of crude palm oil in 2008 was 17,734,441 tonnes. However, the production of this amount of crude palm oil results in even larger amounts of palm oil mill effluent (POME). In the year 2008 alone, at least 44 million tonnes of POME was generated in Malaysia. Currently, the ponding system is the most common treatment method for POME but other processes such as aerobic and anaerobic digestion, physicochemical treatment and membrane filtration may also provide the palm oil industries with possible insights into the improvement of POME treatment processes. Generally, open ponding offers low capital and operating costs but this conventional method is becoming less attractive because the methane produced is wasted to the atmosphere and the system can not be certified for Carbon Emission Reduction trading. On the other hand, anaerobic digestion of POME provides the fastest payback of investment because the treatment enables biogas recovery for heat generation and treated effluent for land application. Lastly, it is proposed herewith that wastewater management based on the promotion of cleaner production and environmentally sound biotechnologies should be prioritized and included as a part of the POME management in Malaysia for attaining sustainable development. This paper thus discusses and compares state-of-the-art POME treatment methods as well as their individual performances. PMID:20231054

37

Characterization of adsorbent prepared from oil-palm shell by CO{sub 2} activation for removal of gaseous pollutants  

Characterization of activated carbon prepared from oil-palm shell, an abundant agricultural solid waste from palm-oil processing mills in some tropical countries, by carbon dioxide (CO{sub 2}) activation was carried out in this paper. The effects of activation temperature on the textural and chemical properties of the activated carbon were studied. It was found that significant weight losses occurred during the activation process due to continual release of volatile matter and carbon burn-off through weak carbon-CO{sub 2} oxidation, resulting in an increase of solid density and a decrease of apparent density. Hence, the activated carbons prepared from oil-palm shells possessed well-developed porosities and predominant microporosities, which were verified by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), respectively. The development of microporosity for the oil-palm-shell activated carbon would lead to potential applications in gas-phase adsorption for the removal of air pollutants. Adsorption test results showed a linear relationship between the BET surface area and the adsorptive capacity for both nitrogen dioxide (NO{sub 2}) and ammonia (NH{sub 3}) gases. This could be elucidated by the neutral surface functional groups of the oil-palm-shell activated carbon, as detected by Fourier Transform Infrared Spectroscopy (FTIR)

38

European Policies towards Palm Oil - Sorting Out some Facts  

This paper analyses the role of palm oil and its sustainability from different perspectives. We consider the role of palm oil within the GHG context. We discuss the impact of palm oil on biodiversity and analyse how palm oil can contribute to economic growth and development in tropical countries. Fi...

39

An integrated anaerobic-aerobic bioreactor (IAAB) for the treatment of palm oil mill effluent (POME): Start-up and steady state performance  

Palm oil mill effluent (POME) with average chemical oxygen demand (COD) and biochemical oxygen demand (BOD) of 70,000 and 30,000mg/L, respectively, can cause serious environmental hazards if discharged untreated. There are conventional palm oil mill effluent (POME) treatment systems that require large footprint, long HRT and fail to meet the Malaysian Department of Environment (DOE) discharge limit. Hence, the current research is aimed to design a novel integrated anaerobic-aerobic bioreactor (IAAB) for POME treatment in order to overcome these shortcomings of the conventional system. IAAB is a new bioreactor configuration which integrates anaerobic and aerobic digestion in one reactor. The overall removal efficiencies in steady state condition in terms of chemical oxygen demand (COD), bio...

40

Briquetting of palm fibre and shell from the processing of palm nuts to palm oil  

Malaysia is the major producer of palm oil in the world. It produces 8.5 million tonnes per year (8.5x10{sup 6} ty{sup -1}) of palm oil from 38.6x10{sup 6} ty{sup -1} of fresh fruit bunches. Palm oil production generates large amounts of process residues such as fibre (5.4x10{sup 6} ty{sup -1}), shell (2.3x10{sup 6} ty{sup -1}), and empty fruit bunches (8.8x10{sup 6} ty{sup -1}). A large fraction of the fibre and much of the shell are used as fuel to generate process steam and electricity in the palm processing mill itself. However, much is wasted by pile burning in the open air with attendant air pollution, dumped in areas adjacent to the mill, or utilized as manure in the palm oil plantation. In this paper, an attempt has been made to convert these residues into solid fuel. The palm shell and fibre is densified into briquettes of diameter 40, 50 and 60mm under moderate pressure of 5-13.5 MPa in a hydraulic press. Experiments are carried out to determine density, durability, impact and compressive strength of the briquettes. The heating value, burning characteristics, ash and moisture content are other objects of the study. A relationship between press pressure and the briquette density has been established. The produced briquettes have densities between 1100 and 1200 kgm{sup -3}. The briquettes properties are quite good with good resistance to mechanical disintegration, and will withstand wetting. The gross calorific value is about 16.4 MJkg{sup -1} (maf), and the ash content is about 6% and the equilibrium moisture content is about 12%. Further work is required to acquire complete understanding of the densification process before good quality and durable briquettes could be made free from cracks. (Author)

 
 
 
 
41

Economic optimisation potentials of the energetic utilisation of palm oil; Oekologische Optimierungspotenziale der energetischen Nutzung von Palmoel  

Aim and background: The use of palm oil for bioenergy has become increasingly important for Europe in the last years because of its favourable proportion of yield to area under cultivation. Thus, palm oil presents a low-priced alternative to other energy sources, e.g. rapeseed oil. Currently, however, palm oil gets a bad press due to new studies about the negative environmental consequences of cultivation practices. Due to the high demand for palm oil, land is becoming scarce. This results in the clearing of primary forests and consequently in the loss of biodiversity and in an increase of greenhouse gas emissions. To reduce the latter, not only the process of oil palm cultivation has to be optimised but also the practice of establishing new plantations by clearing natural forests has to be questioned. The aim of this article is to disclose potentials for greenhouse gas reductions in existing as well as in newly-planned oil palm plantations. Results and discussion: For existing oil palm plantations, two main fields for possible optimisation can be identified: one is improving the plantation management, the other is increasing the efficiency of the utilisation of waste products such as fibres and husks or oil mill effluents. For newly-planned oil palm plantations alternative land use scenarios have to be considered. The results show a big potential for optimisation. Thus, the greenhouse gas balance improves slightly if plantations are run more efficiently. If the waste products are used to generate energy, there are significantly positive effects on the greenhouse gas balance, especially through the reduction of methane emissions. By running a plantation in a professional best-practice way, 4.8 t of greenhouse gases can be saved annually per hectare cultivation area, expressed as CO{sub 2} equivalents. If newly-planned oil palm plantations are established on fallow land, greenhouse gas emissions can be further reduced by an additional 4.8 t of CO{sub 2} equivalents per hectare and year. From an economic perspective, this may be more costly than clearing primary forest but it is advantageous for both the greenhouse gas balance and the biodiversity of the concerned areas. All in all, exploiting the whole potential for optimisation could result in the saving of 10.2 t CO{sub 2} equivalents per hectare and year more than it is the case in the existing mode of cultivation. Conclusions and perspectives: Due to the high demand of palm oil by the world market, cultivation areas for oil palms are becoming increasingly scarce. Thus, it is vital to exploit the fuel potential of oil palm cultivation in an environmentally and economically sustainable way. The management of plantations has to be optimised and a generally valid waste management system must be implemented in existing and future plantations. New plantations should preferably be established on fallow land, not by the clearing of primary forests. It is essential for a sustainable palm oil production to tap the full potential for optimisation. This, however, is currently not happening due to the high start-up investments. It is thus recommended to introduce an internationally valid certification system which may provide an incentive for more sustainable and effective production methods. (orig.)

42

Electrocoagulation of palm oil mill effluent as wastewater treatment and hydrogen production using electrode aluminum.  

Palm oil mill effluent (POME) is highly polluting wastewater generated from the palm oil milling process. Palm oil mill effluent was used as an electrolyte without any additive or pretreatment to perform electrocoagulation (EC) using electricity (direct current) ranging from 2 to 4 volts in the presence of aluminum electrodes with a reactor volume of 20 L. The production of hydrogen gas, removal of chemical oxygen demand (COD), and turbidity as a result of electrocoagulation of POME were determined. The results show that EC can reduce the COD and turbidity of POME by 57 and 62%, respectively, in addition to the 42% hydrogen production. Hydrogen production was also helpful to remove the lighter suspended solids toward the surface. The production of Al(OH)XHO at the aluminum electrode (anode) was responsible for the flocculation-coagulation process of suspended solids followed by sedimentation under gravity. The production of hydrogen gas from POME during EC was also compared with hydrogen gas production by electrolysis of tap water at pH 4 and tap water without pH adjustment under the same conditions. The main advantage of this study is to produce hydrogen gas while treating POME with EC to reduce COD and turbidity effectively. PMID:21712603

43

The political ecology of land management in the oil palm based cropping system on the Adja plateau in Benin  

The Adja plateau (Benin) is densely populated by tenant and landowner farmers engaged in oil palm based cropping. Landowners use oil palm sap for the production of sodabi (a local spirit), and an oil palm fallow (if no crops are grown beneath the palms) to restore soil fertility. In this area, growing oil palm for its oil is uncommon. Tenants access the land under specific contracts but are not allowed to plant oil palm. They grow food crops beneath the oil palm and extend the cropping period by severely pruning the palms because their right to grow food crops terminates when the palms reach a height of 2m. The competing claims between landowners and tenants and between oil palm and annual food crops result in conflicts over practices that either degrade or restore soil fertility. Using a ...

44

Analytical characteristics of crude and refined palm oil and fractions  

Palm oil provides significantly higher amounts of oil/ha than any other commercial oil crop. Palm oil can be physically refined and fractionated into various fractions, ranging from very hard palm stearin with iodine values below 10 to palm superolein with iodine values as high as 72. Palm mid fractions consisting of symmetrical triacylglycerols provide sharp-melting fats for niche applications. The wide range of palm oil fractions provides versatility for different food applications, with the additional advantage that natural palm oil is trans free and genetic modification free. Palm oil and its fractions are widely used for direct blending with other oils or are interesterified with other oils to meet the trans-free fat requirements of the food industry. The sn-2 position of palm oil tri...

45

Optimization of carotene recovery from extracted oil of POME by adsorption chromatography using response surface methodology  

The recovery of carotene from extracted oil of palm oil mill effluent (POME) was optimized by the simultaneous maximization of the carotene recovery in hexane fraction, carotene concentration and oil recovery. A central composite design consisting of 20 runs was then applied to study the factors of temperature, solvent amount and oil:adsorbent ratio. A second-order polynomial model was used to describe the experimental data regarding the responses. The main factors, solvent amount and oil:adsorbent ratio were the significant model terms for carotene and oil recoveries whereas oil:adsorbent ratio was the significant model term for carotene concentration. The optimum conditions for carotene recovery were predicted to be 40^oC, 200mL solvent and 1:4.36 of oil to adsorbent ratio and the corres...

46

Coconut, Date and Oil Palm Genomics  

A review of genomics research is presented for the three most economically important palm crops, coconut (Cocos nucifera), date palm (Phoenix dactylifera) and oil palm (Elaeis guineensis), encompassing molecular markers studies of genetic diversity, genetic mapping, quantitative trait loci discovery...

47

Development and characterisation of novel heterogeneous palm oil mill boiler ash-based catalysts for biodiesel production  

Novel heterogeneous catalysts from calcium oxide (CaO)/calcined calcium carbonate (CaCO3) loaded onto different palm oil mill boiler ashes were synthesised and used in the transesterification of crude palm oil (CPO) with methanol to yield biodiesel. Catalyst preparation parameters including the type of ash support, the weight percentage of CaO and calcined CaCO3 loadings, as well as the calcination temperature of CaCO3 were optimised. The catalyst prepared by loading of 15wt% calcined CaCO3 at a fixed temperature of 800degreeC on fly ash exhibited a maximum oil conversion of 94.48%. Thermogravimetric analysis (TGA) revealed that the CaCO3 was transformed into CaO at 770degreeC and interacted well with the ash support, whereas rich CaO, Al2O3 and SiO2 were identified in the composition usin...

48

Improvement potential for net energy balance of biodiesel derived from palm oil: A case study from Indonesian practice  

Biodiesel derived from palm oil has been recognized as a high-productivity oil crop among the first generation of biofuels. This study evaluated and discussed the net energy balance for biodiesel in Indonesia by calculating the net energy ratio (NER) and net energy production (NEP) form the total energy input and output. The results of the calculation of energy input for the default scenario demonstrated that the primary energy inputs in the biodiesel production lifecycle were the methanol feedstock, energy input during the biodiesel production process, and urea production. These three items amounted to 85% of the total energy input. Next, we considered and evaluated ways to potentially improve the energy balance by utilizing by-products and biogas from wastewater treatment in the palm oil mill. This result emphasized the importance of utilizing the biomass residue and by-products. Finally, we discussed the need to be aware of energy balance issues between countries when biofuels are transported internationally. (author)

49

Antioxidants from palm (Elaeis guineensis) fruit extracts.  

Background - Phenolic compounds have been shown to exhibit bioactive properties, and in particular antioxidant effects. A phenolic-rich fraction has been isolated from the aqueous by-product obtained during the milling of oil palm fruits. Objective - To characterise the phenolic compounds obtained from crude and ethanolic extracts of oil palm fruits and to evaluate the antioxidant properties of these extracts. Design - Characterisation of the profile of phenolics by NMR spectroscopy and evaluation of antioxidant properties using the 1,1-diphenyl-2-picrylhydrazyl radical (DPPH.), reducing power, and hydrogen peroxide scavenging assays. Outcomes - NMR studies indicate that both extracts consist of mixtures of sugars and phenolic compounds, of which gallic acid and 4-hydroxybenzoate predominate. The antiradical power (ARP, mole ratios expressed in arbitrary units) of the crude extract (3.14) and ethanol extract (3.31), measured by the DPPH. assay were comparable to the ARP of ascorbic acid (3.78). Crude and ethanol extracts of 1mM gallic acid equivalence (GAE) had reducing powers comparable to that of 0.3 mM gallic acid. In the hydrogen peroxide scavenging assay, 100% scavenging was achieved at concentration of 0.3 mM GAE for both crude and ethanol extracts. Conclusions - These findings suggest that oil palm fruit extracts are able to act as primary antioxidants by their hydrogen- and electron-donating capacity. Similar findings have been reported for extracts from olives and tea. These preliminary observations also suggest that oil palm fruit extracts are potential sources of nutraceuticals. PMID:15023645

50

Palm oil boom in Indonesia: from plantation to downstream products and biodiesel  

Indonesia has been the biggest producer of palm oil (PO) in the world since 2005. The total production in 2007 was 17.0 and 1.9 million tons of crude palm oil (CPO) and crude palm kernel oil (CPKO), respectively. More than 70% of the CPO was exported and 87% of the domestic consumption was used for food. The production and subsequent refining and fractionation of CPO and CPKO generated biomass by-products that consists of trunk, frond, empty fruit bunch (EFB), fiber, shell, and palm kernel meal (PKM), and discharged wastes of palm oil mill effluent (POME) as well as palm fatty acid distillate (PFAD). The amount of by-products and wastes produced has been growing very rapidly and efforts to diversify and improve their utilization are a great challenge. As claimed in many research reports, the by-products and wastes could be potentially utilized as sources of energy, animal feed, chemicals, paper pulp, advanced materials, medicines and food ingredients. A more important role may be played by PO as the Indonesian Government took further steps in 2006 to become the world's largest producer of biodiesel. As a starting point, Presidential Instruction No. 1/2006 for the Production and Use of Biofuel as Alternative Fuel was issued in January 2006. Responding to this Presidential Instruction, at least 15 companies are planning to establish new larger biodiesel refineries to enhance the currently produced 82.5 million L of biodiesel. It is planned to start production in 2008/2009 with two new refineries that have a total capacity of ca. 1,600 million L/year. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

51

Polymorphic Behavior of Palm Oil and Modified Palm Oils  

Refined, bleached and deodorized palm oil, its purified palm triacylglycerol (PTG), palm olein (PO), palm stearin (PS) and high melting palm stearin (HMPS) fractions as well as randomized palm oil (RP) and its high melting randomized palm stearin (HMRPS) fractions were solidified at 5°C and kept isothermally at 10, 20 and 30°C for 60 days. X-ray diffraction showed that PTG was in ?' form crystals, while palm oil and RP were in both ?- and ?' forms at 5°C. In HMPS and HMRPS, the higher percentage of ?-transformation was observed with a higher content of trisaturated triacylglycerols and at a higher temperature. RP transformed from ?' to the intermediate form crystals during prolonged storage. Other fats were stable in ?' form crystals. Palm oil, RP, HMPS and HMRPS exhibited long-spacing values between those of tripalmitin and tristearin in ?, ?' and ? modifications, respectively. This confirms that palm oil and its modified oils form a double-chain-length conformation.   

52

Palm oil and soybean oil as fry fats: sensory acceptability of a deep-fat fried Nigerian snack food.  

The objective of the project was to compare the acceptability of a African snack product, chin-chin, when fried in soybean, palm, palm olein and palm stearin oils. Forty complete responses were obtained from volunteer judges who were attending an agricultural exposition sponsored by the University of Nebraska. After tasting all products, the judges gave slightly better rating scores to the palm stearin fried chin-chin than to the soybean oil fried products (p palm olein and palm oil fried products being given intermediate scores. The forced ranking evaluation gave directionally similar results but, because of smaller variation among scores, these differences were significantly different at the p palm olein oil). PMID:8378268

53

Interesterifikasi Stearin Sawit Dengan Minyak Kemiri Menjadi Pengganti Lemak Margarin  

Fractination of RBDPO (Rafined Bleazed Deodorized Palm Oil) is produced RBDPOlein (Rafined Bleased Deodorized Palm Olein) in the liquid form and RBDPStearin (Rafined Bleazed deodorized Palm Stearin) in the solid form in proportion 60 : 40% w/w depend on used palm oil. RBDPOlein in liquid form, can ...

54

Enzymatic synthesis of fatty hydrazides from palm oils.  

Fatty hydrazides (FH) have been successfully synthesized from palm oils by a one-step lipase catalyzed reaction. The synthesis was carried out by treating the oils with hydrazine hydrate at neutral pH using an immobilized lipase, Lipozyme as the catalyst. The percentages of conversion of RBD (refined, bleached and deodorized) palm oil (PO), RBD palm olein (POn), RBD palm stearin (PS) and RBD palm kernel olein (PKOn) into their fatty hydrazides are 95, 97, 97 and 99, respectively. PMID:18391474

55

Reduction of Methane Released from Palm Oil Mill Lagoon in Malaysia and Its Countermeasures  

Palm oil industry in Malaysia is one of the potential candidates for the CDM project because large amount of methane is emitted from the lagoons and open digesting tank of the wastewater treatment system. Therefore the first objective of the project is to investigate the actual GHG emission from the lagoons and open digesting tank in palm oil mills in order to establish the baseline for CDM project. Results indicated that methane contribution to biogas released from the open digesting tank and lagoon systems were 35% and 45%, respectively. These values are much lower than the reported value of 65% obtained by complete anaerobic condition of lab-scale experiments. Based on actual methane release measurement and information gathered from palm oil mill about wastewater treatment, significant amount of methane emission to the atmosphere can be reduced with the installation of new closed digesting tank system converted from the open digesting tank such as just by covering it with applying CDM. It is estimated that a total of RM2.6 million could be obtained from the selling of electricity generated from biogas generation and Certified Emission Reduction (CER)

56

Spatial undergrowth species composition in oil palm (Elaeis guineensis Jacq.) in West Sumatra Spatial undergrowth species composition in oil palm (Elaeis guineensis Jacq.) in West Sumatra  

The area planted to oil palm expanded during the last decades substantially, making it become the world's second most important oil crop. Despite its economic significance the oil palm remains remarkably unknown. Little attention is paid also to the oil palm undergrowth, though important in stabiliz...

57

Thermophilic anaerobic co-digestion of oil palm empty fruit bunches with palm oil mill effluent for efficient biogas production  

The effect of pretreatment methods for improved biodegradability and biogas production of oil palm empty fruit bunches (EFB) and its co-digestion with palm oil mill effluent (POME) was investigated. The maximum methane potential of POME was 502mL CH"4/gVS-added corresponding to 33.2m^3 CH"4/ton POME and 98% biodegradability. Meanwhile, the maximum methane potential of EFB was 202mL CH"4/gVS-added corresponding to 79.1m^3 CH"4/ton EFB with 38% biodegradability. Co-digestion of EFB with POME enhanced microbial biodegradability and resulted in 25-32% higher methane production at mixing ratios of 0.4:1, 0.8:1 and 2.3:1 on VS basis than digesting EFB alone. The methane yield was 276-340mL CH"4/gVS-added for co-digestion of EFB with POME at mixing ratios of 0.4:1-2.3:1, while minor improvement w...

58

Utilization of oil palm decanter cake for cellulase and polyoses production  

The abundance of oil palm decanter cake (OPDC) is a problem in oil palm mills. However, this lignocellulosic biomass can be utilized for cellulase and polyoses production. The effectiveness of chemical and physical pretreatment in reducing the lignin content was studied by saccharification using a Celluclast 1.5 L and scanning electron microscope. Physicochemical pretreatment of OPDC with 1% (w/v) NaOH and autoclaving at 121?C for 20 min increased potential polyoses produced to 52.5% and removed 28.7% of the lignin content. The optimized conditions for cellulase production by a locally isolated fungus were a time of 120 h, a substrate of untreated OPDC, a spore concentration of 1 ? 107 spore/mL, a temperature of 30?C, and a pH between 7.0 and 7.5. Trichoderma asperellum UPM1 produced carbo...

59

Utilization of interesterified oil blends in the production of frankfurters.  

Ten treatments of frankfurters were produced with interesterified oil and oil blends (palm oil, palm stearin, cottonseed oil, hazelnut oil and their mixtures) and were compared to control, produced with all animal fat. Addition of interesterified oil and oil blends affected (p0.05) scores for sensory attributes with the control, while all other treatments were also acceptable. PMID:22062272

60

77 FR 8254 - Notice of Data Availability Concerning Renewable Fuels Produced From Palm Oil Under the RFS...  

...Notice of Data Availability Concerning Renewable Fuels Produced From Palm Oil Under the...Notice of Data Availability Concerning Renewable Fuels Produced From Palm Oil Under the...a feedstock to produce biodiesel and renewable diesel under the Renewable Fuel...

 
 
 
 
61

77 FR 19663 - Notice of Data Availability Concerning Renewable Fuels Produced from Palm Oil Under the RFS...  

...Notice of Data Availability Concerning Renewable Fuels Produced from Palm Oil Under the...Notice of Data Availability Concerning Renewable Fuels Produced from Palm Oil under the...a feedstock to produce biodiesel and renewable diesel under the Renewable Fuel...

62

Honduras: Biofuels. Annual Report, 2008. GAIN Report Number HO8008.  

Hondura's growing demand for fuel and the increase in production of African palm oil result in expanded opportunities for biofuel development. The production of African palm oil has become more efficient leading to increased output and more land planted t...

63

Oil palm: domestication achieved?  

The natural habitat of the oil palm comprises very wet and relatively dry niches in the lowland rain forest in West and Central Africa. The domestication of the oil palm started with the extraction of fruits from wild forest resources. When forests were cleared for shifting cultivation, oil palms we...

64

Oil palm bunch ripeness classification using fluorescence technique  

Oil palm is Malaysia's major agriculture product and it covers approximately 5 million hectares of Malaysia's land. Limited land resources have been an important factor that motivated the need to increase oil extraction rate (OER). OER of oil palm fresh fruit bunches (FFB) depends highly on their maturity stage. The ripe oil palm FFB will produce high OER while the under ripe and over ripe oil palm FFB will produce less oil. Thus, this paper presents a method of classification between oil palm FFB into ripe, under-ripe and over-ripe categories. This research was done at an oil palm plantation in peninsular Malaysia. A total of two-hundred and ten oil palm FFB that consist of seventy bunches for each category of under-ripe, ripe and over-ripe had been used. Each bunch was scanned ten times ...

65

Physico-chemical properties of various palm-based diacylglycerol oils in comparison with their corresponding palm-based oils  

Palm-based diacylglycerol (P-DAG) oils were produced through enzymatic glycerolysis of palm kernel oil (PKO), palm oil (PO), palm olein (POL), palm mid fraction (PMF) and palm stearin (PS). High purity DAG (83-90%, w/w) was obtained and compared to palm-based oils (P-oil) had significantly (P<0.05) different fatty acid composition (FAC), iodine value (IV) and slip melting point (SMP). Solid fat content (SFC) profiles of P-DAG oils as compared to P-oils had less steep curves with lower SFC at low temperature range (5-10degreeC) and the higher complete melting temperatures. Also, P-DAG oils in contrast with P-oils showed endothermic as well as exothermic peaks with higher transition temperatures and significantly (P<0.05) higher crystallisation onsets, heats of fusion, and heats of crystalli...

66

Adsorption of residual oil from palm oil mill effluent using rubber powder  

Abstract in english A synthetic rubber powder was used to adsorb the residual oil in palm oil mill effluent (POME). POME is the wastewater produced by the palm oil industry. It is a colloidal suspension which is 95-96% water, 0.6-0.7% oil and 4-5% total solids including 2-4% suspended solids originating in the mixing of sterilizer condensate, separator sludge and hydrocyclone wastewater. POME contains 4,000 mg dm-3 of oil and grease, which is relatively high compared to the limit of only 50 (more) mg dm-3 set by the Malaysian Department of Environment. A bench-scale study of the adsorption of residual oil in POME using synthetic rubber powder was conducted using a jar test apparatus. The adsorption process was studied by varying parameters affecting the process. The parameters were adsorbent dosage, mixing speed, mixing time and pH. The optimum values of the parameters were obtained. It was found that almost 88% removal of residual oil was obtained with an adsorbent dosage of 30 mg dm-3 and mixing speed of 150 rpm for 3 hr at a pH 7. Adsorption equilibrium was also studied, and it was found that the adsorption process on the synthetic rubber powder fit the Freundlich isotherm model.

67

Isolation and Characterization of a Burkholderia sp. USM (JCM15050) Capable of Producing Polyhydroxyalkanoate (PHA) from Triglycerides, Fatty Acids and Glycerols  

A consortium of microorganisms from oil polluted wastewater sample was cultivated to promote polyhydroxyalkanoate (PHA) accumulation before subjecting the mixed cultures to sucrose density gradient ultracentrifugation. This resulted in the fractionation of the bacterial cells according to their physical features such as size, morphology and/or densities. An isolate was identified as Burkholderia sp. USM (JCM15050), which was capable of converting palm oil products [crude palm kernel oil (CPKO), palm olein (PO), palm kernel acid oil (PKAO), palm stearin (PS), crude palm oil (CPO), palm acid oil (PAO) and palm fatty acid distillate (PFAD)], fatty acids and various glycerol by-products into poly(3-hydroxybutyrate) [P(3HB)]. Up to 70 and 60?wt% of P(3HB) could be obtained when 0.5%(v/v) CPKO a...

68

Isolation of lipase producing fungi from palm oil Mill effluent (POME) dump sites at Nsukka  

Abstract in english In this study, twelve fungal lipase producing strains belonging to Aspergillus, Penicillium, Trichoderma and Mucor genera were isolated from palm oil mill effluent composts. The Aspergillus spp. were more frequent (42%) and was present in all the samples assayed. Mucor sp. was the least encountered (8.3%).The lipase producing profile showed that Trichoderma (8.07-8.24 u/mL) and Aspergillus (6.25 -7.54 u/mL) spp. were the highest lipase producers while Mucor (5.72 u/mL) was the least.

69

Kinetics of methane production from palm oil mill effluent in an immobilised cell bioreactor using saponite as support medium  

A kinetic study of the anaerobic digestion of palm oil mill effluent (POME) was carried out in a continuous, well-stirred digester with microorganisms immobilised on saponite support granules. A COD removal of 96.2% was achieved in the reactor at a volumetric loading rate of 10.6kg COD/m[sup 3] day (hydraulic retention time of 6.2 days); the methane production rate was first order with respect to biodegradable substrate concentration. The apparent rate constant was proportional to the volatile suspended solids concentration and the product yield coefficient, Y[sub p], was 0.325 litre CH[sub 4] STP/g COD consumed. (author)

70

Hydrogen rich gas from oil palm biomass as a potential source of renewable energy in Malaysia  

Oil palm is one of the major economic crops in many countries. Malaysia alone produces about 47% of the world's palm oil supply and can be considered as the world's largest producer and exporter of palm oil. Malaysia also generates huge quantity of oil palm biomass including oil palm trunks, oil palm fronds, empty fruit bunches (EFB), shells and fibers as waste from palm oil fruit harvest and oil extraction processing. At present there is a continuously increasing interest in the utilization of oil palm biomass as a source of clean energy. One of the major interests is hydrogen from oil palm biomass. Hydrogen from biomass is a clean and efficient energy source and is expected to take a significant role in future energy demand due to the raw material availability. This paper presents a review which focuses on different types of thermo-chemical processes for conversion of oil palm biomass to hydrogen rich gas. This paper offers a concise and up-to-date scenario of the present status of oil palm industry in contributing towards sustainable and renewable energy. (author)

71

Bacteriostatic Mode of Action of Trypsin-Hydrolyzed Palm Kernel Expeller Peptide Against Bacillus cereus  

Palm kernel expeller (PKE), the by-product derived from the palm kernel oil milling industry, is commonly added to ruminant feed as a source of protein. Recent research has demonstrated that the enzymatically hydrolyzed protein is inhibitory to spore-forming bacteria including Bacillus cereus. The trypsin-hydrolyzed PKE peptide appears to disrupt the membrane integrity and inhibit the intracellular macromolecule metabolism of B. cereus. The addition of the PKE peptide (350 and 700??g/ml) to B. cereus cultures triggered the efflux of K+ and caused the depletion of the intracellular ATP. However, no proportional increase in cell?s extracellular ATP was observed. Analysis of the biosynthesis of macromolecules demonstrated that RNA was affected by the PKE peptide. Results of this study suggest...

72

Bacteriostatic Mode of Action of Trypsin-Hydrolyzed Palm Kernel Expeller Peptide Against Bacillus cereus  

Palm kernel expeller (PKE), the by-product derived from the palm kernel oil milling industry, is commonly added to ruminant feed as a source of protein. Recent research has demonstrated that the enzymatically hydrolyzed protein is inhibitory to spore-forming bacteria including Bacillus cereus. The trypsin-hydrolyzed PKE peptide appears to disrupt the membrane integrity and inhibit the intracellular macromolecule metabolism of B. cereus. The addition of the PKE peptide (350 and 700 ?g/ml) to B. cereus cultures triggered the efflux of K+ and caused the depletion of the intracellular ATP. However, no proportional increase in cell?s extracellular ATP was observed. Analysis of the biosynthesis of macromolecules demonstrated that RNA was affected by the PKE peptide. Results of this study suggest...

73

Performance of a diesel generator fuelled with palm oil  

Pure palm oil may be employed in diesel engines as an alternative fuel. Engine performance and emissions were influenced by basic differences between diesel fuel and palm oils such as mass based heating values, viscosity, density and molecular oxygen content. The high viscosity of palm oil resulted in poor atomisation, carbon deposits, clogging of fuel lines and starting difficulties in low temperatures. When heated at 100{degree}C palm oil presented lower viscosity, better combustion and less deposits. Tests were conducted in a naturally aspirated MWM 229 direct injection four-stroke 70 kW diesel-generator fuelled with 100% palm oil. 14 refs., 8 figs., 2 tabs.

74

Effect of dietary palm oil and its fractions on rat plasma and high density lipoprotein lipids.  

Male Sprague Dawley rats were fed semipurified diets containing 20% fat for 15 weeks. The dietary fats were corn oil, soybean oil, palm oil, palm olein and palm stearin. No differences in the body and organ weights of rats fed the various diets were evident. Plasma cholesterol levels of rats fed soybean oil were significantly lower than those of rats fed corn oil, palm oil, palm olein or palm stearin. Significant differences between the plasma cholesterol content of rats fed corn oil and rats fed the three palm oils were not evident. HDL cholesterol was raised in rats fed the three palm oil diets compared to the rats fed either corn oil or soybean oil. The cholesterol-phospholipid molar ratio of rat platelets was not influenced by the dietary fat type. The formation of 6-keto-PGF1 alpha was significantly enhanced in palm oil-fed rats compared to all other dietary treatments. Fatty acid compositional changes in the plasma cholesterol esters and plasma triglycerides were diet regulated with significant differences between rats fed the polyunsaturated corn and soybean oil compared to the three palm oils. PMID:2345491

75

Utilization of interesterified oil blends in the production of frankfurters  

Ten treatments of frankfurters were produced with interesterified oil and oil blends (palm oil, palm stearin, cottonseed oil, hazelnut oil and their mixtures) and were compared to control, produced with all animal fat. Addition of interesterified oil and oil blends affected (pL*) of most of the samples with interesterified oil and oil blends were higher (pp>0.05) scores for sensory attributes with the control, while all other treatments were also acceptable.

76

Palm oil. Addressing issues and towards sustainable development  

The quest for renewable energy has intensified since the escalating price of crude petroleum in the recent years. Renewable energy such as biodiesel has the potential to replace petroleum-derived transportation fuel in the future. Biodiesel is defined as the mono-alkyl esters of long-chain fatty acids derived from vegetable oils such palm oil, rapeseed and soybean. Currently, more than 80% of the world biodiesel productions are from rapeseed oil. However, the cost of palm oil which is at least US$ 200 per tonne cheaper than rapeseed oil indicates that palm oil could be a more suitable and attractive candidate as the source of biodiesel compared to other vegetable oils. Although palm oil is known to be a multi-purpose vegetable oil with products ranging from food to biodiesel, there are a lot of issues surrounding palm oil production. Nevertheless, some of these issues reported in the literature were found to be misleading and are thus confusing the public perception on palm oil. Thus, the aim of this paper is to highlight and clarify the negative issues reported in the literature surrounding palm oil production. Apart from that, various policies or/and strategies that will lead to a more sustainable production and development of palm oil industries will also be proposed. Hence, palm oil will be able to become the leading vegetable oil in terms of food and non-food production, especially as the main source of renewable energy, biodiesel. (author)

77

Oil palm and its clonal propagation by tissue culture  

Until recently there has been no known method of vegetative propagation for the oil palm. Now tissue culture techniques make it possible to produce uniform clones of high - yielding top quality oil palms. This article reviews the clonal propagation of the oil palm by tissue culture - the development of which will allow oil palm breeders to combine germ plasm from a wider genetic base than hitherto, removing the pressure to breed for uniformity and the consequent increase of homozygosity of parent palms. (Refs. 15).

78

Palm oil problems; Palmen-Geister  

Indonesia plans a massive expansion of palm oil production for biodiesel production. The locals are opposed to this. The contribution describes a visit to the island of Kalimantan, where the world's biggest palm plantation is planned. (orig.)

79

Influence of palm olein on protein utilisation in the growing rat.  

In view of our preliminary findings that refined palm oil (RPOL) enhanced protein utilisation, and because of the growing importance of palm oil in human diets, two separate studies were conducted. The first study aimed to investigate the effect of the palm oil source and fraction on protein utilisation, as determined by net protein utilization (NPU) in growing rats. The second study aimed to investigate the influence of the dietary concentration of one particular palm oil fraction, refined palm olein (RPO) on net protein utilisation. The fat source of each of the semi-purified diets was as follows: crude palm oil (CPO), refined palm kernel oil (RKO), refined palm olein (RPO), refined palm stearin (RPS), and refined palm oil (RPOL). A sixth control group was offered an identical diet but with olive oil (OO, control) as the fat source. Both the oil source (P < 0.01) and the oil level (P < 0.05) influenced NPU in rats. NPU values were generally higher for rats given the RPO-containing diets, particularly at the 20% dietary level (P < 0.01) compared to the diets containing ground nut oil (GNO). The results of these two experiments indicate that RPO influences protein metabolism specifically at a concentration of at least 20% in the diet. This may suggest that RPO is superior to GNO as a source of fat for the rehabilitation of malnourished children. Human trials notably during the rehabilitation of malnourished children may therefore be the next step in this line of research. PMID:10616647

80

Coagulation-flocculation process for POME treatment using Moringa oleifera seeds extract: Optimization studies  

The treatment of palm oil mill effluent, POME is an important issue for the minimization of water pollution. The coagulation-flocculation process using Moringa oleifera seeds after oil extraction as natural coagulant is reported for POME treatment in the present study. The important process parameters pH, settling time, M. oleifera (after oil extraction) dosage and flocculant (NALCO 7751) dosage were optimized using design of experiments (DOE). A full factorial composite experimental design and response surface methodology (RSM) were used to obtain the optimum values of the parameters. The suspended solids of the raw POME were reduced from 17.927mg/L to 181mg/L and % recovery of the sludge as 87% was obtained at an optimum pH 5, settling time 114min, M. oleifera dosage of 3469mg/L and 6736...

 
 
 
 
81

Fed batch production of hydrogen from palm oil mill effluent using anaerobic microflora  

Anaerobic production of hydrogen from palm oil mill effluent (POME) by microflora was investigated in 5-l bioreactor at 60{sup o}C and pH 5.5. POME sludge was collected from the anaerobic pond of a POME treatment plant at a palm oil mill and used as a source of inocula. A batch reactor was found to yield a total of 4708ml H{sub 2}/(l POME) and the maximum evolution rate was 454ml-H{sub 2}/(l POMEh). A fed batch process was conducted after 50h. Two liters of reaction medium was removed and 2l of fresh POME was added to the reactor every 24h (15 times). The reproducibility of the fed batch process checked by changing the feeding time every 8h (10 times). A yield of 2382ml H{sub 2}/(l POME) and 2419ml H{sub 2}/(l POME) at maximum evolution rate of 313ml H{sub 2}/(l POMEh) and 436ml H{sub 2}/(l POMEh) were obtained, respectively. Throughout the study, methane gas was not observed in the evolved gas mixture. (author)

82

Palm Oil Prospects for 2005.  

In the last two decades, palm oil has emerged as the most traded edible oil and a major component of global oil consumption and production. The increase in palm oil's importance is due primarily to changes in the economics underlying the highly complex ed...

83

Greasy Palms. European buyers of Indonesian palm oil  

The international trade in palm oil is a key driver of rain forest destruction and human rights abuses on a massive scale. This report is one of two research projects undertaken for Friends of the Earth in 2003 into the impacts of the palm oil industry in South East Asia, its links to the European market and the involvement of European companies in the palm oil trade. Chapters 1 - 3 of this report (examining the growth of the European market for oil palm and the Indonesian export market) are printed here. Chapters 4 - 6 (focusing on the palm oil market in UK, the Netherlands and Sweden) are available on request from Friends of the Earth. Research methodology into the impacts of palm oil included monitoring reports compiled by the Indonesian non-governmental organisation (NGO) SawitWatch and interviews with community members and local activists. The SawitWatch data had been gathered over a period of five years, based on field investigations, meetings with local community members, media reports and regular monitoring. The analysis of the European market focused particularly on the companies trading in palm oil in the UK, the Netherlands and Sweden as well as giving a general overview of the trade in oil palm and the growth of the European market. This research is available in two reports: (1) Greasy palms: the social and ecological impacts of large-scale oil palm plantation development in South East Asia; (2) Greasy palms: European buyers of Indonesian palm oil. A summary of the two research reports (Greasy Palms - palm oil, the environment and big business) is also available.

84

Effects of Adding Polyglycerol Behenic Acid Esters on the Crystallization of Palm Oil  

The effects of polyglycerol behenic acid esters on the crystallization of palm oil were studied using optical microscopy and X-ray diffraction. Polyglycerol behenic acid esters were added in an attempt to promote the crystallization of palm oil. Optical microscopy observation confirmed that palm-oil crystals with the addition of 1 wt% of polyglycerol behenic acid esters were smaller and the number of palm oil crystals larger than without the additives. This indicated that the polyglycerol behenic acid ester promoted nucleation and inhibited crystal growth of palm oil. X-ray diffraction patterns of palm oil without the additives revealed that palm oil crystallized in the ?-form after rapid quenching of melted palm oil at 10°C. During the heating process from 10°C to 45°C, the ?-form transformed to the ??-form around 15°C, and the ??-form changed to the ?-form around 40°C. The X-ray diffraction patterns of palm oil with the addition of polyglycerol behenic acid esters showed that palm oil crystallized in the ??-form at 10°C, and did not transform to the ?-form during the heating process. Furthermore, the crystallization of the ??-form was promoted at 20°C and 25°C, but retarded at 28°C by the additive.   

85

PRODUCTION OF REFINED CAROTENE-RICH PALM OIL FROM PALM MESOCARP (ELAEIS GUINEENSIS) USING SUPERCRITICAL CARBON DIOXIDE  

ABSTRACT Simultaneous extraction, degumming and deacidification of palm oil directly from palm mesocarp using supercritical carbon dioxide (SC-CO2) were carried out. The temperatures and pressures used were 40-80C and 18-30 MPa, respectively. The degummed and deacidified palm oil produced from the process meets the specifications of refined, bleached and deodorized palm oil of Malaysian standard, with added value in its carotene content . The recovery of the refined palm oil was 52.8-74.0% based on the total hexane extractable material. Other palm minor components such as vitamin E, phytosterols and squalene were preserved in the refined SC-CO2-extracted carotene-rich palm oil. The solubility of triacylglycerols (TGs), distribution coefficient of free fatty acids (FFAs) and the separation ...

86

Integrated palm oil processing  

Tree palms are a promising source of fuel extenders and substitutes. They are perennials which bear oil for a period of two to three decades after a roughly four year preliminary growth period. Because palms are an important crop in many areas of Asia, Africa, and South America, considerable attention has been given to palm genetic improvement, with the result that tree palms are one of the most efficient energy crops, providing much better solar energy capture than, for example, sugar cane and cassava. Tree palms are particularly attractive in areas where more conventional farming would pose a significant threat of laterization or cause major ecological problems. Technology for palm oil production, including harvest, tree management, and oil pressing are generally suited to village or plantation use, and, for the most part, have been directed toward supplying process energy through the combustion of process waste products, such as palm fruit residue and palm bunch fibers.

87

Thermophilic biohydrogen production from palm oil mill effluent (POME) using suspended mixed culture  

A batch study was conducted to determine the fate of carbohydrate and oil that are present in palm oil mill effluent (POME) during the biohydrogen fermentation process. Sucrose and crude palm oil (CPO) were chosen as substrates and the kinetic profile indicated that mainly sucrose was metabolised by the mixed sludge. The hydrogen yield based on the COD of sucrose added was 146 cm{sup 3} g{sup -1} which is equivalent to a hydrogen to hexose mole ratio of 2.5. The free fatty acids from hydrolysed CPO were not metabolised further which render insignificant generation of hydrogen and volatile fatty acids from oil-based substrate. The average continuous biohydrogen production rate (HPR) from a unit volume of POME under thermophilic condition at 55 C was 2.64 m{sup 3} m{sup -3} d{sup -1} at a hydraulic retention time (HRT) of 4 days. Hydrogen constitutes up to 52% of the total biogas and methane was not detected over the 60 day continuous operation. The hydrogen yield (i.e. based on mole ratio of hydrogen to hexose) was 1.72 with an average carbohydrate conversion efficiency of 58%. These limit the potential of recovering more hydrogen energy from POME under current operating conditions. (author)

88

The effect of natural and synthetic antioxidants on the oxidative stability of palm diesel  

Crude and distilled palm oil methyl esters conveniently known as palm diesel have been successfully evaluated as diesel substitute. Crude palm oil methyl esters are produced from transesterification of crude palm oil with minor components such as carotenes and vitamin E still intact and they are reddish in colour. The distilled palm oil methyl esters are obtained after the recovery of minor components (e.g. Carotenes and vitamin E) from the crude palm oil methyl esters. These valuable minor components are preferably to be recovered as they can be sold as value-added products before they are burnt together with the methyl esters as fuel. Although both possesses fuel characteristics which are comparable to those of petroleum diesel, crude palm oil methyl esters are found to exhibit better oxidative stability than distilled palm oil methyl esters. It is attributed to the presence of vitamin E, a natural antioxidant in the former. While the distilled palm oil methyl esters contain practically no vitamin E and as a result, they exhibit poor oxidative stability. Thus, the crude palm oil methyl esters meet the European standard for biodiesel (EN 14214) which has set a minimum rancimat induction period of 6 h. In the present study, research was conducted to enhance the oxidative stability of distilled palm oil methyl esters in order to meet the aforementioned standard. Natural and synthetic antioxidants were used in the present study to investigate their effect on the oxidative stability of distilled palm oil methyl esters. It was found that both types of antioxidant showed beneficial effects in inhibiting the oxidation of distilled palm oil methyl esters. Comparatively, the synthetic antioxidants were found to be more effective than the natural antioxidants as lower dosage was needed to achieve the minimum rancimat induction period of 6 h. Short communication. 19 refs., 2 figs., 3 tabs.

89

Modelling of palm oil production using fuzzy expert system  

The production of crude palm oil and palm kernel is a complex problem due to the influence of processing variables and environmental factors. These processing variables influence the amount of crude palm oil and palm kernel losses during processing. Instead of mathematical model, fuzzy logic approach provides a simpler and easier mechanism to describe the relationships between the processing variables and the amount of crude palm oil and palm kernel losses. In this study, four fuzzy expert system models were developed for each palm oil processing station. An approximation of centre of gravity method for defuzzification is also proposed to enable the development of the model using Microsoft^(R)Excel. For comparison purpose, the models were also developed using MATLAB^(R). Results obtained f...

90

Modelling of palm oil production using fuzzy expert system  

The production of crude palm oil and palm kernel is a complex problem due to the influence of processing variables and environmental factors. These processing variables influence the amount of crude palm oil and palm kernel losses during processing. Instead of mathematical model, fuzzy logic approach provides a simpler and easier mechanism to describe the relationships between the processing variables and the amount of crude palm oil and palm kernel losses. In this study, four fuzzy expert system models were developed for each palm oil processing station. An approximation of centre of gravity method for defuzzification is also proposed to enable the development of the model using MicrosoftExcel. For comparison purpose, the models were also developed using MATLAB. Results obtained from the ...

91

The effects of physical refining on the formation of 3-monochloropropane-1,2-diol esters in relation to palm oil minor components.  

The formation of 3-monochloropropane-1,2-diol (3-MCPD) esters in refined palm oil during deodorisation is attributed to the intrinsic composition of crude palm oil. Utilising D-optimal design, the effects of the degumming and bleaching processes on the reduction in 3-MCPD ester formation in refined palm oil from poor-quality crude palm oil were studied relative to the palm oil minor components that are likely to be their precursors. Water degumming remarkably reduced 3-MCPD ester formation by up to 84%, from 9.79 mg/kg to 1.55 mg/kg. Bleaching with synthetic magnesium silicate caused a further 10% reduction, to 0.487 mg/kg. The reduction in 3-MCPD ester formation could be due to the removal of related precursors prior to the deodorisation step. The phosphorus content of bleached palm oil showed a significant correlation with 3-MCPD ester formation. PMID:22868161

92

Pretreatment of palm oil mill effluent (POME) using Moringa oleifera seeds as natural coagulant  

Moringa oleifera seeds, an environmental friendly and natural coagulant are reported for the pretreatment of palm oil mill effluent (POME). In coagulation-flocculation process, the M. oleifera seeds after oil extraction (MOAE) are an effective coagulant with the removal of 95% suspended solids and 52.2% reduction in the chemical oxygen demand (COD). The combination of MOAE with flocculant (NALCO 7751), the suspended solids removal increased to 99.3% and COD reduction was 52.5%. The coagulation-flocculation process at the temperature of 30degreeC resulted in better suspended solids removal and COD reduction compared to the temperature of 40, 55 and 70degreeC. The MOAE combined with flocculant (NALCO 7751) reduced the sludge volume index (SVI) to 210mL/g with higher recovery of dry mass of s...

93

Pretreatment of palm oil mill effluent (POME) using Moringa oleifera seeds as natural coagulant.  

Moringa oleifera seeds, an environmental friendly and natural coagulant are reported for the pretreatment of palm oil mill effluent (POME). In coagulation-flocculation process, the M. oleifera seeds after oil extraction (MOAE) are an effective coagulant with the removal of 95% suspended solids and 52.2% reduction in the chemical oxygen demand (COD). The combination of MOAE with flocculant (NALCO 7751), the suspended solids removal increased to 99.3% and COD reduction was 52.5%. The coagulation-flocculation process at the temperature of 30 degrees C resulted in better suspended solids removal and COD reduction compared to the temperature of 40, 55 and 70 degrees C. The MOAE combined with flocculant (NALCO 7751) reduced the sludge volume index (SVI) to 210mL/g with higher recovery of dry mass of sludge (87.25%) and water (50.3%). PMID:17141409

94

Drivers of Land Use Change and the Role of Palm Oil Production in Indonesia and Malaysia. Overview of Past Developments and Future Projections  

This study provides insight into land use changes (LUC) in Indonesia and Malaysia and into the specific role that palm oil production and its expansion have played in the past and may play in the future in both countries. In relation to future land use changes induced by palm oil production expansion also the GHG emissions of this LUC are analysed to indicate the sustainability (from a GHG emission perspective) of the various palm oil expansion projections.

95

Kujurid ei olegi nikerdajad / Aarne Mäe  

Sümpoosioni 'Puu '98' (korraldaja Heiki Kongi) raames Sagadis toimunud puuskulptuuride valmistamisest, kus osalesid Aime Kuulbusch, Aili Vahtrapuu, Hille ja Lembit Palm, Urmas Rauba, Tiiu Kirsipuu, Steve Lester, ning mille tulemusi eksponeeritakse koos Valga- ja Pärnumaal valminutega Rocca al Mares

96

Enzymatic Biodiesel Synthesis Using a Byproduct Obtained from Palm Oil Refining  

An alternative route to produce biodiesel is based on esterification of free fatty acids present in byproducts obtained from vegetable oil refining, such as palm oil fatty acid distillate (PFAD). PFAD is a byproduct of the production of edible palm oil, which contains 96?wt.% of free fatty acids. Th...

97

Spatially explicit scenario analysis for reconciling agricultural expansion, forest protection, and carbon conservation in Indonesia  

Palm oil is the world's most important vegetable oil in terms of production quantity. Indonesia, the world's largest palm-oil producer, plans to double its production by 2020, with unclear implications for the other national priorities of food (rice) production, forest and biodiversity protection, a...

98

Sustainability of smallholder palm oil production in Indonesia  

Palm oil is a widely used commodity and is part of a number of daily products. It is the most used vegetable oil, not just for food consumption, but also for soap and cosmetics. Recently the search for co2 neutral fuels have spurred demand for palm oil to be used in diesel cars. The large demand hav...

99

Development and characterisation of novel heterogeneous palm oil mill boiler ash-based catalysts for biodiesel production.  

Novel heterogeneous catalysts from calcium oxide (CaO)/calcined calcium carbonate (CaCO(3)) loaded onto different palm oil mill boiler ashes were synthesised and used in the transesterification of crude palm oil (CPO) with methanol to yield biodiesel. Catalyst preparation parameters including the type of ash support, the weight percentage of CaO and calcined CaCO(3) loadings, as well as the calcination temperature of CaCO(3) were optimised. The catalyst prepared by loading of 15wt% calcined CaCO(3) at a fixed temperature of 800°C on fly ash exhibited a maximum oil conversion of 94.48%. Thermogravimetric analysis (TGA) revealed that the CaCO(3) was transformed into CaO at 770°C and interacted well with the ash support, whereas rich CaO, Al(2)O(3) and SiO(2) were identified in the composition using X-ray diffraction (XRD). The fine morphology size (<5?m) and high surface area (1.719m(2)/g) of the fly ash-based catalyst rendered it the highest catalytic activity. PMID:23026328

100

Sourcing palm oil from sustainable sources  

Our world is confronted with increasing concerns about global warming and security of energy supply. Renewable energy is promoted as one of the solutions to these challenges. One source of renewable energy is palm oil (derivatives). Crude palm oil and its derivatives can be used to produce biodiesel as well as to produce electricity and heat. Essent, a Dutch electricity producer, has co-fired palm oil for the generation of electricity from renewable sources. However, there has been an increasing concern about the sustainability of palm oil production. It is feared that the large-scale consumption of palm oil by the energy sector may have negative effects, e.g. on the environment in producing countries. In a reaction to this concern Essent suspended its sourcing of palm oil and asked a commission of experts to advise her on the possibilities of sourcing palm oil from verified sustainable sources. This report is the result of the Commission's work and documents the advice of the Commission to Essent. The assignment to the Commission is to determine whether it is possible to implement a certification system for palm oil products in the short term that enables sourcing of palm oil from verified sustainable sources.

 
 
 
 
101

The hidden carbon liability of Indonesian palm oil  

This report highlights the urgent need for global palm oil consumers and investors to support Unilever's call for an immediate moratorium on deforestation and peatland clearance in Indonesia. This report focuses on Unilever, which shares major institutional investors with other leading corporations including Nestle, Procter and Gamble and Kraft. Not only do these corporations share investors, they also share growing carbon liability within their raw material supply chains through the expansion in the palm oil sector in Indonesia. Unilever has recognised the global problems associated with palm oil expansion and the need for drastic reform to this sector. Unilever has taken a bold move in calling for an immediate moratorium on deforestation and peatland clearance. While Unilever's position is strengthened by its status as the largest palm oil consumer in the world, this report shows how, unless companies like Nestle, Procter and Gamble and Kraft support its call for a halt to deforestation, the palm oil industry will continue to present a massive carbon liability over the coming years. This report uses Unilever's palm oil supply chains as a case study to help quantify the carbon liability and collateral risks associated with the Indonesian palm oil sector. It shows how, by buying palm oil from suppliers who account for more than one-third of Indonesia's palm oil production, Unilever and its competitors are increasing their potential carbon liability and thus leaving investors exposed to potentially significant levels of hidden risk, compromising long-term financial and brand stability.

102

The addition of palm oil biodiesel and coal derived FT distillate to GHGenius  

The GHGenius model is suitable for analyzing pollutants emitted during the processing and use of transportation fuels. This study covers work on the addition of coal to the FT distillate pathway in the model. The production of palm oil and palm oil biodiesel and light duty diesel applications have been added, as well. FT distillate from coal is described with regard to coal production, process description and parameters, energy balance, upstream greenhouse gases emissions, lifecycles emissions, and cost effectiveness. Palm production, land use issues, oil extraction process, palm oil biodiesel production, energy balance, upstream and lifecycles emissions, and cost effectiveness are described. 13 refs., 8 figs., 34 tabs.

103

Blending of palm oil, palm stearin and palm kernel oil in the preparation of table and pastry margarine.  

Palm oil (PO ; iodin value = 52), palm stearin (POs1; i.v. = 32 and POs2; i.v. = 40) and palm kernel oil (PKO; i.v. = 17) were blended in ternary systems. The blends were then studied for their physical properties such as melting point (m.p.), solid fat content (SFC), and cooling curve. Results showed that palm stearin increased the blends melting point while palm kernel oil reduced it. To produce table margarine with melting point (m.p.) below 40 degrees C, the POs1 should be added at level of palm stearin increased the blends solidification Tmin and Tmax values, while PKO reduced them. Blends which contained high amount of palm stearin showed melting point and cooling curves quite similar to that of pastry margarine. PMID:8616676

104

Factors impacting the formation of monochloropropanediol (MCPD) fatty acid diesters during palm (Elaeis guineensis) oil production.  

Recently, organic and inorganic chlorinated compounds were detected in crude and commercially refined palm oils. Further, the predominant formation mechanism of monochloropropanediol (MCPD) diesters at high temperatures (>170-180°C) was revealed. The present study involved the development and comparison of solutions to mitigate MCPD diester levels in oils from various stages of palm oil production. Partially refined palm oil samples and oil extracted from fresh palm fruits were submitted to bench-top deodorisation experiments. Application of glycerol and ethanol as refining aids during the deodorisation of refined-bleached palm oil proved to be moderately effective; about 25%-35% reduction of MCPD diester levels was achieved. Washing crude palm oil with ethanol-water (1:1) prior to deodorisation was also an effective strategy yielding an ?30% reduction of MCPD diester contents. Washing palm fruit pulp before oil extraction, however, was most impactful, resulting in a 95% reduction of MCPD diesters when compared to the deodorised control oil. This suggests that intervention upstream in the process chain is most efficient in reducing levels of these contaminants in refined oils. Following the study, a root-cause analysis was performed in order to map the parameters potentially responsible for the occurrence of MCPD diesters in refined palm oil and related fractions. PMID:22168150

105

Mitigation of MCPD-ester and glycidyl-ester levels during the production of refined palm oil  

Abstract In recent years, process contaminants called MCPD and glycidyl esters have been found to be present in refined edible oils. On average, they have been found in higher levels in refined palm oils than typical seed-oil crops. The reasons behind the increased occurrence of these contaminants in palm oils have now been traced all the way back to raw materials such as crude palm oil. This manuscript attempts to summarize some recent breakthroughs in the area of mitigation of MCPD-ester and glycidyl-ester levels during refined palm oil production. It is clear that renovation of the palm oil production process is necessary to further improve the quality and safety of this important commodity.

106

Applications of supercritical fluid extraction (SFE) of palm oil and oil from natural sources.  

Supercritical fluid extraction (SFE), which has received much interest in its use and further development for industrial applications, is a method that offers some advantages over conventional methods, especially for the palm oil industry. SC-CO? refers to supercritical fluid extraction (SFE) that uses carbon dioxide (CO?) as a solvent which is a nontoxic, inexpensive, nonflammable, and nonpolluting supercritical fluid solvent for the extraction of natural products. Almost 100% oil can be extracted and it is regarded as safe, with organic solvent-free extracts having superior organoleptic profiles. The palm oil industry is one of the major industries in Malaysia that provides a major contribution to the national income. Malaysia is the second largest palm oil and palm kernel oil producer in the World. This paper reviews advances in applications of supercritical carbon dioxide (SC-CO?) extraction of oils from natural sources, in particular palm oil, minor constituents in palm oil, producing fractionated, refined, bleached, and deodorized palm oil, palm kernel oil and purified fatty acid fractions commendable for downstream uses as in toiletries and confectionaries. PMID:22328076

107

Alternative fat sources to animal fat for pigs  

The use of fats and oils in diets for pigs is of great importance due to their high energy value. As a consequence of the BSE-crisis in the European Union, the amount of animal fat available for animal feeds has been reduced, and alternative fat sources are of increasing importance. In this paper, we review our main findings on the effects of diets with different fat sources on apparent fat digestibility in pigs. A method for quantitative measurement of fat extraction from feed and faeces has been developed, and this method has been used in a digestibility trial, in which diets added 5% of either animal fat, palm oil mix, palm oil, vegetable oil mix, coconut oil, or rapeseed oil were tested in weaned and growing pigs. It was concluded that several vegetable fat sources (palm oil mix, palm oil, coconut oil, rapeseed oil) could be used as alternatives to animal fat in pig feed, whereas fat blends should be avoided.

108

Comparative kinetics of transesterification for biodiesel production from palm oil and mustard oil  

Abstract The kinetics of palm oil and mustard oil transesterification are compared. Transesterification of palm oil and mustard oil using KOH as a catalyst was performed at various reaction temperatures ranging from 40 to 60C. The reaction steps are reversible and transesterification is favoured at elevated temperatures. The reaction step of triglyceride to diglyceride is the rate determining step (RDS) that controls kinetics of overall transesterification with activation energies of 30.2 and 26.8-kJ/mol for palm oil and mustard oil transesterification, respectively. It is found that percentage of saturated compounds play a vital role on transesterification kinetics. 2011 Canadian Society for Chemical Engineering

109

PRODUCTION OF PALM OIL REFERENCE MATERIALS FOR THE DETERMINATION OF SOLID FAT CONTENT  

ABSTRACT Three palm oil reference materials were produced for solid fat content analysis employing the Malaysian Palm Oil Board (MPOB) Test Methods. Thirteen laboratories participated in the characterization study, where the solid fat content in palm oil, palm olein and palm stearin were identified at temperature range from 0 to 45C. The consensus values were calculated based on the acceptability of statistical results from collaborating laboratories. Both of the consensus values and their uncertainties (%) for each reference material are as follows: 71.12 +- 1.82% (0C), 54.07 +- 1.05% (10C), 37.44 +- 0.88% (15C), 24.18 +- 1.09% (20C), 13.32 +- 0.86% (25C), 7.64 +- 0.28% (30C), 4.05 +- 0.14% (35C) and 1.25 +- 0.49% (40C) for SFC of palm oil, 66.32 +- 1.93% (0C), 43.53 +- 1.32% (10C), 22.50...

110

Palm Pulverisation in Sustainable Oil Palm Replanting  

Malaysia has banned open burning of old oil palm biomass at replanting. The most widely adopted zero burn techniques of replanting oil palms in Malaysia currently are the “chipped and windrow” and “under-planting” methods. These methods resulted in very high breeding of Oryctes rhinoceros beetle, which has become the most serious pest in immature and young mature palms in Malaysia currently. Three new no-burn methods of clearing old oil palms for replanting whereby almost the entire palms are pulverized into fine pieces of less than 0.1g dry weight each and spread widely over the entire field and the root mass dug up at felling are reported. More than 50% of the pulverized palm biomass decomposed by 24 weeks after pulverization, which increased to 80% by the 56th week. All the three methods have good potential in reducing the breeding of Oryctes rhinoceros. They also have good potential in reducing the rat and Ganoderma boninense disease problems. In addition, the new clearing methods reduced the fallow period, facilitated replanting and the subsequent field upkeep work, and improved the utilisation of nutrients released by the decomposing palm biomass by the newly replanted palms. The methods of clearing old oil palms for replanting are environmentally less polluting and also improve the sustainability of oil palm plantations.   

111

Tropical oils: nutritional and scientific issues.  

Individually and in combination with other oils, the tropical oils impart into manufactured foods functional properties that appeal to consumers. The use of and/or labeling in the ingredient lists give the impression that these oils are used extensively in commercially processed foods. The estimated daily intake of tropical oils by adult males is slightly more than one fourth of a tablespoon (3.8 g), 75% of which consists of saturated fatty acids. Dietary fats containing saturated fatty acids at the beta-position tend to raise plasma total and LDL-cholesterol, which, of course, contribute to atherosclerosis and coronary heart disease. Health professionals express concern that consumers who choose foods containing tropical oils unknowingly increase their intake of saturated fatty acids. The saturated fatty acid-rich tropical oils, coconut oil, hydrogenated coconut oil, and palm kernel oil, raise cholesterol levels; studies demonstrating this effect are often confounded by a developing essential fatty acid deficiency. Palm oil, an essential fatty acid-sufficient tropical oil, raises plasma cholesterol only when an excess of cholesterol is presented in the diet. The failure of palm oil to elevate blood cholesterol as predicted by the regression equations developed by Keys et al. and Hegsted et al. might be due to the dominant alpha-position location of its constituent saturated fatty acids. If so, the substitution of interesterified artificial fats for palm oil in food formulations, a recommendation of some health professionals, has the potential of raising cholesterol levels. A second rationale addresses prospective roles minor constituents of palm oil might play in health maintenance. This rationale is founded on the following observations. Dietary palm oil does not raise plasma cholesterol. Single fat studies suggests that oils richer in polyunsaturated fatty acid content tend to decrease thrombus formation. Anomalously, palm oil differs from other of the more saturated fats in tending to decrease thrombus formation. Finally, in studies comparing palm oil with other fats and oils, experimental carcinogenesis is enhanced both by vegetable oils richer in linoleic acid content and by more highly saturated animal fats. The carotenoid constituents of red palm oil are potent dietary anticarcinogens. A second group of antioxidants, the tocotrienols, are present in both palm olein and red palm oil. These vitamin E-active constituents are potent suppressors of cholesterol biosynthesis; emerging data point to their anticarcinogenic and antithrombotic activities. This review does not support claims that foods containing palm oil have no place in a prudent diet. PMID:1345319

112

The use of renewable alternative sources for the isolated electric generation: proposal of agroenergy system implantation based on the palm oil from the Amazonas state, Brazil; O uso de fontes alternativas renovaveis para a geracao eletrica isolada: proposta de implantacao de sistemas agroenergeticos com base na palma africana no Estado do Amazonas  

This paper presents an analysis of the introduction potential of agroenergetic systems in the state of Amazonas, BR, by giving priority to the plantation of the palm oil (Elaeis guineensis) in deforested areas od the state of Amazonas, BR, which presents the edaphoclimatic conditions necessary for the plantation of this palm tree. The palm oil can be used in natura in stationary engines and cas basic raw material for the production of biodiesel, both through transesterification and cracking as well.

113

Production of Bacterial Endoglucanase from Pretreated Oil Palm Empty Fruit Bunch by Bacillus pumilus EB3  

In this study, endoglucanase was produced from oil palm empty fruit bunch (OPEFB) by a locally isolated aerobic bacterium, Bacillus pumilus EB3. The effects of the fermentation parameters such as initial pH, temperature, and nitrogen source on the endoglucanase production were studied using carboxymethyl cellulose (CMC) as the carbon source. Endoglucanase from B. pumilus EB3 was maximally secreted at 37°C, initial pH 7.0 with 10 g/l of CMC as carbon source, and 2 g/l of yeast extract as organic nitrogen source. The activity recorded during the fermentation was 0.076 U/ml. The productivity of the enzyme increased twofold when 2 g/l of yeast extract was used as the organic nitrogen supplement as compared to the non-supplemented medium. An interesting finding from this study is that pretreated OPEFB medium showed comparable results to CMC medium in terms of enzyme production with an activity of 0.063 U/ml. As OPEFB is an abundant solid waste at palm oil mills, it has the potential of acting as a substrate in cellulase production.   

114

Treatment of waste water and wastes from palm oil production in pilot-scale in Medan/Indonesia. Final report; Behandlung von Abwasser und Abfaellen aus der Palmoelproduktion im Pilotmassstab in Medan/Indonesien. Abschlussbericht und Anlage 1: Feasibility Study; Anlage 2: Sojapflanzen-Feldversuche an sauren Boeden mit hohem Al-Gehalt mit Kompost aus EFB: Anlage 3: Planung einer Full-Scale-Anlage in Aek Pancur  

The conventional system for waste water treatment in ponds and the propagated land application are not suitable from ecological and economical point of view. The target was to develop an more environmental-friendly alternative and to evaluate an integrated waste water-/waste concept by a feasibility study. Over 2 years high polluted POME (Palm Oil Mill Effluent) was treated in fixed bed digesters. The results are: The anaerobic fixed bed technology is very suitable for practise. The high expectations were fulfilled in view to process stability, dynamic load characteristic, loading rate and efficiency, short hydraulic retention time and low demand for process control. The waste water is easily degradable. Even though the POME has a low pH of 4 a neutralisation is not necessary. A separation of suspended solids simplify the following treatment steps. A feasibility study were worked out for an integrated waste water-/waste concept based on the results of the experiments. As conclusion can be presented, that the anaerobic fermentation of POME in fixed bed digesters and utilisation of the produced biogas in combination with a composting of solid wastes, which are moistened by the pre-treated POME, gives an realistic Zero-Waste-Concept, which is much better from ecological as from economical point of view than the conventional systems. It is possible to improve the sustainability and the economy of the palm oil production. (orig.)

115

Ethanesulfonic acid-based esterification of industrial acidic crude palm oil for biodiesel production.  

An industrial grade acidic crude palm oil (ACPO) pre-treatment process was carried out using ethanesulfonic acid (ESA) as a catalyst in the esterification reaction. ESA was used in different dosages to reduce free fatty acid (FFA) to a minimum level for the second stage of biodiesel production via alkaline transesterification reaction. Different process operating conditions were optimized such as ESA dosage (0.25-3.5% wt/wt), methanol to ACPO molar ratio (1:1-20:1), reaction temperature (40-70 °C), and reaction time (3-150 min). This study revealed the potential use of abundant quantities of ACPO from oil palm mills for biodiesel production. The lab scale results showed the effectiveness of the pre-treatment process using ESA catalyst. Three consecutive catalyst recycling runs were achieved without significant degradation in its performance. Second and third reuse runs needed more reaction time to achieve the target level of FFA content. Esterification and transesterification using ESA and KOH respectively is proposed for biodiesel industrial scale production. The produced biodiesel meets the international standards specifications for biodiesel fuel (EN 14214 and ASTM D6751). PMID:21855329

116

Effects of palm oil blended with oxidized fish oil on growth performances, hematology, and several immune parameters in juvenile Japanese sea bass, Lateolabrax japonicas  

A 60-day feeding trial was conducted to determine the effects of palm oil blended with oxidized and non-oxidized fish oil on growth performances, hematology, and non-specific immune response in juvenile Japanese sea bass, Lateolabrax japonicas. Japanese sea bass (1.73???0.01?g) were fed seven experimental diets containing 100?g/kg of dietary lipid in forms of palm oil (10P), fish oil (10F), fish oil blended with palm oil at different ratios, 6:4 (6F4P) and 4:6 (4F6P), oxidized fish oil (10OF), and oxidized fish oil blended with palm oil at different ratios, 6:4 (6OF4P) and 4:6 (4OF6P). After the feeding trial, the following results were illustrated. No significant effects were observed in survival, feed conversion ratio, condition factor, and hematocrit after feeding with experimental diet...

117

Effects of palm oil blended with oxidized fish oil on growth performances, hematology, and several immune parameters in juvenile Japanese sea bass, Lateolabrax japonicas  

A 60-day feeding trial was conducted to determine the effects of palm oil blended with oxidized and non-oxidized fish oil on growth performances, hematology, and non-specific immune response in juvenile Japanese sea bass, Lateolabrax japonicas. Japanese sea bass (1.73 ± 0.01 g) were fed seven experimental diets containing 100 g/kg of dietary lipid in forms of palm oil (10P), fish oil (10F), fish oil blended with palm oil at different ratios, 6:4 (6F4P) and 4:6 (4F6P), oxidized fish oil (10OF), and oxidized fish oil blended with palm oil at different ratios, 6:4 (6OF4P) and 4:6 (4OF6P). After the feeding trial, the following results were illustrated. No significant effects were observed in survival, feed conversion ratio, condition factor, and hematocrit after feeding with experimental diet...

118

Enzyme production and profile by Aspergillus niger during solid substrate fermentation using palm kernel cake as substrate.  

The oil palm sector is one of the major plantation industries in Malaysia. Palm kernel cake is a byproduct of extracted palm kernel oil. Mostly palm kernel cake is wasted or is mixed with other nutrients and used as animal feed, especially for ruminant animals. Recently, palm kernel cake has been identified as an important ingredient for the formulation of animal feed, and it is also exported especially to Europe, South Korea, and Japan. It can barely be consumed by nonruminant (monogastric) animals owing to the high percentages of hemicellulose and cellulose contents. Palm kernel cake must undergo suitable pretreatment in order to decrease the percentage of hemicellulose and cellulose. One of the methods employed in this study is fermentation with microorganisms, particularly fungi, to partially degrade the hemicellulose and cellulose content. This work focused on the production of enzymes by Aspergillus niger and profiling using palm kernel cake as carbon source. PMID:15304740

119

Palm-based standard reference materials for iodine value and slip melting point.  

This work described study protocols on the production of Palm-Based Standard Reference Materials for iodine value and slip melting point. Thirty-three laboratories collaborated in the inter-laboratory proficiency tests for characterization of iodine value, while thirty-two laboratories for characterization of slip melting point. The iodine value and slip melting point of palm oil, palm olein and palm stearin were determined in accordance to MPOB Test Methods p3.2:2004 and p4.2:2004, respectively. The consensus values and their uncertainties were based on the acceptability of statistical agreement of results obtained from collaborating laboratories. The consensus values and uncertainties for iodine values were 52.63 +/- 0.14 Wijs in palm oil, 56.77 +/- 0.12 Wijs in palm olein and 33.76 +/- 0.18 Wijs in palm stearin. For the slip melting points, the consensus values and uncertainties were 35.6 +/- 0.3 degrees C in palm oil, 22.7 +/- 0.4 degrees C in palm olein and 53.4 +/- 0.2 degrees C in palm stearin. Repeatability and reproducibility relative standard deviations were found to be good and acceptable, with values much lower than that of 10%. Stability of Palm-Based Standard Reference Materials remained stable at temperatures of -20 degrees C, 0 degrees C, 6 degrees C and 24 degrees C upon storage for one year. PMID:19609396

120

Dietary linoleic acid influences desaturation and acylation of deuterium-labeled linoleic and linolenic acids in young adult males  

This work described study protocols on the production of Palm-Based Standard Reference Materials for iodine value and slip melting point. Thirty-three laboratories collaborated in the inter-laboratory proficiency tests for characterization of iodine value, while thirty-two laboratories for characterization of slip melting point. The iodine value and slip melting point of palm oil, palm olein and palm stearin were determined in accordance to MPOB Test Methods p3.2:2004 and p4.2:2004, respectively. The consensus values and their uncertainties were based on the acceptability of statistical agreement of results obtained from collaborating laboratories. The consensus values and uncertainties for iodine values were 52.63 ± 0.14 Wijs in palm oil, 56.77 ± 0.12 Wijs in palm olein and 33.76 ± 0.18 Wijs in palm stearin. For the slip melting points, the consensus values and uncertainties were 35.6 ± 0.3 °C in palm oil, 22.7 ± 0.4 °C in palm olein and 53.4 ± 0.2 °C in palm stearin. Repeatability and reproducibility relative standard deviations were found to be good and acceptable, with values much lower than that of 10%. Stability of Palm-Based Standard Reference Materials remained stable at temperatures of ?20 °C, 0 °C, 6 °C and 24 °C upon storage for one year. PMID:7914092

 
 
 
 
121

Atmospheric and Soil Carbon and Halophytes  

At 43% of the total landmass, exploiting the. Earth's arid ... replace $70/bbl barrel crude oil. ... Exploiting the Earth's arid ... oil, 0.6 mt/ha (73% linoleic) and meal ( 1.6 mt/ha). .... palm, although sustainable palm is competitive with sugar cane, ...

122

Fatty acid composition and carcass characteristics of growing lambs fed diets containing palm oil supplements  

8 pages, 5 tables.-- Available online Jan 5, 2005. | Thirty 45-day-old male Ojalada lambs were used to investigate the effect of palm oil (as such or in the form of calcium soap) on carcass characteristics and fat composition. Dietary palm oil did not significantly affect dorsal fat thickness, carca...

123

Intestinal Fluid and Glucose Transport in Wistar Rats following Chronic Consumption of Fresh or Oxidised Palm Oil Diet  

Chronic ingestion of thermoxidized palm oil causes functional derangement of various tissues. This study was therefore carried out to determine the effect of chronic ingestion of thermoxidized and fresh palm oil diets on intestinal fluid and glucose absorption in rats using the everted sac technique...

124

Genetic Linkage Map of a High Yielding FELDA Deli×Yangambi Oil Palm Cross  

Enroute to mapping QTLs for yield components in oil palm, we constructed the linkage map of a FELDA high yielding oil palm (Elaeis guineensis), hybrid cross. The parents of the mapping population are a Deli dura and a pisifera of Yangambi origin. The cross out-yielded the average by 8–21% in four tr...

125

Comparative transcriptome and metabolite analysis of oil palm and date palm mesocarp that differ dramatically in carbon partitioning  

Oil palm can accumulate up to 90% oil in its mesocarp, the highest level observed in the plant kingdom. In contrast, the closely related date palm accumulates almost exclusively sugars. To gain insight into the mechanisms that lead to such an extreme difference in carbon partitioning, the transcript...

126

Kinetika Transesterifikasi Minyak Sawit Menjadi Etil Ester (Biodisel)  

Transesterification of palm oil with alcohols, in the presence of a catalyst, yields fatty esters and glycerol. Di-and monoglycerides are intermediates. Reactions are consecutive and reversible. The kinetics of the transesterfication of palm oil is known to follow a three-step reaction mechanism. I...

127

Pyrolysis Kinetics of Oil-Palm Solid Waste  

Pyrolysis of oil-palm shells, a cheap and abundantly available solid waste from palm oil producing process, was carried out using thermogravimetric analysis. The effect of heating rates (10,15,20 and 25°C/min) on the kinetic parameters (activation energy, frequency factor and reaction order) was inv...

128

Effects of palm oil and calcium soaps of palm oil fatty acids in fattening diets on digestibility, performance and chemical body composition of lambs  

12 pages, 6 tables.-- Available online Oct 5, 2005. | The effects on digestibility, performance and chemical body composition of inclusion of palm oil (PO, VETALGRAS®) or calcium soaps of palm oil fatty acids (CaF, MAGNAPAC®), at two levels, in diets of growing lambs were determined. Experimental di...

129

Exploring land use changes and the role of palm oil production in Indonesia and Malaysia  

This study compiles and analyses national-level data on land use change (LUC) and its causes in Indonesia and Malaysia over the past 30 years. The study also explores the role that palm oil has played in past LUC and that projected growth in palm oil production may play in LUC until 2020 and suggest...

130

Malaysia: Oilseeds and Products. Update (Nov), 2007. GAIN Report Number MY7041.  

Malaysia's crude palm oil (CPO) production declined 1.4 percent to 1.58 MMT in October. The small decline in palm oil production was more than offset by a bigger decrease in CPO exports and domestic disappearance, resulting in an increase in carryout stoc...

131

Evaluation of palm oil esters as diesel  

Laboratory and mini-pilot plant preparation of Me esters from crude palm oil and crude stearin was successfully studied. Preliminary evaluation of palm oil Me esters was initiated based on laboratory analyses, testing on stationary engine, and field testing on vehicle. Preliminary technical and economic evaluation was carried out.

132

Nitrogen management is essential to prevent tropical oil palm plantations from causing ground-level ozone pollution  

More than half the world's rainforest has been lost to agriculture since the Industrial Revolution. Among the most widespread tropical crops is oil palm (Elaeis guineensis): global production now exceeds 35 million tonnes per year. In Malaysia, for example, 13% of land area is now oil palm plantatio...

133

Nitrogen management is essential to prevent tropical oil palm plantations from causing ground-level ozone pollution  

More than half the world's rainforest has been lost to agriculture since the Industrial Revolution. Among the most widespread tropical crops is oil palm (Elaeis guineensis): global production now exceeds 35 million tonnes per year. In Malaysia, for example, 13% of land area is now oil palm plantation, compared with 1% in 1974. There are enormous pressures to increase palm oil production for food, domestic products, and, especially, biofuels. Greater use of palm oil for biofuel production is predicated on the assumption that palm oil is an ‘‘environmentally friendly'' fuel feedstock. Here we show, using measurements and models, that oil palm plantations in Malaysia directly emit more oxides of nitrogen and volatile organic compounds than rainforest. These compounds lead to the production of ground-level ozone (O3), an air pollutant that damages human health, plants, and materials, reduces crop productivity, and has effects on the Earth's climate. Our measurements show that, at present, O3 concentrations do not differ significantly over rainforest and adjacent oil palm plantation landscapes. However, our model calculations predict that if concentrations of oxides of nitrogen in Borneo are allowed to reach those currently seen over rural North America and Europe, ground-level O3 concentrations will reach 100 parts per billion (109) volume (ppbv) and exceed levels known to be harmful to human health. Our study provides an early warning of the urgent need to develop policies that manage nitrogen emissions if the detrimental effects of palm oil production on air quality and climate are to be avoided.

134

The influenced of PAC, zeolite, and Moringa oleifera as biofouling reducer (BFR) on hybrid membrane bioreactor of palm oil mill effluent (POME).  

The main objective of this work was to determine the effectiveness of various biofouling reducers (BFRs) to operational condition in hybrid membrane bioreactor (MBR) of palm oil mill effluent (POME). A series of tests involving three bench scale (100 L) hybrid MBR were operated at sludge retention times (SRTs) of 30 days with biofouling reducer (BFR). Three different biofouling reducers (BFRs) were powdered actived carbon (PAC), zeolite (Ze), and Moringa oleifera (Mo) with doses of 4, 8 and 12 g L(-1) respectively were used. Short-term filtration trials and critical flux tests were conducted. Results showed that, all BFRs successfully removed soluble microbial products (SMP), for PAC, Ze, and Mo at 58%, 42%, and 48%, respectively. At their optimum dosages, PAC provided above 70% reductions and 85% in fouling rates during the short-term filtration and critical flux tests. PMID:21251818

135

Biological treatment of anaerobically digested palm oil mill effluent (POME) using a Lab-Scale Sequencing Batch Reactor (SBR)  

The production of highly polluting palm oil mill effluent (POME) has resulted in serious environmental hazards. While anaerobic digestion is widely accepted as an effective method for the treatment of POME, anaerobic treatment of POME alone has difficulty meeting discharge limits due to the high organic strength of POME. Hence, subsequent post-treatment following aerobic treatment is vital to meet the discharge limits. The objective of the present study is to investigate the aerobic treatment of anaerobically digested POME by using a sequencing batch reactor (SBR). The SBR performance was assessed by measuring Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD) and Total Suspended Solids (TSS) removal as well as Sludge Volume Index (SVI). The operating pH and dissolved oxygen con...

136

Green synthesis of gold nanoparticles using palm oil mill effluent (POME): a low-cost and eco-friendly viable approach.  

The present study reports the synthesis of gold nanoparticles (AuNps) from gold precursor using palm oil mill effluent (POME) without adding external surfactant, capping agent or template. The biosynthesized AuNps were characterized by using UV-vis spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). According to the image analysis performed on a representative TEM micrograph by counting 258 particles, the obtained AuNps are predominantly spherical with an average size of 18.75 ± 5.96 nm. In addition, some triangular and hexagonal nanoparticles were also observed. The influence of various reaction parameters such as reaction pH, concentration of gold precursor and interaction time to the morphology and size of biosynthesized AuNps was investigated. This study shows the feasibility of using agro waste material for the biosynthesis of AuNps which is potentially more scalable and economic due to its lower cost. PMID:22297042

137

Green synthesis of gold nanoparticles using palm oil mill effluent (POME): A low-cost and eco-friendly viable approach  

The present study reports the synthesis of gold nanoparticles (AuNps) from gold precursor using palm oil mill effluent (POME) without adding external surfactant, capping agent or template. The biosynthesized AuNps were characterized by using UV-vis spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). According to the image analysis performed on a representative TEM micrograph by counting 258 particles, the obtained AuNps are predominantly spherical with an average size of 18.75+-5.96nm. In addition, some triangular and hexagonal nanoparticles were also observed. The influence of various reaction parameters such as reaction pH, concentration of gold precursor and interaction time to the morphology and size of bios...

138

The influenced of PAC, zeolite, and Moringa oleifera as biofouling reducer (BFR) on hybrid membrane bioreactor of palm oil mill effluent (POME)  

The main objective of this work was to determine the effectiveness of various biofouling reducers (BFRs) to operational condition in hybrid membrane bioreactor (MBR) of palm oil mill effluent (POME). A series of tests involving three bench scale (100L) hybrid MBR were operated at sludge retention times (SRTs) of 30days with biofouling reducer (BFR). Three different biofouling reducers (BFRs) were powdered actived carbon (PAC), zeolite (Ze), and Moringa oleifera (Mo) with doses of 4, 8 and 12gL-1 respectively were used. Short-term filtration trials and critical flux tests were conducted. Results showed that, all BFRs successfully removed soluble microbial products (SMP), for PAC, Ze, and Mo at 58%, 42%, and 48%, respectively. At their optimum dosages, PAC provided above 70% reductions and 8...

139

Anaerobic co-digestion of palm oil mill effluent with rumen fluid as a co-substrate  

The semi-continuous stirred tank reactors (SCSTR) were applied under anaerobic mesophilic conditions at 37+/-3^oC to treat the supernatant layer of the raw palm oil mill effluent (POME). In this study, the anaerobically digested sludge POME (ADS-POME) was mixed with rumen fluid (RF) taken from the first compartment of cow's stomach (5% and 10% by volume) and used for co-digestion and then compared with (ADS-POME) for mono-digestion. The treatment was done at different hydraulic retention times (HRT): 20, 10 and 6days and organic loading rates (OLR): 1.65, 2.85 and 4.06gm COD/L d. The results showed that co-digestion (10% RF+90% ADS-POME) has high COD removal of 96.48% at 20days of HRT with lowest OLR of 1.65gm COD/L d and the higher methane content was 61.8% at 6days HRT with 4.06gm COD/L ...

140

Ultrasonic pretreatment of palm oil mill effluent: Impact on biohydrogen production, bioelectricity generation, and underlying microbial communities  

Substrate bioavailabity is one of the critical factors that determine the relative biohydrogen (bioH"2) yield in fermentative hydrogen production and bioelectricity output in a microbial fuel cell (MFC). In the present undertaking, batch bioH"2 production and MFC-based biolectricity generation from ultrasonically pretreated palm oil mill effluent (POME) were investigated using heat-pretreated anaerobic sludge as seed inoculum. Maximum bioH"2 production (0.7mmolH"2/gCOD) and COD removal (65%) was achieved at pH 7, for POME which was ultrasonically pretreated at a dose of 195J/mL. Maximum value for bioH"2 productivity and COD removal at this sonication dose was higher by 38% and 20%, respectively, than unsonicated treatments. In batch MFC experiments, the same ultrasound dose led to reduced ...

 
 
 
 
141

Start-up, steady state performance and kinetic evaluation of a thermophilic integrated anaerobic-aerobic bioreactor (IAAB)  

Thermophilic treatment of palm oil mill effluent (POME) was studied in a novel integrated anaerobic-aerobic bioreactor (IAAB). The IAAB was subjected to a program of steady-state operation over a range of organic loading rate (OLR)s, up to 30g COD/Lday in order to evaluate its treatment capacity. The thermophilic IAAB achieved high chemical oxygen demand (COD), biochemical oxygen demand (BOD) and total suspended solids (TSS) removal efficiencies of more than 99% for OLR up to 18.5g COD/Lday. High methane yield of 0.32LCH4 (STP)/g CODremoved with compliance of the final treated effluent to the discharge limit were achieved. This is higher than that of the mesophilic system due to the higher maximum specific growth rate (mmax) of the thermophilic microorganisms. Besides, coupling the model o...

142

The use of pretreated palm oil mill effluent for acetone?butanol?ethanol fermentation by Clostridium saccharoperbutylacetonicum N1-4  

Palm oil mill effluent (POME) was used as an acetone?butanol?ethanol (ABE) fermentation medium using Clostridium saccharoperbutylacetonicum N1-4. Various pretreatment methods were applied on POME to increase the amount of fermentable sugars leading to enhanced ABE production. Sulfuric acid-treated POME (SA-POME) method was found to give the highest yield of total reducing sugars (glucose, cellobiose, xylose, and arabinose) as compared to other pretreatment methods. An increment in the concentration of H2SO4 from 1 to 2% resulted in the enhanced release of reducing sugars (18.3, 26.3?g/L, respectively). However, the treatment of POME with 3% H2SO4, decreased the reducing sugars to 21.6?g/L and consequently, the total ABE production was also reduced. The highest yield of ABE was observed fro...

143

Continuous Production of Organic Acids from Palm Oil Mill Effluent with Sludge Recycle by the Freezing-Thawing Method  

The performance of the anaerobic treatment of palm oil mill effluent for organic acids production at a short retention time of less than 5 days was assessed by incorporating a sludge recycle system with no pH control except by adding calcium carbonate. The system could be operated successfully for a 3.5-day retention time at pH 5. The sludge solids in the treated effluent were separated by a freezing-thawing technique and it was partly recycled back to the reactor. The thawed clarified POME solution contained a low SS of 2,200–3,500 mg/L. The organic acids production with a concentration of 10–14 g/L was essentially similar to the treatment for a 5-day retention time without a sludge recycle. Hence by incorporating a sludge recycle system with the freezing-thawing method, the retention time for the treatment could be reduced without affecting the organic acids generation.   

144

Anaerobic digestion of palm oil mill effluent and condensation water waste: an overall kinetic model for methane production and substrate utilization  

The process of anaerobic digestion is viewed as a series of reactions which can be described kinetically both in terms of substrate utilization and methane production. It is considered that the rate limiting factor in the digestion of complex wastewaters is hydrolysis and this cannot be adequately described using a Monod equation. In contrast readily assimilable wastewaters conform well to this approach. A generalized equation has thus been derived, based on both the Monod and Contois equations, which serves extreme case. The model was verified experimentally using continuous feed anaerobic digesters treating palm oil mill effluent (POME) and condensation water from a thermal concentration process. POME represents a complex substrate comprising of unhydrolyzed materials whereas the condensation water is predominantly short chain volatile fatty acids. Substrate removal and methane production in both cases could be predicted accurately using the generalized equation presented. (orig.)

145

Effects of biomass, COD and bicarbonate concentrations on fermentative hydrogen production from POME by granulated sludge in a batch culture  

Effects of three selected variables viz. biomass concentration, initial chemical oxygen demand (COD) concentration and initial bicarbonate alkalinity (BA) on biological hydrogen production from palm oil mill effluent (POME) using the granulated sludge in batch culture were investigated. The experimental results were analyzed and modeled using a central composite design (CCD) of response surface methodology (RSM). In order to carry out a comprehensive analysis of the biohydrogen production process, indicative parameters namely hydrogen yield (Y"H), specific hydrogen production rate (SHPR), and COD removal efficiency were studied as the process responses. Maximum hydrogen yield (124.5 mmol H"2/g COD"r"e"m"o"v"e"d) and specific hydrogen production rate (55.42 mmol H"2/g VSS.d) were achieved a...

146

Calculation of the release of total organic matter and total mineral using the hydrodynamic equations applied to palm oil mill effluent treatment by cascaded anaerobic ponds.  

Anaerobic treatment processes to remove organic matter from palm oil mill effluent (POME) have been used widely in Malaysia. Still the amounts of total organic and total mineral released from POME that may cause degradation of the receiving environment need to be verified. This paper proposes the use of the hydrodynamic equations to estimate performance of the cascaded anaerobic ponds (CAP) and to calculate amounts of total organic matter and total mineral released from POME. The CAP efficiencies to remove biochemical oxygen demands, chemical oxygen demands, total solids and volatile solids (VS) as high as 94.5, 93.6, 96.3 and 98.2 %, respectively, are estimated. The amounts of total organic matter and total mineral as high as 538 kg VS/day and 895 kg FS/day, respectively, released from POME to the receiving water are calculated. The implication of the proposed hydrodynamic equations contributes to more versatile environmental assessment techniques, sometimes replacing laboratory analysis. PMID:22622964

147

Removal of Fe(III), Mn(II) and Zn(II) from palm oil mill effluent (POME) by natural zeolite  

The adsorption capacity of natural zeolite for the removal of heavy metal ions, zinc Zn(II), manganese Mn(II) and iron Fe(III), found in palm oil mill effluent was investigated in this study. The effects of contact time, agitation speed, pH, and sorbent dosage on the sorption of heavy metals were evaluated. The desorption potential of zeolite was also investigated. The sorption was fast with equilibrium reached within 180min. The metal sorption increased with pH, and adsorption capacities ranged between 0.015 and 1.157mg/g of zeolite. Equilibrium data followed the Langmuir isotherm model while the kinetic data were well described by the pseudo-second-order model. Maximum desorption was attained by HCl with 69.638, 58.575 and 61.516% of the initial adsorbed amount for Fe, Zn and Mn, respect...

148

The effect of unburned carbon in palm oil fuel ash on fluidity of cement pastes containing superplasticizer  

The aim of this study was to clarify the influence of unburned carbon in palm oil fuel ash (POFA) on the fluidities of cement pastes containing a polycarboxylate-based superplasticizer (SP). The POFA was ground in a ball mill to produce ground POFA (GPOFA). Unburned carbon, which was the major part of unburned residue in GPOFA, was removed by heating at 500degreeC for 1h, producing treated POFA (TPOFA). Neither glassy phase crystallization nor agglomeration of GPOFA particles occurred during the heat treatment. Cement pastes containing GPOFA and TPOFA had lower fluidities than that of ordinary Portland cement (OPC) paste. Cement pastes containing TPOFA had higher fluidities than cement pastes containing GPOFA. Unburned carbon absorbed more SP than did the other particles in the cement past...

149

The influence of enzyme and surfactant on biohydrogen production and electricity generation using Palm Oil Mill Effluent  

Batch production experiments on biohydrogen from Palm Oil Mill Effluent (POME) pretreated with (i) OPTIMASH BG^(R) (enzyme) and (ii) Tween 80^(R) (surfactant) were carried out using anaerobic seed sludge subjected to heat pretreatment at 105 ^oC for 90 min. Batch experiments were also conducted in a double chamber microbial fuel cell separated by a Proton Exchange Membrane (PEM) to study the amount of electricity produced. Results from a pretreatment with OPTIMASH BG^(R) at 0.20% and pH 7 showed a hydrogen yield of 1.88 mol H"2/g COD. Better results were obtained when the wastewater was pretreated with Tween 80^(R) at the same concentration and pH, where the hydrogen yield was 2.76 mol H"2/g COD. In all pretreatments, no methane production was observed when using the heat-treated sludge as...

150

Development of Bio-PORec® system for polyhydroxyalkanoates (PHA) production and its storage in mixed cultures of palm oil mill effluent (POME).  

High PHA production and storage using palm oil mill effluent (POME) was investigated using a laboratory batch Bio-PORec® system under aerobic-feeding conditions. Results showed that maximum PHA was obtained at a specific rate (q(p)) of 0.343C-mol/C-molh when air was supplied at 20ml/min. The PHA yield was found to be 0.80C-mol/C-mol acetic acid (HAc) at microaerophilic condition and the mass balance calculation showed that PHA production increased up to 15.68±2.15C-mmol/cycle. The experiments showed that short feeding rate, limited requirements for electron acceptors (e.g. O(2), NO(3)) and nutrients (N and P) showed lower tendency of glycogen accumulation and contributed more to PHA productivity. PMID:22989648

151

Conversion of biomass wastes to hydrogen by anaerobic fermentation process  

Sludge and slurry aqueous solution were collected from a lagoon of anaerobic treatment of palm oil mill effluent (POME). Compost was made from fibers of the fruits and the above collected microflora or only from microflora without fibers at 60 C under anaerobic or aerobic circumstances. The capability of these microflora to produce bio-hydrogen was examined with artificial wastewater containing glucose and nutrients or no nutrients under anaerobic circumstances. 1. qualitative studies on gas evolution with the dram/test tube method and 2. quantitative studies on gas evolution and composition of hydrogen/carbon dioxide gas in the reaction course were conducted. There was observed the total gas evolution of 1,340 ml/l - culture for 25 hours, consisting 61.9% of bio-hydrogen gas and 38.1% of carbon dioxide gas based on 1% of glucose and nutrients aqueous solution. (orig.)

152

Characteristics of Eutectic Compositions of Restructured Palm Oil Olein, Palm Kernel Oil and Their Mixtures  

The physico-chemical characteristics of blends of palm olein and palm kernel oil which were further modified by chemical interesterification were studied. The slip melting points of non-interesterified blends were 19.7, 16.2, 14.5, 14.5 and 14.4??C while those of the chemically interesterified blends were 17.7, 16.2, 19.8, 18.7 and 18.7??C at 40, 30, 20, 10 and 0% palm kernel oil, respectively. Chemical interesterification lowered the solid fat content of the pure samples and blends across different temperatures except 90% palm olein at 15??C where the solid fat content was higher than for non-interesterified samples. Palm kernel oil, palm olein and their blends before and after chemical interesterification, crystallized mainly in the ?? form. However, chemical interesterification modified...

153

The effects of palm kernel cake based diet on spermatogenesis in MalinxSanta-Ines rams  

Testes from nine male MalinxSanta-Ines rams with an average body weight of 43.1+-3.53kg, were used to study the effects of palm kernel cake (PKC) based diet on spermatogenic cells and to assess copper (Cu) levels in liver, testis and plasma in sheep. Animals were divided into three groups and randomly assigned three dietary treatments using restricted randomization of body weight in completely randomized design. The dietary treatments were 60% palm kernel cake plus 40% oil palm frond (PKC), 60% palm kernel cake plus 40% oil palm frond supplemented with 23mg/kg dry matter of molybdenum as ammonium molybdate [(NH4)6Mo7O244H2O] and 600mg/kg dry matter of sulphate as sodium sulphate [Na2SO4] (PKC-MS) and 60% concentrate of corn-soybean mix+40% oil palm frond (Control), the concentrate was mixe...

154

Contribution of plant-based sauces to the vitamin A intake of young children in Benin  

A food consumption survey on 420 children was conducted in four areas in Benin to identify the local vitamin A (VA)-rich foods most frequently eaten and assess their contribution to the coverage of VA requirements of young children. Mangoes, eggs, red palm oil, various leafy vegetable (LV) sauces and palm nut juice sauce appeared to be the main VA-rich foods consumed. The recipes of the most promising sauces were characterised. Sauces with red palm oil/palm nut juice showed high carotenoid contents ranging from 0.9+-0.3 to 4.0+-0.8mg Retinol Activity Equivalent/100g dry matter (DM). Lipid contents were also high (from 39.6 to 66.8g/100g DM). When consumed, and taking into account the mean quantity eaten per meal, LV sauces containing red palm oil or palm nut juice contributed to the meetin...

155

A high performance liquid chromatography method for determination of furfural in crude palm oil  

A modified steam distillation method was developed to extract furfural from crude palm oil (CPO). The collected distillates were analysed using high performance liquid chromatography (HPLC) coupled with an ultraviolet diode detector at 284nm. The HPLC method allowed identification and quantification of furfural in CPO. The unique thermal extraction of CPO whereby the fresh fruit bunches (FFB) are first subjected to steam treatment, distinguishes itself from other solvent-extracted or cold-pressed vegetable oils. The presence of furfural was also determined in the fresh palm oil from FFB (without undergoing the normal extraction process), palm olein, palm stearin, olive oil, coconut oil, sunflower oil, soya oil and corn oil. The chromatograms of the extracts were compared to that of standar...

156

NI\\S - NASA Technical Reports Server  

The high saturated fatty acid c·ontent of coconut oil and palm kernel oil ...... black tea. In cuhural terms, tea would appear to have fewer problems associ- ated with ... Cumin. Dill. Garlic. Ginger. Lavender. Marjoram, sweet. Mint. Mustard, white ...

157

Rapid Synthesis of Biodiesel Fuels at Room Temperature in the Presence of Dimethyl Ether  

Vegetable oil such as corn, sunflower, rapeseed, soybean, and palm oil was completely transesterified into biodiesel fuel at short time because of high mass-transfer rate in the homogeneous solution formed by adding environmental-friendly solvent of dimethyl ether (DME).   

158

( coal, gas, hydrocarbon, sea, air) Nutrients (fertilizer requirements )  

124000 bbl/day. Jennings. 1939. Synfuel plants. Congrsman. VonOham. Oil ..... biodesiel (biodiesel blends, e.g., palm oil, algae, halophytes), synthetic fuel, methane ... To Build a Greenhouse (currently being purchased) investigating up to 6 ...

159

Tissue and temporal expression of miR172 paralogs and the AP2-like target in oil palm (Elaeis guineensis Jacq.)  

Oil palm is an economically important crop, and floral development is a critical process in oil palm productivity. MicroRNA172 (miR172) has been shown to be an important regulator of the APETALA2 (AP2)-like family transcription factors involved in floral timing in a number of plants and belongs to a group of highly conserved microRNA that can be identified based on sequence homology. We identified six oil palm miR172 paralogs, representing two distinct mature miR172 isoforms based on sequence identity and predicted hairpin structures and an AP2-like target, using a combination of RT-PCR cloning and bioinformatic analysis of oil palm expressed sequence tags data. Although oil palm miR172 cleavage products were detected through 5â?²-rapid amplification of cDNA ends, mature miR172a and the AP...

160

Determination of Optimum Temperature for the Laboratory Preparation of Biodiesel from Nigerian Palm Kernel Oil  

As Nigeria envisions transition from finite fossil energy requirements to a safer, sustainable, and renewable alternative, local palm kernel oil is investigated as an alternative source of diesel fuel through potassium hydroxide catalyzed transesterification with ethanol. Three replicated experimental runs were conducted at 30°C, 37.5°C, 45°C, 52.5°C, 60°C, 65°C, and 70°C under reaction conditions of 100 g palm kernel oil, 1.0% potassium hydroxide, 20% ethanol (wt% palm kernel oil) and 90 min reaction time. Results show some palm kernel oil biodiesel properties to be within standard fuel specifications, while average palm kernel oil biodiesel yields of 59.0%, 69.0%, 77.4%, 87.5%, 95.4%, 95.4%, and 94.4% were obtained for the respective reaction temperatur...

 
 
 
 
161

Characterization of Apigenin and Luteolin Derivatives from Oil Palm (Elaeis guineensis Jacq.) Leaf Using LC-ESI-MS/MS.  

The palm oil industry generates several byproducts, and more than half of the dry weight of the waste is of oil palm leaf whereby the tissue is underutilized. Recently, several research studies found promising potential of oil palm fronds as a source of nutraceutical due to its bioactive properties. However, the chemical composition of the tissue is still not deciphered. Using reversed-phase liquid chromatography (LC) electrospray mass spectrometry (ESI-MS), glycosylated apigenin and luteolin were separated and identified from oil palm (Elaeis guineensis Jacq.) leaf and structures of the constituents were elucidated by collision-induced dissociation (CID) tandem MS. From 28 derivatives of the flavones, 9 compounds were conjugated with hydroxymethylglutaric (HMG) acid. Improved knowledge on oil palm especially on bioactive component of the leaf tissue will allow correlation of its beneficial effects and further promotes efficient utilization of this agriculture byproduct. PMID:23116142

162

Exploitation of inexpensive substrates for production of a novel SCL?LCL-PHA co-polymer by Pseudomonas aeruginosa MTCC 7925  

Studies conducted with various inexpensive carbon sources such as whey, vegetable oils (palm, mustard, soybean and coconut), a low-cost source of glucose-D, rice and wheat bran, and mustard and palm oil cakes demonstrated palm oil as the best substrate for accumulation of a novel short-chain-length?long-chain-length polyhydroxyalkanoate (SCL?LCL-PHA) co-polymer containing SCL 3HAs [3-hydroxybutyric acid (3HB) and 3-hydroxyvaleric acid (3HV)] and LCL 3HAs of 3-hydroxyhexadecanoic acid (3HHD) and 3-hydroxyoctadecanoic acid (3HOD) units as constituents by a sludge-isolated Pseudomonas aeruginosa MTCC 7925. The co-polymer content reached up to 60% of dry cell weight (dcw) at 48?h of incubation in 0.5% (v/v) palm oil and the extract of 0.5% (v/v) palm oil cake supplemented vessels. The PHAs poo...

163

Biosynthesis and characterization of poly(3-hydroxybutyrate-co-3- hydroxyhexanoate) from palm oil products in a Wautersia eutropha mutant.  

Palm kernel oil, palm olein, crude palm oil and palm acid oil were used for the synthesis of poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) [P(3HB-co-3HHx)] by a mutant strain of Wautersia eutropha (formerly Ralstonia eutropha) harboring the Aeromonas caviae polyhydroxyalkanoate (PHA) synthase gene. Palm kernel oil was an excellent carbon source for the production of cell biomass and P(3HB-co-3HHx). About 87% (w/w) of the cell dry weight as P(3HB-co-3HHx) was obtained using 5 g palm kernel oil/l. Gravimetric and microscopic analyses further confirmed the high PHA content in the recombinant cells. The molar fraction of 3HHx remained constant at 5 mol % regardless of the type and concentration of palm oil products used. The small amount of 3HHx units was confirmed by 13C NMR analysis. The number average molecular weight (M(n)) of the PHA copolymer produced from the various palm oil products ranged from 27 0000 to 46 0000 Da. The polydispersity was in the range of 2.6-3.9. PMID:16215858

164

Different palm oil production systems for energy purposes and their greenhouse gas implications  

This study analyses the greenhouse gas (GHG) emissions of crude palm oil (CPO) and palm fatty acid distillate (PFAD) production in northern Borneo (Malaysia), their transport to the Netherlands and their co-firing with natural gas for electricity production. In the case of CPO, conversion to biodiesel and the associated GHG emissions are also studied. This study follows the methodology suggested by the Dutch Commission on Sustainable Biomass (Cramer Commission). The results demonstrate that land use change is the most decisive factor in overall GHG emissions and that palm oil energy chains based on land that was previously natural rainforest or peatland have such large emissions that they cannot meet the 50-70% GHG emission reduction target set by the Cramer Commission. However, if CPO production takes place on degraded land, management of CPO production is improved, or if the by-product PFAD is used for electricity production, the emission reduction criteria can be met, and palm-oil-based electricity can be considered sustainable from a GHG emission point of view. Even though the biodiesel base case on logged-over forest meets the Cramer Commission's emission reduction target for biofuels of 30%, other cases, such as oil palm plantations on degraded land and improved management, can achieve emissions reductions of more than 150%, turning oil palm plantations into carbon sinks. In order for bioenergy to be sustainably produced from palm oil and its derivatives, degraded land should be used for palm oil production and management should be improved. (author)

165

Effects of palm oil blended with oxidized fish oil on growth performances, hematology, and several immune parameters in juvenile Japanese sea bass, Lateolabrax japonicas.  

A 60-day feeding trial was conducted to determine the effects of palm oil blended with oxidized and non-oxidized fish oil on growth performances, hematology, and non-specific immune response in juvenile Japanese sea bass, Lateolabrax japonicas. Japanese sea bass (1.73 ± 0.01 g) were fed seven experimental diets containing 100 g/kg of dietary lipid in forms of palm oil (10P), fish oil (10F), fish oil blended with palm oil at different ratios, 6:4 (6F4P) and 4:6 (4F6P), oxidized fish oil (10OF), and oxidized fish oil blended with palm oil at different ratios, 6:4 (6OF4P) and 4:6 (4OF6P). After the feeding trial, the following results were illustrated. No significant effects were observed in survival, feed conversion ratio, condition factor, and hematocrit after feeding with experimental diets for 60 days. The relatively higher specific growth rate and hematology were observed in 6F4P. Furthermore, both palm oil and oxidized fish oil acted as a negatively on serum lysozyme activity (P palm oil seems to have the ability to improve the protein efficiency when added to oxidized fish diets as well as a positive trend to the growth performance (P > 0.05). PMID:22763698

166

The impact of dietary oil source and frozen storage on the physical, chemical and sensorial quality of fillets from market-size red hybrid tilapia, Oreochromis sp.  

Red hybrid tilapia (Oreochromis sp.) were fed one of four diets containing either fish oil, crude palm oil, palm fatty acid distillates or refined palm olein as the only added oil. Post-harvest fillet quality was then evaluated at 1, 10 and 30 weeks of frozen storage. Dietary oil source did not significantly (p>0.05) influence the liquid holding capacity and texture of fillets but both these parameters were increased by frozen storage. Fillets from fish fed palm oil-based diets exhibited significantly higher oxidative stability during frozen storage, compared to fish fed the fish oil diet. Dietary oil source and frozen storage had little impact on sensory attributes. Unlike fillet proximate composition, fillet fatty acid composition was significantly affected by both diet and frozen storag...

167

Energy use analysis of selected palm-kernel oil mills in south western Nigeria  

Energy use patterns and utilisation efficiencies in 40 factories producing palm kernel oil (PKO) in southwestern part of Nigeria were studied. The factories were stratified into small, medium and large scale categories based on the mode of operations and production capacities. Questionnaires were administered on the factories to obtain historical data on petrol, diesel and electricity consumption and PKO production outputs for seven years (1998-2004). Energy use efficiency indicators employed include: energy intensity (EI), energy cost per unit product (EC/P), energy ratio (ER), food energy ratio (FER) and percentage oil yield by weight. Results of the study indicated that averagely, 0.58, 0.53 and 0.74 GJ/10{sup 3} l of PKO were needed in the small, medium and large PKO factories, respectively. The average food energy ratios in the small, medium and large mills are 2.48, 2.53 and 2.14, respectively. The corresponding values of PKO conversion ratio are 0.43, 0.50 and 0.35. Electrical energy consumption in medium and large mills was lower than thermal energy due to irregularity and decline in electricity supply from the national grid. The results of the study has provided required baseline information needed for budgeting, comparison of yearly energy consumption, forecasting energy requirements and planning expansion in PKO factories. (author)

168

Potassium hydroxide catalyst supported on palm shell activated carbon for transesterification of palm oil  

In this study, potassium hydroxide catalyst supported on palm shell activated carbon was developed for transesterification of palm oil. The Central Composite Design (CCD) of the Response Surface Methodology (RSM) was employed to investigate the effects of reaction temperature, catalyst loading and methanol to oil molar ratio on the production of biodiesel using activated carbon supported catalyst. The highest yield was obtained at 64.1 C reaction temperature, 30.3 wt.% catalyst loading and 24:1 methanol to oil molar ratio. The physical and chemical properties of the produced biodiesel met the standard specifications. This study proves that activated carbon supported potassium hydroxide is an effective catalyst for transesterification of palm oil. (author)

169

The Effect of Lubricant Viscosity in High Pressure Forming  

In this research, the effects of viscosity of lubricant in cold work extrusion process were investigated. The experimental evaluation was carried out by using cold work plane strain extrusion apparatus with a pair of 45-degree die half angle and a symmetrical workpiece (billet). The billet material was annealed pure aluminum, A1100. The analytical evaluation was carried out using a visioplasticity method. The testing lubricant is RBD palm olein, RBD palm stearin and palm fatty acid distillate. The results were compared with the additive free paraffinic mineral oil. The result shows that palm oil has advantage in reducing the extrusion load. We confirmed that palm oil showed satisfactory lubrication performance, as compared to additive free paraffinic mineral oil.

170

Current status and policies on biodiesel industry in Malaysia as the world's leading producer of palm oil  

This article discusses current status of palm oil-based biodiesel industry in Malaysia, the policies introduced and strategies for its implementation. Due to renewability, high production rate, technical feasibility and role in reducing greenhouse gases (GHG) emission, palm oil is in the right position to supply the energy needs by the incorporation into the diesel supply. As a leading producer of palm oil, Malaysia has embarked on a comprehensive palm biofuel program since 1982. It has successfully established the use of palm biodiesel blend (B5) as a suitable fuel for the transport and industrial sectors through the introduction of the National Biofuel Policy. The current scenario of biodiesel program in Malaysia, as well as biofuel policies with respect to its use, technology, export, environmental issues and implementation aspects are thoroughly discussed. The roles of the policy towards the prosperity of the stakeholders, oil price and the reduction of greenhouse gasses are also highlighted. (author)

171

Fuel conversional aspects of palm oil and sunflower oil  

There are great differences between palm oil and palm kernel oil in physical and chemical characteristics. Palm oil contains mainly palmitic (16:0) and oleic (18:1) acids, the 2 common fatty acids and about 50% saturated, while palm kernel oil contains mainly lauric acid (12:0) and is more than 89% saturated. Palm is widely grown in Southeast Asia, and 90% of the palm oil produced is used for food, while the remaining 10% is used for nonfood consumption, such as production of oleo-chemicals. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. Compared to No. 2 diesel fuel, all of the vegetable oils are much more viscous, while methyl esters of vegetable oils are slightly more viscous. The methyl esters are more volatile than the vegetable oils. The soaps obtained from the vegetable oils can be pyrolyzed into hydrocarbon-rich products. The yield of conversion of the sunflower oil reached the maximum 78.3% at 660 K over ZnCl{sub 2} catalyst. (Author)

172

Utilization of biodiesel waste as a renewable resource for activated carbon. Application to environmental problems  

Stepping into the new globalized and paradigm shifted era, a huge revolution has been undergone by the oil palm industry. From a humble source of the edible oil, today oil palm has demonstrated a wide variety of uses, almost by every part of its plant. With the price of the crude petroleum hitting record height every other day, the feasibility of palm oil and oil palm biomass as renewable substitutes for the production of biodiesel has been proposed. Lately, its development has received various criticisms, mainly hinges on the huge generation of solid residues which are currently no profitable use. In view of the aforementioned reason, this paper presents a state-of-the-art review of oil palm industry, its fundamental background studies, propagation and industrial applications. Moreover, the recent developments on the preparation of activated carbons from oil palm waste, its major challenges together with the future expectation are summarized and discussed. Conclusively, the expansion of oil palm waste in the field of adsorption science represents a potentially viable and powerful tool, leading to the superior improvement of pollution control and environmental conservation. (author)

173

Catalytic conversion of palm oil over mesoporous aluminosilicate MCM-41 for the production of liquid hydrocarbon fuels  

The catalytic cracking of palm oil to liquid hydrocarbon fuels was studied in a fixed bed micro-reactor operated at atmospheric pressure, reaction temperature of 723 K and weight hourly space velocity (WHSV) of 2.5 h{sup -1} over the synthesized mesoporous molecular sieve MCM-41 materials. Mesoporous aluminosilicate with Si/Al ratio of 50 was synthesized using the hydrothermal method. Different pore sizes were obtained by changing the type of template and organic directing agent (ODA) used. The synthesized materials were characterized using various analytical methods such as X-ray powder diffraction (XRD), BET surface area, inductive coupled plasma (ICP), MAS NMR, FTIR and temperature-programmed desorption (TPD). The materials exhibit a crystalline structure of MCM-41 mesoporous molecular sieves with surface area varying from 550 to 1200 m{sup 2}/g and an average pore size (APS) ranging from 1.8 to 2.8 nm. The synthesized MCM-41 catalysts show high activity for palm oil cracking. The conversion of palm kernel oil, lower-molecular-weight oil, was higher as compared to higher-molecular-weight, palm olein oil. MCM-41 materials were selective for the formation of linear hydrocarbons, particularly, C{sub 13} when palm kernel oil was used and C{sub 17} when palm olein oil was fed. The yield of liquid product decreased with the increase of surface area of the catalyst. The gasoline selectivity increased whereas diesel selectivity decreased with the conversion of palm oil.

174

Waste-to-wealth: green potential from palm biomass in Malaysia  

This paper gives an overview of the green potential of the palm biomass industry, which contributes to Malaysia's economic and sustainable development. An overall picture of the green development indicators of the country is provided based on the authors' experiences in policy making, research and business development. The emerging palm biomass industry in Malaysia is foreseen to dominate the country's directional development in the coming years, particularly when the sustainability issue is raised globally. With the increasing volume of palm oil residue accumulation due to palm oil production, palm biomass is gaining significant attention and being increasingly utilised to produce various green products as well as highly valuable biochemicals, such as bioethanol, vitamins, etc. The palm o...

175

Comparison of fatty acids, vitamin E and physicochemical properties of Canarium odontophyllum Miq. (dabai), olive and palm oils  

Canarium odontophyllum Miq. fruit (dabai) is an important food and oil resource for the native people in Sarawak, Malaysia. However, there is little information regarding their oil composition. In this paper, fatty acid compositions, vitamin E contents and physicochemical properties of dabai pulp and kernel oils were studied. These parameters were compared with commercial olive and palm oils. The content of total saturated fatty acid was found to be 44.4% in dabai pulp, kernel (60.8%), palm oil (47.9%) and olive (25.5%) oils. Palmitic, myristic, oleic and linoleic acids were detected in dabai pulp oil (36.1, 5.8, 41.5 and 11.8%) dabai kernel oil (46.4, 9.3, 35.1 and 2.8%), palm oil (33.8, 9.2, 39.7 and 10.9%) and olive oil (9.9, 12.9, 64.4 and 5.1%). Vitamin E was not detected in the dabai...

176

Complementary biodiesel combination from tung and medium-chain fatty acid oils  

The complementary blending of tung oil biodiesel with coconut oil and palm kernel oil biodiesels was investigated to improve the biodiesel properties. Tung oil is considered a potential non-edible oil feedstock for biodiesel production. However, tung oil biodiesel has unfavorable fuel properties, including a high density, kinematic viscosity, and iodine value and low oxidation stability because of the high content of a-elaeostearic acid (C18:3). In contrast, medium-chain saturated fatty acid methyl esters (FAMEs) such as lauric acid methyl ester (C12:0) is the predominant component in palm kernel oil and coconut oil biodiesels. The palm kernel oil and coconut oil biodiesels exhibited a low density, kinematic viscosity, and iodine value as well as high oxidation stability, features that are...

177

Industrial Waste Utilization for Low-Cost Production of Raw Material Oil Through Microbial Fermentation.  

In view of ever-growing demand of biodiesel, there is an urgent need to look for inexpensive and promising renewable raw material oils for its production. In this context, the aim of this study was to evaluate the potential use of industrial wastes for low-cost production of oils through microbial fermentation. Among the strains tested, Yarrowia lipolytica grew best and produced highest lipid when grown on decanter effluent from palm oil mill. When crude glycerol by-product from a biodiesel plant was added into the effluent as a co-substrate, Y. lipolytica produced a higher biomass of 3.21 g/L and a higher amount of lipid of 2.21 g/L which was 68 % of the dry weight. The scale up and process improvement in a 5-L bioreactor increased the biomass and lipid up to 5.53 and 2.81 g/L, respectively. A semi-continuous mode of operation was an effective mode for biomass enhancement while a fed-batch mode was effective for lipid enhancement. These yeast lipids have potential to be used as biodiesel feedstocks because of their similar fatty acid composition to that of plant oil. PMID:23151967

178

Oil palm waste for the production of bio-ethanol  

Malaysia, as one of the top producers of palm oil in the world, is well positioned to take advantage of its enormous output of lignocellulosic biomass, the oil palm residues. It is a potential source that can be used as a raw material for the production of bio-ethanol by fermentation of glucose obtained from the hydrolysis process. There were two main objectives for this study; to determine the effect of sulfuric acid concentration and reaction period on the glucose yields from hydrolysis of oil palm trunk and to determine the effect of temperature and pH on the ethanol yields from fermentation of oil palm trunk hydrolysates using Saccharomyces cerevisae. Oil palm trunk was prepared in 40 mesh sizes and dried to 5 % moisture content prior to chemical analysis and hydrolysis. The two stage concentrated acid sulfuric hydrolysis process with different acid concentration and time were performed on oil palm trunk samples. The hydrolysates obtained were used in the fermentation process with different temperature and pH. Results showed that highest glucose yields for oil palm trunk could be achieved by using 60 % acid concentration reacted for 60 minutes during 1st stage hydrolysis and subsequently followed by 30 % acid concentration reacted 60 minutes during 2nd stage hydrolysis. While the highest ethanol yields were obtained with the temperature of 30 deg C and pH6 from the fermentation process. (orig.)

179

Anti-friction additives for lubricating oils  

A lubricating oil composition is described comprising (i) a major portion of lubricant oil; and (ii) from about 0.05 to about 10.0 wt.% of, as an additive, a product prepared by reacting a natural oil selected from the group consisting of coconut, babassu, palm, palm kernel, olive, castor, peanut, beef tallow and lard, with a (C/sub 2/-C/sub 10/) hydroxy acid and a polyamine.

180

Liquid fuel from fast pyrolysis of oil palm solid wastes  

An investigation was conducted on the potential of producing liquid fuel from oil palm solid waste, particularly the palm fruit shell, by fast pyrolysis. For this purpose, a continuous fluidized bed fast pyrolysis system has been constructed. Fast pyrolysis was performed by feeding oil palm solid waste directly into the bubbling hot sand bed at a temperature ranging from 400 to 600 degrees centigrade in an inert atmosphere. The condensed liquid product was analysed for its properties as potential fuel and compared to petroleum fuel. The fuel characteristics compared were the physical properties, heating value, elemental analysis and chemical composition. The influence of some of the process conditions on the relative proportions of the liquid product and its properties and characteristics are presented. The results show the high potential of fast pyrolysis of oil palm solid waste particularly palm shell as an attractive source of a renewable energy in the form of liquid fuel. (author). 2 tabs., 4 figs., 7 refs.

 
 
 
 
181

Investigation on Nonlinear-Optical Properties of Palm Oil/Silver Nanoparticles  

We have investigated the spatial self phase modulation of palm oil containing silver nanoparticles (palm oil/Ag-NPs). The study carried out using continuous wave diode pumped solid state laser with wavelength of 405 nm and power of 50 mW. The strong spatial self phase modulation patterns were observed that suggest the palm oil/Ag-NPs have a relatively large nonlinear refractive index. The obtained values of nonlinear refractive index were increased with the increment in the volume fractions. The observed experimental patterns were also theoretically modeled which are in good agreement with experimental results.

182

Strategic environmental assessment for sustainable expansion of palm oil biofuels in Brazilian north region  

Biofuels development in Brazil is a key factor for the environment and sustainable development of the country. Brazil has great potential of available areas and has favourable climate and geography for biofuel production, such as palm oil, soy, sugar cane, etc. This research aims to evaluate palm oil production and expansion in Para state, in the north of Brazil and also Amazonian territory. Degraded land will be evaluated through remote sensing, because palm oil crops should be placed in these lands, and secondly, expansion scenarios would be created. This PhD research will be a decision support tool for public policies.

183

Evaluasi Keambaan, Daya Serap Air, dan Kelarutan dari Daun Sawit, Lumpur Sawit, Bungkil Sawit, dan Kulit Buah Coklat Sebagai Pakan Domba (The Evaluation of Voluminous, Water Regain, and Solubility on Palm Oil Leaf, Sludge, Palm Kernel Meal, and Cocoa Pod as Sheep Ration)  

The objective of this study was to evaluate voluminous, water regain, and solubility of palm oil leaf, sludge, palm kernel meal, and cocoa pod. The experiment was arranged in the randomized completely design with 6 times replicated. The result of research showed that voluminous, water regain, and s...

184

NASA Visible Earth: Palm Valley, Australia  

... rocks that have been folded and tilted during ancient episodes of mountain building. ... This is Palm Valley, which contains rare species of palms, some of which can be ... Scientists are using radar data of this region in studies of oil and gas ...

185

0 c! 0  

The dark streaks are extensive oil slicks surrounding many of the .... This is Palm Valley, which contains rare species of palms, some of which can be ... appear red due to the alignment of streets and buildings to the incoming radar beam. Thc ...

186

Characterization of the chloroplast genome sequence of oil palm (Elaeis guineensis Jacq.)  

Oil palm (Elaeis guineensis Jacq.) is an economically important crop, which is grown for oil production. To better understand the molecular basis of oil palm chloroplasts, we characterized the complete chloroplast (cp) genome sequence obtained from 454 pyrosequencing. The oil palm cp genome is 156,973bp in length consisting of a large single-copy region of 85,192bp flanked on each side by inverted repeats of 27,071bp with a small single-copy region of 17,639bp joining the repeats. The genome contains 112 unique genes: 79 protein-coding genes, 4 ribosomal RNA genes and 29 tRNA genes. By aligning the cp genome sequence with oil palm cDNA sequences, we observed 18 non-silent and 10 silent RNA editing events among 19 cp protein-coding genes. Creation of an initiation codon by RNA editing in rp...

187

Processing practices of small-scale palm oil producers in the Kwaebibirem District, Ghana: A diagnostic study  

Ghana produces about 2,000,000 metric tons of oil palm fruits annually, and small-scale processors contribute about 60% of crude palm oil production. The country is not self-sufficient in the fats and oils needed for industrial use and home consumption. A large percentage of the palm oil produced by small-scale processors cannot be utilized by the larger scale industries in Ghana or abroad because of its poor quality. There is an urgent need to explore the causes and to identify ways to address the situation. We carried out a diagnostic study in the Kwaebibirem District using key informant interviews, focus group discussions and surveys based on a semi-structured questionnaire to assess the processing practices of small-scale oil palm fruit processors, and to analyse the rationale behind t...

188

Effects of different oils on the properties of soy protein isolate emulsions and gels  

The emulsion properties, protein adsorption and visco-elastic properties of heat-treated soy protein isolate (SPI) emulsions containing sunflower oil, soy oil and palm stearin were studied at neutral pH. The rheological properties, textural profile and fat adsorption capacity of subsequently induced glucono-d-lactone (GDL) gels were investigated. At neutral pH the palm stearin emulsions showed higher stability than the sunflower and soy oil emulsions. The former also showed higher protein adsorption, emulsifying activity index and visco-elastic properties than the latter, indicating a higher denaturation degree for SPI at the oil/water interface of palm stearin emulsions at neutral pH. Acidified SPI-palm stearin emulsion gels were significantly harder than the soy and sunflower oil version...

189

Synthesis of a base-stock for electrical insulating fluid based on palm kernel oil  

This report presents a method for synthesizing base-stock for green industrial product from a vegetable oil with a high composition of unsaturated fatty acids. Epoxy methyl ester of palm kernel oil was synthesized from laboratory purified palm kernel oil using a two-step reaction and the products were used as a base-stock for green electrical insulation fluid. Epoxidized palm kernel oil was first prepared through epoxidation reaction involving purified palm kernel oil, acetic acid and hydrogen peroxide in the presence of amberlite as catalyst which lasted for 4h. It was then followed by transesterification reaction involving the epoxidized product and methanol in the presence of sodium hydroxide as catalyst to synthesize the corresponding epoxy methyl ester. The thermal and electrical brea...

190

Microemulsion-based palm kernel oil extraction using mixed surfactant solutions  

This study introduces a novel technique using surfactant microemulsion-based oil seed extraction. To achieve this objective, microemulsion formation with palm kernel oil was studied first. Then, the selected microemulsion system was used for palm kernel extraction. The results showed that the mixed surfactant of 3wt% Comperlan KD and either 0.1wt% Alfoterra145-5PO or 145-8PO provided an ultralow interfacial tension with the palm kernel oil (0.0197 and 0.0359mN/m, respectively). By using those two aqueous surfactant systems for palm kernel oil extraction, the extraction efficiency was 93.99 and 94.13% at the optimum crushed kernel size between 0.212 and 0.425mm, using 1g seed load to 10ml of solution and 30min of contact time. The extracted oil quality was evaluated for water content, fatty...

191

Production of poly(3-hydroxybutyrate) and its copolymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Erwinia sp. USMI-20.  

A locally isolated soil microorganism identified as Erwinia sp. USMI-20 has been found to produce poly(3-hydroxybutyrate), P(3HB), from either palm oil or glucose and its copolymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate), P(3HB-co-3HV), from a combination of palm oil and a second carbon source of either one of the following compounds: propionic acid, n-propanol, valeric acid and n-pentanol. It was found that Erwinia sp. USMI-20 could produce P(3HB) up to 69 wt.% polymer content with a dry cell weight of 4.4 g/l from an initial amount of 14.5 g/l of glucose followed by a feeding rate of glucose at 0.48 g/h glucose. On the other hand, the bacteria can achieve 46 wt.% of P(3HB) and a dry cell weight of 3.6 g/l from a batch fermentation in a 10-l fermentor from an initial concentration of 4.6 g/l of palm oil. Further characterisation of the polymer production was also carried out by using different types of palm oil. Among the different palm oils that were used, crude palm oil was the best lipid source for P(3HB) production as compared to palm olein and palm kernel oil. In the production of the copolymer, P(3HB-co-3HV), the highest mole fraction of 3-HV units could be as high as 47 mol% from a single feeding of valeric acid upon initial growth on palm oil. PMID:10416655

192

Frying oil use in China  

Abstract The rapid development of China's economy has resulted in a dramatic increase in the production and purchase of instant fried food products by consumers. China's food industry has relied largely on the importation of soybean oil and palm oil. Palm oil is widely used by the commercial food industry because of its high oxidative stability and low cost. In contrast, the demand for rapeseed oil and peanut oil has gradually increased but only for domestic frying. In the future, specialized frying oils with improved stability and function will be developed for industrial and domestic frying in China.

193

Research on possibility of utilization of palm methylester for diesel engines; Palm yu kara no yusoyo bio fuel jitsuyoka kanosei chosa  

It is expected that palm oil will reduce black smoke/particulates in exhaust gas from the diesel engine. Therefore, an investigation for practical application of palm oil is made on adaptability as a fuel oil and supply potential. For utilization of palm oil to diesel engines, it is necessary to depress a pour point by methylesterification (methylester (ME) oil) and blending with light oil. When using ME oil, such improvements are seen as improved fuel consumption per heat quantity, reduced emission of black smoke/particulates and reduced emission of sulfur oxide; however, reduced emission of nitrogen oxide cannot be expected. When using ME Oil in Japan, 4,940,000 tons are required if it is blended with light oil at an average blending rate of 20%. In Malaysia, which is the largest palm oil producing country, production was 6,140,000 tons in 1991 and is estimated to be 7,600,000 tons in 1995 and 8,750,000 tons in 2000. For utilization of palm oil, supply potential of Indonesia is also expected. 42 figs., 47 tabs.

194

Storage degradation of palm-derived biodiesels: Its effects on chemical properties and engine performance  

Palm olein and palm stearin are co-products of palm oil refining processes having different melting point ranges. This study compares the storage degradation characteristics of biodiesels derived from these two palm products, which are palm olein and palm stearin, in terms of chemical properties, engine performance and exhaust emission. The degradation study was carried out by keeping biodiesels in dark closed-lid containers at room temperature for up to 6 months. It was found that the oxygen present in the container led to slow degradation of biodiesels through oxidative reaction with the double bonds in biodiesel. Within 6 months, the majority of oxidative products were composed of shorter hydroperoxide compounds and other short secondary products. These changes resulted in lower heating...

195

Wear characteristic of RBD palm olein using four-ball tribotester  

Palm oil shows a great potential to be used as a lubricant. It is a vegetable oil which is environmentally friendly and has a high biodegradability in comparison to mineral oil. However, the research of the properties of palm oil based lubricant from the industrial point of view has never been widely conducted. In this research, the tribological properties of RBD palm olein; which is one of the palm oil refine product, was tested with four-ball tribotester to investigate its wear resistance. The testing method followed the ASTM D4172. The investigation was continued with 40kg, 80kg and 120 kg normal loads. For comparison, similar experimental and analytical works were done with additive-free paraffinic mineral oil and their results were compared with RBD palm olein. The analysis focused on the temperature properties, friction coefficient and wear observation. Results show that RBD palm olein has a good wear resistance performance in high and low temperature compared to additive free paraffinic mineral oil, especially at high normal load.

196

Effect of jute fibre loading on tensile and dynamic mechanical properties of oil palm epoxy composites  

Hybrid composites prepared by hand lay-up technique by reinforcing jute and oil palm fibres with epoxy matrix. The tensile properties of hybrid composites were found to increase substantially with increasing jute fibres loading as compared to oil palm-epoxy composite. The nature of fibre/matrix interface was examined through scanning electron microscopy of tensile fracture samples. Addition of jute fibres to oil palm composite increases the storage modulus while damping factor shifts towards higher temperature region. Cole-Cole analysis was made to understand the phase behaviour of the composite samples. The hybrid composite with oil palm:jute (1:4) showed maximum damping behaviour and highest tensile properties. The overall use of hybrid system was found to be effective in increasing tens...

197

wFINAL REPORT SPACE SHUTTLE/FOOD SYSTEM STUDY  

c) cooked whole kernel corn d) apple slices e) plum slices .... Oil package was evaluated for suitability for the Shuttle Orbiter galley. Rehydration .... palm of the hand was pressed hard over the surface to prevent distortion and pressure relief.

198

Certification, with some shortcomings; Mit Luecken zertifiziert  

Cleared forests, dislodged farmers, and high emissions: There are serious doubts concerning the ecological quality of palm oil from Indonesia and Malaysia has serious. There are few producers that meet the EU sustainability criteria.

199

notice this document has been reproduced from microfiche ...  

A SEARCH FOR EXPERIMENTS TO EXPLOIT THE SPACE SHUTTLE ENVIRONMENT. It by. John B. ..... the depletion of oil and gas resources has renewed interest in achieving even small increases in ...... Trina Valencich. 1370 Palms Blvd.

200

Summary of Results from Space Shuttle Main Engine Off-Nominal ...  

displacement, and speed by exploiting Faraday's law of electromagnetic induction. ... Ultrasonic flowmeters are common within the water, oil, chemical and liquid ... Canoga Park teams, the PWR West Palm Beach turbomachiney team, and the ...

 
 
 
 
201

Atlantis stays on trackfor Tuesdaylift-off  

Jul 19, 1991 ... Story oil. LynflonB. Johnson SpaceCenter report. Story on Page 3. Page 4. Houston, Texas ...... Irons, 2-PW, Palm Springs premium model, new. '81 Mercedes .... shape space exploration and exploitation for the headquarters ...

202

1965 Budget Estimates, pt. VI  

Hartford, Connecticut and West Palm Beach, Florida acts as an associate contractor in the ...... comrmnicat ion, seeks the full exploitation of the communication satellite .... The launch vehicle will carry a television system of the type used OIL the ...

203

United Plantations certified despite gross violations of RSPO Standards  

This investigation reveals that deforestation, deep peat conversion, land disputes and illegal practices continue to occur in the plantation estates owned by a company that is RSPO (Roundtable on Sustainable Palm Oil) certified for parts of its operations.

204

How Unilever palm oil suppliers are burning up Borneo  

New evidence shows expansion by Unilever palm oil suppliers is driving species extinction in Central Kalimantan, and fuelling climate change. In November 2007, Greenpeace released 'Cooking the Climate', an 82-page report summarizing the findings of a two-year investigation that revealed how the world's largest food, cosmetic and biofuel companies were driving the wholesale destruction of Indonesia's rainforests and peatlands through growing palm oil consumption. This follow-up report provides further evidence of the expansion of the palm oil sector in Indonesia into remaining rainforests, orang-utan habitat and peatlands in Kalimantan. It links the majority of the largest producers in Indonesia to Unilever, probably the largest palm oil corporate consumer in the world.

205

Palm oil fruit shells as biosorbent for copper removal from water and wastewater: experiments and sorption models.  

Palm oil fruit shells were evaluated as a new bioadsorbent to eliminate toxic copper from water and wastewater. Without any chemical treatment, palm oil fruit shells were washed, dried and grounded into powder (palm oil fruit shells. The results indicate that the highest Cu removal efficiency was found in an aqueous solution with pH of 6.5. The equilibrium sorption capacity of copper was significantly high (between 28 and 60 mg/g) at room temperature. Nonlinear regression analyses for isotherm models revealed that three-parameter isotherms had a better fit to the experimental data (R(2)>0.994) than that of two-parameter isotherms. The copper sorption system was heterogeneous as the values of exponents were lying between 0 and 1. The highly correlated pseudo-second-order kinetics model (R(2)>0.998) ascertained the applicability of copper removal by palm oil fruit shells. PMID:22204888

206

The monster crop - how to tame it  

Malaysia's palm oil industry is going to significant lengths to meet sustainability requirements. However, the Malaysians do not want to be patronized by environmental groups from the West. (orig.)

207

Powered by palm oil?; Power mit Palmoel?  

The oil palm is used worldwide as an energy crop, even in moderate climates. Environmentalists are campaigning against it as indigenous forests are cut down. The contribution presents an outline. (orig.)

208

NASA - Education Weekly Activity Report (WAR)  

Apr 30, 2011 ... TARC teams are challenged to design, build and launch a model rocket that ..... The experiments were entitled Pepper Oil Surprise, Pondering the ..... Flight Competition was from Palm Bay Community Charter School (K-12).

209

Advanced Lubricants  

Sun Coast Chemicals (SCC) of Daytona Inc., Palm Court, Florida was ... the complete Space Shuttle from KSC's Vehicle Assembly Building to the launch pad ... applications ranging from industrial assembly lines to oiling a child's bicycle chain.

210

Dubai, February 2010 : Image of the Day  

Mar 12, 2010 ... Lacking oil, Dubai built its growth on finance, real estate, and tourism. ... Gigantic palm trees also sprouted along the coast—artificial islands made ... vegetation appears red, water appears dark blue, and buildings and paved ...

211

Relative Lifetimes of MAPLUB ®Greases for Space Applications  

building customized databases, organizing and publishing research results.., even providing videos. .... It confirmed that both oil and thickener were present on the ball surface. All specimens .... \\\\'est Palm Beach. (Florida), October. 27-31 ...

212

NASA Visible Earth: Dubai, February 2010  

Lacking oil, Dubai built its growth on finance, real estate, and tourism. ... of part of Dubai, including the resort island of Palm Jumeirah, on February 8, 2010. ... brown, vegetation appears red, water appears dark blue, and buildings and paved ...

213

Tribological Performance of Some Pennzane ® Based Greases for ...  

building customized data bases, organizing and publishing research results.., .... The greasesareall basedon a multiplyalkylatedcyclopentane(Pennzane_) oil [13]. A ..... XLGI 68 _'_Colfer, vce, \\Vest Palm Beach (Florida), October 27-31 2001.

214

102.kml  

Palm Island is a resort under construction on reclaimed land silhouetted against ... Kharg Island is Iran's primary oil export terminal in the Persian Gulf. .... The great white building of the Faisal Mosque appears on the northern margin of the city.

215

NASA - National Laboratory Pathfinder - Cells - Jatropha Biofuels ...  

5 days ago ... Vecenergy (The Vecellio Group), West Palm Beach, FL, United States ... family that produces seeds from which oil can be extracted for use as biofuel. ... J. curcas is a feasible species for the commercial production of biodiesel.

216

Rainforests for palm oil?; Regenwaldopfer fuer Palmoel?  

Environmentalists are all fired up as rainforests are cut down for palm oil production in south eastern Asia. An international certification system is to ensure sustainable production and save the rainforests. (orig.)

217

Perspectives: Why EOS Matters, 10 years later : Feature Articles  

Sep 8, 2009 ... Peak oil may have now occurred, bringing the specter of permanently ... accelerating new pressures on terrestrial ecosystems for biofuel production. ... 30 meter per pixel view of Malaysian palm plantations from Landsat 7.

218

JPL Technologies Chosen for Space Technology Hall of Fame  

Mar 13, 2008 ... Medical Technologies International, of Palm Desert, Calif., licensed the ... Marshall for experiments in orbital production of microspheres gave the basic design ... The natural and biodegradable product cleans up oil and other ...

219

Influence of soil aggregate size on greenhouse gas emission and uptake rate from tropical peat soil in forest and different oil palm development years  

The influence of oil palm development on tropical peat soil decomposition rate was investigated by an incubation experiment. Soil samples from soil surface and around underground water table were taken from forest site, and oil palm site at 1st and 9th year after development. The soil samples were sieved into 0-2mm, 2-8mm and 8-20mm and analyzed for carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) fluxes. The development of oil palm did not change the CO2 emissions and showed inconsistent influence on CH4 flux according to aggregate size, while significantly higher N2O emissions were found for aggregates 0-2mm at high moisture of oil palm plantation soils compared with the original forest. Nitrous oxide fluxes showed significant positive correlation with the CO2 flux, which indi...

220

JPL at Space Technology Hall of Fame  

Mar 13, 2008 ... Medical Technologies International, of Palm Desert, Calif., licensed the ... Marshall for experiments in orbital production of microspheres gave the basic design ... The natural and biodegradable product cleans up oil and other ...

 
 
 
 
221

Space Shuttle Navigation In The GPS Era  

aircraft to take advantage of the existing production line and logistics base. .... Oil a weighted least squares algorithm is used by Mission. Control for orbit determination. Ground-up ...... and Navigation Symposium, Palm Springs, CA,. 15 ...

222

NASA - JPL Technologies Chosen for Space Technology Hall of Fame  

Mar 13, 2008 ... Medical Technologies International, of Palm Desert, Calif., licensed the ... Marshall for experiments in orbital production of microspheres gave the basic design ... The natural and biodegradable product cleans up oil and other ...

223

Project H A Complete Spaceport Hydrogen Solution  

Local hydrogen production and liquefaction capability. - Sized for KSC ... Can be sent to Launch Complex 36, 40, or 41 , West Palm Beach or SSC for incorporation into ... efficiencies to be gained over current oil lubricated piston compressors ...

224

Enzymatic synthesis of palm-based ascorbyl esters  

The synthesis of palm-based ascorbyl esters through transesterification of ascorbic acid and palm oil in tert-amyl alcohol catalyzed by immobilized lipase is described. Highest conversion (70-75%) was determined after 16h reaction at 40degreeC using lipase (Novozyme 435 from Candida antartica) with an ascorbic acid to palm oil mole ratio of 1:8. The purified product was further characterized by 13C NMR and GC-MS and the mixture of ascorbyl monoesters obtained were identified as ascorbyl monooleate (61%), ascorbyl monopalmitate (30%) and ascorbyl monostearate (9%). The antioxidant activity of palm-based ascorbyl esters was evaluated by 1,1-diphenyl-2-picrylhydrazyl (DPPH) test. The results showed that pure palm-based ascorbyl esters have an antioxidant activity with an IC50 value of 0.1mg/m...

225

Investigation on thermochemical behaviour of low rank Malaysian coal, oil palm biomass and their blends during pyrolysis via thermogravimetric analysis (TGA)  

This study aims to investigate the behaviour of Malaysian sub-bituminous coal (Mukah Balingian), oil palm biomass (empty fruit bunches (EFB), kernel shell (PKS) and mesocarp fibre (PMF)) and their respective blends during pyrolysis using thermogravimetric analysis (TGA). The coal/palm biomass blends were prepared at six different weight ratios and experiments were carried out under dynamic conditions using nitrogen as inert gas at various heating rates to ramp the temperature from 25 to 900{sup o}C. The derivative thermogravimetric (DTG) results show that thermal decomposition of EFB, PMF and PKS exhibit one, two and three distinct evolution profiles, respectively. Apparently, the thermal profiles of the coal/oil palm biomass blends appear to correlate with the percentage of biomass added in the blends, thus, suggesting lack of interaction between the coal and palm biomass. First-order reaction model were used to determine the kinetics parameters for the pyrolysis of coal, palm biomass and their respective blends.

226

Evaluations of vegetable oil-based as lubricants for metal-forming processes  

Purpose - The purpose of this paper is to assess lubricating performances of selected locally produced vegetable oil-based lubricants with a view to utilizing them as a possible alternative to petroleum-based lubricants in metal-forming processes. Design/methodology/approach - The ring compression testing and twin disks upsetting testing methods were employed. Findings - The results obtained from these two tests showed that the red palm oil performed better than others at room temperature, followed by sheabutter oil, while palm kernel oil performed the least. High-temperatures compression ring tests gave sheabutter oil lower values of friction coefficients than red palm oil. Research limitations/implications - Further work should be done on numerous vegetable oil-based lubricants. Also tho...

227

The Kalimantan Border Oil Palm Mega-project  

A few years ago, the Indonesian government and sections of the palm oil industry united in the Indonesian Palm Oil Commission (IPOC) to undertake efforts to restore the atrocious public image that the palm oil industry had earned abroad for its role in the demise of Indonesia's tropical rainforests, the massive forest fires and haze in 1997-1998, and for the widespread conflicts between plantation companies and local communities. If IPOC succeeded in restoring the palm oil industry's image abroad, it was shattered again after June 2005 when the Indonesian Minister of Agriculture revealed details of a government plan to develop the world's largest oil palm plantation in a 5-10 kilometer band along the border of Kalimantan and Malaysia. To finance the USD 567 million plantation project, the Indonesian President and Chamber of Commerce and Industry (KADIN) had already met up with the Chinese government and private sector several times, resulting in Memoranda of Understanding between (among other) the Artha Graha and Sinar Mas groups from Indonesia and the Chinese CITIC group and Chinese Development Bank (CDB). The oil palm mega-project, launched in Indonesia under the banner of 'bringing prosperity, security and environmental protection to the Kalimantan border area', turned sour when a business plan developed by the Indonesian State Plantation Corporation (PTPN) began to circulate. This document contained a map that showed beyond doubt how the 1.8 million hectare oil palm project would trash the primary forests of three National Parks, cut through rugged slopes and mountains utterly unsuitable for oil palm cultivation and annihilate the customary rights land of the indigenous Dayak communities in the border area. This report describes what has come of the Kalimantan border oil palm mega-plan since it was announced, who is involved and what research, lobby and campaigning has led to so far. In particular, this study aims to inform civil society organizations, palm oil buyers, investors and government bodies outside Indonesia about the undiminished threats to the tropical rainforests and indigenous peoples related to Indonesia's oil palm expansion plans and the government's overall development agenda for Kalimantan.

228

Malaysian palm oil. Surviving the food versus fuel dispute for a sustainable future  

For the past few decades, palm oil has gone through a revolution that few would have predicted. From a humble source of edible oil that was heavily criticized as being un-healthy and un-fit for human consumption, it has proven itself based on scientific findings that it is indeed one of the most nutritious edible oils in the world. Besides, palm oil, the cheapest vegetable oil in the market has diversified as one of the main feedstock for oleo-chemical industries. Recently, with the price of crude petroleum hitting records height every other day, palm oil has become one of the few feasible sources for biodiesel, a renewable substitute for petroleum-derived diesel. Nevertheless, the conversion of palm oil into biodiesel has again received criticism from various NGOs worldwide, mainly on extinction of orang utans, deforestation and particularly the food versus fuel dispute. It was claimed that the conversion of food crops to fuel would significantly increase the number of undernourished people in the world. Malaysia, being the world second largest producer of palm oil, is not spared from this criticism. On the contrary, in the present study it was found that palm oil is indeed the most economical and sustainable source of food and biofuel in the world market. Besides, it was shown that it has the capacity to fulfill both demands simultaneously rather than engaging in priority debate. Nevertheless, fuel is now a necessity rather than a luxury for economy and development purposes. A few strategies will then be presented on how palm oil can survive in this feud and emerged as the main supply of affordable and healthy source of edible oil while concurrently satisfying the market demand for biodiesel throughout the world. (author)

229

Thermostability and polymorphism of theobroma oil and palm kernel oil as suppository bases  

Thermal stability of pharmaceutical ingredients is an important aspect. In this study, we adopted differential scanning calorimetry (DSC) to investigate thermal stability of suppository bases, theobroma oil (cocoa butter) and a palm kernel oil (PKO) blend. The study shows theobroma oil possesses six polymorphic forms whilst the palm kernel oil blend has three. Upon rescanning, the PKO blend does not show changes in the enthalpy of fusion and the melting point with time, whilst the theobroma oil shows significant reduction, and only regained its thermal stable state after 10 days. This indicates that PKO blend possesses better thermal stability.

230

Application of LC-NMR to analysis of carotenoids in foods  

LC-NMR has been applied to componential analysis of carotenoids in several foods, specifically, tomato juice, palm oil, and satsuma mandarin orange juice. The crude carotenoids extracted with organic solvent from these foodstuffs were analyzed after simple pre-processing. Three, four, and two kinds of carotenoids were identified for tomato juice, palm oil, and satsuma mandarin orange, respectively, primarily by comparing their NMR spectra with those of pure standard.

231

Application of LC-NMR to analysis of carotenoids in foods.  

LC-NMR has been applied to componential analysis of carotenoids in several foods, specifically, tomato juice, palm oil, and satsuma mandarin orange juice. The crude carotenoids extracted with organic solvent from these foodstuffs were analyzed after simple pre-processing. Three, four, and two kinds of carotenoids were identified for tomato juice, palm oil, and satsuma mandarin orange, respectively, primarily by comparing their NMR spectra with those of pure standard. PMID:19810055

232

Cooling for the biology; Abkuehlung fuer die Biologie  

The paper production is water intensive. At the paper mill Palm in Eltmann (FRG), the produced wastewater flows through the own treatment plant. The waste water not only is treated biologically, but also recycled as process water. This can reduce the fresh water demand by about 40 %. Due to fluctuations in the temperatures and volume flows of the waste water, the paper mill uses a free flow plate heat exchanger.

233

Stabilization of palm oils by using Ficus exasperata leaves in local processing methods.  

This work was done to ascertain the efficacy of the local use of Ficus exasperata leaves in processing palm oils to improve and stabilize the quality. Palm oils were obtained from the ripe fruits of Elaeis guineensis and Elaeis guineensis var virescens, including Ficus exasperata leaves in the traditional processing procedures--cooking and soaking the fruits in water. Phytochemical analysis of the Ficus leaves and the oils were performed. The quality of the oils were assessed in terms of saponification, acid and peroxide values, and free fatty acid content. Results showed the presence of phenolic compounds, terpenoids, alcohols and carbonyl compounds in the leaves. Oil from both oil palm varieties contained appreciable amounts of carotenoids, flavonoids and sterols, but only the Elaeis guineensis var virescens oil contained saponins. The use of the Ficus leaves eliminated saponins and the foaming tendencies of the var virescens oil, but reduced the sterol levels and increased the carotenoid levels in the oils from both oil palm varieties. Oils processed by soaking of fruits and use of the Ficus leaves had slightly greater saponification values, while oils processed by cooking of fruit and use of leaves had reduced FFA, acid and peroxide values. The use of Ficus exasperata leaves makes for a better stabilized oil with potentially good keeping qualities. PMID:15182838

234

Performance of a hybrid cylindrical roller bearing  

A 206-size hybrid (ceramic/steel) cylindrical roller bearing was tested in MIL-L-23699 C oil at several speeds and loads. Heat-generation data was collected and subsequently correlated with bearing-analysis software. Bearing-cage slip data was also collected at various oil-flow rates, oil temperatures, and with both MIL-L-7808 J and MIL-L-23699 C oils. The hybrid bearing was tested in MIL-L-23699 C oil for for 25 hours at 2220 N radial load and 1.08 MDN shaft speed. The hybrid bearing technology demonstrated in the report is applicable to the Integrated High Performance Turbine Engine Technology Initiative. 15 refs.

235

Establishing the evidence base for maintaining biodiversity and ecosystem function in the oil palm landscapes of South East Asia.  

The conversion of natural forest to oil palm plantation is a major current threat to the conservation of biodiversity in South East Asia. Most animal taxa decrease in both species richness and abundance on conversion of forest to oil palm, and there is usually a severe loss of forest species. The extent of loss varies significantly across both different taxa and different microhabitats within the oil palm habitat. The principal driver of this loss in diversity is probably the biological and physical simplification of the habitat, but there is little direct evidence for this. The conservation of forest species requires the preservation of large reserves of intact forest, but we must not lose sight of the importance of conserving biodiversity and ecosystem processes within the oil palm habitat itself. We urgently need to carry out research that will establish whether maintaining diversity supports economically and ecologically important processes. There is some evidence that both landscape and local complexity can have positive impacts on biodiversity in the oil palm habitat. By intelligent manipulation of habitat complexity, it could be possible to enhance not only the number of species that can live in oil palm plantations but also their contribution to the healthy functioning of this exceptionally important and widespread landscape. PMID:22006968

236

Characterization of the chloroplast genome sequence of oil palm (Elaeis guineensis Jacq.).  

Oil palm (Elaeis guineensis Jacq.) is an economically important crop, which is grown for oil production. To better understand the molecular basis of oil palm chloroplasts, we characterized the complete chloroplast (cp) genome sequence obtained from 454 pyrosequencing. The oil palm cp genome is 156,973 bp in length consisting of a large single-copy region of 85,192 bp flanked on each side by inverted repeats of 27,071 bp with a small single-copy region of 17,639 bp joining the repeats. The genome contains 112 unique genes: 79 protein-coding genes, 4 ribosomal RNA genes and 29 tRNA genes. By aligning the cp genome sequence with oil palm cDNA sequences, we observed 18 non-silent and 10 silent RNA editing events among 19 cp protein-coding genes. Creation of an initiation codon by RNA editing in rpl2 has been reported in several monocots and was also found in the oil palm cp genome. Fifty common chloroplast protein-coding genes from 33 plant taxa were used to construct ML and MP phylogenetic trees. Their topologies are similar and strongly support for the position of E. guineensis as the sister of closely related species Phoenix dactylifera in Arecaceae (palm families) of monocot subtrees. PMID:22487870

237

Effect of Crystallization Temperature of Palm Oil on Its Crystallization  

The crystallization of Palm Oil and its thermal features were examined in the present study by differential scanning calorimetry (DSC), X-ray diffractometry (XRD) and infrared spectroscopy (IR). The melting behavior of Palm Oil crystals was noted to differ significantly with temperature. One of the particular interest was the finding that small angle X-ray diffraction. Palm Oil crystallized when temperature was maintained at 10°C showed 65Å spacings. The IR absorption band due to the C-O-C group differed from any of those for samples obtained at other crystallization temperatures. It thus follows that the triple-chain length structure is present only in crystals obtained at 10°C and the double-chain length structure is to be found in those obtained at other temperatures. With heat application, the triple-chain length structure was noted to change to the double-chain length structure, this being accompanied by increase in enthalpy. Triacylglycerin in Palm Oil is comprised of POP (1,3-dipalmitoyl-2-oleoyl-glycerol) at about 30% and POO (1,2-dioleoyl-3-palmitoyl-glycerol) at about 20% and thus the present results would account for the varying triacylglycerin content in Palm Oil. Accordingly, when using Palm Oil-based products, attention should be directed to the effects of temperature on crystallization.   

238

Establishment of an oil and gas database for increased recovery and characterization of oil and gas carbonate reservoir heterogeneity. [Jurassic Smackover Formation  

This volume contains maps, well logging correlated to porosity and permeability, structural cross section, graph of production history, porosity vs. natural log permeability plots, detailed core log, paragenetic sequence, and reservoir characterization sheet for the following fields in southwest Alabama: East Huxford oil field; Fanny Church oil field; Gin Creek oil field; Gulf Crest oil field; Hanberry Church oil field; Hatter's Pond oil field; Healing Springs gas condensate field; Huxford oil field; Little Escambia Creek oil field; Little River oil field; Little Rock gas condensate field; Lovetts Creek oil field; Melvin oil field; Mill Creek oil field; Mineola oil field; Movico oil field; and North Choctaw Ridge oil field.

239

Designing Agricultural Development Projects for the Small Scale Farmers: Some Lessons from the World Bank Assistance Small Holder Oil Palm Development Scheme in Nigeria  

The study was carried out to investigate farmers reasons for intercropping their oil palm farms with food and other cash crops rather than the sole oil palm planting arrangement specified for participation in the World Bank Assistance Smallholder Oil Palm development project financed during the 1975-83 period. The study was conducted at the Ekuku-Agbor Tree Crop Unit Zone (to the East) and Mosogar Tree Crop Unit Zone (to the Southwest) of the old Bendel State of Nigeria. A total of 35 oil palm farmers were randomly selected from each zone for the study. The study tried to identify the size of oil palm cultivated, types of food and cash crops planted and the proportion consumed and sold and the sufficiency of labour for various farm activities. The study showed that the average oil palm farm size at Ekuku-Agbor zone was smaller (about 1.57 ha) and more fragmented while for Mosogar zone it was 2.28 ha. However a greater percentage (over 65%) of the farms at both locations were within 0.01-2.00 ha farm size range which could be said to be relatively small. The study revealed that among other factors the farmers desire to ensure adequate family food needs which equates to food security and some cash to meet regular family financial needs necessitated their intercropping of the oil palm farms. Others include the need to maximize the returns from the use of labour which they considered a major limiting factor in farm maintenance and to take advantage of the relative high unit price of cassava and its products that prevailed then by cultivating on any available land space including the palm plantations and thereby increasing their farm income.

240

Formulation, optimization and application of triglyceride microemulsion in enhanced oil recovery  

This paper presents the determination of an aqueous phase composition of a new triglyceride microemulsion in which the triglycerides constitute the whole oil-phase of the microemulsion. Palm oil was used as the oil phase of the microemulsion. Experimental results indicate that the optimum triglyceride microemulsion was achieved when equal mass of palm oil and the aqueous phase containing 3wt% sodium chloride, 1wt% alkyl polyglycosides, 3wt% glyceryl monooleate, and 93wt% de-ionized water were mixed. The formulated composition of the aqueous phase was able to form translucent Winsor Type I microemulsion with palm oil at ambient conditions. The measured interfacial tension between the optimum microemulsion and the model oil, which is n-octane in this study, was 0.0002mN/m. The maximum tertia...

 
 
 
 
241

Gas Assisted Mechanical Expression of Oilseeds  

It is the objective of this thesis to show the general applicability of the Gas Assisted Mechanical Expression (GAME) process for recovery of oil from oilseeds with high yields. In this process, the oilseeds are saturated with supercritical CO2 before mechanical pressing. The CO2 displaces part of the oil during the pressing and therefore increases the oil yield. To prove the general applicability of GAME, a number of oilseeds with a wide range of properties was chosen: sesame, linseed, jatropha, palm kernel and rapeseed. These seeds all produce high added value oils with a low market volume and their properties range from soft (sesame) to hard (jatropha, palm kernel) and from high (sesame) to low oil contents (palm kernel). A lab scale hydraulic press was used to determine the oil yields and expression rates that can be obtained for both conventional expression and GAME expression under a wide range of process conditions.

242

Enzymatic synthesis of phenyl fatty hydroxamic acids from canola and palm oils.  

Phenyl fatty hydroxamic acids (PFHAs) were synthesized from canola or palm oils and phenyl hydroxylamine (FHA) catalyzed by Lipozyme TL IM or RM IM. The reaction was carried out by shaking the reaction mixture at 120 rpm. The optimization was carried out by changing the reaction parameters, namely; temperature, organic solvent, amount and kind of enzyme, period of reaction and the mol ratio of reactants. The highest conversion was obtained when the reaction was carried out under the following conditions: temperature, 39°C; solvent, petroleum ether; kind and amount of lipase, 80 mg Lipozyme TL IM/mmol oil; reaction period, 72 h and FHA-oil ratio, 7.3 mmol FHA/ mmol oil. The highest conversion percentage of phenyl hydroxylaminolysis of the Ladan and Kristal brands commercial canola oils, palm stearin and palm kernel oils were 55.6, 52.2, 51.4 and 49.7 %, respectively. PMID:21606615

243

Heats of combustion of biofuels obtained by pyrolysis and by transesterification and of biofuel/diesel blends  

The obtained heats of combustion were 46.65+/-0.20; 38.09+/-0.31; 39.67+/-0.22; 41.88+/-0.31; 37.86+/-0.46; 39.89+/-0.09; 41.28+/-0.31MJ/kg for diesel, transesterified soybean oil, pyrolysed soybean oil and crude soybean oil, transesterified palm tree oil (Elaeis sp.), pyrolysed palm tree oil, crude palm tree oil, respectively. The results show the heats of combustion of biofuels are approximately 17% smaller than traditional diesel. The data also show the heats of combustion depend on the methodology used for the biofuel production. Addition of biofuels to traditional diesel fuel results in a linear decrease of the heat of combustion with the amount of the alternative fuel added to the diesel. However, for blends with 5% biofuels, which is the limit demanded by Brazilian legislation, no significant decrease of the heat of combustion of the commercial diesel was observed. (author)

244

Moringa Oleifera Oil: A Possible Source of Biodiesel  

Biodiesel is an alternative to petroleum-based conventional diesel fuel and is defined as the mono-alkyl esters of vegetable oils and animal fats. Biodiesel has been prepared from numerous vegetable oils, such as canola (rapeseed), cottonseed, palm, peanut, soybean and sunflower oils as well as a v...

245

Cuphea oil as a potential source of biodiesel with improved properties  

Biodiesel is usually produced from common vegetable oils such as soybean, rapeseed (canola), and palm as well as other feedstocks such as animal fats and used cooking oils. To enhance feedstock supply, other vegetable oils such as jatropha are of increasing interest. However, most of these feedsto...

246

COMPREHENSIVE ANALYSIS ON PERFORMANCE, COMBUSTION AND EMISSION CHARACTERISTICS FUELED BY VARIOUS BLENDS OF BIODIESEL IN A C.I. ENGINE  

Objectives of this paper: To evaluate performance, combustion and emission of various blends of biodiesel (B20). Corn Oil, Palm Oil, Cotton Seed Oil, Various parameters, Brake Thermal Efficiency, Brake Specific Fuel Consumption, Brake Mean Effective Pressure, Instantaneous Heat Release, Cumulative Heat Release, Exhaust Gas Temperature, CO, CO2, HC, NOx, O2 and Smoke Intensity, To Compare with Diesel

247

Associations between tissue fatty acid composition and physiological traits of performance and metabolism in the seabass (Dicentrarchus labrax)  

Seabass were fed for 4 months with diets where the lipid was provided as either canola oil (CO), palm oil ( PO) or fish oil (FO), to generate diversity in their tissue fatty acid (FA) composition and investigate how this influenced major traits of exercise performance, cardiac performance and respir...

248

Availability of triazine herbicides in aged soils amended with olive oil mill waste  

Olive oil extraction generates a lot of organic waste, which can potentially cause adverse environmental impacts. Application of olive oil mill waste, alperujo, to the land could be an effective way to dispose of the waste. However, addition of olive oil mill wastes can modify the binding capacity o...

249

A process for the aqueous enzymatic extraction of corn oil from dry-milled corn germ and enzymatic wet milled corn germ (E-Germ)  

Previously, we reported an aqueous enzymatic oil extraction process that achieved oil yields of 80-90% using corn germ from a commercial corn wet mill. Three commercial cellulases were reported to result in similar oil yields when wet milles corn germ was used as a feedstock in this process. When ...

250

Stability analysis of oil yield in oil palm (Elaeis guineensis) progenies in different environments.  

We evaluated 38 dura x pisifera (DP) oil palm progenies in four locations in Malaysia for genotype by environment interaction and genotypic stability studies. The DP progenies derived from crosses between pisifera palms of AVROS, Serdang S27B, Serdang 29/36, and Lever Cameroon were chosen to be the males' parent and Deli dura palms designated as females' parent. All the locations differed in terms of soil physical and chemical properties, and the soil types ranged from coastal clay to inland soils. The genotype by environment interaction and stability of the individual genotypes were analyzed for oil yield trait using several stability techniques. A genotype by environment interaction was detected for oil yield and it had a larger variance component than genotypic variance (?(2)(gl)/?(2)(g) = 139.7%). Genotype by environment interaction of oil yield was largely explained by a non-linear relationship between genotypic and environmental values. Overall assessment of individual genotypic stability showed that seven genotypes were highly stable and had consistent performance over the environments for the oil yield trait [total individual genotype stability scored more than 10 and mean oil yielded above the average of the environment (genotype means are more than 34.37 kg·palm(-1)·year(-1))]. These genotypes will be useful for oil palm breeding and tissue culture programs for developing high oil yielding planting materials with stable performance. PMID:23096688

251

Method for recovery of bitumen from bituminous emulsion froths  

This patent describes a method for separating bitumen from a bituminous oil-in-water emulsion froth which is resistant to coalescence by milling. In this method, the emulsion is milled with a ball mill, roller mill or equivalent milling device to impart a crushing action on said emulsion froth. Then an amount of previously coalesced bitumen is added to said emulsion froth in order to initiate and maintain coalescence in said mill. A bitumen-rich liquid fraction is allowed to rise to the surface of the milled emulsion, and said bitumen-rich fraction is separated.

252

Development of transformation vectors for the production of potentially high oleate transgenic oil palm  

Abstract in english The main target of Malaysian Palm Oil Board (MPOB) genetic engineering programme is to produce high oleate transgenic palms. The availability of effective transformation vector is one of the pre-requisites for genetic manipulation of oil palm through recombinant DNA technology. Here, we describe the construction of a series of transformation vectors that have a maize ubiquitin promoter (UbiPro)-driven bar gene for selection of transformants on herbicide (Basta or Bialapho (more) s), and mesocarp-specific promoter (MSP1) for expression of the transgenes [antisense palmitoyl-ACP-thioesterase (PAT) and sense ?-ketoacyl-ACP-synthase II (KASII) and sense ?9-stearoyl-ACP-desaturase (SAD)] potentially responsible for high oleate content in oil palm mesocarp. The transformation vectors constructed in this study are suitable for use in both particle bombardment (biolistic) and Agrobacterium-based transformation protocols.

253

A packed bed membrane reactor for production of biodiesel using activated carbon supported catalyst.  

In this study, a novel continuous reactor has been developed to produce high quality methyl esters (biodiesel) from palm oil. A microporous TiO2/Al2O3 membrane was packed with potassium hydroxide catalyst supported on palm shell activated carbon. The central composite design (CCD) of response surface methodology (RSM) was employed to investigate the effects of reaction temperature, catalyst amount and cross flow circulation velocity on the production of biodiesel in the packed bed membrane reactor. The highest conversion of palm oil to biodiesel in the reactor was obtained at 70 °C employing 157.04 g catalyst per unit volume of the reactor and 0.21 cm/s cross flow circulation velocity. The physical and chemical properties of the produced biodiesel were determined and compared with the standard specifications. High quality palm oil biodiesel was produced by combination of heterogeneous alkali transesterification and separation processes in the packed bed membrane reactor. PMID:20888219

254

Food, Fuel, and Climate Change  

Summary This study evaluates the sustainability of biodiesel for transport in Thailand in terms of the availability of fresh fruit bunches (FFB) and crude palm oil (CPO) supply to satisfy the future demands for food and fuel, and the contribution of palm biodiesel to mitigating climate change if biodiesel induces land-use change (LUC). Five land conversions including rubber, cassava, paddy field, set-aside land, and forest land to oil palm are considered along with their displacement effects to other land types to evaluate the greenhouse gas (GHG) emissions associated with the direct and indirect land-use impacts. The net feedstock balance reveals that the policy to expand 0.4 million hectare (Mha) for new oil palm plantations accompanied with an increase of FFB yield to 22 megagrams per h...

255

Comparison of treatment methods for palm oil mill effluent (POME) wastes  

A study of the operational variables involved in the treatment of palm oil mill effluent (POME) was carried out. These included the acidic or alkaline nature of the POME discharged from the oil mills, the efficiency of the decay (or digestion) of the chemical oxygen demand (COD) contents of the POME, the economic benefits that could arise from the digested sludge and biogas and finally the net economic recovery abilities of the various treatment methods available. The chemical oxygen demand (COD) contents of the POME must be reduced to an acceptable level of 2000-3000 mg/solids dm/sup 3/ of sludge before the latter can be used a fertiliser material. In 10 days of operation periods various anaerobic digestion treatment methods gave COD reduction efficiencies of 76-96%, the batch pond anaerobic digestion mode gave an efficiency of 76.5%, the continuous pond modes 92.5-95.5% and the tank digester 93.8%. In all anaerobic operations the optimal pH value of the POME media were in the range 7.1-7.6 and a ratio of the volatile acids to the total alkalinity of the media (VA/TA) of 0.3 or less was found to enhance the performance of these digesters. Economic analyses carried out on all modes of treatment gave the following economic recovery abilities: the decanter/drier system gave a break-even situation of 3 years, the tank digester system, 2 years, and the single stage anaerobic pond system, 6 years. The batch pond system appeared not to give a break-even situation. Of the treatment methods examined the decanter/deier and tank digester systems were concluded to be optimal.

256

Documentation of the 7th biomass conference Rhineland-Palatinate; Dokumentation zur 7. Biomasse-Tagung Rheinland-Pfalz  

Within the scope of the 7th biomass conference Rheinland-Pfalz at 8th and 9th November, 2007, in Birkenfeld (Federal Republic of Germany) the following lectures were held: (1) Biomass - the domestic resource with chances for climate and places of work (Margit Conrad); (2) New possibilities of a sustainable optimization of the regional utilization of biomass (Peter Heck); (3) Combustion of straw - technical, economical, and legal aspects (Elmar Bruegging); (4) Utilization of straw for biofuels of the second generation (Nicolaus Dahmen); (5) Straw in chip boards (Oskar Meyer); (6) Sustainable primary products of energy plants for production of biogas (Katja Goedeke); (7) Productoion of foods or bioenergy - what is better? (Karl Riedesser); (8) Scarce amounts of wood in Rheinland-Pfalz - Consequences for recycling and energetic utilization (Norbert Heidingsfeld); (9) Chances for the small private forest: Mobilization of wood for energetical utilization (Winand Schmitz); (10) Nature conservation by utilization - a national challenge (Christof Thoss); (11) Nature conservation by agriculture? (Frank Wagener); (12) Key factures in the amendment of sewage sludge ordinance - does the agricultural utilization of sewage sludge have a future? (Claus-Gerhard Bergs); (13) Biological treatment of wastes by fermentation as well as utilization of these products (Michael Kraemer); (14) ''Murecks energy cycle'' with the focus of utilisation of waste oil (Karl Totter); (15) Agriculture 2020: Fundament of a sustainable energy supply (Birgit Birnstingl-Gottinger); (16) Supply of great vegetable oil cogeneration plants - only possible with palm oil? (Andreas Krebs); (17) The situation of decentral oil mills in the Federal Republic of Germany: Are imports of petroleum from third countries dangerous? What are the impacts of the realization of finance revenues on decentral oil mills? (Guenter Heil); (18) Certification of plant oil (Anne Miehe); (19) Wood pellets - a young market from the view of a trader (Jan-Fr. Frenzel); (20) Wooden biomass from landscape conservation and forestry for energetic utilization (Andreas Zeller / Hans Baeuscher); (21) Wood logistics for forests resulting from stick efflorescence (Wolfang Kratz); (22) Conception of logistic structures for Biomass (Ralf Gebhard); (23) Utilization of biogas in the field of tension between increasing prices of substrate and continuous remuneration in the Renewable Energy Resources Act (Manuel Maciejczyk); (24) Technology of biological drying in order to produce biomass from bio wastes (Joachim Dach); (25) Realization of long-term assured utilization of sewage sludge - a report in practice (Rainer Gruener); (26) Combustion of cereals - an experience report from Rheinland-Pfalz (Bernhard Wern).

257

World oilseed situation and U. S. export opportunities, March 1984. Foreign agriculture circular  

The world oilseed supply situation tightened in this month with estimated world oilseed, meal and oil production all down from the last month. Reduced peanut and sunflower seed output in drought-damaged areas in Africa more than offset an increase in Argentine soybean output. The protein meal sector remained quiet, with an adjustment in peanut meal production and a reduction in Soviet soybean meal imports. The situation for vegetable and marine oils also remained quiet during the month, with offsetting reductions of Singapore's palm oil imports and exports indicating that country's decline as a transshipper of palm oil.

258

Phenology of the oil palm interspecific hybrid Elaeis oleifera × Elaeis guineensis  

Abstract in english Oil palm is one of the most important oil crops in the world. Because of its high productivity and perennial nature, it has been expanding quickly. Commercial plantations consist mostly of the African palm E. guineensis Jacq. However, producers in Latin America are increasingly planting the O × G interspecific hybrid, a cross between African palm (E. guineensis) and the American palm (E. oleifera (Kunth) Cortés). This interspecific hybrid has emerged as a promising solu (more) tion to diseases such as the bud rot of oil palm because of the apparent partial resistance of this genotype to the disease. This work studied and described the phenology of the O × G interspecific hybrid. The phenology stages were coded using the BBCH scale. The scale for the phenophases was defined using a three-digit code. Due to the nature of the palm, no descriptions were used for stage two (formation of side shoots/tillering) and stage four (development of harvestable vegetative plant parts or vegetative reproductive organs) because these stages do not apply to oil palm. The scale was constructed using germinating seeds, pre-nursery and nursery plants and five year-old palms. For the description of the stem elongation, different age palms of the same O × G hybrid were used. Observations were performed during an 18-month period. Additionally, the interval for the change from one phenology stage to another was determined both in days and degree-days (DD). The interspecific O × G hybrid required 6408 DD from when the spear leaf unfolds until the bunch was ripened and harvested, and 4427.6 DD from leaf unfolding to anthesis.

259

Implementation and testing of the use of vegetable oils as fuel diesel generators in the Amazon isolated communities; Implantacao e testes de utilizacao de oleo vegetal como combustivel para diesel geradores em comunidades isoladas da Amazonia  

The project PROVEGAM 'Implantation and test of a unit demonstration of energetic utilization of vegetable oil', tested in operational conditions of field, the functioning of a conventional diesel engine, adapted to operate with palm oil 'in natura' in the community of Vila Soledade, city of Moju, Para State. The Vila Soledade is an isolated community that has, approximately, 700 inhabitants and it's located at one hundred kilometers from the city hall by car and more 30 minutes by boat. The electric energy of this community was previously generated, by a conventional diesel engine, obsolete and very expensive to the community, because the fuel price and the transport of the diesel oil from the city to the community. The PROVEGAM project, installed an electric generation group, MWM TD229, manufactured in Brazil, adapted with a conversion kit to operate with 'in natura' palm oil, working 6 hours per day. Because of the viscosity of the palm oil and its combustion point, it was necessary to heat the vegetable oil before its injection into the engine. The operation begins and finishes with diesel oil, in order to heat the palm oil and to clean possible residues deposited in the interior of the engine. The use of the palm oil justifies itself for being produced in the region, which means that it doesn't have to be imported. Currently, the generating group is working in the community during 5 hours per day with palm oil, and 1 hour per day with diesel oil and it already has more than 1600 hours of testing. The results of this project, so far, have confirmed the conceived premises, and this electric model of generating energy is already recommended to be implemented in other communities in the Amazon region. (author)

260

Thermal stability evaluation of palm oil as energy transport media  

The thermal stability of palm oil as energy transport media in a hydraulic system was studied. The oils were aged by circulating the oil in an open loop hydraulic system at an isothermal condition of 55 deg. C for 600 h. The thermal behavior and kinetic parameters of fresh and degraded palm oil, with and without oxidation inhibitor, were studied using the dynamic heating rate mode of a thermogravimetric analyser (TGA). Viscometric properties, total acid number and iodine value analyses were used to complement the TGA data. The thermodynamic parameter of activation energy of the samples was determined by direct Arrhenius plot and integral methods. The results may have important applications in the development of palm oil based hydraulic fluid. The results were compared with commercial vegetable based hydraulic fluid. The use of F10 and L135 additives was found to suppress significantly the increase of acid level and viscosity of the fluid.

 
 
 
 
261

Effects of dietary fish oil replacement by various vegetable oils on growth performance, body composition and fatty acid profile of juvenile Malaysian mahseer, Tor tambroides  

Abstract The current study was carried out to investigate the effects of replacing dietary fish oil with different vegetable oil sources and ratios on the growth performance and tissue fatty acid profiles of juvenile Tor tambroides. Three different vegetable oils (sunflower oil, linseed oil and palm oil) were used in two different substitution ratios (50% and 100%). A diet without replacement (100% fish oil) was used as a control. Triplicate groups of T.tambroides juveniles (5.0--0.4-g) were fed the test diets for 9-weeks. The highest weight gain was observed in fish fed palm oil diets that, of course, were reared in aquaria. There was a significant effect (P--0.05) of the percentage of fish oil replacement on the liver weight after controlling for the effect of fish weight (P--0.05). The ...

262

Inoculation of Bacillus sphaericus UPMB-10 to Young Oil Palm and Measurement of Its Uptake of Fixed Nitrogen Using the (15)N Isotope Dilution Technique.  

There are increasing applications of diazotrophic rhizobacteria in the sustainable agriculture system. A field experiment on young immature oil palm was conducted to quantify the uptake of N derived from N(2) fixation by the diazotroph Bacillus sphaericus strain UPMB-10, using the (15)N isotope dilution method. Eight months after (15)N application, young immature oil palms that received 67% of standard N fertilizer application together with B. sphaericus inoculation had significantly lower (15)N enrichment than uninoculated palms that received similar N fertilizers. The dilution of labeled N served as a marker for the occurrence of biological N(2) fixation. The proportion of N uptake that was derived from the atmosphere was estimated as 63% on the whole plant basis. The inoculation process increased the N and dry matter yields of the palm leaflets and rachis significantly. Field planting of young, immature oil palm in soil inoculated with B. sphaericus UPMB-10 might mitigate inorganic fertilizer-N application through supplementation by biological nitrogen fixation. This could be a new and important source of nitrogen biofertilizer in the early phase of oil palm cultivation in the field. PMID:22446306

263

Life cycle GHG emissions from Malaysian oil palm bioenergy development: The impact on transportation sector's energy security  

Malaysia's transportation sector accounts for 41% of the country's total energy use. The country is expected to become a net oil importer by the year 2011. To encourage renewable energy development and relieve the country's emerging oil dependence, in 2006 the government mandated blending 5% palm-oil biodiesel in petroleum diesel. Malaysia produced 16 million tonnes of palm oil in 2007, mainly for food use. This paper addresses maximizing bioenergy use from oil-palm to support Malaysia's energy initiative while minimizing greenhouse-gas emissions from land-use change. When converting primary and secondary forests to oil-palm plantations between 270-530 and 120-190 g CO{sub 2}-equivalent per MJ of biodiesel produced, respectively, is released. However, converting degraded lands results in the capture of between 23 and 85 g CO{sub 2}-equivalent per MJ of biodiesel produced. Using various combinations of land types, Malaysia could meet the 5% biodiesel target with a net GHG savings of about 1.03 million tonnes (4.9% of the transportation sector's diesel emissions) when accounting for the emissions savings from the diesel fuel displaced. These findings are used to recommend policies for mitigating GHG emissions impacts from the growth of palm oil use in the transportation sector. - Research highlights: {yields} We modeled greenhouse gas emissions in the production of palm-biodiesel. {yields} Five land types were included to model emissions associated with land-use change. {yields} Land-use change has the biggest impact on the emissions in making palm-biodiesel. {yields} Emissions from fertilizer use and effluent treatment are still significant. {yields} At 5% biodiesel grown on suitable lands Malaysia would obtain an emissions savings.

264

Oleico+ sustainability in the olive mill waste management  

Olive oil production generates olive mill wastes estimated at 2.5 million tonnes. More than 80% of olive mill wastes consist in water. Olive mill wastewater (OMW) has environmental impacts due to its high organic load and contents in phenols, lipids and organic acids. The project Oleico +, supported...

265

Palm oil as a sustainable energy alternative in degraded areas of the Amazon region; O dende como alternativa energetica sustentavel em areas degradadas na Amazonia  

Bio fuels are important tools in reducing emissions of greenhouse gases (GHG); however, to minimize the conflict with food crops, energy crops with high efficiency and capacity to absorb Co2, such as the oil palm, should be prioritized. The European Union intends to replace 10% of liquid fossil fuel demand with bio fuels by 2020. According to studies conducted by the European Commission, this will entail the annual import of more than 3 million tonnes of palm oil, the most produced and least expensive vegetable oil in the world. 87% of global production comes from Indonesia and Malaysia, where the relentless expansion of oil palm cultivation has caused extensive forest devastation, threatening biodiversity and increasing GHG emissions. The Netherlands, a large importer of oil palm products, developed a methodology (Cramer) for the certification of sustainable bio energy production, assessing economic, social, environmental aspects, as well as GHG emissions, throughout the supply chain. It sets a mandatory minimum 30% reduction of GHG emissions in the bio-energy chain for use in transport and 70% for use in heat and power generation, as compared to the chain of the fossil counterpart. This dissertation shows that oil and bio diesel (ethyl ester) from palm grown in the Amazon meets this GHG mitigation criterion when degraded areas are utilized for cultivation, but not when forests are razed for that purpose. (author)

266

Catalytic conversion of palm oil to fuels and chemicals  

Conversion of palm oil to hydrocarbons using a selective zeolite catalyst was studied. The palm oil was passed over HZMS-5 catalyst in a fixed-bed micro-reactor, operated at atmospheric pressure in a temperature range of 360-420 degrees C, and weight hourly space velocity (WHSV) of 2-4 h{sub 1}. The main objective was to study the effect of reaction variables such as temperature and oil space velocity on the conversion of palm oil to fuels and chemicals, and to find the optimum value of palm oil conversion and yield of organic liquid products, especially gasoline range hydrocarbons. Results showed maximum conversion of palm oil to a mixture of liquid and gaseous hydrocarbons of 67 weight-per cent. The amount of gas in the converted material increased with an increase in the reaction temperature. The maximum gasoline-range hydrocarbons yield of 40 weight-per cent of the total product was obtained at 400 degrees C and 2h{sub 1} space velocity. Formation of kerosene and diesel range hydrocarbons was the minimum where formation of gasoline was maximum. Calcined HZSM-5 showed the highest rate of cracking or reaction. It also enhanced the formation of aromatic and alcohol compounds compared to uncalcined HZSM-5. 13 refs., 6 tabs., 5 figs.

267

FY 1998 industrial technology R and D project. Report on the results of the development of utilization technology of biological resource such bioconsortia system (Development of production technology of biological use petroleum substituting fuels); 1998 nendo sangyo gijutsu kenkyu kaihatsu jigyo. Fukugo seibutsukeinado seibutsu shigen riyo gijutsu kaihatsu (seibutsu riyo sekiyu daitai nenryo seizo gijutsu no kaihatsu)  

Technology development was conducted for production of useful substances using the bioconsortia system. In FY 1998, the development of element technology was studied. As to the utilization technology of gut symbiotic microorganisms such as termite and longhorn beetle, clone types of gut microorganism complex system were analyzed to find out the diversification. In the decay of wood, co-culture of two species of mold fungus was increased in efficiency than single culture. More than 90% was classified/identified of the mold fungi accumulated (in wood piece)/separated for the utilization of plant symbiotic microorganisms. For the production of petroleum substituting useful resource, conditions were established of callus induction from immature embryos of tropical oil crops, especially oil palm, and of regeneration of a lot of small plants from the callus. To establish the Agrobacterium-mediated transformation system of oil palm, the binary vector harboring the reporter gene and selectable marker gene was constructed. Using the vector, oil palm tissues are inoculated and infected with agrobacteria. To heighten the function of palm oil, 10 particular clones were selected from the complementary DNA library obtained from oil palm fruit tissues. The genetic study of germs was also made. (NEDO)

268

Babacu palm tree (Orbignya phalerata Mart. ). Ecological and ethnobotanic aspects of its exploitation in the Brazilian state of Piaui. Die Babacu-Palme (Orbignya phalerata Mart. ). Oekologische und ethnobotanische Aspekte ihrer Nutzung im brasilianischen Bundesstaat Piaui  

The Babacu palm tree, spread over an area of some 20,000 km/sup 2/ in the state of Piaui is an integral part of the traditional exploitation of the palm woods by the inhabitants. Next to the use of all parts of the palm tree in the rural household the sale of the seeds and lately also the shells has gained an increasing importance. The seeds are processed in factories for the production of oil. The seeds are taken from 5 different kinds of palm trees and are of like shape and chemical composition. Three of them belong to the species Orbignya, one to Markleya and the last to Maximiliana. Orbignya phalerata Martius is the most important and widespread kind. The palms play an important role in the protection of the ecological stability of the region by preservation of soil humidity, erosion protection and return of nutrients. This small agricultural system is a combined forestry-agricultural system since the palm trees and the annual crops are planted together on one area and it is proven that these cultures influence each other. The efficiency of the palm tree exploitation could be increased by commercial activities and thus preserve the babacu palm tree economy. Even if the domestic need for charcoal were completely covered, an amount between 30 kg and 112 kg of shells would be unused every week. Since several years the Piaui beer brewery purchases around 700 t of Babacu shells per month to use them as fuel in their furnaces.

269

Synthesis and characterization of fatty hydroxamic acids from triacylglycerides.  

In this study, fatty haydroxamic acids (FHAs), which have biological activities as antibiotics and antifungal, have been synthesized via refluxing of triacylglycrides, palm olein, palm stearin or corn oil with hydroxylamine hydrochloride. The products were characterized using the complex formation test of hydroxamic acid group with zinc(I), copper(II) and iron(III), various technique methods including nuclear magnetic resonance ((1)H NMR) spectroscopy, Fourier transform infrared (FTIR) spectroscopy and elemental analysis. Parameters that may affect the conversion of oils to FHAs including the effect of reaction time, effect of organic solvent and effect of hydro/oil molar issue were also investigated in this study. Results of characterization indicate that FHAs were successfully produced from triacylglycrides. The conversion percentages of palm stearin, palm olein and corn oil into their fatty hydroxamic acids are 82, 81 and 78, respectively. Results also showed that hexane is the best organic solvent to produce the FHAs from the three oils used in this study. The optimum reaction time to achieve the maximum conversion percentage of the oils to FHAs was found to be 10 hours for all the three oils, while the optimum molar ration of hydro/to oil was found to be 7:1 for all the different three oils. PMID:20032595

270

Comparison of nutrient composition in kernel of tenera and clonal materials of oil palm (Elaeis guineensis Jacq.)  

Nutritive information about oil palm kernel is scarce, especially on the composition of sugars and water-soluble vitamins. This study aims to evaluate both tenera and clonal materials for their proximate composition, fatty acid profile, amino acid composition, sugar, mineral and water-soluble vitamin contents. The tenera material had a higher moisture, fat and fibre content as compared to the clonal material, whereas protein, carbohydrate and ash content were higher in the clonal material. The major fatty acid constituents in palm kernel oil were lauric acid, myristic acid and oleic acid. The palm kernel proteins were deficient in lysine and tryptophan but rich in glutamic acid, arginine and aspartic acid. Sucrose was the most abundant sugar in palm kernel. The mineral analysis of the samp...

271

Phytoplasmas associated with disease of coconut in Malaysia: phylogenetic groups and host plant species  

Coconut palm (Cocos nucifera), oil palm (Elaeis guineensis), Bermudagrass (Cynodon dactylon) and Madagascar periwinkle (Catharanthus roseus) with symptoms indicative of phytoplasma disease were collected from different locations in Malaysia. PCR assays employing phytoplasma universal rRNA gene primers P1/P7 alone or P1/P7 followed by R16F2n/R16R2 detected phytoplasmas in eight out of 20 Malayan Red Dwarf (MRD), nine out of 12 Malayan Yellow Dwarf (MYD) and 12 out of 12 Malayan Tall (MT) coconut palms displaying coconut yellow decline symptoms. Positive detections were also obtained from six out of six oil palm seedlings showing symptoms of yellowing and necrosis, from 10 out of 10 Bermudagrass samples with white leaf symptoms, and from eight out of eight periwinkle plants showing phyllody,...

272

Process design methodology for fractionation of fatty acids from palm fatty acid distillates in countercurrent packed columns with supercritical CO2  

In this work, the fractionation of fatty acids from palm oil deodorizer distillates, a by-product of the physical refining process of palm oil, has been investigated in a laboratory scale countercurrent packed column with supercritical CO2 as solvent. Experiments were carried out at 26 and 29MPa and 373K. Phase equilibria for the mixture palm fatty acids distillates+CO2 have been investigated experimentally by the static method at 333, 353, and 373K and pressures between 20 and 29MPa. The chemical identification of free fatty acids has been performed by gas chromatography. Hydrodynamic experiments were carried out for the systems palm fatty acids distillates+CO2 at 333, 353, and 373K and pressures between 20 and 29MPa in order to compute the column hydraulic capacity. A separation analysis...

273

21 CFR 582.20 - Essential oils, oleoresins (solvent-free), and natural extractives (including distillates).  

...distillates). Essential oils, oleoresins (solvent-free...nobilis L. Bay (myrcia oil) Pimenta racemosa (Mill... L., or other grains. Mandarin Citrus reticulata Blanco...Burm. f. Petitgrain mandarin or tangerine Citrus...

274

21 CFR 582.20 - Essential oils, oleoresins (solvent-free), and natural extractives (including distillates).  

...including distillates). Essential oils, oleoresins (solvent-free), and...leaves Laurus nobilis L. Bay (myrcia oil) Pimenta racemosa (Mill.) J. W...Neroli, bigarade Citrus aurantium L. Nutmeg Myristica fragrans Houtt....

275

A manufacturer's perspective on selected palm-based products.  

An overview from the perspective of one manufacturer is provided on products that utilise either palm oil or palm kernel oil. The manufacturer is Macphie of Glenbervie while the products are of a wide-ranging nature for use in bakery, food service and food-manufacturing. Much of the discussion concerns cream alternatives on the grounds that this product-category places great demand on the type of fat needed and, to Macphie of Glenbervie, is responsible for most of the oil from oil palm used. However, other products are also touched on. The overview considers key product attributes the function that fat has within these products, together with research requirements and future opportunity. PMID:16326645

276

Expression of Aeromonas caviae polyhydroxyalkanoate synthase gene in Burkholderia sp. USM (JCM15050) enables the biosynthesis of SCL-MCL PHA from palm oil products  

Abstract Aims:- Burkholderia sp. USM (JCM15050) isolated from oil-polluted wastewater is capable of utilizing palm oil products and glycerol to synthesize poly(3-hydroxybutyrate) [P(3HB)]. To confer the ability to produce polymer containing 3-hydroxyhexanoate (3HHx), plasmid (pBBREE32d13) harbouring the polyhydroxyalkanoate (PHA) synthase gene of Aeromonas caviae (phaCAc) was transformed into this strain. Methods and Results:- The resulting transformant incorporated approximately 1--03-mol% of 3HHx in the polymer when crude palm kernel oil (CPKO) or palm kernel acid oil was used as the sole carbon source. In addition, when the transformed strain was cultivated in the mixtures of CPKO and sodium valerate, PHA containing 69 -mol% 3HB, 30-mol% 3-hydroxyvalerate and 1 -mol% 3HHx monomers was p...

277

Old oil palm trunk: A promising source of sugars for bioethanol production  

Oil palm trees are replanted at an interval of approximately 25 years because of decreased oil productivity of old trees. Consequently the felled trunks are the enormous amount of biomass resources in the palm oil producing countries such as Malaysia and Indonesia. In this report, we found that the felled oil palm trunk contains large quantity of sap, which accounts for approximately 70% of the whole trunk weight, and that sugars existing in the sap increased remarkably during storage after logging. Total sugar in the sap increased from 83 mg ml-1 to 153 mg ml-1, the concentration comparable to that of sugar cane juice, after 30 days of storage, followed by the gradual decrease. The sugars contained in the sap were glucose, sucrose, fructose and galactose, all of which are fermentable by o...

278

The oil palm industry bows to NGO campaigns  

Abstract Palm oil has become the key supplier to the global edible oils market. Continued oil palm development should be a good thing as it is the most effective supplier in terms of low land usage, and it brings much needed development to poor tropical developing regions. It provides livelihoods for an estimated 4.5 million people. As a monocrop that has supplanted forest and peat lands in areas with unmatched biodiversity and inhabited by poor indigenous tribes, it has been heavily criticized for its negative environmental and social impacts. Escalating NGO campaigns, particularly from Europe, over the last seven years have seriously reined in the speed and prospects for oil palm expansion in Indonesia and Malaysia. Large corporate growers have acceded to NGO pressures, as these have res...

279

DETERMINATION OF FREE FATTY ACIDS IN CRUDE PALM OIL, BLEACHED PALM OIL AND BLEACHED DEACIDIFIED PALM OIL BY FOURIER TRANSFORM INFRARED SPECTROSCOPY  

ABSTRACT A rapid method for quantitative determination of free fatty acids from crude palm oil to bleached palm oil (BPO) and then distilled BPO and refluxed BPO by Fourier transform infrared (FTIR) transmission spectroscopy is described. A partial least square (PLS) model was calibrated to predict the FFA content of palm oil samples based on the spectral range of 1,729.89-1,694.48/cm. Multivariate calibration step was carried out by comparing the FFA values predicted by PLS model to the values obtained from the official American Oil Chemists' Society method. The resulting PLS calibrations were linear and the root mean standard error of cross-validation was 0.063 with a correlation coefficient (R2) of 0.9898. The results indicated that FTIR spectroscopy is an efficient, rapid and accurate ...

280

Structured lipids obtained by chemical interesterification of olive oil and palm stearin  

Interesterification of palm stearin (PS) with liquid vegetable oils could yield a good solid fat stock that may impart desirable physical properties, because PS is a useful source of vegetable hard fat, providing bprime stable solid fats. Dietary ingestion of olive oil (OO) has been reported to have physiological benefits such as lowering serum cholesterol levels. Fat blends, formulated by binary blends of palm stearin and olive oil in different ratios, were subjected to chemical interesterification with sodium methoxide. The original and interesterified blends were examined for fatty acid and triacylglycerol composition, melting point, solid fat content (SFC) and consistency. Interesterification caused rearrangement of triacylglycerol species, reduction of trisaturated and triunsaturated ...

 
 
 
 
281

Comparison of UASB and EGSB reactors performance, for treatment of raw and deoiled palm oil mill effluent (POME)  

Anaerobic digestion of palm oil mill effluent (POME) and deoiled POME was investigated both in batch assays and continuous reactor experiments using up-flow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors. The methane potential determined from batch assays of POME and deoiled POME was 503 and 610mL-CH4/gVS-added, respectively. For the treatment of POME in continuously fed reactors, both in UASB and EGSB reactors more than 90% COD removal could be obtained, at HRT of 5 days, corresponding to OLR of 5.8gVS/(L-reactor.d). Similar methane yields of 436–438mL-CH4/gVS-added were obtained for UASB and EGSB respectively. However, for treatment of deoiled POME, both UASB and EGSB reactors could operate at lower OLR of 2.6gVS/(L-reactor.d), with the methane yield of 600 and 555mL-CH4/gVS-added for UASB and EGSB, respectively. The higher methane yield achieved from the deoiled POME was attributed to lower portion of biofibers which are more recalcitrant compared the rest of organic matter in POME. The UASB reactor was found to be more stable than EGSB reactor under the same OLR, as could be seen from lower VFA concentration, especially propionic acid, compared to the EGSB reactor.

282

Hydrogen production from palm oil mill effluent by fermentation  

Hydrogen production by fermentation was examined by using palm oil mill effluent. Clostridium butyricum produced more than 2.2 NL of hydrogen from 1 L of raw POME at pH 5.0, and Enterobacter aerogenes produced ca. 1.9 NL at pH 6.0. While from the culture liquid added 1% of peptone on the raw POME, C. butyricum produced more than 3.3 NL and also E. aerogenes 3.4 NL at pH 6.0 and 5.0, respectively. In this manner, the addition of nitrogen source to the POME liquid exerted an influence on the volume of hydrogen production. Since Aspergillus niger has ability to produce cellulase, co-cultivation of C.butyricum with A. niger was tried to utilize celluloses in the POME. Against our expectations, however, the results were lower productivities than pure cultivation's. We analyzed the components of POME by liquid chromatography and capillary electrophoresis before and after cultivation. The main substrate for hydrogen production was found to be glycerol. (authors)

283

Optimization of phototrophic hydrogen production by Rhodopseudomonas palustris PBUM001 via statistical experimental design  

Phototrophic hydrogen production by indigenous purple non-sulfur bacteria, Rhodopseudomonas palustris PBUM001 from palm oil mill effluent (POME) was optimized using response surface methodology (RSM). The process parameters studied include inoculum sizes (% v/v), POME concentration (% v/v), light intensity (klux), agitation (rpm) and pH. The experimental data on cumulative hydrogen production and COD reduction were fitted into a quadratic polynomial model using response surface regression analysis. The path to optimal process conditions was determined by analyzing response surface three-dimensional surface plot and contour plot. Statistical analysis on experimental data collected following Box-Behnken design showed that 100% (v/v) POME concentration, 10% (v/v) inoculum size, light intensity at 4.0 klux, agitation rate at 250 rpm and pH of 6 were the best conditions. The maximum predicted cumulative hydrogen production and COD reduction obtained under these conditions was 1.05 ml H{sub 2}/ml POME and 31.71% respectively. Subsequent verification experiments at optimal process values gave the maximum yield of cumulative hydrogen at 0.66 {+-} 0.07 ml H{sub 2}/ml POME and COD reduction at 30.54 {+-} 9.85%. (author)

284

Effect of temperature and initial pH on biohydrogen production from palm oil mill effluent: long-term evaluation and microbial community analysis  

Abstract in english Anaerobic sludge from palm oil mill effluent (POME) treatment plant was used as a source of inocula for the conversion of POME into hydrogen. Optimization of temperature and initial pH for biohydrogen production from POME was investigated by response surface methodology. Temperature of 60ºC and initial pHof 5.5 was optimized for anaerobic microflora which gave a maximum hydrogen production of 4820 ml H2/l-POME corresponding to hydrogen yield of 243 ml H2/g-sugar. Total s (more) ugar consumption and chemical oxygen demand (COD) removal efficiency were 98.7% and 46%, respectively. Long-term hydrogen production in continuous reactor at HRT of 2 days, 1 day and 12 hrs were 4850 ± 90, 4660 ± 99 and 2590 ± 120 ml H2/l-POME, respectively. Phylogenetic analysis of the mixed culture revealed that members involved hydrogen producers in both batch and continuous reactors were phylogenetically related to the Thermoanaerobacterium thermosaccharolyticum. Batch reactor showed more diversity of microorganisms than continuous reactor. Microbial community structure of batch reactor was comprised of T. thermosaccharolyticum, T. bryantii, Thermoanaerobacterium sp., Clostridium thermopalmarium and Clostridium NS5-4, while continuous reactor was comprised of T. thermosaccharolyticum, T. bryantii and Thermoanaerobacterium sp. POME is good substrate for biohydrogen production under thermophilic condition with Thermoanaerobacterium species play an important role in hydrogen fermentation.

285

Evaluation of methods for preparing hydrogen-producing seed inocula under thermophilic condition by process performance and microbial community analysis.  

Five methods for preparation of hydrogen-producing seeds (base, acid, 2-bromoethanesulfonic acid (BESA), load-shock and heat shock treatments) as well as an untreated anaerobic digested sludge were compared for their hydrogen production performance and responsible microbial community structures under thermophilic condition (60 degrees C). The results showed that the load-shock treatment method was the best for enriching thermophilic hydrogen-producing seeds from mixed anaerobic cultures as it completely repressed methanogenic activity and gave the a maximum hydrogen production yield of 1.96 mol H(2) mol(-1) hexose with an hydrogen production rate of 11.2 mmol H(2) l(-1)h(-1). Load-shock and heat-shock treatments resulted in a dominance of Thermoanaerobacterium thermosaccharolyticum with acetic acid and butyric acid type of fermentation while base- and acid-treated seeds were dominated by Clostridium sp. and BESA-treated seeds were dominated by Bacillus sp. The comparative experimental results from hydrogen production performance and microbial community analysis showed that the load-shock treatment method was better than the other four methods for enriching thermophilic hydrogen-producing seeds from anaerobic digested sludge. Load-shock treated sludge was implemented in palm oil mill effluent (POME) fermentation and was found to give maximum hydrogen production rates of 13.34 mmol H(2) l(-1)h(-1) and resulted in a dominance of Thermoanaerobacterium spp. Load-shock treatment is an easy and practical method for enriching thermophilic hydrogen-producing bacteria from anaerobic digested sludge. PMID:18768309

286

16S rRNA-targeted probes for specific detection of Thermoanaerobacterium spp., Thermoanaerobacterium thermosaccharolyticum, and Caldicellulosiruptor spp. by fluorescent in situ hybridization in biohydrogen producing systems  

16S rRNA gene targeted oligonucleotide probes for specific detection of genera Thermoanaerobacterium (Tbm1282), Caldicellulosiruptor (Ccs432), and specie Thermoanaerobacterium thermosaccharolyticum (Tbmthsacc184) were designed and used to monitor the spatial distribution of hydrogen producing bacteria in sludge and granules from anaerobic reactors. The designed probes were checked for their specificity and then validated using fluorescence in situ hybridization with target microorganisms and non-target microorganisms. Thermoanaerobacterium spp., T. thermosaccharolyticum and Caldicellulosiruptor spp. were detected with the probes designed with coverage of 75%, 100% and 93%, respectively. Thermophilic (60 °C) hydrogen producing reactors, one fed with sucrose and another, fed with palm oil mill effluent comprised of following major groups of hydrogen producers: Thermoanaerobacterium spp. (49% and 36%), T. thermosaccharolyticum (16% and 10%), phylum Firmicutes (low G+C) gram positive bacteria (15% and 27%). Extreme-thermophilic (70 °C) hydrogen producing reactors, one fed with xylose and another, fed with lignocellulosic hydrolysate comprised of following major groups of hydrogen producers: Caldicellulosiruptor spp. (40.5% and 20.5%), phylum Firmicutes (low G+C) gram positive bacteria (17% and 20%), Archaea (7% and 8.5%), and Thermoanaerobacterium spp. (0% and 5%). Results obtained, showed good applicability of the probes Tbm1282, Tbmthsacc184 and Ccs432 for specific detection and quantification of thermophilic and extreme-thermophilic hydrogen producers in complex environments.

287

UASB performance and microbial adaptation during a transition from mesophilic to thermophilic treatment of palm oil mill effluent.  

The treatment of palm oil mill effluent (POME) by an upflow anaerobic sludge bed (UASB) at organic loading rates (OLR) between 2.2 and 9.5 g COD l(-1) day(-1) was achieved by acclimatizing the mesophilic (37 °C) microbial seed to the thermophilic temperature (57 °C) by a series of stepwise temperature shifts. The UASB produced up to 13.2 l biogas d(-1) with methane content on an average of 76%. The COD removal efficiency ranged between 76 and 86%. Microbial diversity of granules from the UASB reactor was also investigated. The PCR-based DGGE analysis showed that the bacterial population profiles significantly changed with the temperature transition from mesophilic to thermophilic conditions. In addition, the results suggested that even though the thermophilic temperature of 57 °C was suitable for a number of hydrolytic, acidogenic and acetogenic bacteria, it may not be suitable for some Methanosaeta species acclimatized from 37 °C. Specifically, the bands associated with Methanosaeta thermophila PT and Methanosaeta harundinacea can be detected during the four consecutive operation phases of 37 °C, 42 °C, 47 °C and 52 °C, but their corresponding bands were found to fade out at 57 °C. The DGGE analysis predicted that the temperature transition can result in significant methanogenic biomass washout at 57 °C. PMID:22466006

288

Comparative mesophilic and thermophilic anaerobic digestion of palm oil mill effluent using upflow anaerobic sludge blanket.  

The effects of organic loading rate and operating temperature on the microbial diversity and performances of upflow anaerobic sludge blanket (UASB) reactors treating palm oil mill effluent (POME) were investigated. The following two UASB reactors were run in parallel for comparison: (1) under a mesophilic condition (37 degrees C) and (2) under a mesophilic condition in transition to a thermophilic condition (57 degrees C). A polymerase chain reaction (PCR)-based denaturing gradient gel electrophoresis (DGGE) analysis showed that the microbial population profiles significantly changed with the organic loading rate (OLR) and the temperature transition from the mesophilic to the thermophilic condition. Significant biomass washout was observed for the mesophilic UASB when operating at a high organic loading rate (OLR) of 9.5 g chemical oxygen demand (COD)/L.d. In contrast, the thermophilic UASB can be operated at this OLR and at a temperature of 57 degrees C with satisfactory COD removal and biogas production. The PCR-based DGGE analysis suggested that the thermophilic temperature of 57 degrees C was suitable for a number of hydrolytic, acidogenic, and acetogenic bacteria. PMID:22876480

289

CUPHEA OIL EXTRACTION AND REFINING  

Oils from the seeds of several Cuphea (Lytraceae) species were found to contain high levels of medium-chain fatty acids (MCFA). Currently, MCFAs used in cosmetics, soaps, detergents, lubricants and other related products are obtained from coconut and palm kernel oils. One promising outcome of the ...

290

DIETARY BORON MODIFIES THE EFFECT OF CHANGING DIETARY FATTY ACID COMPOSITION ON RAT BEHAVIOR AND EYE MITOCHONDRIAL MORPHOLOGY  

Female and male Sprague-Dawley rats were fed diets containing about 70 ug boron (B)/kg in a factorial arrangement with variables being supplemental B at 0 (deficient) and 3 (adequate) mg/kg and canola oil (CO) or palm oil (PO) at 75 g/kg. After 5 wks, 6 females per treatment were bred. Pup diets w...

291

DIETARY FAT COMPOSITION MODIFIES THE EFFECT OF BORON ON BONE CHARACTERISTICS AND PLASMA LIPIDS IN RATS  

Female and male rats weighing about 170 g and 200 g, respectively, were fed diets (~70 ug boron/kg) in a factorial arrangement with supplemental boron at 0 (deficient) and 3 (adequate) mg/kg and canola oil or palm oil at 75 g/kg of diet as variables. After 5 weeks, six females in each treatment were...

292

75 FR 862 - Bacillus subtilis; Registration Review Proposed Decision; Notice of Availability  

...heading, Federal Register date and page number). ii...oil seed crops, oil palm, okra, peanuts, peppers...or before the closing date. These comments will...received by the closing date and will provide a...decision will explain the effect that any comments...

293

Crystallization Kinetics of Fully Hydrogenated Palm Oil in Sunflower Oil Mixtures  

The crystallization kinetics of mixtures of fully hydrogenated palm oil (HP) in sunflower oil (SF) was studied. The thermal properties and phase behavior of this model system were characterized by means of differential scanning calorimetry and X-ray diffraction. From the melting enthalpy and clear p...

294

Mining for single nucleotide polymorphisms and insertions / deletions in expressed sequence tag libraries of oil palm  

The oil palm is a tropical oil bearing tree. Recently EST-derived SNPs and SSRs are a free by-product of the currently expanding EST (Expressed Sequence Tag) data bases. The development of high-throughput methods for the detection of SNPs (Single Nucleotide Polymorphism) and small indel...

295

Towards more efficient selection for oil yield in the oil palm (Elaeis guineensis Jacquin)  

Detailed studies are made of the variability and heritability of a number of components of oil yield in the oil palm using published data of the breeding programme of the NIFOR in Nigeria and results of a number of experiments carried out at the OPRC in Ghana during the period 1965-1971. Estimations...

296

Weighing in on Dietary Fats  

... meat fats, stick margarine, shortening, and coconut and palm oils. They’re often found in chocolates, baked goods, ... and their Families . Deliciously Healthy Eating Fats and Oils to Choose ... of Communications and Public Liaison Building 31, Room 5B64 Bethesda, MD 20892-2094 nihnewsinhealth@ ...

297

Learning about Fats  

... milk except skim. Saturated fats are also in palm and coconut oils, which are often used in commercial baked goods ( ... help absorb some vitamins. They also are the building blocks of hormones and ... and heart-healthy oils, you've already made fat your friend! Reviewed ...

298

MADS box genes in oil palm (Elaeis guineensis): patterns in the evolution of the SQUAMOSA, DEFICIENS, GLOBOSA, AGAMOUS, and SEPALLATA subfamilies.  

MADS box genes code for a large family of transcription factors which regulate development in higher plants, notably flower formation. We describe here a study of members of the MADS box gene family in oil palm (Elaeis guineensis Jacq.), a representative of the family Arecaceae and order Arecales, a key group of monocotyledons which has been unreported in previous phylogenetic reconstructions of the different recognized clades of MADS box genes. In this study, 13 oil palm MADS box genes were identified and characterized. They were found to belong to five different subfamilies, namely, the previously defined SQUAMOSA, AGAMOUS, AGAMOUS-like2, DEFICIENS, and GLOBOSA groups. Genes belonging to each of these groups play a critical role in the determination of flower structure as defined by the ABCDE model. The in planta expression profiles of the oil palm MADS box genes were studied by RT-PCR and phylogenetic sequence diversity within individual subfamilies was investigated by comparing their deduced protein sequences with those of other angiosperms. Most of the oil palm sequences studied were observed to group with distinct supported clades within their subfamily. Some unexpected groupings were observed between monocot sequences (including oil palm ones) of non-Poaceae origin, probably illustrating the importance of obtaining adequate taxon representation in monocot molecular phylogenies. PMID:16320117

299

Expression of Bacillus thuringiensis insecticidal protein gene in transgenic oil palm  

Abstract in english Oil palm, like all other crops, is susceptible to attack from several insect pests causing significant reduction in productivity. In the past, cry genes from Bacillus thuringiensis have been reported to be effective in conferring resistance towards insect pests in crops such as corn and rice. One of the advantages of these toxin proteins is their specificity towards certain harmful insects. A rapid and efficient method was developed for the transformation and evaluation o (more) f CryIA(b) expression in oil palm. A recombinant vector was introduced into immature embryos (IEs) of oil palm via the biolistic method. More than 700 putative transformed IEs from independent transformation events were generated. Transient transformation efficiency of 81-100 % was achieved. We found that pre-treatment of target tissues with phytohormones is essential for increasing the transformation efficiency. This finding could enable higher transformation rate in oil palm that was previously difficult to transform. PCR analysis further confirmed the presence of the CryIA(b) in the transformed tissues. Expression of CryIA(b) from PCR-positive samples was further confirmed using a rapid gene expression detection system. This novel and rapid detection system could serve as a good opportunity to analyze the impact of transgenes upon transfer to the new environment, especially for crops with long generation cycle, such as oil palm.

300

Regioisomerism of triacylglycerols in lard, tallow, yolk, chicken skin, palm oil, palm olein, palm stearin, and a transesterified blend of palm stearin and coconut oil analyzed by tandem mass spectrometry.  

Triacylglycerols (TAG) of lard, tallow, egg yolk, chicken skin, palm oil, palm olein, palm stearin, and a transesterified blend of palm stearin and coconut oil (82:18) were investigated by chemical ionization and collision-induced dissociation tandem mass spectrometry. Accurate molecular level information of the regioisomeric structures of individual TAGs was achieved. When existing in a TAG molecule of lard, palmitic acid occupied 90-100% of the sn-2 position. Within the major fatty acid combinations in tallow TAGs, the secondary position sn-2 was preferentially occupied in the decreasing order by oleoyl > palmitoyl > stearoyl residues, the order in saturated TAGs being myristoyl > stearoyl = palmitoyl. TAGs in egg yolk were more asymmetric than in chicken skin, with linoleic acid highly specifically attached in the yolk sn-2 carbon. Nearly 50% of yolk TAGs contained 52 carbon atoms with two or three double bonds. Linoleic, oleic, and palmitic acids were in the sn-2 location in decreasing quantities in palm oil and its fractions. Triacylglycerols of equal molecular weight behaved similarly in the fractionation process. Randomization of the parent oil TAGs was seen in the transesterified oil. The tandem mass spectrometric analysis applied provided detailed information of the distribution of fatty acids in individual combinations in TAGs. PMID:11453776

 
 
 
 
301

Optimization of the Enzyme-Catalyzed Synthesis of Amino Acid-Based Surfactants from Palm Oil Fractions  

The feasibility of using palm oil fractions as cheap and abundant sources of raw material for the synthesis of amino acid surfactants was investigated. Of a number of enzymes screened, the best results were obtained with the immobilized enzyme, Lipozyme. The effects of temperature, solvent, incubation period, fatty substrate/amino acid molar ratio, enzyme amount, and water removal on the reactions were analyzed and compared to those on reactions with free fatty acids and pure triglycerides as fatty substrates. All reactions were most efficient when carried out at high temperatures (70–80°C) in hexane as a solvent. However, while reactions with free fatty acids proceeded better when a slight excess of the free fatty acids over the amino acids was used, reactions with triglycerides and palm oil fractions were best performed at equimolar ratios. Also, the addition of molecular sieves slightly enhanced reactions with free fatty acids but adversely affected reactions with triglycerides and palm oil fractions. Although reactions with palm oil fractions took longer (6 d) to reach equilibrium compared to reactions with free fatty acids (4 d) and pure triglycerides (4 d), better yields were obtained. Such lipase-catalyzed transacylation of palm oil fractions with amino acids is potentially useful in the production of mixed medium- to long-chain surfactants for specific applications.   

302

Tool Wear Characteristics of Oil Palm Empty Fruit Bunch Particleboard  

A series of machining experiments on the Oil-Palm Empty Fruit Bunch (OPEFB) particleboard were carried out using a CNC router, to evaluate the tool wearing properties of the composite in comparison to the conventional wood-material particleboard. A single-fluted tungsten-carbide router bit (12 mm ?, 18 000 rpm), with a rake angle of 15° was used in this experiment, in which the depth of cut was 1.5 mm and feed speed was 4.5 m min-1. The router bit machined the edge of the board, moving along the full length before returning to repeat the cycle. The tool was examined for the extent of wear after complete failure had occurred. The result found that the wear pattern was similar in the oil-palm based particleboard and the wood-based particleboard, but the former was twice more abrasive compared to the latter. Microscopic examination of the cutter edge revealed greater incidence of micro-fracture when cutting the oil-palm based particleboard, indicating the presence of hard impurities in the composite. From an economic perspective, the tooling cost for machining oil-palm based particleboard is estimated to be twice of the cost for machining wood-based particleboard. This study shows that the machining properties of oil-palm based particleboard will be a primary concern, if the board is to find widespread application as a potential substitute for wood-based particleboard.

303

Construction of PHB and PHBV multiple-gene vectors driven by an oil palm leaf-specific promoter.  

One of the targets in oil palm genetic engineering programme is the production of polyhydroxybutyrate (PHB) and polyhydroxybutyrate-co-valerate (PHBV) in the oil palm leaf tissues. Production of PHB requires the use of phbA (beta-ketothiolase type A), phbB (acetoacetyl-CoA reductase) and phbC (PHB synthase) genes of Ralstonia eutropha, whereas bktB (beta-ketothiolase type B), phbB, phbC genes of R. eutropha and tdcB (threonine dehydratase) gene of Escherichia coli were used for PHBV production. Each of these genes was fused with a transit peptide (Tp) of oil palm acyl-carrier-protein (ACP) gene, driven by an oil palm leaf-specific promoter (LSP1) to genetically engineer the PHB/PHBV pathway to the plastids of the leaf tissues. In total, four transformation vectors, designated pLSP15 (PHB) and pLSP20 (PHBV), and pLSP13 (PHB) and pLSP23 (PHBV), were constructed for transformation in Arabidopsis thaliana and oil palm, respectively. The phosphinothricin acetyltransferase gene (bar) driven by CaMV35S promoter in pLSP15 and pLSP20, and ubiquitin promoter in pLSP13 and pLSP23 were used as the plant selectable markers. Matrix attachment region of tobacco (RB7MAR) was also included in the vectors to stabilize the transgene expression and to minimize silencing due to positional effect. Restriction digestion, PCR amplification and/or sequencing were carried out to ensure sequence integrity and orientation. PMID:19699761

304

Development of lightweight aggregate concrete using local palm oil clinker industrial waste  

Malaysia is one of the largest producers and manufacturers of palm oil products. Palm oil by-products can be recycled into palm oil clinker (POC). Palm-oil byproducts can be used in concrete, resulting in lower construction costs due to the reduction of dead load and the preservation of nature by eliminating the need to harvest natural aggregates from natural sources. This paper presented the results of an investigation into the mechanical properties of lightweight aggregate concrete made with palm oil clinker as an aggregate replacement material. Five concrete mixtures were prepared including one control mixture and four POC concrete. The paper discussed the materials and methods employed in the study. The paper also reported on tests that were undertaken in which POC was replaced to determine the influence of fine and coarse aggregate in fresh and hardened state concrete. In addition, the properties of POC concrete were evaluated and compared to control concrete by conducting a series of tests on compressive strength, slump and durability. Results were presented according to:workability and density; strength development; split tensile strength; flexural strength; and modulus of elasticity. It was concluded that the POC concrete had sufficient strength and adequate density to be accepted as structural lightweight concrete. 14 refs., 7 tabs., 2 figs.

305

Effect of Oil Palm Fibres Volume Fraction on Mechanical Properties of Polyester Composites  

The effect of two types of oil palm fibres (bunch and fruit) on mechanical properties of polyester composites is examined in the current work considering different volume fractions. Tensile, compression, and flexural properties of the composites were investigated. In addition to that, tensile strengths were calculated theoretically using Hirsch model. Scanning electron microscope (SEM) was used to observe the fracture mechanism of the specimens. Single fibre pull-out tests were performed to determine the interfacial shear strength between polyester resin and both types of oil palm fibres. Results revealed that both types of oil palm fibres enhanced the mechanical performance of polyester composites. At a higher volume fraction (40-50%), tensile strength of the polyester composite was improved, i.e., 2.5 times improvement in the tensile strength value. Experimental tensile strength values of oil palm bunch/polyester composites have a good correlation with the theoretical results, especially at low volume fractions of fibre. Flexural strength of polyester worsened with oil palm fibres at all volume fractions of fibre.

306

Committed carbon emissions, deforestation, and community land conversion from oil palm plantation expansion in West Kalimantan, Indonesia.  

Industrial agricultural plantations are a rapidly increasing yet largely unmeasured source of tropical land cover change. Here, we evaluate impacts of oil palm plantation development on land cover, carbon flux, and agrarian community lands in West Kalimantan, Indonesian Borneo. With a spatially explicit land change/carbon bookkeeping model, parameterized using high-resolution satellite time series and informed by socioeconomic surveys, we assess previous and project future plantation expansion under five scenarios. Although fire was the primary proximate cause of 1989-2008 deforestation (93%) and net carbon emissions (69%), by 2007-2008, oil palm directly caused 27% of total and 40% of peatland deforestation. Plantation land sources exhibited distinctive temporal dynamics, comprising 81% forests on mineral soils (1994-2001), shifting to 69% peatlands (2008-2011). Plantation leases reveal vast development potential. In 2008, leases spanned ?65% of the region, including 62% on peatlands and 59% of community-managed lands, yet oil palm, generating 26% of net carbon emissions. Intact forest cover declines to 4%, and the proportion of emissions sourced from peatlands increases 38%. Prohibiting intact and logged forest and peatland conversion to oil palm reduces emissions only 4% below BAU, because of continued uncontrolled fire. Protecting logged forests achieves greater carbon emissions reductions (21%) than protecting intact forests alone (9%) and is critical for mitigating carbon emissions. Extensive allocated leases constrain land management options, requiring trade-offs among oil palm production, carbon emissions mitigation, and maintaining community landholdings. PMID:22523241

307

QUIET CLEAN SHORT-HAUL EXPERIMENTAL ENGINE (QCSEE)  

Star „ear support interface flange c. Ring gear output .... were light weight, minimum noise, operation with MIL-L-7808 or MIL-L-23699 oils at oil-in ..... aerospace spur gears which is divided into three bands: low scoring risk, medium scoring ...

308

Effect of microwave- and microwave-convection drying conditions on the total soluble phenolic content of 2-phase olive mill waste  

The California olive oil industry produces tons of 2-phase olive mill waste (2POMW) every year as a byproduct of the olive oil milling process. 2POMW is rich in health-promoting phenolic compounds, but it is greater than 60% moisture (wet basis) in its native form and thus expensive to store and tr...

309

Echium oil reduces atherosclerosis in apoB100-only LDLrKO mice  

Introduction: The anti-atherogenic and hypotriglyceridemic properties of fish oil are attributed to its enrichment in eicosapentaenoic acid (EPA; 20:5, n-3) and docosahexaenoic acid (DHA; 22:6, n-3). Echium oil contains stearidonic acid (SDA; 18:4, n-3), which is metabolized to EPA in humans and mice, resulting in decreased plasma triglycerides. Objective: We used apoB100 only, LDLrKO mice to investigate whether echium oil reduces atherosclerosis. Methods: Mice were fed palm, echium, or fish oil-containing diets for 16 weeks and plasma lipids, lipoproteins, and atherosclerosis were measured. Results: Compared to palm oil, echium oil feeding resulted in significantly less plasma triglyceride and cholesterol levels, and atherosclerosis, comparable to that of fish oil. Conclusion: This is the...

310

Application of Multivariate Analysis in Mid-Infrared Spectroscopy as a Tool for the Evaluation of Waste Frying Oil Blends  

Mid-infrared spectroscopy, in association with multivariate chemometric techniques, was employed for pattern recognition and the determination of the composition of waste frying oils (WFO); data are presented in terms of the percentage of soybean oil, palm oil and hydrogenated vegetable fat in frying oil blends. Principal component analysis (PCA) was performed using spectral data (3,000?600?cm?1) to discriminate between the samples containing 100% soybean oil, 100% palm oil, 100% hydrogenated vegetable fat groups and their blends. Additionally, the results indicated that partial least squares (PLS) models based on mid-infrared spectra were suitable as practical analytical methods for predicting the oil contents in WFO blends. PLS models were validated by a representative prediction set, an...

311

Squalene in oils and fats from domestic and commercial fryings of potatoes.  

Squalene was determined in commercial frying oils and fats (sunflower oil, cottonseed oil, corn oil, soybean oil, palm kernel oil, palm oil, vegetable shortening oil, and cooking fats) sampled during deep-frying of potatoes from 21 restaurants in Athens, Greece, and in domestic frying oils [virgin olive oil (VOO), vegetable shortening and sunflower oil] used during the domestic pan-frying and deep-frying of potatoes. The analyses were carried out after cold saponification of the oils followed by gas chromatography-mass spectrometry of the hexane extract. Quantification was carried out by reference curve, using standard squalene solutions. Fresh vegetable oils and fats were found to contain small amounts of squalene (10.2-49.3 mg/100 g oil or fat), with the exception of fresh VOO, which contained 454 mg/100 g. The squalene content of the frying oils was reduced during frying, its lower concentration found in cooked fats (5.9 mg/100 g fat) and its higher in fried VOO (428 mg/100 g oil) after the first frying session. Squalene appeared to be rather stable during frying. Its retention in used restaurant seed oils and fats remained over 50% even after 30 h of frying while a high recovery of 84-96% was observed during the domestic deep-frying of potatoes in VOO. It seems that by using VOO as frying medium a considerable amount of squalene is absorbed by the fried potatoes, thus becoming part of our diet. PMID:14985184

312

Development of palm-based reference materials for the quantification of fatty acids composition.  

Characterisation of fatty acids composition of three palm-based reference materials was carried out through inter-laboratory proficiency tests. Twelve laboratories collaborated in these tests and the fatty acids compositions of palm oil, palm olein and palm stearin were determined by applying the MPOB Test Methods p3.4:2004 and p3.5:2004. Determination of consensus values and their uncertainties were based on the acceptable statistical agreement of results obtained from the collaborating laboratories. The consensus values and uncertainties (%) for each palm oil reference material produced are listed as follows : 0.20% (C12:0), 1.66+/-0.05% (C14:0), 43.39+/-0.39% (C16:0), 0.14+/-0.06% (C16:1), 3.90+/-0.11% (C18:0), 40.95+/-0.23% (C18:1), 9.68+/-0.21% (C18:2), 0.16+/-0.07% (C18:3) and 0.31+/-0.08% (C20:0) for fatty acids composition of palm oil; 0.23+/-0.04% (C12:0), 1.02+/-0.04% (C14:0), 39.66+/-0.19% (C16:0), 0.18+/-0.07% (C16:1), 3.81+/-0.04% (C18:0), 44.01+/-0.08% (C18:1), 10.73+/-0.08% (C18:2), 0.20+/-0.06% (C18:3) and 0.34+/-0.04% (C20:0) for fatty acids composition of palm olein; and 0.20% (C12:0), 1.14+/-0.05% (C14:0), 49.42+/-0.25% (C16:0), 0.16+/-0.08% (C16:1), 4.15+/-0.10% (C18:0), 36.14+/-0.77% (C18:1), 7.95+/-0.29% (C18:2), 0.11+/-0.07% (C18:3) and 0.30+/-0.08% (C20:0) for fatty acids composition of palm stearin. PMID:18391476

313

Immature embryo: A useful tool for oil palm (Elaeis guineensis Jacq.) genetic transformation studies  

Abstract in english Oil palm (Elaeis guineensis Jacq.) is the highest yielding oil-bearing crop. However, being a perennial crop, genetic improvement of oil palm is extremely slow. Indeed, compared to other annual oil crops such as soybean and rapeseed, genetic manipulations remained less important. Therefore, to remain competitive, oil palm growers and breeders need new and novel approaches. In this report, the potential of immature embryos (IE) as a useful tool for oil palm genetic transfo (more) rmation studies was evaluated. It was evident that IEs were amenable to both direct and Agrobacterium-mediated gene transfer. Due to the abundant supply of IE, optimization of biolistic and Agrobacterium-mediated gene transfer into IEs were easily carried out. Transient transformation frequencies were comparable to other plant systems reported, with as high as 97.4% recorded for biolistic and 64.4% for Agrobacterium-mediated gene transfer. Like most moncots, oil palm tissues were less sensitive to kanamycin, geneticin and chloramphenicol. Instead, both hygromycin and phosphinotrycin were toxic 20 mg/l, making both suitable candidates for selecting putative transformants. IEs were also more responsive to in vitro manipulations as compared to other explants such as leaf and root tissues. Rapid in vitro response to callusing and embryogenesis or rapid and highly efficient direct germination resulted in a shorter culture period. This would minimize the production of abnormal clonal palms, which has been associated to chromosomal aberration due to prolonged time in culture. In addition, IEs also allows rapid and direct introduction of elite genes into breeding programs and in biclonal seed production.

314

FY 1999 report on the technically fundamental study on feasibility of the model projects for effective utilization of palm waste in Malaysia; 1999 nendo Malaysia/palm yashi haikibutsu yuko riyo model jigyo jisshi kanosei ni kakawaru gijutsuteki kiso chosa hokokusho  

Described herein are the FY 2000 results of the feasibility study on the projects for effective utilization of palm waste (empty fruits bunches, fibers and shells). Case II considers to transfer EFB discharged from palm oil plants to palm oil refiners to be used as boiler fuel. This is a promising system for various advantages; for example, it needs a lower investment cost, the site can be easily selected, and the spreading effects can be expected. Case III considers to convert all types of waste (fibers, shells and EFB's) discharged from palm oil plants into steam and electricity in the same plants. It produces electricity at a lower cost than Case II, although needing a 2 times higher construction cost. Applicability of this case, including site selection, is more limited, because all the existing equipment would have to be replaced, or co-generation plants would have to be installed in new palm oil plants. For implementing the model project, it is necessary to conduct the technical assessment through combustion tests, and also to verify that boiler combustion systems to be employed are economically capable of spreading in Malaysia. At the same time, it is important to assess the energy potential and needs at the sites. (NEDO)

315

A Greenhouse Gas Balance of Electricity Production from Co-firing Palm Oil Products from Malaysia  

The Netherlands imports significant quantities of biomass for energy production, among which palm oil has been used increasingly for co-firing in existing gas-fired power plants for renewable electricity production. Imported biomass, however, can not simply be considered a sustainable energy source. The production and removal of biomass in other places in the world result in ecological, land-use and socio-economic impacts and in GHG emissions (e.g. for transportation). As a result of the sustainability discussions, the Cramer Commission in the Netherlands has formulated (draft) criteria and indicators for sustainable biomass production. This study develops a detailed methodology for determining the GHG balance of co-firing palm oil products in the Netherlands based on the Cramer Commission methodology. The methodology is applied to a specific bio-electricity chain: the production of palm oil and a palm oil derivative, palm fatty acid distillate (PFAD), in Northeast Borneo in Malaysia, their transport to the Netherlands and co-firing with natural gas for electricity production at the Essent Claus power plant.

316

Thermal and Structural Behavior of Palm Oil. Influence of Cooling Rate on Fat Crystallization  

Summary: The effects of scanning rates (q = -0.5 degreeC/min to -50 degreeC/min) on the formation of the different phases occurring at low temperature of a palm oil are investigated by means of calorimetry and optical analysis. It is demonstrated that the cooling rates changed the polymorphism of triacylglycerols (TAGs). The centrifugation is used to separate the two fractions (olein and stearin) of palm oil. We show whereas the rate of centrifugation the separation is not effective. We obtained two fractions, a liquid fraction and a solid fraction which contains some liquid TAGs. It is observed that the solid fraction of palm oil is more sensitive to the effects of the cooling rates. By changing the cooling rate q, it appears threshold behaviour for q = -3 degreeC/min dividing the data di...

317

FY 1999 report on the model project on the effective utilization of waste-base biomass fuels. Basic survey for the feasibility; 1999 nendo haikibutsukei biomass nenryo yuko riyo model jigyo jisshi kanosei kiso chosa hokokusho  

Survey on the waste biomass was conducted for Thailand, Malaysia, Indonesia, Vietnam, Laos, Nepal, Butan, Myanmar and Cambodia to study feasibility of the project for the concrete utilization of biomass resources. In Thailand, it is expected to construct large-scale model plants for biomass resources such as rice hulls, bagasse, wood waste and oil palm. In Malaysia, expected are the cogeneration at 5MW class palm oil plant, large-scale power plant using wood waste, plant using the biomass from waste palm oil, etc. In Indonesia, there is a great potentiality, but it is necessary to handle it carefully in consideration of the unstable situation of the society. In Vietnam, the detailed survey of feasibility is needed on the project for efficiency heightening at state-run plants, the assumed national plants (recommended by the government), etc. In Laos, small-scale power generation using the forestry waste such as sawdust is expected. (NEDO)

318

Oil palm biomass as a sustainable energy source: A Malaysian case study  

It has been widely accepted worldwide that global warming is by far the greatest threat and challenge in the new millennium. In order to stop global warming and to promote sustainable development, renewable energy is a perfect solution to achieve both targets. Presently million hectares of land in Malaysia is occupied with oil palm plantation generating huge quantities of biomass. In this context, biomass from oil palm industries appears to be a very promising alternative as a source of raw materials including renewable energy in Malaysia. Thus, this paper aims to present current scenario of biomass in Malaysia covering issues on availability and sustainability of feedstock as well as current and possible utilization of oil palm biomass. This paper will also discuss feasibility of some bio...

319

Coal fly ash-based synthetic aggregates as potential alternative container substrates for ornamentals  

This research was carried out to study the characteristics and the potential utilization of coal fly ash-based synthetic aggregates (CSA) with oil palm waste as an alternative container substrate for ornamental-plant production. CSA only, oil palm waste only, and two mixing ratios of CSA with oil palm waste at the ratio of 1:5 and 1:10 (V/V) were utilized under this study. Zeolite was utilized as a standard substrate to compare characteristics of other substrates. The physical and chemical properties of all substrates were characterized. Scanning electron microscopy (SEM) of coal fly ash and CSA were conducted in order to study the structural configuration of the CSA. Developed CSA gave an alkaline pH (9.82), high electrical conductivity (96.1 mS m-1), high cation concentrations, high wate...

320

Comparative exergetic performance analysis of hydrogen production from oil palm wastes and some other biomasses  

In this study, we investigate the exergetic performance assessment of hydrogen production from gasification of various biomasses, including oil palm. We employ the operational and energy data as taken from the literature for two different gasifier samples of oil palm biomasses. The first one is a steam gasification of oil palm wastes over supported tri-metallic catalyst. We calculate the specific exergies for shell, fiber and empty fruit bunches (EFB) as 22.7, 21.1 and 20.03 MJ/kg, respectively. Based on these, with no catalyst, calcined dolomite and tri-metallic catalyst cases, hydrogen contents of syngas change from 36.5 to 53.6 (%v/v). We then calculate the specific exergy values of these syngases to be 14.59, 16.65 and 15.15 MJ/kg with no catalyst, calcined dolomite and tri-metallic ca...

 
 
 
 
321

A Novel Transcript of Oil Palm (Elaeis guineensis Jacq.), Eg707, is Specifically Upregulated in Tissues Related to Totipotency  

In this study, we report the molecular characterization of clone Eg707 isolated from cell suspension culture of the oil palm. The deduced polypeptide of clone Eg707 is highly similar to an unknown protein from Arabidopsis thaliana. The presence of an Ald-Xan-dh-C2 superfamily domain in the deduced protein sequence suggested that Eg707 protein might be involved in abscisic acid biosynthesis. Eg707 might be present as a single copy gene in the oil palm genome. This gene is highly expressed in tissue cultured materials compared to vegetative and reproductive tissues, suggesting a role of this gene during oil palm somatic embryogenesis or at the early stages of embryo development. Expression analysis of Eg707 by RNA in situ hybridization showed that Eg707 transcripts were present throughout so...

322

Sequence Analysis of 16S rRNA and secA Genes Confirms the Association of 16SrI-B Subgroup Phytoplasma with Oil Palm (Elaeis guineensis Jacq.) Stunting Disease in India  

Abstract During January 2010, severe stunting symptoms were observed in clonally propagated oil palm (Elaeis guineensis Jacq.) in West Godavari district, Andhra Pradesh, India. Leaf samples of symptomatic oil palms were collected, and the presence of phytoplasma was confirmed by nested polymerase chain reaction (PCR) using universal phytoplasma-specific primer pairs P1/P7 followed by R16F2n/R16R2 for amplification of the 16S rRNA gene and semi-nested PCR using universal phytoplasma-specific primer pairs SecAfor1/SecArev3 followed by SecAfor2/SecArev3 for amplification of a part of the secA gene. Sequencing and BLAST analysis of the -1.25-kb and -480-bp of 16S rDNA and secA gene fragments indicated that the phytoplasma associated with oil palm stunting (OPS) disease was identical to 16SrI a...

323

The conservation value of oil palm plantation estates, smallholdings and logged peat swamp forest for birds  

The expansion of industrial oil palm cultivation threatens tropical biodiversity globally, especially in developing countries. Driven by plans to generate economic revenue, large-scale plantations are emerging in Southeast Asia, Africa and Brazilian Amazon. However, the ecological impacts of the sector are poorly studied with respect to oil palm management system, and recommended conservation measures are based on limited data. We studied avifauna in oil palm landscapes in Peninsular Malaysia under different management systems (large plantation estates versus smallholdings) and age classes (uniform age versus mixed-age stands). We sampled 41 large plantation estates and 14 smallholdings, as well as 20 sites in an extensively logged peat swamp forest, the type of natural forest prior to con...

324

Wildlife-friendly oil palm plantations fail to protect biodiversity effectively  

Abstract Expansion of agriculture is a principal driver of biodiversity losses in the tropics, prompting suggestions that plantations should be made more hospitable to wildlife. Such "wildlife-friendly" practices contrast with the alternative "land sparing" strategy, which promotes separation of agricultural and conservation areas. Focusing on the wildlife-friendly strategy of retaining fragments of forest within the agricultural matrix, here we report the abundance and diversity of birds within oil palm plantations, fragments, and contiguous forest. Abundances of imperiled bird species were 60 times lower in fragments and 200 times lower in oil palm than in contiguous forest. Forest fragments also did not increase bird abundances in adjacent oil palm, had lower species richness than conti...

325

Torrefaction and low temperature carbonization of oil palm fiber and eucalyptus in nitrogen and air atmospheres.  

Torrefaction is a pretreatment method for upgrading biomass as solid fuels. To provide flexible operations for effectively upgrading biomass at lower costs, the aim of this study was to investigate the properties of oil palm fiber and eucalyptus pretreated in nitrogen and air atmospheres at temperatures of 250-350°C for 1h. Based on energy and solid yield and introducing an energy-mass co-benefit index (EMCI), oil palm fiber pretreatment under nitrogen at 300°C provided the solid fuel with higher energy density and less volume compared to other temperatures. Pretreatment of oil palm fiber in air resulted in the fuel with low solid and energy yields and is therefore not recommended. For eucalyptus, nitrogen and air can be employed to upgrade the biomass, and the suggested temperatures are 325 and 275°C, respectively. PMID:22940305

326

The biofuel connection - transnational activism and the palm oil boom  

The 10 percent mandatory target for 'renewable energy' adopted by the European Parliament in December 2008 is fuelling a frenzy of investment in palm oil across Southeast Asia, leading in turn to the emergence of new, transnational campaign alliances. The specific dynamics of alliance building, political strategies and impacts of palm oil activism are shaped by the key role of the Indonesian environmental and agrarian justice movement, the broadening and radicalisation of groups in Europe and the ways in which these are interconnected by transnational activists. Campaigning has been successful in creating a transnational political debate around palm oil and biofuels and in influencing public opinion in Europe. Peasant activists have played an important role by combining issues of biodivers...

327

Preparation of diacylglycerol-enriched palm olein by phospholipase A1-catalyzed partial hydrolysis  

Partial hydrolysis of palm olein catalyzed by phospholipase A1 (Lecitase Ultra) in a solvent-free system was carried out to produce diacylglycerol (DAG)-enriched palm olein (DEPO). Four reaction parameters, namely, reaction time (2-10 h), water content (20-60 wt-% of the oil mass), enzyme load (10-50 U/g of the oil mass), and reaction temperature (30-60 degreeC), were investigated. The optimal conditions for partial hydrolysis of palm olein catalyzed by Lecitase Ultra were obtained by an orthogonal experiment as follows: 45 degreeC reaction temperature, 44 wt-% water content, 8 h reaction time, and an enzyme load of 34 U/g. The upper oil layer of the reaction mixture with an acid value of 54.26 +- 0.86 mg KOH/g was first molecularly distilled at 150 degreeC to yield a DEPO with 35.51 wt-% ...

328

Microalgae as a sustainable energy source for biodiesel production: A review  

Of the three generations of biodiesel feedstocks described in this paper, food crops, non-food crops and microalgae-derived biodiesel, it was found that the third generation, microalgae, is the only source that can be sustainably developed in the future. Microalgae can be converted directly into energy, such as biodiesel, and therefore appear to be a promising source of renewable energy. This paper presents a comparison between the use of microalgae and palm oil as biodiesel feedstocks. It was found that microalgae are the more sustainable source of biodiesel in terms of food security and environmental impact compared to palm oil. The inefficiency and unsustainability of the use of food crops as a biodiesel source have increased interest in the development of microalgae species to be used as a renewable energy source. In this paper, the main advantages of using microalgae for biodiesel production are described in comparison with other available feedstocks, primarily palm oil. (author)

329

BVOC fluxes from oil palm canopies in South East Asia  

Fluxes by virtual disjunct eddy covariance were measured for the first time in South-East Asia in 2008 from an oil palm plantation. Malaysia and Indonesia account for more than 80% of world oil palm production. Our in situ findings suggest much higher isoprene emissions from oil palms than from rainforest, which is consistent with earlier lab-based predictions of emissions from oil palms (Wilkinson et al., 2006). 50% of global biogenic VOC emissions are estimated to derive from tropical rainforests (Guenther et al., 1995) although in fact a large portion of the emission may derive from oil palms in the tropics. Isoprene and monoterpenes are regarded as the most important biogenic VOCs for the atmospheric chemistry. Overall, maximum isoprene emissions from oil palms were recorded at 11:00 local time, with a mean value of 13 mg m-2 h-1. At the rainforest, the maximum fluxes of isoprene were observed later in the day, at about 13:00 with an average of 2.5 mg m-2 h-1. Initial flux results for total monoterpenes indicate that their mass emission ratio with respect to isoprene was about 1:9 at the rainforest and 1:18 at the oil palm plantation. The results are presented with reference to temperature, photosynthetic radiation and meteorological drivers as well as in comparison with CO2 and H2O fluxes. Empirical parameters in the Guenther algorithm for MEGAN (Guenther et al, 2006), which was originally designed for the Amazon region, have been optimised for this oil palm study. The emission factor obtained from eddy covariance measurements was 18.8 mg m-2 h-1, while the one obtained from leaf level studies at the site was 19.5 mg m-2 h-1. Isoprene fluxes from both Amazonia (Karl et al., 2007) and from rainforest in Borneo 2008 seem to be much lower than from oil palms. This can have consequences for atmospheric chemistry of land use change from rainforest to oil palm plantation, including formation of ozone, SOA and particles and indirect effects on the removal rate of greenhouse gases and pollutants by decreasing OH budgets. Global models predicting atmospheric changes and bottom-up estimates from the tropics must be constrained by direct measurements such as presented here, taking separate account of these major contributions from oil palm plantations and tropical rainforests. References: Guenther, A., C.N. Hewitt, D. Erickson, R. Fall, C. Geron, T.E. Graedel, P. Harley, L. Klinger, M. Lerdau, W.A. McKay, T. Pierce, B. Scholes, R. Steinbrecher, R. Tallamraju, J. Taylor and P. Zimmerman, 1995: A global model of natural volatile organic compound emissions. Journal of Geophysical Research 100, 8873-8892. Guenther, A., T. Karl, P. Harley, C. Wiedinmyer, P. I. Palmer, and C. Geron, 2006: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature). Atmos. Chem. Phys. Discuss., 6, 107-173. Karl, T., A. Guenther, R. J. Yokelson, J. Greenberg, M. Potosnak, D. R. Blake, and P. Artaxo, 2007: The tropical forest and fire emissions experiment: Emission, chemistry, and transport of biogenic volatile organic compounds in the lower atmosphere over Amazonia. Journal of Geophysical Research 112, D18302. Wilkinson, M. J., S. M. Owen, M. Possell, J. Hartwell, P. Gould, A. Hall, C. Vickers, and C. N. Hewitt, 2006: Circadian control of isoprene emissions from oil palm (Elaeis guineensis). Plant Journal 47, 960-968.

330

Ethanol production from oil palm trunks treated with aqueous ammonia and cellulase.  

Oil palm trunks are a possible lignocellulosic source for ethanol production. Low enzymatic digestibility of this type of material (11.9% of the theoretical glucose yield) makes pretreatment necessary. An enzymatic digestibility of 95.4% with insoluble solids recovery of 49.8% was achieved after soaking shredded oil palm trunks in ammonia under optimum conditions (80°C, 1:12 solid-to-liquid ratio, 8h and 7% (w/w) ammonia solution). Treatment with 60 FPU of commercial cellulase (Accellerase 1000) per gram of glucan and fermentation with Saccharomyces cerevisiae D(5)A resulted in an ethanol concentration of 13.3g/L and an ethanol yield of 78.3% (based on the theoretical maximum) after 96 h. These results indicate that oil palm trunks are a biomass feedstock that can be used for bioethanol production. PMID:21616661

331

Energy balance of oil palm growing. An approach  

Because the average calorific value of palm and palm kernel oils is close to that of diesel oil, the industrial plantations can produce a significant energy equivalent of about 4.7 TPE/ha. In relation to this potential an attempt has been made by an appraisal of its biomass and of the energy spent to produce it to estimate the degree of efficiency of this crop and to determine the influence of the main parameters on its energy management. A priori, with a degree of efficiency of 3.7, the balance is satisfactory. Many elements, not well known at present, remain to be studied if the oil palm's energy potential is to be better known and used. (Refs. 20).

332

Kinetic study on partial hydrolysis of palm oil catalyzed by Rhizomucor miehei lipase  

A kinetic study on partial hydrolysis for the production of diacylglycerol (DAG) catalyzed by Rhizomucor meihei (Lipase RM IM) was investigated. The optimum conditions were estimated to be 10% (w/w) catalyst with 5% (w/w) water content at 55^oC with stirring speed of 500rpm based on the initial reaction velocity of 7.04mmol/L/min. At optimum conditions, the DAG yield was 31wt% after 6h of reaction. The rheological properties of both untreated palm oil and DAG-enriched palm oil were also investigated and both exhibited Newtonian flow behavior with insignificant differences with respect to their viscosity and flow activation energy. Activation energy for the partial hydrolysis of palm oil was calculated to be 31.35kJ/mol using Arrhenius equation. Morphological evaluation of enzyme particles ...

333

Promotion eligibility of the use of palm oil for electricity production; Foerderungsfaehigkeit der Verwendung von Palmoel zur Stromerzeugung nach paragraph 8 EEG  

Palm oil is classifiable as biomass within the meaning of the Biomass Ordinance. It meets the requirements of paragraph 2 Section 2 Number 2 of the Biomass Ordinance because it is a plant component that is cultivated especially for the purpose of energy production, and no substances of nonbiogenic origin are added to the palm oil in the course of its manufacture and processing for this purpose. Electricity from palm oil is eligible not only for the basic compensation granted for electricity from biomass but also for the bonus granted for the use of renewable raw materials under paragraph 8 Section 2 of the Electricity Feed Law, provided the above conditions are met and provided the installed power plant capacity does not exceed 5 MW.

334

Upgrading of oil palm wastes to animal feeds by radiation and fermentation treatment  

Upgrading of oil palm cellulosic wastes to animal feeds by radiation and fermentation treatment has been investigated in order to recycle the agro-resources and to reduce the smoke pollution. The process is as follows; decontamination of microorganisms in fermentation media using oil palm wastes by irradiation, inoculation of useful microorganisms, and subsequent microbial digestion of cellulosic materials as well as production of proteins. The dose of 25 kGy was required to sterilize the contaminated bacteria whereas the dose of 5 - 10 kGy was enough to eliminate the fungi. Among many kinds of fungi tested, C. cinereus was selected as the most suitable seed microorganism for the fermentation of EFB (Empty Fruit Bunch of oil palm). The protein content increased to 13 % and the crude fiber content decreased to 20 % after 30 days incubation with C. cinereus at 30degC in solid state fermentation. It is considered that these fermented products can be used for the ruminant animal feeds. (author).

335

Effect of dietary fats rich in lauric, myristic, palmitic, oleic or linoleic acid on plasma, hepatic and biliary lipids in cholesterol-fed hamsters.  

Effects of different dietary fats on plasma, hepatic and biliary lipids were determined in male golden Syrian hamsters (Mesocricetus auratus) fed on purified diets for 7 weeks. Diets were made by blending different fats containing characteristic fatty acids: butter (14:0 + 16:0), palm stearin (16:0), coconut oil (12:0 + 14:0), rapeseed oil (18:1), olive oil (18:1) and sunflowerseed oil (18:2). In all diets except the sunflowerseed oil diet dietary 18:2 was held constant at 2% energy. Total fat supplied 12% of energy and cholesterol was added at 4 g/kg diet. Plasma cholesterol and triacyglycerol concentrations were increased by dietary cholesterol. After 7 weeks, plasma cholesterol concentrations were highest with the palm stearin, coconut oil and olive oil diets (8.9, 8.9 and 9.2 mmol/l) and lowest with the rapeseed oil and sunflowerseed oil diets (6.7 and 5.5 mmol/l) while the butter diet was intermediate (8.5 mmol/l). Hepatic cholesterol concentration was highest in hamsters fed on the olive oil diet and lowest with the palm stearin diet (228 v. 144 mumol/g liver). Biliary lipids, lithogenic index and bile acid profile of the gall-bladder bile did not differ significantly among the six diets. Although the gallstone incidence was generally low in this study, three out of 10 hamsters fed on the palm stearin diet developed cholesterol gallstones. In contrast, no cholesterol gallstones were found with the other diets. Rapeseed and sunflowerseed oils caused the lowest plasma cholesterol and triacyglycerol concentrations whereas olive oil failed to demonstrate a cholesterol-lowering effect compared with diets rich in saturated fatty acids. Since 18:2 was kept constant at 2% of energy in all diets, the different responses to rapeseed and olive oils could possibly be attributed to their different contents of 16:0 (5.6% v. 12.8% respectively). Other possible explanations are discussed. PMID:9155509

336

Palm-based biofuel refinery (PBR) to substitute petroleum refinery: An energy and emergy assessment  

As the most active palm industry cluster in the world, Malaysia produces enormous amount of biomass from the industry. This work studies the possibility of creating a renewable and sustainable source of energy by fully utilizing an area of land to provide liquid biofuel for the country. Palm-based biofuel refinery (PBR) proposed in this study has the ultimate goal to displace petroleum fuels and fulfill domestic energy demand. It fully utilizes indigenous palm biomass to fulfill 35.5% of energy demand in the country by using land area of only 8% of current palm cultivation. The operation concept of PBR is similar to petroleum refinery in which a single source feedstock (crude petroleum) can be processed to multiple products. In PBR, products from an oil palm plantation will be converted to various biofuel end products. Renewable biofuel such as biodiesel and bioethanol can be produced from crude palm oil and lignocellulosic residues. Energy and emergy assessment were made in this work to evaluate the sustainability and efficiency of PBR. Biofuel produced from PBR has a high energy equivalent of 31.56 MJ/kg as 1 ha of land can produce 182,142 MJ annually. Although there are still obstacles to be overcome, it is important for Malaysia to develop its own energy supply from indigenous resources as an initiative not only for security but also lower carbon emission. (author)

337

Electron spin resonance spectroscopy for evaluation of early oxidative events in semisolid palm oil  

Abstract Electron spin resonance (ESR) spectroscopy was applied to study early oxidative events in semisolid palm oil in bulk. Oil was stored at mildly accelerated conditions of 50C for 7 days and the free radical formation was followed with the addition of spin trap N-tert-butyl--phenyl-nitrone. Dissolution of the oil samples in isooctane prior to ESR measurements stabilized the ESR signal allowing the changes in relative free radical concentrations during oil storage to be monitored. Formation of lipid hydroperoxides as primary lipid oxidation products was found to correlate with the tendency for the formation of free radicals in the oil during the storage and accordingly, ESR spectroscopy may be used to detect the early events in lipid oxidation in palm oil. However, the interference of...

338

Use of palm oil-based biofuel in the internal combustion engines: Performance and emissions characteristics  

Palm oil (PO) was treated using different methods in order to use and test it as fuel in Compression Ignition (CI) engines. The treatments include PO preheated and preparation of PO/diesel oil blends, using mixtures of PO with waste cooking oil (WCO), which are converted into esters by a transesterification process. The purpose of this study is to evaluate the potential of the palm oil-based biofuels to replace diesel oil in CI engines. Tests were conducted in a single cylinder, four-stroke, air-cooled, direct injection diesel engine (no engine modifications were required). Experiments were initially carried out with diesel oil for providing baseline data. All the tested fuels have a low heating value compared to diesel fuel. A high fraction of PO in diesel fuel decreases the heating value...

339

Influence of a lipid phase on steam jet agglomeration of maltodextrin powders  

The contribution of an oil phase to the agglomeration mechanisms of food powders was evaluated. Maltodextrin (DE 10), palm oil stearin and two palm oil oleins (up to 25% dry mass) were used as food models. Granulation runs were carried out in a pilot plant steam jet agglomerator. The powders containing oleins were more cohesive than those with stearin and the presence of oil changed the agglomeration mechanisms. The size increase mechanism of pure maltodextrin powder was controlled by surface plasticization and agglomerates with suitable instant properties were obtained. Small amount of oil degenerated drastically the rate of dispersion in water of the powders and their agglomerates but the average size and the mechanical resistance of the agglomerates increased when the oil content of the...

340

Identification of volatile aroma compounds in processed cheese analogues based on different types of fat  

The simple and rapid solid-phase micro-extraction method using gas chromatography was used for the identification and quantification of volatile aroma compounds in various types of processed cheese analogues produced from different types of fat (butter, butter oil, coconut oil, palm oil, and sunflower oil). In total, 31 organic compounds belonging to five chemical groups were identified, with the alcohols and fatty acids quantitatively predominant. The contents of the aroma compounds (the so-called aroma profiles) of the analogues and corresponding fats used as raw materials were compared. Significant differences (p < 0.05) were found between samples. The highest total content of aroma compounds was found in coconut oil analogue ((547.30 ? 9.82) mg kg?1), the lowest in palm oil analogue ((...

 
 
 
 
341

Elemental and thermo-chemical analysis of oil palm fronds for biomass energy conversion  

Oil palm frond is the most abundant yet untapped biomass waste in Malaysia. This paper investigates the characteristics of raw oil palm fronds and its ash to evaluate its potential utilization as a biomass fuel for gasification process using single throat downdraft gasifier. The morphological nature, elemental content, proximate and ultimate analysis and calorific value were studied. Field emission scanning electron microscopy and x-ray fluorescence were used to investigate the surface morphology, elemental and mineralogical nature of oil palm frond and its ash. The results were compared with other agricultural and forestry biomass wastes. From proximate analysis volatile matter, fixed carbon and ash were found to be 83.5%, 15.2% and 1.3%, respectively on dry basis. From ultimate analysis result values of 44.58%, 4.53%, 0.71% and 0.07% for carbon, hydrogen, nitrogen and sulfur were found respectively on dry basis. Oxygen was determined by difference and found to be 48.81%. The proximate and ultimate analysis results indicate that oil palm frond is better than agricultural wastes and less than most forestry wastes to use as a feedstock in the gasification process in order to get a better quality of syngas. The amount of ash content in OPF was found to be much less than in agricultural wastes and higher than most forestry wastes. From x-ray fluorescence analysis CaO and K2O were found as the major oxides in oil palm fronds and rice husk ash with the amount of 28.46% and 15.71% respectively. The overall results of oil palm fronds were found to be satisfactory to use as a feedstock for the process of gasification.

342

Oil palm BVOC emissions and their potential for aerosol formation  

During ambient measurements at oil palm plantation (OP3/ACES projects) which took place from May to June 2008 we recorded by direct eddy covariance technique with proton transfer reaction mass spectrometry (PTR-MS) large emission fluxes of isoprene (mid-day mean 8.6 mg m-2 h-1), estragole (0.81 mg m-2 h-1), acetone (0.1 mg m-2 h-1), hexanals (0.05 mg m-2 h-1) and remaining compounds (~ 1 mg m-2 h-1). However, secondary products of isoprene oxidation such as MVK+MACR exhibited high deposition rates (1 cm s-1) which were close to maximal theoretical values. In addition, methanol and, to some extent, other VOC compounds exhibited negative fluxes during the day. Despite several times higher emissions of isoprene from oil palm than from a nearby rainforest, it is uncertain how these differences would impact on the formation of aerosols. There have been recently many speculations about actual contribution of isoprene emissions to aerosol formation, for example whether they could inhibit the creation of aerosols due to scavenging of hydroxyl radicals, in contradiction to an earlier OH-radical recycling hypothesis. Regardless, mass aerosol yields from isoprene have been thought low (up to ~2%), which can however make up significant overall loading at large emissions such as encountered at oil palm. Although oil palm was not found to be a monoterpene emitter, it appears that the largest contributor to aerosol production from oil palms might be floral emissions of estragole with its aerosol yield from photooxidation of this compound being similar to that of monoterpenes (~40%). In addition, other VOCs might have also an effect. We show the parameterisation for emission and deposition of particular VOCs and relate them to aerosol yields found in literature. Overall, it seems that the net aerosol formation potential with regards to VOCs emitted from oil palm may not be much different to that of rainforest, despite differences in the VOC mix emitted by these land uses.

343

Somatic embryogenesis in macaw palm (Acrocomia aculeata) from zygotic embryos  

Macaw palm (Acrocomia aculeata) is an oleaginous palm tree that is highly productive and adapted to semiarid ecosystems, which oil can be used to produce biodiesel. Such characteristics make macaw palm a potential crop to be used by farmers from semi-arid regions, but its propagation is still problematic. This paper reports the first description of somatic embryogenesis for macaw palm from zygotic embryos. The explants were cultured on Y3 medium and different combinations of plant growth regulators. After 60 days of culture, embryogenic callus were induced with 9mM of 4-amino-3,5,6-trichloropicolonic acid (picloram) or 2,4-dichlorophenoxyacetic acid (2,4-D), combined or not with 1mM N-phenyl Nprime1,2,3 thidiazol-5-yl urea (TDZ). Naphthoxy acetic acid (NOA) and 4-chlorophenoxyacetic acid (...

344

Natural efficiency of parasitism by Billaea rhynchophorae (Blanchard) (Diptera: Tachinidae) for the control of Rhynchophorus palmarum (L.) (Coleoptera: Curculionidae).  

The occurrence of the tachinid parasitoid Billaea rhynchophorae (Blanchard) on larvae of the palm weevil Rhynchophorus palmarum (L.) was evaluated in plantations of piassava palm (Attalea funifera Mart.) and African oil palm (Elaeis guineensis Jacquin), in southeastern Bahia, Brazil. The monthly percentages of parasitism were evaluated during 13 months, from November 2000 to November 2001, based on the comparison between the number of parasitized and non-parasitized cocoons of R. palmarum. Mean parasitism was 40% and ranged from 50% in November 2000 to 18% in July 2001. While there is no method of mass reproduction of the parasitoid, a simple management practice is recommended, in order to preserve its beneficial effects in palm plantations. PMID:17348142

345

Analysis of beta-carotene hydroxylase gene cDNA isolated from the American oil-palm (Elaeis oleifera) mesocarp tissue cDNA library.  

It is well known that the nutritional quality of the American oil-palm (Elaeis oleifera) mesocarp oil is superior to that of African oil-palm (Elaeis guineensis Jacq. Tenera) mesocarp oil. Therefore, it is of important to identify the genetic features for its superior value. This could be achieved through the genome sequencing of the oil-palm. However, the genome sequence is not available in the public domain due to commercial secrecy. Hence, we constructed a cDNA library and generated expressed sequence tags (3,205) from the mesocarp tissue of the American oil-palm. We continued to annotate each of these cDNAs after submitting to GenBank/DDBJ/EMBL. A rough analysis turned our attention to the beta-carotene hydroxylase (Chyb) enzyme encoding cDNA. Then, we completed the full sequencing of cDNA clone for its both strands using M13 forward and reverse primers. The full nucleotide and protein sequence was further analyzed and annotated using various Bioinformatics tools. The analysis results showed the presence of fatty acid hydroxylase superfamily domain in the protein sequence. The multiple sequence alignment of selected Chyb amino acid sequences from other plant species and algal members with E. oleifera Chyb using ClustalW and its phylogenetic analysis suggest that Chyb from monocotyledonous plant species, Lilium hubrid, Crocus sativus and Zea mays are the most evolutionary related with E. oleifera Chyb. This study reports the annotation of E. oleifera Chyb. ABBREVIATIONS: ESTs - expressed sequence tags, EoChyb - Elaeis oleifera beta-carotene hydroxylase, MC - main cluster. PMID:21364789

346

Electricity generation using vegetal oils: the implantation model for the isolated communities in the Amazon Region; Geracao de eletricidade a partir de oleos vegetais: um modelo de implantacao para comunidades isoladas amazonicas  

The territorial occupation from the Amazon region is characterized by isolated communities, which makes the conventional electric distribution economically and technically impracticable. To solve the electric problem of these communities, it is necessary for them to produce their own fuel in order to generate electric energy and promote the development. These are the premises that have guided the elaboration of the project PROVEGAM - which has as objective, the installation and performance testing of a conventional diesel engine, adapted to operate with palm oil 'in natura' at the community of Vila Soledade, city of Moju, Para State. Vila Soledade is an isolated community that has, approximately, 700 inhabitants. The PROVEGAM project installed a diesel generator adapted with a conversion kit to operate with 'in natura' palm oil. The operation begins and finishes with diesel oil, in order to heat the palm oil and cleaning possible residues. During the diesel generator installation, diesel oil emissions and performance were compared with the palm oil. Analysing the results, this electric model of generating energy is already recommended to be implemented in others Amazon region communities. (author)

347

Trading forests for yields in the Peruvian Amazon  

Our knowledge of how agriculture expands, and the types of land it replaces, is remarkably limited across the tropics. Most remote-sensing studies focus on the net gains and losses in forests and agricultural land rather than the land-use transition pathways (Gibbs et al 2010). Only a handful of studies identify land sources for new croplands or plantations, and then only for farming systems aggregated together (e.g., Koh and Wilcove 2008, Morton et al 2006, Gibbs et al 2010). Gutiérrez-Vélez et al (2011), however, have taken a leap forward by tracking the different expansion pathways for smallholder and industrial oil palm plantations. Using a combination of Landsat, MODIS and field surveys, they investigate whether higher yields in new agricultural lands spare forests in the Peruvian Amazon and in a smaller focus area in the Ucayali region. Across the Peruvian Amazon, they show that between 2000 and 2010, new high-yield oil palm plantations replaced forests 72% of the time and accounted for 1.3% of total deforestation, with most expansion occurring after 2006. Gutiérrez-Vélez et al went further in the Ucayali region and compared land sources for new high-yield and low-yield plantations. Expansion of higher-yield agricultural lands should logically reduce the total area needed for production, thus potentially sparing forests. In the Ucayali focus area, expansion of high-yield oil palm did convert less total land area but more forest was cleared than with low-yield expansion. Smaller-scale plantations tended to expand into already cleared areas while industrial-scale plantations traded their greater yields for forests, leading to higher land-clearing carbon emissions per production unit (Gibbs et al 2008). Gutiérrez-Vélez et al show that higher yields may require less land for production but more forest may be lost in the process, and they emphasize the need for stronger incentives for land sparing. The potential land-saving nature of these high-yield plantations could be further analyzed by considering whether they help depress global prices, reducing incentives to expand elsewhere (Angelsen and Kaimowitz 2001). The significance of the study goes well beyond the bounds of Ucayli, and highlights risks to Amazonian forests from oil palm expansion (Butler and Laurance 2010). Oil palm is an astoundingly profitable and productive crop, with typical oil yields more than ten times that of soy. Some have even argued that oil palm is innately land sparing because it would take substantially more land for all other oil-bearing crops to provide the same output. However, most production gains from oil palm have occurred through increased area rather than increased yield, and in many cases expansion has been through forest clearing (Koh and Wilcove 2008, Gibbs et al 2010). The findings of Gutiérrez-Vélez et al (2011) are particularly significant considering that the booming palm oil sectors in Indonesia and Malaysia, which currently produce over 80% of the world's product, are facing a host of pressures that constrain future area expansion. Malaysia has little remaining land suited for plantations and Indonesia faces intensifying international scrutiny over the future of their forestlands. Consequently, the Amazon basin is widely considered the new frontier, with more than half of its forest area suitable for palm oil cultivation (Butler and Laurance 2010) and growing incentives from Brazil's Program for the Sustainable Production of Oil Palm, which aims to utilize degraded lands and spur reforestation efforts. Their results also illuminate another key issue, namely the constraints faced by large-scale producers when they seek to expand plantation area. Emerging demand-side conservation efforts, such as the Roundtable for Sustainable Palm Oil (RSPO), assume that already cleared and non-forested lands are freely available. Gutiérrez-Vélez et al (2011) hint at the obstacles to using such cleared lands, which is that they are inhabited and often have contested land tenure. We must carefully consider our consumption of these c

348

Re-Inventing Dualism: Policy Narratives and Modes of Oil Palm Expansion in Sarawak, Malaysia  

The policy narrative underpinning the current rapid expansion of large-scale, private, oil palm plantations in Sarawak, Malaysia, implies a dualistic conception of the agrarian transformation underway, such as prevailed in the 1950s. This narrative is inconsistent with the history of smallholder commercialisation in Sarawak. Post-1981 policy has sought to limit smallholder development and deliver large land areas to private estates, thus 're-inventing' a dualistic agrarian structure. Oil palm expansion in Sarawak has various potential pathways and is driven in its present direction, not by dualistic economics, but the exercise of state power to maximise opportunities for surplus extraction and political patronage.

349

Comportamento de cristalização de lipídios estruturados obtidos a partir de gordura de palmiste e óleo de peixe/ Crystallization behavior of structured lipids produced from palm kernel fat and fish oil  

Abstract in english The aim of this study is to evaluate the crystal structure of binary mixtures of palm kernel fat and fish oil, before and after chemical and enzymatic interesterification. The crystal structure was analyzed by polarized light microscopy. The addition of fish oil didn't change the palm kernel fat crystallization characteristics, spherullites of types A and B being observed. However, due to chemical and enzymatic interesterification, smaller crystals were obtained. There wa (more) s no difference between chemical and enzymatic interesterification, probably as a function of acyl migration in discontinuous processes catalyzed by lipases.

350

Potential Availability of Energetically Usable Crop Residues in Nigeria  

An assessment of the potential availability of selected residues from maize, cassava, millet, plantain, groundnuts, sorghum, oil palm, palm kernel, and cowpeas for possible conversion to renewable energy in Nigeria has been made. It is estimated that nearly 58 million tonnes of these residues were potentially available in the year 2004 with energy potential of about 20.8 million tonnes oil equivalents. The residue availability for 2010 is projected to be about 80 million tonnes. These residues, when converted to energetically usable forms, can substitute or complement the fossil energy sources in Nigeria by more than 80%.

351

A study of the effect of palm oil as MQL lubricant on high speed drilling of titanium alloys  

The main objective was to study the potency of MQL palm oil (MQLPO) as a lubricant in the high speed drilling of Ti-6Al-4V. For the comparison, MQL synthetic ester (MQLSE), air blow and flood conditions were selected. Uniform flank wear, micro-chipping, thermal cracking and flaking were the dominant tool failure modes. It was found that MQLSE and MQLPO gave comparable performance with the flood conditions. In addition, MQLPO outperformed MQLSE on the cutting forces, temperature, power and specific cutting energy. This shows that palm oil can be used as a viable alternative to synthetic ester for MQL lubricant.

352

Low density polyethylene-chitosan composites: A study based on biodegradation  

In recent years, there has been a marked increase in the interest in biodegradable polymer materials for the use in packaging, agriculture, medicine, and other areas. Biodegradable composite films has been fabricated, via peroxide initiated melt-compounding process, by blending low density polyethylene (LDPE) and chitosan, in a rotor disperser. Chitosan, maleic anhydride (MA), dicumyl peroxides (DCP) and oleic acid constituent in palm oil have been used as biodegradable filler, coupling agent, free radical initiator and Lewis acid catalyst, respectively. The palm oil serves the additional function of a plasticizer as indicated by the mechanical property studies. The hydrophilicity, thermal, biodegradablity and dielectric properties of the biocomposite system have also been investigated. Bi...

353

New perspectives for sustainably produced palm oil?; Neue Perspektiven fuer nachhaltiges Palmoel?  

Power generation from biomass is one of the key issues of renewable power generation today, and the demand for raw materials like palm oil is increasing accordingly. Malaysia, the world's second biggest producer after Indonesia, considers that the time has come for a change of perspective in the political discussion of the global biomass potential. Palm oil may indeed become a staple in biomass supply for power generation and mobility, but only if rigid sustainability criteria are maintained to prevent environmental damage from the very biomass utilization technology originally developed to protect the environment.

354

Intake of Repeatedly Heated Palm Oil Causes Elevation in Blood Pressure with Impaired Vasorelaxation in Rats  

Oxidization of dietary cooking oil increases the risk of cardiovascular diseases such as hypertension by increasing the formation oxidative oxygen radicals. The aim of study was to investigate the effects of repeatedly heated palm oil on blood pressure, plasma nitrites, and vascular reactivity. Nitrites were measured, as an indirect marker for nitric oxide production. Male Sprague-Dawley rats were divided into four groups: control group fed with basal diet and other three groups fortified with 15% weight/weight fresh palm oil (FPO), palm oil heated five times (5HPO) or palm oil heated ten times (10HPO) for 24 weeks. The oil was heated to 180°C for 10 min. Blood pressure was measured at baseline and at intervals of four weeks for 24 weeks using non-invasive tail-cuff method. Following 24 weeks, the rats were sacrificed and thoracic aortas were dissected for measurement of vascular reactivity. Blood pressure was elevated significantly (p < 0.05) in 5HPO and 10HPO groups, with the 10HPO group showing higher values. Aortic rings from animals fed with heated oil showed diminished relaxation in response to acetylcholine or sodium nitroprusside, and greater contraction to phenylephrine. Acetylcholine and sodium nitroprusside cause endothelium-dependent and endothelium-independent relaxation, respectively. Relaxation responses remained unaltered in the FPO group, with the attenuated contractile response to phenylephrine, compared to control group. FPO increased plasma nitrites by 28%, whereas 5HPO and 10HPO reduced them by 25% and 33%, respectively. Intake of repeatedly heated palm oil causes an increase in blood pressure, which may be accounted for by the attenuated endothelium-dependent vasorelaxant response.   

355

Recycling of Waste Mill Oil through Non-recovery Coke Making  

A plant scale trial was conducted to recycle the mill oil waste through non recovery coke oven route. The waste mill oil was added in the coal blend as a binder before hammer mill and charged in the ovens. JSW Steel has non-recovery coke ovens synergized with vibro-compaction technology to produce coke of 1.2 Mtpa. About 300 L of the mill oil which is generated in the hot strip mill daily was used in the trial. A cake density of 1.1 t/m3 has been achieved using vibro-compaction with optimized moisture, oil addition and crushing fineness. The coke produced with and without oil of same coal blend and coking conditions, was tested and compared. It is observed that utilization of mill oil has not shown any deteriorating effect on coke quality. There is a marginal increase in flue gas as well as oven crown temperature which helped to increase the power generation. This present paper describes the effect of mill oil addition on coke quality and the oven thermal conditions and the feasibility of recycling the waste through non recovery coke ovens at JSW Steel Ltd.   

356

Processing of oilseeds in distributed plants. Results of a survey; Verarbeitung von Oelsaaten in dezentralen Anlagen. Ergebnisse einer Befragung  

The processing of oilseeds in decentralized oil mills has developed to a remarkable branch of business for the agriculture. Since the year 1999 the number of decentralized oil mills in Germany has increased from 79 up to 219 plants. In the year 2003 around 10% of the German rapeseed harvest was processed in 219 decentralized oil mills at an average of 250 working days. Rapeseed oil as a fuel for vegetable oil suited diesel engines as well as rapeseed oil as a raw material for the transesterification to fatty acid methyl esters (FAME) were the two main focuses, when producing cold-pressed oil. In addition to rapeseed, oil was also produced of false flax-, sunflower- and hempseed for the use as edible oil, forage oil and technical oil. The byproduct press cake is used as a high-quality animal food. The acquisition of the rapeseed and the distribution of the two products (oil and rapeseed) happens mainly regionally within an area of maximum 50 km. The technical equipment of the plants differ widely, which results in a high potential for process optimization. Over 70% of the operators of decentralized oil mills would build up a plant for producing cold-pressed oil again, if they had to come to this decision once more. (orig.)

357

Single-laboratory validation of a GC/MS method for the determination of 27 polycyclic aromatic hydrocarbons (PAHs) in oils and fats.  

A protocol for the measurement of 27 polycyclic aromatic hydrocarbons (PAHs) in vegetable oils by GC/MS has undergone single-laboratory validation. PAHs were measured in three oils (olive pomace, sunflower and coconut oil). Five samples of each oil (one unfortified, and four fortified at concentrations between 2 and 50 microg kg(-1)) were analysed in replicate (four times in separate runs). Two samples (one unfortified and one fortified at 2 microg kg(-1)) of five oils (virgin olive oil, grapeseed oil, toasted sesame oil, olive margarine and palm oil) were also analysed. The validation included an assessment of measurement bias from the results of 120 measurements of a certified reference material (coconut oil BCR CRM458 certified for six PAHs). The method is capable of reliably detecting 26 out of 27 PAHs, at concentration oils, olive pomace oil, sunflower oil and coconut oil. Quantitative results were obtained that are fit for purpose for concentrations from oil, sunflower oil and coconut oil. The reliable detection of 2 microg kg(-1) of PAHs in five additional oils (virgin olive oil, grapeseed oil, toasted sesame oil, olive margarine and palm oil) has been demonstrated. The method failed to produce fit-for-purpose results for the measurement of dibenzo[a,h]pyrene, anthanthrene and cyclopenta[c,d]pyrene. The reason for the failure was the large variation in results. The likely cause was the lack of availability of (13)C isotope internal standards for these PAHs at the time of the study. The protocol has been shown to be fit-for-purpose and is suitable for formal validation by inter-laboratory collaborative study. PMID:17487605

358

Determination of the herbicide fluroxypyr in oil matrices.  

The purpose of this study was to develop a method for the determination of fluroxypyr (4-amino-3,5-dichloro-6-fluro2-pyridyloxyacetic acid) residue in palm oil namely crude palm oil (CPO) and crude palm kernel oil (CPKO). The method involves the extraction of the herbicide from the oil matrix followed by low temperature precipitation and finally quantification of the residues using the high performance liquid chromatography (HPLC). The extraction efficiency of the method was evaluated by conducting recovery studies. The recovery of fluroxypyr from the fortified CPO samples ranged from 78%-111% with the relative values for the coefficient of variation ranging from 1.4 to 8.6%. Furthermore, the recovery of fluroxypyr from the spiked CPKO samples ranged from 91-107% with the relative values for the coefficient of variation ranging from 0.6 to 4.5%. The minimum detection limit of fluroxypyr in CPO and CPKO was 0.05 microg/g. The method was used to determine fluroxypyr residues from the field-treated samples of CPO and CPKO. When fluroxypyr was used for weed control in oil palm plantations no residue was detected in CPO and CPKO irrespective of the sampling interval and the dosage applied at the recommended or double the manufacturer's recommended dosage. PMID:18246505

359

Old oil palm trunk: A promising source of sugars for bioethanol production  

Oil palm trees are replanted at an interval of approximately 25 years because of decreased oil productivity of old trees. Consequently the felled trunks are the enormous amount of biomass resources in the palm oil producing countries such as Malaysia and Indonesia. In this report, we found that the felled oil palm trunk contains large quantity of sap, which accounts for approximately 70% of the whole trunk weight, and that sugars existing in the sap increased remarkably during storage after logging. Total sugar in the sap increased from 83 mg ml{sup -1} to 153 mg ml{sup -1}, the concentration comparable to that of sugar cane juice, after 30 days of storage, followed by the gradual decrease. The sugars contained in the sap were glucose, sucrose, fructose and galactose, all of which are fermentable by ordinary industrial yeast strains. The results indicate that old oil palm trunk becomes a promising source of sugars by proper aging after logging and, thus, its sap can be a good feedstock for bioethanol. (author)

360

Full chain energy analysis of biodiesel production from palm oil in Thailand  

Biodiesel from palm oil has been considered for partial substitution of diesel fuel for transportation in Thailand. The Thai government recently has set up a production target of 8.5 million liters per day of palm oil-based biodiesel by 2011. The aim of this study is to investigate the energy consumption of palm methyl ester (PME) production in Thailand using a life cycle approach compared to other possible oil crops for biodiesel production including jatropha and coconut. The main contributors to the energy use are cultivation, oil production, transesterification and transportation. Taking into account only fossil fuel or petroleum inputs in the production cycle, the energy analysis provides results in favour of PME in Thailand. The net energy balance (NEB) and net energy ratio (NER) of PME and co-products are 100.84 GJ/ha and 3.58, respectively. The NER of PME without co-products is 2.42, which is still higher than one indicating a favourable result. The results are important in selecting an appropriate feedstock for biodiesel production and this study will support policy makers in the energy sector to make informed decisions vis-a-vis promotion of oil palm plantation for biodiesel. This will also support the Thai government in its policy to promote the use of indigenous and renewable sources for transportation fuels. (author)

 
 
 
 
361

Pyrolysis of oil palm empty fruit bunch biomass pellets using multimode microwave irradiation.  

Oil palm empty fruit bunch pellets were subjected to pyrolysis in a multimode microwave (MW) system (1kW and 2.45GHz frequency) with and without the MW absorber, activated carbon. The ratio of biomass to MW absorber not only affected the temperature profiles of the EFB but also pyrolysis products such as bio-oil, char, and gas. The highest bio-oil yield of about 21wt.% was obtained with 25% MW absorber. The bio-oil consisted of phenolic compounds of about 60-70 area% as detected by GC-MS and confirmed by FT-IR analysis. Ball lightning (plasma arc) occurred due to residual palm oil in the EFB biomass without using an MW absorber. The bio-char can be utilized as potential alternative fuel because of its heating value (25MJ/kg). PMID:23026320

362

Emission and performance characteristics of an indirect ignition diesel engine fuelled with waste cooking oil  

Biofuel has so far been backed by government policies in the quest for low carbon fuel in the near future and promises to ensure energy security through partially replacing fossil fuels. At present biodiesel is mostly produced by transesterification reaction from oil-seed feedstock and has to conform to ASTM D6751 specifications. Biodiesel sustainability has sparked debate on the pros and cons of biodiesel and the question of food security. The use of waste cooking oil such as palm and coconut oil in diesel engines is more sustainable if they can perform similarly to ordinary diesel fuel (B0). This paper presents the experimental study carried out to evaluate emission and performance characteristics of a multi-cylinder diesel engine operating on waste cooking oil such as 5% palm oil with 9...

363

Supercritical carbon dioxide extraction of the residual oil from palm kernel cake  

Palm kernel cake contains residual oil that has never been retrieved and it is treated as wastes. In this study, supercritical carbon dioxide was used to separate the oil from the palm kernel matrix. The studied extraction parameters were at the set pressures 27.57, 34.47 and 41.36MPa, temperatures 40-70degreeC and carbon dioxide flow rate between 1 and 3ml/min. The effect of the particle size on the oil yield was examined using different particle size that separated by sieving from 106, 150, 180, 250 and 450mm. The results showed that the highest oil removed was 9.26g oil/100g sample (p<0.05) for the particle 150mm, and under extraction temperature of 70degreeC, pressure 41.36MPa, and carbon dioxide flow rate of 2ml/min. The experimental results indicate that supercritical carbon dioxide ...

364

Pyrolysis of oil palm empty fruit bunch biomass pellets using multimode microwave irradiation  

Oil palm empty fruit bunch pellets were subjected to pyrolysis in a multimode microwave (MW) system (1kW and 2.45GHz frequency) with and without the MW absorber, activated carbon. The ratio of biomass to MW absorber not only affected the temperature profiles of the EFB but also pyrolysis products such as bio-oil, char, and gas. The highest bio-oil yield of about 21wt.% was obtained with 25% MW absorber. The bio-oil consisted of phenolic compounds of about 60-70 area% as detected by GC-MS and confirmed by FT-IR analysis. Ball lightning (plasma arc) occurred due to residual palm oil in the EFB biomass without using an MW absorber. The bio-char can be utilized as potential alternative fuel because of its heating value (25MJ/kg).

365

Direct Determination of MCPD Fatty Acid Esters and Glycidyl Fatty Acid Esters in Vegetable Oils by LC?TOFMS  

Analysis of MCPD esters and glycidyl esters in vegetable oils using the indirect method proposed by the DGF gave inconsistent results when salting out conditions were varied. Subsequent investigation showed that the method was destroying and reforming MCPD during the analysis. An LC time of flight MS method was developed for direct analysis of both MCPD esters and glycidyl esters in vegetable oils. The results of the LC?TOFMS method were compared with the DGF method. The DGF method consistently gave results that were greater than the LC?TOFMS method. The levels of MCPD esters and glycidyl esters found in a variety of vegetable oils are reported. MCPD monoesters were not found in any oil samples. MCPD diesters were found only in samples containing palm oil, and were not present in all palm ...

366

Replacing saturated fat with PUFA-rich (sunflower oil) or MUFA-rich (rapeseed, olive and high-oleic sunflower oil) fats resulted in comparable hypocholesterolemic effects in cholesterol-fed hamsters.  

Recent studies have suggested that monounsaturated fatty acid (MUFA)-rich dietary fats do not have the same plasma cholesterol-lowering effects whereby rapeseed oil was more effective than olive oil. This phenomenon could be explicable by the content of other fatty acids or plant sterols. To further evaluate the effects of different MUFA-rich oils (18:1-rich sunflower oil, rapeseed oil, olive oil) in comparison to polyunsaturated (PUFA)-rich oils (18:2-rich sunflower oil) and saturated fat (palm stearin) on cholesterol and bile acid metabolism, male Syrian golden hamsters were fed semipurified diets containing 5% fat and 0.2% cholesterol for 5 weeks. To test whether oil refining would have an impact on the cholesterol-lowering potential, unrefined and refined varieties of rapeseed and olive oil were included. After 5 weeks, plasma total cholesterol (TC) was highest with palm stearin (10.0 +/- 2.6 mmol/l) while the MUFA- or PUFA-rich fats significantly lowered TC. The lowest TC concentrations were found with refined rapeseed, cold pressed rapeseed and 18:2-rich sunflower oil (6.7 +/- 1.2; 7.1 +/- 0.7 and 7.1 +/- 0.7 mmol/l, respectively), whereas TC was 10-15% higher (not significant) with 18:1-rich sunflower, virgin and refined olive oil. Liver cholesterol concentrations were lowest in hamsters fed palm stearin or 18:2-rich sunflower oil while MUFA-rich fats increased hepatic cholesteryl ester accumulation, especially of cholesteryl oleate. There were no significant differences in the fecal neutral sterol and bile acid excretion. These data demonstrate that MUFA-rich dietary fats, e.g. rapeseed, olive and 18:1-rich sunflower oil, are comparable in their hypocholesterolemic potential and cause similar effects on plasma cholesterol as 18:2-rich sunflower oil in hamsters when the dietary cholesterol intake is moderate. PMID:10545672

367

A candidate auxin-responsive expression marker gene, EgIAA9, for somatic embryogenesis in oil palm (Elaeis guineensis Jacq.)  

This study correlates the potential for somatic embryogenesis in cultured leaf explants of oil palm trees with changes in the expression of hormone-responsive genes. The results show that expression of the putative Aux/IAA gene EgIAA9 is specifically correlated to somatic embryogenesis. A regression model for embryogenesis indicated a predictive R2 value of 63.55?% for this expression marker. Auxin is the plant growth regulator used for induction during the early stages of oil palm tissue culture. Expression of EgIAA9 decreased in response to increasing concentrations of exogenous 2,4-D. EgIAA9 expression profiles in cultured leaf explants from highly embryogenic palms, in embryogenic and non-embryogenic calli, and in response to increasing exogenous 2,4-D, suggested that endogenous auxin ...

368

The shoot apical meristem of oil palm (Elaeis guineensis; Arecaceae): developmental progression and dynamics  

Background and Aims Oil palm, an unbranched perennial monocotyledon, possesses a single shoot apical meristem (SAM), which is responsible for the initiation of the entire above-ground structure of the plant. To compare the palm SAM structure with those of other monocots and to study variations in its structure throughout the life of the plant, its organization was characterized from the embryonic stage to that of the reproductive plant. Methods SAM structure was studied by a combination of stained histological sections, light and confocal microscopy, and serial section-based three-dimensional reconstructions. Key Results The oil palm SAM is characterized by two developmental phases: a juvenile phase with a single tunica-corpus structure displaying a gradual increase in size; and a mature p...

369

Pyrolysis and combustion of oil palm stone and palm kernel cake in fixed-bed reactors.  

The main objective of this research was to investigate the main characteristics of the thermo-chemical conversion of oil palm stone (OPS) and palm kernel cake (PKC). A series of combustion and pyrolysis tests were carried out in two fixed-bed reactors. The effects of heating rate at the temperature of 700 degrees C on the yields and properties of the pyrolysis products were investigated. The results from the combustion experiments showed that the burning rates increased with an increase in the air flow rate. In addition, the FLIC code was used to simulate the combustion of the oil palm stone to investigate the effect of primary air flow on the combustion process. The FLIC modelling results were in good agreement with the experimental data in terms of predicting the temperature profiles along the bed height and the composition of the flue gases. PMID:20153960

370

Solid substrate fermentation for cellulase production using palm kernel cake as a renewable lignocellulosic source in packed-bed bioreactor  

Palm kernel cake (PKC), is an agro-industrial residue created in the palm oil industry, and large quantities of PKC are produced in Malaysia. Sustainable development of the palm oil industry in Malaysia demands an economical technology for the environmentally friendly utilization of PKC in industrial utility systems. This research was carried out to evaluate the use of PKC in the production of cellulase by the cultivation of Aspergillus niger FTCC 5003 in a laboratory packed-bed bioreactor for seven days. A central composite design was used to perform eighteen trials of solid substrate fermentation under selected conditions of incubation temperature, initial moisture content of substrate, and airflow rate. Experimental results showed that a cellulase yield of 244.53 U/g of dry PKC was obta...

371

Industry to Industry By-products Exchange Network towards zero waste in palm oil refining processes  

This paper presents a systematic framework for optimal utilization of by-products generated during crude palm oil refining processes. Three by-products are considered in the supply chain network: soapstock, palm fatty acid distillate (PFAD) and spent bleaching earth (SBE). These by-products, generated from neutralization, deodorization and bleaching processes, are viable feedstocks to other commercial industries such as animal feed, biodiesel, lubricant and soap. The case study is formulated as Mixed Integer Linear Programming (MILP) and integrated into the framework with the objective to maximize the refinery's profit as well as moving towards a conscious mindset of zero waste. This is the first time that such framework is developed and applied for the palm oil industry. The framework is ...

372

Physical properties of palm-based diacylglycerol and palm-based oils in the preparation of shelf-stable margarine  

Abstract Ternary mixtures containing palm olein (POL), palm kernel oil (PKO) and palm oil-based diacylglycerol (PO-DAG) were designed using mixture design. The corresponding physical properties such as solid fat content (SFC) as well as deviation from SFC (SFC) using nuclear magnetic resonance (NMR) and melting and crystallization properties using differential scanning calorimetry (DSC) were studied. Ternary phase behaviour was analysed using isosolid diagrams. The most intensive eutectic interaction among the three binary blends studied was observed along the binary line of PKO/PO-DAG followed by POL/PKO and POL/PO-DAG. The higher SFC did not always lead to the more intensive eutectic behaviour among the blends. Addition of pure POL, 33.33 and 66.66% POL, and no POL to 50/50 mixture of PK...

373

Interesterification of fat blends using a fermented solid with lipolytic activity  

Enzymatic processes to produce interesterified fats and oils with desirable properties to incorporate in margarines and shortenings are currently quite expensive. In the current work, fermented solids, produced by growing Rhizopus oryzae and Rhizopus microsporus on a mixture of sugarcane bagasse and sunflower seed meal, were able to catalyze the interesterification of a mixture of palm stearin, palm kernel oil and a concentrate of triacylglycerols enriched with -3 polyunsaturated fatty acids (''EPAX 4510TG''). The best conditions for the interesterification reaction with the fermented solid produced by R. oryzae, found by response surface methodology, were a temperature of 65^oC, a palm stearin content of 38% and an EPAX content of 15%. Under these conditions, after 24h, the product had a ...

374

Datos bionómicos y descripción de los inmaduros de Calyptocephala gerstaeckeri Boheman (Coleoptera: Chrysomelidae), plaga de la palma aceitera (Elaeis guineensis J.) y de la palma camedor (Chamaedorea elegans Mart.) (Arecaceae) en Tabasco, México/ Bionomics data and descriptions of the immatures of Calyptocephala gerstaeckeri Boheman (Coleoptera: Chrysomelidae), pest of the oil palm (Elaeis guineensis J.) and camedor palm (Chamaedorea elegans Mart.) (Arecaceae) in Tabasco, Mexico  

Abstract in spanish En el presente trabajo se presentan descripciones de la morfología externa del huevo, instares larvales y pupa de Calyptocephala gerstaeckeri Boheman, insecto plaga de la palma aceitera (Elaeis guineensis J.) y de la palma camedor (Chamaedorea elegans Mart.) en el estado de Tabasco, México. Además se aportan algunos datos acerca de la bionomía de esta especie, la cual fue criada en laboratorio sobre plantas jóvenes de palma aceitera. Abstract in english Characters of the external morphology of egg, larval instars and pupae of Calyptocephala gerstaeckeri Boheman, insect pest of oil palm (Elaeis guineensis J.) and camedor palm (Chamaedorea elegans Mart.) in the State of Tabasco, Mexico, are described and illustrated. Some bionomics data are also presented. The specie was reared in the laboratory on young oil palm plants.

375

Kinetic study on pyrolytic process of oil-palm solid waste using two-step consecutive reaction model  

Pyrolysis of oil-palm (Elaeis guineensis Jacq.) shell, a cheap and abundantly available solid waste from palm oil producing process, was carried out using thermogravimetric analysis. The effects of raw material particle size and heating rate on the pyrolytic properties and kinetic parameters (activation energy, frequency factor and reaction order) were investigated. A one-step global model and a two-step consecutive reaction model were used to simulate the pyrolytic process and predict the weight loss during pyrolysis. The two-step model fitted the experimental data much better than the one-step model as the softening effect and formation of an intermediate during the pyrolytic process were taken into account. This two-stage reaction characteristic was confirmed by two obvious maxima in the derivative thermogram for pyrolysis of palm shells under different heating rates. The pyrolytic reactions at the low- and high-temperature regimes were found to be based on a first-order reaction mechanism and a contracting volume mechanism, respectively. (author)

376

Influence of Vegetable Oils on Micellization of Lutein in a Simulated Digestion Model  

Lutein and zeaxanthin are selectively accumulated in the macula of the retina, yet their bioavailability is influenced by various dietary factors. Insights regarding the effects of dietary lipids on lutein micellization that is available for absorption are limited. This study investigated the influence of vegetable oils on the relative efficiency of lutein micellization using in vitro digestion procedure. Lutein dispersed in either olive oil (OO), corn oil (CO), soybean oil (SBO), sunflower oil (SFO), groundnut oil (GNO), rice bran oil (RBO) or palm oil (PO) was subjected to simulated gastric and small intestinal digestion. Results showed that the efficiency of micellization of lutein dispersed in olive oil exceeds the other vegetable oils. The percent lutein micellization was in the order...

377

Single-laboratory validation of a GC/MS method for the determination of 27 polycyclic aromatic hydrocarbons (PAHs) in oils and fats  

A protocol for the measurement of 27 polycyclic aromatic hydrocarbons (PAHs) in vegetable oils by GC/MS has undergone single-laboratory validation. PAHs were measured in three oils (olive pomace, sunflower and coconut oil). Five samples of each oil (one unfortified, and four fortified at concentrations between 2 and 50 µg kg-1) were analysed in replicate (four times in separate runs). Two samples (one unfortified and one fortified at 2 µg kg-1) of five oils (virgin olive oil, grapeseed oil, toasted sesame oil, olive margarine and palm oil) were also analysed. The validation included an assessment of measurement bias from the results of 120 measurements of a certified reference material (coconut oil BCR CRM458 certified for six PAHs). The method is capable of reliably detecting 26...

378

Efectos del Aceite Crudo de Palma en los Lípidos Plasmáticos de Conejos  

Abstract in spanish Conejos de la raza Nueva Zelandia se sometieron a una dieta de conejarina enriquecida con 10% de aceite de palma (grupo experimental) o aceite de maíz (grupo control) por 9 semanas, con lo cual, el contenido de lípidos totales en la dieta de ambos grupos fue igual con variación en el porcentaje de ácidos grasos. Al finalizar el período experimental los conejos fueron anestesiados después de 12 horas de ayuno. Se extrajo la sangre y en el plasma se analizó el porcen (more) taje de ácidos grasos de los TG y ECT, así como el contenido de TG y CT en las fracciones de lipoproteínas. En el grupo experimental se encontró un aumento no significativo de los TG y CT plasmático, así como en los TG y CT de la VLDL. La dieta con aceite crudo de palma contiene mayor relación de ácidos grasos S/P, produciendo diferencias en el contenido de C16:0 y C18:2,n-6 de los TG, sin cambio significativo en los ácidos grasos de los ECT, reflejándose en la concentración de los TG de la VLDL que aumentó de 19,7 a 42,4 mg/dL no significativamente, lo cual se debería considerar en el control dietético de pacientes con hiperlipidemia tipo IV, caracterizada por una elevación en los TG de la VLDL. Abstract in english The Scientific literature does not show a clear effect of a diet rich in palm oil on the plasma content of lipoproteins, triglycerides and cholesterol, some of the reports are in disagreement. The aim of this work was to study the effect of palm oil on triglycerides and cholesterol content on plasma in lipoproteins and fatty acid composition in plasma lipids. The experiment was carreid out in New Zealand male rabbits, fed with a diet 10% (wt/wt) fat content during 9 weeks (more) . The fats used were corn oil (control group) or palm iol (experimental group). The animals were anaesthetized after 12 hour of starvation, fatty acid composition on triglycerides, cholesterol plasmatic and lipoproteins levels were determined. The animals fed with palm oil showed a not significant increase in very low density lipoprotein (VLDL) and plasma triglycerides and cholesterol. Palm oil diet showed high relation of satured/poliinsatured fatty acids and increased the contend of palmitic acid in plasma triglycerides with reduction of linoleic acids in this lipids fraction; However, the cholesteryl ester fatty acids did not change between corn oil and palm oil diet. The non significant increase in plasma triglycerides and VLDL content of the palm oil group must be taken into account in the dietetic control of type IV hiperlipidemic patient.

379

Wear resistance evaluation of palm fatty acid distillate using four-ball tribotester  

Petroleum reserves are declining nowadays while ironically petroleum is a major source of pollution despite many uses. Researchers are in effort to find an alternative to replace petroleum as a lubricant. One of the best replace sources for petroleum is bio-oil. In this paper, a comparative study of friction and wear was carried out using a fourball tester. In this research, Palm Fatty Acid Distillate (PFAD) and Jatropha oil, two well-known oils from the vegetable family oils were compared with Hydraulic mineral oil and commercial mineral Engine oil. All investigated oils in this study are used in industries as lubricants. PFAD is a product from refined crude palm oil. It exists as a light brown solid at room temperature and Jatropa oil is produced from the seeds of the Jatropha cruces, a plant that grows in marginal lands. For the wear test, the experimental research condition was comparing four kind of oils with ASTM condition in which the load applied was 392N. The sliding speed was 1200rpm under the lubricant temperature of 75 degree Celsius. The experiment was run for 3600 seconds. The experimental results demonstrated that the PFAD and Jatropha oils exhibited better performance in term of friction and wear compared to Hydraulic and Engine mineral oils.

380

Gasifier selection, design and gasification of oil palm fronds with preheated and unheated gasifying air.  

Oil palm frond biomass is abundantly available in Malaysia, but underutilized. In this study, gasifiers were evaluated based on the available literature data and downdraft gasifiers were found to be the best option for the study of oil palm fronds gasification. A downdraft gasifier was constructed with a novel height adjustment mechanism for changing the position of gasifying air and steam inlet. The oil palm fronds gasification results showed that preheating the gasifying air improved the volumetric percentage of H(2) from 8.47% to 10.53%, CO from 22.87% to 24.94%, CH(4) from 2.02% to 2.03%, and higher heating value from 4.66 to 5.31MJ/Nm(3) of the syngas. In general, the results of the current study demonstrated that oil palm fronds can be used as an alternative energy source in the energy diversification plan of Malaysia through gasification, along with, the resulting syngas quality can be improved by preheating the gasifying air. PMID:23073112

 
 
 
 
381

Quality characteristics and oxidative stability of date seed oil during storage  

Studies were conducted on some quality characteristics of date seed oil from two date palm cultivars (Phoenix dactylifera L.): Deglet Nour and Allig. The following values were obtained for Deglet Nour and Allig cultivars respectively: unsaponifiable matter 8.92-7.76%, iodine value 45.49-44.08, total...

382

75 FR 16113 - Bacillus subtilis; Registration Review Final Decision; Notice of Availability  

...Fusarium and is also used to promote more effective nodulation by nitrogen-fixing bacteria to improve yields. It is used as a seed and...seed crops, oil palm, okra, peanuts, peppers, pome fruit, rice, root/tuber crops, silage crops, stone fruits,...

383

PARTIAL PURIFICATION AND PROPERTIES OF LIPASE FROM GERMINATING SEEDS OF JATROPHA CURCAS L.  

The lipase present in the seeds of Jatropha curcas L. was isolated, partially purified, and some of its properties studied. Lipase activity was detected in both the dormant and germinating seeds. The lipase hydrolysed palm kernel, coconut, and olive oils at comparable rates (approximately 5 µg FFA...

384

Jatropha-Palm biodiesel blends: An optimum mix for Asia  

Biodiesel, an alternative renewable fuel made from transesterification of vegetable oil with alcohol, is becoming more readily available for use in blends with conventional diesel fuel for transportation applications. Soybean and Rapeseed are common feedstocks for Biodiesel production in USA and Europe, respectively. However, Asian countries are not self sufficient in edible oil and exploring non-edible seed oils, like Jatropha and Pongamia as biodiesel raw materials. However there is a gestation period of few years before these crops start yielding seeds and oil. On the other hand, South Eastern countries like Malaysia and Thailand have surplus Palm crops. But due to substantial amount of saturated fats in Palm, the Palm biodiesel has poor low temperature properties. In order to exploit the proximity of South Asian and South-East Asian countries, blends of Jatropha and Palm biodiesel have been examined to study their physico-chemical properties and to get an optimum mix of them to achieve better low temperature properties, with improved oxidation stability. 15 refs., 6 figs., 2t abs.

385

Physical Properties of Normal Grade Biodiesel and Winter Grade Biodiesel  

In this study, optical and thermal properties of normal grade and winter grade palm oil biodiesel were investigated. Surface Plasmon Resonance and Photopyroelectric technique were used to evaluate the samples. The dispersion curve and thermal diffusivity were obtained. Consequently, the variation of...

386

Drainage and land use impacts on changes in selected peat properties and peat degradation in West Kalimantan Province, Indonesia  

Degradation of tropical peats is a global concern due to large Carbon emission and loss of biodiversity. The degradation of tropical peats usually starts when the government drains and clears peat forests into open peats used for food crops, oil palm and industrial timber plantations. Major properties of tropical peat forests are high in Water Contents (WC), Loss on Ignition (LOI) and Total Organic Carbon (TOC), and low in peat pH, Dry Bulk Density (DBD), and Total Nitrogen (TN). In this study, we investigated impacts of drainage and land use change on these properties. We collected peat samples from peat forests, logged over peat forest, industrial timber plantation, community agriculture, and oil palms. We used independent t-tests and oneway ANOVA to analyze mean differences of the research variables. We found that peat pH, DBD, and TN tend to increase. A significant decrease of C/N ratio in oil palm and agriculture sites importantly denotes a high rate of peat decompositions. Water contents, LOI, and TOC are relatively constants. We suggest that changes in pH, DBD, TN and atomic C/N ratio are important indicators for assessing tropical peat degradation. We infer that land use change from tropical peat forests into cleared and drained peats used for intensive timber harvesting, oil palms and industrial timber plantations in Indonesia has greatly degraded major ecological function of tropical peats as Carbon storage.

387

The legitimacy of biofuel certification  

The biofuel boom is placing enormous demands on existing cropping systems, with the most crucial consequences in the agri-food sector. The biofuel industry is responding by initiating private governance and certification. The Roundtable on Sustainable Palm Oil (RSPO) and the Cramer Commission, among...

388

The legitimacy of biofuel certification  

Abstract The biofuel boom is placing enormous demands on existing cropping systems, with the most crucial consequences in the agri-food sector. The biofuel industry is responding by initiating private governance and certification. The Roundtable on Sustainable Palm Oil (RSPO) and the Cramer ...

389

(97%) with nutrients (80%) plus brackish waters and nutrients ... - Nasa  

Nov 20, 2008 ... 80% Jet-A: 20% processed babassu nut-coconut oils (Parente). Ground tests to 60JetA:40biojet no discernable problems. ? Continental – GE plan CFM56–7B biofuel 737 test (2009) .... In a nut shell, here is the basis for our interest in Halophytes and ... Common crop oilseed [ soybean, palm, coconut etc) ...

390

t  

study comparing the RHOiV kernel function method and the doublet-lattice method are ...... 86-0736, West Palm. Beach, Florida, March ...... for NACA 64A010A air!oil at. M = 0.78 and MBB-A3 airfoil at. M = 0.79. (Bland and Edwards , Ref. 114) ...

391

HARVESTING TECHNIQUES FOR CUPHEA, A NEW OILSEED CROP  

Cuphea is a potential alternative oilseed crop that produces medium chain-length fatty acids (capric and lauric acids). These fatty acids are feedstocks for non-food products, such as lubricants and detergents, all of which currently are derived from imported coconut and palm kernel oils. Cuphea gro...

392

HERBICIDE TOLERANCE IN CUPHEA: A NEW OILSEED CROP  

Cuphea is a potential alternative oilseed crop that produces medium chain-length fatty acids (capric and lauric acids). These fatty acids are feedstocks for non-food products such as lubricants and detergents, which currently are imported in the form of coconut and palm kernel oils. Cuphea grows wel...

393

Suspended sediment fluxes in an Indonesian River draining a rainforested basin subject to land cover change  

Forest clearing for reasons of timber production, open pit mining and the establishment of oil palm plantations generally results in excessively high sediment loads in the tropics. The increasing sediment fluxes pose a threat to coastal marine ecosystems such as coral reefs. This study presents obse...

394

A comparison of used cooking oils: a very heterogeneous feedstock for biodiesel  

The increased interest in and use of biodiesel renders the availability of a sufficient supply of feedstock ever more urgent. While commodity vegetable oils such as soybean, rapeseed (canola), palm and sunflower may be seen as "classical" biodiesel feedstocks, additional feedstocks are needed to me...

395

The effect of fat on calcium absorption from a mixed meal in normal subjects, patients with malabsorptive disease, and patients with a partial gastrectomy  

The absorption of 47Ca Cl2 taken with a milk and porridge meal was measured in normal subjects, patients with a partial gastrectomy, and patients with malabsorption. The addition of palm oil to the meal depressed calcium absorption, whereas the addition of medium-chain triglyceride had no effect. Th...

396

Evaluation of oil palm research and the dissemination of its results in Nigeria  

This dissertation evaluates public investment in oil palm research and the dissemination of research results in Nigeria using the economic surplus technique adapted to suit the specific setting in which these activities are carried out. The issues raised include: (1) development of appropriate test of investment effectiveness suitable for appraising public investment in hybrid palm research and extension; (2) specification and econometric estimation of supply and demand functions for oil and kernels; (3) computation of the social returns to research; (4) sensitivity of returns to variations in extraction rates for both oil and kernels; (5) sensitivity of returns to research to types of supply shift; and (6) isolation of qualitative implications for public policy with respect to maximum exploitation of the economic opportunities offered by the knowledge generated by oil palm research. The author found that investments in hybrid palm research and extension are socially profitable under a wide range of conditions. The returns to research and related activities were computed and reported by periods according to the data situation and accrued, expected and total benefits over the investment.

397

Automated Instrumentation for Continuous Monitoring of the ...  

[tlodcls. It, is well IItldcrstcmd that cficlcctric co[lsta[lt del)('[ids dircctl:. oIl \\'egc- tation \\vater content. ... 'llllc key to exploiting raclar as an instru- ment- for ... larger. Monocotylous trees such as palms and yucca have evenly clistributecl units ...

398

Serving the Marshall Space  

Jul 11, 2002 ... Technologies Corp., of West Palm Beach, Fla.; and the Aerojet missile and space propulsion .... was a first step in the exploitation of high-power ion ..... taught farm safety classes at Standard Oil, was a U.S. Army veteran and ...

399

nasa johnson space center oral history project oral history transcript  

Dec 11, 2007 ... in the palm of your hand and bring it back close to you and take it home with you. Take it home ...... Got involved in the oil industry. ..... all our money, all our eggs, all our technology, all our resources in space exploitation at the ...

400

Solid-state light sources getting smart  

RAPD is a simple dominant marker system widely used in biology. Effectiveness of RAPD can be improved by selecting and redesigning primers whose priming sites occur in target sequence(s) of gene or organism at optimum distance. We developed software that uses sequences of random decamer primers and nucleotide sequence(s) as two input files. It locates the priming sites in input sequences and generates output files listing frequency and distance between priming sites. When the priming sites of a single primer occur more than once in a sequence with a distance of 200 to 2000?bp, the software also designs pairs of iSCAR primers. An input of 387 RAPD primers and 42,432 expressed sequences of oil palm are used as test. Wet-lab PCR results from a publication that used the same set of primers were compared with software output on priming sites. In the test sequences of oil palm covering 1.4% of genome, we found that at least 60% the primers chosen using software are sure of giving PCR amplification. We designed 641 iSCAR primers suitable for amplification of oil palm DNA. The software successfully predicted 92% (67 out of 73) of published polymorphic RAPD primers in oil palm. PMID:15919985

 
 
 
 
401

Mutual Solubility Study in Supercritical Fluid Extraction of Tocopherols from Crude Palm Oil Using CO2 Solvent  

In this article, the mutual solubility of tocopherols from crude palm oil was studied using carbon dioxide as a solvent at the temperatures of 80, 100 and 120 °C. Each sample from the phase equilibrium unit contained two parts. The liquid part was analyzed by gas chromatography (GC) in order to meas...

402

Palm oil thorn-induced squamous cell carcinoma with underlying burns scar.  

Marjolin's ulcers are malignancies that arise from previously traumatised, chronically inflamed or scarred skin. We present a case with childhood burns, who had repeated irritation of his forearm skin with palm oil thorns that eventually led to malignant change. PMID:22865804

403

Large estragole fluxes from oil palms in Borneo  

During two field campaigns (OP3 and ACES), which ran in Borneo in 2008, we measured large emissions of estragole in ambient air above oil palm canopies flower enclosures. However, we did not detect this compound at a nearby rainforest. Estragole is a known attractant of the Afric...

404

An Empirical Analysis Of Asymmetric Duopoly In The Indonesian Crude Palm Oil Industry  

The apparent increase in market concentration and vertical integration in the Indonesian crude palm oil (CPO) industry has led to concerns about the presence of market power. For the Indonesian CPO industry, such concerns attract more attention because of the importance of this sector to the Indones...

405

Pemanfaatan Beberapa Hasil Sampingan Tanaman Kelapa Sawit, Padi, dan Jagung terhadap Pertumbuhan dan IOFC Domba Lokal Betina Selama Penggemukan (The Utilization Several Feed Base on Oil Palm, Paddy and Corn by Product to Growth and Income Over Feed Cost of Female Local Sheep During Fattening)  

The objective of this research was to know the response of the oil palm, paddy and corn by product to growth and income over feed cost of female local sheep since the research done. The method of this research was using completely randomized design (CRD) with four treatment and five replication, su...

406

Red palm oil suppresses the formation of azoxymethane (AOM) induced aberrant crypt foci (ACF) in Fisher 344 male rats.  

Dietary modulation of cancer & cancer biomarkersDietary item or component studied: Red palm oil (RPO)Outcome studied: aberrant crypt foci (ACF)Study type: male Fisher 344 rats Tissue/biological material/sample size: colonMode of exposure: dietaryImpact on outcome (including dose-response): Numbers o...

407

Lee Solid  

palm trees and all that stuff I thought that sounded pretty good even though I didn ?t .... was going on in the company; I knew that we were building engines for the ...... Rocco that caused me to burn the midnight oil and learn as much as I could, ...

408

Slice of History: Scanning Electron Microscope - Blog - NASA Jet ...  

Jun 4, 2012 ... In September 1970, construction began on building 264, the Systems .... one that makes detergent bubbles and thin slicks of oil on water show colors. .... that small angle is comparable to the width of your palm at arm's length, ...

409

Posts Tagged 'nasajpl' - Blog - NASA Jet Propulsion Laboratory ...  

Jun 4, 2012 ... In September 1970, construction began on building 264, the Systems .... one that makes detergent bubbles and thin slicks of oil on water show colors. .... that small angle is comparable to the width of your palm at arm's length, ...

410

Autonomous dexterous end-effectors for space robotics  

about an axis normal to the palm, to bring it into opposition ... Oil!(-',. '_'"I p_r,L-". BLACK ANi_ V_"_-,_iT_I,-_i.._OiOGRAPH. Figure. 1. Belgrade/USC .... Building a Generic. Architecture for Robot. Hand Control,. Proc 1988 IEEE. Conference ...

411

Publications  

Oct 25, 2012 ... Roles of urban tree canopy and buildings in urban heat island ... Air quality over the Canadian oil sands: A first assessment using satellite observations Geophys. ... doi:10.1029/2011JD017006; Melfi, S.H., and S. Palm (2012).

412

Blog - NASA Jet Propulsion Laboratory » jpl  

Jun 4, 2012 ... In September 1970, construction began on building 264, the Systems .... one that makes detergent bubbles and thin slicks of oil on water show colors. .... that small angle is comparable to the width of your palm at arm's length, ...

413

NASA - 2010 Kennedy News Releases  

NASA and the LEGO Group Partner to Inspire Children to Build and Explore the Future .... from the effects of the BP Deepwater Horizon oil spill in the Gulf of Mexico. .... 04.12.10 - Skyler Mondell of West Palm Beach, Fla., has spent almost four ...

414

Saving Sumatra's species: Combining economics and ecology to define an efficient and self-sustaining program for inducing conservation within oil palm plantations  

The paper presents results from a four year study of the economic and ecological potential for implementation of conservation schemes within the rapidly expanding palm oil plantations of South East Asia. Unparalleled access to financial records combined with a highly intensive ecological data gather...

415

Suspended sediment fluxes in an Indonesian river draining a rainforested basin subject to land cover change  

Forest clearing for reasons of timber production, open pit mining and the establishment of oil palm plantations generally results in excessively high sediment loads in the tropics. The increasing sediment fluxes pose a threat to coastal marine ecosystems such as coral reefs. This study presents obse...

416

Development and industrialization of extraction technology for natural carotene from palm oil; Palm yu kara no carotene kaishu gijutsu no kaihatsu to kogyoka  

Described herein is the technology which leads to the world`s first extraction of natural carotene from palm oil on a commercial scale. It is difficult to directly extract carotene from palm oil, because of their proximity in solubility parameter. Extraction of carotene was suggested by chance while the authors were studying separation of palm oil by a membrane process and others, after crude palm oil was ester-exchanged with methanol to form the methyl ester. The ester is emulsified, when it is stirred together with methanol and a small quantity of water. When allowed to stand, the emulsion is separated into two phases, carotene being selectively concentrated in the lower phase. The concentrated carotene is treated by molecular distillation to remove the ester, and then purified by chromatography. The upper phase containing methanol is reused for the extraction process, whereas the carotene-deprived lower phase is used as a stock for producing detergents. The basic study began in 1982, pilot study in 1986, and commercial production in 1991. 3 figs., 1 tab.

417

Factors associated with the allocation of carbohydrates to bunch dry matter production in oil palm.  

This thesis reports on the factors relevant to the allocation of assimilates to oil palm bunch dry matter (DM) production, based on an extensive set of growth and yield records from experiments in Papua New Guinea and Malaysia.Basically, assimilates from gross assimilation of the canopy are first us...

418

Ecological modernization in selected Malaysian industrial sectors: political modernization and sector variations  

The aim of this paper is to understand the differences in environmental performance of palm oil versus textile and apparel production chains in Malaysia by applying ecological modernization theory via substantive quantitative testing. Ecological modernization is tested via four hypotheses, namely po...

419

Study on the effective utilization of palm oil (Part 1). Survey of catalysts for oxidative cleavage of palm stearin into mono and dibasic acids with middle carbon chains  

Production of palm oil in Malaysia increases annually and it is estimated that the production will reach 6 million tons in 1990. Palm stearin which constitutes 20% or more of palm oil is not suitable for the food production, but if it is successfully converted into mono and dibasic acids with middle carbon chains, a big potential demand as excellent lubricating oil is expected. Chemical Engineering Institute, Agency of Industrial Science and Technology studied this matter jointly with Malaysian Institute of Palm Oil. Various metal (II) ion-exchanged zeolites which were considered to be effective catalysts for the above conversion were screened and from the analytical results utilizing signal strength of carboxyl proton, it was found that several catalysts were effective for the formation of carboxylic acids. Furthermore, it was revealed that Mn (II) ion-exchanged zeolite 5A and Co(II)-Cu(II) ion-exchanged zeolite Y were the catalysts suitable for the objective of this study, but a study for finding out the conditions to obtain high conversion ratio is required. (4 tabs, 28 refs)

420

A quantitative methodology to test the ecological modernization theory (EMT): The first steps for the Palm Oil Production Chain in Malaysia  

The aim of this paper is to develop a quantitative methodology to test the Ecological Modernization Theory (EMT). This is a pioneering research as the EMT has not been quantitatively tested before. The sector selected is the palm oil production chain in Malaysia. Background information is provided i...

 
 
 
 
421

Improving ruminal degradability of oil palm fronds using white rot fungi  

The use of oil palm fronds (OPF) in livestock production is limited as up to 0.20 of their dry biomass is lignin. White rot fungi (WRF) are very effective basidiomycetes for biological pre-treatment as they degrade lignin extensively. Ten WRF were screened for their potential to increase OPF digesti...

422

Kinetics of Autoxidation of an Oil Extract from Terminalia catappa  

Soxhlet extractor was used in the extraction of oil from milled seeds of Terminalia catappa using petroleum ether (40-60°). The optimal oil yield was 56.71±1.66% with a viscosity of 40.79±1.05 centipoises. Other parameters of the oil were found as follows; specific gravity-0.9248, refractive index-1...

423

Composition and physical properties of arugula, shepherd's purse, and upland cress oils  

The fatty acid, tocopherol and phytosterol profiles of arugula [AO; Eruca vesicaria (L.) Cav. subsp. sativa (Mill.) Thell.], upland cress [UCO; Barbarea verna (Mill.) Asch.], and shepherd's purse [SPO; Capsella bursa-pastoris (L.) Medik.] oils are reported, along with their physical properties. The...

424

Recovery of bitumen from bituminous oil-in-water emulsions  

Bitumen recovery from a tar sands emulsion or other bituminous oil-in-water emulsion is increased by milling the emulsion for a time sufficient to cause a bitumen-rich liquid fraction to rise to the surface, and separating such fraction. Addition of water to the starting emulsion or during milling further enhances the recovery of bitumen.

425

Cost optimization of stirred ball mill grinding  

On going research at the University of Alabama has shown that stirred ball mill grinding is the highest cost unit operation in the beneficiation of Eastern Oil Shales. Minimization of that cost is critical if oils derived by beneficiation and hydroretorting of Eastern shales are to become an economic alternative to conventional crude oils. Cost optimization of stirred ball milling is a substantially different problem than optimizing a conventional (tumbling) mill operation. For conventional mills minimum cost is virtually synonymous with minimum energy consumption. Because the technology is mature and well understood, the operator can predictably optimize within a very narrow range of operating conditions. In contrast, stirred ball milling offers the operator several more ``degrees of freedom`` in selecting operating conditions. An example is the selection of rotor speed. In general, lower speeds result in lower energy consumption per ton of material ground but at the cost of reduced mill capacity per unit volume. Because stirred ball mills have a high capital cost per unit volume the trade off between energy consumption and capacity becomes critical. This paper presents a generalized total cost mode for stirred ball milling and examines data generated in the grinding of oil shales in terms of the model. The paper also discuss the role of the cost model in guiding future research in grinding circuit optimization.

426

Chemical interesterification of blends of palm stearin, coconut oil, and canola oil: physicochemical properties.  

trans-Free interesterified fat was produced for possible usage as a margarine. Palm stearin, coconut oil, and canola oil were used as substrates for chemical interesterification. The main aim of the present study was to evaluate the physicochemical properties of blends of palm stearin, coconut oil, and canola oil submitted to chemical interesterification using sodium methoxide as the catalyst. The original and interesterified blends were examined for fatty acid composition, softening and melting points, solid fat content, and consistency. Chemical interesterification reduced softening and melting points, consistency, and solid fat content. The interesterified fats showed desirable physicochemical properties for possible use as a margarine. Therefore, our result suggested that the interesterified fat without trans-fatty acids could be used as an alternative to partially hydrogenated fat. PMID:22229347

427

Preparation and Application of Trans-free Vanaspati Substitute in Selected Indian Traditional Foods  

Speciality fat with no trans fatty acids prepared by blending palm oil fraction with rice bran oil showed melting characteristics similar to those of commercial vanaspati. This fat is used in preparation of Indian traditional foods such as Parota, Mysorepak, Sohan papdi and Badusha substituting vanaspati and the quality was evaluated in comparison with those prepared using vanaspati. The appearance, texture and sensory analyses of all the products prepared with speciality fat were similar and comparable with those prepared with vanaspati. The products prepared with vanaspati and commercial samples contain trans fatty acids (0.3 ? 6.3%), whereas those prepared with speciality fat did not contain any trans fatty acids. The study therefore revealed that the trans-free speciality fat prepared using palm oil fraction and rice bran oil could be used as vanaspati (trans fatty acids 17.7%) substitute to prepare a range of traditional foods and thereby improve nutritional quality.   

428

Production of biofuel from waste cooking palm oil using nanocrystalline zeolite as catalyst: Process optimization studies  

The catalytic cracking of waste cooking palm oil to biofuel was studied over different types of nano-crystalline zeolite catalysts in a fixed bed reactor. The effect of reaction temperature (400-500degreeC), catalyst-to-oil ratio (6-14) and catalyst pore size of different nanocrystalline zeolites (0.54-0.80nm) were studied over the conversion of waste cooking palm oil, yields of Organic Liquid Product (OLP) and gasoline fraction in the OLP following central composite design (CCD). The response surface methodology was used to determine the optimum value of the operating variables for maximum conversion as well as maximum yield of OLP and gasoline fraction, respectively. The optimum reaction temperature of 458degreeC with oil/catalyst ratio=6 over the nanocrystalline zeolite Y with pore size...

429

Potential of waste palm cooking oil for catalyst-free biodiesel production  

Disposal of waste palm cooking oil (WPCO) via an environmental-friendly route is of major importance in the quest for sustainable development. In this study, WPCO was utilized instead of refined vegetable oils as the source of triglycerides for biodiesel production. WPCO contains several impurities, such as water and free fatty acids, which limit its application in catalytic transesterification processes. Consequently, a catalyst-free process using supercritical methanol was employed to investigate the potential of WPCO as an economical feedstock for biodiesel production. The parameters that influence the reaction, including reaction time, temperature and the molar ratio of alcohol to oil, were investigated. For comparison purposes, refined palm oil (RPO) was also subjected to supercritica...

430

Regeneration and Reutilization of Oil-Laden Spent Bleaching Clay via in Situ Transesterification and Calcination  

Landfill bound waste from the oil palm industry, spent bleaching clay (SBC) containing significant amounts of adsorbed crude palm oil (CPO) has the potential to be used for biodiesel production. In this study, SBC was subjected to ultrasound-aided in situ transesterification with a co-solvent to convert the oil into methyl esters (biodiesel). Optimized reaction conditions used were 5.4?wt% KOH, methanol to oil mass ratio of 5.9:1 and 1:1 mass ratio of co-solvent (petroleum ether or ethyl methyl ketone) to SBC. The remaining bleaching clay was calcined at 500??C for 30?min and reutilized for bleaching. Absence of ?CH absorption peaks in the FTIR and TGA-FTIR analysis of regenerated clays shows the regeneration efficiency of the method. In situ transesterification and heat regeneration helpe...

431

Effect of Moringa Oleifera Oil Blending on Fractional Crystallization Behavior of Palm Oil  

The objective of this study was to see the effect of Moringa oleifera oil blending on the fractional crystallization behavior of palm oil. Palm oil blended with Moringa oleifera oil at 20% (w/w) was subjected to crystallization using a dry process at 21 and 18°C and a solvent process at 15 and 10°C. After recording the quantitative recoveries of the liquid and solid fractions, their fatty acid and triacylglycerol compositions, and the thermal profiles were determined by using gas liquid chromatography, high performance liquid chromatography, and differential scanning calorimetry, respectively. Results showed that the yield recoveries of liquid fractions under solvent-assisted crystallization were higher than those obtained by dry-crystallization conditions. Almost all of the liqu...

432

Biooxidation of fatty acid distillates to dibasic acids by a mutant of Candida tropicalis.  

Fatty acid distillates (FADs) produced during physical refining of vegetable oil contains large amount of free fatty acid. A mutant of Candida tropicalis (M20) obtained after several stages of UV mutation are utilized to produce dicarboxylic acids (DCAs) from the fatty acid distillates of rice bran, soybean, coconut, palm kernel and palm oil. Initially, fermentation study was carried out in shake flasks for 144 h. Products were isolated and identified by GLC analysis. Finally, fermentation was carried out in a 2 L jar fermenter, which yielded 62 g/L and 48 g/L of total dibasic acids from rice bran oil fatty acid distillate and coconut oil fatty acid distillate respectively. FADs can be effectively utilized to produce DCAs of various chain lengths by biooxidation process. PMID:17693693

433

Melting and Solidification Properties of Palm-Based Diacylglycerol, Palm Kernel Olein, and Sunflower Oil in the Preparation of Palm-Based Diacylglycerol-Enriched Soft Tub Margarine  

Many studies have been conducted to deliver more healthy alternatives to full fat products. Incorporation of a high proportion of diacylglycerol oil as a functional oil into the plastic fat products through development of blend formulation is considered as one such attempt. Ternary mixtures containing sunflower oil (SFO), palm kernel olein (PKOL), and palm-based diacylglycerol oil (POL-DAG) with certain proportions were designed using mixture design. The corresponding physical properties such as solid fat content (SFC) as well as deviation from SFC (DSFC) using nuclear magnetic resonance and melting and crystallization properties using differential scanning calorimetry were studied. Ternary phase behavior was analyzed with isosolid diagrams. The eutectic behavior was observed along the bin...

434

Prediction of the identity of fats and oils by their fatty acid, triacylglycerol and volatile compositions using PLS-DA  

The identity of a variety of animal fats and vegetable oils was predicted by three different analytical techniques with help of chemometrics. The sample material of animal origin consisted of milk fat, cow fat, pig fat and poultry fat. The vegetable oils comprised coconut, palm and palm kernel oils. Each product group was composed of at least eight samples of independent batches. For the identity prediction of the fats/oils several (combinations of) datasets were used: absolute and relative measurements of fatty acid compositions, of triacylglycerol compositions, and of combined fatty acid and triacylglycerol compositions. Volatile organic compound compositions were used as well. Fatty acid and triacylglycerol compositions were determined by gas chromatography. Fingerprints of volatile com...

435

Some Aspects of Palm Oil Bleaching with Activated Plantain Peel Ash  

The present study seeks to investigate the bleaching of palm oil with activated plantain peel ash (APPA). Concentrations of ?-carotene, iron, copper, lead, and phosphorus in the crude (unbleached) and bleached palm oil were evaluated. The peroxide value, anisidine value, acidity and colour of the oils were also determined. The objectives were to assess the bleaching performance of the APPA, compare the performance of APPA with that of a commercial natural earth (Pure-Flo Neutral B-80) and investigate the effects of particle size of APPA and APPA/oil ratio on the bleaching performance of APPA. The results indicated that APPA significantly decreased all the investigated characteristics apart from acidity. Results also indicated that Pure-Flo Neutral B-80 slightly performed better than APPA under the same experimental conditions.   

436

Mechanistic study on spraying of blended biodiesel using phase Doppler anemometry  

Droplet size and dynamics of blended palm oil-based fatty acid methyl ester (FAME) and diesel oil spray were mechanistically investigated using a phase Doppler anemometry. A two-fluid atomizer was applied for dispersing viscous blends of blended biodiesel oil with designated flow rates. It was experimentally found that the atomizer could generate a spray with large droplets with Sauter mean diameters of ca. 30 {mu}m at low air injection pressure. Such large droplets traveled with a low velocity along their trajectory after emerging from the nozzle tip. The viscosity of blended biodiesel could significantly affect the atomizing process, resulting in the controlled droplet size distribution. Blended biodiesel with a certain fraction of palm oil-based FAME would be consistently atomized owing to its low viscosity. However, the viscosity could exert only a small effect on the droplet velocity profile with the air injection pressure higher than 0.2 MPa. (author)

437

Recovering renewable energy from palm oil waste and biogas  

Malaysia is endowed with abundant supplies of non-renewable energy resources, especially oil and gas. However, its current oil and gas reserves are expected to be depleted within 17 and 37 years, respectively. With the future prospect of energy prices likely to soar when the level of use of these non-renewable fossil fuel resources exceeds their threshold capacity, there is an urgent need for Malaysia to optimize the use of its huge quantities of palm oil biomass wastes as a renewable energy source. Against this background, this article aims to empirically and quantitatively analyze the potential of recovering renewable energy from palm oil wastes, which contributes substantially to harnessing a sustainable resource management system in Malaysia (Author)

438

Biodiesel production from palm oil via heterogeneous transesterification  

This paper presents the study of the transesterification of palm oil via heterogeneous process using montmorillonite KSF as heterogeneous catalyst. This study was carried out using a design of experiment (DOE), specifically response surface methodology (RSM) based on four-variable central composite design (CCD) with {alpha} (alpha) = 2. The transesterification process variables were reaction temperature, x{sub 1} (50-190 C), reaction period, x{sub 2} (60-300 min), methanol/oil ratio, x{sub 3} (4-12 mol mol{sup -1}) and amount of catalyst, x{sub 4} (1-5 wt%). It was found that the yield of palm oil fatty acid methyl esters (FAME) could reach up to 79.6% using the following reaction conditions: reaction temperature of 190 C, reaction period at 180 min, ratio of methanol/oil at 8:1 mol mol{sup -1} and amount of catalyst at 3%. (author)

439

Long term activity of modified ZnO nanoparticles for transesterification  

Biodiesel can be produced by the transesterification of natural oils with methanol using modified ZnO nanoparticles as catalyst. Crude algae oil, corn oil from DDGs, crude palm oil, crude soybean oil, crude coconut oil, waste cooking oil, food-grade soybean oil and food-grade soybean oil with 3% water and 5% FFA addition were converted into FAME within 3h using this new catalyst. The ZnO nanoparticles were reused 17 times without any activity loss in a batch stirred reactor and the average yield of FAME was around 93.7%. ZnO nanoparticles were used continuously for 70days in a fix bed continuous reactor and the average yield of FAME was around 92.3%. XRD, ICP, TEM and HRTEM were used to characterize the long term used catalyst structure. Results show that this catalyst is a mixture of wurt...

440

21 CFR 582.20 - Essential oils, oleoresins (solvent-free), and natural extractives (including distillates).  

... L. Bay leaves Laurus nobilis L. Bay (myrcia oil) Pimenta racemosa (Mill.) J. W. Moore. Bergamot (bergamot orange) Citrus aurantium L. subsp. bergamia Wright et Arn. Bitter almond (free from prussic acid)...

 
 
 
 
441

Water reuse from oil mill industries. Reutilizacion de aguas en las industrias de extraccion de aceite de oliva  

The reuse of oil mill wastewater using a two stages flash evaporator has been studied. The results have been compared between three phases continuous centrifugation and the two phases p