WorldWideScience
1

AN AES/XPS STUDY OF THE CHEMISTRY OF PALLADIUM ...  

Science.gov (United States)

... AT THE INTERFACE, A THIN OXIDE LAYER IS OBSERVED ALONG WITH POSSIBLE PALLADIUM SILICIDES. PALLADIUM ...

1981-02-01

2

7 - NASA Technical Reports Server  

Science.gov (United States)

... where the total palladium concentration equals that of silicon, the concentrations of palladium associated with various palladium silicides (Pd(x)Si , ...

3

Detecting Airborne Mercury by Use of Palladium Chloride Detecting ...  

Science.gov (United States)

Palladium chloride films have been found to be useful as ... when suitably prepared palladium chlo- ride films are exposed ... Like the palladium chloride ( PdCl2) ...

4

Origin of water salinity in the coastal Sarafand aquifer (South-Lebanon)  

International Nuclear Information System (INIS)

Author.The geochemical and isotopic study, based on the analysis of twenty water samples from well in the coastal plain of Sarafand (South-Lebanon), permit to eliminate the hypothesis of marine intrusion in this aquifer. The increase of salinity observed in certain wells is due to the contamination of cretaceous aquifer water by the quaternary formations. The two poles of mixing are respectively characterized: by weak tritium contents (between 2 and 3 UT) and a value of stable isotopes (-5,9<0,18<-5,5) corresponding to the appearance of cretaceous formation area; by the high tritium contents and enrichment relative to heavy isotope in the mineralized water of superficial formations. On the other hand, the isotope contents permit the set a rapid renewal of the cretaceous aquifer water due to quick circulation in the Karstic system

5

Determination of the radon diffusion coefficient and radon exhalation rate in Moroccan quaternary samples using the SSNTD technique  

International Nuclear Information System (INIS)

Measurements have been made of radon ("2"2"2Rn), release from diverse quaternary samples collected from different sediment deposits in the Errachidia and Beni-Mellal areas (Morocco). The radon diffusion coefficient as one of some important parameters of radon transport in the soil has been measured using solid state nuclear track detectors (SSNTD). Radon #alpha#-activity, uranium content and radon exhalation rate have been determined in the studied samples. Uranium concentrations were found to vary from 0.14 to 9.52 ppm whereas the radon exhalation rate varied from 0.003 to 0.145 Bq x m"-"2 x h"-"1. A positive correlation has been found between radon exhalation rate and uranium content in the studied samples. The average radon diffusion coefficients were found to vary from (1.26 #+-# 0.09) x 10"-"6 m"2 x s"-"1 to (4.3 #+-# 0.36) x 10"-"6 m"2 x s"-"1. Furthermore, the correlation between "2"2"2Rn diffusion coefficient and ...

2003-06-01

6

Open-system Behavior during Pluton-Wall-rock Interaction as Constrained from a Study of Endoskarns in the Sierra Nevada Batholith, California  

British Library Electronic Table of Contents (United Kingdom)

Crustal xenoliths (pyroxenites and plagioclase + quartz + pyroxene lithologies) from the Quaternary Big Pine volcanic field on the eastern flank of the Sierra Nevada Batholith in California (USA) represent the products of metasomatic reaction between the margins of a Cretaceous granodioritic pluton and Paleozoic marbles, possibly at mid-crustal depths based on the equilibration temperatures recorded by Ti-in-quartz geothermometry. This interpretation is based on the presence of plagioclase showing relict plutonic textures, pyroxenite characterized by nearly pure diopside clinopyroxene, recrystallized plagioclase with anomalously high anorthite content, textures indicating replacement of plagioclase by clinopyroxene (and vice versa), `ghost' plagioclase rare earth element signatures in some...

2011-01-01

7

Surface and Interface Study of PdCr/SiC Schottky Diode Gas Sensor ...  

Science.gov (United States)

indications of the formation of palladium silicides. 2, 4. It has been reported .... At room temperature, palladium silicides formed in a relatively narrow interface ...

8

Acrobat Distiller, Job 7 - GLTRS - NASA  

Science.gov (United States)

into the SiC interface to form of palladium silicides (PdSix) and the subsequent migration of elemental silicon to the surface from the SiC. Palladium silicides are ...

9

Characterization of an improved disposal site for low and intermediate level waste using Cs-137 deposition profiles  

International Nuclear Information System (INIS)

According to the present concept, the low and intermediate level wastes generated during the Cernavoda NPP operation will be disposed in a near surface repository. The Saligny site, placed in the NPP protected area, has been proposed for their disposal. Geologically, the main components of this site are the quaternary loess, the Precambrian and Pre-quaternary clays, the Eocene and Barremian limestone. Hydrologically, the site can be divided into a vadose zone down to 45-50 m and three distinct aquifers, two of them in the limestone beds and the third in the lenses of sand and limestone existing in the pre-quaternary clay layer. A large research program for site characterization was initiated in 1996. At present, the site characteristics requested for safety analysis have been experimentally measured on soil samples or calculated by different computer programs. Hundreds of experimental values of the density, porosity, ...

2004-09-09

10

A REAL-TIME COAL CONTENT/ORE GRADE (C2OC) SENSOR  

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a three year DOE funded project titled ''A real-time coal content/ore grade (C{sub 2}OG) sensor''. The sensor, which is based on hyperspectral imaging technology, was designed to give a machine vision assay of ore or coal. Sensors were designed and built at Resonon, Inc., and then deployed at the Stillwater Mining Company core room in southcentral Montana for analyzing platinum/palladium ore and at the Montana Tech Spectroscopy Lab for analyzing coal and other materials. The Stillwater sensor imaged 91' of core and analyzed this data for surface sulfides which are considered to be pathfinder minerals for platinum/palladium at this mine. Our results indicate that the sensor could deliver a relative ore grade provided tool markings and iron oxidation were kept to a minimum. Coal, talc, and titanium sponge samples were also imaged and analyzed for ...

2005-04-01

11

A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.  

Science.gov (United States)

Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316

2011-08-11

12

Metallothionein (MT) response after chronic palladium exposure in the zebra mussel, Dreissena polymorpha  

International Nuclear Information System (INIS)

The effects of different exposure concentrations of palladium (Pd) on relative metallothionein (MT) response and bioaccumulation were investigated in zebra mussels (Dreissena polymorpha). The mussels were exposed to 0.05, 5, 50, and 500 ?g/L Pd2+ for 10 weeks under controlled temperature and fasting conditions. Relative MT contents were assessed by a modified Ag-saturation method, which allows to discriminate between MT bound to Pd (Pd-MT) and MT bound to unidentified metals (Ag-MT). Determination of metal contents resulted from atomic absorption spectrometry following a microwave digestion. For unexposed mussels and mussels exposed to 0.05 ?g/L Pd no metal accumulation could be detected. All other exposure concentrations resulted in detectable Pd accumulation in mussels with final tissue concentrations of 96 ?g/g (500 ?g/L), 45 ?g/g (50 ?g/L), and 9 ?g/g (5 ?g/L). Compared with initial levels Pd-MT concentrations at the ...

2008-11-01

13

On the evolution of quasicrystalline and crystalline phases in rapidly quenched Al-Co-Cu-Ni alloy  

International Nuclear Information System (INIS)

The occurrence of stable decagonal quasicrystalline phase in Al-Co-Ni and Al-Cu-Co alloys through conventional solidification is well established. Earlier, we have studied the effect of Cu substitution in place of Co in the Al_7_0Co_1_5Ni_1_5 alloy. Here we report the structural/micro-structural changes with substitution of Cu for Ni in rapidly solidified Al-Co-Ni alloys. The melt spun ribbons have been characterized using X-ray diffractometry, scanning and transmission electron microscopy. With an increase in Cu content in the melt spun Al_7_0Co_1_5Cu _xNi_1_5_-_x (x = 0-15 at.%) alloys, the relative amount of the decagonal phase decreased up to 10 at.% of Cu. At this composition, the quaternary alloy showed the co-existence of decagonal quasicrystal and superstructure of #tau#_3 vacancy ordered crystalline phases. The decagonal phase containing Cu showed more disordering than Al-Co-Ni alloys. The implication of the structural and ...

2007-03-25

14

Palladium-catalyzed combustion of methane: Simulated gas turbine combustion at atmospheric pressure  

Energy Technology Data Exchange (ETDEWEB)

Atmospheric pressure tests were performed in which a palladium catalyst ignites and stabilizes the homogeneous combustion of methane. Palladium exhibited a reversible deactivation at temperatures above 750 C, which acted to ``self-regulate`` its operating temperature. A properly treated palladium catalyst could be employed to preheat a methane/air mixture to temperatures required for ignition of gaseous combustion (ca. 800 C) without itself being exposed to the mixture adiabatic flame temperature. The operating temperature of the palladium was found to be relatively insensitive to the methane fuel concentration or catalyst inlet temperature over a wide range of conditions. Thus, palladium is well suited for application in the ignition and stabilization of methane combustion.

1995-04-01

15

The ternary system cerium-palladium-silicon  

International Nuclear Information System (INIS)

Phase relations in the ternary system Ce-Pd-Si have been established for the isothermal section at 800 deg. C based on X-ray powder diffraction and EMPA techniques on about 130 alloys, which were prepared by arc-melting under argon or powder reaction sintering. Eighteen ternary compounds have been observed to participate in the phase equilibria at 800 deg. C. Atom order was determined by direct methods from X-ray single-crystal counter data for the crystal structures of #tau#_8-Ce_3Pd_4Si_4 (U_3Ni_4Si_4-type, Immm; a=0.41618(1), b=0.42640(1), c=2.45744(7) nm), #tau#_1_6-Ce_2Pd_1_4Si (own structure type, P4/nmm; a=0.88832(2), c=0.69600(2) nm) and also for #tau#_1_8-CePd_1_-_xSi_x (x=0.07; FeB-type, Pnma; a=0.74422(5), b=0.45548(3), c=0.58569(4) nm). Rietveld refinements established the atom arrangement in the structures of #tau#_5-Ce_3PdSi_3 (Ba_3Al_2Ge_2-type, Immm; a=0.41207(1), b=0.43026(1), c=1.84069(4) nm) and #tau#_1_3-Ce_3_-_xPd_2_0_+_xSi_6 (0#<=#x#<=#1, Co_2_0Al_3B_6-type, ...

2009-09-01

16

Metallization of large silicon wafers. Final report  

Science.gov (United States)

A metallization scheme has been developed which allows selective plating of silicon solar cell surfaces. The system is comprised of three layers. Palladium, through the formation of palladium silicide at 300/sup 0/C in nitrogen, makes ohmic contact to the silicon surface. Nickel, plated on top of the palladium silicide layer, forms a solderable interface. Lead-tin solder on the nickel provides conductivity and allows a convenient means for interconnection of cells. To apply this metallization, three chemical plating baths are employed. Palladium is deposited with an immersion palladium solution and an electroless palladium solution, and nickel is deposited with an electroless nickel solution. Solder is applied with a molten solder dip. Extensive development work has been performed to achieve an effective immersion palladium solution ...

17

Summaries of Competitive Food Defense Research Reports, 2005  

Science.gov (United States)

... The least effective disinfectant was CTACl, which is a quaternary ammonium surfactant similar to those used in common household disinfectants. ...

18

Development of a 2-Aza-Cope-[3+2] Dipolar Cycloaddition Strategy for the Synthesis of Quaternary Proline Scaffolds  

UK PubMed Central (United Kingdom)

A one-pot multicomponent procedure for the synthesis of highly functionalized pyrrolidine rings through a domino...Full Text Available

2010-09-03

19

Studies about oxygen accumulation in palladium silicide formed at Pd/a-Si interface  

International Nuclear Information System (INIS)

... 194 p. auger electron spectroscopy decomposition deposition interfaces oxygen

1986-04-23

20

Behaviour of OFHC copper in highly pure water; Comportamento del rame OFHC in acqua di elevata purezza  

Energy Technology Data Exchange (ETDEWEB)

In order to gain a wider knowledge of corrosion phenomena in OFHC (oxygen free high conductivity) copper pipes of the stator cooling circuit of a power plant turboalternator, a research program was laid out which is based on the use of an experimental loop simulating real operating conditions as closely as possible. The samples examined were either copper foils or hollow conductors of the type that is normally used in the stator cooling system, and the circulating fluid was high purity water with controlled O/sub 2/, H/sub 2/ and C0/sub 2/ contents. Investigations were focused on the kinetics of O/sub 2/ removal through catalytic resins covered with metallic palladium (at different temperatures and pressures) and on the kinetics of CO/sub 2/ removal through mixed bed resins. Subsequently, attention was directed to the corrosion of copper (in the form of foils or hollow conductors) under different experimental conditions simulating either ...

1991-12-31

21

The effect of hydrogenation/dehydrogenation cycles on palladium physical properties  

International Nuclear Information System (INIS)

A series of hydrogenation/dehydrogenation cycles have been performed on palladium wire samples, stressed by a constant mechanical tension, in order to investigate the changes in electrical and mechanical properties. A large increase of palladium electrical resistivity has been reported due to the combined effects of the production of defects linked to hydrogen insertion into the host lattice and the stress applied to the sample. An increase of the palladium sample strain due to hydrogenation/dehydrogenation cycles in ????? phase transitions is observed compared to the sample subjected to mechanical tension only. The loss of initial metallurgical properties of the sample occurs already after the first hydrogen cycle, i.e. a displacement from the initial metallic behavior (increase of the resistivity and decrease of thermal coefficient of resistivity) to a worse one occurs already after the first hydrogen cycle. A linear ...

2009-08-24

22

Banana peel extract mediated novel route for the synthesis of palladium nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

Bio-inspired palladium nanoparticles were synthesized by using banana peel extract (BPE), a non-toxic eco-friendly material. Boiled, crushed, acetone precipitated, air-dried peel powder was used to reduce palladium chloride. The palladium nanoparticles were characterized by using UV-Visible spectroscopy, scanning electron microscope-energy dispersive spectra (SEM-EDS) and X-ray diffraction (XRD) analysis. Dynamic light scattering (DLS) studies revealed the average size of nanoparticles to be 50nm. Fourier transform infra red spectroscopy (FTIR) implicated the role of carboxyl, amine and hydroxyl groups in the synthetic process. This paper thus describes a novel green method for the synthesis of palladium nanoparticles.

2010-01-01

23

Ternary and quaternary fission  

Energy Technology Data Exchange (ETDEWEB)

In a systematic survey of ternary fission induced by thermal neutrons at the Lohengrin spectrometer of the ILL/Grenoble, the target nucleus {sup 249}Cf has recently been added to the list of actinides under study. Special emphasis was put on the search for the heaviest ternary particles. At the limit of detection (some 10{sup -9} per fission), the heaviest isotopes observed for {sup 249}Cf(n{sub th},f) are {sup 37}Si and {sup 37}S. Another rare process in low energy fission is quaternary fission. Here two light charged particles accompany the main fragments. The reaction {sup 233} U(n,f) has been studied at a cold neutron beam of the ILL. Two processess have to be disentangled: simultaneous and sequential quaternary fission. In the simultaneous decay the most probable combination of particles is ({alpha} + {alpha}) with a yield of {approx}10{sup -7}/fission.

2004-04-05

24

Kramers-Kronig Analysis of Infrared Reflectance Spectra for Quaternary In_xAl_yGa_1_-_x_-_yN Alloy  

International Nuclear Information System (INIS)

In this paper, a Kramers-Kronig (KK) analysis of infrared (IR) reflectance spectrum of quaternary In_0_._0_1Al_0_._0_6Ga_0_._9_3N film grown by molecular beam epitaxy (MBE) is reported. The infrared measurement is performed in the reflection mode at an incident angle of 15 degree sign by Fourier transform infrared (FTIR) spectroscopy at T = 300 K. The Kramers-Kronig analysis of the reflectivity data has been used to obtain the real and imaginary parts of the index of refraction (n and k), and the real and imaginary parts of the dielectric response function (#epsilon#' and #epsilon#') of the materials. Finally, the transverse optical and longitudinal optical phonons for quaternary In_xAl_yGa_1_-_x_-_yN were obtained.

2010-07-07

25

Ion beam crystallography of metal-silicon interfaces: Pd-Si(111)  

Energy Technology Data Exchange (ETDEWEB)

The application of medium energy ion scattering in combination with channelling and blocking to the study of the initial stages of palladium silicide formation is discussed. After a brief description of the experimental arrangement and method, the effects on the Rutherford backscattering spectra of depositing small quantities of palladium on clean Si(111) are reported. The uniformity and thermal stability of thin palladium silicide films grown at room temperature were measured. Finally, channelling and blocking results were used to carry out a structural analysis of thin epitaxial Pd/sub 2/Si layers.

1982-07-09

26

Ion beam crystallography of metal-silicon interfaces: Pd-Si(111)  

International Nuclear Information System (INIS)

The application of medium energy ion scattering in combination with channelling and blocking to the study of the initial stages of palladium silicide formation is discussed. After a brief description of the experimental arrangement and method, the effects on the Rutherford backscattering spectra of depositing small quantities of palladium on clean Si(111) are reported. The uniformity and thermal stability of thin palladium silicide films grown at room temperature were measured. Finally, channelling and blocking results were used to carry out a structural analysis of thin epitaxial Pd_2Si layers. (Auth.).

27

Properties and performance of new metastable Ti-B-C-N hard coatings prepared by magnetron sputtering  

Energy Technology Data Exchange (ETDEWEB)

Thin films of new metastable materials from the system Ti-B-C-N were deposited on metallic substrates by d.c. magnetron sputtering in different Ar+N{sub 2} atmospheres. The multiphase compound targets used were based on various compositions on the TiC-TiB{sub 2} and TiB{sub 2}-C tie lines of the Ti-B-C phase diagram. The structure and chemical composition of the films were characterized by electron microprobe analysis, depth profiling Auger electron spectroscopy, X-ray diffraction and transmission electron microscopy. The hardness, critical load of failure and the tribological behavior of the coatings were investigated. Superhard single-phase crystalline metastable Ti-B-C-N layers with hardness values exceeding 5000 HV{sub 0.05} and extremely low sliding wear against 100Cr6 and Al{sub 2}O{sub 3} counterparts could be produced by reactive sputtering of various TiC-TiB{sub 2} targets in Ar+N{sub 2} atmospheres with low nitrogen flows. In the case of carbon-rich coatings (carbon ...

1995-10-01

28

TmPd_2Si_2 and YbPd_2Si_2. Crystal fields and intermediate valence  

International Nuclear Information System (INIS)

... low temperature moessbauer effect palladium silicides thulium silicides thulium

30

Studies about oxygen accumulation in palladium silicide formed at Pd/a-Si interface  

International Nuclear Information System (INIS)

Portuguese 1986. p. 186. Brazil Achete, CA Rio de Janeiro Univ. (Brazil).

1986-04-23

31

SURFACE AND INTERFACE PROPERTIES OF PdCr/SiC SCHOTTKY DIODE GAS ...  

Science.gov (United States)

The formation of palladium silicides near the interface may decrease hydrogen solubility at the effective metal/semiconductor ...

32

Palladium- and Copper-Catalyzed Arylation of Carbon-Hydrogen Bonds  

UK PubMed Central (United Kingdom)

The transition-metal-catalyzed functionalization of C-H bonds is a powerful method for generating carbon-carbon...Full Text Available

2009-08-18

33

Microcrystalline-Si thin-film transistors formed by using palladium silicided source/drain contact electrode  

British Library Electronic Table of Contents (United Kingdom)

Microcrystalline-Si thin-film transistors (?C-Si TFTs) formed by using the source/drain contact electrode of self-aligned palladium silicide have been investigated. Both the self-aligned palladium silicided scheme and the previous top-gate staggered structure employ two-mask process steps for fabricating ?C-Si TFTs. However, the self-aligned palladium silicided scheme would cause better device characteristics than the top-gate staggered structure, primarily due to more carrier tunneling. For a gate length of 2 ?m, as compared to the top-gate staggered scheme, this silicided scheme can result in a 40% improvement of on-state current. In addition, as the gate length is reduced to 1 ?m, considerable short-channel effect is caused for both the device schemes.

2010-01-01

34

Metallization of large silicon wafers. Quarterly technical report No. 1, August 26--December 31, 1977. [45 references  

Science.gov (United States)

A proposed metallization system for large area silicon solar cells with shallow junctions is outlined, and its desirable features are discussed. A baseline process sequence for the nickel palladium metallization system (NPMS) is delineated. This baseline process sequence is serving as the starting point from which process variations are being performed. The eventual goal is optimization of the NPMS process and determination of the control ranges for NPMS process variables. Initial studies of palladium displacement and electroless chemical plating solutions used in the baseline NPMS have begun and progress is reported. In support of this work, an annotated bibliography (45 citations) dealing primarily with palladium plating and palladium-silicon contact formation has been prepared (and will be subject to updating in the future reports).

1977-01-01

35

8 - NASA Technical Reports Server  

Science.gov (United States)

Palladium silicides (Pd(x)Si) formed at a broadened interface after annealing, but a significant layer of alloy film is still free of silicon and carbon. ...

36

The ternary system cerium-palladium-silicon  

Science.gov (United States)

Phase relations in the ternary system Ce-Pd-Si have been established for the isothermal section at 800 deg. C based on X-ray powder diffraction and EMPA techniques on about 130 alloys, which were prepared by arc-melting under argon or powder reaction sintering. Eighteen ternary compounds have been observed to participate in the phase equilibria at 800 deg. C. Atom order was determined by direct methods from X-ray single-crystal counter data for the crystal structures of tau{sub 8}-Ce{sub 3}Pd{sub 4}Si{sub 4} (U{sub 3}Ni{sub 4}Si{sub 4}-type, Immm; a=0.41618(1), b=0.42640(1), c=2.45744(7) nm), tau{sub 16}-Ce{sub 2}Pd{sub 14}Si (own structure type, P4/nmm; a=0.88832(2), c=0.69600(2) nm) and also for tau{sub 18}-CePd{sub 1-x}Si{sub x} (x=0.07; FeB-type, Pnma; a=0.74422(5), b=0.45548(3), c=0.58569(4) nm). Rietveld refinements established the atom arrangement in the structures of tau{sub 5}-Ce{sub 3}PdSi{sub 3} (Ba{sub 3}Al{sub 2}Ge{sub 2}-type, Immm; a=0.41207(1), b=0.43026(1), ...

2009-09-15

37

Pyridinium based amphiphilic hydrogelators as potential antibacterial agents  

UK PubMed Central (United Kingdom)

SummaryThe numerous applications of hydrogelators have led to rapid expansion of this field. In the present work we report the facile synthesis of amphiphilic hydrogelators having a quaternary...Full Text Available

38

Method and composition for acidizing subterranean formations  

Energy Technology Data Exchange (ETDEWEB)

The present invention relates to a method of acidizing a subterranean formation or well bore employing an acidic solution containing a corrosion inhibitor composition comprising an inhibiting effective amount of an acetylenic alcohol, a quaternary ammonium compound, an aromatic hydrocarbon and an antimony compound.

1985-02-12

39

Disulfide Bonds and the Quaternary Structure of Factor VIII/von Willebrand Factor  

UK PubMed Central (United Kingdom)

Human Factor VIII/von Willebrand factor, purified by calcium citrate-cellulose chromatography and 4% agarose gel filtration was subjected to sodium dodecyl sulfate gel electrophoresis on gels containing...Full Text Available

1978-09-01

40

Overview of the geothermal activities in Greece during 1985-89  

International Nuclear Information System (INIS)

In this paper following a brief outline of the geological background in Greece, as related to geothermal exploration, the prospective areas for low enthalpy fluids are classified into four groups. These are the Tertiary grabens associated with Lithospheric stretching and crustal subsidence, the Arc of the Aegean Plio-Quaternary volcanism induced by the subduction of the African plate, Central Aegean islands of distensive tectonism bordering back-arc marine basins and finally Tertiary-Quaternary sedimentary basins of various types, not classified as grabens. The geothermal regime in each of these groups is outlined, and the current status of exploration is reviewed.

1990-08-20

41

Reactivity of ceramic superconductors with palladium alloys  

Science.gov (United States)

This paper reports Palladium alloy compositions investigated for suitability as a nonreactive material for the processing of ceramic superconductors. Barium-based superconductors were tested on Pd-Au and Pd-Ag alloys for reactivity. Bismuth-based superconductors were tested on a Pd-Ag alloy. The least reactive was found to be 70% Pd-30% Ag for the barium-based high-temperature superconductors (HTSC), whereas 30% Pd-70% Ag was found to be least reactive for bismuth-based HTSC.

1990-06-01

42

Palladium-catalyzed carbonylative coupling of benzyl chlorides with terminal alkynes to give 1,4-diaryl-3-butyn-2-ones and related furanones.  

Science.gov (United States)

A general palladium-catalyzed carbonylative Sonogashira coupling of benzyl chlorides with terminal acetylenes has been established. Depending on the alkyne 1,4-diaryl-3-butyn-2-ones or substituted furanones are obtained in moderate to good yields. Best catalytic performance is achieved applying a mixed Pd(PPh(3))Cl(2)/P(OPh)(3) catalyst system. PMID:21968528

2011-10-01

43

XPS/AES Study of Electrical and Chemical Properties of Pd/SiC Interface  

Science.gov (United States)

Silicon carbide (SiC) based electronic devices are of great importance for applications under the condition of high temperature, high power and high radiation. Schottky diodes of Palladium/SiC are good candidates for hydrogen and hydrocarbon gas sensors at elevated temperature. The detection sensibility of the diodes has been found heavily temperature dependent. In this work, the electrical and chemical properties of Pd/SiC Schottky contacts were studied by XPS and AES at different annealing temperatures. Schottky diodes were made by depositing ultra-thin palladium films onto a silicon carbide substrate. No significant change in the Schottky barrier height of the Pd/SiC contact was found in the temperature range of 300-673K. Palladium diffusion into SiC and the formation of palladium silicides were observed at room temperature and became significant at 300^oC and higher temperature. The mechanism of ...

1997-11-01

44

Photoresponsivity of ultraviolet detectors based on In{sub x}Al{sub y}Ga{sub 1-x-y}N quaternary alloys  

Energy Technology Data Exchange (ETDEWEB)

We describe the growth, fabrication, and characterization of an ultraviolet (UV) photoconductive detector based on In{sub x}Al{sub y}Ga{sub 1-x-y}N quaternary alloy that is lattice matched to GaN. The detector consisted of 0.1 {mu}m In{sub x}Al{sub y}Ga{sub 1-x-y}N alloy grown on 0.5-1.0 {mu}m GaN epilayer by metalorganic chemical vapor deposition. With varying indium concentration, the cut-off wavelength of the In{sub x}Al{sub y}Ga{sub 1-x-y}N detectors could be varied to the deep UV range. The most important and intriguing result is that the responsivity of the In{sub x}Al{sub y}Ga{sub 1-x-y}N quaternary alloy exceeded that of AlGaN alloy of a comparable cutoff wavelength by a factor of five. This makes the nitride quaternary alloy very important material for solar blind UV detectors applications particularly in the deep UV range where Al rich AlGaN alloys have problems with low quantum efficiency and cracks due in part ...

2000-08-07

45

Photoresponsivity of ultraviolet detectors based on In_xAl_yGa_1_-_x_-_yN quaternary alloys  

International Nuclear Information System (INIS)

We describe the growth, fabrication, and characterization of an ultraviolet (UV) photoconductive detector based on In_xAl_yGa_1_-_x_-_yN quaternary alloy that is lattice matched to GaN. The detector consisted of 0.1 #mu#m In_xAl_yGa_1_-_x_-_yN alloy grown on 0.5-1.0 #mu#m GaN epilayer by metalorganic chemical vapor deposition. With varying indium concentration, the cut-off wavelength of the In_xAl_yGa_1_-_x_-_yN detectors could be varied to the deep UV range. The most important and intriguing result is that the responsivity of the In_xAl_yGa_1_-_x_-_yN quaternary alloy exceeded that of AlGaN alloy of a comparable cutoff wavelength by a factor of five. This makes the nitride quaternary alloy very important material for solar blind UV detectors applications particularly in the deep UV range where Al rich AlGaN alloys have problems with low quantum efficiency and cracks due in part to lattice mismatch with GaN. The advantages ...

2000-08-07

46

Study on the solid state reaction between bilayered Pd/Au films and silicon substrates  

British Library Electronic Table of Contents (United Kingdom)

Bilayers of pure palladium and gold films were evaporated alternatively on (100) and (111) monocrystalline silicon substrates. After annealing, in a vacuum furnace from 100 to 650degreeC during 30min, the growth sequence of the Pd2Si and PdSi phases that evolved as the result of the diffusion reaction was examined by means of Rutherford backscattering spectrometry (RBS), X-ray diffraction (XRD), whereas the surface morphology was investigated by scanning electron microscopy (SEM) technique. The effect of the intermediate gold layer is investigated in order to test its effectiveness as barrier for Cu and Si atoms interdiffusion and its influence on the morphology of the formed palladium silicides. The effect of substrate orientation on the palladium silicides growth and formation was also e...

2006-01-01

47

Palladium polypyridyl complexes: synthesis, characterization, DNA interaction and biological activity on Leishmania (L.) mexicana  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the search for new potential chemotherapeutic agents based on transition metal complexes with planar ligands. In this study, palladium polypyridyl complexes were synthesized and characterized by elemental analysis, NMR, UV-VIS and IR spectroscopies. The interaction of the complexes with DNA was also investigated by spectroscopic methods. All metal-to-ligand charge transfer (MLCT) bands of the palladium polypyridyl complexes exhibited hypochromism and red shift in the presence of DNA. The binding constant and viscosity data suggested that the complexes [PdCl{sub 2}(phen)] and [PdCl{sub 2}(phendiamine)] interact with DNA by electrostatic forces. Additionally, these complexes induced an important leishmanistatic effect on L. (L.) mexicana promastigotes at the final concentration of 10 {mu}mol L{sup -1} in 48 h. (author)

2008-07-01

48

Rutherford backscattering study of the oxidation of palladium silicide on amorphous silicon substrates  

International Nuclear Information System (INIS)

Marker experiments for studying the mass transport through a palladium silicide layer on a crystalline substrate during thermal oxidation at 700 to 850 deg C have been reported recently. In this work argon gas embedded in amorphous silicon during sputtering was implemented as the inert marker and the oxidation of PdSi was processed above 900 deg C. At this high-temperature oxidation silicon-rich silicide PdSisub(y), with y exceeding 5, may be obtained. This can be anticipated by considering the Pd-Si phase diagram which shows the liquid phase may appear at an annealing temperature above 892 deg C. As a result, a non-stoichiometric and non-uniform silicide layer may develop at the sample surface. Marker analysis showed that both palladium and silicon dissociated at the Pdsub(x)Si/ SiO_2 interface and moved to the substrate with the silicon being the dominant diffuser. The Rutherford backscattering spectra (RBS) showing the oxide film and ...

49

Palladium-catalyzed Heck-type reaction of oxime ether bearing a pendant vinyl iodide moiety.  

Science.gov (United States)

A Pd(0)-catalyzed intramolecular Heck-type reaction of oxime ether has been developed, providing convenient access to heterocyclic oximes. PMID:21964259

2011-10-01

50

Palladium(II) and platinum(II) saccharinate complexes containing pyridine and 3-acetylpyridine: Synthesis, crystal structures, fluorescence and thermal properties  

British Library Electronic Table of Contents (United Kingdom)

New palladium(II) and platinum(II) complexes of saccharinate (sac), trans-[Pd(py)"2(sac)"2] (1), cis-[Pt(py)"2(sac)"2] (2), trans-[Pd(3-acpy)"2(sac)"2] (3) and cis-[Pt(3-acpy)"2(sac)"2] (4) (py=pyridine and 3-acpy=3-acetylpyridine) have been synthesized. Elemental analysis, UV-Vis, IR, NMR and TG/DTA characterizations have been carried out. The structures of 1-4 were determined by X-ray diffraction. The palladium(II) and platinum(II) ions are coordinated by two N-bonded sac ligands, and two nitrogen atoms of py or 3-acpy, forming a distorted square-planar geometry. The palladium(II) complexes (1 and 3) are trans isomers, while the platinum(II) complexes (2 and 4) are cis isomers. The mononuclear species in the solid state are connected by weak intermolecular C-H...O hydrogen bonds, C-H...@...

2011-01-01

51

Evaluating the cytotoxicity of palladium/magnetite nano-catalysts intended for wastewater treatment  

International Nuclear Information System (INIS)

Palladium/magnetite nanoparticulate catalysts were developed for efficient elimination of halogenated organic pollutants from contaminated wastewater. Particle recovery from treated water can be ensured via magnetic separation. However, in worst-case scenarios, this catalyst removal step might fail, leading to particle release into the environment. Therefore, a toxicological study was conducted to investigate the impact of both pure magnetite and palladium/magnetite nanoparticle exposure upon human skin (HaCaT) and human colon (CaCo-2) cell lines and a cell line from rainbow trout gills (RTgill-W1). To quantify cell viability after particle exposure, three endpoints were examined for all tested cell lines. Additionally, the formation of reactive oxygen species was studied for the human cells. The results showed only minor effects of the particles on the tested cell systems and support the assumption that palladium/magnetite ...

2010-01-01

52

Electronic and Interfacial Properties of Pd/6H-SiC Schottky Diode ...  

Science.gov (United States)

and palladium silicides (Pd,Si) with a total. AES intensity ratio of Pd to Si of 35/65. Scanning Electron Microscopy. (SEM') of the Pd region shows that ...

53

Absorption and diffusion of hydrogen in palladium-silver alloys by density functional theory  

Science.gov (United States)

The vibrational states, absorption energies, and diffusions of H in Pd and Pd1-xAgx(0Pd-Ag alloys should avoid the Ag-rich areas.

2002-11-01

54

Structure and antimicrobial activity relationship of quaternary N-alkyl chitosan derivatives against some plant pathogens  

British Library Electronic Table of Contents (United Kingdom)

In the present work, quaternary chitosans as water-soluble compounds were prepared based on three-step process. Schiff bases were firstly synthesized by the reaction between the amino groups of chitosan with aliphatic aldehydes followed by a reduction with sodium borohydride (NaBH4) to form N-(alkyl) chitosans. N,N,N-(dimethyl alkyl) chitosans were then obtained by a reaction of chitosan containing N-butyl, N-pentyl, N-hexyl, N-heptyl, and N-octyl substituents with methyl iodide. The compounds were characterized using IR and NMR spectroscopy. Subsequent experiments were conducted to test their antimicrobial activities against the most economic plant pathogenic bacteria of crown gall disease Agrobacterium tumefaciens, soft mold disease Erwinia carotovora, fungi of grey mold Botrytis cinerea...

2010-01-01

55

Chemical stability of {gamma}-butyrolactone-based electrolytes for aluminium electrolytic capacitors  

Energy Technology Data Exchange (ETDEWEB)

{gamma}-Butyrolactone-based electrolytes have been used as the operating electrolytes for aluminum electrolytic capacitors. The chemical stability of these electrolytes at elevated temperatures has been examined by monitoring the decrease in their electrolytic conductivities. The deteriorated electrolytes were analyzed by gas and liquid chromatography and the conductivity decrease was directly correlated with the loss of acid components. In quaternary ammonium hydrogen maleate/{gamma}-butyrolactone electrolytes, the maleate anion decomposed by decarboxylation resulting in a complex polymer containing polyester and polyacrylate structures. Quaternary ammonium benzoate/{gamma}-butyrolactone electrolytes decomposed by SN2 reactions giving alkyl benzoates and trialkylamines. The deterioration of the carboxylate salt/{gamma}-butyrolactone electrolytes was accelerated by electrolysis. (orig.)

1996-06-01

56

Impact of palladium silicide formation on the catalytic properties of Pd/SiO2 catalysts in liquid-phase semihydrogenation of phenylacetylene  

British Library Electronic Table of Contents (United Kingdom)

Palladium silicide was formed on the sol-gel derived SiO2 supported Pd catalysts prepared by ion-exchange method (Pd/SiO2-SG-ion). However, the catalysts exhibited superior performances than commercial SiO2 supported ones in liquid-phase semihydrogenation of phenylacetylene. It was probably due to an inhibition of a product of styrene, which is adsorbed on the surface of Pd, more strongly on Pd/SiO2-SG in which Pd is electron-deficient as shown by larger binding energy from XPS results.

2007-01-01

57

Tritium release from lithium orthosilicate pebbles deposited with palladium  

International Nuclear Information System (INIS)

Full text of publication follows: Slightly over-stoichiometric lithium orthosilicate pebbles have been selected as one optional breeder material for the European Helium Cooled Pebble Bed (HCPB) blanket. This material has been developed in collaboration of Research Center Karlsruhe and the Schott Glass, Mainz. The lithium orthosilicate pebbles are fabricated from lithium hydroxide and silica by a melting and spraying method in a semi-industrial scale facility. Lithium hydroxide was selected as the precursor since enriched lithium hydroxide is commercially available. The lithium orthosilicate pebbles produced by the process contains oxide phases besides orthosilicate, but it was also found that the oxide phases can be decomposed by annealing at high temperatures. The lithium orthosilicate pebbles produced in this way possesses satisfactory pebble characteristics. Therefore, the authors performed out-of-pile annealing tests using the lithium orthosilicate pebbles irradiated in a research ...

2007-12-10

58

Study of the physical and mechanical changes in packaging materials used in radiation processing - measuring methods of physical and mechanical properties  

International Nuclear Information System (INIS)

The behaviour of the packaging materials under radiation field has a great importance in radiation processing, because, in most cases, they are finally responsible for the preservation of the beneficent changes achieved in irradiated products. For example, in radiation sterilisation and food irradiation, the packages must preserve the sterilisation, respectively the sanitisation. They must preserve also the physical barrier feature. The radiation effects on plastics were extensively studied in the last decades for nuclear industry and more recently for radiation processing. The two major effects of nuclear radiation on polymeric materials are the degradation and cross-linking. The degradation consists in breaking of macromolecules after interaction with nuclear particles, amplified by the free radicals which persist long periods, especially in crystalline polymers. Oxygen could penetrate the sample and interact with free radicals so that the degradation process continues after the ...

59

THE CONTENT OF ADENINE NUCLEOTIDES AND ...  

Science.gov (United States)

... Accession Number : AD0262144. Title : THE CONTENT OF ADENINE NUCLEOTIDES AND CREATINE PHOSPHATE IN BRAIN. ...

1961-05-01

60

Rapid Responding Palladium-Silver Surface Modified Microsensor for Hydrogen  

Science.gov (United States)

Most palladium thin film based hydrogen gas sensors have response and recovery times that are too long to make them useful in vehicular and stationary gas leak detection applications. In contrast, a palladium-silver thin film based microcantilever (MC) hydrogen gas microsensor is reported herein with near ideal response characteristics for use in these hydrogen economy related applications. Specifically, 3-10 second response and recovery times have been measured for these sensors in contrast to previous sensor response measurements of several to tens of minutes using Pd thin film and MC based sensing techniques. The much reduced response times observed in the present study are attributed to a wet chemical Pd-Ag thin film deposition technique and a gas conditioning protocol that produces a highly nanostructured, porous film that rapidly adsorbs and desorbs H2, allowing rapid equilibration with the H2 concentration in the surrounding air. The wet ...

2010-01-01

61

Impedance analysis of hydrogen adsorption on palladium in 0. 1 M NaOH solution  

Energy Technology Data Exchange (ETDEWEB)

The behaviour of hydrogen adsorption on palladium has been investigated by a.c. impedance measurements in 0.1 M NaOH solution of pH 13 at 298 K. The electrode impedance has been measured by superimposing an a.c. voltage of 5 mV amplitude ranging between 10{sup -1} and 10{sup 4} Hz on a d.c. potential range from -0.76 to 0.44 V (standard hydrogen electrode (SHE)). The equivalent circuit representing the hydrogen adsorption reaction is proposed from the analysis of the frequency dependence of electrode admittance. The capacitance, arising from the adsorbed hydrogen, has been determined as a function of applied potential by complex non-linear least-squares curve fitting method based on the proposed equivalent circuit. As the cathodic applied potential increased from -0.36 to -0.76 V (SHE), the adsorption capacitance considerably increased owing to the enhanced coverage of hydrogen adsorbed on the palladium surface. In the applied potential range ...

1991-10-21

62

How epitaxial are Pd/sub 2/Si-Si interfaces  

Energy Technology Data Exchange (ETDEWEB)

Pd/sub 2/Si layers produced by evaporation or sputtering onto silicon substrates were examined by high resolution electron microscopy, microdiffraction, X-ray, energy loss and Auger spectroscopy. The Si-Pd/sub 2/Si interfaces produced by evaporation were in all cases rougher and more polycrystalline than those produced by sputtering. X-ray microanalysis showed the predictable variation in palladium distribution across the interface but quantification did not produce the expected palladium-to-silicon ratios, primarily because of probe broadening and X-ray-induced fluorescence. Energy loss spectra showed plasmon energy shifts and changes in Si L edge shape due to bond formation with palladium. Auger data provided evidence for a small amount of oxygen at the Si-Pd/sub 2/Si interface. Electrical measurements of the ideality factor for Schottky barriers made from the materials produced higher values for the rougher ...

1983-06-17

63

Effects of palladium particle size and palladium silicide formation on fourier transform infrared spectra of CO adsorbed on Pd/SiO sub 2 catalysts  

Energy Technology Data Exchange (ETDEWEB)

Two major modes of CO adsorption on SiO{sub 2}-supported Pd reflect different extents of back-donation, which is, at least in part, controlled by the local electron density at the adsorption site. The fraction of CO in the bridging mode (B) increases and that of the linear mode (L) decreases, with increasing size of the Pd particles, indicating high electron density at Pd atoms in terraces of close-packed crystal faces, in agreement with Smoluchowski's classical model. For samples reduced at 300{degree}C our data points and those of other authors are located on a common curve of B/L vs metal dispersion. Extensive reduction at 600{degree}C results in significantly lower B/L values, attributed to the incipient formation of a palladium silicide. Oxidation followed by reduction at 300{degree}C destroys the silicide, and the B/L value returns to the original curve.

1989-06-15

64

Effects of palladium particle size and palladium silicide formation on fourier transform infrared spectra of CO adsorbed on Pd/SiO sub 2 catalysts  

Science.gov (United States)

Two major modes of CO adsorption on SiO{sub 2}-supported Pd reflect different extents of back-donation, which is, at least in part, controlled by the local electron density at the adsorption site. The fraction of CO in the bridging mode (B) increases and that of the linear mode (L) decreases, with increasing size of the Pd particles, indicating high electron density at Pd atoms in terraces of close-packed crystal faces, in agreement with Smoluchowski's classical model. For samples reduced at 300{degree}C our data points and those of other authors are located on a common curve of B/L vs metal dispersion. Extensive reduction at 600{degree}C results in significantly lower B/L values, attributed to the incipient formation of a palladium silicide. Oxidation followed by reduction at 300{degree}C destroys the silicide, and the B/L value returns to the original curve.

1989-06-15

65

Self-diffusion of silicon in thin films of cobalt, nickel, palladium and platinum silicides  

International Nuclear Information System (INIS)

Radioactive "3"1Si was used as a tracer to study silicon self-diffusion in thin film silicides of cobalt, nickel, palladium and platinum. The specimens were prepared by sequential electron beam evaporation of radioactive "3"1Si and of the metal onto cleaned silicon wafers. By vacuum annealing at the appropriate formation temperature a silicide about 250 nm thick containing a sharp radioactive band about 50 nm thick was generally formed. Subsequent heating above the formation temperature resulted in a spreading of the activity owing to silicon self-diffusion. Activity profiles in the silicides were measured by a combination of ion beam sputtering, radioactivity counting and Rutherford backscattering of charged nuclear particles. (orig.).

66

Plasma treatment process for palladium chemisorption onto polymers before electroless deposition  

Science.gov (United States)

Before electroless plating, polymer surfaces must be sensitized and/or activated by using either the conventional two-step or one-step process. The latter stage is a compulsory one to make such surfaces catalytic, e.g., for Ni-P deposition. These processes are performed here using O{sub 2}, NH{sub 3}, or N{sub 2} plasma pretreatments. Reaction mechanisms are proposed for each of the processes and for each type of surface considered (oxygenated or both oxygenated and nitrogenated by the plasma treatment). Direct palladium chemisorption onto nitrogenated groups is highlighted. This allows one to simplify the process making the surface catalytic via elimination of the use of SnCl{sub 2} and to extend the method to any polymer. An additional interest of the plasma treatments, besides their high efficiency in grafting chemical functions, is to perform this grafting at will on selected areas which results in selective metallization.

1996-02-01

67

Electrochemical properties of palladium adlayers on Pt(110) substrates  

British Library Electronic Table of Contents (United Kingdom)

Palladium deposition on Pt(110) electrodes was studied. Differently from Pt(111) and Pt(100), first and further layers cannot be distinguished in this case only through the voltammetric behavior of hydrogen and anion adsorption. The potential of zero total charge (pztc) was determined as a function of the amount of deposited Pd using CO charge displacement experiments and voltammetric curves. The variation of the voltammetric charge due to hydrogen and anion adsorption has been followed during Pd deposition. The voltammetric charge between 0.06 and 0.4V first decreases to a minimum, then increases and finally becomes stable, suggesting that the surface is finally covered with a Pd multilayer. The pztc and CO oxidation charge show similar behavior. CO oxidation, NO reduction and Cu UPD were...

2011-01-01

68

Auger electron spectroscopy studies of GaAs and Si metal-semiconductor structures  

Science.gov (United States)

The use of Auger electron spectroscopy (AES) combined with in situ sputter etching for revealing the metallurgy of the metal-semiconductor interface is presented. The physical basis, measurement techniques, and data interpretation for Auger analysis of thin-film structures are briefly reviewed. Results of a detailed study of an alloyed multilayered contact (Ni/Au-Ge) on n-type epitaxial GaAs are summarized to illustrate how electrical and metallurgical contact properties can be correlated using AES. In addition, the results of a study of the growth kinetics and chemical phase identification of palladium silicide on single-crystal Si is given, as well as the initial results of a study of aluminum-palladium silicide interaction at elevated temperature. (auth)

1975-01-01

69

Auger electron spectroscopy studies of GaAs and Si metal-semiconductor structures  

International Nuclear Information System (INIS)

The use of Auger electron spectroscopy (AES) combined with in situ sputter etching for revealing the metallurgy of the metal-semiconductor interface is presented. The physical basis, measurement techniques, and data interpretation for Auger analysis of thin-film structures are briefly reviewed. Results of a detailed study of an alloyed multilayered contact (Ni/Au-Ge) on n-type epitaxial GaAs are summarized to illustrate how electrical and metallurgical contact properties can be correlated using AES. In addition, the results of a study of the growth kinetics and chemical phase identification of palladium silicide on single-crystal Si is given, as well as the initial results of a study of aluminum-palladium silicide interaction at elevated temperature.

70

Ar/sup +/ ion beam induced silicide formation mechanism at the Pf-Si interface  

Energy Technology Data Exchange (ETDEWEB)

Evaporated palladium films of 45 nm thickness on Si(111) were irradiated using 78 keV Ar/sup +/ ions with doses in the range of 1 x 10/sup 15/ to 1.5 x 10/sup 16/ cm/sup -2/ for the purpose of studying silicide formation. Rutherford backscattering analysis shows that intermixing has occurred across the Pd-Si interface at room temperature. The mixing behaviour increases with increasing dose of the bombarding ions, which agrees well with a theoretical model of isotropic cascade mixing for palladium, and radiation-enhanced diffusion associated with an interstitial mechanism for silicon.

1989-01-01

71

Processing and characterization of polyethylene/Brazilian clay nanocomposites  

Energy Technology Data Exchange (ETDEWEB)

Nanocomposites containing polyethylene (PE) and montmorillonite clay organically modified (OMMT) with quaternary ammonium salts were obtained via direct melt intercalation. A montmorillonite sample from the Brazilian state of Paraiba was treated with four different types of quaternary ammonium salts. After the treatment, the powder was characterized by X-ray diffraction and scanning electron microscopy. The dispersion and morphologies of OMMT within PE were investigated by X-ray diffraction and transmission electron microscopy. The results revealed the formation of intercalated montmorillonite layers in the PE matrix. The thermal stability and flammability of the PE/montmorillonite clay nanocomposites were measured by thermogravimetry and horizontal burning tests for HB classification, Underwrites Laboratories (UL 94), respectively. It was shown that the samples do not degrade at the processing temperature. By adding only 3 wt.% ...

2007-02-15

72

On the band gap dependence of refractive indices of some quaternary III-V and II-VI compounds of device interest  

International Nuclear Information System (INIS)

The credibility of the model proposed by Ghosh in predicting the refractive indices of mixed semiconductor crystals of technological importance within their miscibility range as a function of band gap is demonstrated. The high-frequency refractive indices of four quaternary alloys Al_xGa_1_-_x_-_yIn_yP (y = 0.49, 0 #<=# x #<=# 0.51), InSb_xAs_1_-_x_-_yP_y (y = 2.2x, 0 #<=# x #<=# 0.313, 0 #<=# y #<=# 0.638), Cd_xZn_1_-_x_-_yHg_ySe (x + y = 1, 0.153 #<=# x #<=# 0.684, 0.316 #<=# y #<=# 0.847), and CdS_1_-_x_-_ySe_xTe_y (x + y = 1, 0.15 #<=# x #<=# 0.93, 0.07 #<=# y #<=# 0.85) are calculated according to the relation n"2-1 = A/(E_g + B)"2 where A is an energy gap dependent constant and B is a constant depending on crystal ionicity. The calculated values show excellent agreement with the experimental data thus justifying the validity of the model.

73

Inhibition of corrosion resistant alloys in hot hydrochloric acid solutions  

Energy Technology Data Exchange (ETDEWEB)

Weight loss measurements were performed in 20% and 28% hydrochloric acid at 90/sup 0/C on carbon steel, 22Cr5Ni duplex stainless steel, and two superaustenitic steels - 27Cr31Ni3Mo and 19Cr25Ni4Mo -, in presence of organic substances used singly or mixed. The organic substances examined were quaternary ammonium salts (1-4-pyridyl)-pyridinium chloride hydrochloride, dodecylpyridiniumchloride, benzyldimethylstearylammonium chloride, and dodecyltrimethylammonium bromide), alkynols (1-octyn-3-ol, propargyl alcohol) and trans-cinnamaldehyde. The synergistic effect of potassium iodide on the inhibitive efficiency of the organic substances was studied. The variations of corrosion rate during the test time (normally six hours) were recorded by means of polarization resistance measurements. Polarization curves were also recorded. The results showed that the corrosion rates of the four steels examined can be reduced to less than 1 mg/cm/sup -2/ . h/sup -1/ using ternary ...

1988-12-01

74

Development of GaInAsP for GaInAsP/Ge cascade solar cells  

Energy Technology Data Exchange (ETDEWEB)

Quaternary semiconductor compounds are ideal candidates for use in monolithic cascade solar cells because the lattice constant and the bandgap of such compounds can be independently varied. The quaternary semiconductor compound Ga[sub 0.83]In[sub 0.17]As[sub 0.67]P[sub 0.33] not only is lattice matched to GaAs and Ge but also provides a current matched top cell for the GaInAsP/Ge monolithic cascade solar cell. Under concentration of 100 suns, the projected efficiency for such a cell is about 34%. The growth of Ga[sub 0.83]In[sub 0.17]As[sub 0.67]P[sub 0.33] lattice matched to GaAs and Ge has been demonstrated. GaInAsP solar cells have been grown on both GaAs and Ge substrates. A GaInAsP on GaAs solar cell with an active area efficiency of 23.2% for 1 sun, AM 1.5 direct illumination has been prepared. A proposed structure for the GaInAsP/Ge cascade cell is also given.

1992-12-01

75

Emulsans. [Acinetobacter sp. ATCC 31012  

Energy Technology Data Exchange (ETDEWEB)

The production and uses are described for extracellular microbial polysaccharides (generically called emulsans) and for a new class of extracellular microbial protein-associated lipopolysaccharides (collectively called alpha-emulsans) produced by Acinetobacter Sp. ATCC 31012, its mutants or recombinants. Also included are the deproteinized lipopolysaccharides (collectively called apoemulsans) obtained from such emulsans, as well as to the divalent metal, ammonium, and quaternary ammonium salts of such emulsans and apoemulsans. The materials can be used (1) in cleaning oil-contaminated vessels used to transport or store crude oil or petroleum fractions in such a manner that the residual oil may be recovered for fuel value or for refining and (2) in enhanced oil recovery.

1983-07-05

76

Seismic stratigraphy in the South Cretan fault valley system: A comparison with the upper Quaternary gravitative sedimentation of the region  

Energy Technology Data Exchange (ETDEWEB)

A synthesis of the sedimentation processes as deduced from the seismic stratigraphy and the deduced facies associations suggests the following. Small fans developed along the northern major fault line of the SCFVS and contains sediment fed directly from Crete through a series of small canyons, most of which trend perpendicular to the coast. However, the main east-west-trending valley transects the mid- and lower fan sectors and contains several intravalley basinal areas, converging toward the main Messara basin. Thus much of the suprafan sediment is reworked and longitudinally transported into the deeper basins. In these deeper intrabasinal and main basinal areas the thickness of the post-Messinian sediments generally exceeds 800 m and in places exceeds 1,500 m. Toward the south the SCFVS receives additional sediment from the Ptolemy Mountains and the Gavdos rise. Cores recovered along the SCFVS contain a remarkable association of sedimentary sequences which are interpreted as deposits ...

1988-08-01

77

Quaternary faults near the proposed Eagle Flat low-level radioactive waste repository, Trans-Pecos Texas  

Science.gov (United States)

The Eagle Flat basin, an intermontane basin in Trans-Pecos Texas, is being considered as a possible site for the Texas repository of low-level radioactive wastes. Intermontane basins and associated normal faults formed in response to Basin and Range tectonism that began about 24 Ma ago. The most active late Tertiary and Quaternary faults occur within the Hueco Bolson (HB) and the Salt Basin/Salt Flat/Lobo Valley, west and east, respectively, of the proposed repository. Several faults of the southeast HB which are within 50 km of the site, displace middle Pleistocene deposits 10 to 24 m. The most recent surface rupture in the southeast HB probably occurred on the Amargosa fault during the Holocene. Upper Pleistocene deposits are offset 2.5 to 4.5 m, and middle Pleistocene deposits are displaced 24 m. Fault scarps within 50 km east of the proposed repository are associated with faults bounding the Salt Basin/Salt Flat/Lobo Valley. In the southern Salt Basin and ...

1992-01-01

78

Formation and stabilization of anionic metal complexes in concentrated aqueous quaternary ammonium salt solutions  

Energy Technology Data Exchange (ETDEWEB)

Anionic complexes of transition metals were stabilized in aqueous solutions containing high concentrations of various short-chain quaternary ammonium salts. Compounds with longer paraffin chains were effective in much less concentrated solution. Complex ions were detected spectrophotometrically. FeCl/sub 4//sup -/, which is usually formed in concentrated HCl, was the predominant Fe(III) complex in 30 m choline chloride containing only 0.12 M HCl. A yellow transitory Tc(VII) chloro-addition intermediate, formed in the reduction of TcO/sub 4//sup -/ by concentrated HCl, was stabilized when the solution also contained 25 m choline chloride. Its spectrum, as well as the isolation of an already known Tc(VII) bipyridyl complex, is reported. Concentrated organic electrolytes also stabilized Tc(V) oxide halides against disproportionation and Tc(IV) hexahalides against hydrolysis. Halochromates of Cr(VI) were formed and stabilized in dilute acid containing ...

1985-02-04

79

Energy gap and bond lengths of Al_xGa_yIn_1_-_x_-_yN, Al_xGa_yIn_1_-_x_-_yP and Al_xGa_yIn_1_-_x_-_yAs quaternary alloys  

International Nuclear Information System (INIS)

We use the Generalized Quasi-Chemical Approach (GQCA) combined with ab initio ultrasoft pseudopotential calculations within density functional theory in order to obtain the structural and electronic properties of Al_xGa_yIn_1_-_x_-_yX (X=As, P or N) quaternary alloys in the zincblende structure. Results for the bond lengths show that their variations with composition are approximately linear and that they do not deviate much from the values of the corresponding binary compounds. For the variation of the band gaps, we obtain a bowing parameter b=0.26 eV for the (Ga_0_._4_7In_0_._5_3As)_z(Al_0_._4_8In_0_._5_2As)_1_-_z quaternary alloy lattice matched to InP, in very good agreement with experimental data. In the case of AlGaInN, a bowing parameter of 0.22 eV is obtained for zincblende AlGaInN lattice matched to GaN. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

80

X-ray diffraction studies of palladium silicide thin films  

Energy Technology Data Exchange (ETDEWEB)

The solid state reaction between a Pd thin film and a Si substrate produces a single new phase, Pd/sub 2/Si, for temperatures <700/sup 0/C. When the substrate is a single crystal of (111) surface orientation, this process is particularly interesting because the silicide grows epitaxially. Growth of epitaxial interfacial Pd/sub 2/Si was the focus of this study using X-ray diffraction techniques.

1985-01-01

81

Electrodeless, multi-megawatt reactor for room-temperature, lithium-6/deuterium nuclear reactions  

International Nuclear Information System (INIS)

This paper describes a reactor design to facilitate a room-temperature nuclear fusion/fission reaction to generate heat without generating unwanted neutrons, gamma rays, tritium, or other radioactive products. The room-temperature fusion/fission reaction involves the sequential triggering of billions of single-molecule, "6LiD 'fusion energy pellets' distributed in lattices of a palladium ion accumulator that also acts as a catalyst to produce the molecules of "6LiD from a solution comprising D_2O, "6LiOD with D_2 gas bubbling through it. The D_2 gas is the source of the negative deuterium ions in the "6LiD molecules. The next step is to trigger a first nuclear fusion/fission reaction of some of the "6LiD molecules, according to the well-known nuclear reaction: "6Li + D #-># 2"4He + 22.4 MeV. The highly energetic alpha particles ("4He nuclei) generated by this nuclear reaction within the palladium will cause shock and vibrations in the ...

82

Efficient synthesis of unsymmetric diarylalkynes from decarboxylative coupling in a continuous flow reaction system  

British Library Electronic Table of Contents (United Kingdom)

Unsymmetric diaryl alkynes were synthesized from the palladium-catalyzed decarboxylative coupling of aryl halides and propiolic acid using a continuous flow reaction system. This flow chemistry system continuously gave the desired products in moderate to good yields, and produced less byproduct than was formed in the batch reaction.

2011-01-01

83

Efficient combining of ion pumps and getter-palladium thin films  

International Nuclear Information System (INIS)

Nonevaporable getters (NEGs) have been extensively studied in the last several years for their sorption properties toward many gases. In particular, an innovative alloy as a thin film by magnetron sputtering was developed and characterized at the European Organization for Nuclear Research. It is composed of Ti-Zr-V and protected by an overlayer of palladium (Pd), according to a technology for which the authors got the licence. NEG-Pd thin films used in combination with ion getter pumps is a simple, easy way to handle pumping devices for ultrahigh and extremely high vacuum applications. To show how to apply this coating technology to the internal surface of different types of ion pumps, the authors carried out several tests on pumps of various shapes, sizes (in terms of nominal pumping speed), and types (diode, noble diode, and triode). Special care was taken during the thermal cycle of baking and activation of the pumps to preserve the internal film from sources of ...

2008-07-01

87

Residual water losses during determination of total water content in brown coal  

Energy Technology Data Exchange (ETDEWEB)

Discusses Czechoslovak regulations for determining moisture content in brown coal. Standard formulae for determining total moisture content and residual water content are described. Factors that influence accuracy in determining moisture content under laboratory conditions are analyzed: brown coal type, season of the year, air humidity, method and duration of coal sample drying, number of coal samples simultaneously dried in 1 dryer, ash content of coal. On the basis of analysis recommendations for a modified method of determining moisture content in brown coal are made. 5 refs.

1988-01-01

88

Silver(I), mercury(II) and palladium(II) complexes of functionalized N-heterocyclic carbenes: Synthesis, structural studies and catalytic activity  

British Library Electronic Table of Contents (United Kingdom)

A series of NHC silver(I), mercury(II) and palladium(II) complexes, [(1,3-diethylbimy)6Ag4I3]I (2), [(1-benzyl-3-picolylbimy)Ag2Br2]n (3), [(1-benzyl-3-picolylbimy)HgI(CH2CN)]2 (4), {[(1-picolyl-3-npropylbimy)2Hg][Hg2I6]}n (5) and [(1,3-dipicolylbimy)PdCl]Cl (6), as well as one anionic complex [1,3-diethylbimidazolium]2[HgI4] (1) (bimy=benzimidazol-2-ylidene), have been prepared and characterized. Interestingly, a wind wheel-like Ag4I3 arrangement in 2 is formed, 1D polymeric chain containing 12-membered macrometallocycles and quadrangle Ag2Br2 units in 3 is generated, and the a-carbon atom of deprotonated acetonitrile ([CH2CN]-) in 4 participates in coordination with mercury(II) atom. In the crystal packings of complexes 1-6, 2D supramolecular layers or 3D supramolecular architectures are...

2011-01-01

89

Low-temperature radiation controlled diffusion of palladium and platinum in silicon for advanced lifetime control  

International Nuclear Information System (INIS)

Radiation defects produced by helium implantation were used to shape profiles of palladium (Pd) and platinum (Pt) atoms in-diffusing (for 20 min at temperatures 600-800 deg. C) either from surface silicide (Pd_2Si, PtSi) or implanted layers. Results show that this procedure allows a strong localization of substitutional Pd and Pt at the depth where the damage produced by helium peaks. This results in local reduction of carrier lifetime by an almost ideal recombination centers - the acceptor level of substitutional Pd (E _c - 0.22 eV) or Pt (E _c - 0.23 eV). While optimum conditions for Pt in-diffusion are about 700 deg. C, Pd gives the best results already at lower temperatures (600 deg. C) where it also exhibits higher peak solubility. Both methods were used for optimization of turn-off properties of high power PiN diodes. The devices, where the lifetime was killed locally by Pd and Pt, exhibited similar trade-off between the static and dynamic parameters as the ...

2006-12-01

90

In situ excimer laser annealing of low-temperature low-pressure chemical vapour deposition grown polycrystalline silicon: influence of metal diffusion on the film morphology and on the growth rate  

Energy Technology Data Exchange (ETDEWEB)

Polycrystalline silicon films have been grown from Si{sub 2}H{sub 6} by low-pressure chemical vapour deposition at 800 K and in situ laser annealing (LA) on amorphous silicon seed layers deposited on a metallic Ti/Pd/Ag multilayer. The crystalline volume fraction in the seed layer was controlled by thermal annealing. According to the metal-induced crystallization effect, the presence of the metal induces a lower-temperature crystallization of silicon in the seed layers. X-ray diffraction and scanning electron microscopy data show that the formation of palladium silicides in the seed layer drives the growth of wire-like columns which are found to change morphology depending on the seed layer microstructure and LA parameters. It is suggested that superficial palladium was found to affect also the growth rate by enhancing the Si{sub 2}H{sub 6} dissociation.

2004-06-30

91

In situ excimer laser annealing of low-temperature low-pressure chemical vapour deposition grown polycrystalline silicon: influence of metal diffusion on the film morphology and on the growth rate  

International Nuclear Information System (INIS)

Polycrystalline silicon films have been grown from Si_2H_6 by low-pressure chemical vapour deposition at 800 K and in situ laser annealing (LA) on amorphous silicon seed layers deposited on a metallic Ti/Pd/Ag multilayer. The crystalline volume fraction in the seed layer was controlled by thermal annealing. According to the metal-induced crystallization effect, the presence of the metal induces a lower-temperature crystallization of silicon in the seed layers. X-ray diffraction and scanning electron microscopy data show that the formation of palladium silicides in the seed layer drives the growth of wire-like columns which are found to change morphology depending on the seed layer microstructure and LA parameters. It is suggested that superficial palladium was found to affect also the growth rate by enhancing the Si_2H_6 dissociation.

2004-06-30

92

Characterization of supported palladium catalysts II. Pd/SiO sub 2  

Science.gov (United States)

The isomerization of neopentane has been investigated over the 0.76 wt% Pd/SiO{sub 2} catalyst. It is found that after high temperature reduction (HTR, at 873 K) the selectivity for isomerization is much higher than that after low temperature reduction (LTR, at 573 K). A variety of experiments, including kinetic, chemisorption (O{sub 2}, H{sub 2}, and CO), temperature-programmed desorption of H{sub 2}, and X-ray diffraction, showed that this selectivity enhancement cannot be interpreted in terms of H{sub 2} retention by catalyst. Instead, the formation of Pd-Si compound(s) (most probably Pd{sub 3}Si) during HTR seems immediately responsible for the catalytic behavior of HTR Pd/SiO{sub 2} catalysts. A mechanism is proposed for the Pd-SiO{sub 2} interaction in which Pd atoms (or ions) are incorporated into the silica support (via oxygen vacancies) and a new phase of palladium silicide is formed. Regeneration by an oxygen treatment of the HTR sample does not fully ...

1989-06-01

93

Anodic stripping voltammetric determination of uranium at a thin palladium film-aluminum electrode. Analysis of some uranium mineral ores  

International Nuclear Information System (INIS)

In the present work, a rapid deposition anodic stripping voltammetry (ASV) for determination of uranium is presented. For this purpose, the uranyl hexacyanoferrate (K2UO2[Fe(CN)6]) is deposited electrochemically on a thin palladium-aluminum electrode (Pd-Al) from a UO22+ solution in the presence of K3Fe(CN)6. Then, the well stable (K2UO2[Fe(CN)6]) on the electrode was stripped by anodic differential pulse voltammetry for measuring the UO22+ ion concentration. The effect of operational parameters, including: concentration of K3Fe(CN)6, solution pH, deposition potential, and deposition time were studied. In optimum conditions, the calibration graph was linear in the concentration range 105-7 x 10-4 mol L-1 with a detection limit of 6.2 x 10-6 mol L-1. The influence of some concomitant ions in K2UO2[Fe(CN)6] formation was investigated. The proposed method was used for the rapid determination of uranium in some uranium mineral ores. (orig.)

2010-01-01

94

Weathering behaviour and construction suitability of dimension stones from the Drei Gleichen area (Thuringia, Germany)  

British Library Electronic Table of Contents (United Kingdom)

The construction suitability of a dimension stone depends on its weathering properties along with the petrology and the petrophysical properties. The aim of this study was to evaluate the suitability of the dimension stones from the ?Drei Gleichen? area for construction and replacement purposes. In total, six sandstones (Ingersleben, Wachsenburg, Hindfelden, Seeberg, R?hnberg, Gleichenberg; Upper Triassic) as well as two carbonates (Wachsenburg sinter; Quaternary, Wandersleben dolomite; Middle Triassic) were analysed. The results from our laboratory and on-site studies of the dimension stones show that rocks from the same stratigraphic layer, like the sandstones from the upper Triassic, can show major differences in their petrophysical and weathering properties. These differences are attri...

2011-01-01

95

Preparation and evaluation of a novel glass-ionomer cement with antibacterial functions  

British Library Electronic Table of Contents (United Kingdom)

Objective.The objective of this study was to use the newly synthesized poly(quaternary ammonium salt) (PQAS)-containing polyacid to formulate the light-curable glass-ionomer cements and study the effect of the PQAS on the compressive strength and antibacterial activity of the formed cements.Materials and methods.The functional QAS and their constructed PQAS were synthesized, characterized and formulated into the experimental high-strength cements. Compressive strength (CS) and Streptococcus mutans viability were used to evaluate the mechanical strength and antibacterial activity of the cements. Fuji II LC cement was used as control. The specimens were conditioned in distilled water at 37 degrees C for 24 h prior to testing. The effects of the substitute chain length, loading as well as gra...

2011-01-01

96

NAME=\\  

Wastenet

...Synthesis of low-temperature, fast, single-firing body for porcelain stoneware tiles with coal gangue Synthesis of low-temperature, fast, single-firing body for porcelain stoneware ... tiles with coal gangue Synthesis of low-temperature, fast, single-firing body for porcelain stoneware tiles with coal gangue Wei et al.,... Article Synthesis of low-temperature, fast, single-firing body for porcelain stoneware tiles with coal gangue Qiangwei Wei1, Wenyuan Gao1*, and Xinguo ...According to phase diagram theory, a low-temperature, fast, single-firing body mix for porcelain stoneware tiles was designed in the quaternary system CaO-MgO-Al2O3-SiO2, using ...

97

Synthesis of high specific activity tritium labelled [2-{sup 3}H]-adenosine-5`-triphosphate  

Energy Technology Data Exchange (ETDEWEB)

A procedure for high level tritium labelling at the C2-H position of adenosine 5`-triphosphate ([2-{sup 3}H]-ATP, 1), based on the tritiodehalogenation reaction of 2-bromoadenosine 5`-triphosphate (2) has been elaborated. This precursor was prepared in a six-step synthesis from guanosine. The tritiodehalogenation of (2) for three hours over palladium oxide in phosphate buffer yielded tritium labelled ATP with high specific activity, in good chemical yield. (author).

1996-08-01

98

Phase diagrams  

International Nuclear Information System (INIS)

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

99

Magnetic properties of some RPd_2Si_2 compounds (R = Gd, Tb, Dy, Ho and Er)  

International Nuclear Information System (INIS)

The magnetic susceptibility of the ternary compounds, RPd_2Si_2 (where R=Gd, Tb, Dy, Ho and Er) has been measured. GdPd_2Si_2 and TbPd_2Si_2 order antiferromagnetically at 13 and 20 K respectively; the rest of the compounds do not show clear ordering down to 4.2 K. Palladium carries no moment in these compounds. The De Gennes formula is not obeyed indicating that the exchange interaction between the 4f moments via conduction electrons is not isotropic. (orig.).

100

Hydrogen electrocatalysis on overlayers of rhodium over gold and palladium substrates-more active than platinum?  

Science.gov (United States)

We have investigated the stability and catalytic activity of epitaxial overlayers of rhodium on Au(111) and Pd(111). Both surfaces show a strong affinity for hydrogen. We have calculated the energy of adsorption both for a strongly and a more weakly adsorbed species; the latter is the intermediate in the hydrogen evolution reaction. Both the energy of activation for hydrogen adsorption (Volmer reaction) and hydrogen recombination (Tafel reaction) are very low, suggesting that these overlayers are excellent catalysts. PMID:21847482

2011-08-16

101

Effect of Inner Electrode on Electrical Properties of (Zn,Mg)TiO3-Based Multilayer Ceramic Capacitor  

Science.gov (United States)

In this study, different proportions of silver-palladium alloy used as an inner electrode are adopted to fabricate (Zn,Mg)TiO3-based multilayer ceramic capacitors. Effects of sintering temperature, and measuring frequency on the dielectric properties of the samples with different proportions of the Pd-Ag inner electrode are investigated. The continuity of the inner electrode and the proportion of Pd-Ag of the inner electrode of samples sintered at different temperatures play important roles in determining the dielectric properties.

2005-12-01

102

Preparation and Crystal Structure of the Equiatomic Rare Earth Palladium Silicides NdPdSi, SmPdSi, alpha-GdPdSi, and alpha-TbPdSi  

Science.gov (United States)

The title compounds were prepared by arc-melting of the elemental components. Whereas NdPdSi and SmPdSi are already present after the arc-melting, alpha-GdPdSi and alpha-TbPdSi are formed only during the annealing at 800 degC. The four compounds crystallize with the recently reported alpha-YbAuGe type structure, which was refined for alpha-GdPdSi: Pnma, a=2108.0(4) pm, b=433.9(1) pm, c=745.6(1) pm, Z=12, R=0.026 for 1447 structure factors and 62 variable parameters. The lanthanoid atoms are situated between two-dimensionally infinite nets of condensed, puckered hexagons formed by alternating palladium and silicon atoms, with Pd-Si distances varying between 251 and 262 pm. In the third dimension these nets are linked via weak Pd-Pd (300 pm), Pd-Si (283 pm), and Si-Si bonds (261 pm). The refinements of the occupancy parameters suggested that ca. 2% of the palladium sites are occupied by silicon atoms and vice versa. The structural relationships ...

1999-01-01

103

Curious Results with Palladium- and Platinum-Carrying Polymers in Mass Cytometry Bioassays and an Unexpected Application as a Dead Cell Stain.  

Science.gov (United States)

We describe the synthesis of metal-chelating polymers (MCPs) with four different pendant polyaminocarboxylate ligands (EDTA, DTPA, TTHA, DOTA) and an orthogonal end-group, either a fluorescein molecule or a bismaleimide linker for antibody attachment. Polymer characterization by a combination of (1)H NMR, UV/vis absorption measurements, and thermal gravimetric analysis (TGA) indicated that each chain of the fluorescein-terminated polymers contained one dye molecule. These polymer samples were loaded with three different types of lanthanide ions as well as palladium and platinum ions. The numbers of metal atoms per chain were determined by a combination of UV/vis and conventional ICP-MS measurements. The experiments with lanthanide ions demonstrated that a net anionic charge on the polymer is important for water solubility. These experiments also showed that at least one type of lanthanide ion (La(3+)) is capable of forming a bimetallic complex with pendant DTPA ...

2011-09-28

104

Recovery and mutual separation of noble metals from the simulated insoluble residue of spent fuel  

International Nuclear Information System (INIS)

The recovery of noble metals from the quaternary Mo-Ru-Rh-Pd alloy in the simulated insoluble residue was studied by means of Pb extraction and the recovery yield was found to be more than 90% for Ru, Rh and Pd. The recovery yield of Mo was very small due to the oxidative vaporization in air. The decontamination factor for Ce as a stand-in of Pu was determined to be around 200 for one stage. These results on the recovery yields of noble metals from the quaternary alloy and the decontamination factor for Ce are in good agreement with those for the ternary Mo-Ru-Pd alloy previously reported by the present authors. The mutual separation of noble metal elements recovered in Pb button was examined by means of re-extraction with molten Zn and the dissolution in boiling 3M or 6M nitric acid solution. The dissolution fractions of Pd and Rh recovered in the Pb button in boiling 3M and 6M nitric acid solution for 12 h were about 90 and 30%, respectively, ...

105

New molten salt systems for high temperature molten salt batteries: Ternary and quaternary molten salt systems based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr  

British Library Electronic Table of Contents (United Kingdom)

Using a new simulative technique developed by us, we systematically investigated new ternary or quaternary molten salt systems, which are based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr binary systems, for use as electrolytes in thermal batteries, and evaluated their ionic conductivities and melting points experimentally. It was confirmed experimentally that LiF-LiBr-KF (melting point: 425^oC, ionic conductivity at 500^oC: 2.52Scm^-^1), LiCl-LiBr-KF (405^oC, 2.56Scm^-^1), LiCl-LiBr-NaF-KF (425^oC, 3.11Scm^-^1), LiCl-LiBr-NaCl-KCl (420^oC, 2.73Scm^-^1), and LiCl-LiBr-NaBr-KBr (420^oC, 2.76Scm^-^1) meet our targets for both melting point (350-430^oC) and ionic conductivity (2.0Scm^-^1 and higher at 500^oC). A single cell using the newly developed LiCl-LiBr-NaCl-KCl molten salt as an electrolyte w...

2011-01-01

106

Late Quaternary high resolution sequence stratigraphy of an active rift, the Sperchios Basin, Greece: An analogue for subtle stratigraphic plays  

Energy Technology Data Exchange (ETDEWEB)

The Sperchios Basin is an active asymmetric graben, bounded to the south by a major border fault system with major fault segments typically 20-30 km long. The basin is dominated by a major axial fluvio-deltaic system which enters the partially enclosed Maliakos Gulf to the east. Lateral sourced depositional systems within the basin comprise hanging-wall and footwall-derived alluvial fans and a narrow coastal plain along the footwall scarp bordering the Maliakos Gulf. High resolution seismic data from the Maliakos Gulf reveals three late Quaternary progradational parasequences sourced from axial and lateral depositional systems, with a regional late-Pleistocene transgressive surface dated at circa. 10 ka BP within the Maliakos Gulf. Differential subsidence of the late Pleistocene transgressive surface indicates marked variation in subsidence from 2.4 m ka[sup -1] at fault segment centers to 0.8 m ka[sup -1] at segment boundaries. The geometry and internal ...

1996-01-01

107

Late Quaternary high resolution sequence stratigraphy of an active rift, the Sperchios Basin, Greece: An analogue for subtle stratigraphic plays  

Energy Technology Data Exchange (ETDEWEB)

The Sperchios Basin is an active asymmetric graben, bounded to the south by a major border fault system with major fault segments typically 20-30 km long. The basin is dominated by a major axial fluvio-deltaic system which enters the partially enclosed Maliakos Gulf to the east. Lateral sourced depositional systems within the basin comprise hanging-wall and footwall-derived alluvial fans and a narrow coastal plain along the footwall scarp bordering the Maliakos Gulf. High resolution seismic data from the Maliakos Gulf reveals three late Quaternary progradational parasequences sourced from axial and lateral depositional systems, with a regional late-Pleistocene transgressive surface dated at circa. 10 ka BP within the Maliakos Gulf. Differential subsidence of the late Pleistocene transgressive surface indicates marked variation in subsidence from 2.4 m ka{sup -1} at fault segment centers to 0.8 m ka{sup -1} at segment boundaries. The geometry and internal ...

1996-12-31

108

Geology And Radioactivity of Gabal Halal, Northern Sinai, Egypt  

International Nuclear Information System (INIS)

Gabal Ralal is one of the major asymmetrical doubly- plunging anticlinal fold belts (50 Km length) related to the Syrian Arc System in northern Sinai, Egypt. The exposed rock units at Gabal Ralal range from Cretaceous to Quaternary and are divided into eight formations which are from base to top: Malha, Ralal, Wata, Themed, Sudr, Beida, Egma and Quaternary wadi deposits. The image processing is applied using Landsat-7 satellite data to discriminate structure and lithology for defining the horizons of the radioactive anomalies of each rock unit. The extracted structural lineaments, using Ge Analyst-PCl package, from digital ETM data showed that the main structural trends are NE-SW and NW-SE normal faults which originated as extensional fractures with lateral dip-slip displacement. The axial trace of Gabal Ralal fold is curved and plunging to Wand SW directions while the northeastern part (Gabal Dalfa) is plunging to NE direction. The use of ...

109

Deep-ocean record of major late Cenozoic rhyolitic eruptions from New Zealand  

International Nuclear Information System (INIS)

A 12 m.y. record of large rhyolitic eruptions from the Coromandel (CVZ) and Taupo (TVZ) volcanic zones of New Zealand is contained in cores retrieved by Leg 181 of the Ocean Drilling Program. Site 1124, located 670 km from the TVZ, has a maximum of 134 macroscopic tephra layers with a total thickness of 13.18 m. These units, along with between 7 and 63 tephras from 3 other sites, were dated by a combination of magnetostratigraphy, biostratigraphy, isothermal plateau fission track determinations, and geochemical correlation with onshore tephra deposits. Additional time control for the last 3 m.y. came from an orbitally tuned, benthic, oxygen isotope profile for Site 1123. Results extend the incomplete terrestrial record of volcanism by placing the first major rhyolitic eruption in the CVZ at c. 12 Ma, c. 1.6-1 m.y. earlier than previously known. Tephras became thicker and more frequent from the late Miocene into the Quaternary - a trend that probably reflected (1) ...

2004-09-01

110

The actin content of fibroblasts.  

UK PubMed Central (United Kingdom)

Cultures of chick skin fibroblasts were dissolved in solutions of sodium dodecyl sulphate, and their entire protein content was examined by gel electrophoresis. The most abundant species migrated in...Full Text Available

1975-05-01

111

Fiber Reinforced Superalloys - NASA Technical Reports Server  

Science.gov (United States)

hlgh fiber content composites met the minlmum requirements. (1400 O F ) , the hlgher fiber content as-fabricated composites have impact strengths distinctly ...

112

Content analysis of cancer blog posts*  

UK PubMed Central (United Kingdom)

Objectives:The efficacy of user-defined subject tagging and software-generated subject tagging for describing and organizing cancer blog contents was explored.Methods:The...Full Text Available

2009-10-01

115

Optimization of lead content in bismuth (2223) superconductor  

International Nuclear Information System (INIS)

In the present study the Pb content in Bi(2223) phase by regression or curve fitting method are optimized. The best fitting curve can be obtained by the method of least square. To study the effect of Pb content in Pb substituted Bi (2223) superconductors, prepared by solid state reaction method data is obtained. The deviation of T_c from the target value for different Pb content is summarized

2003-01-29

116

Microwave Oven for the Rapid Determination of Total Solids Content of Natural Rubber Latex  

British Library Electronic Table of Contents (United Kingdom)

The suitability of using the microwave oven for the rapid determination of total solids content (TSC) of natural rubber latex has been established over a broad range of dry rubber content (DRC). The total solids content values obtained by the microwave oven method are compared with the values obtained by heating in a conventional convection oven. Heating in a microwave oven is advantageous as the measurement time could be reduced considerably.

2008-01-01

121

The effect of temperature on the grain growth of nanocrystalline metals and its simulation by molecular dynamics method  

British Library Electronic Table of Contents (United Kingdom)

In this study, the thermodynamic stability of the grain boundaries and the grain growth of nanocrystalline Palladium (Pd) at various temperatures were investigated. For this purpose, the Gibbs free energy curves of grain boundaries were plotted in terms of the excess volume by the use of the equation of state (EOS) and Song's thermodynamic models. The results showed that, according to the prediction of these models, the nanocrystalline growth in metals was stopped at the grain sizes less than the critical grain size. Also, the results of the temperature variations and its effect on the Gibbs free energy curves showed that by the increase of the temperature, the possibility for the stoppage of grain growth is facilitated and the critical grain size is increased. To investigate the validity ...

2012-01-01

122

Supercritical Fluid Immersion Deposition: A New Process for Selective Deposition of Metal Films on Silicon Substrates  

Energy Technology Data Exchange (ETDEWEB)

Supercritical CO2 is used as a new solvent for immersion deposition, a galvanic displacement process traditionally carried out in aqueous HF solutions containing metal ions, to selectively develop metal films on featured or non-featured silicon substrates. Components of supercritical fluid immersion deposition (SFID) solutions for fabricating Cu and Pd films on silicon substrates are described along with the corresponding experimental setup and procedure. Only silicon substrates exposed and reactive to SFID solutions can be coated. The highly pressurized and gas-like supercritical CO2, combined with the galvanic displacement property of immersion deposition, enables the SFID technique to selectively deposit metal films in small features. SFID may also provide a new method to fabricate palladium silicide in small features or to metallize porous silicon.

2005-01-01

123

Study of surface segregation of Si on palladium silicide using Auger electron spectroscopy  

International Nuclear Information System (INIS)

The transformation of Pd/Si to Pd_2Si/Si is studied using Auger electron spectroscopy over a wide temperature range of 370-1020 K. The Pd film gets totally converted to Pd_2Si upon annealing at 520 K, and beyond 570 K, Si starts segregating on the surface of silicide. It is found that the presence of surface oxygen influences the segregation of Si. The time evolution study of Si segregation reveals that segregation kinetics is very fast and the segregated Si concentration increases as the temperature is increased. Scanning electron microscopy measurements show that Pd_2Si is formed in the form of islands, which grow as the annealing temperature is increased.

2004-11-21

124

Reversing flow catalytic converter for a natural gas/diesel dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

An experimental and modelling study was performed for a reverse flow catalytic converter attached to a natural gas/diesel dual fuel engine. The catalytic converter had a segmented ceramic monolith honeycomb substrate and a catalytic washcoat containing a predominantly palladium catalyst. A one-dimensional single channel model was used to simulate the operation of the converter. The kinetics of the CO and methane oxidation followed first-order behaviour. The activation energy for the oxidation of methane showed a change with temperature, dropping from a value of 129 to 35 kJ/mol at a temperature of 874 K. The reverse flow converter was able to achieve high reactor temperature under conditions of low inlet gas temperature, provided that the initial reactor temperature was sufficiently high. (author)

2001-07-01

125

Reaction technical and structural investigations of Pd/Ag-layers produced by electrodeposition; Reaktionstechnische und strukturelle Untersuchungen an galvanisch erzeugten Pd/Ag-Schichten  

Energy Technology Data Exchange (ETDEWEB)

Membranes in Palladium and its alloys, in particular Pd/Ag alloys, are selectively permeable to hydrogen and can therefore be used to purify hydrogen. It is intended to use them as material for electrodes in fuel cells. As the manufacturing process of a substrate Pd/Ag-layer consists of several stages and is still not completely understood, it would be advantageous to be able to characterise separately the layers of noble metals obtained by electro-plating . Attempts are being made in this work to vary the cristallographical structure of the deposited alloy by the choice of test parameters and by sintering when depositing the Pd/Ag. The layers produced are to be examined using an interference microscope and X-ray diffraction. Moreover, the diffusion behaviour of the hydrogen is to be examined with an electro-chemical pulse method specifically developed for this purpose. figs., tabs., 27 refs.

1991-03-01

126

Parallelization of the FLAPW method  

International Nuclear Information System (INIS)

The FLAPW (full-potential linearized-augmented plane-wave) method is one of the most accurate first-principles methods for determining electronic and magnetic properties of crystals and surfaces. Until the present work, the FLAPW method has been limited to systems of less than about one hundred atoms due to a lack of an efficient parallel implementation to exploit the power and memory of parallel computers. In this work we present an efficient parallelization of the method by division among the processors of the plane-wave components for each state. The code is also optimized for RISC (reduced instruction set computer) architectures, such as those found on most parallel computers, making full use of BLAS (basic linear algebra subprograms) wherever possible. Scaling results are presented for systems of up to 686 silicon atoms and 343 palladium atoms per unit cell, running on up to 512 processors on a CRAY T3E parallel computer.

1999-12-01

127

Magnetic properties of some RPd/sub 2/Si/sub 2/ compounds (R = Gd, Tb, Dy, Ho and Er)  

Energy Technology Data Exchange (ETDEWEB)

The magnetic susceptibility of the ternary compounds, RPd/sub 2/Si/sub 2/ (where R=Gd, Tb, Dy, Ho and Er) has been measured. GdPd/sub 2/Si/sub 2/ and TbPd/sub 2/Si/sub 2/ order antiferromagnetically at 13 and 20 K respectively; the rest of the compounds do not show clear ordering down to 4.2 K. Palladium carries no moment in these compounds. The De Gennes formula is not obeyed indicating that the exchange interaction between the 4f moments via conduction electrons is not isotropic.

1982-10-01

128

Low energy ion scattering study of palladium films on silicon(111)-7 x 7 surfaces  

Energy Technology Data Exchange (ETDEWEB)

The initial growth process and surface structure of thin Pd(silicide) films on clean Si(111)-7x7 surfaces have been studied by low energy ion scattering (ISS) and LEED-Auger techniques. Considerable reaction between Pd and Si at room temperature is observed to extend up to 25 ML thickness of deposited Pd. Heat treatment of the room temperature film produced epitaxial silicide Pd/sub 2/Si(0001) films covered with the accumulated elementary Si layers of 1-2 ML thickness. Deposition of 1/3 ML Pd onto a heated substrate gives a Pd-embedded ordered surface of Si(111)-..sqrt..3x..sqrt..3R30/sup 0/, the feature being similar to the cases of Ag, Au/Si(111) systems.

1983-12-15

129

Low energy ion scattering study of palladium films on silicon(111)-7 x 7 surfaces  

International Nuclear Information System (INIS)

The initial growth process and surface structure of thin Pd(silicide) films on clean Si(111)-7x7 surfaces have been studied by low energy ion scattering (ISS) and LEED-Auger techniques. Considerable reaction between Pd and Si at room temperature is observed to extend up to 25 ML thickness of deposited Pd. Heat treatment of the room temperature film produced epitaxial silicide Pd_2Si(0001) films covered with the accumulated elementary Si layers of 1-2 ML thickness. Deposition of 1/3 ML Pd onto a heated substrate gives a Pd-embedded ordered surface of Si(111)-#sq root#3x#sq root#3R30"0, the feature being similar to the cases of Ag, Au/Si(111) systems. (orig.).

130

Ion-induced phase formation in metal-silicon systems. [Xenon ion implantation effects  

Energy Technology Data Exchange (ETDEWEB)

By using megaelectronvolt /sup 4/He ion backscattering techniques and transmission electron microscopy, the authors have investigated the interactions of ion beams with thin film structures in a number of silicide-forming systems. The mixed layer was found to be an equilibrium compound for near-noble metals and an amorphous phase for refractory metals. Differences in behavior have also been observed in near-noble metal systems. For palladium, the Pd/sub 2/Si phase grew with ion dose and remained crystalline up to high dose. For nickel, the compound Ni/sub 2/Si was formed initially and became amorphous on prolonged irradiation. All the results indicate the significance of atomic mobility at target temperatures in determining the phase formation and in explaining the sensitivity of the silicides to ion bombardment.

1985-01-11

131

Ion-induced phase formation in metal-silicon systems  

International Nuclear Information System (INIS)

By using megaelectronvolt "4He ion backscattering techniques and transmission electron microscopy, the authors have investigated the interactions of ion beams with thin film structures in a number of silicide-forming systems. The mixed layer was found to be an equilibrium compound for near-noble metals and an amorphous phase for refractory metals. Differences in behavior have also been observed in near-noble metal systems. For palladium, the Pd_2Si phase grew with ion dose and remained crystalline up to high dose. For nickel, the compound Ni_2Si was formed initially and became amorphous on prolonged irradiation. All the results indicate the significance of atomic mobility at target temperatures in determining the phase formation and in explaining the sensitivity of the silicides to ion bombardment. (Auth.).

132

In situ ultrahigh vacuum transmission electron microscopy studies of palladium silicide island formation on silicon (111) 7x7 surface  

International Nuclear Information System (INIS)

Pd was deposited onto Si (111) 7x7 surface at approximately 700 K inside an ultrahigh vacuum transmission electron microscope. Plan-viewed transmission electron microscopy (TEM) observation indicated that the islands have two kinds of shapes, round and rectangular (one-dimensional) ones. In a diffraction pattern for the rectangular islands, extra spots along the <110> direction of the Si surface, spacing of which is 1/8 times as long as that of Si (220) spots, were seen. A high resolution TEM image showed the corresponding superstructure in the rectangular islands. In situ observation of the growing process of the rectangular islands showed repeat of introduction and relief of strains during the growth, suggesting that such superstructure would be constructed by stacking compositionally different phases or introducing defects so that the periodically maximized strain is relieved.

2003-01-22

133

In situ strain measurements during the formation of palladium silicide films  

Energy Technology Data Exchange (ETDEWEB)

The evolution of strain in the Pd-Si system during the growth of Pd{sub 2}Si thin films on Si (100) substrate has been followed in situ using a double optical beam technique. As was observed for the Pt-Si system, the reaction to form Pd{sub 2}Si yields a compressive intrinsic surface film stress as well as for the silicon-rich suicides as proposed by Angilello et al. [Thin Film Interfaces and Interactions, edited by J. Baglin and J. Poate (The Electrochemical Society, Pennington, NJ, 1980)]. A transmission electron microscopy analysis has revealed grain growth during the formation of Pd{sub 2}Si which cannot account for the compressive film stresses. The formation of silicide at the interfaces rather than the overall change in volume agrees with the sign of the stresses formed. 29 refs., 4 figs., 3 tabs.

1993-03-01

134

Double promotion of palladium/silica catalysts by iron and magnesium oxide in the synthesis of methanol from carbon monoxide and hydrogen  

Energy Technology Data Exchange (ETDEWEB)

The structure and catalytic properties of 2 wt.-% Pd/SiO/sub 2/ catalysts promoted with 2 wt.-% MgO and 0.2-5 wt.-% iron have been investigated. Catalysts were characterized by TPR, hydrogen chemisorption, and Moessbauer spectroscopy and their catalytic performance in methanol formation was also measured. At 16 at.-% iron a sharp maximum was observed in the activity which can be interpreted as being due to simultaneous promotion with iron and MgO. Independent mechanisms of promotion were found for the two modifiers: iron influenced the metallic component by forming bimetallic PdFe particles while MgO changed the properties of silica in a favourable way. 6 figs., 29 refs., 1 tab.

1988-12-01

135

Diffusion examined by diffraction  

Science.gov (United States)

X-ray diffraction offers a unique combination of advantages for kinetic study which include the non-destructive nature of the measurement, the use of bulk crystals, and the convenience of the experimental arrangements. These attributes and the availability of position-sensitive detectors and high-flux synchrotron radiation sources make this technique most useful for in situ, dynamical investigations. When using diffraction techniques to determine a diffusion coefficient, the principle of analysis entails a scattering theory and a kinetic model. The former allows the kinetic parameter(s) to be extracted from measured intensity, while the latter relates the kinetic parameter(s) to the diffusion coefficient(s). Three examples are demonstrated: (1) Palladium Silicide (Pd{sub 2}Si) Layer Growth on Silicon, (2) Decomposition of an Ni-12.5at%Si Superalloy, and (3) Short-range Ordering in Cu-Au Solid Solutions.

136

The effects of the stoichiometry and synthesis temperature on the preparation of the inverse spinel LiNiVO{sub 4} and its performance as a new high voltage cathode material  

Energy Technology Data Exchange (ETDEWEB)

The high temperature solid-state reaction between LiNiO{sub 2} and V{sub 2}O{sub 3} (or V{sub 2}O{sub 5}) in air used to prepare LiNiVO{sub 4} has been further studied. This quaternary Li-Ni-V-O reaction is strongly dependent on reaction temperature and lithium stoichiometry in Li{sub x}Ni{sub 2-x}O{sub 2} and has produced a highly crystalline LiNiVO{sub 4} material whose structure has been confirmed to be an inverse spinel by Rietveld analysis with a Bragg R-factor of 1.18 in the absence of crystal orientation preference. The cell performance of LiNiVO{sub 4} prepared at various temperatures or by varying x-values in Li{sub x}Ni{sub 2-x}O{sub 2} has been examined in lithium coin cells and indicated that preparation at low temperatures or when x=0.89 provided an electrode material with higher cell capacity. (orig.)

1997-10-01

137

Preliminary study of the application of natural olivine in Cenozoic dating  

Energy Technology Data Exchange (ETDEWEB)

The study investigated the luminescence behaviour of natural olivine to discuss the potential for Cenozoic (quaternary) dating. The UV-blue thermoluminescence (TL) glow curves of irradiated olivines have a resolved peak at 190 deg. C and other peaks at higher temperature at lower dose levels, and broad signals around 275-310 and 375-400 deg. C at higher dose levels. The UV-blue TL increases with additional laboratory dose to {approx}1.6kGy within a plateau temperature region, suggesting the possibility of dosimetry and Cenozoic dating. Both infrared stimulated luminescence (IRSL) and blue light stimulated luminescence (BLSL) were detected from laboratory-irradiated olivines although the BLSL was weaker than the IRSL. Furthermore, post-BL IRSL was detected but post-IR BLSL was not observed. Therefore, IR stimulation is recommended for optically stimulated luminescence measurements with natural olivine. The growth of the IRSL signal component with doses less than ...

2006-08-15

138

Large single crystal quaternary alloys of IB-IIIA-SE.sub.2 and methods of synthesizing the same  

Energy Technology Data Exchange (ETDEWEB)

New alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2 (where x ranges between 0 and 1 and preferably has a value of about 0.75) and CuIn.sub.y Ga.sub.(1-y) Se.sub.2 (where y ranges between 0 and 1 and preferably has a value of about 0.90) in the form of single crystals with enhanced structure perfection, which crystals are substantially free of fissures are disclosed. Processes are disclosed for preparing the new alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2. The process includes placing stoichiometric quantities of a Cu, Ag, In, and Se reaction mixture or stoichiometric quantities of a Cu, In, Ga, and Se reaction mixture in a refractory crucible in such a manner that the reaction mixture is surrounded by B.sub.2 O.sub.3, placing the thus loaded crucible in a chamber under a high pressure atmosphere of inert gas to confine the volatile Se to the crucible, and heating the reaction mixture to its melting point. The melt can then be cooled slowly to form, by direct solidification, a single crystal ...

1988-01-01

139

High power (1,4W) AlGaInP graded-index separate confinement heterostructure visible (. lambda. -658 nm)laser  

Science.gov (United States)

A high power AlGaInP single quantum well graded index separate confinement heterostructure. It comprises a substrate and a multiplicity of layers deposited thereon comprising a single Ga{sub x}In{sub x}P quantum well where x has a value from about 0.4 to about 0.6; multiple graded index regions on both sides of the quantum well and cladding layers adjacent to each graded region of the well, the graded region comprising Al{sub y}(Ga{sub 1{minus}y}){sub 0.5}In{sub 0.5}P quaternary alloy; wherein the value of y in the graded region varies from about 0.2 at the quantum well/graded region interface to up to about 0.6 for the cladding layers/graded index regions; the heterostructure having a low broad area threshold current with pulsed thresholds in the range from about 1 to about 2 Amps/cm{sup 2} and a differential efficiency of from about 20 to about 60 percent.

1991-03-26

140

Gulf of Mexico petroleum accumulations a review of recent studies on sources of the oils, modes of source rock maturation and oil migration  

Energy Technology Data Exchange (ETDEWEB)

Recent organic geochemical studies differ radically in their interpretation of the origin of the Gulf coast oils. However all studies since (and including) Thompson, et al. 1989, emphasize the considerable geographic variation in genetic oil types and are in generalized agreement as to the genetic oil types present and their spatial and stratigraphic relationships. In particular it is accepted that the Gulf rim (both north and south) is encircled by a ring of Mesozoic carbonate-sourced oils and that there is also at least one major deep water trend of carbonate-sourced oils in the northern Gulf. It is also generally agreed that many of the Gulf rim oils are of Oxfordian-Kimmeridgian age, though some, like the Sunniland oils of Florida, are of lower Cretaceous origin. Major disagreement still occurs over the sources of the Louisiana offshore oils and onshore Wilcox reservoired oils. One {open_quotes}school of thought{close_quotes} assigns all these oils to Mesozoic sources. The other ...

1996-09-01

141

Geology of the lower Yellow Creek area, northwestern Colorado  

Energy Technology Data Exchange (ETDEWEB)

The geology and resources of the lower Yellow Creek area, an area at the northwestern margin of the Piceance Creek basin comprising of four 7.5-minute quadrangles, are described. Subsurface face rocks penetrated by drill holes range in age from Pennsylvania to Cretaceous. Measured sections show the Mancos Shale and the Castlegate Sandstone, Iles Formation, and Williams Fork Formation of the Mesaverde Group of Late Cretaceous age and the Fort Union, Wasatch, Green River, and Uinta formations of Tertiary age. Surficial deposits of Quaternary age include terrace gravels, alluvium, and landslides. Fold axes and faults in the area trend northwesterly. The southern part of the area contains major oil-shale resources. Coal-bearing zones in the Williams Fork and Iles formations contain considerable coal. The coal-resources potential is limited, however, by nonpersistence of the thicker coal beds. Small amounts of gas have been produced from shallow, lenticular Tertiary ...

1990-01-01

142

Geology of the central Roan Plateau area, northwestern Colorado  

Energy Technology Data Exchange (ETDEWEB)

The geology of the central Roam Plateau area in the south-central part of the Piceance Creek basin, comprising four 7.5-minute quadrangles, is described. Subsurface rocks penetrated by drill holes include the Mancos Shale and Mesaverde Formation of Later Cretaceous age, and parts of the Wasatch Formation of Paleocene and Eocene age, and Green River Formation of Eocene age. Exposed rocks, aggregating as much as 4,550 feet in thickness, are all Eocene in age and include the upper part of the Wasatch Formation , and the Green River and Uinta formations. The Green River and Uinta formations are extensively intertongued. Surficial deposits of Quaternary age include alluvium, talus, slopewash, and landslides. Two northwesterly trending folds, the Clear Creek Syncline and the Crystal Creek anticlinal nose, are present in the northern part of the area. There are no major faults. The area contains large potentially important oil-shale resources, mostly in the Parachute ...

1992-01-01

143

ESR dating of fault rocks  

Energy Technology Data Exchange (ETDEWEB)

Past movement on faults can be dated by measurement of the intensity of ESR signals in quartz. These signals are reset by local lattice deformation and local frictional heating on grain contacts at the time of fault movement. The ESR signals then grow back as a result of bombardment by ionizing radiation from surrounding rocks. The age is obtained from the ratio of the equivalent dose, needed to produce the observed signal, to the dose rate. Fine grains are more completely reset during faulting, and a plot of age vs. grain size shows a plateau for grains below critical size; these grains are presumed to have been completely zeroed by the last fault activity. We carried out ESR dating of fault rocks collected near the Gori nuclear reactor. Most of the ESR signals of fault rocks collected from the basement are saturated. This indicates that the last movement of the faults had occurred before the Quaternary period. However, ESR dates from the Oyong fault zone range ...

2003-02-15

144

Band parameters for III - V compound semiconductors and their alloys  

International Nuclear Information System (INIS)

We present a comprehensive, up-to-date compilation of band parameters for the technologically important III - V zinc blende and wurtzite compound semiconductors: GaAs, GaSb, GaP, GaN, AlAs, AlSb, AlP, AlN, InAs, InSb, InP, and InN, along with their ternary and quaternary alloys. Based on a review of the existing literature, complete and consistent parameter sets are given for all materials. Emphasizing the quantities required for band structure calculations, we tabulate the direct and indirect energy gaps, spin-orbit, and crystal-field splittings, alloy bowing parameters, effective masses for electrons, heavy, light, and split-off holes, Luttinger parameters, interband momentum matrix elements, and deformation potentials, including temperature and alloy-composition dependences where available. Heterostructure band offsets are also given, on an absolute scale that allows any material to be aligned relative to any other. [copyright] 2001 American Institute of ...

2001-06-01

145

Aluminum-containing intergranular phases in hot-pressed silicon carbide  

Energy Technology Data Exchange (ETDEWEB)

Aluminum-containing intergranular phases, forming intergranular films and secondary phase particles at triple-junctions in SiC hot-pressed with aluminum, boron, and carbon additions, were studied by transmission electron microscopy. Statistical high-resolution electron microscopy study of intergranular films indicated that a large fraction of the vitreous intergranular films in the s-hot-pressed SiC crystallized during postannealing in argon above 1000 C. However, brief heating to 1900 C indeed re-melted 25 percent of the crystallized intergranular films. The structural transitions were reflected in the statistical width distributions of the amorphous grain boundary layers. At triple-junctions, Al2O3, Al2OC-SiC solid solution, and mullite phases were newly identified. These phases,together with others reported before are represented in a quaternary phase diagram for 1900 C. It is proposed that a SiC-Al2OC liquid domain is to be included in this phase diagram.

2003-01-12

146

Aerial gamma ray and magnetic survey: Idaho Project, Idaho Falls quadrangle, Idaho. Final report  

International Nuclear Information System (INIS)

The Idaho Falls quadrangle in southeastern Idaho lies at the juncture of the Snake River Plain, the Northern Rocky Mountains, and the Basin-Range Province. Quaternary basalts of the Snake River Plain occupy 70% of the quadrangle. The rest of the area is covered by uplifted Paleozoic, Mesozoic, and Cenozoic rocks of the Pre-Late Cenozoic Orogenic Complex. Magnetic data apparently show contributions from both shallow and deep sources. The apparent expression of intrusive and extrusive rocks of late Mesozoic and Cenozoic age tends to mask the underlying structural downtrap thought to exist under the Snake River Plain. The Idaho Falls quadrangle has been unproductive in terms of uranium mining. A single claim exists in the Sawtooth Mountains, but no information was found concerning its present status at the time of this study. A total of 169 anomalies are valid according to the criteria set forth in Volume I of this report. These anomalies are scattered throughout the ...

147

The bone mineral content and ultimate compressive strength of lumbar vertebrae.  

Science.gov (United States)

The bone mineral content of 109 lumbar vertebrae from 36 different subjects was determined by dual photon absorptiometry. The mean age of the subjects was 58.5 years (range, 31 to 79 years). The ultimate strength of the vertebral bodies was determined during axial compression. Bone mineral content and ultimate compressive strength were correlated (r = 0.86) and the strength was found to increase linearly with increasing amounts of bone mineral content. No differences in this correlation were found in the four vertebral levels (L-4) included in the study, but a difference in this correlation was found between specimens taken from male and female subjects. The results make it possible to estimate the strength of a vertebral body from the knowledge of its bone mineral content as determined by dual photon absorptiometry and provide a basis of estimations of normal and abnormal amounts of bone mineral ...

148

Theoretical study on antitumor activity of palladium(II) and platinum(II) complexes with isoxazole and its derivatives  

Energy Technology Data Exchange (ETDEWEB)

The palladium(II) and platinum(II)complexes(where, (M(L){sub 2}X{sub 2}), M=Pd(II), Pt(II); L=isoxazole (isox), 3, 5-dimethylisoxazole(3, 5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Ph-isox), and 4-amino-3, 5-di-methylisoxazole (4-ADI); X=Cl, Br) with isoxazole and its derivatives were investigated on antitumor activity by MM2 and EHMO calculation. Because for all the complexes the {sigma}MO energy level (E{sub {sigma}}{sub (M-X)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of halogen atom is less than {sigma}MO energy level E{sub {sigma}}{sub (M-N)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of N atom, without exception. And judging, from the lower E{sub {sigma}}{sub (M-X)} value in trans, the bonding strength was found to be weaker in trans isomer than in cis. For the Pd(II) and Pt(II) complexes which have planar ligands, it was shown that for all the complexes dissociation of ...

1998-02-01

149

The development of emissions of heavy metals in the Federal Republic of Germany from 1985 to 1995; Die Entwicklung der Schwermetallemissionen in der Bundesrepublik Deutschland von 1985 bis 1995  

Energy Technology Data Exchange (ETDEWEB)

Emission inventories were estimated for the airborne emissions of: Arsenic, Beryllium, Cadmium, Chromium, Cobalt, Copper, Mercury, Manganese, Molybdenum, Nickel, Lead, Antimony, Selenium, Tellur, Thallium, Zinc, Platinum, Palladium, Rhodium, Tin. The inventories were made for the status of 1985 and 1990. A prognosis was given for 1995. The investigations were made for the whole area of the Federal Republic of Germany including the former German Democratic Republic. Working point was an overview about the plant-specific emissions for the various industrial branches and the production statistics. The results are given as total emissions from the existing plants and industrial branches. (orig.) [Deutsch] Es erfolgte eine Abschaetzung der luftseitigen Emissionen fuer die Elemente: Arsen, Beryllium, Cadmium, Chrom, Kobalt, Kupfer, Quecksilber, Mangan, Molybdaen, Nickel, Blei, Antimon, Selen, Tellur, Thallium, Zink, Platin, Palladium, Rhodium und ...

1995-03-01

150

The crystal structure of YPdSi, the isotopic compounds LnPdSi (Ln=Gd-Lu), and their structural relation to some other equiatomic compounds of the rare earth and transition metals with main group elements  

International Nuclear Information System (INIS)

The nine title compounds were prepared from the elements by arc-melting and subsequent heat treatment in resistance and high-frequency furnaces. The crystal structure of these isotypic compounds was determined for YPdSi from single-crystal X-ray diffractometer data: Pmmn, a = 430.8(1) pm, b = 1391.2(1) pm, c = 743.1(1) pm, Z = 8, R = 0.024 for 417 structure factors and 40 variable parameters. The crystal structures of the isotypic compounds GdPdSi and ErPdSi were also refined from single-crystal data. The structure is of a new type. It consists of condensed, six-membered rings of alternating palladium and silicon atoms with Pd-Si bond distances varying between 249.6 and 258.8 pm. These two-dimensionally infinite nets are connected to each other via weak Pd-Si and Si-Si bonds with bond distances of 276.3 and 259.5 pm. The rare earth atoms are situated above and below the six-membered palladium-silicon rings in a manner as it is known for the ...

151

Spectroscopic Studies of Phosphazene Polymers Containing Photoluminescent Metal Complexes  

British Library Electronic Table of Contents (United Kingdom)

Abstract A series of small phosphazene ligands with pendant 6-phenyl-2,2--bipyridyl moieties, namely L1 [N3P3(OPh)5(OPhbpyPh)], L2 [N3P3(biph)2(OPhbpyPh)2], L3 [N3P3(tBubiph)2(OPhbpyPh)2], L4 [N3P3(biph)2(OPhbpyPh)Cl] and L5 [N3P3(biph)2(OPhbpyPh)(OPh)] [OPhbpyPh = 4-(4-phenoxy)-6-phenyl-2,2--bipyridine, OPh = phenoxy, biph = 2,2--oxybiphenyl and tBubiph = 4,4--di-tert-butyl-2,2--oxybiphenyl], have been used to synthesise the new cyclometallated palladium(II) and platinum(II) complexes [(L1-H)PdCl], [(L1-H)PtCl], [(L1-H)(PdCl)2], [(L3-H)(PdCl)2], [(L4-H)PtCl], [(L5-H)PtCl] and the rhenium(I) complex [L5Re(CO)3Cl]. Single-crystal X-ray diffraction analysis was performed on the free ligand L2 and the palladium complexes [(L1-H)PdCl] and [(L3-H)(PdCl)2]. In both PdII complexes, the metal cent...

2011-01-01

152

Probing anodic reaction kinetics and interfacial mass transport of a direct formic acid fuel cell using a nanostructured palladium-gold alloy microelectrode  

International Nuclear Information System (INIS)

The anodic reaction kinetics and interfacial mass transport of a direct polymer electrolyte membrane formic acid fuel cell have been investigated in an all solid-state electrochemical cell using a highly active nanostructured palladium-gold alloy microelectrode as an in situ probe. Well-defined 'S-shaped' steady-state cyclic voltammograms exhibiting current-rising region at lower overpotentials and limiting current region at higher overpotentials have been first obtained for the electrochemical oxidation of formic acid at varying temperature. The 'S-shaped' steady state polarization curves and chronoamperometric curves enable convenient measurements of the anodic reaction kinetics and interfacial mass transport of formic acid under real polymer electrolyte membrane conditions. It is encouragingly found that formic acid can be directly oxidized to CO2 with the first electron transfer being the likely rate-determining step and the formation of surface poison can be ...

2009-07-30

153

Experimental and modelling study of reverse flow catalytic converters for natural gas/diesel dual fuel engine pollution control  

Energy Technology Data Exchange (ETDEWEB)

There is renewed interest in the development of natural gas vehicles in response to the challenge to reduce urban air pollution and consumption of petroleum. The natural gas/diesel dual fuel engine is one way to apply natural gas to the conventional diesel engine. Dual fuel engines operating on natural gas and diesel emit less nitrogen oxides, and less carbon soot to the air compared to conventional diesel engines. The problem is that at light loads, fuel efficiency is reduced and emissions of hydrocarbons and carbon monoxide are increased. This thesis focused on control methods for emissions of hydrocarbons and carbon monoxide in the dual fuel engine at light loads. This was done by developing a reverse flow catalytic converter to complement dual fuel engine exhaust characteristics. Experimental measurements and numerical simulations of reverse flow catalytic converters were conducted. Reverse flow creates a high reactor temperature even when the engine is run at low exhaust ...

2000-07-01

154

Ab initio calculations of the electronic structure of the silver palladium oxide Ag_2PdO_2  

International Nuclear Information System (INIS)

Ab initio calculations of the electronic structure were performed for the silver palladium oxide, Ag_2PdO_2, by the full potential mixed linearized augmented plane wave and augmented plane wave plus local orbitals method (mixed LAPW/APW+lo) within the density functional theory and using the generalized gradient approximation (GGA96, Phys. Rev. Lett. 77 (1996) 3865) for the exchange-correlation potential. The lattice parameters were calculated from the ground-state total energy versus volume curve, and are in good agreement with the available experimental results. Our calculations of band structure predicted that the compound Ag_2PdO_2 has indirect band gap, and the Pd 4d states strongly hybridize with the O 2p states all over the valence bands and conduction bands. The valence bands are composed mainly of Ag, Pd 4d states and O 2p states, while the conduction bands consist mainly of the Pd 4d states and O 2p states. In addition, focusing on the calculation ...

2003-09-01

155

A study of palladium silicide formed by focused ion beam implantation of palladium ions  

Science.gov (United States)

The formation and properties of Pd{sub 2}Si formed by focused ion beam implantation of Pd ions into Si is presented in this thesis. An extensive microstructural study using transmission electron microscopy was undertaken and the as-implanted as well as annealed microstructure is shown. Results of other analysis techniques such as Rutherford back scattering and secondary ion mass spectrometry etc. are also presented. Kinetic information on the growth of Pd{sub 2}Si obtained by both microstructural and resistance measurements indicates that the activation energy for growth of the silicide is around 0.36 to 0.39 eV. This can be compared with the normally reported value of 1.5 eV for Pd{sub 2}Si formed by annealing thin film Pd on Si. The growth of the silicide was found to follow t{sup 1/2} kinetics. Microstructural observation of the as-implanted samples showed extensive in-situ formation of Pd{sub 2}Di and also surprisingly few defect structures. A heat transfer model for the ...

1989-01-01

156

A study of palladium silicide formed by focused ion beam implantation of palladium ions  

International Nuclear Information System (INIS)

The formation and properties of Pd_2Si formed by focused ion beam implantation of Pd ions into Si is presented in this thesis. An extensive microstructural study using transmission electron microscopy was undertaken and the as-implanted as well as annealed microstructure is shown. Results of other analysis techniques such as Rutherford back scattering and secondary ion mass spectrometry etc. are also presented. Kinetic information on the growth of Pd_2Si obtained by both microstructural and resistance measurements indicates that the activation energy for growth of the silicide is around 0.36 to 0.39 eV. This can be compared with the normally reported value of 1.5 eV for Pd_2Si formed by annealing thin film Pd on Si. The growth of the silicide was found to follow t"1"/"2 kinetics. Microstructural observation of the as-implanted samples showed extensive in-situ formation of Pd_2Di and also surprisingly few defect structures. A heat transfer model for the implantation indicates no ...

157

Study of the thermodynamic properties of (U,Ce)O{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

The X-ray diffraction analysis of (U,Ce)O{sub 2} with the CeO{sub 2} contents ranging from 0 to 20 mol% CeO{sub 2} was performed at room temperature to obtain the variation in the lattice parameter with the CeO{sub 2} content. Ultrasonic pulse echo measurements were also carried out to estimate the change in the mechanical properties of (U,Ce)O{sub 2} with the CeO{sub 2} content. The lattice parameter of (U,Ce)O{sub 2} was found to decrease with increasing CeO{sub 2} content. The variation in the lattice parameter with the CeO{sub 2} content closely followed the Vegard law. The shear and longitudinal velocities in (U,Ce)O{sub 2} were found to decrease with increasing CeO{sub 2} content. The Young`s and shear moduli, and Poisson`s ratio estimated from the wave velocities decreased with the CeO{sub 2} content. No mechanical property showed ...

1997-08-01

158

Statistical Support Document for Proposed Effluent Limitations Guidelines and Standards for the Metal Products and Machinery Industry.  

Science.gov (United States)

Table of Contents: Overview of Organization and Contents of Document; Analytical Data Collection Efforts and Definition of Options; Description of Data Conventions; Statistical Methodology: Modified Delta-Lognormal Model; Estimation Under the Modified Del...

2000-01-01

159

Online social support for individuals concerned with heart disease: observing gender differences.  

UK PubMed Central (United Kingdom)

Using a theoretical framework of social support, and content analysis, the content and pattern of support in messages posted in a 4-week period on a commercial health network for individuals concerned...Full Text Available

1999-01-01

160

Muscle glycogen content and glucose uptake during exercise in humans: influence of prior exercise and dietary manipulation  

UK PubMed Central (United Kingdom)

There are many factors that can influence glucose uptake by contracting skeletal muscle during exercise and although one may be intramuscular glycogen content, this relationship is at present not fully...Full Text Available

2002-05-15

161

Influence of moisture on flow property indicators of poor quality anthracite  

Energy Technology Data Exchange (ETDEWEB)

Describes investigations into flow density, angle of repose, coefficients of friction and adhesion using poor quality anthracite culm (from the 50-letie Ukrainy mine) and anthracite slurry with a high ash content (from the Tsentral'naya and Partizanskaya mines) on samples of varying moisture content (2-22%). The results show that flow properties are impaired when anthracite has a moisture content of 8.5 to 9.5%; when these anthracites are used in electric power plants they should be stored in bunkers with walls with a slope of greater than 70 degrees (or dried) to prevent sticking. Results of investigations into internal and external friction, adhesion and cohesion varied for the different samples, but the highest coefficient of internal friction was found with concrete where it increases continuously with moisture content. With rubber, PVC, St. 3 steel and stainless steel, the friction ...

1988-03-01

162

Failure of carnitine in improving hepatic nitrogen content in alcoholic and non?alcoholic malnourished rats  

UK PubMed Central (United Kingdom)

AIMS:To investigate the effect of carnitine supplementation on alcoholic malnourished rats' hepatic nitrogen content.METHODS:Malnourished rats, on...Full Text Available

2010-09-01

163

Effects of norepinephrine infusion on myocardial high-energy phosphate content and turnover in the living rat.  

UK PubMed Central (United Kingdom)

Using 31P-nuclear magnetic resonance, we studied the relationship between myocardial high-energy phosphate content and flux values for the creatine kinase reaction in the living rat under inotropic...Full Text Available

1987-06-01

164

Decrease in dust content and removal of sludge during drilling ascending shafts in coal  

Energy Technology Data Exchange (ETDEWEB)

Results are presented of analysis of the dust content of air and the resources for removing sludge at the mines of the Kuzbass during drilling of ascending shafts. A design is proposed for sludge removing devices with automatic opening and closing of the valve hinges.

1983-01-01

165

Acute change in the cyclic AMP content of rat mammary acini in vitro. Influence of physiological and pharmacological agents.  

UK PubMed Central (United Kingdom)

The cyclic AMP content of acini, freshly prepared from mammary tissue of lactating rats, was measured during incubation in vitro. Neither adrenergic agonists nor cyclic AMP phosphodiesterase inhibitors...Full Text Available

1985-08-15

166

Tritium Oxide Content Control  

International Science & Technology Center (ISTC)

Development of Method and Technical Project of the Plant for Thermo-Vacuum Desorption of Tritium Oxide (HTO) from the Environmental Samples

168

Factors Affecting the Environmental Stability of Laminates,  

Science.gov (United States)

... The moisture content-dimension relationship of two laminate components, phenolic core and melamine overlay, are compared. (Author, modified). ...

1967-02-08

169
171

Determination of ash content in coal by means of backscattered X-ray radiation and X-ray fluorescence analysis, and devices manufactured by the PAR company  

Energy Technology Data Exchange (ETDEWEB)

Discusses methods for determining ash content in coal using backscattering in X-ray fluorescence. The following aspects are evaluated: principle of ash content determination, energy sources, factors that influence measurement accuracy, reliability. Types of X-ray fluorescence analyzers developed in Czechoslovakia and manufactured in the Czech Republic are comparatively evaluated. Operation of the RPM 113.1 radionuclide X-ray fluorescence analyzer developed by the PAR company and used for measuring ash content in coal and coal calorific value is discussed. 7 refs.

1993-09-01

172

Analysis of catechin and epicatechin contents in leaves of Maytenus ilicifolia  

International Nuclear Information System (INIS)

English 2007 1 p. Brazil Souza, LM Cipriani, TR Iacomini, M. Sassaki, GL

2007-05-21

174

The influence of compound admixtures on the properties of high-content slag cement  

Energy Technology Data Exchange (ETDEWEB)

Based on the activation theory of alkali and sulfate, the influence of compound admixtures on the properties of high-content slag cement was studied by testing the strength, pore structure, hydrates, and microstructure, Test results show that compound admixtures can obviously improve the properties of high-content slag cement. The emphasis of the present research is two-fold: substituting gypsum with anhydrite and calcining gypsum. These both can improve early and later performance.

2000-01-01

175

Seasonal variations in biochemical composition of Sepia officinalis (Mollusca) from the Mediterranean waters off Alexandria, Egypt  

Energy Technology Data Exchange (ETDEWEB)

The biochemical compositions of 465 Sepia officinalis mantles from the Mediterranean waters off Alexandria Egypt, were studied from September 1989 to August 1990. Water contents of males and females were not significantly different, and followed the same pattern showing a sharp decrease in summer. Lipid contents of males and females were similar, showing two peaks in summer and autumn. A clear reverse relationship between water and lipid contents was found. Protein and ash contents showed irregular patterns. Protein contents were increased in early spring and mid-summer. The relationship between body compositions and mantle size, gonads maturation and environmental conditions was discussed.

1995-12-31

176

Lipid composition of liver microsomes and mitochondria after acute and chronic {gamma}-irradiation of rats  

Energy Technology Data Exchange (ETDEWEB)

Acute {gamma}-irradiation of rats at doses of 100 and 270 Gy stimulates lipid synthesis and changes the lipid composition of liver cell organelles. The content of cholesterol and cholesterol esters in microsomes increased at 100 Gy and decreased at 270 Gy, with total phospholipid content remaining unchanged. The lipid content in mitochondria decreased considerably 1 h after irradiation at 270 Gy. This change was significantly less pronounced 47 h later. Under chronic {gamma}-irradiation (0.129 Gy/day), cholesterol and cardiolipin in mitochondria increased. The changes in lipid content caused by acute irradiation are presumed to be related to activated synthesis of lipids in the liver. The modification of the lipid content of mitochondria observed in chronically irradiated rats may indicate that energy-metabolizing liver cell systems are involved in the adaptation to irradiation.

1994-07-01

177

Electrical properties and x-ray diffraction of wood and wood plastic composite (WPC)  

Energy Technology Data Exchange (ETDEWEB)

Wood plastic composite (WPC) of kadom, simul, mango and debdaro were prepared with two monomers methylmethacrylate (MMA) and butylmethacrylate (BMA) using high energy ionizing radiation. X-ray diffraction and scanning electron microscope (SEM) studies reveal that significant grafting occurred with wood fiber. Electric properties like resistivity and dielectric constant of both wood and WPC were measured under different moisture contents and relative humidities. The resistivities of wood decreased dramatically with increase of moisture content, but those of WPC decreased very slowly with moisture content. The dielectric constant of wood increased significantly with moisture content but no significant difference was observed in the case of WPC within the range of moisture contents studied. The dielectric constants of untreated wood also increased with their densities. (author).

1991-01-01

178

Effect of hydroxyapatite content on the microstructure, thermal and mechanical properties of Ti-based glassy alloy/hydroxyapatite composite prepared by spark plasma sintering  

British Library Electronic Table of Contents (United Kingdom)

In the present paper, the effects of hydroxyapatite (HA) content on the microstructure, thermal and mechanical properties of Ti-based glassy alloy/HA composite prepared by spark plasma sintering (SPS) are investigated. The microstructure of the composites is homogeneous when the HA is lower than 2 wt%. When the HA content is higher than 3 wt%, the crystalline precipitates with size of less than 5 nm are distributed in the glassy matrix. HA decomposes during sintering procedure for the composite with high HA content. With increasing HA addition, compressive strength decreases. Especially for the HA content is over 2 wt%, the strength decreases sharply because of partial crystallization of glassy alloy matrix.

2011-01-01

179

A new approach to fabrication of gradient WC-Co hardmetals  

British Library Electronic Table of Contents (United Kingdom)

WC-Co hardmetals with gradient structure comprising neither -phase nor grain growth inhibitors were produced for the first time by regulating the WC re-crystallisation and carbon content in their near-surface layer and core. Hardmetals with low Co contents in the surface region were obtained by selective carburisation of the near-surface zone of green articles with the original low carbon content and their consequent liquid-phase sintering. The surface region of such gradient hardmetals has a hardness of up 150 Vickers units higher and fracture toughness significantly superior than those of the core. Gradient hardmetals with high Co contents in the surface region were obtained by selective decarburisation of the near-surface zone of green articles with the original high carbon content and ...

2010-01-01

180

Sensitivity analysis and development of calibration methodology for near-surface hydrogeology model of Laxemar  

Energy Technology Data Exchange (ETDEWEB)

This report describes modelling where the hydrological modelling system MIKE SHE has been used to describe surface hydrology, near-surface hydrogeology, advective transport mechanisms, and the contact between groundwater and surface water within the SKB site investigation area at Laxemar. In the MIKE SHE system, surface water flow is described with the one-dimensional modelling tool MIKE 11, which is fully and dynamically integrated with the groundwater flow module in MIKE SHE. In early 2008, a supplementary data set will be available and a process of updating, rebuilding and calibrating the MIKE SHE model based on this data set will start. Before the calibration on the new data begins, it is important to gather as much knowledge as possible on calibration methods, and to identify critical calibration parameters and areas within the model that require special attention. In this project, the MIKE SHE model has been further developed. The model area has been extended, and the present ...

2007-11-15

181

Numerical modelling of surface hydrology and near-surface hydrogeology at Forsmark. Site descriptive modelling SDM. Site Forsmark  

Energy Technology Data Exchange (ETDEWEB)

SKB is currently performing site investigations at two potential sites for a final repository for spent nuclear fuel. This report presents results of water flow and solute transport modelling of the Forsmark site. The modelling reported in this document focused on the near-surface groundwater, i.e. groundwater in Quaternary deposits and shallow rock, and surface water systems, and was performed using the MIKE SHE tool. The most recent site data used in the modelling were delivered in the Forsmark 2.3 dataset, which had its 'data freeze' on March 31, 2007. The present modelling is performed in support of the final version of the Forsmark site description that is produced during the site investigation phase. In this work, the hydrological modelling system MIKE SHE has been used to describe near-surface groundwater flow and the contact between groundwater and surface water at the Forsmark site. The surface water system at Forsmark is described with ...

2008-09-15

182

Water-soluble cis-[(NHC)PdBr2(TPPTS)] catalysts and their applications in Suzuki-Miyaura coupling of aryl chlorides  

British Library Electronic Table of Contents (United Kingdom)

New palladium(II) complexes (2), bearing NHC/TPPTS ligands, (NHC=benzimidazol-2-ylidene; TPPTS=triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt) have been prepared and characterized by elemental analyses and spectroscopic methods. Their ability to catalyze the Suzuki-Miyaura reaction in neat water has been studied at 100^oC. Very high activities have been observed in the coupling of phenylboronic acid with aryl chlorides in the presence of 1% of the catalyst. We have compared the electronic properties of cis-[PdBr2(NHC)(TPPTS)] with the related complexes, [PdX2(NHC)]2 and [trans-PdBr2(NHC)(pdca)] (pdca=pyridine-2,6-dicarboxyic acid) (3) via three different techniques: cyclic voltammetry, thermogravimetric analysis and ^1^3C NMR spectroscopy.

2011-01-01

183

Ultra-high tritium decontamination of simulated fusion fuel exhaust using a 2-stage palladium membrane reactor  

Energy Technology Data Exchange (ETDEWEB)

A 2-stage cold (non-tritium) PMR system was tested with the ITER mix in61 days of continuous operation. No decrease in performance was observed over the duration of the test. Decontamination factor (DF) was found to increase with decreasing inlet rate. Decontamination factors in excess of 1.4 {times} 10{sup 5} were obtained, but the exact value of the highest DF could not be determined because of analysis limitations. Results of the 61-day test were used to design a 2-stage PMR system for use in tritium testing. The PMR system was scaled up by a factor of 6 and built into a glovebox in the Tritium Systems Test Assembly (TSTA) of the Los Alamos National Laboratory. This system is approximately 1/5th of the expected full ITER scale. The ITER mix was injected into the PMR system for 31 hours, during which 4.5 g of tritium were processed. The 1st stage had DF = 200 and the 2nd stage had DF = 2.9 {times} 10{sup 6}. The overall DF = 5.8 {times} 10{sup 8}, which is greater than ITER ...

1996-12-31

184

Ultra-high tritium decontamination of simulated fusion fuel exhaust using a 2-stage palladium membrane reactor  

International Nuclear Information System (INIS)

A 2-stage cold (non-tritium) PMR system was tested with the ITER mix in 61 days of continuous operation. No decrease in performance was observed over the duration of the test. Decontamination factor (DF) was found to increase with decreasing inlet rate. Decontamination factors in excess of 1.4x10"5 were obtained, but the exact value of the highest DF could not be determined because of analysis limitations. Results of the 61-day test were used to design a 2-stage PMR system for use in tritium testing. The PMR system was scaled up by a factor of 6 and built into a glovebox in the Tritium Systems Test Assembly (TSTA) of the Los Alamos National Laboratory. This system is approximately 1/5"t"h of the expected full ITER scale. The ITER mix was injected into the PMR system for 31 hours, during which 4.5 g of tritium were processed. The 1"s"t stage had DF =200 and the 2"n"d stage had DF=2.9x10"6. The overall DF=5.8x10"8, which is greater than ITER requirements. 3 refs., 10 figs.

1996-06-16

185

The ternary system cerium-palladium-silicon  

British Library Electronic Table of Contents (United Kingdom)

Phase relations in the ternary system Ce-Pd-Si have been established for the isothermal section at 800degreeC based on X-ray powder diffraction and EMPA techniques on about 130 alloys, which were prepared by arc-melting under argon or powder reaction sintering. Eighteen ternary compounds have been observed to participate in the phase equilibria at 800degreeC. Atom order was determined by direct methods from X-ray single-crystal counter data for the crystal structures of t8-Ce3Pd4Si4 (U3Ni4Si4-type, Immm; a=0.41618(1), b=0.42640(1), c=2.45744(7)nm), t16-Ce2Pd14Si (own structure type, P4/nmm; a=0.88832(2), c=0.69600(2)nm) and also for t18-CePd1-xSix (x=0.07; FeB-type, Pnma; a=0.74422(5), b=0.45548(3), c=0.58569(4)nm). Rietveld refinements established the atom arrangement in the structures of...

2009-01-01

186

The crystal structure of the novel ternary silicide Sm_4Pd_4Si_3  

International Nuclear Information System (INIS)

The crystal structure of the compound Sm_4Pd_4Si_3 was determined by the single-crystal method (KM-4 automatic diffractometer, Mo K#alpha# radiation). Sm_4Pd_4Si_3 has the monoclinic Nd_4Rh_4Ge_3 type structure: space group C2/c, mC44 (No. 15), a=20.693(6), b=5.584(1), c=7.699(2) A, #beta#=109.48(3) , V=838 A"3, Z=4, #mu#=36.23 mm"-"1, R_F=0.0537, R_W=0.0435 for 1652 unique reflections. The coordination numbers of samarium atoms are 17 and 18. For palladium and silicon atoms icosahedra and trigonal prisms with additional atoms are typical as coordination polyhedra. The structure of Sm_4Pd_4Si_3 is composed of fragments of the YPd_2Si and Y_3Rh_2Si_2 structure in a ratio 1:1. (orig.).

187

Synthesis, characterization and biological evaluation of mononuclear Co(II), Ni(II), Cu(II) and Pd(II) complexes with new N2O2 Schiff base ligands.  

Science.gov (United States)

New tetradentate N(2)O(2) donor Schiff bases and their mononuclear Co(II), Ni(II), Cu(II), and Pd(II) complexes were synthesized and characterized extensively by IR, (1)H-, (13)C-NMR, mass, ESR, conductivity measurements, elemental and thermal analysis. Specifically the magnetic and electronic spectral measurements demonstrate the octahedral structures of cobalt(II), nickel(II) complexes and square planar geometries of copper(II), palladium(II) complexes. All the ligands and complexes were screened for their in vitro antibacterial activity against two gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus) and two gram-negative bacteria (Escherichia coli, Klebsiella pneumonia). In this study, Pd(II) complexes exhibited potent antibacterial activity against B. subtilis, S. aureus whereas other metal complexes also exerted good activity towards all tested strains even than standard drugs streptomycin and ampicillin. PMID:21297294

2011-02-01

188

Stereospecific ligands and their complexes. Part VII. Synthesis, characterization and in vitro antitumoral activity of platinum(II) complexes with O,Oprime-dialkyl esters of (S,S)-ethylenediamine-N,Nprime-di-2-(4-methyl)pentanoic acid  

British Library Electronic Table of Contents (United Kingdom)

Platinum(II) complexes (1-4) with bidentate N,Nprime-ligands, O,Oprime-dialkyl esters (alkyl = ethyl, n-propyl, n-butyl and n-pentyl), of (S,S)-ethylenediamine-N,Nprime-di-2-(4-methyl)pentanoic acid were synthesized and characterized by IR, 1H NMR and 13C NMR spectroscopy and elemental analysis. DFT calculations were performed for the complexes and it was found that only one diastereoisomer could be formed. Cytotoxic activity of complexes 1-4 was determined against chronic lymphocytic leukemia cells (CLL) and compared to the activity of ligand precursors L12HCl-L42HCl and corresponding palladium(II) complexes, [PdCl2L] (L = L1-L4). The complexes were found to exhibit significantly higher antitumor activities than cisplatin on CLL cells. Cytotoxic effect of platinum(II) complexes on CLL cel...

2011-01-01

189

Semirelativistic technique for k#centre dot#p calculations: Optical properties of Pd and Pt  

International Nuclear Information System (INIS)

A semirelativistic two-component extended linear augmented plane-wave k#centre dot#p method is described. In order to ensure a high accuracy of the k#centre dot#p method, it is necessary to include into the radial-basis set, which is used for the augmentation of the plane waves, functions that are neither solutions of the Schrodinger equation nor their energy derivatives. The usual scalar relativistic procedure, which is nonlinear in energy, is not applicable to such basis sets. As an alternative, we suggest an approximation to the Foldy-Wouthuysen Hamiltonian that produces an explicitly Hermitean matrix in the augmented plane wave representation. The technique is applied to the calculation of the full dielectric matrix and optical properties of palladium and platinum metals over the photon energy region up to 100 eV. Special attention is paid to the far ultraviolet absorption by the excitations of semicore Pd 4p and Pt 5p and 4f states. A strong effect of local ...

2001-06-15

190

Processing method and processing facility for carbon steel parts in nuclear power plant  

International Nuclear Information System (INIS)

In a closed circuit formed by bypassing pipelines connected to carbon steel parts, low oxygen coolants pass there through during operation. A solution containing ions of metals more noble than iron are circulated to bring the solution into contact with the carbon steel surface of the inner wall of the parts to form a deposition membrane of the metal more noble than iron on the surface to prevent acceleration of corrosion of the carbon steel parts due to low oxygen coolants. The solution containing ions of metals more noble than iron is a solution of palladium nitrate containing ions of platinum elements. This operation is conducted under a temperature condition of from 50degC to 150degC. In addition, the metal ion concentration of the solution circulating in the closed circuit is measured, it is compared with metal ion concentration previously determined, and the results are feed back to a means for controlling water quality of the solution to control the metal ion ...

1996-11-27

191

Preparation, characterization and electrical properties of SnO{sub 2} based liquid petroleum gas sensor  

Energy Technology Data Exchange (ETDEWEB)

The present investigation deals with the fabrication of liquid petroleum gas (LPG) sensor based on semiconducting oxide SnO{sub 2}. The gas sensor elements have been prepared by conventional solid state route. Addition of noble metal sensitizer, palladium and grain growth inhibitor, aluminum silicate to the base material SnO{sub 2}, not only improved the sensitivity towards LPG but also the selectivity in the presence of CO and CH{sub 4} gases. Out of various sensor compositions, SnO{sub 2}:Al{sub 2}Si{sub 2}O{sub 7} (35 wt.%):Pd (1.5 wt.%) sintered at 800 C for 5 h has shown high sensitivity (0.97) towards LPG at an operating temperature of 350 C. Different characterization techniques have been employed, such as differential thermal analysis (DTA), surface area analyzer, X-ray diffraction (XRD), to study the formation of SnO{sub 2}, surface area and crystallite size, respectively. The results suggested the possibility of utilizing the sensor element for the ...

1999-03-25

192

Prediction of stable long-period superstructures in Cu-Pd, Ag-Pd and Au-Pd within a first-principles approach  

Energy Technology Data Exchange (ETDEWEB)

One- and two-dimensional long-period superstructures (LPS), based on the L1{sub 2} substructure, are systematically investigated for the noble metal-palladium alloys Cu-Pd, Ag-Pd and Au-Pd with first-principles methods. Notwithstanding the fact that the experimental phase diagrams of these systems yield totally different features, quite similar behaviour with respect to formation of low temperature ordered LPS-phases (Cu{sub 3}Pd: LPS 3, Ag{sub 3}Pd: LPS 3, Au{sub 3}Pd: LPS 2; {l_brace}Cu, Au{r_brace}Pd{sub 3}: L1{sub 2}, AgPd{sub 3}: not a ground state) is predicted. As a lever between via LDA obtained formation enthalpies and a thorough ground state scan, the cluster expansion method in conjunction with a genetic algorithm provides adequate means for the extraction of effective interactions, which also allow for an enhanced ground state scan in the configurational space of LPS structures. As a result, the sequences and energetical hierarchies for stable LPSs in ...

2007-07-01

193

In situ ultrahigh vacuum transmission electron microscopy studies of palladium silicide island formation on silicon (111) 7x7 surface  

Energy Technology Data Exchange (ETDEWEB)

Pd was deposited onto Si (111) 7x7 surface at approximately 700 K inside an ultrahigh vacuum transmission electron microscope. Plan-viewed transmission electron microscopy (TEM) observation indicated that the islands have two kinds of shapes, round and rectangular (one-dimensional) ones. In a diffraction pattern for the rectangular islands, extra spots along the <110> direction of the Si surface, spacing of which is 1/8 times as long as that of Si (220) spots, were seen. A high resolution TEM image showed the corresponding superstructure in the rectangular islands. In situ observation of the growing process of the rectangular islands showed repeat of introduction and relief of strains during the growth, suggesting that such superstructure would be constructed by stacking compositionally different phases or introducing defects so that the periodically maximized strain is relieved.

2003-01-22

194

Evaluation of Pd-Ag alloys as electrocatalysts for oxygen reduction reaction  

Energy Technology Data Exchange (ETDEWEB)

Alkaline fuel cells (AFCs) provide a less corrosive environment and can provide higher electrode reaction kinetics than proton exchange membrane fuel cells (PEMFCs). The alkaline media also allows for the replacement of platinum (Pt) based electrocatalysts with non-Pt electrocatalysts. Studies have shown that palladium (Pd) and silver (Ag) form a homogenous solid solution with a face-centred cubic structure within a large range of temperatures. This study described the results of an oxygen reduction reaction (ORR) on lead-silver (Pd-Ag) alloy electrodes in alkaline media. The reaction was compared with Pd and Ag electrodes. The alloys were synthesized as thin films using a sequential electroless deposition of Pd and Ag on stainless steel discs followed by an annealing procedure in an Ar stream. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to characterize catalyst structure, morphology, and ...

2010-07-01

195

Comparison of the charge injection barrier at realistic and ideal metal/organic interfaces: metals become faceless  

Energy Technology Data Exchange (ETDEWEB)

Most of the organic electronic devices are nowadays fabricated under poor vacuum conditions. In this regard, there is only little knowledge about the impact of contamination of the metal electrode on the charge injection barrier in this kind of electronic devices. In our study we have performed X-ray and ultra violet photoemission spectroscopy (XPS, UPS) on interfaces between the organic semiconductor -sexithiophene and sputter cleaned (ideal) metals as well as contaminated (realistic) metals. As metal substrates we have used silver, gold, palladium, and platinum. These metals provide us a wide range of metal work functions from 4.2 eV for silver up to 5.5 eV for platinum. For all interfaces of -sexithiophene and contaminated metals we have observed a reduction of the interface dipole and the hole injection barrier. The charge injection barrier in all four cases is almost independent of the underlying metal (within an error of 0.2 eV) and the interface dipole ...

2007-07-01

196

A one-pot synthetic approach to prepare palladium nanoparticles embedded hierarchically porous TiO2 hollow spheres for hydrogen peroxide sensing  

Science.gov (United States)

A simple one-step method to fabricate hierarchically porous TiO2/Pd composite hollow spheres without any template was developed by using solvothermal treatment. Pd nanoparticles (2-5 nm) were well dispersed in the mesopores of the TiO2 hollow spheres via in-situ reduction. In our experiment, polyvinylpyrrolidone played an important role in the synthetic process as the reducing agent and the connective material between TiO2 and Pd nanoparticles. HF species generated from solvothermal reaction leaded to the formation of TiO2 hollow spheres and Ostwald ripening was another main factor that affected the size and structure of the hollow spheres. The as-prepared TiO2/Pd composite hollow spheres exhibited high electrocatalytic activity towards the reduction of H2O2. The sensitivity was about 226.72 ?A mM-1 cm-2 with a detection limit of 3.81 ?M at a signal-to-noise ratio of 3. These results made the hierarchically porous TiO2/Pd composite a promising platform for fabricating new nonenzymic ...

2010-10-01

197

Characterization of the deviation of the ideality of concentrated electrolytic solutions: plutonium 4 and uranium 4 nitrate salts study; Contribution a la caracterisation de l'ecart a l'idealite des solutions concentrees d'electrolytes: application aux cas de nitrates de plutonium (4) et d'uranium (4)  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work was to establish a new binary data base by compiling the activity coefficients of plutonium and uranium at oxidation state +IV to better account for media effects in the liquid-liquid extraction operations implemented to reprocess spent nuclear fuel. Chapter 1: first reviews the basic thermodynamic concepts before describing the issues involved in acquiring binary data for the tetravalent actinides. The difficulties arise from two characteristics of this type of electrolyte: its radioactive properties (high specific activity requiring nuclearization of the experimental instrumentation) and its physicochemical properties (strong hydrolysis). After defining the notion of fictive binary data, an approach based on the thermodynamic concept of simple solutions is described in which the activity coefficient of an aqueous phase constituent is dependent on two parameters: the water activity of the system and the total concentration of dissolved constituents. The method ...

2000-07-01

198

Effects of Cr content and the addition of Cr_2O_7"2"- ion on corrosion resistance of stainless steel in nitric acid solutions  

International Nuclear Information System (INIS)

A nitric acid solution containing Cr_2O_7"2"- ion is used for a corrosion test which simulates the condition in a nuclear fuel reprocessing plant. As the effect of Cr content on the corrosion resistance of stainless steel is not yet fully understood in that solution, the effects of Cr content in an alloy and that of Cr_2O_7"2"- ion in nitric acid on the corrosion rate were studied by using electro-chemical measurements. The increase of Cr content reduced the general corrosion rate in nitric acid solution without Cr_2O_7"2"- ion, however it increased that in nitric acid solution containing Cr_2O_7"2"- ion. It is considered that the reversal of the Cr content dependency is due to a rise of the corrosion potential caused by addition of Cr_2O_7"2"- ion to the potential region where a high Cr alloy shows higher anodic dissolution rate than a low Cr content alloy. (author).

199

Effect of water content on the activity of lipase-hydrolysis of olive oil in reverse micelles. Gyakuso micelle nai ni okeru lipase no olive oil kasui bunkai hanno no gansuiritsu izonsei  

Energy Technology Data Exchange (ETDEWEB)

Hydrolysis of olive oil by Chromobacterium viscosum lipase was studied in a reverse micellar system of a anionic surfactant Aerosol OT (AOT) and isooctane. Different methods of solubilization of the micellar system afford specific dependence of enzymatic activity of the lipase on the water content in the micelles. In an injection method, water content is controlled by the amount of injected water, which determines the micelle size and hydrophobicity of the micelle without salt addition and changes reversibly the conformation of lipase corresponding to the change of lipase activity. The activity reaches the maximum at a water content (water/AOT)of 7. In a phase transfer method, water content is determined by salt concentration in the aqueous phase in contact with micelles and the water content corresponding to the maximum activity is 12 to 13, below which the activity decrese ...

1992-01-10

200

Effect of field natural rubber latex with different ammonia contents and storage period on physical properties of latex concentrate, stability of skim latex and dipped film  

British Library Electronic Table of Contents (United Kingdom)

The effect of ammonia treatment in field natural rubber (NR) latex with different storage period time on the properties of concentrated NR latex and stability of skim latex was investigated. Fresh NR latex was treated with various ammonia contents such as 0.35, 0.60 and 0.80% w/w, and then they were centrifuged to get the concentrated NR latex with 60% dry rubber content (DRC) containing 0.16, 0.18 and 0.25% w/w, respectively and skim NR latex with roughly 5% DRC containing 0.42, 0.60 and 0.80% w/w, respectively. The effect of storage times with ?0, 15, 30 and 45 days for concentrated NR latex with different ammonia contents on their properties such as alkalinity, magnesium content and viscosity was observed. It was found that generally, magnesium content in field NR latex and latex...

2009-01-01

201

Effect of La content on characterization of PLZT ceramics  

Energy Technology Data Exchange (ETDEWEB)

This work has been undertaken with a view to study the effect of lanthanum content on properties of PLZT ceramics. The polycrystalline complex compounds of PLZT with Pb{sub 1-x}La{sub x}(Zr{sub 0.40}Ti{sub 0.60}){sub 1-x/4}O{sub 3}, +10% PbO formula were prepared from the nano-size individual oxides powders by hot-pressed process. Transparent PLZT (x/40/60) bulk ceramics with pure tetragonal phase was obtained. The studies of the microstructures, dielectric and ferroelectric properties of the ceramics were carried out. The experiment results showed that when La content increased from 7 to 13 mol.%, the grain size increased from 2 to 7 {mu}m. La content also effects the dielectric property obviously, the dielectric constant increased with La content increasing. Moreover, the ferroelectric properties are sensitive to the variation of La content.

2003-05-25

202

Effect of La content on characterization of PLZT ceramics  

International Nuclear Information System (INIS)

This work has been undertaken with a view to study the effect of lanthanum content on properties of PLZT ceramics. The polycrystalline complex compounds of PLZT with Pb_1_-_xLa_x(Zr_0_._4_0Ti_0_._6_0)_1_-_x_/_4O_3, +10% PbO formula were prepared from the nano-size individual oxides powders by hot-pressed process. Transparent PLZT (x/40/60) bulk ceramics with pure tetragonal phase was obtained. The studies of the microstructures, dielectric and ferroelectric properties of the ceramics were carried out. The experiment results showed that when La content increased from 7 to 13 mol.%, the grain size increased from 2 to 7 #mu#m. La content also effects the dielectric property obviously, the dielectric constant increased with La content increasing. Moreover, the ferroelectric properties are sensitive to the variation of La content.

2003-05-25

203

Changes of magnetization transfer ratio according to rat brain development  

International Nuclear Information System (INIS)

We assessed the age-related changes in magnetization transfer ratio (MTR) value and the ratio of water content in rat brain (frontal lobe and pons) during normal development. All studies were done on 42 normal Wistar rats. MTR was calculated by using the equation (M_o_f_f-M_o_n)/M_o_f_f, where M_o_f_f and M_o_n were the measured signal intensities on the conventional and MT-prepared SPGR images, respectively. The ratios of water content were measured by comparing the wet weight with the dry weight of the frontal lobe and the pons, which were extracted from a rat brain soon after MTR measurements. The ratio of water content was calculated by using the equation 100 x (wet weight-dry weight)/wet weight (%). The ratio of water content decreased markedly during the first 30 days, but the decrease was very slight there after both in the frontal lobe and the pons. The change in MTR was similar to that of the ...

204

The amount of bone mineral and Schmorl's nodes in lumbar vertebrae.  

Science.gov (United States)

The bone mineral areal content and the ultimate compressive strength were determined in 109 lumbar vertebrae from 36 subjects. The bone mineral areal content was related to the number, shape, and localization of the Schmorl's nodes detected in the x-rayed and sectioned vertebral bodies. One type of node, irregular in shape and localization, occurred only in the vertebrae with low bone mineral areal content values and thus in vertebrae with relatively low compressive strength. A second type of Schmorl's nodes, regular in shape and localization, did not reflect any general weakness of the vertebral bodies. PMID:6623194

1983-04-01

205

Radionuclide X-ray fluorescence analysis  

International Nuclear Information System (INIS)

The author's achievements in the title field are summarized and discussed. The following topics are dealt with: (i) principles of radionuclide X-ray fluorescence analysis; (ii) mathematical methods in X-ray fluorescence analysis; (iii) Ross differential filters; (iv) application of radionuclide X-ray fluorescence analysis in the coal industry (with emphasis on the determination of the ash content, sulfur content, and arsenic content of coal); and (v) evaluation of the X-ray fluorescence analyzer from the radiological safety point of view. (P.A.).

1994-01-01

206

Iron catalyzed hydrogenation of high sulphur content coals  

Energy Technology Data Exchange (ETDEWEB)

Four high-sulphur low-rank coals have been treated at hydrogenation conditions with three iron-based catalyst precursors: Red Mud (Fe[sub 2]O[sub 3]), iron sulphide and iron pentacarbonyl. The obtained yields show a dependence with the sulphur content of the coals; the organic sulphur content correlates with the conversion and THF-solubles when Red Mud and iron sulphide are added. In spite of the high hydrogen sulphide partial pressure in the reaction, the addition of other sources of sulphur enhances the percentages in conversion products. 15 refs., 2 figs., 3 tabs.

1993-12-01

207

Effect of the fillers contents on the chemical, mechanical and thermal properties of polymer composites  

International Nuclear Information System (INIS)

Polymer composites are used in numerous applications. In spite of this fact, new developments are still under way to explore in other field of application of these materials and to tailor their properties for more extreme condition. A particular emphasis is focused on fillers content is summarized. Some steps towards the functionally graded materials are illustrated. The FT-IR spectroscopic studies revealed the information about curing of epoxy with fillers. It was observed that mechanical properties like tensile strength, hardness etc get enhanced up with filler contents. The effect of the different formulations were investigated and discussed for optimum process condition. (author)

1398-01-01

208

Biopsy examination during the course of radiotherapy. Progress report. [DNA content of tumor cells in biopsy samples determined by microfluorometric or multiangle light-scatter spectrometry  

Science.gov (United States)

Studies begun during the first year of this project on biopsies from spontaneous tumors in dogs and from human patients undergoing radiotherapy treatment were continued. The results indicate that significant fractions of the spontaneous tumors in dogs and cervical carcinomas in patients undergoing radiotherapy have a DNA content higher than normal diploid cells. The higher DNA content in tumor cells permits distinguishing them from normal cells in the biopsy material with the aid of flow microfluorometric (FMF) instrumentation or multiangle light-scatter spectrometry.

1977-12-01

209

Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas  

International Nuclear Information System (INIS)

Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field ...

2000-12-01

210

Short-wavelength (approx. <6400 A) room-temperature continuous operation of p-n In/sub 0. 5/(Al/sub x/Ga/sub 1//sub -//sub x/)/sub 0. 5/P quantum well lasers  

Science.gov (United States)

Data are presented demonstrating short-wavelength (approx. <6400 A) continuous (cw) laser operation of p-n diode In/sub 0.5/(Al/sub x/Ga/sub 1-//sub x/)/sub 0.5/P multiple quantum well heterostructure (QWH) lasers grown lattice matched on GaAs substrates using metalorganic chemical vapor deposition. In the range from -30 /sup 0/C to room temperature (RTapprox. =300 K, lambdaapprox. =6395 A) the threshold current density changes from 2.3 x 10/sup 3/ A/cm/sup 2/ (-30 /sup 0/C) to 3.7 x 10/sup 3/ A/cm/sup 2/ (RT, 300 K). The cw 300 K photopumped laser operation of the same quaternary QWH crystal is an order of magnitude lower in threshold (7 x 10/sup 3/ W/cm/sup 2/, J/sub eq/approx.2.9 x 10/sup 3/ A/cm/sup 2/) than previously reported for this crystal system, and agrees with the successful demonstration of cw 300 K laser diodes at this short wavelength.

1988-11-07

211

Seismic stratigraphy based chronostratigraphy (SSBC) of the Serbian Banat region of the Pannonian Basin  

Science.gov (United States)

Seismic stratigraphy based chronostratigraphic (SSBC) analysis of the Serbian Banat region allows the delineation of the spatial and stratigraphic relationships of the generally regressive and shallowing upward Neogene depositional fill of a tectonically unstable central portion of the Pannonian Basin. When geometrically restored in time and space, the sediment dispersal directions, sediment source directions, types of sedimentation breaks and the tectonic events influencing basin evolution can be delineated. For such an analysis the time-transgressive lithostratigraphic units used in the neighbouring Hungarian part of the Pannonian Basin are conveniently introduced based upon their characteristic seismic facies and constrained borehole log records as mappable seismic stratigraphic sequence units, termed "seismic operational sequences". The respective Neogene stage and operational sequence equivalents (Hungarian lithostratigraphic units or formations) are the Middle Miocene (Badenian, ...

2010-12-01

212

Reactive magnetron sputtering of hard Si-B-C-N films with a high-temperature oxidation resistance  

International Nuclear Information System (INIS)

Based on the results obtained for C-N and Si-C-N films, a systematic investigation of reactive magnetron sputtering of hard quaternary Si-B-C-N materials has been carried out. The Si-B-C-N films were deposited on p-type Si(100) substrates by dc magnetron co-sputtering using a single C-Si-B target (at a fixed 20% boron fraction in the target erosion area) in nitrogen-argon gas mixtures. Elemental compositions of the films, their surface bonding structure and mechanical properties, together with their oxidation resistance in air, were controlled by the Si fraction (5-75%) in the magnetron target erosion area, the Ar fraction (0-75%) in the gas mixture, the rf induced negative substrate bias voltage (from a floating potential to -500 V) and the substrate temperature (180-350 deg. C). The total pressure and the discharge current on the magnetron target were held constant at 0.5 Pa and 1 A, respectively. The energy and flux of ions bombarding the growing films were ...

2005-11-01

213

Quaternary tilt of Death Valley determined from landform modelling of alluvial fans  

Energy Technology Data Exchange (ETDEWEB)

Alluvial fans along the east side of central Death Valley are being actively back-tilted along the Death Valley fault zone. Initial modelling of the Copper Canyon and Furnace Creek fans led to recognition of distinct segments. Field reconnaissance and aerial photo mapping were conducted to check model results and improve segment discrimination. Surface roughness, relative position, vegetation distribution, and drainage patterns provided independent evidence for segment discrimination. Subsequent modelling of individual segments produced a range of tilt values from 0.275[degree] to 0.559[degree] down to the northeast. Continued analysis of these fan segments is concentrated on: (1) assigning confidence and error values to the tilt values; and (2) dating individual segments. Further work will compare the tilt rates of east-side fans with those from the west. The mean squared error (MSE) is currently being used as a first order assessment of the quality of the model's fit to data ...

1993-04-01

214

Phase equilibria of the Ba-Sm-Y-Cu-O system for coated conductor applications  

International Nuclear Information System (INIS)

The complex phase relationships near the BaO-poor region of the quaternary Ba-Sm-Y-Cu-O oxide system prepared in pure air (pO2=22 kPa, 950 oC) and in 0.1% O2 (pO2=100 Pa, 810 oC) have been determined. This investigation also included the subsolidus compatibilities in ten subsystems (Ba-Sm-Y-O, Ba-Sm-Cu-O, Ba-Y-Cu-O, Sm-Y-Cu-O, Ba-Sm-O, Ba-Y-O, Ba-Cu-O, Sm-Y-O, Sm-Cu-O, and Y-Cu-O), and the homogeneity range of five solid solutions (Ba(SmxY2-x)CuO5, (Sm,Y)2O3, (Sm,Y)2CuO4, (Y,Sm)2Cu2O5, and Ba(Sm,Y)2O4). The single phase range of the superconductor solid solution, (Ba2-xSmx)(Sm1-yYy)Cu3O6+z, and the phase compatibilities in its vicinity, which are particularly important for processing, are described in detail. The phase equilibrium data of the Ba-Sm-Y-Cu-O system will enable the improvement of the intrinsic superconducting properties of second-generation wires, and facilitate the flux-pinning process. -- Graphical Abstract: Phase diagram overview of the Ba-Sm-Y-Cu-O ...

2010-12-01

215

Organometallic vapor phase epitaxial growth of (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P and its heterostructures  

International Nuclear Information System (INIS)

The (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P material system, lattice matched to GaAs substrates, is useful for visible laser diodes. Here, low pressure organometallic vapor phase epitaxial growth of Ga/sub 0.5/In/sub 0.5/P and (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P is examined. Epitaxial layers of bulk materials are characterized using photoluminescence, electroreflectance, Raman scattering spectroscopy, and surface morphology studies to determine lattice match and optimum growth conditions. Lattice matching at the growth temperature produces featureless growth surfaces, while lattice matching at room temperatures results in minimum photoluminescence linewidth but cracked surface due to tensile strain during growth. Raman scattering spectra of the quaternary reveal a three-mode structure, with spectral peaks due to GaP-like, in P-like, and AIP-like LO phonons. Additionally, (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P/Ga/sub 0.5/In/sub 0.5/P ...

216

Organometallic vapor phase epitaxial growth of (Al/sub x/Ga/sub 1-x/)/sub 0. 5/In/sub 0. 5/P and its heterostructures  

Science.gov (United States)

The (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P material system, lattice matched to GaAs substrates, is useful for visible laser diodes. Here, low pressure organometallic vapor phase epitaxial growth of Ga/sub 0.5/In/sub 0.5/P and (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P is examined. Epitaxial layers of bulk materials are characterized using photoluminescence, electroreflectance, Raman scattering spectroscopy, and surface morphology studies to determine lattice match and optimum growth conditions. Lattice matching at the growth temperature produces featureless growth surfaces, while lattice matching at room temperatures results in minimum photoluminescence linewidth but cracked surface due to tensile strain during growth. Raman scattering spectra of the quaternary reveal a three-mode structure, with spectral peaks due to GaP-like, in P-like, and AIP-like LO phonons. Additionally, (Al/sub x/Ga/sub 1-x/)/sub 0.5/In/sub 0.5/P/Ga/sub 0.5/In/sub 0.5/P ...

1988-09-01

217

Isotope and trace element systematics in a spinel-lherzolite-bearing suite of basanitic volcanic rocks from San Luis Potosi, Mexico  

Energy Technology Data Exchange (ETDEWEB)

Lherzolite-bearing basanitic magmas of Quaternary age have erupted to form maars, lava/cinder cones and lava flows in two volcanic fields (Ventura and Santo Domingo) in the central Mexican state of San Luis Potosi. The systematics of the radiogenic isotopes of Sr, Nd, and Pb and the relationship between these parameters and elemental compositions are used to investigate the petrogenesis of the volcanic rocks and the nature of their mantle sources. Sr and Nd isotopic data are presented for 19 basanitic rocks, 5 kaersutites, and 6 lherzolitic xenoliths; Pb data presented for the same 19 volcanic rocks and 4 of the 5 kaersutites. The isotopic compositions for all of these samples fall within the mantle range defined by MORBs and OIBs. The basanites generally plot within the OIB field on isotopic diagrams; most of the kaersutites are displaced to slightly more-depleted (i.e. MORB-like) values than the volcanic samples and the xenoliths, with one exception, are ...

1989-01-01

218

High-power (1. 4 W) AlGaInP graded-index separate confinement heterostructure visible (lambdaapprox. 658 nm) laser  

Science.gov (United States)

Pulsed operation of an AlGaInP graded-index separate confinement heterostructure laser grown by organometallic vapor phase epitaxy is reported. The laser active region consists of a single 100 A Ga/sub 0.5/In/sub 0.5/P quantum well and 1600 A graded index regions on both sides of the well. The graded index regions were produced by lattice-matched graded composition (Al/sub y/Ga/sub 1-//sub y/)/sub 0.5/In/sub 0.5/P quaternary alloys. This structure reduces the broad-area threshold current compared to a double heterostructure laser, with pulsed thresholds as low as 1050 A/cm/sup 2/. Total pulsed power of 1.4 W at 658 nm is available from an 80 ..mu..m x 300 ..mu..m mesa-stripe laser. A differential quantum efficiency of approx.56% is measured. By examining the cavity length dependence of the threshold current density and quantum efficiency, it is apparent that the quantum well gain has not saturated in these structures. This suggests that devices containing a thinner ...

1987-11-23

219

Buried soils of Late Quaternary moraines of the Wind River Mountains, Wyoming  

Energy Technology Data Exchange (ETDEWEB)

Buried soils occur on kettle floors of four Pinedale moraine catenas of the western Wind River Mountains of Wyoming. Radiocarbon ages from bulk samples of Ab horizons indicate the soils were buried during the mid-Holocene. Soils on kettle floors have silty A and Bw horizons that overlie buried A and B horizons that also formed in silt-rich sediments. Crests and backslope soils also have A and Bw horizons of sandy loam formed over 2BCb and 2Cb horizons of stony coarse loamy sand. Recent data show the silty textures of the A and B horizons are due to eolian silt and clay from the Green River Basin just west of the mountains. The buried soils appear to represent alternate periods of erosion and deposition on the moraines during the Holocene. The original soils developed on higher slopes of the moraines were eroded during the mid-Holocene and the 2BC and 2C horizons exposed at the surface. Eroded soil sediments were transported downslope onto the kettle floors. Following erosion, silt-rich ...

1992-01-01

220

Analysis of acidic compound classes in crude oil by negative ion electrospray ionization high resolution FT-ICR mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

Acidic constituents in crude oil are associated with the formation of stable emulsions during production and present a challenge for efficient oil recovery and processing. Acid molecules, including naphthenic acids and acidic sulfur in crude oil cause corrosion in refineries and pipelines. Naphthenic acids are also significant because of their surface activity and marginal water solubility, so that they may leach to wastewaters and cause adverse environmental effects. Acidic components of oil are not limited to carboxylic acids but also molecules that contain sulfur and nitrogen. As such, an improved understanding of the chemistry and physics of petroleum at the molecular level is needed in order to understand the range of problems associated with acidic oil components and to design better solutions. The applications of negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for speciation of acidic oil compound classes was ...

2008-07-01

221

contents - NASA History Office  

Science.gov (United States)

David N. Spires and Rick W. Sturdevant, "From Advent to Milstar: The United States Air Force and the Challenges of Military Satellite Communications. Chapter 8 ...

222

WC-TiC-Ni cemented carbide with enhanced properties  

British Library Electronic Table of Contents (United Kingdom)

In the paper, the effect of Ni content, WC grain size and Mo2C addition on WC-6.25wt%TiC-9.3wt%Ni cemented carbide were investigated to improve the properties of Ni-bonded cemented carbides. The results show that the decrease of Ni content will result in the decrease of transverse rupture strength and increase of hardness; with the decrease of WC particle size, hardness increases due to the refinement of WC grains, however, the transverse rupture strength decrease due to the decrease of Ni binder thickness; Mo2C proves to be an effective grain growth inhibitor. With the increase of Mo2C content, the WC grains are refined and the hardness and transverse rupture strength are improved. Generally, when the Ni content is decreased to 8.4wt%, 13.45mm WC is used and 1.2wt% Mo2C is added, a higher...

2008-01-01

223

USAID Policy: Competitive Sourcing  

Science.gov (United States)

Skip to main content About USAID Locations Our Work Public Affairs Careers Business / Policy USAID: From The American People Policy USAID's 50th Anniversary Policy Home »...

2011-09-25

224

The Anniversary History of Weather Radar Research (40th) in ...  

Science.gov (United States)

... water content according to the hydrometeor type. ... the documentation and the movement personnel and ... Dyer, RM, 1970: Particle fall speeds within ...

1989-01-30

225

Teaching Patient Assessment Skills to Doctor of Pharmacy Students: The TOPAS Study  

UK PubMed Central (United Kingdom)

ObjectivesTo determine the content and extent, design, and relative importance of patient assessment courses in the professional pharmacy curriculum.MethodsA...Full Text Available

2007-08-15

226

Synthesis of magnetic particles via a cationic-anionic surfactant vesicle method  

Energy Technology Data Exchange (ETDEWEB)

In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe{sup 3+} and Fe{sup 2+}) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.

2006-10-15

227

Synthesis of magnetic particles via a cationic-anionic surfactant vesicle method  

International Nuclear Information System (INIS)

In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe"3"+ and Fe"2"+) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.

2006-10-01

229

Loss of Skeletal Calcium by Patients on Maintenance Dialysis  

UK PubMed Central (United Kingdom)

Direct radiological measurements of the mineral content of femoral bone were performed in 13 patients on maintenance dialysis. They were found to be sufficiently sensitive to be used for monitoring,...Full Text Available

1970-08-29

230

Laser Raman microscopic studies of passive films formed on type 316LN stainless steels during pitting in chloride solution  

Energy Technology Data Exchange (ETDEWEB)

The surface films formed on type 316LN stainless steels (SS) with different nitrogen contents, during potentiodynamic polarization in acidified 1 M NaCl solution, were characterized by Laser Raman Spectroscopy (LRS). LRS confirmed the presence of oxides and oxychlorides of iron and chromium, hydrated chlorides and nitrates in the film. Raman mapping showed increasing nitrate content in the film with increasing nitrogen content. The film on the uncorroded material showed the presence of chromium and molybdenum oxides. The improvement in pitting corrosion resistance of type 316LN SS with increasing nitrogen content was attributed to increased amount of nitrates in the passive film.

2010-06-15

231

Laser Raman microscopic studies of passive films formed on type 316LN stainless steels during pitting in chloride solution  

International Nuclear Information System (INIS)

The surface films formed on type 316LN stainless steels (SS) with different nitrogen contents, during potentiodynamic polarization in acidified 1 M NaCl solution, were characterized by Laser Raman Spectroscopy (LRS). LRS confirmed the presence of oxides and oxychlorides of iron and chromium, hydrated chlorides and nitrates in the film. Raman mapping showed increasing nitrate content in the film with increasing nitrogen content. The film on the uncorroded material showed the presence of chromium and molybdenum oxides. The improvement in pitting corrosion resistance of type 316LN SS with increasing nitrogen content was attributed to increased amount of nitrates in the passive film.

2010-06-01

233

Health Information for Travelers to Iran - Travelers' Health...  

Science.gov (United States)

please visit this page: About CDC.gov. Travelers' Health Home Destinations (238) Iran Regions Vaccinations News & Announcements Travel Notices Diseases Yellow Book Contents...

2011-09-04

234

Handbook of Dangerous Animals for Field Personnel  

Science.gov (United States)

... 110 Page 9. CONTENTS (Continued) Evaluation of Antivenin for Common Cobra (Naja naja) and Blue Krait (Bungarus caeruleus) Venoms I 13 ...

1972-12-01

235

Evergreen broad-leaved forest improves soil water status compared with tea tree plantation in Ailao Mountains, Southwest China  

British Library Electronic Table of Contents (United Kingdom)

In this paper, the spatial-temporal dynamics of soil moisture content was investigated in an evergreen broad-leaved forest and a tea tree plantation in Ailao Mountains, which was dominated by Fagaceae (Castanopsis wattii and Lithocarpus xylocarpus). Soil moisture content was studied between January 2005 and December 2006 at different depths (from 0-150 cm) with a neutron probe. The results showed that mean soil moisture content in the evergreen broad-leaved forest was usually higher than in the tea tree plantation in the dry season, whereas it was lower than the tea tree plantation in the rainy season. In addition, mean soil moisture content was depth dependent, and in the 10-50 cm layer the spatial variability was due to the active root zone within this depth area in two types of land use...

2011-01-01

236

Evaluation of adhesive bonded sandwich panels for ...  

Science.gov (United States)

... content of the environment) are significant factors affecting the useful service life of adhesive bonded plastic composite sandwich panels at 650 F ...

1970-10-01

237

Effect of some chemicals on the radiation-induced lipid peroxidation  

International Nuclear Information System (INIS)

The effect of exposure to gamma rays on LPO contents in liver, spleen and kidney of mice and the anti-lipid-peroxidation of preparations of chinonin, tannic acid and squalene were reported. All these preparations were given by intragastric perfusion. For LPO, a modified method of TBA spectrophotometry was used for determination. The results show that LPO contents in tissues increased 72 h after whole-body exposure of mice to gamma rays, that in range of 0-4 Gy, there was a linear relationship between radiation doses and LPO contents, and that all three preparations were effective in reduction of the LPO content in liver, spleen and kidney of mice, with chinonin (at dose of 0.35 mg/mouse#centre dot#day) being more effective than tannic acid (at dose of 15 mg/mouse#centre dot#day) and squalene (at dose of 0.6 mg/mouse#centre dot#day).

238

Continuing the Work to Advance Normal Birth  

UK PubMed Central (United Kingdom)

The editor of The Journal of Perinatal Education describes the contents of this issue, which offer a broad range of resources, research, and inspiration for childbirth educators.

2005-01-01

239

Contents of polycyclic aromatic hydrocarbons (PAH) and phenolic substances in Frankfurter-type sausages depending on smoking conditions using glow smoke  

British Library Electronic Table of Contents (United Kingdom)

The contents of polycyclic aromatic hydrocarbons (PAH) and phenolic substances in Frankfurter-type sausages were investigated depending on hot smoking conditions (glow smoke). For the 24 smoking experiments (performed in duplicates) three different smoke densities and ventilator velocities as well as wood chips with five different moisture contents were tested. During the smoking process, concentrations of O"2, CO"2 and CO, humidity and temperature in the smoking chamber as well as smoke generation temperature were determined. The chemical analysis included the contents of the 15+1 EU priority PAH and the phenolic substances guaiacol, 4-methylguaiacol, syringol, eugenol and trans-isoeugenol. The smoking conditions had a significant influence on smoke generation temperature, organoleptic pr...

2012-01-01

240

Content of hydrogen, helium, and heavy elements in Procyon  

Energy Technology Data Exchange (ETDEWEB)

The values of X = 0.77, Z = 0.035, and Y = 0.195 and the stage of evolution of Procyon are determined from the evolutionary tracks and the results of an analysis of the chemical composition of the atmosphere.

1985-05-01

241

Chemical plant factors affecting resistance in sugarcane in against Scirpophaga Nivella f  

International Nuclear Information System (INIS)

The study was conducted during 2000 to determine the role of various chemical plant factors viz., total minerals, nitrogen, fat contents, carbohydrate, macro an micro nutrients in the leaves of five genotypes of sugarcane i.e., BF-162, SPSG-26, L-118, CP-43/33 and CP-72/2086 by correlating the infestation of top borer, Scirpophaga Nivella F. at tillering stage. None of the genotype was found completely resistant to the pest. CP-43/33 and BF-162 proved susceptible and resistant varieties, respectively. Total mineral, manganese and copper contents did not show significant correlation with the pest infestation, whereas nitrogen, potassium, calcium, magnesium and ferrous contents played a positive and significant role. Phosphorous, carbohydrates, fats and zinc contents played a significant and negative effect on the pest infestation at tillering stage. (author)

242

CH-TRU Waste Content Codes (CH-TRUCON)  

Energy Technology Data Exchange (ETDEWEB)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table ...

2007-08-15

243

CH-TRU Waste Content Codes (CH-TRUCON)  

Energy Technology Data Exchange (ETDEWEB)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table ...

2007-06-15

244

CH-TRU Waste Content Codes (CH-TRUCON)  

Energy Technology Data Exchange (ETDEWEB)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table ...

2005-06-20

245

Bone geometry, biomechanics, and mineral content of the distal radius in uremic patients with severe hyperparathyroidism  

International Nuclear Information System (INIS)

Bone integrity and mineral status were studied with a noninvasive method in uremic patients with severe secondary hyperparathyroidism undergoing maintenance hemodialysis.

1999-04-01

246

Biogenesis of the Protein Storage Vacuole Crystalloid  

UK PubMed Central (United Kingdom)

We identify new organelles associated with the vacuolar system in plant cells. These organelles are defined biochemically by their internal content of three integral membrane proteins: a chimeric reporter...Full Text Available

2000-08-21

247

Apparatus for in situ determination of burnup cooling time and fissile content of an irradiated nuclear fuel assembly in a fuel storage pond  

Energy Technology Data Exchange (ETDEWEB)

A detector head for in situ inspection of irradiated nuclear fuel assemblies submerged in a water-filled nuclear fuel storage pond. The detector head includes two parallel arms which extend from a housing and which are spaced apart so as to be positionable on opposite sides of a submerged fuel assembly. Each arm includes an ionization chamber and two fission chambers. One fission chamber in each arm is enclosed in a cadmium shield and the other fission chamber is unshielded. The ratio of the outputs of the shielded and unshielded fission chambers is used to determine the boron content of the pond water. Correcting for the boron content, the neutron flux and gamma ray intensity are then used to verify the declared exposure, cooling time and fissile material content of the irradiated fuel assembly.

1985-04-09

248

:z:..... \\ - NASA Technical Report Server (NTRS)  

Science.gov (United States)

A common reinforced liner material is a cloth formed of PTFE fibers and fiber of ... and ablation protection provided. All of these methods of thermal ..... The influence of fiber content on the microstructures of the composites is ...

249

Three-Dimensional Dispaly Of Document Set  

Energy Technology Data Exchange (ETDEWEB)

A method for spatializing text content for enhanced visual browsing and analysis. The invention is applied to large text document corpora such as digital libraries, regulations and procedures, archived reports, and the like. The text content from these sources may be transformed to a spatial representation that preserves informational characteristics from the documents. The three-dimensional representation may then be visually browsed and analyzed in ways that avoid language processing and that reduce the analysts' effort.

2003-06-24

250

The content of natural radioactive materials in phosphate fertilizers and their contribution to the radiation exposure of the human population  

International Nuclear Information System (INIS)

The Ra, Th, and K-40 content of the most important phosphate fertilizers used and authorized in the FRG was determined by #gamma#-spectroscopy. The results, together with statistical data on the consumption and use of fertilizers, were used for an estimation of the contribution of #gamma#-radiation from phosphate fertilizers to the external population exposure in the FRG. (orig./AK).

1974-09-23

251

Stability ranges of Li-#alpha#'-sialons  

International Nuclear Information System (INIS)

The formation of #alpha#'-sialon using Li as a modifying cation was investigated. The effects of the Li content, firing temperatures and Si/Al ratios on #alpha#'- yield were studied. The results indicated that at lower sintering temperatures the stabilisation of #alpha#'-sialons was obtained but the high weight losses of Li at higher temperatures limited the stabilisation. Increased ''Al'' content in the compositions resulted in an increase in the stability of Li-#alpha#'-sialon at higher temperatures, by the formation of a liquid phase which retains Li in the system. (orig.).

1993-10-04

252

Results and recommendations from studies of basic handling characteristics of solid biomass fuels  

Energy Technology Data Exchange (ETDEWEB)

Main results are summarised for a project carried out with the aim of increasing the knowledge of relations between handling characeristics and properties such as moisture content, particle size and shape etc. Handling characteristics that were studied: angle of repose, friction between fuel and different surfaces, the fuel`s tendency to bridge across openings, and its freezing characteristics. Some forty solid biomass fuels were studied, mainly wood fuels, with particle sized from 1 to 200 mm. New methods were developed for measurement of bridging across openings and freezing characeristics. The angle of repose varied between 25 and 55 deg. The particle shape had a significant influence, a high ratio of length/thickness gave a high angle of repose. When the fuel moisture content was increased the angle of repose first increased, then decreased, and finally increased again. The particle size had no influence. The friction depended more on the ...

1996-12-31

253

Pollution control instrumentation for oil and effluents  

Energy Technology Data Exchange (ETDEWEB)

This book provides discusses recent developments in oil pollution control instrumentation. Some of the topics covered are as follows: 1. Technical requirements of the IMCO International Performance and Test Specification A393x concerning oil content meters; and 2. Oil in water detection; and 3. Methods for the disposal of recovered oil and oily sludge; and 4. Oil content monitoring at ballast water treatment facilities and offshore production platforms.

1986-01-01

254

Peculiarity of counterion - polyion interactions in aqueous solutions of copolymers of acrylamide with cadmium acrylate  

Energy Technology Data Exchange (ETDEWEB)

Binding of Cd/sup 2 +/ ions in aqueous solutions of statistical copolymers of acrylamide with cadmium acrylate with different content of ionogenic groups in copolymers was investigated by polarography, conductometry, viscometry and dialysis. It is shown that the degree of binding of Cd/sup 2 +/ ions increases with increasing of the content of ionogenic groups in the copolymer and with decreasing of ionic strength of the solution. The values of the degree of binding of Cd/sup 2 +/ ions obtained by polarography and dialysis show satisfactory agreement.

1984-02-01

255

Guarantee outline of radiation hardening for satellite  

International Nuclear Information System (INIS)

The Guarantee Outline presents the technical demands of design and contents of assessment for radiation hardening in satellite engineering in China. It includes the basis of design in space environment of polar orbit, the contents of design for general radiation hardening, the requirements and assessments of the single-board computer, the requirements of design for circuits (including hardware and software), the choices and assessments for devices, and the primary stipulations for the requirements of design and assessments against the phenomenon of charge and discharge.

256

Effect of WC particle size on grain growth inhibition in the WC-xVC-Co system  

Energy Technology Data Exchange (ETDEWEB)

The effect of WC particle size with the addition of VC as a grain growth inhibitor was investigated during the liquid phase sintering of WC-Co system. With increasing WC particle size at the same VC content, the effect of grain growth inhibition was increased. Also, with increasing the VC content, the grain shape of WC was changed from the faceted shape to the distorted shape, and the step density of the WC grain was increased. (orig.)

2003-07-01

257

Dispersed alkali elements in minerals and products of natural salts processing  

International Nuclear Information System (INIS)

Distribution of scattered elements in basic minerals of salt-rocks is studied. It is shown that rubidium and cesium are accumulated mainly in carnallites and are contained in small quantities halites. These elements are accumulated primarily in the carnallite production products, wherein their content in a number of cases exceeds by dozens and hundred times their content in source rocks. It is noted that only carnallites may be considered in the list of actual sources for rubidium and cesium separation

1995-06-01

258

Determination of the conversion factor for infrared measurements of carbon in silicon  

Energy Technology Data Exchange (ETDEWEB)

The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.

1986-10-01

259

Sulfur content of non-blast furnace coke from coal from the Cheremkhovo Deposit of the Irkutsk Coalfield  

Science.gov (United States)

The non-blast furnace coke produced in the shaft ovens of the Angarsk Semi-coking Plant is used principally in gas generator ovens and partially as a carbonaceous reducing agent in the ferroalloy process. The sulfur content of this coke is not limited by the standards documents, but it is significant, especially in the production of process gases. In a number of recent years the sulfur removal system of the gasification divisions have been experiencing difficulties, not achieving the assigned gas purification parameters, with a resulting H/sub 2/S concentration in the purified gas of 300-700 mg/m/sup 3/ as compared to the standard of 50. Realizing that in the gasification practically all the organic matter of the coke, including the sulfur, enters the gas, the impairment in the quality of the sulfur removal is related to the increase in the sulfur content of the coke. Thus, an analysis of the results was conducted for the determination of the ...

1984-01-01

260

Hydrothermal synthesis of semiconductive PZT solid solutions and electromechancal properties of sintered bodies. Suinetsuho ni yoru handosei PZT koyotai no gosei to shoketsutai no denki kikaiteki seishitsu  

Energy Technology Data Exchange (ETDEWEB)

Semiconductive crystalline PZT powders doped with Bi and K were synthesized by hydrothermal reaction at 200{degree}C for 48 hours. The synthesis of the crystalline powders became difficult with an increase in doped amount of Bi and K, and in Zr/(Ti+Zr) ratio. Since substantial amounts of Pb remained in solution after hydrothermal reaction, the addition of Pb in excess of 25% was necessary to obtain the stoichiometric composition of the PZT solid solution. Bi contents in the powders were identical to those in starting materials, while K contents were less than expected ones. The electromechanical properties of the sintered bodies could be precisely measured by an admittance-curve-fitting method. The electromechanical coupling factor and piezoelectric coefficient of the sintered bodies varied with the Bi content like those of specimens prepared by solid state reaction, and showed the maximum values at a given Bi ...

1989-10-01

261

Ellipsometry studies on nitrogenated diamond-like carbon (DLC) thin films produced by RF magnetron sputtering  

International Nuclear Information System (INIS)

Nitrogen doped Diamond-like carbon thin films were deposited on n-Si and SiO_2 substrates by rf magnetron sputtering using pure graphite (99.999%) as the target material and mixtures of Ar, N_2 and H_2 for plasma generation. The dependence of structural and optical properties on nitrogen content was investigated using XPS, Raman spectroscopy, FT-IR spectroscopy, and Ellipsometry studies. It was found that as the nitrogen content was increased in the plasma, sp"2 bonding favored. Also it was observed that oxygen contamination increased with nitrogen content. Typical C-H stretching modes connected with diamond-like carbon could be seen in FT-IR spectra. The I_D and I_G bands were well defined and it was observed that as nitrogen content increased I_G band was enhanced. Ellipsometry studies revealed that the optical constants like refractive index (n) and extinction co-efficient (k) increased with increase ...

2003-03-01

262

Development of structural steels for nuclear application - Enhancement of corrosion resistance of stainless steels for nuclear power plant  

Energy Technology Data Exchange (ETDEWEB)

Fe-Cr-Mn stainless steel is one of the candidate materials for the 1`st wall materials and structural applications of fusion reactor as regards reduced radioactivation properties than Fe-Cr-Ni austenitic stainless steels. This report deals with the effects of annealing and aging heat treatment on the microstructure, mechanical properties and corrosion resistance of Fe-Cr-Mn alloys varying Mn and W contents, which were made using vacuum high frequency induction furnace. Increasing Mn contents, austenite phase was increased, and maximum .epsilon. martensite phase was formed at about 21% Mn. W-addition made small amount of ferrite phase in the matrix, and the ferrite contents were increased with raising annealing temperature. Increased Mn contents reduced tensile stress and yield stress but increased the elongation. W-addition raised the high temperature tensile properties. The variation of Mn ...

1996-07-01

263

Effects on surface hydrology and near-surface hydrogeology of an open repository in Laxemar Results of modelling with MIKE SHE  

Energy Technology Data Exchange (ETDEWEB)

This report presents the methodology and the results from the modelling of an open repository for spent nuclear fuel in Laxemar. Specifically, the present work analyses the hydrological effects of the planned repository during the construction and operational phases when it is open, i.e. air-filled, and hence may cause a disturbance of the hydrological conditions in the surroundings. The numerical modelling is based on the SDM-Site Laxemar MIKE SHE model. The modelling was divided into three steps. The first step was to update the SDM-Site Laxemar model with a new hydrogeological bedrock model. The other main updates were an increase of the depth of the MIKE SHE model domain, enhanced vertical computational resolution and that the drainage of the Aespoe Hard Rock Laboratory was included in the model. The resulting model was used to simulate undisturbed natural conditions. The next step was to describe the open repository conditions, using Laxemar layout D2, by implementing the access ...

2009-10-15

264

Performance and emission comparison of a supercharged dual-fuel engine fueled by producer gases with varying hydrogen content  

Energy Technology Data Exchange (ETDEWEB)

This study investigated the effect of hydrogen content in producer gas on the performance and exhaust emissions of a supercharged producer gas-diesel dual-fuel engine. Two types of producer gases were used in this study, one with low hydrogen content (H{sub 2} = 13.7%) and the other with high hydrogen content (H{sub 2} = 20%). The engine was tested for use as a co-generation engine, so power output while maintaining a reasonable thermal efficiency was important. Experiments were carried out at a constant injection pressure and injection quantity for different fuel-air equivalence ratios and at various injection timings. The experimental strategy was to optimize the injection timing to maximize engine power at different fuel-air equivalence ratios without knocking and within the limit of the maximum cylinder pressure. Two-stage combustion was obtained; this is an indicator of maximum power output conditions and a precursor ...

2009-09-15

265

Feasibility study of iron mineral separation from red mud by high gradient superconducting magnetic separation  

International Nuclear Information System (INIS)

Research highlights: #-># Red mud residues (RM) were disposed in alumina production. #-># Utilization of Red mud residues was affected by its iron content. #-># Superconducting magnetic separation (HGSMS) was used in iron separation from RM. #-># RM with high and low iron contents were separated in HGSMS. - Abstract: The disposal of bayer red mud tailings now seriously threats the environment safety. Reduction and recycling of red mud is now an urgent work in aluminum industry. High gradient superconducting magnetic separation (HGSMS) system was applied to separate the extreme fine RM particles (<100 #mu#m) into high iron content part and low iron content part. Two sorts of RM were fed in the HGSMS. The iron oxide contents in concentrates were about 65% and 45% when RM 1 and RM 2 were fed respectively. Meanwhile, the residues contained 52.0% or 14.1% iron oxide in ...

2011-02-01

266

Total phenolic content and antioxidant capacity of extracts obtained from six important fruit residues  

British Library Electronic Table of Contents (United Kingdom)

The extracts from kinnow peel, kinnow seeds, litchi pericarp, litchi seeds, grape seeds, and banana peel were screened for total phenolic content (TPC), trolox equivalent antioxidant capacity (TEAC), 1,1 diphenyl-2-picryl hydrazyl (DPPH) radical scavenging activity, as well as reducing power. Kinnow peel extract exhibited the highest reducing power, TEAC, and DPPH free radical scavenging activity, whereas, the phenolic content of 37.4 mg GAE/g-dw was highest for grape seed extract. Banana peel extract with a low TPC showed the lowest reducing power, TEAC as well as DPPH free radical scavenging activity among the fruit residue extracts examined in the present study. Correlation analysis between the reducing power and DPPH radical scavenging ability; reducing power and ABTS radical scavengin...

2011-01-01

267

The effect of oxygen enriched air obtained by gas separation membranes from the emission gas of diesel engines  

British Library Electronic Table of Contents (United Kingdom)

Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...

2006-01-01

268

System and method for non-destructive evaluation of surface characteristics of a magnetic material  

Energy Technology Data Exchange (ETDEWEB)

A system and a related method for non-destructive evaluation of the surface characteristics of a magnetic material. The sample is excited by an alternating magnetic field. The field frequency, amplitude and offset are controlled according to a predetermined protocol. The Barkhausen response of the sample is detected for the various fields and offsets and is analyzed. The system produces information relating to the frequency content, the amplitude content, the average or RMS energy content, as well as count rate information, for each of the Barkhausen responses at each of the excitation levels applied during the protocol. That information provides a contiguous body of data, heretofore unavailable, which can be analyzed to deduce information about the surface characteristics of the material at various depths below the surface.

1994-05-17

269

Radiosensitization of human lung fibroblasts by chemicals that decrease ATP levels  

International Nuclear Information System (INIS)

Radiosensitization by lactate, pyruvate, nalidixic acid and novobiocin was studied in exponentially growing SH-18L human lung fibroblasts. All the chemicals had a slight radiosensitizing effect at a low concentration and a definite effect at a higher one. Decreases in the D_0 and/or Dq values were present in each dose survival curve. Fibroblasts incubated with the low concentration of each chemical for 24 hrs after X irradiation showed no reduction in intracellular ATP content, whereas, the higher concentration produced a significant decrease. These observations suggest that the decrease in the ATP content may be involved in the radiosensitization of human fibroblasts at high concentrations of these chemicals. In contrast, radiosensitization at a low concentration is not explained by a relationship to ATP content. Different mechanisms may be involved in radiosensitization at low and high concentrations of these chemicals. ...

270

Probing Student Understanding of Scientific Thinking in the Context of Introductory Astrophysics  

Science.gov (United States)

Common forms of testing of student understanding of science content can be misleading about their understanding of the nature of scientific thinking. Observational astronomy integrated with related ideas of force and motion is a rich context to explore the correlation between student content knowledge and student understanding of the scientific thinking about that content. In this paper, we describe this correlation in detail with a focus on a question about the relative motion of the Sun and the Earth. We find that high achieving high school students throughout New York City struggle with what constitutes scientific justification and thought processes, but can improve these skills tremendously in an inquiry-oriented summer astronomy-physics program. (Contains 3 tables and 4 figures.)

2008-12-01

271

Preparation of nanocomposite dispersions based on cellulose whiskers and acrylic copolymer by miniemulsion polymerization: Effect of the silane content  

British Library Electronic Table of Contents (United Kingdom)

Abstract A one step method was used to prepare stable aqueous nanocomposite dispersions based on cellulose whiskers extracted from the rachis of the date palm tree and a poly(styrene co 2 ethyl hexylacrylate) copolymer via miniemulsion polymerization. A reactive silane, i.e., methacryloxypropyl triethoxysilane was added to stabilize the dispersion and favor the anchoring of the whiskers on polymer particles. Dynamic light scattering was used to study the effect of the silane and whiskers contents on the average particle size of the polymer. Nanocomposites materials were prepared from these dispersions using a casting/evaporation method. The effect of the silane and whiskers contents on the thermal and mechanical properties were studied using differential scanning calorimetry and dynamic me...

2011-01-01

272

Post harvest improvement of zeaxanthin content of vegetables  

British Library Electronic Table of Contents (United Kingdom)

Zeaxanthin is a carotenoid produced by plants and has been associated with protection of the photosynthetic machinery under light stress and, together with lutein, in protection of the central retina of the eye. Zeaxanthin levels in blood plasma have been negatively correlated to the development of AMD (age-related macular degeneration) (Gale et al., 2003). Under normal conditions, plants have a low content of zeaxanthin. The aim of this study was to increase the zeaxanthin content in green vegetables by post harvest treatments. Efficient conditions for activation of the endogenous enzyme system generating zeaxanthin was established and included incubation at low pH (2.5-5.5), with the membrane permeable acetic acid/acetate buffer at room temperature or above for 30min or more. Typically m...

2010-01-01

273

Method for the reduction of image content redundancy in large image databases  

Energy Technology Data Exchange (ETDEWEB)

A method of increasing information content for content-based image retrieval (CBIR) systems includes the steps of providing a CBIR database, the database having an index for a plurality of stored digital images using a plurality of feature vectors, the feature vectors corresponding to distinct descriptive characteristics of the images. A visual similarity parameter value is calculated based on a degree of visual similarity between features vectors of an incoming image being considered for entry into the database and feature vectors associated with a most similar of the stored images. Based on said visual similarity parameter value it is determined whether to store or how long to store the feature vectors associated with the incoming image in the database.

2010-03-02

274

Influence of sputtering parameters and nitrogen on the microstructure of chromium nitride thin films deposited on steel substrate by direct-current reactive magnetron sputtering  

International Nuclear Information System (INIS)

Chromium nitride thin films were deposited on SA-304 stainless steel substrates by using direct-current reactive magnetron sputtering. The influence of process conditions such as nitrogen content in the fed gas, substrate temperature, and different sputtering gases on microstructural characteristics of the films was investigated. The films showed (200) preferred orientation at low nitrogen content (< 30%) in the fed gas. The formation of Cr_2N and CrN phases was observed when 30% and 40% N_2 were used, with a balance of Ar, respectively. Field emission scanning electron microscopy and atomic force microscopy were used to characterize the morphology and surface topography of the thin films, respectively. Microhardness tests showed a maximum hardness of 16.95 GPa for the 30% nitrogen content.

2010-08-02

275

Evaluation of bone mineral content using Quantitative Computed Tomography  

International Nuclear Information System (INIS)

The authors have evaluated bone mineral content in the vertebral spongiosa by means of Computed Tomography. The method proposed by Genant and Cann [17, 18] has been applied to examine 164 healthy volunteers and 108 patients. Both healthy males and females showed a progressive bone mineral loss increasing with age; the bone mineral loss was most severe in females during the 4th and 5th decade of life. Pathology included patients with osteoporotic fractures (vertebral and femural neck), patients with partial gastrectomy, renal failure, primary hyperparathyroidism, Cushing syndrome, corticosteroid therapy. Bone mineral values were significantly lower in most pathologic groups. Computed Tomography proves thus to be a valuable method to assess bone mineral content and to identify patients at risk for fractures.

1988-01-01

276

Effects of pre- and postnatal exposure to tritiated water for five generations on postnatal brain development  

International Nuclear Information System (INIS)

The possible long-term effects of chronic radiation exposure have been studied. Rats were given tritiated drinking water (3 #mu#Ci/ml) before and during pregnancy and thereafter continuously through five generations. The brains were studied at 30 and 120 days postnatally. Significant decreases in weight and DNA and protein contents of specific parts of the brain were found, the most pronounced decreases being in the diencephalon. The decrease in protein content were more pronounced than the decreases in DNA content; the decreases were also more pronounced at 30 days than at 120 days, and more pronounced in the fith generation than in previous generations.

277

Effects of boron addition on weldability and high temperature strength properties of Hastelloy alloy XR  

Energy Technology Data Exchange (ETDEWEB)

The effects of boron addition on weldability and high temperature strength properties were investigated for Hastelloy alloy XR used TIG welding process with the filler metals. Four versions of filler metals with different boron contents were used. The results obtained may be summarized as follows: (1) The influence of boron addition on weldability was not observed within the range of the present experiment. (2) The result of chemical analysis for deposited metals showed that boron desorption did not occur during welding. (3) The tensile properties of weldments, particularly in high temperature ductility were raised with increasing boron content. (4) In the creep properties of weldments, creep rupture life increased with increasing boron content under the given stress conditions. (author).

1990-11-01

278

Effects of boron addition on weldability and high temperature strength properties of Hastelloy alloy XR  

International Nuclear Information System (INIS)

The effects of boron addition on weldability and high temperature strength properties were investigated for Hastelloy alloy XR used TIG welding process with the filler metals. Four versions of filler metals with different boron contents were used. The results obtained may be summarized as follows: 1) The influence of boron addition on weldability was not observed within the range of the present experiment. 2) The result of chemical analysis for deposited metals showed that boron desorption did not occur during welding. 3) The tensile properties of weldments, particularly in high temperature ductility were raised with increasing boron content. 4) In the creep properties of weldments, creep rupture life increased with increasing boron content under the given stress conditions. (author).

279

Comparison of stomach contents and condition of two catfish species living at ambient temperatures and in a heated discharge  

International Nuclear Information System (INIS)

The lower condition factors for two catfish species in water heated by effluents from APCo's Glen Lyn, Virginia plant as compared to control areas probably is not due to lack of food as evidenced by macroinvertebrate sampling and the fact that only 4.3 percent of the catfish stomachs were empty. Results suggested that young-of-the-year channel catfish were nonselectively eating food organisms present at both control and heated stations. The difference between stomach contents of flatheat catfish from the heated site and fauna available at that site indicated that fish were either moving out of the heated area to feed or were selectively feeding on organisms (particularly mayflies) which were in the substrate or drifted into the heated area. Stomach contents of the two species and distribution and abundance of the macroinvertebrate benthos community are detailed.

280

Clostridiaceae and Enterobacteriaceae as active fermenters in earthworm gut content  

British Library Electronic Table of Contents (United Kingdom)

The earthworm gut provides ideal in situ conditions for ingested heterotrophic soil bacteria capable of anaerobiosis. High amounts of mucus- and plant-derived saccharides such as glucose are abundant in the earthworm alimentary canal, and high concentrations of molecular hydrogen (H2) and organic acids in the alimentary canal are indicative of ongoing fermentations. Thus, the central objective of this study was to resolve potential links between fermentations and active fermenters in gut content of the anecic earthworm Lumbricus terrestris by 16S ribosomal RNA (rRNA)-based stable isotope probing, with [13C]glucose as a model substrate. Glucose consumption in anoxic gut content microcosms was rapid and yielded soluble organic compounds (acetate, butyrate, formate, lactate, propionate, succi...

2011-01-01

281

Chronic irradiation and brain development. Final (4th) progress report  

International Nuclear Information System (INIS)

The possible long term effects of chronic radiation exposure have been studied. Rats were given tritiated drinking water (3#mu#Ci/ml) before pregnancy, during pregnancy and threafter, continuously through 5 generations. The brains were studied at 30 and 120 days postnatally. Significant decreases in weight, DNA and protein contents of specific parts of the brain were found, the most pronounced decreases being in the diencephalon. The decreases in protein content were more pronounced than the decreases in DNA content; the decreases were also more pronounced at 30 days than at 120 days, and more pronounced in the fifth generation than in previous generations. An attempt was made to explain these complex phenomena on the basis of known periods of proliferation of various brain cells, damage to mothers themselves in each generation, and damage and repair of nucleic acids caused by radioactivity.

282

Chemical resistance, void content and tensile properties of oil palm/jute fibre reinforced polymer hybrid composites  

British Library Electronic Table of Contents (United Kingdom)

Tri layer hybrid composites of oil palm empty fruit bunches (EFB) and jute fibres was prepared by keeping oil palm EFB as skin material and jute as the core material and vice versa. The chemical resistance, void content and tensile properties of oil palm EFB/Jute composites was investigated with reference to the relative weight of oil palm EFB/Jute, i.e. 4:1, the fibre loading was optimized and different layering pattern were investigated. It is found from the chemical resistance test that all the composites are resistant to various chemicals. It was observed that marked reduction in void content of hybrid composites in different layering pattern. From the different layering pattern, the tensile properties were slightly higher for the composite having jute as skin and oil palm EFB as core ...

2011-01-01

283

Changes in DNA content during rhizobial nodule development in Lupinus luteus L. 1  

International Nuclear Information System (INIS)

Cytophotometric measurements of DNA content after Feulgen's reaction and autoradiography after incubation with "3H-thymidine were performed to investigate the early stages of development of yellow lupin root nodule. The first response of the host plant to the contact with Rhizobium lupini was the enhancement of nuclear DNA endoreplication in root cortex cells. A conversion of the initially mixoploid nodule meristem into a diploid one during root nodule formation was found. Differentiation of bacteroid-containing tissue both from diploid and polyploid cells was observed. The highest content of nuclear DNA in the uninfected root cortex, nodule cortex and in bacteroid-containing tissue was 16 C. (author).

1989-01-01

284

Change from polycrystalline to amorphous growth in sputtered CoZr/Cu multilayers  

International Nuclear Information System (INIS)

The authors present an investigation of structural changes occurring in bilayer stacks with crystalline columnar growth when one of the layers is substituted by layers known to grow amorphous. In Co/Cu multilayers the Co layers were substituted by CoZr layers of varying Zr content and layer thickness. Structural characterization was performed by transmission electron microscopy (TEM). They show that the amorphization of the CoZr layers leading to a destruction of the columnar growth depends both on the Zr content and on the thickness of the CoZr layers. Additionally a change to textured growth with a normal to the substrate occurs with increasing Zr content. They explain their observations by a simple picture based on the hard sphere model.

1997-04-04

285

Biomechanical properties of the femoral neck relative to osteosynthesis methods and bone mineral content assessed by computed tomography  

International Nuclear Information System (INIS)

Bone mineral content as determined by computerized tomography (CT) and mechanical strength on axial loading were compared in 36 cadaveric femur specimens. Based on the CT measurements of density and area, the mass of a transverse slice of the femur was estimated. Highly significant correlations were demonstrated between strength and cancellous bone density. Even higher correlations were revealed when the bone masses of the proximal and distal femoral areas were calculated. Based on these findings, an equal distribution of the effective mass of the femur was postulated. This hypothesis was confirmed in an experimental rotational model. The CT attenuation values were also correlated to direct measurements of bone mineral content, i.e. calcium. Moreover, the strength of different metal implants, commonly used in femoral neck fractures, were assessed in cadaver specimens. 134 refs., 13 figs., 12 tabs.

286

Antioxidant phytochemicals and gingerol content in diploid and tetraploid clones of ginger (Zingiber officinale Roscoe)  

British Library Electronic Table of Contents (United Kingdom)

Fresh rhizomes of 18 diploid and tetraploid genotypes of Indian ginger, including commercial cultivars and experimental genotypes, were assayed for gingerol content and antioxidant activity. The tetraploid ginger type was derived from the respective diploid ginger by shoot tip culture. [6]-Gingerol was identified as the major pungent phenolic compound in all samples (mean 1354.78+/-470mg/g), while [8]- (mean 180.94+/-45mg/g) and [10]-gingerol (mean 234+/-79mg/g) occurred in lower concentrations. The total gingerol content of the tetraploid type was much higher than that of the respective diploid type and especially the [10]-gingerol. Both diploid and tetraploid types of the cv. Meghalaya Local contained the highest level of gingerol. At both ploidy levels, the genotypes showed significant ...

2010-01-01

287

Accumulation of glycosaminoglycans in radiation-induced muscular fibrosis  

Energy Technology Data Exchange (ETDEWEB)

The content and biosynthesis of glycosaminoglycans (GAGs) were studied in pig thigh muscle after acute local {gamma}-irradiation. Seven months following irradiation, the muscular tissue next to the irradiation cone was replaced by severe mutilating fibrosis delimited by an intermediary perifibrotic zone. Results showed a parallel increase of collagen and GAG content in perifibrotic and fibrotic tissues. Sulphated GAGs, heparan sulphate and dermatan sulphate were preferentially accumulated in fibrotic tissue, while the hyaluronic acid content increased only slightly. Synthesis of sulphated GAGs was more elevated in fibrotic tissue than in perifibrotic zone as compared with normal muscle. Seven months after irradiation well-developed fibrotic tissue continued to synthesize and to accumulate extracellular matrix macromolecules. (Author).

1992-05-01

288

A report on the CCNA 2007 professional practice analysis.  

Science.gov (United States)

The purpose of this column is to present the results of the 2007 Professional Practice Analysis (PPA) of the field of nurse anesthesia, conducted by the Council on Certification of Nurse Anesthetists. The PPA used survey and rating scale methodologies to collect data regarding the relative emphasis of various aspects of the nurse anesthesia knowledge domain and competencies. A total of 3,805 survey responses were analyzed using the Rasch rating scale model, which aggregates and transforms ordinal (rating scale) responses into linear measures of relative importance and frequency. Summaries of respondent demographics and educational and professional background are provided, as well as descriptions of how the survey results are used to develop test specifications. The results of this analysis provide evidence for the content outline and test specifications (content percentages) and thus serve as a basis of content validation ...

2009-06-01

289

The ternary silicide ZrPd{sub 3}Si{sub 3}, a stacking variant of the {alpha}-FeSi{sub 2} and Re{sub 3}B structure types  

Energy Technology Data Exchange (ETDEWEB)

The ternary zirconium palladium silicide ZrPd{sub 3}Si{sub 3} has been synthesized by arc-melting of the elemental components. It adopts a new structure type and crystallizes in the orthorhombic space group Cmcm with a = 3.8127(4){angstrom}, b = 15.551(1){angstrom}, c = 7.0390(5){angstrom}, and Z = 4 (Pearson symbol oC28). The structure can be regarded as being built up of Re{sub 3}B-type slabs of composition Pd{sub 3}Si alternating with {alpha}-FeSi{sub 2} slabs of composition ZrSi{sub 2}. Notable features include the presence of Si{sub 2} pairs, square pyramidal and tetrahedral coordination of Pd centers by Si atoms, an unusual distorted cubic coordination of the Zr atoms by the Si{sub 2} pairs, and an extensive network of Zr-Zr, Zr-Pd, and Pd-Pd metal-metal bonds. ZrPd{sub 3}Si{sub 3} is weakly metallic with a room-temperature resistivity of 1.7 x 10{sup {minus}3} {Omega} cm. Extended Hueckel band structure calculations confirm the metallic behavior; support the ...

1999-11-01

290

Tantalum nitride and tungsten as diffusion barriers for palladium and cobalt silicides in multilayer metallization schemes  

Science.gov (United States)

The efficiency of two thin-film diffusion barriers to be used in silicide/aluminum metallization schemes for silicon integrated circuits were evaluated. Control samples of Si/CoSi{sub 2}/Al and Si/Pd{sub 2}Si/Al, and test samples of Si/CoSi{sub 2}/Ta{sub 2}N/Al, Si/CoSi{sub 2}/W/Al and Si/Pd{sub 2}Si/Ta{sub 2}N/Al were used for sheet resistance, X-ray diffraction, Rutherford backscattering, and Auger-electron spectroscopic measurements. TEM studies were carried out on representative samples to examine the nature of the interfaces. Results from the analytical tests indicated that all three types of test samples are resistant to gross diffusion and intermixing of Co, Pd, Al and Si. They also showed that in the control samples, annealing causes interdiffusion of these species, necessitating the presence of a diffusion barrier. For test contacts, results demonstrated that although diffusion barriers may be successful in preventing metallurgical interdiffusion, they may not be viable in ...

1988-01-01

291

Structure and electronic studies of defects in amorphous silicon. Final report, March 1980-February 1981  

Science.gov (United States)

Basic research of the structure and electronic properties of a-Si:H is reported with particular emphasis on the role of defects. The main findings are as follows: (1) low defect density material can be deposited at a high rate using SiH/sub 4/ diluted in He or Ne. Using Ar or Kr results in a high defect density and columnar material; (2) an electrical bias during deposition modifies the band gap, hydrogen concentration and structure; (3) the clustering of hydrogen in the regions between the columns is confirmed; (4) hydrogen diffusion is observed by NMR; (5) the oxidation of an a-Si:H surface results in approx. 3 x 10/sup 11/ cm/sup -2/ dangling bonds at the interface; (6) auger recombination of photoexcited carriers is a significant non-radiative mechanism at low temperatures; (7) non-radiative recombination by diffusion and capture at dangling bonds is observed at temperatures above 50 to 100/sup 0/K; (8) the defect density in doped and compensated a-Si:H is determined by the ...

1981-08-01

292

Schottky barrier and homojunction gallium arsenide solar cells  

Energy Technology Data Exchange (ETDEWEB)

New techniques were developed to construct Schottky barrier and homojunction solar cells on GaAs substrates. Schottky barrier metal-semiconductor solar cells were produced for the first time on p-type GaAs substrate using a sputter-deposition method to form the barrier. The sputter deposition of gold or gold/palladium is the key to the method since normal thermal evaporation of gold onto p-type GaAs produces ohmic contacts. The results of this investigation are consistent with the idea that sputter damage produces donor type surface states on GaAs. Barrier heights were measured for both p-type sputtered and n-type thermally evaporated diodes using current-voltage and capacitance-voltage methods. Deep-level transient spectroscopy was used to identify the trap center concentration and energy levels for both diodes in an effort to explain the relatively large dark current in the p-type sputtered diodes. Homojunction GaAs solar cells were fabricated using several ...

1983-01-01

293

A systematic neutron reflectometry study on hydrogen absorption in thin Mg{sub 1-x}Al{sub x} alloy films  

Energy Technology Data Exchange (ETDEWEB)

Various methods for storing hydrogen have been examined in an effort to find ways to store hydrogen in increasingly smaller volumes with decreasing weight of the whole hydrogen storage system. Metal hydrides, in which hydrogen is chemically bound to a metal atom, are considered to be very promising candidates for hydrogen storage because they have high gravimetric and volumetric storage capacities. This study investigated the effect of different magnesium (Mg) and aluminium (Al) ratios on the absorption and desorption properties of thin films. Neutron reflectometry (NR) was used in this study to better understand the absorption and desorption properties of commercially promising hydrogen storage materials. The large negative scattering length of hydrogen atoms changes the reflectivity curve substantially, so that NR can determine the total amount of stored hydrogen as well as the hydrogen distribution along the film normal, with nanometer resolution. In order to use NR, the samples ...

2010-10-15

294

Yield-increasing additives in kraft pulping: Effect on carbohydrate retention, composition and handsheet properties  

Energy Technology Data Exchange (ETDEWEB)

In this thesis, increased hemicellulose retention during kraft pulping has been studied. The work has been divided into three parts: i) Development of an accessible and reliable method for determination of carbohydrate composition of kraft pulps ii) Investigation of the composition and molecular mass distributions of the carbohydrates in kraft pulps with increased hemicellulose content iii) Investigation of the effect of increased hemicellulose content on the sheet properties of kraft pulps with increased hemicellulose content. A method for carbohydrate determination was developed. In this method, enzymes are used to hydrolyse the pulp into monosaccharides. A relatively mild acid hydrolysis is performed prior to detection on an HPLC with an RI-detector. The pulp is not derivatized and no pre-treatment (mechanical or chemical) is needed to determine the carbohydrate composition using the method developed here. Peak ...

2008-07-01

295

Ventilated Improved Pit Latrines: Recent Developments in Zimbabwe.  

Science.gov (United States)

Contents: Ventilated improved pit latrines; (General description, odor control, insect control); Zimbabwean VIP latrine designs; (Latrine entrance, ferrocement spirals, rural spirals, training and education, design transfer).

1982-01-01

296

Usual Energy Intake from Saturated Fat  

Science.gov (United States)

Skip to Content Cancer Control and Population Sciences Home Applied Research Home Risk Factor Monitoring and Methods Home Diet Usual Dietary Intakes: Background The NCI Method Details of the NCI Method Food Intakes, US Population, 2001-04 Selected Intakes

297

Usual Energy Intake from Monounsaturated Fat  

Science.gov (United States)

Skip to Content Cancer Control and Population Sciences Home Applied Research Home Risk Factor Monitoring and Methods Home Diet Usual Dietary Intakes: Background The NCI Method Details of the NCI Method Food Intakes, US Population, 2001-04 Selected Intakes

298

Thermodynamic and structural analysis of microtubule assembly: the role of GTP hydrolysis.  

UK PubMed Central (United Kingdom)

Different models have been proposed that link the tubulin heterodimer nucleotide content and the role of GTP hydrolysis with microtubule assembly and dynamics. Here we compare the thermodynamics of...Full Text Available

1997-03-01

299

The concentration of natural radioactive materials in building materials  

International Nuclear Information System (INIS)

A survey is given on the results in hand on the natural radioactivity of building materials. It is shown that only a small percentage of building materials has an increased content of radioactive materials. The results are compared with approximate values given in a Russian publication. (orig./AK).

1974-09-23

300

The Role of an Online Community for People With a Rare Disease: Content Analysis of Messages Posted on a Primary Biliary Cirrhosis Mailinglist  

UK PubMed Central (United Kingdom)

BackgroundThis study focuses on the role of an Internet-based group for people who have an autoimmune liver disease, primary biliary cirrhosis. Primary biliary...Full Text Available

301

TEENET Cleaner Production Databases  

Wastenet

...of stations and a number of components, and meta information on air quality monitoring networks and stations. Access the database Producer Europe Environment Agency Content ...of stations and a number of components, and meta information on air quality monitoring networks and stations. Coverage National (Europe) Number of records...

302

Repeated tumor oximetry to identify therapeutic window during metronomic cyclophosphamide treatment of 9L gliomas  

UK PubMed Central (United Kingdom)

Malignant gliomas are aggressive and angiogenic tumors with high VEGF content. Consequently, approaches such as metronomic chemotherapy, which have an antiangiogenic effect, are being investigated....Full Text Available

2011-07-01

303

Regulations | Alternatives / SNAP | US EPA  

Science.gov (United States)

Jump to main content. [logo] US EPA Ozone Layer Protection - Alternatives / SNAP Recent Additions | Contact Us Search: All EPA This Area Go You are here: EPA Home Ozone Layer...

2011-10-06

304

Regulation of the brown and white fat gene programs through a PRDM16/CtBP transcriptional complex  

UK PubMed Central (United Kingdom)

Brown fat is a specialized tissue that can dissipate energy and counteract obesity through a pattern of gene expression that greatly increases mitochondrial content and uncoupled respiration. PRDM16...Full Text Available

2008-05-15

305

Regulation of Na(+)-K+ pump activity in contracting rat muscle.  

UK PubMed Central (United Kingdom)

1. In rat soleus muscle, high frequency electrical stimulation produced a rapid increase in intracellular Na+ (Na+i) content. This was considerably larger in muscles contracting without developing tension...Full Text Available

1997-09-15

306

Rapid Phytochrome-mediated Changes in Adenosine 5?-Triphosphate Content of Etiolated Bean Buds 1  

UK PubMed Central (United Kingdom)

This study was designed to determine the effects of red and far red irradiation on ATP metabolism in etiolated bean buds (Phaseolus vulgaris L. var. Red Kidney). Compared to dark controls,...Full Text Available

1974-01-01

307

Randomized controlled trial comparing four strategies for delivering e-curriculum to health care professionals [ISRCTN88148532  

UK PubMed Central (United Kingdom)

BackgroundInternet education is increasingly provided to health professionals, but little is known about the most effective strategies for delivering the content. The purpose of...Full Text Available

308

PtdIns 3-Kinase Orchestrates Autophagosome Formation in Yeast  

UK PubMed Central (United Kingdom)

Eukaryotic cells can massively transport their own cytoplasmic contents into a lytic compartment, the vacuole/lysosome, for recycling through a conserved system called autophagy. The key process in...Full Text Available

2011-01-01

309

Production and stability of implanted Pd-Si hydride  

Energy Technology Data Exchange (ETDEWEB)

Combining in situ Rutherford backscattering and electrical transport measurements on low-temperature hydrogen-implanted amorphous Pd/sub 80/Si/sub 20/ films, we have studied the correlation between the hydrogen content and the resistivity.

1983-05-01

310

Process for purifying alumina  

Energy Technology Data Exchange (ETDEWEB)

In a process for separating insoluble red mud from Bayer process streams the improvement is described which comprises contacting and mixing a Bayer process stream with a tertiary polyamine having a molecular weight of at least about 10,000 in an amount effective to reduce the iron content thereof.

1988-01-05

311

Prediction and diagnosis of bladder cancer recurrence based on urinary content of hTERT, SENP1, PPP1CA, and MCM5 transcripts  

UK PubMed Central (United Kingdom)

BackgroundIdentification of urinary biomarkers for detection of bladder cancer recurrence would be beneficial to minimize the frequency of cystoscopy. Our objective was to determine...Full Text Available

312

Partial purification and characterization of the multiple molecular forms of staphylococcal clotting activity (coagulase).  

UK PubMed Central (United Kingdom)

The clotting activity of Staphylococcus aureus strain 104 was purified 46,000-fold, but absolute purity was not achieved. Carbohydrate content of the purified material was not more than 5%. Elution...Full Text Available

1981-12-01

313

Paraquat-induced resinosis in Japanese pine. I. The effect of paraquat on Pinus densiflora and P. thunbergii  

Energy Technology Data Exchange (ETDEWEB)

Treatment of Japanese pines (P. densiflora and P. thunbergii) with paraquat induced a zone of lightwood. Determinations of turpentine and ether extractives contents in lightwoods showed high levels as compared with those in control woods. (Refs. 5).

1980-01-01

314

Parallel Loss of Plastid Introns and Their Maturase in the Genus Cuscuta  

UK PubMed Central (United Kingdom)

Plastid genome content and arrangement are highly conserved across most land plants and their closest relatives, streptophyte algae, with nearly all plastid introns having invaded the genome in their...Full Text Available

315

Oxidation of sialon ceramics with widely varying alumina content  

International Nuclear Information System (INIS)

Within the framework of a study on the chemical wear behaviour of sialon ceramics a range of compositions were prepared in which the alumina content was varied from 6 to 77 weight percent. The materials were hot-pressed from alumina and silicon nitride powders to a density of at least 97%. The structure and compositions of the phases occurring in these samples i.e. the O' phase, #beta#'-sialon solid solution and especially the X-phase were thoroughly characterized with respect to structure and composition using electron microprobe and transmission electron microscopy techniques. These results will be discussed in the light of earlier phase diagram studies. Some basic properties such as E-modulus and toughness were measured and related to microstructural features. E-modulus as well as toughness are at a minimum for materials with a high content of the X-phase. Oxidation of the materials was studied at 1300 deg C and 1450 deg C using weight gain ...

316

NHTSA Contact Information | National Highway Traffic Safety Administra...  

Science.gov (United States)

Skip to Main Content Skip to Main Navigation National Highway Traffic Safety Administration Accessible menu--Sitemap Driving Safety Aggressive Driving Bicycles Child Safety...

2011-09-24

317

Multiple mechanisms account for lower plasma iron in young copper deficient rats  

UK PubMed Central (United Kingdom)

Copper deficiency lowers brain copper and iron during development. The reduced iron content could be due to hypoferremia. Experiments were conducted to evaluate plasma iron and “ferroxidase”...Full Text Available

2008-06-01

318

Modeling of the relaxation kinetics of metastable tensile strained Si:C alloys  

Energy Technology Data Exchange (ETDEWEB)

In order to enhance the performance of CMOS transistors, embedded epitaxial layers of Si:C can be used. In the present work, Si:C layers with Carbon contents up to 1.9 at-% and in-situ Phosphorus doping up to 4 x 10{sup 20}At/cm{sup 3} have been investigated. Due to the low solubility of Carbon in Silicon (0.0004 at.-% at the melting point), all layers considered in this work are metastable and tend to relax. Since it is crucial to the application to retain the strain of those layers, the responsible mechanisms must be understood. The relaxation during thermal treatment was studied by high resolution X-ray diffraction and was found to behave differently, depending on Carbon content and Phosphorus doping concentration. In this work, we propose a relaxation mechanism based on a kick-out reaction of substitutional Carbon which is accelerated by Phosphorus content through transient enhanced diffusion. We simulate the time ...

2010-07-01

319

Mid-trimester diagnosis of bladder neck obstruction by ultrasound and paracentesis.  

UK PubMed Central (United Kingdom)

A bladder neck obstruction was suspected after ultrasound investigation at 16 weeks' gestation. Evaluation of protein content in the amniotic fluid, fetal ascites, and fluid from the overdistended bladder...Full Text Available

1983-06-01

320

Mapping neuropeptide expression by mass spectrometry in single dissected identified neurons from the dorsal ganglion of the nematode Ascaris suum  

UK PubMed Central (United Kingdom)

We have developed a method for dissecting single neurons from the nematode Ascaris suum, in order to determine their peptide content by mass spectrometry (MS). In this paper,...Full Text Available

2010-07-21

321

Localization and Toxic Effects of Cadmium, Copper, and Uranium in Azolla1  

UK PubMed Central (United Kingdom)

The storage and distribution of copper, cadmium, and uranium and their effects on ionic contents in roots and shoots of Azolla filiculoides has been studied by x-ray microanalysis....Full Text Available

1988-09-01

322

Introduction of a Secondary Blast Process into an Unlined Hot-Blast Cupola Furnace. Final Report.  

Science.gov (United States)

In a series of comprehensive tests lasting 18 months the relationship between the CO-content of the waste gas from a hot-blast cupola furnace and the amount of secondary blast was determined. The additional CO-combustion by means of the secondary blast an...

1986-01-01

323

Influence of potassium fluoride on the syntheses of methylpiperazine-modified poly(vinyl chloride)s for use as fixed-site proton carrier membranes.  

Science.gov (United States)

Aminated poly(vinyl chloride) (PVC) membranes were prepared that had a Nernstian response over a wide range of pH. The reaction between PVC and methyl-piperazine (MePIP) in dimethylformamide (DMF) was studied over a wide range of time and temperature, and in the presence of the catalyst, potassium fluoride (KF). Time, temperature, and KF increased the nitrogen (N) content of the resulting polymers, but sometimes at the expense of decreasing their specific viscosities (molecular weights). Activation energies of processes that occurred in different temperature ranges were estimated assuming an Arrhenius relationship. A Nernstian response occurred once the N content approached to about 0.3 w/w %, and was accelerated by the presence of KF at elevated temperatures. Increasing the N content above about 3% led to a loss of the Nernstian response either because of an increase in the double bond content and a ...

1998-03-15

324

Influence of Water Deficits on the Abscisic Acid and Indole-3-Acetic Acid Contents of Cotton Flower Buds and Flowers  

UK PubMed Central (United Kingdom)

A field experiment was conducted during the summer of 1988 to test the hypothesis that water deficit affects the abscisic acid (ABA) and indole acetic acid (IAA) concentrations in cotton (Gossypium...Full Text Available

1990-07-01

325

Impact of diffuse nitrate pollution sources on groundwater quality--some examples from Czechoslovakia.  

UK PubMed Central (United Kingdom)

In several regions of Czechoslovakia with intensive agricultural production, the correlation between the amount of nitrogen fertilizer applied and the nitrate content in groundwater has been recognized....Full Text Available

1989-11-01

326

Immunoreactive somatostatin and. beta. -endorphin content in the brain of mature rats after neonatal exposure to propylthiouacil. [Propylthiouracil  

Energy Technology Data Exchange (ETDEWEB)

The contents of immunoreactive somatostatin (IR-SRIF) and ..beta..-endorphin (IR-..beta..-EP) in 12 brain regions were examined in rats exposed neonatally to propylthiouracil (PTU) through the mother's milk. Since the dose of PTU used in this study is lower than the usual dose employed to induce hypothyroidism, a milder form of neonatal hypothyroidism resulted. This conclusion is supported by the only mild subnormal growth of rats to adulthood and serum T/sub 4/ and T/sub 3/ concentrations in the normal range. Adult rats treated with PTU neonatally had significantly higher IR-SRIF contents in several brain regions compared to controls, whereas IR-..beta..-EP levels were not significantly different in most regions. The results indicate that even mild hypothyroidism during early postnatal development causes permanent impairment of brain function, which manifests itself in part by an altered brain content of IR-SRIF.

1982-01-01

327

Highly Conserved Regimes of Neighbor-Base-Dependent Mutation Generated the Background Primary-Structural Heterogeneities along Vertebrate Chromosomes  

UK PubMed Central (United Kingdom)

The content of guanine+cytosine varies markedly along the chromosomes of homeotherms and great effort has been devoted to studying this heterogeneity and its biological implications. Already...Full Text Available

328

Graduate Quantum Mechanics Reform  

CERN Document Server

We address four main areas in which graduate quantum mechanics education in the U.S. can be improved: course content; textbook; teaching methods; and assessment tools. We report on a three year longitudinal study at the Colorado School of Mines using innovations in all four of these areas. In particular, we have modified the content of the course to reflect progress in the field in the last 50 years, use modern textbooks that include such content, incorporate a variety of teaching techniques based on physics education research, and used a variety of assessment tools to study the effectiveness of these reforms. We present a new assessment tool, the Graduate Quantum Mechanics Conceptual Survey, and further testing of a previously developed assessment tool, the Quantum Mechanics Conceptual Survey (QMCS). We find that graduate students respond well to research-based techniques that have previously been tested mainly in ...

2008-01-01

329

Glycolipids of human primary testicular germ cell tumours.  

UK PubMed Central (United Kingdom)

The glycolipid content of human non-seminomatous germ cell tumour cell lines correlates with their differentiation lineage. To analyse whether this reflects the situation in primary tumours, we studied...Full Text Available

1996-07-01

330

Genomic Content of Bordetella pertussis Clinical Isolates Circulating in Areas of Intensive Children Vaccination  

UK PubMed Central (United Kingdom)

BackgroundThe objective of the study was to analyse the evolution of Bordetella pertussis population and the influence of herd immunity in different areas of the...Full Text Available

331

Gasmap 2006. Bringing Norwegian gas to Europe; En publikasjon om norsk gass og gasseksport  

Energy Technology Data Exchange (ETDEWEB)

A publication on Norwegian gas and gas export. The content is wide spread from use of gas in daily life via sub sea pipeline repair systems to an overview over tomorrows gas fields. (AG)

2006-06-15

332

Formulation and make-up of simulate dilute water, low ionic content aqueous solution  

Energy Technology Data Exchange (ETDEWEB)

This procedure describes the formulation and make-up of Simulated Dilute Water (SOW), a low-ionic-content water to be used for Activity E-20-50, Long-Term Corrosion Studies. This water has an ionic content which is nominally a factor of ten higher than that of representative waters at or near Yucca Mountain. Representative waters were chosen as J-13 well water [Harrar, 1990] and perched water at Yucca Mountain [Glassley, 1996]. J-13 well water is obtained from ground water that is in contact with the Topopah Spring tuff, which is the repository horizon rock. The perched water is located in the Topopah Spring tuff, but below the repository horizon and above the water table. A nominal times ten higher ionic content was chosen to simulate the effect of ionic concentrating due to elevated temperature water flowing through fractures where salts and minerals have been deposited due to evaporation and boiling.

1997-04-04

333

Evaluating the Nickel Content in Metal Alloys and the Threshold for Nickel-Induced Allergic Contact Dermatitis  

UK PubMed Central (United Kingdom)

Many patients are currently suffering from nickel (Ni)-induced allergic contact dermatitis (ACD). There have been few Korean studies dealing with the threshold of Ni-induced ACD and quantifying the...Full Text Available

2008-04-01

334

Erythrocyte Membrane Fatty Acid Content in Infants Consuming Formulas Supplemented with Docosahexaenoic Acid (DHA) and Arachidonic Acid (ARA): an Observational Study  

UK PubMed Central (United Kingdom)

In this observational study, we compared erythrocyte membrane fatty acids in infants consuming formula supplemented with docosahexaenoic acid (DHA) and arachidonic acid (ARA) with those consuming...Full Text Available

2010-10-01

335

Environmental effects and energy efficiency in building design: A green building approach. Part 1, energy efficiency techniques. Research report  

Energy Technology Data Exchange (ETDEWEB)

;Contents: Energy Use; Building Fabric Performance; Ventilation and Infiltration; Passive Solar Design; Heating Systems and Controls; Hot and Cold Water Provision; and Lighting and Electrical Appliances.

1993-01-01

336

Environmental assessment of the Alaskan continental shelf. Final reports of principal investigators, Volume 15. Biological studies  

Energy Technology Data Exchange (ETDEWEB)

The contents of the report include: Identification, documentation and delineation of coastal migratory bird habitat; and an annotated bibliography of literature on Alaska Water Birds.

1981-12-01

337

Environmental Effects and Energy Efficiency in Building Design: A Green Building Approach. Part 3. Design Case Studies.  

Science.gov (United States)

Contents: Introduction; Design Criteria for a Green Building; Comparison of Energy Efficiency Measures; Whole House Energy Efficiency; Built Examples of Energy Efficient Houses; and Product Energy of Building Elements.

1993-01-01

338

Environmental Effects and Energy Efficiency in Building Design: A Green Building Approach. Part 1, Energy Efficiency Techniques.  

Science.gov (United States)

Contents: Energy Use; Building Fabric Performance; Ventilation and Infiltration; Passive Solar Design; Heating Systems and Controls; Hot and Cold Water Provision; and Lighting and Electrical Appliances.

1993-01-01

339

Endometriosis: MedlinePlus tutorial interactivo del Instituto...  

Science.gov (United States)

Compartir Skip to Content Endometriosis Empezar Programa Interactivo de X-Plain Empezar Programa Interactivo de X-Plain Empezar el Programa de X-Plain Auto-operado Empezar el...

2011-04-27

340

Elsevier  

Wastenet

...comply with funding body archiving policies, including the policies put in place by the National Institutes of Health, The Wellcome Trust and the Howard Hughes Medical Institute . Delayed Access Select journals provide content to some or all of a journalrsquo;s backfile. For example, articles in ...

341

Effects of moisture content on bending properties and creep behavior of phenolic-resin-treated particleboards; Fenoru jushi ganshin shori particleboard no seiteki mage oyobi mage creep seino ni oyobosu gansuiritsu no eikyo  

Energy Technology Data Exchange (ETDEWEB)

The effects of the rate of resin addition and moisture content (MC) on the static bending properties and creep behavior of phenol-resin-treated particleboards are investigated. The modulus of rupture (MOR) of phenol-resin-treated boards shows the maximum value at 7 to 9 percent MC and large decreases at 19 to 28 percent MC, retaining values about 30 to 40 percent lower than those in the oven dry condition. The bending property is improved with the increase of low molecular weight resin content, and the tendency is obvious when MC is high. Creep compliance tends to increase with the increase of MC, and the rate of increase is larger with smaller resin content. The value of creep compliance after 48 hours under load becomes about 1.8 times the value in the dry condition at 7 to 9 percent MC, and about 2 times the value when MC increases to 19 to 27 percent from 7 to 9 percent. In addition, the orientation of particleboard has ...

1998-04-15

342

Effects of Sildenafil and Tadalafil on Intraocular Pressure in Sheep: Implications for Aqueous Humor Dynamics  

UK PubMed Central (United Kingdom)

Purpose.To determine the effects of vasodilators on intraocular pressure (IOP) and the protein content of sheep aqueous humor (AH), because the vasodilators may increase fluid leakage...Full Text Available

2010-06-01

343

Effect of NAD+ on Malate Oxidation in Intact Plant Mitochondria 1  

UK PubMed Central (United Kingdom)

Potato tuber mitochondria oxidizing malate respond to NAD+ addition with increased oxidation rates, whereas mung bean hypocotyl mitochondria do not. This is traced to a low endogenous content...Full Text Available

1980-08-01

344

Durability of stabilized flue gas desulfurization sludge.  

Science.gov (United States)

The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and...

1995-01-01

345

Detection of TP53 mutation, loss of heterozygosity and DNA content in fine-needle aspirates of breast carcinoma.  

UK PubMed Central (United Kingdom)

Recent preclinical and clinical data suggest that TP53 status and TP53 mutations may be important in determining tumour aggressiveness and therapy response. In this study we investigate the feasibility...Full Text Available

1998-01-01

346

Detection of Atopobium vaginae in Postmenopausal Women by Cultivation-Independent Methods Warrants Further Investigation  

UK PubMed Central (United Kingdom)

We sequenced 16S rRNA genes from the vaginal swab contents of a postmenopausal woman with asymptomatic bacterial vaginosis (BV). Sequences from Atopobium vaginae were the most commonly...Full Text Available

2004-04-01

347

Content validity of manual spinal palpatory exams - A systematic review  

UK PubMed Central (United Kingdom)

BackgroundMany health care professionals use spinal palpatory exams as a primary and well-accepted part of the evaluation of spinal pathology. However, few studies have explored...Full Text Available

348

Complete plastid genome sequences suggest strong selection for retention of photosynthetic genes in the parasitic plant genus Cuscuta  

UK PubMed Central (United Kingdom)

BackgroundPlastid genome content and protein sequence are highly conserved across land plants and their closest algal relatives. Parasitic plants, which obtain some or all of their...Full Text Available

349

Comparison of Disulfide Contents and Solubility at Alkaline pH of Insecticidal and Noninsecticidal Bacillus thuringiensis Protein Crystals  

UK PubMed Central (United Kingdom)

We compared two insecticidal and eight noninsecticidal soil isolates of Bacillus thuringiensis with regard to the solubility of their proteinaceous crystals at alkaline pH values. The...Full Text Available

1994-10-01

350

Coal reactor conservation of blast furnace coke  

Science.gov (United States)

Coke consumption may be cut as much as fifty percent using a coal reactor to furnish carbon monoxide for ore reduction in a blast furnace while lowering the sulfur content of pig iron accompanied by a smaller slag volume.

1982-02-23

351

Characterization of the 5'-terminal cap structures of early simian virus 40 mRNA.  

UK PubMed Central (United Kingdom)

Early simian virus 40-specific mRNA was isolated from lytically infected and stably transformed cells and analyzed with respect to the 5'-terminal cap content. An analogous diversity of capped structures...Full Text Available

1980-09-01

352

Characterization of interactions of coal surface with solvent by flow microcalorimetric measurement. 3; Netsuryo sokutei ni yoru sekitan hyomen to yozai tono sogo sayo no hyoka. 3  

Energy Technology Data Exchange (ETDEWEB)

An investigation was given on the relationship between methanol adsorbing behavior of reformed coal surface and oxygen containing functional groups in coal. Akabira bituminous coal was air-oxidized or Yallourn brown coal was decarbonated in oil as a reformation treatment. Both of the treated and untreated coals showed an adsorption heat curve of the Langmuir type. The Akabira coal had its oxygen content and the adsorption heat increased as a result of the air oxidizing reformation treatment. The Yallourn coal had its oxygen content and adsorption heat decreased as a result decarbonation reformation treatment. Oxygen containing functional groups act as strong adsorption sites for methanol, and the maximum adsorption amount depends on oxygen content in the coals. Since the coal surface is non-uniform in terms of energy, methanol is adsorbed first into sites with higher molar adsorption heat, and then into lower sites ...

1996-10-28

353

Changes in contents of somatostatin in hypophysis and arginine vasopressin in hypothalamus of postnatal developing brain induced by low level prenatal #beta#-irradiation of tritiated water in mice  

International Nuclear Information System (INIS)

Changes in contents of the two kinds of neuropeptides have been measured in the brains of postnatal G57BL/6J strain mice that received accumulative doses of 0, 0.05, 0.10 or 0.30 Gy respectively in utero from tritium #beta#-irradiation during the mother mice's pregnancy from the 12.5th day of gestation to the day of delivery. Dose response relationship for alteration in somatostatin content due to exposure to 0.10 Gy or above was observed, and it was also noted that 0.30 Gy could cause decrease in arginine vasopressin in hypothalamus. These results were consistent with findings in research on brain development and reflex behavior in the literature. 0.10 Gy exposure may represent a threshold for exposure to tritiated water within the range from day 12.5 of gestation to the day of delivery using change in content of somatostatin in hypophysis as a parameter.

354

Chalk Point Cooling Tower Project: Drift Salinity Experiments.  

Science.gov (United States)

Results of feasibility experiments for determining the mineral content of individual stains on special Sensitized Paper are presented. The stains were formed on the paper by the impaction of laboratory generated salt water droplets. Of the techniques exam...

1979-01-01

355

Cerebrospinal Fluid Steroidomics: Are Bioactive Bile Acids Present in Brain?*  

UK PubMed Central (United Kingdom)

In this study we have profiled the free sterol content of cerebrospinal fluid by a combination of charge tagging and liquid chromatography-tandem mass spectrometry. Surprisingly, the most abundant cholesterol...Full Text Available

2010-02-12

356

Cellulase-Xylanase Synergy in Designer Cellulosomes for Enhanced Degradation of a Complex Cellulosic Substrate  

UK PubMed Central (United Kingdom)

Designer cellulosomes are precision-engineered multienzyme complexes in which the molecular architecture and enzyme content are exquisitely controlled. This system was used to examine enzyme cooperation...Full Text Available

357

Calorimetric studies of the kinetic unfreezing of molecular motions in hydrated lysozyme, hemoglobin, and myoglobin.  

UK PubMed Central (United Kingdom)

Differential scanning calorimetric (DSC) studies of the glassy states of as-received and hydrated lysozyme, hemoglobin, and myoglobin powders, with water contents of < or = 0.25, < or...Full Text Available

1994-01-01

358

Buoyant Densities and Dry-Matter Contents of Microorganisms: Conversion of a Measured Biovolume into Biomass  

UK PubMed Central (United Kingdom)

Several isolates of bacteria and fungi from soil, together with cells released directly from soil, were studied with respect to buoyant density and dry weight. The specific volume (cubic centimeters...Full Text Available

1983-04-01

359

Association of mineral composition of neonatal intravenous feeding solutions and metabolic bone disease of prematurity.  

UK PubMed Central (United Kingdom)

To assess the effects of increasing the mineral content of parenteral nutrition solutions on the biochemical and radiological indicators of metabolic bone disease of prematurity 27 neonates who required...Full Text Available

1989-04-01

360

Assay of the uranium and plutonium content in process residues and wastes using the correction for sample self attenuation in segmented gamma scanning system  

International Nuclear Information System (INIS)

A method of the correction for sample self attenuation used in segmented gamma scanner (SGS) is described. The method of calibration for assaying the uranium and plutonium contents of each category of heterogeneous process residues and wastes in nuclear facilities is studied. The effect of variable measurement parameter on measurement results is also studied. The measurement results of SGS assay is compared with that of the destructive assay (DA), which is aimed at evaluating SGS method for assaying uranium and plutonium content in process residues and wastes. The deviation of two assay results is 3.6%. The SGS assay results and DA assay results both are coincided well in error limits. Four category of heterogeneous process residues and wastes in nuclear facilities have assayed successfully in physical inventory. The uncertainty of measurement results for uranium and plutonium content in process residues and wastes is 5% ...

1998-09-01

361

Agmatine attenuates brain edema through reducing the expression of aquaporin-1 after cerebral ischemia  

UK PubMed Central (United Kingdom)

Brain edema is frequently shown after cerebral ischemia. It is an expansion of brain volume because of increasing water content in brain. It causes to increase mortality after stroke. Agmatine, formed...Full Text Available

2010-05-01

362

A new method to measure necrotic core and calcium content in coronary plaques using intravascular ultrasound radiofrequency-based analysis  

UK PubMed Central (United Kingdom)

Although previous intravascular ultrasound (IVUS) radiofrequency-based analysis data showed acceptable reproducibility for plaque composition, measurements are not easily obtained, particularly that...Full Text Available

2010-04-01

363

A late presenting congenital diaphragmatic hernia misdiagnosed as spontaneous pneumothorax  

UK PubMed Central (United Kingdom)

Congenital diaphragmatic hernia (CDH) is described as (1) failure of diaphragmatic closure at development, (2) presence of herniated abdominal contents into chest and (3) pulmonary hypoplasia. Usually,...Full Text Available

2010-09-01

364

A comparative analysis of phenylpropanoid metabolism, N utilization, and carbon partitioning in fast- and slow-growing Populus hybrid clones  

UK PubMed Central (United Kingdom)

The biosynthetic costs of phenylpropanoid-derived condensed tannins (CTs) and phenolic glycosides (PGs) are substantial. However, despite reports of negative correlations between leaf phenolic content...Full Text Available

2009-08-01

365

45 CFR 170.205 - Content exchange standards and implementation specifications for exchanging electronic health...  

Science.gov (United States)

...standards and implementation specifications for exchanging electronic health information. 170.205 Section 170.205 Public Welfare DEPARTMENT OF HEALTH AND HUMAN SERVICES HEALTH INFORMATION TECHNOLOGY HEALTH INFORMATION TECHNOLOGY...

2010-10-01

366

40 CFR 52.515 - Original identification of plan section.  

Science.gov (United States)

...Amendments to Sections 8-2:704 (Use of Certain Fuel Oils Forbidden), 8-2:705 (Use of Certain Coal Forbidden...and Nitrogen Oxides. Section 801(Sulfur Content of Fuel Oils), subsection 801.1 Section 802(Sulfur...

2009-07-01

367

Zinc determination in medicinal powders by radionuclide X-ray fluorescence analysis  

International Nuclear Information System (INIS)

X-ray fluorescence analysis was used to determine the zinc content of the ''Perilacin'' powder and the ZnO content of the ''Epiderman-pix'' powder. The characteristic Ksub(#alpha#) line of zinc was excited using a "1"4"7Pm/Mo source (10"7 s"-"1) and the molybdenum Ksub(#alpha#) line (17.47 keV). 4 to 5% Zn and 45 to 49% ZnO were determined with a NaI(Tl) scintillation detector. The radiation intensity was found to decrease with particle size. (M.K.).

1977-01-01

368

Water resources data for Oklahoma, water year 1992. Volume 2. Red River Basin. Water-data report (Annual), 1 October 1991-30 September 1992  

Energy Technology Data Exchange (ETDEWEB)

Volume 2 of the water resources data for the 1992 water year for Oklahoma consists of record of stage, discharge, and water quality of streams; stage, contents, and water quality of lakes or reservoirs; and water levels of ground-water well. The report contains discharge records for 136 gaging stations; stage and contents for 31 lakes or reservoirs; water quality for 50 gaging stations. Also included are 61 partial-record or miscellaneous streamflow stations and 28 ground-water sites.

1993-04-01

369

Total mercury and its distribution in blue crab and deep water pink shrimp from Alexandria coast.  

Science.gov (United States)

Total mercury content and its distribution in muscles and viscera of male and female blue crab (Callinectes sapidus Rothbum) and deep water pink shrimp (Parapenacus longirostris) collected from the 3 main fishing grounds near the Alexandria coast in the Mediterranean sea was estimated. The results indicate that the mercury content in the muscles of both species differ according to fishing areas, size, sex, and species. More than 75% of total mercury were accumulated in the viscera of both species which indicates that the mercury entered in these organisms via the feed chain. PMID:3696196

1987-01-01

370

Stress corrosion cracking and pitting corrosion relation for zircaloy-4 in chloride-containing hydro-alcoholic media  

International Nuclear Information System (INIS)

A study of stress corrosion cracking susceptibility of Zircaloy-4 in chloride-containing aqueous methanolic media is presented. The influence of water content is investigated in the 5-100 vol. % water range. The dependence of stress corrosion cracking on potential is evidenced. A close correlation is established with pitting susceptibility determined by a statistical analysis of induction times. A correlation with the repassivation potential is observed in the water-rich solutions. In the low water content solutions, two repassivation curves are determined according to the experimental technique. Pit morphology and fractography show a transition from aqueous to organic media. (author).

371

Statistical comparison of the effect of relative and absolute humidity on fixed-bed carbon adsorption capacity. Report for January 1987-July 1988  

Energy Technology Data Exchange (ETDEWEB)

This paper describes statistical methods used to evaluate data for toluene (at several typical operating temperatures and humidity levels) and to determine which measure of humidity (relative or absolute) is more important in determining carbon adsorption efficiency. The water content of a solvent-laden stream is critical for its control via carbon adsorption, especially at relative humidities about 50-70%. (Relative humidity is the percent of saturation: absolute humidity is the total water content.)

1989-01-01

372

Reducing Losses of Nitrogen from Duff Consumption by Prescribed Fire in Douglas-Fir/Western Hemlock Clearcuts : Final Report.  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study was to determine if nitrogen loss from prescribed fire can be mitigated by reducing the amount of large fuel on a clearcut prior to burning. We examine the relations between nitrogen loss and duff consumption by prescribed fire with respect to the amount of woody biomass on the unit and the moisture content of that biomass before burn. Equations are presented to predict duff consumption from preburn conditions. Sources of variability of nitrogen concentration and content of duff within and between units are also evaluated.

1985-06-28

373

Process for reducing the water content of coal containing bound water  

Energy Technology Data Exchange (ETDEWEB)

An improved process is disclosed for reducing the water content of coal containing bound water by releasing at least a portion of the bound water by maintaining the coal at a temperature from about 220/sup 0/ to about 500/sup 0/ F. in the presence of water at a pressure sufficient to maintain at least portion of the water in a liquid phase for a time sufficient to release at least a portion of the bound water wherein the improvement comprises contacting the coal during such treatment with an active material selected from the group consisting of carboxylic organic acids containing up to about 6 carbon atoms, phenol, phenolic acids and inorganic acids.

1983-08-23

374

On the problem of blast furnace coke quality  

Science.gov (United States)

The introduction of large blast furnaces, oxygen-enriched blast and natural gas firing means that the coke rate is determined mainly by the ability of the coke charge to loosen up the burden and ensure a high level of permeability. Coke strength is now of great importance to the steelmaker, alongside ash and sulphur contents. The article suggests that moisture still offers a useful negotiating base for furnace operators and suppliers. It is important to know the moisture content and a sampling procedure is recommended for determining the moisture desorption time. Such tests also indicate any relationship between different quenching plants and the product.

1982-10-01

375

Neutron activation analysis of trace elements in Japanese hormesis cosmetics  

International Nuclear Information System (INIS)

In Japan, cosmetics claiming hormesis effect are available through Internet. Although these cosmetics show the contents, they never mention the minor elements and radioactive sources. The existence of radioisotopes, however, was observed by measurements of the gamma-rays with a HPGe detector. In this study, in order to clarify the contents of trace elements, the hormesis cosmetics including radioactive sources were analyzed using INAA, PGAA and NAA with multiple gamma-ray detection (NAAMG). Nineteen elements were analyzed quantitatively in hormesis cosmetics by INAA, PGAA and NAAMG and 16 elements were detected qualitatively by SEM-EPMA. (author)

2008-12-01

376

Multielement XRF-analysis of blood from patients with dilated cardiomyopathy  

International Nuclear Information System (INIS)

Radionuclide x-ray fluorescence analysis was used for the determination of Fe, Zn, Br and Rb levels in whole blood from dilated cardiomyopathy patients and from a control group. The XRF-system consisted of a radionuclide source "1"0"9Cd, a semiconductor Si/Li detector connected to a multichannel analyzer. Fe content in blood of patients was significantly lower than that of the control. Zn content showed no deviation from normal range. Values for Br and Rb in patients highly exceed the range reported for them. (author) 4 tabs.; 9 refs.

1991-03-01

377

Enriched lithium collection from lithium plasma flow  

International Nuclear Information System (INIS)

In order to understand the physical processes concerned with the selective heating by ion cyclotron resonance and with the subsequent collection of heated particles, experiments were carried out with the extraction of lithium samples, enriched with "6Li isotopes. Probe and integral extractors allow to collect enriched Li at the end of the selective heating region. Surface density distribution on the collector and local isotopic content of lithium are measured, as a function of the screen height and the retarding potential. Dependence of the collected amount of lithium and of its isotopic content on the value of the magnetic field is also measured. 4 figs., 2 tabs., 5 refs.

378

Effect of the quality of the iron-ore-bearing raw materials and coke on the performance indices of blast furnaces at the Novolipetsk metallurgical combine  

British Library Electronic Table of Contents (United Kingdom)

Results are presented from an evaluation of the effect of the quality of the iron-ore-bearing raw materials and coke on the performance of blast furnaces at the Novolipetsk Metallurgical Combine. It is shown that the technical-economic indices of the smelting operation are improved by increasing the pellet content of the charge, the basicity of the sinter, and the sinter?s content of the ?5 mm fraction. An analysis of the performance of the blast furnaces on coke with a hot-strength index CSR = 40?60% confirmed the qualitative and quantitative effect of this index on furnace productivity and coke consumption. The analysis also showed that the magnitude of this effect depends on smelting rate and the basicity of the furnace slag.

2010-01-01

379

Determination of Mn, Fe, Cu, Zn, and Pb in particulate matter, raw and final materials of a brick factory by radionuclide X-ray fluorescence analysis  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence method with a Si/Li semiconductor detector and "2"3"8Pu exciting source was used in the study of Mn, Fe, Cu, Zn, and Pb content of solid emissions, raw and final materials of a brick factory. From the point of view of metal content, the working environment if the brick factory is safe for workers. (author) 2 refs.; 2 figs.; 1 tab.

1994-01-01

380

Comparison of temperature and humidity profiles with elastic-backscatter lidar data  

Energy Technology Data Exchange (ETDEWEB)

This contribution analyzes elastic-backscatter lidar data and temperature and humidity profiles from radiosondes acquired in Barcelona in July 1992. Elastic-backscatter lidar data reveal the distribution of aerosols within the volume of atmosphere scanned. By comparing this information with temperature and humidity profiles of the atmosphere at a similar time, we are able to asses de relationship among aerosol distribution and atmospheric stability or water content, respectively. Comparisons have shown how lidar`s revealed layers of aerosols correspond to atmospheric layers with different stability condition and water content.

1995-04-01

381

Application of radionuclide X-ray fluorescence analysis in determining lanthanum content in tungsten and in iron by internal standard technique  

Energy Technology Data Exchange (ETDEWEB)

The use of the method is described on powder samples before and after sintering with a La content of up to 1%. For excitation of the K series of La a /sup 241/Am source with an activity of 1.11 GBq was used. The obtained results showed that the method is sufficiently accurate (error 7%) at a short period of measurement (100 s). It gives satisfactory results even in the comparison of the experimental relative count rate and the theoretically calculated value despite the fact that the analytical signal comes from the sample surface.

1983-05-01

382

Application of radionuclide X-ray fluorescence analysis in determining lanthanum content in tungsten and in iron by internal standard technique  

International Nuclear Information System (INIS)

The use of the method is described on powder samples before and after sintering with an La content of up to 1%. For excitation of the K series of La a _2_4_1Am source with an activity of 1.11 GBq was used. The obtained results showed that the method is sufficiently accurate (error 7%) at a short period of measurement (100 s). It gives satisfactory results even in the comparison of the experimental relative count rate and the theoretically calculated value despite the fact that the analytical signal comes from the sample surface. (Ha).

1983-01-01

383

Active dissolution of nickel based alloys in thiosulphate solution  

International Nuclear Information System (INIS)

Repassivation resulting from the bared metal surface is a critical process for judging whether or not material suffers from corroding or immunizing. Nickel based alloys with high chromium content were developed to increase the corrosion resistant to sulphur compounds. Active humps resulting from active dissolution of nickel were obtained by creating the bared metal surfaces in thiosulphate solutions. The lower the Cr content the higher is the dissolution rate. The passive films formed on the bared metal surface were examined by ac impedance. Results suggest the formation of multi-layers oxide which were affected by active dissolution reactions during repassivation. (author).

1989-10-01

384

Co-combustion of recycled waste materials with peat and coal in a 15 kw fluidized bed reactor  

Energy Technology Data Exchange (ETDEWEB)

Co-combustion tests for recycled fuels and peat were made at a 15 kW fluidized bed reactor at VTT Energy in Jyvaeskylae. Peat was used as reference fuel. 25 tests in total were performed during 1994 - 1996. A part of the peat energy was substituted by coal in five tests, in order to change the sulphur/chlorine ratio of the fuel mixture. Fuel mixtures (25% recycled fuel and 75% peat, at energy ratio) were pelletized in order to get homogeneous fuel mixtures. The tests in the year 1994 were air staging experiments (with and without tertiary air). All test were performed with air staging in the years 1995 and 1996. The aim of the research was to determine whether the co-combustion of waste materials will cause additional emission problems, as compared to combustible emissions from conventional air-staged fluidized bed combustion. Further, the aim was to study which large-volume components can be burned safely. One aim was to study the influence of fuel properties and combustion conditions ...

1998-12-31

385

Investigating of composition, structure and properties of Si modification under variable dose ions implantation influence  

International Nuclear Information System (INIS)

Interest to thin film of metals' silicides first of all is conditioned intrinsic al them unique physical properties. On their basis of it is possible to produce extremely sophisticated devices of solid-state electronics, production which needs the controlled change of physics, chemical and electrical properties with high-level of accuracy. On the present time most are in detail investigated composition, structure and properties of three-dimensional samples of metals' silicides. In the last years the intensive are led to researches in the direction of creation and study of physical-chemical properties thin (500-1000 Angstroms) and ultrafine (100-120 Angstroms) films silicides. It has information about composition, morphology of surface and emission of properties of thin film of silicides of barium, of cobalt and of palladium, was obtained in conditions of ultra-high vacuum. Low energy ion implantation and further annealing on composition, electronic and crystalline ...

386

In-situ growth of porous alumino-silicates and fabrication of nano-porous membranes  

Science.gov (United States)

Feasibility of depositing continuous films of nano-porous alumino-silicates, primarily zeolites and MCM-41, on metallic and non-metallic substrates was examined with an aim to develop membranes for separation of gaseous mixtures and also for application as hydrogen storage material. Mesoporous silica was deposited in-side the pores of these nano-porous disks with an aim to develop membranes for selective separations. Our study involves supported zeolite film growth on substrates using in-situ hydrothermal synthesis. Faujasite, Silicalite and Mesoporous silica have been grown on various metallic and non-metallic supports. Metallic substrates used for film growth included anodized titanium, sodium hydroxide treated Titanium, Anodized aluminum, and sintered copper. A non-metallic substrate used was nano-porous aluminum oxide. Zeolite film growth was characterized using Scanning Electron Microscope (AMRAY 1820) and High Resolution Transmission electron microscope. Silicalite was found to ...

2009-01-01

387

Heterodifunctional ligands derived from monooxidized Bis(phosphino)amines. Synthesis and transition metal (Molybdenum(0), Tungsten(0), Rhodium(I), Palladium(II), and Platinum(II)) complexes of (Diphenylphosphino)(diphenylphosphinothioyl)- and (Diphenylphosphino) (diphenylphosphinoselenoyl)phenylamine, Ph[sub 2]PN(Ph)P(E)PH[sub 2] (E = S, Se). Crystal and molecular structure of the Pt(II) Complex [Cl[sub 2]P[ovr tPPh[sub 2]N(Ph)P(S)]Ph[sub 2  

Energy Technology Data Exchange (ETDEWEB)

Bis(diphenylphosphino)phenylamine can be selectivity oxidized by S or Se in toluene or hexane solvents to the monooxidized thioyl or selenoyl products Ph[sub 2]PN(PH)PPh[sub 2]=E, (E = S, Se). These compounds act as bidentate chelate ligands toward metal complexes forming (CO)[sub 4]M(LL) (M = Mo, W), CO(Cl)Rh(LL), and Cl[sub 2]M(LL), (M = Pt, Pd) where (LL) is the thioyl or selenoyl derivative of the aminobis(phosphine). IR and NMR data are given for all complexes. The carbonyl infrared stretching frequencies show that the chelates form with the phosphine cis to any CO which is present. The [sup 31]P NMR of all complexes of two doublets except for the Rh complexes wherein the Rh spin also couples to phosphorous to produce two doublets of doublets. The [sup 2]J[sub PP] values range from 56 to 112 Hz. [sup 1]J[sub PSe] coupling provide valuable assistance for the assignment of the phosphorus resonances which range widely from 55 to 126 ppm for P[sup III] and from 60 to 80 ppm for the ...

1993-12-08

388

The Effect of Static Magnetic Forces on Water Contents and Photosynthetic Pigments in Sweet Basil Ocimum basilicum L. (Lamiaceae)  

International Nuclear Information System (INIS)

Three different magnetic regimes; aerial, surface and buried; each with three different forces, have been used to investigate their effects on the water contents and photosynthetic pigments of sweet basil plants (Ocimum basilicum L.). Two groups of sweet basil seeds, Ocimum basilicum L. have been cultivated, one under normal conditions and the second has been subdivided into three portion (aerial, surface and buried) to examine the effect of different magnetic forces coming from the three directions on the resulted plants. At all directions of magnets, water contents have been significantly affected by the magnetic forces. Chlorophyll A and carotene contents have been affected, as well, according to the three magnetic forces coming from soil surface regime only. Chlorophyll B did not significantly affected by differences magnetic forces in the three regimes, but it is affected by magnetism wherever its direction or force. ...

389

Novel injectable and in situ curable glycolide/lactide based biodegradable polymer resins and composites.  

Science.gov (United States)

Novel in situ polymerizable liquid three-arm biodegradable oligomeric polyesters based upon glycolic acid (GA), L-lactic acid (LLA), and their copolymers are synthesized and characterized. Injectable and in situ curable polymer neat resins and their composites formulated with bioabsorbable beta-tricalcium phosphate are prepared at room temperature using photo- and redox-initiation systems, respectively. The cured neat resins show the initial compressive yield strength (YCS, MPa), modulus (M, MPa), ultimate compressive strength (UCS, MPa), and toughness (T, kN mm), ranging from 4.0 to 20.1, 201.5 to 730.2, 82.7 to 310.5, and 1.02 to 3.93. The cured composites show the initial YCS, M, UCS and T, ranging from 27.7 to 56.4, 1440 to 4870, 81.6 to 158.9, and 0.94 to 1.97. Increasing GA/LLA ratio increases all the initial compressive strengths of both neat resins and composites. Increasing filler content increases YCS and M but decreases UCS and T. A diametral tensile ...

2006-08-18

390

Mineralogy and geochemistry of the No. 6 Coal (Pennsylvanian) in the Junger Coalfield, Ordos Basin, China  

Energy Technology Data Exchange (ETDEWEB)

This paper discusses the mineralogy and geochemistry of the No. 6 Coal (Pennsylvanian) in the Junger Coalfield, Ordos Basin, China. The results show that the vitrinite reflectance (0.58%) is lowest and the proportions of inertinite and liptinite (37.4% and 7.1%, respectively) in the No. 6 Coal of the Junger Coalfield are highest among all of the Late Paleozoic coals in the Ordos Basin. The No. 6 Coal may be divided vertically into four sections based on their mineral compositions and elemental concentrations. A high boehmite content (mean 6.1%) was identified in the No. 6 Coal. The minerals associated with the boehmite in the coal include goyazite, rutile, zircon, and Pb-bearing minerals (galena, clausthalite, and selenio-galena). The boehmite is derived from weathered and oxidized bauxite in the weathered crust of the underlying Benxi Formation (Pennsylvanian). A high Pb-bearing mineral content of samples ZG6-2 and ZG6-3 is likely of ...

2006-04-03

391

Lesion localization in patients with hyperparathyroidism using double-phase Tc-99m MIBI parathyroid scintigraphy  

International Nuclear Information System (INIS)

This study was performed to evaluate the diagnostic usefulness of double-phase Tc-99m MIBI parathyroid scintigraphy with single photon emission computed tomography (SPECT) in patients with hyperparathyroidism. We also evaluated the relationship between Tc-99m MIBI uptake and oxyphil cell contents in parathyroid glands. The subjects were 28 parathyroid glands of 10 patients who underwent Tc-99m MIBI parathyroid scintigraphy and parathyroidectomy for clinically suspected hyperparathyroidism. Early and delayed pinhole images were obtained at 15 minutes and 2 hours after injection of Tc-99m MIBI, and SPECT images were followed. The weight and oxyphil cell contents of parathyroid tissue were obtained from pathologic specimen, and the scintigraphic findings were compared with histopathology. In surgical histopathology, 6 parathyroid adenomas and 9 parathyroid hyperplasias were confirmed. The sensitivity, specificity, and positive predictive value of ...

1999-02-01

392

Element distribution in the brain sections of rats measured by synchrotron radiation X-ray fluorescence  

International Nuclear Information System (INIS)

The concentration of trace elements in brain sections was measured by synchrotron radiation X-ray fluorescence. The relative concentration was calculated by means of the normalization of Compton scattering intensity approximately 22 keV, after the normalization for collecting time of X-ray spectrum and the counting of the ion chamber, and subtracting the contribution of the polycarbonate film for supporting sample. Furthermore, the statistical evaluation of the element distribution in various regions of the brain sections of the 20-day-old rats was tested. For investigating the distribution of elements in the brain of iodine deficient rats, Wistar rats were fed with iodine deficient diet and deionized water (ID group). The rats were fed the same iodine deficient diet, but drank KIO_3 solution as control (CT group). The results showed that the contents of calcium (Ca) in thalamus (TH) and copper (Cu) and iron (Fe) in cerebral cortex (CX) of ID rats were ...

2004-02-27

393

Effects of matrix resin and fiber content on behavior of fatigue crack propagation in continuous-fiber-mat reinforced CP-resin composites; Renzoku sen`i mat kyoka CP resin fukugozai no hiro kiretsu denpa tokusei ni oyobosu bozai oyobi sen`i gan`yuritsu no eikyo  

Energy Technology Data Exchange (ETDEWEB)

The purpose of the present work is to investigate the effects of matrix resin and fiber content on the behavior of fatigue crack propagation in continuous-glass-fiber-mat reinforced CP-resin composites. For this purpose, ductile matrix resin and brittle one are used. These two kinds of resins have the characteristic that the elastic modulus and tensile strength are nearly the same with each other while the elongation is different. The composite specimens are made of these resins and continuous grass fiber mat of 20 wt.% and 60 wt% fiber contents. The fatigue crack propagation test was conducted by using the tapered DCB specimens to control the stress intensity factor range, {delta}K, during the test. The results obtained are as follows; (1) The relation between the crack propagation rate, da/dN, and {delta}K for all the present materials is shown by a straight line in logarithmic representation. (2) For the composites of 20 wt.% fiber ...

1996-05-15

394

Effects of composition, heat treatment and cold work on structure and properties of alloy 800  

Energy Technology Data Exchange (ETDEWEB)

The creep characteristics of alloy 800 at temperatures around 600/sup 0/C are greatly affected by the composition and treatments in the final stages of manufacture. Short-term and creep properties of alloy 800 at 600/sup 0/C are described for six melts covering the carbon range 0.054-0.078%, the titanium range 0.23-0.57% and the aluminium range 0.17-0.52%. The properties are related to the alloy chemistry and the microstructure. It is shown that homogeneously nucleated ..gamma..'-precipitates are the main cause of low ductility in alloy 800 but there is also some influence of, for instance, grain boundary M/sub 23/C/sub 6/ films and discontinuous precipitation of Ni/sub 3/Ti or M/sub 23/C/sub 6/ in grain boundaries. The extent of ..gamma..'-precipitation is controlled primarily by the (Ti+Al)-content. To avoid ..gamma..' and ensure a high creep ductility the (Ti+Al)-content should be limited to 0.70-0.75% for alloy ...

1982-04-01

395

Effects of composition, heat treatment and cold work on structure and properties of alloy 800  

International Nuclear Information System (INIS)

The creep characteristics of alloy 800 at temperatures around 600"0C are greatly affected by the composition and treatments in the final stages of manufacture. Short-term and creep properties of alloy 800 at 600"0C are described for six melts covering the carbon range 0.054-0.078%, the titanium range 0.23-0.57% and the aluminium range 0.17-0.52%. The properties are related to the alloy chemistry and the microstructure. It is shown that homogeneously nucleated #gamma#'-precipitates are the main cause of low ductility in alloy 800 but there is also some influence of, for instance, grain boundary M_2_3C_6 films and discontinuous precipitation of Ni_3Ti or M_2_3C_6 in grain boundaries. The extent of #gamma#'-precipitation is controlled primarily by the (Ti+Al)-content. To avoid #gamma#' and ensure a high creep ductility the (Ti+Al)-content should be limited to 0.70-0.75% for alloy 800 with a carbon content of 0.054-0.078% and ...

396

Effect of total pressure on sulfur capture of Ca-ion exchanged coal; Kaatsu jokenka ni okeru Ca-tanjitan no datsuryu koka  

Energy Technology Data Exchange (ETDEWEB)

In relation to coal gasification and combustion under high pressure as highly efficient coal utilization, the effect of total pressure and sintering on the SO2 capture ability of Ca-ion exchanged coal and other desulfurizing agents were studied. In experiment, specimens were filled into a small pressurized reactor to heat them under high-pressure N2 atmosphere. After the completion of combustion reaction of char at 850{degree}C, SO2, CO2 and CO gases were measured at an outlet while flowing SO2/N2. As the experimental result, all of the S content in Ca-ion exchanged coal was not absorbed by Ca content in coal during pyrolysis and combustion, resulting in discharge of 36% of the S content. Since Ca-ion exchanged coal is fast in combustion reaction, most of the S content was desulfurized by coal ash. The ash content yielded from Ca-ion exchanged coal was more excellent in SO2 capture ...

1996-10-28

397

Clinical significance of changes of plasma endothelial vasoactive factors contents after treatment in patients with systemic sclerosis (SSc)  

International Nuclear Information System (INIS)

Objective: To investigate the relationship between endothelial vasoactive factors and development of systemic sclerosis (SSc). Methods: Blood circulating endothelial cell count (CEC, with density gradient precipitation method); plasma endothelin (ET), thromboxane B2 (TXB2 ), 6-keto-prostaglandin F1? concentrations (all above three with RIA); nitric oxide (NO) contents (with Griss method) and plasma intercellular adhesion molecule-1 (ICAM-1), p-selectin (P-S) contents (with ELISA) were measured in 52 patients with systemic sclerosis (SSc) both before and after treatment with prostaglandin E1 and 30 controls. Results: Plasma ET, TXB2, ICAM-1, P-S contents and CEC were significantly higher and plasma NO, 6-K-PGF1? contents were significantly lower in all the patients with SSc before treatment than those in the controls, After treatment, the patients with satisfactory responses (n=33) had the abnormal ...

2005-02-01

398

[Reactivity of the limestone in wet flue gas desulfurization].  

Science.gov (United States)

On the basis of the analysis of chemical components of the natural limestones from different deposits in China, the pore structures of the typical limestones, with the different CaCO3 content, were examined. The reactivity of the limestones was investigated by sulfuric acid titration and gas-liquid absorption methods. The research results showed that the specific surface area of the natural limestones studied in this work was about 1.8 m2/g. It was seen that the pH of the limestone slurry rapidly decreased and then back up when the sulfuric acid was added. The higher the CaCO3 content was, or the smaller the particle size was, the larger the pH back-up rate was, and similarly the faster the SO2 concentration of the reactor outlet increased. The Reactivity of the limestone obtained by the sulfuric acid titration had the same features as that obtained by the gas liquid absorption. Compared with the specific surface area, the CaCO3 ...

2005-11-01

399

Transesterification of palm oil and esterification of palm fatty acid in near- and super-critical methanol with SO4-ZrO2 catalysts  

British Library Electronic Table of Contents (United Kingdom)

Sulfated zirconia (SO4-ZrO2) catalysts, prepared with three different sulfur loading contents (0.75%, 1.8% and 2.5%) at two calcination temperatures (500degreeC and 700degreeC), were tested for use in the transesterification of purified palm oil (PPO) and the esterification of palm fatty acid (PFA) in near-critical and super-critical methanol. Techniques including BET, XRD, NH3- and CO2-TPD revealed that the sulfur content and calcination temperature strongly affects the catalyst base-acid site, specific surface area, average pore size, phase structure, and thus the catalytic reactivity. The most suitable sulfur loading content was found to be 1.8% and the optimum calcination temperature 500degreeC. The results show that the use of SO4-ZrO2 reduces esterification reaction times, the amount...

2010-01-01

400

Total phenolics and antioxidant activity of five medicinal plant; Fenois totais e atividade antioxidante de cinco plantas medicinais  

Energy Technology Data Exchange (ETDEWEB)

This paper describes total phenolics content and antioxidant activity in the ethanolic extract of leaves, bark and roots of five medicinal plants: Terminalia brasiliensis Camb., Terminalia fagifolia Mart. and Zucc., Copernicia cerifera (Miller) H.E. Moore, Cenostigma macrophyllum Tul. var. acuminata Teles Freire and Qualea grandiflora Mart. The total phenolics content of the plant extracts, determined by the Folin-Ciocalteu method, varied from 250.0 {+-}8,2 to 763,63 {+-}13.03 mg of gallic acid equivalent/g dry EtOH extract. The antioxidant activity of extracts was evaluated using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay system. Extract of bark from T. brasiliensis, the most active, with an EC{sub 50} value of 27.59 {+-} 0.82 {mu}g/mL, was comparable to rutin (EC{sub 50} = 27.80 {+-} 1.38) and gallic acid (EC{sub 50} = 24.27 {+-} 0.31), used as positive controls. The relationship between total phenolic content and ...

2007-03-15

401

The influence of metallurgical variables on the temperature dependence of irradiation hardening in pressure vessel steels  

International Nuclear Information System (INIS)

Yield stress elevations (#DELTA##sigma#_y) in pressure vessel steels irradiated at intermediate flux and fluence systematically decreased with increasing temperature and decreasing copper and nickel content. Lower stress relief temperature also decreased #DELTA##sigma#_y at bulk copper concentrations greater than about 0.3%. The dependence of #DELTA##sigma#_y on irradiation temperature between 260 and 316 C increased with copper and nickel content and decreased with phosphorus content. When normalized by the average #DELTA##sigma#_y, the fractional temperature dependence correlates with a simple empirical chemistry factor of copper and phosphorus. The correlation predicts data on the irradiation temperature dependence of #DELTA##sigma#_y found in the literature within a standard error of about 0.3 MPa/degree C and is consistent with current understanding of hardening mechanisms. However, questions remain about the effects ...

1994-06-20

402

The Mechanical Properties of Alumina Films Formed by Plasma Deposition and by Ion Irradiation of Sapphire  

Energy Technology Data Exchange (ETDEWEB)

This paper examines the correlation between mechanical properties and the density, phase, and hydrogen content of deposited alumina layers, and compares them to those of sapphire and amorphous alumina synthesized through ion-beam irradiation of sapphire. Alumina films were deposited using electron beam evaporation of aluminum and co-bombardment with O{sub 2}{sup +} ions (30-230 eV) from an electron cyclotron resonance (ECR) plasma. The H content and phase were controlled by varying the deposition temperature and the ion energy. Sapphire was amorphized at 84 K by irradiation with Al and O ions (in stoichiometric ratio) to a defect level of 4 dpa in order to form an amorphous layer 370 nm thick. Nanoindentation was performed to determine the elastic modulus, yield strength and hardness of all materials. Sapphire and amorphized sapphire have a higher density and exhibit superior mechanical properties in comparison to the deposited alumina films. ...

1999-07-16

403

Structure and Crystallization Behavior of Nylong 66/Multi-Walled Carbon Nanotube Nanocomposites at Low Carbon Nanotube Contents  

Energy Technology Data Exchange (ETDEWEB)

Multi-walled carbon nanotubes (MWNTs) were modified with poly(hexamethylene adipamide) (also known as Nylon 66) via a controlled polymer solution crystallization method. A 'nanohybrid shish kebab' (NHSK) structure was found wherein the MWNT resembled the shish while Nylon 66 lamellar crystals formed the kebabs. These Nylon 66-functionalized MWNTs were used as precursors to prepare polymer/MWNT nanocomposites. Excellent dispersion was revealed by optical and electron microscopies. Nitric acid etching of the nanocomposites showed that MWNT formed a robust network in Nylon 66. Non-isothermal DSC results showed multiple melting peaks, which can be attributed to lamellar thickness changes upon heating. The crystallite sizes L{sub 100} and L{sup 010} of Nylon 66, determined by WAXD, decreased with increasing MWNT contents. Isothermal DSC results showed that crystallization kinetics increased first and then decreased with increasing MWNT ...

2007-01-01

404

Structural, electronic and magnetic properties of splat-quenched FeCsub(x) alloys (x<0.05)  

International Nuclear Information System (INIS)

The results of a combined investigation of splat-quenched Fe-Csub(x) (x<0.05) alloys by resistivity, X-ray diffraction and Moessbauer spectroscopy are presented. The residual resistivity increases linearly with the carbon content (#DELTA#rho=5#mu##OMEGA#cm/at.%) with a slope identical to that observed in the dilute ferritic phase. X-ray diffraction reveals the presence of a martensite structure in addition to a small fraction of residual austenite; the dependence of the a and c lattice parameters on xsub(c) agrees with earlier measurements. A detailed investigation of the relative reflexion intensities shows that the as-quenched martensites consist of a mixing of massive martensite and tetragonal martensite for low carbon content and of tetragonal martensite only for xsub(c) approximately 0.05. The Moessbauer spectra reveal 3 or 4 magnetically non equivalent iron sites. From a detailed analysis of the intensity dependence of the subspectra ...

2006-01-01

405

Structural studies of some phospho-borate glasses using ultrasonic pulse-echo technique, DSC and IR spectroscopy  

International Nuclear Information System (INIS)

Glasses in the system (95-x) [0.25 Na2O-0.75 B2O3]-x P2O5-5 Fe2O3 (0?x?15 mol%), have been prepared by the melt quenching technique. Elastic properties and FT-IR spectroscopic studies have been employed to study the role of P2O5 on the structure of the glass system. Elastic properties Poisson's ratio, micro-hardness and Debye temperature have been investigated using sound wave velocity measurements at 4 MHz (both longitudinal and shear) at room temperature. The results showed that the density and the molar volume increase as both sound velocities and the determined glass transition temperatures decrease with increasing the contents of P2O5. Infrared spectra of the glasses reveal that the borate network consists of diborate units and is affected by the increase in the concentration of P2O5 content as a second network former. These results are interpreted in terms of the replacement of the diborate units with B-O-B bridges by phosphate units with ...

2009-06-01

406

Straining electrode behavior and corrosion resistance of nickel base alloys in high temperature acidic solution  

International Nuclear Information System (INIS)

Repassivation behavior and IGA resistance of nickel base alloys containing 0#approx#30 wt% chromium was investigated in high temperature acid sulfate solution. (1) The repassivation rate was increased with increasing chromium content. And so the amounts of charge caused by the metal dissolution were decreased with increasing chromium content. (2) Mill-annealed Alloy 600 suffered IGA at low pH environment below about 3.5 at the fixed potentials above the corrosion potential in 10%Na_2SO_4+H_2SO_4 solution at 598K. On the other hand, thermally-treated Alloy 690 was hard to occur IGA at low pH environments which mill-annealed Alloy 600 occurred IGA. (3) It was considered that the reason, why nickel base alloys containing high chromium content such as Alloy 690 (60%Ni-30%Cr-10%Fe) had high IGA/SCC resistance in high temperature acidic solution containing sulfate ion, is due to both the promotion of the repassivation and the ...

1991-08-25

407

Seasonal variation of radon in dwellings in an area close to uraniferous fluorite veins in northern Thailand  

Energy Technology Data Exchange (ETDEWEB)

Indoor radon concentration measurements are carried out in an area close to uraniferous fluorite veins in northern Thailand. The concentrations are found to vary from season to season, having the highest value of 154 {plus minus} 51 Bq.m{sup -3} in winter and lowest value of 50 {plus minus} 12 Bq.m{sup -3} in summer. In the rainy season the concentration is 65 {plus minus} 23 Bq.m{sup -3}. There is a large discrepancy in radon concentrations from house to house in winter. These phenomena are believed to be influenced primarily by the degree of ground moisture content and air mass movement, i.e. much lower moisture content and less air movement during the winter compared to the summer and rainy season. The annual average radon concentrations in these dwellings very from 56 to 163 Bq.m{sup -3}, having an arithmetic mean of 89 {plus minus} 22 Bq.m{sup -3}, compared to the arithmetic mean of 37 {plus minus} 7 Bq.m{sup -3} found from dwellings in ...

1990-01-01

408

SE and I content in military total diet  

International Nuclear Information System (INIS)

Selenium and iodine are trace elements that play an important role in health of man and animals. Concerning supply of both elements it is important to meet nutritional needs. According to discoveries selenium is a part of an active group of glutathione peroxidase enzyme. It prevents necrotic changes in liver, muscle dystrophy and has impact on growth. Extensive studies on content of selenium in plant and animal origin products were started in the beginning of the seventies in Western Europe (Frankenberger, et al., 1998). The aim of our work was to determine selenium and iodine content in total diets of Slovene military. Slovene military nutrition is based on its own nutritional standards, which determine 200 #mu#g of iodine and 50 #mu#g of selenium in daily diet (Rep. Slovenija Ministrstvo za Obrambo, 1994). To determine if the amounts of both elements meet the standards we have analysed 20 total daily diets from four different barracks within ...

2003-06-10

409

Removal and recovery system of hexavalent chromium from waste water by tannin gel particles  

Energy Technology Data Exchange (ETDEWEB)

Tannin gel particles that have extremely high adsorption capacity for hexavalent chromium Cr(VI) have been developed by controlling gelation of Mimosa tannin extracted from the bark of plants. The gelation process is composed of two stages; partial gelation of Mimosa tannin by reaction with formaldehyde (cross-linking agent) and granulation by dispersing the partially gelated solution into a liquid mixture of decalin ad a polyether nonionic surfactant with vigorous stirring. The structure of the tannin gel particles is controlled by a combination of operating conditions such as reaction time and temperature at both stages. The water content of the tannin gel particles that reflects their structure can be widely changed from 40 to 79 %(wet basis), even for a constant composition of 23 g Mimosa tannin and 6 ml formaldehyde (37 wt %). It is found that it is very important to increase the water content without losing mechanical strength and supply ...

2000-10-01

410

Radon exhalation from uranium mill tailings: Modelisation and in situ validation  

International Nuclear Information System (INIS)

TRACI, a model based on the physical mechanisms governing the radon transport in unsaturated soils, has been developed to evaluate the radon flux density at Uranium Mill Tailings (UMT) covers surface. First, moisture contents in the soil, induced by weather conditions, are calculated. Then, radon concentrations in the air-filled pore space, and radon flux density at the soil surface, are deduced from a transport model which takes account for diffusion and convection in the pore space. To check the hypothesis used in TRACI and the efficiency of cover layers, an in situ study was launched in 1997 with the French uranium mining company, COGEMA. It consists of continuous measurements of moisture contents, suctions, radon concentrations at various depths inside an UMT cover, and flux density at its surface. The first analysis made on in situ observations shows that radon concentrations and flux density, calculated with a steady-state diffusion model ...

2002-02-01

411

Quantitative assessment of mineral content in metacarpal bone with Fuji computed radiography  

Energy Technology Data Exchange (ETDEWEB)

A new microdensitometry method for quantitative assessment of bone mineral content using Fuji computed radiography (FCR) was developed and the results were compared with those obtained by the conventional film-screen method. Using both methods, X-ray pictures of the 2nd metacarpal bone were taken with a reference aluminum step wedge in nine normal subjects and nine parameters representing the width and density of bone marrow and cortex were calculated in middle of the bone shaft. Interobserver reproducibility assessed for three parameters was significantly higher in the FCR method than the conventional one. The value of {Sigma}GS computed by the FCR method, that is equivalent to the net bone density of the transverse section of the shaft, showed higher correlation with the one obtained by computed tomography in comparison with the conventional method. In our FCR method, moreover, interobserver reproducibility and accuracy was improved by employing automatic ...

1990-05-01

412

Quantitative assessment of mineral content in metacarpal bone with Fuji computed radiography  

International Nuclear Information System (INIS)

A new microdensitometry method for quantitative assessment of bone mineral content using Fuji computed radiography (FCR) was developed and the results were compared with those obtained by the conventional film-screen method. Using both methods, X-ray pictures of the 2nd metacarpal bone were taken with a reference aluminum step wedge in nine normal subjects and nine parameters representing the width and density of bone marrow and cortex were calculated in middle of the bone shaft. Interobserver reproducibility assessed for three parameters was significantly higher in the FCR method than the conventional one. The value of #SIGMA#GS computed by the FCR method, that is equivalent to the net bone density of the transverse section of the shaft, showed higher correlation with the one obtained by computed tomography in comparison with the conventional method. In our FCR method, moreover, interobserver reproducibility and accuracy was improved by employing automatic ...

1990-01-01

413

Production of phenols and charcoal from bagasse by a rapid continuous pyrolysis process  

Energy Technology Data Exchange (ETDEWEB)

Tar and charcoal could be produced in high yields from bagasse by applying a rapid continuous pyrolysis process at a relatively low temperature. The ether extractives of the pyrolytic tar and oil amounted to 9.4% based on bagasse. Phenols represented 79% of these extractives. Gas chromatographic separation showed that guaiacol and its derivatives constituted 38% of the identified simple phenols. There were much smaller amounts of syringol and none at high pyrolysis temperatures. Depithing did not reduce the ash content of the charcoal, but it yielded an environmentally clean charcoal containing practically no sulfur or nitrogen. It was necessary to remove the fine particle size fraction of the bagasse after grinding in order to reduce the ash content of the charcoal. The carbon content of the charcoal increased rapidly with increasing temperature, and reached 96% at 720/sup 0/C. The charcoal had a remarkably high adsorption ...

1982-01-01

414

Operating experience with solidification of radioactive waste by a thin-film evaporator  

Energy Technology Data Exchange (ETDEWEB)

In the nuclear power stations of GDR the rough radioactive waste includes borat-containing evaporator bottoms and spent ion exchanger resins. For its final disposal in deep geological formations (rock salt mines) this waste has to be solidified. The experience of one year lasting operation of a steam heated thin-film evaporator (heating surface 2 m{sup 3}) for evaporator bottoms to be solidified with a solid content of 200-250 g/l are reported on. In short time such amount of water is abstracted from the rough waste that due to the borate content a hot high-viscous product passes from evaporator to waste drum and there solidifies like glass to monolith. The product quality depends on the adjustment of the flow-equilibrium in the evaporator. Boric acid is used as matrix for the radioactive residues. The residual water content of the solidified waste product was about 15-20%, the volume reduction was V{sub f}=5...6. In order ...

1990-01-01

415

Operating experience with solidification of radioactive waste by a thin-film evaporator  

International Nuclear Information System (INIS)

In the nuclear power stations of GDR the rough radioactive waste includes borat-containing evaporator bottoms and spent ion exchanger resins. For its final disposal in deep geological formations (rock salt mines) this waste has to be solidified. The experience of one year lasting operation of a steam heated thin-film evaporator (heating surface 2 m"3) for evaporator bottoms to be solidified with a solid content of 200-250 g/l are reported on. In short time such amount of water is abstracted from the rough waste that due to the borate content a hot high-viscous product passes from evaporator to waste drum and there solidifies like glass to monolith. The product quality depends on the adjustment of the flow-equilibrium in the evaporator. Boric acid is used as matrix for the radioactive residues. The residual water content of the solidified waste product was about 15-20%, the volume reduction was V_f=5...6. In order to be sure ...

1990-06-01

416

Neutron shielding and constructional characteristics of a new type concrete and from borated clinker  

International Nuclear Information System (INIS)

A boron containing cement, which can be used as nuclear shielding material, is produced at pilot plant scale applying two different methods. In the first method, the raw mixture of a normal portland cement is mixed with pre-calcined colemanite, a calcium borate mineral, and clinkerized in a rotary kiln (borated-clinker). In the second method, the colemanite is mixed with an admixture, which contains mainly limestone and marl, and burnt in the rotary kiln to obtain a borated-lime composite. The borated-lime composite is then added to the normal portland cement clinker up to 2% B_2O_3 content for shielding purpose. The results have shown that the borated-clinker contained untolerable amount of free lime resulting in a decrease in compressive strength. The addition of the borated-lime composite to the normal portland cement clinker up to 1% B_2O_3 content did not alter the setting time and the volume expansion properties. The reduction in the ...

1994-11-07

417

Limit of pitting corrosion at high-alloyed special steels and NiCrMo alloys in chloride solution; Die Lochkorrosionsbegrenzung bei hochlegierten Sonderedelstaehlen und NiCrMo-Legierungen in Chloridloesung - Einflussfaktoren und Ausmass  

Energy Technology Data Exchange (ETDEWEB)

The phenomenon of the limit of pitting corrosion in direction to positive potentials is studied by potentiokinetic polarization after a jump in the transpassive range and by potentiostatic tests at technical wrought materials and at model alloys of the systems NiCrMo and NiMo in CaCl{sub 2} solution in the concentration range 1 to 9 mol/l chloride at pH-values of 1 to 9 at temperatures of 30 to 110 C. Surface-analytical investigations gives in connection with knowledges from anodic polarization studies directions to the mechanism of the limit of pitting corrosion. Ranges of the limit of pitting corrosion are obtained at materials with a Mo content above 6.5% and contents of chloride of the media above 2 mol/l chloride. Increasing temperatures, increasing contents of chloride and sulfate shift the potential of the limit of pitting corrosion being always above 0.2 V (SCE) at potentiostatic determination to noble direction. ...

2001-08-01

418

Influences of particle sizes and contents of chemical blowing agents on foaming wood plastic composites prepared from poly(vinyl chloride) and rice hull  

British Library Electronic Table of Contents (United Kingdom)

This research aims to investigate the effects of chemical blowing agent (CBA) contents and particle sizes on the properties of foamed poly(vinyl chloride) (PVC)/rice hull (RH) composites. Fine particles of azodicarbonamide (AC) at 5, 8, 11 and 22mm were modified with 20% by weight of ZnO and used at 0-3.0% by weight. The average cell size and density of the PVC/RH foamed profiles were reduced as the content of modified azodicarbonamide (mAC) increased. Larger mAC particles lowered the density more effectively. Maximum reduction of density by 46% was achieved when mAC 22mm was applied at 2.0% by weight. Larger blowing particles led to PVC/RH foam with greater flexural modulus and strength. Greater impact strength, observed when 5mm mAC was applied, resulted from the rather thick cell wall c...

2011-01-01

419

Influence of iron deficiency in the radiopharmaceutical behavior of red blood cells labeled with "9"9"mTc("9"9"mTC-RBC)  

International Nuclear Information System (INIS)

Full text: Red blood cells (RBCs) labeled with "9"9"mTc are commonly used in the evaluation of cardiac function, gastrointestinal tract bleeding, red blood cell volume or splenic sequestration. Generally stannous ion is used as reducing agent. A proposed mechanism is that once the stannous ion (Sn) and the pertechnetate ("9"9"mTc) reach the interior of the RBC, the radionuclide is mainly house in the #beta#-chain of hemoglobin. The aim of this study was to determine if hemoglobin content reduction, an indicator of iron deficiency anemia, could affect the efficiency of RBC labeling and the biological distribution of this radiopharmaceutical. We studied 30 rats fed for 3 weeks after weaning with diets with iron contents of 6.5 ppm (group A), 18 ppm (group B) and 100 ppm (control). For all groups, the labeling yields were always higher than 97%; the percentage of radioactivity was mostly founded in blood with almost negligible radioactivity the ...

2005-11-09

420

Field corrosion tests for a low chromium steel carried out at superheater area of a utility boiler with three coals containing different chlorine contents  

Energy Technology Data Exchange (ETDEWEB)

Field corrosion tests for a low chromium steel were carried out at a superheater area of a 100 MW pulverized coal-fired boiler for various times up to 500 h, when three coals having different chlorine contents were combusted. The low chromium steel had obvious metal loss due to corrosion, and comparison of the metal loss and corrosion scale structure was made among the three coals in respect to chlorine contents as well as other elements affecting its corrosion. Corrosion scales of the low chromium steel had a general two-layer structure: an inner layer containing iron, chromium, oxygen and sulfur, and an outer layer made of porous iron oxide and fly ash particles. Distinct molten phase formation, which is an indication of severe corrosion, was observed for the coal containing only the middle high chlorine, and it initiated in the outer layer of the corrosion scales. (author)

2007-04-15

421

Evaluation of new corrosion-resistant superheater tubing in high-efficiency waste-to-energy plants  

Energy Technology Data Exchange (ETDEWEB)

Field corrosion tests were conducted on eight single tube materials and two welded overlay materials in three typical Japanese waste incineration plants in an effort to develop new corrosion-resistant superheater tubes capable of functioning efficiently under temperature and pressure conditions of 500 C and 100 kgf/cm{sup 2}-g in high-efficiency waste-to-energy (WTE) plants. Austenitic alloys containing higher concentrations of chromium, nickel, and molybdenum [Cr + Ni + Mo] showed excellent corrosion-resistant properties, and the new alloys JHN24 and HR30M showed good corrosion resistance. Different corrosion rates found in each of the three plants were explained by differences in operating conditions, such as gas temperature, concentration of molten salts resulting from chlorine (Cl) content of deposits, heavy metal (zinc oxide [ZnO] + lead oxide [PbO]) content, etc. It was confirmed that the corrosion rate of materials positioned in the ...

1998-07-01

422

Emission characterization of an alcohol/diesel-pilot fueled compression-ignition engine and its heavy-duty diesel counterpart. Final report, August 1980-August 1981  

Energy Technology Data Exchange (ETDEWEB)

This report describes results from emissions testing of a prototype diesel engine, developed by Volvo Truck Corporation of Sweden, which uses pilot injection of diesel fuel for compression ignition of alcohol fuel injection for main combustion. In addition to this dual-fuel engine, emission testing was also conducted on a heavy-duty diesel engine of similar design. Both engines were tested over the 1979 13-mode FTP, or shorter versions of this modal test, and over the 1984 Transient FTP as well as an experimental bus cycle. The dual-fuel engine was characterized with methanol, ethanol and ethanol with 30 percent water (wt %). An oxidation catalyst was also used with methanol and ethanol. Emission characterization included regulated emissions (HC, CO, and NOX) along with total particulate, unburned alcohols, individual hydrocarbons, aldehydes, phenols, and odor. The particulate matter was characterized in terms of particle size distribution, sulfate content, C, H, ...

1981-08-01

423

El Roque de Los Muchachos Site Characteristics. III. Analysis of Atmospheric Dust and Aerosol Extinction  

CERN Document Server

Canary Islands are normally interested by dominant North-East winds that, in some meteorological conditions, can transport sand at high altitude from the Sahara desert. The dust may affect the efficiency of the telescopes and decreases the transparency of the sky. In order to maximize the scientific return of the telescopes located at the ORM, we present an analysis of the atmospheric dust content and its effects on astronomical observations. B, V and I dust aerosol astronomical extinction are derived. Using a 5 years series database of data taken from the four channel TNG dust monitor, we compute a mean hourly and daily values of the dust content. We have detected particles having size 0.3, 0.5, 1.0 and 5.0 um. Using a power law we have derived the content of 10.0 um particles. We found a typical local dust concentration ranging from 3x10^6 particles per cubic meter at 0.3 um, to 10^3 at 5.0 um and 10 at 10.0 um, ...

2008-01-01

424

Effects of gamma irradiation on medicinal plants and spices (2): Piper cubeba, piper nigrum, piper retrofractum, amomum cardamomum, and myristica fragrans  

Energy Technology Data Exchange (ETDEWEB)

Effects of gamma irradiation on essential oils of five medicinal plants i.e. dried seeds of piper cubeba(cubeb), piper nigrum(black pepper), piper retrofractum, amomum cardamomum(cardamom) and myristica fragrans(mace), packed in low density polyethylene bag of 0.13 mm thickness have been investigated. After being irradiated at doses of 5 and 10 kGy, a part of the samples was analysed, and the rest were stored for six months at temperature of 30 +- 2 degC, and humidity ranging from 70 to 95%. The essential oil characteristics of control, irradiated and six month stored samples were analysed using infrared and ultraviolet spectrophotometers, HPLC, GLC and refractometer. Other parameters observed were moisture content and essential oil content of the samples. Results showed that irradiation up to a dose of 10 kGy do not give any significant effect on these parameters. Significant changes were only found in the essential oil ...

1983-12-01

425

Effects of an acute dose of gamma radiation exposure on stem diameter growth, carbon gain, and biomass partitioning in Helianthus annuus  

Energy Technology Data Exchange (ETDEWEB)

Nineteen-day-old dwarf sunflower plants (Helianthus annuus, variety NK894) received a variable dose (0-40 Gy) from a cobalt-60 gamma source. A very sensitive stem monitoring device, developed at Battelle's Pacific Northwest Laboratories, Richland, Washington was used to measure real-time changes in stem diameter. Exposure of plants caused a significant reduction in stem growth and root biomass. Doses as low as 5 Gy resulted in a significant increase in leaf density, suggesting that nonreversible morphological growth changes could be induced by very low doses of radiation. Carbohydrate analysis of 40-Gy irradiated plants demonstrated significantly more starch content in leaves and significantly less starch content in stems 18 days after exposure than did control plants. In contrast, the carbohydrate content in roots of 40-Gy irradiated plants were not significantly different from unirradiated plants 18 days after ...

1988-05-25

426

Effects of Soil Properties and Nitrogen Fertilization on Distribution of NO3-N in Soils of Eastern Poland  

British Library Electronic Table of Contents (United Kingdom)

The effects of anthropogenic (nitrogen fertilization) and natural [soil texture, pH content of humus, ammonium nitrogen (N-NH4), and the available forms of phosphorus (P), potassium (K), magnesium (Mg)] factors on nitrate nitrogen (NO3-N) content and distribution were shown. The dependencies between these factors and the content of NO3-N in soil were estimated in three soil layers: 0-30 cm; 31-60 cm; 61-90 cm. The research was carried out in 2004-2006, and the soil samples were taken from 411 places throughout eastern Poland in two seasons: spring and autumn. The concentration of NO3-N significantly depended on the year of investigation, season of the year, and depth of sampling. Distribution of NO3-N in the soil profile indicates possibility of NO3 leaching during winter and early spring....

2011-01-01

427

Effect of solute content on plasma nitriding behavior of Fe-Cr alloys; Fe-Cr gokin purazuma chikka kyodo ni oyobosu yoshitsu nodo no eikyo  

Energy Technology Data Exchange (ETDEWEB)

It has been clarified by the present authors, based on the plasma nitriding of Fe-Cr alloys and Fe-Ti alloys carried out at the temperature under 550{degree}C hitherto, that an internal nitriding layer is formed due to the fine dispersion of the particles of Cr nitride and Ti nitride in {gamma}{prime} Fe4N layer on the specimen surface. In this study, the plasma nitriding of Fe-Cr alloys are carried out at 650{degree}C, and the effects of the solute (Cr) content on the structures, nitride and the thickness distribution are examined. The main results obtained therefrom are indicated hereafter. In accordance with the observation on the cross-sectional structure of the alloys, only the nitriding layer deduced as the dispersion and precipitation of the particles of Cr nitride from {alpha}-Fe of the mother phase is formed, while {gamma}{prime}-Fe4N layer, which is found at the temperature under 550{degree}C, is not formed. The nitride of Cr generated in the nitriding ...

1996-03-15

428

Effect of natural rubber processing sludge on the degradation of crude oil hydrocarbons in soil  

Energy Technology Data Exchange (ETDEWEB)

Crude oil-polluted soil (five parts of weathered crude oil per 100 parts of soil; equivalent to 50,000 mg oil kg{sup -}1 soil) samples were slurried in deionised water (300% of the water retention capacity of the soil) and treated with various amounts of natural-rubber processing sludge (nitrogen content 62.15 mgkg{sup -1} and phosphorus contents 8.75 mgkg{sup -1}) in a well-stirred, continuously-aerated tank at 29{sup o}C. Changes in the total hydrocarbon content of the soil sample were determined, using a spectrophotometric technique, as a function of time. The extent of crude oil degradation was markedly higher (by up to 100%) in the sludge-treated soil than in the untreated soil sample. The efficiency of biodegradation of the crude oil hydrocarbons using the slurry-phase technique was compared with that of solid-phase technique. (author)

2002-03-01

429

Effect of low copper content and heat treatment on intergranular corrosion of model AlMgSi alloys  

International Nuclear Information System (INIS)

Certain 6000-series extrusions may develop susceptibility to intergranular corrosion (IGC) by improper heat treatment, especially if copper is present as an alloying element. Although occurrence of IGC in such cases is documented, the underlying mechanisms are not adequately explained. We present corrosion data for two model alloys, having different Cu content and Mg:Si ratio, showing that the susceptibility to IGC depended primarily on the Cu content and secondly on thermal processing. Low Cu samples (0.0005 wt.% Cu) were essentially resistant to IGC. High Cu samples (0.12 wt.% Cu), which were air cooled after extrusion, exhibited significant IGC. However, IGC susceptibility was reduced significantly as a result of artificial aging to peak strength. Water quenched high Cu samples were essentially resistant to IGC. However, slight IGC susceptibility was introduced after aging. Electron optical characterisation revealed Al_4Mg_8Si_7Cu_2 ...

2006-01-01

430

Effect of hot air aging on properties of EPDM/SmBO3/EVA and EPDM/ATO/EVA composites  

British Library Electronic Table of Contents (United Kingdom)

Abstract Ethylene-propylene-diene rubber (EPDM)/samarium borate (SmBO3)/ethylene-vinyl acetate (EVA) copolymer and EPDM/antimony-doped tin oxide (ATO)/EVA composites are aged at 150C for different intervals. Surface modification is used to improve filler to matrix interphase. The main aim is to investigate the effect of filler type and vinyl acetate (VA) content in EVA on stability of EPDM composites. It is found that acidic ATO particles can lower pH level of EPDM composites and then promote the degradation of acetic acid during aging. Moreover, when VA content exceeds 14 wt %, the instable VA content causes more acetic acids escape during aging. With the increasing of aging time, EPDM/SmBO3 control and EPDM/SmBO3/EVA composites tend to become darker while EPDM/ATO and EPDM/ATO/EVA compos...

2011-01-01

431

Effect of gamma irradiation on the antimicrobial and free radical scavenging activities of Glycyrrhiza glabra root  

International Nuclear Information System (INIS)

The efficacy of gamma irradiation as a method of decontamination for food and herbal materials is well established. In the present study, Glycyrrhiza glabra roots were irradiated at doses 5, 10, 15, 20 and 25 kGy in a cobalt-60 irradiator. The irradiated and un-irradiated control samples were evaluated for phenolic contents, antimicrobial activities and DPPH scavenging properties. The result of the present study showed that radiation treatment up to 20 kGy does not affect the antifungal and antibacterial activity of the plant. While sample irradiated at 25 kGy does showed changes in the antibacterial activity against some selected pathogens. No significant differences in the phenolic contents were observed for control and samples irradiated at 5, 10 and 15 kGy radiation doses. However, phenolic contents increased in samples treated with 20 and 25 kGy doses. The DPPH scavenging activity significantly (p<0.05) increased in ...

2010-04-01

432

Determination of the Al, Ti, V, Cu, Mn, Mo, and W content of nickel-base alloys by neutron activation analysis  

Science.gov (United States)

The authors develop a procedure for the determination of the Al, Ti, V, Cu, Mn, Mo, and W content of nickel-base alloys by neutron activation analysis. An M-10 microtron with a beryllium target in a paraffin microtron (with a beryllium target) in a paraffin moderator served as the neutron source. In order to evaluate the procedure for quantitative analysis, the authors determined the contents of the above elements in five reference standards, the bulk density of which was 2.94-4.17 g/cm/sup 3/. The difference in the self-absorption of the gammaquanta was assessed by determining the number of gamma-quanta with energies in the range 60-1332 keV that had passed through the RS N4 and N8 which showed the greatest difference in their composition. The results of the determination are presented. The proposed procedure is simple and rapid and can be used to determine the alloying components of nickel-based alloys with satisfactory precision.

1986-04-01

433

Determination of the Al, Ti, V, Cu, Mn, Mo, and W content of nickel-base alloys by neutron activation analysis  

International Nuclear Information System (INIS)

The authors develop a procedure for the determination of the Al, Ti, V, Cu, Mn, Mo, and W content of nickel-base alloys by neutron activation analysis. An M-10 microtron with a beryllium target in a paraffin microtron (with a beryllium target) in a paraffin moderator served as the neutron source. In order to evaluate the procedure for quantitative analysis, the authors determined the contents of the above elements in five reference standards, the bulk density of which was 2.94-4.17 g/cm"3. The difference in the self-absorption of the gammaquanta was assessed by determining the number of gamma-quanta with energies in the range 60-1332 keV that had passed through the RS N4 and N8 which showed the greatest difference in their composition. The results of the determination are presented. The proposed procedure is simple and rapid and can be used to determine the alloying components of nickel-based alloys with satisfactory precision.

434

Constructing Folksonomies from User-specified Relations on Flickr  

CERN Document Server

Many social Web sites allow users to publish content and annotate with descriptive metadata. In addition to flat tags, some social Web sites have recently began to allow users to organize their content and metadata hierarchically. The social photosharing site Flickr, for example, allows users to group related photos in sets, and related sets in collections. The social bookmarking site Del.icio.us similarly lets users group related tags into bundles. Although the sites themselves don't impose any constraints on how these hierarchies are used, individuals generally use them to capture relationships between concepts, most commonly the broader/narrower relations. Collective annotation of content with hierarchical relations may lead to an emergent classification system, called a folksonomy. While some researchers have explored using tags as evidence for learning folksonomies, we believe that hierarchical relations described ...

2008-01-01

435

Characterization of acai seeds as a feedstock for electricity generation via gasification; Caracterizacao do caroco de acai como insumo para geracao de eletricidade via gaseificacao  

Energy Technology Data Exchange (ETDEWEB)

This work presents an overview of the characterization physical-chemistry and energy of the aca pit used as input in process of generation of electricity through gasification. Acai pits analyses were accomplished with relationship to the acai pit drying, energy content, proximate and ultimate analyses, size, TGA experiments, bulk density. It was observed that the acai pit can be used as bioenergy but, it presents a low energy content (16,36 MJ/kg) in relationship that of the ' typical' biomass (21 MJ/kg ) and this is not due to the ash content that is very low (1,15%), but yes, the only composition that resembles each other more the Carbohydrates than to the typical composition of the usual biomass. The average diameter of 10 pits chosen at random was 9.5 mm. The acai pits have an angle of repose of {approx}20 degrees, making them ideal for feeding into gasification and combustion processes. (author)

2008-07-01

436

An indicator, high speed method for determining the water and aqueous phase content in a hydrocarbon fuel  

Energy Technology Data Exchange (ETDEWEB)

A method and an instrument for determining the total water content in a hydrocarbon fuel using an indicator composition, which includes calcium hydride and phenolphthaleyn, are developed. The essence of the method is fixing the presence of water with its interaction with the calcium hydride and subsequent indication of the formed Ca(OH)2 using the phenolphthallen. To make the indicator composition, a hygroscopic cotton, prewashed by rectified alcohol and dried for 30 minutes at 105 degrees, is impregnated by a 1 percent alcohol solution of phenolphthaleyn and is dried in the same conditions. Then the cotton is processed by a powder form calcium hydride (a layer thickness of 0.1 to 0.2 millimeters, and a granule size of less than or equal to 80 micromters). The indicator composition is placed in a glass tube (a diameter of 4 to 7 millimeters and a length of 80 to 100 millimeters), whose ends are sealed or filled with paraffin. The content of ...

1983-01-01

437

Alpha-spectrometric determination of uranium, plutonium, americium and curium isotope content in 'hot' particles and irradiated nuclear fuel  

International Nuclear Information System (INIS)

A method for express determination of "2"3"4"-"2"3"8U, "2"3"8"-"2"4"2Pu, "2"4"1"-"2"4"3Am and "2"4"2"-"2"4"4Cm content in fuel 'hot' particles and spent nuclear fuel is offered. The method is based on precision measurement of a sample #alpha# activity followed by estimate of relative contributions of individual nuclides, or groups of radionuclides, to total activity. Segregation in separate fractions of uranium, plutonium, americium and curium was made with the help of ion-exchange chromatography. Results are presented of "2"3"4"U, "2"3"8U, "2"3"8"Pu,"2"3"9"+"2"4"0Pu, "2"4"1Pu, "2"4"2Pu, "2"4"1"Am, "2"4"2"mAm, "2"4"3Am "2"4"2"Cm and "2"4"4Cm definition in 'hot' particles sampled in Chernobyl NPP surroundings, Opportunities to apply this method for identifying radionuclide content of spent nuclear fuel are discussed.

438

Active biomonitoring of heavy metal pollution using Rosa rugosa plants  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work was to evaluate the quality of a rural area near Faenza (Italy) by using an active biomonitoring approach, i.e., by placing homogeneous individuals of the perennial shrub Rosa rugosa in different sites throughout the area. Further sites, within the city or its environs, were used for comparison. Soil and leaves of R. rugosa were analyzed for their heavy metal content. The total heavy metal pattern of leaves closely paralleled the pattern registered in soil, with the highest content (both in total and assimilable forms) at the site in the urban area, which is exposed to heavy traffic. Pollen quality (abortiveness and viability) was also tested as a potential indicator of pollution. Pollen abortiveness was strictly related to Pb levels in leaves, while viability was inversely related to leaf Cr content. Our results suggest that R. rugosa has the potential to be a good biomonitoring system. - Rosa ...

2007-09-15

439

Active biomonitoring of heavy metal pollution using Rosa rugosa plants  

International Nuclear Information System (INIS)

The purpose of this work was to evaluate the quality of a rural area near Faenza (Italy) by using an active biomonitoring approach, i.e., by placing homogeneous individuals of the perennial shrub Rosa rugosa in different sites throughout the area. Further sites, within the city or its environs, were used for comparison. Soil and leaves of R. rugosa were analyzed for their heavy metal content. The total heavy metal pattern of leaves closely paralleled the pattern registered in soil, with the highest content (both in total and assimilable forms) at the site in the urban area, which is exposed to heavy traffic. Pollen quality (abortiveness and viability) was also tested as a potential indicator of pollution. Pollen abortiveness was strictly related to Pb levels in leaves, while viability was inversely related to leaf Cr content. Our results suggest that R. rugosa has the potential to be a good biomonitoring system. - Rosa ...

2007-09-01

440

A sensitivity study on neutronic properties of DUPIC fuel  

Energy Technology Data Exchange (ETDEWEB)

A sensitivity study has been done to determine the composition of DUPIC fuel from the viewpoint of neutronics fuel design. The spent PWR fuel compositions were generated and fissile contents adjusted by blending fresh uranium after mixing two spent PWR fuel assemblies. The {sup 239}Pu and {sup 235}U enrichments of DUPIC fuel were adjusted by controlling the amount of fresh uranium feed and the ratio of slightly enriched and depleted uranium in the feed uranium. Based on the material balance calculation, it is recommended that DUPIC fuel composition be such that spent PWR fuel utilization is more than 90%. A sensitivity study on the temperature reactivity coefficient of DUPIC fuel and shown that it is desirable to increase the {sup 239}Pu and {sup 235}U contents to reduce both the fuel and coolant temperature coefficients. On the other hand, refueling simulations of the DUPIC core have shown that the channel power peaking factor, which is a ...

1998-12-31

441

A novel approach to personal photo album representation and management  

Science.gov (United States)

In this paper we present a novel approach to personal photo album management allowing the end user to efficiently access the collection without any need for tedious manual annotation or indexing of the photos. The proposed work exploits methods and technology from the field of computer vision and pattern recognition for face detection, face representation and image annotation to automatically create description of images useful for content-based searching and retrieval. In fact, even if most of the used techniques are not reliable enough to address the general problem of content-based image retrieval, we show that, in a limited domain such as the one of personal photo album, it is possible to obtain results that improve the browsing capabilities of current photo album management systems. In particular, starting from the observation that most personal photos depict a usually small number of people in a relatively small number of different ...

2008-01-01

442

Wood-plastic composites using woods native to Iran  

International Nuclear Information System (INIS)

Radiation induced polymerization of methylmethacrylate and copolymerization of styrene-acrylonitrile mixture in mamrase Carpinus betulus was carried out by means of #gamma#-ray, under different moisture levels and additives. Under all conditions the degree of polymerization was as high as 60%. No pronounced differences were observed in the kinetics of the polymerization of MMA either with moisture content of wood nor with kind and amount of additives. At high moisture (80% RH) content the dimensional stability of wood-PMMA was increased four fold as compared with untreated wood. The hardness increased about 100% for a weight conversion of monomer of about 30 to 40%. Hardness of this wood-polymer composite is comparable to that of the best noble woods in the world. (author).

1978-10-26

443

Water resources data for Minnesota, water year 1993. Volume 2. Upper Mississippi and Missouri River basins. Water-data report (Annual), 1 October 1992-30 September 1993  

Energy Technology Data Exchange (ETDEWEB)

Water-resources data for the 1993 water year for Minnesota consists of records of stage, discharge and water quality of streams; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality in wells and springs. This volume contains discharge records for 58 gaging stations; stage and contents for 9 lakes and reservoirs; water quality 15 stream stations, 1 lakes station, 1 precipitation station, and water levels for 15 observation wells. Also included are 61 high-flow partial-record stations. Additional water data were collected at various sites, not part of the systematic data collection program and are pulished as miscellaneous measurements.

1994-07-01

444

Water resources data for Minnesota, water year 1991. Volume 2. Upper Mississippi and Missouri River Basins. Water-data report (Annual), 1 October 1990-30 September 1991  

Energy Technology Data Exchange (ETDEWEB)

Water-resources data for the 1991 water year for Minnesota consist of records of stage, discharge and water quality of streams; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality in wells and springs. The volume contains discharge records for 60 gaging stations; stage and contents for 9 lakes and reservoirs; water quality for 18 stream stations, 1 lake station, 22 partial-record sites, 1 precipitation station, 108 wells; and water levels for 119 observation wells. Also included are 59 high-flow partial-record stations. Additional water data were collected at various sites, not part of the systematic data collection program and are published as miscellaneous measurements or low-flow investigations.

1992-09-01

445

The prooxidant-antioxidant homeostasis in Guinea pigs after exposure to fractionated low-low X-radiation and correction of its disturbances with antioxidant complex treatment  

International Nuclear Information System (INIS)

The state of prooxidant-antioxidant homeostasis in Guinea pigs exposed to whole-body fractionated X-irradiation (5 fractions of 0.2 Gy at a 24 hr interval, up to total dose of 1.0 Gy, at a dose rate of 0.425 R/min) and a possibility of its disturbance correction with the complex of vitamins C, E and P was studied. Accumulation of primary and secondary lipid peroxidation products, decrease of the ascorbic acid content, increase of the content of its oxidized forms (dehydroascorbic acid and diketogulonic acid) in radiosensitive and radioresistant organs were found. Antioxidant complex administration reduced the disturbances of prooxidant-antioxidant homeostasis, but did not provide complete normalization.

446

Temporal variations of fluoride concentration in Isparta public water system and health impact assessment (SW-Turkey)  

British Library Electronic Table of Contents (United Kingdom)

Water?rock interaction is one of the prime factors affecting the fluoride contents of surface and groundwater. If fluoride concentration of drinking water has been neglected, excess fluoride can cause serious dental and medical problems on human health, which is well known at Golcuk-Isparta region. In the research area, Egirdir lake, Golcuk lake and surrounding springs have been utilized as drinking water sources. Golcuk lake water and surrounding groundwaters have high fluoride content (1.4?4.6?mg/l), which is above the WHO standards. Fluoride is predominantly supplied by dissolution of fluoride within the fluormicas of volcanics during the circulation of water. Fluoride concentrations of waters have shown variations for dry and rainy seasons depending on the degree of interaction between...

2008-01-01

447

System for cooling primary gas coolers using return water stabilized by means of ammonium sulfate  

Energy Technology Data Exchange (ETDEWEB)

Discusses scaling of closed systems for cooling coal gas from black coal coking. Scaling rate and factors that influence scaling are analyzed. Physical and chemical properties of scale buildup on the inner walls of pipe cooling systems are evaluated. Water pH value and its effects on scaling and solubility of chemical compounds that form scale are discussed. Use of ammonium sulfate for scale control is analyzed. Consumption rate of ammonium sulfate depends on ambient temperature, water pH value and chloride content in return water. Formulae for calculating optimum content of ammonium sulfates for scale control are derived. 3 refs.

1989-08-01

448

Study on polyamide thin-film composite nanofiltration membrane by interfacial polymerization of polyvinylamine (PVAm) and isophthaloyl chloride (IPC)  

British Library Electronic Table of Contents (United Kingdom)

A novel thin-film composite polyamide nanofiltration membrane was prepared through interfacial polymerization of polymeric polyamine polyvinylamine (PVAm) with isophthaloyl chloride (IPC) on a polysulfone supporting film. The composite membranes were prepared under different conditions and characterized in terms of chemical and morphological structures, surface zeta potential, pure water permeability, and rejection to different solutes including electrolytes and sucrose. The results showed that the membrane performance was significantly affected by the content of amine units of PVAm and the concentrations of PVAm and IPC. The increase of the content of amine units of PVAm and the concentration of IPC resulted in an augment in salt rejection and a decrease in permeability, while the increas...

2011-01-01

449

Study on fracture behaviour of Al?15%Mg2Si metal matrix composite with and without beryllium additions  

British Library Electronic Table of Contents (United Kingdom)

In this study, the influence of Beryllium (Be) content on the fracture behaviour of Al?15%Mg2Si composite was investigated. The results showed an increase in mechanical properties with increasing of Be content. The stress?strain curves of samples showed a same category of serrations reflecting non-uniform deformation. Scanning electron microscopy was employed to examine the crack nucleation and fracture model. The results indicate that Al?15%Mg2Si composite shows different behaviours of crack initiation and fracture for samples with and without Be. Differences observed in the fracture behaviour were attributed to microstructural changes as well as morphological aspects of primary Mg2Si particles.

2011-01-01

450

Study of some nuclear reaction interferences in determination of nitrogen content of plant materials by 14-MeV neutron-activation analysis  

Energy Technology Data Exchange (ETDEWEB)

The nitrogen content of 10 medicinal plant species has been determined by fast-neutron activation analysis (FNAA). Correction factors for the effects of the /sup 16/O(p,..cap alpha..)/sup 13/N knock-on proton-induced reaction and the (n,2n) reactions, which produce interfering positron-emitting radionuclides, have also been determined. The total relative interference from the /sup 16/O(p,..cap alpha..)/sup 13/N and (n,2n) reactions of K, Cl, Fe and Br was found to be 5.1 to 32.1% for the plant samples.

1983-05-01

451

Studies on gamma irradiated medicinal plants and spices (1): Myristica argentea, Myristica fragrans, Coriandrum sativum and Foeniculum vulgare  

Energy Technology Data Exchange (ETDEWEB)

Medicinal plants i.e. dried seeds of myristica argentea, myristica fragrans, coriandrum sativum and foeniculum vulgare were stored for 0 and 6 months, with and without gamma irradiation at 5 kGy. No detectable changes were seen in infrared and UV spectra, GLC chromatograms and refraction indices of steam distilled, essential oils from the irradiated medicinal plants. The same results were also obtained from irradiated samples stored for 6 months at ambient conditions. Storage for 6 months caused significant changes in the gas liquid chromatograms and UV spectra of all samples compared to non-stored samples. The moisture content of all samples packed in polyethylene bags seems to be constant after 6 months of storage. No measurable changes were found in the amount of essential oil content caused by irradiation.

1981-10-01

452

Source and profile of paralytic shellfish poisoning toxins in shellfish in Daya Bay, South China Sea  

British Library Electronic Table of Contents (United Kingdom)

Changes in cell density and cyst flux of Alexandrium tamarense, paralytic shellfish poisoning (PSP) toxin contents in shellfishes, and environmental parameters were measured in two stations in Daya Bay, South China Sea from March 2005 to July 2006. Vegetative cells of A. tamarense occurred sporadically; however, they presented abundantly during the winter months. Meanwhile, cyst flux reached its maximum level just following the peak abundance of motile cells. The PSP contents in shellfish were generally low, but higher in winter with the maximum of 14,015 @mg STX equiv./kg. The majority of toxins were found in digestive glands, with a maximum of 66,227 @mg STX equiv./kg. There were significant positive relationships between toxin level and vegetative cell density and cyst flux. This indica...

2011-01-01

453

Research on the preparation of coal water fuel (CWF) from Banko coal, south Sumatera  

Energy Technology Data Exchange (ETDEWEB)

Studies of CWF preparation at laboratory scale have been carried out using the type and amount of additives and coal content as process variables. Other factors such as particle size, time and rate of stirring were kept constant. CWF with 45 wt% of dry solids, heating value of 5,475 BTU/lb, and stable without the evidence of sedimentation for 9 weeks have been obtained using carboxy methyl cellulose (CMC) as the additive. Low coal content and low heating value can be increased by hydrothermal process on the elevated temperature and pressure. By this process, CWF with dry solid of 55 wt% and a heating value of 7,125 BTU/lb could be obtained. 6 refs., 8 figs., 2 tabs.

1994-01-01

454

Relationships of radon diffusion coefficient with saturated hydraulic conductivity, fines content and moisture saturation of radon/infiltration barriers for the UMTRA Project  

Energy Technology Data Exchange (ETDEWEB)

The release of {sup 222}Radon to the atmosphere is controlled by the rate of its gas transport through earthen materials. Of the many soil-related parameters, radon diffusion coefficient is the key parameter that characterizes this transport. We compared the radon diffusion coefficients measured at the laboratories for the UMTRA Project with simple empirical correlations developed by others. The empirical correlations predict the radon diffusion coefficient based on the fraction of moisture saturation and porosity. One of the more recent correlations agrees reasonably well with the measurements. In addition, by using a series of correlation curves, we studied the empirical relationships of the. radon diffusion coefficient with the saturated hydraulic conductivity, the fines content, and the moisture saturation in soil. The results reveal that a reliable determination of the long-term moisture and porosity is essential in the design of an adequate radon barrier with ...

1994-01-24

455

Quality control and evaluation for environmental radiological baseline study of Guangdong Daya Bay nuclear power station  

International Nuclear Information System (INIS)

The main points of quality control methods and technique of environmental radiological baseline study of Guangdong Daya Bay Nuclear Power Station are reported. Results of intercalibration of international and inland laboratories are given. The random chosen samples are checked and compared with two measurement methods. The data obtained in Daya Bay environment are put to the correlation statistics test using the linear regression analysis method between the correlative items such as "4"0K activity by gamma spectrum measurement and potassium content by chemical analysis, total #alpha#(#beta#) activity and nuclide content, as well as environmental gamma radiation dose rate and TLD accumulation dose. The data of Daya Bay environmental radioactivity baseline level show good concordance and reliability.

456

Prediction of drug particle size and content uniformity in low-dose solid dosage forms  

British Library Electronic Table of Contents (United Kingdom)

Drug particle size distribution has a profound impact to the content uniformity in low-dose solid drug products. We derived theoretically the skewness of potency distribution as a function of particle size distribution and target dose. It was demonstrated that both skewness and coefficient of variation diverge simultaneously with inverse square root of the target dose. This scaling relation was observed in recent experiment and was verified by Monte Carlo (MC) simulation, which was employed for the first time to solve for the full potency distribution from a random retrieving model. When tested against the criteria from USP uniformity of dosage units, MC simulation showed a striking anisotropic distribution of the data. This suggests a full-scale consideration of the potency distribu...

2010-01-01

457

Population studies of 16 bovine STR loci for forensic purposes  

British Library Electronic Table of Contents (United Kingdom)

As a consequence of the close integration of cattle into the food chain of humans, forensically relevant cases involving cattle (Bos taurus) DNA analysis are common. However, scientific publications reporting the information content of the commonly used bovine short tandem repeat (STR) loci remains scarce. Population studies were performed for 16 polymorphic STR loci (BM1818, BM1824, BM2113, CSRM60, CSSM66, ETH3, ETH10, ETH225, HAUT27, ILSTS006, INRA023, SPS115, TGLA53, TGLA122, TGLA126, and TGLA227) including 4,162 randomly selected cattle representing 20 distinct breeds. The power of parental exclusion, expected and observed heterozygosity, probability of identity, and non-amplifying (?null?) allele frequencies were calculated. Major differences existed in the information content between...

2011-01-01

458

Plasma ignition and stabilization of combustion of anthracite culm from the Donbass  

Energy Technology Data Exchange (ETDEWEB)

From 1965 to 1980 ash content in anthracite from the Donbass supplied to power plants increased from 21.9 to 35.5%, moisture content increased from 7.6 to 10.1%, calorific value declined from 23.7 to 18.5 MJ/kg. Combustion of anthracite culm is stabilized by mazout combustion. Heat treatment of anthracite culm by means of plasma generators improves fuel quality. High temperature causes emission of volatile matter from anthracite and partial gasification of coke particles. Combustion of volatile matter from anthracite and coke is a reliable ignition method for anthracite culm. It also stabilizes combustion of pulverized anthracite. Heat treatment of about 20% anthracite by plasma generators reduces nitrogen oxide emission from a furnace by 30-40%. 5 refs.

1990-01-01

459

Pitting corrosion of stainless steels; Lochkorrosion an nichtrostenden Staehlen  

Energy Technology Data Exchange (ETDEWEB)

Stainless steels can get pitting corrosion in halide containing solution, which make them a big risk in industrial production. Many investigations were made in the past in order to understand processes involved in pitting corrosion, pit initiation and pit growth. Results about the influence of alloying elements, their contents, the state of the structure, the condition of the surface, the content of chloride, the temperature, the pH-value, the velocity of flow and of the oxidizer on the chloride induced pitting corrosion of passive stainless steels are presented. Electrochemical measurements and the application of surface analytical methods (SEM, SAM, XPS) with high lateral resolution are carried out. A part of the samples received a diffusion annealing in order to obtain reproducible results. Pitting Resistance Equivalents (PRE) - Pitting Index - with different multipliers are given and discussed critical. An electrochemical method for ...

1996-01-01

460

Phase Information and the Evolution of Cosmological Density Perturbations  

CERN Document Server

The Fourier transform of cosmological density perturbations can be represented in terms of amplitudes and phases for each Fourier mode. We investigate the phase evolution of these modes using a mixture of analytical and numerical techniques. Using a toy model of one-dimensional perturbations evolving under the Zel'dovich approximation as an initial motivation, we develop a statistic that quantifies the information content of the distribution of phases. Using numerical simulations beginning with more realistic Gaussian random-phase initial conditions, we show that the information content of the phases grows from zero in the initial conditions, first slowly and then rapidly when structures become non-linear. This growth of phase information can be expressed in terms of an effective entropy: Gaussian initial conditions are a maximum entropy realisation of the initial power spectrum, gravitational evolution decreases the phase entropy. We show that ...

2000-01-01

461

Ozone generation in a negative corona discharge fed with N_2O and O_2  

International Nuclear Information System (INIS)

Ozone production in a negative corona discharge has been studied experimentally at atmospheric pressure in mixtures of N_2O+O_2 at ambient temperature. Ozone formation was found to be dramatically reduced with increase in the content of N_2O in the mixture. The reaction of O("1D) with nitrous oxide is the most likely process reducing the rate of ozone generation. A considerable decrease in the mean discharge current at a constant voltage was also observed with increasing content of nitrous oxide in the mixture and is attributed to the formation of anions in the discharge. The low values of the calculated mobility of negative charge carriers in the drift region of the discharge is caused by the formation of O"- #centre dot# (N_2O)_n and NO"-#centre dot#(N_2O)_n cluster anions in the drift region of the negative corona discharge.

2004-04-07

462

Nuclear magnetic resonance imaging of the abnormal live rat and correlations with tissue characteristics  

Energy Technology Data Exchange (ETDEWEB)

Nuclear magnetic resonance (NMR) images of live rats with sterile and pyogenic abscesses, hematomas, and various implanted and spontaneous neoplasms demonstrated good contrast differentiation between pathologic and surrounding normal tissues. This differentiation was maximal when both the T1 and T2 tissue relaxation times were used as criteria. Neoplasms have a broad range of T1 and T2 values and may be confused with abscesses or hematomas. Tissue rate constants (1/T1 and 1/T2) are mainly dependent on total water content, the exception being fat, which has a 1/T2 value much shorter than that expected on the basis of water content alone.

1981-10-01

463

Nomographs for predicting crown fire initiation in Aleppo pine (Pinus halepensis Mill.) forests  

British Library Electronic Table of Contents (United Kingdom)

Nomographs that calculate the threshold values of surface fire parameters which lead to crown fire initiation were created by linking two separate fire behavior models: Van Wagner?s crown fire ignition criteria and Byram?s surface fire model. The nomographs were also based on the existing surface (fuel load, fuel heat content) and canopy (foliar moisture content, live crown base height) fuel models of Aleppo (Pinus halepensis Mill.) pine forests of Mediterranean Greece. The most important fire parameters for crown fire initiation that are calculated by the nomographs are the critical flame length and the forward spread rate of the surface fire. These parameters are readily observable in the field during fires. The nomographs provide a judicious way to assess whether a crown fire is likely ...

2007-01-01

464

Magnetic resonanse imaging in otorhinolaryngology. With special reference to the influence of factors upon NMR parameters and differential diagnosis of otorhinolaryngic lesions  

Energy Technology Data Exchange (ETDEWEB)

MRI diagnosis for malignant tumors are made possible by direct comparison to the results obtained by the brain and it seems possible to differentiate malignant tumors from other benign lesions. Cystic lesions, and mycotic sinusitis sometimes resemble malignant tumors in MR Image. In the present report, we investigated the relationships between the biochemical contents of cystic lesions and NMR-parameters to clarify why some inflammatory lesions appeared similar to malignant tumors in MRI. The variation of relaxation time depends upon the amount of protein in the cystic contents and the amount of glucose affects the relaxation time. We conclude that NMR-parameters are useful for the differential diagnosis of malignant tumors, cystic lesions and mycositic sinusitis by using the multiple variation analysis.

1987-07-01

465

Laser-processed thin-film transistors fabricated from sputtered amorphous-silicon films  

Energy Technology Data Exchange (ETDEWEB)

Low-temperature polysilicon thin-film transistors (TFT's) have been fabricated from sputtered silicon films and characterized as a function of as-deposited hydrogen (H) content and laser crystallization fluence. A general trend is observed where TFT performance improves as the H content is lowered. Devices made from {approximately}0% H sputtered films perform similar to those made from low-pressure chemical-vapor deposition processes (LPCVD), but are fabricated at a much lower process temperature (300 C). The best sputtered TFT's had mobilities of {approximately}200 cm{sup 2}/Vs, and on/off current ratios of more than 10{sup 8}.

2000-01-01

466

Isoflavone content and apoptotic effect in HT-29 cancer cells of a soy germ extract  

British Library Electronic Table of Contents (United Kingdom)

Colon cancer is one of the leading causes of death and a major public health problem in western countries. We examined the isoflavone content of 70% ethanol extract of soy germ (SG) and its apoptotic effect in HT-29 colon cancer cells. Our results showed that the major isoflavones of the SG extract were daidzein and genistein, and it effectively induced apoptosis in HT-29 cancer cells. In addition, nuclear factor-kappa B (NF-kB) expression was reduced in cells treated with the SG extract, which reduced cyclooxygenase-2 (COX-2) and nitric oxide synthase (iNOS) expression. These combined effects ultimately resulted in apoptosis via caspase-3 activation. In addition, daidzein and genistein, the major isoflavones of SG extract, also exerted the apoptotic effect against HT-29 cancer cells. Thes...

2012-01-01

467

Influence of sodium chloride and sodium sulfate salinities on photosynthetic carbon assimilation in peanut  

International Nuclear Information System (INIS)

The effect of NaCl and Na_2SO_4 treatments on chlorophyll content, rate of "1"4C assimilation and products of photosynthesis in peanut (Arachish hypogaea L.) variety TMV-10 has been investigated. It was observed that chlorophyll content was affected mainly by NaCl, Na_2SO_4 treatment lowered the rate of photosynthetic "1"4CO_2 fixation. The analysis of labelled products revealed that the salts affect the carbon metabolism differently. The radioactivity was found to be accumulated in fractions of sugars and sugarphosphates in the leaves of NaCl treated plants. Na_2SO_4 treatment brought about considerable decline in labelling of sugars and an increase in labelling of amino acids and sugarphosphates. (orig.).

1980-01-01

468

Influence of short carbon fiber content on mechanical and dielectric properties of Cfiber/Si3N4 composites  

British Library Electronic Table of Contents (United Kingdom)

Cfiber/Si3N4 composites were prepared by hot-pressed sintering using a-Si3N4 powders, short carbon fibers and sintering additives as starting materials. The mechanical and dielectric properties of these composites were studied. When the short carbon fiber content of the composites increases from 0 to 1wt.%, the fracture toughness increases from 3.456 to 4.203MPam1/2, and both the real and imaginary part of permittivity increase greatly over the frequency range 8.2-12.4GHz. These effects were due to the anisotropy of short carbon fibers.

2007-01-01

469

Influence of FeSO4 concentration on thermal emissivity of coatings formed on titanium alloy by micro-arc oxidation  

British Library Electronic Table of Contents (United Kingdom)

Ceramic coatings with high emission were fabricated on Ti6Al4V alloy by microarc oxidation (MAO) with additive FeSO4 into the electrolyte. The microstructure, chemical composition and chemical state of the coatings were determined by SEM, XRD, EDS and XPS, respectively. The bonding strength between the coating and substrate was studied by tensile strength test, together with the thermal shock resistance of the coating. The results showed that Fe content in the coating layer significantly affect its thermal emissivity. The relative content of Fe in the coatings surface increased at first and then decreased with increasing the concentration of FeSO4 in electrolytes, so does the emissivity of the coatings. The bonding strength became weaker with increasing the concentration of FeSO4. In addit...

2011-01-01

470

In vitro effects of medium tonicity, nutrient concentration, and free chlorine content on Acanthamoeba  

British Library Electronic Table of Contents (United Kingdom)

Background: The environment preferred by Acanthamoeba trophozoites and the mechanism by which the amebae enters the cornea are not yet fully understood. A better understanding of the pathogenesis of this disease may help with prevention and treatment. Purpose: To define the preferred environments for Acanthamoeba survival and proliferation in vitro by examining the effect of tonicity, nutrient concentration, and free chlorine content on Acanthamoeba. Materials and methods: Human corneal isolates of Acanthamoeba castellanii and Acanthamoeba polyphaga trophozoites were cultured at 22^oC (room temperature) in PYG (peptone-yeast extract-glucose) medium. The effect of tonicity on amebae was determined by incubating trophozoites in sodium chloride solutions in concentrations ranging from 0% to 1...

2011-01-01

471

High resolution gamma-ray spectrometry of culverts containing transuranic waste at the Savannah River Site  

Energy Technology Data Exchange (ETDEWEB)

A number of concrete culverts used to retrievably store drummed, dry, radioactive waste at the Savannah River Site (SRS), were suspected of containing ambiguous quantities of transuranic (TRU) nuclides. These culverts were assayed in place for Pu-239 content using thermal and fast neutron counting techniques. High resolution gamma-ray spectroscopy on 17 culverts, having neutron emission rates several times higher than expected, showed characteristic gamma-ray signatures of neutron emitters other than Pu-239 (e.g., Pu-238, Pu/Be, or Am/Be neutron sources). This study confirmed the Pu-239 content of the culverts with anomalous neutron rates and established limits on the Pu-239 mass in each of the 17 suspect culverts by in-field, non-intrusive gamma-ray measurements.

1990-01-01

472

High resolution gamma-ray spectrometry of culverts containing transuranic waste at the Savannah River Site  

Energy Technology Data Exchange (ETDEWEB)

A number of concrete culverts used to retrievably store drummed, dry, radioactive waste at the Savannah River Site (SRS), were suspected of containing ambiguous quantities of transuranic (TRU) nuclides. These culverts were assayed in place for Pu-239 content using thermal and fast neutron counting techniques. High resolution gamma-ray spectroscopy on 17 culverts, having neutron emission rates several times higher than expected, showed characteristic gamma-ray signatures of neutron emitters other than Pu-239 (e.g., Pu-238, Pu/Be, or Am/Be neutron sources). This study confirmed the Pu-239 content of the culverts with anomalous neutron rates and established limits on the Pu-239 mass in each of the 17 suspect culverts by in-field, non-intrusive gamma-ray measurements.

1990-12-31

473

Growth and gas exchange response to water shortage of a maize crop on different soil types  

British Library Electronic Table of Contents (United Kingdom)

The effect of water shortage on growth and gas exchange of maize grown on sandy soil (SS) and clay soil was studied. The lower soil water content in the SS during vegetative growth stages did not affect plant height, above-ground biomass, and leaf area index (LAI). LAI reduction was observed on the SS during the reproductive stage due to early leaf senescence. Canopy and leaf gas exchanges, measured by eddy correlation technique and by a portable photosynthetic system, respectively, were affected by water stress and a greater reduction in net photosynthetic rate (A N) and stomatal conductance (g s) was observed on SS. Chlorophyll and carotenoids content was not affected by water shortage in either condition. Results support two main conclusions: (1) leaf photosynthetic capacity was unaffec...

2009-01-01

474

Formation conditions, chloride content, and stability of passive films on an iron-chromium alloy  

Energy Technology Data Exchange (ETDEWEB)

Passive films were formed on a high purity Fe-23 Cr alloy in acid sulfate solutions in the presence and absence of chloride ion. The resulting film composition was investigated by Auger depth profiling. The passivated samples were exposed to a 1M NaCl solution at a constant potential slightly above the critical pitting potential, and the current-time transient was measured in order to compare the relative stability of the different films. The results obtained suggest that the formation conditions influence the chloride content of the passive film and the breakdown behavior. Passive films formed in the presence of chloride contain and are slightly less stable towards breakdown. No chloride was found in films formed in sulfate and subsequently exposed to chloride well below the pitting potential.

1993-07-01

475

Flow cytometric analysis of respiratory tract cells exposed to oil shale and silica particulates. [Hamsters  

Science.gov (United States)

Flow cytometric techniques were used to measure the cytological and biochemical damage to respiratory tract cells in animals exposed to particulates. Hamsters were exposed to raw and spent oil shale particulates and silica by intratracheal instillation. Exfoliated lung cells were obtained by sacrificing the animals and lavaging the respiratory tract posterior to the trachea with saline. Cell samples were fixed in ethanol and stained with mithramycin for fluorescence analysis of DNA content. DNA content distributions from hamsters exposed to spent oil shale and silica particulates showed atypical changes 28 to 35 days later. Cell counts and total numbers of macrophages, leukocytes, and epithelial cells in the lavage fluid also showed marked changes related to time after exposure.

1979-01-01

476

Evaluation of quality of alkylsalicylate additives with high content of active substance  

Energy Technology Data Exchange (ETDEWEB)

This article describes the chemical preparation of petroleum additives of the MASK type from samples of concentrated alkylsalicylic acids. The obtained additives contain high contents of calcium alkylsalicylate and respective total alkalinities of 156, 131, and 130 mg KOH/g. Sodium alkylsalicylate concentrates, obtained in the form of an aqueous acetone solution, were converted to alkylsalicylic acids by interaction with hydrochloric acid. The solvent was removed from the upper and lower layers by distillation, and the resulting products were analyzed by liquid chromatography. Service tests were performed on a model formulation of the additive in M-11 oil in a Petter AV-1 test stand unit in comparison with commercial MASK additive. The results indicate that the model additive formulation gives approximately the same corrected piston fouling ratings as the commercial additive.

1984-09-01

477

Evaluation of Chemical Interactions of Maleic Acid with Sodium Hypochlorite and Chlorhexidine Gluconate  

British Library Electronic Table of Contents (United Kingdom)

IntroductionThe elimination of microorganisms from the root canal system necessitates the use of combination of irrigating solutions to enhance their antimicrobial property. The combination of irrigants and their interaction sometimes could be detrimental to the outcome of the root canal therapy. The purposes of this study were (1) to evaluate the interaction between 7% maleic acid (MA) and 2% chlorhexidine gluconate solution (CHX) and to find out the availability of individual irrigant and (2) to determine the free available chlorine content when 7% MA was mixed with 2.5% sodium hypochlorite (NaOCl) solution. MethodsInteraction between MA and CHX was assessed by high-performance liquid chromatography. Available chlorine content in NaOCl was evaluated by the standard iodine/thiosulfate tit...

2011-01-01

478

Estimation of dry rubber content in natural rubber latex by differential scanning calorimetry  

British Library Electronic Table of Contents (United Kingdom)

Differential Scanning Calorimetry (DSC) is employed to study the changes in enthalpy of natural rubber latex samples when heated under a controlled temperature program. It is found that the mass normalized areas of the DSC curves between room temperature and 170??C for different latex samples are inversely proportional to the dry rubber content (DRC) of the samples, measured following the weighing and drying method. The changes in total enthalpy of the samples in this temperature range are interpreted as due to the variations in the quantity of water present in the samples. The measurements have been repeated by diluting selected samples with known quantities of water, and it is found that the normalized areas of the DSC curves are directly proportional to the amount of water added to the ...

2010-01-01

479

Effects of pork/beef levels and various casings on quality properties of semi-dried jerky  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to investigate the effects of pork/beef levels and the casings on the quality properties of semi-dried jerky. The pork/beef levels in the four test formulations were as follows: T-1 (pork: beef=100:0), T-2 (95:5), T-3 (90:10), and T-4 (80:20). After tumbling for 30min with curing solution, the cured meats were stuffed into natural sheep casings, collagen casings, or cellulose casings, and then dried. The restructured jerky with cellulose casing had the lowest water content and the highest protein content, with no significant differences between various formulations. There were no significant differences among all formulations with regard to pH and total microbial counts, and jerky with cellulose casing had the lowest value of water activity. The processing yields ...

2008-01-01

480

Effects of manganese doping on properties of sol-gel derived biphasic calcium phosphate ceramics  

British Library Electronic Table of Contents (United Kingdom)

We have investigated the effect of manganese (Mn) doping on properties of nanosized biphasic calcium phosphate powders and their dense bodies. Manganese levels of 0.6, 1.3, 1.9, 4.3, 7.0 and 11.9at.% were successfully incorporated into biphasic calcium phosphate via a sol-gel route. The prepared powders were calcined at temperatures of 500-1200^oC. The X-ray diffraction analysis revealed that a mix phase comprising of hydroxyapatite and @b-tricalcium phosphate were present, however the content of each phases in the structure was affected by the Mn content. The studies found that the largest portion of @b-tricalcium phosphate was detected at 4.3at.% Mn doping. The incorporation of Mn has also greatly increased the crystallinity of the biphasic calcium phosphate powder due to progressive den...

2011-01-01

481

Effect of organoclay on the mechanical/thermal properties of microcellular injection molded PBT-clay nanocomposites  

British Library Electronic Table of Contents (United Kingdom)

An organically modified montmorillonite (MMT) was compounded with polybutylene terephthalate (PBT) in a twin-screw extruder. The organoclay PBT nanocomposites were then injection molded by conventional and microcellular methods. Nitrogen was used as the blowing agent. The effect of organoclay content, organoclay size (8 and 35mm), and speed of the screw (80 and 100rpm) on the mechanical and thermal properties were investigated. The results showed that when the MMT content was 1.0wt.%, the nanocomposites have maximum tensile strength, wear resistance, and cell density. Moreover, the larger the particle size, the greater the tensile strength. The screw speed during compounding also affected the mechanical strength. The higher speed of the screw increased the tensile strength of the nanocompo...

2010-01-01

482

Effect of gamma radiation on chlorophylls contents, net photosynthesis and respiration of chlorella pyrenoidosa  

International Nuclear Information System (INIS)

The effect of five doses of gamma radiation: 10, 100, 500, 1000 and 5000 Gy on chlorophylls content, net photosynthesis and respiration of chlorella pyrenoidosa has been studied. A decrease in chlorophylls levels is produced after irradiation at 500, 1000 and 5000 Gy, being, at first 'b' chlorophyll affected to a greater extent than 'a' chlorophyll. Net photosynthesis and respiration decline throughout the time of the observations after irradiation, this depressing effect being much more remarkable for the first one. Net photosynthesis inhibition levels of about 30% have got only five hours post irradiation at a dose of 5000 Gy. (author).

483

Effect of chemical composition on the structure and mechanical properties of Mn-Al-C alloys in the magnetic region  

Energy Technology Data Exchange (ETDEWEB)

The thermal stability and deformability of Mn-Al-C alloys containing 0.6 pct C are investigated experimentally as a function of excess phase content. It is shown that an increase in Mn content from 68.9 to 73.5 pct leads to increased stability of the high-temperature epsilon phase. The enrichment of the system Mn-Al-Cu in Mn and Al above the optimum composition leads to the formation of nonmagnetic excess phases, eta and beta, which reduce the magnetization of the alloy. In addition, a decrease in thermal stability is observed in the alloy with 73.5 pct Mn due to the decomposition of the ferromagnetic phase. 7 references.

1988-01-01

484

Effect of alloying elements on intergranular corrosion susceptibility of Mo contained austenitic stainless steel in nitric acid solution  

International Nuclear Information System (INIS)

In this study, effects of alloying elements such as Mo, Cr and Ni on intergranular corrosion (IGC) resistance of Mo contained austenitic stainless steels in boiling 65% nitric acid solution (Huey Test) were studied. Obtained results are as follows; (1) Mo deteriorates IGC resistance of austenitic stainless steel in Huey test due to enhance precipitation of Laves ((Fe, Cr)_2Mo) phase at grain boundary. (2) Cr improves IGC resistance of Mo contained austenitic stainless steel in Huey test, which is considered to reduce dissolution rate of Laves phase into nitric acid solution by increasing Cr content in Laves phase as increasing Cr content of stainless steel. (3) Ni suppresses occurrence of IGC of Mo contained austenitic stainless steel in Huey test. (author).

1995-01-01

485

Development of thick layer re-wetting model for brown rice packaged with LDPE and PBT films  

British Library Electronic Table of Contents (United Kingdom)

A mathematical model was developed to predict a moisture content profile during the thick layer re-wetting process of brown rice unpackaged and packaged with low density polyethylene (LDPE) and polybutylene terephthalate (PBT) films. Model validation was carried out by comparing predicted with measured moisture content derived from relative humidity data obtained from the brown rice re-wetting test for 6days at 25degreeC and 90% RH. The moisture standard errors of the model validation for brown rice packaged in LDPE and PBT films were 0.08% wet basis (wb) and 0.11%wb, respectively. It was concluded that the proposed re-wetting model could successfully describe the thick layer re-wetting of brown rice under the experimental conditions. Using this model, re-wetting simulations were carried o...

2010-01-01

486

Desulphurisation of fumes as a potential source of prime materials  

Energy Technology Data Exchange (ETDEWEB)

A survey is given by the authors of methods of removing the sulphur dioxide content of fumes which can be linked together with producing useful final products. From these technologies those suppling well utilizable gypsum, the Walther process, producing ammonium sulphate, the Wellman-Lord and Bergbau-Forschung processes, respectively adapted to produce sulphuric acid or sulphur, may be of interest. Also in the method of fumes desulphurisation by catalysis by manganese, developed in KBFI, utilizable final products are given. Background of the work of developing this method. Detailed description of the manganese catalytic method based on the use of a red mud desulphurizing agent. By this process, in addition to desulphurizing fumes, enriched red mud with reduced Na/sub 2/O content is produced, which as an iron carrier, is to be reckoned with, or to be used in the cement industry for replacing imported calcined pyrites.

1986-01-01

487

Comparative studies on the characterization and antioxidant properties of biodegradable alginate films containing ginseng extract  

British Library Electronic Table of Contents (United Kingdom)

The physical and antioxidant properties of alginate biodegradable film incorporating white, red and extruded white ginseng extracts were investigated. No differences in moisture contents of all alginate film samples were noticeable (p>0.05) except those film samples incorporated without ginseng extract, which had the highest moisture content. The addition of ginseng extract to alginate film decreased tensile strength and elastic modulus (p<0.05) but increased the percent elongation at break. The presence of extracts did not significantly affect the water vapor permeability of the film samples. Alginate film containing extruded white ginseng extract at a barrel temperature of 130degreeC presented the highest (61.12%) free-radical scavenging activity against the 2,2-diphenyl-1-picryhydrazyl ...

2010-01-01

488

Characterization of Y2BaCuO5 nanoparticles synthesized by nano-emulsion method  

British Library Electronic Table of Contents (United Kingdom)

Nanoscale yttrium?barium?copper oxide (Y2BaCuO5, Y211) particles were synthesized using the emulsion method and the solution method. The basic water-in-oil (w/o) emulsion system consisted of n-octane (continuous oil phase), cetyltrimethylammonium bromide (cationic surfactant), butanol (cosurfactant) and water. The composition of the emulsion system was varied and characterized by measuring the conductivity of the solutions and droplet size. The droplet size of emulsion was determined by using the dynamic light scattering method. The water content, cosurfactant content, and surfactant/n-octane ratio affected the droplet size which was in the range of 3?8?nm, and hence the w/o emulsion system was referred to as a nano-emulsion system. A model was used to verify the droplet size. The influenc...

2007-01-01

489

Changes in the soils of solonetzic associations in 30 years after their reclamation with the use of moldboard plowing, deep tillage with a three-tier plow, and deep rotary tillage  

British Library Electronic Table of Contents (United Kingdom)

Changes in the properties of solonetzic soil associations (chestnut solonetzic soils and chestnut solonetzes) in the dry steppe after their reclamation have been studied for 30 years. The reclamation included the deep three-tier plowing and the approach of rotary tillage. A single rotary tillage operation resulted in the formation of fine aggregates of equal sizes in the plow layer; any morphological features of the restoration of solonetzic pedogenesis are absent. The atmospheric moisture easily penetrates into the soil, and soluble salts are leached off to a great depth. In 30 years since the soil amelioration with the use of a PMS-70 rotary tiller, the humus content has increased up to 3.3% in the upper 20-cm-thick layer and up to 2.4% in the layer of 20?40 cm. The content of adsorbed N...

2011-01-01

490

Behavior of radioactive elements (uranium and thorium) in Bayer process  

International Nuclear Information System (INIS)

It is essential that alumina used for manufacturing electronic devices should contain an extremely low level of alpha-radiation. The principal source of alpha-radiation in alumina is uranium, a minor source being thorium. Uranium in bauxite dissolves into the liquor in the digestion process and is fixed to the red mud as the desilication reaction progresses. A part of uranium remaining in the liquor precipitates together with aluminum hydroxide in the precipitation process. The uranium content of aluminum hydroxide becomes lower as the precipitation velocity per unit surface area of the seed becomes slower. Organic matters in the Bayer liquor has an extremely significant impact on the uranium content of aluminum hydroxide. Aluminum hydroxide free of uranium is obtainable from the liquor that does not contain organic matters.

491

Australia's Latrobe Valley brown coal fields  

Energy Technology Data Exchange (ETDEWEB)

Brown coal resources of the Latrobe Valley in Australia total 140 billion tons to a depth of 975 feet, while economically recoverable reserves have been calculated to total 57 billion tons. Although the coal provides only a very low heating value, about 3300 Btu/lb with 60% moisture content, the enormous seam thicknesses with little overburden allow large scale, open cut mining operations. The low cost and high reactivity of the coal is attracting extensive coal liquefaction research. Research into dewatering processes for the high moisture content brown coal is being conducted. The dried brown coal could be used both domestically and internationally for electricity generation and as an industrial fuel.

1984-02-01

492

Asymmetry effect of particle size distribution on content uniformity and over-potency risk in low-dose solid drugs  

British Library Electronic Table of Contents (United Kingdom)

Most active pharmaceutical ingredients (API) exhibit particle size distributions with some degrees of asymmetry deviating from log-normality. A new log-skew-normal (L-S-N) distribution model is proposed for a systematic comparison of the asymmetry effect on content uniformity. The new model originated from the S-N model used by Azzalini gives a close approximation to real API particle size distribution. Monte-Carlo method was employed to simulate the dosage potency distribution. A high risk of over potency is uncovered when either the dose is low or API particle size distribution is positively skewed. This is due to the formation of pseudo heavy tail in potency distribution that decays slower than exponentially. Nomographs of API particle size versus dosage strength were constructed with a...

2010-01-01

493

Association between chemical and genetic variation in Calophyllum inophyllum, a medicinally important tree of the Western Ghats of India  

British Library Electronic Table of Contents (United Kingdom)

The objective of the present work is to study the chemical variation in Calophyllum inophyllum growing along the Western Ghats of India. Contents of dipyranocoumarins (inophyllums) in C.?inophyllum were determined to assess whether they could be used as a taxonomic marker for C.?inophyllum. This study also aims to establish inter simple sequence repeat (ISSR) markers that can be used to study genetic variation within the species and explore correlation between ISSR and chemical markers. The contents of dipyranocoumarins were estimated in seeds collected from 20 locations. Leaves from plants at the same 20 locations were assayed for ISSR variation. A dendrogram based on Nei?s genetic distance as well as principal component analysis based on dipyranocoumarins and ISSR variation clustered pla...

2011-01-01

494

Analysis and assay of flavonoid content in the vegetative and reproductive organs of the showy tick trefoil  

British Library Electronic Table of Contents (United Kingdom)

We report here a many-year study of the qualitative and quantitative content of flavonoids in the reproductive organs of the showy tick trefoil (Desmodium canadense (L.) DC., Fabaceae) - stems, leaves, buds, inflorescences,pods, and seeds - collected at different phases of growth at the Department of Medicinal Plants, Kaunas Botanical Garden, Vytautas Magnus University. HPLC studies identified 15 aglycone and glycoside flavonoids: apigenin, apigenin-7-O-glycoside, luteolin, rutin, vicenin-2, vitexin, isovitexin, vitexin rhamnoside, orientin, homoorientin, quercetrin, quercetin, hyperoside, astralagin, and kaempferol. The largest quantities of flavonoids in the vegetative organs from year 2 to year 4 of plant growth were present in the leaves (2.64% and 2.61% at budding and flowering in the...

2011-01-01

495

Active biomonitoring of heavy metal pollution using Rosa rugosa plants  

British Library Electronic Table of Contents (United Kingdom)

The purpose of this work was to evaluate the quality of a rural area near Faenza (Italy) by using an active biomonitoring approach, i.e., by placing homogeneous individuals of the perennial shrub Rosa rugosa in different sites throughout the area. Further sites, within the city or its environs, were used for comparison. Soil and leaves of R. rugosa were analyzed for their heavy metal content. The total heavy metal pattern of leaves closely paralleled the pattern registered in soil, with the highest content (both in total and assimilable forms) at the site in the urban area, which is exposed to heavy traffic. Pollen quality (abortiveness and viability) was also tested as a potential indicator of pollution. Pollen abortiveness was strictly related to Pb levels in leaves, while viability was ...

2007-01-01

496

A study on the preparation of wood-polymer composites with recycled PE films  

Energy Technology Data Exchange (ETDEWEB)

Wood-Polymer Composites (WPC) was prepared from recycled films of agricultural use and wood wastes, and LLDPE and neat PE resin mixture were also utilized in order to compare the properties. Maleic anhydride (MA) and dicumyl peroxide were used as an adhesion promoter and an initiator, respectively. Tensile properties of WPC were measured via tensile test as a function of wood filler and MA content, and fracture surface was also investigated with SEM. As the content of wood filler increased, elongation decreased but modulus increased. However, tensile strength of WPC increased only when MA was used, and 1 wt.% of MA may be high enough to increase the tensile properties. The tensile properties of WPC prepared from recycled PE films were almost same as those of neat PE resin mixture. (author). 18 refs., 5 figs.

1999-10-31

497

A digitization and multimedia project at Quinnipiac University, Hamden, Connecticut, USA  

British Library Electronic Table of Contents (United Kingdom)

Purpose - The purpose of this paper is to encourage other libraries to provide access to their own original content via the web. By way of case study, the process of identifying materials, scanning them and creating web access to original content will be explored. Design/methodology/approach - To implement a book digitization project, three major things need to be present. The library must own material that was published prior to 1923, making them safely out of copyright in the USA; the library needs access to server space on the web and the library needs to own scanning equipment. Findings - This project demonstrated that a library does not necessarily need to obtain grant funding to begin an effective and successful digitization program. It also revealed a few things that would improve t...

2007-01-01

498

A 1500-year record of lead, copper, arsenic, cadmium, zinc level in Antarctic seal hairs and sediments  

British Library Electronic Table of Contents (United Kingdom)

To reconstruct the profiles of heavy metal levels in the South Ocean ecosystem of Antarctica, the concentrations of lead (Pb), copper (Cu), arsenic (As), cadmium (Cd), and zinc (Zn) in seal hairs and lake sediments spanning the past 1500?years from Fildes Peninsula of King George Island and in weathering lake sediments from Nelson Island of West Antarctica were determined. The lead contents in the seal hairs and the weathering sediments show a sharp increase since the late 1800s, very likely due to anthropogenic contamination from modern industries. After the 1980s, the Pb content in seal hairs dropped by one-third, apparently due to the reduced usage of leaded gasoline in the Southern Hemisphere. Copper arises mainly from the weathering process, and its level may be substantially affected...

2006-01-01