WorldWideScience
1

'Sheltered disruption' of Neurospora crassa MOM22, an essential component of the mitochondrial protein import complex.  

UK PubMed Central (United Kingdom)

MOM22 is a component of the protein import complex of the mitochondrial outer membrane of Neurospora crassa. Using the newly developed procedure of 'sheltered disruption', we created a heterokaryotic...Full Text Available

1995-03-15

2

Aluminium, gallium and indium complexing with methylthymol blue  

International Nuclear Information System (INIS)

Al, Ga and In complexing with methylthymol blue (H_6R) purified by gel filtration is studied. in the case of metal excess complexes with the ratio of components M:H_6R=2:1 with #lambda#=587(Al), 590(Ga) and 593 nm(In) appear. In the case of reacting agent excess complexes with the ratio of component 1:1 with #lambda#_m_a_x=480-490 (Al) and 480 nm(Ga, In) appear. The mechanism of complexing reactions is studied. Molar extinction coefficients and stability constants are calculated.

1988-01-01

3

SIRT1 contributes to telomere maintenance and augments global homologous recombination  

UK PubMed Central (United Kingdom)

Yeast Sir2 deacetylase is a component of the silent information regulator (SIR) complex encompassing Sir2/Sir3/Sir4. Sir2 is recruited to telomeres through Rap1, and this complex spreads into subtelomeric...Full Text Available

2010-12-27

4

Influence of major histocompatibility complex genotype on mating success in a free-ranging reptile population  

UK PubMed Central (United Kingdom)

Major histocompatibility complex (MHC) genes are highly polymorphic components of the vertebrate immune system, which play a key role in pathogen resistance. MHC genes may also function as odour-related...Full Text Available

2009-05-07

5

Identification of Contractile Vacuole Proteins in Trypanosoma cruzi  

UK PubMed Central (United Kingdom)

Contractile vacuole complexes are critical components of cell volume regulation and have been shown to have other functional roles in several free-living protists....Full Text Available

6

Testing modern protective relays  

Energy Technology Data Exchange (ETDEWEB)

Modern microprocessor-based relays for the protection of the various power system components such as generators, transformers, feeders, and high voltage transmission lines are becoming more sophisticated as increasingly more complex functions and capabilities can be included in the microprocessor. With this increasing complexity, and the increasing complexity of the power system itself, there is even more value in testing the suitability of relaying equipment for the intended applications. This paper reviews the testing philosophy, experience, and capabilities developed at Ontario Hydro over more than 25 years of testing protective relays.

1994-01-01

7

Fuzzy risk analysis for safeguards and network security  

Science.gov (United States)

Analyzing the risk of a safeguards system, in particular the security of a computer network based on the notion of fuzzy sets and linguistic variables, addresses concerns such as complexity and inherent imprecision in estimating the possibility of loss or compromise. Automated risk analysis allows the risk to be determined for an entire system based on estimates for lowest level components and the component weight. In addition, for each component (asset) we select the most effective combination of protection mechanisms against a given set of threats.

1992-01-01

8

Relating Complex Fluid Composition and Thermophysical Properties with the Advanced Distillation Curve Approach  

British Library Electronic Table of Contents (United Kingdom)

Complex fluids have long posed a significant challenge in our ability to characterize and model fluid properties. Here, we consider complex fluids to be mixtures with many components that can differ significantly in polarity and polarizability. The penultimate complex fluid is crude oil, although many other fluids such as finished fuels are also highly complex. We have recently introduced a measurement strategy that can simplify these efforts and provides the added potential of linking chemical composition (i.e. analytical) information with physical property information. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic and transport properties for such complex heterogeneous streams. The technique is based on the advanced distillation cu...

2010-01-01

9

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids  

British Library Electronic Table of Contents (United Kingdom)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, wh...

2010-01-01

10

Regional assessment of ambient volatile organic compounds from biopharmaceutical R&D complex  

British Library Electronic Table of Contents (United Kingdom)

Biopharmaceutical R&D complexes are major emission sources of volatile organic compounds (VOCs), which may pose potential health risks for staff on site and residents nearby. In this paper health risk assessments were performed for the VOCs in the ambient air of a typical biopharmaceutical R&D complex in China. Results showed halogenated and alkyl compounds were dominant components among 24 major VOCs from 9 selected sampling sites, inside or around the complex. The principal component analysis (PCA) indicated VOCs were generated predominantly from the biopharmaceutical research activities (factor 1 (F1), 71.6%) and traffic vehicles (factor 2 (F2), 15.4%), which were confirmed by contour maps of five selected VOCs (benzene, toluene, chlorobenzene, methylene chloride and n-hexane) simulated...

2011-01-01

11

Pharmacokinetics of ceftriaxone during plasma exchange in polyarteritis nodosa patients.  

UK PubMed Central (United Kingdom)

Plasma exchange (PE) is currently being used to treat a variety of disorders involving immune complexes, such as polyarteritis nodosa. This procedure removes endogenous toxic components that accumulate...Full Text Available

1994-07-01

12

Pathophysiological, Genetic and Gene Expression Features of a Novel Rodent Model of the Cardio-Metabolic Syndrome  

UK PubMed Central (United Kingdom)

BackgroundComplex etiology and pathogenesis of pathophysiological components of the cardio-metabolic syndrome have been demonstrated in humans and animal models.Methodology/Principal...Full Text Available

13

Orp1, a member of the Cdc18/Cdc6 family of S-phase regulators, is homologous to a component of the origin recognition complex.  

UK PubMed Central (United Kingdom)

cdc18+ of Schizosaccharomyces pombe is a periodically expressed gene that is required for entry into S phase and for the coordination of S phase with mitosis. cdc18+ is related to the Saccharomyces...Full Text Available

1995-12-19

14

Molecular Identification and Expression Analysis of Filaggrin-2, a Member of the S100 Fused-Type Protein Family  

UK PubMed Central (United Kingdom)

Genes of the S100 fused-type protein (SFTP) family are clustered within the epidermal differentiation complex and encode essential components that maintain epithelial homeostasis and barrier functions....Full Text Available

15

Dissecting the Genetic Components of Adaptation of Escherichia coli to the Mouse Gut  

UK PubMed Central (United Kingdom)

While pleiotropic adaptive mutations are thought to be central for evolution, little is known on the downstream molecular effects allowing adaptation to complex ecologically relevant environments. Here...Full Text Available

2008-01-01

16

Deficiency of circadian protein CLOCK reduces lifespan and increases age-related cataract development in mice  

UK PubMed Central (United Kingdom)

Circadian clock is implicated in the regulation of aging. The transcription factor CLOCK, a core component of the circadian system, operates in complex with another circadian clock protein BMAL1. Recently...Full Text Available

17

Southern receiver system: Environmental impact assessment status report: Conawapa to Winnipeg Power Transmission Complex  

Energy Technology Data Exchange (ETDEWEB)

The Conawapa-Winnipeg Power Transmission Complex includes five interrelated transmission and conversion facilities. This booklet describes work done on the upgrade of the southern receiver system, one component of the complex. The southern receiver system is composed of a network of high voltage transmission lines and station facilities. The booklet includes a description of the upgrade, the project setting, short and long-term effects and impact management, and the next steps to be taken in the process, including the regulatory process and public consultation.

1992-01-01

18

Optical measurement of electron bunching in vacuum  

International Nuclear Information System (INIS)

We report the homodyne detection of phase modulation sidebands induced on a laser beam by a coherently bunched electron beam. This provides a sensitive and nonperturbing measurement of complex Fourier time series components of the electron density. A proof-of-principle measurement of the microwave frequency component of electron density in a crossed-field device, which agrees well with a calculation of the same quantity, is reported.

19

Major steam turbine losses. Causes, repair measures, recommissioning; Grossschaeden an Dampfturbosaetzen. Ursachen, Reparaturen, Weiterbetrieb  

Energy Technology Data Exchange (ETDEWEB)

Substantial damages at main components of steam turbines do not have to result inevitably in an exchange of the components concerned. Rather a preliminary or final repair is possible which also considers the cause of the damage. An important condition with the technically complex questions is an appropriate qualification and experience of all involved persons. The common task of operators, manufacturers and insurance companies is to preserve the balance from costs, expenditure of time and risk.

2010-07-01

20

Sulfonaphtholazoresorcinol as reagent for tungsten  

International Nuclear Information System (INIS)

Interaction of W(6) with sulphonaphtholazoresorcinol (SNAR) in aqueous solution has been studied. Tungsten is determined in the form of sulphonaphtholazoresorcinate by extraction with higher alcohols. The optimum conditions for the formation of a complex of W with SNAR in aqueous solution are as follows: a 10-fold excess of SNAR, concentration of HCl 1-1.5N, ethanol content 5-10 vol.%, time of formation of the complex 30 min. A component ratio for the complex has been established in the case of aqueous solution and extract; molar extinction coefficients are 0.9x10"4 and 1.7x10"4, respectively. The formation constant for the complex being extracted is 2.2x10"2"3. A method has been developed for determination of microgram quantities of W in a vanadium specimen.

1977-01-01

21

Study of praseodymium complexing with ethylenediaminetetraacetic acid by proton magnetic resonance  

Energy Technology Data Exchange (ETDEWEB)

The method of proton magnetic resonance (PMR) has been used to study the mechanism of reaction of complexing of paramagnetic Pr/sup 3 +/ ion with ethylenediaminetetra acetic acid (EDTA). The influence of medium acidity (pH5-12), EDTA/Pr ratio varying from 1 to 50, Pr/sup 3 +/ ion concentration (from 5x10/sup -3/ to 3x10/sup -1/ g-ion/l) and temperature (8-98 deg C) on chemical shifts and broadening of signals of EDTA molecule protons is investigated. Data on ratio of components, coordination and stability of forming complexes are obtained. The existence of two types of complexes with the Pr/EDTA ratio equal to 1:1 and 1:2 has been found. Equimolecular complex (1:1) is stable all over the studied temperature interval in contrast to the complex 1:2 for which at 50 deg C fast extrasphere exchange (Pr EDTA)EDTA * + EDTA/sup 0/ reversible (PrEDTA)EDTA/sup 0/ + EDTA * ...

1983-05-01

22

Extraction of copper-, nickel-, zinc- and cadmium complexes with 4-(2-pyridilazo)-resorcin and 2-aminopyridine  

International Nuclear Information System (INIS)

Extraction of copper-, nickel-, zinc- and cadmium complexes with 4-(2 pyridilazo)-resorcin (PAR) is studied in the presence of 2-aminopyridine (Am). Maximum optical densities of the extracts are attained at pH=7.5-8.0; 6.0-7.0; 6.5-7.0 and 7.0-8.0, respectively. The ratio of components in the complexes extractable by chloroform was defined by the method of isomolar series and equilibrium shift. It is established that nickel and copper are extracted to the organic phase as the NiAm(PAR)_2 and CuAmPAR complexes, and, in the case of zinc and cadmium, complexes of different composition are extracted, for example Zn(Am)_2PAR and ZnAm(PAR)_2. The light absorption spectra are studied and molar extinction coefficients of complex extracts are determined at lambdasub(max). It is shown that the general low of light absorption is observed within a sufficiently wide range of ...

1984-01-01

23

Applications of cathodic protection for the protection of aqueous and soil corrosion of power plant components  

International Nuclear Information System (INIS)

Power plant components exposed to environments such as water and soil are susceptible to severe corrosion. Many times the effect of corrosion in power plant components can be catastrophic. The problem is aggravated for underground pipelines due to additional factors such as large network of pipelines, proximity to earth mat, high voltage transmission lines, corrosive chemicals, inadequate approach etc. Other components such as condenser water boxes, internals of pipelines, clarifier bridge structures, cooling water inlet gates and pipes etc. which are in continuous contact with water, are subjected to severe corrosion. The nature and locations of all such components are at places which are not accessible for routine maintenance and hence they require long term reliable protection against corrosion. Experience has shown that anti-corrosive coatings are inadequate in preventing corrosion and due to their ...

1999-11-22

24

Ultrafast fluorescence dynamics of Sybr Green I/DNA complexes  

British Library Electronic Table of Contents (United Kingdom)

The ultrafast dynamics of the DNA fluorescent dye Sybr Green I (SG) has been studied in buffer, single-stranded (ssDNA), double-stranded (dsDNA) and triple-stranded DNA (tsDNA). The fluorescence quantum yield of SG increases dramatically when bound to DNA (including tsDNA). The fluorescence dynamics of the free SG has shown two decay components with 0.15-0.4ps and 1.3-2.1ps time constants, depending on the fluorescence wavelength. Upon binding to DNA, the dynamics becomes slower exhibiting four decay components. This is mainly due to the restriction of the internal motions of the dye caused by the relatively rigid environment of the dye complexed with DNA.

2010-01-01

25

Model for risk and reliability analysis of complex production systems: Application to FPSO/flow-Riser system  

British Library Electronic Table of Contents (United Kingdom)

A model for risk and reliability analysis of complex multifunctional production process systems is presented. The model employs Monte-Carlo and Markov Chain algorithms that uses a weighted index to train and simulate the fuzzy hazard data sets which represents failure outcomes of risk component transient and non-transient systems. Early simulation results shows that hazard rates and the risk of containment loss from typical floating production and storage offloading (FPSO)-Riser system for the risk components in parallel or series increases exponentially with time and decreases as safety ratings fraction increases. The reliability value decreases with time and safety fraction (SFAC) for all fuzzy hazard classifications. The results of the computed mean time before repair (MTBR) show that t...

2009-01-01

26

Determination of rare earths in eluates after chromatographic separation  

International Nuclear Information System (INIS)

Spectrophotometry was used to study the conditions under which three-component complexes are formed of rare-earth elements (REE) with aminopolycarboxylic complexes and #beta#-diketones; the molar extinction coefficients of the above REE complexes were also found. A procedure is suggested for determining REE in chromatographic eluates with lower boundary of the contents determined being at 0.6-1.5 #mu#g/ml (Pr, Nd, Ho and Er) and 5-7 #mu#g/ml (Sm and Tm) with account for oxides. Luminescent techniques were also suggested for determining terbium in the presence of EDTA and terbium in an eluate containing EDTA and oxyethyl ethylene diamine triacetic acid, both acids being characterized by a relative standard deviation equal to 0.015-0.03.

1977-01-01

27

Research activities of MPA, Stuttgart University, for enhanced safety and reliability of components under complex load; Forschungsaktivitaeten der MPA Universitaet Stuttgart zu Erhoehung der Sicherheit und Zuverlaessigkeit komplex beanspruchter Bauteile  

Energy Technology Data Exchange (ETDEWEB)

MPA research activities focus on fracture prevention and on the development of a generally applicable method of component integrity testing which, independent of the safety relevance of the components involved, is also part of ageing management. (orig.) [German] Die Forschungsaktivitaeten an der MPA im Hinblick auf die Erhoehung der Sicherheit und Zuverlaessigkeit komplex beanspruchter Bauteile orientieren sich an den Grundgedanken des Basissicherheitskonzepts (Prinzip des Bruchausschlusses). Zielsetzung war dabei die Entwicklung eines allgemein anwendbaren Nachweisverfahrens zur Komponentenintegritaet, das, abhaengig von der sicherheitstechnischen Relevanz der zu betrachtenden Komponenten, auch Bestandteil des Alterungsmanagements ist. (orig.)

2004-07-01

28

Power fluidics and the environment  

International Nuclear Information System (INIS)

This paper reviews power fluidics technology in the nuclear industry giving emphasis also on its potential uses in chemical plants and in flood and irrigation control. This is a technology of controlling process fluids by purely hydrodynamic methods, which should increase system reliability by eliminating valves, pumps and other fluid control devices that are often causes of failure. This review indicates that the hydrodynamics of fluidic components are not satisfactorily understood at present and may be more complex than similar theory in electronics.

29

Multi-disciplinary - EA BOOKS  

Wastenet

... Quenching is one of the most fundamentally complex processes in the heat treatment of metals, and it is something on which mechanical properties and distortion of engineering components depend. AU$236.36 ex-GST Terms and Conditions Eyes on the Skies: 400... Adopted as the official book of the International Year of Astronomy (IYA) 2009, this stunningly illustrated history of telescopic discovery spans the range ...

30

Mapping of TH1 helper T-cell epitopes on major secreted mycobacterial antigen 85A in mice infected with live Mycobacterium bovis BCG.  

UK PubMed Central (United Kingdom)

TH1 cytokine secretion was examined in response to synthetic peptides of the 85A component of the major secreted, fibronectin-binding antigen 85 complex from Mycobacterium tuberculosis in seven different...Full Text Available

1994-02-01

31

Improved understanding of atmospheric organic aerosols via innovations in soft ionization aerosol mass spectrometry.  

Science.gov (United States)

Organic molecules are a significant and highly varied component of atmospheric aerosols. Measurement of aerosol composition and improvements in our understanding of the complex chemistry involved in their formation and aging are being aided by innovations in soft ionization aerosol MS. (To listen to a podcast about this feature, please go to the Analytical Chemistry multimedia page at pubs.acs.org/page/ancham/audio/index.html.). PMID:21275431

2011-01-24

32

Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions  

Energy Technology Data Exchange (ETDEWEB)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, ...

2010-01-11

33

In situ isotopic analyses of U and Pb in zircon by remotely operated SHRIMP II, and Hf by LA-ICP-MS: an example of dating and genetic evolution of zircon by 176Hf/177Hf from the Ita Quarry in the Atuba Complex, SE, Brazil  

International Nuclear Information System (INIS)

Remotely-operated SHRIMP dating of zircon is an interesting alternative for dating of zircon crystals. Although it does not represent any technical progress of the geochronological method using the U-Pb system in zircon it is a very useful and cheap facility. The procedure was first used for mass spectrometric analyses involving two international laboratories in Sao Paulo, Brazil and Beijing, China. It was applied to samples of three gneiss-migmatitic rocks from the Ita quarry in the Atuba Complex (located between the Luis Alves and the Apiai Domain) to test previous controversial hypotheses about its evolution. The presence of important archaean and paleo proterozoic components in the complex is confirmed by analyses of zircon found in probably neo proterozoic leucosomes. Diorite intrusion also occurred during the neo proterozoic, associated with the 0.6Ga continental collisions involved in the assembly of Gondwana. The ...

2009-10-01

34

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids.  

Science.gov (United States)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are ...

2009-11-17

35

The multidrug resistance efflux complex, EmrAB from Escherichia coli forms a dimer in vitro  

International Nuclear Information System (INIS)

Tripartite efflux systems are responsible for the export of toxins across both the inner and outer membranes of Gram negative bacteria. Previous work has indicated that EmrAB-TolC from Escherichia coli is such a tripartite system, comprised of EmrB an MFS transporter, EmrA, a membrane fusion protein and TolC, an outer membrane channel. The whole complex is predicted to form a continuous channel allowing direct export from the cytoplasm to the exterior of the cell. Little is known, however, about the interactions between the individual components of this system. Reconstitution of EmrA + EmrB resulted in co-elution of the two proteins from a gel filtration column indicating formation of the EmrAB complex. Electron microscopic single particle analysis of the reconstituted EmrAB complex revealed the presence of particles approximately 240 x 140 A, likely to correspond to two EmrAB dimers in a back-to-back ...

2009-03-06

36

Thermal-hydraulic limitations on water-cooled fusion reactor components  

Energy Technology Data Exchange (ETDEWEB)

An assessment of the cooling requirements for fusion reactor components, such as the first wall and limiter/divertor, was carried out using pressurized water as the coolant. In order to establish the coolant operating conditions, a survey of the literature on departure from nucleate boiling, critical heat flux, asymmetrical heating and heat transfer augmentation techniques was carried out. The experimental data and the empirical correlations indicate that thermal protection for the fusion reactor components based on conventional design concepts can be provided with an adequate margin of safety without resorting to either high coolant velocities, excessive coolant pressures, or heat transfer augmentation techniques. If, however, the future designs require unconventional shapes or heat transfer enhancement techniques, experimental verification would be necessary since no data on heat transfer augmentation techniques exist for ...

1986-01-01

37

Thermal-hydraulic limitations on water-cooled fusion reactor components  

Energy Technology Data Exchange (ETDEWEB)

An assessment of the cooling requirements for fusion reactor components, such as the first wall and limiter/divertor, was carried out using pressurized water as the coolant. In order to establish the coolant operating conditions, a survey of the literature on departure from nucleate boiling, critical heat flux, asymmetrical heating and heat transfer augmentation techniques was carried out. The experimental data and the empirical correlations indicate that thermal protection for the fusion reactor components based on conventional design concepts can be provided with an adequate margin of safety without resorting to either high coolant velocities, excessive coolant pressures, or heat transfer augmentation techniques. If, however, the future designs require unconventional shapes or heat transfer enhancement techniques, experimental verification would be necessary since no data on heat transfer augmentation techniques exist for ...

1987-01-01

38

Thermal-hydraulic limitations on water-cooled fusion reactor components  

International Nuclear Information System (INIS)

An assessment of the cooling requirements for fusion reactor components, such as the first wall and limiter/divertor, was carried out using pressurized water as the coolant. In order to establish the coolant operating conditions, a survey of the literature on departure from nucleate boiling, critical heat flux, asymmetrical heating and heat transfer augmentation techniques was carried out. The experimental data and the empirical correlations indicate that thermal protection for the fusion reactor components based on conventional design concepts can be provided with an adequate margin of safety without resorting to either high coolant velocities, excessive coolant pressures, or heat transfer augmentation techniques. If, however, the future designs require unconventional shapes or heat transfer enhancement techniques, experimental verification would be necessary since no data on heat transfer augmentation techniques exist for ...

1986-12-07

39

TENT - a CORBA based component architecture for MPI-parallel CFD simulation systems and their supporting tools  

Energy Technology Data Exchange (ETDEWEB)

This paper describes TENT, a system designed for integrating the various tools and parts of a CFD simulation system (CFD - Computational Fluid Dynamics) and the simulation code itself in one interactive simulation environment. Initially the system was intended to be a TEstbed for Numerical Turbine simulation but it turned out that the approach was general enough to be suitable for more complex simulation tasks in the field of aircraft simulation. The paper will give a brief description of a CFD simulation system and its component interactions, which are the basis for describing the Component Architecture based on CORBA. This includes the control architecture using an event model and data flow considerations. Because most CFD codes use parallelization techniques based on Message Passing, a so called MIMD Object Abstraction is described in order to abstract the parallel computation threads to a single CORBA conform instance. ...

1998-07-01

40

Interactions between creep and corrosion in Alloy 800  

Energy Technology Data Exchange (ETDEWEB)

Metallic components within or immediately adjacent to gasifiers, such as gas distributors, thermowells, transfer lines, and cyclones, are subjected to severe of temperature, pressure, and hostile multicomponent gas environments. Metallic heat exchangers/waste-heat boilers resistant to sulfidation, corrosion. and erosion in low- and medium-Btu gas environments are essential components in large-scale gasification schemes, in both dry ash and slogging type gasifiers. Components, in general. must be resistant to corrosion, erosion, and high-temperature creep. A substantial data base is needed on the mechanical properties of materials exposed to complex gas environments to provide a more viable basis for establishing long-term reliability of components. This work examines high-temperature creep of Alloy 800, a high-chromium alloy widely used in coal conversion systems, after exposure to ...

1994-04-01

41

The strong associations between organism characteristics and network architecture  

CERN Document Server

Understanding the dependence and interplay between architecture and function in biological networks has great relevance to disease progression, biological fabrication and biological systems in general. Recent research in complex systems and networks, presents methods to properly mine the architectural interdependence in networks. Guided by such work, we propose methods to associate organism characteristics with network topology by analyzing a large number of architectural patterns. We adopt an automated approach using 11 topological metrics from complex networks to characterize a collection of various kinds of biological networks. Principal component analysis and clustering allow us to extract the indispensable, independent and informative metrics. Using hierarchical linear modeling, we observe that organism characteristics associate with these metrics, surprisingly well. This work can serve as a stepping stone to ...

2009-01-01

42

Spectrophotometric study of lanthanoid complexes with antipyrine and salicylic acid  

International Nuclear Information System (INIS)

The extraction-spectrophotometric method has been used to study lanthanoid ion complexing (Pr, Nd, Ho and Er) with antipyrine (Ant) and salicylic acid (Sal). The component relationship in different-ligand compounds Ln:Aut:Sal=2:3:6 and solvate number equal to 5 are determined; molar extinction coefficients of binary and different-ligand compounds are calculated. Oscillator strengths of absorption bands corresponding to supersensitive transitions of neodymium, holmium, erbium and some most intensive praseodymium bands are calculated. The study of IR spectra of investigated compounds allows to conclude on formation of coordination bonds of the central atom with the antipyrine molecule through the oxygen of the carbonyl group as well as on carboxyl group hydrogen substitution for metal and formation of coordination bond with OH group in salicylic acid molecules.

1981-01-01

43

Interaction of rare earths with orthanyl K and its spectrophotometric determination in binary mixtures  

International Nuclear Information System (INIS)

A study has been made of the colour reaction involved in the interaction or rare-earth elements with the reagent orthanyl K, the optimum conditions for the reaction being: pH=4.0-4.5 and lambda=660-670 nm. The ratio of components in the complex is Me:R=1:2. Consideration of the relative optical density values of the complex solutions as a function of the serial number of the rare-earth elements made it possible to recommend orthanyl K as a selective reagent for determining La, Ce, Pr and Nb in a mixture of Tu, Yb, Lu and Y oxides. The molar extinction coefficients, the sensitivity of the reaction and the concentration limits where Beer's law applies were calculated. Lanthanum was determined in a binary mixture with thulium and yttrium. (author).

1975-01-01

44

Future directions in controlling the LAMPF-PSR Accelerator Complex at Los Alamos National Laboratory  

Energy Technology Data Exchange (ETDEWEB)

Four interrelated projects are underway whose purpose is to migrate the LAMPF-PSR Accelerator Complex control systems to a system with a common set of hardware and software components. Project goals address problems in performance, maintenance and growth potential. Front-end hardware, operator interface hardware and software, computer systems, network systems and data system software are being simultaneously upgraded as part of these efforts. The efforts are being coordinated to provide for a smooth and timely migration to a client-sever model-based data acquisition and control system. An increased use of the distributed intelligence at both the front-end and operator interface is a key element of the projects. 2 refs., 2 figs.

1991-01-01

45

Feynman rules in N=2 projective superspace. II. Massive hypermultiplets  

International Nuclear Information System (INIS)

For pt.I see ibid., vol.516, p.426-48, 1998. Manifest N=2 supersymmetric hypermultiplet mass terms can be introduced in the projective N=2 superspace formalism. In the case of complex hypermultiplets, where the gauge covariantized spinor derivatives have an explicit representation in terms of gauge prepotentials, it is possible to interpret such masses as vacuum expectation values of an Abelian vector multiplet. The duality transformation that relates the N=2 off-shell projective description of the hypermultiplet to the on-shell description involving two N=1 chiral superfields allows us to obtain the massive propagators of the N=1 complex linear fields in the projective hypermultiplet. The N=1 massive propagators of the component superfields in the projective hypermultiplet suggest a possible ansatz for the N=2 massive propagator, which agrees with an explicit calculation in N=2 superspace. (orig.).

46

Applications and benefits of the FFTF IEM cell training facility  

Energy Technology Data Exchange (ETDEWEB)

The Interim Examination and Maintenance (IEM) Cell is located within the Fast Flux Test Facility (FFTF) Reactor Containment Building. This cell is a complex vertical hot cell whose purpose is to process reactor experiments and to perform maintenance on reactor and refueling components. Because access to this very complex cell is limited, a mock-up called the IEM Training Facility (IEMTF) has been developed. The IEMTF provides the IEM cell with many valuable benefits. Four of these benefits are: (1) development of alternate processing methods; (2) hands-on evaluation of equipment problems; (3) a ready source of verified parts, and (4) training facilities for IEM Cell technicians.

1982-05-01

47

Study of ebullated bed fluid dynamics for H-Coal. Quarterly progress report No. 2, December 1, 1977--February 28, 1978  

Science.gov (United States)

The H-Coal ebullated bed reactor contains at least four discrete components: gas, liquid, catalyst, and unconverted coal and ash. Because of the complexity created by these four components, it is desirable to understand the fluid dynamics of the system. The objective of this program is to establish the dependence of the ebullated bed fluid dynamics on process parameters. This will permit improved control of the ebullated bed reactor. Progress has been made in the study undertaken for defining the hydrodynamic properties of gas/liquid/solid systems as related to the H-Coal process. The literature search was completed, and a report will be issued shortly. Design and construction of the fluid dynamics unit proceeded as planned. Unit completion is scheduled for May 1, 1978.

1978-03-01

48

Simulating Large-scale Structure  

CERN Document Server

After two decades of direct dynamical simulation of large-scale structure in the universe, it is safe to say the subject is now mature. Still, there are parts of the problem that are less well developed than others. In general, the collisionless dynamics of the dark matter component is better understood than the collisional gas dynamics of the baryonic component. In situations where the gas dynamics is relatively simple, such as the Lyman-$\\alpha$ forest and the intracluster medium in X-ray clusters, our ability to reproduce observational data has evolved rapidly, and the interpretive and predictive power of such experiments should now be taken seriously. A comparison of twelve gas dynamic codes to the problem of forming a single X-ray cluster shows that numerical inaccuracies are modest (typically below ten percent), leaving missing physics as the main source for large systematic differences between theory and observation. Galaxy formation, ...

1998-01-01

49

Means and method of balancing multi-cylinder reciprocating machines  

Energy Technology Data Exchange (ETDEWEB)

A virtual balancing axis arrangement is described for multi-cylinder reciprocating piston machines for effectively balancing out imbalanced forces and minimizing residual imbalance moments acting on the crankshaft of such machines without requiring the use of additional parallel-arrayed balancing shafts or complex and expensive gear arrangements. The novel virtual balancing axis arrangement is capable of being designed into multi-cylinder reciprocating piston and crankshaft machines for substantially reducing vibrations induced during operation of such machines with only minimal number of additional component parts. Some of the required component parts may be available from parts already required for operation of auxiliary equipment, such as oil and water pumps used in certain types of reciprocating piston and crankshaft machine so that by appropriate location and dimensioning in accordance with the teachings of the ...

1985-01-01

50

A one-dimensional, two-phase model for direct methanol fuel cells - Part I: Model development and parametric study  

British Library Electronic Table of Contents (United Kingdom)

A one-dimensional, steady-state, two-phase direct methanol fuel cell (DMFC) model is developed to precisely investigate complex physiochemical phenomena inside DMFCs. In this model, two-phase species transport through the porous components of a DMFC is formulated based on Maxwell-Stefan multi-component diffusion equations, while capillary-induced liquid flow in the porous media is described by Darcy's equation. In addition, the model fully accounts for water and methanol crossover through the membrane, which is driven by the effects of electro-osmotic drag, diffusion, and the hydraulic pressure gradient. The developed model is validated against readily available experimental data in the literature. Then, a parametric study is carried out to investigate the effects of the operating temperat...

2010-01-01

51

Investigating the complex X-ray spectrum of a broad-line 2MASS red quasar: XMM-Newton observation of FTM 0830+3759  

CERN Document Server

We report results from a 50 ks XMM-Newton observation of the dust-reddened broad-line quasar FTM 0830+3759 (z=0.413) selected from the FIRST/2MASS Red Quasar survey. For this AGN, a very short 9 ks Chandra exposure had suggested a feature-rich X-ray spectrum and HST images revealed a very disturbed host galaxy morphology. Contrary to classical, optically-selected quasars, the X-ray properties of red (i.e. with J-Ks> 1.7 and R-Ks> 4) broad line quasars are still quite unexplored, although there is a growing consensus that, due to moderate obscuration, these objects can offer a unique view of spectral components typically swamped by the AGN light in normal, blue quasars. The XMM-Newton observation discussed here has definitely confirmed the complexity of the X-ray spectrum revealing the presence of a cold (or mildly-ionized) absorber with Nh ~10^{22} cm^-2 along the line of sight to the nucleus and a Compton reflection ...

2010-01-01

52

Solvent extraction of well defined astatine species  

International Nuclear Information System (INIS)

During solvent extraction of At"-, [At(H_2O)_2]"+, AtCl, AtCl_2"- as well as of astatine compounds with higher oxidation states like AtO_n"-, the astatine species are changed into astatine of the oxidation state zero at the phase boundary independent on the organic solvent used. At(O) probably reacts with components of the organic phase or with decomposition products formed by chemical reactions or by radiolysis. The extraction coefficients of the astatine species depend on the experimental conditions applied, the redox potential, and on complex forming reactions or associations, resp., occuring in the aqueous phase. (author).

53

Medical Devices; Managing the Mismatch An Outcome of the Priority Medical Devices Project  

CERN Document Server

Choosing a medical device is complex and requires a transparent process based on reason, evidence and assessment of prioritized public health needs. Poor choices lead to inappropriate use or non-use of medical devices and a waste of resources.This report suggests how an agenda to improve access to appropriate medical devices could be devised from applying the crucial 4 components - Availability, Accessibility, Appropriateness, and Affordability, to the 15 global high-burden diseases and some cross-cutting issues. The results of this exercise suggest several areas of research necessary to help

2010-01-01

54

Global Dissipative Dynamics of the Extended Brusselator System  

CERN Document Server

The existence of a global attractor for the solution semiflow of the extended Brusselator system in the $L^2$ phase space is proved, which is a cubic-autocatalytic and partially reversible reaction-diffusion system with linear coupling between two compartments. The method of grouping and re-scaling estimation is developed to deal with the challenge in proving the absorbing property and the asymptotic compactness of this typical multi-component reaction-diffusion systems. It is also proved that the global attractor is an $(H, E)$ global attractor with the $L^\\infty$ regularity and that the Hausdorff dimension and the fractal dimension of the global attractor are finite. The results and methodology can find many applications and further extensions in complex biological and biochemical dynamical systems.

2011-01-01

55

Failure of the Tibial Insert in a Rotating Hinge Total Knee Arthroplasty  

British Library Electronic Table of Contents (United Kingdom)

There has been a steady increase in the number of revision total knee arthroplasties being performed in the United States. Hinge knee prostheses are used predominantly in complex primary or revision arthroplasties, often as salvage procedures. Significant improvement of the articulation between the rotating hinge mechanism and tibial component has decreased the stresses that contributed to earlier failures in previous generation designs. Two cases of fracture of the tibial metal post in the rotating hinge of a revision total knee arthroplasty were evaluated and treated at our institution within a 1-month period. We present our experience with this construct failure and subsequent patient management.

2011-01-01

56

Electromagnetic coupling of high-altitude, nuclear electromagnetic pulses  

International Nuclear Information System (INIS)

We have used scale models to measure the predicted coupling of electromagnetic fields simulating the effects of high-altitude nuclear electromagnetic pulses (HEMP) on the interior surfaces of electronic components. Predictive tools for exterior coupling are adequate. For interior coupling, however, such tools are in their infancy. Our methodological approach combines analytical, computational, and laboratory techniques in a complementary way to take advantage of their separate strengths. Computer models are a promising tool, as they can be used to treat complex objects with arbitrary shapes, dielectrics, and cables, and multiple apertures. Laboratory tests can expand the domain of investigation even further.

1984-11-01

57

An Apparent Hard X-ray Decline of CH Cygni  

CERN Document Server

CH Cygni is a symbiotic star consisting of an M giant and an accreting white dwarf, which is known to be a highly variable X-ray source with a complex, two-component, spectra. Here we report on two Suzaku observations of CH Cyg, taken in 2006 January and May, during which the system was seen to be in a soft X-ray bright, hard X-ray faint state. Based on the extraordinary strength of the 6.4 keV fluorescent Fe K-alpha line, we show that the hard X-rays observed with Suzaku are dominated by scattering.

2006-01-01

58

Irradiation-assisted stress corrosion cracking of austenitic stainless steels: Recent progress and new approaches  

Energy Technology Data Exchange (ETDEWEB)

Irradiation-assisted stress corrosion cracking (IASCC) of several types of BWR field components fabricated from solution-annealed austenitic stainless steels (SSs), including a core internal weld, were investigated by means of slow-strain-rate test (SSRT), scanning electron microscopy (SEM), Auger electron spectroscopy (AES), and field-emission-gun advanced analytical electron microscopy (FEG-AAEM). Based on the results of the tests and analyses, separate effects of neutron fluence, tensile properties, alloying elements and major impurities identified in the American Society for Testing and Materials (ASTM) specifications, minor impurities, water chemistry, and fabrication-related variables were determined. The results indicate strongly that minor impurities not specified by the ASTM-specifications play important roles, probably through a complex synergism with grain-boundary Cr depletion. These impurities, typically associated with steelmaking ...

1996-09-01

59

The ATG1/ATG13 Protein Kinase Complex Is Both a Regulator and a Target of Autophagic Recycling in Arabidopsis.  

Science.gov (United States)

Autophagy is an intracellular recycling route in eukaryotes whereby organelles and cytoplasm are sequestered in vesicles, which are subsequently delivered to the vacuole for breakdown. The process is induced by various nutrient-responsive signaling cascades converging on the Autophagy-Related1 (ATG1)/ATG13 kinase complex. Here, we describe the ATG1/13 complex in Arabidopsis thaliana and show that it is both a regulator and a target of autophagy. Plants missing ATG13 are hypersensitive to nutrient limitations and senesce prematurely similar to mutants lacking other components of the ATG system. Synthesis of the ATG12-ATG5 and ATG8-phosphatidylethanolamine adducts, which are essential for autophagy, still occurs in ATG13-deficient plants, but the biogenesis of ATG8-decorated autophagic bodies does not, indicating that the complex regulates downstream events required for autophagosome enclosure and/or ...

2011-10-01

60

Extraction-spectrophotometric determination of terbium in its mixture with lanthanum  

International Nuclear Information System (INIS)

A spectrophotometric study of the extraction with isobutanol of rare-earth elements in the form of complexes with quinoilizarin and N-benzene-N-phenylhydroxylamine has been made. The purpose of the study is to find out whether this reaction can be used in determining the concentration of elements in the presence of other rare-earth elements. In determining the relationship between the pH and light absorption the pH of the solution is measured after the extraction. The extraction of complexes begins at pH approximately 4 and reaches a maximum at pH7-8 (for La) and pH6-9 (for Er). The complexes underge decomposition when pH of the solution increased. The composition of complex compounds is determined by spectrophotometric methods for isomolar series, molar ratios and from the slope of logarithmic plots. Under optimal conditions (pH7.5) aAd at the measured ratio of the component for ...

1975-01-01

61

Operational simulation, design and management of decentralized energy systems; Betriebliche Modellierung, Auslegung und Management von dezentralen Energiesystemen  

Energy Technology Data Exchange (ETDEWEB)

Chapter 2 describes the worldwide increase of primary energy consumption, which is expected in coming decades and results in possible solutions of a decentralised energy supply that is mainly based upon renewable energy carriers and the use of cogeneration systems. Chapter 3 shows the characteristics of decentralised system components that have been investigated in the frame of this research work as well as the resulting model library to depict the operational performance of the individual components and their mutual influence. A detailed dynamic simulation of a complete fuel cell system based on a steam reformer including the concept of local and superordinate control circuits is presented in chapter 4. Chapter 5 includes the integrated concepts for the intelligent and adaptable management of complex decentralised energy systems as well as a description of their implementation. Apart from the applied metaheuristic ...

2007-06-28

62

DEVELOPMENT OF TECHNOLOGIES AND ANALYTICAL CAPABILITIES FOR VISION 21 ENERGY PLANTS  

Energy Technology Data Exchange (ETDEWEB)

The goal of this DOE Vision-21 project work scope is to develop an integrated suite of software tools that can be used to simulate and visualize advanced plant concepts. Existing process simulation software does not meet the DOE's objective of ''virtual simulation'' which is needed to evaluate complex cycles. The overall intent of the DOE is to improve predictive tools for cycle analysis, and to improve the component models that are used in turn to simulate the cycle. Advanced component models are available; however, a generic coupling capability that will link the advanced component models to the cycle simulation software remains to be developed. In the current project, the coupling of the cycle analysis and cycle component simulation software will be based on an existing suite of programs. The challenge is to develop a general-purpose ...

2002-08-31

63

High resolution sequence stratigraphy of Miocene deep-water clastic outcrops, Taranaki coast, New Zealand  

Energy Technology Data Exchange (ETDEWEB)

Approximately 700m of deep water clastic deposits of Mt. Messenger Formation are superbly exposed along the Taranaki coast of North Island, New Zealand. Biostratigraphy indicates the interval was deposited during the time span 10.5-9.2m.y. in water depths grading upward from lower bathyal to middle-upper bathyal. This interval is considered part of a 3rd order depositional sequence deposited under conditions of fluctuating relative sea-level, concomitant with high sedimentation rates. Several 4th order depositional sequences, reflecting successive sea-level falls, are recognized within the interval. Sequence boundaries display a range of erosive morphologies from metre-wide canyons to scours several hundred metres across. All components of a generic lowstand systems tract--basin floor fan, channel-levee complex and progading complex--are present in logical and temporal order. They are repetitive through the interval, with ...

1995-08-01

65

Micromachining using a focused ion beam miller  

International Nuclear Information System (INIS)

Full text: The focused ion beam (FIB) miller is becoming well established as a machine for the structural analysis of materials and for the rapid preparation of transmission electron microscope specimens. It has also been used for some time in the semiconducting materials industry for the analysis, repair and redesign of device materials. However, one emerging technique is the use of the FIB for micromachining. The FIB software can also be used to manufacture and machine components. This process can occur through converting software, typically in the form of bitmaps or TIF files, to proprietary 'stream' files. These files allow, often complex, patterns to be generated and milled into the specimen and thus the generation of micro-electromechanical systems. Frequently, this involves largely two-dimensional patterns and structures, however, more complex patterns and file types can be generated which allow, for example, device ...

2002-02-01

66

Focused ion beam techniques for fabricating geometrically-complex components and devices.  

Energy Technology Data Exchange (ETDEWEB)

We have researched several new focused ion beam (FIB) micro-fabrication techniques that offer control of feature shape and the ability to accurately define features onto nonplanar substrates. These FIB-based processes are considered useful for prototyping, reverse engineering, and small-lot manufacturing. Ion beam-based techniques have been developed for defining features in miniature, nonplanar substrates. We demonstrate helices in cylindrical substrates having diameters from 100 {micro}m to 3 mm. Ion beam lathe processes sputter-define 10-{micro}m wide features in cylindrical substrates and tubes. For larger substrates, we combine focused ion beam milling with ultra-precision lathe turning techniques to accurately define 25-100 {micro}m features over many meters of path length. In several cases, we combine the feature defining capability of focused ion beam bombardment with additive techniques such as evaporation, sputter deposition and electroplating in order to build ...

2004-03-01

67

Determination of the specific heat petroleum derivates; Determinacao do calor especifico de derivados ultrapesados de petroleo  

Energy Technology Data Exchange (ETDEWEB)

In the development of the specific mathematical modeling for heavy and ultra heavy petroleum fractions in a molecular distiller is very important the definition of physical and chemical parameters as density and specific heat of the mixture, the enthalpy of vaporization, among others, since they are used in the energy balance. Information on these properties and their variation with temperature are found in the open literature for mixture with few components (simple mixtures). However, for multicomponent solutions consisting of complex mixtures such as oil and its heavy and ultraheavy fractions, available data are few, or are limited to low temperatures. The specific heat is an important property in the energy balance. This property can be measured by Differential Scanning Calorimetry (DSC), which gives results with great sensitivity and accuracy. This paper presents the variation of specific heat with the temperature of ultra-heavy oil ...

2008-07-01

68

Conversion of char nitrogen to N2 under incomplete combustion conditions; Fukanzen nensho jokenka ni okeru char chuchisso no N2 eno tenka  

Energy Technology Data Exchange (ETDEWEB)

The effect of combustion conditions on conversion of char nitrogen to N2 was studied in the combustion experiment of char obtained by pyrolysis of coal. Char specimen was prepared by holding ZN coal of Chinese lignite in Ar atmosphere at 1123K for one hour. A batch scale quartz-made fluidized bed reactor was used for combustion experiment. After the specimen was fluidized in reaction gas, it was rapidly heated to start combustion reaction. CO, CO2 and N2 in produced gases were online measured by gas chromatography (GC). As the experimental result, under the incomplete combustion condition where a large amount of CO was produced by consuming almost all of O2, no NOx and N2O produced from char were found, and almost all of N-containing gas was N2. At the final stage of combustion, pyridinic-N disappeared completely, and pyrrolic-N decreased, while O-containing nitrogen complexes became a main component. It was thus suggested that O-containing ...

1996-10-28

69

Conawapa to Winnipeg Power Transmission Complex. Southern Receiver System: Environmental impact assessment status report  

International Nuclear Information System (INIS)

Development of the Conawapa-Winnipeg power transmission complex in Manitoba includes five interrelated transmission and conversion facilities. Environmental and socio-economic assessment work done to date on one component of this system (the upgrading of the Southern Receiver System) is described. This system is composed of a network of high voltage transmission lines and station facilities serving power demand in Winnipeg and southern Manitoba. The upgrading involves three main elements: energizing a second 230 kV ac circuit on an existing tower line running from the proposed Riel Station site to the existing St. Vital Station; constructing a new double-circuit 230 kV tower line on the same existing right-of-way between St. Vital and the Riel site area; and installing an additional transformer and other necessary equipment at St. Vital and other stations affected by the upgrade. The environmental impacts of these projects are generally not ...

1992-01-01

70

Antihemostatic molecules from saliva of blood-feeding arthropods.  

Science.gov (United States)

The ability to feed on vertebrate blood has evolved many times in various arthropod clades. Each time this trait evolves, novel solutions to the problem posed by vertebrate hemostasis are generated. Consequently, saliva of blood-feeding arthropods has proven to be a rich source of antihemostatic molecules. Vasodilators include nitrophorins (nitric oxide storage and transport heme proteins), a variety of peptides that mimic endogenous vasodilatory neuropeptides, and proteins that catabolize or sequester endogenous vasoconstrictors. A variety of platelet aggregation inhibitors antagonize platelet responses to wound-generated signals, including ADP, thrombin, and collagen. Anticoagulants disrupt elements of both the intrinsic and extrinsic pathways. Molecular approaches (termed 'sialomics') to characterize the full inventory of mRNAs transcribed in salivary glands have revealed a surprising level of complexity within a single species. Multiple salivary proteins may be ...

2005-01-01

71

A Glance into the Future of Human Computer Interaction  

CERN Document Server

Computers have a direct impact on our lives nowadays. Human's interaction with the computer has modified with the passage of time as improvement in technology occurred the better the human computer interaction became. Today we are facilitated by the operating system that has reduced all the complexity of hardware and we undergo our computation in a very convenient way irrespective of the process occurring at the hardware level. Though the human computer interaction has improved but it's not done yet. If we come to the future the computer's role in our lives would be a lot more rather our life would be of the artificial intelligence. In our future the biggest resource would be component of time and wasting time for a key board entry or a mouse input would be unbearable so the need would be of the computer interaction environment that along with the complexity reduction also minimizes the time wastage in the human computer ...

2011-01-01

72

The mammalian neuroendocrine hormone norepinephrine supplies iron for bacterial growth in the presence of transferrin or lactoferrin.  

Science.gov (United States)

Norepinephrine stimulates the growth of a range of bacterial species in nutritionally poor SAPI minimal salts medium containing 30% serum. Addition of size-fractionated serum components to SAPI medium indicated that transferrin was required for norepinephrine stimulation of growth of Escherichia coli. Since bacteriostasis by serum is primarily due to the iron-withholding capacity of transferrin, we considered the possibility that norepinephrine can overcome this effect by supplying transferrin-bound iron for growth. Incubation with concentrations of norepinephrine that stimulated bacterial growth in serum-SAPI medium resulted in loss of bound iron from iron-saturated transferrin, as indicated by the appearance of monoferric and apo- isoforms upon electrophoresis in denaturing gels. Norepinephrine also caused the loss of iron from lactoferrin. The pharmacologically inactive metabolite norepinephrine 3-O-sulfate, by contrast, did not result in iron loss from ...

2000-11-01

73

Trade-off between angular resolution and straylight contamination in CMB anisotropy experiments. II. Straylight evaluation  

CERN Document Server

Satellite CMB anisotropy missions and new generation of balloon-borne and ground experiments, make use of complex multi-frequency instruments at the focus of a meter class telescope. Between 70 GHz and 300 GHz, where foreground contamination is minimum, it is extremely important to reach the best trade-off between the improvement of the angular resolution and the minimization of the straylight contamination mainly due to the Galactic emission. We focus here, as a working case, on the 30 and 100 GHz channels of the Planck Low Frequency Instrument (LFI). We evaluate the GSC introduced by the most relevant Galactic foreground components for a reference set of optical configurations. We show that it is possible to improve the angular resolution of 5-7% by keeping the overall GSC below the level of few microKelvin. A comparison between the level of straylight introduced by the different Galactic components for different beam ...

2003-01-01

74

Thermal-hydraulic limitations on water-cooled limiters  

Energy Technology Data Exchange (ETDEWEB)

An assessment of the cooling requirements for fusion reactor components, such as the first wall and limiter/divertor, was carried out using pressurized water as the coolant. In order to establish the coolant operating conditions, a survey of the literature on departure from nucleate boiling, critical heat flux, asymmetrical heating and heat transfer augmentation techniques was carried out. The experimental data and the empirical correlations indicate that thermal protection for the fusion reactor components based on current design concepts can be provided with an adequate margin of safety without resorting to either high coolant velocities, excessive coolant pressures, or heat transfer augmentation techniques. If, however, the future designs require heat transfer enhancement techniques, experimental verification would be necessary since no data on heat transfer augmentation techniques exist for complex geometries, ...

1984-08-01

75

Swift panchromatic observations of the bright gamma-ray burst GRB050525a  

CERN Document Server

The bright gamma-ray burst GRB050525a has been detected with the Swift observatory, providing unique multiwavelength coverage from the very earliest phases of the burst. The X-ray and optical/UV afterglow decay light curves both exhibit a steeper slope ~0.15 days after the burst, indicative of a jet break. The timing of the jet break combined with the total gamma-ray energy of the burst constrains the opening angle of the jet to be 2.5 degrees. We derive an empirical `time-lag' redshift from the BAT data of z_hat = 0.69 +/- 0.02, in good agreement with the spectroscopic redshift of 0.61. Prior to the jet break, the X-ray data can be modelled by a simple power law with index alpha = -1.2. However after 300s the X-ray flux brightens by about 30% compared to the power-law fit. The optical/UV data have a more complex decay, with evidence of a rapidly falling reverse shock component that dominates in the first minute or so, giving way to a flatter ...

2006-01-01

76

Optimization of productivity of mining equipment systems  

Energy Technology Data Exchange (ETDEWEB)

The operation of equipment in a mine produces a complex system which requires monitoring, simulation, analysis and reconciliation to ensure optimum production. The work described in the paper represents the initial steps in an overall program to enable optimization of production and equipment usage. Two areas of investigation are covered in some detail. The first concerns large haul trucks which accomplish much of the movement of minerals and wastes in many open pit mining operations. The monitoring of trucks in normal operation is described along with some of the results of such work. The second concerns draglines which are similarly important in moving overburden in many coal mines. A program of computer simulation of draglines is described. This shows the benefits of a simulation model which can be used to determine the effects of productivity of small changes in stripping procedure or dragline characteristics. The above investigations are placed in the context ...

1983-05-01

77

Determination of principal and impurity components in monocrystals of erbium and yttrium formates grown on the basis of high-pure substances  

International Nuclear Information System (INIS)

Determination of principal and impurity components in monocrystals of erbium and yttrium formates grown on the basis of high-pure formates from oriental primers, using the method of isothermal evaporation of the salt aqueous solutions with pH 4.4 - 4.5, is described. Er and Y were determined complexonometrically by the titration of the complex with arsenazo 1 by EDTA solution, and formate-ion was determined iodometrically. Impurities were analyzed by atomic-absorption and titrimetric methods. The atomic-absorption method permits to determine in the monocrystal from 1 x 10"-"4 to 5 x 10"-"3 % Mg at relative standard deviation S_r = 0.05; from 1 x 10"-"3 to 2.5 x 10"-"2 % Ca at S_r = 0.07 and from 2 x 0"-"4 to 5 x 10"-"3 % Pb ar S_r = 0.08.

78

Thermoluminescent (Tl) dosimetry of slow-neutron fields at radiotherapy dose level  

Energy Technology Data Exchange (ETDEWEB)

The dosimetry for radiotherapy involving neutrons is very complicated, owing to the complexity of secondary radiation components, whose contributions to the total absorbed dose have to be discriminated, owing to the different radiobiological effects. In order to separate thermal neutrons and photons, LiF dosimeters are mostly utilized. containing different percentage of Li, like as TLD-700, TLD-100 and TLD-600, but many problems arise. In the response of TLD-700 exposed to neutron-gamma mixed fields with high neutron flux, the contribution of thermal neutrons to the Tl emission is high. Moreover. TLD-100 and TLD-600 may undergo radiation damage, and great care has to be taken in order to obtain reliable results. Other TLDs showing lower sensitivity to neutrons are proposed and experimented for such high-flux neutron fields. The faced problems and various proposed solutions are here described. (Author)

2003-07-01

79

Sodium-driven motor of the polar flagellum in marine bacteria Vibrio  

British Library Electronic Table of Contents (United Kingdom)

The Na+-driven bacterial flagellar motor is a molecular machine powered by an electrochemical potential gradient of sodium ions across the cytoplasmic membrane. The marine bacterium Vibrio alginolyticus has a single polar flagellum that enables it to swim in liquid. The flagellar motor contains a basal body and a stator complexes, which are composed of several proteins. PomA, PomB, MotX, and MotY are thought to be essential components of the stator that are required to generate the torque of the rotation. Several mutations have been investigated to understand the characteristics and function of the ion channel in the stator and the mechanism of its assembly around the rotor to complete the motor. In this review, we summarize recent results of the Na+-driven motor in the polar flagellum of ...

2011-01-01

80

Reliability-based robustness analysis for a Croatian sports hall  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a probabilistic approach for structural robustness assessment for a timber structure built a few years ago. The robustness analysis is based on a structural reliability based framework for robustness and a simplified mechanical system modelling of a timber truss system. A complex timber structure with a large number of failure modes is modelled with only a few dominant failure modes. First, a component based robustness analysis is performed based on the reliability indices of the remaining elements after the removal of selected critical elements. The robustness is expressed and evaluated by a robustness index. Next, the robustness is assessed using system reliability indices where the probabilistic failure model is modelled by a series system of parallel systems.

2011-01-01

81

Recovery of transplutonium elements from aqueous and water-ethanol solutions of sulfuric acid and their separation from other actinides  

Energy Technology Data Exchange (ETDEWEB)

The behavior of Am, Cm, Bk, Cf, Es, and other actinides, as well as Zr, on anion and cation exchangers in aqueous and water-ethanol solutions of sulfuric acid as a function of the various components of the solution has been investigated. It has been discovered that the presence of ethanol in sulfuric acid solutions causes an increase in the distribution coefficients both on cation exchangers and on anion exchangers. The possibility of the use of ion exchangers for the preconcentration and separation of transplutonium elements from U, Np, Pu, Zr, and other elements which form strong complexes with sulfate ions over a broad range of concentrations of sulfuric acid has been demonstrated.

1988-05-01

82

Radiation hardening of integrated circuits technologies  

International Nuclear Information System (INIS)

The radiation hardening studies started in the mid decade 1960-1970. To survive the different military or space radiative environment, a new engineering science was born, to understand the degradation of electronics components. The different solutions to improve the electronic behavior in such environments have been named 'radiation hardening' of the technologies. Improvement of existing technologies, and qualification methods have been widely studied. However, on the other hand, specific technologies were developed: the Silicon On Insulator technologies for CMOS or Bipolar. The HSOI3HD technology offers today the highest hardening level for the integration density of hundreds of thousand transistors on the same silicon. Full complex systems could be produced on a single die with a technological radiation hardening and no more system hardening.

83

Numerical methods for thermal-hydraulics and structure in nuclear engineering  

International Nuclear Information System (INIS)

Designs of nuclear reactor plants aim for high performance under safety consideration. Because of large scale and high pressure/temperature conditions, data from costly mockup tests have been required to verify simulation codes of systems and components. Establishment of design by analysis (DBA) in nuclear engineering is required for development of next generation nuclear reactors. Recent powerful computers and simulation technique enable numerical analyses to predict realistic behaviors of thermo-fluid flow, structure and do on. The present report describes resent simulation results of complex gas-liquid two-phase flow, large scale structure dynamics and fluid-structure interaction. (author)

2008-06-01

84

Nanoengineered explosives  

Energy Technology Data Exchange (ETDEWEB)

A complex modulated structure is described for reactive elements that have the capability of considerably more heat than organic explosives while generating a working fluid or gas. The explosive and method of fabricating same involves a plurality of very thin, stacked, multilayer structures, each composed of reactive components, such as aluminum, separated from a less reactive element, such as copper oxide, by a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures. The various layers of material, thickness of 10 to 10,000 angstroms, can be deposited by magnetron sputter deposition. The explosive detonates and combusts a high velocity generating a gas, such as CO, and high temperatures. 2 figs.

1996-04-09

85

Multi-scale evaluation of river health in Liao River Basin, China  

British Library Electronic Table of Contents (United Kingdom)

Previous studies on river health evaluation mainly focused on characterizations at a river-corridor scale and ignored the complex interactions between the river ecosystem and other components of the river basin. Based on the consideration of the interactions among rivers, associated river basin and habitats, an assessment framework with multi-scale indicators was developed. An index system divided among these three scales to characterize the health of river ecosystems in China???s Liao River Basin was established. Set pair analysis was applied to integrate the multi-scale indicators and determine the health classes. The evaluation results indicated that the rivers in the western and eastern zones of the Liao River were classified as sick, and rivers in the main stream of the Liao and Hunta...

2011-01-01

86

Interplay between coherence and decoherence in LHCII photosynthetic complex  

CERN Document Server

This paper investigates the dynamics of excitonic transport in photocomplex LHCII, the primary component of the photosynthetic apparatus in green plants. The dynamics exhibits a strong interplay between coherent processes mediated by the excitonic Hamiltonian, and incoherent processes due to interactions with the environment. The spreading of the exciton over a single monomer is well described by a proper measure of delocalization that allows one to identify two relevant time scales. An exciton initially localized in one chromophore first spreads coherently to neighboring chromophores. During this initial coherent spreading, quantum effects such as entanglement play a role. As the effects of a decohering environment come into play, coherence and decoherence interact to give rise to efficient and robust excitonic transport, reaching a maximum efficiency at the levels of decoherence found in physiological conditions. We analyze the efficiency for different possible ...

2011-01-01

87

Five years operating experience at the Fast Flux Test Facility  

Energy Technology Data Exchange (ETDEWEB)

The Fast Flux Test Facility (FFTF) is a 400 Mw(t), loop-type, sodium-cooled, fast neutron reactor. It is operated by the Westinghouse Hanford Company for the United States Department of Energy at Richland, Washington. The FFTF is a multipurpose test reactor used to irradiate fuels and materials for programs such as Liquid Metal Reactor (LMR) research, fusion research, space power systems, isotope production and international research. FFTF is also used for testing concepts to be used in Advanced Reactors which will be designed to maximize passive safety features and not require complex shutdown systems to assure safe shutdown and heat removal. The FFTF also provides experience in the operation and maintenance of a reactor having prototypic components and systems typical of large LMR (LMFBR) power plants. The 5 year operational performance of the FFTF reactor is discussed in this report. 6 refs., 10 figs., 2 tabs.

1987-04-01

88

Five years operating experience at the Fast Flux Test Facility  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400 Mw(t), loop-type, sodium-cooled, fast neutron reactor. It is operated by the Westinghouse Hanford Company for the United States Department of Energy at Richland, Washington. The FFTF is a multipurpose test reactor used to irradiate fuels and materials for programs such as Liquid Metal Reactor (LMR) research, fusion research, space power systems, isotope production and international research. FFTF is also used for testing concepts to be used in Advanced Reactors which will be designed to maximize passive safety features and not require complex shutdown systems to assure safe shutdown and heat removal. The FFTF also provides experience in the operation and maintenance of a reactor having prototypic components and systems typical of large LMR (LMFBR) power plants. The 5 year operational performance of the FFTF reactor is discussed in this report. 6 refs., 10 figs., 2 tabs.

1987-09-13

89

Chemical stability of {gamma}-butyrolactone-based electrolytes for aluminium electrolytic capacitors  

Energy Technology Data Exchange (ETDEWEB)

{gamma}-Butyrolactone-based electrolytes have been used as the operating electrolytes for aluminum electrolytic capacitors. The chemical stability of these electrolytes at elevated temperatures has been examined by monitoring the decrease in their electrolytic conductivities. The deteriorated electrolytes were analyzed by gas and liquid chromatography and the conductivity decrease was directly correlated with the loss of acid components. In quaternary ammonium hydrogen maleate/{gamma}-butyrolactone electrolytes, the maleate anion decomposed by decarboxylation resulting in a complex polymer containing polyester and polyacrylate structures. Quaternary ammonium benzoate/{gamma}-butyrolactone electrolytes decomposed by SN2 reactions giving alkyl benzoates and trialkylamines. The deterioration of the carboxylate salt/{gamma}-butyrolactone electrolytes was accelerated by electrolysis. (orig.)

1996-06-01

90

A case-based approach to outpatient evaluation and management service coding.  

Science.gov (United States)

Understanding Center for Medicare and Medicaid Services (CMS) documentation and coding rules is challenging for most physicians. To accurately bill for clinical services, physicians must learn a system that may initially seem daunting, but is in fact governed by a small number of straightforward rules. The Evaluation and Management (E/M) guidelines for all service codes specify 3 components: history, examination, and medical decision-making, each with a defined set of elements or characteristics. Service coding is based on the level of care supported by the number of history and examination elements and the complexity of decision-making. This article will clarify the guidelines for outpatient clinical services and suggest a practical method of selecting appropriate E/M codes. Because physicians must often choose between billing codes 99213 and 99214 for a visit by an established patient, it will particularly focus on the minimum documentation ...

2008-11-01

91

Thermochemistry of mixed explosives  

Energy Technology Data Exchange (ETDEWEB)

In order to predict thermal hazards of high-energy materials, accurate kinetics constants must be determined. Predictions of thermal hazards for mixtures of high-energy materials require measurements on the mixtures, because interactions among components are common. A differential-scanning calorimeter (DSC) can be used to observe rate processes directly, and isothermal methods enable detection of mechanism changes. Rate-controlling processes will change as components of a mixture are depleted, and the correct depletion function must be identified for each specific stage of a complex process. A method for kinetics measurements on mixed explosives can be demonstrated with Composition B is an approximately 60/40 mixture of RDX and TNT, and is an important military explosive. Kinetics results indicate that the mator process is the decomposition of RDX in solution in TNT with a perturbation caused by interaction between the two ...

1982-01-01

92

Effect of hydraulic retention time on the biodegradation of complex phenolic mixture from simulated coal wastewater in hybrid UASB reactors  

International Nuclear Information System (INIS)

This study describes the feasibility of anaerobic treatment of complex phenolics mixture from a simulated synthetic coal wastewater using four identical 13.5 L (effective volume) bench scale hybrid up-flow anaerobic sludge blanket (HUASB) (combining UASB + anaerobic filter) reactors at four different hydraulic retention times (HRT) under mesophilic (27 #+-# 5 "oC) conditions. Synthetic coal wastewater with an average chemical oxygen demand (COD) of 2240 mg/L and phenolics concentration of 752 mg/L was used as substrate. The phenolics contained phenol (490 mg/L); m-, o-, p-cresols (123.0, 58.6, 42 mg/L); 2,4-, 2,5-, 3,4- and 3,5-dimethyl phenols (6.3, 6.3, 4.4 and 21.3 mg/L) as major phenolic compounds. The study demonstrated that at optimum HRT, 24 h, and phenolic loading rate of 0.75 g COD/(m"3-d), the phenolics and COD removal efficiency of the reactors were 96% and 86%, respectively. Bio-kinetic models were applied to data obtained from experimental studies in ...

2008-05-01

93

Design, fabrication, qualification and reliability of the major components of ''MONJU'' from a safety point of view  

International Nuclear Information System (INIS)

This paper will review code and standard and the safety related features of major components of Monju: Components of the Reactor Coolant Boundary; Components of the Reactor Shurdown Systems; Components of the Decay Heat Removal Systems; Components of the Engineered Safety Features; Other Safety Related Components. Their relationship to the system or plant function is emphasized, in reviewing these components.

1982-07-01

94

Formation and stability of astatide-mercury complexes  

International Nuclear Information System (INIS)

The formation of astatide-mercury complexes was investigated in aqueous solutions.The obtained complexes were examined by paper electrophoresis. It was found that Hg(OH)At and Hg(OH)I complexes were formed in neutral solution. The stability constants of the obtained complexes were determined by ion-exchange. The preliminary results indicate that the complex of mercury with astatide is much more stable than similar complexes with iodide. (author)

2006-04-01

95

Designer's handbook for forced-cooled high-pressure oil-filled pipe-type cable systems. Final report  

Energy Technology Data Exchange (ETDEWEB)

This handbook provides the necessary tools for the engineer to design forced-cooled HPOF pipe-type cable systems. It represents the final objective of a major project which included an extensive research program at the Waltz Mill Forced-Cooling Test Facility. The formulas and procedures presented in this handbook are consistent with the results of this program as well as other full-scale and model investigations. Introductory material, including historical information, general design concepts and basic heat transfer and fluid dynamics theory is given for those who are unfamiliar with the fundamental principles of forced-cooling. The nucleus of the handbook consists of equations and calculating procedures for determining forced-cooled parameters and thermal/hydraulic performance levels. Both simple and sophisticated procedures have been provided, with the more complex procedures treating such areas as the thermal interaction between cable pipes as well as the ...

1984-07-01

96

Characterization of thermoplastic polymer welding done with microwaves  

International Nuclear Information System (INIS)

Thermoplastic polymer materials and the compounds made with them are being used more frequently for industrial components and for general use. However, the application of these materials for the production of complex shaped or relatively large pieces is limited, because of the difficulty and cost of making the necessary tool kit for the job. One solution is the use of the welding process. But the safe and reliable union of different thermoplastic material parts is not a simple process, even less so in the case of unions of large components. Welding by microwaves using polymer conductors can help, since the large scale equipment is available, and methods for continuous processes by microwave have been developed, that can be used to weld large and small components. Many thermoplastics (ex. polyethylene) do not absorb, or absorb very little, energy from microwaves. Polymer conductors, however, heavily ...

2004-11-01

97

Algebraic complexities and algebraic curves over finite fields  

UK PubMed Central (United Kingdom)

We consider the problem of minimal (multiplicative) complexity of polynomial multiplication and multiplication in finite extensions of fields. For infinite fields minimal complexities are known [Winograd,...Full Text Available

1987-04-01

98

Analytical study on integrity of BWR reactor internal structures against water hammer under RIA conditions  

Energy Technology Data Exchange (ETDEWEB)

The integrity of the RPV head and reactor internals was assessed by means of fluid-structural analyses using a coupled method to evaluate the water hammer phenomenon arising from high burnup fuel failure under RIA conditions. The fluid viscosity effect on the water column burst as well as the complex three-dimensional flow paths caused by a core shroud and standpipes were considered in this study. The three analysis scenarios were designed to investigate the above mentioned influential factors separately. In the first scenario, a two-dimensional axisymmetric reactor vessel model without any reactor internals was modeled to assess the influence of the fluid dynamics in the NSC RIA regulatory evaluation. This model has an actual RPV geometry and can be simply separated from other influential factors in order to concentrate only on investigation of the fluid viscosity effect. In the second scenario, a two-dimensional axisymmetric reactor vessel model with major ...

2003-07-01

102

Complex fluid analysis with the advanced distillation curve approach.  

Science.gov (United States)

An improved method for measuring distillation curves reveals the physicochemical properties of complex fluids such as fuels. PMID:20041713

2010-02-01

103

Mechanism of zirconium complexing with biphenyl mono- and biscatecholylazo derivatives  

Energy Technology Data Exchange (ETDEWEB)

The complex formation of zirconium with biphenyl mono- and biscatecholyazo derivatives has been studied spectrophotometrically. The composition of the complexes, form and charge of complex-forming zirconium ions have been established. A procedure is suggested for calculation of molar absorptivities and stability constants for each of the complexes formed simultaneously in the system. Possible complex formation schemes have been studied. The data obtained were used to develop a spectrophotometric method of determining zirconium in the presence of large amounts of copper.

1982-05-01

104

Variations in ventral root axon morphology and locomotor behavior components across different inbred strains of mice  

British Library Electronic Table of Contents (United Kingdom)

Locomotion is a complex behavior affected by many different brain- and spinal cord systems, as well as by variations in the peripheral nervous system. Recently, we found increased gene expression for EphA4, a gene intricately involved in motor neuron development, between high-active parental strain C57BL/6J and the low-active chromosome substitution strain 1 (CSS1). CSS1 mice carry chromosome 1 from A/J mice in a C57BL/6J genetic background, allowing localization of quantitative trait loci (QTL) on chromosome 1. To find out whether differences in motor neuron anatomy, possibly related to the changes in EphA4 expression, are involved in the motor activity differences observed in these strains, motor performance in various behavioral paradigms and anatomical differences in the ventral roots ...

2009-01-01

105

Truck tactics: dispatch from Vancouver  

Energy Technology Data Exchange (ETDEWEB)

Any mine that uses haultrucks has a dispatching system of some sort, even if it is only a very basic and simple arrangement. The larger, more complex operations have found that, if properly applied, automated computerised dispatching improves the productivity of the equipment as well as improving overall control and reporting. However, not every mine can justify going this far; in these cases a computerised monitoring and reporting system with manual dispatching can still give considerable benefits. Wenco International Mining Systems of Vancouver supplies its computerised system to three different specification levels to suit most open pit mining operations. The article describes the 3 PMCSs (Production Monitoring and Control System) available: PMCS 1000, for monitoring and reporting only; PMCS 2000, for dispatching to maximise production; and PMCS 3000, for dispatching with optimised product quality and production. The major components of the ...

1991-11-01

106

Thermodynamic prediction of distribution coefficients for the solvent extraction of the rare earth metals  

International Nuclear Information System (INIS)

A thermodynamic model for predicting the distribution coefficients has been developed by taking into account the extraction mechanism and the chloride complexation when Sm, Eu, Gd, Tb, Dy and Ho for single component systems are extracted from acidic chloride solutions by di-2-ethylhexyl ester in kerosene, respectively. The model equation includes two constants, of which one corresponds to the apparent extraction equilibrium constant and the other is due to the variation of the activity coefficients of organic species. These values are determined from a few experimental data by the curve fitting method. Then, the distribution coefficients under untried calculations, Bromley's formulation is used to estimate the activity coefficients of aqueous species and the interaction parameters for some rare earth chlorides are reported in terms of morality and molarity using data from Spedding et al. According to the authors the validity of this method has ...

107

The year 2000 embedded systems problem to maintain the safety of nuclear installations  

International Nuclear Information System (INIS)

The Y2K problem may impact on nuclear installations in a number of ways because embedded systems are used in nuclear routine operation, monitoring and control system. The very simplest embedded systems are capable of performing only a single function or set of functions to meet a single predetermined purpose. In more complex systems the functioning of the embedded system is determined by an application program that enables the embedded system to be used for a particular purpose in a specific application. The simplest devices consist of a single microprocessor which may itself be packaged with other chips in a hybrid system or Application Specific Integrated Circuit (ASIC). Its input comes from a detector or sensor and its output goes to a switch or activator which may start or stop the operation of a positioning motors or, by operating a valve, may control the flow of cooling system to reactor core. Embedded systems in our organization are also be found in Batan ...

1999-02-01

108

The response of some TL albedo neutron dosimeters  

International Nuclear Information System (INIS)

As part of a general study of personnel neutron dosimetry systems, three British and two German TL albedo dosimeters were compared. They range from simple albedo devices to multi-element devices which detect combinations of incident and albedo neutrons. They were exposed to beams of mono-energetic neutrons, a thermal neutron column and a "2"5"2Cf source. The variation in response with neutron energy above 0.1 MeV was similar for all dosimeters. The resuls show that in general multi-component dosimeters fo not provide enough information to deduce the effective energy of incident neutrons. The choice of single or multi-element dosimeters for particular types of environment is discussed. The Harvey dosimeter has the most acceptable thermal neutron response of the simpler devices. For neutron energies below 0.5 MeV its response varies roughly as the cosine of the angle of incidence but is more complex at higher energies. (author).

109

The Oak Ridge Y-12 Plant biological monitoring and abatement program for East Fork Poplar Creek  

Energy Technology Data Exchange (ETDEWEB)

In May 1985, a National Pollutant Discharge Elimination System permit was issued for the Oak Ridge Y-12 Plant, a nuclear weapons components production facility located in Oak Ridge, Tennessee, and operated by Martin Marietta Energy Systems, Inc., for the US Department of Energy. As a condition of the permit, a Biological Monitoring and Abatement Program (BMAP) was developed to demonstrate that the effluent limitations established for the Oak Ridge Y-12 Plant protect the classified uses of the receiving stream (East Fork Poplar Creek), in particular, the growth and propagation of fish and aquatic life, as designated by the Tennessee Department of Health and Environment. A second purpose for the BMAP is to document the ecological effects resulting from implementation of a water pollution control program that will include construction of nine new wastewater treatment facilities over the next 4 years. Because of the complex nature of the effluent ...

1989-10-01

110

Technological advances and applications of geothermal energy pile foundations and their feasibility in Australia  

Energy Technology Data Exchange (ETDEWEB)

Geothermal energy pile foundations are an alternative energy source for heating and cooling needs. Utilising this source of energy has great potential due to the environmental, economic and social benefits. This paper looks at an extensive amount of literature on the technology behind the system including the overall process, primary considerations for each of the main components including latest developments as well as design implications such as the integration of ground energy systems into structural piles of buildings. Environmental considerations including performance-dependent parameters of the subsurface are described. Main parameters include thermal conductivity, thermal diffusivity, specific heat capacity and moisture content. Temperature and groundwater effects are also discussed and design considerations are provided. Mathematical models are available to aid in the design of these systems but there are various other issues and ...

2010-12-15

111

Stability study of a gyrotron-traveling-wave amplifier based on a lossy dielectric-loaded mode-selective circuit  

Science.gov (United States)

The millimeter microwave source of gyrotron-traveling-wave amplifier (gyro-TWT) is capable of generating high power coherent radiation in a broad bandwidth, while its performance is severely deteriorated by the stability problems. This paper focuses on modeling and the stability analysis of the Naval Research Laboratory (NRL) Ka-band TE{sub 01} mode gyro-TWT based on an interaction circuit alternately loaded with lossy ceramic shells and metal rings. The propagation characteristics of the interaction circuit is analyzed first, based on which the boundary impedance method is employed to build an equivalent uniform lossy circuit. Then the stability of the interaction system is studied using linear and nonlinear theories. The analysis reveals that, due to the special waveguide structure and the dielectric loss, the propagation characteristics of the complex waveguide are similar to that of a uniform lossy circuit. The analysis of the absolute instabilities ...

2009-07-15

112

Stability study of a gyrotron-traveling-wave amplifier based on a lossy dielectric-loaded mode-selective circuit  

International Nuclear Information System (INIS)

The millimeter microwave source of gyrotron-traveling-wave amplifier (gyro-TWT) is capable of generating high power coherent radiation in a broad bandwidth, while its performance is severely deteriorated by the stability problems. This paper focuses on modeling and the stability analysis of the Naval Research Laboratory (NRL) Ka-band TE01 mode gyro-TWT based on an interaction circuit alternately loaded with lossy ceramic shells and metal rings. The propagation characteristics of the interaction circuit is analyzed first, based on which the boundary impedance method is employed to build an equivalent uniform lossy circuit. Then the stability of the interaction system is studied using linear and nonlinear theories. The analysis reveals that, due to the special waveguide structure and the dielectric loss, the propagation characteristics of the complex waveguide are similar to that of a uniform lossy circuit. The analysis of the absolute instabilities characterizes the ...

2009-07-01

113

Reliability analysis of pipe whip impacts  

Energy Technology Data Exchange (ETDEWEB)

A probability-based approach is presented as the integration of probabilistic methods and deterministic modelling based on the finite element method. An existing finite element software package was linked to an existing probabilistic package to analyse the complex mechanics that occur during the transient non-linear analysis of impact problems. This methodology is applied to a pipe whip analysis of a group-distribution-header, which results from a guillotine break, and subsequent impact with the adjacent building wall; this is a postulated accident for the Ignalina Nuclear Power Plant RBMK-1500 reactors. The uncertainties of material properties, component geometry data and loads were taken into consideration. The probabilities of failure of the impacted header and of the header support-wall were estimated given uncertainties in material properties, geometrical parameters and loading. The software ProFES was used for the probabilistic analysis ...

2005-08-01

114

Radionuclide release rates from spent fuel for performance assessment modeling  

Energy Technology Data Exchange (ETDEWEB)

In a scenario of aqueous transport from a high-level radioactive waste repository, the concentration of radionuclides in water in contact with the waste constitutes the source term for transport models, and as such represents a fundamental component of all performance assessment models. Many laboratory experiments have been done to characterize release rates and understand processes influencing radionuclide release rates from irradiated nuclear fuel. Natural analogues of these waste forms have been studied to obtain information regarding the long-term stability of potential waste forms in complex natural systems. This information from diverse sources must be brought together to develop and defend methods used to define source terms for performance assessment models. In this manuscript examples of measures of radionuclide release rates from spent nuclear fuel or analogues of nuclear fuel are presented. Each example represents a very different ...

1994-11-01

115

Post-machining thermal treatment after surface finishing of hardened steels: Kinetics of XRD line width reduction and improvement in rolling contact lifetime under mixed friction conditions  

Energy Technology Data Exchange (ETDEWEB)

Hard surface finishing represents the final manufacturing step for functional areas of machine elements in state-of-the-art production. Raceways of rolling bearing rings are ground and honed to the required low roughness. Plastic deformation is restricted to a narrow edge zone of the hardened steel. Reheating of the machined components below the martensite tempering or bainite transformation temperature results in a marked decrease of the XRD line width on the surface. The investigated samples are made of through-hardened standard bearing steel 100Cr6 (international denotation: SAE 52100). On the basis of a material model that explains the effect as a complex diffusion process of dislocational carbon segregation, i.e. static strain aging, the measured kinetics of the XRD line width reduction is simulated by an Arrhenius-type equation, which describes the rate-controlling reaction step of temper carbide dissolution. The formation of a small ...

2008-07-01

116

Polarised foreground removal at low radio frequencies using rotation measure synthesis: Uncovering the signature of hydrogen reionisation  

CERN Document Server

Measurement of redshifted 21-cm emission from neutral hydrogen promises to be the most effective method for studying the reionisation history of hydrogen and, indirectly, the first galaxies. These studies will be limited not by raw sensitivity to the signal, but rather, by bright foreground radiation from Galactic and extragalactic radio sources and the Galactic continuum. In addition, leakage due to gain errors and non-ideal feeds conspire to further contaminate low-frequency radio obsevations. This leakage leads to a portion of the complex linear polarisation signal finding its way into Stokes I, and inhibits the detection of the non-polarised cosmological signal from the epoch of reionisation. In this work, we show that rotation measure synthesis can be used to recover the signature of cosmic hydrogen reionisation in the presence of contamination by polarised foregrounds. To achieve this, we apply the rotation measure synthesis technique to the Stokes I ...

2010-01-01

117

Oxidation of trivalent arsenic to pentavalent arsenic with oxygen in the presence of nitrite and iodide ions  

Science.gov (United States)

In view of the effect of the acidity on the oxidation potentials of nitrous, arsenous, and arsenic acids, one should expect a complex relationship between the rate of arsenic (III) to arsenic (V) and the pH of the solution. They studied the kinetics of the reaction 2AsO/sub 2//sup -/ + O/sub 2/ ..-->.. 2AsO/sub 3//sup -/ as functions of concentrations (partial pressure) of all the components of the system NaAsO/sub 2/-HCl(HClO/sub 4/)-NaNO/sub 2/-KI-H/sub 2/O-O/sub 2/ and temperature. The study of the kinetics of arsenic(III) oxidation to arsenic(V) with oxygen in the presence of sodium nitrite and iodide ions showed that the reaction rate passes through a maximum at an acid content of 1.2-2.5 M and rises in proportion to the second exponent of the sodium nitrite concentration and to the first exponent of the iodide ion concentrations and partial oxygen pressure. A fall in the temperature facilitates intensification of the process and ...

1986-10-20

118

Negative regulation of {beta}-catenin/Tcf signaling by naringenin in AGS gastric cancer cell  

Science.gov (United States)

Functional activation of {beta}-catenin/Tcf signaling plays an important role in early events in carcinogenesis. We examined the effect of naringenin against {beta}-catenin/Tcf signaling in gastric cancer cells. Reporter gene assay showed that naringenin inhibited {beta}-catenin/Tcf signaling efficiently. In addition, the inhibition of {beta}-catenin/Tcf signaling by naringenin in HEK293 cells transiently transfected with constitutively mutant {beta}-catenin gene, whose product is not phosphorylated by GSK3{beta}, indicates that its inhibitory mechanism was related to {beta}-catenin itself or downstream components. To investigate the precise inhibitory mechanism, we performed immunofluorescence, Western blot, and EMSA. As a result, our data revealed that the {beta}-catenin distribution and the levels of nuclear {beta}-catenin and Tcf-4 proteins were unchanged after naringenin treatment. Moreover, the binding activities of Tcf complexes to ...

2005-09-30

119

Mechanisms controlling the composition influence on radiation hardening and embrittlement of iron-base alloys  

International Nuclear Information System (INIS)

Classification and ranking of the solid solution on their reaction to the irradiation is suggested on the basis of binary system structure controlled by mixing enthalpy sign, melting temperatures relation of components and solidus curves slope. Several combinations of these characteristics permit to pick out three groups of substitutional elements capable of forming the vacancy-solute atom complexes either low-mobile or fast-mobile ones as compared to monovacancies migration. The radiation hardening (and embrittlement) of binary alloys should be intensified respectively either due to heterogeneous point defect clusters nucleation on solute traps or due to solute atom clusters/ precipitate formation. A local cohesion decrease may also occur especially if low-melting elements (characterized by low surface energy) are segregating on internal sinks or grain boundaries. The predicted specifics of different alloy group under irradiation and during ...

1994-06-20

120

Logistics modeling of future solid waste storage, treatment, and disposal  

Energy Technology Data Exchange (ETDEWEB)

Logistics modeling is a powerful analytical technique for effective planning of waste storage, treatment, and disposal activities. Logistics modeling facilitates analyses of alternate scenarios for future waste flows, facility schedules, and processing or handling capacities. These analyses provide an increased understanding of the specific needs for waste storage, treatment, and disposal while adequate time remains to plan accordingly. They also help to determine the sensitivity of these needs to various system parameters. This paper discusses a logistics modeling system developed by the Pacific Northwest Laboratory (PNL) to aid in solid waste planning for a large industrial complex managing many different types and classifications of waste. The basic needs for such a system are outlined, and the approach adopted in developing the system is described. A key component of this approach is the development of a conceptual model that provides a ...

1993-11-01

121

Line shapes for some specific transitions in Hydrogenic, Lithium-like, and Helium-like ions  

Energy Technology Data Exchange (ETDEWEB)

A set of computer codes have been developed to produce spectral line shapes of highly stripped ions for a number of transitions in Hydrogenic, Helium-like and Lithium-like species. The choice of the transitions has been dictated largely by the laser compression experiments. The transitions of Hydrogenic species are: Lyman ..cap alpha..; Lyman ..beta..; Lyman ..gamma..; Lyman delta; Balmer ..cap alpha..; and Balmer ..beta... The transitions of Helium-like species are: 1s/sup 2/(/sup 1/S/sub 0/)-1s2p(/sup 1/P); 1s/sup 2/(/sup 1/S/sub 0/)-1s3p(/sup 1/P); 1s/sup 2/(/sup 1/S/sub 0/)-1s4p(/sup 1/P) and the associated dipole-forbidden components. The transitions of Lithium-like species are the entire n = 2 to n = 3 and n = 4 complexes.

1980-12-29

122

High damping Fe-Mn martensitic alloys for engineering applications  

International Nuclear Information System (INIS)

Conventional methods for reducing vibration in engineering designs (i.e. by stiffening or detuning) may be undesirable or inadequate in conditions where size or weight must be minimized or where complex vibration spectra exist. Alloys which combine high damping capacity with good mechanical properties can provide attractive technical and economic solutions to problems involving seismic, shock and vibration isolation. To meet these trends, we have developed a new high damping Fe-17%Mn alloy. Also, the alloy has advantages of good mechanical properties and is more economical than any other known damping alloys (a quarter the cost of non-ferrous damping alloy). Thus, the high damping Fe-17%Mn alloy can be widely applied to household appliances, automobiles, industrial facilities and power plant components with its excellent damping capacity (SDC, 30%) and mechanical property (T.S. 700 MPa). It is the purpose of this paper to introduce the ...

2000-06-01

123

Fluence-convolution broad-beam (FCBB) dose calculation  

International Nuclear Information System (INIS)

IMRT optimization requires a fast yet relatively accurate algorithm to calculate the iteration dose with small memory demand. In this paper, we present a dose calculation algorithm that approaches these goals. By decomposing the infinitesimal pencil beam (IPB) kernel into the central axis (CAX) component and lateral spread function (LSF) and taking the beam's eye view (BEV), we established a non-voxel and non-beamlet-based dose calculation formula. Both LSF and CAX are determined by a commissioning procedure using the collapsed-cone convolution/superposition (CCCS) method as the standard dose engine. The proposed dose calculation involves a 2D convolution of a fluence map with LSF followed by ray tracing based on the CAX lookup table with radiological distance and divergence correction, resulting in complexity of O(N"3) both spatially and temporally. This simple algorithm is orders of magnitude faster than the CCCS method. Without ...

2010-12-07

124

Extension of the EQ3/6 computer codes to geochemical modeling of brines  

Energy Technology Data Exchange (ETDEWEB)

Recent modifications to the EQ3/6 geochemical modeling software package provide for the use of Pitzer's equations to calculate the activity coefficients of aqueous species and the activity of water. These changes extend the range of solute concentrations over which the codes can be used to dependably calculate equilibria in geochemical systems, and permit the inclusion of ion pairs, complexes, and undissociated acids and bases as explicit component species in the Pitzer model. Comparisons of calculations made by the EQ3NR and EQ6 compuer codes with experimental data confirm that the modifications not only allow the codes to accurately evaluate activity coefficients in concentrated solutions, but also permit prediction of solubility limits of evaporite minerals in brines at 25/sup 0/C and elevated temperatures. Calculations for a few salts can be made at temperatures up to approx. 300/sup 0/C, but the temperature range for most ...

1984-10-23

125

Electric power system design: The NEC and the IEC approach  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to compare the techniques and results obtained when a general industrial or commercial building power electrical system is prepared using the US National Electrical Code{copyright} (NEC) and the International Electrotechnical Commission (IEC) Standards. The final design offer the reader the possibility of making an initial comparison and analyzation of the two methods based of their overall effectiveness (sizing, protection, co-ordination of protective devices with components etc.), safety and cost. In order to make such a comparison a specific example was developed and limited in detail to avoid complexity in this study. The power source selected will be a delta-wye utility supplied transformer feeding various load groups such as lighting and motor circuits (possibly through associated transformers). Relevant NE Code references, IEC standards, and appropriate justifications will be made at various points. Since ...

1995-12-31

126

EPR investigation of some irradiated traditional oriental spices  

International Nuclear Information System (INIS)

The X-band EPR spectra of unirradiated and "6"0 Co gamma ray irradiated cardamom (Elettaria cardamomum L. Maton, Zingiberaceae), ginger ((Zingiber officinale Rosc., Zingiberaceae), saffron (Crocus sativus L., Iridaceae), and curry have been investigated at room temperature. All unirradiated spices presented a weak resonance line with g-factors around free-electron ones, most probably due to the presence of semiquinones, previously reported to have paramagnetic properties. After gamma ray irradiation at absorbed dose up to 11.3 kGy we have noticed in all spices the presence of complex EPR spectra consisting of a superposition of at last two different paramagnetic species whose amplitude increase monotonously with the absorbed dose. A 100 deg. C isothermal annealing of 11.3 kGy irradiated samples has shown a differential reduction of amplitude of various components that form the initial spectra, but even after 5 h of thermal treatment, the ...

2005-09-13

127

Chemical source identifications for natural resource injury/damage assessments and site assessments  

International Nuclear Information System (INIS)

Current regulations guiding technical aspects of natural resource damage assessments combine source, exposure pathway, resource injury, and monetary damage components. In order to associate any observed injury to the uncontrolled release of chemicals (e.g. oil spills, contaminated sediments, in-place toxics, etc.), it is important to link the chemical ''release'' to the injured resource. In complex environmental settings where multiple sources of similar chemicals are combined, multicomponent chemical methods must be used to link the release to the environmental distribution of chemicals. Three examples of the utility of multicomponent organic chemical analyses linked to comprehensive and representative sampling strategies will be discussed--the Shell Martinez Refinery oil spill, the Exxon Valdez oil spill, and a contaminated sediment assessment. These NRDA-based source identifications are based on use of polycyclic aromatic hydrocarbons, ...

1993-11-14

128

An improved soft switched PWM interleaved boost AC-DC converter  

International Nuclear Information System (INIS)

In this paper, an improved soft switched two cell interleaved boost AC/DC converter with high power factor is proposed and investigated. A new auxiliary circuit is designed and added to two cell interleaved boost converter to reduce the switching losses. The proposed auxiliary circuit is implemented using only one auxiliary switch and a minimum number of passive components without an important increase in the cost and complexity of the converter. The main advantage of this auxiliary circuit is that it not only provides zero-voltage-transition (ZVT) for the main switches but also provides soft switching for the auxiliary switch and diodes. Though all semiconductor devices operate under soft switching, they do not have any additional voltage and current stresses. The proposed converter operates successfully in soft switching operation mode for a wide range of input voltage level and the load. In addition, it has advantages such as fewer structure ...

2011-01-01

129

Advanced solution algorithms for transient multidimensional thermohydraulic flow problems in complex geometries with the programme COMMIX-2/KfK  

Energy Technology Data Exchange (ETDEWEB)

The computer programme COMMIX-2 describes steady state and transient multidimensional single- and two-phase fluid flows with heat transfer in nuclear reactor components and multicomponent systems. Originally from the Argonne National Laboratory, the code has been further developed at the Kernforschungszentrum Karlsruhe. The original Point-SOR iterative method for the solution of a Poisson-like equation describing the pressure distribution in the fluid as well as the transport of enthalpy and turbulent quantities has been complemented with iterative and direct line- and block-methods. None of the newly implemented methods is original in itself but their implementation into the computer code, which can describe the most general shapes of definition domains, gave a code speed-up by a factor of 2-5, depending on the problem treated. The code capabilities are assessd by the calculation of a benchmark problem involving the numerical simulation of thermal buoyancy ...

1987-03-01

130

Advanced solution algorithms for transient multidimensional thermohydraulic flow problems in complex geometries with the programme COMMIX-2/KfK  

International Nuclear Information System (INIS)

The computer programme COMMIX-2 describes steady state and transient multidimensional single- and two-phase fluid flows with heat transfer in nuclear reactor components and multicomponent systems. Originally from the Argonne National Laboratory, the code has been further developed at the Kernforschungszentrum Karlsruhe. The original Point-SOR iterative method for the solution of a Poisson-like equation describing the pressure distribution in the fluid as well as the transport of enthalpy and turbulent quantities has been complemented with iterative and direct line- and block-methods. None of the newly implemented methods is original in itself but their implementation into the computer code, which can describe the most general shapes of definition domains, gave a code speed-up by a factor of 2-5, depending on the problem treated. The code capabilities are assessd by the calculation of a benchmark problem involving the numerical simulation of thermal buoyancy ...

1987-01-01

131

Absence of linkage of apparently single gene mediated ADHD with the human syntenic region of the mouse mutant coloboma  

Energy Technology Data Exchange (ETDEWEB)

Attention deficit disorder (ADHD) is a complex biobehavioral phenotype which affects up to 8% of the general population and often impairs social, academic, and job performance. Its origins are heterogeneous, but a significant genetic component is suggested by family and twin studies. The murine strain, coloboma, displays a spontaneously hyperactive phenotype that is responsive to dextroamphetamine and has been proposed as a genetic model for ADHD. Coloboma is a semi-dominant mutation that is caused by a hemizygous deletion of the SNAP-25 and other genes on mouse chromosome 2q. To test the possibility that the human homolog of the mouse coloboma gene(s) could be responsible for ADHD, we have carried out linkage studies with polymorphic markers in the region syntenic to coloboma (20p11-p12). Five families in which the pattern of inheritance of ADHD appears to be autosomal dominant were studied. Segregation analysis of the traits studied suggested ...

1995-12-18

132

Computational Complexity of Cyclotomic Fast Fourier Transforms over Characteristic-2 Fields  

CERN Document Server

Cyclotomic fast Fourier transforms (CFFTs) are efficient implementations of discrete Fourier transforms over finite fields, which have widespread applications in cryptography and error control codes. They are of great interest because of their low multiplicative and overall complexities. However, their advantages are shown by inspection in the literature, and there is no asymptotic computational complexity analysis for CFFTs. Their high additive complexity also incurs difficulties in hardware implementations. In this paper, we derive the bounds for the multiplicative and additive complexities of CFFTs, respectively. Our results confirm that CFFTs have the smallest multiplicative complexities among all known algorithms while their additive complexities render them asymptotically suboptimal. However, CFFTs remain valuable as they have the smallest overall ...

2011-01-01

133

Complexing of vanadium(3) with chromotropic acid derivatives  

International Nuclear Information System (INIS)

A spectrophotometric study has been made of the complex formation of vanadium (3) with arsenazo(1), arsenazo(3) and some monosubstituted derivatives of chromotropic acid and sulphanylamides. In acid medium vanadium (3) reacts with each of these reagents to produce a 1:1 complex. Optimum conditions of the complex formation was found. The effect of H"+ on the complex formation of vanadium (3) with chromotropic acid derivatives was established. It was found by the graphical method that the formation of the complex is accompanied by the elimination of one proton. Patterns were found of the influence of the nature of substituents in the organic compound on the ionization constants of acid groups and stability of complexes. Molar extinction coefficients, equilibrium constants of the formation reactions and instability constants for the complexes ...

1976-01-01

134

Heat capacity of VT1-0 commercial titanium and VT5 and VT5-1 titanium base alloys at low temperature  

International Nuclear Information System (INIS)

The temperature dependences of the heat capacity of commercial titanium VT1-0 and alloys on its base, VT5 and VT5-1, have been derived in the temperature range of 4 to 290 K. For comparison, similar measurements have been conducted on pure titanium and specially prepared solid solutions on its base (Ti+3.7 at.% Al and Ti+0.82 at.% Sn). The measurement accuracy has been sufficient for comparing the results with calculation data. The obtained results are interpreted using the known concepts of the role of the mass of interstitial atoms and changes in the interatomic bond forces. It is shown that the phonon components of the molar heat capacities of solid solutions of Al in titanium have lower values in the entire temperature range, as compared to titanium. The corresponding differences are proportional to the Al concentrations. The lower molar heat capacity in the case of dissolution of Al is due to the low mass of the impurity atoms and stronger interatomic bonds in ...

1978-01-01

135

Coupled modeling of non-isothermal multiphase flow, solutetransport and reactive chemistry in porous and fractured media: 1. ModelDevelopment and Validation  

Energy Technology Data Exchange (ETDEWEB)

Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, mineral deposition, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. Here they present a numerical simulation model, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered. The model can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions is considered, such as aqueous complexation, gas dissolution/exsolution, cation exchange, and surface complexation. Mineral ...

1998-09-01

136

A lateral cephalometric study of craniofacial variation in Korean child twins  

International Nuclear Information System (INIS)

A study was performed to investigate the degree of similarities and differences in components of craniofacial complex between Korean twins and normal children by lateral cephalometric analysis. Dimensions of S-N, S-Ba, N-Ba, Go-Me, Ar-Go and Ar-Me were plotted against linear measurement and angles of N-S-Ba and gonial against angular measurement in twins and control groups. The lateral cephalograms of twin were composed of 88 twins aged from 7 to 12:44 males aged 10.65 and 44 females aged 9. 55, while those of 50 normalities were composed of 25 male and 25 female aged 10.9 respectively. In order to analyze growth proportion and sexual differences, twins were divided into 3 groups according to two year age intervals and the author compared male with female in 3 groups. For the purpose of observing similarities and differences in twins and normalities by sex, total twins were compared with normalities. The obtained results were as follows: 1. ...

1974-11-01

139

Search for the active components and studies on the mechanism of the hematopoiesis improvement foods  

Energy Technology Data Exchange (ETDEWEB)

In this experiments, we established long-termed culture methods of bone marrow stromal cells for proliferation and differentiation of stem cells. And we selected some extracts which support maximal proliferation of stromal cells with this method. We conformed the synergic effects of herval mixture extracts for stromal cell growth. The proliferation of stromal cells was increased rather by the addition of mixture extracts than by addition of single strain extract. In the previous and cooperative experiments, we selected complex extracts which increased the number of nonadherent mononuclear cells. Different cytokine expression patterns were observed stromal cells cultured in the presence or absence of mixture extracts which support differentiation of nonadherent cells. Stimulation of macrophage cell line with herval extracts with the treatments of recombinant interferon-{gamma} resulted in increased nitric oxide synthesis in a dose-dependent manners. In addition, ...

1999-04-01

140

Open test assembly (OTA) shear demonstration testing work/test plan  

Energy Technology Data Exchange (ETDEWEB)

This document describes the development testing phase associated with the OTA Shear activity and defines the controls to be in place throughout the testing. The purpose of the OTA Shear Program was to provide equipment that is needed for the processing of 40 foot long, sodium wetted, irradiated core components previously used in the FFTF reactor to monitor fuel and materials tests. There are currently 15 of these OTA test stalks located in the Test Assembly Conditioning Station (TACS) inerted vault. These need to be dispositioned for a shutdown mission to eliminate this highly activated, high dose inventory prior to turnover to the ERC since they must be handled by remote operations. These would also need to be dispositioned for a restart mission to free up the vault they currently reside in. The waste handling and cleaning equipment in the J33M Cell was designed and built for the handling of reactor components up to the standard 12 foot ...

1998-07-16

141

Development of functional foods for radiation workers - Search for the active components and studies on the mechanism of the hematopoiesis improvement foods  

Energy Technology Data Exchange (ETDEWEB)

In this experiments, we established long-termed culture methods of bone marrow stromal cells for proliferation and differentiation of stem cells. And we selected some extracts which support maximal proliferation of stromal cells with this method. We conformed the synergic effects of herbal mixture extracts for stromal cell growth. The proliferation of stromal cells was increased rather by the addition of mixture extracts than by addition of single strain extract. In the previous and cooperative experiments, we selected complex extracts (Him-I, Him-II) which increased the number of nonadherent mononuclear cells. Different cytokine expression patterns were observed stromal cells cultured in the presence or absence of mixture extracts which support differentiation of nonadherent cells. Some fractions of Him-I and Him-II increased the proliferation of bone marrow cells irradiated {gamma}-ray(4Gray). Stimulation of macrophage cell line with herval extracts with the ...

2000-04-01

142

Cloning of human basic A1, a distinct 59-kDa dystrophin-associated protein encoded on chromosome 8q23-24  

Energy Technology Data Exchange (ETDEWEB)

Duchenne and Becker muscular dystrophies are caused by defects of dystrophin, which forms a part of the membrane cytoskeleton of specialized cells such as muscle. It has been previously shown that the dystrophin-associated protein A1 (59-kDa DAP) is actually a heterogeneous group of phosphorylated proteins consisting of an acidic ({alpha}-A1) and a distinct basic ({beta}-A1) component. Partial peptide sequence of the A1 complex purified from rabbit muscle permitted the design of oligonucleotide probes that were used to isolate a cDNA for one human isoform of A1. This cDNA encodes a basic A1 isoform that is distinct from the recently described syntrophins in Torpedo and mouse and is expressed in many tissues with at least five distinct mRNA species of 5.9, 4.8, 4.3, 3.1, and 1.5 kb. A comparison of the human cDNA sequence with the GenBank expressed sequence tag (EST) data base has identified a relative from human skeletal muscle, EST25263, which ...

1994-05-10

143

Chelation of intracellular calcium blocks insulin action in the adipocyte  

Energy Technology Data Exchange (ETDEWEB)

The hypothesis that intracellular Ca/sup 2 +/ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca/sup 2 +/ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl/sub 2/ and the Ca/sup 2 +/ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl/sub 2/ from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. Quin-2 loading also inhibited insulin-stimulated glucose oxidation and the ability of insulin to inhibit cAMP-stimulated lipolysis without affecting their basal activities. Incubation of cells with 100 ..mu..M ...

1987-02-01

144

Chelation of intracellular calcium blocks insulin action in the adipocyte  

International Nuclear Information System (INIS)

The hypothesis that intracellular Ca"2"+ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca"2"+ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl_2 and the Ca"2"+ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl_2 from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. Quin-2 loading also inhibited insulin-stimulated glucose oxidation and the ability of insulin to inhibit cAMP-stimulated lipolysis without affecting their basal activities. Incubation of cells with 100 #mu#M quin-2 or quin-2 AM had no ...

145

Assessing radiologic risk for population due to human activities  

International Nuclear Information System (INIS)

The most important factor in assessing radiologic risk is ensuring scientific means for evaluation of the radioactive release impact upon humans and organisms. To evaluate quantitatively this impact not only knowledge of radioactivity distribution in these dynamical systems is necessary but also understanding the transfer mechanisms between ecosystem components is needed. Thus a complete radioecologic study appear to be very complex and needs defining the source term, dynamic description of radionuclides behavior in the ecosystem, estimation of radiation doses in the major components of the ecosystem and finally the effects of radiation doses upon different parts of the systems. A diagram of the steps implied in evaluation of the effects due to radioactive effluent release in the environment is presented and discussed. The following steps are described: - identification of radioactive sources, as well as their input rate. ...

2002-09-06

147

Ceramic inspection system  

Science.gov (United States)

A system for inspecting a ceramic component. The ceramic component is positioned on a first rotary table. The first rotary table rotates the ceramic component. Light is directed toward the first rotary table and the rotating ceramic component. A detector is located on a second rotary table. The second rotary table is operably connected to the first rotary table and the rotating ceramic component. The second rotary table is used to move the detector at an angle to the first rotary table and the rotating ceramic component.

2006-05-16

148

Stable halogen complexes of astatine cations in aqueous solutions  

International Nuclear Information System (INIS)

Halide complexes of astatine cations At"+ and AtO"+ were prepared and their rate of migration was measured. The complexes are of the type AtX_2"- and AtOX_2"- (X = Cl"-, Br"-, I"-). The bromo complexes, AtBr_2"- and AtOBr_2"-, have a higher stability than the chloro complexes. The hydrolysis in weakly alkaline solution of AtX_2"- resulted At"-, and that of AtOX_2"- AtO_2"-. (author).

149

The complexity of gene expression dynamics revealed by permutation entropy  

UK PubMed Central (United Kingdom)

BackgroundHigh complexity is considered a hallmark of living systems. Here we investigate the complexity of temporal gene expression patterns using the concept of Permutation Entropy...Full Text Available

150

Subunits of the Drosophila CCR4-NOT complex and their roles in mRNA deadenylation  

UK PubMed Central (United Kingdom)

The CCR4-NOT complex is the main enzyme catalyzing the deadenylation of mRNA. We have investigated the composition of this complex in Drosophila melanogaster by immunoprecipitation...Full Text Available

2010-07-01

151

Rapamycin inhibits trypanosome cell growth by preventing TOR complex 2 formation  

UK PubMed Central (United Kingdom)

Target of rapamycin (TOR) kinases control cell growth through two functionally distinct multiprotein complexes. TOR complex 1 (TORC1) controls temporal cell growth and is sensitive to rapamycin, whereas...Full Text Available

2008-09-23

152

Photochemistry and charge transfer chemistry of the platinum group elements  

Energy Technology Data Exchange (ETDEWEB)

During the past 3 years, progress was made in elucidating the excited state structures of Pt(diimine)(dithiolate) complexes, while more recent efforts focused on the photochemistry of these complexes and electronic structure of other dithiolate systems. A carbonyl-Ir-maleonitrile dithiolate complex is also studied.

1992-12-01

153

On the ease of predicting the thermodynamic properties of beta-cyclodextrin inclusion complexes  

UK PubMed Central (United Kingdom)

BackgroundIn this study we investigated the predictability of three thermodynamic quantities related to complex formation. As a model system we chose the host-guest complexes of...Full Text Available

154

Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump  

UK PubMed Central (United Kingdom)

Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes...Full Text Available

2008-09-02

155

Application of ?- and ?-Isomerism of Octahedral Metal Complexes for Inducing Chiral Nematic Phases  

UK PubMed Central (United Kingdom)

The Δ- and Λ-isomerism of octahedral metal complexes is employed as a source of chirality for inducing chiral nematic phases. By applying a wide range of chiral metal complexes as a...Full Text Available

156

Targeting a Ruthenium Complex to the Nucleus with Short Peptides  

UK PubMed Central (United Kingdom)

In an effort to develop octahedral metal complexes as chemotherapeutic and diagnostic agents targeted to DNA, it is critical to optimize the properties of their cellular uptake. Appending d-octaarginine...Full Text Available

2010-05-15

158

General Disclaimer One or more of the Following Statements may ...  

Science.gov (United States)

complexe sur paroi non-isotherme, LContri5ution to the Study thermal ... paroi chaude essentiellement non-isotherme, LVaporization in a Complex ...

159

Catalytic hydration of alkynes with platinum(II) complexes  

Energy Technology Data Exchange (ETDEWEB)

Platinum(II) complexes have been investigated in the hydration of alkynes. These catalysts offer improved regioselectivity over Hg(II) counterparts. 1 fig., 2 tabs.

1993-12-17

160

AN EVALUATION OF AN IMPORTANT ADVANCE IN ...  

Science.gov (United States)

... No. 52. Metal Complexes-I. Preparation and Physical Properties of Transition Metal Complexes of 6-Mercaptopurine and 4-Mercapto-6, 7-Diphenyl ...

1965-03-01

161

Carbon fibers and composites modified by intercalation  

International Nuclear Information System (INIS)

The aim of this paper was to describe ability to intercalation of laboratory prepared carbon composites and their constituents. In work the following materials were tested; pinch-based fibres of P-120 and K-1100 manufacturer's designations, carbon matrix and resulting composites. To prepare a matrix of composites, phenol-formaldehyde resin (Z) and pinch-based precursor (PAK) were used. After initial carbonization, the carbon matrix was heated to 2150 "oC i to improve ability to the future intercalation. Three kinds of composites (P/Z, K/Z and K/PAK), with two directional reinforcement (2D), were prepared. All carbon samples were intercalated with copper chloride(II). To study the structure of all materials, before and after intercalation, X-ray diffraction method was used. It enabled to measure microstructure parameters (L_c and L_a), interplanar distance (d_0_0_2) thickness of an intercalation layer (d_i). Before intercalation, graphite fibers are characterized by well developed ...

162

ELECTRONIC COMPONENT COOLING ALTERNATIVES: COMPRESSED AIR AND LIQUID NITROGEN  

Science.gov (United States)

The goal of this study was to evaluate topics used to troubleshoot circuit boards with known or suspected thermally intermittent components. Failure modes for thermally intermittent components are typically mechanical defects, such as cracks in solder paths or joints, or broken b...

167

The complexities of skeletal biology  

Science.gov (United States)

For a long time, the skeleton was seen as an amorphous tissue of little biological interest. But

2003-01-01

169

Radionuclides Migration Prevention  

International Science & Technology Center (ISTC)

Prevention of Radionuclide Migration from the Soil of Semipalatinsk Nuclear Test Site by Using of Interpolymer Complexes

170

Preparation of radioactive lead complexes utilizing Chelex methodology  

Energy Technology Data Exchange (ETDEWEB)

The use of Chelex resin for the synthesis of radioactive lead complexes has been explored. The process involved immobilization of {sup 203}Pb on the resin and subsequent elution of complexed lead by chelating agents. {sup 203}Pb complexes derived from meso- and racemic dimercaptosuccinic acid (meso-DMSA, rac-DMSA) were prepared and assessed for stability in vitro.

1996-11-01

171

Preparation of radioactive lead complexes utilizing Chelex methodology  

International Nuclear Information System (INIS)

The use of Chelex resin for the synthesis of radioactive lead complexes has been explored. The process involved immobilization of "2"0"3Pb on the resin and subsequent elution of complexed lead by chelating agents. "2"0"3Pb complexes derived from meso- and racemic dimercaptosuccinic acid (meso-DMSA, rac-DMSA) were prepared and assessed for stability in vitro.

1996-11-01

172

Permutation Complexity Related to the Letter Doubling Map  

CERN Document Server

Given a countable set X (usually taken to be the natural numbers or integers), an infinite permutation, \\pi, of X is a linear ordering of X. This paper investigates the combinatorial complexity of infinite permutations on the natural numbers associated with the image of uniformly recurrent aperiodic binary words under the letter doubling map. An upper bound for the complexity is found for general words, and a formula for the complexity is established for the Sturmian words and the Thue-Morse word.

2011-01-01

173

Organic electronic conductors and precursors. Pt. 15. Novel dithiolene-nickel complexes based on benzenehexathiolate derivatives  

Energy Technology Data Exchange (ETDEWEB)

Dithiolato-nickel complexes with multisulfur ligands derived from benzenehexathiolate have been synthesized. The properties of the monomeric and polymeric complexes have been characterized by ESR spectroscopic and magnetochemical data and by electrical conductivity measurements. The prepared complexes are paramagnetic and have characteristic absorptions between 800 and 1000 nm. (orig.).

1992-04-01

175

Mo"5 and W"5 complexing with tri-tret-butyl phenyl ether of 1.2-naphthoquinonediazide-(2)-5-sulfochloride  

International Nuclear Information System (INIS)

The complexing of paramagnetic salts of molybdenum and tungsten with tri-tert-butylphenyl ester of 1,2-naphthoquinone-diazide-(2)-5-sulfochloride is studied by PMR and EPR methods. From the changes of half-widths of lines in PMR spectra and analysis of g-factor in EPR spectra, the kinetic and thermodynamic parameters of the complexing are determined, and the composition of the complexes formed is established, and the schemes of their formation are suggested.

177

Fluorescent Silicate Materials for the Detection of Paraoxon  

Science.gov (United States)

... significantly lower limits of detection. The complex fluorescence spectra of these constructs indicated that only a portion ...

2010-03-19

182
183

Complex Abdominal Wall Repair  

Medline Plus

... presentation will be archived on the OR-Live website. 00:46:02 ANNOUNCER: This has been a ...

184

Calculation of some energetic parameters of astatine compounds  

International Nuclear Information System (INIS)

... astatine complexes astatine compounds coulomb energy effective charge

188

,>22u  

Science.gov (United States)

(Watkins and. Corbett,. 1964) which is a phosphorous-vacancy complex, i.e., ...... Grover. 1965. Semiconductor. Surfaces. ...

189

Palladium polypyridyl complexes: synthesis, characterization, DNA interaction and biological activity on Leishmania (L.) mexicana  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the search for new potential chemotherapeutic agents based on transition metal complexes with planar ligands. In this study, palladium polypyridyl complexes were synthesized and characterized by elemental analysis, NMR, UV-VIS and IR spectroscopies. The interaction of the complexes with DNA was also investigated by spectroscopic methods. All metal-to-ligand charge transfer (MLCT) bands of the palladium polypyridyl complexes exhibited hypochromism and red shift in the presence of DNA. The binding constant and viscosity data suggested that the complexes [PdCl{sub 2}(phen)] and [PdCl{sub 2}(phendiamine)] interact with DNA by electrostatic forces. Additionally, these complexes induced an important leishmanistatic effect on L. (L.) mexicana promastigotes at the final concentration of 10 {mu}mol L{sup -1} in 48 h. (author)

2008-07-01

190

Behavior of Np(VII, VI, V) in Silicate Solutions  

Energy Technology Data Exchange (ETDEWEB)

Spectrophotometric methods were used to investigate the properties of neptunium(VII), (VI), and (V) in silicate solution. The transition of cationic neptunium(VII) to anionic species in non-complexing environments proceeds in the range of ?? 5.5 to 7.5. In the presence of carbonate, this transition occurs at ?? 10.0 to 11.5 and in silicate solutions at ?? 10.5-12.0. These findings show that cationic neptunium(VII) forms complexes with both carbonate and silicate and that the silicate complex is stronger than that of the carbonate. The competition of complex formation reactions for neptunium(VI) with carbonate and silicate and on the known complex stability constant of NpO2(CO3)34- allowed the NpO2SiO3 complex stability constant, log ? = 16.5, to be estimated. Determination of the formation constant of Np(V) complexes with SiO32- was not ...

2004-11-30

191

Achieving a vanishing SNR-gap to exact lattice decoding at a subexponential complexity  

CERN Document Server

The work identifies the first lattice decoding solution that achieves, in the general outage-limited MIMO setting and in the high-rate and high-SNR limit, both a vanishing gap to the error-performance of the (DMT optimal) exact solution of preprocessed lattice decoding, as well as a computational complexity that is subexponential in the number of codeword bits. The proposed solution employs lattice reduction (LR)-aided regularized (lattice) sphere decoding and proper timeout policies. These performance and complexity guarantees hold for most MIMO scenarios, all reasonable fading statistics, all channel dimensions and all full-rate lattice codes. In sharp contrast to the above manageable complexity, the complexity of other standard preprocessed lattice decoding solutions is shown here to be extremely high. Specifically the work is first to quantify the complexity of these lattice ...

2011-01-01

192

Redox reactions of Cu(II)-amine complexes in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

A number of amines can be employed for all volatile treatment (AVT) of steam generator (SG) systems of nuclear power reactors. These amines form complexes with Cu{sup 2+} and Ni{sup 2+} ions which come into water due to corrosion. The redox reactions of a number of Cu(II)-AVT amine complexes and the stability of the transient species formed have been studied by pulse radiolysis technique. Rate constants for the reaction of e{sub aq}{sup -} with a number of Cu(II)-amine complexes have been determined by following the decay of e{sub aq}{sup -} absorption. Stability of Cu(I)-amine complexes was studied by following the kinetics of the bleaching signal formed at the {lambda}{sub max} of the Cu(II) amine complex. Except for Cu(I)-triethanolamine complex all other Cu(I)-amine complexes were found to be stable. One-electron oxidation of Cu(II) ...

2003-03-01

193

Biophysical analysis of DNA modified by 1,2-diaminocyclohexane platinum(II) complexes  

Energy Technology Data Exchange (ETDEWEB)

Modification of DNA and double-stranded deoxyoligonucleotides with antitumor 1,2-diamino-cyclohexanedinitroplatinum(II) (Pt-dach) complexes was investigated with the aid of physico-chemical methods and chemical probes of nucleic acid conformation. The three Pt-dach complexes were used which differed in isomeric forms of the dach non-leaving ligand-Pt(1R,2R-dach), Pt(1S,2S-dach) and Pt(1R,2S-dach) complexes. The latter complex has lower antitumor activity than the other two Pt-dach complexes. Pt(1R,2S-dach) complex exhibits the slowest kinetics of its binding to DNA and of the conversion of monofunctional binding to bifunctional lesions. The anomalously slow electrophoretic mobility of multimers of the platinated and ligated oligomers suggests that bifunctional binding of Pt-dach complexes to a d(GG) site within double-stranded ...

1992-01-25

194

Fermilab Steering Group Report  

Energy Technology Data Exchange (ETDEWEB)

The Fermilab Steering Group has developed a plan to keep U.S. accelerator-based particle physics on the pathway to discovery, both at the Terascale with the LHC and the ILC and in the domain of neutrinos and precision physics with a high-intensity accelerator. The plan puts discovering Terascale physics with the LHC and the ILC as Fermilab's highest priority. While supporting ILC development, the plan creates opportunities for exciting science at the intensity frontier. If the ILC remains near the Global Design Effort's technically driven timeline, Fermilab would continue neutrino science with the NOVA experiment, using the NuMI (Neutrinos at the Main Injector) proton plan, scheduled to begin operating in 2011. If ILC construction must wait somewhat longer, Fermilab's plan proposes SNuMI, an upgrade of NuMI to create a more powerful neutrino beam. If the ILC start is postponed significantly, a central feature of the proposed Fermilab plan calls for building ...

2007-01-01

195

The effect of phosphonic acid substituents on europium(III) complex stability in acidic solutions  

Science.gov (United States)

The thermodynamics of protonation and europium(III) complex formation with substituted methane diphosphonic acids have been reported recently. These ligands form strong complexes with europium in moderately acidic solutions ((H{sup +}) {ge} 0.1 M), conditions not conducive to complexation by most carboxylate and aminopolycarboxylate ligands. A correlation of log {beta} vs pK{sub a} values for phosphonate and carboxylate ligands is used to explore the effect of ligand structure on complex stability. 5 refs., 1 fig.

1990-01-01

196

Mechanism of the metal-mediated carbalkoxylation of vinyl electrophiles. 1. Preparation, molecular structure, and alcoholysis of vinylic acyl platinum(II) complexes  

Energy Technology Data Exchange (ETDEWEB)

Carbalkoxylation of vinyl electrophiles was investigated using platinum complexes. This reaction occurs in two steps: (a) carbonyl insertion of {sigma}-vinyl Pt(II) halides and (b) alcoholysis of vinylic acyl Pt(II) complexes. Alcoholysis of vinylic acyl Pt(II) triflate complexes is investigated kinetically. Vinylic acyl Pt(II) complexes were isolated and characterized. 51 refs., 5 figs., 6 tabs.

1992-03-01

197

Investigation of formation of Sn-PM tetracycline and Sn-PM-tetracycline-_9_9Tc complexes  

International Nuclear Information System (INIS)

The formation and stability constants of the [sup(99m)Tc]PM tetracycline have been investigated by the potentiometric method. The pK value of the complex formed was measured as pK = 5.49 +- 0.19. The spectrophotometric study has been performed on the formation of a complex of Sn(II) and TcO"4"- in the presence of PM Tetracycline. This study shows that Sn(II) forms with PMT a complex at a mole ratio of 1:1. The molar extinction coefficients of the Sn-PMT and [_9_9Tc]PMT complexes have been measured. (author).

1983-01-01

198

First investigations of complex formation of At(I) with phosphorous organic compounds  

Energy Technology Data Exchange (ETDEWEB)

Reaction of At(I) with triphenylphosphine, triethylphosphite and tri-n-octylphosphine oxide was investigated in ethanolic solution by means of electromigration. A cationic complex with triphenylphosphine was identified being stable at pH = 1,9 in the concentration range of the ligand between c = 10{sup -5} to 10{sup -3} M. At a higher ligand concentration and at pH>2, the reduction effect of phosphine is superimposed on the complex formation. Complex formation is confirmed by ligand exchange reactions with Br{sup -} and I{sup -}. A comparatively weak complex is formed by triethylphosphite and At(I). No compound is formed by tri-n-octylphosphine oxide and At(I). (orig.).

1989-01-01

199

First investigations of complex formation of At(I) with phosphorous organic compounds  

International Nuclear Information System (INIS)

Reaction of At(I) with triphenylphosphine, triethylphosphite and tri-n-octylphosphine oxide was investigated in ethanolic solution by means of electromigration. A cationic complex with triphenylphosphine was identified being stable at pH = 1,9 in the concentration range of the ligand between c = 10"-"5 to 10"-"3 M. At a higher ligand concentration and at pH>2, the reduction effect of phosphine is superimposed on the complex formation. Complex formation is confirmed by ligand exchange reactions with Br"- and I"-. A comparatively weak complex is formed by triethylphosphite and At(I). No compound is formed by tri-n-octylphosphine oxide and At(I). (orig.).

200

Validation of the Canadian atmospheric dispersion model for small exclusion area boundaries  

International Nuclear Information System (INIS)

AECL is undertaking the validation of ADDAM, an atmospheric dispersion and dose code based on the Canadian Standards Association model CSA N288.2. The key component of the validation program involves the comparison of air concentrations predicted by the model with measured values. Measurements are available from field studies at two Canadian reactor sites and from a wind tunnel study of the CANDU site at Wol song, Korea. The measurements were obtained close enough to the release points to test the model for exclusion area boundaries as small as 500 m. Model predictions were higher than the observations almost 75 percent of the time and the magnitude of the over predictions was typically much larger than the magnitude of the under predictions. The effect of the topography at the Wol song site was limited to small changes in plume trajectory due to channeling in valleys and a small reduction in the lateral spread of the plume. The terrain did not substantially ...

1999-11-04

201

Unbundling services in a competitive electricity market  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this presentation is to provide an in-depth discussion of the possible evolution of unbundling of services in a competitive environment. The author discusses unbundling from both a technical/engineering and an economic perspective. The main thrust of the talk is threefold: (a) that in the long run the potential for unbundling of services is extremely large from an engineering perspective; (b) that the form of the initial industry structure will have an important impact on the extent of service unbundling; and (c) that unbundling of wholesale related services is where most of the initial demand will be. (A) Engineering Perspectives on Unbundling: A large proportion of ancillary services can be provided in a competitive framework with current technologies. The author discusses those that current technologies may not facilitate such a decentralized approach. (B) The relation between unbundling and industry structure: Not all industry structures provide the same incentives ...

1996-03-01

202

Transmit-receive eddy current probes  

International Nuclear Information System (INIS)

In the last two decades, due to increased inspection demands, eddy current instrumentation has advanced from single-frequency, single-output instruments to multifrequency, computer-aided systems. This has significantly increased the scope of eddy current testing, but, unfortunately, it has also increased the cost and complexity of inspections. In addition, this approach has not always improved defect detectability or signal-to-noise. Most eddy current testing applications are still performed with impedance probes, which have well known limitations. However, recent research at AECL has led to improved eddy current inspections through the design and development of transmit-receive (T/R) probes. T/R eddy current probes, with laterally displaced transmit and receive coils, present a number of advantages over impedance probes. They have improved signal-to-noise ratio in the presence of variable lift-off compared to impedance probes. They have strong directional ...

1997-10-27

203

Towards an objective evaluation of tolerances for beam modeling in a treatment planning system  

International Nuclear Information System (INIS)

The performance of a convolution/superposition based treatment planning system depends on the ability of the dose calculation algorithm to accurately account for physical interactions taking place in the tissue, key components of the linac head and on the accuracy of the photon beam model. Generally the user has little or no control over the performance of the dose calculation algorithm but is responsible for the accuracy of the beam model within the constraints imposed by the system. This study explores the dosimetric impact of limitations in photon beam modeling accuracy on complex 3D clinical treatment plans. A total of 70 photon beam models was created in the Pinnacle(TM) treatment planning system. Two of the models served as references for 6 MV and 15 MV beams, while the rest were created by perturbing the reference models in order to produce specific deviations in specific regions of the calculated dose profiles (central axis and ...

2007-09-21

204

The use of dynamic adaptive chemistry in combustion simulation of gasoline surrogate fuels  

Energy Technology Data Exchange (ETDEWEB)

A computationally efficient dynamic adaptive chemistry (DAC) scheme is described that permits on-the-fly mechanism reduction during reactive flow calculations. The scheme reduces a globally valid full mechanism to a locally, instantaneously applicable smaller mechanism. Previously we demonstrated its applicability to homogeneous charge compression ignition (HCCI) problems with n-heptane [L. Liang, J.G. Stevens, J.T. Farrell, Proc. Combust. Inst. 32 (2009) 527-534]. In this work we demonstrate the broader utility of the DAC scheme through the simulation of HCCI and shock tube ignition delay times (IDT) for three gasoline surrogates, including two- and three-component blends of primary reference fuels (PRF) and toluene reference fuels (TRF). Both a detailed 1099-species mechanism and a skeletal 150-species mechanism are investigated as the full mechanism to explore the impact of fuel complexity on the DAC scheme. For all conditions studied, ...

2009-07-15

205

The p75"N"T"R tumor suppressor induces cell cycle arrest facilitating caspase mediated apoptosis in prostate tumor cells  

International Nuclear Information System (INIS)

The p75 neurotrophin receptor (p75"N"T"R) is a death receptor which belongs to the tumor necrosis factor receptor super-family of membrane proteins. This study shows that p75"N"T"R retarded cell cycle progression by induced accumulation of cells in G0/G1 and a reduction in the S phase of the cell cycle. The rescue of tumor cells from cell cycle progression by a death domain deleted (#DELTA#DD) dominant-negative antagonist of p75"N"T"R showed that the death domain transduced anti-proliferative activity in a ligand-independent manner. Conversely, addition of NGF ligand rescued retardation of cell cycle progression with commensurate changes in components of the cyclin/cdk holoenzyme complex. In the absence of ligand, p75"N"T"R-dependent cell cycle arrest facilitated an increase in apoptotic nuclear fragmentation of the prostate cancer cells. Apoptosis of p75"N"T"R expressing cells occurred via the intrinsic mitochondrial pathway leading to a ...

2006-03-24

206

The application of computer modeling to health effect research  

Energy Technology Data Exchange (ETDEWEB)

In the United States, estimates show that more than 30,000 hazardous waste disposal sites exist, not including military installations, U.S. Department of Energy nuclear facilities, and hundreds and thousands of underground fuel storage tanks; these sites undoubtedly have their own respective hazardous waste chemical problems. When so many sites contain hazardous chemicals, how does one study the health effects of the chemicals at these sites? There could be many different answers, but none would be perfect. For an area as complex and difficult as the study of chemical mixtures associated with hazardous waste disposal sites, there are no perfect approaches and protocols. Human exposure to chemicals, be it environmental or occupational, is rarely, if ever, limited to a single chemical. Therefore, it is essential that we consider multiple chemical effects and interactions in our risk assessment process. Systematic toxicity testing of chemical mixtures in the ...

1996-12-31

207

State-of-the-art review of computational fluid dynamics modeling for fluid-solids systems  

Energy Technology Data Exchange (ETDEWEB)

As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBRS) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the Clean Air Act Amendment (CAAA) of 1995. Solids motion is also ...

1994-05-12

208

Quantitative genetic activity graphical profiles for use in chemical evaluation  

International Nuclear Information System (INIS)

A graphic approach, terms a Genetic Activity Profile (GAP), was developed to display a matrix of data on the genetic and related effects of selected chemical agents. The profiles provide a visual overview of the quantitative (doses) and qualitative (test results) data for each chemical. Either the lowest effective dose or highest ineffective dose is recorded for each agent and bioassay. Up to 200 different test systems are represented across the GAP. Bioassay systems are organized according to the phylogeny of the test organisms and the end points of genetic activity. The methodology for producing and evaluating genetic activity profile was developed in collaboration with the International Agency for Research on Cancer (IARC). Data on individual chemicals were compiles by IARC and by the US Environmental Protection Agency (EPA). Data are available on 343 compounds selected from volumes 1-53 of the IARC Monographs and on 115 compounds identified as Superfund Priority Substances. ...

1990-06-27

209

Nonaqueous synthesis of metal oxide nanoparticles: Short review and doped titanium dioxide as case study for the preparation of transition metal-doped oxide nanoparticles  

Science.gov (United States)

The liquid-phase synthesis of metal oxide nanoparticles in organic solvents under exclusion of water is nowadays a well-established alternative to aqueous sol-gel chemistry. In this article, we highlight some of the advantages of these routes based on selected examples. The first part reviews some recent developments in the synthesis of ternary metal oxide nanoparticles by surfactant-free nonaqueous sol-gel routes, followed by the discussion of the morphology-controlled synthesis of lanthanum hydroxide nanoparticles, and the presentation of structural peculiarities of manganese oxide nanoparticles with an ordered Mn vacancy superstructure. These examples show that nonaqueous systems, on the one hand, allow the preparation of compositionally complex oxides, and, on the other hand, make use of the organic components (initially present or formed in situ) in the reaction mixture to tailor the morphology. Furthermore, obviously even the crystal ...

2008-07-15

210

Nanocrystal Bioassembly: Asymmetry, Proximity, and Enzymatic Manipulation  

Energy Technology Data Exchange (ETDEWEB)

Research at the interface between biomolecules and inorganic nanocrystals has resulted in a great number of new discoveries. In part this arises from the synergistic duality of the system: biomolecules may act as self-assembly agents for organizing inorganic nanocrystals into functional materials; alternatively, nanocrystals may act as microscopic or spectroscopic labels for elucidating the behavior of complex biomolecular systems. However, success in either of these functions relies heavily uponthe ability to control the conjugation and assembly processes.In the work presented here, we first design a branched DNA scaffold which allows hybridization of DNA-nanocrystal monoconjugates to form discrete assemblies. Importantly, the asymmetry of the branched scaffold allows the formation of asymmetric2assemblies of nanocrystals. In the context of a self-assembled device, this can be considered a step toward the ability to engineer functionally distinct inputs and ...

2008-05-01

211

Multiphase integral reacting flow computer code (ICOMFLO): User`s guide  

Energy Technology Data Exchange (ETDEWEB)

A copyrighted computational fluid dynamics computer code, ICOMFLO, has been developed for the simulation of multiphase reacting flows. The code solves conservation equations for gaseous species and droplets (or solid particles) of various sizes. General conservation laws, expressed by elliptic type partial differential equations, are used in conjunction with rate equations governing the mass, momentum, enthalpy, species, turbulent kinetic energy, and turbulent dissipation. Associated phenomenological submodels of the code include integral combustion, two parameter turbulence, particle evaporation, and interfacial submodels. A newly developed integral combustion submodel replacing an Arrhenius type differential reaction submodel has been implemented to improve numerical convergence and enhance numerical stability. A two parameter turbulence submodel is modified for both gas and solid phases. An evaporation submodel treats not only droplet evaporation but size dispersion. Interfacial ...

1997-11-01

212

Monte Carlo simulation and dosimetric verification of radiotherapy beam modifiers  

International Nuclear Information System (INIS)

Monte Carlo simulation of beam modifiers such as physical wedges and compensating filters has been performed with a rectilinear voxel geometry module. A modified version of the EGS4/DOSXYZ code has been developed for this purpose. The new implementations have been validated against the BEAM Monte Carlo code using its standard component modules (CMs) in several geometrical conditions. No significant disagreements were found within the statistical errors of 0.5% for photons and 2% for electrons. The clinical applicability and flexibility of the new version of the code has been assessed through an extensive verification versus dosimetric data. Both Varian multi-leaf collimator (MLC) wedges and standard wedges have been simulated and compared against experiments for 6 MV photon beams and different field sizes. Good agreement was found between calculated and measured depth doses and lateral dose profiles along both wedged and unwedged directions for different depths and ...

2001-11-01

213

Methodology for the development and the UML (unified modified language) simulation of data acquisition and data processing systems dedicated to high energy physics experiments; Methodologie de developpement et de modelisation UML des systemes d'acquisition et de traitement en temps reel pour les experiences de physique des hautes energies  

Energy Technology Data Exchange (ETDEWEB)

The increasing complexity of the real-time data acquisition and processing systems (TDAQ: the so called Trigger and Data AcQuisition systems) in high energy physics calls for an appropriate evolution of development tools. This work is about the interplay between in principle specifications of TDAQ systems and their actual design and realization on a concrete hardware and software platform. The basis of our work is to define a methodology for the development of TDAQ systems that meets the specific demands for the development of such systems. The result is the detailed specification of a 'methodological framework' based on the Unified Modeling Language (UML) and designed to manage a development process. The use of this UML-based methodological framework progressively leads to the setting up of a 'home-made' framework, i.e. a development tool that comprises reusable components and generic architectural elements ...

2002-09-01

214

Gene Repressive Activity of RIP140 Through Direct Interaction with CDK8.  

Science.gov (United States)

Receptor interacting protein 140 (RIP140) is a coregulator for numerous nuclear receptors and transcription factors and primarily exerts gene-repressive activities on various target genes. We previously identified a spectrum of posttranslational modifications on RIP140 that augment its property and biological activity. In T(3)-triggered biphasic regulation of cellular retinoic acid binding protein 1 (Crabp1) gene along the course of fibroblast-adipocyte differentiation, we found TRAP220(MED1) critical for T(3)-activated chromatin remodeling whereas RIP140 essential for T(3)-repressive chromatin remodeling of this gene promoter. In this current study, we aim to examine whether and how RIP140 replaces TRAP220(MED1) on the CrabpI promoter in differentiating adipocyte cultures. We find increasing recruitment of RIP140 to this promoter, with corresponding reduction in TRAP220(MED1) recruitment during the T(3)-repressive phase. We also uncover direct interaction of RIP140 with ...

2011-08-25

215

Functions of mammalian Cdc7 kinase in initiation/monitoring of DNA replication and development  

Energy Technology Data Exchange (ETDEWEB)

Cdc7 kinase plays an essential role in firing of replication origins by phosphorylating components of the replication complexes. Cdc7 kinase has also been implicated in S phase checkpoint signaling downstream of the ATR and Chk1 kinases. Inactivation of Cdc7 in yeast results in arrest of cell growth with 1C DNA content after completion of the ongoing DNA replication. In contrast, conditional inactivation of Cdc7 in undifferentiated mouse embryonic stem (ES) cells leads to growth arrest with rapid cessation of DNA synthesis, suggesting requirement of Cdc7 functions for continuation of ongoing DNA synthesis. Furthermore, loss of Cdc7 function induces recombinational repair (nuclear Rad51 foci) and G2/M checkpoint responses (inhibition of Cdc2 kinase). Eventually, p53 becomes highly activated and the cells undergo massive p53-dependent apoptosis. Thus, defective origin activation in mammalian cells can generate DNA replication checkpoint signals. ...

2003-11-27

216

Energy systems. Tome 3: advanced cycles, low environmental impact innovative systems  

International Nuclear Information System (INIS)

This third tome about energy systems completes the two previous ones by showing up advanced thermodynamical cycles, in particular having a low environmental impact, and by dealing with two other questions linked with the study of systems with a changing regime operation: - the time management of energy, with the use of thermal and pneumatic storage systems and time simulation (schedule for instance) of systems (solar energy type in particular); - the technological dimensioning and non-nominal regime operation studies. Because this last topic is particularly complex, new functionalities have been implemented mainly by using the external classes mechanism, which allows the user to freely personalize his models. This tome is illustrated with about 50 examples of cycles modelled with Thermoptim software. Content: foreword; 1 - generic external classes; 2 - advanced gas turbine cycles; 3 - evaporation-concentration, mechanical steam compression, desalination, hot gas ...

217

Electrochemical noise measurements of sustained microbially influenced pitting corrosion in a laboratory flow loop system.  

Energy Technology Data Exchange (ETDEWEB)

Because of the chaotic nature of the corrosion process and the complexity of the electrochemical noise signals that are generated, there is no generally accepted method of measuring and interpreting these signals that allows the consistent detection and identification of sustained localized pitting (SLP) as compared to general corrosion. We have reexamined electrochemical noise analysis (ENA) of localized corrosion using different hardware, signal collection, and signal processing designs than those used in conventional ENA techniques. The new data acquisition system was designed to identify and monitor the progress of SLP by analyzing the power spectral density (PSD) of the trend of the corrosion current noise level (CNL) and potential noise level (PNL). Each CNL and PNL data point was calculated from the root-mean- square value of the ac components of current and potential fluctuation signals, which were measured simultaneously during a short ...

1999-01-13

218

Characterizing explosives and blasting emissions  

Energy Technology Data Exchange (ETDEWEB)

With the advance of science, rise of public interest in environmental matters, and continuing erosion of air quality, Federal and state regulators are demanding an increasing complex array of data concerning emissions produced by burning and detonating energetic materials. The US Department of Defense, one of the world`s largest consumers of energetic materials, now must characterize combustion products resulting from open burning/open detonation disposal operations. The catch-all phrase ``below detection limits`` no longer satisfies the regulators who now want testing to delve into the ppt level for volatile organic compounds and ppt level for semivolatile organic compounds. Regulators are also expanding their scope of interest and may soon be asking for emissions data on training operations such as artillery firing. Providing this type of information is no longer an impossibility. The Army, as the single manager of conventional munitions for the three military ...

1995-12-31

219

Calibration free laser-induced breakdown spectroscopy of oxide materials  

Energy Technology Data Exchange (ETDEWEB)

The quantitative determination of oxide concentration by laser-induced breakdown spectroscopy is relevant in various fields of applications (e.g.: analysis of ores, concrete, slag). Calibration free laser-induced breakdown spectroscopy and the multivariate calibration are among the methods employed for quantitative concentration analysis of complex materials. We measured the intensity of neutral and ionized atomic emission lines of oxide materials by laser-induced breakdown spectroscopy and we modified the calibration free laser-induced breakdown spectroscopy method to increase the accuracy. The concentration of oxides was obtained by using stoichiometric relations. Sample materials were prepared from oxide powder (Fe{sub 2}O{sub 3}, MgO, CaO) by mixing and pressing. The concentration was 9.8-33.3 wt.% Fe{sub 2}O{sub 3}, 7.6-33.3 wt.% MgO and 33.3-81.2 wt.% CaO for different samples. Nd:YAG laser (wavelength 1064 nm, pulse duration {approx} 6 ns) ablation was ...

2010-08-15

220

CHEMICAL TECHNOLOGY DIVISION, UNIT OPERATIONS SECTION MONTHLY PROGRESS REPORT, JULY 1960  

Science.gov (United States)

A critical review of the literature revealed no experiments on uranyl ion transfer from an aqueous to a tributyl phosphate phase which positively measured the kinetics of the chemical reaction at the interphase. Drawing isorhythmic lines on a three component diagram gives a complex correlation for the compaction of three sizes of glass beads. Neither the use of thoria sols nor high feed solution concentrations of thorium nitrate gave any significant increase in mean particle diameters over those obtained from nitrate solutions of lower concentrations in flame denitration. A hydraulic film resistance has been detected in the anion exchange of uranyl sulfate into Dowex 2lK, and chloride elution was found to give a higher apparent uranium diffusion coefficient than nitrate elution. The rate of dissolution of mixed thorium-uranium oxides was determined as a function of the per cent of mixed oxides dissolved. Mixing in ...

1960-10-27

221

Assessment of Distribution and Decontamination Factor during Melt Decontamination of Scrap Metal Contaminated with Natural Uranium  

International Nuclear Information System (INIS)

Metal waste generated from domestic nuclear operation for defense and commercial application has led to a growing stockpile of radioactively contaminated scrap metal, much of which is stainless steel. A significant fraction of this material cannot be efficiently surface decontaminated. The burial of this material would be wasteful and expensive, since long term monitoring would be necessary in order to minimize environmental risk. Much of this waste consists of bulky equipment. In many case, this equipment contains valuable material that may be recycled. The piece of equipment considered frequently also has complex geometries, making extremely difficult, time-consuming and expensive to determine the exact location and level of radioactivity on the internal surfaces. After melting, however, the radioactivity may be precisely determined from samples of each ingot. Moreover, an ingot may be released for restricted or unrestricted reuse, or stored for decay to ...

2007-05-10

226

JAVA Stereo Display Toolkit  

Science.gov (United States)

This toolkit provides a common interface for displaying graphical user interface (GUI) components in

2008-01-01

227

Interstellar PAH Analogs in the Laboratory: Comparison with Astronomical Data  

Science.gov (United States)

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing

2005-01-01

228

Hardening process relating to the irradiation of active electronic components and large hardened components  

International Nuclear Information System (INIS)

A patent is claimed for the invention of a hardening (ionizing radiation resistance) process for MOS type components and CMOS or bipolar type components. The ionizing radiation effect on those systems is the electron-hole pair production, which induces interference phenomena. The MOS main structure is successively composed of a silicon substrate layer, a layer of an irradiation resistant material and a layer of partially monocrystalline silicon.

1988-12-09

229

FFTF and the ASME Code  

Science.gov (United States)

Photographs are presented of the FFTF reactor facility, components, and some materials.

1978-01-01

235

 

UK PubMed Central (United Kingdom)

Health surveillance program This article outlines the principal components of quality control of laboratory rodents.

1986-02-01

236

Humic substances in natural waters and their complexation with trace metals and radionuclides: a review. [129 references  

Energy Technology Data Exchange (ETDEWEB)

Dissolved humic substances (humic and fulvic acids) occur in surface waters and groundwaters in concentrations ranging from less than 1 mg(C)/L to more than 100 mg(C)/L. Humic substances are strong complexing agents for many trace metals in the environment and are also capable of forming stable soluble complexes or chelates with radionuclides. Concentrations of humic materials as low as 1 mg(C)/L can produce a detectable increase in the mobility of some actinide elements by forming soluble complexes that inhibit sorption of the radionuclides onto rock materials. The stability of trace metal- or radionuclide-organic complexes is commonly measured by an empirically determined conditional stability constant (K'), which is based on the ratio of complexed metal (radionuclide) in solution to the product concentration of uncomplexed metal and humic complexant. ...

1985-07-01

237

Thermal loads on tokamak plasma-facing components during normal operation and disruptions  

Energy Technology Data Exchange (ETDEWEB)

Power loadings experienced by tokamak plasma-facing components during normal operation and during off-normal events are discussed. A model for power and particle flow in the tokamak boundary layer is presented and model predictions are compared to infrared measurements of component heating. The inclusion of the full three-dimensional geometry of the components and of the magnetic flux surface is very important in the modeling. Experimental measurements show that misalignment of component armour tile surfaces by only a millimeter can lead to significant localized heating. An application to the design of plasma-facing components for future machines is presented. Finally, thermal loads expected during tokamak disruptions are discussed. The primary problems are surface melting and vaporization due to localized intense heating during the disruption thermal quench and volumetric heating ...

1990-01-01

238

SNRS component positioning systems  

Energy Technology Data Exchange (ETDEWEB)

This paper discusses the stationary neutron radiography system (SNRS) with respect to the component positioning systems (CPSs) and the rationale behind their design. As design work is on-going at Science Applications International Corporation, this report gives a current update of progress. The SNRS has four separate radiography bays, Bays 1 through 4. The first three bays have automated positioning systems for real-time and near real-time neutron radiography of aircraft components. Bay 4 has been designed to accommodate components from the solid rocket booster, but will be used first for film radiography of pyrotechnic components.

1987-01-01

239

SNRS (stationary neutron radiography system) component positioning systems  

Energy Technology Data Exchange (ETDEWEB)

This paper discusses the stationary neutron radiography system (SNRS) with respect to the component positioning systems (CPSs) and the rationale behind their design. As design work is on-going at science Applications International Corporation, this report gives a current update of progress. The SNRS has four separate radiography bays, Bays 1 through 4. The first three bays have automated positioning systems for real-time and near real-time neutron radiography of aircraft components. Bay 4 has been designed to accommodate components from the solid rocket booster, but will be used first for film radiography of pyrotechnic components.

1987-01-01

240

Critical phenomena in four-component systems  

Science.gov (United States)

This article examines problems relating to the calculation of the position of regions of limited solubility of components in the liquid state for four-component systems. An approach based on the use of criterion of stability with respect to diffusion for obtaining equations which describe the region of stratification of the liquid phase in a four-component system is used. The authors used a ES-1020 computer to analyze the critical phenomena in Al-In-P-Sb, Al-Ga-In-P, Al-Ga-In-As, and In-Ga-As-P systems. The position of the spinode in the phase diagram of a four-component system is obtained.

1987-06-01

241

Computer control of fuel handling activities at FFTF  

International Nuclear Information System (INIS)

The Fast Flux Test Facility near Richland, Washington, utilizes computer control for reactor refueling and other related core component handling and processing tasks. The computer controlled tasks described in this paper include core component transfers within the reactor vessel, core component transfers into and out of the reactor vessel, remote duct measurements of irradiated core components, remote duct cutting, and finally, transferring irradiated components out of the reactor containment building for off-site shipments or to long term storage. 3 refs., 16 figs.

1985-09-08

242

Component design for LMFBR's  

Science.gov (United States)

Just as FFTF has prototype components to confirm their design, FFTF is serving as a prototype for the design of the commercial LMFBR's. Design and manufacture of critical components for the FFTF system have been accomplished primarily using vendors with little or no previous experience in supplying components for high temperature sodium systems. The exposure of these suppliers, and through them a multitude of subcontractors, to the requirements of this program has been a necessary and significant step in preparing American industry for the task of supplying the large mechanical components required for commercial LMFBR's. (auth)

1975-01-01

243

The phosphate complexation of neptunium(V)  

International Nuclear Information System (INIS)

The phosphate complexation of Np(V) is investigated in the pH range from 6.4 to 10.0 in 0.1 M NaClO_4 at 22#+-#2 C by absorption spectroscopy. The formation of two phosphate complexes is confirmed by spectroscopic speciation: NpO_2HPO"-_4 at 988.8 nm and NpO_2PO"2"-_4 at 993.6 nm with molar extinction coefficients of 251#+-#8 and 201#+-#11 1/mol cm, respectively. The complexation constants are determined to be log #beta# = 2.54#+-#0.02 for NpO_2HPO"-_4 and log #beta# = 6.33#+-#0.08 for NpO_2PO"2"-_4. The competition of the phosphate complexation with the carbonate complexation is demonstrated by speciation calculation under different geochemical conditions. (orig.).

1996-01-01

244

A variable gene delivery carrier-biotinylated chitosan/polyethyleneimine  

International Nuclear Information System (INIS)

A variable gene delivery system has been developed based on conjugating chitosan to biotin through a functionalized poly(ethylene glycol) (PEG) spacer, which can be used to further bind different molecules on the outer layer of a polymer/DNA complex by streptavidin (SA)-biotin linkage. In this study, TAT-conjugated SA was used as the model molecule to prove the conjugation function of the prepared complex. In addition, low-molecular-weight poly(ethyleneimine) (PEI) was added into the polymer/DNA complex to increase the transfection efficiency. The results of the luciferase assay show that the transfection efficiency of the prepared complex was significantly correlated with the amount of PEI and was further enhanced when TAT was conjugated to the complex by SA-biotin linkage. Considered to have negligible cytotoxic effects, the variable gene delivery complex ...

2010-12-01

245

Tuberous Sclerosis Complex Activity is Required to Control Neuronal Stress Responses in an mTOR-Dependent Manner  

UK PubMed Central (United Kingdom)

Tuberous Sclerosis Complex (TSC) is a neurogenetic disorder caused by loss-of-function mutations in either the TSC1 or TSC2 genes and frequently results in...Full Text Available

2009-05-06

246

The requirement of yeast replication origins for pre-replication complex proteins is modulated by transcription  

UK PubMed Central (United Kingdom)

The mini-chromosome maintenance proteins Mcm2–7 are essential for DNA replication. They are loaded onto replication origins during G1 phase of the cell cycle to form a pre-replication complex...Full Text Available

2005-01-01

247

The effect of an ?-globulin preparation and of polyribonuclease complexes on humoral antibody formation  

UK PubMed Central (United Kingdom)

The effects of bovine α-globulin (BAG), bovine-ribonuclease serum albumin (BSA-RNase) and polyribonuclease (poly-RNase) complexes on the primary response of rodents to sheep erythrocytes have...Full Text Available

1968-06-01

248

The Nature of Arsenic-Phytochelatin Complexes in Holcus lanatus and Pteris cretica1  

UK PubMed Central (United Kingdom)

We have developed a method to extract and separate phytochelatins (PCs)—metal(loid) complexes using parallel metal(loid)-specific (inductively coupled plasma-mass spectrometry) and organic-specific...Full Text Available

2004-03-01

249

The Dystrophin Complex Controls BK Channel Localization and Muscle Activity in Caenorhabditis elegans  

UK PubMed Central (United Kingdom)

Genetic defects in the dystrophin-associated protein complex (DAPC) are responsible for a variety of pathological conditions including muscular dystrophy, cardiomyopathy, and vasospasm. Conserved DAPC...Full Text Available

2009-12-01

250

Stereospecific ligands and their complexes. Part VII. Synthesis, characterization and in vitro antitumoral activity of platinum(II) complexes with O,Oprime-dialkyl esters of (S,S)-ethylenediamine-N,Nprime-di-2-(4-methyl)pentanoic acid  

British Library Electronic Table of Contents (United Kingdom)

Platinum(II) complexes (1-4) with bidentate N,Nprime-ligands, O,Oprime-dialkyl esters (alkyl = ethyl, n-propyl, n-butyl and n-pentyl), of (S,S)-ethylenediamine-N,Nprime-di-2-(4-methyl)pentanoic acid were synthesized and characterized by IR, 1H NMR and 13C NMR spectroscopy and elemental analysis. DFT calculations were performed for the complexes and it was found that only one diastereoisomer could be formed. Cytotoxic activity of complexes 1-4 was determined against chronic lymphocytic leukemia cells (CLL) and compared to the activity of ligand precursors L12HCl-L42HCl and corresponding palladium(II) complexes, [PdCl2L] (L = L1-L4). The complexes were found to exhibit significantly higher antitumor activities than cisplatin on CLL cells. Cytotoxic effect of platinum(II) complexes on CLL cel...

2011-01-01

251

Spoligotype Profile of Mycobacterium tuberculosis Complex Strains from HIV-Positive and -Negative Patients in Nigeria: a Comparative Analysis ?  

UK PubMed Central (United Kingdom)

We ran a comparative analysis of all patients for whom a positive culture of Mycobacterium tuberculosis complex was available between April 2004 and October 2005 and whose HIV serology...Full Text Available

2011-01-01

252

Sodium ion cycling mediates energy coupling between complex I and ATP synthase  

UK PubMed Central (United Kingdom)

We show here sodium ion cycling between complex I from Klebsiella pneumoniae and the F1F0 ATP synthase from Ilyobacter tartaricus in a reconstituted...Full Text Available

2003-02-04

253

Selective Enrichment of Azide-Containing Peptides from Complex Mixtures  

UK PubMed Central (United Kingdom)

A general method is described to sequester peptides containing azides from complex peptide mixtures, aimed at facilitating mass spectrometric analysis to study different aspects of proteome...Full Text Available

2009-07-01

254

Resonance Raman enhancement of phenyl ring vibrational modes in phenyl iron complex of myoglobin.  

UK PubMed Central (United Kingdom)

Resonance Raman spectra are reported for the organometallic phenyl-FeIII complexes of horse heart myoglobin. We observed the resonance enhancement of the ring vibrational modes of the bound phenyl group....Full Text Available

1990-04-01

255

Resolving Individuals Contributing Trace Amounts of DNA to Highly Complex Mixtures Using High-Density SNP Genotyping Microarrays  

UK PubMed Central (United Kingdom)

We use high-density single nucleotide polymorphism (SNP) genotyping microarrays to demonstrate the ability to accurately and robustly determine whether individuals are in a complex genomic DNA mixture....Full Text Available

2008-08-01

256

Preparation and Evaluation of Taste Masked Famotidine Formulation Using Drug/?-cyclodextrin/Polymer Ternary Complexation Approach  

UK PubMed Central (United Kingdom)

The main aim of the present study was to evaluate potential of ternary complexation (comprising of drug, cyclodextrin and polymer) as an approach for taste masking. For this purpose famotidine with...Full Text Available

257

Potential of mTOR inhibitors for the treatment of subependymal giant cell astrocytomas in tuberous sclerosis complex  

UK PubMed Central (United Kingdom)

Rapamycin inhibits the mTOR (target of rapamycin) pathway and extends lifespan in multiple species. The tuberous sclerosis complex (TSC) protein is a negative regulator of mTOR. In humans, loss of the...Full Text Available

258

Oxidation of phosphine by iron(III) chloride complexes supported on activated charcoal  

Energy Technology Data Exchange (ETDEWEB)

It has been discovered that iron(III) chloride complexes supported on activated charcoal oxidize phosphine under normal conditions. The process accelerates as the concentration of the chloride ions and the proton acid increases.

1988-06-01

259

On scientific and technical maintenance of the nuclear power complex in Ukraine  

International Nuclear Information System (INIS)

The article gives a brief description of the state of the nuclear power engineering in Ukraine and in the world as of today. There are basic organizational and practical actions on scientific and technical maintenance of the Ukraine nuclear power complex presented in the article.

2006-01-01

260

Nuclear Pore Complex Number and Distribution throughout the Saccharomyces cerevisiae Cell Cycle by Three-Dimensional Reconstruction from Electron Micrographs of Nuclear Envelopes  

UK PubMed Central (United Kingdom)

The number of nuclear pore complexes (NPCs) in individual nuclei of the yeast Saccharomyces cerevisiae was determined by computer-aided reconstruction of entire nuclei from electron...Full Text Available

1997-11-01

261

Multivesicular bodies in the enigmatic amoeboflagellate Breviata anathema and the evolution of ESCRT 0  

UK PubMed Central (United Kingdom)

Endosomal sorting complexes required for transport (ESCRTs) are heteromeric protein complexes required for multivesicular body (MVB) morphogenesis. ESCRTs I, II, III and III-associated are ubiquitous...Full Text Available

2011-02-15

262

Method of removing hydrogen sulfide and carbon dioxide from gases  

Energy Technology Data Exchange (ETDEWEB)

A process for the recovery of nitrilotriacetic acid values from solutions containing polyvalent metal complexes of nitrilotriacetic and the decomposition products thereof is described, the process being characterized by the addition to such solutions of sufficient strong acid to dissociate the complex under conditions to precipitate the nitrilotriacetic acid.

1984-04-17

263

Long-lived quantum coherence in photosynthetic complexes at physiological temperature  

UK PubMed Central (United Kingdom)

Photosynthetic antenna complexes capture and concentrate solar radiation by transferring the excitation to the reaction center that stores energy from the photon in chemical bonds. This process occurs...Full Text Available

2010-07-20

264

Intracellular ribonucleoprotein complexes of visna virus are infectious.  

UK PubMed Central (United Kingdom)

Sheep choroid plexus cells infected with visna virus produce intracytoplasmic viral ribonucleoprotein complexes with sedimentation values of 120S to 200S and buoyant densities of 1.29 to 1.32 g/cm3....Full Text Available

1982-06-01

265

Insertion of a Bulky Rhodium Complex into a DNA Cytosine-Cytosine Mismatch: An NMR Solution Study  

UK PubMed Central (United Kingdom)

The bulky octahedral complex, Rh(bpy)2chrysi3+ (chrysi = 5, 6- chrysenequinone diimine), binds single base mismatches in a DNA duplex with micromolar binding affinities...Full Text Available

2007-10-10

266

Identification of Triploid Individuals and Clonal Lines in Carassius Auratus Complex Using Microsatellites  

UK PubMed Central (United Kingdom)

The Carassius auratus complex in natural populations includes diploid triploid and polyploidy individuals. Diploid individuals belong to the species Carassius auratus...Full Text Available

267

Genetic architecture of complex traits: Large phenotypic effects and pervasive epistasis  

UK PubMed Central (United Kingdom)

The genetic architecture of complex traits underlying physiology and disease in most organisms remains elusive. We still know little about the number of genes that underlie these traits, the magnitude...Full Text Available

2008-12-16

268

Failure to detect circulating DNA--anti-DNA complexes by four radioimmunological methods in patients with systemic lupus erythematosus.  

UK PubMed Central (United Kingdom)

The presence of DNA-anti-DNA complexes in sera from patients with systemic lupus erythematosus (SLE) was investigated by two new radioimmunoassays (RIA) developed for this purpose and by measuring the...Full Text Available

1977-12-01

269

Developmental plasticity and the evolution of animal complex life cycles  

UK PubMed Central (United Kingdom)

Metazoan life cycles can be complex in different ways. A number of diverse phenotypes and reproductive events can sequentially occur along the cycle, and at certain stages a variety of developmental...Full Text Available

2010-02-27

270

Design complexity in termite-fishing tools of chimpanzees (Pan troglodytes)  

UK PubMed Central (United Kingdom)

Adopting the approach taken with New Caledonian crows (Corvus moneduloides), we present evidence of design complexity in one of the termite-fishing tools of chimpanzees (Pan...Full Text Available

2009-06-23

271

Cellulase-Xylanase Synergy in Designer Cellulosomes for Enhanced Degradation of a Complex Cellulosic Substrate  

UK PubMed Central (United Kingdom)

Designer cellulosomes are precision-engineered multienzyme complexes in which the molecular architecture and enzyme content are exquisitely controlled. This system was used to examine enzyme cooperation...Full Text Available

272

Carney-Complex: Multiple resections of recurrent cardiac myxoma  

UK PubMed Central (United Kingdom)

We report a case of a female patient who was operated at the third relapse of an atrial myxoma caused by Carney complex. The difficult operation was performed without any complications despite extensive...Full Text Available

273

Animal and human studies of a new /sup 99m/Tc labelled phosphine-isocyanide complex with possible applications to radionuclide ventriculography  

Energy Technology Data Exchange (ETDEWEB)

A new /sup 99m/Tc-phosphine-isocyanide complex with the general structure (/sup 99m/Tc (DEPE)/sub 2/(CNR)/sub 2/)/sup +/ has been synthesised and tested in animals and one human. In three animal species (rat, rabbit, dog), the complex is an efficient myocardial imaging agent, while in humans it remains in the blood pool. The complex is 100% protein bound in animals and humans, but whereas in humans it is attached to a 51.5 kdalton protein (probably prealbumin), in rabbits it appears to be bound to a larger macromolecule (M.W.>100 kdalton). The efficiency of the complex for blood pool labelling was tested in a human volunteer and compared with the standard in vivo red cell labelling technique with stannous pyrophosphate. A satisfactory radionuclide angiogram could be performed with less than 370 MBq of the complex. The count rate for the complex (cps/MBq) was ...

1987-04-01

274

Ability of complement to release systemic lupus erythematosus immune complexes from cell receptors.  

UK PubMed Central (United Kingdom)

Endogenous immune complexes present in sera from 10 different patients with systemic lupus erythematosus (SLE) in an active phase were allowed to bind to Raji cells; the ability of intact complement...Full Text Available

1981-05-01

275

A genome-wide survey of Major Histocompatibility Complex (MHC) genes and their paralogues in zebrafish  

UK PubMed Central (United Kingdom)

BackgroundThe genomic organisation of the Major Histocompatibility Complex (MHC) varies greatly between different vertebrates. In mammals, the classical MHC consists of a large number...Full Text Available

276

A functional comparison of the hyolingual complex in pygmy and dwarf sperm whales (Kogia breviceps and K. sima), and bottlenose dolphins (Tursiops truncatus)  

UK PubMed Central (United Kingdom)

The function of the hyolingual complex in three odontocete species was investigated to compare adaptations of divergent feeding strategies, suction and ram feeding. Pygmy and dwarf sperm whales, members...Full Text Available

2007-07-01

278

Treatment of multi-ruptured complex pseudoaneurysm with injection of fibrin sealant into lumens: report of one case with literature review  

International Nuclear Information System (INIS)

This paper is to report a case of multi-ruptured complex pseudoaneurysm confirmed by three-dimensional DSA. Under three-dimensional DSA guidance, the thrombin was injected into lumens in the attempt to cure the pseudoaneurysm. As the result was unsatisfactory, fibrin sealant was used to inject into the lumens again, and good curative effect was obtained. In clinical interventional practice, the incidence of pseudoaneurysm has been steadily increasing and the lesions have become more and more complex. In this paper the authors have discussed the diagnostic and therapeutic methods of complex pseudoaneurysm in order to provide clinical physicians with useful information. (authors)

2009-03-01

279

The electronic structure of organometallic complexes of the f elements XXV. Crystal field splitting pattern of the anionic complex [Cp_3Pr. NCS]"-  

International Nuclear Information System (INIS)

The absorption, emission and magnetic circular dichroism spectra of the anionic complex (Cp_3Pr. NCS)"- were measured at room and low temperatures. On the basis of these spectra the electronic structure in the f-f range could be derived. The parameters of an empirical Hamiltonian were fitted to the experimentally determined crystal field splitting pattern. Compared with the previously examined neutral Cp_3 Pr.X complexes the quadratic crystal field parameter B_0"2 is considerably reduced.

281

Syntheses and phosphorus-31 NMR studies of five-coordinate platinum(II) complexes of tris(2-(diphenylphosphino)ethyl)phosphine and monodentate phosphorus ligands  

Energy Technology Data Exchange (ETDEWEB)

The first preparation and characterization of the platinum (II) complexes containing five phosphorus ligands are reported herein. The complexes are represented by the formulae (Pt(PP/sub 3/)(P(OR)/sub 3/)Cl/sub 2/, where R = Me or Et, and (Pt(PP/sub 3/)(PEt/sub 3/))Cl/sub 2/. The /sup 31/P spectra of the complexes are presented. 10 references, 2 tables.

1987-12-02

282

Structure of Irradiated Materials  

International Science & Technology Center (ISTC)

Fundamental Research of Materials Structure and Properties Changes Resulted from Irradiation by Means of Complex of Modern Physical Methods

284

Solid-phase synthesis and pharmacological evaluation of novel nucleoside-tethered dinuclear platinum(II) complexes  

British Library Electronic Table of Contents (United Kingdom)

Three novel inosine-based dinuclear platinum complexes have been synthesized via a solid-phase strategy. In these compounds, the metal is linked both to the N-7 of the purine nucleus and to the terminal amine group of a hexylamine side chain installed on N-1. Cis- or trans- diamine as well as ethylenediamine ligands are coordinated to platinum along with a chloride. The synthesised complexes were tested against four different human tumor cell lines. One of these complexes proved to be more cytotoxic than cisplatin against the MCF7 cancer cell line in a short-term exposure assay.

2011-01-01

285

Proceedings of ARO Workshop Biostructures as Composite ...  

Science.gov (United States)

... interactive surfaces and interfaces, and 3) the more complex a ... carbonate or calcium phosphate with a thin interface ... diameter) for nerve prosthesis. ...

1990-03-01

287

On Phase Transition of Compressed Sensing in the Complex Domain  

CERN Document Server

The phase transition is a performance measure of the sparsity-undersampling tradeoff in compressed sensing (CS). This letter reports, for the first time, the existence of an exact phase transition for the $\\ell_1$ minimization approach to the complex valued CS problem. This discovery is not only a complementary result to the known phase transition of the real valued CS but also shows considerable superiority of the phase transition of complex valued CS over that of the real valued CS. The results are obtained by extending the recently developed ONE-L1 algorithms to complex valued CS and applying their optimal and iterative solutions to empirically evaluate the phase transition.

2011-01-01

288

Magnetic properties of oxovanadium(IV) complexes with bidentate on donor Schiff bases  

International Nuclear Information System (INIS)

(Feb 1977). Japan Syamal, A. Bombay Univ. (India). Univ. Dept. of Chemical

1977-01-01

289

KoderaUNEP_Uploaded web [Compatibility Mode  

Wastenet

complex -agriculture sector in a local community -blast furnace -cokes oven -cement kiln

290

ICDF Complex Operations Waste Management Plan  

Science.gov (United States)

This Waste Management Plan functions as a management and planning tool for managing waste streams generated as a result of operations at the Idaho CERCLA Disposal Facility (ICDF) Complex. The waste management activities described in this plan support the selected remedy presented in the Waste Area Group 3, Operable Unit 3-13 Final Record of Decision for the operation of the Idaho CERCLA Disposal Facility Complex. This plan identifies the types of waste that are anticipated during operations at the Idaho CERCLA Disposal Facility Complex. In addition, this plan presents management strategies and disposition for these anticipated waste streams.

2006-12-01

293

Ammoxidation of methanol to produce hydrogen cyanide  

Energy Technology Data Exchange (ETDEWEB)

Promoted antimony phosphate oxide complexes are excellent catalysts for the ammoxidation of methanol to HCN especially at high methanol throughputs.

1985-04-16

294

Development of a system for the observation of the stable operation in multi stage axial compressors. Final report; Erprobung und Weiterentwicklung eines Messsystems zur Stabilitaetsueberwachung im Verdichter einer HTGT. Abschlussbericht  

Energy Technology Data Exchange (ETDEWEB)

This report describes work carried out in the context of TurboTech Interim for the development of a system for monitoring stationary gas turbines for approaching the stability limit of the compressor. The requirements for the system components were defined and the suitability of different types and positions of pressure sensors were examined and evaluated. It was found very early in the work that, due to the complexity of the object being monitored, one would not succeed in finding a simple criterion for monitoring the pump limit. Rather, apart from the selection of suitable sensors and optimum positions, one must analyse the present signals in different ways and create a decision matrix from this. Existing work on this subject is mostly concerned with the phenomena in the context of experiments on experimental compressors or is not suitable for the requirements of stationary industrial gas turbines. The project is being carried out in the ...

1996-12-31

295

Thorium different-ligand complexes with morin as analytic form for extraction-photometric determination of thorium microamounts  

International Nuclear Information System (INIS)

Consideration is given to results of investigation into thorium complexing with morin (H_2Mor) in extraction systems containing different carboxylic acids as well as different salt background. The obtained data enabled to suggest the method of photometric determination of thorium in the form of Th(HMor)_2Benz_2 different-ligand complex (where Benz-anion of benzilic acid) with 0.25 #mu#g/ml detection limit.

1989-01-01

296

Study of complexing reactions and ligand exchange of zirconium and hafnium tetrachlorides with substituted derivative of O-naphthoquinonediazide  

Energy Technology Data Exchange (ETDEWEB)

Using the PMR method the interaction of zirconium and hafnium tetrachlorides with tri.tet.butylphenyl ester of 1,2- naphthoquinonediazide (2)-5-sulfonic acid is studied. The formation of MCl/sub 4/xNQD complexes is established, the equilibrium constants and thermodynamic parameters of complexing reaction are determined. The presence of rapid ligand exchange, proceeding according to associative mechanism, is detected. The rate constants and activation energies of the exchange reaction are calculated.

1981-11-01

297

Study of complexing reactions and ligand exchange of zirconium and hafnium tetrachlorides with substituted derivative of O-naphthoquinonediazide  

International Nuclear Information System (INIS)

Using the PMR method the interaction of zirconium and hafnium tetrachlorides with tri.tet.butylphenyl ester of 1,2- naphthoquinonediazide (2)-5-sulfonic acid is studied. The formation of MCl_4xNQD complexes is established, the equilibrium constants and thermodynamic parameters of complexing reaction are determined. The presence of rapid ligand exchange, proceeding according to associative mechanism, is detected. The rate constants and activation energies of the exchange reaction are calculated.

298

Solvent extraction studies using tetracycline as a complexing agent. Pt. 12. Determination of stability constants for the complexes of uranium and tetracycline  

Energy Technology Data Exchange (ETDEWEB)

Stability constants for uranium-tetracycline complexes were determined by the method of average number of ligands, the method of limiting values, the method of two parameters and the method of weighted least squares. Solvent extraction technique was used to obtain experimental data. (author). 10 refs.; 5 figs.

1985-09-01

299

Photochemistry and charge transfer chemistry of the platinum group elements. Summary progress report, May 1, 1990--April 30, 1993  

Energy Technology Data Exchange (ETDEWEB)

During the past 3 years, progress was made in elucidating the excited state structures of Pt(diimine)(dithiolate) complexes, while more recent efforts focused on the photochemistry of these complexes and electronic structure of other dithiolate systems. A carbonyl-Ir-maleonitrile dithiolate complex is also studied.

1992-12-01

300

FT-IR spectroscopic studies of fulvic acid from weathered coal and its complexes  

International Nuclear Information System (INIS)

FT-IR spectrum of fulvic acid from wheathered coal of Gongxian is determined using second derivative spectroscopy and the spectroscopic resolution is enhanced. Moreover, FT-IR spectra of the complexes of fulvic acid with Ca"2"+, Ba"2"+, Cu"2"+, Pb"2"+ and UO_2"2"+ under different pH are determined and the nature of the coordination of these complexes is discussed.

1995-01-01

301

Characterization of DTPA complexes and conjugated antibodies of astatine  

International Nuclear Information System (INIS)

The complex formation of astatine(I) cation with diethylene triamine pentaacetic acid (DTPA) and characterization of the complexes were investigated by electromigration in free electrolytes and by gel-chromatography on Sephadex G 25. The conjugation procedure for the production of At-DTPA conjugated polyclonal antibodies is described. (author) 15 refs.; 2 figs.

302

Asilomar conference on managing complexity in high energy physics: A summary and renaming of the conference  

Energy Technology Data Exchange (ETDEWEB)

The complex aspects of high energy physics work are briefly described, and approaches to managing them are discussed. Management of software and data are covered. For managing complexity in experimental physics, the choice of building or buying processor systems is addressed and the issues of compatibility and standardization are discussed. (LEW)

1987-02-01

303

A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.  

Science.gov (United States)

Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316

2011-08-11

304

Biphasic Low-Grade Nasopharyngeal Papillary Adenocarcinoma with a Prominent Spindle Cell Component: Report of a Case Localized to the Posterior Nasal Septum  

British Library Electronic Table of Contents (United Kingdom)

A case (female, 39?years of) of thyroid-like nasopharyngeal low-grade papillary adenocarcinoma with a significant spindle cell component is presented. The tumor was located on the posterior nasal septum. The spindle cells displayed nuclear features very much similar to the epithelial component and the two cell types merged imperceptibly. Immunohistochemically, the neoplastic cells (including the spindle cell component) were strongly and diffusely positive for TTF-1, cytokeratins (AE1-3), cytokeratin 19 and vimentin. C-kit immunohistochemistry showed diffuse mild to moderate membranous positivity with focal areas displaying moderate to strong immunoreactivity. EMA was strongly positive in the epithelial component with membranous and cytoplasmic reactivity whereas the spindle cell component ...

2011-01-01

305

Tissue structure, nuclear organization and gene expression in normal and malignant breast  

Energy Technology Data Exchange (ETDEWEB)

Because every cell within the body has the same genetic information, a significant problem in biology is to understand how cells within a tissue express genes selectively. A sophisticated network of physical and biochemical signals converge in a highly orchestrated manner to bring about the exquisite regulation that governs gene expression in diverse tissues. Thus, the ultimate decision of a cell to proliferate, express tissue-specific genes, or apoptose must be a coordinated response to its adhesive, growth factor, and hormonal milieu. The unifying hypothesis examined in this overview is that the unit of function in higher organisms is neither the genome nor the cell alone but the complex, three-dimensional tissue. This is because there are bidirectional connections between the components of the cellular microenvironment (growth factors, hormones, and extracellular matrix) and the nucl2048 These connections are made via membrane-bound ...

2000-01-27

306

Local chromatin structure of heterochromatin regulates repeatedDNA stability, nucleolus structure, and genome integrity  

Energy Technology Data Exchange (ETDEWEB)

Heterochromatin constitutes a significant portion of the genome in higher eukaryotes; approximately 30% in Drosophila and human. Heterochromatin contains a high repeat DNA content and a low density of protein-encoding genes. In contrast, euchromatin is composed mostly of unique sequences and contains the majority of single-copy genes. Genetic and cytological studies demonstrated that heterochromatin exhibits regulatory roles in chromosome organization, centromere function and telomere protection. As an epigenetically regulated structure, heterochromatin formation is not defined by any DNA sequence consensus. Heterochromatin is characterized by its association with nucleosomes containing methylated-lysine 9 of histone H3 (H3K9me), heterochromatin protein 1 (HP1) that binds H3K9me, and Su(var)3-9, which methylates H3K9 and binds HP1. Heterochromatin formation and functions are influenced by HP1, Su(var)3-9, and the RNA interference (RNAi) pathway. My thesis project investigates how ...

2007-05-05

307

Field driven ferromagnetic phase evolution originating from the domain boundaries in antiferromagnetically coupled perpendicular anitsotropy films  

Energy Technology Data Exchange (ETDEWEB)

Strong perpendicular anisotropy systems consisting of Co/Pt multilayer stacks that are antiferromagnetically coupled via thin Ru or NiO layers have been used as model systems to study the competition between local interlayer exchange and long-range dipolar interactions [1,2]. Magnetic Force Microscopy (MFM) studies of such systems reveal complex magnetic configurations with a mix of antiferromagnetic (AF) and ferromagnetic (FM) phases. However, MFM allows detecting surface stray fields only and can interact strongly with the magnetic structure of the sample, thus altering the original domain configuration of interest [3,4]. In the current study they combine magnetometry and state-of-the-art soft X-ray transmission microscopy (MXTM) to investigate the external field driven FM phase evolution originating from the domain boundaries in such antiferromagnetically coupled perpendicular anisotropy films. MXTM allows directly imaging the perpendicular ...

2008-05-01

308

Assessment and Forecasting Natural Gas Reserve Appreciation in the Gulf Coast Basin  

Energy Technology Data Exchange (ETDEWEB)

Reserve appreciation, also called reserve growth, is the increase in the estimated ultimate recovery (the sum of year end reserves and cumulative production) from fields subsequent to discovery from extensions, infield drilling, improved recovery of in-place resources, new pools, and intrapool completions. In recent years, reserve appreciation has become a major component of total U.S. annual natural gas reserve additions. Over the past 15 years, reserve appreciation has accounted for more than 80 percent of all annual natural gas reserve additions in the U.S. lower 48 states (Figure 1). The rise of natural gas reserve appreciation basically came with the judgment that reservoirs were much more geologically complex than generally thought, and they hold substantial quantities of natural gas in conventionally movable states that are not recovered by typical well spacing and vertical completion practices. Considerable evidence indicates that many ...

1997-10-01

309

A dinuclear Ni(I) system having a diradical Ni2N2 diamond core resting state: synthetic, structural, spectroscopic elucidation, and reductive bond splitting reactions.  

Science.gov (United States)

One-electron reduction of the square-planar nickel precursor (PNP)NiCl ( 1) (PNP (-) = N[2-P(CHMe 2) 2-4-methylphenyl] 2) with KC 8 effects ligand reorganization of the pincer ligand to assemble a Ni(I) dimer, [Ni(mu 2-PNP)] 2 ( 2), containing a Ni 2N 2 core structure, as inferred by its solid-state X-ray structure. Solution magnetization measurements are consistent with a paramagnetic Ni(I) system likely undergoing a monomer dimer equilibrium. The room-temperature and 4 K solid-state X-band electron paramagnetic resonance (EPR) spectra display anisotropic signals. Low-temperature solid-state X-band EPR data at 4 K reveal rhombic values g z = 1.980(4), g x = 2. 380(4), and g y = 2.225(4), as well as a forbidden signal at g = 4.24 for the Delta M S = 2 half field transition, in accord with 2 having two weakly interacting metal centers. Utilizing an S = 1 model, full spin Hamiltonian simulation of the low-temperature EPR spectrum on the solid sample was achieved by applying a nonzero ...

2008-10-15

310

Vacancy complex scattering mobility of holes in IR-photoexcited p-type ZnTe  

Energy Technology Data Exchange (ETDEWEB)

Conductivity and Hall effect measurements were made in dark and IR-photoexcited p-type ZnTe samples between 77 and 300 K. Acceptor vacancy complexes of activation energies 0.09-0.1 eV were found to be present in the photoexcited samples. Different possible scattering mobilities were considered for both samples to explain the observed hole mobility. In the photoexcited sample a scattering mobility due to vacancy complexes was suggested for the first time to explain the results. The scattering centres were associated with native vacancy complexes segregated at the dislocations sites. The expression for the complex scattering mobility has been deduced using the curve fitting method to be {mu}{sub C}=(6.6x10{sup -11})T{sup 5} e{sup 725/T}. (orig.).

1990-10-01

311

Studies of technetium chemistry. Pt. 13: The relationship between solvation free energies and brain uptakes of "9"9Tc"m complexes  

International Nuclear Information System (INIS)

Based on the X-ray crystallographic data of Tc-complexes for brain imaging agents, geometry optimizations in vacuo of TcO-BAT, TcO-MAMA, TcO-L, L-ECD, TcN-BAT and TcN-L, L-ECD complexes are performed with Hartree-Fock method and LANL 2 DZ basis set of G98W program. Then solvation free energy for each Tc-complex mentioned above in water is calculated by polarizable continuum method (PCM) including models of CPCM and IEFPCM. The results show that solvation free energy of Tc-complex is not only an indicator of lipophilicity but also one of the important factors that influence the brain uptake

2002-02-01

312

Origin of complex quantum amplitudes and Feynman's rules  

International Nuclear Information System (INIS)

Complex numbers are an intrinsic part of the mathematical formalism of quantum theory and are perhaps its most characteristic feature. In this article, we show that the complex nature of the quantum formalism can be derived directly from the assumption that a pair of real numbers is associated with each sequence of measurement outcomes, with the probability of this sequence being a real-valued function of this number pair. By making use of elementary symmetry conditions, and without assuming that these real number pairs have any other algebraic structure, we show that these pairs must be manipulated according to the rules of complex arithmetic. We demonstrate that these complex numbers combine according to Feynman's sum and product rules, with the modulus-squared yielding the probability of a sequence of outcomes.

2010-02-01

313

Mixed-ligand complexes of scandium with 4-(2-pyridylazo)resorcinol and monocarboxylic acids  

International Nuclear Information System (INIS)

Scandium reacts with 4-(2-pyridylazo)resorcinol in the presence of monocarboxylic acids (X) to form mixed-ligand complexes with a Sc:PAR:x ratio of 1:2:2. The chemical nature of this interaction has been established, and the extraction of these mixed-ligand complexes has also been investigated; stability constants and molar extinction coefficients have been calculated. The values of the latter decrease in the order CH_3COOH > CH_2ClCOOH > CCl_3COOH. The formation and extraction of mixed-ligand complexes in Sc-PAR-HX systems make it possible to increase the sensitivity and selectivity of scandium determination in comparison with the use of the Sc-PAR mono-ligand complex.

1987-09-01

314

Mitochondrial NADH:ubiquinone oxidoreductase (complex I) in eukaryotes: A highly conserved subunit composition highlighted by mining of protein databases  

British Library Electronic Table of Contents (United Kingdom)

Complex I (NADH:ubiquinone oxidoreductase) is the largest enzyme of the mitochondrial respiratory chain. Compared to its bacterial counterpart which encompasses 14-17 subunits, mitochondrial complex I has almost tripled its subunit composition during evolution of eukaryotes, by recruitment of so-called accessory subunits, part of them being specific to distinct evolutionary lineages. The increasing availability of numerous broadly sampled eukaryotic genomes now enables the reconstruction of the evolutionary history of this large protein complex. Here, a combination of profile-based sequence comparisons and basic structural properties analyses at the protein level enabled to pinpoint homology relationships between complex I subunits from fungi, mammals or green plants, previously identified...

2011-01-01

315

Mitochondrial DNA background modulates the assembly kinetics of OXPHOS complexes in a cellular model of mitochondrial disease  

British Library Electronic Table of Contents (United Kingdom)

Lebers hereditary optic neuropathy (LHON), the most frequent mitochondrial disorder, is mostly due to three mitochondrial DNA (mtDNA) mutations in respiratory chain complex I subunit genes: 3460/ND1, 11778/ND4 and 14484/ND6. Despite considerable clinical evidences, a genetic modifying role of the mtDNA haplogroup background in the clinical expression of LHON remains experimentally unproven. We investigated the effect of mtDNA haplogroups on the assembly of oxidative phosphorylation (OXPHOS) complexes in transmitochondrial hybrids (cybrids) harboring the three common LHON mutations. The steady-state levels of respiratory chain complexes appeared normal in mutant cybrids. However, an accumulation of low molecular weight subcomplexes suggested a complex I assembly/stability defect, which was ...

2008-01-01

316

Metallointercalators and Metalloinsertors  

Science.gov (United States)

Since the elucidation of the structure of double helical DNA, the construction of small molecules that recognize and react at specific DNA sites has been an area of considerable interest. In particular, the study of transition metal complexes that bind DNA with specificity has been a burgeoning field. This growth has been due in large part to the useful properties of metal complexes, which possess a wide array of photophysical properties and allow for the modular assembly of an ensemble of recognition elements. Here we review recent experiments in our laboratory aimed at the design and study of octahedral metal complexes that bind DNA non-covalently and target reactions to specific sites. Emphasis is placed both on the variety of methods employed to confer site-specificity and upon the many applications for these complexes. Particular attention is given to the family of complexes ...

2007-09-20

317

Metallo-intercalators and metallo-insertors.  

Science.gov (United States)

Since the elucidation of the structure of double helical DNA, the construction of small molecules that recognize and react at specific DNA sites has been an area of considerable interest. In particular, the study of transition metal complexes that bind DNA with specificity has been a burgeoning field. This growth has been due in large part to the useful properties of metal complexes, which possess a wide array of photophysical attributes and allow for the modular assembly of an ensemble of recognition elements. Here we review recent experiments in our laboratory aimed at the design and study of octahedral metal complexes that bind DNA non-covalently and target reactions to specific sites. Emphasis is placed both on the variety of methods employed to confer site-specificity and upon the many applications for these complexes. Particular attention is given to the family of complexes ...

2007-09-20

318

Imazalil-cyclomaltoheptaose (beta-cyclodextrin) inclusion complex: preparation by supercritical carbon dioxide and 13C CPMAS and 1H NMR characterization.  

Science.gov (United States)

An inclusion complex between imazalil (IMZ), a selected fungicide, and cyclomaltoheptaose (beta-cyclodextrin, betaCD) was obtained using supercritical fluid carbon dioxide. The best preparation conditions were determined, and the inclusion complex was investigated by means of 1H NMR spectroscopy in aqueous solution and 13C CPMAS NMR spectroscopy in the solid state. Information on the geometry of the betaCD/IMZ complex was obtained from ROESY spectroscopy, while the dynamics of the inclusion complex in the kilohertz range was obtained from the proton spin-lattice relaxation times in the rotating frame, T(1rho) (1H). PMID:14553984

2003-10-10

319

Enhanced catalytic activity of Fe bimetallic modified PAN fiber complexes prepared with different assisted metal ions for degradation of organic dye  

British Library Electronic Table of Contents (United Kingdom)

Two transition metal ions (Cu^2^+ and Co^2^+) and two rare earth metal ions (Ce^3^+ and La^3^+) were used as the assisted metal ions, respectively to prepare the transition metal and rare metal assisted Fe bimetallic amidoximated polyacrylonitrile (AO-PAN) fiber complexes. And their coordination configuration and visible light adsorption properties were examined by coordination number determination and UV-vis-DRS. Then the catalytic performance of these complexes was evaluated as the heterogeneous Fenton catalysts in Rhodamine B degradation by changing the nature and dosage of the assisted ions added. The results indicated that the incorporation of the assisted metal ions led to Fe bimetallic AO-PAN complexes with the more unsaturated configurations than Fe monometallic AO-PAN complex due ...

2011-01-01

320

Effect of pressure on iodine complexes, 1  

International Nuclear Information System (INIS)

Absorption spectra of the visible I_2 band of I_2 complexes with Et_2O, Et_2S, and Et_2Se in heptane have been measured up to 3300 bar at 25"0C. The equilibrium constants and volume changes accompanying complex formation, the molar extinction coefficients and the absorption maxima have been estimated. The volume changes were found comparable with those estimated from the X-ray data of the I_2 complexes in the crystalline state. The enhancement of the molar extinction coefficient and the blue shift of the visible I_2 band with increasing pressure have been established. The results suggest a decrease in the bond distance between an n-donor and I_2, compared with the spectroscopic properties of the I_2 complex at 1 bar. The decrease has been estimated as 0.008 nm with increasing pressure up to 3300 bar. (author).

1979-01-01

321

Correlations of /sup 195/Pt-/sup 31/P coupling constants with platinum-ligand and platinum-platinum bond lengths in platinum(I) dimers and in related platinum(II) complexes  

Energy Technology Data Exchange (ETDEWEB)

The availability of dimeric Pt(I) complexes with bridging bis(diphenylphosphino)methane ligands, (L--L')/sup n+/, presents an opportunity to study the physical properties and reactivity of metal-metal bonds as a function of the ligand trans to it with a minimum of competing variables. Several interesting trends of Pt-P coupling constants with the Pt-L and Pt-Pt bond lengths in Pt(I) dimers, (L--L')/sup n+/, and structurally related Pt(II) complexes are reported here. The data indicate that the Pt-P coupling constants continue to be sensitive indicators of not only the structure and stereochemistry of platinum phosphine complexes but also the electronic and steric influences of the ligand in such complexes, 23 references, 1 figure, 4 tables.

1986-03-12

322

Complexity Adjusted Soft-Output Sphere Decoding by Adaptive LLR Clipping  

CERN Document Server

A-posteriori probability (APP) receivers operating over multiple-input, multiple-output channels provide enhanced performance at the cost of increased complexity. However, employing full APP processing over favorable transmission environments, where less efficient approaches may already provide the required performance at a reduced complexity, results in waste of resources (e.g, processing energy/power). Therefore, for slowly varying channel statistics, substantial complexity savings can be achieved by simple adaptive schemes which perform performance tracking and adjust the complexity of the soft output sphere decoder by adaptively setting the related log-likelihood ratio (LLR) clipping value.

2010-01-01

323

Complex plasma: dusts in plasma  

International Nuclear Information System (INIS)

Dust particles in a plasma are charged negatively and are subject to various types of forces, including a drag force by plasma particles and a force due to the collective nature of a plasma. Dust particles are found in a sheath in laboratories balanced by the gravitational force and the electric force, while dust particles in space are ubiquitous, including planetary magnetospheres and interstellar space. Because of the novel nature of a complex system involving plasma particles and dust particles in a collective way, the dusty plasma is often called a complex plasma. The complex plasma is characterized by two distinctly different scales in time and in space. The plasma with electrons, ions and neutrals is characterized by the collective motion with a fast time scale and a short wavelength, while the dust particles move in a slow time scale and a long spatial scale. Some fundamental aspects of a complex ...

2007-04-21

324

211At-Rh(16-S4-diol) as a starting complex for preparing an astatine-labeled radiopharmaceutical  

British Library Electronic Table of Contents (United Kingdom)

A new procedure for preparing an 211At-labeled radiopharmaceutical is suggested. The 211At? anion forms a strong bond with the Rh3+ cation incorporated in the complex with a thiother ligand, 1,5,9,13-tetrathiacyclohexadecane-3,11-diol (16-S4-diol). The reaction conditions are optimized with 131I as astatine analog. The complexes are studied by paper electrophoresis, ion exchange, and thin-layer chromatography. The kinetics of the addition of the 131I? anion to Rh(16-S4-diol) and the dependence of the yield of the forming complex 131I-Rh(16-S4-diol) on the temperature, solution acidity, and reactant concentrations are examined. Taking into account the results obtained, the complex 211At-Rh(16-S4-diol) is prepared by adding astatide (211 At?) to equivalent amounts of RhCl3 and the tetrathioe...

2008-01-01

325

TEENET Cleaner Production Databases  

Wastenet

...of stations and a number of components, and meta information on air quality monitoring networks and stations. Access the database Producer Europe Environment Agency Content ...of stations and a number of components, and meta information on air quality monitoring networks and stations. Coverage National (Europe) Number of records...

326

Serotype- and strain- dependent contribution of the sensor kinase CovS of the CovRS two-component system to Streptococcus pyogenes pathogenesis  

UK PubMed Central (United Kingdom)

BackgroundThe Streptococcus pyogenes (group A streptococci, GAS) two-component signal transduction system CovRS has been described to be important for pathogenesis...Full Text Available

327

Seismic Testing of Reactor Components.  

Science.gov (United States)

This report is the final report on the seismic testing of reactor components conducted since 1977 with opening of the vibration laboratory at KAERI. In 1979, forced vibration testing of Wolsung-1 steam generator model using sine dwell and white nosie rand...

1980-01-01

328

Role of IgG and complement component C5 in the initial course of experimental cryptococcosis.  

UK PubMed Central (United Kingdom)

Although cellular immunity has a crucial role during cryptococcosis, several in vitro studies have pointed out the importance of IgG anti-Cryptococcus neoformans antibodies and complement components...Full Text Available

1989-12-01

329

Power electronics in electrical propulsion  

Energy Technology Data Exchange (ETDEWEB)

Various energy sources and motors of divers types can be used in electric cars with operating modes subjected to a number of particular constraints. As a result, the possible structures of the converters, that are analysed in detail, are about a dozen in number. Also considered is the use of solid-state components - thyristors, power transistors and new components.

1982-12-01

330

Identification of a Copper-Responsive Two-Component System on the Chromosome of Escherichia coli K-12  

UK PubMed Central (United Kingdom)

Using a genetic screen we have identified two chromosomal genes, cusRS (ylcA ybcZ), from Escherichia coli K-12 that encode a two-component, signal...Full Text Available

2000-10-01

331

Estimating Load-Sharing Properties in a Dynamic Reliability System  

UK PubMed Central (United Kingdom)

An estimator for the load share parameters in an equal load-share model is derived based on observing k-component parallel systems of identical components that have a continuous...Full Text Available

2005-01-01

332

Dynamic Analysis and Qualification Test of Nuclear Components.  

Science.gov (United States)

This report contains the study on the dynamic characteristics of Wolsung fuel rod and on the dynamic balancing of rotating machinery to evaluate the performance of nuclear reactor components. The study on the dynamic characteristics of Wolsung fuel rod wa...

1981-01-01

333

Development of contact scanner for Wolsung NPP alarm and annunciation system.  

Science.gov (United States)

Contact scanner system in Wolsung NPP(model ESE-1565) is an early '70 equipment, so most of components are obsolete. To make it 100% compatible, PCBs for this system is the main object of the study. Most of components used in the system are not available ...

1995-01-01

334

Angiotensin II Promotes Development of the Renal Microcirculation through AT1 Receptors  

UK PubMed Central (United Kingdom)

Pharmacologic or genetic deletion of components of the renin-angiotensin system leads to postnatal kidney injury, but the roles of these components in kidney development are unknown. To test the hypothesis...Full Text Available

2010-03-01

335

100 Area and 300 Area Component of the River Corridor Baseline Risk Assessment Spring 2006 Data Compilation  

International Nuclear Information System (INIS)

The purpose of this report is to describe the sampling approaches, modifications made to the 100 Area and 300 Area component of the RCBRA Sampling and Analysis Plan, summarize validation efforts, and provide sample identification numbers.

2010-05-01

336

Synthesis, characterization and biological evaluation of mononuclear Co(II), Ni(II), Cu(II) and Pd(II) complexes with new N2O2 Schiff base ligands.  

Science.gov (United States)

New tetradentate N(2)O(2) donor Schiff bases and their mononuclear Co(II), Ni(II), Cu(II), and Pd(II) complexes were synthesized and characterized extensively by IR, (1)H-, (13)C-NMR, mass, ESR, conductivity measurements, elemental and thermal analysis. Specifically the magnetic and electronic spectral measurements demonstrate the octahedral structures of cobalt(II), nickel(II) complexes and square planar geometries of copper(II), palladium(II) complexes. All the ligands and complexes were screened for their in vitro antibacterial activity against two gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus) and two gram-negative bacteria (Escherichia coli, Klebsiella pneumonia). In this study, Pd(II) complexes exhibited potent antibacterial activity against B. subtilis, S. aureus whereas other metal complexes also exerted good activity towards all ...

2011-02-01

337

Molybdenum complexes of biochemical interest. New coordination complexes of oxomolybdenum(V) with the tridentate ONO donor Schiff bases derived from salicylaldehydes and ethanolamine  

Energy Technology Data Exchange (ETDEWEB)

New oxomolybdenum(V) complexes MoOClL (where LH/sub 2/ = Schiff base) derived from ethanolamine and salicylaldehyde, 5-chlorosalicylaldehyde, 5-bromosalicylaldehyde, 5-nitrosalicylaldehyde, 3-ethoxysalicylaldehyde and 2-hydroxy-1-naphthaldehyde have been synthesized and characterised by elemental analyses, conductance, molecular weight, I.R. and electronic spectra and magnetic measurements. The Schiff bases behave as dibasic tridentate ONO donor ligands. The complexes are non-electrolytes and dimers. The complexes exhibit subnormal magnetic moments and are involved in antiferromagnetic exchange with S = 0 ground state. The complexes exhibit electronic spectral bands at ca. 13000 and ca. 17000 cm/sup -1/ due to the transitions dsub(xy)- > dsub(xz,yz) (/sup 2/B/sub 2/- > /sup 2/E) and dsub(xy)- > dsub(x2-y2) (/sup 2/B/sub 2/- > /sup 2/B/sub 1/), respectively. The ..nu..(Mo = O) frequency of ...

1985-02-01

338

Molybdenum complexes of biochemical interest. New coordination complexes of oxomolybdenum(V) with the tridentate ONO donor Schiff bases derived from salicylaldehydes and ethanolamine  

International Nuclear Information System (INIS)

New oxomolybdenum(V) complexes MoOClL (where LH_2 = Schiff base) derived from ethanolamine and salicylaldehyde, 5-chlorosalicylaldehyde, 5-bromosalicylaldehyde, 5-nitrosalicylaldehyde, 3-ethoxysalicylaldehyde and 2-hydroxy-1-naphthaldehyde have been synthesized and characterised by elemental analyses, conductance, molecular weight, i.r. and electronic spectra and magnetic measurements. The Schiff bases behave as dibasic tridentate ONO donor ligands. The complexes are non-electrolytes and dimers. The complexes exhibit subnormal magnetic moments and are involved in antiferromagnetic exchange with S = 0 ground state. The complexes exhibit electronic spectral bands at ca. 13000 and ca. 17000 cm"-"1 due to the transitions dsub(xy)->dsub(xz,yz) ("2B_2->"2E) and dsub(xy)->dsub(x2-y2) ("2B_2->"2B_1), respectively. The #nu#(Mo=O) frequency of the complexes is observed in the ...

1985-01-01

339

Effect of pressure on iodine complexes, 2  

International Nuclear Information System (INIS)

Absorption spectra of the CT bands of I_2 complexes with Et_2O, Et_2S, and Et_2Se in heptane have been measured up to 4400 bar at 25"0C. The equilibrium constants and the volume changes accompanying complex formation, and the molar extinction coefficients and absorption maxima have been estimated. The volume changes were comparable with those estimated by the visible I_2 bands and by the X-ray data of the I_2 complexes in the crystalline state. In the CT bands of Et_2S-I_2 and Et_2Se-I_2 complexes inversion of shift from red to blue has been observed with increasing pressure though the CT band of Et_2O-I_2 complex shifted only through red. This inversion appears to be characteristic of the strong CT complex. Enhancement of the molar extinction coefficient of the CT band has been found with increasing pressure suggesting enhancement of the CT interaction between ...

1979-01-01

340

Complexation study on no-carrier-added astatine with insulin: A candidate radiopharmaceutical  

Energy Technology Data Exchange (ETDEWEB)

No-carrier-added astatine radionuclides produced in the {sup 7}Li-irradiated lead matrix were separated from bulk lead nitrate target by complexing At with insulin, followed by dialysis. The method offers simultaneous separation of At from lead as well as its complexation with insulin. The At-insulin complex might be a potential radiopharmaceutical in the treatment of hepatocellular carcinoma. The stability of At-insulin complex was checked by dialysis against deionized water and Ringer lactate (RL) solution. It has been found that the half-life of At-insulin complex is about {approx}12 h, when dialyzed against deionized water and is only 6 h, when dialyzed against RL solution having the same composition as blood serum. The 6 h half-life of this Insulin-At complex is perfect for killing cancer cells from external cell surfaces as the half-life of internalization ...

2008-12-15

341

Complexation study on no-carrier-added astatine with insulin: A candidate radiopharmaceutical  

International Nuclear Information System (INIS)

No-carrier-added astatine radionuclides produced in the "7Li-irradiated lead matrix were separated from bulk lead nitrate target by complexing At with insulin, followed by dialysis. The method offers simultaneous separation of At from lead as well as its complexation with insulin. The At-insulin complex might be a potential radiopharmaceutical in the treatment of hepatocellular carcinoma. The stability of At-insulin complex was checked by dialysis against deionized water and Ringer lactate (RL) solution. It has been found that the half-life of At-insulin complex is about #approx#12 h, when dialyzed against deionized water and is only 6 h, when dialyzed against RL solution having the same composition as blood serum. The 6 h half-life of this Insulin-At complex is perfect for killing cancer cells from external cell surfaces as the half-life of internalization of ...

2008-12-01

342

Wideband Modulation and Tuning of Semiconductor Lasers ...  

Science.gov (United States)

... Tunable semiconductor lasers are essential components for links employing optical frequency modulation (OFM) for enhanced dynamic range or ...

1996-07-01

343

Variations in Manufacturing Processes 155 mm Combustible ...  

Science.gov (United States)

... Descriptors : *Combustible cartridge cases, *Ammunition components, *Manufacturing, Fabrication, Industrial production, Nitrocellulose, Adhesives ...

1983-08-01

344

The Stefan problem of evaporation of a volatile component from a binary liquid mixture  

Science.gov (United States)

The study is concerned with the Stefan problem of evaporation of a volatile component from its solution with a virtually non-volatile material. The analysis provides an analytical solution to the problem based on mass-transfer fundamentals. Results yield the evaporation rate, interfacial mole fractions, concentration profiles in the gas and liquid phases, and the location of the evaporation front. The analysis can be used to provide the binary liquid diffusion coefficient of the volatile component based on experimental data for the liquid gas interface position as a function of time. The requirements for such a measurement are discussed in terms of the volatility of the evaporating component and its initial concentration in the liquid mixture.[Figure not available: see fulltext.

2006-01-01

345

Survey of Biodegradation of Electronic Components and ...  

Science.gov (United States)

... This pinhole process may be similar to the formation of an oxide layer in aluminum electrolytic capacitors immersed in a borax solution. ...

1991-08-01

346

Status of R and D of the plasma facing components for the ITER divertor  

International Nuclear Information System (INIS)

The paper reports the progress made by the ITER Home Teams in the development of robust carbon and tungsten armoured plasma facing components for the ITER divertor. The activities on the development and study of armour materials, joining technologies, non-destructive evaluation techniques, high heat flux testing of manufactured components and neutron irradiation resistance studies are presented. The results of these activities confirm the feasibility of the main divertor components. Examples of the fruitful collaboration between Parties and future R and D needs are also described. (author)

2001-05-01

347

Refinement of conventional PSS design in multimachine system by modal analysis  

Science.gov (United States)

The design of the lead/lag network in a conventional power system stabilizer (PSS) is intended to provide the correct compensation in order to obtain an electrical torque component in phase with the speed variation. It is shown that, for a multimachine system, the conventional design analysis and synthesis tend to oversimplify the system representation and hence the interaction effects. A more rigorous approach is preferred considering four torque (or power) components instead of the conventional single component. Based on modal analysis, the significance of these other components is revealed, the more comprehensive treatment using a generalized multimachine representation is justified and a reliable means for optimizing the PSS parameters is explained.

1993-05-01

348

RECEIVED  

Science.gov (United States)

with full-scale component test data, a final requirement for completing general materials selection criteria. It also should be pointed out that, ...

349

NASTRAN nonlinear dynamic transient accident analysis for FFTF reactor component  

International Nuclear Information System (INIS)

... computer calculations fftf reactor nonlinear problems reactor accidents reactor

1976-11-14

350

Factors Affecting the Environmental Stability of Laminates,  

Science.gov (United States)

... The moisture content-dimension relationship of two laminate components, phenolic core and melamine overlay, are compared. (Author, modified). ...

1967-02-08

351

FFTF progress highlights, winter 1975--1976  

Science.gov (United States)

Milestones concerning equipment, reactor components, and testing and operations at the FFTF since July 1, 1975 are highlighted. (JWR)

1975-07-01

353

Evolution of the primary components of massive binary stars in the case of Roche lobe overflow after main-sequence evolution  

International Nuclear Information System (INIS)

The components with masses 32 and 64M _s_u_n, evolved with the matter mixing in the semiconvective zone and filling their Roche lobes, after the main-sequence evolution overflow their Roche lobes and lose matter during the first part of the helium core burning. After the overflow end, the components lose the matter by stellar wind. The components shrink in the nuclear timescale. At first, they have the blue supergiant character with anomalous CNO abundance, then - the Wolf-Rayet stars character.

355

Design, Fabrication, Test, and Evaluation of Spiral Bevel ...  

Science.gov (United States)

... Development Tapered Roller Bearing Program . . . 11 ... 98 61 Tapered Roller Bearing Component t Identification..... 104 ...

1973-06-01

357

Coefficient of Variation Spectral Analysis: An Application to ...  

Science.gov (United States)

... A major problem in the analysis of power spectral density measurements is distinguishing between narrowband spectral components of interest ...

1983-05-03

358

Challenges of Aircraft Design Integration  

Science.gov (United States)

... The program generates conceptual layouts of wing structural components and creates a beam finite element model of the wing structure (Figure 6 ...

2003-03-01

359

FEA Analysis of AP-0 Target Hall Collection Lens (Current Design)  

Energy Technology Data Exchange (ETDEWEB)

The AP-0 Target Hall Collection Lens is a pulsed device which focuses anti-protons just downstream of the Target. Since the angles at which the anti-protons depart the Target can be quite large, a very high focusing strength is required to maximize anti-proton capture into the downstream Debuncher Ring. The current design of the Collection Lens was designed to operate with a focusing gradient of 1,000 T/m. However, multiple failures of early devices resulted in lowering the normal operating gradient to about 750 T/m. At this gradient, the Lens design fares much better, lasting several million pulses, but ultimately still fails. A Finite Element Analysis (FEA) has been performed on this Collection Lens design to help determine the cause and/or nature of the failures. The Collection Lens magnetic field is created by passing high current through a central conductor cylinder. A uniform current distribution through the cylinder will create a tangential or azimuthal magnetic field that ...

2001-06-22

360

The safety concept of public gas supply in Germany  

Energy Technology Data Exchange (ETDEWEB)

The risk perception of the public consists of two components: the objectively factual component and the subjectively irrational component. The two strategies adopted by the German gas supply industry are the internal and the external communication strategy. Concepts and measures of accident precaution, registration and analysis of accident data (installation and operating errors, defects on flue systems, pipelines and valves, subsequent installation of gas appliances) are discussed. (R.P.)

1997-09-01

361

The issues in electronics hardening  

International Nuclear Information System (INIS)

This paper addresses the background and the continuously evolving topics of hardening and electronic components. Typical radiation environments from 1960 are described. Examples of a civilian satellite and of future particle physics colliders help illustrate hardening problems. Effects in components, limits of shielding, and three methods of providing components are described. The authors conclude by focusing on both future trends of radiation environments and anticipated progress in electronics. (authors). 10 refs., 9 figs., 4 tabs.

362

Quantitative electron-paramagnetic-resonance measurements of the electron-transfer components of the photosystem-I reaction centre. The reaction-centre chlorophyll (P700), the primary electron acceptor X and bound iron-sulphur centre A.  

UK PubMed Central (United Kingdom)

An e.p.r. spectrum of the reduced form of the electron-transport component (X), thought to be the primary electron acceptor of Photosystem I, was obtained. By using line-shape simulations of this component...Full Text Available

1978-02-15

363

Principal component analysis as a method for silicide investigation with Auger electron spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

The possibilities and problems of PCA in phase separation are shown on Ni, Pd, and Pt silicides. The PCA depth profiles are less influenced by sputter and matrix effects than usual Auger depth profiles. The position of the silicide-Si interface is well defined by the component distribution crossover in PCA profiles. An interface component between Pd and Pt silicides and Si substrate is determined by PCA.

1983-10-16

364

Principal component analysis as a method for silicide investigation with Auger electron spectroscopy  

International Nuclear Information System (INIS)

The possibilities and problems of PCA in phase separation are shown on Ni, Pd, and Pt silicides. The PCA depth profiles are less influenced by sputter and matrix effects than usual Auger depth profiles. The position of the silicide-Si interface is well defined by the component distribution crossover in PCA profiles. An interface component between Pd and Pt silicides and Si substrate is determined by PCA. (author).

365

Nine-component vertical seismic profiling at Yucca Mountain, Nevada  

Energy Technology Data Exchange (ETDEWEB)

Nine-component vertical seismic profiling has been conducted at the UE-25 UZ No. 16 borehole at Yucca Mountain, Nevada, in support of investigation of the hydrologic significance of fault and fracture systems. A large data set from multi-component sources and receivers allows state-of-the-art advances in processing using polarization filtering and reverse time migration, for enhanced interpretation of geologic features.

1996-12-01

366

Nine-component vertical seismic profiling at Yucca Mountain, Nevada  

International Nuclear Information System (INIS)

Nine-component vertical seismic profiling has been conducted at the UE-25 UZ No. 16 borehole at Yucca Mountain, Nevada, in support of investigation of the hydrologic significance of fault and fracture systems. A large data set from multi-component sources and receivers allows state-of-the-art advances in processing using polarization filtering and reverse time migration, for enhanced interpretation of geologic features.

367

Gamma absorption determination of concentration in a three-component mixture  

International Nuclear Information System (INIS)

A method for the analysis of three-component mixtures is described. The method is used for contact-free determination of component concentration in the mixtures transported via a product duct. Formulae as an aid in choosing the gamma radiation source and estimating the efficiency of measurement are given. The errors of measurement by the method of formaline-water-carbamide mixture is 1-2 %. 9 refs.; 1 fig.

368

SRS conversion of XeCl laser radiation into shifted Stokes components  

International Nuclear Information System (INIS)

An experimental study and a theoretical simulation were made of stimulated Raman scattering (SRS) conversion into shifted components. It was found that there were optimal values of the pressure and focal distance for conversion into the first 'blue' satellite of the first Stokes component. A study was made of the spatial and temporal dynamics of SRS conversion, which took into account generation of the shifted components. It was demonstrated theoretically and experimentally that the satellite intensity could be enhanced significantly by additional electron-collision excitation of the vibrational levels in the conversion medium or by the application of pairs of pump pulses. The maximum efficiency of conversion to the first 'blue' satellite of the first Stokes component was 10% and the satellite intensity reached one-third of the intensity of the main Stokes line. (nonlinear optical phenomena and devices)

1998-01-31

369

New NDT developments for the control of components in the FA3 EPR nuclear reactor at Flamanville; Nouveau developpement END pour le controle de composants de la tranche EPR de Flamanville (FA3)  

Energy Technology Data Exchange (ETDEWEB)

New Non Destructive Testing techniques are currently being developed for the inspection of two groups of components in the FA3 EPR nuclear reactor at Flamanville. The first group of components to be controlled is constituted by the welds of the (89) rod cluster control assemblies' containment; two control types are to be used: an ultrasonic technique (UT) evaluation from the outside of the flange-casing weld, and an ET control from the inside of the three other welds. The second group of components is formed by the 44 welded joints of the primary circuit, which will be inspected through ultrasonic testing. Details of the components, control devices and sensors are given and some test results are presented

2009-07-01

370

Method of constraint loss correction of CTOD fracture toughness for fracture assessment of steel components  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a procedure for transferring the CTOD fracture toughness obtained from laboratory specimens to an equivalent CTOD for structural components, taking constraint loss into account. The Weibull stress criterion is applied to correct the CTOD for constraint loss, which leads to an equivalent CTOD ratio, b, defined as b=d/dWP, where d and dWP are CTODs of the standard fracture toughness specimen and the structural component, respectively, at the same level of the Weibull stress. The CTOD ratio b is intended to apply to the fracture assessment of ferritic steel components to stress levels beyond small-scale yielding. Nomographs are given to determine the b-value as a function of the crack type and size in the component, the yield-to-tensile ratio of the material and the Weibul...

2006-01-01

371

Rotation seismic sensor and its calibration; Kaiten seibun jishinkei no shisaku to kando no kentei  

Energy Technology Data Exchange (ETDEWEB)

Sensor has been developed for the measurement of seismic wave rotary components. The vertical axis rotary component sensor is constituted of four L22Ds, similar to each other in performance, fixed in a ring formation on a metal bed. The ring is 22cm in diameter, and the four coils are connected so that their outputs will be added up. A horizontal axis rotary component sensor is built in the similar way. The rotary component sensors are all connected to a spectrum analyzer for the measurement of micromotions. It is found that the four-L22D combination can detect a rotary component of 335mV/deg/s. The sensor can detect both vertical and horizontal components with roughly the same sensitivity. A ring-form combination of conventional electromagnetic seismometers, though only as a temporary expedient, can perform high-resolution detection of rotary ...

1997-05-27

372

BIMA Array Observations of the Highly Unusual SiO Maser Source with a Bipolar Nebulosity, IRAS 19312+1950  

CERN Document Server

We report the results of mapping observations of the bipolar nebula with SiO maser emission, IRAS 19312+1950, in the CO (J=1-0 and J=2-1), 13CO (J=1-0 and J=2-1), C18O (J=1-0), CS (J=2-1), SO (J_K=3_2-2_1) and HCO+ (J=3-2) lines with the Berkeley-Illinois-Maryland Association array. Evolutional status of this source has been evoking a controversy since its discovery, though SiO maser sources are usually identified as late-type stars with active mass loss. In line profiles, two kinematical components are found as reported in previous single-dish observations: a broad pedestal component and a narrow component. Spatio-kinetic properties of a broad component region traced by 12CO lines are roughly explained by a simple spherical outflow model with a typical expanding velocity of an AGB star, though some properties of the broad component region still conflict with properties of a typical ...

2005-01-01

373

Ageing assessments with application of PSA Models  

International Nuclear Information System (INIS)

One of the main applications of PSA studies is related to identification of the major key issues related to plant safety. In standard PSA one assumes a constant value for component failure rates by considering that the component doesn't experience any degradation that could affect its performance. Used in this manner, standard PSA tools do not adequately address important ageing issues, and this fact could have a significant impact on the conclusions drawn from PSA studies and applications, in conditions of operation of ageing plants. To obtain realistic results, it is necessary to consider in the PSA model the ageing effects, and to do that it is necessary to take into consideration the change in component failure rate as a function of component age. In case of ageing phenomena, this dependence causes the failure rate of a component (or a set of components) to ...

2009-10-12

374

A pilot application of risk-based methods to establish in-service inspection priorities for nuclear components at Surry Unit 1 Nuclear Power Station  

International Nuclear Information System (INIS)

As part of the Nondestructive Evaluation Reliability Program sponsored by the US Nuclear Regulatory Commission, the Pacific Northwest Laboratory is developing a method that uses risk-based approaches to establish in-service inspection plans for nuclear power plant components. This method uses probabilistic risk assessment (PRA) results and Failure Modes and Effects Analysis (FEMA) techniques to identify and prioritize the most risk-important systems and components for inspection. The Surry Nuclear Power Station Unit 1 was selected for pilot applications of this method. The specific systems addressed in this report are the reactor pressure vessel, the reactor coolant, the low-pressure injection, and the auxiliary feedwater. The results provide a risk-based ranking of components within these systems and relate the target risk to target failure probability values for individual components. These results ...

375

The chemistry of technetium(V) complexes containing tetradentate amine oxime ligands  

International Nuclear Information System (INIS)

Technetium-99m was previously shown to form a stable, neutral and lipopholic complex with propylene amine oxime, PnAO. This Tc-99m-PnAO complex was shown to efficiently extracted by normal brain. However, it is not sufficiently retained in the brain to image its cerebral distribution using convertional SPECT (single-photon emission computerized tomography) instrumentation. A number of derivatives of PnAO have been synthesized and their technetium-99m complexes have been biologically evaluated. A number of these have been shown to have high brain uptake without exhibiting the rapid cerebral clearance that was observed with Tc-99m-PnAO. To better understand the chemistry of these potential brain imaging agents, a number of technetium-99 complexes of derivatives of PnAO have been synthesized and characterized. Substituents on the tetradentate amine oxime backbone were varied to probe the effect(s) of these ...

376

New dioxomolybdenum(VI) complexes with tridentate dibasic ONO donor schiff bases  

International Nuclear Information System (INIS)

Several dioxomolybdenum(VI) complexes of the schiff bases derived from salicylaldehyde, 2-hydroxy-1-naphthaldehyde, o-hydroxyacetophenone or pyridoxal and o-aminobenzylalcohol, o-aminophenol, o-hydroxybenzylamine, o-hydroxy(methylbenzyl)amine or 3-amino-2-naphthoic acid have been synthesized and characterized by elemental analysis, electrical conductance, molecular weight, IR and electronic spectral and magnetic susceptibility measurements. The schiff bases behave as dibasic, tridentate ligands and coordinate through ONO donor system forming complexes of the type MoO_2L.X (where LH_2=schiff base, X=H_2O or Ch_3OH). The compounds MoO_2L.Ch_3OH react with 2,2'-dipyridyl to form heterochelates of the type MoO_2L.dipyridyl. The complexes are non-electrolytes, monomers, diamagnetic and possess a cis-MoO_2 structure. The complexes exhibit a ligand-to-metal charge-transfer transition around 25000 cm"-"1. The ...

377

Luminescent property and catalytic activity of Ru(II) carbonyl complexes containing N, O donor of 2-hydroxy-1-naphthylideneimines  

British Library Electronic Table of Contents (United Kingdom)

The reaction of the chelating ligands (obtained by the condensation of 2-hydroxy-1-naphthaldehyde with various primary amines) with [RuHCl(CO)(EPh3)2(B)] (where E=P; B=PPh3, py or pip: E=As; B=AsPh3) in benzene afforded new stable ruthenium(II) carbonyl complexes of the general formula [Ru(Cl)(CO)(EPh3)(B)(L)] (L=anion of bidentate Schiff bases). The structure of the new complexes was investigated using elemental analyses, spectral (FT-IR, UV-vis and 1H NMR) and electrochemical studies and is found to be octahedral. All the metal complexes exhibit characteristic MLCT absorption and luminescence bands in the visible region. The luminescence efficiency of the ruthenium(II) complexes was explained based on the ligand environment around the metal ion. These complexes catalyze oxidation of prim...

2007-01-01

378

Liposome encapsulation of lipophilic N-alkyl-propanediamine platinum complexes: impact on their cytotoxic activity and influence of the carbon chain length  

Energy Technology Data Exchange (ETDEWEB)

Antitumor platinum(II) complexes derived from N-alkyl-propanediamine differing in the length of their carbon chain (C8, C10, C12 and C14) were incorporated in liposomes and the cytotoxic activity of these formulations was evaluated against tumor (A{sub 549}, MDA-MB-231, B16-F1 and B16-F10) and non-tumor (BHK-21 and CHO) cell lines. Stable and monodisperse liposome suspensions incorporating the platinum complexes were obtained from the lipid composition consisting of distearoyl-sn-glycero-3-phosphocholine, cholesterol and 1,2-distearoyl-sn-glycero- 3-phosphoethanolamine-N-(methoxy(polyethylene glycol)-2000) at 5:3:0.3 molar ratio. The entrapment efficiency (EE%) of the platinum complexes in liposomes increased with the carbon chain length. EE% was higher than 80% in C12- and C14-derivatives. The effect of liposome encapsulation on the cytotoxic activity of the complexes was found to depend on the carbon ...

2010-07-01

379

Complex Gradient Systems  

CERN Document Server

Let $M$ be a complex manifold of complex dimension $n+k$. We say that the functions $u_1,...s,u_k$ and the vector fields $\\xi_1,...,\\xi_k$ on $M$ form a \\emph{complex gradient system} if $\\xi_1,...,\\xi_k,J\\xi_1,...,J\\xi_k$ are linearly independent at each point $p\\in M$ and generate an integrable distribution of $TM$ of dimension $2k$ and $du_\\alpha(\\xi_\\beta)=0$, $\\d^c\\u_\\alpha(\\xi_\\beta)=\\delta_{\\alpha\\beta}$ for $\\alpha,\\beta=1,...,k$. We prove a Cauchy theorem for such complex gradient systems with initial data along a $\\CR-$submanifold of type $(\\CRdim,\\CRcodim)$. We also give a complete local characterization for the complex gradient systems which are \\emph{holomorphic} and \\emph{abelian}, which means that the vector fields $\\xi_\\alpha^c=\\xi_\\alpha-J\\xi_\\beta$, $\\alpha=1,...,k$ are holomorphic and satisfy $[\\xi_alpha^c,\\bar{\\xi_\\beta^c}]=0$ ...

2011-01-01

380

Binary copper(II) and uranyl(VI) complexes of glycocyamine, taurine and pyridoxal and ternary complexes involving 2,2'-bipyridine, 1,10-phenanthroline or nitrilotriacetic acid  

International Nuclear Information System (INIS)

Chelating tendencies of several biologically important compounds viz. glycocyamine (GCN: N-amidino-aminoethanoic acid) taurine (TRN: 2-aminoethanesulphonic acid) and pyridoxal [PDL: 3-hydroxy-5-(hydroxymethyl)-2-methyl-pyridine-4-carbaldehyde] have been examined by pH-metric titration technique in their binary complex formation with copper(II) and uranyl(VI) ions. The work has further been extended to investigating the ternary complex formation involving 2.2'-bipyridine. 1,10-phenanthroline or nitrilotriacetic acid as a primary and TRN and PDL as secondary ligands. All the experiments were carried out at 25"0C and at an ionic strength of 0.1M (NaCl0_4) in aqueous or 50% (v/v) aqueous-ethanol medium according to the suitability of the experimental conditions. Stabilities of ternary complexes as compared to those of the corresponding binary complexes of the secondary ligands have also been discussed. ...

381

Universal spectrochemical series of six-coordinate octahedral metal complexes for modifying the ligand field splitting.  

Science.gov (United States)

We studied a novel universal spectrochemical series of six-coordinated octahedral 3d transition metal complexes, which can be used for any combination of central metal atom and ligand molecules. A two dimensional spectrochemical series could be used to estimate the ligand field splitting energy of not only known compounds but also the unknown compounds. Therefore, it should be possible to control the physical properties, such as the electronic and magnetic properties and the optical phenomena of octahedral transition metal complexes by modifying the ligand field splitting. PMID:19378561

2009-01-28

382

The application of advanced techniques for complex focused-ion-beam device modification  

Energy Technology Data Exchange (ETDEWEB)

Advanced techniques for focused-ion-beam (FIB) device modification have been developed for complex, multistep modifications to circuitry on planar chip technology. Applying gas-assisted etching (GAE) techniques for high-aspect-ratio milling and the selective milling of both conductive and insulating films enhances process latitude. Localized ion-beam-induced deposition of an insulating film provides reconstructive capability in previously modified areas. The application of both techniques for complex device modification on VSLI devices fabricated with CMOS process technology is reviewed. (UK).

1996-12-31

383

Synthesis and characterization of nickel(II), chromium(III), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes with isatin- isonicotinoylhydrazone  

International Nuclear Information System (INIS)

A few metal complexes of isatin-isonicotinoylhydrazone with Ni(II), Cr(III), Co(II), Cu(II), Zn(II) and Cd(II) have been prepared and characterized on the basis of elemental analyses, infrared and electronic spectra as well as "1H NMR spectra, conductivity and magnetic measurements. In view of the results obtained, it has been found that two molecules of isatin-isonicotinoylhydrazone are chelated to the central metal ion as bis-uninegative ONO tridentate ligand forming non-electrolytic octahedral metal complexes. (author)

1997-03-01

384

Status of bismuth and lead for radioimmunoimaging and therapy  

International Nuclear Information System (INIS)

Of the radionuclides with physical properties most suited for use with monoclonal antibody for tumor imaging or therapy, few are more available or desirable than Pb-203, 212 and Bi-212. Yet no clinical studies have as yet been possible solely due to the lability in vivo of known complexes. We now report that bismuth complexes of the ligands p-SCN-Bz-DOTA and p-SCN-Bz-trans-cyclohexylDTPA are effective at protecting Bi-206 from release when linked to immunoproteins. Practicable, efficient ligand syntheses will be reported. Initial studies reveal that antibody is labeled efficiently with radiolead DOTA complexes. Preliminary studies indicate stability in vivo.

1990-08-26

385

Mixed-ligand tungsten-antipyrine-trihydroxyfluorone complexes and their use in analysis  

International Nuclear Information System (INIS)

In order to increase the sensitivity of photometric determination of tungsten and to find forms with high molar extinction coefficients, mixed-ligand complexes of tungsten with antipyrine and trihydroxyfluorone have been studied. The molar extinction coefficients have been determined for chloride associates of mixed-ligand complexes containing different trioxyfluorones: phenylfluorone, salicylflourone, p-bromphenylfluorone, anthrafluorone, dioxyfluorescein, and dioxyfluoroscein ethylate (DOFE). An associate formed by DOFE has the maximum molar extinction coefficient. It has been used for photometric determination of microgram amounts of tungsten impurity in vanadyl sulphate.

1977-01-01

386

Long non-coding RNAs in nervous system function and disease  

British Library Electronic Table of Contents (United Kingdom)

Central nervous system (CNS) development, homeostasis, stress responses, and plasticity are all mediated by epigenetic mechanisms that modulate gene expression and promote selective deployment of functional gene networks in response to complex profiles of interoceptive and environmental signals. Thus, not surprisingly, disruptions of these epigenetic processes are implicated in the pathogenesis of a spectrum of neurological and psychiatric diseases. Epigenetic mechanisms involve chromatin remodeling by relatively generic complexes that catalyze DNA methylation and various types of histone modifications. There is increasing evidence that these complexes are directed to their sites of action by long non-protein-coding RNAs (lncRNAs), of which there are tens if not hundreds of thousands speci...

2010-01-01

387

Lanthanide(III) complexes of ONO donor schiff bases derived from salicylaldehyde and o-hydroxybenzylamine or o-aminobenzylalcohol  

International Nuclear Information System (INIS)

Several new complexes of isomeric schiff bases derived from salicylaldehyde and o-hydroxybenzylamine/o-aminobenzyl-alcohol with Pr(III), Nd(III), Sm(III), Gd(III), Tb(III), and Dy(III) have been synthesized and characterized by elemental analysis, molar conductance, IR, electronic spectra and magnetic susceptibility measurements. The schiff bases behave as monobasic tridentate ONO donor and dibasic tridentate ONO donor ligands and form complexes of the type Ln(LH)L. (author). 12 refs.

1988-01-01

388

Facility Safety Plan B360 Complex Biohazardous Operations CMLS-412r0  

Science.gov (United States)

This Addendum to the Facility Safety Plan (FSP) 360 Complex describes the safety requirements for the safe conduct of all biohazardous research operations in all buildings within the 360 complex program areas. These requirements include all the responsibilities and authorities of building personnel, operational hazards, and environmental concerns and their controls. In addition, this Addendum prescribes facility-specific training requirements and emergency controls, as well as maintenance and quality assurance requirements for ES&H-related building systems.

2007-01-08

389

Electrochemical and spectroelectrochemical studies on Bis(acetylacetonate)(dimethyl sulfoxide) dioxouranium(VI) in dimethyl sulfoxide  

International Nuclear Information System (INIS)

The mechanistic aspects of electrochemical reductions of U"V"IO_2(acac)_2dmso(acac=acetylacetonate, dmso=dimethyl sulfoxide) complex with bidentate ligand(acac) in DMSO were investigated by using cyclic voltammetry, normal pulse voltammetry, and spectrophotometer equipped with an optical transparent thin layer electrode cell. It is concluded that the uranyl complexes with bidentate ligands at the equatorial plane form stable U(V) complexes by the electrochemical reduction and that their molar extinction coefficients in the visible region are very small. (J.P.N.).

1996-01-01

390

Determination of Scaling Parameter and Dynamical Resonances in Complex-Rotated Hamiltonian II: Numerical Analysis  

International Nuclear Information System (INIS)

This paper is concerned with the determination of a unique scaling parameter in complex scaling analysis and with accurate calculation of dynamics resonances. In the preceding paper we have presented a theoretical analysis and provided a formalism for dynamical resonance calculations. In this paper we present accurate numerical results for two non-trivial dynamical processes, namely, models of diatomic molecular predissociation and of barrier potential scattering for resonances. The results presented in this paper confirm our theoretical analysis, remove a theoretical ambiguity on determination of the complex scaling parameter, and provide an improved understanding for dynamical resonance calculations in rigged Hilbert space.

2008-03-15

391

Complexing of ruthenium during sorption by a graft copolymer of a polyacrylonitrile fiber with poly-2-methvl-5-vinylpyridine (PAN-MVP)  

Energy Technology Data Exchange (ETDEWEB)

This paper studies the sorption of chlorine complexes of ruthenium (IV) on the graft copolymer of a polyacrylonitrile fiber with poly-2-methyl-5-vinylpyridine (PAN-MVP). The composition of the fiber is illustrated. It is shown that sorption of chlorine complexes of ruthenium (IV) from acid solutions by a pyridine fiber sorbent takes place according to an anion-exchange mechanism and is due to the formation of compounds of the diamine type (Ru(RPy)/sub 2/Cl/sub 4/).

1985-05-20

392

Complex Networks on a Rock Joint  

CERN Document Server

A complex network approach on a rough fracture is developed. In this manner, some hidden metric spaces (similarity measurements) between apertures profiles are set up and a general evolutionary network in two directions (in parallel and perpendicular to the shear direction) is constructed. Also, an algorithm (COmplex Networks on Apertures: CONA) is proposed in which evolving of a network is accomplished using preferential detachments and attachments of edges (based on a competition and game manner) while the number of nodes is fixed. Also, evolving of clustering coefficients and number of edges display similar patterns as well as are appeared in shear stress, hydraulic conductivity and dilation changes, which can be engaged to estimate shear strength distribution of asperities.

2009-01-01

393

A survey of the wetlands and floodplains of the borrow area and wetland/shorebird complex for the remedial action at the chemical plant area of the Weldon Spring Site  

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy is conducting cleanup operations at the Weldon Spring site, St. Charles, Missouri, that will include development of a 77-ha (191-acre) soil borrow area. Eight wetlands, including riverine and palustrine emergent wetland types and totaling 0.9 ha (2.2 acres), will be eliminated during excavation of the borrow area. A 23-ha (57-acre) wetland/shorebird complex will be created at the Busch Conservation Area. The complex will include 2 ha (5 acres) of palustrine emergent wetland as mitigation for wetland losses in the borrow area.

1995-02-01

394

Workshop on dense granular flows  

Environmental Research Database

ObjectivesThe objective of this meeting will be to interface the two ends of the particulate flow spectrum - those working to understand the fundamentals of granular flows and those attempting to control particulate flows in an industrial setting - to develop solutions to the complex problems presented by dense granular flows. We will aim~%~~%~to provide a forum for the interface between practical users of particulate technology and the developers of theories for understanding granular flow;~%~to present [continued...]DescriptionIn practical situations such as those met in industry where segregation and mixing are important, understanding particulate flows is complex due to the presence of polydispersity, anisotropy and complex grain morphology. In attempting to model such systems, many of these features are generally ignored, except perhaps through empirical parameter fitting. Developing a theory to ...

2009-01-08

395

View larger image for ISS022-E-26137 - Earth Sciences and Image ...  

Science.gov (United States)

The Asarco-Mission complex (image left) is an active producer of copper and molybdenum (important in making steel and other metal alloys), ...

396

Useful vacancies: Positron beam interrogation of fluorine-vacancy complexes in semiconductor device structures  

Energy Technology Data Exchange (ETDEWEB)

The formation, migration and agglomeration in silicon of fluorine-vacancy complexes have been monitored by single-detector Doppler broadening spectroscopy. After electronics engineers found that fluorine ion implantation effectively eliminated the transient-enhanced diffusion of dopants in the creation of ultra-shallow junctions, a vital step in the further miniaturization of device structures, positron beams have played a pivotal role in providing an insight into the mechanisms underlying this phenomenon, being able to detect FV complexes in implanted and annealed samples. Secondary Ion Mass Spectrometry has provided complementary information on fluorine concentrations so that the nature of the F{sub m}V{sub n} complexes can be further assessed. New results on Si and SiGe structures are presented.

2008-10-31

397

Unravelling the complexity of collective mental models: A method for developing and analysing scenarios in multi-organisational contexts  

British Library Electronic Table of Contents (United Kingdom)

In multi-organisational contexts, scenario building has been used to engage stakeholders in a critical discussion on issues of mutual importance, and to gain their support with regards to possible future responses. A review of existing literature suggests that much has been written regarding the process of scenario development and the benefits of the process, but the detailed analysis of scenario building outcomes, which encompass a large number of issues and their complex interconnections, has not been made explicit for studying and enhancing understanding of a complex societal problem. This paper presents a systematic method for analysing such complex outcomes in order to facilitate reflective thinking on important issues within the wider context for policy development. The method was em...

2011-01-01

398

UFFizi: a generic platform for ranking informative features  

UK PubMed Central (United Kingdom)

BackgroundFeature selection is an important pre-processing task in the analysis of complex data. Selecting an appropriate subset of features can improve classification or clustering...Full Text Available

399

The innate immune repertoire in Cnidaria - ancestral complexity and stochastic gene loss  

UK PubMed Central (United Kingdom)

BackgroundCharacterization of the innate immune repertoire of extant cnidarians is of both fundamental and applied interest - it not only provides insights into the basic immunological...Full Text Available

2007-01-01

400

The Natural Statistics of Audiovisual Speech  

UK PubMed Central (United Kingdom)

Humans, like other animals, are exposed to a continuous stream of signals, which are dynamic, multimodal, extended, and time varying in nature. This complex input space must be transduced and sampled...Full Text Available

2009-07-01

401

The Influence of Interleukin-4 on Ligament Healing  

UK PubMed Central (United Kingdom)

Despite a complex cascade of cellular events to reconstruct the damaged extracellular matrix, ligament healing results in a mechanically inferior scarred ligament. During normal healing, granulation...Full Text Available

2011-05-01

402

The IKK complex contributes to the induction of autophagy  

UK PubMed Central (United Kingdom)

In response to stress, cells start transcriptional and transcription-independent programs that can lead to adaptation or death. Here, we show that multiple inducers of autophagy, including nutrient...Full Text Available

2010-02-03

403

Synthesis, Characterization and Biological Properties of Anions of Bivalent Transition Metal [Co(II) and Ni(II)] Complexes With Acylhydrazine Derived ONO Donor Schiff Bases.  

Science.gov (United States)

Some acylhydrazine derived ONO donor Schiff bases and their Co(II) and Ni(II) complexes have been prepared having the same metal ion (cation) but different anions. These synthesized metal(II) complexes have been characterized on the basis of their elemental analyses, magnetic moment, molar conductance, and IR and electronic spectral data. All of the Schiff base ligands function as tridentates and the deprotonated enolic form is preferred for coordination. In order to evaluate the effect of anions on the bactericidal activity, these synthesized complexes, in comparison to the uncomplexed Schiff bases have been screened against bacterial species., Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa and the results are reported. PMID:18475936

2000-01-01

404

Synthesis characterization and biological evaluation of a novel mixed ligand "9"9"mTc complex as potential brain imaging agent  

International Nuclear Information System (INIS)

One approach in the design of neutral oxotechnetium complexes is based on the simultaneous substitution of a tridentate dianionic ligand and a monodentate monoanionic coligand on a [Tc(V)O]"+"3 precursor. Following this ''mixed ligand'' concept, a novel "9"9"mTc complex with N,N-bis(2-mercaptoethyl)-N'N'-diethylethylenediamine as ligand and 1-octanethiol as coligand is prepared and evaluated as potential brain radiopharmaceutical. Preparation of the complex at tracer level was accomplished by using "9"9"mTc-glucoheptonate as precursor. The substitution was optimized and a coligand/ligand ratio of 5 was selected. Under this conditions the labeling yield was over 80% and a major product (with radiochemical purity > 80%) was isolated by HPLC methods and used for biological evaluation. Chemical characterization at carrier level was developed using the corresponding rhenium complex as structural model. ...

1998-08-01

407

Synthesis and biodistribution of a novel 99mTc-DMSA-metronidazole ester as a potential tumor hypoxia imaging agent  

British Library Electronic Table of Contents (United Kingdom)

The dimercaptosuccinic acid metronidazole ester (DMSAMe) was synthesized and radiolabeled with 99mTc to form the 99mTc-DMSAMe complex in high yield. The radiochemical purity of the 99mTc-DMSAMe complex was over 90%, as measured by TLC and by HPLC, without any notable decomposition at room temperature over a period of 6?h. Its partition coefficient indicated that it was a lipophilic complex. The tumor cell experiment and the biodistribution in mice bearing S 180 tumor showed that the 99mTc-DMSAMe complex had a certain hypoxic selectivity and accumulated in the tumor with high uptake and good retention. The tumor/blood and tumor/muscle ratios increased with time, suggesting it would be a possible tumor hypoxia imaging agent.

2010-01-01

408

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative [Clln(SCH2(CO)O)2]2-[(4-MepyH)2]2+  

Science.gov (United States)

The synthesis and structural characterization of a novel In(III) complex is described. The reaction

2004-01-01

409

Sun rises on station era - Johnson Space Center - NASA  

Science.gov (United States)

Dec 4, 1998 ... throwing a single switch to as complex as the Spartan deploy and retrieve. ...... The camera, called the Acousto-Optic ...

410

Structural and operational complexity of the Geobacter sulfurreducens genome  

UK PubMed Central (United Kingdom)

Prokaryotic genomes can be annotated based on their structural, operational, and functional properties. These annotations provide the pivotal scaffold for understanding cellular functions on a genome-scale,...Full Text Available

2010-09-01

411

Spin transition in octahedral metal complexes containing tetraazamacrocyclic ligands  

British Library Electronic Table of Contents (United Kingdom)

This review focusses on spin crossover complexes with octahedral metal ions which are bound to a tetraazamacrocyclic ligand and additionally either to two monodentate ligands or to one bidentate ligand. Macrocyclic ligands with a sufficiently large ring size prefer to coordinate to metal ions in an equatorial fashion yielding trans-octahedral coordination environments. In contrast, twelve-membered tetraazamacrocycles with high steric rigidity, such as 2,11-diaza[3.3](2,6)pyridinophanes or 2,11-dithia[3.3](2,6)pyridinophane, are prone to form cis-octahedral complexes. While the electronic and the steric properties of the coordinated tetraazamacrocycle in trans-octahedral complexes are very likely responsible for the paucity of observed spin transitions, the cis-octahedral coordination mode ...

2009-01-01

413

Small and neutral Tc"vO BAT, bisaminoethanethiol (N_2S_2) complexes for developing new brain imaging agents  

International Nuclear Information System (INIS)

Bisaminoethanethiol (BAT) ligands with various gem-dimethyl and amide groups were prepared, and the corresponding neutral Tc-99m complexes were prepared and evaluated for their relative stabilities by ligand-exchange reactions. It was demonstrated that technetium complexes containing gem-dimethyl substituents have higher lipophilicities, whereas those with an amide group possess greater stability, which enhances ligand-exchange reaction. The most interesting observation was that the brain uptake in rats is not determined only by lipophilicity. Apparently, Tc-99m complexes with an amide functional group display lower brain uptakes in rats compared to those without an amide group. The brain uptake was strongly influenced by substituents on the BAT ligand. These factors are critically important and should be taken into consideration when designing Tc-99m-labeled agents for CNS receptor imaging.

1998-02-01

414

Shock Tunnel Studies of Scramjet Phenomena - NASA Technical Report ...  

Science.gov (United States)

Kinetic reaction mechanisms have a hierarchical smacture with mechanisms for complex fuels built up on sub-mechanisms for simple fuel molecules ...

415

Separation of oligo-RNA by reverse-phase HPLC.  

UK PubMed Central (United Kingdom)

A rapid and highly reproducible chromatographic technique has been developed for analysis and purification of complex mixtures of oligoribonucleotides. The method utilizes a column of microparticulate...Full Text Available

1979-10-25

416

Self-Organization in Coordination-Driven Self-Assembly  

UK PubMed Central (United Kingdom)

ConspectusSelf-assembly allows for the preparation of highly complex molecular and supramolecular systems from relatively simple starting materials. Typically, self-assembled...Full Text Available

2009-10-20

417

Science and technology for industrial ecology  

Energy Technology Data Exchange (ETDEWEB)

This paper first discusses the challenge offered by natural and anthropogenic systems in all of their complexity and then indicates some areas of research in which specific scientific and technological needs are identifiable.

1996-07-10

418

SASE: Complex Event Processing over Streams  

CERN Document Server

RFID technology is gaining adoption on an increasing scale for tracking and monitoring purposes. Wide deployments of RFID devices will soon generate an unprecedented volume of data. Emerging applications require the RFID data to be filtered and correlated for complex pattern detection and transformed to events that provide meaningful, actionable information to end applications. In this work, we design and develop SASE, a com-plex event processing system that performs such data-information transformation over real-time streams. We design a complex event language for specifying application logic for such transformation, devise new query processing techniques to effi-ciently implement the language, and develop a comprehensive system that collects, cleans, and processes RFID data for deliv-ery of relevant, timely information as well as storing necessary data for future querying. We demonstrate an initial prototype of SASE ...

2006-01-01

420

Repair of a Complex Congenital Cardiac Defect  

Medline Plus

... stenosis. It looks from the transesophageal and the 3-D echo that most of the problem is really ... posterior leaflet, which you can see on the 3-D echo image is a major source. The anterior ...

421

Recurrent Partial Words  

CERN Document Server

Partial words are sequences over a finite alphabet that may contain wildcard symbols, called holes, which match or are compatible with all letters; partial words without holes are said to be full words (or simply words). Given an infinite partial word w, the number of distinct full words over the alphabet that are compatible with factors of w of length n, called subwords of w, refers to a measure of complexity of infinite partial words so-called subword complexity. This measure is of particular interest because we can construct partial words with subword complexities not achievable by full words. In this paper, we consider the notion of recurrence over infinite partial words, that is, we study whether all of the finite subwords of a given infinite partial word appear infinitely often, and we establish connections between subword complexity and recurrence in this more general framework.

2011-01-01

422

Progress and problems in the chemistry of technetium-99m tracers  

International Nuclear Information System (INIS)

The recent acceleration of effort to elucidate and explore the coordination chemistry of technetium has been prompted mainly by the need for a new generation of radiotracers in nuclear medicine, preferentially for tomograhic studies. Current approaches and their limitations in designing "9"9"mTc complexes capable of penetrating cell membranes of the target organs, and remaining there sufficiently long, are reviewed. With the predominance of Tc(V) oxo compounds, especially for brain imaging agents, new N4 and N2S2 coordinate complexes have been developed by shifting from bidentate to tetradentate ligands with a variable side chain or other adjustable reactivity. The search for myocardial imaging agents has focused on a variety of mixed ligand complexes of Tc(III) and most promising [Tc(CNR)_6]"+ complexes of Tc(I). 64 refs. (author).

423

Power Analyzer for Pocket Computing (PAPC)  

Science.gov (United States)

... Those functions are fundamental routines to build a power model for more complex circuits or functional blocks. ... 21 of 54 6. Memory Power Model ...

2004-01-01

424

Polyphenols and Aging  

UK PubMed Central (United Kingdom)

Age-associated changes within an individual are inherently complex and occur at multiple levels of organismal function. The overall decline in function of various tissues is known to play a...Full Text Available

2010-02-01

426

Polyhydroxyflavones as extractants. Communication 7. Solvent extraction of europrium complexes with morin from alkaline media  

Energy Technology Data Exchange (ETDEWEB)

This paper studies the analytical application of europium (III)-morin complex which is formed in alkaline medium and has an intense color. The extent of europium extraction was determined by adding to the extract a morin solution in isoamyl alcohol in a 50-100-fold excess with respect to europium. The dependence of the optical density of the extracts on the ph in the system europium (III)-morin-water-organic solvent for different excesses of the reagent is shown: this indicates formation of two extractable complexes, one being dominant in the pH range 4-7, the other at pH greater than or equal to 8.5. The extraction of the europium (III)-morin complex from alkaline solution is used for direct extraction-photometric determination of europium(III) in compounds of elements having amphoteric properties or forming amines (Zns, Mo0/sub 3/).

1985-09-01

427

Pitch discrimination by ferrets for simple and complex sounds  

UK PubMed Central (United Kingdom)

Although many studies have examined the performance of animals in detecting a frequency change in a sequence of tones, few have measured animals' discrimination of the fundamental frequency...Full Text Available

2009-09-01

428

Optimizing efficacy of Amphotericin B through nanomodification  

UK PubMed Central (United Kingdom)

The polyene antibiotic Amphotericin B (AMB) is one of the first therapeutic agents to be marketed commercially as nanosized formulations in which the drug is associated with lipids as liposomes or complexes....Full Text Available

2007-09-01

429

On synergism in inhibition of liquidphase oxidation of styrene and tetralin by organic phosphites and transition eleement acetylacetonates  

International Nuclear Information System (INIS)

Synergism has been observed during inhibiting initiated oxidation of styrene or tetralin by organic phosphites in the presence of complex compounds of some transition metals. The results are given of non-additive intensification of antioxidative activity of triphenylphosphite (TPP) and tri-(4-methyl-6-tert.-- butyl)-phenyl-phosphite (TMBP) in the process of initiated oxidation of styrene or tetralin with addition of acetylacetonates of cobalt and vanadyl. During styrene oxidation, inhibition of the reaction with chelate complex of vanadyl is weakened considerably when phosphite is added into the reaction system. During tetralin oxidation, postcatalytic (or branched) oxidation is observed only for large concentration of vanadyl complex. Addition of TPP to above complex sharply increases the induction period. When the induction period is completed, oxidation of tetralin follows the mechanism of usual, ...

430

On Issues Concerning Flow Separation and Vortical Flows in Three ...  

Science.gov (United States)

impflrtant to the understanding of complex vortical flows. ... tions like the slender wing, flow separations are controlled in the s,. ...... 10, AGARD LS-121, Dec. ...

431

Novel Magnetic Fluids for Breast Cancer Therapy  

Science.gov (United States)

... metal-oleate complexes. At this point, this method has been reported only for iron nanoparticles [15]. We have demonstrated ...

2008-01-01

432

Nitrilotriacetate complex of univalent astatine  

Energy Technology Data Exchange (ETDEWEB)

Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)[sup 2-] and its stability constant (lgK[sub 1]=8.97(4), 25degC, [mu]=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10[sup -3] mol . l[sup -1] of the oxidizer Na[sub 2]S[sub 2]O[sub 8] in the interval 4[<=]pH[<=]8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK[sub dp]=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).

1992-01-01

433

Nitrilotriacetate complex of univalent astatine  

International Nuclear Information System (INIS)

Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)"2"- and its stability constant (lgK_1=8.97(4), 25degC, #mu#=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10"-"3 mol . l"-"1 of the oxidizer Na_2S_2O_8 in the interval 4#<=#pH#<=#8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK_d_p=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).

434

Negative frequency and complex-carrier modulation and demodulation  

CERN Document Server

Negative frequency has a physical meaning, the complete description of a frequency signal is a rotating complex signal, in complete description, positive frequency signal exp(iwt) and negative frequency signal exp(-iwt) is two distinguishable and independent frequency signals. Because the real-carrier modulation and demodulation do not distinguish positive and negative frequency, so half of the spectrum resources and signal energy are wasted. The complex-carrier modulation uses the distinguishable positive frequency signal exp(iwt) and negative frequency signal exp(-iwt) as the carrier signals, they can carry different information, so the spectrum resources is full used, the complex-carrier demodulation does not lose signal energy, so the spectrum efficiency is improved.

2010-01-01

435

Molecular structure of platinum(III) hydroxoacetates according to data from EXAFS spectra  

Energy Technology Data Exchange (ETDEWEB)

The EXAFS spectra of the platinum(III) complexes Pt/sub 4/(OAc)/sub 10/(OH)/sub 2/ (I) and Pt/sub 4/ (OAc)/sub 4/(OH)/sub 8/(H/sub 2/O)/sub 2/ (II) have been investigated. It has been found by a curve-fitting method and with the aid of Fourier transformations that the shortest Pt-Pt distances are 2.61 A in complex I and 2.36 and 2.6 A in II. The values of the bond lengths obtained are consistent with the molecular structures proposed for complexes I and II, which contain skeletons of four platinum atoms in the form of a square or a rectangle, as well as with the known literature data on the lengths of Pt-Pt bonds in Pt(III) complexes.

1986-04-01

436

Metal phthalocyanine catalysts  

Energy Technology Data Exchange (ETDEWEB)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

1994-01-01

437

Menstrual Cycle: Basic Biology  

UK PubMed Central (United Kingdom)

The basic biology of the menstrual cycle is a complex, coordinated sequence of events involving the hypothalamus, anterior pituitary, ovary, and endometrium. The menstrual cycle with all its...Full Text Available

2008-01-01

438

MODELING AND BIOLOGICAL CONTROL OF MOSQUITOES  

UK PubMed Central (United Kingdom)

Models can be useful at many different levels when considering complex issues such as biological control of mosquitoes. At an early stage, exploratory models are valuable in exploring the characteristics...Full Text Available

2007-01-01

439

Limitations of silicon devices for quantum computing  

Energy Technology Data Exchange (ETDEWEB)

There is considerable interest in the use of silicon devices as qubits for quantum computing. The existence of nuclear spin in a silicon isotope and the complex band structure of silicon are unfavourable for this application of silicon devices. (viewpoint)

2004-04-28

440

Kinetic manifestation of cooperative interaction between quinuclidinyl benzilate and rat brain muscarine cholinoreceptors  

Energy Technology Data Exchange (ETDEWEB)

A study was made of the kinetics of L-(/sup 3/H)quinuclidinyl benzilate binding with membrane-bound muscarine cholinoreceptors from the rat brain. Determination was made of the rate constants of this process, and constants as a function of ligand concentration was investigated, indicating that there is a complex mechanism of interaction of antagonists with muscarine receptor. With up to 3.5 nM concentrations of L-(/sup 3/H)quinuclidinyl benzilate, the binding reaction occurs in two stages: rapid equilibrated binding is followed by a slow process of conformational isomerization of the receptor-ligand complex. At higher ligand concentrations, there is additional drastic increase in constant of rate of ligand binding a new plateau is reached. Such dependence of rate constant on ligand concentration is indicative of the cooperative nature of interaction between antagonists and muscarine receptors. This is possible if there are in the receptor ...

1985-01-01

441

Journals at IDEAS  

Wastenet

... Advances in Complex Systems ( ACS) 413 (413) 2001-2011 Springer Advances in Data Analysis and Classification 59 (59) 2008-2011 Advances in Management Advances In Management ...

442

Issues in the Pharmacokinetics of Trichloroethylene and Its Metabolites  

UK PubMed Central (United Kingdom)

Much progress has been made in understanding the complex pharmacokinetics of trichloroethylene (TCE). Qualitatively, it is clear that TCE is metabolized to multiple metabolites either locally or into...Full Text Available

2006-09-01

443

Interaction of dioxygen with the electronic excited state of Ir(III) and Ru(II) complexes: Principles and biomedical applications  

British Library Electronic Table of Contents (United Kingdom)

Luminescent transition metal complexes are enjoying a growing interest because of their ubiquitous applications in, e.g., the fields of material science, sensors and (biomedical) diagnostics, and iridium(III) and ruthenium(II) complexes are among the best studied. Due to their long-living excited states, these complexes can have a strong interaction with dioxygen, resulting in luminescence quenching. This oxygen quenching might be regarded as an unwanted effect in luminescence imaging, but, on the other hand, it can be exploited for diagnostic and therapeutic applications as well. After a theoretical introduction concerning the dioxygen quenching mechanism and the parameters involved, in the second part of this review we focus on the possibility of tailoring this quenching by modifying sel...

2011-01-01

444

Identification of Metal Ion Chloro Complexes in an Ambient ...  

Science.gov (United States)

... a given ternary molten salt system under conditions which are greatly " different than the normal method of potentiometric titration, that is, high ...

1985-05-25

445

Human Factors Assessment of the UH-60M Common Avionics ...  

Science.gov (United States)

... 1768 1475 360 to 3400 ... The TSC provided an independent assessment of SA based on ... Complexity of Situation Degree of complication (number of ...

2005-12-01

446

Genome analysis with inter-nucleotide distances  

UK PubMed Central (United Kingdom)

Motivation: DNA sequences can be represented by sequences of four symbols, but it is often useful to convert the symbols into real or complex numbers for further analysis. Several mapping...Full Text Available

2009-12-01

447

Formation of complex Langmuir and Langmuir-Blodgett films of water soluble rosebengal  

British Library Electronic Table of Contents (United Kingdom)

This communication reports the formation of complex Langmuir monolayer at the air-water interface by charge transfer types of interaction with the water soluble N-cetyl Formula Not Shown -trimethyl ammonium bromide (CTAB) molecules doped with rosebengal (RB), with the stearic acid (SA) molecules of a preformed SA Langmuir monolayer. The reaction kinetics of the formation of RB-CTAB-SA complex monolayer was monitored by observing the increase in surface pressure with time while the barrier was kept fixed. Completion of interaction kinetics was confirmed by FTIR study. This complex Langmuir films at the air-water interface was transferred onto solid substrates at a desired surface pressure to form multilayered Langmuir-Blodgett films. Spectroscopic characterizations reveal some molecular lev...

2007-01-01

448

Foreign Terrorist Threat to Singapore: An Assessment  

Science.gov (United States)

... USS Cole, on 9 October 2000, in Aden, Yemen, killing ... and complex interior, it can be attacked by a ... Though there has not been an attack on this ...

2001-04-01

449

FIRST Workshop Presentation Abstract: Circumstellar Matter Around ...  

Science.gov (United States)

and the implications for massive star evolution. In recent years, the complex nature of the circumstellar regions of evolved massive stars has become apparent. ...

450

Extraction of americium of different oxidation states in two-phase aqueous system based on polyethylene glycol  

International Nuclear Information System (INIS)

Americium extraction in different oxidation states in two-phase aqueous system based on polyethylene glycol is investigated. Conditions for quantitative extraction of americium (3) and americium (5) from ammonium sulfate solutions within pH=3-5 interval in the presence of arsenazo 3 are found. Composition of the produced americium complexes with reagent is determined; americium (3) interacts with arsenazo 3 in ammonium sulfate solutions with the formation of MeR and Me_2R composition complexes. Absorption spectrum characteristics of americium (3) and- (5) complexes with arsenazo 3 in ammonium sulfate solutions and extracts based polyethylene glycol aqueous solutions are given. Molar extinction coefficients of americium complexes with arsenazo (3) in these solutions are determined.

1987-01-01

451

Expression and regulation of the NALP3 inflammasome complex in periodontal diseases  

UK PubMed Central (United Kingdom)

Periodontitis is an infectious process characterized by inflammation affecting the supporting structures of the teeth. Porphyromonas gingivalis is a major oral bacterial species implicated...Full Text Available

2009-09-01

452

Existence of a complex closed trajectory in a three-dimensional dynamical system  

British Library Electronic Table of Contents (United Kingdom)

The DN-tracking method is used to prove the existence of a closed trajectory in a quadratic system of ordinary differential equations in three dimensions.

2011-01-01

453

Embryonic Retinal Cells and Support to Mature Retinal Neurons  

UK PubMed Central (United Kingdom)

Purpose.There is a paucity of neuron replacement studies for retinal ganglion cells. Given the complex phenotype of these neurons, replacement of ganglion cells may be impossible....Full Text Available

2010-04-01

454

Electrospinning of poly(vinyl pyrrolidone)-iodine complex and poly(ethylene oxide)/poly(vinyl pyrrolidone)-iodine complex - a prospective route to antimicrobial wound dressing materials  

British Library Electronic Table of Contents (United Kingdom)

New nanofibers containing poly(vinyl pyrrolidone)-iodine complex (PVP-iodine) were obtained by electrospinning in order to prepare materials suitable for wound dressings. Different approaches were used: a one-step method based on electrospinning of PVP-iodine or poly(ethylene oxide)/PVP-iodine solutions and a three-step method based on electrospinning of PVP or poly(ethylene oxide)/PVP mixed solutions followed by photo-mediated crosslinking of the obtained nanofibers and subsequent complexation with iodine. The average diameters of the fibers were in the range 150-470nm depending on the composition and on the applied field strength (AFS) and increased with increasing the amount of PEO in the spinning solutions. Higher AFS resulted in greater fiber diameter and in size distribution broadeni...

2007-01-01

455

Efficacy of drug prophylaxis.  

UK PubMed Central (United Kingdom)

With the spread of chloroquine resistant Plasmodium falciparum the control of malaria has become increasingly complex. In recent years, particular concern has arisen over how best to prevent malaria...Full Text Available

1989-01-01

456

Distributed Computer Networks in Support of Complex Group Practices  

UK PubMed Central (United Kingdom)

The economics of medical computer networks are presented in context with the patient care and administrative goals of medical networks. Design alternatives and network topologies are discussed with...Full Text Available

1978-11-09

457

Direct nano ESI time-of-flight mass spectrometric investigations on lanthanide BTP complexes in the extraction-relevant diluent 1-octanol  

Energy Technology Data Exchange (ETDEWEB)

The present work focuses on investigations of a highly selective ligand for Am(III)/Ln(III) separation: bis-triazinyl-pyridine (BTP). By means of nano-electro-spray mass spectrometry, complex formation of BTP with selected elements of the lanthanide series is investigated. We show that the diluent drastically influences complex speciation. Measurements obtained in the extraction-relevant diluent 1-octanol show the occurrence of Ln(BTP){sub i} (i 1-3) species in different relative abundances, depending on the lanthanide used. Here, the relative abundances of the Ln(BTP){sub 3} complexes correlate with the distribution ratios for extraction to the organic phase of the respective lanthanide. (authors)

2009-12-15

458

Dielectric studies of hydrogen bonded ternary systems: Acetonitrile+alcohols+benzene  

British Library Electronic Table of Contents (United Kingdom)

Any molecule which has a hydrogen atom attached directly to oxygen or nitrogen is capable of hydrogen bonding. The molecular complexes formed by hydrogen have particularly attracted considerable attention to understand the nature of the bond. The hydrogen bonded complexes formed by acetonitrile with certain alcohols such as tertiary butyl alcohol, isoamyl alcohol, cyclohexyl alcohol, hexyl alcohol and diethylene glycol in benzene were studied. The dipole moments of 1:1 complexes of the above said systems were determined at 308K. The dipolar increments for these systems were computed from the bond angle data available from molecular orbital studies. All these studied systems show that polarization interaction dominates in all the complexes.

2010-01-01

459

Development of anion-exchange resins for separations of actinides  

Energy Technology Data Exchange (ETDEWEB)

The evolution of these new ion-exchange resins hinges upon an understanding of the chemistry of actinide metal complexes as they exist in solution and when interacting with the cationic sites. Molecular modeling of electrostatic interactions between the metal complex and the cationic substrate is used to help visualize uptake mechanisms and, eventually, to predict optimized coordination sites. Thus, these new materials integrate the fields of ion-specific chelation and ion-exchange technology. Synthesized resins contain cationic sites designed to facilitate the uptake of plutonium nitrato complexes from high-nitrate solutions, and they exhibit distribution coefficients that are up to 10 times higher than those observed for commercial resins. Additionally, some new resins show surprisingly large Kd`s for anionic complexes of Am(III) and U(VI).

1997-12-31

460

Density functional theory and topological analysis on the hydrogen bonding interactions in cysteine-thymine complexes  

British Library Electronic Table of Contents (United Kingdom)

Abstract Hydrogen bonding interactions between amino acids and nucleic acid bases constitute the most important interactions responsible for the specificity of protein binding. In this study, complexes formed by hydrogen bonding interactions between cysteine and thymine have been studied by density functional theory. The relevant geometries, energies, and IR characteristics of hydrogen bonds (H-bonds) have been systematically investigated. The quantum theory of atoms in molecule and natural bond orbital analysis have also been applied to understand the nature of the hydrogen bonding interactions in complexes. More than 10 kinds of H-bonds including intra- and intermolecular H-bonds have been found in complexes. Most of intermolecular H-bonds involve O (or N) atom as H-acceptor, whereas the...

2011-01-01

461

Dendritic Cells in Systemic Lupus Erythematosus  

UK PubMed Central (United Kingdom)

Systemic lupus erythematosus (SLE) persists as a chronic inflammatory autoimmune disease and is characterized by the production of autoantibodies and immune complexes that affects multiple organs....Full Text Available

2010-04-01

462

DISTORTION OF A MAGNETIC FIELD BY THE MOTION OF A ...  

Science.gov (United States)

... No. 52. Metal Complexew-I. Preparation and Physical Properties of Transition Metal Complexes of 6-Mercaptopurine and ,-Mercapto-6, 7-Diphenyl ...

1965-06-01

464

Comparing healthcare outcomes.  

UK PubMed Central (United Kingdom)

Governments are increasingly concerned to compare the quality and effectiveness of healthcare interventions but find this a complex matter. Crude hospital statistics can be dangerously misleading and...Full Text Available

1994-06-04

465

Can you count on computers?  

CERN Document Server

"Machines of all kinds depend on complex software to keep them operating safely. But how reliable is the software - and how can we be sure it is reliable?" (4 pages)

1989-01-01

466

Can microRNAs act as biomarkers of aging?  

UK PubMed Central (United Kingdom)

Aging can be defined as a progressive decline in physiological efficiency regulated by an extremely complex multifactorial process. The genetic makeup of an individual appears to dictate this rate...Full Text Available

467

Caenorhabditis elegans Pheromones Regulate Multiple Complex Behaviors  

UK PubMed Central (United Kingdom)

Summary of recent advancesA family of small molecules called ascarosides act as pheromones to control multiple behaviors in the nematode Caenorhabditis elegans....Full Text Available

2009-08-01

468

Bioengineering the Hair Follicle  

UK PubMed Central (United Kingdom)

The hair follicle develops from the primitive embryonic epidermis as a result of complex epithelial-mesenchymal interactions. The full follicle, consisting of epithelial cylinders under control of a...Full Text Available

2007-01-01

469

Analysis of Mammalian Carboxylesterase Inhibition by Trifluoromethylketone-Containing Compounds  

UK PubMed Central (United Kingdom)

Carboxylesterases (CE) are ubiquitous enzymes that hydrolyze numerous ester-containing xenobiotics, including complex molecules, such as the anticancer drugs irinotecan (CPT-11) and capecitabine...Full Text Available

2007-03-01

470

An atlas of the dorsal thalamus of the marsupial brush-tailed possum, Trichosurus vulpecula.  

UK PubMed Central (United Kingdom)

In several respects the dorsal thalamus of Trichosurus presents a level of organizational complexity considerably in advance of that seen in Didelphis. In particular, such features as the lamination...Full Text Available

1978-06-01

471

AFM Imaging of SWI/SNF action: mapping the nucleosome remodeling and sliding  

CERN Document Server

We propose a combined experimental (Atomic Force Microscopy) and theoretical study of the structural and dynamical properties of nucleosomes. In contrast to biochemical approaches, this method allows to determine simultaneously the DNA complexed length distribution and nucleosome position in various contexts. First, we show that differences in the nucleo-proteic structure observed between conventional H2A and H2A.Bbd variant nucleosomes induce quantitative changes in the in the length distribution of DNA complexed with histones. Then, the sliding action of remodeling complex SWI/SNF is characterized through the evolution of the nucleosome position and wrapped DNA length mapping. Using a linear energetic model for the distribution of DNA complexed length, we extract the net wrapping energy of DNA onto the histone octamer, and compare it to previous studies.

2007-01-01

472

A stem cell niche dominance theorem  

UK PubMed Central (United Kingdom)

BackgroundMultilevelness is a defining characteristic of complex systems. For example, in the intestinal tissue the epithelial lining is organized into crypts that are maintained...Full Text Available

473

A new vanadium Schiff base complex as catalyst for oxidation of alcohols  

British Library Electronic Table of Contents (United Kingdom)

The monoanionic bidentate Schiff base, N-(phenolyl)-benzaldimine (HL), has been employed to synthesize a new vanadium(IV) complex of general composition [VO(L)2] (where L = O, N donor of Schiff base). The ligand and complex have been fully characterized by elemental analyses, molar conductance data, FT-IR, 1H- and 13C-NMR, and UV-Vis spectroscopies. Oxidation of alcohols to their corresponding aldehydes and ketones was conducted by this complex catalyst using Oxone as oxidant under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent under air at room temperature.

2010-01-01

474

3 - NASA Technical Reports Server  

Science.gov (United States)

Mar 1, 2011... properties to a complex model demanding full combustion kinetics, transport properties, and poppet valve flow characteristics. ...

476

Composing simulations using persistent software components  

Energy Technology Data Exchange (ETDEWEB)

The traditional process for developing large-scale simulations is cumbersome, time consuming, costly, and in some cases, inadequate. The topics of software components and component-based software engineering are being explored by software professionals in academic and industrial settings. A component is a well-delineated, relatively independent, and replaceable part of a software system that performs a specific function. Many researchers have addressed the potential to derive a component-based approach to simulations in general, and a few have focused on military simulations in particular. In a component-based approach, functional or logical blocks of the simulation entities are represented as coherent collections of components satisfying explicitly defined interface requirements. A simulation is a top-level aggregate comprised of a collection of ...

1999-03-01

477

Breaking the Biological barriers to Cellulosic Ethanol: A Joint Research Agenda  

Energy Technology Data Exchange (ETDEWEB)

A robust fusion of the agricultural, industrial biotechnology, and energy industries can create a new strategic national capability for energy independence and climate protection. In his State of the Union Address (Bush 2006), President George W. Bush outlined the Advanced Energy Initiative, which seeks to reduce our national dependence on imported oil by accelerating the development of domestic, renewable alternatives to gasoline and diesel fuels. The president has set a national goal of developing cleaner, cheaper, and more reliable alternative energy sources to substantially replace oil imports in the coming years. Fuels derived from cellulosic biomass - the fibrous, woody, and generally inedible portions of plant matter - offer one such alternative to conventional energy sources that can dramatically impact national economic growth, national energy security, and environmental goals. Cellulosic biomass is an attractive energy feedstock because it is an abundant, domestic, renewable ...

2006-06-01

478

Characterization of an improved disposal site for low and intermediate level waste using Cs-137 deposition profiles  

International Nuclear Information System (INIS)

According to the present concept, the low and intermediate level wastes generated during the Cernavoda NPP operation will be disposed in a near surface repository. The Saligny site, placed in the NPP protected area, has been proposed for their disposal. Geologically, the main components of this site are the quaternary loess, the Precambrian and Pre-quaternary clays, the Eocene and Barremian limestone. Hydrologically, the site can be divided into a vadose zone down to 45-50 m and three distinct aquifers, two of them in the limestone beds and the third in the lenses of sand and limestone existing in the pre-quaternary clay layer. A large research program for site characterization was initiated in 1996. At present, the site characteristics requested for safety analysis have been experimentally measured on soil samples or calculated by different computer programs. Hundreds of experimental values of the density, porosity, hydraulic conductivity, soil-water retention, ...

2004-09-09

479

Splice assembly tool and method of splicing  

Energy Technology Data Exchange (ETDEWEB)

A splice assembly tool for assembling component parts of an electrical conductor while producing a splice connection between electrical cables therewith, comprises a first structural member adaptable for supporting force applying means thereon, said force applying means enabling a rotary force applied manually thereto to be converted to a longitudinal force for subsequent application against a first component part of said electrical connection, a second structural member adaptable for engaging a second component part in a manner to assist said first structural member in assembling the component parts relative to one another and transmission means for conveying said longitudinal force between said first and said second structural members, said first and said second structural members being coupled to one another by said transmission means, wherein at least one of said component parts ...

1980-01-01

480

Efficient calculation of the worst-case error and (fast) component-by-component construction of higher order polynomial lattice rules  

CERN Document Server

We show how to obtain a fast component-by-component construction algorithm for higher order polynomial lattice rules. Such rules are useful for multivariate quadrature of high-dimensional smooth functions over the unit cube as they achieve the near optimal order of convergence. The main problem addressed in this paper is to find an efficient way of computing the worst-case error. A general algorithm is presented and explicit expressions for base~2 are given. To obtain an efficient component-by-component construction algorithm we exploit the structure of the underlying cyclic group. We compare our new higher order multivariate quadrature rules to existing quadrature rules based on higher order digital nets by computing their worst-case error. These numerical results show that the higher order polynomial lattice rules improve upon the known constructions of quasi-Monte Carlo rules based on higher order digital nets.

2011-01-01

481

Bonding exterior grade structural panels with copolymer resins of biomass residue components, phenol, and formaldehyde  

Energy Technology Data Exchange (ETDEWEB)

Components of various forest and agricultural residue biomass-including the polyphenolic compounds-were converted into aqueous solution and/or suspension by extraction and digestion. Some biomass components reacted vigorously under alkaline catalysis with formaldehyde and initially showed a high degree of exothermic reaction; however, other components did not react as vigorously under these conditions, indicating that different biomass materials require different methods to obtain optimum reactivity for the copolymerization with phenol. Our primary goal is to develop adhesives capable of producing acceptable bond quality, as determined by the wood products industries` standards, under a reasonable range of gluing conditions. Copolymer resins of phenol, formaldehyde, and biomass components were synthesized and evaluated for gluability of bonding exterior grade structural replaced with chemicals derived ...

1993-12-31

482

Avoidable thermodynamic inefficiencies and costs in an externally fired combined cycle power plant  

Energy Technology Data Exchange (ETDEWEB)

The real thermodynamic inefficiencies in a thermal system are related to exergy destruction and exergy loss. An exergy analysis identifies the system components with the highest exergy destruction and the processes that cause them. However, only a part of the exergy destruction in a component can be avoided. A minimum exergy destruction rate for each system component is imposed by physical, technological, and economic constraints. The difference between the total and the unavoidable exergy destruction rate represents the avoidable exergy destruction rate, which provides a realistic measure of the potential for improving the thermodynamic efficiency of a component. The calculation of avoidable cost rates associated with both exergy destruction and capital investment is described in the paper and is applied to the exergoeconomic evaluation of an externally fired combined cycle power plant. For each plant ...

2006-08-15

483

Use of high energy radiation component as a reference source for radiometric testing  

International Nuclear Information System (INIS)

The possibility of providing high accuracy of absorption and albedo methods of radiometric testing due to the use of high-energy radiation component that has passed through a barrier and gone from it in the opposite direction as a reference source, is considered. It is shown that the use of high-energy component of penetrating radiation as a reference source decreases the device response to the main interference in a much larger degree than its response to the change of measured parameter. Experiments are performed using steel pipes and plates. "2"4"1Am, "1"3"7Cs and "6"0Co are used as sources.

484

The impact of fatigue strength considerations for the lifetime management for pumped-storage power plants  

Energy Technology Data Exchange (ETDEWEB)

Due to changed operational conditions and because of the increasing age of several hydro power plant components, there is an increasing risk of damages and the control of degradation mechanisms is of increasing significance. Therefore lifetime considerations for safety relevant components in pumped-storage plants become more and more important. The development of a lifetime management system, in conjunction with monitoring systems and specific surveillance for a group of pumped-storage power plants of different ages and in a wide range of power output is presented. The special focus is on the impact of fatigue strength considerations within this framework. The applied procedure will be described for typical mechanical components in pumped-storage plants exemplarily. (orig.)

2010-07-01

485

Stability of model recycled mixed plastic waste compatibilised with a cooperative compatibilisation system  

British Library Electronic Table of Contents (United Kingdom)

The effect of the degree of degradation of the components of a model municipal plastic waste (a mixture of low-density polyethylene, high-density polyethylene, polypropylene and high-impact polystyrene) on the toughness and stability of recyclates compatibilised with a cooperative compatibilisation system (a mixture of ethylene-propylene statistical and styrene-butadiene block copolymers with a secondary amine-based stabiliser) was studied. It was shown that good impact strength was achieved for recyclates having components with a low or medium degree of degradation. Mechanical properties of recyclates having the components with a high degree of degradation are deteriorated. The addition of the cooperative compatibilisation system leads to a higher thermo-oxidative stability of recyclates ...

2011-01-01

486

Risk assessment for the SNR-300 reactor. Earthquake hazard emanating from reactor component failure  

International Nuclear Information System (INIS)

The risk analysis was carried out in consideration of conditions prevailing at the Kalkar site analogous to the investigations in phase A of DRS (German Reactor Study). Earthquake design loads include the probabilities of upper deviations of the site intensities to be expected. The calculations of dynamic loads for select buildings are made using models and computational methods. Component analyses were performed analogous to DRS for the supports of large components, supports of the roof construction of the reactor building taking into account support reserves due to plastic work capacity, wall disks in steam generator buildings and switchboard plant buildings. (DG).

487

Residual Stress Field Analysis and Prediction in Nitrided Tool Steel  

British Library Electronic Table of Contents (United Kingdom)

Residual stresses are present in engineering components as an unintended consequence of manufacturing processes, but they are also deliberately introduced to beneficial effect during surface engineering procedures. Plasma nitriding is a process of particular importance for forming tools and dies, giving significant advantages in wear, and fatigue resistance through the generation of near-surface compressive residual stresses. A precise knowledge of the level and distribution of residual stresses that exist in engineering components is necessary for an accurate design and prediction of a component's fatigue resistance. However, measurement of residual stresses is not always possible, which is especially true for forming tools. Therefore, other methods for residual stress evaluation and pred...

2011-01-01

488

Method for producing form coke  

Science.gov (United States)

A method is disclosed for the production of form coke, such as coke for use in the smelting industry as blast furnace coke and also in electro-metallurgical facilities. The process consists of : coking a high volatile coal containing at least 35% volatile constituents so as to remove the volatile constituents to form a non-baking base coal; mixing a plurality of fine grain coal components together, of which at least one of the components comprises said non-baking base coal and at least one other component comprises a baking bituminous coal so as to form a mixture of such coals; subjecting the mixture to a degassing operation using highly volatile coals; coking the degassed mixture; and pressing the coke into briquettes.

1980-02-05

489

Loaded Transducer Fpr Downhole Drilling Component  

Energy Technology Data Exchange (ETDEWEB)

A robust transmission element for transmitting information between downhole tools, such as sections of drill pipe, in the presence of hostile environmental conditions, such as heat, dirt, rocks, mud, fluids, lubricants, and the like. The transmission element maintains reliable connectivity between transmission elements, thereby providing an uninterrupted flow of information between drill string components. A transmission element is mounted within a recess proximate a mating surface of a downhole drilling component, such as a section of drill pipe. To close gaps present between transmission elements, transmission elements may be biased with a "spring force," urging them closer together.

2005-07-05

490

Investigation of Various Wind Turbine Drivetrain Condition Monitoring Techniques  

Energy Technology Data Exchange (ETDEWEB)

The wind industry has experienced premature turbine component failures during the past years. With the increase in turbine size, these failures, especially those found in the major drivetrain components, i.e. main shaft, gearbox, and generator, have become extremely costly. Given that the gearbox is the most costly component in the drivetrain to fix, the National Renewable Energy Laboratory (NREL) initiated the Gearbox Reliability Collaborative (GRC) to determine the causes for premature gearbox failures and subsequently, recommend improvements to gearbox design, manufacture, and operational practices. The GRC has two identical test gearboxes, which are planned for a dynamometer and a field test, respectively.

2010-08-01

491

Design and Testing of Superconducting Microwave Passive Components for Quantum Information Processing  

CERN Document Server

We report on the design, fabrication and testing of two superconducting passive microwave components, a quadrature hybrid and a 20 dB directional coupler. These components are designed to be integrated with superconducting qubits or Josephson parametric amplifiers and used in quantum information processing applications. For the coupler, we measure return loss and isolation > 20 dB, and insertion loss 20 dB and insertion loss < 0.3 dB in a 10% band around 6.5 GHz. These values are within the design specifications of our application; however, we find a 7% difference between the designed and measured center frequency for the hybrid.

2010-01-01

492

Wake-up-call, a lin-52 paralogue, and Always early, a lin-9 homologue physically interact, but have opposing functions in regulating testis-specific gene expression  

UK PubMed Central (United Kingdom)

A conserved multi-subunit complex (MybMuvB, MMB), regulates transcriptional activity of many different target genes in Drosophila somatic cells. A paralogous complex, tMAC, controls...Full Text Available

2011-07-15

493

The stability of synthetic cutting fluids to microbe damage  

Energy Technology Data Exchange (ETDEWEB)

The resistance to microbe damages of aqueous solutions of cutting fluids (SOZh), which contain dual and more complex mixtures of known compounds, is studied. Lauric acid, myristic and tridecanic acid give microbic resistance to the compositions of synthetic cutting fluids. A complexing of the compositions as a rule does not support precisely expressed effects of synergism or antagonism.

1983-01-01

494

The Acidic Domain of Hepatitis C Virus NS4A Contributes to RNA Replication and Virus Particle Assembly?  

UK PubMed Central (United Kingdom)

Hepatitis C virus NS3-4A is a membrane-bound enzyme complex that exhibits serine protease, RNA helicase, and RNA-stimulated ATPase activities. This enzyme complex is essential for viral genome replication...Full Text Available

2011-02-01

495

Synthesis and radiolabelling of cysteine derivatives and pharmacological behaviour of their "9"9"mTc complexes  

International Nuclear Information System (INIS)

Full text: HMPAO, a butane monoxime derivative of propylene amine and ECD, ethyl cysteinate dimer, are currently being used as brain imaging agents. In an effort to develop new radiopharmaceuticals for imaging brain, we have synthesized amine and imine derivatives of ethyl cysteinate with butane monoxime, optimized labelling procedure with "9"9"mTc and studied the in vivo behaviour of their "9"9"mTc complexes. Imine derivative of ethyl cysteinate with butane monoxime was synthesized by refluxing equimolar amounts of butane monoxime and ethyl cystinate in dry benzene for 3 hours. The product was purified over silica with 10% ethyl acetate in chloroform as eluent. Amine derivative was prepared by reducing the imine derivative with sodium borohydride. The ligands were characterized by NMR spectroscopy and were found to be pure. The ligands were labelled with "9"9"mTc using stannous chloride as reducing agent. The complexes were characterized by ...

1998-09-01

496

Structural features and types of collectors of productive formations of the North Saremboyskiy field  

Energy Technology Data Exchange (ETDEWEB)

An examination is made of the structure of the North Saremboyskiy oil field and productive lower Devonian deposits of well 15. Based on detailed lithological studies, as well as investigation of filtering-capacitance properties of rocks, the complex structure of the carbonate deposits and the dominant development of complex type collectors is indicated.

1982-01-01

497

Spin-1/2 equations with tachyons and complex energies in small external fields  

International Nuclear Information System (INIS)

One normally identifies the prediction of tachyons with a higher spin problem. We show that the same phenomenon also happens with certain spin-1/2 equations, in exactly the same circumstances. Furthermore, we prove that these equations also have the defect of possessing solutions with complex energies, even with the smallest external fields. The consequences of these results are analyzed.

498

Metallic aggregate synthesis by radiolysis of simple or complex salt aqueous solutions. Study by electron microscope of aggregate grafting on carbon membranes  

International Nuclear Information System (INIS)

French ... Title Synthese d'agregats metalliques par radiolyse de solutions aqueuses de sels simples ou complexes. Etude par M. E. du greffage des agregats sur membranes de carbone.

1987-05-20

499

Formation and stabilization of anionic metal complexes in concentrated aqueous quaternary ammonium salt solutions  

Energy Technology Data Exchange (ETDEWEB)

Anionic complexes of transition metals were stabilized in aqueous solutions containing high concentrations of various short-chain quaternary ammonium salts. Compounds with longer paraffin chains were effective in much less concentrated solution. Complex ions were detected spectrophotometrically. FeCl/sub 4//sup -/, which is usually formed in concentrated HCl, was the predominant Fe(III) complex in 30 m choline chloride containing only 0.12 M HCl. A yellow transitory Tc(VII) chloro-addition intermediate, formed in the reduction of TcO/sub 4//sup -/ by concentrated HCl, was stabilized when the solution also contained 25 m choline chloride. Its spectrum, as well as the isolation of an already known Tc(VII) bipyridyl complex, is reported. Concentrated organic electrolytes also stabilized Tc(V) oxide halides against disproportionation and Tc(IV) hexahalides against hydrolysis. Halochromates of Cr(VI) were ...

1985-02-04