WorldWideScience
1

Investigation of the radiological safety concerns and medical history of the late Joseph T. Harding, former employee of the Paducah Gaseous Diffusion Plant  

Energy Technology Data Exchange (ETDEWEB)

An ex-employee's claims that inadequate enforcement of radiation safety regulations allowed excess radiation exposure thereby causing his deteriorating health was not substantiated by a thorough investigation.

1981-03-01

2

Sampling and Analysis at the Vortec Vitrification Facility in Paducah, Kentucky. Semiannual report, November 1, 1996--March 31, 1997  

Science.gov (United States)

The Vortec Cyclone Melting System (CMS) facility; to be located at the U.S. Department of Energy (DOE) Paducah Gaseous Diffusion Plant, is designed to treat soil contaminated with low levels of heavy metals and radioactive elements, as well as organic waste. The primary components of Vortec`s CMS are a counter rotating vortex (CRV) reactor and cyclone melter. In the CMS process, granular glass forming ingredients and other feedstocks are introduced into the CRV reactor where the intense CRV mixing allows the mixture to achieve a stable reaction and rapid heating of the feedstock materials. Organic contaminants in the feedstock are effectively oxidized, and the inert inorganic solids are melted. The University of North Dakota Energy {ampersand} Environmental Research Center (EERC) has been contacted to help in the development of sampling plans and to conduct the sampling at the facility. This document is written in a format ...

1997-12-31

3

Gas fixation solar cell using gas diffusion semiconductor electrode  

Energy Technology Data Exchange (ETDEWEB)

A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.

1980-12-23

4

The effects of a hot gaseous halo in galaxy major mergers  

CERN Document Server

Cosmological hydrodynamical simulations as well as observations indicate that spiral galaxies are comprised of five different components: dark matter halo, stellar disc, stellar bulge, gaseous disc and gaseous halo. While the first four components have been extensively considered in numerical simulations of binary galaxy mergers, the effect of a hot gaseous halo has usually been neglected even though it can contain up to 80% of the total gas within the galaxy virial radius. We present a series of hydrodynamic simulations of major mergers of disc galaxies, that for the first time include a diffuse, rotating, hot gaseous halo. Through cooling and accretion, the hot halo can dissipate and refuel the cold gas disc before and after a merger. This cold gas can subsequently form stars, thus impacting the morphology and kinematics of the remnant. Simulations of isolated systems with total ...

2011-01-01

5

Influence of mass transfer on thermogravimetric analysis of combustion and gasification reactivity of coke  

British Library Electronic Table of Contents (United Kingdom)

Non-isothermal TG/DTG measurements are widely used to determine kinetic parameters of oxidation and gasification of carbons, e.g. by multi-heating rate methods. Thereby it is important to avoid spurious effects due to diffusion limitations. In this work, TG/DTG experiments with activated carbon were conducted under isothermal and non-isothermal conditions. The agreement of the experimental results with results of simulations based on the intrinsic kinetics, pore diffusion and external diffusion in/to the sample (crucible) is very good. The simulations show that mass transfer has an unwanted influence on TG measurements, if the concentration of the gaseous reactant (O2 and CO2) is too low and/or the heating rate is too high. Based on literature data, the simulation was extended to blast fur...

2010-01-01

6

An aerial radiological survey of the Portsmouth Gaseous Diffusion Plant and surrounding area  

International Nuclear Information System (INIS)

An aerial radiological survey was conducted from August 10-16, 1993, over a 78-square-kilometer (30-square-mile) area of the Portsmouth Gaseous Diffusion Plant and surrounding area located near Portsmouth, Ohio. The survey was performed at a nominal altitude of 46 meters (150 feet) with a line spacing of 76 meters (250 feet). A contour map of the terrestrial gamma exposure rate extrapolated to 1 meter above ground level was prepared and overlaid on a set of United States Geological Survey topographic maps of the area and an aerial photograph of the plant. The terrestrial gamma exposure rates varied from about 7 to 14 microroentgens per hour at 1 meter above the ground. Protactinium-234m was observed at six sites within the boundaries of the plant. At a seventh site, only uranium-235 was observed. No other man-made, gamma ray-emitting radioactive material was present in a detectable quantity, either on or off the plant property. Soil sample and ...

2005-05-01

7

DISPOSAL OF FLUE GAS DESULFURIZATION WASTES: EPA SHAWNEE FIELD EVALUATION  

Science.gov (United States)

The report summarizes results of the flue gas desulfurization (FGD) waste disposal field evaluation project sponsored by EPA at TVA's Shawnee steam plant, Paducah, KY. This pilot-scale project, initiated in 1974 and completed in September 1980, evaluated methods and costs for dis...

8

Molina: a non-linear code to compute the internal hydrodynamics of a gas centrifuge  

Energy Technology Data Exchange (ETDEWEB)

Uranium enrichment by gas centrifugation relies on the pressure diffusion of the isotopes when their gaseous mixture is submitted to the pressure diffusion in the strong radial pressure gradient due to the centrifugal force in a very rapidly rotating cylinder. To compute the isotope separation in a gas centrifuge, the viscous compressible Navier-Stokes equations are solved for the mixture, then the diffusion equations are solved for the isotopes. As far as the separation performance is concerned, the models deal with the steady state of the axi-symmetric gas motion in the rotating cylinder. The numerical tools are briefly presented: first, the MOLINA code which numerically solves the axi-symmetric gas motion in the specific conditions of rapid rotation by use of a change of variables suited to the high density gradient and by use of a Marker And Cell method; then, the diffusion ...

2003-07-01

9

Water management studies in PEM fuel cells, part III: Dynamic breakthrough and intermittent drainage characteristics from GDLs with and without MPLs  

British Library Electronic Table of Contents (United Kingdom)

The transport of liquid water and gaseous reactants through a gas diffusion layer (GDL) is one of the most important water management issues in a proton exchange membrane fuel cell (PEMFC). In this work, the liquid water breakthrough dynamics, characterized by the capillary pressure and water saturation, across GDLs with and without a microporous layer (MPL) are studied in an ex-situ setup which closely simulates a real fuel cell configuration and operating conditions. The results reveal that recurrent breakthroughs are observed for all of the GDL samples tested, indicating the presence of an intermittent water drainage mechanism in the GDL. This is accounted for by the breakdown and redevelopment of the continuous water paths during water drainage as demonstrated by Haines jumps. For GDL ...

2010-01-01

10

Photocatalytic degradation of gaseous pyridine over zeolite-supported titanium dioxide  

Energy Technology Data Exchange (ETDEWEB)

The photocatalyzed degradation of pyridine in the gas phase was investigated using titanium dioxide semiconductor supported on mordenite. The complete mineralization was found to occur over a catalyst containing 75 wt% TiO{sub 2} and 25 wt% mordenite in about 180 min in the presence of saturated water vapor at O{degrees}C (4.6 Torr). Low water vapor pressure of 0.096 Torr was found to be sufficient to achieve a reasonably high percentage and rate of degradation. Diffusion of pyridine within the catalyst adversely affects the activity when the thickness of the catalyst coating exceeds the penetration depth of illumination. The activity of the zeolite-supported catalysts was higher than that of TiO{sub 2}. The photonic efficiency for the complete mineralization of pyridine to CO{sub 2} was determined to be 0.48. 29 refs., 6 refs., 1 tab.

1994-09-01

11

Alloying element diffusion in alloy 800 H (UNS N08810) and alloy 617 (UNS N06617)  

Energy Technology Data Exchange (ETDEWEB)

Samples of alloy 800 H (LJNS N08810) and alloy 617 (UNS N06617) were oxidized in a simulated process gas atmosphere. The principal elements of the gaseous environment were 50% H{sub 2}O, 35% H{sub 2} and 5% of CO{sub 2}, CO, and CH{sub 4}, respectively. The experiments were carried out at temperatures from 850 C to 950 C for exposures ranging from 600 to 5,000 hours. After the exposure, the alloy surfaces showed compact oxide layers, which resulted in a depleted zone of oxidizing elements in the substrate layer. Using Electron Probe Microanalysis (EPMA), concentration profiles and the extension of the depleted zone were measured. Calculated theoretical profiles were then fitted to the EPMA-measured profiles, using Fick`s second law of diffusion and resolved by a finite difference method and diffusion coefficients as fitting parameters. The diffusion coefficients for chromium may be represented as D = Do ...

1996-10-01

13

Photocatalytic degradation of gaseous benzene over TiO{sub 2}/Sr{sub 2}CeO{sub 4}: Preparation and photocatalytic behavior of TiO{sub 2}/Sr{sub 2}CeO{sub 4}  

Energy Technology Data Exchange (ETDEWEB)

The paper demonstrates that the photocatalytic activity of TiO{sub 2} towards the decomposition of gaseous benzene in a batch reactor can be greatly improved by loading TiO{sub 2} on the surface of Sr{sub 2}CeO{sub 4}. The research investigates the optimum loading amount of TiO{sub 2} on Sr{sub 2}CeO{sub 4} in enhancing the photocatalytic activity of TiO{sub 2}. The prepared photocatalyst was characterized by XRD, UV-vis diffuse reflectance and XPS analyses. TiO{sub 2} is loaded on Sr{sub 2}CeO{sub 4} at 773 K. TiO{sub 2}/Sr{sub 2}CeO{sub 4} absorbs much more visible light than TiO{sub 2}. The XPS spectrum shows that there are Ti, O, C, Sr elements on the surface of the TiO{sub 2}/Sr{sub 2}CeO{sub 4}, and that the binding energy value of Ti2p transfers to a lower value. TiO{sub 2}/Sr{sub 2}CeO{sub 4} demonstrates 2.0 times the photocatalytic activity of pure TiO{sub 2}. Based upon these observations, the mechanistic role of Sr{sub 2}CeO{sub 4} ...

2007-02-09

14

Law project adopted by the Senate and authorizing the ratification of the additional protocol to the agreement between France, the European atomic energy community and the international atomic energy agency relative to the application of warranties in France; Projet de loi adopte par le Senat autorisant la ratification du protocole additionnel a l'accord entre la France, la Communaute europeenne de l'energie atomique et l'Agence internationale de l'energie atomique relatif a l'application de garanties en Franc  

Energy Technology Data Exchange (ETDEWEB)

This project of law concerns an additional protocol to the agreement of warranties signed on September 22, 1998 between France, the European atomic energy community and the IAEA. This agreement concerns the declaration of all information relative to the R and D activities linked with the fuel cycle and involving the cooperation with a foreign country non endowed with nuclear weapons. These information include the trade and processing of nuclear and non-nuclear materials and equipments devoted to nuclear reactors (pressure vessels, fuel loading/unloading systems, control rods, force and zirconium tubes, primary coolant pumps, deuterium and heavy water, nuclear-grade graphite), to fuel reprocessing plants, to isotope separation plants (gaseous diffusion, laser enrichment, plasma separation, electromagnetic enrichment), to heavy water and deuterium production plants, and to uranium conversion plants. (J.S.)

2002-10-01

15

Electrochemical power generation apparatus and methods  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and methods are described for generating heat and electricity from the consumption of a variety of aluminum products. The method consists of (A) a reaction chamber containing an aqueous electrolyte solution and adapted for introduction therein of aluminum pieces of various shapes and sizes up to a certain maximum predetermined size and for effecting a chemical reaction between said aqueous electrolyte and said aluminum pieces yielding aluminum hydroxide and an intermediate reactant; (B) means for feeding said aluminum pieces into said reaction chamber in small quantities upon demand; (C) means for removing the heat generated in said chamber as a result of said reaction; (D) means for removing said aluminum hydroxide reaction product; and (E) means for oxidizing said intermediate reactant in an electrochemical cell, thereby generating electrical energy. The intermediate reactant is preferably hydrogen or zinc. The latter may be used in a slurry type zinc/air battery, whereas ...

1981-03-03

16

Electrochemical power generation  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and methods for generating heat and electricity from the consumption of a variety of aluminum products comprise: (A) a reaction chamber containing an aqueous electrolyte solution and adapted for introduction therein of aluminum pieces of various shapes and sizes up to a certain maximum predetermined size and for effecting a chemical reaction between said aqueous electrolyte and said aluminum pieces yielding aluminum hydroxide and an intermediate reactant; (B) means for feeding said aluminum pieces into said reaction chamber in small quantities upon demand; (C) means for removing the heat generated in said chamber as a result of said reaction; (D) means for removing said aluminum hydroxide reaction product; and (E) means for oxidizing said intermediate reactant in an electrochemical cell, thereby generating electrical energy. The intermediate reactant is preferably hydrogen or zinc. The latter may be used in a slurry type zinc/air battery, whereas hydrogen is preferably ...

1983-01-18

17

An aerial radiological survey of the Oak Ridge Reservation, Oak Ridge, Tennessee  

International Nuclear Information System (INIS)

An aerial radiological survey of the Oak Ridge Reservation (ORR) and surrounding area in Oak Ridge, Tennessee, was conducted during the period March 30 to April 14,1992. The purpose of the survey was to measure and document the terrestrial radiological environment of the Oak Ridge Reservation for use in environmental management programs and emergency response planning. The aerial survey was flown at an altitude of 150 feet (46 meters) along a series of parallel lines 250 feet (76 meters) apart and included X-10 (Oak Ridge National Laboratory), K-25 (former Gaseous Diffusion Plant), Y-12 (Weapons Production Plant), the Freels Bend Area and Oak Ridge Institute for Science and Education, the East Fork Poplar Creek (100-year floodplain extending from K-25 to Y-12), Elza Gate (former uranium ore storage site located in the city of Oak Ridge), Parcel A, the Clinch River (river banks extending from Melton Hill Dam to the city of Kingston), and the CSX ...

1993-06-22

18

Liquid nitrogen dewar for protein crystal growth  

Science.gov (United States)

Gaseous Nitrogen Dewar apparatus developed by Dr. Alex McPherson of the University of California,

2001-01-01

19

Gaseous dielectrics V  

Energy Technology Data Exchange (ETDEWEB)

This book discusses the progress and problems of current interest in gaseous dielectrics and their use, with special emphasis on insulation in high-voltage transmission lines and substations. Topics covered include: basic physics of gaseous dielectrics; basic mechanisms; gas decomposition, reactions and toxicity; diagnostics and field probes; gases and mixtures for GIS transformers and circuit breakers; gaseous media for discharge chemistry and etching/corona; gas engineering for pulsed power and switching; gas breakdown under steep-fronted voltages; new developments in gas-insulated equipment and gas handling; gas/insulator interface/flashover; and quality control in testing gas-insulated equipment. Contains approximately 85 papers.

1987-01-01

20

Physics of thermal gaseous nebulae  

Energy Technology Data Exchange (ETDEWEB)

Much of the material presented in this book derived originally from the series ''Physical Processes in Gaseous Nebulae'' initiated at the Harvard College Observatory in the 1930's. The subject of gaseous nebulae, which offers opportunities for studies of stellar evolution, should be of interest to atomic physicists, spectroscopists, plasma experts, and to observers and theoreticians alike for the study of attenuated ionized gases.

1984-01-01

21

Gas-diesel dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a gas-diesel dual fuel engine apparatus having a diesel engine, a diesel fuel supply system including a diesel fuel injection pump, a gaseous fuel supply system including gaseous fuel regulating valve, and a governing and controlling device for governing the speed of the engine and controlling the switchover of the operation of the engine between a diesel fuel mode and a gaseous fuel mode.

1986-08-05

22

Control of Phosphorus Transient Enhanced Diffusion using Co-implantation  

CERN Document Server

Control of Phosphorus Transient Enhanced Diffusion using Co-implantation

2006-01-01

23

Sensitivity of dual fuel engine combustion and knocking limits to gaseous fuel composition  

International Nuclear Information System (INIS)

Combustion noise, knock and ignition limits data are measured and presented for a dual fuel engine running on dual fuels of Diesel and three gaseous fuels separately. The gaseous fuels used are liquefied petroleum gas, pure methane and compressed natural gas mixture. The maximum pressure rise rate during combustion is presented as a measure of combustion noise, and the knocking and ignition limits are presented as torque output at the onset of knocking and ignition failure. Experimental investigation on the dual fuel engine revealed the noise generated from combustion, knocking and ignition limits for all gases at different design and operating conditions. A Ricardo E6 Diesel version engine is converted to run on dual fuel of Diesel and the tested gaseous fuel and is used throughout the work. The engine is fully computerized, and the cylinder pressure data, crank angle data and engine operating variables are stored in a PC ...

2004-02-01

24

Influence of performance characteristic of a gaseous fuel supply system on hydrocarbon emissions of a dual-fuel engine  

Energy Technology Data Exchange (ETDEWEB)

The performance of the gaseous fuel supply and its influence on hydrocarbon (HC) emissions of dual-fuel engines have been investigated. A new design of manifold respirators with mixers is also presented in the paper. The design of the gaseous fuel supply system has a great influence on HC emissions in the dual-fuel engine at light load. The problem of scavenging is discussed and solved by using the manifold respirators in the dual-fuel engine. It performs the function of retarding the gaseous fuel entry timing from the moment of intake valve opening, and its delaying effects have been measured and tested. Experimental results show that the manifold respirator gives the best performance in reducing HC emissions compared with a common pipe mixer and a respirator with bo miser. In addition, the mixing effects are sensitive to the mixer configuration. (Author)

2000-11-01

25

Fuel conversion apparatus and method  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and method are described for the vaporization of liquid fuel oils to produce a gaseous mixture suitable for burning in a burner normally designed for operation utilizing natural gas.

1981-11-24

26

0100127 - Liquid nitrogen dewar for protein crystal growth - NASA  

Science.gov (United States)

Gaseous Nitrogen Dewar apparatus developed by Dr. Alex McPherson of the University of California, Irvine for use aboard Mir and the International Space ...

27

NASA/DOD Aerospace Knowledge Diffusion Research Project. Paper 10: The NASA/DOD Aerospace Knowledge Diffusion Research Project  

Science.gov (United States)

The role of the NASA/DOD Aerospace Knowledge DIffusion Research Project in helping to maintain U.S.

1991-01-01

28

Diffusion in Brain Extracellular Space  

UK PubMed Central (United Kingdom)

Diffusion in the extracellular space (ECS) of the brain is constrained by the volume fraction and the tortuosity and a modified diffusion equation represents the transport behavior of many molecules...Full Text Available

2008-10-01

29

An examination of the ignition delay period in gas-fueled diesel engines  

Energy Technology Data Exchange (ETDEWEB)

Changes in the physical and chemical processes during the ignition delay period of a gas-fueled diesel engine (dual-fuel engine) due to the increased admission of the gaseous fuels and diluents are examined. The extension to the chemical aspects of the ignition delay with the added gaseous fuels and the diluents into the cylinder charge is evaluated using detailed reaction kinetics for the oxidation of dual-fuel mixtures at an adiabatic constant volume process while employing n-heptane as a representative of the main components of the diesel fuel. In the examination of the physical aspects of the delay period, the relative contributions of changes in charge temperature, pressure, physical properties, pre-ignition energy release, heat transfer, and the residual gas effects due to the admission of the gaseous fuels are discussed and evaluated. It is shown that the introduction of gaseous fuels and ...

1998-01-01

31

Air shifting diffusion; Diffusion d'air par deplacement  

Energy Technology Data Exchange (ETDEWEB)

The technique of air diffusion by shifting presents several advantages in terms of thermal comfort, indoor air quality and energy conservation. This book presents the principle, dimensioning, and implementation of air shifting diffusion systems. (J.S.)

2001-07-01

33

Diffusion Zink Planting of Steels  

International Science & Technology Center (ISTC)

Research on Diffusion Zinc Cladding of Structural Steels, as Well as Their Mechanical and Corrosion Properties to Replace Their Cyanic Cadmium Plating

34

An Experimental Investigation of Short Diffusers for Gas ...  

Science.gov (United States)

... within an accuracy of +5 psig. 2. Starting Pressure and Diffuser Geometra Preliminary, tests indicated that the geometry suggested by Ref. ...

1974-06-01

35

Results of the remote sensing feasibility study for the uranium hexafluoride storage cylinder yard program  

Energy Technology Data Exchange (ETDEWEB)

The US DOE manages the safe storage of approximately 650,000 tons of depleted uranium hexafluoride remaining from the Cold War. This slightly radioactive, but chemically active, material is contained in more than 46,000 steel storage cylinders that are located at Oak Ridge, Tennessee; Paducah, Kentucky; and Portsmouth, Ohio. Some of the cylinders are more than 40 years old, and approximately 17,500 are considered problem cylinders because their physical integrity is questionable. These cylinders require an annual visual inspection. The remainder of the 46,000-plus cylinders must be visually inspected every four years. Currently, the cylinder inspection program is extremely labor intensive. Because these inspections are accomplished visually, they may not be effective in the early detection of leaking cylinders. The inspection program requires approximately 12--14 full-time-equivalent (FTE) employees. At the cost of approximately $125K per FTE, this translates to ...

1997-02-01

36

Mathematical model for radon diffusion in earthen materials  

Energy Technology Data Exchange (ETDEWEB)

Radon migration in porous, earthen materials is characterized by diffusion in both the air and water components of the system as well as by the interaction of the radon between the air and water. The size distribution and configuration of the pore spaces and their moisture distributions are key parameters in determining the radon diffusion coefficient for the bulk material. A mathematical model is developed and presented for calculating radon diffusion coefficients solely from the moisture content and pore size distribution of a soil, reducing the need for resorting to radon diffusion measurements. The resulting diffusion coefficients increase with the median pore diameter of the soil and decrease with increasing widths of the pore size distribution. The calculated diffusion coefficients are suitable for use in simple homogeneous-medium ...

1982-10-01

37

The effects of pilot fuel quality on the ignition delay of gas fueled diesel engines  

Energy Technology Data Exchange (ETDEWEB)

The effects of changes in the cetane number of liquid pilot fuels on the ignition delay period in dual fuel engines were investigated experimentally. Various pilot fuel quantities were employed with methane, propane and low heating value gaseous fuel mixtures over a wide range of engine load.the ignition delay variation with increased gaseous fuel admission showed a strong dependence on both the quantity and the quality of the pilot fuel used. It was found that the use of high cetane number pilot liquid fuels permitted smaller pilot quantities to be used satisfactorily. Engine operation on propane and low heating value gaseous fuels improved in comparison with dual fuel engine operation employing common diesel fuels.

1997-07-01

38

Calculation of the radionuclide concentration in gaseous effluents from the Daya Bay Nuclear Power Plant  

International Nuclear Information System (INIS)

Presented here is the calculation of radionuclide concentration in gaseous effluents from the Daya Bay Nuclear Power Plant by using the Gaussian model, based on the analysis of the radionuclides in gaseous effluents and based on the measured wind field in the area of Guangdong province in November 2005. The calculating results about the relative concentration distribution of the radionuclides in Guangdong province, especially in Daya Bay, Shengzheng, Zhuhai and Guangzhou, are obtained. These results can provide reference data for the effect of radiation on the environment of Guangdong province under normal conditions of operation of the Daya Bay Nuclear Power Plant. It can also provide reference data for monitoring possible nuclear incidents in nuclear power plants. (authors)

2007-07-01

39

Analytical examination of the preignition processes within homogeneous mixtures of a gaseous fuel and air in a motored engine  

Energy Technology Data Exchange (ETDEWEB)

Examination is made of the main features of the physical and chemical preignition processes within homogeneous mixtures of air and gaseous fuels, such as propane, methane and hydrogen in a motored engine, while employing detailed chemical kinetics in a one zone analytical model. The changes in the compression temperature and pressure due to the admission of gaseous fuels, energy release during the preingition reactions and the contributions of heat transfer and residual gases to the preignition reaction activity were followed over a number of consecutive cycles until the occurrence of autoignition. Some of the observed differences in engine behaviour when operating on methane, propane and hydrogen were discussed with particular reference to the observed trends in dual fuel engine operation. Calculated results showed good agreement with some corresponding experimental trends. 14 refs., 9 figs.

1994-10-01

40

Radiation-stimulated diffusion of aerosols  

Energy Technology Data Exchange (ETDEWEB)

The diffusion coefficient of particles in radioactive gases has been calculated with account of random wandering of aerosols (occurrence of local fields affecting the particles; recoils accompanying radiation emitted by particles, etc.). To determine the diffusion coefficient, the method of Fokker-Planck equation derivation was used. A formula is presented for calculating the radiation-stimulated diffusion coefficient. A linear growth of the diffusion coefficient with radioactivity is noted according to the formula, the diffusion coefficient is mainly determined by the field in the radiation damage region. The aerosol radioactivity may result in a more rapid deposition of aerosols in the pipelines and aerosol purification systems. The diffusion rate grows not only in the presence of intrinsic radioactivity but in case of external radiation exposure as well.

1984-04-01

41

Utility of CT in the diagnosis of psoitis  

International Nuclear Information System (INIS)

A 65-year-old woman who was diagnosed as having psoitis by CT findings, which disclosed non-symmetrical dilation of the psoas muscle and gaseous image. Pus from the psoas muscle seen at surgery corresponded to CT findings. Preoperative CT examination was useful in the establishment of diagnosis. (Namekawa, K.).

1984-01-01

43

Methane conversion process using phosphate-containing catalysts  

Energy Technology Data Exchange (ETDEWEB)

A process is described for covering methane to a higher order hydrocarbon comprising contacting a gaseous reactant consisting of methane with a phosphate-containing catalyst for a sufficient period of time and at an effective temperature to provide the phosphate-containing catalyst consisting essentially of the higher order hydrocarbon. The catalyst is represented by a formula.

1987-05-12

44

Laser hardening of titanium-zirconium alloy  

International Nuclear Information System (INIS)

The methods of surface modification of Ti-Zr alloy by laser treatment are considered. Characteristics of laser modification without- and with surface melting and with melting in different gaseous environments and with nickel microalloying are presented. Maximum depth, hardness and corrosion resistance are observed under nickel laser alloying.

45

Gaseous fuels and other alternative fuels  

Energy Technology Data Exchange (ETDEWEB)

This book contains papers relating to the 1990 Future Transportation Technology Conference and Exposition. Included are the following papers; Examination of rich mixtures operation of a dual fuel engine, A hybrid natural gas vehicles, Performance analysis of a spark ignited engine with ETBE as a blending agent.

1990-01-01

46

Formation and fate of gaseous and particulate mutagens and carcinogens in real and simulated atmospheres.  

UK PubMed Central (United Kingdom)

The growing use of coal for heating and electric power generation and diesel engines in light duty motor vehicles will increase not only the existing atmospheric concentrations of criteria pollutants...Full Text Available

1983-01-01

47

Developments of heavy-ion gas detectors at LNL  

Energy Technology Data Exchange (ETDEWEB)

The most important developments in gaseous detectors at LNL are reviewed. Some aspects of timing, pulse height and position resolutions of avalanche counters are reported. The experimental work on heavy-ion identification by Bragg curve spectroscopy is summarized.

1984-05-01

48

Catalyst for olefin production  

Energy Technology Data Exchange (ETDEWEB)

A process is claimed for selectively preparing alpha-olefins having from 2 to about 22 carbon atoms by contacting a gaseous mixture containing carbon monoxide and hydrogen with an iron titanate alkali metal hydroxide catalyst at reaction conditions correlated so as to favor the formation of a substantial proportion of such alpha-olefin product.

1981-04-14

49

An experimental and numerical investigation of the combustion characteristics of a dual fuel engine with a swirl chamber  

Energy Technology Data Exchange (ETDEWEB)

The results of an experimental investigation of the performance of a small bore engine with a swirl chamber when operating as a dual fuel engine with commercial methane as the gaseous fuel were presented in this paper. The experiment involved using a 3-dimensional computational fluid dynamics model to predict the performance of the engine. A detailed chemical kinetics for the gaseous fuel component, consisting primarily of methane and a reduced detailed chemical kinetics for the diesel fuel while considering the turbulent combustion processes an associated performance of a dual fuel engine with a swirl chamber were incorporated in the simulation. The study experimentally and numerically investigated the effects of changes in the quantities of the liquid fuel pilot and gaseous fuels on the combustion processes, engine performance, cyclic variations, and emissions. The paper discussed the experimental approach and results. It ...

2007-07-01

50

Diffusion modeling of ion implanted boron in Si during RTA: Correlation of extended defect formation and annealing with the enhanced diffusion of boron  

International Nuclear Information System (INIS)

Accurate modeling of the enhanced diffusion of boron during rapid thermal annealing has been accomplished by incorporating the effects of extended defect formation and annealing on enhanced diffusion into a multizone, semiempirical model. The multizone model divides the implant profile into three zones defining regions of different defects and diffusion enhancements. The model also contains the initial enhanced diffusion and the transient diffusion effects associated with the dissolution of defect clusters and the annealing of extended defects, respectively. The saturation time for transient-enhanced diffusion contains an exponential function of implant dose in order to model the increase in point defect generated with higher implant dose. As a result, the model accurately simulates the boron diffusion profile over a wide range of implant ...

51

On the theory of transient enhanced diffusion in boron-implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

Transient enhanced diffusion in boron-implanted silicon is interpreted as being due to the fact that during rapid thermal annealing a relaxation process takes place, associated with quasi-chemical reactions including defects. A simple analytical model makes it possible to describe the annealing mechanism on a microscopic scale in terms of reaction-diffusion processes. The measured dependences of the boron diffusion coefficient of the enhanced diffusion on time, temperature and implantation energy are satisfactorily explained. (author).

1991-01-01

52

On the theory of transient enhanced diffusion in boron-implanted silicon  

International Nuclear Information System (INIS)

Transient enhanced diffusion in boron-implanted silicon is interpreted as being due to the fact that during rapid thermal annealing a relaxation process takes place, associated with quasi-chemical reactions including defects. A simple analytical model makes it possible to describe the annealing mechanism on a microscopic scale in terms of reaction-diffusion processes. The measured dependences of the boron diffusion coefficient of the enhanced diffusion on time, temperature and implantation energy are satisfactorily explained. (author).

53

Modeling of defect-phosphorus pair diffusion in phosphorus-implanted silicon  

International Nuclear Information System (INIS)

The point-defect-impurity pair diffusion model proposed recently by Mulvaney and Richardson is adopted and modified to simulate the coupled diffusion of phosphorus and self-interstitials in phosphorus-implanted silicon. The assumption of implantation-induced, but empirically determined initial interstitial distributions of Gaussian shape allows a simulation of the net effect of transient enhanced diffusion. As a result an improved modeling of phosphorus diffusion in silicon is achieved for a broad range of ion-implantation and annealing conditions. (author).

54

Diffusion in silicon isotope heterostructures  

Science.gov (United States)

The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded ...

2004-05-14

55

Boron uphill diffusion during ultrashallow junction formation  

International Nuclear Information System (INIS)

The recently observed phenomenon of boron uphill diffusion during low-temperature annealing of ultrashallow ion-implanted junctions in silicon has been investigated. It is shown that the effect is enhanced by preamorphization, and that an increase in the depth of the preamorphized layer reduces uphill diffusion in the high-concentration portion of boron profile, while increasing transient enhanced diffusion in the tail. The data demonstrate that the magnitude of the uphill diffusion effect is determined by the proximity of boron and implant damage to the silicon surface.

2003-05-26

56

Uptake of iodine-131 in gaseous state on Ag-impregnated amberlite IR-120 resin and its comparison with activated charcoal. [dry and wet conditions  

Energy Technology Data Exchange (ETDEWEB)

The paper describes uptake of gaseous lodine-131 on silver impregnated organic resin, Amberlite IR-120, available at the Secondary Steam Generator (S.S.G.) Opening at T.A.P.S. in comparison with activated charcoal. The experiments are conducted in dry and wet conditions by soaking the impregnated resin and activated charcoal in distilled water for wet condition. The paper also describes the iodine sampler specially designed and fabricated for these experiments.

1982-01-01

57

In situ bioremediation using horizontal wells  

Energy Technology Data Exchange (ETDEWEB)

In Situ Bioremediation (ISB), which is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation, remediates soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISB involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove .VOCs from the vadose zone concomitant with biodegradation of VOCs. The innovation is in the combination of 3 emerging technologies, air stripping, horizontal wells, and bioremediation via gaseous nutrient injection with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

1995-04-01

58

The effect of aqueous composition on diffusion coefficient in bentonite  

International Nuclear Information System (INIS)

The diffusion coefficients (De) in bentonite were measured to understand and quantify the influence of groundwater chemistry such as ionic strength and to quantify the alteration of smectite mineralogical transformations. (author)

2009-12-01

59

Opposed jet diffusion flames of nitrogen-diluted hydrogen vs air - Axial LDA and CARS surveys; fuel/air rates at extinction  

Science.gov (United States)

An experimental study of H-air counterflow diffusion flames (CFDFs) is reported. Coaxial tubular

1989-01-01

60

NASA/DOD Aerospace Knowledge Diffusion Research Project. Paper 19: Computer and information technology and aerospace knowledge diffusion  

Science.gov (United States)

To remain a world leader in aerospace, the US must improve and maintain the professional competency

1992-01-01

61

Effective diffusion coefficient of radon in concrete, theory and method for field measurements  

International Nuclear Information System (INIS)

A linear diffusion model serves as the basis for determination of an effective radon diffusion coefficient in concrete. The coefficient was needed to later allow quantitative prediction of radon accumulation within and behind concrete walls after application of an impervious radon barrier. A resolution of certain discrepancies noted in the literature in the use of an effective diffusion coefficient to model diffusion of a radioactive gas through a porous medium is suggested. An outline of factors expected to affect the concrete physical structure and the effective diffusion coefficient of radon through it is also presented. Finally, a field method for evaluating effective radon diffusion coefficients in concrete is proposed and results of measurements performed on a concrete foundation wall are compared with similar published values of gas ...

62

Effect of engine parameters and type of gaseous fuel on the performance of dual-fuel gas diesel engines. A critical review  

Energy Technology Data Exchange (ETDEWEB)

Petroleum resources are finite and, therefore, search for their alternative non-petroleum fuels for internal combustion engines is continuing all over the world. Moreover gases emitted by petroleum fuel driven vehicles have an adverse effect on the environment and human health. There is universal acceptance of the need to reduce such emissions. Towards this, scientists have proposed various solutions for diesel engines, one of which is the use of gaseous fuels as a supplement for liquid diesel fuel. These engines, which use conventional diesel fuel and gaseous fuel, are referred to as 'dual-fuel engines'. Natural gas and bio-derived gas appear more attractive alternative fuels for dual-fuel engines in view of their friendly environmental nature. In the gas-fumigated dual-fuel engine, the primary fuel is mixed outside the cylinder before it is inducted into the cylinder. A pilot quantity of liquid fuel is injected towards the ...

2009-08-15

63

Gas-diesel dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

A gas-diesel dual fuel engine apparatus is described having a diesel engine, a diesel fuel supply system including a diesel fuel injection pump, a gaseous fuel supply system including a gaseous fuel regulating valve, and a governing and controlling device for governing the speed of the engine through the control of fuel supplied to the engine and controlling the switchover of the operation of the engine between a diesel fuel mode and a gaseous fuel mode. The improvement of the governing and controlling device consists of: (a) at least one electronic governor means adapted to compare a speed signal representing the actual operating speed of the diesel engine with a set speed signal representing the set speed thereof; (b) a pair of electric actuator means having respective power amplifier circuits and mechanically connected to the diesel fuel injection pump and the gaseous fuel regulating valve, ...

1986-03-18

64

Emissions results for dedicated propane Chrysler minivans: the 1996 propane vehicle challenge  

Energy Technology Data Exchange (ETDEWEB)

The U.S. Department of Energy (US DOE), through Argonne National Laboratory, and in cooperation with Natural Resources-Canada and Chrysler Canada, sponsored and organized the 1996 Propane Vehicle Challenge (PVC). For this competition , 13 university teams from North America each received a stock Chrysler minivan to be converted to dedicated propane operation while maintaining maximum production feasibility. The converted vehicles were tested for performance (driveability, cold- and hot-start, acceleration, range, and fuel economy) and exhaust emissions. Of the 13 entries for the 1996 PVC, 10 completed all of the events scheduled, including the emissions test. The schools used a variety of fuel-management, fuel-phase and engine-control strategies, but their strategies can be summarized as three main types: liquid fuel-injection, gaseous fuel-injection, and gaseous carburetor. The converted vehicles performed similarly to the gasoline minivan. ...

1997-02-01

65

Effects of diluent admissions and intake air temperature in exhaust gas recirculation on the emissions of an indirect injection dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

The operation of Diesel engines on gaseous fuels, commonly known as dual fuel engines, uses Diesel fuel as the pilot fuel and gaseous fuel (methane and sometimes propane in the present work) as the main fuel. The gaseous fuel was inducted in the intake manifold to mix with the intake air. The investigation was conducted on a high speed indirect injection (Ricardo-E6) dual fuel engine and was concerned with the effects of exhaust gas recirculation (EGR) on the dual fuel engine combustion and emissions, in particular, the effects of intake air temperature and diluent admissions (N{sub 2} and CO{sub 2}) on combustion and emissions. The use of diluents to displace oxygen (O{sub 2}) in the intake air resulted in a reduction in the O{sub 2} supplied to the engine, increased the inlet charge thermal capacity (thermal effect) and, potentially, CO{sub 2} and N{sub 2} participated in the combustion process (chemical effect). In a ...

2001-05-01

66

Mass and charge transfer on various relevant scales in polymer electrolyte fuel cells[Dissertation 16991  

Energy Technology Data Exchange (ETDEWEB)

This dissertation is concerned with the development, experimental diagnostics and mathematical modelling and simulation of polymer electrolyte fuel cells (PEFC). The central themes throughout this thesis are the closely interlinked phenomena of mass and charge transfer. In the face of developing a PEFC system for vehicle propulsion these phenomena are scrutinized on a broad range of relevant scales. Starting from the material related level of the membrane and the gas diffusion layer (GDL) we turn to length scales, where structural features of the cell additionally come into play. These are the scale of flow channels and ribs, the single cell and the cell stack followed by the cell, stack, and system development for an automotive power train. In Chapter 3 selected fundamental material models and properties, respectively, are explored that are crucial for the mathematical modelling and simulation of PEFC, as needed in some succeeding parts of this work. First, ...

2007-07-01

68

Transient enhanced diffusion of oxygen in Fe mediated by large electronic excitation  

International Nuclear Information System (INIS)

Contrary to the electronic excitation induced phenomena of desorption and sputtering, we observed incorporation of oxygen in a thin Fe film during its irradiation with swift heavy ions. It is observed that the adsorbed oxygen diffuses in to the Fe film. The incorporation of oxygen and its diffusion in the bulk of the film is a manifestation of extremely large electronic energy deposition by the incident ions. It is shown that the experimentally observed high diffusivity of oxygen in Fe during irradiation is due to the existence of transient melt phase of Fe.

2003-10-15

69

The Application of Diffusion Approximations to the Study of ...  

Science.gov (United States)

... Descriptors : *QUEUEING THEORY, *APPROXIMATION ... MODELS, OPTIMIZATION, STOCHASTIC PROCESSES ... Categories : TERMINAL FLIGHT ...

79

Radon diffusion studies through building construction materials using solid state nuclear track detectors  

International Nuclear Information System (INIS)

Radon appears mainly by diffusion processes from the point of origin following #alpha#- decay of "2"2"6Ra in underground soil and building materials used, in the construction of floors, walls, and ceiling. The transport phenomenon of radon through diffusion is a significant contributor to indoor radon entry. In the present study radon diffusion through sand, cement, mixtures of sand + cement (1:1), sand + cement (2:1), sand + cement (3:1), sand + cement (4:1) has been carried out using LR-115 type II solid state nuclear track detectors (SSNTDs). The radon diffusion coefficient and diffusion lengths have been calculated for different materials. The effect of compaction, which changes the porosity and permeability of the materials, on radon diffusion has also been studied. (author)

2003-10-16

80

Models for growth kinetics of A-15 compounds by solid state diffusion  

International Nuclear Information System (INIS)

In the formation of A-15 superconducting compounds by solid state diffusion, the time exponent in the growth law under different experimental conditions varies widely from about 0.25 to 1.0. Specific models of growth for different operative rate-controlling conditions are proposed. When the diffusion of B atoms in the matrix is rate-controlling, the thickness of the reacted compound layer increases as tsup(1/2) or tsup(2/3). When the diffusion of B atoms through the compound layer is rate controlling, a tsup(1/2) dependence both for bulk diffusion and grain-boundary diffusion is predicted. When substantial grain growth occurs in the reacted layer during the diffusion anneal, the time exponent observed could be as low as 1/4. Experimental data in support of the predictions of the proposed models are presented. (author).

81

Diffusion of antimony in silicon in the presence of point defects  

Energy Technology Data Exchange (ETDEWEB)

We have investigated the diffusion of Sb in Si in the presence of defects injected by high-energy implantation of Si ions at room temperature. MeV ion implantation increases the concentrations of vacancies, which induce transient-enhanced diffusion of Sb deposited in Si. We observed a significant enhancement of Sb diffusion. Secondary ions mass spectroscopy has been performed on the implanted samples before and after annealing. Rutherford-backscattering spectrometry has been used to characterize the high-energy implantation damage. By fitting diffusion profiles to a linear diffusive model, information about atomic scale diffusion of Sb, i.e. the generation rate of mobile state Sb and its mean migration length were extracted.

2007-08-15

82

Diffusion of antimony in silicon in the presence of point defects  

International Nuclear Information System (INIS)

We have investigated the diffusion of Sb in Si in the presence of defects injected by high-energy implantation of Si ions at room temperature. MeV ion implantation increases the concentrations of vacancies, which induce transient-enhanced diffusion of Sb deposited in Si. We observed a significant enhancement of Sb diffusion. Secondary ions mass spectroscopy has been performed on the implanted samples before and after annealing. Rutherford-backscattering spectrometry has been used to characterize the high-energy implantation damage. By fitting diffusion profiles to a linear diffusive model, information about atomic scale diffusion of Sb, i.e. the generation rate of mobile state Sb and its mean migration length were extracted.

2007-08-01

83

Application of high energy ion beam for the control of boron diffusion  

Energy Technology Data Exchange (ETDEWEB)

For the purpose of optimizing the process of co-implantation of MeV Si ions to reduce boron transient enhanced diffusion and boron-enhanced diffusion in Si, multiple MeV implantations and annealing at different temperatures have been performed. A slight improvement on the suppression of B diffusion is observed by adding a low temperature annealing step after the MeV implantation. No differences in B diffusion are observed when the Si doses are increased from 1 x 10{sup 15} to 1 x 10{sup 16} cm{sup -2}. This dose independent behavior is speculated to be a quasi-steady state of vacancy cluster evaporation.

2006-01-15

84

Application of high energy ion beam for the control of boron diffusion  

International Nuclear Information System (INIS)

For the purpose of optimizing the process of co-implantation of MeV Si ions to reduce boron transient enhanced diffusion and boron-enhanced diffusion in Si, multiple MeV implantations and annealing at different temperatures have been performed. A slight improvement on the suppression of B diffusion is observed by adding a low temperature annealing step after the MeV implantation. No differences in B diffusion are observed when the Si doses are increased from 1 x 10"1"5 to 1 x 10"1"6 cm"-"2. This dose independent behavior is speculated to be a quasi-steady state of vacancy cluster evaporation.

2006-01-01

85

Trapping technology for gaseous fission products from voloxidation process  

Energy Technology Data Exchange (ETDEWEB)

The objective of this report is to review the different technologies for trapping the gaseous wastes containing Cs, Ru, Tc, {sup 14}C, Kr, Xe, I and {sup 3}H from a voloxidation process. Based on literature reviews and KAERI's experimental results on the gaseous fission products trapping, appropriate trapping method for each fission product has been selected considering process reliability, simplicity, decontamination factor, availability, and disposal. Specifically, the most promising trapping method for each fission product has been proposed for the development of the INL off-gas trapping system. A fly ash filter is proposed as a trapping media for a cesium trapping unit. In addition, a calcium filter is proposed as a trapping media for ruthenium, technetium, and {sup 14}C trapping unit. In case of I trapping unit, AgX is proposed. For Kr and Xe, adsorption on solid is proposed. SDBC (Styrene Divinyl Benzene Copolymer) is also ...

2005-05-15

86

Exhaust emissions from an indirect injection dual-fuel engine  

Energy Technology Data Exchange (ETDEWEB)

Diesel engines operating on gaseous fuels are commonly known as dual-fuel engines. In the present work, a single-cylinder, compression ignition, indirect injection research (Ricardo E6) engine has been installed at United Arab Emirates University for investigation of the exhaust emissions when the engine is operating as a dual-fuel engine. The influence of changes in major operating and design parameters, such as the concentration of gaseous fuel in the cylinder charge, pilot fuel quantity, injection timing and intake temperature, on the production of exhaust emissions was investigated. Diesel fuel was used as the pilot fuel, while methane or propane was used as the main fuel which was inducted in the intake manifold and mixed with the intake air. The experimental investigations showed that the poor emissions at light loads can be improved significantly by increasing the concentration of gaseous fuel (total equivalence ...

2000-04-01

87

Evaluation of Neonatal Membrane Oxygenators With Respect to Gaseous Microemboli Capture and Transmembrane Pressure Gradients  

British Library Electronic Table of Contents (United Kingdom)

Abstract A series of studies performed at our center demonstrates that gaseous microemboli (GME) remain a challenge in cardiac surgical procedures. Evaluation of novel oxygenators must address hemodynamic parameters and microemboli capture capability. The objective of this study is to compare two neonatal membrane oxygenators, the Quadrox i (MAQUET Cardiopulmonary AG, Hirrlingen, Germany) and the Capiox RX05 (Terumo Corporation, Tokyo, Japan), with respect to GME capture and hemodynamic energy delivery. The experimental circuit included a Maquet HL 20 heart lung machine, a Heater Cooler Unit HCU 30 (MAQUET Cardiopulmonary AG), a membrane oxygenator (Quadrox i Neonatal or Capiox RX05), and inch tubing from the COBE Heart/Lung Perfusion Pack (COBE Cardiovascular, Inc., Arvada, CO, USA). A Ca...

2010-01-01

88

Evaluation of HL 20 Roller Pump and Rotaflow Centrifugal Pump on Perfusion Quality and Gaseous Microemboli Delivery  

British Library Electronic Table of Contents (United Kingdom)

Abstract The purpose of this study was to compare the HL 20 roller pump (Jostra USA, Austin, TX, USA) and Rotaflow centrifugal pump (Jostra USA) on hemodynamic energy production and gaseous microemboli (GME) delivery in a simulated neonatal cardiopulmonary bypass (CPB) circuit under nonpulsatile perfusion. This study employed a simulated model of the pediatric CPB including a Jostra HL 20 heart lung machine (or a Rotaflow centrifugal pump), a Capiox BabyRX05 oxygenator (Terumo Corporation, Tokyo, Japan), a Capiox pediatric arterial filter (Terumo Corporation), and inch tubing. The total volume of the experimental system was 700 mL (500 mL for the circuit and 200 mL for the pseudo neonatal patient). The hematocrit was maintained at 30% using human blood. At the beginning of each trial, a 5 ...

2010-01-01

89

Evaluation of Capiox FX05 Oxygenator With an Integrated Arterial Filter on Trapping Gaseous Microemboli and Pressure Drop With Open and Closed Purge Line  

British Library Electronic Table of Contents (United Kingdom)

Abstract Gaseous microemboli (GME) remain a challenge for cardiopulmonary bypass (CPB) because there is a positive correlation between microemboli exposure during CPB and postoperative neurological injury. Thus, minimizing the number of GME delivered to pediatric patients undergoing CPB procedures would lead to better clinical outcomes. In this study, we used a simulated CPB model to evaluate the effectiveness of capturing GME and the degree of membrane pressure drop for a new membrane oxygenator, Capiox Baby FX05 (Terumo Corporation, Tokyo, Japan), which has an integrated arterial filter with open and closed purge line. We used identical components in this study as our clinical CPB circuit. Three emboli detection and classification quantifier transducers were placed at prepump, preoxygena...

2010-01-01

90

Coal technology programme meeting reports. coal winning: NCB mining research and development establishment, 8 november 1979. coal conversion: NCB coal research establishment, 16 april 1980  

Science.gov (United States)

During 1978 the Engineering Board of SRC granted Specially Promoted Program status to the Coal Technology program. This recognized that coal would increase in importance as the cost of liquid and gaseous hydrocarbons rises with the decreasing availability of petroleum related sources. It was, therefore, considered necessary to anticipate and improve, through SRC supported research, the technologies required to win, transport, convert to liquid and gaseous fuels and utilize coal and coal based substances. In view of the interest in the program, and also in the hope of reaching a still wider audience the reports of the two meetings have been combined in this single booklet. The reports indicate specific problems of importance in coal winning and coal conversion but, naturally, do not cover all of the program priorities.

1980-10-01

91

Chemical aspects of the trapping and recovery of uranium hexafluoride and fluorine during remediation activities  

Energy Technology Data Exchange (ETDEWEB)

Decontamination and decommission activities related to the Molten Salt Reactor Experiment (MSRE) involve the trapping and recovery of radiolitically generated uranium hexafluoride and fluorine. Although fission product radiolysis was known to generate F{sub 2}, the formation of UF{sub 6} and its transport from the fuel salt was unexpected. Some of these gaseous radiolysis products have been moving through the gas piping to a charcoal bed since the reactor was shut down in 1969. Current and planned remediation and clean-up activities involve the trapping of the gaseous products, deactivation and treatment of the activated charcoal bed, stabilization and reconditioning of the fuel salt, and recovery of the uranium. The chemical aspects of these processes, including radiolytic generation mechanisms, reactions between uranium hexafluoride and fluorine and trapping materials such as activated charcoal, activated alumina, and sodium fluoride, along ...

1996-10-01

92

An examination of the flame spread limits in a dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

The performance of a gas-fuelled diesel engine (dual fuel) is examined at light load and an effective threshold limit to the combustion of the gaseous fuel through bulk flame spread is identified. The relationship of such a limit to some of the key operating parameters is then discussed. A comparison between the measured values of the limit with those corresponding to the lower flammability limits of the gaseous fuel when evaluated under the prevailing cylinder conditions during pilot diesel fuel ignition showed similar trends. It is suggested that such a similarity may form a basis for estimating the lean operation limits for duel a fuel combustion in engines. A simple approach for estimating the limiting equivalence ratio for the apparent bulk flame spread limit is described for a methane-fuelled dual fuel engine. (Author)

1999-10-01

93

An examination of the exhaust emissions of gas fueled diesel engines  

Energy Technology Data Exchange (ETDEWEB)

A multi-zone computational model in conjunction with some engine tests are used to examine the combustion process of gas fueled diesel engines common known as dual fuel engine to provide information about details of the production of exhaust emissions, especially at light load when very lean mixtures are employed. Detailed chemical reaction kinetic simulation is employed for each of these individual combustion zones so as to establish the associated temporal variations in the concentrations of reacting species right to the exhaust stage. The influence of changes in major operating and design parameters such as the concentration of the gaseous fuel in the cylinder charge, intake temperature and the size of the diesel pilot fuel employed on the production of the exhaust emissions are examined. It is demonstrated in general that any measure that tends to increase the size of the combustion regions within the overly lean cylinder charge will reduce markedly the ...

1996-12-31

94

An examination of the exhaust emissions of gas fueled diesel engines  

Energy Technology Data Exchange (ETDEWEB)

A multi-zone computational model in conjunction with some engine tests are used to examine the combustion process of gas fueled diesel engines commonly known as dual fuel engine to provide information about details of the production of exhaust emissions, especially at light load when very lean mixtures are employed. Detailed chemical reaction kinetic simulation is employed for each of these individual combustion zones so as to establish the associated temporal variations in the concentrations of reacting species right to the exhaust stage. The influence of changes in major operating and design parameters such as the concentration of the gaseous fuel in the cylinder charge, intake temperature and the size of the diesel pilot fuel employed on the production of the exhaust emissions are examined. It is demonstrated in general that any measure that tends to increase the size of the combustion regions within the overly lean cylinder charge will reduce markedly the ...

1997-07-01

95

2D SPH simulations of planet-disc interactions.  

Science.gov (United States)

Current theories on planetary formation establish that massive objects accrete gaseous envelopes, becoming gaseous planets if the accretion process proceeds before the accretion disc dissolution. One of the unsolved problems is that the planet formation is contextual to their quick migration towards the central star, due to the protoplanets-disc interaction, on a timescale lower by an order of magnitude than that of gas accretion onto the protoplanet. These arguments have been recently broached using N-body and/or Eulerian fluid-dynamics codes, mainly in 2D, or a mixing of them. In this work, 2D simulations with a SPH code are performed, to study the migration of one protoplanet. The goal is to scrutinise the protoplanet dragging as a function of planet's mass.

2009-01-01

96

Diffusion modeling of ion implanted boron in Si during RTA: Correlation of extended defect formation and annealing with the enhanced diffusion of boron. [Rapid Thermal Annealing  

Energy Technology Data Exchange (ETDEWEB)

Accurate modeling of the enhanced diffusion of boron during rapid thermal annealing has been accomplished by incorporating the effects of extended defect formation and annealing on enhanced diffusion into a multizone, semiempirical model. The multizone model divides the implant profile into three zones defining regions of different defects and diffusion enhancements. The model also contains the initial enhanced diffusion and the transient diffusion effects associated with the dissolution of defect clusters and the annealing of extended defects, respectively. The saturation time for transient-enhanced diffusion contains an exponential function of implant dose in order to model the increase in point defect generated with higher implant dose. As a result, the model accurately simulates the boron diffusion profile over a wide range of implant ...

1993-01-01

97

Relationships of radon diffusion coefficient with saturated hydraulic conductivity, fines content and moisture saturation of radon/infiltration barriers for the UMTRA Project  

Energy Technology Data Exchange (ETDEWEB)

The release of {sup 222}Radon to the atmosphere is controlled by the rate of its gas transport through earthen materials. Of the many soil-related parameters, radon diffusion coefficient is the key parameter that characterizes this transport. We compared the radon diffusion coefficients measured at the laboratories for the UMTRA Project with simple empirical correlations developed by others. The empirical correlations predict the radon diffusion coefficient based on the fraction of moisture saturation and porosity. One of the more recent correlations agrees reasonably well with the measurements. In addition, by using a series of correlation curves, we studied the empirical relationships of the. radon diffusion coefficient with the saturated hydraulic conductivity, the fines content, and the moisture saturation in soil. The results reveal that a reliable determination of the long-term moisture and ...

1994-01-24

98

Modeling of phosphorus diffusion in Ge accounting for a cubic dependence of the diffusivity with the electron concentration  

International Nuclear Information System (INIS)

Up to now, P diffusion in Ge is modeled with an effective diffusivity involving at most a quadratic dependence with the free electron concentration (n). However, recent theoretical studies suggest the existence of a triply negatively charged state for the free vacancy in germanium and experimental data indicate that the E center (PV pair) in Ge has a double acceptor state. These two facts would be consistent with a diffusivity model involving a cubic dependence with n. In this paper the validity of this approach is checked for both pure thermal diffusion (intrinsic and extrinsic) and implanted phosphorus, using either our own experiments or other data available from the literature. Although some discrepancies still exist in some cases for the redistribution of implanted P, it is shown that the introduction of this cubic dependence significantly improves the overall agreement as compared with the usual ...

2010-02-26

99

Defects and diffusion in silicon processing. Materials Research Society symposium proceedings Volume 469  

Energy Technology Data Exchange (ETDEWEB)

A strong effort is currently being devoted to the investigation of defects and diffusion phenomena in silicon. This effort is not only driven by the stringent technological requirements for the processing of integrated circuits of increased complexity and miniaturization, but also by the lack of fundamental understanding of many of the critical parameters and mechanisms involved. Experimental and theoretical investigations are needed to identify the properties of the defects, the mechanisms of impurity diffusion and the strength of impurity-defect, defect-defect, and impurity-impurity interactions. This volume provides a unique and interdisciplinary forum for the discussion of experimental, theoretical and applied aspects of defects and diffusion phenomena in silicon. Topics include: defect properties and diffusion phenomena in silicon; experimental and theoretical assessments of defect properties; ...

1997-07-01

100

Boron enhanced diffusion due to high energy ion-implantation and its suppression by using RTA process  

Energy Technology Data Exchange (ETDEWEB)

SIMS measurements revealed that high energy boron-implantation causes transient enhanced diffusion (TED) of a shallow dopant profile due to Si interstitials even for a relatively low dose of {approximately}2E13cm{sup {minus}2}. By systematic analysis, it is found that this anomalous diffusion is most significant in 700--800 C annealing, and it takes place in the initial stage (less than 30 sec for 800 C) of annealing. Moreover, this anomalous diffusion is more considerable than the enhanced diffusion during oxidation (OED) in practical device fabrication processes. It is found that rapid thermal annealing (RTA) at 1,000--1,100 C is effective for suppressing the transient enhanced diffusion and realizing a shallow channel profile for deep sub-micron devices.

1995-12-31

101

Boron enhanced diffusion due to high energy ion-implantation and its suppression by using RTA process  

International Nuclear Information System (INIS)

SIMS measurements revealed that high energy boron-implantation causes transient enhanced diffusion (TED) of a shallow dopant profile due to Si interstitials even for a relatively low dose of #approx#2E13cm"-"2. By systematic analysis, it is found that this anomalous diffusion is most significant in 700--800 C annealing, and it takes place in the initial stage (less than 30 sec for 800 C) of annealing. Moreover, this anomalous diffusion is more considerable than the enhanced diffusion during oxidation (OED) in practical device fabrication processes. It is found that rapid thermal annealing (RTA) at 1,000--1,100 C is effective for suppressing the transient enhanced diffusion and realizing a shallow channel profile for deep sub-micron devices.

102

Boron diffusion in amorphous silicon  

Energy Technology Data Exchange (ETDEWEB)

We have investigated B diffusion in pre-amorphized silicon. In our experiments, the crystalline surface layer of silicon-on-insulator (SOI) substrates was completely amorphized by Ge ion implantation. Using SOI substrates in this fashion suppressed solid-phase-epitaxy regrowth, making it possible to investigate B diffusion in pre-amorphous silicon over a wider range of temperatures (500-650 deg. C) and times (5-1000 s) than has previously been reported. Diffusivities were determined with the aid of computational processes modeling. The results from this work demonstrate the B diffusion in a-Si is concentration dependent, exhibits a transient enhanced diffusion, and possesses an Arhennius behavior with activation energy of {approx}2.1 eV.

2005-12-05

103

Boron diffusion in amorphous silicon  

International Nuclear Information System (INIS)

We have investigated B diffusion in pre-amorphized silicon. In our experiments, the crystalline surface layer of silicon-on-insulator (SOI) substrates was completely amorphized by Ge ion implantation. Using SOI substrates in this fashion suppressed solid-phase-epitaxy regrowth, making it possible to investigate B diffusion in pre-amorphous silicon over a wider range of temperatures (500-650 deg. C) and times (5-1000 s) than has previously been reported. Diffusivities were determined with the aid of computational processes modeling. The results from this work demonstrate the B diffusion in a-Si is concentration dependent, exhibits a transient enhanced diffusion, and possesses an Arhennius behavior with activation energy of #approx#2.1 eV.

2005-12-05

104

Application of polycrystalline diffusion barriers  

International Nuclear Information System (INIS)

Degradation of contacts of the electronic equipment at the raised temperatures is connected with active diffusion redistribution of components contact - metalized systems (CMS) and phase production on interphase borders. One of systems diffusion barriers (DB) are polycrystalline silicide a film, in particular silicides of the titan. Reception disilicide the titan (TiSi_2) which on the parameters is demanded for conditions of microelectronics from known silicides of system Ti-Si, is possible as a result of direct reaction of a film of the titan and a substrate of silicon, and at sedimentation of layer Ti-Si demanded stoichiometric structure. Simultaneously there is specific problem polycrystalline diffusion a barrier (PDB): the polycrystalline provides structural balance and metastability film disilicide, but leaves in it borders of grains - easy local ways of diffusion. In clause the analysis ...

105

Wartsila 32DF, the dual-fuel engine  

Energy Technology Data Exchange (ETDEWEB)

This paper gives details of the development of the Wartsila 32DF duel-fuel lean-burn engine that can burn liquid or gaseous fuels, and reports on the installation of four of the engines in Turkey. The combustion process, and the design of the gas admission, pilot fuel, cylinder control, air-fuel control, and engine control and monitoring systems are described. The advantages of the engine are discussed.

1999-06-01

106

The physics of Electron Beam Ion Sources  

Energy Technology Data Exchange (ETDEWEB)

There are 13 Electron Beam Ion Sources in operation which produce highly charged ions, up to Th[sup 80+] and Xe[sup 53+]. Most of the sources are used to study these ions under electron impact or when recombining with gaseous or solid targets. That provides an insight into the atomic physics of these highly charged ions and into the physics of the plasma in which such ions can be found. This paper reviews the present knowledge of atomic processes, important in the production of such ions with an EBIS.

1990-01-01

107

The physics of Electron Beam Ion Sources  

Energy Technology Data Exchange (ETDEWEB)

There are 13 Electron Beam Ion Sources in operation which produce highly charged ions, up to Th{sup 80+} and Xe{sup 53+}. Most of the sources are used to study these ions under electron impact or when recombining with gaseous or solid targets. That provides an insight into the atomic physics of these highly charged ions and into the physics of the plasma in which such ions can be found. This paper reviews the present knowledge of atomic processes, important in the production of such ions with an EBIS.

1990-12-31

108

Simulations of dual morphology in spiral galaxies  

CERN Document Server

Gas and stars in spiral galaxies are modelled with the DUAL code, using hydrodynamic and N-body techniques. The simulations reveal morphological differences mirroring the dual morphologies seen in B and K' band observations of many spiral galaxies. In particular, the gaseous images are more flocculent with lower pitch angles than the stellar images, and the stellar arm-interarm contrast correlates with the degree of morphological decoupling.

2003-01-01

109

Pyrolysis of dichlorodithiourea cadmium(II)  

Energy Technology Data Exchange (ETDEWEB)

By means of infrared spectroscopy, x-ray diffraction, and differential thermal analysis, the authors investigate the pyrolysis of dichlorodithiourea cadmium, the vapor phase epitaxy of the cadmium sulfide film, and the composition of the solid and gaseous pyrolysis products. Those products are found to include the thiocyanates of guanidine, ammonium, and hydrogen along with cadmium oxides and sulfates and hydrochloric acid.

1987-02-20

110

Partially-carbonized polyacrylonitrile filter  

Energy Technology Data Exchange (ETDEWEB)

A filter for extracting solids and liquids from gaseous combustion exhausts comprises a textile filter element formed of polyacrylonitrile fibers oxidized by careful heat treatment and comprising approximately 61% carbon after treatment. The filter may be woven, knitted or formed as a batting of randomly-oriented fibers. Abrasion resistant coatings and lubricants for the fibers are disclosed. The filter material is especially useful as a filter bag.

1984-04-24

111

Nonisothermal Atmospheric Dispersion Model for a Gaseous Pollutant of Any Density in the Presence of Orographic Nonuniformities Modele de Dispersion Atmospherique Non-Isotherme d'UN Pollutant Gazeux de Densite Quelconque en Presence de Non-Uniformites Orographiques.  

Science.gov (United States)

A mathematical model describing the behavior of a gas of any density released into a turbulent atmosphere was developed. A numerical treatment was established for two dimensional flow. An understanding of the effects of accidental or continuous release wa...

1981-01-01

112

New technologies in fossil-fuel utilization  

Energy Technology Data Exchange (ETDEWEB)

This document contains the outline and viewgraphs used in the speech. Topics covered are: conventional oil and gas recovery; unconventional oil and gas sources; oil shale resources; conventional coal combustion; advanced fossil power systems; fluidized bed combustion; coal/oil or coal/water mixtures; and gaseous and liquid fuels from coal. (DMC)

1982-01-01

113

Microturbine applications for the oil and gas industries of South America  

Energy Technology Data Exchange (ETDEWEB)

This paper will describe the application of power generation by the use of microturbine technology by Capstone Turbine Corporation throughout South America. The purpose of this paper is to describe the technology and the experience gained over the last six years. The microturbines are power generation systems that produce energy from a diverse range of liquid or gaseous fuels. The generator is driven by a small gas turbine with a common shaft for the rotors of the generator and the engine. (author)

2008-07-01

114

High-resolution primary ion beam probe for SIMS  

Energy Technology Data Exchange (ETDEWEB)

High-brightness negative ion beams, especially O{sup -} beams, from a compact gaseous plasma source are studied to evaluate the suitability for high-resolution SIMS. Ion-optical calculations are made using the beam parameters from the new source. Results suggest that sub-100 nm spot with O{sup -} beam current of 10 pA is achievable. Beam focusing, the resulting beam current distributions at the target and the expected instrumental performance are discussed.

2004-06-15

115

Explosives for mining  

Energy Technology Data Exchange (ETDEWEB)

The explosive known under the name Saletrol (mixture of ammonium nitrate and hydrocarbon fuel or a mixture of ammonium nitrate, hydrocarbon fuel and aluminum powder) is characterized by the absence of physical stability during storage (the oily fluid flows from the upper layers of the explosive downward) and as a consequence of this, decrease in the required effectiveness of blasting and increased release of toxic gaseous blasting products. In order to eliminate this shortcoming, lightening clay is added to Saletrol in a quantity of 3-12% by weight of the total explosive mass.

1982-07-31

116

Dual fuel combustion in a turbocharged diesel engine  

Energy Technology Data Exchange (ETDEWEB)

The modification of a turbocharged diesel engine to a dual-fuel engine using methane as the supplementary fuel has been carried out. The effect of the gaseous fuel in a turbo-charged diesel engine has been investigated by means of a heat release study and a computer program already developed at Leicester Polytechnic. It is used in order to examine the rate of heat released under any operational condition.

1987-01-01

117

Development of Hyundai Motor Company hydrogen-fueled vehicle  

Energy Technology Data Exchange (ETDEWEB)

At HMC, fundamental research on the hydrogen fueled engine and vehicle has been carried out. For this engine, solenoid driven injector is used to supply gaseous hydrogen into the cylinder and various operating parameters have been changed to study the combustion characteristics of hydrogen. After these experiments on the engine, a hydrogen fueled vehicle has been constructed and it is controlled by an ECU. The amount of emission from the hydrogen vehicle with stoichiometric operation is less than 1/3 of the ULEV legislation.

1995-12-31

118

Desulphurization of hot reducing gases in the entrained bed reactor  

Energy Technology Data Exchange (ETDEWEB)

Using an experimental pilot plant, designed and built for the tests, the influence of the following parameters was determined: desulphurization of the test gas, temperature, residence time in the reactor tube, concentration of the hydrogen sulphide and desulphurization agent, size of the particles which comprise the agent and composition of the gas. Allowance was made for the effect of calcination and carbonisation. Desulphurization was carried out with limestone on a gaseous mixture of CO and H/sub 2/. A mathematical description of the test findings and yield is presented. 8 refs.

1986-08-01

119

Cyclization of N-(2-cyclopent-1-en-1-ylphenyl)benzamides in solution and under mass-spectrometric conditions  

British Library Electronic Table of Contents (United Kingdom)

The cyclization has been studied of N-(2-cyclopent-1-en-1-ylphenyl)benzamides into the corresponding 3,1-benzoxazines by the action of gaseous hydrogen chloride, trifluoroacetic acid, or bromine, and also under conditions of electron impact in the gas phase. A scheme is proposed for the fragmentation of the molecular ions of the products obtained.

2011-01-01

120

Bragg curve spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

A new method named 'Bragg curve spectroscopy', based on the Bragg curve of the heavy ion being stopped in a gaseous ionization chamber, has been developed for identifying the particle and measuring its energy. The design of such a chamber and the experience obtained with chamber using various kinds of fast heavy ions are described. In conclusion, several problems to be solved in this method are pointed out.

1982-05-01

121

Bragg curve spectroscopy  

International Nuclear Information System (INIS)

A new method named 'Bragg curve spectroscopy', based on the Bragg curve of the heavy ion being stopped in a gaseous ionization chamber, has been developed for identifying the particle and measuring its energy. The design of such a chamber and the experience obtained with chamber using various kinds of fast heavy ions are described. In conclusion, several problems to be solved in this method are pointed out. (orig.).

122

A simple, high efficiency, negative surface ionization source  

Energy Technology Data Exchange (ETDEWEB)

A spherical-geometry, self-extraction negative ion source has been designed and fabricated. The source utilizes direct surface ionization to form negative ion beams resulting from interactions between high electron affinity gaseous elemental or molecular materials and a negatively biased, spherical-sector LaB{sub 6} surface ionizer maintained at {similar to}1300 K. The design features of this source and principles upon which the source is based are discussed in this report.

1992-04-01

123

Xylem Embolism in Response to Freeze-Thaw Cycles and Water Stress in Ring-Porous, Diffuse-Porous, and Conifer Species 1  

UK PubMed Central (United Kingdom)

Vulnerability to xylem embolism by freeze-thaw cycles and water stress was quantified in ring-porous (Quercus gambelii Nutt.), diffuse-porous (Populus tremuloides Michx.,...Full Text Available

1992-10-01

124

Transient-diffusion measurements of radon. Practical interpretation of measured data  

International Nuclear Information System (INIS)

The mathematical calculation to obtain a radon diffusion coefficient from measured radon transient-diffusion data is usually done by fitting a difference equation to the data. The difference equation is obtained through transformation of the time-dependent diffusion equation based on Fick's law. But, actual measured transient-diffusion data often have much scatter. Therefore just fitting over the whole range of the measured data through the method of least squares may not always be valid, because the method offers mathematical interpretation rather than a physical one. Instead, the actual radon diffusion coefficients must be otherwise obtainable from measured radon transient data. Taking this viewpoint, the present paper claims that about a 90% leveling-off time is often easily discernible regardless of the shape of the radon transient curve obtained from the measured data and it ...

2007-07-01

125

Transient radon diffusion through radon-proof membranes: A new technique for more precise determination of the radon diffusion coefficient  

Energy Technology Data Exchange (ETDEWEB)

The following paper is focused on the numerical modelling of the transient radon diffusion through radon-proof membranes during the measurement of their radon diffusion coefficient. The major aim of such numerical modelling is to increase the accuracy of radon diffusion coefficients derived from the measured data sets. The developed complex ''transient'' numerical model is able to calculate the radon diffusion coefficient with sufficient accuracy from almost any data set - even from a short-time measurement with a non-linear course of results. This numerical model can also be used for various analyses of transient radon transfer processes (e.g. for the calculation of radon distribution curves within the membrane). The following paper presents governing equations for the simulation model, together with a brief description of algorithms incorporated in the newly ...

2009-06-15

126

Set of equations for stress-mediated evolution of the nonequilibrium dopant-defect system in semiconductor crystals  

Energy Technology Data Exchange (ETDEWEB)

A set of equations describing a stress-mediated evolution of the nonequilibrium dopant-defect system has been derived and analyzed. Together with coupled diffusion of dopant atoms and point defects, we consider the drift of all mobile species in different charge states, namely vacancies, self-interstitials, and pairs 'dopant atom-point defect', in the field of stress. It has been shown that stresses may affect the diffusion of dopant atoms mainly in two ways: (1) directly, due to the drift of the pairs in the field of stress; (2) indirectly, by the formation of nonuniform defect distribution due to the drift of point defects. On this basis, various features of doping processes, such as phenomena of 'uphill' impurity diffusion near the surface (within the framework of the first or second mechanisms) and the peculiarities of high concentration phosphorus diffusion (due ...

2004-11-17

127

Set of equations for stress-mediated evolution of the nonequilibrium dopant-defect system in semiconductor crystals  

International Nuclear Information System (INIS)

A set of equations describing a stress-mediated evolution of the nonequilibrium dopant-defect system has been derived and analyzed. Together with coupled diffusion of dopant atoms and point defects, we consider the drift of all mobile species in different charge states, namely vacancies, self-interstitials, and pairs 'dopant atom-point defect', in the field of stress. It has been shown that stresses may affect the diffusion of dopant atoms mainly in two ways: (1) directly, due to the drift of the pairs in the field of stress; (2) indirectly, by the formation of nonuniform defect distribution due to the drift of point defects. On this basis, various features of doping processes, such as phenomena of 'uphill' impurity diffusion near the surface (within the framework of the first or second mechanisms) and the peculiarities of high concentration phosphorus diffusion (due to the second mechanism), can be ...

2004-11-17

128

Properties of rare-gas solids. [Diffusion rate of xenon through epithelial tissue  

Science.gov (United States)

Results are reported from studies of the diffusion rate of xenon through frog abdominal skin and toad urinary bladders, typical epithelial membranes. It was concluded that intracellular water serves as the principal barrier for xenon passage through epithelial tissue.

1977-01-01

129

NASA/DOD Aerospace Knowledge Diffusion Research Project: A Research Agenda.  

Science.gov (United States)

The NASA/DoD Aerospace Knowledge Diffusion Research Project is a cooperative effort sponsored by NASA, Office of Aeronautics, Exploration and Technology (OAET), and DoD, SAF/AQT Deputy for Scientific and Technical Information. The research project is a jo...

1990-01-01

130

NASA/DOD Aerospace Knowledge Diffusion Research Project. Phase 2: Respondents Including Frequency Distributions.  

Science.gov (United States)

Phase 2 of the four phase NASA/DoD Aerospace Knowledge Diffusion Research Project was undertaken to study the transfer of scientific and technical information (STI) from government to the aerospace industry and the role of librarians and technical informa...

1991-01-01

132

Lung diffusing capacity in a hyperbaric environment: assessment by a rebreathing technique.  

UK PubMed Central (United Kingdom)

A rebreathing method was developed for measuring diffusing lung capacity for carbon monoxide (DLCO) in a hyperbaric environment. Twenty two professional naval divers with normal lung function were included...Full Text Available

1992-04-01

133

Effects of interstitial clustering on transient enhanced diffusion of boron in silicon  

Energy Technology Data Exchange (ETDEWEB)

A simulation model for boron diffusion which takes into account the aggregation of the excess interstitials in clusters, and subsequently, the dissolution of these defects, is proposed. The interstitial supersaturation and generation rate are determined according to the classical theory of nucleation and growth of particles, in analogy with the precipitation of a new phase in heavily doped silicon. The clusters are considered as precipitates formed by interstitial Si atoms. The B diffusion is modelled on the basis of the dopant-interstitial pair diffusion mechanism. The clusters dissolution during annealing maintains nearly constant, for a long period, the interstitial supersaturation and the related enhancement of the boron diffusion. This gives a good account of the diffusion results over a large range of experimental conditions. Furthermore, this approach describes most of the ...

1997-11-01

134

Effective Reduced Diffusion-Models: A Data Driven Approach to the Analysis of Neuronal Dynamics  

UK PubMed Central (United Kingdom)

We introduce in this paper a new method for reducing neurodynamical data to an effective diffusion equation, either experimentally or using simulations of biophysically detailed models. The dimensionality...Full Text Available

2009-12-01

135

EXPONENTIAL TENSORS: A FRAMEWORK FOR EFFICIENT HIGHER-ORDER DT-MRI COMPUTATIONS  

UK PubMed Central (United Kingdom)

In Diffusion Tensor Magnetic Resonance Image (DT-MRI) processing a 2nd order tensor has been commonly used to approximate the diffusivity function at each lattice...Full Text Available

2007-05-15

136

Design Calibration and Field Use of a Stomatal Diffusion Porometer  

UK PubMed Central (United Kingdom)

Modifications of the design and calibration procedure of a diffusion porometer permit determinations of stomatal resistance which agree well with results obtained by leaf energy balance. The energy...Full Text Available

1969-06-01

137

Dependence of anomalous phosphorus diffusion in silicon on depth position of defects created by ion implantation  

Energy Technology Data Exchange (ETDEWEB)

Transient enhanced diffusion of phosphorus in silicon has been investigated for implants below and above the threshold for a complete amorphization. Rapid thermal processes (electron beam) and conventional furnaces have been used for the annealing. In the case of implants below amorphization, a strong enhanced diffusion, proportional to the amount of damage produced, has been observed. The extent of the phenomenon is practically independent of the damage depth position. In contrast to this, the formation of extended defects at the original amorphous-crystalline interface makes the diffusivity strongly dependent on depth in the case of post-amorphized samples. No enhanced diffusion effect is observed if the dopant is confined in the amorphous layer, while a remarkable increase in the diffusivity is detected for the dopant located in the crystalline region beyond the ...

1989-03-01

138

Absorption and diffusion of hydrogen in palladium-silver alloys by density functional theory  

Science.gov (United States)

The vibrational states, absorption energies, and diffusions of H in Pd and Pd1-xAgx(0Pd-Ag alloys should avoid the Ag-rich areas.

2002-11-01

139

A Multi-Method Process Evaluation for a Skin Cancer Prevention Diffusion Trial  

UK PubMed Central (United Kingdom)

This article describes process evaluation methods for the Pool Cool Diffusion Trial across four years. Pool Cool is a skin cancer prevention program that was...Full Text Available

2009-06-01

140

Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results ...

2010-05-15

142

Solution of vector Stefan problems with cross-diffusion  

Science.gov (United States)

A general model for the dissolution of particles in multi-component alloys is proposed and analyzed. The model is based on diffusion equations with cross-terms for the several species, combined with a Stefan condition as the equation of motion of the interface between the particle and diffusive phase. Several numerical schemes for the solution of the Stefan problem are proposed and compared. It turns out that diagonalization is useful for numerical purposes. However, for the case of position-dependent diffusion coefficients one has to use a different scheme. Here, we analyze stability and workload of several time integration methods.

2005-04-01

143

Relaxation oscillations and diffusion chaos in the Belousov reaction  

British Library Electronic Table of Contents (United Kingdom)

Asymptotic and numerical analysis of relaxation self-oscillations in a three-dimensional system of Volterra ordinary differential equations that models the well-known Belousov reaction is carried out. A numerical study of the corresponding distributed model-the parabolic system obtained from the original system of ordinary differential equations with the diffusive terms taken into account subject to the zero Neumann boundary conditions at the endpoints of a finite interval is attempted. It is shown that, when the diffusion coefficients are proportionally decreased while the other parameters remain intact, the distributed model exhibits the diffusion chaos phenomenon; that is, chaotic attractors of arbitrarily high dimension emerge.

2011-01-01

144

Principles of air pollution meteorology  

Energy Technology Data Exchange (ETDEWEB)

This book is divided into the following chapters: the atmospheric boundary layer; atmospheric diffusion; pollutants and their properties; and environmental monitoring and impact.

1990-01-01

145

Practical measurement of diffusion constants in sintered zirconias by using a light-scattering method  

Energy Technology Data Exchange (ETDEWEB)

A practical method to determine the ionic diffusion coefficient and activation energy by using quasielastic light scattering (QELS) is presented. It is shown that a temperature dependence curve of the QELS intensity at a fixed frequency can be well fitted by Jonscher's formula and that the diffusion parameters can be obtained from this curve fitting. This method is successfully applied not only to crystals with high optical quality, as reported earlier, but also to opaque ceramics, which are more important than the crystals from a practical point of view. The composition dependence of the ionic diffusion coefficient is studied in sintered YbSZ to show the usefulness of this method.

1991-03-01

146

Point defect supersaturation and enhanced diffusion in SPE regrown silicon  

Energy Technology Data Exchange (ETDEWEB)

Transient, greatly enhanced diffusion has been observed on annealing solid-phase-epitaxial (SPE) grown Si-Sb alloys. This is shown to be due to a high concentration of interstitials being trapped during SPE regrowth. The migration enthalpy, for diffusion of Sb by an interstitialcy mechanism was measured as 1.8 +/- 0.2 eV. The interstitials eventually condensed into loops, marking the end of the transient. In a SPE grown Si-Bi alloy a similar transient enhanced diffusion was observed, with an activation energy of 2.0 +/- 0.2 eV, but no loops formed. 8 figures, 7 references.

1984-01-01

147

Point defect supersaturation and enhanced diffusion in SPE regrown silicon  

International Nuclear Information System (INIS)

Transient, greatly enhanced diffusion has been observed on annealing solid-phase-epitaxial (SPE) grown Si-Sb alloys. This is shown to be due to a high concentration of interstitials being trapped during SPE regrowth. The migration enthalpy, for diffusion of Sb by an interstitialcy mechanism was measured as 1.8 +/- 0.2 eV. The interstitials eventually condensed into loops, marking the end of the transient. In a SPE grown Si-Bi alloy a similar transient enhanced diffusion was observed, with an activation energy of 2.0 +/- 0.2 eV, but no loops formed. 8 figures, 7 references.

148

Horizontal liquid film-mist two-phase flow. I - Concentration distribution and diffusivity of entrained liquid droplets  

Science.gov (United States)

The entrainment flow rate distribution, the gas velocity profile, and the concentration profile of droplets across the channel cross section in fully developed region of a horizontal rectangular channel of 150mm width and 50mm height were measured. The concentration profile of droplets was expressed by a simple equation based on a constant diffusion coefficient model. From this equation the effects of gravity and turbulent diffusion of droplets on the concentration profile were evaluated. The characteristic mean settling velocity of a group of droplets with various diameters was derived, and using this value the mean diffusion coefficient of the group of droplets was obtained

1980-06-01

149

Feynman-Wiener path integral representation for scalar advected diffusion  

Energy Technology Data Exchange (ETDEWEB)

We write a path-integral expression for the Green function of a advected scalar on a fluid flux. (author)

2000-07-01

150

Diffusion-weighted MRI suggests the coexistence of cytotoxic and vasogenic oedema in a case of deep cerebral venous thrombosis  

Energy Technology Data Exchange (ETDEWEB)

We report a 20-year-old woman who suffered headaches before presenting with a state of fluctuating vigilance. MRI showed diffuse high signal in the basal ganglia bilaterally on diffusion- and T2-weighted images, which had areas of both low and high apparent diffusion coefficient, presumed to correspond to cytotoxic and vasogenic oedema. MR venography showed no flow in the deep cerebral veins or straight sinus. Heparin was given, with clinical recovery. On follow-up MRI, the appearances became normal. (orig.)

2000-10-01

152

A Comparison of the Technical Communications Practices of ...  

Science.gov (United States)

... Scientists. NASA/DoD Aerospace Knowledge Diffusion Research Project. Descriptive Note : Technical memo. rept. no. 29,. ...

1994-12-01

153

Transient enhanced diffusion and deactivation of ion-implanted As in strained Si  

International Nuclear Information System (INIS)

First results on the effects of strain on transient enhanced diffusion and deactivation of As-implanted ultrashallow junctions are presented. A significant effect of strain on the magnitude and timescale of transient enhanced diffusion is observed, which is consistent with the stabilization of interstitial-type defects by tensile strain. Our results show no significant impact of strain on As electrical activity during the deactivation timescale accessed in this study.

2005-08-01

154

Study of transient enhanced dopant diffusion in silicon and proposed limiting methods  

International Nuclear Information System (INIS)

The transient enhanced diffusion in crystalline silicon implanted with dopants ad followed by high temperature annealing to activate the dopants is introduced. The physical mechanisms of transient enhanced dopant diffusion are then reviewed together with a short introduction to the proposed suppressing methods. Finally, the perspectives with using high energy heavy ions in this field are briefly discussed

2001-09-01

155

Simulation of arsenic diffusion during rapid thermal annealing of silicon layers doped with low-energy high-dose ion implantation  

International Nuclear Information System (INIS)

The model of transient enhanced diffusion of ion-implanted As is formulated and the finite-difference method for numerical solution of the system of equations obtained is developed. The nonuniform distribution of point defects near the interface and more accurate description of arsenic clustering are simultaneously taken into account. Simulation of As diffusion during rapid annealing gives a reasonable agreement with the experimental data. (authors)

2005-09-01

156

NASA/DOD Aerospace Knowledge Diffusion Research Project, Paper Six: Aerospace Knowledge Diffusion in the Academic Community: A Report of Phase 3 Activities of the NASA/DoD Aerospace Knowledge Diffusion Research Project.  

Science.gov (United States)

Although the U.S. aerospace industry continues to be the leading positive contributor to the balance of trade among all merchandise industries, it is experiencing significant changes whose implications may not be well understood. Increasing U.S. collabora...

1990-01-01

157

Diffusion absorption heat pump. Diffusion-Absorptions-Waermepumpe  

Energy Technology Data Exchange (ETDEWEB)

The development of a gas-operated diffusion absorption heat pump for the heating of living spaces is described. By various improvement an energy efficiency of the prototypes of 1.5 was achieved. Structural alterations led to a lower overall height and lower production costs. The CFCs used in electric heat pumps were replaced by environmentally neutral ammonia. Compared with conventional gas heating systems, the CO2 output could be reduced by more than 30%. figs., tabs.

1992-02-01

158

Analysis of current diffusive ballooning mode in tokamaks  

Energy Technology Data Exchange (ETDEWEB)

The effect of finite gyroradius on the current diffusive ballooning mode is examined. Starting from the reduced MHD equations including turbulent transports, coupling with drift motion and finite gyroradius effect of ions, we derive a ballooning mode equation with complex transport coefficients. The eigenfrequency, saturation level and thermal diffusivity are evaluated numerically from the marginal stability condition. Preliminary results of their parameter dependence is presented. (author)

1999-12-01

159

An interface - marker technique applied to the study of metal silicide growth  

International Nuclear Information System (INIS)

An interface-marker technique has been used to investigate the relative rates of diffusion of Si and of metal atoms during the growth of metal silicide films. The technique enables recognition of a reference plane in thin film diffusion using Rutherford backscattering, while minimizing any perturbation of the diffusion process. Examples are drawn from studies of the growth of silicides of W, Mo, Ta, Nb, Pd and Pt. (orig.).

160

The diffusion bonding and theoretical model including void growth mechanism in magnesium alloys  

Energy Technology Data Exchange (ETDEWEB)

There are many factors affecting diffusion bonding in order to obtain high quality joining. Therefore, in the beginning, we constructed diffusion bonding model based on void growth mechanism to predict bonding pressures and times. In addition, in order to compare theoretical values with experimental values, diffusion bonding tests were carried out by using commercial AZ31 magnesium alloy sheets with different grain sizes, 16 and 130 {mu}m. The present AZ31 alloys were successfully diffusion bonded at several conditions, and the bonding strength was more than 0.8 of each parent materials. The experimental bonding conditions in high quality joining, times and pressures, were good agreed with prediction analysis. (orig.)

2003-07-01

161

A method for measuring effective radon diffusion coefficients in radon barriers by using modified Lucas cells  

Energy Technology Data Exchange (ETDEWEB)

Radon proof barriers are used for lowering of radon transport from the soil into the house and the determination of the radon diffusion coefficient is an important parameter to be determined in order to design the minimal thickness of the radon proof insulation. A method has been developed in our laboratory by using modified Lucas cells connected to a radon source and tightly closed onto the top by the tested membranes whose radon diffusion coefficients are being measured. Solving the time-dependent differential equation for radon diffusion in the membrane for well-defined experimental conditions the effective radon diffusion coefficient of the insulating material can be evaluated by comparing the radon concentration decrease in the cell for the first hours with the well-known radioactive decay. First results obtained in several preliminary tests carried out with a parafilm M barrier and two ...

2005-01-01

162

Method for predicting diffusion of discharged warm water in the regions of coastal sea  

International Nuclear Information System (INIS)

The present situation of the researches that have been made for predicting the process and range of diffusion of warm drain is reviewed. This review is divided into eight sections. The first section deals with the present situation of warm drain from power plants. For the establishment of drainage standard, there are many difficult problems to be solved because water temperature differs in its nature from other regulation items. In the second section, the process of diffusion and cooling of warm drain is explained. The third section deals with the diffusion characteristics of warm drain in Japanese coastal sea due to water temperature. Two types of diffusion are known. One is dominant irregular current, and the other is periodical reciprocating stream. The fourth section deals with the methods of prediction of diffusion. Research methods and simulation models are described. The ...

1975-01-01

163

Simulation of p-type diffusion in compound semiconductor: the case of beryllium implanted in InGaAs  

Energy Technology Data Exchange (ETDEWEB)

A system of equations describing transient enhanced diffusion of beryllium in InGaAs due to kick-out mechanism or due to formation, migration, and dissociation of the pairs ''beryllium atom-group III self-interstitial'' is proposed and analyzed. Simulation of coupled diffusion of beryllium atoms and self-interstitials in InGaAs during rapid thermal annealing was done for the case of dual implantation. For the experiment under consideration the first ion implantation of phosphorus atoms produced the region of extended defects that led to ''uphill'' diffusion of implanted Be in the defect region and in the vicinity of the surface. The suggested reason of ''uphill'' diffusion could be related to the nonuniform distribution of group III self-interstitials that was formed due to the absorption of point ...

2006-10-15

164

Radiation-enhanced diffusion in amorphous Pd-Cu-Si  

Energy Technology Data Exchange (ETDEWEB)

Diffusion during He/sup +/, Ne/sup +/, and Xe/sup +/ irradiations of trace amounts of Au in melt-spun amorphous Pd/sub 78/Cu/sub 6/Si/sub 16/ has been experimentally investigated. Diffusion constants were measured by following the changes in ion-implanted Au profiles with Rutherford-backscattering spectrometry. Heat treatments and simultaneous irradiations were performed as a function of temperature (533--588 K), ion flux, and ion mass. Total integrated fluences being very small, ion-beam-mixing effects are negligible. More than an order of magnitude enhancement in the diffusion was observed because of irradiations. This enhancement saturates at higher fluxes, the level being independent of ion mass, i.e., independent of collision-cascade parameters. Except at higher temperatures, where the enhancement decreases, the temperature dependence of the diffusion-saturation level is similar to that of the ...

1988-11-01

165

Radiation-enhanced diffusion in amorphous Pd-Cu-Si  

International Nuclear Information System (INIS)

Diffusion during He"+, Ne"+, and Xe"+ irradiations of trace amounts of Au in melt-spun amorphous Pd/sub 78/Cu_6Si/sub 16/ has been experimentally investigated. Diffusion constants were measured by following the changes in ion-implanted Au profiles with Rutherford-backscattering spectrometry. Heat treatments and simultaneous irradiations were performed as a function of temperature (533--588 K), ion flux, and ion mass. Total integrated fluences being very small, ion-beam-mixing effects are negligible. More than an order of magnitude enhancement in the diffusion was observed because of irradiations. This enhancement saturates at higher fluxes, the level being independent of ion mass, i.e., independent of collision-cascade parameters. Except at higher temperatures, where the enhancement decreases, the temperature dependence of the diffusion-saturation level is similar to that of the ...

166

Normal and abnormal water diffusion in the brain  

International Nuclear Information System (INIS)

Diffusion magnetic resonance imaging (MRI) has become an important tool in the radiologic diagnosis of diseases of the brain as it measures molecular motion of water that characterizes the microstructure of tissues. Its most important clinical use to date is the early detection of cerebral ischemia by revealing the ischemic injury shortly after vessel occlusion and simultaneously providing therapy-relevant information on the tissue at risk. Furthermore, diffusion MRI is diagnostically promising in other diseases of the brain and is thus increasingly becoming part of routine clinical protocols in the diagnosis of tumors, inflammation, trauma, demyelination, dysmyelination and neurodegeneration. Although abnormalities of diffusion are generally not pathognomonic, diffusion MRI affords information about tissue changes for specific disorders that complements information obtained with standard MR techniques ...

2003-10-01

167

Implantation damage and anomalous diffusion of implanted boron in silicon through SiO_2 films  

International Nuclear Information System (INIS)

Boron is implanted in crystalline silicon through oxide layers with different thicknesses. The implantation is carried out at various doses and energies of interest in ultra large scale integration (ULSI) application. Rapid thermal annealings (RTA) are used to obtain shallow junctions and electrical activation of the B atoms. However, transient enhanced diffusion induced by implantation damage can be observed. The boron concentration profiles before and after annealing are obtained with secondary ion mass spectrometry (SIMS). It is found that the diffusion transient in the tail region of the boron profile increases with decreasing oxide thickness. Even more, if the implantation damage concerns mostly the oxide, i.e. when the concentration peak is located in this oxide, the oxygen knocked into the silicon substrate could play this way an important role in restricting the boron diffusion, which is good to obtain very shallow ...

168

Implantation damage and anomalous diffusion of implanted boron in silicon through SiO[sub 2] films  

Energy Technology Data Exchange (ETDEWEB)

Boron is implanted in crystalline silicon through oxide layers with different thicknesses. The implantation is carried out at various doses and energies of interest in ultra large scale integration (ULSI) application. Rapid thermal annealings (RTA) are used to obtain shallow junctions and electrical activation of the B atoms. However, transient enhanced diffusion induced by implantation damage can be observed. The boron concentration profiles before and after annealing are obtained with secondary ion mass spectrometry (SIMS). It is found that the diffusion transient in the tail region of the boron profile increases with decreasing oxide thickness. Even more, if the implantation damage concerns mostly the oxide, i.e. when the concentration peak is located in this oxide, the oxygen knocked into the silicon substrate could play this way an important role in restricting the boron diffusion, which is good to obtain very shallow ...

1993-07-16

169

Brain development during the first year of life. Quantitative assessment with ADC imaging  

International Nuclear Information System (INIS)

Brain development during the first year of life was assessed quantitatively using apparent diffusion coefficient (ADC) images constructed from diffusion-weighted MR image data. The imaging plane was coronal at the section of the pons. The cerebral peduncle, internal capsule, corona radiata, superior longitudinal fasciculus and thalamus were selected for evaluation of their ADC values. A diffusion sensitive gradient was added in the anteroposterior direction. Thus the orientation of nerve fibers in the cerebral peduncle, internal capsule and corona radiata was perpendicular to it, and that in the superior longitudinal fasciculus was parallel to it. In neonates, the cerebral peduncle and internal capsule, having been moderately myelinated at birth, showed the slowest diffusion. The corona radiata and superior longitudinal fasciculus, having been unmyelinated at birth, showed the fastest ...

170

Annealing and diffusion characteristics of boron-through-oxide implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

The author investigates the diffusion and damage-annealing characteristics as a result of boron implantation through a surface oxide into the silicon, a process that is commonly realized in the fabrication of p-n junctions. Defect structures were examined using plan-view and cross-section transmission-electron microscopies. It is shown that recoil-implanted oxygen plays a critical role in determining the above annealing characteristics. For instance, transient-enhanced diffusion of boron, as is widely observed for boron-implanted silicon, does not occur in the case of through-oxide implantation. The initial suppression of the defect-enhanced diffusion lasts for a limited period of time after which enhanced diffusion occurs again. The so-called incubated enhanced diffusion' is characterized as due to recoiled-oxygen precipitation-emitting point defect that enhances boron ...

1991-01-01

171

Annealing and diffusion characteristics of boron-through-oxide implanted silicon  

International Nuclear Information System (INIS)

The author investigates the diffusion and damage-annealing characteristics as a result of boron implantation through a surface oxide into the silicon, a process that is commonly realized in the fabrication of p-n junctions. Defect structures were examined using plan-view and cross-section transmission-electron microscopies. It is shown that recoil-implanted oxygen plays a critical role in determining the above annealing characteristics. For instance, transient-enhanced diffusion of boron, as is widely observed for boron-implanted silicon, does not occur in the case of through-oxide implantation. The initial suppression of the defect-enhanced diffusion lasts for a limited period of time after which enhanced diffusion occurs again. The so-called incubated enhanced diffusion' is characterized as due to recoiled-oxygen precipitation-emitting point defect that enhances boron motion. The ...

172

Anaerobic degradation of DCM diffusing through clay  

Energy Technology Data Exchange (ETDEWEB)

Two series of diffusion tests were performed to examine the degradation of dichloromethane (DCM) as it diffuses through clay. The first series showed the use of a synthetic leachate with no significant initial bacterial population diffusing through a plug of intact clay; there was an induction period of 95--135 d, during which diffusion was as expected in the absence of degradation, followed by a second stage, where degradation occurred with an apparent half-life of less than 55 d at a temperature of 24 C. The second series of tests examined the diffusion of an actual leachate from the Keele Valley Landfill (KVL) (which provided both nutrients and a source of bacteria), through a compacted clay. In these tests, the induction period was reduced to 40--60 d, after which the apparent half-life was 20 d or less at 27 C. The diffusion coefficient for DCM was ...

1997-12-01

173

Understanding of the volatility of GeO/sub 2/ in the presence of WO/sub 2/  

Energy Technology Data Exchange (ETDEWEB)

The equilibria composition of the gaseous and the solid phase in the system GeO/sub 2//WO/sub 2/ is calculated with an improved thermodynamical program for temperatures 1100 < T < 1400 K and constant volume. By means of the results the experimental observed migration of GeO/sub 2/ in the presence of WO/sub 2/ in a temperature gradient T/sub 2/ ..-->.. T/sub 1/ (1200 ..-->.. 1100 K) in sealed evacuated silica tubes is due to a chemical transport with H/sub 2/ as the transporting agent. The H/sub 2/ is formed by H/sub 2/O which is desorbed by the quartz glass of the ampoules. The also observed volatility of WO/sub 2/ and its deposition in form of Ge/sub 0.75/W/sub 3/O/sub 9/ at the 'cold' end (T/sub 1/) of the tubes is performed by gaseous GeWO/sub 4/. The calculated and experimental transport rates are compared and discussed.

1983-08-01

174

The fate of trace elements at coal-fired power plants  

International Nuclear Information System (INIS)

Within the framework of a Dutch research program on the environmental effects of coal combustion 15 measuring campaigns were carried out in the eighties. All the relevant ingoing and outgoing flows of electric power plants were sampled and the heavy metals composition was determined. An overview is given of these fifteen measuring campaigns. It is concluded that between 99.7% and 99.9% of the fly ash can be separated by electrofilters. The removal of solid elements is higher than 99%, except for those elements, which are enriched in the fly ash, f.e. Cd and Se (>90% removal is possible). Additional separation of the emissions of fly ash and elements in the fly ash takes place in a flue gas desulfurization (FGD) installation. Some elements are emitted as gaseous wastes. After the electrofilter Cl, F and I can be found for almost 100%, Br and Hg for 50% on average, and only small amounts of As and Se in the gaseous phase. In a wet FGD unit ...

175

Selective perovskite catalysts to oxidize ammonia to nitric oxide  

Energy Technology Data Exchange (ETDEWEB)

A process is described for the selective oxidation of ammonia to nitric oxide in about 90% or greater yield with a minimum of nitrogen or dinitrogen oxide (N/sub 2/O) as by-products, comprising: (1) contacting gaseous ammonia in an oxygen containing gas optionally with an inert gaseous diluent with a mixed metal perovskite catalyst of the general formula: ABO/sub 3/, wherein: A is selected from the alkali, alkaline earth, lanthanide, or actinide metals or a mixture of these metals having a relatively large ionic, radius, and B is selected from an element or a combination of elements selected from Groups IB, IVB, VB, VIB, VIIB, or VIII of the Periodic Table, wherein the perovskite phase of the catalyst has an equilibrium partial pressure of oxygen at 1000/sup 0/C of greater than about 10/sup -15/ bar; and (2) heating the reactants of step (1) at greater than about 500/sup 0/C under conditions of 10 to 100,000 hr/sup -1/ hourly space velocity.

1989-03-14

176

Selective perovskite catalysts to oxidize ammonia to nitric oxide  

International Nuclear Information System (INIS)

A process is described for the selective oxidation of ammonia to nitric oxide in about 90% or greater yield with a minimum of nitrogen or dinitrogen oxide (N/sub 2/O) as by-products, comprising: (1) contacting gaseous ammonia in an oxygen containing gas optionally with an inert gaseous diluent with a mixed metal perovskite catalyst of the general formula: ABO/sub 3/, wherein: A is selected from the alkali, alkaline earth, lanthanide, or actinide metals or a mixture of these metals having a relatively large ionic, radius, and B is selected from an element or a combination of elements selected from Groups IB, IVB, VB, VIB, VIIB, or VIII of the Periodic Table, wherein the perovskite phase of the catalyst has an equilibrium partial pressure of oxygen at 1000"0C of greater than about 10/sup -15/ bar; and (2) heating the reactants of step (1) at greater than about 500"0C under conditions of 10 to 100,000 hr/sup -1/ hourly space velocity.

1989-03-01

177

Secondary star formation within massive star clusters: Origin of multiple stellar populations in globular clusters  

CERN Document Server

We numerically investigate whether and how gaseous ejecta from AGB stars can be converted into new stars within originally massive star clusters (MSCs) in order to understand the origin of multiple stellar populations in globular clusters (GCs). We adopt a scenario in which (i) MSCs with masses of M_s can be formed from high-mass, high-density giant molecular clouds (GMCs) in their host galactic building blocks embedded in dark matter halos at high redshifts and (ii) their evolution therefore can be significantly influenced by M_s, their initial locations, and physical properties of their hosts. Our 3D hydrodynamical simulations show that gaseous ejecta from AGB stars can be retained within MSCs and consequently converted into new stars very efficiently in the central regions of MSCs, only if M_s exceed a threshold mass (M_th) of ~10^6 M_sun. The new stars can correspond to the ``second generation (SG)'' of stars with higher Na and lower O ...

2010-01-01

178

Proceedings of waste stream minimization and utilization innovative concepts: An experimental technology exchange. Volume 2, Industrial liquid waste processing, industrial gaseous waste processing  

Energy Technology Data Exchange (ETDEWEB)

This two-volume proceedings summarize the results of fifteen innovations that were funded through the US Department of Energy`s Innovative Concept Program. The fifteen innovations were presented at the sixth Innovative Concepts Fair, held in Austin, Texas, on April 22--23, 1993. The concepts in this year`s fair address innovations that can substantially reduce or use waste streams. Each paper describes the need for the proposed concept, the concept being proposed, and the concept`s economics and market potential, key experimental results, and future development needs. The papers are divided into two volumes: Volume 1 addresses innovations for industrial solid waste processing and municipal waste reduction/recycling, and Volume 2 addresses industrial liquid waste processing and industrial gaseous waste processing. Individual reports are indexed separately.

1993-04-01

179

Performance enhancement of a compact radio frequency ion source by the injection of supplemental electrons  

Energy Technology Data Exchange (ETDEWEB)

A versatile, high brightness, volume type, low power RF source, capable of producing positive ion beams with intensities as high as 1 mA from gaseous feed materials and microamperes of negative ion beams has been characterized. The source can also be operated as a plasma sputter negative ion source to generate up to 1 mA of a selected species. The performance of the source in the positive and negative volume modes of operation can be greatly enhanced by addition of a removable, water cooled filament assembly in place of the negative sputter probe. For examine, the material utilization efficiencies of gaseous feed species can be more than doubled, total current intensities increased up to 40%, molecular dissociation fractions increased by 20% and minimum operating pressures reduced by a factor of four when operated in the volume mode. These added electrons also favorably effect, as a consequence of lower pressures, the emittance apparently ...

1995-07-01

180

On the orbital evolution and growth of protoplanets embedded in a gaseous disc  

CERN Document Server

We present a new computation of the linear tidal interaction of a protoplanetary core with a thin gaseous disc in which it is fully embedded. For the first time a discussion of the orbital evolution of cores with eccentricity (e) significantly larger than the gas-disc scale height to radius ratio (H/r) is given. We find that the direction of orbital migration reverses for e>1.1H/r. This occurs as a result of the orbital crossing of resonances in the disc that do not overlap the orbit when the eccentricity is very small. Simple expressions giving approximate fits to the eccentricity damping rate and the orbital migration rate are presented. We go on to calculate the rate of increase of the mean eccentricity for a system of protoplanetary cores due to dynamical relaxation. By equating the eccentricity damping time-scale with the dynamical relaxation time-scale we deduce that an equilibrium between eccentricity damping and excitation through scattering is attained ...

1999-01-01

181

Membrane compressor for leakfree compression of gaseous fluids; Membranverdichter fuer das leckfreie Verdichten gasfoermiger Fluide  

Energy Technology Data Exchange (ETDEWEB)

Leakfree compression of gaseous liquids prevents impurities resulting from entry of lubricants and abrasive particles and is therefore an important requirement on modern compressors. Another requirement voiced increasingly often is the reduction or even prevention of problematic off-gases and contaminated residues of libricating oils. Further, compressors should have high corrosion resistance, low noise, a long service life and high reliability. Membrane compressors are largely able to meet these requirements. The article describes the technical concept and applications of membrane compressors. (orig.) [Deutsch] Umweltschutz und steigende Forderungen der Industrie an die Reinheit technischer Gase verlangen Kompressoren, die weitgehend leckagefrei verdichten und keine Verunreinigungen des Gases durch Schmierstoffe und Abrieb hervorrufen. Immer haeufiger wird in diesem Zusammenhang die Reduzierung oder sogar die Vermeidung von schwer zu entsorgenden Abgasen und ...

1996-09-01

182

IC 4767 (the X-galaxy) - the missing link for understanding galaxies with peanut-shaped bulges?  

International Nuclear Information System (INIS)

Photometric and kinematic observations of the peculiar S0 galaxy IC 4767, the X-galaxy, are presented. At various intensities the bulge of this galaxy looks like a normal spheroidal system with elliptical isophotes, a well-defined rectangle, and a peanut-shaped or X-shaped structure with components aligned at oblique angles to the major axis. The observations reveal a rapidly rotating inner disk of gas and dust which is nearly aligned with the major axis. The presence of gaseous emission alone suggests an accretion event. The stars in the outer regions of the X-component are rotating nearly as rapidly as the gas in the main disk, indicating that they are in relatively circular orbits. The five most prominent peanut-shaped bulges all have several nearby companions, evidence that the peanut deformity is due to interaction between galaxies. An analogy with the formation mechanism proposed for polar-ring galaxies suggests how an X-shaped component could develop from ...

1988-01-01

183

Fuel/propellant mixing in an open-cycle gas core nuclear rocket engine  

International Nuclear Information System (INIS)

A numerical investigation of the mixing of gaseous uranium and hydrogen inside an open-cycle gas core nuclear rocket engine (spherical geometry) is presented. The gaseous uranium fuel is injected near the centerline of the spherical engine cavity at a constant mass flow rate, and the hydrogen propellant is injected around the periphery of the engine at a five degree angle to the wall, at a constant mass flow rate. The main objective is to seek ways to minimize the mixing of uranium and hydrogen by choosing a suitable injector geometry for the mixing of light and heavy gas streams. Three different uranium inlet areas are presented, and also three different turbulent models (k-var-epsilon model, RNG k-var-epsilon model, and RSM model) are investigated. The commercial CFD code, FLUENT, is used to model the flow field. Uranium mole fraction, axial mass flux, and radial mass flux contours are obtained. copyright 1997 American Institute of Physics.

1997-01-01

184

Extended Gas in Seyfert Galaxies Near Infrared Observations of NGC 2110 and Circinus  

CERN Document Server

We present results of near--IR long-slit spectroscopy in the J and K bands of the Seyfert 2 galaxies NGC 2110 and Circinus, investigating the gaseous distribution, excitation, reddening and kinematics. In NGC 2110, the emission line ratio [FeII]/Pa beta increases towards the nucleus (to ~ 7). The nuclear [Fe II]1.257 (microns) and Pa beta lines are broader (FWHM ~ 500 km/s) than the H2 (2.121) line (FWHM ~ 300 km/s). Both these results suggest that shocks, driven by the radio jet, are an important source of excitation of [Fe II]. The H2 excitation appears to be dominated by X-rays from the nucleus. In Circinus, both [FeII]/Pa beta and H2/Br gamma decrease from ~ 2 at 4 arcsec from the nucleus to nuclear values of ~ 0.6 and ~ 1, respectively, suggesting that the starburst dominates the nuclear excitation, while the AGN dominates the excitation further out (r > 2 arcsec). For both galaxies, the gaseous kinematics are consistent with circular ...

1998-01-01

185

Elucidation of hydrogen mobility in tetralin under coal liquefaction conditions using a tritium tracer method. Effects of the addition of H2S and H2O; Tritium tracer ho wo mochiita sekitan ekika hanno jokenka deno tetralin no suiso idosei hyoka. Ryuka suiso oyobi mizu no tenka koka  

Energy Technology Data Exchange (ETDEWEB)

It was previously reported that the tritium tracer method is useful for the quantitative consideration of hydrogen behavior in coal during coal liquefaction reaction. Tetralin is excellent hydrogen donating solvent, and is considered as one of the model compounds of coal. In this study, effects of H2S and H2O on the hydrogen exchange reaction between tetralin and gaseous hydrogen labeled by tritium were investigated. It was suggested that the conversion of tetralin and the hydrogen exchange reaction between gaseous hydrogen and tetralin proceed through the radical reaction mechanism with a tetralyl radical as an intermediate product. When H2S existed in this reaction, the hydrogen exchange yield increased drastically without changing the conversion yield. This suggested that the hydrogen exchange reaction proceeds even in the reaction where radical does not give any effect. In the case of H2O addition, the conversion yield and hydrogen exchange ...

1996-10-28

186

Dynamic behaviors of sulfur evolved in the gas phase from pyrolysis of six Chinese coals  

Energy Technology Data Exchange (ETDEWEB)

Dynamic behaviors of gaseous sulfur-containing compounds evolved from pyrolysis of six Chinese coals were studied in the temperature range of up to 800{sup o}C under N{sub 2} and H{sub 2}. The released amount of total sulfur-containing gases was traced by an online flame photometric detector (FPD). Simultaneously, the changes of different sulfur forms, including H{sub 2}S, SO{sub 2}, COS and CS{sub 2}, also were investigated using an online mass spectrometer (MS). FPD results show that the effect of H{sub 2} on gaseous sulfur evolved is complex, which promoted certain peak and suppresses other peaks. Based on the data from MS, it is suggested that a series of competitive reactions between active sulfur and other active matters during pyrolysis may impact on the sulfur form in gas phase. Interactions between active sulfur-containing intermediates and the coal matrix are attributed to be the main factor determining the dynamic behavior.

2006-07-01

187

Development of Micromegas-like gaseous detectors using a pixel readout chip as collecting anode  

International Nuclear Information System (INIS)

This thesis reports on the fabrication and test of a new gaseous detector with a very large number of readout channels. This detector is intended for measuring the tracks of charged particles with an unprecedented sensitivity to single electrons of almost 100 %. It combines a metal grid for signal amplification called the Micromegas with a pixel readout chip as signal collecting anode and is dubbed GridPix. GridPix is a potential candidate for a sub-detector at a future electron linear collider (ILC) foreseen to work in parallel with the LHC around 2020--2030. The tracking capability of GridPix is best exploited if the Micromegas is integrated on the pixel chip. This integrated grid is called InGrid and is precisely fabricated by wafer post-processing. The various steps of the fabrication process and the measurements of its gain, energy resolution and ion back-flow property are reported in this document. Studies of the response of the complete detector formed by an ...

188

Decomposed methanol workshop report alternative fuels utilization contractors' coordination meeting. Part 1  

Energy Technology Data Exchange (ETDEWEB)

The proceedings of a workship of researchers and potential users of decomposed method fuel for Otto cycle engines are presented. The purpose of the meeting was to review the state-of-the-art. Proponents for its use state that by using exhaust waste heat to decompose the methanol, the resulting gaseous fuel constituents have more energy content than that in the original liquid. The drawbacks include the unapplicability during engine warmup and the fraction of automobile duty cycle related thereto, the reduced volumetric efficiency associated with any gaseous fuel, and the tradeoffs between improved thermal efficiency and reduced power output with lean fuel mixtures. There has always been a dilemma as to whether a decomposed methanol system is a variation on the application of methanol, of hydrogen, or both. However, the more immediate issue is whether use of methanol is liquid, decomposed or dual form is the most cost effective and energy ...

1983-10-01

189

Binaries migrating in a gaseous disk: Where are the Galactic center binaries?  

CERN Document Server

The massive stars in the Galactic center inner arcsecond share analogous properties with the so-called Hot Jupiters. Most of these young stars have highly eccentric orbits, and were probably not formed in-situ. It has been proposed that these stars acquired their current orbits from the tidal disruption of compact massive binaries scattered toward the proximity of the central supermassive black hole. Assuming a binary star formed in a thin gaseous disk beyond 0.1 pc from the central object, we investigate the relevance of disk-satellite interactions to harden the binding energy of the binary, and to drive its inward migration. A massive, equal-mass binary star is found to become more tightly wound as it migrates inwards toward the central black hole. The migration timescale is very similar to that of a single-star satellite of the same mass. The binary's hardening is caused by the formation of spiral tails lagging the stars inside the binary's Hill radius. We show ...

2010-01-01

190

Air pollutants emissions from waste treatment and disposal facilities.  

Science.gov (United States)

This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some cases the levels ...

2006-01-01

191

A two-arm gaseous spiral in the inner 200 pc of the early-type galaxy NGC 2974: signature of an inner bar  

CERN Document Server

TIGER integral-field spectrography and HST/WFPC2 imaging of the E3 galaxy NGC 2974 are used to derive the kinematics of the stellar and ionized gas components in its central 500 pc. We derive a numerical two-integral distribution function from a MGE mass model using the HQ formalism. The TIGER as well as published long-slit stellar kinematics are well fitted with this self-consistent model, requiring neither the addition of a significant mass contribution from a hidden disc structure, nor the presence of a central dark mass. The data reveal the presence of a striking, highly contrasted, two-arm gaseous spiral structure within a radius of ~200 pc, corresponding to a total mass of 6.8x10^4 Msun of ionized gas. We use a deconvolved TIGER datacube to probe its kinematics at a resolution of about 0.35 arcsec. Strong departures from circular motions are observed, as well as high velocity dispersion values on the inner side of the arms. We interpret the observed gas ...

2003-01-01

192

Multiscale modeling of transdermal drug delivery  

Science.gov (United States)

This study addresses the modeling of transdermal diffusion of drugs, to better understand the permeation of molecules through the skin, and especially the stratum corneum, which forms the main permeation barrier of the skin. In transdermal delivery of systemic drugs, the drugs diffuse from a patch placed on the skin through the epidermis to the underlying blood vessels. The epidermis is the outermost layer of the skin and can be further divided into the stratum corneum (SC) and the viable epidermis layers. The SC consists of keratinous cells (corneocytes) embedded in the lipid multi-bilayers of the intercellular space. It is widely accepted that the barrier properties of the skin mostly arises from the ordered structure of the lipid bilayers. The diffusion path, at least for lipophilic molecules, seems to be mainly through the lipid bilayers. Despite the advantages of transdermal drug delivery compared to other drug ...

2006-01-01

193

Diffusion of adatoms on face-centered cubic transition metal surfaces  

Energy Technology Data Exchange (ETDEWEB)

Mechanisms and associated energetics for adatom diffusion on the (100) and (110) surfaces of Ni, Cu, Rh, Pd, and Ag are investigated. Self-diffusion was studied on (100) and (I 10) surfaces of Ni, Cu, Pd and Ag using corrected effective medium method (CEM) and approximation to CEM used for molecular dynamics and Monte Carlo studies (MD/MC-CEM). Self-diffusion on Pd(100), Ag(100), Ni(110), Cu(110), Pd(110), and Ag(110) is accomplished by classical diffusion: the adatom hops from its equilibrium adsorption site over an intervening bridge site to an adjacent equilibrium site. Self-diffusion on Ni(100) and Cu(100) proceeds by atomic-exchange diffusion: the adatom on the surface displaces an atom in the first surface layer. Aside from explicit inclusion of the kinetic-exchange-correlation energy, it is critical to include enough movable atoms in the calculation to ...

1994-05-10

194

Wear resistance of a laser surface alloyed Ti-6Al-4V alloy  

Energy Technology Data Exchange (ETDEWEB)

Laser surface alloying with gaseous nitrogen was utilized to improve the wear resistance of a Ti-6Al-4V alloy. Wear-resistant composite coatings reinforced by hard TiN dendrites were produced 'in-situ' on a substrate of a Ti-6Al-4V alloy. The hardness and wear resistance of the laser alloyed coating under two-body abrasive and block-on-ring full-sliding wear conditions were significantly enhanced. (orig.)

2000-08-01

195

The design of an irradiator for the continuous processing of liquid latex  

International Nuclear Information System (INIS)

This paper presents anew design concept for a gamma irradiation plant for the continuous processing of pumpable liquids. Typical applications of such a plant include: the irradiation vulcanisation of natural latex rubber; disinfection of municipal sewage sludge for agricultural use; sterilisation of liquids in the pharmaceutical and cosmetics industries; industrial processing of bulk liquids The authors describe the design and operation of the latex irradiator now operating on a small production scale in Malaysia and proposed developments. The design allows irradiation processing to be carried out under an inert or other gaseous environment. State-of-the-art computer control system ensures the fully automatic processing operation needed by industrial computers.

1998-06-01

196

Statement of Work (SOW) for services provided by the Waste Sampling and Characterization Facility for the Effluent and Environmental Monitoring Program during calendar year 1998  

Energy Technology Data Exchange (ETDEWEB)

This document defines the services the Waste Sampling and Characterization Facility (WSCF) shall provide the Effluent and Environmental Monitoring Program (EEM) throughout the calendar year for analysis. The purpose of the EEM Program is to monitor liquid and gaseous effluents, and the environment immediately around the facilities which may contain radioactive and hazardous materials. Monitoring data are collected, evaluated, and reported to determine their degree of compliance with applicable federal and state regulations and permits.

1998-10-22

197

Selection of detailed items for periodic safety review on PWR radwaste management system  

International Nuclear Information System (INIS)

Selection of detailed-items for Periodic Safety Review on PWR radwaste management system, the main component could be faithfully clarified according to the purpose of establishment on each system and basic purpose. It is proper to select detailed-items those of radioactivities in the reactor coolant activity levels and the released volume of liquid and gaseous radioactive material on safety performance. It's also proper to select solid radwaste production quantities as detailed-item that it would be predict the next ten years trends after PSR.

2003-10-01

198

Reports of the Hokkaido National Industrial Research Institute, No. 63, March 1995  

Energy Technology Data Exchange (ETDEWEB)

;Table of Contents: Gaseous Pollutants Emissions from Coal Combustors and Their Control Technologies in Japan; Simultaneous Determination of Cooper (II) and Iron (III) Using 8-Quinolinol by Solvent Extraction Flow-injection Method; Fundamental Studies on Red Mud as a Catalyst for Coal Liquefaction: Studies on Active Components in Red Mud and Possibilities for Improvement of Its Catalytic Activities; Elution Behavior of Coal-derived Liquids with Sephadex LG-20; Characteristic of Activated Carbon Produced from Scrap Tires at Different Activation Temperatures; Energy Saving Snow Melting System.

1995-03-01

199

Refining technique for converting coal to liquid fuel  

Science.gov (United States)

According to W. H. Wiser and A. G. Oblad, the program at the University of Utah to develop coal conversion techniques, which has received federal grants of $1.35 million since 1969, recently was awarded $425,000 from the U.S. Office of Coal Research for the development of catalysts for coal conversion and low-sulfur fuel oil production. In tests, 100 lb of coal have been converted into 95 lb of products composed of 30 lb liquid fuel like gasoline, 5 lb of diesel or fuel oil, 30 lb of gaseous fuel, and 30 lb of char.

1973-10-01

200

Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane  

Energy Technology Data Exchange (ETDEWEB)

A process is claimed for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons, namely, acetic acid, ethanol and acetaldehyde, by continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with one or more alkali metals selected from the group consisting of lithium, potassium, cesium and rubidium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.

1980-11-25

201

In situ bioremediation using horizontal wells. Innovative technology summary report  

Energy Technology Data Exchange (ETDEWEB)

In Situ Bioremediation (ISB) is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation. This process (ISB) involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove Volatile Organic Compounds (VOCs) from the vadose zone concomitant with biodegradation of the VOCs. This process is effective for remediation of soils and ground water contaminated with VOCs both above and below the water table. A full-scale demonstration of ISB was conducted as part of the Savannah River Integrated Demonstration: VOCs in Soils and Ground Water at Nonarid Sites. This demonstration was performed at the Savannah River Site from February 1992 to April 1993.

1995-04-01

202

Ignition delay in the dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

Tests have been conducted on a special compression ignition research engine to investigate the effects of gaseous fuels on the ignition delay in dual fuel engines. Diesel oil, n-heptane, or cetane were used as pilot fuels, and hydrogen, carbon monoxide, or methane were inducted in the intake manifold. Induction of nitrogen was used as a reference to eliminate the influence of changes in oxygen concentration and specific heats. Helium was inducted in additional tests. From the results of a number of parameter variations, the cylinder charge temperature (determined by intake temperature and compression ratio), the pilot fuel amount, and the flow of combustible gas were found to have the most significant influence on the ignition delay.

1987-01-01

203

Experimental determination of the evolution of organic matter thermal maturity indicators. Application to the Toarcian kerogens from the Paris basin  

Energy Technology Data Exchange (ETDEWEB)

The experimental maturation of an immature kerogen from the Toarcian of the Paris basin has been carried out in a confined system under pressure. The evolution of various thermal maturity parameters was plotted against the corrected organic carbon percentage chosen as a common maturity indicator and compared with data extracted from a natural series. Results show the occurrence of three distinct stages respectively characterized by the removal of oxygenated compounds, the genesis of liquid hydrocarbons and the production of gaseous hydrocarbons.

1989-03-01

204

Anion formation from gaseous and condensed molecules on low-energy electron impact  

International Nuclear Information System (INIS)

The interaction of free electrons in the energy range from 0 to 10 eV with molecules at different stages of aggregation is investigated. The mechanism in the gas phase under single collision conditions is described. Fullerenes C_6_0 and C_7_0 are used as targets. Electron impact on condensed molecules can lead to temporary negative ions. The formation of Cl"- from gas phase CCl_4 and the desorption of Cl"- from 6 monolayer CCl_4 film on an Au substrate is determined experimentally. (Suda).

1994-03-20

205

Advances in imaging THGEM-based detectors  

International Nuclear Information System (INIS)

We report on recent measurements with Thick GEM-like (THGEM)-based imaging detectors. The THGEM is a robust gaseous electron multiplier similar to GEM but with larger dimensions. It has high electron multiplication, of 105 and 107 in single- and double-THGEM structure, respectively, fast signals and ?10MHz/mm2 counting rate capability. It can be produced in any shape and over large area. In view of many possible applications of THGEM-based imaging detectors, in particle physics and beyond, we have recently studied the localization properties of a 2D 10x10cm2 detector. The results of these studies are presented.

2007-03-01

206

Thermal release of volatile fission products from irradiated nuclear fuel  

International Nuclear Information System (INIS)

An effective procedure for removing _3H, Xe and Kr from irradiated fuels was demonstrated using Shippingport UO"2 fuel. The release characteristics of _3H, Kr, Xe, and I from irradiated nuclear fuel have been determined as a function of temperature and gaseous environment. Vacuum outgassing and a flowing gas stream have been used to vary the gaseous environment. Vacuum outgassing released about 99% of the _3H and 20% of both Kr and Xe within a 3 h at 1500_0C. Similar results were obtained using a carrier gas of He containing 6% H"2. However, a carrier gas containing only He resulted in the release of approximately 80% of the _3H and 99% of both Kr and Xe. These results indicate that the release of these volatile fission products from irradiated nuclear fuel is a function of the chemical composition of the gaseous environment. The rate of tritium release increased with increasing temperature (1100 to 1500_0C) and with the ...

207

Spectroscopic investigation of the charge dynamics of heavy ions penetrating solid and gaseous targets  

Energy Technology Data Exchange (ETDEWEB)

This thesis presents the study of the slowing down process of fast heavy ions inside matter. In the framework of this research, the influence of the target density on the stopping process is investigated. Experiments on the interaction of {sup 48}Ca{sup 6+}-{sup 48}Ca{sup 10+} and {sup 26}Mg{sup 5+} ion beams with initial energies of 11.4 MeV/u and 5.9 MeV/u with solid and gaseous targets have been carried out. A novel diagnostic method, X-ray spectroscopy of K-shell projectile radiation, is used to determine the ion charge state in relation to its velocity during the penetration of fast heavy ions inside the stopping material. A spatially resolved analysis of the projectile and target radiation in solids is achieved for the first time. The application of low-density silica aerogels as stopping media provided a stretching of the ion stopping length by 20 - 100 times in comparison with solid quartz. The Doppler Effect observed on the projectile K-shell spectra is ...

2007-01-15

208

Numerical simulation of the direct-injection diesel engine under motored and firing conditions  

Energy Technology Data Exchange (ETDEWEB)

An Eulerian/Langrangian model was developed to study the two-phase flow in a two-dimensional, axisymmetric, direct-injection diesel engine, under motored and firing conditions. The liquid phase was tracked in a Lagrangian sense using discrete droplet packets (DDP). The gaseous phase was solved using an implicit, iterative, finite-difference, scheme of the control volume variety. Gaseous-phase turbulence was modeled using a compressible two-equation k/epsilon model. Turbulence effects on the liquid phase were modeled by superimposing a randomly oriented turbulent eddy velocity proportional to the root of the turbulent kinetic energy, on each packet's mean relative velocity. Droplet-droplet interactions were neglected. The general knowledge obtained during validation studies, was used to simulate the direct-injection two-stroke diesel engine under motored conditions. The simulation showed that by beginning of the injection, (15/sup 0/ ...

1986-01-01

209

Geochemical characteristics and origin of gases from the Upper, Lower Paleozoic and the Mesozoic reservoirs in the Ordos Basin, China  

Energy Technology Data Exchange (ETDEWEB)

The Ordos Basin, the second largest sedimentary basin in China, contains the broad distribution of natural gas types. So far, several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin, each having over 1000x10{sup 8}m{sup 3} of proven gas reserves, and several gas pools have also been discovered in the Mesozoic. This paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs, and then discussed their origin. For hydrocarbons preserved in the Upper Paleozoic, the elevated {delta}{sup 13}C values of methane, ethane and propane indicate that the gases would be mainly coal-formed gases; the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different maturity. In the Lower Paleozoic, the {delta} {sup 13}C{sub 1} values are mostly similar with those in the Upper Paleozoic, but the {delta}{sup 13}C{sub 2} and ...

2008-05-15

210

Effect of secondary fuels and combustor temperature on mercury speciation in pulverized fuel co-combustion: part 1  

Energy Technology Data Exchange (ETDEWEB)

The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel particles, low surface ...

2007-08-15

211

Degradation of materials under conditions of the sulfur-iodine thermochemical cycle  

Energy Technology Data Exchange (ETDEWEB)

The sulfur-iodine (SI) thermochemical cycle is one of the main candidate methods to produce hydrogen from non-fossil sources like nuclear (GEN IV reactor) or solar thermal power. A major issue for the successful implementation of the SI cycle is the selection of technically viable and economic materials for construction of process components, particularly heat exchangers. Challenging conditions are encountered in each of the three sections of the SI cycle due to the corrosive chemicals present, including sulfuric acid, iodine, hydroiodic acid, sulfur dioxide, hydrogen, oxygen, and others. In Section I, aqueous, non-aqueous (liquid iodine), and gaseous multi-component phases are present at about 120 {sup o}C and 0.7 MPa. Section II involves gaseous and aqueous phases of sulfuric acid, sulfur dioxide, and oxygen at up to about 830 {sup o}C and 3.6 MPa. In Section III , aqueous, non-aqueous, and gaseous phases, at up to 310 ...

2009-07-01

212

Weak Ties: A Subtle Role in the Information Diffusion of Online Social Networks  

CERN Document Server

As a social media, online social networks play a vital role in the social information diffusion. However, due to its unique complexity, the mechanism of the diffusion can be different from the ones in other types of networks and remains unclear to us. Meanwhile, few works have been done to reveal the coupled dynamics of both the structure and the diffusion of online social networks. To this end, in this paper, we propose a model to investigate how the structure is coupled with the diffusion in online social networks from the view of weak ties. Through numerical experiments on large-scale online social networks, we find that in contrast to some previous research results, selecting weak ties preferentially to republish cannot make the information diffuse quickly, while random selection can achieve this goal. However, when we remove the weak ties gradually, the coverage of the ...

2010-01-01

213

Modelisation of boron diffusion from ultra-low-energy implantation in crystalline silicon  

Energy Technology Data Exchange (ETDEWEB)

We have investigated and modeled the boron diffusion in silicon following ultra-low-energy implantation (500 eV). It is well known that reducing implant energies is an effective way to eliminate transient enhanced diffusion due to the excess of interstitials from the implant. However, for sub-keV B implants diffusion remains enhanced. This enhancement is linked to the presence of a silicon boride layer located at the silicon surface which creates interstitials. This phenomenon is named 'boron enhanced diffusion' (BED). The BED effect is of obvious interest since it counteracts the advantage obtained by reducing the ion implantation energy. For these reasons, we have investigated the diffusion of low-energy boron implanted in crystalline silicon and tested a complete simulation program, which takes into account the effect of boron precipitation and the effect of the ...

2003-12-31

214

Mechanism for transient-enhanced diffusion in ion-implanted silicon  

International Nuclear Information System (INIS)

High-dose ion implantation followed by solid-phase-epitaxial (SPE) growth is now a well-established technique for the production of supersaturated silicon alloys. However, these alloys also contain a high supersaturation of silicon interstitials, which give rise to transient, greatly enhanced dopant diffusion with subsequent heating. In this contribution, the authors present a study of a series of Si-Sb alloys of various concentrations which were made by Sb implantation under various conditions to deduce the origin of the observed transient diffusion. A multiple implant scheme was employed to produce samples with an approximately uniform dopant concentration from 40 to 150 nm in depth, but with the amorphous layer extending to a depth of 380 nm. By scaling the implant doses, alloys with different concentrations in the uniform region were produced, allowing an accurate measure of diffusion coefficients as a function of ...

1985-03-01

215

Effect of the Ge preamorphization dose on boron diffusion and defect evolution in silicon  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we study the effect of the Ge{sup +} preamorphization dose on boron diffusion and on the thermal evolution of end of range (EOR) defects during annealing. Amorphizations were carried out by implanting Ge{sup +} at 150 keV to doses ranging from 1x10{sup 15} to 8x10{sup 15} ions/cm{sup 2}. Boron was subsequently implanted at 3 keV with a dose of 1x10{sup 14} ions/cm{sup 2}. Rapid thermal annealing (RTA) was performed for various time/temperature combinations in nitrogen ambient. Secondary ion mass spectroscopy (SIMS) and transmission electron microscopy (TEM) were used to study boron diffusion and defect evolution, respectively. We have found that after a given annealing, both the defect size and boron diffusivity are independent on the Ge ion dose. Increasing this dose only results in an increase of the defect density. These results are discussed and definitely show that EOR defects are involved in a ...

2002-01-01

216

Effect of the Ge preamorphization dose on boron diffusion and defect evolution in silicon  

International Nuclear Information System (INIS)

In this paper, we study the effect of the Ge"+ preamorphization dose on boron diffusion and on the thermal evolution of end of range (EOR) defects during annealing. Amorphizations were carried out by implanting Ge"+ at 150 keV to doses ranging from 1x10"1"5 to 8x10"1"5 ions/cm"2. Boron was subsequently implanted at 3 keV with a dose of 1x10"1"4 ions/cm"2. Rapid thermal annealing (RTA) was performed for various time/temperature combinations in nitrogen ambient. Secondary ion mass spectroscopy (SIMS) and transmission electron microscopy (TEM) were used to study boron diffusion and defect evolution, respectively. We have found that after a given annealing, both the defect size and boron diffusivity are independent on the Ge ion dose. Increasing this dose only results in an increase of the defect density. These results are discussed and definitely show that EOR defects are involved in a quasi-conservative Ostwald ripening ...

2002-01-01

217

Boron-enhanced diffusion of boron from ultralow-energy ion implantation  

Energy Technology Data Exchange (ETDEWEB)

We have investigated the diffusion enhancement mechanism of boron-enhanced diffusion (BED), wherein boron diffusivity is enhanced four to five times over the equilibrium diffusivity at 1050&hthinsp;{degree}C in the proximity of a silicon layer containing a high boron concentration. It is demonstrated that BED is driven by excess interstitials injected from the high boron concentration layer during annealing. For evaporated layers, BED is observed above a threshold boron concentration between 1{percent} and 10{percent}, though it appears to be closer to 1{percent} for B-implanted layers. For sub-keV B implants above the threshold, BED dominates over the contribution from transient-enhanced diffusion to junction depth. For 0.5 keV B, this threshold implantation dose lies between 3{times}10{sup 14} and 1{times}10{sup 15} cm{sup {minus}2}. It is proposed that the excess ...

1999-04-01

218

Boron-enhanced diffusion of boron from ultralow-energy ion implantation  

International Nuclear Information System (INIS)

We have investigated the diffusion enhancement mechanism of boron-enhanced diffusion (BED), wherein boron diffusivity is enhanced four to five times over the equilibrium diffusivity at 1050 ampersand hthinsp;degree C in the proximity of a silicon layer containing a high boron concentration. It is demonstrated that BED is driven by excess interstitials injected from the high boron concentration layer during annealing. For evaporated layers, BED is observed above a threshold boron concentration between 1% and 10%, though it appears to be closer to 1% for B-implanted layers. For sub-keV B implants above the threshold, BED dominates over the contribution from transient-enhanced diffusion to junction depth. For 0.5 keV B, this threshold implantation dose lies between 3x10"1"4 and 1x10"1"5 cm"-"2. It is proposed that the excess interstitials responsible for BED are produced during the ...

1999-04-01

219

A transient enhanced diffusion model of lattice restoration during rapid thermal annealing (RTA)  

International Nuclear Information System (INIS)

A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of As-implanted Si. The relations of the enhanced diffusion to residual defects and lattice restoration have been studied in detail. The As concentration profiles and residual defects are measured. It is found from the data that the lattice has been restored when the implanted sample is annealed at 1150 deg C (or 1050 deg C) for 1s. The defect density decreases rapidly with increase of annealing time (from 1 to 12s). The enhanced diffusion coefficient maximum appears in the annealing time ranging from 1 to 5s. Allmost a 'complete' annealing of displacemet damage is obtained and the diffusion coefficient is less than that in above-mentioned conditions when the implanted samples are annealed at 1150 deg C in the time ranging from 12 to 20s. the mechanism of lattice restoration and enhanced ...

220

Solution-based characterization of surface-enhanced Raman response of single scattering centers  

Energy Technology Data Exchange (ETDEWEB)

We demonstrate the rapid optical characterization of large numbers of individual metal nanoparticles freely diffusing in colloidal solution by confocal laser spectroscopy. We find that hollow gold nanospheres and solid silver nanoparticles linked with a bifunctional ligand, both designed nanostructures, exhibit significantly higher monodispersity in their Rayleigh and Raman scattering response than randomly aggregated gold and silver nanoparticles. We show that measurements of rotational diffusion timescales allow sizing of particles significantly more reliably than can be obtained using translational diffusion timescales.

2008-03-06

221

Single-shot diffusion-weighted echo-planar imaging of normal and cirrhotic livers using a phased-array multicoil  

Energy Technology Data Exchange (ETDEWEB)

Single-shot spin-echo diffusion-weighted echo-planar imaging using a phased-array multicoil was performed to distinguish between normal and cirrhotic livers. Sets of 6 images with different b-value were acquired with breath-holding. Significant differences were observed between controls and cirrhosis cases in the signal ratios when the b-value was 383 s/mm{sup 2}, and apparent diffusion coefficients. (orig.)

1998-07-01

222

Precipitation, phase transformation, and enhanced diffusion in ion-implanted silicon  

International Nuclear Information System (INIS)

This paper describes Z-contrast scanning transmission electron microscopy used to study the connection between dopant precipitation and phase transformation in high dose In"+ and Sb"+ implanted Si. In the case of In, the observations confirm a heterogeneous nucleation model. Images of the precursor precipitates give the first measurement of the diffusion coefficient in amorphous Si, with an enhancement of 10"7 over tracer crystalline values. With Sb"+ implants enhanced homogeneous nucleation is observed. The connection between these results and the transient enhanced diffusion observed in crystallized Si is discussed.

223

Oil shale oxidation at subretorting temperatures  

Energy Technology Data Exchange (ETDEWEB)

Green River oil shale was air oxidized at subretorting temperatures. Off gases consisting of nitrogen, oxygen, carbon monoxide, carbon dioxide, and water were monitored and quantitatively determined. A mathematical model of the oxidation reactions based on a shrinking core model has been developed. This model incorporates the chemical reaction of oxygen and the organic material in the oil shale as well as the diffusivity of the oxygen into the shale particle. Diffusivity appears to be rate limiting for the oxidation. Arrhenius type equations, which include a term for oil shale grade, have been derived for both the chemical reaction and the diffusivity.

1980-06-01

224

Numerical study of Cosmic Ray Diffusion in MHD turbulence  

CERN Document Server

We study diffusion of Cosmic Rays (CRs) in turbulent magnetic fields using test particle simulations. Electromagnetic fields are produced in direct numerical MHD simulations of turbulence and used as an input for particle tracing, particle feedback on turbulence being ignored. Statistical transport coefficients from the test particle runs are compared with earlier analytical predictions. We find qualitative correspondence between them in various aspects of CR diffusion. In the incompressible case, that we consider in this paper, the dominant scattering mechanism occurs to be the non-resonant mirror interactions with the slow-mode perturbations. Perpendicular transport roughly agrees with being produced by magnetic field wandering.

2010-01-01

225

Horizontal liquid film-mist two-phase flow, 1  

International Nuclear Information System (INIS)

The entrainment flow rate distribution, the gas velocity profile, and the concentration profile of droplets across the channel cross section in fully developed region of a horizontal rectangular channel of 150 mm width and 50 mm height were measured. The concentration profile of droplets was expressed by a simple equation based on a constant diffusion coefficient model. From this equation the effects of gravity and turbulent diffusion of droplets on the concentration profile were evaluated. The characteristic mean settling velocity of a group of droplets with various diameters was derived, and using this value the mean diffusion coefficient of the group of droplets was obtained. (author).

1980-01-01

226

Feynman scaling violation due to baryon number diffusion in rapidity space  

CERN Document Server

A significant asymmetry in baryon/antibaryon yields in the central region of high energy collisions is observed when the initial state has non-zero baryon charge. This asymmetry is connected with the possibility of a baryon charge diffusion in rapidity space. Evidently, such a diffusion should decrease the baryon charge in the fragmentation region leading to the corresponding decrease of the multiplicity of leading baryons. As a result, a new mechanism for Feynman scaling violation in the fragmentation region is obtained. We present the quantitative predictions for the Feynman scaling violation at LHC energies and even at highier energies that can be important for cosmic ray physics.

2011-01-01

227

Diffusion bonding on superplastic-aluminum and -magnesium alloys  

Energy Technology Data Exchange (ETDEWEB)

The superplastic characteristics and diffusion bonding behaviors were investigated in commercial 7475 aluminum alloy and AZ31 magnesium alloy sheets. In this study, the presently used materials behaved in a superplastic manner at {proportional_to} 773 K (7475Al) and {proportional_to} 523 K (AZ31). Then, by the theoretical relationship between pressure and time, these materials were successfully diffusion bonded at the superplastic temperatures. The bonding strength was more than 65 MPa. The experimental bonding conditions in high quality joining, times and pressures, were good agreed with prediction analysis. (orig.)

2004-07-01

228

Combined effect of magnetic field and thermal dispersion on a non-darcy mixed convection  

British Library Electronic Table of Contents (United Kingdom)

This paper is devoted to investigate the influences of thermal dispersion and magnetic field on a hot semi-infinite vertical porous plate embedded in a saturated Darcy-Forchheimer-Brinkman porous medium. The coefficient of thermal diffusivity has been assumed to be the sum of the molecular diffusivity and the dynamic diffusivity due to mechanical dispersion. The effects of transverse magnetic field parameter (Hartmann number Ha), Reynolds number Re (different velocities), Prandtl number Pr (different types of fluids) and dispersion parameter on the wall shear stress and the heat transfer rate are discussed.

2011-01-01

229

Buoyancy effects in double-diffusive and mixed convection flows  

Science.gov (United States)

When induced by bottom heating in a horizontal fluid layer which is characterized by forced motion or solute stratification, buoyancy-driven flows may assume a variety of forms. The flows, which are examples of mixed or double-diffusive convection, can strongly influence heat tranfer or the entrainment of stratified fluid. General aspects of each form of convection are reviewed, and emphasis is placed on mixed convection in a horizontal rectangular channel and on double-diffusive convection due to thermally driven mixed-layer development in a solutally stratified fluids. Flow conditions are described, and experimental and theoretical results are presented for related heat-transfer and entrainment parameters.

1986-01-01

230

Transient enhanced diffusion in B/sup +/ and P/sup +/ implanted silicon  

International Nuclear Information System (INIS)

The authors report the transient enhanced diffusion of supersaturated phosphorous in ion-implanted SPE grown Si. Precipitation proceeds rapidly to a metastable SiP phase, which can be converted to an orthorhombic form or re-dissolved by subsequent heat treatment. The effects are strongly temperature dependent, and consistent with the trapped interstitial model. The behavior of different dopants follow their relative interstitialcy diffusion coefficients. The results suggest that ion implantation induced point defects dominate over thermally activated point defects during low temperature and certain rapid thermal processing, controlling dopant deactiviation and diffusion in crystalline or amorphous silicon, and can also affect the SPE growth rate.

231

Thermal diffusivity of homogeneous SBR MOX fuel with a burn-up of 35 MWd/kgHM  

International Nuclear Information System (INIS)

The effect of burn-up on the thermal conductivity of homogeneous SBR MOX fuel is investigated and compared with standard UO_2 LWR fuel. New thermal diffusivity results obtained on SBR MOX fuel with a pellet burn-up of 35 MWd/kgHM are reported. The thermal diffusivity measurements were carried out at three radial positions using a shielded 'laser-flash' device and show that the thermal diffusivity increases from the pellet periphery to the centre. The fuel thermal conductivity was found to be in the same range as for UO_2 of similar burn-up. The annealing behaviour was characterized in order to identify the degradation due to the out-of-pile auto-irradiation.

2010-05-31

232

Study of Zircaloy-2 corrosion in high temperature water using ion beam methods  

Energy Technology Data Exchange (ETDEWEB)

Experiments have been carried out in water at 355 C to study transport of oxygen and hydrogen (as deuterium) in growing corrosion films. Composition of the films was also examined in 2.9 Mev and 3.9 Mev /alpha/-particle backscattering experiments. Corrosion occurs predominantly by oxygen diffusion through the film via grain boundary or similar short circuit diffusion paths, to form fresh oxide at the oxide metal interface. Increasing grain size within thick pre-breakaway films contributes to a decrease in diffusivity. The rate transition results from the generation of new diffusion pathways in previously protective oxide. Unexpectedly high concentrations of deuterium were observed. 26 refs.

1981-10-01

234

Plasma processing: a novel method to reduce the transient enhanced diffusion of boron implanted in silicon  

International Nuclear Information System (INIS)

In this paper a novel method is presented, based on the use of plasma processing, to suppress the transient enhanced diffusion of boron implanted in silicon. We found for silicon samples processed with plasma and subsequently boron implanted that the anomalous diffusion of the dopant atoms at the beginning of the annealing process is almost completely suppressed. This phenomenon is interpreted in terms of capture of the ion beam generated interstitials by the dislocations induced by the plasma processing. At room temperature the dislocations are observed to grow in size after the boron implant, attesting their efficiency as trapping centres for interstitials. Moreover, varying the plasma process conditions we can establish a general relation between the presence of the trapping centres induced by the plasma processing and the suppression of the transient diffusion.

1999-01-01

235

PIV measurements of flows around the wind turbines with a flanged-diffuser shroud  

British Library Electronic Table of Contents (United Kingdom)

The wind turbines with a flanged-diffuser shroud-so called ?wind lens turbine??-are developed as one of high performance wind turbines by Ohya et al. In order to investigate the flow characteristics and flow acceleration, the paper presents the flow velocity measurements of a long-type and a compact-type wind turbines with a flanged-diffuser shroud by particle image velocimetry. In the case of the long type wind turbine, the velocity vectors of the inner flow field of the diffuser for turbine blades rotating and no blades rotating are presented at Reynolds number, 0.9?105. Furthermore the flow fields between with and without rotating are compared. Through the PIV measurement results, one can realize that the turbine blades rotating affects as suppress the disturbance and the flow separatio...

2008-01-01

236

Nonlinear Wave and Diffusion Equations  

Science.gov (United States)

... A. Fasano, SD Howison. JR Ockendon & M. Primicerio. Some remarks on the regularisation of the supercooled one-phase Stefan problem. Quart. ...

1990-08-01

237

N95. 14209 - NASA Technical Report Server (NTRS)  

Science.gov (United States)

coupled heat/mass transfer Stefan problem. Taking the diffusion coefficient of Bi as a free parameter, the best fit was observed for the published value, ...

238

Manipulation of Nf-KappaB Activity in the Macrophage ...  

Science.gov (United States)

... as far as mammary development is concerned but carries the NF-κB reporter, there is diffuse NF-κB activity throughout the epithelial tissue that is ...

2008-05-01

239

Laboratory studies of the diffusive transport of 137Cs and 60Co through potential waste repository soils  

British Library Electronic Table of Contents (United Kingdom)

Tests using reconstituted samples have been performed to assess the diffusive transport of 137Cs and 60Co through natural regolith materials from a region in South Australia being considered for a radioactive waste repository. A double diffusion cell apparatus made of polycarbonate resin was developed to estimate the effective diffusion (De) and sorption coefficients (Kd) that allowed large withdrawals from the source and collector cells and has enabled tests with low concentrations of radioactivity. An alternative to porous stainless steel filter plates has also been used to reduce uncertainty in test interpretation. Analysis of the transient data used a staged method of the Laplace transform to take into consideration the volume of the samples withdrawn from the apparatus during testing....

2010-01-01

240

Future instrumentation for the study of the Warm-Hot Intergalactic Medium  

CERN Document Server

We briefly review capabilities and requirements for future instrumentation in UV- and X-ray astronomy that can contribute to advancing our understanding of the diffuse, highly ionised intergalactic medium.

2008-01-01

241

Filtered Density Function for Subgrid Scale Modeling of ...  

Science.gov (United States)

... Compilation Part Notice ADP023645 TITLE: Filtered Density Function for Subgrid Scale Modeling of Turbulent Diffusion Flames ...

2006-06-01

242

Factors influencing radon attenuation by tailing covers  

Energy Technology Data Exchange (ETDEWEB)

The US NRC, in its Generic Environmental Impact Statement on uranium milling has specified that the radon flux escaping a uranium mill tailings pile will be reduced to pCi/m/sup 2/ s by application of covering layers of soils and clays. These covers present a radon diffusion barrier, which sufficiently increases the time required for radon passage from the tailings to the atmosphere to allow for decay of /sup 222/Rn within the cover. The depth of cover necessary to reduce the escaping radon flux to the prescribed level is to be determined by calculation, and requires precise knowledge of the radon diffusion coefficient in the covering media. A Radon Attenuation Test Facility was developed to determine rates of radon diffusion through candidate cover materials. This paper describes this facility and its application for determining the influence of physical properties of the soil column on the radon ...

1981-07-01

243

Exact Simulation of Bessel Diffusions  

CERN Document Server

We consider the exact path sampling of the squared Bessel process and some other continuous-time Markov processes, such as the CIR model, constant elasticity of variance diffusion model, and hypergeometric diffusions, which can all be obtained from a squared Bessel process by using a change of variable, time and scale transformation, and/or change of measure. All these diffusions are broadly used in mathematical finance for modelling asset prices, market indices, and interest rates. We show how the probability distributions of a squared Bessel bridge and a squared Bessel process with or without absorption at zero are reduced to randomized gamma distributions. Moreover, for absorbing stochastic processes, we develop a new bridge sampling technique based on conditioning on the first hitting time at zero. Such an approach allows us to simplify simulation schemes. New methods are illustrated with pricing path-dependent options.

2009-01-01

244

Effect of recoil implantation of oxygen on boron enhanced diffusion in silicon  

International Nuclear Information System (INIS)

In device fabrication, dopants are frequently implanted into silicon through silicon dioxide masks. A consequence of this technique is the co-implantation of recoiled oxygen into the substrate. This study investigates the effect of recoiled oxygen on the widely observed transient enhanced boron diffusion. Comparison of the spreading resistance profiles of annealed through-oxide and directly implanted samples reveals that transient enhanced diffusion of boron can be suppressed by the former process. Continued annealing of the through-oxide implanted silicon recovers the enhanced diffusion of boron. This behavior is believed to be due to precipitation of recoiled oxygen. The mechanisms leading to the above observations are discussed and transmission electron microscopy support presented. 11 refs., 5 figs.

1989-04-25

245

Diffusion tensor MR imaging in pediatric patients with periventricular leukomalacia  

International Nuclear Information System (INIS)

Objective: To compare pediatric patients with periventricular leukomalacia (PVL) with normal children by using diffusion tensor MR imaging. Methods: Diffusion tensor images were obtained in 15 pediatric patients with PVL and 15 age-matched normal children. Regions of interest were drawn to measure the fractional anisotropy (FA) in bilateral posterior limb of internal capsule, bilateral optic radiation, genu of corpus callosum, and splenium of corpus callosum. The values of PVL patients and normal children were compared using non-dependent samples T-test. Results: The FA values of regions of interest prescribed were significantly lower in PVL patients than in normal children (P<0.01). Conclusion: Diffusion tensor imaging may reveal retard of myelination of fiber tracts in PVL patients. It can be a potential tool in evaluating the brain development of children. (authors)

2005-03-01

246

Development work currently being carried out on the time-dependent finite-element diffusion code TRANSFUSION for nuclear oil well logging problems  

Energy Technology Data Exchange (ETDEWEB)

The code is being developed starting from the steady-state finite element code FENDER for the solution of the diffusion equation by extending it to become time-dependent. The numerical solution of the time-dependent multigroup diffusion equations within TRANSFUSION is performed at the present stage of development by using a backward difference scheme for the time variable, leading to a rearrangement of FENDER by adding a new loop over time steps. The code retains the multigroup coupled neutron-gamma features of FENDER, and provides a consistent two-, and quasi three-dimensional numerical solution of both static and time-dependent multigroup diffusion equations. (orig./DG)

1993-04-01

247

Design and fabrication of a two dimensional valveless micropump  

Energy Technology Data Exchange (ETDEWEB)

The scale-down of a liquid mini-pump (order of 10 mm) to a micrometre scale has been attempted using a novel valveless nozzle-diffuser design and new application of an organic physical vapor-deposited membrane. The micropump employs no moving parts other than the membrane and accomplishes the rectification of fluid flow due to pressure recovery differences in the nozzle and diffuser flow directions. More specifically, liquids flow with less resistance (i.e. conduct more fluid) in the diffuser direction than the nozzle direction, for a given pressure differential. At the micrometre scale, the fabrication of the critical nozzle and diffuser elements was performed by focused ion beam (FIB) microlithography of glass slides. Etched slides were sandwiched to make two-dimensional venturis. Sternme and Sternme noted the importance of a lower Reynolds Number linfit on the desired pressure recovery which ...

1995-12-31

248

Degradation of a poly(ester urethane) elastomer. IV. Sorption and diffusion of water in PBX 9501 and its components  

British Library Electronic Table of Contents (United Kingdom)

In preparation for studying the hydrolytic degradation of Estane 5703 in the plastic-bonded explosive PBX 9501, the sorption (solubility) and diffusion of water in PBX 9501 and each of its components are studied experimentally and modeled theoretically. Experiments are reported that measure the weight gain or loss due to a change in the relative humidity (RH). For all of the components, the equilibrium amount of water sorbed per gram of sample is linear in the RH at low relative humidities but curves upwards at higher relative humidities. This behavior is modeled with a water cluster model. Diffusion coefficients are determined by modeling the time dependence of the water concentrations assuming Fickian diffusion, and that fits the data for some of the materials. However, all the samples t...

2007-01-01

249

Characteristics of compounds that cross the blood-brain barrier  

UK PubMed Central (United Kingdom)

Substances cross the blood-brain barrier (BBB) by a variety of mechanisms. These include transmembrane diffusion, saturable transporters, adsorptive endocytosis, and the extracellular pathways. Here,...Full Text Available

250

Boron-enhanced-diffusion of boron: The limiting factor for ultra-shallow junctions  

Energy Technology Data Exchange (ETDEWEB)

Reducing implant energy is an effective way to eliminate transient enhanced diffusion (TED) due to excess interstitials from the implant. It is shown that TED from a fixed Si dose implanted at energies from 0.5 to 20 keV into boron doping-superlattices decreases linearly with decreasing Si ion range, virtually disappearing at sub-keV energies. However, for sub-keV B implants diffusion remains enhanced and x{sub j} is limited to {ge} 100 nm at 1,050 C. The authors term this enhancement, which arises in the presence of B atomic concentrations at the surface of {approx} 6%, Boron-Enhanced-Diffusion (BED).

1997-12-01

251

Annealing of silicon implanted with arsine and hydrogen ions  

Energy Technology Data Exchange (ETDEWEB)

Arsenic and hydrogen ions produced from a mixture of arsine and hydrogen gas were implanted with a dose of 3 x 10{sup 15} As{sup +} ions/cm{sup 2} into silicon using an ion-shower implanter. The dominant ionic species implanted into the silicon were As{sub 2}H{sup +}, AsH{sup +}, H{sub 5}{sup +}, and H{sub 3}{sup +} ions. Arsenic atoms diffused into the silicon with large diffusion coefficients during annealing at 700 and 800 C. However, when the implanted silicon was annealed at 900 C, the arsenic atoms diffused into a deeper region in the silicon with a very small diffusion coefficient that was independent of concentration. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

2003-01-01

252

An anisotropic mesh adaptation method for the finite element solution of heterogeneous anisotropic diffusion problems  

CERN Document Server

Heterogeneous anisotropic diffusion problems arise in the various areas of science and engineering including plasma physics, petroleum engineering, and image processing. Standard numerical methods can produce spurious oscillations when they are used to solve those problems. A common approach to avoid this difficulty is to design a proper numerical scheme and/or a proper mesh so that the numerical solution validates the discrete counterpart (DMP) of the maximum principle satisfied by the continuous solution. A well known mesh condition for the DMP satisfaction by the linear finite element solution of isotropic diffusion problems is the non-obtuse angle condition that requires the dihedral angles of mesh elements to be non-obtuse. In this paper, a generalization of the condition, the so-called anisotropic non-obtuse angle condition, is developed for the finite element solution of heterogeneous anisotropic diffusion problems. ...

2010-01-01

253

Adsorption rate of phenol from aqueous solution onto organobentonite: Surface diffusion and kinetic models.  

Science.gov (United States)

The concentration decay curves for the adsorption of phenol on organobentonite were obtained in an agitated tank batch adsorber. The experimental adsorption rate data were interpreted with diffusional models as well as first-order, second-order and Langmuir kinetic models. The surface diffusion model adjusted the data quite well, revealing that the overall rate of adsorption was controlled by surface diffusion. Furthermore, the surface diffusion coefficient increased raising the mass of phenol adsorbed at equilibrium and was independent of the particle diameter in the range 0.042-0.0126cm. It was demonstrated that the overall rate of adsorption was essentially not affected by the external mass transfer. The second-order and the Langmuir kinetic models fitted the experimental data quite well; however, the kinetic constants of both models varied without any physical meaning while increasing the particle size and the mass of ...

2011-08-22

254

A gravitational diffusion model without dark matter  

UK PubMed Central (United Kingdom)

In this model, without dark matter, the flat rotation curves of galaxies and the mass-to-light ratios of clusters of galaxies are described quantitatively. The hypothesis is that the agent of gravitational...Full Text Available

1998-03-31

255

A diffusion criterion of the crystal-liquid phase transition  

Science.gov (United States)

A diffusion criterion of the crystal-liquid phase transition (PT) is proposed according to which the PT begins when the E d/ k b ratio reaches a threshold value of E d( s)/ k b T m, where E d is the self-diffusion energy, k B is the Boltzmann constant, T is the absolute temperature, and E d( s) is the self-diffusion energy in the solid phase at the melting temperature T m. It is shown that this criterion is a generalization of the Lindemann criterion and is applicable both to solids exhibiting normal melting and to those melting with a decrease in the specific volume. Based on the new criterion, it is possible to explain the relation T N < T m, where T N, is the crystallization onset temperature. The results of calculations of the T N/ T m ratio well coincide with experimental data.

2007-10-01

256

#left brace#311#right brace# Defects in ion-implanted silicon: The cause of transient diffusion, and a mechanism for dislocation formation  

International Nuclear Information System (INIS)

Ion implantation is used at several critical stages of Si integrated circuit manufacturing. The authors show how #left brace#311#right brace# defects arising after implantation are responsible for both enhanced dopant diffusion during annealing, and stable dislocations post-anneal. They observe #left brace#311#right brace# defects in the earliest stages of an anneal. They subsequently undergo rapid Ostwald ripening and evaporation. At low implant doses evaporation dominates, and they can quantitatively relate the interstitials emitted from these defects to the transient enhancement in diffusivity of dopants such as B and P. At higher doses Ostwald ripening is significant, and they observe the defects to undergo a series of unfaulting reactions to form both Frank loops and perfect dislocations. They demonstrate the ability to control both diffusion and dislocations by the addition of small amounts of carbon impurities.

1995-03-20

257

Waste acid recycling via diffusion dialysis  

Energy Technology Data Exchange (ETDEWEB)

Inorganic acids are commonly used for surface cleaning and finishing of metals. The acids become unuseable due to contamination with metals or diluted and weakened. Diffusion dialysis has become a way to recover the useable acid and allow separation of the metals for recovery and sale to refineries. This technique is made possible by the use of membranes that are strong enough to withstand low ph and have long service life.

1995-05-26

258

Use of ceramic porous membranes in molten carbonate fuel cells  

Energy Technology Data Exchange (ETDEWEB)

The diffusion of alkali vapours in the anode compartment of a DIR-MCFC produces the deactivation of the internal reforming catalyst. Sets of ceramic porous membranes purposed to limit the diffusion have been manufactured by different techniques and the influence of the preparation technique and of the preparative variables on the morphological characteristics of the membranes structures has been studied.

1996-12-31

259

Stein method for invariant measures of diffusions via Malliavin calculus  

CERN Document Server

Given a random variable $F$ regular enough in the sense of the Malliavin calculus, we are able to measure the distance between its law and almost any continuous probability law on the real line. The bounds are given in terms of the Malliavin derivative of $F$. Our approach is based on the theory of It\\^o diffusions and the stochastic calculus of variations. Several examples are considered in order to illustrate our general results.

2011-01-01

260

Spiral modes in the diffusion of a single granular particle on a vibrating surface  

International Nuclear Information System (INIS)

We consider a particle that is subject to a constant force and scatters inelastically on a vibrating periodically corrugated floor. At small friction and for small scatterers the dynamics is dominated by resonances forming spiral structures in phase space. These spiral modes lead to pronounced maxima and minima in the diffusion coefficient as a function of the vibration frequency, as is shown in computer simulations. Our theoretical predictions may be verified experimentally by studying transport of single granular particles on vibratory conveyors.

2004-11-29

261

Single photon emission computed tomography and its neurological application  

Energy Technology Data Exchange (ETDEWEB)

A review is made of the various brain imaging agents utilised in the post few years with their own characters and respective advantages: cerebral blood volume tracers, non diffusible tracers, diffusible tracers among which gases and lipophilic agents. Our results with IAMP and SPECT are presented in two different clinical application fields: normal pressure hydrocephalus and cerebral ischemia.

1984-12-01

262

Single photon emission computed tomography and its neurological application  

International Nuclear Information System (INIS)

A review is made of the various brain imaging agents utilised in the post few years with their own characters and respective advantages: cerebral blood volume tracers, non diffusible tracers, diffusible tracers among which gases and lipophilic agents. Our results with IAMP and SPECT are presented in two different clinical application fields: normal pressure hydrocephalus and cerebral ischemia.

263

Quantum theory of light interstitial diffusion and other aspects of inert gas motion in solids  

International Nuclear Information System (INIS)

Most diffusion phenomena in solids can be understood (or sometimes misunderstood) on a purely classical model. For light interstitials (hydrogen isotopes, the positive muon, and potentially He) there may be anomalous temperature dependences, and isotope effects, and anomalous response to electric fields and temperature gradients. Some of these anomalies are quantal in origin, and will be discussed. (author).

1980-03-01

264

Phase reactions in Ti(C,N)/(Ti,W)C, Ti(C,N)/(Ti,Mo)C, (Ti,W)(C,N)/Co and (Ti,W)(C,N)/Ni diffusion couples  

International Nuclear Information System (INIS)

In order to investigate interactions of (Ti,W)(C,N) and (Ti,Mo)(C,N) with binder metals solid/solid diffusion couples were annealed. These two-dimensional arrangements provide good access to phase reactions occurring upon sintering already in the solid state. It was found in (Ti,W)(C,N)/Co- and (Ti,W)(C,N)/Ni-based couples that the reaction zone is thinner in contact with Co than with Ni. It was also observed that the reaction rate with both Co and Ni is lower if nitrogen is added to the hard phases. Beside a thickness variation of the diffusion zones a change in the microstructure was found. At the interface of nitrogen-free hard phases in contact with Co elongated microstructural constituents are formed with the main axis perpendicular to the interface, while at the interface of nitrogen-containing hard phases these elongated microstructural constituents were found in contact with Ni. Also phase reactions and the ...

2001-05-01

265

Measurement of the Self-Diffusion Coefficient of Water as a Function of Position in Wheat Grain Using Nuclear Magnetic Resonance Imaging  

UK PubMed Central (United Kingdom)

A pulsed field gradient spin echo sequence has been incorporated in a nuclear magnetic resonance (NMR) imaging experiment to provide an image contrast dependent on local molecular self-diffusion. The...Full Text Available

1988-01-01

266

Marker studies of silicide formation, silicon self-diffusion and silicon epitaxy using radioactive silicon and Rutherford backscattering  

International Nuclear Information System (INIS)

Radioactive "3"1Si(Tsub(1/2) = 2.62 h) and Rutherford backscattering were used to study Ni_2Si, Pd_2Si and Pt_2Si formation, silicon self-diffusion in silicides and silicon epitaxy in the Si(100)/Pd_2Si/Si (amorphous) system. (Auth.).

267

Kinetic dialysis as a method for determining mixed micelle composition  

Energy Technology Data Exchange (ETDEWEB)

A new method for the determination of the cmc using a dialysis technique which allows monometric species to diffuse through but no micelles has been applied for determining the mixed micelle composition. The method is based on determining the amount of surfactant that diffuses through at two different times which allows for the calculation of the cmc by use of the appropriate equation. This method requires the preparation of only one concentration of solution and lends itself particularly well to the determination of the composition of mixed micelles. (orig.)

1982-02-16

268

Helicoidal instability of a scroll vortex in three-dimensional reaction-diffusion systems  

International Nuclear Information System (INIS)

We study the dynamics of scroll vortices in excitable reaction-diffusion systems analytically and numerically. We demonstrate that intrinsic three-dimensional instability of a straight scroll leads to the formation of helicoidal structures. This behavior originates from the competition between the scroll curvature and unstable core dynamics. We show that the obtained instability persists even beyond the meander core instability of the two-dimensional spiral wave. copyright 1998 The American Physical Society.

1998-10-01

269

Gas diffusion electrodes for the oxidation of sulfur dioxide in the presence of potassium iodide. [In hydrogen production by electrolysis of sulfuric acid solutions  

Energy Technology Data Exchange (ETDEWEB)

The oxidation of sulfur dioxide in gas diffusion electrodes (GDE) in the presence of a homogeneous catalyst, potassium iodide, is investigated. The influence of this catalyst on the voltage-current (V-I) characteristics of the electrodes and the utilization of sulfur dioxide is determined. It is shown that when using the homogeneous catalyst potassium iodide, the utilization can reach 95-100%.

1986-01-01

270

Diffusion and adsorption of methane confined in nanoporous carbon aerogel: a combined quasi-elastic and small-angle neutron scattering study  

Energy Technology Data Exchange (ETDEWEB)

The diffusion of methane confined in nano-porous carbon aerogel with the average pore size 48 {angstrom} and porosity 60% was investigated as a function of pressure at T = 298 K using quasi-elastic neutron scattering (QENS). The diffusivity of methane shows a clear effect of confinement: it is about two orders of magnitude lower than in bulk at the same thermodynamic conditions and is close to the diffusivity of liquid methane at 100 K (i.e. {approx} 90 K below the liquid-gas critical temperature T{sub C} {approx} 191 K). The diffusion coefficient (D) of methane initially increases with pressure by a factor of {approx}2.5 from 3.47 {+-} 0.41 x 10{sup -10} m{sup 2} s{sup -1} at 0.482 MPa to D = 8.55 {+-} 0.33 x 10{sup -10} m{sup 2} s{sup -1} at 2.75 MPa and starts to decrease at higher pressures. An explanation of the observed non-monotonic behavior of the diffusivity in the confined ...

2010-04-01

271

Continuous flow dielectrophoretic particle concentrator  

Energy Technology Data Exchange (ETDEWEB)

A continuous-flow filter/concentrator for separating and/or concentrating particles in a fluid is disclosed. The filter is a three-port device an inlet port, an filter port and a concentrate port. The filter separates particles into two streams by the ratio of their dielectrophoretic mobility to their electrokinetic, advective, or diffusive mobility if the dominant transport mechanism is electrokinesis, advection, or diffusion, respectively.Also disclosed is a device for separating and/or concentrating particles by dielectrophoretic trapping of the particles.

2007-04-17

272

Complex fractal dimensions describe the hierarchical structure of diffusion-limited-aggregate clusters  

Energy Technology Data Exchange (ETDEWEB)

We analyze large diffusion-limited aggregates and uncover a {ital discrete} scaling invariance in their inner structure, which can be quantified by the introduction of a set of {ital complex} fractal dimensions. We provide a theoretical framework and prediction of their values based on renormalization group theory and a previous wavelet analysis. {copyright} {ital 1996 The American Physical Society.}

1996-01-01

273

Attractors for nonlinear reaction-diffusion systems in unbounded domains via the method of short trajectories  

CERN Document Server

We consider a nonlinear reaction-diffusion equation settled on the whole euclidean space. We prove the well-posedness of the corresponding Cauchy problem in a general functional setting, namely, when the initial datum is uniformly locally bounded in L^2. Then we adapt the short trajectory method to establish the existence of the global attractor and, if the space dimension is at most 3, we also find an upper bound of its Kolmogorov's entropy.

2009-01-01

274

A numerical method for determining radon diffusion coefficient through buffer materials from low-level radwaste disposal site  

Energy Technology Data Exchange (ETDEWEB)

The diffusion coefficient of radioactive radon (Rn) through buffer materials from low-level radwaste disposal site was determined in this present study by measuring the time-dependent diffusion of radon through a thin slab of the material. The diffusion process was required to reach a steady state so as to obtain a good estimate of the diffusion coefficient. A numerical method using the nonlinear least-squares and Marquardt`s method (NLSM method) was proposed for characterizing the diffusion coefficient of Rn so as to determine whether the process has reached steady-state or not. Natural mordenite, a potential buffer material of LLW disposal facility, was selected as testing porous material. The NLSM method was shown by the results to be able to estimate the diffusion coefficient even if the process was in transient period. Additionally, this method was also ...

1994-12-31

275

{ital Ab Initio} Pseudopotential calculations of dopant diffusion in Si  

Energy Technology Data Exchange (ETDEWEB)

The ab initio pseudopotential method is used to study transient-enhanced-diffusion (TED) related processes. The electronic degrees of freedom are included explicitly, together with the fully self-consistent treatment of the electron charge density. A large supercell and a fine k-point mesh are used to ensure numerical convergence. Such method has been demonstrated to give quantitative description of defect energetic. We will show that boron diffusion is significantly enhanced in the presence of the Si interstitial due to the substantial lowering of the migrational barrier through a kick-out mechanism. The resulting mobile boron can also be trapped by another substitutional boron, forming an immobile and elect rically inactive two-boron pair. Similarly, carbon diffusion is also enhanced significantly due to the pairing with Si interstitial. However, carbon binds to Si interstitial much more strongly than boron does, taking ...

1997-04-28

276

Transient enhanced diffusion of Sb and B due to MeV silicon implants  

Energy Technology Data Exchange (ETDEWEB)

We measure the transient enhanced diffusion of shallow molecular-beam-epitaxy grown marker layers of Sb and B due to deep MeV Si{sup +} ion implants at very high doses ({approx}10{sup 16}cm{sup {minus}2}). We expect the near-surface region of these implants to be vacancy rich, and we observe transient enhanced diffusion of Sb (the classic vacancy diffuser). The large enhancements imply a significant vacancy supersaturation ({approx}700 at 740{degree}C). Double implantation of the high-dose MeV Si followed by a shallow (40 keV) Si implant and annealing produces a greatly reduced number of {l_brace}311{r_brace} defects compared to a 40 keV implant into virgin Si, again consistent with a vacancy-rich region in the near-surface region of an MeV implant. However, the shallow B marker layers also show transient enhanced diffusion for the same MeV implant under similar annealing conditions, implying that an ...

1997-06-01

277

Transient enhanced diffusion of Sb and B due to MeV silicon implants  

International Nuclear Information System (INIS)

We measure the transient enhanced diffusion of shallow molecular-beam-epitaxy grown marker layers of Sb and B due to deep MeV Si"+ ion implants at very high doses (#approx#10"1"6cm"-"2). We expect the near-surface region of these implants to be vacancy rich, and we observe transient enhanced diffusion of Sb (the classic vacancy diffuser). The large enhancements imply a significant vacancy supersaturation (#approx#700 at 740 degree C). Double implantation of the high-dose MeV Si followed by a shallow (40 keV) Si implant and annealing produces a greatly reduced number of #left brace#311#right brace# defects compared to a 40 keV implant into virgin Si, again consistent with a vacancy-rich region in the near-surface region of an MeV implant. However, the shallow B marker layers also show transient enhanced diffusion for the same MeV implant under similar annealing conditions, implying that an interstitial ...

278

Transient enhanced diffusion in ion-implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

We discuss the transient-enhanced diffusion of Sb, As, P, In, Ga, and B in ion-implanted Si, where the near-surface region has been amorphized by the dopant or by a self-implantation process. With Sb, a large transient diffusion enhancement is observed proportional to dopant concentration. For Sb, As, P, and In, the enhancement follows the relative interstitialcy diffusion coefficient. We believe this behavior is caused by stable implantation-induced point defects present in the amorphous surface layer, which decay during thermal processing to release high concentrations of self-interstitials. This process occurs in competition with the solid phase epitaxial (SPE) growth process, and for high dopant concentrations can occur in the amorphous phase ahead of the crystallization front. We believe this may be the origin of the dopant redistribution which can occur during SPE growth, which sets the upper limit to the dopant ...

1987-03-01

279

Thermal diffusivity measurements of irradiated UO_2 pellets  

International Nuclear Information System (INIS)

Thermal diffusivity was measured with a laser flash method up to 2000 K for UO_2 pellets irradiated in a commercial reactor. Measurements were done on micro samples of disks (2 mm diameter) or regular prisms (1.5 or 2 mm square cross sections). Thermal diffusivity degraded on extending burnup in agreement with reported values for UO_2 irradiated in test reactors, and it showed hysteresis during the laser flash experiments. Thermal diffusivity began to recover above 750 K and almost completely recovered above 1400 K, which corresponded with the reported radiation damage recovery. The obtained data were in agreement with predictions applying the thermal conductivity expression for irradiated UO_2 proposed by Amaya and Hirai. The sample experiencing power ramp showed higher thermal diffusivity than that of the base irradiated sample and had no obvious hysteresis. This suggested that the radiation damage ...

1998-08-01

280

The interstitial fraction of diffusivity of common dopants in Si  

Energy Technology Data Exchange (ETDEWEB)

The relative contributions of interstitials and vacancies to diffusion of a dopant A in silicon are specified by the interstitial fraction of diffusivity, f{sub A}. Accurate knowledge of f{sub A} is required for predictive simulations of Si processing during which the point defect population is perturbed, such as transient enhanced diffusion. While experimental determination of f{sub A} is traditionally based on an underdetermined system of equations, we show here that it is actually possible to derive expressions that give meaningful bounds on f{sub A} without any further assumptions but that of local equilibrium. By employing a pair of dopants under the same point-defect perturbance, and by utilizing perturbances very far from equilibrium, we obtain experimentally f{sub Sb}{le}0.012 and f{sub B}{ge}0.98 at temperatures of {approximately}800{degree}C, which are the strictest bounds reported to date. Our results are in ...

1997-12-01

281

The interstitial fraction of diffusivity of common dopants in Si  

International Nuclear Information System (INIS)

The relative contributions of interstitials and vacancies to diffusion of a dopant A in silicon are specified by the interstitial fraction of diffusivity, f_A. Accurate knowledge of f_A is required for predictive simulations of Si processing during which the point defect population is perturbed, such as transient enhanced diffusion. While experimental determination of f_A is traditionally based on an underdetermined system of equations, we show here that it is actually possible to derive expressions that give meaningful bounds on f_A without any further assumptions but that of local equilibrium. By employing a pair of dopants under the same point-defect perturbance, and by utilizing perturbances very far from equilibrium, we obtain experimentally f_S_b#<=#0.012 and f_B#>=#0.98 at temperatures of #approx#800 degree C, which are the strictest bounds reported to date. Our results are in agreement with a theoretical ...

282

Technological diffusion in industry: research needs and shortcomings. [Literature review for last 20 to 25 years  

Energy Technology Data Exchange (ETDEWEB)

Advances in technology are widely regarded as major sources of improvements in the competitive positions of firms and industries as well as of increases in national economic growth rates and standards of living. Because the benefits of such advances obviously depend on the extent to which they are utilized, considerable research has been focused on the diffusion of technological innovations. Most of these studies have sought to measure the dimensions of technological diffusion and to explain differences in diffusion patterns among innovations, industries, and nations as well as changes in such patterns over time. However, the most valuable contributions made so far have been to reveal the need for more-penetrating concepts, better measures, more-comprehensive analytical frameworks, and wider samplings of the variegated phenomena to be encompassed. Shortcomings in the theoretical work have seldom been directly harmful to ...

1981-03-01

283

Second law analysis of compressible flow through a diffuser subjected to constant heat flux at wall  

International Nuclear Information System (INIS)

Entropy generation is equivalent to destruction of available work (exergy). The useful energy is destroyed due to the intrinsic irreversibility associated within thermodynamic systems. Exergy analysis can be used as an effective basis for the development and improvement of systems design not only in the overall perspective but also in the individual component level. Second law analysis provides a useful tool to identify the irreversibility in any thermal system. This study presents the investigation of local and total entropy generation in compressible flow through a diffuser. Air is used as the fluid. Uniform heat flux boundary condition is applied at the wall. Two dimensional solution of velocity and temperature fields are obtained using the CFD code FLUENT. Distribution of entropy generation rate is investigated throughout the volume of the fluid as it flows through the diffuser. Regions of high entropy generation in the ...

2010-12-01

284

Research by ESS Division for the Nevada Nuclear Waste Storage Investigations: Progress report, January-June 1985  

Energy Technology Data Exchange (ETDEWEB)

Petrographic research for the Nevada Nuclear Waste Storage Investigations focused on xenolithic variability in the Topopah Spring Member and on variations of clinoptilolite composition at Yucca Mountain. Zeolite and smectite occurrences were considered in terms of their relation to a disturbed zone beneath the potential repository, and mineral stability experiments have produced a new clinoptilolite structure as a result of prolonged heating at low temperature. Limitations were defined on the abundance of erionite and of sulfur. X-ray diffraction studies lead to improved analytical methods. Progress was made in the comparative study of mineralogy in sand ramps and in faults. Geological modeling considered the differences of the diffusion of nonsorbing tracers in vertically and in horizontally fractured rock. Modeling also treated the diffusion of a nonsorbing tracer in devitrified and in zeolitized rock. The results of these experiments in all ...

1987-10-01

285

Procedures and interpretation of oxygen diffusion and burn up trials in the laboratory and in situ; Procedures et interpretation des essais de diffusion et de consommation d'oxygene en laboratoire et in situ  

Energy Technology Data Exchange (ETDEWEB)

The development of soil cover with capillary effect required laboratory experiments where diffusion was studied. The effective diffusion coefficients D of materials in the different layers were determined, as well as the reaction constants of reactive materials. Once soil cover is in place, its efficiency can be controlled by oxygen burn up trials in situ. In the specific case where the materials that comprise the soil cover consume oxygen, even in small quantities, the usual interpretation of these trials is not applicable. In this poster presentation, the authors proposed different procedures for long term trials, in situ and in the laboratory, as well as a new interpretation method based on the use of numerical solutions to the modified Fick equations of diffusion for reactive materials. Special emphasis is placed on the proper enunciation of the laws and the solutions appropriate in such situations. The authors ...

2000-07-01

286

PDE-based Non-Linear Diffusion Techniques for Denoising Scientific and Industrial Images: An Empirical Study  

Energy Technology Data Exchange (ETDEWEB)

Removing noise from data is often the first step in data analysis. Denoising techniques should not only reduce the noise, but do so without blurring or changing the location of the edges. Many approaches have been proposed to accomplish this; in this paper, they focus on one such approach, namely the use of non-linear diffusion operators. This approach has been studied extensively from a theoretical viewpoint ever since the 1987 work of Perona and Malik showed that non-linear filters outperformed the more traditional linear Canny edge detector. They complement this theoretical work by investigating the performance of several isotropic diffusion operators on test images from scientific domains. They explore the effects of various parameters such as the choice of diffusivity function, explicit and implicit methods for the discretization of the PDE, and approaches for the spatial discretization of the non-linear operator etc. ...

2001-12-20

287

Observation of the Far-ultraviolet Continuum Background with SPEAR/FIMS  

CERN Document Server

We present the general properties of the far-ultraviolet (FUV; 1370-1720A) continuum background over most of the sky, obtained with the Spectroscopy of Plasma Evolution from Astrophysical Radiation instrument (SPEAR, also known as FIMS), flown aboard the STSAT-1 satellite mission. We find that the diffuse FUV continuum intensity is well correlated with N_{HI}, 100 $\\mu$m, and H-alpha intensities but anti-correlated with soft X-ray. The strongest correlation is with the H-alpha emission, and the correlation of the diffuse background with the direct stellar flux is weaker than the correlation with other parameters. The continuum spectra are relatively flat. However, a weak softening of the FUV spectra toward some sight lines, mostly at high Galactic latitudes, is found not only in direct-stellar but also in diffuse background spectra. The diffuse background is relatively softer that the direct stellar ...

2010-01-01

288

New insight on the interaction and diffusion properties of ion beam injected self-interstitials in crystalline silicon  

Energy Technology Data Exchange (ETDEWEB)

The diffusion of ion beam injected self-interstitials (I) and their interaction with impurities in crystalline Si has been investigated and modeled. In particular, the I-substitutional carbon (C) interactions have been studied, using a molecular-beam-epitaxy grown Si{sub 1-y}C{sub y} layer interposed between the shallow I-source and a deeper B-spike (marker for I-concentration). Substitutional C atoms are shown to trap I's, to be removed from their substitutional sites, and to form stable precipitates into the C-rich region. The I-trapping mechanism was quantitatively studied by a simulation code. The reactions causing trapping and deactivation are described. In addition, the boron markers approach was extended to the two dimensional (2D) diffusion. High resolution scanning capacitance microscopy was used for quantitative measurements of the 2D boron transient enhanced diffusion induced on a boron delta array by ...

2003-05-01

289

New insight on the interaction and diffusion properties of ion beam injected self-interstitials in crystalline silicon  

International Nuclear Information System (INIS)

The diffusion of ion beam injected self-interstitials (I) and their interaction with impurities in crystalline Si has been investigated and modeled. In particular, the I-substitutional carbon (C) interactions have been studied, using a molecular-beam-epitaxy grown Si_1_-_yC_y layer interposed between the shallow I-source and a deeper B-spike (marker for I-concentration). Substitutional C atoms are shown to trap I's, to be removed from their substitutional sites, and to form stable precipitates into the C-rich region. The I-trapping mechanism was quantitatively studied by a simulation code. The reactions causing trapping and deactivation are described. In addition, the boron markers approach was extended to the two dimensional (2D) diffusion. High resolution scanning capacitance microscopy was used for quantitative measurements of the 2D boron transient enhanced diffusion induced on a boron delta array by the I's ion beam ...

2003-05-01

290

Mound Facility activities in chemical and physical research: July--December 1977. [Kr-Xe and Kr-Ar diffusion; Ne-Ar thermal diffusion  

Science.gov (United States)

Isotope separation of Ar, C, /sup 3/He, Kr, Ne, O, and Xe isotopes is reported. TiFeH/sub x/, TiCoH/sub x/, TiCuH/sub x/, and VH/sub x/ were studied using NMR (proton relaxation times). VD/sub x/ and VT/sub x/ were synthesized. The problem of calculating the valence state of Pu is discussed. A series solution to the plutonium (N,H) characteristic equation is suggested. Shipments of /sup 231/Pa, /sup 230/Th, and /sup 229/Th are reported. Separation and processing of /sup 234/U are also reported. Theoretical methods were developed to calculate temperature distributions as functions of water flow rate in liquid thermal diffusion columns. Diffusion coefficients were measured from 300 to 1200/sup 0/K for Kr-Xe and Kr-Ar. New thermal diffusion factors are submitted for Ne-Ar.

1978-05-01

291

Modelling the effects of a radiation induced polymer impregnation on the moisture of wood-polymer composites  

Energy Technology Data Exchange (ETDEWEB)

The adverse effect of moisture diffusion on the properties of wood has been one of the main weaknesses of wood. Using a gamma irradiation method, wood-polymer composites have been produced which exhibit significant improvement in mechanical properties like compression, creep deformation and creep rupture particularly at high humidity. It has been thought that the impregnation of polymer into the wood has affected the moisture diffusion in the wood, so that its adverse effects on the mechanical properties has been reduced. In this report the apparent diffusion coefficients of a Ramin wood impregnated with varying amounts of polymethyl methacrylate (PMMA) were determined using a Fick's law approach. An initial linear relationship was found for impregnation of up to 70% PMMA, after which the diffusion coefficient levels off to a maximum value, for the three environmental relative humidity levels ...

1989-01-01

292

Modelling the effects of a radiation induced polymer impregnation on the moisture of wood-polymer composites  

International Nuclear Information System (INIS)

The adverse effect of moisture diffusion on the properties of wood has been one of the main weaknesses of wood. Using a gamma irradiation method, wood-polymer composites have been produced which exhibit significant improvement in mechanical properties like compression, creep deformation and creep rupture particularly at high humidity. It has been thought that the impregnation of polymer into the wood has affected the moisture diffusion in the wood, so that its adverse effects on the mechanical properties has been reduced. In this report the apparent diffusion coefficients of a Ramin wood impregnated with varying amounts of polymethyl methacrylate (PMMA) were determined using a Fick's law approach. An initial linear relationship was found for impregnation of up to 70% PMMA, after which the diffusion coefficient levels off to a maximum value, for the three environmental relative humidity levels of 40, 60 ...

1989-01-01

293

Matrix diffusion studies by electrical conductivity methods. Comparison between laboratory and in-situ measurements  

Energy Technology Data Exchange (ETDEWEB)

Traditional laboratory diffusion experiments in rock material are time consuming, and quite small samples are generally used. Electrical conductivity measurements, on the other hand, provide a fast means for examining transport properties in rock and allow measurements on larger samples as well. Laboratory measurements using electrical conductivity give results that compare well to those from traditional diffusion experiments. The measurement of the electrical resistivity in the rock surrounding a borehole is a standard method for the detection of water conducting fractures. If these data could be correlated to matrix diffusion properties, in-situ diffusion data from large areas could be obtained. This would be valuable because it would make it possible to obtain data very early in future investigations of potentially suitable sites for a repository. This study compares laboratory electrical ...

1998-09-01

294

Investigation on boron transient enhanced diffusion induced by the advanced P{sup +}/N ultra-shallow junction fabrication processes  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P{sup +}/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B{sup +} and BF{sub 2}{sup +} ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF{sub 3} as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical ...

2005-08-01

295

Investigation on boron transient enhanced diffusion induced by the advanced P"+/N ultra-shallow junction fabrication processes  

International Nuclear Information System (INIS)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P"+/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B"+ and BF_2"+ ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF_3 as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical insights explaining the ...

2005-08-01

296

Grain-boundary self-diffusion of alloy 800 and influence of S, P and C on grain-boundary diffusion and creep cavity formation in alloy 800  

Energy Technology Data Exchange (ETDEWEB)

Alloy 800 is an austenitic Fe-Ni-Cr steel containing relatively minor but important amounts of carbon, aluminium and titanium. Special grades of alloy 800 known as 800H, 800HT and 800LC differ in the concentrations of these elements. In addition to these industrial specifications, further melts were prepared containing phosphorous or sulphur. Using a radioactive tracer method the bulk and grain-boundary diffusion of {sup 59}Fe was investigated in these alloys in the temperature range 800 to 1000 C. For evaluation of the diffusion profiles the approximation of Suzuoka was used, which considers the depletion of the tracer on the surface. By autoradiography it was confirmed that such depletion occurs. In alloy 800H the activation energy of grain-boundary diffusion of {sup 59}Fe was found to be (209{+-}17) kJ/mol; dissolved elements, especially phosphorous, increase the activation energy. The same materials - aged at 800 C for ...

1999-10-01

297

Grain-boundary self-diffusion of alloy 800 and influence of S, P and C on grain-boundary diffusion and creep cavity formation in alloy 800  

International Nuclear Information System (INIS)

Alloy 800 is an austenitic Fe-Ni-Cr steel containing relatively minor but important amounts of carbon, aluminium and titanium. Special grades of alloy 800 known as 800H, 800HT and 800LC differ in the concentrations of these elements. In addition to these industrial specifications, further melts were prepared containing phosphorous or sulphur. Using a radioactive tracer method the bulk and grain-boundary diffusion of "5"9Fe was investigated in these alloys in the temperature range 800 to 1000 C. For evaluation of the diffusion profiles the approximation of Suzuoka was used, which considers the depletion of the tracer on the surface. By autoradiography it was confirmed that such depletion occurs. In alloy 800H the activation energy of grain-boundary diffusion of "5"9Fe was found to be (209#+-#17) kJ/mol; dissolved elements, especially phosphorous, increase the activation energy. The same materials - aged at 800 C for 100 h - ...

298

Grain boundary self-diffusion of alloy 800 as affected by sulphur, phosphorous and carbon  

Energy Technology Data Exchange (ETDEWEB)

Using a radioactive tracer method the bulk and grain boundary diffusion of {sup 59}Fe was determined in industrial alloy 800 and melts of alloy 800 with additional P and S in the temperature range 800 to 1000 C. The use of the approximation of Suzuoka was confirmed by autoradiographs. In alloy 800 H the activation energy of grain boundary diffusion of {sup 59}Fe is (209 {+-} 17)kJ/mol. Dissolved elements especially P increase the activation energy of the grain boundary diffusion of Fe by their segregation to the grain boundaries. In addition the influence of the grain boundary diffusion on the growth of creep cavities was investigated in the same materials, and the chemical composition of the creep cavities and grain boundaries were analysed by Auger electron spectroscopy (AES). For alloy 800 + 0.088 wt-%P an enrichment of about 14 at-%P was observed at the grain boundaries. The addition of P clearly ...

1999-08-01

299

Grain boundary self-diffusion of alloy 800 as affected by sulphur, phosphorous and carbon  

International Nuclear Information System (INIS)

Using a radioactive tracer method the bulk and grain boundary diffusion of "5"9Fe was determined in industrial alloy 800 and melts of alloy 800 with additional P and S in the temperature range 800 to 1000 C. The use of the approximation of Suzuoka was confirmed by autoradiographs. In alloy 800 H the activation energy of grain boundary diffusion of "5"9Fe is (209 #+-# 17)kJ/mol. Dissolved elements especially P increase the activation energy of the grain boundary diffusion of Fe by their segregation to the grain boundaries. In addition the influence of the grain boundary diffusion on the growth of creep cavities was investigated in the same materials, and the chemical composition of the creep cavities and grain boundaries were analysed by Auger electron spectroscopy (AES). For alloy 800 + 0.088 wt-%P an enrichment of about 14 at-%P was observed at the grain boundaries. The addition of P clearly enhances ...

1998-07-06

300

Effects of moisture on radon emanation including the effects on diffusion. Open file report oct 79-Nov 81  

Energy Technology Data Exchange (ETDEWEB)

Radon emanation coefficients of 0.02 to 0.55 were measured at moisture contents ranging from dry to saturation in 18 different ores. The emanation coefficients rose from a minimum when dry to a plateau usually starting at 5 to 20 percent of saturation. A model, using measured pore-size distributions, suggested that the radium mineralization may be confined to annular layers about 0.02 micrometers thick around pores. Radon's diffusion coefficient was determined as a function of moisture. The techniques involved comparing a disk's exhalation as a function of time whether or not the disk had a distributed source. The model was free of approximations and included the effects of porosity and adsorption. An increase of diffusion coefficient with moisture for one or two ores was explained in terms of a model's equation for the diffusion coefficient in terms of both volume and surface ...

1981-11-01

301

Double-diffusive convection in a Darcy porous medium saturated with a couple-stress fluid  

Energy Technology Data Exchange (ETDEWEB)

The onset of double-diffusive convection in a couple-stress fluid-saturated horizontal porous layer is studied using linear and weak nonlinear stability analyses. The modified Darcy equation that includes the time derivative term and the inertia term is used to model the momentum equation. The expressions for stationary, oscillatory and finite-amplitude Rayleigh number are obtained as a function of the governing parameters. The effect of couple-stress parameter, solute Rayleigh number, Vadasz number and diffusivity ratio on stationary, oscillatory and finite-amplitude convection is shown graphically. It is found that the couple-stress parameter and the solute Rayleigh number have a stabilizing effect on stationary, oscillatory and finite-amplitude convection. The diffusivity ratio has a destabilizing effect in the case of stationary and finite-amplitude modes, with a dual effect in the case of oscillatory convection. The ...

2010-06-15

302

Double-diffusive convection in a Darcy porous medium saturated with a couple-stress fluid  

International Nuclear Information System (INIS)

The onset of double-diffusive convection in a couple-stress fluid-saturated horizontal porous layer is studied using linear and weak nonlinear stability analyses. The modified Darcy equation that includes the time derivative term and the inertia term is used to model the momentum equation. The expressions for stationary, oscillatory and finite-amplitude Rayleigh number are obtained as a function of the governing parameters. The effect of couple-stress parameter, solute Rayleigh number, Vadasz number and diffusivity ratio on stationary, oscillatory and finite-amplitude convection is shown graphically. It is found that the couple-stress parameter and the solute Rayleigh number have a stabilizing effect on stationary, oscillatory and finite-amplitude convection. The diffusivity ratio has a destabilizing effect in the case of stationary and finite-amplitude modes, with a dual effect in the case of oscillatory convection. The ...

2010-06-01

303

Diffusion simulations of boron implanted at low energy (500 eV) in crystalline silicon  

Energy Technology Data Exchange (ETDEWEB)

Several models have been proposed for the simulation of boron diffusion during annealing after implantation in silicon. It has been shown that transient enhanced diffusion (TED) tends to disappear at sub-keV implant energies. Under these conditions boron concentration is higher than the boron solubility limit value, precipitation phenomena occur. Extended defects ({l_brace}3 1 1{r_brace}, EOR) formation and boron precipitation affect both the redistribution during the annealing and activation of the boron. For these reasons, we have investigated the diffusion of low energy boron implanted in crystalline silicon and tested a complete simulation program which takes into account the effects of type I defects as a sink for self-interstitials and of boron precipitation. Experimental results have been simulated and consistent parameters have been found to fit the data. Boron enhanced diffusion effect has been ...

2004-02-01

304

Diffusion simulations of boron implanted at low energy (500 eV) in crystalline silicon  

International Nuclear Information System (INIS)

Several models have been proposed for the simulation of boron diffusion during annealing after implantation in silicon. It has been shown that transient enhanced diffusion (TED) tends to disappear at sub-keV implant energies. Under these conditions boron concentration is higher than the boron solubility limit value, precipitation phenomena occur. Extended defects (#left brace#3 1 1#right brace#, EOR) formation and boron precipitation affect both the redistribution during the annealing and activation of the boron. For these reasons, we have investigated the diffusion of low energy boron implanted in crystalline silicon and tested a complete simulation program which takes into account the effects of type I defects as a sink for self-interstitials and of boron precipitation. Experimental results have been simulated and consistent parameters have been found to fit the data. Boron enhanced diffusion effect ...

2004-02-01

305

Diffusion of linalool and methylchavicol from polyethylene-based antimicrobial packaging films  

British Library Electronic Table of Contents (United Kingdom)

The diffusion of linalool and methylchavicol from thin (45-50 mm) antimicrobial low-density polyethylene-based films was evaluated after immersion in isooctane and the effect of temperature (4, 10, or 25 degreeC) on the diffusion rate was evaluated. The kinetics of linalool and methylchavicol release showed a non-Fickian behavior at the lowest temperature. An increase in temperature from 4 degreeC to 25 degreeC resulted in an increase in the diffusion coefficient from 4.2 x 10-13 m2 s-1 to 2.5 x 10-12 m2 s-1 for linalool and from 3.5 x 10-13 m2 s-1 to 1.1 x 10-12 m2 s-1 for methylchavicol. The effect of temperature on the diffusion coefficient followed an Arrhenius-type model (r2 = 0.972) in relation to a time-response function with a Hill coefficient. Activation energies of 57.8 kJ mol-1 ...

2011-01-01

306

Cosmic-Ray Nuclei, Antiprotons and Gamma-rays in the Galaxy: a New Diffusion Model  

CERN Document Server

We model the transport of cosmic ray nuclei in the Galaxy by means of a new numerical code. Differently from previous numerical models we account for a generic spatial distribution of the diffusion coefficient. We found that in the case of radially uniform diffusion, the main secondary/primary ratios (B/C, N/O and sub-Fe/Fe) and the modulated antiproton spectrum match consistently the available observations. Convection and re-acceleration do not seem to be required in the energy range we consider: $1 \\le E \\le 10^3$ GeV/nucleon. We generalize these results accounting for radial dependence of the diffusion coefficient, which is assumed to trace that of supernova remnants. While this does not affect the prediction of secondary/primary ratios, the simulated longitude profile of the diffuse $\\gamma$-ray emission is significantly different from the uniform case and may agree with EGRET measurements ...

2008-01-01

307

Atomistic modeling of the effects of dose and implant temperature on dopant diffusion and amorphization in Si  

International Nuclear Information System (INIS)

We discuss atomistic simulations of ion implantation and annealing of Si over a wide range of ion dose and substrate temperatures. The DADOS Monte Carlo model has been extended to include the formation of amorphous regions, and this allows simulations of dopant diffusion at high doses. As the dose of ions increases, the amorphous regions formed by cascades eventually overlap, and a continuous amorphous layer is formed. In that case, most of the excess interstitials generated by the implantation are swept to the surface as the amorphous layer regrows, and do not diffuse in the crystalline region. This process reduces the amount of transient enhanced diffusion (TED) during annealing. This model also reproduces the dynamic annealing during high temperature implants. In this case, the local amorphous regions regrow as the implant proceeds, without the formation of a continuous amorphous layer. For sufficiently high ...

2001-06-01

308

Atomistic analysis of defect evolution and transient enhanced diffusion in silicon  

International Nuclear Information System (INIS)

Kinetic Monte Carlo simulations are used to analyze the ripening and dissolution of small Si interstitial clusters and #left brace#113#right brace# defects, and its influence on transient enhanced diffusion of dopants in silicon. The evolution of Si interstitial defects is studied in terms of the probabilities of emitted Si interstitials being recaptured by other defects or in turn being annihilated at the surface. These two probabilities are related to the average distance among defects and their distance to the surface, respectively. During the initial stages of the defect ripening, when the defect concentration is high enough and the distance among them is small, Si interstitials are mostly exchanged among defects with a minimal loss of them to the surface. Only when defects grow to large sizes and their concentration decreases, the loss of Si interstitials through diffusion to the surface prevails, causing their dissolution. The presence of ...

2003-07-15

309

A Plan to Diffuse Instructional Materials for Use by Transportation Educators.  

Science.gov (United States)

A plan to diffuse instructional modules for the preparation of transportation professionals is presented, based on research and demonstration projects sponsored by the Urban Mass Transportation Administration (UMTA). The diffusion/adoption plan involves: developing instructional modules; disseminating the modules to professors teaching transportation courses at the college level; promoting the use and adoption of the modules; and evaluating and revising the plan. Transportation educators teach in a variety of disciplines (e.g., engineering, public administration, urban planning, and technology). Eight design and evaluation criteria for the instructional modules are listed, along with the procedures used by West Virginia University in developing the five instructional modules. The diffusion strategy involves repackaging UMTA research findings, change agents, and the use of information channels (e.g, television/radio, ...

1986-01-01

310

Reduced boron diffusion under interstitial injection in fluorine implanted silicon  

International Nuclear Information System (INIS)

Point defect injection studies are performed to investigate how fluorine implantation influences the diffusion of boron marker layers in both the vacancy-rich and interstitial-rich regions of the fluorine damage profile. A 185 keV, 2.3x10"1"5 cm"-"2 F"+ implant is made into silicon samples containing multiple boron marker layers and rapid thermal annealing is performed at 1000 deg. C for times of 15-120 s. The boron and fluorine profiles are characterized by secondary ion mass spectroscopy and the defect structures by transmission electron microscopy (TEM). Fluorine implanted samples surprisingly show less boron diffusion under interstitial injection than those under inert anneal. This effect is particularly noticeable for boron marker layers located in the interstitial-rich region of the fluorine damage profile and for short anneal times (15 s). TEM images show a band of dislocation loops around the range of the fluorine implant and the ...

2007-12-01

311

Wind-induced contaminant transport in near-surface soils with application to radon entry into buildings  

Energy Technology Data Exchange (ETDEWEB)

Indoor air exposures to gaseous contaminants originating in soil can cause large human health risks. To predict and control these exposures, the mechanisms that affect vapor transport in near-surface soils need to be understood. In particular, radon exposure is a concern since average indoor radon concentrations lead to much higher risks than are generally accepted for exposure to other environmental contaminants. This dissertation examines an important component of the indoor radon problem: the impacts of wind on soil-gas and radon transport and entry into buildings. The research includes experimental and modeling studies of wind`s interactions with a building`s superstructure and the resulting soil-gas and radon flows in the surrounding soil. In addition to exploring the effects of steady winds, a novel modeling technique is developed to examine the impacts of fluctuating winds on soil-gas and radon transport.

1996-05-01

312

Wear resistant composite structure of vitreous carbon containing convoluted fibers  

Energy Technology Data Exchange (ETDEWEB)

Very good friction and wear measurements are reported for MRCC (metal reinforced carbon composites), made from low-wear non-graphitic carbon matrix with metal-fiber reinforcement. Counterfaces include austenitic and martensitic stainless steels, Si nitride, and alumina. Effects of high load, high temperature, and gaseous environments are reported: removal of humidity, atm. oxygen have little effect on friction, wear for MRCC sliding against ceramic or stainless steel. Wear of Al oxide riders on MRCC is very low, not affected by contact load. 260 C temperatures do not degrade performance of 440-C riders on MRCC disks or raise friction. In small or large sizes, MRCC is made in a single-pass process for about the same volume cost as cast iron. It can survive heating in nitrogen above 1600 C without loss of integrity or major change of dimensions.

1995-02-01

313

Use of primary electron counting for detection of ultrasoft x-rays with a low-pressure multistep gaseous detector  

International Nuclear Information System (INIS)

The use of primary electron counting techniques as an alternative to the more usual parallel plate avalanche chamber that has been employed in soft x-ray scattering experiments is being investigated at the National Synchrotron Light Source. The theoretical aspects of primary electron counting and motivation behind building a primary electron counting detector are described, as well as characteristics and future improvements of the device constructed at the NSLS. The detector consists of a low electric field drift region and a low pressure multistep avalanche region which can be operated with two or three stages of electron multiplication. The device has worked well in extensive tests as a simple parallel plate avalanche chamber, providing energy resolutions of 58% and 43% at 277 and 500 eV, respectively. Operated as a primary electron counter, preliminary results show an energy resolution of 38% at 500 eV.

314

UK Achievements in the application of power fluidic technology for nuclear processing plants  

International Nuclear Information System (INIS)

Power Fluidic systems for the control of liquids and gaseous flows have been adopted for use in radioactive processing plants in the UK. These devices are intrinsically reliable with no mechanical moving parts because they are able to make use of the hydrodynamics of the fluids being controlled. This reliability feature leads to a zero cell maintenance concept and the elimination of mechanical drive/control systems in cell. The first phase of the development work led to their use in the Fast Reactor Reprocessing Plant at Dounreay and the Highly Active Liquor Storage facility at Sellafield. The success of these early developments has led to an extensive development programme for an extended range of applications in the Thermal Oxide Reprocessing Plant and its associated waste treatment facilities at Sellafield. The technology has now been fully demonstrated and adopted for these plants with considerable benefit over a wide range of applications.

315

Tungsten coating on low activation vanadium alloy by plasma splay process  

International Nuclear Information System (INIS)

Tungsten (W) coating on fusion candidate V-4Cr-4Ti (NIFS-HEAT-2) substrate was demonstrated with plasma spray process for the purpose of applying to protection of the plasma facing surface of a fusion blanket. Increase in plasma input power and temperature of the substrate was effective to reduce porosity of the coating, but resulted in hardening of the substrate and degradation of impact property at 77 K. The hardening seemed to be due to contamination with gaseous impurities and deformation by thermal stress during the coating process. Since all the samples showed good ductility at room temperature, further heating seems to be acceptable for the vanadium substrate. The fracture stress of the W coating was estimated from bending tests as at least 313 MPa, which well exceeds the design stress for the vanadium structure in fusion blanket. (author)

2008-03-01

316

Theoretical search for optimal pump parameters for observing spontaneous radiation amplification on the {lambda}=41.8-nm transition of Xe IX in plasma  

Science.gov (United States)

Based on a collisional-radiative model, an atomic-kinetic calculation of the gains on the 41.8-nm transitions of Pd-like xenon was performed for the plasma produced due to the interaction of a femtosecond laser pulse with gaseous xenon. The gains g(z,{tau}) averaged over the spatial and temporal coordinates were compared with the known gains which had been measured experimentally in Xe{sup 8+}. The amplification was shown to occur under the conditions of ionisation of the working ions, and the time of output radiation saturation depends on the time of Xe{sup 8+} transformation to higher-ionised ions. Our theoretical investigation enables determining the optimal pump parameters, at which the product of the gain g by the active medium length L is about 20, which exceeds the experimental gL value. (active media)

2004-11-30

317

Theoretical search for optimal pump parameters for observing spontaneous radiation amplification on the ?=41.8-nm transition of Xe IX in plasma  

International Nuclear Information System (INIS)

Based on a collisional-radiative model, an atomic-kinetic calculation of the gains on the 41.8-nm transitions of Pd-like xenon was performed for the plasma produced due to the interaction of a femtosecond laser pulse with gaseous xenon. The gains g(z,?) averaged over the spatial and temporal coordinates were compared with the known gains which had been measured experimentally in Xe8+. The amplification was shown to occur under the conditions of ionisation of the working ions, and the time of output radiation saturation depends on the time of Xe8+ transformation to higher-ionised ions. Our theoretical investigation enables determining the optimal pump parameters, at which the product of the gain g by the active medium length L is about 20, which exceeds the experimental gL value. (active media)

2004-11-30

318

Survival of gas phase amino acids and nucleobases in space radiation conditions  

CERN Document Server

We present experimental studies on the photoionization and photodissociation processes (photodestruction) of gaseous amino acids and nucleobases in interstellar and interplanetary radiation conditions analogs. The measurements have been undertaken at the Brazilian Synchrotron Light Laboratory (LNLS), employing vacuum ultraviolet (VUV) and soft X-ray photons. The experimental set up basically consists of a time-of-flight mass spectrometer kept under high vacuum conditions. Mass spectra were obtained using photoelectron photoion coincidence technique. We have shown that the amino acids are effectively more destroyed (up to 70-80%) by the stellar radiation than the nucleobases, mainly in the VUV. Since polycyclic aromatic hydrocarbons have the same survival capability and seem to be ubiquitous in the ISM, it is not unreasonable to predict that nucleobases could survive in the interstellar medium and/or in comets, even as a stable cation.

2008-01-01

319

Study on low calorific gas combustion. Part 1  

Energy Technology Data Exchange (ETDEWEB)

Effects of combustion conditions on the critical calorific value of flame blowout were reported for low calorific gas on the assumption of using coal derived gaseous fuel. Further, calculations of adiabatic flame temperature by using chemical equilibrium calculation were conducted in order to get a possibility of increasing exit gas temperature of gas turbine combustor to 1,300 C for low calorific value gas fuel. As a result, effects of (1) fuel composition, (2) preheating fuel temperature, (3) calorific value, and (4) combustion air velocity and fuel nozzle diameter, on the critical calorific values of flame blowout were clarified. In increasing exit gas temperature of gas turbine combustor to 1,300 C when using low calorific value gas fuel, it is essential to get an advanced cooling technology for the gas turbine combustor.

1986-01-01

320

Pulsed laser deposition of titanium-carbonitride thin films  

Energy Technology Data Exchange (ETDEWEB)

The goal of this research program is to determine whether pulsed laser deposition is an effective alternative method for growing TiCN thin films. Pulsed laser deposition (PLD) is chosen because of its well-documented capability for growing uniform, stoichiometric films in ultra-high vacuum or gaseous environments. Processing of thin films by PLD is also achieved at relatively low temperatures compared with CVD processing. Given these attributes, the primary objectives in this article are to determine whether nitrogen may be readily incorporated into films resulting from the laser-ablation of TiC in an N{sub 2} environment, determine what effect nitrogen has on mechanical properties, and determine whether nitrogen incorporation is strongly influenced by processes unrelated to laser deposition (e.g., thermally-activated surface reactions).

1997-05-15

321

Palladium-catalyzed combustion of methane: Simulated gas turbine combustion at atmospheric pressure  

Energy Technology Data Exchange (ETDEWEB)

Atmospheric pressure tests were performed in which a palladium catalyst ignites and stabilizes the homogeneous combustion of methane. Palladium exhibited a reversible deactivation at temperatures above 750 C, which acted to ``self-regulate`` its operating temperature. A properly treated palladium catalyst could be employed to preheat a methane/air mixture to temperatures required for ignition of gaseous combustion (ca. 800 C) without itself being exposed to the mixture adiabatic flame temperature. The operating temperature of the palladium was found to be relatively insensitive to the methane fuel concentration or catalyst inlet temperature over a wide range of conditions. Thus, palladium is well suited for application in the ignition and stabilization of methane combustion.

1995-04-01

322

Non-oxidative removal of hydrogen sulfide from gaseous, petrochemical, and other streams  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a method of reducing the hydrogen sulfide level in streams containing hydrogen sulfide at concentrations from about 2 ppm up to about 1,000 ppm. It comprises reacting the hydrogen sulfide with an unsaturated hydrocarbon in the presence of an acidic solid catalyst selected from the group consisting of polymeric sulfonic acid resins, solid polyphosphoric acid, supported sulfuric acid, supported boric acid, silica-aluminas, clays, faujasite, mordenite, and L, omega, X or Y zeolites at mercaptan-forming concentrations, and recovering a stream having a reduced hydrogen sulfide concentration and containing no more than 5 ppm hydrogen sulfide.

1991-07-23

323

Models for the rate of benzene sulfonation in heterogeneous systems  

Science.gov (United States)

Macrokinetics of benzene sulfonation in liquid-liquid and gas-liquid systems has been studied in continuous mixed reactors. It has been shown that the rate of sulfonation of benzene at 25/sup 0/C in two liquid phases using concentrated sulfuric acid is kinetically controlled. Whereas the rate of the latter reaction by gaseous sulfur trioxide at the same temperature is largely affected by the diffusional phenomena. At this temperature, the rate of reaction in gas-liquid system was described by a model assuming a fast reaction in the liquid phase. However, by increasing the temperature, the fast reaction region gradually changed to instantaneous reaction regime. A model, describing such a regime has also been developed and verified experimentally.

1986-09-01

324

Investigation of mixed convection in a large rectangular enclosure  

Energy Technology Data Exchange (ETDEWEB)

This experimental research investigates mixed convection and heat transfer augmentation by gaseous forced jets in a large enclosure, at conditions simulating those of passive containment cooling systems for Gen III+ passively safe reactors. The experiment is designed to measure the key parameters governing heat transfer augmentation by forced jets, and to investigate the effects of geometric factors, including the jet diameter, jet injection orientation, interior structures, and enclosure aspect ratio. The tests cover a variety of injection modes leading to flow configurations of interest for mixing and stratification phenomena in containments under accident conditions. Correlations for heat transfer augmentation by forced jets are developed and compared with experimental data. The characteristic recirculation speed inside the enclosure is introduced and analyzed. Steady stratified temperature distributions are compared with model simulations of the BMIX++ code.

2007-05-15

325

Investigation of mixed convection in a large rectangular enclosure  

International Nuclear Information System (INIS)

This experimental research investigates mixed convection and heat transfer augmentation by gaseous forced jets in a large enclosure, at conditions simulating those of passive containment cooling systems for Gen III+ passively safe reactors. The experiment is designed to measure the key parameters governing heat transfer augmentation by forced jets, and to investigate the effects of geometric factors, including the jet diameter, jet injection orientation, interior structures, and enclosure aspect ratio. The tests cover a variety of injection modes leading to flow configurations of interest for mixing and stratification phenomena in containments under accident conditions. Correlations for heat transfer augmentation by forced jets are developed and compared with experimental data. The characteristic recirculation speed inside the enclosure is introduced and analyzed. Steady stratified temperature distributions are compared with model simulations of the BMIX++ code.

2007-05-01

326

Integrated coke, asphalt and jet fuel production process and apparatus  

Science.gov (United States)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

1991-01-01

327

Integrated Analysis of Environment-driven Operational Effects in Sensor Networks  

Energy Technology Data Exchange (ETDEWEB)

There is a rapidly growing need to evaluate sensor network functionality and performance in the context of the larger environment of infrastructure and applications in which the sensor network is organically embedded. This need, which is motivated by complex applications related to national security operations, leads to a paradigm fundamentally different from that of traditional data networks. In the sensor networks of interest to us, the network dynamics depend strongly on sensor activity, which in turn is triggered by events in the environment. Because the behavior of sensor networks is sensitive to these driving phenomena, the integrity of the sensed observations, measurements and resource usage by the network can widely vary. It is therefore imperative to accurately capture the environmental phenomena, and drive the simulation of the sensor network operation by accounting fully for the environment effects. In this paper, we illustrate the strong, intimate coupling between the ...

2007-07-01

328

Impact of the addition of chicken litter on mercury speciation and emissions from coal combustion in a laboratory-scale fluidized bed combustor  

Energy Technology Data Exchange (ETDEWEB)

Co-combustion of chicken litter with coal was performed in a laboratory-scale fluidized bed combustor to investigate the effect of chicken litter addition on the partitioning behavior of mercury. Gaseous total and elemental mercury concentrations in the flue gas were measured online, and ash was analyzed for particle-bound mercury along with other elemental and surface properties. The mercury mass balance was between 85 and 105%. The experimental results show that co-combustion of chicken litter decreases the amount of elemental and total mercury in the gas phase. Mercury content in fly ash increases with an increasing chicken litter share. 22 refs., 6 figs., 5 tabs.

2008-07-15

329

Hydrogen energy storage: hydrogen and oxygen storage subsystems  

Energy Technology Data Exchange (ETDEWEB)

Hydrogen seems to possess all the characteristics to store the excess of electrical energy produced during off-peak periods. Hydrogen energy storage plants could be environmentally non-polluting, easy to place, not sensible to load variation, unbounded in size, efficient and safe. These last two features seem to contradict one another. An option that could give a reliable solution is the storage of hydrogen in metal hydride and the storage of oxygen as a liquid. Such a choice is probably the safest one to make and allows the achievement of efficiencies comparable to those obtainable with gaseous storage of both electrolytic products. The power consumption for H{sub 2} and O{sub 2} storage is only 3% of the total energy stored and the charging ratio approaches the values obtained with hydro-pumped storage plants. (Author)

1997-12-31

330

High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, July 1, 1995--September 30, 1995  

Energy Technology Data Exchange (ETDEWEB)

Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam-cycle is the conventional conversion method; however total energy conversion efficiencies for this type of process are only slightly over 30%. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40%. Conversion processes based on gasification offer efficiencies above 50%. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. This process is concerned with the removal of H{sub 2} from coal gas through an electrochemical membrane technology.

1996-03-01

331

Greenhouse effect gas reduction in large industries. Approaches and solutions  

International Nuclear Information System (INIS)

Efforts in industry concerning pollution abatement up to nowadays were aimed at: solid particles contained in gaseous effluents, SO_2 effluent reduction, nitrogen oxide effluent limitation through combustion technology enhancement. Various CO_2 emission scenarios with different energy production means (same or increased nuclear plant number, energy consumption reduction) show that energy conservation schemes for the developed countries are the best solution to CO_2 control. Different solutions for greenhouse gas abatement from industrial plant are reviewed: effluent processing, burner technological enhancement, heat transfer optimization on industrial processes, computer assisted management for industrial processes, plasma technic for refining, substitution of gas to oil in chemistry, etc.

1991-01-01

332

Fingerprint testing of contaminated ventilation extract filter systems at Sizewell B  

International Nuclear Information System (INIS)

Sizewell B is Nuclear Electric's latest power station, and the Pressurised Water Reactor (PWR) design on which it is based represents a ''first'' for the UK. One of the integral components of the plant is the heating, ventilation and air-conditioning (HVAC) system, which performs a contamination control and gaseous waste management function for the site. During the commissioning of Sizewell B Power Station the extract systems of the HVAC plant underwent a procedure known as ''fingerprinting''. This entailed the characterisation of the facilities provided to test the filtration plant during its lifetime. The assessment of their adequacy was then used to identify necessary modifications and/or to propose the manner in which future in situ performance testing would be carried out. The paper outlines the basic principles and procedure that was used to ''fingerprint'' test systems during the commissioning of Sizewell B. A specific example is presented to demonstrate the ...

333

Experimental studies on fumigation of ethanol in a small capacity Diesel engine  

British Library Electronic Table of Contents (United Kingdom)

To diversify the mix of domestic energy resources and to reduce dependence on imported oil, ethanol is widely investigated for applying in combination with Diesel fuel to reduce pollutants, including smoke and NOx. Present work aims at developing a fumigation system for introduction of ethanol in a small capacity Diesel engine and to determine its effects on emission. Fumigation was achieved by using a constant volume carburetor. Different percentages of ethanol fumes with air were then introduced in the Diesel engine, under various load conditions. Ethanol is an oxygenated fuel and lead to smooth and efficient combustion. Atomization of ethanol also results in lower combustion temperature. During the present study, gaseous emission has been found to be decreasing with ethanol fumigation. ...

2011-01-01

334

Evaluation of the maximum horsepower of vehicles converted for use with natural gas fuel  

Energy Technology Data Exchange (ETDEWEB)

Tests to measure the maximum horsepower of commercial vehicles converted for use with natural gas fuel indicate a reduction of approximately 20% in horsepower compared with gasoline-driven vehicles. This reduction in horsepower resulting from the use of gas is due basically to the lower thermal efficiency of the cycle of natural gas compared with that of gasoline and to its lower volumetric efficiency, since natural gas is injected into the combustion chamber in gaseous form, unlike gasoline, in which part of the fuel entering the cylinder is in the liquid phase. Natural gas used as a fuel generates lower quantities of air pollutants, particularly unburned hydrocarbons (HCs) and carbon monoxide (CO). Despite the downside of reduced horsepower, the use of natural gas as a fuel for automotive vehicles equipped with Otto-cycle engines is economically viable owing to the wide availability of natural gas. 34 refs., 5 figs., 2 tabs.

2006-10-15

335

Effect of charge dilution on gaseous and particulate emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol and ethanol  

British Library Electronic Table of Contents (United Kingdom)

In this study, the effect of intake charge dilution with carbon dioxide on the combustion and emission characteristics of a 4-cylinder direct-injection diesel engine fueled with biodiesel, ethanol-biodiesel and methanol-biodiesel were investigated. With increase of intake CO"2 concentration, CO, HC, particulate mass concentration, particle number concentration and geometric diameter (GMD) of all fuels increased while NO"x decreased obviously. After addition of methanol and ethanol in biodiesel, the NO"x, particulate mass concentration and particle number concentration decreased at each intake CO"2 concentration, compared with biodiesel. Moreover, as the intake CO"2 concentration increased from 2% to 5.6%, particulate mass concentration of the alcohol-biodiesel blends remained almost unchan...

2011-01-01

336

Development of ambient sampling chemi/chemical ion source with dielectric barrier discharge  

British Library Electronic Table of Contents (United Kingdom)

The development of a new configuration of chemical ionization (CI)-based ion source is presented. The ambient air containing the gaseous sample is sniffed into an enclosed ionization chamber which is of sub-ambient pressure, and is subsequently mixed with metastable species in front of the ion inlet of the mass spectrometer. Metastable helium atoms (He*) are used in this study as the primary ionizing agents and are generated from a dielectric barrier discharge (DBD) source. The DBD is powered by an AC high-voltage supply and the configuration of the electrodes is in such a way that the generated plasma is confined within the discharge tube and is not extended into the ionization chamber. The construction of the ion source is simple, and volatile compounds released from the bulky sample can...

2010-01-01

337

Development of PC 4 dual-fuel engine  

Energy Technology Data Exchange (ETDEWEB)

Recently, utilization of natural gas, which is considered to be one of most important alternative fuels for petroleum, has been marked. As thermal efficiency of dual-fuel engine is higher than those of other prime movers with gaseous fuel, i.e., spark-ignited gas engine or gas turbine, it is possible to construct fuel-economical gas power plants with dual-fuel engines. However, its horsepower has been limited to the rather lower range. In 1984, NKK succeeded in developing large-sized dual-fuel engines based on the Pielstick PC4 diesel engine. The horsepower is 1200 HP/cyl, i.e. 21,600 HP for 18-cyclinder engine.

1985-01-01

338

Chemical and physical conversion in cold atmosphere and the effect of radiation  

Energy Technology Data Exchange (ETDEWEB)

The project is focusing on the formation and growth mechanisms of atmospheric aerosol and cloud droplets. Both aerosol particles and cloud droplets affect strongly on the atmospheric radiation fluxes by scattering and absorption. The droplet formation results from physical and chemical processes occurring simultaneously. The studies concerning the tropospheric cloud droplet formation, laboratory experiments with a cloud chamber and stratospheric cloud formation are summarized. The recent studies summarized in this presentation indicate that both aerosol particles and cloud droplets have a significant role in climatic change and ozone depletion problems. The anthropogenic emissions of gaseous and particulate pollutants change the properties of atmospheric aerosols and cloud droplets. The research in this field will be continued and more quantitative understanding based both experimental and theoretical studies is required

1996-12-31

339

Catalytic hydroliquefaction of biomass with red mud and CoO-MoO sub 3 catalysts  

Energy Technology Data Exchange (ETDEWEB)

Rye straw was completely hydroliquefied, using red mud or CoO-MoO{sub 3} as the catalyst. Red mud catalyst exhibited a satisfactory activity only in the presence of sulphur at {approx} 673 K. Depending on reaction conditions, different amounts of gaseous and liquid products were formed. Their product distributions were comparable to those obtained in hydroliquefaction of cellulose and lignin. All results could be described by a model which assumed that: pyrolysis precedes hydrogenation of pyrolysis products; CO and CO{sub 2} are products of pyrolysis reaction; and hydrogen is consumed mainly in hydrodeoxygenation reactions. Therefore, from a practical point of view, red mud, which is known as a coal liquefaction catalyst, can also be recommended as a cheap and powerful catalyst in the hydroliquefaction of biomass. 29 refs., 6 figs., 11 tabs.

1990-04-01

340

Catalytic hot gas conditioning of biomass derived product gas  

Energy Technology Data Exchange (ETDEWEB)

Biomass gasification provides the potential to efficiently and economically produce a renewable source of a clean gaseous fuel suitable for power generation or synthesis gas (syngas) applications. An important side benefit of the use of biomass is the effective minimization of the primary greenhouse gas, carbon dioxide (CO{sub 2}), by providing a means to close-loop the CO{sub 2} cycle. However, high molecular weight hydrocarbon constituents (tar) in the product gas from gasification can complicate the downstream uses of the gas. This paper discusses both the development of a low cost, disposable catalyst system that can eliminate these heavy hydrocarbons from the gas and the use of the catalyst in conjunction with the Battelle high-throughput gasification process for power generation and synthesis applications. (author)

1997-12-31

341

Bragg Curve Spectroscopy  

Energy Technology Data Exchange (ETDEWEB)

An alternative utilization is presented for the gaseous ionization chamber in the detection of energetic heavy ions, which is called Bragg Curve Spectroscopy (BCS). Conceptually, BCS involves using the maximum data available from the Bragg curve of the stopping heavy ion (HI) for purposes of identifying the particle and measuring its energy. A detector has been designed that measures the Bragg curve with high precision. From the Bragg curve the range from the length of the track, the total energy from the integral of the specific ionization over the track, the dE/dx from the specific ionization at the beginning of the track, and the Bragg peak from the maximum of the specific ionization of the HI are determined. This last signal measures the atomic number, Z, of the HI unambiguously.

1981-05-01

342

Approaches to the modelling of energy utilisation in product life cycles  

Energy Technology Data Exchange (ETDEWEB)

The paper considers research carried out on the topic of life cycle (LC) modelling of industrial processes with emphasis upon energy utilisation and gaseous emissions. The aim of the work is to investigate existing LC assessment codes, in particular for their outputs and decision making potential, and to develop the characteristics of new software as appropriate. The paper focuses on a comparison of two methods for LC modelling: use of ''SimaPro 5'' with ECO-indicators and logical-information modelling. The considered approaches require attention to dynamic modelling having features for decision making; for example, in areas of costs, sensitivity analysis and optimisation of LC process parameters to economically reduce the total environmental load. Brick making is chosen as an energy intensive process for model application. (orig.)

2006-05-15

343

An investigation of turbulent catalytically stabilized channel flow combustion of lean hydrogen - air mixtures  

Energy Technology Data Exchange (ETDEWEB)

The catalytically stabilised thermal combustion (CST) of lean hydrogen-air mixtures was investigated numerically in a turbulent channel flow configuration using a two-dimensional elliptic model with detailed heterogeneous and homogeneous chemical reactions. Comparison between turbulent and laminar cases having the same incoming mean properties shows that turbulence inhibits homogeneous ignition due to increased heat transport away from the near-wall layer. The peak root-mean-square temperature and species fluctuations are always located outside the extent of the homogeneous reaction zone indicating that thermochemical fluctuations have no significant influence on gaseous combustion. (author) 4 figs., 6 refs.

1999-08-01

344

Adiabatic flame temperature of hydrogen in combination with gaseous fuels  

Energy Technology Data Exchange (ETDEWEB)

The equilibrium composition and temperature resulting from the combustion of hydrocarbon fuels in combination with hydrogen have been analytically evaluated. Rich, lean and stoichiometric mixtures have been considered for this purpose. The flame temperature data obtained from computer calculations has been fitted with an equation expressed in terms of calorific value, C/H ratio, air-fuel ratio and heat of dissociation of the fuel mixture. This equation can be used to calculate the flame temperature directly without resorting to the elaborate calculation of species concentration. The results obtained using the equation have been found to have an accuracy of 0.05 to 2.5% for different fuel combinations. (author).

1989-01-01

345

A method for producing a filtering material for organic substances  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for making a filtering material (FM) through applying bitumen or tar to a porous substance and subsequent roasting. Blast furnace slag, pumice and other inorganic substances are used as the porous substance. The method makes it possible to acquire an inexpensive filtering material with a developed surface (Pv), which replaces activated charcoal. Example. Blast furnace slag is heated to 200 to 300 degrees and with mixing is impregnated by 5 to 15 percent bitumen or tar. The impregnated slag is roasted at 800 to 1,000 degrees until full carbonization of the bitumen or tar, acquiring in this way a filtering material, which is characterized by a specific surface of 700 to 1,000 square centimeters per gram and suitable as a replacement for activated charcoal for removing organic components and heavy metals from gaseous and liquid phases. The cost of the filtering material is one eighth to one tenth of that of activated charcoal.

1981-06-27

346

A future of floods?; Droht Land unter?  

Energy Technology Data Exchange (ETDEWEB)

There are alarming scenarios that state that global heating caused by anthropogenic gaseous emissions will melt the ice caps of Greenland and the Antarctic. This would cause flooding of coastal regions on a global scale. The floods are expected already in the next century, but there are no realistic assessments of the extent of the danger. (orig.) [Deutsch] Alarmierenden Szenarien zufolge koennten durch eine globale Erwaermung, die der Mensch mit dem Ausstoss von Treibhausgasen in die Atmosphaere verursacht, die Eiskappen auf der Antarktis und Groenland abschmelzen. Schon im kommenden Jahrhundert wuerden dadurch weite kuestennahe Gebiete ueberflutet. Noch aber laesst sich schwer abschaetzen, wie real die Gefahr ist. (orig.)

1997-06-01

347

5. Sampling  

International Nuclear Information System (INIS)

The sampling is described for radionuclide X-ray fluorescence analysis. Aerosols are captured with various filter materials whose properties are summed up in the table. Fine dispersed solid and liquid particles and gaseous admixtures may be captured by bubbling air through a suitable absorption solution. The concentration of small amounts of impurities from large volumes of air is done by adsorbing impurities on surfactants, e.g., activated charcoal, silica gel, etc. Aerosols may be captured using an electrostatic precipitator and aerosol fractions may be separated with a cascade impactor. Water sampling differs by the water source, i.e., ground water, surface water, rain or waste water. Soil samples are taken by probes. (ES).

1983-12-01

348

Water diffusion profile measurements in epoxy using neutron radiography  

International Nuclear Information System (INIS)

The diffusion characteristics of water in polymer materials have been studied for a few decades. Several methods have been developed to provide water diffusion characteristics as a function of time, temperature, pressure, or thickness of polymer. Unfortunately, most of these methods give the amount of water absorbed as a function of weight versus time at given environmental conditions. Concentration profiles of the water diffusion through the polymer have been unobtainable by these established methods. Neutron radiography is a method of non-destructive testing that has grown rapidly over the past ten years and is capable of giving these concentration profiles. Epoxy is one of the most commonly used polymers for which water diffusion information is important. In the automotive industry, epoxy is used both as a sealant and a bonder to prevent water from getting inside structures and causing corrosion. To ...

349

Transient enhanced diffusion from decaborane molecular ion implantation  

Energy Technology Data Exchange (ETDEWEB)

Transient enhanced diffusion (TED) from implantation of 5thinspkeVthinspB{sub 10}H{sub 14} and 0.5 keV B ions has been quantified and compared for nominal boron doses of 10{sup 14} and 10{sup 15}thinspcm{sup {minus}2}. Boron diffusivity during annealing was extracted from secondary ion mass spectroscopy depth profiles of diffused marker layers in boron doping-superlattices and the actual implanted B dose was independently measured by nuclear reaction analysis. Comparable enhancements were observed from both ions. Transmission electron microscopy analysis revealed that both boron- and decaborane-implanted samples were amorphized at a nominal 10{sup 15}thinspcm{sup {minus}2}thinspB dose. A comparison with data from low energy Si implants revealed a similar dependence of diffusivity enhancement on implant dose. These findings are consistent with the understanding that TED is caused by the interstitial ...

1998-10-01

350

Transient enhanced diffusion from decaborane molecular ion implantation  

International Nuclear Information System (INIS)

Transient enhanced diffusion (TED) from implantation of 5keVB_1_0H_1_4 and 0.5 keV B ions has been quantified and compared for nominal boron doses of 10"1"4 and 10"1"5cm"-"2. Boron diffusivity during annealing was extracted from secondary ion mass spectroscopy depth profiles of diffused marker layers in boron doping-superlattices and the actual implanted B dose was independently measured by nuclear reaction analysis. Comparable enhancements were observed from both ions. Transmission electron microscopy analysis revealed that both boron- and decaborane-implanted samples were amorphized at a nominal 10"1"5cm"-"2B dose. A comparison with data from low energy Si implants revealed a similar dependence of diffusivity enhancement on implant dose. These findings are consistent with the understanding that TED is caused by the interstitial supersaturation resulting from a number of excess interstitials ...

1998-10-01

351

Self-interstitial diffusion and clustering with impurities in crystalline silicon  

International Nuclear Information System (INIS)

In this work the diffusion of ion-beam-injected self-interstitials (Is) and their interaction with impurities in crystalline Si are presented. In particular, the I penetration into a molecular beam epitaxy grown Si structure was studied by means of diffusion effects induced on B spikes, analyzed by a developed simulation code. Trapping effects at sample-surface and bulk are evidenced and modeled. The B marker approach was extended to the two-dimensional (2D) I-diffusion occurring as a consequence of ion implantation through a sub-micron dimension patterned oxide mask. I-source size effects on the I penetration have been found and modeled, quantitatively describing the 2D I-diffusion. The I-substitutional carbon interactions have been also studied, showing the C ability to effectively retain Is. The I-trapping mechanism was quantitatively studied by the simulation code, showing that one I is able to ...

2004-02-01

352

Nonstoichiometry and diffusion in ceria and ceria solid solutions  

Energy Technology Data Exchange (ETDEWEB)

Some of the results of property measurements of CeO{sub 2} and its solid solutions were reviewed. The deviation from stoichiometry of undoped and doped CeO{sub 2} was presented in several figures, which suggested that CeO{sub 2} fired at high temperatures in air might be nonstoichiometric in some degree. At low temperatures, the deviation from stoichiometry in doped CeO{sub 2} is higher than undoped CeO{sub 2}. As another interesting property, CeO{sub 2} shows high solubility to trivalent cations such as rare earth elements. A possible reason behind this high solubility was presented. The nonstoichiometric defect in undoped CeO{sub 2} and the trivalent cation in solid solution with CeO{sub 2} have to be compensated by other defects. The possible defect structures in this solid solution were reviewed and the most probable structure was chosen based on density measurement and impurity dependence of oxygen diffusion coefficient. Finally the oxygen ...

2003-07-01

353

Laser Raman scattering measurements of differential molecular diffusion in turbulent nonpremixed jet flames of H{sub 2}/CO{sub 2} fuel  

Science.gov (United States)

This paper explores effects of differential diffusion in nonpremixed turbulent jet flames. Pulsed Raman scattering spectroscopy is used to measure temperature and species concentrations in chemically reacting jets of H{sub 2}/CO{sub 2} into air, over a range of jet Reynolds numbers from 1,000 to 30,000 based on cold jet fluid properties. Results show significant effects of differential diffusion at all jet Reynolds numbers considered. Differential diffusion between H{sub 2} and C0{sub 2} produces differences between the hydrogen element mixture fraction ({xi}{sub H}) and the carbon element mixture fraction ({xi}{sub c}). The greatest effects occur on the rich side of stoichiometric, where {xi}{sub H} is observed to be smaller than {xi}{sub C} at all Reynolds numbers. Differential diffusion between H{sub 2} and H{sub 2}O creates a net flux of hydrogen element toward the stoichiometric contour and causes ...

1994-01-01

354

Solid state diffusion in metal silicides  

International Nuclear Information System (INIS)

Radioactive "3"1Si was used as a marker to study metal silicide formation. Activity profiles in the silicides were measured by a combination of ion beam sputtering, radioactivity counting and Rutherford backscattering of charged nuclear particles. It was found that the metal is the diffusing species during Co_2Si, Pt_2Si, NiSi and PtSi formation, while silicon diffuses during CrSi_2, TiSi_2 and ZrSi_2 formation. Silicon was also found to be the diffusing species during second phase formation of CoSi from Co_2Si. However, in this case it was established that the silicon diffuses by a grain boundary and/or interstitial mechanism. Both the metal and silicon diffuse during Ni_2Si and Pd_2Si formation. In an attempt to interpret complex radioactivity profiles a computer program, simulating various diffusion mechanisms during both first and second phase silicide ...

355

Yttrium Y 90 Ibritumomab Tiuxetan, Fludarabine, Radiation Therapy, and Donor Stem Cell Transplant in Treating Patients With Relapsed or Refractory Non-Hodgkin's Lymphoma  

Science.gov (United States)

B-cell Chronic Lymphocytic Leukemia; Nodal Marginal Zone B-cell Lymphoma; Recurrent Adult Burkitt Lymphoma; Recurrent Adult Diffuse Large Cell Lymphoma; Recurrent Adult Diffuse Mixed Cell Lymphoma; Recurrent Adult Diffuse Small Cleaved Cell Lymphoma; Recurrent Adult Grade III Lymphomatoid Granulomatosis; Recurrent Adult Immunoblastic Large Cell Lymphoma; Recurrent Adult Lymphoblastic Lymphoma; Recurrent Grade 1 Follicular Lymphoma; Recurrent Grade 2 Follicular Lymphoma; Recurrent Grade 3 Follicular Lymphoma; Recurrent Mantle Cell Lymphoma; Recurrent Marginal Zone Lymphoma; Recurrent Small Lymphocytic Lymphoma; Splenic Marginal Zone Lymphoma; Waldenstrom Macroglobulinemia

2010-10-12

356

Wetting failure and contact line dynamics in a Couette flow  

CERN Document Server

Liquid-liquid wetting failure is investigated in a two-dimensional Couette system with two immiscible fluids of arbitrary viscosity. The problem is solved exactly using a sharp interface treatment of hydrodynamics (lubrication theory) as a function of the capillary number, viscous ratio and separation of scale, i.e. slip length versus macroscopic scale of the system. The existence of critical velocities, above which no stationary solutions are found, is analyzed in detail in terms of the relevant parameters of the system. Comparisons with existing analysis for other geometries are also carried out. A numerical method of analysis is also presented, based on diffuse interface models obtained from multiphase extensions of the lattice Boltzmann equation (LBE). Sharp interface and diffuse interface models are quantitatively compared face to face indicating the correct limit of applicability of the diffuse interface models.

2008-01-01

357

Transient-enhanced diffusion during furnace and rapid thermal annealing of ion-implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of ion-implanted silicon. We have studied this transient in detail and show that, for doses of Group V dopants sufficient to amorphize the silicon, it arises from the trapping of interstitials by dopant atoms during implantation. These are retained during solidphase-epitaxial (SPE) growth, but can be released by additional thermal processing to cause the observed transient and the formation of a band of extended defects. We have measured the enhanced diffusion coefficients and the duration of the transient for Sb-implanted Si by careful furnace annealing experiments. We obtain general expressions which predict the effects of the transient during any thermal processing based on SPE growth (furnace, CW laser, or rapid thermal annealing). We show that there is no analogous mechanism of vacancy trapping by Group III elements.

1985-08-01

358

Transient-enhanced diffusion during furnace and rapid thermal annealing of ion-implanted silicon  

International Nuclear Information System (INIS)

A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of ion-implanted silicon. We have studied this transient in detail and show that, for doses of Group V dopants sufficient to amorphize the silicon, it arises from the trapping of interstitials by dopant atoms during implantation. These are retained during solidphase-epitaxial (SPE) growth, but can be released by additional thermal processing to cause the observed transient and the formation of a band of extended defects. We have measured the enhanced diffusion coefficients and the duration of the transient for Sb-implanted Si by careful furnace annealing experiments. We obtain general expressions which predict the effects of the transient during any thermal processing based on SPE growth (furnace, CW laser, or rapid thermal annealing). We show that there is no analogous mechanism of vacancy trapping by Group III elements.

359

Thermal diffusion by Brownian motion induced fluid stress  

CERN Document Server

The Ludwig-Soret effect, the migration of a species due to a temperature gradient, has been extensively studied without a complete picture of its cause emerging. Here we investigate the dynamics of DNA and spherical particles sub jected to a thermal gradient using a combination of Brownian dynamics and the lattice Boltzmann method. We observe that the DNA molecules will migrate to colder regions of the channel, an observation also made in the experiments of Duhr, et al[1]. In fact, the thermal diffusion coefficient found agrees quantitatively with the experimental value. We also observe that the thermal diffusion coefficient decreases as the radius of the studied spherical particles increases. Furthermore, we observe that the thermal fluctuations-fluid momentum flux coupling induces a gradient in the stress which leads to thermal migration in both systems.

2007-01-01

360

The effect of excimer laser pretreatment on diffusion and activation of boron implanted in silicon  

International Nuclear Information System (INIS)

We have investigated the effect of excimer laser annealing (ELA) on transient enhanced diffusion (TED) and activation of boron implanted in Si during subsequent rapid thermal annealing (RTA). It is observed that ELA with partial melting of the implanted region causes reduction of TED in the region that remains solid during ELA, where the diffusion length of boron is reduced by a factor of #approx#4 as compared to the as-implanted sample. This is attributed to several mechanisms such as liquid-state annealing of a fraction of the implantation induced defects, introduction of excess vacancies during ELA, and solid-state annealing of the defects beyond the maximum melting depth by the heat wave propagating into the Si wafer. The ELA pretreatment provides a substantially improved electrical activation of boron during subsequent RTA.

2005-11-07

361

Testing and design of radon resisting membranes based on the experience from the Czech Republic  

International Nuclear Information System (INIS)

Testing of barrier properties of insulating materials against radon is usually based on the measurement of the radon diffusion coefficient. Presented report summarizes results of radon diffusion coefficients measurements in more than 120 insulating materials obtained throughout Europe. All measurements were performed by the Czech Technical University, Faculty of Civil Engineering in cooperation with the Radiation Protection Institute. We have found out that great differences exist in diffusion properties, because the diffusion coefficients vary within eight orders from 10"-"1"5 m"2/s to 10"-"8 m"2/s. For each material category of different chemical composition statistical evaluation of results is presented. Possibilities of usage of the radon diffusion coefficient for the design of radon resisting membranes are discussed. Based on the experience from the Czech Republic the paper is ...

362

Tantalum nitride as a diffusion barrier between Pd_2Si or CoSi_2 and aluminum  

International Nuclear Information System (INIS)

Reactively sputtered tantalum nitride (Ta_2N) has been investigated as a diffusion barrier between Pd_2Si and aluminum and CoSi_2 and Al. Ta_2N is found to be an excellent matallurgical diffusion barrier for the two systems up to 555 "0C, with no intermixing observed in Rutherford backscattering and Auger electron spectroscopic studies. Schottky barrier devices n-Si/Pd_2Si/Ta_2N/Al were excellent and showed no deterioration after annealing at 500 "0C. However, similar devices with CoSi_2 contacts and Ta_2N barrier showed a creation of high contact resistance between the silicide and the as-deposited nitride.

363

Tantalum nitride as a diffusion barrier between Pd/sub 2/Si or CoSi/sub 2/ and aluminum  

Energy Technology Data Exchange (ETDEWEB)

Reactively sputtered tantalum nitride (Ta/sub 2/N) has been investigated as a diffusion barrier between Pd/sub 2/Si and aluminum and CoSi/sub 2/ and Al. Ta/sub 2/N is found to be an excellent matallurgical diffusion barrier for the two systems up to 555 /sup 0/C, with no intermixing observed in Rutherford backscattering and Auger electron spectroscopic studies. Schottky barrier devices n-Si/Pd/sub 2/Si/Ta/sub 2/N/Al were excellent and showed no deterioration after annealing at 500 /sup 0/C. However, similar devices with CoSi/sub 2/ contacts and Ta/sub 2/N barrier showed a creation of high contact resistance between the silicide and the as-deposited nitride.

1989-04-15

364

Suppression of transient enhanced diffusion following {ital in} {ital situ} photoexcitation during boron ion implantation  

Energy Technology Data Exchange (ETDEWEB)

The effect of {ital in} {ital situ} photoexcitation during boron ion implantation on subsequent transient enhanced B diffusion in Si has been investigated. Photoexcitation using a mercury arc lamp was performed during B{sup +} implantation at 35 keV for a dose of 5{times}10{sup 14} cm{sup {minus}2} at 177 K. A reduction in the electrical activation dip, i.e., reverse annealing effect, in the temperature range 550--700 {degree}C was observed. Also, the transient enhanced diffusion of B, measured using SIMS following 800 {degree}C, 30 min annealing, was suppressed. Both effects demonstrate that the creation of self-interstitials during the implantation process is significantly reduced. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

1995-10-09

365

Suppression of transient enhanced diffusion following in situ photoexcitation during boron ion implantation  

International Nuclear Information System (INIS)

The effect of in situ photoexcitation during boron ion implantation on subsequent transient enhanced B diffusion in Si has been investigated. Photoexcitation using a mercury arc lamp was performed during B"+ implantation at 35 keV for a dose of 5x10"1"4 cm"-"2 at 177 K. A reduction in the electrical activation dip, i.e., reverse annealing effect, in the temperature range 550--700 degree C was observed. Also, the transient enhanced diffusion of B, measured using SIMS following 800 degree C, 30 min annealing, was suppressed. Both effects demonstrate that the creation of self-interstitials during the implantation process is significantly reduced. copyright 1995 American Institute of Physics.

366

Self-diffusion of silicon in thin films of cobalt, nickel, palladium and platinum silicides  

International Nuclear Information System (INIS)

Radioactive "3"1Si was used as a tracer to study silicon self-diffusion in thin film silicides of cobalt, nickel, palladium and platinum. The specimens were prepared by sequential electron beam evaporation of radioactive "3"1Si and of the metal onto cleaned silicon wafers. By vacuum annealing at the appropriate formation temperature a silicide about 250 nm thick containing a sharp radioactive band about 50 nm thick was generally formed. Subsequent heating above the formation temperature resulted in a spreading of the activity owing to silicon self-diffusion. Activity profiles in the silicides were measured by a combination of ion beam sputtering, radioactivity counting and Rutherford backscattering of charged nuclear particles. (orig.).

367

Recommended changes in meteorological measurement and prediction methods for coastal sites  

Energy Technology Data Exchange (ETDEWEB)

A study was performed to examine currently recommended meteorological measurement programs and atmospheric transport and diffusion prediction models for nuclear power plants to determine their adequacy for plants located in coastal zones where meteorological conditions are normally more complex than at inland sites and to make recommendations for changes to improve current procedures. Recommendations were based on an extensive literature review and on studies of coastal meteorology and diffusion. The study was focused on the following areas: coastal internal boundary layers; tower location; instrument heights; atmospheric stability classification; plume meander; and diffusion calculations. Each of the areas is discussed with appropriate recommendations which were made with respect to either the scientific or the regulation aspects of current procedures or both. Other potential problem areas are also pointed out.

1980-01-01

368

Prediction of transient-enhanced diffusion during rapid thermal annealing of ion-implanted silicon  

International Nuclear Information System (INIS)

There have been several reports of transient-enhanced diffusion during furnace or rapid thermal annealing of ion-implanted silicon and some reports of no enhancement. In this contribution, the authors show that many of the observed effects can be accounted for by an interstitial trapping mechanism, in which large numbers of Si atoms are trapped by group V dopant atoms in the amorphous material during implantation. These trapped atoms are retained during solid-phase-epitaxial (SPE) growth, but can be released later during thermal processing to give the transient-enhanced diffusion. The authors present a model which can predict the transient effects (or lack of them) for any concentration of Sb, Bi, or As dopants sufficient to amorphize the silicon and any thermal processing technology which relies on SPE growth (furnace, cw laser, or rapid thermal annealing).

1985-03-01

369

New Radiation Stable and Long-Lived Plastic Scintillators  

International Nuclear Information System (INIS)

A study of the influence of the concentration of secondary addition, high concentrations of primary dopant, diffusion enhancer and stabilizer on radiation hardness is presented. It is concluded that the diffusion enhancing technique is the most powerful method for improving radiation hardness. A new polystyrene scintillator which contains 2% pT, 0.02% POPOP, 20% diffusion enhancer and 0.02% stabilizer gave 91% of initial light output immediately after 3 Mrad irradiation in air. Data are presented that show that scintillator prepared from commercial polymer is more radiation-hard and has greater light output than scintillator prepared from monomer. It is assumed that this difference is due to different molecular weight distributions. Some protocols for acceleration of aging (yellowing and crazing) are presented. It is shown that one of the main reasons for aging of plastic scintillators is residual monomer. 10 refs., 18 ...

1993-11-15

370

Modulation of proton NMR free induction decay by spin diffusion  

Energy Technology Data Exchange (ETDEWEB)

The effects of spin diffusion on the free induction decay (FID) of protons associated with the noncrystalline domains of two polymers, polyethylene and blended Nylon 66 (ZYTEL-408), have been examined using Goldman--Shen NMR pulse sequence ((1/2)..pi..x-t/sub 0/-(1/2)..pi..x-bar-tau-(1/2)..pi..x-t). At tau< or approx. =100 ..mu..s, the FID is drastically distorted from the exponential form while at longer tau(tau> or approx. =500 ..mu..s) an exponential FID is observed; but its transverse spin relaxation rate is smaller than that of the FID obtained after a single (1/2)..pi..x pulse and approaches this value at the limit of large tau. These findings are interpreted in terms of the theory of rapid spin diffusion. The spatial variation in the spin relaxation rate within the noncrystalline domain is inferred.

1982-02-01

371

Modelling of MeV alpha particle energy transfer to lower hybrid waves  

Energy Technology Data Exchange (ETDEWEB)

The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. Here we calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favourable for wave amplification from alpha energy. We find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy transfer, is investigated. This technique is shown to offer a large potential benefit. ...

1994-05-01

372

Modelling of MeV alpha particle energy transfer to lower hybrid waves  

International Nuclear Information System (INIS)

The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. Here we calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favourable for wave amplification from alpha energy. We find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy transfer, is investigated. This technique is shown to offer a large potential benefit. ...

373

Modeling of drug release from bulk-degrading polymers  

British Library Electronic Table of Contents (United Kingdom)

This paper aims to provide a comprehensive review of the various models or simulations for predicting drug release from bulk-degrading systems. A brief description of bulk degradation processes and factors affecting the degradation rate, and consequently the release kinetics, is presented first. Next, several important classical models, often used as the basis for subsequent model development, are discussed. Both mathematical models and Monte-Carlo based simulations have been developed for controlled release from bulk-degrading systems. The mathematical models can be further subdivided into two categories. First, the diffusion-based models whose transport mechanism is mainly governed by diffusion, but with degradation-dependent diffusion coefficients. These are generally simpler and easier...

2011-01-01

374

Modeling of MeV alpha particle energy transfer to lower hybrid waves  

Energy Technology Data Exchange (ETDEWEB)

The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. An initial analytic study was done by Fisch and Rax. Here the authors calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favorable for wave amplification from alpha energy. They find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy transfer, is investigated. ...

1993-10-01

375

Meteorological measurement methods and diffusion models for use at coastal nuclear reactor sites  

Energy Technology Data Exchange (ETDEWEB)

A study, based on a literature review was made to examine currently recommended meteorological measurement programs and diffusion prediction methods for nuclear power plants to determine their adequacy for plants located in coastal zones. Although procedures for handling the near-worst case (stable, light-wind situation) were judged adequately conservative, deficiencies in guidelines and procedures were found with respect to the following: failure to consider the role of coastal internal boundary layers; specifications for tower locations and instrument heights; methods of classifying atmospheric stability; methods of allowing credit for plume meander, and models specified for diffusion calculations. Recommendations were made for changes in the guidelines applicable to these topics. Areas in which additional research is needed were identified.

1980-11-01

376

Marker experiments in growth studies of Ni_2Si, Pd_2Si, and CrSi_2 formed both by thermal annealing and by ion mixing  

International Nuclear Information System (INIS)

Inert markers (evaporated tungsten and silver) were used in growth studies of silicides formed both by thermal annealing and by ion mixing in the Ni/Si, Pd/Si, and Cr/Si systems. The markers were initially imbedded inside silicides and backscattering spectrometry was used to determine the marker displacement after different processing conditions. The results obtained in thermal annealing are quite consistent with that found in previous investigations. Ni is the dominant diffusing species in Ni_2Si, while Si is the diffusing species in CrSi_2. In Pd_2Si, both Pd and Si are moving species with Pd the faster of the two. In contrast, in growth of silicides by ion irradiation Si is the faster diffusing species in all three systems.

377

Marker experiments in growth studies of Ni/sub 2/Si, Pd/sub 2/Si, and CrSi/sub 2/ formed both by thermal annealing and by ion mixing  

Energy Technology Data Exchange (ETDEWEB)

Inert markers (evaporated tungsten and silver) were used in growth studies of silicides formed both by thermal annealing and by ion mixing in the Ni/Si, Pd/Si, and Cr/Si systems. The markers were initially imbedded inside silicides and backscattering spectrometry was used to determine the marker displacement after different processing conditions. The results obtained in thermal annealing are quite consistent with that found in previous investigations. Ni is the dominant diffusing species in Ni/sub 2/Si, while Si is the diffusing species in CrSi/sub 2/. In Pd/sub 2/Si, both Pd and Si are moving species with Pd the faster of the two. In contrast, in growth of silicides by ion irradiation Si is the faster diffusing species in all three systems.

1985-08-15

378

Mapping subcortical diffusivity. Application to brain development. Presidential award proceeding  

International Nuclear Information System (INIS)

We studied age-related microstructural changes in the subcortical white matter from adolescence to middle age in 16 healthy male subjects (age range: 12 to 47 years) using diffusion-weighted magnetic resonance (MR) imaging (DWI). Mean diffusivity (MD) of subcortical white matter was mapped onto the overlying cortical surface using our original method. The mean MD values within 76 cortical regions were measured using atlas-based gray matter segmentation and then correlated with age. A significant negative correlation with age was observed in subcortical MD values in several cortical regions, primarily over the bilateral temporal and occipital lobes. Our results demonstrated subcortical microstructural change in postadolescence that may reflect continuing myelination. (author)

2007-01-01

379

Leaching of zinc sulfide by Thiobacillus ferrooxidans: Bacterial oxidation of the sulfur product layer increases the rate of zinc sulfide dissolution at high concentrations of ferrous ions  

Energy Technology Data Exchange (ETDEWEB)

This paper reports the results of leaching experiments conducted with and without Thiobacillus ferroxidans at the same conditions in solution. The extent of leaching of ZnS with Bacteria is significantly higher than that without bacteria at high concentrations of ferrous ions. A porous layer of elemental sulfur is present on the surfaces of the chemically leached particles, which no sulfur is present on the surfaces of the bacterially leached particles. The analysis of the data using the shrinking-core model shows that the chemical leaching of ZnS is limited by the diffusion of ferrous ions through the sulfur product layer at high concentrations of ferrous ions. The analysis of the data shows that diffusion through the product layer does not limit the rate of dissolution when bacteria are present. This suggests that the action of T.ferroxidans in oxidizing the sulfur formed on the particle surface is to remove the barrier to ...

1999-12-01

380

Investigation of factors affecting the diffusion of mobile telephone services: An empirical analysis for Vietnam  

British Library Electronic Table of Contents (United Kingdom)

This paper analyzes the diffusion of mobile telecommunications services in Vietnam and examines how telecommunications regulation and potential substitute/complement services affect the growth of the number of mobile telephone subscribers. Using a logistic diffusion model, it is found that fixed telephone services are a complement while data services have a negative relation to mobile telephone services in Vietnam. As for regulation, the policy of introducing competition has been found to be the most effective in influencing the adoption of mobile services. Another important result is that the estimated potential market is roughly 76% of the total population. The findings suggest that suitable regulation that guarantees competition in the mobile telecommunications market in a developing co...

2009-01-01

381

Influence of substitutional carbon incorporation on implanted-indium-related defects and transient enhanced diffusion  

International Nuclear Information System (INIS)

It has been demonstrated that, by incorporating a thin #approx#20 nm Si_1_-_yC_y (with y as low as 0.1%) layer at the deep indium implant end-of-range (EOR) region, the EOR defects and enhanced diffusion behavior associated with indium implant can be eliminated. The Si_1_-_yC_y layer was grown epitaxially followed by a silicon epitaxy cap of 60 nm. Indium implantations were performed at 1x10"1"4 cm"-"2 at 115 keV followed by spike annealing at 1050 deg. C. The experimentally observed EOR defect and enhanced diffusion elimination are explained based on the undersaturation of implantation-induced silicon interstitials with the presence of substitutional carbon at the Si_1_-_yC_y layer.

2003-11-17

382

Influence of fluorine on the simulation of the transient enhanced diffusion of 15 keV BF_2"+ ion implantation into silicon  

International Nuclear Information System (INIS)

We have simulated the transient enhanced diffusion (TED) of boron fluoride (BF_2"+) implanted in crystalline and germanium amorphized silicon. Based on recently published models, the effect of fluorine on boron diffusion in silicon has been introduced and a modelling has been suggested. In order to simulate the boron experimental profiles, we have assumed that fluorine forms clusters involving interstitial boron which reduces the junction depth. Experimental results indicate that fluorine behaviour depends on amorphization energy. Moreover, even no germanium preamorphization is performed, silicon is still amorphized by fluorine species. Hence, BF_2"+ implantation leads to an amorphous/crystalline (a/c) interface near the surface. An improvement of published models is suggested taking into account fluorine effects. The simulations satisfactory reproduce the SIMS experimental profiles for a large scale of experimental conditions.

2002-01-01

383

Implant damage and redistribution of indium in indium-implanted thin silicon-on-insulator  

Energy Technology Data Exchange (ETDEWEB)

The indium implant damage and diffusion behavior in thin silicon-on-insulator (SOI) with a 200 nm top silicon layer were studied for different implantation energies and doses. Rutherford backscattering spectrometry in the channeling mode (RBS/C) was used to characterize the implant damage before and after annealing. Secondary ion mass spectrometry (SIMS) was used to study the indium transient enhanced diffusion (TED) behavior in the top Si layer of the SOI structure. An anomalous redistribution of indium after relatively high energy (200 keV) and dose (1 x 10{sup 14} cm{sup -2}) implantation was observed in both bulk Si and SOI substrates. However, there exist differences in these two substrates that are attributable to the more predominant out-diffusion of indium as well as the influence of the buried oxide layer in the SOI structure.

2004-12-15

384

Implant damage and redistribution of indium in indium-implanted thin silicon-on-insulator  

International Nuclear Information System (INIS)

The indium implant damage and diffusion behavior in thin silicon-on-insulator (SOI) with a 200 nm top silicon layer were studied for different implantation energies and doses. Rutherford backscattering spectrometry in the channeling mode (RBS/C) was used to characterize the implant damage before and after annealing. Secondary ion mass spectrometry (SIMS) was used to study the indium transient enhanced diffusion (TED) behavior in the top Si layer of the SOI structure. An anomalous redistribution of indium after relatively high energy (200 keV) and dose (1 x 10"1"4 cm"-"2) implantation was observed in both bulk Si and SOI substrates. However, there exist differences in these two substrates that are attributable to the more predominant out-diffusion of indium as well as the influence of the buried oxide layer in the SOI structure.

2004-12-15

385

High temperature deformation behaviour of Ti-10V Alloy and associated activation energy  

International Nuclear Information System (INIS)

High temperature deformation behaviour of an experimental Beta-titanium alloy Ti-10V has been studied in the temperature range 800 to 945 degree C by using the method of crosshead speed cycling. Although subgrain formation was observed but the alloy did not exhibit superplastic behaviour in the entire temperature range studied. A very large initial grain size and elongation of grains during the deformation are considered the main factors responsible for absence of superplastic behaviour. The activation energy values for regions II and III of the ln sigma vs. ln small epsilon plots are close to the lower of the two activation energy values proposed together to describe self diffusion in beta-phase suggesting that the rate controlling mechanism is that for lattice diffusion rather then grain boundary diffusion. (author)

2004-06-01

386

Grain mantles: The impact on grain evolution and selective extinction  

International Nuclear Information System (INIS)

Depletion studies are used to infer the presence of mantles and to constrain grain evolutionary models in the diffuse interstellar medium. The presence of these mantles appears to be important in the evolution of the grains inside diffuse as well as dense clouds. In dense clouds where the element-to-element abundances sometimes differ from those found in diffuse clouds, empirical relationships are starting to emerge between gas abundances and various types of peculiar selective extinction. These peculiar extinction curves may be the results of nonvolatile mantle formation on grain cores or may reflect chemical differences due to variations in the intrinsic metalicity from one cloud to another. A simple model of the time evolution of a parcel of gas and dust as observed by the depletion of two elements is presented. Different studies of grain evolution and selective extinction are discussed and compared.

1989-12-01

387

Experiments on air movement. Experimental contribution to the calculation of room air velocity with diffuse air distribution  

Energy Technology Data Exchange (ETDEWEB)

In the paper presented, an attempt is made to describe quantitatively the room air motion by diffuse air distribution. Since solving the problem theoretically, seems to be hopeless at present, only an experimental solution seems to promise success. Experiments with diffuse air distribution offer suitable preconditions. With this kind of air introduction into the room, a relatively regular distribution of room air motion can be expected. A further simplification will be achieved by isotherme flow conditions. The first goal of the experiments was to establish whether the velocities measured are reproducible to demonstrate, and can be brought into a functional connection. The room air motion is a measured value which changes temporarily and locally quite largely, far more than is customary with technical measurements. From there, a second task arises, i.e. to evaluate the fluctuation of the velocity registered by its quantity in an appropriate ...

1985-08-01

388

Enhanced diffusion from interstitial trapping during solid-phase-epitaxial growth of silicon alloys. Draft  

Energy Technology Data Exchange (ETDEWEB)

During the recrystallization by solid-phase-epitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, we propose that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing.

1984-08-01

389

Enhanced diffusion from interstitial trapping during solid-phase-epitaxial growth of silicon alloys  

Energy Technology Data Exchange (ETDEWEB)

During the recrystallization by solid-phase-expitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +/- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, it is proposed that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing. 12 references, 6 figures.

1984-01-01

390

Effects of ion irradiation on the diffusion of pre-implanted B atoms in crystalline silicon  

International Nuclear Information System (INIS)

N-type crystalline Si (100) implanted with 5 keV B ions was subsequently irradiated with MeV Si, O and F ions. The B atom profiles were measured by means of secondary ion mass spectrometer after the treatment of rapid thermal annealing. The results show that the transient enhanced diffusion of B atoms is effectively limited by the post-implantation of high energy ions at high dose. At the same irradiation conditions, it is found that the existence of a SiO_2 layer in the near surface of Si is even more effective in suppressing the transient enhanced diffusion of the doped B atoms. The results are qualitatively discussed in combination with the analyses of RBS/c measurements and calculation of the DICADA code

2001-12-01

391

Effect of the tide on the diffusion of "3H in the liquid effluent discharged from Daya Bay Nuclear Power Station  

International Nuclear Information System (INIS)

The tide field at the time of liquid effluent discharging from Daya Bay nuclear power station, and the average water speed at the monitoring points in west Daya Bay from the time of discharging to the time of sampling were calculated by ADI (Alternating Direction Implicit) method. By comparing analysis, the difference of "3H diffusion between spring tide and neap tide (the expansion of "3H within one day of spring tide is greater than that within one day of neap tide) was found. So, an equivalent diffusion time is introduced to modify the original model, and a better attenuation relation between the average "3He concentration in west Daya Bay and the time since the liquid "3H discharging is obtained. (authors)

2006-07-01

392

Diffusion examined by diffraction  

Science.gov (United States)

X-ray diffraction offers a unique combination of advantages for kinetic study which include the non-destructive nature of the measurement, the use of bulk crystals, and the convenience of the experimental arrangements. These attributes and the availability of position-sensitive detectors and high-flux synchrotron radiation sources make this technique most useful for in situ, dynamical investigations. When using diffraction techniques to determine a diffusion coefficient, the principle of analysis entails a scattering theory and a kinetic model. The former allows the kinetic parameter(s) to be extracted from measured intensity, while the latter relates the kinetic parameter(s) to the diffusion coefficient(s). Three examples are demonstrated: (1) Palladium Silicide (Pd{sub 2}Si) Layer Growth on Silicon, (2) Decomposition of an Ni-12.5at%Si Superalloy, and (3) Short-range Ordering in Cu-Au Solid Solutions.

393

Determination of the helium thermal diffusion coefficient in britholite using a NRA method: new results  

International Nuclear Information System (INIS)

Dimensioning of actinides waste packages for long duration storage has to take into account helium production from natural decay and release rates from the material. For the latter, we propose here an improved method for the determination of the helium diffusion coefficient in britholite, to be used for minor actinides storage. This work is based on results we previously published using the classical three steps method: "3He implantation on a Van de Graaff facility, "3He profile determination analysing the protons resulting from the "3He(d,p)"4He reaction in a nuclear microprobe, evolution of the helium profile during annealings. Taking explicitly into account the incident deuterons energy stragglings allows us to show that the implanted helium profiles are bimodal, each component leading to a different helium diffusion coefficient.

2005-02-01

394

Degradation of gas turbine coatings and life assessment  

Energy Technology Data Exchange (ETDEWEB)

MCrAlY coatings are widely used on hot section components of gas turbines to provide hot corrosion and/or oxidation protection by formation of an oxide layer on the surface. As the protective oxide scale exfoliates during service, aluminum from the coating diffuses outward for reformation of the protective scale. Aluminum may also diffuse inward due to the differences in composition between the coating and the substrate. Thus, the coatings degrade due to oxidation, oxide scale spallation, and inward and outward diffusion of aluminum. Service life of these coatings is controlled by the aluminum content in the coating, operating temperature and start- shutdown cycles. In-service degradation of CoCrAlY and CoNiCrAlY coatings is presented. A procedure to predict the remaining service life of coatings under oxidizing conditions is discussed. (orig.) 12 refs.

1998-12-31

395

Brookhaven National Laboratory Coastal Meteorology Program, 1972-1983  

Energy Technology Data Exchange (ETDEWEB)

Research conducted at Brookhaven National Laboratory under the Coastal Meteorology and Diffusion Research Program from 1972 to 1983 is summarized by the following study areas: Diffusion Studies, Boundary Layer Studies, Coastal Meteorology Studies, Air-Sea Interaction Studies, Coastal Transport and Diffusion Climatology, Seabreeze Modeling and Instrument Development, all supported by the US Department of Energy. Studies supported by the Nuclear Regulatory Commission, the National Science Foundation and the American Petroleum Institute are also described. A summary of a Workshop on Coastal Atmospheric Transport Processes, an account of studies in progress, recommendations for future research and a description of facilities and instrumentation available are also included. A list of all publications and presentations prepared as part of the program is given with abstracts. 7 figures, 1 table.

1983-06-01

396

Boron transient enhanced diffusion in heavily phosphorus doped silicon  

International Nuclear Information System (INIS)

A study has been made of B transient enhanced diffusion (TED) in heavily P-doped Si using secondary ion mass spectroscopy (SIMS) and positron annihilation spectroscopy (PAS). The P-doped silicon was implanted with boron ions of 40 keV energy to a dose of 3 x 10"1"4 cm"-"2, and then annealed at temperatures ranging from 700--1,000 C in a N_2 ambient for varying durations. As P doping concentration increased from 3 x 10"1"9 to 1 x 10"2"0 cm"-"3, boron diffusivity and the immobile boron fraction decreased. The experimental results are inconsistent with the predictions of the Fermi-level model and suggest that the clustering between B atoms and Si interstitials should be invoked in order to explain the immobile portion of the B peak during TED.

1996-12-02

397

Atomic scale models of Ion implantation and dopant diffusion in silicon  

Energy Technology Data Exchange (ETDEWEB)

We review our recent work on an atomistic approach to the development of predictive process simulation tools. First principles methods, molecular dynamics simulations, and experimental results are used to construct a database of defect and dopant energetics in Si. This is used as input for kinetic Monte Carlo simulations. C and B trapping of the Si self- interstitial is shown to help explain the enormous disparity in its measured diffusivity. Excellent agreement is found between experiments and simulations of transient enhanced diffusion following 20-80 keV B implants into Si, and with those of 50 keV Si implants into complex B-doped structures. Our simulations predict novel behavior of the time evolution of the electrically active B fraction during annealing.

1999-03-01

398

Assessment of GABARAP self-association by its diffusion properties  

Energy Technology Data Exchange (ETDEWEB)

Gamma-aminobutyric acid type A receptor-associated protein (GABARAP) belongs to a family of small ubiquitin-like adaptor proteins implicated in intracellular vesicle trafficking and autophagy. We have used diffusion-ordered nuclear magnetic resonance spectroscopy to study the temperature and concentration dependence of the diffusion properties of GABARAP. Our data suggest the presence of distinct conformational states and provide support for self-association of GABARAP molecules. Assuming a monomer-dimer equilibrium, a temperature-dependent dissociation constant could be derived. Based on a temperature series of {sup 1}H{sup 15}N heteronuclear single quantum coherence nuclear magnetic resonance spectra, we propose residues potentially involved in GABARAP self-interaction. The possible biological significance of these observations is discussed with respect to alternative scenarios of oligomerization.

2010-09-15

399

A nodal integral method for neutron diffusion in hexagonal geometry  

International Nuclear Information System (INIS)

A nodal integral method is derived for the monoenergetic, steady-state, fixed source neutron diffusion equation in hexagonal geometry based on a coordinate transformation that maps a parallelogram into a rectangle. The new hexagonal nodal diffusion method is implemented in the computer code HND where the discrete-variable equations are solved via an iterative scheme. Because the new method's equations are derived for a rhombus, they can be solved on a sequence of embedded meshes to study the method's error order. Indeed a preliminary numerical error analysis reveals a second-order error in the mesh size, and comparison with finite difference results obtained with the finite difference based BOLD-VENTURE code indicate the superior accuracy of our new nodal method.

1992-03-08

400

A combined interpretation of cosmic ray and antiproton high energy measurements  

Energy Technology Data Exchange (ETDEWEB)

In the last months several ballon and satellite experiments improved significantly our knowledge of cosmic ray (CR) spectra at high energy. In particular CREAM allowed to measure B/C, C/O and N/O ratios up to 1 TeV/n and PAMELA the anti p/p ratio up to 100 GeV with unprecedented accuracy. These measurements offer a valuable probe of CR propagation properties. We performed a statistical analysis to test the compatibility of these results, as well as other most significant experimental data, with the predictions of a new numerical CR diffusion package (DRAGON). We found that above 1 GeV/n all data are consistent with a plain diffusion scenario and point to well defined ranges for the normalization and energy dependence of the diffusion coefficient. (orig.)

2009-09-15

401

Radioactive iodine absorbing properties of tetrathiafulvalene  

Energy Technology Data Exchange (ETDEWEB)

For the purpose of searching some effective absorbents of gaseous radioactive iodine, 16 substances considered as having an affinity for iodine were investigated with regular iodine and /sup 125/I. In a preliminary survey, only tetrathiafulvalene (TTF) was found to have satisfactory absorbing properties comparable to activated charcoal. A further detailed comparison of the properties between TTF and activated charcoal led us to the conclusion that the former has more preferable properties as absorbent of radioactive iodine than the latter in all points studied. The results are summarized as follows: (1) The absorption of iodine on TTF in atmosphere was about twice as much as that on activated charcoal. Desorption of iodine from saturatedly absorbed iodine on TTF was practically negligible except trace amount of initial desorption, while that on activated charcoal was considerable (3%/50h) even in the air at room temperature. (2) Absorbed amount of iodine on ...

1989-05-01

402

Evaluation of the impact of RCRA amendments on waste-to-energy activities by using a system simulation computer code  

Energy Technology Data Exchange (ETDEWEB)

The primary methodology that is used for disposal of municipal solid waste is the use of land fills; 80--85% of the municipal solid waste (MSW) produced in the country currently is land filled. The two other disposal alternatives used are recycling and incineration. Waste-to-energy technology (WTE) which incinerates MSW to produce electricity and/or steam is attractive in other cases since it reduces landfill volume, reduces the consumption of fossil and other fuels, and produces a revenue stream from the sale of the electricity or steam. The gaseous effluents from landfills can also be used to fuel power plants. Recycling and material separation programs can have a substantial impact on the throughput and heating value of MSW collected and thus impact WTE plant economics; the magnitude of the impact will depend upon a number of factors such as what materials and what fraction are separated and recycled, the design of the WTE plant itself (its operating window); ...

1994-09-01

403

Environmental benefits and economic rationale of expanding the Italian natural gas private car fleet  

International Nuclear Information System (INIS)

There are several concerns which bring to consider natural gas as a viable alternative to liquid fuels in transport. First, natural gas allows the curbing of global pollution in this steadily growing industry. Indeed, decoupling greenhouse gas emissions from transport growth has become a major issue in tackling climate change. Second, a more extensive use of natural gas would relieve city air quality, which is presently at levels harmful of human health. Nonetheless, this is just one side of the coin. The other side entails building a refuelling station network, and this carries financial requirements. The financing fraction holds a pivotal role in deciding whether natural gas for automotive purposes is an efficient solution. The final aim of this work is, therefore, to compare the natural gas advantages, stemming from avoided global and local emission, with the economic rationale of engaging in supplementary model network investments. A system dynamics model underlies this study's ...

2005-01-01

405

Use of Microelectrode Arrays to Directly Measure Diffusion of ...  

Science.gov (United States)

... F.; Murray, R. W. J. Am. Chem. ... 14. Thackeray, J. W.; White, H. S.; Wrighton, M. SJ Phys. ... Dr. James S. Murday (1) Dr. Harold H. Singerman (i) ...

1990-05-16

406

Treatment of acid-effluent by diffusion-dialysis and acid-retardation. Kakusan tosekiho, acid retardation ho ni yoru haisan no shori  

Energy Technology Data Exchange (ETDEWEB)

Recently, in various production engineering of inorganic chemistry system, a large quantity of acids such as nitric acid and hydrocholoric acid have been used, the examples that acid and slats with high concentration are included in the sewer, treatment technique of acid-effluent in the sewer has been known as the diffusion-dialysis, acid-retardation using anion exchange resin. In this report, treatment and properties of acid-effluent recovery and effect of a coexisting slat by the diffusion-dialysis and acid retardation were compared. In the acid retardation, the concentration beyond the solution system can be recovered when the flow interval between waste acid and water was selected appropriately. In the diffusion-dialysis, it has a tendency that rate of recovery was low in the week acid. However, even in the case of which metal irons form complex anion, it is possible that acid and slat were separated well. 7 refs., 11 ...

1992-03-10

407

The influence of mucus on the diffusion of chloride ions across the oesophagus of the minnow (Phoxinus phoxinus (L.].  

UK PubMed Central (United Kingdom)

Micro-electrodes sensitive to Cl- have been used to measure Cl- activities in the mucous layer on the mucosal surface of an isolated oesophageal preparation of the fresh-water teleost, Phoxinus phoxinus...Full Text Available

1984-01-01

408

Temperature and current coefficients of lasing wavelength in tunable diode laser spectroscopy  

UK PubMed Central (United Kingdom)

The factors determining temperature and current coefficients of lasing wavelength are investigated and discussed under monitoring CO2-gas absorption spectra. The diffusion rate of...Full Text Available

2010-08-01

409

Temperature Dependence of Structure, Bending Rigidity, and Bilayer Interactions of Dioleoylphosphatidylcholine Bilayers  

UK PubMed Central (United Kingdom)

X-ray diffuse scattering was measured from oriented stacks and unilamellar vesicles of dioleoylphosphatidylcholine lipid bilayers to obtain the temperature dependence of the structure and of the material...Full Text Available

2008-01-01

410

Submergence-Induced Morphological, Anatomical, and Biochemical Responses in a Terrestrial Species Affect Gas Diffusion Resistance and Photosynthetic Performance  

UK PubMed Central (United Kingdom)

Gas exchange between the plant and the environment is severely hampered when plants are submerged, leading to oxygen and energy deficits. A straightforward way to reduce these shortages of oxygen and...Full Text Available

2005-09-01

411

Self-organization of nickel atoms in silicon  

British Library Electronic Table of Contents (United Kingdom)

We present experimental evidence for self-organization of nickel microparticles in silicon under certain thermodynamic conditions of nickel diffusion doping. The concentration and distribution of the microparticles in silicon are very uniform. Additional anneals lead to self-ordering of the impurity microparticles.

2011-01-01

412

SAES(R) ST909 Bench Scale Methane Cracking Tests  

Energy Technology Data Exchange (ETDEWEB)

Bench Scale methane cracking tests have been completed using a stack of ten whole SAES(R) St909 pellets - a 6 gram sample size. Methane was found to be the most difficult impurity to process and can impact diffuser operation.

2001-09-25

413

SAES(R) ST909 Bench Scale Methane Cracking Tests  

International Nuclear Information System (INIS)

Bench Scale methane cracking tests have been completed using a stack of ten whole SAES(R) St909 pellets - a 6 gram sample size. Methane was found to be the most difficult impurity to process and can impact diffuser operation.

2001-09-01

414

Relativistic Feynman-type integrals  

Energy Technology Data Exchange (ETDEWEB)

It is shown that within the framework of the Kershaw stochastic model generalized by the author to the relativistic case a Feynman-type process may be constructed which can formally be understood as a diffusion phenomenon in Euclidean space. This makes it possible to introduce a real probability measure in the scheme of quantum mechanics proposed by Feynman.

1980-05-01

415

Reduction of transient diffusion from 1{endash}5 keV Si{sup +} ion implantation due to surface annihilation of interstitials  

Energy Technology Data Exchange (ETDEWEB)

The reduction of transient enhanced diffusion (TED) with reduced implantation energy has been investigated and quantified. A fixed dose of 1{times}10{sup 14} cm{sup {minus}2} Si{sup +} was implanted at energies ranging from 0.5 to 20 keV into boron doping superlattices and enhanced diffusion of the buried boron marker layers was measured for anneals at 810, 950, and 1050{degree}C. A linearly decreasing dependence of diffusivity enhancement on decreasing Si{sup +} ion range is observed at all temperatures, extrapolating to {approximately}1 for 0 keV. This is consistent with our expectation that at zero implantation energy there would be no excess interstitials from the implantation and hence no TED. Monte Carlo modeling and continuum simulations are used to fit the experimental data. The results are consistent with a surface recombination length for interstitials of {lt}10 nm. The data presented here demonstrate that in the ...

1997-11-01

416

Reduction of transient diffusion from 1 endash 5 keV Si"+ ion implantation due to surface annihilation of interstitials  

International Nuclear Information System (INIS)

The reduction of transient enhanced diffusion (TED) with reduced implantation energy has been investigated and quantified. A fixed dose of 1x10"1"4 cm"-"2 Si"+ was implanted at energies ranging from 0.5 to 20 keV into boron doping superlattices and enhanced diffusion of the buried boron marker layers was measured for anneals at 810, 950, and 1050 degree C. A linearly decreasing dependence of diffusivity enhancement on decreasing Si"+ ion range is observed at all temperatures, extrapolating to #approx#1 for 0 keV. This is consistent with our expectation that at zero implantation energy there would be no excess interstitials from the implantation and hence no TED. Monte Carlo modeling and continuum simulations are used to fit the experimental data. The results are consistent with a surface recombination length for interstitials of <10 nm. The data presented here demonstrate that in the range of annealing temperatures of ...

417

Radon-mitigation in buildings  

International Nuclear Information System (INIS)

From the indoor radon problem arises a great challenge for the radiation protection of the population. The soil can be considered as the only source for high radon concentrations in buildings. The contribution of common building materials to high indoor concentrations with a range of 30 Bq/m"3 is negligible low. Therefore building materials for radon mitigation should be judged by their tightness against diffusive radon and not by their radon exhalation rate. Also isolation materials for mitigation should be radon tight. The radon diffusion coefficient describes the physical processes in relatively homogeneous samples. The diffusion coefficient D and the diffusion length R are very exactly determined by a self engineered measuring method. The range of D reaches from D = (0.0005 to 2.35) . 10"-"6 m"2/s for building materials and from D = (0.07 to < 10"-"6) . 10"-"6 m"2/s for isolation materials. ...

418

Radon concentration measurement in dwellings in Belgrade  

International Nuclear Information System (INIS)

The results of the radon concentration measurements in dwellings in Belgrade were shown in this paper. The measurements were done using long term method with diffusion cups equipped with solid state nuclear track detector LR-115-II or CR-39. (author).

419

Predictions of nitrogen oxides production in diffusion turbulent flames; Predictions de la production des oxydes d`azote dans les flammes turbulentes de diffusion  

Energy Technology Data Exchange (ETDEWEB)

The suitability of the turbulent combustion flamelets model in order to predict the index of NO{sub x} production in turbulent flames of hydrogen diffusion is analyzed. In the flamelet approach, the turbulent flame is equivalent to a group of laminar flames submitted to a mechanical stretching which generates a chemical disequilibrium. This effect can be described by the stretching or by the scalar dissipation ratio. A numerical modeling is performed in order to evaluate the advantages of both approaches and to compare the behaviour of the NO{sub x} emission index with the experiments of Chen and Driscoll. This study shows that predictions of NO{sub x} emission indexes have a correct behaviour with respect to the Damkoehler number only when the scalar dissipation ratio is used as a parameter to describe the chemical state outside equilibrium. Predictions of the flamelet models are improving when the Damkoehler number increases. On the other hand, the absolute ...

1996-12-31

420

Photographic measurements of the diffuse light in the coma cluster  

International Nuclear Information System (INIS)

The diffuse background light in the Coma cluster is measured using isodensity tracings of B, G, V, and R photographic plates taken with the Palomar 1.2-m Schmidt telescope. The isodensity contours are calibrated using the star profile derived by Kormendy (1973). Between 4 and 14 arc min from the center, the surface brightness of the diffuse light decreases from approximately 26 to approximately 28 G magnitudes arc sec"-"2. The total magnitude in this annulus is G = 11.22, which is approximately 45 percent of the light in galaxies alone, or approximately 30 percent of the total. This does little to alleviate the ''missing mass'' problem. The isodensity contours and the equivalent profile of the diffuse light closely parallel the distribution of light in galaxies, implying no strong mass segregation. However, the background light appears to be bluer than the galaxies. This is consistent with the hypothesis that the background ...

421

Online quasi-continuous measurement of organic acids in the atmosphere  

Energy Technology Data Exchange (ETDEWEB)

The concentration of some organic acids in the atmosphere was determined using a wet effluent diffusion denuder-aerosol collector coupled with Ion Chromatography. Three organic acids and four inorganic anions were identified and quantified in the air sample, taken from the backyard of PSI. (author)

2002-03-01

422

Nonnegative Factorization of Diffusion Tensor Images and Its Applications  

UK PubMed Central (United Kingdom)

This paper proposes a novel method for computing linear basis images from tensor-valued image data. As a generalization of the nonnegative matrix factorization, the proposed method aims to approximate...Full Text Available

2011-01-01

427

Modeling the suppression of boron transient enhanced diffusion in silicon by substitutional carbon incorporation  

Energy Technology Data Exchange (ETDEWEB)

Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si{sub 1-x-y}Ge{sub x}C{sub y} during 750{sup o}C inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes {l_brace}311{r_brace} defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional (C{sub i}C{sub s}) pairing reaction that successfully simulates ...

2001-08-15

428

Modeling the suppression of boron transient enhanced diffusion in silicon by substitutional carbon incorporation  

International Nuclear Information System (INIS)

Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si_1_-_x_-_yGe_xC_y during 750"oC inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes #left brace#311#right brace# defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional (C_iC_s) pairing reaction that successfully simulates carbon suppression ...

2001-08-15

429

Metal atom diffusion in amorphous silica and at the silica surface. Progress report, December 1, 1982-December 1, 1983  

Energy Technology Data Exchange (ETDEWEB)

Objective is to study the effects of local structure, interatomic forces, and atom size on the mobility of metal atoms in amorphous silica and at the silica surface. EXAFS studies of Zn and Pt in silica are reported. (DLC)

1983-01-01

430

Mechanistic insights from a quantitative analysis of pollen tube guidance  

UK PubMed Central (United Kingdom)

BackgroundPlant biologists have long speculated about the mechanisms that guide pollen tubes to ovules. Although there is now evidence that ovules emit a diffusible attractant, little...Full Text Available

431

Mechanisms controlling the leaching kinetics of fixated flue gas desulfurization (FGD) material under neutral and acidic conditions.  

Science.gov (United States)

A number of agricultural and engineering uses for fixated flue gas desulfurization (FGD) material exist; however, the potential for leaching of hazardous elements has limited widespread application and the processes controlling the leaching of this material are poorly understood. In this study, a flow-through rotating-disk system was applied to elucidate the relative importance of bulk diffusion, pore diffusion, and surface chemical reaction in controlling the leaching of fixated FGD material under pH conditions ranging from 2.2 to 6.8. Changing the hydrodynamics in the rotating disk system did not affect the leaching kinetics at both pH 2.2 and 6.8, indicating that bulk diffusion was not the kinetic-limiting step. Application of the shrinking core model (SCM) to the data suggested a surface reaction-controlled mechanism, rather than a pore diffusion mechanism. The leaching of fixated FGD material ...

2007-05-07

432

Low-temperature radiation controlled diffusion of palladium and platinum in silicon for advanced lifetime control  

International Nuclear Information System (INIS)

Radiation defects produced by helium implantation were used to shape profiles of palladium (Pd) and platinum (Pt) atoms in-diffusing (for 20 min at temperatures 600-800 deg. C) either from surface silicide (Pd_2Si, PtSi) or implanted layers. Results show that this procedure allows a strong localization of substitutional Pd and Pt at the depth where the damage produced by helium peaks. This results in local reduction of carrier lifetime by an almost ideal recombination centers - the acceptor level of substitutional Pd (E _c - 0.22 eV) or Pt (E _c - 0.23 eV). While optimum conditions for Pt in-diffusion are about 700 deg. C, Pd gives the best results already at lower temperatures (600 deg. C) where it also exhibits higher peak solubility. Both methods were used for optimization of turn-off properties of high power PiN diodes. The devices, where the lifetime was killed locally by Pd and Pt, exhibited similar trade-off between the static and ...

2006-12-01

433

Low energy boron implantation in silicon: (1) reduction of channeling tail by careful alignments. (2) Transient diffusion during rapid thermal annealing  

Energy Technology Data Exchange (ETDEWEB)

An attempt was made to minimize the channeling tail by implantation along a random equivalent direction following a careful alignment of the target. In order to analytically determine the random equivalent directions, critical angles for channeling were mapped on a stereogram. Boron ions with energies of 17 and 45 keV are implanted along specified directions determined from the map. The depth distribution of the dopant is profiled by SIMS and the effects of water orientation upon the channeling tail are noted. Industrial common use of a 7/sup 0/ tilt is not optimum. However, implantation with the wafer tilted at 5.5 +/- 0.5/sup 0/ from the surface normal and rotated at 7.0 +/- 0.5/sup 0/ from a (100) plane shows the least channel-tail compared to implantation along other directions. Rapid thermal annealing (RTA) is a promising annealing method for shallow junction formation. Transient enhanced diffusion of implanted boron is observed. Two different mechanisms for ...

1985-01-01

434

Low energy boron implantation in silicon: (1) reduction of channeling tail by careful alignments. (2) Transient diffusion during rapid thermal annealing  

International Nuclear Information System (INIS)

An attempt was made to minimize the channeling tail by implantation along a random equivalent direction following a careful alignment of the target. In order to analytically determine the random equivalent directions, critical angles for channeling were mapped on a stereogram. Boron ions with energies of 17 and 45 keV are implanted along specified directions determined from the map. The depth distribution of the dopant is profiled by SIMS and the effects of water orientation upon the channeling tail are noted. Industrial common use of a 7"0 tilt is not optimum. However, implantation with the wafer tilted at 5.5 +/- 0.5"0 from the surface normal and rotated at 7.0 +/- 0.5"0 from a (100) plane shows the least channel-tail compared to implantation along other directions. Rapid thermal annealing (RTA) is a promising annealing method for shallow junction formation. Transient enhanced diffusion of implanted boron is observed. Two different mechanisms for the boron ...

435

Kinetic Monte Carlo (KMC) simulations for boron diffusion in ion-implanted crystalline materials  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we report kinetic Monte Carlo study on the diffusion behavior of boron in silicon crystal, more particularly on the transient enhanced diffusion (TED) of boron in silicon during implantation and annealing. Firstly, the accuracy of our KMC code was verified by investigating the time evolutionary behavior of interstitial (I) and vacancy (V) when a silicon substrate is implanted with silicon dose with an energy of 10 keV and with a dose of 1 X 10{sup 14} ions/cm{sup 2}. To investigate the influence of native defects (I, V) on boron diffusion, a single and multi boron markers grown by MBE were employed. The simulation results revealed that the precursor of boron cluster (BI{sub 2}) is dominant at the initial stage of annealing, which explains the boron TED phenomenon in terms of the concentration of boron complexes and I, V clusters, respectively. The formation of {l_brace}311{r_brace} defects and dislocation ...

2004-11-15

436

Kinetic Monte Carlo (KMC) simulations for boron diffusion in ion-implanted crystalline materials  

International Nuclear Information System (INIS)

In this paper, we report kinetic Monte Carlo study on the diffusion behavior of boron in silicon crystal, more particularly on the transient enhanced diffusion (TED) of boron in silicon during implantation and annealing. Firstly, the accuracy of our KMC code was verified by investigating the time evolutionary behavior of interstitial (I) and vacancy (V) when a silicon substrate is implanted with silicon dose with an energy of 10 keV and with a dose of 1 X 10"1"4 ions/cm"2. To investigate the influence of native defects (I, V) on boron diffusion, a single and multi boron markers grown by MBE were employed. The simulation results revealed that the precursor of boron cluster (BI_2) is dominant at the initial stage of annealing, which explains the boron TED phenomenon in terms of the concentration of boron complexes and I, V clusters, respectively. The formation of #left brace#311#right brace# defects and dislocation loop were ...

2004-11-01

437

Investigating radon transport through different saudi building materials  

International Nuclear Information System (INIS)

Radon has been recognized by various international health organizations as a major lung carcinogen. The onset of cellular carcinogenesis involves DNA damage to bronchi epithelial cells by particles emitted by radon progeny. Radon diffusion is an important release mechanism for radon that is produced inside a building material. The physical parameter that characterizes this process is the radon diffusion Coefficient D(m-2 s-l). The diffusion constant and Diffusion length has been measured as 2.15xl0- 6 m-2s-1, 1.01m for soil, 1.65x10-6m-2s-1, 0.89m for sand and 0.21x 10-6m-2s-1, 0.31m for crush aggregate saudi building materials respectively. The values are found to be minimum for crush aggregates, which shows that crush aggregate is least permeable to radon flow as compared with the other building materials studied. (author)

2007-06-01

438

Intracellular pH in adipocytes: effects of free fatty acid diffusion across the plasma membrane, lipolytic agonists, and insulin.  

UK PubMed Central (United Kingdom)

The main function of white adipose tissue is to store nutrient energy in the form of triglycerides. The mechanism by which free fatty acids (FFA) move into and out of the adipocyte has not been resolved....Full Text Available

1996-09-17

439

Interdiffusion of molybdenum in high-alloy austenitic CrNiMo(N)-steels. Chemische Diffusion von Molybdaen in hochlegierten austenitischen CrNiMo(N)-Staehlen  

Energy Technology Data Exchange (ETDEWEB)

The volume diffusion of Mo in austenitic CrNiMo(N)-steels was studied using the sandwich method. Accordingly the interdiffusion coefficients of Mo were found to be independent of its concentration for the given steel composition with 12 to 19 wt.% Cr, 12 to 16 wt.% Ni, 0 to 2 wt.% Mo and 0 to 0.27 wt.% N and within the temperature range from 1283 to 1523 K. The diffusivity of Mo is greater than that of Cr, Ni and Fe in such steels. The diffusion parameters of Mo are decreased by alloying addition of nearly 0.25 wt.% N in steel; possibly as a result of lattice expansion or increasing vacancy concentration caused by N. Small variations in Cr and Ni initial contents of examined specimens showed negligible effect on the absolut values of interdiffusion coefficients of Mo. (orig.).

1991-08-01

440

Improvement of top shield analysis technology for CANDU 6 reactor.  

Science.gov (United States)

As for Wolsung NPP unit 1, radiation shielding analysis was performed by using neutron diffusion codes, one-dimensional discrete ordinates code ANISN, and analytical methods. But for Wolsung NPP unit 2, 3, and 4, two-dimensional discrete ordinates code DO...

1996-01-01

441

Impact of diffuse nitrate pollution sources on groundwater quality--some examples from Czechoslovakia.  

UK PubMed Central (United Kingdom)

In several regions of Czechoslovakia with intensive agricultural production, the correlation between the amount of nitrogen fertilizer applied and the nitrate content in groundwater has been recognized....Full Text Available

1989-11-01

442

Hydrogen in metals  

International Nuclear Information System (INIS)

An important application of metal hydrides is as a moderator material in nuclear reactors. The fundamental properties of hydrides are illustrated and an impression given of the current research into hydrogen in transition metals. Phase diagrams, magnetic properties, temperature dependence of the diffusion coefficient, energy level schemes and superconductivity are considered. (C.F.).

443

Formation of stable dopant interstitials during ion implantation of silicon  

Energy Technology Data Exchange (ETDEWEB)

High concentrations of self-interstitials are trapped by dopant atoms during ion implantation into Si. For group V dopants, these complexes are sufficiently stable to survive solid-phase-epitaxial (SPE) growth but break up on subsequent thermal processing and cause a transient-enhanced diffusion. Dopant diffusion coefficients are enhanced by up to five orders of magnitude over tracer values and are characterized by an activation energy of approximately one half of the tracer values. In the case of group III dopants, any complexes formed during implantation do not survive SPE growth but a second source of self-interstitials becomes significant and leads to similar transient effects. This is the damaged layer underlying the original amorphous/crystalline interface. These observations provide direct evidence for long-range self-interstitial migration in Si, and we believe these are the first observations of the interstitialcy ...

1986-05-01

444

Formation of stable dopant interstitials during ion implantation of silicon  

International Nuclear Information System (INIS)

High concentrations of self-interstitials are trapped by dopant atoms during ion implantation into Si. For group V dopants, these complexes are sufficiently stable to survive solid-phase-epitaxial (SPE) growth but break up on subsequent thermal processing and cause a transient-enhanced diffusion. Dopant diffusion coefficients are enhanced by up to five orders of magnitude over tracer values and are characterized by an activation energy of approximately one half of the tracer values. In the case of group III dopants, any complexes formed during implantation do not survive SPE growth but a second source of self-interstitials becomes significant and leads to similar transient effects. This is the damaged layer underlying the original amorphous/crystalline interface. These observations provide direct evidence for long-range self-interstitial migration in Si, and we believe these are the first observations of the interstitialcy ...

445

Enhanced diffusion of dopants in vacancy supersaturation produced by MeV implantation  

Energy Technology Data Exchange (ETDEWEB)

The diffusion of Sb and B markers has been studied in vacancy supersaturations produced by MeV Si implantation in float zone (FZ) silicon and bonded etch-back silicon-on-insulator (BESOI) substrates. MeV Si implantation produces a vacancy supersaturated near-surface region and an interstitial-rich region at the projected ion range. Transient enhanced diffusion (TED) of Sb in the near surface layer was observed as a result of a 2 MeV Si{sup +}, 1 {times} 10{sup 16}/cm{sup 2}, implant. A 4{times} larger TED of Sb was observed in BESOI than in FZ silicon, demonstrating that the vacancy supersaturation persists longer in BESOI than in FZ. B markers in samples with MeV Si implant showed a factor of 10{times} smaller diffusion relative to markers without the MeV Si{sup +} implant. This data demonstrates that a 2 MeV Si{sup +} implant injects vacancies into the near surface region.

1997-04-01

446

Effects of intersegmental transfers on target location by proteins  

CERN Document Server

We study a model for a protein searching for a target, using facilitated diffusion, on a DNA molecule confined in a finite volume. The model includes three distinct pathways for facilitated diffusion: (a) sliding - in which the protein diffuses along the contour of the DNA (b) jumping - where the protein travels between two sites along the DNA by three-dimensional diffusion, and finally (c) intersegmental transfer - which allows the protein to move from one site to another by transiently binding both at the same time. The typical search time is calculated using scaling arguments which are verified numerically. Our results suggest that the inclusion of intersegmental transfer (i) decreases the search time considerably (ii) makes the search time much more robust to variations in the parameters of the model and (iii) that the optimal search time occurs in a regime very different than that found for models ...

2008-01-01

447

Effect of energy and dose on transient-enhanced diffusion and defect microstructure in low energy high dose As{sup +} implanted Si  

Energy Technology Data Exchange (ETDEWEB)

(001) CZ silicon wafers were implanted with arsenic (As{sup +}) at energies of 10--50 keV to doses of 2 {times} 10{sup 14} to 5 {times} 10{sup 15}/cm{sup 2}. All implants were amorphizing in nature. The samples were annealed at 700 C for 16 hrs. The resultant defect microstructures were analyzed by XTEM and PTEM and the As profiles were analyzed by SIMS. The As profiles showed significantly enhanced diffusion in all of the annealed specimens. The diffusion enhancement was both energy and dose dependent. The lowest dose implant/annealed samples did not show As clustering which translated to a lack of defects at the projected range. At higher doses, however, projected range defects were clearly observed, presumably due to interstitials generated during As clustering. The extent of enhancement in diffusion and its relation to the defect microstructure is explained by a combination of factors including surface recombination of ...

1997-11-01

448

Effect of energy and dose on transient-enhanced diffusion and defect microstructure in low energy high dose As"+ implanted Si  

International Nuclear Information System (INIS)

(001) CZ silicon wafers were implanted with arsenic (As"+) at energies of 10--50 keV to doses of 2 x 10"1"4 to 5 x 10"1"5/cm"2. All implants were amorphizing in nature. The samples were annealed at 700 C for 16 hrs. The resultant defect microstructures were analyzed by XTEM and PTEM and the As profiles were analyzed by SIMS. The As profiles showed significantly enhanced diffusion in all of the annealed specimens. The diffusion enhancement was both energy and dose dependent. The lowest dose implant/annealed samples did not show As clustering which translated to a lack of defects at the projected range. At higher doses, however, projected range defects were clearly observed, presumably due to interstitials generated during As clustering. The extent of enhancement in diffusion and its relation to the defect microstructure is explained by a combination of factors including surface recombination of point defects, As ...

1996-12-02

449

Diffusion mechanism of implanted Be in GaAs  

Energy Technology Data Exchange (ETDEWEB)

The transient enhanced diffusion of low and high dose implanted beryllium in undoped gallium arsenide during post-implant rapid thermal annealing in the temperature range of 700-900 C for 60-240 s has been studied and successfully simulated by the kick-out diffusion model, involving singly positively charged Be interstitials and doubly positively charged Ga self-interstitials. Using the ''plus one'' approach for Ga interstitial generation after implantation with the local Ga interstitial sink concept as well as the appropriate initial and boundary conditions for involved mobile species, and taking into account Fermi-level and built-in electric field effects, the obtained partial differential equations have been solved numerically by means of an explicit finite difference method. The thermal equilibrium concentrations and the diffusivities of Be and Ga interstitials, all as a function of ...

2008-01-15

450

Diffuse $\\gamma$-rays and $\\bar{p}$ flux from dark matter annihilation -- a model for consistent results with EGRET and cosmic ray data  

CERN Document Server

In this work we develop a new propagation model for the Galactic cosmic rays based on the GALPROP code, including contributions from dark matter annihilation. The model predicts compatible Galactic diffuse $\\gamma$ ray spectra with EGRET data in all sky regions. It also gives consistent results of the diffuse $\\gamma$ ray longitude and latitude distributions. Further the results for B/C, $^{10}$Be/$^9$Be, proton, electron and antiproton spectra are also consistent with cosmic ray measurements. In the model we have taken a universal proton spectrum throughout the Galaxy without introducing large fluctuation for the proton energy loss is negligible. The dark matter annihilation signals are `boosted' after taking the contribution from subhalos into account. Another interesting feature of the model is that it gives better description of the diffuse $\\gamma$ rays when taking the source distribution compatible with supernova ...

2007-01-01

451

Determination of the radon diffusion coefficient and radon exhalation rate in Moroccan quaternary samples using the SSNTD technique  

International Nuclear Information System (INIS)

Measurements have been made of radon ("2"2"2Rn), release from diverse quaternary samples collected from different sediment deposits in the Errachidia and Beni-Mellal areas (Morocco). The radon diffusion coefficient as one of some important parameters of radon transport in the soil has been measured using solid state nuclear track detectors (SSNTD). Radon #alpha#-activity, uranium content and radon exhalation rate have been determined in the studied samples. Uranium concentrations were found to vary from 0.14 to 9.52 ppm whereas the radon exhalation rate varied from 0.003 to 0.145 Bq x m"-"2 x h"-"1. A positive correlation has been found between radon exhalation rate and uranium content in the studied samples. The average radon diffusion coefficients were found to vary from (1.26 #+-# 0.09) x 10"-"6 m"2 x s"-"1 to (4.3 #+-# 0.36) x 10"-"6 m"2 x s"-"1. Furthermore, the correlation between "2"2"2Rn diffusion coefficient and ...

2003-06-01

452

Default Times in a Continuous-Time Markovian Regime Switching Model  

British Library Electronic Table of Contents (United Kingdom)

We investigate the default time of a firm when a stochastic discount factor is used so that both diffusion and regime switching risks are priced. We establish the relationship between the probability distribution of the default time and the solution of a system of coupled partial differential equations.

2011-01-01

453

Control of diffusion of implanted boron in preamorphized Si: Elimination of interstitial defects at the amorphous-crystal interface  

Energy Technology Data Exchange (ETDEWEB)

Transient-enhanced diffusion (TED) during thermal annealing of ion-implanted B in Si is well established and attributed to the ion-induced, excess interstitials. On the other hand, the mechanism to account for TED of B in preamorphized (PA) Si remains unclear. Enhanced diffusion of the B persists in regrown layers even though the ion-induced interstitial defects responsible for TED in B{sup +}-only implanted Si are eliminated following regrowth. To test the hypothesis that TED in PA Si results from the {open_quotes}excess{close_quotes} interstitial-type defects below the amorphous-crystalline (a-c) interface, a buried PA layer has been recrystallized from the surface inward to the SiO{sub 2} interface of silicon-on-insulator material to eliminate all possible sources of excess interstitials. The effect on B diffusion and the role of the residual interstitial-type defects will be discussed. {copyright} {ital 1999 American ...

1999-02-01

454

Configurational diffusion of coal macromolecules  

Energy Technology Data Exchange (ETDEWEB)

The objective of our research was to obtain fundamental information regarding the functional dependence of the diffusion coefficient of coal molecules on the ratio of molecule to pore diameter. That is, the objective of our study was to examine the effect of molecule size and configuration on hindered diffusion of coal macromolecules through as porous medium. To best accomplish this task, we circumvented the complexities of an actual porous catalyst by using a well defined porous matrix with uniform capillaric pores, i.e., a track-etched membrane. In this way, useful information was obtained regarding the relationship of molecular size and configuration on the diffusion rate of coal derived macromolecules through a pore structure with known geometry. Similar studies were performed using a pellet formed of porous alumina, to provide a link between the idealized membranes and the actual complex pore structure of real catalyst ...

1991-01-01

455

Complex Spatio-Spectral Structure of Diffuse X-Ray emission in the ...  

Science.gov (United States)

SN 1987A: Soft X-Ray Intensity Ratio. 2002-12 to 2000-12. 2005-7 to 2002-12. Contours: 2002-12. (0.5 2 keV). (0.5 2 keV). Contours: 2005-7 ...

456

Clinical evaluation of life size image of Fuji computed radiography for detection of diffuse interstitial lung diseases  

Energy Technology Data Exchange (ETDEWEB)

To evaluate the diagnostic accuracy of Fuji computed radiography (FCR) in the detection of interstitial pulmonary infiltrates, FCR life-size images at a pixel size of 0.1 mm were compared with conventional radiographs taken on the same day. Seventeen radiologists assessed the radiographs and FCR images of 56 cases, including 39 cases of various interstitial lung diseases such as interstitial pneumonia, pulmonary abnormalities associated with collagen disease, sarcoidosis, multiple pulmonary metastases, diffuse panbronchiolitis and pulmonary emphysema, and 17 normal controls. All of the pulmonary abnormalities were confirmed by high resolution CT. Observer performance tests were carried out using receiver operating characteristic analysis. In 21 cases of increased pulmonary density revealed by high resolution CT, FCR was significantly superior to conventional radiographs in the detection of reticular or linear shadows. In 11 cases of subtle interstitial ...

1991-11-01

457

Clinical evaluation of life size image of Fuji computed radiography for detection of diffuse interstitial lung diseases  

International Nuclear Information System (INIS)

To evaluate the diagnostic accuracy of Fuji computed radiography (FCR) in the detection of interstitial pulmonary infiltrates, FCR life-size images at a pixel size of 0.1 mm were compared with conventional radiographs taken on the same day. Seventeen radiologists assessed the radiographs and FCR images of 56 cases, including 39 cases of various interstitial lung diseases such as interstitial pneumonia, pulmonary abnormalities associated with collagen disease, sarcoidosis, multiple pulmonary metastases, diffuse panbronchiolitis and pulmonary emphysema, and 17 normal controls. All of the pulmonary abnormalities were confirmed by high resolution CT. Observer performance tests were carried out using receiver operating characteristic analysis. In 21 cases of increased pulmonary density revealed by high resolution CT, FCR was significantly superior to conventional radiographs in the detection of reticular or linear shadows. In 11 cases of subtle interstitial ...

1991-01-01

458

Changes of the surface-to-volume ratio and diffusion coefficient of fission gas in fuel pellets during irradiation  

International Nuclear Information System (INIS)

Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not clearly observed. In addition, it is likely that the restructuring effect of fuel pellet on the ...

2010-07-31

459

Atomistic calculations of ion implantation in Si: Point defect and transient enhanced diffusion phenomena  

Energy Technology Data Exchange (ETDEWEB)

A new atomistic approach to Si device process simulation is presented. It is based on a Monte Carlo diffusion code coupled to a binary collision program. Besides diffusion, the simulation includes recombination of vacancies and interstitials, clustering and re-emission from the clusters, and trapping of interstitials. We discuss the simulation of a typical room-temperature implant at 40 keV, 5{times}10{sup 13} cm{sup {minus}2} Si into (001)Si, followed by a high temperature (815{degree}C) anneal. The damage evolves into an excess of interstitials in the form of extended defects and with a total number close to the implanted dose. This result explains the success of the {open_quote}{open_quote}+1{close_quote}{close_quote} model, used to simulate transient diffusion of dopants after ion implantation. It is also in agreement with recent transmission electron microscopy observations of the number of interstitials stored in ...

1996-01-01

460

Atomistic calculations of ion implantation in Si: Point defect and transient enhanced diffusion phenomena  

International Nuclear Information System (INIS)

A new atomistic approach to Si device process simulation is presented. It is based on a Monte Carlo diffusion code coupled to a binary collision program. Besides diffusion, the simulation includes recombination of vacancies and interstitials, clustering and re-emission from the clusters, and trapping of interstitials. We discuss the simulation of a typical room-temperature implant at 40 keV, 5x10"1"3 cm"-"2 Si into (001)Si, followed by a high temperature (815 degree C) anneal. The damage evolves into an excess of interstitials in the form of extended defects and with a total number close to the implanted dose. This result explains the success of the open-quote open-quote+1 close-quote close-quote model, used to simulate transient diffusion of dopants after ion implantation. It is also in agreement with recent transmission electron microscopy observations of the number of interstitials stored in (311) defects. copyright 1996 ...

461

Analysis and calibration of transient enhanced diffusion for an indium impurity in a nanoscale semiconductor device  

Energy Technology Data Exchange (ETDEWEB)

We developed a new systematic calibration procedure which was applied to the prediction of the diffusivity, the segregation, and transient enhanced diffusion (TED) of an indium impurity. The TED of the indium impurity was studied using four different experimental conditions. Although indium is susceptible to TED, rapid thermal annealing (RTA) is effective in suppressing the TED effect and maintaining a steep retrograde profile. Like boron impurities, the indium shows significant oxidation-enhanced diffusion in silicon and has segregation coefficients much less than 1 at the Si/SiO{sub 2} interface. In contrast to boron, the segregation coefficient of indium decreases as the temperature increases. The accuracy of the proposed procedure was validated by using secondary ion mass spectrometry (SIMS) data and by using the 0.13-{mu}m device characteristics, such as V{sub th} and I{sub dsat}, for which the differences between ...

2005-02-15

462

Analysis and calibration of transient enhanced diffusion for an indium impurity in a nanoscale semiconductor device  

International Nuclear Information System (INIS)

We developed a new systematic calibration procedure which was applied to the prediction of the diffusivity, the segregation, and transient enhanced diffusion (TED) of an indium impurity. The TED of the indium impurity was studied using four different experimental conditions. Although indium is susceptible to TED, rapid thermal annealing (RTA) is effective in suppressing the TED effect and maintaining a steep retrograde profile. Like boron impurities, the indium shows significant oxidation-enhanced diffusion in silicon and has segregation coefficients much less than 1 at the Si/SiO_2 interface. In contrast to boron, the segregation coefficient of indium decreases as the temperature increases. The accuracy of the proposed procedure was validated by using secondary ion mass spectrometry (SIMS) data and by using the 0.13-#mu#m device characteristics, such as V_t_h and I_d_s_a_t, for which the differences between simulation and ...

2005-02-01

463

A Measurement of the Spatial Distribution of Diffuse TeV Gamma Ray Emission from the Galactic Plane with Milagro  

Energy Technology Data Exchange (ETDEWEB)

Diffuse {gamma}-ray emission produced by the interaction of cosmic-ray particles with matter and radiation in the Galaxy can be used to probe the distribution of cosmic rays and their sources in different regions of the Galaxy. With its large field of view and long observation time, the Milagro Gamma Ray Observatory is an ideal instrument for surveying large regions of the Northern Hemisphere sky and for detecting diffuse {gamma}-ray emission at very high energies. Here, the spatial distribution and the flux of the diffuse {gamma}-ray emission in the TeV energy range with a median energy of 15 TeV for Galactic longitudes between 30{sup o} and 110{sup o} and between 136{sup o} and 216{sup o} and for Galactic latitudes between -10{sup o} and 10{sup o} are determined. The measured fluxes are consistent with predictions of the GALPROP model everywhere except for the Cygnus region (l {element_of} [65{sup o}, 85{sup o}]). For the ...

2008-05-14

464

Diagnosis of plasmocytomas using magnetic resonance imaging; Diagnostik des Plasmozytoms mit der MRT  

Energy Technology Data Exchange (ETDEWEB)

Background. In multiple myeloma 5 different infiltration patterns can be differentiated: 1. Normal appearance of bone marrow, 2. focal involvement, 3. homogeneous diffuse infiltration, 4. combined diffuse and focal infiltration, 5. 'salt-and pepper' pattern with inhomogeneous bone marrow with interposition of fat islands. Methods. For the fast and total acquisition of all patterns a combination of a T1-weighted spin echo sequence and a fat suppression technique is superior. The focal involvement is clearly demonstrated as areas of high signal intensity on e.g. STIR images. Diffuse involvement can be quantified objectively by calculation of the percentage of signal intensity increase after contrast material injection. MRI is superior to X-ray in focal and diffuse involvement. With ultrafast sequences a 'screening' of the whole red bone marrow as for myeloma ...

2000-08-01

465

Transverse glow discharges in supersonic air and methane flows  

British Library Electronic Table of Contents (United Kingdom)

Transverse glow discharges in supersonic air and methane flows are studied both experimentally and theoretically. The experiments show that a diffuse volume discharge filling the whole cross section of the flow can easily be initiated in air, whereas a diffuse discharge in a methane flow shows a tendency to transition into a constricted mode. The electron transport coefficients (mobility and drift velocity) and the kinetic coefficients (such as collisional excitation rates of the vibrational levels of a methane molecule, as well as dissociation and ionization rates) are calculated by numerically solving the Boltzmann equation for the electron energy distribution function. The calculated coefficients are used to estimate the parameters of the plasma and the electric field in the positive co...

2006-01-01

466

Toward a predictive atomistic model of ion implantation and dopant diffusion in silicon  

Energy Technology Data Exchange (ETDEWEB)

We review the development and application of kinetic Monte Carlo simulations to investigate defect and dopant diffusion in ion implanted silicon. In these type of Monte Carlo models, defects and dopants are treated at the atomic scale, and move according to reaction rates given as input principles. These input parameters can be obtained from first principles calculations and/or empirical molecular dynamics simulations, or can be extracted from fits to experimental data. Time and length scales differing several orders of magnitude can be followed with this method, allowing for direct comparison with experiments. The different approaches are explained and some results presented.

1998-09-18

467

The effect of temperature and flow stress for climb-controlled dislocation creep in magnesium alloy  

Energy Technology Data Exchange (ETDEWEB)

Effect of strain rate, temperature and grain size in the climb-controlled dislocation creep region for AZ31 magnesium alloy was examined at lower temperature of {proportional_to}473 K. The flow stress was not affected by the difference in grain size. The strain rate sensitivity, m, was obtained 0.14 and 0.2 at low temperatures in high strain rate and at high temperature in low strain rate, respectively. It was found that the notion of effective diffusivity could express the dominant diffusion process during climb-controlled dislocation creep behavior uniquely. (orig.)

2003-07-01

468

The application of platinum-silicide anode layer to decrease the static and turn-off losses in high-power P-i-N diode  

Energy Technology Data Exchange (ETDEWEB)

The platinum-silicide layer was investigated as the anode contact of a high-power P-i-N diode. The thermal stability at 700 deg. C was found sufficient for the purpose of Pt in-diffusion from the platinum-silicide layer into the volume. The diffusion, which was controlled using the radiation defects resulting from the 10 MeV alpha particle irradiation, represents a new local lifetime control in the float zone silicon with very low-leakage current, while keeping the benefits of traditional approaches.

2003-06-02

469

Spatial heterogeneity and ecological models. [Predation  

Energy Technology Data Exchange (ETDEWEB)

The role of natural enemies in the regulation of populations is one of the major questions facing population ecologists. Simplification have led to two theoretical ways of incorporating the role of natural enemies in single ecological models: diffusion models and patch-type models. The predictions of the models are different because of the way variability is incorporated. Three equations are presented for diffusion models and one for patch models. Since the two types of models apply at different combinations of spatial and temporal scales, the right model(s) to choose for a particular study requires careful assessment. A continuing dialogue between experimentalists and theoreticians will lead to a better understanding of natural systems such as those that occur in biological control.

1990-04-01

470

Renewable energy technologies for irrigation water pumping in India: projected levels of dissemination, energy delivery and investment requirements using available diffusion models  

Energy Technology Data Exchange (ETDEWEB)

Using the past diffusion trends of four renewable energy technologies for irrigation water pumping in India (SPV pumps, windmill pumps and biogas/producer gas driven dual fuel engine pumps), results of an attempt to project their future dissemination levels, have been presented in this study. The likely contribution of the renewable energy options considered in the study to the projected energy demand for irrigation water pumping in India has been estimated. Estimates of the associated investment requirements taking into account the learning effect have also been presented. (author)

2005-12-01

471

Numerical Computation of Diffusion on a Surface  

Energy Technology Data Exchange (ETDEWEB)

We present a numerical method for computing diffusive transport on a surface derived from image data. Our underlying discretization method uses a Cartesian grid embedded boundary method for computing the volume transport in region consisting of all points a small distance from the surface. We obtain a representation of this region from image data using a front propagation computation based on level set methods for solving the Hamilton-Jacobi and eikonal equations. We demonstrate that the method is second-order accurate in space and time, and is capable of computing solutions on complex surface geometries obtained from image data of cells.

2005-02-24

472

Modelling and measurement of radon diffusion through soil for application on mine tailings dams  

International Nuclear Information System (INIS)

The mine dumps that arise from the gold mining operations in South Africa are a potential source of high concentrations of radon (222"Rn). Studying the diffusion of radon and the emanation from the soil will help to deduce the radon flux from these dumps to identify the problem areas for rehabilitation. This study describes measurements of the emanation coefficient and the modelling of the depth profile of the radon activity concentration, which is compared to a depth profile that was measured on such a mine dump. Emanation coefficients ranging from 0.13 to 0.39 have been obtained.

2005-04-01

473

Modeling of extended defects in silicon  

Energy Technology Data Exchange (ETDEWEB)

Transient Enhanced Diffusion (TED) is one of the biggest modeling challenges present in predicting scaled technologies. Damage from implantation of dopant ions changes the diffusivities of the dopants and precipitates to form complex extended defects. Developing a quantitative model for the extended defect behavior during short time, low temperature anneals is a key to explaining TED. This paper reviews some of the modeling developments over the last several years, and discusses some of the challenges that remain to be addressed. Two examples of models compared to experimental work are presented and discussed.

1997-11-01

474

Modeling of dislocation loop growth and transient enhanced diffusion in silicon for amorphizing implants  

Energy Technology Data Exchange (ETDEWEB)

It has been observed that dislocation loops form and grow during annealing of silicon wafers implanted at doses above the amorphization threshold. Dislocation loops can act to store interstitials for prolonged periods of anneals, sustaining an interstitial super-saturation and thus causing substantial transient enhanced diffusion (TED). The authors have developed a comprehensive model which, in combination with a model and parameters for {l_brace}311{r_brace} defects from previous work, accounts for the formation and evolution of dislocation loops during ion implant annealing, as well as giving the correct TED behavior.

1997-11-01

475

Modeling of dislocation loop growth and transient enhanced diffusion in silicon for amorphizing implants  

International Nuclear Information System (INIS)

It has been observed that dislocation loops form and grow during annealing of silicon wafers implanted at doses above the amorphization threshold. Dislocation loops can act to store interstitials for prolonged periods of anneals, sustaining an interstitial super-saturation and thus causing substantial transient enhanced diffusion (TED). The authors have developed a comprehensive model which, in combination with a model and parameters for #left brace#311#right brace# defects from previous work, accounts for the formation and evolution of dislocation loops during ion implant annealing, as well as giving the correct TED behavior.

1996-12-02

476

Mechanisms of Alloy 800 corrosion in helium  

International Nuclear Information System (INIS)

Cr_2O_3 scales are found to form on Alloy 800 and a similar pure ternary alloy in air, and 1 and 50 atm. helium containing oxidizing impurities typical of those in an SGHTR. The strong temperature dependence and neglibible helium overpressure dependence indicate that gas transport through the scales is not rate controlling. Surface oxidation rates are therefore controlled by solid state diffusion and the low oxygen partial pressure dependence of the oxidation rate in Alloy 800 is ascribed to the presence of extrinsic defects in the Cr_3O_3 (due to doping by alloying elements) or to the presence of short circuit diffusion paths. (Auth.).

477

Mechanical variations of diffused plasma parameters in a double plasma device  

International Nuclear Information System (INIS)

Experimentally it is shown that a movable grounded metallic plate placed inside a multi-dipole magnetic cage can vary the diffused plasma parameters such as density, plasma potential and electron temperature. Plasma is solely produced in the source section of a double plasma device by a dc hot filament discharge and a low-density plasma is produced in the target section by local ionization of neutral gas by the high energetic electrons coming from the source section. A grounded movable stainless steel plate is inserted in the target section of the device. The floating potential of the plate also changes depending on the position of the plate inside the magnetic cage.

2007-06-21

478

Magnetic braking in weakly ionized media  

International Nuclear Information System (INIS)

The combined magnetic braking-ambipolar diffusion problem in weakly ionized, rigidly rotating disks is studied. An analytical solution is presented for a disk whose angular velocity and magnetic yield vectors are aligned with the symmetry axis, illustrating the effects of the relative azimuthal drift of neutrals and ions. The effects of radial drift are added, commenting on the ratio of the characteristic ambipolar diffusion and magnetic braking time scales in high-mass and low-mass disks. A numerical calculation is used to show the combined action of these two processes. 31 references.

479

Interstitial injection in silicon after high-dose, low-energy arsenic implantation and annealing  

International Nuclear Information System (INIS)

In this work, we investigate the interstitial injection into the silicon lattice due to high-dose, low-energy arsenic implantation. The approach consists in monitoring the diffusion of the arsenic profile as well as of the boron profile in buried #delta#-doped layers, when amounts of the as-implanted arsenic profile are removed by low-temperature wet silicon etching. The experimental results indicate that the contribution of the implantation damage to the transient enhanced diffusion of boron, and thus the interstitial injection, is not the main one. On the contrary, interstitial generation due to arsenic clustering seems to be more important for the present conditions.

2005-11-14

480

Interpolation theory and influence of boundary conditions on room air diffusion  

Energy Technology Data Exchange (ETDEWEB)

This paper analyses the errors caused by interpolation from existing cases for assessing indoor air flow, air quality and thermal comfort in an office. A sensitivity study is then provided to determine the influence of several boundary conditions on indoor air diffusion. The research is conducted numerically by using a low-Reynolds-number k-{epsilon} model. It can be concluded that the interpolation errors caused by the variations of solar radiation, window size, heat source location due to lighting, and the surface temperatures of interior walls are small and can be quantitatively determined. But it is difficult to estimate the errors introduced by the variations of furniture location and size. (author).

1991-01-01

481

Influence of oxygen precipitates on the measurement of minority carrier diffusion length in p-type silicon material using surface photovoltage technique  

Science.gov (United States)

Metallic contamination was monitored with Surface Photovoltage (SPV) technique in integrated circuit manufacturing facilities. Conventionally, Czochralski silicon bulk materials were used as monitor wafers. However, it has been observed that the diffusion length and the `Iron' concentration measured with SPV were inconsistent from run to run in one facility. The inconsistency is believed to be due to oxygen precipitate in silicon materials during the thermal cycle. By using low oxygen concentration or Float Zone wafers, metallic contaminants can be monitored more accurately and consistently.

1997-09-01

482

Global Dissipative Dynamics of the Extended Brusselator System  

CERN Document Server

The existence of a global attractor for the solution semiflow of the extended Brusselator system in the $L^2$ phase space is proved, which is a cubic-autocatalytic and partially reversible reaction-diffusion system with linear coupling between two compartments. The method of grouping and re-scaling estimation is developed to deal with the challenge in proving the absorbing property and the asymptotic compactness of this typical multi-component reaction-diffusion systems. It is also proved that the global attractor is an $(H, E)$ global attractor with the $L^\\infty$ regularity and that the Hausdorff dimension and the fractal dimension of the global attractor are finite. The results and methodology can find many applications and further extensions in complex biological and biochemical dynamical systems.

2011-01-01

483

Geometry changes transient transport in plasmas  

Energy Technology Data Exchange (ETDEWEB)

Role of ballooning effect in toroidal plasmas on the transient transport problems is investigated. Due to the mode localization along the magnetic field line, a meso scale appears in a radial correlation length of fluctuating fields. This scale length introduces the interference of the gradient and flux in different radial locations. For the fluctuation which gives the gyro-Bohm-like diffusion in a stationary state, this long radial correlation of the fluctuating field causes a fast propagation of response against a rapid transient perturbation. Upper bound of transient thermal diffusivity is derived. (author)

2001-06-01

484

Formation of charge and energy distribution of heavy ions in substance according to diffusion model  

International Nuclear Information System (INIS)

The formation of the ions charge and energy distributions of the ions slowed down or randomly changing their charge in the collisions with the medium particles are studied. The effect of the ions dispersion by the charge on the Bragg curve form is investigated. The proposed diffusion approximation for the heavy ions kinetic equation makes it possible to determine simply the parameters of the ions distribution by charge and energy on the whole way of the ions motion. The relation between the ions charge distribution characteristics and the cross sections of the ionization-recombination processes is indicated. The ions distributions, calculated in the proposed analytical model, are compared with the results of the numerical calculations. Good agreement between the analytical, numerical and experimental results is obtained

2003-11-01

485

Expansion Rate Measurements at Moderate Pressure of Nonneutral Electron Plasmas in the Electron Diffusion Gauge (EDG) Experiment  

Energy Technology Data Exchange (ETDEWEB)

Measurements of the expansion rate of pure-electron plasmas have been performed on the Electron Diffusion Gauge (EDG) device at background helium gas pressures in the 5 x 10(superscript -8) Torr to 1 x 10(superscript -5) Torr range, where plasma expansion due to electron-neutral collisions dominates over plasma expansion due to trap asymmetries. It is found that the expansion rate, defined as the time rate of change of the particles' mean-square radius, scales approximately linearly with pressure and inversely as the square of the magnetic field strength in this regime, in agreement with classical predictions.

2001-05-18

486

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

Energy Technology Data Exchange (ETDEWEB)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

1992-03-01

487

Evaluation of tritiated water retention capacity of fusion reactor concrete building  

International Nuclear Information System (INIS)

In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.

488

Eulerian-Lagrangian relationships in Monte Carlo simulations of turbulent diffusion  

Energy Technology Data Exchange (ETDEWEB)

The results of this study show that Monte Carlo simulations of diffusion in homogeneous turbulence can be formulated in terms of the Eulerian space-time velocity autocorrelation function. Numerical results obtained using this approach agree with results obtained by Taylor (1921) using the Lagrangian autocorrelation function. Use was made of the equivalence of the Lagrangian and Eulerian Monte Carlo approaches to derive analytic relations between the Lagrangian integral time scale and the Eulerian integral space and time scales. These analytic results were verified by comparison to Monte Carlo simulations and to other theoretical results. They are in general agreement with many existing theories and semi-empirical relations.

1983-01-01

489

Electronic structure calculations of vacancies and their influence on materials properties  

Energy Technology Data Exchange (ETDEWEB)

We provide two examples to illustrate how electronic structure calculations contribute to our understanding of vacancies and their role in determining material properties. Diffusion and elctromigration in aluminium are known to depend strongly on vacancies. Electronic structure calculations show that the vacancy-impurity interaction oscillates with distance, and this leads to an explanation for both the increased elctromigration resistance and the slow impurity diffusion for copper in aluminium. Calculations of vacancies in plutonium have been used in conjunction with positron annihilation lifetime measurements to identify the presence of helium-filled vacanies. Helium stabilization of vacancies can provide the precursors for subsequent vacancy-related changes in materials properties.

1997-08-01

490

Development of low cost contacts to silicon solar cells  

Science.gov (United States)

The results of the second phase of the program of developing low cost contacts to silicon solar cells using copper are presented. Phase 1 yielded the development of a plated Pd-Cr-Cu contact system. This process produced cells with shunting problems when they were heated to 400 C for 5 minutes. Means of stopping the identified copper diffusion which caused the shunting were investigated. A contact heat treatment study was conducted with Pd-Ag, Ci-Ag, Pd-Cu, Cu-Cr, and Ci-Ni-Cu. Nickel is shown to be an effective diffusion barrier to copper.

1980-01-01

491

Comparison of Different Methods for Nonlinear Diffusive Shock Acceleration  

CERN Document Server

We provide a both qualitative and quantitative comparison among different approaches aimed to solve the problem of non-linear diffusive acceleration of particles at shocks. In particular, we show that state-of-the-art models (numerical, Monte Carlo and semi-analytical), even if based on different physical assumptions and implementations, for typical environmental parameters lead to very consistent results in terms of shock hydrodynamics, cosmic ray spectrum and also escaping flux spectrum and anisotropy. Strong points and limits of each approach are also discussed, as a function of the problem one wants to study.

2010-01-01

492

An integrated approach to the modelling of hydrogen assisted failure in 316L steel  

International Nuclear Information System (INIS)

An integrated approach to the modelling of hydrogen assisted failure in 316L steel is presented. The approach includes experimental, fractographic, numerical and theoretical analysis of the phenomenon. The physical adequacy of the mechanical models of hydrogen embrittlement (notch extension model and notch cracking model) is discussed by comparing the virtual damage depth (theoretical) predicted by the models with the embrittled zone (microphysical) measured in the fractographic analysis by scanning electron microscopy. In addition, a numerical modelling of hydrogen diffusion is performed, concluding that bulk diffusion is not important in hydrogen embrittlement of 316L steel, so that hydrogen transport accelerated by the microdamage itself should be taken into account. (orig.)

1998-09-01

493

A theoretical study of radon measurement with activated charcoal  

Energy Technology Data Exchange (ETDEWEB)

Diffusion of radon in a bed of activated charcoal is described by diffusion equations. An analytical solution of these equations is presented for the case of constant radon concentration in the atmosphere. The solutions are given separately for short term and long term exposure. An analytical form of the calibration constant f for long term exposure and constant radon concentration in air, was found. A numerical method and computer code based on the method of finite elements is developed for the case of variable radon concentration in air. This program simulates radon adsorption by the activated charcoal bed, enabling determination of sensitivity. The dependence of sensitivity on different parameters, such as temperature, thickness of the charcoal, etc. was studied using this program. (orig.) 10 refs.

1998-04-11

494

A NEM diffusion code for fuel management and time average core calculation  

International Nuclear Information System (INIS)

A computer code based on Nodal expansion method has been developed for solving two groups three dimensional diffusion equation. This code can be used for fuel management and time average core calculation. Explicit Xenon and fuel temperature estimation are also incorporated in this code. TAPP-4 phase-B physics experimental results were analyzed using this code and a code based on FD method. This paper gives the comparison of the observed data and the results obtained with this code and FD code. (author)

2005-11-01

495

Transient enhanced diffusion of dopants in preamorphized Si layers  

Energy Technology Data Exchange (ETDEWEB)

Transient Enhanced Diffusion (TED) of dopants in Si is the consequence of the evolution, upon annealing, of a large supersaturation of Si self-interstitial atoms left after ion bombardment. In the case of amorphizing implants, this supersaturation is located just beneath the c/a interface and evolves through the nucleation and growth of End-Of-Range (EOR) defects. For this reason, the authors discuss here the relation between TED and EOR defects. Modelling of the behavior of these defects upon annealing allows one to understand why and how they affect dopant diffusion. This is possible through the development of the Ostwald ripening theory applied to extrinsic dislocation loops. This theory is shown to be readily able to quantitatively describe the evolution of the defect population (density, size) upon annealing and gives access to the variations of the mean supersaturation of Si self-interstitial atoms between the loops and responsible for ...

1997-11-01

496

Physical mechanisms of transient enhanced dopant diffusion in ion-implanted silicon  

International Nuclear Information System (INIS)

Implanted B and P dopants in Si exhibit transient enhanced diffusion (TED) during annealing which arises from the excess interstitials generated by the implant. In order to study the mechanisms of TED, transmission electron microscopy measurements of implantation damage were combined with B diffusion experiments using doping marker structures grown by molecular-beam epitaxy (MBE). Damage from nonamorphizing Si implants at doses ranging from 5x10"1"2 to 1x10"1"4/cm"2 evolves into a distribution of #left brace#311#right brace# interstitial agglomerates during the initial annealing stages at 670 endash 815 degree C. The excess interstitial concentration contained in these defects roughly equals the implanted ion dose, an observation that is corroborated by atomistic Monte Carlo simulations of implantation and annealing processes. The injection of interstitials from the damage region involves the dissolution of #left brace#311#right brace# defects ...

497

An experimental study of the ventilation performance of cold-air distribution systems  

Energy Technology Data Exchange (ETDEWEB)

The ventilation performance of cold-air distribution systems was investigated in a full-scale test room for three different designs of ceiling-mounted diffusers: a large square radial, a small square radial, and two linear diffusers. The supply air temperature was 38 F (3.3 C). Tests were conducted with internal heat loads and with and without furnishings. The local mean ages of air, air diffusion effectiveness, and contaminant-removal efficiency were measured using tracer gas techniques to assess the performance of the ventilation system in maintaining adequate air quality conditions in the occupied region. Air velocities and temperatures were also measured in the occupied region to calculate the air diffusion performance index (ADPI). It was found that the cold-air distribution system provided satisfactory air quality and thermal comfort conditions to the occupied region of the room. It was also found ...

1994-12-31