Energy Technology Data Exchange (ETDEWEB)

Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam-cycle is the conventional conversion method; however total energy conversion efficiencies for this type of process are only slightly over 30%. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40%. Conversion processes based on gasification offer efficiencies above 50%. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. This process is concerned with the removal of H{sub 2} from coal gas through an electrochemical membrane technology.

Energy Technology Data Exchange (ETDEWEB)

Recent research at the laboratory scale by a number of organizations in different countries has shown that with the use of particular types of solvents it is possible to achieve almost complete conversion of coal to liquid products under relatively mild process conditions. This work is reviewed and the conclusions to be drawn from it are summarized.

Energy Technology Data Exchange (ETDEWEB)

In seeking ways to reduce emissions from two-stroke locomotive type engines, the Navy has evaluated dual-fuel conversions operating on a compression ignition cycle, using up to 94% natural gas and 6% diesel pilot fuel. The Navy has conducted an evaluation and test program under the direction of Dr. Normnn L. Helgeson, at the Naval Facilities Engineering Service Center in Port Hueneme, California. Of the Navy`s many diesel engines, those installed in its MUSE (mobile utility support equipment) units for temporary electrical power were the first Navy off-road engines to be affected by emissions regulations. Most of the units are powered by the EMD 645 engine, and when burning diesel fuel do not meet the emission requirements in many areas of the country. This paper discusses the changes and results of the conversion and shakedown tests.

Science.gov (United States)

The authors report here, for the first time, high frequency testing of a new type of electrochemical double layer capacitor (EDLC), based on carbon aerogels: the Aerocapacitor. Carbon aerogels, are a novel type of carbon foam developed by Lawrence Livermore National Laboratory for military applications. The unique properties of carbon aerogels, high surface area (700 m{sup 2}/g), high density (1g/cc), well controlled pore diameter and high material conductivity (25 S/cm) made it an ideal EDLC electrode material. Using carbon aerogel as the electrode material, the authors have developed Aerocapacitors. These new EDLC`s have a frequency response comparable to that of aluminum electrolytic capacitors and are thus ideally suited to power conversion applications.

International Nuclear Information System (INIS)

The magnetic #beta#-spectrometer of the #pi# #sq root#2 type with 0.07% pulse resolution is used to measure the intensities of interval conversion electrons on L- and M-subshells of 70.45 keV "1"7"7 Ta gamma-transition. The results are analyzed and the values of mixing parameter #sigma#(E2/M1) and penetration parameter #lambda# are obtained.

UK PubMed Central (United Kingdom)

The nr₁ soybean (Glycine max [L.] Merr.) mutant does not contain the two constitutive nitrate reductases, one of which is responsible for enzymic conversion of nitrite to...Full Text Available

International Nuclear Information System (INIS)

Neutron transmutation doping(NTD) for producing ntype silicon semiconductor is based on the conversion of the Si-30 isotope into phosphorus atom by neutron absorption reaction. By using this method, silicon semiconductors with extremely uniform n-type dopant distributions can be produced, and this is the dominant advantage of NTD compared with the conventional chemical doping. HANARO has two vertical holes for NTD, and the commercial NTD service for 5 and 6 inch silicon ingots has been going on at the NTD2 hole. Generally, NTD method is applied to the initially n-type silicon material. But, an initially p-type silicon material can also be used for the production of uniformly doped n-type silicon by using NTD method. Therefore, in this work, we investigated the relationship between the irradiation neutron fluence and the final resistivity of the initially p-type ...

International Nuclear Information System (INIS)

An oxidative precipitation reaction of rare-earth chlorides in a LiCl-KCl molten salt was successfully carried out by a lab-scale apparatus. The conversion efficiency of the used rare earth chlorides into the insoluble precipitates was increased with the sparging time and temperature and was affected on oxygen sparger type. In the conditions of 700 .deg. C molten salt temperature and above 540min sparging time, the final conversion efficiencies were over 99% for all the experimented rare-earth chlorides. The hydrodynamic characteristics of an oxygen-molten salt two phase flow system are very important for a co-oxidative precipitation of rare earth elements

Energy Technology Data Exchange (ETDEWEB)

This report describes progress during the first year of a three-year project. The objective of the research is to examine new design approaches for achieving very high conversion efficiencies. The program is divided into two areas. The first centers on exploring new thin-film approaches specifically designed for III-V semiconductors. The second area centers on exploring design approaches for achieving high conversion efficiencies without requiring extremely high quality material. Research activities consisted of an experimental study of minority carrier recombination in n-type, metal-organic chemical vapor deposition (MOCVD)-deposited GaAs, an assessment of the minority carrier lifetimes in n-GaAs grown by molecular beam epitaxy, and developing a high-efficiency cell fabrication process.

Energy Technology Data Exchange (ETDEWEB)

The main sources of energy that might be available in remote low populated areas of Libya are either diesel generating units or wind mills for water pumping. Several problems in the working performance of these two types of energy production may arise due to environmental conditions. Direct conversion of solar energy can replace other ways of energy delivery or production, especially in this country where the solar radiation all year is relatively high. Direct conversion of solar energy is relatively expensive, however the cost of erecting long feeders and supervising them may be much more expensive than the usage of solar systems. This paper investigates the economics associated with either solutions of energy production. A case study is given in detail to supply one of the remote areas with a population of about 250. (author)

International Nuclear Information System (INIS)

The consequences of converting a facility from brown coal fuel to gas fuel were analyzed by model simulation. Treated were a district heating plant with an output of 700 TJ/yr and minor local heating sources (stoves) at a density of 1 family house per 100 m"2. Emissions of particulate matter, sulfur dioxide, nitrogen oxides, carbon monoxide, and hydrocarbons before and after the conversion are given for the two types of source. Conversion of a major air pollution source to gas fuel would result in a reduction of the contribution of sulfur dioxide emissions of the order of 10"-"4, of particulate matter and carbon monoxide of the order of 10"-"3, and of hydrocarbons of the order of 10"-"2. The decrease will be lowest for nitrogen oxides, viz. about 40%. Analogous data for local heating sources in towns would be 10"-"5 for sulfur dioxide, 10"-"4 for particulate matter, 10"-"3 for carbon monoxide and hydrocarbons, and roughly ...

Science.gov (United States)

placed on direct energy conversion. This is an advanced technology which is ..... Of the direct energy conversion methods discussed, the only one which may ...

Energy Technology Data Exchange (ETDEWEB)

The batchwise preparation of molecular sieves for methanol conversion shows some inconsistency in catalytic stability. This is a result mainly of the change of SiO/SUB/2/Al/SUB/2O/SUB/3 in ion exchange to an H-type sieve. The dealumination during ion exchange depends upon crystal size and structural factors, which can be characterised by the cyclohexane adsorption of the raw molecular sieve. A high SiO/SUB/2/Al/SUB/2O/SUB/3 H-molecular sieve can be prepared from a molecular sieve of high adsorption capacity, this leading to a catalyst of higher stability. (4 refs.)

International Nuclear Information System (INIS)

Central in the paper are two results on the existence of 'economical' embeddings in a Euclidean space. The first result (Corollary 1.4) states the existence of an embedding with image intersecting the large-dimensional planes in sets of 'controllable' dimension. The second result (Corollary 1.6) proves the existence of maps such that each small-dimensional plane contains 'controllably' many points of the image. Well known results of Noebeling-Pontryagin, Roberts, Hurewicz, Boltyanskii, and Goodsell can be obtained as consequences of these results. Their infinite-dimensional version concerning an embedding in a Hilbert space is also established (Theorem 1.8).

International Nuclear Information System (INIS)

Elemental substitution of Ca by Y was investigated for Ca-#alpha#-SiAlON:Eu yellow phosphors, which is useful for the white light-emitting diode lamps of phosphor conversion type. Depending on the ratio of the elemental substitution, not only the red shift of emission in wavelength occurred but also the figure of the excitation spectra changed. Their excitation band widths and flatness were discussed. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Energy Technology Data Exchange (ETDEWEB)

Direct electric heating by passing an electrical current directly through a bed of adsorbent may prove to be an efficient means of regenerating activated charcoal in continuous and batch adsorption processes. Obvious advantages of this type of regeneration are its almost complete lack of inertia, which makes it possible to reduce the number and dimensions of the adsorbers, and its highly efficient use of energy due to the small number of steps in the conversion of the energy, as well as the reduction of heat losses involved in warming the structure and making up for losses to the surroundings. The authors consider the kinetics of direct electric heating of a stationary bed of activated charcoal not containing adsorbed substances.

British Library Electronic Table of Contents (United Kingdom)

Selectivity control is a key issue in the zeolite facilitated conversion of methanol to hydrocarbons. This work addresses: (a) How the zeolite topology (MFI versus BEA) determines the type of intermediate participating in the catalytic cycle thereby controlling the ethene/propene product selectivity in the methanol to alkenes reaction, and (b) to what extent light alkene formation occurs via aromatic and alkene reaction intermediates for H-ZSM-5. Three catalyst samples have been studied in experiments relying on isotopic labeling. For H-beta, penta- and hexamethylbenzene are involved in an aromatics based hydrocarbon pool type mechanism leading predominantly to propene and the higher alkenes (a very low yield of ethene is observed), whereas for H-ZSM-5, the lower methylbenzenes are the aro...

Energy Technology Data Exchange (ETDEWEB)

Basic information on photovoltaic conversion technology is provided for those unfamiliar with the field. Various types of photovoltaic products and systems currently available off-the-shelf are described. These include products without batteries, battery chargers, power packages, home electric systems, and partial systems. Procedures are given for designing a photovoltaic system from scratch. A few custom photovoltaic systems are described, and a list is compiled of photovoltaic firms which can provide custom systems. Guidance is offered for deciding whether or not to use photovoltaic products. A variety of installations are described and their performance is appraised by the owners. Information is given on various financial incentives available from state and federal governments. Sources of additional information on photovoltaics are listed. A matrix is provided indicating the sources of various types of photovoltaic ...

Energy Technology Data Exchange (ETDEWEB)

Abstract - We have designed, built, and tested a 2-D pixellated thermal neutron detector. The detector is modeled after the MicroMegas-type structure previously published for collider-type experiments. The detector consists of a 4X4 square array of 1 cm 2 pixels each of which is connected to an individual preamplifier-shaper-data acquisition system. The neutron converter is a 10B film on an aluminum substrate. We describe the construction of the detector and the test results utilizing 252Cf sources in Lucite to thermalize the neutrons.Drift electrode (Aluminum) Converter (10B) 3 mm Conversion gap neutron (-900 V)

Energy Technology Data Exchange (ETDEWEB)

Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam- cycle is the conventional conversion method; however, total energy conversion efficiencies for this type of process are only slightly over 30{percent}. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40{percent}. Conversion processes based on gasification offer efficiencies above 50{percent}. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. Problems arise due to the corrosive nature of H{sub 2}S on metal components contained in these cycles. Because of this, H{sub 2}S concentrations must be reduced to low levels corresponding to certain power applications. An advanced process for the separation of hydrogen sulfide ...

International Nuclear Information System (INIS)

Conversion electron studies of medium-heavy to heavy nuclear mass systems are important where the internal conversion process begins to dominate over gamma-ray emission. The use of a segmented detector array sensitive to conversion electrons has been used to study multiple conversion electron cascades from nuclear transitions. The application of the silicon array for conversion electron detection (SACRED) for in-beam measurements has successfully been implemented. (orig.). With 2 figs.

CERN Document Server

A Smarandache quasigroup(loop) is shown to be universal if all its f,g-principal isotopes are Smarandache f,g-principal isotopes. Also, weak Smarandache loops of Bol-Moufang type such as Smarandache: left(right) Bol, Moufang and extra loops are shown to be universal if all their f,g-principal isotopes are Smarandache f,g-principal isotopes. Conversely, it is shown that if these weak Smarandache loops of Bol-Moufang type are universal, then some autotopisms are true in the weak Smarandache sub-loops of the weak Smarandache loops of Bol-Moufang type relative to some Smarandache elements. Futhermore, a Smarandache left(right) inverse property loop in which all its f,g-principal isotopes are Smarandache f,g-principal isotopes is shown to be universal if and only if it is a Smarandache left(right) Bol loop in which all its f,g-principal isotopes are Smarandache f,g-principal isotopes. Also, it is established ...

Energy Technology Data Exchange (ETDEWEB)

Site-selective spectroscopy fluorescence experiments (emission and excitation) in the near-infrared region associated with the {sup 4}I{sub 15/24}I{sub 11/2} transitions of Er{sup 3+} ions have been successfully used to show the presence of two different Er{sup 3+} centres in the Bi{sub 12}SiO{sub 20} piezoelectric crystal. Green (545-570 nm), red (650-690 nm) and near-infrared (850-890 nm) up-converted emissions have been observed and resolved for each type of centre under excitation up to the {sup 4}{sub I11/2} state. The Stark energy level schemes of the three lower energy states of Er{sup 3+} ions have been determined and compared for both centres, showing two quite different crystalline field environments. The mechanisms responsible for the up-conversion process (excited state absorption and/or energy transfer up-conversion) are also analysed. (author)

Energy Technology Data Exchange (ETDEWEB)

A wind turbine is disclosed which permits high energy production over a wide range of wind forces while being protected against climatic hazards. According to the invention, a mast supports an energy recuperator comprising vane-type rotors by means of a frame which is orientable around a vertical axis. An energy conversion device is connected to the recuperator in order to be driven in rotation by the recuperator. The frame is responsive to the aerodynamic force exerted on the recuperator with respect to the mast and to the ground so as to optimize the power collected by the machine. The frame comprises a turret pivoted to the mast about the vertical axis and a structure pivoted to the turret about a horizontal axis of tilting motion. A balance weight maintains the recuperator in the top position when there is no wind. The aerodynamic drag of the recuperator acts in the opposite direction. In consequence, in the event of a high wind, the ...

Energy Technology Data Exchange (ETDEWEB)

This project is concerned with the structure and function of the unique antenna system found in the green photosynthetic bacteria. The antenna system in these organisms is contained within a vesicle known as a chlorosome, which is attached to the cytoplasmic side of the cell membrane. Additional antenna pigments and reaction centers are contained in integral membrane proteins. Energy absorbed by the bacteriochlorophyll c (BChl c) pigments in the chlorosome is transferred via a ``baseplate`` array of BChl a antenna pigments into the membrane and to the reaction center. This system is similar in some respects to the phycobilisome antenna system found in cyanobacteria and some types of algae, in that a membrane-associated structure absorbs light and transfers it to the membrane where conversion to chemical energy takes place. However, the overall structure, the type of pigments utilized and the nature of the proteins in these ...

Energy Technology Data Exchange (ETDEWEB)

The rationale for hybrid fusion-fission reactors is the production of fissile fuel for fission reactors. A new class of reactor, the fission-suppressed hybrid promises unusually good safety features as well as the ability to support 25 light-water reactors of the same nuclear power rating, or even more high-conversion-ratio reactors such as the heavy-water type. One 4000-MW nuclear hybrid can produce 7200 kg of /sup 233/U per year. To obtain good economics, injector efficiency times plasma gain (eta/sub i/Q) should be greater than 2, the wall load should be greater than 1 MW m/sup -2/, and the hybrid should cost less than 6 times the cost of a light-water reactor. Introduction rates for the fission-suppressed hybrid are unusually rapid.

British Library Electronic Table of Contents (United Kingdom)

Mutations in sclerostin function or expression cause sclerosing bone dysplasias, involving decreased antagonism of Wnt/Lrp5 signaling. Conversely, deletion of the VHL tumor suppressor in osteoblasts, which stabilize HIF-a isoforms and thereby enables HIF-a/b-driven gene transcription, increases bone mineral content and cross-sectional area compared to wild-type controls. We examined the influence of cellular hypoxia (1% oxygen) upon sclerostin expression and canonical Wnt signaling. Osteoblasts and osteocytes cultured under hypoxia revealed decreased sclerostin transcript and protein, and increased expression and nuclear localization of activated b-catenin. Similarly, both hypoxia and the hypoxia mimetic DFO increased b-catenin gene reporter activity. Hypoxia and its mimetics increased exp...

Energy Technology Data Exchange (ETDEWEB)

This report reviews coal conversion processes which may be introduced in Canada within the next decade if interest in alternate energy technologies continues. A detailed review was conducted on coal liquefaction and gasification projects worldwide including information on individual proprietors, process technologies used, their present status and available environmental data. Further assessment of emissions and wastes emanating from commercial-scale plants was used to determine significant or potentially significant wastestreams connected to the various technologies, particularly wastewater discharges. Emphasis was placed on those technologies that are close to commercialization in Canada, i.e. SASOL II-type liquefaction facility at Hat Creek. Available information on wastewater treatment/reuse is also included in this report.

Science.gov (United States)

A general model for the analysis of metal-semiconductor solar cells is presented. The model takes into account the cell optical properties, carrier recombination effects, semiconductor minority-carrier properties, series resistance, cell thickness, and active surface area. Numerical methods are used to solve the appropriate continuity equations and hence compute the photocurrent density under AMO conditions. The operation of the model is demonstrated using p- and n-type Si and GaAs with Au being taken as the barrier metal. Calculations are presented showing the effect on solar energy conversion efficiency of surface recombination velocity, barrier height, minority-carrier lifetime, barrier metal thickness, collecting grid configuration, and cell thickness. A comparison of practical and computed data for the Au/n-GaAs system yields good agreement. (AIP)

Energy Technology Data Exchange (ETDEWEB)

The nuclear lamina proteins, prelamin A, lamin B, and a 70-kD lamina-associated protein, are posttranslationally modified by a metabolite derived from mevalonate. This modification can be inhibited by treatment with (3-R,S)-3-fluoromevalonate, demonstrating that it is isoprenoid in nature. We have examined the association between isoprenoid metabolism and processing of the lamin A precursor in human and hamster cells. Inhibition of 3-hydroxy-3-methylglutaryl coenzyme A reductase by mevinolin (lovastatin) specifically depletes endogenous isoprenoid pools and inhibits the conversion of prelamin A to lamin A. Prelamin A processing is also blocked by mevalonate starvation of Mev-1, a CHO cell line auxotrophic for mevalonate. Moreover, inhibition of prelamin A processing by mevinolin treatment is rapidly reversed by the addition of exogenous mevalonate. Processing of prelamin A is, therefore, dependent on isoprenoid metabolism. Analysis of the ...

UK PubMed Central (United Kingdom)

A rehabilitation programme for patients with conversion paralysis has been introduced in which they are offered physical rehabilitation. During an eight month period between October 1984 and May 1985...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Nomographs have been constructed to estimate the average evaporation loss from internal floating-roof tanks. Loss determined from the charts can be used to evaluate the economics of seal conversion and to reconcile refinery, petrochemical plant, and storage terminal losses. The losses represent average standing losses only. They do not cover losses associated with the movement of product into or out of the tank. The average standing evaporation loss from an internal floating-roof tank depends on: vapor pressure of the product; type and condition of roof seal; tank diameter; and type of fixed roof support. The nomographs can estimate evaporation loss for product true vapor pressures (TVP) ranging from 1.5 to 14 psia, the most commonly used seals for average and tight fit conditions, tank diameters ranging from 50 to 250 ft, welded and bolted designs, and both self-supporting and column-support fixed roof designs. The charts ...

International Science & Technology Center (ISTC)

New Catalysts and Sorbents on the Basis of Pillared Clays for the Processes of Hydrocarbons Conversion and Water Purification

Science.gov (United States)

... Descriptors : *TERMINAL BALLISTICS, *WOUND BALLISTICS, VELOCITY, CONVERSION, REPRINTS, TISSUES(BIOLOGY), MANUFACTURING ...

Energy Technology Data Exchange (ETDEWEB)

The performance of a thermophotovoltaic (TPV) converter for solar energy is compared with that of direct solar energy conversion by silicon and germanium solar cells. The optical selectivity of an intermediate emitter is computed. Experimental results on selective emission, based on selectively emitting materials and on antireflection coatings on metals, are reported. For a TPV converter equipped with silicon solar cells, no selective emitter is found to yield better results than would be obtained by direct conversion. A TPV converter with germanium cells operating with a ThO/sub 2/-coated tungsten emitter, however, may achieve a conversion efficiency superior to that of direct solar energy conversion by either silicon or germanium solar cells.

Energy Technology Data Exchange (ETDEWEB)

The effect of adding hydrogen to methane as a fuel for spark ignited engines has been extensively investigated. Both the possibility of adding a limited amount of hydrogen as well as equal amounts of hydrogen and carbon dioxide to natural gas has been investigated. A 10 vol% addition of hydrogen to the natural gas caused a reduction in UHC of approximately 40%, and an increase in efficiency of approximately three percentage points at the test engine. It is unknown if the gain is representative for large engines. Similar results for UHC reduction and efficiency were obtained for combined hydrogen and carbon dioxide addition. The carbon dioxide was added by exhaust gas recirculation. However, the price of hydrogen, makes this idea uneconomical even when carbon dioxide is readily available through recirculation of engine exhaust. Adiabatic prereforming may be used to convert natural gas into methane, hydrogen and carbon dioxide in order to generate hydrogen and at the same time increase ...

Energy Technology Data Exchange (ETDEWEB)

In many parts of the United States, as well as other regions of the world, competing demands for fresh water or water suitable for desalination are outstripping sustainable supplies. In these areas, new water supplies are necessary to sustain economic development and agricultural uses, as well as support expanding populations, particularly in the Southwestern United States. Increasing the supply of water will more than likely come through desalinization of water reservoirs that are not suitable for present use. Surface-deployed seismic and electromagnetic (EM) methods have the potential for addressing these critical issues within large volumes of an aquifer at a lower cost than drilling and sampling. However, for detailed analysis of the water quality, some sampling utilizing boreholes would be required with geophysical methods being employed to extrapolate these sampled results to non-sampled regions of the aquifer. The research in this report addresses using seismic and EM methods in ...

Energy Technology Data Exchange (ETDEWEB)

CuO/bentonite and CuO-BHA nanocomposites were studied as oxygen carriers in chemical-looping combustion (CLC) of simulated synthesis gas. Global reaction rates of reduction and oxidation, as the function of reaction conversion, were calculated from 10-cycle oxidation/reduction tests utilizing thermogravimetric analysis at atmospheric pressure between 700 and 900{degree}C. It was found that the reduction reactions are always faster than oxidation reactions; reaction temperature and particle size do not significantly affect the reaction performance of CuO/bentonite. Multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for production of CO{sub 2} from fuel gas at 800 and 900{degree}C and full consumption of hydrogen during the reaction. Results of the tapered element oscillating microbalance showed a negative effect of pressure on the global rates of reduction-oxidation reactions at higher fractional conversions. ...

Energy Technology Data Exchange (ETDEWEB)

The visible semiconductor laser includes an InAlGaP active region surrounded by one or more AlGaAs layers on each side, with carbon as the sole p-type dopant. Embodiments of the invention are provided as vertical-cavity surface-emitting lasers (VCSELs) and as edge-emitting lasers (EELs). One or more transition layers comprised of a substantially indium-free semiconductor alloy such as AlAsP, AlGaAsP, or the like may be provided between the InAlGaP active region and the AlGaAS DBR mirrors or confinement layers to improve carrier injection and device efficiency by reducing any band offsets. Visible VCSEL devices fabricated according to the invention with a one-wavelength-thick (1{lambda}) optical cavity operate continuous-wave (cw) with lasing output powers up to 8 mW, and a peak power conversion efficiency of up to 11%. 5 figs.

Energy Technology Data Exchange (ETDEWEB)

Strong support for the existence of catalytically-active, sub-surface oxygen is proposed. The existence of two types of sub-surface oxygen was determined by thermal-desorption spectroscopy (TDS). The first is termed O{sub {beta}} and is characterized by a board thermal-desorption peak centered at approximately 773 K. The second is referred to as O{sub {gamma}} and is characterized by an unsaturated thermal desorption signal beginning at approximately 873 K. O{sub {gamma}} is assigned to oxygen which is incorporated in the uppermost layers of low-indexed terminating crystal structures such as (111) formed as a result of thermal reordering. O{sub {beta}} diffusion occurs most likely via interstitial jumping and O{sub {gamma}} via interstitialcy diffusion. Both CH{sub 4} conversion and C{sub 2} selectivity improve with time on stream. This improvement in catalytic performance correlates well with surface facetting and particle rupture, which ...

International Nuclear Information System (INIS)

Measurements were carried out for calibration and performance testing of a set of 10 electronic personal dosimeters (EPDs) at the Secondary Standard Dosimetry Laboratory of Sudan. Calibrations were carried out at three X-ray beam qualities described in ISO standard 4037 in addition to 137Cs and 60Co gamma ray beams. The experimental was performed with EPDs mounted on ICRU Slab phantom. X-ray and ?-ray beams were characterized in terms of air kerma free-in-air which were converted to the known delivered personal dose equivalent, Hp(10) using appropriate the air kerma to personal dose equivalent conversion coefficients. Dosimeters tested showed excellent energy and angular response and relative error of indication within the recommended limit for photon energies from 65 keV to 1.25 MeV. The study showed encouraging results for using electronic dosimeters in personal dosimetry.

CERN Document Server

Given an invariant gauge potential and a periodic scalar potential \\tilde{V} on a Riemannian manifold \\tilde{M} with a discrete symmetry group \\Gamma, consider a \\Gamma-periodic quantum Hamiltonian \\tilde{H}=-\\tilde{\\Delta}_{B}+\\tilde{V} where \\tilde{\\Delta}_{B} is the Bochner Laplacian. Both the gauge group and the symmetry group \\Gamma can be noncommutative, and the gauge field need not vanish. On the other hand, \\Gamma is supposed to be of type I. To any unitary representation \\Lambda of \\Gamma one relates a Hamiltonian H^{\\Lambda}=-\\Delta_{B}^{\\Lambda}+V on M=\\tilde{M}/\\Gamma where V is the projection of \\tilde{V} to M. We describe a construction of the Bloch decomposition of \\tilde{H} into a direct integral whose components are H^{\\Lambda}, with \\Lambda running over the dual space \\hat{\\Gamma}. The evolution operator and the resolvent decompose correspondingly. Conversely, given \\Lambda\\in\\hat{\\Gamma}, one can ...

International Nuclear Information System (INIS)

Proton exchange membrane fuel cells (PEMFCs) are attractive because of their high conversion efficiency, low pollution, lightweight, and high power density. A major area of challenges is the design and engineering of active, robust, and low-cost electrocatalysts. This report discusses recent findings of our investigations of the design and nano-engineering of platinum-vanadium-iron catalysts for use in PEMFC. The membrane electrode assembly was prepared using nano-engineered PtVFe nanoparticles with controlled composition and size supported on carbon as cathode electrocatalysts. The electrocatalytic activity and stability of the catalysts have been characterized by both rotating disk electrode and membrane electrode assembly measurements. The trimetallic catalysts have been shown to exhibit excellent electrocatalytic performance in PEMFC in comparison with commercial platinum catalysts. The results exhibited a good agreement between obtained these two ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this report is to summarize the assumptions, dose factors, consumption rates, and methodology used to evaluate potential radiation doses to persons who may eat contaminated wildlife or contaminated plants collected from the Hanford Site. This report includes a description of the number and variety of wildlife and edible plants on the Hanford Site, methods for estimation of the quantities of these items consumed and conversion of intake of radionuclides to radiation doses, and example calculations of radiation doses from consumption of plants and wildlife. Edible plants on the publicly accessible margins of the shoreline of the Hanford Site and Wildlife that move offsite are potential sources of contaminated food for the general public. Calculations of potential radiation doses from consumption of agricultural plants and farm animal products are made routinely and reported annually for those produced offsite, using information about concentrations of ...

Energy Technology Data Exchange (ETDEWEB)

Metallic components within or immediately adjacent to gasifiers, such as gas distributors, thermowells, transfer lines, and cyclones, are subjected to severe of temperature, pressure, and hostile multicomponent gas environments. Metallic heat exchangers/waste-heat boilers resistant to sulfidation, corrosion. and erosion in low- and medium-Btu gas environments are essential components in large-scale gasification schemes, in both dry ash and slogging type gasifiers. Components, in general. must be resistant to corrosion, erosion, and high-temperature creep. A substantial data base is needed on the mechanical properties of materials exposed to complex gas environments to provide a more viable basis for establishing long-term reliability of components. This work examines high-temperature creep of Alloy 800, a high-chromium alloy widely used in coal conversion systems, after exposure to oxygen and oxygen/sulfur mixed-gas environments over a wide ...

Energy Technology Data Exchange (ETDEWEB)

A literature review on gasification of lignocellulosic biomass in various types of fluidized bed gasifiers is presented. The effect of several process parameters such as catalytic bed material, bed temperature and gasifying agent on the performance of the gasifier and quality of the producer gas is discussed. Based on the priorities of researchers, the optimum values of various desired outputs in the gasification process including improved producer gas composition, enhanced LHV, less tar and char content, high gas yield and enhanced carbon conversion and cold gas efficiency have been reported. The characteristics and performance of different fluidized bed gasifiers were assessed and the obtained results from the literature have been extensively reviewed. Survey of literature revealed that several industrial biomass gasification plants using fluidized beds are currently conducting in various countries. However, more research and development of ...

Energy Technology Data Exchange (ETDEWEB)

Electron interference in the presence of nonclassical microwaves with frequency {omega}{sub 1} and classical RF radiation with frequency {omega}{sub 2}, is studied. The relative phase factor between the two electron beams is a quantum-mechanical operator, whose expectation value with regard to the density matrix describing the nonclassical microwaves, determines the interference. It is shown that the visibility of the time-averaged intensity is a constant for all irrational values of {omega}{sub 1}/{omega}{sub 2}, and shows peaks (fractional Shapiro steps) at all rational values. These peaks can provide direct experimental evidence of the highly nonlinear processes of frequency conversion from {ital N} photons with frequency {omega}{sub 1}, to {ital M} photons with frequency {omega}{sub 2}. Results for various types of nonclassical microwaves (e.g., coherent states, squeezed states, number eigenstates, etc.) are derived and a comparison with ...

Science.gov (United States)

All first-stage experimental tests were completed for Task 4 (and the Contract). The first-stage one-liter autoclave tests that were made were duplicates of Run 41-LA. The conditions used were chosen last quarter to reduce the cost of the first-stage of the process from those used at the conclusion of Task 3. Filtration and second-stage tests were made using the products of the first-stage tests. Post-second-stage filtration, tested as an alternative to interstage (pre-second- stage) filtration, resulted in low filtration rates. Different catalyst loadings and type and residence time for second-stage hydrotreating were explored. Longer residence times did not result in significantly more resid conversion. Higher catalyst loadings were more effective in converting the resid at the same residence time. The material and elemental balances for the first-stage were completed. The material and elemental balances for the second-stage were initiated.

Science.gov (United States)

Recent fuel cost increases coupled with energy shortages have resulted in an awareness of the need to conserve energy and to expand the United States domestic energy base. Increase in coal conversion and utilization are major objectives of the research and development activities in the US Department of Energy. Several alternate processing schemes are being developed to convert coal to environmentally acceptable liquid fuels. A few of these technologies are approaching the commercialization stage and scale-up is being carried forward on the most promising processes. The various coal liquefaction processes are discussed by dividing them into four general classifications. Processes for converting various types of coal to synthetic liquid fuels are being improved so that clean fuels can be produced commercially. Emphasis is on the production of fuels suitable for firing industrial and electric utility boilers and on synthetic crude oils for ...

Energy Technology Data Exchange (ETDEWEB)

A new model for fuel spray penetration (location of spray tip) is suggested and validated against available experimental data. Simple analytical expressions for fuel spray penetration are derived in two limiting cases: the initial stage and the two-phase flow regime. At the initial stage, the effects of droplet drag and entrainment of air are accounted for. In the case of the two-phase flow, it is assumed that the spray droplets have the same velocities as the entrained air. The characteristic time of droplet break-up in the spray is estimated for both bag and stripping break-up mechanisms. For realistic diesel spray parameters, the droplet break-up takes place almost immediately after the droplets leave the nozzle. This leads to a considerable shortening of the initial stage and a rapid conversion of the flow to the two-phase stage. This allows the analysis to be restricted to the two-phase flow approximation for this type of spray. The ...

Energy Technology Data Exchange (ETDEWEB)

Breast cancer progression is characterized by inappropriate cell growth. Normal cells cease growth after a limited number of cell divisions--a process called cellular senescence-while tumor cells may acquire the ability to proliferate indefinitely (immortality). Inappropriate expression of specific oncogenes in a key cellular signaling pathway (Ras, Raf) can promote tumorigenicity in immortal cells, while causing finite lifespan cells to undergo a rapid senescence-like arrest. We have studied when in the course of transformation of cultured human mammary epithelial cells (HMEC), the response to overexpressed oncogenic Raf changes from being tumor-suppressive to tumor enhancing, and what are the molecular underpinnings of this response. Our data indicate: (1) HMEC acquire the ability to maintain growth in the presence of oncogenic Raf not simply as a consequence of overcoming senescence, but as a result of a newly discovered step in the process of immortal transformation uncovered by ...

Science.gov (United States)

as for direct energy conversion in specialized direct electrical energy conversion plants. Figure 1. An energetic (~163KeV) proton and a 11boron nucleus fuse ...

Energy Technology Data Exchange (ETDEWEB)

A schematic diagram of the decision making process for air pollution control equipment for the conversion of a fossil-fired generating unit from oil to coal is presented and explained.

Science.gov (United States)

Sunflower power conversion system development test program

International Nuclear Information System (INIS)

... beta decay energy levels energy-level transitions internal conversion

International Nuclear Information System (INIS)

(Jun 1976). United States Tokerud, LD Garcia, R. Aerojet Energy Conversion

Energy Technology Data Exchange (ETDEWEB)

The invention concerns the conversion of steam turbines, particularly condensation turbines, for the economic coupling of process steam and heating steam. The conversion occurs by retaining the basic construction of foundations, housing and bearings as support group and coupling member and matching the specially developed construction for the idea of use into the existing housing, and inserting the rotor into the shaft unit. By having the unchanged supports of the housing and the bearings of the shaft unit, the elasticity in expansion and the vibration behaviour of the turbine are retained and the conversion costs can be lowered.

Energy Technology Data Exchange (ETDEWEB)

Microscopic non-energy weighted sum-rules for the total rates of the neutrinoless ..mu..-e conversion process are constructed in the frame of the shell model for closed shell nuclei. For non-closed shell nuclei the relevant rates were obtained by interpolation. Also the contribution of the coherent process to the total ..mu..-e conversion rate is calculated and discussed.

Energy Technology Data Exchange (ETDEWEB)

The lepton flavor-violating coherent ( /sup -/, e/sup -/) conversion is investigated. Photonic and nonphotonic contributions arising in various gauge models are considered. The dependence of the conversion rate on the structure of the nucleus is given by the elastic form factors. These are obtained in the context of shell model taking into account finite-size effects or extracted from the electron scattering data whenever possible. The relevant branching ratios are studied throughout the periodic table.

International Nuclear Information System (INIS)

Solid state effects are taken into account in an internal conversion coefficients computation by using Wigner-Seitz boundary conditions. Both the bound and free electron wave functions are calculated from an atomic Dirac-Hartree-Fock-Slater self consistent potential. These internal conversion coefficients are compared with those obtained from the usual free atom boundary conditions. (orig.).

Energy Technology Data Exchange (ETDEWEB)

When biomass is used as fuel for thermal conversion plants, minerals from the fuel can be responsible for major problems. Generally, these problems are associated with the existence and development of low melting compounds or eutectics, which form sticky layers. In a fluidised bed, this can result in bed-agglomeration and defluidisation. This causes local high temperature, which often accelerates the process. It ultimately can lead to a completely sintered bed content with a glassy phase gluing the bed particles together and shut-down of the plant. The main objective of the title project is to develop a methodology to predict ash/bed agglomeration and sintering problems, to indicate related problems and, furthermore, to identify solution methods to make different types of biomass streams more viable for energy production. Within the present study, selected fuels are subjected to different existing methods together with some new ones, in order ...

Energy Technology Data Exchange (ETDEWEB)

Measurements of temperature and NO concentration in laminar, partially premixed methane-air flames stabilized on a ceramic burner in coflow are reported. The NO concentration and temperature were determined by laser-induced fluorescence (LIF) and coherent anti-Stokes Raman scattering (CARS), respectively. Upstream heat loss to the burner was varied by changing the exit velocity of the fuel-air mixture at a constant equivalence ratio of 1,3; this alters the structure of the flame from an axisymmetric Bunsen-type to a strongly stabilized flat flame. To facilitate analysis of the results, a method is derived for separating the effects of dilution from those of chemical reaction based on the relation between the measured temperature and the local mixture fraction, including the effects of upstream heat loss. Using this method, the amount of NO formed during burnout of the hot, fuel-rich combustion products can be ascertained. In the Bunsen-type ...

International Nuclear Information System (INIS)

Apoptosis, or programmed cell death (PCD), is a fundamental process that protects organismal integrity. In earlier work, we demonstrated that over-expression of either of two anti-apoptotic members of the BCL-2 family (BCL-2 or BCL-X L could elevate the frequency of radiation-induced mutations at the autosomal TK1 locus in human TK6 lymphoblasts that express wild-type TP53. Ectopic expression of BCL-X L also elevated the frequencies of double-strand break-induced gene conversion. The purpose of this study is to determine if BCL-2 family proteins promote radiation mutagenesis indirectly through their suppression of PCD, or whether the 'pro-mutagenic' function of these proteins can be separated from their anti-apoptotic function. We developed stable transfectants of TK6 cells that express a mutated form of BCL-X L with a single amino acid substitution in the BH1 domain that is known to interfere with the ability to suppress PCD (BCL-X L ...

Energy Technology Data Exchange (ETDEWEB)

An investigation was conducted into alternative techniques for zinc and electrolyte regeneration and reuse in the refuelable zinc/air battery that was developed by LLNL and previously tested on a moving electric bus using cut wire. Mossy zinc was electrodeposited onto a bipolar array of inclined Ni plates with an energy consumption of 1.8 kWh/kg. Using a H{sub 2}-depolarized anode, zinc was deposited at 0.6 V (0.8 kA/m{sup 2}); the open circuit voltage was 0.45 V. Three types of fuel pellets were tested and compared with results for 0.75 mm cut wire: spheres produced in a spouted bed (UCB); coarse powder produced by gas-atomization (Noranda); and irregular pellets produced by chopping 1-mm plates of compacted zinc fines (Eagle-Picher, Inc.). All three types transported within the cell. The coarse powder fed continuously from hopper to cell, as did the compacted pellets (< 0.83 mm). Large particles (> 0.83 mm; Eagle-Picher and UCB) ...

British Library Electronic Table of Contents (United Kingdom)

Oxidation of propylene with oxygen, air and a mixture of nitrogen?oxygen in a barrier discharge is investigated. The selectivity towards formation of propylene oxide in pure oxygen is shown to be as high as 45 wt% and the propylene conversion ratio is found to be 12.9 wt%. In the oxidation with air, the propylene oxide selectivity is 23 wt%, while the conversion is 7.5 wt%. The values of propylene conversion and selectivity towards formation of propylene oxide in a barrier discharge are consistent with those obtained by the thermocatalytic methods for production of propylene oxide.

Energy Technology Data Exchange (ETDEWEB)

Red mud, and red mud activated by dissolution in hydrochloric acid and reprecipitation with ammonia, were tested as catalysts for the hydrogenation of an anthracene oil in a trickle-bed reactor. Conversion data were determined for the different polyaromatic compounds in the anthracene oil. Red mud shows appreciable catalytic activity, which is enhanced by the activation. Although both red mud and activated red mud are less active than a commercial Ni-Mo/[gamma]-alumina hydrotreating catalyst, the difference in activity is smaller when conversion to hydroaromatics instead of total conversion of reactants is considered. 20 refs., 8 figs., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

Physical processes in the region of laser conversion for the next Linear Colliders (NLC) are discussed. The main goal of this conversion is to obtain high-energy intense #gamma# beams for #gamma#e and #gamma##gamma# colliders. This conversion has important by-products: (i) one can observe here effect of nonlinear QED (in a strong external field)-production of e"+e"- pairs by a high-energy photon and emission of very high-energy photons by an electron; (ii) one can produce and observe here the invisible axion in colliding #gamma#_0e beams. The NQED effects also result in variation of the spectra of high-energy photons and an additional background. 12 refs., 12 figs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

Apparatus and method are described for the vaporization of liquid fuel oils to produce a gaseous mixture suitable for burning in a burner normally designed for operation utilizing natural gas.

UK PubMed Central (United Kingdom)

BackgroundMutations that disrupt the conversion of prelamin A to mature lamin A cause the rare genetic disorder Hutchinson-Gilford progeria syndrome and a group of laminopathies....Full Text Available

Science.gov (United States)

... This is the case for the 82nd Airborne Division ready brigade force (DRB) and the Military Airlift Command (MAC) strategic airlift system operating ...

Energy Technology Data Exchange (ETDEWEB)

To investigate mechanisms responsible for positive and negative transcriptional control, the authors have utilized two types of promoters that are diffferentially regulated by thyroid hormone (T{sub 3}) receptors. Promoters containing the palindromic T{sub 3} response element TCAGGTCA TGACCTGA are positively regulated by the T{sub 3} receptor after the administration of T{sub 3}, whereas otherwise identical promoters containing the estrogen response element TCAGGTCA CTG TGACCTGA can be regulated negatively; converse effects are observed with the estrogen receptor. They describe evidence that the transcriptional inhibitory effects of the T{sub 3} or estrogen receptors on the estrogen or T{sub 3} response elements, respectively, are imposed by amino acid sequences in the C'-terminal region that colocalize with dimerization and hormone-binding domains and that these sequences can transfer inhibitory functions to other classes of ...

Energy Technology Data Exchange (ETDEWEB)

Among the most promising technological alternatives for the development of photovoltaic modules and cells of a low cost, good energetic conversion and feasibility for mass production, polycrystalline silicon thin film solar cells deposited directly on a transparent substrate are currently being considered the best. We have developed in our laboratory a PECVD reactor capable of producing the deposition of amorphous hydrogenated silicon at rates of above 2 nm/seg, allowing a significant production per line on the plant. Discharge gas is silane, to which diborane or phosphine is added so as to form the cell. Basically, work is done on a structure of cell type TCO/n+/p-/p+/M, which has 2 {mu}m of total thickness. Schott AF-37 glass is used as a substrate, for their ability to withstand temperatures of up to 800 C. The amorphous cell is subsequently annealed at gradual temperatures of 100 C to achieve dehydrogenation up to 650-700 C for 12 h until ...

Energy Technology Data Exchange (ETDEWEB)

The cost of liquid fuels from coal is a complex function of many factors, such as capital investment, cost of coal and labor cost. Furthermore, the cost will depend on geographical position, the size of the operation and the efficiency of the process. There is no single answer and case studies will have to be made to establish economics at different locations. In the following, the 1980 order-of-magnitude investment costs and operating costs for a coal liquefaction plant are estimated. For a Sasol II type of plant with the product output indicated earlier, the total capital cost is estimated at $4 billion in 1980 dollars. Capital cost accounts for approximately 50%, utilities and materials for 30%, and labor for 20% of the total cost. Given the market value of by-product ethylene ($175/t), tar products ($300/t), chemicals ($300/t), ammonia ($200/t) and sulfur ($25/t), the credit for by-products is $146 million per year. The cost of motor fuel is thus estimated at ...

Energy Technology Data Exchange (ETDEWEB)

The aim with this project sponsored by Energimyndigheten is to develop a method for calculations of grate boilers fueled by bark. This report describes this project, 'Evaluation Method for Grate Combustion' (EMGC). CFD codes is an engineering tool applicable in the area of the over-grate section called the furnace. This part of the boiler is easy to model for an experienced CFD code user and the results are usually quite satisfactory for evaluating the combustion process in general. Various gas phases reactions and related combustion processes over the burning bed can be simulated including air staging, fuel staging and SNCR. However the simulation needs information of amount and properties of the burning bed products, entering the furnace. The simulation of the in-furnace processes without this information is often just a numerical speculation. A predictive mathematical model based on physical and chemical data for the grate and fuel bed would solve this problem. ...

International Nuclear Information System (INIS)

The IAEA Department of Safeguards established a project in 1996 for the year 2000 (Y2K) conversion activities. This project covered assessment, conversion and testing of the software applications, instrument evaluation software, embedded systems and Personal Computer (PC) hardware attached to various equipment. Significant progress has been made in converting the applications and instruments to be year 2000 compliant. At the same time Member states have made an effort as well in converting the systems used jointly at the facilities

British Library Electronic Table of Contents (United Kingdom)

The catalytic performance of alkaline-treated zeolite H-ZSM-5 in the conversion of methanol to gasoline has been studied. After treatment with 0.20M NaOH, the total conversion capacity increased by a factor of 3.3, and the selectivity towards the gasoline fraction increased by a factor of 1.7. Physical characterization indicated the formation of mesopores and improved crystallinity.

Energy Technology Data Exchange (ETDEWEB)

This paper reports the effectiveness of solvents on the liquefaction of 11 different Turkish lignites investigated by using tetralin, creosote, and anthracene oils. The highest total conversions were obtained with tetralin. The catalytic effects of CoMo and red mud were compared by using creosote oil as the solvent. It was found that red mud catalyzed mainly the asphaltene formation reaction for the given experimental conditions. The additional of CoMo significantly catalyzed the liquefaction reaction, thus increasing the lignite conversion and oil formation.

Energy Technology Data Exchange (ETDEWEB)

The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.

Energy Technology Data Exchange (ETDEWEB)

This thesaurus contains the vocabulary used to index the Biomass Database maintained by the IEA Biomass Conversion Technical Information Service. The database, which is used to produce Biomass Abstracts, contains indexed and abstracted references to the published literature relating to biomass energy including cultivations, harvesting, materials handling, conversion techniques, environmental aspects and economics.

Energy Technology Data Exchange (ETDEWEB)

Nine coals from Spanish, British, German and American mining basins were hydrogenated using Fe catalyst precursors (red mud and FeSO{sub 4}), without solvent at 300, 350, and 400 {degree}C and 10 MPa of H{sub 2}. Overall conversion and product distribution are related to the textural characteristics of the original coals and are studies throughout the distinct hydrogenation processes. Results reveal that with FeSO{sub 4} as a catalyst precursor, conversions increase with coal surface area. However, when red mud (RM) is used, conversions are independent of coal textural characteristics. Higher conversions are obtained with FeSO{sub 4} than with RM at 300 and 350 {degree}C whereas at 400 {degree}C higher conversions are obtained with RM. This different catalytic activity is also reflected in the changes of the textural characteristics observed in each case. Up to 350 {degree}C, the ...

British Library Electronic Table of Contents (United Kingdom)

This paper addresses the unique structural requirements for successful conversion of tankers for floating production storage and offloading (FPSO) or floating storage and offloading (FSO) service. A description is given of the steps undertaken during two recent and very different conversions of a highly optimized 1980s VLCC to FPSO service, and a typical robust 1970s ULCC to FSO service. The paper describes the steps needed for ensuring the FPSO or FSO requirements are successfully met during conversion of the two tankers - each having its own history, e.g. date of build, original design, material choices, class society, voyage history and repairs. Firstly, the paper describes the procedure and results of an early initial structural assessment procedure on the basis of an American Bureau o...

Energy Technology Data Exchange (ETDEWEB)

The Science Council accepted the recommendations of the Swan Wooster report on Opportunities for coal liquefaction research in British Columbia, Vancouver, BC, Canada, Science Council of British Columbia, 173 pp (May 1980), following review by the Sub-committee on Coal Research. The Sub-Committee has recommended a four year Research and Development programme on B.C. coals to be carried out at B.C. Research Council. About 5 million dollars would be spent during the four year period. The overall objective is to provide sufficient technical data to identify and evaluate coal conversion opportunities in B.C. A significant secondary objective is to provide a group of trained engineers and scientists in the Province familiar with the technology of coal conversion. (1 ref.)

Energy Technology Data Exchange (ETDEWEB)

Conversion of the microprocessors and software for the Mold Heating and Cooling (MHAC) pump package control systems was initiated to allow required system enhancements and provide data communications capabilities with the Plastics Information and Control System (PICS). The existing microprocessor-based control systems for the pump packages use an Intel 8088-based microprocessor board with a maximum of 64 Kbytes of program memory. The requirements for the system conversion were developed, and hardware has been selected to allow maximum reuse of existing hardware and software while providing the required additional capabilities and capacity. The new hardware will incorporate an Intel 80286-based microprocessor board with an 80287 math coprocessor, the system includes additional memory, I/O, and RS232 communication ports.

International Nuclear Information System (INIS)

This paper examines cupric chloride solid conversion during hydrolysis in a thermochemical copper-chlorine (Cu-Cl) cycle for hydrogen production. The hydrolysis reaction is a challenging step, in terms of the excess steam requirement and the decomposition of cupric chloride (CuCl_2) into cuprous chloride (CuCl) and chlorine (Cl_2). The hydrolysis and decomposition reactions are analyzed with respect to the chemical equilibrium constant. The effects of operating parameters are examined, including the temperature, pressure, excess steam and equilibrium conversion. A maximization of yield and selectivity are very important. Rate constants for the simultaneous reaction steps are determined using a uniform reaction model. A shrinking core model is used to determine the rate coefficients and predict the solid conversion time, with diffusional and reaction control. These new results are useful for scale-up of the engineering ...

International Nuclear Information System (INIS)

Pollen morphology of 30 species of the family Acanthaceae belonging to 11 genera has been investigated using light and scanning electron microscope. Acanthaceae is a eurypalynous family. Pollen are usually radially symmetrical, isopolar, sub-prolate to prolate rarely prolate-spheroidal or sub-oblate to oblate-spheroidal, generally tricolporate or heterocolporate rarely colpate or porate. Exine ornamentation varies from medium to coarse reticulate, or often lopho-reticulate with luminae perforated to baculate or scabrate. On the basis of apertural type, exine ornamentation and colpal membrane eight distinct pollen types have been recognized viz., Pollen type-I: Barleria cristata-type, Pollen type-II: Blepharis ciliaris-type, Pollen type-III: Hygrophila polysperma - type, Pollen type-IV: Justicia ...

Science.gov (United States)

vehicles including the H2-A rocket and the space shuttle. .... The vacuum can's main function is to provide a high vacuum so that the science experiment and its sensors ... EMI-shielded power conversion from the incoming ISS power supply. 4. ...

Energy Technology Data Exchange (ETDEWEB)

The present invention relates to a method of recycling polymeric waste products into monomers and high value forms of carbon by pyrolytic conversion using an induction coupled RF plasma heated reactor.

Energy Technology Data Exchange (ETDEWEB)

The purpose of the conversion process is to convert the {sup 233}U fluoride compounds that are being extracted from the Molten Salt Reactor Experiment (MSRE) equipment to a stable oxide for long-term storage at Bldg. 3019.

Energy Technology Data Exchange (ETDEWEB)

Purpose: calculation of conversion coefficients for the reconstruction of organ doses from entrance doses for abdomen radiographs of 0, 1, 5, 10, 15, and 30-year-old patients in conventional pediatric radiology for the radiographic settings recommended by the German and European guidelines for quality management in diagnostic radiology. Materials und method: using the commercially available personal computer program PCXMC developed by the Finnish Center for Radiation and Nuclear Safety (Saeteilyturvakeskus STUK), conversion coefficients for conventional abdomen radiographs were calculated performing Monte Carlo simulations in mathematical hermaphrodite phantom models describing patients of different ages. The possible clinical variation of beam collimation was taken into consideration by defining optimal and suboptimal radiation fields on the phantoms' surfaces. Results: conversion coefficients for the ...

UK PubMed Central (United Kingdom)

The speA gene in Bacillus subtilis encodes arginine decarboxylase, which catalyzes the conversion of arginine to agmatine. Arginine decarboxylase is an important enzyme...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Electron cyclotron emission (ECE) can be used to determine the electron temperature profile in magnetized plasmas. The complex structure of the magnetic field configuration in the Large Helical Device (LHD), which has a large shear, complicates the analysis of the ECE spectrum. In a sheared magnetic field the propagation of X and O-mode polarization through the plasma are coupled, causing mode conversion and polarization rotation. Mode scrambling is also caused by wall reflections. In this report, this mode conversion in LHD is numerically analyzed. It was found that at low density mode conversion scrambles the ECE spectra. However, at higher density (n{sub eo} > 1.0{center_dot}10{sup 19} m{sup -3}) the polarization mode is found to rotate with the sheared magnetic field, yielding only a negligible mode conversion. Wall reflections are found to depolarize the ECE spectrum. Notwithstanding the LHD ...

UK PubMed Central (United Kingdom)

Dimethacrylate polymers and composites are seeing increased usage in orthopedics. As these applications require the material to integrate with the surrounding tissues, direct contact cytotoxicity...Full Text Available

International Nuclear Information System (INIS)

Extra-terrestrial exploration and development missions of the next century will require reliable, low-mass power generation modules of 100 kW_e and more. These modules will be required to support both fixed-base and manned rover/explorer power needs. Low insolation levels at and beyond Mars and long periods of darkness on the moon make solar conversion less desirable for surface missions. For these missions, a closed Brayton cycle energy conversion system coupled with a reactor heat source is a very attractive approach. The authors conducted parametric studies to assess optimized system design trends for nuclear-Brayton systems as a function of operating environment and user requirements. The inherent design flexibility of the closed Brayton cycle energy conversion system permits ready adaptation of the system to future design constraints. This paper describes a dramatic contrast between system designs requiring man-rated ...

Energy Technology Data Exchange (ETDEWEB)

A process is described for covering methane to a higher order hydrocarbon comprising contacting a gaseous reactant consisting of methane with a phosphate-containing catalyst for a sufficient period of time and at an effective temperature to provide the phosphate-containing catalyst consisting essentially of the higher order hydrocarbon. The catalyst is represented by a formula.

UK PubMed Central (United Kingdom)

BackgroundThe immunoregulatory enzyme indoleamine 2,3-dioxygenase, which catalyzes the conversion of tryptophan into kynurenine, is expressed in a significant subset of patients...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The authors investigate the possibility of the direct heterogeneous catalytic synthesis of ethylbenzoate from benzonitrile. The catalysts tested were oxides of aluminium, titanium, and vanadium. The main conversion product detected chromatographically was ethylbenzoate; benzaldehyde, benzamide, and benzanilide were also identified. Aluminium oxide was found to be the most effective catalyst.

Energy Technology Data Exchange (ETDEWEB)

In order to develop a high-efficiency coal pyrolysis method, flash pyrolysis was experimented on slurry prepared by using liquid-phase oxidation reformed coal and a methanol-based solvent mixture. Australian Morwell coal was used for the experiment. The oxidized coal, into which carboxyl groups have been introduced, has the condensation structure relaxed largely, and becomes highly fluid slurry by means of the solvent. Char production can be suppressed by making the oxidation-pretreated coal into slurry, resulting in drastically improved pyrolytic conversion. The slurry was divided into dissolved solution, dried substance, extracted residue, and residual slurry, which were pyrolized independently. The dissolved solution showed very high conversion. Improvement in the conversion is contributed by separating the dissolved substances (coal macromolecules) at molecular levels, coagulating the molecules, suppressing cross-link ...

Energy Technology Data Exchange (ETDEWEB)

The 7 conference papers in Vol. 9 review the implications of environmental problems and discuss the consequences of pollution abatement measures, especially for the economics of energy conversion. The future developments of pollutant emissions are assessed.

Wastenet

...wood smoke, emissions, pollution, heaters, environment, Earthbeat - 25/5/2002: Woodsmoke, Health & the Environment Love that Planet All in the Mind The Buzz Health Report In Conversation Ockhams Razor Science Show The Lab Health Matters Catalyst Quantum ...

British Library Electronic Table of Contents (United Kingdom)

A new process for the hydrogenation of coal in the presence of wide-cut coal tar was proposed; it involves cavitation treatment, mixing with catalytic additives, and heating the resulting mixture at an elevated pressure in an atmosphere of hydrogen. The yields of hydrocarbon fractions to 300?C and gas condensate were evaluated.

Science.gov (United States)

DOE is supporting the development of several conversion processes that are currently in the pilot plant stage. Each of these processes is described briefly and information given as to contractor, contract, funding, site and current progress. Several support projects are treated similarly. (LTN)

Energy Technology Data Exchange (ETDEWEB)

The objective of this project is to identify feasible Louisiana-grown biomass crops and residues, to combine these with technically and economically feasible conversion processes, and to provide integrated biomass energy production systems in Louisiana. Among the recommended integrated systems are: cotton gin trash and rice hull processing residues used for either direct combustion or methane or ethanol production. Steam generation via direct combustion is recommended. Hardwood chips are economically feasible despite considerable price and supply instability, while high sugar or starch content crops are easily converted to ethanol but limited by price. Possible breakthroughs in biomass production or in the hydrolysis of starch or cellulose substrates may decrease processing costs. Recommended areas for future study dealing with production include: (1) increase biomass availability and density; (2) increase harvesting, transportation and storage technologies; (3) ...

Energy Technology Data Exchange (ETDEWEB)

The overall goal of the Gas-to-Liquids Program at the U.S. Department of Energy`s Pittsburgh Energy Technology Center (PETC) is to develop technologies for the production of hydrocarbon fuels and premium chemicals from light alkane gases. PETC`s current Gas-to-Liquids Program comprises the development of four primary advanced conversion technologies, namely, partial oxidation, oxidative coupling, oxyhydrochlorination, and novel conversion processes. Based on the current state of development, it can be concluded that, in the near future, one or more of these technologies will reach proof-of-concept demonstration. Oxyhydrochlorination is the most advanced direct conversion technology, and the synthesis of lower cost methyl chloride from natural gas would impact several commercial technologies that utilize methyl chloride as an intermediate to high value products. Technology development for the partial oxidation of methane to ...

Energy Technology Data Exchange (ETDEWEB)

This report describes studies made during the fourth quarter of 1986 using the revised microautoclave experimental technique. Studies were made of the effect of reaction time on conversion using Kemmerer coal. Results that, at least during the first 30 minutes, conversion is a monotonically increasing function of reaction time and temperature. A study was also made of the effect of temperature on conversion. In general, conversion increased with temperature. The reactivity of coal appears to be unaffected by exposure to Certigrav fluid, if the exposed coal is subjected to two acetone washings under a nitrogen blanket. Work was started on using SCR-II process solvent in place of tetralin. Results indicate that SRC-II process solvent is a satisfactory solvent donor for high reactivity, high ash bituminous coals, but slightly less effective for low ash, subbituminous coals. Some tests were made to examine ...

Science.gov (United States)

THE GFS WILL BE THAT THE DEFAULT PRECIPITATION TYPE ALGORITHM WILL CHANGE FROM THE BALDWIN METHOD TO THE DOMINANT PRECIPITATION TYPE. THE DOMINANT PRECIPITATION TYPE IS...

Energy Technology Data Exchange (ETDEWEB)

This paper reports on the results of experiments into efficient higher-order anti-Stokes Raman conversion of tunable short-pulse XeCl laser radiation. The maximum output energy of the pumping laser, in which the radiation of a frequency-doubled dye laser is amplified by two XeCl laser amplifiers, is 55 mJ with a pulse duration of 1 ns FWHM. Using hydrogen gas as a Raman medium, a series of anti-Stokes lines up to the 12th order (121.5 nm) is generated in the vacuum ultraviolet (VUV) region. 16 references.

Energy Technology Data Exchange (ETDEWEB)

Polymer electrolyte membrane fuel cells (PEMFCs) are energy conversion devices that produce electricity from a supply of fuel, such as hydrogen. One of the major challenges in achieving efficient energy conversion is the development of cost-effective materials that can act as electrocatalysts for PEMFCs. In this letter, we demonstrate that, instead of conventional noble metals, such as platinum, chromium nitride nanocrystals of fcc structure exhibit attractive catalytic activity for PEMFCs. Device testing indicates good stability of nitride nanocrystals in low temperature fuel cell operational environment.

Energy Technology Data Exchange (ETDEWEB)

This paper reports the presence of face centered cubic cobalt precipitates inside tungsten carbide in nanocomposite of WC-Co synthesized by spray conversion processing. EDS was used to identify the presence and micro-diffraction was employed to determine the nature of the precipitates. There is entrapment of cobalt in tungsten carbide during the spray conversion process used to form WC/Co powder. During consolidation, at high temperatures, the cobalt attains enough mobility to precipitate inside WC. A vanadium containing compound was seen at the interfaces in samples which incorporated VC as a grain growth inhibitor. (orig.)

Science.gov (United States)

Fluidized bed technology was experimentally evaluated for the combustion and gasification of cotton gin waste. The isothermal bed temperatures in the reactors could be maintained below the ash fusion point of the waste. Raw stripper harvested cotton gin trash could be metered directly into the fluidized-bed reactors indicating that little feed preparation is required. H and CO were the primary products of gasification, and approximately 3200-400 Btu of gas were produced per lb of cotton gin waste. These techniques offer the potential of providing small-scale energy conversion systems for use on farms.

Energy Technology Data Exchange (ETDEWEB)

The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.

Energy Technology Data Exchange (ETDEWEB)

The Reduced-Moderation Water Reactor (RMWR) is a next generation water-cooled reactor, based on the experienced light water reactor (LWR) technology, aiming at effective utilization of uranium resources, high burn-up and long operation cycle and plutonium multiple recycling. These characteristics can be achieved by the high conversion ratio from {sup 238}U to {sup 239}Pu resulted from the higher neutron energy spectrum in comparison to conventional LWRs. Considering the extension of LWR utilization, Japan Atomic Energy Research Institute (JAERI) started the research on it in 1997 and then started a collaboration in the conceptual design study with the Japan Atomic Power Company (JAPC) in 1998, under technical cooperation with three Japanese reactor vendors. In the core design study of the RMWR, several basic core designs with the high conversion ratio more than 1 and the negative void reactivity coefficient have been proposed, and then, ...

International Nuclear Information System (INIS)

The precipitation reaction of some rare earth chlorides (La/Ce/Nd/GdCl3) in a LiCl-KCl molten salt has been carried out by using the oxygen sparging method. In this study, regardless of the oxygen sparging time and the molten salt temperature, oxychlorides (REOCl) for LaCl3, NdCl3 and GdCl3, and an oxide (REO2) for CeCl3 are formed as a precipitate. The conversion of rare-earth chlorides into insoluble precipitates was described by using a conversion ratio. The conversion ratio increased exponentially with the oxygen sparging time and finally showed asymptotic value at 1,023K of the molten salt temperature condition. The conversion ratios of LaCl3, NdCl3 and GdCl3 were increased with the molten salt temperature, however, even though the conversion ratio was increased from 0.660 to 0.995 with increasing molten salt temperature from 823 to 923 K at 60 min of a sparging time, the ...

KoreaScience (Korea)

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KoreaScience (Korea)

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International Nuclear Information System (INIS)

... Natural convection cooling of the channel type reactor performed with the fuel

Energy Technology Data Exchange (ETDEWEB)

The Energy Conversion and Storage Program applies chemistry and materials science principles to solve problems in (1) production of new synthetic fuels, (2) development of high-performance rechargeable batteries and fuel cells, (3) development of advanced thermochemical processes for energy conversion, (4) characterization of complex chemical processes, and (5) application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis. Electrochemistry research aims to develop advanced power systems for electric vehicle and stationary energy storage applications. Topics include identification of new electrochemical couples for advanced rechargeable batteries, improvements in battery and fuel-cell materials, and the establishment of engineering ...

Energy Technology Data Exchange (ETDEWEB)

This report describes progress on the Advanced Coal Liquefaction project by the Gulf Research and Development Company's Merriam Laboratory during the months of January through March 1983. The liquefaction behavior of Illinois No. 6 coal beneficiated in various ways was studied in both single-stage recycle (SRC II) and short contact time (SCT) modes of operation. The distillate yield increased as the iron level in the feed slurry increased in both modes of operation. In the SCT mode, the conversion increased at greater depths of cleaning. In the SRC II mode, the distillate yield and conversion were much higher with deep cleaning and add-back of pyrite than with conventional cleaning. Pyrite addition resulted in a significant increase in short contact time conversion of subbituminous Belle Ayr coal in both high and low quality solvents. Solvent quality itself, however, had little effect on ...

International Nuclear Information System (INIS)

Two-dimensional calculations are performed to obtain the conversion efficiency of traveling wave direct energy convertor adopted in a conceptual design of field reversed configuration D-"3He fusion reactor ARTEMIS. For fusion-born 14.67MeV protons, the efficiency obtained is very small compared with that from one-dimensional analysis. This is because the effective electric field for deceleration of the proton is smaller due to distortion of potentials near girds used to excite the traveling wave and because some fractions of the incident proton beams are inevitably lost to the grids with high energy. To increase the efficiency, the potentials may have to be increased. It seems from the two-dimensional analysis performed here that the conversion efficiency obtainable is less than about 60% with the maximum potential of about 6MV, while the corresponding values from the one-dimensional analysis are about 80% and 1.5MV, respectively. (author).

Energy Technology Data Exchange (ETDEWEB)

The selective catalytic reduction of nitric oxide by methane over copper ion-exchanged natural zeolites was investigated in a packed-bed tubular reactor. The catalytic activity of Cu-N and Cu-H-N catalysts was confirmed as NO, CH{sub 4}, and O{sub 2} displayed very little reaction in the absence of any catalyst and zeolite without ion exchange was totally inactive. A maximum NO conversion of 33% at 650 C for Cu-N-66 was achieved with 2% NO and 1% CH{sub 4} and a contact time of 0.9 g s/cm{sup 3}, but the introduction of 2% O{sub 2} reduced the NO conversion to only 12%. Ion exchange for the H-form prior to copper ion exchange was essential for oxygen to promote catalytic activity over the temperature range 250--650 C, with a maximum conversion of 30% at 450 C with O{sub 2} present. The direct reduction of NO by methane was ruled out as a possible reaction pathway.

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to analyze the safeties and the economics for Co-60 production from Wolsung PHWR and to verify the feasibility on the manufacturing of the final Co-60 source for industrial irradiation. The feasibility of reactor conversion was carried out with KEPCO collaboration. Through the site survey on the experience of Gentililly-2 in Canada, a feasibility of plant conversion, changes in design, equipment and tools for Co-60 production was verified. It was estimated that the reactor conversion would not impose adverse impact on plant safety. For the encapsulation of radiation source and storage of the final products, a modification of concrete hot cell at KAERI was primary concerns. The installation and improvement of facilities are needed to avoid cross contamination and extra radiation exposure. Main items for these are pressure gauge, separated HEPA filter the ceiling separation, extra-shielding and ...

Energy Technology Data Exchange (ETDEWEB)

For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is oxidized preferentially, and a portion with low reactivity remains finally. Minerals in coal are known to accelerate the ...

International Nuclear Information System (INIS)

Single crystals of semi-organic L-histidine hydrobromide have been grown by slow evaporation technique from a mixture of L-histidine and hydrobromic acid in aqueous solution at ambient temperature. From high-resolution X-ray diffraction analysis, the crystalline perfection of the grown crystal has been studied. Single crystal X-ray diffraction analyses, Nuclear Magnetic Resonance spectral analysis, Thermo-Gravimetry (TG), Differential Thermal Analysis (DTA) and hardness test have been employed to characterize the as-grown crystals. The UV cutoff wavelength of the grown crystal is below 300 nm and has a wide transparency window, which is suitable for second harmonic generation of laser in the blue region. Nonlinear optical characteristics have been studied using Q switched Nd:YAG laser (#lambda#=1064 nm). The second harmonic generation conversion efficiency of the grown crystals confirms their suitability for frequency conversion applications.

Energy Technology Data Exchange (ETDEWEB)

This report details the status of the Biological Conversion of Synthesis Gas Project. The following tasks are described as being completed: (1) the test plan, (2) culture development, and (3) the mass transfer/kinetic studies. The bioreactor studies (Task 4) are underway. The continuous stirred tank reactor system for the conversion of H{sub 2}S to elemental sulfur using Chlorobium thiosulfatophilum has been studied for varying light intensities. The system was also modified to include both sulfur recovery and cell recycle using ceramic membranes. Studies were also performed to observe the effects of cell recycle using a polysulfone hollow filter membrane module. Work on Task 5, limiting conditions/scale-up, includes a scale-up study with three different size reactors to establish the optimum operating conditions for hydrogen production from synthesis gas by the biological water-gas shift reaction using the photosynthetic bacterium ...

Energy Technology Data Exchange (ETDEWEB)

Red mud is generated as a by-product in the production of Al(OH){sub 3}/Al{sub 2}O{sub 3} from bauxite ore. In this study the pellet-type adsorbents have been made from the red mud, and their adsorption capacities of heavy metal ions have been tested. The pellet-type adsorbents were synthesized to utilize the excellent adsorption capacity of the powder-type adsorbent for industrial application. The pellet-type adsorbents were prepared by mixing several kinds of additives with the red mud. It is found that the pellet-type adsorbent, made by sintering a mixture of red mud (96.0 wt%), polypropylene (2.5 wt%), fly ash (0.5 wt%), and sodium meta-silicate (1.0 wt%) at 1200 deg.C for 30 minutes, has the highest adsorption capacity. In this work, the two kinds of pellet-type adsorbents (bead-type, crushed-type) were prepared. ...

International Nuclear Information System (INIS)

Forty resected cases of intrahepatic cholangiocarcinoma were classified into four types according to the gross appearance; type I: mass forming type (n=8), type II: mass forming with periductal infiltrating type (n=20), type III: periductal infiltrating type (n=9) and type IV: intraductal growth type (n=3). Diagnostic features of these four types were studied. Peripheral enhancement was a common angiographic feature and tumor stains were recognized in 88%, 20%, 0%, 33%, respectively. Angiography and dynamic computed tomography (D-CT) were useful in differential diagnosis with hepatocellular carcinoma. Accuracy rate in diagnosis of portal vein involvement by angiography and D-CT was 82% and 91%, respectively. MRI was more useful in tumor detection than D-CT in cases with ...

Energy Technology Data Exchange (ETDEWEB)

Although destruction of United States wetlands has slowed, their continued conversion, especially in certain inland regions of the country, may pose adverse ecological effects over the next few decades. The Army Corps of Engineers' regulatory program (Section 404 of the Clean Water Act) protects most coastal wetlands, but provides no protection for 95% of the country's wetlands which remain inland. These inland, freshwater wetlands, converted for agricultural purposes, comprise 80% of the wetland losses over the past 30 years. This report outlines options for more effective federal management, such as the mapping and categorizing of wetlands to determine relative values. In effect, agencies can focus protection programs on higher-value wetlands, especially those threatened by agricultural conversion. The report also discusses the contradictory federal policies aimed at wetlands; for example, the tax code encourages the ...

CERN Document Server

The process of radiation induced electron capture by protons or deuterons producing new ultra low momentum neutrons and neutrinos may be theoretically described within the standard field theoretical model of electroweak interactions. For protons or deuterons in the neighborhoods of surfaces of condensed matter metallic hydride cathodes, such conversions are determined in part by the collective plasma modes of the participating charged particles, e.g. electrons and protons. The radiation energy required for such low energy nuclear reactions may be supplied by the applied voltage required to push a strong charged current across a metallic hydride surface employed as a cathode within a chemical cell. The electroweak rates of the resulting ultra low momentum neutron production are computed from these considerations.

Science.gov (United States)

A phase 2 study has been initiated to investigate surfactant-assisted coal liquefaction, with the objective of quantifying the enhancement in liquid yields and product quality. This report covers the second quarter of work. The major accomplishments were: completion of coal liquefaction autoclave reactor runs with Illinois number 6 coal at processing temperatures of 300, 325, and 350 C, and pressures of 1800 psig; analysis of the filter cake and the filtrate obtained from the treated slurry in each run; and correlation of the coal conversions and the liquid yield quality to the surfactant concentration. An increase in coal conversions and upgrading of the liquid product quality due to surfactant addition was observed for all runs.

British Library Electronic Table of Contents (United Kingdom)

An experimental investigation on the thermal decomposition of CH4 into C and H2 was carried out using a 5kW particle-flow solar chemical reactor tested in a solar furnace in the 1300-1600K range. The reactor features a continuous flow of CH4 laden with mm-sized carbon black particles, confined to a cavity receiver and directly exposed to concentrated solar irradiation of up to 1720 suns. The reactor performance was examined for varying operational parameters, namely the solar power input, seed particle volume fraction, gas volume flow rate, and CH4 molar concentration. Methane conversion and hydrogen yield exceeding 95% were obtained at residence times of less than 2.0s. A solar-to-chemical energy conversion efficiency of 16% was experimentally reached, and a maximum value of 31% was numer...

Energy Technology Data Exchange (ETDEWEB)

Efforts concentrated on updating of the Rockwell reference concept, definition of new system options, studies of special emphasis topics, further definition of the transportation system, and further program definition. The Rockwell reference satellite concept has a gallium arsenide (GaAs) solar cell array having flat concentrators with an effective concentration ratio of 1.83at end of life. Alternatives to this concept includes solid state power amplifiers or magnetrons for dc/RF conversion and multibandgap solar cells for solar to dc energy conversion. Two solid state concepts were studied. It was determined that the magnetron approach was the lowest mass and cost system.

Science.gov (United States)

Hydrogenation of high-volatile bituminous coal under high temperatures and pressures produced low-sulfur fuel oils. At a coal conversion of 80 percent, the ratio of oil to gas yields was approximately 3 : 1 and 23 percent of the coal sulfur was contained in the oil. Sulfur content of the oil, however, remained the same at different coal-conversion levels. The data obtained in the semicontinuous dilute-phase hydrogenation system showed that the whole oil can be directly used as a fuel oil where 1 percent sulfur is tolerated. Fuel oils containing 0.5 percent and 0.25 percent sulfur were produced by desulfurization of the whole oil.

International Nuclear Information System (INIS)

Point contact Josephson junctions can function as millimeter wave heterodyne mixers with conversion gain. The best results achieved thus far show a single sideband conversion gain of 1.3 and a mixer contribution to the system noise temperature of 54"0K. Both of these results are approximately 5 times better than the best published figures for cooled Schottky barrier diode mixers operated at the same frequency. The measured noise for a variety of junctions can be expressed as a universal function of the normalized rf frequency #OMEGA# = h#omega#/2eI/sub c/R. It is about a factor 2 larger than the calculated noise arising from the thermal noise in the junction shunt resistance, R. The noise calculation was done for the resistively shunted junction model using an analog junction simulator.

Energy Technology Data Exchange (ETDEWEB)

Energy International is developing a technology that will create a staged formulation with the first coal form (Mulled Coal) that can be stored, transported, and pumped. Just prior to combustion, the Mulled Coal (MC) would be modified to provide the properties needed for proper atomization. This concept is an alternative to the expensive and energy intensive thermal drying processing of fine coal wet cakes. The material is suitable for both direct feed use in conventional and fluid bed combustors as well as on-site conversion to combustible slurries. By maintaining the coal form relatively close to the feed wet cake, only minor processing with low additive levels and low energy blending needed at the point of production. Its conversion to slurry or other use-feed form is made near the time of use and thus the requirements for stability, climatic control, and other storage, transport, and handling requirements are much less severe.

International Nuclear Information System (INIS)

Intermediate products of the conversions of 6-aminophenalenone in ethanol were investigated by pulse radiolysis. In alkaline medium the main product is the 6-aminophenalenone radical cation, the optical absorption spectrum of which contains two bands with maxima at 355 and 400 nm. The precursors of this particle are e_s, CH_3CHOH and CH_3CHO"- radicals. In neutral and acid medium, radical cations are protonated in reactions with alcohol and hydrogen ions. The H-adduct of 6-aminophenalenone that arises has optical absorption maxima at 350 and 390 nm. The presence of two maxima is due to two different structures of the product. The molar extinction coefficients of the radical anions and H-adducts of 6-aminophenalenone and the rate constants of the reactions involving them were estimated. 6 refs., 4 figs., 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

Hydrogenation of napthalene to tetralin using activated red mud as catalyst was studied as a typical hydrogen-donor system. Under the chosen reaction conditions, unprocessed red mud resulted in a conversion of napthalene of 3.55%. The most active catalyst, prepared by adding 20 wt% of TiO/SUB/2 to the red mud, followed by acid digestion and re-precipitation, resulted in a 58% conversion of naphthalene. This technology may have an important bearing on processes such as coal hydrogenation or crude-oil-residue processing, where the rate of reaction and product quality may depend upon the rate at which a hydrogen-donor solvent can be re-hydrogenated. (7 refs.)

British Library Electronic Table of Contents (United Kingdom)

A highly efficient integrated energy conversion system is built based on a methane catalytic decomposition reactor (MCDR) together with a direct carbon fuel cell (DCFC) and an internal reforming solid oxide fuel cell (IRSOFC). In the MCDR, methane is decomposed to pure carbon and hydrogen. Carbon is used as the fuel of DCFC to generate power and produce pure carbon dioxide. The hydrogen and unconverted methane are used as the fuel in the IRSOFC. A gas turbine cycle is also used to produce more power output from the thermal energy generated in the IRSOFC. The output performance and efficiency of both the DCFC and IRSOFC are investigated and compared by development of exact models of them. It is found that this system has a unique loading flexibility due to the good high-loading property of ...

British Library Electronic Table of Contents (United Kingdom)

Conversion of tropical forests to oil palm plantations in Malaysia and Indonesia has resulted in large-scale environmental degradation, loss of biodiversity and significant carbon emissions. For both countries to participate in the United Nation's REDD (Reduced Emission from Deforestation and Degradation) mechanism, assessment of forest carbon stocks, including the estimated loss in carbon from conversion to plantation, is needed. In this study, we use a combination of field and remote sensing data to quantify both the magnitude and the geographical distribution of carbon stock in forests and timber plantations, in Sabah, Malaysia, which has been the site of significant expansion of oil palm cultivation over the last two decades. Forest structure data from 129ha of research and inventory p...

Science.gov (United States)

During 1978 the Engineering Board of SRC granted Specially Promoted Program status to the Coal Technology program. This recognized that coal would increase in importance as the cost of liquid and gaseous hydrocarbons rises with the decreasing availability of petroleum related sources. It was, therefore, considered necessary to anticipate and improve, through SRC supported research, the technologies required to win, transport, convert to liquid and gaseous fuels and utilize coal and coal based substances. In view of the interest in the program, and also in the hope of reaching a still wider audience the reports of the two meetings have been combined in this single booklet. The reports indicate specific problems of importance in coal winning and coal conversion but, naturally, do not cover all of the program priorities.

Energy Technology Data Exchange (ETDEWEB)

Industrial solid wastes (fly ash and red mud, a by-product of the aluminium industry) have been employed as supports for preparation of Ru-based catalysts. Physical and chemical treatments on red mud were conducted and these modified supports were also used for preparation of Ru-based catalysts. Those Ru catalysts were characterized by various techniques such as N2 adsorption, H{sub 2} adsorption, XRD, XPS, and temperature-programmed reduction (TPR), and were then tested for catalytic ammonia decomposition to hydrogen. It was found that red-mud-supported Ru catalyst exhibits higher ammonia conversion and hydrogen production than fly-ash-supported catalyst. Heat and chemical treatments of the red mud greatly improve the catalytic activity. Moreover, a combination of acid and heat treatments produces the highest catalytic conversion of ammonia. 35 refs., 4 figs., 4 tabs.

Energy Technology Data Exchange (ETDEWEB)

A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

UK PubMed Central (United Kingdom)

This study determined the phylogenetic groups and virulence factors of 37 Escherichia coli isolates producing types of CTX-M compared with those of 19 isolates producing different types...Full Text Available

UK PubMed Central (United Kingdom)

Wild-type viruses from the ViroLogic phenotype-genotype database were evaluated to determine the upper confidence limit of the drug susceptibility distributions, or “biological cutoffs,”...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundPerfluorocarbons (PFC) are used to improve gas exchange in diseased lungs. PFC have been shown to affect various cell types. Thus, effects on alveolar type II (ATII) cells...Full Text Available

UK PubMed Central (United Kingdom)

Background:Erectile dysfunction in type-2 diabetes may be an independent marker for coronary artery disease. Present study was undertaken to investigate whether type-2 diabetic...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

We consider the dynamics toward the initial singularity of Bianchi type IX vacuum and orthogonal perfect fluid models with a linear equation of state. The 'Bianchi type IX attractor theorem' states that the past asymptotic behavior of generic type IX solutions is governed by Bianchi type I and II vacuum states (Mixmaster attractor). We give a comparatively short and self-contained new proof of this theorem. The proof we give is interesting in itself, but more importantly it illustrates and emphasizes that type IX is special, and to some extent misleading when one considers the broader context of generic models without symmetries.

CERN Document Server

We consider the dynamics towards the initial singularity of Bianchi type IX vacuum and orthogonal perfect fluid models with a linear equation of state. The `Bianchi type IX attractor theorem' states that the past asymptotic behavior of generic type IX solutions is governed by Bianchi type I and II vacuum states (Mixmaster attractor). We give a comparatively short and self-contained new proof of this theorem. The proof we give is interesting in itself, but more importantly it illustrates and emphasizes that type IX is special, and to some extent misleading when one considers the broader context of generic models without symmetries.

Science.gov (United States)

The results of this research centered on the experimental studies of a single superconducting persistent current qubit, the implementation of type-II algorithms using these qubits, and the proposal for adiabatic quantum computing using these qubits. The m...

Science.gov (United States)

... and high-quality photospheric-phase Type II SN spectra to constrain core- collapse SN explosions, massive star evolution, and distances in the Universe ...

Science.gov (United States)

... dartevellei is only known from the type locality (Matadi, Lower Congo River basin) and it has only ... the type locality is in the region of Matadi, and not only of Matadi itself. If there ... ...

Energy Technology Data Exchange (ETDEWEB)

One requirement of a thermophotovoltaic (TPV) radiator is to efficiently emit photons at high temperatures to TPV cells for conversion to electric power. Because many candidate radiator materials with adequate structural properties display low emissivity, coatings or other surface modifications are required for enhancement of emissivity. Six plasma sprayed coatings and one textured surface demonstrated adequate thermal stability and emittance values of 0.8 or greater. Promising attributes of modified surfaces are identified.

Science.gov (United States)

A series of questions and answers addresses issues related to developing synthetic fuels, including the potential supplies, regulatory road blocks, and development incentives to promote the role of the private sector. Chevron's efforts in the area of synfuels are aimed at shale oil tar sands and coal conversion. The status of these research and development projects and the projected recoverable reserves from each are summarized. (DCK)

Wastenet

... This is an amount less that the measurement accuracy of even the best meteorological instruments . So, is it really worth committing to 40 years of drastic carbon emissions reductions (which necessarily involves increasing the cost of hydrocarbon fuels in order to reduce fuel consumption, and force an industry-wide conversion to much more expensive alternative energy sources), all so that after nearly all of us are ...

Energy Technology Data Exchange (ETDEWEB)

Research is presented on oil and gas technologies, advanced systems, soil remediation and remediation of acid mine drainage, applied science research in plastics and petroleum coprocessing, and fossil fuel and hydrocarbon conversion using a hydrogen rich plasmas.

Energy Technology Data Exchange (ETDEWEB)

Single and binary metal molybdates, supported on silica (80 wt% active phase/20 wt% SiO{sub 2}), having the formula AMoO{sub 4}, where A = Ni, Co, Mg, Mn, and/or Zn, and some ternary molybdates having the formula Ni{sub 0.45}Co{sub 0.45}X{sub 0.066}MoO{sub 4}, where X = P, Bi, Fe, Cr, V, and Ce, were investigated for the oxydehydrogenation of propane to propylene. The reaction is catalytic and is first order in propane disappearance, consistent with the abstraction of a methylene hydrogen being the rate limiting step. Propane conversion and yields of propylene produced vary greatly with the choice of the A metal of the molybdate and the surface area of the catalyst. At 560{degrees}C and atmospheric pressure, the highest propane conversion and highest propylene yields are obtained with NiMoO{sub 4}/SiO{sub 2} (16% at 27% conversion), closely followed by Ni{sub 0.5}Co{sub 0.5}MoO{sub 4}/SiO{sub 2}. The molybdenum content of ...

Energy Technology Data Exchange (ETDEWEB)

The NREL Sensitized Solar Cell (SSC) Core Program supports the Solar America Initiative by: (1) targeting new devices and processes for commercialization by 2015 that are less expensive, more efficient, highly reliable, and environmentally benign; (2) collaborating with DOE OS/BES to conduct basic research targeting breakthroughs in key areas, such as ultra-high efficiency and/or ultra-low cost materials and devices.

International Nuclear Information System (INIS)

A physical model of free-electron laser (FEL) amplifier with variable-parameter wiggler magnets for one-dimensional numerical simulation is presented and a numerical example is given. The wiggler parameters, efficiency of energy conversion between electron beam and laser field, laser intensity, phase-space distributions and energy spectrum of electrons are computed. The period of synchronous oscillation and saturation value of laser intensity agree with estimated one.

Energy Technology Data Exchange (ETDEWEB)

The catalytic dehydration of methanol to dimethyl ether was investigated for application on-board a methanol fuelled vehicle. Several catalysts have been tested in a fixed bed reactor. Our approach is to develop a small and efficient reactor converting liquid MeOH under pressure and at low reaction temperatures. (author) 2 figs., 5 refs.

CERN Document Server

We report an observation of a delayed all-optical routing/switching phenomenon based on ultraslow group velocity of light via nondegenerate four-wave mixing processes in a defected solid medium. Unlike previous demonstrations of enhanced four-wave mixing processes using the slow light effects, the present observation demonstrates a direct retrieval of the resonant Raman-pulse excited spin coherence into photon coherence through coherence conversion processes.

Energy Technology Data Exchange (ETDEWEB)

Elastic depth imaging of both P-wave and S-wave prestack seismic reflection data is formulated as a degraded form of Kirchhoff migration known as Wavepath Migration (WM). Applications to the SEG/EAGE salt model show that the method is sufficiently versatile anti relaitively inexpensive. It handles S-wave data with at least the same accuracy as Pwave data when local mode conversions are removed. WM also provides an understanding of multi-mode illumination.

Energy Technology Data Exchange (ETDEWEB)

The Monthly Energy Review (MER) presents an overview of the Energy Information Administration`s recent monthly energy statistics. The statistics cover the major activities of US production, consumption, trade, stocks, and prices for petroleum, natural gas, coal, electricity, and nuclear energy. Also included are international energy and thermal and metric conversion factors. 37 figs., 61 tabs.

Energy Technology Data Exchange (ETDEWEB)

The special features of prostaglandin biochemistry, of importance for investigation of the possible physiological roles of prostaglandins, are briefly reviewed. The formation of prostaglandins and related compounds from endogenous and exogenous arachidonic acid in homogenates of human gastric mucosal and muscle-serosal layers is described. These preliminary data seem to indicate that a low conversion of exogenous precursor does not necessarily mean that the capacity of the tissue to synthesize prostaglandins from endogenous precursor is low.

International Nuclear Information System (INIS)

Thermally recyclable Nb point-contact Josephson junctions are investigated as low-noise mixers with an external local oscillator at 115 GHz. The best single sideband mixer noise temperature achieved is 140 ( +- 20) K with a (SSB) conversion loss of 2.4 ( +- 0.5) dB. Such rugged junctions are suitable for use in practical receivers and should give unprecedented sensitivity at the shorter millimeter wavelengths.

International Nuclear Information System (INIS)

Heterodyne detection with a point-contact Josephson junction has been investigated both experimentally and theoretically. The measured performance of the device at 36 GHz is in good agreement with the theory. By operating vanadium point contacts at 1.4 K, the authors have achieved a single-sideband (SSB) mixer noise temperature of 54 K with a conversion gain of 1.35 and a signal bandwidth on the order of 1 GHz. A potentially impressive performance for these devices at submillimeter wavelengths can be extrapolated from the results.

Energy Technology Data Exchange (ETDEWEB)

The proceedings contain 21 papers arranged under the following topical sections: Exploration technology (4 papers); Reservoir technology (5 papers); Energy conversion technology (8 papers); Drilling technology (2 papers); and Direct use and geothermal heat pump technology (2 papers). An additional section contains a report on a workshop on dual-use technologies for hydrothermal and advanced geothermal reservoirs.

Science.gov (United States)

Glucoamylase and pullulanase were immobilized on reconstituted bovine-hide collagen membranes using the covalent azide linkage method. A pretanning step was incorporated into the immobilization procedure to enable the support matrix to resist proteolytic activity while accommodating an operating temperature of 50 degrees C. The immobilized glucoamylase and pullulanase activities were 0.91 and 0.022 mg dextrose equivalent (DE) min(-1) cm(-2) of membrane, respectively. Immobilized glucoamylase had a half-life of 50 days while the immobilized pullulanase had a half-life of 7 days. This is a considerably improved stability over that reported by other researchers. The enzymes were studied in their free and immobilized forms on a variety of starch substrates including waxy maize, a material which contains 80% alpha-1-6-glucosidic linkages. Substrate concentrations ranged from 1% to a typical commercial concentration of 30%. Conversion efficiencies of 90-92% DE were ...

Energy Technology Data Exchange (ETDEWEB)

A) diffuse bilayer, B) spontaneously formed multilayer, and C) vertically homogenous thin films, are fabricated. The photocurrent/voltage performance is compared and it is found that the self-stratified structure (B) yields the highest energy conversion efficiency. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

International Nuclear Information System (INIS)

New measurements of relative gamma-ray emission probabilities in the decay of "1"0"1Mo and "1"0"1Tc are reported. Previously published conversion-electron data have been used along with the gamma-ray data to formulate self-consistent decay schemes. (orig.).

Energy Technology Data Exchange (ETDEWEB)

The crabbing of an incident photon beam from a laser, and the electron beam with which it interacts at the conversion point, is shown to have the same efficiency as in head-on Compton scattering, but with the advantages of a crossing geometry. The resulting {gamma}-ray beam is also crabbed, which allows for a crossing collision point, while maintaining the luminosity at the same value it would have in a head-on collision. ((orig.)).

Energy Technology Data Exchange (ETDEWEB)

Simulated atmospheric corrosion studies were performed to determine the corrosion protection provided by galvanized zinc coatings on depleted uranium, U-0.75 Ti alloy, and U-6 Nb alloys. The accelerated ASTM tests consisted of exposing the galvanized samples to aqueous and aqueous chloride environments. The test results showed that anodic protection was provided by the electronegative zinc coatings on uranium and uranium alloys. Treating zinc with chromate conversion coatings also provided more protection.

British Library Electronic Table of Contents (United Kingdom)

Communicating and collaborating online are becoming common requirements in education. The specialized notations and symbols necessary for some content areas where mathematical expressions are part of the conversation require that users select appropriate communication tools. The purpose of this article is to describe tools that can be used for online, asynchronous or synchronous communication involving mathematical expressions.

Science.gov (United States)

A process is provided for conducting organic compound conversion over a catalyst composition comprising a supported crystalline zeolite having a high initial silica-to-alumina mole ratio, said supported zeolite being prepared by compositing said crystalline zeolite with alumina, reacting the composite with a particular hydrogen fluoride solution in a specified way, drying the hydrogen fluoride reacted composite, treating the dried composite by hydrolysis, ammonolysis and/or by contact with an ammonium salt solution, and calcining the resulting material.

Energy Technology Data Exchange (ETDEWEB)

The thermal accommodation coefficients of helium, neon, argon, hydrogen and deuterium have been measured in the temperature range of 77-340 K on the surface of a graphitized carbon filament. The dependence of the accommodation coefficient upon the molecular weight as well as the temperature of measurement, and the conversion from orthohydrogen to parahydrogen, have been discussed.

Medline Plus

... they're not from other things such as endometriosis and other types of polyps and tumors that ...

International Nuclear Information System (INIS)

Short communication.

KoreaScience (Korea)

Full Text Available

Science.gov (United States)

... the type locality on the Zaire River at Matadi, where it was first recorded in the 1940s ... ...

Science.gov (United States)

... Congo, Guinea Equatorial, and Angola. The record from Matadi from the Lower Congo and the type locality ... ...

International Nuclear Information System (INIS)

... bwr type reactors closures fluidic control devices operation performance pwr

International Nuclear Information System (INIS)

... Abstract only 1063-7869 v. 44(10) CLASSICAL AND QUANTUM MECHANICS,

KoreaScience (Korea)

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J-STORE (Japan)

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KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

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International Nuclear Information System (INIS)

To assess the clinical and pathologic features of each type of intrahepatic cholangiocarcinoma, which is divided into three types according to gross appearance, and to determine the efficacy of CT in detecting this tumor. The pathologic and CT features of 53 surgically proven cases of intrahepatic cholangio-carcinoma were reviewed. On the basis of their gross appearance, the tumors were divided into three types, as follows : mass forming (n=33), periductal infiltrating (n=6), and intraductal growth type (n=14). CT scans were analyzed for sensitivity of detection and correlation between a tumors appearance and its histopathology. The most common histopathologic feature of mass forming and periductal infiltrating type was tubular adenocarcinoma, while in the intraductal growth type, papillary adenocarcinoma (100%) was common. With regard to pattern of tumor ...

International Nuclear Information System (INIS)

For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements to their molten salt-insoluble precipitates were ...

Energy Technology Data Exchange (ETDEWEB)

Deregulation of utilities will require providers of electric power to put the issue of competition at the top of their strategic planning agenda. The companies that will flourish in this new competitive environment are those that have strongly committed customers and potential to grow. {open_quotes}Commitment{close_quotes} is the complex psychological bond between a customer and a brand (or choice); it is critical to measure because it is the foundation of loyalty and brand equity. The Conversion Model is an established, validated strategic research tool that measures customer commitment and potential to change. It was designed to help marketers devise strategies to strengthen the commitment of current customers and to acquire new customers. The Model helps companies protect and grow their businesss by first quantifying the commitment of current customers and the potential to convert competitors` customers. Further, the Model provides managers with actionable ...

Science.gov (United States)

Mg-Al mixed oxides with Mg/Al molar ratios of 0.5--9.0 were obtained by thermal decomposition of precipitated hydrotalcite precursors. The effect of composition on structure and surface and catalytic properties was studied by combining several characterization methods with ethanol conversion reactions. The nature, density, and strength of surface basic sites depended on the Al content. The catalyst activity and selectivity of Mg-Al mixed oxides in ethanol conversion reactions depended on composition. The dehydrogenation of ethanol to acetaldehyde and the aldol condensation to n-butanol both involved the initial surface ethoxide formation on a Lewis acid-strong base pair. The dehydration of ethanol to ethylene, and the coupling and dehydration to diethyl ether increased with Al content, probably reflecting the density increase of both Al{sup 3+}-O{sup 2{minus}} pairs and low- and medium-strength basic sites. Pure Al{sub 2}O{sub 3} displayed the ...

Energy Technology Data Exchange (ETDEWEB)

Plutonium metal is produced by reducing PuF{sub 4} prepared from PuO{sub 2} by fluorination. Both fluorination and reduction are batch processes at the Los Alamos Plutonium Facility. The conversion of plutonium oxide to fluoride greatly increases the neutron yield, a result of the high cross section for alpha-neutron ({alpha},n) reactions on fluorine targets compared to the (more than 100 times) smaller {alpha},n yield on oxygen targets. Because of the increase, total neutron counting can be used to monitor the conversion process. This monitoring ability can lead to an improved metal product, reduced scrap for recycle, waste reduction, minimized reagent usage, and reduce personnel radiation exposures. A new stirred-bed fluorination process has been developed simultaneously with a recent evaluation of an automated neutron-counting instrument for quantitative process monitoring. Neutrons are counted with polyethylene-moderated {sup 3}He-gas ...

Energy Technology Data Exchange (ETDEWEB)

An almost primordial trend in the conversion and use of energy is an increased complexity and cost of conversion systems designed to utilize cheaper and more-abundant fuels; this trend is exemplified by the progression fossil fission {yields} fusion. The present projections of the latter indicate that capital costs of the fusion ``burner`` far exceed any commensurate savings associated with the cheapest and most-abundant of fuels. These projections suggest competitive fusion power only if internal costs associate with the use of fossil or fission fuels emerge to make them either uneconomic, unacceptable, or both with respect to expensive fusion systems. This ``implementation-by-default`` plan for fusion is re-examined by identifying in general terms fusion power-plant embodiments that might compete favorably under conditions where internal costs (both economic and environmental) of fossil and/or fission are not as great as is needed to justify ...