Trace element geochemistry of the Whitewood Mine coals in Alberta
Subbituminous coals, taken from a freshly mined open pit as well as from nine drillholes in the Whitewood Mine, Alberta, were analyzed for their elemental and radionuclide concentration. Furthermore, the coal ash was analyzed for major oxides, and a comparison was made with coals of similar rank and present only 12 km away, in the Highvale Mine. The Whitewood Mine coals are clean by world standards and do not contain any environmentally deleterious elements in excess amounts. They are suitable for utilization, but care should be taken to minimize the negative opacity effects on the electrostatic precipitators (ESPs). The low Na{sub 2}O content in the coals, particularly in the open-pit samples, may affect ash resistivity. This could result in a decrease in the flow of current and thus a decrease in the precipitator efficiency. Certain trends of major oxides in the coal ash are observed in a north-south direction and are discussed, with particular emphasis on the Na{sub 2}O distribution in the six coal seams. The Whitewood Mine drillhole samples contain the following mean concentration of elements in ppm, unless stated otherwise: As (4.7), Br (15.1), Cl (21.5), Co (3.3), Cr (7), Mo (4.8), Na (710), Ca (1.5%), Mn (110), Th (6), U (2.5), V (19.3), and Sb (0.7). In the surface samples, the mean concentrations of the above elements are as follows in ppm: As (4.5), Br (196.2), Cl (38.4), Co (5.4), Cr (200), Mo (16.7), Na (263), Ca (1.4%), Mn (120), Th (5.2), U (1.6), V (14.3), and Sb (0.7). The open-pit surface samples are much enriched in Br, Mo, and Cr, slightly enriched in Cl and Co, much depleted in Na, and slightly depleted in Th, U, and V compared to the drillhole samples. Both sets have similar concentrations of As and Mn. There is a slight increase in As concentration in the north and south ends of the pit; a slight increase in a northern direction was also noted for Si, U, and Na. All rare earth elements are within the world range for most coals.