International Nuclear Information System (INIS)

... energy levels intermediate mass nuclei isotopes nuclei odd-even nuclei

Science.gov (United States)

The gamma spectra and lifetimes of the Ta and W isotopes havimg mass numbers 173, 175, 177, and 179 are determined. (T.F.H.)

International Nuclear Information System (INIS)

Cross sections for (n,2n) (n,p) (n,#alpha#), and (n,d*)"1 reactions have been measured on ruthenium isotopes at the neutron energies of 13.5 to 14.8 MeV using the activation technique in combination with high-resolution gamma-ray spectroscopy. Data are reported for the following reactions: "1"0"4Ru(n,2n)"1"0"3Ru, "9"8Ru(n,2n)"9"7Ru, "9"6Ru(n,2n)"9"5Ru, "9"6Ru(n,p)"9"6Tc"g, "9"6Ru(n,p)"9"6Tc"m, "1"0"4Ru(n,p)"1"0"4Tc, "1"0"2Ru(n,p)"1"0"2Tc"m, "1"0"4Ru(n,#alpha#)"1"0"1Mo, "1"0"2Ru(n,#alpha#)"9"9Mo, "9"6Ru(n,#alpha#)"9"3Mo"m, and "9"6Ru(n,d*)"9"5Tc"m. Results were discussed and compared with the previous works.

International Nuclear Information System (INIS)

... coriolis force de-excitation excited states half-life iridium 187 multipolarity

Energy Technology Data Exchange (ETDEWEB)

The ..beta.. decay half-lives of neutron-rich isotopes with Z=24-28 are calculated in the QRPA with a Gamow-Teller residual interaction. For odd-mass and odd-odd systems QRPA phonon correlations are introduced to quasiparticle transitions in first-order perturbation. The calculated half-lives agree very well with the experimental values. For later application of this model to nuclei far from stability, we have examined the dependence of the calculated half-lives on the model parameters.

International Nuclear Information System (INIS)

A review of the experimental work performed at the GASP array with the purpose of the identification and first spectroscopic measurements of the heaviest even-even N = Z and odd-A N = Z + 1 nuclei (mass larger than 80) is made. Systematic experiments in this mass region led to the first study of seven such nuclei: "8"8Ru, "8"1Zr, "8"5Mo, "8"9Ru, "9"1Rh, "9"3Pd, and "9"5Ag, and extensive data on many other nuclei in their neighborhood. The systematic evolution of the level structures in both even-even and odd-A nuclei, between N #approx# Z #approx# 40 and N #approx# Z #approx# 47 is briefly presented. The possibility that effects of the neutron-proton pairing have been observed, as well as the type of collectivity observed in this region are discussed. (author)

Energy Technology Data Exchange (ETDEWEB)

The thesis explains the development of a mass spectrometerical isotope dilution analysis (MS/DA) for determining trace amounts of Tc. The Tc-97 isotope has been prepared by in-core irradiation of Ru of natural isotopic composition, and used as the indicator isotope. For separation of Tc-97 from the Ru matrix, a method has been developed to quantitatively separate Tc-97 from a high Ru surplus. For determining the isotope ratio for the MS/DA, a mass spectrometrical measuring technique has been found which allows reproducible measurement of the Tc-99/Tc-97 isotope ratio. Positive and, for the first time, also negative thermoionisation has been used as a method of selective ionisation of Tc. The applicability of the MS/DA for Tc trace analysis has been verified using two Al foils doped with Tc-99 or ...

International Nuclear Information System (INIS)

... lutetium isotopes nuclei odd-even nuclei radioisotopes rhenium isotopes

International Nuclear Information System (INIS)

A "9"2Mo beam with an energy of E/A=70 MeV has been used to produce new isotopes near the proton drip line. The Michigan State University National Superconducting Cyclotron Laboratory A1200 fragment separator was used to detect the new isotopes "7"8Y, "8"2Nb, "8"5Mo, "8"6Tc, and "8"9","9"0Ru.

CERN Multimedia

What are the odds of time travel?

Energy Technology Data Exchange (ETDEWEB)

Using Gammasphere data on prompt gamma rays from spontaneous fission of 252Cf, we propose energy-level schemes for 110,111,112, & 113Rh (Z=45). The fission-gamma data complement earlier studies of others on beta decay of fission products in that prompt fission gammas mainly populate yrast or near-yrast levels, while beta decay populates lower-spin levels. For the odd-A rhodium nuclei studied here, their ground bands and collective sidebands are compared with model calculations using triaxial-shaped nucleus with one odd quasi-proton. The energies and E2 transition rates are best fit by a shape slightly to the prolate side of maximum triaxiality, namely, gamma = 28 deg. The model calculations also show a K=1/2+ band with energies not in good agreement with a corresponding experimental band. The experimental 1/2+ band is regarded as an intruder band from a prolate-driving proton orbital 1/2[431] above the Z=50 closed shell. This intruder band, ...

International Nuclear Information System (INIS)

A detailed analysis of the positive parity levels in odd iridium isotopes is carried out with an extended version of the Hecht and Satchler model. A satisfactory description of "1"8"7"-"1"9"3Ir positive parity states and their electromagnetic properties is obtained by coupling several Nilsson particle configurations to an asymmetric rotor. (orig.).

Science.gov (United States)

The systematic behavior of excited nuclear levels was studied with Lu (Z = 71), Ta (Z = 73), and Re (Z = 75) activities produced in the ORNL proton cyclotron. Conversion-electron data are presented for electron-capture decay of Lu/sup 170.174m/, Ta/sup 173-178/, and Re/sup 179.181/. Level schemes are proposed based on these and on previously published up 173.175-179/, tulated. The proper ties of odd-A nuclei in the strongly deformed region of odd-N numbers 95-107 are discussed in connection with predictions of Mottelson and Nilsson. Two activities, Lu/sup 174m/ and Re/sup 179/ ( es sufficiert t 20 min), are previously unreported. (auth)

International Nuclear Information System (INIS)

An experimental study was performed in order to study the nuclear structure in odd--odd In isotopes. Low lying nuclear energy levels in "1"1"0In and "1"1"2In were determined from de-excitation #gamma#-rays produced with "1"0"7AG(#alpha#,n#gamma#)"1"1"0In, "1"0"8Pd("6Li,4n#gamma#)"1"1"0In, "1"0"9Ag(#alpha#,n#gamma#)"1"1"2In and "1"1"0Pd("6Li,4n#gamma#)"1"1"2In reactions. In addition, the "1"1"4In energy level structure was investigated with the "1"1"0Pd("7Li,3n#gamma#)"1"1"4In reaction. Properties of de-excitation #gamma#-rays were determined from #gamma#--#gamma# coincidence excitation and angular distribution measurements conducted with Ge(Li) and Ge(intr.) #gamma#-ray detectors. A sequence of intraconnected levels in each of "1"1"0 "1"1"2 "1"1"4In were assigned to the (#pi#"-"1/sub 9/2/, #nu#h/sub 11/2) configuration. For the "1"1"0 "1"1"2"1"1"4In energy level schemes a model calculation was performed using the pairing-plus-quadrupole model, ...

Energy Technology Data Exchange (ETDEWEB)

This work is based on the study of cesium ({sup 118,146}Cs) and francium ({sup 207-213}Fr,{sup 220-228}Fr) isotopes by hyperfine atomic spectroscopy and on the interpretation of these results from the nuclear physics point of view. The measured nuclear quantities are: the spin, the magnetic moment, the electric quadrupole moment and the mean square charge radius. The experimental method which is based on hyperfine optical pumping with a tunable laser, followed by magnetic analysis of the atoms is described in the first part. Results related to atomic physics are also presented. In the second part, these data are interpreted in the framework of nuclear models. The deformation of light cesium isomers are compared to values obtained from a theoretical self-consistent calculation. Heavy francium isotopes are situated in an area where the existence of static octupole deformations have been predicted. The odd-even staggering ...

Energy Technology Data Exchange (ETDEWEB)

High-spin states in the neutron-rich nuclei {sup 172,173}Yb have been populated in a {sup 170}Er({sup 7}Li,(p,d,t)xn) incomplete-fusion reaction and the emitted {gamma}-radiation was detected with the GASP array. The signature partners of the 7/2{sup +}[633] rotational band of the odd-N {sup 173}Yb isotope have been newly established and were observed up to spin values of (45/2{sup +}) and (43/2{sup +}), respectively. The ground-state band of the even-even nucleus {sup 172}Yb has been observed up to a spin value of (22{sup +}). No band crossings were found in these bands. To explain this observation, it is proposed that the static pair field is absent, considering that the neutron odd-even mass differences reach for these nuclei very small values and that the band crossing is absent in cranked shell modell calculations without pairing. The results indicate, however, that strong dynamic correlations are still present. ...

International Nuclear Information System (INIS)

... deformed nuclei eigenvalues even-odd nuclei gold 195 hamiltonians iridium

CERN Document Server

The recently measured experimental data of Argonne National Laboratory for high-spin states in neutron-rich $^{71,73,75,77}$Ga isotopes have been interpreted in the framework of large-scale shell model. Calculations have been performed in $f_{5/2}pg_{9/2}$ model space with two recent effective shell model interactions, JUN45 and jj44b. We also predict high-spin states for $^{79,81}$Ga, where very little is known experimentally. The calculated results show that existence of band structure built on top of the 3/2$^-$, 5/2$^-$ and 9/2$^+$ levels in $^{71-77}$Ga. The collective structure reflected in experimental data is not well reproduced in calculated values. The calculated positive parity states in $^{71,73,75}$Ga are higher in energy in comparison to experimental finding, while for $^{77,79}$Ga, the positive parity states are in better agreement. Both the interactions predict, leading configuration of $\\pi(f_{5/2}^3)$ and $\\pi(p_{3/2}f_{5/2}^2)$ for ...

Energy Technology Data Exchange (ETDEWEB)

Several reactions producing odd-Z transactinide compound nuclei were studiedwith the 88-Inch Cyclotron and the Berkeley Gas-Filled Separator at the LawrenceBerkeley National Laboratory. The goal was to produce the same compound nucleus ator near the same excitation energy with similar values of angular momentum via differentnuclear reactions. In doing so, it can be determined if there is a preference in entrancechannel, because under these experimental conditions the survival portion of Swiatecki, Siwek-Wilcznska, and Wilczynski's"Fusion By Diffusion" model is nearly identical forthe two reactions. Additionally, because the same compound nucleus is produced, theexit channel is the same. Four compound nuclei were examined in this study: 258Db, 262Bh, 266Mt, and 272Rg. These nuclei were produced by using very similar heavy-ion induced-fusion reactions which differ only by one proton in the projectile or target nucleus (e.g.: 50Ti + 209Bi vs. ...

International Nuclear Information System (INIS)

... Ukraine) INIS-UA--107 211 p. PHYSICS OF ELEMENTARY PARTICLES AND

International Nuclear Information System (INIS)

An attempt is taken to explain anomalies in "9"2Mo(d, n)"9"3Tc, "9"2Mo(d, #alpha#)"9"0Nb, "9"4Mo(d, n)"9"5Tc, "9"8Mo(d, n)"9"9Tc, "9"8Mo(d, p)"9"9Mo, "9"8Mo(d, #alpha#)"9"6Nb, "1"0"0Mo(d, p)"1"0"1Mo and "1"0"0Mo(d, n)"1"0"1Tc reactions with input states having a one-particle nature. Thin films saturated with molybdenum isotopes at the approximately 1 mgxcm"-"2 surface density are used as targets. The targets are irradiated by the extracted cyclotron beam. The deuteron energy is 5-12 MeV. The reaction cross sections are determined by the activation analysis method. Quasi-stationary levels of the nucleus-deuteron system are calculated. Weak anomalies revealing in a smooth (d, #alpha#) reaction cross section on sup(92, 98)Mo nuclei, which do not necessarily correlate with anomalies in the (d, n) and (d, p) channels, are observed. The ground states of the (d, #alpha#) reaction products "9"0Nb and "9"6Nb have (8"+) and (6"+) spins, respec,.ively, that testifies to a ...

KoreaScience (Korea)

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International Nuclear Information System (INIS)

Nuclear shape changes can bring about rapid changes in nuclear properties. That such vibrational #-># symmetric rotor #-># asymmetric nucleus changes may be present in the A approximately 100 region is suggested by rapid, low-energy level density changes and unexpected #beta#-decay rate changes in several series of odd-odd and odd-mass fisions product nuclei. In order to define the nature of these nuclei we have performed measurements on a series of nuclei using JOSEF and Lohengrin mass separators, fast-chemistry, and n-capture #gamma#-ray techniques. Here we summarize the several features we find.

Energy Technology Data Exchange (ETDEWEB)

The peak evaluation in alpha liquid scintillation is known to be easy, mostly due to the gaussian shape of the peaks. However, we often observed a high-energy tail in addition to a pure gaussian function. This effect is only detectable with a high resolution {alpha} liquid scintillation spectrometer such as the PERALS trademark system. Indeed, its intrinsic resolution (180 keV for a 4 MeV {alpha} particle) is better than that obtained for conventional LSC spectrometers. The peak asymmetry was quantified using the Fisher's coefficient {gamma}{sub 1} (symmetry factor). We show that the main effect responsible for the asymmetry is internal conversion. Indeed, most of the even-even nuclides have low {alpha} intensity transitions leading to excited levels of their daughter nuclides. The internal conversion is almost equal to 100% and consequently produces a sum peak at higher energy. No generalization is possible for odd-even nuclides, but the knowledge of ...

International Nuclear Information System (INIS)

... coupling deformed nuclei gold 195 high spin states iridium 187 moment of

International Nuclear Information System (INIS)

Properties of unique parity states in odd-proton (_7_7Ir, _7_9Au) and odd-neutron nuclei (_7_8Pt) are investigated in the framework of the interacting boson-fermion approximation model. The core (boson)-particle (fermion) interaction is represented by a quadrupole-quadrupole interaction and an exchange term, which takes into account the effects of the Pauli exclusion principle. The even-even core nucleus is described in terms of the IBA-1 hamiltonian. The change in the properties of the corresponding odd-A nuclei can be interpreted in terms of a transition of the core hamiltonian between the O(6) and SU(3) limiting cases. (orig.).

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

UK PubMed Central (United Kingdom)

BackgroundGlucocorticoids down-regulate cytokine synthesis and suppress inflammatory responses. The glucocorticoid receptor (GR) antagonist RU486 may exacerbate the inflammatory...Full Text Available

Science.gov (United States)

Not Available

International Nuclear Information System (INIS)

In Ce(Ru_1_-_xPd_x)_2Si_2 the dilution of the transition metal leads to strong electronic effects resulting in the disappearance and the appearance of long-range magnetic order in CePd_2Si_2 and CeRu_2Si_2, respectively. ((orig.)).

UK PubMed Central (United Kingdom)

The nature of binding of Ru(phen) 2+ (I), Ru(bipy) 2+ (II), Ru(terpy) 2+ (III) (phen = 1,10-phenanthroline, bipy 3 = 2,2'-bipyridyl, 3 terpy = 2,2'2," - 2 terpyridyl) to DNA, poly[d(G-C)] and poly[d(A-T)]...Full Text Available

Scientific Electronic Library Online (English)

Abstract in english Ru(1%)/SiO2 and Cu(1%)Ru(1%)/SiO2 catalysts were prepared by cogelation. The effect of pH and the amount of water on the physical-chemical properties and the catalytic properties of them were analyzed. The acid medium increased the formation of microporosity and the formation of small size of metallic ruthenium particle. The variation of the water quantity used in the gelation not modify considerably the texture neither the dispersion of the noble metal. The reduction lev (more) el of all prepared catalyst was similar, showing displacement in some of reduction peaks. The toluene hydrogenation indicated that the conversion and the quantity of hydrogenate product varied with the pH and the quantity of water used in the gelation. The addition of copper to Ru/SiO2 catalysts diminished the reactive conversion and their hydrogenant activity

International Nuclear Information System (INIS)

The ruthenium decontamination factor in Purex process falls quickly with recycles of TBP. So it is necessary to change the chemical states of RuNO complexes in order to improve DF_R_u in the uranium purification cycle. The retention of RuNO complexes in TBP-kerosenelaurohydroxamic acid is observed to be quite large in our previous work. Therefore, water-soluble short chain hydroxamic acid is used as complexing agent to decrease the distribution coefficient of Ru. Hydroxamic acid can transform RuNO complexes into in-extractable species by TBP-kerosene in certain conditions. The result of cascade experiment indicates that the ruthenium decontamination can be increased by a factor of 40-50. Acidity has more influence on the effect of pretreatment. The higher acidity is, the worse the effect will be. The pretreatment is first carried out in low acidic solution, then extractive acidity is increased. In this ...

Energy Technology Data Exchange (ETDEWEB)

Within the framework of the EFTTRA cooperation between CEA, ECN, EDF, FZK, IAM and ITU, six metallic {sup 99}Tc rods have been irradiated in the Petten HFR for 193 effective full power days. During this irradiation, more than 6% of the {sup 99}Tc has been transmuted to the stable {sup 100}Ru. At ECN, one of the six rods has been examined in the hot cell laboratory. The ruthenium concentration in the rod measured by Isotope Dilution Mass Spectrometry reaches 6.4% at 5 mm from the bottom of the rod and 6.0% at 5 mm from the top. Also the axial and radial distributions of the ruthenium have been measured by Electron Probe Micro Analysis. The ruthenium concentrations calculated by the three-dimensional Monte Carlo code KENO reach 6.1% at 5 mm from the bottom of the rod and 5.7% at 5 mm from the top. These values are in reasonable agreement with the measured ones. However, the calculated radial distribution of the ruthenium concentration is not in ...

International Nuclear Information System (INIS)

High-spin states (I < or approx. 50(#Planck constant#/2#pi#)) of the odd-odd nucleus "1"7"0Ta have been investigated with the "1"2"4Sn("5"1V,5n) reaction. The resolving power of Gammasphere has allowed for the observation of eleven rotational bands (eight of which are new) and over 430 transitions (#approx#350 of which are new) in this nucleus. Many interband transitions have been observed such that the relative spins and excitation energies of the 11 bands have been established. This is an unusual circumstance in an odd-odd study. Configurations have been assigned to most of these bands based upon features such as alignment properties, band crossings, B(M1)/B(E2) ratios, and the additivity of Routhians. A systematic study of the frequency at which normal signature ordering occurs in the #pi#h_9_/_2#nu#i_1_3_/_2 band has been performed and it is found that its trend is opposite to that observed in the #pi#h_1_1_/_2#nu#i_1_3_/_2 bands. A ...

Energy Technology Data Exchange (ETDEWEB)

The level structure of the doubly-odd /sup 242/Am nucleus was investigated by means of thermal-neutron-capture gamma-ray and conversion electron spectroscopy. Pair, curved-crystal, and ..beta.. spectrometers were used. The data from these measurements, combined with previous direct reaction results, permit us to establish a detailed level scheme including six new well-developed bands. Our experimental results are interpreted in the framework of the Nilsson model. Precise Gallagher-Moszkowski splittings and Newby odd-even shifts extracted from the data are compared with theoretical calculations.

International Nuclear Information System (INIS)

The high-spin states in transitional odd-mass nuclei are studied in terms of an odd quasi-particle coupled to an asymmetric rotor with a variable moment of inertia (VMI). In order to take into account the VMI, the basis states are expanded in terms of the core eigenfunctions. Excitation energies, quadrupole moments, magnetic moments, B(E2) values and B(M1) values are calculated and compared with the experimental data for nuclei in Au and La regions. On comparison with other descriptions it is found that the treatment with VMI provides a more satisfactory explanation of the data. (Auth.).

International Nuclear Information System (INIS)

... gamma cascades kev range 10-100 lifetime lutetium 171 lutetium 173 lutetium

International Nuclear Information System (INIS)

Doubly decoupled structures in doubly odd deformed nuclei are reexamined and shown to be composed of a pseudo-spin aligned neutron and a decoupled proton. (orig.).

International Nuclear Information System (INIS)

... Moscow (Russian Federation) INIS-RU--495 385 p. INORGANIC, ORGANIC,

International Nuclear Information System (INIS)

... Thesis (Ph.D.). coincidence spectrometry excited states gamma spectra internal

British Library Electronic Table of Contents (United Kingdom)

A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2prime-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.

CERN Document Server

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

Abstract only.

International Nuclear Information System (INIS)

Evidence for triaxial nuclear shapes from families of unique-parity states in transitional odd-A nuclei around mass A=190 and A=130 is reviewed. The experimental data are analysed within the odd-A triaxial core model. Regular two-dimensional band patterns are found in experiment and are shown to be a consequence of broken axial symmetry. Recent theoretical developments are discussed including the question of how stable the triaxial shapes are.

International Nuclear Information System (INIS)

The P-odd asymmetries in deep inelastic scattering (DIS) of polarized leptons on nuclei are considered in the framework of the standard model and the parton-flucton model. The model predictions, within the experimental errors,agree well with the present data. 13 refs., 2 figs., 2 tabs. (author).

International Nuclear Information System (INIS)

The measurements of the nuclear decay of actinide isotopes and the evaluation of the radioactive properties of nuclide with the mass 242 is discussed in this paper.

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the electronic structure of ruthenium. Synchrotron radiation in the range from 15 to 45 eV and angle-resolved ultraviolet photoemission are used to map the energies of the electronic states. The Fermi surface of Ru is determined using angle-resolved ultraviolet photoemission spectroscopy. The experimental results are compared with calculated photoemission spectra obtained within the framework of the one-step model of photoemission. (author)

International Nuclear Information System (INIS)

This paper aims at the study of the transfer and accumulation of "1"0"6Ru from marine foods to man through the grazing food chain and evaluation of the radiation exposure to man. As a model, accumulation and excretion of "1"0"6Ru in mice orally administered by the meat of prawn (Penaeus japonicus) which accumulated the radionuclide from the sea water, were examined and compared with those in mice administered by non-radioactive prawn meat mixed with the contaminant in inorganic chemical forms (the control diet); on the latter experiment, the previous evaluation method of the radiation exposure was based. Higher concentrations of "1"0"6Ru in tissues and organs of mice were observed in the former diet than in the latter because of the higher absorption rate of "1"0"6Ru from the gastrointestinal tract (17.4 +- 4.4%, the control diet: 0.7 +- 0.7%) and smaller excretion. As the results of this experiment, ...

International Nuclear Information System (INIS)

The ruthenium decontamination factor in Purex process falls quickly in successive TBP cycles. So, it is necessary to change the chemical states of RuNO complexes in order to improve DF_R_u in the uranium purification cycle. Hydrazine nitrate is being used to transform RuNO complexes into in-extractable Ru(III)and Ru(IV). However, hydrazine nitrate may be inverted into hydrazoic acid which is dangerous and can bring an unstable factor. Pretreatment using U(IV) solution provides another method to improve the decontamination of ruthenium in Purex process. 0.02 mol/lU(IV) solution can transform RuNO complexes into inextricable species by heating in water bath. The D_R_u can be decreased by a factor of 10-20. U(IV) pretreatment does not bring any harmful chemical in process. The acidity has a very large influence on the effect of pretreatment. The higher the acidity is, the worse the ...

British Library Electronic Table of Contents (United Kingdom)

A novel method for the determination of metoclopramide (MCP) using electrogenerated chemiluminescence (ECL) is presented. A tris(2,2prime-bipyridyl)dichlororuthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticle/perfluoinated ion-exchange resin (Nafion) with nanocomposite membrane modified glassy carbon electrode (GCE) is used. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The analytical performance of this ECL sensor for MCP is shown in detail. Under optimal experimental conditions, it has good linearity in the concentration range from 2x10-8mol/L to 1x10-5mol/L (R=0.9989) with a detection limit of 7x10-9mo...

Energy Technology Data Exchange (ETDEWEB)

Ruthenium is one of the fission products in the reprocessing of irradiated fuels that requires a specific processing management. Its elimination, upstream by the PUREX process, has been considered. A process, called electro-volatilization, which take advantage of the RuO{sub 4} volatility, has been optimised in the present study. It consists in a continuous electrolysis of ruthenium solutions in order to generate RuO{sub 4} species that is volatilized and easily trapped. This process goes to satisfying ruthenium elimination yields with RuNO(NO{sub 3}){sub 3}(H{sub 2}O){sub 2} synthetic solutions but not with fuel dissolution solutions. Consequently, this work consisted in the speciation studies of dissolved ruthenium species were carried out by simulating fuel solutions produced by hot acid attack of several ruthenium compounds (Ru(0), RuO{sub 2},xH{sub 2}O, polymetallic alloy). In ...

International Nuclear Information System (INIS)

The ternary stannides RE_3Ru_4Sn_1_3 (RE = La, Ce, Pr, Nd) were obtained by arc-melting of the elements. The polycrystalline samples were characterized by powder X-ray diffraction. The structures of three compounds were refined from single-crystal diffractometer data: Yb_3Rh_4Sn_1_3 type, Pm anti 3n, a = 977.74(3) pm, wR2 = 0.0379, 280 F"2 values for La_3Ru_4Sn_1_3, a = 971.34(9) pm, wR2 = 0.0333, 274 F"2 values for Ce_3Ru_4Sn_1_3, a = 970.68(8) pm, wR2 = 0.0262, 272 F"2 values for Nd_3Ru_4Sn_1_3 with 13 variables per refinement. The structures consist of three-dimensional networks of condensed RuSn_6_/_2 trigonal prisms with the RE (CN 16) and Sn2 (CN 12) atoms in two different types of cavities of the networks. The two crystallographically independent tin sites have been resolved by "1"1"9Sn Moessbauer spectroscopy. Temperature-dependent magnetic susceptibility measurements of ...

International Nuclear Information System (INIS)

A unified calculation of neutron-rich isotopes in lithium is performed using the hyperspherical basis in which the underlying symmetry of each isotope exhibits a simple structure. The variation of the binding energy as a function of mass number is qualitatively reproduced, and the asymptotic of radial distribution of each isotope decreases exponentially. The form factors of the lithium isotopes are calculated and display diffraction minima. 27 refs., 3 figs., 3 tabs.

British Library Electronic Table of Contents (United Kingdom)

Feasibility of using fixed bed column of conventional ion exchangers/sorbent and chemical precipitation based processes have been examined for the effective removal of the very low levels of 106Ru activity from NH4NO3 effluent generated during wet processing of rejected sintered depleted uranium fuel pellets. Based on the results, a simple process involving precipitation of cobalt sulphide along with ferric hydroxide was selected and further optimization of process variables was carried out. The optimized process has been found to be highly efficient in reducing 106Ru activity down to extremely low levels.

British Library Electronic Table of Contents (United Kingdom)

The crystal structure of Ca2RuD6 has been determined by neutron powder diffraction: space group Fm3m, K2PtCl6 structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340K and 50K. The deuterium nuclear quadrupole coupling constant, 54.7kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A2MH6 salts are interpreted in terms of the ionization energies of the cation and the central metal atom.

International Nuclear Information System (INIS)

We described the use of silica nanoparticles as building blocks for the immobilization of electrogenerated chemiluminescence (ECL) reagent Ru(bpy)_3"2"+ and the fabrication of layer-by-layer assembly film by alternating the deposition of the Ru(bpy)_3"2"+-doped silica nanoparticles and Au nanoparticles. UV-vis absorption spectroscopy, scanning electron microscopy (SEM), cyclic voltammetry and ECL were used to characterize the uniform growth of the multilayer film. Since Ru(bpy)_3"2"+ could still maintain its ECL property when doped into the silica nanoparticles, the as-prepared multilayer film could be used as an effective ECL sensor, and the sensor showed high sensitivity and good stability.

British Library Electronic Table of Contents (United Kingdom)

Polymer-coated magnetic nanoparticles (MNPs) have been prepared and used as an immobilization matrix for the fabrication of solid-state tris(2,2prime-bipyridyl)ruthenium(II) (Ru(bpy)32+) electrogenerated chemiluminescence (ECL) sensor. The pre-synthesized maghemite (g-Fe2O3) MNPs were coated with poly(3-thiopheneacetic acid) based on an oxidative polymerization method using KMnO4. The poly(3-thiopheneacetic acid)-coated MNPs have formed the clusters with average diameter of 200-500nm. The multilayer films of poly(3-thiopheneacetic acid)-coated MNPs were uniformly formed on the surface of a Pt electrode by an external magnet. The Ru(bpy)32+ was rapidly incorporated into the multilayer films within 5min through the electrostatic interaction between the Ru(bpy)32+ and the negatively charged c...

International Nuclear Information System (INIS)

The electronic structures of platinum group elements (Ru, Os, Rh, Ir, Pd, and Pt) silicides have been calculated. Ir_3Si_5 is a semiconductor with the direct gap of 1.14 eV. Among monosilicides, RuSi and OsSi with the FeSi-type structure are semiconductors with the gap values of 0.21 and 0.41 eV but RhSi, IrSi, PdSi, and PtSi with the MnP-type structure are metals. No semiconducting compounds can be found in other platinum group elements silicides other than known Ru_2Si_3, Os_2Si_3, and OsSi_2.

International Nuclear Information System (INIS)

The main features and advantages of a new low energy nuclear spectroscopic method, the in-beam spectroscopy are described. Results of in-beam spectroscopic experiments performed at the Institute of Nuclear Research (ATOMKI, Debrecen, Hungary) are summarized. Gamma spectra of in-beam produced odd-odd nuclei were measured, gamma-energies were determined. Measurement of gamma-gamma coincidences led to the construction of energy level schemes of the investigated nuclei. Internal conversion electron spectroscopy was used to determine the multipolarities of transitions. A few spectra and level schemes are presented to illustrate the review. Theoretical interpretation of experimental results are briefly summarized. (D.Gy.).

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Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. The heavier lithium isotope was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was determined according to the method of Glueckauf from the elution curve and isotopic assays. The separation factor of {sup 6}Li{sup +} -{sup 7}Li{sup +} isotope pair fractionation was 1.018.

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In this study, the bend properties of the single-crystalline molybdenum brazed by using Mo-40%Ru alloys containing boron of 1-6 mass%Ru alloy for the improvement of the joint strength was determined. (orig.) [Deutsch] Durchgefuehrt wurde die Herstellung von Verbindungen aus einkristallinem Molybdaen. Hierbei kamen Mo-40%Ru-Legierungen mit 1 bis 6 Gew.-% Bor als Lotmaterialien zum Einsatz. Festigkeit und Duktilitaet der Verbindungen wurden mittels 3-Punkt-Biegepruefung bei Raumtemperatur und unter fluessigem Stickstoff ermittelt. Die Bruchflaechen der Proben wurden mit Hilfe eines Rasterelektronenmikroskopes untersucht. Die Ergebnisse lassen sich wie folgt zusammenfassen: Der optimale Borgehalt bezueglich Festigkeit und Duktilitaet der geloeteten Verbindung liegt bei 2 Gew.-%. Die entsprechende Probe hat bei einem Biegewinkel von 100 bei Raumtemperatur nicht versagt. Auch unter fluessigem Stickstoff zeigte diese Probe eine ...

International Nuclear Information System (INIS)

The magnetic structure of a tetragonal Ce(Ru_0_._9_6Pd_0_._0_4)_2Si_2 single crystal, determined by neutron diffraction measurements, is similar to that observed in Rh doped alloys. The magnetic moments are oriented and modulated along the c-axis. Here the wave vector is incommensurate: k=(0,0,0.38). At 1.5 K, the moment is estimated to about 0.3 #mu#_B. Magnetization, magnetoresistance and Hall effect measurements performed on this alloy are also reported. (orig.).

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In this paper, an attempt is made to outline the priority areas for research in human nutrition in India that could be tackled by appropriate application of stable isotope technology. 10 refs.

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We present a laser spectroscopic approach for measuring the charge radius of the halo nucleus {sup 11}Li and report on recent progress in the development of the experimental apparatus.

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The sol-gel-immobilized Tris(2,2'-bipyridyl)ruthenium(II) [Ru(bpy){sub 3} {sup 2+}] electrogenerated chemiluminescence (ECL) sensor was applied to the reversed-phase high-performance liquid chromatography (HPLC) determination of phenothiazine derivatives (promazine, chlorpromazine, triflupromazine, thioridazine, and trifluoperazine) and erythromycin in human urine samples. In this method, Ru(bpy){sub 3} {sup 2+} was immobilized in sol-gel-derived titania (TiO{sub 2})-Nafion nanocomposite films coated on a dual platinum electrode. This method eliminates an extra pump needed for the delivery of Ru(bpy){sub 3} {sup 2+} reagent into a reaction/observation zone in front of photomultiplier tube because the immobilized-Ru(bpy){sub 3} {sup 2+} is recycled on the electrode surface by an applied potential at +1.3 V versus Ag/AgCl (3 M NaCl) reference electrode. The resulting analytical performances such ...

International Nuclear Information System (INIS)

Description of problem or function: Format: EXREM III; Nuclides: radioactive decay data on 252 Nuclides: 1H-3, 4Be-7, 6C-11, 6C-14, 7N-13, 8O-15, 9F-18, 11Na-22, 11Na-24, 12Mg-28, 13Al-28, 15P-32, 15P-33, 16S-35, 17Cl-36, 17Cl-38, 18A-37, 18A-39, 19K-40, 19K-42, 19K-43, 20Ca-45, 20Ca-47, 20Ca-49, 21Sc-46, 21Sc-47, 21Sc-49, 24Cr-51, 25Mn-52M, 25Mn-52, 25Mn-54, 26Fe-52, 26Fe-55, 26Fe-59, 27Co-56, 27Co-57, 27Co-58, 27Co-60, 28Ni-56, 28Ni-63, 29Cu-64, 30Zn-65, 30Zn-69M, 30Zn-69, 31Ga-67, 31Ga-68, 32Ge-77, 33As-76, 33As-77, 34Se-75, 35Br-80M, 35Br-80, 35Br-82, 35Br-83, 35Br-84, 36Kr-79, 36Kr-83M, 36Kr-85M, 36Kr-85, 36Kr-87, 36Kr-88, 37Rb-84, 37Rb-86, 37Rb-87, 37Rb-88, 37Rb-89, 37Rb-90M, 37Rb-90, 38Sr-85, 38Sr-87M, 38Sr-89, 38Sr-90, 38Sr-91, 38Sr-92, 38Sr-93, 39Y-87, 39Y-88, 39Y-90, 39Y-91M, 39Y-91, 39Y-92, 39Y-93, 40Zr-93, 41Nb-93M, 40Zr-95, 40Zr-97, 41Nb-95M, 41Nb-95, 41Nb-97M, 41Nb-97, 42Mo-99, 43Tc-99M, 43Tc-99, 44Ru-103, 44Ru-105, ...

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Aimed at post-graduate and post-doctoral researchers in geochemistry, this book reflects the rapid changes in the applications of radioactive and stable isotope analysis to a range of geological and geochemical problems. Isotropic chemistry and methods used in mass spectroscopy are discussed initially. The second section deals with radiometric dating methods. The role of isotopes in climate and environmental research is also explored. The book closes with a section on extra-terrestrial matter, geothermometry and the isotopic geochemistry of the Earth`s lithosphere. (UK).

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... lifetime lutetium isotopes lutetium 171 lutetium 173 lutetium 175 lutetium 177

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In our previous theoretical analyses, solubility-limited mass transfer from waste solids applies if a species is at a constant elemental concentration in liquid at the waste surface. For an element with isotopes that decay appreciably during the time of interest, a solubility boundary condition results in a time-dependent boundary concentration of each isotope. Here we present mass-transfer equations that include the effects of isotopic decay boundary conditions. 9 refs., 1 fig.

International Nuclear Information System (INIS)

The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.

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No abstract prepared

International Nuclear Information System (INIS)

In this comprehensive review of current research on isotopic variations of elements in extraterrestrial materials, the variations were classified in terms of the major process involved in the modification of the isotopic composition of the element concerned. Maximum isotopic variations of each element were retrieved from publications which were available in Tokyo up to December 1985, and are presented in tabular form. (author).

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Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to ...

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DOE/NNSA and IRSN collaborated on a study of gamma-ray instruments and analysis methods used to perform isotopic measurements of special nuclear materials. The two agencies agreed to collaborate on the project in response to inconsistencies that were found in the various versions of software and hardware used to determine the isotopic abundances of uranium and plutonium. IRSN used software developed internally to test the MGA and FRAM isotopic analysis codes for criteria used to stop data acquisition. The stop-criterion test revealed several unusual behaviors in both the MGA and FRAM software codes.

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A summary of the off-gas behavior in the HARVEST pot vitrification process is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The main volatile elements were Ru, B, Cs. Some volatility was also shown by Na and Li. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) proceses involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The Ru volatility ...

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The Schroedinger equation for nuclear quadruple surface vibrations is linearized with the consequence that a new spin degree of freedom appears in the wave function of the linearized equation. This spin is called collective spin and has a value of 3/2. The linearized Schroedinger equation for quadrupole vibrations is used for the description of certain collective aspects of even-odd {sup 187,189,191}Ir nuclei which have a spin 3/2 in their ground state. As a potential we use the {gamma}-soft collective potential of the neighboring even-even nuclei, which is inserted into the linearized Schroedinger equation via a scalar coupling. This leads to a collective spin-dependent fine structure splitting of the energy levels governed by a collective SO(5) spin-orbit coupling and a correction to the kinetic energy. Further, we consider explicitly spin-dependent potentials which effectively describe the interaction of the valence nucleon with the core of the ...

International Nuclear Information System (INIS)

Stable isotopes are valuable tools for research on mineral bioavailability and metabolism. They can be used as tracers with no exposure to radiation and they do not decay over time. Attempts to use stable isotopes of minerals as metabolic tracers were first described only 25 years ago. There were relatively few reports of their use over the next 15 years, but interest in stable isotopes has expanded markedly in the last 10 years. The advantages of stable isotope tracers are so great that scientists have been willing to accept the laborious and costly nature of mineral isotope analysis, and substantial progress has been made in the field. New applications for stable isotopes and new analytical methods have been introduced recently. However, limitations to the approach and methodological problems remain to be resolved. This review describes early work in the field ...

CERN Document Server

We discuss three possible ways to address quantum physics behind chiral magnetic effect and electric charge fluctuation patterns in heavy ion collisions. The first one makes use of P-parity violation probed by local order parameters, the second considers CME in quantum measurement theory framework and the third way is to study P-odd * P-odd contributions to P-even observables. In the latter approach relevant form-factor is extracted and computed for weak magnetic field in confinement region and for free quarks in strong field regime. It is shown that the effect is negligible in the former case. We also discuss saturation effect - charge fluctuation asymmetry for free fermions reaches constant value at asymptotically large fields.

International Nuclear Information System (INIS)

The linearized collective Schroedinger equation for nuclear quadrupole surface vibrations incorporates a new spin degree of freeedom with a spin value of 3/2. We use this equation to describe the low energy spectrum of certain even-odd Ir nuclei which have a spin 3/2 in their ground state. For that purpose we explicitly introduce collective spin-dependent potentials which simulate the interaction of the valence nucleon with the core. The linearized Schroedinger equation is transformed into an effective Schroedinger equation with collective spin-dependent potentials. Already collective spin-orbit couplings of SO(3) and SO(5) type are sufficient to reproduce the lowest excited states of even-odd Ir nuclei. (orig.).

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In recent years, the method for unitarizing nonunitary Dyson boson realizations of shell-model algebras has been both generalized and substantially simplified through the introduction of overtly group-theoretical methods. In this paper, these methods are applied to the boson-odd-particle realization of the algebra SO(2..nu..+1) for ..nu.. single-particle levels, adapted to the group chain SO(2..nu..+1) contains SO(2..nu..) contains U(..nu..), which Marshalek first derived by brute force summation of a Taylor expansion and later Okubo by a largely algebraic technique.

International Nuclear Information System (INIS)

We investigate the effects of the velocity-dependent force on the magnetic form factors and magnetic moments of odd-Z nuclei. The form factors are calculated with the harmonic-oscillator wavefunctions. It is found that the contributions of the velocity-dependent force manifest themselves in the very large momentum transfer region (q?4 fm-1). In the low and medium q region the contributions of the velocity-dependent force are very small compared with those without this force. However, in the high-q region the contributions of the velocity-dependent force are larger than the normal form factors. The diffraction structures beyond the existing experimental data are found after the contributions of the velocity-dependent force are included. The formula of the correction to the single particle magnetic moment due to the velocity-dependent force is reproduced exactly in the long-wavelength limit (q=0) of the M1 form factor. (authors)

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Hydrogenation of carbon monoxide at 101.3 kPa has been studied over a series of ion-exchanged Ru catalysts supported on NaX, NaY, KL, Na mordenite, and HY zeolites. The type of zeolite had pronounced effects on the activity and selectivity of the Ru. The specific activity would appear to be related to the dispersion of reduced ruthenium in the zeolite. Methane selectivity, however, seems to be strongly influenced by the type and concentration of alkali cations remaining in the ion-exchanged zeolite. These cations appear to promote chain growth much as traditional alkali promoters would, though perhaps more indirectly. Due to bifunctional properties of the zeolite-supported catalysts, a significant fraction of C/sub 4/ was in the form of isobutane. Formation of isobutane seems to be related to either the Si/Al ratio in the zeolites or the concentration of the remaining alkali cations, but not to the OH concentration. In addition, H/sub 2/ ...

International Nuclear Information System (INIS)

CANDU 600 nuclear reactors are usually fuelled with STANDARD (STD), 37 rods fuel bundles. Natural uranium (NU) dioxide (UO_2), is used as fuel composition. A new fuel bundle geometry called CANFLEX (CFX) with 43 rods is proposed and some new fuel composition are considered. Flexibility is the key word for the attempt to use some different fuel geometries and compositions for CANDU 600 nuclear reactors as well as for innovative ACR-700/1000 nuclear reactors. The fuel bundle considered in this paper is CFX-RU-0.90 that encodes the CANFLEX geometry, recycled dioxide uranium (RU) with 0.90% enrichment. The goal of this proposal is ambitious: a higher average discharge burn-up up to 14000 MWd/tU and, for the same amount of generated electric power, reduction in nuclear fuel fabrication, reduction of spent nuclear fuel radioactive waste and reduction of refueling operational work by using fewer bundles. An improved sub-channel approach for ...

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We have measured production cross-sections of the new neutron-rich isotopes {sup 58}Ti, {sup 61}V, {sup 63}Cr, {sup 66}Mn, {sup 69}Fe, {sup 71}Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u {sup 86}Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss measurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parametrization. The resulting prospects for reaching even more neutronrich isotopes, such as the doubly-magic nuclide {sup 78}Ni, are discussed. (orig.).

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The spin relaxation processes within the pyrochlore Ho{sub 2}Ru{sub 2}O{sub 7} have been investigated by neutron scattering and bulk property techniques. A single-ion process, that is thermally activated, dominates the spin-spin relaxation spectrum above 2 K. Assuming Arrhenius behaviour, we found an activation energy {delta} = (329 {+-} 6) K and characteristic relaxation time {tau}{sub 0} (5.2 {+-} 0.3) x 10{sup -12} s in the paramagnetic state, akin to those found in the spin ice, Ho{sub 2}Ti{sub 2}O{sub 7}. Atlow temperature (T<95 K) the activation energy lowers and below 20 K the entropy and ac susceptibility are similar to that observed in other spin ice compounds within a 10 kOe field.

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The magnetic pyrochlore Er{sub 2}Ru{sub 2}O{sub 7} has been studied with neutron scattering and susceptibility measurements down to a base temperature of 270 mK. For the low temperature phase in which the Er sublattice orders, new magnetic Bragg peaks are reported which can be indexed with integer (hkl) for a face centered cubic cell. Inelastic measurements reveal a wealth of crystal field levels of the Er ion and a copious amount of magnetic scattering below 15 meV. The three lowest groups of crystal field levels are at 6.7, 9.1 and 18.5 meV.

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Lithium isotope separation by displacement chromatography is studied using fundamental principles; the equations are derived assuming theoretical stages in lithium adsorption bands. The concentration profiles in the band are calculated numerically under unsteady state.

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The angular ..gamma gamma..-correlations for nuclei of Sr even-even isotopes with A=82, 84, 86, 88 were measured. Multipole structurs of ..gamma..-transtion series and th coefficients multipole mixing were determined.

UK PubMed Central (United Kingdom)

Fatty acid biomarker analysis coupled with gas chromatography-isotope ratio mass spectrometry was used to confirm the presence of methanotrophic and thiotrophic bacterial endosymbionts in the tissues...Full Text Available

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

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A combination of degenerate four-wave mixing spectroscopy and a low-pressure sampling technique has been studied for isotopic analysis in an air-acetylene flame. Hyperfine spectra of D lines of sodium and several mixtures of lithium isotopes obtained in this way are presented.

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

International Nuclear Information System (INIS)

The essential difference as well as the apparent identity between the triaxial-rotor model and the gamma-vibrational model have been discussed. From the gamma decay mode, the [19/2"-]_1 states of the j = 11/2"- family in "1"8"7Ir and "1"8"9Ir have been identified as the K = j + 4 states, the presence of which contradicts the particle plus triaxial-rotor model. (author).

International Nuclear Information System (INIS)

Full text: The isotopic assay instrument under development at Pacific Northwest National Laboratory (PNNL) is capable of rapid prescreening to detect small and rare particles containing high concentrations of uranium in a heterogeneous sample. The isotopic measurement concept is based on laser vaporization of solid samples followed by sensitive isotope-specific detection using either uranium atomic fluorescence emission or uranium atomic absorbance. Both isotopes are measured concurrently, following a single ablation laser pulse using two external-cavity violet diode lasers. The simultaneous measurement of both isotopes enables the correlation of the fluorescence and absorbance signals on a shot-to-shot basis. This measurement approach demonstrated negligible channel crosstalk between isotopes. Scanning the heterogeneous samples provides high-resolution imagery ...

International Nuclear Information System (INIS)

German (1975). Germany Borgs, JW Fabbri, R. Grueter, JW Khan,

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... air pollution coprecipitation isotope production lead 203 proton beams

International Nuclear Information System (INIS)

... nuclear electric moments nuclear magnetic moments nuclear radii quadrupole

International Nuclear Information System (INIS)

... carrier-free isotopes hafnium compounds irradiation protons solvent extraction

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The effects of temperature and the use of macroreticular resins were studied in lithium isotope separation by an ion-exchange method. The isotope separation factors obtained decreased by increasing the temperature, and the factors for macroreticular resins were identical with those for the usual gel-type resins. However, the performance of isotope separation per unit band length in displacement chromatography was found to be improved by increasing the temperature and using macroreticular resins, because accelerating the interphase mass transfer caused the reduction of HETP (Height Equivalent to a Theoretical Plate).

International Nuclear Information System (INIS)

Page 1. RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL

International Nuclear Information System (INIS)

Short note. 2 refs.; 1 tab.

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The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of [sup 87]Mo are studied in detail and explained by the evolution of the [gamma]-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N [>=] 47 for the spherical shape of the Mo isotopes. (orig.)

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Values of frequency splittings in the lithium isotopes have been determined with the aid of laser-induced fluorescene in a supersonic beam, perpendicularly irradiated by a CW ring dye laser. The residual 2s-2p isotope shift has been found to bw 4721.8 +- 2.0 MHz, leading to a specific mass shift for the 2p level of -3610.8 +- 5 MHz.

International Nuclear Information System (INIS)

Results of americium-242m and americium-242 preparation by irradiating initial americium-241 at a reactor in the form of a diphtalocyanine complex are presented. The enrichment coefficient, equalling 10, has been obtained using the extraction method of recoil atom separation from the parent isotope. Application of the chromatographic column with Dowex-50 permits to increase the enrichment coefficient of isotopes upto 24.6.

UK PubMed Central (United Kingdom)

Studies of ribulose-1,5-bisphosphate (RuBP) carboxylase from taxonomically diverse plants show that the enzyme from C₃ and crassulacean acid metabolism pathway species exhibits lower K_m(CO₂)...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

A highly sensitive and stable tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy){sub 3} {sup 2+}) electrogenerated chemiluminescence (ECL) sensor was developed based on carbon nanotube (CNT) dispersed in mesoporous composite films of sol-gel titania and perfluorosulfonated ionomer (Nafion). Single-wall (SWCNT) and multi-wall carbon nanotubes (MWCNT) can be easily dispersed in the titania-Nafion composite solution. The hydrophobic CNT in the titania-Nafion composite films coated on a glassy carbon electrode certainly increased the amount of Ru(bpy){sub 3} {sup 2+} immobilized in the ECL sensor by adsorption of Ru(bpy){sub 3} {sup 2+} onto CNT surface, the electrocatalytic activity towards the oxidation of hydrophobic analytes, and the electronic conductivity of the composite films. Therefore, the present ECL sensor based on the CNT-titania-Nafion showed improved ECL sensitivity for tripropylamine (TPA) compared to the ECL ...

International Nuclear Information System (INIS)

An alternative and graphical representation of the magnetic moment and the effective paramagnetic moment for polycrystalline Ce compounds with tetragonal site symmetry is described. The reduced moments can be calculated by means of standard perturbation theory. The calculated values deduced from the ground states of CeCu_2Si_2, CeRu_2Si_2, and CePd_2Si_2 polycrystals are compared with experimental magnetic moments.

International Nuclear Information System (INIS)

Lead is contained as trace element in uranium ores and propagates throughout the production process to intermediate products like yellow cake or uranium oxide. The lead isotopes in such material originate from two sources: natural lead and radiogenic lead. The variability of the isotopic composition of lead in ores and yellow cakes was studied and the applicability of this parameter for nuclear forensic investigations was investigated. Furthermore, the chemical impurities contained in these materials were measured in order to identify characteristic differences between materials from different mines. For the samples investigated, it could be shown, that the lead isotopic composition varies largely from mine to mine and it may be used as one of the parameters to distinguish between materials of different origins. Some of the chemical impurities show a similar pattern and support the conclusions drawn from the lead ...

International Nuclear Information System (INIS)

Lithium isotopes are used as the raw material of tritium which is the fuel for fusion power generation and the material for fusion reactors, accordingly those are indispensable for future nuclear fusion power generation. As for boron isotopes, the neutron absorption corss section is very large, therefore, they are used for shielding neutrons and controlling fast neutron reactors. In order to further develop the utilization of nuclear power, it is important to develop the technology for separating and refining light element isotopes in large amount. In fiscal year 1995, the relation of the ion sieve characteristics of inorganic ion exchanger and the behavior of lithium isotope separation was examined. The behavior of forming boron complex of polyol amine was examined by B-11 NMR. These experiments and the results are reported. It was shown to be feasible that lithium is adsorbed from seawater, and ...

International Nuclear Information System (INIS)

Study of the ground-state properties of Kr, Sr and Zr isotopes has been performed in the framework of the relativistic mean-field (RMF) theory using the recently proposed relativistic parameter set NL-SH. It is shown that the RMF theory provides an unified and excellent description of the binding energies, isotope shifts and deformation properties of nuclei over a large range of isospin in the Z=40 region. It is observed that the RMF theory with the force NL-SH is able to describe the anomalous kinks in isotope shifts in Kr and Sr nuclei, the problem which has hitherto remained unresolved. This is in contrast with the density-dependent Skyrme-Hartree-Fock approach which does not reproduce the behaviour of the isotope shifts about shell closure. On the Zr chain we predict that the isotope shifts exhibit a trend similar to that of the Kr and Sr nuclei. The RMF theory also predicts ...

Energy Technology Data Exchange (ETDEWEB)

The half-life ({ital T}{sub 1/2}) and {ital g} factor of the 2002 keV 11{sup {minus}} isomer in the odd-odd nucleus {sup 92}Tc produced by the pulsed heavy-ion reaction {sup 68}Zn({sup 28}Si,{ital p}3{ital n}){sup 92}Tc have been measured using time differential perturbed angular distribution method. The measured {ital T}{sub 1/2} value is 3.15(20) ns. From the observed spin precession frequency {omega}{sub {ital L}} of a {sup 92}Tc recoil implanted into a ferromagnetic Ni host, we obtain the {ital g} factor to be 0.806(20). The measured value of the {ital g} factor is in good agreement with a shell model analysis carried out using {pi}({ital p}{sub 1/2}{ital g}{sub 9/2}) and {nu}({ital p}{sub 1/2}{ital g}{sub 9/2}) orbitals for the proton particles and neutron holes outside the {sup 88}Sr core. {copyright} {ital 1996 The American Physical Society.}

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Polarized antiprotons produced by spin filtering with an internal polarized gas target provide access to a wealth of single- and double-spin observables, thereby opening a window to physics uniquely accessible with the HESR at FAIR. This includes a first measurement of the transversity distribution of the valence quarks in the proton, and a first measurement of the moduli and the relative phase of the time-like electric and magnetic form factors G{sub E,M} of the proton. In polarized and unpolarized pp-bar elastic scattering open questions like the contribution from the odd charge-symmetry Landshoff-mechanism at large |t| and spin-effects in the extraction of the forward scattering amplitude at low |t| can be addressed.

Wastenet

... (restricted)] 319-341 The value of container terminal investment to ocean carrier strategy by Thomas Pawlik & Lars Stemmler & Alfred J Baird ... (restricted)] 142-173 Prediction of arrival times and human resources allocation for container terminal by Gianfranco Fancello & Claudia Pani & Marco Pisano ... (restricted)] 347-369 Analysis of berth allocation and inspection operations in a container terminal by Yongpei Guan & Kang-hung Yang [Downloadable! (... (restricted)] 237-262 Container terminal concessions: A game theory application to the case of the ports of Pakistan by Naima Saeed & Odd ...

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The available experimental data on the (/sup 3/He,n) reaction between the ground states of even-even nuclei and lowest 1/2/sup -/ levels of odd-A nuclei in the Aapprox.=100 region are analyzed in a systematic way by the DWBA. The deduced relative intensities of these two-proton transfers, and their uncertainties, are compared to the predictions of various nuclear models. In particular, the influence of the finite dimension of the configuration space available to the transferred protons, and of the blocking effect of a 2p1/2/sup -/ proton, are examined. (orig.).

Energy Technology Data Exchange (ETDEWEB)

For analysis of a small quantity of americium, it is necessary to separate from curium which has similar chemical property. As a chemical separation method for americium and curium, the oxidation of americium with pentavalent bismuth and subsequent co-precipitation of trivalent curium with BIP O{sub 4} were applied to analyze americium in irradiated MOX fuels which contained about 30wt% plutonium and 0.9wt% {sup 241}Am before irradiation and were irradiated up to 26.2GWd/t in the experimental fast reactor Joyo. The purpose of this study is to measure isotopic ratio of americium and to evaluate the change of isotopic ratio with irradiation. Following results are obtained in this study. (1) The isotopic ratio of americium ({sup 241}Am, {sup 242m}Am and {sup 243}Am) can be analyzed in the MOX fuels by isolating americium. The isotopic ratio of {sup 242m}Am and {sup 243}Am increases up to 0.62at% and ...

International Nuclear Information System (INIS)

Liquid-liquid extractive separation of lithium isotopes was carried out in order to investigate the fluctuation of separation factors (a) as a function of salt concentrations in an aqueous phase. Two equations for separation factor (a_o_b_s) as a function of the concentration were introduced; one for the diluted region, and another for the concentrated region. In the former solution where hydrated lithium ions are predominant, 1n a_o_b_s = Ac + B, and in the latter where ion-pairs with anions are predominant, 1n a_o_b_s = Dc + E(c - F)"1"/"3 + G. Some guidelines are derived from the salt-specific constants A, B, D, E, F and G. The heavier isotopes are inclined to be in the more hydrated state in the diluted solution, while the lighter isotopes tend to be in a less hydrated state. In the concentrated solution, heavier isotopes are more likely to be in ion-pair form. Ionic association occurs from the ...

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The naive time reversal odd (T-odd) parton distribution $h_{1}^{\\perp}$, the so-called Boer-Mulders function, for both $u$- and $d$-quarks is considered in the diquark spectator model. While other approaches give evidence that the signs of the Boer-Mulders function for both flavors $u$ and $d$ are the same and negative, previous caculations in the diquark-spectator model found $h_{1}^{\\perp(u)}$ and $h_{1}^{\\perp(d)}$ have differnet signs. The flavor dependence is of significance for the analysis of the azimuthal $\\cos(2\\phi)$ asymmetries in unpolarized SIDIS and DY-processes, as well as for the overall physical understanding of the distribution of transversely polarized quarks in unpolarized nucleons. We find substantial differences with previous work. In particular we obtain estimates of the zeroth, half and first moments of Boer-Mulders functions that are negative over the full range in Bjorken $x$ for both the up and down quarks. In ...

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We propose a novel method for ultrasensitive isotope analysis that combines magnetic mass selection, resonant charge-exchange neutralization, and resonant laser ionizaion. Our method attains high isotopic abundance selectivity by means of continuous multistage separation of ions stored in a small ring. For the environmentally interesting case of /sup 90/Sr versus /sup 88/Sr we estimate that sensitivity better than 10/sup -15/ for a throughput of 10/sup 13/ atoms/sec and an efficiency (after the ion source) greater than 10% are readily achievable.

International Nuclear Information System (INIS)

The neutron-rich Fe isotopes from A=61 to 66 were studied through multinucleon transfer reactions by bombarding a "2"3"8U target with a 400 MeV "6"4Ni beam. Unambiguous identification of prompt #gamma# rays belonging to each nucleus was achieved using coincidence relationships with the ions detected in a high-acceptance magnetic spectrometer. The new data extend our knowledge of the level structure of Fe isotopes, which is discussed in terms of the systematics of the region and compared with large-scale shell-model calculations.

International Nuclear Information System (INIS)

Special beam extraction channel is used at INR linac for isotope production. It starts from 160 MeV measuring and matching area of accelerator. This choice of beam extraction enables to direct to the target of isotope complex a proton beam of wide energy range up to 160 MeV. It is important for production of different types of nuclides. The measuring results of proton beam behavior in this region are presented. Required beam forming in 160 MeV measuring and matching area of accelerator and in beam extraction channel is discussed.

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented.

International Nuclear Information System (INIS)

COMPLIS is an experimental facility designed to carry out spectroscopic studies on radioisotopes produced by disintegration of elements available at CERN's Booster-ISOLDE on-line isotope separator. During recent series of experimental runs, hyperfine structure measurements have yielded information on nuclear moments and deformations of platinum and iridium isotopes. For the first time, population by #alpha#-decay from Hg was exploited to investigate "1"7"8"-"1"8"1Pt--the most neutron-deficient Pt isotopes yet studied. Successful measurements have recently been carried out on "1"8"2"-"1"8"9Ir.

Energy Technology Data Exchange (ETDEWEB)

A laser-induced plasma of alkali atoms was studied with a view to efficient recovery of isotope ions, with small charge exchange losses. The electron temperature was measured by the double-probe method for several kinds of excitation schemes, which gave the relationship between temperature and the energy given to ions by laser photons. A charge exchange process between lithium isotopes was also studied in an electromagnetic field. It was shown that optimum electrostatic and magnetic field strength exist which maximise the 'separative power'.

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The carbon cycle is an important part of major biogeochemical cycles. Many techniques may be used to characterize carbon amounts and sources in the environment. Here we first review the most popular techniques for the determination of organic and inorganic carbon concentrations. Decarbonatation techniques are also reviewed in details since it is often an important part of organic carbon analysis. The second part of this paper addresses the use of carbon stable isotopes to characterize organic carbon sources and processes in the environment. An overview of general stable isotopes background and terminology is given as well as the most popular analytical techniques.

Energy Technology Data Exchange (ETDEWEB)

The behaviour of tetracycline as an extracting agent for Sr, I, Ba, Mo, Tc, Zr, Nb, Cs, Ru, Te and U was studied and the influence of the acidity of the aqueous phase upon extraction of the elements mentioned was examined. Experiments were made to determine whether the species extracted into the organic phase is the complex formed between tetracycline and the elements considered and to determine the time of shaking necessary so that the equilibrium between the phases is attained. As a practical application, the possibility of using the tetracycline-benzyl alcohol system for separating the fission products sup(137)Cs, sup(140)La, sup(141)Ce, sup(103)Ru, sup(95)Nb from each other and from uranium is presented. The same study was made for sup(131)I, sup(99m)Tc, sup(99)Mo, sup(132)Te, sup(239)Np and uranium and the steps necessary for the separation of these elements are proposed.

International Nuclear Information System (INIS)

CO poisoning is a major issue when reformate is used as a fuel in PEM fuel cells. Normally it is necessary to reduce the CO to very low levels (#approx#5 ppm) and CO tolerant catalysts, such as Pt-Ru, are often employed. As an alternative approach, we have studied the use of pulsed oxidation for the regeneration of CO poisoned cells. Results are presented for the regeneration of Pt and Pt-Ru anodes in a PEM fuel cell fed with CO concentrations as high as 10,000 ppm. The results show periodic removal of CO from the catalyst surface by pulsed oxidation can increase the average cell potential and increase overall efficiency. A method for enhancing the performance of a fuel cell stack using a microprocessor-based Fuel Cell Health Manager (FCHM) has been developed. The results of a cost/benefit analysis for the use of a FCHM on a 4 kW residential fuel cell system are presented. (author)

British Library Electronic Table of Contents (United Kingdom)

Abstract Coordination compounds [Ru(acac)2(Q)] (acac=acetylacetonate; Q=o-benzoquinone) were prepared as complexes 1 (Q=o-benzoquinone), 2 (Q=3-methoxy-o-benzoquinone), 3 (Q=4-methyl-o-benzoquinone), and 4 (Q=3,5-di-tert-butyl-o-benzoquinone). The structures of 1 and 2 were determined to reveal a RuIII/o-benzosemiquinone formulation, supported by analysis of experimental data (spectroscopy, magnetism of 1) and by DFT calculations. The S=1 ground state calculated for 1 stands in contrast to the spin-paired analogues with arylimino-o-benzosemiquinonato and diimino-o-benzoquinone ligands. The close contacts of about 5.3- possible between semiquinone O atoms of different molecules in the crystal allow for intermolecular spin-spin interactions and an overall complex magnetic behavior. One quasi...

Energy Technology Data Exchange (ETDEWEB)

This paper studies the sorption of chlorine complexes of ruthenium (IV) on the graft copolymer of a polyacrylonitrile fiber with poly-2-methyl-5-vinylpyridine (PAN-MVP). The composition of the fiber is illustrated. It is shown that sorption of chlorine complexes of ruthenium (IV) from acid solutions by a pyridine fiber sorbent takes place according to an anion-exchange mechanism and is due to the formation of compounds of the diamine type (Ru(RPy)/sub 2/Cl/sub 4/).

Energy Technology Data Exchange (ETDEWEB)

New isotopic age determinations carried out with the rubidium-strontium method on granodioritic basement rocks from the Mecsek Mountains in Southeastern Transdanubia give further support to assumptions on a polyphase development of the Mecsek crystalline. As shown by initial Sr isotopic ratios, the protolith of the granodioritic assemblage of polymetamorphic-anatectic origin must have been strongly basic in its composition. The scatter of individual model ages obtained on total rock samples reflects the polymetamorphic-polytectonized character of the basement, and suggests that following a primary granitization process secondary events might have led to the total or partial recrystallization of the rocks in question. The tectonic development of the basement crystalline as reflected in the isotopic age data closed at about 270+-20 million years ago, with processes causing retrograde changes in the crystalline as a whole but ...

International Nuclear Information System (INIS)

Author.The geochemical and isotopic study, based on the analysis of twenty water samples from well in the coastal plain of Sarafand (South-Lebanon), permit to eliminate the hypothesis of marine intrusion in this aquifer. The increase of salinity observed in certain wells is due to the contamination of cretaceous aquifer water by the quaternary formations. The two poles of mixing are respectively characterized: by weak tritium contents (between 2 and 3 UT) and a value of stable isotopes (-5,9<0,18<-5,5) corresponding to the appearance of cretaceous formation area; by the high tritium contents and enrichment relative to heavy isotope in the mineralized water of superficial formations. On the other hand, the isotope contents permit the set a rapid renewal of the cretaceous aquifer water due to quick circulation in the Karstic system

International Nuclear Information System (INIS)

The energy level schemes of tin isotopes produced in the heavy ion reactions are presented. The using of #gamma# spectroscopy technique is also described. 4 refs, 12 figs.

Energy Technology Data Exchange (ETDEWEB)

In order to get the separation of natural isotopes of lithium by electrolytic amalgamation, an electrolytic cell with a confined mercury cathode was used to obtain data for the design of a separation stage. The initial work was followed by the design of a moving mercury cathode electrolytic cell and three experiments with six batches stages were performed for the determination of the elementary separation factor. The value obtained, 1.053, was ill agreement: with the specialized literature. It was verified in all experiments that the lithium - 6 isotope concentrated in the amalgam phase and that the lithium - 7 isotope concentrated in the aqueous phase. A stainless-steel cathode for the decomposition of the lithium amalgam and the selective desamalgamation were also studied. In view of the results obtained, a five stages continuous scheme was proposed. (author)

Science.gov (United States)

The location of defective LMFBR fuel pins by the determination of gas tag isotopic ratios is discussed. The application of this method to the FFTF Reactor briefly described.

Energy Technology Data Exchange (ETDEWEB)

A tunable diode laser is used to obtain infrared spectra of carbon dioxide in biological materials. The spectral resolution is sufficient to readily distinguish differing isotopic species. The technique may prove useful in clinical tests.

Energy Technology Data Exchange (ETDEWEB)

A brief review of standard big bang nucleosynthesis theory and the related observations of the light element isotopes is presented. Implications of BBN on chemical evolution and constraints on particle properties will also be discussed.

Energy Technology Data Exchange (ETDEWEB)

Recently, the precise isotope ratios of some refractory elements in meteorites have been reported using inductively coupled plasma mass spectrometry. The in situ decay of {sup 182}Hf (T{sub 1/2}=9 Myr), which was produced at the latest nucleosynthesis, is recognized in many meteorites as isotopic anomalies of its daughter isotope, {sup 182}W. The degrees of relative {sup 182}W isotopic deviation in extra-terrestrial and terrestrial silicate samples vary from +0.3% to {+-}0% related to the size of their parent bodies. One ready interpretation of its correlation is the difference in timing of metal-silicate separation in the parent bodies. Between the earth and meteorite parent bodies, the difference is calculated to be about four times of the half-life of {sup 182}Hf, equivalent to 36 Myr. (author)

International Nuclear Information System (INIS)

... Inst. of Modern Physics 7-5022-0983-2 180 p. beta decay ft value ground states

International Nuclear Information System (INIS)

Removal of radioactive ions was studied from low and medium level radioactive waste solutions by electrodialysis using ion exchange membranes. The test solutions contained "1"3"7Cs"+, "1"0"6Ru"3"+ or fission products (F.P.) as active ions and NaCl, Na_2SO_4 or Ca(NO_3)_2 as inactive coexisting salts. The decontamination factor of the active ions was in the order: "1"3"7Cs"+ (greater than 99%) > "9"0Sr"2"+ > F.P. > "1"0"6Ru"3"+. The dialysis time required to attain the saturation was the shortest for monovalent cations K"+, Cs"+ and Na"+, intermediate for divalent cation Sr"2"+, and the longest for trivalent cation Ru"3"+. The ratio of the decontamination factor of an active ion eta sub( a) to the desalination factor of an inactive ion eta sub( b) was nearly equal to unity for "2"4Na, "4"2K, "1"3"7Cs and "9"0Sr. On the other hand, the apparent selective permeability of an active ion (A"+) against Na"+ ion, T ...

International Nuclear Information System (INIS)

This paper reviews three key initiatives undertaken in the historical city of Oxford to bring about reductions in energy-related CO_2 emissions on a city-wide scale. The author has been part of all the three initiatives. In 2002, a collaborative partnership between academia, industry and city council started the Oxford Solar Initiative (OSI) which uses a community-based approach to help households and organisations in Oxford, financially and technically, to install solar energy systems and energy efficiency measures in buildings. So far OSI has facilitated the installation of 80 active solar systems, over 450 energy efficiency measures and 3,000 low energy bulbs. The scientific basis of OSI is a GIS-based DECoRuM model which estimates and maps baseline energy use and CO_2 emissions on a house-by house level, identifies 'pollution' hotspots, predicts the potential for reductions in CO_2 emissions and monitors reductions achieved as a result of deploying energy ...

International Nuclear Information System (INIS)

The intensity of luminescence from the "2E state of Cr(bpy)_3"3"+ (bpy = 2, 2'-bipyridine) is lower in D_2O, although the "2E lifetime is unchanged, indicating that the "4T_2 (precursor to "2E) is sensitive to the isotopic nature of the solvent. A photophysical mechanism is proposed for Cr(NN)_3"3"+ complexes.

International Nuclear Information System (INIS)

Most diffusion phenomena in solids can be understood (or sometimes misunderstood) on a purely classical model. For light interstitials (hydrogen isotopes, the positive muon, and potentially He) there may be anomalous temperature dependences, and isotope effects, and anomalous response to electric fields and temperature gradients. Some of these anomalies are quantal in origin, and will be discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

Presently available relativistic and nonrelativistic effective interactions do not predict the same behavior for the isotope shifts in the Pb region.We analyze this difference and find that it is related to the characteristics of the spin-orbit term used in the parametrizations. We show that a simple modification of the spin-orbit contribution to the nonrelativistic Skyrme functional solves this problem. ((orig.))

International Nuclear Information System (INIS)

Projectilelike fragments following the 80 MeV "1"6O+"2"7Al reaction have been detected using a Bragg-curve spectroscopy ionization chamber (BCS-IC). The atomic number is deduced from the Bragg-peak amplitude. Nitrogen isotopes are clearly resolved using either range or energy loss data. This is the first application of the BCS method for complete ion identification in a heavy-ion-induced reaction.

Science.gov (United States)

Evaluation procedures used to produce sets of evaluated data for the 33 heavy isotopes that fall in the range Z = 90 to Z = 98 are described. At the beginning of the discussion for each individual isotope, a computer-generated listing is given which summarizes the main properties of the data sets that are contained in the evaluation. (RWR)

International Nuclear Information System (INIS)

We have performed precision measurements in a magneto-optical trap of the 7P1/2 hyperfine structure of the isotopes 209-210Fr. The ratio of these hyperfine constants to the previously measured 7S1/2 ground state values reveals a significant hyperfine anomaly. This anomaly results from the different radial dependence of the electron density in the two atomic levels. The measurements are sensitive to changes in the radial distribution of the neutron magnetism.

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Prompt neutron spectra for Am isotopes ({sup 241}Am, {sup 242m}Am, {sup 243}Am) were calculated on the basis of a modified version of the Madland-Nix model combined with multimodal fission model. The predicted spectra were found to be in fair agreement with recent data. (author)

International Nuclear Information System (INIS)

Americium 242m and americium 242 were prepared by reactor irradiation of americium 241 as its diphthalocyanine complex. The product atoms were extracted from the parent isotope at an enrichment factor of 10. A Dowex 50 chromatographic column raised the factor to 24.6.

International Nuclear Information System (INIS)

In a cold fusion method by electrolysis, a hydrogen occluding material mainly comprising vanadium is used as a material for a negative electrode, and lithium isotopes are incorporated in the material by more than 93%. That is, the ratio of lithium 7 ("7Li) isotope is increased to higher than the natural existent ratio, so that tritium ("3H) concentration in the hydrogen occluding material can be increased, to attain energy at high efficiency. (T.M.).

Energy Technology Data Exchange (ETDEWEB)

Anorthosites are rocks consisting almost completely of calcic plagioclase, usually from andesine to labradorite. They are not widespread, and until recently were of no economic interest. However, with the advance of the new global tectonics, which has excited considerable interest in the structure and composition of upper-mantle rocks, interest in the anorthosites has grown. This has particularly been the case since the discovery of anorthosites on the moon, where they appear to be more widespread than on the earth. Data have recently been obtained on the strontium isotope compositions of anorthosite intrusions in the Dzhugdzhur-Stanovoy zone and in the rocks surrounding them, which have revealed some unexpected features. The paper describes the geological features of anorthosites, initial concepts on strontium isotope geochemistry, strontium isotope compositions of this region, and discusses some genetic consequences from ...

International Nuclear Information System (INIS)

Laser spectroscopy measurements have been performed on neutron-deficient iridium isotopes. The hyperfine structure and isotope shift of the optical Ir I transition 5d"76s"2 "4F_9_/_2#->#5d"76s6p "6F_1_1_/_2 have been studied for the "1"8"2"-"1"8"9Ir, "1"8"0Ir"m and "1"9"1","1"9"3Ir isotopes. The nuclear magnetic and quadrupole moments were obtained from the hyperfine splitting measurements and the changes of the mean square charge radii from the isotope shift measurements. A large deformation change between "1"8"7Ir and "1"8"6Ir and between "1"8"6Ir"m and "1"8"6Ir"g has been observed.

Energy Technology Data Exchange (ETDEWEB)

Burnable poisons are used in nuclear reactors to produce a more level distribution of power in the reactor core and to reduce to necessity for a large control system. An ideal burnable poison would burn at the same rate as the fuel. In this study, separation of neutron-absorbing isotopes was investigated in order to eliminate isotopes that remain as absorbers at the end of fuel life, thus reducing useful fuel life. The isotopes Gd-157, Dy-164, and Er-167 were found to have desirable properties. These isotopes were separated from naturally occurring elements by means of plasma separation to evaluate feasibility and cost. It was found that pure Gd-157 could save approximately $6 million at the end of four years. However, the cost of separation, using the existing facility, made separation cost- ineffective. Using a magnet with three times the field strength is expected to reduce the cost by a factor of ...

International Nuclear Information System (INIS)

1 - Description of program or function: MCB-JEF2.2 is a continuous-energy cross section libraries in ACE Format suitable for the MCB-1C and MCNP codes. Libraries for various materials were generated at six different Temperatures, and cover the energy range up to 20 MeV. Format: ACE. Number of groups: Continuous energy. Nuclides: H-1, H-2, H-3, He-3, He-4, Li-6, Li-7, Be-9, B-10, B-11, C-nat., N-14, N-15, O-16, O-17, Na-23, F-19, Mg-nat., Al-27, Si-nat., P-31, S-32, S-33, S-34, S-36, Cl-nat, K-nat, Ca-nat., Ti-nat, V-nat, Cr-50, Cr-52, Cr-53, Cr-54, Mn-55, Fe-54, Fe-56, Fe-57, Fe-58, Co-59, Ni-58, Ni-59, Ni-60, Ni-61, Ni-62, Ni-64, Cu-nat, Ga-nat, Ge-72, Ge-73, Ge-74, Ge-76, As-75, Se-74, Se-76, Se-77, Se-78, Se-80, Se-82, Br-79, Br-81, Kr-78, Kr-80, Kr-82, Kr-83, Kr-84, Kr-85, Kr-86, Rb-85, Rb-86, Rb-87, Sr-84, Sr-86, Sr-87, Sr-88, Sr-89, Sr-90, Y-89, Y-90, Y-91, Zr-nat, Zr-90, Zr-91, Zr-92, Zr-93, Zr-94, Zr-95, Zr-96, Nb-93, Nb-94, Nb-95, Mo-nat, Mo-92, Mo-94, Mo-95, Mo-96, Mo-97, ...

Energy Technology Data Exchange (ETDEWEB)

The distribution of carrier free lead-203 between plasma and cells of canine blood in vitro was measured. Activity in the plasma decreased to less than 5% of the initial blood activity during the first 15 min and then exponentially with a half time of 160 min. Incubation in cell free plasma before addition to whole blood transformed the isotope, decreasing the amount subsequently associated with cells. In animal studies, activity was measured in plasma, blood cells, urine, and feces after exposure to lead-203. In one group, the animals were exposed by intravenous injection of dilute citric acid solutions of isotope. In a second group, carrier free isotope which had been transformed by incubation in plasma was injected intravenously. The kinetics of the distribution of the isotope differed between the two experimental groups. After injection of the transformed lead, the lead-203 content of the blood cell ...

CERN Document Server

Infinite loop space theory, both additive and multiplicative, arose largely from two basic motivations. One was to solve calculational questions in geometric topology. The other was to better understand algebraic K-theory. The Adams conjecture is intrinsic to the first motivation, and Quillen's proof of that led directly to his original, calculationally accessible, definition of algebraic K-theory. In turn, the infinite loop understanding of algebraic K-theory feeds back into the calculational questions in geometric topology. For example, use of infinite loop space theory leads to a method for determining the characteristic classes for topological bundles (at odd primes) in terms of the cohomology of finite groups. We explain just a little about how all that works, focusing on the central role played by E infinity ring spaces.

International Nuclear Information System (INIS)

The authors search for the extended conformal algebra with two spin-s (s:integer) and one spin-1 generators. This search is inspired by the existence of chiral algebra in the Gaussian model for rational radius. For odd s, the conformal properties of the three-point functions imply that a general fusion rule can be reduced to those of the Gaussian model. For arbitrary even s, these conditions are weaker. In particular, for s = 2 the authors show that the chiral algebra of the Gaussian model is the unique extended conformal algebra with the value of the central charge fixed to be c = 1. It is also shown that the conformal generator is necessarily a bilinear of the spin-1 generator just as the Gaussian model. The authors conjecture that this remains true for arbitrary value of s.

British Library Electronic Table of Contents (United Kingdom)

Abstract Background- Pemphigus vulgaris is a chronic disease not currently curable. Physical involvement and the impact of chronic therapies can lead patients to changes in psychological and relational areas. Objectives- To provide a measure of psychological distress, dysfunctional investment in one's appearance, and their relationship. Methods- Self-administered questionnaires (ASI, HADS) were given to 74 pemphigus inpatients. Results- Strong associations between psychological distress and dysfunctional investment in one's appearance were observed [adjusted odds ratio (OR) = 7.36, 95% confidence intervals (CI) 1.20-45.11; OR 5.38, 95% CI 0.81-35.87, respectively, for appearance stereotyping and body-image vulnerability], together with a perceived high disease severity (OR 6.03, 95% CI 1.9...

International Nuclear Information System (INIS)

We present the effects of heavy CP-even (H) and CP-odd (A) Higgs bosons on the production cross section of the process #gamma##gamma##->#tt at the energy around the mass poles of the Higgs bosons. It is found that interference between H and A with small mass gap, as well as the ones between Higgs bosons and continuum, contributes to the cross section, if the photon beams are polarized and if we observe the helicity of the top quarks. It is demonstrated in the framework of the minimal supersymmetric extension of the standard model that the H and A contributions can be sizable at future #gamma##gamma# colliders for small values of tan #beta#. The methods to measure the CP-parity of the Higgs boson are also presented. The statistical significance of detecting the Higgs signals and measuring the Higgs CP-parity is evaluated. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The detection of explosives is a notoriously difficult problem, especially at stand-off distances, due to their (generally) low vapor pressure, environmental and matrix interferences, and packaging. We are exploring optimal dynamic detection to exploit the best capabilities of recent advances in laser technology and recent discoveries in optimal shaping of laser pulses for control of molecular processes to significantly enhance the standoff detection of explosives. The core of the ODD-Ex technique is the introduction of optimally shaped laser pulses to simultaneously enhance sensitivity of explosives signatures while reducing the influence of noise and the signals from background interferents in the field (increase selectivity). These goals are being addressed by operating in an optimal nonlinear fashion, typically with a single shaped laser pulse inherently containing within it coherently locked control and probe sub-pulses. With sufficient bandwidth, the ...

Energy Technology Data Exchange (ETDEWEB)

A more complete level scheme is presented here for the decay of [sup 187]Pt, incorporating many new lines and levels up to 2.4 MeV. Emphasis has been placed on the extraction of multipole mixing ratios from nuclear orientation data. Analysis of that data, however, required a more complete understanding of the level structure (including, in particular, branching ratios, conversion coefficients, and level feedings), prompting the collection of new spectroscopy data. The low-lying, positive-parity levels are described in terms of (odd-proton) single-particle Nilsson states coupled to a triaxial core. Multipole mixing ratios are compared to those calculated in the Particle-Plus-Triaxial-Rotor Model. (orig.).

British Library Electronic Table of Contents (United Kingdom)

Systematically review risks of an infant being born with low birth weight (LBW), preterm birth (PTB) or small for gestational age (SGA) among married and unmarried women. Medline, Embase, CINAHL, and bibliographies of identified articles were searched for English language studies. Studies reporting birth outcomes of married and unmarried (single and cohabitant) were included. Two reviewers independently collected data and assessed the quality of the studies for biases in sample selection, exposure assessment, confounder, analytical, outcome assessments, and attrition. Meta-analyses were performed using random effect model for both unadjusted and adjusted data and odds ratio (OR), and 95% confidence interval (CI) were calculated. Twenty-one studies of low to moderate risk of bias were inclu...

CERN Document Server

We investigate the equivariant cohomology of the natural torus action on a K-contact manifold and its relation to the topology of the Reeb flow. Using the contact moment map, we show that the equivariant cohomology of this action is Cohen-Macaulay, which is a generalization of equivariant formality for torus actions without fixed points. As a consequence, a generic component of the contact moment map is a perfect Morse-Bott function for the basic cohomology of the orbit foliation F of the Reeb flow. Assuming that the closed Reeb orbits are isolated, we show that the basic cohomology of F is trivial in odd degrees, and its dimension equals the number of closed Reeb orbits. We characterize the K-contact manifolds with minimal number of closed Reeb orbits as real cohomology spheres. We also prove a GKM type theorem for K-contact manifolds, which allows us to calculate the equivariant cohomology algebra of K-contact manifolds in presence of the nonisolated GKM ...

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The relationship between X chromosome-linked adrenoleukodystrophy and the red/green color pigment gene cluster on Xq28 was investigated in a large kindred. The DNA in a hemizygous male showed altered restriction fragment sizes compatible with at least a deletion extending from the 5[prime] end of the color pigment genes. Segregation analysis using a DNA probe within the color pigment gene cluster showed significant linkage with adrenoleukodystrophy (logarithm of odds score of 3.19 at [theta] = 0.0). These data demonstrate linkage, rather than association, between a unique molecular rearrangement in the color pigment gene cluster and adrenoleukodystrophy. The DNA changes in this region are thus likely to be helpful for determining the location and identity of the responsible gene. 33 refs., 4 figs.

British Library Electronic Table of Contents (United Kingdom)

Harmonics bred from loads are mainly odd order because the current waveforms have half-wave symmetry. Since the even harmonics are negligibly small, they generally are not measured in electric power systems. However, even harmonics were measured at a 500/275/154 kV substation in Hokuriku Electric Power Company after a transmission line fault was corrected. The even harmonics caused malfunctions of protective digital relays because the relays used 4th harmonics at the input filter as the automatic supervisory signal. This paper describes mechanisms of generation of the even harmonics by comparing the measured waveforms with the ATP-EMTP simulation results. Analysis of these results has clearly shown that there are three different mechanisms of generation of even harmonics. The first mechani...

Science.gov (United States)

The progression of hip dysplasia was investigated in 116 military working dogs. Serial pelvic radiographs were graded for degree of dysplasia and degenerative joint disease (DJD). Norberg angles, angles of inclination, and joint space widths were measured. There was a significant correlation between the Norberg angle and the degree of dysplasia (p less than 0.0001). Angles of inclination and joint space width measurements did not demonstrate a correlation to canine hip dysplasia. Dysplastic dogs had a significant estimated risk for development of DJD compared to normal dogs (p less than 0.0001; odds ratio of 70.2). Dogs with normal hip conformation at 24 months of age or older did not develop moderate nor severe DJD. PMID:8875357

Energy Technology Data Exchange (ETDEWEB)

Q/sub ..beta..-values are determined for 18 nuclei (Zr-, Nb-, Mo-, Tc-, Ru- and Rh-nuclides) with mass numbers 101 less than or equal toA less than or equal to106 and A=109 from measurements of beta decay energies which were carried out at the LOHENGRIN mass separator at the Institut Laue-Langevin in Grenoble (France). The given Q/sub ..beta..-values between 2 and 8 MeV show errors of about 1.5% (with the exception of /sup 103/Zr and /sup 105/Nb resp. and /sup 103/Tc for which larger errors result due to statistical resp. systematic reasons): /sup 101/Zr 5500+-70, /sup 101/Nb 4580+-45, /sup 102/Zr 4670+-40, /sup 102/Nb 7230+-70, /sup 103/Zr 6790+-240, /sup 103/ 5740+-70, /sup 103/Mo 3575+-80, /sup 103/Tc 2585+-70, /sup 104/Nb 8250+-130, /sup 104/Mo 2180+-40, /sup 104/Tc 5520+-100, /sup 105/Nb 6570+-150, /sup 105/Mo 4885+-80, /sup 105/Tc 3750+-60, /sup 106/Mo 3515+-45, /sup 106/Tc 6540+-70, /sup 109/Ru 4150+-80, /sup 109/Rh 2550+-50 (all values ...

Energy Technology Data Exchange (ETDEWEB)

The operation of a nuclear power reactor necessarily implies the consumption or burnup of reactor fuel by fission and capture, which gives rise to a decrease in the reactivity of the reactor. The effect of americium formation on the criticality of a thermal power reactor using two types of fuel is studied. The three-dimensional core calculation is used to calculate the production of the transuranium isotopes and their effect on the effective multiplication factor (K[sub eff]). This effect cannot be neglected for thermal power reactors with UO[sub 2]-PuO[sub 2] fuel (3.11% after 70 weeks of operation). The effect of the transuranium isotopes on the K[sub eff] for a thermal power reactor with UO[sub 2] fuel is about 0.0018% and can be ignored. (author).

Science.gov (United States)

The neutron-rich Mn isotopes from A=59 to 63 have been studied through multi-nucleon transfer reactions by bombarding a {sup 238}U target with a beam of {sup 70}Zn at an energy of E{sub lab}=460 MeV. Prompt {gamma} rays measured by the CLARA array have been identified unambiguously for each nucleus, using coincidence relationships with ions detected in the high-acceptance magnetic spectrometer PRISMA. The new data extends the knowledge of the low-lying level structure of Mn isotopes, which is discussed in terms of the systematics of the region. Results are compared with large-scale shell-model calculations using different effective interactions and valence spaces.

International Nuclear Information System (INIS)

Target materials for inertial fusion energy (IFE) power plant designs might be selected for a wide variety of reasons including wall absorption of driver energy, material opacity, cost and ease of fabrication. While each of these issues are of great importance, target materials should also be selected based upon their safety and environmental (S and E) characteristics. The present work focuses on the recycling, waste management and accident dose characteristics of potential target materials. If target materials are recycled so that the quantity is small, isotopic separation may be economically viable. Therefore, calculations have been completed for all stable isotopes for all elements from lithium to polonium. The results of these calculations are used to identify specific isotopes and elements that are most likely to be offensive as well as those most likely to be acceptable in terms of their S and E characteristics.

Energy Technology Data Exchange (ETDEWEB)

Elastic and inelastic proton scattering has been measured in inverse kinematics on the unstable nucleus {sup 40}S. A phenomenological DWBA analysis yields a quadrupole deformation parameter {beta}{sub 2} = 0.35 {+-} 0.05 for the 2{sup +}{sub 1} state. Consistent phenomenological and microscopic proton scattering analyses have been applied to all even-even Sulfur isotopes from A = 32 to A = 40. The microscopic analysis used microscopic collective model densities and a modified Jeukenne-Lejeune-Mahaux effective interaction. This analysis suggests the presence of a neutron skin in the heavy sulfur isotopes. The analysis is consistent with normalization values for {lambda}{sub {upsilon}} and {lambda}{sub {omega}} of 0.95 for both the real and imaginary parts of the JLM potential. (author)

Energy Technology Data Exchange (ETDEWEB)

The known biological functions of RNA have expanded in recent years and now include gene regulation, maintenance of sub-cellular structure, and catalysis, in addition to propagation of genetic information. As for proteins, RNA function is tightly correlated with structure. Unlike proteins, structural information for larger, biologically functional RNAs is relatively limited. NMR signal degeneracy, relaxation problems, and a paucity of long-range {sup 1}H-{sup 1}H dipolar contacts have limited the utility of traditional NMR approaches. Selective isotope labeling, including nucleotide-specific and segmental labeling strategies, may provide the best opportunities for obtaining structural information by NMR. Here we review methods that have been developed for preparing and purifying isotopically labeled RNAs, as well as NMR strategies that have been employed for signal assignment and structure determination.

International Nuclear Information System (INIS)

Studies on the kinetics of the distribution of lead-203 in body fluids have been carried out in vitro, and in animal studies using beagle dogs. In vitro, the distribution of carrier free lead-203 between plasma and cells of canine blood at 37"0C was measured after the addition of isotope. In animal studies, activity in plasma was measured for about 150 hours, and activity in blood cells, urine and feces measured for about 400 hours after exposure to lead-203. Linear compartmental models for distribution of the isotope are presented for both in vitro and in vivo experimental systems. The models contain compartments for both untransformed lead, for isotope added in saline or citric acid, and transformed lead, as obtained by lead-203 incubation in plasma.

British Library Electronic Table of Contents (United Kingdom)

The Early Bronze Age barrows at Irthlingborough and Gayhurst in central England are notable for the large number of cattle (Bos taurus) remains associated with their human Beaker burials. Previous work using strontium isotope analysis has indicated that most of the cattle analysed, and one aurochs (Bos primigenius), were of local origin [Towers, J., Montgomery, J., Evans, J., Jay, M., Parker Pearson, M., 2010. An investigation of the origins of cattle and aurochs deposited in the Early Bronze Age barrows at Gayhurst and Irthlingborough. Journal of Archaeological Science 37, 508-515.]. In this study, stable isotope analysis of enamel and bone was carried out to investigate whether the mature cattle had experienced similar husbandry practices, climate and environment. Bulk carbon, nitrogen a...

Science.gov (United States)

We have obtained convincing evidence for localization of the optical electron on a single-ring fragment of a chelated bipyridine-like'' ligand (ie., pyridylpyrazine or 4-Methyl-bipyridine). In addition we have completed studies of Ru(bipyrazine){sub 3}{sup 2+} in aqueous sulfuric acid (0--98% by weight) and find clear evidence for sequential addition of six-protons to the six peripheral nitrogen atoms. Studies of zeolite-entrapped complexes are continuing and a series of homo- and heteroleptic complexes have been prepared and characterized. Finally, the synthesis of zeolite-entrapped metallophthalocyanines has now been developed and the copper and cobalt analogues synthesized. The characterization of these materials is now in progress.

British Library Electronic Table of Contents (United Kingdom)

Many important advances in the physics of strongly correlated electron systems have been driven by the development of new materials: for instance the filled skutterudites Formula Not Shown ( Formula Not Shown metal, alkaline earth, lanthanide, or actinide; Formula Not Shown , Ru, or Os; Formula Not Shown , As, or Sb), certain lanthanide and actinide intermetallic compounds such as Formula Not Shown and Formula Not Shown ( Formula Not Shown , Rh, or Ir), and layered oxypnictides and related materials. These types of complex multinary d- and f-electron compounds have proven to be a vast reservoir of novel strongly correlated electron ground states and phenomena. In these materials, the occurrence of such a wide range of ground states and phenomena arises from a delicate interplay between com...

British Library Electronic Table of Contents (United Kingdom)

Luminescent transition metal complexes are enjoying a growing interest because of their ubiquitous applications in, e.g., the fields of material science, sensors and (biomedical) diagnostics, and iridium(III) and ruthenium(II) complexes are among the best studied. Due to their long-living excited states, these complexes can have a strong interaction with dioxygen, resulting in luminescence quenching. This oxygen quenching might be regarded as an unwanted effect in luminescence imaging, but, on the other hand, it can be exploited for diagnostic and therapeutic applications as well. After a theoretical introduction concerning the dioxygen quenching mechanism and the parameters involved, in the second part of this review we focus on the possibility of tailoring this quenching by modifying sel...

Energy Technology Data Exchange (ETDEWEB)

The experimental study of the proton-rich nuclei close to the N=Z line is a constant challenge for nuclear spectroscopy, mainly due to the difficulty to produce them with the currently available beam/target combinations. Significant advances on this direction were obtained from experiments performed with the GASP array during the last two years: the yrast line of {sup 84}Mo was extended up to 10{sup +}, {sup 88}Ru observed for the first time, and the N=Z+1 line was mapped from {sup 81}Zr to {sup 95}Ag. These new results allow us to have a more complete image of the transition from the well-deformed shell closure at N,Z=40 to the spherical-shell closure at N,Z=50, and highlights some particular effects that can be observed only in the vicinity of the N=Z line. (orig.)

International Nuclear Information System (INIS)

The ability of a local strain of grape phylloxera to develop and reproduce on irradiated in vitro cultured rootstocks (Ru140, R99 and 3309C and one local variety 'Helwani' was determined. The results showed that there was great variation in developmental time and reproduction of phylloxera between irradiated and unirradiated in vitro cultured plants. Survival, number of eggs and mean developmental time were greatly reduced when phylloxera was reared on irradiated rootstocks. Based on the examined biological parameters of phylloxera, all tested rootstocks would be more resistant toward such destructive insect when they were irradiated. Thus, phylloxera resistance was enhanced when in vitro cultured plants were treated with low doses of gamma irradiation. (author)

Science.gov (United States)

... M. Taylor, T. Kurt Kyser. (2009) Feather isotope analysis discriminates age-classes of Western, Least, and Semipalmated sandpipers when plumage ... ...

International Nuclear Information System (INIS)

Using nitrogen-13 initial measurements have been made of rumen ammonia-nitrogen pool size and turnover, and rate of incorporation of ammonia into microbial protein. It is also feasible to measure the rate of incorporation of absorbed ammonia into urea and the appearance of label in saliva.

UK PubMed Central (United Kingdom)

A fast and sensitive LC-ESI-MS method is described for the comparative quantification of 16 estrogen metabolites based on the derivatization of estrogens with a novel derivatizing reagent, N-methyl-nicotinic...Full Text Available

UK PubMed Central (United Kingdom)

In vivo short-term effects of recombinant human TNF-alpha on lipolysis, FFA flux, fat oxidation, triglyceride-fatty acid cycling, and glucose kinetics were evaluated with stable isotopic tracers and...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Optical Isotope shift measurements have been performed for the {sup 240f,242f}Am fission isomers to test the stability of nuclear deformation as function of the neutron number. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with fission detection of the ionization process. The {sup 240f,242f}Am fission isomers have been produced by {sup 242}Pu(p, 3n), {sup 242}Pu(d, 2n) reactions, respectively. Relative isotope shift ratios X{sub exp}{sup 242f}(500 nm)=IS{sup 242f,241}/IS{sup 243,241}=41.4(8) and X{sub exp}{sup 240f}(500 nm)=IS{sup 240f,241}/IS{sup 243,241}=39.2(8) were measured. From these ratios a small difference {delta}{beta}{sub 2}{sup 242f,240f}=0.0076(14) of the deformation parameter {beta}{sub 2} can be deduced assuming that the isotope shift between the reference isotopes {sup 241,243}Am is caused by a pure volume change. (orig.)

International Nuclear Information System (INIS)

Laser spectroscopy measurements have been performed on neutron deficient iridium isotopes. The hyperfine structure and isotope shift of the optical Ir I transition 5d"76s"2"4F_9_/_2 "#-># 5d"76s6p "6F_1_1_/_2 at 351.5 nm have been studied for the "1"8"2"-"1"8"9Ir, "1"8"6Ir"1m and "1"9"1","1"9"3Ir isotopes. The nuclear magnetic and quadrupole moments were obtained from the HFS measurements and the changes of the mean square charge radii from the IS measurements. A large mean square charge radius change between "1"8"7Ir and "1"8"6Ir and between "1"8"6Ir"1m and "1"8"6Ir"1g has been observed.

Energy Technology Data Exchange (ETDEWEB)

Uranium enrichment by gas centrifugation relies on the pressure diffusion of the isotopes when their gaseous mixture is submitted to the pressure diffusion in the strong radial pressure gradient due to the centrifugal force in a very rapidly rotating cylinder. To compute the isotope separation in a gas centrifuge, the viscous compressible Navier-Stokes equations are solved for the mixture, then the diffusion equations are solved for the isotopes. As far as the separation performance is concerned, the models deal with the steady state of the axi-symmetric gas motion in the rotating cylinder. The numerical tools are briefly presented: first, the MOLINA code which numerically solves the axi-symmetric gas motion in the specific conditions of rapid rotation by use of a change of variables suited to the high density gradient and by use of a Marker And Cell method; then, the diffusion equations solver which uses a Finite Volume ...

Energy Technology Data Exchange (ETDEWEB)

A method for quick, high-accuracy measurement of lithium isotopes has become necessary in carrying out research on the separation and concentration of lithium isotopes by ion exchange. The present report focuses on the application of a hollow cathode, as excitation source, to emission spectral analysis for lithium isotope measurement. The grating monochromator used incorporates a pressure scanned etalon. With decreased Doppler broadening and pressure broadening, the hollow cathode, used as excitation source, can give narrow spectral lines, permitting good separation among them. To achieve a high accuracy, the emission intensity of the hollow cathode should be maintained as stable as possible relative to time. In particular, the stability of a light source can be affected significantly by the chemical form of the sample. A study is also made here to identify a condition where lithium acetate effluent as-obtained from an ion ...