A classic sum rule by Das et al. is extended to seven of the low-energy constant K{sub i}, introduced by Urech, which parameterizes electromagnetic corrections at chiral order O(e{sup 2}p{sup 2}). Using the spurion formalism, a simple convolution representation is shown to hold and the structure in terms of the chiral renormalization scale, QCD renormalization scale and the QED gauge parameter is displayed. The role of the resonances is studied as providing rational interpolants to relevant QCD n-point functions in the Euclidean domain. A variety of asymptotic constraints must be implemented which have phenomenological consequences. A current assumption concerning the dominance of the lowest-lying resonances is shown clearly to fail in some cases. (author)
The corrosion behavior of steel in water from certain oil fields with various organic inhibitors was studied by applying potentiodynamic technique at pH 5.9. The inhibitors which were used include 2-methylbenzimidazole (I), 2-mercaptobenzimidazole (II), 2-mercapto-5-methylbenzimidazole (III), and 2-mercaptothiazole (IV). The inhibiting efficiency of the different additives was evaluated from their anodic and cathodic polarization curves at different temperatures. A comparative study of curve fitting procedures using the kinetic thermodynamic model and those utilizing well-known adsorption isotherms was undertaken. Three types of isotherms were used, Langmuir, Frumkin and Flory-Huggins isotherm. The results show that the kinetic-thermodynamic model and Flory-Huggins isotherms are more suitable to fit the data for the four inhibitors, at all applied temperatures. From the values of binding constants, K, the order of inhibitor efficiency is: III > IV > ...
The analyses were carried out using real climate data for the years 1987 and 1989. The course of the indoor climate for year-round free ventilation with a constant flow volume is discussed. Numerous diagrams inform on ambient temperature, water vapour content, the condition of space air, and temperature drops below dew point. For the event of heating of the central part of the church, space air condition, the annual air humidification requirement, and the temperature field in this part of the building are described. (MSK) [Deutsch] Die Untersuchungen wurden mit aktuellen Klimadaten fuer die Jahre 1987 und 1989 durchgefuehrt. Der Verlauf des Raumklimas bei ganzjaehrig freier Klimatisierung mit konstantem Foerderstrom wird erlaeutert. Dabei wird die Raumlufttemperatur, der Wasserdampfgehalt, der Raumluftzustand sowie die Taupunktunterschreitung in zahlreichen Diagrammen aufgezeigt. Weiter werden fuer den Fall der Beheizung des Hauptraums der Kirche der ...
The high-speed direct-injection diesel engine for passenger cars has been a resounding success in the marketplace in the last few years. This was due to an intensive development process as a result of which the direct-injection diesel engine for passenger cars is currently setting new standards with regard to performance and fuel consumption in spite of the constant tightening of emission regulations. Of particular importance in this context is exhaust gas recirculation (EGR). This technology permits a considerable reduction in nitrogen oxide emissions, which are especially critical in the case of the direct-injection diesel engine. In addition, continuing development of supercharging technology, in particular the turbocharger with variable turbine geometry, have allowed further improvement of the full-load behaviour and the engine response and a considerable reduction in the fuel consumption of direct-injection diesel engines. This FVV paper deals with the ...
The Dynamic Analog Scale (DAS) is introduced as a technique for generating single-item measures of personality traits. The DAS is comprised of extensive trait definitions and an analog scale on which respondents simultaneously rate themselves and others. In two studies the Big Five personality traits were assessed with the DAS and compared to a multiple-item questionnaire that measured the same traits. Statistical analysis supported the validity of the DAS for predicting self-reported behavioral acts, drinking behaviors, affect, and religiosity in ways similar to the multiple-item questionnaire. Consistent with previous research, both studies supported the viability of measuring personality traits with single items.
Based on QCD conformal partial wave expansion to leading order conformal spin accuracy, we present the light-cone distribution amplitudes (DAs) of {sigma} and {lambda} baryons up to twist 6. It is concluded that fourteen independent DAs are needed to describe the valence three-quark states of the baryons at small transverse separations. The nonperturbative parameters relevant to the DAs are determined within the framework of QCD sum rule method. With the obtained DAs, a simple investigation on the electromagnetic form factors of these baryons are given. The magnetic moments of the baryons are estimated by fitting the magnetic form factor with the dipole formula.
Two spreading experiments were performed at the FARO facility with prototypical core melts of a UO{sub 2}/ZrO{sub 2} weight percentage of 80/20. The objective was to obtain data on the spreading at flow rates of about 2 l/s of more than 100 kg prototypic high temperature oxide melt on a dry and wet stainless steel plate. For the second spreading test a shallow water layer of 10 mm was added on the substrate. Solutions for an isothermal spreading with a constant volume flux boundary condition in a sector with an angle {phi} are used to analyse the FARO L-32S experiment and to identify the source of discrepancies between the code results (THEMA, CORFLOW) and the experimental findings. The observed spreading behaviour of both FARO experiments can only be explained if an initial melt temperature below the liquidus temperature, i.e. about 120 K lower than the temperature measured by the UTS sensors is assumed. (orig.) [German] Zwei Ausbreitungsexperimente mit einer ...
56 patients with the clinical diagnosis of sprained ankles were investigated. Evaluation of the anterior (AFTL) and posterior fibulotalar ligament (PFTL) was performed with the foot in dorsiflexion (20 ) and of the fibulo calcanear ligament (FCL) in plantarflexion (45 ). Axial T{sub 1}w-SE and T{sub 2}w-TSE images were obtained. Full-length visualisation of ligmaments in one slice and the extent of injury were evaluated. 12 ankle injuries were confirmed by operation. With MRI full-length visualisation of lateral ankle ligaments was possible in 86%. A partial/complete rupture of the AFTL was noticed in 33/64% and of the FCI in 29/39%, and of the PFTL in 27/5%. Sensitivity/specificity of MRI when compared to surgery was 100/100% for injuries of the AFTL, 64/100% for the FCL, and 33/78% for the PFTL. (orig./MG) [Deutsch] 56 Patienten wurden mit der klinischen Diagnose einer frischen Supinationsverletzung des oberen Sprunggelenkes untersucht. Das Lig. talofibulare ...
We report for the first time about a micromachined mass flow sensor directly integrated between the double guidance and the needle seat into the body of a Common Rail (CR) injection nozzle. The thermal measurement principle was chosen because gaseous as well as liquid mass flows can be determined fast and precisely. Additionally, with glass-ceramic materials fabricated in a low cost batch process, a high temperature and especially pressure stable substrate can be used. The flow sensitive thin film is realized by an e-beam evaporated 110 nm thick molybdenum (Mo) layer. The latter is electrically characterized by the resistivity of {rho} = 8.2 x 10{sup -7} {omega} m ({+-}2%) at room temperature as well as by the first {alpha}=4.5 x 10{sup -4} K{sup -1} ({+-}5%) and second {beta}=3.0 x 10{sup -6} K{sup -2} ({+-}12%) temperature coefficients of resistance up to 300 C. The static temperature field at and around the thin film sensor on the glass-ceramic substrate is investigated with an IR ...
Normally, the alloy NiMo28 is used in the solution annealed and quenched condition in which it has a face centred cubic matrix structure. The matrix of the material is supersaturated with molybdenum and, at temperatures above 800 C, has a tendency to form intermetallic precipitates such as the Ni{sub 4}Mo-ordered phase leading to the embrittlement of the NiMo28-ordered phase leading to the embrittlement of the NiMo28 alloy during hot working. For this reason, the aim of these investigations was to optimise the alloy by reducing its tendency to embrittle. The TEM-analyses carried out served to investigate the precipitation of the material as a function of its iron content after ageing at 700 C. The change in hardness and in the lattice constants of the NiMo28-specimens with iron content were also determined. To improve the hot working properties of this material it is recommended that the iron content be kept to about 3.2 mass % in order to reduce the tendency of ...
A singular stress field can occur at the edge of the joint plane in a thermally or mechanically loaded material compound. This stress field was calculated analytically and was compared with the results from the finite element method. If one of the two partners consists of ceramic material, unstable crack spread starting from faults in this strongly stressed area can lead to failure. In linear elastic material, the behaviour of a crack is clearly described by the stress intensity factors. These can be calculated for a known stress distribution in the uncracked structure by the method of the weight function. The corresponding weight functions for surface cracks parallel to the boundary surface were determined with the aid of suitable reference load cases. The effect of the position of the crack in the compound and the elastic constants of the compound are discussed. For examples, the stress intensity factors for cracks in a thermally stressed material compound were ...
Magnetic pulse welding, a cold solid state bonding process, is becoming a viable replacement for conventional fusion welding processes and explosive welding. The process is presented here along with its fundamental equations and applications of similar and dissimilar welds are illustrated along with typical interface microstructures. (orig.) [German] Magnetimpuls-schweissen, ein Verbindungsverfahren im kalten Festzustand, wird ein funktionsfaehiger Ersatz fuer das herkoemmliche Schmelzschweissverfahren und das Explosionsschweissverfahren. Das Verfahren wird hier mit seinen grundlegenden Gleichungen vorgestellt, und Anwendungen von aehnlichen und unaehnlichen Schweissungen werden mit typischen Schnittstellen-Mikrostrukturen veranschaulicht. (orig.)
Portuguese ... Orig. Title Isolamento e identificacao do flavonoide (-)-4'-metil-epigalocatequina das raizes de Maytenus obtusifolia Mart. (Celastraceae)
The use of WPC as an important insulating material is studied by determining its dielectric constant. The variation of dielectric constant with moisture content is also investigated. Preliminary results show that all untreated woods studied have a higher dielectric constant than their polymer composites with the exception of Kapur and Keruing. It is therefore postulated that the presence of polymers has led to a decrease in the number of polarizable units. Such a material may be useful commercially.
The use of WPC as an important insulating material is studied by determining its dielectric constant. The variation of dielectric constant with moisture content is also investigated. Preliminary results show that all untreated woods studied have a higher dielectric constant than their polymer composites with the exception of Kapur and Keruing. It is therefore postulated that the presence of polymers has led to a decrease in the number of polarizable units. Such a material may be useful commercially. (author).
One hope to solve the cosmological constant problem is to identify a symmetry principle, based on which the cosmological constant can be reduced either to zero, or to a tiny value. Here, we note that requiring that the vacuum state is Lorentz invariant significantly reduces the theoretical value of the vacuum energy density. Hence, this also reduces the discrepancy between the observed value of the cosmological constant and its theoretical expectation, down from 123 orders of magnitude to 56 orders of magnitude. We find that, at one loop level, massless particles do not yield any contribution to the cosmological constant. Another important consequence of Lorentz symmetry is stabilization of the gravitational hierarchy: the cosmological constant (divided by Newton's constant) does not run as the quartic power of the renormalization group scale, but instead only ...
Borehole stability is affected to a significant extent by the 3D local and regional stress field. Preliminary information on underground stress fields is provided by the World Stress Map, which shows N-NW stress at a depth of about 5000 m for the Voelkersen field. Earlier data analyses showed various directions in the range of 310-360 degrees. This was assumed to be a methodical error. An extensive study was carried out to evaluate and interpret all relevant information provided by borehole tests, borehole logs, and drill core measurements. [German] Standsicherheit und Stabilitaet von Bohrungen werden ganz wesentliche beeinflusst durch das umgebende dreidimensionale lokale und regionale Spannungsfeld. Fuer die Planung zukuenftiger (horizontaler) Bohrungen und die Erzeugung kuenstlicher Risse (''fracs'') spielt das Spannungsfeld eine bedeutende Rolle. Erste Hinweise ueber das regionale ...
A high-temperature flow reactor and different technical plants were tested within the framework of this research project. Anthropogenic N{sub 2}O emissions form during secondary flue gas or waste gas purification as secondary emissions during denitrification and pollution abatement measures. N{sub 2}O forms as an intermediate product as NO is reduced to N{sub 2}. Under certain operating conditions N{sub 2}O is not decomposed completely. Different secondary flue gas purification measures, i.e. selective noncatalytic reduction (SNCR), selective catalytic reduction (SCR), and nonselective catalytic reduction (NSCR) were investigated testing several technical plants and the high-temperature flow reactor. (orig./EF) [Deutsch] Das Forschungsprojekt ``Messung der N{sub 2}O-Emissionen von Verbrennungsanlagen und Untersuchung von Moeglichkeiten zur Emissionsminderung`` wurde an einem Hochtemperatur-Stroemungsreaktor und an verschiedenen technischen Anlagen durchgefuehrt. ...
Using a quasi-static approach valid for Stefan numbers less than one, we derive approximate equations governing the movement of a phase change front for materials which generate internal heat. These models are applied for both constant surface temperature and constant surface heat flux boundary conditions, in cylindrical, spherical, plane wall and semi-infinite geometries. Exact solutions with the constant surface temperature condition are obtained for the steady-state solidification thickness using the cylinder, sphere, and plane wall geometries which show that the thickness depends on the inverse square root of the internal heat generation. Under constant surface heat flux conditions, closed form equations can be obtained for the three geometries. In the case of the semi-infinite wall, we show that for constant temperature and constant heat flux out of the ...
The current discussion on worldwide climate change suggests that the current situation is unusual or extreme, and that climate changes never - or hardly ever - occurred in the centuries before. The author discusses whether this is really the case, and whether air pollution abatement measures can really help. His answers are based on the findings of palaeoclimatology. [German] Verfolgt man die Diskussion um den derzeitigen Klimawandel, so gewinnt man den Eindruck, Aussergewoehnliches und Extremes wuerde geschehen, und man bekommt zudem ueber Beratungsgremien und Medien vermittelt, dass sich in den Jahrhunderten vor dem heutigen Klimawandel das Klima nicht oder nur wenig geaendert hat. Es wird auch der Eindruck erweckt, man koenne das Klima stabilisieren und durch Emissionsminderungsmassnahmen das Klima schuetzen. Ist Klimaschutz eine loesbare Herausforderung oder ueberschaetzen wir Menschen unsere Moeglichkeiten? Man kann ...
We develop a general framework for the formulation of the action principle and the noether theorem for classical noncommutative field theories. We give a concrete example of an algebra that fits into this framework. It describes a scalar field theory on noncommutative minkowski space. We develop a notion of locality for this algebra and investigate the locality properties of localised interaction terms. This leads us to the definition of local functionals on the field algebra. We propose a scheme for the quantisation of these functionals. (orig.) [German] Wir entwickeln eine allgemeinen rahmen, der es erlaubt, das wirkungsprinzip und das noether-theorem fuer klassische nichtkommutative feldtheorien zu formulieren. Als ein konkretes beispiel betrachten wir eine algebra, die sich in diesem rahmen einfuegt, und die eine skalare feldtheorie auf dem nichtkommutativen minkowski-raum beschreibt. Fuer diese algebra wird ein lokalitaetsbegriff ...
Abstract in english We present a detailed derivation of the effective dielectric constant to be used in the dispersion relation for electrostatic waves in the case of a plasma immersed in a inhomogeneous magnetic field, with inhomogeneity perpendicular to the direction of the magnetic field.
... Fluctuating Incubation Temperatures in the Multi-banded Krait, Bungarus multicintus (Elapidae)Xiang Ji1,2,*, Jian-Fang Gao1, ... rather than applying constant-temperature regimes. We incubated Bungarus mu...
The rate constants for both acylation and deacylation of beta-lactamase PC1 from Staphylococcus aureus and the RTEM beta-lactamase from Escherichia coli were determined by the acid-quench method [Martin...Full Text Available
Faserbewehrter Beton wird heute zunehmend auch bei Tunnelbauwerken (Tunnelinnenschalen, Tubbinge) eingesetzt. Wesentliche Vorteile sind das hohe Tragvermogen, das daraus entstehende Einsparungspotential an herkommlicher stabformiger Bewehrung (Biegebewehrung, Bugelbewehrung in der Randzone), die Aufnahme von Spaltzugbeanspruchungen durch die Fasern, Rissbreitenbegrenzung, erhohte Dauerhaftigkeit, verbesserter Brandwiderstand (insbesondere bei Verwendung von Kunststofffasern), Optimierung der Arbeitsablaufe etc. Neue Entwicklungen in der Betontechnologie haben in den letzten Jahrzehnten den faserbewehrten ultrahochfesten Beton (engl. UHPFRC - Ultra High Performance Fibre Reinforced Concrete) hervorgebracht. Im Rahmen dieser Arbeit wird der Einsatz des ultrahochfesten, stahlfaserbewehrten Be...
Initially, the decision of the operator in Dortmund-Derne to select the impact-type separator concept is explained. None of the tenderers for this 52 t/h boiler could supply references for this fluidized bed steam generator concept with staged combustion in a high-expansion fluidized bed. Under the circumstances, the simple configuration of the Steinmueller fluidized bed steam generator, its compact construction, the reduced amount of refractory and the operational behaviour of the boiler resulting therefrom were decisive in the operator`s decision to select this concept. The development schedule shows the individual stages from cold and hot trials in various test rigs and pilot plants to the final design. So far, this fluidized bed steam generator concept has been realized in the plants Derne (52 t/h), commissioned in November 1989, and Brilon (100 t/h), commissioned in November 1990. The discussion on the essential design features points out to the deliberate differences in the two ...
Elektrochemische Potentialmessungen (auch Potentialfeldmessungen) haben sich seit Jahren bewahrt, Bereiche mit aktiver chloridinduzierter Korrosion an tausalzexponierten Bauwerken, wie z. B. Bruckentafeln sowie Zwischendecks und Bodenplatten von Parkhausern und Tiefgaragen nachzuweisen. Bereits 1990 erschien die erste Fassung des Merkblatts B3 der DGZfP. Das DAfStb Heft 422 (1991) - Prufung von Beton Empfehlungen und Hinweise zu DIN 1048 - enthielt die Potentialfeldmessung bzw. das Merkblatt B3 im Anhang. In Deutschland liegen somit zwei Jahrzehnte Erfahrungen mit den entsprechenden Regelwerken und naturlich auch in der praktischen Anwendung vor. In der Praxis zeigte sich jedoch auch, dass die Anwendung verbessert werden muss. Die Potentialmessung wurde vielfach sogar falsch durchgefuhrt, ...
The article describes the solar aircraft `Icare`` which was constucted in a joint project by engineers and scientists of Stuttgart university. The aircraft requires slightly more than one kW for staying up. The theoretical fundamentals are presented in the dissertation of Peer Frank, ``Aircraft design for minimum fuel consumption` (Institute of Aircraft Engineering, Stuttgart, 1992). (orig.) [Deutsch] Allein mit Sonnenkraft kann das Flugzeug `Icare` fliegen. Es entstand in Gemeinschaftsarbeit von Ingenieuren und Wissenschaftlern der Stuttgarter Universitaet. Das Solarflugzeug Icare benoetigt etwas ueber ein Kilowatt, um oben zu bleiben. In seiner Doktorarbeit `Die Auslegung von Flugzeugen mit geringstem Antriebsleistungsbedarf` (Institut fuer Flugzeugbau, Stuttgart, 1992) hat der Duesseldorfer Peer Frank die theoretischen Grundlagen dazu behandelt. (orig.)
Fur die Trennung binarer Gemische wird zunehmend das Simulated Moving Bed (SMB)-Verfahren verwendet. Fur einen storungsfreien Betrieb mussen die Volumenstrome sowie die Umschaltzeit exakt eingestellt werden. In diesem Beitrag wird mit Hilfe des Coherence-Konzepts eine Methode aufgezeigt, mit der sich die Stellgroen fur einen dispersionsfreien SMB-Prozess bestimmen lassen. Fur Langmuir- und Anti-Langmuir-Isotherme konnen einfache explizite Gleichungen bei vollstandiger Trennung angegeben werden. Das Grundprinzip dieser Methode lasst sich auch auf andere Isotherme sowie fur die unvollstandige Trennung ubertragen.
The research project started in April, 2008 before adoption of the cabinet report of the Federal Government to the German strategy for Adaptation to Climate Change. The German Strategy for Adaptation emphasizes the meaning of information about requirements for adaptation and the active involvement of all social groups in the other process of the strategy. For this the research project has made concrete proposals for the information, communication and participation of social groups. These proposals are based in the essentials on an interest analysis about interviews with stakeholders and the economy to their demands and expectations to the German strategy for Adaptation. Besides we have researched international examples for the adaptation to the climate change for the public relations. For the interactive development of the Internet platform www.anpassung.net concrete proposals were developed. (orig.)
The stability constant values of Pa(V) with some complexing ligands (chloride, sulfate and oxalate) are graphically determined using solvent extraction data. The organic phase was at constant composition of HTTA in benzene while the aqueous phase was held at constant hydrogen ion concentration and ionic strength of 3. The curve-fitting method was adopted throughout this investigation, giving the following values. The stability constants obtained are used to calculate the distribution of the different Pa (V) species in the corresponding aqueous phase (expressed in mole fraction) as a function of ligand ion concentration.
The pM{sup '}-pC{sub H} diagrams allowed to determine the saturation and non-saturation zones of Lu(OH){sub 3} in solid phase and those were applied for determining the hydrolysis and lutetium solubility constants, using the radioactive isotope Lu-177. The first constant of hydrolysis was also determined by the potentiometric method in absence of solid phase. (Author)
Symplectic integrators designed for simulating soft matter at constant temperature and constant pressure (or constant surface tension) are presented. In addition to the well-known merits of symplectic integrators, such as long time stability, these methods allow the estimation of thermal heat production/absorption and thus entropy differences through a simple function of the time scaling factor ?. The relative entropy estimation around crystal-liquid phase transition is given for systems with soft core repulsive potential.
In this work, the thermodynamic behaviour of single-stage horizontal spray coolers with one or more spray levels is experimentally examined. Further, a spray cooler calculation model was developed, in order to describe the processes and to make a comparison of the results of calculation and measurement. The state of the mine climate and the cold water are taken as the thermodynamic reference. (orig.).
The ERICAM model (Environmental Risk Internalization through Capital Markets) includes the capital markets as a source contributing to the coverage of risks due to nuclear activites, thus enhancing the effectiveness and functions of the nuclear liability law. The model proposed will allow higher amounts for compensation and will increase financial security, flow of information, and efficient use of resources. The implementation of the model can be achieved on the financing side by issuing Nuke bonds, linking accident-specific options to government bonds. This will essentially increase the risk coverage compared to present means, and will be a pin-pointed addition to the existing layer system. There are three institutions proposed to act as mediators in the implementation of the model: A government authority to supervise the trade in Nuke bonds. Risk-bearing associations in oder to enhance the model`s efficiency, and to reduce transaction costs. Rating agencies that will reduce the ...
The staff of the Southwest Technology Development Institute (SWTDI), in conjunction with the staff of Industrial Solar Technology (IST), have analyzed the performance, operation, and maintenance of a large solar process heat system in use at the 5,000 inmate California Correctional Institution (CCI) in Tehachapi, CA. This report summarizes the key design features of the solar plant, its construction and maintenance histories through the end of 1991, and the performance data collected at the plant by a dedicated on-site data acquisition system (DAS).
Zusammenfassung Der vom Bundesamt f?r Sicherheit in der Informationstechnik (BSI) entwickelte Ansatz des IT-Grundschutzes war bereits Gegenstand von Beitr?gen in der DuD. Inzwischen hat das ?Grundschutzhandbuch? Eingang in die internationale Standard-Familie ISO 2700x gefunden. Der Autor berichtet ?ber die Erfahrungen mit den ersten durchgef?hrten Zertifizierungen nach dem neuen ISO-Standard auf der Basis von IT-Grundschutz.
Abstract Der folgende Artikel setzt die Reihe unserer ChiuZ-Beitrge zur Chemi- und Biolumineszenz mit einer interessanten und neuen experimentellen Arbeit zum -kalten Licht- spezieller ungesttigter Verbindungen fort, deren Anwendung auch in der modernen Zeit der Nanotechnologie im biochemischen bzw. medizinisch-chemischen Labor vllig neue Akzente gesetzt hat.
This work shows the influence of the consumer density (density/km) in rural electric networks implementation costs. The analysis of the costs aims the criteria definition for the calculation of the financial involving rates of the rural consumer density. 3 figs., 10 tabs.
A prospective study was performed on 50 patients suffering from osteochondritis dissecans of the knee and ankle to define criteria for stability and fixation of osteochondral lesions. Morphological parameters in MRI (size, fragmentation, cartilage, interface) and conventional radiology (separation, fragmentation) were registered and compared with arthroscopical staging. MRI staging based on different types of interfaces was demonstrated on T{sub 1}- and T{sub 2}-weighted images. MRI could correctly predict a Grade 1 lesion in 50%, a Grade 2 lesion in 90%, a Grade 3 lesion on 0%, and a Grade 4 lesion in 79%. Stable lesions were differentiated from unstable lesions in 90%. Radiographic findings corresponded with arthroscopic staging in only 56% of the cases because fibrotic connection may guarantee stability in case of bony separation. (orig./MG) [Deutsch] In einer prospektiven Studie an 50 Patienten mit einer Osteochondrosis dissecans (OD) des Knie- und Sprunggelenkes sollten ...
Myocardial time-activity curves can be described by two or more parameters. To establish the optimal curve fitting method 33 myocardial time-activity curves were analyzed with different curve fitting methods: monoexponential, biexponential and monoexponential plus constant. A background correction was not applied. Biexponential curve fitting resulted in redundancy of parameters. Optimal curve fitting was obtained with monoexponential plus constant. The constant represents the background activity together with the stores radiolabelled lipids and the half-time value represents the wash-out of radioiodide from the myocardium. A strong relation was found between the constant and the half-time value: small errors in the determination of the constant (background activity) resulted in considerable errors of the half-time value. It is concluded that optimal analysis of a myocardial ...
There are several equivalent descriptions for constant B-field background of open string. The background can be interpreted as constant B-field as well as constant gauge field strength or infinitely many D-branes with non-commuting Chan-Paton matrices. In this article, the equivalence of these open string theories is studied in Witten's cubic open string field theory. Through the map between these equivalent descriptions, both algebra of non-commutative coordinates as well as Chan-Paton matrix algebra are identified with subalgebras of open string field algebra. (author)
The constants, applied in the phenomenological approaches for describing the nuclear reactions with the high transmitted pulse, are obtained within the frames of the multiquark flucton microscopic model. The constants values prove to be universal for all the nuclei and independent on the collision energy and flucton properties (excluding its mass), i.e. the peculiar scaling is manifested in the reaction cross sections. The theoretically obtained values of these constants are in good agreement with the phenomenological values, derived from the (p, p'X) reaction cross sections on the nuclei for X=d, t, "3He
The effect of variations of the fundamental constants on the thermonuclear rate of the triple alpha reaction, "4He(#alpha##alpha#, #gamma#)"1"2C, that bridges the gap between "4He and "1"2C is investigated. We have followed the evolution of 15 and 60 M#centre dot# zero metallicity stellar models, up to the end of core helium burning. They are assumed to be representative of the first (Population III) stars. The calculated oxygen carbon abundances resulting from helium burning can then be used to constrain the variation of the fundamental constants.
We examine the late-time behavior of initially expanding homogeneous cosmological models satisfying Einstein's equation with a positive cosmological constant ..lambda... It is shown that such models of all Bianchi types except IX exponentially evolve toward the de Sitter solution, with time scale (3/..lambda..)/sup 1/2/. The behavior of Bianchi type-IX universes is similar, provided that ..lambda.. is sufficiently large compared with spatial-curvature terms. Thus, a positive cosmological constant provides an effective means of isotropizing homogeneous universes.
We examine the late-time behavior of initially expanding homogeneous cosmological models satisfying Einstein's equation with a positive cosmological constant #LAMBDA#. It is shown that such models of all Bianchi types except IX exponentially evolve toward the de Sitter solution, with time scale (3/#LAMBDA#)/sup 1/2/. The behavior of Bianchi type-IX universes is similar, provided that #LAMBDA# is sufficiently large compared with spatial-curvature terms. Thus, a positive cosmological constant provides an effective means of isotropizing homogeneous universes.
Diffusion of radon in a bed of activated charcoal is described by diffusion equations. An analytical solution of these equations is presented for the case of constant radon concentration in the atmosphere. The solutions are given separately for short term and long term exposure. An analytical form of the calibration constant f for long term exposure and constant radon concentration in air, was found. A numerical method and computer code based on the method of finite elements is developed for the case of variable radon concentration in air. This program simulates radon adsorption by the activated charcoal bed, enabling determination of sensitivity. The dependence of sensitivity on different parameters, such as temperature, thickness of the charcoal, etc. was studied using this program. (orig.) 10 refs.
A study was made of the kinetics of L-(/sup 3/H)quinuclidinyl benzilate binding with membrane-bound muscarine cholinoreceptors from the rat brain. Determination was made of the rate constants of this process, and constants as a function of ligand concentration was investigated, indicating that there is a complex mechanism of interaction of antagonists with muscarine receptor. With up to 3.5 nM concentrations of L-(/sup 3/H)quinuclidinyl benzilate, the binding reaction occurs in two stages: rapid equilibrated binding is followed by a slow process of conformational isomerization of the receptor-ligand complex. At higher ligand concentrations, there is additional drastic increase in constant of rate of ligand binding a new plateau is reached. Such dependence of rate constant on ligand concentration is indicative of the cooperative nature of interaction between antagonists and muscarine receptors. This is ...
where I was in El Paso, I could always look up and see the smokestacks of the old Asarco smelter looming. The facility affected the city in more ways than that constant visual...
where I was in El Paso, I could always look up and see the smokestacks of the old Asarco smelter looming. The facility affected the city in more ways than that constant visual...
Sep 1, 2011 ... We find that since 2003, recent mining deforestation in Madre de Dios, Peru is increasing nonlinearly alongside a constant annual rate of ...
Experience with the identification and tuning of exciter constants for a generating unit as the Second Nuclear Power Plant of Taiwan Power Company is reported. Field test is first performed on the excitation system with the generator open-circuited. Since the field test results differ from the computer simulation results using manufacturer`s constants, the authors first modify the manufacturer`s constants based on their previous experience to reach a preliminary set of parameters for the excitation system. Then a hybrid nonlinear simulation-sensitivity matrix method is developed to further refine the excitation system parameters. The exciter constants are tuned in order to give better dynamic response before a power system stabilizer is applied to the generator. Field tests are then performed in order to compare the dynamic response of the generator without and with power system stabilizer.
Experience with the identification and tuning of exciter constants for a generating unit as the Second Nuclear Power Plant of Taiwan Power Company is reported. Field test is first performed on the excitation system with the generator open-circuited. Since the field test results differ from the computer simulation results using manufacturer's constants, the authors first modify the manufacturer's constants based on their previous experience to reach a preliminary set of parameters for the excitation system. Then a hybrid nonlinear simulation-sensitivity matrix method is developed to further refine the excitation system parameters. The exciter constants are tuned in order to give better dynamic response before a power system stabilizer is applied to the generator. Field tests are then performed in order to compare the dynamic response of the generator without and with power system stabilizer.
The formation constants of species formed in the system H"+"+alanine and VO_"2"+alanine have be determined in aqueous solution for 1.0constants were determined ny curve fitting method and it was shown that di oxovanadium(V) forms two mononuclear 1:1 and 1:2 species with alanine of the type VO_2L and VO_2L_2 The protonation constant of the amino group of alanine has been determined using a computer program which employ a least-squares method. The defence of the protonation of alanine and the stability constant of the species on ionic strength are described by a Debby-huckel type equation.
... 3. Critical constants, and triple point 4. Compressibility isothermE S. Density, molar volume (of a condensed phase) 6. Equations of state, general ...
We briefly discuss the transcendental constants generated through the #epsilon# expansion of generalized hypergeometric functions and their interrelation with the 'sixth root of unity.'
Today electric power steering systems are regularly considered by the car manufacturers as an alternative to a conventional hydraulic power steering system in the development of new vehicle platforms. Simplified vehicle assembly and the potential to contribute to the reduction of the vehicle's energy consumption are the main motivation for this. The performance of the systems available at present with 13.5 V supply voltage will be improved even more as soon as the future 42 V vehicle electrical systems are available. Like most active chassis systems, electric power steering has to meet the highest safety requirements imaginable. This article summarizes the safety philosophy of the TRW rack drive Electric Power Steering system. (orig.) [German] Elektromechanische Servolenkungen werden heute bei der Entwicklung neuer Fahrzeuge als Alternative zur konventionellen hydraulischen Servolenkung in Betracht gezogen. Die vereinfachte Fahrzeugmontage und das ...
In two pilot projects Maingas AG has complemented an existing marketing mix with a telephone marketing segment. One of these telephone marketing campaigns was conducted for the purpose of `Intensification`, the other for `Activation of Unused Mains Connections`. The aim was to provide professional support to canvassing campaigns in their various phases in order to minimise diffusion losses and increase the probability of winning new customers. The slogan chosen for the drive was therefore: `Its no good being present unless one`s efficient in the preparation, execution, and revision of a campaign`. (orig.) [Deutsch] Die Maingas AG hat in zwei Pilotprojekten das bestehende Marketing-Mix durch das Segment Telefonmarketing ergaenzt. Es wurde eine Telefonmarketing-Aktion im Bereich `Verdichtung` und eine Telefonmarketing-Aktion im Bereich `Aktivierung Inaktive Hausanschluesse` durchgefuehrt. Ziel war es, durch einen professionellen flankierenden ...
On February 20th 1998 Auckland, the biggest city of New Zealand, was nearly paralyzed by an extended power failure. On this day the last of four cables supplying the central business district failed and caused a five weeks lasting blackout. This failure has caused costs of 128.3 Mio NZ Dollar for the affected utility Mercury Energy Ltd. The official ministerial inquiry was published on July 21st 1998 and reproaches the utility in an unusual clear manner. (orig.) [Deutsch] Am 20. Februar 1998 wurde Auckland, die groesste Stadt Neuseelands, von einer folgenschweren Unterbrechung der Stromversorgung nahezu lahmgelegt. An diesem Tag fiel das letzte von vier 110-kV-Kabeln zur Versorgung des Innenstadtbereiches aus und verursachte damit einen 5 Wochen dauernden Stromausfall. Diese Versorgungsunterbrechung hat bisher Kosten in Hoehe von 128,3 Mio NZ Dollar (rd. 115,5 Mio DM) fuer den oertlichen Stromversorger Mercury Energy Limited verursacht. Der am 21. Juli 1998 ...
Modern oscillation- and analysis systems are often mentioned in the context of oscillation diagnosis which implies that this is a method of establishing the causes of the mechanical changes that cause the unwanted oscillation. Experience shows, however, that oscillation monitoring instruments can merely indicate oscillation symptoms at an early point in time. These findings must be interpreted in a machine-specific way and seen in the context of previous developments in order to establish the mechanical root cause of the matter. A 1000 MVA-generator shows that conventional oscillation measuring systems may also serve for diagnostic purposes within certain limits.(orig.) [German] Im Zusammenhang mit modernen Schwingungsmess- und Analysensystemen wird haeufig der Begriff der Schwingungsdiagnose verwandt und inpliziert, damit auch die Ursache von mechanischen Veraenderungen finden zu koennen, welche das beanstandete Schwingungsverhalten hervorruft. In der Praxis zeigt ...
The austenitic nitrided Cr-Mn steels CrMnN 1812, CrMnNMo 1714 and CrNiTi 1810 has been investigated in chloride nitric acid at temperature 20-60 C. The Potentials of pitting nucleation and the time for pitting initiation has been determinate by the hronoamperometric method. It was established that alloying only with nitrogen is not sufficient procedure for obtaining of resistive to localised corrosion steel structure. Of importance for the resistance to localised corrosion of Cr-Mn steels is alloying with molybdenum. (orig.) [Deutsch] Die austenitischen stickstoffhaltigen Cr-Mn Staehle CrMnN 1812, CrMnNMo 1714 und der klassische CrNiTi 1810 wurden in chloridhaltigen Salpetersaeureloesungen im Temperaturbereich 20-60 C untersucht. Durch die hronoamperometrische Methode wurden die Potentiale der Lochfrassbildung und die Zeit zur Initiierung der Lochfrasskorrosion bestimmt. Man stellte fest, dass das Legieren der Staehle nur mit Stickstoff eine nicht genuegende ...
The new multi-purpose oxygen cupola furnace is a coke-fired shaft furnace that is operated on pure oxygen. The top gas is recirculated, and the fumes are drawn off at temperatures ranging from 800 to 1 000 C. The furnace offers the possibility of melting down contaminated and zinc-bearing scrap without the occurrence of any environment-polluting gas emissions. The absence of nitrogen ballast permits a high energy efficiency. (orig.) [Deutsch] Der neue Mehrzweck-Sauerstoff-Kupolofen ist ein koksbeheizter Schachtofen, der mit reinem Sauerstoff betrieben wird. Das Gichtgas wird im Kreislauf gefuehrt, und das Abgas wird aus einem Bereich mit Temperaturen von 800 bis 1 000 C abgefuehrt. Der Ofen bietet die Moeglichkeit, verunreinigte und zinkhaltige Schrotte einzuschmelzen, ohne dass umweltbelastende Gasemissionen auftreten. Der fehlende Stickstoffbalast bewirkt einen hohen energetischen Wirkungsgrad. (orig.)
Procedures followed in designing for offshore production rigs in the Northeastern Areas of the Campos Basin are presented. Various advantages afforded by the mast in the performance of required tasks are analyzed, along with all calculation premises and methods for adequate sizing. Standards covering mast design, materials used in manufacture, and test routines are also examined. (author). 16 figs., 3 tabs., 11 refs
There is much interest worldwide in low-emission, low-noise electric cars. Modern vehicles with advanced technology are an interesting alternative to conventional cars. (orig.) [Deutsch] Das Interesse an den emissionsfreien und leisen Elektroautos ist weltweit ungebrochen. Die heute verfuegbaren Fahrzeuge zeigen die betraechtlichen, in den letzten Jahren erzielten Fortschritte, die sie fuer immer mehr Anwender zu einer beliebten Alternative zur Benutzung des konventionellen Autos machen. (orig.)
This publication, with comparisons of laws and empirical-sociological evaluations for solutions, takes into account laws and regulations up to February 1988. Exemplary references to German law are presented, and the interrelationship of certain legislation illustrated by bringing examples of the known legal systems. Every legal norm and every legal institution is investigated with a view to finding out which function it has to fulfil, and whether this is done in an adequate way or whether another norm or another institution could do this better. (HP).
Two hypotheses are in the centre of this investigation, on the one hand the question, whether microwaves as exogenous fields alone are able to stimulate human muscle cells above-threshold, and on the other hand, whether microwaves as conditioning to cathodical electrical pulses can modify the excitation threshold and form. No excitation through the application of microwaves alone can be introduced at any subject. The conditioning of above-threshold cathodical electrical pulses with UMTS-microwaves leads not to a transgression of the threshold or the electrical muscle response (EMG) depending on the amplitude, the duration or the dose rate. (orig.)
Since mid-1995, Audi is the second European producer to offer a direct-injection diesel engine for passenger cars. The 2.0 l engine is installed in the middle-class sedan Rover 620 SDi. (orig.) [Deutsch] Als nach Audi zweiter europaeischer Hersteller bietet Rover seit Mitte dieses Jahres einen Pkw-Dieselmotor mit direkter Einspritzung an. Eingesetzt wird das Aggregat mit 2,0 l Hubraum in der Mittelklasselimousine Rover 620 SDi. (orig.)
Biogas supply to the public gas grid is a new option discussed in the most recent publication of Fachagentur Nachwachsende Rohstoffe (FNR) e.V. The biogas is purified, upgraded to natural gas quality and fed into an existing gas grid. Once there, it can be transported across long distances and also used for electric power generation at the consumer side. The study investigates inhowfar and in what instances this method is feasible and promising. It discusses the technical background and the regional potential of biogas. Seven model biogas systems are presented as examples. (orig.)
In this project the influence of residual compression stresses on the stress corrosion cracking behaviour of the turbine disc steel 26 NiCrMoV 14 5 (Rp(sub 0.2) = 850 N/mm(sup 2)) was investigated. The residual compression stresses were produced by shot p...
To get a better understanding of the condensation oscillation and chugging process during blowdown of a BWR after a LOCA a large number of large scale pressure suppression experiments have been performed in several countries. ECN has performed a detailed analysis of the results of one of these experiments, e.g. the DAS M10 experiment of GKSS. This analysis includes the following aspects: Power Spectral Density (PSD) analysis of the data, analysis of the acoustic frequencies of the downcomers and an analysis of the eigenfrequencies of the downcomers. The results of these analyses and an evaluation are given in this paper. It is shown that all dominant frequencies in the experimental results can be correlated with the vent-acoustic or eigenfrequencies. (orig.).
The basis of assessment for particulate exhaust emissions is the gravimetric analysis of the particle concentration of diluted exhaust gases at temperatures below 52 C. This is very time consuming and takes sufficient sensitivity at low particulate emission rates like downstream of particle filters. For this reason the C/S-method, based on the thermographic analysis of carbon and sulfur, has been developed as an alternative to the gravimetric anallysis. This method yields particle mass as well as the main particle compounds. Comparisons between both methods have been carried out for heavy duty and automobile diesel engines as well as road vehicles and large diesel engines. The tests were conducted with commercial diesel fuel and also with other fuels, such as heavy oils. It could be shown that the C/S-procedure yields the same results as the gravimetric procedure independent of engine, engine mode and kind of fuel. The analysis of all important particulate compounds - elemental carbon ...
When performing trenchless pipe renovation work - whichever process you use - the success of the job depends on the careful removal of all scale, sediments and rust from the innerwall surfaces. The VACUJET process - in which the pipe is cleaned with water at pressures of up to 2 500 bar using a technique jointly developed by Preussag Rohrsanierung GmbH and Fabex GmbH - meets all requirements. The equipment includes a mobile waste water treatment unit which is small enough to fit on a standard trailer. Despite its compact dimensions this plant is so effective that it can treat all the waste water generated during the high pressure cleaning jobs so that it is suitable for reuse in the cleaning process or for release into the sewerage system. (orig.) [Deutsch] Bei der grabenlosen Rohrsanierung, ganz gleich nach welchem Verfahren saniert wird, ist die sorgfaeltige Entfernung von alten Beschichtungen, Ablagerungen und Rost eine wesentliche Voraussetzung fuer den Sanierungserfolg. ...
The ECOTEC combustion system and the architecture of the new Opel 2.2 l aluminum engine have been configured to achieve low noise and exhaust emissions. This power unit, employed in Germany for the first time in the Astra Coupe, already complies with the Euro IV emissions standard. It features minimum maintenance requirements and a long operating life. The DOHC spark-ignition engine with four valves per cylinder has two chain-driven camshafts, valve gear with roller cam followers and hydraulic lash adjusters. Two chain driven balancer shafts have been integrated into the engine block. The cylinder head and block, lower crankcase, oil pan, and cylinder head cover are all made of aluminum. A modular concept makes it possible to adapt the engine effectively to different vehicle concepts and markets. (orig.) [German] Das ECOTEC-Verbrennungssystem und die Motorarchitektur des neuen 2,2-l-Aluminium-Triebwerks von Opel sind auf niedrige Geraeusch- und Abgasemissionen ...
The textbook is primarily intended for radiologic staff and radiologic safety officers and gives information on the current regulatory provisions of the German X-ray Ordinance, applications of X-rays, quality assurance, organisational aspects of film processing and quality requirements of X-rays. An annex lists the guidelines of the Bundesaerztekammer (German National Chamber of Physicians) relating to quality assurance aspects, and further useful information on commercially available film-screen systems, the various associations of physicians in Germany, and requirements and performance of radiation surveys. (vhe) [Deutsch] Das vorliegende Lehrbuch, das sich vor allem an das technische Personal und an Strahlenschutzbeauftragte wendet, unterrichtet ueber die derzeit gueltigen Bestimmungen der Roentgenverordnung, die Anwendung von Roentgenstrahlen, ueber Qualitaetssicherung, die Organisation der Filmverarbeitung sowie ueber ...
A numeric method for predicting mineral ash deposition in coal dust furnaces is presented which is based on a bidirectional working time coupling of thermodynamic calculation routines (ChemApp{sup TM}) with the commercial CFD code FLUENT{sup TM}. The deposition characteristics of particles and wall surfaces is assessed on the basis of evaluations of flow simulation parameters and results of thermodynamic calculations for the mineral matter contained in the fuel particles, taking into account the complete energy, momentum and mass exchange history of the ash and the mineral conversion. The models enables calculations of the gaseous release of mineral components (e.g. alkaline substances and chlorine) from ash during combustion and its distribution inside a combustion chamber. The method and model are validated using experimental data. (orig.) [German] In der vorliegenden Arbeit wird ein numerisches Verfahren beschrieben, mit dem die Ansatzbildung in Kohlestaubfeuerungen praediktiv ...
The typical MRI features of the most common pancreatic diseases, such as pancreatitis and adenocarcinoma of the pancreas, have been established. However, even in these common pancreatic disorders, MRI correlation with the underlying pathology is limited for clinical reasons. We emphasize MR-pathological correlation of inflammatory and neoplastic pancreatic changes, including pancreatitis, adenocarcinoma, acinar cell carcinoma, rare cystic and solid pancreatic neoplasms, and islet cell tumors. By highlighting the correlation of key pathological features with MR findings, a better understanding of the MR appearance of pancreatic pathology can be provided. In addition, MRI may prove a powerful tool in detection and characterization of pancreatic tumors. (orig.) [Deutsch] Das MR-tomographische Erscheinungsbild von Pankreatitiden und Adenokarzinomen des Pankreas, als den haeufigsten Pankreaserkrankungen, ist zwar ausreichend bekannt; allerdings ist selbst bei diesen ...
Since enterprises operating offices and facilities at geographically distributed sites have been establishing an intranet for inter-office communication at the management level, the idea of integrating another intranet for multi-site technological facility management comes naturally. The Aachen-based technology enterprise Eurem for this purpose developed a Network and Security concept with solutions that can be customized for linking a variety of computerized control and monitoring systems. The package includes a modular substation named modUS, which is open to the field side as well as to the management side, is capable of efficiently and reliably performing the facility management functions by way of remote controlling via intranets. (orig./CB) [Deutsch] Nachdem in den Unternehmen mit verteilten Liegenschaften die unterschiedlichsten Buerokommunikationssysteme ueber eigene Netzwerke verbunden werden, liegt es nahe, auch verteilte Gebaeudeautomationssysteme in diese Vernetzung ...
Since its establishment as nuclear research plant Juelich in the year 1956, the research centre Juelich (FZJ) is concerned with the material processing of special metals. Among those are, above all, the high-melting refractory metals niobium, molybdenum and tungsten. Electron beam welding has always been considered to be an innovative special welding method; in the FZJ, electron beam welding has, moreover, always been adapted to the increasing demands made by research partners and involved manufacturing and design sectors. From the manual equipment technology right up to highly modern multi-beam technique, the technically feasible for fundamental research has, this way, always been realised. (Abstract Copyright [2007], Wiley Periodicals, Inc.) [German] Das Forschungszentrum Juelich (FZJ) beschaeftigt sich seit seiner Gruendung als Kernforschungsanlage Juelich im Jahr 1956 mit der Materialbearbeitung von Sondermetallen. Hierzu zaehlen vor allem die hochschmelzenden ...
The low budgets of local governments and Federal States in Germany as well as lack of financial means of renters delaying thorough modernisation of existing heating systems in residential and public buildings, novel heat supply and related customer services are emerging on the market. Heat supply companies and housing construction associations increasingly use modern electronics and telecommunication systems for heating system upgrading and reliable operation and maintenance. This option holds an enormous potential of saving money today and in the future. Installation of remote control and maintenance systems and the related telephone-based services offer fast repair and other services via electronic telecommunications systems, thus saving money and manpower for the repair services of heat suppliers or plumbers, or financial losses due to rents being docked for broken down heating systems. Such remote control and maintenance systems however need to be reasonable in price, and versatile ...
For the transformation of gasoline direct injection concepts into production solutions not only fuel economy and emission potential but also system stability and durability is important as well as the optimized interaction with exhaust gas aftertreatment and engine management. By application of optical diagnostic methods on research engines and especially in real multicylinder engines, a DI gasoline combustion system could be developed meeting all these requirements. Its fuel economy in the lower part load range is found within the scatterband of DI-Diesel engines. Special emphasis has been concentrated on the optimum adaptation of the combustion system to the limited exhaust gas temperature range of the NOx storage catalyst technology. A combination of this DI gasoline concept with turbocharging reveals a high potential especially regarding transient response. (orig.) [Deutsch] Bei der Ueberfuehrung von Direkteinspritzkonzepten in reale Serienloesungen sind nicht nur ...
Smooth and notched specimens of the bearing steel 100Cr6 (SAE 52100) in a bainitic condition were used to determine the S-N curves under tensile, torsional and combined in- and out-of-phase loading. In the area of high-cycle fatigue, crack initiation was most likely caused by inclusions like Titanium Carbonnitrides or Aluminium Oxides. A micro mechanical model for the crack initiation by inclusions was developed. Another model was developed to describe the influence of these inclusions on the lifetime. A weakest-link model, using the statistical distribution of inclusions and surface flaws, was used to describe the endurance limit. (orig.) [German] Es wurden Woehlerlinien unter Zug-Druck-, Torsions- sowie kombinierter phasengleicher und phasenverschobener Zug-Druck- und Torsionsbelastung fuer glatte und gekerbte Proben des Stahls 100Cr6 (SAE 52100) im bainitischen Zustand erstellt. Im Bereich der Langzeitermuedung gingen die Risse meistens von nichtmetallischen Einschluessen ...
Shortened excerpt from the head notes: The emission limits laid down in the TA Luft concretize the scope of the measures ordered by the law to provide for protection against harmful effects on the environment. Air pollution abatement measures imposed by the competent authority as post-licensing requirements based on the BImSchG (German Federal Emission Control Act) in general are in compliance with the principle of reasonableness considering the terms allowed by the TA Luft for backfitting measures. With this decision, the court qualified the emission limits defined in the TA Luft to be substantial and legally binding standards, to be applied by the competent authorities in licensing and post-licensing administrative procedures, also in order to fulfill the intended task of concretizing the less definite concepts of law laid down in the relevant legislation. (orig./CB) [Deutsch] Verkuerzte Zitierung aus den Leitsaetzen: Die in der TA Luft aufgestellten emissionsbegrenzenden ...
The electron-phonon coupling constant lambda has been calculated for vanadium. The electron energy bands and wave functions were obtained from a model augmented plane wave muffin-tin potential. The electron-phonon matrix elements were evaluated using the rigid-ion approximation and the measured phonon spectra. The results show that lambda is strongly affected by d-f scattering.
Using the PMR method the interaction of zirconium and hafnium tetrachlorides with tri.tet.butylphenyl ester of 1,2- naphthoquinonediazide (2)-5-sulfonic acid is studied. The formation of MCl/sub 4/xNQD complexes is established, the equilibrium constants and thermodynamic parameters of complexing reaction are determined. The presence of rapid ligand exchange, proceeding according to associative mechanism, is detected. The rate constants and activation energies of the exchange reaction are calculated.
Using the PMR method the interaction of zirconium and hafnium tetrachlorides with tri.tet.butylphenyl ester of 1,2- naphthoquinonediazide (2)-5-sulfonic acid is studied. The formation of MCl_4xNQD complexes is established, the equilibrium constants and thermodynamic parameters of complexing reaction are determined. The presence of rapid ligand exchange, proceeding according to associative mechanism, is detected. The rate constants and activation energies of the exchange reaction are calculated.
Stability constants for uranium-tetracycline complexes were determined by the method of average number of ligands, the method of limiting values, the method of two parameters and the method of weighted least squares. Solvent extraction technique was used to obtain experimental data. (author). 10 refs.; 5 figs.
The authors have determined quantitative characteristics for oxide films forming on (111) surfaces of cadmium telluride single crystals on anodic oxidation in 0.1 M KOH: the constants in the Guenterschulze-Betz equation and the film growth constant, which is 2.4 nm/V, from which the activation energy for cadmium telluride electrooxidation has been calculated.
Pyrheliometric methods are described (particularly methods for measuring the solar constant), and theoretical and experimental studies in this field are surveyed and systematized. Particular attention is given to the analysis of instruments intended for pyrheliometers used as standards, reference instruments, and solar-constant meters is examined, and consideration is given to methods for determining the thermal-radiation properties of absorbing coatings and methods for calculating the absorption coefficients of cavity receivers.
A possibility of generating collimated beams of faster-than-light particles (tachyons) and using them for rocket propulsion is explored. The relativistic rocket equations are derived, and are solved for a single-stage rocket with constant mass flow rate, constant exhaust velocity and no coasting period. The features of these solutions for faster-than-light exhaust velocities are discussed. It is shown that a tachyon drive would not violate the first law of thermodynamics. However, as seen in the Galactic frame, it would violate the second law.
X-ray results on the lattice parameters, molar volume and thermal expansion coefficients of solid ortho-deuterium for the region from 2 K to the melting point are reported. It is found that the thermal expansion of ortho-deuterium crystals, similarly to parahydrogen is essentially anisotropic near the melting temperature. The vacancy density at the triple point is estimated. Some thermodynamic characteristics of ortho-deuterium are calculated and temperature dependences of heat capacity at constant volume, isothermal compressibility and Gruneisen constant are analyzed.
The protonation constants (KiH) of 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene-3,6,9,-triacetic acid (PCTA) and stability constants of...Full Text Available
The effective elastic constants of a superlattice composed of layers of orthorhombic symmetry (with principal axes along the superlattice axis) are derived. These results generalize previous determinations for elastically isotropic layers (Rytov, Akust. Zh. 2, 71 (1956) (Sov. Phys.: Acoust. 2, 68 (1956))), but a completely different approach is used.
Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433?479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.
Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433-479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.
This book presents topics on: Density of rocks and minerals, includes histograms of density ranges; elastic constants of minerals, elastic moduli, thermal properties; inelastic properties, strength and rheology for rocks and minerals, rock mechanics and friction, and stress-strain relations; radioactivity, decay constants and heat production of isotope systems in geology; seismic attenuation, in rocks, minerals, and the earth, with application to oil exploration and terrestrial studies; and index.
In order to design the microstructure of ceramics with desired dielectric property, an estimation method of dielectric constant of ceramics taking into account the characteristics of microstructure of the ceramics is proposed. In the estimation model, the microstructure of ceramics is represented by the assembly of unit cells comprising of grain, pore and grain boundary. The sizes of grain and pore and the thickness of grain boundary in each unit cell were determined exactly according to their size and thickness distributions in a real ceramic. The dielectric constant of the assembly can be calculated on the basis of equivalent circuit theory. The estimated values of dielectric constant of ceramic BaTiO{sub 3} using the proposed estimation method agree well with experimental ones. The dependence of characteristics of microstructure on the dielectric constant was clarified by the estimation of dielectric ...
The interaction of Pu(IV) and Zr(IV) with citric acid in nitric acid solutions (C/sub HNO/sub 3// greater than 0.1 M) of lithium nitrate was studied by the distribution method in the interval of nitrate ion concentrations from 1 to 6 g-eq/liter. A 40 percent solution of TBP in decane was used as the extraction reagent. It was established that within the range of concentrations studied, complex compounds of plutonium and zirconium are formed: PuHCit/sup 2 +/ and ZrH/sub 2/Cit/sup 3 +/. The concentration equilibrium constants of the reactions of formation of these compounds retain a constant value at constant ionic strength and undergo substantial variation when the total concentration of the nitrate ion in solution is varied. The values of the effective equilibrium constants, calculated considering the change in the activity coefficient of the hydrogen ion, retain a constant value ...
This work was made with the purpose to complete information about the hydrolysis constants of Europium (III) in high ion strength media. So it was determined at a ion forces media 4, 5 and 6 M of sodium perchlorate at 303 K. The method used was the potentiometric with the aid of the Super quad computer program. In high ion strength media, the measurements of p H do not correspond directly to negative logarithm of the concentration of hydrogen ions, by this it is necessary to calibrate the electrode in these conditions. The Europium was hydrolized at pC{sub H} values greater 6 in all cases. The potentiometric method used under the described experimental conditions is adequate to determine the hydrolysis constants of Europium (III). According to the results and diagrams of chemical species of Europium obtained we can conclude that the hydrolysis constants, differ by its distribution but not in its identity. (Author)
The report describes the processing of TiSi{sub 2}, MoSi{sub 2} and Ti{sub 5}Si{sub 3} by means of metal injection molding (MIM). First, the sintering activities of the three materials were investigated. After this, the viscosities of different mixtures of organic binder and powders of the three materials were determined, and in the final stage, components were produced by injection molding, the binder was removed, and the components were sintered. TiSi{sub 2} in powder form could be sintered to more than 95% of its theoretical density after 4 h at 1386 C. Metallographic analyses proved leaktightness of the component at this density. In the case of Ti{sub 5}Si{sub 3}, it was found that this material requires very long sintering times and high sintering temperatures for sintering to about 94% of its theoretical density. Metallographic analyses showed that only about 90% of the theoretical density was reached. MoSi{sub 2} in powder form could be sintered to only 90% of its theoretical ...
The thermochemical calculations performed with a large number of elements to describe the chemical system in a Phebus FP test allow the following conclusions: The metallic absorber materials play a significant role in fission product speciation. At around 1000 C and above, silver iodide is the dominant iodine carrier in a full steam atmosphere in both FPT0 and FPT1. At lower temperatures, cadmium iodide takes over. In a reduced environment, indium iodide becomes important. Caesium iodide does certainly appear; at certain test conditions it becomes the major iodine transporting vehicle. But its role is not greater than that of the other iodides. It has more chances in FPT1 than in FPT0. Chlorine, which was present in FPT0 as a contaminant in relatively large amounts, does not prevent the iodine from forming Csl. Both share the caesium like partners. The evolution of caesium chloride and iodide proceeds in parallel. When CsCl is abundant, Csl is strong, too. Should boron be added to the ...
The discovery that the cosmic expansion is accelerating has been followed by an intense theoretical and experimental response in physics and astronomy. The discovery implies that our most basic notions about how gravity work are violated on cosmological distance scales. One simple fix is the introduction of a cosmological constant into the field equations for general relativity. However, the extremely small value of the cosmological constant, relative to theoretical expectations, has led theorists to explore a wide variety of alternative explanations that involve the introduction of an exotic negative-pressure fluid or a modification of general relativity. Here we briefly review the evidence for cosmic acceleration. We then survey some of the theoretical attempts to account for it, including the cosmological constant, quintessence and its variants, mass-varying neutrinos, and modifications of general relativity, such as ...
The use of a running coupling constant in renormalizable theories is well known, but the implementation of this idea for effective field theories with a dimensional coupling constant is in general less useful. Nevertheless there are multiple attempts to define running couplings including the effects of gravity, with varying conclusions. We sort through many of the issues involved, most particularly the idea of operator mixing and also the kinematics of crossing, using calculations in Yukawa and lambda phi^4 theory as illustrative examples. We remain in the perturbative regime. In some theories with a high permutation symmetry, such as lambda phi^4, a reasonable running coupling can be defined. However in most cases, such as Yukawa and gauge theories, a running coupling fails to correctly account for the energy dependence of the interaction strength. As a byproduct we also contrast on-shell and off-shell renormalizaton schemes and show that ...
In order to investigate the charging mode of an in-series assembly of lithium-carbon battery cells, a test has been performed on 5 commercial cells (18650) of 0.95 Ah nominal capacity. Results show that it is possible to cycle the cells at 80% of their output capacities during more than 2000 cycles. The management of the battery consists in maintaining a constant battery voltage as soon as a cell reaches its limit voltage during constant current charging. The initial dispersion of cells has been maintained practically constant during the cycling and the charge state of all cells has decreased progressively. (J.S.)
General relativity postulates the Minkowski space-time to be the standard flat geometry against which we compare all curved space-times and the gravitational ground state where particles, quantum fields and their vacuum states are primarily conceived. On the other hand, experimental evidences show that there exists a non-zero cosmological constant, which implies in a deSitter space-time, not compatible with the assumed Minkowski structure. Such inconsistency is shown to be a consequence of the lack of a application independent curvature standard in Riemann's geometry, leading eventually to the cosmological constant problem in general relativity. We show how the curvature standard in Riemann's geometry can be fixed by Nash's theorem on locally embedded Riemannian geometries, which imply in the existence of extra dimensions. The resulting gravitational theory is more general than general relativity, similar to brane-world gravity, but where the ...
A method for determining the rational capacity of the shield supports under various geological conditions is proposed. Based on the instrumentation of the pressure histories of the shield legs in eight mines, the relation between the final load or the increment of support resistance in a mining cycle and the setting load is established. The relation is represented by a mathematical equation with characteristic constants. Those constants are related to the physical properties of the immediate and main roof strata. Nomographs were constructed for determining the constants under various geological conditions. The paper discusses the principles and step-by-step procedures for determining the rational setting and yield loads for all the shield supports employed in the eight mines. The predicted values are then compared with the actual ones used by the operators. 7 refs., 6 figs., 4 tabs.
General expressions for the interlattice displacements of the A-15 structure compounds are obtained in terms of the strain components making use of the deformation theory. The nature of the interlattice displacements of all the 8 atoms in the unit cell is discussed. It is found that the interlattice displacements occur in such a way that the pair of atoms along any linear chain move in opposite directions with equal magnitudes. Expression for the strain energy of these compounds is developed using deformation theory and this is compared with the strain energy expression from continuum theory to obtain the elastic constants. The theoretical values of the elastic constants fairly agree with the experimental values for V_3Si, V_3Ge and Nb_3Sn. (author).
General expressions for the interlattice displacements of the A-15 structure compounds are obtained in terms of the strain components making use of the deformation theory. The nature of the interlattice displacements of all the 8 atoms in the unit cell is discussed. It is found that the interlattice displacements occur in such a way that the pair of atoms along any linear chain move in opposite directions with equal magnitudes. Expression for the strain energy of these compounds is developed using deformation theory and this is compared with the strain energy expression from continuum theory to obtain the elastic constants. The theoretical values of the elastic constants fairly agree with the experimental values for V3Si, V3Ge and Nb3Sn.
Wood plastic composite (WPC) of kadom, simul, mango and debdaro were prepared with two monomers methylmethacrylate (MMA) and butylmethacrylate (BMA) using high energy ionizing radiation. X-ray diffraction and scanning electron microscope (SEM) studies reveal that significant grafting occurred with wood fiber. Electric properties like resistivity and dielectric constant of both wood and WPC were measured under different moisture contents and relative humidities. The resistivities of wood decreased dramatically with increase of moisture content, but those of WPC decreased very slowly with moisture content. The dielectric constant of wood increased significantly with moisture content but no significant difference was observed in the case of WPC within the range of moisture contents studied. The dielectric constants of untreated wood also increased with their densities. (author).
We study the dynamical evolution of a scalar field coupling to Einstein's tensor in the background of a Reissner-Nordstroem black hole. Our results show that the coupling constant #eta# imprints in the wave dynamics of a scalar perturbation. In the weak coupling, we find that with the increase of the coupling constant #eta# the real parts of the fundamental quasinormal frequencies decrease and the absolute values of imaginary parts increase for fixed charge q and multipole number l. In the strong coupling, we find that for l#not =#0 the instability occurs when #eta# is larger than a certain threshold value #eta#_c which deceases with the multipole number l and charge q. However, for the lowest l=0, we find that there does not exist such a threshold value and the scalar field always decays for arbitrary coupling constant.
The availability of dimeric Pt(I) complexes with bridging bis(diphenylphosphino)methane ligands, (L--L')/sup n+/, presents an opportunity to study the physical properties and reactivity of metal-metal bonds as a function of the ligand trans to it with a minimum of competing variables. Several interesting trends of Pt-P coupling constants with the Pt-L and Pt-Pt bond lengths in Pt(I) dimers, (L--L')/sup n+/, and structurally related Pt(II) complexes are reported here. The data indicate that the Pt-P coupling constants continue to be sensitive indicators of not only the structure and stereochemistry of platinum phosphine complexes but also the electronic and steric influences of the ligand in such complexes, 23 references, 1 figure, 4 tables.
A spectrophotometric study has been made of the complex formation of vanadium (3) with arsenazo(1), arsenazo(3) and some monosubstituted derivatives of chromotropic acid and sulphanylamides. In acid medium vanadium (3) reacts with each of these reagents to produce a 1:1 complex. Optimum conditions of the complex formation was found. The effect of H"+ on the complex formation of vanadium (3) with chromotropic acid derivatives was established. It was found by the graphical method that the formation of the complex is accompanied by the elimination of one proton. Patterns were found of the influence of the nature of substituents in the organic compound on the ionization constants of acid groups and stability of complexes. Molar extinction coefficients, equilibrium constants of the formation reactions and instability constants for the complexes were calculated. The structure of complexes was suggested. Similar behaviour of all ...
The magnetic hyperfine constants of the V sub(K) center in CaF_2, SrF_2 and BaF_2 have been calculated, assuming a phenomenological model, based on the F"-_2 'central molecule', to describe the wave function of the defect. The introduction of covalence with the ions neighboring the 'central molecule', has shown that this is a better description for the defect than a simple 'central molecule' model. It was also shown that the results for the hyperfine constants are strongly dependent on the relaxations of these neighboring ions, which have been determined by fitting the experimental data. The present results are compared with other previous calculations where similar and different methods have been used. A better description for the wave function of the defect is suggested. (author).
Spectrophotometric methods were used to investigate the properties of neptunium(VII), (VI), and (V) in silicate solution. The transition of cationic neptunium(VII) to anionic species in non-complexing environments proceeds in the range of ?? 5.5 to 7.5. In the presence of carbonate, this transition occurs at ?? 10.0 to 11.5 and in silicate solutions at ?? 10.5-12.0. These findings show that cationic neptunium(VII) forms complexes with both carbonate and silicate and that the silicate complex is stronger than that of the carbonate. The competition of complex formation reactions for neptunium(VI) with carbonate and silicate and on the known complex stability constant of NpO2(CO3)34- allowed the NpO2SiO3 complex stability constant, log ? = 16.5, to be estimated. Determination of the formation constant of Np(V) complexes with SiO32- was not possible using similar methods.
The ODS superalloys MA 6000 and MA 760 were investigated with regard to their behaviour under non-isothermal fatigue stress. For this purpose, strain-controlled thermomechanical and bithermal experiments with different phase relationships between strain and temperature were carried out on the one hand; on the other hand, the deformation behaviour under thermomechanical stress was modelled on the basis of isothermal cyclic creep data. The fatigue experiments show that a diamond-shaped cycle derived from the stress pattern of a turbine blade is clearly less critical than in-phase and out-of-phase cycles. The life of the diamond-shaped cycle is determined by oxidation-induced crack initiation and propagation and can be predicted easily with a suitable damage model. Important damage parameters required by the model can be obtained by the less complicated bithermal fatigue tests. Modelling of the TMF hystereses suggests that cyclic, non-isothermal deformaltion is determined mainly by ...
Characterisation of the classification of brain tumours authorised by the WHO. Method of appraisal: This classification was revised and published in its second version. In the revision, some tumours were regrouped histogenetically and some tumour variants were added. Radiologically relevant changes of the classification include the differentiation of four new tumour entities that are easily distinguished by MR imaging. These four tumours belong to the group of childhood tumours or tumours occurring in early adulthood and are characterized by a good prognosis after extirpation. Results of appraisal: Central neurocytomas are small-cyst ventricular tumours associated with the foramen of Monroi and show moderate contrast enhancement. Infantile desmoplastic gangliogliomas/astrocytomas commonly consist of a solid tumour portion related to the leptomeninges with pronounced contrast enhancement and a typically very large cyst. Pleomorphic xanthostrocytomas are circumscribed cortical tumours ...
The ECOTEC is a mass-efficient gasoline DOHC 4-valve per cylinder engine with balance shafts, chain driven camshafts and roller finger followers with hydraulic lash adjusters for valve actuation. It has lightweight aluminium components such as camcover, cylinder head, cylinder block, lower crankcase and structural oil pan. Other features include composite intake manifold and a coil-on-plug ignition cassette. The ECOTEC combustion system and engine architecture are optimized for low engine out and tail pipe emissions. It also includes several designed-in 'green' features for environmental benefits. The product design, development and validation process drew upon the best knowledge and practices available worldwide both inside and outside General Motor. The manufacturing systems were also designed by leveraging the best available knowledge around the world resulting in implementation of world class processes and error proofing to achieve the competitive edge in product ...
DMT has developed what is called the stepped reforming process. This is an allothermal gasification process which uses hydrogen for a gasification medium. First the biomass is pyrolised by means of a heat transfer material. The escaping gaseous and condensable constituents are hydrogenated, heated in a reforming stage and are made to react to a hydrogen-rich product gas by means of homogeneous gasification. The heat required for this is provided by burning the pyrolysis coke. This makes it possible to dispense with process stages that would involve gasification of solid material and hence require higher pressure levels. The present process also works at ambient pressure. Moreover, stepped reforming promises a number of additional advantages: low-tar product gas containing 60% hydrogen, high cold gas efficiency, no wastewater arisings, robust operating behaviour. This paper outlines the basic ideas that led to the development of stepped reforming process and describes its diverse ...
In comparison to deterministic criteria, probabilistic reliability indices like interruption frequency and unavailability give a more differentiated insight into reliability in an electrical energy network. One possibility for network planning based on these indices is the definition of limits for customer nodes, another is the monetarisation of reliability in terms of interruption costs. Because of numerous disadvantages, interruption cost methods could not up to now win broad recognition in network planning in Western Europe. A more recent method for the monetarisation of reliability circumventing most of these disadvantages is the insurance system. In this system the customer selects a tariff class in an insurance system, and the utility reimburses its customers in the case of an interruption. In its first section, the paper describes a method for the flexible and realistic optimisation of MV networks. This method based on Genetic optimisation is able to integrate probabilistic ...
The aim of this review is to evaluate the role of inflammatory spine disease in patients with chronic back pain. The contribution of imaging modalities for the diagnostic evaluation of back pain is discussed. A systematic literature search based on the classification of seronegative spondyloarthropathies and rheumatoid arthritis was performed. The results of this search and the experiences in a large collective of rheumatological patients are analyzed. The prevalence of rheumatoid arthritis (1-2%) is comparable to that of spondyloarthropathies (1.9%). The etiology of these entities is not fully elucidated. Magnetic resonance imaging is increasingly used for early detection and surveillance of therapy with TNF-{alpha} antagonists. Bone marrow edema, which is only detectable with MRI, represents an early sign of inflammation. Therapy with TNF-{alpha} antagonists is based on clinical and laboratory criteria, and signs of inflammation in MRI. MRI is useful for assessment of the ...
For a wider application of GaAs single crystals for semiconductor devices a cheaper process to grow crystals with high purity and low dislocation density is required. According to todays knowledge the Czochralski method with a hot wall vessel should be the choice. The temperature of the vessel has to be 700deg C to avoid condensation of arsenic which vapourizes from the 1240deg C hot melt. Arsenic vapour is very agressive against all metals. Therefore the corrosion resistance of metals and alloys with a high melting point and also ceramics has been tested. All the alloys under investigation are corroded severely so that they have to be excluded as a material for the vessel. The metals tantalum, molybdenum and tungsten are more resistent, titanium forms initially a thick protection layer and further corrosion is greatly reduced. The ceramics investigated (TiB{sub 2}; ALN; Makor; BN) are not attacked by arsenic though they may store some arsenic. (orig./MM). [Deutsch] Fuer breitere ...
It is shown that the interaction of a class of positive energy tachyons decreases the area of the horizon of the T-S, delta = 3 metric even in the case of a reversible transformation (Msub(ir) = constant). This is a violation of the second law of black hole physics.
It is shown that the interaction of a class of positive energy tachyons decreases the area of the horizon of the T-S, delta = 3 metric even in the case of a reversible transformation (Msub(ir) = constant). This is a violation of the second law of black hole physics. (author).
Three new classes of finite, homogeneous and nonsingular solutions of Einstein's equations which have time-dependent expansion, shear and rotation are presented. The t-constant sections are of Bianchi type IX. The source of these geometries is a fluid which has not been thermalized. (Author).
An exact cosmological solution of Einstein's equations which has time-dependent rotation is presented. The t-constant sections are of Bianchi type II. The source of this geometry is a fluid which has not been thermalized. (Author).
Quartz has a dissipation factor of approximately 10(-4), which is an order of magnitude less than that of the best glasses previously used to fabricate patch pipettes; it's dielectric constant of 3.8...Full Text Available
The rate of appearance of unlabelled glucose was calculated from tracer data and compared with the actual rate of infusion of unlabelled glucose into a anaesthetized dog with all sources of endogenous...Full Text Available
The intracellular concentration of protein may be as high as 400 mg per ml; thus it seems inevitable that within the cell, numerous protein-protein contacts are constantly occurring. A basic biochemical...Full Text Available
A survey is given on the present status of the nucleon parton distributions and related precision calculations and precision measurements of the strong coupling constant {alpha}{sub s}(M{sup 2}{sub Z}). We also discuss the impact of these quantities on precision observables at hadron colliders. (orig.)
Sustained metabolic rates (SusMR) are time-averaged metabolic rates that are measured in free-ranging animals maintaining constant body mass over periods long enough that metabolism is fueled by food...Full Text Available
The first-step formation constants of UO_2"2"+-complexes of some N-hydroxysuccinamic acids viz. N-phenyl N-hydroxysuccinamic acid (Rsub(p)H(sub(2))), N-o-toyl N-hydroxysuccinamic acid(Rsub(t)oHsub(2)) and N-m-tolyl N-hydroxysuccinamic acid (Rsub(t)mHsub(2)) have been determined spectrophotometrically. Stabilities are in the ligand order Risup(m)Hsub(2)>Rsub(t)oHsub(2)>Rsub(p)Hsub(2). The first-step hydrolysis constant k' of UO_2"2"+ ion has been determined spectrophotometrically and found to be pk'=4.00 at a constant ionic strength (#mu#=0.5) at 30deg-+0.5deg and the molar extinction coefficients of the species UO_2"2"+ and UO_2(OH)"+ at #LAMBDA#=385 nm are found to be 2.0 and 13.0 respectively. (author).
Ring opening dynamics of diarylethene derivative (BTF6) in n-hexane are studied by femtosecond transient absorption and time resolved spontaneous fluorescence techniques. Cyclo-reversion time constant is obtained.
By forming [2/1] Pad? approximants to the constants we obtain: re = 1.125 $Aring $ (1.128 $Aring$), Be = 1.943 cm-1 (1.9312 cm-1), ?eB = 0.0156 cm-1 (0.0175 ...
Outpatient practice after percutaneous coronary intervention (PCI) is gaining momentum due to constantly optimizing results. Furthermore, the availability of limited beds to handle the large volume...Full Text Available
It is shown that calculation of the anomalous expectation values for the massless Gross-Neveu model in the Hartree-Fock approximation indicates the presence of an ordinary chiral phase transition if the coupling constant has the normal sign (g > 0) and of a different transition of the superconductivity type if g < 0.
Cancer cells constantly adapt to oxidative phosphorylation (OXPHOS) suppression resulting from hypoxia or mitochondria defects. Under the OXPHOS suppression, AMP-activated protein kinase (AMPK) regulates...Full Text Available
Mitochondrial DNA is constantly exposed to oxidative injury. Due to its location close to the main site of reactive oxygen species, the inner mitochondrial membrane, mtDNA is more susceptible...Full Text Available
The optimizing criterion is assumed to be the maximum net present value of the project. The following summarizes the significant conclusions. (1) Over a large range of discount rates, mining and milling of the mineral deposit at a constant cutoff grade and a constant production rate consistently results in smaller annual discounted cash flows than the optimal schedule determined by the dynamic programming model (dpm) where the cutoff grade and mining rate are allowed to vary in response to fluctuating product price. (2) With an increasing discount rate, under the dpm the annual discounted cash flows decrease at a slower rate than if the mineral inventory is mined and milled at a constant cutoff grade and a constant production rate. (3) Cuttoff grade increases only where higher equity ore is available. Thus, to maintain the mill feed requirement, the mining rate also increases. (4) Not withstanding an ...
1. The mechanical power spent to accelerate the limbs relative to the trunk in level walking and running, Ẇint, has been measured at various `constant' speeds (3-33...Full Text Available
The report gives results of the measurement of dissolution rates of reagent CaCO3 and commercial limestones (9 types/19 grinds) at constant pH and solution composition by batch titration with HC1. Conditions were selected to simulate flue gas desulfurizat...
As with mammalian enzymes, green crab (Scylla serrata) alkaline phosphatase can be activated by Mg2+ through a time-dependent course. The activation is mainly a Vmax effect. Tsou's method was used to study the kinetic course of activation. The results show that the enzyme was activated by a complexing scheme that had not been previously identified: the enzyme first reversibly and quickly binds Mg2+ and then undergoes a slow reversible course to activation, with a relatively high activation energy (78 +/- 4 kJ/mol) and a slow conformational change. The activation reaction is a single molecule reaction, and the apparent activation rate constant is independent of Mg2+ concentration if the concentration is sufficiently high. The microscopic rate constants of activation and the association constant were determined from the measurements. The proposed scheme may also be applied to the Mg2+ activation mechanism for mammalian ...
Hydrogenolysis of quinoline was carried out using red mud catalyst at 390{degree}C and 450{degree}C to study denitrogenation reaction in the first stage liquefaction of coal. Quinoline was decomposed to ammonia via 1-THQ or hydrogenated to 5-THQ. The reaction rate constants obtained at 390{degree}C were k{sub 1} = 1.83 {times} 10{sup {minus}6}, k{sub 2} = 1.16 {times} 10{sup {minus}7}, and k{sub 3} = 3.24 {times} 10{sup {minus}7} mol {center dot} dm{sup {minus}3} {center dot} min{sup {minus}1} {center dot} g {center dot} {sup {minus}1}. The rate constants for hydrogenation of quinoline were in the order of hexadecane > trans-decalin > 1-methylnaphthalene. Ratios of equilibrium adsorption constant between trans-decalin and quinoline and between 1-methylnaphthalene and quinoline were found to be 0.055 and 0.155 respectively. The equilibrium constant of phenol to red mud catalyst adsorption was ...
Three major series of experiments have been conducted with the FELIX facility at ANL. Experiments on the coupling between eddy currents and angular displacements of loops and plates in crossed constant and changing magnetic fields demonstrated that the co...
Various electrochemical capacitors (ultracapacitors) are being developed for hybrid vehicles as candidate power assist devices for the fast response engine. The primary functions of the ultracapacitor are to level the dynamic power loads on the primary propulsion device and recover available energy from regenerative breaking during off-peak power periods. Ultracapacitors show promise toward being able to accept high regenerative pulses while exhibiting very high cycle life. This paper will present test data from selected US Department of Energy (DOE) supported ultracapacitor projects designed to meet the fast response engine requirements. Devices containing carbon, conducting polymers, and metal oxide electrode materials in combination with aqueous or organic electrolytes are being supported by the DOE. This paper will present and discuss testing data obtained from recent prototype capacitors supplied by Maxwell Energy Products, Inc., SAFT America, Inc., Federal Fabrics-Fibers and the ...
Nebulised antibiotics have been shown to be beneficial in the treatment of lung infections in cystic fibrosis. Studies on the efficiency of nebuliser systems are constantly required in view of the large...Full Text Available
A simulation is developed that qualitatively describes the small-zone-gel-filtration behaviour of a reversibly associating protein. The results reflect the dependence of the apparent molecular weight...Full Text Available
This project addresses the problem of flue gas desulfurization (FGD) sludge disposal to land. Specifically, the chemical species of FGD sludge constituents are thermodynamically modeled using the equilibrium constant approach, in an attempt to predict the constituent concentratio...
There are no 'intelligent' buildings but only 'intelligently controlled' buildings. Intelligent control requires communication between technical facilities, which in turn requires building automation and system integration. [German] Es gibt keine ''intelligenten'', sondern nur ''intelligent betriebene'' Gebaeude. Mit dieser Feststellung ist die Vorbedingung festgelegt, dass Gebaeude ein gewerkeuebergreifendes System benoetigen, das die Komponenten miteinander kommunizieren laesst. Dafuer eignet sich die Gebaeudeautomation. Damit diese ihre Aufgaben erfuellen kann, bedarf es der Systemintegration. (orig.)
The isothermal flow field for the axial cyclone has been experimentally determined. The velocity fields are used for determination particle paths (particle removal and suspended state), and inter alia of heat and mass transfer processes in the axial cyclone combustion chamber. The results are extremely significant as input value approximations for mathematical modelling, since experimentally obtained results are indispensable for complex flows and geometries. (orig.) [Deutsch] Es ist fuer den Axialzyklon experimentell das isotherme Stroemungsfeld ermittelt. Die Geschwindigkeitsfelder dienen zur Ermittlung der Partikelbahnen (Partikelabscheidung, Schwebebedingung), der Waerme- und Stoffuebertragungsprozesse u.a. in der Axialzyklonbrennkammer. Die Ergebnisse sind als Startwertnaeherung bei einer mathematischen Modellierung sehr wichtig, da bei komplexen Stroemungen und Geometrien versuchstechnische Ergebnisse unumgaenglich sind. (orig.)
Fatigue tests were accomplished with a series of specimens doped with trace elements of a hardened Fe-Ni-Cr alloy, cast and hardened with intermetallic phases for determining the influence of these elements on the high temperature strength properties. The results of extensive fatigue tests show that even small contents of Te, Bi, Se, Pb, Tl and Zn considerably influence the life and creep processes especially after longer running periods, when added individually or combinedly. In contrast to this, the fatigue ductility is reduced by trace element additions even with short running periods. The order in which the metallic trace elements influence the fatigue properties nearly correlates with earlier work concerning Ni- and Co-superalloys. (orig.)
ZusammenfassungUbelkeit und Erbrechen stellen zwei Symptome dar, die grundlich untersucht worden sind und bei Krebspatienten haufig auftreten. Die meisten Studien haben sich bislang mit Haufigkeit und Management dieser beiden Symptome befasst. Das Ziel dieser Studie bestand darin, ein besseres Verstandnis dafur zu entwickeln, wie Krebspatienten ihre Symptome erleben-insbesondere Ubelkeit und Erbrechen nach Chemotherapie-und welche Auswirkungen diese Symptome auf den Tagesablauf der Patienten haben. Neun Frauen mit unterschiedlichen Krebsleiden und Chemotherapie Regimes wurden zwecks Chemotherapie stationar aufgenommen und nahmen an der Studie teil. Es wurden halbstrukturierte Interviews einschliesslich einer Inhaltsanalyse in Anlehnung an Kvale durchgefuhrt (Klarung und Entwicklung neuer B...
Biosorption behaviour of and toxic effects of heavy metals in submersed and immobilised microorganisms was studied in batches and in continuous processes in an airlift-recycle reactor. Nickel, cadmium, and zinc were used as heavy metals. (orig./VHE) [Deutsch] Am Beispiel einer Naphthalin-2-sulfonsaeure-abbauenden Kultur wurde das Biosorptionsverhalten und die toxische Wirkung von Schwermetallen auf submerse und immobilisierte Mikroorganismen im Batch-Ansatz und im kontinuierlichen Betrieb in einem Airlift-Schlaufenreaktor untersucht. Als Schwermetalle wurden Nickel, Cadmium und Zink eingesetzt. (orig./VHE)
Liberalization and the associated necessity of providing, where possible, inexpensive electrical energy, has intensified still further the demand for higher efficiency steam turbines. Accordingly, continuous efforts are being taken to improve all the flow guiding components of a steam turbine. Special attention is given here to the blading. (orig.) [Deutsch] Die Liberalisierung und die damit verbundene Notwendigkeit, elektrische Energie moeglichst preisguenstig zur Verfuegung zu stellen, hat die Forderung nach hohen Wirkungsgraden von Dampfturbinen weiter verschaerft. Es werden daher kontinuierlich Anstrengungen unternommen, alle stroemungsfuehrenden Teile einer Dampfturbine zu verbessern. Das Hauptaugenmerk gilt dabei der Beschaufelung. (orig.)
Facility management has long been regarded as a cost reduction measure, but it is also a means of raising the financial worth of a building so that landlords can get higher rents or sell the building at a better price. [German] Lange Zeit wurde Facility Management als eine Massnahme zur Kostensenkung angesehen. Heutzutage zeigt sich immer mehr, dass das Facility Management sehr viel umfassender zu verstehen ist: Der Wert eines Gebaeudes bemisst sich nicht allein an einer niedrigen Kostenquote, sondern er soll umfassend Investoren wie Mietern den hoechst moeglichen Nutzen bringen. Nicht allein der kostenguenstige Betrieb ist entscheidend, sondern der Wert des Gebaeudes muss insgesamt gesteigert werden. (orig.)
MPA research activities focus on fracture prevention and on the development of a generally applicable method of component integrity testing which, independent of the safety relevance of the components involved, is also part of ageing management. (orig.) [German] Die Forschungsaktivitaeten an der MPA im Hinblick auf die Erhoehung der Sicherheit und Zuverlaessigkeit komplex beanspruchter Bauteile orientieren sich an den Grundgedanken des Basissicherheitskonzepts (Prinzip des Bruchausschlusses). Zielsetzung war dabei die Entwicklung eines allgemein anwendbaren Nachweisverfahrens zur Komponentenintegritaet, das, abhaengig von der sicherheitstechnischen Relevanz der zu betrachtenden Komponenten, auch Bestandteil des Alterungsmanagements ist. (orig.)
Zusammenfassung Das Lungenkarzinom ist eine der h?ufigsten Krebserkrankungen und die h?ufigste Krebstodesursache. Mit der Einf?hrung innovativer Substanzen ist die M?glichkeit einer individualisierten Therapie gegeben, die eine Verbesserung von Prognose und Lebensqualit?t verspricht. Die Wirksamkeit dieser Therapeutika basiert auf spezifischen molekularen Eigenschaften des Lungenkarzinoms und stellt neue Anforderungen an die pathohistologische Diagnostik. Neben dem Histotyp haben sich molekulare Alterationen, insbesondere EGFR-Mutationen, als pr?diktive Marker erwiesen. Die histologische Typisierung umfasst daher nicht nur die Unterscheidung von SCLC und NSCLC, sondern die Subtypisierung der NSCLC unter Einbezug immunhistologischer und molekularer Untersuchungen. Zusammenfassend werden Kri...
A programme to optimize the short-term operation planning of hydrothermal system scheduling is presented. Based on heuristics, an operational planning of pumped storage plants and a method for fast evaluations of spot market deals under consideration of load forecast errors was developed. (orig.) [German] Vorgestellt wird ein Programm, das - basierend auf Heuristiken - den kurzfristigen Einsatz eines hydrothermischen Kraftwerksparks optimiert. Im Programm wurde dazu ein Verfahren zur Pumpseichereinsatzplanung und zur sekundenschnellen Bewertung von Spot-Markt-Geschaeften unter Beruecksichtigung von Lastprognosefehlern entwickelt. (orig.)
Zusammenfassung Die Festigkeitshypothesen und Flie?fl?chen aus den klassischen Kursen der Mechanik (die Normalspannungshypothese, die Modelle nach von Mises und Tresca) reichen oft nicht aus, das tats?chliche Verhalten von Bauteilen unter Belastung zu erfassen. Deshalb werden in der Literatur weitere Modelle mit einem oder mehreren Parametern vorgeschlagen. Diese Modelle beschr?nken allerdings die Geometrien der zul?ssigen Formen der Fl?chen im Spannungsraum. In dieser Arbeit wird ein auf die Zugspannung normiertes Druck-Torsion-Diagramm vorgestellt, in dem sich die Modelle inkompressiblen Materialverhaltens miteinander vergleichen lassen. Mit diesem Diagramm wird der Begriff der Symmetrie der Fl?che in der ?-Ebene verdeutlicht. Die konvexen Fl?chen inkompressiblen Materialverhaltens sind ...
Zusammenfassung Eine genauere Untersuchung der bekannten Modelle isotropen Materialverhaltens (z.B. von Mises, Tresca, Mohr-Coulomb, Drucker-Prager usw.) zeigt, dass sie selten mit Versuchsergebnissen ?bereinstimmen. Modelle mit inkompressiblen Eigenschaften sch?tzen oft das Materialverhalten bei mehraxialen Zugbelastungen falsch ein. Beim Flie?en unter Druck liefern die Modelle mit kompressiblen Eigenschaften unzul?ssige Werte der Querkontraktionszahl. Erfahrungen zeigen, dass es schwierig ist, mehrdimensionales Materialverhalten bei h?ufig fehlenden Informationen werkstoffgerecht abzubilden. Viele Modelle liefern akzeptable Ergebnisse nur f?r bestimmte Bereiche des Spannungsraumes. Diese Beobachtung hat auf die Idee gef?hrt, ,,bew?hrte?? Modelle miteinander zu verbinden. In diesem Artike...
To evaluate the usefulness of radiation therapy alternative to surgery for clinical N0-N1 non-small cell lung cancer (NSCLC). From 1976 through 1989, 116 patients with NSCLC without mediastinal involvement were treated with definitive radiation therapy alone at Gunma University Hospital. All patients were treated with once-daily standard fractionation using 10 MV X-rays. The total dose ranged from 60 Gy to 80 Gy. The actuarial 2- and 5-year survival rates of the entire group were 43% and 20%, respectively with a median survival time of 19 months. The survival of 76 patients with stage T2 tumors was significantly better than that of 28 patients with T3 tumors (mean survival time 21 versus 15.5 months; p<0.05). Sixty-two patients with tumors less than 5 cm in diameter had a 2-year progression rate of 20%, in comparison with 39% of 54 patients with tumors greater than 5 cm. The difference of survivals for these 2 groups was statistically significant. Twelve patients given a total dose ...
More than 200 years after the birth of the steam engine, the first thermal engine ever invented, thermal engines such as steam turbines, gas turbines or internal combustion engines are still driving most generators for electric power generation, most machines, and most vehicles, and this will remain so until far into the next century. (orig.) [Deutsch] Mit Waermekraftmaschinen wie Dampfturbinen, Gasturinen und Verbrennungsmotoren werden auch heute - mehr als 200 Jahre nach der technischen Reife der Dampfmaschine (der ersten Waermekraftmaschine) - die meisten Generatoren zur Stromerzeugung, die meisten Arbeitsmaschinen und die meisten Fahrzeuge angetrieben. Und dabei wird es auch bis weit in das 21. Jahrhundert bleiben. (orig.)
Only two types of 110-kV-cables: Namely XLPE-Cables and External-Gas-Pressure-Cables will be reinstalled in the Federal Republic of Germany. XLPE-Cables have been already developed for higher voltages. An idea how the external-gas-pressure-cable could be made fit for higher voltage levels will be given in this paper. (orig.) [Deutsch] In der Bundesrepublik Deutschland werden in der Zukunft nur noch zwei Kabeltypen der 110-kV-Ebene den Kabelmarkt beherrschen, naemlich: VPE-Kabel und Gasaussendruck-Kabel. Waehrend VPE-Kabel auch fuer hoehere Spannungsebenen bereits entwickelt worden sind, wird im folgenden vorgeschlagen, wie auch das Prinzip der Gasaussendruck-Kabel zu hoeheren Spannungen hin erweitert werden kann. (orig.)
Zusammenfassung Das Konzept der ?quivalenten Spannung (Vergleichsspannung) wird seit langem angewendet und hat sich bew?hrt. Ein wesentlicher Grund daf?r liegt darin, dass es u.?a. bei der Formulierung ph?nomenologischer Werkstoffmodelle weiterhilft. Von Nachteil ist, dass es weder mit physikalischen Prinzipien in Verbindung steht, noch Informationen ?ber die Mikrostruktur des Werkstoffs enth?lt. Trotzdem wurden zahlreiche Hypothesen zur Formulierung von ?quivalenten Spannungen in der Vergangenheit aufgestellt und in der Praxis mit unterschiedlichem Erfolg angewendet. Als Basis f?r die Systematisierung der zahlreichen Modelle hat Yu die Unified Strength Theory (UST) vorgeschlagen. Diese eignet sich, u.?a. inkompressibles inelastisches Materialverhalten sowie kompressible Werkstoffe mit unt...
The present contribution focuses on the input side of individual process techniques. It shows on the basis of example calculations how two parameters describing the incinerable (residual) waste that are of particular importance for unconventional thermal treatment methods, namely ``pollutant load`` and ``calorific value``, can be influenced by a recycling stage and then further by mechanical-biological pretreatment. [Deutsch] Im folgenden soll das Hauptaugenmerk auf die Inputseite zu den einzelnen thermischen Verfahren gelegt werden und anhand einer Beispielrechnung aufgezeigt werden, wie sich die fuer einen Einsatz in nichtkonventionellen thermischen Verfahren besonders wichtigen Parameter des aufbereiteten (Rest)Abfalls `Schadstoffbelastung` und `Heizwert` zunaechst durch eine Verwertung und weiter durch eine mechanisch-biologische Vorbehandlung veraendern. (orig./SR)
Against the background of more severe limitation of particle emission in all application areas of Diesel engines, it is necessary to monitor the particle emission, but also the chemical composition of the particles. The basis of assessing particle emission is formed by gravimetric determination of the particle concentration from exhaust gas diluted with particle-free ambient air, with a maximum temperature of 52 degrees C at the sampling position. While it is already possible, using the part flow dilution system, to take samples locally, previously the subsequent particle determination and characterisation could only be done in a chemical laboratory. For this reason, the C/S particle measurement process was developed as an alternative to gravimetry, which can be used locally, eg: on ships and which makes it possible to determine the particle mass and composition. This process is based on a thermographic carbon and sulphate determination. Comparative investigations were done both on ...
The research project aimed at the selection or development of wear-reducing measures for submerged components of hydroelectric power plants. This comprised the optimisation of hydraulic profiles as well as materials testing for abrasion and cavitation. Another field of research was the development of appropriate application processes. (orig.) [German] Das Hauptziel des Forschungsvorhabens bestand in der Auswahl bzw. Entwicklung geeigneter Schutzmassnahmen zur Verschleissminderung an wasserberuehrten Komponenten von Wasserkraftanlagen. Diesem Ziel untergeordnet waren neben der Optimierung hydraulischer Profile auch Materialuntersuchungen hinsichtlich Verschleissbestaendigkeit gegenueber Abrasion und Kavitation. Ebenso war die Entwicklung geeigneter Applikationsprozesse ein wichtiger Bestandteil der Aufgabenstellung. (orig.)
In certain regions of the sea floor, water and methane from organic depositions have turned into a burnable form of ice, i.e. methane hydrates which contain more stored energy than all fossil fuel reserves. If they should desintegrate as a result of global heating, methane will be released and will contribute to further global heating. [Deutsch] Im Boden bestimmter Meeresregionen haben sich Wasser und Methan aus organischen Ablagerungen zu einer brennbaren Form von Eis vereinigt. Diese Methanhydrate speichern mehr Energie als alle fossilen Brennstoffvorraete. Wenn sie sich bei einer globalen Erwaermung zersetzen, koennte das entweichende Methan als Treibhausgas die Erde noch mehr aufheizen. (orig.)
High temperature components of power plants are in many cases subjected to variable loading conditions such as cyclic creep or strain cycling. Therefore the cyclic behaviour of important heat resistant steels has been investigated under stress control and to a smaller extent under strain control. The behaviour under cyclic creep rupture conditions was determined in long term experiments covering a wide range of loading conditions. This behaviour can be described with the modified life fraction rule and a factor concept of relative life for single stage cycles and additionally with a multistep hypothesis for multi-stage cycles. The description can be adapted to estimate the life consumption under service type random conditions. The strain cycling behaviour was investigated in regard to the conditions of the heated surface of large components. To simulate this type of loading and to generate long term creep fatigue data, a service type strain cycle was developed. Anisothermal and ...
This conference report contains the lectures presented at the BMBF status seminar on the cooperative project ``Bodies of landfills``, which took place at Wuppertal on 25th and 26th April 1995. The cooperative project was started in autumn 1993 and studies the long-term behaviour of wastes deposited at landfills in general. Inorganic and municipal wastes are studied separately. (orig./SR) [Deutsch] Der vorliegende Tagungsband enthaelt die Vortraege des BMBF-Statusseminars zum Verbundvorhaben `Deponiekoerper` vom 25. und 26. April 1995 in Wuppertal. Das Verbundvorhaben `Deponiekoerper` wurde im Herbst 1993 begonnen und befasst sich ganz generell mit dem langfristigen Deponieverhalten von Abfaellen. Es ist unterteilt in die Untersuchung von anorganischen Abfaellen und von Siedlungsabfaellen. (orig./SR)
In this work was made an assessment of the supramolecular structures presents into human breast tissue normal and pathological samples, as well as into two types of animals samples (tendon chicken and pork fat) using the small angle x-ray scattering (SAXS) technique. The scattering profiles of the samples were determined at the momentum transfer range O.150nm{sup -1}<=5:q(=4pi.sin({theta}/2)/{lambda})<=8.500nm{sup -1}. In this range, it was possible identify structures corresponding to collagen fibrils (glandular tissue) and to triacylglycerides (adipose tissue) from the correlation between the information extracted from the human breast tissues scattering profiles and those extracted from animals samples. (author)
Knowledge, assessment and understanding of phenomena caused by ageing, together with systematic utilization and extension of the technical life-time of components and systems, are of critical importance to the safety and economy of electricity generation in nuclear power stations. Economic use can be optimized by integrated ageing and life-time management; it can also be used to improve performance characteristics. (orig.) [Deutsch] Fuer die Sicherheit und Wirtschaftlichkeit der Stromerzeugung in Kernkraftwerken sind die Kenntnis, Bewertung und Beherrschung alterungsbedingter Phaenomene und systematische Ausnutzung bzw. Verlaengerung der technischen Lebensdauer der Komponenten und Systeme von zentraler Bedeutung. Durch ganzheitliches Alterungs- und Lebensdauermanagement, das auch auf die Verbesserung von Leistungsmerkmalen abzielt, kann der wirtschaftliche Nutzen optimiert werden. (orig.)
The solvent extraction of europium(III) into solutions of thenoyltrifluoroacetone and benzoic acid in cyclohexane, carbon tetrachloride, benzene, chloroform, pentachloroethane, and tetrachloroethane has been measured at 25/sup 0/ C. It has been found that the extracted species involve two types of adducts, EuA/sub 3/HB and EuA/sub 3/ . 2HB where A denotes the TTA anion and HB the benzoic acid monomer. The magnitude of the adduct formation constants in different solvents has been correlated with the dimerization constants of benzoic acid in the solvents. 2 figures, 2 tables.
Nuclear grade production tubing of Alloy 600 was evaluated for stress corrosion cracking (SCC) susceptibility in high purity water at 365, 345, 325, and 290 C. Reverse tube U-bend specimens provided crack initiation data and constant extension rate tests were employed to determine the crack velocities experienced in th crack propagation stage. Initial results indicate that a linear extrapolation of data received from high temperature tests can be used to predict the service life of steam generator tubing that has been plastically deformed or is continually deforming by ''denting.''.
The ion mobilities of |"2"1"1At|At(I) in dependence on thiourea (tu) concentration, iodide concentration and a mixture of both ligands were measured by the electromigration method in free electrolytes. An equilibrium model was developed for the characterization of electromigration curves which permitted the calculation of stability constants and ion mobilities of the complexes |AtI|, |AtI_2|"-, |Attu|"+, |Attu_2|"+ and |AtItu| existing in these solutions. Ethanol and water served as solvents. The temperature was 298 K and the ionic strength was about 0.05 mol/dm"3. (author) 16 refs.; 2 figs.
The Bragg Curve Spectrometer (BCS) is an ionization chamber long enough to stop particles of interest. Particles enter through the cathode window and leave an ionization track parallel to the electric field. The ionization electrons drift through a Frisch grid and are collected on an anode. The anode current, as a function of time, is split and used as input for two amplifiers, one with a long integration time constant for energy measurement, and one with a short time constant to pick off the maximum ionization or Bragg peak. The Bragg peak, which is proportional to the nuclear charge, is used for particle identification. We have constructed and tested several versions of the BCS. The results are described.
The Bragg Curve Spectrometer (BCS) is an ionization chamber long enough to stop particles of interest. Particles enter through the cathode window and leave an ionization track parallel to the electric field. The ionization electrons drift through a Frisch grid and are collected on an anode. The anode current, as a function of time, is split and used as input for two amplifiers, one with a long integration time constant for energy measurement, and one with a short time constant to pick off the maximum ionization or Bragg peak. The Bragg peak, which is proportional to the nuclear charge, is used for particle identification. We have constructed and tested several versions of the BCS. The results are described.
Pionier-I is a vertical axis wind turbine (VAWT) of the Darrieus-type with a diameter of 15 m. In the month of September 1983 performance and efficiency were measured. Measurements were done with constant rotational speed and with constant tip speed ratio. For the calculation of the possible (theoretical) output of electric power an anemometer was present. Measurement results are conditioned to one digital signal and processed by a microcomputer (Apple II). It becomes evident that the yearly energy output of the Pionier-I is quite well comparable with that of a horizontal axis turbine with the same diameter.
Hydrogen piston engines can be simultaneously optimized for improved thermal efficiency and for extremely low emissions. Using these engines in constant-speed, constant-load systems such as series hybrid-electric automobiles or home cogeneration systems can result in significantly improved energy efficiency. For the same electrical energy produced, the emissions from such engines can be comparable to those from natural gas-fired steam power plants. These hydrogen-fueled high-efficiency, low-emission (HELE) engines are a mechanical equivalent of hydrogen fuel cells. HELE engines could facilitate the transition to a hydrogen fuel cell economy using near-term technology.
The heat transfer characteristics of a newly developed transport and storage cask for vitrified heat-producing radioactive waste from reprocessing are described. The theoretical layout of the cask was tested by measurements on a prototype cask of the scale 1:1. These measurements confirmed the theoretical thermodynamic layout data. They can be described by the function Nu=CxRa"m, with the constant C, but not the constant m, differing for a vertical and a horizontal position of the cask. The measured velocity and temperature profiles of the cask were verified with an existing code for the calculation of heat transfer from finned horizontal cylinders by natural convection. (orig.).
By employing the higher dimensional version of the Wu-Yang Ansatz we obtain magnetically charged new black hole solutions in the Einstein-Yang-Mills-Lovelock (EYML) theory with second ($\\alpha2$) and third ($\\alpha3$)order parameters. These parameters, where $\\alpha2$ is also known as the Gauss-Bonnet parameter, modify the horizons (and the resulting thermodynamical properties) of the black holes. It is shown also that asymptotically, these parameters contribute to an effective cosmological constant -without cosmological constant- so that the solution behaves de-Sitter (Anti de-Sitter) like.
We explore the features of Flatte-like parametrizations. In particular, we demonstrate that the large variation in the absolute values of the coupling constants to the {pi}{eta} (or {pi}{pi}) and K anti K channels for the a{sub 0}(980) and f{sub 0}(980) mesons that one can find in the literature can be explained by a specific scaling behaviour of the Flatte amplitude for energies near the K anti K threshold. We argue that the ratio of the coupling constants can be much better determined from a fit to experimental data. (orig.)
We present results from ab-initio electronic-structure calculations of mechanical properties of the rhombohedral phase of vanadium reported in recent experiments (R Ia), and other predicted high-pressure phases (R Ib and bcc), focusing on properties relevant to dynamic experiments. We find that of the three transitions the largest volume collapse (1.3%) is for the R Ia to R Ib transition. Calculations of the single crystal and polycrystal elastic constants reveal a remarkably small discontinuity across the phase transitions even at zero temperature where the transitions are first order.
If quantum fields exist in extra compact dimensions, they will give rise to a quantum vacuum or Casimir energy. That vacuum energy will manifest itself as a cosmological constant. The fact that supernova and cosmic microwave background data indicate that the cosmological constant is of the same order as the critical mass density to close the universe supplies a lower bound on the size of the extra dimensions. Recent laboratory constraints on deviations from Newton's law place an upper limit. The allowed region is so small as to suggest that either extra compact dimensions do not exist, or their number is about to be tightly constrained by experimental data.
If quantum fields exist in extra compact dimensions, they will give rise to a quantum vacuum or Casimir energy. That vacuum energy will manifest itself as a cosmological constant. The fact that supernova and cosmic microwave background data indicate that the cosmological constant is of the same order as the critical mass density to close the universe supplies a lower bound on the size of the extra dimensions. Recent laboratory constraints on deviations from Newton's law place an upper limit. The allowed region is so small as to suggest that either extra compact dimensions do not exist, or their properties are about to be tightly constrained by experimental data.
Abstract in english A simplified model for drying solids in the constant rate period in a batch fluidised bed was developed.It assumes the bed to be divided into dense and bubble phases with heat and mass transfer between the phases.The model predicts the constant-rate drying period, provided the fluid bed shape and material characteristics are known.The model is compared with experimental data reported in the literature covering a wide range of materials, gas flow rates, column diameters, m (more) aterial hold-ups, air temperatures and humidities.Model predictions compare satisfactorily with the experimental data.
A comparative study has been performed to compare the 30 wt% of 2-amino-2-methyl-1-propanol (AMP) aqueous solution and 30 wt% of methyldiethanol amine (MDEA) aqueous solution to capture carbon dioxide contained in the flue gas stream. The equilibrium constants for each electrolyte reactions have been used to estimate the carbon dioxide absorption process. Henry's constants for each binary pairs between solute gases and solvent have been used to estimate solubility of the gas components.
Thermally stable materials with low dielectric constant (k<3.9) are being hotly pursued. They are essential as interlayer dielectrics/intermetal dielectrics in integrated circuit technology, which reduces parasitic capacitance and decreases the RC time constant. Most of the currently employed materials are based on silicon. Low k films based on organic polymers are supposed to be a viable alternative as they are easily processable and can be synthesized with simpler techniques. It is known that the employment of ac/rf plasma polymerization yields good quality organic thin films, which are homogenous, pinhole free and thermally stable. These polymer thin films are potential candidates for fabricating Schottky devices, storage batteries, LEDs, sensors, super capacitors and for EMI shielding. Recently, great efforts have been made in finding alternative methods to prepare low dielectric constant thin films in place of ...
The RCP method was designed as a residue-optimised alternative to the thermally optimised grate firing of residual wastes. Its technical realisation and development to market maturity took no more than 5 years. In the first process stage the waste is converted to high-carbon pyrolysis charcoal and high-rank gas in the absence of oxygen. In the second stage these substances are oxidised by addition of oxygen. The resulting temperature causes the non-combustible constituents of the slag to melt. In a third, optional, stage this molten slag can be liberated of (heavy) metals to such an extent that it can subsequently be used directly as additive for grinding. Further exhaust gas treatment is facilitated by the use of a circulatory fluidised-bed secondary combustion chamber. Despite the reduced flue gas volume and resultant higher pollutant concentrations in the crude gas, overall emissions are lower than in conventional plants. [Deutsch] Das reststoffoptimierte RCP ...
The time-temperature-precipitation diagrams and the resulting time-temperature-sensitization diagrams have been established and are presented for today's current nickel-chromium-molybdenum alloys C-4, C-276, 22 and the recently developed alloy 59. Compared to those materials alloy 625 behaves differently due to its high niobium content. In addition, also the precipitation and sensitization of alloy G-3 has been established. Under the materials considered alloy C-276 has the strongest tendency to precipitate the intermetallics Mu and P together with the carbide M{sub 6}C at intermediate temperatures, followed by the alloys 22 and 59. The tendency to sensitization in the sense of the 50{mu}m (2 mils) intercrystalline penetration criterion when exposed to the ASTM G-28, method A test solution is greatest with alloy C-276, and decreases over the alloys 22, 59 and G-3 to alloy 625. Sensitization is caused by precipitation of the intermetallics {mu} and P and the carbide M{sub 6}C ...
The VerTech Pit Method for wet oxidation of municipal sewage sludge offers an ecologically and economically advantageous alternative for dealing with sewage and special sludges. Europe`s first commercial plant has now been commissioned in Apeldoorn in the Netherlands following industrial-scale trials in the USA. Up to its present stage of operation the plant has achieved a high degree of reduction of solid residues and a favourable resource and environmental profile, thus impressively confirming earlier results. It is amply in keeping with the landfill criteria laid down in the Household Waste Technical Code. Furthermore, the potential sludge throughput has been found to exceed the projected value. [Deutsch] Mit dem VerTech-Tiefschachtverfahren zur Nassoxidation kommunaler Klaerschlaemme steht ein alternatives Verfahren zur Behandlung von Klaer- und Sonderschlaemmen zur Verfuegung, das oekologische und wirtschaftliche Vorteile aufweist. Nach grosstechnischer ...
The aim of the study was to establish by means of a measuring programme how much energy for space heating can be saved by the installed hybrid system. Further, experience with the systems was to be gathered under practical use conditions. As user behaviour can influence space heating energy consumption to an extent having several times the effect of the contribution of the hybrid system, a fact that is also reported in literature, it is not sufficient to measure only space heating energy consumption. So, a unit in one of the terraced houses was scrupulously measured. In the three other terraced houses, only space heating energy consumption was measured.- This final report contains not only a description of the concepts of the buildings and hybrid system but also the energy consumptions measured, and detailed analyses of the budgets. (orig./AKF) [Deutsch] Mit Hilfe eines Messprogrammes sollte ermittelt werden, welche Heizwaermeeinsparung durch das installierte ...
The regenerator of Stirling cycle machines has an relatively unknown potential for thermal shorting, because the thermal flow path within the solid of a randomly stacked wire mesh, which is defined by its 'connectivity', is unknown. Earlier publications have shown two principles of experimental techniques to quantify connectivity. One quantifies connectivity as a function of axial pressure using the electric current analogy, the other measures connectivity via the temperature gradients along a regenerator and a series-connected reference body of known conductivity. Both papers offer preliminary results of reduced usefulness related to the testing method or setup. This contribution describes a new setup and its technique, which results from the practical knowledge and experience of the first two attempts, and aims for an improved determination of connectivity of the original representative Stirling regenerators with and without housing. Please contact the author for ...
A phenomenological model of the heat transfer in direct injection diesel engines was developed. Utilizing the thermodynamic results of a combustion model as an input, the model is able to predict the temporal variation of the heat losses from the cylinder gas to the cylinder walls. Additionally, the division into isothermal combustion chamber subsurfaces allows the consideration of the spatial variation of the wall heat fluxes. The physical mechanisms such as flow dependent convection, heat radiation due to hot soot particles and isolation effects of deposited soot layers are described in detail. Thus the effects of these mechanisms on the overall heat transfer can be studied. The heat transfer model was verified successfully by the comparison to measured wall heat fluxes in a single-cylinder direct injection diesel engine. It is shown that the effects of engine speed and load, turbocharging and soot deposition can be predicted with good accuracy. [German] Es wurde ein ...
In coke-oven operations flue-gas valves are used to switch the regenerator function from rich gas firing to lean gas firing. Compared with the simple geometry of the other parts of the flow path, which comprise flues and regenerators, the narrow and winding passages of the flue-gas valves give rise to relatively high losses in pressure. Without the construction of high (and therefore expensive) chimneys, this means that operating problems may well arise due the inadequate suction capacity. The project focused on the theoretical and experimental analysis of a coke-oven flue-gas valve. The primary aim was to reduce the pressure drop through the valve without modifying its external geomerty. The internal flow characteristics created by different valve geometries under a variety of operating conditions were simulated using the commercial CFD code Fluent/UNS, which provided velocity and pressure distributions. A half-scale model valve was constructed in order to characterise the internal ...
The first quarter 1982 report summarizes the operating and test data obtained at the six ton per day Advanced Coal Liquefaction Research and Development Facility in Wilsonville, Alabama. The Wilsonville R and D Facility was in operation 52% of the period with scheduled shutdowns accounting for 33% of the downtime. Illinois 6 coal from the Burning Star No. 2 mine was processed during Run 236. The three process units of the Wilsonville facility were operated in a non-integrated mode to evaluate process parameters and to test equipment and operating modifications. Data were obtained in the following areas: In the SRC Unit: operation at low severity reaction conditions for single stage liquefaction with a high LSRC recycle rate using Illinois 6 coal; process solvent activity control; and preliminary feeding tests with hydrotreated SRC as a replacement for LSRC in the process solvent. In the CSD Unit: operation with T102 Vacuum Column bottoms produced at low severity reaction conditions ...
The position paper will provide the basis for further strategies on offshore wind power development in consideration of ecological and conservation aspects. [German] Das Positionspapier des Bundesministeriums fuer Umwelt, Naturschutz und Reaktorsicherheit (BMU) einschliesslich des Umweltbundesamtes (UBA) und des Bundesamtes fuer Naturschutz (BfN) ist Ergebnis der Arbeiten der BMU-Projektgruppe 'Windenergienutzung im Offshore-Bereich im Hinblick auf die BMU-Anliegen'. Es beschreibt den derzeitigen Stand einer Strategie zur umwelt- und naturvertraeglichen Erschliessung der Windenergienutzung auf See (Offshore). Es bildet die Grundlage fuer die Weiterentwicklung dieser Strategie und dabei insbesondere zur Abstimmung mit den Anliegen anderer Bundesressorts und den Kuestenlaendern, sowie zur intensiveren Einbeziehung beteiligter Verbaende und Fachkreise. Vor dem Hintergrund der zur Genehmigung eingereichten Antraege fuer Offshore-Windparks, mangelnder ...
In an extended case report, we discuss four cases with masses in the lacrimal fossa representing the most important entities in this region (lymphoma, pleomorphadenoma, inflammatory pseudotumor, and malignant epithelial tumor). The different indications for CT and MRI are explained. For the differential diagnosis of lacrimal gland lesions, the following imaging parameters are important: The shape of the lacrimal gland, the inner structure, the degree of contrast enhancement, and the surrounding bony structures. In the evaluation of the expansion of lacrimal gland lesions, CT in thin slices with multiplanar reconstructions is equal to MRI. However, the contrast-enhancement of lacrimal glands is better evaluated with MRI than with CT. The bony structures are better visualized on CT than on MRI. (orig.) [Deutsch] In einem erweiterten Fallbericht wird ueber die vier grossen Entitaeten bei Traenendruesenraumforderungen berichtet (Lymphom, pleomorphes Adenom, entzuendlicher Pseudotumor und ...
Buildings in the USA are commonly not perceived as energy efficient and sustainable. Considering this, it comes as a surprise that the LEED (Leadership in Energy and Environmental Design) certification system is leading the process to certify ''Green Buildings'' despite the broad range of certification systems in countries such as BREEAM in England, CASBEE in Japan, HQE in France, Green Star in Australia, and most recently DGNB in Germany. International companies are pursuing the LEED certification due to its worldwide applicability - over 20,000 buildings in 76 countries are currently registered. (Abstract Copyright [2009], Wiley Periodicals, Inc.) [German] Die USA sind nicht gerade fuer oekologisches und energieeffizientes Bauen bekannt. Umso erstaunlicher ist es, dass das LEED-Zertifizierungssystem (Leadership in Energy and Environmental Design) neben anderen landesspezifischen Systemen wie z. B. BREEAM in England, CASBEE in ...
In order for fuel cells to be successful, a full-scale hydrogen infastructure is required. The HyTra concept is presented here (HYdrogen TRAnsform, Transfer and TRAnsport) involves combined production, storage and supply of hydrogen in a transportable trailer, i.e. it is both a hydrogen production unit and a mobile filling station. The trailer can be transported to the selected site, where it will produce gaseous hydrogen from electricity and water by electrolysis. A compressor pumps the gas into an internal pressure tank and compresses it to filling pressure. Filling takes place by the overflow principle via a flexible high-pressure line with a standardised H{sub 2} filling unit. (orig.) [German] Um die Marktdurchdringung der Brennstoffzellentechnik gewaehrleisten zu koennen, muss eine flaechendeckende Wasserstoffinfrastruktur aufgebaut werden. Das neue HyTra-Konzept (HYdrogen TRAnsform, TRAnsfer and TRAnsport) beruht auf der Kombination von Wasserstoff-Erzeugung, ...
High oleic acid sunflower oils have been commercially available for some years now. Due to their high content of monounsaturated fatty acids these oils have a number of potential applications in the oleochemical industry, especially where technical oleic acids and their derivatives are used. Whereas conventional sunflower oil contains approx. 68% linoleic acid (C{sub 1}8:2), it is now possible through breeding measures to obtain ''new sunflower oils'' (NSb oils) with oleic acid levels of 70-95% oleic acid (C{sub 1}8:1). The oil itself is of interest for technical applications: it is light-coloured, has a neutral odour and is relatively resistant to oxidation. Plant oils, especially those with a low content of polyunsaturated fatty acids, are increasingly gaining interest as ester oils in technical application areas, e.g. as lubricants. However, there are limits to the technical applicability of triglycerides due to their temperature behaviour or ...
Alloyed steels containing retained austenite after martensitic hardening are widely applied in technical practice. Although many practical investigations have been made into the mechanical behaviour of composite microstructures with retained austenite, there is still a lack of knowledge concerning their fatigue and crack propagation behaviour. For this reason, the author investigated the effects of retained austenite concentration and stability on the transformation and deformation behaviour of hardened states of the steels X210Cr12 and 100Cr6. For this purpose, monotone tensile tests, cyclic tensile pressure tests, and supplementary crack propagation experiments were carried out. The concentrations of retained austenite were varied between 10 and 100% by volume by means of different heat treatments. [Deutsch] Legierte Staehle, die nach martensitischer Haertung noch Restaustenit enthalten, finden in der technischen Praxis verbreitete Anwendung. Zum mechanischen Verhalten von ...
In addition to dependable starting - even at extreme sub-zero temperatures - the starting behaviour of modern commercial vehicle diesel engines is increasingly being evaluated on the basis of HC emissions in the starting and warm-up phases. To improve their performance in this respect, most small and medium-sized diesel engines (with a capacity of 3 to 12 litres) are therefore equipped with intake air heating systems. As an alternative to high-performance, fuel-burning flame start systems, the automotive industry supplier Beru has now developed a new type of self-regulating electric heating element which not only ensures dependable starting with short heating times but also allows drastic reductions in HC emissions. (orig.) [Deutsch] Das Startverhalten moderner Nutzfahrzeug-Dieselmotoren wird, ergaenzend zum Hauptmerkmal des sicheren Starts auch bei extremen Minustemperaturen, zunehmend anhand der HC-Emission in der Start- und Warmlaufphase beurteilt. Zur ...
The intermetallic phase NiAl is a potential material for high-temperature applications; however, its technical application was prevented so far by its high brittleness at room temperature. This problem may be solved by incorporating relatively high-ductility particles into the NiAl matrix. Controlled crack propagation experiments, tensile and pressure tests were carried out in order to analyze the toughness and deformation characteristics of NiAl composite materials containing niobium or molybdenum particles at room temperature and in ambient atmosphere. Both the niobium and the molybdenum particles increase the toughness as compared to the pure NiAl matrix, but no ductilisation was observed in the composite materials investigated. Model experiments in consideration of experimental data suggest, hovewer, that the toughness and ductility of NiAl may be enhanced by optimizing the microstructural and production parameters of the incorporated ductile particles. (orig.) [Deutsch] Die ...
Pulmonary infections and tumors are a major cause of death in patients with AIDS. The combination of clinical, radiological, laboratory, and pathohistological data helps to narrow the spectrum of differential diagnoses or even allows a specific diagnosis in many patients. Nevertheless, an accurate diagnosis should be obtained as soon as possible during the clinical course of the illness to initiate treatment in time. Computed tomography (CT) has proven to provide promising results in the diagnosis of AIDS-related throacic diseases. The aim of this paper was to demonstrate the diagnostic capacities of CT in the context of particular AIDS-related thoracic pathologies. Additional information on the spectrum of pathological agents and on differential diagnostic signs is summarized. (orig.) [Deutsch] Pulmonale Infektionen und Tumore sind eine wesentliche Todesursache bei Patienten, die am erworbenen Immunmangelsyndrom AIDS leiden. In den meisten Faellen gelingt es, durch Zusammenschau ...
A model for combined mass and heat transfer during nonisothermal gas absorption in a two-phase gas- liquid bubbly medium with a high gas content and/or large times of gas-liquid contact is suggested. Diffusion and thermal interactions between bubbles is taken into account in the approximation of a cellular model of a bubbly medium whereby a bubbly medium is viewed as a periodic structure consisting of identical spherical cells with periodic boundary conditions at a cell boundary. Distribution of concentration of dissolved gas, temperature distribution in liquid and coefficients of mass and heat transfer during nonisothermal absorption of a soluble pure gas from a bubble by liquid are determined. In the limiting case of absorption without heat release the derived formulas recover the expressions for isothermal absorption. (orig.). With 1 fig., 1 tab. [Deutsch] Es wird ein Modell vorgestellt, das den kombinierten Waerme- und Stoffaustausch waehrend der ...
The precipitation of heavy metals as hydroxides is the standard technique for the decontamination of waste water streams polluted by these elements. On the other side, progress in research has been made concerning the biosorption onto dead biomass and bioprecipitation supported by physiologically active bacteria. As the aim of this study, a flexible strategy has been envisaged cleaning a waste water with definite heavy metal load underlying the process mentioned above. Suitable bacteria were enriched and the process was tested in a technical plant. As result, a very high efficiency of heavy metal elimination has been found. The field of application covered by the acquired process is identical with the whole range of the waste water streams polluted by heavy metals. In addition, a second stage may be necessary if there are any further contaminants to be removed. (orig.) [Deutsch] Bei der Reinigung von schwermetallhaltigen Abwaessern ist der derzeitige Stand der Technik gegeben durch die ...
The `biotechnology 2000` project is supervised by the project sponsor `biology, energy, ecology` at Forschungszentrum Juelich on behalf of the Federal Ministry for Research and Technology. The project activities cover the development of techniques and methods, cell biology, gene structure and gene regulation, photosynthetic production processes, biological hydrogen production, synthetic biology, protein design, neurobiological research, biosystems, plant breeding, phytomedicine and plant protection, the biology of waste disposal methods, research into methods which replace animal experiments, biological safety research, technology risk assessment, and ethical aspects. A general survey introduces the promoted projects, and standardized data sheets briefly introduce the individual activities. The appendix gives the project indices, the indices of joint projects, a list of the supported companies and institutions, and the project sponsor flowsheet. (orig.) [Deutsch] ...
Transients induced in nuclear power plants from many sources result in one or more fluid conditions changing with time. Fluid conditions of pressure, inlet temperature, inlet flow, or even system power many change separately or in conjunction with each other. The result of the condition change may be one which induces departure from nucleate boiling. An experimental investigation of transient which were intended to achieve Critical Heat Flux was performed at the Heat Transfer Research Facility of Columbia University for Siemens Nuclear Power Corporation. The transients were set up to include broad ranges of flow and pressure conditions near the operating range of pressurized water reactors. Transient events were dominated by varying single conditions and measuring the response of the system and of the rod thermocouples. Because of coupling effects within the test loop, secondary conditions would also vary. In order to perform controlled tests which achieved the desired result, CHF ...
The quenched chiral logarithms are examined on a 163x28 lattice with Iwasaki gauge action and overlap fermions. The pion decay constant fpi is used to set the lattice spacing, a = 0.200(3) fm. With pion mass as low as {approx}180 MeV, we see the quenched chiral logarithms clearly in mpi2/m and fP, the pseudoscalar decay constant. The authors analyze the data to determine how low the pion mass needs to be in order for the quenched one-loop chiral perturbation theory (chiPT) to apply. With the constrained curve-fitting method, they are able to extract the quenched chiral logarithmic parameter delta together with other low-energy parameters. Only for mpi<=300 MeV do we obtain a consistent and stable fit with a constant delta which they determine to be 0.24(3)(4) (at the chiral scale Lambdachi = 0.8 GeV). By comparing to the 123x28 lattice, they estimate the finite volume effect to be about 2.7% for the smallest pion ...
The quenched chiral logarithms are examined on a 163x28 lattice with Iwasaki gauge action and overlap fermions. The pion decay constant fpi is used to set the lattice spacing, a = 0.200(3) fm. With pion mass as low as #approx#180 MeV, we see the quenched chiral logarithms clearly in mpi2/m and fP, the pseudoscalar decay constant. The authors analyze the data to determine how low the pion mass needs to be in order for the quenched one-loop chiral perturbation theory (chiPT) to apply. With the constrained curve-fitting method, they are able to extract the quenched chiral logarithmic parameter delta together with other low-energy parameters. Only for mpi<=300 MeV do we obtain a consistent and stable fit with a constant delta which they determine to be 0.24(3)(4) (at the chiral scale Lambdachi = 0.8 GeV). By comparing to the 123x28 lattice, they estimate the finite volume effect to be about 2.7% for the smallest pion mass. ...
Particle swarm optimization (PSO) is extensively used for real parameter optimization in diverse fields of study. This paper describes an application of PSO to the problem of designing a fractional-order proportional-integral-derivative (FOPID) controller whose parameters comprise proportionality constant, integral constant, derivative constant, integral order (lambda) and derivative order (delta). The presence of five optimizable parameters makes the task of designing a FOPID controller more challenging than conventional PID controller design. Our design method focuses on minimizing the Integral Time Absolute Error (ITAE) criterion. The digital realization of the deigned system utilizes the Tustin operator-based continued fraction expansion scheme. We carry out a simulation that illustrates the effectiveness of the proposed approach especially for realizing fractional-order plants. This paper also attempts to study the ...
Triaxial compression tests following stress paths of constant {sigma}{sub 1} were conducted to determine the shear strength of five processed scrap tire products having different gradations and particle shapes. The interparticle frictional component was separated from the total shear strength according to the energy correction concept proposed by researchers. The experimental results show that all five tire chip products have ultimate internal friction angles of 45{degree} to over 60{degree}. The interparticle frictional component of the strength was fully mobilized and nearly reached a constant value after approximately 5% axial strain. The experimental results confirmed that the strength parameter obtained with constant {sigma}{sub 1} was more reasonable. This finding is supported by field observation in which the tire chips have an angle of repose ranging from 37{degree} to 43{degree} (loosely stock piled) and up to ...
The kinetics of calcium sulfate crystal growth is of importance in various fields, such as geochemistry, desalination technology, petroleum industry, and water and wastewater treatment. The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90 C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO[sub 4]H[sub 2]O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was similar to the crystal solubility behavior in aqueous ...
We present results from a comprehensive number of relativistic, time-dependent, axisymmetric simulations of the runaway instability of non-constant angular momentum thick discs around black holes. This second paper extends earlier results where only constant angular momentum discs were considered. All relevant aspects of the theory of stationary thick discs around rotating black holes, necessary to build the initial state in our simulations, are presented in great detail. The angular momentum of the discs is assumed to increase outwards with the radial distance according to a power law. The main simplifying assumptions of our approach are not to include magnetic fields and self-gravity in the discs. Furthermore, the dynamics of the spacetime is accounted for by computing the transfer of mass and angular momentum from the disc to the black hole through the event horizon : the evolution of the central black hole is assumed to follow a sequence of ...
Stress corrosion cracking tests in constant extension rate tensile (CERT) and constant load tensile (CLT) tests were conducted on Ni-xCr- 9Fe-yC in Ar, water, and a LiOH-boric acid solution. Cr and C improve the resistance of Ni-base alloys to IG cracking in both Ar and water at 360C. Since creep plays a role in IG cracking, one possible explanation for the role of the environment involves its effect on the creep. Experiments were conducted on the role of C in the deformation behavior and failure mode of Ni-16Cr-9Fe. Constant load experiments were conducted on Ni-16Cr-9Fe to determine if the CLT test is more aggressive than CERT. The electron backscattering technique in a SEM is being developed in order to extend the IG cracking studies to grain sizes typical of commercial alloys, 20-30 microns.
Stress corrosion cracking tests in constant extension rate tensile (CERT) and constant load tensile (CLT) tests were conducted on Ni-xCr- 9Fe-yC in Ar, water, and a LiOH-boric acid solution. Cr and C improve the resistance of Ni-base alloys to IG cracking in both Ar and water at 360C. Since creep plays a role in IG cracking, one possible explanation for the role of the environment involves its effect on the creep. Experiments were conducted on the role of C in the deformation behavior and failure mode of Ni-16Cr-9Fe. Constant load experiments were conducted on Ni-16Cr-9Fe to determine if the CLT test is more aggressive than CERT. The electron backscattering technique in a SEM is being developed in order to extend the IG cracking studies to grain sizes typical of commercial alloys, 20-30 microns.
The distribution of Cu, Ni, Co and Mn between an aqueous solution of constant ionic strength and Versatic Acid 911 diluted with benzene was investigated. Only one extracted species of Cu was revealed to have a dimeric structure of the composition (CuR_2.RH)_2, while both monomer and dimer were found in the extraction of Ni, Co and Mn. The curve-fitting method was employed to determine these species, from which the composition of the extracted species was found to be NiR_2.4RH and (NiR_2.2RH)_2, CoR_2.4RH and (CoR_2.2RH)_2, and MnR_2.4RH and (MnR_2.2RH)_2, respectively. The apparent equilibrium constants of the above species and those between monomer and dimer were also determined. The curve-fitting method was proved to be a precise method for determining the equilibrium constants and extracted species. (author).
We consider a general, neutral, dynamical model of biodiversity. Individuals have i.i.d. lifetime durations, which are not necessarily exponentially distributed, and each individual gives birth independently at constant rate \\lambda. We assume that types are clonally inherited. We consider two classes of speciation models in this setting. In the immigration model, new individuals of an entirely new species singly enter the population at constant rate \\mu (e.g., from the mainland into the island). In the mutation model, each individual independently experiences point mutations in its germ line, at constant rate \\theta. We are interested in the species abundance distribution, i.e., in the numbers, denoted I_n(k) in the immigration model and A_n(k) in the mutation model, of species represented by k individuals, k=1,2,...,n, when there are n individuals in the total population. In the immigration model, we prove that the ...
In this thesis the rate constants for a number of radical reactions in aqueous solution have been studied in a wide temperature range. The reactions of H with H_2O_2, OH and HO_2 and the reactions of HO_2 with OH, Fe"2"+ and Cu"2"+ have been studied. For each reaction rate constants have been determined as a function of temperature using the technique of high temperature, high pressure (HTP) pulse radiolysis. The rate constants were obtained by fitting a kinetic computer model to the experimental data. From an Arrhenius plot the activation energy of each reaction was determined. The data determined in this way are important for modeling of radiolysis in nuclear light water reactors. A previously developed model for calculation of the effect of water radiolysis products on oxidation and dissolution of spent nuclear fuel has been improved. In the new model, called TraRaMo, simultaneous transport by diffusion and chemical ...
We present a new class of exact solutions of Deser, Jackiw, and Templeton's theory (DJT) of topologically massive gravity which consists of homogeneous, anisotropic manifolds. In these solutions the coframe is given by the left-invariant 1-forms of 3-dimensional Lie algebras up to constant scale factors. These factors are fixed in terms of the DJT coupling constant {mu}m which is the constant of proportionality between the Einstein and Cotton tensors in 3-dimensions. Differences between the scale factors result in anisotropy which is a common feature of topologically massive 3-manifolds. We have found that only Bianchi Types VI, VIII, and IX lead to nontrivial solutions. Among these, a Bianchi Type IX, squashed 3-sphere solution of the Euclideanized DJT theory has finite action, Bianchi Type VIII, IX solutions can variously be embedded in the de Sitter/anti-de Sitter space. That is, some DJT 3-manifolds that we ...
We present a new class of exact solutions of Deser, Jackiw, and Templeton's theory (DJT) of topologically massive gravity which consists of homogeneous, anisotropic manifolds. In these solutions the coframe is given by the left-invariant 1-forms of 3-dimensional Lie algebras up to constant scale factors. These factors are fixed in terms of the DJT coupling constant #mu#m which is the constant of proportionality between the Einstein and Cotton tensors in 3-dimensions. Differences between the scale factors result in anisotropy which is a common feature of topologically massive 3-manifolds. We have found that only Bianchi Types VI, VIII, and IX lead to nontrivial solutions. Among these, a Bianchi Type IX, squashed 3-sphere solution of the Euclideanized DJT theory has finite action, Bianchi Type VIII, IX solutions can variously be embedded in the de Sitter/anti-de Sitter space. That is, some DJT 3-manifolds that we shall ...
Glass-ceramic materials containing 0-60% glass, 0-40% cordierite and 0-40% mullite were developed with dielectric constant lower than of Al{sub 2}O{sub 3} (5.2-6.7). The following glasses were used: SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}, CaO-ZnO-B{sub 2}O{sub 3}, CaO-ZnO-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}, BaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2} and BaO-ZnO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}. The influence of the content of the particular components on the value of dielectric constant of the ceramics was investigated. (author). 9 refs, 3 tabs.
This patent describes a display unit of a speedometer for an automobile, comprising: a constant speed running circuit capable of producing output signals indicative of a desired car speed; an actual car speed operational circuit capable of producing output signals indicative of actual car speed; a comparing circuit for comparing the amplitudes of the output signals of the constant speed running operational circuit and the actual car speed operational circuit; bar graph decoders receiving the output signals from the constant speed running operational circuit and the actual car speed operational circuit; an EX-OR circuit having inputs coupled to respective bar graph decoders and having an output; and OR circuit having inputs coupled to respective bar graph decoders and having an output; selector means coupled to the output of the EX-OR circuit and the output of the OR circuit and controlled by an output of the comparing means ...
This research involves the development of an analysis which yielded recommendations regarding the plate thickness at which the effects of transverse shear become significant enough to be taken into consideration during vibration testing of composite plates. The specimens designed using this analysis are to be used for the {open_quotes}inverse{close_quotes} problem of determining through-the-thickness elastic constants as well as in-plane elastic constants from modal vibration response data. The effects of transverse shear were studied over the range of practical plate aspect ratios (length to thickness ratios) and mode numbers. Behavior of composite plates ranging from isotropic to highly orthotropic was studied in order to investigate the effects of transverse shear. Orthotropic plates having in-plane dimensions of 254 x 254 mm and thicknesses varying from 10 mm to 80 mm, with free-free edge boundary conditions, were considered. A methodology ...
The pulse radiolysis technique has been employed in studying charge-transfer reactions of anionic C{sub 2}O{sub 4}{sup {minus}}, and cationic C{sub 2}O{sub 4}{sup +} species in supercritical carbon dioxide (scCO{sub 2}) over a range of reduced densities {rho}{sub r} = 0.36--1.5 and at a reduced temperature of T{sub r} = 1.03. The absorption spectrum measured in the visible region with a maximum around 700 nm is assigned to the dimer cation C{sub 2}O{sub 4}{sup +}. The pressure dependence of charge-transfer reactions was examined using dimethylaniline (DMA), benzoquinone (BQ), and oxygen as charge acceptors. The reaction rates of DMA with cations, and BQ with anions are at or near the diffusion-controlled limit. The rates decrease an order of magnitude with increase of pressure. The reaction of C{sub 2}O{sub 4}{sup +} with oxygen is much slower with an almost constant rate over the pressure range examined. The measured rate constants of ...
The major purpose of the work described in this report was to use diffusion modeling techniques to calculate the impact on ambient air quality of SO2 emissions from the ASARCO copper smelter in Tacoma, Washington for the existing smelter configuration (51-percent constant emissions control) and for 20 alternative smelter configurations with varying degrees of constant emissions control. The accuracy of the modeling techniques was established by the close correspondence obtained between calculated and observed short-term ground-level SO2 concentrations for 20 selected historical cases, when high hourly SO2 concentrations were measured in the area surrounding the smelter, as well as by the close agreement between calculated and observed annual average concentrations for 1972. The results of the model calculations show that the maximum allowable constant SO2 emission rate consistent with maintaining the Washington Department ...
Purpose: The nint version of the licensing regulation for medical doctors (Approbation Regulation (AR)) sets a benchmark in terms of practical experience, interdigitation of preclinical and clinical studies, interdisciplinary approach, economic efficiency, independence of students, added new teaching and learning modalities, and ongoing evaluation of the progress of the medical students. It is the aim to implement these major points of the AR in a model course for diagnostic radiology and radiation protection within the scope of the Virtual University of Bavaria and test them in practice. Materials and Methods: In cooperation with residents and board certified radiologists, students developed the virtual course 'Web-Based Training (WBT) Radiology' in diagnostic radiology and radiation protection for students in the first clinical semester. A representative target group taken from the student body was asked about the options to get access to the World Wide Web ...
Objective: To determine the reproductibility of three-dimensional volume and thickness measurements of the knee joint cartilage with MRI in volunteers. Methods: The knees of 7 healthy individuals (ages 23 to 58 yrs.) were sagitally imaged with a resolution of 2x0.31x0.31 mm{sup 3}, using a fat-suppressed FLASH-3 D sequence. The knee was repositioned in between replicate acquisitions, 6 data sets being obtained in each case. After semiautomatic segmentation and three-dimensional reconstruction of the cartilage, the thickness was determined independent of the original section orientation. The coefficient of variation for repeated volume measurements and the deviations of the maximal cartilage thickness values were calculated subsequently. Results: The mean variation of the cartilage volumes of the replicate measurements was 1.4% ({+-}0.8%) in the patella, 1.7% ({+-}1.5%) in the femur, 3.0% ({+-}1.2%) in the medial tibial plateau and 3.5% ({+-}2.0%) in the lateral tibial plateau. The ...
The experimental effect investigation programme on Zircaloy-4/air oxidation was pursued and expanded to isothermal specimen exposure and the comparison of the oxidation between the atmospheres Ar/O{sub 2} and air. In close connection with the EC project OPSA, which is meanwhile terminated, the investigation concerned specimen exposure in a thermobalance to flowing atmospheres, namely dry Ar/O{sub 2} of composition 80/20 or synthetic air, respectively. As test parameters the linear heat-up rate was varied in the range 5 to 40 K/min and the ramp or holding temperature between 800 and 1500 C. Mass increase and reaction rate were continuously recorded or evaluated in temperature/time dependence. The oxide scale growth was found to be accompanied by colour changes, crack formation and spalling of layers, as well as by dimensional substrate growth, which are the reasons for the observed kinetic results. The microstructural investigation confirms nitrogen to be essentially responsible for the ...
Purpose: To report on the nephron-sparing, percutaneous ablation of a large renal cell carcinoma by combined superselective embolization and percutaneous radiofrequency ablation. Materials and Methods: A 5 cm renal cell carcinoma of a 43-year-old drug abusing male with serologically proven HIV, hepatitis B and C infection, who refused surgery, was superselectively embolized using microspheres (size: 500 - 700 {mu}m) and a platinum coil under local anesthesia. Percutaneous radiofrequency ablation using a 7F LeVeen probe (size of expanded probe tip: 40 mm) and a 200 Watt generator was performed one day after transcatheter embolization under general anesthesia. Results: The combined treatment resulted in complete destruction of the tumor without relevant damage of the surrounding healthy renal tissue. The patient was discharged 24 hours after RF ablation. No complications like urinary leaks or fistulas were observed and follow up CT one day and 4 weeks after the radiofrequency ...
From autumn this year, the FRJ-2 of the Research Center Juelich will be supplying molybdenum targets to the Institut National des Radioelements in Fleurus, Belgium - which deals in medical radio-isotopes worldwide - thus helping to meet the need for technetium-99, which is used in the medical profession for diagnostic purposes because of its favourable radiological characteristics. Technetium-99 is formed as a result of the radioactive decay of molybdenum-99. For many years now, molybdenum has been produced by the irradiation of uranium in research reactors, so that the initiation of molybdenum production in the FRJ-2 is not especially new. What is unusual, however, are the particular peripheral conditions which result from the combination of the irradiation requirements, a predetermined target design and the technical characteristics of the reactor and which necessitated special solutions. This applies especially to the handling of the targets after irradiation, which is much more ...
Purpose: To determine the diagnostic value of high resolution MR imaging with a circularly polarised (c.p.) body phased-array coil for the staging of pelvic lymph nodes in cervical carcinoma. Material and methods: 42 patients with histologically proven carcinoma of the cervix were studied on a 1.5 T scanner by using a c.p. body phased-array coil. The imaging protocol included T{sub 2}-weighted turbo-spin-echo (TSE) and T{sub 1}-weighted spin-echo sequences pre and post IV application of Gd-DTPA; slice thickness was 5-7 mm and pixel size 0.53 mm{sup 2}. Lymph nodes with a diameter of {>=}8 mm were considered to have metastatic involvement. MR imaging results were compared with histopathologic findings. Results: MR imaging showed enlarged lymph nodes ({>=} 8 mm) in 16 of 18 patients with histologic proof of lymph node metastases (sensitivity 89%). In 22 of 24 cases MR findings were true negative (specificity 92%). Diagnostic accuracy was 91%. Conclusion: High-resolution MR imaging ...
Purpose: The aim of this study was to demonstrate the typical appearance of ganglioneuromas in computer-assisted tomography (CT), and magnetic resonance imaging (MRI). Material and methods: Retrospective analysis of diagnostic imaging (9 CT, 6 MRI) in 9 children aged 3 to 15 years with the histological diagnosis of ganglioneuroma. Results: The tomographies showed large (max. 13.4 cm in diameter) round or oval tumors with sharp delineation. The sites of the tumors were the retroperitoneum (5), the mediastinum (3), and the adrenal gland (1). Intraspinal tumor involvement occurred in 4 cases. On comparing CT with MRI, MRI was more accurate in defining the intraspinal involvement. The ganglioneuromas were of hypodense appearance in the native CT scan and showed moderate enhancement upon administration of contrast media. In five patients tumor calcifications with a disseminated sprinkled pattern were seen in CT. In MRI T{sub 1}-weighted scans the tumors were homogeneous and hypointense, ...
Atomization of liquid fuel in aircraft engines requires application of airblast atomizers, where the kerosene is supplied into the shear layer between two swirling airstreams. The transfer of this functional principle towards gaseous fuel, as illustrated in Fig. 1, yielded a strong influence of the swirl arrangement of the airflows on flame stability and homogeneity of the fuel/air-mixture. Compared to the co-swirl configuration the flow field of the counter-swirl arrangement exhibits a marked increase of the mass flow recirculated in the internal recirculation zone and a reduction of its length in axial direction. This is attributed to the faster decay of tangential velocity maxima in case of counter-rotating airflows. This generates a stronger positive axial pressure gradient dp/dx, thus enhancing the internal recirculation zone. Analysis of local turbulence quantities yields a restriction of turbulent exchange to smaller radial sections and lower maximum values in the jet dominated ...
The observation that Type Ia supernovae are fainter than expected given their red shifts has led to the conclusion that the expansion of the universe is accelerating. The widely accepted hypothesis is that this acceleration is caused by a cosmological constant or, more generally, some dark energy field that pervades the universe. This hypothesis presents a challenge to physics so severe that one is motivated to explore alternative explanations. In this paper, we explore whether the data from Type Ia supernovae can be explained with an idea that is almost as old as that of the cosmological constant, namely, that the strength of gravity varies on a cosmic timescale. This topic is an ideal one for investigation by an undergraduate physics major because the entire chain of reasoning from models to data analysis is well within the mathematical and conceptual sophistication of a motivated undergraduate.
Gravitational lenses are rare in the known samples of quasars, indicating that the conditions involved in their formation are unusual. In particular, the distribution of matter along the light rays from the observer through the deflector to the quasar may be very different from mean conditions. We show that reasonable deviations in the density of matter along the beams can significantly alter the relationship between time delays and the Hubble constant (H/sub 0/) and conclude that gravitational lenses are not promising estimators of H/sub 0/. However, should an independent, precise determination of H/sub 0/ become available, gravitational lenses could be used to probe long-range density fluctuations.
A method of abrasion testing according to ASTM C 704-76 a is presented for steel fibre concrete mortar, fusion-cast basalt and a surface coating material and results of practical interest are mentioned. Due to the high technical demands on these materials and their specific fields of application, the very first test already supplied interesting findings. From the user's point of view, the method is an interesting alternative to the common test methods, e.g. according to DIN 52 108 (wheel test according to Boehme). In English-speaking countries, testing according to ASTM is often mandatory in the refractory industry in order to assure constant quality of refractory materials after setting. The method is characterized by good comparability and high accuracy of measurement. Only the test piece is exchanged while the test conditions remain constant, so that accurate information on the material studied is obtained.
Cosmological constant a.k.a. dark energy problem is considered to be one major challenge in modern cosmology. Here we present a model where large scale structure formation causes spatially-flat FRW universe to fragment into numerous `FRW islands' surrounded by vacuum. We show that this mechanism can explain the origin of dark energy as well as the late time cosmic acceleration. This explanation of dark energy does not require any exotic matter source nor an extremely fine-tuned cosmological constant. This explanation is given within classical general relativity and relies on the fact that our universe has been undergoing structure formation since its recent past.
We study the stability of the circular orbits of the electromagnetic two-body problem of classical electrodynamics. We introduce the concept of resonant dissipation, i.e. a motion that radiates the center-of-mass energy while the interparticle distance performs bounded oscillations about a metastable orbit. The stability mechanism is established by the existence of a quartic resonant constant generated by the stiff eigenvalues of the linear stability problem. This constant bounds the particles together during the radiative recoil. The condition of resonant dissipation predicts angular momenta for the metastable orbits in reasonable agreement with the Bohr atom. The principal result is that the emission lines agree with the predictions of quantum electrodynamics (QED) with 1 percent average error even up to the $40^{th}$ line. Our angular momenta depend logarithmically on the mass of the heavy body, such that the deuterium and the muonium atoms ...
The Bragg Curve Spectrometer (BCS) is an ionization chamber long enough to stop particles of interest. Particles enter through the cathode window and leave an ionization track parallel to the electric field. The ionization electrons drift through a Frisch grid and are collected on an anode. The anode current, as a function of time, is proportional to the specific ionization along the track. The preamp output is split and used as input for two amplifiers, one with a long integration time constant for energy measurement, and one with a short time constant to pick off the maximum ionization or Bragg peak. The Bragg peak, which is proportional to the nuclear charge, is used for particle identification. Several versions of the BCS have been constructed and tested. Test results, detector characteristics and some design problems are discussed.
A new power system stabilizer (PSS) design method for single-machine infinite-bus systems is developed. This design method not only assigns the poles corresponding to the electro-mechanical oscillation modes in the system, but also located other system poles in suitable places in the s-plane. The design procedure is used first to translate a PSS design problem to an equivalent constant output feedback controller design problem for a single-input multi-output (SIMO) system. Then, a new algorithm developed in this paper is applied to design a constant output feedback controller to achieve the desired closed-loop system pole locations. Finally, the controller gains are transferred back to the parameters in the PSS. The extension of the method to multi-machine power systems is also illustrated. (Author).
The authors examine the overheating of a chemical detonation wave, which results in hybrid detonation processes, for example, photochemical or electrochemical detonation, depending on the source. The schemes for obtaining the overheated detonation are shown. Analysis has shown that: normal stationary overheated detonation waves are possible when the overheating power density is constant, just as when the specific energy of overheating is constant; the use of the ''gas'' equation of state for describing overheated detonation in condensed explosives yields wave parameters which are too high; and the assumption that the chemical energy released in the explosive is independent of the overheating energy also leads to wave parameters which are too high, and the overestimation increases as the overheating is intensified.
Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)[sup 2-] and its stability constant (lgK[sub 1]=8.97(4), 25degC, [mu]=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10[sup -3] mol . l[sup -1] of the oxidizer Na[sub 2]S[sub 2]O[sub 8] in the interval 4[<=]pH[<=]8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK[sub dp]=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).
Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)"2"- and its stability constant (lgK_1=8.97(4), 25degC, #mu#=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10"-"3 mol . l"-"1 of the oxidizer Na_2S_2O_8 in the interval 4#<=#pH#<=#8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK_d_p=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).
On efficient glass capillary columns packed with graphitized thermal carbon black (GTCB) the stereoisomers of aromatic and saturated tricyclic hydrocarbons are completely separated and identified. The Henry's adsorption constants of the individual isomers were determined from mixture at different temperatures. Five isomers of perhydroanthracene, five isomers of perhydrofluorene, two isomers of perhydrophenalene, four isomers of perhydroacenaphthene, as well as phenalene, dihydrophenalene, acenaphthene and acenaphthylene were investigated. The increase of the hydrogenization degree of unsaturated tricyclic hydrocarbons reduces the retention. Among the saturated tricyclic isomers the retention becomes shorter with the larger bending of the molecules, i.e. from the molecule having more equatorial bonds to the molecules having more axial connections. The experimentally determined Henry's constants were qualitatively compared with ...
Vacuum pressure standards of the orifice-flow type require known gas flows of 10/sup -6/ mol/s (10/sup -2/ atm cm/sup 3//s at 0 /sup 0/C) and less. Known gas flows can also be used to calibrate ''standard'' leaks by comparing the pressures generated when flows from the leak and the flowmeter are alternately passed through a constant conductance. Two constant-pressure, piston displacement flowmeters developed at the National Bureau of Standards are described that can generate flows between 10/sup -6/ and 10/sup -10/ mol/s with an estimated uncertainty of 0.8% to 2%. Comparisons of the flowmeters with alternate calibration techniques, and repeated low-range leak and vacuum gauge calibrations, have been used to confirm the estimated uncertainty and random errors of the flowmeter.
The high-frequency data from 12 sensors at the ITCE 1976 are analyzed to determine the Kolmogoroff constants for velocity, temperature and humidity fluctuations, ..cap alpha../sub u/, ..cap alpha../sub T/, and ..cap alpha../sub q/. The occurrence of aliasing in the spectral analysis in some cases together with the limited response of some sensors at the higher frequencies introduces some uncertainties into the analysis. The Soviet sonic anemometer, fine-wire thermometer and infrared hygrometer and the Australian infrared hygrometer provide the best information, namely that: ..cap alpha../sub u/ = 0.59 +/- 0.01, ..cap alpha../sub T/ = 0.68 +/- 0.02, ..cap alpha../sub q/ = 0.76 +/- 0.03, where the errors quoted refer solely to statistical errors. The other instruments provide general support to these values. The technique of using spectral density measurements to determine eddy fluxes is illustrated.
The kinetics of the reaction of 2,4-dinitrohalogenobenzenes (chlorine, bromine, and iodine derivatives) with tetraethylammonium azide in acetonitrile and in a mixed acetonitrile-dioxane solvent (80 vol. % dioxane) were studied. It was established that there is a marked increase (by more than three orders of magnitude) in the azidization rate constant in the transition from protic solvents to aprotic media, due to the decrease in the activation energy barrier of the reaction. The nucleophilicity parameters N/sup +/ for the azide ion in the investigated solvents were determined in terms of Ritchie's relationship. It was established that the effect of the nature of the leaving group on the rate constant of the reactions is complex in character, and it was shown that treatment of the relative reactivity series for the investigated substrates must be based on an analysis of the activation parameters and not restricted to data obtained at ...
A bubble column absorber was used to investigate kinetics of the reaction between carbon dioxide and aqueous solutions of diisopropanolamine (DIPA), by means of gas absorption experiments. These were conducted in the temperature range of 10 to 40deg C, with DIPA concentrations from 5 to 500 mol/m{sup 3}, and CO{sub 2} partial pressures between 5 and 101 kPa. A model based on the Danckwerts' surface reneval theory was used to analyze the experimental results and to determine the rate constant. The obtained data support the assumption of a second-order overall reaction, with the rate constants being well correlated by the Arrhenius equation: k{sub 2} = 1.112 x 10{sup 10} exp(-4848/T). (orig.).
We review and extend in several directions recent results on the asymptotic safety approach to quantum gravity. The central issue in this approach is the search of a Fixed Point having suitable properties, and the tool that is used is a type of Wilsonian renormalization group equation. We begin by discussing various cutoff schemes, i.e. ways of implementing the Wilsonian cutoff procedure. We compare the beta functions of the gravitational couplings obtained with different schemes, studying first the contribution of matter fields and then the so-called Einstein-Hilbert truncation, where only the cosmological constant and Newton's constant are retained. In this context we make connection with old results, in particular we reproduce the results of the epsilon expansion and the perturbative one loop divergences. We then apply the Renormalization Group to higher derivative gravity. In the case of a general action quadratic in curvature we recover, ...
The n3 and n4 vibrational transitions of CH3 and CD3 isolated in solid parahydrogen were studied by high-resolution infrared spectroscopy. The radicals were produced by in situ UV photolysis of methyl iodides trapped in solid parahydrogen. The observed spectra showed clear rotational fine structures, which were subjected to further splitting due to the electrostatic field of solid parahydrogen. The molecular constants and crystal field parameters of the radicals in solid parahydrogen were determined by analyzing the spectral structures of the n3 and n4 transitions of CD3 by the crystal field theory. The rotational constants of the CD3 radical were found to be only a few percent smaller than those in the gas phase. The determined crystal field parameters indicated significant quantum effect...
After mathematicians and physicists had learned that the structure of physical space was not necessarily Euclidean, it became conceivable that the global topological structure of space was non-trivial. In the context of the late 19th century debates on physical space this speculation gave rise to the problem of classifying spaces of constant curvature from a topological point of view. William Kingdon Clifford, Felix Klein and Wilhelm Killing, the latter of whom devoted a substantial amount of work to the topic in the early 1890s, clearly perceived this problem as relevant for both mathematics and natural philosophy (i.e., physics or cosmology). To some extent, a cosmological interest may even be found among those authors who restated the space form problem in more modern terms in the early 20th century, such as Heinz Hopf.
Mixed convection heat transfer from longitudinal fins inside a horizontal channel has been investigated for a wide range of modified Rayleigh numbers and different fin heights and spacings. An experimental parametric study was made to investigate effects of fin spacing, fin height and magnitude of heat flux on mixed convection heat transfer from rectangular fin arrays heated from below in a horizontal channel. The optimum fin spacing to obtain maximum heat transfer has also been investigated. During the experiments constant heat flux boundary condition was realized and air was used as the working fluid. The velocity of fluid entering channel was kept nearly constant (0.15win0.16m/s) using a flow rate control valve so that Reynolds number was always about Re=1500. Experiments were conducted...
A novel method to control the mixed-mode bending (MMB) specimen is presented. By maintaining a constant opening, or Mode 1, displacement rate, stable delamination growth is achieved for all mixed-mode ratios. A constant-opening displacement rate is achieved by attaching a second displacement transducer to the hinges of the specimen. The test machine is then controlled externally by the second displacement transducer. By achieving stable delamination growth and monitoring the opening displacement, an experimental compliance calibration may be derived for the Modes 1 and 2 parts. This new approach to control the test and determine the experimental compliance calibration, overcomes the potential inaccuracies of the previously used beam theory expressions to determine compliance and to separate the modal values of G.
The thermodynamic characteristics of adsorption (the Henry constant, the heat and entropy of adsorption) of amino acids associates with acetic, trifluoroacetic, nonafluoropentanoic acids and formamide with different values of hydrogen bond lengths and various conformations on a graphitized thermal carbon black (GTCB) were calculated. The experimental results, as the Henry constant, lnK1, and the differences in the molar Gibbs energies, d(DG), obtained by a high performance liquid chromatography (HPLC) on a carbon sorbent Hypercarb, were compared with the values of thermodynamic characteristics of adsorption of the amino acids on the GTCB surface calculated by a molecular-statistical method. A satisfactory correlation was observed between the experimental and calculated values with a coeffi...
Five arylethylenes with 1-naphthyl, 2-naphthyl, and phenyl groups in 1,2-positions have been studied for singlet-mediated charge-transfer interactions with several amines and paraquat dication. 1-Phenyl-2-(2-naphthyl)ethylene and 1,2-di(2-naphthyl)ethylene exhibit distinct dependence of exciplex emission maxima and lifetimes, and fluorescence quenching constants, on excitation and/or monitoring wavelengths; this is in conformity with the existence of ground-state rotamers for these systems, wtih distinguishable absorption-emission spectra and fluorescence lifetimes. The fluorescence quenching by aromatic amines and paraquat dication occurs with rate constants in the limit of diffusion control and is accompanied by the formation of radical ions in polar solvents (acetonitrile). The transient spectra and kinetics associated with the radical ions, observed by 337.1- and 355-nm laser flash photolysis, are also reported. 10 figures, 4 tables.
The kinetics of passive film formation on iron in borate buffer solution has been studied at different anodic potentials. The process of film growth has been found to occur in four distinct stages. About 80-90% of the total film thickness formed in 1h grows during the initial two stages which last for only 1-3s (depending upon potential). The electric field strength across the film is not constant but decreases with progressing film growth. The thickness of the film determined ellipsometrically is less than that calculated from the electric charge consumed. The process of anodic film formation is accompanied by the dissolution of iron which occurs over the whole range of potentials.
Measurements of the electrical conductivity, dielectric constant and magnetic susceptibility of pellets of erbium tungstate are reported for the temperature range 300 to 1000 K. The known phase transition near 600 K is in evidence in all these measurements. The conductivity data for T>600 K have been analysed in terms of an exponential relation sigma=sigmasub(0)exp(-Esub(g)/2kT), giving sigma_0=8.892x10"2ohm"-"1cm"-"1 and Esub(g)=1.52eV. There is a weak dispersion in the dielectric constant at around 10"4Hz and a rapid increase above 600 K. The high-temperature data for the susceptibility obey a Curie-Weiss law that gives a value of 9.50 Bohr magneton for Er"3"+ ions and a (ferromagnetic) Curie temperature of 160 K. (author).
The effect of lattice damage caused by room temperature irradiations with products of "1"0B(n,#alpha#)"7Li reactions and "2"3"5U fissions and with fast neutrons on transition curves, quenching curves, and lattice constants of Nb_3Sn, Nb_3Al, Nb_3(Al,Ge), and V_3Si have been investigated. The critical currents in transverse magnetic fields could be increased up to more than one order of magnitude. For heavily irradiated samples drastically reduced values for the critical currents, the upper critical fields, and the transition temperatures were observed. The lattice constants were increased up to 0.5 percent by irradiation. (U.S.).
Emeraldine base (EB) polymer?ZnO nanoparticles composite films has been synthesized by solution casting technique on ITO-coated glass substrate and characterized by XRD, FTIR and TEM for their structure and morphology. Dielectric behaviour of these composite films has been investigated in the very low frequency region to medium frequency region (1?kHz?1?MHz). The dielectric constant of the composite with 30% nanoparticles is almost one-tenth of the pure EB. The dielectric value becomes constant in the frequency region greater than 400?kHz. The change in dielectric behaviour of the composite is explained on the basis of multilayered interface formed between the ZnO nanoparticles and emeraldine chains. Nanoparticles have high energy surface which is responsible for the decrease of free volum...
Dielectric and thermal characteristics of gel grown single crystals of ytterbium tartrate trihydrate have been carried out. The dielectric constant has been measured as a function of frequency in the range 2?kHz?1?MHz and temperature range 30?300??C. The dielectric constant increases with temperature, attains a peak near 215??C, and then decreases as the temperature exceeds 215??C. The dielectric anomaly at 215??C is suggested to be due to phase transition brought about in the material. The dielectric behaviour of the material is correlated with the results on thermal analysis. Thermogravimetric and differential thermal analysis have been used to study the thermal characteristics of the material. The experimental results show that the material is thermally stable up to 200??C. The decompos...
BaTi_0_._9(Ni_1_/_2W_1_/_2)_0_._1O_3 ceramics were fabricated and their dielectric properties were investigated. With the sintering temperature increasing from 1250 to 1280 deg. C, the grain size abruptly increases from 1-2 to 20-40 #mu#m, accompanying significant changes in dielectric response. The samples with larger grains exhibit giant dielectric constant characteristics, which are considered to be mainly attributed to the domain boundary effect. The activation energies of the dielectric relaxation E_r_e_l_a_x=0.325 eV reveal the existence of microdomains in larger grains. The ac conductivity results also give the evidence of the domain boundary effect in the present ceramics.
This paper examines cupric chloride solid conversion during hydrolysis in a thermochemical copper-chlorine (Cu-Cl) cycle for hydrogen production. The hydrolysis reaction is a challenging step, in terms of the excess steam requirement and the decomposition of cupric chloride (CuCl_2) into cuprous chloride (CuCl) and chlorine (Cl_2). The hydrolysis and decomposition reactions are analyzed with respect to the chemical equilibrium constant. The effects of operating parameters are examined, including the temperature, pressure, excess steam and equilibrium conversion. A maximization of yield and selectivity are very important. Rate constants for the simultaneous reaction steps are determined using a uniform reaction model. A shrinking core model is used to determine the rate coefficients and predict the solid conversion time, with diffusional and reaction control. These new results are useful for scale-up of the engineering equipment in the ...
In order to understand the parameters of the standard model of electroweak and strong interactions (coupling constants, masses, mixing angles) one needs to embed the standard model into some larger theory that accounts for the observed values. This means some additional sector is needed that fixes and stabilizes the values of the fundamental constants of nature. In these lecture notes we describe in nontechnical terms how such a sector can be constructed. Our additional sector is based on rapidly fluctuating scalar fields that, although completely deterministic, evolve in the strongest possible chaotic way and exhibit complex behaviour. These chaotic fields generate potentials for moduli fields, which ultimately fix the fundamental parameters. The chaotic dynamics can be physically interpreted in terms of vacuum fluctuations. These vacuum fluctuations are different from those of QED or QCD but coupled with the same moduli fields as QED and QCD ...
In their Letter [Phys. Rev. Lett. 92, 121302 (2004)] (also [Astron. Astrophys. 417, 853 (2004)]), Srianand et al. analysed optical spectra of heavy-element species in 23 absorption systems along background quasar sight-lines, reporting limits on relative variations in the fine-structure constant: da/a=(-0.06+/-0.06) x 10^{-5}. Here we demonstrate basic flaws in their analysis, using the same data and absorption profile fits, which led to spurious values of da/a and significantly underestimated uncertainties. We conclude that these data and fits offer no stringent test of previous evidence for a varying alpha.
In this article a methodology is presented for studying the influence of the biomass moisture content and the biomass/air ratio on the producer gas composition and on the chemiluminescent emissions during the combustion process. Firstly, a mathematical model based on the thermo-chemical processes inside the gasifier is used to predict the composition of the producer gas as a mixture of CO, CO2, H2, N2, CH4 and H2O gases. Secondly, the predicted composition is introduced into a constant volume combustion bomb (CVCB), which simulates the typical conditions inside the combustion chamber of an internal combustion engine, in order to characterize its combustion under gasoline-type conditions through the instantaneous pressure and the detection of the spontaneous luminous radiation (chemilumines...
We have studied the vibrational properties of the filled tetrahedral semiconductor LiMgAs and its binary analog AlAs by using the plane-wave pseudopotential method within density functional theory. The calculated lattice constants for the studied compounds are in good agreement with previous theoretical and experimental results. The phonon dispersion curves and phonon density of states are calculated by using density functional perturbation theory. The sound speeds in different directions are quantitatively similar in LiMgAs and AlAs. The assignment of the zone center modes to the relative motion of the atoms shows that the lower optic modes are due to the Mg-As pair vibrations, while for the upper ones the Li-Mg pair dominates, which is attributed to the smaller Mg atom mass. The longitudinal interatomic force constant of Mg-As is about 66% higher than that of Li-As, showing the relatively high covalency of the former bond.
We investigate the quantum cosmology of spatially homogeneous models with compact spatial sections admitting a u(2) isometry algebra. The metric ansatz in these models is that of Bianchi type IX with two scale factors set to be equal. We apply the Hartle-Hawking no-boundary path integral prescription and find the semi-classical contributions to the wave function. Exact formulae are obtainable for certain contributions and otherwise the limits of large and small anisotropy (for the pure vacuum case) and large spatial volume or small anisotropy (for the case with a positive cosmological constant) are considered. For the pure vacuum case we find no semiclassical components which would correspond to Lorentzian universes. For the case with a cosmological constant the Hartle-Hawking boundary conditions formally constrain one of the parameters in the Lorentzian solutions to be purely imaginary. Possible interpretations of this imaginary parameter are ...
We investigate the quantum cosmology of spatially homogeneous models with compact spatial sections admitting a u(2) isometry algebra. The metric ansatz in these models is that of Bianchi type IX with two scale factors set to be equal. We apply the Hartle-Hawking no-boundary path integral prescription and find the semi-classical contributions to the wave function. Exact formulae are obtainable for certain contributions and otherwise the limits of large and small anisotropy (for the pure vacuum case) and large spatial volume or small anisotropy (for the case with a positive cosmological constant) are considered. For the pure vacuum case we find no semiclassical components which would correspond to Lorentzian universes. For the case with a cosmological constant the Hartle-Hawking boundary conditions formally constrain one of the parameters in the Lorentzian solutions to be purely imaginary. Possible interpretations of this imaginary parameter are ...
Austenitic stainless steel AISI 304 has been nitrided by radio frequency (rf) plasma containing various nitrogen-hydrogen gas mixtures, in order to study the effect of hydrogen on structure and magnetic properties of the formed compound layer. The thermal temperature has been measured at the vicinity of the samples. The compound layer thus produced has been characterized using, X-ray diffractometer and vibration sample magnetometer. Providing the total pressure of nitrogen and hydrogen is held constant, the addition of hydrogen up to 50% gives new structural phases. The magnetization values of the plasma treated samples are strongly dependent on the percentage of H_2 in the gas phase. An excessive amount of hydrogen (#approx#75%) on the other hand, retards the nitriding process. The surface temperature of the sample and plasma condition is crucial factors for nitriding process.
For quantitative acquisition of the influence of surface decarburizing phenomena on the failure of construction parts under cyclic stress different surface decarburization stages were generated in the steels 42CrMo4 and 100Cr6. After construction part-specific thermal treatment the generated states of residual stress were then determined and life span-oriented fatigue tests were conducted. The studies showed that already a small decarburization in martensitic material conditions of the steels 42CrMo4 and 100Cr6 led to a reduction of the alternating bending strength. The decrease of alternate strength can be associated with the micro-notch effects caused by the internal oxides formed by surface oxidation and/or the residual tension stress developed during the hardening in sub-surface sample areas. Decarburization degrees of more than 50% cause a noticeable decrease of surface stability, an increase of residual tension stresses close to the surface and as a result a pronounced decrease ...
The author discusses the implementation in Germany of the EC Directive on Environmental Impact Statements in the light of the legal tradition and concepts of law in Germany, especially in the context of the nuclear licensing procedure. His analysis reveals some legal provisions and legal concepts in existing German law that will have to be ``sacrificed`` in order to do justice to the European Union, as in the formation of the body of EC law governing environmental issues, the Anglo-Saxon approach to regulatory law has been the prevailing line of orientation (the EU ecological audit being an example). On the whole, however, the implementation of the EU Directive will not lead to substantial changes beyond procedural modifications. (HP) [Deutsch] Der Autor diskutiert die Umsetzung der EG-Richtlinien in deutsche Rechtstraditionen und -vorstellungen, besonders beim atomrechtlichen Genehmigungsverfahren. Dabei seien Abstriche an deutsche Rechtsvorschriften der Preis der Europaeischen ...
A century of technical development put steam turbines on a high level regarding efficiency and reliability. This procedure is still ongoing. The technological-commercial point of view - influenced intensively by liberalisation of the energy-market - makes great demands on field services. Well suited concepts in service and modernization are the solutions, as shown in NPP Emsland upgrade. [German] Ein Jahrhundert technischer Entwick lung brachte Dampfturbinen auf ein hohes Niveau bezueglich Effizienz und Zuverlaessigkeit. Dieser Vorgang ist auch in der heutigen Zeit nicht ab geschlossen. Die technologisch-wirtschaftliche Betrachtungs weise '' von der Liberalisierung des Strommarktes intensiv beeinflusst '' stellt dementsprechend hohe Anforderungen auch an den Kraftwerksservice. Massgeschneiderte Modernisierungs- und Servicekonzepte sind die Antwort, wie das Beispiel Kernkraftwerk Emsland zeigt. (orig.)
The danger potential for 110 kV cables, which are installed on racks and in tunnels, caused by catching fire because of arcing short circuits and mechanical overstressing by peak shortcircuit current, has been experimental analysed under Bewag network conditions. As a result, recommendations for an improved installation of 110 kV cables are given. (orig.) [Deutsch] Fuer offen gelegte 110-kV-Kabel in Raeumen, auf Fussboeden und in Schaechten wurde das von Kurzschluessen auf den Kabeln ausgehende Gefaehrdungspotential fuer die Entstehung von Kabelbraenden durch Fehlerlichtboegen und fuer eine mechanische Ueberbeanspruchung von Kabeln durch Stosskurzschlussstroeme unter Beruecksichtigung der Netzverhaeltnisse der Bewag experimentell untersucht. Im Ergebnis geben die Verfasser Empfehlungen fuer die sichere Anordnung offen gelegter 110-kV-Kabel. (orig.)
For the laying of natural gas transport pipelines severe soil protection guidelines are in force in Switzerland. These guidelines influence, above all, the course of the construction in a substantial way. The Federal Office of Energy promulgated these guidelines in May 1993. They have provisional character and shall be reviewed based on the experiences with the in 1994 executed pipeline constructions. The protection of the soil from mechanical-physical loads, specially from soil erosion and compaction, is also a part of the modification of the federal legislation concerning environmental protection which is being dealt with at present by the federal parliament. (orig.) [Deutsch] Fuer die Verlegung von Erdgas-Transportleitungen gelten in der Schweiz strenge Bodenschutzrichtlinien, die vor allem den Bauablauf nachhaltig beeinflussen. Die Richtlinien wurden im Mai 1993 durch das Bundesamt fuer Energiewirtschaft erlassen. Sie haben provisorischen Charkater und sollen ...
A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and ...
This paper describes EPRI`s computer based Performance, Operation and Maintenance Management System (``POMMS``) consisting of four (4) modules (``Modules``). These Modules are used to monitor, evaluate and analyze the cost effective operation of simple cycle and combined cycle gas turbine power plants. Inputs to POMMS relating to plant performance, availability and maintenance are monitored, stored in a data acquisition system and analyzed to determine their impact on performance and cost parameters. POMMS was developed by EPRI, Project Manager Fluor Daniel Power Generation Company and by the subcontractors who, together, engineered the individual POMMS Modules while working on EPRI`s Durability Surveillance of Advanced Gas Turbines Project (``Project``). The following modules are described in this paper and may be applied together or individually: Rotating Blade Temperature Measurement and Evaluation System Module (``BTMES``), Data Acquisition System Module ...
This works evaluates by punctuation the performance in conventional Brazilian industries radiation protection area which make use of small industrial gauges and industrial radiography. It proposes, procedures for industry self-evaluation, besides a new radiation protection plans pattern for the small industrial gauges area. The data source where inspection reports of Dosimetry Radiation Protection Institute/Nuclear Energy Commission conventional Brazilian industries' radiation protection plans, beyond visitation to the inspection place. The performance evaluation has been realized both in the administrative and operational aspects of the industries. About of 60% of the industries have a satisfactory register control which does not happen to the operational control. The performance evaluation advantage is that industries may self-evaluate, foreseeing Dosimetry Radiation Protection Institute's regulation inspections, correcting its irregularities, automatically ...
Optische Uhren nutzen die Anregung optischer Ubergange in neutralen Atomen oder Ionen. Deren Ubergangsfrequenz liegt bei etwa 1015 Hz, also funf Groenordnungen oberhalb der Gigahertz-Schwingungen heutiger Atomuhren. Das erlaubt eine bis zu tausendmal prazisere Zeitmessung. Fur die Genauigkeit ist es entscheidend, dass der Uhrenubergang eine schmale Linienbreite besitzt und seine Frequenz nicht verschoben wird. Dazu mussen die Atome oder Ionen moglichst ungestort und genau lokalisiert sein. Deshalb basiert ein Uhrentyp auf einem kalten Ion in einer Paul-Falle, ein anderer Uhrentyp arbeitet mit vielen kalten Neutralatomen in optischen Gittern. Der Metrologie sollen optische Uhren zunachst als sekundare Realisierung der Sekunde dienen. Derzeit ermoglichen sie bereits Frequenzmessungen mit 17 ...
Until now, monitoring of power transformers focussed mainly large generator and network transformers. Siemens goes a step ahead and provides a system especially developed and designed for small and medium power transformers, e.g. for the 100 kV level. This low cost version could be achieved by restriction to really necessary measuring quantities. This allows to realize also for small and medium power transformers an online monitoring including an estimation of aging and as an option an early warning to avoid unexpected failures. (orig.) [German] Die Ueberwachung (Monitoring) von Leistungstransformatoren war bisher vor allem fuer Maschinentransformatoren und grosse Netzkuppeltransformatoren in der Diskussion. Siemens geht einen Schritt weiter und stellt nun auch ein System bereit, das speziell fuer kleine und mittlere Leistungstransformatoren, z.B. der 110-kV-Spannungsebene, konzipiert ist. Diese kostenguenstige Variante wurde durch Beschraenkung auf die aus ...
Fuel cells can make an important contribution to ecologically acceptable energy supply. There are many pilot projects in the 1 W to 1 MW range. Especially the motor car industry is quite interested, and a breakthrough seems to be in sight. The second part of this series discusses the physical and chemical fundamentals of the fuel cell, the function of the electrolyte and catalyst, and the functional principle. (orig.) [German] Brennstoffzellen koennen bei der Riesenaufgabe, den weiter wachsenden Energiebedarf oekologisch vertraeglicher als bisher zu decken, einen wichtigen Beitrag leisten. Bis heute (2004) gibt es zahllose Pilotprojekte im Leistungsbereich 1 W bis ueber 1 MW, die die Alltagstauglichkeit der BZ beweisen. Verschiedenste Branchen - vor allem auch die Automobilindustrie - zeigen grosses Interesse fuer kommerzielle Anwendungen. Die Brennstoffzelle als effizienter Energiewandler, scheint vor dem Durchbruch zu stehen. Der zweite Teil befasst sich mit den ...
Liberalisation of the energy market will lead to enhanced use of environment-friendly, high-efficiency combined-cycle power stations - a great challenge to steam turbine producers. In this highly competitive market, advanced technology and interesting technical features are key issues. MAN Turbomaschinen AG GHH BORSIG, Oberhausen and Berlin, have been producers of steam turbines since 1905. Performance optimisation is the main aspect of development today. [German] Die jetzt eingeleitete Liberalisierung des Energiemarktes wird in der Zukunft den verstaerkten Einsatz von neuen umweltfreundlichen und zugleich hoch effizienten Kombikraftwerken notwendig machen. Eine grosse Herausforderung an fuehrende Hersteller modernster Dampfturbinen. Eine ausgereifte Technik sowie technische Alleinstellungsmerkmale sind im heutigen Verdraengungswettbewerb eine Voraussetzung bei Industriedampfturbinen. Seit dem Jahre 1904 baut die MAN Turbomaschinen AG GHH BORSIG, Oberhausen und Berlin, Dampfturbinen, ...
Leakfree compression of gaseous liquids prevents impurities resulting from entry of lubricants and abrasive particles and is therefore an important requirement on modern compressors. Another requirement voiced increasingly often is the reduction or even prevention of problematic off-gases and contaminated residues of libricating oils. Further, compressors should have high corrosion resistance, low noise, a long service life and high reliability. Membrane compressors are largely able to meet these requirements. The article describes the technical concept and applications of membrane compressors. (orig.) [Deutsch] Umweltschutz und steigende Forderungen der Industrie an die Reinheit technischer Gase verlangen Kompressoren, die weitgehend leckagefrei verdichten und keine Verunreinigungen des Gases durch Schmierstoffe und Abrieb hervorrufen. Immer haeufiger wird in diesem Zusammenhang die Reduzierung oder sogar die Vermeidung von schwer zu entsorgenden Abgasen und kontaminierten ...
Meltdown and gasification of waste in an oxygen atmosphere ('2sv' process) is an economically efficient alternative to energetic and thermal utilisation of biomass. Organic pollutants are split at temperatures up to 2000 C in a reducing atmosphere. The process uses elements of the oxygen cupola furnace for melting and gasification of many different waste fractions, e.g. polluted waste wood, household refuse and bulk waste, old tyres, light shredder fractions, sewage sludge, etc. [German] Die Sauerstoff-Schmelz-Vergasung ('2sv') stellt eine wirtschaftliche Alternative zur energetischen Nutzung von Biomassen wie auch zur thermischen Abfallverwertung dar. Organische Schadstoffe werden bei diesem neuen Verfahren bei Temperaturen bis zu 2000 C unter reduzierenden Bedingungen aufgespalten. Das Verfahren nutzt Elemente des Sauerstoff-Kupolofens fuer die Schmelzvergasung und eignet sich fuer zahlreiche Abfallarten wie z.B. belastetes ...
Rehabilitation of the abandoned uranium mining areas in Saxonia and Thuringia is a task posing also legal problems. The radiation protection laws of the former GDR continued to be effective to a great extent and proved to be a legal basis not ``perfect`` in formal terms, but suitably efficient in practice to tackle the manifold problems encountered in the land reclamation and waste disposal work. Originally intended to serve as a legal interim regime awaiting amendment at a later date, the body of laws available for the task proved to be a sufficient basis. (orig./HP) [Deutsch] Das fortgeltende Strahlenschutzrecht der frueheren DDR hat sich zwar nicht als formal `perfektes`, in der Sache aber strahlenschutzgerechtes und praktikables Instrument zur Loesung der anstehenden Sanierungsaufgaben erwiesen. Bei seiner Beurteilung darf nicht ausser Acht gelassen werden, dass die Ueberleitung dieses Rechts seinerzeit aus der Not eines kurzfristigen Regelungsbedearfs geboren ...
Despite successful reduction of the general lead exposure, this heavy metal is still a matter of public concern due to the fact that associations with intellectual impairment or delayed puberty are found to correlate with very low lead blood concentrations. Lead in tap water is still an important contribution to lead exposure which may cause health risk for infants. Therefore, lead pipes should be completely sanitated by exchange against pipes made from more healthy materials. (orig.) [German] Trotz erfolgreicher Reduktion der allgemeinen Belastung ist Blei auch heute noch umweltmedizinisch relevant, weil es moeglicherweise bei niedrigeren als bisher angenommenen Belastungen gesundheitlich nachteilige Wirkungen, insbesondere waehrend der fruehkindlichen Entwicklung des Nervensystems, ausloest. Insbesondere Blei aus bleiernen Trinkwasserleitungen ist eine Belastung, die fuer Saeuglinge und Kleinkinder nach wie vor ein gesundheitliches Risiko darstellen kann. Solche Leitungen sollten ...
Zusammenfassung Hintergrund Die vorliegende Arbeit untersucht, welche Frequenzkombination f?r die Berechnung der mittleren H?rverluste im Tonschwellenaudiogramm am besten mit dem H?rverlust f?r Zahlen im Sprachaudiogramm korreliert, da in der Literatur verschiedene Rechenvarianten f?r diese gutachterliche Plausibilit?tspr?fung beschrieben werden. Es wurden die 3?Rechenvarianten A (250, 500 und 1000?Hz), B (500 und 1000?Hz) und C (500, 1000 und 2000?Hz) verglichen. Methoden Die Audiogramme von 80?Normalh?rigen, 106?Schwerh?rigen und 135 zu Begutachtenden wurden retrospektiv analysiert. Die Differenzen der Mittelwerte aus dem Tonschwellenaudiogramm und dem H?rverlust f?r Zahlen wurden f?r das rechte und linke Ohr getrennt in den 3?Patientenkollektiven berechnet und statistisch verglichen. Er...
The paper examines the influence of various total strain amplitudes and mean strains on the cyclic deformation processes in GGG-60 at temperatures of 20 C, 350 C, and 500 C ,the total strain amplitudes being varied between 1.0 permille {<=}{epsilon}{sub a,t}{<=}3.8 permille , and the mean strains between -4.0 permille {<=}{epsilon}{sub m,t}{<=}4.0 permille . - [Deutsch] In der Arbeit wird der Einfluss unterschiedlicher Totaldehnungsamplituden und Mitteldehnungen auf das Wechselverformungsverhalten von GGG-60 bei Temperaturen von 20 C, 350 C und 500 C untersucht. Dabei werden die Totaldehnungsamplituden zwischen 1,0 permille {<=} {epsilon}{sub a,t} {<=} 3,8 permille und die Mitteldehnungen zwischen -4,0 permille {<=} {epsilon}{sub m,t} {<=} 4,0 permille variiert. (orig./MM)
In the first part of the symposium, experts reviewed the state of the art of decentralized waste water treatment in Europe. In the second part, exemplary solutions in Poland and the Czech Republic were presented. The final part was dedicated to future concepts and strategies. [German] Im Herbst letzten Jahres hat die Kommunale Umwelt-AktioN U.A.N. in einer Abfolge von drei Abwasserfachsymposien Expertenrunden zum Austausch ueber den aktuellen Stand des Wissens zum Thema dezentrale Abwasserbehandlung veranstaltet. Mit dem Internationalen Symposium 'Konzepte zur Abwasserbehandlung im laendlichen Raum Europas' in Celle hat das Projekt der U.A.N. seinen Abschluss gefunden. Der Konzeption des Projektes entsprechend haben im 1. Teil des Symposiums Experten ueber den Stand der Entwicklung auf dem Sektor der dezentralen Abwasserbehandlung in Deutschland berichtet. Im 2. Teil unserer Fachtagung wurden europaeische Beispiele fuer dezentrale Loesungen aus ...
Disposal of fine-particled byproducts via injection into a capola furnace using natural gas/O{sub 2} burners is a cost-efficient alternative to landfill dumping. Tests conducted in a foundry demonstrated that dusts collected there can be injected without detriment to melt-down rate and iron quality. The replacement of FeSi pellets with FeSi dust in addition reduced the slag content, while injection of coal dust permitted a decrease in coke consumption. (orig.) [Deutsch] Die Entsorgung von feinkoernigen Reststoffen durch Einblasen in einen Kupolofen ueber Erdgas/O{sub 2}-Brenner ist eine wirtschaftliche Alternative zur Deponierung. Anhand von Versuchen in einer Giesserei konnte aufgezeigt werden, dass hier anfallende Staeube ohne nachteilige Auswirkungen auf Schmelzleistung und Eisenqualitaet einzublasen sind. Die Substitution von FeSi-Formlingen durch FeSi-Staub brachte zudem eine Reduzierung des Schlackeanteils und das Einblasen von Kohlenstaub eine Verminderung ...
The harnessing and enhanced use of renewable energy today is a matter of lively debate and much concern. Amazingly, hydro power is either rarely considered in these discussions or viewed in a negative light. But hydro power continues to be the most important source of renewable energy, and its use potential is considerable and should be taken into account when, for instance, agreeing on or implementing carbon dioxide reduction targets. Small hydro power stations are an effective means of harnessing existing energy potentials. (orig.) [Deutsch] Ueber die Nutzung und den Ausbau regenerativer Energien wird heutzutage lebhaft diskutiert und gerungen. Es mag erstaunen, dass in diesen Diskussionen die Wasserkraft kaum Beachtung findet oder in einem schlechten Licht gesehen wird. Dabei ist die Wasserkraft nach wie vor bei weitem die wichtigsten Quelle regenerativer Energie, und sie besitzt ein beachtliches Ausbaupotential, das man wenigstens ins Kalkuel ziehen sollte, ...
The technical potentials of electric power generation from hydro power in Germany, the current harnessing of hydro power, its costs, and certain characteristic quantities reflecting its effects on the environment are described. These diverse characteristic quantities are compared with those of other renewable and fossil energy sources used to generate electricity. On this basis, opportunities for extending the use of hydro power in Germany and its limits are discussed. (orig.) [Deutsch] Das Ziel der folgenden Ausfuehrungen ist, die technischen Potentiale und deren derzeitige Nutzung, die Kosten und bestimmte die Umwelteffekte beschreibende Kenngroessen einer Stromerzeugung aus Wasserkraft in Deutschland darzustellen. Diese unterschiedlichen Kenngroessen werden anschliessend mit denen anderer regenerativer Energien und fossiler Energietraeger zur Stromerzeugung verglichen. Ausgehend davon werden die Moeglichkeiten und Grenzen einer weitergehenden Wasserkraftnutzung ...
The described heat transfer model supplies plausible results for the size distribution of active nucleation spots. For boiling states for which a comparison with measured bubble covering density is possible, that is for low boiling pressures and low heat flux densities, the bubble covering densities calculated by model on the basis of heat transfer measurements agree relatively well with the values observed. (orig.) [Deutsch] Das beschriebene Waermeuebergangsmodell liefert plausible Ergebnisse fuer die Groessenverteilung der aktiven Keimstellen. Fuer die Siedezustaende, fuer die ein Vergleich mit gemessenen Blasenbelegungsdichten moeglich ist, d.h. fuer niedrige Siededruecke und kleine Waermestromdichten, stimmen die aufgrund der Waermeuebergangsmessungen mit dem Modell berechneten Blasenbelegungsdichten verhaeltnismaessig gut mit den beobachteten Werten ueberein. (orig.)
The pilot project of the conversion of the green forage drying plant Lengenfeld to biomass firing could not be realized without problems. But the experience until now shows that it is in principle possible. The farmers involved are devoted to the project. For them the cultivation of biomass is an alternative to the abandonment of fields. The present low oil price sets limits to the positive income effect. The aim is an increase of the biomass share in heating energy supply to about 80%. (orig.) [Deutsch] Die Umstellung der Gruenfuttertrocknung Lengenfeld auf Biomassefeuerung ist als Pilotprojekt nicht ohne Probleme moeglich gewesen. Die bisherigen Erfahrungen zeigen jedoch die grundsaetzliche Praktikabilitaet. Die beteiligten Landwirte sind engagiert bei der Sache und schaetzen die Produktionsmoeglichkeit als Alternative zur Flaechenstillegung. Der derzeit niedrige Oelpreis setzt der positiven Einkommenswirkung jedoch enge Grenzen. Eine Erhoehung des Biomasseanteils an der ...
Purpose: To assess the new method of 3-dimensional echocardiography in comparison to the 'gold standard' MRI as to its ability to calculate left ventricular volumes in patients with congenital heart disease. Materials and methods: Eighteen patients between the ages of 3.9 to 37.3 years (mean: 12.8{+-}9.7) with a geometrically abnormal left ventricle were examined using a 1.5 T scanner with a fast gradient-echo sequence (TR=14 ms, TE=2.6-2.9 ms, FOV=300-400 mm, flip angle=20 , matrix=128:256, slice thickness=5 mm, retrospective gating) in multislice-multiphase technique. Transthoracic 3D-echocardiography was performed with a 3.5 MHz transducer and a Tomtec {sup trademark} (Munich, Germany) system for 3D reconstruction. Results: Volume calculation was possible in all patients with 3D-echocardiography, but the muscle mass calculation only succeeded in 11 to 18 patients (61%) due to inadequate visualization of the entire myocardium. Comparing MRI and 3D-echocardiography, ...
Wider coal lines and larger power plant units necessitate measures for increasing the capacity of the mills without driving up power consumption and installation costs. The result of this development is the modern ALSTOM bowl mill. This paper indicates the stages of development which were necessary for this and the experience which could be accumulated through these measures. The paper also describes in detail the areas of flow in the mills, of design of milling equipment, of mill power supply and of grading in this development. (orig.) [Deutsch] Breitere Kohlebaender und groessere Kraftwerkseinheiten zwingen zu Massnahmen, um die Leistung der Muehlen zu vergroessern, ohne jedoch den Kraftbedarf und die Installationskosten in die Hoehe zu treiben. Das Ergebnis dieser Entwicklung ist die moderne ALSTOM-Schuesselmuehle. Der Beitrag zeigt, welche Entwicklungsschritte hierzu erforderlich waren und welche Erfahrungen mit den Massnahmen gesammelt werden konnten. Im ...
The microelectronic cable diagnosis is a substantial tool to determine destruction free the residual strength and the lifetime of laid PE/XLPE medium voltage cables. Fundamentals of the ageing diagnosis and a cost reduced inspection concept are the `Isothermal-Relaxation-Current` Analysis and the Neuro-Fuzzy evaluation software. These new tools are able to determine the ageing status of the investigated cable without any references. The authors also show that the test breakdown during the assessment of the ageing status of criterial systems can be reduced by this approach. The cable diagnosis equipment KDA is also useful for the steering of investment as well as for preventive maintenance. (orig.) [Deutsch] Die zerstoerungsfreie dielektrische Kabeldiagnostik kann heute einen wesentlichen Beitrag zur Bestimmung der Restfestigkeit und der Restlebensdauer eines PE/VPE-isolierten Mittelspannungskabels leisten. Basis der Alterungsdiagnose und des Konzeptes zur kostensparenden Pruefung ist ...
Melting in a cokeless cupola furnace fuelled with natural gas is a novel, energy-saving and environment-friendly process. In order to be able to monitor the processes inside the furnace with detailed mass and heat balances, an experimental furnace with an efficient measuring system was constructed in the framework of a research project financed by the BMFT and Messrs. Eisenwerke Dueker GmbH und Co. KG, Laufach, Germany. (orig./HS) [Deutsch] Das Schmelzen im kokslosen erdgasgefeuerten Kupolofen ist ein neues, energiesparendes und umweltfreundliches Verfahren. Um die Vorgaenge im Ofen mit umfassenden Stoff- und Waermebilanzen erfassen zu koennen, ist im Rahmen eines vom BMFT und der Firma Eisenwerke Dueker GmbH und Co. KG, Laufach, finanzierten Forschungsvorhabens, ein Versuchsofen mit umfangreicher Messeinrichtung gebaut worden. (orig./HS)
The principle of radiodiagnosis consists in the fact the X-ray beam is attenuated at different degrees by distinct tissues. For this reason, the anatomical structures have distinct radiological opacities, that produce the radiographic image. The progresses in radiology are related to the development if new radiographic image formation systems that enable an amplification in the quality, with low dose and/or risk to the patient. The objective of this work is the sensitometric valuation of a screen-film combination, that is still the most used, for the standardization, of radiographic images. Thinking about this, were constructed homogeneous phantoms of the chest, skull and pelvis, for the calibration of X-ray beams, with the purpose of obtaining radiographic images of good quality, basing in the routine of a radiodiagnosis service and in the scientific knowledge. Questions were approached about the choice of the suitable equipment, that allow the obtention of k Vp and m As combinations, ...
In the last few years the supercharging of Otto-cycle-engines has regained popularity, as demonstrated by a number of series-production engines. After listing the aims to be met by a modern supercharger the paper describes the technical status of mass-produced or close to production superchargers. This is followed by a comparative evaluation of the systems, enabling the reader to select possible solutions for a projected supercharger-engine-system by means of a comparison chart. The paper is concluded by a list of possible directions for further development and additional potential for twin-screw superchargers. (orig.) [German] In neuerer Zeit hat die Aufladung von Ottomotoren wieder ein verstaerktes Interesse gefunden, das sich auch in einer Anzahl serienmaessig gefertigter aufgeladener Motortypen wiederspiegelt. Der vorliegende Beitrag beschreibt, nach einer Darstellung der Anforderungen an ein modernes Aufladegeraet, den Stand der Technik bei serienmaessigen ...
Pulmonary tumors in children are rare. Nevertheless, there are besides malign primary neoplasms and metastases also some benign tumors that the radiologist should know. The identification of some tumors is difficult, since some of them may mimic pulmonary inflammation. The first diagnostic tool is chest radiography. After that, a CT with contrastmedium should be performed, if possible a multislice-CT (MSCT). Identification of mediastinal structures is best with MRI. (orig.) [German] Tumoren der Lunge sind im Kindesalter selten. Trotzdem finden sich neben den malignen primaeren und sekundaeren Raumforderungen auch im Kindesalter immer wieder benigne Tumoren, die der Radiologe kennen sollte. Eine eindeutige Identifizierung kann schwierig sein, da z. B. entzuendliche Infiltrate vorgetaeuscht werden koennen. Die primaere Untersuchungsmethode ist das konventionelle Thoraxroentgen. Die weitere Diagnostik muss mit der Computertomographie, nach Moeglichkeit mit einem ...
Internal combustion engines with mechanically driven superchargers are known for good performance at low engine speeds and fast response times under fluctuating loads. Application engineers can choose between superchargers with and without internal compression - the familiar roots (blower) type or true compressors - for supercharging an internal combustion engine. This article by DaimlerChrysler describes two options for improving the partial load behaviour of mechanically supercharged internal combustion engines with compressors. (orig.) [German] Die Aufladung mit mechanisch angetriebenen Verdraengerladern zeichnet sich durch guten Druckaufbau bei niedrigen Drehzahlen und gute Dynamik bei Lastwechseln aus. Fuer die Applikation am Verbrennungsmotor koennen Maschinen ohne innere Verdichtung - wie die bekannten Roots-Geblaese - oder Maschinen mit innerer Verdichtung - Kompressoren im eigentlichen Sinne - zum Einsatz kommen. In diesem Beitrag von DaimlerChrysler sind zwei Moeglichkeiten ...
The proposed ERICAM model exhibits deficiencies of a nature making it inacceptable to responsible governments. These deficiencies are: it does not provide the required financial security. The availability of insurance coverage will be dependent on the situation in the financial markets. Pricing will not be determined by the absolute probability of incidents causing damage, so that this may entail a distortion of allocations of resources. (orig./HP) [Deutsch] Das ERICAM Modell hat Konstruktionsmaengel, dass es sicher fuer verantwortliche Regierungen nicht in Frage kaeme, dessen Realisierung in Erwaegung zu ziehen. Die wichtigsten sind: Die benoetigte Sicherheit der Deckungsmittel ist nicht gegeben. Die Lage an den Finanzmaerkten dominiert die Verfuegbarkeit der Deckungsmittel. Die Preisbildung wird nicht durch die absolute Schadenswahrscheinlichkeit bestimmt, so dass eine Verfaelschung der Allokation von Ressourcen eintreten wuerde. (orig./HP)
In the future fossil fuelled power plants are realised/laid down as combined cycle power plants with high current generation efficiencies. The method of pressure fluidized-bed combustion with downstream hot gas cleaning is going to compete with methods combined with a pressure coal gasification or a pressure dust combustion. The advantages of the pressure fluidized bed combustion are the simpler method set-up and consequently lower investment costs. (orig./CD) [Deutsch] Kohlegefeuerte Kraftwerke werden zukuenftig als kombinierte Gas/Dampfturbinen-Kraftwerke mit hohen Stromerzeugungswirkungsgraden ausgefuehrt werden. Das Verfahren der Druckwirbelschichtverbrennung mit nachgeschalteter Heissgasreinigung und Rauchgasturbine wird dabei mit Verfahren mit einer vorgeschalteten Kohledruckvergasung oder mit einer Druckstaubfeuerung konkurrieren. Die Vorteile der Druckwirbelschichtverbrennung liegen dabei auf dem insgesamt einfacheren Verfahrensaufbau und damit wohl auch ...
Much of the current technology on 3D-prestack depth migration is based on the Kirchhoff method and the traveltime information needed for this purpose is obtained by the ray-theory approximation. The main motivation driving these options is to reduce computations but it can also have an adverse effect on the quality of results. Experience with real data indicates that the corresponding poststack data migrated by the reverse-time method often yields superior results. Considerable computational efficiency can be obtained by employing nonuniform coarse grid spacing during the reverse-time migration. We followed this strategy for developing a parallel scheme for doing 3D- prestack depth migration. However, we worked only on a small subset of shot gathers whose determined by the Quasi-Monte Carlo method. The results were indistinguishable from those obtained by using a much larger population of uniformly spaced shot gathers. We present examples of migration of 3-D data. (author)
The investigations showed that the new adsorber/catalyst composites are well suited for chemical degradation of persistent water pollutants. Compared with alternative processes, the reaction selectivity and the consumption of oxidant are more favourable as the reaction now takes place on/inside the solid. The process, which was developed originally for purification of contaminated water, can be transferred to many other systems of materials. For example, it is expected that the soot emissions of diesel engines will be reduced significantly after efficient hydrogenation of the aromatics contained in the diesel engine on molybdenum-charged mesoporous composites. [German] Mit den vorliegenden Untersuchungen konnte ein erster Nachweis gefuehrt werden, dass die neu entwickelten Adsorber/Katalysator-Komposite fuer den chemischen Abbau persistenter Wasserschadstoffe geeignet sind. Im Vergleich zu alternativen Verfahrensloesungen kann die Selektivitaet der Reaktion und der Verbrauch an ...
The onshore Potiguar basin has nowadays around 5.000 artificial lifting petroleum wells, distributed into 80 fields located on the states of Rio Grande do Norte and Ceara, representing approximately 8% of the national oil production. For that, well maintenance service, realized by Workover Rigs, is essential to preserve the oil productivity of the reservoirs on these fields. However, as the number of rigs is lower than to the number of wells needing maintenance, the task of administrating the management of such equipment according to the demand created by the wells, generates an optimization problem. The decision for a rig intervention on a well depends on parameters such as flow rate, depth, wasted time on intervention, distance from the rig to the next well, type of operation, rig capacity, environmental risks, etc. The objective of this paper is to present an interactive Computational System for Support Decision to the optimized management of the wells attended by the rig fleet. ...
Report by a participant in the International Nuclear Law School. In 2001, this advanced training course was first offered by the OECD-NEA together with the University of Montpellier and other international partners. This effort is intended to provide an overview of nuclear law, a discipline normally playing a subordinate role in curricula. In this way, a contribution is to be made to the important preservation of the existing knowledge base and to increasing know-how in this field. In 2003, the International Nuclear Law School will be continued with a new curriculum addressed to all interested participants. (orig.) [German] Erfahrungsbericht eines Teilnehmers der Internationalen Schule fuer Nuklearrecht 2002 an der Universitaet Montpellier. Erstmals im Jahr 2001 wurde diese Fortbildungsveranstaltung von der Nuclear Energy Agency der Organisation for Economic Co-operation and Development (OECD-NEA) zusammen mit der Universitaet Montpellier und weiteren internationalen ...
Purpose: To evaluate the success rates of the implantation of stent grafts in the treatment of peripheral aneurysms. Materials and methods: in 13 patients with 15 aneurysms at the common iliac artery (n = 6), external iliac artery (n = 1), hypogastric artery (n = 2), femoral artery (n = 2) or popliteal artery (n = 4), implantation of dacron-covered nitinol stents was performed. The patients were followed up for three to 20 months (mean, 8.8 months) with intravenous digital subtraction angiography, CT or colour-coded Doppler sonography. Results: In all cases, the aneurysm was successfully occluded after stent implantation. In one case with a popliteal aneurysm, kinking of the vessel caused thrombosis of the stent. The stent was successfully reopened. The aneurysm however, had to be surgically treated 9 months later. The primary and secondary patency rates at 6 months were 93% and 100%, respectively. Conclusion: The method described might be an alternative therapy to surgery. There are ...
The precipitation hardened, ferrite-pearlite medium-carbon steels microalloyed with vanadium (AFP steels) have been developed over the last few years as materials allowing processing by controlled, continuous cooling down from forging temperatures, for achieving benefits such as reducing the number of required heat treatment and working processes and saving expensive alloying materials. Due to their cost-saving advantages, the steels rapidly have been accepted as an alternative material to the quenched and tempered steels and re particularly used for fabrication of automobile parts. Their drawbacks however are the lower yield strength, and low ductility and toughness as compared to the heat-treatable steels. The research project therefore was intended to enhance the properties of the microalloyed, medium-carbon steels and widen their applicability by establishing further and improving existing thermomechanical treatment processes that will considerably improve the steels` strength and ...
This feasibility study of the uve Institut fuer Technische Chemie und Umweltschutz GmbH discusses the scientific and technical fundamentals of a catalytic process for complete removal of organic pollutants (PAH, H-HC, PCB, phenols, nitro-aromatics and organometallic compounds, e.g. from polluted soil and groundwater) by thermal-catalytic cracking and conversion into simple gases. The process is based on the catalytic reaction of the hydrocarbon compounds with water vapour in the temperature range of 700-900 degrees centigrade. The resulting gas mixtures consist mainly of hydrogen, carbon monoxide, carbon dioxide and methane which can be used as fuels, e.g. for heating or in gas engines. The process is an alterntive to combustion. It is therefore well suited whenever the pollutant to be removed is already mixed with water or water vapour and wherever in-situ removal would be too great a hazard. [Deutsch] Die vorliegende Machbarkeitsstudie aus dem uve Institut fuer Technische Chemie und ...
After 3 years of construction the trial run of the heating power station HKW 2 ended in November 1997 on time. No extraordinary damage occured during construction, assembly or commissioning. The plant has been operating according to schedule since November 1997. A brief inspection carried out in the summer of 1998 in order to assess warranty claims showed no damage to any part except one valve. Experience shows that all aforementioned activities were necessary. The paper reports about success and negative experience. Certification according to DIN EN ISO 9000ff., however, affords to guarantee of high-quality construction. Builders of such plants therefore need to set up their own quality assurance centre and ensure its technical competence. If necessary,additional experts should be called in.Quality assurance costs for HKW 2 came to about 0.5-0.6 percent of total costs. In view of the success and long life of this investment these expenses are more than justified. (orig.) [German] Nach ...
In the year 1996 the spheres of competence of several DLR-Institutes working in the areas of fluid dynamics, reaction kinetics, combustion, numerical methods and laser measuring techniques have been brought together while contributing to the internal DLR project 'combustion chamber modelling (BKM)', in order to proceed with the computational simulation of combustion processes in combustion chambers of gas turbines. The main issue was the development of a research code for numerical simulation of fluid flow in real combustion chambers. Here the development of computational models of physical and chemical processes was emphasized, among other processes the formation of soot was treated. Moreover, a worldwide outstanding database of measured data for the purpose of code validation has been created within the framework of the BKM project using the laboratory facilities of the DLR, which are in Germany unique for the experimental investigation of the various processes in ...
Lung cancer staging according to the TNM system is based on morphological assessment of the primary cancer, lymph nodes and metastases. All aspects of this important oncological classification are measurable with MRI. Pulmonary nodules can be detected at the clinically relevant size of 4-5 mm in diameter. The extent of mediastinal, hilar and supraclavicular lymph node affection can be assessed at the same time. The predominant metastatic spread to the adrenal glands and spine can be detected in coronal orientation during dedicated MRI of the lungs. Search focused whole body MRI completes the staging. Various additional MR imaging techniques provide further functional and clinically relevant information during a single examination. In the oncological context the most important techniques are imaging of perfusion and tumor motion. Functional MRI of the lungs complements the pure staging and improves surgical approaches and radiotherapy planning. (orig.) [German] Das ...
Preserving customers` investments in capital goods is one of the strategic market services offered by ABB, and to this end the company has developed project-specific retrofit concepts especially for older power generation plant. A prime example of such a modernization is the Umm Al Nar East (UANE) combined cycle power station in Abu Dhabi, UAE. UANE has two gas turbines of type GT13D, which together generate 140 MW of electrical energy, and heat-recovery boilers which supply steam to a seawater desalination plant with a capacity of 80 million liters of drinking water per day. After almost 20 years in operation, UANE is being modernized. To address the owner`s concerns and minimize plant downtime, ABB has introduced Service, Operation and Rehabilitation (SOR) Key Account Management for Abu Dhabi. In the first phase of the modernization project, the static starting equipment was upgraded and the mechanical turbine governor replaced by the EGATROL electro-hydraulic control system. Also, ...
Clinical studies have proved the effectiveness of local ablading methods in pations with non-resectable liver metastases of a colorectal carcinoma. RF ablation and LITT are a potentially curative therapy option and an alternative to systemic chemotherapy; the latter is carried out primarily for reducing tumour size with the goal of secondary resectability. The number of R0-sesectable metastases can be enhanced by a combined therapy of surgery and local ablading methods, e.g. by preoperative, intraoperative or postoperative ablasion of further non-resectable tumours during surgery. Systemic chemotherapy combined with surgery as an adjuvant method is not recommended unless in cases of non-abladable tumour recidivation. Currently, systemic chemotherapy is used as a neo-adjuvant therapy for tumour size reduction with the goal of secondary resectability or, in case of inoperability, local ablation. (orig.) [German] Abladierende Verfahren. Klinische Studien belegen die Effektivitaet der ...
When the use of retarders in utility vehicles increased in the middle of the 80s, the Forschungsvereinigung Automobiltechnik (FAT) commissioned a study on the safety aspect of this braking technology in trucks. Retarders are wear-free permanent brakes that are fitted in the drive transmission system of utility vehicles, thereby generating braking forces only at the wheels of the live shaft. The question of the possible overbraking of the live shafts was just as well investigated as the interaction between the retarder and service brake in so-called integrated braking systems, and both under conditions of low adhesion as well as in the border area of the dynamics of vehicle movement. This subject met with considerable joint interest on the part of the motor vehicle industry as well as of manufacturers of towed vehicles and unit sets. FAT, therefore, commissioned the Institut fuer Kraftfahrwesen of the University of Hannover to carry out a three-phase research project on the braking ...
Tribological performance of alumina and silicon carbide ceramics as well as of the hardened steel 100Cr6 for reference was studied during reciprocating sliding and cavitation erosion in isooctane as substitute of gasoline and in distilled water. It was the aim to characterize effects of surface finish of the specimens and the liquid media on friction, resistance to sliding wear and cavitation erosion. Sliding wear tests were run on the self-mated ceramics and ceramic/steel pairs under conditions of boundary lubrication using a laboratory tribometer with cylinder-on-plate geometry. Vibratory cavitation erosion tests were conducted according to ASTM G 32-92. High initial surface roughness of coarse ground specimens led to a distinct running-in period during sliding contact with a transition from high to low values of friction coefficient and wear intensity. Incubation time was reduced with increasing surface roughness in the cavitation tests. Depending on the materials investigated, the ...
Surface structure analysis, i.e. metallographic analysis of component surfaces with the aid of replicas, is an established method of component monitoring and the only reliable non-destructive method for detecting and analyzing beginning creep damage in the form of creep pores. Creep pore development provides a basis for component condition analysis. It must be noted, however, that the modern martensitic 9-12 % Cr steels - like the established steels 10CrMo9-10 (P22) und X20CrMoV12-1 - have comparatively high creep fracture deformation rates in fatigue tests. This raises the question if these steels can be judged on the basis of data for established steels. The results so far suggest that even with low pore densities (single pores), a higher degree of damage and a shorter time until failure must be assumed. [German] Eine bewaehrte Methode der Bauteilueberwachung stellt die Oberflaechengefuegeuntersuchung, d. h. die metallografische Untersuchung der Bauteiloberflaeche mit Hilfe von ...
Low-cost titanium alloy components are getting increasing attention in aerospace applications. Cost reductions are possible in the alloys themselves and in the production techniques. The former aspect is less promising as titanium alloys are costly to produce. Of course, there are some new developments like the (alpha plus beta) alloy Ti-6 Al-2 Fe-0.2 Si (TIMETAL 62S) and the beta-alloy Ti-6.8 Mo-4.5 Fe-1.5 Al (TIMETAL LCB), in which low-cost iron replaces costly beta alloying elements like vanadium or molybdenum, but these will be used mainly on the mass production markets, e.g. motor car construction. In consequence, optimisation of production methods is the more promising option. Near net shape processes will reduce the production cost and improve the fly-to-buy ratio. Some of these production processes are explained. [Deutsch] Die Herstellung preiswerter Bauteile aus Titanlegierungen gewinnt auch in der Luft- und Raumfahrt zunehmend an Bedeutung. Zwei Wege werden hier beschritten: ...
On account of a raised appearing of plastic waste and shreddered light fraction (SLF) from old car utilization as well as legal handicaps experiments were carried out at the Institute of Ferrous Metallurgy (RWTH Aachen) on a laboratory rig to inject DSD (Duales System Deutschland)-plastic waste and SLF with the destination of a subsequent raw material utilization in the blast furnace and cupola furnace. The experiments on the laboratory rig with DSD plastics could verify that by injection of specific coal/plastic mixtures into the blast furnace the injection rate could be raised by an improvement in the conversion degree and therefore the amount of the inserted reducing agent can be lowered. The injection of SLF without reduction of the inert materials and of the contents on alloying elements and/or tramp elements by extensive preparation has no advantages according to the experiments for the blast furnace process. Pilot experiments on the cupola furnace showed that, assuming a certain ...
A new generation of lead alloys for making lead batteries is being introduced in highly developed countries. A very important characteristic of these alloys is the presence of Ca, Al and Sn. Such alloys have the property of stabilizing the amount of gas emitted as a result of the decomposition of the electrolyte on the level of pure lead i.e. significantly smaller than lead alloys containing Se e.g. PbSb 1.7Se. Such alloys have not been produced in Poland so far. - In this paper we are presenting the method and equipment used to produce a pilot portion of PbSnCaAl alloy (mass approximately 80 Mg) on an industrial scale at HMN ''Szopienice'' S.A. lead refinery. We also present the results of the tests regarding the chemical homogeneity of the alloy produced, as well as its structural and casting properties. On the basis of the tests conducted it has been found that the method is industrially adequate and as such it has been introduced into the ...
CT-Expo is a novel MS Excel application for assessing the radiation doses delivered to patients undergoing CT examinations, based on computational methods that were used to analyze the data collected in the German survey on CT practice in 1999. The program enables the calculation of all dose quantities of practical value, such as axial dose free-in-air, weighted CTDI, dose-length product, effective dose and uterine dose. In contrast to existing programs for CT dose assessment, CT-Expo offers a number of unique features, such as gender-specific dose calculation for all age groups (adults, children, newborns), applicability to all existing scanner models including correction of scanner-specific influences, and the possibility of comparison with the results from the German CT survey on CT practice. Three different application modules offer free and standardized dose calculations as well as a comprehensive benchmarking section including guidance on dose optimization. The program is ...
A Bianchi type-IX cosmological model has been found as a solution of Einstien's vacuum field equations with a cosmological constant. The solution represents a rotating generalziation fo the de Sitter universe. This universe shows a transition to exponential expansion and the vorticity begins to decay exponentially at the grand-unified-theory time. The point of time for this transition is independent of the magnitude of the vorticity. During the Guth inflationary era the vorticity decays by a factor of the order 10 US.
A Bianchi type-IX cosmological model has been found as a solution of Einstien's vacuum field equations with a cosmological constant. The solution represents a rotating generalziation fo the de Sitter universe. This universe shows a transition to exponential expansion and the vorticity begins to decay exponentially at the grand-unified-theory time. The point of time for this transition is independent of the magnitude of the vorticity. During the Guth inflationary era the vorticity decays by a factor of the order 10"-"1"4"2.
1. From a 150 mM-NH4 salicylate medium salicylate enters human red cells with a rate constant of 1.9 min-1 at 0 degrees C. 2. Salicylate increases the red cell permeability for Ca2+ (and Mg2+). There...Full Text Available
We derive the explicit formula for the joint Laplace transform of the Wishart process and its time integral which extends the original approach of Bru. We compare our methodology with the alternative results given by the variation of constants method, the linearization of the Matrix Riccati ODE's and the Runge-Kutta algorithm. The new formula turns out to be fast, accurate and very useful for applications when dealing with stochastic volatility and stochastic correlation modelling.
An extension of data mining, text mining involves the extraction of information and knowledge from unstructured text. This constantly evolving field is increasingly used by major corporations, such as Google, Yahoo, and Microsoft. Featuring contributions from leading researchers in the field, this book provides a detailed overview of text mining theory, applications, and visualization. The theory section discusses text mining, information retrieval, latent semantic analysis, pagerank, latent Dirichlet allocation, and probabilistic relational models. In the section on text mining applications,
The Feynman-#alpha# method was applied to measurement of reactivity and the ability of this method for a real-time reactivity monitoring system was assessed. In the experiment, all measured data by BF_3 detectors were stored in a multi-channel scaler controlled by a personal computer, and they were analyzed to obtain prompt neutron decay constant (#alpha#) and reactivity with consideration of dead time of detector. It was found that #alpha# could be obtained almost in a real-time even for both positive and negative reactivities by the present experimental technique. (author).
Structural relaxation, crystallization and optimisation processes in soft magnetic amorphous alloys based on iron are examined by applying different experimental techniques: X-ray diffraction analysis, high-resolution electron microscopy, measurements of magnetic and electric properties (permeability, after-effect resistivity). The presented results are discussed in terms of annealing out of microvoids, formation of nanocrystalline phase and changes of effective magnetostriction constant. (author)
A new classically stable model of spontaneous compactification is investigated. D=10 dimensional Einstein-Yang-Mills SU(3) x U(1) theory compactifies to CP(3) giving SU(4) x U(1) effective D=4 theory with no tachyons. An effective SU(4) coupling constant is calculated.
Possibility for using a sodium iodide scintillator as a reference signal source is considered. Experimental data on studying the performance of a gamma thickness gage with an additional scintillator are given. Results of experimental investigations of a thickness gage dummy proved practical expediency of the principle being considered. It is established, in particular, that the device is ready to operate without warm-up with a constant sensitivity, the deviation not exceeding 0.5%, in the ambient temperature range of 15-25 deg C.
We consider a particle that is subject to a constant force and scatters inelastically on a vibrating periodically corrugated floor. At small friction and for small scatterers the dynamics is dominated by resonances forming spiral structures in phase space. These spiral modes lead to pronounced maxima and minima in the diffusion coefficient as a function of the vibration frequency, as is shown in computer simulations. Our theoretical predictions may be verified experimentally by studying transport of single granular particles on vibratory conveyors.
We prove that the density of a topologically nontrivial, area-minimizing hypercone with an isolated singularity must be greater than the square root of 2. The Simons' cones show that this is the best possible constant. If one of the components of the complement of the cone has nontrivial kth homotopy group, we prove a better bound in terms of k; that bound is also best possible. The proofs use mean curvature flow.
We describe exact cosmological solutions with rotation and expansion in the low-energy effective string theory. These models are spatially homogeneous (closed Bianchi type IX) and they belong to the family of shear-free metrics which are causal (no closed timelike curves are allowed), admit no parallax effects and do not disturb the isotropy of the background radiation. The dilaton and the axion fields are nontrivial, in general, and we consider both cases with and without the central charge (effective cosmological constant)
We describe exact cosmological solutions with rotation and expansion in the low-energy effective string theory. These models are spatially homogeneous (closed Bianchi type IX) and they belong to the family of shear-free metrics which are causal (no closed timelike curves are allowed), admit no parallax effects and do not disturb the isotropy of the background radiation. The dilaton and the axion fields are nontrivial, in general, and we consider both cases with and without the central charge (effective cosmological constant).
In this note we prove to all orders in the small scale expansion that all off-shell parameters which appear in the chiral effective Lagrangian with explicit DELTA(1232) isobar degrees of freedom can be absorbed into redefinitions of certain low-energy constants and are therefore redundant.
Decomposition yields of tetracycline sulphate and oxytetracycline sulphate were determined in argon saturated 0.1N H/sub 2/SO/sub 4/ solutions. The decomposition yields of teracyclines decrease in the presence of the Cl/sup -/ ions. The reaction rate constants of the OH radicals with tetracyclines were also determined.
The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.
After a brief survey of the known level measurement methods the particularities of the radiometric measurement of the still utilisable residual volume of a bulk material in a large bin are discussed. At constant angle of repose the measurement in a suitably positioned plane of measurement suffices, at variable angle of repose two planes of measurement are required. The probable working ranges for a 1300-t lime bin are estimated.
The observed strength of the carbon dioxide absorption bands recorded on spectrobolograms of the transparency of the earth's atmosphere between wavelengths 300 and 2500 nanometers as part of the Smithsonian Solar Constant Program were used to extract the abundance of carbon dioxide in the atmosphere. The details of the analysis and the sources of error are discussed. 11 references, 5 figures, 1 table. (ACR)
We report on studies of device degradation in organic photovoltaic devices based on blends of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM). Since delamination, oxidation, and chemical interactions at the metal electrode/organic interface have long been posited as degradation pathways in organic electronic devices, we first investigated the stability of a variety of electrodes for devices stored in an inert, dark environment. Second, a set of experiments was designed to separate the effects at the metal/organic interface from the degradation of the active layer or the hole extraction interface. To do this, Ca/Al electrodes were deposited to complete half of a substrate's devices, and samples were left both under constant illumination and 10% illumination (10% duty cycle of 1 sun illumination) in a glovebox environment. After more than 200 h of measurement, additional electrodes were deposited and device performance of ...
Experience and technical innovations in power plant engineering have resulted in continuous improvements of operation control, availability and safety of pumped storage plants. Process control is constantly improved as new developments are made in equipment and systems engineering. Plant control concepts with increasingly complex automation hierarchy are described by which pumped storage processes can be controlled optimally, reliably, and automatically.
Crystalline and non-crystalline iron oxide (#alpha#-Fe_2O_3) thin films were obtained by spray pyrolysis onto glass substrate at different temperatures. The results of X-ray diffraction showed that with increasing the deposition time, the film structure changed from non-crystalline to crystalline at the same substrate temperature. At different substrate temperatures and low deposition times (5 min), iron oxide appears almost in non-crystalline form. With rising the substrate temperature and deposition time, the crystallinity was improved. The effect of substrate temperature as well as deposition time on the optical features (absorption coefficient and bandgap) and optical constants of these films has been investigated. Optical constants of the films were determined from spectrophotometric measurement of reflectance and transmittance. Analysis of the results showed that, for non-crystalline iron oxide films of different thicknesses (76-118 nm) ...
A n-time generalization of Newton's law (of universal gravitation) formula in N =n + d + 1-dimensional space-time is conjectured. This formula implies a relation for effective N-dimensional gravitational constant G_{eff} = G cos^2 \\theta, where \\theta is the angle between the direction of motion of two particles in n-dimensional time manifold R^n.
Measurements of the two-body recombination of spin-polarized atomic hydrogen in a magnetic field of 40 kG have been extended to temperatures above 0.5/sup 0/K. The rate constant for the formation of parahydrogen shows an unexpected increase with temperature, which is explained by inverse predissociation into the v = 14,J = 4 level of H/sub 2/. Data indicate the level is bound by 0.7 +- 0.1/sup 0/K.
Lithium tetrachloroaluminate solutions in thionylchloride, methylacetate and their mixtures are studied by "7Li and "2"7Al NMR. It is found that introduction of methylacetate in the LiAlCl_4-SOCl_2 system results in a change of lithium tetrachloroaluminate formation constant. In the ternary system, Li"+ is solvated by methyl-acetate after complete destruction of tetrachloroaluminate anion. Refs. 9, figs. 2.
The method and results of the quantitative gas chromatographic determination of volatile organic substances in an urban atmosphere are presented. The concentration of organic substances was determined by using a mixed adsorber consisting of graphitized thermal carbon black and activated charcoal modified by pyrocarbon. Average, maximum and minimum concentrations of constant organic components in the atmosphere of Leningrad as a typical large industrial city are reported.
The complex formation of zirconium with biphenyl mono- and biscatecholyazo derivatives has been studied spectrophotometrically. The composition of the complexes, form and charge of complex-forming zirconium ions have been established. A procedure is suggested for calculation of molar absorptivities and stability constants for each of the complexes formed simultaneously in the system. Possible complex formation schemes have been studied. The data obtained were used to develop a spectrophotometric method of determining zirconium in the presence of large amounts of copper.
How far can a stack of $n$ identical blocks be made to hang over the edge of a table? The question dates back to at least the middle of the 19th century and the answer to it was widely believed to be of order $\\log n$. Recently, Paterson and Zwick constructed $n$-block stacks with overhangs of order $n^{1/3}$, exponentially better than previously thought possible. We show here that order $n^{1/3}$ is indeed best possible, resolving the long-standing overhang problem up to a constant factor.
Measurement of the magnetic susceptibility of powder samples of heavy rare-earth (Tb, Dy, Ho, Er, Tm and Yb) tungstates have been reported in the temperature range 300 to 900 K. Curie-Weiss law behaviour has been observed for all samples. The Curie constant, paramagnetic Curie temperature and magneton number for the magnetic ions have also been evaluated for each material. (author).
The kinetics of the reaction of zirconium phosphates with carbon tetrachloride in sodium and potassium chloride melt as well as the effect of temperature, gas flow, solubility and weight of the solid phase of the phosphate, and stirring of the melt on the chlorination rate has been studied. The kinetic parameters of the reaction (rate constants, activation energy, etc.) have been calculated.
(3H)Cyclofoxy (CF: 17-cyclopropylmethyl-3,14-dihydroxy-4,5-alpha-epoxy-6-beta-fluoromorp hinan) is an opioid antagonist with affinity to both mu and kappa subtypes that was synthesized for quantitative evaluation of opioid receptor binding in vivo. Two sets of experiments in rats were analyzed. The first involved determining the metabolite-corrected blood concentration and tissue distribution of CF in brain 1 to 60 min after i.v. bolus injection. The second involved measuring brain washout for 15 to 120 s following intracarotid artery injection of CF. A physiologically based model and a classical compartmental pharmacokinetic model were compared. The models included different assumptions for transport across the blood-brain barrier (BBB); estimates of nonspecific tissue binding and specific binding to a single opiate receptor site were found to be essentially the same with both models. The nonspecific binding equilibrium constant varied modestly in different brain ...
The multidrug efflux transporter AcrAB-TolC is known to pump out a diverse range of antibiotics, including β-lactams. However, the kinetic constants of the efflux process, needed for the quantitative...Full Text Available
In our previous theoretical analyses, solubility-limited mass transfer from waste solids applies if a species is at a constant elemental concentration in liquid at the waste surface. For an element with isotopes that decay appreciably during the time of interest, a solubility boundary condition results in a time-dependent boundary concentration of each isotope. Here we present mass-transfer equations that include the effects of isotopic decay boundary conditions. 9 refs., 1 fig.
Most of the Turkish lignites have undesired fuel properties and they are extremely polluting. In this study, Sweet Sorghum was chosen as the energy plant. Combustion experiments of lignite and lignite-Sweet Sorghum mixtures were carried out in a fluidised bed system. The fuel-feeding ratio was set such that the thermal output of the system remained constant. Addition of Sweet Sorghum to the lignite reduces the pollutant concentration. The results were supported by experimental results.
Evaluation procedures used to produce sets of evaluated data for the 33 heavy isotopes that fall in the range Z = 90 to Z = 98 are described. At the beginning of the discussion for each individual isotope, a computer-generated listing is given which summarizes the main properties of the data sets that are contained in the evaluation. (RWR)
To achieve the high degree of management control and operational efficiency necessary for new undertakings, there will be a heavy dependence on schemes for the remote control and monitoring of all mine activities both on the surface and underground, plus the provision of information on operations, plant and equipment. This will all need to be supervised from a central control point on the colliery surface. A survey of recently introduced instrumentation systems makes it clear that British manufacturers already have made major advances in the field of automation, and new equipment constantly comes on to the market.
Experimentally it is found that at constant temperature the order-parameter relaxation time, tausub(..delta..), decreases with increasing power of the microwaves, coupled into a superconducting strip. If the same increase in critical current, that corresponds with a given power of the microwaves, is obtained by lowering the temperature, the decrease in tausub(..delta..) is smaller. This reflects the fact that quasiparticles are removed more efficiently from the gap edge by microwaves than by lowering the temperature in equilibrium. A modified time-dependent Ginzburg-Landau equation is shown to describe these results adequately.
AC/DC voltage standards based entirely on solid-state references used as secondary, working, or transfer standards is widespread, although metrological performance is typically defined only via comparison with a higher level standard. The present report shows the improvements of the output metrological characteristics of an ac/dc calibrator by establishing three internal hierarchical levels of dc voltage references and by constant calibration of ac measuring circuits.
This paper reports the results of in situ observation of fatigue crack growth in a ferrite?pearlite steel. Stress intensity factor range (?K) decreasing/increasing and constant-?K fatigue tests have been carried out. In banded pearlite orientation, intense crack branching was observed which leads to fatigue crack retardation. Crack closure during the test was monitored to understand the fatigue crack growth behaviour.
The method of double microwave--radio-frequency resonance has been used to obtain spectra of the 2/sub 11/reverse arrow2/sub 12/ and 3/sub 21/reverse arrow3/sub 22/ transitions in HCOOD, DCOOH, and HCOOH molecules. The constants of the quadrupole bond of the deuterons have been determined, magnetic interactions being taken into acocunt. A comparison with results of previous studies is given.
We have performed precision measurements in a magneto-optical trap of the 7P1/2 hyperfine structure of the isotopes 209-210Fr. The ratio of these hyperfine constants to the previously measured 7S1/2 ground state values reveals a significant hyperfine anomaly. This anomaly results from the different radial dependence of the electron density in the two atomic levels. The measurements are sensitive to changes in the radial distribution of the neutron magnetism.
Infrared spectra of bicyclo[1.1.1]pentane (C5H8) have been recorded at a resolution (0.0015 cm-1) sufficient to resolve for the first time individual rovibrational lines. This initial report presents the ground state constants for this molecule determined from the detailed analysis of three of the ten infrared-allowed bands, v14(e?) at 540 cm-1, v17(a2?) at 1220 cm-1, v18(a2?) at 832 cm-1, and a partial analysis of the v11(e?) band at 1237 cm-1. The upper states of transitions involving the lowest frequency mode, v14(e?), show no evidence of rovibrational perturbations but those for the v17 and v18 (a2?) modes give clear indication of Coriolis coupling to nearby e? levels. Accordingly, ground state constants were determined by use of the combination-difference method for all three bands. The assigned frequencies provided over 3300 consistent ground state difference values, yielding the following constants for the ground ...
The research of the CELLO collaboration is reviewed. After a description of the CELLO detector tests of QCD and hadronic final states by determination of the strong coupling constant and studies of inclusive production of electrons and muons in multihadronic events in e"+e"- annihilation are described. Then studies of deep inelastic e#gamma# scattering with lepton pair production and the study of the structure function of the photon are briefly described. Finally studies on QED processes are described together with tau decays. (HSI).
Among important candidates for babesial vaccines are apical complex proteins, including rhoptry-associated protein 1 (RAP-1) from Babesia bovis and B. bigemina, which...Full Text Available
The Grueneisen parameter and lattice thermal expansion of the A-15 compounds V_3Si and V_3Ge at room temperature are evaluated on the basis of the method due to Brugger and Fritz from the third order elastic constants reported earlier. The calculated values are compared with available experimental values and are found to fit satisfactorily. (author).
We consider a generalization of the DGP model, by adding a second brane with localized curvature, and allowing for a bulk cosmological constant and brane tensions. We study radion and graviton fluctuations in detail, enabling us to check for ghosts and tachyons. By tuning our parameters accordingly, we find bigravity models that are free from ghosts and tachyons. These models will lead to large distance modifications of gravity that could be observable in the near future.
The $\\beta$ function for a scalar field theory describes the dependence of the coupling constant on the renormalization mass scale. This dependence is affected by the choice of regularization scheme. I explicitly relate the $\\beta$-functions of momentum cut-off regularization and dimensional regularization on scalar field theories by a gauge transformation using the Hopf algebras of the Feynman diagrams of the theories.
A high voltage oil-impregnated electrical cable with fully polymer taped insulation operable to 765 kV. Biaxially oriented, specially processed, polyethylene, polybutene or polypropylene tape with an embossed pattern is wound in multiple layers over a conductive core with a permeable screen around the insulation. Conventional oil which closely matches the dielectric constant of the tape is used, and the cable can be impregnated after field installation because of its excellent impregnation characteristics.
Analytical solutions are derived for a flow in a semi-infinite vertical porous medium with heat and mass transfer. When the temperature and mass concentration are uniform a constant pressure is possible and sustains a fully developed flow. Thereafter there is a small perturbation on the wall temperature and concentration and the subsequent two-dimensional problem is tackled for a large Prandtl number, free convection parameters and small Reynolds number. The heat transfer rate at the wall is discussed quantitatively.
The formation of astatide-mercury complexes was investigated in aqueous solutions.The obtained complexes were examined by paper electrophoresis. It was found that Hg(OH)At and Hg(OH)I complexes were formed in neutral solution. The stability constants of the obtained complexes were determined by ion-exchange. The preliminary results indicate that the complex of mercury with astatide is much more stable than similar complexes with iodide. (author)
In the case of large capacity steam turbines the conventional nozzle group control is, for mechanical and thermodynamic reasons, diminishing more and more in importance in favour of variable pressure control. A design for constant-pressure operation as an alternative to nozzle group control is described; this demonstrates a series of important advantages compared with the latter. (orig.).
The free electron laser (FEL) FLASH at DESY in Hamburg is the first x-ray FEL ever built. Many new developments were necessary in order to exploit the unique properties of this novel light source for scientific experiments. The facility has constantly been improved and several major upgrades have been made or are currently underway. This paper reviews the main characteristics of the user facility as well as the major developments and upgrades.
We propose and construct a new type of extended superconformal algebra (ESA) based on the super Toda field theory. Both in the N = 1 ESA and in the N = 2 ESA, an arbitrary value of the central charge is allowed in contrast with the previously known super W-algebra. The generators of ESA are interpreted as the constants of motion in the super Toda field theory. (orig.).
Li shell-model calculation has been made in the isospin formalism in the complete (0 + n)#Planck constant##omega# model space with the assumption of a closed core "4He. The calculation could probably be improved by use of a better effective interaction and increasing shell model space. With the use of faster computer with large memories, the authors are in hope of calculation in spsd shell-model space
The receptor occupancy-biological effect relationship for muscarinic receptors in guinea pig ileal smooth muscle has been studied by comparison of radioligand binding and contractile response. Muscarinic receptors in homogenates of ileal smooth muscle were labeled with (/sub 3/H)-1-Quinuclidinyl benzilate. Treatment with propylbenzilylcholine mustard (PrBCM), to inactivate irreversibly muscarinic receptors, caused a large dose dependent rightward shift of the dose-response curve to three agonistic furtrethonium derivatives with a concomitant decrease in maximal response. Using those data, the fraction of receptors remaining unoccupied (q-values) and true affinity constants (-log K/sub A/-values) were calculated. Exposure to 20 or 60 nM PrBCM for 15 minutes resulted in a 39% and a 61% reduction in specific (/sup 3/H)-1-Quinuclidinyl benzilate binding sites respectively to be compared with a 62% and a 85% decrease expected from calculated q-values. K/sub A/-values ...
The stability constants of [AtX_2]"- with X = Cl, Br and I in ethanol and methanol as well as their ion mobilities at a temperature of 298 K and an ionic strength of 0.05 were determined by horizontal zone electromigration in homogeneous electrolyte solution. The results are compared with existing data from aqueous electrolyte systems. (author).
The free energy of a gas of closed strings with extrinsic curvature (smooth strings) is evaluated on a torus. This is compared with the free energy of a collection of free particles, and hence the mass spectrum of excitations of the smooth strings is deduced. It is found that above a critical value of the coupling constant of the curvature term the spectrum is free of tachyons. Furthermore, there are no massless spin-2 excitations. The absence of massless spin-2 fields is a consequence of the fact that the smooth-string theory is not modular invariant.
The ErNi{sub 1-} {sub x} Cu {sub x} Al compounds crystallize all in the hexagonal ZrNiAl-type structure. The concentration dependence of lattice constants shows a discontinuity between x=0.5 and 0.6. This structural change has no primary impact on the magnetic order in this series, but influences the crystal field. The lower part of the crystal-field energy-level schemes has been estimated from the specific-heat data.
The ErNi_1_- _x Cu _x Al compounds crystallize all in the hexagonal ZrNiAl-type structure. The concentration dependence of lattice constants shows a discontinuity between x=0.5 and 0.6. This structural change has no primary impact on the magnetic order in this series, but influences the crystal field. The lower part of the crystal-field energy-level schemes has been estimated from the specific-heat data.
The catalytic properties of molybdena-alumina catalysts reduced in hydrogen were studied in the function of the reduction temperature, i.e. in the function of the extent of reduction. The deuterium exchange reaction of benzene was used as model catalytic reaction. It was concluded that the reaction rate constant and the multiplicity factor decreased with the extent of reduction parallel with the change in the extent of dehydroxylation of the catalysts. (orig.)
With the help of the symmetry at the P point, we have determined the relations between the force constants and the moduli of elasticity for A-15 compounds. Based on these relations, a semi-experimental method for the study of the lattice dynamic behaviors of A-15 compounds is developed. Numerical calculations of the phonon spectrum of Nb/sub 3/Sn and its temperature dependence have been made, and they are in good agreement with the experimental data.
The values of the second dissociation constant pK2 and related thermodynamic quantities of the ampholyte 3-(N-morpholino)-2-hydroxypropanesulfonic acid (MOPSO) have...Full Text Available
We study the high energy behaviour of Yang-Mills theory under the inclusion of gravity. In the weak-gravity limit, the running gauge coupling receives no contribution from the gravitational sector, if all symmetries are preserved. This holds true with and without cosmological constant. We also show that asymptotic freedom persists in general field-theory-based gravity scenarios including gravitational shielding as well as asymptotically safe gravity.
An S-brane solution with two non-composite electric branes and a set of l scalar fields is considered. The intersection rule for branes corresponds to the Lie algebra A_2. The solution contains five factor spaces with the fifth one interpreted as ``our'' 3-dimensional space. It is shown that there exists a time interval where accelerating expansion of ``our'' 3-dimensional space is compatible with small enough value of effective gravitational ``constant'' variation.
Interfacial tension in the system toluene solution of di-2-ethylhexylphosphoric acid HDEHP-aqueous solutions of inorganic salts has been measured by the drop volume method. The ion-exchange constants in the monolayers formed by HDEHP and alkaline-earth metals have been measured.
Barley (Hordeum vulgare L. cv Golden Promise) plants were grown in a continuous culture system in which the root and shoot ammonia and amino acid levels were constant over a 6-hour...Full Text Available
A heat pump was tested in the cooling mode under the following conditions: (1) a steady-state test with 95/sup 0/F (35/sup 0/C) outdoor temperature, various indoor conditions, and a dry indoor coil; (2) a steady-state test with 82/sup 0/F (27.8/sup 0/C) outdoor temperature, various indoor conditions, and a dry indoor coil; (3) a cyclic test with an outdoor room temperature of 82/sup 0/F (27.8/sup 0/C), various indoor conditions, and a dry indoor coil. The indoor conditions were varied as follows: (1) indoor temperatures of 75/sup 0/F (23.9/sup 0/C), 80/sup 0/F (26.7/sup 0/C) and 85/sup 0/F (29.4/sup 0/C); (2) volume flowrates over the evaporator coil of 880 cfm (0.47 m/sup 3//s), 1100 cfm (0.52 m/sup 3//s) and 1425 cfm (0.67 m/sup 3//s); (3) during the off-time the dampers were closed in one test series and kept open with a continuously running air handling fan in another test series; (4) the on and off times of the heat pump during the cyclic tests were 6/24 and 10/10 minutes ...
Purpose: For planning the therapeutic strategies and estimating the prognosis in esophageal cancer, N-staging is very important. To date, MRI still is of minor importance as imaging modality of the mediastinum despite promising developments in the past, like ECG-gating or 'averaging' sequences, e.g. LOTA (Long-term averaging), which facilitate mediastinal and thoracic MR-imaging. In a prospective approach, the value of MRI based N-staging was examined with respect to LOTA-sequences. Material and Methods: Within from weeks prior to esophagectomy, standardized MRI of the esophagus was performed in 15 patients (10 squamous-cell-carcinomas and 5 adenocarcinomas) using a 1.5 T whole body scanner. Imaging quality was classified based on depiction of aortic wall or tracheal wall layers. Criteria for malignant infiltration were a diameter of more than 15 mm or a round appearance of a lymph node together with GD-DTPA enhancement. All data were blinded and separately read by ...
Early effects of 100 Kilorads of X-rays on muscle cell membrane properties have been measured in sartorius muscles from Leptodactylus ocellatus. Threshold strength for rectangular current pulses increased 10% after irradiation, and action potential propagation velocity decreased 10%. Passive membrane parameters were calculated from potential responses to sub-threshold current pulses, assuming conventional cable theory. Specific membrane conductance increased to 18% after irradiation, membrane capacitance increased 14%, and length constant decreased 10% but membrane time constant was unchanged. Cell diameter decreased 5%, and resting membrane potential decreased 8%. Membrane parameters during an action potential were also evaluated by the phase-plane and current-voltage plot techniques. Irradiation significantly decreased the action potential amplitude, the excitation potential, and the maximum rates of rise and fall of membrane potential. ...
In this paper nickel acetate catalyzed sodium borohydride cartridges have been prepared and hydrolyzed with water for hydrogen production. Two technological solutions have been tested to increase the overall hydrogen yield, namely a porous water diffuser and a hydrophobic membrane. The first was used to improve water diffusion inside the hydride while the second to confine water inside the cartridge. The generated hydrogen flow showed a very reproducible behavior. Hydrogen promptly evolved just after water was pumped into the cartridge. After some initial peaks, a constant hydrogen flow has been recorded for the whole reaction time. The constant flow was related to the presence of the porous diffuser. The use of a hydrophobic membrane to confine the water inside the cartridge allowed to increase the overall hydrogen yield: about 6 water molecules per mol of hydride were required to complete the reaction. The reaction product was identified by ...
In this paper, we prove a uniqueness result in the inverse problem of determining several non-constant coefficients of one-dimensional reaction-diffusion equations. Such reaction-diffusion equations include the classical model of Kolmogorov, Petrovsky and Piskunov as well as more sophisticated models from biology. When the reaction term contains an unknown polynomial part of degree $N,$ with non-constant coefficients $\\mu_k(x),$ our result gives a sufficient condition for the uniqueness of the determination of this polynomial part. This sufficient condition only involves pointwise measurements of the solution $u$ of the reaction-diffusion equation and of its spatial derivative $\\partial u / \\partial x$ at a single point $x_0,$ during a time interval $(0,\\epsilon).$ In addition to this uniqueness result, we give several counter-examples to uniqueness, which emphasize the optimality of our assumptions. Finally, in the particular cases N=2 and ...
Software has been developed for the calculation of the thermodynamic cycle and the entropy changes in a turbocharged, direct injection, diesel engine based upon the measured cylinder pressure and a shaft encoder output. Assumptions of homogeneous mixture and equilibrium thermodynamic properties are made for the products of combustion and temporal variation in the fluid thermodynamic state is followed in a quasi-steady manner through a series of adjacent equilibrium states, each separated by finite intervals of one degree crank angle (1degCA). The thermodynamic properties are calculated by either of two equivalent formulations -- equilibrium constant or minimisation of Gibbs free energy, and are expressed in algebraic equations of the partial derivative of internal energy and gas constant with respect to temperature, pressure and equivalence ratio. The effect of the engine operating conditions on the thermodynamic cycle is studied, Results show ...
A thermodynamic model for predicting the distribution coefficients has been developed by taking into account the extraction mechanism and the chloride complexation when Sm, Eu, Gd, Tb, Dy and Ho for single component systems are extracted from acidic chloride solutions by di-2-ethylhexyl ester in kerosene, respectively. The model equation includes two constants, of which one corresponds to the apparent extraction equilibrium constant and the other is due to the variation of the activity coefficients of organic species. These values are determined from a few experimental data by the curve fitting method. Then, the distribution coefficients under untried calculations, Bromley's formulation is used to estimate the activity coefficients of aqueous species and the interaction parameters for some rare earth chlorides are reported in terms of morality and molarity using data from Spedding et al. According to the authors the validity of this method has ...
We study the spectral and temporal behavior of the High Mass X-ray Binary A 0535+26 during a `pre-outburst flare' which took place ~5 d before the peak of a normal (type I) outburst in August/September 2005. We compare the studied behavior with that observed during the outburst. We analyse RXTE observations that monitored A 0535+26 during the outburst. We complete spectral and timing analyses of the data. We study the evolution of the pulse period, present energy-dependent pulse profiles both at the initial pre-outburst flare and close to outburst maximum, and measure how the cyclotron resonance-scattering feature (hereafter CRSF) evolves. We present three main results: a constant period P=103.3960(5)s is measured until periastron passage, followed by a spin-up with a decreasing period derivative of Pdot=(-1.69+/-0.04)x10^(-8)s/s at MJD 53618, and P remains constant again at the end of the main outburst. The spin-up provides evidence for the ...
The relationship between the emission line equivalent width and the continuum luminosity, so called the Baldwin effect, plays an important role in studying the broad line region physics of AGNs. Using the archived ultraviolet spectra obtained by IUE, HST and HUT in 1978-2002, we investigated the intrinsic CIV Baldwin effect of a best-studied Seyfert 1 galaxy NGC 4151. Both its continuum flux and CIV emission line flux varied about two orders of magnitude in more than two decades, making it one of the best targets for studying the slope variation of the Baldwin effect. We fitted the CIV line profile of the 490 archived UV spectra of NGC 4151 with a same model consisting of a few Gaussian components, and derived the slope in the log-log plot for the total flux of CIV emission line against the UV continuum flux in different observation epochs.We found that the slope is not constant for NGC 4151, varying from 0.58 in the highest flux epoch to 0.83 in the lowest flux ...
The effects of equal #SIGMA#Ai for different combinations of the annealing temperature and annealing time on corrosion resistance and evolution of precipitates of Zircaloy-2 were investigated. Nodular corrosion resistance in the out-of-pile corrosion test was degraded with increasing #SIGMA#Ai only when it was increased by extending the annealing time at 894 K but did not depend on #SIGMA#Ai which was increased by raising the annealing temperature for a constant annealing time of 2.5 h. Extensive observation and micro-analysis of precipitates by analytical electron microscope (AEM) suggested the cause of degradation of nodular corrosion resistance to be the remarkable increase in volume fraction of Si-containing precipitates such as Zr_3Si and Zr_2Si, which were observed more frequently in large #SIGMA#Ai only when it was increased by extending the annealing time at 894 K. On the other hand, uniform corrosion resistance was improved with increasing #SIGMA#Ai ...
voltammetric methods. This remained evident for varying extents of silver dissolution. Ag(111) electrodes were oxidised in 0.1 M KCIO sub 4 solutions by a single swept ORC of 0.77x10 sup - sup 3 C cm sup - sup 2. The final rest potential of the Ag(111) working electrode was over the potential range of -36 mV to 114 mV versus the SCE where the silver islands of the reformed surface are believed to be unstable. Results show that a majority of silver islands of all sizes are stable with time, whereas the silver islands with irregular shapes tended to evolve to exhibit higher degrees of spherical geometry. Additionally, the position of the silver islands did not remain constant during the acquisition of STM images. Results from in situ STM demonstrated that the underlying step-terrace morphology of the Ag(111) electrodes did not remain constant with time. Both macroscale and nanoscale changes to the Ag(111) electrode surface were observed. It is ...
We report on the spectral cross-calibration results of the Konus-Wind, the Suzaku/WAM, and the Swift/BAT instruments using simultaneously observed gamma-ray bursts (GRBs). This is the first attempt to use simultaneously observed GRBs as a spectral calibration source to understand systematic problems among the instruments. Based on these joint spectral fits, we find that 1) although a constant factor (a normalization factor) agrees within 20% among the instruments, the BAT constant factor shows a systematically smaller value by 10-20% compared to that of Konus-Wind, 2) there is a systematic trend that the low-energy photon index becomes steeper by 0.1-0.2 and Epeak becomes systematically higher by 10-20% when including the BAT data in the joint fits, and 3) the high-energy photon index agrees within 0.2 among the instruments. Our results show that cross-calibration based on joint spectral analysis is an important step to understanding the ...
The isotropic and anisotropic hyperfine constants of the ground X/sup 2/..sigma../sup +/ state of /sup 88/SrF and /sup 86/SrF are reported. Vibrational and rotational dependences are studied in a Dunham expansion analysis. Furthermore, the vibrational, rotational, and isotopic dependence of the spin-rotation constant is determined. The following values are obtained for X/sup 2/..sigma../sup +/, ..nu.. = 0, in /sup 88/SrF: ..gamma../sub 0/ = 74.79485 MHz, ..gamma../sub 1/ = 5.752 x 10/sup -5/ MHz, ..gamma../sub 2/ = -6.3 x 10/sup -10/ MHz, b/sub 0/ = 97.0834 MHz, b/sub 1/ = -3.300 x 10/sup -4/ MHz, c/sub 0/ = 30.268 MHz, C/sub I/ = 0.00230 MHz, where ..gamma.. is the spin-rotation parameter, b and c are the Frosch and Foley hyperfine parameters, and C/sub I/ is a nuclear spin-rotation correction. 4 figures, 4 tables.
The two-compartment radioassay for microbial kinetics based on continuous measurement of the {sup 14}CO{sub 2} released by bacterial metabolism of 14C-labeled substrate offers a valuable approach to testing the potency of antimicrobial drugs. By using a previously validated radioassay with gram-positive and gram-negative bacteria, a group of protein synthesis inhibitors was evaluated for their effect on microbial growth kinetics. All tested drugs induced changes in both the slopes and intercepts of the growth curves. An exponential growth model was applied to quantify the drug effect on the processes of bacterial {sup 14}CO{sub 2} liberation and cell generation. The response was measured in terms of a generation rate constant. A linear dependence of the generation rate constant on the dose of spectinomycin was observed with Escherichia coli. Sigmoidal-shaped curves were found in the assays of chloramphenicol and tetracycline. The implications ...
The Co-doped BaTiO{sub 3} nanosized powders and ceramics were prepared via the sol-gel process. The powders and ceramics were characterized by methods of XRD, SEM and TEM. The dielectric properties of the ceramics were also determined by these methods. The influence of sintering temperature, sintering time and Co concentration on the microstructure and dielectric properties was discussed. The results revealed that the powders were in nanometer scale (30-50 nm) and were mainly composed of cubic BaTiO{sub 3} phase and small amount of BaCO{sub 3}. After sintering, both the cubic BaTiO{sub 3} and BaCO{sub 3} were transformed into tetrahedron BaTiO{sub 3}. The sintering temperatures of the Co-doped BaTiO{sub 3} ceramics decreased (about 100 deg. C) and the Curie temperatures of the ceramics were then moved to lower temperature. In addition, the dielectric constant of the ceramics doping with Co was higher than that of the pure BaTiO{sub 3} ceramics. The dielectric ...
Mixtures of organic-inorganic substances are studied for their performance as energy storage media. Use is made of the fact that organic substances give higher amounts of energy but within a wide range of temperature on the one side and the fact that inorganic substances give lower amounts of energy at constant temperature on the other side. Mixtures of both types of substances, in different ratios, are investigated for the object of determining that optimum composition which stores a higher amount of energy and, meanwhile, releases it at a constant temperature or within a narrow range of temperature. The mixtures used are composed of Glauber`s salt (Na{sub 2}SO{sub 4}.10H{sub 2}O) and stearic acid in different proportions. The effect of cooling fluid flow rate and ambient temperature as well as the effect of addition of a nucleating agent is studied. The results showed that the highest amount of energy stored could be obtained from a mixture ...
Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the ...
The credibility of the model proposed by Ghosh in predicting the refractive indices of mixed semiconductor crystals of technological importance within their miscibility range as a function of band gap is demonstrated. The high-frequency refractive indices of four quaternary alloys Al_xGa_1_-_x_-_yIn_yP (y = 0.49, 0 #<=# x #<=# 0.51), InSb_xAs_1_-_x_-_yP_y (y = 2.2x, 0 #<=# x #<=# 0.313, 0 #<=# y #<=# 0.638), Cd_xZn_1_-_x_-_yHg_ySe (x + y = 1, 0.153 #<=# x #<=# 0.684, 0.316 #<=# y #<=# 0.847), and CdS_1_-_x_-_ySe_xTe_y (x + y = 1, 0.15 #<=# x #<=# 0.93, 0.07 #<=# y #<=# 0.85) are calculated according to the relation n"2-1 = A/(E_g + B)"2 where A is an energy gap dependent constant and B is a constant depending on crystal ionicity. The calculated values show excellent agreement with the experimental data thus justifying the validity of the model.
Let A and B be two affinely generating sets of (Z_2)^n. As usual, we denote their Minkowski sum by A+B. How small can A+B be, given the cardinalities of A and B? We give a fairly tight answer to this question. Our bound is attained when both A and B are unions of cosets of a certain subgroup of (Z_2)^n. These cosets are arranged as Hamming balls, the smaller of which has radius 1. By similar methods, we reprove the Freiman-Ruzsa theorem in (Z_2)^n, with an optimal upper bound. Denote by F(K) the maximal spanning constant || / |A|, over all subsets A of (Z_2)^n with doubling constant |A+A| / |A| < K. We explicitly calculate F(K), and in particular show that 4^K / 4K < F(K) (1+o(1)) < 4^K / 2K. This improves the estimate F(K) = poly(K) 4^K, found recently by Green and Tao and by Konyagin.
Using the transfer matrix method we calculate the omni-directional band gap of a 1-D photonic crystal consisting of alternating layers of two dielectric materials A and B with refractive index n{sub A} and n{sub B}, respectively. The refractive index of layer A is constant and the refractive index of layer B varies according to the envelope of a Gaussian function. We find that under certain circumstances it is possible to obtain 100% reflectivity for both polarizations and any value of the incident angle of the electromagnetic waves. Although the structure considered does not posses a higher omni-directional band gap than the periodic sequence of low and high constant refractive indexes, it can be used to produce a new type of omni-directional mirrors without abrupt interfaces. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
A dilute tungsten heavy alloy consisting of 50W-35Ni-15Fe (wt pct) was liquid phase sintered at 1,500 C for times ranging from 30 to 960 minutes. This alloy corresponds to a nominal solid content of 20 vol pct at the sintering temperature. Because of the excess liquid, the alloy densified easily and exhibited extensive liquid-solid separation due to the density difference between the phases. The solid content at the compact bottom ranged from 45 to 70 vol pct over position and time. The microstructure of the settled region was quantified for volume fraction of tungsten, grain size, connectivity, and settled solid angle of repose. These results provide a basis for extending the microstructural parameters to possible microgravity conditions. The grain growth rate constant varies with the inverse 2/3 power of the volume fraction of liquid, possibly reflecting combined coalescence and solution-reprecipitation processes. This volume-fraction effect on the ...
A dilute tungsten heavy alloy consisting of 50W-35Ni-15Fe (wt pct) was liquid phase sintered at 1,500 C for times ranging from 30 to 960 minutes. This alloy corresponds to a nominal solid content of 20 vol pct at the sintering temperature. Because of the excess liquid, the alloy densified easily and exhibited extensive liquid-solid separation due to the density difference between the phases. The solid content at the compact bottom ranged from 45 to 70 vol pct over position and time. The microstructure of the settled region was quantified for volume fraction of tungsten, grain size, connectivity, and settled solid angle of repose. These results provide a basis for extending the microstructural parameters to possible microgravity conditions. The grain growth rate constant varies with the inverse 2/3 power of the volume fraction of liquid, possibly reflecting combined coalescence and solution-reprecipitation processes. This volume-fraction effect on the ...
A study was undertaken of the effect of monovalent cations (Li/sup +/, Na/sup +/, K/sup +/) on the dielectric constant (epsilon) of the water-lipid interface of unilamellar phosphatidylcholine (PC) vesicles, i.e., the ester carbonyl oxygen region of the PC molecules or the neighborhood of the oxygen atoms of the phosphorylcholine moiety. epsilon was determined by reacting the free radical 1,1-diphenyl-2-picrylhydrazyl with ..cap alpha..-tocopherol incorporated in the lipid vesicles. The results are consistent with a decrease of epsilon (LiCl: 35.5 to 29.5; NaCl: 34 to 29; KCl: 33 to 29) as the concentration of the salts in the solvent media increases from 0.025 to 0.5 M. These effects can be rationalized in terms of dielectric saturation at the water-lipid interface brought about by ion-induced local electric fields. In the unilamellar PC vesicles the effect of the ions on epsilon follows the sequence K/sup +/ > Na/sup +/ > Li/sup +/ which contrasts ...
Object: To control the average liquid level of each steam generator at a constant level irrespective of the flow rate of sodium thereby to decrease change in the retained amount of sodium and at the same time to improve the load response characteristic. Construction: A method for decreasing to as large an extent as possible a change in the amount of sodium retained in a steam generator due to change in the flow rate, which comprises the steps of detecting the main recirculating flow rate of liquid sodium by the use of a sodium flow rate detector, amplifying the detected flow rate signal depending upon the ratio between the flow rates respectively in a super-heater and a re-heater (distribution ratio), delivering the amplified signal to a function generator which generates a liquid level setting signal for maintaining the respective average liquid levels of the super-heater and the re-heater at constant levels irrespective of the flow rates, and ...
Local-density-functional calculations of the energy bands, equilibrium lattice constant, bulk modulus, and cohesive energy have been performed using a newly developed self-consistent full-potential linearized augmented-plane-wave (LAPW) program. Scalar-relativistic effects are included for the band states, and the core-level states are treated fully relativistically in a central-field approximation. Excellent agreement is obtained with the experimental lattice constant and bulk modulus. Generally good agreement is obtained with the scalar-relativistic pseudopotential results of Bylander and Kleinman. In this context, the impact of various approximations used in including the core states is assessed, and these findings are related to the frozen-core and pseudopotential approximations, especially with regard to the treatment of the somewhat overlapping 5p semicore states and their effect on ground-state properties. Comparison with the recent LAPW ...
The effects of the contrast of the pump field interference pattern, that is, the effectiveness of the dynamic amplitude-phase grid, and various optical arrangements on the lasing efficiency and tuning range of a dynamic distributed-feedback dye laser are investigated. It is shown that the proper choice of prism apex angle, prism material and dye solvent in a laser in the range 400-1000 microns pumped by two beams of different intensity directed through the congruent sides of an isosceles prism in contact with the active medium solution on its third side can lead to optical losses of less than 2% from the boundaries of the prism. Measurements of polymethine dye laser efficiency and tuning range as a function of the relative intensity of the two ruby-laser pump beams reveals that as the contrast of the pump beam interference pattern decreases, the tuning range remains practically constant and the efficiency increases in the nonlinear (saturation) region of the ...
The Moderator Temperature Coefficient of reactivity (MTC) was earlier proven to be properly determined via noise analysis when the neutron noise is measured locally and when the radial average of the moderator temperature noise is used. Nevertheless, measurements revealed that the MTC was correctly estimated on a much narrower frequency band (0.6 - 0.7 Hz) than expected (0.1 - 1.0 Hz). The present paper investigates the effect of the feedback on the MTC determination using this new MTC noise estimator (which could explain the deviation at low frequencies, i.e. between 0.1 - 0.5 Hz) and the effect of the detector time constants (which could explain the deviation at high frequencies, i.e. between 0.7 - 1.0 Hz). For that purpose, a coupled neutronic/thermalhydraulic model of the Ringhals-3 PWR is developed in the frequency-domain, based on a radial 2-dimensional heterogeneous representation of the core. The transfer function of the detectors is also modelled in this ...
Flow structures and heat transfer at the liquid-liquid interface are investigated experimentally and analytically in the entrance region of a liquid metal-water stratified flow in a horizontal rectangular channel. The two-equation model and the mixing length mode, including a damping turbulent region near the interface, are used to obtain analytical results for pressure drop, position of the interface, and heat transmission coefficients across the interface. Analytical results are compared with experimental results. Conclusions are presented and include the following: (1) vertical position of the interface increases or decreases along the stream according to the fluid flow rate of both fluids, and then approaches a constant value in the fully developed region; (2) pressure drop increases along the stream from the minimum value at the inlet; and (3) heat transmission coefficients across the interface decrease in the entrance region to a minimum value and then ...
The quantum behavior of the vacuum Bianchi type-IX universe with the cosmological constant is investigated in terms of the Ashtekar variables. An exact solution to the quantum Hamiltonian constraint in the holomorphic representation is given. This solution reduces to the Hartle-Hawking wave function in the spatially isotropic sector and extends in the triad representation to the classically forbidden region where the determinant of the spatial metric becomes negative. The analysis of the quantum Robertson-Walker universe indicates that if the superspace is extended to such a classically forbidden region, the holomorphic representation picks up some restricted class of solutions in general. This observation leads to a new ansatz on the boundary condition of the Universe. In particular, the behavior of the Lorentzian and Euclidean WKB orbits corresponding to the solution suggests a new picture on the semiclassical behavior of the quantum Universe: that the Universe ...
The quantum behavior of the vacuum Bianchi type-IX universe with the cosmological constant is investigated in terms of the Ashtekar variables. An exact solution to the quantum Hamiltonian constraint in the holomorphic representation is given. This solution reduces to the Hartle-Hawking wave function in the spatially isotropic sector and extends in the triad representation to the classically forbidden region where the determinant of the spatial metric becomes negative. The analysis of the quantum Robertson-Walker universe indicates that if the superspace is extended to such a classically forbidden region, the holomorphic representation picks up some restricted class of solutions in general. This observation leads to a new ansatz on the boundary condition of the Universe. In particular, the behavior of the Lorentzian and Euclidean WKB orbits corresponding to the solution suggests a new picture on the semiclassical behavior of the quantum Universe: that the Universe ...
A series of cyclic strain controlled tests have been carried out at 600/sup 0/C on three high temperature austenitic iron-based alloys, AISI type 316 stainless steel, Alloy 800 H and Sandvik 253 MA. The tests were carried out under constant total strain control using a constant strain rate of 0.005 s/sup -1/. By considering the changes in modulus throughout the life of each specimen it was found that damage evolution could be successfully predicted as a function of plastic strain range despite the fact that each alloy had been chosen because of a different stress response at 600/sup 0/C. Although each alloy accumulated fatigue damage in a similar manner the longer lives of Sandvik 253 MA and Alloy 800 H at a given total strain range were due to a smaller plastic strain component and a reduced stage I crack propagation rate. In the 253 MA alloy, slip was predominantly planar with some cells occasionally forming at high strain ranges. Slip was ...
We construct two families of refinements of the (projectivized) support variety of a finite dimensional module $M$ for a finite group scheme $G$. For an arbitrary finite group scheme, we associate a family of {\\it non maximal rank varieties} $\\Gamma^j(G)_M$, $1\\leq j \\leq p-1$, to a $kG$-module $M$. For $G$ infinitesimal, we construct a finer family of locally closed subvarieties $V^{\\ul a}(G)_M$ of the variety of one parameter subgroups of $G$ for any partition $\\ul a$ of $\\dim M$. For an arbitrary finite group scheme $G$, a $kG$-module $M$ of constant rank, and a cohomology class $\\zeta$ in $\\HHH^1(G,M)$ we introduce the {\\it zero locus} $Z(\\zeta) \\subset \\Pi(G)$. We show that $Z(\\zeta)$ is a closed subvariety, and relate it to the non-maximal rank varieties. We also extend the construction of $Z(\\zeta)$ to an arbitrary extension class $\\zeta \\in \\Ext^n_G(M,N)$ whenever $M$ and $N$ are $kG$-modules of constant Jordan type.
A numerical investigation of the mixing of gaseous uranium and hydrogen inside an open-cycle gas core nuclear rocket engine (spherical geometry) is presented. The gaseous uranium fuel is injected near the centerline of the spherical engine cavity at a constant mass flow rate, and the hydrogen propellant is injected around the periphery of the engine at a five degree angle to the wall, at a constant mass flow rate. The main objective is to seek ways to minimize the mixing of uranium and hydrogen by choosing a suitable injector geometry for the mixing of light and heavy gas streams. Three different uranium inlet areas are presented, and also three different turbulent models (k-var-epsilon model, RNG k-var-epsilon model, and RSM model) are investigated. The commercial CFD code, FLUENT, is used to model the flow field. Uranium mole fraction, axial mass flux, and radial mass flux contours are obtained. copyright 1997 American Institute of Physics.
Mixed convection heat transfer from longitudinal fins inside a horizontal channel has been investigated in the natural convection dominated region for a wide range of Rayleigh numbers and different fin heights and spacings. An experimental parametric study was made to investigate effects of fin spacing, fin height and magnitude of heat flux on mixed convection heat transfer from rectangular fin arrays heated from below in a horizontal channel. The optimum fin spacing to obtain maximum heat transfer has also been investigated. During the experiments constant heat flux boundary condition was realized and air was used as the working fluid. The velocity of fluid entering channel was kept nearly constant (0.02win0.025m/s) using a flow rate control valve so that Reynolds number was always about ...
Electron paramagnetic resonance (EPR) of coals was considered by using iodine doping technique. Sub-bituminous coal (WA) and bituminous coal (UF) were used to observe EPR spectra using microwaves. With the UF coal, strength of the narrow component of the spectra was found constant regardless of amount of the doped iodine, wherein radicals without interaction with iodine were detected. Strength of the broad component increased with the iodine doping amount, where in deviation of {pi} electrons was detected, which have been generated as a result of interaction between aromatic rings and iodine in the coals. Spin concentration of the WA coal with low coalification degree is constant regardless of the iodine doping amount, and the interaction of the iodine with the aromatic rings was found small. The higher the coalification degree, the more the aromatic ring structure grows, and electron donor capability for the iodine increases. In a system with ...
The biosorption of lead (II) and copper (II) ions, single component and binary systems, by dried P. putida was investigated in a batch system. The effects of initial pH, temperature, initial single and binary mixture concentrations on the biosorption kinetics and equilibrium uptake of each component, both single and binary mixtures were investigated. The bacterial biomass exhibited the highest single and binary lead (II) and copper (II) ions uptake capacity at 25 and 30 deg. C, respectively, the initial pH value of 5.5 and at the initial metal ions concentration of 100 mg dm{sup -3}. The Freundlich and Langmuir adsorption models were used for the mathematical description of the biosorption equilibrium and isotherm constants were evaluated at different temperatures. Adsorption data were well described by the Langmuir model, although they could be modeled by the Freundlich equation. The thermodynamics constants of the adsorption process: ...
The combined effects of environment, yield strength and stress state on the cracking susceptibility of beta-extruded Ti-6Al-6V-2Sn have been examined. At a constant yield strength and under plane strain conditions, the stress intensity required for slow crack propagation decreased as the severity of the environment increased, i.e., from laboratory air to 3.5% NaCl. Furthermore, the crack propagation rates were a function of both stress intensity, and environmental severity. Although the fracture toughness and threshold stress intensities for slow crack growth generally decreased with increasing yield strength, aging, which resulted in the precipitation of ordered Ti3Al particles in the primary alpha phase, tended to accentuate the susceptibility of this alloy to sustained load/stress corrosion cracking. Finally, at constant yield strength, the sustained load cracking threshold stress intensity was a function of stress state.
The detailed energy-band structure of hexagonal-close-packed technetium, corresponding to the atomic configuration 4d"55s"2 of its seven outermost valence electrons, has been obtained throughout the Brillouin zone using the composite-wave variational version of the augmented-plane-wave (APW) method in conjunction with the X#alpha# (#alpha# = 0.702 99) exchange approximation for obtaining the potentials. From the band-structure data the electronic density of states (DOS) and the angular-momentum--decomposed DOS were calculated by the accurate Gilat-Raubenheimer method. These quantities were used to calculate the electron-phonon coupling constant and the transition temperature (T/sub c/) using the theories of Gaspari and Gyorffy and of McMillan. Also studied were the Fermi surface and the optical properties of Tc via the imaginary part of the interband dielectric constant for bound electrons, the latter being the first of such a study on Tc to ...
Cu[sup 2+] is a sensitive electron spin resonance (ESR) probe for the penetration of various polar solvents in membranes made of Nafion and as an indicator for the replacement of one solvent by another. The ESR parameters (g and [sup 63]Cu hyperfine tensors) can be translated into a structure of the solvent around the cation. The replacement of a solvent in the membrane by another depends on the polarity of the two solvents. The solvent with the largest dielectric constant, N-methylformamide (NMF), can be replaced by water but not by methanol or acetonitrile (dielectric constants 182, 78.5, 32.7, and 37.5, respectively). Preferential solvation of the cation by water in three water/acetonitrile mixtures (9:1, 1:1, and 1:9 by volume) in contact with silica gel, Sephadex, and Nafion has been observed in various degrees. Nafion is most selective, followed by Sephadex and by silica gel. The selectivity appears to be related to electrostatic ...
First-principles plane-wave pseudopotential and full-potential linearized-augmented plane-wave methods have been used to study the elastic and electronic properties of several potential superhard RuO_2 phases. The structures, relative stabilities, and the elastic constants and bulk moduli of these phases have been calculated within local-density approximation (LDA) and generalized gradient approximation (GGA). In RuO_2, the LDA and GGA approximations yield smaller and larger lattice constants, respectively, for the Pa3-bar-RuO_2 structure. The internal structural parameter for oxygen atoms in the Pa3-bar structure has a volume dependence that differs from the experimental result and therefore implies a significantly different compression mechanism. The calculated bulk moduli are very similar for the fluorite and Pa3-bar structures and therefore apparently independent of the internal structural parameter. The structure and stability of a ...
The ion-velocity dependence of the ionization probability for an atom ejected from a surface is examined by using a quantum approach in which the coupled motion between electrons and the outgoing nucleus is followed along the whole trajectory by solving the stationary Schroedinger equation. We choose a very-small-cluster-model system in which the motion of the atom is restricted to one dimension, and with energy potential curves corresponding to the involved channels varying appreciably with the atom position. We found an exponential dependence on the inverse of the asymptotic ion velocity for high emission energies, and a smoother behavior with slight oscillations at low energies. These results are compared with those obtained within a dynamical-trajectory approximation using either a constant velocity equal to the asymptotic ionic value, or expressions for the velocity derived from the eikonal approximation and from the classical limit of the current vector. Both ...
BaxSr1-xTiO3 (x=0.6, 0.75, 0.80, 0.85 and 0.9) compositions are prepared by solid-state reaction route using controlled heating and cooling. Density optimization by varying sintering temperature was achieved. X-ray diffraction (XRD) analysis shows the phase pure materials. The lattice constant decreases from 3.9868A (x=0.90) to 3.9449A (x=0.60) with increasing Sr2+; the tetragonal distortion also decreases. Dielectric constant show sharp peaks for samples having low strontium content (0.10, 0.15) and gets smeared out as the strontium content is increased (0.20, 0.25). For further higher Sr2+ composition (0.40), the dielectric peak could not be observed in the measured temperature range. The peak broadening in Sr2+ rich compositions indicates that diffused transitions and is attributed to t...
Microwave dielectric properties and far-infrared reflectivity spectra of (Zr{sub 0.8}Sn{sub 0.2})TiO{sub 4} ceramics with 1.0mol.% Sb{sub 2}O{sub 5} or WO{sub 3} were investigated in the various sintering atmospheres. The Q{center_dot}f value of the specimens sintered in oxygen atmosphere was enhanced due to the decrease of lattice anharmonic interaction resulting from the decrease of oxygen vacancies, whereas the dielectric constants remained constant regardless of sintering atmosphere. The effects of the sintering atmosphere on the changes of ionic and electronic polarization and the intrinsic microwave losses of the specimens were investigated by using the infrared reflectivity spectra from 50 to 4000cm{sup -1}, which were evaluated using Kramers-Kronig analysis and classical oscillator model. The relative tendency of microwave dielectric properties of the specimens calculated from the reflectivity data was in good agreement with the results ...
Makrofol-De 1-1 CC Polycarbonate is a class of polymeric solid state nuclear track detectors which has many applications in various industrial fields. A study of the modification possibility of the dielectric properties of Makrofol polymer using laser irradiation has been carried out. In tbe present work, Makrofol samples were irradiated using different fluences between 0.47 and 10.4 J/cm"2 of 5 watt infrared pulsated laser. The mollifications in the laser irradiated Makrofol samples have been studied as a function of fluence using dielectric constant #epsilon#', dielectric loss #epsilon#"and AC conductivity #sigma#_AC measurements. Tbe frequency dependencies (100 Hz-5 MHz) of #epsilon#', #epsilon#"and #sigma#_AC at 35 degree c were investigated. The dielectric constant #epsilon#', dielectric loss #epsilon#"and AC conductivity #sigma#_AC were found to increase at heating up to 100 degree C. This indicates that #epsilon#', #epsilon#"#sigma#_AC ...
This paper investigates the relationship between economic growth and pollutant emissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO{sub 2}) and sulfur dioxide (SO{sub 2}) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO{sub 2} emissions and GDP has been found, with income turning point approximately equals to $1200 (constant 2000 prices) or to $3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO{sub 2} emissions. Furthermore, the causality results show that the relationship ...
This paper investigates the relationship between economic growth and pollutant emissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO2) and sulfur dioxide (SO2) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO2 emissions and GDP has been found, with income turning point approximately equals to $1200 (constant 2000 prices) or to $3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO2 emissions. Furthermore, the causality results show that the relationship between income and ...
This paper investigates the relationship between economic growth and pollutant emissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO{sub 2}) and sulfur dioxide (SO{sub 2}) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO{sub 2} emissions and GDP has been found, with income turning point approximately equals to 1200 (constant 2000 prices) or to 3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO{sub 2} emissions. Furthermore, the causality results show that the relationship ...
The present paper deals with the conversion of solar energy in a gas turbine plant with a parabolic dish collector. Particular consideration is devoted to the thermodynamic and mechanical design and partload behavior of the receiver. The incident sunlight is focussed by the parabolic dish and then beamed into the cavity receiver. Here the working medium of the gas turbine flows through tubes and is heated up to the receiver outlet temperature. The task of the receiver is to transfer the radiated energy as efficiently as possible to the working medium. Furthermore the required heating surface should be small as possible i.e. optimum use must be made of the tube material with respect to its state of stress. It is shown which geometric and thermodynamic plant parameters influence these two design criteria. An optimum receiver design is presented on the basis of the results thus obtained. Finally, the variations in receiver efficiency and tube stressing when the gas turbine runs at ...
The conditions of production and the stability regions have been studied for the following crystallohydrates of trisubstituted uranyl orthophosphates: (UO_2)_3(PO_4)_2x6H_2O, (UO_2)_3(PO_4)_2x4H_2O, and (UO_2)_3(PO_4)_2xH_2O. Their thermal stability has been studied. It is shown that thermal dehydration of high-water hydrates at 220-240 deg C gives (UO_2)_3(PO_4)_2xH_2O. The anion composition and crystal structure of the compound remain constant up to 1000 deg C. The mixture of the composition of U_3O_8xU_3(PO_4)_4 is the final product of decomposition at 1000 deg C. The thermodynamic constants of dehydration processes have been calculated. A conclusion has been made about the polymer structure of the compound in which water is located between the uranylphosphate layers.
Constant extension rate (CERT) tests were performed on Alloy 690 and Alloy 800 nuclear steam generator tubing specimens. For the Alloy 690 specimens, tests were performed in deaerated 10% sodium hydroxide solutions at 315 deg C with a +100 mV applied potential. For the Alloy 800 specimens, tests were performed in deaerated 5% sodium hydroxide solutions at 343 deg C with no applied potential. The test specimens were machined from tubing which was produced by different manufacturing processes and in different heat treated conditions. The Alloy 690 tubing was tested in six different thermomechanical conditions, while the Alloy 800 tubing was tested in four different thermomechanical conditions. The results from the test program include a complete microstructural examination using light-optical and scanning electron microscopy. The CERT test results (such as maximum stress achieved and crack morphology) are correlated to tubing microstructure, chemistry and ...
Complex formation between neptunium(IV) and neptunium(V) ions with thiosemicarbazidodiacetic acid in solution has been studied spectrophotometrically. Under the conditions employed herein complexes of composition 1:2 and 1:1, in the form Np(HR)_2 and NpO_2R"2"-, respectively, are formed. Stability constants for these complexes have been calculated and their molar extinction coefficients have been determined, and are equal to (1.33 +/- 0.25) x 10"7, log #beta# = 7.11 +/- 0.8, element of/sub K/ = 96 +/- 3 liter/mole x cm for Np(HR)_2, and (2.34 +/- 0.2) x 10"3, log #beta# = 3.36 +/- 0.036, element of/sub K/ = 235 +/- 1 liter/mole x cm for NpO_2R"2"-. Spectrophotometric titration has also shown that in basic solutions thiosemicarbazidodiacetic acid behaves as a tribasic acid; it third ionization constant has been determined and is equal to 10/sup -9.2/.
Soils of arid regions of Central Asia contain salts of different types that may differentially affect seed germination and plant development. We studied effect of NaCl, Na2SO4, 2NaCl + KCl + CaCl2 and 2Na2SO4+K2SO4+MgSO4 on germination of Kochia prostrata and Kochia scoparia seeds under a range of concentrations from 0.5 to 5% and at two constant temperature regimes +22 degrees C and +6 degrees C. The observed salt tolerance limit of germination at constant temperature +22 degrees C for both species was 5-6%, while at low temperature (+6 degrees C) this limit was 2%. The salt tolerance of young plants (before flowering) was 3% for NaCl. Low concentrations of sulfuric and mixed salts had a stimulating effect on seed germination in K. prostrata. Despite similarity of salt-tolerance limits...
The growth kinetics constants and concentration of active attached biomass in an anaerobic fluidized bed which decomposes acetic, propionic and butyric acid were estimated. The mixture of above mentioned fatty acids was supplied to the fluidized bed in the range of hydraulic retention time (HRT) from 0.25 to 2 days. After the effluent reached in a steady state in quality, batch experiments were conducted separately with each fatty acid as a substrate in order to investigate the decomposition characteristics of each substrate by attached biomass. In order to estimate the parameter values of the growth kinetics of the bacteria, batch experiments were also conducted under the completely mixed condition using detached biomass from a support material. The changes of fatty acid concentrations with time were clearly expressed with the Monod growth model. Maximum specific substrate decomposition rates and saturation constants, and active biomass ...
This paper addresses the problem of blind separation of convolutive mixtures of BPSK and circular linearly modulated signals with unknown (and possibly different) baud rates and carrier frequencies. In previous works, we established that the Constant Modulus Algorithm (CMA) is able to extract a source from a convolutive mixture of circular linearly modulated signals. We extend the analysis of the extraction capabilities of the CMA when the mixing also contains BPSK signals. We prove that if the various source signals do not share any non zero cyclic frequency nor any non conjugate cyclic frequencies, the local minima of the constant modulus cost function are separating filters. Unfortunately, the minimization of the Godard cost function generally fails when considering BPSK signals that have the same rates and the same carrier frequencies. This failure is due to the existence of non-separating local minima of the Godard cost function. In order ...
We investigate the quantum cosmology of spatially homogeneous models with compact spatial sections admitting a u(2) isometry algebra. The metric ansatz in these models is that of Bianchi type IX with two scale factors set to be equal. We apply the Hartle-Hawking no-boundary path integral prescription and find the semi-classical contributions to the wave function. Exact formulae are obtainable for certain contributions and otherwise the limits of large and small anisotropy (for the pure vacuum case) and large spatial volume or small anisotropy (for the case with a positive cosmological constant) are considered. For the pure vacuum case we find no rapidly oscillating semiclassical components in the wave function, and hence do not recover lorentzian space-time as a prediction of the no-boundary proposal. For the case with a cosmological constant the wave function does contain rapidly oscillating components and thus predicts approximately ...
We investigate the quantum cosmology of spatially homogeneous models with compact spatial sections admitting a u(2) isometry algebra. The metric ansatz in these models is that of Bianchi type IX with two scale factors set to be equal. We apply the Hartle-Hawking no-boundary path integral prescription and find the semi-classical contributions to the wave function. Exact formulae are obtainable for certain contributions and otherwise the limits of large and small anisotropy (for the pure vacuum case) and large spatial volume or small anisotropy (for the case with a positive cosmological constant) are considered. For the pure vacuum case we find no rapidly oscillating semiclassical components in the wave function, and hence do not recover lorentzian space-time as a prediction of the no-boundary proposal. For the case with a cosmological constant the wave function does contain rapidly oscillating components and thus predicts approximately ...
Non-axisymmetric forces are presented for 107 spiral galaxies using the 2 Micron All Sky Survey (2MASS) images. We apply both Cartesian integration and a polar grid integration utilizing a limited number of azimuthal Fourier components of density. We found that bar strength is independent of the method used to evaluate the gravitational potential. However, the polar method is more suitable for weak and noisy images. Bar strength was found to be sensitive to the Hubble-type dependent scale height of the disk, which has been ignored in the previous studies. On the other hand, the method is rather insensitive to the vertical model of the disk, as long as a same vertical dispersion is assumed, or to the boxy/peanut shaped structure, studied in terms of non-constant vertical scale height along the disk. In the near-IR most galaxies in our sample show non-axisymmetric forces in some level, and 40 percent of them have bars in a sense that they have regions with a ...
The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the augmentation observed are negligible. For the range of values studied ...
Mathematical tools are needed to screen out sites where Joule-Thomson cooling is a prohibitive factor for CO{sub 2} geo-sequestration and to design approaches to mitigate the effect. In this paper, a simple analytical solution is developed by invoking steady-state flow and constant thermophysical properties. The analytical solution allows fast evaluation of spatiotemporal temperature fields, resulting from constant-rate CO{sub 2} injection. The applicability of the analytical solution is demonstrated by comparison with non-isothermal simulation results from the reservoir simulator TOUGH2. Analysis confirms that for an injection rate of 3 kg s{sup -1} (0.1 MT yr{sup -1}) into moderately warm (>40 C) and permeable formations (>10{sup -14} m{sup 2} (10 mD)), JTC is unlikely to be a problem for initial reservoir pressures as low as 2 MPa (290 psi).
Thermodynamic data has been selected for solids and aqueous species of technetium. Equilibrium constants have been calculated in the temperature range 0 to 300 deg C at a pressure of 1 bar for T<100 deg C and at the steam saturated pressure at higher temperatures. For aqueous species, the revised Helgeson-Kirkham-Flowers model is used for temperature extrapolations. The data base contains a large amount of estimated data, and the methods used for these estimations are described in detail. A new equation is presented that allows the estimation of #DELTA#_rCdeg_p_m values for mononuclear hydrolysis reactions. The formation constants for chloro complexes of Tc(V) and Tc(IV), whose existence is well established, have been estimated. The majority of entropy and heat capacity values in the data base have also been estimated, and therefore temperature extrapolations are largely based on estimations. The uncertainties derived from these calculations ...
In the present work the effect of different surface conditions on plasma nitriding response of AISI M2 high speed steel was investigated. The plasma nitriding of ground and sandblasted samples and drills was performed at temperatures of 400 C and 500 C for two gas mixtures: 5 vol.% N{sub 2} and 76 vol.% N{sub 2} in hydrogen. Surface layers were characterized before and after plasma nitriding concerning the microstructure, roughness, microhardness, chemical composition, phase composition and residual stress states. Machining tests were carried out with drills during which drilling forces and flank wear have been measured. A significant effect of the surface state prior to nitriding on residual stress states and the properties of the nitrided layer and untreated core has been observed. Thinner nitrided layers on ground and sandblasted samples were attributed to high compressive residual stress states and a stress affected diffusion of nitrogen and carbon. In the machining tests, ...
Purpose: The aim of this study was to test the feasibility of iliac artery stent placement under MR guidance with real-time MR radial scanning in an animal model. Materials and methods: The experiments were performed on three pigs in a 1.5 T scanner. Radial scanning with a gradient echo technique (T{sub R} 8.4 ms, T{sub E} 3.6 ms, flip angle 10 ) was used. A dedicated backprojector performed the reconstruction of the raw data in real-time. The resulting MR-images were displayed on LCD screens beside the magnet. The sliding window reconstruction technique allowed image acquistion at a frame rate of 16 images per second. MR-compatible self-expanding stents with a diameter of 8 mm and a length of 3 cm were placed into the left iliac artery. Their positions were verified by digital subtraction angiography (DSA) and compared to MRI. Results: All stents were successfully placed. Stent positions as monitored by real-time MR were identical to those seen on DSA images. The time needed for exact ...
A working group (SC 45B/WG B8) exists within the international electrochemical commission (IEC) which is working on the combination and revision of the IEC standards 61283, 61323, 61344, 61525 and 61526. All these standards concern direct reading, electronic, personal dose equivalent meters for the quantities H{sub p}(10) and H{sub p}(0,07); they are different with regard to the kind of radiation (photons, and/or beta rays and/or neutrons). The new standard with the number 61526 shall cover the following topics: 1. Combination of all the mentioned standards; 2. Maintenance of the essential requirements of the former standards; 3. Inclusion of the determination of the uncertainty of measurement for the measured dose equivalent value according to the ''Guide to the Expression of Uncertainty in Measurement''; 4. Consideration of all the relevant ISO-standards for reference radiation fields for photon, beta and neutron radiations; 5. Consideration of ...
To evaluate the current situation and implementation of embolization of uterine leiomyomas into the treatment concept in women with symptomatic uterine leiomyomas in Germany. A questionnaire addressing the clinical background of uterine myomas, recommended treatment concepts, preclinical evaluation, technical approach and complications was sent to 164 departments of gynecology and radiology in Germany. 33 radiological departments and 19 gynecological departments submitted a completed questionnaire. Only 7 departments of radiology reported to have own experience with embolization of uterine leiomyomas, while only 2 departments of gynecology considered embolization as an alternative treatment option in patients with symptomatic leiomyomas. 18/33 radiological departments offer this treatment option but get no patient referrals. Agreement was found concerning the indications for treatment, preclinical evaluation by ultrasound and MRI, preferable location of treatable fibroids, technical ...
The aim of this work was the examination of the coarse grain recrystallisation of the {gamma}-free ODS nickel-based alloy PM 1000 depending on the various parameters due to the processing during heat treatment. After isotropic hot compacting (HIP) of the mechanically alloyed powder, one observes a homogeneous sub-microscopic fine grain structure which can coarsen during high temperature heat treatment, due to sufficiently high driving force from the grain boundary energy via abnormal grain growth to 600 times its size. The setting of the elongated high temperature resistant recrystallisation structure is, however, not connected with this. The dependence of the sucess of re-crystallisation on the re-forming parameters (re-forming temperature and degree of re-forming) was shown by a socalled re-forming card. In order to achieve re-crystallisation to a coarse and aligned grain structure, apart from a certain absolute minimum degree of re-forming, the re-forming must occur within a defined ...
Within its competence for energy research, the Bundesministerium fuer Wirtschaft und Arbeit (BMWA) (Federal Ministry of Economics and Technology) sponsors investigations into the safety of nuclear power plants. The objective of these investigations is to provide fundamental knowledge, procedures and methods to contribute to realistic safety assessments of nuclear installations, to the further development of safety technology and to make use of the potential of innovative safety-related approaches. The Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) mbH, by order to the BMWi, continuously issues information on the status of such investigations by publishing semi-annual and annual progress reports within the series of GRS-F-Fortschrittsberichte (GRS-F-Progress Reports). Each progress report represents a compilation of individual reports about the objectives, work performed, results achieved, next steps of the work etc. The individual reports are prepared in a standard form by the ...
Purpose: The purpose of this study was to observe the process of fixation in liver specimens non-invasively by means of magnetic resonance. The fixation process of several formaldehyde-containing solutions was monitored with MRI and MRS at two different temperatures. Materials and Methods: Liver specimens were conserved in aqueous fixative solutions containing formaldehyde concentrations of 0.7, 1.8, 4 and 7.2% and at different temperatures of 5 C and 20 C. MRI was performed with T1-, T2- and PD-weighted TSE sequences, a 2D FLASH-sequence with and without magnetization transfer, and a FISP 3D-sequence on a clinical 1.5 Tesla MR whole-body unit, and MRS with {sup 1}H-spectroscopic methods (STEAM-sequence) on a 3 Tesla MR whole-body unit. Results: The diffusion of formaldehyde into the tissue was best identified on PD- and T1-weighted images as a band under the liver surface with increasing thickness, penetrating especially fast during the first three days. Spectroscopic measurements ...
The fundamental recommendations of the ICRP issued in its publication of 1990 stipulate the general principle of performance of dose measurements at regular intervals in the field of diagnostic radiology, for the purpose of equipment performance checking and optimization of radiological protection. In response to this requirement, the Federal Ministry, in cooperation with experts and the competent supervising authorities, has issued an order to install dose-area-product meters in angiographic examination systems, imaging systems and fluoroscopic screen devices primarily used for examining infants and children up to the age of 12. This is done in response to reported cases of adverse effects of radiation exposure and the high priority given to radiological protection in the examination of infants and children. In 1992, an expert group was convened to discuss and elaborate instructions for including dose-area product measurement in the dosimetry activities in medical diagnostic ...
Austenitic stainless steel (18% Cr, 12% Ni, Mo gradation between 0,06 to 3,6%) had been solution nitrided. By step-by-step removing, the samples could be prepared with various surface contents of nitrogen from 0.04 to 0.42%. In two test series the influence of nitrogen had been determined. The susceptibility against pitting corrosion of these samples had been tested by the chronopotentiostatical method. For the investigated steel composition and the used corrosion system there is no influence of molybdenum on the effectiveness of nitrogen. The effectiveness of nitrogen can be described by the factor 25 in the PRE. By the investigation of the surfaces with the XPS analysis, it could be shown that the passivation and the pit nucleation is influenced by nitrogen. In these ranges NO{sub x}, NH{sub x}, and NH{sub z}-spectra have been detected. Bound Mo was found in steels containing molybdenum. It is assumed that the repassivation mechanisms of N and Mo work independently of each other. ...
The R and D activities of the institute focused on two major projects, ``Molecular and cellular environmental toxicology``, and ``Biophysics of multi-cellular systems``. For assessment of health risks emanating from the uptake of heavy metal compounds, work performed under the first mentioned project studies the formation of allergy-inducing metabolic products from membrane lipids, and the effects of related cellular signaling processes. These studies are accompanied by an approach to quantify and classify the toxicity of environmental organometallic compounds. Another major task is research into the pathogenesis of lung disease induced by dusts, gases, and gas-dust mixtures and the liberation of inflammatory agents by immunological cell reactions (alveolar macrophages). Atomic force microscopy is the tool used to visualize the related dynamic changes in bronchial cells. Studies for detection of the localisation and structure of the Fe-Mo co-factor in nitrogenase by means of the method ...
Aim: Treatment of carcinoma of the uterine cervix by remote afterloading brachytherapy has been accompanied with new isotopes having dose rates different from the classical low-dose rate (LDR) radium source. The dose rate conversion factor from LDR to high-dose rate (HDR) found to be around 0.54 in most studies. As regards medium-dose rate (MDR) brachytherapie, the published data are very few and the experience is still short. In this study the experience of Osaka University Hospital with micro-HDR-Selectron and Selectron-MDR, as a preliminary report of the clinical trial, is presented. Results: The 3-year survival and loco-regional control rates for both modalities were nearly equivalent (62% and 67% for HDR and 68% and 74% for MDR)(totally 45 patients). The cumulative rectal and bladder complication rates were the same in both groups (29% at 3 years), with only 1 patient (MDR-group) developed grade 3 rectal and bladder complication. In this study, point A dose rate correction factor ...
Purpose: With intracranial tumors a flat, contrast-enhancing, probably dural structure adjacent to the tumor can occasionally be observed on gadolinium-DTPA enhanced MR images. Therefore we have attempted to evaluate a tumor infiltration of this enthancement on MRI. Material and Methods: This study included 50 patients. 19 patients had a dural thickening at the tumor base (13 meningiomas and 6 metastases), while 31 patients did not (12 meningiomas and 19 metastases). Studies included plane T{sub 2}-weighted spin echo (SE) images as well as T{sub 1}-weighted axial, coronal, or sagittal plains with and without contrast agent. Histopathological examinations, were done on the tumor base adjacent to the dura mater. Results: 7 of 12 meningiomas showed a meningeal thickening on MRI with histopathologically proven tumor infiltration as did also 5 of 6 metastases. But 3 of 12 meningiomas and 15 of 19 metastases without dural thickening at the tumor base also showed tumor invasion into the dura ...
A cooperative effort of the Center for Solar Energy and Hydrogen Research (ZSW) and Phototronics Solartechnik GmbH (PST) aimed at the transfer of highly efficient solar cells developed on a laboratory scale, to large-area thin-film solar modules suitable for production. This work was based on research and development at the Institute for Physical Electronics (IPE) of Stuttgart University and ZSW on one hand, and on the know-how of PST in regard to large-area module fabrication on the other hand. The various thin-film layers of the cells and modules comprize molybdenum as rear contact, copper-indium(gallium)-diselenide (CIGS) as absorber material, the combination of cadmium sulphide (CdS) and ZnO as window layer. To produce these layers on large areas (30x30 cm{sup 2}), equipment was constructed and procedures were developed. Monolithic series connection of cells, used in other thin-film technologies, was studied and optimized by suitable patterning procedures, such as laser-scribing, ...
This report describes work carried out in the context of TurboTech Interim for the development of a system for monitoring stationary gas turbines for approaching the stability limit of the compressor. The requirements for the system components were defined and the suitability of different types and positions of pressure sensors were examined and evaluated. It was found very early in the work that, due to the complexity of the object being monitored, one would not succeed in finding a simple criterion for monitoring the pump limit. Rather, apart from the selection of suitable sensors and optimum positions, one must analyse the present signals in different ways and create a decision matrix from this. Existing work on this subject is mostly concerned with the phenomena in the context of experiments on experimental compressors or is not suitable for the requirements of stationary industrial gas turbines. The project is being carried out in the context of TurboTech II with the main aims of: ...
The instability of the phonon spectrum in liquid Helium for T < 1 K is a well established experimental fact. We discuss the role of q-deformation as a possible mechanism to supply the energy deficit that forbidden one-phonon decay into two phonons when the constant {gamma} in the phonon anomalous dispersion relation ({omega}{sup ph} = c{sub 0} p(1 - {gamma}p{sup 2})) is positive, through the analysis of three-phonon processes in a q-phonons gas. (author). 19 refs.
An electroweak model with running coupling constants described by an energy dependent entire function is utraviolet complete and avoids unitarity violations for energies above 1 TeV. The action contains no physical scalar fields and no Higgs particle and the physical electroweak model fields are local and satisfy microcausality. The $W$ and $Z$ masses are compatible with a symmetry breaking $SU(2)_L\\times U(1)_Y \\rightarrow U(1)_{\\rm em}$, which retains a massless photon. The vertex couplings possess an energy scale $\\Lambda_W > 1$ TeV predicting scattering amplitudes that can be tested at the LHC.
The Active Magnetospheric Particle Tracer Explorers (AMPTE) program provided important information on the behavior of clouds of plasma artificially injected into the solar wind and the earth's magnetosphere. Now that the releases are over, data from the satellites are being analyzed to investigate the processes by which the ambient solar wind mass, momentum, and energy are transferred to the magnetosphere. Work in progress at APL indicates that the solar wind is much more inhomogeneous than previously believed, that the solar wind constantly buffets the magnetosphere, and that ground observers may remotely sense these interactions as geomagnetic pulsations. 8 refs.
We study the static potential of open bosonic membranes in the 1/d approximation, where d is the space-time dimensionality. For a fixed square boundary of side length R we find, in contrast to the string potential, no critical distance below which tachyons appear. Instead, we find a correction factor to the classical potential, V/sub cl/=kR/sup 2/, which for small distances shifts the perturbative ground state energy by a positive constant. We interpret the shift as the mass gap of this quantum membrane.
In this work, we report the preparation of lead titanate (PT) nanoceramics (with an average grain size of ~200nm in diameter) by using hydrothermal PT nanoparticles as start materials and characterized the dielectric and ferroelectric properties. The dielectric constant of the ceramic was found to be ~180 (at 1kHz) at room temperature and reached a maximum value of 8330 at ~490^oC, suggesting that the Curie temperature of the nanoceramics is consistent with the known value of PT crystals. Ferroelectric domains and hysteresis loops were obtained through piezoelectric force microscopy measurements, which provide direct and clear evidence for the ferroelectricity in the nanoceramic samples.
The method of reactivity determination using noise analysis correlation measurements with /sup 252/Cf was used to determine the reactivity for subcritical 17.77-cm-dia uranium (93.2 wt percent /sup 235/U) metal cylinders with reactivities as low as 25 dollars. Far subcritical tests were performed with right circular cylinders of uranium metal for which the subcritical reactivity was known from other inverse kinetics and prompt neutron decay constant measurements.
Nano-materials in which a large fraction of atoms resides within a few atomic layers near the surface can be designed to have novel properties by manipulating their surface parameters. We show that the effective elastic constants of nano-porous/cellular materials can be made to exceed those of the parent materials provided the pore surface elastic parameters satisfy certain conditions. These stiff nano-porous materials herald a radical breakthrough in sandwich-type construction.
Nano-materials in which a large fraction of atoms resides within a few atomic layers near the surface can be designed to have novel properties by manipulating their surface parameters. We show that the effective elastic constants of nano-porous/cellular materials can be made to exceed those of the parent materials provided the pore surface elastic parameters satisfy certain conditions. These stiff nano-porous materials herald a radical breakthrough in sandwich-type construction.
We briefly report on zero-temperature photoassociation of a Bose-Einstein condensate, focusing on the many-body rate limit for atom-molecule conversion. An upgraded model that explicitly includes spontaneous radiative decay leads to an unanticipated shift in the position of the photoassociation resonance, which affects whether the rate (constant) maximizes or saturates, as well as the limiting value itself. A simple analytical model agrees with numerical experiments, but only for high density. Finally, an explicit comparison with the two-body unitary limit, set by the size of the condensate, finds that the many-body rate limit is generally more strict.
The author briefly discusses definition of terms, gives an introduction to measurement techniques and describes the characteristics of various low-frequency fields and their causes using typical examples: natural electric fields (thunderstroms), natural magnetic fields, technical electric constant fields (urban transportation, households), static magnetic fields (urban transportation, nuclear magnetic resonance imaging), technical electric alternating fields (high-voltage transmission lines, households), and magnetic alternating fields (high-voltage transmission lines). The author discusses both occupational exposure and that of the general public while underpinning his statements by numerous tables, measurement diagrams and charts. (Uhe).
The interactions of flavonoid, quercetin with sodium dodecyl sulfate (anionic surfactant) and cetyltrimethyl ammonium bromide (cationic surfactant) micelles were investigated. The average location site of quercetin in different micelles was determined by the cyclic voltammetry method with the aid of molecular optimization. The interaction parameters of quercetin with micelles of different charges such as binding constant K and normal binding energy DG were calculated. Furthermore, the morphologic change of the SDS and CTAB spherical micelles and rod-like micelles upon their interaction with quercetin was also observed.
The capability of screen-film combinations of detection and representation of information is described by the detective quantum efficiency (DQE). The DQE may be calculated from the sensitivity, the gradient of the characteristic curve, the modulation transfer function and the Wiener spectrum. These parameters have been determined for fourteen screen-film combinations and the DQE's have been calculated. It is shown that the low frequency region the DQE does not depend on spatial frequency. This constant level of DQE is mostly dependent on the absorbance of the screens. Consequences from this fact, as well for the manufacturer as for the user of the screens, are discussed.
The capability of screen-film combinations of detection and representation of information is described by the detective quantum efficiency (DQE). The DQE may be calculated from the sensitivity, the gradient of the characteristic curve, the modulation transfer function and the Wiener spectrum. These parameters have been determined for fourteen screen-film combinations and the DQE's have been calculated. It is shown that the low frequency region the DQE does not depend on spatial frequency. This constant level of DQE is mostly dependent on the absorbance of the screens. Consequences from this fact, as well for the manufacturer as for the user of the screens, are discussed. (orig.).
We consider the radiation of particles (electrons and positrons) undergoing planar channeling in a single crystal of small thickness L. We show that for Lapprox...pi..b/theta/sub L/, where b is the lattice constant and theta/sub L/ is the Lindhard angle, in addition to the principal maxima of spontaneous radiation of channeled particles in the spectrum there are additional interference maxima, and the positions of all maxima of the radiation intensity depend on L. We discuss the dependence of the intensity of radiation at various frequencies on the crystal thickness.
Decomposition yields of tetracycline hydrochloride (TC.HCl) and chlorotetracycline hydrochloride (ClTC.HCl) in methanol solution saturated with Ar or N/sub 2/O were determined. Rate constants of the reaction esub(s)/sup -/ with some antibiotics were obtained. It was demonstrated by /sup 1/H NMR that the radical formed by degradation of 7-C-Cl group is recombined with the H atoms leading to ClTC.HCl being converted into tetracycline hydrochloride (TC.HCl).
In this study the authors examine the convective cooling provided by fluid trapped in the cavity between two consecutive rollers in a roller bearing. In order to calculate the steady-state temperature of the roller, the designer must know nor only the rolling-contact heat input received by the roller but also the convection cooling effect of the surrounding fluid. Until recently, this lateral convection cooling effect was modeled by assuming a certain (constant) heat transfer coefficient h at the roller surface, and then calculating the steady-state temperature distribution around the roller.
Let $\\A$ be an irreducible Coxeter arrangement and $\\bfk$ be a multiplicity of $\\A$. We study the derivation module $D(\\A, \\bfk)$. Any two-dimensional irreducible Coxeter arrangement with even number of lines is decomposed into two orbits under the action of the Coxeter group. In this paper, we will {explicitly} construct a basis for $D(\\A, \\bfk)$ assuming $\\bfk$ is constant on each orbit. Consequently we will determine the exponents of $(\\A, \\bfk)$ under this assumption. For this purpose we develop a theory of universal derivations and introduce a map to deal with our exceptional cases.
A discrete time control algorithm using the damped least squares is introduced for acceleration and energy exchange controls in nonlinear vibrating systems. It is shown that the damping constant of least squares and sampling time step of the controller must be inversely related to insure that vanishing the time step has little effect on the results. The algorithm is illustrated on two linearly coupled Duffing oscillators near the 1:1 internal resonance. In particular, it is shown that varying the dissipation ratio of one of the two oscillators can significantly suppress the nonlinear beat phenomenon.
The objective of the present study is to reveal thermal characteristic of microcapsulated lauric acid slurry in circular pipe. Test were performed with microcapsulated lauric acid slurry in a heating test section with a constant heat flux boundary condition. Local Nusselt number and the effective thermal capacity were measured. As the size of microcapsulated lauric acid were increased, local Nusselt number of microcapsulated lauric acid slurry were increased. The effective thermal capacity of microcapsulated lauric acid slurry was 0.5 times than it of water.
Localized corrosion has a stochastic character by nature. This character leads to an observed random behavior: fluctuations of the free potential, fluctuations of the current when a constant potential is maintained. This random signal, which is similar to an electric noise, can be analyzed either in the time domain by counting the events or in the frequency domain by measuring the power spectral density of the electrochemical noise. The experimental techniques developed for investigating the localized corrosion on the probabilistic point of view, i.e., statistical counting and power spectral density measurements, are discussed. Then the experimental results reported in the literature are reviewed in order to see what kind of parameters are accessible and how they can be related to the localized corrosion processes.