UK PubMed Central (United Kingdom)
Increased clouds and precipitation normally decrease the diurnal temperature range (DTR) and thus have commonly been offered as explanation for the trend of reduced DTR observed for many land areas...Full Text Available
2007-11-13
High temperature properties of ceramics in the SiAlON system
International Nuclear Information System (INIS)
A series of SiAlON materials with a cordierite-based matrix were annealed for different lengths of time to cause crystallization of the glass phase. Their fracture toughness, hardness, and elastic modulus were measured from room temperature up to 1100"0C. The fracture toughness generally decreased with temperature. Short time annealing raised toughness at lower temperatures, while further annealing lowered it back to the value for as-hot pressed materials. At higher test temperatures annealing had no effect on toughness. This annealing behavior is significantly different from that previously reported in the system SaAlON-YAG. Hardness decreased monotonically with temperature for all samples. Both hardness and the elastic modulus were not affected by the annealing treatment. At elevated temperatures appreciable scatter of modulus results allowed only a rough ...
Energy Technology Data Exchange (ETDEWEB)
Examination is made of the main features of the physical and chemical preignition processes within homogeneous mixtures of air and gaseous fuels, such as propane, methane and hydrogen in a motored engine, while employing detailed chemical kinetics in a one zone analytical model. The changes in the compression temperature and pressure due to the admission of gaseous fuels, energy release during the preingition reactions and the contributions of heat transfer and residual gases to the preignition reaction activity were followed over a number of consecutive cycles until the occurrence of autoignition. Some of the observed differences in engine behaviour when operating on methane, propane and hydrogen were discussed with particular reference to the observed trends in dual fuel engine operation. Calculated results showed good agreement with some corresponding experimental trends. 14 ...
1994-10-01
The dependence of radiation hardening and embrittlement on irradiation temperature
International Nuclear Information System (INIS)
Assessments of the hardening and embrittlement of pressure vessel steels and welds as a function of neutron dose use trend curves derived from surveillance programs and accelerated irradiation data. A temperature dependent factor is incorporated for assessing vessel locations operating at different temperatures. As hardening and embrittlement arise from the sum of matrix damage and copper impurity precipitation, the influence of irradiation temperature on each process needs to be established. For irradiations performed below #approx# 300 C recent data shows that the dose-dependent growth of copper precipitates ceases at a mean diameter of about 2 nm that also corresponds to peak hardening and embrittlement by copper. For doses beyond this peak copper dose the property-dependence on irradiation temperature can be identified with that of matrix damage alone. An analysis of several ...
1994-06-20
Effects of composition and temperature on irradiation hardening of pressure vessel steels
International Nuclear Information System (INIS)
The effects of key metallurgical variables on the low fluence hardening in a set of A533B model steels were evaluated over a wide range of irradiation temperatures. Above about 163 degrees C hardening increased with higher copper and nickel contents, as is typical of the pressure vessel operating regime around 290 degrees C. However, at 121 degrees C the hardening was generally lower and unaffected by copper and nickel variations. This observation of decreased hardening with lower temperature (e.g. an open-quotes invertedclose quotes temperature dependence) is tentatively attributed to a reduced contribution of copper precipitation. Tensile data for a set of commercial steels with a range of (uncontrolled) compositions also showed minimal sensitivity to copper variations at 121 degrees C. Unlike the hardness data no systematic reductions in the yield stress increases were observed ...
1991-08-25
Laser-processed thin-film transistors fabricated from sputtered amorphous-silicon films
Energy Technology Data Exchange (ETDEWEB)
Low-temperature polysilicon thin-film transistors (TFT's) have been fabricated from sputtered silicon films and characterized as a function of as-deposited hydrogen (H) content and laser crystallization fluence. A general trend is observed where TFT performance improves as the H content is lowered. Devices made from {approximately}0% H sputtered films perform similar to those made from low-pressure chemical-vapor deposition processes (LPCVD), but are fabricated at a much lower process temperature (300 C). The best sputtered TFT's had mobilities of {approximately}200 cm{sup 2}/Vs, and on/off current ratios of more than 10{sup 8}.
2000-01-01
Adsorption of hexavalent chromium from aqueous solution by using activated red mud
Energy Technology Data Exchange (ETDEWEB)
Adsorption by activated red mud (ARM) is investigated as a possible alternative to the conventional methods of Cr(VI) removal from aqueous synthetic solutions and industrial effluents. Adsorption characteristics suggest the heterogenous nature of the adsorbent surface sites with respect to the energy of adsorption. Various factors such as pH, contact time, Cr(VI) concentration, amount of adsorbent, and temperature are taken into account, and promising results are obtained. The applicability of the Langmuir as well as Freundlich adsorption isotherms for the present system is tested. The loading factor (i.e., milligrams Cr(VI) adsorbed per gram of ARM) increased with initial Cr(VI) concentration, whereas a negative trend was observed with increasing temperature. The influence of the addition of anions on the adsorption of Cr(VI) depends on the relative affinity of the anions for the surface and the ...
1999-09-01
Energy Technology Data Exchange (ETDEWEB)
Experimental discussions were given on effect of V and W addition on the high temperature strength properties of 12% Cr-15% Mn austenite steels. The test samples were added with W at 0% to 3.5% and V at 0% to 0.5% in addition to C and N, and were given aging treatment or solution treatment. This paper describes the following matters on the results of high-temperature strength measurements and structural observation: A remarkable trend was observed that M23 Cb type carbides precipitate in the aging treatment, wherein aging hardening appears prominently which is attributable to ultra-fine deposits of vanadium nitride (VN) in the V-added material; the V addition is very effective in increasing the high-temperature tensile strength and creep fracture strength as compared with single W addition, wherein the said carbides that accelerate the precipitation as a result ...
1992-11-01
Deposit formation tendency of lubricants at high temperatures
Energy Technology Data Exchange (ETDEWEB)
A thin film microoxidation test utilizing the concept of the Lubricant Stability Map has been used to study the effect of temperature on deposit formation by lubricants on upper piston locations of low heat rejection engines. The stability maps were established for two formulated lubricants in this study. These two lubricants were also evaluated in a series of engine tests with various piston temperatures. The deposition phenomena observed in the engine tests have been adequately simulated and described by the stability maps. It is concluded that lubricants at upper piston locations are under a thin film condition similar to that achieved by the thin film microoxidation test. The deposit formation trend is determined by the volatility, thermal stability, and oxidative stability of the base stock. Additives have little effect on deposit formation at very high temperatures. A combined ...
1995-05-01
International Nuclear Information System (INIS)
In general, over the course of the time, the phenomenon of acceleration in physical development may be observed, i.e. the children and adults of the next generation are taller and heavier than in former generation. Our data presented in this paper show a regular trend of acceleration in the development on Vietnamese, but the trend is still slow and was mostly probably influenced by our difficulties in a long time of war. It is hoped that, the acceleration in the development may be increased in the future following the economical acceleration of our country, however it is known that the ratio between the length of different parts of human body is a specific characteristic for human race, sex and group age. Therefore we may estimate these ratio for the prolongation of the utilization of our measured physical data. The result of studies on water balance of Vietnamese living in comfortable environment air ...
1998-02-01
Stream temperature is an important physical characteristic of headwater streams that plays a critical role in the presence and health of juvenile salmonids. Headwater stream temperature was documented in two geomorphic settings on the Kenai Peninsula, Alaska, focusing on the variation in temperature induced by diffuse groundwater discharge and variable air temperature. Eighteen headwater stream reaches were studied in four watersheds, with 11 drainageway sites and seven discharge-slope sites. In drainageway sites, low-gradient streams flow through broad valleys with groundwater-fed fen wetlands; in discharge-slope sites, high-gradient streams flow through narrow valleys with groundwater-fed slope wetlands. At all 18 sites, hourly stream temperatures were measured for one year. At one drainageway and one discharge-slope site, groundwater temperatures, stream ...
2010-12-01
Energy Technology Data Exchange (ETDEWEB)
Quasi-carbon fibers (QCFs) were prepared from Polyacrylonitrile (PAN) precursor by pyrolysis in the temperature range from 400{degrees}C to 950{degrees}C. The QCF-reinforced composites were fabricated by impregnating the QCFs with the PAN resin. The microstructural changes of both QCFs and their composites were characterized by the X-ray diffraction method. The stacking size and the crystallinity of the QCFs increased with the increasing heat treatment temperature (HTT). The crystallinity of the PAN matrix in a composite was also affected by various QCFs. DSC data indicated that thermal reaction mechanism of the composite could be altered due to the interaction between the fiber and the matrix. DMTA studies showed that good adhesion existed at the interface of the QCF-reinforced composites containing lower HTT fibers. The modulus magnitudes of QCFs and their composites increased with the QCF pyrolysis temperature. Although ...
1994-12-31
Fission neutron damage rates and efficiencies in several metals
International Nuclear Information System (INIS)
Initial rates of resistivity-measured low-temperature damage production by fission-spectrum fast neutrons have been determined for 14 metals in the same very well characterized irradiation facility. Six of these metals were fcc, 5 bcc, and 3 hcp. Most were of quite high purity. Observed damage rates, after correction for all known extraneous resistivity-producing effects, were compared with rates predicted by the damage calculation code RECOIL, using parameters chosen from the literature. These parameters, effective displacement threshold energy, E/sub d/, and Frenkel-pair resistivity, rho/sub F/, were in many cases only best estimates, the further refinement of which may be aided by the present results. Damage efficiencies (measured/predicted rates) follow the same trends by crystal classes as seen in other fast-neutron studies.
2003-04-01
British Library Electronic Table of Contents (United Kingdom)
Effect of oil palm empty fruit bunch (OPEFB) fiber and poly(methyl acrylate) grafted OPEFB on several mechanical properties of poly(vinyl chloride)/epoxidized natural rubber (PVC/ENR) blends were studied. The composites were prepared by mixing the fiber and the PVC/ENR blends using HAKEE Rheomixer at the rotor speed of 50 rpm, mixing temperature 150degreeC, and mixing period of 20 min. The fiber loadings were varied from 0 to 30% and the effect of fiber content in the composites on their ultimate tensile strength (UTS), Youngs modulus, elongation at break, flexural modulus, hardness, and impact strength were determined. An increasing trend was observed in the Youngs modulus, flexural modulus, and hardness with the addition of grafted and ungrafted fiber to the PVC/ENR blends. However the i...
2008-01-01
International Nuclear Information System (INIS)
The absorption spectra of an unoriented single crystal of the title compound (1) have been measured at room and at low temperatures. Assuming a similar sequence of crystal field (CF) levels as for the previously analyzed Nd[N(SiMe_3)_2]_3 (2) a truncated CF splitting pattern is derived from the spectra obtained. The parameters of an empirical Hamiltonian are fitted to the energies of 71 levels to give an r.m.s. deviation of 24.2 cm"-"1. The parameters obtained are compared with those of 2 and Nd[N(SiMe_3)_2]_3(CNC_6H_1_1)_2 (3). The observed trends of CF parameters are consistent with the results of simple model calculations in the framework of the angular overlap model. (orig.)
1998-07-24
Pitting corrosion of Inconel 600 in chloride and sulfate solutions at low temperature
International Nuclear Information System (INIS)
Pitting corrosion of Inconel 600 was examined in chloride and sulfate solutions through usage of potentiodynamic polarization techniques. The effects of chloride and sulfate concentration were investigated in the range of 0.0001 to 0.1 M. Increasing chloride concentrations resulted in active shifts of the pit nucleation potential. Immunity to pitting corrosion was evident at a chloride level below 0.005 M. Increasing sulfate concentrations resulted in improved pitting resistance of Inconel 600 in chloride solutions. Detrimental effects associated with pitting were evident with low-level sulfate being added to dilute chloride media. The density of pits increased with increasing chloride concentrations or temperature between room temperature and 70 C. Systematic trends for the depth of pits were not evident. The observations of pitting corrosion in open immersion were consistent with those in polarization ...
Energy Technology Data Exchange (ETDEWEB)
Praseodymium-doped Bi{sub 4}Ti{sub 3}O{sub 12} (BIT) with various compositions of dopant, Pr (x = 0.5, 0.6, 0.7, 0.8) in Bi{sub 4-x}Pr{sub x}Ti{sub 3}O{sub 12} (BPT) were synthesized using a low temperature wet chemical technique. Powders calcined at 800 deg. C exhibit a single phase polycrystalline perovskite bismuth-layered structure. Randomly oriented plate-like structures were observed under Scanning Electron Microscope (SEM). A small amount of Pr doping (x = 0.5) resulted in dramatically reduced of grain size from 2 {mu}m to less than 50 nm in which Pr plays the role as a grain growth inhibitor. However, by increasing the composition of Pr, bigger grain size of up to 1 {mu}m was observed for x = 0.8 that was caused by diffusion of Pr in the perovskite structure. Dielectric properties showed that dielectric permittivity decreased with the addition of x = 0.50, and increasing with further addition of Pr. Dissipation ...
2009-05-05
International Nuclear Information System (INIS)
Praseodymium-doped Bi_4Ti_3O_1_2 (BIT) with various compositions of dopant, Pr (x = 0.5, 0.6, 0.7, 0.8) in Bi_4_-_xPr_xTi_3O_1_2 (BPT) were synthesized using a low temperature wet chemical technique. Powders calcined at 800 deg. C exhibit a single phase polycrystalline perovskite bismuth-layered structure. Randomly oriented plate-like structures were observed under Scanning Electron Microscope (SEM). A small amount of Pr doping (x = 0.5) resulted in dramatically reduced of grain size from 2 #mu#m to less than 50 nm in which Pr plays the role as a grain growth inhibitor. However, by increasing the composition of Pr, bigger grain size of up to 1 #mu#m was observed for x = 0.8 that was caused by diffusion of Pr in the perovskite structure. Dielectric properties showed that dielectric permittivity decreased with the addition of x = 0.50, and increasing with further addition of Pr. Dissipation factor (tan #delta#) followed the ...
2009-05-05
Recent trends in heavy-fermion physics
Energy Technology Data Exchange (ETDEWEB)
We discuss recent results obtained for the heavy-fermion metals UPd{sub 2}Al{sub 3} and YbRh{sub 2}Si{sub 2}. UPd{sub 2}Al{sub 3} is the first among all superconductors for which tunneling and inelastic neutron-scattering data highlight a non-phononic, i.e., magnetic-exciton mediated, pair state. YbRh{sub 2}Si{sub 2} represents a model system exhibiting pronounced non-Fermi liquid effects above a weak antiferromagnetic phase transition at T{sub N}=70 mK. Upon approaching the quantum critical point (T{sub N}{yields}0), by low doping with Ge, one observes for T<0.3 K disparate behavior in the temperature dependences of both the electrical resistivity and the electronic specific heat as well as a Curie-Weiss law in the uniform magnetic susceptibility, implying uncompensated large 4f moments. These observations indicate a break up of the composite quasiparticles into their local f-spin and itinerant conduction-electron ...
2003-05-01
A radiation hardening model of 9Cr-martensitic steels including Dpa and helium
International Nuclear Information System (INIS)
Full text of publication follows: Low activation ferritic/martensitic steels are receiving a high priority in the European long term materials research. Although extensively investigated, the available experimental data do not cover all required parameter ranges and cannot unambiguously be used to produce hardening/embrittlement trend curves. Therefore, the main objective of this work is to provide a physically-based engineering model offering a rational to experimental observations. From the literature, experimental data were selected to establish a database that mainly consists of 8 to 9Cr-steels irradiated in the range of 50 to 600 deg. C up to 30 dpa and with a He-content up to 5000 appm. The database includes neutron and proton irradiations, He-implanted as well as B- and Ni-doped steels. Because of the difficulty of interpretation inherent to the Charpy impact test, only tensile data were considered. The difficulty stems from the large ...
2007-12-10
i " GeorgeC. Marshall Space Flight Center _i. Marshall SpaceFlight ...
learning curve values as observed from data taken to plot a trend .... Log QF = Log F1 + Log F2 + Log F3 + Log F4 ffi 2.98227 . ...
HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model
Energy Technology Data Exchange (ETDEWEB)
Experiments in a homogeneous charge compression ignition (HCCI) engine have been conducted with four gasoline surrogate fuel blends. The pure components in the surrogate fuels consisted of n-heptane, isooctane, toluene, ethanol and diisobutylene and fuel sensitivities (RON-MON) in the fuel blends ranged from two to nine. The operating conditions for the engine were p{sub in}=0.1 and 0.2 MPa, T{sub in}=80 and 250 C, {phi}=0.25 in air and engine speed 1200 rpm. A semidetailed chemical kinetic model (142 species and 672 reactions) for gasoline surrogate fuels, validated against ignition data from experiments conducted in shock tubes for gasoline surrogate fuel blends at 1.0{<=} p{<=}5.0MPa, 700{<=} T{<=}1200 K and {phi}=1.0, was successfully used to qualitatively predict the HCCI experiments using a single zone modeling approach. The fuel blends that had higher fuel sensitivity were more resistant to autoignition for low intake temperature ...
2009-04-15
Heat capacity of VT1-0 commercial titanium and VT5 and VT5-1 titanium base alloys at low temperature
International Nuclear Information System (INIS)
The temperature dependences of the heat capacity of commercial titanium VT1-0 and alloys on its base, VT5 and VT5-1, have been derived in the temperature range of 4 to 290 K. For comparison, similar measurements have been conducted on pure titanium and specially prepared solid solutions on its base (Ti+3.7 at.% Al and Ti+0.82 at.% Sn). The measurement accuracy has been sufficient for comparing the results with calculation data. The obtained results are interpreted using the known concepts of the role of the mass of interstitial atoms and changes in the interatomic bond forces. It is shown that the phonon components of the molar heat capacities of solid solutions of Al in titanium have lower values in the entire temperature range, as compared to titanium. The corresponding differences are proportional to the Al concentrations. The lower molar heat capacity in the case of dissolution of Al is due to the low mass of the ...
1978-01-01
Abundances of Jupiter's Trace Hydrocarbons From Voyager and Cassini
The flybys of Jupiter by the Voyager spacecraft in 1979, and over two decades later by Cassini in 2000, have provided us with unique datasets from two different epochs, allowing the investigation of seasonal change in the atmosphere. In this paper we model zonal averages of thermal infrared spectra from the two instruments, Voyager 1 IRIS and Cassini CIRS, to retrieve the vertical and meridional profiles of temperature, and the abundances of the two minor hydrocarbons, acetylene (C2H2) and ethane (C2H6). The spatial variation of these gases is controlled by both chemistry and dynamics, and therefore their observed distribution gives us an insight into both processes. We find that the two gases paint quite different pictures of seasonal change. Whilst the 2-D cross-section of C2H6 abundance is slightly increased and more symmetric in 2000 (northern summer solstice) compared to 1979 (northern fall equinox), the major trend of ...
2010-01-01
Pacific decadal oscillation hindcasts relevant to near-term climate prediction
Decadal-scale climate variations over the Pacific Ocean and its surroundings are strongly related to the so-called Pacific decadal oscillation (PDO) which is coherent with wintertime climate over North America and Asian monsoon, and have important impacts on marine ecosystems and fisheries. In a near-term climate prediction covering the period up to 2030, we require knowledge of the future state of internal variations in the climate system such as the PDO as well as the global warming signal. We perform sets of ensemble hindcast and forecast experiments using a coupled atmosphere-ocean climate model to examine the predictability of internal variations on decadal timescales, in addition to the response to external forcing due to changes in concentrations of greenhouse gases and aerosols, volcanic activity, and solar cycle variations. Our results highlight that an initialization of the upper-ocean state using historical observations is effective for successful ...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
The Siberian Altai covers about 70% of the area of all south Siberian glaciers, which provide fresh water to the upper tributaries of the Ob and Yenisey rivers. The observed air temperature has increased by 1.2 deg. C over northern Eurasia during the last 120 years, affecting the degradation of the Siberian Altai glaciers. In this study, we estimated glacier area changes in the Aktru River basin (44.8 km{sup 2}), located in the central Altai mountains. We used the 1952, 1966, 1975 and 2006 remote sensed images with 0.6-3.0 m spatial resolution (aerial photographs, Corona and PRISM satellite images) and differential GPS (DGPS) data. From 1952 to 2006, the total glacier area in the Aktru basin shrank by 7.2% (1.2 km{sup 2}). During the last three decades, the rate of glacier area loss increased by a factor of 1.8, thus resembling trends in other mountain systems of Eurasia (Alps, Tien Shan). The glacier area changes were ...
2007-10-15
International Nuclear Information System (INIS)
The Siberian Altai covers about 70% of the area of all south Siberian glaciers, which provide fresh water to the upper tributaries of the Ob and Yenisey rivers. The observed air temperature has increased by 1.2 deg. C over northern Eurasia during the last 120 years, affecting the degradation of the Siberian Altai glaciers. In this study, we estimated glacier area changes in the Aktru River basin (44.8 km"2), located in the central Altai mountains. We used the 1952, 1966, 1975 and 2006 remote sensed images with 0.6-3.0 m spatial resolution (aerial photographs, Corona and PRISM satellite images) and differential GPS (DGPS) data. From 1952 to 2006, the total glacier area in the Aktru basin shrank by 7.2% (1.2 km"2). During the last three decades, the rate of glacier area loss increased by a factor of 1.8, thus resembling trends in other mountain systems of Eurasia (Alps, Tien Shan). The glacier area changes were caused mainly ...
International Nuclear Information System (INIS)
The effects of catalytic metal additives on the hydrogen desorption properties of the submicrocrystalline magnesium hydride (#beta#-MgH_2) formed after hydrogenation of the Mg + 10 wt.%X (X = V, Y, Zr) mechanically (ball) milled composites were studied. The composites with catalytic metals were processed by controlled mechanical milling (CMM) in the magneto-mill Uni Ball Mill 5 under protective Ar atmosphere. X-ray diffraction of the milled powders revealed the formation of Mg nanograins (50-60 nm range) interdispersed with the nanograined metal additives within the powder particles. Scanning electron microscopy showed particle size reduction after milling. After activation and hydrogenation in a Sieverts-type apparatus under about 2 MPa pressure of hydrogen, the tetragonal #beta#-MgH_2 hydride co-exists with the small amount of retained unreacted Mg phase and the small amount of MgO in all three composites. The #beta#-MgH_2 phase after hydrogenation is submicrocrystalline with the ...
2006-04-13
Fusion zone microstructure and porosity in electron beam welds of an #alpha# + #beta# titanium alloy
International Nuclear Information System (INIS)
The effect of electron beam welding parameters on fusion zone (FZ) microstructure and porosity in a Ti-6.8 Al-3.42 Mo-1.9 Zr-0.21 Si alloy (Russian designation VT 9) has been investigated. It has been observed that the FZ grain width increased continuously with increase in heat input when the base metal was in the #beta# heat-treated condition, while in the #alpha# + #beta# heat-treated base metal welds, the FZ grain width increased only after a threshold energy input. The difference is attributed to both the weld thermal cycle and the pinning effect of equiaxed primary alpha on grain growth in the heat-affected zone (HAZ) of #alpha# + #beta# heat-treated base metal. Postweld heat treatment (PWHT) in the subtransus and supertransus regions did not alter the columnar grain morphology in the FZ, possibly due to the lack of enough driving force for the formation of new grains by the breaking up of the columnar grains and grain boundary movement for grain growth. The ...
1999-03-01
AERONAUTICAL ENGINEERING - NASA Technical Report Server (NTRS)
Topics addressed include future trends in IR sensors, IR observer performance modeling ... steer a sensor platform with a thermal camera or an air-to-air missile system. .... Skyship and Sentinel series airships. It also outlines the current .... A layout schematic of the UPS is given. AIAA. A93-55494 ...
Energy Technology Data Exchange (ETDEWEB)
Low temperature Nonphotochemical Hole Burning (NPHB) Spectroscopy of the dye rhodamine 800 (MF680) was applied for the purpose of discerning differences between cultured normal and carcinoma ovarian surface epithelial (OSE) cells. Both the cell lines were developed and characterized at the Mayo Clinic (Rochester, MN), with the normal cell line having been transfected with a strain of temperature sensitive Simian Virus 40 Large T Antigen (SV40) for the purpose of extending the life of the cell culture without inducing permanent changes in the characteristics of the cell line. The cationic lipophilic fluorophore rhodamine 800 preferentially locates in in situ mitochondria due to the high lipid composition of mitochondria and the generation of a large negative membrane potential (relative to the cellular cytoplasm) for oxidative phosphorylation. Results presented for NPHB of MF680 located in the cells show significant differences between the two ...
2002-06-27
Energy Technology Data Exchange (ETDEWEB)
Low temperature Nonphotochemical Hole Burning (NPHB) Spectroscopy of the dye rhodamine 800 (MF680) was applied for the purpose of discerning differences between cultured normal and carcinoma ovarian surface epithelial (OSE) cells. Both the cell lines were developed and characterized at the Mayo Clinic (Rochester, MN), with the normal cell line having been transfected with a strain of temperature sensitive Simian Virus 40 Large T Antigen (SV40) for the purpose of extending the life of the cell culture without inducing permanent changes in the characteristics of the cell line. The cationic lipophilic fluorophore rhodamine 800 preferentially locates in in situ mitochondria due to the high lipid composition of mitochondria and the generation of a large negative membrane potential (relative to the cellular cytoplasm) for oxidative phosphorylation. Results presented for NPHB of MF680 located in the cells show significant differences between the two ...
2002-08-01
Parental Subfecundity and Risk of Decreased Semen Quality in the Male Offspring: A Follow-up Study
British Library Electronic Table of Contents (United Kingdom)
A few studies have found poor semen quality in sons whose mothers have received fertility treatment, but it is unknown whether the poor semen quality is related to the infertility treatment or to infertility per se, for example, whether it is caused by hereditable factors. Using data from a population-based, Danish follow-up study conducted in 2005-2006, the authors of the present study examined whether sons of subfertile couples who had not received fertility treatment had poorer semen quality than sons of fertile couples. Among the 311 participants, an inverse association between parental waiting time to pregnancy and both semen volume and total sperm count was observed (p trend = 0.04 and p trend = 0.046, respectively). Semen volume in sons of subfertile parents (pregnant after ?1 ye...
2008-01-01
British Library Electronic Table of Contents (United Kingdom)
The Kyoto Protocol attempts through political negotiations to guide participating industrialized countries' greenhouse gas (GHG) emissions from a positive growing trend, to reach a peak point (or turning point), and then be reduced to a negative growth. That means the relationship between decreasing GHG emissions and economic growth may be described by an inverted-U curve (or called a bell-shaped curve), which is consistent with the concept of the Environmental Kuznets Curve (EKC) hypothesis.This research observed that the economic development and GHG emissions in Economies in Transition (EITs) exhibit a hockey-stick curve trend (or called quasi-L-shape curve), that also generates a lot of "hot air" which is significant to the implementation of the Kyoto Protocol. In addition, through the ...
2008-01-01
Are Stars with Planets Polluted?
We compare the metallicities of stars with radial velocity planets to the metallicity of a sample of field dwarfs. We confirm recent work indicating that the stars-with-planet sample as a whole is iron rich. However, the lowest mass stars tend to be iron poor, with several having [Fe/H]0.48) that contributes to but does not explain the mass-metallicity trend in the stars-with-planets sample. We use Monte Carlo models to show that adding an average of 6.5 Earth masses of iron to each star can explain both the mass-metallicity and the age-metallicity relations of the stars-with-planets sample. However, for at least one star, HD 38529, there is good evidence that the bulk metallicity is high. We conclude that the observed metallicities and metallicity trends are the result of the interaction of three effects; accretion of about 6 Earth masses of iron rich material, selection effects, and in some cases, high intrinsic ...
2002-01-01
Heating of magneto-rheological fluid dampers: a theoretical study
This paper focuses on a theoretical model that predicts the temperature increase of Magneto-rheological (MR) fluid dampers experiencing a sinusoidal input motion. A theoretical model is developed to estimate the temperature rise based on the non-linear behavior of the MR fluid damper. This model is solved numerically, and the numerical solution is compared with a known linear solution and experimental result in order to validate the accuracy of the model. Also, a non-dimensional form of the governing equations are developed to examine the key parameters. The non-dimensional terms show the effect of external and internal parameters on the trends of heat dissipation as well as heat generation within the MR fluid damper.
1999-05-01
First observation of excited states in the T_z=1/2 nucleus "8"5Mo
International Nuclear Information System (INIS)
Excited states in the T_z=(1/2) nucleus "8"5Mo have been observed for the first time with the reaction "5"8Ni("3"2S,#alpha#n#gamma#) at 105 MeV. #gamma#-ray transitions in this nucleus have been assigned unambiguously by combining the information from the GASP #gamma#-ray array, the ISIS silicon ball, and the n-Ring neutron detector. Two band structures have been observed in this nucleus; they continue the smooth evolution of the known bands from the lighter N=43 isotones and have been tentatively assigned spins and parity on this basis. After reaching a maximum of collectivity at "8"3Zr, the trend with increasing mass is reversed, showing a smaller collectivity at "8"5Mo. The rotational behavior of the observed bands is discussed on the basis of the projected shell model calculations.
2002-03-01
International Nuclear Information System (INIS)
The optical absorption of the Tm"3"+ ion in the gadolinium oxychloride (GdOCl) matrix in the UV, visible, and NIR range was studied at temperatures between 9 and 300 K. The visible luminescence of GdOCl:Tm"3"+ under Ar"+ ion laser and mercury lamp excitation was recorded at 9, 77, and 300 K, too. The crystal field (CF) splitting of the "3H_4_-_6, "3F_2_-_4, "1G_4, "1D_2, and "1I_6 levels of the Tm"3"+ ion deduced from the spectra was analysed according to the C_4_v point symmetry of the RE"3"+ site. The resulting energy level scheme, consisting of 39 levels (i.e. 55 Stark components) out of the total of 70 (91) for the whole 4f"1"2 configuration, was simulated with the aid of a phenomenological theory taking simultaneously into account both the free-ion and CF effects. The model included 13 adjustable parameters describing the electrostatic (the Racah parameters E_0_-_3) and the configuration interaction (the Trees parameters #alpha#, #beta#, and #gamma#) as well ...
1995-06-26
International Nuclear Information System (INIS)
Current trends in nuclear power generation (and particularly in pressurized water reactors) are toward plant life extension and extended fuel burnup. A higher heat generation rate can induce local boiling regimes at the fuel rod surface in the hottest channels of the core, which can strongly modify the chemical environment of the cladding and influence the oxidation rate of zirconium alloys. Tests performed in out-of-pile loops under severe chemical and thermal-hydraulic conditions (nucleate boiling, higher lithium contents compared to PWRs) reveal two important phenomena: an increase of the oxidation rate of Zircaloy-4 cladding materials in 'high' lithiated environments; an enrichment of the chemical additives in the primary water (boron, lithium) at the surface of the cladding under nucleate boiling conditions. The latter phenomenon, also called 'hideout effect', is mainly controlled by some thermal hydraulic parameters such as bubble diameters and nucleation ...
1999-12-01
Alignments, additivity, and signature inversion in odd-odd "1"7"0Ta: A comprehensive high-spin study
International Nuclear Information System (INIS)
High-spin states (I < or approx. 50(#Planck constant#/2#pi#)) of the odd-odd nucleus "1"7"0Ta have been investigated with the "1"2"4Sn("5"1V,5n) reaction. The resolving power of Gammasphere has allowed for the observation of eleven rotational bands (eight of which are new) and over 430 transitions (#approx#350 of which are new) in this nucleus. Many interband transitions have been observed such that the relative spins and excitation energies of the 11 bands have been established. This is an unusual circumstance in an odd-odd study. Configurations have been assigned to most of these bands based upon features such as alignment properties, band crossings, B(M1)/B(E2) ratios, and the additivity of Routhians. A systematic study of the frequency at which normal signature ordering occurs in the #pi#h_9_/_2#nu#i_1_3_/_2 band has been performed and it is found that its trend is opposite to that observed in ...
2010-06-01
Ion temperature anisotropy in high power helium neutral beam fuelling experiments in JET
Energy Technology Data Exchange (ETDEWEB)
During helium beam fuelling experiments in JET, distinctive anisotropic features have been observed in the velocity distribution function describing both fast and thermal alpha particle populations. During the initial fuelling phase the central helium ion temperature observed perpendicular to the magnetic field is higher than the central electron temperature, while the central helium ion temperature observed parallel to the magnetic field is lower than or equal to the central electron temperature. In order to verify temperature measurements of both perpendicular and parallel lines of sight, other independent methods of deducing the ion temperature are investigated: deuterium ion temperature, deuterium density, comparison with neutron rates and profiles (influence of a possible ...
1994-07-01
Structural material trends in future power plants
Energy Technology Data Exchange (ETDEWEB)
Future power plants will be more fuel efficient, environmentally benign, and economical than current power plants. A high performance power system (HIPPS), based on a coal-fired combined cycle, is currently being developed. The corrosion and temperature-strength properties of currently available metallic materials limit the maximum efficiency of this cycle. Recently, ceramic matrix composites have shown promise in overcoming the design limitations on the future power plants. In particular, the high-temperature, and corrosion and erosion resistant properties of continuous fiber ceramic composites (CFCCs) will allow engineers to design high-temperature heat exchangers, cyclone vortex finder tubes, and other components. Research being performed to evaluate candidate materials for use in future power plants is discussed.
2000-07-01
Expert overseer for mass spectrometer system
Energy Technology Data Exchange (ETDEWEB)
This patent describes an expert overseer for the operation and real-time management of a mass spectrometer and associated laboratory equipment. The overseer is a computer-based expert diagnostic system implemented on a computer separate from the dedicated computer used to control the mass spectrometer and produce the analysis results. An interface links the overseer to components of the mass spectrometer, components of the laboratory support system, and the dedicated control computer. Periodically, the overseer polls these devices and as well as itself. These data are fed into an expert portion of the system for real-time evaluation. A knowledge base used for the evaluation includes both heuristic rules and precise operation parameters. The overseer also compares current readings to a long-term database to detect any developing trends using a combination of statistical and heuristic rules to evaluate the results. The overseer has the capability to alert lab ...
1991-06-18
Expert overseer for mass spectrometer system
International Nuclear Information System (INIS)
This patent describes an expert overseer for the operation and real-time management of a mass spectrometer and associated laboratory equipment. The overseer is a computer-based expert diagnostic system implemented on a computer separate from the dedicated computer used to control the mass spectrometer and produce the analysis results. An interface links the overseer to components of the mass spectrometer, components of the laboratory support system, and the dedicated control computer. Periodically, the overseer polls these devices and as well as itself. These data are fed into an expert portion of the system for real-time evaluation. A knowledge base used for the evaluation includes both heuristic rules and precise operation parameters. The overseer also compares current readings to a long-term database to detect any developing trends using a combination of statistical and heuristic rules to evaluate the results. The overseer has the capability to alert lab ...
1989-04-04
Computational and experimental study of a railplug ignitor
Energy Technology Data Exchange (ETDEWEB)
The plasma plume generated by a new type of high energy Janitor known as the railplug, is examined. The railplug is a miniaturized railgun that has the potential for improving ignition characteristics of combustible mixtures in engines. The objective of the study is to gain an uderstanding of the characteristics of the plasma created by a transparent railplug, and to validate a multidimensional computer simulation of the plasma and shock fronts. The nature of the plume emitted by the railplug was examined for three levels of electrical energy while firing into air at a pressure of 1 atm. The computer model is to be used to predict trends in railplug performance for various railplug designs, energies, and ambient conditions. The velocity of the plasma movement inside a transparent railplug was measured, as well as the velocity of the plume ejected from the cavity. A shock is produced at the initiation point of the arc and propagates down the cavity, eventually ...
1992-01-01
Energy Technology Data Exchange (ETDEWEB)
The temperature rise induced by shock compression of polymethyl methacrylate (PMMA) was determined from measurements of the electrical resistivity of embedded copper foils. The temperature of the copper was determined from the observed foil resistance and known values of the change in copper resistivity with temperature and shock compression. Temperature values obtained over a stress range from 0.9 to 6.0 GPa are in good agreement with thermocouple measurements reported previously.
1980-01-01
Gas-temperature-dependent generation of cryoplasma jet under atmospheric pressure
International Nuclear Information System (INIS)
Plasma with a gas temperature below room temperature is not yet fully understood although it is expected to be an attractive tool for applications to material processing. In the present work, gas-temperature-dependent generation of a cryoplasma jet was studied. So far, we have generated a helium cryoplasma jet (296-5 K) under atmospheric pressure. At gas temperatures below 20 K, the helium excimer, He2, was observed clearly from by optical emission spectroscopy.
2008-09-08
Nuclear data sheets for A = 177
International Nuclear Information System (INIS)
Nuclear structure information for all nuclei with mass number A = 177 is summarized. Data from various decay and reaction experiments are compared. Evaluated data and the adopted spin, parity, and Nilsson--state assignments are given. Deviations from the regional trend of Nilsson ground-state assignments are noted for "1"7"7W and "1"7"7Re. Similar shifts have been observed in this region for nuclei 8 to 10 neutrons removed from the #beta#-stability line. In all cases, low-lying K/sup #pi#/ = 1/2/sup +-/ orbitals move to ground. Data received prior to February 1975 were included. (auth).
Impact of profile resilience on energy confinement
International Nuclear Information System (INIS)
Multi-machine experimental observations indicate resilience in the temperature profiles at low pedestal temperatures,whereas at high pedestal temperatures the profile stiffness seems to disappear.The change of the profile behavior impacts the energy confinement,basically due to a strong non-linear dependence of the energy transport on the pedestal temperature together with different critical conditions for the onset of turbulence in the ions and electrons.This possible explanation for the different observations is based on the assumption that both ion and electron energy transport is governed by turbulence which sets in at a critical temperature gradient as well as on a significant energy equipartition between electrons and ions.
What's happening out there? (Climatic change impacts)
International Nuclear Information System (INIS)
This article briefly comments on some stumbling-blocks to climatic change modelling accuracy - in assessments of the greenhouse effect, 25% (missing link) of atmospheric carbon dioxide absorption is still unaccounted for; 1989 World Bank estimates of the Amazon rain forest deforestation rate have since proven to be inaccurate; there are difficulties in assessing the movement of the earth's crust relative to variations in sea level; and different studies vary in results relative to global temperature measurement and trend assessment. The need for an assessment of the economic impacts of increased atmospheric concentrations of carbon dioxide is also pointed out.
1990-01-01
V51 Knight Shift in Fine V3Si Particles
The Knight shift of vanadium (KV) in fine V3Si particles was studied. The average diameter (\\bar{d}) ranged from 60 to 8000 A. The strong temperature dependence of the KV characteristic of high-Tc A-15 compounds was weakened in the particles. KV at 77 K increased with a decrease in \\bar{d}. The above-mentioned trends were consistent with a broadening of the sharp peak in the electronic density of states around the Fermi energy in particles resulting from a perturbation of the surface.
1987-12-01
Corrosion cracking of rotor steels of steam turbines
International Nuclear Information System (INIS)
Results of investigation of stress corrosion cracking of steam turbine materials in nuclear, fossil and geothermal power plants have been analysed. The role of factors that cause damage to rotor discs, mono block and welding rotors of steam turbines has been shown. These are yield stress and steel composition, stress intensity coefficient and crack growth rate, composition and temperature of the condensed steam and water, electrochemical conditions. The conclusion has been made about the state of stress corrosion cracking of the rotors materials, and main investigation trends which are necessary to solve this problem have been listed.
Ab initio study of the elastic anomalies in Pd-Ag alloys
International Nuclear Information System (INIS)
Ab initio total-energy calculations, based on the exact muffin-tin orbital method, are used to determine the elastic properties of Pd1-xAgx random alloys in the face-centered-cubic crystallographic phase. The compositional disorder is treated within the coherent-potential approximation. The single crystal and polycrystalline elastic constants and the Debye temperature are calculated for the whole range of concentration, 0?x?1. It is shown that the variation in the elastic parameters of Pd-Ag alloys with chemical composition strongly deviates from a simple linear or parabolic trend. The complex electronic origin of these anomalies is demonstrated.
2009-02-15
British Library Electronic Table of Contents (United Kingdom)
To evaluate soil erodibility under different land uses and to study the applicability of nomograph for estimation of soil erodibility a field experiment was conducted under both natural and simulated rainfall conditions under four land uses viz. barren, cultivated, grassland, and forest in the sub-mountainous tract of Punjab (India). Measured soil erodibility (K) values varied from 033 to 067 under natural rainfall conditions and from 023 to 040 under simulated rainfall conditions. Among different land uses, measured K was in the order of barren > cultivated > grassland > forest soils. The values of the K estimated by nomograph were very low as compared to the observed values. The trends were also in contrast to these observed values of K under simulated and natural rainfall conditions. To...
2009-01-01
International Nuclear Information System (INIS)
A study on the distribution of "1"3"7Cs in coastal waters up to a distance of 15 km was undertaken for a decade (1995-2004) and observed that the activity has reduced by 15-20 fold. Statistical and trend analysis was carried out to resolve the contribution of different facilities at a distance of 5 km (north and south) from the discharge point by log normal probability analysis and found that at 5 km south, the median value of "1"3"7Cs due to TAPS and FRP discharges were 3.7 mBq/l and 1.50 mBq/l respectively. The observed levels of "1"3"7Cs are of no consequences from the point of view of dose to members of the public. (author)
2005-11-23
Energy Technology Data Exchange (ETDEWEB)
The optical absorption of the Tm{sup 3+} ion in the gadolinium oxychloride (GdOCl) matrix in the UV, visible, and NIR range was studied at temperatures between 9 and 300 K. The visible luminescence of GdOCl:Tm{sup 3+} under Ar{sup +} ion laser and mercury lamp excitation was recorded at 9, 77, and 300 K, too. The crystal field (CF) splitting of the {sup 3}H{sub 4-6}, {sup 3}F{sub 2-4}, {sup 1}G{sub 4}, {sup 1}D{sub 2}, and {sup 1}I{sub 6} levels of the Tm{sup 3+} ion deduced from the spectra was analysed according to the C{sub 4v} point symmetry of the RE{sup 3+} site. The resulting energy level scheme, consisting of 39 levels (i.e. 55 Stark components) out of the total of 70 (91) for the whole 4f{sup 12} configuration, was simulated with the aid of a phenomenological theory taking simultaneously into account both the free-ion and CF effects. The model included 13 adjustable parameters describing the electrostatic (the Racah parameters E{sub 0-3}) and the ...
1995-06-26
Temperature regulates limb length in homeotherms by directly modulating cartilage growth
UK PubMed Central (United Kingdom)
Allen's Rule documents a century-old biological observation that strong positive correlations exist among latitude, ambient temperature, and limb length in mammals. Although genetic selection for thermoregulatory...Full Text Available
2008-12-09
Superconducting A-15 compounds
International Nuclear Information System (INIS)
The critical superconducting paramters of A-15 compounds are reviewed, and the trends analysed in order to predict maximum values. Experimental data on critical temperature is summarized and compared with theory. The ability to form the stoichiometric, well-ordered materials required for maximum Tsub(c) is discussed in terms of the thermodynamic stability of the A-15 phase. It is concluded that critical temperatures in excess of 25 K, in the A-15 structure, are unlikely. The upper critical field data show that, whereas the vanadium-based compounds are paramagnetically limited, the niobium-based compounds are not. The relation between critical current and microstructure is explored. Best data on critical current densities and ac losses is presented. Finally an account is given of the various methods by which actual conductors, both tapes and multifilamentary wires, are made. (author).
Energy Technology Data Exchange (ETDEWEB)
This experiment is carried out in the series of the investigation on the damage mechanism of carbon steel. In this paper, the damage situation is considered by structure observations. The test were carried out in 600degC-1200degC temperature range, in blowing an argon gas. The reagents are Na{sub 2}O, Na{sub 2}O{sub 2} and NaOH. From structure observations, the holes are observed on the surface of iron-base material in some test conditions. This result is indicated that the selective reaction occurs. The selective reaction is more obvious as the time exposed to the high temperature is longer. It is considered that the selective reaction occurs after the chemical reaction between iron-base material and sodium compound. The areas, in which Mn-concentration is higher, are observed in products on the surface of specimen. (author)
1997-07-01
Magnetic properties of FeSi with cobalt impurities
Energy Technology Data Exchange (ETDEWEB)
Results of experimental researches of impurity level crystals Fe1-xCoxSi are presented in this article. Magnetic properties in a temperature range up to T {<=} 1000 K are analyzed. It was established that with Co impurities increasing origin of magnetic ordering exists at low temperatures. At high temperatures a high temperature maximum of susceptibility of nominally pure iron monosilicide crystal is observed.
2010-01-01
Magnetic fluctuations in paramagnetic Mn{sub 0.81}Ni{sub 0.19}
Energy Technology Data Exchange (ETDEWEB)
Magnetic fluctuations present in the paramagnetic Mn{sub 0.81}Ni{sub 0.19} system have been investigated by measuring inelastic magnetic neutron scattering from a single crystal at temperatures of 450, 585 and 700 K. Antiferromagnetic correlations are observed to be present at all the temperatures studied. The spectral width of the magnetic scattering has been observed to increase with temperature, while the spatial range of the magnetic correlations is seen to decrease as the temperature is raised. The wave-vector-dependent susceptibility is found to follow a Curie-Weiss law near the (1 0 0) position, in agreement with theoretical predictions.
2006-11-15
VUV efficiency and radiant emittance characterization of xenon positive column discharges
Energy Technology Data Exchange (ETDEWEB)
The pure xenon dc positive column discharge has been characterized for various xenon pressures, currents, and discharge tube radii. The absolute output at the 147 nm resonance transition has been measured using two independent techniques to yield the radiant emittance at 147 nm (power per unit surface area). The efficiency of 147 nm production is obtained by combining the measured radiant emittance with the measured electrical power per unit length deposited in the gas. The radiant emittance and the efficiency are the two principle figures of merit for characterizing the discharge as a source of VUV radiation. It is observed that the trends in efficiency and radiant emittance change substantially when the discharge transitions from two-step electron impact excitation/ionization at higher pressures to single-step electron impact ionization at lower pressures. Modeling of the xenon positive column discharge yields radiant emittance and efficiency ...
1996-12-31
International Nuclear Information System (INIS)
Natural convection flow is established in KMRR (Korea Multi-Purpose Research Reactor) reflector tank at the loss of reflector circulator. To simulate the reflector tank natural convection flow with high temperatures at the inner shell and bottom plate due to nuclear heating, experimental and numerical studies in an open cavity with 'L' type heated wall made by the combination of a vertical and horizontal plate were performed. It was confirmed through these studies that the heat transfer rates were highest at the lower region of the vertical plate and the inlet region of horizontal plate and comparatively high at the middle portion of both plates. The heat transfer rate distribution of this trend shows a desirable trend for the effective natural convection cooling of KMRR reflector tank. It was also confirmed that the average Nusselts numbers at the 'L' type heated wall were lower than those obtained from the existing ...
1991-10-26
Energy Technology Data Exchange (ETDEWEB)
Described herein are the latest trends in rolling mill facilities toward the 21st. century and new techniques developed by Hitachi Ltd. These cover hot rolling facilities, such as two-stage twin, high crown control-roll cross mill, roll shaping machine and continuous hot rolling systems; cold rolling facilities, such as pickling line-tandem cold mill and other continuous systems; and fine steel rolling facilities, such as roll mill for very small diameter pipes and others to improve productivity and product quality. The other new techniques include systems to pursue reliability and maintainability, in which electric appliances, instruments and computers are integrated, or equipped with built-in large-capacity inverters and drivers. For hot rolling, the above techniques lead to development of a new system named Hi-HOT, which produces high-quality hot coils at a sufficient speed, while keeping rolled steel at a desired temperature. 1 ref., 3 ...
1996-06-01
Accretion onto Supermassive Black Holes in Quasars: Learning from Optical/UV Observations
Accretion processes in quasars and active galactic nuclei are still poorly understood, especially as far as the connection between observed spectral properties and physical parameters is concerned. Quasars show an additional degree of complexity compared to stars that is related to anisotropic emission/obscuration influencing the observed properties in most spectral ranges. This complicating factor has hampered efforts to define the equivalent of an Hertzsprung-Russel diagram for quasars. Even if it has recently become possible to estimate black hole mass and Eddington ratio for sources using optical and UV broad emission lines, the results are still plagued by large uncertainties. Nevertheless, robust trends are emerging from multivariate analysis of large spectral datasets of quasars. A firm observational basis is being laid out by accurate measurements of broad emission line properties especially ...
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
Since 1984 the Environmental Protection Agency (LfU) of the State of Baden-Wuerttemberg has been investigating the heavy metal burden of earthworms from representative long-term forest observation plots. These investigations are aimed at elucidating and assessing adverse effects of pollutants on the soil biocenosis. Methods: At first only lead and cadmium were measured in the worms; in repetitive measurements over the years further metals or metalloid elements such as aluminum, arsenic, chromium, cobalt, copper, manganese, mercury, nickel, thallium, vanadium, and zinc were added to the agenda. Results and conclusion: The frequency distribution of the metals in the earthworms was characterized statistically. For the first time state-wide background values, normal values and threshold values were established for all the elements measured. A comparable study with a similar range of parameters is known neither nationally nor internationally. Time ...
2006-08-15
Lubrication of an 85-mm ball bearing with RP-1
Energy Technology Data Exchange (ETDEWEB)
A parametric experimental investigation of an 85 millimeter bore angular contact ball bearing running in RP-1 fuel was performed at speeds of 10,000 to 24,000 rpm. Thrust loads were varied from 4450 to 17,800 Newtons (1000 to 4000 lbs.). Radial loads were varied from 1335 to 13,350 Newtons (300 to 3000 lbs.). RP-1 lubrication for the bearing was provided through a stationary jet ring located adjacent to the test bearing outer ring. Increases in both the thrust and radial loads resulted in increased bearing temperature, while increases in shaft speed resulted in much more dramatic increases in bearing temperature. These trends are typical for ball bearings operating under these types of conditions. Results are given for outer ring temperatures of the test bearing at the various test conditions employed. In addition, the heat energy removed from the bearing by the RP-1 was determined by measuring the ...
1993-01-01
Fluid temperature measurement technique by using Raman scattering
Energy Technology Data Exchange (ETDEWEB)
Temperature measurement technique by using Raman scattering was developed for the liquid water at temperature of 20 - 90 degree C and atmospheric pressure. Strong relationship between Raman scattering characteristics and liquid temperature change was observed. Various kinds of measurement techniques, such as Peak Intensity, Peak Wavelength, FWHM (Full Width at Half Maximum), PMCR ( Polymer Monomer Concentration RAte), TSIR (Temperature Sensitive Intensity Ratio), IDIA (Integral Difference Intensity Area) were tested. TSIR has the highest accuracy in mean error or 0.1 deg C and standard deviation of 0.1248 deg C. This report is one of the results in developing process of Raman temperature measurement technique. Next research step is to develop Raman temperature measurement technique at the high temperature and high ...
1999-06-01
Characteristics of infrared-stimulated luminescence from a feldspar at low temperatures
International Nuclear Information System (INIS)
The characteristics of infrared-stimulated luminescence (IRSL) from a sample of potassium feldspar at low temperatures are presented. These studies extend the previous work from this laboratory on the optical bleaching characteristics and emission spectra of feldspars at room temperature and recent measurements of the stimulated spectrum for a sample of potassium feldspar at room temperature. Stimulation spectra have been measured at 290, 160 and 145 K. By fitting Gaussian functions to the spectra, the peak position is shown to shift to higher photon energies at lower temperatures and the full-width half-maximum of the peak to reduce with decreasing temperature. The variation of IRSL intensity with temperature for several stimulating wavelengths has been determined and the form of the IRSL decay curve measured at 290 and 160 K. No substantial differences were ...
1993-07-01
and streambed sediment samples 2-6. Graphs showing: 2. Cesium-137 profile in HOE core 3. PAH trends in Lake Houston cores 4. DDE trends in Lake Houston cores 5. Trends in six trace...
2011-08-27
Energy Technology Data Exchange (ETDEWEB)
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min{sup -1}. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The {beta}-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase ...
2009-01-28
International Nuclear Information System (INIS)
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min-1. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The ?-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are ...
2009-01-28
International Patenting Trends in Advanced Materials: Ceramics
International Patenting Trends in Advanced Materials: Ceramics (June 18, 1999) This report is the ... manufacturing, biotechnology, and advanced materials. Hypertext Format Portable Document Format ...
Inelastic scattering of He atoms from Cu(001) at low temperature with energy analysis
International Nuclear Information System (INIS)
A LiF crystal analyzer has been used to measure phonon creation events when a low energy He beam scatters from a Cu(001) surface at low temperature (16 "0K). As only phonon creation events were observed, the inelastic scattering was subspecular. Atom parallel momentum gain and loss events were observed and both bulk and surface modes contributed to the inelastic scattering. An elastic component of scattering was observed over a wide angular range.
1981-09-01
Structural Phase Transition in AuZn Alloys
Energy Technology Data Exchange (ETDEWEB)
AuxZn1-x alloys undergo a shape memory martensitic transformation whose temperature and nature (continuous or discontinuous) is strongly composition dependent. Neutron diffraction experiments were performed on single crystals of x=50 and 52 to explore the structural changes occurring at the transition temperature. A transverse modulation with wavevector q0=(1/3,1/3,0) develops below the transition temperature, with no observable change in lattice parameter. However, the Bragg peak width shows a broadening suggesting an unresolved rhombohedral distortion similar to what has been observed in NiTi-Fe alloys.
2009-05-03
Implications of the dwarfs spheroidal galaxy mass-metallicity relation
International Nuclear Information System (INIS)
The properties of the mass-metallicity relation among dwarf spheroidal galaxies are discussed in terms of a model which assumes that the internal chemical evolution of the dwarf spheroidals was promoted by supernova activity. The model can be used to explain the observed dwarf spheroidal mass-metallicity relation assuming the present mass of these systems M sub s is proportional to their initial masses M as M sub s varies according to a power-law index of exp 7/4. It is inferred from the power-law dependence of M on the proto-cloud radius that the most massive dwarf spheroids were formed from the densest clouds. The observed slope of the mass-metallicity relation for dwarf spheroidal galaxies is found to be significantly different from theoretical estimates of this slope for elliptical galaxies. It is suggested that the difference may imply that spheroidal dwarfs and elliptical galaxies had different formation histories, confirming Kormendy's ...
Energy Technology Data Exchange (ETDEWEB)
New York City data indicate that seasonal and annual variations in dispersion-normalized air pollutant concentrations appear to accurately reflect changes in source emission patterns. The normalized concentrations make it possible to observe the impact of regulatory changes on ambient air quality without these impacts being obscured by meteorological fluctuations. It is found that numerical modeling techniques and regression analysis can be powerful tools for extracting information from large sets of air quality data. The use of differential, as opposed to absolute, pollutant concentration values will reduce artifact correlations caused by seasonal, weekly, or daily meteorological fluctuations and will permit more accurate estimation of the regression coefficients. This technique was successfully applied to a set of daily pollution measurements whose absolute concentrations were found not to yield a statistically significant fit by multiple regression.
1980-01-01
International Nuclear Information System (INIS)
New York City data indicate that seasonal and annual variations in dispersion-normalized air pollutant concentrations appear to accurately reflect changes in source emission patterns. The normalized concentrations make it possible to observe the impact of regulatory changes on ambient air quality without these impacts being obscured by meteorological fluctuations. It is found that numerical modeling techniques and regression analysis can be powerful tools for extracting information from large sets of air quality data. The use of differential, as opposed to absolute, pollutant concentration values will reduce artifact correlations caused by seasonal, weekly, or daily meteorological fluctuations and will permit more accurate estimation of the regression coefficients. This technique was successfully applied to a set of daily pollution measurements whose absolute concentrations were found not to yield a statistically significant fit by multiple regression.
Nuclear Phenomenology: A Conceptual Proposal for High School Teaching
The discovery of atomic nucleus by E. Rutherford, at the beginning of the twentieth century, was the Nuclear Physics original landmark. From then, a series of experiments in which beams of particles composed of neutrons, protons and others, brought to collide with a nucleus in order to unravel its structure or produce artificial elements through nuclear transmutation, were triggered. With the development of experimental equipment, a number of other nuclear phenomena have been observed, such as beta decay, nuclear fission and fusion, M\\"oesbauer effect, etc. In view of the global political and economic landscape and the contemporary educational trends, this work suggest alternative topics in nuclear physics that can be discussed at the conceptual level in high school teaching, where the main focus lies in the historical and technological importance of such phenomena in society.
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
The crystal structure of Ca{sub 2}RuD{sub 6} has been determined by neutron powder diffraction: space group Fm3m, K{sub 2}PtCl{sub 6} structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340 K and 50 K. The deuterium nuclear quadrupole coupling constant, 54.7 kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A{sub 2}MH{sub 6} salts are interpreted in terms of the ionization energies of the cation and the central metal atom.
2008-07-28
British Library Electronic Table of Contents (United Kingdom)
The crystal structure of Ca2RuD6 has been determined by neutron powder diffraction: space group Fm3m, K2PtCl6 structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340K and 50K. The deuterium nuclear quadrupole coupling constant, 54.7kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A2MH6 salts are interpreted in terms of the ionization energies of the cation and the central metal atom.
2008-01-01
British Library Electronic Table of Contents (United Kingdom)
Global supply chain practices and their effects have received considerable attention over the last two decades. In the recent past, the need for integration across supply chains has been identified as a key for effective and efficient operations of supply chains. This is observed with the increasing trend of collaborative partnerships among supply chain partners. This paper presents an integrated approach for manufacturing and distribution networks within the supply chain system of a global car company. The paper shows that the integration of manufacturing and distribution networks creates the environment for effective planning of many components and execution/follow-up of those plans. These components include materials, resources, operations/activities, suppliers and customers. The main f...
2011-01-01
Heat and fluid flow during the formation of metallic glasses by splat cooling
A model is presented for heat and fluid flow during hammer and anvil splat cooling. Predictions are made for the effects of superheat and hammer speed on splat thickness, cooling rate, and subsequent glass formation. The regime of Newtonian heat flow is extended well beyond the previously accepted limiting value of Nusselt number. Measurements of the structure, stability, and thickness of Fe{sub 80}B{sub 20} and Pd{sub 80}Si{sub 20} hammer and anvil splats qualitatively confirm the model prediction. Variations of superheat in shock tube splats produced similar trends to those observed in the hammer and anvil device. In an attempt to vary the equivalent of hammer speed in a shock tube device, an orifice producing a supersonic shock wave was utilized. Significant splat flake thickness reductions resulted as compared to subsonic orifices.
Fundamental concepts of digital image processing
The field of a digital-image processing has experienced dramatic growth and increasingly widespread applicability in recent years. Fortunately, advances in computer technology have kept pace with the rapid growth in volume of image data in these and other applications. Digital image processing has become economical in many fields of research and in industrial and military applications. While each application has requirements unique from the others, all are concerned with faster, cheaper, more accurate, and more extensive computation. The trend is toward real-time and interactive operations, where the user of the system obtains preliminary results within a short enough time that the next decision can be made by the human processor without loss of concentration on the task at hand. An example of this is the obtaining of two-dimensional (2-D) computer-aided tomography (CAT) images. A medical decision might be made while the patient is still under ...
1983-03-01
Properties of A-15 Superconductors with Defects
It is suggested that the large reduction of the superconducting transition temperature Tc due to defects observed experimentally in some A-15 compounds is caused by smearing of a high peak in the density of states at the Fermi level. The influence of defects on other physical properties (the magnetic susceptibility ?, the elastic modulus Cs, the structural transformation temperature Tm and the electrical resistivity ?) is also discussed from the same point of view. We expect the anomalous temperature dependence of ?, Cs and ? will be suppressed by defects.
1978-05-01
Observation of inverse predissociation of spin-polarized atomic hydrogen at low temperatures
Energy Technology Data Exchange (ETDEWEB)
Measurements of the two-body recombination of spin-polarized atomic hydrogen in a magnetic field of 40 kG have been extended to temperatures above 0.5/sup 0/K. The rate constant for the formation of parahydrogen shows an unexpected increase with temperature, which is explained by inverse predissociation into the v = 14,J = 4 level of H/sub 2/. Data indicate the level is bound by 0.7 +- 0.1/sup 0/K.
1986-10-01
International Nuclear Information System (INIS)
The influence of structure on mechanical properties in the course of tensile tests in a wide range of temperatures was studied, using the VT16 structure thermally strengthened (alpha+beta)-titanium alloy by way of example. It is ascertained that transition from ductile to brittle fracture at the temperature of -196 deg C is observed only in coarse-grain alloy having alpha-eldging of beta grains.
Measurement of the electrical resistivity of the lithium isotopes at low temperatures
Energy Technology Data Exchange (ETDEWEB)
The electrical resistivity at low temperatures (T = 10 to 90 K) of the lithium isotopes /sup 6/Li and /sup 7/Li and of an isotopic mixture /sup 7 +6/Li has been studied. The specimens contained a small amount of chemical impurities. An appreciable difference was observed in the temperature dependence of the resistivity produced both by deformation of the phonon spectrum, related to the change in isotopic composition, and by the presence of chemical impurities making the nonequilibrium part of the electron distribution function more isotropic.
1982-03-01
Carbide transformations in a gamma/gamma-prime nickel alloy during prolonged aging
Energy Technology Data Exchange (ETDEWEB)
Carbide reactions occurring in a precipitation-hardening gamma/gamma-prime Ni-Cr alloy during prolonged high-temperature aging are investigated experimentally. It is found that the decomposition of primary MC carbides, which is accompanied by the precipitation of M23C6 particles, may lead to void nucleation and growth. The effect of carbide transformations on the residual properties of the material at temperatures above the equicohesion temperature is observed at the late stages of aging only. 6 references.
1988-08-01
Valence mixing in rare earth compounds
International Nuclear Information System (INIS)
The concepts of ''fast'' and ''slow'' time scale valence measurements are emphasized by a comparison of L/sub III/ absorption and Mossbauer effect measurements on the temperature induced valence change in EuPd/sub 2/Si/sub 2/. Further the authors show how synchrotron radiation based L/sub III/ measurements of the Ce-valence state can be used to demonstrate electronic structure trends under wide changes in chemical environment. The purpose of this paper is to provide an introduction to researchers in the People's Republic of China to the field of mixed valent rate earth compounds. They hope to illustrate some of the basic concepts in this field, how the field is contributing to the overall insight into the chemical physics of solids and finally how synchrotron radiation measurements in particular are playing a key role in this field.
International Nuclear Information System (INIS)
The authors make two points. Firstly, they emphasise that while the correlation suggested by the B.C.S. formula, Tsub(c) = 1.14 thetasub(D) exp[-1/n(Esub(F))V], between Tsub(c) and the density of states at the Fermi energy, N(Esub(F)), appears to coincide with the empirical trends, this agreement is purely fortuitous. Such a correlation is due to the influence of N(Esub(F)) on the phonon frequencies, which in turn determine the strength of the electron-phonon coupling. Secondly, they point out that their analysis, which was developed for transition metals, is directly applicable to the A-15 compounds leading to results in agreement with the work of Fradin et al. (Auth.).
Energy Technology Data Exchange (ETDEWEB)
Contents: recent trend of battery technologies; alkaline manganese battery with no mercury addition; high capacity zinc-air battery series for hearing aids; characteristics of vanadium-niobium-lithium rechargeable battery; high-energy density lithium-ion rechargeable battery; lithium polymer rechargeable battery: polymer gel electrolyte and electrode; high-capacity ni-cd battery sm120; high-capacity nickel-metal hydride battery; sealed-type batteries for electric vehicles; high-temperature-durable calcium-type battery for automobiles; sealed lead acid batteries for upss; solar cell power unit; solid oxide fuel cell (1); battery management system.
1994-08-01
British Library Electronic Table of Contents (United Kingdom)
Abstract Aim- Two alternative hypotheses attempt to explain the upper elevation limit of tree lines world-wide, the carbon-limitation hypothesis (CLH) and the growth-limitation hypothesis (GLH); the altitudinal decrease of temperature is considered the driver constraining either carbon gain or growth. Using a widely distributed tree line species (Nothofagus pumilio) we tested whether tree line altitude is explained by the CLH or the GLH, distinguishing local from global effects. We elaborated expectations based on most probable trends of carbon charging with altitude according to both hypotheses, considering the alternative effects of drought. Location- Two climatically contrasting tree line ecotones in the southern Andes of Chile: Mediterranean (3654- S) and Patagonia (4604- S). Methods- ...
2011-01-01
Climatic changes in Central Italy and their potential effects on corn water consumption
British Library Electronic Table of Contents (United Kingdom)
This study evaluates the trends of meteorological and agrometeorological indices computed at different sites in the Region of Umbria (Central Italy). The indices were selected on the basis of whether they enable the evaluation of the potential effects of climatic changes on agricultural water requirements and management. The meteorological stations were preliminarily selected considering the length and entirety of the data series and a homogeneous spatial coverage of the region under study. The daily rainfall and minimum and maximum temperature data collected at the stations were elaborated to calculate meteorological and agrometeorological indices (for corn, widespread irrigated crop in Central Italy).The results of the analysis show that rainfall has decreased generally everywhere and th...
2008-01-01
Strain softening and hardening effects in Ti-6Al-4V during high temperature deformation
International Nuclear Information System (INIS)
Effect of strain and temperature on high temperature deformation properties of an alpha + beta titanium alloy Ti-6Al-4V has been investigated in the temperature range 800 to 910 deg. C by using the method of cross head speed cycling. On the basis of flow stress strain rate-strain rate sensitivity data and microstructural studies of the undeformed and deformed regions of tensile test pieces, both strain introduced hardening and softening effects were observed during the course of deformation which could be associated with grain coarsening and refining respectively. (author)
Chemical thermodynamics of silica: a critique on its geothermometer
Energy Technology Data Exchange (ETDEWEB)
The chemical thermodynamic concepts used in the calculation of solubility data of silica (quartz) are presented taking into account the PVT characteristics of water. The temperature-dependence trends between the thermodynamically calculated and the experimental quartz solubility data are very similar, but the values are widely different at high temperatures. The experimental solubility, especially along the saturation curve at high temperature and thermodynamic data for silica need to be reevaluated in order to use silica chemistry to understand geological processes. There could exist a wide range of values for silica solubility at a specified temperature, depending upon the amount of water in the reaction vessel. Thus the silica contents in geothermal fluid, in general, cannot be used as a geothermometer to estimate the reservoir temperature. The derivation of ...
2000-06-01
The authors have studied (Al{sub x}Ga{sub 1{minus}x}){sub 0.5}In{sub 0.5}P doped with tellurium using deep level transient spectroscopy and associated electrical measurements. Several defect states are observed in the upper half of the band gap, that are believed to be intrinsic to the alloy system as well as related to the tellurium donors. Defects observed at measurement temperatures above 390 K exhibit a hysteretic behavior. The observed spectra depend on the biasing conditions applied to the Schottky diode during cooling. The hysteretic behavior suggests the existence of different defect configurations, which can be accessed under conditions of high temperatures and electrical stress, but remain stable below 300 K.
2000-02-01
Energy Technology Data Exchange (ETDEWEB)
The authors have studied (Al{sub x}Ga{sub 1{minus}x}){sub 0.5}In{sub 0.5}P doped with tellurium using deep level transient spectroscopy and associated electrical measurements. Several defect states are observed in the upper half of the band gap, that are believed to be intrinsic to the alloy system as well as related to the tellurium donors. Defects observed at measurement temperatures above 390 K exhibit a hysteretic behavior. The observed spectra depend on the biasing conditions applied to the Schottky diode during cooling. The hysteretic behavior suggests the existence of different defect configurations, which can be accessed under conditions of high temperatures and electrical stress, but remain stable below 300 K.
2000-02-01
Impact of heavy metals on macro-invertebrate fauna of the thaddo stream
International Nuclear Information System (INIS)
Impact of some heavy metals like zinc, lead, copper, chromium and cadmium were studied at four spots on the macro-invertebrate fauna of the Thaddo stream, a tributary of Malir River. This was in correlation with an earlier study on the physico-chemical aspects of water which showed a severe pollution in this stream. Present data for the qualitative and quantitative analyses of macro-invertebrates and the ranges of heavy metals (Zn 0.5-3.5, Pb 0.90-1.42, Cu 0.35-0.93, Cr 0.0-0.08 and Cd 0.003-0.01 ppm) in the water samples also indicate high level of pollution in the stream. Macro-invertebrate fauna comprises only of aquatic insects which include larvae of Chironomus spp., adults of the Notonectus sp., and nymphs of Gomphus sp. (dragon fly) belonging to the order Diptera , Hemiptera and Odonata, respectively. Quantitatively Notonectus sp. predominated and followed by Chironomus larvae. The maximum concentrations of all heavy metals were recorded at spot 3. A general ...
British Library Electronic Table of Contents (United Kingdom)
In order to provide pigs a comfortable sleeping area in hot weather, a floor cooling system was designed and applied to production buildings. Experiments were conducted to compare the floor temperatures and to observe the lying behaviour of pigs in the sleeping area of the buildings with and without floor cooling system. The results showed that, without the floor cooling system, the floor temperature was nearly the same as the air temperature in the open pig house. With the floor cooling system, the floor temperature of the sleeping area was controlled at 22-26degreeC, even though the air temperature was as high as 34degreeC, which improved the comfort of the pigs in the sleeping area. The pig lying behaviour was greatly affected by the floor temperature. More than 85% of the pigs were lyi...
2006-01-01
Evaluation of a temperature model of the continuous steel casting process
Energy Technology Data Exchange (ETDEWEB)
This report summarizes some experiences gathered when using the semi-empirical temperature model that forms the heart of the steel casting advisory system `TUNDTEMP` in simulating the casting process. The model estimates the evolution of the liquid steel temperature in a tundish of a continuous casting machine through a temperature prediction at a couple of central time instants during the casting process. The results are compared with corresponding actual observations during the castings - measured steel temperatures and recorded casting difficulties and interruptions. Explanations for the possible discrepancies are suggested. Starting from a heuristically chosen set of model parameter values, some developing steps have been tested to reduce the simulation errors. The study concentrates mainly on temperature predictions for single heat castings. At the end of ...
1993-11-01
Temperature dependence of threshold current of injection lasers for short pulse excitation
Energy Technology Data Exchange (ETDEWEB)
We report measurements of the temperature dependence of the threshold current of GaAs, 1.3-..mu..m InGaAsP, and 1.5-..mu..m InGaAsP double heterostructure lasers using short electrical pulses. T/sub 0/approx.200 K is observed for all the lasers. These high T/sub 0/ values show that the carrier density at threshold does not increase rapidly with increasing temperature in any of the lasers studied and thus the observed low cw T/sub 0/ of InGaAsP lasers is primarily due to a decrease of the carrier lifetime at threshold with increasing temperature.
1984-05-15
In this study, the complete sequence of the mitochondrial DNA (mtDNA) of Atelura formicaria (Hexapoda: Zygentoma) is described. The molecule is 15.205 bp in length and it is the third complete mt genome sequenced from the Zygentoma. The genome organization conforms with the putative ancestral insect gene arrangement. All protein coding genes use standard initiation codons (methionine and isoleucine). The exception is nad4 that starts with GTG, a codon used for this purpose in other insect species. A peculiar strand skew bias is observed, given that the PCGs encoded on the J-strand contain more thymines than adenines and more cytosines than guanines. This trend in nucleotide composition has been observed also in the "firebrat" Thermobia domestica (Zygentoma, Lepismatidae), but differs from that of the majority of hexapod species, including Tricholepidion gertschi (Zygentoma, Lepidotrichidae), where adenines and cytosines ...
2009-03-11
We report on the spectral cross-calibration results of the Konus-Wind, the Suzaku/WAM, and the Swift/BAT instruments using simultaneously observed gamma-ray bursts (GRBs). This is the first attempt to use simultaneously observed GRBs as a spectral calibration source to understand systematic problems among the instruments. Based on these joint spectral fits, we find that 1) although a constant factor (a normalization factor) agrees within 20% among the instruments, the BAT constant factor shows a systematically smaller value by 10-20% compared to that of Konus-Wind, 2) there is a systematic trend that the low-energy photon index becomes steeper by 0.1-0.2 and Epeak becomes systematically higher by 10-20% when including the BAT data in the joint fits, and 3) the high-energy photon index agrees within 0.2 among the instruments. Our results show that cross-calibration based on joint spectral analysis is an important step to ...
2010-01-01
Environmental Research Database
ObjectivesThe overall scientific aim of this project is, through development of an appropriate numerical modelling tool, to identify and investigate the mechanisms that control the current observed rapid thinning and acceleration of Greenland outlet glaciers and to investigate their likely future behaviour in the context of climate warming. This aim is addressed through the four major specific objectives below. These objectives build on each and therefore the order of priority is driven by the order in wh [continued...]DescriptionCurrently, the Greenland ice sheet is undergoing rapid changes in the coastal regions which have been attributed to a general warming trend to the regions climate over the last decade. Several of the narrow and fast flowing outlet glaciers that drain the ice sheet into the sea are observed to have accelerated their flow and thinned. For instance, Jakobshavn Isbrae on the West coast of Greenland has ...
2008-01-31
British Library Electronic Table of Contents (United Kingdom)
The photoelectron resonance capture ionization (PERCI) of cysteine (Cys) and small gas-phase neutral peptides that contain the Cys residue (Cys-Gly, g-Glu-Cys, and glutathione (g-Glu-Cys-Gly)) is reported. At an ionization energy less than 1eV two types of dissociative electron attachment ionization were observed for Cys: hydrogen atom loss, resulting in formation of the ion [Cys-H]-, and dissociation of the CH2-SH bond, resulting in formation of the ion [SH]-. The presence of these ions suggests that both the p*(-CO2H) and *(C-S) orbitals can act as low energy electrophores on Cys. This ionization trend was observed for the dipeptides Cys-Gly and g-Glu-Cys as well as glutathione, with evidence that dissociation of the CH2-SH bond in these peptides can also result in ions of the form [M-SH...
2009-01-01
Heat transfer and hydraulics of liquid metal-gas two-phase magnetohydrodynamic flow
International Nuclear Information System (INIS)
Local properties and heat transfer have been investigated in a NaK-nitrogen two-phase flow in a vertical tube under transverse magnetic field. An objective two-phase flow regime identification was also carried out systematically, using the probability distribution function of two-phase electromagnetic flowmeter signals. The application of a magnetic field was bound to bring about a drastic change in the void fraction profile, i.e., asymmetric profile perpendicular to the field direction. This effect was more remarkably observed in bubbly flows. The magnetic field was also observed to decrease the number of bubbles, by promoting the agglomeration of small bubbles into larger ones and also break-up of large slugs, and, thus, to shift the flow regime boundaries. It has been also shown that the two-phase Nusselt number increases in bubbly flows, while it decreases in slug flows. This trend however reduces in the presence of a ...
1986-08-01
International Nuclear Information System (INIS)
Holmium doped barium based hexaferrites BaFe_1_2_-_2_xHo_2_xO_1_9 with (x = 0.0-1.0) were synthesized by solid state reaction method. Structural and magnetic characterization of these ferrites provide significant information about their reactive physical properties. X-ray analysis reveals that in all samples M-type structure exist with few secondary phases. Scanning electron microscope revealed the grain size of the specimen. The results show that grain size decreases with the substitution degree of Holmium. Thus rare earth element Holmium Ho"3"+ acts as a grain growth inhibitor. The magnetic hysteresis loops show the variation in the values of magnetic parameters like saturation magnetization (M_s), remanent magnetization (M_r) and coercivity (H_c) were observed by changing Ho"3"+ content in BaFe_1_2_-_2_xHo_2_xO_1_9 ferrites. Coercivity showed a maximum value of 2230 Oe for (x = 0.4) and then decreasing trend were ...
2010-04-09
Analysis of dose rate build-up in Tarapur Atomic Power Station unit-4
International Nuclear Information System (INIS)
Tarapur Atomic Power Station Unit-4 was made critical on 6th March 2005. Since radiation field builds up with the power level due to formation of fission products and activation products in different systems. Radiation dose rates were recorded from different areas using Area Radiation Monitors (ARMs) installed at different areas. These monitors are connected to Radiation Data Acquisition System (RADAS). The trend of radiation field build-up was also analyzed by making survey of different plant areas at various power levels and comparison was made with RADAS readings. The results obtained were compared with 220 MWe dose rates. This study discusses about the dose rates observed at accessible area, shut down accessible area and hotspots observed during the early stage of operation of the reactor. The attempt was also made to find the contributing factors of the high dose rates. It was found that the finding of the study was ...
2005-11-23
Energy Technology Data Exchange (ETDEWEB)
This paper introduces marketability and parts application of PBT in the automotive field. Based on the pursuits in automobiles of weight reduction as measures to improve engine performance, drive performance, and fuel consumption, as well as trends of higher class car orientation, market expansion is expected on engineering resins including PBT. Adoption of PBT/polycarbonate (PC)-based alloy resins is on increase for use in external car parts because of the chemical resistance in PBT, low-temperature shock resistance and appearance of PC. Substitution from Nylon resin in connector application is progressing rapidly because of problems in dimensional stability and compound noise. Air bag sensor parts need to be free of maloperation due to contamination and corrosion in metal contacts caused from gases generated from formed parts, hence development of resins of low gas generation grade is wanted. Valves for exhaust control require ...
1992-06-18
Experimental investigation of premixed combustion within highly porous media
International Nuclear Information System (INIS)
This paper reports on an experimental investigation of premixed methane/air combustion stabilized within a reticulated partially stabilized zirconia foam burner that was performed. A flame holder was used to extend the stability range to allow a stable flame to be maintained for a variety of flow rate and equivalence ratio combinations. The stability range, temperature distributions, and emissions were examined over a range of equivalence ratios and flow rates. The flame was found to be axisymmetric for all conditions in which the reactants were sufficiently well mixed and the flow distribution was sufficiently uniform. Burning speeds were measured that were well in excess of the laminar flame speed. The axial temperature distribution (measured around the burner annulus) in the postflame zone was found to be relatively insensitive to flow rate but dependent upon the burner core length. Very low concentrations of NO_x were found for fuel/air ...
1991-03-17
Paul Scherrer Institut Scientific Report 2001. Volume V: General Energy
Energy Technology Data Exchange (ETDEWEB)
Major advances in 'Energy and Materials Cycles' have been achieved in the removal of heavy metals from the solid residues of municipal waste incineration. It has been conclusively shown that the oxidation/reduction conditions established during the thermal treatment of filter ash have a decisive influence on the evaporation of groups of heavy metals. With respect to biomass gasification, studies have been carried out with respect to the best way of extracting pure hydrogen from the low calorific value gas that is typically obtained from a biomass gasifier. The overarching goal of the laboratory 'High Temperature Solar Technology' is the use of solar energy for the production of solar fuels, or for the reduction of CO{sub 2} emissions in large scale industrial processes that are conventionally carried out with the use of fossil fuels. In a short-term project targeted at the solar production of lime, highly encouraging results (98% ...
2002-03-01
A survey of theoretical research on acoustic plasmons is given and prospects for the observation of these elusive modes are examined. Possible acoustic plasmon contributions to the transition temperatures of the superconducting A-15 compounds are considered. Directions for future experiments and theory are suggested.
1981-09-01
Application of high energy ion beam for the control of boron diffusion
Energy Technology Data Exchange (ETDEWEB)
For the purpose of optimizing the process of co-implantation of MeV Si ions to reduce boron transient enhanced diffusion and boron-enhanced diffusion in Si, multiple MeV implantations and annealing at different temperatures have been performed. A slight improvement on the suppression of B diffusion is observed by adding a low temperature annealing step after the MeV implantation. No differences in B diffusion are observed when the Si doses are increased from 1 x 10{sup 15} to 1 x 10{sup 16} cm{sup -2}. This dose independent behavior is speculated to be a quasi-steady state of vacancy cluster evaporation.
2006-01-15
Application of high energy ion beam for the control of boron diffusion
International Nuclear Information System (INIS)
For the purpose of optimizing the process of co-implantation of MeV Si ions to reduce boron transient enhanced diffusion and boron-enhanced diffusion in Si, multiple MeV implantations and annealing at different temperatures have been performed. A slight improvement on the suppression of B diffusion is observed by adding a low temperature annealing step after the MeV implantation. No differences in B diffusion are observed when the Si doses are increased from 1 x 10"1"5 to 1 x 10"1"6 cm"-"2. This dose independent behavior is speculated to be a quasi-steady state of vacancy cluster evaporation.
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
The possibility of improving the cold formability of wrought magnesium alloys is considered in light of their good hot forming characteristics. Magnesium alloy AZ31B sheet is selected as a model system. Parameters affecting formability, such as strain hardening rate, strain rate sensitivity, and the degree of anisotropy are examined systematically by conducting tensile tests over a range of temperatures (room temperature to 250 C) and strain rates (1 x 10{sup -5} to 0.1 s{sup -1}). The plastic anisotropy and deformation texture evolution are examined in samples aligned with the sheet rolling and transverse directions. Polycrystal plasticity simulations using a viscoplastic self-consistent (VPSC) formulation are used to model the observed anisotropy and texture evolution. The adjustable parameters in the model are the relative critical resolved shear stresses of the dislocation mechanisms known to operate within magnesium. ...
2003-07-01
Studying the internal structure of granular magnetic nanocomposites by ferromagnetic resonance
British Library Electronic Table of Contents (United Kingdom)
A method for estimating the form of magnetic nanoparticles in composite film structures based on the observation of ferromagnetic resonance phenomenon is offered. Within the model of the effective medium, an explanation is given for experimentally observed concentration and temperature dependences of resonant fields for composite nanosystem (Co45Fe45Z10) f +(Al2O3)100?f .
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
It is shown that observations of the lithium isotope ratio in high surface temperature Population II stars may be critical to cosmological nucleosynthesis models. In particular, decaying particle scenarios as derived in some supersymmetric models may stand or fall with such observations. 18 references.
1988-06-01
International Nuclear Information System (INIS)
Electron microscopic observations of neutron irradiated Nb_3Sn revealed the presence of highly disordered regions of size approximately 35 A in a much less disordered matrix. This observation is shown to provide a means of explaining quantitatively many superconducting properties of irradiated A-15 compounds. In particular Tsub(c) of the irradiated materials could be easily predicted using the mathematical formulations developed for the proximity effect. (Auth.).
Resistivity, Hall effect, and magnetic susceptibility of UPd_2Si_2
International Nuclear Information System (INIS)
The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd_2Si_2 have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd_2Si_2 is Curie-Wiess-like along the c axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.
Resistivity, Hall effect, and magnetic susceptibility of UPd[sub 2]Si[sub 2
Energy Technology Data Exchange (ETDEWEB)
The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd[sub 2]Si[sub 2] have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd[sub 2]Si[sub 2] is Curie-Wiess-like along the [ital c] axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.
1993-12-15
International Nuclear Information System (INIS)
The ternary rare earth compound NdRh_4B_4 has been studied by means of critical field, low temperature heat capacity, and static magnetic susceptibility measurements. Features in the upper critical field and heat capacity data at 1.31 K and 0.89 K suggest the occurrence of long-range magnetic order in the superconducting state. The temperature dependence of the static magnetic susceptibility follows a Curie-Weiss law with an effective magnetic moment #mu#sub(eff) = 3.58 +- 0.05 #mu#sub(B) and a Curie-Weiss temperature thetasub(p) = -6.2 +- 1.0 K between 20 K and room temperature. However, magnetization vs. applied magnetic field isotherms suggest the development of a ferromagnetic component in the Nd"3"+ magnetization at low temperatures. (author).
1979-01-01
Observation of Fluorescence for some lanthanides in LiCl-KCl molten salt media at high temperature
Energy Technology Data Exchange (ETDEWEB)
To our knowledge, the fluorescence studies of lanthanides in LiCl-KCl eutectic molten salt at a high temperature are not reported yet. The fluorescence of the lanthanide-ions was generally decreased when the temperature was increased. Moreover, the fluorescence of the lanthanides was strong when the sample was solidified to or from the melt. The temperature, where the fluorescence was decreased, was identified to be different depending on the species of the lanthanides and the substrates was considered to possibly be from quenching of the fluorescence due to either the collisions of melted samples induced by high temperature media or the re-absorption of fluorescence by the samples. Several comparison experiments were performed to explain and understand this phenomenon and improve the fluorescence. In this way, an on-line monitoring of chemical species and the concentration for lanthanides elements in ...
2008-08-15
Jump in the air gasification rate of potassium-doped cellulosic chars
Energy Technology Data Exchange (ETDEWEB)
Chars prepared from potassium-exchanged carboxy methyl cellulose at several heat treatment temperatures (HTTs) were gasified in air isothermally at selected gasification temperatures (GTs) in the range 633-893 K to investigate the catalytic effectiveness of potassium species. The chars displayed a noticeable jump in gasification rate at a particular gasification temperature (called jump temperature, T{sub j}). The magnitude of jump was much less than that reported for copper and nickel catalysis, but comparable with that for calcium catalysis. Increase in HTT caused a decrease in the jump temperature of chars in contrast with the increase observed in copper, nickel and calcium catalysis; also the magnitude of jump did not decrease, but remained unaltered, on increasing HTT. The different behavior of potassium catalysis is correlated to a change in the chemical ...
2010-12-15
Hardening effect in Ti-3Al-2.5V during high temperature deformation
International Nuclear Information System (INIS)
High temperature deformation behavior of an alpha + beta titanium alloy Ti-3Al-2.5V has been investigated in the temperature range 830 deg. C to 910 deg. C by using the method of cross head speed cycling. On the basis of flow stress-strain rate and strain rate sensitivity data, it was found that the alloy exhibits a hardening effect in the entire temperature range studied, amount of hardening being significant at the highest test temperature of 910 deg. C which resulted in a degradation of superplastic properties of the alloy. Grain growth in beta-phase due to strain was considered responsible for the hardening effect observed.
Field-induced valence transition of Eu(Pd_1_-_xPt_x)_2Si_2
International Nuclear Information System (INIS)
The magnetic susceptibility and high-field magnetization have been measured for the intermediate valence system Eu(Pd_1_-_xPt_x)_2Si_2 with 0#<=#x#<=#0.15. A first-order valence transition is observed for all the compounds under high field of 100 T at low temperatures. This valence transition is of first order accompanied with a large hysteresis, which is in contrast to a continuous valence change against temperature. Based on the interconfigurational fluctuation (ICF) model, the temperature- and field-induced valence transitions are discussed. It is found that a first-order valence transition can be induced by magnetic field, even if the system shows a continuous valence transition against temperature. Metamagnetic behavior at finite temperatures is also understood qualitatively by the ICF model. copyright 1997 The American Physical Society.
British Library Electronic Table of Contents (United Kingdom)
Abstract Dynamic testing of a phosphoric acid-based high temperature PEM fuel cell shows a peculiar phenomenon. A certain current loss is observed after temperature cycling at constant voltage. This loss is incidentally recovered by applying a cell voltage spike to open circuit voltage. Experimental investigations into temperature, cell voltage, and ageing effects show that this phenomenon might occur due to the orientation of the adsorbed phosphate species on the platinum catalyst surface. Along with some supporting literature and experimental results, a hypothesis is presented in order to explain this occurrence. Phosphoric acid adsorption hysteresis on platinum catalyst due to temperature cycling could cause the temporary cell current loss. Electrode potential-dependent molecule symmetr...
2011-01-01
The superconducting critical temperature of radiation damaged A-15 compounds
International Nuclear Information System (INIS)
A simple model is used to explain the decrease in superconducting critical temperature with damage observed for irradiated A-15 compounds. A truncated t-matrix approximation is used to describe the disorder along the one-dimensional transition metal chains. Three dimensionality is introduced by the inclusion of interaction between transition metal atoms on different chains. Numerical fits to experiment are discussed in the conclusion. (author).
Radiation-annealing hardening of vanadium
International Nuclear Information System (INIS)
A study is made of the mechanical properties of vanadium irradiated with fast neutrons up to dose 8.6.10"-"4 dpa, as a function of the temperature of post-radiation annealing. The radiation-annealing hardening (RAH) effect is observed at 300"oC, in agreement with previous studies. It is established for the first time that RAH is accompanied by fall in ductility. A phenomenological model is described which explains the dependence of RAH on radiation dose and temperature, as well as on the content of chemically active alloying impurities. (author).
Radiation-annealing hardening of vanadium
International Nuclear Information System (INIS)
Mechanical properties of vanadium, irradiated with fast neutrons up to 8.6x10"-"4 dpa depending on postirradiation annealing temperature, are studied. It is shown that radiation-annealing hardening (RAH) is observed at 300 deg C, which agrees with earlier performed studies. It is first stated that RAH is accompanied by plasticity decrease. Phenomenological model permitting to explain RAH dependence on irradiation temperature and dose and also on content of chemically active alloying impurities is suggested.
Petroleum waxes in solvent systems
Energy Technology Data Exchange (ETDEWEB)
Wax appearance temperature (WAT) of three petroleum waxes in different solvent systems under varying thermal conditions has been determined. It is observed that this temperature mainly is a function of the concentration of the wax and the solubility parameter ([delta]) of the solvent taken. This dependence of WAT has been quantified in terms of these variables in the form of mathematical equation and nomographs. (orig.)
1994-01-01
Parahydrogen clusters: Numerical estimates and physical effects
Energy Technology Data Exchange (ETDEWEB)
We study by means of Quantum Monte Carlo simulations based on the Worm Algorithm the low temperature (down to T = 0.05 K) properties of parahydrogen clusters comprising up to 40 molecules. Three different intermolecular interactions are employed: the Silvera-Goldman, the Buck and the Lennard-Jones potential. Despite important discrepancies observed in the numerical estimates of energy and superfluid fraction, the mechanism by which clusters melt at low T is independent of the particular choice of the potential, whose only effect is to alter the temperature scale.
2009-02-01
International Nuclear Information System (INIS)
The susceptibility of solid "3He is deduced from multiple echoes observed in pulsed NMR experiments. It follows a Curie Weiss law at high temperature, increases faster than this law below 5 mK and drops abruptly around 1 mK. (Auth.).
1977-02-01
Magnetic properties of heavy rare-earth tungstates
International Nuclear Information System (INIS)
Measurement of the magnetic susceptibility of powder samples of heavy rare-earth (Tb, Dy, Ho, Er, Tm and Yb) tungstates have been reported in the temperature range 300 to 900 K. Curie-Weiss law behaviour has been observed for all samples. The Curie constant, paramagnetic Curie temperature and magneton number for the magnetic ions have also been evaluated for each material. (author).
1978-12-01
ROSAT observations of the RSCVn binary sigma Geminorum
DEFF Research Database (Denmark)
X-ray observations of the RSCVn system sigma Geminorum have been undertaken with the ROSAT observatory. Several spectra of very good signal-to-noise ratio were obtained. Spectral fitting using metal abundances amounting to 50% of solar values reveal two temperature components at 2 MK and 12 MK. Previous EXOSAT observations showed another component at 40 MK. Particular interest is focused on the temporal variations of the X-ray emission. It is found that variations occur on time scales ranging from years to hours and minutes.
1997-01-01
Energy Technology Data Exchange (ETDEWEB)
We present high-quality X-ray scattering experiments on pure water taken over a temperature range of 2 to 77 C using a synchrotron beam line at the advanced light source (ALS) at Lawrence Berkeley National Laboratory. The ALS X-ray scattering intensities are qualitatively different in trend of maximum intensity over this temperature range compared to older X-ray experiments. While the common procedure is to report both the intensity curve and radial distribution function(s), the proper extraction of the real-space pair correlation functions from the experimental scattering is very difficult due to uncertainty introduced in the experimental corrections, the proper weighting of OO, OH, and HH contributions, and numerical problems of Fourier transforming truncated data in Q-space. Instead, we consider the direct calculation of X-ray scattering spectra using electron densities derived from density functional theory based on ...
2003-03-01
Superplastic behaviour in Ti-3Al-4V
International Nuclear Information System (INIS)
Superplastic deformation behavior in an alpha + beta titanium alloy Ti-3A-4V has been investigated by using the method of cross head speed cycling in the temperature range 750-910 /sup 0/C. On the basis of flow stress-strain rate-strain rate sensitivity data, the alloy was found to be superplastic in the entire temperature range studied. Optimum superplasticity was observed in the strain-rate range 3 x 10/sup -5/ sec./sup -1/ to 6 x 10/sup -5/ and at the highest temperature of 910 deg. C. (author).
Reactive sticking coefficients for silane and disilane on polycrystalline silicon
Energy Technology Data Exchange (ETDEWEB)
Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition-rate measurements using molecular beam scattering and a very low-pressure cold-wall reactor. The RSCs have nonlinear Arrhenius temperature dependencies and decrease with increasing flux at low (710 /sup 0/C) temperatures. Several simple models are proposed to explain these observations. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction and low-pressure chemical vapor deposition-rate measurements.
1988-04-15
Properties of A-15 superconductors with defects
International Nuclear Information System (INIS)
It is suggested that the large reduction of the superconducting transition temperature T sub(c) due to defects observed experimentally in some A-15 compounds is caused by smearing of a high peak in the density of states at the Fermi level. The influence of defects on other physical properties (the magnetic susceptibility chi, the elastic modulus C sub(s), the structural transformation temperature T sub(m) and the electrical resistivity rho) is also discussed from the same point of view. We expect the anomalous temperature dependence of chi C sub(s) and rho will be suppressed by defects. (auth.).
Hall mobility minimum of temperature dependence in polycrystalline silicon
Molten zone recrystallized as well as sheet grown polycrystalline silicon has shown a minimum in the temperature dependence of the Hall mobility. In order to explain this experimental finding a new model is proposed, which is based on negatively charged grain boundaries for the p-type silicon material under study. This results in a potential well at the grain boundaries instead of the more generally observed potential barrier. A key feature in the model is that the space charge density at the grain boundary depends on the Fermi level position and therefore on temperature. In addition, the change in the measured Hall mobility before and after hydrogen passivation of the grain boundaries is discussed.
1998-01-01
Dielectric behavior of Ba{sub 0.95}Sr{sub 0.05}TiO{sub 3} ceramics sintered by microwave
Energy Technology Data Exchange (ETDEWEB)
Here we report detailed dielectric studies carried out on a Barium strontium titanate (BST) (95:5) composition. The material was synthesized by conventional ceramic method and microwave processing, and the later technique resulted in material with high density, improved microstructure and dielectric properties. The dielectric properties were studied as a function of frequency and temperature and well-defined ferroelectric behavior of first order transition was observed. It follows Curie-Weiss law above transition temperature (paraelectric region). Curie temperature is slightly higher for microwave sintered (MS) material.
2002-12-01
High temperature susceptibilities of actinide monopnictides and monochalcogenides
International Nuclear Information System (INIS)
The inverse susceptibilities of the monopnictides and monochalcogenides of the light rare earths plotted vs. temperature flatten off at high temperatures. This behaviour is well explained by van Vleck paramagnetism of the excited states of the multiplet. For almost all actinide pnictides and chalcogenides a similar flattening-off is observed. Since spin orbit coupling is much stronger than in the light rare earth compounds an analogous interpretation is not possible. Susceptibility curves for uranium compounds can be fitted by adding a temperature dependent enhanced Pauli paramagnetism to the Curie-Weiss term (modified Curie-Weiss law). The high temperature susceptibility behaviour of neptunium compounds is very similar to uranium compounds i.e. an appreciable deviation from the Curie-Weiss law is only visible for the chalcogenides. The plutonium chalcogenides show a ...
1998-06-12
Magnetic properties of RPd_2Si ternary compounds with (R = Gd, Tb, Dy, Ho and Er)
International Nuclear Information System (INIS)
Magnetic properties of polycrystalline samples of RPd_2Si compounds (R = Gd, Tb, Dy, Ho and Er) are presented. The Gd and Tb based compounds are antiferromagnetic with Neel temperatures of 13.5 and 21 K respectively. For both compounds a metamagnetic transition is observed in low field. Moreover, in TbPd_2Si a transition between two different antiferromagnetic phases is observed at 8.5 K. The Dy, Ho and Er based compounds are ferromagnetic with Curie temperatures of 9, 3.5 ad 2.8 K respectively. The observed properties result from indirect exchange interactions and crystal field effects acting on rare earth ions which lie in a very low symmetry site. (author).
Magnetic properties of RPd/sub 2/Si ternary compounds with (R = Gd, Tb, Dy, Ho and Er)
Energy Technology Data Exchange (ETDEWEB)
Magnetic properties of polycrystalline samples of RPd/sub 2/Si compounds (R = Gd, Tb, Dy, Ho and Er) are presented. The Gd and Tb based compounds are antiferromagnetic with Neel temperatures of 13.5 and 21 K respectively. For both compounds a metamagnetic transition is observed in low field. Moreover, in TbPd/sub 2/Si a transition between two different antiferromagnetic phases is observed at 8.5 K. The Dy, Ho and Er based compounds are ferromagnetic with Curie temperatures of 9, 3.5 ad 2.8 K respectively. The observed properties result from indirect exchange interactions and crystal field effects acting on rare earth ions which lie in a very low symmetry site.
1984-01-01
Influence of weather on the behaviour of outdoor-wintered beef cattle in Scandinavia
British Library Electronic Table of Contents (United Kingdom)
The aim of the present investigation was to study the effect of weather and available protection on the behaviour of outdoor-wintered beef cattle (Bos taurus). A herd of 78-85 cattle head was studied during four winter months in the Southwest of Sweden. Protection was offered by coniferous forest situated on and around the 12ha pasture, which we divided into protection categories. During 240h we observed 10 cows and 10 heifers as focal animals (each 3h/month) during day time and adjusted observation times to the altitude of the sun. Close to the animals and at an unprotected spot of the pasture we measured temperature, wind speed and solar radiation and combined these variables to a single measure called Wind Chill Temperature (WCT). During observations the animals were in the forest in 12...
2011-01-01
Most of the general population is exposed to carbaryl and other contemporary-use insecticides at low levels. Studies of laboratory animals, in addition to limited human data, show an association between carbaryl exposure and decreased semen quality. In the present study we explored whether environmental exposures to 1-naphthol (1N), a metabolite of carbaryl and naphthalene, and 3,5,6-trichloro-2-pyridinol (TCPY), a metabolite of chlorpyrifos and chlorpyrifos-methyl, are associated with decreased semen quality in humans. Subjects (n=272) were recruited through a Massachusetts infertility clinic. Individual exposures were measured as spot urinary concentrations of 1N and TCPY adjusted using specific gravity. Semen quality was assessed as sperm concentration, percent motile sperm, and percent sperm with normal morphology, along with sperm motion parameters (straight-line velocity, curvilinear velocity, and linearity). Median TCPY and 1N concentrations were 3.22 and 3.19microg/L, ...
2004-12-01
Energy Technology Data Exchange (ETDEWEB)
A synthesis of the sedimentation processes as deduced from the seismic stratigraphy and the deduced facies associations suggests the following. Small fans developed along the northern major fault line of the SCFVS and contains sediment fed directly from Crete through a series of small canyons, most of which trend perpendicular to the coast. However, the main east-west-trending valley transects the mid- and lower fan sectors and contains several intravalley basinal areas, converging toward the main Messara basin. Thus much of the suprafan sediment is reworked and longitudinally transported into the deeper basins. In these deeper intrabasinal and main basinal areas the thickness of the post-Messinian sediments generally exceeds 800 m and in places exceeds 1,500 m. Toward the south the SCFVS receives additional sediment from the Ptolemy Mountains and the Gavdos rise. Cores recovered along the SCFVS contain a remarkable association of sedimentary ...
1988-08-01
Parental subfecundity and risk of decreased semen quality in the male offspring: a follow-up study.
A few studies have found poor semen quality in sons whose mothers have received fertility treatment, but it is unknown whether the poor semen quality is related to the infertility treatment or to infertility per se, for example, whether it is caused by hereditable factors. Using data from a population-based, Danish follow-up study conducted in 2005-2006, the authors of the present study examined whether sons of subfertile couples who had not received fertility treatment had poorer semen quality than sons of fertile couples. Among the 311 participants, an inverse association between parental waiting time to pregnancy and both semen volume and total sperm count was observed (p trend = 0.04 and p trend = 0.046, respectively). Semen volume in sons of subfertile parents (pregnant after > or =1 years) was 19% lower in comparison with that in sons of parents whose waiting time to pregnancy was 0-6 months (p = 0.02). ...
2008-04-11
Parental subfecundity and risk of decreased semen quality in the male offspring: a follow-up study
DEFF Research Database (Denmark)
A few studies have found poor semen quality in sons whose mothers have received fertility treatment, but it is unknown whether the poor semen quality is related to the infertility treatment or to infertility per se, for example, whether it is caused by hereditable factors. Using data from a population-based, Danish follow-up study conducted in 2005-2006, the authors of the present study examined whether sons of subfertile couples who had not received fertility treatment had poorer semen quality than sons of fertile couples. Among the 311 participants, an inverse association between parental waiting time to pregnancy and both semen volume and total sperm count was observed (p trend = 0.04 and p trend = 0.046, respectively). Semen volume in sons of subfertile parents (pregnant after > or =1 years) was 19% lower in comparison with that in sons ofparents whose waiting time to pregnancy was 0-6 months (p = 0.02). ...
2008-01-01
International Nuclear Information System (INIS)
Complete text of publication follows. Paleomagnetic study in southern Tibet and the Higher Himalayan Crystalline (HHC) was twofold: (1) the recognition of vertical and horizontal block rotations and (2) the examination of the high grade metamorphic rocks (gneisses) from the HHC for their suitability for paleomagnetic investigations. Toward the separation of local and regional tectonic effects, the results from southern Tibet reflect a regional trend in agreement with oroclinal bending and rotational under-thrusting. On the other hand, measured 'anomalous inclinations' are interpreted as a consequence of extensional tectonic, and the circular distribution of magnetic remanences is attributed to long wavelength folding within the study area as well as doming in the crust. The examination of the high grade metamorphic rocks was successful: The high quota of isolated stable and well grouping secondary magnetic remanences, demonstrate their suitability for paleomagnetic ...
2009-08-23
Energy Technology Data Exchange (ETDEWEB)
The Kyoto Protocol attempts through political negotiations to guide participating industrialized countries' greenhouse gas (GHG) emissions from a positive growing trend, to reach a peak point (or turning point), and then be reduced to a negative growth. That means the relationship between decreasing GHG emissions and economic growth may be described by an inverted-U curve (or called a bell-shaped curve), which is consistent with the concept of the Environmental Kuznets Curve (EKC) hypothesis. This research observed that the economic development and GHG emissions in Economies in Transition (EITs) exhibit a hockey-stick curve trend (or called quasi-L-shape curve), that also generates a lot of 'hot air' which is significant to the implementation of the Kyoto Protocol. In addition, through the analysis of single-country time series data and GDP data, this research demonstrated that statistical data ...
2008-01-15
Energy Technology Data Exchange (ETDEWEB)
The Kyoto Protocol attempts through political negotiations to guide participating industrialized countries' greenhouse gas (GHG) emissions from a positive growing trend, to reach a peak point (or turning point), and then be reduced to a negative growth. That means the relationship between decreasing GHG emissions and economic growth may be described by an inverted-U curve (or called a bell-shaped curve), which is consistent with the concept of the Environmental Kuznets Curve (EKC) hypothesis. This research observed that the economic development and GHG emissions in Economies in Transition (EITs) exhibit a hockey-stick curve trend (or called quasi-L-shape curve), that also generates a lot of 'hot air' which is significant to the implementation of the Kyoto Protocol. In addition, through the analysis of single-country time series data and GDP data, this research demonstrated that statistical data ...
2008-01-15
A systematic analysis of the spectra of trivalent actinide chlorides in D_3_h site symmetry
International Nuclear Information System (INIS)
The optical spectra of actinide ions in the compound AnCl_3 and doped into single crystal LaCl_3 were interpreted in terms of transitions within 5f"N configurations. Energy-level calculations were carried out using an effective operator Hamiltonian, the parameters of which were determined by fitting experimental data. Atomic and crystal-field matrices were diagonalized simultaneously assuming an approximate D_3_h site symmetry. The spectroscopic data were taken from the literature but in most cases supplemented by unpublished measurements in absorption and in fluorescence. Spectroscopic data for each ion were analyzed independently, then the model parameters were intercompared and in many cases adjusted such that in the final fitting process the principal interactions showed uniform trends in parameter values with increasing atomic number. Consistent with analyses of the spectra of lanthanide ions in both LaCl_3 and LaF_3, abrupt changes in magnitude of certain ...
1986-08-01
Magnetic behavior and crystal field of Pr"3"+ in praseodymium selenate octahydrate
International Nuclear Information System (INIS)
Measurements are made on the principal magnetic susceptibilities and anisotropies of praseodymium selenate octahydrate single crystals in the temperature range 90 to 300 K. Although the effective magnetic moment is close to the free ion value, the anisotropy is quite high at room temperature. A least sequares fit of the Curie-Weiss law to the observed average susceptibility yields -36.5 K as the paramagnetic Curie temperature. An analysis of the results with a crystal field (CF) of D_4 symmetry, explains the observed results quite well. The CF and the spin-orbit interaction matrix is block diagonalized in the complete 33 dimensional basis of the "3H term in order to obtain the Stark energies and their eigenstates. Intermediate coupling effects are also considered. The ground state being a singlet, the g-factors are absent. Some predictions on the electronic heat capacity and the ...
1988-09-01
Compact Single-Stage Fuel Processor for PEM Fuel Cells. Final report
Energy Technology Data Exchange (ETDEWEB)
Based on observations during the steam reforming of ethanol, the authors conclude that carbon was forming in the steam generator due to the thermal decomposition of ethanol. Since ethanol is being thermally decomposed, they were operating the steam generator at too high of a temperature. The thermal degradation of ethanol was confirmed by using a GC with a flame ionization detector. They observed trace amounts of additional hydrocarbons other than methane in the effluent which we assume maybe ethane and ethylene. We identified the operating conditions that allowed us to steam reform ethanol for an acceptable amount of time. These conditions were a steam temperature of 200 C and a wall temperature of 400 C at the center of the reactor. The calculated ratios of CO{sub 2}/CO indicate that we can lower the potential for carbon deposition from the Boudouard further by reducing the ...
2000-01-01
Irradiation hardening of reduced activation martensitic steels
International Nuclear Information System (INIS)
Irradiation response on the tensile properties of 9Cr-2W steels has been investigated following FFTF/MOTA irradiations at temperatures between 646 and 873 K up to doses between 10 and 59 dpa. The largest irradiation hardening accompanied by the largest decrease in the elongation is observed for the specimens irradiated at 646 K at doses between 10 and 15 dpa. The irradiation hardening appears to saturate at a dose of around 10 dpa at the irradiation temperature. No hardening but softening was observed in the specimens irradiated at above 703 K to doses of 40 and 59 dpa. Microstructural observation by transmission electron microscope (TEM) revealed that the dislocation loops with the a left angle 100 right angle type Burgers vector and small precipitates which were identified to be M_6C type carbides existed after the irradiation at below 703 K. As for the void formation, the average ...
Precision Measurements of the Cluster Red Sequence using an Error Corrected Gaussian Mixture Model
Energy Technology Data Exchange (ETDEWEB)
The red sequence is an important feature of galaxy clusters and plays a crucial role in optical cluster detection. Measurement of the slope and scatter of the red sequence are affected both by selection of red sequence galaxies and measurement errors. In this paper, we describe a new error corrected Gaussian Mixture Model for red sequence galaxy identification. Using this technique, we can remove the effects of measurement error and extract unbiased information about the intrinsic properties of the red sequence. We use this method to select red sequence galaxies in each of the 13,823 clusters in the maxBCG catalog, and measure the red sequence ridgeline location and scatter of each. These measurements provide precise constraints on the variation of the average red galaxy populations in the observed frame with redshift. We find that the scatter of the red sequence ridgeline increases mildly with redshift, and that the slope decreases with redshift. We also ...
2009-07-01
Energy Technology Data Exchange (ETDEWEB)
Primary dendrite spacings, secondary dendrite spacings, and microsegregation have been examined in PWA-1480 single crystal specimens which were directionally solidified during parabolic maneuvers on the KC-135 aircraft. Experimentally observed growth rate and thermal gradient dependence of primary dendrite spacings are in good agreement with predictions from dendrite growth models for binary alloys. Secondary dendrite coarsening kinetics show a reasonable fit with the predictions from an analytical model proposed by Kirkwood for a binary alloy. The partition coefficients of tantalum, titanium, and aluminum are observed to be less than unity, while that for tungsten and cobalt are greater than unity. This is qualitatively similar to the nickel base binaries. Microsegregation profiles experimentally observed for PWA-1480 superalloy show a good fit with Bower, Brody, and Flemings model developed for binary alloys. Transitions ...
1990-11-01
UK PubMed Central (United Kingdom)
ObjectivesUse of prescription opioids for chronic pain is increasing, as is abuse of these medications, though the nature of the link between these trends is unclear....Full Text Available
2010-01-01
Selection of trends for recultivation of land in the Dnieper coal basin
Energy Technology Data Exchange (ETDEWEB)
Types of disorders in the earth's surface as a result of open pit mining operations are analyzed. Trends for recultivation of lands are defined. Formulas are presented for calculating the economic expediency of the selected direction of recultivation.
1980-01-01
Energy Technology Data Exchange (ETDEWEB)
Emissions of sulphur and nitrogen oxides are continuing to fall in Europe but rise in Asia, according to calculations based on individual countries' predictions of economic development. The upward trend is slower than in previous predictions. 2 refs., 2 figs., 2 tabs.
2005-06-01
Prospects of robotics research in the field of remote handling systems
International Nuclear Information System (INIS)
The main trends of research carried out in remote handling systems in the fields of ergonomy, robotics and reliability are presented.
Preliminary analysis of patent trends for sodium/sulfur battery technology
Energy Technology Data Exchange (ETDEWEB)
This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.
1985-07-01
Energy Technology Data Exchange (ETDEWEB)
The primary objective of this project is to investigate the effects of global change on the biodiversity of aphid communities in Western Europe. Biodiversity has been examined at 3 levels: total number of species, phenology and reproductive strategy. Data were provided by EXAMINE, the European suction traps network which has been now operating for 35 years. 392 different species have been identified. At each location, total number of species has been regularly increasing, one additional species being caught every 1 or 2 years depending on location. This is due to introduced species but also to warming which favours rare species. No general trend of increasing density has been detected, but phenological earliness of almost all species (annual date of first appearance in suction traps) is strongly correlated with temperature and especially with mean daily temperature (during more or less long periods of time lying principally ...
2007-07-01
Quantum Teleportation with Continuous Variables: a survey
Very recently we have assisted to a new development of quantum information, the so-called continuous variable (CV) quantum information theory. Such a further development has been mainly due to the experimental and theoretical advantages offered by CV systems, i.e., quantum systems described by a set of observables, like position and momentum, which have a continuous spectrum of eigenvalues. According to this novel trend, quantum information protocols like quantum teleportation have been suitably extended to the CV framework. Here, we briefly review some mathematical tools relative to CV systems and we consequently develop the concepts of quantum entanglement and teleportation in the CV framework, by analogy with the qubit-based approach. Some connections between teleportation fidelity and entanglement properties of the underlying quantum channel are inspected. Next, we face the study of CV quantum teleportation networks where more users share a ...
2006-01-01
International Nuclear Information System (INIS)
Inner ring structures are observed in about one quarter of all lenticular or spiral galaxies. Statistics of the relative frequencies of the pure ring (r) and broken ring (rs) varieties in the Second Reference Catalogue (RC2) among the different families (A, AB, B) of lenticular (L) and spiral (S) galaxies at different stages (T) along the revised Hubble sequence are presented; selection effects dependent on classification weight, apparent diameter and axis ratio are discussed. Comparisons of ring diameters D/sub r/ listed in the (First) Reference Catalogue (RC1) with independent measurements of 43 barred systems by Kormendy show good systematic agreement with a standard deviation sigma_1_2(D/sub r/) = 0'.10 and individual relative mean errors sigma(D/sub r/)/ < D/sub r/ > approx. = 5%. Axis ratios are also in good agreement with sigma_1_2(b/a) = 0.06. Comparisons of axis ratios of rings and parent galaxies show systematic trends dependent ...
Improved adhesion for thermoplastic polymers using oxyfluorination
Energy Technology Data Exchange (ETDEWEB)
Industrial applications of thermoplastic polymers are often limited by their poor adhesion properties. In this work the effect of surface oxyfluorination on the adhesion properties was investigated for polyethylene (PE), polyoxymethylene (POM), polybutylene terephthalate (PBT) and polyamide 6 (PA6). The adhesive joint strength was quantified using lap-shear tests. These results were correlated with the changes in the chemical composition of the surface, determined by X-ray photoelectron spectroscopy (XPS), in the surface free energy, measured by the contact angle method, and in the topography, using white-light confocal microscopy. The adhesive strength is strongly improved for all four polymers, but the degree of this increase depends on the polymer type. The surface free energy shows a similar trend for all four polymers. A high surface free energy exceeding 50 mN/m was observed after oxy-fluorination, whereby the polar component was strongly ...
2008-03-15
Ground-state properties of exotic nuclei near Z=40 in the relativistic mean-field theory
International Nuclear Information System (INIS)
Study of the ground-state properties of Kr, Sr and Zr isotopes has been performed in the framework of the relativistic mean-field (RMF) theory using the recently proposed relativistic parameter set NL-SH. It is shown that the RMF theory provides an unified and excellent description of the binding energies, isotope shifts and deformation properties of nuclei over a large range of isospin in the Z=40 region. It is observed that the RMF theory with the force NL-SH is able to describe the anomalous kinks in isotope shifts in Kr and Sr nuclei, the problem which has hitherto remained unresolved. This is in contrast with the density-dependent Skyrme-Hartree-Fock approach which does not reproduce the behaviour of the isotope shifts about shell closure. On the Zr chain we predict that the isotope shifts exhibit a trend similar to that of the Kr and Sr nuclei. The RMF theory also predicts shape coexistence in heavy Sr isotopes. Several dramatic shape ...
Energy Technology Data Exchange (ETDEWEB)
An experimental investigation was conducted to evaluate the effect of three different oxygenated compounds, diglyme, diethyl maleate and dibutyl maleate, on emissions from a Volkswagen 1.9 litre, turbocharged, direct injection diesel engine. Sampling was performed using a mini-dilution tunnel technique to obtain particulate matter and a Fourier transform infrared (FTIR) spectrometer for gaseous emissions. The particulate samples were analysed using thermal analysis and Soxhlet extraction to determine the fraction of volatile and soluble organic material respectively. All three oxygenated compounds were found to be effective at reducing particulate emissions, with the maleate compounds being more effective overall than the diglyme. Analysis of the relative contributions of changes in the soot and soluble organic fraction (SOF) to the reduction of particulate matter indicated that, for diethyl maleate and diglyme, reductions in soot were the dominant effect. No consistent ...
2000-02-01
Effect of antioxidants on aging of nuclear plant cable insulation
International Nuclear Information System (INIS)
The effects of various antioxidants and antioxidant concentrations on the radiation and thermal stability of EPDM and XLPE polymers used for insulation of electric cable in nuclear power plants were measured. The objective was to determine if particular antioxidants could be identified as being especially effective for stabilization against radiation aging and combined thermal and radiation aging. Elongation to rupture was used as the measure of stability. Materials were irradiated to doses up to 2 MGy (200 Mrad) at a dose rate of 200 to 300 Gy/h in the Cobalt-60 Gamma Irradiation Facility at the University of Virginia. All of the antioxidants tested, which were known to provide excellent thermal stability, also provided good stability for radiation aging and combined thermal/radiation aging, although small differences between antioxidants were noted. No antioxidant or antioxidant combination was identified as being especially outstanding. Stabilization against radiation increased with ...
Density changes in plutonium observed from accelerated aging using Pu-238 enrichment
Energy Technology Data Exchange (ETDEWEB)
In support of Stockpile Stewardship activities, accelerated aging tests on a plutonium alloy enriched with 7.3 at.% of {sup 238}Pu is underway using dilatometry at 35, 50, and 65 deg. C and immersion density measurements of materials stored at 50 deg. C. Changes in density are expected from radiation damage in the lattice and helium in-growth. After 25 equivalent years of aging, the dilatometry data shows that the alloys at 35 deg. C have expanded in volume by 0.11-0.12% and have started to exhibit a near linear expansion behavior primarily caused by the helium accumulation. The average He-to-vacancy ratio from tested specimens was determined to be around 2.55. The model for the lattice damage and helium in-growth accurately represents the volume swelling at 35 deg. C. The density converted from the dilatometry corresponds well to the decreasing density trend of reference plutonium alloys as a function of time.
2006-09-01
Density changes in plutonium observed from accelerated aging using Pu-238 enrichment
International Nuclear Information System (INIS)
In support of Stockpile Stewardship activities, accelerated aging tests on a plutonium alloy enriched with 7.3 at.% of "2"3"8Pu is underway using dilatometry at 35, 50, and 65 deg. C and immersion density measurements of materials stored at 50 deg. C. Changes in density are expected from radiation damage in the lattice and helium in-growth. After 25 equivalent years of aging, the dilatometry data shows that the alloys at 35 deg. C have expanded in volume by 0.11-0.12% and have started to exhibit a near linear expansion behavior primarily caused by the helium accumulation. The average He-to-vacancy ratio from tested specimens was determined to be around 2.55. The model for the lattice damage and helium in-growth accurately represents the volume swelling at 35 deg. C. The density converted from the dilatometry corresponds well to the decreasing density trend of reference plutonium alloys as a function of time.
2006-09-01
Density Changes in Plutonium Observed from Accelerated Aging Using Pu-238 Enrichment
Energy Technology Data Exchange (ETDEWEB)
In support of Stockpile Stewardship activities, accelerated aging tests on a plutonium alloy enriched with 7.3 atomic percentage of {sup 238}Pu is underway using dilatometry at 35, 50, and 65 C and immersion density measurements of material stored at 50 C. Changes in density are expected from radiation damage in the lattice and helium in-growth. After twenty-five equivalent years of aging, the dilatometry data shows that the alloys at 35 C have expanded in volume by 0.11% to 0.12% and have started to exhibit a near linear expansion behavior primarily caused by the helium accumulation. The average He-to-vacancy ratio from tested specimens was determined to be around 2.3. The model for the lattice damage and helium in-growth accurately represents the volume swelling at 35 C. The density converted from the dilatometry corresponds well to the decreasing density trend of reference plutonium alloys as a function of time.
2005-10-19
Energy Technology Data Exchange (ETDEWEB)
To attain reproducible and stable contacts to compound semiconductor devices, it is necessary to achieve thermodynamically stable phases after the reaction of metals with the compound semiconductor. In this study, the final phases produced by the reactions between GaAs and thin metal films of Co, Rh, Ir, Ni, Pd, and Pt have been investigated. They are identified as MGa for M = Co, Rh, Ni, Pd, and Pt, monoarsenides of Co and Ni, diarsenides of Rh, Ir, Pd, and Pt, and Ir/sub 3/Ga/sub 5/. These phases, if deposited directly onto GaAs, will produce thermally stable contacts. In addition to the identification of these stable phases, analyses of the products of thin-film M/GaAs reactions by transmission electron microscopy, x-ray diffraction, and Rutherford backscattering spectrometry reveal the distribution, grain size, and crystallographic texture of these end phases. Trends in these observations across the six metal/GaAs reactions studied are ...
1987-09-01
Biological responses to the chemical recovery of acidified fresh waters in the UK
International Nuclear Information System (INIS)
We report biological changes at several UK Acid Waters Monitoring Network lakes and streams that are spatially consistent with the recovery of water chemistry induced by reductions in acid deposition. These include trends toward more acid-sensitive epilithic diatom and macroinvertebrate assemblages, an increasing proportional abundance of macroinvertebrate predators, an increasing occurrence of acid-sensitive aquatic macrophyte species, and the recent appearance of juvenile (<1 year old) brown trout in some of the more acidic flowing waters. Changes are often shown to be directly linked to annual variations in acidity. Although indicative of biological improvement in response to improving water chemistry, 'recovery' in most cases is modest and very gradual. While specific ecological recovery endpoints are uncertain, it is likely that physical and biotic interactions are influencing the rate of recovery of certain groups of organisms at particular sites. - ...
2005-09-01
Atmospheric carbon dioxide measurements in the remote global troposphere, 1981-1984
Energy Technology Data Exchange (ETDEWEB)
The carbon dioxide concentration has been measured in air samples collected approximately once per week at 22 globally distributed sites during 1981-1984. All samples were analyzed on the same non-dispersive infrared analyzer apparatus. The measured concentrations are directly traceable to the WMO primary CO/sub 2/ standards. Samples which do not contain well-mixed, regionally representative air or which have been contaminated during or subsequent to sampling, have been identified. The selected data have been analyzed using an objective curve fitting method which enables improved estimation of uncertainties associated with derived parameters. The latitudinal distribution of annual mean CO/sub 2/ concentration at the network sites shows significant interannual variability possibly related to the 1982-1983 El NinoSouthern Oscillation event. No evidence was found for significant interannnual variations or trend in the phase or amplitude of the seasonal cycle. ...
1988-01-01
Analysis of High-Moderation MOX Core MISTRAL-3 with SRAC and MVP
International Nuclear Information System (INIS)
To obtain reactor physics parameters for high-moderation mixed-oxide (MOX) cores, Nuclear Power Engineering Corporation (NPEC), the French Atomic Commission (CEA), and their industrial partners have conducted a MOX core physics experimental program called MISTRAL with the EOLE critical facility of the Cadarache research center. This program consists of four high-moderation cores and was successfully completed in July 2000. This paper describes the analysis results of MISTRAL-3 that is a homogeneous full MOX cylindrical core (H/HM = 6.2) with an 80-cm height and a 59-cm diameter consisting of 1388 standard pressurized water reactor-type MOX fuel rods of 7.0 wt% plutonium-enrichment in a square pitch of 1.39 cm. NPEC has been analyzing the experimental results by using the SRAC and MVP code systems. SRAC and MVP calculate the nuclear core characteristics correctly for the high-moderation MOX core MISTRAL-3. No apparent trend with the moderation ratio is ...
2001-06-17
Spin correlations in the frustrated square lattice Pb{sub 2}VO(PO{sub 4}){sub 2}
Energy Technology Data Exchange (ETDEWEB)
The new frustrated square-lattice system, Pb{sub 2}VO(PO{sub 4}){sub 2}, has been investigated using polarised neutron scattering. From these studies, made on powdered samples, we have determined the nature of the exchange interactions and the magnetic ordering for this novel quantum magnet. Quantum order from disorder occurs at low temperature, and the ground state observed below the Neel temperature T {sub N}{approx}3.7 K is a collinear antiferromagnet. At room temperature there are no magnetic correlations and it is possible to model the scattering with the V{sup 4+} magnetic form factor. However, at T{approx}20 K, a temperature well into the paramagnetic phase, magnetic correlations are observed, and these spin correlations have been modelled using a high-temperature series expansion. Ferromagnetic nearest-neighbour exchange J {sub ...
2007-03-15
Thermal diffusion by Brownian motion induced fluid stress
The Ludwig-Soret effect, the migration of a species due to a temperature gradient, has been extensively studied without a complete picture of its cause emerging. Here we investigate the dynamics of DNA and spherical particles sub jected to a thermal gradient using a combination of Brownian dynamics and the lattice Boltzmann method. We observe that the DNA molecules will migrate to colder regions of the channel, an observation also made in the experiments of Duhr, et al[1]. In fact, the thermal diffusion coefficient found agrees quantitatively with the experimental value. We also observe that the thermal diffusion coefficient decreases as the radius of the studied spherical particles increases. Furthermore, we observe that the thermal fluctuations-fluid momentum flux coupling induces a gradient in the stress which leads to thermal migration in both systems.
2007-01-01
XPS/AES Study of Electrical and Chemical Properties of Pd/SiC Interface
Silicon carbide (SiC) based electronic devices are of great importance for applications under the condition of high temperature, high power and high radiation. Schottky diodes of Palladium/SiC are good candidates for hydrogen and hydrocarbon gas sensors at elevated temperature. The detection sensibility of the diodes has been found heavily temperature dependent. In this work, the electrical and chemical properties of Pd/SiC Schottky contacts were studied by XPS and AES at different annealing temperatures. Schottky diodes were made by depositing ultra-thin palladium films onto a silicon carbide substrate. No significant change in the Schottky barrier height of the Pd/SiC contact was found in the temperature range of 300-673K. Palladium diffusion into SiC and the formation of palladium silicides were observed at room temperature and became ...
1997-11-01
Effects of microwaves on cell survival at elevated temperatures
Energy Technology Data Exchange (ETDEWEB)
Since microwaves are used in human cancer therapy, information on specific biological effects of microwaves at elevated temperatures is important. To help supply this information, we exposed mammalian cells (CHO) and bacteria (Serratia marcescens) to hyperthermal temperatures (43, 44, and 45/sup o/C for CHO and 48, 49, and 50/sup o/C for the bacteria) with and without microwave irradiation. Temperature control was maintained by a refrigeration-reheat system and high-velocity water recirculation. The 2450-MHz microwave source was operated in a pulsed mode with power density up to 500 mW/cm/sup 2/. As expected, the survival curve slopes for both cell types increased rapidly with temperature, doubling for each degree Celsius. Microwave irradiation produced no significant change in extrapolation number for either cell type. However, survival curves of CHO cells which received microwaves were steeper by a ...
1981-12-01
Technetium-99m dithiocarbamates as potential agents for brain imaging
International Nuclear Information System (INIS)
Thallium-201 diethyldithiocarbamate (DDC) behaves like a chemical microsphere and is trapped by spontaneous decomposition in the brain in proportion to regional perfusion. They have shown that the technetium-99m analog, Tc-99m DDC (1), is unsuitable for cerebral perfusion imaging because it does not decompose rapidly enough to be trapped in the brain. With the goal of turning this greater stability of 1 into an advantage, a series of dithiocarbamates with lipophilic or amine groups designed to enhance cerebral uptake and retention was prepared from the following amines by reaction with carbon disulfide and sodium hydroxide: pyrrolidine (2), piperazine (3), 4-benzylpiperazine (4), and 4-(1-piperidino)piperidine (5). These ligands (5 mg) were labelled with Tc-99m in > 95% efficiency (ITLC-SG, saline) by reduction of pertechnetate at room temperature with formamidine sulfinic acid at alkaline pH. In preliminary studies, 4 and 5 show a trend of ...
International Nuclear Information System (INIS)
A series of 27 reflood experiments has been carried out in a full-length electrically heated rod bundle facility. The primary objective of these tests was to study the effects of a simultaneous upper plenum and downcomer coolant injection and to provide data for the verification of computer codes. The experimental results indicate that an upper plenum injection alone cools the test rods slowly, a simultaneous coolant injection to the downcomer improves cooling significantly, and a downcomer injection alone cools the test rod bundle best if the total value of the coolant flow rate is the same in these three different cases. If the coolant injected to the upper plenum increases the total flow rate, the quench time of the test rods decreases at all elevations. Quenching time and clad temperature histories calculated with the computer codes NORCOOL-I and FLOOD4 are in a reasonable quantitative agreement with experiments in the case of pure downcomer injection. ...
1983-02-01
Railgun. Challenge to ultra-high speed; Railgun. Chokosoku eno chosen
Energy Technology Data Exchange (ETDEWEB)
A railgun has an armature driven between two rail-like conductors. In other words, it is a linear drive device system that drives airframes by using the Lorentz`s force. The system is expected as a next-generation high-speed transport means, or as a means to create such ultimate fields as ultra-high pressures, ultra-high temperatures, and ultra-ferromagnetic fields. This paper is a report on investigations on the relevant technological trends as surveyed by the investigation committee at the Institute of Electrical Engineers of Japan using research reports published inside and outside the country. The reported themes cover explanations from the construction to the pulse power supply that forms the core of the technology, problems in switching, recent status of research and development, and to application fields. Compatibility in the high-level electrical and mechanical performances demanded in the railgun is not as easy as has been anticipated ...
1995-09-12
Energy Technology Data Exchange (ETDEWEB)
Polycarbonate (PC), a non-crystalline resin, and polybutylene terephthalate (PBT), a crystalline resin, can be achieved by means of alloying of improving such various properties as chemical resistance, heat and impact resistance, and formability. This paper describes its manufacturing methods, properties, and market trends. A PC/PBT alloy improves the chemical resistance if the PBT composition ratio is high, but reduces thermal deformation temperature and impact strength. It is regarded adequate, therefore, that the PBT component ratio is set to 20% to 30%. The impact strength is improved by adding elastomer as a third component. The national production amount in 1992 was 4,800 tons a year; price per kilogram is 700 to 800 yen; and the main application is interior and exterior parts for automobiles. While PP and urethane are often used for interior and exterior automotive parts, there is a high possibility of transferring to PC/PBT in the ...
1994-04-05
Estimation of vapour pressure over MOX fuel
International Nuclear Information System (INIS)
Use of high plutonia MOX as fuel is contemplated from the point of view of rapid disposition of plutonium and economic power generation. The fuel pellets are subjected to steep thermal gradients #approx# 1700 K drop across a radius of #approx# 2.5mm. This leads to evaporation-condensation of the fuel constituents to cooler regions. Vaporization depends on fuel compositions such as Pu fraction, Oxygen-to-Metal (O/M) ratio and local temperature. Knowledge of vapour chemistry is essential in understanding the fuel behavior. The vaporization behaviour of MOX was analyzed in this work using thermochemical methods. The vapour phase consisted of nine species; O, O_2, Pu, PuO, PuO_2, U, UO, UO_2 and UO_3. Oxygen formed part of the vapour phase along with other species and oxygen potential was not controlled independently. The vapour pressures were estimated at 2000 K as a function of (O/M) for several Pu-fraction. Results for MOX-28%PuO_2 is shown in the study. The results ...
2010-12-01
International Nuclear Information System (INIS)
The grain boundary misorientation distribution of 203 grain boundaries in bulk processed high Tc superconductor YBa_2Cu_3O_7_-_#delta# with five processing conditions;, was studied. Two complementary analytical approaches, Grain Boundary Misorientation Distribution (GBMD) from the random description, using a hypothesis test and #chi#"2 analysis, and Grain Boundary Character Distribution (GBCD), using the Coincidence Site Lattice (CSL) model, were applied. The GBMD and GBCD both showed grain boundary evolution departing from a random distribution above 935 C processing temperature. The GBCD analyses indicated an approximately linear increase in the population of CSL-related boundaries, among which the tetragonal CSL (c/a #not =# 3) boundaries grew in the same trend while orthorhombic boundaries (c/a = 3) became stagnated. The results from comparing the corresponding GBCD and volume averaged J_c for each batch indicated that the tetragonal CSL ...
1997-04-04
A non-linear approach to the structure-mobility relationship in protein main chains
Energy Technology Data Exchange (ETDEWEB)
A correlation investigation was carried out on the series of atomic coordinates (MPV) and temperature factor (T {sub f}), respectively for human hemoglobin and HIV-1 protease protein main chains. The MPV series revealed resemblances to the corresponding T {sub f} series. Each minor or major peak in a series had a corresponding peak in the related series. This brings a qualitative evidence for the connection of the two parameters. The series were further subjected to spectral and detrended fluctuation analysis which all revealed long-range correlation properties. This combined analysis revealed that the data were controlled both by the correlation of stationary fluctuation and trends or non-stationary contribution to correlation. The correlation of all MPV series was found to be much less sensitive to ligand binding than the corresponding T {sub f} series. Thus the long-range correlation properties of the protein main chain structure and ...
2007-05-15
A non-linear approach to the structure-mobility relationship in protein main chains
International Nuclear Information System (INIS)
A correlation investigation was carried out on the series of atomic coordinates (MPV) and temperature factor (T _f), respectively for human hemoglobin and HIV-1 protease protein main chains. The MPV series revealed resemblances to the corresponding T _f series. Each minor or major peak in a series had a corresponding peak in the related series. This brings a qualitative evidence for the connection of the two parameters. The series were further subjected to spectral and detrended fluctuation analysis which all revealed long-range correlation properties. This combined analysis revealed that the data were controlled both by the correlation of stationary fluctuation and trends or non-stationary contribution to correlation. The correlation of all MPV series was found to be much less sensitive to ligand binding than the corresponding T _f series. Thus the long-range correlation properties of the protein main chain structure and mobility revealed two ...
2007-05-01
British Library Electronic Table of Contents (United Kingdom)
In this work, a three-dimensional multiphase non-isothermal model incorporated with a capillary-extended sub-model in gas channels is used to investigate the coupled phenomena of water and thermal transport in proton exchange membrane fuel cells. Distributions of water and temperature along the flow path in the channel are highlighted and the pros and cons of various operating temperatures are elaborated. In addition, this work also sheds light on the impacts of temperature variations of bipolar plates induced by non-uniform cooling conditions, which have been overlooked by most previous works. An important phenomenon of water distribution, dry-out at inlets and flooding at outlets (DIFO), is observed and this non-uniform distribution is revealed to be greatly influenced by the operating t...
2011-01-01
International Nuclear Information System (INIS)
The electrochemical behaviour and fracture morphology of homogenized and sensitized type SAE 304 stainless steel U bent specimens, in 3% NaCl solution, at pH=2.0 and pH=7.0 both at room temperature and 100"0C was studied. Polarization curves, galvanostatic and potentiostatic experiments were run. It could be observed that high temperature and low pH favour transgranular cracking and longer sensitization times lower fracture time and tend to give rise to intergranular fracture. Light sensitization can produce transgranular cracking even at room temperature, when the homogenized alloy does not present stress-corrosion cracking for the same condition. (Author).
High temperature deformation behaviour of Ti-10V Alloy and associated activation energy
International Nuclear Information System (INIS)
High temperature deformation behaviour of an experimental Beta-titanium alloy Ti-10V has been studied in the temperature range 800 to 945 degree C by using the method of crosshead speed cycling. Although subgrain formation was observed but the alloy did not exhibit superplastic behaviour in the entire temperature range studied. A very large initial grain size and elongation of grains during the deformation are considered the main factors responsible for absence of superplastic behaviour. The activation energy values for regions II and III of the ln sigma vs. ln small epsilon plots are close to the lower of the two activation energy values proposed together to describe self diffusion in beta-phase suggesting that the rate controlling mechanism is that for lattice diffusion rather then grain boundary diffusion. (author)
2004-06-01
Corrosion behaviour of Alloy 800 in high temperature aqueous solutions: Electrochemical studies
International Nuclear Information System (INIS)
The anodic behaviour and passivity breakdown of Alloy 800 in aqueous solutions of sodium chloride, sodium sulphate and sodium bicarbonate were studied by electrochemical techniques in the temperature range from 60 C to 280 C. The pitting resistance and pitting morphology of the alloy in chloride plus sulphate and chloride plus bicarbonate mixtures, at 60 C and 280 C, were also examined. Increasing bicarbonate or sulphate additions to chloride solutions shift the characteristic pitting potential of Alloy 800 to higher values, both at low and high temperatures. Changes in pitting morphology were observed in sulphate containing solutions while the morphology of the attack found in bicarbonate containing solutions was similar to that in pure chloride solutions. Finally, no localized or substantial generalized corrosion was detected in pure sulphate or bicarbonate solutions at any temperature. (orig.).
Characterization and Wear Behavior of Plasma Nitrided Nickel Based Dental Alloy
British Library Electronic Table of Contents (United Kingdom)
In the present work, the plasma nitriding behavior of a nickel based dental alloy was investigated. Plasma nitriding experiments carried out under constant gas mixture (15% H2?85% N2) for different process parameters including time (4, 6, 10, and 20?h) and temperature (400, 450, 500, and 550??C). Depending on nitriding parameters, it was found that triple or double layers formed on the surface of the samples. Increasing of treatment time and temperature has resulted in a double layer. ?N1 layer was in formed all nitrided samples. However, ?N2 layer is formed only at low temperatures and in short times. Layer growth of nickel based alloys increases until a critical time or a critical temperature reached. Above these critical values, it is observed that the layer thickness decreases. It was ...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
VHF wind-profiling radars often measure a decrease of echo power with zenith angle, which can be explained from in situ measurements of horizontal layering or anisotropy of metre-scale temperature structure in the atmosphere. There can also be an azimuthal variation of echo power, which is increased in an azimuth opposite to the vertical shear vector of horizontal wind. This paper checks if the azimuth variation can also be linked to in situ observations of temperature structure, using aircraft flights in the tropopause region near a VHF radar. At heights where VHF radar measures wind shear and aspect sensitivity, there can be an asymmetry in the probability distribution of horizontal gradient of potential temperature, for horizontal scale of e.g. hundreds of metres. The asymmetry is often...
2007-01-01
Assessment of generation temperatures of crude oils
Energy Technology Data Exchange (ETDEWEB)
Biological marker maturity parameters were used to estimate the minimum HC generation temperatures of crude oils from Eastern Hungary. More than 50 oils and oil shows were analysed. Molecular- and homologous-ratios of biological marker compounds (triterpanes, steranes, mono- and triaromatic steroid hydrocarbons) were used as maturation parameters. The oils have at least five maturity stages, i.e. they have been generated under different thermal conditions. The highest reservoir temperature in each group was chosen as the best estimate of the groups' temperature just below the generation temperature, i.e. reservoirs of the group might be expected to be at shallower depths (lower temperatures) than those of the generation zone due to vertical migration into pools. For each maturation level, a threshold temperature range for genesis was inferred from ...
2000-07-01
Trend arbitrage, bid-ask spread and market dynamics
Microstructure of market dynamics is studied through analysis of tick price data. Linear trend is introduced as a tool for such analysis. Trend arbitrage inequality is developed and tested. The inequality sets limiting relationship between trend, bid-ask spread, market reaction and average update frequency of price information. Average time of market reaction is measured from market data. This parameter is interpreted as a constant value of the stock exchange and is attributed to the latency of exchange reaction to actions of traders. This latency and cost of trade are shown to be the main limit of bid-ask spread. Data analysis also suggests some relationships between trend, bid-ask spread and average frequency of price update process.
2006-01-01
International Nuclear Information System (INIS)
Using the full potential linearized augmented plane wave (FLAPW) method, thickness dependent magnetic anisotropy of ultrathin FeCo alloy films in the range of 1 monolayer (ML) to 5 ML coverage on Pd(0 0 1) surface has been explored. We have found that the FeCo alloy films have close to half metallic state and well-known surface enhancement in thin film magnetism is observed in Fe atom, whereas the Co has rather stable magnetic moment. However, the largest magnetic moment in Fe and Co is found at 1 ML thickness. Interestingly, it has been observed that the interface magnetic moments of Fe and Co are almost the same as those of surface elements. The similar trend exists in orbital magnetic moment. This indicates that the strong hybridization between interface FeCo alloy and Pd gives rise to the large magnetic moment. Theoretically calculated magnetic anisotropy shows that the 1 ML FeCo alloy has in-plane magnetization, but ...
2009-06-01
Effect of pitting corrosion on local strength of hold frames of bulk carriers (1st report)
Energy Technology Data Exchange (ETDEWEB)
Firstly, pitting corrosion observed on hold frames in cargo holds of bulk carriers which exclusively carry coal and iron ore has been investigated in detail. It was shown that the shape of the corrosion pits observed on them is a circular cone and the ratio of the diameter to the depth is in the range between 8 to 1 and 10 to 1, which is different from the trend observed for the bottom shell of the oil tanker where the ratio is in the range between 4 to 1 and 6 to 1. Secondly, a series of tensile tests has been conducted to investigate the effect of pitting corrosion on tensile strength of members. It was pointed out that the tensile strength decreases gradually and the total elongation decreases drastically with the increase of the thickness loss due to pitting corrosion. The reduction of the tensile strength of the members with pitting corrosion is larger than that of members with uniform thickness ...
2004-09-01
International Nuclear Information System (INIS)
Structure and magnetic properties of UNi_1_0_-_xFe_xSi_2 intermetallics and "2"9Si nuclear magnetic resonance (NMR) in UNi_1_0Si_2 are investigated in a wide temperature range. Solid solutions in the exactly single-phase tetragonal form, ThMn_1_2 type, exist for x<2. The Ni and Fe atoms occupy the 8(f), 8(i) and 8(j) positions statistically, whereas the U atoms occupy the 2(a) and the Si atoms the 8(j) sites. The lattice parameters roughly follow Vegard's law. The magnetic susceptibility does not exhibit Curie-Weiss behaviour and, at about 630 K, an anomaly in the temperature dependence is observed. At low temperature, other anomalies are observed at 32 K and 45 K, for x=0.5 and 1.0 respectively. These low temperature anomalies are probably connected with magnetic ordering of a ferromagnetic character, whereas that at 630 K might result from the ...
1993-09-01
Non-equilibrium modelling of an oxygen-plasma cutting torch
International Nuclear Information System (INIS)
A two-temperature, axi-symmetric, chemical non-equilibrium model has been developed for an oxygen-plasma cutting torch in two dimensions to obtain distributions of different plasma quantities inside the torch. Apart from mass, momentum and potential conservation equations, separate energy balance equations are considered for electrons and heavy particles. The ?-? model has been used to account for turbulence. Non-equilibrium properties required for fluid dynamic simulations are obtained from a non-equilibrium property code that includes chemical non-equilibrium. The results show distributions of temperature, velocity, pressure, potential, current density and different species densities inside the plasma torch for an arc current of 200 A. Plasma pressure inside the torch varies from several atmospheres to near-atmospheric pressure. It has been observed that the electron and the heavy particle ...
2007-04-07
Neutron diffraction study of quasi-one-dimensional spin-chain compounds Ca3Co2-xFexO6
International Nuclear Information System (INIS)
We report the results of the DC magnetization, neutron powder diffraction and neutron depolarization studies on the spin-chain compounds Ca3Co2-xFexO6 (x = 0, 0.1, 0.2 and 0.4). Rietveld refinement of neutron powder diffraction patterns at room temperature confirms the single-phase formation for all the compounds in rhombohedral structure with space group R3-barc. Rietveld refinement also confirms that Fe was doped at the trigonal prism site, 6a (0, 0, 1/4) of Co. The high temperature magnetic susceptibility obeys the Curie-Weiss law; the value of the paramagnetic Curie temperature (?p) decreases as the concentration of iron increases and it becomes negative for x = 0.4. No extra Bragg peak as well as no observable enhancement in the intensity of the fundamental (nuclear) Bragg peaks has been observed in the neutron diffraction patterns down to 30 K. No depolarization of neutron ...
2008-11-01
Late Archean intrusive charnockites from the west-central Wind River Mountains, Wyoming
Energy Technology Data Exchange (ETDEWEB)
Late Archean (ca. 2.5Ga) porphyritic granites to comprise about 25% of the crystalline rocks of the Wind River uplift. In most localities, they are typical biotite-hornblende granites but on the western margin of the range there is evidence that portions of at least one pluton were emplaced as charnockite. In the Burnt Lake area homogenous charnockite crops out over an area of at least 3km while in the Boulder Creek Canyon, 8km to the S.E. charnockite occurs locally as blotches in porphyritic biotite granite. One sample from Boulder Creek, 15 cm in the longest dimension, shows a complete transition from charnockite to biotite granite. Textures indicate that the transition occurred as subsolidus hydration, with hornblende and biotite replacing augite and orthopyroxene, respectively. Pryoxene geothermometry from this sample yields maximum temperatures of around 900/sup 0/C, with a cooling trend to 600/sup 0/. Fluid inclusion of both CO/sub 2/ (p ...
1985-01-01
Stable p-channel polysilicon thin film transistors fabricated by laser doping technique
Energy Technology Data Exchange (ETDEWEB)
In this work we present the electrical characterization of non self-aligned p-channel thin film transistors fabricated by using laser doping technique for source/drain contact formation and gate oxide deposited at room temperature by Electron Cyclotron Resonance Plasma Enhanced Chemical Vapour Deposition. These techniques are suitable for a very low temperature process for TFT fabrication. The output characteristics show a current increase at high drain voltage ('kink' effect) rather moderate, if compared to self aligned polysilicon TFTs, probably due to the gradual doping profile induced by laser doping process. After bias stress at low gate voltage and high drain voltage condition a strong reduction of kink current has been observed in the output characteristics at high drain voltage, whereas minor changes has been observed in the transfer characteristics. This behaviour is similar ...
2005-09-01
Stable p-channel polysilicon thin film transistors fabricated by laser doping technique
International Nuclear Information System (INIS)
In this work we present the electrical characterization of non self-aligned p-channel thin film transistors fabricated by using laser doping technique for source/drain contact formation and gate oxide deposited at room temperature by Electron Cyclotron Resonance Plasma Enhanced Chemical Vapour Deposition. These techniques are suitable for a very low temperature process for TFT fabrication. The output characteristics show a current increase at high drain voltage ('kink' effect) rather moderate, if compared to self aligned polysilicon TFTs, probably due to the gradual doping profile induced by laser doping process. After bias stress at low gate voltage and high drain voltage condition a strong reduction of kink current has been observed in the output characteristics at high drain voltage, whereas minor changes has been observed in the transfer characteristics. This behaviour is similar to what ...
2005-09-01
In situ thermal desorption of H{sub 2} from LiNH{sub 2}-2LiH monitored by environmental SEM
Energy Technology Data Exchange (ETDEWEB)
This article describes in situ heating and observation of a LiNH{sub 2}-2LiH mixture in an environmental scanning electron microscope (ESEM). The LiNH{sub 2}-2LiH mixture showed extensive morphological changes with heating and attendant hydrogen desorption. Static images and real-time movies were obtained during the dehydrogenation process. H{sub 2} evolution commences at {proportional_to}150 C (LiNH{sub 2} + 2LiH {yields} Li{sub 2}NH + H{sub 2} + LiH), and continues until {proportional_to}410 C. Dramatic morphological changes are observed at 220 and 410 C (Li{sub 2}NH + LiH {yields} Li{sub 3}N + H{sub 2}). The material converts to a microcrystalline phase at higher temperatures (>500 C). The observed H{sub 2} desorption and morphological changes occur at temperatures in good agreement with those measured by complementary analytical methods. This is the first time the major ...
2009-01-15
Stress-induced amorphization at moving crack tips in NiTi.
Energy Technology Data Exchange (ETDEWEB)
In situ fracture studies on thin-film NiTi intermetallic compounds have been carried out in the high-voltage electron microscope at Argonne National Laboratory. Local stress-induced amorphization of regions directly in front of moving crack tips has been observed under tensile loading conditions. The stress-induced amorphization at crack tips exhibits a temperature dependence similar to that of ion-induced amorphization of NiTi. The upper limiting temperature for stress-induced amorphization is the same as that for ion-induced amorphization of crystalline NiTi and for amorphous phase formation during ion-beam mixing of Ni and Ti multilayer specimens. This upper limiting temperature of 600K is also the lowest temperature at which stress-induced amorphous phase crystallizes during isothermal annealing. This isothermal crystallization temperature is nearly 200K ...
1998-01-29
Quantum Transition State Theory for proton transfer reactions in enzymes
We consider the role of quantum effects in the transfer of hyrogen-like species in enzyme-catalysed reactions. This study is stimulated by claims that the observed magnitude and temperature dependence of kinetic isotope effects imply that quantum tunneling below the energy barrier associated with the transition state significantly enhances the reaction rate in many enzymes. We use a path integral approach which provides a general framework to understand tunneling in a quantum system which interacts with an environment at non-zero temperature. Here the quantum system is the active site of the enzyme and the environment is the surrounding protein and water. Tunneling well below the barrier only occurs for temperatures less than a temperature $T_0$ which is determined by the curvature of potential energy surface near the top of the barrier. We argue that for most enzymes this ...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
Onset of convection in a layer of couple-stress fluid-saturated porous medium is investigated for different types of basic temperature gradients. The boundaries are considered to be adiabatically insulated to temperature perturbations. The eigenvalue equations of the perturbed state obtained from the normal mode analysis are solved analytically using a regular perturbation technique with wave number as a perturbation parameter and also numerically using the Galerkin technique. The critical stability parameters obtained from these two techniques are in excellent agreement and an increase in the value of couple-stress parameter is found to delay the onset of convection. The results also indicate that the piecewise linear temperature profile hastens the onset of convection when compared to linear, parabolic, and inverted parabolic temperature profiles. In addition, the influence of thermal depth on the ...
2010-08-15
Magnetic properties of Pr_2PdSi_3 single crystals
International Nuclear Information System (INIS)
Ternary R_2TSi_3 intermetallic compounds (R=Rare Earth, T=Transition Metal) with hexagonal AlB_2-type crystallographic structure are known because of their interesting physical properties. Pr_2PdSi_3 single crystals were grown by a vertical floating zone method. The compound exhibits congruent melting behavior at a liquidus temperature of about 1770 C. Single crystalline samples show a huge anisotropy at low temperatures due to the crystal electric field effect and order antiferromagnetically below the Neel temperature T_N=2.17 K. This value approximately obeys the linear de Gennes scaling for this class of compounds. The [001] orientation was identified as the magnetic easy axis at room temperature. At lower temperature (#approx#20 K) magnetic easy and hard axes interchange with each other. Two additional magnetic phase transitions were observed at ...
2010-03-21
Energy Technology Data Exchange (ETDEWEB)
Tensile specimens of the normalized and tempered fully martensitic steel DIN 1.4914 were helium implanted up to 340 appm within the temperature range 300-720/sup 0/C using a 104 MeV alpha particle beam. The high He/damage ratio of 1850 appm He/dpa allowed to determine the effect of helium on material properties. After irradiation tensile strength and ductility were investigated mainly at test temperatures equal to the irradiation temperatures. While short time irradiations with helium contents up to 100 appm have shown no visible effect on the tensile behaviour at all temperatures investigated, long time irradiations reduced the material strength at irradiation temperatures above about 440/sup 0/C. This irradiation induced softening obscured the predicted minor hardening effect of the observed He-bubbles completely and increases with irradiation time and ...
1988-07-01
Energy Technology Data Exchange (ETDEWEB)
Low transition temperature (low-{Tc}) and high-{Tc} Superconducting QUantum Interference Devices (SQUIDs) have been used to perform high-resolution magnetic measurements on samples whose temperatures are much higher than the operating temperatures of the devices. Part 1 of this work focuses on measurements of the rigidity of flux vortices in high-{Tc} superconductors using two low-{Tc} SQUIDs, one on either side of a thermally-insulated sample. The correlation between the signals of the SQUIDs is a direct measure of the extent of correlation between the movements of opposite ends of vortices. These measurements were conducted under the previously-unexplored experimental conditions of nominally-zero applied magnetic field, such that vortex-vortex interactions were unimportant, and with zero external current. At specific temperatures, the authors observed highly-correlated noise ...
1997-05-01
Energy Technology Data Exchange (ETDEWEB)
The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the augmentation ...
1992-10-01
Phase and microstructural evolution of Ca #alpha#-SiAlON containing elongated grains
International Nuclear Information System (INIS)
Rare earth stabilised #alpha#-SiAlONs are commonly observed with an equiaxed grain morphology. Elongated #alpha#-SiAlON has been observed in some of these systems, however it usually results from special techniques such as pressure sintering. The formation of elongated #alpha#-SiAlON grains during pressureless sintering has been shown to commonly occur in the Ca #alpha#-SiAlON system. Examination of phase and microstructural development in three Ca #alpha#-SiAlON compositions in the temperature range 1400 deg to 1800 deg C showed that phase development and grain growth occurred at different temperatures. It was found that chemical reactions were completed by 1550 deg C, however significant grain growth did not occur at this temperature. Grain growth progressed from 1600 deg C and continued up to 1800 deg C, the maximum temperature investigated. At 1800 deg C, ...
1998-09-28
Thermoluminescence studies in lead doped KCl and KBr crystals
International Nuclear Information System (INIS)
Lead is known to enter substitutionally in divalent state when doped in alkali halides. When irradiated at room temperature these lead centers (Pb"+"+) act as traps for electrons knocked off from the halogen ions and become Pb"+ and Pb"0 (for large doses of irradiation). These changes could be followed in the optical absorption studies. These lead-doped crystals after X-ray irradiation yield a thermoluminescence output smaller than that observed in 'pure' crystals. However, two new glow peaks are observed in additions to those due to F-centers. In KCl : Pb and Kbr : Pb crystals part of the F-center glow preceds the new glow peaks. The new peaks are attributed to the Pb"+ and Pb"0 centers. The glow peak temperatures and trap depths for these peaks an obtained by total-curve fitting method are reported. (author).
1975-02-12
Pd adsorption on Si(1 1 3) surface: STM and XPS study
Energy Technology Data Exchange (ETDEWEB)
Pd-induced surface structures on Si(1 1 3) have been studied by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). In the initial process of the Pd adsorption below 0.10 ML, Pd silicide (Pd{sub 2}Si) clusters are observed to form randomly on the surface. By increasing the Pd coverage to 0.10 ML, the clusters cover the entire surface, and an amorphous layer is formed. After annealing the Si(1 1 3)-Pd surface at 600 deg. C, various types of islands and chain protrusions appears. The agglomeration, coalescence and crystallization of these islands are observed by using high temperature (HT-) STM. It is also found by XPS that the islands correspond to Pd{sub 2}Si structure. On the basis of these results, evolution of Pd-induced structures at high temperatures is in detail discussed.
2008-09-30
Observation of dislocation-mediated layer-by-layer interface growth
Energy Technology Data Exchange (ETDEWEB)
The growth of thin Pd[sub 2]Si films on Si(111) surfaces is studied using [ital in] [ital situ] transmission electron microscope under ultrahigh vacuum conditions. No immediate reaction of deposited Pd with Si is observed at room temperature. At [similar to]200 [degree]C, uniform Pd[sub 2]Si films can be formed. The thin Pd[sub 2]Si films are found to grow into strained islands at elevated temperatures. Interfacial misfit dislocations associated with interfacial steps propagate across the strained islands, causing the islands to grow layer-by-layer at the interface. The strain fields associated with the misfit dislocations are believed to be responsible for this behavior.
1994-07-11
Influence of annealing on the microstructure of commercial Mg alloy AZ31 after mechanical forming
International Nuclear Information System (INIS)
The microstructure of commercial rolled magnesium alloy AZ31B (nominal composition Mg-3Al-0.9Zn-0.15Mn in wt.%) was investigated with the help of light microscopy, electron backscatter diffraction (EBSD) and X-ray diffraction technique after annealing in the temperature range from room temperature (RT) to 400 deg. C. Tensile tests at RT were performed to show the influence of the microstructure on mechanical properties. Static recrystallization (SRX) was observed during annealing of as-received alloy at and above 150 deg. C. Twins play an important role during SRX and serve as nucleation sites and preferred paths for growth of grains. The strong basal texture caused by rolling was weakened by SRX. Significant differences in the stress strain curves were observed for as-received and annealed specimens.
2006-09-25
Observation of a surface peak in low energy implant depth profiles in silicon
Energy Technology Data Exchange (ETDEWEB)
In situ Auger sputter depth profiles of saturation implants of 3 keV N/sub 2//sup +/ in silicon at room temperature exhibit a sharp peak in the nitrogen concentration in the outermost layers, followed by a monotonic decrease. No broad plateau was observed. The energy of the Auger line corresponding to the Si(2p) core electron excitation, monitored throughout the profiling, exhibits a chemical shift of up to 7 eV at the surface peak concentration. Inert gas ion post-bombardment of unsaturated implants significantly modifies the profile, and supports the suggestion that the surface peak arises through radiation enhanced diffusion of implanted atoms.
1984-03-01
Energy Technology Data Exchange (ETDEWEB)
A low power polychromatic beam of microwaves is used to diagnose the behavior of turbulent fluctuations in the core of the JT-60U tokamak during the evolution of the internal transport barrier. A continuous reduction in the size of turbulent structures is observed concomitant with the reduction of the density scale length during the evolution of the internal transport barrier. The density correlation length decreases to the order of the ion gyroradius, in contrast to the much longer scale lengths observed earlier in the discharge, while the density fluctuation level remain similar to the level before transport barrier formation.
2005-03-29
Infrared stimulated luminescence in quartz
Energy Technology Data Exchange (ETDEWEB)
Infrared (IR, 880 nm) stimulated luminescence (IRSL) signal was observed from quartz at room temperature. The characteristics of the signal such as its response to {gamma}-ray irradiation, thermal stability and thermal assistance energy show that the signal originates from different traps than those responsible for the luminescence signal stimulated by green light (GL, 514 nm). The IRSL signal's short lifetime (18 days at 15 deg. C) may have been the reason why it was not detected in previous experiments. The decay of the IR signal after GL illumination was observed. The thermoluminescence at 76 deg. C was enhanced after IR illumination.
2005-02-01
Effect of discharge voltage on an ion sheath formed at a grid in a multi-dipole discharge plasma
International Nuclear Information System (INIS)
It is experimentally demonstrated that a relatively strong ion-rich sheath formed at a fixed negative bias of the grid can be changed to a rather weak ion sheath (sheath potential weakly retards electrons) only by increasing the discharge voltage in the system. At sufficiently high negative grid bias, an increase of discharge voltage enhances the ion collection current at the grid. An explanation is put forward in support of this experimental observation. A slight density enhancement with a fall in plasma electron temperature is also observed with the increasing negative grid bias. (authors)
2008-03-01
Energy Technology Data Exchange (ETDEWEB)
Intraionic spin-orbit--split multiplet levels have been observed by electronic Raman scattering in the intermediate-valence compound EuPd/sub 2/Si/sub 2/. From the temperature dependence of the Raman peak positions and widths the interconfigurational excitation energy E/sub x/ and an upper limit of the interconfigurational mixing width T/sub f/, respectively, have been obtained. This is the first spectroscopic support for the underlying assumptions of the ionic interconfigurational fluctuation model that has been proposed to describe intermediate valence.
1985-01-21
International Nuclear Information System (INIS)
Intraionic spin-orbit--split multiplet levels have been observed by electronic Raman scattering in the intermediate-valence compound EuPd_2Si_2. From the temperature dependence of the Raman peak positions and widths the interconfigurational excitation energy E/sub x/ and an upper limit of the interconfigurational mixing width T/sub f/, respectively, have been obtained. This is the first spectroscopic support for the underlying assumptions of the ionic interconfigurational fluctuation model that has been proposed to describe intermediate valence.
Relic abundance of WIMPs in non-standard cosmological scenarios
Energy Technology Data Exchange (ETDEWEB)
In this thesis we study the relic density n{sub {chi}} of non--relativistic long--lived or stable particles {chi} in various non--standard cosmological scenarios. First, we discuss the relic density in the non--standard cosmological scenario in which the temperature is too low for the particles {chi} to achieve full chemical equilibrium. We also investigated the case where {chi} particles are non--thermally produced from the decay of heavier particles in addition to the usual thermal production. In low temperature scenario, we calculate the relic abundance starting from arbitrary initial temperatures T{sub 0} of the radiation--dominated epoch and derive approximate solutions for the temperature dependence of the relic density which can accurately reproduces numerical results when full thermal equilibrium is not achieved. If full equilibrium is reached, our ansatz no longer reproduces the correct ...
2007-08-06
Texture development of AZ31 magnesium alloy during ECAE processing
Energy Technology Data Exchange (ETDEWEB)
Mg-3%Al-1%Zn (AZ31) alloy was subjected to ECAE processing at 523 and 573 K. Microstructure observation and texture analysis were carried out using optical microscope and SEM-EBSD technique in order to investigate the process of microstructural changes including texture development during ECAE processing. Grain refinement during ECAE processing is enhanced by dynamic continuous recrystallization. The texture of the ECAE-processed AZ31 alloy specimens change with ECAE processing temperature, and the textural changes relate to deformation mechanisms that change with ECAE processing temperature. (orig.)
2003-07-01
Strain induced hardening in Ti-3Al-4V at 910 deg. C
International Nuclear Information System (INIS)
High temperature deformation behavior of an alpha + beta titanium alloy Ti-3Al-4V has been investigated at 910 deg. C. by using the method of cross head speed cycling. On the basis of flow stress, strain rate and strain rate sensitivity data, the alloy was found to exhibit strain hardening at this temperature which resulted in degradation in superplastic properties of the alloy. A high beta-phase volume fraction and grain-growth in both alpha and beta phases were considered responsible for the observed hardening effect. (author)
Energy Technology Data Exchange (ETDEWEB)
A rocket borne experiment to measure the temperature structure of the inner solar corona via the doppler broadening of the resonance hydrogen Lyman-..cap alpha.. (lambda1216A) radiation scattered by ambient neutral hydrogen atoms was attempted during the 16 Feb 1980 solar eclipse. Two Nike-Black Brant V sounding rockets carrying instrumented payloads were launched into the path of the advancing eclipse umbra from the San Marco satellite launch platform 3 miles off the east coast of Kenya.
1981-01-01
International Nuclear Information System (INIS)
Lithium orthosilicate (Li_4SiO_4) powder was synthesized by the solid-state reaction of lithium oxide with amorphous silica, and the effects of fabrication parameters on the structural characteristics of the product were investigated. Processing considerations such as milling media, drying technique, calcination time and temperature, pressing behavior, sintering time and temperatures, and impurity concentration were addressed. The initial powder particle size was observed to be important in achieving high sintered density, with densities as high as 98% TD achieved with a particle size of approximately 1 #mu#m. 9 refs., 6 figs.
1988-04-10
Energy Technology Data Exchange (ETDEWEB)
Methylmethacrylate polymerisation in the presence of 4 wt% butadiene-acrylonitrile rubber was carried out at fixed dose-rate and temperature. The effect of irradiation was investigated with respect to the mechanical and dynamic-mechanical properties in the solid state. A general increase of the 'compatibilisation' on irradiation is obtained. In fact both rubber and polymethylmethacrylate glass transition temperatures, determined through dynamic-mechanical analysis, reveal the presence of strong interactions between the components. Furthermore an improvement of the mechanical tensile properties of the blends is observed when irradiation is continued after polymerisation, at least until a certain absorbed dose.
2001-12-01
On the mechanism of the nonmonotonic relaxation processes in the metallic melts
International Nuclear Information System (INIS)
The numerical analysis of the experimental data on viscosity change by time in the period after fast heating and crystal-liquid phase transition for the copper nonequilibrium melts and the Fe_7_0Cr_1_0P_1_3C_7 glass-forming melt near their melting temperatures is accomplished through the method of correlation functions and the Rytov-Dimentberg criterion. The observed dependences have nonmonotonic oscillating character but they do not relate to auto-oscillations. The proposed theoretical model of the properties oscillations origination by relaxation in the nonequilibrium liquids explains them as manifestation of noise-induced transitions in the metastable area near the critical temperatures (melting, structural transitions)
2000-01-01
Neutron scattering study on the normal-incommensurate phase transition in K2ZnCl4
Energy Technology Data Exchange (ETDEWEB)
The normal-incommensurate phase transition in K2ZnCl4 was studied by neutron scattering measurements. A well-defined soft phonon behavior was not observed above the normal-incommensurate transition temperature of Tsub(i)=288C. Diffuse scattering develops around(h,0,1 +- 0.3) as temperature approaches Tsub(i) from above, and the peak intensity obeys a Curie-Weiss law above Tsub(i). The results indicate that the normal-incommensurate phase transition in K2ZnCl4 can be interpreted as an order-disorder process.
1984-12-01
Neutron irradiation effects in austenitic alloys
International Nuclear Information System (INIS)
The post (neutron) -irradiation high-temperature tensile and creep-rupture properties, deformation and fracture characteristics of austenitic alloys, particularly solution annealed Type 316 steel, are surveyed and correlated with the damage structures developed as a function of irradiation temperature (and dose). The mechanisms proposed to explain the irradiation-induced changes in properties and behaviour are summarised. The factors responsible for the observed differences in the post-irradiation and 'in-reactor' creep-rupture properties and behaviour of an austenitic steel are discussed in terms of the helium gas and stress driven growth of small intergranular bubbles and the atom plating associated with their growth and coalescence. (author).
1980-03-01
International Nuclear Information System (INIS)
Formation of the soft magnetic nanostructure in amorphous Fe_1_4Ni_4_0Zr_7B_1_2 alloy due to heat treatment is studied by the Moessbauer, differential scanning calorimetry, and X-ray diffraction techniques. Annealing at temperatures 520-580 "oC leads to the formation of extremely soft nanocrystalline alloy as revealed by the rf-Moessbauer measurements. The superparamagnetic behaviour was observed for the alloy annealed at 620-640 "oC. At higher annealing temperatures good soft magnetic properties deteriorate. (author)
2001-09-23
A low temperature synthesized NbC grain growth inhibitor in WC-Co hardmetal alloy
Energy Technology Data Exchange (ETDEWEB)
The efficiency of NbC on WC grain coarsening in a WC-10wt.%Co hardmetal alloy was demonstrated by hardness measurement and WC granulation observation. The heterogeneous and overall grain growth were controlled. A low temperature experimentally produced NbC was used and compared to the inhibition potential of a commercial NbC powder. The results were the same in terms of structural fineness and hardness. The dispersion of the experimental NbC was not a problem, in spite of its size. The experimental NbC has very large particles, formed by agglomerates of small crystallites. During milling these agglomerates could be broken down. (orig.)
2001-07-01
One-electron reduction of chloroperoxidase by radiolytically generated electrons
Energy Technology Data Exchange (ETDEWEB)
Upon irradiation of aqueous ethylene glycol/water solutions of native chloroperoxidase (CPO) with {sup 60}Co-gamma rays at 77K one observes the one-electron reduction of the enzyme active site by radiolytically generated thermolyzed electrons. In the present study the first absorption spectrum of a low-spin ferrous form of CPO is reported which has peaks at 438, 532 and 563 nm, similar to those observed previously for cytochrome P-450. All previously described ferrous forms of CPO are high spin. In order to observe the final results of the CPO reaction with electrons, the spectral changes of native enzyme after room temperature-gamma-irradiation have also been investigated. Evidence of changes is also presented probably connected with disruption of the tertiary structure of enzyme, correlated with decrease of enzyme activity.
1990-05-16
One-electron reduction of chloroperoxidase by radiolytically generated electrons
International Nuclear Information System (INIS)
Upon irradiation of aqueous ethylene glycol/water solutions of native chloroperoxidase (CPO) with "6"0Co-gamma rays at 77K one observes the one-electron reduction of the enzyme active site by radiolytically generated thermolyzed electrons. In the present study the first absorption spectrum of a low-spin ferrous form of CPO is reported which has peaks at 438, 532 and 563 nm, similar to those observed previously for cytochrome P-450. All previously described ferrous forms of CPO are high spin. In order to observe the final results of the CPO reaction with electrons, the spectral changes of native enzyme after room temperature-gamma-irradiation have also been investigated. Evidence of changes is also presented probably connected with disruption of the tertiary structure of enzyme, correlated with decrease of enzyme activity.
1990-05-01
On the suitability of alternate fuels for dual fuel engine operation
Energy Technology Data Exchange (ETDEWEB)
A compression ignition engine was operated on dual fuel principle inducting two commercial fuels and four pure hydrocarbon fuels in turn through intake manifold along with air and injecting diesel fuel to initiate the combustion in the conventional manner. The engine was operated at different loads and at each load the quantity of inducted fuel was increased gradually till knocking set in. The engine performance and exhaust pollutant emissions were recorded at different operating conditions. It was observed that the extent of induction and the effect on the performance depend on the properties of the inducted fuel such as volatility, self ignition temperature and oxidation characteristics. The energy release during the cycle was also observed to shift depending on the properties of inducted fuel. With the dual fuel operation, the thermal efficiency at part loads was observed to be less compared to neat ...
1980-12-01
Magnetic and electronic properties of Mn{sub 4}Si{sub 7}
Energy Technology Data Exchange (ETDEWEB)
We present a systematic study of the magnetization, Hall effect and specific heat on single crystals of Mn{sub 4}Si{sub 7}. Curie-Weiss law is observed above 43 K. At low-temperature moments order in an anisotropic helical state and are aligned above 1 T. We observe an anomalous Hall effect in both {rho}{sub H} vs. B and in R{sub H} vs. T curves and a field dependence of the low T specific heat due to spin fluctuations. The magnetic moments (p{sub eff} and p{sub sat}) are the lowest reported for similar itinerant magnetic systems, this suggests that Mn{sub 4}Si{sub 7} is a good candidate to observe critical quantum fluctuations expected for a marginal Fermi liquid.
2004-05-01
Infrared bleaching of the thermoluminescence of four feldspars
International Nuclear Information System (INIS)
This paper studies the effect upon the thermoluminescence (TL) signal of four feldspar samples of exposing them to infrared stimulation, as occurs during infrared-stimulated luminescence (IRSL) measurement. Together with pulse annealing measurements these results are used to show which part of the TL signal is removed by exposure to IR and which part is directly related to the IRSL signal that is observed. When the samples are preheated prior to measurement in order to remove any low-temperature (< 200"oC) TL signals, a linear relationship is observed between the amount of TL that is lost and the IRSL light sum that is produced. The IRSL light sum is consistently four times larger than the amount of TL that is lost. Three possible explanations are proposed for this, but no conclusive evidence could be obtained to support any of them. A close similarity is observed in the pulse annealing results and ...
1995-06-01
Cosmological Information from Lensed CMB Power Spectra
Gravitational lensing distorts the cosmic microwave background (CMB) temperature and polarization fields and encodes valuable information on distances and growth rates at intermediate redshifts into the lensed power spectra. The non-Gaussian bandpower covariance induced by the lenses is negligible to l=2000 for all but the B polarization field where it increases the net variance by up to a factor of 10 and favors an observing strategy with 3 times more area than if it were Gaussian. To quantify the cosmological information, we introduce two lensing observables, characterizing nearly all of the information, which simplify the study of non-Gaussian impact, parameter degeneracies, dark energy models, and complementarity with other cosmological probes. Information on the intermediate redshift parameters rapidly becomes limited by constraints on the cold dark matter density and initial amplitude of fluctuations as ...
2006-01-01
International Nuclear Information System (INIS)
The important role of thyroid hormones in growth and development, maintenance of body temperature, digestion, cardiac function, and normal brain development can be disrupted by environmental contaminants like polychlorinated biphenyls (PCB). Polychlorinated biphenyls are environmental contaminants that are widespread, persistent, lipophilic, and bioaccumulate through food webs, concentrating in adipose tissue. Placental and lactational PCB exposure of offspring causes metabolic and endocrine disruptions including hypothyroxinemia, spatial learning and memory deficits, neurochemical and neurobehavioral alterations, and reproductive problems. Previous studies in our lab using the individual congeners PCB 47 (2,2',4,4'-tetrachlorobiphenyl, ortho-substituted) and PCB 77 (3,3',4,4'-tetrachlorobiphenyl, non-ortho-substituted) have demonstrated alterations in thyroid hormone levels, alterations in brain choline acetyltransferase (ChAT) activity, and spatial learning ...
2004-10-15
British Library Electronic Table of Contents (United Kingdom)
Abstract Phase-separation dynamics are investigated by SALS in aqueous MC solutions in the presence of 5% NaCl, promoted by a quench temperature. The observed scattering peak indicates that the phase separation occurs by the SD mechanism, leading to a bicontinuous structure. A semilog plot of I(q) against time in the early stage of SD gives a straight line, but the position of qmax varies; also, a Cahn-Hilliard plot indicates that diffusive processes dominate and the data can be described by linear CHC theory. Dapp shows a kinetic dependency on the quench temperature. The spinodal temperature of the sample is 41-C. In the late stages, S(q,t) collapses into a universally time-independent curve.
2011-01-01
Nuclear magnetic resonance study of La_3X compounds and related phases
International Nuclear Information System (INIS)
Normal state nuclear magnetic resonance studies of the La_3In, La_3Tl compounds have been made in order to investigate the origin of the large temperature-dependent magnetic susceptibility. It is possible to analyse the different contributions to the susceptibility using Knight-shift and relaxation time T_1 measurements of In"1"1"5 and Tl"2"0"5 nuclei. The exchange enhancement of the spin-susceptibility chisub(pd) is of the same order as that found in A-15 compounds and the strong temperature-dependence of chi(T) is attributed to the presence of a peak in the electronic density of states near the Fermi level. The variation of the Knight-shift in the ternary alloys La_3Xsub(1-y)Xsub(y)sup(') is analogous to that observed in the corresponding La_3X phases, on the other hand the Knight-shift in the carbides La_3XC is temperature independent. (author).
Non-Fermi-liquid scaling in UCu_5_-_xPd_x (x=1, 1.5): a phenomenological description
International Nuclear Information System (INIS)
We present a unified description of the imaginary part of the dynamical magnetic susceptibility #chi#"'"'(#omega#.T) and measurements of the static susceptibility #chi#(T) and electrical resistivity #rho#(T) in the uranium intermetallics UCu_5_-_xPd_x (x = 1.1.5). For temperatures T and excitation energies #omega# in the range 12 K < #omega#, T < 150 K, our analysis demonstrates that the dynamics of isolated uranium ions are responsible for the observed temperature and frequency scaling, although interion interactions may become important at lower temperatures and frequencies. We derive a strict criterion for single-ion scaling in the form of a universal scaling function, providing a model-independent description of the compiled experimental data. (orig.).
International Nuclear Information System (INIS)
The present work is a research of the effect of helium on the microstructure, mechanical properties and fracture behaviors of a type 316 austenitic steel. Helium implantation was performed by 30-MeV #alpha#-particle injection on very small size specimens, using a cyclotron. Average helium content in a He-deposited region was up to 2000 appm He. In the case of 2000appm He implantation, intergranular fracture was sometimes observed on the helium deposited region after tensile test at room temperature. At elevated temperature test, however, this material showed the transition of fracture mode from transgranular-ductile fracture at 773K to intergranular fracture at 873. In the case of 500 appm He implantation, the transition of fracture mode was recognized at a temperature range of 873K to 973K. (author).
Magnetocaloric and magnetoresistance studies of GdPd{sub 2}Si
Energy Technology Data Exchange (ETDEWEB)
The compound GdPd{sub 2}Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric effect and ...
2001-01-22
Magnetocaloric and magnetoresistance studies of GdPd_2Si
International Nuclear Information System (INIS)
The compound GdPd_2Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric effect and magnetoresistance, ...
2001-01-22
Magnetic properties of some Au_3R compounds
International Nuclear Information System (INIS)
The magnetization of a series of intermetallic compounds Au_3R, where R is Gd through Yb, was investigated at 2.5 to 300"0K in applied fields up to 26 kOe. All the compounds studied exhibited the orthorhombic TiCu_3--Do/sub a/ type structure. For high temperatures, the temperature dependence of the inverse susceptibility followed a Curie--Weiss law, yielding effective paramagnetic moments in good agreement with the values calculated for free tripositive rare earth ions. At low temperatures, deviations from Curie--Weiss behavior were observed in all cases. These deviations are ascribed to the influence of crystal-field and exchange interactions. (auth).
1974-12-03
Energy Technology Data Exchange (ETDEWEB)
Kinetics of postradiation polymerization of triethylene glycol ..cap alpha.., ..omega..-dimethacrylate has been studied by calorimetric method. The low-temperature radiolysis has been studied by ESR method. The radiation-chemical yield of radicals on ..gamma..-irradiation by /sup 60/Co is determined being equal to 6+-1 1/100 ev. Transformation of the radicals spectrum into the spectrum of propagating macroradicals proceeds at 140 K. After the transition from glassy to liquid state (Tsub(g)=193 K) the intensive postpolymerization begins. During the polymerization the disappearance of radicals is observed. For the low-temperature region the effective activation energy of polymerization is determined beina equal to 50.7+-0.8 kJ/mol.
1984-04-01
International Nuclear Information System (INIS)
It has recently been shown that the superconducting properties of Nb-base A-15 compounds, A_3B, are severely degraded when exposed to high-energy (E>1 MeV) neutron irradiation at ambient reactor temperatures. In each case, superconducting transition temperatures, Tsub(c), and the Bragg Williams order parameters, S, were observed to decrease steadily with irradiations in excess of 10"1"8 nvt. During irradiation the A-15 structure is retained and subsequent isothermal annealing restores almost completely the compound's original Tsub(c) value. In this letter a correlation between B atom diameter and the recovery rates of Tsub(c) for the irradiated materials Nb_3Ge, Nb_3Ga, Nb_3Al and Nb_3Sn is reported. (Auth.).
Energy Technology Data Exchange (ETDEWEB)
The effects of boron addition on weldability and high temperature strength properties were investigated for Hastelloy alloy XR used TIG welding process with the filler metals. Four versions of filler metals with different boron contents were used. The results obtained may be summarized as follows: (1) The influence of boron addition on weldability was not observed within the range of the present experiment. (2) The result of chemical analysis for deposited metals showed that boron desorption did not occur during welding. (3) The tensile properties of weldments, particularly in high temperature ductility were raised with increasing boron content. (4) In the creep properties of weldments, creep rupture life increased with increasing boron content under the given stress conditions. (author).
1990-11-01
International Nuclear Information System (INIS)
The effects of boron addition on weldability and high temperature strength properties were investigated for Hastelloy alloy XR used TIG welding process with the filler metals. Four versions of filler metals with different boron contents were used. The results obtained may be summarized as follows: 1) The influence of boron addition on weldability was not observed within the range of the present experiment. 2) The result of chemical analysis for deposited metals showed that boron desorption did not occur during welding. 3) The tensile properties of weldments, particularly in high temperature ductility were raised with increasing boron content. 4) In the creep properties of weldments, creep rupture life increased with increasing boron content under the given stress conditions. (author).
Dielectric properties of sols of silver nanoparticles capped by alkyl carboxylate ligands
British Library Electronic Table of Contents (United Kingdom)
Sols of silver nanoparticles in toluene were studied by broadband dielectric spectroscopy (10?3?105 Hz). The frequency dependences of the specific alternating current (ac) conductivity and the complex electric modulus were used to estimate the temperature/frequency intervals of long- and short-range charge transfer occurs, respectively. A considerable increase (by more than 30 ?C) in the Vogel temperature T 0 and the glass transition temperature T g in sols compared with the pure solvent was found. It can be hypothesized that these cooperative effects reflect the initial stage of the superlattice formation. Although the dielectric characteristics of sols are generally controlled by the conductivity relaxation, the dielectric response was observed in the high-frequency range (1?103 Hz) at l...
2011-01-01
Development of a detailed kinetic model for gasoline surrogate fuels
Energy Technology Data Exchange (ETDEWEB)
A detailed chemical kinetic model to describe the autoignition of gasoline surrogate fuels is presented consisting of the fuels iso-octane, n-heptane, toluene, diisobutylene and ethanol. Model predictions have been compared with shock tube ignition delay time data for surrogates of gasoline over practical ranges of temperature and pressure, and the model has been found to be sensitive to both changes in temperature and pressure. Moreover, the model can qualitatively predict the observed synergistic and antagonistic non-linear blending behaviour in motor octane number (MON) for different combinations of primary reference fuels (PRFs) and non-PRFs by correlating calculated autoignition delay times from peak pressures and temperatures in the MON test to experimental MON values. The reasons for the blending behaviour are interpreted in terms autoignition chemistry. 37 refs., 11 figs., 4 tabs.
2008-08-15
Black hole radiation in Bose-Einstein condensates
We study the phonon fluxes emitted when the condensate velocity crosses the speed of sound, i.e., in backgrounds which are analogue to that of a black hole. We focus on elongated one dimensional condensates, and on stationary flows. Our theoretical analysis and numerical results are based on the Bogoliubov-de-Gennes equation without any further approximation. The spectral properties of the fluxes and of the long distance density-density correlations are obtained, with and without an initial temperature. In realistic conditions, we show that the condensate temperature dominates the fluxes, and thus hides the presence of the spontaneous emission (the Hawking effect). We also explain why the temperature amplifies the long distance correlations which are intrinsic to this effect. This confirms that the correlations pattern offers a neat signature of the Hawking effect. Optimal conditions to observe the ...
2009-01-01
Assessment of GABARAP self-association by its diffusion properties
Energy Technology Data Exchange (ETDEWEB)
Gamma-aminobutyric acid type A receptor-associated protein (GABARAP) belongs to a family of small ubiquitin-like adaptor proteins implicated in intracellular vesicle trafficking and autophagy. We have used diffusion-ordered nuclear magnetic resonance spectroscopy to study the temperature and concentration dependence of the diffusion properties of GABARAP. Our data suggest the presence of distinct conformational states and provide support for self-association of GABARAP molecules. Assuming a monomer-dimer equilibrium, a temperature-dependent dissociation constant could be derived. Based on a temperature series of {sup 1}H{sup 15}N heteronuclear single quantum coherence nuclear magnetic resonance spectra, we propose residues potentially involved in GABARAP self-interaction. The possible biological significance of these observations is discussed with respect to alternative scenarios of oligomerization.
2010-09-15
Antiferromagnetic ordering of defects in GaAs
Energy Technology Data Exchange (ETDEWEB)
The magnetic susceptibility of GaAs samples containing a large concentration of native defects was investigated by dc magnetization measurements. Thin GaAs films grown by molecular-beam epitaxy at very low temperatures and bulk GaAs:S samples irradiated with fast neutrons have been studied. For all samples, the susceptibility follows a Curie-Weiss law, indicating the presence of localized magnetic moments. These moments are attributed to unpaired spins located at the native defects. Negative Curie-Weiss temperatures found for both neutron-irradiated and low-temperature-grown GaAs is a clear manifestation of an antiferromagnetic interaction between the moments. The presence of a highly inhomogeneous distribution of native defects has to be assumed to account for the observed antiferromagnetic ordering.
1992-10-15
Supramolecular selectivity of [60]-fullerene among equivalently photoactive porphyrins
International Nuclear Information System (INIS)
The photophysical investigation of different para-substituted tetraphenylporphyrins (TP), viz., meso-tetra(4'-hydroxyphenyl)-21H-23H-porphyrin(1),meso-tetrakis (4'-hex-5-enyloxyphenyl)-21H-23H-porphyrin(2), meso-tetrakis(4'-oct-7-enyloxyphenyl)-21H-23H-porphyrin(3) and meso-tetrakis(4'-undecyloxyphenyl)-21H-23H-porphyrin (4) revealed that except for quantum yield (#phi#) the para-substitution has little effect on any other photophysical properties like lifetime, excitation, emission wavelength, etc. The host-guest type interactions of these tetraarylporphyrins (TP 1-4), with [60]-fullerene (F) have been studied with "1H NMR and fluorescence spectrometric techniques in carbon tetrachloride medium. Fluorescence studies revealed that the Q band of the TPs was sufficiently quenched upon addition of F. All the fullerene/porphyrin systems were found to produce stable complexes with 1:1 stoichiometry. Binding constants (K) of all the fullerene/porphyrin complexes have been determined by ...
2010-10-01
Prognostic factors in the treatment of Ewing's sarcoma
International Nuclear Information System (INIS)
From 1981 up to February 1985, a total of 93 protocol patients entered the study CESS 81. The protocol recommended an initial 18-week period of polychemotherapy (VACA) followed by local therapy and two additional cycles of chemotherapy. Local therapy consisted either of radical surgery or of incomplete resection plus postoperative irradiation with 36 Gy or of radiotherapy alone (46 and 60 Gy). Centrally located lesions were always irradiated with 60 Gy. This article summarizes the data after 5 years. Data of 93 patients were analysed in October 1986 after a median follow-up of 37 months. The projected 5-year survival is 50%. The relapse rate was 42%, distant relapses occurred in 19%, local (plus distant) relapses in 23%. Most of the relapses occurred during the first 3 years of observation. Failure rate was high in patients undergoing irradiation alone (44%). Initial tumour mass (> 100 ml) and histopathologic response to initial chemotherapy were identified as ...
Energy Technology Data Exchange (ETDEWEB)
In August 1989, representatives from the Alberta Oil Sands Technology and Research Authority (AOSTRA) were the guests of the USSR Interbranch Scientific Technological Complex, Oil Recovery Institute (MNTK) in an extensive visit to heavy oil and gas fields and to various research institutes. Observations made during this tour concerning developments in the USSR heavy oil/bitumen industry, enhanced oil recovery, research programs, proposals for joint ventures, and technological developments are reported. It is noted that oil production in the USSR seems to have peaked and is in a state of decline, indicating the vital importance of enhanced recovery projects in reversing this trend. The areas visited included the Yarega field, where underground thermal recovery methods are used; the Sakhalin Island area, where successful thermal methods are used and where the USSR's largest offshore drilling rig is located; the Krasnodar/Black Sea area, ...
1990-01-01
Energy Technology Data Exchange (ETDEWEB)
Holmium doped barium based hexaferrites BaFe{sub 12-2x}Ho{sub 2x}O{sub 19} with (x = 0.0-1.0) were synthesized by solid state reaction method. Structural and magnetic characterization of these ferrites provide significant information about their reactive physical properties. X-ray analysis reveals that in all samples M-type structure exist with few secondary phases. Scanning electron microscope revealed the grain size of the specimen. The results show that grain size decreases with the substitution degree of Holmium. Thus rare earth element Holmium Ho{sup 3+} acts as a grain growth inhibitor. The magnetic hysteresis loops show the variation in the values of magnetic parameters like saturation magnetization (M{sub s}), remanent magnetization (M{sub r}) and coercivity (H{sub c}) were observed by changing Ho{sup 3+} content in BaFe{sub 12-2x}Ho{sub 2x}O{sub 19} ferrites. Coercivity showed a maximum value of 2230 Oe for (x = 0.4) and then decreasing ...
2010-04-09
Energy Technology Data Exchange (ETDEWEB)
The gotten concentrations of radon-222 in the installations of the IEN had been determined using the active and passive methods. The active method consisted on the use of the alpha spectrometry with a portable equipment Tracerlab Instruments WLM- Plus. In the determination for the passive method, one used detectors of nuclear strokes of type LEXAN. The raised values had been gotten in the wastes deposit and its annexes, room of the press and laboratory of wastes handling. It was observed, in this sector, an instantaneous measure of alpha spectrometry, concentrations around 1000 Bq.m-3, which had over all to the function of storage, the sector, a great volume of natural radioactive materials, especially of radium-226. This determination was carried through in an extreme situation of ventilation zero, where the gates had been kept closed during the execution of the same one. It was observed, however, a considerable fall, with values ten times ...
2000-07-01
Characterization of TiN coatings deposited on plasma nitrided tool steel surfaces
Energy Technology Data Exchange (ETDEWEB)
Wear-resistant TiN coatings deposited on tool steels are used frequently in industry. There is a trend towards further optimizing these coatings, e.g. by plasma nitriding the tool surface prior to TiN deposition. In this work the influence of the nitriding conditions on the surface properties of AISI 304 and ASP 23 tool steels was investigated. The plasma nitriding was carried out in a triode ion plating configuration normally used to deposit TiN coatings. At the surface of AISI 304 stainless steel, only a thin compound layer (Fe{sub 4}N, Fe{sub 3}N) was found, probably as a consequence of the rather slow nitrogen diffusion in the austenite matrix. For ASP 23 high speed steel, the different nitriding behaviour of the martensitic matrix causes the formation of a diffusion layer which results in an increase in hardness at the surface. On an analogous set of specimens the TiN deposition was started immediately after the plasma nitriding. To optimize this combined ...
1991-07-07
International Nuclear Information System (INIS)
The molar extinction coefficients at the absorption maximum of the solvated electron spectrum have been evaluated to be 900, 970, and 1000 mol-1?m2 for 1,2-ethanediol (12ED), 1,2-propanediol (12PD), and 1,3-propanediol (13PD), respectively. These values are two-third or three-fourth of the value usually reported in the published report. Picosecond pulse radiolysis studies have aided in depicting the radiolytic yield of the solvated electron in these solvents as a function of time from picosecond to microsecond. The radiolytic yield in these viscous solvents is found to be strongly different from that of the water solution. The temperature dependent absorption spectra of the solvated electron in 12ED, 12PD, and 13PD have been also investigated. In all the three solvents, the optical spectra shift to the red with increasing temperature. While the shape of the spectra does not change in 13PD, a widening on the blue side of the absorption band is ...
2007-02-01
Thermal basis for disruption of operant behavior by microwaves in three animal species
Energy Technology Data Exchange (ETDEWEB)
A large variety of microwave producing devices are used in contemporary naval communications and weapons systems. Public and scientific concern about potential biological effects of microwave irradiation such as produced by these various devices requires documentations of such effects. Currently, the only well documented direct effect of microwaves is heating of the exposed organism. The present report is of a series of studies whose aim was to explore several microwave frequencies and their effect on performance and simultaneously to investigate the relationship to core heating in the exposed animals. Three difficult sized species of animals were used so that generalization to larger animals could be made. Rats, squirrel monkeys, and rhesus monkeys showed consistent effects of 60-minute exposures to microwaves when their body temperatures were increased at least 1 C above baseline temperatures. Performance was not reliably affected when body ...
1982-06-01
Field-induced valence transition of Eu(Pd{sub 1{minus}x}Pt{sub x}){sub 2}Si{sub 2}
Energy Technology Data Exchange (ETDEWEB)
The magnetic susceptibility and high-field magnetization have been measured for the intermediate valence system Eu(Pd{sub 1{minus}x}Pt{sub x}){sub 2}Si{sub 2} with 0{le}x{le}0.15. A first-order valence transition is observed for all the compounds under high field of 100 T at low temperatures. This valence transition is of first order accompanied with a large hysteresis, which is in contrast to a continuous valence change against temperature. Based on the interconfigurational fluctuation (ICF) model, the temperature- and field-induced valence transitions are discussed. It is found that a first-order valence transition can be induced by magnetic field, even if the system shows a continuous valence transition against temperature. Metamagnetic behavior at finite temperatures is also understood qualitatively by the ICF model. {copyright} {ital 1997} {ital The ...
1997-05-01
International Nuclear Information System (INIS)
High temperature fatigue crack growth (FCG) and creep crack growth (CCG) experiments have been conducted in air on weld metal, heat affected zone (HAZ) and base metal of the austenitic Alloy 800 and the nickel base Alloy 617. Tests were performed on specimens machined from pipes, in the temperature range 550-900 deg. C. The crack propagation mode was examined. At all temperatures and for both materials, FCG of base metal was found to be the highest, whereas the weld metal exhibited the lowest FCG rate. The FCG rate in the HAZ was found to lie in between of those observed for base and weld metal. The crack propagation mode remained transgranular in base metal and transdendritic in weld metal at all temperatures. CCG behaviour could be described using the energy rate integral C*. Base metal and weld metal exhibited similar CCG rate at same C*. The crack propagation mode under CCG ...
1993-08-15
Chemical-looping combustion of methane with CaSO{sub 4} oxygen carrier in a fixed bed reactor
Energy Technology Data Exchange (ETDEWEB)
Chemical-looping combustion is a promising technology for the combustion of gas or solid fuel with efficient use of energy and inherent separation of CO{sub 2}. Chemical-looping combustion of methane with calcium sulfate as a novel oxygen carrier was conducted in a laboratory scale fixed bed reactor. The effects of reaction temperature, gas flow rate, sample mass, and particle size on reduction reactions were investigated and an optimum operating condition was determined. The results show that this novel oxygen carrier has a high reduction reactivity and stability in a long-time reduction/oxidation test. The conversions of CH{sub 4} increased with a higher temperature, smaller gas flow rate, larger sample mass and smaller particle size. The suitable reaction temperature seems to be around 950 deg. C. Low temperatures lead to a low CH{sub 4} conversion, but a significant SO{sub 2} formation was ...
2008-11-15
Chemical-looping combustion of methane with CaSO{sub 4} oxygen carrier in a fixed bed reactor
Energy Technology Data Exchange (ETDEWEB)
Chemical-looping combustion is a promising technology for the combustion of gas or solid fuel with efficient use of energy and inherent separation of CO{sub 2}. Chemical-looping combustion of methane with calcium sulfate as a novel oxygen carrier was conducted in a laboratory scale fixed bed reactor. The effects of reaction temperature, gas flow rate, sample mass, and particle size on reduction reactions were investigated and an optimum operating condition was determined. The results show that this novel oxygen carrier has a high reduction reactivity and stability in a long-time reduction/oxidation test. The conversions of CH{sub 4} increased with a higher temperature, smaller gas flow rate, larger sample mass and smaller particle size. The suitable reaction temperature seems to be around 950 C. Low temperatures lead to a low CH{sub 4} conversion, but a significant SO{sub 2} formation was ...
2008-11-15
Energy Technology Data Exchange (ETDEWEB)
Eu 4f electronic structures of a temperature-induced valence transition system EuPd{sub 2}Si{sub 2} have been investigated by bulk-sensitive high-resolution photoemission spectroscopy at temperatures from 20 to 300 K. The bulk Eu{sup 2+} 4f component is definitely distinguished from two surface Eu{sup 2+} 4f components. The changes in the spectral intensity of the bulk Eu{sup 2+} and Eu{sup 3+} 4f configurations and in the energy separation between these states are observed in the temperature dependent photoemission spectra. These temperature dependences are related to the valence transition of EuPd{sub 2}Si{sub 2}. The Eu mean valence is evaluated to be 2.75{+-}0.03 at 20 K and 2.30{+-}0.05 at 300 K. These values are in good agreement with those evaluated from Moessbauer and Eu L{sub III}-edge X-ray absorption measurements.
2004-07-01
Understanding and predicting soot generation in turbulent non-premixed jet flames.
Energy Technology Data Exchange (ETDEWEB)
This report documents the results of a project funded by DoD's Strategic Environmental Research and Development Program (SERDP) on the science behind development of predictive models for soot emission from gas turbine engines. Measurements of soot formation were performed in laminar flat premixed flames and turbulent non-premixed jet flames at 1 atm pressure and in turbulent liquid spray flames under representative conditions for takeoff in a gas turbine engine. The laminar flames and open jet flames used both ethylene and a prevaporized JP-8 surrogate fuel composed of n-dodecane and m-xylene. The pressurized turbulent jet flame measurements used the JP-8 surrogate fuel and compared its combustion and sooting characteristics to a world-average JP-8 fuel sample. The pressurized jet flame measurements demonstrated that the surrogate was representative of JP-8, with a somewhat higher tendency to soot formation. The premixed flame measurements revealed that flame ...
2010-10-01
Synthesis and characterization of LiCo{sub y}Ni{sub (1-y)}VO{sub 4} lithium insertion materials
Energy Technology Data Exchange (ETDEWEB)
A family of mixed LiCo{sub y}Ni{sub (1-y)}VO{sub 4} (y=0.2, 0.5 and 0.8) compounds of potential use as high voltage cathode materials in lithium batteries, has been synthesized and characterized. The X-ray diffraction analysis showed that these compounds adopt an inverse spinel structure where in average 85% of the Ni{sup 2+} and Co{sup 2+} ions occupy octahedral sites and the other 15% occupy tetrahedral sites with the V{sup 5+} ions, although this occupation share is somewhat influenced by the preparation temperature. The annealing temperature plays also a key role in determining the particle size, as demonstrated by scanning electron microscope analysis. Cycling voltammetry tests showed that the lithium insertion-deinsertion process in the LiCo{sub y}Ni{sub (1-y)}VO{sub 4} electrode materials occurs reversibly around 4.3-4.4 V vs. Li, as also confirmed by cycling tests. The cycling capacity is somewhat modest; however, the ...
2000-02-01
Thermal transport during electron cyclotron heating in the TEXT tokamak
International Nuclear Information System (INIS)
Electron Cyclotron Heating experiments have been performed on the TEXT tokamak using Varian gyrotron. Some degradation of electron energy confinement is observed for sawtoothing and non-sawtoothing discharges. Sharp electron temperature profiles are produced in high-q discharges by extremely localized ECH power deposition.
1989-05-01
Temporal variations of radon in soil related to earthquakes
Energy Technology Data Exchange (ETDEWEB)
A radon detector with LR-115 nuclear track film was constructed for radon concentration measurements in soil. Temporal radon variations, as well as the barometric pressure, precipitation and temperature were measured for two years. Negative correlation between radon concentration in soil and barometric pressure was found. For some of the recorded earthquakes that occurred during the observation period, soil radon anomalies may be noticed one month before the quakes.
2001-08-01
Radon transport in an activated charcoal canister
Energy Technology Data Exchange (ETDEWEB)
The transport of Rn through activated charcoal was modelled for a charcoal canister used for surface emanation measurements. Derived Rn concentration distributions in full and half charcoal charges were compared with measured Rn profiles. The distributions were also compared with an empirical expression for the measured profiles. Close agreement was observed between the measured, empirically generated and derived profiles. The influence of temperature and humidity on Rn accumulation and transport is also discussed.
1989-02-01
Oscillations in radioactive exponential decay
Energy Technology Data Exchange (ETDEWEB)
Several older and recent reports provided evidence for the oscillatory character of the exponential decay law in radioactive decay and attempted to explain it with basic physics. We show here that the measured effects observed in some of the cases, namely in the decay of {sup 226}Ra, {sup 32}Si in equilibrium, and {sup 36}Cl, can be explained with the temperature variations.
2009-05-25
Energy Technology Data Exchange (ETDEWEB)
The effect of small misch metal additions (0.25 to 1 wt.%) on the corrosion behaviour of aluminium was studied through electrochemical polarization in 0.1 N inorganic and organic acids at room temperature. It has been observed that rare earth addition improves the corrosion resistance of aluminium. (orig.).
1992-10-01
Effect of ultrasonic energy on Mn-Zn ferrite powder behavior
Energy Technology Data Exchange (ETDEWEB)
Effect of ultrasonic-wave irradiation on the Mn-Zn ferrite powder suspension prepared by solid-state reaction and alcoholic dehydration methods was investigated. Size, distribution, and morphology of the powders prepared at different temperatures were examined, as a function of irradiation time. It was observed that the powders were reduced in size by ultrasonic energy through distinct routes. 8 refs., 7 figs., 1 tab.
1999-07-01
Density changes in amorphous Pd{sub 80}Si{sub 20} during low temperature ion irradiation
Energy Technology Data Exchange (ETDEWEB)
Density changes in amorphous Pd{sub 80}Si{sub 20} during ion irradiation below 100K were detected by in situ HVEM measurements of the changes in specimen length as a function of ion fluence. A decrease in mass density as a function of the ion fluence was observed. The saturation value of the change in mass density was determined to be approximately -1.2%.
1994-11-01
Boron uphill diffusion during ultrashallow junction formation
International Nuclear Information System (INIS)
The recently observed phenomenon of boron uphill diffusion during low-temperature annealing of ultrashallow ion-implanted junctions in silicon has been investigated. It is shown that the effect is enhanced by preamorphization, and that an increase in the depth of the preamorphized layer reduces uphill diffusion in the high-concentration portion of boron profile, while increasing transient enhanced diffusion in the tail. The data demonstrate that the magnitude of the uphill diffusion effect is determined by the proximity of boron and implant damage to the silicon surface.
2003-05-26
A new high-temperature solar research furnace
Energy Technology Data Exchange (ETDEWEB)
A new highly concentrating solar research furnace has recently been completed at the University of Minnesota. The experimentally observed flux concentration ratio, at small aperture, of a cavity receiver is about 7000. The furnace embodies features which may be of interest to others in the solar energy community. This paper describes its construction and performance.
1983-08-01
Swimming endurance of whiteleg shrimp, Litopenaeus vannamei exposed to various temperatures (15, 20, and 25 degrees C) and salinities (15, 32, and 40 per thousand) was determined in a swimming channel against one of five flow velocities (5.41, 6.78, 8.21, 10.11, and 11.47 cm s(-1)) for up to 9000 s. No shrimp swam the full 9000 s throughout the experiment. The swimming endurance decreased as swimming speed was increased at any of the temperatures and salinities tested and was significantly affected by temperature and salinity (Ppower model (nu x t(b) = a) showed a better fit to the relationship between swimming endurance (t, in s) and swimming speed (nu, in cm s(-1)) at any of the temperatures and salinities tested. The swimming ability index (SAI), defined as SAI = integral(0)(9000) vdt x 10(-4) (cm), was found to be temperature- and salinity-dependent in L. vannamei. The optimum ...
2006-11-29
Extension of improved particle and energy confinement regime in the core of LHD plasma
International Nuclear Information System (INIS)
Recent two major topics of Large Helical Device (LHD) towards fusion relevant conditions, high-density operation and high-ion-temperature operation, are reported. Super dense core plasma was obtained by the combination of repetitive hydrogen ice pellet injection and high power neutral beam injection (NBI) heating. A very peaked density profile with the highest central density of 1.1x1021 m-3 was produced showing that the particle transport was suppressed very well in the plasma core. The spatial density varies as the position of magnetic axis (Rax), and the steepest profile is obtained at Rax=3.95 m. The highest central ion temperature of 5.6 keV was obtained in hydrogen plasma at electron density of 1.6 x 1019 m-3 by NBI, where a peaked ion-temperature profile with internal ion energy transport barrier was observed. The profile of electron temperature did not change much and was ...
2009-06-01
Energy Technology Data Exchange (ETDEWEB)
The ability of residual biomass from the thermotolerant ethanol-producing yeast strain Kluyveromyces marxianus IMB3 to function as a biosorbent for uranium has been examined. It was found that the biomass had an observed maximum biosorption capacity of 120 mg U/g dry weight of biomass. The calculated value for the biosorption maximum, obtained by fitting the data to the Langmuir model was found to be 130 mg U/g dry weight biomass. Maximum biosorption capacities were examined at a number of temperatures and both the observed and calculated values obtained for those capacities increased with increasing temperature. Decreasing the pH of the biosorbate solution resulted in a decrease in uptake capacity. When biosorption reactions were carried out using sea-water as the diluent it was found that the maximum biosorption capacity of the biomass increased significantly. Using transmission electron microscopy, ...
1997-06-01
Wetland Trends in the Greater Buffalo Area, New York: 1980-2002
... upland development or destroyed during sand and gravel pit mining operations. Gains Increases in nonvegetated wetlands mainly through pond ... ...
SOFIA - Metadata - Historical Changes in Salinity, Water Quality...
will be derived from biochemical analyses of molluscs, ostracodes, foraminifera and corals. The corals will allow us to compare marine and estuarine trends, examine the linkage...
2011-08-27
Multifractal Fourier detrended cross-correlation analysis of traffic signals
Multifractal detrended cross-correlation analysis (MF-DXA) has been developed to detect the long-range power-law cross-correlation of considered signals in the presence of non-stationarity. However, crossovers arising from extrinsic periodic trends make the scaling behavior difficult to analyze. We introduce a Fourier filtering method to eliminate the trend effects and systematically investigate the multifractal cross-correlation of simulated and real traffic signals. The crossover locations are found approximately corresponding to the periods of underlying trend. Traffic velocity on one road and flows on adjacent roads show strong cross-correlation. They also present weak multifractality after periodic trends are removed. The traffic velocity and flow are cross-correlated in opposite directions which is accordant to their actual evolution.
2011-10-01
Electronic Warfare Technology - Trends and Visions
... I3a. -YPE OF REPORT T7b 7,ME COVEE 14 DATE OF REPORT (Year, Month. ... the addition of various materials to the standard flare in order to ...
1990-05-01
Costs of ambulatory care related to female pelvic floor disorders in the United States
UK PubMed Central (United Kingdom)
OBJECTIVETo evaluate trends in costs of ambulatory care related to female pelvic floor disorders (PFD) in the United States.STUDY DESIGNFull Text Available
2010-05-01
1 Title: Historic Emissions from Deforestation and Forest ...
on the range of available deforestation, forest degradation, ... Results: Deforestation estimates showed good agreement for multi-year trends of increasing ...
The effect of annealing parameter on corrosion resistance of Zircaloy-2
International Nuclear Information System (INIS)
The effects of equal #SIGMA#Ai for different combinations of the annealing temperature and annealing time on corrosion resistance and evolution of precipitates of Zircaloy-2 were investigated. Nodular corrosion resistance in the out-of-pile corrosion test was degraded with increasing #SIGMA#Ai only when it was increased by extending the annealing time at 894 K but did not depend on #SIGMA#Ai which was increased by raising the annealing temperature for a constant annealing time of 2.5 h. Extensive observation and micro-analysis of precipitates by analytical electron microscope (AEM) suggested the cause of degradation of nodular corrosion resistance to be the remarkable increase in volume fraction of Si-containing precipitates such as Zr_3Si and Zr_2Si, which were observed more frequently in large #SIGMA#Ai only when it was increased by extending the annealing time at 894 K. On the other hand, uniform ...
Energy Technology Data Exchange (ETDEWEB)
The investigated hybrid nanocomposite consists of a porous silicon template with electrochemically embedded Ni or Co nanostructures and offers magnetic characteristics which can be tailored by the electrochemical process parameters during fabrication. A twofold magnetic behaviour can be observed, a first one due to the spinmagnetism at magnetic fields below the saturation magnetization of the deposited metals and a second non-saturating term at higher fields (>1 T up to 7 T) above the saturation magnetization. In case of Ni deposited within the pores this non-saturating term shows a paramagnetic characteristic and follows exactly the Curie-Weiss law, whereas for Co/porous silicon samples the temperature dependent magnetization shows some deviations from the Curie Weiss law. In this high field region a difference in the temperature dependence between Ni and Co is observed whereas the ...
2009-10-15
The problem of homochirality is of crucial importance for the origins of Life. While most laboratory studies are focused on the search of physical and chemical sources of handedness in the Universe, they reflect only one aspect of the problem: the origin of homochiral biomolecules. At the same time, any space environments where biomolecules are expected to form and where they have to pass through before the first primitive forms of Life emerge, include strong irradiation or/and high temperatures. This automatically implies the possibility of losing the optical activity, i.e. racemization. The simulation experiments performed by our group deal with the following two aspects of amino acid abiotic chemistry: (1) amino acid pyrolysis associated with their extraterrestrial delivery; and (2) peptide formation from amino acids catalyzed by inorganic oxides. According to our observations, the racemization phenomena are very common in the systems ...
2001-01-01
On the temperature dependence of the magnetic excitations
International Nuclear Information System (INIS)
We compare experimental data for temperature dependence of the magnetic order parameter and the magnetic excitations (spin waves) in materials with a quenched orbital moment and a well-defined spin quantum number. It is observed that the thermal decrease of the two quantities proceeds according to the same analytical function of the type y(T)=1-cT"#epsilon# with an identical exponent #epsilon#. This power function applies not only asymptotically for T->0 but holds over a wide temperature range. The exponent #epsilon# is universal, i.e. independent of spin order type and lattice symmetry and depends only on the dimensionality of the relevant interactions and on whether the spin quantum number is integer or half-integer. The different T"#epsilon# functions are identified as representations of stable universality classes. The fact that order parameter and magnetic excitations follow the same T"#epsilon# function shows that ...
2005-07-15
Lubrication properties of molybdenum disulfide films deposited by RF sputtering method
Energy Technology Data Exchange (ETDEWEB)
A radio frequency sputtering apparatus with a pair of targets has been developed for depositing a film of uniform thickness onto a complex-geometric specimen such as the retainer of a ball bearing. The deposition characteristics of the apparatus were compared with those of the conventional sputtering apparatus. Lubrication properties of MoS/sub 2/ films made by these devices were also compared under a variety of conditions. Finally, friction and wear of MoS/sub 2/ films applied to angular-contact type ball bearings of 20 mm bore were studied in air, nitrogen and vacuo. The two-target sputtering has an advantage mentioned above. However, the films deposited by the method exhibited a rather short wear life because of the temperature rise of the substrate during ion bombardment and during the sputtering process. This temperature dependence was observed in films on those substrates that had been heated with a built-in heater ...
1986-01-01
Double umbrella structure in terbium iron garnet
International Nuclear Information System (INIS)
The umbrella magnetic structure of the terbium iron garnet (TbIG) has been studied using neutron diffraction experiments peformed in the 4.2 to 650 K temperature range which covers both the Neel temperature (Tsub(N) = 550 +- 10 K) and the compensation temperature (Tsub(comp) = 244 +- 2 K). When T > Tsub(N), the observed peak intensities originate from nuclear contribution only. When Tsub(comp) < T < Tsub(N), the results have been interpreted in the Neel theory of ferrimagnetism. Below Tsub(comp), three salient features have been observed: there appears superstructure lines forbiden by the cubic space group Ia3d, whereas the other superstructure peaks are found absent contrary to other heavy rare earth garnets; the strongest reflexion (110) vanishes near Tsub(comp). The magnetic modes associated to the rhombohedral symmetry space group R(-3)c have been calculated; the two ...
1984-04-10
Thermal Hydraulics Analysis for the 3MW TRIGA MARK-II Research Reactor Under Transient Condition
International Nuclear Information System (INIS)
Some important thermal hydraulic parameters of the 3 MW TRIGA MARK-II research reactor operating under transient condition were investigated using two computer codes PULTRI and TEMPUL. Major transient parameters, such as, peak power and prompt energy released after pulse, maximum fuel and coolant temperature, surface heat flux, time and radial distribution of temperature within fuel element after pulse, fuel, fuel-cladding gap width variation, etc. were computer and compared with the experimental and operational values as reported in the safety Analysis Report (SAR). It was observed that pulsing of the reactor inserting an excess reactivity of $2.00 shoots the reactor power level to 854.353 MW compared to an experimental value of 852 MW; the maximum fuel temperature corresponding to this peak power was found to be 846.76"o C which is much less than the limiting maximum value of fuel ...
1985-07-01
The specific heat capacity and thermal conductivity of normal liquid "3He
International Nuclear Information System (INIS)
By observing the diffusion of a heat pulse along a 10-cm column of normal liquid "3He with the aid of two vibrating wire thermometers, it has been possible to measure the heat capacity C and thermal conductivity K of the liquid in the temperature range from T /sub c/ to 10 mK and at pressures of 0.21, 4.39, 9.97, 20.01, and 29.32 bar. By using a Pt NMR thermometer, an LCMN thermometer, and a "3He melting curve thermometer calibrated using the melting curve given by Greywall in 1983, a temperature scale has been established and (1) it has been shown that this melting curve is consistent in the temperature range 5-22 mK with the Korringa law for the Pt thermometer with a Korringa constant of 29.8 +/- 0.2 sec mK, (2) departures have been observed from the Curie-Weiss law for LCMN at low temperatures, and (3) values of the superfluid transition ...
1986-01-01
Energy Technology Data Exchange (ETDEWEB)
In order to illustrate morphological features and variations of temperature in the upper thermosphere, we performed numerical simulations with a whole atmosphere general circulation model (GCM) for the solar minimum and geomagnetically quiet conditions in March, June, September, and December. In previous GCMs, tidal effects were imposed at the lower boundaries assuming dominant diurnal and semi-diurnal tidal modes. Since the GCM used in the present study covers all the atmospheric regions, the atmospheric tides with various modes are generated within the GCM. The global temperature distributions obtained from the GCM are in agreement with ones obtained from NRLMSISE-00. In addition, the GCM also represents localised temperature structures which are superimposed on the global day-night distributions. These localised structures, which vary from hour to hour, would be observed as variations with periods of ...
2010-07-01
Energy Technology Data Exchange (ETDEWEB)
Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO[sub 2] absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the [ital P] branch of the fundamental absorption band (2150--1950 cm[sup [minus]1]) while the CO[sub 2] vibrational-rotational lines were from the far wing of the [ital R] branch of the [nu][sub 3] fundamental band (2395--2380 cm[sup [minus]1]). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO[sub 2]/N[sub 2] gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak ...
1994-11-01
International Nuclear Information System (INIS)
Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO_2 absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the P branch of the fundamental absorption band (2150--1950 cm"-"1) while the CO_2 vibrational-rotational lines were from the far wing of the R branch of the #nu#_3 fundamental band (2395--2380 cm"-"1). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO_2/N_2 gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak overlap. Line strength measurements were made from the corrected ...
Suzaku and Optical Spectroscopic Observations of SS 433 in the 2006 April Multiwavelength Campaign
We report results of the 2006 April multi-wavelengths campaign of SS 433, focusing on X-ray data observed with Suzaku at two orbital phases (in- and out-of- eclipse) and simultaneous optical spectroscopic observations. By analyzing the Fe25 K_alpha lines originating from the jets, we detect rapid variability of the Doppler shifts, dz/dt ~ 0.019/0.33 day^-1, which is larger than those expected from the precession and/or nodding motion. This phenomenon probably corresponding to "jitter" motions observed for the first time in X-rays, for which significant variability both in the jet angle and intrinsic speed is required. From the time lag of optical Doppler curves from those of X-rays, we estimate the distance of the optical jets from the base to be ~(3-4) \\times 10^14 cm. Based on the radiatively cooling jet model, we determine the innermost temperature of the jets to be T_0 = 13 +/- 2 keV and 16 +/- 3 ...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
In order to clarify a mechanism of melt-jet breakup and fragmentation entirely different from the mechanism of stripping, a series of experiments were carried out by using molten tin jets of 100 grams with initial temperatures from 250degC to 900degC. Molten tin jets with a small kinematic viscosity and a large thermal diffusivity were used to observe breakup and fragmentation of melt jets enhanced thermally and hydrodynamically. We observed jet columns with second-stage large-scale structures generated by the coalescence of large-scale structures recognized in the field of fluid mechanics. At a greater depth, the segmentation of jet columns between second-stage large-scale structures and the fragmentation of the segmented jet columns were observed. It is reasonable to consider that the segmentation and the fragmentation of jet columns are caused by the boiling of water hydrodynamically entrained within ...
1999-07-01
The in-flight wavelength calibration for the Ozone Monitoring Instrument is discussed. The observed variability in the wavelength scale is two orders of magnitude larger than caused by temperature changes in the instrument. These wavelength variations are the result of rapid changes in time in the radiance levels during an individual observation in the presence of clouds or snow and ice. We have developed a data processing method to account and correct for these changes. In February 2005 this correction was implemented in the official data processing stream. We explain in detail how and how accurately this method works. Before correction, the error in the wavelength scale can be as much as a few tenths of a pixel; after correction it is mostly less than 1/100th of a pixel, which is the required preflight accuracy. This means that higher-level products such as the total column amounts of ozone, NO2, and SO2 are not ...
2006-05-01
Detection of H2 Emission from Mira B in UV Spectra from the Hubble Space Telescope
We present ultraviolet spectra of Mira's companion star from the Space Telescope Imaging Spectrograph (STIS) instrument on board the Hubble Space Telescope (HST). The companion is generally assumed to be a white dwarf surrounded by an accretion disk fed by Mira's wind, which dominates the UV emission from the system. The STIS UV spectrum is dominated by numerous, narrow H2 lines fluoresced by H I Ly-alpha, which were not detected in any of the numerous observations of Mira B by the International Ultraviolet Explorer (IUE). The high temperature lines detected by IUE (e.g., C IV 1550) still exist in the STIS spectrum but with dramatically lower fluxes. The continuum fluxes in the STIS spectra are also much lower, being more than an order of magnitude lower than ever observed by IUE, and also an order of magnitude lower than fluxes observed in more recent HST Faint Object Camera objective prism spectra ...
2001-01-01
Anisotropy of tensile properties of extruded magnesium alloy AZ31
Energy Technology Data Exchange (ETDEWEB)
The mechanical behaviour of wrought magnesium alloy AZ31 has been characterised by tensile testing at room temperature. Tests were carried out at various strain rates between 0.00003 s{sup -1} and 0.01 s{sup -1} on material which had been extruded to a bar of approximately 6 mm thick, and 80 mm wide. Specimens were machined from three orientations relative to the extrusion direction: parallel, perpendicular, and 45 from the extrusion direction. Significant variations of the properties were observed depending on the extrusion orientation and strain rate. At all strain rates the yield stress declined as the test orientation was rotated away from the extrusion direction. Parallel to the extrusion direction, the yield stress was found to increases markedly with increasing strain rate, whereas at 45 and 90 a lesser influence of strain rate was observed. The work hardening exponent was also influenced by the test orientation. ...
2003-07-01
Lean-burn engines UHC emission reduction
Energy Technology Data Exchange (ETDEWEB)
The effect of adding hydrogen to methane as a fuel for spark ignited engines has been extensively investigated. Both the possibility of adding a limited amount of hydrogen as well as equal amounts of hydrogen and carbon dioxide to natural gas has been investigated. A 10 vol% addition of hydrogen to the natural gas caused a reduction in UHC of approximately 40%, and an increase in efficiency of approximately three percentage points at the test engine. It is unknown if the gain is representative for large engines. Similar results for UHC reduction and efficiency were obtained for combined hydrogen and carbon dioxide addition. The carbon dioxide was added by exhaust gas recirculation. However, the price of hydrogen, makes this idea uneconomical even when carbon dioxide is readily available through recirculation of engine exhaust. Adiabatic prereforming may be used to convert natural gas into methane, hydrogen and carbon dioxide in order to generate hydrogen and at the same time increase ...
1999-04-01
Analysis of Thermally Induced Permeability Enhancement in Geothermal Injection Wells
Energy Technology Data Exchange (ETDEWEB)
Reinjection of spent geothermal brine is a common means of disposing of geothermal effluents and maintaining reservoir pressures. Contrary to the predictions of two-fluid models (two-viscosity) of nonisothermal injection, an increase of injectivity, with continued injection, is often observed. Injectivity enhancement and thermally-affected pressure transients are particularly apparent in short-term injection tests at the Los Azufres Geothermal Field, Mexico. During an injection test, it is not uncommon to observe that after an initial pressure increase, the pressure decreases with time. As this typically occurs far below the pressure at which hydraulic fracturing is expected, some other mechanism for increasing the near-bore permeability must explain the observed behavior. This paper focuses on calculating the magnitude of the near-bore permeability changes observed in several nonisothermal injection ...
1987-01-20
Energy Technology Data Exchange (ETDEWEB)
Nickel-titanium alloys may coexist in more than one crystalline structure. There is a high temperature phase, austenite, and a low temperature phase, martensite. The metallurgical basis for the superelasticity and the shape memory effect relies in the ability of these alloys to transform easily from one phase to another. There are three essential factors for the orthodontist to understand nickel-titanium alloys behaviour: stress; deflection; and temperature. These three factors are related to each other by the stress-deflection, stress-temperature and deflection-temperature diagrams. This work was undertaken with the objective to analyse commercial nickel-titanium alloys for orthodontics application, using the dynamical mechanical analyser - DMA. Four NiTi 0,017 X 0,025'' archwires were studied. The archwires were Copper NiTi 35 deg C (Ormco), Neo Sentalloy F200 ...
2002-07-01
Methods for evaluating long-term changes in thermal resistance of vacuum insulation panels
Energy Technology Data Exchange (ETDEWEB)
Vacuum insulation panels (VIP) offer excellent thermal resistance properties that can enhance the energy efficiency of insulating systems, save space and contribute to energy consumption reductions. However, VIPs are not used much in Canada, and new commitments to carbon dioxide reductions has created the need to study the prospect of using VIPs in various components of a building envelope. For that reason, assessment methods for the applicability and sustainability of VIPs for use in building envelope construction were developed. There are practical aspects regarding the long-term performance and application of VIPs in building construction. Air molecules and water molecules can permeate through the foil and seams of the VIPs, causing a reduction in thermal resistance. This paper addresses some of the test methods that may accelerate long term changes in thermal resistance. Results were presented from tests using elevated pressure, relative humidity and ...
2005-07-01
Ultrastructural effect of gamma radiation on grass shrimps (Penaeus monodon Fabricius)
Energy Technology Data Exchange (ETDEWEB)
The effect of ionizing radiation (2, 5, and 10 KGy of gamma rays) on muscle ultrastructure of grass shrimps (Penaeus monodon Fabricius) tails at ambient or frozen (-18{sup 0}C) temperature was investigated by transmission electron microscopy (TEM). No significant change was found in muscle ultrastructure of shrimp meat irradiated at doses of 2 or 5 KGy and then stored at 4{sup 0}C for 0 and 8 days. However, in shrimps which were irradiated at ambient temperature at a dose of 10 KGy, the margin of A-band of the myofibrils in longitudinal sections exhibited an irregular zig-zag pattern. In cross section some myosin filaments in the A-band regions were missing. A possible interpretation of these results would be that 10 KGy gamma irradiation dose at ambient temperature depolymerized myosin in the A-band from the tail of thick filament. Actin damage was also observed in some cross sections. Irradiation ...
1990-01-01
Ultrastructural effect of gamma radiation on grass shrimps (Penaeus monodon Fabricius)
International Nuclear Information System (INIS)
The effect of ionizing radiation (2, 5, and 10 KGy of gamma rays) on muscle ultrastructure of grass shrimps (Penaeus monodon Fabricius) tails at ambient or frozen (-18"0C) temperature was investigated by transmission electron microscopy (TEM). No significant change was found in muscle ultrastructure of shrimp meat irradiated at doses of 2 or 5 KGy and then stored at 4"0C for 0 and 8 days. However, in shrimps which were irradiated at ambient temperature at a dose of 10 KGy, the margin of A-band of the myofibrils in longitudinal sections exhibited an irregular zig-zag pattern. In cross section some myosin filaments in the A-band regions were missing. A possible interpretation of these results would be that 10 KGy gamma irradiation dose at ambient temperature depolymerized myosin in the A-band from the tail of thick filament. Actin damage was also observed in some cross sections. Irradiation damage of ...
The nucleation kinetics of calcium sulfate dihydrate in NaCl solutions up to 6 m and 90 C
Energy Technology Data Exchange (ETDEWEB)
The crystallization of calcium sulfate from aqueous solutions with NaCl is both geological and industrial interest because NaCl is the dominant solute in natural brines and many industrial fluids. Induction periods for the nucleation of calcium sulfate dihydrate were experimentally determined as a function of supersaturation in NaCl solutions from 0 to 6 m at 25 C and in 3.0-m NaCl solutions at temperatures from 25 to 90 C. Using classic nucleation theory, the interfacial tension between gypsum and 3.0-m NaCl solution was estimated to be about 39 mJ/m[sup 2] at 25 C and increases with increasing temperature (to 63 mJ/m[sup 2] at 90 C). It was observed that the induction period decreases with increasing NaCl concentrations up to 3 m and then starts to increase slightly at a given temperature and saturation state. The electrolyte effect on nucleation was proportional to the enhanced solubility of calcium ...
1994-02-01
Study of transformation behavior in a Ti-4.4 Ta-1.9 Nb alloy
International Nuclear Information System (INIS)
An alloy of composition Ti-4.4 wt.% Ta-1.9 wt.% Nb is being developed as a structural material for corrosion applications, as titanium and its alloys possess excellent corrosion resistance in many oxidizing media. The primary physical metallurgy database for the Ti-4.4 wt.% Ta-1.9 wt.% Nb alloy is being presented for the first time. Determination of the #beta# transus, M_s temperature and classification of the alloy have been carried out, employing a variety of microscopy techniques, X-ray diffraction (XRD), micro-hardness and differential scanning calorimetry (DSC). The #beta# transition temperature or #beta# transus determined using different experimental techniques was found to agree very well with evaluations based on empirical calculations. Based on chemistry and observed room temperature microstructure, the alloy has been classified as an #alpha# + #beta# titanium alloy. The high ...
2005-01-15
Paramagnetic susceptibility of nonstoichiometric fluorides with the fluorite-type structure
Energy Technology Data Exchange (ETDEWEB)
Magnetic properties of single crystals of nonstoichiometric fluorides M[sub 1-x]R[sub x]F[sub 2+x] (M = Ca, Sr, Ba; R = Ce, Pr, Nd, Gd, Ho, Er, Tm, Yb; with 0.05 [le] x [le] 0.28) with the fluorite-type structure have been studied for the first time. The magnetic susceptibility was measured using a Faraday balance in the 15-300 K temperature range. The samples are paramagnetic following the Curie-Weiss law. The values of paramagnetic Curie temperatures and effective magnetic moments of rare-earth ions have been found. Deviations of the temperature dependence of magnetic susceptibility from the Curie-Weiss law are observed for some nonstoichiometric fluorides at temperatures ranging from 60 to 85 K. Possible reaons for these deviations are discussed. Measurements of magnetic susceptibility provide an effective technique for a rapid and accurate determination of the concentration of ...
1993-01-01
Energy Technology Data Exchange (ETDEWEB)
Fine-grained AZ31 magnesium alloy sheets were prepared through hot rolling process. The superplastic properties of hot-rolled AZ31 Mg alloy was examined by uniaxial tensile tests at a temperature range 250{proportional_to}450 C and strain rate range 0.7 x 10{sup -3}{proportional_to}1.4 x 10{sup -1} s{sup -1}. Optical and scanning electronic microscope (SEM) were used to observe the microstructure evolution and fracture behavior in superplastic deformation of AZ31 Mg alloy and the values of deformation activation energy at various temperatures were calculated. It is demonstrated that, the hot-rolled AZ31 alloy begins to exhibit superplasticity from 300 C and a maximum elongation of 362.5% is obtained at 400 C and 0.7 x 10{sup -3} s{sup -1}. In the temperature range 300{proportional_to}400 C, the dominant superplastic deformation mechanism is grain boundary sliding (GBS) controlled by grain boundary ...
2005-07-01
Isotope exchange reaction between tritiated water and hydrogen on SiC
Energy Technology Data Exchange (ETDEWEB)
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical ...
2003-11-15
Isotope exchange reaction between tritiated water and hydrogen on SiC
International Nuclear Information System (INIS)
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve ...
2003-11-15
Energy Technology Data Exchange (ETDEWEB)
The effective electron mobility was measured as a function of surface field in polysilicon thin film transistors having the following three types of gate dielectrics; silicon dioxide deposited by low temperature (350degC) plasma-enhanced chemical vapor deposition (PECVD), low temperature (400degC) nitrogen-rich PECVD silicon nitride and high temperature (1050degC) thermally grown silicon dioxide. At low surface fields, the maximum true effective electron mobility was 40[+-]3 cm[sup 2] V[sup -1] s[sup -1] in all devices independent of the type of gate dielectric, indicating that the quality of the interface is the same. However, at high surface fields a stronger degradation of the mobility was observed in devices having the thermally grown silicon dioxide as gate dielectric, indicating the presence of surface roughness within the interfacial region. The polysilicon structure was studied by transmission ...
1992-08-28
Hydrogen synthesis via combustion of fuel-rich natural gas/air mixtures at elevated pressure
Energy Technology Data Exchange (ETDEWEB)
Combustion of extremely fuel-rich ({phi}=4) methane/air mixtures at elevated pressures is investigated as a potential means to generate molecular hydrogen by non-catalytic partial oxidation. This system is investigated both computationally and experimentally. The computations use a perfectly-stirred reactor model and an explicit methane cool-flame mechanism to investigate the effects of reactor parameters on reaction time and product composition. Under adiabatic conditions, such mixtures are predicted to autoignite at low temperatures {approx}700 K for pressures exceeding 8.5 atm. Above 15 atm, conversion to products is complete in roughly 1 s. The dependence of reaction time and hydrogen yield is investigated as a function of inlet temperature, system pressure, and flame equivalence ratio. Actual product yields are measured in a tube reactor facility, and many of the predictions of the model, including long relaxation times to chemical ...
2005-07-01
High temperature deformation behavior of AZ31 Mg alloy
Energy Technology Data Exchange (ETDEWEB)
High temperature deformation behavior of AZ31 Mg alloy was investigated in this study on the basis of a processing map ({epsilon} {approx} 0.6). To construct a processing map, compression tests were carried out at various temperatures and strain rates. Two regions of high deformation efficiency ({eta}) were identified as: (1) a dynamic recrystallization (DRX) domain at 250 C and 1/s and (2) a superplasticity domain at 450 C and 10{sup -4}/s. The average grain size observed in the DRX region was considerably smaller (2.9{mu}m) than in any other region. In the superplastic condition, tensile elongation to failure approached to 1040%. At the high Z regions, flow softening occurred resulting from the dynamic recrystallization but below 10{sup 10} of Z value, flow hardening occurred due to the grain growth. Possible deformation mechanisms operating at high temperature were discussed in relation to the ...
2005-07-01
Hardening by point defects in neutron irradiated AlN and SiC
International Nuclear Information System (INIS)
Pressureless-sintered AlN and hot-pressed, pressureless-sintered and reaction-bonded SiC were neutron irradiated at temperatures between 100 and 785degC up to a fluence of 5.2 x 10"2"4 n/m"2. The hardness was increased by up to 51% in AlN and 84% in SiC. The hardness decreased after annealing at temperatures around the irradiation temperature. At the same temperatures, the macroscopic length, which was increased by irradiation, also began to decrease. The hardness and length were almost recovered after 1,200 #approx# 1,400degC annealing. Thus, hardening in irradiated AlN and SiC is controlled by the number of point defects, or, more precisely, by the strain caused by small point defect clusters which pin down dislocation movement. Dislocation loops were still observed in some samples after 1,400degC annealing while the hardness was almost recovered to that in the unirradiated state. ...
DEFF Research Database (Denmark)
We present an experimental study of vesicle fusion using light and neutron scattering to monitor fusion events. Vesicles are reproducibly formed with an extrusion procedure using an single amphiphile triethylene glycol mono-n-decyl ether in water. They show long-term stability for temperatures around 20 C, but at temperatures above 26 C we observe an increase in the scattered intensity due to fusion. The system is unusually well suited for the study of basic mechanisms of vesicle fusion. The vesicles are flexible with a bending rigidity of only a few k(H)T. The monolayer spontaneous curvature, Ho, depends strongly on temperature in a known way and is thus tunable. For temperatures where H-0 > 0 vesicles tyre long-term stable, while in the range H-0 < 0 the fusion rate increases the more negative the Spontaneous curvature Through a quantitative;analysis of the fusion rate we ...
2010-01-01
Flux pinning and critical currents in A-15 superconductors
The relationship between processing, microstructure, and properties was studied for A-15 compounds in multifilamentary composites produced by solid-state diffusion and in thin-film samples produced by vapor deposition. Grain sizes of A-15 superconducting compounds were measured by transmission electron microscopy of multifilamentary composites reacted at various temperatures. Critical current densities at 4.2 K and fields up to 6 T were found to be similar for niobium-tin, vanadium-gallium, and vanadium-silicon of the same grain size. Study of the Cu-V-Si phase diagram led to the production of improved multifilamentary vanadium-silicon conductors. The effects of various alloying elements on A-15 layers produced by solid-state diffusion were studied. The most promising new observation was that tantalum can be incorporated into niobium-tin reaction layers, leading to an enhancement of critical currents at high fields. The critical ...
1978-02-01
Energy Technology Data Exchange (ETDEWEB)
With relation to the coals delivered as common samples in the coal fundamental technology development project, an experimental study was conducted on agglomeration characteristics and reaction characteristics in the fluidized-bed coal gasifier. For the experiment, used was a fluidized bed gasifier inserted with a cone-shape dispersion plate with a nozzle in the center. After raising the temperature of the gasifier up to 773K, gasification was conducted sending to the gasifier air from the nozzle and steam from the dispersion plate. The mean particle diameter and gas concentration of chars were measured till the temperature reaches 1373K. As a result of the experiment, it was confirmed that the carbon conversion ratio increases with a decrease in coalification degree of the coal. Moreover, influence of the coal kind was markedly observed at the grid zone of the lower part of the bed, and it was clarified that the lower ...
1996-10-28
Future of the Japanese steel industry and a suggestion to the Canadian coal industry
Energy Technology Data Exchange (ETDEWEB)
Discussion is presented of world crude steel production, the Japanese steel industry and its expectations of the Canadian coal industry. It is concluded that the Canadian coal industry should pay attention to the trend in customer's requirements regarding coal quality, maintain price competitiveness in the international market place, and remain flexible with regard to the market trend.
1989-01-01
Cause trending analysis for licensing operational events in Daya Bay Nuclear Power Station
International Nuclear Information System (INIS)
The human causal factors for all human error licensing operational events on Daya Bay nuclear power station since 1993 to 2003 are categorized, the trend of these causal factors is analyzed. The emphasis is placed on analyzing the deficiencies on complying with and executing regulations and procedures. The results provide directional reference for nuclear power station to improve human performance. (author)
2005-09-01
Assessing the Risks of Sampling Rates for Surveilling a Population
British Library Electronic Table of Contents (United Kingdom)
Surveillance of a population, such as a weapon stockpile, is needed to discover manufacturing defects as well as deterioration as the population ages. This article considers the risks of sampling rates for surveillance from three perspectives: detection probability of defects in a proportion of a population with pass/fail data, detection of a trend in a defective proportion of the population with pass/fail data, and detection of a trend with quantitative degradation measurements. Understanding of these risks will help the decision maker choose a sampling rate to protect against such problems of a specified size at a tolerable risk.
2011-01-01
Exploration petrology of Sunoco Felda trend of south Florida
Energy Technology Data Exchange (ETDEWEB)
The Sunoco Felda oil trend of the South Florida basin has been a prolific oil producer. All the oil is produced from the Cretaceous Sunniland formation, a leached limestone bioherm. Although the producing section has been considered reefal in the literature, petrographic and biostratigraphic analyses of various cores in producing fields have determined that these deposits are composed of particles of fragmented rudist and other fauna deposited in a tidal shoal. Atop this debris an algae and gastropod section has been deposited, typical of a mound deposited on a tidal mud flat. This model is exemplified in the Sunoco Felda and West Sunoco fields and was used in exploring the Sunoco Felda trend. From the petrological analysis of these two fields and from knowledge of other wells in the basin, biostratigraphic and lithologic trends can be determined and extended offshore into the eastern Gulf of Mexico. The author stresses ...
1986-09-01
DEFF Research Database (Denmark)
B vitamins and polymorphisms in genes coding for enzymes involved in one-carbon metabolism may affect DNA synthesis and methylation and thereby be implicated in carcinogenesis. Previous data on vitamins B2 and B6 and genetic polymorphisms other than those involving MTHFR as risk factors for gastric cancer (GC) are sparse and inconsistent. In this case-control study nested within the European Prospective Investigation into Cancer and Nutrition cohort, cases (n = 235) and controls (n = 601) were matched for study center, age, sex, and time of blood sampling. B2 and B6 species were measured in plasma, and the sum of riboflavin and flavin mononucleotide was used as the main exposure variable for vitamin B2 status, whereas the sum of pyridoxal 5'-phosphate, pyridoxal, and 4-pyridoxic acid was used to define vitamin B6 status. In addition, we determined eight polymorphisms related to one-carbon metabolism. Relative risks for GC risk were calculated with conditional logistic regression, ...
2010-01-01
SGTR Project: Separate Effect Studies for Vertical Steam Generators
Energy Technology Data Exchange (ETDEWEB)
The SGTR project has been carried out within the fifth EURATOM Framework Programme (Contract No FIKS-CT-1999-0007). Its main objective was to provide an experimental database and to develop and/or verify models to support definition of accident management measures in the hypothetical case of a Steam Generator tube Rupture (SGTR) sequence. The project addressed both vertical and horizontal steam generator designs. This report summarises the main results obtained in the intermediate scale experimentation that addressed Western type steam generators. The specific goal of this test programme was to investigate aerosol retention in the break stage of the secondary side of a water-empty steam generator. The test matrix consisted of 12 tests that explored the influence of variables such as break type and orientation and inlet gas flow rate. This work was performed in the PECA facility of the Laboratory for Analysis of Safety Systems (LASS). Aerosol retention at the break stage of a dry steam ...
2003-07-01
International Nuclear Information System (INIS)
Reactive Magnetron Sputtering is a complex process and huge efforts are made addressing the understanding of its fundamental phenomena and the simulation of the deposition process by e.g. Particle in Cell/Monte Carlo (PIC/MC). One of the most uncertain parameters in this reactive sputtering process is the incorporation coefficient of the reactive gas in the growing layer, i.e. the real-time sticking coefficient during deposition. In this work, mass spectrometry is used to deliver more insights on this complex matter. Earlier, a method was developed to determine the incorporation coefficient of the reactive gas molecules in the growing metal film, using mass spectrometry combined with thin film analysis techniques (electron probe microanalysis and x-ray photoelectron spectroscopy). This method delivers a global, realistic incorporation coefficient which can be used in models for the reactive sputtering process. In this work, new insights have been added to the classical method. As ...
2009-12-31
Energy Technology Data Exchange (ETDEWEB)
The grey-black mudstones of the Sonehat Formation form part of the Middle Jurassic fill of the Jameson Land Basin in East Greenland. The formation is exposed in the southernmost part of the north south-trending, Mesozoic rift system in East Greenland that was part of the epeiric seaway betaveen East Greenland and Norway. Sedimentological observations of the Sortehat Formation indicate deposition in an offshore marine setting that was typically low energy and periodically oxygen-deficient but was influenced by storm currents on occasion. Detailed palynological studies of the Sortehat Formation have resulted in the definition of theee palynological assemblage zones recognised at four localities, namely Enhjoerningen Dal and Pelion (north Jameson Land), the type section at Sortehat (central Jameson Land) and Albuen at Neill Klinter along Hurry Inlet (south-east Jameson Land). In stratigraphic order, these zones are termed the Botryococcus ...
2003-07-01
Measurement of the L sub 2 - L sub 3 Coster-Kronig transition probability in Tm( Z =69)
Energy Technology Data Exchange (ETDEWEB)
The {ital L}{sub 2}-{ital L}{sub 3} Coster-Kronig transition probability ({ital f}{sub 23}) in Tm was measured by multiparameter {ital K} versus {ital L} x-ray coincidence techniques. The Tm x rays were obtained from a radioactive source of {sup 169}Yb and were detected with cooled germanium and silicon detectors of high-energy resolution. Corrections were applied for the contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak and for the contribution of unresolved {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak. The contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak was determined solely from the results of the coincidence measurements using a method of data analysis which was previously described elsewhere. The contribution of {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak was determined from the coincidence measurements and published values of the {ital L}{eta} to {ital L}{beta}{sub ...
1989-11-01
Measurement of the L sub 2 - L sub 3 Coster-Kronig transition probability in Tm( Z =69)
The {ital L}{sub 2}-{ital L}{sub 3} Coster-Kronig transition probability ({ital f}{sub 23}) in Tm was measured by multiparameter {ital K} versus {ital L} x-ray coincidence techniques. The Tm x rays were obtained from a radioactive source of {sup 169}Yb and were detected with cooled germanium and silicon detectors of high-energy resolution. Corrections were applied for the contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak and for the contribution of unresolved {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak. The contribution of {ital K}{alpha}{sub 1} x rays to the {ital K}{alpha}{sub 2} x-ray peak was determined solely from the results of the coincidence measurements using a method of data analysis which was previously described elsewhere. The contribution of {ital L}{eta} x rays to the {ital L}{alpha}{sub 1,2} x-ray peak was determined from the coincidence measurements and published values of the {ital L}{eta} to {ital L}{beta}{sub ...
1989-11-01
International Nuclear Information System (INIS)
Purpose: To analyze p53, bcl-2, c-myc, and cyclooxygenase-2 protein expression changes and examine their relationship with various antioxidant enzymes in esophageal carcinoma patients. Methods and Materials: Patients in Group 1 underwent transhiatal esophagectomy and those in Group 2 were administered chemoradiotherapy followed by surgery after 4 weeks of neoadjuvant therapy. Results: The relationship analysis among the various protein markers and antioxidant enzymes showed an inverse correlation between bcl-2 and superoxide dismutase/catalase in tumor tissues, irrespective of the treatment arm followed. An important positive association was observed between bcl-2 and reduced glutathione levels in the tumor tissue of patients receiving neoadjuvant therapy. Another apoptosis-modulating marker, c-myc, in the tumor tissue of Group 2 patients showed similar pattern levels (high and low) as that of superoxide dismutase/catalase. The association of cyclooxygenase-2 and ...
2008-02-01
International Nuclear Information System (INIS)
Environmental Survey Laboratory at Tarapur, Maharashtra site carries out environmental radioactivity measurements in different matrices to evaluate the impact of operating nuclear installations. In this paper, the evaluation of data of 1983-2007 (25 years) is presented. Time trends of particulate radioactivity, correlation between "1"3"7Cs in discharge canal seawater and station discharged activity and correlation of "1"3"7Cs, "6"0Co, and "1"3"1I in marine species like Sponge and Nerita and corresponding discharged activity were carried out. Statistical analysis of environmental data of seawater and marine fish for several radionuclides, for distributions, showed that the data best fits lognormal distribution. A strong correlation between "1"3"7Cs in seawater and "1"3"7Cs in liquid waste discharge was observed (R"2 = 0.8, P = 0.000). Similarly correlation was very good for Nerita and discharged concentration for "1"3"7Cs, "1"3"1I and "6"0Co ...
2008-07-16
Historical trends in the accumulation of chemicals in Puget Sound sediment
International Nuclear Information System (INIS)
As human activity in and around Puget Sound increased, so did the contaminant levels in the sediment. Sediment cores collected in 1 982 revealed inputs of chemicals to the Sound, including lead (Pb), mercury (Hg), silver (Ag), copper (Cu) and petroleum hydrocarbons, began to increase above background in the late 1800s and peaked between 1945 and 1965. Synthetic organic compounds, such as polychlorinated biphenyls (PCBs) and DDT, first appeared in sediments deposited in the 1930s and reached a maximum in the 1960s. The presence of the subsurface maximum concentrations suggests that pollution-control strategies have improved the sediment quality of central Puget Sound. Additional sediment coring was performed in 1991 and samples were collected at six locations in the main basin of Puget Sound. Sediment ages were determined using Pb"2"1"0 radio isotope dating. Sedimentation rates were approximately 1 to 2 cm/yr and deposition rates ranged from 480 to 1000 mg/cm2/yr. The contaminant level ...
1995-11-05
High pressure waterjets for oil containment in calm and wavy waters; a parametric study
International Nuclear Information System (INIS)
The use of high pressure waterjets (HPWJ) as oil barriers has been proposed and tested. It has been shown that a series of waterjets directed horizontally above the free water surface provide an effective means of containing or deflecting oil slicks. The waterjets generate a high speed air flow capable of moving the surface layer of the liquid. A numerical model is implemented to study the characteristics of the entrained turbulent air flow using the Spectral Element Method (SEM) and an algebraic turbulent model for the Reynolds stresses. A test of the code is done for turbulent Couette Flow to check the accuracy of the calculated shear stresses against published data. A parametric study is performed to evaluate the HPWJ system performance at various operating and design parameters which include manifold pressure, nozzle flow rate, nozzle characteristics, jet height and surface wave conditions. The total driving shear force and power required for effective containment are used as ...
1994-01-01
Effective didactic skills training for teachers in continuing medical education
International Nuclear Information System (INIS)
Purpose: To develop, test, evaluate and implement effective state-of-the-art teacher training in didactic skills and methods. The training concept should be designed and beneficial for medical teachers' postgraduate medical education (CME). Materials and methods: A 5-day workshop with 12 theoretical and 9 'hands-on' modules was designed and stepwise improved, according to the trainees' feedback. All trainees were trained in small groups (6 to 10 participants per workshop). The workshops consisted of mini-lectures, repeated micro teaching exercises and video-supported feedback concerning the following key-competencies: Communication of goals; methods to trigger interactivity; design of slides in power point presentations; effective feedback-techniques; and use of media, time-management, skills teaching, assessment methods (e.g. OSCE and others), evaluation and general presentation skills. The evaluation was based on two components: (A) trainees' scores in two objective structured ...
2005-09-01
Cosmological condensation of scalar fields: Making a dark energy
Our Universe is ruled by quantum mechanics and its extension quantum field theory. However, the explanations for a number of cosmological phenomena such as inflation, dark energy, symmetry breakings, and phase transitions need the presence of classical scalar fields. Although the process of condensation of scalar fields in the lab is fairly well understood, the extension of results to a cosmological context is not trivial. Here we investigate the formation of a condensate--a classical scalar field--after reheating of the Universe. We assume a light quantum scalar field produced by the decay of a heavy particle, which for simplicity is assumed to be another scalar. We show that during the radiation domination epoch under certain conditions, the decay of the heavy particle alone is sufficient for the production of a condensate. This process is very similar to preheating--the exponential particle production at the end of inflation. During the matter domination epoch when the expansion of ...
2010-05-15
de Haas--van Alphen effect and Fermi surface of lutetium
International Nuclear Information System (INIS)
We report de Haas--van Alphen measurements of the Fermi surface of lutetium at temperatures down to 0.3 K and in fields up to 150 kG in the (1010) and (1120) planes. Lutetium, having a filled 4f shell, serves as a nonmagnetic prototype of the structurally similar (hcp), trivalent, heavy rare-earth elements from Gd to Tm. The fact that no complete frequency branches were observed indicates that there are no closed pieces of the Fermi surface. We observed all but one orbit predicted by relativistic augmented-plane-wave calculations of Keeton and Loucks and by recent spin-orbit--linearized-augmented-plane-wave calculations of Tibbetts and Harmon. The data support a geometry similar to that of yttrium, and in good qualitative agreement with energy-band theory.
International Nuclear Information System (INIS)
We have fabricated nanometer-spaced electrodes on electron-transparent silicon nitride membranes. A thin Cr/Au layer is evaporated on the backside of the membrane which serves as a gate electrode. Using these devices, we have performed three-terminal electron transport measurements on gold nano-particles at liquid helium temperature. Coulomb Blockade features have been observed and the capacitance to the gate has been extracted. After transport measurements, the Cr/Au back gate is removed and the devices are inspected with a transmission-electron microscope (TEM). TEM inspection reveals the presence of a few nano-particles in the nanogap, which is in agreement with the transport measurements. In addition, the nano-particle size as observed by TEM coincides with the one estimated from the gate capacitance value.
2009-10-14
Energy Technology Data Exchange (ETDEWEB)
The elastic behaviour of YBaCuO specimens has been studied by very low-frequency isothermal internal-friction measurements. A relaxation peak is observed which is attributed to oxygen atom jumps, between A(1/2 0 0) and B(0 1/2 0) sites, in the CuO planes of the orthorhombic phase. A limit relaxation time {tau}{sub 0}, 2.6 {center dot} 10{sup -15}s, and an activation energy, 1.3eV, have been obtained from the shift of the maximum damping frequency observed when the measurement temperature is changed. The proposed values for the limit relaxation time and the activation energy are in good agreement with those previously proposed in the literature.
1992-02-07
Structure and properties of Li2Zn2(MoO4)3 crystals activated with copper and chromium ions
British Library Electronic Table of Contents (United Kingdom)
Based on the corrected phase diagrams proper growth conditions for Li2Zn2(MoO4)3 crystals are selected. Large crystals (up to 100 mm), both impurity-free and activated by transition metal ions (Cu, Cr), are grown by the low-gradient Czochralski method. By the EPR method the charge state and structural position of copper and chromium ions are determined. The performed studies of luminescent properties show that for impurity-free crystals luminescence with ? = 388 nm with a two-exponential luminescence decay with ?1 = 2 ns and ?2 = 6 ns is observed at room temperature. At 77 K for both impurity-free crystals and those activated with transition metal ions luminescence with ? = 560 nm and the luminescence lifetime ? = 100 ns is observed, the intensity of luminescence with ? = 560 nm depending ...
2011-01-01
International Nuclear Information System (INIS)
Defect cluster formation in 14-MeV neutron irradiated polycrystalline copper has been observed by transmission electron microscopy (TEM) and correlated with the increase in yield stress. The measurements indicate that the radiation hardening component of the yield strength in polycrystals is not directly additive to the unirradiated yield strength. A transitional behavior was observed for radiation hardening at low fluences, which produces an anomalous variation of the defect cluster barrier strength with fluence. The behavior is attributed to the effect of grain boundaries on slip band transmission. An upper limit for the room temperature barrier strength of defect clusters in neutron-irradiated copper was determined to be #alpha#=0.23. (orig.).
1989-12-04
Peel-off case failure in thermal explosions observed by the deflagration cylinder test
British Library Electronic Table of Contents (United Kingdom)
We have discovered a previously unidentified thermal explosion mode using the Los Alamos deflagration cylinder test (DFCT). The DFCT is a "pipe bomb"-style test similar to the detonation cylinder test (DTCT), which has been used for many years to calibrate detonation product equations of state. The shot is heated in an oven to a uniform test temperature. The pre-heated high explosive (HE) is triggered by a hot wire initiator on one end. The tube is back-illuminated by a bright light source, and its combustion-driven deformation and subsequent break-up are observed by a high-speed framing camera. Like the DTCT, the DFCT tube wall motion provides the primary diagnostic. A variety of reactive responses are possible, including quasi-steady deflagration and deflagration-to-detonation transition...
2009-01-01
OBSERVATION OF NUCLEAR PARTICLE TRACKS IN THE ELECTRON MICROSCOPE
A fine-grained photosensitive layer was prepared for electron- microscopic radioautography. The layer was obtained by evaporating Ag at low pressure and temperature on electron microscope grids and sensitizing the silvered grids with Br/sub 2/. The resulting particles had an average diameter of -- 100 A. The sensitivity of the layer to ionizing radiation was tested by sprinkling the grids with fine uranium aeetate particles and examining the processed grids in an electron microscope. Shont tracks and side spurs were observed which are probably due to alpha radiation from U/sup 235/ and secondary electrons scattered from the silver, respectively. Tests with P/sup 32/- phosphate are also described. (D.L.C.)
1962-08-01
Microstructure characterization and tensile properties of b phase containing TiAl pancake
British Library Electronic Table of Contents (United Kingdom)
The microstructure and tensile properties of Ti-44Al-6V-3Nb-0.3Y (at.%) alloy after canned forging were investigated. SEM results showed that the TiAl pancake exhibits inhomogeneous microstructure, which can be ascribed to the temperature drop and friction between billet and outer pack during forging, as well as the intrinsic anisotropy of lamellar colony. By means of TEM observation and EBSD analysis, the microstructure in the dominant area of the pancake was further characterized. This deformation area consists of 87.7% content of g grains plus some refined lamellar colonies and the rest of B2 grains. The grain size ranges between 1mm and 8.5mm. High-angle boundaries dominate the deformation microstructure, several substructures and twins are observed as well. Additionally, current forge...
2011-01-01
Magnetic layer formation on plasma nitrided CoCrMo alloy
British Library Electronic Table of Contents (United Kingdom)
In this study structural and magnetic character of the expanded austenite phase (gN) layer formed on a medical grade CoCrMo alloy by a low-pressure Radio-Frequency plasma nitriding process was investigated. The formation of the expanded austenite phase is facilitated at a substrate temperature near 400^oC for 1, 2, 4, 6 and 20h under a gas mixture of 60% N2-40% H2. The magnetic state of the gN layers was determined by a surface sensitive technique, magneto-optic Kerr effect (MOKE), and with a scanning probe microscope in magnetic force mode (MFM). Strong evidence for the ferromagnetic nature of the gN-(Co,Cr,Mo) phase is provided by the observation of stripe domain structures and the hysteresis loops. The ferromagnetic state for the gN phase observed here is mainly linked to large lattice ...
2011-01-01
Magnetic and magnetostrictive properties of manganese substituted cobalt ferrite
International Nuclear Information System (INIS)
The magnetic and magnetostrictive properties of polycrystalline Co1-xMnxFe2O4 (0 ? x ? 0.4) have been studied. Although the Curie temperature decreases continuously with increasing concentration of Mn, the magnetization remains high up to x = 0.3 and unexpectedly low coercivity is observed for this composition showing an unusual magnetostrictive behaviour. This composition shows a relatively larger magnetostriction at low fields. Moreover, the strain derivative which is the slope of the magnetostriction curve at low magnetic fields is almost doubled and the field at which maximum magnetostriction is observed is reduced to almost half for 30% of Mn substitution. The results show that x ? 0.3 in Co1-xMnxFe2O4 is an optimum composition with superior magnetostrictive properties for many applications.
2007-06-07
Energy Technology Data Exchange (ETDEWEB)
Langmuir-Blodgett (LB) preparations containing stacked monolayers of phospholipids or stearic acid were irradiated with UV light and the electric conductance perpendicular to the planes of the monolayers was measured. There was no observable change of conductance when LB preparations of stearic acid were irradiated. For LB preparations of phospholipids, a rise of conductance, dependent on dose rate, was observed, reaching an equilibrium level after a few hours. After irradiation the conductance fell with a temperature-dependent time constant, and eventually reached a final level a little above the initial value. A three-state model is proposed for the LB phospholipid preparations. This suggests that the absorption of one photon raises a molecule from the ground to an excited state; and the absorption of a second photon carries it into a damaged but repairable or metastable state. (author).
1992-12-01
International Nuclear Information System (INIS)
Nano indentation analysis and transmission electron microscopy observation were performed to investigate a microstructural evolution and its influence on the hardening behavior in Fe-Cr alloys after an irradiation with 8 MeV Fe4+ ions at room temperature. Nano indentation analysis shows that an irradiation induced hardening is generated more considerably in the Fe-15Cr alloy than in the Fe-5Cr alloy by the ion irradiation. TEM observation reveals a significant population of the a0 dislocation loops in the Fe-15Cr alloy and an agglomeration of the 1/2a0 dislocation loops in the Fe-5Cr alloy. The results indicate that the a0 dislocation loops will act as stronger obstacles to a dislocation motion than 1/2a0 dislocation loops.
2008-11-01
Investigations of microstructure of thin TbFeCo films by high-resolution electron microscopy
International Nuclear Information System (INIS)
High-resolution electron microscope observations confirm the presence of small crystallites in thin TbFeCo films protected by Si_3N_4 overcoats. Selected area electron diffraction patterns in top-view projection indicate that the crystals have a face-centered-cubic structure. Microscope analysis reveals grain growth following annealing of these protected thin films at 200 degree C in vacuum, and Kerr measurements yield large reductions in coercivity relative to the room-temperature value. The typical grain size visible in top-view observations increases from about 3 nm in the as-deposited samples to about 30 nm after annealing at 200 degree C for 36 h while the static coercivity, H_c, drops by about 40%. The fcc structure of the crystals is retained after annealing.
Influence of calcite on the electrokinetic treatment of a natural clay
British Library Electronic Table of Contents (United Kingdom)
After presenting a geochemical model for the interaction between calcite and varying environmental conditions, the paper discusses the experimental results of long duration electrokinetic tests, run on a natural clayey soil in unbuffered conditions. Local measurements of electrical potential, temperature and water flow were performed during the tests, while pH and fluid conductivity were measured locally once the tests had been dismantled. Sharp change of pH and reduction of the soil electrical conductivity, that in pure clays usually occur in the proximity of the cathode, were observed in the region close to the anode. As well, the soil in the anode area systematically tended to develop fractures, that mostly persisted until the end of the experiments. The features observed, that are not ...
2009-01-01
Banana peel extract mediated novel route for the synthesis of silver nanoparticles
British Library Electronic Table of Contents (United Kingdom)
Bio-inspired silver nanoparticles were synthesized with the aid of a novel, non-toxic, eco-friendly biological material namely, banana peel extract (BPE). Boiled, crushed, acetone precipitated, air-dried peel powder was used for reducing silver nitrate. Silver nanoparticles were formed when the reaction conditions were altered with respect to pH, BPE content, concentration of silver nitrate and incubation temperature. The colorless reaction mixtures turned brown and displayed UV-visible spectra characteristic of silver nanoparticles. Scanning electron microscope (SEM) observations revealed the predominance of silver nanosized crystallites after short incubation periods. When the reaction mixtures were incubated for 15 days, some micro-aggregates were also observed. Energy dispersive spectr...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
The growth of the Pd{sub 2}Si thin fllms on Si(111) substrates has been monitored by an {ital in} {ital situ} x-ray diffraction technique in vacuum and in helium atmosphere from 160 to 250 {degree}C. A familiar parabolic growth rate was found, confirming the diffusion-controlled film growth process. The activation energies were found to be 1.34 and 1.37 eV for the measurements performed in vacuum and helium environment, respectively. Stress relaxation in the growing Pd{sub 2}Si fllm was observed when the reaction temperature exceeds 200 {degree}C. The relaxed films showed a higher degree of texture as evidenced by the rocking curve measurements.
1990-04-15
The growth of the Pd{sub 2}Si thin fllms on Si(111) substrates has been monitored by an {ital in} {ital situ} x-ray diffraction technique in vacuum and in helium atmosphere from 160 to 250 {degree}C. A familiar parabolic growth rate was found, confirming the diffusion-controlled film growth process. The activation energies were found to be 1.34 and 1.37 eV for the measurements performed in vacuum and helium environment, respectively. Stress relaxation in the growing Pd{sub 2}Si fllm was observed when the reaction temperature exceeds 200 {degree}C. The relaxed films showed a higher degree of texture as evidenced by the rocking curve measurements.
1990-04-15
A model of chemistry and thermal hydraulics in PWR fuel crud deposits
Energy Technology Data Exchange (ETDEWEB)
A model is described for simulating thermal hydraulic and chemical conditions within fuel crud deposits. Heat transfer takes place by wick boiling in which water flows through the porous deposit and evaporates into steam at the surface of chimneys. The transport and chemistry of dissolved species within the deposit is also modelled. This chemistry includes the equilibrium chemistry of Li/boric acid species, the equilibrium chemistry of Fe/Ni species and the radiolysis chemistry of water. The unique feature of this model is that the chemistry is coupled to the thermal hydraulics via the increase in the saturation temperature with the concentration of dissolved species. This has a profound effect on evaporative heat transfer within thick deposits, leading to conditions that explain the precipitation of LiBO{sub 2} and the possible formation of bonaccordite. The model helps understand several crud scrape observations, including why AOA is ...
2006-07-01
A mobile remote sensing laboratory for water vapor, trace gas, aerosol, and wind speed measurements
Energy Technology Data Exchange (ETDEWEB)
The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.
1993-03-19
Vibrational population dynamics in liquids and glasses: IR pump-probe experiments from 10 K to 300 K
Energy Technology Data Exchange (ETDEWEB)
The temperature dependent vibrational relaxation of the CO stretching mode of Rhodium dicarbonyl acetylacetonate (Rh(CO){sub 2}(acac)) and tungsten hexacarbonyl (W(CO){sub 6}) in dibutylphthalate (DBP) and 2-methylpentane (2-MP) were measured with IR pump and probe (P-P) experiments. The experiments were performed with {approximately}1.5 ps pulses generated by the Stanford superconducting accelerator pumped free electron laser (FEL). Measurements were performed on the Rh(CO){sub 2}(acac) CO asymmetric stretching mode at {lambda} = 4.98{mu}m from 10 K to 300 K. Both the parallel and magic angle probe polarizations decay curves are biexponential over the entire temperature range. The slow component (ranging from 40 ps at 300 K to 55 ps at 10K) is attributed to the population relaxations. For the fast component (ranging from 4-5 ps at 300 K to 13-15 ps at 10K), we propose a mechanism of spectral diffusion, in contrast to the previously proposed ...
1995-12-31
International Nuclear Information System (INIS)
Conventional plasma carburizing or nitriding for austenitic stainless steels results in a degradation of corrosion resistance. However, a low temperature plasma surface treatment can improve surface hardness without deteriorating the corrosion resistance. The 2-step low temperature plasma processes (the combined carburizing and post nitriding) offers the increase of both surface hardness and thickness of hardened layer and corrosion resistance than the individually processed low temperature nitriding and low temperature carburizing techniques. In the present paper, attempts have been made to investigate the influence of the introduction of Ar gas (0#approx#20%) in nitriding atmosphere during low temperature plasma nitriding at 370 .deg. C after low temperature plasma carburizing at 470 .deg. C. All treated specimens exhibited the increase of the surface hardness ...
2008-03-01
NO formation in the burnout region of a partially premixed methane-air flame with upstream heat loss
Energy Technology Data Exchange (ETDEWEB)
Measurements of temperature and NO concentration in laminar, partially premixed methane-air flames stabilized on a ceramic burner in coflow are reported. The NO concentration and temperature were determined by laser-induced fluorescence (LIF) and coherent anti-Stokes Raman scattering (CARS), respectively. Upstream heat loss to the burner was varied by changing the exit velocity of the fuel-air mixture at a constant equivalence ratio of 1,3; this alters the structure of the flame from an axisymmetric Bunsen-type to a strongly stabilized flat flame. To facilitate analysis of the results, a method is derived for separating the effects of dilution from those of chemical reaction based on the relation between the measured temperature and the local mixture fraction, including the effects of upstream heat loss. Using this method, the amount of NO formed during burnout of the hot, fuel-rich combustion products can be ascertained. ...
1999-09-01
Correlating microstructure and thermal transport of irradiated SiC
International Nuclear Information System (INIS)
Full text of publication follows: The effect of neutron irradiation on the thermal conductivity of silicon carbide can be dramatic depending on the irradiation temperature and fluence the material is subjected to, and may be a critical factor defining it's use in fusion systems. Historically there have been several papers describing the effect of neutron irradiation on thermal conductivity degradation of SiC, predominately in the low to intermediate temperature ranges. Practically all of this work has been at temperatures lower than the application temperature for SiC being considered by the conceptual fusion reactors. This paper provides new data on the thermal conductivity of high quality CVD silicon carbide irradiated in a range of doses and temperature spanning the proposed fusion reactor temperature range. Specifically, an irradiation was carried out from ...
2007-12-10
Use of a novel acoustic dissolved oxygen transmitter for fish telemetry
DEFF Research Database (Denmark)
The multiple responses of fishes to changes in dissolved oxygen saturations have been studied widely in the laboratory. In contrast only few studies have included field observations. The objective of the present study was to evaluate the performance of a novel acoustic dissolved oxygen transmitter for field biotelemetry. The results demonstrated that the output of the transmitter was unaffected by three different temperatures (10 to 30 degrees C) and described the dissolved oxygen saturation with high accuracy (r(2) > 0.99) over the entire range of 0 to 191% saturation. The response time (>= 90% of end value) of the transmitter was 12 s both in terms of decreasing (100 to 0%) and increasing (0 to 100%) oxygen saturations. When externally attached to fishes the present findings support the use of the transmitter for reliable dissolved oxygen measurements on individuals living in environments that may change both temporally and spatially ...
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
Molar excess volumes have been determined by means of a vibrating-tube densimeter for binary liquid mixtures of cycloalkanones (cyclopentanone and cyclohexanone) + cyclohexane, + benzene, and + tetrachloromethane. The V/sup E/ data are reported over the complete mole fraction range at 288.15, 298.15, and 308.15{Kappa}. The obtained excess volumes are positive for mixtures of cyclopentanone with cyclohexane and are negative for mixtures of the cycloalkanones with benzene and tetrachloromethane; for the system cyclohexanone-cyclohexane the V/sup E/ values are positive for a wide range of mole fraction, but at very low cyclohexane mole fraction an inversion of the sign of V/sup E/ is observed. The data show that in the considered range of temperature the values of the temperature coefficient ({partial derivative}V/sup E//{partial derivative}T) are negative for mixtures of the cycloalkanones with benzene and are almost zero for ...
1989-04-01
International Nuclear Information System (INIS)
The partial pressures of the components (ThCl_4, MCl and MThCl_5) in the saturated vapours of ThCl_4 solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl_4 concentration (2 to 50 mol% ThCl_4) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl. (author).
1984-01-01
The influence of ultrasound on the fluoroquinolones antibacterial activity
British Library Electronic Table of Contents (United Kingdom)
In this work, the antibacterial effect of fluoroquinolones (FQs) upon Escherichia coli (E.coli) was measured with and without application of 40kHz ultrasound (US) stimulation. The research results demonstrated that simultaneous application of 40kHz US apparently enhanced the antibacterial effectiveness of FQs. That is, the synergistic effect was observed and the bacterial viability was reduced when FQs and US were combined. In addition, various influencing factors, such as FQs drug concentration, US irradiation time and solution temperature, on the inhibition of E.coli were also investigated. The antibacterial activity was enhanced apparently with increasing of FQs drug concentration, US irradiation time and solution temperature. Furthermore, we discussed preliminarily the mechanism of US ...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Two rapidly solidified powders with compositions Al-6.7 wt.% Fe-5.9 wt.% Ce and Al-6.2 wt.% Fe-5.9 wt.% Ce-1.63 wt.% Si were separated into -32 [mu]m and +32 to -63 [mu]m size fractions. Powders from both size fractions were extruded at 500 C. For comparison purposes, extrusion at a lower temperature of 400 C was also performed. In this investigation, tensile property evaluation indicated that processing of finer size fractions at high temperature offers no advantages in terms of the tensile properties but is advantageous in terms of improving the fracture toughness of alloy B. These observations underline the importance of the stability of powder microstructure during thermomechanical processing for the development of optimum mechanical properties. (orig.)
1994-04-01
Study on probability of failure for RPV nozzle region under severe accident conditions
Energy Technology Data Exchange (ETDEWEB)
Most of previous study for creep rupture of RPV lower head under severe accident condition, have been focused on global failure of RPV lower head. In contract, the local failure of the RPV nozzle region has not been studied in detail. The existence and features of nozzle failure in LAVA-ICI specimen of KAERI and LHF-4 specimen of Sandia National Lab., are observed. It is confirmed that the nozzle failure of LHF-4 specimen is due to the hoop stress in the RPV. The tensile tests in various temperatures and the creep rupture tests in various temperatures and stresses, are accomplished. The finite element analysis for LAVA-ICI experiment was confirmed, and the stress and deformation analysis results are used in LAVA-ICI experiment. 17 refs., 34 figs., 3 tabs. (Author)
2001-04-01
Statistical analyses of coads wind data in coastal regions of the United States
Energy Technology Data Exchange (ETDEWEB)
In the study, wind data from the Comprehensive Ocean-Atmosphere Data Set (COADS) are used to determine atmospheric circulation changes which are empirically associated with the air temperature changes. Some understanding of the natural processes which produce climate change is anticipated from the study of these associations. Systematic changes of wind in US coastal regions with periods of climate warming and cooling suggest circulation changes, in addition to carbon dioxide-controlled radiation effects, could produce the climate changes indicated by air temperature. A statistical procedure for analyses of COADS was used to determine decade-period vector wind-field differences from the COADS record period. The statistical procedure for these analyses is explained and the wind differences are compared to summaries of mid-Atlantic coast island-station observations.
1992-08-01
Stability of A-15 compounds in multifilamentary superconducting wires
International Nuclear Information System (INIS)
With the preeminence of A-15 superconducting multifilamentary wires in magnet technology, it has become important to understand the thermodynamic factors influencing the formation of these compounds under solid-state reaction conditions. The six systems Nb--Sn, Nb--Ga, Nb--Ge, Nb--Al, V--Si, and V--Ga were prepared as single filament bronze wires and heat treated in an attempt to precipitate the appropriate A-15 compound. The compounds observed to form were categorized using a formation temperature ratio (stability index) based on the melting temperatures of the constituents which make up the single filament composites. This study has led to several predictions regarding the formation of A-15 compounds using a solid-state bronze diffusion technique. The results of experimentation based on these predictions are presented.
Soliton microdynamics and thermal conductivity of uranium nitride at high temperatures
British Library Electronic Table of Contents (United Kingdom)
The microdynamics of soliton waves and localized modes of nonlinear vibrations of the acoustic and optical types in uranium nitride has been investigated. It has been shown that, with an increase in the excitation energy in the spectral gap between the bands of optical and acoustic phonons, the energies of solitons increase, whereas the energies of local modes decrease. The previously experimentally observed unidentified quasi-resonant features, which shift in the gap with variations in the temperature, can represent the revealed soliton waves and local modes. The microdynamics of heat conduction of uranium nitride has been studied for the stochastic generation of soliton waves and local modes in the case of spatially distant energy absorption. The thermal conductivity coefficient determin...
2011-01-01
Sialon sintering product excellent in liquid sodium corrosion resistance
International Nuclear Information System (INIS)
A sialon sintering product of the present invention comprises #beta#'-sialon grains and less than 2vol% of a grain boundary phase, and a relative density of the sintering product is greater than 98%. It exhibits a high temperature strength of greater than 500Mpa at 650degC and shows such high corrosion resistances that the reduction of the volume due to corrosion is less than 0.5mg/cm"2 in a liquid sodium immersion test, and the corrosion of the grain boundary is not observed. Accordingly, there can be provided a sialon sintering product excellent in corrosion resistance in a liquid sodium circumstance while keeping the high temperature strength as an excellent characteristic of the sialon sintering product. (T.M.).
1995-04-19
Photoluminescences from Al{sub x}Ga{sub 1{minus}x}P liquid phase epitaxial layers
Homogenous Al{sub x}Ga{sub 1{minus}x}P liquid phase epitaxial layers have been obtained with the temperature difference method under controlled vapor pressure (TDM-CVP). Very clear fine structures near band edge in photoluminescence spectra have been observed at 77 K for the first time. Photoluminescence measurement results confirmed that the free exciton recombination without phonon assistance plays an important role in the luminescence at 77 K and becomes dominant at room temperature. It is considered that Zero-phonon assisted free exciton recombination is intensified by some local perturbations to electrical potentials against carriers or excitons introduced by Al atoms in Al{sub x}Ga{sub 1{minus}x}P layers, which can give momentum change necessary for recombination.
1999-10-01
Energy Technology Data Exchange (ETDEWEB)
The flow of current inside a conductor leads to its overheating. This conductor is also submitted to other climatic phenomena, such as wind, sun light and ambient temperature. The knowledge of this overheating is important to ensure a functioning temperature compatible with the materials used for the conductor manufacturing and with the dip of overhead power lines above the ground and buildings. On the other hand, according to the Laplace works, the flow of current inside parallel conductors induces electromagnetic forces inside them, proportional to the product of currents in both conductors. In the case of short-circuit between aerial power lines or between flexible cables, electrodynamical stresses (traction and flexion) are applied to insulators and holders and important swinging of the lines can be observed. These stresses can be extremely important and must be considered in the design of overhead lines. These two ...
1997-05-01
Microstructural characterization of plasma nitrided austenitic stainless steel
Energy Technology Data Exchange (ETDEWEB)
The microstructure of the layers produced by plasma nitriding austenitic stainless steel at different treatment temperatures (400 and 500 C) were studied by transmission electron microscopy (TEM) together with X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the microstructures were composed of 'expanded austenite' ({gamma}{sub N}) and {alpha}(ferrite)+CrN following plasma nitriding at lower and higher treatment temperatures, respectively. The former contains stacking faults and deformed twin substructures, while the latter is made up of colonies displaying a lamellar structure. Kurdjumov-Sachs or Nishiyama-Wassermann orientation relationships between the {alpha} and CrN layer were observed. (orig.)
2000-10-23
Examinations of polished and dry cut sections of feed and tuyere coke revealed some possible mechanisms for the physical influence of mineral compounds on the reactivity and strength of coke. It was observed that rounded particles of mineral phases that are exposed to the pore walls and surface of coke at high temperature create an inorganic cover, thus reducing the surface available for gas-solid reactions. The particles of mineral matter that have a low melting point and viscosity can affect the coke at earlier stages in the blast furnace process, acting in the upper parts of the blast furnace (BF). The temperature-driven redistribution of mineral phases within the coke matrix probably leads to the creation of weak spots and in general to anisotropy in its properties, thus reducing its strength. 9 refs., 2 figs., 1 tab.
2006-12-15
Magnetic properties of Fe-Co-Mo-Cu-B nanocrystalline ribbons with stressing surfaces
British Library Electronic Table of Contents (United Kingdom)
Magnetic properties of Fe-Co-Mo-Cu-B alloy system with Co up to 26at.% were investigated. After proper thermal treatment, the nanocrystalline grain remains tiny, the density hardly increases, but the room-temperature saturation attains 1.5T mainly due to a high enough Curie temperature. The generally observed slant hysteresis loops point to ribbon surfaces, which stress the ribbon interior and induce a specific magnetoelastic contribution to hard-ribbon-axis magnetic anisotropy even after vacuum annealing. The effect does not come from cobalt but rather from the lack of silicon. Partial removal of the surfaces resulted in a decrease of the loop tilt.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water permeability changes were ...
1995-12-01
Low energy ion scattering study of palladium films on silicon(111)-7 x 7 surfaces
Energy Technology Data Exchange (ETDEWEB)
The initial growth process and surface structure of thin Pd(silicide) films on clean Si(111)-7x7 surfaces have been studied by low energy ion scattering (ISS) and LEED-Auger techniques. Considerable reaction between Pd and Si at room temperature is observed to extend up to 25 ML thickness of deposited Pd. Heat treatment of the room temperature film produced epitaxial silicide Pd/sub 2/Si(0001) films covered with the accumulated elementary Si layers of 1-2 ML thickness. Deposition of 1/3 ML Pd onto a heated substrate gives a Pd-embedded ordered surface of Si(111)-..sqrt..3x..sqrt..3R30/sup 0/, the feature being similar to the cases of Ag, Au/Si(111) systems.
1983-12-15
Low energy ion scattering study of palladium films on silicon(111)-7 x 7 surfaces
International Nuclear Information System (INIS)
The initial growth process and surface structure of thin Pd(silicide) films on clean Si(111)-7x7 surfaces have been studied by low energy ion scattering (ISS) and LEED-Auger techniques. Considerable reaction between Pd and Si at room temperature is observed to extend up to 25 ML thickness of deposited Pd. Heat treatment of the room temperature film produced epitaxial silicide Pd_2Si(0001) films covered with the accumulated elementary Si layers of 1-2 ML thickness. Deposition of 1/3 ML Pd onto a heated substrate gives a Pd-embedded ordered surface of Si(111)-#sq root#3x#sq root#3R30"0, the feature being similar to the cases of Ag, Au/Si(111) systems. (orig.).
We report electronic and magnetic structure of arsenic-doped manganese clusters from density-functional theory using generalized gradient approximation for the exchange-correlation energy. We find that arsenic stabilizes manganese clusters, though the ferromagnetic coupling between Mn atoms are found only in Mn$_2$As and Mn$_4$As clusters with magnetic moments 9 $\\mu_B$ and 17 $\\mu_B$, respectively. For all other sizes, $x=$ 3, 5-10, Mn$_x$As clusters show ferrimagnetic coupling. It is suggested that, if grown during the low temperature MBE, the giant magnetic moments due to ferromagnetic coupling in Mn$_2$As and Mn$_4$As clusters could play a role on the ferromagnetism and on the variation observed in the Curie temperature of Mn-doped III-V semiconductors.
2005-01-01
Irreversible Performance of a Quantum Harmonic Heat Engine
The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio ...
2006-01-01
Interface-induced conversion of infrared to visible light at semiconductor interfaces
International Nuclear Information System (INIS)
Efficient, low-temperature conversion of infrared light into visible light (red, orange, green) is reported at single heterojunctions and undoped quantum wells of GaAs and ordered Al_xGa_1_-_xInP_2; an increase in photon energy of 700 meV is obtained. The signal originates from the high-band-gap layers and disappears only if the excitation energy is tuned below the GaAs band gap. The intensity of the up-converted photoluminescence (PL) is found to decrease significantly slower with increasing temperature than that of the regular PL and it remains observable up to 200 K. Interface-induced cold Auger processes along with the presence of trapped states for both electrons and holes in these ordered alloys account for this nonlinear mechanism. A colinear double-beam experiment confirms this. copyright 1996 The American Physical Society.
Energy Technology Data Exchange (ETDEWEB)
Passive films formed on Alloy 690 in different pH solutions at high temperatures were studied by potentiodynamic polarization, Auger electron spectroscopy, thermodynamic diagrams and the Mott-Schottky relation. The chemical compositions and electronic structures of the passive films were found to be strongly pH-dependent. In alkaline solutions, a secondary passivation was clearly observed on potentiodynamic polarization curves. The passive films were a mixture of Cr{sub 2}O{sub 3} and FeCr{sub 2}O{sub 4} below the flat band potential of nickel oxide and were NiFe{sub 2}O{sub 4} above this potential. Electronic structure models, describing the electrochemical properties of the passive films, are proposed and discussed.
2009-12-15
International Nuclear Information System (INIS)
Passive films formed on Alloy 690 in different pH solutions at high temperatures were studied by potentiodynamic polarization, Auger electron spectroscopy, thermodynamic diagrams and the Mott-Schottky relation. The chemical compositions and electronic structures of the passive films were found to be strongly pH-dependent. In alkaline solutions, a secondary passivation was clearly observed on potentiodynamic polarization curves. The passive films were a mixture of Cr2O3 and FeCr2O4 below the flat band potential of nickel oxide and were NiFe2O4 above this potential. Electronic structure models, describing the electrochemical properties of the passive films, are proposed and discussed.
2009-12-01
Heat capacities of the mixtures of ionic liquids with acetonitrile
International Nuclear Information System (INIS)
Isobaric specific heat capacities were measured for {1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF4) + acetonitrile (MeCN)} and {1-methyl-3-octylimidazolium tetrafluoroborate (OMIMBF4) + acetonitrile} within the whole range of composition and temperatures from (283.15 to 323.15) K. The excess molar heat capacities were calculated from the experimental results and satisfactorily fitted to Redlich-Kister type polynomials for several selected temperatures. Negative deviations from the additivity of molar heat capacities were observed within the whole composition range of (HMIBMF4 + MeCN) and (OMIMBF4 + MeCN). The results obtained have been interpreted in terms of interactions between ionic liquids and acetonitrile.
2010-02-01
Formation of AlN-polytypoid phases during #alpha#-SiAlON decomposition
International Nuclear Information System (INIS)
Phase transformations from #alpha#- to #beta#-SiAlONs (i.e., from #alpha#' to #beta#') have been recently reported in a number of rare-earth SiAlON systems during postsintering heat treatment. In the present work, this transformation process in a Sm (#alpha# + #beta#)-SiAlON material is studied by using XRD, TEM, and EDS X-ray mapping techniques. It is observed that in addition to the formation of #beta#' and M' phases, the #alpha#'-to-#beta#' transformation is accompanied by a significant increase in the amount of an AlN-polytypoid phase. The results suggest that some #alpha#' phases are thermodynamically unstable at temperatures lower than the material sintering temperature and will decompose when conditions allow. For the composition studied in this work, the #alpha#-SiAlON decomposition can be described in general as #alpha#' #-># #beta#' + M' + AlN polytypoid.
Electronic properties of low temperature microcrystalline silicon carbide prepared by Hot Wire CVD
Energy Technology Data Exchange (ETDEWEB)
Microcrystalline silicon carbide ({mu}c-SiC) was prepared at low substrate temperatures using Hot Wire chemical vapor deposition (HWCVD). High crystalline volume fractions were achieved at high hydrogen dilution and high deposition pressure. Without intentional doping, such material shows high dark conductivity and high optical absorption below the band gap. The material prepared at low deposition pressure or low hydrogen dilution, on the other hand, shows much lower conductivity and sub-gap absorption, but high spin densities up to 5 x 10{sup 19} cm{sup -3}. This high absorption can be attributed to free carriers, different to {mu}c-Si:H where a correlation between the sub-gap absorption and the spin density is observed.
2008-01-15
Effect of pressure on the valence state of Yb in YbPd_2Si_2
International Nuclear Information System (INIS)
The intermediate valent behaviour of YbPd_2Si_2 has been studied under pressure in the temperature range from 1.2 K to 90 K by using the 84 keV Moessbauer transition in "1"7"0Yb. At 54 kbar and 4.2 K we obtain an increase of the electric field gradient (EFG) by a factor of #approx =# 3. In addition, the EFG varies strongly with temperature, in contrast to the behaviour at ambient pressure. At 1.2 K a change of the hyperfine pattern is observed indicating a magnetic character of the Yb ion. These results provide evidence of a pressure induced change of the valence state close to 3+. (orig.).
International Nuclear Information System (INIS)
The effect of lattice damage caused by room temperature irradiations with products of "1"0B(n,#alpha#)"7Li reactions and "2"3"5U fissions and with fast neutrons on transition curves, quenching curves, and lattice constants of Nb_3Sn, Nb_3Al, Nb_3(Al,Ge), and V_3Si have been investigated. The critical currents in transverse magnetic fields could be increased up to more than one order of magnitude. For heavily irradiated samples drastically reduced values for the critical currents, the upper critical fields, and the transition temperatures were observed. The lattice constants were increased up to 0.5 percent by irradiation. (U.S.).
Corrosion of gold bridgewire in electronic components
Energy Technology Data Exchange (ETDEWEB)
Accelerated aging tests on gold bridgewired detonator assemblies to determine compatibility of the Au and Pd-In-Sn solder with the organic explosive, PENT, have revealed an unusual corrosion process. These tests, conducted at 74/sup 0/C and 54/sup 0/C indicated a preferential attack of the gold. A matrix of corrosion test units was established to study this corrosion problem with accelerating temperatures up to 100/sup 0/C. Scanning electron microscopy (SEM), energy dispersive x-ray (EDX), and x-ray diffraction techniques were used to determine the extent of the corrosion and identify the corrosion products. Results indicate the preferential attack of the gold was due to HCN formed by decomposition of the explosive powder (PETN) at high temperatures. Other associated reactions were also observed including subsequent attack of the solder by the gold corrosion product and degradation of the plastic header.
1986-01-01
British Library Electronic Table of Contents (United Kingdom)
A mechanism is proposed for the previously observed [1] jump in erythrocyte fluidity through a microcapillary 1.3 ?m in diameter at a temperature of 36.6?0.3?C. Our interpretation is based on the experimental evidence both for existence of ortho and para H2O isomers in water and on spin-selective interaction of proteins with para H2O isomers as hydration shells of biomolecules are being formed [2]. It is important that the formation of hydration shells of proteins and DNA in aqueous solutions is accompanied by an increase in the Brillouin shift to 0.4 cm?1 (?0.25 cm?1 in water), which points to the formation of icelike structures. We believe that the coincidence of the translational energy kT of the Brownian motion and the energy of the rotational quanta for the 313?202 transition of para ...
2009-01-01
Chemical isomeric effects on propanol glassy structures
Energy Technology Data Exchange (ETDEWEB)
We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)
2002-07-01
Chemical isomeric effects on propanol glassy structures
International Nuclear Information System (INIS)
We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)
British Library Electronic Table of Contents (United Kingdom)
Major forecast errors on the background error covariance from initial conditions, atmospheric forcing, model open boundary conditions, and the river discharges are examined in a coastal model of northern South China Sea. The analysis of background error covariance matrix produced by model ensemble shows that the perturbations of the initial conditions and atmospheric forcing play major roles in producing and maintaining the amplitude of ensemble spread except for the sea surface height (SSH) field. The perturbation of model open boundary conditions can influence ensemble spread of all variables and covariance between temperature and velocity or between temperature and SSH. The perturbation of river discharge mainly affects the covariance of salinity in river estuary. A data assimilation ex...
2011-01-01
Use of coal as fuel for chemical-looping combustion with Ni-based oxygen carrier
Energy Technology Data Exchange (ETDEWEB)
Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas presents a monotonously increasing trend, whereas the dry basis concentration of CO, ...
2008-12-15
The life span of the biosphere revisited
Energy Technology Data Exchange (ETDEWEB)
A decade ago, Lovelock and Whitfield raised the question of how much longer the biosphere can survive on Earth. They pointed out that, despite the current fossil-fuel induced increase in the atmospheric CO[sub 2] concentration, the long-term trend should be in the opposite direction: as increased solar luminosity warms the Earth, silicate rocks should weather more readily, causing atmospheric CO[sub 2] to decrease. In their model, atmospheric CO[sub 2] falls below the critical level for C3 photosynthesis, 150 parts per million (p.p.m.), in only 100 Myr, and this is assumed to mark the demise of the biosphere as a whole. Here, this problem is re-examined using a more elaborate model that includes a more accurate treatment of the greenhouse effect of CO[sub 2] a biologically mediated weathering parameterization, and the realization that C4 photosynthesis can persist to much lower concentrations of atmospheric CO[sub 2] ([lt]10 p.p.m.). It was found that a ...
1992-12-24
International Nuclear Information System (INIS)
Lappeenranta University of Technology (LTKK) and VTT Energy carried out a series of preliminary tests in 1999 to study the behavior of noncondensable (NC) gases in VVER geometry. The tests aimed at studying the effect of NC gases on system thermal-hydraulics and on heat transfer in a horizontal steam generator (HSG). The system behavior can be affected by hydrogen produced in the core in case of a severe accident, by nitrogen from hydro-accumulators released into the primary circuit in case of a loss-of-coolant accident (LOCA) and more generally by any NC gas in all cases where cooling is ensured by natural circulation. A secondary objective of the tests - the first series of tests ever performed with NC gas with PACTEL - was to find out, if the instrumentation of PACTEL was adequate for this type of tests and if it was functioning properly. This paper presents the measured and calculated (CATHARE code version V15a mod 2.1) results of the test NCg-l. It was carried out in natural ...
2001-03-20
Energy Technology Data Exchange (ETDEWEB)
The aim of this work is to simulate the reduction by hydrogen of the tri-uranium octo-oxide U{sub 3}O{sub 8} (obtained by uranium trioxide calcination) into uranium dioxide. The kinetics curves have been obtained by thermal gravimetric analysis, the hydrogen and steam pressures being defined. The geometrical modeling which has allowed to explain the trend of the kinetics curves and of the velocity curves is an anisotropic germination-growth modeling. The powder is supposed to be formed of spherical grains with the same radius. The germs of the new UO{sub 2} phase appear at the surface of the U{sub 3}O{sub 8} grains with a specific germination frequency. The growth reactivity is anisotropic and is very large in the tangential direction to the grains surface. Then, the uranium dioxide growths inside the grain and the limiting step is the grain surface. The variations of the growth reactivity and of the germination specific frequency in terms of the gases partial ...
1997-12-04
Post-CHF Heat Transfer characteristics in one rod bundle geometry
Energy Technology Data Exchange (ETDEWEB)
In the present paper, experimental study of forced convection boiling were performed to investigate the post-CHF characteristics of a vertical annular channel with one heated rod and four spacer grids for new refrigerant R-134a. The experiments were conducted under outlet pressure of 11.6, 13, 16 and 20 bar, mass fluxes of 100-600 kg/m{sup 2}s, and inlet temperatures of 25-51 .deg. C. The parametric trend of the post-CHF data was well consistent with previous studies. The two phase flow regime in tube flow occurring downstream of the CHF has been called post-CHF, dispersed flow, liquid-deficient flow, mist flow and film boiling. This regime is characterized by a continuous vapor phase with discrete liquid drops and a non-wetted heated surface. This regime has a considerable importance in the areas of light water reactor(LWR) accident analysis and other film boiling applications. The post-CHF region occurs by design in heat exchangers operating ...
2006-07-01
Post-CHF Heat Transfer characteristics in one rod bundle geometry
International Nuclear Information System (INIS)
In the present paper, experimental study of forced convection boiling were performed to investigate the post-CHF characteristics of a vertical annular channel with one heated rod and four spacer grids for new refrigerant R-134a. The experiments were conducted under outlet pressure of 11.6, 13, 16 and 20 bar, mass fluxes of 100-600 kg/m2s, and inlet temperatures of 25-51 .deg. C. The parametric trend of the post-CHF data was well consistent with previous studies. The two phase flow regime in tube flow occurring downstream of the CHF has been called post-CHF, dispersed flow, liquid-deficient flow, mist flow and film boiling. This regime is characterized by a continuous vapor phase with discrete liquid drops and a non-wetted heated surface. This regime has a considerable importance in the areas of light water reactor(LWR) accident analysis and other film boiling applications. The post-CHF region occurs by design in heat exchangers operating in the ...
2006-11-02
Novel in situ polymerizable liquid three-arm biodegradable oligomeric polyesters based upon glycolic acid (GA), L-lactic acid (LLA), and their copolymers are synthesized and characterized. Injectable and in situ curable polymer neat resins and their composites formulated with bioabsorbable beta-tricalcium phosphate are prepared at room temperature using photo- and redox-initiation systems, respectively. The cured neat resins show the initial compressive yield strength (YCS, MPa), modulus (M, MPa), ultimate compressive strength (UCS, MPa), and toughness (T, kN mm), ranging from 4.0 to 20.1, 201.5 to 730.2, 82.7 to 310.5, and 1.02 to 3.93. The cured composites show the initial YCS, M, UCS and T, ranging from 27.7 to 56.4, 1440 to 4870, 81.6 to 158.9, and 0.94 to 1.97. Increasing GA/LLA ratio increases all the initial compressive strengths of both neat resins and composites. Increasing filler content increases YCS and M but decreases UCS and T. A diametral tensile ...
2006-08-18
Energy Technology Data Exchange (ETDEWEB)
Vermicomposts as a biofertilizer can be a great option for pond manuring as they never cause any long term harm to the soil like chemical fertilizer. In this study vegetable and horticulture waste was used as an important media for vermiculture. Three separate cemented tanks (6 m{sup 3} each) were used in the system as control tank, vermicompost fertilized tank and inorganic fertilizer manured tank. Monoculture of fish was carried out with cat fish, Clarias batrachus. The produced earthworms were used as fish feed. Regular monitoring of water parameter was conducted in three different ponds. Specifically, the algal biomass variation was quite helpful in analysing the behavior of the ponds. NPK value of soil samples was analyzed intermittently to know the eutrophication level. Despite the hot summer temperature in northern part of India, which is not ideal for fish growth, we have recorded an encouraging growth performance in organic manured pond along with ...
2004-05-01
Energy Technology Data Exchange (ETDEWEB)
In light water reactors, austenitic stainless steels (SSs) are used extensively as structural alloys in reactor core internal components because of their high strength, ductility, and fracture toughness. However, exposure to high levels of neutron irradiation for extended periods degrades the fracture properties of these steels by changing the material microstructure (e.g., radiation hardening) and microchemistry (e.g., radiation-induced segregation). Experimental data are presented on the fracture toughness and crack growth rates (CGRs) of wrought and cast austenitic SSs, including weld heat-affected-zone materials, that were irradiated to fluence levels as high as {approx} 2x 10{sup 21} n/cm{sup 2} (E > 1 MeV) ({approx} 3 dpa) in a light water reactor at 288-300 C. The results are compared with the data available in the literature. The effects of material composition, irradiation dose, and water chemistry on CGRs under cyclic and stress corrosion cracking conditions were ...
2008-01-21
Understanding of the volatility of GeO/sub 2/ in the presence of WO/sub 2/
Energy Technology Data Exchange (ETDEWEB)
The equilibria composition of the gaseous and the solid phase in the system GeO/sub 2//WO/sub 2/ is calculated with an improved thermodynamical program for temperatures 1100 < T < 1400 K and constant volume. By means of the results the experimental observed migration of GeO/sub 2/ in the presence of WO/sub 2/ in a temperature gradient T/sub 2/ ..-->.. T/sub 1/ (1200 ..-->.. 1100 K) in sealed evacuated silica tubes is due to a chemical transport with H/sub 2/ as the transporting agent. The H/sub 2/ is formed by H/sub 2/O which is desorbed by the quartz glass of the ampoules. The also observed volatility of WO/sub 2/ and its deposition in form of Ge/sub 0.75/W/sub 3/O/sub 9/ at the 'cold' end (T/sub 1/) of the tubes is performed by gaseous GeWO/sub 4/. The calculated and experimental transport rates are compared and discussed.
1983-08-01
The response of quartz crystals coated with thin fatty acid film to organic gases
Energy Technology Data Exchange (ETDEWEB)
We tried to apply a quartz crystal as a sensor by using the resonant frequency and the resistance properties of quartz crystals. Four kinds of fatty acids that have the same head groups were coated on the surfaces of the quartz crystals, and the shift of the resonant frequency and the resistance were observed based on the lengths of the tail groups. Myristic acid (C{sub 14}), palmitic acid (C{sub 16}), stearic acid (C{sub 18}), and arachidic acid (C{sub 20}) were deposited on the surfaces of quartz crystals by using the Langmuir-Blodgett (LB) method. As a result, the resonant frequency change was more sensitive to high molecular-weight fatty acids than to low molecular-weight ones. We also observed the effect of temperature on stearic acid LB films, and the response properties of quartz crystals coated with stearic-acid LB films to organic gases were investigated. As a result, the sensitivity of quartz crystals to organic ...
1999-07-01
International Nuclear Information System (INIS)
When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, Tg, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of Tg is observed for small pore sizes and attractive surface while Tg decreases for non ...
2006-01-01
Studies on accumulation of uranium by fungus Lentinus sajor-caju
Energy Technology Data Exchange (ETDEWEB)
The untreated, heat- and alkali-treated Lentinus sajor-caju mycelia were used for the recovery of uranium from aqueous solutions. The effect of pH, temperature, initial concentration of UO{sub 2} {sup 2+} ions and contact time parameters were investigated in a batch system. The particles sizes of the fungal mycelia were ranging from 100 to 200 {mu}m. Biosorption equilibriums were established in about 30 min and the correlation regression coefficients show that the adsorption process can be well defined by the Freundlich equation. The alkali treated form had a high biosorption capacity (378 mg/g) than those of the untreated (268 mg/g) and heat-treated fungal mycelia (342 mg/g). Optimum biosorption was observed at pH 4.5 for all the tested fungal preparations and was independent of temperature (5-35 deg. C). In addition, the polarity and surface energy of the fungal biomass film preparations were determined by contact angle ...
2006-08-21
International Nuclear Information System (INIS)
The structural, morphological and optical properties of vacuum-evaporated CdTe thin films were investigated as a function of substrate temperature and post-deposition annealing without and with CdCl2/treatment at 400 C for 30 min. Diffraction patterns are almost the same exhibiting higher preferential orientation corresponding to (111) plane of the cubic phase. The intensity of the (111) peak increased with the CdCl2/annealing treatment. The microstructure observed for all films following the CdCl2/annealing treatment are granular, regardless of the as-deposited microstructure. The grain sizes are increased after the CdCl2/annealing treatment but now contain voids around the grain boundaries. The optical band gaps, Eg, were found to be 1.50, 1.50 and 1.48 eV for films deposited at 200 K and annealed without and with CdCl2/treatment at 400 C for 30 min respectively. A progressive sharpening of the absorption edge upon heat treatment particularly ...
2007-09-01
Crystal structure and magnetic properties of Sm{sub 3}ReO{sub 7}
Energy Technology Data Exchange (ETDEWEB)
Crystals of a new ternary samarium rhenium oxide, Sm{sub 3}ReO{sub 7} were obtained by subsolidus reaction of samariumsesquioxide and rheniumdioxide (ratio 1.5:1) in sealed Pt-10Rh-tubes at 1673 K. The structure was determined by single-crystal X-ray diffraction. Sm{sub 3}ReO{sub 7} crystallizes in the orthorohombic system with unit cell dimensions a = 10.736(5), b = 7.392(3), and c = 7.519(3) in space group Cmcm (No. 63) with Z = 4. The structure consists of ReO{sub 6} octahedra, distorted SmO{sub 6} octahedra, and SmO{sub 8} prisms that are interconnected to each other to form a three-dimensional network. Rhenium has the formal oxidation state of +5 but no metal-metal bond is observed in this compound. The observed magnetization in the temperature range 4 K < T < 52 K is explained by a Curie-Weiss law modified by a temperature independent Van Vleck paramagnetism of samarium (3+).
1996-08-01
Change in pore structure of coals by activation with KOH; KOH fukatsushita sekitan no saiko kozo
Energy Technology Data Exchange (ETDEWEB)
Three typical Japanese coals of non-coking coal, coking coal and anthracite were heat-treated with KOH, and change in their pore structure was examined by absorption of N2, X-ray diffraction and TEM observation. In addition, the relation between a coal rank and pore structure was also studied by absorption experiment of N2. In experiment, the mixture of coal and KOH in a nickel holder was heat-treated in N2 gas flow at heating rate of 2{degree}C/min, and held at a fixed temperature for one hour. To clarify the pore structure, N2 absorption isotherms were measured at -196{degree}C under nearly 76cmHg using a commercially available full-automatic absorption measurement equipment. Based on the X-ray diffraction and TEM observation results on activated coals, the relation between the N2 absorption and pore structure was studied. The results are summarized as follows: (1) The yield and absorption ability of coals increase with a ...
1996-10-28
A Chandra Observation of Supernova Remnant G350.1-0.3 and Its Central Compact Object
We present a new Chandra observation of supernova remnant (SNR) G350.1-0.3. The high resolution X-ray data reveal previously unresolved filamentary structures and allow us to perform detailed spectroscopy in the diffuse regions of this SNR. Spectral analysis demonstrates that the region of brightest emission is dominated by hot, metal-rich ejecta while the ambient material along the perimeter of the ejecta region and throughout the remnant's western half is mostly low-temperature, shocked interstellar/circumstellar medium (ISM/CSM) with solar-type composition. The data reveal that the emission extends far to the west of the ejecta region and imply a lower limit of 6.6 pc on the diameter of the source (at a distance of 4.5 kpc). We show that G350.1-0.3 is likely in the free expansion (ejecta-dominated) stage and calculate an age of 600-1200 years. The derived relationship between the shock velocity and the electron/proton ...
2011-01-01
Thermal properties of UPdSn and UCuSn
International Nuclear Information System (INIS)
We report on the specific heat and the thermopower of UPdSn and UCuSn, both of which order antiferromagnetically at low temperatures. The compounds show similar behaviour in the specific heat, and the large magnetic-entropy changes around T_N are evidence for a large degree of 5f-electron localization. For both compounds, we find that thermopower results are consistent with the findings for the electrical resistance. While for UCuSn very abrupt changes at 25 and 60 K are observed for both quantities, more continuous changes at the magnetic transitions (25 and 40 K) are found for UPdSn. (orig.).
1996-09-24
Superconductivity of neutron irradiated Mo_3Os
International Nuclear Information System (INIS)
The effect of high energy neutron irradiation (E > 1 MeV) on the superconducting transition temperature, Tsub(c), of the A-15 compound Mo_3Os is reported. Tsub(c) was found to decrease with increasing neutron dose, but at a rate considerably less than observed in other A-15 compounds composed of non-transition metals. The results lend support to the idea that the effect of ordering on Tsub(c) is smaller for A-15 compounds composed only of transition metals than those composed of transition and non-transition metals. (author).
Superconductivity in irradiated A-15 compounds at low fluences. I. Neutron-irradiated V_3Si
International Nuclear Information System (INIS)
The behavior of the superconducting transition temperature T/sub c/ of single-crystal and polycrystalline V_3Si was investigated as a function of low-fluence neutron irradiation. It is found that the initial degradation of T/sub c/ is sample-dependent, some specimens showing no degradation in T/sub c/ up to a fluence of 2 x 10"1"8 n/cm"2. This and many other earlier observations on low-fluence behavior are explained in terms of a recently proposed model of radiation damage in A-15 compounds.
Sunyaev-Zel'dovich Effects from Quasars Shining in Galaxies and Groups
The energy fed by active galactic nuclei to the surrounding diffuse baryons changes the latter's amount, temperature, and distribution; so in groups and in member galaxies it affects the X-ray luminosity and also the Sunyaev-Zel'dovich effect. Here we compute how the latter is enhanced by the transient blastwave driven by a shining quasar, and is depressed when the equilibrium is recovered with a depleted density. We constrain such depressions and enhancements with the masses of relic black holes in galaxies and the X-ray luminosities in groups. We discuss how all these linked observables can tell the quasar contribution to the thermal history of the baryons pervading galaxies and groups.
2003-01-01
Studies of Plasma Confinement in GOL-3 Multi-mirror Trap
International Nuclear Information System (INIS)
Recent results of the experiments at GOL-3 facility are presented. Plasma with a density of 1014...1016 cm-3 is confined in a 12-meter-long solenoid, which comprises 55 corrugation cells with mirror ratio Bmax/B min=4.8/3.2 T. The plasma is heated up to 2...4 keV temperature by a high power relativistic electron beam (?1 MeV, ? 330 kA, ?8?s, ?120 kJ) injected through one of the ends. Mechanism of experimentally observed fast ion heating, issued of plasma stability and confinement are discussed.
2006-01-01
International Nuclear Information System (INIS)
Phase transformations in TiD_#approx#_0_._7_5 subjected to high-pressure treatment were investigated by simultaneous real-time measurements of neutron diffraction and small-angle neutron scattering. The neutron spectra were taken on heating the samples in temperature ranges 100 to 300 K and 300 to 870 K. A sequence of structural transitions was observed, which involves 7 different phases and intermediate states with hcp, fcc, fco or bcc metal sublattices and hydrogen atoms. 30 refs., 9 figs., 1 tab.
1992-09-01
Randomization of heavily damaged regions in annealed low energy Ge{sup +}-implanted (0 0 1)Si
Energy Technology Data Exchange (ETDEWEB)
Apparent growth of amorphous layers during low temperature annealing was observed in low energy Ge{sup +}-implanted (0 0 1)Si by high-resolution transmission electron microscopy. The occurrence of abnormal growth is due to the randomization of heavily damaged regions beneath the original amorphous/crystalline interfaces. The randomization process is attributed to the strain, incurred by the presence of a high density of large Ge atoms in the heavily damaged Si substrate, relaxation to lower the free energy of the systems. The randomization upon annealing may be fruitfully applied to minimize the transient enhanced diffusion in shallow junction formation.
2004-01-15
Randomization of heavily damaged regions in annealed low energy Ge"+-implanted (0 0 1)Si
International Nuclear Information System (INIS)
Apparent growth of amorphous layers during low temperature annealing was observed in low energy Ge"+-implanted (0 0 1)Si by high-resolution transmission electron microscopy. The occurrence of abnormal growth is due to the randomization of heavily damaged regions beneath the original amorphous/crystalline interfaces. The randomization process is attributed to the strain, incurred by the presence of a high density of large Ge atoms in the heavily damaged Si substrate, relaxation to lower the free energy of the systems. The randomization upon annealing may be fruitfully applied to minimize the transient enhanced diffusion in shallow junction formation.
2004-01-01
Quantum Darwinism in quantum Brownian motion: the vacuum as a witness
We study quantum Darwinism -- the redundant recording of information about a decohering system by its environment -- in zero-temperature quantum Brownian motion. An initially nonlocal quantum state leaves a record whose redundancy increases rapidly with its spatial extent. Significant delocalization (e.g., a Schroedinger's Cat state) causes high redundancy: many observers can measure the system's position without perturbing it. This explains the objective (i.e. classical) existence of einselected, decoherence-resistant pointer states of macroscopic objects.
2007-01-01
Plasma nitriding of low alloy steels at floating and cathodic potentials
International Nuclear Information System (INIS)
The low alloy steels were nitrided in the plasma atmosphere generated by using hollow cathode discharge. For comparison, specimens of 40 Cr steel were in two different potential states. One kind is isolated from cathode and anode between them the discharge was created. The other kind is placed on the plate which is connected to the cathode. The nitriding was carried out at different temperatures. The surface morphology, phase of compound layers and microhardness profiles were analyzed. The optical microscopy observation and X-ray diffraction showed that the compound layers were formed in all experiments. The results of the nitriding treatment are weakly dependent on the potentials applied on the specimens.
2008-08-15
Partial oxidation of 2-propanol on perovskites
Energy Technology Data Exchange (ETDEWEB)
Partial oxidation of 2-propanol was carried out on AB{sub 1-x}B`{sub x}O{sub 3} (A=Ba, B=Pb, Ce, Ti; B`=Bi, Sb and Cu) type perovskite oxides. Acetone was the major product observed on all the catalysts. All the catalysts underwent partial reduction during the reaction depending on the composition of the reactant, nature of the B site cation and the extent of substitution at B site. The catalytic activity has been correlated with the reducibility of the perovskite oxides determined from Temperature Programmed Reduction (TPR) studies. (orig.)
1998-12-31
Observation of dislocation dynamics in the electron microscope
Deformation experiments performed in-situ in the transmission electron microscope have led to an increased understanding of dislocation dynamics. To illustrate the capability of this technique two examples will be presented. In the first example, the processes of work hardening in Mo at room temperature will be presented. These studies have improved our understanding of dislocation mobility, dislocation generation, and dislocation-obstacle interactions. In the second example, the interaction of matrix dislocations with grain boundaries will be described. From such studies predictive criteria for slip transfer through grain boundaries have been developed.
2001-01-17
Negative charges in liquid hydrogen and deuterium
Energy Technology Data Exchange (ETDEWEB)
The temperature and pressure dependence of the mobilities of negative charges injected into liquid hydrogen and deuterium have been measured. The authors propose the existence of two types of charge carriers in liquid parahydrogen. One is a bubble with an electron inside while the other has higher mobility. Relaxation of the current through liquid hydrogen was observed. It is suggested that in liquid and solid hydrogen under {beta}-irradiation neutral complexes are created which can trap the negative charges and have a lifetime of about 10 hours. 6 refs., 5 figs.
1992-11-01
NMR study of one-dimensional ionic conductor with hollandite-type structure (IV) Rb-priderite
International Nuclear Information System (INIS)
Conduction properties of Rb"+ ion in Rb-Al-priderite and K"+ ion and Rb"+ ion in (K,Rb)-Al-priderite, were investigated by NMR using "2"7Al in the framework as a probe. Size effect was observed remarkably in the activation energies. Frequency dependence of T_1 in Rb-Al-priderite at a low temperature indicates that the relaxation behavior of "2"7Al in Rb-Al-priderite can be described by the continuum model. Barrier height distributions and 'attempt frequencies' in both samples obtained by a curve-fitting method are discussed in comparison with those of K-Al-priderite. (orig.).
1985-08-18
Molecular dynamics study of reaction kinetics in viscous media
British Library Electronic Table of Contents (United Kingdom)
Predicted by stochastic models and observed experimentally in a number of isomerization reactions, viscosity-induced solvent effects manifest themselves in a significant departure of the reaction rates from the values expected on the basis of transition state theory. These effects are well understood within the framework of stochastic models; however, the predictive power of such models is limited by the fact that their parameters are not readily available. Experiment and molecular dynamics (MD) simulations can provide such information and can serve as the testing grounds for various stochastic models. In real solvents, a change in viscosity is inevitably associated with variation of at least one of the three factors - temperature, pressure, or solvent identity, resulting in different solv...
2011-01-01
Metastability of Molecular Phases of Nitrogen: Implications to the Phase Diagram
Energy Technology Data Exchange (ETDEWEB)
Despite their simplicity, diatomic molecules of first row elements can exhibit very complex phase diagrams. Determination of the phase diagrams can be further complicated by the existence of hysteretic molecular phases that can be observed over large regions of coexistence. Here we present evidence for a previously unreported molecular phase of nitrogen existing at room temperature at least over the range of 33-74 GPa. Our measurements show that sample history may have a significant impact on the thermodynamic states accessed by the molecular nitrogen solid and, by extension, also on the established phase diagram.
2001-09-12
Magnetic response of ultrathin Fe on MgO: A polarized neutron reflectometry study
Energy Technology Data Exchange (ETDEWEB)
The magnetization of ultrathin bcc Fe films (two and three monolayers) on MgO was measured and compared with the behavior predicted for a two-dimensional ferromagnet. The experiment indicated that no hysteresis was present in the magnetization. Instead, the magnetization at low temperature was affected by a marked field cooling effect. These observations lead to the conclusion that films of Fe on MgO of such thickness exhibit superparamagnetic behavior as if they were not entirely continuous. In contrast, films thicker than five monolayers exhibit a magnetic response close to that of bulk iron.
1994-11-15
Macro and micro observations on mortar alternation mechanism under the various solution conditions
Energy Technology Data Exchange (ETDEWEB)
Accelerated aging tests have been conducted to evaluate the long-term durability of cementitious material against aggressive ions. In tests, cementitious specimens were immersed in the solutions containing concentrated aggressive ions at high temperature and it promoted diffusion of the ions in the specimen. This method would be suitable for the evaluation on the aging as the alteration of the specimen would be expected to resemble the natural behavior. This paper presents a classification of alteration mechanism in the immersion tests using MgCl{sub 2} and Na{sub 2}SO{sub 4} solution. This classification was done by relating the changes of compressive strength to microscopic and mineralogical changes.
1995-12-31
Knock limitations of methane-air mixtures in a turbocharged dual-fuel engine
Energy Technology Data Exchange (ETDEWEB)
Knock limitations are investigated using natural gas, with diesel pilot ignition, as a fuel for the 3406 DI-TA Caterpillar diesel engine. Thermodynamic properties at TDC are generated by computer and compared with experimental results. Exhaust emissions are analyzed. A comparison is made of dual-fuel operation relative to diesel. Observations are made to determine the onset of knock. The onset of knock is characterized as a function of engine speed, load, inlet manifold temperature, and air-fuel ratio (A/F). The conditions at the inset of knock are determined using cylinder pressure data. The most efficient operating range is determined with knock avoidance as a prime parameter.
1987-01-01
Full-length fuel rod behavior under severe accident conditions
Energy Technology Data Exchange (ETDEWEB)
This document presents an assessment of the severe accident phenomena observed from four Full-Length High-Temperature (FLHT) tests that were performed by the Pacific Northwest Laboratory (PNL) in the National Research Universal (NRU) reactor at Chalk River, Ontario, Canada. These tests were conducted for the US Nuclear Regulatory Commission (NRC) as part of the Severe Accident Research Program. The objectives of the test were to simulate conditions and provide information on the behavior of full-length fuel rods during hypothetical, small-break, loss-of-coolant severe accidents, in commercial light water reactors.
1992-12-01
Free electron laser (FEL) annealing of diamond
International Nuclear Information System (INIS)
Free Electron Laser (FEL) with wide wavelength tunability has been developed and used for various applications. We report the structural-changes in P-ion-implanted diamond when we can achieve resonant excitation of the vibrations of specific bonds in the lattice of target (P-C) by using FEL. The change of property was analyzed by SIMS and Raman spectroscopy. After 5.8 #mu#m-FEL irradiation, we observed the crystallization of amorphous structure which was induced by P-ion-implantation. These results indicated the FEL annealing of diamond at room temperature. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)
1998-09-02
Electrical conductivity of pyrolyzed polyacrylonitrile
Energy Technology Data Exchange (ETDEWEB)
Using ultrapure samples of polyacrylonitrile (PAN) of 485,000 or 150,000 average molecular weight solution cast in dimethylformamide, the dc conductivity (sigma) of pyrolyzed PAN (PANP) films has been studied for pyrolysis temperatures (T/ sub p/) of 280 to 435/sup 0/C. Conductivity measurements made during pyrolysis indicate the onset of a dramatic increase in sigma for T/sub p/ of 390 to 435/sup 0/C. Conductivities as high as 5 (ohm-cm)/sup -1/ have been observed for T/sub p/ < 435/sup 0/C.
1981-01-01
Damage mechanism in high temperature fatigue of alloy 800 H
Energy Technology Data Exchange (ETDEWEB)
In order to investigate the influence of grain boundary cavities on the life time of Alloy 800 H various fatigue tests have been performed at 800/sup 0/C. Cavity formation has been observed only in asymmetrical tests. Compared to the corresponding symmetrical tests, the cyclic life time is shorter. As the cavitation damage increases, the ratio of life times in vacuum and in air steadily decreases from an initial value of 5. In extreme cases it can reach a value close to 1. In this case, cavitation damage dominates over the usual damage mechanism, which is cracks from the surface.
1986-09-01
Energy Technology Data Exchange (ETDEWEB)
The thawing of permafrost regions is supposed to increase climatic change processes due to the released methane. During the last decades the temperature of permafrost soils has increased by several tenths of degree up to 2 deg C. It is supposed that 10 to 20% of the permafrost regions will thaw during the next 100 years. The southern boundary of the permafrost region will move several hundred kilometers toward the north. Besides the increased risk for the climate system there will also be disadvantageous consequences for the ecosystems. Negative economic consequences are already observed and will be enhanced in the futures with significant cost for the public.
2006-08-15
The surface composition and composition near the surface and properties of high-silica zeolites of the TsVK-1 type were studied by XPES, IRS, and low-temperature adsorption of N/sub 2/. It was found that changing the sequence of operations during preparation of the H form of the zeolites results in a different set of acid centers on their surface, caused by migration of cations into the bulk of the zeolites. Migration of elements is also observed during the catalytic reaction of conversion of ethanol.
1988-08-01
Application of light microscopy to direct coal liquefaction research
Energy Technology Data Exchange (ETDEWEB)
Light microscopy was used to analyze the effects of added catalyst at different conditions (temperature and reaction times) in liquefaction testing of a low pyritic sulfur bituminous coal. Quantitative changes in vitrinite/vitroplast reflectance of coal and liquefaction residues were shown to be useful markers in analyzing and understanding the role of catalyst during the initial stage of coal particle hydrogenation. Lower reflectance values corresponded to increased conversions up to about the 60 min and 375{degrees}C experimental conditions. Microscopical observation of liquefaction residues also revealed the presence of `wall scales` of varying width.
1998-01-01
Anomalous electrical resistivity and defects in A-15 compounds
International Nuclear Information System (INIS)
Measurements of the temperature dependence of the electrical resistivity and correlations observed with T/sub c/ for V_3Si, V_3Ge, and A-15 Nb-Ge show (i) the existence of a universal defect in the A-15 superconductors which is not nonstoichiometry, (ii) a normal state anomaly also strongly influenced by the defects, and (iii) evidence that T/sub c/ and the electron-phonon interactions for transport processes are approx.100 times more sensitive to defect producing sample modifications in the A-15 compounds than in Nb.
Anomaliously high radiation hardening of iron-chromium alloys
International Nuclear Information System (INIS)
Argon ions irradiation of 12% Cr steels and Fe/Cr alloys results in the hardening up to 10000 MPa. This value exceeds the hardening level even for martensitic transformation. Along with the increase of microhardness following irradiation the shape of X-ray graph of the affected materials changes considerable. Hardening value and behavior are determined by temperature radiation doze, preliminary ageing, extent of cold strain and alloying. The odserved phenomenon is supposed to be caused by irradiation-induced structural transformations. Reversibility of radiation hardening of the materials in question was observed.
An influence of ion bombardment on plasma nitriding process of Ti6Al14V alloy at 843 K temperature
International Nuclear Information System (INIS)
This work presents results of investigations on d.c. glow discharge nitriding of #alpha#+#beta# Ti-6Al-4V titanium alloy. The treatment was performed at 843 K in nitrogen-hydrogen atmosphere, pressure 300 Pa. Special attention was paid to nitriding mechanism and determination of the role of ion bombarding in nitriding process of titanium alloys. Produced as a result of d.c. plasma nitriding surface layers were subjected to macroscopic observations, microstructure studies, microhardness testing and X-ray analysis. (author)
2004-06-20
International Nuclear Information System (INIS)
The properties of the passive films formed on Alloy 600 at different applied potentials in 10% NaOH solution at 315 .deg. C was studied using in situ AC impedance and polarization measurements. The results were correlated with the stress corrosion cracking (SCC) behavior obtained from the C-ring tests in the same conditions. The change of the semiconductive property and the peak of relaxation time were observed at 0.2 V where the SCC rate showed a maximum. These results were also consistent with the prediction parameter for SCC obtained from fast and slow polarization scans.
2001-10-01
A NEM diffusion code for fuel management and time average core calculation
International Nuclear Information System (INIS)
A computer code based on Nodal expansion method has been developed for solving two groups three dimensional diffusion equation. This code can be used for fuel management and time average core calculation. Explicit Xenon and fuel temperature estimation are also incorporated in this code. TAPP-4 phase-B physics experimental results were analyzed using this code and a code based on FD method. This paper gives the comparison of the observed data and the results obtained with this code and FD code. (author)
2005-11-01
Magnetic and structural investigation of magnetic thin films with obliquely deposited underlayers
An in-plane uniaxial magnetic anisotropy has been observed in thin Co films normally deposited onto obliquely sputtered Ta and Pt underlayers. Associated with this anisotropy is an augmented easy axis coercivity. The in-plane easy axis is, in most cases, perpendicular to the incident deposition plane. Microstructural results indicate that grains are well connected along the magnetic easy axis but are separated by long continuous voids along the hard axis, which is ascribed to a geometric shadowing effect due to the oblique incidence deposition of the underlayer. Hence, the magnetic anisotropy mimics the film growth anisotropy. It is therefore believed that the observed magnetic properties are due to magnetostatic shape anisotropy effects. In-plane coercivity and anisotropy field are shown to increase with underlayer deposition angle, underlayer thickness and magnetic layer thickness. The choice of capping layer is also ...
2002-01-01
Washboard modes as ELM-related events in JET
Energy Technology Data Exchange (ETDEWEB)
Washboard (WB) modes (Smeulders P et al 1999 Plasma Phys. Control. Fusion 41 1303) are a very common edge instability regularly observed in the H-mode regime in JET. They are detected as (normally several) bands of continuously fluctuating magnetic activity rotating in the direction of the electron diamagnetic drift with typical frequencies in the range of 10-90 kHz. The time evolution of the WB mode frequency is found to follow qualitatively the evolution of the electron temperature measured near the pedestal top, probably due to the strong diamagnetic drift associated with the large pedestal gradients. Evidence for their involvement in the pedestal and ELM dynamics will be presented. Increasing WB mode amplitude is correlated with an increase in the time between consecutive type-I ELMs. In situations in which a sudden increase (decrease) of WB mode activity is observed, the build-up of the pedestal ...
2004-01-01
SUBMILLIMETER ARRAY OBSERVATIONS TOWARD THE MASSIVE STAR-FORMING CORE MM1 OF W75N
International Nuclear Information System (INIS)
The massive star-forming core MM1 of W75N was observed using the Submillimeter Array with #approx#1'' and 2'' spatial resolutions at 217 and 347 GHz, respectively. From the 217 GHz continuum we found that the MM1 core consists of two sources, separated by about 1'': MM1a (#approx#0.6 M_s_u_n) and MM1b (#approx#1.4 M_s_u_n), located near the radio continuum sources VLA 2/VLA 3 and VLA 1, respectively. Within MM1b, two gas clumps were found to be expanding away from VLA 1 at about #+-#3 km s"-"1, as a result of the most recent star formation activity in the region. Observed molecular lines show emission peaks at two positions, MM1a and MM1b: sulfur-bearing species have emission peaks toward MM1a, but methanol and saturated species at MM1b. We identified high-temperature (#approx#200 K) gas toward MM1a and the hot core in MM1b. This segregation may result from the evolution of the massive star-forming core. In the very early ...
2010-11-10
Transport and superconducting properties of RNi_2B_2C (R=Y, Lu) single crystals
International Nuclear Information System (INIS)
The in-plane resistivity, in-plane absolute thermopower, and upper critical field measurements are reported for single-crystal samples of YNi_2B_2C and LuNi_2B_2C superconductors. The in-plane resistivity shows metallic behavior and varies approximately linearly with temperature near room temperature (RT) but shows nearly quadratic behavior in temperature at low temperatures. The YNi_2B_2C and LuNi_2B_2C single-crystal samples exhibit large transverse magnetoresistance (#approx#6 8% at 45 kOe) in the ab plane. The absolute thermopower S(T) is negative from RT to the superconducting transition temperature T_c. Its magnitude at RT is a few times of the value for a typical good metal. S(T) is approximately linear in temperature between #approx#150 K and RT. Extrapolation to T=0 gives large intercepts (few #mu#V/K) for both samples suggesting the presence of a much ...
Temperature dependence of the performance of ultraviolet detectors
Energy Technology Data Exchange (ETDEWEB)
We present the results of a comprehensive study of the temperature dependences of the quantum efficiency for ultraviolet detectors based on GaAs, GaP and 4H--SiC Schottky structures, and on Si, GaAs p-n structures. For ultraviolet detectors based on Schottky structures, the quantum efficiency increases with increasing temperature for all photon energies, even including the semiconductor intrinsic absorption region. On the other hand, for ultraviolet detectors based on p-n structures, the quantum efficiency is practically temperature independent in the semiconductor intrinsic absorption region. The change in the quantum efficiency for the GaAs and Si detectors is less than 0.01% per degree. To explain the measurements, a variable trap occupancy model is presented. Subsurface imperfections of the semiconductor cause fluctuations in the profile of the conduction band and the valence band edges. In the presence of an electric ...
2003-08-21
Temperature dependence of the performance of ultraviolet detectors
International Nuclear Information System (INIS)
We present the results of a comprehensive study of the temperature dependences of the quantum efficiency for ultraviolet detectors based on GaAs, GaP and 4H--SiC Schottky structures, and on Si, GaAs p-n structures. For ultraviolet detectors based on Schottky structures, the quantum efficiency increases with increasing temperature for all photon energies, even including the semiconductor intrinsic absorption region. On the other hand, for ultraviolet detectors based on p-n structures, the quantum efficiency is practically temperature independent in the semiconductor intrinsic absorption region. The change in the quantum efficiency for the GaAs and Si detectors is less than 0.01% per degree. To explain the measurements, a variable trap occupancy model is presented. Subsurface imperfections of the semiconductor cause fluctuations in the profile of the conduction band and the valence band edges. In the presence of an electric ...
2003-08-21
Preface: phys. stat. sol. (c) 7/11 12
British Library Electronic Table of Contents (United Kingdom)
AbstractTrends in Nanotechnology (TNT2009) This special issue of Physica Status Solidi presents representative contributions describing the main topics covered at the 10th Trends in Nanotechnology (TNT2009) International Conference, held in Barcelona (Spain), September 07 11, 2009. During the last years many international or national conferences have emerged in response to the growing awareness of the importance of nanotechnology as key issue for the future scientific and technological development. Among these, the conference series Trends in Nanotechnology has become one of the most important meeting points in the nano technology field: it provides fresh organisation ideas, brings together well known speakers, and promotes a suitable environment for discussions, exchanging ideas, enhancin...
2010-01-01
International Nuclear Information System (INIS)
Trends in front-end-of-line technology are discussed. At the chip level, many of the important parameters are published in the National Technology Roadmap for Semiconductors in 1994. At the device and circuit level, both bipolar and CMOS are scalable. However, the large standby power of bipolar circuits severely limits the integration level of bipolar chips. The inherently low standby power of CMOS, on the contrary, allows the integration level of CMOS circuits to continue increasing with scaling. In reality, both the electric field and power density of CMOS devices have been gradually rising over the generations owing to non-scaling effects of thermal voltage and silicon bandgap. As power supply voltage reaches 1.5V and below, circuit performance can only be gained at the expense of higher active or standby power of the chip. Implications of device scaling on contact and silicide technology are addressed. Trends of local and global ...
FEBEX II Project Final report on thermo-hydro-mechanical laboratory tests
International Nuclear Information System (INIS)
The results of the thermo-hydro-mechanical (THM) study of the FEBEX bentonite performed during FEBEX II are presented. The laboratory test program continued in part with the works carried out during FEBEX I, particularly in activities related to tests aimed to the calibration of the models, the acquisition of parameters by back-analysis and the improvement of the knowledge on the behaviour of expansive clays. But the program has also included tests on new areas: investigations about the influence of the microstructure changes in bentonite, of temperature and of the solute concentration on the behaviour of clay. Besides, several tests were proposed in order to understand the unexpected behaviour observed in the mock-up test, towards the end of year 2. Temperature effects on water retention curves in confined and unconfined conditions were determined, and swelling pressure, hydraulic conductivity and swelling and ...
Measurements of water vapor adsorption on the Geysers rocks
Energy Technology Data Exchange (ETDEWEB)
The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 °C and at 200 °C as a function of pressure in the range 0.00 ≤ p/p0 ≤ 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were determined. These parameters are important in estimating water retention capability of a ...
1996-01-24
Energy Technology Data Exchange (ETDEWEB)
Mechanical properties, flow characteristics and chemical resistance of polycarbonate (PC)/polybutylene terephthalate (PBT)/impact modifier (IM) blends were investigated over the various composition ranges of PC and PBT. Mechanical properties of the PC/PBT/IM blends for different IMs, butadiene based IM and butyl acrylate based IM, were studies for various compositions of the IMs. Impact strength at low temperature was also observed. For the study of chemical resistance of the PC/PBT/IM blends, the blends were dipped in organic solvent, thinner, and then variations of mechanical properties were analyzed. Tensile and flexural strengths were increased linearly and heat distortion temperature (HDT) also increased as PC content in the blends increased. Impact strength increased drastically as PC content increased up to 50 wt% and stayed stable value. Flowability decreased as PC content increased. impact strengths of the blend ...
2002-03-01
Dielectric dispersion study of Mn-doped PLZT (8/65/35)
International Nuclear Information System (INIS)
Mn-modified Pb0.92La0.08(Zr0.65Ti0.35)O3 (PLZT) was prepared chemically by a coprecipitate method using their respective nitrate salts and isopropoxides. Differential thermal analysis (DTA) and X-ray analysis clearly show the formation of PLZT single rhombohedral phase for samples calcined beyond 750 C. Uniform grain distribution was observed from scanning electron microscopic (SEM) studies and grain size was found to increase with Mn doping up to x=0.08 and then decreased. Dielectric measurement shows the decrease in peak transition temperature (TC) with Mn doping up to x=0.12 and then increase along with a sharp rise in dielectric maxima. A diffuse dielectric dispersion is observed in all the compositions. A detailed dispersion study was carried out using the Vogel-Fulcher empirical relation, a universal relaxation law and the Havriliak-Negami function. The Vogel-Fulcher relation fitting parameters of activation energy ...
2009-07-01
International Nuclear Information System (INIS)
We review the current status of Andreev reflection spectroscopy on the heavy fermions, mostly focusing on the case of CeCoIn5, a heavy-fermion superconductor with a critical temperature of 2.3 K. This is a well-established technique to investigate superconducting order parameters via measurements of the differential conductance from nanoscale metallic junctions. Andreev reflection is clearly observed in CeCoIn5 as in other heavy-fermion superconductors. Considering the large mismatch in Fermi velocities, this observation seemingly appears to disagree with the Blonder-Tinkham-Klapwijk (BTK) theory. The measured Andreev signal is highly reduced to the order of maximum ?13% compared to the theoretically predicted value (100%). The background conductance exhibits a systematic evolution in its asymmetry over a wide temperature range from above the heavy-fermion coherence temperature down ...
2009-03-11
International Nuclear Information System (INIS)
Generally, neutron, ion and electron Irradiations cause a substantial amount of hardening and significantly alter the deformation behavior of metals and alloys at relatively low irradiation temperatures. A radiation hardening is caused by the formation of microstructural defects such as dislocation loops, voids and precipitates under irradiation. Therefore, it is important to have a better knowledge of the irradiation induced microstructural defects under irradiation condition. As a part of the National mid- and long-term atomic energy R and D program, we are dealing with the radiation hardening behavior in Fe-Cr binary alloy. Fe-Cr binary alloy is a base alloy of Ferritic/Martensitic steel(F/M steel) planning to use for the Gen IV nuclear system. In this work, we investigated the radiation hardening and microstructural defect evolution in ion irradiated Fe-Cr alloys with irradiation temperature using nano-indentation measurement and ...
2009-05-01
The in-reactor deformation of the PCA alloy
Energy Technology Data Exchange (ETDEWEB)
The swelling and in-reactor creep behaviors of the PCA alloy have been determined from the irradiation of pressurized tube specimens in the FFTF reactor. These data have been obtained to a peak neutron fluence corresponding to approximately 80 dpa in the FFTF reactor for irradiation temperatures between 400 and 750/sup 0/C. Diametral measurements performed on the unstressed specimens indicate the possible onset of swelling in the PCA alloy for irradiation temperatures between 400 and 550/sup 0/C and at a neutron fluence corresponding to approx.50 dpa. The creep data suggest a non-linear fluence dependence and linear stress dependence (for hoop stresses less than 100 MPa) which is consistent with the in-reactor creep behavior of many cold worked austenitic stainless steels. These PCA creep data are compared to available 316 SS in-reactor creep data. The in-reactor creep strains for PCA are significantly less than observed in ...
1986-04-01
The in-reactor deformation of the PCA alloy
International Nuclear Information System (INIS)
The swelling and in-reactor creep behaviors of the PCA alloy have been determined from the irradiation of pressurized tube specimens in the FFTF reactor. These data have been obtained to a peak neutron fluence corresponding to approximately 80 dpa in the FFTF reactor for irradiation temperatures between 400 and 750"0C. Diametral measurements performed on the unstressed specimens indicate the possible onset of swelling in the PCA alloy for irradiation temperatures between 400 and 550"0C and at a neutron fluence corresponding to #approx#50 dpa. The creep data suggest a non-linear fluence dependence and linear stress dependence (for hoop stresses less than 100 MPa) which is consistent with the in-reactor creep behavior of many cold worked austenitic stainless steels. These PCA creep data are compared to available 316 SS in-reactor creep data. The in-reactor creep strains for PCA are significantly less than observed in 20% cold ...
1986-04-13
Energy Technology Data Exchange (ETDEWEB)
This work was initiated to examine the effect of frequency and treatment temperature on the formation of nitrided layers and surface characteristics during plasma nitriding. Plasma nitriding experiments were performed with 316L austenitic stainless steel at the temperatures 400 .deg. C and 500 deg. C using a pulsed d.c. plasma with various frequencies in an atmosphere of N{sub 2}-H{sub 2} gas mixture. The microstructure and thickness of the nitrided layer and morphology of the nitrided surface were investigated using OM, SEM, XRD, EDS and AFM. XRD patterns revealed that the surface layer formed at 400 deg. C consisted of S phase only and CrN+Fe{sub 4}N nitrides at 500 .deg. C and no change of phase composition with frequency was observed. The compound layer thickened slightly with increased frequency. Also, the surface roughness increased as the frequency of the pulsed plasma increased from 50 to 5,000Hz.
1999-04-01
Energy Technology Data Exchange (ETDEWEB)
Pretreatment of brown coal in oil was conducted using 1-methyl naphthalene or mixture of tetralin and 1-methyl naphthalene as solvent at temperatures ranging from 300 to 430{degree}C under nitrogen atmosphere. Effects of the solvent properties on the structural change of oxygen-functional groups (OFG) and coal liquefaction were investigated by means of quantitative analysis of OFG and solid state {sup 13}C-NMR measurement. When hydrogen transfer from solvent was insufficient, it was suggested that brown coal molecules loose their hydrogen to be aromatized. While, at lower temperatures ranging from 300 to 350{degree}C, hydrogen contained in brown coal molecules was consumed for the stabilization of pyrolytic radicals, and the deterioration of liquefaction was not observed. When hydrogen transfer from solvent was insufficient at higher temperatures above 400{degree}C in nitrogen atmosphere during ...
1996-10-28
International Nuclear Information System (INIS)
Glasses in the system (95-x) [0.25 Na2O-0.75 B2O3]-x P2O5-5 Fe2O3 (0?x?15 mol%), have been prepared by the melt quenching technique. Elastic properties and FT-IR spectroscopic studies have been employed to study the role of P2O5 on the structure of the glass system. Elastic properties Poisson's ratio, micro-hardness and Debye temperature have been investigated using sound wave velocity measurements at 4 MHz (both longitudinal and shear) at room temperature. The results showed that the density and the molar volume increase as both sound velocities and the determined glass transition temperatures decrease with increasing the contents of P2O5. Infrared spectra of the glasses reveal that the borate network consists of diborate units and is affected by the increase in the concentration of P2O5 content as a second network former. These results are interpreted in terms of the replacement of the diborate units with B-O-B bridges by ...
2009-06-01
Spin-lattice relaxation in A-15 type intermetallic compounds
Energy Technology Data Exchange (ETDEWEB)
The temperature dependence of T/sub 1/ spin-lattice relaxation time on /sup 51/V, /sup 69/Ga, /sup 71/Ga and Knight shift on /sup 51/V and /sup 29/Si nuclei in polycrystalline V/sub 3/Si, V/sub 3/Ga, V/sub 3/Ge and in the monocrystal V/sub 3/Si in normal state is investigated. For V/sub 3/Si and V/sub 3/Ga a rapid growth (T/sub 1/T)/sup -1/ is observed with temperature decrease while for V/sub 3/Ge the maximum (T/sub 1/T)/sup -1/ at T approximately equal to 60 K has been found. The temperature dependence peculiarities have been discussed on the basis of theoretical models available and zone structure calculations for A-15 compounds. The T/sub 1/ anisotropy and possibility of its experimental discovery are considered. Anisotropic contribution in (T/sub 1/T)/sup -1/ and contributions of d states of different symmetries into the electron state density at the Fermi level are estimated for V/sub 3/Si from ...
1981-04-01
Spin-lattice relaxation in A-15 type intermetallic compounds
International Nuclear Information System (INIS)
The temperature dependence of T_1 spin-lattice relaxation time on "5"1V, "6"9Ga, "7"1Ga and Knight shift on "5"1V and "2"9Si nuclei in polycrystalline V_3Si, V_3Ga, V_3Ge and in the monocrystal V_3Si in normal state is investigated. For V_3Si and V_3Ga a rapid growth (T_1T)"-"1 is observed with temperature decrease while for V_3Ge the maximum (T_1T)"-"1 at T approximately equal to 60 K has been found. The temperature dependence peculiarities have been discussed on the basis of theoretical models available and zone structure calculations for A-15 compounds. The T_1 anisotropy and possibility of its experimental discovery are considered. Anisotropic contribution in (T_1T)"-"1 and contributions of d states of different symmetries into the electron state density at the Fermi level are estimated for V_3Si from T_1 measurements.
Radiation-enhanced diffusion in amorphous Pd-Cu-Si
Energy Technology Data Exchange (ETDEWEB)
Diffusion during He/sup +/, Ne/sup +/, and Xe/sup +/ irradiations of trace amounts of Au in melt-spun amorphous Pd/sub 78/Cu/sub 6/Si/sub 16/ has been experimentally investigated. Diffusion constants were measured by following the changes in ion-implanted Au profiles with Rutherford-backscattering spectrometry. Heat treatments and simultaneous irradiations were performed as a function of temperature (533--588 K), ion flux, and ion mass. Total integrated fluences being very small, ion-beam-mixing effects are negligible. More than an order of magnitude enhancement in the diffusion was observed because of irradiations. This enhancement saturates at higher fluxes, the level being independent of ion mass, i.e., independent of collision-cascade parameters. Except at higher temperatures, where the enhancement decreases, the temperature dependence of the diffusion-saturation level is similar to that of the ...
1988-11-01
Radiation-enhanced diffusion in amorphous Pd-Cu-Si
International Nuclear Information System (INIS)
Diffusion during He"+, Ne"+, and Xe"+ irradiations of trace amounts of Au in melt-spun amorphous Pd/sub 78/Cu_6Si/sub 16/ has been experimentally investigated. Diffusion constants were measured by following the changes in ion-implanted Au profiles with Rutherford-backscattering spectrometry. Heat treatments and simultaneous irradiations were performed as a function of temperature (533--588 K), ion flux, and ion mass. Total integrated fluences being very small, ion-beam-mixing effects are negligible. More than an order of magnitude enhancement in the diffusion was observed because of irradiations. This enhancement saturates at higher fluxes, the level being independent of ion mass, i.e., independent of collision-cascade parameters. Except at higher temperatures, where the enhancement decreases, the temperature dependence of the diffusion-saturation level is similar to that of the diffusion without ...
Perovskite-type oxides. Catalysts for the total oxidation of chlorinated hydrocarbons
Energy Technology Data Exchange (ETDEWEB)
Chloromethane, dichloromethane and 1,2-dichloroethane were completely decomposed in air on perovskite-type catalysts (LaMnO{sub 3}, LaCoO{sub 3}, (La{sub 0.84},Sr{sub 0.16})(Mn{sub 0.67},Co{sub 0.33})O{sub 3}) at reaction temperatures above 550C. Besides the main reaction products (carbon dioxide, water and hydrochloric acid), by-products (higher chlorinated-, C-C coupling- and cracking products) were formed in the low temperature range. Depending on the reaction temperature, residence time and kind of chlorinated hydrocarbon a reversible catalyst deactivation takes place. In the case of LaCoO{sub 3} catalysts an irreversible deactivation was observed. X-ray diffraction (XRD) and electron probe microanalysis (EPMA) measurements with the perovskite-type catalysts after interaction of chlorinated hydrocarbons indicate the formation of chlorinated species on the catalyst surface and in the bulk
1998-11-09
Passivation behavior of SUS 304 stainless steel in neutral solutions at elevated temperature
International Nuclear Information System (INIS)
Cyclic voltammograms of SUS 304 stainless steel in various neutral solutions such as Na_2SO_4 at high temperature were measured, as a successive study to previous report in which effects of temperature and pH on polarization behavior of stainless steel were studied. In this measurement Ag/AgCl reference electrode and platinum counter electrode were used in a static autoclave lined with inconel. Passive films formed in various conditions were analysed by electron diffraction and Auger spectroscopy. Results obtained were compared with anodic behavior of iron, chromium and nickel and with thermodynamical stabilities of their compounds. The main results are summarized as follows. (1) Stainless steel shows such electrochemical behavior as active dissolution, passivation and transpassivation in a deaerated neutral solution at 250"0C after fully reductive treatment of the specimen. In air-saturated solution, the peak of active dissolution is not ...
1981-01-01
We review results from general relativistic axisymmetric magnetohydrodynamic simulations of accretion in Sgr A*. We use general relativistic radiative transfer methods and to produce a broad band (from millimeter to gamma-rays) spectrum. Using a ray tracing scheme we also model images of Sgr A* and compare the size of image to the VLBI observations at 230 GHz. We perform a parameter survey and study radiative properties of the flow models for various black hole spins, ion to electron temperature ratios, and inclinations. We scale our models to reconstruct the flux and the spectral slope around 230 GHz. The combination of Monte Carlo spectral energy distribution calculations and 230 GHz image modeling constrains the parameter space of the numerical models. Our models suggest rather high black hole spin ($a_*\\approx 0.9$), electron temperatures close to the ion temperature ($T_i/T_e \\sim 3$) and high ...
2010-01-01
Magnetic properties of Y_2Cu_2O_5, Y_2BaCuO_5, and Y_2Ba_2O_5 compounds
International Nuclear Information System (INIS)
The magnetic susceptibility of Y_2Cu_2O_5, Y_2BaCuO_5, and Y_2Ba_2O_5 single-phase compounds in weak magnetic fields (H_0=0.1--20 Oe) and moderate magnetic fields (H_0#=#0.2 Oe it converts into a paramagnetic maximum #chi#(T) which corresponds to an antiferromagnetic transition. In a moderate magnetic field H=500 Oe a normal Curie-Weiss law, #chi##approx##mu#"2_e_f_f (T-#theta#) is observed. At temperatures T=150--300 K, #theta#=38 K and #mu#_e_f_f#approx#2.2 #mu#_B/at. Cu. At T<150 k the temperature dependence of #chi# is described by a simple Curie law with #theta##approx#0. Although the paramagnetic signal is extremely weak, in the Y_2Ba_2O_5 compound the curve of #chi#(T, H_0=100 Oe) for a Y_2ba_2O_5 sample exhibits a slightly smeared maximum at a temperature T#approx#13 K.
1989-01-01
Knight shift in the superconducting state of several vanadium based A-15 compounds
International Nuclear Information System (INIS)
The resonance line shift of a series of A-15 structures (V_3Pt, Vsub(0.76)Ptsub(0.24) and Vsub(0.62)Irsub(0.38) is measured as a function of temperature in the superconducting state. A method will be described to separate the contribution of the diamagnetism of the superconductor (Meissner effect) and that of the Knight shift to this line shift. From the temperature dependence of the Knight shift of the V atoms the sum of the s and d contribution to the Knight shift can be determined. In these three compounds the s and d contributions appear to cancel out nearly. Moreover the temperature dependence of kappa_2 can be calculated from the measurements. The values of kappa_2 extrapolated at T=Tsub(c) are about 70 for these samples. From the obtained sum of Ksub(s) and Ksub(d) and the data of the susceptibility or of the specific heat of these samples Ksub(s) and Ksub(d) can be separated. For all samples Ksub(s)=0.06+-0.005%. ...
Ion mixing of near-noble monosilicides with Si substrates
Energy Technology Data Exchange (ETDEWEB)
Xe ion irradiation of NiSi, PdSi, and PtSi on Si was performed at various substrate temperatures. The phase formation and mixing behavior of the three monosilicides with their Si substrates are quite different. For NiSi, NiSi/sub 2/ was formed on amorphous Si substrates at 350 /sup 0/C, while NiSi remained stable on crystalline Si substrates even at 400 /sup 0/C. PtSi reacted with Si to form a metastable Pt/sub 4/Si/sub 9/ phase, which decomposed back to PtSi and Si by successive irradiation at higher temperatures. The decomposition of the metastable Pt/sub 4/Si/sub 9/ was easier on crystalline Si substrates than on amorphous substrates. No mixing was observed for PdSi on Si in the temperature range of 35--400 /sup 0/C. The ion mixing results were compared with those from thermal annealing. The importance of demixing of a thermally stable system was explored.
1989-05-01
Ion mixing of near-noble monosilicides with Si substrates
International Nuclear Information System (INIS)
Xe ion irradiation of NiSi, PdSi, and PtSi on Si was performed at various substrate temperatures. The phase formation and mixing behavior of the three monosilicides with their Si substrates are quite different. For NiSi, NiSi_2 was formed on amorphous Si substrates at 350 "0C, while NiSi remained stable on crystalline Si substrates even at 400 "0C. PtSi reacted with Si to form a metastable Pt_4Si_9 phase, which decomposed back to PtSi and Si by successive irradiation at higher temperatures. The decomposition of the metastable Pt_4Si_9 was easier on crystalline Si substrates than on amorphous substrates. No mixing was observed for PdSi on Si in the temperature range of 35--400 "0C. The ion mixing results were compared with those from thermal annealing. The importance of demixing of a thermally stable system was explored.
Inhomogeneous grain growth and elongation of Dy-#alpha# SiAlON ceramics
International Nuclear Information System (INIS)
Dysprosium #alpha#-sialon ceramic has been fabricated from #alpha#-Si_3N_4, AlN, Al_2O_3 and Dy_2O_3 starting powders, using gas pressure sintering at 1800 deg C or higher temperatures under a relatively low gas pressure of 0.9MPa N_2. The resultant #alpha#-sialon grains showed significantly different features, such as equiaxed, elongated, and even a few extraordinarily large with high aspect ratio grains in the fine matrix, which has rarely been observed in #alpha#' ceramics. It is suggested that the temperature strongly influences the grain morphologies of #alpha#-sialon, playing an important role particularly in the latter stage of the 'nucleation-growth' process. Such a microstructural morphology of mixed with equiaxed and elongated grains toughens the #alpha#-sialon ceramics and leaves them still hard. Overly high temperature treatment leads to the preferential growth of a few #alpha#' grains which ...
Evaluation of the humidification requirements of new proton exchange membranes for fuel cells
Measurements of PEM fuel cell device performance were made with different gas inlet temperatures and relative humidity using a newly-designed test fixture. Significant improvement in device performance was observed when the fuel inlet temperature was increased above the operating temperature of the cell. These measurements were then correlated to a model to describe energy and mass transport processes. Proton exchange membrane (PEM), fuel cells--the focus of this study--use an ion conducting polymer, especially polyperfluorosulfonic acid materials. These polymer materials, when imbibed with water, exhibit solution-like properties, but because the anions are chemically bound to the polymeric structure, the electrolyte is contained. Importantly, product water removal is simplified, as electrolyte dilution is not a concern. However, the proton transport rate is a function of the polymer geometry, which is ...
1995-05-01
International Nuclear Information System (INIS)
Glasses in the system (1 - x) [29Na2O- 4Al2O3- 67B2O3]- xZnO (0 ? x ? 35 mol%), have been prepared by the melt quenching technique. Elastic properties, X-ray and FT-IR spectroscopic studies have been employed to study the role of ZnO on the structure of the investigated glass system. Elastic properties and Debye temperature have been investigated using sound wave velocity measurements at 4 MHz at room temperature. The results showed that the density increases and the molar volume decreases while both sound velocities and the determined glass transition temperatures decrease with increase in x. X-ray and infrared spectra of the glasses reveal that the borate network consists of diborate units and is affected by the increase in the concentration of ZnO content. These results are interpreted in terms of the decrease in the N4 values (fraction of tetrahedral coordinated boron atoms), and substitution of longer bond lengths of ...
2009-05-05
Effects of Thermal Annealing Upon the Nanomorphology of Poly(3-hexylselenophene)-PCBM Blends
British Library Electronic Table of Contents (United Kingdom)
Abstract Grazing incidence X-ray diffraction (GI-XRD) is used to characterize the crystallographic dynamics of low molecular weight (LMW) and high molecular weight (HMW) poly(3-hexylselenophene) (P3HS) films and blend films of P3HS with [6-6-]-phenyl-C61-butyric acid methyl ester (PCBM) as a function of -step-by-step- thermal annealing, from room temperature to 250-C. The temperature-dependent GIXRD data show how the melting point of P3HS crystallites is decreased by the presence of PCBM. P3HS crystallite domain sizes dramatically increase upon annealing to the P3HS melting temperature. The formation of well-oriented HMW P3HS crystallites with the (100) plane parallel to the substrate (edge-on orientation), when cooled from melt, are observed. We compare the behaviour of P3HS pure and blen...
2011-01-01
Effect of carbon on irradiation hardening of reduced-activation 10Cr-30Mn austenitic steels
International Nuclear Information System (INIS)
Tensile properties of reduced-activation 10Cr-30Mn austenitic steels with carbon levels from 0.003 to 0.55% were investigated over the temperature range from room temperature to 873 K after neutron irradiation in the Japan Materials Testing Reactor at 573 K to 8.5x10"2"2 n/m"2. Irradiation-induced increase in yield stress increased significantly with carbon concentration up to about 0.1% and it was constant above 0.1% carbon. A high density of dislocation loops with small (below 10 nm) and large (20-30 nm) sizes formed during irradiation. The high density, small loops caused a large irradiation hardening, while the large loops contributed only slightly to irradiation hardening. It was considered that carbon atoms formed the small loops together with irradiation defects. The deformation channeling was observed in the irradiated high carbon steels, 0.11 and 0.55% carbon, but not in the very low carbon steel, 0.003% carbon, ...
EPR, optical, infrared and Raman studies of VO"2"+ ions in polyvinylalcohol films
International Nuclear Information System (INIS)
Electron paramagnetic resonance (EPR), optical, infrared and Raman spectral studies have been carried out on vanadyl ions doped in polyvinylalcohol (PVA) films. The spin-Hamiltonian parameters (g and A) and the molecular orbital coefficients (#beta#_2"*"2 and k) have been evaluated. The values of spin-Hamiltonian parameters confirm that the vanadyl ions are present in PVA films as VO"2"+ molecular ions in an octahedral site with a tetragonal compression (C_4_v). The temperature variation EPR studies reveal that the variation of number of spins with temperature is in accordance with Boltzmann law. It is interesting to observe that the variation of susceptibility with temperature obeys Curie-Weiss law. The FT-IR and FT-Raman spectrum exhibits few bands, which are attributed to O-H, C-H, C-C and C-O groups of stretching and bending vibrations. The optical absorption spectrum exhibits two bands, which are ...
2007-01-15
Development of sialon using Yttria and alumina as additive
International Nuclear Information System (INIS)
Full text: The production of #beta#-sialon from kaolinite and carbon has been studied using Hulu Langat Kaolin and activated carbon as raw materials. The sintered temperature is shown to play a prominent role in the process of sialon conversion. Apart from temperature, nitrogen flow rate is also affect the production of #beta#--sialon. This study was carried out on the effect of additive, Y_2O_3 and Al_2O_3 at different temperature that will be mixed and sintered. The additives are expected to affect the formation of #beta#--sialon and Y-sialon upon the synthesis. The mineral and phase development was analysed using X-Ray Diffraction technique (Rigaku Geigerflex) while its chemical compositions through X-Ray Fluorescent Spectrophotometer (Shimadzu XRF 1700) and the particle size distribution analysis through Particle Size Analyser (Horiba, CAPA 700). The observed changes in the microstructure were ...
2005-08-16
Consequences of warm-up of a sector above 80K
There may be circumstances when a sector has to be partially or totally warmed-up to temperatures above 80 K, that is when thermal dilatation starts to play a role. Some equipment have been identify as presenting a risk, like the non-conform "plug-in" modules in the arcs. Because of motion induced by thermal dilatation, the electrical (ElQA) quality control may also have to be done again after cool-down. The main reason identified so far for partial warm-up is the required maintenance of the cooling towers and the cryogenics plants. There is also the request from the vacuum group to periodically warm-up the beam screen to temperatures in the 100 K region to release and pump-out the gas crysorbed on the surface of the beam screen. Observed and expected temperature conditions and statistics on failures of PIMs in sectors which have been warmed-up will be presented in this contribution. Methods to detect ...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
To improve organic electronic applications, knowledge about microscopic mechanisms determining the charge carrier mobilities is pivotal. 9,10-Diphenylanthracene (DPA) has been identified as model system to study those correlations due to its high electron and hole mobilities at room temperature and its complex structural phase behaviour. We demonstrate our temperature dependent Time-Of-Flight data on single crystals grown by vapor phase transport (VPT) and by Bridgman growth technique. Both preparation techniques revealed crystals of different morphologies resulting in significant variations of the related bipolar mobilities. As a key result, the charge carrier mobility of {proportional_to}1 cm{sup 2}/Vs at room temperature along the (111)-direction of Bridgman crystals exceeds that along the (001)-direction of VPT grown crystals by about one order of magnitude. The observed differences in the mobility ...
2010-07-01
British Library Electronic Table of Contents (United Kingdom)
Soils of arid regions of Central Asia contain salts of different types that may differentially affect seed germination and plant development. We studied effect of NaCl, Na2SO4, 2NaCl + KCl + CaCl2 and 2Na2SO4+K2SO4+MgSO4 on germination of Kochia prostrata and Kochia scoparia seeds under a range of concentrations from 0.5 to 5% and at two constant temperature regimes +22 degrees C and +6 degrees C. The observed salt tolerance limit of germination at constant temperature +22 degrees C for both species was 5-6%, while at low temperature (+6 degrees C) this limit was 2%. The salt tolerance of young plants (before flowering) was 3% for NaCl. Low concentrations of sulfuric and mixed salts had a stimulating effect on seed germination in K. prostrata. Despite similarity of salt-tolerance limits...
2011-01-01
Anisotropy in Magnetic Properties and Electronic Structure of Single Crystal LiFePO4
Energy Technology Data Exchange (ETDEWEB)
We report the experimental and theoretical results on the anisotropies in the magnetic properties and x-ray absorption spectra of single-crystal LiFePO4. A mean-field theory is developed to explain the observed strong anisotropies in Lande g-factor, paramagnetic Curie temperature, and effective moment for LiFePO4 single crystals. The values of the in-plane nearest- and next-nearest-neighbor spin exchange (J1 and J2), interplane spin exchange (J{perpendicular}), and single-ion anisotropy (D), obtained recently from neutron scattering measurements, are used for calculating the Curie temperatures with the formulas derived from the mean-field Hamiltonian. It is found that the calculated Curie temperatures match well with that obtained by fitting the magnetic susceptibility curves to the modified Curie-Weiss law. For the polarized Fe K-edge x-ray absorption spectra of single-crystal LiFePO4, a different ...
2008-01-01
Diverging trends in incidence and mortality of testicular cancer in Denmark, 1943-1982.
UK PubMed Central (United Kingdom)
Between 1943 and 1982, 5,140 new cases of testicular cancer were diagnosed in Denmark. The age-standardized incidence rate more than doubled in the period. Striking variations is seen in the age-relationship...Full Text Available
1986-04-01
Cyberpharmacies and the role of the US Food And Drug Administration
UK PubMed Central (United Kingdom)
The sale of consumer products over the Internet has grown rapidly, including the sale of drugs. While the growth in online drug sales by reputable pharmacies is a trend that may provide benefits to...Full Text Available
Amazon.com: Customer Reviews: Womenomics: Write Your Own Rules for Success
...Own Rules for Success (Hardcover) The authors have rightly identified that there is a growing demand for, trend towards, and interest in guidance for creating flexible working arrangements. However, for $27.99, you can secure more concrete advice on reaching your \\
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